Powered by Deep Web Technologies
Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

State Restrictions on Methyl Tertiary Butyl Ether (released in AEO2006)  

Reports and Publications (EIA)

By the end of 2005, 25 States had barred, or passed laws banning, any more than trace levels of MTBE in their gasoline supplies, and legislation to ban MTBE was pending in 4 others. Some State laws address only MTBE; others also address ethers such as ethyl tertiary butyl ether (ETBE) and tertiary amyl methyl ether (TAME). AEO2006 assumes that all State MTBE bans prohibit the use of all ethers for gasoline blending.

Information Center

2006-02-01T23:59:59.000Z

2

Catalytic distillation for the synthesis of tertiary butyl alcohol.  

E-Print Network (OSTI)

??Catalytic Distillation for the synthesis of tertiary butyl alcohol (TBA) is investigated in this thesis. The solvent, ethylene glycol, is proposed as a means of… (more)

Safinski, Tomasz

2005-01-01T23:59:59.000Z

3

Enhanced diisobutene production in the presence of methyl tertiary butyl ether  

DOE Patents (OSTI)

In the liquid phase reaction of isobutene in the presence of resin cation exchange resins with itself in a C[sub 4] hydrocarbon stream to form dimers, the formation of higher polymers, oligomers, and co-dimer by-products is suppressed by the presence of 0.0001 to 1 mole per mole of isobutene of methyl tertiary butyl ether. 1 fig.

Smith, L.A. Jr.

1983-03-01T23:59:59.000Z

4

Ethyl-tertiary-butyl-ether (ETBE) as an aviation fuel: Eleventh international symposium on alcohol fuels  

DOE Green Energy (OSTI)

This paper discusses the preliminary flight testing of an aircraft using neat burning ethyl-tertiary-butyl-ether (ETBE) as a fuel. No additional changes were made to the fuel delivery systems which had previously been modified to provide the higher fuel flow rates required to operate the engine on neat ethanol. Air-fuel ratios were manually adjusted with the mixture control. This system allows the pilot to adjust the mixture to compensate for changes in air density caused by altitude, pressure and temperature. The engine was instrumented to measure exhaust gas temperatures (EGT), cylinder head temperatures (CHT), and fuel flows, while the standard aircraft instruments were used to collect aircraft performance data. Baseline engine data for ETBE and Avgas are compared. Preliminary data indicates the technical and economic feasibility of using ETBE as an aviation fuel for the piston engine fleet. Furthermore, the energy density of ETBE qualifies it as a candidate for a turbine engine fuel of which 16.2 billion gallons are used in the US each year.

Maben, G.D.; Shauck, M.E.; Zanin, M.G.

1996-12-31T23:59:59.000Z

5

Frozen Bullets Tame Unruly Edge Plasmas in Fusion Experiment...  

NLE Websites -- All DOE Office Websites (Extended Search)

Frozen Bullets Tame Unruly Edge Plasmas in Fusion Experiment American Fusion News Category: General Atomics (GA) Link: Frozen Bullets Tame Unruly Edge Plasmas in Fusion Experiment...

6

LLNL-CONF-409744 An Experiment to Tame the  

E-Print Network (OSTI)

LLNL-CONF-409744 An Experiment to Tame the Plasma Material Interface R. J. Goldston, J. E. Menard supported in part by U.S. DOE Contract # DE-AC02-76CH03073 Prepared by LLNL under Contract DE-AC52-07NA27344

Harilal, S. S.

7

An Experiment to Tame the Plasma Material Interface  

SciTech Connect

The plasma material interface in Demo will be more challenging than that in ITER, due to requirements for approximately four times higher heat flux from the plasma and approximately five times higher average duty factor. The scientific and technological solutions employed in ITER may not extrapolate to Demo. The key questions to be resolved for Demo and the resulting key requirements for an experiment to 'tame the plasma material interface' are analyzed. A possible design point for such an experiment is outlined.

Goldston, R J; Menard, J E; Allain, J P; Brooks, J N; Canik, J M; Doerner, R; Fu, G; Gates, D A; Gentile, C A; Harris, J H; Hassanein, A; Gorelenkov, N N; Kaita, R; Kaye, S M; Kotschenreuther, M; Kramer, G J; Kugel, H W; Maingi, R; Mahajan, S M; Majeski, R; Neumeyer, C L; Nygren, R E; Ono, M; Owen, L W; Ramakrishnan, S; Rognlien, T D; Ruzic, D N; Ryutov, D D; Sabbagh, S A; Skinner, C H; Soukhanovskii, V A; Stevenson, T N; Ulrickson, M A; Valanju, P M; Woolley, R D

2009-01-08T23:59:59.000Z

8

Refinery & Blenders Net Input of Methyl Tertiary Butyl Ether ...  

U.S. Energy Information Administration (EIA)

-No Data Reported; --= Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Notes: RBOB with Ether, RBOB ...

9

Experimental Pathology Laboratories, Inc. Ethyl-Tertiary-Butyl Ether  

E-Print Network (OSTI)

a plantation about 15-year-old in the Les Cedres area, near Montreal (45820H N, 73854H W). Trees in open

Bandettini, Peter A.

10

A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion  

NLE Websites -- All DOE Office Websites (Extended Search)

A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion Plasmas Recent experiments have confirmed the great potential of a novel plasma-material interface concept. By U.S Department of Energy Office of Science October 31, 2012 Tweet Widget Facebook Like Google Plus One National Spherical Torus Experiment (Photo by Elle Starkman, Office of Communications, PPPL) National Spherical Torus Experiment The Science Heat escaping from the core of a twelve-million degree nuclear fusion plasma device was successfully contained by a snowflake-shaped magnetic field to mitigate its impact on device walls. The Impact One of the grand challenges of the magnetic fusion research is to "tame the plasma-material interface"-to develop an interface between the hot

11

A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion  

NLE Websites -- All DOE Office Websites (Extended Search)

A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion Plasmas Fusion Energy Sciences (FES) FES Home About Research Facilities Science Highlights Benefits of FES Funding Opportunities Fusion Energy Sciences Advisory Committee (FESAC) News & Resources Contact Information Fusion Energy Sciences U.S. Department of Energy SC-24/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-4941 F: (301) 903-8584 E: sc.fes@science.doe.gov More Information » October 2012 A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion Plasmas Recent experiments have confirmed the great potential of a novel plasma-material interface concept. Print Text Size: A A A Subscribe FeedbackShare Page Click to enlarge photo. Enlarge Photo

12

Proving Correctness of the Basic TESLA Multicast Stream Authentication Protocol with TAME  

E-Print Network (OSTI)

Proving Correctness of the Basic TESLA Multicast Stream Authentication Protocol with TAME Presented, Washington, DC 20375 E-mail: archer@itd.nrl.navy.mil The TESLA multicast stream authentication protocol just been revealed. While an informal argument for the correctness of TESLA has been published

13

NETL: News Release - Florida Demo Tames High Sulfur Coal: Delivers Power at  

NLE Websites -- All DOE Office Websites (Extended Search)

March 11, 2005 March 11, 2005 Florida Demo Tames High Sulfur Coal: Delivers Power at Very Low Emissions Shows that New Technology Cuts Pollutants to Fractions of Federal Clean Air Limits JACKSONVILLE, FL - Recent tests with one of the nation's mid- to high-sulfur coals have further verified that a new electric generation technology in its first large-scale utility demonstration here is one of the world's cleanest coal-based power plants. This city's municipal utility JEA logged the achievement at its Northside Generating Station using Illinois No. 6 coal in a 300 megawatt demonstration of circulating fluidized bed (CFB) combustion, which is the largest application yet of the new form in the United States. It almost triples the size of a previous demonstration and scales up the technology to the sizes preferred for adding new plants and replacing old ones, also called repowering.

14

Tertiary carbonate reservoirs in Indonesia  

Science Conference Proceedings (OSTI)

Hydrocarbon production from Tertiary carbonate reservoirs accounted for ca. 10% of daily Indonesian production at the beginning of 1978. Environmentally, the reservoirs appear as parts of reef complexes and high-energy carbonate deposits within basinal areas situated mainly in the back arc of the archipelago. Good porosities of the reservoirs are represented by vugular/moldic and intergranular porosity types. The reservoirs are capable of producing prolific amounts of hydrocarbons: production tests in Salawati-Irian Jaya reaches maximum values of 32,000 bpd, and in Arun-North Sumatra tests recorded 200 MMCF gas/day. Significant hydrocarbon accumulations are related to good reservoir rocks in carbonates deposited as patch reefs, pinnacle reefs, and platform complexes. Exploration efforts expand continuously within carbonate formations which are extensive horizontally as well as vertically in the Tertiary stratigraphic column.

Nayoan, G.A.S.; Arpandi; Siregar, M.

1981-01-01T23:59:59.000Z

15

Tertiary Storage: Current Status and Future Trends  

E-Print Network (OSTI)

This report summarizes current state of the art in tertiary storage systems. We begin with a comprehensive discussion of magnetic tape and optical storage technologies. This is followed by a classification of commercial products based on their performance characteristics. Our analysis of product data indicates that in contrast to disk technology, tertiary storage products have significant variablility in terms of data transfer rates as well as other performance figures. We then summarize efforts in the areas of operating systems, databases and advanced applications to integrate tertiary storage. We point out that different assumptions about the underlying technology result in entirely different algorithms and system design. We conclude the report with a speculation of future trends. 1 Introduction With the recent improvements in network and processor speeds, several data intensive applications have become much more feasible than ever before. Examples of such applications include digit...

S. Prabhakar; D. Agrawal; A. El Abbadi; A. Singh; A. El; Abbadi A. Singh

1996-01-01T23:59:59.000Z

16

SUMMARY OF TERTIARY COAL RESOURCES OF THE DENVER BASIN, COLORADO  

E-Print Network (OSTI)

Chapter SD SUMMARY OF TERTIARY COAL RESOURCES OF THE DENVER BASIN, COLORADO By D. J. Nichols in U.S. Geological Survey Professional Paper 1625-A 1999 Resource assessment of selected Tertiary coal beds and zones here or on this symbol in the toolbar to return. 1999 Resource assessment of selected Tertiary coal

17

A SUMMARY OF COAL IN THE COALMONT FORMATION (TERTIARY),  

E-Print Network (OSTI)

Chapter SN A SUMMARY OF COAL IN THE COALMONT FORMATION (TERTIARY), NORTH PARK BASIN, COLORADO By S assessment of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great

18

Room Temperature Aging Study of Butyl O-rings  

Science Conference Proceedings (OSTI)

During testing under the Enhanced Surveillance Campaign in 2001, preliminary data detected a previously unknown and potentially serious concern with recently procured butyl o-rings. All butyl o-rings molded from a proprietary formulation throughout the period circa 1999 through 2001 had less than a full cure. Tests showed that sealing force values for these suspect o-rings were much lower than expected and their physical properties were very sensitive to further post curing at elevated temperatures. Further testing confirmed that these o-rings were approximately 50% cured versus the typical industry standard of > 90% cured. Despite this condition, all suspect o-rings fully conformed to their QC acceptance requirements, including their individual product drawing requirements.

Mark Wilson

2009-08-07T23:59:59.000Z

19

Aqueous flooding methods for tertiary oil recovery  

DOE Patents (OSTI)

A method of aqueous flooding of subterranean oil bearing formation for tertiary oil recovery involves injecting through a well into the formation a low alkaline pH aqueous sodium bicarbonate flooding solution. The flooding solution's pH ranges from about 8.25 to 9.25 and comprises from 0.25 to 5 weight percent and preferably about 0.75 to 3.0 weight percent of sodium bicarbonate and includes a petroleum recovery surfactant of 0.05 to 1.0 weight percent and between 1 and 20 weight percent of sodium chloride. After flooding, an oil and water mixture is withdrawn from the well and the oil is separated from the oil and water mixture.

Peru, Deborah A. (Bartlesville, OK)

1989-01-01T23:59:59.000Z

20

A Brief Survey Of Tertiary Storage Systems And Research  

E-Print Network (OSTI)

This report summarizes current state of the art in tertiary storage systems. We also summarize the current technologies and research efforts to integrate tertiary storage in operating systems, databases and advanced applications. Appeared in ACM Symposium on Applied Computing, ACM SAC, San Jose Feb.-Mar. 1997 1 Introduction With the recent improvements in network and processor speeds, several data intensive applications have become much more feasible than ever before. These applications are characterized by very large computational and storage requirements. In the present commercial setting and most likely in the near future, the only practical solution for storing such enormous amounts of data is Work partially supported by a research grant from NSF/ARPA/NASA IRI9411330, and from NSF CDA9421978 and by a research gift from NEC Japan. tertiary storage. Although tertiary storage, in particular magnetic tapes, has been used solely for archiving or backup purposes, the exploding stora...

S. Prabhakar; D. Agrawal; A. El Abbadi; A. Singh; A. El; Abbadi A. Singh

1997-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

North Burbank Unit Tertiary Recovery Pilot Test. Final report  

Science Conference Proceedings (OSTI)

During the last fifteen months of the project, fresh water injection was continued, while efforts were made to raise injection rates. Chemical analyses of fluids showed that production of surfactant components and polyacrylamide declined steadily almost to the vanishing point in all the producers. The oil production rate has declined slowly since reaching its peak level of 286 BPD in April 1978, and appears to be on an exponential decline curve which projects the continuation of tertiary oil production several years into the future. As of August 11, 1979 (expiration date), the total oil production rate was about 195 BPD at a water-oil ratio of about 66. At that time, a total of 153,500 barrels of tertiary oil had been recovered. It is predicted that 283,000 barrels of tertiary oil will be recovered if the pilot is operated to the economic limit of the wells. This will require an additional 9 years at present rates of injection.

Trantham, J.C. (ed.)

1980-06-01T23:59:59.000Z

22

Effects of simulant mixed waste on EPDM and butyl rubber  

Science Conference Proceedings (OSTI)

The authors have developed a Chemical Compatibility Testing Program for the evaluation of plastic packaging components which may be used in transporting mixed waste forms. In this program, they have screened 10 plastic materials in four liquid mixed waste simulants. These plastics were butadiene-acrylonitrile copolymer (Nitrile) rubber, cross-linked polyethylene, epichlorohydrin rubber, ethylene-propylene (EPDM) rubber, fluorocarbons (Viton and Kel-F{trademark}), polytetrafluoro-ethylene (Teflon), high-density polyethylene, isobutylene-isoprene copolymer (Butyl) rubber, polypropylene, and styrene-butadiene (SBR) rubber. The selected simulant mixed wastes were (1) an aqueous alkaline mixture of sodium nitrate and sodium nitrite; (2) a chlorinated hydrocarbon mixture; (3) a simulant liquid scintillation fluid; and (4) a mixture of ketones. The screening testing protocol involved exposing the respective materials to approximately 3 kGy of gamma radiation followed by 14-day exposures to the waste simulants at 60 C. The rubber materials or elastomers were tested using Vapor Transport Rate measurements while the liner materials were tested using specific gravity as a metric. The authors have developed a chemical compatibility program for the evaluation of plastic packaging components which may be incorporated in packaging for transporting mixed waste forms. From the data analyses performed to date, they have identified the thermoplastic, polychlorotrifluoroethylene, as having the greatest chemical compatibility after having been exposed to gamma radiation followed by exposure to the Hanford Tank simulant mixed waste. The most striking observation from this study was the poor performance of polytetrafluoroethylene under these conditions. In the evaluation of the two elastomeric materials they have concluded that while both materials exhibit remarkable resistance to these environmental conditions, EPDM has a greater resistance to this corrosive simulant mixed waste.

Nigrey, P.J.; Dickens, T.G.

1997-11-01T23:59:59.000Z

23

A SUMMARY OF COAL IN THE FORT UNION FORMATION (TERTIARY), BIGHORN BASIN,  

E-Print Network (OSTI)

Chapter SB A SUMMARY OF COAL IN THE FORT UNION FORMATION (TERTIARY), BIGHORN BASIN, WYOMING assessment of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U...........................................................................................................................SB-1 Coal Production History

24

A SUMMARY OF TERTIARY COAL RESOURCES OF THE WIND RIVER BASIN, WYOMING  

E-Print Network (OSTI)

Chapter SW A SUMMARY OF TERTIARY COAL RESOURCES OF THE WIND RIVER BASIN, WYOMING By R.M. Flores of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great

25

A SUMMARY OF TERTIARY COAL RESOURCES OF THE RATON BASIN, COLORADO AND NEW MEXICO  

E-Print Network (OSTI)

Chapter SR A SUMMARY OF TERTIARY COAL RESOURCES OF THE RATON BASIN, COLORADO AND NEW MEXICO By R of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great

26

The effect of confinement in metabolism stalls on the cortisol, antibody production, and antibody-dependent cell-mediated cytotoxicity of tame lambs  

E-Print Network (OSTI)

Thirty 10-wk-old, Rambouillet wethers were used to evaluate the effect of confinement in metabolism stalls on cortisol and specific and non-specific immune function. All lambs were habituated to human contact and maintained in an outside lot for one month prior to data collection. After taming, the lambs were blocked by temperament score and weight and assigned to either experiment I (EXP I, n = 18) or to experiment II (EXP II,, n = 12). In EXP I, 6 lambs were placed in metabolism stalls on d -7 ("stalled -7"), and 6 lambs were placed in either metabolism stalls ("stalled") or a group pen ("penned") on d 0. All of the lambs were given .5 ml subcutaneous (SC) and .5 ml intramuscular (IM) injections of chicken red blood cells (CRBC) in incomplete adjuvant on d 0. Blood samples were collected via jugular venipuncture at 2 d intervals (d 0 to d 12). Plasma cortisol concentrations and antibody (Ab) production in response to CRBC were determined for all sampling times. There was a significant treatment by day interaction (P .3) except for "penned" being higher on d 4 (P .7). In EXP II, 6 lambs were placed in either metabolism stalls or in a group pen ("stalled" or "penned") on d 0. Plasma cortisol concentrations were determined at 2 d intervals (d 0 to d 12) while mononuclear effector cell activity was determined by antibody-dependent cell-mediated cytotoxicity (ADCC) assays at 0, 4, 8, and 12 d. Cortisol concentrations and mononuclear cell efficiency were influenced by days on treatment (P .4 and P > .8, respectively). The mononuclear effector cell activity of both "penned" and "stalled" animals increased significantly and reached a peak on d 8,, then declined on d 12. Confinement of 10-wk-old lambs in metabolism stalls had a highly variable effect on the pituitary-adrenal and immune system, perhaps reflecting differences in how individual sheep perceived and coped with the treatments.

Hsieh, Man-Ling

1993-01-01T23:59:59.000Z

27

Tertiary Containment in a Multi-Room Tritium Facility  

SciTech Connect

An experimental system to provide tertiary containment at Mound has been upgraded to support a new multi-room tritium handling facility. This system is used to remove tritium from room air in the event of primary (process) and secondary (glovebox) containment failure. The upgraded system includes a faster response time, piping and valves that are more leaktight, and a new control panel that better indicates the system status and operating conditions.

Kent, L. R.

1985-04-01T23:59:59.000Z

28

Scheduling Tertiary I/O in Database Applications  

E-Print Network (OSTI)

We study the problem of scheduling I/O requests for tertiary storage libraries to improve performance. The focus is on scheduling policies that process all requests on a loaded medium before unloading it. For single drive settings an efficient algorithm that produces optimal schedules is developed. For multiple drives the problem is shown to be NP-Complete. Efficient and effective heuristics are presented for the multiple drives case. The scheduling policies developed achieve significant performance gains over more naive first come first server policies. The study is general enough to be applicable to any storage library handling removable media, such as tapes or optical disks.

Sunil Prabhakar; Divyakant Agrawal; Amr El Abbadi; Ambuj Singh

1997-01-01T23:59:59.000Z

29

Use of a Balloon and N-Butyl-2-Cyanoacrylate for Treatment of Arteriovenous Fistula  

Science Conference Proceedings (OSTI)

We report a patient who developed a large arteriovenous fistula in right lower extremity after gunshot injury. Because other endovascular methods failed, the patient was successfully treated with concomitant use of detachable latex balloon and N-butyl-2-cyanoacrylate (NBCA). The combination of detachable balloon and NBCA can be effectively used for endovascular treatment of peripheral arteriovenous fistulas in selected cases when effective embolization could not be achieved with other embolizing agents or their various combinations.

Doenmez, Halil, E-mail: hdonmez68@yahoo.com; Mavili, Ertugrul [Erciyes University Medical Faculty, Department of Radiology (Turkey); Toker, Birguel; Oztuerk, M. Halil; Soylu, Serra O.; Hekimoglu, Baki [SB Diskapi Yildirim Beyazit Egitim ve Arastirma Hastanesi, Department of Radiology (Turkey)

2008-07-15T23:59:59.000Z

30

Comprehensive testing to measure the response of butyl rubber to Hanford tank waste simulant  

Science Conference Proceedings (OSTI)

This report presents the findings of the Chemical Compatibility Program developed to evaluate plastic packaging components that may be incorporated in packaging mixed-waste forms for transportation. Consistent with the methodology outlined in this report, the authors performed the second phase of this experimental program to determine the effects of simulant Hanford tank mixed wastes on packaging seal materials. That effort involved the comprehensive testing of five plastic liner materials in an aqueous mixed-waste simulant. The testing protocol involved exposing the materials to {approximately}143, 286, 571, and 3,670 krad of gamma radiation and was followed by 7-, 14-, 28-, 180-day exposures to the waste simulant at 18, 50, and 60 C. Butyl rubber samples subjected to the same protocol were then evaluated by measuring seven material properties: specific gravity, dimensional changes, mass changes, hardness, compression set, vapor transport rates, and tensile properties. From the analyses, they determined that butyl rubber has relatively good resistance to radiation, this simulant, and a combination of these factors. These results suggest that butyl rubber is a relatively good seal material to withstand aqueous mixed wastes having similar composition to the one used in this study.

NIGREY,PAUL J.

2000-05-01T23:59:59.000Z

31

Data race: tame the beast  

Science Conference Proceedings (OSTI)

Data races hamper parallel programming and threaten the reliability of future software. This paper proposes the data race prevention scheme View-Oriented Data race Prevention (VODAP), which can prevent data races in the View-Oriented Parallel Programming ... Keywords: Cilk, Concurrent programming, Data race free, Data-centric programming, Multicore, SPMD, Shared-memory, VOPP, View oriented parallel programming

K. Leung; Z. Huang; Q. Huang; P. Werstein

2010-03-01T23:59:59.000Z

32

West Hackberry Tertiary Project. Annual report, September 3, 1997--September 2, 1998  

SciTech Connect

The following report is the Project Management Plan for the fifth year of the West Hackberry Tertiary Project. The West Hackberry Tertiary Project is one of four mid-term projects selected by the United States Department of Energy (DOE) as part of the DOE`s Class 1 Program for the development of advance recovery technologies in fluvial dominated deltaic reservoirs. The West Hackberry Tertiary Project is a field test of the idea that air injection can be combined with the Double Displacement Process to produce a low cost tertiary recovery process which is economic at current oil prices. The Double Displacement Process is the gas displacement of a water invaded oil column for the purpose of recovering tertiary oil by gravity drainage. The Double Displacement Process is based upon the concept that in fields such as West Hackberry waterdrive recoveries are typically 50%-60% of the original oil in place while gravity drainage recoveries average 80%-90% of the original oil in place. Therefore, by injecting a gas into a watered out reservoir, a gas cap will form an additional oil can be recovered due to gravity drainage. Although the Double Displacement Process has been shown to be successful in recovering tertiary oil in other fields, this project will be the first to utilize air injection in the Double Displacement Process. The use of air injection in this process combines the benefits of air`s low cost and universal accessibility with the potential for accelerated oil recovery due to the combustion process. If successful, this project will demonstrate that the use of air injection in the Double Displacement Process will result in an economically viable tertiary process in reservoirs where tertiary oil recovery is presently uneconomical.

Gillham, T.H.

1997-09-10T23:59:59.000Z

33

Hydrogen Oxidation Catalysis by a Nickel Diphosphine Complex with Pendant tert-Butyl Amines  

DOE Green Energy (OSTI)

A bis-diphosphine nickel complex with t-butyl functionalized pendant amines [Ni(PCy2Nt-Bu2)2]2+ has been synthesized. It is a highly active electrocatalyst for the oxidation of hydrogen in the presence of base. The turn-over rate of 50 s 1 under 1.0 atm H2 at a potential of –0.77 V vs the ferrocene couple is 5 times faster than the rate reported heretofore for any other molecular H2 oxidation catalyst. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy. Computational resources were provided by the Environmental Molecular Science Laboratory (EMSL) and the National Energy Research Scientific Computing Center (NERSC) at Lawrence Berkeley National Laboratory.

Yang, Jenny Y.; Chen, Shentan; Dougherty, William G.; Kassel, W. S.; Bullock, R. Morris; DuBois, Daniel L.; Raugei, Simone; Rousseau, Roger J.; Dupuis, Michel; Rakowski DuBois, Mary

2010-11-09T23:59:59.000Z

34

Method for photochemical reduction of uranyl nitrate by tri-N-butyl phosphate and application of this method to nuclear fuel reprocessing  

DOE Patents (OSTI)

Uranyl ion in solution in tri-n-butyl phosphate is readily photochemically reduced to U(IV). The product U(IV) may effectively be used in the Purex process for treating spent nuclear fuels to reduce Pu(IV) to Pu(III). The Pu(III) is readily separated from uranium in solution in the tri-n-butyl phosphate by an aqueous strip.

De Poorter, Gerald L. (Los Alamos, NM); Rofer-De Poorter, Cheryl K. (Los Alamos, NM)

1978-01-01T23:59:59.000Z

35

Molecular Dynamics Simulation of Tri-n-Butyl-Phophate Liquid: A Force Field Comparative Study  

SciTech Connect

Molecular dynamics (MD) simulations were conducted to compare the performance of four force fields in predicting thermophysical properties of tri-n-butyl-phosphate (TBP) in the liquid phase. The intramolecular force parameters used were from the Assisted Model Building with Energy Refinement (AMBER) force field model. The van der Waals parameters were based on either the AMBER or the Optimized Potential for Liquid Simulation (OPLS) force fields. The atomic partial charges were either assigned by performing quantum chemistry calculations or utilized previously published data, and were scaled to approximate the average experimental value of the electric dipole moment. Canonical ensemble computations based on the aforementioned parameters were performed near the atmospheric pressure and temperature to obtain the electric dipole moment, mass density, and self-diffusion coefficient. In addition, the microscopic structure of the liquid was characterized via pair correlation functions between selected atoms. It has been demonstrated that the electric dipole moment can be approximated within 1% of the average experimental value by virtue of scaled atomic partial charges. The liquid mass density can be predicted within 0.5-1% of its experimentally determined value when using the corresponding charge scaling. However, in all cases the predicted self- diffusion coefficient is significantly smaller than a commonly quoted experimental measurement; this result is qualified by the fact that the uncertainty of the experimental value was not available.

Cui, Shengting [ORNL; de Almeida, Valmor F [ORNL; Hay, Benjamin [ORNL; Ye, Xianggui [ORNL; Khomami, Bamin [ORNL

2012-01-01T23:59:59.000Z

36

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction  

Science Conference Proceedings (OSTI)

During a review of the H-Canyon authorization basis, Defense Nuclear Facility Safety Board (DNFSB) staff members questioned the margin of safety associated with a postulated tri-n-butyl phosphate (TBP)/nitric acid runaway reaction due to the inadvertent heating of a canyon tank containing greater than 3000 lbs (1362 kg) of TBP. The margin of safety was partially based on experiments and calculations performed by the Actinide Technology Section (ATS) to support deletion of indication of tank agitation as a Safety Class System. In the technical basis for deletion of this system, ATS personnel conservatively calculated the equilibrium temperature distribution of a canyon tank containing TBP and nitric acid layers which were inadvertently heated by a steam jet left on following a transfer. The maximum calculated temperature (128 degrees C) was compared to the minimum initiation temperature for a runaway reaction (greater than 130 degrees C) documented by experimental work in the mid 195 0s. In this work, the initiation temperature as a function of nitric acid concentration was measured for 0 and 20 wt percent dissolved solids. The DNFSB staff members were concerned that data for 0 wt percent dissolved solids were not conservative given the facts that data for 20 wt percent dissolved solids show initiation temperatures at or below 130 degrees C and H-Canyon solutions normally contained a small amount of dissolved solids.

Rudisill, T.S.

2000-11-28T23:59:59.000Z

37

Monitoring Electricity Consumption in the Tertiary Sector- A Project within the Intelligent Energy Europe Program  

E-Print Network (OSTI)

The electricity consumption in the tertiary sector in the EU is still increasing and a further increase is expected of more than 2 % per year during the next 15 years. This sector includes companies and institutions of public and private services with heterogeneous economic and energy-related characteristics. Building managers and decision-makers are not enough informed about the electricity consumption structure and electricity-saving potentials. Within the EU Intelligent Energy project EL-TERTIARY an overview of existing studies showed that the availability of disaggregated data on electricity consumption and its use by purpose (lighting, office equipment, ventilation, air conditioning, etc.) is poor. The methods of determining the types of end-uses are weak; most studies are based on calculations and estimations, only a few on measurement. In addition, many of the results are not published. EL-TERTIARY developed an internet-based methodology for monitoring electricity consumption. It was applied in more than 120 case studies in 12 EU countries. They cover various types of buildings: offices, schools, universities, kindergartens, hotels, supermarkets, and hospitals evaluating more than 900 technical systems. On the background of ongoing activities on EU level, such as directives, research and implementation projects the paper illustrates the concept of EL-TERTIARY, the newly developed methodology for the documentation of building audits and monitoring as well as selected results.

Plesser, S.; Fisch, M. N.; Gruber, E.; Schlomann, B.

2008-10-01T23:59:59.000Z

38

Butyl benzyl phthalate suppresses the ATP-induced cell proliferation in human osteosarcoma HOS cells  

Science Conference Proceedings (OSTI)

Butyl benzyl phthalate (BBP), an endocrine disruptor present in the environment, exerts its genomic effects via intracellular steroid receptors and elicits non-genomic effects by interfering with membrane ion-channel receptors. We previously found that BBP blocks the calcium signaling coupled with P2X receptors in PC12 cells (Liu and Chen, 2006). Osteoblast P2X receptors were recently reported to play a role in cell proliferation and bone remodeling. In this present study, the effects of BBP on ATP-induced responses were investigated in human osteosarcoma HOS cells. These receptors mRNA had been detected, named P2X4, P2X7, P2Y2, P2Y4, P2Y5, P2Y9, and P2Y11, in human osteosarcoma HOS cells by RT-PCR. The enhancement of cell proliferation and the decrease of cytoviability had both been shown to be coupled to stimulation via different concentrations of ATP. BBP suppressed the ATP-induced calcium influx (mainly coupled with P2X) and cell proliferation but not the ATP-induced intracellular calcium release (mainly coupled with P2Y) and cytotoxicity in human osteosarcoma HOS cells. Suramin, a common P2 receptor's antagonist, blocked the ATP-induced calcium signaling, cell proliferation, and cytotoxicity. We suggest that P2X is mainly responsible for cell proliferation, and P2Y might be partially responsible for the observed cytotoxicity. BBP suppressed the calcium signaling coupled with P2X, suppressing cell proliferation. Since the importance of P2X receptors during bone metastasis has recently become apparent, the possible toxic risk of environmental BBP during bone remodeling is a public problem of concern.

Liu, P.-S., E-mail: pslediting@mail.scu.edu.t [Department of Microbiology, Soochow University, Shihlin, Taipei, Taiwan (China); Chen, C.-Y. [Department of Microbiology, Soochow University, Shihlin, Taipei, Taiwan (China)

2010-05-01T23:59:59.000Z

39

Field pilot tests for tertiary recovery using butane and propane injection  

SciTech Connect

This work describes a pilot project for tertiary recovery of liquid hydrocarbons through LPG injection in water-out sections of the Bolivar reservoir in La Pena Field, Santa Cruz, Boliva. The promising results obtained in the initial field miscibility tests, as well as the results from a mathematical model built to stimulate and evaluate the tertiary recovery project, directed subsequent work into a cyclic scheme for enhanced recovery. This scheme is explained and injection production data is presented. Field facilities built to handle both the injected LPG and the produced oil-LPG mixture are described. The oil/LPG ratio and the LPG recovered/injected fraction are the main factors measured in this to make further considerations for a full scale project.

Pacheco, E.F.; Garcia, A.I.

1981-01-01T23:59:59.000Z

40

Tertiary application of a hydrocarbon miscible flood; Rainbow Keg River B Pool  

SciTech Connect

The Rainbow Keg River B pool EOR scheme calls for placement of a 12% (net after recycle)-original-HCPV miscible bank in the crestal region of the pool. This bank will be chased vertically downward with more than 1 PV of dry gas. The injected solvent and chase gas will push the oil/water contact (OWC) downward as the previously injected water is produced. A tertiary oil bank will be formed in the region previously occupied by the water. This paper reports tertiary flood performance, results of the 1987 reservoir simulation study, and the operational strategy and problems encountered in monitoring the flood. The well-completion technique implemented to operate the flood is described, and the scheme economics is reviewed.

Nagel, R.G.; Hunter, B.E.; Peggs, J.K.; Fong, D.K. (Husky Oil Operations Ltd., Calgary (CA)); Mazzocchi, E. (EBCO Auctioneers International Inc. (CA))

1990-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

PROPERTIES OF THE CLOSE-IN TERTIARY IN THE QUADRUPLE SYSTEM V401 CYG  

SciTech Connect

V401 Cyg is a quadruple system in which the spectroscopic signature of a close-in tertiary and a distant visual companion star were reported. Orbital properties of the close-in companion should provide valuable information on the formation of close binaries and stellar dynamical interaction. By analyzing new times of minimum light together with those collected from the literature, we discovered that the observed-calculated (O - C) curve of V401 Cyg shows a cyclic change with a short period of 3.5 yr and a semi-amplitude of 0.00436 days while it undergoes an upward parabolic variation. Those photoelectric and CCD data covered more than two cycles and were analyzed for the light-travel time effect via the presence of the tertiary companion. The mass of the third body was determined to be M{sub 3}sin i' = 0.65({+-} 0.08) M{sub Sun }, which is close to the value estimated from the spectroscopic data (M{sub 3} {approx} 0.64 M{sub Sun }). This reveals that the orbital inclination of the tertiary was about i' {approx} 90 Degree-Sign , indicating that the contact components of V401 Cyg have the possibility of being eclipsed by the tertiary at an orbital distance of about 3.0 AU, and it may be a triply eclipsing hierarchical triple system. The upward parabolic change indicates a period increase at a rate of (P-dot{sub 2} = 1.5 x 10{sup -7} revealing a mass transfer from the secondary to the primary (M-dot{sub 2} = 5.9 x 10{sup -8} M{sub Sun} yr{sup -1}). This is consistent with the predictions of the theory of thermal relaxation oscillation (TRO) suggesting that V401 Cyg is undergoing an expanding-orbit stage in the TRO cycles.

Zhu, L.-Y.; Qian, S.-B.; Zhou, X.; Li, L.-J.; Zhao, E.-G.; Liu, L.; Liu, N.-P., E-mail: qsb@ynao.ac.cn [Yunnan Observatories, Chinese Academy of Sciences (CAS), P.O. Box 110, 650011 Kunming (China)

2013-08-01T23:59:59.000Z

42

OECD THEMATIC REVIEW OF TERTIARY EDUCATION COUNTRY BACKGROUND REPORT FOR SWEDEN Swedish National Agency for Higher Education  

E-Print Network (OSTI)

Government as an input to the OECD Thematic Review of Tertiary Education. The document was prepared in response to guidelines the OECD provided to all participating countries. The guidelines encouraged the author(s) to canvass a breadth of views and priorities on tertiary education issues. The opinions expressed are not necessarily those of the Swedish Government, the OECD or its Member countries. Sweden has granted the

unknown authors

2006-01-01T23:59:59.000Z

43

Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-  

E-Print Network (OSTI)

Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

44

RNA tertiary interactions in the large ribosomal subunit: The A-minor motif  

DOE Green Energy (OSTI)

Analysis of the 2.4-{angstrom} resolution crystal structure of the large ribosomal subunit from Haloarcula marismortui reveals the existence of an abundant and ubiquitous structural motif that stabilizes RNA tertiary and quaternary structures. This motif is termed the A-minor motif, because it involves the insertion of the smooth, minor groove edges of adenines into the minor groove of neighboring helices, preferentially at C-G base pairs, where they form hydrogen bonds with one or both of the 2' OHs of those pairs. A-minor motifs stabilize contacts between RNA helices, interactions between loops and helices, and the conformations of junctions and tight turns. The interactions between the 3' terminal adenine of tRNAs bound in either the A site or the P site with 23S rRNA are examples of functionally significant A-minor interactions. The A-minor motif is by far the most abundant tertiary structure interaction in the large ribosomal subunit; 186 adenines in 23S and 5S rRNA participate, 68 of which are conserved. It may prove to be the universally most important long-range interaction in large RNA structures.

Nissen, Poul; Ippolito, Joseph A.; Ban, Nenad; Moore, Peter B.; Steitz, Thomas A. (Yale University); (Yale University); (Yale Unversity)

2009-10-07T23:59:59.000Z

45

A distributed approach to taming peak demand  

Science Conference Proceedings (OSTI)

A significant portion of all energy capacity is wasted in over-provisioning to meet peak demand. The current state-of-the-art in reducing peak demand requires central authorities to limit device usage directly, and are generally reactive. We apply techniques ...

Michael Sabolish; Ahmed Amer; Thomas M. Kroeger

2012-06-01T23:59:59.000Z

46

The taming of Leviathan: Competition among governments  

Science Conference Proceedings (OSTI)

the government as club management acts as an entrepreneur attempting to attract .... Tiebout's (1956) model of residential choice among local communities.

47

Energy flux limitation by tame turbulence  

SciTech Connect

A quasi-linear theory of energy flux limitation by ion acoustic turbulence is presented. This distribution function is modelled by a Maxwellian plus an additional piece which carries a heat flux Q. By taking the fourth moment of the Vlasov equation one finds the anomalous thermal conductivity K approximately 3 v/sub e/ delta/sub De/ (e phi/T/sub e/)$sup -2$. Other moments treated self-consistently include anomalous ion heating, electron cooling, current generation and enhanced inverse bremsstrahlung due to the nonthermal ion fluctuations. (auth)

Manheimer, W.M.

1975-11-01T23:59:59.000Z

48

Determination of Methyl tert-Butyl Ether and tert-Butyl Alcohol in Water by Solid-Phase Microextraction/Head Space Analysis in Comparison to EPA Method 5030/8260B  

DOE Green Energy (OSTI)

Methyl tert-butyl ether (MTBE) is now one of the most common groundwater contaminants in the United States. Groundwater contaminated with MTBE is also likely to be contaminated with tert-butyl alcohol (TBA), because TBA is a component of commercial grade MTBE, TBA can also be used as a fuel oxygenate, and TBA is a biodegradation product of MTBE. In California, MTBE is subject to reporting at concentrations greater than 3 {micro}g/L. TBA is classified as a ''contaminant of current interest'' and has a drinking water action level of 12 {micro}g/L. In this paper, we describe the development and optimization of a simple, automated solid phase microextraction (SPME) method for the analysis of MTBE and TBA in water and demonstrate the applicability of this method for monitoring MTBE and TBA contamination in groundwater, drinking water, and surface water. In this method, the headspace (HS) of a water sample is extracted with a carboxen/polydimethylsiloxane SPME fiber, the MTBE and TBA are desorbed into a gas chromatograph (GC), and detected using mass spectrometry (MS). The method is optimized for the routine analysis of MTBE and TBA with a level of quantitation of 0.3 {micro}g/L and 4 {micro}g/L, respectively, in water. MTBE quantitation was linear for over two orders of concentration (0.3 {micro}g/L -80 {micro}g/L). TBA was found to be linear within the range of 4 {micro}g/L-7,900 {micro}g/L. The lower level of detection for MTBE is 0.03 {micro}g/L using this method. This SPME method using headspace extraction was found to be advantageous over SPME methods requiring immersion of the fiber into the water samples, because it prolonged the life of the fiber by up to 400 sample analyses. This is the first time headspace extraction SPME has been shown to be applicable to the measurement of both MTBE and TBA at concentrations below regulatory action levels. This method was compared with the certified EPA Method 5030/8260B (purge-and-trap/GC/MS) using split samples from laboratory bioreactors treating MTBE contaminated water and applied to environmental samples collected throughout the East Bay area of California. Results from the SPME-HS/GC/MS method were directly comparable to the EPA Method 5030/8260B. This method provides an simple, inexpensive, accurate, and sensitive alternative to EPA Method 5030/8260B for the analysis of MTBE and TBA in water samples.

