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1

State Restrictions on Methyl Tertiary Butyl Ether (released in AEO2006)  

Reports and Publications (EIA)

By the end of 2005, 25 states had barred, or passed laws banning, any more than trace levels of methyl tertiary butyl ether (MTBE) in their gasoline supplies, and legislation to ban MTBE was pending in 4 others. Some state laws address only MTBE; others also address ethers such as ethyl tertiary butyl ether (ETBE) and tertiary amyl methyl ether (TAME). Annual Energy Outlook 2006 assumes that all state MTBE bans prohibit the use of all ethers for gasoline blending.

2006-01-01T23:59:59.000Z

2

Experimental Pathology Laboratories, Inc. Methyl-Tertiary-Butyl Ether  

E-Print Network [OSTI]

COORDINATOR'S REPORT FOR LIFETIME CARCINOGENICITY STUDY OF METHYL-TERTIARY-BUTYL ETHER (MTBE) IN SPRAGUE CARCINOGENICITY STUDY OF METHYL-TERTIARY-BUTYL ETHER (MTBE) IN SPRAGUE-DAWLEY RATS CONDUCTED AT THE CANCER

Baker, Chris I.

3

Atmospheric Methyl Tertiary Butyl Ether (MTBE) at a Rural Mountain Site in California  

E-Print Network [OSTI]

Atmospheric Methyl Tertiary Butyl Ether (MTBE) at a Rural Mountain Site in California Gunnar W. Schade,* Gabrielle B. Dreyfus, and Allen H. Goldstein ABSTRACT (CARB) measured MTBE in urban regions in 1995­ 1996, reporting a range of 0.4 to 13.2 ppbv in the LosMethyl tertiary butyl ether (MTBE

Cohen, Ronald C.

4

Anhydrous aluminum chloride as an alkylation catalyst: identification of mono- and dialkyl-benzenes from the condensation of tertiary butyl alcohol with benzene.  

E-Print Network [OSTI]

LIBRARY a a w c"I. I. SI - O~ TI:YAf ANHYDROUS ALUMINUM CHLORIDE AS AN ALKYLATION CATALYST: IDENTIFICATION OF MONO- AND DIALKYIZENZENES FROM THE CONDENSATION QF TERTIARY BUTYL ALCOHOL WITH BENKENE IACEY EUGENE SCOGGINS 4 A Thesis Submitted...: IDENTIFICATION OF MONO- AND DI~NZZNES FROM THE CONDENSATION OF TERTIARY BUTYL ALCOHOL WITH BENZENE A Thesis By LACEY EUGENE SCOGGINS Approved as to style and content hy: Chairman of Committee Head of Chemistry Department 1959 ACKNOWLEDGME1VTS The author...

Scoggins, Lacey E

1959-01-01T23:59:59.000Z

5

Toxicity of methyl tertiary butyl ether to Daphnia magna and photobacterium phosphoreum  

SciTech Connect (OSTI)

Methyl tertiary butyl ether (MTBE) is a liquid organic compound added to gasoline to increase its oxygen content and to reduce the emission of carbon monoxide during combustion in many urban areas. In order to meet the 1990 Clean Air Act amendments, gasoline must contain 2.7% oxygen (by weight) or 15% (by volume) of MTBE in gasoline to meet the regulations for the control of carbon monoxide emissions. Health effects caused by inhalation of MTBE include headaches, dizziness, irritated eyes and nausea; MTBE is one of cancer--causing chemicals. Intracaval injection of MTBE (0.2 mg/kg) caused the highest mortality (100%) in rats. General anesthetic effect induced by MTBE was found at or above 1200 mg/kg body weight; Rosenkranz and Klopman (1991) predicted that MTBE is neither a genotoxicant nor a carcinogen. Nevertheless, the safety of using MTBE in oxygenated fuels is now being questioned from its potential as groundwater pollutant. This study measures the toxicity of MTBE to Daphnia magna and Photobacterium phosphoreum. 13 refs.

Gupta, G.; Lin, Y.J. [Univ. of Maryland Eastern Shore, Princess Anne, MD (United States)

1995-10-01T23:59:59.000Z

6

Disposition, metabolism, and toxicity of methyl tertiary butyl ether, an oxygenate for reformulated gasoline  

SciTech Connect (OSTI)

Studies of the toxicology of methyl tertiary butyl ether (MTBE) were reviewed as a possible information base for evaluating the health effects of evaporative emissions from reformulated gasoline (RFG). Perirenal fat/blood MTBE concentration ratios ranged from 9.7 to 11.6 after 15 wk of intermittent exposure. During an oxyfuels program in Fairbanks, AK, blood levels of occupationally exposed workers were 0.2-31.5 {mu}g/L MTBE and 1.6 to 72.2 {mu}g/L TBA with a mean TBA:MTBE blood concentration ratio of 4.2. In patients who received MTBE by percutaneous, transhepatic puncture for the dissolution of cholesterol gallstones, concentrations of MTBE in fat tissue reached 60 and 300 {mu}g/g at a treatment time when mean blood MTBE was less than 20 {mu}g/ml. The results of laboratory and clinical studies indicate that metabolites of MTBE may contribute to the nephropathy, neoplasms, and other pathological changes associated with repeated exposure to MTBE in experimental animals. It is concluded that such studies can provide a well-defined database for quantitatitive safety comparisons and health risk-benefit analyses of MTBE and other oxygenates in RFG. 39 refs., 1 tab.

Hutcheon, D.E.; Hove, W. ten; Boyle, J. III [UMDNJ, New Jersey Medical Schook, Newark, NJ (United States)] [UMDNJ, New Jersey Medical Schook, Newark, NJ (United States); Arnold, J.D. [Arnold & Arnold, Inc., Kansas City, MO (United States)] [Arnold & Arnold, Inc., Kansas City, MO (United States)

1996-04-05T23:59:59.000Z

7

Acute toxicity of methyl-tertiary-butyl ether (MTBE) to aquatic organisms  

SciTech Connect (OSTI)

Due to the recent amendment of the Clean Air Act, oxygenates are now being added to gasolines to boost octane and reduce air pollution from combustion in heavily populated areas. Oxygenates such as alcohols (i.e. methanol) and ethers (methyl-tertiary-butyl ether, MTBE) are commonly being used. A series of bioassay studies have been conducted with MTBE, one of the most commonly used octane-enhancing additives. Freshwater and marine studies were conducted with fish, invertebrates and algae to determine the impact of this material on the environment following accidental spills. Static-renewal studies were run to ensure maintenance of MTBE, a highly volatile material in the test containers. Chemical confirmation of exposure concentrations demonstrated the adequacy of the exposure system. Mysid shrimp were highly sensitive to MTBE, with significantly less effect observed with the other species evaluated. These data have implications for spill response, particularly since MTBE is slow to biodegrade and will rapidly move through groundwater. Comparative data for other oxygenates will also be discussed.

BenKinney, M.T.; Barbieri, J.F.; Gross, J.S.; Naro, P.A. [Stonybrook Labs. Inc., Princeton, NJ (United States)

1994-12-31T23:59:59.000Z

8

Alveolar breath sampling and analysis to assess exposures to methyl tertiary butyl ether (MTBE) during motor vehicle refueling  

SciTech Connect (OSTI)

In this study we present a sampling and analytical methodology that can be used to assess consumers` exposures to methyl tertiary butyl ether (MTBE) that may result from routine vehicle refueling operations. The method is based on the collection of alveolar breath samples using evacuated one-liter stainless steel canisters and analysis using a gas chromatograph-mass spectrometer equipped with a patented `valveless` cryogenic preconcentrator. To demonstrate the utility of this approach, a series of breath samples was collected from two individuals (the person pumping the fuel and a nearby observer) immediately before and for 64 min after a vehicle was refueled with premium grade gasoline. Results demonstrate low levels of MTBE in both subjects` breaths before refueling, and levels that increased by a factor of 35 to 100 after the exposure. Breath elimination models fitted to the post exposure measurements indicate that the half-life of MTBE in the first physiological compartment was between 1.3 and 2.9 min. Analysis of the resulting models suggests that breath elimination of MTBE during the 64 min monitoring period was approximately 155 {mu}g for the refueling subject while it was only 30 {mu}g for the nearby observer. This analysis also shows that the post exposure breath elimination of other gasoline constituents was consistent with previously published observations. 20 refs., 3 figs., 4 tabs.

Lindstrom, A.B.; Pleil, J.D. [U.S. Environmental Protection Agency, Research Triangle Park, NC (United States)

1996-07-01T23:59:59.000Z

9

Health concerns fuel EPA study of ETBE and TAME  

SciTech Connect (OSTI)

Citing possible health risks associated with the use of methyl tert-butyl ether (MTBE) in winter-blend gasoline and requirements of the 1990 Clean Air Act (CAA), EPA has called for testing the health effects of ethyl tert-butyl ether (EBTE) and tert-amyl methyl ether (TAME). The program calls for toxicity testing to develop data on the health effects of ETBE and TAME. EPA may require chemical manufacturers and processors to provide the data. A public meeting will be held this week to begin working on an agreement. EPA says most of the data should be collected in 1995 and expects the program to cost approximately $3 million. In December, EPA floated a proposal to require 30% of the oxygenates used in the reformulated gasoline program to come from renewable sources such as ETBE and ethanol. Although EPA found no serious health risks associated with MTBE, questions remain, which is why EPA says it will test the use of ETBE and TAME. William Piel, business manager for oxygenated fuels at Arco Chemical (Newtown Square, PA), says testing is {open_quotes}just a formality.{close_quotes} There should be no difference in results among MTBE, ETBE, or TAME, he says. But ETBE and TAME have much lower volatility than MTBE, which would mean significantly less exposure to these oxygenates, Piel says. Arco is the biggest producer of MTBE but also has capability to make ETBE.

Lucas, A.

1994-05-11T23:59:59.000Z

10

Use TAME and heavier ethers to improve gasoline properties  

SciTech Connect (OSTI)

Producing oxygenates from all potential FCC tertiary olefins is one of the most economic methods for reducing olefins and Reid vapor pressure (Rvp) in motor gasoline. MTBE production based on FCC isobutylene has reached a very high level. But the amount of MTBE from a refinery sidestream MTBE unit is insufficient for producing reformulated gasoline (RFG) and additional oxygenates must be purchased. The next phase will see conversion of isoamylenes in FCC light gasoline to TAME. Very little attention has been given to the heavier tertiary olefins present in the FCC light gasoline like tert-hexenes and heptenes. This route allows higher levels of oxygenates production, thereby lowering Rvp and the proportion of olefins in the gasoline pool and maximizing the use of FCC olefins. By using all the components produced by an FCC efficiently, many gasoline problems can be solved. Isobutene is converted to MTBE, C[sub 3]/C[sub 4] olefins are converted to alkylate and C[sub 5] tertiary olefins can be converted to TAME. All of these are preferred components for gasoline quality. By producing more oxygenates like MTBE, TAME and heavier ethers, a refinery can be self-sufficient in blending reformulated gasoline and no oxygenates need to be purchased. The technology for producing TAME and other ethers is described.

Ignatius, J.; Jaervelin, H.; Lindqvist, P. (Neste Engineering, Porvoo (Finland))

1995-02-01T23:59:59.000Z

11

Race to license new MTBE and TAME routes heats up  

SciTech Connect (OSTI)

With refineries and petrochemical manufacturers continuing to gear up production of oxygenates for use in reformulated fuels, new routes to methyl tert-butyl ether (MTBE) and tert-amyl methyl ether (TAME) are clearly hot items in the licensing market. And probably nowhere has the competition become as intense as in offerings for skeletal isomerization technologies to boost ethers production from fluid catalytic cracking and steam cracking.

Rotman, D.

1993-01-06T23:59:59.000Z

12

TAMING MATLAB Anton Dubrau  

E-Print Network [OSTI]

TAMING MATLAB by Anton Dubrau School of Computer Science McGill University, Montréal Friday, April OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF SCIENCE Copyright © 2012 Anton Dubrau #12;#12;Abstract MATLAB is a dynamic scientific language used by scientists, engineers and students worldwide. Although MATLAB is very

Verbrugge, Clark

13

Protein folding tames chaos  

E-Print Network [OSTI]

Protein folding produces characteristic and functional three-dimensional structures from unfolded polypeptides or disordered coils. The emergence of extraordinary complexity in the protein folding process poses astonishing challenges to theoretical modeling and computer simulations. The present work introduces molecular nonlinear dynamics (MND), or molecular chaotic dynamics, as a theoretical framework for describing and analyzing protein folding. We unveil the existence of intrinsically low dimensional manifolds (ILDMs) in the chaotic dynamics of folded proteins. Additionally, we reveal that the transition from disordered to ordered conformations in protein folding increases the transverse stability of the ILDM. Stated differently, protein folding reduces the chaoticity of the nonlinear dynamical system, and a folded protein has the best ability to tame chaos. Additionally, we bring to light the connection between the ILDM stability and the thermodynamic stability, which enables us to quantify the disorderli...

Xia, Kelin

2013-01-01T23:59:59.000Z

14

Mode of action of ethyl tertiary-butyl ether hepatotumorigenicity in the rat: Evidence for a role of oxidative stress via activation of CAR, PXR and PPAR signaling pathways  

SciTech Connect (OSTI)

To elucidate possible mode of action (MOA) and human relevance of hepatotumorigenicity in rats for ethyl tertiary-butyl ether (ETBE), male F344 rats were administered ETBE at doses of 0, 150 and 1000 mg/kg body weight twice a day by gavage for 1 and 2 weeks. For comparison, non-genotoxic carcinogen phenobarbital (PB) was applied at a dose of 500 ppm in diet. Significant increase of P450 total content and hydroxyl radical levels by low, high doses of ETBE and PB treatments at weeks 1 and 2, and 8-OHdG formation at week 2, accompanied accumulation of CYP2B1/2B2, CYP3A1/3A2 and CYP2C6, and downregulation of DNA oxoguanine glycosylase 1, induction of apoptosis and cell cycle arrest in hepatocytes, respectively. Up-regulation of CYP2E1 and CYP1A1 at weeks 1 and 2, and peroxisome proliferation at week 2 were found in high dose ETBE group. Results of proteome analysis predicted activation of upstream regulators of gene expression altered by ETBE including constitutive androstane receptor (CAR), pregnane-X-receptor (PXR) and peroxisome proliferator-activated receptors (PPARs). These results indicate that the MOA of ETBE hepatotumorigenicity in rats may be related to induction of oxidative stress, 8-OHdG formation, subsequent cell cycle arrest, and apoptosis, suggesting regenerative cell proliferation after week 2, predominantly via activation of CAR and PXR nuclear receptors by a mechanism similar to that of PB, and differentially by activation of PPARs. The MOA for ETBE hepatotumorigenicity in rats is unlikely to be relevant to humans. - Highlights: We focus on MOA and human relevance of hepatotumorigenicity in rats for ETBE. ETBE was administered to F344 rats for 1 and 2 weeks. Oxidative stress formation, proliferation and apoptosis in the liver are analyzed. ETBE-induced changes of gene and protein expression in the liver are examined. The effects are compared with those induced by non-genotoxic carcinogen PB.

Kakehashi, Anna, E-mail: anna@med.osaka-cu.ac.jp [Department of Pathology, Osaka City University Graduate School of Medicine, 1-4-3 Asahi-machi, Abeno-ku, Osaka 545-8585 (Japan); Hagiwara, Akihiro; Imai, Norio [DIMS Institute of Medical Science, Inc., 64 Goura, Nishiazai, Azai-cho, Ichinomiya, Aichi 491-0113 (Japan); Nagano, Kasuke [Nagano Toxicologic-Pathology Consulting, Ochiai, Hadano, Kanagawa 257-0025 (Japan); Nishimaki, Fukumi [Biofuel Assessment Group, New Fuels Dept., Japan Petroleum Energy Center (JPEC), 4-3-9 Toranomon, Minato-ku, Tokyo 105-0001 (Japan); Banton, Marcy [Toxicology and Risk Assessment, LyondellBasell Industries, LyondellBasell Corporate HSE/Product Safety, One Houston Center, Suite 700, 1221 McKinney Street, Houston, TX 770 10 (United States); Wei, Min [Department of Pathology, Osaka City University Graduate School of Medicine, 1-4-3 Asahi-machi, Abeno-ku, Osaka 545-8585 (Japan); Fukushima, Shoji [Department of Pathology, Osaka City University Graduate School of Medicine, 1-4-3 Asahi-machi, Abeno-ku, Osaka 545-8585 (Japan); Japan Bioassay Research Center, Japan Industrial Safety and Health Association, 2445 Hirasawa, Hadano, Kanagawa 257-0011 (Japan); Wanibuchi, Hideki [Department of Pathology, Osaka City University Graduate School of Medicine, 1-4-3 Asahi-machi, Abeno-ku, Osaka 545-8585 (Japan)

2013-12-01T23:59:59.000Z

15

REVIEW ARTICLE Taming molecular beams  

E-Print Network [OSTI]

REVIEW ARTICLE Taming molecular beams The motion of neutral molecules in a beam can be manipulated time-varying fields can be used to decelerate or accelerate beams of molecules to any desired velocity. We review the possibilities that this molecular-beam technology offers, ranging from ultrahigh

Loss, Daniel

16

The tame and the wild valuation 13.1 Tame and purely wild extensions  

E-Print Network [OSTI]

Chapter 13 The tame and the wild valuation theory 13.1 Tame and purely wild extensions Lemma 7) is a subextension of (Kr |K, v). By 321 #12;322 CHAPTER 13. THE TAME AND THE WILD VALUATION THEORY assumption, (E) of a henselian field (K, v) is called purely wild if it satisfies the following conditions: (PW1) vL/vK is a p

Kuhlmann, Franz-Viktor

17

The structure of tame minimal dynamical systems  

E-Print Network [OSTI]

A dynamical version of the Bourgain-Fremlin-Talagrand dichotomy shows that the enveloping semigroup of a dynamical system is either very large and contains a topological copy of $\\beta \\N$, or it is a "tame" topological space whose topology is determined by the convergence of sequences. In the latter case the dynamical system is called tame. We use the structure theory of minimal dynamical systems to show that, when the acting group is Abelian, a tame metric minimal dynamical system (i) is almost automorphic (i.e. it is an almost 1-1 extension of an equicontinuous system), and (ii) admits a unique invariant probability measure such that the corresponding measure preserving system is measure theoretically isomorphic to the Haar measure system on the maximal equicontinuous factor.

Eli Glasner

2006-09-18T23:59:59.000Z

18

Taming MATLAB Anton Dubrau and Laurie Hendren  

E-Print Network [OSTI]

Taming MATLAB Anton Dubrau and Laurie Hendren McGill University anton.dubrau@mail.mcgill.ca, hendren@cs.mcgill.ca Abstract MATLAB is a dynamic scientific language used by scientists, engineers and students worldwide. Although MATLAB is very suitable for rapid prototyping and development, MAT- LAB users

19

Taming the Plasma-Material Interface  

E-Print Network [OSTI]

Demo R&D: Taming the Plasma- Material Interface Rob Goldston #12;Outline PMI-Based Mission Risks) National High-Power Advanced Torus Experiment (NHTX) version of PMIF #12;PMI Mission Risks - I 1 facing surface. #12;PMI Mission Risks - II 5. Steady heat and particle loads result in unacceptable power

20

Effects of oxygenate concentration on species mole fractions in premixed n-heptane flames  

E-Print Network [OSTI]

-heptane/oxygenate mixtures were 2.7 and 3.4. Three different fuel oxygenates (i.e. MTBE, methanol, and ethanol) were tested tertiary-butyl ether (MTBE), ethyl tertiary-butyl ether (ETBE), and tertiary amyl methyl ether (TAME)) were considered as possible fuel oxygenates. MTBE and ethanol are the most common oxygenates currently used

Senkan, Selim M.

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

New low energy process for MTBE and TAME  

SciTech Connect (OSTI)

Considered as new bulk petrochemicals of limited feedstocks MTBE (methyltertbutylether) and TAME (tertamylmethylether) need cheap and simple, minimum-cost production processes. The problems in optimizing the etherification are set by specifications for ether products and hydrocarbon raffinates. Working up reaction products from etherification processes containing hydrocarbons, methanol and ether to secure the pure main and side products is difficult because of azeotrope formation of methanol with ethers or hydrocarbons. At EC Erdolchemie GmbH, Cologne, a semicommercial unit with a capacity of 2,500 metric t/y has now been successfully operated for nearly one year producing high purity MTBE (> 99 wt.%) and a raffinate II with methanol content of < 0.05 wt.%. The TAME process has successfully been tested in a 3,000 kg/y TAME pilot plant for almost two years. Based on the operating experience, EC has prepared the engineering for a commercial multiproduct plant, including the production of 30,000 metric t/y MTBE, 15,000 metric t/y TAME and 6,000 metric t/y methylbutenes (TAME cracking product) in the first stage. EC has made application to the authorities for a construction permit. The process for MTBE and TAME will be licensed by EC Erdolchemie GmbH, Postfach 75 20 02, 5000 Cologne 71, West Germany or by Lurgi Kohle und Mineraloltechnik GmbH, Postfach 11 12 31, 6000 Frankfurt Main 2, West Germany.

Herwig, J.; Schleppinghoff, B.; Schulwitz, S.

1984-06-01T23:59:59.000Z

22

Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process  

E-Print Network [OSTI]

, methanol recovery 1. Introduction A process of producing TAME via reactive distillation has been presented the bulk of the reaction between C5 and methanol to produce TAME and a reactive distillation. MethanolDesign of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

Al-Arfaj, Muhammad A.

23

TAME-BLIND EXTENSION OF MORPHISMS OF TRUNCATED BARSOTTI-TATE GROUP SCHEMES  

E-Print Network [OSTI]

TAME-BLIND EXTENSION OF MORPHISMS OF TRUNCATED BARSOTTI-TATE GROUP SCHEMES YUICHIRO HOSHI OCTOBER with perfect residue fields extend in a "tame-blind" fashion -- i.e., under a condition which is unaffected. The "tame-blindness" of our extension result al- lows one to verify the analogue of a result of Tate

24

THE TAME-WILD PRINCIPLE FOR DISCRIMINANT RELATIONS FOR NUMBER FIELDS  

E-Print Network [OSTI]

THE TAME-WILD PRINCIPLE FOR DISCRIMINANT RELATIONS FOR NUMBER FIELDS JOHN W. JONES AND DAVID P, these divisibility relations continue to hold even in the presence of wild ramification. 1. Overview Let G that the tame- wild principle holds for (G, 1, . . . , r). Our terminology "tame-wild principle" is intended

Roberts, David P.

25

New etherification process commercialized in Finland  

SciTech Connect (OSTI)

The phase-out of leaded fuels in Europe, Asia, and parts of Africa and Latin America is increasing demand for octane and octane-bearing fuel components such as ethers. Early solutions to the problem of increasing octane while reducing tailpipe emissions involved use of methyl tertiary butyl ether (MTBE). According to Neste, using both tertiary amyl methyl ether (TAME) and MTBE can give refiners increased blending flexibility for volatility control. But the economics associated with TAME production often make TAME units difficult to justify. The paper discusses the NExTAME process, the unit at the Porvoo refinery and process improvements.

NONE

1997-01-06T23:59:59.000Z

26

Taming Hurricanes With Arrays of Offshore Wind Turbines  

E-Print Network [OSTI]

Taming Hurricanes With Arrays of Offshore Wind Turbines Mark Z. Jacobson Cristina Archer, Willet #12;Representation of a vertically-resolved wind turbine in model Lines are model layers) or 50 m/s (destruction) speed. Can Walls of Offshore Wind Turbines Dissipate Hurricanes? #12;Katrina

Firestone, Jeremy

27

Taming water waves Case study: Surface Water Waves  

E-Print Network [OSTI]

Taming water waves Case study: Surface Water Waves Few things in nature are as dramatic, and potentially dangerous, as ocean waves. The impact they have on our daily lives extends from shipping to the role they play in driving the global climate. From a theoretical viewpoint water waves pose rich

28

Tame and wild automorphisms of free algebras Ivan Shestakov  

E-Print Network [OSTI]

Tame and wild automorphisms of free algebras Ivan Shestakov Let An be an algebra of polynomials which he sug- gested to be non-time (wild). Later Anick provided a candidate for a wild automorphism in the free associative algebra on 3 generators. In 2004, Shestakov and Umirbaev solved the problem of wild

Kunkle, Tom

29

Taming turbulence in magnetized plasmas: from fusion energy to  

E-Print Network [OSTI]

occurs (fusion of particle beams will not work...) Thermonuclear fusion in a confined plasma (T~10 keTaming turbulence in magnetized plasmas: from fusion energy to black hole accretion disks Troy?: In fusion plasmas turbulent leakage of heat and particles is a key issue. Sheared flow can suppress

30

Taming the Curse of Dimensionality: Discrete Integration by Hashing and Optimization  

E-Print Network [OSTI]

Taming the Curse of Dimensionality: Discrete Integration by Hashing and Optimization Stefano Ermon but without a tightness guarantee. Markov Chain Monte Carlo (MCMC) methods for sampling are asymptotically

Bejerano, Gill

31

Character formulas and tame representations for gl(m|n)  

E-Print Network [OSTI]

In 1994, Kac and Wakimoto suggested a generalization of Bernstein and Leites character formula for basic Lie superalgebras, and the natural question was raised: to which simple highest weight modules does it apply? They called modules that satisfy this character formula tame, and proved the formula in some special cases. In this paper, we prove a similar formula for a larger class of finite dimensional simple modules for the Lie superalgebra gl(m|n).

Michael Chmutov; Crystal Hoyt; Shifra Reif

2014-07-01T23:59:59.000Z

32

An Experiment to Tame the Plasma Material Interface  

SciTech Connect (OSTI)

The plasma material interface in Demo will be more challenging than that in ITER, due to requirements for approximately four times higher heat flux from the plasma and approximately five times higher average duty factor. The scientific and technological solutions employed in ITER may not extrapolate to Demo. The key questions to be resolved for Demo and the resulting key requirements for an experiment to 'tame the plasma material interface' are analyzed. A possible design point for such an experiment is outlined.

Goldston, R J; Menard, J E; Allain, J P; Brooks, J N; Canik, J M; Doerner, R; Fu, G; Gates, D A; Gentile, C A; Harris, J H; Hassanein, A; Gorelenkov, N N; Kaita, R; Kaye, S M; Kotschenreuther, M; Kramer, G J; Kugel, H W; Maingi, R; Mahajan, S M; Majeski, R; Neumeyer, C L; Nygren, R E; Ono, M; Owen, L W; Ramakrishnan, S; Rognlien, T D; Ruzic, D N; Ryutov, D D; Sabbagh, S A; Skinner, C H; Soukhanovskii, V A; Stevenson, T N; Ulrickson, M A; Valanju, P M; Woolley, R D

2009-01-08T23:59:59.000Z

33

We're a step closer to taming the Sun (Filed: 06/07/2005)  

E-Print Network [OSTI]

We're a step closer to taming the Sun (Filed: 06/07/2005) An experimental thermonuclear reactor days in the 1950s when scientists first dreamt of taming the Sun, tens of billions have been spent that fusion - the source of the Sun's power - could solve the world's future energy needs by generating vast

34

Radical-anions of aromatic compounds. VII. Reaction of the products from the reduction of nitrobenzene by sodium with isopropyl and tert-butyl iodides  

SciTech Connect (OSTI)

The reaction of the products from the reduction of nitrobenzene by one and two equivalents of sodium with isopropyl iodide leads to the formation of N,O-diisopropylphenylhydroxylamine, while the reaction with tert-butyl iodide leads to p-(tert-butyl)nitrobenzene. Such a change in the nature of the reaction product in the transition from the primary and secondary alkyl halides to the tertiary alkyl halides clearly results from a change in the S/sub N/2 mechanism to the S/sub RN/1 mechanism, involving transfer of an electron from the radical-anion or dianion of nitrobenzene to the alkyl halide. The formation of considerable amounts of azoxybenzene in the reaction with tert-butyl iodide shows that the dianion and, to a lesser degree, the radical-anion of nitrobenzene exhibit basic characteristics.

Danilova, N.K.; Shteingarts, V.D.

1986-09-20T23:59:59.000Z

35

antioxidant butylated hydroxytoluene: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Fusarium solani CiteSeer Summary: Fusarium solani degraded methyl tert-butyl ether (MTBE) and other oxygenated compounds from gasoline including tert-butyl alcohol (TBA). The...

36

Biodegradation of methyl tertiary butyl ether (MTBE) using a granular activated carbon trickling filter  

SciTech Connect (OSTI)

A pilot scale trickling filter was constructed using granular activated carbon (GAC) as the packing medium and inoculated with a microbial culture known to degrade MTBE. The packing dimensions were 0.076 m in diameter and 0.22 m deep. The unit operated with recycling flow for two months before a biofilm was observed on the GAC. After two additional months the biofilm had visibly spread throughout the packing. A few pieces of GAC were placed in a sealed bottle with MTBE-contaminated water and nutrients. Headspace analysis performed over 14 days confirmed that MTBE degradation was occurring. The trickling filter was converted to continuous flow and operated for one month at a nominal flow rate of 0.1 L/min and a hydraulic loading rate of 32 m{sup 3}/m{sup 2}-d. Samples were collected for analysis at the spray nozzle and at the bottom of the trickling filter. Fractional removal varied with influent MTBE concentration, temperature and liquid flow rate. Percent MTBE removal was as high as 85%. A mechanical failure resulted in the trickling filter bed drying and percent removal dropping to less than 1 percent. However, the system recovered within five days.

Converse, B.M.; Schroeder, E.D.; Chang, D.P.Y.

1999-07-01T23:59:59.000Z

37

Taming Uncertainties in Wireless Messaging for Automotive Cyber-Physical-Systems  

E-Print Network [OSTI]

Taming Uncertainties in Wireless Messaging for Automotive Cyber-Physical-Systems Hongwei Zhang Wireless networking for automotive CPS Today's vehicles are much more than a mechanical device, and complex to the scalability of vehicular communication system, which is a basic element of automotive cyber-physical systems

Rajkumar, Ragunathan "Raj"

38

Proving Correctness of the Basic TESLA Multicast Stream Authentication Protocol with TAME  

E-Print Network [OSTI]

Proving Correctness of the Basic TESLA Multicast Stream Authentication Protocol with TAME Presented, Washington, DC 20375 E-mail: archer@itd.nrl.navy.mil The TESLA multicast stream authentication protocol just been revealed. While an informal argument for the correctness of TESLA has been published

39

Taming Data Complexity in Lifelogs: Exploring Visual Cuts of Personal Informatics Data  

E-Print Network [OSTI]

-based self-tracking devices and applications, questions arise about how personal informatics tools can better of devices and applications are becoming increasingly popular for collecting and tracking personal dataTaming Data Complexity in Lifelogs: Exploring Visual Cuts of Personal Informatics Data Daniel A

Munson, Sean A.

40

E-Print Network 3.0 - ammoniated glycyrrhizin butylated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ammoniated glycyrrhizin butylated Search Powered by Explorit Topic List Advanced Search Sample search results for: ammoniated glycyrrhizin butylated Page: << < 1 2 3 4 5 > >> 1...

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Influence of taming on the episodic pattern of LH in peripheral plasma of percentage-Brahman heifers  

E-Print Network [OSTI]

INFLUENCE OF TAMING ON THE EPISODIC PATTERN OF LH IN PERIPHERAL PLASMA OF PERCENTAGE-B~N HEIFERS A Thesis by ROHN HAYDEN HENRICKS Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1982 Maj or Subj ect: Physiology of Reproduction INFLUENCE OF TAMING ON THE EPISODIC PATTERN OF LH IN PERIPHERAL PLASMA QF PERCENTAGE-BRAHMM HEIFERS A Thesis by ROHN HAYDEN HENRICKS Approved as to style and content...

Henricks, Rohn Hayden

1982-01-01T23:59:59.000Z

42

Impacts of Ethanol on Anaerobic Production of Tert-Butyl Alcohol (TBA) from Methyl Tert-Butyl Ether (MTBE) in Groundwater  

E-Print Network [OSTI]

Methyl Tert-Butyl Ether (MTBE) in Groundwater P.I. names,Methyl tert-butyl ether (MTBE) is a contaminant of concernsubsurface environments. MTBE appears to be degraded readily

Scow, K M; MacKay, Douglas

2008-01-01T23:59:59.000Z

43

Concentrating aqueous acetate solutions with tertiary amines  

E-Print Network [OSTI]

Water may be extracted from aqueous calcium acetate or sodium acetate solutions using low miscibility, low molecular weight tertiary amines, e.g. triethylamine (TEA) and N,N- dietliylmethylaniine (DEMA). This novel extraction technology...

Lee, Champion

1993-01-01T23:59:59.000Z

44

Economics for iso-olefin production using the fluid catalytic cracking unit  

SciTech Connect (OSTI)

The Clean Air Act of 1990 requires use of oxygenates in some gasolines to improve both CO and hydrocarbon auto tailpipe emissions. Various oxygenates are currently being used by the refining industry. For the fully integrated refinery having a fluid catalytic cracking unit, the most commonly used oxygenates are methyl tertiary butyl ether (MTBE) and tertiary amyl ether (TAME). The FCC unit produces the isobutylene and iso-amylases need for manufacture of both MTBE and TAME. The economics for an assumed refinery processing scheme for several FCC cases are examined giving estimates of income and investments for each case. Up to one-third of the total gasoline pool can be made in reformulated gasoline using TAME and MTBE with the FCC unit as the sole source of feedstock. This processing route is much more economical than the alternative scheme using butane isomerization/iosbutane dehydrogenation.

McClung, R.G.; Witoshkin, A.; Bogert, D.C.; Winkler, W.S. [Englehard Corp., Iselin, NJ (United States)

1993-12-31T23:59:59.000Z

45

Control Study of Ethyl tert-Butyl Ether Reactive Distillation Muhammad A. Al-Arfaj  

E-Print Network [OSTI]

-butyl ether (ETBE) for gasoline blending as a replacement for methyl tert-butyl ether (MTBE) because and be blended with ETBE in the gasoline pool. Even for neat operation, if the conversion is low, the unconverted

Al-Arfaj, Muhammad A.

46

alkyl tert-butyl ether: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Fusarium solani CiteSeer Summary: Fusarium solani degraded methyl tert-butyl ether (MTBE) and other oxygenated compounds from gasoline including tert-butyl alcohol (TBA). The...

47

active methyl tert-butyl: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Fusarium solani CiteSeer Summary: Fusarium solani degraded methyl tert-butyl ether (MTBE) and other oxygenated compounds from gasoline including tert-butyl alcohol (TBA). The...

48

Methyl tertiary butyl ether (MtBE) contamination of the City of Santa Monica drinking water supply  

SciTech Connect (OSTI)

In the summer of 1996, the City of Santa Monica ceased pumping groundwater from two Well Fields (Charnock and Arcadia) used for public drinking water supply due to persistent and increasing concentrations of MtBE in all seven municipal water supply wells. This lost production accounted for 50% of the City`s total drinking water supply. In late 1996, the City, in cooperation with State and Federal agencies, initiated an investigation of MtBE contamination at the two well fields. The objectives of the investigation were as follows: (1) Review available data on the production, use, chemical characteristics, fate and transport, toxicology, and remediation of MtBE; (2) Identify locations of potential sources of MtBE groundwater contamination at the well fields; (3) Develop an understanding of the hydrologic pathways from the potential sources to the drinking water wells; and (4) Evaluate alternative treatment technologies for the removal of MtBE from drinking water. In addition to a review of available information about MtBE, the investigation included an extensive review of literature and available data relevant to the well fields, including well field production histories, site and regional hydrogeology, all well logs and production in the groundwater basins, general groundwater quality, and the record of MtBE detection. Based upon the review of background information, conceptual hydrogeologic models were developed. A detailed review of agency files for over 45 potential source sites was conducted. The information from this review was summarized, and source site screening and ranking criteria were developed. A field program was conducted at the major well field (Charnock), including soil gas surveys, CPTs, soil borings and well installations, geophysics, and aquifer testing. The field program provided site data which allowed the conceptual hydrogeologic model to be refitted to actual site conditions.

Brown, A.; Farrow, J.R.C. [Komex H2O Science, Huntington Beach, CA (United States); Rodriguez, R.A. [City of Santa Monica, CA (United States)] [and others

1997-12-31T23:59:59.000Z

49

Review of potential technologies for the treatment of Methyl tertiary butyl Ether (MtBE) in drinking water  

SciTech Connect (OSTI)

At present, the state of knowledge on effective treatment technologies for MtBE in drinking water, and groundwater in general, is limited. Research by others is focusing on the remediation of MtBE close to the point of release. The City of Santa Monica, MWD, Komex and USC are currently conducting research into different technologies that could be used to remove MtBE from drinking water supplies. The objectives of the research are to evaluate different treatment technologies to identify cost-effective and technically feasible alternatives for the removal of MtBE from drinking water. The evaluation is considering moderate to high water flow rates (100 to 2,000+ gpm) and low to moderate MtBE concentrations (<2,000 {mu}g/l). The research program includes four phases: (1) Literature Review; (2) Bench Scale Study; (3) Field Scale Pre-pilot Study; and (4) Summary Evaluation. This paper presents some preliminary information and findings from the first phase of this research - the literature review. The review discusses the chemical properties of MtBE and how they affect remediation and thus, an evaluation of alternative treatment technologies. The review of available literature, and the applicability and limitations of the following technologies are presented in detail.

Brown, A.; Browne, T.E. [Komex H2O Science, Huntington Beach, CA (United States); Devinny, J.S. [Univ. of Southern California, Los Angeles, CA (United States)] [and others

1997-12-31T23:59:59.000Z

50

A SUMMARY OF COAL IN THE COALMONT FORMATION (TERTIARY),  

E-Print Network [OSTI]

Chapter SN A SUMMARY OF COAL IN THE COALMONT FORMATION (TERTIARY), NORTH PARK BASIN, COLORADO By S assessment of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great

51

SUMMARY OF TERTIARY COAL RESOURCES OF THE DENVER BASIN, COLORADO  

E-Print Network [OSTI]

Chapter SD SUMMARY OF TERTIARY COAL RESOURCES OF THE DENVER BASIN, COLORADO By D. J. Nichols in U.S. Geological Survey Professional Paper 1625-A 1999 Resource assessment of selected Tertiary coal beds and zones here or on this symbol in the toolbar to return. 1999 Resource assessment of selected Tertiary coal

52

Taming Matlab.  

E-Print Network [OSTI]

??MATLAB is a dynamic scientific language used by scientists, engineers and students worldwide. Although MATLAB is very suitable for rapid prototyping and development, MATLAB users (more)

Dubrau, Anton

2012-01-01T23:59:59.000Z

53

Oxygenates du`jour...MTBE? Ethanol? ETBE?  

SciTech Connect (OSTI)

There are many different liquids that contain oxygen which could be blended into gasoline. The ones that have been tried and make the most sense are in the alcohol (R-OH) and ether (R-O-R) chemical family. The alcohols considered are: methanol (MeOH), ethanol (EtOH), tertiary butyl alcohol (TBA). The ethers are: methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE), tertiary amyl methyl ether (TAME), tertiary amyl ethyl ether (TAEE), di-isopropyl ether (DIPE). Of the eight oxygenates listed above, the author describes the five that are still waiting for widespread marketing acceptance (methanol, TBA, TAME, TAEE, and DIPE). He then discusses the two most widely used oxygenates in the US, MTBE and ethanol, along with the up-and-coming ethanol ether, ETBE. Selected physical properties for all of these oxygenates can be found in Table 2 at the end of this paper. A figure shows a simplified alcohol/ether production flow chart for the oxygenates listed above and how they are interrelated.

Wolfe, R.

1995-12-31T23:59:59.000Z

54

Cytotoxic and DNA-damaging effects of methyl tert-butyl ether and its metabolites on HL-60 cells in vitro  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) is a widely used oxygenate in unleaded gasoline; however, few studies have been conducted on the toxicity of this compound. This study evaluates the cytotoxic and DNA-damaging effects of MTBE and its metabolites in a human haemopoietic cell line, HL-60. The metabolites of MTBE studied include tertiary butyl alcohol (TBA), {alpha}-hydroxyisobutyric acid (HIBA), and formaldehyde. Comet assay is used to assess DNA damage, and the cytotoxicity is investigated by lactate dehydrogenease (LDH) release. The results show no significant cytotoxic effects of MTBE, TBA, and HIBA over a concentration ranging from 1 to 30 mM. Formaldehyde, in contrast, causes a substantial LDH release at a concentration of 5 {mu}M. Hydrogen peroxide, a known oxidative agent, at concentrations ranging from 10 to 100 {mu}M, produces a significant dose-related increase in DNA damage, whereas a much higher concentration of MTBE (1 to 30 mM) is required to produce a similar observation. The genotoxic effects of TBA and HIBA appear to be identical to that of MTBE. Conversely, DNA damage is observed for formaldehyde at a relatively low concentration range (5 to 100 {mu}M). These findings suggest that MTBE and its metabolites, except formaldehyde, have relatively low cytotoxic and genotoxic effects. 16 refs., 4 figs.

Tang, G.H. [Xian Medical Univ. (China); Shen, Y.; Shen, H.M. [National Univ. of Singapore (Singapore)] [and others

1996-12-31T23:59:59.000Z

55

Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 2.  

E-Print Network [OSTI]

vapors of methyl tert-butyl ether (MTBE), a gasoline additive of great environmental concern MTBE treatment are discussed. Introduction The rapidly rising number of reports of groundwater con- taminated with the gasoline additive methyl tert-butyl ether (MTBE) has raised concerns about its

56

Environmental Microbiology (2001) 3(6), 407416 Methyl tert-butyl ether (MTBE) degradation by a  

E-Print Network [OSTI]

Environmental Microbiology (2001) 3(6), 407±416 Methyl tert-butyl ether (MTBE) degradation of California, Riverside, Riverside, CA 92521, USA. Summary The widespread use of methyl tert-butyl ether (MTBE is often proposed as the most promising alter- native after treatment. However, MTBE biodegradation appears

57

Shear viscosity measurements in the binary mixture butyl cellosolve-water near its upper and lower critical consolute points  

E-Print Network [OSTI]

has been measured for a two-component critical liquid system, butyl cellosolve-water, in the region to report measurements of the shear viscosity of critical binary mixture butyl cello- solve (2-n353 Shear viscosity measurements in the binary mixture butyl cellosolve-water near its upper

Boyer, Edmond

58

EXECUTIVE SUMMARY TERTIARY COAL RESOURCES IN THE NORTHERN  

E-Print Network [OSTI]

Professional Paper 1625-A 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern or on this symbol in the toolbar to return. 1999 Resource assessment of selected Tertiary coal beds and zones......................................................................ES-8 Figures ES-1. Coal basins under study in the current resource assessment, by region. ES-2

59

E-Print Network 3.0 - ai tertiary structures Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

tertiary structures Search Powered by Explorit Topic List Advanced Search Sample search results for: ai tertiary structures Page: << < 1 2 3 4 5 > >> 1 OECD FACTBOOK 2008 ISBN...

60

Aqueous flooding methods for tertiary oil recovery  

DOE Patents [OSTI]

A method of aqueous flooding of subterranean oil bearing formation for tertiary oil recovery involves injecting through a well into the formation a low alkaline pH aqueous sodium bicarbonate flooding solution. The flooding solution's pH ranges from about 8.25 to 9.25 and comprises from 0.25 to 5 weight percent and preferably about 0.75 to 3.0 weight percent of sodium bicarbonate and includes a petroleum recovery surfactant of 0.05 to 1.0 weight percent and between 1 and 20 weight percent of sodium chloride. After flooding, an oil and water mixture is withdrawn from the well and the oil is separated from the oil and water mixture.

Peru, Deborah A. (Bartlesville, OK)

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Oxidation of methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) by ozone and combined ozone/hydrogen peroxide  

SciTech Connect (OSTI)

The aim of this work was to study the reaction of ozone and combined ozone/hydrogen peroxide on oxygenated additives such as methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) in dilute aqueous solution using controlled experimental conditions. Experiments conducted in a semi-continuous reactor with MTBE and ETBE in combination (initial concentration: 2 mmol/L of each) showed that ETBE was better eliminated than MTBE with both ozone and combined O[sub 3]/H[sub 2]O[sub 2]. batch experiments led to the determination of the ratio of the kinetic constants for the reaction of OH[degree]-radical with MTBE and ETBE (k[sub OH[degree]/ETBE]/k[sub OH[degree]//MTBE] = 1.7). Tert-butyl formate and tert-butyl acetate were identified as the ozonation byproducts of MTBE an ETBE, respectively, while tert-butyl alcohol was found to be produced during the ozonation of both compounds. 10 refs., 10 figs., 1 tab.

Leitner, N.K.V.; Papailhou, A.L.; Croue, J.P.; Dore, M. (Univ. de Poitiers (France)); Peyrot, J. (British Petroleum, Harfleur (France))

1994-01-01T23:59:59.000Z

62

The Effect of the Di-Tertiary Butyl Peroxide (DTBP) additive on HCCI Combustion of Fuel Blends of Ethanol and Diethyl Ether  

E-Print Network [OSTI]

Charge Compression Ignition (HCCI) Engines: Key Research andJ. Girard, and R. Dibble, "HCCI in a CFR Engine: ExperimentsRyan III, and J.S. Souder, "HCCI Operation of a Dual-Fuel

Mack, John Hunter; Buchholz, Bruce A; Flowers, Daniel L; Dibble, Robert W

2005-01-01T23:59:59.000Z

63

The Effect of the Di-Tertiary Butyl Peroxide (DTBP) additive on HCCI Combustion of Fuel Blends of Ethanol and Diethyl Ether  

E-Print Network [OSTI]

diethyl ether (DEE) in ethanol fuel blends for a range ofbio-derived fuel components (ethanol) in emission productsHCCI Combustion of Fuel Blends of Ethanol and Diethyl Ether

Mack, John Hunter; Buchholz, Bruce A; Flowers, Daniel L; Dibble, Robert W

2005-01-01T23:59:59.000Z

64

Analysis of dissolved benzene plumes and methyl tertiary butyl ether (MTBE) plumes in ground water at leaking underground fuel tank (LUFT) sites  

SciTech Connect (OSTI)

The 1990 Clean Air Act Amendments mandate the addition of oxygenates to gasoline products to abate air pollution. Currently, many areas of the country utilize oxygenated or reformulated fuel containing 15- percent and I I-percent MTBE by volume, respectively. This increased use of MTBE in gasoline products has resulted in accidental point source releases of MTBE containing gasoline products to ground water. Recent studies have shown MTBE to be frequently detected in samples of shallow ground water from urban areas throughout the United States (Squillace et al., 1995). Knowledge of the subsurface fate and transport of MTBE in ground water at leaking underground fuel tank (LUFT) sites and the spatial extent of MTBE plumes is needed to address these releases. The goal of this research is to utilize data from a large number of LUFT sites to gain insights into the fate, transport, and spatial extent of MTBE plumes. Specific goals include defining the spatial configuration of dissolved MTBE plumes, evaluating plume stability or degradation over time, evaluating the impact of point source releases of MTBE to ground water, and attempting to identify the controlling factors influencing the magnitude and extent of the MTBE plumes. We are examining the relationships between dissolved TPH, BTEX, and MTBE plumes at LUFT sites using parallel approaches of best professional judgment and a computer-aided plume model fitting procedure to determine plume parameters. Here we present our initial results comparing dissolved benzene and MTBE plumes lengths, the statistical significance of these results, and configuration of benzene and MTBE plumes at individual LUFT sites.

Happel, A.M.; Rice, D. [Lawrence Livermore National Lab., CA (United States); Beckenbach, E. [California Univ., Berkeley, CA (United States); Savalin, L.; Temko, H.; Rempel, R. [California State Water Resources Control Board, Sacramento, CA (United States); Dooher, B. [California Univ., Los Angeles, CA (United States)

1996-11-01T23:59:59.000Z

65

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE  

E-Print Network [OSTI]

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE SURVEYS By Michael J. Moran, Rick M. Clawges, and John S. Zogorski U.S. Geological Survey 1608 Mt. View Rapid City, SD 57702 Methyl tert-butyl ether (MTBE) is commonly added to gasoline

66

Eutrophication potential of secondary and tertiary wastewater effluents  

E-Print Network [OSTI]

hydroxi de or some other base. 8ecause of its low cost 1n some areas, waste pickle 11quor will probably be useful in some treatment systems. Alum has been used for phosphate removal in both the secondary (act1vated sludge) and tertiary processes.... In the secondary process, alum has reduced the effluent phosphorus concentration to 0 . 5 - 1. 0 mg/1. Tertiary alum treatment has been used at the FWOA ? Lebanon Pilot Plant, Lebanon, Oh1o (8). The pilot plant at Dallas, Texas, is investigating the use of 11...

Ivy, James Thomas

1972-01-01T23:59:59.000Z

67

A SUMMARY OF COAL IN THE FORT UNION FORMATION (TERTIARY), BIGHORN BASIN,  

E-Print Network [OSTI]

Chapter SB A SUMMARY OF COAL IN THE FORT UNION FORMATION (TERTIARY), BIGHORN BASIN, WYOMING assessment of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U...........................................................................................................................SB-1 Coal Production History

68

Energy Efficiency Improvement and Cost Saving Opportunities for the Petrochemical Industry - An ENERGY STAR(R) Guide for Energy and Plant Managers  

E-Print Network [OSTI]

Ethylene dichloride 1 MTBE 2 Vinylchloride 3 Ethylbenzene 1Methyl- Tertiary-Butyl-Ether (MTBE) or Ethyl-Tertiary-Butyl-Styrene Vinylchloride MTBE Benzene, Toluene, Xylene Acetone

Neelis, Maarten

2008-01-01T23:59:59.000Z

69

E-Print Network 3.0 - australian tertiary referral Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Darwin Institution Programme Summary: ANUTECH (Australian National University) Foundation Studies Program Australian National University... for Tertiary Studies) Batchelor...

70

TERTIARY INSTITUTIONS SERVICE CENTRE (Incorporated in Western Australia)  

E-Print Network [OSTI]

TERTIARY INSTITUTIONS SERVICE CENTRE (Incorporated in Western Australia) 100 Royal Street East Perth, Western Australia 6004 Telephone (08) 9318 8000 Facsimile (08) 9225 7050 http://www.tisc.edu.au/ Curtin University Edith Cowan University Murdoch University The University of Western Australia

71

TERTIARY INSTITUTIONS SERVICE CENTRE (Incorporated in Western Australia)  

E-Print Network [OSTI]

TERTIARY INSTITUTIONS SERVICE CENTRE (Incorporated in Western Australia) Level 1, 100 Royal Street East Perth, Western Australia 6004 Telephone (08) 9318 8000 Facsimile (08) 9225 7050 http://www.tisc.edu.au/ Curtin University Edith Cowan University Murdoch University The University of Western Australia

72

Treatment of Methyl tert-Butyl Ether Contaminated Water Using a Dense  

E-Print Network [OSTI]

-butyl ether (MTBE) in a dense medium plasma (DMP) reactor utilizing gas chromatog- raphy-massspectrometryandgaschromatography-thermal conductivity techniques. A rate law is developed for the removal of MTBE from an aqueous solution in the DMP. The oxidation products from the treatment of MTBE-contaminated water in the DMP reactor were found

Dandy, David

73

International Journal of Mass Spectrometry 249250 (2006) 303310 Pyrolysis of 2-methoxy-2,3,3-trimethylbutane (MTMB) monitored by  

E-Print Network [OSTI]

used fuel oxygenates MTBE and TAME), the predominance of bond homolysis at temperatures >900 K suggests homologues ­ methyl tert-butyl ether (MTBE) and tert-amyl methyl ether (TAME) ­ present a new set of problems discussed as alternatives to MTBE and TAME, because they are expected to be much less soluble in water. More

Morton, Thomas Hellman

74

Pool octanes via oxygenates  

SciTech Connect (OSTI)

Increasingly stringent antipollution regulations placed on automobile exhaust gases with consequent reduction or complete lead ban from motor gasoline result in octane shortage at many manufacturing sites. Attractive solutions to this problem, especially in conjunction with abundant methanol supplies, are the hydration and etherification of olefins contained in light product streams from cracking unit or produced by field gas dehydrogenation. A comparison is made between oxygenates octane-volume pool contributions and established refinery technologies. Process reviews for bulk manufacture of fuel-grade isopropanol (IPA), secondary butanol (SBA), tertiary butanol (TBA), methyl tertiary butyl ether (MTBE) and tertiary amyl methyl ether (TAME) are presented together with the characteristic investment and operating data. The implantation of these processes into a typical FCCU refinery complex with the resulting octane-pool improvement possibilities is descried.

Prezelj, M.

1987-09-01T23:59:59.000Z

75

Extraction of Plutonium into 30 Percent Tri-Butyl Phosphate from Nitric Acid Solution Containing Fluoride, Aluminum, and Boron  

SciTech Connect (OSTI)

This work consists of experimental batch extraction data for plutonium into 30 volume-percent tri-butyl phosphate at ambient temperature from such a solution matrix and a model of this data using complexation constants from the literature.

Kyser, E.A.

2000-01-06T23:59:59.000Z

76

Aerobic mineralization of MTBE and tert-butyl alcohol by stream-bed sediment microorganisms  

SciTech Connect (OSTI)

Microorganisms indigenous to the stream-bed sediments at two gasoline-contaminated groundwater sites demonstrated significant mineralization of the fuel oxygenates, methyl tert-butyl ether (MTBE) and tert-butyl alcohol (TBA). Up to 73% of [U-{sup 14}C]-MTBE and 84% of [U-{sup 14}C]-TBA were degraded to {sup 14}CO{sub 2} under mixed aerobic/anaerobic conditions. No significant mineralization was observed under strictly anaerobic conditions. The results indicate that, under the mixed aerobic/anaerobic conditions characteristic of stream-bed sediments, microbial processes may provide a significant environmental sink for MTBE and TBA delivered to surface water bodies by contaminated groundwater or by other sources.

Bradley, P.M.; Landmeyer, J.E.; Chapelle, F.H. [Geological Survey, Columbia, SC (United States)] [Geological Survey, Columbia, SC (United States)

1999-06-01T23:59:59.000Z

77

Aging of Weapon Seals An Update on Butyl O-ring Issues  

SciTech Connect (OSTI)

During testing under the Enhanced Surveillance Campaign in 2001, preliminary data detected a previously unknown and potentially serious concern with recently procured butyl o-rings on several programs. All butyl o-rings molded from a proprietary formulation throughout the period circa 1999 through 2001 had less than a full cure. Engineering judgment was that under curing is detrimental and could possibly lead to sub-optimum performance or, in the worst case, premature seal failure. An aging study was undertaken to ensure that suspect o-rings installed in the stockpile will retain sufficient sealing force for a minimum ten-year service life. A new prediction model developed for this study indicates suspect o-rings do not need to be replaced before the ten-year service life. Long-term testing results are reported on a yearly basis to validate the prediction model. This report documents the aging results for the period September 2002 to January 2011.

Wilson, Mark H.

2011-07-13T23:59:59.000Z

78

Multiple steady states during reactive distillation of methyl tert-butyl ether  

SciTech Connect (OSTI)

This paper presents results of computer simulations of the synthesis of methyl tert-butyl ether (MTBE) in a fixed-bed reactor and in a reactive distillation column. These calculations clearly showed the advantages of MTBE synthesis in a catalytic distillation tower. Furthermore, the computer simulations showed that multiple steady states may occur in the reactive distillation column during MTBE synthesis in a broad range of operating conditions. An analysis of some sensitivity studies is presented.

Nijhuis, S.A. (Univ. of Amsterdam (Netherlands). Chemical Engineering Dept.); Kerkhof, F.P.J.M.; Mak, A.N.S. (Comprimo Engineers and Contractors, Amsterdam (Netherlands))

1993-11-01T23:59:59.000Z

79

Batch polymerization of styrene initiated by n-butyl lithium in a cyclohexane solvent  

E-Print Network [OSTI]

anionic mechanism. A mathematical model is de- veloped and the predicted values are compared with their corresponding experimental values. Initiator and monomer concentrations are varied and their conversion time profiles are studied. A G&el... and Storage Vessels Purification of Monomer Purification of Solvent Polymerization Reaction Scavenger Level Analysis o f Butyl Lithium Analysis of Molecular Weight Distributions by the Use of Gel Permeation Technique 10 19 19 ZO Zl ZZ 24 25 25...

Landon, Thomas Rodman

1971-01-01T23:59:59.000Z

80

E-Print Network 3.0 - academic tertiary care Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Rochester, Rochester, New York 14627 (Received 1 April 1996) Tertiary protons with birth... targets, such as those planned for the National Ignition Facility. Measurement of...

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Early Tertiary subsidence and sedimentary facies - northern Sirte Basin, Libya  

SciTech Connect (OSTI)

The subsidence curves and subsidence rate curves for the Sirte basin, constructed from the stratigraphic record, show that subsidence was continuous throughout Late Cretaceous and Tertiary times, reaching a maximum during the Paleocene and Eocene, when a major reactivation of faults occurred. Shales and carbonates were deposited during all of the Late Cretaceous and Tertiary. Abrupt lateral facies changes occur from the platform areas toward the deeper troughs along with steep downdip thickening. These conditions were probably assisted by contemporaneous faulting along structurally weak hinge lines where the dominant structural elements are normal step faults. The absence of upper Paleozoic and lower Mesozoic sediments suggests that the area was domed, faulted, and eroded during the late Mesozoic. As a result of crustal extension during the Paleocene, a marked lithologic and structural change occurred. The Heira Shale succeeded the Kalash Limestone in the Marada trough. Reactivation of the earlier faults, accompanied by an increase in the sediment supply from the south, caused these lower Paleocene shales to cover the entire area, with the exception of the old highs where carbonate deposition continued. An intercalation of shales and carbonates provides a sensitive indicator of change of depth and sediment type.

Gumati, Y.D.; Kanes, W.H.

1985-01-01T23:59:59.000Z

82

Early Tertiary subsidence and sedimentary facies - Northern Sirte Basin, Libya  

SciTech Connect (OSTI)

The subsidence curves and subsidence rate curves for the Sirte basin, constructed from the stratigraphic record, show that subsidence was continuous throughout Late Cretaceous and Tertiary times, reaching a maximum during the Paleocene and Eocene, when a major reactivation of faults occurred. Shales and carbonates were deposited during all of the Late Cretaceous and Tertiary. Abrupt lateral facies changes occur from the platform areas toward the deeper troughs along with steep downdip thickening. The absence of upper Paleozoic and lower Mesozoic sediments suggests that the area was domed, faulted, and eroded during the late Mesozoic. As a result of crustal extension during the Paleocene, a marked lithologic and structural change occurred. The Heira Shale succeeded the Kalash Limestone in the Marada trough. Reactivation of the earlier faults, accompanied by an increase in the sediment supply from the south, caused these lower Paleocene shales to cover the entire area, with the exception of the old highs where carbonate deposition continued. An intercalation of shales and carbonates provides a sensitive indicator of change of depth and sediment type. 14 figures.

Gumati, Y.D.; Kanes, W.H.

1985-12-01T23:59:59.000Z

83

Batch polymerization of styrene and isoprene by n-butyl lithium initiator  

E-Print Network [OSTI]

-20). Analysis of products consists of determining the point at which no free lithium alkyl remains. Thus if a butyl lithium initiated polymerization were terminated with water, butane would be evolved as long as the initiator were present. The butane...? agent were evaporated under a hood. Finally the polymer. was dried in a vacuum oven at about 50'C and under a vacuum of 30 inches of gg for about 30 hours. The weight of polymer formed was determined by final weighing. 25 The monomer conversion...

Hasan, Sayeed

1970-01-01T23:59:59.000Z

84

A kinetic investigation of the reaction of dibutyl sodiophosphonate with n-butyl bromide  

E-Print Network [OSTI]

of Texn~ in partial fulfillment of the requirements for the de ree of MASTER OF SCIENCE August 1955 Major Subject: Chemistry A KINETIC INVESTIGATION OF THE REACTION OF DIBUTYL SODIOPHOSPHONATE WITH N-BUTYL BROMIDE A Thesis By James Howard Shaffer... Concentrations o " Reactants and Calculated Second Order Specific Reaction pa, ". ;e Rate Constants Table 1, 40 C Table 2, 50 0 Table 3, BO C 3c II. Initial Concentrations of React iit : ?d Apparent Rate Constants of Erofosed Die er 1!echani sm Table 4...

Shaffer, James Howard

1955-01-01T23:59:59.000Z

85

Measurement of methyl-tert-butyl-ether (MTBE) in raw drinking water  

SciTech Connect (OSTI)

In order to assess the pathways for human exposure to methyl-tert-butyl-ether (MTBE) and to understand the extent of MTBE contamination in watersheds, a purge and trap gas chromatographic mass spectrometric method to measure part-per-trillion (ppt) concentrations of MTBE in environmental waters was developed. A variety of California's raw drinking waters were analyzed. No detectable MTBE was found in deep groundwater (>1000 feet). However shallow groundwater ({approx}250 feet) contained MTBE concentrations of non-detect to 1300 ppt. MTBE concentrations measured in rivers and lakes ranged from non-detect to 3500 ppt. East (San Francisco) Bay area rain water contained approximately 80 ppt MTBE.

Davisson, M L; Koester, C J; Moran, J E

1999-10-14T23:59:59.000Z

86

The identification of recurrent tertiary motifs by interactions of protein secondary structure units  

E-Print Network [OSTI]

. Through an informatics analysis of recurrent tertiary contacts, we have derived a database of recurrent tertiary motifs. A group of 691 high-resolution, non-redundant protein structures was obtained. For each protein in this source data, we found all...

Hodges, Hamilton Courtney

2013-02-22T23:59:59.000Z

87

A SUMMARY OF TERTIARY COAL RESOURCES OF THE WIND RIVER BASIN, WYOMING  

E-Print Network [OSTI]

and C. W. Keighin in U.S. Geological Survey Professional Paper 1625-A 1999 Resource assessment Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great member of the Fort Union Formation. 1999 Resource assessment of selected Tertiary coal beds and zones

88

Review of the environmental behavior and fate of methyl tert-butyl ether  

SciTech Connect (OSTI)

A review of pertinent equations and current research indicates that when gasoline oxygenated with methyl tert-butyl ether (MTBE) comes into contact with water, large amounts of MTBe can dissolve. At 25 C, the water solubility of MTBE is about 5,000 mg/L for a gasoline that is 10% MTBE by weight, whereas for a nonoxygenated gasoline, the total hydrocarbon solubility in water is typically about 120 mg/L. Methyl tert-butyl ether sorbs only weakly to subsurface solids; therefore, sorption does not substantially retard the transport of MTBE by ground water. In addition, MTBE generally resists biodegradation in ground water. The half-life of MTBE in the atmosphere can be as short as 3 d in a regional airshed. In the air, MTBE tends to partition into atmospheric water, including precipitation. However, the washing out of gas-phase MTBE by precipitation will not, by itself, greatly alter the gas-phase concentration of the compound in the air. The partitioning of MTBE to precipitation can nevertheless result in concentrations as high as 3 {micro}g/L or more in urban precipitation and can contribute to the presence of MTBE in surface and ground water.

Squillace, P.J.; Zogorski, J.S. [Geological Survey, Rapid City, SD (United States); Pankow, J.F. [Oregon Graduate Inst. of Science and Technology, Beaverton, OR (United States). Dept. of Environmental Science and Engineering; Korte, N.E. [Oak Ridge National Lab., TN (United States). Environmental Science Div.

1997-09-01T23:59:59.000Z

89

Photoionization of methyl t-butyl ether (MTBE) and t-octyl methyl ether (TOME) and analysis of their pyrolyses by  

E-Print Network [OSTI]

Photoionization of methyl t-butyl ether (MTBE) and t-octyl methyl ether (TOME) and analysis 1999; accepted 20 July 1999 Abstract The pyrolysis products of neutral methyl-d3 t-butyl ether (MTBE-d3 from thermal cracking patterns. MTBE and TOME both exhibit base peaks at m/z 73 (which shifts to m/z 76

Morton, Thomas Hellman

90

Water quality for secondary and tertiary oil recovery  

SciTech Connect (OSTI)

A key element in many secondary and tertiary oil recovery processes is the injection of water into an oil-bearing formation. Water is the fluid which displaces the oil in the pore space of the rock. A successful waterflood requires more than the availability of water and the pumps and piping to inject the water into the formation. It requires an understanding of how water enters the oil bearing formation and what happens once the injected water comes into contact with the rock or sand, the oil, and the water already in the reservoir. Problems in injectivity will arise unless care and constant monitoring are exercised in the water system for a flood operation. This study examines water availability and quality in relation to waterflooding.

Michnick, M.J.

1983-01-01T23:59:59.000Z

91

Taming Plasma Fusion Snakes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatus TomAboutManus Site-Inactive TWPCarbonTake aTalent

92

Treatment of methyl t-butyl ether contaminated water using a dense medium plasma reactor, a mechanistic and kinetic investigation  

E-Print Network [OSTI]

and oxidation mechanisms of methyl t-butyl ether (MTBE) in a dense medium plasma (DMP) reactor utilizing gas for the removal of MTBE from an aqueous solution in the DMP reactor. Rate constants are also derived for three reactor configurations and two pin array spin rates. The oxidation products from the treatment of MTBE

Dandy, David

93

Tests for mutagenic effects of ammoniated glycyrrhizin, butylated hydroxytoluene, and gum arabic in roden germ cells  

SciTech Connect (OSTI)

Ammoniated glycyrrhizin, butylated hydroxytoluene, and gum Arabic are generally recognized as safe (GRAS) substances that are used primarily as additives in foods. These substances were incorporated into rodent diets and fed to male rats and mice for 10 and 8 wk, respectively. The treated male mice and rats were then tested for dominant lethal effects. The mice were also tested for induced heritable translocation. Results of the rat studies indicated a statistically significant dominant lethal effect of each of the compounds tested; however, the biological significance of this response is not known. Results of the mouse dominant lethal and heritable translocation studies, on the other hand, indicated no adverse effects of the compounds tested.

Sheu, C.W.; Cain, K.T.; Rushbrook, C.J.; Jorgenson, T.A.; Generoso, W.M.

1986-01-01T23:59:59.000Z

94

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction  

SciTech Connect (OSTI)

In a review of the safety basis for solvent extraction processes at the Department of Energy's Savannah River Site, a question was raised concerning the safety margin associated with a postulated accident involving a runaway tri-n-butyl phosphate (TBP)/nitric acid reaction due to the inadvertent heating of a tank. The safety margin was based on studies which showed the maximum temperature would not exceed 128 degrees Celsius compared to 130 degrees Celsius, the minimum initiation temperature for runaway reaction established in the 1950's following damaging incidents at the Savannah River and Hanford Sites. The reviewers were concerned the minimum temperature was not conservative since data for solutions containing 20 wt percent dissolved solids showed initiation temperatures at or below 130 degrees Celsius and process solutions normally contain some dissolved solids.

Rudisill, T.S.

2001-09-14T23:59:59.000Z

95

A thermodynamic model of nitric acid extraction by tri-n-butyl phosphate  

SciTech Connect (OSTI)

A thermodynamic model is presented for nitric acid extraction by tri-n-butyl phosphate (TBP). This model is based on the formation of the organic phase species: TBP.HNO/sub 3/ and (TBP)/sub 2/.HNO/sub 3/. The model works successfully at TBP concentrations of 5 to 100 vol% and was found to be effective at predicting the extraction of HNO/sub 3/ from HNO/sub 3//NaNO/sub 3/ and HNO/sub 3//LiNO/sub 3/ solutions. Within the TBP concentration range of 5 to 30%, a single set of extraction constants was sufficient to fit extraction data. Stoichiometric activity coefficients of nitric acid in HNO/sub 3//NaNO/sub 3/ and HNO/sub 3//LiNO/sub 3/ mixtures were calculated using a model developed by Bromley.

Chaiko, D.J.; Vandegrift, G.F.

1988-07-01T23:59:59.000Z

96

Green polymer electrolytes based on chitosan and 1-butyl-3-methylimidazolium acetate  

SciTech Connect (OSTI)

Green polymer electrolytes based on chitosan as the polymer matrix and ionic liquid 1-butyl-3-methylimidazolium acetate [Bmim][OAc] as charge carriers were prepared by solution casting technique. Complexes with various amount of ionic liquid loading were investigated as possible ionic conducting polymers. The ionic conductivity was found to increase with increasing weight percent of ionic liquid. The highest ionic conductivity of the charged chitosan-[Bmim][OAc] was 2.44 10{sup ?3} S cm{sup ?1} at 90 wt.% of [Bmim][OAc] content at ambient temperature. Attenuated Total Reflection Fourier Transform infrared (ATR-FTIR) spectroscopy has proven the interaction between chitosan and [Bmim][OAc]. X-ray Diffraction (XRD) has shown that the amorphosity of the complexes increase as the amount of [Bmim][OAc] increase.

Shamsudin, Intan Juliana [Chemistry Department, Centre for Defence Foundation Studies, National Defence University of Malaysia, 57000 Kuala Lumpur (Malaysia); Ahmad, Azizan; Hassan, Nur Hasyareeda [School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600, Bangi, Selangor Darul Ehsan (Malaysia)

2014-09-03T23:59:59.000Z

97

Why methyl tert-butyl ether production by reactive distillation may yield multiple solutions  

SciTech Connect (OSTI)

This paper presents an explanation of why methyl tert-butyl ether (MTBE) production by reactive distillation may yield multiple solutions. Widely different composition profiles and conversions may, as already reported by Krishna and others, results with identical column specifications, depending on the initial estimates provided. A hypothesis yielding a qualitative understanding of this phenomenon has been developed. The inert n-butene plays a key role in the proposed explanation: As the reaction mixture is diluted with n-butene, the activity coefficient of methanol increases substantially and the temperature decreases. This dilution has a profound effect on the equilibrium conversion, enabling MTBE to escape from the reactive zone without decomposition. When methanol is fed below or in the lower part of the reactive zone of the column, the ``lifting capacity`` of the minimum boiling point MTBE-methanol azeotrope will also be important.

Hauan, S.; Hertzberg, T.; Lien, K.M. [Univ. of Trondheim (Norway)

1995-03-01T23:59:59.000Z

98

A SUMMARY OF TERTIARY COAL RESOURCES OF THE RATON BASIN, COLORADO AND NEW MEXICO  

E-Print Network [OSTI]

............................................................................................................SR-13 Coal-bed Methane and potential coal-bed methane production in Raton Basin. Adapted from Hemborg (1996). 1999 RChapter SR A SUMMARY OF TERTIARY COAL RESOURCES OF THE RATON BASIN, COLORADO AND NEW MEXICO By R

99

Concentrating aqueous volatile fatty acid salt solutions using a tertiary amine mixture  

E-Print Network [OSTI]

Lee (1993) has shown that tertiary amines are able to hics. extract water from low-concentration calcium acetate and sodium acetate solutions. This thesis extends the previous work to include calcium propionate and butyrate. Amine extraction may...

Gaskin, David J

1997-01-01T23:59:59.000Z

100

West Hackberry Tertiary Project. Annual report, September 3, 1997--September 2, 1998  

SciTech Connect (OSTI)

The following report is the Project Management Plan for the fifth year of the West Hackberry Tertiary Project. The West Hackberry Tertiary Project is one of four mid-term projects selected by the United States Department of Energy (DOE) as part of the DOE`s Class 1 Program for the development of advance recovery technologies in fluvial dominated deltaic reservoirs. The West Hackberry Tertiary Project is a field test of the idea that air injection can be combined with the Double Displacement Process to produce a low cost tertiary recovery process which is economic at current oil prices. The Double Displacement Process is the gas displacement of a water invaded oil column for the purpose of recovering tertiary oil by gravity drainage. The Double Displacement Process is based upon the concept that in fields such as West Hackberry waterdrive recoveries are typically 50%-60% of the original oil in place while gravity drainage recoveries average 80%-90% of the original oil in place. Therefore, by injecting a gas into a watered out reservoir, a gas cap will form an additional oil can be recovered due to gravity drainage. Although the Double Displacement Process has been shown to be successful in recovering tertiary oil in other fields, this project will be the first to utilize air injection in the Double Displacement Process. The use of air injection in this process combines the benefits of air`s low cost and universal accessibility with the potential for accelerated oil recovery due to the combustion process. If successful, this project will demonstrate that the use of air injection in the Double Displacement Process will result in an economically viable tertiary process in reservoirs where tertiary oil recovery is presently uneconomical.

Gillham, T.H.

1997-09-10T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Petrological comparison of some tertiary and quaternary sands from Brazos and adjourning counties, Texas  

E-Print Network [OSTI]

//ipyramids of quartz in the Catahoula sands differ- / / entiates them from P ~ternary sands. The Claiborne sands contain much , , ' / muscovite. Volcarj g glass is common in the Jackson sends. / Angular-s+' gular roundness ratios vary for both Tertiary... and / / / Quaternary sar g. Occasional angular-subangular ratio va1ues in excess / / of 2. 00 are saracteristic of the Quaternary sands. / / Glaua' gite is more common in Tertiary than in Quaternary sands. / / / Add' Lional petrological studies of the clay...

Elsik, William Clinton

1960-01-01T23:59:59.000Z

102

A review of Tertiary climate changes in southern South America and the Antarctic Peninsula. Part 1: Oceanic conditions .  

E-Print Network [OSTI]

??Oceanic conditions around southern South America and the Antarctic Peninsula have a major influence on climate patterns in these subcontinents. During the Tertiary, changes in (more)

Le Roux, J. P.

2012-01-01T23:59:59.000Z

103

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction  

SciTech Connect (OSTI)

During a review of the H-Canyon authorization basis, Defense Nuclear Facility Safety Board (DNFSB) staff members questioned the margin of safety associated with a postulated tri-n-butyl phosphate (TBP)/nitric acid runaway reaction due to the inadvertent heating of a canyon tank containing greater than 3000 lbs (1362 kg) of TBP. The margin of safety was partially based on experiments and calculations performed by the Actinide Technology Section (ATS) to support deletion of indication of tank agitation as a Safety Class System. In the technical basis for deletion of this system, ATS personnel conservatively calculated the equilibrium temperature distribution of a canyon tank containing TBP and nitric acid layers which were inadvertently heated by a steam jet left on following a transfer. The maximum calculated temperature (128 degrees C) was compared to the minimum initiation temperature for a runaway reaction (greater than 130 degrees C) documented by experimental work in the mid 195 0s. In this work, the initiation temperature as a function of nitric acid concentration was measured for 0 and 20 wt percent dissolved solids. The DNFSB staff members were concerned that data for 0 wt percent dissolved solids were not conservative given the facts that data for 20 wt percent dissolved solids show initiation temperatures at or below 130 degrees C and H-Canyon solutions normally contained a small amount of dissolved solids.

Rudisill, T.S.

2000-11-28T23:59:59.000Z

104

Thorium ions transport across Tri-n-butyl phosphate-benzene based supported liquid membranes  

SciTech Connect (OSTI)

Transport of Th(IV) ions across tri-n-butyl phosphate (TBP) benzene based liquid membranes supported in microporous hydrophobic polypropylene film (MHPF) has been studied. Various parameters such as variation of nitric acid concentration in the feed, TBP concentration in the membrane, and temperature on the given metal ions transport have been investigated. The effects of nitric acid and TBP concentrations on the distribution coefficient were also studied, and the data obtained were used to determine the Th ions-TBP complex diffusion coefficient in the membrane. Permeability coefficients of Th(IV) ions were also determined as a function of the TBP and nitric acid concentrations. The optimal conditions for the transport of Th(IV) ions across the membrane are 6 mol{sm_bullet}dm{sup -3} HNO{sub 3} concentration, 2.188 mol {center_dot} dm{sup -3} TBP concentration, and 25{degrees}C. The stoichiometry of the chemical species involved in chemical reaction during the transport of Th(IV) ions has also been studied.

Rasul, G.; Chaudry, M.A. [Pakistan Institute of Nuclear Chemistry, Islamabad (Pakistan); Afzal, M. [Quaid-I-Azam Univ., Islamabad (Pakistan)

1995-12-01T23:59:59.000Z

105

Exposure to methyl tert-butyl ether and benzene among service station attendants and operators  

SciTech Connect (OSTI)

Concerns for atmospheric pollution from auto exhaust have led to the blending of {open_quotes}oxygenates{close_quotes} with motor fuels. The most common oxygenate, methyl tert-butyl ether (MTBE) is currently required within several metropolitan areas (Denver and Phoenix) in the range of 12% of the motor fuel. Amendments to the Clean Air Act may expand this requirement to as many as 44 other areas of the United States in the near future. In consideration of the magnitude of potential uncontrolled exposures from its extensive use and a related concern involving the potential influence of MTBE blending on exposures to other constituents of gasoline (particularly benzene), an evaluation of exposures among service station attendants and operators was undertaken at the request, and in cooperation with, the American Petroleum Institute during the latter part of 1990. For application of the survey results to a broad audience, three categories or types of service stations were identified with regard to MTBE use and exposure potential: (a) service stations that do not use MTBE or use it only as an octane enhancer, (b) service stations with seasonal requirements to use 12-15% MTBE (the Denver, Colorado, and Phoenix, Arizona, metropolitan areas), and (c) service stations equipped with stage II (active) vapor recovery systems (several coastal areas, most notably Southern California). 4 refs., 4 tabs.

Hartle, R. [National Inst. for Occupational Safety and Health, Cincinnati, OH (United States)

1993-12-01T23:59:59.000Z

106

Reaction calorimetry study of the liquid-phase synthesis of tert-butyl methyl ether  

SciTech Connect (OSTI)

The liquid-phase addition of methanol to isobutene to give tert-butyl methyl ether (MTBE) on the ion-exchange resin Lewatit K2631 has been studied in a calorimetric reactor. Heat capacity of MTBE and enthalpy of the MTBE synthesis reaction in the temperature range 312--333 K have been determined. MTBE heat capacity in the liquid phase has been found to obey the equation c[sub P] (J/mol[center dot]K) = 472.34 [minus] 2.468(T/K) + 0.005071(T/K)[sup 2]. At 298 K the standard molar reaction enthalpy is [Delta]H[degree] = [minus]33.8 kJ/mol. A method to estimate apparent activation energies from heat flow rate in a given reaction has been developed and proved to be valid for the MTBE synthesis. Using this method, an apparent activation energy of 91.1--95.2 kJ/mol is calculated. A [minus]3.8 kJ/mol value has been found for the adsorption enthalpy of methanol on the ion-exchange resin Lewatit K2631 by a combination of reaction calorimetry and thermogravimetry. This allows the calculation of an activation energy on the gel phase of the resin of 91 kJ/mol.

Sola, L.; Pericas, M.A.; Cunill, F.; Iborra, M. (Univ. de Barcelona (Spain). Dept. d'Enginyeria Quimica)

1994-11-01T23:59:59.000Z

107

Observation on the biodegradation and bioremediation potential of methyl t-butyl ether  

SciTech Connect (OSTI)

There have been few reports documenting evidence for the biodegradation of the fuel oxygenate alkyl ether, methyl t-butyl ether (MTBE) in groundwater, soils, and biosludges. Partial (or complete) microbial breakdown of MTBE has been observed in an anaerobic subsoil, a river sediment under methanogenic conditions, a cyclohexane-degrading bacterial consortium and a pure culture of the methylotroph, Methylisnus trichosporium OB3b. An aerobic bacterial enrichment (BC-1) isolated from an industrial transient (non-accumulating) metabolic intermediate. The studies suggest that MTBE is cleaved by BC-1 to TBA which is then metabolized via isopropanol and acetone. There is little information on the occurrence of indigenous MTBE-degraders in groundwater, soils and activated sludges. Preliminary evidence has been obtained, however, from a marketing terminal groundwater site that naturally-occurring MTBE-degraders are present in some monitoring wells. Microcosm experiments with groundwater from this aquifer show that MTBE is aerobically degraded (no TBA formed) with a first-order decay rate (0.31/day) similar to BTEX. Also, MTBE did not inhibit the intrinsic biodegradation potential of BTEX in groundwater microcosms. In summary, the data presented indicate that MTBE biodegradation has been observed in some environmental media. Further work is needed to assess the feasibility of using indigenous or derived aerobic and anaerobic MTBE-degrading cultures for treating fuel ethers in groundwaters or wastewater with in-situ or ex-situ bioremediation technologies.

Salanitro, J.; Wisniewski, H.; McAllister, P. [Shell Development Co., Houston, TX (United States)

1995-12-31T23:59:59.000Z

108

Health risks associated with exposure to gasoline additives-methyl tertiary butyl ether [MTBE]. Hearing before a Subcommittee of the Committee on Appropriations, United States Senate, One Hundred Third Congress, First Session, Special Hearing  

SciTech Connect (OSTI)

This hearing focuses on an Alaskan study by the Centers for Disease Control which examines possible health risks associated with exposure to gasoline additive know as MTBE. Testimony is given by Dr. William Roper, Director, CDC.

Not Available

1993-01-01T23:59:59.000Z

109

LIDEM unit for the production of methyl tert-butyl ether from butanes  

SciTech Connect (OSTI)

One of the basic problems in the production of motor fuels is how to obtain high-octane unleaded gasolines that will meet today`s ecological requirements. The term {open_quotes}reformulated gasolines{close_quotes} has come into general use throughout the world to denote fuels with a certain chemical composition. These gasolines consist of preselected components; as shown by worldwide experience, they must include oxygen-containing compounds that are distinguished by high octane numbers and low reactivities. Standards in effect in the United States, Japan, and certain Western European countries require that automotive gasolines must contain at least 2-4% by weight of oxygen-containing compounds (calculated as oxygen). In the last 15 years, in order to meet these requirements, production has been set up in various countries for the manufacture of high-octane oxygen-containing components known as oxygenates. The most common of these is methyl tert-butyl ether (MTBE), obtained by etherification of isobutene by methanol. Process technology developed by this last organization was used as the basis for constructing a unit in the Nizhnekamskneftekhim Production Association and at the Mazheikyai Petroleum Refinery in Lithuania. MTBE production has been held back mainly by a shortage of isobutene, which is obtained mainly from butane-butene cuts produced in cat crackers. In order to alleviate this shortage, it has been proposed that MTBE should be obtained from saturated C{sub 4} hydrocarbons that are recovered in processing oilfield associated gas, and also in the refinery from primary distillation units, catalytic reformers, and hydrocrackers. A working design was developed in 1991-1992 by Lengiproneftekhim for a basically new combination unit designed for the processing of saturated C{sub 4} hydrocarbons, which has been termed the LIDEM unit (Leningrad - isomerization - dehydrogenation - MTBE).

Rudin, M.G.; Zadvornov, M.A.

1994-09-01T23:59:59.000Z

110

Biodegradation of methyl tert-butyl ether by a bacterial pure culture  

SciTech Connect (OSTI)

A bacterial strain, PM1, which is able to utilize methyl tert-butyl ether (MTBE) as its sole carbon and energy source, was isolated from a mixed microbial consortium in a compost biofilter capable of degrading MTBE. Initial linear rates of MTBE degradation by 2 x 10{sup 6} cells ml{sup {minus}1} were 0.07, 1.17, and 3.56 {mu}g ml{sup {minus}1} h{sup {minus}1} for initial concentrations of 5, 50, and 500 {mu}g MTBE ml{sup {minus}1}, respectively. When incubated with 20 {mu}g of uniformly labeled [{sup 14}C]MTBE ml{sup {minus}1}, strain PM1 converted 46% to {sup 14}CO{sub 2} and 19% to {sup 14}C-labeled cells within 120 h. This yield is consistent with the measurement of protein accumulation at different MTBE concentrations from which was estimated a biomass yield of 0.18 of cells mg MTBE{sup {minus}1}. Strain PM1 was inoculated into sediment core material collected from a contaminated groundwater plume at Port Hueneme, California, in which there was no evidence of MTBE degradation. Strain PM1 readily degraded 20 {micro}g of MTBE ml{sup {minus}1} added to the core material. The rate of MTBE removal increased with additional inputs of 20 {micro}g of MTBE ml{sup {minus}1}. These results suggest that PM1 has potential for use in the remediation of MTBE-contaminated environments.

Hanson, J.R.; Ackerman, C.E.; Scow, K.M.

1999-11-01T23:59:59.000Z

111

The Cretaceous/ Tertiary boundary: sedimentology and micropalaeontology at El Mulato section, NE Mexico  

E-Print Network [OSTI]

The Cretaceous/ Tertiary boundary: sedimentology and micropalaeontology at El Mulato section, NE and sedimentological analysis of this transition at the El Mulato section (NE Mexico), in order to infer the little Palaeogene Velasco Formation, there is a 2-m-thick Clastic Unit. Strati- graphical and sedimentological ana

Royer, Dana

112

Interplay between Secondary and Tertiary Structure Formation in Protein Folding Cooperativity  

E-Print Network [OSTI]

Interplay between Secondary and Tertiary Structure Formation in Protein Folding Cooperativity¨lich, 52425 Ju¨lich, Germany Received June 14, 2010; E-mail: deserno@andrew.cmu.edu Abstract: Protein folding be difficult to measure. Therefore, protein folding cooperativity is often probed using the calorimetric

Bachmann, Michael

113

Occurrence and Implication of dissolved organic phosphorus (DOP) in tertiary wastewater Effluents Page 1 of 6  

E-Print Network [OSTI]

GU, APRIL Occurrence and Implication of dissolved organic phosphorus (DOP) in tertiary wastewater wastewater effluents L. Liu1 , D. S. Smith2 , M. Bracken3 , J.B. Neethling4 , H.D. Stensel5 and S. Murthy6 levels (e.g. TPwastewater treatment plants. A few previous studies (Benisch et al., 2007

Brody, James P.

114

An Efficient Genetic Algorithm for Predicting Protein Tertiary Structures in the 2D HP Model  

E-Print Network [OSTI]

, predicting its tertiary structure is known as the protein folding problem. This problem has been widely genetic algo- rithm for the protein folding problem under the HP model in the two-dimensional square Genetic Algorithm, Protein Folding Problem, 2D HP Model 1. INTRODUCTION Amino acids are the building

Istrail, Sorin

115

The Scientific Basis for the Regulation of Nanoparticles: Challenging Paracelsus and Pare  

E-Print Network [OSTI]

NANOTECHNOILOGY 402 (2007). 20. MTBE unquestionably causesTertiary-Butyl Ether (MTBE)-a Gasoline Additive-CausesMethyl Tertiary-butyl Ether (MTBE) in CD-I Mice and F-344

Goldstein, Bernard D.

2010-01-01T23:59:59.000Z

116

MTBE Production Economics (Released in the STEO April 2001)  

Reports and Publications (EIA)

The purpose of this analysis is to evaluate the causes of methyl tertiary butyl ether (MTBE) price increases in 2000.

2001-01-01T23:59:59.000Z

117

Vol. 83, No. 2, 2006 121 Analysis of Heat Transfer Fouling by Dry-Grind Maize Thin Stillage  

E-Print Network [OSTI]

-tertiary butyl ether (MTBE), a petroleum derivative, and ethanol. In recent years, MTBE has been phased out due

118

Play analysis and stratigraphic position of Uinta Basin tertiary - age oil and gas fields  

SciTech Connect (OSTI)

Tertiary-age sediments in the Uinta basin produce hydrocarbons from five types of plays. These play types were determined by hydrocarbon type, formation, depositional environment, rock type, porosity, permeability, source, and per-well recovery. Each well was reviewed to determine the stratigraphic position and producing characteristics of each producing interval. The five types of plays are as follows: (1) naturally fractured oil reservoirs, (2) low-permeability oil reservoirs, (3) high-permeability of oil reservoirs, (4) low-permeability gas reservoirs, and (5) tight gas sands. Several fields produce from multiple plays, which made it necessary to segregate the hydrocarbon production into several plays. The stratigraphic position of the main producing intervals is shown on a basin-wide cross section, which is color-coded by play type. This 61-well cross section has several wells from each significant Tertiary oil and gas field in the Uinta basin.

Williams, R.A. (Pennzoil Exploration and Production Co., Houston, TX (United States))

1993-08-01T23:59:59.000Z

119

Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-  

E-Print Network [OSTI]

Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

120

Successful Pregnancy with a Full-Term Vaginal Delivery One Year After n-Butyl Cyanoacrylate Embolization of a Uterine Arteriovenous Malformation  

SciTech Connect (OSTI)

Uterine arteriovenous malformation (AVM) causes significant morbidity with vaginal bleeding. Traditional therapy is a hysterectomy with no potential for future pregnancy. We present a case of successful superselective embolization of uterine AVM using n-butyl cyanoacrylate with subsequent normal term pregnancy and uncomplicated vaginal delivery in 1 year.

McCormick, Colleen C. [Johns Hopkins University School of Medicine, Department of Gynecology and Obstetrics (United States); Kim, Hyun S. [Johns Hopkins University School of Medicine, Russell H. Morgan Department of Radiology and Radiological Science (United States)], E-mail: sikhkim@jhmi.edu

2006-08-15T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

West Hackberry Tertiary Project. Quarterly technical progress report, January 1, 1996--March 31, 1996  

SciTech Connect (OSTI)

The goal of the West Hackberry Tertiary Project is to demonstrate the technical and economic feasibility of combining air injection with the Double Displacement Process for tertiary oil recovery. The Double Displacement Process is the gas displacement of a water invaded oil column for the purpose of recovering oil through gravity drainage. The novel aspect of this project is the use of air as the injection fluid. The target reservoir for the project is the Camerina C-1,2,3 sand located on the West Flank of West Hackberry Field in Cameron Parish, Louisiana. If successful, this project will demonstrate that the use of air injection in the Double Displacement Process can economically recover oil in reservoirs where tertiary oil recovery is presently uneconomic. The first quarter of 1996 was outstanding both in terms of volume of air injected and low cost operations. More air was injected during this quarter than in any preceding quarter. The compressors experienced much improved run time with minimal repairs. Low operating costs resulted from no repairs required for injection or production wells. A discussion of the following topics are contained herein: (1) performance summary for the injection and production wells, (2) air compressor operations, (3) updated bottom hole pressure data, (4) technology transfer activities and (5) plans for the upcoming quarter.

Gillham, T.; Cerveny, B.; Turek, E.

1996-04-10T23:59:59.000Z

122

Kinetics and modeling of mixture effects during complete catalytic oxidation of benzene and methyl tert-butyl ether  

SciTech Connect (OSTI)

The performance of a catalytic incinerator depends on the nature of the compounds being oxidized and cannot be predicted simply by knowing the performance of the incinerator with pure-component model compounds. Considering the importance of mixture effects, an attempt was made to develop a combined model to predict the conversion when benzene and methyl tert-butyl ether (MTBE) are simultaneously oxidized. Complete catalytic oxidation of benzene and MTBE, singly and in mixtures, was investigated over a platinum catalyst. No inhibition effects were seen with benzene, but MTBE conversion was distinctly inhibited by benzene. A Mars-van Krevelen rate model was used to explain the results. Model parameters were obtained from pure-component experiments and then incorporated into a multicomponent model without any adjustment or additional rate parameters. The multicomponent model was able to predict the conversion of benzene and MTBE oxidation in the binary mixture using the pure-component data without adjustable parameters.