Oh, Keun-Chan; Stringfellow, William T.

2003-10-02T23:59:59.000Z

49

Concentrating aqueous volatile fatty acid salt solutions using a tertiary amine mixture  

E-Print Network (OSTI)

Lee (1993) has shown that tertiary amines are able to hics. extract water from low-concentration calcium acetate and sodium acetate solutions. This thesis extends the previous work to include calcium propionate and butyrate. Amine extraction may be used to selectively remove water from a fermentation broth thus concentrating calcium acetate, propionate, and butyrate. Compared to competing technologies that extract undissociated acids from a volatile fatty acid fermentation broth, extracting water with tertiary amines allows for higher pH levels in the broth resulting in greater productivity. Specifically, triethylamine and N,N-diethyl-methylamine in a 1:2 volumetric mixture are superior to any other examined mixture or single amine for extracting water at 40[]C, the proposed fermentation temperature (Lee, 1993; Davison et al., 1966, 1967). Once the acid salts have been concentrated, a variety of techniques are available to convert the concentrated salts into other products such as ketones, alcohols, and acids. At low temperatures, the low-molecular-weight amine mixture has a high affinity for water. By raising the temperature 20 to 25[]C, the water separates from the amine allowing for convenient solvent regeneration of the amine. The distribution coefficients, [] , measure the selectivity of concentrating calcium salts in the aqueous phase. The distribution coefficients generally vary as follows: [] thus, there is less selectivity as the aliphatic group increases in size. The amine mixture was used to extract water from actual fermentation broth to determine whether possible surfactants in the broth interfere with the extraction. Prior to extraction, the fermentation broth was adjusted to pH 11.5 by adding a small amount of lime. The high pH precipitate protein which can be recycled to the fermentor or collected for animal feed. Through 15 extraction runs, no degradation of the amine was observed.

Gaskin, David J

1997-01-01T23:59:59.000Z

50

Understanding the redox shuttle stability of 3,5-di-tert-butyl-1,2-dimethoxybenzene for overcharge protection of lithium-ion batteries.  

DOE Green Energy (OSTI)

3,5-di-tert-butyl-1,2-dimethoxybenzene (DBDB) has been synthesized as a new redox shuttle additive for overcharge protection of lithium-ion batteries. DBDB can easily dissolve in carbonate-based electrolytes, which facilitates its practical use in lithium-ion batteries; however, it has poor electrochemical stability compared to 2,5-di-tert-butyl-1,4-dimethoxybenzene (DDB). The structures of DBDB and DDB were investigated using X-ray crystallography and density functional calculations. The structures differ in the conformations of the alkoxy bonds probably due to the formation of an intramolecular hydrogen bond in the case of DBDB. We investigated reaction energies for decomposition pathways of neutral DBDB and DDB and their radical cations and found little difference in the reaction energies, although it is clear that kinetically, decomposition of DBDB is more favorable.

Zhang, Z.; Zhang, L.; Schlueter, J. A.; Redfern, P. C.; Curtiss, L.; Amine, K.

2010-01-01T23:59:59.000Z

51

Identification of volatile butyl rubber thermal-oxidative degradation products by cryofocusing gas chromatography/mass spectrometry (cryo-GC/MS).  

Science Conference Proceedings (OSTI)

Chemical structure and physical properties of materials, such as polymers, can be altered as aging progresses, which may result in a material that is ineffective for its envisioned intent. Butyl rubber formulations, starting material, and additives were aged under thermal-oxidative conditions for up to 413 total days at up to 124 %C2%B0C. Samples included: two formulations developed at Kansas City Plant (KCP) (%236 and %2310), one commercially available formulation (%2321), Laxness bromobutyl 2030 starting material, and two additives (polyethylene AC-617 and Vanax MBM). The low-molecular weight volatile thermal-oxidative degradation products that collected in the headspace over the samples were preconcentrated, separated, and detected using cryofocusing gas chromatography mass spectrometry (cryo-GC/MS). The majority of identified degradation species were alkanes, alkenes, alcohols, ketones, and aldehydes. Observations for Butyl %2310 aged in an oxygen-18 enriched atmosphere (18O2) were used to verify when the source of oxygen in the applicable degradation products was from the gaseous environment rather than the polymeric mixture. For comparison purposes, Butyl %2310 was also aged under non-oxidative thermal conditions using an argon atmosphere.

Smith, Jonell Nicole; White, Michael Irvin; Bernstein, Robert; Hochrein, James Michael

2013-02-01T23:59:59.000Z

52

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. [801Methyl tert-butyl ether  

DOE Green Energy (OSTI)

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: (1) Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. (2) Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. (3) Addition of methanol to slurry phase FT synthesis making iso-olefins. During the sixth quarter we completed the construction of the slurry bubble column reactor (SBCR), conducted initial shake-down experiments in a cold-flow mode, and finalized the selection process of the acid catalysts for conversion of syngas-produced alcohols and isobutylene to MTBE (scheme 2). Tasks 3, 4, and 5 are awaiting complete implementation of the SBCR system.

Marcelin, G.

1992-06-24T23:59:59.000Z

53

North and west central Texas. Mitchell EOR (enhanced oil recovery) projects yield tertiary oil in Wise and Jack counties  

SciTech Connect

An enhanced oil recovery project utilizing a miscible LPG process provides Mitchell Energy and Development Corp. engineers with a springboard for other miscible flood projects while yielding incremental tertiary oil that otherwise would remain in the ground. The LPG flood project is in the Alvord (3,000-ft Strawn) Unit in Wise County, Texas. The field had been waterflooded for 14 yr, and was producing near its economic limit under waterflood, the alternative to starting a tertiary project would have been to abandon the field. The LPG flood process was chosen because liquefied petroleum gases are miscible with oil at the low pressures that must be maintained in shallow reservoirs such as the Alvord Strawn. Propane was determined to be the suitable LPG for the project because of its availability and ease of handling.

Mickey, V.

1982-09-01T23:59:59.000Z

54

Factors controlling reservoir quality in tertiary sandstones and their significance to geopressured geothermal production  

DOE Green Energy (OSTI)

Variable intensity of diagenesis is the factor primarily responsible for contrasting regional reservoir quality of Tertiary sandstones from the upper and lower Texas coast. Detailed comparison of Frio sandstone from the Chocolate Bayou/Danbury Dome area, Brazoria County, and Vicksburg sandstones from the McAllen Ranch Field area, Hidalgo County, reveals that extent of diagenetic modification is most strongly influenced by (1) detrital mineralogy and (2) regional geothermal gradients. The regional reservoir quality of Frio sandstones from Brazoria County is far better than that characterizing Vicksburg sandstones from Hidalgo County, especially at depths suitable for geopressured geothermal energy production. However, in predicting reservoir quality on a site-specific basis, locally variable factors such as relative proportions for porosity types, pore geometry as related to permeability, and local depositional environment must also be considered. Even in an area of regionally favorable reservoir quality, such local factors can significantly affect reservoir quality and, hence, the geothermal production potential of a specific sandstone unit.

Loucks, R.G.; Richmann, D.L.; Milliken, K.L.

1981-01-01T23:59:59.000Z

55

Geometry and reservoir heterogeneity of tertiary sandstones: a guide to reservoir continuity and geothermal resource development  

DOE Green Energy (OSTI)

External and internal continuity of Tertiary sandstones are controlled by various factors including structural trends, sand body geometry, and the distribution of mineral framework, matrix, and intersticies within the sand body. Except for the limits imposed by faults, these factors are largely inherited from the depositional environment and modified during sandstone compaction and cementation. Sandstone continuity affects energy exploration and production strategies. The strategies range in scope from regional to site-specific and closely parallel a sandstone hierarchy. The hierarchy includes subdivisions ranking from genetically related aquifer systems down to individual reservoirs within a fault-bounded sandstone. Volumes of individual reservoirs are 50% less to 200% more than estimated from conventional geologic mapping. In general, mapped volumes under-estimate actual volumes where faults are nonsealing and overestimate actual volumes where laterally continuous shale breaks cause reductions in porosity and permeability. Gross variations in these pore properties can be predicted on the basis of internal stratification and sandstone facies. Preliminary analyses indicate that large aquifers are found where barrier and strandplain sandstones parallel regional faults or where fluvial (meandering) channels trend normal to regional faults. Within these sand bodies, porosity and permeability are highest in large-scale crossbedded intervals and lowest in contorted, bioturbated, and small-scale ripple cross-laminated intervals.

Morton, R.A.; Ewing, T.E.

1981-01-01T23:59:59.000Z

56

Use of Treated Municipal Wastewater as Power Plant Cooling System Makeup Water: Tertiary Treatment versus Expanded Chemical Regimen for Recirculating Water Quality Management  

SciTech Connect

Treated municipal wastewater is a common, widely available alternative source of cooling water for thermoelectric power plants across the U.S. However, the biodegradable organic matter, ammonia-nitrogen, carbonate and phosphates in the treated wastewater pose challenges with respect to enhanced biofouling, corrosion, and scaling, respectively. The overall objective of this study was to evaluate the benefits and life cycle costs of implementing tertiary treatment of secondary treated municipal wastewater prior to use in recirculating cooling systems. The study comprised bench- and pilot-scale experimental studies with three different tertiary treated municipal wastewaters, and life cycle costing and environmental analyses of various tertiary treatment schemes. Sustainability factors and metrics for reuse of treated wastewater in power plant cooling systems were also evaluated. The three tertiary treated wastewaters studied were: secondary treated municipal wastewater subjected to acid addition for pH control (MWW_pH); secondary treated municipal wastewater subjected to nitrification and sand filtration (MWW_NF); and secondary treated municipal wastewater subjected nitrification, sand filtration, and GAC adsorption (MWW_NFG). Tertiary treatment was determined to be essential to achieve appropriate corrosion, scaling, and biofouling control for use of secondary treated municipal wastewater in power plant cooling systems. The ability to control scaling, in particular, was found to be significantly enhanced with tertiary treated wastewater compared to secondary treated wastewater. MWW_pH treated water (adjustment to pH 7.8) was effective in reducing scale formation, but increased corrosion and the amount of biocide required to achieve appropriate biofouling control. Corrosion could be adequately controlled with tolytriazole addition (4-5 ppm TTA), however, which was the case for all of the tertiary treated waters. For MWW_NF treated water, the removal of ammonia by nitrification helped to reduce the corrosivity and biocide demand. Also, the lower pH and alkalinity resulting from nitrification reduced the scaling to an acceptable level, without the addition of anti-scalant chemicals. Additional GAC adsorption treatment, MWW_NFG, yielded no net benefit. Removal of organic matter resulted in pitting corrosion in copper and cupronickel alloys. Negligible improvement was observed in scaling control and biofouling control. For all of the tertiary treatments, biofouling control was achievable, and most effectively with pre-formed monochloramine (2-3 ppm) in comparison with NaOCl and ClO2. Life cycle cost (LCC) analyses were performed for the tertiary treatment systems studied experimentally and for several other treatment options. A public domain conceptual costing tool (LC3 model) was developed for this purpose. MWW_SF (lime softening and sand filtration) and MWW_NF were the most cost-effective treatment options among the tertiary treatment alternatives considered because of the higher effluent quality with moderate infrastructure costs and the relatively low doses of conditioning chemicals required. Life cycle inventory (LCI) analysis along with integration of external costs of emissions with direct costs was performed to evaluate relative emissions to the environment and external costs associated with construction and operation of tertiary treatment alternatives. Integrated LCI and LCC analysis indicated that three-tiered treatment alternatives such as MWW_NSF and MWW_NFG, with regular chemical addition for treatment and conditioning and/or regeneration, tend to increase the impact costs and in turn the overall costs of tertiary treatment. River water supply and MWW_F alternatives with a single step of tertiary treatment were associated with lower impact costs, but the contribution of impact costs to overall annual costs was higher than all other treatment alternatives. MWW_NF and MWW_SF alternatives exhibited moderate external impact costs with moderate infrastructure and chemical conditioner dosing, which makes them (especially

David Dzombak; Radisav Vidic; Amy Landis

2012-06-30T23:59:59.000Z

57

RESULTS OF A DATING ATTEMPT -CHEMICAL AND PHYSICAL MEASUREMENTS RELEVANT TO THE CASE OF THE CRETACEOUS TERTIARY EXTINCTIONS  

SciTech Connect

In Gubbio, Italy, a l em layer of clay between extensive limestone formations marks the boundary between the Cretaceous and Tertiary Periods. This clay layer was known to have been deposited about 65 million years ago when many life forms became extinct, but the length of time associated with the deposition was not known. In an attempt to measure this time with normally deposited meteoritic material as a clock, extensive measurements of iridium abundances (and those of many other elements) were made on the Gubbio rocks. Neutron activation analysis was the principal tool used in these studies. About 50 elements are searched for in materials like the earth's crust, about 40 are detected and about 30 are measured with useful precision. We were not able to determine exactly how long the clay deposition took. Instead the laboratory studies on the chemical and physical nature of the Cretaceous-Tertiary boundary led to the theory that an asteroid collision with the earth was responsible for the extinction of many forms of life including the dinosaurs.

Asaro, Frank; Michel, Helen V.; Alvarez, Luis W.; Alvarez, Walter

1980-09-01T23:59:59.000Z

58

Investigating Sequestration Potential of Carbonate Rocks during Tertiary Recovery from a Billion Barrel Oil Field, Weyburn, Saskatchewan: the Geoscience Framework (IEA Weyburn CO2 Monitoring Project)  

NLE Websites -- All DOE Office Websites (Extended Search)

Sequestration Potential of Carbonate Rocks during Tertiary Sequestration Potential of Carbonate Rocks during Tertiary Recovery from a Billion Barrel Oil Field, Weyburn, Saskatchewan: the Geoscience Framework (IEA Weyburn CO 2 Monitoring and Storage Project) G. Burrowes (Geoffrey_Burrowes@pancanadian.ca; 403-290-2796) PanCanadian Resources 150 - 9 th Avenue S.W., P.O. Box 2850 Calgary, Alberta, Canada T2P 2S5 C. Gilboy (cgilboy@sem.gov.sk.ca; 306-787-2573) Petroleum Geology Branch, Saskatchewan Energy and Mines 201 Dewdney Avenue East Regina, Saskatchewan, Canada S4N 4G3 Introduction In Western Canada the application of CO 2 injection for enhanced, 'tertiary' oil recovery is a relatively recent addition to the arsenal available to reservoir engineers. The first successful application of CO 2 as a miscible fluid in Western Canada began in 1984 at Joffre Field, a

59

Origin of gaseous hydrocarbons from Upper Cretaceous and Tertiary strata in the Piceance basin, western Colorado  

E-Print Network (OSTI)

Natural gas samples were collected for geochemical analyses from Upper Cretaceous and Tertiary strata of the Piceance basin in western Colorado to: 1) determine the origin of gases (i.e., microbial versus thermogenic), 2) determine the thermogenic source rock(s) for the gas-rich Williams Fork Formation, and 3) assess the nature of gas migration. Mud logging gases were sampled approximately every 60 m between 350 and 2800 m and analyzed for "C compositions and CI/C,-3 ratios. Samples collected from low gas content intervals above 1950 m define two parallel trends of increasing "Cc, content with depth. Data from the first trend are based on eighteen analyses and range from-69.9 to-38.3%o (R 2 = 0.92). These data suggest a microbial and mixed microbial/thermogenic origin for methane. Only one sample from above 1950 m contained sufficient amounts of C2for isotopic analysis (813 CC2 =-27.0%o at 1718 m). Data from the second trend are based on seven analyses and are offset by approximately +20%o compared with the primary trend at comparable depths. These data range from-65.0 to-38.5%0 (R' = 0.84). 813c ci and C,/CI-3data from both trends are similar when viewed on a crossplot, thus suggesting that large-scale, vertical gas migration has occurred. Migration was probably aided by fractures that formed during maximum burial and peak gas generation. Except for one sample collected at 1718 m, "CC2compositions above 1950 m were not determined due to insufficient sample sizes. Below 1950 m, gas contents abruptly increase and approach 10-4' gas units. These gases have "C compositions indicative of thermogenic origin. Gases between 1950 and 2450 m have relatively uniform geochemistries (8"Cc, =-39.9 0?.3%ol 613C C2 =-27.4 I?.i%ol CI/Cl-3 = 0-91 0?.03), and are chemically distinct and therefore Renetically different from gases between 2450 and 2791 M (513C ci =-37.9 +-O.2%og 813C C2 =-26.4 0?.5%09 CI/Cl-3 = 0.88 0?.01). Gases of the latter group were probably derived from coalbeds that comprise the Cameo Group, as abundant coals are found between 2450 and 2630 m. Only three thin coalbeds occur within the Coal Ridge Group between 1950 and 2450 m, so gases from this interval were probably derived from interbedded shales. Core and cuttings samples were also collected and sealed in cans from several intervals for geochemical analyses. Canned methanes at or above 858 m are "C-enriched by 13 to 33%o compared with logging methanes at equivalent intervals. Below 1934 m, however, 813C ci values for core and cuttings are comparable to logging gas values. This observation suggests that 813 Cc, discrepancies above 858 m are related to low gas contents in the core and cutting samples. Therefore, geochemical data from core and cuttings were not used to assess migration or to interpret gas origin.

Katz, David Jonathan

1997-01-01T23:59:59.000Z

60

Mathematical simulation and X-ray diffraction investigation of the crystal structure of 1-phenyl-1-tert-butyl-3-methyl-1,3-dihydroisobenzofuran  

SciTech Connect

An algorithm for using a priori generation of crystal structures by the discrete modeling method for the interpretation of data obtained from single-crystal X-ray diffraction experiments is considered. The crystal structure of 1-phenyl-1-tert-butyl-3-methyl-1,3-dihydroisobenzofuran is mathematically simulated using the discrete modeling of molecular packings and studied by X-ray diffraction. The simulation is performed for two isomers of the initial chemical compound that are possible from the viewpoint of the mechanism of the chemical reaction used in the synthesis of this compound. Appropriate models that can serve as starting models for solving and refining the crystal structure with the use of X-ray diffraction data are chosen from a complete set of calculated structural models in accordance with specific criteria. The structure is solved using a starting model calculated using the discrete modeling method and refined by the full-matrix least-squares procedure.

Maleev, A. V., E-mail: andr_mal@mail.ru; Zhitkov, I. K.; Potekhin, K. A. [Vladimir State Pedagogical University (Russian Federation)

2008-07-15T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

NETL: Gasifipedia  

NLE Websites -- All DOE Office Websites (Extended Search)

chemical feedstock for production of a range of important industrial chemicals, primarily acetic acid, formaldehyde, methyl methacrylate and methyl tertiary-butyl ether (MTBE)....

62

Impact of Renewable Fuels Standard/MTBE Provisions of S. 517 Requested by Sens. Daschle & Murkowski  

Reports and Publications (EIA)

Additional analysis of the impact of the Renewable Fuels Standard (RFS) and methyl tertiary butyl ether (MTBE) ban provisions of S. 517.

Information Center

2002-04-01T23:59:59.000Z

63

Impact of Renewable Fuels Standard/MTBE Provisions of S.1766  

U.S. Energy Information Administration (EIA)

SR/OIAF/2002-06 Release date: March 2002 This report analyzes the Renewable Fuels Standard (RFS)/methyl tertiary butyl ether (MTBE) provisions of S. 1766.

64

BLAST BIOLOGY--A STUDY OF THE PRIMARY AND TERTIARY EFFECTS OF BLAST IN OPEN UNDERGROUND PROTECTIVE SHELTERS  

SciTech Connect

Dogs, pigs, rabbits, guinea pigs, and mice were exposed to nuclear detonatiors in two open underground pantitioned shelters. The shelters were of similar constructions and each was exposed to separate detonations. Each inner chamber filled through its own orifice; thus four separate pressure enviromments were obtained. An aerodynamic mound was placed over the escape hatch of each structure to determine its effect on the pressurecurve shape inside the chamber. In one test a sieve plate bolted across the top of the mound was evaluated. Wind protective baffles of solid plate and of heavy wire screen were installed in the shelters to compare primary and tertiary blast effects on dogs. The shelters also contained static and dynamic pressure gages, radiation detectors, telemetering devices, and, in one test, air-temperature measuring instruments, dustcollecting trays, and eight pigs for the biological assessment of thermal effects. One dog was severely injured from tertiary blast effects associated with a maximal dynamic pressure (Q) of 10.5 psi, and one was undamaged with a maximal Q of 2 psi. Primary blast effects resulting from peak overpressures of 30.3, 25.5, 9.5. and 4.1 psi were minimal. The mortality was 19 per cent of the mice exposed to a peak pressure of 30.3 psi and 5 and 3 per cent of the guinea pigs and mice exposed to a peak pressure of 25.5 psi. Many of the rabbits, guinea pigs, and mice sustained slight lung hemorrhages at maximum pressures of 25.5 and 30.3 psi. Eardrum perforation data for all species, except mice, were recorded. Following shot 2, thermal effects were noted. Animals of the groups saved for observation have died from ionizing-radiation effects. (auth)

Ricmond, D.R.; Taborelli, R.V.; Bowen, I.G.; Chiffelle, T.L.; Hirsch, F.G.; Longwell, B.B.; Riley, J.G.; White, C.S.; Sherping, F.; Goldizen, V.C.; Ward, J.D.; Wetherbe, M.B.; Clare, V.R.; Kuhn, M.L.; Sanchez, R.T.

1959-02-01T23:59:59.000Z

65

Effect of Gradient Sequencing on Copolymer Order?Disorder Transitions: Phase Behavior of Styrene/n-Butyl Acrylate Block and Gradient Copolymers  

SciTech Connect

We investigate the effect of gradient sequence distribution in copolymers on order-disorder transitions, using rheometry and small-angle X-ray scattering to compare the phase behavior of styrene/n-butyl acrylate (S/nBA) block and gradient copolymers. Relative to block sequencing, gradient sequencing increases the molecular weight necessary to induce phase segregation by over 3-fold, directly consistent with previous predictions from theory. Results also suggest the existence of both upper and lower order-disorder transitions in a higher molecular weight S/nBA gradient copolymer, made accessible by the shift in order-disorder temperatures from gradient sequencing. The combination of transitions is speculated to be inaccessible in S/nBA block copolymer systems due to their overlap at even modest molecular weights and also their location on the phase diagram relative to the polystyrene glass transition temperature. Finally, we discuss the potential impacts of polydispersity and chain-to-chain monomer sequence variation on gradient copolymer phase segregation.

Mok, Michelle M.; Ellison, Christopher J.; Torkelson, John M. (NWU); (UMM)

2012-11-14T23:59:59.000Z

66

Solvent extraction of technetium from alkaline waste media using bis-4,4{prime}(5{prime})[(tert-butyl)cyclohexano]-18-crown-6  

SciTech Connect

The crown ether bis-4,4`(5`)[(tert-butyl)cyclohexano]-18-crown-6 can be utilized in a solvent-extraction process for the removal of technetium as pertechnetate ion, TcO{sub 4}{sup {minus}} from solutions simulating highly radioactive alkaline defense wastes (``tank wastes``) stored at several sites in the United States. The process employs non-halogenated and non-volatile diluents and modifiers and includes an efficient stripping procedure using only water. More than 95% of the pertechnetate present at 6 {times} 10{sup {minus}5} M in Melton Valley (Oak Ridge, TN) and Hanford (Washington) tank-waste simulants was removed following two cross-current extraction contacts using 0.02 M bis-4,4`(5`)[(tertbutyl)cyclohexano]- 18-crown-6 in 2:1 vol/vol TBP/Isopar{reg_sign} M diluent at 25 C. Similarly, for both simulants, more than 98% of the pertechnetate contained in the solvent was back-extracted following two cross-current stripping contacts using deionized water.

Bonnesen, P.V.; Presley, D.J.; Moyer, B.A.

1995-07-01T23:59:59.000Z

67

Liver Hypertrophy After Percutaneous Portal Vein Embolization: Comparison of N-Butyl-2-Cyanocrylate Versus Sodium Acrylate-Vinyl Alcohol Copolymer Particles in a Swine Model  

Science Conference Proceedings (OSTI)

Purpose: Percutaneous portal vein embolization (PPVE) induces hypertrophy of the future liver remnant before hepatic resection. The ideal embolic material has not yet been determined. We compared N-butyl-2-cyanocrylate (NBCA) with sodium acrylate-vinyl alcohol copolymer particles using a swine model. Materials and Methods: Twelve pigs underwent PPVE. Six pigs (group A) were embolized with NBCA, and 6 pigs (group B) were embolized with sodium acrylate-vinyl alcohol copolymer particles. Computed tomographic volumetry of the embolized lobe (EL) and the nonembolized lobe (NEL), along with liver function tests, was performed before and at 14 and 28 days after embolization. Tissue samples from both lobes were taken 14 and 28 days after PPVE. Results: NEL-volume and NEL-ratio increases were significantly higher in group A at 14 and 28 days after PPVE (78 and 52% and 91 and 66%, respectively) than in group B (32 and 12% and 28 and 10%, respectively) (p < 0.05). Percent change of the EL-volume was significantly higher for group A at 28 days after PPVE. No statistically significant difference was found between the groups regarding hepatocyte proliferation on the NEL and apoptosis on the EL at both time intervals. Conclusion: PPVE using NBCA is more efficient and causes more NEL hypertrophy than microspheres.

Tsoumakidou, Georgia, E-mail: gtsoumakidou@yahoo.com [National and Kapodistrian University of Athens, 2nd Department of Radiology, Medical School, General University Hospital Attikon (Greece); Theocharis, Stamatis, E-mail: theocharis@ath.forthnet.gr [National and Kapodistrian University of Athens, Department of Forensic Medicine and Toxicology, Medical School (Greece); Ptohis, Nikolaos, E-mail: nikptohis@yahoo.gr; Alexopoulou, Efthimia, E-mail: ealex64@hotmail.com [National and Kapodistrian University of Athens, 2nd Department of Radiology, Medical School, General University Hospital Attikon (Greece); Mantziaras, George, E-mail: gmantziaras@yahoo.com [Academy of Athens, Biomedical Research Foundation (Greece); Kelekis, Nikolaos L., E-mail: kelnik@med.uoa.gr; Brountzos, Elias N., E-mail: ebrountz@med.uoa.gr [National and Kapodistrian University of Athens, 2nd Department of Radiology, Medical School, General University Hospital Attikon (Greece)

2011-10-15T23:59:59.000Z

68

Is Embolization of the Pancreas Safe? Pancreatic Histological Changes after Selective Transcatheter Arterial Embolization with N-Butyl Cyanoacrylate in a Swine Model  

SciTech Connect

Purpose: This study was designed to evaluate the safety of selective transcatheter arterial embolization (TAE) with N-butyl cyanoacrylate (NBCA) in a swine model in terms of histological changes in the pancreas. Methods: Three groups of two female swine (58-64 kg) per group underwent TAE of the dorsal pancreatic artery, under anesthesia, with 1:1, 1:4, and 1:9 mixtures of NBCA and iodized oil. Blood parameters were evaluated at days 1, 4, and 10 after TAE, after which the animals were sacrificed and pancreatic tissues were examined under light microscopy. Results: All of the animals were asymptomatic and survived for 10 days. Cone beam computed tomographic angiography revealed occlusion of the dorsal pancreatic artery and no enhancement in the embolized area. The white blood cell count and C-reactive protein level were elevated slightly on day 1 after TAE (mean {+-} SD: 252.7 {+-} 27.8 Multiplication-Sign 10{sup 2}/{mu}l and 0.15 {+-} 0.07 mg/l, respectively), but they normalized or remained near the upper normal limit thereafter. The serum amylase and lipase levels also were elevated on day 1 (8831.7 {+-} 2169.2 U/l and 130 {+-} 53.4 U/l, respectively) but normalized thereafter. Histologically, necrosis and fibrosis were noted only in the embolized segment, and necrosis and acute inflammatory reactions were absent in the nonembolized segment. The border between both segments was well defined. Lymphocytic infiltration and foreign body reaction were noted around the embolized vessels. Conclusions: Selective TAE with NBCA in the pancreas caused localized ischemic necrosis without clinically significant pancreatitis; therefore, this procedure is tolerable in swine.

Okada, Takuya, E-mail: okabone@gmail.com; Yamaguchi, Masato [Kobe University Graduate School of Medicine, Department of Radiology (Japan); Takahashi, Takuya [Kobe Red Cross Hospital, Department of Pathology (Japan); Izaki, Kenta; Uotani, Kensuke; Sakamoto, Noriaki; Sugimura, Kazuro; Sugimoto, Koji [Kobe University Graduate School of Medicine, Department of Radiology (Japan)

2012-02-15T23:59:59.000Z

69

Stratigraphy, petrology, and depositional environments of upper Cretaceous and Lower Tertiary Sabbath Creek section, Arctic National Wildlife Refuge (ANWR), Alaska  

Science Conference Proceedings (OSTI)

A 9387-ft (2816-m) section of Upper Cretaceous-Lower Tertiary strata is exposed along Sabbath Creek in the northern ANWR of north-eastern Alaska and represents a regressive depositional sequence. The entire section is divided into four lithologic units (A-D), each characterized by distinct depositional assemblages. Unit A, at the base of the section, consists of several coarsening-upward sequences of alternating thick organic-rich siltstones an fine-grained litharenites, representing deposition in subaqueous to lower delta-plain environments. Unit B stratigraphically overlies Unit A and is characterized by multiple, mutually erosive, fining-upward sequences of fine to coarse pebble litharenites typical of point-bar sequences in a meandering stream environment (lower to upper delta plain). Unit C consists of multiple, poorly developed fining-upward sequences of dominantly clast- and matrix-supported pebble conglomerate interpreted as braided stream deposits. At the top of the section, Unit D is characterized by multiple fining- and a few coarsening-upward sequences of organic-rich shale with minor amounts of medium to coarse litharenite and pebble conglomerate representing meandering stream deposition. The Sabbath Creek section is lithologically dissimilar to coeval units to the west. The Sagavanirktok Formation and Colville Group contain pyroclastic material and thick coal beds not seen in the Sabbath Creek section. Instead, this section is lithologically similar to the Moose Channel formation - a regressive, fluvial, deltaic sequence exposed in the MacKenzie delta area of northwestern Canada. Consequently , detailed interpretation of the sabbath Creek section has important implications concerning the petroleum potential of the Arctic National Wildlife Refuge and offshore beaufort Sea.

Buckingham, M.L.

1985-04-01T23:59:59.000Z

70

Taming massive distributed datasets: data sampling using bitmap indices  

Science Conference Proceedings (OSTI)

With growing computational capabilities of parallel machines, scientific simulations are being performed at finer spatial and temporal scales, leading to a data explosion. The growing sizes are making it extremely hard to store, manage, disseminate, ... Keywords: big data, bitmap indexing, data sampling

Yu Su; Gagan Agrawal; Jonathan Woodring; Kary Myers; Joanne Wendelberger; James Ahrens

2013-06-01T23:59:59.000Z

71

Taming the Blue Beast: A Survey of Bluetooth Based Threats  

Science Conference Proceedings (OSTI)

Bluetooth has become a prominent technology since its public debut in 1998, finding its way into everything from Blackberry smart phones to Samsung home theaters to the Toyota Prius and millions of other devices worldwide. This growth has also made Bluetooth ... Keywords: Bluetooth, wireless communications, mobile computing, hacking, security taxonomy

John Dunning

2010-03-01T23:59:59.000Z

72

Taming the Internet for eBusiness Use  

Science Conference Proceedings (OSTI)

Many companies nowadays realise that secure Internet access is a precursor to joining the information superhighway. This paper outlines the solution that BT's Advanced Communications Engineering (ACE) directorate produced, in a joint effort with Concert ...

R. Davison

2000-04-01T23:59:59.000Z

73

Robusta: taming the native beast of the JVM  

Science Conference Proceedings (OSTI)

Java applications often need to incorporate native-code components for efficiency and for reusing legacy code. However, it is well known that the use of native code defeats Java's security model. We describe the design and implementation of Robusta, ... Keywords: JNI, JVM, SFI, sandboxing

Joseph Siefers; Gang Tan; Greg Morrisett

2010-10-01T23:59:59.000Z

74

Taming the wind: Aeolian sound practices in Australasia  

Science Conference Proceedings (OSTI)

The movement of air is a powerful sound generator. Its presence has been perceived and encoded for over 40,000 years in Australia. It is present in natural and humanly organised environments. This paper traces various wind paths, from natural casuarinas ...

Ros Bandt

2003-08-01T23:59:59.000Z

75

Packaged air cleaning systems tame desert dust storms in Oman  

SciTech Connect

Vast storms created when cold, northwesterly air masses slam into hot, southwesterly monsoons, moving lethargically over the Sudan and Red Sea, generate swift downdrafts that strike the ground and deflect forward in a powerful, swirling air stream up to 500 km long. As the wind moves along the ground, it churns up particles ranging in size from 80 to 2000 micrometers. This churning also kicks up particles in the 0.1 to 80 micrometer range, and these may rise to heights of 500 m or more, the smaller of which remain suspended for hours. These conditions made it imperative to protect the blades and internal mechanisms of the gas turbines in use at Yibal, Sultanate of Oman. Each of the gas turbines is equipped with a packaged intake air cleaning system. Because no single air filter has been designed to handle effectively the extremely high concentrations of particulates encountered during storms, the AAF air filters are multistage filtration systems. These systems are discussed.

1980-12-01T23:59:59.000Z

76

Blast biology: a study of the primary and tertiary effects of blast in open underground protective shelters. Project 33. 1 of Operation Plumbbob  

SciTech Connect

Dogs, pigs, rabbits, guinea pigs, and mice were exposed to nuclear detonations in two open underground partitioned shelters. The shelters were of similar construction, and each was exposed to separate detonations. Each inner chamber filled through its own orifice; thus four separate pressure environments were obtained. An aerodynamic mound was placed over the escape hatch of each structure to determine its effect on the pressure-curve shape inside the chamber. In one test a sieve plate bolted across the top of the mound was evaluated. Wind protective baffles of solid plate and of heavy wire screen were installed in the shelters to compare primary and tertiary blast effects on dogs. The shelters also contained static and dynamic pressure gages, radiation detectors, telemetering devices, and, in one test, air-temperature measuring instruments, dust-collecting trays, and eight pigs for the biological assessment of thermal effects. One dog was severely injured from tertiary blast effects associated with a maximal dynamic pressure (Q) of 10.5 psi, and one was undamaged with a maximal Q of 2 psi. Primary blast effects resulting from peak overpressures of 30.3, 25.5, 9.5, and 4.1 psi were minimal. The mortality was 19% of the mice exposed to a peak pressure of 30.3 psi and 5 and 3% of the guinea pigs and mice exposed to a peak pressure of 25.5 psi. Many of the rabbits, guinea pigs, and mice sustained slight lung hemorrhages at maximum pressues of 25.5 and 30.3 psi. Eardrum perforation data for all species, except mice, were recorded. Following shot 2, thermal effects were noted. Animals of the groups saved for observation have died from ionizing-radiation effects.

Ricmond, D.R.; Taborelli, R.V.; Bowen, I.G.

1959-02-01T23:59:59.000Z

77

Effects of in-phase and out-of-phase sediment supply responses to tectonic movement on the sequence development in the late Tertiary Southern Ulleung Basin, East (Japan) Sea  

Science Conference Proceedings (OSTI)

Stratigraphic inverse modeling using the SEDPAK stratigraphic simulator established the size of the physical parameters that together controlled the development of the stratal patterns in the late Tertiary Ulleung Basin, East (Japan) Sea. The modeling ... Keywords: Back-arc, Eustatic sea level, Stratigraphic modeling, Tectonic subsidence, Ulleung Basin

Wonsuck Kim; Daekyo Cheong; Christopher G. St. C. Kendall

2007-03-01T23:59:59.000Z

78

Factors controlling reservoir quality in tertiary sandstones and their significance to geopressured geothermal production. Annual report, May 1, 1979-May 31, 1980  

DOE Green Energy (OSTI)

Differing extents of diagenetic modification is the factor primarily responsible for contrasting regional reservoir quality of Tertiary sandstones from the Upper and Lower Texas Gulf Coast. Detailed comparison of Frio sandstones from the Chocolate Bayou/Danbury Dome area, Brazoria County, and Vicksburg sandstones from the McAllen Ranch Field area, Hidalgo County, reveals that extent of diagenetic modification is most strongly influenced by (1) detrital mineralogy and (2) regional geothermal gradients. Vicksburg sandstones from the McAllen Ranch Field area are less stable, chemically and mechanically, than Frio sandstones from the Chocolate Bayou/Danbury dome area. Vicksburg sandstones are mineralogically immature and contain greater proportions of feldspars and rock fragments than do Frio sandstones. Thr reactive detrital assemblage of Vicksubrg sandstones is highly susceptible to diagenetic modification. Susceptibility is enhanced by higher than normal geothermal gradients in the McAllen Ranch Field area. Thus, consolidation of Vicksburg sandstones began at shallower depth of burial and precipitation of authigenic phases (especially calcite) was more pervasive than in Frio sandstones. Moreover, the late-stage episode of ferroan calcite precipitation that occluded most secondary porosity in Vicksburg sandstones did not occur significantly in Frio sandstones. Therefore, regional reservoir quality of Frio sandstones from Brazoria County is far better than that characterizing Vicksburg sandstones from Hidalgo County, especially at depths suitable for geopressured geothermal energy production.

Loucks, R.G.; Richmann, D.L.; Milliken, K.L.

1980-07-01T23:59:59.000Z

79

Gulf Coast (PADD 3) Exports of Crude Oil and Petroleum Products  

U.S. Energy Information Administration (EIA)

Area: Period-Unit: Download Series History ... 51: 64: 59: 70: 70: 62: 2009-2013: Methyl Tertiary Butyl Ether (MTBE) 41: 44: 49: 61: 49: 50: 2004-2013: Other ...

80

U.S. Oxygenate Production - Energy Information Administration  

U.S. Energy Information Administration (EIA)

Area: Apr-13 May-13 Jun-13 Jul-13 Aug-13 Sep-13 View History; Fuel Ethanol: 855: 877: 891: 868: 849: 852: 1981-2013: Methyl Tertiary Butyl Ether (MTBE) 48: 55: 54: 51 ...

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Preparations for Meeting New York and Connecticut MTBE Bans  

Reports and Publications (EIA)

In response to a Congressional request, EIA examined the progress being made to meet the bans on the use of methyl tertiary butyl ether (MTBE) being implemented in New York and Connecticut at the end of 2003.

Joanne Shore

2003-10-01T23:59:59.000Z

82

35461,"AECTRA REFG & MKTG",1,152,"MOTOR GAS, OTHER FINISHED"...  

U.S. Energy Information Administration (EIA) Indexed Site

TERTIARY BUTYL ETHER (MTBE)",2809,"SANFRANCISCO, CA","CALIFORNIA",5,515,"KOREA, REPUBLIC OF",32,0,0,"WICKLAND OIL CO","SELBY TERM","CA","CALIFORNIA",5...

83

On the Role of Tertiary ?  

Science Conference Proceedings (OSTI)

a solution of 45% acetic acid, 45% butylcellosolve and 10% perchloric acid at 263 K and 25 V. Constant load tensile creep tests were conducted in air at 700°C .

84

Towards a characterization of order-invariant queries over tame structures  

Science Conference Proceedings (OSTI)

This work deals with the expressive power of logics on finite structures with access to an additional “arbitrary” linear order. The queries that can be expressed this way are the order-invariant queries for the logic. For the standard ...

Michael Benedikt; Luc Segoufin

2005-08-01T23:59:59.000Z

85

Taming the Storage Dragon: The Adventures of HoTMaN  

E-Print Network (OSTI)

HoTMaN (HoT-standby MaNager) is a joint research and development project between MySpace and USC Database Laboratory to design and develop a tool to ensure a 24x7 up-time and ease administration of Terabytes of storage that sits underneath hundreds of database servers. The HoTMaN tool’s innovation and uniqueness is that it can, with a few clicks, perform operational tasks that require hundreds of keyboard strokes by “trusted trained ” experts. With HoTMaN, MySpace can within minutes migrate the relational database(s) of a failed server to a hot-standby. A process that could take over 1 hour and had a high potential for human error is now performed reliably. A database internal to HoTMaN captures all virtual disks, volume and file configurations associated with each SQL Server and candidate hot-standby servers where SQL server processing could be migrated. HoTMaN is deployed in production and its current operational benefits include: (i) enhanced availability of data, and (ii) planned maintenance and patching. In the future, HoTMaN can be extended to migrate relational databases when a server reaches an autonomic threshold. 1

Shahram Gh; Andrew Goodney; Chetan Sharma; Chris Bissell; Felipe Cariño; Naveen Nannapaneni; Alex Wergeles; Aber Whitcomb

2009-01-01T23:59:59.000Z

86

A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh...  

NLE Websites -- All DOE Office Websites (Extended Search)

plasma-material interface"-to develop an interface between the hot plasma in the nuclear fusion reactor and the low-temperature material wall. The novel snowflake configuration...

87

Taming Nuclear Power. What have we learned from the Fukushima disaster?  

E-Print Network (OSTI)

We analyze the main causes and consequences of the Fukushima nuclear disaster, in comparison with the previous major accidents of Three Mile Island and Chernobyl (among a total of 30 civilian nuclear accidents).

CERN. Geneva

2011-01-01T23:59:59.000Z

88

Taming Wild Horses: The Need for Virtual Time-based Scheduling of VMs in Network Simulations  

SciTech Connect

The next generation of scalable network simulators employ virtual machines (VMs) to act as high-fidelity models of traffic producer/consumer nodes in simulated networks. However, network simulations could be inaccurate if VMs are not scheduled according to virtual time, especially when many VMs are hosted per simulator core in a multi-core simulator environment. Since VMs are by default free-running, on the outset, it is not clear if, and to what extent, their untamed execution affects the results in simulated scenarios. Here, we provide the first quantitative basis for establishing the need for generalized virtual time scheduling of VMs in network simulators, based on an actual prototyped implementations. To exercise breadth, our system is tested with multiple disparate applications: (a) a set of message passing parallel programs, (b) a computer worm propagation phenomenon, and (c) a mobile ad-hoc wireless network simulation. We define and use error metrics and benchmarks in scaled tests to empirically report the poor match of traditional, fairness-based VM scheduling to VM-based network simulation, and also clearly show the better performance of our simulation-specific scheduler, with up to 64 VMs hosted on a 12-core simulator node.

Yoginath, Srikanth B [ORNL; Perumalla, Kalyan S [ORNL; Henz, Brian J [ORNL

2012-01-01T23:59:59.000Z

89

VERY LOW MASS STELLAR AND SUBSTELLAR COMPANIONS TO SOLAR-LIKE STARS FROM MARVELS. II. A SHORT-PERIOD COMPANION ORBITING AN F STAR WITH EVIDENCE OF A STELLAR TERTIARY AND SIGNIFICANT MUTUAL INCLINATION  

Science Conference Proceedings (OSTI)

We report the discovery via radial velocity (RV) measurements of a short-period (P = 2.430420 {+-} 0.000006 days) companion to the F-type main-sequence star TYC 2930-00872-1. A long-term trend in the RV data also suggests the presence of a tertiary stellar companion with P > 2000 days. High-resolution spectroscopy of the host star yields T{sub eff} = 6427 {+-} 33 K, log g = 4.52 {+-} 0.14, and [Fe/H] = -0.04 {+-} 0.05. These parameters, combined with the broadband spectral energy distribution (SED) and a parallax, allow us to infer a mass and radius of the host star of M{sub 1} = 1.21 {+-} 0.08 M{sub Sun} and R{sub 1} = 1.09{sup +0.15}{sub -0.13} R{sub Sun }. The minimum mass of the inner companion is below the hydrogen-burning limit; however, the true mass is likely to be substantially higher. We are able to exclude transits of the inner companion with high confidence. Further, the host star spectrum exhibits a clear signature of Ca H and K core emission, indicating stellar activity, but a lack of photometric variability and small vsin I suggest that the primary's spin axis is oriented in a pole-on configuration. The rotational period of the primary estimated through an activity-rotation relation matches the orbital period of the inner companion to within 1.5 {sigma}, suggesting that the primary and inner companion are tidally locked. If the inner companion's orbital angular momentum vector is aligned with the stellar spin axis as expected through tidal evolution, then it has a stellar mass of {approx}0.3-0.4 M{sub Sun }. Direct imaging limits the existence of stellar companions to projected separations <30 AU. No set of spectral lines and no significant flux contribution to the SED from either companion are detected, which places individual upper mass limits of M{sub {l_brace}2,3{r_brace}} {approx}< 1.0 M{sub Sun }, provided they are not stellar remnants. If the tertiary is not a stellar remnant, then it likely has a mass of {approx}0.5-0.6 M{sub Sun }, and its orbit is likely significantly inclined from that of the secondary, suggesting that the Kozai-Lidov mechanism may have driven the dynamical evolution of this system.

Fleming, Scott W.; Ge Jian; De Lee, Nathan; Jiang Peng; Lee, Brian; Nelson, Ben [Department of Astronomy, University of Florida, 211 Bryant Space Science Center, Gainesville, FL 2611-2055 (United States); Barnes, Rory [Department of Astronomy, University of Washington, P.O. Box 351580, Seattle, WA 98195 (United States); Beatty, Thomas G.; Gaudi, B. Scott; Shappee, Benjamin J. [Department of Astronomy, Ohio State University, 140 West 18th Avenue, Columbus, OH 43210 (United States); Crepp, Justin R. [Department of Astronomy, California Institute of Technology, 1200 E. California Blvd., Pasadena, CA 91125 (United States); Esposito, Massimiliano; Femenia, Bruno; Gonzalez Hernandez, Jonay I. [Instituto de Astrofisica de Canarias (IAC), E-38205 La Laguna, Tenerife (Spain); Ferreira, Leticia; Porto de Mello, Gustavo F. [Observatorio do Valongo, Universidade Federal do Rio de Janeiro, Ladeira do Pedro Antonio, 43, CEP: 20080-090, Rio de Janeiro, RJ (Brazil); Gary, Bruce; Hebb, Leslie; Stassun, Keivan [Department of Physics and Astronomy, Vanderbilt University, Nashville, TN 37235 (United States); Ghezzi, Luan, E-mail: scfleming@psu.edu [Laboratorio Interinstitucional de e-Astronomia, LIneA, Rua Gal. Jose Cristino 77, Rio de Janeiro, RJ-20921-400 (Brazil); and others

2012-09-15T23:59:59.000Z

90

Refiners look at H sub 2 SO sub 4 alkylation and catalytic reforming  

Science Conference Proceedings (OSTI)

Sulfuric acid alkylation and catalytic reforming drew many questions at the most recent National Petroleum Refiners Association (NPRA) question and answer session on refining and petrochemical technology. At this annual meeting, presubmitted questions are answered by a panel of experts. For more information on the meeting's format, see OGJ, Mar. 16, p. 37. This third and final article in the series of excerpts from the 1991 NPRA Q and A Session examines such pertinent alkylation topics as tertiary amyl methyl ether (TAME) raffinate processing and unit operation during acid runaway. Also discussed are skewed platinum/rhenium reforming catalyst and how catalyst life affects reformate aromatics levels.

Not Available

1992-04-27T23:59:59.000Z

91

Very Low-mass Stellar and Substellar Companions to Solar-like Stars from MARVELS II: A Short-period Companion Orbiting an F Star with Evidence of a Stellar Tertiary And Significant Mutual Inclination  

E-Print Network (OSTI)

We report the discovery via radial velocity of a short-period (P = 2.430420 \\pm 0.000006 days) companion to the F-type main sequence star TYC 2930-00872-1. A long-term trend in the radial velocities indicates the presence of a tertiary stellar companion with $P > 2000$ days. High-resolution spectroscopy of the host star yields T_eff = 6427 +/- 33 K, log(g) = 4.52 +/- 0.14, and [Fe/H]=-0.04 +/- 0.05. These parameters, combined with the broad-band spectral energy distribution and parallax, allow us to infer a mass and radius of the host star of M_1=1.21 +/- 0.08 M_\\odot and R_1=1.09_{-0.13}^{+0.15} R_\\odot. We are able to exclude transits of the inner companion with high confidence. The host star's spectrum exhibits clear Ca H and K core emission indicating stellar activity, but a lack of photometric variability and small v*sin(I) suggest the primary's spin axis is oriented in a pole-on configuration. The rotational period of the primary from an activity-rotation relation matches the orbital period of the inner...

Fleming, Scott W; Barnes, Rory; Beatty, Thomas G; Crepp, Justin R; De Lee, Nathan; Esposito, Massimiliano; Femenia, Bruno; Ferreira, Leticia; Gary, Bruce; Gaudi, B Scott; Ghezzi, Luan; Hernández, Jonay I González; Hebb, Leslie; Jiang, Peng; Lee, Brian; Nelson, Ben; de Mello, Gustavo F Porto; Shappee, Benjamin J; Stassun, Keivan; Thompson, Todd A; Tofflemire, Benjamin M; Wisniewski, John P; Wood-Vasey, W Michael; Agol, Eric; Prieto, Carlos Allende; Bizyaev, Dmitry; Brewington, Howard; Cargile, Phillip A; Coban, Louis; Costello, Korena S; da Costa, Luis N; Good, Melanie L; Hua, Nelson; Kane, Stephen R; Lander, Gary R; Liu, Jian; Ma, Bo; Mahadevan, Suvrath; Maia, Marcio A G; Malanushenko, Elena; Malanushenko, Viktor; Muna, Demitri; Nguyen, Duy Cuong; Oravetz, Daniel; Paegert, Martin; Pan, Kaike; Pepper, Joshua; Rebolo, Rafael; Roebuck, Eric J; Santiago, Basilio X; Schneider, Donald P; Shelden, Alaina; Simmons, Audrey; Sivarani, Thirupathi; Snedden, Stephanie; Vincent, Chelsea L M; Wan, Xiaoke; Wang, Ji; Weaver, Benjamin A; Weaver, Gwendolyn M; Zhao, Bo

2012-01-01T23:59:59.000Z

92

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Ethanol Plant Production Ethanol Plant Production Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Fuel Ethanol An anhydrous alcohol (ethanol with less than 1% water) intended for gasoline blending as described in the Oxygenates definition. Oxygenates Substances which, when added to gasoline, increase the amount of oxygen in that gasoline blend. Ethanol, Methyl Tertiary Butyl Ether (MTBE), Ethyl Tertiary Butyl Ether (ETBE), and methanol are common oxygenates. Fuel Ethanol: Blends of up to 10 percent by volume anhydrous ethanol (200 proof) (commonly referred to as the "gasohol waiver"). Methanol: Blends of methanol and gasoline-grade tertiary butyl alcohol (GTBA) such that the total oxygen content does not exceed 3.5 percent by weight and the ratio of methanol to GTBA is less than or equal to 1. It is also specified that this blended fuel must meet ASTM volatility specifications (commonly referred to as the "ARCO" waiver).

93

SciTech Connect: "smart grid"  

Office of Scientific and Technical Information (OSTI)

Taming the Grid: Dynamic Load Composition Quantification at the Distribution-Transformer Level Citation Details In-Document Search Title: Taming the Grid: Dynamic Load Composition...

94

Uranium favorability of tertiary sedimentary rocks of the Pend Oreille River valley, Washington. [Measurement and sampling of surface sections, collection of samples from isolated outcrops, chemical and mineralogical analyses of samples, and examination of available water logs  

SciTech Connect

Tertiary sedimentary rocks in the Pend Oreille River valley were investigated in a regional study to determine the favorability for potential uranium resources of northeastern Washington. This project involved measurement and sampling of surface sections, collection of samples from isolated outcrops, chemical and mineralogical analyses of samples, and examination of available water well logs. The Box Canyon Dam area north of Ione is judged to have very high favorability. Thick-bedded conglomerates interbedded with sandstones and silty sandstones compose the Tiger Formation in this area, and high radioactivity levels are found near the base of the formation. Uranophane is found along fracture surfaces or in veins. Carbonaceous material is present throughout the Tiger Formation in the area. Part of the broad Pend Oreille valley surrounding Cusick, Washington, is an area of high favorability. Potential host rocks in the Tiger Formation, consisting of arkosic sandstones interbedded with radioactive shales, probably extend throughout the subsurface part of this area. Carbonaceous material is present and some samples contain high concentrations of uranium. In addition, several other possible chemical indicators were found. The Tiger-Lost Creek area is rated as having medium favorability. The Tiger Formation contains very hard, poorly sorted granite conglomerate with some beds of arkosic sandstone and silty sandstone. The granite conglomerate was apparently derived from source rocks having relatively high uranium content. The lower part of the formation is more favorable than the upper part because of the presence of carbonaceous material, anomalously high concentrations of uranium, and other possible chemical indicators. The area west of Ione is judged to have low favorability, because of the very low permeability of the rocks and the very low uranium content. (auth)

Marjaniemi, D.K.; Robins, J.W.

1975-08-01T23:59:59.000Z

95

FCC LPG olefinicity and branching enhanced by octane catalysts  

SciTech Connect

Refiners are increasingly recognizing the downstream opportunities for fluid catalytic cracking LPG olefins for the production of methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE, if the ethanol subsidy is extended to the production of ETBE), and as petrochemical feedstocks. Some of new gasoline FCC octane-enhancing catalysts can support those opportunities because their low non-framework alumina (low NFA) preserve both LPG olefinicity and promote branching of the LPG streams from the FCCU. The combined effect results in more isobutane for alkylate feed, more propylene in the propane/propylene stream, and more isobutene - which makes the addition of an MTBE unit very enticing.

Keyworth, D.A.; Reid, T.A.; Kreider, K.R.; Yatsu, C.A.

1989-05-29T23:59:59.000Z

96

Motor Gasoline Outlook and State MTBE Bans  

Reports and Publications (EIA)

The U.S. is beginning the summer 2003 driving season with lower gasoline inventories and higher prices than last year. Recovery from this tight gasoline market could be made more difficult by impending State bans on the blending of methyl tertiary butyl ether (MTBE) into gasoline that are scheduled to begin later this year.

Information Center

2003-04-01T23:59:59.000Z

97

Understanding the Benefits of Dispersed Grid-Connected Photovoltaics: From Avoiding the Next Major Outage to Taming Wholesale Power Markets  

SciTech Connect

Thanks to new solar resource assessment techniques using cloud cover data available from geostationary satellites, it is apparent that grid-connected PV installations can serve to enhance electric grid reliability, preventing or hastening recovery from major power outages and serving to mitigate extreme price spikes in wholesale energy markets. (author)

Letendre, Steven E.; Perez, Richard

2006-07-15T23:59:59.000Z

98

Radiation chemistry of alternative fuel oxygenates -- Substituted ethers  

DOE Green Energy (OSTI)

The electron beam process, an advanced oxidation and reduction technology, is based in the field of radiation chemistry. Fundamental to the development of treatment processes is an understanding of the underlying chemistry. The authors have previously evaluated the bimolecular rate constants for the reactions of methyl tert-butyl ether (MTBE) and with this study have extended their studies to include ethyl tert-butyl ether (ETBE), di-isopropyl ether (DIPE) and tert-amyl methyl ether (TAME) with the hydroxyl radical, hydrogen atom and solvated electron using pulse radiolysis. For all of the oxygenates the reaction with the hydroxyl radical appears to be of primary interest in the destruction of the compounds in water. The rates with the solvated electron are limiting values as the rates appear to be relatively low. The hydrogen atom rate constants are relatively low, coupled with the low yield in radiolysis, they concluded that these are of little significance in the destruction of the alternative fuel oxygenates (and MTBE).

Mezyk, S. P.; Cooper, W. J.; Bartels, D. M.; Tobien, T.; O'Shea, K. E.

1999-11-15T23:59:59.000Z

99

Texas Alliance for Minorities in Engineering The University of Texas at Austin  

E-Print Network (OSTI)

Texas Alliance for Minorities in Engineering The University of Texas at Austin 10100 Burnet Road, R9200 Austin, Texas 78758 www.tame.org (512) 471-6100 Report: TAME Trailblazer­ Dunbar Jr. High, Lubbock August 29-Sept 2, 2005 Sponsored by Texas Tech University On Monday, August 29, 2005, the TAME

Zhang, Yuanlin

100

Two US markets, or one? How the MTBE-gasoline relationship is evolving  

SciTech Connect

This issue of Energy Detente features the price sensitivity of Methyl Tertiary Butyl Ether. Data is presented for US wholesale gasoline prices vs. MTBE for the 20-month period beginning in June 1994 and ending in January 1996, and the data is discussed. Also contained in this issue is the refining netback data and the fuel price/tax data for the period ending January 5, 1996.

1996-01-26T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

An approach to catalytic asymmetric electrocyclization  

E-Print Network (OSTI)

petroleum ether 40-60 Ph phenyl ppm parts per million Pr propyl q quartet Rf retention factor rt room temperature s singlet sept septet t triplet t tertiary TBAF tetrabutylammonium fluoride TBS tert... demonstrated by Nelson.73 In this case, we observed the formation of lactone 75 by vinyl nucleophile addition to the corresponding aldehydes 71 and 72. We require a less basic source of vinyl anion, or a bulkier ester such as tert-butyl, to prevent any...

Kothari, Abhishek

2010-02-09T23:59:59.000Z

102

Weekly Petroleum Status Report  

U.S. Energy Information Administration (EIA) Indexed Site

5 5 Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH3-(CH2)n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usually refers to the high octane product from alkylation units. This alkylate is used in

103

Update of Summer Reformulated Gasoline Supply Assessment for New York and Connecticut  

Reports and Publications (EIA)

In October 2003, EIA published a review of the status of the methyl tertiary butyl ether (MTBE) ban transition in New York (NY) and Connecticut (CT) that noted significant uncertainties in gasoline supply for those States for the summer of 2004. To obtain updated information, EIA spoke to major suppliers to the two States over the past several months as the petroleum industry began the switch from winter- to summer-grade gasoline.

Information Center

2004-05-01T23:59:59.000Z

104

Process for tertiary oil recovery using tall oil pitch  

DOE Patents (OSTI)

Compositions and process employing same for enhancing the recovery of residual acid crudes, particularly heavy crudes, by injecting a composition comprising caustic in an amount sufficient to maintain a pH of at least about 11, preferably at least about 13, and a small but effective amount of a multivalent cation for inhibiting alkaline silica dissolution with the reservoir. Preferably a tall oil pitch soap is included and particularly for the heavy crudes a polymeric mobility control agent.

Radke, Clayton J. (El Cerrito, CA)

1985-01-01T23:59:59.000Z

105

Process for tertiary oil recovery using tall oil pitch  

DOE Patents (OSTI)

A process and compositions for enhancing the recovery of acid crudes are disclosed. The process involves injecting caustic solutions into the reservoir to maintain a pH of 11 to 13. The fluid contains an effective amount of multivalent cation for inhibiting alkaline silica dissolution with the reservoir. A tall oil pitch soap is added as a polymeric mobility control agent. (DMC)

Radke, C.J.

1983-07-25T23:59:59.000Z

106

Efficient I/O Scheduling in Tertiary Libraries  

Science Conference Proceedings (OSTI)

With the recent improvements in network and processor speeds, several data intensive applications have become much more feasible than ever before. The only practical solution for storing such enormous amounts of data is tertiarystorage. Automated access ...

Sunil Prabhakar; Divyakant Agrawal; Amr El Abbadi; Ambuj Singh

1996-10-01T23:59:59.000Z

107

Tertiary oxidation in Westwater Canyon member of Morrison formation  

SciTech Connect

Hematitic oxidation in the Westwater Canyon Sandstone Member of the Morrison Formation extends along the outcrop from the Pipeline fault northeast of Gallup, New Mexico, to the San Mateo fault north of Grants, New Mexico. The hematitic sandstone forms a broad lobe in the subsurface to a depth of 2,400 ft (730 m). The downdip edge of this sandstone arcs eastward from northeast Church Rock through Crownpoint, and southeastward to the west edge of the Ambrosia Lake district. The red sandstone is bordered on the downdip side by a band of limonitic oxidation, which interfingers with reduced sandstones basinward. The limonitic oxidation forms a relatively narrow band along the north and west sides of the hematitic lobe but expands progressively in an east and southeast direction. Weak limonitic oxidation, as indicated by the absence of pyrite and by a bleached to faint yellowish-gray color, appears to extend from the San Mateo fault eastward under Mount Taylor to the Rio Puerco of the east. The hematitic oxidation is epigenetic and is believed to be of early Miocene to late Pliocene age. The limonitic oxidation follows the present ground-water flow pattern and probably dates from late Pliocene to the Holocene. The oxidation patterns are important in uranium exploration because the hematitic area is essentially barren, whereas the limonitic areas contain ore deposits that are in the process of being destroyed by oxidation.

Saucier, A.E.

1980-01-01T23:59:59.000Z

108

Evaluation of the North Burbank Unit tertiary recovery pilot test  

SciTech Connect

A review of the performance of the Phillips North Burbank micellar-polymer flood has been completed. The projected ultimate recovery is estimated to be ca 300,000 bbl, which is approximately one-half of the initial prediction made by Phillips. Although oil recovery has been less than expected, sufficient additional oil has been recovered to consider the project technically successful. The lower-than-expected oil recovery is attributed principally to high sulfonate losses. Loss of the sulfonate appears to be the result of significant adsorption to the oil-wet pore surfaces and mixing of micellar fluids with in-place water, which is of high salinity and hardness. Contact of the sulfonate with the high concentration of calcium ions creates calcium sulfonate, which either precipitates as an insoluble phase or partitions into the oil phase. Sulfonate partitioning would have created an upper-phase microemulsion, which cannot be displaced easily by water due to the relatively high interfacial tension. 11 references.

Tracy, G.W.; Dauben, D.L.

1982-08-01T23:59:59.000Z

109

Evaluation of the North Burbank unit tertiary recovery pilot test  

Science Conference Proceedings (OSTI)

A review of the performance of the Phillips North Burbank micellar-polymer flood has been completed. The projected ultimate recovery is estimated to be about 300,000 barrels, which is about one half of the initial prediction made by Phillips. Although oil recovery has been less than expected, sufficient additional oil has been recovered to consider the project technically successful. The lower-than-expected oil recovery is attributed principally to high sulfonate losses. Loss of the sulfonate appears to be the result of significant adsorption to the oil-wet pore surfaces and mixing of micellar fluids with in-place water, which is of high salinity and hardness. Contact of the sulfonate with the high concentration of calcium ions creates calcium sulfonate, which either precipitates as an insoluble phase or partitions into the oil phase. Sulfonate partitioning would have created an upper-phase microemulsion, which cannot be easily displaced by water due to the relatively high interfacial tension. The following recommendations are made for improvement of the project: (1) Since preflushes may not always be effective or practical, use a surfactant system which is more tolerant of salinity and hardness. (2) A preflush, if needed, could be improved by designing the volume and salinity of injected fluids to efficiently remove divalent ions from reservoir clays and to displace excess salinity. (3) The surfactant system should be designed with the aid of displacement tests in field cores, conducted over the range of frontal velocities expected in the reservoir. It is particularly important to evaluate displacement at the lower velocity range. (4) Improve operational procedures by conducting workovers prior to pilot initiation and by careful control of injection pressures to insure that fracture extension does not occur.

Tracy, G.W.; Dauben, D.L.

1982-08-01T23:59:59.000Z

110

Low Barrier Hydrogen Bonds in Acyclic Tertiary Diamines  

E-Print Network (OSTI)

In Search of a Low Barrier Hydrogen Bond in Proton Bridgedand J.A. Gerlt, “The Low Barrier Hydrogen Bond in EnzymaticShow That Low-Barrier Hydrogen Bonds do not Offer a

Khodagholian, Sevana

2010-01-01T23:59:59.000Z

111

The CretaceousTertiary Mass Extinction, Chicxulub Impact,  

E-Print Network (OSTI)

) and Meyerhoff et al. (1994) described Cretaceous assemblages in limestones over- lying breccias in Yucatan Pemex-examined the geophysical logs, sedimentology, and biostratigraphy of seven Pemex wells from northern Yucatan and concluded is often not available for study in PEMEX or UNAM wells. As noted earlier, Cretaceous planktic

Keller, Gerta

112

Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 2.  

E-Print Network (OSTI)

will controlled by diffusion in the biofilm near the outlet of the reactor. A fundamental parameter and control in bioreactors equipped with some degree of instrumentation, fundamental knowledge for the proper handbook of physical-chemical properties and environmental fate for organic chemicals, Volume III. Volatile

113

Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 1.  

E-Print Network (OSTI)

, weed-eater, shovel, and a rake. A chipper, compost bin, or a large rented trash dumpster may be useful

114

Spinning Carbon Fiber Precursors from 1-Butyl-3-Methylimidazolium Chloride Cellulose Solutions.  

E-Print Network (OSTI)

??Cellulose is an abundant natural renewable polymer that is used in the production of many materials. However, limited processibility and reduced solubility have restricted its… (more)

Gelderloos-Sammons, Rhea J

2007-01-01T23:59:59.000Z

115

Molecular motions in a viscous organic liquid: ferrocene in cold butyl phthalate  

SciTech Connect

The two main purposes of this work were to learn (a) if rotational diffusion can be seen along with translational, and (b) is (x(T)/sup 2/) unusual as the sample is heated from a glass to a liquid. Our observations show that (a) rotational molecular diffusion is not likely ever to be observed by quadrupole relaxation and (b) that there is indeed a fast increase in (x/sup 2/) above T/sub g/. This increase is correlated with a rapid and linear increase of the number of ''soft modes'' for the liquid above the glass transition temperature.

Ruby, S.L.; Zabransky, B.J.; Flinn, P.A.

1976-01-01T23:59:59.000Z

116

Science and technology review, September 1997  

SciTech Connect

This month`s issue contains articles entitled Nova Laser Experiments and Stockpile Stewardship; Sharing the Challenges of Non- proliferation; and Taming Explosives for Training.

Upadhye, R.

1997-09-01T23:59:59.000Z

117

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Inputs & Utilization Inputs & Utilization Definitions Key Terms Definition All Other Motor Gasoline Blending Components Naphthas (e.g. straight-run gasoline, alkylate, reformate, benzene, toluene, xylene) used for blending or compounding into finished motor gasoline. Includes receipts and inputs of Gasoline Treated as Blendstock (GTAB). Excludes conventional blendstock for oxygenate blending (CBOB), reformulated blendstock for oxygenate blending, oxygenates (e.g. fuel ethanol and methyl tertiary butyl ether), butane, and pentanes plus. Barrel A unit of volume equal to 42 U.S. gallons. Blending Plant A facility which has no refining capability but is either capable of producing finished motor gasoline through mechanical blending or blends oxygenates with motor gasoline.

118

Petroleum Supply Monthly  

Gasoline and Diesel Fuel Update (EIA)

0 0 December 2011 Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH3-(CH2)n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usually refers to the high octane product from alkylation units. This alkylate is used in blending high octane gasoline. Alkylation. A refining process for chemically combining isobutane with olefin hydrocarbons (e.g., propylene, butylene) through the control of temperature and pressure in the presence of an acid catalyst,

119

Petroleum Supply Monthly  

U.S. Energy Information Administration (EIA) Indexed Site

September 2013 September 2013 Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH3-(CH2)n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usually refers to the high octane product from alkylation units. This alkylate is used in blending high octane gasoline. Alkylation. A refining process for chemically combining isobutane with olefin hydrocarbons (e.g., propylene, butylene) through the control of temperature and pressure in the presence of an acid catalyst,

120

MTBE, Oxygenates, and Motor Gasoline (Released in the STEO October 1999)  

Reports and Publications (EIA)

The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an increase in MTBE production between 1990 and 1994. MTBE demand increased from 83,000 in 1990 to 161,000 barrels per day in 1994. The reformulated gasoline (RFG) program provided a further boost to oxygenate blending. The MTBE contained in motor gasoline increased to 269,000 barrels per day by 1997.

Information Center

1999-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model (Released in the STEO March 1998)  

Reports and Publications (EIA)

The blending of oxygenates, such as fuel ethanol and methyl tertiary butyl ether (MTBE), into motor gasoline has increased dramatically in the last few years because of the oxygenated and reformulated gasoline programs. Because of the significant role oxygenates now have in petroleum product markets, the Short-Term Integrated Forecasting System (STIFS) was revised to include supply and demand balances for fuel ethanol and MTBE. The STIFS model is used for producing forecasts in the Short-Term Energy Outlook. A review of the historical data sources and forecasting methodology for oxygenate production, imports, inventories, and demand is presented in this report.

Information Center

1998-03-01T23:59:59.000Z

122

California's Move Toward E10 (released in AEO2009)  

Reports and Publications (EIA)

In AEO2009, E10a gasoline blend containing 10 percent ethanolis assumed to be the maximum ethanol blend allowed in California RFG, as opposed to the 5.7-percent blend assumed in earlier AEOs. The 5.7-percent blend had reflected decisions made when California decided to phase out use of the additive methyl tertiary butyl ether in its RFG program in 2003, opting instead to use ethanol in the minimum amount that would meet the requirement for 2.0 percent oxygen content under the CAA provisions in effect at that time

Information Center

2009-03-31T23:59:59.000Z

123

Fuel Ethanol Oxygenate Production  

Gasoline and Diesel Fuel Update (EIA)

Product: Fuel Ethanol Methyl Tertiary Butyl Ether Merchant Plants Captive Plants Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day Product: Fuel Ethanol Methyl Tertiary Butyl Ether Merchant Plants Captive Plants Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area May-13 Jun-13 Jul-13 Aug-13 Sep-13 Oct-13 View History U.S. 27,197 26,722 26,923 26,320 25,564 27,995 1981-2013 East Coast (PADD 1) 628 784 836 842 527 636 2004-2013 Midwest (PADD 2) 25,209 24,689 24,786 24,186 23,810 26,040 2004-2013 Gulf Coast (PADD 3) 523 404 487 460 431 473 2004-2013 Rocky Mountain (PADD 4) 450 432 430 432 415 429 2004-2013 West Coast (PADD 5)

124

Health hazard evaluation report HETA 86-018-1758, Robbins and Myers, Incorporated, Moyno Products Division, Springfield, Ohio. [Vitiligo  

Science Conference Proceedings (OSTI)

In response to a request from Robbins and Myers, Inc., an investigation was made of a possible health hazard at its Moyno Products Division, Springfield, Ohio. A case of vitiligo, possibly related to working with rubber products in pump manufacture was identified by a dermatologist. Uncured and cured rubber was found to contain 2,4-di-tertiary-butyl-phenol (DTBP) (0.01 to 0.03%) and para-tertiary-butyl-phenol (too low to quantitate). This class of compounds has been associated with vitiligo. Medical survey and examinations revealed four cases of active vitiligo. Its presence was significantly associated with highest exposure to rubber. Rubber department workers had a 22-fold higher risk for the condition compared to other employees. Comparing the four observed cases with an expected 1.1 cases (Health and Nutrition Examination Survey) yielded a standardized morbidity ratio of 3.6. The authors conclude that exposure to DTBP in rubber is the cause of vitiligo in these workers. Recommendations include testing rubber samples for contaminants, modification of work practices, and medical screening of exposed workers.

O'Malley, M.A.; Mathias, C.G.T.

1986-12-01T23:59:59.000Z

125

Hydrocarbons in New Guinea, controlled by basement fabric, Mesozoic extension and Tertiary convergent margin tectonics  

Science Conference Proceedings (OSTI)

Most models for the tectonic evolution of New Guinea involve Early and Late Miocene arc-continent collisions, creating an orogenic belt. Structural trends and prospectivity are then analyzed in terms of belts across the country; the Fold Belt (with the discovered oil and gas fields), the Mobile Belt and the accreted arcs. This model inhibits realistic assessment of prospectivity. It now appears the Mobile Belt formed by Oligocene compression then by Early Miocene extension, related to slab-rollback, that unroofed metamorphic core complexes adjacent to starved half-grabens. The grabens filled in the Middle Miocene and were largely transported intact during the Pliocene arc-collision. Early Miocene reefs and hypothesized starved basin source rocks create a viable play throughout northern New Guinea as in the Salawati Basin. The Pliocene clastic section is locally prospective due to overthrusting and deep burial. Within the Fold Belt, the site and types of oil and gas fields are largely controlled by the basement architecture. This controlled the transfer zones and depocentres during Mesozoic extension and the location of major basement uplifts during compression. In PNG, the Bosavi lineament separates an oil province from a gas province. In Irian Jaya the transition from a relatively competent sequence to a rifted sequence west of [approx]139[degrees]E may also be a gas-oil province boundary. Understanding, in detail, the compartmentalization of inverted blocks and areas of thin-skinned thrusting, controlled by the basement architecture, will help constrain hydrocarbon prospectivity.

Hill, K.C.; Kendrick, R.D.; Crowhurst, P.V. (VIEPS, Melbourne (Australia) SAEFUDIN Ijep, GRDC (India))

1996-01-01T23:59:59.000Z

126

Borehole gravity surveys in the Cretaceous-Tertiary Sagavanirktok Formation, Kuparuk River oil field, Alaska  

SciTech Connect

Detailed borehole gravity surveys (sponsored by the US Department of Energy) were made in three wells in the Kuparuk River and westernmost Prudhoe Bay oil fields, Alaska from depths as shallow as 15 m to as great as 1,340 m through permafrost and underlying heavy oil bearing sandstones of the Sagavanirktok Formation. A subbituminous coal-bearing sequence and the stability field for methane hydrate occur partly within and partly below the permafrost zone, whose base, defined by the 0{degree}C isotherm, varies from 464 to 564 m. The surveys provided accurate, large-volume estimates of in-situ bulk density from which equivalent porosity was calculated using independent grain and pore-fluid density information. This density and porosity data helped to define the rock mass properties within the hydrate stability field and the thermal conductivity, seismic character, and compaction history of the permafrost. Bulk density of the unconsolidated to poorly consolidated sections ranges mostly from 1.9 to 2.3 g/cm{sup 3}. The shallow permafrost section appears to be slightly overcompacted in comparison to similar sedimentary sequences in nonpermafrost regions. The cause of this apparent overcompaction is unknown but may be due to freeze-thaw processes that have similarly affected sea floor and surficial deposits elsewhere in the Arctic. Fluctuations of bulk density appear to be controlled principally by (1) textural variations of the sediments, possibly exaggerated locally within the permafrost zone by excess ice, (2) presence or absence of carbonaceous material, and (3) type of pore-fluid (water-ice vs. water vs. hydrocarbons). As hypothetical models predict bulk-density is slightly lower opposite one interval of possible methane hydrate. Porosity may be as high as 40-45% for selected coarser grained units within the permafrost zone, and as high as 30-35% in a series of well sorted, heavy oil-bearing sandstones.

Beyer, L.A. (Geological Survey, Menlo Park, CA (USA))

1990-05-01T23:59:59.000Z

127

Influence of provenance on detrital and diagenetic mineralogy of small tertiary fans in southwestern Montana  

SciTech Connect

In the North Boulder River basin in southwestern Montana, alluvial fans of the Renova (Oligocene-Miocene) and the Sixmile Creek (Miocene) Formations were deposited on the flanks of north-south-trending uplifts that also supplied the detritus. The Elkhorn Mountain volcanics (78 m.y.) overlying the Boulder batholith make up the western highlands, a small patch of Precambrian Belt Group rocks occur in the southwest and Paleozoic siliciclastic and carbonate rocks forming the eastern margin. The fan sediments thus allow adequate control for studying the influence of source rocks on detrital and diagenetic mineralogy. Modal analysis of 6228 grains in 31 thin sections shows a decrease of VRF away from the igneous sources (37% to 1% in a north-south transect; 37% to 7% in a west-east transect) along with an increase in quartz (8% to 24% and 3% to 13%) and plagioclase (2% to 16% and 2% to 10%); orthoclase abundance is low except in the southwest. Volcanic ash and glass shards are found in the younger sediments in the northern part of the basin. Their data show a positive correlation between the abundance of orthoclase and kaolinite (north-south transect); between SRF and carbonate cement (west-east transect) and between glass shards and smectite (both north-south and west-east transects). They infer that the diagenetic mineralogy of these sands was controlled essentially by the detrital particles, which were strongly controlled by source rocks in this area.

Olson, J.; Basu, A.

1987-05-01T23:59:59.000Z

128

Tertiary nitrogen heterocyclic material to reduce moisture-induced damage in asphalt-aggregate mixtures  

DOE Patents (OSTI)

Asphalt-aggregate roads crack when subjected to freezing and thawing cycles. Herein, the useful life of asphalts are substantially improved by a minor amount of a moisture damage inhibiting agent selected from compounds having a pyridine moiety, including acid salts of such compounds. A shale oil fraction may serve as the source of the improving agent and may simply be blended with conventional petroleum asphalts.

Plancher, Henry (Laramie, WY); Petersen, Joseph C. (Laramie, WY)

1982-01-01T23:59:59.000Z

129

Exposure to, perceptions and levels of mental skills among tertiary institution field hockey players / Maryke Eloff.  

E-Print Network (OSTI)

??The importance of mental skills training (MST) is emphasized by previous/available research findings which show that by combining MST with physical training it enhances players’… (more)

Eloff, Maryke

2010-01-01T23:59:59.000Z

130

ThinkFree: using a visual Wiki for IT knowledge management in a tertiary institution  

Science Conference Proceedings (OSTI)

We describe ThinkFree, an industrial Visual Wiki application which provides a way for end users to better explore knowledge of IT Enterprise Architecture assets that is held within a large enterprise wiki. The application was motivated ... Keywords: knowledge management, visual wiki, visualization

Christian Hirsch; John Hosking; John Grundy; Tim Chaffe

2010-07-01T23:59:59.000Z

131

Secondary porosity in immature Late Cretaceous and Tertiary sandstones, northeast Alaska and northwest Canada  

Science Conference Proceedings (OSTI)

Petrographic and scanning electron microscope analysis of Upper Cretaceous to lower Eocene sandstone from outcrops west of the Mackenzie delta and in the central Arctic National Wildlife Refuge (ANWR) reveals secondary porosity. Recognizing this secondary porosity is important for oil and gas exploration because early diagenesis has eliminated most primary porosity in these immature litharenites. The litharenites are dominated by grains of quartz, cherty argillite, chert, volcanic rock fragments, variable amounts of feldspar, and minor amounts of metamorphic rock fragments. Because of the abundance of ductile grains all deep burial (probable burial to depths in excess of 3,000 m), these sandstones have suffered the loss of most primary porosity. Additional reduction of primary porosity has occurred due to the formation of minor amount of precompaction rim cement (carbonate, chlorite, and illite/smectite) and syncompaction quartz overgrowths. Dissolution of framework grains and, to a lesser degree, matrix has resulted in secondary porosities of up to 8% in outcrop samples. Framework grains commonly dissolved include volcanic rock fragments, feldspar, chert, cherty argillite, argillite, and quartz. Two processes are responsible for the dissolution. The first process is the direct dissolution of grains. The second process involves two steps in which grains and matrix are initially replaced by carbonate cement followed by dissolution of the cement and creation of secondary porosity. Secondary porosity is reported to exceed 20% in subsurface samples in northwest Canada.