Dangi, S.; Abraham, M.A. [Univ. of Tulsa, OK (United States). Dept. of Chemical Engineering] [Univ. of Tulsa, OK (United States). Dept. of Chemical Engineering

1997-06-01T23:59:59.000Z

123

Determination of Methyl tert-Butyl Ether and tert-Butyl Alcohol in Water by Solid-Phase Microextraction/Head Space Analysis in Comparison to EPA Method 5030/8260B  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) is now one of the most common groundwater contaminants in the United States. Groundwater contaminated with MTBE is also likely to be contaminated with tert-butyl alcohol (TBA), because TBA is a component of commercial grade MTBE, TBA can also be used as a fuel oxygenate, and TBA is a biodegradation product of MTBE. In California, MTBE is subject to reporting at concentrations greater than 3 {micro}g/L. TBA is classified as a ''contaminant of current interest'' and has a drinking water action level of 12 {micro}g/L. In this paper, we describe the development and optimization of a simple, automated solid phase microextraction (SPME) method for the analysis of MTBE and TBA in water and demonstrate the applicability of this method for monitoring MTBE and TBA contamination in groundwater, drinking water, and surface water. In this method, the headspace (HS) of a water sample is extracted with a carboxen/polydimethylsiloxane SPME fiber, the MTBE and TBA are desorbed into a gas chromatograph (GC), and detected using mass spectrometry (MS). The method is optimized for the routine analysis of MTBE and TBA with a level of quantitation of 0.3 {micro}g/L and 4 {micro}g/L, respectively, in water. MTBE quantitation was linear for over two orders of concentration (0.3 {micro}g/L -80 {micro}g/L). TBA was found to be linear within the range of 4 {micro}g/L-7,900 {micro}g/L. The lower level of detection for MTBE is 0.03 {micro}g/L using this method. This SPME method using headspace extraction was found to be advantageous over SPME methods requiring immersion of the fiber into the water samples, because it prolonged the life of the fiber by up to 400 sample analyses. This is the first time headspace extraction SPME has been shown to be applicable to the measurement of both MTBE and TBA at concentrations below regulatory action levels. This method was compared with the certified EPA Method 5030/8260B (purge-and-trap/GC/MS) using split samples from laboratory bioreactors treating MTBE contaminated water and applied to environmental samples collected throughout the East Bay area of California. Results from the SPME-HS/GC/MS method were directly comparable to the EPA Method 5030/8260B. This method provides an simple, inexpensive, accurate, and sensitive alternative to EPA Method 5030/8260B for the analysis of MTBE and TBA in water samples.

Oh, Keun-Chan; Stringfellow, William T.

2003-10-02T23:59:59.000Z

124

Use of ferric sulfate: acid media for the desulfurization of model compounds of coal. [Dibenzothiophene, diphenyl sulfide, di-n-butyl sulfide  

SciTech Connect (OSTI)

The objective of this work has been to investigate the ability of ferric sulfate-acid leach systems to oxidize the sulfur in model compounds of coal. Ferric iron-acid leach systems have been shown to be quite effective at removal of inorganic sulfur in coal. In this study, the oxidative effect of ferric iron in acid-leach systems was studied using dibenzothiophene, diphenyl sulfide, and di-n-butyl sulfide as models of organic sulfur groups in coal. Nitrogen and oxygen, as well as various transition metal catalysts and oxidants, were utilized in this investigation. Dibenzothiophene was found to be quite refractory to oxidation, except in the case where metavanadate was added, where it appears that 40% oxidation to sulfone could have occurred per hour at 150/sup 0/C and mild oxygen pressure. Diphenyl sulfide was selectively oxidized to sulfoxide and sulfone in an iron and oxygen system. Approximately 15% conversion to sulfone occurred per hour under these conditions. Some of the di-n-butyl sulfide was cracked to 1-butene and 1-butanethiol under similar conditions. Zinc chloride and ferric iron were used at 200/sup 0/C in an attempt to desulfonate dibenzothiophene sulfone, diphenyl sulfone, and di-n-butyl sulfone. Di-n-butyl sulfone was completely desulfurized on one hour and fragmented to oxidized parafins, while dibenzothiophene sulfone and diphenyl sulfone were unaffected. These results suggest that an iron-acid leach process could only selectively oxidize aryl sulfides under mild conditions, representing only 20% of the organic sulfur in coal (8% of the total sulfur). Removal through desulfonation once selective sulfur oxidation had occurred was only demonstrated for alkyl sulfones, with severe oxidation of the fragmented paraffins also occurring in one hour.

Clary, L.R.; Vermeulen, T.; Lynn, S.

1980-12-01T23:59:59.000Z

125

Plant observation report and evaluation, Pennwalt Corporation, secondary and tertiary aliphatic monoamines  

SciTech Connect (OSTI)

A site visit was made to the amine manufacturing facility of the Pennwalt Corporation, Wyandotte, Michigan, to evaluate the facility in regard to the Secondary and Tertiary Aliphatic Monoamines Criteria Document. A total of 21 people were directly in contact with the amine production process. Two to four of the maintenance personnel may also come in contact with the process. Maintenance workers ran the risk of exposure not only to primary, secondary and tertiary amine compounds, but also to several other chemicals being used in the process. The processes used to unload raw materials are described, along with reactor operations, decanter and recycling operations, distillation operations, product storage and shipping. Medical monitoring at the facility included chest x-ray, respiratory function tests, sight screening, urinalysis, and back x-rays. Restricted and potentially hazardous area signs were clearly posted. Employees wore hard hats and safety glasses on the job as well as gloves, rubber boots, face shields, goggles, and respirators as necessary. Emergency procedures are described, including fire protection. Sanitation and personal hygiene are discussed, along with monitoring of the workplace conditions.

Not Available

1980-08-27T23:59:59.000Z

126

Sterically controlled recyclable system. Reversible photoredox reactions between anthraquinone and hindered tertiary amines  

SciTech Connect (OSTI)

Photochemical reactions of 9,10-anthraquinone (AQ) with sterically hindered tertiary amines have been studied. The reactivity and products are strongly dependent on the structure of the tertiary amine. Irradiation of AQ in the presence of the sterically hindered amine 1,2,2,6,6-pentamethyl-4-piperidinol (3) (or 1,2,2,6,6-pentamethylpiperidine (5)) in degassed dry benzene leads chiefly to the formation of 9-hydroxy-9-[N-(2,2,6,6-tetramethyl-4-piperidinol)-methyl]anthr one (8), which is found to be metastable at room temperature under vacuum. The reaction may be thermally reversed to regenerate the starting materials. The photolysis products and thermal reversion are solvent dependent. While in dry benzene adduct 8 is the major product, in dry acetonitrile the ionic redox products AQH-and iminium cation are detected and no thermal reversal occurs. The results are explained in terms of equilibrium between a product ion pair (AQH[sup [minus

Gan, H.; Whitten, D.G. (Univ. of Rochester, NY (United States))

1993-09-08T23:59:59.000Z

127

Identification of volatile butyl rubber thermal-oxidative degradation products by cryofocusing gas chromatography/mass spectrometry (cryo-GC/MS).  

SciTech Connect (OSTI)

Chemical structure and physical properties of materials, such as polymers, can be altered as aging progresses, which may result in a material that is ineffective for its envisioned intent. Butyl rubber formulations, starting material, and additives were aged under thermal-oxidative conditions for up to 413 total days at up to 124 %C2%B0C. Samples included: two formulations developed at Kansas City Plant (KCP) (%236 and %2310), one commercially available formulation (%2321), Laxness bromobutyl 2030 starting material, and two additives (polyethylene AC-617 and Vanax MBM). The low-molecular weight volatile thermal-oxidative degradation products that collected in the headspace over the samples were preconcentrated, separated, and detected using cryofocusing gas chromatography mass spectrometry (cryo-GC/MS). The majority of identified degradation species were alkanes, alkenes, alcohols, ketones, and aldehydes. Observations for Butyl %2310 aged in an oxygen-18 enriched atmosphere (18O2) were used to verify when the source of oxygen in the applicable degradation products was from the gaseous environment rather than the polymeric mixture. For comparison purposes, Butyl %2310 was also aged under non-oxidative thermal conditions using an argon atmosphere.

Smith, Jonell Nicole; White, Michael Irvin; Bernstein, Robert; Hochrein, James Michael

2013-02-01T23:59:59.000Z

128

Kinetics and mechanism of the sonolytic destruction of methyl tert-butyl ether by ultrasonic irradiation in the presence of ozone  

SciTech Connect (OSTI)

The kinetics and mechanism of the sonolytic degradation of methyl tert-butyl ether (MTBE) have been investigated at an ultrasonic frequency of 205 kHz and power of 200 W L{sup {minus}1}. The observed first-order degradation rate constant for the loss of MTBE increased from 4.1 {times} 10{sup {minus}4} s{sup {minus}1} to 8.5 {times} 10{sup {minus}4} s{sup {minus}1} as the concentration of MTBE decreased from 1.0 to 0.01 mM. In the presence of O{sub 3}, the sonolytic rate of destruction of MTBE was accelerated substantially. The rate of MTBE sonolysis with ozone was enhanced by a factor of 1.5--3.9 depending on the initial concentration of MTBE. tert-Butyl formate, tert-butyl alcohol, methyl acetate, and acetone were found to be the primary intermediates and byproducts of the degradation reaction with yields of 8, 5, 3, and 12%, respectively. A reaction mechanism involving three parallel pathways that include the direct pyrolytic decomposition of MTBE, the direct reaction of MTBE with ozone, and the reaction of MTBE with hydroxyl radical is proposed.

Kang, J.W. [Yonsei Univ., Wonju (Korea, Republic of). Dept. of Industrial Environment and Health] [Yonsei Univ., Wonju (Korea, Republic of). Dept. of Industrial Environment and Health; Hoffmann, M.R. [California Inst. of Tech., Pasadena, CA (United States). W.M. Keck Labs.] [California Inst. of Tech., Pasadena, CA (United States). W.M. Keck Labs.

1998-10-15T23:59:59.000Z

129

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. [801Methyl tert-butyl ether  

SciTech Connect (OSTI)

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: (1) Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. (2) Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. (3) Addition of methanol to slurry phase FT synthesis making iso-olefins. During the sixth quarter we completed the construction of the slurry bubble column reactor (SBCR), conducted initial shake-down experiments in a cold-flow mode, and finalized the selection process of the acid catalysts for conversion of syngas-produced alcohols and isobutylene to MTBE (scheme 2). Tasks 3, 4, and 5 are awaiting complete implementation of the SBCR system.

Marcelin, G.

1992-06-24T23:59:59.000Z

130

Molecular Dynamics Simulations of Tri-n-butyl-phosphate/n-Dodecane Mixture: Thermophysical Properties and Molecular Structure  

SciTech Connect (OSTI)

Molecular dynamics simulations of tri-n-butyl-phosphate (TBP)/n-dodecane mixture in the liquid phase have been carried out using two recently developed TBP force field models (J. Phys. Chem. B 2012, 116, 305) in combination with the all-atom optimized potentials for liquid simulations (OPLS-AA) force field model for n-dodecane. Specifically, the electric dipole moment of TBP, mass density of the mixture, and the excess volume of mixing were computed with TBP mole fraction ranging from 0 to 1. It is found that the aforementioned force field models accurately predict the mass density of the mixture in the entire mole fraction range. Commensurate with experimental measurements, the electric dipole moment of the TBP was found to slightly increase with the mole fraction of TBP in the mixture. Also, in accord with experimental data, the excess volume of mixing is positive in the entire mole fraction range, peaking at TBP mole fraction range 0.3 0.5. Finally, a close examination of the spatial pair correlation functions between TBP molecules, and between TBP and n-dodecane molecules, revealed formation of TBP dimers through self-association at close distance, a phenomenon with ample experimental evidence.

de Almeida, Valmor F [ORNL; Cui, Shengting [ORNL; Khomami, Bamin [ORNL

2014-01-01T23:59:59.000Z

131

ORGANIC GEOCHEMISTRY, DEPOSITIONAL ENVIRONMENT AND HYDROCARBON POTENTIAL OF THE TERTIARY OIL SHALE DEPOSITS IN NW ANATOLIA, TURKEY  

E-Print Network [OSTI]

In this study, organic geochemical characteristics and depositional environ-ment of the Tertiary-aged oil shale deposits in Northwest Anatolia have been examined. Oil shales in all the studied areas are typically characterized by high hydrogen index and low oxygen index values. Beypazar?

R. Kara Glbay; S. Korkmaz

132

LOW-MASS TERTIARY COMPANIONS TO SPECTROSCOPIC BINARIES. I. COMMON PROPER MOTION SURVEY FOR WIDE COMPANIONS USING 2MASS  

SciTech Connect (OSTI)

We report the first results of a multi-epoch search for wide (separations greater than a few tens of AU), low-mass tertiary companions of a volume-limited sample of 118 known spectroscopic binaries within 30 pc of the Sun, using the Two Micron All Sky Survey Point Source Catalog and follow-up observations with the KPNO and CTIO 4 m telescopes. Note that this sample is not volume complete but volume limited, and, thus, there is incompleteness in our reported companion rates. We are sensitive to common proper motion companions with separations from roughly 200 AU to 10,000 AU ({approx}10'' {yields} {approx} 10'). From 77 sources followed-up to date, we recover 11 previously known tertiaries, 3 previously known candidate tertiaries, of which 2 are spectroscopically confirmed and 1 rejected, and 3 new candidates, of which 2 are confirmed and 1 rejected. This yields an estimated wide tertiary fraction of 19.5{sup +5.2}{sub -3.7}%. This observed fraction is consistent with predictions set out in star formation simulations where the fraction of wide, low-mass companions to spectroscopic binaries is >10%.

Allen, Peter R. [Department of Physics and Astronomy, P.O. Box 3003, Franklin and Marshall College, Lancaster, PA 17604 (United States); Burgasser, Adam J. [Department of Physics, University of California, San Diego, CA 92093 (United States); Faherty, Jacqueline K. [Department of Astrophysics, American Museum of Natural History, Central Park West at 79th Street, New York, NY 10034 (United States); Kirkpatrick, J. Davy, E-mail: peter.allen@fandm.edu [IPAC, California Institute of Technology, Pasadena, CA 91125 (United States)

2012-08-15T23:59:59.000Z

133

Recent advances in modeling the transition at the secondary and tertiary stages of creep  

SciTech Connect (OSTI)

With the use of macro- and micro-experimental techniques, the creep mechanisms of the WIPP rock salt have been investigated under simple loading paths with an emphasis on the transition between the secondary and tertiary stages of creep. It appears that the essential feature of the transition is characterized by the evolution of localized creep damage that is manifested by the formation and propagation of a material boundary between localized and non-localized deformation fields. Based on an energy point of view, a partitioned-modeling approach has been proposed to predict localized creep damage. To establish a sound mathematical foundation for the proposed procedure, a set of moving jump forms of conservation laws have been used to define the moving boundary, and analytical solutions have been obtained for one-dimensional problems. Based on the lessons learnt from the previous work, this presentation discusses recent experimental and theoretical results on modeling the transition between the secondary and tertiary stages of rock salt creep. Since the transition involves the change from a continuous failure mode into a discontinuous failure mode, a reliable experimental procedure must be developed to obtain quantitative data of satisfactory quality. Especially, the determination of an appropriate load level is non-trivial to get a group of consistent data within the limitation of experimental instruments, because of the random defects of the rock salt obtained from the WIPP site. And also, a simple modeling approach, which catches the essential physical mechanisms of the transition, must be formulated for engineering applications. Keeping these facts in mind, a combined experimental and theoretical effort is being made, with a strain-based partitioned procedure. The preliminary results look quite promising. To illustrate the proposed procedure, both experimental data and model predictions will be given for uniaxial and triaxial compression problems.

Chen, Z.; Wang, M.L.; Lu, T. [Univ. of New Mexico, Albuquerque, NM (United States)

1995-12-31T23:59:59.000Z

134

Whole-genorne analysis of the methyl tert-butyl ether-degrading beta-proteobacterium Methylibium petroleiphilum PM1  

SciTech Connect (OSTI)

Methylibium petroleiphilum PM1 is a methylotroph distinguished by its ability to completely metabolize the fuel oxygenate methyl tert-butyl ether (MTBE). Strain PM1 also degrades aromatic (benzene, toluene, and xylene) and straight-chain (C, to C,,) hydrocarbons present in petroleum products. Whole-genome analysis of PM1 revealed an similar to 4-Mb circular chromosome and an similar to 600-kb megaplasmid, containing 3,831 and 646 genes, respectively. Aromatic hydrocarbon and alkane degradation, metal resistance, and methylotrophy are encoded on the chromosome. The megaplasmid contains an unusual t-RNA island, numerous insertion sequences, and large repeated elements, including a 40-kb region also present on the chromosome and a 29-kb tandem repeat encoding phosphonate transport and cobalamin biosynthesis. The megaplasmid also codes for alkane degradation and was shown to play an essential role in MTBE degradation through plasmid-curing experiments. Discrepancies between the insertion sequence element distribution patterns, the distributions of best BLASTP hits among major phylogenetic groups, and the G+C contents of the chromosome (69.2%) and plasmid (66%), together with comparative genome hybridization experiments, suggest that the plasmid was recently acquired and apparently carries the genetic information responsible for PM1's ability to degrade MTBE. Comparative genomic hybridization analysis with two PM1-like MTBE-degrading environmental isolates (similar to 99% identical 16S rRNA gene sequences) showed that the plasmid was highly conserved (ca. 99% identical), whereas the chromosomes were too diverse to conduct resequencing analysis. PM1's genome sequence provides a foundation for investigating MTBE biodegradation and exploring the genetic regulation of multiple biodegradation pathways in M. petroleiphilum and other MTBE-degrading beta-proteobacteria.

Kane, Staci R. [Lawrence Livermore National Laboratory (LLNL); Chakicherla, Anu Y. [Lawrence Livermore National Laboratory (LLNL); Chain, Patrick S. G. [Lawrence Livermore National Laboratory (LLNL); Schmidt, Radomir [University of California, Davis; Shin, M [U.S. Department of Energy, Joint Genome Institute; Legler, Tina C. [Lawrence Livermore National Laboratory (LLNL); Scow, Kate M. [University of California, Davis; Larimer, Frank W [ORNL; Lucas, Susan [Joint Genome Institute, Walnut Creek, California; Richardson, P M [U.S. Department of Energy, Joint Genome Institute; Hristova, Krassimira R. [University of California, Davis

2007-03-01T23:59:59.000Z

135

Exposure to methyl tert-butyl ether, benzene, and total hydrocarbons at the Singapore-Malaysia causeway immigration checkpoint  

SciTech Connect (OSTI)

The primary aim of this study was to determine the extent and levels of exposure to volatile organic compounds (VOCs) from automobile emissions in a group of immigration officers at a busy cross-border checkpoint. A majority (80%) of the workers monitored were exposed to benzene at levels between 0.01 and 0.5 ppm, with only 1.2% exceeding the current Occupational Safety and Health Administration occupational exposure limit of 1 ppm. The geometric mean (GM) concentrations of 8-hr time-weighted average exposure were 0.03 ppm, 0.9 ppm, and 2.46 ppm for methyl-tert-butyl ether (MTBE), benzene, and total hydrocarbons (THC), respectively. The highest time-weighted average concentrations measured were 1.05 ppm for MTBE, 2.01 ppm for benzene, and 34 ppm for THC. It was found that motorbikes emitted a more significant amount of pollutants compared with motor cars. On average, officers at the motorcycle booths were exposed to four to five times higher levels of VOCs (GMs of 0.07 ppm, 0.23 ppm, and 4.7 ppm for MTBE, benzene, and THC) than their counterparts at the motor car booths (GMs of 0.01 ppm, 0.05 ppm, and 1.5 ppm). The airborne concentrations of all three pollutants correlated with the flow of vehicle traffic. Close correlations were also noted for the concentrations in ambient air for the three pollutants measured. Benzene and MTBE had a correlation coefficient of 0.97. The overall findings showed that the concentrations of various VOCs were closely related to the traffic density, suggesting that they were from a common source, such as exhaust emissions from the vehicles. The results also indicated that although benzene, MTBE, and THC are known to be volatile, a significant amount could still be detected in the ambient environment, thus contributing to our exposure to these compounds. 4 refs., 6 figs.

Tan, C.; Ong, H.Y.; Kok, P.W. [and others

1996-12-31T23:59:59.000Z

136

Solvent Extraction Behavior of Neptunium (IV) Ions between Nitric Acid and Diluted 30% Tri-butyl Phosphate in the Presence of Simple Hydroxamic Acids  

SciTech Connect (OSTI)

Formo- and aceto-hydroxamic acids are very effective reagents for stripping tetravalent actinide ions such as Np(IV) and Pu(IV) ions from a tri-butyl phosphate phase into nitric acid. Distribution data for Np(IV) in the presence of these hydroxamate ions have now been accumulated and trends established. Stability constants for aceto-hydroxamate complexes of Np(IV) and Np(V) ions have also been determined in a perchlorate medium, and these reaffirm the affinity of hydroxamate ligands for actinide (IV) ions over actinyl (V,VI) ions.

Taylor, Robin J.; Sinkov, Sergey I.; Choppin, Gregory R.; May, Iain

2008-01-15T23:59:59.000Z

137

An evaluation of the 3M Organic Vapor Monitor #3500 as a short term exposure limit sampling device for acetone, methyl ethyl ketone, and methyl iso butyl ketone  

E-Print Network [OSTI]

. An exploded view of the monitor is illustrated in Figure 1. The theory of diffusive sampling considers a concentration gra- dient between the ambient air and the adsorbent to be the driving force for sampling. For the adsorption to be controlled by diffu...AN EVALUATION OF THE 3M ORGANIC VAPOR MONITOR 43500 AS A SHOR'I TERM EXPOSURE LIMIT SAMPLING DEVICE FOR ACETONE, METHYL ETHYL KETONE, AND METHYL ISO BUTYL KETONE A Thesis by LLOYD B. ANDREW III Submitted to the Graduate College of Texas ASM...

Andrew, Lloyd B.

2012-06-07T23:59:59.000Z

138

Manipulation of the HIFVegf pathway rescues methyl tert-butyl ether (MTBE)-induced vascular lesions  

SciTech Connect (OSTI)

Methyl tert-butyl ether (MTBE) has been shown to be specifically anti-angiogenic in piscine and mammalian model systems at concentrations that appear non-toxic in other organ systems. The mechanism by which MTBE targets developing vascular structures is unknown. A global transcriptome analysis of zebrafish embryos developmentally exposed to 0.006255 mM MTBE suggested that hypoxia inducible factor (HIF)-regulated pathways were affected. HIF-driven angiogenesis via vascular endothelial growth factor (vegf) is essential to the developing vasculature of an embryo. Three rescue studies were designed to rescue MTBE-induced vascular lesions: pooled blood in the common cardinal vein (CCV), cranial hemorrhages (CH), and abnormal intersegmental vessels (ISV), and test the hypothesis that MTBE toxicity was HIFVegf dependent. First, zebrafish vegf-a over-expression via plasmid injection, resulted in significantly fewer CH and ISV lesions, 46 and 35% respectively, in embryos exposed to 10 mM MTBE. Then HIF degradation was inhibited in two ways. Chemical rescue by N-oxaloylglycine significantly reduced CCV and CH lesions by 30 and 32% in 10 mM exposed embryos, and ISV lesions were reduced 24% in 5 mM exposed zebrafish. Finally, a morpholino designed to knock-down ubiquitin associated von HippelLindau protein, significantly reduced CCV lesions by 35% in 10 mM exposed embryos. In addition, expression of some angiogenesis related genes altered by MTBE exposure were rescued. These studies demonstrated that MTBE vascular toxicity is mediated by a down regulation of HIFVegf driven angiogenesis. The selective toxicity of MTBE toward developing vasculature makes it a potentially useful chemical in the designing of new drugs or in elucidating roles for specific angiogenic proteins in future studies of vascular development. - Highlights: Global gene expression of MTBE exposed zebrafish suggested altered HIF1 signaling. Over expression of zebrafish vegf-a rescues MTBE-induced vascular lesions. Inhibiting PHD or knocking down VHL rescues MTBE-induced vascular lesions. HIF1-Vegf driven angiogenesis is a target for MTBE vascular toxicity.

Bonventre, Josephine A., E-mail: josephine.bonventre@oregonstate.edu [Rutgers, The State University of New Jersey, Joint Graduate Program in Toxicology, 170 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Rutgers, The State University of New Jersey, Department of Biochemistry and Microbiology, 76 Lipman Dr., New Brunswick, NJ 08901 (United States); Oregon State University, Department of Environmental and Molecular Toxicology, 1011 Agricultural and Life Sciences Bldg, Corvallis, OR 97331 (United States); Kung, Tiffany S., E-mail: tiffany.kung@rutgers.edu [Rutgers, The State University of New Jersey, Joint Graduate Program in Toxicology, 170 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Rutgers, The State University of New Jersey, Department of Biochemistry and Microbiology, 76 Lipman Dr., New Brunswick, NJ 08901 (United States); White, Lori A., E-mail: lawhite@aesop.rutgers.edu [Rutgers, The State University of New Jersey, Joint Graduate Program in Toxicology, 170 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Rutgers, The State University of New Jersey, Department of Biochemistry and Microbiology, 76 Lipman Dr., New Brunswick, NJ 08901 (United States); Cooper, Keith R., E-mail: cooper@aesop.rutgers.edu [Rutgers, The State University of New Jersey, Joint Graduate Program in Toxicology, 170 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Rutgers, The State University of New Jersey, Department of Biochemistry and Microbiology, 76 Lipman Dr., New Brunswick, NJ 08901 (United States)

2013-12-15T23:59:59.000Z

139

Derivation of a human equivalent concentration for n-butanol using a physiologically based pharmacokinetic model for n-butyl acetate and metabolites n-butanol and n-butyric acid  

SciTech Connect (OSTI)

The metabolic series (family) approach for risk assessment uses a dosimetry-based analysis to develop toxicity information for a group of metabolically linked compounds using pharmacokinetic (PK) data for each compound and toxicity data for the parent compound. An initial physiologically-based pharmacokinetic (PBPK) model was developed to support the implementation of the metabolic series approach for n-butyl acetate and its subsequent metabolites, n-butanol, and n-butyric acid (the butyl series) (Barton et al. 2000). In conjunction with pilot pharmacokinetic studies, the model was used to design the definitive intravenous (i.v.) PK studies. Rats were implanted with dual indwelling cannulae and administered test compounds by i.v. bolus dose, i.v. infusion, or by inhalation in a recirculating closed chamber. Hepatic, vascular and extravascular metabolic constants for metabolism were estimated by fitting the model to the blood time course data from these experiments. The respiratory bioavailability of n-butyl acetate and n-butanol was estimated from closed chamber inhalation studies and measured ventilation rates. The resulting butyl series PBPK model successfully reproduces the blood time course of these compounds following i.v. administration, and inhalation exposure to n-butyl acetate and n-butanol. A fully scaled human version of the model successfully reproduces arterial blood n-butanol kinetics following inhalation exposure to n-butanol. These validated i.v (rat) and inhalation route models (rat, butyl acetate, n-butanol; human, butanol only) can be used to support species and dose-route extrapolations required for risk assessment of butyl series family of compounds. Further, this work demonstrates the usefulness of i.v. kinetic data for parameterization of systemic metabolism and the value of collaboration between experimentalists and kineticists in the development of PBPK models. The product of this effort, validated rat and human PBPK models for the butyl series compounds, illustrates the effectiveness of broad multi-institutional public/private collaborations in the pursuit of developing state of the art tools for risk assessment.

Teeguarden, Justin G.; Deisinger, P. J.; Poet, Torka S.; English, J C.; Faber, W D.; Barton, H. A.; Corley, Rick A.; Clewell, III, H. J.

2005-05-01T23:59:59.000Z

140

Natural gas accumulations in low-permeability Tertiary, and Cretaceous (Campanian and Maastrichtian) rock, Uinta Basin, Utah  

SciTech Connect (OSTI)

This report characterizes Upper Cretaceous Campanian and Maastrichtian, and lower Tertiary gas-bearing rocks in the Uinta Basin with special emphasis on those units that contain gas in reservoirs that have been described as being tight. The report was prepared for the USDOE whose Western Tight Gas Sandstone Program cofunded much of this research in conjunction with the US Geological Survey's Evolution of Sedimentary Basins, and Onshore Oil and Gas Programs. (VC)

Fouch, T.D.; Wandrey, C.J.; Pitman, J.K.; Nuccio, V.F.; Schmoker, J.W.; Rice, D.D.; Johnson, R.C.; Dolton, G.L.

1992-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Natural gas accumulations in low-permeability Tertiary, and Cretaceous (Campanian and Maastrichtian) rock, Uinta Basin, Utah. Final report  

SciTech Connect (OSTI)

This report characterizes Upper Cretaceous Campanian and Maastrichtian, and lower Tertiary gas-bearing rocks in the Uinta Basin with special emphasis on those units that contain gas in reservoirs that have been described as being tight. The report was prepared for the USDOE whose Western Tight Gas Sandstone Program cofunded much of this research in conjunction with the US Geological Survey`s Evolution of Sedimentary Basins, and Onshore Oil and Gas Programs. (VC)

Fouch, T.D.; Wandrey, C.J.; Pitman, J.K.; Nuccio, V.F.; Schmoker, J.W.; Rice, D.D.; Johnson, R.C.; Dolton, G.L.

1992-02-01T23:59:59.000Z

142

Factors controlling reservoir quality in tertiary sandstones and their significance to geopressured geothermal production  

SciTech Connect (OSTI)

Variable intensity of diagenesis is the factor primarily responsible for contrasting regional reservoir quality of Tertiary sandstones from the upper and lower Texas coast. Detailed comparison of Frio sandstone from the Chocolate Bayou/Danbury Dome area, Brazoria County, and Vicksburg sandstones from the McAllen Ranch Field area, Hidalgo County, reveals that extent of diagenetic modification is most strongly influenced by (1) detrital mineralogy and (2) regional geothermal gradients. The regional reservoir quality of Frio sandstones from Brazoria County is far better than that characterizing Vicksburg sandstones from Hidalgo County, especially at depths suitable for geopressured geothermal energy production. However, in predicting reservoir quality on a site-specific basis, locally variable factors such as relative proportions for porosity types, pore geometry as related to permeability, and local depositional environment must also be considered. Even in an area of regionally favorable reservoir quality, such local factors can significantly affect reservoir quality and, hence, the geothermal production potential of a specific sandstone unit.

Loucks, R.G.; Richmann, D.L.; Milliken, K.L.

1981-01-01T23:59:59.000Z

143

Interplay between Secondary and Tertiary Structure Formation in Protein Folding Cooperativity  

E-Print Network [OSTI]

Protein folding cooperativity is defined by the nature of the finite-size thermodynamic transition exhibited upon folding: two-state transitions show a free energy barrier between the folded and unfolded ensembles, while downhill folding is barrierless. A microcanonical analysis, where the energy is the natural variable, has shown better suited to unambiguously characterize the nature of the transition compared to its canonical counterpart. Replica exchange molecular dynamics simulations of a high resolution coarse-grained model allow for the accurate evaluation of the density of states, in order to extract precise thermodynamic information, and measure its impact on structural features. The method is applied to three helical peptides: a short helix shows sharp features of a two-state folder, while a longer helix and a three-helix bundle exhibit downhill and two-state transitions, respectively. Extending the results of lattice simulations and theoretical models, we find that it is the interplay between secondary structure and the loss of non-native tertiary contacts which determines the nature of the transition.

Tristan Bereau; Michael Bachmann; Markus Deserno

2011-07-01T23:59:59.000Z

144

Maturation of Tertiary sediments in the Asian Continental Margins: A basis for hydrocarbon generation studies  

SciTech Connect (OSTI)

In the marginal areas of the Asian continent, the Paleogene and Miocene coal-bearing formations are sporadically distributed. In some areas, particularly in the sea regions, their equivalents are possibly explored for oil and gas. The basins mainly formed as tectonic depressions, and are filled with fluvial to marine clastic rocks. The formations show marked lateral variation in thickness, lithology, and sediment characteristics, which are related to the geotectonic settings of the basins at active plate margins. Remarkable accumulation of overburden and high paleogeothermal conditions, which are marked in northern Kyushu, Japan, and Thailand, influenced diagenesis. Organic and inorganic maturation studies in northern Kyushu reveal a progress of diagenesis from the inland of Kyushu toward the sea region essentially controlled by additional heat supply from the sea region during and after sedimentation. The sediments on the land surface are chiefly overmatured, and/or contain minor amounts of organic carbon. High paleogeothermal influence on Tertiary maturation is clear also in northern Thailand. The high paleotemperature conditions in these areas may be related to tectonic interaction between the oceanic and continental plates.

Miki, Takashi (Kyushu Univ., Fukuoka (Japan))

1994-07-01T23:59:59.000Z

145

Seismic reflection evidence for two phase development of Tertiary basins from east-central Nevada  

SciTech Connect (OSTI)

Two east-west seismic reflection profiles crossing Antelope Valley, Smokey Valley, Railroad Valley and Big Sand Springs Valley demonstrate the evolution of Tertiary extension from broad sags to narrow, fault-bounded basins. Seismic reflection data was acquired for the Anschutz Corporation by the Digicon Corporation during the winter of 1988/1989. Reprocessing of a 480 channel, 60 fold, dynamite source experiment enabled good imaging of the basin stratigraphy. These data suggest two distinct phases of basin development occurred, separated by a regional unconformity. The early phase is characterized by development of a broad basin riddled with many small offset normal faults. The later phase shows a narrowing of the basin and subsidence along one dominant structure, an apparent planar normal fault. The unconformity separating the two phases of extension marks a transition from broad subsidence to local asymmetric tilting that took place over a short period of time relative to sedimentation rates. Antelope Valley and Railroad Valley clearly show strong evidence for two phase development, whereas Smokey Valley represents mostly the early phase and Big Sand Springs Valley represents only the later phase of extension. The absence of dating within the basins precludes the authors from determining if the abrupt tectonic transition within the basins resulted from differences in local strain rates or amounts, or was due to changes in regional stress fields.

Liberty, L.M.; Heller, P.L.; Smithson, S.B. (Univ. of Wyoming, Laramie, WY (United States). Dept. of Geology and Geophysics)

1993-04-01T23:59:59.000Z

146

Life-cycle Environmental Inventory of Passenger Transportation in the United States  

E-Print Network [OSTI]

Methyltert?ButylEther(MTBE);http://www.atsdr.cdc.gov/MethylTertiaryButyl Ether (MTBE), which was easilyaccountingwasnotperformedonMTBEandtheresult of

Chester, Mikhail V

2008-01-01T23:59:59.000Z

147

Modeling of the simultaneous extraction of nitric acid and uranyl nitrate with tri-n-butyl phosphate. Application to extraction operation  

SciTech Connect (OSTI)

A mathematical model developed for the equilibrium HNO{sub 3}-UO{sub 2}(NO{sub 3}){sub 2}-tri-n-butyl phosphate (TBP)-diluent is the basis of the computation of distribution isotherms. The isotherms are used to study the influence of TBP concentration on two chosen operation parameters, distribution coefficients and number of theoretical stages, for the selected flow sheets. It is established that an increase in TBP concentration leads to a decrease in the number of theoretical stages for the extraction flow sheets but to their increase for the striping flow sheets. Given diagrams can be used to determine the efficiency of extraction processes. Agreement with available literature calculations on the number of theoretical stages supports the use of the model in the computation of distribution isotherms, of the system quoted above, in a wide range of nitric acid, uranyl nitrate, and TBP concentrations.

Comor, J.J.; Tolic, A.S.; Kopecni, M.M.; Petkovic, D.M. [Vinca Inst. of Nuclear Sciences, Belgrade (Yugoslavia). Chemical Dynamics Lab.] [Vinca Inst. of Nuclear Sciences, Belgrade (Yugoslavia). Chemical Dynamics Lab.

1999-01-01T23:59:59.000Z

148

Treatment of methyl tert-butyl ether vapors in a biotrickling filters. 2. Analysis of the rate-limiting step and behavior under transient conditions  

SciTech Connect (OSTI)

Detailed experiments were performed with gas phase biotrickling filters treating vapors of methyl tert-butyl ether (MTBE), a gasoline additive of great environmental concern. A particular emphasis was placed on the analysis of the rate-limiting step, and it was found that the process was mostly limited by the biological reaction rather than by mass transfer. Further experiments involved the study of the dynamic behavior of the biotrickling filters under simulated field conditions. In all cases, the biotrickling filters adapted rapidly to the new conditions, and new steady states were obtained within hours. The relevance of the results and the implications as far as implementation of biotrickling filters for field MTBE treatment are discussed.

Fortin, N.Y.; Deshusses, M.A. [Univ. of California, Riverside, CA (United States). Dept. of Chemical and Environmental Engineering] [Univ. of California, Riverside, CA (United States). Dept. of Chemical and Environmental Engineering

1999-09-01T23:59:59.000Z

149

Thermally Switchable Thin Films of an ABC Triblock Copolymer of Poly(n-butyl methacrylate)-poly(methyl methacrylate)-poly(2-fluoroethyl methacrylate)  

SciTech Connect (OSTI)

The thermo-responsive behavior of polymer films consisting of novel linear triblock copolymers of poly(n-butyl methacrylate)-poly(methyl methacrylate)-poly(2-fluoroethyl methacrylate) (PnBuMA-PMMA-P2FEMA) are reported using differential scanning calorimetry (DSC), atomic forcing microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and contacting angle (CA) measurements. The surface morphology, wettability and chemical structure of thin films of these triblock copolymers on silicon wafers as a function of temperature have been investigated. It has been shown that the wettability of the films is thermally switchable. Detailed structural analysis shows that thermo-responsive surface composition changes are produced. The underlying mechanism of the thermoresponsive behavior is discussed.

Zhang, Shanju [Georgia Institute of Technology; Liu, Zhan [Georgia Institute of Technology; Bucknall, David G. [Georgia Institute of Technology; He, Lihong [ORNL; Hong, Kunlun [ORNL; Mays, Jimmy [ORNL; Allen, Mark [Georgia Institute of Technology

2011-01-01T23:59:59.000Z

150

Use of Treated Municipal Wastewater as Power Plant Cooling System Makeup Water: Tertiary Treatment versus Expanded Chemical Regimen for Recirculating Water Quality Management  

SciTech Connect (OSTI)

Treated municipal wastewater is a common, widely available alternative source of cooling water for thermoelectric power plants across the U.S. However, the biodegradable organic matter, ammonia-nitrogen, carbonate and phosphates in the treated wastewater pose challenges with respect to enhanced biofouling, corrosion, and scaling, respectively. The overall objective of this study was to evaluate the benefits and life cycle costs of implementing tertiary treatment of secondary treated municipal wastewater prior to use in recirculating cooling systems. The study comprised bench- and pilot-scale experimental studies with three different tertiary treated municipal wastewaters, and life cycle costing and environmental analyses of various tertiary treatment schemes. Sustainability factors and metrics for reuse of treated wastewater in power plant cooling systems were also evaluated. The three tertiary treated wastewaters studied were: secondary treated municipal wastewater subjected to acid addition for pH control (MWW_pH); secondary treated municipal wastewater subjected to nitrification and sand filtration (MWW_NF); and secondary treated municipal wastewater subjected nitrification, sand filtration, and GAC adsorption (MWW_NFG). Tertiary treatment was determined to be essential to achieve appropriate corrosion, scaling, and biofouling control for use of secondary treated municipal wastewater in power plant cooling systems. The ability to control scaling, in particular, was found to be significantly enhanced with tertiary treated wastewater compared to secondary treated wastewater. MWW_pH treated water (adjustment to pH 7.8) was effective in reducing scale formation, but increased corrosion and the amount of biocide required to achieve appropriate biofouling control. Corrosion could be adequately controlled with tolytriazole addition (4-5 ppm TTA), however, which was the case for all of the tertiary treated waters. For MWW_NF treated water, the removal of ammonia by nitrification helped to reduce the corrosivity and biocide demand. Also, the lower pH and alkalinity resulting from nitrification reduced the scaling to an acceptable level, without the addition of anti-scalant chemicals. Additional GAC adsorption treatment, MWW_NFG, yielded no net benefit. Removal of organic matter resulted in pitting corrosion in copper and cupronickel alloys. Negligible improvement was observed in scaling control and biofouling control. For all of the tertiary treatments, biofouling control was achievable, and most effectively with pre-formed monochloramine (2-3 ppm) in comparison with NaOCl and ClO2. Life cycle cost (LCC) analyses were performed for the tertiary treatment systems studied experimentally and for several other treatment options. A public domain conceptual costing tool (LC3 model) was developed for this purpose. MWW_SF (lime softening and sand filtration) and MWW_NF were the most cost-effective treatment options among the tertiary treatment alternatives considered because of the higher effluent quality with moderate infrastructure costs and the relatively low doses of conditioning chemicals required. Life cycle inventory (LCI) analysis along with integration of external costs of emissions with direct costs was performed to evaluate relative emissions to the environment and external costs associated with construction and operation of tertiary treatment alternatives. Integrated LCI and LCC analysis indicated that three-tiered treatment alternatives such as MWW_NSF and MWW_NFG, with regular chemical addition for treatment and conditioning and/or regeneration, tend to increase the impact costs and in turn the overall costs of tertiary treatment. River water supply and MWW_F alternatives with a single step of tertiary treatment were associated with lower impact costs, but the contribution of impact costs to overall annual costs was higher than all other treatment alternatives. MWW_NF and MWW_SF alternatives exhibited moderate external impact costs with moderate infrastructure and chemical conditioner dosing, which makes them (especially

David Dzombak; Radisav Vidic; Amy Landis

2012-06-30T23:59:59.000Z

151

Multiple Objective Stormwater Management For the Coliseum Complex  

E-Print Network [OSTI]

methyl tertiary butyl ether (MTBE) remain in the soil around5.2 ppb xylenes, and 160 ppb MTBE remain in the groundwater

Jones, Jesse; Kraai, Rachel

2009-01-01T23:59:59.000Z

152

The Drinking Water Security and Safety Amendments of 2002: Is America's Drinking Water Infrastructure Safer Four Years Later?  

E-Print Network [OSTI]

355 tertiary butyl ether ("MTBE"). 43 8 Amazingly, even "[c]Water: Study Estimates Cost of MTBE Remedia- tion At Up to $

Shermer, Steven D.

2006-01-01T23:59:59.000Z

153

Agricultural and Resource Economics Update  

E-Print Network [OSTI]

tertiary butyl ether (MTBE), a natural-gas derivative, werebattle between advocates for ethanol and those for MTBE.MTBE became the dominant additive because it was less

Smith, Aaron; Zilberman, David; Saitone, Tina; Sexton, Richard J.

2012-01-01T23:59:59.000Z

154

Uranium mineralization along a fault plane in tertiary sedimentary rocks in the McLean 5 Mine, Live Oak Conty, Texas  

E-Print Network [OSTI]

URAN1IUM MINERALIZATION ALONG A FAULT PLANE IN TERTIARY SEDIMENTARY ROCKS IN THE MCLEAN 5 MINE, LIVE OAK COUNTY, TEXAS A Thesis by BRENDA JEAN BOMBER Submitted to the Graduate College of Texas ARM University in partial fulfillment... as to sty1e and content by: Chairman of Committee Member Memb r H o De artment December 1980 ABSTRACT Uranium Mineralization along a Fault Plane in Tertiary Sedimentary Rocks in the McLean 5 Mine, Live Oak County, Texas. (December 1980) Brenda Jean...

Bomber, Brenda Jean

1980-01-01T23:59:59.000Z

155

Taming the off-shell Higgs boson  

E-Print Network [OSTI]

We study the off-shell Higgs data in the process $pp\\to h^{(*)} \\to Z^{(\\ast)}Z^{(\\ast)}\\to 4\\ell$, to constrain deviations of the Higgs couplings. We point out that this channel can be used to resolve the long- and short-distance contributions to Higgs production by gluon fusion and can thus be complementary to $pp\\to ht\\bar t$ in measuring the top Yukawa coupling. Our analysis, performed in the context of Effective Field Theory, shows that current data do not allow one to draw any model-independent conclusions. We study the prospects at future hadron colliders, including the high-luminosity LHC and accelerators with higher-energy, up to 100 TeV. The available QCD calculations and the theoretical uncertainties affecting our analysis are also briefly discussed.

Aleksandr Azatov; Christophe Grojean; Ayan Paul; Ennio Salvioni

2015-03-10T23:59:59.000Z

156

Taming the Energy Hog in Cloud Infrastructure  

E-Print Network [OSTI]

energy consumption consumed 61 Billion kWh in 2006, enough to power 5.8 Million average US households constrained #12;Energy Expenditure of The Cloud The IT industry is on fire! constitutes about 2% of total USTaming the Energy Hog in Cloud Infrastructure Jie Liu Microsoft Research liuj@microsoft.com RTSS

Hunt, Galen

157

Taming the Runaway Problem of Inflationary Landscapes  

E-Print Network [OSTI]

Predictions on the neutrinoless double beta decay from thethe rate of neutrinoless double beta decay and, in the caseon the rate of neutrinoless double beta decay are available

Hall, Lawrence J.

2009-01-01T23:59:59.000Z

158

Taming the Runaway Problem of Inflationary Landscapes  

E-Print Network [OSTI]

A wide variety of vacua, and their cosmological realization, may provide an explanation for the apparently anthropic choices of some parameters of particle physics and cosmology. If the probability on various parameters is weighted by volume, a flat potential for slow-roll inflation is also naturally understood, since the flatter the potential the larger the volume of the sub-universe. However, such inflationary landscapes have a serious problem, predicting an environment that makes it exponentially hard for observers to exist and giving an exponentially small probability for a moderate universe like ours. A general solution to this problem is proposed, and is illustrated in the context of inflaton decay and leptogenesis, leading to an upper bound on the reheating temperature in our sub-universe. In a particular scenario of chaotic inflation and non-thermal leptogenesis, predictions can be made for the size of CP violating phases, the rate of neutrinoless double beta decay and, in the case of theories with gauge-mediated weak scale supersymmetry, for the fundamental scale of supersymmetry breaking.