Myers, M.D. (Univ. of Alaska, Fairbanks (USA)); Smith, T.N. (State Div. of Oil and Gas, Anchorage, AK (USA))

1990-05-01T23:59:59.000Z

132

New surfactant classes for enhanced oil recovery and their tertiary oil recovery potential  

E-Print Network (OSTI)

conditioned to residual waterflood oil saturation prior to surfactant slug injection. This was followed for more than 35 years, in particular in the USA in depleted oil reservoirs after waterflooding (Garrett., 2000; Jayanti et al., 2001; Berger and Lee, 2002; Endo et al., 2002). During a waterflood (which can

Goddard III, William A.

133

Multiple impacts across the CretaceousTertiary boundary G. Kellera,*, W. Stinnesbeckb  

E-Print Network (OSTI)

to the PEMEX well Soyalo 1. Bochil-2 is about 8 km from the intersection with the main road, whereas Bochil-1

Keller, Gerta

134

Petroleum systems of the Southeast Tertiary basins and Marbella area, Southeast Mexico  

SciTech Connect

This study was done in an area where insufficient organic-rich rocks were available for a reliable oil-source rock correlation. However, oil-rock correlations, molecular characteristics of key horizons, paleofacies maps, maturation and potential migration pathways suggest the Tithonian as a major source rock. Moreover, there is good evidence of high quality source rocks in Oxfordian, Kimmeridgian, Middle-Upper Cretaceous and Paleogene (mainly in the Eocene). Plays were identified in Upper Jurassic oolitic sequences, Early-Middle Cretaceus carbonate platform rocks and breccias, Late Cretaceous basinal fracture carbonates, Paleogene carbonates and breccias, Early-Middle Miocene mounds and submarine fans and isolated carbonate platform sediments and Miocene-Recent turbidites. Seal rocks are shaly carbonates and anhydrites from Tithonian, basinal carbonates and anhydrites from Middle-Upper Cretaceous, basinal carbonates and marls from Upper Cretaceous and Paleogene shales, and bathyal shales from Early Miocene-Recent. The first phase of oil migration from upper Jurassic-Early Cretaceous source rocks occurred in the Early-Middle Cretaceous. In the Upper Cretaceous the Chortis block collided with Chiapas, and as a result mild folding and some hydrocarbons were emplaced to the structural highs. The main phase of structuration and folding of the Sierra de Chiapas started in the Miocene, resulting in well-defined structural traps. Finally, in Plio-Pleistocene the Chortis block was separated, the major compressional period finished and the southern portion of Sierra de Chiapas was raised isostatically. As a result of major subsidence, salt withdrawal and increased burial depth, conditions were created for the generation of liquid hydrocarbons from the Paleogene shales.

Fuentes, F. [Pemex Exploration y Produccion, Mexico City (Mexico)]|[Joint Team, Pemex Exploration y Producion and BP Exploration, Mexico City (Mexico)

1996-08-01T23:59:59.000Z

135

Tertiary Motifs Revealed in Analyses of Higher-Order RNA Junctions  

E-Print Network (OSTI)

. Stahley, A. B. Kosek, J. Wang and S. A. Strobel, Nature, 2004, 430, 45; P. L. Adams, M. R. Stahley, M. L. Gill, A. B. Kosek, J. Wang and S. A. Strobel, RNA, 2004, 10, 1867. 13 F. Guo, A. R. Gooding and T. R

Schlick, Tamar

136

Benign nodular tertiary syphilis: A rare presenting manifestation of HIV infection  

E-Print Network (OSTI)

Hospital, Bangalore Medical College and Research Institute,Hospital, Bangalore Medical College and Research Institute,

Revathi, TN; Bhat, Shilpa; Asha, GS

2011-01-01T23:59:59.000Z

137

Whole-Genome Analysis of Methyl tert-Butyl Ether-Degrading Beta-Proteobacterium Methylibium petroleiphilum PM1  

E-Print Network (OSTI)

of benzene to phenol, catechol, and 1,2,3-trihydroxybenzeneof benzene to phenol (and catechol), and toluene toa multi-component PH, catechol 2,3-dioxygenase and the meta-

2007-01-01T23:59:59.000Z

138

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE  

E-Print Network (OSTI)

and Energy Research (NIPER), 2) the Motor Vehicle Manufacturers Association (MVMA), and 3) the U interested in fuel comparisons Thousands each year Motor Vehicle Manufacturers Association (MVMA) National gasoline survey Motor Vehicle Manufacturers Association 23 cities throughout the U.S. Summer of 1988

139

Influence of temperature on the extraction of Pu(IV) by tri-n-butyl phosphate from acidic nitrate solutions.  

E-Print Network (OSTI)

??The goal of Advanced Fuel Cycle Initiative program is to efficiently separate and recover actinides in attempts to reprocess irradiated nuclear fuel and reduce the… (more)

[No author

2010-01-01T23:59:59.000Z

140

Whole-Genome Analysis of Methyl tert-Butyl Ether-Degrading Beta-Proteobacterium Methylibium petroleiphilum PM1  

E-Print Network (OSTI)

by pure cultures of butane-degrading bacteria. Appl.of K s values for MTBE by butane- degrading bacteria (52).

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

The Friction and Wear Behaviors of (quinazolin-4-ones)-3-methyl-butyl Borate as Additive in Liquid Paraffin  

Science Conference Proceedings (OSTI)

There has been growing concern for the use of mineral oils because of the worldwide interest in environmental issues. This has promoted the use of ash less additives as environmental friendly lubricants. A potential ash less additive containing N, B, ... Keywords: Synthesis, Quinazolin-4-ones, Borate, Additive, Friction and wear behaviors

Ouyang Ping; Zhang Xianming

2011-01-01T23:59:59.000Z

142

Microsoft PowerPoint - AWWA Webinar Modeling talk Dec 8 2008...  

NLE Websites -- All DOE Office Websites (Extended Search)

Phase III TAME Ethanol Plant Appalachian Basin FirstEnergy R.E. Burger Plant Phase III Duke Energy Edwardsport Plant Ohio CO 2 Seq. Test Well Cincinnati Arch Duke Energy East...

143

FACT SHEET NSTX-U  

NLE Websites -- All DOE Office Websites (Extended Search)

current will double to 2 million amperes as a result of the upgrade. A 100-watt light bulb draws 1 amp of current. * Strategies developed for taming the intensely hot plasma...

144

Total Refinery Net Input of Crude Oil and Petroleum Products  

U.S. Energy Information Administration (EIA) Indexed Site

Input Input Product: Total Crude Oil & Petroleum Products Crude Oil Natural Gas Plant Liquids Pentanes Plus Liquefied Petroleum Gases Normal Butane Isobutane Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Hydrogen Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils (net) Unfinished Oils, Naphthas and Lighter Unfinished Oils, Kerosene and Light Gas Oils Unfinished Oils, Heavy Gas Oils Residuum Motor Gasoline Blending Components (MGBC) (net) MGBC - Reformulated MGBC - Reformulated - RBOB MGBC - Reformulated, RBOB for Blending w/ Alcohol MGBC - Reformulated, RBOB for Blending w/ Ether MGBC - Conventional MGBC - CBOB MGBC - Conventional, GTAB MGBC - Other Conventional Aviation Gasoline Blending Components (net) Alaskan Crude Oil Receipts Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

145

Glossary - U.S. Energy Information Administration (EIA)  

U.S. Energy Information Administration (EIA) Indexed Site

petroleum petroleum Alcohol: The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH(3)-(CH(2))n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate: The product of an alkylation reaction. It usually refers to the high-octane product from alkylation units. This alkylate is used in blending high octane gasoline. Alkylation: A refining process for chemically combining isobutane with olefin hydrocarbons (e.g., propylene, butylene) through the control of temperature and pressure in the presence of anacid catalyst, usually sulfuric acid or hydrofluoric acid. The product alkylate, an isoparaffin, has high octane value and is blended with motor and aviation gasoline to

146

Assessment of Summer RBOB Supply for NY & CT  

Gasoline and Diesel Fuel Update (EIA)

Update of Summer Reformulated Gasoline Supply Update of Summer Reformulated Gasoline Supply Assessment for New York and Connecticut May 5, 2004 In October 2003, EIA published a review of the status of the methyl tertiary butyl ether (MTBE) ban transition in New York (NY) and Connecticut (CT) 1 that noted significant uncertainties in gasoline supply for those States for the summer of 2004. To obtain updated information, EIA spoke to major suppliers to the two States over the past several months as the petroleum industry began the switch from winter- to summer-grade gasoline. As discussed on our earlier report, the NY and CT bans on MTBE mainly affect reformulated gasoline (RFG), which in recent years has been provided by domestic refineries on the East Coast (PADD 1) and imports. Our recent findings indicate that

147

Comparative Environmental Performance of Two-Diesel-Fuel Oxygenates: Dibutyl Maleate (DBM) and Triproplyene Glycol Monomethyl Ether (TGME)  

DOE Green Energy (OSTI)

Many studies have shown that the addition of oxygen bearing compounds to diesel fuel can significantly reduce particulate emissions. To assist in the evaluation of the environmental performance of diesel-fuel oxygenates, we have implemented a suite of diagnostic models for simulating the transport of compounds released to air, water, and soils/groundwater as well as regional landscapes. As a means of studying the comparative performance of DBM and TGME, we conducted a series of simulations for selected environmental media. Benzene and methyl tertiary butyl ether (MTBE) were also addressed because they represent benchmark fuel-related compounds that have been the subject of extensive environmental measurements and modeling. The simulations showed that DBM and TGME are less mobile in soil because of reduced vapor-phase transport and increased retention on soil particles. The key distinction between these two oxygenates is that DBM is predicted to have a greater potential than TGME for aerobic biodegradation, based on chemical structure.

Layton, D.W.; Marchetti, A.A.

2001-10-01T23:59:59.000Z

148

Refinery & Blenders Net Input of Crude Oil  

U.S. Energy Information Administration (EIA) Indexed Site

Input Input Product: Total Crude Oil & Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane Normal Butane Isobutane Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Hydrogen Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils (net) Unfinished Oils, Naphthas and Lighter Unfinished Oils, Kerosene and Light Gas Oils Unfinished Oils, Heavy Gas Oils Residuum Motor Gasoline Blending Components (MGBC) (net) MGBC - Reformulated MGBC - Reformulated - RBOB MGBC - Reformulated, RBOB for Blending w/ Alcohol MGBC - Reformulated, RBOB for Blending w/ Ether MGBC - Reformulated, GTAB MGBC - Conventional MGBC - CBOB MGBC - Conventional, GTAB MGBC - Other Conventional Aviation Gasoline Blending Components (net) Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

149

@Title = Definitions of Petroleum Products and Other Terms  

U.S. Energy Information Administration (EIA) Indexed Site

Definitions of Petroleum Products and Other Terms (Revised January 2010) Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH 3 - (CH 2 )n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usually refers to the high octane product from alkylation units. This alkylate is used in blending high octane gasoline. Alkylation. A refining process for chemically combining isobutane with olefin hydrocarbons (e.g., propylene, butylene) through the control of temperature and pressure in the presence of an acid catalyst, usually sulfuric acid or hydrofluoric acid. The product, alkylate, an

150

MTBE Production Economics  

Gasoline and Diesel Fuel Update (EIA)

MTBE Production MTBE Production Economics Tancred C. M. Lidderdale Contents 1. Summary 2. MTBE Production Costs 3. Relationship between price of MTBE and Reformulated Gasoline 4. Influence of Natural Gas Prices on the Gasoline Market 5. Regression Results 6. Data Sources 7. End Notes 1. Summary Last year the price of MTBE (methyl tertiary butyl ether) increased dramatically on two occasions (Figure 1) (see Data Sources at end of article.): 1. Between April and June 2000, the price (U.S. Gulf Coast waterborne market) of MTBE rose from $1.00 per gallon to over $1.60 per gallon. This represented an increase in the price premium for MTBE over the wholesale price of conventional gasoline from its normal (1995 though 2000 average) $0.26 per gallon to $0.60 per gallon. The MTBE

151

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Total Stocks Total Stocks Definitions Key Terms Definition All Other Motor Gasoline Blending Components Naphthas (e.g. straight-run gasoline, alkylate, reformate, benzene, toluene, xylene) used for blending or compounding into finished motor gasoline. Includes receipts and inputs of Gasoline Treated as Blendstock (GTAB). Excludes conventional blendstock for oxygenate blending (CBOB), reformulated blendstock for oxygenate blending, oxygenates (e.g. fuel ethanol and methyl tertiary butyl ether), butane, and pentanes plus. Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels per short ton.

152

Annual Energy Outlook 2005-Acronyms  

Gasoline and Diesel Fuel Update (EIA)

AD AD Associated-dissolved (natural gas) AEO2004 Annual Energy Outlook 2004 AEO2005 Annual Energy Outlook 2005 Altos Altos Partners AMT Alternative Minimum Tax ANWR Arctic National Wildlife Refuge Btu British thermal unit CAFE Corporate average fuel economy CAMR Clean Air Mercury Rule CARB California Air Resources Board CBECS Commercial Buildings Energy Consumption Survey (EIA) CBO Congressional Budget Office CCCC Climate Change Credit Corporation CH 4 Methane CHP Combined heat and power CO 2 Carbon dioxide CTL Coal-to-liquids DB Deutsche Bank, A.G. E85 Fuel containing a blend of 70 to 85 percent ethanol and 30 to 15 percent gasoline by volume EEA Energy and Environmental Analysis, Inc. EIA Energy Information Administration EPA U.S. Environmental Protection Agency EPACT Energy Policy Act of 1992 ETBE Ethyl tertiary butyl ether EVA Energy Ventures Analysis, Incorporated FERC

153

Word Pro - Untitled1  

U.S. Energy Information Administration (EIA) Indexed Site

chemical compounds composed of chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group: CH 3 -(CH 2 )n-OH (e.g., metha- nol, ethanol, and tertiary butyl alcohol). See Fuel Ethanol. Alternative Fuel: Alternative fuels, for transportation applications, include the following: methanol; denatured ethanol, and other alcohols; fuel mixtures contain- ing 85 percent or more by volume of methanol, denatured ethanol, and other alco- hols with motor gasoline or other fuels; natural gas; liquefied petroleum gas (propane); hydrogen; coal-derived liquid fuels; fuels (other than alcohol) derived from biological materials (biofuels such as soy diesel fuel); electricity (including electricity from solar energy); and "... any other fuel the Secretary determines, by

154

Status and Impact of State MTBE Bans  

Gasoline and Diesel Fuel Update (EIA)

Status and Impact of State MTBE Bans Status and Impact of State MTBE Bans Background As a result of the Clean Air Act Amendments of 1990 (CAAA90), the year-round use of reformulated gasoline (RFG) has been required in cities with the worst smog problems since 1995 (Figure 1). One of the requirements of RFG specified by CAAA90 is a 2- percent oxygen requirement, which is met by blending "oxygenates," 1 including methyl tertiary butyl ether (MTBE) and ethanol, into the gasoline. MTBE is the oxygenate used in almost all RFG outside of the Midwest. Ethanol is currently used in the Midwest as an oxygenate in RFG and as an octane booster and volume extender in conventional gasoline. Several years ago, MTBE was detected in water supplies scattered throughout the country, but predominantly in areas using RFG. MTBE from RFG was apparently

155

MTBE, Oxygenates, and Motor Gasoline  

Gasoline and Diesel Fuel Update (EIA)

MTBE, Oxygenates, and MTBE, Oxygenates, and Motor Gasoline Contents * Introduction * Federal gasoline product quality regulations * What are oxygenates? * Who gets gasoline with oxygenates? * Which areas get MTBE? * How much has been invested in MTBE production capacity? * What does new Ethanol capacity cost? * What would an MTBE ban cost? * On-line information resources * Endnotes * Summary of revisions to this analysis Introduction The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an

156

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Weekly Supply Estimates Weekly Supply Estimates Definitions Key Terms Definition All Other Motor Gasoline Blending Components Naphthas (e.g. straight-run gasoline, alkylate, reformate, benzene, toluene, xylene) used for blending or compounding into finished motor gasoline. Includes receipts and inputs of Gasoline Treated as Blendstock (GTAB). Excludes conventional blendstock for oxygenate blending (CBOB), reformulated blendstock for oxygenate blending, oxygenates (e.g. fuel ethanol and methyl tertiary butyl ether), butane, and pentanes plus. Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels per short ton.

157

Annual Energy Outlook 2000 - Acronyms  

Gasoline and Diesel Fuel Update (EIA)

Homepage Homepage ACEEE American Council for an Energy-Efficient Economy AD Associated-dissolved (natural gas) AEO Annual Energy Outlook AGA American Gas Association ANWR Arctic National Wildlife Refuge API American Petroleum Institute BRP Blue Ribbon Panel Btu British thermal unit CAAA90 Clean Air Act Amendments of 1990 CARB California Air Resources Board CCAP Climate Change Action Plan CDM Clean Development Mechanism CECA Comprehensive Electricity Competition Act CIDI Compression ignition direct injection CO Carbon monoxide DBAB Deutsche Banc Alex. Brown DOE U.S. Department of Energy DRI Standard & PoorÂ’s DRI EIA Energy Information Administration EOR Enhanced oil recovery EPA U.S. Environmental Protection Agency EPACT Energy Policy Act of 1992 ETBE Ethyl tertiary butyl ether

158

Appendix A - Acronyms  

NLE Websites -- All DOE Office Websites (Extended Search)

A - ACRONYMS A - ACRONYMS AASHTO American Association of State Highway and Transportation Officials CNG Compressed Natural Gases CVO Commercial Vehicle Operation DOE Department of Energy DOT Department of Transportation E85 85% Ethanol, 15% Gasoline EPA Environmental Protection Agency ExFIRS Excise Files Information Retrieval System ExSTARS Excise Summary Terminal Activity Reporting System FHWA Federal Highway Administration FTA Federation of Tax Administrators GAO General Accounting Office HTF Highway Trust Fund IFTA International Fuel Tax Agreement IM Interstate Maintenance IRS Internal Revenue Service LNG Liquid Natural Gases LPG Liquefied Petroleum Gases M85 85% Methanol, 15% Gasoline MTBE Methyl Tertiary Butyl Ether NHS National Highway System ORNL Oak Ridge National Laboratory STP Surface Transportation Program

159

Word Pro - Untitled1  

U.S. Energy Information Administration (EIA) Indexed Site

chemical chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH(3)-(CH(2)) n -OH (e.g., methanol, ethanol, and tertiary butyl alcohol). See Fuel Ethanol. Alternative Fuel: Alternative fuels, for transportation applications, include the following: methanol; denatured ethanol, and other alcohols; fuel mixtures containing 85 percent or more by volume of methanol, denatured ethanol, and other alcohols with motor gasoline or other fuels; natural gas; liquefied petroleum gas (propane); hydro- gen; coal-derived liquid fuels; fuels (other than alcohol) derived from biological materials (biofuels such as soy diesel fuel); electricity (including electricity from solar

160

Total Blender Net Input of Petroleum Products  

U.S. Energy Information Administration (EIA) Indexed Site

Input Input Product: Total Input Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquid Petroleum Gases Normal Butane Isobutane Other Liquids Oxygenates/Renewables Methyl Tertiary Butyl Ether (MTBE) Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Unfinished Oils (net) Unfinished Oils, Naphthas and Lighter Unfinished Oils, Kerosene and Light Gas Oils Unfinished Oils, Heavy Gas Oils Residuum Motor Gasoline Blending Components (MGBC) (net) MGBC - Reformulated MGBC - Reformulated - RBOB MGBC - Reformulated, RBOB for Blending w/ Alcohol MGBC - Reformulated, RBOB for Blending w/ Ether MGBC - Reformulated, GTAB MGBC - Conventional MGBC - Conventional, CBOB MGBC - Conventional, GTAB MGBC - Other Conventional Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Motor Gasoline Outlook and State MTBE Bans  

Gasoline and Diesel Fuel Update (EIA)

Motor Gasoline Outlook Motor Gasoline Outlook and State MTBE Bans Tancred Lidderdale Contents 1. Summary 2. MTBE Supply and Demand 3. Ethanol Supply 4. Gasoline Supply 5. Gasoline Prices A. Long-Term Equilibrium Price Analysis B. Short-Term Price Volatility 6. Conclusion 7. Appendix A. Estimating MTBE Consumption by State 8. Appendix B. MTBE Imports and Exports 9. Appendix C. Glossary of Terms 10. End Notes 11. References 1. Summary The U.S. is beginning the summer 2003 driving season with lower gasoline inventories and higher prices than last year. Recovery from this tight gasoline market could be made more difficult by impending State bans on the blending of methyl tertiary butyl ether (MTBE) into gasoline that are scheduled to begin later this year. Three impending State bans on MTBE blending could significantly affect gasoline

162

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Imports & Exports Imports & Exports Definitions Key Terms Definition All Other Motor Gasoline Blending Components Naphthas (e.g. straight-run gasoline, alkylate, reformate, benzene, toluene, xylene) used for blending or compounding into finished motor gasoline. Includes receipts and inputs of Gasoline Treated as Blendstock (GTAB). Excludes conventional blendstock for oxygenate blending (CBOB), reformulated blendstock for oxygenate blending, oxygenates (e.g. fuel ethanol and methyl tertiary butyl ether), butane, and pentanes plus. Barrel A unit of volume equal to 42 U.S. gallons. Conventional Blendstock for Oxygenate Blending (CBOB) Motor gasoline blending components intended for blending with oxygenates to produce finished conventional motor gasoline. Conventional Gasoline Finished motor gasoline not included in the oxygenated or reformulated gasoline categories. Excludes reformulated gasoline blendstock for oxygenate blending (RBOB) as well as other blendstock.

163

PSADEFS.CHP:Corel VENTURA  

Gasoline and Diesel Fuel Update (EIA)

Definitions Definitions of Petroleum Products and Other Terms Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH 3 - (CH 2 )n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usu- ally refers to the high octane product from alkylation units. This alkylate is used in blending high octane gaso- line. Alkylation. A refining process for chemically combining isobutane with olefin hydrocarbons (e.g., propylene, buty- lene) through the control of temperature and pressure in the presence of an acid catalyst, usually sulfuric acid or hydrofluoric acid. The product, alkylate, an isoparaffin, has high octane value and is blended with motor and aviation gasoline to improve the antiknock

164

Eliminating MTBE in Gasoline in 2006  

Gasoline and Diesel Fuel Update (EIA)

02/22/2006 02/22/2006 Eliminating MTBE in Gasoline in 2006 Summary In 2005, a number of petroleum companies announced their intent to remove methyl tertiary-butyl ether (MTBE) from their gasoline in 2006. Companies' decisions to eliminate MTBE have been driven by State bans due to water contamination concerns, continuing liability exposure from adding MTBE to gasoline, and perceived potential for increased liability exposure due to the elimination of the oxygen content requirement for reformulated gasoline (RFG) included in the Energy Policy Act of 2005. EIA's informal discussions with a number of suppliers indicate that most of the industry is trying to move away from MTBE before the 2006 summer driving season. Currently, the largest use of MTBE is in RFG consumed on the East Coast outside of

165

Annual Energy Outlook 1999 - Acronyms  

Gasoline and Diesel Fuel Update (EIA)

acronyms.gif (3491 bytes) acronyms.gif (3491 bytes) AD - Associated/dissolved natural gas AEO98 - Annual Energy Outlook 1998 AEO99 - Annual Energy Outlook 1999 AFVs - Alternative-fuel vehicles AGA - American Gas Association API - American Petroleum Institute BTAB - BT Alex Brown CAAA90 - Clean Air Act Amendments of 1990 CCAP - Climate Change Action Plan CDM - Clean Development Mechanism CFCs - Chlorofluorocarbons CNG - Compressed natural gas CO - Carbon monoxide CO2 - Carbon dioxide DOE - U.S. Department of Energy DRI - DRI/McGraw-Hill EIA - Energy Information Administration EOR - Enhanced oil recovery EPA - U.S. Environmental Protection Agency EPACT - Energy Policy Act of 1992 ETBE - Ethyl tertiary butyl ether EU - European Union FERC - Federal Energy Regulatory Commission GDP - Gross domestic product

166

MTBE movements between Texas Gulf Coast plants to be enhanced  

SciTech Connect

This paper reports that Texas Eastern Products Pipeline Co. (Teppco), Houston, has begun construction of its shuttle pipeline, a 10-mile, 6 and 8-in. line to move methyl tertiary butyl ether (MTBE) between producers and refiners along the Houston Ship Channel. Funding for the project has been approved, rights-of-way are secured, and procurement of materials is under way, according to Teppco. The line will flow from the western edge of Shell's refinery eastward to storage facilities of Teppco's Baytown terminal. The shuttle pipeline anticipates the US requirement for oxygenated gasolines that takes effect Nov. 1. Approximately 70% of the available US merchant capacity for MTBE is located along the shuttle's path, Teppco says.

Not Available

1992-07-27T23:59:59.000Z

167

The efficient use of natural gas in transportation  

DOE Green Energy (OSTI)

Concerns over air quality and greenhouse gas emissions have prompted discussion as well as action on alternative fuels and energy efficiency. Natural gas and natural gas derived fuels and fuel additives are prime alternative fuel candidates for the transportation sector. In this study, we reexamine and add to past work on energy efficiency and greenhouse gas emissions of natural gas fuels for transportation (DeLuchi 1991, Santini et a. 1989, Ho and Renner 1990, Unnasch et al. 1989). We add to past work by looking at Methyl tertiary butyl ether (from natural gas and butane component of natural gas), alkylate (from natural gas butanes), and gasoline from natural gas. We also reexamine compressed natural gas, liquified natural gas, liquified petroleum gas, and methanol based on our analysis of vehicle efficiency potential. We compare the results against nonoxygenated gasoline.

Stodolsky, F.; Santini, D.J.

1992-01-01T23:59:59.000Z

168

The efficient use of natural gas in transportation  

DOE Green Energy (OSTI)

Concerns over air quality and greenhouse gas emissions have prompted discussion as well as action on alternative fuels and energy efficiency. Natural gas and natural gas derived fuels and fuel additives are prime alternative fuel candidates for the transportation sector. In this study, we reexamine and add to past work on energy efficiency and greenhouse gas emissions of natural gas fuels for transportation (DeLuchi 1991, Santini et a. 1989, Ho and Renner 1990, Unnasch et al. 1989). We add to past work by looking at Methyl tertiary butyl ether (from natural gas and butane component of natural gas), alkylate (from natural gas butanes), and gasoline from natural gas. We also reexamine compressed natural gas, liquified natural gas, liquified petroleum gas, and methanol based on our analysis of vehicle efficiency potential. We compare the results against nonoxygenated gasoline.

Stodolsky, F.; Santini, D.J.

1992-04-01T23:59:59.000Z

169

Catalytic distillation process  

DOE Patents (OSTI)

A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

Smith, Jr., Lawrence A. (Bellaire, TX)

1982-01-01T23:59:59.000Z

170

Catalytic distillation process  

DOE Patents (OSTI)

A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

Smith, L.A. Jr.

1982-06-22T23:59:59.000Z

171

An empirical study of potentials of adoption of grid computing as a vehicle for tertiary institutions collaboration  

Science Conference Proceedings (OSTI)

Grid computing is emerging as the foundation upon which virtual collaborations can be built among large organisations with the aim of integrating and sharing computer resources, and thus offering performance and resource availability, which is unattainable ...

Faith-Michael E. Uzoka; B. A. Akinnuwesi; S. O. Olabiyisi; Alabi Demilade

2012-06-01T23:59:59.000Z

172

INCREASED OIL PRODUCTION AND RESERVES UTILIZING SECONDARY/TERTIARY RECOVERY TECHNIQUES ON SMALL RESERVOIRS IN THE PARADOX BASIN, UTAH  

Science Conference Proceedings (OSTI)

The Paradox Basin of Utah, Colorado, and Arizona contains nearly 100 small oil fields producing from shallow-shelf carbonate buildups or mounds within the Desert Creek zone of the Pennsylvanian (Desmoinesian) Paradox Formation. These fields typically have one to four wells with primary production ranging from 700,000 to 2,000,000 barrels (111,300-318,000 m{sup 3}) of oil per field at a 15 to 20 percent recovery rate. Five fields in southeastern Utah were evaluated for waterflood or carbon-dioxide (CO{sub 2})-miscible flood projects based upon geological characterization and reservoir modeling. Geological characterization on a local scale focused on reservoir heterogeneity, quality, and lateral continuity as well as possible compartmentalization within each of the five project fields. The Desert Creek zone includes three generalized facies belts: (1) open-marine, (2) shallow-shelf and shelf-margin, and (3) intra-shelf, salinity-restricted facies. These deposits have modern analogs near the coasts of the Bahamas, Florida, and Australia, respectively, and outcrop analogs along the San Juan River of southeastern Utah. The analogs display reservoir heterogeneity, flow barriers and baffles, and lithofacies geometry observed in the fields; thus, these properties were incorporated in the reservoir simulation models. Productive carbonate buildups consist of three types: (1) phylloid algal, (2) coralline algal, and (3) bryozoan. Phylloid-algal buildups have a mound-core interval and a supra-mound interval. Hydrocarbons are stratigraphically trapped in porous and permeable lithotypes within the mound-core intervals of the lower part of the buildups and the more heterogeneous supramound intervals. To adequately represent the observed spatial heterogeneities in reservoir properties, the phylloid-algal bafflestones of the mound-core interval and the dolomites of the overlying supra-mound interval were subdivided into ten architecturally distinct lithotypes, each of which exhibits a characteristic set of reservoir properties obtained from outcrop analogs, cores, and geophysical logs. The Anasazi and Runway fields were selected for geostatistical modeling and reservoir compositional simulations. Models and simulations incorporated variations in carbonate lithotypes, porosity, and permeability to accurately predict reservoir responses. History matches tied previous production and reservoir pressure histories so that future reservoir performances could be confidently predicted. The simulation studies showed that despite most of the production being from the mound-core intervals, there were no corresponding decreases in the oil in place in these intervals. This behavior indicates gravity drainage of oil from the supra-mound intervals into the lower mound-core intervals from which the producing wells' major share of production arises. The key to increasing ultimate recovery from these fields (and similar fields in the basin) is to design either waterflood or CO{sub 2}-miscible flood projects capable of forcing oil from high-storage-capacity but low-recovery supra-mound units into the high-recovery mound-core units. Simulation of Anasazi field shows that a CO{sub 2} flood is technically superior to a waterflood and economically feasible. For Anasazi field, an optimized CO{sub 2} flood is predicted to recover a total 4.21 million barrels (0.67 million m3) of oil representing in excess of 89 percent of the original oil in place. For Runway field, the best CO{sub 2} flood is predicted to recover a total of 2.4 million barrels (0.38 million m3) of oil representing 71 percent of the original oil in place. If the CO{sub 2} flood performed as predicted, it is a financially robust process for increasing the reserves in the many small fields in the Paradox Basin. The results can be applied to other fields in the Rocky Mountain region, the Michigan and Illinois Basins, and the Midcontinent.

Thomas C. Chidsey, Jr.

2002-11-01T23:59:59.000Z

173

Solvent-extraction and purification of uranium(VI) and molybdenum(VI) by tertiary amines from acid leach solutions  

Science Conference Proceedings (OSTI)

Considering international interest in the yellow-cake price, Argentina is seeking to exploit new uranium ore bodies and processing plants. A study of similar plants would suggest that solvent- extraction with Alamine 336 is considered the best method for the purification and concentration of uranium present in leaching solutions. In order to study the purification of these leach liquors, solvent-extraction tests under different conditions were performed with simulated solutions which containing molybdenum and molybdenum-uranium mixtures. Preliminary extraction tests carried out on mill acid-leaching liquors are also presented. (authors)

La Gamma, Ana M.G.; Becquart, Elena T.; Chocron, Mauricio [Gerencia Quimica, Comision Nacional de Energia Atomica, Av. del Libertador 8250 (1429), Buenos Aires (Argentina)

2008-07-01T23:59:59.000Z

174

Paleomagnetic and structural evidence for middle Tertiary counterclockwise block rotation in the Dixie Valley region, west-central Nevada  

Science Conference Proceedings (OSTI)

Paleomagnetic data from late Oligocene to early Miocene ash-flow tuffs at four localities in the northern Dixie Valley region, west-central Nevada, indicate that parts of the crust have rotated counterclockwise by at least 25/sup 0/ and perhaps significantly more in late Cenozoic time. Field relations in White Rock Canyon, Stillwater Range, suggest that rotation (1) was accommodated by right-lateral slip on northwest-trending faults, (2) spanned ash-flow tuff emplacement, and (3) probably ceased before eruption of overlying middle Miocene basalts. Accurate estimates of Cenozoic extension, as well as evaluation of earlier Mesozoic structures, must include the strain partitioned into rotation in the area.

Hudson, M.R.; Geissman, J.W.

1987-07-01T23:59:59.000Z

175

Volume and accessibility of entrained (solution) methane in deep geopressured reservoirs - tertiary formations of the Texas Gulf Coast. Final report  

DOE Green Energy (OSTI)

The objective of this project was to appraise the total volume of in-place methane dissolved in formation waters of deep sandstone reservoirs of the onshore Texas Gulf Coast within the stratigraphic section extending from the base of significant hydrocarbon production (8000 ft)* to the deepest significant sandstone occurrence. The area of investigation is about 50,000 mi/sup 2/. Factors that determine the total methane resource are reservoir bulk volume, porosity, and methane solubility; the latter is controlled by the temperature, pressure, and salinity of formation waters. Regional assessment of the volume and the distribution of potential sandstone reservoirs was made from a data base of 880 electrical well logs, from which a grid of 24 dip cross sections and 4 strike cross sections was constructed. Solution methane content in each of nine formations or divisions of formations was determined for each subdivision. The distribution of solution methane in the Gulf Coast was described on the basis of five reservoir models. Each model was characterized by depositional environment, reservoir continuity, porosity, permeability, and methane solubility.

Gregory, A.R.; Dodge, M.M.; Posey, J.S.; Morton, R.A.

1980-10-01T23:59:59.000Z

176

Increased Oil Production and Reserves Utilizing Secondary/Tertiary Recovery Techniques on Small Reservoirs in the Paradox Basin, Utah  

SciTech Connect

The primary objective of this project is to enhance domestic petroleum production by field demonstration and technology transfer of an advanced- oil-recovery technology in the Paradox basin, southeastern Utah. If this project can demonstrate technical and economic feasibility, the technique can be applied to approximately 100 additional small fields in the Paradox basin alone, and result in increased recovery of 150 to 200 million barrels (23,850,000-31,800,000 m3) of oil. This project is designed to characterize five shallow-shelf carbonate reservoirs in the Pennsylvanian (Desmoinesian) Paradox Formation and choose the best candidate for a pilot demonstration project for either a waterflood or carbon-dioxide-(CO2-) miscible flood project. The field demonstration, monitoring of field performance, and associated validation activities will take place within the Navajo Nation, San Juan County, Utah.

Jr., Chidsey, Thomas C.; Allison, M. Lee

1999-11-02T23:59:59.000Z

177

Polymer floods: A case study of nonlinear wave analysis and of instability control in tertiary oil recovery  

SciTech Connect

Polymer flooding in oil reservoir simulation is considered in two space dimensions. The wave structures associated with such a process give rise to interesting phenomena in the nonlinear regime which have direct bearing on the efficiency of oil recovery. These waves influence and can prevent surface instabilities of the fingering mode. In this paper we resolve these waves by a front tracking method. We consider the fingering problem and the issue of oil recovery for the polymer flood. The details of these two phenomena depend on the separation between the waves and upon the viscosity contrast between the oil, water and polymer. We identify a nonlinear transfer of instability between adjacent waves and a nonlinear enhancement of recovery due to successive waves. The conclusions produced by this work are also pertinent to tracer flooding. One interesting conclusion applies to polymer injection followed by pure water injection. In this case the instability is transferred to the polymer-water interface, and the pure water region can break through the polymer to achieve direct contact with the oil. The polymer is left in narrow ribbons parallel to the main flow field and is by-passed by pure water. The effect of narrow regions of by-passed polymer can be simulated by the front tracking method and is not equivalent to numerical or physical diffusion, which would distribute the polymer more uniformly and retard the breakthrough of water through the polymer layer. 45 refs., 15 figs.

Daripa, P.; Glimm, J.; Lindquist, B.; McBryan, O.

1986-11-01T23:59:59.000Z

178

Polymer floods: A case study of nonlinear wave analysis and of instability control in tertiary oil recovery  

Science Conference Proceedings (OSTI)

Polymer flooding in oil reservoir simulation is considered in two space dimensions. The wave structures associated with such a process give rise to interesting phenomena in the nonlinear regime which have direct bearing on the efficiency of oil recovery. These waves influence and can prevent surface instabilities of the fingering mode. In this paper the authors resolve these waves by a front tracking method. They consider the fingering problem and the issue of oil recovery for the polymer flood. The details of these two phenomena depend on the separation between the waves and upon the viscosity contrast between the oil, water and polymer. They identify a nonlinear transfer of instability between adjacent waves and a nonlinear enhancement of recovery due to successive waves. The conclusions produced by this work are also pertinent to tracer flooding. One interesting conclusion applies to polymer injection followed by pure water injection. In this case the instability is transferred to the polymer-water interface, and the pure water region can break through the polymer to achieve direct contact with the oil. The polymer is left in narrow ribbons parallel to the main flow field and is by-passed by pure water. The effect of narrow regions of by-passed polymer can be simulated by the front tracking method and is not equivalent to numerical or physical diffusion, which would distribute the polymer more uniformly and retard the breakthrough of water through the polymer layer.

Daripa, P.; Glimm, J.; Lindquist, B.; McBryan, O.

1988-04-01T23:59:59.000Z

179

Extraction of Am(III) from nitric acid by octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide-tri-n-butyl phosphate mixtures  

SciTech Connect

The extraction behavior of Am(III) from nitric acid by octyl(phenyl)-N,N-diisobutylcarbamoylmethyphosphine oxides, O0D(IB)CMPO, in the presence of tributylphosphate, TBP, has been studied using diethylbenzene, decalin, and normal aliphatic hydrocarbon diluents. Relative to O0D(IB)CMPO alone, mixtures of TBP and O0D(IB)CMPO show a slight enhancement in the extraction of Am(III) from nitric acid solution above 2 M and a moderate decrease in extraction for lower acid concentrations. The net effect of TBP addition to O0D(IB)CMPO (as well as other selected carbamoylmethylphosphoryl extractants) is a relative insensitivity of the distribution ratio of Am(III) to HNO/sub 3/ concentration in the range of 0.5 M to 6 M and facilitated stripping of Am(III) with dilute acid. Since a continuous variation study of Am(III) extraction using mixtures of O0D(IB)CMPO and TBP at a fixed total concentration revealed no evidence of a mixed complex, the TBP appears to be behaving primarily as a phase modifier. The most significant benefit gained from addition of TBP to O0D(IB)CMPO is the increased metal ion loading capacity and extractant compatibility with alicyclic and aliphatic diluents. The use of TBP to overcome phase compatibility with other bifunctional extractants of the carbamoylmethylphosphoryl type and the use of other phase modifiers with O0D(IB)CMPO have also been investigated. 15 references, 7 figures, 2 tables.

Horwitz, E.P.; Kalina, D.G.

1984-01-01T23:59:59.000Z

180

Task 4.9 -- Value-added products from syngas. Semi-annual report, July 1--December 31, 1996  

DOE Green Energy (OSTI)

The work on advanced fuel forms in 1996 focused on the synthesis of higher alcohols from mixtures of hydrogen and carbon dioxide (syngas) from coal gasification. Initial work in this project utilized a novel molybdenum sulfide catalyst previously shown to be active for hydrodesulfurization reactions of coal liquids. A pressurized fixed-bed flow-through reactor was constructed, and the MoS{sub 2} catalysts were tested with syngas under a variety of conditions. Unfortunately, the catalysts, even with higher molybdenum loading and addition of promoters, failed to give alcohol products. A batch reactor test of the catalyst was also conducted, but did not produce alcohol products. Group VIII metals have been used previously in catalysts for syngas reactions. Ruthenium and rhodium catalysts were prepared by impregnation of a hydrotalcite support. Tests with these catalysts in flow-through reactors also did not produce the desired alcohol products. The formation of higher alcohols from smaller ones, such as methanol and ethanol, could be commercially important if high selectivity could be achieved. The methanol and ethanol would be derived from syngas and fermentation, respectively. Based on previous work in other laboratories, it was hypothesized that the hydrotalcite-supported MoS{sub 2} or Ru or Rh catalysts could catalyze the formation of butyl alcohols. Although the desired 1-butanol was obtained in batch reactions with the promoted ruthenium catalyst, the reaction was not as selective as desired. Product suitable for a lower-vapor-pressure gasoline oxygenate additive was obtained, but it may not be economical to market such products in competition with methyl tertiary-butyl ether (MTBE). Flow-through catalytic bed reactions were not successful.

Olson, E.S.; Sharma, R.K.

1997-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Modeling the Geometric Electronic and Redox Properties of Iron(lll)-Containing Amphiphiles with Asymmetric [NNO] Headgroups  

DOE Green Energy (OSTI)

Two iron(III)-containing amphiphiles 1 and 2 have been synthesized with the [NN'O] ligands HL{sup tBu-ODA} (2-((octadecyl(pyridin-2-ylmethyl)amino)methyl)-4,6-di-tert-butylphenol) and HL{sup I-ODA} (2-((octadecyl(pyridin-2-ylmethyl)amino)methyl)-4,6-diiodophenol), respectively. Compound 1 is monometallic, whereas EXAFS data suggest that 2 is a mixture of mono- and bimetallic species. The archetypical [Fe{sup III}(L{sup NN'O}){sub 2}]{sup +} complexes 3-9 have been isolated and characterized in order to understand the geometric, electronic, and redox properties of the amphiphiles. Preference for a monometallic or bimetallic nuclearity is dependent on (i) the nature of the solvent used for synthesis and (ii) the type of the substituent in the phenol moiety. In methanol, the tert-butyl-, methoxy-, and chloro-substituted 3, 4, and 5 are monometallic species, whereas the bromo- and iodo-substituted 6 and 7 form bimetallic complexes taking advantage of stabilizing methoxo bridges generated by solvent deprotonation. In dichloromethane, the bromo- and iodo-substituted 8 and 9 are monometallic species; however, these species favor meridional coordination in opposition to the facial coordination observed for the tert-butyl- and methoxy-substituted compounds. Molecular structures for species 5, 7, 8, and 9 have been solved by X-ray diffraction. Furthermore, the electronic spectrum of the amphiphile 1 was expected to be similar to those of facial/cis archetypes with similar substituents, but close resemblance was observed with the profile for those meridional/cis species, suggesting a similar coordination mode. This trend is discussed based on DFT calculations, where preference for the meridional/cis coordination mode appears related to the presence of tertiary amine nitrogen on the ligand, as when a long alkyl chain is attached to the [NN'O] headgroup.

R Shakya; M Allard; M Johann; M Heeg; E Rentschler; J Shearer; B McGarvey; C Verani

2011-12-31T23:59:59.000Z

182

Preliminary geologic characterization of Upper Cretaceous and Lower Tertiary low-permeability (tight) gas bearing rocks in the Wind River Basin, Wyoming  

SciTech Connect

The geology and stratigraphy of natural gas deposits in the Wind River Basin, Wyoming, was investigated. The study will be utilized to help determine the gas potential of the basin.

Johnson, R.C.; Finn, T.M.; Keefer, W.R.; Flores, R.M.; Keighin, C.W.; Szmajter, R.J.; Nuccio, V.F.

1995-05-01T23:59:59.000Z

183

Comparison of maternal and neonatal outcome before and after the availability of a rapid assay for fetal fibronectin at a tertiary level maternity hospital  

E-Print Network (OSTI)

before and after test availability as compared to those whoBenjamin A. (2005). Does availability of fetal fibronectinBefore and After the Availability of a Rapid Assay for Fetal

Poeltler, Debra Ann Milbert

2010-01-01T23:59:59.000Z

184

Semantic management of middleware  

Science Conference Proceedings (OSTI)

The Ph.D. proposal addresses the complexity of building distributed applications and systems with Application Servers and Web Services middleware, respectively. Despite their flexible XML-based configuration, taming the ever growing complexity remains ... Keywords: application server, middleware, ontology, semantic technology, service oriented architecture, web service

Daniel Oberle

2004-10-01T23:59:59.000Z

185

QuarterlyCouncil > In this issue  

E-Print Network (OSTI)

updates its long-term plan for meeting growth in demand.The power plant that became Langley Gulch has been of helping to tame the wild child of the energy world, wind power. The Langley Gulch Power Plant will help system.The plant is capable of producing enough power for about 208,000 homes. At a dedication ceremony

186

meeting of the NSTX Program Advisory Committee Princeton Plasma Physics Laboratory  

E-Print Network (OSTI)

lithium divertor (LLD) for particle pumping, higher-power fast-wave heating for current ramp-up studies to inform the design of a demonstration #12;fusion power plant." The ST physics issues identified to "Tame the plasma material interface" (such as NHTX), for an ST-based demonstration power plant (ST- Demo

Princeton Plasma Physics Laboratory

187

Physics Department Alumni Reunion  

E-Print Network (OSTI)

Physics Department Alumni Reunion September 21-22, 2012 Collegeof Communication (COM) MetcalfScienceCenter (SCI) MetcalfPlaza CommonwealthAvenue PhysicsResearch Building LifeScienceand Engineering Beacon Barabasi (PhD 1994) Distinguished University Professor of Physics, Northeastern University Taming

188

A New Approach to Gaudapadakarika  

E-Print Network (OSTI)

and being kept on it becomes explanded Likewise is the yogin's mind (ch. 156). The tamed horse also may be compared here (Ibid). The Y ogasutra refers to about nine factors of distraction and their s<'tellites about five in all (I, 30-32). In order...

Sastri, N. Aiyaswami

1971-02-26T23:59:59.000Z

189

Towards Integrated Verification of Timed Transition Models  

Science Conference Proceedings (OSTI)

This paper describes an attempt to combine theorem proving and model-checking to formally verify real-time systems in a discrete time setting. The Timed Automata Modeling Environment (TAME) has been modified to provide a formal model for Time Transition ... Keywords: PVS, Real-time, SAL, equivalence verification, model reduction, model-checking, theorem proving

Mark Lawford; Vera Pantelic; Hong Zhang

2006-04-01T23:59:59.000Z

190

U.S. Blender Net Input  

U.S. Energy Information Administration (EIA) Indexed Site

2007 2008 2009 2010 2011 2012 View 2007 2008 2009 2010 2011 2012 View History Total Input 1,184,435 1,522,193 1,850,204 2,166,784 2,331,109 2,399,318 2005-2012 Natural Gas Plant Liquids and Liquefied Refinery Gases 3,445 5,686 6,538 7,810 10,663 2008-2012 Pentanes Plus 2,012 474 1,808 1,989 2,326 4,164 2005-2012 Liquid Petroleum Gases 2,971 3,878 4,549 5,484 6,499 2008-2012 Normal Butane 2,943 2,971 3,878 4,549 5,484 6,499 2005-2012 Isobutane 2005-2006 Other Liquids 1,518,748 1,844,518 2,160,246 2,323,299 2,388,655 2008-2012 Oxygenates/Renewables 234,047 274,974 286,837 295,004 2009-2012 Methyl Tertiary Butyl Ether (MTBE) 2005-2006 Renewable Fuels (incl. Fuel Ethanol) 234,047 274,974 286,837 295,004 2009-2012 Fuel Ethanol 131,810 182,772 232,677 273,107 281,507 287,433 2005-2012

191

U.S. Blender Net Input  

U.S. Energy Information Administration (EIA) Indexed Site

Apr-13 May-13 Jun-13 Jul-13 Aug-13 Sep-13 View Apr-13 May-13 Jun-13 Jul-13 Aug-13 Sep-13 View History Total Input 206,541 217,867 212,114 216,075 219,783 208,203 2005-2013 Natural Gas Plant Liquids and Liquefied Refinery Gases 891 352 376 196 383 1,397 2008-2013 Pentanes Plus 261 301 313 67 287 393 2005-2013 Liquid Petroleum Gases 630 51 63 129 96 1,004 2008-2013 Normal Butane 630 51 63 129 96 1,004 2005-2013 Isobutane 2005-2006 Other Liquids 205,650 217,515 211,738 215,879 219,400 206,806 2008-2013 Oxygenates/Renewables 25,156 26,576 26,253 26,905 27,788 25,795 2009-2013 Methyl Tertiary Butyl Ether (MTBE) 2005-2006 Renewable Fuels (incl. Fuel Ethanol) 25,156 26,576 26,253 26,905 27,788 25,795 2009-2013 Fuel Ethanol 24,163 25,526 24,804 25,491 25,970 24,116 2005-2013

192

Total Crude Oil and Petroleum Products Exports  

U.S. Energy Information Administration (EIA) Indexed Site

Exports Exports Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Motor Gasoline Blend. Comp. (MGBC) MGBC - Reformulated MGBC - Conventional Aviation Gasoline Blend. Comp. Finished Petroleum Products Finished Motor Gasoline Reformulated Gasoline Conventional Gasoline Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., Greater than 15 to 500 ppm Distillate F.O., Greater than 500 ppm Residual Fuel Oil Naphtha for Petro. Feed. Use Other Oils Petro. Feed. Use Special Naphthas Lubricants Waxes Petroleum Coke Asphalt and Road Oil Miscellaneous Products Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

193

Annual Energy Outlook 2000 - Legislation & Regulations  

Gasoline and Diesel Fuel Update (EIA)

leg_reg.gif (4810 bytes) Climate Change Action Plan Comprehensive Electricity Competition Act Tier 2 Vehicle Emissions and Gasoline Sulfur Standards California Ban of Methyl Tertiary Butyl Ether Low-Emission Vehicle Program Introduction Because analyses by the Energy Information Administration (EIA) are required to be policy-neutral, the projections in this Annual Energy Outlook 2000 (AEO2000) are based on Federal, State, and local laws and regulations in effect on July 1, 1999. The potential impacts of pending or proposed legislation, regulations, and standards and sections of existing legislation for which funds have not been appropriated are not reflected in the projections. Federal legislation incorporated in the projections includes the Omnibus Budget Reconciliation Act of 1993, which adds 4.3 cents per gallon to the Federal tax on highway fuels [1]; the National Appliance Energy Conservation Act of 1987; the Clean Air Act Amendments of 1990 (CAAA90); the Energy Policy Act of 1992 (EPACT); the Outer Continental Shelf Deep Water Royalty Relief Act of 1995; the Tax Payer Relief Act of 1997; and the Federal Highway Bill of 1998, which includes an extension of the ethanol tax credit. AEO2000 assumes the continuation of the ethanol tax credit through 2020.

194

The National Energy Modeling System: An Overview 2000 - International  

Gasoline and Diesel Fuel Update (EIA)

international energy module (IEM) consists of four submodules (Figure 4) that perform the following functions: international energy module (IEM) consists of four submodules (Figure 4) that perform the following functions: world oil market submodule—calculates the average annual world oil price (imported refiner acquisition cost) that is consistent with worldwide petroleum demand and supply availability crude oil supply submodule—provides im- ported crude oil supply curves for five crude oil quality classes petroleum products supply submodule—pro- vides imported refined product supply curves for eleven types of refined products oxygenates supply submodule—provides imported oxygenates supply curves for methyl tertiary butyl ether (MTBE) and methanol. Figure 4. International Energy Module Structure The world oil price that is generated by the world oil market submodule is used by all the modules of NEMS as well as the other submodules of IEM. The import supply curves for crude oils, refined products, and oxygenates are used by the petroleum market module.

195

Word Pro - Untitled1  

U.S. Energy Information Administration (EIA) Indexed Site

1 1 Table 10.5 Estimated Number of Alternative-Fueled Vehicles in Use and Fuel Consumption, 1992-2010 Year Alternative and Replacement Fuels 1 Liquefied Petroleum Gases Compressed Natural Gas Liquefied Natural Gas Methanol, 85 Percent (M85) 3 Methanol, Neat (M100) 4 Ethanol, 85 Percent (E85) 3,5 Ethanol, 95 Percent (E95) 3 Elec- tricity 6 Hydro- gen Other Fuels 7 Subtotal Oxygenates 2 Bio- diesel 10 Total Methyl Tertiary Butyl Ether 8 Ethanol in Gasohol 9 Total Alternative-Fueled Vehicles in Use 11 (number) 1992 NA 23,191 90 4,850 404 172 38 1,607 NA NA NA NA NA NA NA NA 1993 NA 32,714 299 10,263 414 441 27 1,690 NA NA NA NA NA NA NA NA 1994 NA 41,227 484 15,484 415 605 33 2,224 NA NA NA NA NA NA NA NA 1995 172,806 50,218 603 18,319 386 1,527

196

Refinery Stocks of Crude Oil and Petroleum Products  

Gasoline and Diesel Fuel Update (EIA)

Product: Crude Oil and Petroleum Products Crude Oil Petroleum Products Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils Naphthas and Lighter Kerosene and Light Gas Oils Heavy Gas Oils Residuum Motor Gasoline Blending Components MGBC - Reformulated MGBC - Reformulated - RBOB MGBC - RBOB for Blending with Alcohol* MGBC - RBOB for Blending with Ether* MGBC - Conventional MGBC - Conventional CBOB MGBC - Conventional GTAB MGBC - Conventional Other Aviation Gasoline Blending Components Finished Motor Gasoline Reformulated Reformulated Blended with Fuel Ethanol Reformulated, Other Conventional Gasoline Conventional Gasoline Blended with Fuel Ethanol Conventional Gasoline Blended with Fuel Ethanol, Ed55 and Lower Conventional Other Gasoline Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Distillate Fuel Oil Distillate Fuel Oil, 15 ppm and Under Distillate Fuel Oil, Greater than 15 ppm to 500 ppm Distillate Fuel Oil, Greater than 500 ppm Residual Fuel Oil Less than 0.31 Percent Sulfur 0.31 to 1.00 Percent Sulfur Greater than 1.00 Percent Sulfur Petrochemical Feedstocks Naphtha for Petrochemical Feedstock Use Other Oils for Petrochemical Feedstock Use Special Naphthas Lubricants Waxes Petroleum Coke Marketable Coke Asphalt and Road Oil Miscellaneous Products Period-Units: Monthly-Thousand Barrels Annual-Thousand Barrels

197

Catalyst and process development for synthesis gas conversion to isobutylene. Quarterly report, October 1, 1993--December 31, 1993  

SciTech Connect

The objectives of this project are to develop a new catalyst; the kinetics for this catalyst; reactor models for trickle bed, slurry and fixed bed reactors; and to simulate the performance of fixed bed trickle flow reactors, slurry flow reactors, and fixed bed gas phase reactors for conversion of a hydrogen lean synthesis gas to isobutylene. A hydrogen-lean synthesis gas with a ratio of H{sub 2}/CO of 0.5 to 1.0 is produced from the gasification of coal, lignite, or biomass. Isobutylene is a key reactant in the synthesis of methyl tertiary butyl ether (MTBE) and of isooctanes. MTBE and isooctanes are high octane fuels used to blend with low octane gasolines to raise the octane number required for modern automobiles. The production of these two key octane boosters is limited by the supply of isobutylene. MTBE, when used as an octane enhancer, also decreases the amount of pollutants emitted from the exhaust of an automobile engine.

Anthony, R.G.; Akgerman, A.

1994-05-01T23:59:59.000Z

198

Heterogeneous catalytic process for alcohol fuels from syngas. Final technical report  

DOE Green Energy (OSTI)

The primary objective of this project has been the pursuit of a catalyst system which would allow the selective production from syngas of methanol and isobutanol. It is desirable to develop a process in which the methanol to isobutanol weight ratio could be varied from 70/30 to 30/70. The 70/30 mixture could be used directly as a fuel additive, while, with the appropriate downstream processing, the 30/70 mixture could be utilized for methyl tertiary-butyl ether (MTBE) synthesis. The indirect manufacture of MTBE from a coal derived syngas to methanol and isobutanol process would appear to be a viable solution to MTBE feedstock limitations. To become economically attractive, a process fro producing oxygenates from coal-derived syngas must form these products with high selectivity and good rates, and must be capable of operating with a low-hydrogen-content syngas. This was to be accomplished through extensions of known catalyst systems and by the rational design of novel catalyst systems.

Dombek, B.D.

1996-03-01T23:59:59.000Z

199

Task 4.9 -- Value-added products from syngas  

DOE Green Energy (OSTI)

The work on advanced fuel forms in 1996 focused on the synthesis of higher alcohols from mixtures of hydrogen and carbon dioxide (syngas) from coal gasification. The conversion of coal gasification products to commercially valuable alcohols will provide an important new market for current and future gasification plants. Initial work in this project utilized a novel molybdenum sulfide catalyst previously shown to be active for hydrodesulfurization reactions of coal liquids. The support for the active metal sulfide is a layered mixed oxide (hydrotalcite) capable of interaction with the metal sites for catalysis of carbon monoxide reductions. These catalysts have a high surface area, are highly porous, and have basic and acidic functionality. A pressurized fixed-bed flow-through reactor was constructed, and the MoS{sub 2} catalysts were tested with syngas under a variety of conditions. Unfortunately, the catalysts, even with higher molybdenum loading and addition of promoters, failed to give alcohol products. A batch reactor test of the catalyst was also conducted, but did not produce alcohol products. Group 8 metals have been used previously in catalysts for syngas reactions. Ruthenium and rhodium catalysts were prepared by impregnation of a hydrotalcite support. Tests with these catalysts in flow-through reactors also did not produce the desired alcohol products. The formation of higher alcohols from smaller ones, such as methanol and ethanol, could be commercially important if high selectivity could be achieved. The methanol and ethanol would be derived from syngas and fermentation, respectively. Based on previous work in other laboratories, it was hypothesized that the hydrotalcite supported MoS{sub 2} or Ru or Rh catalysts could catalyze the formation of butyl alcohols. Although the desired 1-butanol was obtained in batch reactions with the promoted Ru catalyst, the reaction was not as selective as desired. Product suitable for a lower-vapor-pressure gasoline oxygenate additive was obtained, but it may not be economical to market such products in competition with methyl tertiary-butyl-ether. Flow-through catalytic bed reactions were not successful.

Olson, E.S.; Sharma, R.K.

1997-02-01T23:59:59.000Z

200

Self-Assembly of Surfactant Vesicles that Transform into Viscoelastic Wormlike Micelles upon Heating  

E-Print Network (OSTI)

worms such as the above find use in industrial applications such as hydraulic fracturing for tertiary

Raghavan, Srinivasa

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

The Earth System Grid: Turning Climate Datasets  

E-Print Network (OSTI)

Download Data Search NERSC MSS, HPSS: Tertiary data storage systems First Generation ESG Architecture RLS

202

Microsoft Word - MRCSP Phase III FactSheet _09-08_ _2_.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

MRCSP Large Scale CO2 Storage in the Mount Simon Reservoir 1 MRCSP Large Scale CO2 Storage in the Mount Simon Reservoir 1 FACT SHEET FOR PARTNERSHIP FIELD VALIDATION TEST Midwest Regional Carbon Sequestration Partnership (MRCSP) NETL Cooperative Agreement DE-FC26-05NT42589 DOE/NETL Project Manager: Lynn Brickett, Lynn.Brickett@NETL.DOE.GOV Submitted by Battelle September 2008 MRCSP Phase III Large Scale Geologic Injection Test Principal Investigator Dave Ball, Battelle (614)-424-4901; balld@battelle.org) Test Location Primary Site: The Andersons Marathon Ethanol (TAME) Plant, Greenville, Ohio. Optional Site: Duke IGCC plant, Edwardsport, Indiana Amount and Source of CO 2 Primary Site: 1,000,000 tons CO 2 over 4 years. Source, TAME Ethanol Plant Optional Site: 2,000,000 tons CO 2 over 4 years. Source, Duke IGCC

203

Maintenance Effectiveness Assessment  

Science Conference Proceedings (OSTI)

Utilities want to know whether their equipment is being maintained in the most effective manner. Understanding the relationship between maintenance costs and benefits becomes even more important when established practices and schedules change. This report defines the problem of and presents a roadmap for the development of metrics for evaluating substation equipment maintenance effectiveness. A proposed suite of tools for assessing maintenance effectiveness TAME can provide a business analytics framework...

2010-12-23T23:59:59.000Z

204

Optics and Fluid Dynamics Ris-R-1227(EN) Annual Progress Report for 2000  

E-Print Network (OSTI)

of polymer films by laser ablation 12 2.3 New laser systems 13 2.3.1 A new high-power 1.5 µm laser diode thickness determination and cutting of plants by lasers 22 3. Optical diagnostics and information processing dynamics 49 4.1 Introduction 49 4.2 Fusion plasma physics 49 4.2.1 Taming drift-wave turbulence 49 4

205

Ethanol Demand in United States Production of Oxygenate-limited Gasoline  

SciTech Connect

Ethanol competes with methyl tertiary butyl ether (MTBE) to satisfy oxygen, octane, and volume requirements of certain gasolines. However, MTBE has water quality problems that may create significant market opportunities for ethanol. Oak Ridge National Laboratory (ORNL) has used its Refinery Yield Model to estimate ethanol demand in gasolines with restricted use of MTBE. Reduction of the use of MTBE would increase the costs of gasoline production and possibly reduce the gasoline output of U.S. refineries. The potential gasoline supply problems of an MTBE ban could be mitigated by allowing a modest 3 vol percent MTBE in all gasoline. In the U.S. East and Gulf Coast gasoline producing regions, the 3 vol percent MTBE option results in costs that are 40 percent less than an MTBE ban. In the U.S. Midwest gasoline producing region, with already high use of ethanol, an MTBE ban has minimal effect on ethanol demand unless gasoline producers in other regions bid away the local supply of ethanol. The ethanol/MTBE issue gained momentum in March 2000 when the Clinton Administration announced that it would ask Congress to amend the Clean Air Act to provide the authority to significantly reduce or eliminate the use of MTBE; to ensure that air quality gains are not diminished as MTBE use is reduced; and to replace the existing oxygenate requirement in the Clean Air Act with a renewable fuel standard for all gasoline. Premises for the ORNL study are consistent with the Administration announcement, and the ethanol demand curve estimates of this study can be used to evaluate the impact of the Administration principles and related policy initiatives.

Hadder, G.R.

2000-08-16T23:59:59.000Z

206

Dehydration of isobutanol to isobutene in a slurry reactor  

DOE Green Energy (OSTI)

The April 1990 Alternative Fuels Proposal to the Department of Energy involved the development of new technology, based on the liquid phase process, for conversion of coal-derived synthesis gas to oxygenated hydrocarbon fuels, fuel additives, and fuel intermediates. The objective of this work was to develop a slurry reactor based process for the dehydration of isobutanol to isobutene. The isobutene can serve as a feedstock for the high octane oxygenated fuel additive methyl tertiary-butyl either (MTBE). Alumina catalysts were investigated because of their wide use as a dehydration catalyst. Four commercially available alumina catalysts (Catapal B, Versal B, Versal GH, and Al-3996R) were evaluated for both activity and selectivity to the branched olefin. All four catalysts demonstrated conversions greater than 80% at 290 C, while conversions of near 100% could be obtained at 330 C. The reaction favors low pressures and moderate to low space velocities. A yield of 0.90 mole isobutene per mole reacted isobutanol or better was obtained at conversions of 60--70% and higher. From 75 to 98% conversion, the four catalysts all provide isobutene yields ranging from 0.92 to 0.94 with the maximum occurring around 90% conversion. At low conversions, the concentration of diisobutyl ether becomes significant while the concentration of linear butenes is essentially a linear function of isobutanol conversion. Doping the catalyst with up to 0.8 wt % potassium showed a modest increase in isobutene selectivity; however, this increase was more than offset by a reduction in activity. Investigations using a mixed alcohols feed (consistent with isobutanol synthesis from syngas) demonstrated a small increase in the C4 iso-olefin selectivity over that observed for a pure isobutanol feed. 55 refs.

Latshaw, B.E.

1994-02-01T23:59:59.000Z

207

Fuel cycle evaluations of biomass-ethanol and reformulated gasoline. Volume 1  

DOE Green Energy (OSTI)

The US Department of Energy (DOE) is using the total fuel cycle analysis (TFCA) methodology to evaluate energy choices. The National Energy Strategy (NES) identifies TFCA as a tool to describe and quantify the environmental, social, and economic costs and benefits associated with energy alternatives. A TFCA should quantify inputs and outputs, their impacts on society, and the value of those impacts that occur from each activity involved in producing and using fuels, cradle-to-grave. New fuels and energy technologies can be consistently evaluated and compared using TFCA, providing a sound basis for ranking policy options that expand the fuel choices available to consumers. This study is limited to creating an inventory of inputs and outputs for three transportation fuels: (1) reformulated gasoline (RFG) that meets the standards of the Clean Air Act Amendments of 1990 (CAAA) using methyl tertiary butyl ether (MTBE); (2) gasohol (E10), a mixture of 10% ethanol made from municipal solid waste (MSW) and 90% gasoline; and (3) E95, a mixture of 5% gasoline and 95% ethanol made from energy crops such as grasses and trees. The ethanol referred to in this study is produced from lignocellulosic material-trees, grass, and organic wastes -- called biomass. The biomass is converted to ethanol using an experimental technology described in more detail later. Corn-ethanol is not discussed in this report. This study is limited to estimating an inventory of inputs and outputs for each fuel cycle, similar to a mass balance study, for several reasons: (1) to manage the size of the project; (2) to provide the data required for others to conduct site-specific impact analysis on a case-by-case basis; (3) to reduce data requirements associated with projecting future environmental baselines and other variables that require an internally consistent scenario.

Tyson, K.S.

1993-11-01T23:59:59.000Z

208

The feasibility of ethanol production in Texas  

E-Print Network (OSTI)

Agricultural interests across Texas are looking at the possibility of an ethanol industry in Texas. Continued conflict in the Middle East, the ban of methyl tertiary butyl ether (MTBE) in California, and low commodity prices have all lead to increased interest in ethanol throughout the state of Texas. There have been several ethanol feasibility studies conducted. Most studies have been focused in other states, and only one incorporated risk on input and output prices. Very little research has been done in Texas. Previous studies are typically for a generic location and only looked at ethanol production from corn. This study looks at four different plant sizes in three different regions using corn and grain sorghum. This study incorporates risk on input prices (corn, grain sorghum, natural gas, and electricity) and the output prices of ethanol and dried distillers grain with solubles (DDGS). The regions that were analyzed in the study are the Texas Panhandle, the Central Texas region, and the Southeast Texas region. The results indicate that the only plants expected to generate a positive net present value (NPV) were the larger grain sorghum based plants in the Texas Panhandle. The smaller sorghum based plants in the Panhandle did not have a positive NPV. The only other plants that were close to having a positive net present value were the grain sorghum plants in the Central Texas Region. Sorghum in the Southeast Texas Region was not feasible. Using corn as the feedstock was not as feasible in any region. The results of a sensitivity analysis show that a small increase in the net income in the form of increased revenue or reduced costs would make all the plants profitable.

Herbst, Brian Keith

2003-01-01T23:59:59.000Z

209

Three-year Evaluation of Pre-employment Screening for Tuberculosis (TB) and Post-exposure Compliance with Therapy for Latent TB Infection Among Healthcare Workers Working in A Tertiary Care Hospital in Saudi Arabia.  

E-Print Network (OSTI)

??Background: Controlling tuberculosis (TB) among occupationally exposed healthcare workers (HCWs) is challenged by limited documentation of pre- employment tuberculin skin test (TST) screening and the… (more)

Kentenyants, Karine

2012-01-01T23:59:59.000Z

210

Geochemistry, age and strontium isotope composition of late tertiary and quaternary basalts and andesites in western Nevada and their relation to geothermal potential. Final report, October 1, 1982-December 31, 1983  

DOE Green Energy (OSTI)

This research was undertaken to characterize the late Cenozoic volcanic rocks associated with active geothermal systems in west-central Nevada. Petrographic and microprobe, geochemical and isotopic analysis and age dating techniques were used to characterize these young volcanic rocks. These data were combined with the limited data previously reported in the literature on these same volcanic areas to interpret their petrogenesis. The overall characterization resulted from integrating the petrogenesis with a structural-tectonic model of the region. Potassium-argon isotopic ages ranging up to 14 million years were determined for eight localities within the Reno 1 x 2/sup 0/ study region. These ages are consistent with the morphology of the volcanic landforms, the active geothermal systems associated with them, and with other isotopic ages reported in the literature for these and similar rocks within the study region. Petrographic analysis of hand specimens and thin-sections indicated mineralogic assemblages of the respective rock types and specific mineral textures and phenocryst compositions and characteristics. These identifications were further substantiated by microprobe analysis of selected phenocrysts and groundmass phases. Classification of the respective rock types was also based on chemical composition and normative calculations using the program PETCAL. Basaltic andesites are identified and described for Steamboat Hills, Table Mountain, Silver Springs, Churchill Butte, Cleaver Peak, Desert Peak and Carson City sites.

Fultz, L.A.; Bell, E.J.; Trexler, D.T.

1984-01-01T23:59:59.000Z

211

Stephanie L. Outcalt  

Science Conference Proceedings (OSTI)

... The instrument has also been used to measure the solubility of carbon dioxide, propane, propene, butane, and 1-butene in the ionic liquid 1-butyl-3 ...

2012-12-20T23:59:59.000Z

212

Scalable Modeling of Carbon Tetrachloride Migration in the ...  

27 combined with lard oil, tributyl phosphate (TBP) and dibutyl butyl phosphonate 28 (DBBP). ... giving the computer 11.8 TFlops peak theoretical ...

213

xml version="1.0" encoding="UTF-8"?>

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a
real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Stellar Astrophysics Requirements NERSC Forecast  

NLE Websites -- All DOE Office Websites (Extended Search)

Requirements for Requirements for m461:Stellar Explosions in Three Dimensions Tomek Plewa (Florida State University) + 3 graduate students, Artur Gawryszczak (Warsaw), Konstantinos Kifonidis (Munich), Andrzej Odrzywolek (Cracow), Ju Zhang (FIT), Andrey Zhiglo (Kharkov) 1. m461: Stellar Explosions in Three Dimensions * Summarize your projects and expected scientific objectives through 2014 * Modeling and simulations of transient phenomena in stellar astrophysics driven by either radiation or thermonuclear processes * Numerical solution of a coupled system of PDEs and ODEs * Tame nonlinearity! * Our goal is to ... * Explain observed properties of exploding stellar objects * Present focus is ... * Neutrino-driven core-collapse supernova explosions * In the next 3 years we expect to ...

222

SSRL HEADLINES April 2008  

NLE Websites -- All DOE Office Websites (Extended Search)

0 April, 2008 0 April, 2008 __________________________________________________________________________ Contents of this Issue: Science Highlight - Faster than the Speed of Melting Science Highlight - Taming Asthma-related Proteins Could Lead to Easier Breathing for Many LCLS Proposal Preparation Workshops Announced Other Upcoming Schools, Users' Meetings and Workshops JCSG Annual Meeting New Sample Preparation Laboratory Access Policies at SSRL User Administration Update __________________________________________________________________________ 1. Science Highlight - Faster than the Speed of Melting (contacts: A.M. Lindenberg, aaronl@slac.stanford.edu and K.J. Gaffney, kgaffney@slac.stanford.edu) The process of melting has long been of interest to scientists. In the case

223

Fuel-Cycle energy and emission impacts of ethanol-diesel blends in urban buses and farming tractors.  

DOE Green Energy (OSTI)

About 2.1 billion gallons of fuel ethanol was used in the United States in 2002, mainly in the form of gasoline blends containing up to 10% ethanol (E10). Ethanol use has the potential to increase in the U.S. blended gasoline market because methyl tertiary butyl ether (MTBE), formerly the most popular oxygenate blendstock, may be phased out owing to concerns about MTBE contamination of the water supply. Ethanol would remain the only viable near-term option as an oxygenate in reformulated gasoline production and to meet a potential federal renewable fuels standard (RFS) for transportation fuels. Ethanol may also be blended with additives (co-solvents) into diesel fuels for applications in which oxygenation may improve diesel engine emission performance. Numerous studies have been conducted to evaluate the fuel-cycle energy and greenhouse gas (GHG) emission effects of ethanol-gasoline blends relative to those of gasoline for applications in spark-ignition engine vehicles (see Wang et al. 1997; Wang et al. 1999; Levelton Engineering et al. 1999; Shapouri et al. 2002; Graboski 2002). Those studies did not address the energy and emission effects of ethanol-diesel (E-diesel or ED) blends relative to those of petroleum diesel fuel in diesel engine vehicles. The energy and emission effects of E-diesel could be very different from those of ethanol-gasoline blends because (1) the energy use and emissions generated during diesel production (so-called ''upstream'' effects) are different from those generated during gasoline production; and (2) the energy and emission performance of E-diesel and petroleum diesel fuel in diesel compression-ignition engines differs from that of ethanol-gasoline blends in spark-ignition (Otto-cycle-type) engine vehicles. The Illinois Department of Commerce and Community Affairs (DCCA) commissioned Argonne National Laboratory to conduct a full fuel-cycle analysis of the energy and emission effects of E-diesel blends relative to those of petroleum diesel when used in the types of diesel engines that will likely be targeted first in the marketplace. This report documents the results of our study. The draft report was delivered to DCCA in January 2003. This final report incorporates revisions by the sponsor and by Argonne.

Wang, M.; Saricks, C.; Lee, H.

2003-09-11T23:59:59.000Z

224

Total Crude Oil and Petroleum Products Imports by Area of Entry  

U.S. Energy Information Administration (EIA) Indexed Site

by Area of Entry by Area of Entry Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane Ethylene Propane Propylene Normal Butane Butylene Isobutane Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Fuel Other Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils Naphthas and Lighter Kerosene and Light Gas Oils Heavy Gas Oils Residuum Motor Gasoline Blending Components (MGBC) MGBC - Reformulated, RBOB MGBC - Conventional MGBC - Conventional, CBOB MGBC - Conventional, GTAB MGBC - Other Conventional Aviation Gasoline Blending Components Finished Petroleum Products Finished Motor Gasoline Reformulated Gasoline Reformulated Blended w/ Fuel Ethanol Conventional Gasoline Conventional Blended w/ Fuel Ethanol Conventional Blended w/ Fuel Ethanol, Ed55 and Lower Conventional Other Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene-Type Bonded Aircraft Fuel Other Bonded Aircraft Fuel Kerosene Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., Bonded, 15 ppm and under Distillate F.O., Other, 15 ppm and under Distillate F.O., Greater than 15 to 500 ppm Distillate F.O., Bonded, Greater than 15 to 500 ppm Distillate F.O., Other, Greater than 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., Greater than 500 to 2000 ppm Distillate F.O., Bonded, Greater than 500 to 2000 ppm Distillate F.O., Other, Greater than 500 ppm to 2000 ppm Distillate F.O., Greater than 2000 ppm Distillate F.O., Bonded, Greater than 2000 ppm Distillate F.O., Other, Greater than 2000 ppm Residual Fuel Oil Residual F.O., Bonded Ship Bunkers, Less than 0.31% Sulfur Residual F.O., Bonded Ship Bunkers, 0.31 to 1.00% Sulfur Residual F.O., Bonded Ship Bunkers, Greater than 1.00% Sulfur Petrochemical Feedstocks Naphtha for Petrochem. Feed. Use Other Oils for Petrochem Feed. Use Special Naphthas Lubricants Waxes Petroleum Coke Asphalt and Road Oil Miscellaneous Products Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

225

[Research and workshop on alternative fuels for aviation. Final report  

DOE Green Energy (OSTI)

The Renewable Aviation Fuels Development Center (RAFDC) at Baylor University was granted U. S. Department of Energy (US DOE) and Federal Aviation Administration (FAA) funds for research and development to improve the efficiency in ethanol powered aircraft, measure performance and compare emissions of ethanol, Ethyl Tertiary Butyl Ether (ETBE) and 100 LL aviation gasoline. The premise of the initial proposal was to use a test stand owned by Engine Components Inc. (ECI) based in San Antonio, Texas. After the grant was awarded, ECI decided to close down its test stand facility. Since there were no other test stands available at that time, RAFDC was forced to find additional support to build its own test stand. Baylor University provided initial funds for the test stand building. Other obstacles had to be overcome in order to initiate the program. The price of the emission testing equipment had increased substantially beyond the initial quote. Rosemount Analytical Inc. gave RAFDC an estimate of $120,000.00 for a basic emission testing package. RAFDC had to find additional funding to purchase this equipment. The electronic ignition unit also presented a series of time consuming problems. Since at that time there were no off-the-shelf units of this type available, one had to be specially ordered and developed. FAA funds were used to purchase a Super Flow dynamometer. Due to the many unforeseen obstacles, much more time and effort than originally anticipated had to be dedicated to the project, with much of the work done on a volunteer basis. Many people contributed their time to the program. One person, mainly responsible for the initial design of the test stand, was a retired engineer from Allison with extensive aircraft engine test stand experience. Also, many Baylor students volunteered to assemble the. test stand and continue to be involved in the current test program. Although the program presented many challenges, which resulted in delays, the RAFDC's test stand is an asset which provides an ongoing research capability dedicated to the testing of alternative fuels for aircraft engines. The test stand is now entirely functional with the exception of the electronic ignition unit which still needs adjustments.

NONE

1999-09-01T23:59:59.000Z

226

Electrochemical Windows of Room-Temperature Ionic Liquids from Molecular Dynamics and Density Functional Theory Calculations  

E-Print Network (OSTI)

We investigated the cathodic and anodic limits of six room-temperature ionic liquids (ILs) formed from a combination of two common cations, 1-butyl-3-methylimidazolium (BMIM) and N,N-propylmethylpyrrolidinium (P13), and ...

Ong, Shyue Ping

227

Chemical Hygiene and Safety Plan  

E-Print Network (OSTI)

towards shop operations. H-1 Chemic_l Hygiene and Safety ,of this section, any chemic:ads per kflop'am of body welshtUNSUPPORTED CHEMIC. -M. VITON NITrlI.E NATI'R.4I. BUTYL

Ricks Editor, R.

2009-01-01T23:59:59.000Z

228

Radiation Chemistry of MTBE in Aqueous Solution  

NLE Websites -- All DOE Office Websites (Extended Search)

Methyl-tert-Butyl Ether (MTBE) in Aqueous Solution Stephen P. Mezyk, Jace Jones, William J. Cooper, Thomas Tobien, Michael G. Nickelsen, J. Wesley Adams, Kevin E. O'Shea, David M....

229

Effect of ultrasonic irradiation on preparation and properties of ionogels  

Science Conference Proceedings (OSTI)

Silica-gel matrices containing ionic liquid (IL) 1-butyl-3-methylimidazolium hexafluorophosphate viz. ionogels have been synthesized using one-pot nonhydrolytic sol-gel method and taking tetraethyl orthosilicate (TEOS) as starting precursor. Effect of ...

Yogendra Lal Verma; Manish Pratap Singh; Rajendra Kumar Singh

2012-01-01T23:59:59.000Z

230

Incorporation of silica into baroplastic core-shell nanoparticles  

E-Print Network (OSTI)

Core-shell baroplastics are nanophase materials that exhibit pressure-induced flow at low temperatures and high pressures. Core-shell baroplastics used in this work are comprised of a low Tg poly(butyl acrylate) (PBA) core ...

Hewlett, Sheldon A

2006-01-01T23:59:59.000Z

231

Microstructural Stability and Creep of Ru-Containing Nickel-Base ...  

Science Conference Proceedings (OSTI)

distilled water and 65 ml butyl cellusolve. .... The creep curves of UM-F27 and UM -F30 ..... Larson Miller curves of commercial alloys were plotted with data.