Lawrence J. Hall; Taizan Watari; T. T. Yanagida

2006-03-15T23:59:59.000Z

159

Transport study of hafnium(IV) and zirconium(IV) ions mutual separation by using Tri-n-butyl phosphate-xylene-based supported liquid membranes  

SciTech Connect (OSTI)

A Hf transport study through supported liquid membranes has been carried out to determine flux and permeability data for this metal ion. Tri-n-butyl phosphate (TBP)-xylene-based liquid membranes supported in polypropylene hydrophobic microporous film have been used. These data for hafnium and the previous data for zirconium have furnished the Zr to Hf flux ratio (S) as a function of nitric acid and TBP concentrations of the order of 12 in a single stage at room temperature. Optimum conditions for the separation of these two metal ions appear to 5-6 TBP mol/dm{sup 3} HNO{sub 3}, concentrations {le} 2.93 mol/dm{sup 3}, and 10C. The value of S from an aqueous solution containing 2.4% Hf with respect to Zr has been found to be >125 at 10C and 1.78 mol/dm{sup 3} TBP concentration in the membrane. The technique appears to be feasible for purification of Zr respect to Hf or vice versa.

Chaudry, M.A.; Ahmed, B. (Pakistan Inst. of Nuclear Science and Technology, Islamabad (Pakistan))

1992-02-01T23:59:59.000Z

160

Fluctuating micro-heterogeneity in watertert-butyl alcohol mixtures and lambda-type divergence of the mean cluster size with phase transition-like multiple anomalies  

SciTech Connect (OSTI)

Watertert-butyl alcohol (TBA) binary mixture exhibits a large number of thermodynamic and dynamic anomalies. These anomalies are observed at surprisingly low TBA mole fraction, with x{sub TBA} ? 0.030.07. We demonstrate here that the origin of the anomalies lies in the local structural changes that occur due to self-aggregation of TBA molecules. We observe a percolation transition of the TBA molecules at x{sub TBA} ? 0.05. We note that islands of TBA clusters form even below this mole fraction, while a large spanning cluster emerges above that mole fraction. At this percolation threshold, we observe a lambda-type divergence in the fluctuation of the size of the largest TBA cluster, reminiscent of a critical point. Alongside, the structure of water is also perturbed, albeit weakly, by the aggregation of TBA molecules. There is a monotonic decrease in the tetrahedral order parameter of water, while the dipole moment correlation shows a weak nonlinearity. Interestingly, water molecules themselves exhibit a reverse percolation transition at higher TBA concentration, x{sub TBA} ? 0.45, where large spanning water clusters now break-up into small clusters. This is accompanied by significant divergence of the fluctuations in the size of largest water cluster. This second transition gives rise to another set of anomalies around. Both the percolation transitions can be regarded as manifestations of Janus effect at small molecular level.

Banerjee, Saikat; Furtado, Jonathan; Bagchi, Biman, E-mail: bbagchi@sscu.iisc.ernet.in [SSCU, Indian Institute of Science, Bangalore 560012 (India)] [SSCU, Indian Institute of Science, Bangalore 560012 (India)

2014-05-21T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Low-temperature CVD of iron, cobalt, and nickel nitride thin films from bis[di(tert-butyl)amido]metal(II) precursors and ammonia  

SciTech Connect (OSTI)

Thin films of late transition metal nitrides (where the metal is iron, cobalt, or nickel) are grown by low-pressure metalorganic chemical vapor deposition from bis[di(tert-butyl)amido]metal(II) precursors and ammonia. These metal nitrides are known to have useful mechanical and magnetic properties, but there are few thin film growth techniques to produce them based on a single precursor family. The authors report the deposition of metal nitride thin films below 300?C from three recently synthesized M[N(t-Bu){sub 2}]{sub 2} precursors, where M?=?Fe, Co, and Ni, with growth onset as low as room temperature. Metal-rich phases are obtained with constant nitrogen content from growth onset to 200?C over a range of feedstock partial pressures. Carbon contamination in the films is minimal for iron and cobalt nitride, but similar to the nitrogen concentration for nickel nitride. X-ray photoelectron spectroscopy indicates that the incorporated nitrogen is present as metal nitride, even for films grown at the reaction onset temperature. Deposition rates of up to 18?nm/min are observed. The film morphologies, growth rates, and compositions are consistent with a gas-phase transamination reaction that produces precursor species with high sticking coefficients and low surface mobilities.

Cloud, Andrew N.; Abelson, John R., E-mail: abelson@illinois.edu [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 201 Materials Science and Engineering Building, 1304 W. Green St., Urbana, Illinois 61801 (United States); Davis, Luke M.; Girolami, Gregory S., E-mail: girolami@scs.illinois.edu [School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Ave., Urbana, Illinois 61801 (United States)

2014-03-15T23:59:59.000Z

162

Fluctuating micro-heterogeneity in water - tert-butyl alcohol mixtures and lambda-type divergence of the mean cluster size with phase transition-like multiple anomalies  

E-Print Network [OSTI]

Water - tert-butyl alcohol (TBA) binary mixture exhibits a large number of thermodynamic and dynamic anomalies. These anomalies are observed at surprisingly low TBA mole fraction, with $x_{\\text{TBA}} \\approx 0.03 - 0.07$. We demonstrate here that the origin of the anomalies lies in the local structural changes that occur due to self-aggregation of TBA molecules. We observe a percolation transition of the TBA molecules at $x_{\\text{TBA}} \\approx 0.05$. We note that "islands" of TBA clusters form even below this mole fraction, while a large spanning cluster emerges above that mole fraction. At this percolation threshold, we observe a lambda-type divergence in the fluctuation of the size of the largest TBA cluster, reminiscent of a critical point. Alongside, the structure of water is also perturbed, albeit weakly, by the aggregation of TBA molecules. There is a monotonic decrease in the tetrahedral order parameter of water, while the dipole moment correlation shows a weak non-linearity. Interestingly, water molecules themselves exhibit a reverse percolation transition at higher TBA concentration, $x_{\\text{TBA}} \\approx 0.45$, where large spanning water clusters now break-up into small clusters. This is accompanied by significant divergence of the fluctuations in the size of largest water cluster. This second transition gives rise to another set of anomalies around. Both the percolation transitions can be regarded as manifestations of Janus effect at small molecular level.

Saikat Banerjee; Jonathan Furtado; Biman Bagchi

2014-02-20T23:59:59.000Z

163

Treatment of methyl tert-butyl ether vapors in biotrickling filters. 1. Reactor startup, steady-state performance, and culture characteristics  

SciTech Connect (OSTI)

An aerobic microbial consortium able to biodegrade methyl tert-butyl ether (MTBE) was enriched in two waste air biotrickling filters after continuous operation for 6 months. After this acclimation phase, the two laboratory-scale biotrickling filters were able to degrade up to 50 g of MTBE per cubic meter of reactor per hour, a value comparable to other gasoline constituents. Such high performance could be sustained for at least 4--6 weeks. After the acclimation phase, the MTBE degrading biotrickling filters were characterized by their almost full conversion of MTBE to carbon dioxide and the absence of any degradation byproducts in either the gas or the liquid phase. They also exhibited a very high specific degradation activity per amount of biomass, and a low rate of biomass accumulation. An observed biomass yield of 0.1 g g{sup {minus}1} and a specific growth rate of 0.025 day{sup {minus}1} were determined for the biotrickling filter process culture. Further data on MTBE mass transfer and on the dynamic behavior of the biotrickling filter are presented in part 2 of this paper. Overall, the results demonstrate that MTBE can be effectively biodegraded under carefully controlled environmental conditions.

Fortin, N.Y.; Deshusses, M.A. [Univ. of California, Riverside, CA (United States). Dept. of Chemical and Environmental Engineering] [Univ. of California, Riverside, CA (United States). Dept. of Chemical and Environmental Engineering

1999-09-01T23:59:59.000Z

164

Review and reconnaissance of the hydrogeology of Tertiary sedimentary rocks in the vicinity of Frenchman Flat, Nevada Test Site  

SciTech Connect (OSTI)

Work is currently underway within the Underground Test Area (UGTA) subproject of the US Department of Energy/Nevada Operations Office Environmental Restoration Program to develop corrective action plans in support of the overall corrective action strategy for the Nevada Test Site (NTS) as established in the Federal Facility Agreement and Consent Order (FFACO, 1996). A closure plan is currently being developed for Frenchman Flat, which has been identified in the FFACO as a Corrective Action Unit (CAU). Part of this effort requires that hydrogeologic data be compiled for inclusion in a CAU-specific hydrologic flow and transport model that will be used to predict contaminant boundaries. Hydrogeologic maps and cross sections are currently being prepared for use in the model to define the nature and extent of aquifers and confining units that might influence the flow of contaminated groundwater from underground nuclear tests conducted in Frenchman Flat. During this effort, it has been found that older Tertiary-age sediments might be hydrogeologically important in the Frenchman Flat model area. Although the character and extent of these units are poorly known, there is reason to believe that in some parts of Frenchman Flat they may lie between the regional Lower Carbonate Aquifer (LCA) and the younger Tertiary saturated alluvium and volcanic units in which several underground nuclear tests were conducted. It was not possible to quickly determine their extent, or ascertain whether or not these units might act as confining units or aquifers. The work described in this report was done to gain a better understanding of the hydrogeology of these rocks.

Prothro, L.B.; Drellack, S.L. Jr.

1997-09-01T23:59:59.000Z

165

UNIVERSITY OF CALIFORNIA Santa Barbara  

E-Print Network [OSTI]

, B. Dooher, and D. Rice, Analysis of dissolved benzene plumes and methyl tertiary butyl ether (MTBE, An evaluation of MTBE impacts to California groundwater resources, pp. 68 p., Lawrence Livermore National, Temporal Analysis of Methyl Tertiary Butyl Ether (MTBE) Plumes at California Leaking Underground Fuel tank

California at Santa Barbara, University of

166

Effect of Ethanol and Methyl-tert-Butyl Ether on Monoaromatic Hydrocarbon Biodegradation: Response Variability for Different Aquifer Materials Under Various Electron-Accepting Conditions  

SciTech Connect (OSTI)

Aquifer microcosms were used to determine how ethanol and methyl-tert-butyl ether (MtBE) affect monoaromatic hydrocarbon degradation under different electron-accepting conditions commonly found in contaminated sites experiencing natural attenuation. Response variability was investigated by using aquifer material from four sites with different exposure history. The lag phase prior to BTEX (benzene, toluene, ethylbenzene, and xylenes) and ethanol degradation was typically shorter in microcosms with previously contaminated aquifer material, although previous exposure did not always result in high degradation activity. Toluene was degraded in all aquifer materials and generally under a broader range of electron-accepting conditions compared to benzene, which was degraded only under aerobic conditions. MtBE was not degraded within 100 days under any condition, and it did not affect BTEX or ethanol degradation patterns. Ethanol was often degraded before BTEX compounds, and had a variable effect on BTEX degradation as a function of electron-accepting conditions and aquifer material source. An occasional enhancement of toluene degradation by ethanol occurred in denitrifying microcosms with unlimited nitrate; this may be attributable to the fortuitous growth of toluene-degrading bacteria during ethanol degradation. Nevertheless, experiments with flow-through aquifer columns showed that this beneficial effect could be eclipsed by an ethanol-driven depletion of electron acceptors, which significantly inhibited BTEX degradation and is probably the most important mechanism by which ethanol could hinder BTEX natural attenuation. A decrease in natural attenuation could increase the likelihood that BTEX compounds reach a receptor as well as the potential duration of exposure.

Ruiz-Aguilar, G L; Fernandez-Sanchez, J M; Kane, S R; Kim, D; Alvarez, P J

2003-10-06T23:59:59.000Z

167

Is Embolization of the Pancreas Safe? Pancreatic Histological Changes after Selective Transcatheter Arterial Embolization with N-Butyl Cyanoacrylate in a Swine Model  

SciTech Connect (OSTI)

Purpose: This study was designed to evaluate the safety of selective transcatheter arterial embolization (TAE) with N-butyl cyanoacrylate (NBCA) in a swine model in terms of histological changes in the pancreas. Methods: Three groups of two female swine (58-64 kg) per group underwent TAE of the dorsal pancreatic artery, under anesthesia, with 1:1, 1:4, and 1:9 mixtures of NBCA and iodized oil. Blood parameters were evaluated at days 1, 4, and 10 after TAE, after which the animals were sacrificed and pancreatic tissues were examined under light microscopy. Results: All of the animals were asymptomatic and survived for 10 days. Cone beam computed tomographic angiography revealed occlusion of the dorsal pancreatic artery and no enhancement in the embolized area. The white blood cell count and C-reactive protein level were elevated slightly on day 1 after TAE (mean {+-} SD: 252.7 {+-} 27.8 Multiplication-Sign 10{sup 2}/{mu}l and 0.15 {+-} 0.07 mg/l, respectively), but they normalized or remained near the upper normal limit thereafter. The serum amylase and lipase levels also were elevated on day 1 (8831.7 {+-} 2169.2 U/l and 130 {+-} 53.4 U/l, respectively) but normalized thereafter. Histologically, necrosis and fibrosis were noted only in the embolized segment, and necrosis and acute inflammatory reactions were absent in the nonembolized segment. The border between both segments was well defined. Lymphocytic infiltration and foreign body reaction were noted around the embolized vessels. Conclusions: Selective TAE with NBCA in the pancreas caused localized ischemic necrosis without clinically significant pancreatitis; therefore, this procedure is tolerable in swine.

Okada, Takuya, E-mail: okabone@gmail.com; Yamaguchi, Masato [Kobe University Graduate School of Medicine, Department of Radiology (Japan); Takahashi, Takuya [Kobe Red Cross Hospital, Department of Pathology (Japan); Izaki, Kenta; Uotani, Kensuke; Sakamoto, Noriaki; Sugimura, Kazuro; Sugimoto, Koji [Kobe University Graduate School of Medicine, Department of Radiology (Japan)

2012-02-15T23:59:59.000Z

168

Distribution of hazardous air pollutant trace elements, total sulfur, and ash in coals from five Tertiary basins in the Rocky Mountain Region  

SciTech Connect (OSTI)

Arithmetic mean values of the contents of hazardous air pollutant (HAP) trace elements named in the 1990 Clean Air Act Amendments (antimony, arsenic, beryllium, cadmium, chromium, cobalt, lead, manganese, mercury, nickel, selenium, and uranium), ash, and total sulfur were statistically compared on a whole-coal basis for Paleocene coals from five Tertiary basins in the Rocky Mountain Region. The study of proximate and elemental analyses indicate a relationship between trace element contents and paleogeography.

Ellis, M.S.; Stricker, G.D.; Flores, R.M. [Geological Survey, Denver, CO (United States)

1994-12-31T23:59:59.000Z

169

Adverse Drug Reaction Monitoring In Psychiatric OPD Adverse Drug Reaction Monitoring In Psychiatric Outpatient Department Of A Tertiary Care Hospital  

E-Print Network [OSTI]

Abstracts Background:Pharmacovigilance in psychiatry units can play vital role in detecting adverse drug reactions (ADRs) and alerting physician to such events, thereby protecting the user population from avoidable harm. Objective: To assess the suspected ADRs profile of psychotropic drugs in psychiatry OPD of a tertiary care hospital and its comparison with available literature data as well as to create awareness among the consultant psychiatrists to these ADRs profile. Materials and Methods: A prospective study was conducted in the psychiatry OPD. Thirty five consecutive patients per day were screened irrespective of their psychiatric diagnosis for suspected ADRs on 3 fixed days in a week from January 2011 to December 2011. CDSCO form was used to record the ADRs. Causality was assessed by WHO causality assessment scale while severity was assessed using Hartwig and Siegel scale. Results: Out of 4410 patients were screened, 383 patients were suspected of having at least one ADR. Thus, 8.68 % of our study population reported ADRs. Of 407 events recorded, 369(90.60%) were probable and rest possible according to WHO-UMC causality assessment

Hiren K. Prajapati; Nisarg D. Joshi; Hiren R. Trivedi; Manubhai C. Parmar; Shilpa P. Jadav; Dinesh M. Parmar; Jalpan G. Kareliya

170

Sonolytic destruction of methyl tert-butyl ether by ultrasonic irradiation: The role of O{sub 3}, H{sub 2}O{sub 2}, frequency, and power density  

SciTech Connect (OSTI)

The kinetics of degradation of methyl tert-butyl ether (MTBE) by ultrasonic irradiation in the presence of ozone as functions of applied frequencies and applied power are investigated. Experiments are performed over the frequency range of 205--1,078 kHz. The higher overall reaction rates are observed at 358 and 618 kHz and then at 205 and 1,078 kHz. The observed pseudo-first-order rate constant, k{sub 0}, for MTBE degradation increases with increasing power density up to 250 W L{sup {minus}1}. A linear dependence of the first-order rate constant, k{sub O{sub 3}}, for the simultaneous degradation of O{sub 3} on power density is also observed. Naturally occurring organic matter (NOM) is shown to have a negligible effect on observed reaction rates.

Kang, J.W.; Hung, H.M.; Lin, A.; Hoffmann, M.R. [California Inst. of Tech., Pasadena, CA (United States). W.M. Keck Labs.] [California Inst. of Tech., Pasadena, CA (United States). W.M. Keck Labs.

1999-09-15T23:59:59.000Z

171

Kinetics and mechanism of the thermal dissociation of O,O'-bis(1,3,5-TRI-tert-butyl-4-oxo-2,5-cyclo-hexadienyl)-p-benzoquinone dioxime in solution  

SciTech Connect (OSTI)

The kinetics and mechanism of the thermal dissociation of O,O'-bis(1,3,5-tri-tert-butyl-4-oxo-2,5-cyclohexadienyl)-p-benzoquinone dioxime (quinol ether) in solutions in nonpolar solvents were investigated. The dissociation of the quinol ether is reversible two-stage process and involves the formation of an intermediate radical. In relation to the reaction conditions (initial concentration, temperature) the dissociation rate of the quinol ether obeys the kinetic equations omega = k/sub eff/ x c/sup 1/2/ or omega = k/sub 1/c. The change in the reaction order is due to the ratio of the rates of dissociation of the intermediate radical and of its reaction with the phenoxyl radical. The ESR spectra were recorded on a Varian E-9 radiospectrometer with high-frequency modulation of 100 kHz.

Khizhnyi, V.A.; Danilova, T.A.; Goloverda, G.Z.; Dobronravova, Z.A.

1987-09-20T23:59:59.000Z

172

Reference: De Vleeschouwer, M. & Gueudet, G. (2011, fvrier). Secondary-tertiary transition and evolution of didactic contract : the example of duality in linear algebra. In Pytlak, M., Rowland, T., Swoboda, E. Proceedings of  

E-Print Network [OSTI]

and evolution of didactic contract : the example of duality in linear algebra. In Pytlak, M., Rowland, T-TERTIARY TRANSITION AND EVOLUTIONS OF DIDACTIC CONTRACT: THE EXAMPLE OF DUALITY IN LINEAR ALGEBRA Martine De, and a didactic contract perspective we argue that some of the novice students' difficulties can result from

Paris-Sud XI, Université de

173

Variations in Mg/Ca as a control on distribution of strontium concentrations and delta/sup 18/O in upper Tertiary dolomites from Bahamas  

SciTech Connect (OSTI)

Strontium concentrations and delta/sup 18/O are commonly used to infer the gross composition of dolomitizing waters, yet the bases for such inferences are not firmly established. A new approach to calibrating these 2 parameters is suggested from analyses of a section of upper Tertiary dolomites from the Bahamas. In an interval of dolomite, 120 m (394 ft) from a core taken on San Salvador Island, mole % MgCO/sub 3/ is correlated positively with delta/sup 18/O, and negatively with strontium. Strontium substitutes mainly for calcium, thus the negative correlation with mole % MgCO/sub 3/. Dolomites are enriched between 3 to 7% in delta/sup 18/O as compared with coprecipitated calcite, and thus the positive correlation. These two covariations indicate the need to consider the stoichiometric coefficient of dolomites, and to normalize strontium concentrations and delta/sup 18/O with their respective stoichiometric coefficients before inferring their relationship with fluid composition.

Swart, P.K.; Dawans, J.M.

1984-04-01T23:59:59.000Z

174

TORP (Tertiary Oil Recovery Project) stream tube model for waterflood performance calculations in a reservoir with arbitrary well patterns and irregular boundaries  

SciTech Connect (OSTI)

The Tertiary Oil Recovery Project stream tube model was developed as a tool to help oil operators in Kansas evaluate and understand their waterflood projects in a more systematic approach. The model utilizes the stream tube concept and Buckley-Leverett theory and can be applied to any homogeneous reservoir with arbitrary well patterns and regular or irregular boundaries. It also can be applied to tracer projects to estimate tracer breakthrough time if the tracer is injected during the stage of high water-oil ratio. The computer package has been prepared in a fashion such that minimum effort and interaction are required for the user to obtain the final results from specified input data. The model was applied to an example problem consisting of a 5-spot pattern. 19 references.

Vossoughi, S.

1981-01-01T23:59:59.000Z

175

Nonassociated gas resources in low-permeability sandstone reservoirs, lower tertiary Wasatch Formation, and upper Cretaceous Mesaverde Group, Uinta Basin, Utah  

SciTech Connect (OSTI)

The US Geological Survey recognizes six major plays for nonassociated gas in Tertiary and Upper Cretaceous low-permeability strata of the Uinta Basin, Utah. For purposes of this study, plays without gas/water contacts are separated from those with such contacts. Continuous-saturation accumulations are essentially single fields, so large in areal extent and so heterogeneous that their development cannot be properly modeled as field growth. Fields developed in gas-saturated plays are not restricted to structural or stratigraphic traps and they are developed in any structural position where permeability conduits occur such as that provided by natural open fractures. Other fields in the basin have gas/water contacts and the rocks are water-bearing away from structural culmination`s. The plays can be assigned to two groups. Group 1 plays are those in which gas/water contacts are rare to absent and the strata are gas saturated. Group 2 plays contain reservoirs in which both gas-saturated strata and rocks with gas/water contacts seem to coexist. Most units in the basin that have received a Federal Energy Regulatory Commission (FERC) designation as tight are in the main producing areas and are within Group 1 plays. Some rocks in Group 2 plays may not meet FERC requirements as tight reservoirs. However, we suggest that in the Uinta Basin that the extent of low-permeability rocks, and therefore resources, extends well beyond the limits of current FERC designated boundaries for tight reservoirs. Potential additions to gas reserves from gas-saturated tight reservoirs in the Tertiary Wasatch Formation and Cretaceous Mesaverde Group in the Uinta Basin, Utah is 10 TCF. If the potential additions to reserves in strata in which both gas-saturated and free water-bearing rocks exist are added to those of Group 1 plays, the volume is 13 TCF.

Fouch, T.D.; Schmoker, J.W.; Boone, L.E.; Wandrey, C.J.; Crovelli, R.A.; Butler, W.C.

1994-08-01T23:59:59.000Z

176

APPENDXD.CHP:Corel VENTURA  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Report The Form EIA-819, "Monthly Oxygenate Report" provides production data for fuel ethanol and methyl tertiary butyl ether (MTBE). End-of-month stock data held at ethanol...

177

A Low-Carbon Fuel Standard for California Part 1: Technical Analysis  

E-Print Network [OSTI]

methyl-tertiary butyl ether (MTBE), from gasoline by 2004.MTBE was used to meet a requirement for gasoline to containbeginning in 2002, replacing MTBE with ethanol. According to

2007-01-01T23:59:59.000Z

178

Emissions of volatile organic compounds inferred from airborne flux measurements over a megacity  

E-Print Network [OSTI]

methyl-tertiary-butyl- ether (MTBE) and the biomass burningfrom all source categories. MTBE is a gasoline additive andwith the fuel tracer MTBE (e.g. 0.82 for MTBE/benzene).

Karl, T.; Apel, E.; Hodzic, A.; Riemer, D. D; Blake, D. R; Wiedinmyer, C.

2009-01-01T23:59:59.000Z

179

Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area  

E-Print Network [OSTI]

Methanol Ethanol Acetone MEK MTBE CO Methane UCI UCI TOGA/methyl tertiary butyl ether (MTBE), and toluene all ratioedthe observed decay. For MTBE, also a species that is not

2010-01-01T23:59:59.000Z

180

Soil type, crop and irrigation technique affect nitrogen leaching to groundwater  

E-Print Network [OSTI]

water contamination with MTBE (methyl tertiary-butyl ether,that areas vulnerable to MTBE are also vulner- able tothat affect the movement of MTBE. If only a small amount of

Letey, John; Vaughan, Peter

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3and SO2  

E-Print Network [OSTI]

methyl tertiary- butyl ether (MTBE) and its effect on plasmaand three VOCs (propyne, furan, MTBE) remained below their 3Ethanol Acetone MEK MAC MVK MTBE Furan CH 3 OH C 2 H 5 OH C

2010-01-01T23:59:59.000Z

182

A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis  

E-Print Network [OSTI]

methyl-tertiary butyl ether (MTBE), from gasoline by 2004.MTBE was used to meet a requirement for gasoline to containbeginning in 2002, replacing MTBE with ethanol. According to

Farrell, Alexander E.; Sperling, Dan

2007-01-01T23:59:59.000Z

183

Factors influencing biological treatment of MTBE contaminated ground water  

E-Print Network [OSTI]

Methyl tertiary-butyl ether (MTBE) biodegradation in batchCometabolic degradation of MTBE by a cyclohexane-oxidizingof 49 Biological Treatment of MTBE Fortin, N. Y. , and M. A.

Stringfellow, William T.; Hines Jr., Robert D.; Cockrum, Dirk K.; Kilkenny, Scott T.

2001-01-01T23:59:59.000Z

184

Finding the missing stratospheric Bry: a global modeling study of CHBr3 and CH2Br2  

E-Print Network [OSTI]

Methanol Ethanol Acetone MEK MTBE CO Methane UCI UCI TOGA/methyl tertiary butyl ether (MTBE), and toluene all ratioedthe observed decay. For MTBE, also a species that is not

2010-01-01T23:59:59.000Z

185

Life-Cycle Water Impacts of U.S. Transportation Fuels  

E-Print Network [OSTI]

Drinking Water: Methyl Tertiary Butyl Ether (MTBE).http://www.epa.gov/mtbe/water.htm (11/30/10), Chiu, Y. W. ;LCFS LCI LP LPG MED MRO MSF MTBE MWD MWDOC NAICS NERC NETL

Scown, Corinne Donahue

2010-01-01T23:59:59.000Z

186

{gamma}-aminobutyric acid{sub A} (GABA{sub A}) receptor regulates ERK1/2 phosphorylation in rat hippocampus in high doses of Methyl Tert-Butyl Ether (MTBE)-induced impairment of spatial memory  

SciTech Connect (OSTI)

Experimental and occupational exposure to Methyl Tert-Butyl Ether (MTBE) has been reported to induce neurotoxicological and neurobehavioral effects, such as headache, nausea, dizziness, and disorientation, etc. However, the molecular mechanisms involved in MTBE-induced neurotoxicity are still not well understood. In the present study, we investigated the effects of MTBE on spatial memory and the expression and function of GABA{sub A} receptor in the hippocampus. Our results demonstrated that intraventricular injection of MTBE impaired the performance of the rats in a Morris water maze task, and significantly increased the expression of GABA{sub A} receptor {alpha}1 subunit in the hippocampus. The phosphorylation of ERK1/2 decreased after the MTBE injection. Furthermore, the decreased ability of learning and the reduction of phosphorylated ERK1/2 level of the MTBE-treated rats was partly reversed by bicuculline injected 30 min before the training. These results suggested that MTBE exposure could result in impaired spatial memory. GABA{sub A} receptor may play an important role in the MTBE-induced impairment of learning and memory by regulating the phosphorylation of ERK in the hippocampus.

Zheng Gang; Zhang Wenbin [Department of Occupational and Environmental Health, School of Public Health and Military Preventive Medicine, Fourth Military Medical University, Xi'an 710032 (China); Zhang Yun [465 Hospital, Jilin Medical College, Jilin 132001 (China); Chen Yaoming; Liu Mingchao; Yao Ting; Yang Yanxia; Zhao Fang [Department of Occupational and Environmental Health, School of Public Health and Military Preventive Medicine, Fourth Military Medical University, Xi'an 710032 (China); Li Jingxia; Huang Chuanshu [Nelson Institute of Environmental Medicine, New York University School of Medicine, Tuxedo, New York 10987 (United States); Luo Wenjing [Department of Occupational and Environmental Health, School of Public Health and Military Preventive Medicine, Fourth Military Medical University, Xi'an 710032 (China)], E-mail: luowenj@fmmu.edu.cn; Chen Jingyuan [Department of Occupational and Environmental Health, School of Public Health and Military Preventive Medicine, Fourth Military Medical University, Xi'an 710032 (China)], E-mail: jy_chen@fmmu.edu.cn

2009-04-15T23:59:59.000Z

187

Factors controlling reservoir quality in tertiary sandstones and their significance to geopressured geothermal production. Annual report, May 1, 1979-May 31, 1980  

SciTech Connect (OSTI)

Differing extents of diagenetic modification is the factor primarily responsible for contrasting regional reservoir quality of Tertiary sandstones from the Upper and Lower Texas Gulf Coast. Detailed comparison of Frio sandstones from the Chocolate Bayou/Danbury Dome area, Brazoria County, and Vicksburg sandstones from the McAllen Ranch Field area, Hidalgo County, reveals that extent of diagenetic modification is most strongly influenced by (1) detrital mineralogy and (2) regional geothermal gradients. Vicksburg sandstones from the McAllen Ranch Field area are less stable, chemically and mechanically, than Frio sandstones from the Chocolate Bayou/Danbury dome area. Vicksburg sandstones are mineralogically immature and contain greater proportions of feldspars and rock fragments than do Frio sandstones. Thr reactive detrital assemblage of Vicksubrg sandstones is highly susceptible to diagenetic modification. Susceptibility is enhanced by higher than normal geothermal gradients in the McAllen Ranch Field area. Thus, consolidation of Vicksburg sandstones began at shallower depth of burial and precipitation of authigenic phases (especially calcite) was more pervasive than in Frio sandstones. Moreover, the late-stage episode of ferroan calcite precipitation that occluded most secondary porosity in Vicksburg sandstones did not occur significantly in Frio sandstones. Therefore, regional reservoir quality of Frio sandstones from Brazoria County is far better than that characterizing Vicksburg sandstones from Hidalgo County, especially at depths suitable for geopressured geothermal energy production.

Loucks, R.G.; Richmann, D.L.; Milliken, K.L.

1980-07-01T23:59:59.000Z

188

Exposure to di(n-butyl)phthalate and benzo(a)pyrene alters IL-1{beta} secretion and subset expression of testicular macrophages, resulting in decreased testosterone production in rats  

SciTech Connect (OSTI)

Di(n-butyl)phthalate (DBP) and benzo(a)pyrene (BaP) are environmental endocrine disruptors that are potentially hazardous to humans. These chemicals affect testicular macrophage immuno-endocrine function and testosterone production. However, the underlying mechanisms for these effects are not fully understood. It is well known that interleukin-1 beta (IL-1{beta}), which is secreted by testicular macrophages, plays a trigger role in regulating Leydig cell steroidogenesis. The purpose of this study was to reveal the effects of co-exposure to DBP and BaP on testicular macrophage subset expression, IL-1{beta} secretion and testosterone production. Adult male Sprague-Dawley rats were randomly divided into seven groups; two groups received DBP plus BaP (DBP + BaP: 50 + 1 or 250 + 5 mg/kg/day) four groups received DBP or BaP alone (DBP: 50 or 250 mg/kg/day; BaP: 1 or 5 mg/kg/day), and one group received vehicle alone (control). After co-exposure for 90 days, the relative expression of macrophage subsets and their functions changed. ED2{sup +} testicular macrophages (reactive with a differentiation-related antigen present on the resident macrophages) were activated and IL-1{beta} secretion was enhanced. DBP and BaP acted additively, as demonstrated by greater IL-1{beta} secretion relative to each compound alone. These observations suggest that exposure to DBP plus BaP exerted greater suppression on testosterone production compared with each compound alone. The altered balance in the subsets of testicular macrophages and the enhanced ability of resident testicular macrophages to secrete IL-1{beta}, resulted in enhanced production of IL-1{beta} as a potent steroidogenesis repressor. This may represent an important mechanism by which DBP and BaP repress steroidogenesis.

Zheng Shanjun [Department of High Altitude Military Hygiene, College of High Altitude Military Medicine, Third Military Medical University, Chongqing 400038 (China); Key Laboratory of High Altitude Medicine, Ministry of Education, Chongqing 400038 (China); Key Laboratory of High Altitude Physiology and High Altitude Disease, PLA, Chongqing 400038 (China); Tian Huaijun, E-mail: huaijunt@sohu.co [Department of High Altitude Military Hygiene, College of High Altitude Military Medicine, Third Military Medical University, Chongqing 400038 (China); Key Laboratory of High Altitude Medicine, Ministry of Education, Chongqing 400038 (China); Key Laboratory of High Altitude Physiology and High Altitude Disease, PLA, Chongqing 400038 (China); Cao Jia [Department of Hygienic Toxicology, College of Preventive Medicine, Third Military Medical University, Chongqing 400038 (China); Gao Yuqi, E-mail: yanhua007_007@hotmail.co [Department of High Altitude Military Hygiene, College of High Altitude Military Medicine, Third Military Medical University, Chongqing 400038 (China); Key Laboratory of High Altitude Medicine, Ministry of Education, Chongqing 400038 (China); Key Laboratory of High Altitude Physiology and High Altitude Disease, PLA, Chongqing 400038 (China)

2010-10-01T23:59:59.000Z

189

Taming astrophysical bias in direct dark matter searches  

SciTech Connect (OSTI)

We explore systematic biases in the identification of dark matter in future direct detection experiments and compare the reconstructed dark matter properties when assuming a self-consistent dark matter distribution function and the standard Maxwellian velocity distribution. We find that the systematic bias on the dark matter mass and cross-section determination arising from wrong assumptions for its distribution function is of order ? 1?. A much larger systematic bias can arise if wrong assumptions are made on the underlying Milky Way mass model. However, in both cases the bias is substantially mitigated by marginalizing over galactic model parameters. We additionally show that the velocity distribution can be reconstructed in an unbiased manner for typical dark matter parameters. Our results highlight both the robustness of the dark matter mass and cross-section determination using the standard Maxwellian velocity distribution and the importance of accounting for astrophysical uncertainties in a statistically consistent fashion.

Pato, Miguel [Physik-Department T30d, Technische Universitt Mnchen, James-Franck-Strae, 85748 Garching (Germany); Strigari, Louis E. [Kavli Institute for Particle Astrophysics and Cosmology, Stanford University, Stanford, CA 94305 (United States); Trotta, Roberto [Astrophysics Group and Imperial Centre for Inference and Cosmology, Imperial College London, Blackett Laboratory, Prince Consort Road, London SW7 2AZ (United Kingdom); Bertone, Gianfranco, E-mail: miguel.pato@tum.de, E-mail: strigari@stanford.edu, E-mail: r.trotta@imperial.ac.uk, E-mail: gf.bertone@gmail.com [GRAPPA Institute, University of Amsterdam, Science Park 904, 1090 GL Amsterdam (Netherlands)

2013-02-01T23:59:59.000Z

190

Optofluidic taming of a colloidal dimer with a silicon nanocavity  

SciTech Connect (OSTI)

We report here the optical trapping of a heterogeneous colloidal dimer above a photonic crystal nanocavity used as an on-chip optical tweezer. The trapped dimer consists of a cluster of two dielectric microbeads of different sizes linked by van der Waals forces. The smallest bead, 1??m in diameter, is observed to be preferentially trapped by the nanotweezer, leaving the second bead untrapped. The rotational nature of the trapped dimer Brownian motion is first evidenced. Then, in the presence of a fluid flow, control of its orientation and rotation is achieved. The whole system is found to show high rotational degrees of freedom, thereby acting as an effective flow-sensitive microscopic optical ball joint.

Pin, C.; Renaut, C. [Groupe d'Optique de Champ Proche - LRC CEA nDSM-08-36, Laboratoire Interdisciplinaire Carnot de Bourgogne, UMR CNRS n6303- Universit de Bourgogne, Dijon (France); University Grenoble Alpes, INAC-SP2M-SINAPS, F-38000 Grenoble, France and CEA, INAC-SP2M-SINAPS, F-38000 Grenoble (France); University Grenoble Alpes, CNRS, CEA-Leti Minatec, LTM, F-38054 Grenoble Cedex (France); Cluzel, B., E-mail: benoit.cluzel@u-bourgogne.fr; Fornel, F. de [Groupe d'Optique de Champ Proche - LRC CEA nDSM-08-36, Laboratoire Interdisciplinaire Carnot de Bourgogne, UMR CNRS n6303- Universit de Bourgogne, Dijon (France); Peyrade, D. [University Grenoble Alpes, CNRS, CEA-Leti Minatec, LTM, F-38054 Grenoble Cedex (France); Picard, E.; Hadji, E. [University Grenoble Alpes, INAC-SP2M-SINAPS, F-38000 Grenoble, France and CEA, INAC-SP2M-SINAPS, F-38000 Grenoble (France)

2014-10-27T23:59:59.000Z

191

Taming Coulomb interactions in models for ions and water  

E-Print Network [OSTI]

Extended Simple Point Charge (SPC/E) Model H-bonds in SPC/E water result from frustrated ion pairing Max gCammon, and Rossky, J. Chem. Phys. 80, 4448 (1984) Water and short water models near hydrophobic walls SPC/E water

192

The Taming of Two Alley CATs D. Recoskie  

E-Print Network [OSTI]

Canada, Norway, and Switzerland), Canada - 2 wins (beat Norway and Switzerland, Switzerland - 1 win (beat Norway), Norway - 0 wins. The increasing sequence corresponding to this outcome is 0123 (Norway

Sawada, Joe

193

Taming Density Functional Theory by Coarse-Graining  

E-Print Network [OSTI]

The standard (``fine-grained'') interpretation of quantum density functional theory, in which densities are specified with infinitely-fine spatial resolution, is mathematically unruly. Here, a coarse-grained version of DFT, featuring limited spatial resolution, and its relation to the fine-grained theory in the $L^1\\cap L^3$ formulation of Lieb, is studied, with the object of showing it to be not only mathematically well-behaved, but consonant with the spirit of DFT, practically (computationally) adequate and sufficiently close to the standard interpretation as to accurately reflect its non-pathological properties. The coarse-grained interpretation is shown to be a good model of formal DFT in the sense that: all densities are (ensemble)-V-representable; the intrinsic energy functional $F$ is a continuous function of the density and the representing external potential is the (directional) functional derivative of the intrinsic energy. Also, the representing potential $v[\\rho]$ is quasi-continuous, in that $v[\\rho]\\rho$ is continuous as a function of $\\rho$. The limit of coarse-graining scale going to zero is studied to see if convergence to the non-pathological aspects of the fine-grained theory is adequate to justify regarding coarse-graining as a good approximation. Suitable limiting behaviors or intrinsic energy, densities and representing potentials are found. Intrinsic energy converges monotonically, coarse-grained densities converge uniformly strongly to their low-intrinsic-energy fine-grainings, and $L^{3/2}+L^\\infty$ representability of a density is equivalent to the existence of a convergent sequence of coarse-grained potential/ground-state density pairs.

Paul E. Lammert

2010-08-10T23:59:59.000Z

194

Plasmonics with a Twist: Taming Optical Tornadoes on the Nanoscale  

E-Print Network [OSTI]

This chapter discusses a hydrodynamics-inspired approach to trap and manipulate light in plasmonic nanostructures, which is based on steering optical powerflow around nano-obstacles. New insights into plasmonic nanofocusing ...

Boriskina, Svetlana V.

2013-01-01T23:59:59.000Z

195

Taming the Wild World of Management, Performance and Communication - 13459  

SciTech Connect (OSTI)

Management has evolved a long way from its original meaning of 'governing a horse'. The industrial revolution fostered 'scientific management'; 1930's Hawthorne studies discovered that people's social interactions could alter productivity; and the dawn of the computer age in the post-war 1950's brought general systems theory into management thinking. Today, mobile wireless connectivity aims to transform ever-changing networks of players, mandates, and markets into something that can be 'managed'. So why is there no clear and simple recipe for how to practice management? We talk about financial management, safety management, and operations management, but surely the 'management' part of those endeavors will share the same set of practices. Instead, we are still arguing for 'management' to include everything from developing people to negotiating contracts. A manager's job may include many things, but one of them, the job of management, needs to be nailed down. Three standard practices for managing in a network are developed: (a) support the dialogues that connect people vital to accomplishing a goal or objective; (b) develop and sustain the scoreboards that serve as a road-map to reach the goal; and (c) control the feedback to 'govern the horse'. These three practices are useful for more than reaching goals, as they also support coordinating across boundaries and running productive meetings. The dialogues for productive relationships, scoreboards for goals and deliverables, and feedback for performance together constitute a recipe for managing in a networked world. (authors)

Ford, Laurie [Critical Path Consultants, 3101 Splitrock Road, Columbus Ohio 43221 (United States)] [Critical Path Consultants, 3101 Splitrock Road, Columbus Ohio 43221 (United States)

2013-07-01T23:59:59.000Z

196

TAME SETS, DOMINATING MAPS, AND COMPLEX TORI 1 ...  

E-Print Network [OSTI]

Dec 18, 2002 ... lattice in C and a lattice in Cn?1, then ? is ?-avoidable, and even ...... and Dynamics (Electron. J. Amer. Math. Soc.) 2 (1998), 4555. MR.

2003-02-22T23:59:59.000Z

197

Taming the IXP Network Processor Network Speed Technologies, Inc  

E-Print Network [OSTI]

employs CPS as its in- termediate representation; some of the invariants that this IR guar- antees are essential for the formulation of a practical ILP model. Appel and George used a similar ILP-based technique

Blume, Matthias

198

Frozen Bullets Tame Unruly Edge Plasmas in Fusion Experiment | Princeton  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr Flickr Editor's note:Computing | Argonnechallenging

199

An Application of Algebraic Geometry to Encryption Tame ...  

E-Print Network [OSTI]

of dimension 2:69(1016 ). The dimension is too high to be handled by present technology. To .... new families of asymmetric algorithms. Advances in Cryptology

200

LANXESS Global Butyl Rubber Research Facility  

E-Print Network [OSTI]

Park, in partnership with Surface Science Western $10million City of London Investment in Fraunhofer- fraunhofer Agreement chosen to highlight celebrations for 40th Anniversary of Canada-Germany cooperation fuel cluster in Sarnia-Lambton, said Sarnia Mayor Mike Bradley, noting the Bioindustrial Innovation

Denham, Graham

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

BIOENERGIZEME INFOGRAPHIC CHALLENGE: Tertiary Treatment  

Broader source: Energy.gov [DOE]

This infographic was created by students from Nikola Tesla STEM High School in Redmond, WA, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME...

202

This manuscript downloaded from www.microgrids.et.aau.dk is the preprint of the final paper: L. Meng, F. Tang, M. Savaghebi, J. C. Vasquez, and J. M. Guerrero, "Tertiary control of voltage unbalance compensation for optimal power quality in  

E-Print Network [OSTI]

distributed generators (DGs) equally share the compensation efforts. Tertiary control, which inherently in a multi-bus islanded system by optimally utilizing DGs as distributed compensators and saves. DG Distributed generation. E0 Rated voltage amplitude. E* Reference of voltage amplitude. fc Cut

Vasquez, Juan Carlos

203

VERY LOW MASS STELLAR AND SUBSTELLAR COMPANIONS TO SOLAR-LIKE STARS FROM MARVELS. II. A SHORT-PERIOD COMPANION ORBITING AN F STAR WITH EVIDENCE OF A STELLAR TERTIARY AND SIGNIFICANT MUTUAL INCLINATION  

SciTech Connect (OSTI)

We report the discovery via radial velocity (RV) measurements of a short-period (P = 2.430420 {+-} 0.000006 days) companion to the F-type main-sequence star TYC 2930-00872-1. A long-term trend in the RV data also suggests the presence of a tertiary stellar companion with P > 2000 days. High-resolution spectroscopy of the host star yields T{sub eff} = 6427 {+-} 33 K, log g = 4.52 {+-} 0.14, and [Fe/H] = -0.04 {+-} 0.05. These parameters, combined with the broadband spectral energy distribution (SED) and a parallax, allow us to infer a mass and radius of the host star of M{sub 1} = 1.21 {+-} 0.08 M{sub Sun} and R{sub 1} = 1.09{sup +0.15}{sub -0.13} R{sub Sun }. The minimum mass of the inner companion is below the hydrogen-burning limit; however, the true mass is likely to be substantially higher. We are able to exclude transits of the inner companion with high confidence. Further, the host star spectrum exhibits a clear signature of Ca H and K core emission, indicating stellar activity, but a lack of photometric variability and small vsin I suggest that the primary's spin axis is oriented in a pole-on configuration. The rotational period of the primary estimated through an activity-rotation relation matches the orbital period of the inner companion to within 1.5 {sigma}, suggesting that the primary and inner companion are tidally locked. If the inner companion's orbital angular momentum vector is aligned with the stellar spin axis as expected through tidal evolution, then it has a stellar mass of {approx}0.3-0.4 M{sub Sun }. Direct imaging limits the existence of stellar companions to projected separations <30 AU. No set of spectral lines and no significant flux contribution to the SED from either companion are detected, which places individual upper mass limits of M{sub {l_brace}2,3{r_brace}} {approx}< 1.0 M{sub Sun }, provided they are not stellar remnants. If the tertiary is not a stellar remnant, then it likely has a mass of {approx}0.5-0.6 M{sub Sun }, and its orbit is likely significantly inclined from that of the secondary, suggesting that the Kozai-Lidov mechanism may have driven the dynamical evolution of this system.