232

BMC Health Services Research BioMed Central  

E-Print Network (OSTI)

Research article Patients ' satisfaction and opinions of their experiences during admission in a tertiary care hospital in Pakistan – a cross sectional study

Sardar Zakariya Imam; Khezar Shahzada Syed; Syed Ahad Ali; Syed Umer Ali; Kiran Fatima; Marium Gill; Muhammad Ovais Hassan; Saad Hasan Hashmi; Maham T Siddiqi; Hadi Muhammad Khan; Omar Farooq Jameel; Maham T Siddiqi; Hadi Muhammad Khan; Omar Farooq Jameel

2007-01-01T23:59:59.000Z

233

Retreat of the state and the market: liberalisation and education expansion in Sudan under the NCP.  

E-Print Network (OSTI)

??This thesis is an analysis of two concurrent processes - the liberalisation of the economy and the expansion of the tertiary education system - by… (more)

Mann, Laura Elizabeth

2012-01-01T23:59:59.000Z

234

Coincident P and Sh reflections from basement rocks at Coso geothermal...  

Open Energy Info (EERE)

the steam field, (2) examining the Tertiary sedimentary basins in Rose Valley and Coso Wash, (3) testing the structural relationship of the Mesozoic Sierran basement to the...

235

Fluorination of Thermodynamically Unstable Nickel Fluorides ...  

... atoms at tertiary carbon sites in highly fluorinated molecules require the more powerful oxidizers, NiF 4 and NiF 3, for their oxidation. ...

236

Structural Analysis of the Desert Peak-Brady Geothermal Fields...  

Open Energy Info (EERE)

mapping, delineation of Tertiary strata, analysis of faults and folds, and a new gravity survey have elucidated the structural controls on the Desert Peak and Brady...

237

Geologic And Geophysical Evidence For Intra-Basin And Footwall...  

Open Energy Info (EERE)

the TertiaryQuaternary basin-fill sediments. Correlation with seismic reflection and gravity surveys shows that some faults recognized by minor displacements at the surface...

238

NETL: Oil & Natural Gas Technologies Reference Shelf - Presentation  

NLE Websites -- All DOE Office Websites (Extended Search)

in Kansas Author: Stan McCool, University of Kansas Center for Research Venue: Tertiary Oil Recovery Projects 18th Improved Oil Recovery Conference, Wichita, KS, April 12,...

239

A Seismic Attribute Study to Assess Well Productivity in the Ninilchik Field, Cook Inlet Basin, Alaska.  

E-Print Network (OSTI)

??Coal bed methane which has formed in the Tertiary Kenai Group strata has been produced from the Ninilchik field of Cook Inlet, Alaska since 2001.… (more)

Sampson, Andrew

2011-01-01T23:59:59.000Z

240

Igneous intrusions and thermal evolution in the Raton Basin, CO-NM: contact metamorphism and coal-bed methane generation .  

E-Print Network (OSTI)

??Tertiary mafic dikes and sills intrude coal-bearing formations of the Raton Basin. This study investigates the role of intrusions in generating methane from coal. Coal… (more)

Cooper, Jennifer Rebecca

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Mineralogy and organic petrology of oil shales in the Sangkarewang formation, Ombilin Basin, West Sumatra, Indonesia.  

E-Print Network (OSTI)

??The Ombilin Basin, which lies in Sumatra Island, is one of the Tertiary basins in Indonesia. This basin contains a wide variety of rock units,… (more)

Fatimah, Fatimah

2009-01-01T23:59:59.000Z

242

u42501.PDF  

Office of Legacy Management (LM)

Younger sedimentary rocks overlying the Wasatch Formation are the Tertiary sandstone, oil shale, and marlstone beds of the Green River Formation which crop out almost continuously...

243

GJO-99-112-TAR Rev.  

Office of Legacy Management (LM)

Younger sedimentary rocks overlying the Wasatch Formation are the Tertiary sandstone, oil shale, and marlstone beds of the Green River Formation which crop out almost continuously...

244

--No Title--  

NLE Websites -- All DOE Office Websites (Extended Search)

Confinement Ventilation Systems) with the following titles: 1) BC Off-Gas Exhaust Standby Fan Autostart, 2) E-Wing Supply and Exhaust Interlocks, 3) BC Tertiary Exhaust...

245

Journal of Research Volume 41  

Science Conference Proceedings (OSTI)

... Dipole moments and molecular association of some picrates of primary, secondary, and tertiary amines in benzene and dioxane, p. 1 Maryott ...

2012-10-05T23:59:59.000Z

246

--No Title--  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Ventilation Systems) with the following titles: 1) BC Off-Gas Exhaust Standby Fan Autostart, 2) E-Wing Supply and Exhaust Interlocks, 3) BC Tertiary Exhaust Interlocks...

247

The Effects of Macroscopic Heterogeneities of Pore Structure and Wettability on Residual Oil Recovery Using the Gravity-Assisted Inert Gas Injection (GAIGI) Process.  

E-Print Network (OSTI)

??To recover oil remaining in petroleum reservoirs after waterflooding, the gravitationally stable mode of gas injection is recognized as a promising tertiary oil recovery process.… (more)

Parsaei, Rafat

2012-01-01T23:59:59.000Z

248

Inversion of field-scale partitioning tracer response for characterizing oil saturation distribution: a streamline approach.  

E-Print Network (OSTI)

??Identifying distribution of remaining oil in the reservoir is vital for evaluation of existing waterflood, design of tertiary recovery projects, and location of infill drilling… (more)

Iliassov, Pavel Alexandrovich

2012-01-01T23:59:59.000Z

249

Method for cleaning solution used in nuclear fuel reprocessing  

DOE Patents (OSTI)

Nuclear fuel processing solution consisting of tri-n-butyl phosphate and dodecane, with a complex of uranium, plutonium, or zirconium and with a solvent degradation product such as di-n-butyl phosphate therein, is contacted with an aqueous solution of a salt formed from hydrazine and either a dicarboxylic acid or a hydroxycarboxylic acid, thereby removing the aforesaid complex from the processing solution.

Tallent, O.K.; Crouse, D.J.; Mailen, J.C.

1980-12-17T23:59:59.000Z

250

Silver  

Science Conference Proceedings (OSTI)

Table 5   Corrosion resistance of silver in organic compounds...2 Benzaldehyde, pure and aqueous Boiling Benzene, pure Boiling <0.05 2 Benzotrifluoride, pure Boiling <0.05 2 Benzyl chloride, pure 180 355 <0.05 2 -bromoisovaleryl bromide, pure 100 212 <0.05 2 -bromoisovaleryl urea, pure Melting point <0.05 2 Butyl acetate, pure Boiling <0.05 2 Butyl alcohol,...

251

COAL RESOURCES, POWDER RIVER BASIN By M.S. Ellis,1  

E-Print Network (OSTI)

Chapter PN COAL RESOURCES, POWDER RIVER BASIN By M.S. Ellis,1 G.L. Gunther,2 A.M. Ochs,2 S, Delaware 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky in the toolbar to return. 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky

252

DECKER COALFIELD, POWDER RIVER BASIN, MONTANA: GEOLOGY, COAL QUALITY, AND COAL  

E-Print Network (OSTI)

Chapter PD DECKER COALFIELD, POWDER RIVER BASIN, MONTANA: GEOLOGY, COAL QUALITY, AND COAL RESOURCES Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U.S. Geological Survey of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great Plains region, U

253

COAL QUALITY AND GEOCHEMISTRY, POWDER RIVER BASIN, WYOMING AND MONTANA  

E-Print Network (OSTI)

Chapter PQ COAL QUALITY AND GEOCHEMISTRY, POWDER RIVER BASIN, WYOMING AND MONTANA By G.D. Stricker Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U.S. Geological Survey of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great Plains region, U

254

ASHLAND COALFIELD, POWDER RIVER BASIN, MONTANA: GEOLOGY, COAL QUALITY, AND COAL  

E-Print Network (OSTI)

Chapter PA ASHLAND COALFIELD, POWDER RIVER BASIN, MONTANA: GEOLOGY, COAL QUALITY, AND COAL of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great

255

FORT UNION COAL IN THE GREATER GREEN RIVER BASIN, EAST FLANK OF THE ROCK SPRINGS UPLIFT,  

E-Print Network (OSTI)

Chapter GS FORT UNION COAL IN THE GREATER GREEN RIVER BASIN, EAST FLANK OF THE ROCK SPRINGS UPLIFT 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky in the toolbar to return. 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky

256

SHERIDAN COALFIELD, POWDER RIVER BASIN: GEOLOGY, COAL QUALITY, AND COAL RESOURCES  

E-Print Network (OSTI)

Chapter PH SHERIDAN COALFIELD, POWDER RIVER BASIN: GEOLOGY, COAL QUALITY, AND COAL RESOURCES By M assessment of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great

257

FORT UNION COAL IN THE POWDER RIVER BASIN, WYOMING AND MONTANA: A SYNTHESIS  

E-Print Network (OSTI)

Chapter PS FORT UNION COAL IN THE POWDER RIVER BASIN, WYOMING AND MONTANA: A SYNTHESIS By R of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great

258

COAL RESOURCES OF THE HANNA AND CARBON By M.S. Ellis,1  

E-Print Network (OSTI)

Chapter HN COAL RESOURCES OF THE HANNA AND CARBON BASINS By M.S. Ellis,1 G.L. Gunther,2 A.M. Ochs,2, Delaware 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky in the toolbar to return. 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky

259

Petroleum Geologic Characteristics of Suprasalt Strata in Block 15/06, Angola  

Science Conference Proceedings (OSTI)

Block 15/06 is located in the Angola deep sea, which belongs to Lower Congo basin. The primary source rock of the Block is the marine shale of Iabe and Landana formation of Upper Cretaceous & Lower Tertiary. The main reservior of supra-salt strata is ... Keywords: tertiary, suprasalt, source rock, salt dome, fault, accumulation model

Wang Lei, Shi Yanli, Fan Tailiang, Cai Xiyuan, Zhao Yan

2013-06-01T23:59:59.000Z

260

FERRIS AND HANNA COAL IN THE HANNA AND CARBON BASINS, WYOMING: A SYNTHESIS  

E-Print Network (OSTI)

Chapter HS FERRIS AND HANNA COAL IN THE HANNA AND CARBON BASINS, WYOMING: A SYNTHESIS By R of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

COLSTRIP COALFIELD, POWDER RIVER BASIN, MONTANA: GEOLOGY, COAL QUALITY, AND COAL  

E-Print Network (OSTI)

Chapter PC COLSTRIP COALFIELD, POWDER RIVER BASIN, MONTANA: GEOLOGY, COAL QUALITY, AND COAL 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky in the toolbar to return. 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky

262

COAL RESOURCES, GREATER GREEN RIVER BASIN By M.S. Ellis,1  

E-Print Network (OSTI)

Chapter GN COAL RESOURCES, GREATER GREEN RIVER BASIN By M.S. Ellis,1 G.L. Gunther,2 A.M. Ochs,2 J of Delaware, Newark, Delaware 1999 Resource assessment of selected Tertiary coal beds and zones here or on this symbol in the toolbar to return. 1999 Resource assessment of selected Tertiary coal

263

American Fusion News | Princeton Plasma Physics Lab  

NLE Websites -- All DOE Office Websites (Extended Search)

American Fusion News American Fusion News General Atomics (GA) December 4, 2012 The Scorpion's Strategy: "Catch and Subdue" December 4, 2012 Frozen Bullets Tame Unruly Edge Plasmas in Fusion Experiment February 15, 2012 General Atomics (GA) Fusion News: A New Spin on Understanding Plasma Confinement See All Massachusetts Institute of Technology (MIT) April 5, 2013 Applying physics, teamwork to fusion energy science February 22, 2013 A Tour of Plasma Physics in Downtown Cambridge December 4, 2012 Placing Fusion Power on a Pedestal September 21, 2012 MASSACHUSETTS INSTITUTUE OF TECHNOLOGY See All National Ignition Facility February 22, 2013 Summary of Assessment of Prospects for Inertial Fusion Energy February 16, 2012 National Ignition Facility (NIF): Under Pressure: Ramp-Compression Smashes

264

Windmills  

NLE Websites -- All DOE Office Websites (Extended Search)

Windmills Windmills Nature Bulletin No. 558-A March 15, 1975 Forest Preserve District of Cook County George W. Dunne, President Roland F. Eisenbeis, Supt. of Conservation WINDMILLS Two products of Yankee ingenuity -- barbed wire and the windmill -- played leading parts in the taming of the Wild West. Windmills made it possible to build the railroads and establish the ranches and farms which now occupy the Great Plains from Canada to Mexico. In that vast territory, once known as "The Great American Desert, " the annual rainfall is less than 20 inches -- frequently much less. Unless you have lived there, you cannot realize how terribly hot and dry that country becomes, nor how hard the winds may blow incessantly for days, weeks or even months. Windmills made it possible to pump, from veins far underground, water that was more precious than gold.

265

Theory Seminar Schedule  

NLE Websites -- All DOE Office Websites (Extended Search)

7-2008 7-2008 Click on a title to read an abstract, if available (underlined). 12 June 2008 Kristina Sviratcheva Louisiana State University kristina@rouge.phys.lsu.edu Symplectic Ab Initio No-Core Shell Model - Taming the Model Space Dilemma 5 June 2008 Wick Haxton INT, University of Washington haxton@u.washington.edu Probing Time-odd Moments in Atoms and Nuclei 1 May 2008 Wolfgang Bentz Tokai University, Japan bentz@keyaki.cc.u-tokai.ac.jp Fragmentation functions in an effective quark theory 17 April 2008 Special Time: 10:30am Dmitry G. Yakovlev Ioffe Physico-Technical Institute, St.Petersburg yak@astro.ioffe.rssi.ru Landau and Neutron Stars Tuesday 15 April 2008 Special Day Jochen Wambach GSI and TU Darmstadt J.Wambach@gsi.de Viscosity in the Nambu--Jona-Lasinio Model Tuesday 8 April 2008

266

MIT Plasma Science & Fusion Center: research, alcator, publications & news,  

NLE Websites -- All DOE Office Websites (Extended Search)

1st Annual Meeting of the APS Division of Plasma Physics, Atlanta, 2009 1st Annual Meeting of the APS Division of Plasma Physics, Atlanta, 2009 Invited Orals I. Cziegler Structures and Velocities of the Edge Turbulence in Alcator C-Mod M. Greenwald Verification and Validation for Magnetic Fusion: Moving Toward Predictive Capability J. Hughes Edge Pedestal and Confinement Regulation on Alcator C-Mod L. Lin Comparison of Experimental Measurements and Gyrokinetic Turbulent Electron Transport Models in Alcator C-Mod Plasmas M. Porkolab Taming Magnetically Confined Plasmas with RF Waves: a Historical Perspective S. Shiraiwa Plasma Wave Simulation Based on a Versatile FEM Solver on Alcator C-Mod D. Whyte Runaway Electron Transport & Disruption Mitigation Optimization on Alcator C-Mod Contributed Orals B. Bose Studies of Filament Formation during Lithium Pellet Injection in Alcator C-Mod

267

Turkeys  

NLE Websites -- All DOE Office Websites (Extended Search)

No. 619 November 26, 1960 No. 619 November 26, 1960 Forest Preserve District of Cook County Daniel Ryan, President Roberts Mann, Conservation Editor David H. Thompson, Senior Naturalist TURKEYS : WILD AND DOMESTICATED The story of the first Thanksgiving in 1621 and of the wild "Turkies" which the Pilgrims hunted to provide meat for the feast is familiar to every American. Today, although very few of us can claim that we had ancestors on the Mayflower, a lot of us imagine that our Thanksgiving bird is descended from those wild turkeys. This is not quite correct. A century before, in Mexico, the early Spanish adventurers had found Indians raising turkeys around their homes. The Aztec emperor, Montezuma, kept them in his famous zoo, it is said, as food for the other animals. It is not known how long those Mexican birds had been tamed and bred but they are the true ancestors of our only domestic animal with an origin in North America.

268

Abstract for Kristina D. Sviratcheva  

NLE Websites -- All DOE Office Websites (Extended Search)

Kristina D. Sviratcheva Kristina D. Sviratcheva Louisiana State University Symplectic Ab Initio No-Core Shell Model - Taming the Model Space Dilemma Understanding the origin, structure, and phases of hadronic matter is a forefront research area in physics. An integral part of this challenge is to achieve realistic modeling of the complex dynamics of atomic nuclei, which is key to comprehending the evolution of the universe from a fundamental quark-gluon level. We recently demonstrated the potential power of an innovative concept, the ab initio symplectic no-core shell model (Sp-NCSM), based on expanding the conventional harmonic oscillator basis in terms of the symmetry-adapted and physically relevant symplectic basis, to reach new domains of nuclear structure. Using realistic interactions tied

269

NREL: News Feature - OpenStudio Visualizes Energy Use in Buildings  

NLE Websites -- All DOE Office Websites (Extended Search)

OpenStudio Visualizes Energy Use in Buildings OpenStudio Visualizes Energy Use in Buildings March 8, 2011 Lo ok around you. Odds are, you are indoors reading this story using a computer or mobile device, perhaps sipping on a favorite cup of coffee. If you are indoors at this moment, you're draining energy from one of the largest consumers of energy in the U.S. - a building. Together, residential and commercial buildings account for a staggering 40 percent of energy use in the United States. However, the U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL) is developing a suite of tools to tame this energy beast - and it is free to anyone who wants to use it. Whether retrofitting existing buildings or designing new buildings, energy modeling is a core component to changing a building from an energy guzzler

270

Top ECMs for Labs and Data Centers  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Top ECMs for Labs and Top ECMs for Labs and Data Centers FUPWG Otto Van Geet, PE October 10, 2012 2 Labs are Energy Hogs! * 3 to 8 times as energy intensive as office buildings Total Site Energy Use Intensity BTU/sf-yr for various laboratories in the Labs21 Benchmarking Database Typical Office Building 3 * Core information resources - Design Guide - Case Studies - Energy Benchmarking - Best Practice Guides - Technical Bulletins * Design process tools - Env. Performance Criteria - Labs21 Process Manual Labs21 Toolkit 4 Six BIG HITS 1. Scrutinize the air changes: Optimize ventilation rates 2. Tame the hoods: Compare exhaust device options 3. Get real with loads: Right-size HVAC systems 4. Just say no to re-heat: Minimize simultaneous heating and cooling 5. Drop the pressure drop:

271

60 Years Since Nuclear Turned on the Lights | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

60 Years Since Nuclear Turned on the Lights 60 Years Since Nuclear Turned on the Lights 60 Years Since Nuclear Turned on the Lights December 20, 2011 - 10:50am Addthis Niketa Kumar Niketa Kumar Public Affairs Specialist, Office of Public Affairs "We have moved far to tame for peaceful uses the mighty forces unloosed when the atom was split." President Johnson, 1966 At 1:23pm on December 20, 1951, Argonne National Laboratory director Walter Zinn scribbled into his log book, "Electricity flows from atomic energy. Rough estimate indicates 45 kw." At that moment, scientists from Argonne and the National Reactor Testing Station, the forerunner to today's Idaho National Laboratory, watched four light bulbs glow, powered by the world's first nuclear reactor to generate electricity. Fifteen years later, in Arco, Idaho, President Johnson stood at this same

272

Transfer maps and nonexistence of joint determinant.  

E-Print Network (OSTI)

Transfer Maps, sometimes called norm maps, for Milnor's $K$-theory were first defined by Bass and Tate (1972) for simple extensions of fields via tame symbol and Weil's reciprocity law, but their functoriality had not been settled until Kato (1980). On the other hand, functorial transfer maps for the Goodwillie group are easily defined. We show that these natural transfer maps actually agree with the classical but difficult transfer maps by Bass and Tate. With this result, we build an isomorphism from the Goodwillie groups to Milnor's $K$-groups of fields, which in turn provides a description of joint determinants for the commuting invertible matrices. In particular, we explicitly determine certain joint determinants for the commuting invertible matrices over a finite field, the field of rational numbers, real numbers and complex numbers into the respective group of units of given field.

Sung Myung

273

High-loop perturbative renormalization constants for Lattice QCD (II): three-loop quark currents for tree-level Symanzik improved gauge action and n_f=2 Wilson fermions  

E-Print Network (OSTI)

Numerical Stochastic Perturbation Theory was able to get three- (and even four-) loop results for finite Lattice QCD renormalization constants. More recently, a conceptual and technical framework has been devised to tame finite size effects, which had been reported to be significant for (logarithmically) divergent renormalization constants. In this work we present three-loop results for fermion bilinears in the Lattice QCD regularization defined by tree-level Symanzik improved gauge action and n_f=2 Wilson fermions. We discuss both finite and divergent renormalization constants in the RI'-MOM scheme. Since renormalization conditions are defined in the chiral limit, our results also apply to Twisted Mass QCD, for which non-perturbative computations of the same quantities are available. We emphasize the importance of carefully accounting for both finite lattice space and finite volume effects. In our opinion the latter have in general not attracted the attention they would deserve.

Brambilla, Michele

2013-01-01T23:59:59.000Z

274

Diffraction at HERA  

E-Print Network (OSTI)

Between 1992 and 2007, the HERA accelerator provided $ep$ collisions at center of mass energies beyond $300 \\ {\\rm GeV}$ at the interaction points of the H1 and ZEUS experiments. Interesting results to emerge relate to the newly accessed field of perturbative strong interaction physics at low Bjorken-$x$, where parton densities become extremely large. Questions arise as to how and where non-linear dynamics tame the parton density growth and challenging features such as geometric scaling are observed. Central to this low $x$ physics landscape is a high rate of diffractive processes, in which a colorless exchange takes place and the proton remains intact. A review is given for main results obtained by H1 and ZEUS experiments in this field.

Schoeffel, Laurent

2011-01-01T23:59:59.000Z

275

Fuel property effects on engine combustion processes. Final report  

DOE Green Energy (OSTI)

A major obstacle to improving spark ignition engine efficiency is the limitations on compression ratio imposed by tendency of hydrocarbon fuels to knock (autoignite). A research program investigated the knock problem in spark ignition engines. Objective was to understand low and intermediate temperature chemistry of combustion processes relevant to autoignition and knock and to determine fuel property effects. Experiments were conducted in an optically and physically accessible research engine, static reactor, and an atmospheric pressure flow reactor (APFR). Chemical kinetic models were developed for prediction of species evolution and autoignition behavior. The work provided insight into low and intermediate temperature chemistry prior to autoignition of n-butane, iso-butane, n-pentane, 1-pentene, n-heptane, iso-octane and some binary blends. Study of effects of ethers (MTBE, ETBE, TAME and DIPE ) and alcohols (methanol and ethanol) on the oxidation and autoignition of primary reference fuel (PRF) blends.

Cernansky, N.P.; Miller, D.L.

1995-04-27T23:59:59.000Z

276

IMPACT OF OXYGENATED FUEL ON DIESEL ENGINE PERFORMANCE AND EMISSIONS  

DOE Green Energy (OSTI)

As evidenced by recent lawsuits brought against operators of large diesel truck fleets [1] and by the Consent Decree brought against the heavy-duty diesel manufacturers [2], the environmental and health effects of diesel engine emissions continue to be a significant concern. Reduction of diesel engine emissions has traditionally been achieved through a combination of fuel system, combustion chamber, and engine control modifications [3]. Catalytic aftertreatment has become common on modern diesel vehicles, with the predominant device being the diesel oxidation catalytic converter [3]. To enable advanced after-treatment devices and to directly reduce emissions, significant recent interest has focused on reformulation of diesel fuel, particularly the reduction of sulfur content. The EPA has man-dated that diesel fuel will have only 15 ppm sulfur content by 2007, with current diesel specifications requiring around 300 ppm [4]. Reduction of sulfur will permit sulfur-sensitive aftertreatment devices, continuously regenerating particulate traps, NOx control catalysts, and plasma assisted catalysts to be implemented on diesel vehicles [4]. Another method of reformulating diesel fuel to reduce emissions is to incorporate oxygen in the fuel, as was done in the reformulation of gasoline. The use of methyl tertiary butyl ether (MTBE) in reformulated gasoline has resulted in contamination of water resources across the country [5]. Nonetheless, by relying on the lessons learned from MTBE, oxygenation of diesel fuel may be accomplished without compromising water quality. Oxygenation of diesel fuel offers the possibility of reducing particulate matter emissions significantly, even for the current fleet of diesel vehicles. The mechanism by which oxygen content leads to particulate matter reductions is still under debate, but recent evidence shows clearly that ''smokeless'' engine operation is possible when the oxygen content of diesel fuel reaches roughly 38% by weight [6]. The potential improvements in energy efficiency within the transportation section, particularly in sport utility vehicles and light-duty trucks, that can be provided by deployment of diesel engines in passenger cars and trucks is a strong incentive to develop cleaner burning diesel engines and cleaner burning fuels for diesel engines. Thus, serious consideration of oxygenated diesel fuels is of significant practical interest and value to society. In the present work, a diesel fuel reformulating agent, CETANERTM, has been examined in a popular light-medium duty turbodiesel engine over a range of blending ratios. This additive is a mixture of glycol ethers and can be produced from dimethyl ether, which itself can be manufactured from synthesis gas using Air Products' Liquid Phase Dimethyl Ether (LPDME TM) technology. CETANERTM is a liquid, has an oxygen content of 36 wt.%, has a cetane number over 100 and is highly miscible in diesel fuel. This combination of physical and chemical properties makes CETANERTM an attractive agent for oxygenating diesel fuel. The present study considered CETANERTM ratios from 0 to 40 wt.% in a California Air Resources Board (CARB) specification diesel fuel. Particulate matter emissions, gaseous emissions and in-cylinder pressure traces were monitored over the AVL 8-Mode engine test protocol [7]. This paper presents the results from these measurements and discusses the implications of using high cetane number oxygenates in diesel fuel reformulation.

Boehman, Andre L.

2000-08-20T23:59:59.000Z

277

Better Methods for Predicting Lifetimes of Seal Materials  

Science Conference Proceedings (OSTI)

We have been working for many years to develop better methods for predicting the lifetimes of polymer materials. Because of the recent interest in extending the lifetimes of nuclear weapons and the importance of environmental seals (o-rings, gaskets) for protecting weapon interiors against oxygen and water vapor, we have recently turned our attention to seal materials. Perhaps the most important environmental o-ring material is butyl rubber, used in various military applications. Although it is the optimum choice from a water permeability perspective, butyl can be marginal from an aging point-of-view. The purpose of the present work was to derive better methods for predicting seal lifetimes and applying these methods to an important butyl material, Parker compound B6 12-70.

Celina, M.; Gillen, K.T.; Keenan, M.R.

1999-03-16T23:59:59.000Z

278

Tenth oil recovery conference  

SciTech Connect

The Tertiary Oil Recovery Project is sponsored by the State of Kansas to introduce Kansas producers to the economic potential of enhanced recovery methods for Kansas fields. Specific objectives include estimation of the state-wide tertiary oil resource, identification and evaluation of the most applicable processes, dissemination of technical information to producers, occasional collaboration on recovery projects, laboratory studies on Kansas applicable processes, and training of students and operators in tertiary oil recovery methods. Papers have been processed separately for inclusion on the data base.

Sleeper, R. (ed.)

1993-01-01T23:59:59.000Z

279

EVALUATION OF GLOVEBOX GLOVES FOR EFFECTIVE PERMEATION CONTROL  

DOE Green Energy (OSTI)

A research and development task was undertaken to determine the permeabilities of hydrogen and dry air through different polymeric glove materials that are used to maintain the integrity of glovebox secondary containment. Fifteen different glove samples were obtained from four different manufacturers and samples cut from these gloves were tested. The gloves included baseline butyl rubber, Viton{reg_sign}, Dupont{reg_sign} Hypalon{reg_sign}, polyurethane, as well as composite gloves. The testing indicated that all of the vendor's butyl rubber gloves and the Jung Viton{reg_sign} gloves performed comparably in both gases.

Korinko, P.

2012-02-29T23:59:59.000Z

280

Radioisotope Thermoelectric Generator Package O-Ring Seal Material Validation Testing  

DOE Green Energy (OSTI)

The Radioisotope Thermoelectric Generator Package O-Ring Seal Material Validation Test was conducted to validate the use of the Butyl material as a primary seal throughout the required temperature range. Three tests were performed at (1) 233 K ({minus}40 {degrees}F), (2) a specified operating temperature, and (3) 244 K ({minus}20 {degrees}F) before returning to room temperature. Helium leak tests were performed at each test point to determine seal performance. The two major test objectives were to establish that butyl rubber material would maintain its integrity under various conditions and within specified parameters and to evaluate changes in material properties.

Adkins, H.E.; Ferrell, P.C.; Knight, R.C.

1994-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

The Structure of Rene' 88DT  

Science Conference Proceedings (OSTI)

etching for 3 to 5 seconds at 5 volts, in the same cycle, electrolyte and temperature. .... solvus for tertiary of y ' exists at this combination of time and temperature.

282

NETL F 451.1/1-1, Categorical Exclusion Designation Form  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Changing Technology of Polymeric-Surfactants for Tertiary Oil Sample collection of crude oil and brine water samples (sample size: 200 ml each) for producing oil wells. Gary L....

283

Re^Os evidence for replacement of ancient mantle lithosphere beneath the North China craton  

E-Print Network (OSTI)

^Os data for peridotite xenoliths carried in Paleozoic kimberlites and Tertiary alkali basalts confirm, coupled with the presence of cold, refractory mantle xenoliths carried in kimberlite pipes that erupt

Mcdonough, William F.

284

F. Groeschel On behalf of the IFMIF-EVEDA Project Team  

E-Print Network (OSTI)

concept (2003) Quench Tank Deuteron Beams EM Pump HX(Li / Organic Oil) Dump Tank HX(Organic Oil / Water/10" Operating temperature 250-350C Heat to be removed 10 MW Secondary cooling oil Tertiary cooling water

McDonald, Kirk

285

Alternate Methods in Reservoir Simulation  

Science Conference Proceedings (OSTI)

As time progresses, more and more oil fields and reservoirs are reaching maturity; consequently, secondary and tertiary methods of oil recovery have become increasingly important in the petroleum industry. This significance has added to the industry's ...

Guadalupe I. Janoski; Andrew H. Sung

2001-05-01T23:59:59.000Z

286

Abstract--Telerehabilitation is the provision of rehabilitation services at a distance, by a therapist at a remote location.  

E-Print Network (OSTI)

by therapists at a remote location. Telerehabilitation can be clinic- based or home-based (see Rosen [1) clinic is being coached by a therapist expert at a tertiary care (or university) setting. For home-based

New Jersey, University of Medicine and Dentistry of

287

Stabilizers for oil slurries of carbonaceous material  

SciTech Connect

Slurries of carbonaceous material in oil, particularly coal, are stabilized with particular tertiary amines. An example is tallow amine first condensed with two moles of propylene oxide and then condensed with thirteen moles of ethylene oxide.

Schick, M. J.

1985-01-08T23:59:59.000Z

288

AOCS Official Method Tf 2b-64  

Science Conference Proceedings (OSTI)

Primary, Secondary and Tertiary Amine Values of Fatty Amines, Indicator Method AOCS Official Method Tf 2b-64 Methods Downloads Methods Downloads DEFINITION The primary amine value is the mg of potassium hydroxide

289

AOCS Official Method Tf 2a-64  

Science Conference Proceedings (OSTI)

Primary, Secondary, and Tertiary Amine Values of Fatty Amines, Potentiometric Method AOCS Official Method Tf 2a-64 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION ...

290

Deformation, erosion and sedimentation in collisional orogens : case studies from eastern Tibet and southwestern China  

E-Print Network (OSTI)

This dissertation addresses aspects of the tectonics of regions adjacent to the eastern Himalayan syntaxis. The first chapter describes the Tertiary Gonjo basin, includes structural and sedimentologic observations, and ...

Studnicki-Gizbert, Christopher Terrance

2006-01-01T23:59:59.000Z

291

FERMILAB-TM-XXXX-DO  

NLE Websites -- All DOE Office Websites (Extended Search)

T-979 Ultra-Fast Timing T-977 MINERA Experiment Detector Calibration T-953 U. Iowa Cerenkov Light Tests T-932 Diamond Detector 27 Developing a New Tertiary Low-Energy Beamline...

292

NERSC Users Group Meeting January 28-29, 1997 Presentations  

NLE Websites -- All DOE Office Websites (Extended Search)

Harvard Holmes | Download File: Tertiary-Storage.pdf | pdf | 173 KB Report on Graphics Packages January 28, 1997 | Author(s): Steve Lau | URL: http:www.nersc.govabout...

293

C-H functionalisation through singlet chlorocarbenes insertions – MP2 and DFT investigations  

Science Conference Proceedings (OSTI)

The insertion reactions of singlet mono and dichlorocarbenes (1CHCl and 1CCl2) into primary, secondary and tertiary C-H bonds of methane, ethane, propane, n-butane and iso-butane have been investigated at ...

M. Ramalingam; K. Ramasami; P. Venuvanalingam; V. Sethuraman

2006-05-01T23:59:59.000Z

294

Experimental development of a chemical flood and the geochemistry of novel alkalis.  

E-Print Network (OSTI)

??Surfactant-Polymer (SP) and Alkaline-Surfactant-Polymer (ASP) floods are tertiary oil recovery processes that mobilize residual oil to waterflood. These Chemical EOR processes are most valuable when… (more)

Winters, Matthew Howard

2012-01-01T23:59:59.000Z

295

A recoverable versatile photo-polymerization initiator catalyst  

E-Print Network (OSTI)

A photo-polymerization initiator based on an imidazolium and an oxometalate, viz., (BMIm)2(DMIm) PW12O40 (where, BMIm = 1-butyl-3-methylimizodium, DMIm = 3,3'-Dimethyl-1,1'-Diimidazolium) is reported. It polymerizes several industrially important monomers and is recoverable hence can be reused. The Mn and PDI are controlled and a reaction pathway is proposed.

Chen, Dianyu; Roy, Soumyajit

2012-01-01T23:59:59.000Z

296

Lithium Diisopropylamide-Mediated Ortholithiations: Lithium Chloride Catalysis  

E-Print Network (OSTI)

Lithium Diisopropylamide-Mediated Ortholithiations: Lithium Chloride Catalysis Lekha Gupta, 2008 Ortholithiations of a range of arenes mediated by lithium diisopropylamide (LDA) in THF at -78 °C protocols with unpurified commercial samples of n-butyl- lithium to prepare LDA or commercially available

Collum, David B.

297

Development of Supported Polymeric Liquid Membrane Technology for Aqueous MTBE Mitigation  

Science Conference Proceedings (OSTI)

The use of MTBE (methyl tert-butyl ether) as a gasoline additive has generated a serious, widespread groundwater contamination problem in California. This study evaluated the use of supported polymeric liquid membrane technology in the remediation of MTBE contaminated groundwater.

2002-07-02T23:59:59.000Z

298

DIMENSIONS of DISCOVERY Sponsored Program Awards  

E-Print Network (OSTI)

, batteries, electro- magnetic shielding materials, artificial noses and muscles, solar cells, electrodes). The treatment of thiophene with butyl lithium provides 2,5-dilithiothiophene that can be polymerized with CuCl2 me- tallation of 15 with lithium diisopropylamide (LDA)[79,80] to generate 16. The organolithium

Ginzel, Matthew

299

Center for Energy Efficiency and Renewable Energy BBuuiillddiinngg EEnneerrggyy EEffffiicciieennccyy PPrrooggrraamm  

E-Print Network (OSTI)

Governor's Dr. Amherst, MA 01003-9265 PRELIMINARY REPORT Computer Modeling of Heat Transfer and Comparison The product selected for testing is a nominal 80'x80' aluminum horizontal sliding window. Thermo physical locations for a sill section is shown in Fig. 1. Glazing System EPDM Butyl Rubber Radiation Enclosure

Massachusetts at Amherst, University of

300

d'Ordre : D. U. 2255 Universit Blaise Pascal  

E-Print Network (OSTI)

-clayey in the upper horizons with increasing sand content with depth; they become coarse-textured with greater depth (>1 m: sand and gravel). More details on the study site are given else- where (Sanchez-Perez et al to a 150 ml gas tight glass jar equipped with a butyl rubber stopper. The experi- ment was started

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Studies on the Extraction of Phenol from the Wastewater of Multi-generation System  

Science Conference Proceedings (OSTI)

Recovery of phenol from the wastewater produced in the multi-cogeneration system has been studied. Based on the experimental results and theoretical analysis, butyl acetate was selected as the extractant and 99.95% of the volatile phenols in the wastewater ... Keywords: phenol, solvent extraction, wastewater, multigeneration system, recycle

Zhenjing Shi; Mengxiang Fang; Chunguang Zhou; Qinghui Wang; Zhongyang Luo

2011-02-01T23:59:59.000Z

302

Fatigue Crack Initiation in Nickel-Based Superalloy René 88 DT at ...  

Science Conference Proceedings (OSTI)

9% distilled water and 13% butyl cellosolve under conditions of. -35°C, 20V and ... The ultrasonic fatigue stress-life curve for René 88 DT at 593?C is shown in Figure 4 ... 600MPa. Figure 4. S-N data of Rene 88 DT at 593?C (Arrows indicate.

303

The Bobwhite Quail  

NLE Websites -- All DOE Office Websites (Extended Search)

Bobwhite Quail Bobwhite Quail Nature Bulletin No. 232-A May 28, 1966 Forest Preserve District of Cook County Seymour Simon, President Roland F. Eisenbeis, Supt. of Conservation THE BOBWHITE QUAIL While plowing on a May morning many years ago, my father saw a crow, passing overhead, drop something white from its beak. Before the crow could retrieve it, he shouted and ran to pick up -- an egg, unbroken on the soft newly turned soil. Suspecting that it was a quail's egg, he wrapped it in his handkerchief and, at noon, had mother place it with the incubating eggs under a "setting" hen. A few days later, out popped a damp chick scarcely larger than a bumblebee. Within a few hours its downy feathers had fluffed out into fine brown fuzz, with a dark streak down its back, and it was scampering about in a shoe box in the warm kitchen. Fed bits of egg yolk, meal, live crickets and flies, that baby quail soon became very tame and would creep inside the cuff of a sleeve or nestle under a cupped hand. After a week or two it had well- developed wing feathers and was trying to fly.

304

MHK Technologies/Savanious Turbine | Open Energy Information  

Open Energy Info (EERE)

Savanious Turbine Savanious Turbine < MHK Technologies Jump to: navigation, search << Return to the MHK database homepage Savanious Turbine.jpg Technology Profile Primary Organization Rugged Renewables EMAT Inc Technology Resource Click here Current Technology Type Click here Axial Flow Turbine Technology Readiness Level Click here TRL 4 Proof of Concept Technology Description The large blade area of the Savonious Turbine allows for low blade loading which eases the mechanical design The low speed in relation to flow speed ensures minimal environmental disturbance The output characteristic is peaked with a maximum free running speed at a tip speed ratio of about 1 5 Hence a runaway Savonius freewheeling in a fast flow current is quite tame and over speed protection is not required Since the turbine is unidirectional it does not require an alignment system The turbine is capable of extracting energy from flow which is fluctuating rapidly in speed and direction The swept area is rectangular in shape fitting it for applications unsuitable for propeller turbines

305

Pet House Sparrow  

NLE Websites -- All DOE Office Websites (Extended Search)

Pet House Sparrow Pet House Sparrow Name: mary Location: N/A Country: N/A Date: N/A Question: I found a Baby House Sparrow and raised it. This Sparrow is a female and is about 5 months old and very tame. We are keeping this bird as a pet. We are interested in possibly breeding this bird and was wondering if you can mix breed the House Sparrow with a Finch or type of Sparrow that you could purchase at a pet store? What is the life expectancy of the House Sparrow? Replies: In the wild most small birds only live a year or two; well cared for in captivity they might be able to make it twice that long, but don't count on it. There are some records of exceptional life lengths for some species of small birds, 8 or 10 years, but I haven't heard of any for house sparrows. I don't think you would be able to cross breed house sparrows with any of the others, but I couldn't say for sure. Hybridization normally occurs only between very closely related species; I don't know enough about genetics.

306

Farm Ponds  

NLE Websites -- All DOE Office Websites (Extended Search)

Farm Ponds Farm Ponds Nature Bulletin No. 410-A March 13, 1971 Forest Preserve District of Cook County George W. Dunne, President Roland F. Eisenbeis, Supt. of Conservation FARM PONDS Since colonial times, farmers have been scooping out reservoirs or damming small watercourses to impound water for their livestock or satisfy a hankering for a private fishing hole. Such a pond was usually too shallow and was rarely fenced. In hot weather, cattle stood belly- deep in the water and hogs wallowed in the shallows. The shores were trampled bare of vegetation. It served as a swimming place for a flock of tame ducks and the youngsters of the family but, other than bullheads, a few fish could live in it. In most cases the dam was made of earth dug with a team and "slip scraper" to deepen the hole, without a proper spillway for the overflow during heavy rains. As a result, or because of holes tunneled through them by muskrats and crawfish, these dams eventually washed out. A number of them in our Palos preserves, built by early settlers, have been enlarged, provided with adequate spillways, and serve as harbors for fish and wildlife.

307

Transformational Technologies to Expedite Space Access and Development  

Science Conference Proceedings (OSTI)

Throughout history the emergence of new technologies has enabled unforeseen breakthrough capabilities that rapidly transformed the world. Some global examples from the twentieth century include AC electric power, nuclear energy, and turbojet engines. At the systems level, success of both Apollo and the Space Shuttle programs depended upon taming hydrogen propulsion and developing high-temperature atmospheric reentry materials. Human space development now is stymied because of a great need for breakthrough technologies and strategies. It is believed that new capabilities exist within the present states-of-the-art of superconducting technology that can be implemented to transform the future of human space development. This paper is an overview of three other papers presented within this forum, which summarizes the principles and consequences of StarTram, showing how the resulting breakthrough advantages can lead directly to safe space tourism and massive development of the moon, Mars and the outer solar system. StarTram can implement cost-effective solar power from space, simple utilization of asteroid material to protect humans from ionizing radiation, and effective defense of the Earth from devastating cosmic impacts. Synergistically, StarTram technologies will revolutionize ground transportation on the Earth, leading to enormous reduction in energy consumption and creation of millions of jobs. High energy lasers will also be discussed because of their importance to power beaming applications.

Rather, John D. G. [Rather Creative Innovations Group, Inc., 102 Windsong Lane, Oak Ridge, TN (United States)

2010-01-28T23:59:59.000Z

308

Multiphase Nano-Composite Coatings for Achieving Energy Optimization  

SciTech Connect

UES Inc. and ANL teamed in this work to develop novel coating systems for the protection of surfaces from thermal degradation mainly in two applications; Machining and Die casting. These coatings were specifically designed for the purpose by incorporating required material phases and the overall architecture, which led to reduce the energy usage and increase efficiency of the operations. Following the UES/ANL'Â?s feasibility work, the coatings were developed utilizing High power impulse magnetron sputtering (HiPMS) and Large area filtered arc deposition (LAFAD) techniques. Toughness, hardness and oxidation resistance: contrasting qualities have been mixed in the right proportion to attain the suitable material characteristic for the cause. Hafnium diboride (HfB2) based materials provided such a system and its properties were tamed to attain the right combination of toughness and hardness by working on the microstructure and architecture of coatings. An effective interfacing material (graded concentrations of topcoat) was also achieved in this work to provide the required adhesion between the substrate and the coating. Combination of an appropriate bond coat and a functional top coat provided the present thermal degradation resistant coating for cutting tools and die-casting applications. Laboratory level performance tests and industrial level application tests by partner companies (Beta Site Testing) were used for the development of these coatings.

Dr. Jose Nainaparampil

2012-03-26T23:59:59.000Z

309

Designer organisms for photosynthetic production of ethanol from carbon dioxide and water  

DOE Patents (OSTI)

The present invention provides a revolutionary photosynthetic ethanol production technology based on designer transgenic plants, algae, or plant cells. The designer plants, designer algae, and designer plant cells are created such that the endogenous photosynthesis regulation mechanism is tamed, and the reducing power (NADPH) and energy (ATP) acquired from the photosynthetic water splitting and proton gradient-coupled electron transport process are used for immediate synthesis of ethanol (CH.sub.3CH.sub.2OH) directly from carbon dioxide (CO.sub.2) and water (H.sub.2O). The ethanol production methods of the present invention completely eliminate the problem of recalcitrant lignocellulosics by bypassing the bottleneck problem of the biomass technology. The photosynthetic ethanol-production technology of the present invention is expected to have a much higher solar-to-ethanol energy-conversion efficiency than the current technology and could also help protect the Earth's environment from the dangerous accumulation of CO.sub.2 in the atmosphere.

Lee, James Weifu (Knoxville, TN)

2011-07-05T23:59:59.000Z

310

Flow-Assisted Alkaline Battery: Low-Cost Grid-Scale Electrical Storage using a Flow-Assisted Rechargeable Zinc-Manganese Dioxide Battery  

SciTech Connect

GRIDS Project: Traditional consumer-grade disposable batteries are made of Zinc and Manganese, 2 inexpensive, abundant, and non-toxic metals. But these disposable batteries can only be used once. If they are recharged, the Zinc in the battery develops filaments called dendrites that grow haphazardly and disrupt battery performance, while the Manganese quickly loses its ability to store energy. CUNY Energy Institute is working to tame dendrite formation and to enhance the lifetime of Manganese in order to create a long-lasting, fully rechargeable battery for grid-scale energy storage. CUNY Energy Institute is also working to reduce dendrite formation by pumping fluid through the battery, enabling researchers to fix the dendrites as they’re forming. The team has already tested its Zinc battery through 3,000 recharge cycles (and counting). CUNY Energy Institute aims to demonstrate a better cycle life than lithium-ion batteries, which can be up to 20 times more expensive than Zinc-based batteries.

2010-09-15T23:59:59.000Z

311

Designer organisms for photosynthetic production of ethanol from carbon dioxide and water  

SciTech Connect

The present invention provides a revolutionary photosynthetic ethanol production technology based on designer transgenic plants, algae, or plant cells. The designer plants, designer algae, and designer plant cells are created such that the endogenous photosynthesis regulation mechanism is tamed, and the reducing power (NADPH) and energy (ATP) acquired from the photosynthetic water splitting and proton gradient-coupled electron transport process are used for immediate synthesis of ethanol (CH.sub.3CH.sub.2OH) directly from carbon dioxide (CO.sub.2) and water (H.sub.2O). The ethanol production methods of the present invention completely eliminate the problem of recalcitrant lignocellulosics by bypassing the bottleneck problem of the biomass technology. The photosynthetic ethanol-production technology of the present invention is expected to have a much higher solar-to-ethanol energy-conversion efficiency than the current technology and could also help protect the Earth's environment from the dangerous accumulation of CO.sub.2 in the atmosphere.

Lee, James Weifu (Knoxville, TN)

2011-07-05T23:59:59.000Z

312

Multiple slug scaling of linear and pattern laboratory chemical floods  

SciTech Connect

Linear floods were conducted in a synthetic water-wet matrix. The multiple slug scaling approach used oil saturation distributions measured by microwave attenuation in one laboratory flood to predict accurately the tertiary residual oil saturation and tertiary oil breakthrough in another laboratory linear flood run with larger slug sizes. Oil saturation distributions at 0.11 V/V/sub p/ intervals during the flood, as well as at S/sub orc/, were also accurately predicted. A laboratory quarter five-spot pattern flood involving sequential injection of a small surfactant slug, a small polymer slug, and continuous drive water was run in a water-wet synthetic matrix. Linear flood oil saturation distributions were scaled to predict the oil saturation distributions in the pattern using a fixed twelve streamtube model for the flow. Details of this scaling procedure are given. Residual tertiary oil saturation, tertiary recovery, and oil saturation changes with time were predicted to within the experimental errors involved in the procedures. The observed tertiary oil breakthrough was later than predicted. Observed oil saturation distributions tended to show more oil left in the corners of the model than predicted by the scaling theory. These secondary effects and the overall behavior of the pattern flood are considered in terms of the chosen streamtube network and the assumptions of stable unit mobility flow. (JMT)

Haskin, H.K.; Davis, L.A.

1982-01-01T23:59:59.000Z

313

Conceptual Model At Raft River Geothermal Area (2011) | Open Energy  

Open Energy Info (EERE)

2011) 2011) Exploration Activity Details Location Raft River Geothermal Area Exploration Technique Conceptual Model Activity Date 2011 Usefulness not indicated DOE-funding Unknown Exploration Basis Explore for development of an EGS demonstration project Notes The reservoir is developed in fractured Proterozoic schist and quartzite, and Archean quartz monzonite cut by younger diabase intrusions. The basement complex was deformed during the mid Tertiary and covered by approximately 5000 ft of late Tertiary sedimentary and volcanic deposits. Listric normal faults of Cenozoic age disrupt the Tertiary deposits but do not offset the basement rocks. RRG-9, the target well, was drilled southwest of the main well field to a measured depth (MD) of 6089 ft. The well is deviated to the west and cased to a depth of 2316 ft MD. It

314

Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

7 results: 7 results: BibTex RIS RTF XML Sort by: Author Title Type [ Year (Desc) ] Filters: Author is Elton J. Cairns [Clear All Filters] 2008 Shin, Joon Ho, Pratyay Basak, John B. Kerr, and Elton J. Cairns. "Rechargeable Li/LiFePO4 Cells Using N-Methyl-N-butyl pyrrolidinium Bis(trifluoromethane sulfonyl)imide-LiTFSI Electrolyte Incorporating Polymer Additives." Electrochimica Acta 54, no. 2 (2008): 410-414. Shin, Joon Ho, and Elton J. Cairns. "N-Methyl-(n-butyl)pyrrolidinium bis(trifluoromethanesulfonyl)imide-LiTFSI-poly(ethylene glycol) dimethyl ether mixture as a Li/S cell electrolyte." Journal of Power Sources 177 (2008): 537-545. 2007 Nakahara, Kentaro, Jiro Iriyama, Shigeyuki Iwasa, Masahiro Suguro, Masaharu Satoh, and Elton J. Cairns. "Al-laminated film packaged organic radical

315

Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

3 results: 3 results: BibTex RIS RTF XML Sort by: Author Title Type [ Year (Desc) ] Filters: Author is Joon Ho Shin [Clear All Filters] 2008 Shin, Joon Ho, Pratyay Basak, John B. Kerr, and Elton J. Cairns. "Rechargeable Li/LiFePO4 Cells Using N-Methyl-N-butyl pyrrolidinium Bis(trifluoromethane sulfonyl)imide-LiTFSI Electrolyte Incorporating Polymer Additives." Electrochimica Acta 54, no. 2 (2008): 410-414. Saint, Juliette A., Adam S. Best, Anthony F. Hollenkamp, Joon Ho Shin, and Marca M. Doeff. "Compatibility of Lix TiyMn1-y02 (y=0,0.11) electrode materials with pyrrolidinium-based ionic liquid electrolyte systems." Journal of The Electrochemical Society 155, no. 2 (2008): A172-A180. Shin, Joon Ho, and Elton J. Cairns. "N-Methyl-(n-butyl)pyrrolidinium

316

Physical Properties of Ionic Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

Physical Properties of Ionic Liquids Consisting of the Physical Properties of Ionic Liquids Consisting of the 1-Butyl-3-Methylimidazolium Cation with Various Anions and the Bis(trifluoromethylsulfonyl)imide Anion with Various Cations Hui Jin, Bernie O'Hare, Jing Dong, Sergei Arzhantsev, Gary A. Baker, James F. Wishart, Alan J. Benesi, and Mark Maroncelli J. Phys. Chem. B 112, 81-92 (2008). [Find paper at ACS Publications] Abstract: Physical properties of 4 room-temperature ionic liquids consisting of the 1-butyl-3-methylimidazolium cation with various perfluorinated anions and the bis(trifluoromethylsulfonyl)imide (Tf2N-) anion with 12 pyrrolidinium-, ammonium-, and hydroxyl-containing cations are reported. Electronic structure methods are used to calculate properties related to the size, shape, and dipole moment of individual ions. Experimental measurements of

317

Recombination of Photogenerated Lophyl Radicals in Imidazolium-Based ILs  

NLE Websites -- All DOE Office Websites (Extended Search)

Recombination of Photogenerated Lophyl Radicals in Imidazolium-Based Ionic Recombination of Photogenerated Lophyl Radicals in Imidazolium-Based Ionic Liquids V. Strehmel, J. F. Wishart, D. E. Polyansky and B. Strehmel ChemPhysChem 10, 3112-3118 (2009). [Find paper at Wiley] Abstract: Laser flash photolysis is applied to study the recombination reaction of lophyl radicals in ionic liquids in comparison with dimethylsulfoxide as an example of a traditional organic solvent. The latter exhibits a similar micropolarity as the ionic liquids. The ionic liquids investigated are 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (1), 1-hexyl-3-methylimidazolium hexafluorophosphate (2), and 1-butyl-3-methylimidazolium tetafluoroborate (3). The recombination of the photolytic generated lophyl radicals occur significantly faster in the ionic liquids than expected from their

318

New concept for coal wettability evaluation and modulation. Technical progress report, October 1, 1993--December 31, 1993  

SciTech Connect

This project is concerned concept for coal surface wettability evaluation and modulation. The objective of the work are to study the fundamental surface chemistry feature about the evaluation of the surface of coal, pyrite and coal pyrite, and also establish a new separation strategy which could contribute to the advanced coal cleaning for premium fuel application. In this quarter, the capillary rise of three coals, colorado mineral pyrite, and coal pyrite in butanol, pentanol, and butyl ether have been tested. The test results shown that the kinetic wettability of the five samples in the alcohol homolog are dependent on the carbon chain length, as the length of the carbon chain is shorter, the surface wettability is the better. Another test results shown that the kinetic wettability of coals are better than mineral pyrite and coal pyrite in the butyl ether.

Hu, Weibai

1993-12-31T23:59:59.000Z

319

Bulk Gold-Catalyzed Reactions of Isocyanides, Amines, and Amine N-Oxides  

Science Conference Proceedings (OSTI)

Bulk gold powder (5–50 ?m particles) catalyzes the reactions of isocyanides with amines and amine N-oxides to produce ureas. The reaction of n-butyl isocyanide (nBu–N?C) with di-n-propylamine and N-methylmorpholine N-oxide in acetonitrile, which was studied in the greatest detail, produced 3-butyl-1,1-dipropylurea (O?C(NHnBu)(NnPr2)) in 99% yield at 60 °C within 2 h. Sterically and electronically different isocyanides, amines, and amine N-oxides react successfully under these conditions. Detailed studies support a two-step mechanism that involves a gold-catalyzed reaction of adsorbed isocyanide with the amine N-oxide to form an isocyanate (RN?C?O), which rapidly reacts with the amine to give the urea product. These investigations show that bulk gold, despite its reputation for poor catalytic activity, is capable of catalyzing these reactions.

Klobukowski, Erik; Angelici, Robert; Woo, Keith L.

2012-01-26T23:59:59.000Z

320

Composition and method for encapsulating photovoltaic devices  

DOE Patents (OSTI)

A composition and method for encapsulating a photovoltaic device which minimizes discoloration of the encapsulant. The composition includes an ethylene-vinyl acetate encapsulant, a curing agent, an optional ultraviolet light stabilizer, and/or an optional antioxidant. The curing agent is preferably 1,1-di-(t-butylperoxy)-3,3,5-trimethylcyclohexane; the ultraviolet light stabilizer is bis-(N-octyloxy-tetramethyl) piperidinyl sebacate and the antioxidant is selected from the group consisting of tris (2,4-di-tert-butylphenyl) phosphite, tetrakis methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate) methane, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, and 2,2'-ethylidene bis(4,6-di-t-butylphenyl) fluorophosponite. The composition is applied to a solar cell then cured. The cured product contains a minimal concentration of curing-generated chromophores and resists UV-induced degradation.

Pern, Fu-Jann (Golden, CO)

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

RECOVERY OF URANIUM VALUES  

DOE Patents (OSTI)

A liquid-liquid extraction method is presented for recovering uranium values from an aqueous acidic solution by means of certain high molecular weight amine in the amine classes of primary, secondary, heterocyclic secondary, tertiary, or heterocyclic tertiary. The uranium bearing aqueous acidic solution is contacted with the selected amine dissolved in a nonpolar water-immiscible organic solvent such as kerosene. The uranium which is substantially completely exiracted by the organic phase may be stripped therefrom by waters and recovered from the aqueous phase by treatment into ammonia to precipitate ammonium diuranate.

Brown, K.B.; Crouse, D.J. Jr.; Moore, J.G.

1959-03-10T23:59:59.000Z

322

Energy Efficiency and Conservation Block Grant Program  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Description Description At the Wastewater Treatment Plant: install dissolved oxygen controls, reprogram wetwell level controls for the tertiary filter pumps, install electric actuators on tertiary filter effluent lines, install power monitors on motors, install standby generator; at the Biosolids Processing Facility and Landfill: install timers or programmable logic controllers (PLC); at the Wastewater Flow Equalization Basin and Pumping Station at Landfill: install timers or PLC, install variable frequency drives on wastewater pumps; at the Water Treatment Plant: install power monitors on motors; at several of the wastewater treatment facilities replace existing interior and exterior lighting fixtures with high efficiency units and provide engineering services.

323

Bifunctional anion-exchange resins with improved selectivity and exchange kinetics  

DOE Patents (OSTI)

Disclosed herein are a class of anion exchange resins containing two different exchange sites with improved selectivity and sorptive capability for chemical species in solution, such as heptavalent technetium (as pertechnetate anion, TcO.sub.4.sup.-). The resins are prepared by first reacting haloalkylated crosslinked copolymer beads with a large tertiary amine in a solvent in which the resin beads can swell, followed by reaction with a second, smaller, tertiary amine to more fully complete the functionalization of the resin. The resins have enhanced selectivity, capacity, and exchange kinetics.

Alexandratos, Spiro D. (Knoxville, TN); Brown, Gilbert M. (Knoxville, TN); Bonnesen, Peter V. (Knoxville, TN); Moyer, Bruce A. (Oak Ridge, TN)

2000-01-01T23:59:59.000Z

324

Secondary battery containing zinc electrode with modified separator and method  

DOE Patents (OSTI)

A battery containing a zinc electrode with a porous separator between the anode and cathode. The separator is a microporous substrate carrying therewith an organic solvent of benzene, toluene or xylene with a tertiary organic amine therein, wherein the tertiary amine has three carbon chains each containing from six to eight carbon atoms. The separator reduces the rate of zinc dentrite growth in the separator during battery operation prolonging battery life by preventing short circuits. A method of making the separator is also disclosed.

Poa, D.S.

1984-02-16T23:59:59.000Z

325

Secondary battery containing zinc electrode with modified separator and method  

DOE Patents (OSTI)

A battery containing a zinc electrode with a porous separator between the anode and cathode. The separator is a microporous substrate carrying therewith an organic solvent of benzene, toluene or xylene with a tertiary organic amine therein, wherein the tertiary amine has three carbon chains each containing from six to eight carbon atoms. The separator reduces the rate of zinc dentrite growth in the separator during battery operation prolonging battery life by preventing short circuits. A method of making the separator is also disclosed.

Poa, David S. (Naperville, IL); Yao, Neng-Ping (Clarendon Hills, IL)

1985-01-01T23:59:59.000Z

326

Metal-residence sites in mine tailings in the Magdalena District, New Mexico, USA  

Science Conference Proceedings (OSTI)

Mineralization in the Kelly Mining Camp is hosted by the Mississippian Kelly Limestone and comprises Zn-Pb skarn, replacement, and vein deposits related to Tertiary intrusive activity. The ore consists of primary (hypogene) sulfide mineralization which has been oxidized near surface to form secondary (supergene) mineralization. A zone of secondary sulfide-enrichment separates the sulfide and oxide ores. Mine tailings in the camp contain primary sulfide, oxide and gangue minerals, secondary (supergene) minerals formed during weathering of the primary ore, and tertiary minerals formed by alteration of hypogene and supergene assemblages after deposition in the tailings impoundment.

Larocque, A.C.L. [Univ. of Manitoba, Winnipeg, Manitoba (Canada). Dept. of Geological Sciences; Chapin, C.E. [New Mexico Bureau of Mines and Mineral Resources, Socorro, NM (United States); Laughlin, A.W. [ICF Kaiser Ltd., Los Alamos, NM (United States); Hickmott, D. [Los Alamos National Lab., NM (United States)

1996-05-01T23:59:59.000Z

327

Method for the concentration and separation of actinides from biological and environmental samples  

DOE Patents (OSTI)

A method and apparatus for the quantitative recover of actinide values from biological and environmental sample by passing appropriately prepared samples in a mineral acid solution through a separation column of a dialkyl(phenyl)-N,N-dialylcarbamoylmethylphosphine oxide dissolved in tri-n-butyl phosphate on an inert substrate which selectively extracts the actinide values. The actinide values can be eluted either as a group or individually and their presence quantitatively detected by alpha counting. 3 figs.

Horwitz, E.P.; Dietz, M.L.

1989-05-30T23:59:59.000Z

328

Reactive formulations for a neutralization of toxic industrial chemicals  

DOE Patents (OSTI)

Decontamination formulations for neutralization of toxic industrial chemicals, and methods of making and using same. The formulations are effective for neutralizing malathion, hydrogen cyanide, sodium cyanide, butyl isocyanate, carbon disulfide, phosgene gas, capsaicin in commercial pepper spray, chlorine gas, anhydrous ammonia gas; and may be effective at neutralizing hydrogen sulfide, sulfur dioxide, formaldehyde, ethylene oxide, methyl bromide, boron trichloride, fluorine, tetraethyl pyrophosphate, phosphorous trichloride, arsine, and tungsten hexafluoride.

Tucker, Mark D. (Albuqueruqe, NM); Betty, Rita G. (Rio Rancho, NM)

2006-10-24T23:59:59.000Z

329

Method for the concentration and separation of actinides from biological and environmental samples  

DOE Patents (OSTI)

A method and apparatus for the quantitative recover of actinide values from biological and environmental sample by passing appropriately prepared samples in a mineral acid solution through a separation column of a dialkyl(phenyl)-N,N-dialylcarbamoylmethylphosphine oxide dissolved in tri-n-butyl phosphate on an inert substrate which selectively extracts the actinide values. The actinide values can be eluted either as a group or individually and their presence quantitatively detected by alpha counting.

Horwitz, E. Philip (Naperville, IL); Dietz, Mark L. (Tucson, AZ)

1989-01-01T23:59:59.000Z

330

Adsorption of anionic and cationic surface-active agents by natural coals  

SciTech Connect

Adsorption isotherms were measured in terms of isopropyl-, butyl- and pentyl-amine and isopropyl alcohol for gas coals and anthracite. It was shown that the amount of adsorption depends on the type of coal and the structure of the adsorbate molecules. Cationic surfactants tend to be adsorbed better than anionic. The paper calculates the standard reduction in free energy during adsorption of amines by coal. It was found that the amine adsorption process leads to an increase in pH.

Butuzova, L.F.; Isaeva, L.N.; Saranchuk, V.I.

1983-01-01T23:59:59.000Z

331

Exam 1, Chemistry 210, Dr. Rainer Glaser, W97, MU --1 --Chemistry 210Chemistry 210  

E-Print Network (OSTI)

,4-dimethyl-octane (4 points) 7-tert.-butyl-4-iso.-propyl-3,5-decadiene (3 pts) H O butanal (3 pts) O ethylmethylketone Condensed structural formula of n-butane. (2 pts) H3C-CH2-CH2-CH3 Bond line structure of butane. (2 pts) Newman projection of gauche butane along the central C2-C3 bond. (4 pts) H H Me Me H H

Glaser, Rainer

332

Treatment of biomass gasification wastewaters using liquid-liquid extraction  

DOE Green Energy (OSTI)

Pacific Northwest Laboratory (PNL) investigated liquid-liquid extraction as a treatment method for biomass gasification wastewaters (BGW). Distribution coefficients for chemical oxygen demand (COD) removal were determined for the following solvents: methylisobutyl ketone (MIBK), n-butyl acetate, n-butanol, MIBK/n-butyl acetate (50:50 vol), MIBK/n-butanol (50:50 vol), tri-butyl phosphate, tri-n-octyl phosphine oxide (TOPO)/MIBK (10:90 wt), TOPO/kerosene (10:90 wt), kerosene, and toluene. The best distribution coefficient of 1.3 was given by n-butanol. Chemical analysis of the wastewater by gas chromatography (GC) showed acetic acid and propionic acid concentrations of about 4000 mg/1. Methanol, ethanol, and acetone were identified in trace amounts. These five compounds accounted for 45% of the measured COD of 29,000 mg/1. Because of the presence of carboxylic acids, pH was expected to affect extraction of the wastewater. At low pH the acids should be in the acidic form, which increased extraction by MIBK. Extraction by n-butanol was increased at high pH, where the acids should be in the ionic form.

Bell, N.E.

1981-09-01T23:59:59.000Z

333

Preconceptual ABC design definition and system configuration layout  

SciTech Connect

This document is the conceptual design document for the follow-on to the Molten Salt Breeder Reactor, known as the ABC type reactor. It addresses blanket design options, containment options, off-gas systems, drainage systems, and components/layouts of the primary, secondary, and tertiary systems, and it contains a number of diagrams for the configuration of the major systems.

Barthold, W. [Barthold & Associates, Inc., Knoxville, TN (United States)

1995-03-01T23:59:59.000Z

334

Original article: Power flow Petri Net modelling for building integrated multi-source power system with smart grid interaction  

Science Conference Proceedings (OSTI)

This paper presents an energy management modelling of a multi-source power system composed of photovoltaic (PV) array, storage and power grid connection, and taking into account messages from smart grid. The designed system can supply a tertiary building ... Keywords: Energy management, Petri Net modelling, Photovoltaic, Smart grid, Stateflow

B. C. Wang, M. Sechilariu, F. Locment

2013-05-01T23:59:59.000Z

335

A framework to enrich student interaction via cross-institutional microblogging  

Science Conference Proceedings (OSTI)

This paper introduces a framework for collaborative microblogging that we believe is useful in enriching student interaction, both in-class and outside of contact hours. The framework is called Microblogging for Community of Inquiry (MiCoI). MiCoI is ... Keywords: community of inquiry, microblogging, tertiary institution, twitter

Suku Sinnappan; Samar Zutshi

2011-12-01T23:59:59.000Z

336

COAL QUALITY AND GEOCHEMISTRY, GREATER GREEN RIVER BASIN, WYOMING  

E-Print Network (OSTI)

Chapter GQ COAL QUALITY AND GEOCHEMISTRY, GREATER GREEN RIVER BASIN, WYOMING By G.D. Stricker and M coal beds and zones in the Northern RockyMountains and Great Plains region, U.S. Geological Survey of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great Plains region, U

337

COAL QUALITY AND GEOCHEMISTRY, HANNA AND CARBON BASINS, WYOMING  

E-Print Network (OSTI)

Chapter HQ COAL QUALITY AND GEOCHEMISTRY, HANNA AND CARBON BASINS, WYOMING By G.D. Stricker and M coal beds and zones in the Northern RockyMountains and Great Plains region, U.S. Geological Survey of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great Plains region, U

338

Selenium Bioaccumulation in Stocked Fish as an Indicator of Fishery Potential in Pit Lakes on Reclaimed Coal Mines  

E-Print Network (OSTI)

on Reclaimed Coal Mines in Alberta, Canada L. L. Miller · J. B. Rasmussen · V. P. Palace · G. Sterling · A to selenium (Se) and other metals and metalloids in pit lakes formed by open pit coal mining in Tertiary (thermal coal) and in Cretaceous (metallurgical coal) bedrock. Juvenile hatchery rainbow trout

Hontela, Alice

339

COAL QUALITY AND GEOCHEMISTRY, WILLISTON BASIN, NORTH DAKOTA  

E-Print Network (OSTI)

Chapter WQ COAL QUALITY AND GEOCHEMISTRY, WILLISTON BASIN, NORTH DAKOTA By G.D. Stricker and M coal beds and zones in the Northern RockyMountains and Great Plains region, U.S. Geological Survey of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great Plains region, U

340

Strategies for communication skills development  

Science Conference Proceedings (OSTI)

As the scope of computer science continues to expand and move further into inter-disciplinary research, we see communication skills development (CSD) gain prominence in tertiary courses. Employer groups, professional bodies and universities increasingly ... Keywords: communication across the curriculum, communication skills development, curriculum change

Paul Gruba; Reem Al-Mahmood

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Preliminary evaluation of geothermal resources of South Texas  

DOE Green Energy (OSTI)

Studies on the following are summarized: regional distribution of Frio sands, South Texas; depositional patterns, Gulf-Coast Tertiary; growth faults, mechanisms for downdip thickening; the approach to obtaining sand distribution; reliable correlations from regional cross sections; depositional systems from sand-percentage maps; geopressured Frio related to sand distribution; isothermal maps; and conclusons and potential geothermal fairways. (MHR)

Bebout, D.G.

1974-10-01T23:59:59.000Z

342

Systematic literature reviews in software engineering - A systematic literature review  

Science Conference Proceedings (OSTI)

Background: In 2004 the concept of evidence-based software engineering (EBSE) was introduced at the ICSE04 conference. Aims: This study assesses the impact of systematic literature reviews (SLRs) which are the recommended EBSE method for aggregating ... Keywords: Cost estimation, Evidence-based software engineering, Systematic literature review, Systematic review quality, Tertiary study

Barbara Kitchenham; O. Pearl Brereton; David Budgen; Mark Turner; John Bailey; Stephen Linkman

2009-01-01T23:59:59.000Z

343

A GMDH polynomial neural network-based method to predict approximate three-dimensional structures of polypeptides  

Science Conference Proceedings (OSTI)

Tertiary Protein Structure Prediction is one of the most important problems in Structural Bioinformatics. Along the last 20years many algorithms have been proposed as to solve this problem. However, it still remains a challenging issue because of the ... Keywords: Artificial Neural Networks, Group Method of Data Handling, Multilayer Perceptron, Protein Structure Prediction

MáRcio Dorn; André L. S. Braga; Carlos H. Llanos; Leandro S. Coelho

2012-11-01T23:59:59.000Z

344

BRIGHAM YOUNG UNIVERSITY GEOLOGY STUDIES Volume 27, Part 3  

E-Print Network (OSTI)

by Spieker and Ree- side (1925, p. 443) for exposures near the Blackhawk coal mine On the eastern front Huntington Creek, just south of Little Swens Canyon. East of the mapped area, where coal is being mined fromTertiary floodplains. Nonmarine limestone and thin layen of coal occur in the lacustrine middle pan of the formation

Seamons, Kent E.

345

A studio-based approach to teaching information technology  

Science Conference Proceedings (OSTI)

Studio-based teaching is well-established in creative disciplines such as architecture and the arts, but it has been rarely used in the teaching of IT at a tertiary level. The wider use of the studio model for teaching, originally proposed by Schon (1983), ...

Kathy Lynch; Angela Carbone; David Arnott; Peter Jamieson

2002-07-01T23:59:59.000Z

346

GLHN Architects & Engineers, Inc. Chilled Water System New Mexico State University Not For Construction 0874.00 Utility Development Plan  

E-Print Network (OSTI)

effect absorption chillers. Also included in the production manifold is a thermal storage facility Carrier 19XR electrically driven centrifugal chillers and two nominal 1570 ton Carrier 16JR-150L double-secondary-tertiary pumping arrangement, representative of dedicated constant speed chiller pumps, independent building

Castillo, Steven P.

347

Use of Treated Municipal Wastewater as Power Plant Cooling System...  

NLE Websites -- All DOE Office Websites (Extended Search)

PA 15213-3890 412-268-2946 dzombak@cmu.edu Use of TreaTed MUnicipal WasTeWaTer as poWer planT cooling sysTeM MakeUp WaTer: TerTiary TreaTMenT VersUs expanded cheMical regiMen...

348

Peak Oil Netherlands Foundation (PONL) was founded in May 2005 by a group of citizens who are concerned about the effects of a premature peak in oil and other fossil fuels production. The main aims of  

E-Print Network (OSTI)

leverage and extend conventional oil and natural gas development for unconventional resource development high demand and higher potential for CO2 in existing oilfield tertiary enhanced oil recovery (EOR operations from merely commercial oil production operations to carbon storage operations requires

Keeling, Stephen L.

349

Development of techniques for optimizing selection and completion of western tight gas sands. Phase II report, 1 January Feb 1979--28 February 1979  

SciTech Connect

The Phase II work included the measurement of sandstone bed structural elements at 16 sites on Cretaceous Marine Marginal sandstone beds and at 16 sites on beds in a Lower Tertiary lacustrine sequence in eastern Utah. This work was aimed at defining the internal geometrical characteristics of these two types of reservoir rocks.

Knutson, C.F.; Boardman, C.R.

1979-02-01T23:59:59.000Z

350

Wikis in teaching and assessment: the M/Cyclopedia project  

Science Conference Proceedings (OSTI)

In a knowledge-based, networked economy, students leaving university need to have attained skills in collaborative and creative project-based work and to have developed critical, reflective practices. This paper outlines how a wiki can been used as part ... Keywords: assessment, pedagogy, social constructivism, tertiary education, wiki

Axel Bruns; Sal Humphreys

2005-10-01T23:59:59.000Z

351

FORT UNION COAL IN THE WILLISTON BASIN, NORTH DAKOTA: A SYNTHESIS  

E-Print Network (OSTI)

Chapter WS FORT UNION COAL IN THE WILLISTON BASIN, NORTH DAKOTA: A SYNTHESIS By R.M. Flores and C coal beds and zones in the Northern RockyMountains and Great Plains region, U.S. Geological Survey of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great Plains region, U

352

Resource Assessment of the In-Place and Potentially Recoverable Deep Natural Gas Resource of the Onshore Interior Salt Basins, North Central and Northeastern Gulf of Mexico  

Science Conference Proceedings (OSTI)

The principal research effort for the first six months of Year 2 of the project has been petroleum system characterization. Understanding the burial and thermal maturation histories of the strata in the onshore interior salt basins of the North Central and Northeastern Gulf of Mexico areas is important in petroleum system characterization. The underburden and overburden rocks in these basins and subbasins are a product of their rift-related geohistory. Petroleum source rock analysis and thermal maturation and hydrocarbon expulsion modeling indicate that an effective regional petroleum source rock in the onshore interior salt basins, the North Louisiana Salt Basin, Mississippi Interior Salt Basin, Manila Subbasin and Conecuh Subbasin, was the Upper Jurassic Smackover lime mudstone. The Upper Cretaceous Tuscaloosa shale was an effective local petroleum source rock in the Mississippi Interior Salt Basin and a possible local source bed in the North Louisiana Salt Basin. Hydrocarbon generation and expulsion was initiated in the Early Cretaceous and continued into the Tertiary in the North Louisiana Salt Basin and the Mississippi Interior Salt Basin. Hydrocarbon generation and expulsion was initiated in the Late Cretaceous and continued into the Tertiary in the Manila Subbasin and Conecuh Subbasin. Reservoir rocks include Jurassic, Cretaceous and Tertiary siliciclastic and carbonate strata. Seal rocks include Jurassic, Cretaceous and Tertiary anhydrite and shale beds. Petroleum traps include structural and combination traps.

Ernest A. Mancini; Donald A. Goddard

2005-04-15T23:59:59.000Z

353

Sulfonated polysulfone battery membrane for use in corrosive environments  

SciTech Connect

For batteries containing strong oxidizing electrolyte and a membrane separating two electrolyte solutions, e.g., a zinc ferricyanide battery, an improved membrane is provided comprising an oxidative resistant, conductive, ion-selective membrane fabricated from a catenated aromatic polymer having an absence of tertiary hydrogens, e.g., a sulfonated polysulfone.

Arnold, Jr., Charles (Albuquerque, NM); Assink, Roger (Albuquerque, NM)

1987-01-01T23:59:59.000Z

354

International Conference on Computer Systems and Technologies -CompSysTech'10 An Experiment with Using Google Tools  

E-Print Network (OSTI)

with Using Google Tools for Project Supervision at Tertiary Education Jií Srba Abstract: Problem oriented and coordination management tools for the support of group work. An experiment using a combination of Google Groups on, we chose to focus on Google Groups and other related technology. Google Groups is a service from

Srba, Jiri

355

Post-breakup tectonics in southeast Brazil from thermochronological data and combined inverse-forward thermal history modeling  

E-Print Network (OSTI)

Post-breakup tectonics in southeast Brazil from thermochronological data and combined inverse November 2012. [1] The continental margin of southeast Brazil is elevated. Onshore Tertiary basins and Late with Andean tectonics and those in NE Brazil leads us to assume a plate-wide compressional stress

356

Development of online instructional resources for Earth system science education: An example of current practice from China  

Science Conference Proceedings (OSTI)

Educators around the world are striving to make science more accessible and relevant to students. Online instructional resources have become an integral component of tertiary science education and will continue to grow in influence and importance over ... Keywords: Earth system science, Evaluation, Instructional resource, Online learning

Shaochun Dong; Shijin Xu; Xiancai Lu

2009-06-01T23:59:59.000Z

357

Measurements of Laminar Flame Velocity for Components of Natural Gas  

E-Print Network (OSTI)

Measurements of Laminar Flame Velocity for Components of Natural Gas Patricia Dirrenberger1 flame velocity of components of natural gas, methane, ethane, propane, and nbutane as well as of binary and tertiary mixtures of these compounds proposed as surrogates for natural gas. These measurements have been

358

Storage Hierarchy Management for Scientific Computing  

E-Print Network (OSTI)

of the driving forces behind the design of computer systems. As a result, many advances in CPU architecture were-terabyte tertiary storage system attached to a high- speed computer. The analysis finds that the number of files instead of the two separate views of the system studied. This finding was a major motivation of the design

Miller, Ethan L.

359

Symposium on enhanced oil recovery  

SciTech Connect

The Second Joint Symposium on Enhanced Oil Recovery was held in Tulsa, Oklahoma on April 5 to 8, 1981. Forty-four technical papers were presented which covered all phases of enhanced oil recovery. Field tests, laboratory investigations, and mathematical analyses of tertiary recovery methods such as microemulsion flooding, carbon dioxide injection, in-situ combustion, steam injection, and gas injection are presented.

Not Available

1981-01-01T23:59:59.000Z

360

Downhole steam generator with improved preheating, combustion, and protection features  

DOE Patents (OSTI)

For tertiary oil recovery, a downhole steam generator is designed which provides for efficient counterflow cooling of the combustion chamber walls and preheating of the fuel and water. Pressure-responsive doors are provided for closing and opening the outlet in response to flameout, thereby preventing flooding of the combustion chamber. (DLC)

Fox, R.L.

1981-01-07T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

of Canadian in the 20th  

E-Print Network (OSTI)

WITH SURFACTANT-STABILIZED FOAMS As western Canada's oil fields age,the importance of secondary and tertiary- ary process injection wells. The potential economy of using foams creat- ed by greenhouse or natural gas injection was very attractive. However, since crude oils were known to be effective for foam

Schramm, Laurier L.