Fleming, Scott W.; Ge Jian; De Lee, Nathan; Jiang Peng; Lee, Brian; Nelson, Ben [Department of Astronomy, University of Florida, 211 Bryant Space Science Center, Gainesville, FL 2611-2055 (United States); Barnes, Rory [Department of Astronomy, University of Washington, P.O. Box 351580, Seattle, WA 98195 (United States); Beatty, Thomas G.; Gaudi, B. Scott; Shappee, Benjamin J. [Department of Astronomy, Ohio State University, 140 West 18th Avenue, Columbus, OH 43210 (United States); Crepp, Justin R. [Department of Astronomy, California Institute of Technology, 1200 E. California Blvd., Pasadena, CA 91125 (United States); Esposito, Massimiliano; Femenia, Bruno; Gonzalez Hernandez, Jonay I. [Instituto de Astrofisica de Canarias (IAC), E-38205 La Laguna, Tenerife (Spain); Ferreira, Leticia; Porto de Mello, Gustavo F. [Observatorio do Valongo, Universidade Federal do Rio de Janeiro, Ladeira do Pedro Antonio, 43, CEP: 20080-090, Rio de Janeiro, RJ (Brazil); Gary, Bruce; Hebb, Leslie; Stassun, Keivan [Department of Physics and Astronomy, Vanderbilt University, Nashville, TN 37235 (United States); Ghezzi, Luan, E-mail: scfleming@psu.edu [Laboratorio Interinstitucional de e-Astronomia, LIneA, Rua Gal. Jose Cristino 77, Rio de Janeiro, RJ-20921-400 (Brazil); and others

2012-09-15T23:59:59.000Z

204

Hydrogen sulfide decomposition into hydrogen and sulfur by quinone cycles. First annual report, June 1989-May 1990  

SciTech Connect (OSTI)

The research is evaluating the fundamental mechanisms for recovery of sulfur and H{sub 2} from H{sub 2}S, using mild condition cycles based on oxidation of H{sub 2}S by quinones. During this first year, the research focused on the reaction of H{sub 2}S with tertiary butyl anthraquinone to form tertiary butyl anthrahydroquinone. The progress achieved included extending the quinone conversion from 60-80% to complete conversion, significantly increasing the rate of conversion by varying the solvent, and developing a proposed mechanism for this part of the process.

Plummer, M.A.

1990-06-01T23:59:59.000Z

205

A study of the multiplication and rooting in vitro of shoot tips from mature guayule (Parthenium argentatum Gray) plants  

E-Print Network [OSTI]

10 mL Glacial acetic acid overnight Dehydration Series, Tertiary Butyl Alcohol 1. 50% Dehydration Solution 50 mL distilled water 40 mL 95% Ethyl alcohol 10 mL Tertiary butyl alcohol (t-BuOH) . 2. 70% dehydration solution 30 mL distilled water... alcohol 75 mL -BuOH 2 hours overnight 1 hour 1 hour 1 hour 37 6. Pure t-BuOH 7. Pure t-BuOH 8. Pure t-BuOH 9. Equal volumes t-BuOH and parrifin oil 1 hour overnight 1 hour 24 hours 10. Fill small vials half full with melted parrifin...

Callin, Jeffrey Michael

1990-01-01T23:59:59.000Z

206

Evaluation of organic matter, Subsurface temperature nd pressure with regard to gas generation in low-permeability upper cretaceous and lower tertiary sandstones in Pacific Creek area, sublette and Sweetwater Counties, Wyoming  

SciTech Connect (OSTI)

Investigations of a sequence of Upper Cretaceous and lower Tertiary rocks in the Pacific Creek area of Wyoming show that studies of organic matter content, type, and maturity in conjunction with subsurface temperature and reservoir pressure, will help define prospective gas-saturated intervals and delineate areas of maximum gas-resource potential. The onset of overpressuring occurs at about 11,600 ft (3,500 m), near the base of the Upper Cretaceous Lance Formation. Drill stem test data indicate that at about 12,800 ft (3,900 m) the pressure gradient is as high as 0.84 psi/ft (19.0 kPa/m). The development of overpressuring probably due to the active generation of large amounts of wet gas. Nearly coincident with the top of overpressuring is a reversal of the spontaneous potential (SP) curve that is thought to be caused by a reduction of formation water salinity. The very small amounts of water produced during thermochemical decomposition of organic matter and the dehydration of clays during clay transformation may provide enough low-salinity water to effictively dilute the original formation water to a degree that the formation water resistivity is greater than mud filtrate resistivity. Microscopic and geochemical evaluation of organic matter shows that they are dominantly humic-type kerogen. Total organic carbon contents of 26 samples range from 0.25 to 7.84 weight percent. Most samples exceed 0.5 percent organic carbon and the average is 1.38 percent. A vertial profile of organic maturation, shows that the top of overpressuring and beginning of important wet-gas generation occur at vitrinite reflectance values of 0.74 to 0.86. (JMT)

Law, B.E.; Spencer, C.W.; Bostick, N.H.

1980-04-01T23:59:59.000Z

207

Role of Volatilization in Changing TBA and MTBE Concentrations at  

E-Print Network [OSTI]

a low affinity for gasoline (low Kfw, Table 1). Therefore, minute amounts of TBA in the MTBE blended tertiary butyl ether (MTBE) added to gasoline. Frequent observations of high TBA, and especially rising TBA/MTBE concentration ratios, in groundwater at gasoline spill sites are generally attributed to microbial conversion

208

Water Research 37 (2003) 37563766 Seasonal and daily variations in concentrations of methyl-  

E-Print Network [OSTI]

by volume to gasoline from November to February, and blending 11% MTBE by volume during the rest of the year; accepted 24 March 2003 Abstract Methyl-tertiary-butyl ether (MTBE), an additive used to oxygenate gasoline of gasoline-powered watercraft. This paper documents and explains both seasonal and daily variations in MTBE

Toran, Laura

209

Motor Gasoline Outlook and State MTBE Bans  

Reports and Publications (EIA)

The U.S. is beginning the summer 2003 driving season with lower gasoline inventories and higher prices than last year. Recovery from this tight gasoline market could be made more difficult by impending state bans on the blending of methyl tertiary butyl ether (MTBE) into gasoline that are scheduled to begin later this year.

2003-01-01T23:59:59.000Z

210

untitled  

Gasoline and Diesel Fuel Update (EIA)

3,054 Fuel Ethanol (FE) 1,019 97 1,116 2,133 528 393 3,054 Methyl Tertiary Butyl Ether (MTBE) 561 0 561 0 0 0 0 All Other Oxygenates a 0 0 0 0 0 0 0 Motor Gasoline Blend. Comp....

211

PSA Vol 1 Tables Revised Ver 2 Print.xls  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

11,352 13 1,309 15,181 42 Fuel Ethanol (FE) 0 0 0 0 0 0 0 Methyl Tertiary Butyl Ether (MTBE) 234 928 10,251 0 21 11,434 31 Other Oxygenates 955 390 1,101 13 1,288 3,747 10 Motor...

212

By Martman Cohen News Office staff  

E-Print Network [OSTI]

tertiary butyl ether, or MTBE (another hazardous gasoline component that is hazardous to health the benzene-removal technol- ogy to sites contaminated with MTBE. That gasoline additive tends to mi- grate of MTBE- contaminated sites from around the U.S. By simulating an anaerobic pro- cess similar to what

Lovley, Derek

213

UMass builds bugs to eat MTBE ByAuriaCimino  

E-Print Network [OSTI]

UMass builds bugs to eat MTBE ByAuriaCimino STAfFWRITER An area university's process to destroy with methyl tertiary butyl ether (MTBE), which is found in gasoline. Once the first field trial is complete in particular has suffered from MTBE contamination because of the abundance of groundwater in the state, said

Lovley, Derek

214

untitled  

Gasoline and Diesel Fuel Update (EIA)

Fuel Ethanol (FE) 1,229 108 1,337 2,369 724 497 3,590 Methyl Tertiary Butyl Ether (MTBE) 292 0 292 0 0 0 0 All Other Oxygenates a 0 0 0 0 0 0 0 Motor Gasoline Blend. Comp....

215

Simultaneous Efficiency, NOx, and Smoke Improvements through Diesel/Gasoline Dual-Fuel Operation in a Diesel Engine  

E-Print Network [OSTI]

or liquefied petroleum gas, natural gas, biogas, hydrogen, and alcohols such as methanol, ethanol, iso-propanol, and n-butanol), and fuel additives (MTBE or methyl tertiary-butyl ether, H2O2 or hydrogen peroxide, 2-EHN or ethylhexyl nitrate and DTBP or di...

Sun, Jiafeng

2014-08-05T23:59:59.000Z

216

Tertiary paleomagnetic results from east Kalimantan  

E-Print Network [OSTI]

? Early Miocene basalt, shale, and andesite yield a mean reversed direction of D = 182. 0', I = -2. 2'(oss = 11. 0', k = 22. 8) and a paleomagnetic pole 1 = 87. 8'N, P = 173. 5'E (Ass ? 7. 0', K = 54. 8). Rock magnetic studies suggest that the carrier... for his guidance in the laboratory and writing style and for keeping me honest. I am indebted to Dr. Laura Stokking of Ocean Drilling Program for her guidance in rock magnetism. I thank my good friends Dean Merrill, who dedicated most of his time...

Lumadyo, Leonard E. D

1991-01-01T23:59:59.000Z

217

Later Tertiary Leporidae of North America  

E-Print Network [OSTI]

Saskatchewan. Generic characters. Compared with Megalagus brachyodon, cheek-teeth less hypsodont, molarization of premolars less advanced, molars less reduced, and maxilla and mandibular ramus narrower in premolar region; P3-P4 each having shallow hypostria... the Myton Pocket in Utah and M. wyomingensis from Badwater Creek, Wyoming, specimens from the Wagonhound member of the Uinta Eocene, the Duchesne River (Rand- lett horizon), and the Swift Current Creek beds of Saskatchewan have been referred to this genus...

Dawson, M. R.

1958-05-01T23:59:59.000Z

218

Ion exchange as a tertiary treatment  

E-Print Network [OSTI]

that these treatment methods are capable of removing an appreciable amount of objection? able dissolved organic and inorganic materi aJ s from the final effluent. Color and turbidity were greatly reduced and an appreciable amount of the suspended solids were... Demand Re Resin A General Anion mg. /1. MLVSS psi gpm Milligrams per I. iter Mixed Liquor Volatile Suspended Solids Pounds per Square Inch Gallons per Minute. mm Mi llimeters kgr meq ml Kilogram Milliequilavent Millimeter S. S. BV...

Westervelt, Ronald David

1968-01-01T23:59:59.000Z

219

Apolipoprotein AI tertiary structures determine stability and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone by E-mailRadioimmunotherapy of Cancers. | EMSLbinding

220

Synthesis and characterization of hybrid materials based on 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid and Dawson-type tungstophosphate K{sub 7}[H{sub 4}PW{sub 18}O{sub 62}].18H{sub 2}O and K{sub 6}[P{sub 2}W{sub 18}O{sub 62}].13H{sub 2}O  

SciTech Connect (OSTI)

In this study, we synthesized hybrid materials using well-Dawson polyoxometalates (POMs), K{sub 7}[H{sub 4}PW{sub 18}O{sub 62}].18H{sub 2}O or K{sub 6}[P{sub 2}W{sub 18}O{sub 62}].13H{sub 2}O and a room temperature ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF{sub 4}]). K, W, P and CHN elemental analysis showed that one mole of [H{sub 4}PW{sub 18}O{sub 62}]{sup 7-} reacts with 6 moles of BMIM{sup +} and one mole of [P{sub 2}W{sub 18}O{sub 62}]{sup 6-} reacts with 4 moles of BMIM{sup +} to form, respectively, K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} and K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62}. X-ray diffraction illustrated amorphous structure of the hybrid materials. FT-IR spectra showed the presence of both 1-butyl-3-methylimidazolium cation and the Dawson anion. TG analysis displayed a relative thermal stability of the hybrid materials compared to the parents Dawson POMs. Cyclic voltammetry showed that the reduction peak potentials of the Dawson anion in the hybrid materials shift towards negative values and the shift is more pronounced for K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} compared to K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62}. This was attributed to a decrease in the acidity of the Dawson POM anion in the hybrid material. -- Graphical abstract: Powder XRD patterns of (a) PW{sub 18}, (b) K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62}, (c) P{sub 2}W{sub 18}, and (d) K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62}. Display Omitted Research highlights: {yields} 1-butyl-3-methylimidazolium tetrafluoroborate([BMIM][BF{sub 4}]) reacts with K{sub 7}[H{sub 4}PW{sub 18}O{sub 62}].18H{sub 2}O to form K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62}. {yields} [BMIM][BF{sub 4}] reacts with K{sub 6}[P{sub 2}W{sub 18}O{sub 62}].13H{sub 2}O to form K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62}. {yields} K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} and K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62} displayed amorphous structures. {yields} K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} and K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62} illustrated low water content. {yields} K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} and K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62} showed improved thermal stability.

Ammam, Malika, E-mail: m78ammam@yahoo.f [Department of Metallurgy and Materials Engineering (MTM), K.U Leuven, Kasteelpark Arenberg 44, B-3001 Heverlee (Belgium); Fransaer, Jan [Department of Metallurgy and Materials Engineering (MTM), K.U Leuven, Kasteelpark Arenberg 44, B-3001 Heverlee (Belgium)

2011-04-15T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Reactivity of the Quinone Methide of Butylated hydroxytoluene in Solution  

E-Print Network [OSTI]

BHT is a common antioxidant in pharmaceutical formulations and when oxidized it forms a quinone methide (QM). QM is a highly reactive electrophilic species which can undergo nucleophilic addition. This research investigated ...

Willcockson, Maren Gulsrud

2011-08-31T23:59:59.000Z

222

Determination of methyl tert. butyl ether (MTBE) in gasoline  

SciTech Connect (OSTI)

A GLC-acid extraction method is described for the determination of MTBE in gasolines. The method consists of a programmed GLC analysis starting at about room temperature conducted before and after extraction with cold 85% phosphoric acid. This treatment results in the preferential solubility of ethers and other oxygenated compounds while minimizing the reaction of olefins and aromatics which may be present in the gasolines. Plotting various known concentrations of MTBE in gasolines against the concentrations determined in the same samples by the authors methodology results in a straight line relationship. The concentration of MTBE in any sample of gasoline may thus be determined using their GLC-extraction procedure and the calibration line. The analysis can accommodate a wide choice of standard GLC columns and programs. 2 refs., 1 fig., 1 tab.

Feldman, J.; Orchin, M. (Univ. of Cincinnati, OH (United States))

1993-02-01T23:59:59.000Z

223

Conversion of Lignocellulosic Biomass to Ethanol Butyl Acrylate  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTieCelebrate EarthEnergy Contractor&3-1Program Managers

224

Renormalization of the strongly attractive inverse square potential: Taming the singularity  

E-Print Network [OSTI]

Quantum anomalies in the inverse square potential are well known and widely investigated. Most prominent is the unbounded increase in oscillations of the particle's state as it approaches the origin when the attractive coupling parameter is greater than the critical value of 1/4. Due to this unphysical divergence in oscillations, we are proposing that the interaction gets screened at short distances making the coupling parameter acquire an effective (renormalized) value that falls within the weak range 0 to 1/4. This prevents the oscillations form growing without limit giving a lower bound to the energy spectrum and forcing the Hamiltonian of the system to be self-adjoint. Technically, this translates into a regularization scheme whereby the inverse square potential is replaced near the origin by another that has the same singularity but with a weak coupling strength. Here, we take the Eckart as the regularizing potential and obtain the corresponding solutions (discrete bound states and continuum scattering states).

A. D. Alhaidari

2014-06-14T23:59:59.000Z

225

Taming Wild Horses: The Need for Virtual Time-based Scheduling of VMs in Network Simulations  

SciTech Connect (OSTI)

The next generation of scalable network simulators employ virtual machines (VMs) to act as high-fidelity models of traffic producer/consumer nodes in simulated networks. However, network simulations could be inaccurate if VMs are not scheduled according to virtual time, especially when many VMs are hosted per simulator core in a multi-core simulator environment. Since VMs are by default free-running, on the outset, it is not clear if, and to what extent, their untamed execution affects the results in simulated scenarios. Here, we provide the first quantitative basis for establishing the need for generalized virtual time scheduling of VMs in network simulators, based on an actual prototyped implementations. To exercise breadth, our system is tested with multiple disparate applications: (a) a set of message passing parallel programs, (b) a computer worm propagation phenomenon, and (c) a mobile ad-hoc wireless network simulation. We define and use error metrics and benchmarks in scaled tests to empirically report the poor match of traditional, fairness-based VM scheduling to VM-based network simulation, and also clearly show the better performance of our simulation-specific scheduler, with up to 64 VMs hosted on a 12-core simulator node.

Yoginath, Srikanth B [ORNL; Perumalla, Kalyan S [ORNL; Henz, Brian J [ORNL

2012-01-01T23:59:59.000Z

226

E-Print Network 3.0 - algebras tamely laced Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Claus Michael - Fakultt fr Mathematik, Universitt Bielefeld Collection: Mathematics 2 Combinatorial Representation Theory History and Future Summary: we work over an...

227

SciTech Connect: Taming the Grid: Dynamic Load Composition Quantification  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBi (2) Sr (2) Cawith EXO-200 SearchGalaxy Spectra

228

A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience hands-onASTROPHYSICSHe β-ResearchNewDependent Viscosity |Plasmas

229

A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience hands-onASTROPHYSICSHe β-ResearchNewDependent Viscosity

230

The tame and the wild valuation 13.1 Absolute ramification theory  

E-Print Network [OSTI]

; v) be a henselian field. The inertia field of the normal extension ( ~ KjK; v) (or equivalently) and denoted by (K; v) i or by (K i ; v i ). Similarly, the ramification field of ( ~ KjK; v) will be called

Kuhlmann, Franz-Viktor

231

Texas plant will use new process to coproduce propylene oxide, MTBE  

SciTech Connect (OSTI)

Texaco Chemical Co. is building a $400 + million facility to produce 1.2 billion lb/year (14,000 b/d) methyl tertiary butyl ether (MTBE) and 400 million lb/year (about 500 metric tons/day) propylene oxide (PO). The facility-under construction at Port Neches, Tex.-will utilize a newly developed Texaco process that coproduces the two chemicals. The process produces propylene oxide and tertiary butyl alcohol (TBA) from the reaction of isobutane with oxygen in one step, then in a second step with propylene. The TBA is then reacted with methanol in a one-step process that synthesizes MTBE. The paper describes the Port Neches facilities, construction schedule, feedstocks, product uses, and auxiliary equipment.

Rhodes, A.K.

1993-08-30T23:59:59.000Z

232

Equilibrium thermodynamic analysis of liquid-phase ethyl tert-butylether (ETBE) synthesis  

SciTech Connect (OSTI)

Methyl tertiary butyl ether (MTBE) is now the second largest volume organic chemical, only behind ethylene, produced in the U.S. This is remarkable since its commercial production began barely two decades ago. Although MTBE is currently the industry standard, it has been proposed that ethanol and other renewable additives make up to 30% of the oxygenate market. As a result, ethyl tertiary butyl ether (ETBE, or 2-ethyoxy 2-methyl propane), derived from renewable ethanol and isobutylene, has emerged as a promising new oxygenate. ETBE also has a somewhat lower blending Reid vapor pressure as well as a higher octane number than MTBE. This paper describes the thermodynamic equilibrium constant for the production of ETBE.

Jensen, K.L.; Datta, R. [Univ. of Iowa, Iowa City, IA (United States)

1994-12-31T23:59:59.000Z

233

Two US markets, or one? How the MTBE-gasoline relationship is evolving  

SciTech Connect (OSTI)

This issue of Energy Detente features the price sensitivity of Methyl Tertiary Butyl Ether. Data is presented for US wholesale gasoline prices vs. MTBE for the 20-month period beginning in June 1994 and ending in January 1996, and the data is discussed. Also contained in this issue is the refining netback data and the fuel price/tax data for the period ending January 5, 1996.

NONE

1996-01-26T23:59:59.000Z

234

Statoil outlines MTBE development program  

SciTech Connect (OSTI)

This paper reports that Norway's state oil company Den Norkse state Oljeselskap AS has outlined plans to become one of the major European producers of methyl tertiary butyl ether in the 1990s. Statoil predicts European demand for MTBE will jump to 4.5 million metric tons/year by 2000 from 2.5 million tons in 1990. Europe currently is a net importer of MTBE, with a productive capacity of 2.2 million tons/year.

Not Available

1991-11-25T23:59:59.000Z

235

Current-driven flow instabilities in large-scale liquid metal batteries, and how to tame them  

E-Print Network [OSTI]

The use of liquid metal batteries is considered as one promising option for electric grid stabilisation. While large versions of such batteries are preferred in view of the economies of scale, they are susceptible to various magnetohydrodynamic instabilities which imply a risk of short-circuiting the battery due to the triggered fluid flow. Here we focus on the current driven Tayler instability and give critical electrical currents for its onset as well as numerical estimates for the appearing flow structures and speeds. Scaling laws for different materials, battery sizes and geometries are found. We further discuss and compare various means for preventing the instability.

Weber, Norbert; Stefani, Frank; Weier, Tom

2013-01-01T23:59:59.000Z

236

Understanding the Benefits of Dispersed Grid-Connected Photovoltaics: From Avoiding the Next Major Outage to Taming Wholesale Power Markets  

SciTech Connect (OSTI)

Thanks to new solar resource assessment techniques using cloud cover data available from geostationary satellites, it is apparent that grid-connected PV installations can serve to enhance electric grid reliability, preventing or hastening recovery from major power outages and serving to mitigate extreme price spikes in wholesale energy markets. (author)

Letendre, Steven E.; Perez, Richard

2006-07-15T23:59:59.000Z

237

PUBLISHED ONLINE: 26 FEBRUARY 2014 | DOI: 10.1038/NCLIMATE2120 Taming hurricanes with arrays of o shore  

E-Print Network [OSTI]

models (Geophysical Fluid Dynamic Laboratory (GFDL) and Hurricane Weather Research and Fore- casting to themselves? This study uses an advanced climate­weather computer model that correctly treats the energy only right behind the walls, and limit the access of populations to coastal zones. Large arrays of wind-wave

238

alcohols aromatic tertiary: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of alcohol and drugs. 6. Describe the personality traits of the alcoholic and drug addict. 7. Describe the treatment and rehabilitation of the alcoholic and drug addict. 8....

239

Freezing-induced perturbation of tertiary structure of monoclonal antibody  

E-Print Network [OSTI]

336 338 340 342 344 -30 -20 -10 0 10 20 Temperature (C) E m i ssi o n p eak p o s i t i o n ( n m) 332 334 336 338 340 342 344 -30 -20 -10 0 10 20 Temperature (C) E m is s i on pe a k pos it ion ( n m ) IgG Pre-frozen 20C Frozen -30C Post... -30 -20 -10 0 10 20 Temperature (C) E m i ssi o n p eak p o s i t i o n ( n m) IgG+KCl Pre-frozen 20C Frozen -30C Post-thawed 20C Peak shift due to freez- ing pH8 338.4 ? 0.1 nm 338.7 ? 0.0 nm 338.0 ? 0.1 nm 0.3 nm pH3 340.7 ? 0.5 nm...

Liu, Lu; Kueltzo, L. A.; Jones, L. S.; Carpenter, J. F.

2006-10-25T23:59:59.000Z

240

aliphatic tertiary amines: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of the system. If so, all close binaries should be members of triple (or higher-order) systems. As a test of this prediction, we present a search for the signature of third...

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Low Barrier Hydrogen Bonds in Acyclic Tertiary Diamines  

E-Print Network [OSTI]

B: synthesis of diamide with phosphorous pentoxide, and C:synthesis uses phosphorous pentoxide and dimethylformamide (B: synthesis of diamide with phosphorous pentoxide, and C:

Khodagholian, Sevana

2010-01-01T23:59:59.000Z

242

african tertiary institution: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Batchelor Institute and Charles Darwin 9 "Criminally Unjust: Young People and the Crisis of Mass Incarceration" Conference presented by The Africana Criminal Justice Project...

243

african tertiary teaching: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Archive Summary: Welcome Research InterestsActivity Links to Publications; Courses ... EDCI 425: Teaching of Mathematics in Secondary Schools ... Most material for...

244

Process for tertiary oil recovery using tall oil pitch  

DOE Patents [OSTI]

A process and compositions for enhancing the recovery of acid crudes are disclosed. The process involves injecting caustic solutions into the reservoir to maintain a pH of 11 to 13. The fluid contains an effective amount of multivalent cation for inhibiting alkaline silica dissolution with the reservoir. A tall oil pitch soap is added as a polymeric mobility control agent. (DMC)

Radke, C.J.

1983-07-25T23:59:59.000Z

245

Radiation chemistry of alternative fuel oxygenates -- Substituted ethers  

SciTech Connect (OSTI)

The electron beam process, an advanced oxidation and reduction technology, is based in the field of radiation chemistry. Fundamental to the development of treatment processes is an understanding of the underlying chemistry. The authors have previously evaluated the bimolecular rate constants for the reactions of methyl tert-butyl ether (MTBE) and with this study have extended their studies to include ethyl tert-butyl ether (ETBE), di-isopropyl ether (DIPE) and tert-amyl methyl ether (TAME) with the hydroxyl radical, hydrogen atom and solvated electron using pulse radiolysis. For all of the oxygenates the reaction with the hydroxyl radical appears to be of primary interest in the destruction of the compounds in water. The rates with the solvated electron are limiting values as the rates appear to be relatively low. The hydrogen atom rate constants are relatively low, coupled with the low yield in radiolysis, they concluded that these are of little significance in the destruction of the alternative fuel oxygenates (and MTBE).

Mezyk, S. P.; Cooper, W. J.; Bartels, D. M.; Tobien, T.; O'Shea, K. E.

1999-11-15T23:59:59.000Z

246

Impacts of Ethanol on Anaerobic Production of Tert-Butyl Alcohol (TBA) from Methyl Tert-Butyl Ether (MTBE) in Groundwater  

E-Print Network [OSTI]

Project title: Impacts of Ethanol on Anaerobic Production oftert-butanol (TBA). As ethanol is being promoted as ainvestigate the effect of ethanol release on existing MTBE

Scow, K M; MacKay, Douglas

2008-01-01T23:59:59.000Z

247

The effects of hand-rearing fallow deer in a captive environment  

E-Print Network [OSTI]

21 Hansel and his mother, a non-tame doe . 25 22 Herman and his mother, a tame doe 26 23 The stillborn fawn's mother, a non-tame does . . 27 24 Kieran and her mother, a non-tame doe . 28 25 26 27 Gretel and her mother, a non-tame doe Penelope... birth 8 IIj Figure 23: The stillborn fawn' s mother: a non-tame doe. 28 Record 8: Kieran FAWN Ear tag color and number: white 60 Date of birth: 10/19/98 Sex: F Coat color: chocolate Hours after birth when pulled from mother: 27 Date of first...

Healy, Allison Anne

2013-02-22T23:59:59.000Z

248

THERMODYNAMICS OF EXTRACTION OF NITRIC ACID BY TRI-n-BUTYL PHOSPHATE--HYDROCARBON DILUENT SOLUTIONS  

E-Print Network [OSTI]

the mean act ivi ty coefficient T of TBP and TBP.H20 i n the acid-free, water-saturated organic phase

Wallace Davis

1961-01-01T23:59:59.000Z

249

Safe conditions for contacting nitric acid or nitrates with tri-n-butyl phosphate (TBP)  

SciTech Connect (OSTI)

In response to a request from DOE-SR, the current state of knowledge of the reactions between TBP and aqueous nitrate solutions is critically reviewed, and recommendations are made for the safe operation of SRS separations equipment in which this combination of chemicals may be present. The existing limits for evaporation are validated. Guidelines are presented for cases in which general limits do not apply. The rate of reaction between nitric acid and TBP appears to be controlled by the rate of TBP hydrolysis. The hydrolysis reaction produces dibutyl phosphate and n-butanol. The hydrolysis rate is a strong function of temperature, and becomes very fast at temperatures in the range 130{degrees} to 150{degrees}C. The resulting n-butanol is volatile at high temperatures, boiling at 117.5{degrees}C, but is also subject to exothermic oxidation by nitric acid or nitrates. If oxidation occurs before the n-butanol evaporates, the heat of oxidation may exceed local cooling by convection. The resulting heating will further accelerate the reaction, leading to an energetic runaway and possibly (in confined systems) an explosion. Extensive experiments and practice have shown that in a well-mixed and well-vented aqueous system such as an evaporator, at moderate acidities and temperatures below 130{degrees}C, the heat of reaction is adequately removed by vaporization of steam. In general, the heating will be so slow that natural processes provide adequate cooling at temperatures below 80{degrees}C. Above this temperature, care should be taken to ensure that adequate cooling is available for the amount of TBP that may be present. Experiments suggest that in well-ventilated systems n-butanol evaporation and convective cooling are sufficient to control the reaction at temperatures up to 120{degrees}C.

Hyder, M.L

1994-01-01T23:59:59.000Z

250

Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 1.  

E-Print Network [OSTI]

because of its low cost and blending characteristics. Depending on the season, reformulated gasoline of reactor per hour, a value comparable to other gasoline constituents. Such high performance could enhancer in gasoline. The use of MTBE increased rapidly after the 1990 Clean Air Act Amendments required

251

Optical fibers by butyl methacrylate reactive extrusion Berthet Romuald, Chalamet Yvan, Taha Mohamed*, Zerroukhi Amar  

E-Print Network [OSTI]

limitations. Reactive extrusion experiments were carried out in a twin-screw extruder and the effect optical fibbers, polymethacrylate. Introduction Twin screw extruders are playing an increasing role of reactive extrusion is explained by the different advantages offered by the use of the twin-screw extruders

Paris-Sud XI, Université de

252

E-Print Network 3.0 - aluminum triso-ethylphosphonate butylate...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Resistance Advancements: Dr. Dragan CurcijaDr. Dragan Curcija Summary: -Expanded (EPS) Pine or Douglas Fir Frame Cavity Polyfoam tape Urethane Sealant Silicone...

253

The K-band microwave spectra of t-butyl halides  

E-Print Network [OSTI]

result of centrifugal distortion of the mole? cule, and (c) a group of lines from either the hindered internal rotation of the CH^ groups or torsional vibration along the C-CH-j bonds, or both. In an attempt to determine the sources of the indi... absorption lines in the microwave re? gion were reported by Cleeton and Williams (2) in 1934* No more papers on this subject appeared in the literature until 1946. Since this latter date, however, some 400 papers relating to miorowave absorption spectra...

Crook, George Hardy

1954-01-01T23:59:59.000Z

254

E-Print Network 3.0 - acaricide tri-n-butyl tin Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of California, Davis; Seybold, Steven J. - Departments of Entomology and Forest Resources, University of Minnesota Collection: Biotechnology ; Environmental Sciences and...

255

Saponification rates of isomeric butyl esters in aqueous 1,4-dioxane  

E-Print Network [OSTI]

. Jensen, G. M. Watson and J. B. Beckham, Anal. Chem., 23, 1711-8(1951). (21). F. Daniels, J. H. Mathews and J, W. Williams, "Experimental Physical Chemistry," 3rd. ed., McGraw-Hill Book Co., Inc., New York, N. Y., 19*4-1, p. 167. (22). S. Glasstone...

Ruhnke, Edward Vincent

1954-01-01T23:59:59.000Z

256

Oxidative desulfurization of dibenzothiophene with tert-butyl hydro peroxide in a photochemical micro-reactor.  

E-Print Network [OSTI]

??Sulfur content in fuels is an increasingly critical environmental issue. Hydrodesulfurization removes sulfur from hydrocarbons; however, further desulfurization is necessary in fuels. New methods are (more)

Hebert, Eilleen M.

2007-01-01T23:59:59.000Z

257

Thermal and Photochemistry of tert-Butyl Iodide on Rutile TiO(110). | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 andThe1 MembersStability of MnBi

258

E-Print Network 3.0 - antagonist o-4-ethoxyl-butyl-berbamine...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Kim, Elliot Hawkes, Kyujin Cho, Matthew Jolda, Joe Foley and Robert Wood Summary: of micro-coil spring, we present a novel mesh-worm prototype that utilizes bio-inspired...

259

acid t-butyl ester: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

stable thermodynamically and hydration free energies obtained Yu, Fangqun 189 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

260

E-Print Network 3.0 - acetone-butyl alcohol fermentation Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

then extended this approach to alcoholic fermentation and demonstrated clearly that the process required... the presence of yeast. Alcoholic fermentation was ... Source: Centre...

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

New Jersey Water Resources Research Institute Annual Technical Report  

E-Print Network [OSTI]

of research. Bonventre and her advisor researched the effects of MTBE, ETBE and TAME, three common gasoline

262

California's Move Toward E10 (released in AEO2009)  

Reports and Publications (EIA)

In Annual Energy Outlook 2009, (AEO) E10a gasoline blend containing 10% ethanolis assumed to be the maximum ethanol blend allowed in California erformulated gasoline (RFG), as opposed to the 5.7% blend assumed in earlier AEOs. The 5.7% blend had reflected decisions made when California decided to phase out use of the additive methyl tertiary butyl ether in its RFG program in 2003, opting instead to use ethanol in the minimum amount that would meet the requirement for 2.0% oxygen content under the Clean Air Act provisions in effect at that time.

2009-01-01T23:59:59.000Z

263

Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model (Released in the STEO March 1998)  

Reports and Publications (EIA)

The blending of oxygenates, such as fuel ethanol and methyl tertiary butyl ether (MTBE), into motor gasoline has increased dramatically in the last few years because of the oxygenated and reformulated gasoline programs. Because of the significant role oxygenates now have in petroleum product markets, the Short-Term Integrated Forecasting System (STIFS) was revised to include supply and demand balances for fuel ethanol and MTBE. The STIFS model is used for producing forecasts in the Short-Term Energy Outlook. A review of the historical data sources and forecasting methodology for oxygenate production, imports, inventories, and demand is presented in this report.

1998-01-01T23:59:59.000Z

264

MTBE, Oxygenates, and Motor Gasoline (Released in the STEO October 1999)  

Reports and Publications (EIA)

The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an increase in MTBE production between 1990 and 1994. MTBE demand increased from 83,000 in 1990 to 161,000 barrels per day in 1994. The reformulated gasoline (RFG) program provided a further boost to oxygenate blending. The MTBE contained in motor gasoline increased to 269,000 barrels per day by 1997.

1999-01-01T23:59:59.000Z

265

Evaluation and Optimization of MTBE Biodegradation in Aquifers, Final Report  

SciTech Connect (OSTI)

This study was focused on meeting the following objectives concerning the process of methyl tertiary butyl ether (MTBE) biodegradation, with the goal of optimizing this process in situ: 1. Assess whether intrinsic bioattenuation of MTBE is feasible under aerobic conditions across several contaminated sites. 2. Determine the effect of co-contaminants, specifically water-soluble gasoline components (most notably benzene, toluene, ethylbenzene and xylenes [BTEX]) on MTBE biodegradation. 3. Determine whether microbial and/or chemical factors contribute to different MTBE degradative activities. 4. Isolate and characterize MTBE-degrading microorganisms from sediments in which MTBE biodegradation was observed.

Legler, T; Balser, L; Koester, C; Wilson, W

2004-02-13T23:59:59.000Z

266

Austrian refiner benefits from advanced control  

SciTech Connect (OSTI)

OeMV-AG Energy implemented advanced process controls on 27 units at its refinery in Schwechat, Austria. A variety of controls were implemented on the butadiene and methyl tertiary butyl ether (MTBE) units in January 1993. After more than 1 year of operation, the butadiene/MTBE project has shown a number of benefits, including reduced energy consumption and increased capacity in both units. The paper discusses the process, advanced control, the simple model predictive controller, control objectives, the butadiene unit, the MTBE unit, and benefits of the advanced controllers.

Richard, L.A.; Spencer, M. [Setpoint Inc., Houston, TX (United States); Schuster, R.; Tuppinger, D.M.; Wilmsen, W.F. [OeMV-AG Energy, Schwechat (Austria)

1995-03-20T23:59:59.000Z

267

Petrochem industry expands North American MTBE capacity  

SciTech Connect (OSTI)

This paper reports that petrochemical manufacturers continue to increase methyl tertiary butyl ether (MTBE) capacity in North America. The action reflects refiners' reformulation of gasoline to help reduce auto emissions. Demand for gasoline blending oxygenates such as MTBE is expected to increase as U.S. refiners reconfigure processing trains to produce fuels meeting requirements of the Clean Air Act amendments of 1990. Recent progress includes plans to build an MTBE plant in Mexico and start-ups of plants on the U.S. Gulf Coast and in Canada.

Not Available

1992-10-05T23:59:59.000Z

268

Economics of new MTBE design  

SciTech Connect (OSTI)

Methyl Tertiary Butyl Ether (MTBE) is produced industrially by catalytic reaction between methanol and isobutene. The catalyst that is widely used is an acidic ion exchange resin. This article explores design and economics when sulfuric acid is the catalyst. The profitability of MTBE production depends mainly on the cost of butenes and methhanol. Thus, the example shows MTBE made with a catalyst of sulfuric acid was profitable at a Saudi Arabian location, even though it was not profitable at a U.S. Gulf Coast location.

Al-Jarallah, A.M.; Lee, A.K.K.

1988-07-01T23:59:59.000Z

269

MTBE: Wild card in groundwater cleanup  

SciTech Connect (OSTI)

Subsurface releases of the gasoline oxygenate, methyl tertiary butyl ether (MTBE) seriously compromise the remediation and closure of properties that have ground water contaminated with BTEX and other conventional fuel hydrocarbon components. Although a manageable protocal for BTEX remediation is being set up, the MTBE problem continues to be difficult. This article discusses a new magnesium peroxide compound which could be part of the solution. Covered topics include oxygen release compound (ORC) enhance bioremediation and the role of oxygen and ORC in MTBE remediation. 1 fig.

Koenigsberg, S. [Regenesis Bioremediation Products, San Juan Capistrano, CA (United States)

1997-11-01T23:59:59.000Z

270

Coal-transformation chemistry. Fourth quarterly progress report  

SciTech Connect (OSTI)

Pyrene, perylene, anthracene, 9,10-diphenylanthracene, naphthalene and biphenyl have been employed as electron transfer agents in the reduction of Illinois No. 6 coal with potassium in tetrahydrofuran. These electron transfer agents are about equally effective for the reduction of this coal at short reaction times (3 hours). We conclude that the anions of biphenyl and naphthalene achieve a greater degree of electron transfer to the coal molecules and that the use of these anions enhances the fragmentation reactions of the coal. Illinois No. 6 bituminous coal and Colorado subbituminous coal were reacted with potassium dissolved in a mixture of monoglyme and triglyme at -50/sup 0/C. The reduction reaction proceeded via solvated electrons rather than by an electron transfer reaction. The coals were then alkylated with methyl iodide and their solubilities in tetrahydrofuran were determined. The Illinois coal reductively alkylated via solvated electrons was considerably less soluble in tetrahydrofuran than the same coal reductively alkylated with potassium and naphthalene in tetrahydrofuran. A sample of Illinois No. 6 coal which had been reductively butylated with n-butyl-1-/sup 13/C iodide was hydrolyzed. Carbon nmr spectroscopy of the hydrolyzed coal revealed that the resonances previously assigned either to the presence of n-butyl carboxylates or to n-butyl tertiary ethers were removed. This observation provides definite evidence that only carboxylates were present in the original alkylated product. Selective alkylation of the acidic hydroxyl groups in Illinois No. 6 coal was carried out using tetrabutylammonium hydroxide as a phase transfer catalyst and iodomethane or 1-iodobutane as alkylating agent as described by Liotta. The tetrahydrofuran solubility of the product was significantly improved in a reaction where reductively butylated coal was subsequently coal was subsequently methylated using Liotta's procedure.

Stock, Leon M.; Blain, D. A.; Handy, C. I.; Heimann, P.; Huang, C. B.; King, H. -H.; Landschulz, W.; Willis, R. S.

1980-01-01T23:59:59.000Z

271

The effect of confinement in metabolism stalls on the cortisol, antibody production, and antibody-dependent cell-mediated cytotoxicity of tame lambs  

E-Print Network [OSTI]

stimulation of the reticulo- endothelial system by either specific stimuli (such as antigen-specific antibody production by B lymphocytes) or non-specific stimuli (such as phagocytosis) (Clark et al. , 1976). Research in psychoimmunology employs a variety...

Hsieh, Man-Ling

1993-01-01T23:59:59.000Z

272

A Review of "Taming the Leviathan: The Reception of the Political and Religious Ideas of Thomas Hobbes in England 1640-1700" by Jon Parkin  

E-Print Network [OSTI]

actually claims. Rather, he says that Hobbes?s contemporary critics chose to adopt many of his ideas even while denouncing the author. The ideas were just too good to 216 seventeenth-century news pass up, even if the ?Monster of Malmesbury? was too..., but the trajectory of his arguments were unnerv- ingly similar to those of many more mainstream authors. This, claims Parkin, explains the excessive reactions to what were, at first, some obscure little books. The second edition of De Cive and the subsequent...

Vaughan, Geoffrey M.

2010-01-01T23:59:59.000Z

273

On the structural and impedance characteristics of Li- doped PEO, using n-butyl lithium in hexane as dopant  

SciTech Connect (OSTI)

Nowadays polymer based solid state electrolytes for applications in rechargeable battery systems are highly sought after materials, pursued extensively by various research groups worldwide. Numerous methods are discussed in literature to improve the fundamental properties like electrical conductivity, mechanical stability and interfacial stability of polymer based electrolytes. The application of these electrolytes in Li-ion cells is still in the amateur state, due to low ionic conductivity, low lithium transport number and the processing difficulties. The present work is an attempt to study the effects of Li doping on the structural and transport properties of the polymer electrolyte, poly-ethelene oxide (PEO) (Molecular weight: 200,000). Li doped PEO was obtained by treating PEO with n-Butyllithium in hexane for different doping concentrations. Structural characterization of the samples was done by XRD and FTIR techniques. Impedance measurements were carried out to estimate the ionic conductivity of Li doped PEO samples. It is seen that, the crystallinity of the doped PEO decreases on increasing the doping concentration. XRD and FTIR studies support this observation. It is inferred that, ionic conductivity of the sample is increasing on increasing the doping concentration since less crystallinity permits more ionic transport. Impedance measurements confirm the results quantitatively.

Anand, P. B., E-mail: anandputhirath@gmail.com, E-mail: jayalekshmi@cusat.ac.in; Jayalekshmi, S., E-mail: anandputhirath@gmail.com, E-mail: jayalekshmi@cusat.ac.in [Division for Research in Advanced Materials Department of Physics Cochin University of Science and Technology Cochin 22, Kerala (India)

2014-01-28T23:59:59.000Z

274

Safety of Tri-n-butyl phosphate (TBP) and nitric acid solutions in two-phase systems at elevated temperatures  

SciTech Connect (OSTI)

This paper addresses the prevention of self-accelerating oxidation of nitric acid and tributyl phosphate (TBP). An accident of this type, which occurred at Tomsk-7, Russia, in 1993, resulted from a slow chemical reaction occurring initially at sub-boiling temperatures. The accumulating heat and vapors overpressurized and burst a process tank. Two safety issues are addressed in this summary of experimental data: circumstances under which convection or radiation cooling of vessels will exceed reaction heat, and measures which can prevent or mitigate such reactions. Heat generations rates have been found to range widely. Thermodynamic calculations confirm that heat generation is reduced by a large factor when nitrogen oxides are able to escape from the reaction mixure. Scoping calculations show that the evaporation of water is potentially the most effective mechanism for heat removal in a large vessel, and experiments have demonstrated that water evaporation is effective for preventing runaway reactions in a vented, two-phase system operated below about 120 C. These data indicate that venting is the key to controlling runaway reactions. However, other experiments have indicated that the self-heating reaction did not present a danger, even if reaction heating led to an accelerating reaction, in a sufficiently vented system. To determine how much venting was required, experiments were performed with pure organic phase and two-phase TBP-nitric acid mixtures. Data show a critical ratio of organic mass to vent area, above which the reacting system can reach potentially dangerous pressures. Experiments show runaway reactions occurring in vented systems only as the temperature approaches 130 C. These results clearly indicate that adequate venting of vessels containing heated TBP and nitrate is the key to controlling their reaction.

Hyder, M.L.; Paddleford, D.F.; Thompson, M.C. [Westinghouse Savannah River Company, Aiken, SC (United States)

1995-12-31T23:59:59.000Z

275

Supporting Information A scalable synthesis of the (S)-4-(tert-butyl)-2-(pyridin-2-yl)-4,5-dihydrooxazole  

E-Print Network [OSTI]

with a three-pitched curved blade, an internal thermometer, and a reflux condenser equipped with a two a steam of N2. The flask was charged with (S)-tert-leucine (15.08 g, 115.0 mmol, 1.00 equv, 99% ee and replaced by a condenser and the reaction was heat to reflux (80 °C oil bath). After 20 h the reaction

Stoltz, Brian M.

276

An experimental system for the n-butyl-lithium initiated polymerization of styrene in a multi-sampled batch reactor  

E-Print Network [OSTI]

. The power to the water heater is controlled by a Fisher Proportional Temperature Control (Catalog P3 TENPERATURE CONTROLLER CONSTANT TENPERATURE BATH P2 CHILLER ELECTRICAL HEATER Figure 3. Schematic of Reactor Temperature Control System 20... successful column; i, e, , extremely high pressure drops and low plate counts were observed in these columns. As a last measure, the gel was stirred in a hot, concen- trated sodium hydroxide solution (approximately pH 13) for ten hours. The excess sodium...

Cox, James Harvey

2012-06-07T23:59:59.000Z

277

Whole-Genome Analysis of Methyl tert-Butyl Ether-Degrading Beta-Proteobacterium Methylibium petroleiphilum PM1  

E-Print Network [OSTI]

D. J. Slomczynski. 2003. BTEX/MTBE bioremediation: BionetsScow, and L. Alvarez-Cohen. MTBE and benzene biodegradationinteractions in BTEX and MTBE mixtures by an MTBE-degrading

2007-01-01T23:59:59.000Z

278

Paleoecology of the Cretaceous^Tertiary mass extinction in planktonic foraminifera  

E-Print Network [OSTI]

to be the result of both long-term environmental changes (e.g., climate, sea level, volcanism) and short environmental condi- tions for any living organism due to the culmina- tion of long-term climatic changes, spanning environments from open marine upper bathyal, to shelf and shallow marginal settings, indicate

Keller, Gerta

279

Serpentinites in a Tertiary subduction complex in the northern Dominican Repub-  

E-Print Network [OSTI]

and the global mass balance. Serpentinites are abundant in the northern Dominican Republic on Hispaniola (Fig. 1 their origins and the im- plications for syn- and post-subduction processes. GEOLOGICAL SETTING Hispaniola

280

The geochemistry and petrogenesis of the Tertiary igneous rocks of the Eagle Mountains, Van Horn, Texas  

E-Print Network [OSTI]

Alkaline Ign ~ ~ cons ~ ~ ~ Rocks 21 42 D I S CUSS I QN e ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ Petrogenesis 50 50 Source magma. Fractionation . ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 50 52 Origin of West Texas Nagmas... of Permian and Cretaceous age. The only Permian rocks in the area are represented by the Hueco Limestone Formation. The Cretaceous System, however, is represented by the entire Comanche and Gulf Series (Fig. 2). The Hueco Formation is of marine origin...

Nelson, Ronald Alan

1972-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Micropaleontology and mineralogy of a tertiary sediment core from the Sigsbee knolls, Gulf of Mexico  

E-Print Network [OSTI]

and Adams (1960) and there is even evidence of other modes of nutrition (Bernard, 1948b; Gaarder and Hasle, 1962), These "algae" also exhibit two flagella which are used for locomotion. Thus several observations indicate that the coccolithophores are best...

Pyle, Thomas Edward

1966-01-01T23:59:59.000Z

282

Yoon et al. 1 Research Article: Tertiary Endosymbiosis Driven Genome Evolution in  

E-Print Network [OSTI]

apoprotein; PsbD, photosystem II D2 reaction center protein; PsbO, oxygen-evolving enhancer protein 1 MBE, 2 and Debashish Bhattacharya 1 * 1 Department of Biological Sciences and Roy J. Carver Center, NOAA National Ocean Service, Center for Coastal Environmental Health and Biomolecular Research

Bhattacharya, Debashish

283

Calcareous nannofossils from the uppermost Cretaceous and the lowermost Tertiary of central Texas  

E-Print Network [OSTI]

noflagellates, successively dominate the nanno- fossil assemblage immed1ately above the boundary. The opportunistic of small placolith species, such as Cruci lacolithus sp. cf. C. primus, C ocl la 11th p I, else t p. f. I!. ~di h d T wef s p tat, hl h t lty... yl ld t p dly I I s m I Pal o nannoflora. This boundary succession is nearly ident1cal to the boundary succession documented in detail 1n Spain and 1s most reasonably inter- preted as representing a continuous sect1on because there is no ev1dence...

Jiang, Ming-Jung

2012-06-07T23:59:59.000Z

284

An investigation into student academic help seeking behaviours in a tertiary institution's learning support centre.  

E-Print Network [OSTI]

??The majority of academic help seeking studies worldwide have predominantly used the quantitative paradigm and have been undertaken in the secondary and primary sector. This (more)

Protheroe, Mervyn

2009-01-01T23:59:59.000Z

285

Ultrasonic absorption associated with tertiary butanol complex formation in cyclohexane solutions  

E-Print Network [OSTI]

fY^gl MFe sXFYlFY a^2 vToMVHbMF Xr TXbbVYYll5 LTRA 7 ^ SONIRCBIP vOlMe Xr DlcMHYblFY5 CndnfY hwyp A '.9-n.^ Table of Contents Page Introduction 1 The Two Crystal Method The Apparatus It The Ultrasonic Interferometer ? Methods...^in ldrrln iyouSn du ryn ovfhterdhuw ry^f /2 xIj o1T oeenotf dupnenupnur hT Ttn,^nuiEa 9ht nbocelnw 5oll fyhqnp ryor du qorntw qyntn o1TM yof vnnu hvfntknp rh vn dupnenupnur hT ryn Ttn,^nuiEw dr df ehffdvln rh oiih^ur Tht ryn nbinff ovfhterdhu hknt ryn Brh...

Musa, Raiq S.

1957-01-01T23:59:59.000Z

286

A contribution to the Tertiary geology and paleontology of northeastern Colorado  

E-Print Network [OSTI]

LINNAEUS 39 Martin Canyon local fauna 32 Family Boidae BONAPARTE 39 Pawnee Creek fauna of authors 34 Calamagras murivorus COPE 39 Eubanks, Kennesaw, and Vim-Peetz local faunas 34 Calamagras angulatus COPE 39 Sand Canyon local fauna 35...) 58 Mesohip pus proteulophus OSBORN 80 Adjidaumo sp. (Small form) 58 Mesohip pus eulophus OSBORN 80 Paradjidaumo trilophus (Copz) 58 Mesohippus sp. 81 Family Sciuridae GRAY 59 Miohip pus sp. 81 Cedramus wardi WILSON 59 Family...

Galbreath, E. C.

1953-03-15T23:59:59.000Z

287

Stochastic Programming Approach to Hydraulic Fracture Design for the Lower Tertiary Gulf of Mexico  

E-Print Network [OSTI]

of the requirements for the degree of MASTER OF SCIENCE Chair of Committee, Robert Lane Co-Chair of Committee, Peter Valk? Committee Member, Benchun Duan Head of Department, Daniel Hill August 2013 Major Subject: Petroleum Engineering ii... sampling to well count decision making under uncertainty for gas/condensate reservoirs. Dong, Holditch, and McVay (2013) applied Monte Carlo sampling for resource evaluation in shale gas reservoirs. 13 An alternative and less used model...

Podhoretz, Seth

2013-07-27T23:59:59.000Z

288

Application of a moving bed biofilm reactor for tertiary ammonia treatment in high temperature industrial wastewater  

E-Print Network [OSTI]

industrial wastewater Jennifer L. Shore a,b , William S. M'Coy b , Claudia K. Gunsch a , Marc A. Deshusses a 2012 Available online 17 February 2012 Keywords: Moving bed biofilm reactor Industrial wastewater and industrial wastewater. No biotreatment was observed at 45 °C, although effective nitrification was rapidly

289

Origin of gaseous hydrocarbons from Upper Cretaceous and Tertiary strata in the Piceance basin, western Colorado  

E-Print Network [OSTI]

microbial/thermogenic origin for methane. Only one sample from above 1950 m contained sufficient amounts of C2for isotopic analysis (813 CC2 =-27.0%o at 1718 m). Data from the second trend are based on seven analyses and are offset by approximately +20%o...

Katz, David Jonathan

1997-01-01T23:59:59.000Z

290

New surfactant classes for enhanced oil recovery and their tertiary oil recovery potential  

E-Print Network [OSTI]

for more than 35 years, in particular in the USA in depleted oil reservoirs after waterflooding (Garrett conditioned to residual waterflood oil saturation prior to surfactant slug injection. This was followed., 2000; Jayanti et al., 2001; Berger and Lee, 2002; Endo et al., 2002). During a waterflood (which can

Goddard III, William A.

291

Mineralogy and diagenesis of Gulf Coast Tertiary shales Ann-Mag Field, Brooks County, Texas  

E-Print Network [OSTI]

composition with increasing depth of burial provides evidence of systematic diagenetic conversions (Boles and Franks, 1979; Hower et al. , 1976; Perry and Hower, 1972; Weaver and Beck, 1971; Dunoyer De Segonzac, 1970; Burst, 1969; Powers, 1967). When... not be neglected, many workers have shown that significant mineral ogic changes do occur due to diagenesi s of clay minerals from the same source (Boles and Franks, 1979; Hower, et al. , 1976; Perry and Hower, 1972; Dunoyer De Segonzac, 1970; Burst, 1969). Also...

Bott, Winston Frederick

1985-01-01T23:59:59.000Z

292

Monitoring Electricity Consumption in the Tertiary Sector- A Project within the Intelligent Energy Europe Program  

E-Print Network [OSTI]

Services and Energydesign, Technical University of Braunschweig, Germany Univ.-Prof. Dr.-Ing. M. Norbert Fisch Head of Institute IGS ? Institute of Building Services and Energydesign, Technical University of Braunschweig, Germany Edelgard Gruber... Competence Centre Energy Policy and Energy Systems, Fraunhofer Institute for Systems and Innovation Research, Karlsruhe, Germany Barbara Schlomann Competence Centre Energy Policy and Energy Systems, Fraunhofer Institute for Systems and Innovation...

Plesser, S.; Fisch, M. N.; Gruber, E.; Schlomann, B.

293

Evidence for Large-Scale Laramide Tectonic Inversion and a Mid-Tertiary  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address:011-DNA Jump37. It isInformationexplains a4Evendale, Ohio:Field From

294

Late Tertiary paleomagnetic data from Leyte, Philippines: implications for Philippine fault zone motion  

E-Print Network [OSTI]

= 20. 1' (oss ? 6. 6', le ? 29. 9) and a paleomagnetic pole A ? 89. 0" N, P ? 10. 4'E (Ass ? 4. 8', K ? 55. 3). Eight early Neogene sites (3 normal polarity and 5 reversed polarity) give a mean direction D = 23. 2', I = 13. 9' (oss ? 9. 3', k = 36.... 2) and a paleomagnetic pole A = 66. 5'N, 6 = 220. 5'E (Ass ? 7. 1', It = 62. 0). The late Veogene pole is indistinguishable at the 95% confidence level from published Plio-Pleistocene poles from the entire Philippines and the late Miocene pole...

Cole, Jay Timothy

1988-01-01T23:59:59.000Z

295

The effect of solids retention time on tertiary ozonation and carbon adsorption of petrochemical wastewaters  

E-Print Network [OSTI]

. Biological treatment of wastewater has been used since the turn of the century, and while its application has grown in complexity since that time, the fundamental biological reaction mechanisms have remained unchanged. Most important... organic carbon from the wastewater by conversion into microbial cells, or some other desirable form. Biological waste treatment is usually intended for the removal of organic matter, but certain other contaminants are also removed, For example...

Buys, Ronald Earl

1980-01-01T23:59:59.000Z

296

Tertiary nitrogen heterocyclic material to reduce moisture-induced damage in asphalt-aggregate mixtures  

DOE Patents [OSTI]

Asphalt-aggregate roads crack when subjected to freezing and thawing cycles. Herein, the useful life of asphalts are substantially improved by a minor amount of a moisture damage inhibiting agent selected from compounds having a pyridine moiety, including acid salts of such compounds. A shale oil fraction may serve as the source of the improving agent and may simply be blended with conventional petroleum asphalts.

Plancher, Henry (Laramie, WY); Petersen, Joseph C. (Laramie, WY)

1982-01-01T23:59:59.000Z

297

Science and technology review, September 1997  

SciTech Connect (OSTI)

This month`s issue contains articles entitled Nova Laser Experiments and Stockpile Stewardship; Sharing the Challenges of Non- proliferation; and Taming Explosives for Training.

Upadhye, R.

1997-09-01T23:59:59.000Z

298

EPA`s proposed renewable oxygenate requirement (ROR): Pros and cons  

SciTech Connect (OSTI)

In December 1993, the US Environmental Protection Agency (EPA) released its final rule that sets for the details for requirements to sell reformulated gasoline (RFG) in certain ozone non-attainment areas. At the same time, EPA also issued a proposed rule to require that 30% of the oxygen required in RFG be based on a renewable oxygenate. Renewables include ethanol and its ether derivatives such as ethyl tertiary butyl ether (ETBE). The RFG rule is a final rule, while the Renewable Oxygenate Requirement (ROR) rule is a proposed rule yet to be finalized and subject to revision. Included in this paper are brief reviews of Ashland petroleum Company`s ethanol usage, oxygenated fuel and reformulated gasoline blending economics, and some comments on the EPA proposed renewable oxygenate requirement.

Czeskleba, H.M. [Ashland Petroleum Co., KY (United States)

1995-12-31T23:59:59.000Z

299

US refiners choose variety of routes to MTBE  

SciTech Connect (OSTI)

This paper reports that refiners and merchant manufacturers in the U.S. are gearing up to produce the large volumes of methyl tertiary butyl ether (MTBE) needed to comply with oxygenated gasoline requirements. The 1990 U.S. Clean Air Act Amendments specify that, as of the first of this coming November, gasoline containing a minimum of 2.7 wt % oxygen must be sold in 39 CO-nonattainment cities. Refiners and others are scurrying to bring MTBE capacity on line in time to meet this requirement. Many U.S. refiners already have some operating MTBE capacity, but this will not be nearly enough to meet the looming increase in demand. As a result, additional capacity is being constructed worldwide.

Rhodes, A.K.

1992-09-07T23:59:59.000Z

300

MTBE will be a boon to U. S. gas processors  

SciTech Connect (OSTI)

This paper reports that the advent of methyl tertiary butyl ether (MTBE) as the primary oxygenate blending component for oxygenated and reformulated motor fuels promises significant benefits for the U.S. gas-processing industry. Increased demand for isobutane as MTBE-plant feedstock will buoy both normal butane and isobutane pricing in U.S. gulf Coast during the 1990s. Elimination of the need to crack normal butane in U.S. olefin plants will also strengthen competitive feedstocks somewhat, including ethane and propane. And increased use of normal butane as isomerization feedstock will result in wider recognition of the premium quality of gas plant normal butane production compared to most refinery C[sub 4] production.

Otto, K.W. (Purvin and Gertz, Inc. Dallas, TX (United States))

1993-01-11T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Effect of lower feedstock prices on economics of MTBE complex  

SciTech Connect (OSTI)

Economic evaluation of the methyl tertiary butyl ether (MTBE) complex was carried out starting from n-butane and by captive production of methanol from natural gas. The processing steps consist of isomerization of n-butane to isobutane, dehydrogenation of isobutane to make isobutene, and finally, the reaction of isobutene with methanol to produce MTBE. Two different plant sizes were considered, and the effect of 30% lower feedback prices on profitability was studied. It was found that the raw materials cost is a dominant component, composing about 55% of the total production cost. An internal rate of return of 19% could be realized for 500,000 tons per annum MTBE complex based on economic data in mid-1993. The payback period estimated at this capacity was 3.8 years, and the break-even capacity was 36.6%.

Rahman, F.; Hamid, S.H.; Ali, M.A. [King Fahd Univ. of Petroleum and Minerals, Dhahran (Saudi Arabia)

1996-01-01T23:59:59.000Z

302

Lyondell develops one step isobutylene process  

SciTech Connect (OSTI)

This paper reports that Lyondell Petrochemical Co., Houston, has developed a one step process to convert normal butylenes to isobutylene, a key component of methyl tertiary butyl ether (MTBE). MTBE is expected to become the additive of choice among U.S. refiners to blend oxygenated gasolines required by 1990 amendments to the Clean Air Act. Lyondell Pres. and Chief Executive Officer Bob Gower the the new process could help assure adequate supplies of MTBE to meet U.S. demand for cleaner burning fuels. Lyondell estimates the capital cost of building a grassroots plant to produce isobutylene with the new process would be less than half the cost of a grassroot plant to produce isobutylene with existing technology starting with normal butane.

Not Available

1992-03-23T23:59:59.000Z

303

MTBE: The headache of cleaner air  

SciTech Connect (OSTI)

Gasoline with methyl tertiary butyl ether (MTBE) has been sold in the United States since 1979, when it was added to fuels as an octane enhancer after lead was phased out of motor fuels. Recently it has been introduced as a means of reducing carbon monoxide emissions during the winter months in targeted US cities. However, there is concern over health complaints including headaches, dizziness and nausea from residents of some areas. These reports have launched an era of assidious research by scientists and public health officials across the country to learn more about MTBE`s short-term and long-term, and possibly carcinogenic, health effects. New research should help weigh the risk of MTBE as a possible carcinogen and the effectiveness of MTBE-blended fuels in reducing carbon monoxide levels. The question is whether, in minimizing one risk, is another risk - however small - being introduced?

Kneiss, J.

1995-07-01T23:59:59.000Z

304

Toxicological and performance aspects of oxygenated motor vehicle fuels  

SciTech Connect (OSTI)

At the request of the Environmental Protection Agency, the committee reviewed a draft of a federal report that assesses the effects of oxygenated fuels on public health, air quality, fuel economy, engine performance, and water quality. The committee determined that much of the federal report adequately represents what is known about the effects of methyl tertiary-butyl ether (MTBE) -- the most commonly used additive in the federal oxygenated-fuels program -- on health, the environment, and motor vehicles. MTBE, a chemical added to gasoline to reduce carbon monoxide pollution, appears not to pose a substantial human health risk, but more-definitive data are needed to assess short-term health effects and to determine whether this additive is effective in reducing carbon monoxide pollution in cold environments.

NONE

1996-12-31T23:59:59.000Z

305

MTBE movements between Texas Gulf Coast plants to be enhanced  

SciTech Connect (OSTI)

This paper reports that Texas Eastern Products Pipeline Co. (Teppco), Houston, has begun construction of its shuttle pipeline, a 10-mile, 6 and 8-in. line to move methyl tertiary butyl ether (MTBE) between producers and refiners along the Houston Ship Channel. Funding for the project has been approved, rights-of-way are secured, and procurement of materials is under way, according to Teppco. The line will flow from the western edge of Shell's refinery eastward to storage facilities of Teppco's Baytown terminal. The shuttle pipeline anticipates the US requirement for oxygenated gasolines that takes effect Nov. 1. Approximately 70% of the available US merchant capacity for MTBE is located along the shuttle's path, Teppco says.

Not Available

1992-07-27T23:59:59.000Z

306

The efficient use of natural gas in transportation  

SciTech Connect (OSTI)

Concerns over air quality and greenhouse gas emissions have prompted discussion as well as action on alternative fuels and energy efficiency. Natural gas and natural gas derived fuels and fuel additives are prime alternative fuel candidates for the transportation sector. In this study, we reexamine and add to past work on energy efficiency and greenhouse gas emissions of natural gas fuels for transportation (DeLuchi 1991, Santini et a. 1989, Ho and Renner 1990, Unnasch et al. 1989). We add to past work by looking at Methyl tertiary butyl ether (from natural gas and butane component of natural gas), alkylate (from natural gas butanes), and gasoline from natural gas. We also reexamine compressed natural gas, liquified natural gas, liquified petroleum gas, and methanol based on our analysis of vehicle efficiency potential. We compare the results against nonoxygenated gasoline.

Stodolsky, F.; Santini, D.J.

1992-04-01T23:59:59.000Z

307

The efficient use of natural gas in transportation  

SciTech Connect (OSTI)

Concerns over air quality and greenhouse gas emissions have prompted discussion as well as action on alternative fuels and energy efficiency. Natural gas and natural gas derived fuels and fuel additives are prime alternative fuel candidates for the transportation sector. In this study, we reexamine and add to past work on energy efficiency and greenhouse gas emissions of natural gas fuels for transportation (DeLuchi 1991, Santini et a. 1989, Ho and Renner 1990, Unnasch et al. 1989). We add to past work by looking at Methyl tertiary butyl ether (from natural gas and butane component of natural gas), alkylate (from natural gas butanes), and gasoline from natural gas. We also reexamine compressed natural gas, liquified natural gas, liquified petroleum gas, and methanol based on our analysis of vehicle efficiency potential. We compare the results against nonoxygenated gasoline.

Stodolsky, F.; Santini, D.J.

1992-01-01T23:59:59.000Z

308

Comparative Environmental Performance of Two-Diesel-Fuel Oxygenates: Dibutyl Maleate (DBM) and Triproplyene Glycol Monomethyl Ether (TGME)  

SciTech Connect (OSTI)

Many studies have shown that the addition of oxygen bearing compounds to diesel fuel can significantly reduce particulate emissions. To assist in the evaluation of the environmental performance of diesel-fuel oxygenates, we have implemented a suite of diagnostic models for simulating the transport of compounds released to air, water, and soils/groundwater as well as regional landscapes. As a means of studying the comparative performance of DBM and TGME, we conducted a series of simulations for selected environmental media. Benzene and methyl tertiary butyl ether (MTBE) were also addressed because they represent benchmark fuel-related compounds that have been the subject of extensive environmental measurements and modeling. The simulations showed that DBM and TGME are less mobile in soil because of reduced vapor-phase transport and increased retention on soil particles. The key distinction between these two oxygenates is that DBM is predicted to have a greater potential than TGME for aerobic biodegradation, based on chemical structure.

Layton, D.W.; Marchetti, A.A.

2001-10-01T23:59:59.000Z

309

Physics Motivation for NSTXPhysics Motivation for NSTX UpgradeUpgrade Jon Menard and Masa Ono  

E-Print Network [OSTI]

, DEMO "Taming the plasma-material interface (PMI)" Solutions for very high particle for the ITER era and beyond High heat flux at small size and cost for PMI R&D Future: high neutron flux configuration for "Taming the plasma-material interface" FESAC-PP identified PMI issue as highest priority

Princeton Plasma Physics Laboratory

310

Wild Hypersurfaces joint work with Andrew Crabbe  

E-Print Network [OSTI]

Wild Hypersurfaces joint work with Andrew Crabbe Graham J. Leuschke gjleusch@math.syr.edu Syracuse University Notre Dame, 6 Nov 2010 , Wild Hypersurfaces, Crabbe­Leuschke 1/14 #12;Outline Representation types in general Tame and Wild examples MCM modules over hypersurfaces Finite MCM type for hypersurfaces Tame MCM

Leuschke, Graham

311

WILD HYPERSURFACES GRAHAM J. LEUSCHKE  

E-Print Network [OSTI]

WILD HYPERSURFACES GRAHAM J. LEUSCHKE Abstract. In the representation theory of finite-dimensional algebras over a field, Drozd's trichotomy theorem says that an algebra has either tame module type or wild'll give a little background on the problem, including definitions of tame and wild CM type, and talk about

Leuschke, Graham

312

CRC fuel rating program: road octane performance of oxygenates in 1982 model cars  

SciTech Connect (OSTI)

Because of the widespread interest in the use of alcohols and ethers as gasoline blending components, this program was conducted to evaluate the effects of several oxygenates on gasoline octane performance and to evaluate the effects of car design features such as engine and transmission type. Five oxygenates were evaluated at two nominal concentrations, 5 and 10 volume%, at both regular- and premium-grade octane levels: methanol (MeOH), ethanol (ETOH), isopropanol (IPA), tertiary butanol (TBA), and methyl tertiary butyl ether (MTBE). A blend of 5% MeOH and 5 percent TBA was also tested at both octane levels. Twenty-eight unleaded fuels, including four hydrocarbon fuels, two hydrocarbon fuels plus toluene, and twenty-two oxygenated fuels, were rated in duplicate in thirty-eight cars using the Modified Uniontown Technique (CRC Designation F-28-75 described in Appendix C), plus some additional instructions. All testing was done on chassis dynamometers. Ratings were obtained at full throttle with all thirty-eight cars, and at the most critical part-throttle condition (occurring with manifold vacuum of 4 in. Hg (13.5 kPa) or greater above the full-throttle vacuum) with nine cars.

Not Available

1985-07-01T23:59:59.000Z

313

Molecular organization in the native state of woody tissue: Studies of tertiary structure using the Raman microprobe solid state 13C NMR and biomimetic tertiary aggregates. Progress report, July 1, 1989--June 30, 1993  

SciTech Connect (OSTI)

We have previously shown that all relatively pure plant and bacterial celluloses are, in their native states, composites of two lattice forms, I{sub {alpha}} and I{sub {beta}}, and that the two forms possess molecular chains in the same conformations but with different hydrogen bonding patterns. In the current period we have demonstrated that in higher plant cell wall matrices, the hemicelluloses are likely to have a regulatory function during the aggregation of cellulose. Different hemicelluloses appear to influence the aggregation in different ways. We have also developed preliminary evidence indicating the hemicelluloses may have a protective function against the action of some cellulolytic enzymes. The specific accomplishments during the current period are detailed. Demonstration that hemicelluloses present during biogenesis can transform bacterial cellulose into a cellulose typical of higher plant celluloses, and that each hemicellulose has a different effect on the pattern of aggregation. Evidence is presented that the hemicelluloses may limit the action of certain cellulolytic enzymes, suggesting that their function may go beyond regulation to include passive resistance to cellulolytic pathogens. Enhancing the potential of the Raman microprobe technique for mapping variability of lignin in the cell wall by identifying the contribution of the different substructures of lignin to the intensity of the key band in the Raman spectrum of lignin. Mapping of the variability of lignin across two cell wall sections. The mappings have convoluted within them both composition and concentration, but they demonstrate the potential of the method and point to the improvements we are now making so as to distinguish between variability of concentration and variability of composition.

Atalla, R.H.

1993-12-31T23:59:59.000Z

314

RELATIONS BETWEEN THE DETECTION OF METHYL TERT-BUTYL ETHER (MTBE) IN SURFACE AND GROUND WATER AND ITS CONTENT IN GASOLINE  

E-Print Network [OSTI]

AND ITS CONTENT IN GASOLINE By Michael J. Moran, Mike J. Halde, Rick M. Clawges and John S. Zogorski U in the United States as an octane enhancer and oxygenate in gasoline. Octane enhancement began in the late 1970's with the phase-out of tetraethyl lead from gasoline. The use of oxygenates was expanded

315

alkyl-tert alkyl ethers: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

TREAT METHYL- TERT-BUTYL ETHER CONTAMINATED CiteSeer Summary: Methyl-tert-butyl ether (MTBE) is a commonly used gasoline additive. Leaking underground storage tank systems,...

316

Comparison of SPME headspace analysis to U.S. EPA method5030/8260B for MTBE monitoring  

SciTech Connect (OSTI)

A novel method for analysis of methyl tert-butyl ether andtert-butyl alcohol using solid phase microextraction is described andcompared to a standard method.

Stringfellow, William T.; Oh, Kuen-Chan

2005-02-01T23:59:59.000Z

317

GEOPHYSICAL RESEARCH LETTERS, VOL. ???, XXXX, DOI:10.1029/, Destruction of the Tertiary Ozone Maximum During a Solar  

E-Print Network [OSTI]

Maximum During a Solar Proton Event A. Sepp¨al¨a, P. T. Verronen, V. F. Sofieva, J. Tamminen, E. Kyr¨ol¨a Finnish Meteorological Institute, Earth Observation, Helsinki, Finland C. J. Rodger Physics Department to study the effects of the January 2005 solar storms on the polar winter middle atmosphere. The model

Otago, University of

318

Volume and accessibility of entrained (solution) methane in deep geopressured reservoirs - tertiary formations of the Texas Gulf Coast. Final report  

SciTech Connect (OSTI)

The objective of this project was to appraise the total volume of in-place methane dissolved in formation waters of deep sandstone reservoirs of the onshore Texas Gulf Coast within the stratigraphic section extending from the base of significant hydrocarbon production (8000 ft)* to the deepest significant sandstone occurrence. The area of investigation is about 50,000 mi/sup 2/. Factors that determine the total methane resource are reservoir bulk volume, porosity, and methane solubility; the latter is controlled by the temperature, pressure, and salinity of formation waters. Regional assessment of the volume and the distribution of potential sandstone reservoirs was made from a data base of 880 electrical well logs, from which a grid of 24 dip cross sections and 4 strike cross sections was constructed. Solution methane content in each of nine formations or divisions of formations was determined for each subdivision. The distribution of solution methane in the Gulf Coast was described on the basis of five reservoir models. Each model was characterized by depositional environment, reservoir continuity, porosity, permeability, and methane solubility.

Gregory, A.R.; Dodge, M.M.; Posey, J.S.; Morton, R.A.

1980-10-01T23:59:59.000Z

319

The Influence of Metal Ions on the Tertiary Structure of the Prion Protein and Inherited Prion Disease  

E-Print Network [OSTI]

analysis of 300 subjects. Ann Neurol 46, 224-33 (1999).Creutzfeldt-Jakob disease. Ann Neurol 43, 826-8 (1998).permission from Elsevier) Ann R. Spevacek, Eric G. B. Evans,

Spevacek, Ann

2012-01-01T23:59:59.000Z

320

1,4,7-Trimethyloxatriquinane: SN2 Reaction at Tertiary Carbon Mark Mascal,* Nema Hafezi, and Michael D. Toney  

E-Print Network [OSTI]

at reflux in water or ethanol. Although much less robust than 2, oxatriquinacene 3, a triply bis-allylic, or acetate, led to the anticipated elimination product 12 (Scheme 2). However, it turned out that 1, like 2

Toney, Michael

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Proportions of coarse and fine clay across the Cretaceous-Tertiary boundary in Milam, Falls, and Travis Counties, Texas  

E-Print Network [OSTI]

and are of little value. It is concluded that the method proposed in this thesis is capable of detecting small differences between clay sampi es at a = ingle locai ity, but prob. bly cannot be used to correlate samples f'rom one locality to another. i&1tlloagh... making dispersion and I'rac- tionation difficult. The efficiency of the X-ray diffraction t, echniques is also improved when these constituents are removed. As a simplified means of comp:rison, the various procedures performed on each sample...

Smith, John Charles

1966-01-01T23:59:59.000Z

322

Increased Oil Production and Reserves Utilizing Secondary/Tertiary Recovery Techniques on Small Reservoirs in the Paradox Basin, Utah  

SciTech Connect (OSTI)

The primary objective of this project is to enhance domestic petroleum production by field demonstration and technology transfer of an advanced- oil-recovery technology in the Paradox basin, southeastern Utah. If this project can demonstrate technical and economic feasibility, the technique can be applied to approximately 100 additional small fields in the Paradox basin alone, and result in increased recovery of 150 to 200 million barrels (23,850,000-31,800,000 m3) of oil. This project is designed to characterize five shallow-shelf carbonate reservoirs in the Pennsylvanian (Desmoinesian) Paradox Formation and choose the best candidate for a pilot demonstration project for either a waterflood or carbon-dioxide-(CO2-) miscible flood project. The field demonstration, monitoring of field performance, and associated validation activities will take place within the Navajo Nation, San Juan County, Utah.

Jr., Chidsey, Thomas C.; Allison, M. Lee

1999-11-02T23:59:59.000Z

323

Increased Oil Production and Reserves Utilizing Secondary/Tertiary Recovery Techniques on Small Reservoirs in the Paradox Basin, Utah.  

SciTech Connect (OSTI)

The primary objective of this project is to enhance domestic petroleum production by demonstration and technology transfer of an advanced oil recovery technology in the Paradox basin, southeastern Utah. If this project can demonstrate technical and economic feasibility, the technique can be applied to approximately 100 additional small fields in the Paradox basin alone, and result in increased recovery of 150 to 200 million barrels of oil. This project is designed to characterize five shallow-shelf carbonate reservoirs in the Pennsylvanian (Desmoinesian) Paradox Formation and choose the best candidate for a pilot demonstration project for either a waterflood or carbon dioxide- (CO{sub 2}-) flood project. The field demonstration, monitoring of field performance, and associated validation activities will take place in the Paradox basin within the Navajo Nation. The results of this project will be transferred to industry and other researchers through a petroleum extension service, creation of digital databases for distribution, technical workshops and seminars, field trips, technical presentations at national and regional professional meetings, and publication in newsletters and various technical or trade journals.

Chidsey, T.C. Jr.; Lorenz, D.M.; Culham, W.E.

1997-10-15T23:59:59.000Z

324

Increased Oil Production and Reserves Utilizing Secondary/Tertiary Recovery Techniques on Small Reservoirs in the Paradox Basin, Utah  

SciTech Connect (OSTI)

The primary objective of this project was to enhance domestic petroleum production by field demonstration and technology transfer of an advanced-oil-recovery technology in the Paradox Basin, southeastern Utah. If this project can demonstrate technical and economic feasibility, the technique can be applied to approximately 100 additional small fields in the Paradox Basin alone, and result in increased recovery of 150 to 200 million barrels (23,850,000-31,800,000 m3) of oil. This project was designed to characterize five shallow-shelf carbonate reservoirs in the Pennsylvanian (Desmoinesian) Paradox Formation and choose the best candidate for a pilot demonstration project for either a waterflood or carbon-dioxide-(CO2-) miscible flood project. The field demonstration, monitoring of field performance, and associated validation activities will take place within the Navajo Nation, San Juan County, Utah.

Chidsey Jr., Thomas C.

2003-02-06T23:59:59.000Z

325

Increased Oil Production and Reserves Utilizing Secondary/Tertiary Recovery Techniques on Small Reservoirs in the Paradox Basin, Utah  

SciTech Connect (OSTI)

The primary objective of this project is to enhance domestic petroleum production by demonstration and technology transfer of an advanced oil recovery technology in the Paradox basin, southeastern Utah. If this project can demonstrate technical and economic feasibility, the technique can be applied to about 100 additional small fields in the Paradox basin alone, and result in increased recovery of 150 to 200 million bbl of oil. This project is designed to characterize five shallow-shelf carbonate reservoirs in the Pennsylvanian (Desmoinesian) Paradox Formation and choose the best candidate for a pilot demonstration project for either a waterflood or carbon dioxide-(CO-) flood 2 project. The field demonstration, monitoring of field performance, and associated validation activities will take place in the Paradox basin within the Navajo Nation. The results of this project will be transferred to industry and other researchers through a petroleum extension service, creation of digital databases for distribution, technical workshops and seminars, field trips, technical presentations at national and regional professional meetings, and publication in newsletters and various technical or trade journals.

Allison, M. Lee; Chidsey, Jr., Thomas

1999-11-03T23:59:59.000Z

326

INCREASED OIL PRODUCTION AND RESERVES UTILIZING SECONDARY/TERTIARY RECOVERY TECHNIQUES ON SMALL RESERVOIRS IN THE PARADOX BASIN, UTAH  

SciTech Connect (OSTI)

The Paradox Basin of Utah, Colorado, and Arizona contains nearly 100 small oil fields producing from shallow-shelf carbonate buildups or mounds within the Desert Creek zone of the Pennsylvanian (Desmoinesian) Paradox Formation. These fields typically have one to four wells with primary production ranging from 700,000 to 2,000,000 barrels (111,300-318,000 m{sup 3}) of oil per field at a 15 to 20 percent recovery rate. Five fields in southeastern Utah were evaluated for waterflood or carbon-dioxide (CO{sub 2})-miscible flood projects based upon geological characterization and reservoir modeling. Geological characterization on a local scale focused on reservoir heterogeneity, quality, and lateral continuity as well as possible compartmentalization within each of the five project fields. The Desert Creek zone includes three generalized facies belts: (1) open-marine, (2) shallow-shelf and shelf-margin, and (3) intra-shelf, salinity-restricted facies. These deposits have modern analogs near the coasts of the Bahamas, Florida, and Australia, respectively, and outcrop analogs along the San Juan River of southeastern Utah. The analogs display reservoir heterogeneity, flow barriers and baffles, and lithofacies geometry observed in the fields; thus, these properties were incorporated in the reservoir simulation models. Productive carbonate buildups consist of three types: (1) phylloid algal, (2) coralline algal, and (3) bryozoan. Phylloid-algal buildups have a mound-core interval and a supra-mound interval. Hydrocarbons are stratigraphically trapped in porous and permeable lithotypes within the mound-core intervals of the lower part of the buildups and the more heterogeneous supramound intervals. To adequately represent the observed spatial heterogeneities in reservoir properties, the phylloid-algal bafflestones of the mound-core interval and the dolomites of the overlying supra-mound interval were subdivided into ten architecturally distinct lithotypes, each of which exhibits a characteristic set of reservoir properties obtained from outcrop analogs, cores, and geophysical logs. The Anasazi and Runway fields were selected for geostatistical modeling and reservoir compositional simulations. Models and simulations incorporated variations in carbonate lithotypes, porosity, and permeability to accurately predict reservoir responses. History matches tied previous production and reservoir pressure histories so that future reservoir performances could be confidently predicted. The simulation studies showed that despite most of the production being from the mound-core intervals, there were no corresponding decreases in the oil in place in these intervals. This behavior indicates gravity drainage of oil from the supra-mound intervals into the lower mound-core intervals from which the producing wells' major share of production arises. The key to increasing ultimate recovery from these fields (and similar fields in the basin) is to design either waterflood or CO{sub 2}-miscible flood projects capable of forcing oil from high-storage-capacity but low-recovery supra-mound units into the high-recovery mound-core units. Simulation of Anasazi field shows that a CO{sub 2} flood is technically superior to a waterflood and economically feasible. For Anasazi field, an optimized CO{sub 2} flood is predicted to recover a total 4.21 million barrels (0.67 million m3) of oil representing in excess of 89 percent of the original oil in place. For Runway field, the best CO{sub 2} flood is predicted to recover a total of 2.4 million barrels (0.38 million m3) of oil representing 71 percent of the original oil in place. If the CO{sub 2} flood performed as predicted, it is a financially robust process for increasing the reserves in the many small fields in the Paradox Basin. The results can be applied to other fields in the Rocky Mountain region, the Michigan and Illinois Basins, and the Midcontinent.

Thomas C. Chidsey, Jr.

2002-11-01T23:59:59.000Z

327

Newsfront 18-24 June 2007, Issue 21  

E-Print Network [OSTI]

factions of the Janatantrik Terai Mukti Morcha tamed. In one of his recent meetings with Indian Ambassador, Shiv Shankar Mukherjee , Koirala expressed his worries that the two JTMM faction leaders were directing their Newsbrief Election can take place...

Ghimire, Yubaraj

328

ii Ann. SC. math. Qubec, 1988, vol. 12, no 2, pp. 275-285 MOTS CIRCULAIRESET POLYNMES IRRDUCTIBLES  

E-Print Network [OSTI]

~yuto"m~ (en uw wti6.h) im4%fu~6~~ eft: uti- &WLU (i..e. de /tame dominant 1) de de@ n AUA Fq8 #12;278 PREUVE

Reutenauer, Christophe

329

The Cell Phone and the Crowd: Messianic Politics in the Contemporary Philippines  

E-Print Network [OSTI]

16. Tan, Taming the Cell Phone; De Quiros, UndiscoveredOverwhelm Cops. The Cell Phone and the Crowd Publicnew or different about The Cell Phone and the Crowd of 16

Rafael, Vicente L.

2003-01-01T23:59:59.000Z

330

FESAC-SP Whyte New HTS superconductors + integrated high-B physics  

E-Print Network [OSTI]

launchers & coupling G-9 Tame PMI & heat exhaust G-10-15 Integrated fusion materials & components High & innovative launchers for steady-state - High pressure boundary & PMI control Demountable HTS coils

331

Joint Center for Artificial Photosynthesis  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tamed" May 29, 2014 KCET: "Solar Fuel: An Interesting Idea Takes a Realistic Step" March 7, 2014 RedOrbit: "Promising News for Solar Fuels" December 30, 2013 USA Today: "How...

332

A SIMPLE PROOF OF THE MARKER-STEINHORN THEOREM FOR EXPANSIONS OF ORDERED ABELIAN  

E-Print Network [OSTI]

the standard part map for elementary extensions. That is, if (M, ) = (R, ) and M M = (M, , . . . ), then we can of reals, then every elementary extension of M is tame.) We can then define a standard part map in the same

Aschenbrenner, Matthias

333

8180 Phys. Chem. Chem. Phys., 2011, 13, 81808185 This journal is c the Owner Societies 2011 Cite this: Phys. Chem. Chem. Phys., 2011, 13, 81808185  

E-Print Network [OSTI]

photofragment translational spectroscopy. The tert-butyl radical was produced from flash pyrolysis of azo

Neumark, Daniel M.

334

he U.S. Geological Survey's (USGS) National Water-Quality Assess-  

E-Print Network [OSTI]

of the wells included methyl tert-butyl ether (MTBE), tetrachloroethene (PCE), dichlorodifluoromethane, 1

335

Task 4.9 -- Value-added products from syngas. Semi-annual report, July 1--December 31, 1996  

SciTech Connect (OSTI)

The work on advanced fuel forms in 1996 focused on the synthesis of higher alcohols from mixtures of hydrogen and carbon dioxide (syngas) from coal gasification. Initial work in this project utilized a novel molybdenum sulfide catalyst previously shown to be active for hydrodesulfurization reactions of coal liquids. A pressurized fixed-bed flow-through reactor was constructed, and the MoS{sub 2} catalysts were tested with syngas under a variety of conditions. Unfortunately, the catalysts, even with higher molybdenum loading and addition of promoters, failed to give alcohol products. A batch reactor test of the catalyst was also conducted, but did not produce alcohol products. Group VIII metals have been used previously in catalysts for syngas reactions. Ruthenium and rhodium catalysts were prepared by impregnation of a hydrotalcite support. Tests with these catalysts in flow-through reactors also did not produce the desired alcohol products. The formation of higher alcohols from smaller ones, such as methanol and ethanol, could be commercially important if high selectivity could be achieved. The methanol and ethanol would be derived from syngas and fermentation, respectively. Based on previous work in other laboratories, it was hypothesized that the hydrotalcite-supported MoS{sub 2} or Ru or Rh catalysts could catalyze the formation of butyl alcohols. Although the desired 1-butanol was obtained in batch reactions with the promoted ruthenium catalyst, the reaction was not as selective as desired. Product suitable for a lower-vapor-pressure gasoline oxygenate additive was obtained, but it may not be economical to market such products in competition with methyl tertiary-butyl ether (MTBE). Flow-through catalytic bed reactions were not successful.

Olson, E.S.; Sharma, R.K.

1997-08-01T23:59:59.000Z

336

Heterogeneous catalytic process for alcohol fuels from syngas. Final technical report  

SciTech Connect (OSTI)

The primary objective of this project has been the pursuit of a catalyst system which would allow the selective production from syngas of methanol and isobutanol. It is desirable to develop a process in which the methanol to isobutanol weight ratio could be varied from 70/30 to 30/70. The 70/30 mixture could be used directly as a fuel additive, while, with the appropriate downstream processing, the 30/70 mixture could be utilized for methyl tertiary-butyl ether (MTBE) synthesis. The indirect manufacture of MTBE from a coal derived syngas to methanol and isobutanol process would appear to be a viable solution to MTBE feedstock limitations. To become economically attractive, a process fro producing oxygenates from coal-derived syngas must form these products with high selectivity and good rates, and must be capable of operating with a low-hydrogen-content syngas. This was to be accomplished through extensions of known catalyst systems and by the rational design of novel catalyst systems.

Dombek, B.D.

1996-03-01T23:59:59.000Z

337

Evaluating nonmetallic materials` compatibility with MTBE and MTBE + gasoline service  

SciTech Connect (OSTI)

Methyl-tertiary-butyl-ether (MTBE) has become the leading oxygenate in use in the petroleum industry. Since its introduction several years ago there has been premature deterioration of nonmetallic materials in both neat MTBE and MTBE + gasoline. This degradation is costly in several ways: maintenance, replacement, environmental, and product-loss. Identifying nonmetallic materials compatible with MTBE and MTBE + gasoline is important to the petroleum industry -- all the way from the refinery to the retail sale. Exposure tests have been conducted with different types of nonmetallics in neat MTBE, neat MTBE vapor, and 5% MTBE + 95% gasoline. As in previously reported tests, Teflon{reg_sign} laminates were the top performers, experiencing very little change in any of the properties tested. An ester and ether-based urethane laminate also exhibited only small property changes. Most materials displayed significant deterioration of one or more of the measured properties, even in MTBE condensing vapor and the 5% MTBE + 95% gasoline. The specific effects on each material need to be individually evaluated to determine the effect on service life.

Hotaling, A.C.

1995-12-31T23:59:59.000Z

338

Technical and operational overview of the C[sub 4] Oleflex process at Valero refinery  

SciTech Connect (OSTI)

Changes in gasoline composition stemming from the 1990 Clean Air Act (CAA) Amendments prompted Valero Energy Corporation to evaluate options for producing reformulated gasoline. The evaluation culminated in a project to upgrade butanes into methyl tertiary butyl ether (MTBE). Technology selection focused on the dehydrogenation of isobutane, and the UOP Oleflex process was selected. The MTBE project was implemented in 34 months and was $3 million under budget. The guaranteed MTBE production of 12,500 BPSD was achieved within one month of mechanical completion and has since reached 15,000 BPSD. Even at the low MTBE prices prevailing in late 1993, the butane upgrading project contributed significantly to Valero Refinery's overall profitability. Worldwide demand is expected to increase MTBE prices in 1996, thereby further increasing profits. The paper describes the project evaluation activities which led to the selection of the Oleflex process, engineering and construction, the MTBE complex start-up and operation, the Valero MTBE complex performance, and future plans. The paper also discusses feedstock utilization efficiency and MTBE market analysis.

Hohnholt, J.F.; Payne, D. (Valero Refining Co., Corpus Christi, TX (United States)); Gregor, J.; Smith, E. (UOP, Des Plaines, IL (United States))

1994-01-01T23:59:59.000Z

339

The MTBE solution: Octanes, technology, and refinery profitability  

SciTech Connect (OSTI)

This paper has been developed to provide refiners with business decision insight regarding the production of methyl tertiary butyl ether (MTBE) from refinery - (FCC) produced isobutylene. The driving forces making MTBE an attractive investment are examined with regard to the increasing demand for higher octane unleaded gasolines. The decision to proceed with MTBE production depends on the profitability of such an investment and the refiner's ability to meet market demands using available processing equipment, refinery produced streams and external feedstocks. The factors affecting this decision are analyzed in this paper and include: industry ability to meet rising octane demand; profit potential realized by diverting isobutylene to MTBE; availability of technology for producing MTBE; and investment and operating costs required to produce MTBE. Chemical Research and Licensing and NEOCHEM have developed a simple, low cost process to produce MTBE, reducing the excessive equipment and high operating costs that were associated with conventional MTBE designs. The economics and process benefits of installing a CRandL/NEOCHEM MTBE process are examined within the framework of a generalized medium-sized refinery configuration.

Lander, E.P.; Hubbard, J.N.; Smith, L.A.

1983-03-01T23:59:59.000Z

340

Assessing and Managing the Risks of Fuel Compounds: Ethanol Case Study  

SciTech Connect (OSTI)

We have implemented a suite of chemical transport and fate models that provide diagnostic information about the behavior of ethanol (denoted EtOH) and other fuel-related chemicals released to the environment. Our principal focus is on the impacts to water resources, as this has been one of the key issues facing the introduction of new fuels and additives. We present analyses comparing the transport and fate of EtOH, methyl tertiary butyl ether (MTBE), and 2,2,4 trimethyl pentane (TMP) for the following cases (1) discharges to stratified lakes, subsurface release in a surficial soil, (3) cross-media transfer from air to ground water, and (4) fate in a regional landscape. These compounds have significantly different properties that directly influence their behavior in the environment. EtOH, for example, has a low Henry's law constant, which means that it preferentially partitions to the water phase instead of air. An advantageous characteristic of EtOH is its rapid biodegradation rate in water; unlike MTBE or TMP, which degrade slowly. As a consequence, EtOH does not pose a significant risk to water resources. Preliminary health-protective limits for EtOH in drinking water suggest that routine releases to the environment will not result in levels that threaten human health.

Layton, D.W.; Rice, D.W.

2002-02-04T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

High octane ethers from synthesis gas-derived alcohols. Quarterly technical progress report, April--June 1992  

SciTech Connect (OSTI)

The objective of the proposed research is to synthesize high octane ethers, primarily methyl isobutyl ether (MIBE) and methyl tertiary butyl ether (MTBE), directly from H{sub 2}/CO/CO{sub 2} coal-derived synthesis gas via alcohol mixtures that are rich in methanol and 2-methyl-l-propanol (isobutanol). The overall scheme involves gasification of coal, purification and shifting of the synthesis gas, higher alcohol synthesis, and direct synthesis of ethers. The last stage of the synthesis involves direct coupling of synthesis gas-derived methanol and isobutanol that has been demonstrated by us to occur over superacid catalysts to yield methyl isobutyl ether (MIBE) at moderate pressures and a mixture of methanol and isobutene at low pressures. MIBE is an isomer of MTBE and a process is proposed whereby MTBE from the two alcohols is maximized and MIBE is minimized. This will be achieved by the proper choice of reaction conditions, i.e. intermediate pressures, and of inorganic acid catalysts that are stable at temperatures higher than 200{degree}C, at which the carbonium ion reaction coupling of the two alcohols to MTBE is more effective than the oxonium ion or ester reaction coupling to MIBE. Both organic and inorganic catalysts will be investigated, and the better catalysts of these classes will be subjected to long term performance studies. The long term performance studies of the combined process will extend to 1000 hr and detailed analytical data for all products will be provided.

Klier, K.; Herman, R.G.; Feeley, O.C.; Johansson, M.A.

1992-07-01T23:59:59.000Z

342

MTBE catalyst shows increased conversion in commercial unit  

SciTech Connect (OSTI)

Rising demand for methyl tertiary butyl ether (MTBE) has spawned interest in finding a cost-effective means of increasing production from existing units. A commercial trial of an improved MTBE catalyst was conducted recently at Lyondell Petrochemical Co.'s Channelview, Tex., plant. The new catalyst called Amberlyst 35 Wet, enhanced oxygenate production in the Lyondell trial. The new catalyst changes the activity coefficients of at least one of the components of the MTBE reaction, resulting in higher equilibrium conversion relative to its first-generation counterpart. Key catalyst properties are: particle size, 0.4--1.25 mm; Apparent density, 0.82 g/ml; Surface area, 44 sq m/g; Moisture content, 56%; Concentration of acid sites, 1.9 meq/ml (5.4 meq/g); Porosity, 0.35 cc/g; and Average pore diameter, 300 [angstrom]. Suggested operating conditions are: maximum temperature, 284 F (140 C); minimum bed depth, 24 in. (0.61 m); and liquid hourly space velocity (LHSV), 1--5 hr[sup [minus]1].

Not Available

1994-10-10T23:59:59.000Z

343

Remediation of MTBE in groundwater: A case where pump-and-treat works  

SciTech Connect (OSTI)

Two case studies are discussed in which groundwater pumping reduced levels of dissolved methyl tertiary butyl ether (MTBE) in groundwater by more than two orders of magnitude, in some cases to below detection limits. MTBE contamination in groundwater is becoming an important issue due to the increasing prevalence and regulation of this gasoline additive. In addition, MTBE is more mobile in groundwater than most hydrocarbons, so it is usually the first gasoline constituent to reach sensitive receptors. Since its Henry`s constant is low, in situ removal of MTBE from groundwater by air sparging is slow, and MTBE does not rapidly degrade, either biologically or abiotically. Therefore, groundwater pumping is usually employed to contain and collect MTBE-contaminated groundwater. Pumping groundwater can reduce MME levels to below detection limits within a few years, because MTBE in the subsurface is found mostly dissolved in groundwater. In contrast, the more hydrophobic gasoline hydrocarbons exist mostly in pockets of separate phase material and adsorbed to soil particles and dissolve slowly in groundwater. Hydrocarbon concentrations are rarely reduced to closure levels within a reasonable time frame by pumping. Sites in eastern Massachusetts and southern New Jersey, where groundwater was contaminated with MTBE due to releases of unleaded gasoline from underground storage tanks, are discussed. At these sites, average MTBE levels were reduced by two to three orders of magnitude, from several ppm or more to less than 10 ppb within three years by pumping groundwater at 10 to 30 gpm.

Bass, D.H.; Riley, B. [Groundwater Technology, Inc., Norwood, MA (United States); Farrell, T. [Groundwater Technology, Inc., Trenton, NJ (United States)

1994-12-31T23:59:59.000Z

344

High octane ethers from synthesis gas-derived alcohols  

SciTech Connect (OSTI)

The objective of the proposed research is to synthesize high octane ethers, primarily methyl isobutyl ether (MIBE) and methyl tertiary butyl ether (MTBE), directly from H[sub 2]/CO/CO[sub 2] coal-derived synthesis gas via alcohol mixtures that are rich in methanol and 2-methyl-l-propanol (isobutanol). The overall scheme involves gasification of coal, purification and shifting of the synthesis gas, higher alcohol synthesis, and direct synthesis of ethers. The last stage of the synthesis involves direct coupling of synthesis gas-derived methanol and isobutanol that has been demonstrated by us to occur over superacid catalysts to yield methyl isobutyl ether (MIBE) at moderate pressures and a mixture of methanol and isobutene at low pressures. MIBE is an isomer of MTBE and a process is proposed whereby MTBE from the two alcohols is maximized and MIBE is minimized. This will be achieved by the proper choice of reaction conditions, i.e. intermediate pressures, and of inorganic acid catalysts that are stable at temperatures higher than 200[degree]C, at which the carbonium ion reaction coupling of the two alcohols to MTBE is more effective than the oxonium ion or ester reaction coupling to MIBE. Both organic and inorganic catalysts will be investigated, and the better catalysts of these classes will be subjected to long term performance studies. The long term performance studies of the combined process will extend to 1000 hr and detailed analytical data for all products will be provided.

Klier, K.; Herman, R.G.; Feeley, O.C.; Johansson, M.A.

1992-07-01T23:59:59.000Z

345

Catalyst and process development for synthesis gas conversion to isobutylene. Quarterly report, October 1, 1993--December 31, 1993  

SciTech Connect (OSTI)

The objectives of this project are to develop a new catalyst; the kinetics for this catalyst; reactor models for trickle bed, slurry and fixed bed reactors; and to simulate the performance of fixed bed trickle flow reactors, slurry flow reactors, and fixed bed gas phase reactors for conversion of a hydrogen lean synthesis gas to isobutylene. A hydrogen-lean synthesis gas with a ratio of H{sub 2}/CO of 0.5 to 1.0 is produced from the gasification of coal, lignite, or biomass. Isobutylene is a key reactant in the synthesis of methyl tertiary butyl ether (MTBE) and of isooctanes. MTBE and isooctanes are high octane fuels used to blend with low octane gasolines to raise the octane number required for modern automobiles. The production of these two key octane boosters is limited by the supply of isobutylene. MTBE, when used as an octane enhancer, also decreases the amount of pollutants emitted from the exhaust of an automobile engine.

Anthony, R.G.; Akgerman, A.

1994-05-01T23:59:59.000Z

346

Advances in mass storage technology are producing devices capable of holding terabytes of data. These new devices, often called tertiary storage devices, have dramatically different performance  

E-Print Network [OSTI]

-overwrite technique for managing storage. This technique allows the user to see the entire history of the database of the database at any moment in history. This capability is referred to as time travel. Since only the start time characteristics than magnetic disks. Conventional database systems include explicit dependen- cies on magnetic

California at Irvine, University of

347

Preliminary results on the characterization of Cretaceous and lower Tertiary low-permeability (tight) gas-bearing rocks in the Wind River Basin, Wyoming  

SciTech Connect (OSTI)

The Wind River Basin is a structural and sedimentary basin in central Wyoming (Figure 1) that was created during the Laramide orogeny from Late Cretaceous through Eocene time. The objectives of the Wind River Basin tight gas sandstone project are to define the limits of the tight gas accumulation in the basin and to estimate in-place and recoverable gas resources. The approximate limits of the tight gas accumulation are defined from available drillhole information. Geologic parameters, which controlled the development of the accumulation, are studied in order to better understand the origins of tight gas accumulations, and to predict the limits of the accumulation in areas where little drillhole information is available. The architecture of sandstone reservoirs are studied in outcrop to predict production characteristics of similar reservoirs within the tight gas accumulation. Core and cuttings are used to determine thermal maturities, quality of source rocks, and diagenetic histories. Our work thus far has concentrated in the Wind River Indian Reservation in the western part of the basin.

Fouch, T.D.; Keefer, W.R.; Finn, T.M. [and others

1993-12-31T23:59:59.000Z

348

Increased oil production and reserves utilizing secondary/tertiary recovery techniques on small reservoirs in the Paradox basin, Utah. Annual report  

SciTech Connect (OSTI)

The Paradox basin of Utah, Colorado, and Arizona contains nearly 100 small oil fields producing from carbonate buildups or mounds within the Pennsylvanian (Desmoinesian) Paradox Formation. These fields typically have one to four wells with primary production ranging from 700,000 to 2,000,000 barrels of oil per field at a 15 to 20% recovery rate. At least 200 million barrels of oil is at risk of being unrecovered in these small fields because of inefficient recovery practices and undrained heterogeneous reservoirs. Five fields (Anasazi, mule, Blue Hogan, heron North, and Runway) within the Navajo Nation of southeastern utah are being evaluated for waterflood or carbon-dioxide-miscible flood projects based upon geological characterization and reservoir modeling. The results can be applied to other fields in the Paradox basin and the Rocky Mountain region, the Michigan and Illinois basins, and the Midcontinent. The reservoir engineering component of the work completed to date included analysis of production data and well tests, comprehensive laboratory programs, and preliminary mechanistic reservoir simulation studies. A comprehensive fluid property characterization program was completed. Mechanistic reservoir production performance simulation studies were also completed.

Chidsey, T.C. Jr.

1997-02-01T23:59:59.000Z

349

Study of the kinetics of the gas-phase, iodine catalyzed elimination of HBr from isobutylbromide: the tertiary C-H bond dissociation energy in isobutylbromide.  

E-Print Network [OSTI]

, (with the possible exception of the very electronegative F atom) unless the substituent can delocalize the odd electron such as with the vinyI substituent, i. e. the allyl radical. The stabi'Iization energy is defined as the difference between... of formation of the radical. f s indicated in section (II); the stabilization energy of bromine bridged radical by the delocalization of tne odd electron can be obtained by comparisior, with a localized free radical. Thus, the stabi11zat1on energy...

Jirustithipong, Pongsiri

2012-06-07T23:59:59.000Z

350

Mesozoic to Early Tertiary tectonic-sedimentary evolution of the Northern Neotethys Ocean: evidence from the Beysehir-Hoyran-Hadim Nappes, S.W. Turkey.  

E-Print Network [OSTI]

The Bey?ehir-Hoyran-Hadim Nappes crop out over 700km, from east to west in the Pisidian and Central Taurus Mountains of southern Turkey. During this study, field obsevations of lithological, structural and sedimentological features are combined...

Andrew, Theo

351

Increased oil production and reserves utilizing secondary/tertiary recovery techniques on small reservoirs in the Paradox basin, Utah. Annual report, February 9, 1996--February 8, 1997  

SciTech Connect (OSTI)

The Paradox basin of Utah, Colorado, and Arizona contains nearly 100 small oil fields producing from carbonate buildups or mounds within the Pennsylvanian (Desmoinesian) Paradox Formation. These fields typically have one to four wells with primary production ranging from 700,000 to 2,000,000 barrels of oil per field at a 15 to 20% recovery rate. At least 200 million barrels of oil is at risk of being unrecovered in these small fields because of inefficient recovery practices and undrained heterogeneous reservoirs. Five fields (Anasazi, Mule, Blue Hogan, Heron North, and Runway) within the Navajo Nation of southeastern Utah are being evaluated for waterflood or carbon-dioxide-miscible flood projects based upon geological characterization and reservoir modeling. The results can be applied to other fields in the Paradox basin and the Rocky Mountain region, the Michigan and Illinois basins, and the Midcontinent. The Anasazi field was selected for the initial geostatistical modeling and reservoir simulation. A compositional simulation approach is being used to model primary depletion, waterflood, and CO{sub 2}-flood processes. During this second year of the project, team members performed the following reservoir-engineering analysis of Anasazi field: (1) relative permeability measurements of the supra-mound and mound-core intervals, (2) completion of geologic model development of the Anasazi reservoir units for use in reservoir simulation studies including completion of a series of one-dimensional, carbon dioxide-displacement simulations to analyze the carbon dioxide-displacement mechanism that could operate in the Paradox basin system of reservoirs, and (3) completion of the first phase of the full-field, three-dimensional Anasazi reservoir simulation model, and the start of the history matching and reservoir performance prediction phase of the simulation study.

Chidsey, T.C. Jr.

1997-08-01T23:59:59.000Z

352

Increased oil production and reserves utilizing secondary/tertiary recovery techniques on small reservoirs in the Paradox basin, Utah. Technical progress report, January 1, 1995--March 31, 1995  

SciTech Connect (OSTI)

The primary objective of this project is to enhance domestic petroleum production by demonstration and technology transfer of an advanced oil recovery technology in the Paradox basin, southeastern Utah. If this project can demonstrate technical and economic feasibility, the technique can be applied to approximately 100 additional small fields in the Paradox basin alone, and result in increased recovery of 150 to 200 million barrels of oil. This project is designed to characterize five shallow-shelf carbonate reservoirs in the Pennsylvanian Paradox Formation and choose the best candidate for a pilot demonstration project for either a waterflood or carbon dioxide-flood project. The field demonstration, monitoring of field performance, and associated validation activities will take place in the Paradox basin within the Navajo Nation. The results of this project will be transferred to industry and other researchers through a petroleum extension service, creation of digital databases for distribution, technical workshops and seminars, field trips, technical presentations at national and regional professional meetings, and publication in newsletters and various technical or trade journals.

Allison, M.L.

1995-05-30T23:59:59.000Z

353

Increased oil production and reserves utilizing secondary/tertiary recovery techniques on small reservoirs in the Paradox Basin, Utah, Class II  

SciTech Connect (OSTI)

The primary objective of this project is to enhance domestic petroleum production by field demonstration and technology transfer of an advanced-oil-recovery technology in the Paradox basin, southeastern Utah. If this project can demonstrate technical and economic feasibility, the technique can be applied to approximately 100 additional small fields in the Paradox basin alone, and result in increased recovery of 150 to 200 million barrels (23,850,000-31,800,000 m{sup 3}) of oil. This project is designed to characterize five shallow-shelf carbonate reservoirs in the Pennsylvanian (Desmoinesian) Paradox Formation and choose the best candidate for a pilot demonstration project for either a waterflood or carbon-dioxide-miscible flood project. The field demonstration, monitoring of field performance, and associated validation activities will take place within the Navajo Nation, San Juan County, Utah.

Chidsey, Thomas C.

2000-07-28T23:59:59.000Z

354

QUANTIFYING NON-POINT SOURCES OF VOLATILE ORGANIC COMPOUNDS IN STORMWATER FROM A PARKING LOT  

E-Print Network [OSTI]

-butyl ether (MTBE) on urban particles indicates a site- specific interaction between MTBE and a particulate is a possible source only for the gasoline oxygenate methyl tert-butyl ether (MTBE). Lopes and Bender (1998

355

Characterization of trace gases measured over Alberta oil sands mining operations: 76 speciated C2-C10volatile organic compounds (VOCs), CO2, CH4, CO, NO, NO2, NOy, O3and SO2  

E-Print Network [OSTI]

K. : Atmospheric chemistry of gasoline-related emissions:chemistry. Methyl tert-butyl ether is a solvent and gasoline

2010-01-01T23:59:59.000Z

356

E-Print Network 3.0 - acrylic acid grafted Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

& acronyms 11 PPPP PAA Poly(acrylic acid) PBMA Poly(butyl methacrylate) PE Polyethylene PHEMA Poly... ......

357

An elusive species with many different traits.  

E-Print Network [OSTI]

-Pase detection of HSOH: Synthesis by Flash Vacuum Pyrolysis of ditert-butyl-sulfoxide and rotational- torsional

Giesen, Thomas

358

Center for Water Resources Annual Technical Report  

E-Print Network [OSTI]

of Ethanol on Anaerobic Production of Tert-Butyl Alcohol (TBA) from MTBE in Groundwater Kate M. Scow, Douglas

359

Refinery fuel oxygenates in view of the complex model for reformulated gasline  

SciTech Connect (OSTI)

The final version of the Complex Model for reformulated gasoline (RFG) has now been issued with some surprising features that will significantly affect refinery fuel oxygenates planning. These include the following: (1) The only oxygenates included in the model are MTBE, ETBE, TAME, and Ethanol. (2) The Complex Model calculates that MTBE and TAME are significantly more effective for reduction of air toxics emissions than Ethanol and ETBE. (3) The Complex Model calculates that MTBE and TAME typically produce about equal reduction in air toxics emissions at the same RFG oxygen content. Although gasoline certification by the Complex Model is optional prior to 1998, after 1998 it will be mandatory for both reformulated and conventional gasolines. This paper considers refinery oxygenates production in view of these features of the Complex Model for RFG, basing the discussion on 2.0 weight percent oxygen content for RFG.

Crawford, C.D.; Haelsig, C.P. [Fluor Daniel, Irvine, CA (United States)

1994-12-31T23:59:59.000Z

360

BulletinofMathematicalBiologyVol.47,No.3,pp.367 407,1985. PrintedinGreatBritain  

E-Print Network [OSTI]

the tertiary structure. Five proteins, parvalbumin, hemerythrin, human hemoglobin, lamprey hemoglobin

Cariani, Peter

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Spring 2009 Student Presentations COMPUTER NETWORK & SYSTEM ADMINISTRATION PROGRAM  

E-Print Network [OSTI]

rainwater collection, grey water reuse, composting and low flush toilets, and on-site tertiary wastewater

362

Void-induced dissolution in molecular dynamics simulations of NaCl Ranjit Bahadur and Lynn M. Russella  

E-Print Network [OSTI]

such as corrosion, tertiary oil recovery, and crystallization. The industrial process of floatation, which is used

363

Void-induced dissolution in molecular dynamics simulations of NaCl Ranjit Bahadur and Lynn M. Russella  

E-Print Network [OSTI]

in the characterization of processes such as corrosion, tertiary oil recovery, and crystallization. The industrial process

Russell, Lynn

364

QuarterlyCouncil > In this issue  

E-Print Network [OSTI]

of helping to tame the wild child of the energy world, wind power. The Langley Gulch Power Plant will help the utility integrate growing amounts of renewable energy, including highly variable wind power, into its system.The plant is capable of producing enough power for about 208,000 homes. At a dedication ceremony

365

meeting of the NSTX Program Advisory Committee Princeton Plasma Physics Laboratory  

E-Print Network [OSTI]

of Fusion Energy Sciences (OFES) held a series of Research Needs Workshops (ReNeW) to identify research-performance, steady-state plasmas", "Taming the plasma material interface (PMI)", "Harnessing fusion power) for particle pumping, higher-power fast-wave heating for current ramp-up studies and electron heating

Princeton Plasma Physics Laboratory

366

Normal Crossings Divisors and Configurations for Symplectic Topology  

E-Print Network [OSTI]

in symplectic topology is the existence of an -tame almost complex structure J on X respecting V , i.e. J(TV )=TV . Furthermore, such a J can be chosen to be very regular near V in the following sense on a neighborhood of V in NXV , and lift an almost complex structure JV on V to an almost

Zinger, Aleksey

367

The magazine for College of Fine Arts and Communication alumni and friends It's not Greek to them  

E-Print Network [OSTI]

: Theatre and Dance tames the Furies Inside this issue: Pirate Radio celebrates a decade on air Alumna we are doing our part to positively transform health and health care.Through our education programs, on the stages and galleries of this campus and throughout the region, we provide power- ful inspiration to our

368

PRODUCTION OF RAIN-FED ALFALFA S. Dennis Cash1  

E-Print Network [OSTI]

PRODUCTION OF RAIN-FED ALFALFA S. Dennis Cash1 and David M. Wichman2 ABSTRACT Dryland (rain alfalfa is minor compared to the acreage of native or tame pastures, and the overall production of irrigated alfalfa in this region. However, for ranchers in areas that receive significant snowpack, dryland

Maxwell, Bruce D.

369

PHYSICS TODAY HOME | JOBS | BUYERS GUIDE | EVENT CALENDAR Heating the Sun's corona | Physics Update home | Ice acoustics for detecting neutrinos  

E-Print Network [OSTI]

PHYSICS TODAY HOME | JOBS | BUYERS GUIDE | EVENT CALENDAR Heating the Sun's corona | Physics Update home | Ice acoustics for detecting neutrinos Tuning vibrations for label-free biological for label-free biological imaging Heating the Sun's corona Taming rogue waves to create switchable

Heller, Eric

370

bitcoin.BitMint Bitcoin.BitMint  

E-Print Network [OSTI]

® bitcoin.BitMint 1 Bitcoin.BitMint Reconciling Bitcoin with Central Banks Volatility - No Samid BitMint, LLC * Gideon@BitMint.com The sweeping success of the original (2008) bitcoin protocol indicates an overshoot. We propose to tame bitcoin into bitcoin.BitMint: keeping the bitcoin excitement

371

0.475 ii 1+( )2 = Ep = Eeff in  

E-Print Network [OSTI]

.95 2 0.92= TaD 250K:= TtD 280K:= TsupD 280K:= Tatm 270 K= Ttel 280 K= Tfme 77K:= From my calculations contents of water vapor my tame is few % taD because Desert's are at Zenith whereas mine are corrected

Leclercq, Samuel

372

JULIA SETS AND WILD CANTOR SETS ALASTAIR FLETCHER AND JANG-MEI WU  

E-Print Network [OSTI]

JULIA SETS AND WILD CANTOR SETS ALASTAIR FLETCHER AND JANG-MEI WU Abstract. There exist uniformly quasiregular maps f : R3 R3 whose Julia sets are wild Cantor sets. 1. Introduction The most direct is not tame is called wild. The first example of a wild Cantor set was Antoine's necklace [1

Fletcher, Alastair

373

WILD ALGEBRAS HAVE ONE-POINT EXTENSIONS OF REPRESENTATION DIMENSION AT LEAST FOUR  

E-Print Network [OSTI]

WILD ALGEBRAS HAVE ONE-POINT EXTENSIONS OF REPRESENTATION DIMENSION AT LEAST FOUR STEFFEN OPPERMANN Abstract. We show that any wild algebra has a one-point exten- sion of representation dimension at least between tame and wild representation type is another way of saying "how infinite" the representation

Oppermann, Steffen

374

Wild hypersurfaces Andrew Crabbea  

E-Print Network [OSTI]

Wild hypersurfaces Andrew Crabbea , Graham J. Leuschkea,1, a Department of Mathematics, Syracuse at least 4 have wild Cohen-Macaulay type. Keywords: maximal Cohen­Macaulay module, wild representation type is about CM representation types, specifically tame and wild CM types. See §1 for the definitions

Leuschke, Graham

375

CONTROLLED WILD ALGEBRAS AND WILD HIROSHI NAGASE  

E-Print Network [OSTI]

CONTROLLED WILD ALGEBRAS AND ø­WILD ALGEBRAS HIROSHI NAGASE Dedicated to Professor Yukio Tsushima are dev­ ided into two disjoint classes by Drozd's Tame and Wild dichotomy (see [4] and [2]). In [2 ø is Auslander­Reiten translation. The contraposition of the conjecture says that any wild algebra

Bielefeld, University of

376

What Do We Know About Ethanol and Alkylates as Pollutants?  

SciTech Connect (OSTI)

Gov. Davis issued Executive Order D-5-99 in March 1999 calling for removal of methyl tertiary butyl ether (MTBE) from gasoline no later than December 31, 2002. The Executive Order required the California Air Board, State Water Resources Control Board (SWRCB) and Office of Environmental Health Hazard Assessment (OEHHA) to prepare an analysis of potential impacts and health risks that may be associated with the use of ethanol as a fuel oxygenate. The SWRCB contracted with the Lawrence Livermore National Laboratory (LLNL) to lead a team of researchers, including scientists from Clarkson University, University of Iowa, and University of California, Davis, in evaluating the potential ground and surface water impacts that may occur if ethanol is used to replace MTBE. These findings are reported in the document entitled Health and Environmental Assessment of the Use of Ethanol as a Fuel Oxygenate. This document has been peer reviewed and presented to the California Environmental Policy Council and may be viewed at: http://www-erd.llnl.gov/ethanol/. Ethanol used for fuels is made primarily from grains, but any feed stock containing sugar, starch, or cellulose can be fermented to ethanol. Ethanol contains 34.7% oxygen by weight. It is less dense than water, but infinitely soluble in water. Ethanol vapors are denser than air. One and a half gallons of ethanol have the same energy as one gallon of gasoline. Pure fuel ethanol, and gasoline with ethanol, conducts electricity, while gasoline without ethanol is an insulator. Corrosion and compatibility of materials is an issue with the storage of pure ethanol and gasoline with high percentages of ethanol, but these issues are less important if gasoline with less than 10% ethanol is used.

Rich, D W; Marchetti, A A; Buscheck, T; Layton, D W

2001-05-11T23:59:59.000Z

377

A review of treatment technologies for MTBE  

SciTech Connect (OSTI)

Available treatment technologies for methyl tertiary butyl ether (MTBE) contamination in soil, groundwater, and recovered groundwater are reviewed and assessed. MTBE contamination is becoming an important issue due to the increasing prevalence and regulation of this gasoline additive. In addition, MTBE is more soluble and more mobile in groundwater than most hydrocarbons, so it is usually the first gasoline constituent to reach sensitive receptors. Treatment of MTBE is complicated by its Henry`s constant, which is lower than most other gasoline constituents. Furthermore, evidence of biodegradability of MTBE is mixed, and MTBE does not degrade rapidly abiotically. Groundwater pumping is usually employed to contain and collect MTBE-contaminated groundwater, often successfully because of its high aqueous solubility. Air sparging/soil vapor extraction is also successfully employed to treat MTBE, but its effectiveness is reduced by the low Henry`s constant of MTBE. Sparging and other aerobic bioremediation approaches are hampered by the poor biodegradability of MTBE. Oxidation technologies, such as ozone injection, hold promise for rapid in situ remediation of MTBE. Treatment of recovered groundwater contaminated with MTBE is also problematic. MTBE adsorbs poorly to granular activated carbon; advanced oxidation processes are effective on MTBE, but entail high capital and operating costs; bioreactors are of questionable effectiveness on MTBE. Air stripping is usually the most cost-effective treatment technology for MTBE so long as the off gas from the air stripper can be discharged without treatment. However, off gas treatment is expensive, so groundwater is sometimes heated to reduce the requirement for stripping air.

Bass, D. [Groundwater Technology, Inc., Norwood, MA (United States)

1995-12-31T23:59:59.000Z

378

Ethanol Demand in United States Production of Oxygenate-limited Gasoline  

SciTech Connect (OSTI)

Ethanol competes with methyl tertiary butyl ether (MTBE) to satisfy oxygen, octane, and volume requirements of certain gasolines. However, MTBE has water quality problems that may create significant market opportunities for ethanol. Oak Ridge National Laboratory (ORNL) has used its Refinery Yield Model to estimate ethanol demand in gasolines with restricted use of MTBE. Reduction of the use of MTBE would increase the costs of gasoline production and possibly reduce the gasoline output of U.S. refineries. The potential gasoline supply problems of an MTBE ban could be mitigated by allowing a modest 3 vol percent MTBE in all gasoline. In the U.S. East and Gulf Coast gasoline producing regions, the 3 vol percent MTBE option results in costs that are 40 percent less than an MTBE ban. In the U.S. Midwest gasoline producing region, with already high use of ethanol, an MTBE ban has minimal effect on ethanol demand unless gasoline producers in other regions bid away the local supply of ethanol. The ethanol/MTBE issue gained momentum in March 2000 when the Clinton Administration announced that it would ask Congress to amend the Clean Air Act to provide the authority to significantly reduce or eliminate the use of MTBE; to ensure that air quality gains are not diminished as MTBE use is reduced; and to replace the existing oxygenate requirement in the Clean Air Act with a renewable fuel standard for all gasoline. Premises for the ORNL study are consistent with the Administration announcement, and the ethanol demand curve estimates of this study can be used to evaluate the impact of the Administration principles and related policy initiatives.

Hadder, G.R.

2000-08-16T23:59:59.000Z

379

Location of MTBE and toluene in the channel system of the zeolite mordenite: Adsorption and host-guest interactions  

SciTech Connect (OSTI)

This paper reports a study of the location of Methyl Tertiary Butyl Ether (MTBE) and toluene molecules adsorbed in the pores of the organophylic zeolite mordenite from an aqueous solution. The presence of these organic molecules in the zeolite channels was revealed by structure refinement performed by the Rietveld method. About 3 molecules of MTBE and 3.6 molecules of toluene per unit cell were incorporated into the cavities of mordenite, representing 75% and 80% of the total absorption capacity of this zeolite. In both cases a water molecule was localized inside the side pocket of mordenite. The saturation capacity determined by the adsorption isotherms, obtained by batch experiments, and the weight loss given by thermogravimetric (TG) analyses were in very good agreement with these values. The interatomic distances obtained after the structural refinements suggest MTBE could be connected to the framework through a water molecule, while toluene could be bonded to framework oxygen atoms. The rapid and high adsorption of these hydrocarbons into the organophylic mordenite zeolite makes this cheap and environmental friendly material a suitable candidate for the removal of these pollutants from water. - graphical abstract: Location of MTBE (a) and toluene (b) in mordenite channels (projection along the [001] direction). Highlights: Black-Right-Pointing-Pointer We investigated the MTBE and toluene adsorption process into an organophilic zeolite mordenite. Black-Right-Pointing-Pointer The presence of MTBE and toluene in mordenite was determined by X-ray diffraction studies. Black-Right-Pointing-Pointer About 3 molecules of MTBE and 3.6 molecules of toluene per unit cell were incorporated into the zeolite cavities. Black-Right-Pointing-Pointer MTBE is connected to the framework through a water molecule. Black-Right-Pointing-Pointer Toluene is directly bonded to framework oxygen atoms.

Arletti, Rossella, E-mail: rossella.arletti@unito.it [Department of Earth Sciences, University of Torino Via Valperga Caluso 35, I-10125, Torino (Italy)] [Department of Earth Sciences, University of Torino Via Valperga Caluso 35, I-10125, Torino (Italy); Martucci, Annalisa; Alberti, Alberto [Department of Earth Sciences, University of Ferrara, Via G. Saragat 1, I-44100, Ferrara (Italy)] [Department of Earth Sciences, University of Ferrara, Via G. Saragat 1, I-44100, Ferrara (Italy); Pasti, Luisa; Nassi, Marianna [Department of Chemistry, University of Ferrara, Via L. Borsari 26, I-44100 Ferrara (Italy)] [Department of Chemistry, University of Ferrara, Via L. Borsari 26, I-44100 Ferrara (Italy); Bagatin, Roberto [Research Centre for Non-Conventional Energy-Istituto ENI Donegani, Environmental Technologies, Via Fauser 4, I-28100 Novara (Italy)] [Research Centre for Non-Conventional Energy-Istituto ENI Donegani, Environmental Technologies, Via Fauser 4, I-28100 Novara (Italy)

2012-10-15T23:59:59.000Z

380

In-situ air injection, soil vacuum extraction and enhanced biodegradation: A case study in a JP-4 jet fuel contaminated site  

SciTech Connect (OSTI)

The US Environmental Protection Agency (US EPA) and the US Coast Guard (USCG) conducted a joint demonstration of in situ remediation of a JP-4 jet fuel spill at the USCG Support Center in Elizabeth City, North Carolina. The jet fuel was trapped beneath a clay layer that extended from the surface to a depth of 1.5 in. The water table was 2.0 in below land surface, and jet fuel extended from a depth of 1.0 to 3.5 in. Air was injected under pressure to depress the water table and bring the entire spill into the unsaturated zone, where hydrocarbons could be removed by volatilization and biodegradation. The injected air was recovered through soil vacuum extraction (SVE) at the treatment area. To document actual removal of hydrocarbons, core samples were acquired in August 1992 before air injection, and September 1994 at the end of the demonstration. The spill originally contained 3600 kg of JP-4. Between the core sampling events, only 55 % of the total petroleum hydrocarbons were removed, but more than 98% of benzene was removed. The initial goal was to reduce the concentration of total petroleum hydrocarbons (TPH) to concentrations less than 100 mg/kg soil. This was not accomplished within 18 months of operation. During the period of operation, ground water was monitored for the concentration of benzene, toluene, ethylbenzene, and the xylene isomers (BTEX), and methyl tertiary butyl ether (MTBE). The concentration of BTEX and MTBE in the subsurface was reduced to a very low level, but concentrations of benzene and MTBE in ground water did not meet the EPA drinking water standards in the most heavily impacted wells. The effluent gas from SVE was monitored for the concentration of total hydrocarbon vapors. 12 refs., 7 figs., 5 tabs.

Cho, Jong Soo; DiGiulio, D.C.; Wilson, J.T. [National Risk Management Lab., Ada, OK (United States)

1997-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

MTBE -- A global perspective  

SciTech Connect (OSTI)

Methyl tertiary butyl ether (MTBE) is a major and familiar component of Reformulated and Oxygenated gasoline in the US. As such, it is essential to the success of the Clean Air Act programs now reaching a crescendo in major urban areas. In less than ten years, US MTBE capacity has grown from about 4,000 B/D to more than 200,000 B/D. Outside of the USA, its role is less widely understood. Although MTBE markets elsewhere are much less driven by legislation, they have seen the same spectacular growth prospects. Overall, about as much MTBE is used today overseas as in the US. To date, this has to be one of the petrochemical industry`s major success stories. Yet today, the MTBE industry stands at a crossroads, with the direction of future development uncertain at best. DeWitt`s gasoline and oxygenates team has closely observed the ups and downs of this market during most of its turbulent history. In this paper, the authors shall try to set down the major developments and prospects, with the personal familiarity of having been there when things changed. The story begins with a brief historical sketch, leading up to the identification of four critical periods in which major changes took place. The causes of today`s uncertainty lie in all of these stages, and are in a very real sense an example of the ``Law of Unintended consequences.`` Having set the stage, a cautious set of predictions will be put forth. These are neither as promising as proponents would like, nor as unpromising as some would tend to believe.

Ludlow, W.I.; Miller, K.D. Jr.; Liew, R.E. van [DeWitt and Co., Inc., Houston, TX (United States)

1995-09-01T23:59:59.000Z

382

Fuel cycle evaluations of biomass-ethanol and reformulated gasoline. Volume 1  

SciTech Connect (OSTI)

The US Department of Energy (DOE) is using the total fuel cycle analysis (TFCA) methodology to evaluate energy choices. The National Energy Strategy (NES) identifies TFCA as a tool to describe and quantify the environmental, social, and economic costs and benefits associated with energy alternatives. A TFCA should quantify inputs and outputs, their impacts on society, and the value of those impacts that occur from each activity involved in producing and using fuels, cradle-to-grave. New fuels and energy technologies can be consistently evaluated and compared using TFCA, providing a sound basis for ranking policy options that expand the fuel choices available to consumers. This study is limited to creating an inventory of inputs and outputs for three transportation fuels: (1) reformulated gasoline (RFG) that meets the standards of the Clean Air Act Amendments of 1990 (CAAA) using methyl tertiary butyl ether (MTBE); (2) gasohol (E10), a mixture of 10% ethanol made from municipal solid waste (MSW) and 90% gasoline; and (3) E95, a mixture of 5% gasoline and 95% ethanol made from energy crops such as grasses and trees. The ethanol referred to in this study is produced from lignocellulosic material-trees, grass, and organic wastes -- called biomass. The biomass is converted to ethanol using an experimental technology described in more detail later. Corn-ethanol is not discussed in this report. This study is limited to estimating an inventory of inputs and outputs for each fuel cycle, similar to a mass balance study, for several reasons: (1) to manage the size of the project; (2) to provide the data required for others to conduct site-specific impact analysis on a case-by-case basis; (3) to reduce data requirements associated with projecting future environmental baselines and other variables that require an internally consistent scenario.

Tyson, K.S.

1993-11-01T23:59:59.000Z

383

Chemical behavior of degradation products of tributylphosphate in purex reprocessing  

SciTech Connect (OSTI)

Chemical behavior of butyl nitrate/butyl alcohol, degradation products from dealkylation of tri-n-butylphosphate(TBP) in PUREX reprocessing, which has not so far been reported, was investigated. No accumulation of those compounds in the organic phase of TBP(30%)-dodecane was observed in any separation cycle of PUREX despite the fact that the apparent distribution of the compounds lies to the organic phase at their high concentrations. The distribution of butyl nitrate/butyl alcohol between organic/aqueous phases is found to be dependent on their concentrations and on nitric acid concentration, which could explain the above phenomena. Only butyl nitrate of the above two compounds was slightly detected in the organic streams. It is probable from this investigation that butyl nitrate is removed into aqueous waste stream primarily through alkali scrubber.

Kuno, Y.; Sato, S.; Masui, J. [Power Reactor and Nuclear Fuel Development Corp., Ibaraki (Japan)] [and others

1995-12-01T23:59:59.000Z

384

Nonphosphate Degradation Products of Tributyl Phosphate and Their Reactivities in Purex Media Under Extreme Conditions  

SciTech Connect (OSTI)

The chemical degradation of tributyl phosphate (TBP) in liquid systems, where TBP was in contact with aqueous solutions containing nitric acid and/or uranyl nitrate, was studied experimentally to clarify the mechanisms of the formation and successive reactions of nonphosphate products under atmospheric pressure. Butyl nitrate, propionic acid, acetic acid, butric acid, and butyl alcohol were formed as the nonphosphate butyl products derived from the butyl-groups of TBP in an open system. The total amount of these products almost equals the amount of the major intermediate phosphate products reduced, i.e., di- and monobutyl phosphates and phosphoric acid. Butyl alcohol was found to be the precursor of the other nonphosphate products.Even when the extremely degraded solvent was further contacted with 10 M nitric acid at 90 deg. C, no significant heat evolution was observed at atmospheric pressure. Only butyl alcohol changed into carboxylic acids by exothermic oxidative reactions.

Tashiro, Yoshikazu [Sumitomo Metal Mining Company, Ltd. (Japan); Kodama, Ryuji [Sumitomo Metal Mining Company, Ltd. (Japan); Sugai, Hiroshi [Sumitomo Metal Mining Company, Ltd. (Japan); Suzuki, Katsuhiko [Japan Nuclear Fuel, Ltd. (Japan); Matsuoka, Shingo [Japan Nuclear Fuel, Ltd. (Japan)

2000-01-15T23:59:59.000Z

385

Water Quality  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

which can lead to public health problems. * MtBE (Methyl tert Butyl Ether), a gasoline additive, has begun to contaminate ground water supplies. * Similarly, perchlorate has...

386

agents ionising radiation: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of poly(methyl methacrylate), poly(n-butyl acrylate) and poly(2-hydroxyethyl (more) Bennet, Francesca 2009-01-01 85 Transcriptomic and Secretomic Profiling of Isolated...

387

aux rayonnements ionisants: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of poly(methyl methacrylate), poly(n-butyl acrylate) and poly(2-hydroxyethyl (more) Bennet, Francesca 2009-01-01 138 Factories: The Ionising Radiations (Sealed Sources)...

388

E-Print Network 3.0 - allyl methacrylate styrene Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tetrachloroethylene () Cyclohexanol () Cyclohexanone ()1- 1-Butyl alcohol ()2... ;() Acrolein () Acrylic acid () Allyl zlcohol () Allyl chloride () Allyl glycidyl ether(AGE) ()2-...

389

Biomass IBR Fact Sheet: Archer Daniels Midland  

Broader source: Energy.gov [DOE]

Archer Daniels Midland will develop a pilot plant to demonstrate the continuous production of cellulosic ethanol and butyl acrylate from densified corn stover.

390

Identification of a haloalkaliphilic and thermostable cellulase with improved ionic liquid tolerance  

E-Print Network [OSTI]

acetate ([Emim]Ac), 1-ethyl-3-methylimidazolium chloride ([Emim]Cl), 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) and 1-allyl-

Zhang, Tao

2012-01-01T23:59:59.000Z

391

Stratospheric ozone, global warming, and the principle of unintended consequences - an ongoing science and policy story  

E-Print Network [OSTI]

as methyl-tert-butyl ether (MTBE), lubricating oil and itsthe environment. Use of the MTBE additive in gasoline wasof gasoline laced with MTBE into groundwater resulted in

2013-01-01T23:59:59.000Z

392

Biomass burning and urban air pollution over the Central Mexican Plateau  

E-Print Network [OSTI]

the urban tracers (e.g. C 2 H 2 , MTBE, toluene) are highlymethyl tert-butyl ether (MTBE) because their shorter atmo-

2009-01-01T23:59:59.000Z

393

Effects of water chemistry on NF/RO membrane structure and performance  

E-Print Network [OSTI]

methyl tert-butyl ether (MTBE), benzene, ethylbenzene,TCE** Industrial C 2 HCl 3 MTBE** [48] Industrial C 5 H 12 O

Mo, Yibing

2013-01-01T23:59:59.000Z

394

Cometabolic bioremediation  

E-Print Network [OSTI]

Intrinsic bioremediation of MTBE-contaminated groundwater atcontaminants, e.g. PCE, TCE, MTBE, TNT, dioxane, atrazine,Methyl tert-butyl ether (MTBE) has also been remediated

Hazen, Terry C.

2010-01-01T23:59:59.000Z

395

First Annual U.S. Department of Energy Office of Science Joint Genome Institute User Meeting  

E-Print Network [OSTI]

Genome Analysis of MTBE-Degrading Beta- Proteobacteriummethyl tert- butyl ether (MTBE). Strain PM1 can alsooften co-contaminants with MTBE in groundwater, including

Various

2006-01-01T23:59:59.000Z

396

Material Safety Data Sheet 2407/2457 Series  

E-Print Network [OSTI]

Measures Suitable Extinguishing Media: Carbon dioxide. Dry chemical. Water spray. #12;Material Safety Data. Evaporation Rate (butyl Acetate=1): Not applicable. Viscosity: Not applicable. Section 10. Stability

Rollins, Andrew M.

397

E-Print Network 3.0 - apoptosis-associated reproductive defects...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reproduction and Development March 5, 2009 Summary: -98-1 Birth defects, Spontaneous abortion Known reproductive hazard for males and females. Butyl Benzyl... showed...

398

BIOINFORMATICS Vol. 20 no. 10 2004, pages 16031611  

E-Print Network [OSTI]

that the majority of most proteins fold via a cooperative process where secondary and tertiary structure form

399

Characterizing two-phase flow relative permeabilities in chemical flooding using a pore-scale network model  

E-Print Network [OSTI]

network model, enhanced oil recovery. Corresponding author.many tertiary or enhanced oil recovery (EOR) techniques have

Liu, Qingjie; Shen, Pingping; Wu, Yu-Shu

2008-01-01T23:59:59.000Z

400

U.S. Department of the Interior U.S. Geological Survey  

E-Print Network [OSTI]

Basin are unconsolidated deposits of the Tertiary Santa Fe Group. Post-Santa Fe Group deposits (piedmont

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

2 CHANCELLOR'S INTRODUCTION SECTION 01. OVERVIEW  

E-Print Network [OSTI]

with the Government's tertiary reforms, in the hope that these reforms would assist the University in meeting its of the Education (Tertiary Reform) Amendment Bill. Those provisions, if enacted, would have given the government. Other aspects of this engagement were less encouraging. It seems clear that the current tertiary reforms

Goodman, James R.

402

BULL MOUNTAIN BASIN, MONTANA By G.D. Stricker  

E-Print Network [OSTI]

Paper 1625-A 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky in the toolbar to return. 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky in vertical scale from that in figure SM-3. 1999 Resource assessment of selected Tertiary coal beds and zones

403

DATABASE CREATION AND RESOURCE EVALUATION METHODOLOGY  

E-Print Network [OSTI]

Survey Professional Paper 1625-A 1999 Resource assessment of selected Tertiary coal beds and zones here or on this symbol in the toolbar to return. 1999 Resource assessment of selected Tertiary coal Resource assessment of selected Tertiary coal beds and zones in the Northern RockyMountains and Great

404

Journal of Applied Phycology 12: 105112, 2000. 2000 Kluwer Academic Publishers. Printed in the Netherlands.  

E-Print Network [OSTI]

, tertiary treatment, wastewater Abstract As part of a program to develop biological wastewater treatment indicate that tertiary biological wastewater treatment at low temperatures (5 C) cannot be anticipated in tertiary wastewater treatment P. Chevalier1, D. Proulx1,2, P. Lessard1,3 , W.F. Vincent4 & J. de la Noe1

Vincent, Warwick F.

405

Effect of xenobiotics on the respiratory activity of rat heart mitochondria and the concomitant formation of superoxide radicals  

SciTech Connect (OSTI)

The effects of the xenobiotics atrazine, benzene, butylated hydroxyanisole (BHA), butylated hydroxytoluene (BHT), lindane, toluene, and xylenol on the respiration of isolated rate heart mitochondria were studied. Bioenergetic parameters such as respiratory control (RC) and ATP/oxygen (P/O) values decreased considerably in the presence of these substances, and a concomitant increase of superoxide radical (O[sub 2][sup [minus

Stolze, K.; Nohl, H. (Univ. of Vienna (Austria). Inst. of Pharmacology and Toxicology)

1994-03-01T23:59:59.000Z

406

Monitoring synaptic protein dynamics with higher temporal, spatial, and molecular resolution  

E-Print Network [OSTI]

Spectrometry mSOG MiniSOG MTBE Methyl tert-butyl ether mTORMethyl tert-butyl ether (MTBE, 1.4 mL) was then added for1,000 g, 5 min). The MTBE layer was collected into a 1.5-mL

Butko, Margaret

2012-01-01T23:59:59.000Z

407

Fuel-Cycle energy and emission impacts of ethanol-diesel blends in urban buses and farming tractors.  

SciTech Connect (OSTI)

About 2.1 billion gallons of fuel ethanol was used in the United States in 2002, mainly in the form of gasoline blends containing up to 10% ethanol (E10). Ethanol use has the potential to increase in the U.S. blended gasoline market because methyl tertiary butyl ether (MTBE), formerly the most popular oxygenate blendstock, may be phased out owing to concerns about MTBE contamination of the water supply. Ethanol would remain the only viable near-term option as an oxygenate in reformulated gasoline production and to meet a potential federal renewable fuels standard (RFS) for transportation fuels. Ethanol may also be blended with additives (co-solvents) into diesel fuels for applications in which oxygenation may improve diesel engine emission performance. Numerous studies have been conducted to evaluate the fuel-cycle energy and greenhouse gas (GHG) emission effects of ethanol-gasoline blends relative to those of gasoline for applications in spark-ignition engine vehicles (see Wang et al. 1997; Wang et al. 1999; Levelton Engineering et al. 1999; Shapouri et al. 2002; Graboski 2002). Those studies did not address the energy and emission effects of ethanol-diesel (E-diesel or ED) blends relative to those of petroleum diesel fuel in diesel engine vehicles. The energy and emission effects of E-diesel could be very different from those of ethanol-gasoline blends because (1) the energy use and emissions generated during diesel production (so-called ''upstream'' effects) are different from those generated during gasoline production; and (2) the energy and emission performance of E-diesel and petroleum diesel fuel in diesel compression-ignition engines differs from that of ethanol-gasoline blends in spark-ignition (Otto-cycle-type) engine vehicles. The Illinois Department of Commerce and Community Affairs (DCCA) commissioned Argonne National Laboratory to conduct a full fuel-cycle analysis of the energy and emission effects of E-diesel blends relative to those of petroleum diesel when used in the types of diesel engines that will likely be targeted first in the marketplace. This report documents the results of our study. The draft report was delivered to DCCA in January 2003. This final report incorporates revisions by the sponsor and by Argonne.

Wang, M.; Saricks, C.; Lee, H.

2003-09-11T23:59:59.000Z

408

[Research and workshop on alternative fuels for aviation. Final report  

SciTech Connect (OSTI)

The Renewable Aviation Fuels Development Center (RAFDC) at Baylor University was granted U. S. Department of Energy (US DOE) and Federal Aviation Administration (FAA) funds for research and development to improve the efficiency in ethanol powered aircraft, measure performance and compare emissions of ethanol, Ethyl Tertiary Butyl Ether (ETBE) and 100 LL aviation gasoline. The premise of the initial proposal was to use a test stand owned by Engine Components Inc. (ECI) based in San Antonio, Texas. After the grant was awarded, ECI decided to close down its test stand facility. Since there were no other test stands available at that time, RAFDC was forced to find additional support to build its own test stand. Baylor University provided initial funds for the test stand building. Other obstacles had to be overcome in order to initiate the program. The price of the emission testing equipment had increased substantially beyond the initial quote. Rosemount Analytical Inc. gave RAFDC an estimate of $120,000.00 for a basic emission testing package. RAFDC had to find additional funding to purchase this equipment. The electronic ignition unit also presented a series of time consuming problems. Since at that time there were no off-the-shelf units of this type available, one had to be specially ordered and developed. FAA funds were used to purchase a Super Flow dynamometer. Due to the many unforeseen obstacles, much more time and effort than originally anticipated had to be dedicated to the project, with much of the work done on a volunteer basis. Many people contributed their time to the program. One person, mainly responsible for the initial design of the test stand, was a retired engineer from Allison with extensive aircraft engine test stand experience. Also, many Baylor students volunteered to assemble the. test stand and continue to be involved in the current test program. Although the program presented many challenges, which resulted in delays, the RAFDC's test stand is an asset which provides an ongoing research capability dedicated to the testing of alternative fuels for aircraft engines. The test stand is now entirely functional with the exception of the electronic ignition unit which still needs adjustments.

NONE

1999-09-01T23:59:59.000Z

409

Desorption of carbon monoxide from nickel using mercaptans  

SciTech Connect (OSTI)

An IR spectroscopic study on the displacement of carbon monoxide with 1-propyl, 2-propyl-, 1-butyl-, 2-butyl-, and tert.-butyl mercaptan from nickel foil and silica-supported nickel showed that at low carbon monoxide coverage on supported nickel, mercaptan adsorption initially converted bridged to linear carbon monoxide surface species. At higher mercaptan pressures, carbon monoxide desorbed into the gas phase. A small amount of carbon monoxide remained on the surface when the poisoned sample was evacuated, and additional carbon monoxide adsorbed when 5 mm Hg of carbon monoxide was added to the evacuated sample.

Neff, L.D.; Sturdivant, A.E.; Wallace, J.L.

1980-06-01T23:59:59.000Z

410

A BRIEF HISTORY OF INDUSTRIAL CATALYSIS  

E-Print Network [OSTI]

More recently, Air Products and Chemicals Corporation hasProcess Division of Air Products & Chemicals, Inc. HC Q)air oxidation of isobutane. T-butyl alcohol is a co- product

Heinemann, Heinz

2013-01-01T23:59:59.000Z

411

Metal catalyzed copolymerization processes involving carbon oxides as substrates  

E-Print Network [OSTI]

backbone and electron donating tert-butyl groups in the phenolate rings. This catalyst was used to investigate the effect of altering the nature of the cocatalyst and its concentration. The coupling of carbon monoxide and aziridines has been shown...

Phelps, Andrea Lee

2005-11-01T23:59:59.000Z

412

9900 J. Am. Chem. SOC.1993,115, 9900-9906 Structural Analysis of Covalent Peptide Dimers,  

E-Print Network [OSTI]

and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena. Tethering two 2-PyN ligands through the nitrogens of the central pyrrole rings with propyl, butyl, pentyl

Mrksich, Milan

413

E-Print Network 3.0 - anhydride-vinyl methyl ether Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4-Methyl-2-pentanol Other secondary alcohols... - quire handling with precautions. Acrolein tert-Butyl methyl ether Di(1-propynl) ether n... Methoxy-1,3,5,7- cyclooctatetraene...

414

Accelerated Luminophore Discovery through Combinatorial Michael S. Lowry, William R. Hudson, Robert A. Pascal, Jr., and Stefan Bernhard*  

E-Print Network [OSTI]

. There are three electrochemical stages associated with light emission in a diode-type device: (1) charge injection,4-di-tert-butyl-2,2-dipyridyl), marking the highest emission energy from a single-layer device, to date

Bernhard, Stefan

415

High-resolution infrared measurements on HSOH: Analysis of the OH fundamental vibrational mode  

E-Print Network [OSTI]

-wave spectroscopy on HSOH and H34 SOH [1]. The authors used flash vacuum pyrolysis of di-tert-butyl sulfoxide] identified five of six fundamental vibrational modes of matrix isolated HSOH formed by pyrolysis of di

Giesen, Thomas

416

Incorporation of silica into baroplastic core-shell nanoparticles  

E-Print Network [OSTI]

Core-shell baroplastics are nanophase materials that exhibit pressure-induced flow at low temperatures and high pressures. Core-shell baroplastics used in this work are comprised of a low Tg poly(butyl acrylate) (PBA) core ...

Hewlett, Sheldon A

2006-01-01T23:59:59.000Z

417

Original article Novel attractants of Galleria mellonella L  

E-Print Network [OSTI]

, 1957). Methyl, ethyl, propyl, butyl, allyl esters of octanoic and decanoic acids were synthesized via the reaction of the corre- sponding acid chlorides and alcohols. Decyl and octyl acetates, methyl, ethyl

Boyer, Edmond

418

() Trichloromethane ()1,1,2,2-1,1,2,2-Tetrachloroethane  

E-Print Network [OSTI]

acetate () Ethylene glycol monobutyl ether () Ethylene glycol monomethy ether ()- O-dichlorobenzene ( ) Xylenes(o-,m-,p- isomers) () Cresol - 19 - #12;() Chlorobenzene () Amyl acetate () Isoamyl acetate () Isobutyl acetate () Isopropyl acetate () Ethyl acetate () Propyl acetate () Butyl acetate () Methyl acetate

Huang, Haimei

419

Measurements of volatile organic compounds at a suburban ground site (T1) in Mexico City during the MILAGRO 2006 campaign: measurement comparison, emission ratios, and source attribution  

E-Print Network [OSTI]

methyl tert-butyl ether (MTBE) at 57 amu has been previouslyby a fragment of MTBE (62%) with minor contributions fromFortner and Knighton, 2008). MTBE also in- terfered (16%)

2011-01-01T23:59:59.000Z

420

Synthesis of higher alcohols on copper catalysts supported on alkali-promoted basic oxides  

E-Print Network [OSTI]

-butyl-ether (MTBE) after isobutanol dehydration to form isobutene. An equimolar ratio of methanol to isobutanol would be preferred for MTBE synthesis. Methanol and higher alcohols can also be used for direct blending

Iglesia, Enrique

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Pyrolysis of Organic Molecules Relevant to Combustion as Monitored by Photoionization Time-of-Flight Mass Spectrometry  

E-Print Network [OSTI]

is observed, which is similar to MTBE in this system whichisobutene formed from MTBE, is found to occur. REFERENCES [methyl tert-butyl ether (MTBE) and tert-amyl methyl ether (

Weber, Kevin Howard

2010-01-01T23:59:59.000Z

422

APPLIED AND ENVIRONMENTAL MICROBIOLOGY, Aug. 2004, p. 47204726 Vol. 70, No. 8 0099-2240/04/$08.00 0 DOI: 10.1128/AEM.70.8.47204726.2004  

E-Print Network [OSTI]

contamination of surface and groundwater resources by the gasoline oxygenate methyl tert-butyl ether (MTBE) is leading to its phaseout. Ethanol, a likely candidate to substitute MTBE, is increasingly being used

Alvarez, Pedro J.

423

Assessing the Effectiveness of California's Underground Storage Tank Annual Inspection Rate Requirements  

E-Print Network [OSTI]

Methyl Tert-Butyl Ether (MTBE), a gasoline additive. Thefor the lions share of MTBE contamination, as well asIn response to the MTBE crisis, California increased the

Cutter, W. Bowman

2008-01-01T23:59:59.000Z

424

Trichloroethene Removal From Waste Gases in Anaerobic Biotrickling Filters Through Reductive Dechlorination  

E-Print Network [OSTI]

methyl tert-butyl ether (MTBE) vapors into water was used.MTBE is highly soluble in water (dimensionless Henrysgas stream was laden with MTBE vapors (200-300 mg m -3 )

Popat, Sudeep Chandrakant

2010-01-01T23:59:59.000Z

425

Soluble hyperbranched grafts on polyethylene surfaces  

E-Print Network [OSTI]

Here we report two methods to synthesize hyperbranched poly(acrylic acid) grafts on polyethylene films and powders. The previously reported route using ?,[]-diaminopoly(tert-butyl acrylate) was repeated and all previous results were confirmed...

Britton, Danielle M

2002-01-01T23:59:59.000Z

426

TOXICOLOGY AND APPLIED PHARMACOLOGY 81,2 13-2 19 ( 1985) Role of Extracellular Ca*+ in Toxic Liver Injury: Comparative Studies  

E-Print Network [OSTI]

perfused liver and isolated hepatocytes. The toxins t-butyl- hydroperoxide and carbon tetrachloride on extracellular Ca2+ for cytotoxic injury to cultured hepato- cytes caused by carbon tetrachloride (CC&) and 2

California at Berkeley, University of

427

Method for cleaning solution used in nuclear fuel reprocessing  

DOE Patents [OSTI]

Nuclear fuel processing solution consisting of tri-n-butyl phosphate and dodecane, with a complex of uranium, plutonium, or zirconium and with a solvent degradation product such as di-n-butyl phosphate therein, is contacted with an aqueous solution of a salt formed from hydrazine and either a dicarboxylic acid or a hydroxycarboxylic acid, thereby removing the aforesaid complex from the processing solution.

Tallent, O.K.; Crouse, D.J.; Mailen, J.C.

1980-12-17T23:59:59.000Z

428

Mineralogy and organic petrology of oil shales in the Sangkarewang formation, Ombilin Basin, West Sumatra, Indonesia.  

E-Print Network [OSTI]

??The Ombilin Basin, which lies in Sumatra Island, is one of the Tertiary basins in Indonesia. This basin contains a wide variety of rock units, (more)

Fatimah, Fatimah

2009-01-01T23:59:59.000Z

429

Fractures of the Dammam Dome Carbonate Outcrops: Their Characterization, Development, and Implications for Subsurface Reservoirs.  

E-Print Network [OSTI]

??The exposed Tertiary carbonates of the Dammam Dome present an opportunity to study fractures in outcrops within the oil-producing region of Eastern Saudi Arabia. The (more)

Al-Fahmi, Mohammed M

2012-01-01T23:59:59.000Z

430

Understanding Long-Term Storage Access Patterns  

E-Print Network [OSTI]

4 Scientific Tertiary Storage System Behavior 4.1 Datasetof analyses based on storage system traces. Bibliography [1]in heterogeneous archival storage systems. In Proceedings of

Adams, Ian Forrest

2013-01-01T23:59:59.000Z

431

atacama basin northern: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tucker 2007-02-02 44 BIOSTRATIGRAPHY, EASTERN ROCK SPRINGS UPLIFT, GREATER GREEN RIVER BASIN Environmental Sciences and Ecology Websites Summary: of selected Tertiary coal beds...

432

andesites: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Environmental Sciences and Ecology Websites Summary: ,600 meters. Geology of the basin consists of granodiorite bedrock overlain by Tertiary andesitic volcanics, which are...

433

NERSC Users Group Meeting January 28-29, 1997 Presentations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Overview of NERSC at LBNL January 28, 1997 | Author(s): Bill Kramer | Tertiary Storage January 28, 1997 | Author(s): Keith Fitzgerald, Harvard Holmes | Download File:...

434

NETL F 451.1/1-1, Categorical Exclusion Designation Form  

Broader source: Energy.gov (indexed) [DOE]

American Energy Reserves LLC SCNGO 201224 months Gary Covatch Gibson County, IN Game Changing Technology of Polymeric-Surfactants for Tertiary Oil Sample collection of crude oil...

435

E-Print Network 3.0 - acetic acid cyano- Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

using Aliphatic Tertiary Amines. Summary: CHAPTER 6 Acetic Acid Recovery from Fast Pyrolysis oil. An Exploratory Study on Liquid... of large amounts of organic acids (acetic...

436

E-Print Network 3.0 - acid derivatives sorbtsionnye Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aliphatic Tertiary Amines. Summary: , 6 due to increased demands for derivatives like vinyl acetate monomer (VAM). Currently, acetic acid... CHAPTER 6 Acetic Acid Recovery from...

437

E-Print Network 3.0 - anacardic acid derivatives Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aliphatic Tertiary Amines. Summary: , 6 due to increased demands for derivatives like vinyl acetate monomer (VAM). Currently, acetic acid... CHAPTER 6 Acetic Acid Recovery from...

438

E-Print Network 3.0 - acid derivative hs-1200-induced Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aliphatic Tertiary Amines. Summary: , 6 due to increased demands for derivatives like vinyl acetate monomer (VAM). Currently, acetic acid... CHAPTER 6 Acetic Acid Recovery from...

439

Geothermal Literature Review At Lightning Dock Geothermal Area...  

Open Energy Info (EERE)

Evidence for Large-Scale Laramide Tectonic Inversion and a Mid-Tertiary Caldera Ring Fracture Zone at the Lightning Dock Geothermal System, New Mexico Additional References...

440

alpha hydroxy-5 cap: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

violating conversion mu + A rightarrow e + A, using tertiary muons from high-power pulsed proton beams. In these experiments the products of ordinary muon capture in...

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

ammonium cap alpha: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

violating conversion mu + A rightarrow e + A, using tertiary muons from high-power pulsed proton beams. In these experiments the products of ordinary muon capture in...

442

aot capped cadmium: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

violating conversion mu + A rightarrow e + A, using tertiary muons from high-power pulsed proton beams. In these experiments the products of ordinary muon capture in...

443

Admission Requirements for Mature Age Applicants  

E-Print Network [OSTI]

. UNIVERSITYADMISSION2014 TISC TERTIARY INSTITUTIONS SERVICE CENTRE (incorporated in Western Australia) 100 Royal Street ............................................................................ The University of Western Australia ........................................................ Course Prerequisites .............................................................................. The University of Western Australia ........................................................ Addresses

444

Admission Requirements for Mature Age Applicants  

E-Print Network [OSTI]

. UNIVERSITYADMISSION2015 TISC TERTIARY INSTITUTIONS SERVICE CENTRE (incorporated in Western Australia) Level 1 100 ............................................................................ The University of Western Australia ........................................................ Course Prerequisites .............................................................................. The University of Western Australia ........................................................ Addresses

445

TABLE33.CHP:Corel VENTURA  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

processed; all other products are reported by the PAD District of entry. b Includes crude oil imported for storage in the Strategic Petroleum Reserve. c Includes ethyl tertiary...

446

TABLE34.CHP:Corel VENTURA  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

processed; all other products are reported by the PAD District of entry. b Includes crude oil imported for storage in the Strategic Petroleum Reserve. c Includes ethyl tertiary...

447

Retreat of the state and the market: liberalisation and education expansion in Sudan under the NCP.  

E-Print Network [OSTI]

??This thesis is an analysis of two concurrent processes - the liberalisation of the economy and the expansion of the tertiary education system - by (more)

Mann, Laura Elizabeth

2012-01-01T23:59:59.000Z

448

E-Print Network 3.0 - antigenic protein fractions Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

characteristics is focused on antigenic proteins. Epitopes play... another through protein folding. Thus, the importance of the tertiary conformation of the antigen... that are...

449

E-Print Network 3.0 - aryl bisdiazeniumdiolates potent Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Hindered Alkyl-Aryl Ethers Thomas F. Woiwode... synthesis.2 Our retrosynthetic analysis of phomopsin A targeted the chiral tertiary alkyl-aryl ether... substitution (SNAr)...

450

area baja california: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Todos Santos Bay is bordered on the north by narrow beaches, terraces, and sea cliffs cut into Tertiary sediments and dioritic mountains. just north of Punta San Miguel,...

451

Shallow seismic investigations in the Valles Caldera  

E-Print Network [OSTI]

type · Complex shallow structure Davidson, M. Thesis, Perdue Univ. 1999 unconsolidated sediments fill Davidson, M. Thesis, Perdue Univ. 1999 unconsolidated sediments Permian/tertiary sediments

West, Michael

452

E-Print Network 3.0 - acute cardiac care Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: patients are enrolled in cardiac rehabilitation programmes, both from the health care staV and other... being discharged from a tertiary care centre in western...

453

E-Print Network 3.0 - aliphatic amines extraction Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

; Environmental Sciences and Ecology 37 Exploratory Studies on Fast Pyrolysis Oil Upgrading Summary: using Aliphatic Tertiary Amines... -1 Acetic Acid Recovery from Fast...

454

aerobic packed-bed biofilm: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation Dietrich, Lars 98 Application of a moving bed biofilm reactor for tertiary ammonia treatment in high temperature industrial wastewater Environmental Management and...

455

Non-phosphate degradation products of tributyl phosphate  

SciTech Connect (OSTI)

Tributyl phosphate(TBP) was compulsively degraded with nitric acid and/or uranium nitrate at elevated temperature around 105{degrees}C. Experimental results indicates major non-phosphate degradation products are butyl nitrate (C{sub 4}H{sub 9}NO{sub 3}), propionic acid (C{sub 2}H{sub 5}COOH), acetic acid (CH{sub 3}COOH), butyric acid (C{sub 3}H{sub 7}COOH) and butyl alcohol (C{sub 4}H{sub 9}OH) in ascending order of quantity. Degrading rate in uranium free system is less than that in uranium coexisting system. Carboxylic acids were not produced in uranium free system, and only acetic acid was identified in case of without supplying nitric acid from aqueous phase. Moreover, from the experimental study on the reactivity of each non-phosphate product with nitric acid, carboxylic acids were identified as byproducts of butyl alcohol and butyl nitrate, and each carboxylic acid was stable in these degrading conditions. Finally, butyl alcohol is considered as one of intermediate products to butyl nitrate and carboxylic acids. From this study, the non-phosphate degradation products of TBP is identified and the degrading reaction pass is proposed. Extraction behavior of each non-phosphate product and reactivity of degraded TBP are also elucidated.

Tashiro, Y.; Kodama, R.; Sugai, H. [Japan Nuclear Fuel Ltd., Aomori (Japan)] [and others

1995-12-01T23:59:59.000Z

456

Prediction of diet quality parameters of Rocky Mountain Elk via near infrared reflectance spectroscopy (NIRS) fecal profiling  

E-Print Network [OSTI]

?) of the National Council for Air and Stream Improvement (N.C.A.S.I.) bottle-raised and trained all the tame elk and built the research facilities at Boise Cascade Corporation?s Kamela, Ore., research site and provided needed information on the handling and care... heroes. Austin Blaney was always on hand to grind the many tons of forages or hammer nails in the construction of the elk feeding facility that we built. And to my friends Jim and Blanton Beard of Greenbranch Deer Farm, who loaned me the use...

Keating, Marvin Scott

2006-08-16T23:59:59.000Z

457

Hydrocarbon Processing`s HPI construction boxscore update  

SciTech Connect (OSTI)

Data are compiled for oil and gas industry construction projects worldwide, listing country (and state or province, when appropriate), company, location of the project, purpose, plant capacity, estimated cost, current status, licensor, engineering firm, and construction company. Projects include carbon monoxide, urea, ammonia, isomerizer, hydrogen, alkylation, TAME, desalter, hydrotreating, sulfur, waste gas cleanup, catalytic reformer, ethylene recovery, natural gas helium, nitrogen removal, NGL recovery, cumene, dewaxer, polystyrene, vinyl chloride, synthesis gas, formaldehyde, FCC cracker, isobutylene, H{sub 2}S removal, cogeneration, methanol, delayed coker, gas oil treater, NGL fractionation, BTX, information systems, control systems, waste water cleanup, glycol treater, acid gas removal, LPG, MTBE, caustic cleanup, visbreaker, naphtha treater, and others.

NONE

1996-02-01T23:59:59.000Z

458

UNIVERSITY OF THE WITWATERSRAND, JOHANNESBURG FACULTY OF SCIENCE  

E-Print Network [OSTI]

position in the School of Statistics and Actuarial Science. Minimum qualifications/requirements/criteria: A relevant Matric qualification + applicable experience in tertiary education of at least three years. A tertiary qualification would be an advantage. Computer skills (MSOffice) and knowledge and experience

Wagner, Stephan

459

COAL RESOURCES, POWDER RIVER BASIN By M.S. Ellis,1  

E-Print Network [OSTI]

, Delaware 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky in the toolbar to return. 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky resources in the Powder River Basin reported by 7.5-minute quadrangle map area 1999 Resource assessment

460

Accommodation of a highly symmetric core within a symmetric protein superfold  

E-Print Network [OSTI]

threefold symmetry present in the tertiary structure of the protein fold (the -trefoil superfold factor; de novo design; superfold; protein evolution; -trefoil The protein-folding problem is one tertiary structures can be categorized into 1 of 10 fundamental protein folds (Orengo et al. 1994; Thornton

Blaber, Michael

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

FORT UNION COAL IN THE GREATER GREEN RIVER BASIN, EAST FLANK OF THE ROCK SPRINGS UPLIFT,  

E-Print Network [OSTI]

Chapter GS FORT UNION COAL IN THE GREATER GREEN RIVER BASIN, EAST FLANK OF THE ROCK SPRINGS UPLIFT 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky in the toolbar to return. 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky

462

SHERIDAN COALFIELD, POWDER RIVER BASIN: GEOLOGY, COAL QUALITY, AND COAL RESOURCES  

E-Print Network [OSTI]

Chapter PH SHERIDAN COALFIELD, POWDER RIVER BASIN: GEOLOGY, COAL QUALITY, AND COAL RESOURCES By M assessment of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great

463

Summary of lithologic logging of new and existing boreholes at Yucca Mountain, Nevada, August 1993 to February 1994  

SciTech Connect (OSTI)

Yucca Mountain, Nevada, is being investigated as a potential site for a high-level radioactive waste repository. This report summarizes the lithologic logging of new and existing boreholes at Yucca Mountain that was done from August 1993 to February 1994 by the Rock Characteristics Section, Yucca Mountain Project Branch, US Geological Survey (USGS). Units encountered during logging include Quaternary-Tertiary alluvium/colluvium, Tertiary Rainier Mesa Tuff, all units in the Tertiary Paintbrush Group, Tertiary Calico Hills Formation and Tertiary Prow Pass Tuff. We present criteria used for recognition of stratigraphic contacts, logging results as tables of contact depths for core from neutron (UZN) boreholes and graphical lithologic logs for core from non-UZN boreholes, and descriptions of several distinctive nonwelded tuffs recognized in the PTn hydrogeologic unit of the Paintbrush Group.

Geslin, J.K.; Moyer, T.C.; Buesch, D.C.

1995-05-01T23:59:59.000Z

464

IMPACT OF OXYGENATED FUEL ON DIESEL ENGINE PERFORMANCE AND EMISSIONS  

SciTech Connect (OSTI)

As evidenced by recent lawsuits brought against operators of large diesel truck fleets [1] and by the Consent Decree brought against the heavy-duty diesel manufacturers [2], the environmental and health effects of diesel engine emissions continue to be a significant concern. Reduction of diesel engine emissions has traditionally been achieved through a combination of fuel system, combustion chamber, and engine control modifications [3]. Catalytic aftertreatment has become common on modern diesel vehicles, with the predominant device being the diesel oxidation catalytic converter [3]. To enable advanced after-treatment devices and to directly reduce emissions, significant recent interest has focused on reformulation of diesel fuel, particularly the reduction of sulfur content. The EPA has man-dated that diesel fuel will have only 15 ppm sulfur content by 2007, with current diesel specifications requiring around 300 ppm [4]. Reduction of sulfur will permit sulfur-sensitive aftertreatment devices, continuously regenerating particulate traps, NOx control catalysts, and plasma assisted catalysts to be implemented on diesel vehicles [4]. Another method of reformulating diesel fuel to reduce emissions is to incorporate oxygen in the fuel, as was done in the reformulation of gasoline. The use of methyl tertiary butyl ether (MTBE) in reformulated gasoline has resulted in contamination of water resources across the country [5]. Nonetheless, by relying on the lessons learned from MTBE, oxygenation of diesel fuel may be accomplished without compromising water quality. Oxygenation of diesel fuel offers the possibility of reducing particulate matter emissions significantly, even for the current fleet of diesel vehicles. The mechanism by which oxygen content leads to particulate matter reductions is still under debate, but recent evidence shows clearly that ''smokeless'' engine operation is possible when the oxygen content of diesel fuel reaches roughly 38% by weight [6]. The potential improvements in energy efficiency within the transportation section, particularly in sport utility vehicles and light-duty trucks, that can be provided by deployment of diesel engines in passenger cars and trucks is a strong incentive to develop cleaner burning diesel engines and cleaner burning fuels for diesel engines. Thus, serious consideration of oxygenated diesel fuels is of significant practical interest and value to society. In the present work, a diesel fuel reformulating agent, CETANERTM, has been examined in a popular light-medium duty turbodiesel engine over a range of blending ratios. This additive is a mixture of glycol ethers and can be produced from dimethyl ether, which itself can be manufactured from synthesis gas using Air Products' Liquid Phase Dimethyl Ether (LPDME TM) technology. CETANERTM is a liquid, has an oxygen content of 36 wt.%, has a cetane number over 100 and is highly miscible in diesel fuel. This combination of physical and chemical properties makes CETANERTM an attractive agent for oxygenating diesel fuel. The present study considered CETANERTM ratios from 0 to 40 wt.% in a California Air Resources Board (CARB) specification diesel fuel. Particulate matter emissions, gaseous emissions and in-cylinder pressure traces were monitored over the AVL 8-Mode engine test protocol [7]. This paper presents the results from these measurements and discusses the implications of using high cetane number oxygenates in diesel fuel reformulation.

Boehman, Andre L.

2000-08-20T23:59:59.000Z

465

DME-to-oxygenates process studies  

SciTech Connect (OSTI)

The feasibility of the production of hydrocarbons from dimethyl ether (DNM) has been illustrated in a fixed bed micro-reactor as well as a bench scale fluidized bed reactor by the University of Akron/EPRI DME-to-Hydrocarbon (DTG) Process. The DTG process has distinct advantages over its methanol based counterpart. Specifically, the DTG process excels in the area of higher productivity, higher per-pass conversion, and lower heat duties than the MTG process. Also of special importance is the production of oxygenates -- including MTBE, ETBE, and TAME. DME may be reacted with isobutylene to produce a mixture of MTBE and ETBE. The properties of ETBE excel over MTBE in the areas of lower RVP and higher RON. According to industrial reports, MTBE is the fastest growing chemical (1992 US capacity 135,350 BPD, with expected growth of 34%/year to 1997). Also, recent renewed interest as an octane-enhancer and as a source of oxygen has spurred a growing interest in nonrefinery synthesis routes to ETBE. TAME, with its lower RVP and higher RON has proven useful as a gasoline blending agent and octane enhancer and may also be produced directly from DME. DME, therefore, serves as a valuable feedstock in the conversion of may oxygenates with wide-scale industrial importance. It should be also noted that the interest in the utilization of DME as process feedstock is based on the favorable process economics of EPRI/UA`s liquid phase DME process.

Tartamella, T.L.; Sardesai, A.; Lee, S. [Univ. of Akron, OH (United States); Kulik, C.J. [Electric Power Research Inst., Palo Alto, CA (United States)

1994-12-31T23:59:59.000Z

466

Reactivity of tributyl phosphate degradation products with nitric acid: Relevance to the Tomsk-7 accident  

SciTech Connect (OSTI)

The reaction of a degraded tributyl phosphate (TBP) solvent with nitric acid is thought to have caused the chemical explosion at the Tomsk-7 reprocessing plant at Tomsk, Russia in 1993. The estimated temperature of the organic layer was not high eneough to cause significant reaction of nitric acid with TBP or hydrocarbon diluent compounds. A more reactive organic compound was likely present in the organic layer that reacted with sufficient heat generation to raise the temperature to the point where an autocatalytic oxidation of the organic solvent was initiated. Two of the most likely reactive compounds that are present in degraded TBP solvents are n-butanol and n-butyl nitrate. The reactions of these compounds with nitric acid are the subject of this study. The objective of laboratory-scale tests was to identify chemical reactions that occur when n-butanol and n-butyl nitrate contact heated nitric acid solutions. Reaction products were identified and quantitified, the temperatures at which these reactions occur and heats of reaction were measured, and reaction variables (temperature, nitric acid concentration, organic concentration, and reaction time) were evaluated. Data showed that n-butyl nitrate is less reactive than n-butanol. An essentially complete oxidation reaction of n-butanol at 110-120 C produced four major reaction products. Mass spectrometry identified the major inorganic oxidation products for both n-butanol and n-butyl nitrate as nitric oxide and carbon dioxide. Calculated heats of reaction for n-butanol and n-butyl nitrate to form propionic acid, a major reaction product, are -1860 cal/g n-butanol and -953 cal/g n-butyl nitrate. These heats of reaction are significant and could have raised the temperature of the organic layer in the Tomsk-7 tank to the point where autocatalytic oxidation of other organic compounds present resulted in an explosion.

Barney, G.S.; Cooper, T.D. [Westinghouse Hanford Company, Richland, WA (United States)

1995-12-31T23:59:59.000Z

467

Radioisotope Thermoelectric Generator Package O-Ring Seal Material Validation Testing  

SciTech Connect (OSTI)

The Radioisotope Thermoelectric Generator Package O-Ring Seal Material Validation Test was conducted to validate the use of the Butyl material as a primary seal throughout the required temperature range. Three tests were performed at (1) 233 K ({minus}40 {degrees}F), (2) a specified operating temperature, and (3) 244 K ({minus}20 {degrees}F) before returning to room temperature. Helium leak tests were performed at each test point to determine seal performance. The two major test objectives were to establish that butyl rubber material would maintain its integrity under various conditions and within specified parameters and to evaluate changes in material properties.

Adkins, H.E.; Ferrell, P.C.; Knight, R.C.

1994-09-30T23:59:59.000Z

468

Emission Control and Elimination Through The Use Of Condensation and Heat Recovery Technologies- A Case Study  

E-Print Network [OSTI]

be no addition of water in the process, the level of water in the condensate would falloff dramatically. A prototype unit capable of handling three ovens with a total air flow of 1200 ft 3 /min (cfm) was installed. The unit performed as expected... ether (butyl cellosolve) and propylene glycol monomethyl ether. Butyl cellosolve is a regulated glycol ether (which is a HAP). At the oven process temperatures, the vapor pressure of the solvent mixture is 250 rom Hg. This corresponds to a saturated...

Madewell, A. E.; Bullock, W. N.

469

BRIGHAM YOUNG UNIVERSITY GEOLOGY STUDIES  

E-Print Network [OSTI]

#12;BRIGHAM YOUNG UNIVERSITY GEOLOGY STUDIES Volume 33, Part 1 CONTENTS Tertiary Geologic History Geology of the Deadman Canyon 7112-Minute Quadrangle, Carbon County, Utah, Utah. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .James Douglas Smith 135 Geology

Seamons, Kent E.

470

Gravity modeling of Cenozoic extensional basins, offshore Vietnam  

E-Print Network [OSTI]

(Yinggehai) basins. Gravity modeling results provide important clues to the controversial tectonic development of Southeast Asia during the Tertiary. Combined Bouguer and free-air gravity maps and residual gravity anomaly maps were generated for the study...

Mauri, Steven Joseph

1993-01-01T23:59:59.000Z

471

Timing and Tectonic implications of basin inversion in the Nam Con Son Basin and adjacent areas, southern South China Sea  

E-Print Network [OSTI]

The Nam Con Son (NCS) Basin, located offshore of SE Vietnam, is one of several Tertiary rift basins that formed during initial Eocene(?)-Oligocene rifting. Following cessation of rifting at the end of Oligocene time, these basins were subjected...

Olson, Christopher Charles

2001-01-01T23:59:59.000Z

472

Risk Management Procedures Category: Strategic Management  

E-Print Network [OSTI]

/POLICY SUPPORTED Risk Management Policy Tertiary Education Quality Standards Agency Act 2011 (TEQSA Act 2011) 21 Risk Management Procedures Category: Strategic Management 1. LEGISLATION/ENTERPRISE AGREEMENT. PROCEDURAL DETAILS 2.1. Responsibilities Entity / Officer Responsibilities Planning and Management Committee

473

Membrane Bioreactors: Past, Present and Future?  

E-Print Network [OSTI]

Treatment, Elsevier King County Brightwater WastewaterJudd and Judd, 2006 ], King County, WA, USA (136,000 m3 /d in 2011) [King County] and tertiary treatment at

Hermanowicz, Slav W

2011-01-01T23:59:59.000Z

474

Pediatric Intestinal Failure Associated Liver Disease is Revered with Six Months of Intravenous Fish Oil  

E-Print Network [OSTI]

3. Secondary and tertiary outcomes for the fish oil (FO)and soybean oil (SO) group. Results are either as medianserror of the mean for the fish oil (FO) and soybean oil (SO)

Calkins, Kara

2013-01-01T23:59:59.000Z

475

[superscript 15]N-[superscript 15]N Proton Assisted Recoupling in Magic Angle Spinning NMR  

E-Print Network [OSTI]

We describe a new magic angle spinning (MAS) NMR experiment for obtaining [superscript 15]N?[superscript 15]N correlation spectra. The approach yields direct information about the secondary and tertiary structure of proteins, ...

Lewandowski, Jozef R.

476

ch3probs Page 1 of 9 http://www.jbpub.com/fox/supplementalproblems/ch3pr.htm 11/18/2003  

E-Print Network [OSTI]

-ethyl-2-pentanone e. 3-methylbutanal f. ethanoic anhydride (acetic anhydride) g. ethyl butanoate h. 2. oxidation d. reduction 3.29 a. primary b. tertiary c. primary d. benzylic e. benzylic f. allylic g

Walba, David

477

E-Print Network 3.0 - alpha 2-plasmin inhibitor Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

best buffer at pH 5.0? Summary: ) secondary structure C) tertiary structure D) random coil structure E) alpha-helical structure 12... -H group is small C) free rotation is...

478

Optimizing hysteretic power loss of magnetic ferrite nanoparticles  

E-Print Network [OSTI]

This thesis seeks to correlate hysteretic power loss of tertiary ferrite nanoparticles in alternating magnetic fields to trends predicted by physical models. By employing integration of hysteresis loops simulated from ...

Chen, Ritchie

2013-01-01T23:59:59.000Z

479

Development of a Digital Fringe Projection Technique to Characterize the Transient Behavior of Wind-Driven Droplet/Rivulet Flows  

E-Print Network [OSTI]

endeavor, including lava flows in geology, tertiary oil recovery, lubricant oil films in tribology, surface and environmental problems ranging from microchip manufacturing, structured packing to lava flows in geology

Hu, Hui

480

More seeing in learning  

E-Print Network [OSTI]

Recently, creativity has received increased attention for educational programs from primary to tertiary levels. This research examines the intricacies of the creative process to understand what creativity is and how an ...

Arida, Saeed (Saeed Abdulkarim), 1977-

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Evidence for Large-Scale Laramide Tectonic Inversion and a Mid...  

Open Energy Info (EERE)

Scale Laramide Tectonic Inversion and a Mid-Tertiary Caldera Ring Fracture Zone at the Lightning Dock Geothermal System, New Mexico Jump to: navigation, search OpenEI Reference...

482

Fish Tagging Forum March 22, 2012  

E-Print Network [OSTI]

, Predation, and Population Status Recovery. o For each Tab, there are columns listing: Column A: numbered, such as primary, secondary or tertiary interest. o Other less commonly used tag types will be cons

483

Unfolding of Titin Domains Explains the Viscoelastic Behavior of Skeletal Myofibrils  

E-Print Network [OSTI]

of hysteresis recovery. The rate constants of recovery compared well with the refolding rates of Ig with a high content of Pro (P), Glu (E), Val (V), and Lys (K), but no obvious secondary or tertiary structure

Fernandez, Julio M.

484

CX-007928: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Game Changing Technology of Polymeric-Surfactants for Tertiary Oil CX(s) Applied: A9, B3.6 Date: 02/22/2012 Location(s): Indiana Offices(s): National Energy Technology Laboratory

485

CX-007922: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Game Changing Technology of Polymeric-Surfactants for Tertiary Oil CX(s) Applied: A9, B3.6 Date: 02/23/2012 Location(s): California Offices(s): National Energy Technology Laboratory

486

Protein folding and macromolecular dynamics : fundamental limits of length and time scales.  

E-Print Network [OSTI]

??In this thesis, physics-based models of protein folding at the secondary and tertiary level are developed to resolve long-standing issues of protein folding kinetics. As (more)

Lin, Milo M.

2012-01-01T23:59:59.000Z

487

Adding a Medical Lexicon to an English Parser Peter Szolovits, PhD  

E-Print Network [OSTI]

in the Emergency Department of a large urban tertiary care pediatric hospital (ED), the Link Grammar Parser (LP) [3 summaries, radiology and pathology notes, etc., are nevertheless stored simply as text. 2 This assumes

Szolovits, Peter

488

ENERGY & ENVIRONMENT DIVISION. ANNUAL REPORT FY 1980  

E-Print Network [OSTI]

and J. Sathaye Enhanced Oil Recovery J. Sathaye and M.gallons/ day/ft. ) ENHANCED OIL RECOVERY* J. Sathaye and M.of tertiary or enhanced oil recovery (EOR). These methods

Authors, Various

2010-01-01T23:59:59.000Z

489

GEOLOGY AND HYDROTHERMAL ALTERATION OF THE RAFT RIVER GEOTHERMAL...  

Open Energy Info (EERE)

the base of the Tertiary deposits in RRG-9. The results of thermal and quasi-static mechanical property measurements that were conducted on the core sample are presented. Authors...

490

Tectonic Evolution of the Contaya Arch Ucyali Basin, Peru  

E-Print Network [OSTI]

after deposition of the Pozo Formation sands and shales. To the east of this is the Contaya high. This structure originally formed during the Triassic-Jurassic and was later reactivated in the Tertiary. The easternmost structure, the Moa divisor...

Navarro Zelasco, Luis

2011-08-08T23:59:59.000Z

491

"Simple paperwork made applying for a loan very easy."  

E-Print Network [OSTI]

Commission Public Programs Office (916) 654-4147 pubprog@energy.state.ca.us See Case Study on Back of Flyer at the adjacent wastewater treatment plant. Recently the city upgraded the plant to tertiary wastewater treatment

492

asce denver colorado: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

BASIN, COLORADO By D. J. Nichols in U.S. Geological Survey Professional Paper 1625-A 1999 Resource assessment of selected Tertiary coal beds and zones here or on this symbol in the...

493

Phase selectively soluble polymers for homogeneously supported catalysts  

E-Print Network [OSTI]

synthetic step towards the preparation of the catalytic species. N alkylation of a PIB-supported triazole provides a direct route to the preparation of a PTC. Preparation of a tertiary phosphoninium salt containing a terminal alkyne allows simple attachment...

Sung, Shayna D

2006-10-30T23:59:59.000Z

494

PROCEEDINGS, Thirty-Seventh Workshop on Geothermal Reservoir Engineering Stanford University, Stanford, California, January 30 -February 1, 2012  

E-Print Network [OSTI]

: Organic Rankine Cycle) with maximal installed net capacity of 1.5MWe (Figure 1). Several deep geothermal wells penetrated a hidden fractured granite located in this Tertiary graben. For the sub

Boyer, Edmond

495

Deformation, erosion and sedimentation in collisional orogens : case studies from eastern Tibet and southwestern China  

E-Print Network [OSTI]

This dissertation addresses aspects of the tectonics of regions adjacent to the eastern Himalayan syntaxis. The first chapter describes the Tertiary Gonjo basin, includes structural and sedimentologic observations, and ...

Studnicki-Gizbert, Christopher Terrance

2006-01-01T23:59:59.000Z

496

E-Print Network 3.0 - azeite transtensional shear Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

> >> Page: << < 1 2 3 4 5 > >> 41 Tertiary Evolution of the Three Pagodas Fault, Western Thailand Summary: ductile left-lateral shear zone in a transpressional environment as it...

497

The Case for ApplicationSpecific Operating Systems  

E-Print Network [OSTI]

The Case for Application­Specific Operating Systems Thomas E. Anderson Division of Computer Science processors, higher bandwidth networks, and larger amounts of pri­ mary, secondary, and tertiary storage

Anderson, Tom

498

Opportunities for Energy Efficiency and Open Automated Demand Response in Wastewater Treatment Facilities in California -- Phase I Report  

E-Print Network [OSTI]

biological operations. Tertiary treatment processes wastewaterwastewater treatment system, called the Living Machine, uses natural non-chemical biologicalbiological (Wilkinson 2000). Each type generally refers to a certain point in the wastewater treatment

Lekov, Alex

2010-01-01T23:59:59.000Z

499

Late Cenozoic seismic stratigraphy and structure of the northern Gulf of Alaska  

E-Print Network [OSTI]

are richly organic and have been the source for numerous oil and gas seeps (Plafker, 1971). The Miocene to early Pleistocene marine clastic rocks contain abundant glacial detritus and lie unconformably upon the middle Tertiary sequence (Plafker et al... of this thesis follows the style of the American Association of Petroleum Geologists Bulletin. traps. It is the presence of these geological structures and organic- rich middle Tertiary strata (possible source rocks) that has led to the exploration...

Roden, Rocky Ray

1980-01-01T23:59:59.000Z

500

Surfactant-Polymer Interaction for Improved Oil Recovery  

SciTech Connect (OSTI)

The goal of this research was to use the interaction between a surfactant and a polymer for efficient displacement of tertiary oil by improving slug integrity, oil solubility in the displacing fluid and mobility control. Surfactant-polymer flooding has been shown to be highly effective in laboratory-scale linear floods. The focus of this proposal is to design an inexpensive surfactant-polymer mixture that can efficiently recover tertiary oil by avoiding surfactant slug degradation and viscous/heterogeneity fingering.

Gabitto, Jorge; Mohanty, Kishore K.

2002-01-07T23:59:59.000Z