362

Research Output in Physics from Pakistani Universities 2004-2008 Although Higher Education Commission (HEC) in the previous years had  

E-Print Network (OSTI)

the impact HEC had on the tertiary education in Pakistan, is to determine the number of research papers Pakistan. As Physics is a very broad ranging subject and also the analytical tool of ISI-Web of Science "Physics" is used it composed of following sub-categories. 1. Applied Physics 2. Nuclear Science

Siddiqi, Sajjad Ahmed

363

An overview of protein-folding techniques: issues and perspectives  

Science Conference Proceedings (OSTI)

The importance of protein folding has been recognised for many years. Almost a half century ago, Linus Pauling discovered two quite simple, regular arrangements of amino acids the ?-helix and the ?-sheet that are found ... Keywords: algorithms, bioinformatics, computational biology, folding mechanism, kinetics, protein folding, protein structure prediction, sequence, tertiary structure

Abdur Rahman; Albert Y. Zomaya

2005-04-01T23:59:59.000Z

364

Manhattan Project: Atomic Bombardment, 1932-1938  

Office of Scientific and Technical Information (OSTI)

Solvay Physics Conference, Brussels, October 1933 ATOMIC BOMBARDMENT Solvay Physics Conference, Brussels, October 1933 ATOMIC BOMBARDMENT (1932-1938) Events > Atomic Discoveries, 1890s-1939 A Miniature Solar System, 1890s-1919 Exploring the Atom, 1919-1932 Atomic Bombardment, 1932-1938 The Discovery of Fission, 1938-1939 Fission Comes to America, 1939 M. Stanley Livingston and Ernest O. Lawrence in front of a 27-inch cyclotron, Rad Lab, University of California, Berkeley, 1934. In the 1930s, scientists learned a tremendous amount about the structure of the atom by bombarding it with sub-atomic particles. Ernest O. Lawrence's cyclotron, the Cockroft-Walton machine, and the Van de Graaff generator, developed by Robert J. Van de Graaff at Princeton University, were particle accelerators designed to bombard the nuclei of various elements to disintegrate atoms. Attempts of the early 1930s to split atoms, however, required huge amounts of energy because the first accelerators used proton beams and alpha particles as sources of energy. Since protons and alpha particles are positively charged, they Albert Einstein met substantial resistance from the positively charged target nucleus when they attempted to penetrate atoms. Even high-speed protons and alpha particles scored direct hits on a nucleus only approximately once in a million tries. Most simply passed by the target nucleus. Not surprisingly, Ernest Rutherford, Albert Einstein (right), and Niels Bohr regarded particle bombardment as useful in furthering knowledge of nuclear physics but believed it unlikely to meet public expectations of harnessing the power of the atom for practical purposes anytime in the near future. In a 1933 interview, Rutherford called such expectations "moonshine." Einstein compared particle bombardment with shooting in the dark at scarce birds, while Bohr, the Danish Nobel laureate, agreed that the chances of taming atomic energy were remote.

365

A virtual corporation tackles SO[sub 2] allowance tracking  

SciTech Connect

Beginning in 1995, electric utilities will manage a new corporate asset, an SO[sub 2] emission allowance. The government's allowance program unleashed an accountability monster. How would utilities track thousands of allowance serial numbers They needed a software tool to oversee the myriad SO[sub 2] allowances they would receive from the EPA; provide decisionmaking information about allowance costs, year of issue, and usage; and generate the requisite reports -- but no computer solution existed. For 10 utilities and one software supplier, the way to tame the monster was to form a [open quotes]virtual corporation.[close quotes] The term describes a group of companies that unite to address a specific problem or opportunity. By forming an alliance, they can react to a problem. Electric Software Products (ESP), a developer of software for electric utilities, saw an opportunity to act as the facilitator and software developer for an alliance of Phase 1-affected utilities. The goal of the virtual corporation as seen by ESP was to develop a virtual product that could handle the nuances of tracking and reporting SO[sub 2] allowances. A virtual product is one that can be produced quickly and customized in response to customer demand. The virtual product resulting from the utility collaboration was named the Allowance Tracking Workstation[trademark] (ATW). Version 1.0 of the ATW is scheduled for release on May 27, 1994. Through the Development Group format, the ATW will be flexible enough to meet the changing needs of its customers, the electric utilities.

Plank, K.; Gloski, D.

1994-01-01T23:59:59.000Z

366

Sampling Within k-Means Algorithm to Cluster Large Datasets  

Science Conference Proceedings (OSTI)

Due to current data collection technology, our ability to gather data has surpassed our ability to analyze it. In particular, k-means, one of the simplest and fastest clustering algorithms, is ill-equipped to handle extremely large datasets on even the most powerful machines. Our new algorithm uses a sample from a dataset to decrease runtime by reducing the amount of data analyzed. We perform a simulation study to compare our sampling based k-means to the standard k-means algorithm by analyzing both the speed and accuracy of the two methods. Results show that our algorithm is significantly more efficient than the existing algorithm with comparable accuracy. Further work on this project might include a more comprehensive study both on more varied test datasets as well as on real weather datasets. This is especially important considering that this preliminary study was performed on rather tame datasets. Also, these datasets should analyze the performance of the algorithm on varied values of k. Lastly, this paper showed that the algorithm was accurate for relatively low sample sizes. We would like to analyze this further to see how accurate the algorithm is for even lower sample sizes. We could find the lowest sample sizes, by manipulating width and confidence level, for which the algorithm would be acceptably accurate. In order for our algorithm to be a success, it needs to meet two benchmarks: match the accuracy of the standard k-means algorithm and significantly reduce runtime. Both goals are accomplished for all six datasets analyzed. However, on datasets of three and four dimension, as the data becomes more difficult to cluster, both algorithms fail to obtain the correct classifications on some trials. Nevertheless, our algorithm consistently matches the performance of the standard algorithm while becoming remarkably more efficient with time. Therefore, we conclude that analysts can use our algorithm, expecting accurate results in considerably less time.

Bejarano, Jeremy [Brigham Young University; Bose, Koushiki [Brown University; Brannan, Tyler [North Carolina State University; Thomas, Anita [Illinois Institute of Technology; Adragni, Kofi [University of Maryland; Neerchal, Nagaraj [University of Maryland; Ostrouchov, George [ORNL

2011-08-01T23:59:59.000Z

367

Fuel property effects on engine combustion processes. Annual report, January 1, 1993--December 31, 1993  

DOE Green Energy (OSTI)

Our engine studies have concentrated on 2 areas of interest to autoignition and emissions from engines. In the first, we investigated the effect of nitric oxide (NO) on the reactivity and autoignition behavior of 87 PRF. In the second study, we continued work on the effects of blending ethers on the reactivity and autoignition of a primary reference fuel blend, 87 PRF, with emphasis placed on the chemical interactions between ethers and the baseline fuel. The effects of nitric oxide (NO) on the reactivity and autoignition behavior of 87 PRF were examined in our research engine under motored conditions at compression ratios of 5.2 and 8.2. The most significant conclusions of our study are: (1) nitric oxide does interact with the hydrocarbon oxidation at conditions typically experienced by the end gas in a fired engine; (2) the effect is complex and, depending on the reaction environment, the same concentration of NO can produce dramatically different results. These results are particularly important given the fact that residual fractions and recycled exhaust gases in spark ignited engines typically result in about 200--600 ppm of NO in the unburned charge. The octane enhancing ethers, MTBE, ETBE, TAME, and DIPE, were blended into 87 PRF at a constant 0 atom fraction of 1.94% in the fuel mixtures and the mixtures were tested under motored conditions at our new compression ratio of 8.2. This new compression ratio allows studies on autoignition behaviors of 87 PRF with and without ethers. The results showed that, when using 87 PRF/ether mixtures, reactivity was significantly reduced as indicated by the higher inlet temperature required to initiate reactivity, significantly lower maximum CO concentration and the significantly higher inlet temperature required for autoignition.

Cernansky, N.P.

1994-01-10T23:59:59.000Z

368

The dog originated south of Yangtse river less than 16,000 years ago, from numerous wolves  

SciTech Connect

We here present a detailed picture of the origins of the dog, giving strong and precise evidence for 'where and when', and thereby also a first tentative picture of 'how, why and by whom' the wolf was domesticated. Previous studies of mitochondrial DNA (mtDNA) have failed to definitely establish the time and place of origin because of lack in phylogenetic resolution for the so far studied 582 bp region, and inadequate sampling across the world. We therefore analysed 169 mtDNA genomes, selected from partial sequences (582 bp) from 1,576 dogs worldwide. This shows that dogs universally share a common gene pool, but the three earlier identified universally occurring phylogenetic clades ofhigh age consist often much younger subclades, which originated 5,000-16,000 ya from at least 48 wolf founders. The full range of genetic diversity, all 10 subclades, is found only in south-eastern Asia south of Yangtze River, and the diversity decreases gradually across Eurasia down to only four sub clades in Europe. This establishes that the dog has a single origin in time and space from a large number ofwolves, less than 16,000 ya, probably in China south of Y angtzeRiver. The place and time coincide with the origin of rice agriculture, suggesting an origin among sedentary hunter-gatherers or early rice farmers. The numerous founders indicate that wolf taming was an important cultural trait, and it is noticeable that in this region dogs are since ancient times used as food, offering a possible reason for the wolf domestication.

Leitner, Thomas [Los Alamos National Laboratory; Pang, Jun - Feng [STATE KEY LABORATORY OF GENETIC; Kluetsch, Cornelya [KTH-ROYAL INST. OF TECH

2009-01-01T23:59:59.000Z

369

The Risk Assessment Information System  

NLE Websites -- All DOE Office Websites (Extended Search)

What's New What's New November 2013 Updates ECO mammalian SSLs were updated for cadmium, antimony , arsenic, inorganic, barium, Beryllium, chromium VI, cobalt, copper, lead, silver, vanadium, cyanide (total complex), methyl mercury, sulfide, thallium and tin. October 2013 Updates The biota intake rates for the radionuclide PRG and risk tools were updated to correct an improper units conversion. September 2013 Updates IRIS updates for 1,4-Dioxane and Biphenyl were completed. PPRTV values have been updated for Biphenyl, 3,4-Dichlorobenzotrifluoride, Trinitrophenylmethylnitramine (Tetryl), Endosulfan Sulfate, 1,1,2,2-Tetrachloroethane, Nitromethane, Dibenzothiophene, 2-Ethoxyethanol, 3,3'-Dimethoxybenzidine, Butylated hydroxytoluene, Ethyl Acetate, tert-Amyl Alcohol, 2,2-Difluoropropane,

370

List of Reproductive Toxins and Highly Acute Toxic Materials  

NLE Websites -- All DOE Office Websites (Extended Search)

Reproductive Toxins and Highly Acute Toxic Materials Reproductive Toxins and Highly Acute Toxic Materials Reproductive Toxins Acrylonitr ile Aniline Arsenic and its compounds Benzene Benzo(a)pyrene Beryllium Boric acid (Boron) Cadmium and its compounds Carbon monoxide Chlordecone (Kepone) Chloroform Chloroprene Dibromochloropropane (DBCP) Dichlorobenzene 1,1-Dichloroethane Dichloromethane Dioxane Epichlorohydrin Ethylene Dibromide Ethylene Dichloride Ethylene Oxide Fluorocarbons Formaldehyde Formamides Lead (Organic) Manganese and its compounds Mercury and its compounds (Inorganic) Methyl n-butyl ketone Methyl chloroform Methyl ethyl ketone (MEK) Nitrogen Dioxide Ozone Platinum and its compounds Polybrominated biphenyls (PBB) Polychlorinated bipenyls (PCB) Selenium and its compounds Styrene Tellurium and its compounds Tetr achloroethylene

371

Thermal energy storage material  

DOE Patents (OSTI)

A thermal energy storage material which is stable at atmospheric temperature and pressure and has a melting point higher than 32.degree.F. is prepared by dissolving a specific class of clathrate forming compounds, such as tetra n-propyl or tetra n-butyl ammonium fluoride, in water to form a substantially solid clathrate. The resultant thermal energy storage material is capable of absorbing heat from or releasing heat to a given region as it transforms between solid and liquid states in response to temperature changes in the region above and below its melting point.

Leifer, Leslie (Hancock, MI)

1976-01-01T23:59:59.000Z

372

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. Quarterly technical progress report No. 5, October 1, 1991--December 31, 1991  

DOE Green Energy (OSTI)

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. Addition of methanol to slurry phase FT synthesis making iso-olefins.

Marcelin, G.

1992-06-10T23:59:59.000Z

373

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch  

DOE Green Energy (OSTI)

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. Addition of methanol to slurry phase FT synthesis making iso-olefins.

Marcelin, G.

1992-06-10T23:59:59.000Z

374

Lipid extraction from microalgae using a single ionic liquid  

DOE Patents (OSTI)

A one-step process for the lysis of microalgae cell walls and separation of the cellular lipids for use in biofuel production by utilizing a hydrophilic ionic liquid, 1-butyl-3-methylimidazolium. The hydrophilic ionic liquid both lyses the microalgae cell walls and forms two immiscible layers, one of which consists of the lipid contents of the lysed cells. After mixture of the hydrophilic ionic liquid with a suspension of microalgae cells, gravity causes a hydrophobic lipid phase to move to a top phase where it is removed from the mixture and purified. The hydrophilic ionic liquid is recycled to lyse new microalgae suspensions.

Salvo, Roberto Di; Reich, Alton; Dykes, Jr., H. Waite H.; Teixeira, Rodrigo

2013-05-28T23:59:59.000Z

375

CASTING SLIPS FOR FABRICATION OF REFRACTORY METAL WARE  

DOE Patents (OSTI)

A composition is given for slip casting tungsten metal. The composition consists essentially of tungsten metal with an average particle size of 0.9 micron, an organic vehicle such as methyl chloroform, o-xylene, n-butyl acetate, isobutyl acetate, and 1, 1, 2, 2-tetrachlorethane, and a suspending agent such as ethyl cellulose, with the approximate ratio of said vehicle to the tungsten metal being 12 cc of a solution containing from 5 to about 20 grams of said ethyl cellulose in 400 cc of said organic vehicle per 100 grams of metal. (AEC)

Stoddard, S.D.; Nuckolls, D.E.; Cowan, R.E.

1962-09-01T23:59:59.000Z

376

A study of the kinetics and mechanism of the adsorption and anaerobic partial oxidation of n-butane over a vanadyl pyrophosphate catalyst  

SciTech Connect

The interaction of n-butane with a ((VO){sub 2}P{sub 2}O{sub 7}) catalyst has been investigated by temperature-programmed desorption and anaerobic temperature-programmed reaction. n-Butane has been shown to adsorb on the (VO){sub 2}P{sub 2}O{sub 7} to as a butyl-hydroxyl pair. When adsorption is carried out at 223 K, upon temperature programming some of the butyl-hydroxyl species recombine resulting in butane desorption at 260 K. However, when adsorption is carried out at 423 K, the hydroxyl species of the butyl-hydroxyl pair migrate away from the butyl species during the adsorption, forming water which is detected in the gas phase. Butane therefore is not observed to desorb at 260 K after the authors lowered the temperature to 223 K under the butane/helium from the adsorption temperature of 423 K prior to temperature programming from that temperature to 1100 K under a helium stream. Anaerobic temperature-programmed oxidation of n-butane produces butene and butadiene at a peak maximum temperature of 1000 K; this is exactly the temperature at which, upon temperature programming, oxygen evolves from the lattice and desorbs as O{sub 2}. This, and the fact that the amount of oxygen desorbing from the (VO){sub 2}P{sub 2}O{sub 7} at {approximately}1000 K is the same as that required for the oxidation of the n-butane to butene and butadiene, strongly suggests (1) that lattice oxygen as it emerges at the surface is the selective oxidant and (2) that its appearance at the surface is the rate-determining step in the selective oxidation of n-butane. The surface of the (VO){sub 2}P{sub 2}O{sub 7} catalyst on which this selective oxidation takes place has had approximately two monolayers of oxygen removed from it by unselective oxidation of the n-butane to CO, CO{sub 2}, and H{sub 2}O between 550 and 950 K and has had approximately one monolayer of carbon deposited on it at {approximately}1000 K. It is apparent, therefore, that the original crystallography of the (VO){sub 2}P{sub 2}O{sub 7} catalyst will not exist during this selective oxidation and that theories that relate selectivity in partial oxidation to the (100) face of the (VO){sub 2}P{sub 2}O{sub 7} catalyst cannot apply in this case.

Sakakini, B.H.; Taufiq-Yap, Y.H.; Waugh, K.C.

2000-01-25T23:59:59.000Z

377

Responsive copolymers for enhanced petroleum recovery. Quarterly technical progress report, June 22, 1993 through September 22, 1993  

Science Conference Proceedings (OSTI)

This report summarizes technical progress on advanced copolymer synthesis and characterization of the molecular structure of copolymers to be used to enhanced recovery of petroleum. Polymers examined are acrylamide/acrylamido-3-methylbutanoic acid/N-(4-butyl)phenylacrylamide (AM/AMBA/BPAM) terpolymers, sodium 2-(acrylamido)-2-methylpropanesulfonate and (2-(acrylamido)-2-methylpropyl)trimethylammonium chloride (NaAMPS/AMPTAC) copolymers, AM/NaAMPS/AMPTAC terpolymers, and AM/APS (APS is 2-(1-pyrenylsulfonamido) ethyl acrylamide) copolymers. Polymer associative behavior and polymer solution behavior is characterized.

McCormick, C.; Hester, R.

1993-12-01T23:59:59.000Z

378

Synthesis, characterization and application of water-soluble and easily removable cationic pressure-sensitive adhesives. Quarterly technical report  

DOE Green Energy (OSTI)

The Institute studied the adsorption of cationic pressure-sensitive adhesive (PSA) on wood fiber, and the buildup of PSA in a closed water system during paper recycling; the results are presented. Georgia Tech worked to develop an environmentally friendly polymerization process to synthesize a novel re-dispersible PSA by co-polymerizing an oil-soluble monomer (butyl acrylate) and a cationic monomer MAEPTAC; results are presented. At the University of Georgia at Athens the project focused on the synthesis of water-soluble and easily removable cationic polymer PSAs.

NONE

1999-09-30T23:59:59.000Z

379

Fluorescent temperature sensor  

Science Conference Proceedings (OSTI)

The present invention is a fluorescent temperature sensor or optical thermometer. The sensor includes a solution of 1,3-bis(1-pyrenyl)propane within a 1-butyl-1-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid solvent. The 1,3-bis(1-pyrenyl)propane remains unassociated when in the ground state while in solution. When subjected to UV light, an excited state is produced that exists in equilibrium with an excimer. The position of the equilibrium between the two excited states is temperature dependent.

Baker, Gary A [Los Alamos, NM; Baker, Sheila N [Los Alamos, NM; McCleskey, T Mark [Los Alamos, NM

2009-03-03T23:59:59.000Z

380

Method for measuring surface temperature  

DOE Patents (OSTI)

The present invention relates to a method for measuring a surface temperature using is a fluorescent temperature sensor or optical thermometer. The sensor includes a solution of 1,3-bis(1-pyrenyl)propane within a 1-butyl-1-1-methyl pyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid solvent. The 1,3-bis(1-pyrenyl)propane remains unassociated when in the ground state while in solution. When subjected to UV light, an excited state is produced that exists in equilibrium with an excimer. The position of the equilibrium between the two excited states is temperature dependent.

Baker, Gary A. (Los Alamos, NM); Baker, Sheila N. (Los Alamos, NM); McCleskey, T. Mark (Los Alamos, NM)

2009-07-28T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Adipose tissue stearoyl-CoA desaturase 1 index is increased and linoleic acid is decreased in obesity-prone rats fed a high-fat diet  

E-Print Network (OSTI)

in the adipose tissue and whether these changes occur simul- taneously across lipid fractions. It has previously been found that a HFD, especially a diet rich in SFA, decreases SCD expression in both rat liver and adipose tissue [33,34]. A HFD has also been shown... of petroleum ether containing 0.005% butylated hydroxytolvene after addition of 1.5 ml distilled water. The phases were separated after thorough mixing and centrifugation at 1500 × g for 10 min. The petroleum ether phase was pipetted off and the solvent...

Cedernaes, Jonathan; Alsiö, Johan; Västermark, Åke; Risérus, Ulf; Schiöth, Helgi B

2013-01-08T23:59:59.000Z

382

CX-003574: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

3574: Categorical Exclusion Determination 3574: Categorical Exclusion Determination CX-003574: Categorical Exclusion Determination North Carolina-County-Johnston CX(s) Applied: B2.5, B5.1 Date: 08/26/2010 Location(s): Johnston County, North Carolina Office(s): Energy Efficiency and Renewable Energy Energy Efficiency and Conservation Block Grant Program. At the Wastewater Treatment Plant: install dissolved oxygen controls, reprogram wet well level controls for the tertiary filter pumps, install electric actuators on tertiary filter effluent lines, install power monitors on motors, install standby generator; at the Biosolids Processing Facility and Landfill: install timers or programmable logic controllers (PLC); at the Wastewater Flow Equalization Basin and Pumping Station at Landfill: install timers or

383

A Geological And Geophysical Appraisal Of The Baca Geothermal Field, Valles  

Open Energy Info (EERE)

Geological And Geophysical Appraisal Of The Baca Geothermal Field, Valles Geological And Geophysical Appraisal Of The Baca Geothermal Field, Valles Caldera, New Mexico Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: A Geological And Geophysical Appraisal Of The Baca Geothermal Field, Valles Caldera, New Mexico Details Activities (10) Areas (2) Regions (0) Abstract: The Baca location #1 geothermal field is located in north-central New Mexico within the western half of the Plio-Pleistocene Valles Caldera. Steam and hot water are produced primarily from the northeast-trending Redondo Creek graben, where downhole temperatures exceed 260°C at depths of less than 2 km. Stratigraphically the reservoir region can be described as a five-layer sequence that includes Tertiary and Quaternary volcanic rocks, and Mesozoic and Tertiary sediments overlying Precambrian granitic

384

Geology and Mineral Deposits of Churchill County, Nevada | Open Energy  

Open Energy Info (EERE)

Geology and Mineral Deposits of Churchill County, Nevada Geology and Mineral Deposits of Churchill County, Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geology and Mineral Deposits of Churchill County, Nevada Abstract Churchill County, in west-central Nevada, is an area of varied topography and geology that has had a rather small total mineral production. The western part of the county is dominated by the broad low valley of the Carson Sink, which is underlain by deposits of Lake Lahontan. The bordering mountain ranges to the west and south are of low relief and underlain largely by Tertiary volcanic and sedimentary units. Pre-Tertiary rocks are extensively exposed east of the Carson Sink in the Stillwater Range, Clan Alpine Mountains, Augusta Mountains, and New Pass Mountains. The eastern

385

Core Analysis At Raft River Geothermal Area (2011) | Open Energy  

Open Energy Info (EERE)

2011) 2011) Exploration Activity Details Location Raft River Geothermal Area Exploration Technique Core Analysis Activity Date 2011 Usefulness not indicated DOE-funding Unknown Exploration Basis Explore for development of an EGS demonstration project Notes Core was obtained from RRG-3C. The sample is a brecciated and altered siltstone from the base of the Tertiary sequence and is similar to rocks at the base of the Tertiary deposits in RRG-9. The results of thermal and quasi-static mechanical property measurements that were conducted on the core sample are presented. References Jones, C.; Moore, J.; Teplow, W.; Craig, S. (1 January 2011) GEOLOGY AND HYDROTHERMAL ALTERATION OF THE RAFT RIVER GEOTHERMAL SYSTEM, IDAHO Retrieved from "http://en.openei.org/w/index.php?title=Core_Analysis_At_Raft_River_Geothermal_Area_(2011)&oldid=473834

386

NERSC Users Group Meeting January 28-29, 1997 Presentations  

NLE Websites -- All DOE Office Websites (Extended Search)

Overview of NERSC at LBNL Overview of NERSC at LBNL January 28, 1997 | Author(s): Bill Kramer | Tertiary Storage January 28, 1997 | Author(s): Keith Fitzgerald, Harvard Holmes | Download File: Tertiary-Storage.pdf | pdf | 173 KB Report on Graphics Packages January 28, 1997 | Author(s): Steve Lau | DOE 2000 January 28, 1997 | Author(s): Jim McGraw | Download File: DOE-2000.pdf | pdf | 48 KB The Scientific Computing Group January 28, 1997 | Author(s): Tammy Welcome | Download File: The-Scientific-Computing-Group.pdf | pdf | 67 KB Report on Users' Questions about NERSC 1997 January 28, 1997 | Author(s): Ricky Kendall | Download File: Questions-for-the-ERSUG-Meeting.pdf | pdf | 80 KB Report on Graphics Packages January 28, 1997 | Author(s): Stephen Lau, Nancy Johnston, Terry Ligocki | Download File: NERSC1.pdf | pdf | 85 KB

387

Microsoft Word - Document6  

NLE Websites -- All DOE Office Websites (Extended Search)

Tertiary Storage Tertiary Storage Keith Fitzgerald - Harvard Holmes NERSC File Storage Group Storage Charging: Questions and Answers Why charge for storage? The answer is for the same reason we charge for CPU time on our compute servers. Our resources have limitations and we have the responsibility to provide a deterministic, automated mechanism which insures that the resources are utilized as DOE desires. Our experience has led us to believe that the most critical resources in the storage environment are: 1. Bandwidth. This limitation can show up in many areas .... network, disk cache, archive, etc. but the bottom line is that when you approach a limit, users suffer. 2. The name server. When this is overloaded, service degrades. 3. The archive. We've already experienced and fixed this problem. l> A good management scheme should provide a deterministic mechanism which will encourage users to optimize their utilization of the storage

388

Exploration In A Blind Geothermal Area Near Marysville, Montana, Usa | Open  

Open Energy Info (EERE)

In A Blind Geothermal Area Near Marysville, Montana, Usa In A Blind Geothermal Area Near Marysville, Montana, Usa Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Exploration In A Blind Geothermal Area Near Marysville, Montana, Usa Details Activities (7) Areas (1) Regions (0) Abstract: Extensive geological and geophysical studies were carried out during the summer of 1973 in a blind geothermal area near Marysville, Montana. Earlier studies of regional heat flow resulted in the discovery of the area (BLACKWELL 1969; BLACKWELL, BAAG 1973). The area is blind in the sense that there are no surface manifestations of high heat flow (recent volcanics, hot springs, etc.) within the area. The country rocks are Precambrian sedimentary rocks and Mesozoic and Tertiary intrusive rocks. The most recent Tertiary igneous event took place approximately 37 M.Y.

389

Alaska Coal Geology: GIS Data | OpenEI  

Open Energy Info (EERE)

Coal Geology: GIS Data Coal Geology: GIS Data Dataset Summary Description Estimated Alaska coal resources are largely in Cretaceous and Tertiary rocks distributed in three major provinces. Northern Alaska-Slope, Central Alaska-Nenana, and Southern Alaska-Cook Inlet. Cretaceous resources, predominantly bituminous coal and lignite, are in the Northern Alaska-Slope coal province. Most of the Tertiary resources, mainly lignite to subbituminous coal with minor amounts of bituminous and semianthracite coals, are in the other two provinces. The combined measured, indicated, inferred, and hypothetical coal resources in the three areas are estimated to be 5,526 billion short tons (5,012 billion metric tons), which constitutes about 87 percent of Alaska's coal and surpasses the total coal resources of the conterminous United States by 40 percent. Available here: GIS shapefiles of relevant faults and geology, associated with the following report: http://pubs.usgs.gov/dds/dds-077/pdf/DDS-77.pdf

390

Tuscarora area, Nevada: geothermal reservoir assessment case history, northern basin and range. Final report, 1 October 1978-9 September 1980  

DOE Green Energy (OSTI)

The Tuscarora prospect is located at the north end of Independence Valley approximately 90 km north-northwest of Elko, Nevada. Geothermal exploration on the prospect consisted of an integrated program of geologic, hydrogeochemical and soil geochemistry studies. Geophysical exploration included heatflow studies, aeromagnetic, self-potential, gravity, dipole-dipole resistivity and magnetotelluric surveys. Exploration drilling includes thirty-two shallow thermal gradient holes, six intermediate depth temperature gradient wells and one 5454 foot test for discovery well. Shallow low-temperature reservoirs were encountered in the Tertiary rocks and in the Paleozoic rocks immediately beneath the Tertiary. Drilling problems forced the deep well to be stopped before the high-temperature reservoir was reached.

Pilkington, H.D.

1981-08-01T23:59:59.000Z

391

Gravity and subsurface investigation of the Presidio Bolson area, Texas  

DOE Green Energy (OSTI)

An integrated geophysical-geologic study of the Presidio Bolson area was undertaken primarily using gravity measurements and deep drilling data. Over 2000 gravity readings were used to construct maps of the area and two-dimensional computer modeling of gravity profiles was used to derive earth models. These data outlined the major geologic features of the area and were dominated by Tertiary block faulting and volcanism. The main feature of interest was the Presidio Bolson, which is located in a major graben (Presidio Graben) over 1 km deep in the area near Ruidosa, Texas. These data also suggest that hot springs associated with the Presidio Graben derive their heat from buried Tertiary intrusions associated with this graben or by deep circulation along the boundary faults of the graben.

Mraz, J.R.; Keller, G.R.

1977-01-01T23:59:59.000Z

392

Alvord (3,000-ft strawn) LPG flood - design and performance evaluation  

SciTech Connect

Mitchell Energy Corporation has implemented a LPG-dry gas miscible process in the Alvord (3000' Strawn) Unit in Wise County, Texas utilizing the DOE tertiary incentive program. The field had been waterflooded for 14 years and was producing near its economic limit at the time this project was started. This paper presents the results of the reservoir simulation study that was conducted to evaluate pattern configuration and operating alternatives so as to maximize LPG containment and oil recovery performance. Several recommendations resulting from this study were implemented for the project. Based on the model predictions, tertiary oil recovery is expected to be between 100,000 and 130,000 bbls, or about 7 percent of the oil originally in place in the Unit. 12 refs.

Frazier, G.D.; Todd, M.R.

1982-01-01T23:59:59.000Z

393

Thoughts Regarding the Dimensions of Faults at Rainier and Aqueduct Mesas, Nye County, Nevada, Based on Surface and Underground Mapping  

Science Conference Proceedings (OSTI)

The geologic setting and history, along with observations through 50 years of detailed geologic field work, show that large-displacement (i.e., greater than 30 meters of displacement) syn- to post-volcanic faults are rare in the Rainier Mesa area. Faults observed in tunnels and drill holes are mostly tight, with small displacements (most less than 1.5 meters) and small associated damage zones. Faults are much more abundant in the zeolitized tuffs than in the overlying vitric tuffs, and there is little evidence that faults extend downward from the tuff section through the argillic paleocolluvium into pre-Tertiary rocks. The differences in geomechanical characteristics of the various tuff lithologies at Rainier Mesa suggest that most faults on Rainer Mesa are limited to the zeolitic units sandwiched between the overlying vitric bedded tuffs and the underlying pre-Tertiary units (lower carbonate aquifer–3, lower clastic confining unit–1, and Mesozoic granite confining unit).

Drellack, S.L.; Prothro, L.B.; Townsend, M.J.; Townsend, D.R.

2011-02-01T23:59:59.000Z

394

Enhanced oil recovery. Byron Field polymer waterflood will achieve two important firsts  

SciTech Connect

When Marathon Oil Co. starts up its long-awaited, Byron Field Tensleep-Embar Unit polymer waterflood this December 2, firsts will have been achieved: the Big-Horn basin will see its first full-field commercial tertiary flood, and Marathon also will see its first full-field commercial tertiary flood. Marathon's flood will use a massive amount of polymer. Seventy percent of pore volume will be injected. Big Horn basin fields usually have been subjected only to infill drilling and waterflood because the thicker than average crude lies in heterogeneous formations, yielding a situation whereby, even 60 to 70 yr after discovery, simple infill drilling can cause virgin oil to flow to the well bore. In some cases, 20-, 10-, or 5-acre spacing might be required to drain a reservoir adequately, giving long effective lift to simple primary production techniques. In addition, a natural water drive often is present.

Gill, D.

1982-09-01T23:59:59.000Z

395

Preliminary study of the uranium favorability of the Jornada Del Muerto Basin and adjacent areas, South Central New Mexico  

SciTech Connect

Data indicate that possible uranium host rocks include the Precambrian rocks, the Ordovician Bat Cave Formation and Cable Canyon Sandstone, the Permian Abo Formation, Lower Cretaceous Dakota Sandstone, and the Upper Cretaceous-lower Tertiary McRae Formation. The Cenozoic sequence contains possible host beds; little is known, however, about its stratigraphy. Secondary uranium mineralization is found associated with faults in the Jornada area. All fault zones there are possible sites for uranium deposition. Possible sources for uranium in the Jornada del Muerto area include uraniferous Precambrian rocks, tuffaceous beds in the McRae Formation, and the Tertiary Datil and Thurman Formations. Hydrothermal solutions may have deposited the veinlike fluorite deposits, of which the purple varieties were found to be radioactive during this study.

Templain, C.J.; Dotterrer, F.E.

1978-06-01T23:59:59.000Z

396

TORIS Data Preparation Guidelines  

SciTech Connect

The objective of this manual is to present guidelines and procedures for the preparation of new data for the Tertiary Oil Recovery Information System (TORIS) data base. TORIS is an analytical system currently maintained by the Department of Energy's (DOE) Bartlesville Project Office. It uses an extensive field- and reservoir-level data base to evaluate the technical and economic recovery potential of specific crude oil reservoirs.

Guinn, H.; Remson, D.

1999-03-11T23:59:59.000Z

397

Stochastic Equilibrium Models for Generation Capacity Expansion  

E-Print Network (OSTI)

in household and tertiary and hence reduction of demand. The second reason is that the increasing interest for de- mand side management and the development of new technologies of the smart grid type will progressively introduce a true price response... , for the integrability property). This variant of the equilibrium model can be stated as follows. Let D(?) = (d(`, ?), ` ? L) and P (?) = (p(`, ?), ` ? L) denote the vectors of demand and price in the different time segments. Smart grid technologies aim, among other...

Ehrenmann, Andreas; Smeers, Yves

398

Fractured reservoir discrete feature network technologies. Final report, March 7, 1996 to September 30, 1998  

Science Conference Proceedings (OSTI)

This report summarizes research conducted for the Fractured Reservoir Discrete Feature Network Technologies Project. The five areas studied are development of hierarchical fracture models; fractured reservoir compartmentalization, block size, and tributary volume analysis; development and demonstration of fractured reservoir discrete feature data analysis tools; development of tools for data integration and reservoir simulation through application of discrete feature network technologies for tertiary oil production; quantitative evaluation of the economic value of this analysis approach.

Dershowitz, William S.; Einstein, Herbert H.; LaPoint, Paul R.; Eiben, Thorsten; Wadleigh, Eugene; Ivanova, Violeta

1998-12-01T23:59:59.000Z

399

Oil shale deposits of Thailand  

SciTech Connect

Oil-shale deposits occur in several areas of Thailand. Perhaps the most important deposit occurs at Mae Sod in Tak Province, West Thailand. Other well-known deposits are Li in Lamphum Province, Ko Kha District, Lampang Province, and Krabi in the southern peninsular region. The geological age of all these deposits is late Tertiary, as demonstrated by the presence of the fossils from the oil shale of the Mae Sod series, e.g., fish of the Ostariophysian family Cyprinidae.

Chakrabarti, A.K.

1976-06-01T23:59:59.000Z

400

Middle East oil show: Proceedings. Volume 1  

SciTech Connect

This is a book of conference proceedings which deal with critical issues and technologies being used to maximize recovery of the oil and gas resources of the Middle East. Papers include information on horizontal drilling techniques, corrosion control, offshore technologies, uses of flexible tubing in drilling and completion, scale control technologies, enhanced recovery techniques, and waste management. Other topics include performance testing for drilling fluids and new computer codes for simulating well performance during both tertiary and secondary recovery.

NONE

1995-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Downhole steam generator using low-pressure fuel and air supply  

DOE Patents (OSTI)

For tertiary oil recovery, an apparatus for downhole steam generation is designed in which water is not injected directly onto the flame in the combustor, the combustion process is isolated from the reservoir pressure, the fuel and oxidant are supplied to the combustor at relatively low pressures, and the hot exhaust gases is prevented from entering the earth formation but is used to preheat the fuel and oxidant and water. The combustion process is isolated from the steam generation process. (DLC)

Fox, R.L.

1981-01-07T23:59:59.000Z

402

Downhole steam generator having a downhole oxidant compressor  

DOE Patents (OSTI)

Am improved apparatus is described for the downhole injection of steam into boreholes, for tertiary oil recovery. It includes an oxidant supply, a fuel supply, an igniter, a water supply, an oxidant compressor, and a combustor assembly. The apparatus is designed for efficiency, preheating of the water, and cooling of the combustion chamber walls. The steam outlet to the borehole is provided with pressure-responsive doors for closing the outlet in response to flameout. (DLC)

Fox, R.L.

1981-01-07T23:59:59.000Z

403

Greece licensing round to focus on western sedimentary basins  

SciTech Connect

New opportunities for international oil companies to explore for hydrocarbons in Greece will emerge shortly. Parliament ratified a new petroleum law in January 1995, and DEP-EKY SA will undertake an international licensing round for offshore-onshore areas mainly in western Greece during second half 1995. The paper describes the fold and thrust belt of western Greece; the Katakolon oil field; the tertiary basins of eastern Greece; the Prinos and Prinos North oil fields; and the Epanomi gas field.

Roussos, N.; Marnelis, F. (Public Petroleum Corp. of Greece, Athens (Greece))

1995-03-06T23:59:59.000Z

404

Rockies flood projects add to production  

Science Conference Proceedings (OSTI)

Nine new polymer waterfloods in the Rockies in the past year shows that tertiary recovery needn't be impeded by a $29/bbl oil price, so long as costs are held to a minimum. The uncertain fate faced by several expensive carbon dioxide pilots - even though recoveries have been or promise to be at or well above predictions - points up the overwhelming importance of keeping costs down.

Gill, D.

1983-09-01T23:59:59.000Z

405

Reconnaissance geological and mineral resource map of northern Sierra Madre Occidental, Mexico  

SciTech Connect

The northern Sierra Madre Occidental (SMO) map (scale 1:500,000) comprises 305,000 km/sup 2/ in the states of Chihuahau and Sonora. The centrally-located plateau section is divided into an upper, predominantly rhyolitic sequence, overlying an andesite-rich interval, directly correlatable with Tertiary volcanic units in central and southern SMO, respectively (Clark, 1983; 1984). Precambrian rocks occur in both flanks of SMO, either in the subsurface or surface exposures. They are succeeded by Early and Late Paleozoic sedimentary strata in Sonora and by a more discontinuous sequence in western Chihuahua. Mesozoic strata are dominated by Cretaceous carbonate sequences in central Chihuahua, and by late Triassic - Early Jurassic continental and Jurassic magmatic arc deposits in Sonora. Late Mesozoic - Early Cenozoic batholiths were emplaced in numerous localities in Sonora, whereas only isolated granitoid stocks are exposed in Chihuahua. Widespread lavas of basaltic composition are Late Tertiary to Quaternary in age. Late Cenozoic unconsolidated clastic deposits fill basins and constitute the coastal plain on the west. The main mineralizing epoch occurred in Late Cretaceous - Early Tertiary time, is aligned in northwesterly-trending belts and included numerous porphyry (Cu-Mo) deposits, scattered contact metasomatic (Cu-W) ores and a fissure-vein (Ag-Au) assemblage in the western margin; a (Pb-Zn-Ag) assemblage in fissure-veins and manto-chimney deposits, manganese and volcanogenic uranium ores in the eastern flank. Important industrial minerals and rocks include graphite, fluorspar and building materials.

Clark, K.F.

1985-01-01T23:59:59.000Z

406

The role of Cretaceous seal to the hydrocarbon potential of the Salawati and Bintuni basins, Irian Jaya, Indonesia  

SciTech Connect

The Salawati and Bintuni basins are late Tertiary depocenters located in the westernmost part of Irian Jaya, Indonesia. The two basins are closely located and only separated by a 50-km-wide structural high known as the Ajamaru Plateau. Petroleum exploration results in the Salawati basin are very successful. This basin has produced around 300 Mbbl of oil from the Miocene carbonates of the Kais Formation. Exploration with similar objectives in the Bintuni basin, however, gave only little success. Some oil was obtained from small Wasian and Mogoi fields, which jointly produced around 7 Mbbl of oil between 1951 and 1960. Extensive exploration campaigns between 1970 and 1980 with Miocene Kais Limestone as the objective resulted only in the discovery of the small Wiriagar field. The big difference in petroleum potentially of the Salawati and Bintuni basins has attracted explorationists to evaluate what significant geological factors had influenced it. Evaluation on available exploration data of the basins had some interesting results. In terms of geologic factors controlling hydrocarbon accumulation (presence of mature source rock, migration pathway, good reservoir quality, valid trap, and effective seal), it seems that shales of Cretaceous age have played the most important role. If this regional seal is absent or noneffective, oil could migrate vertically from pre-Tertiary sources to the Tertiary reservoirs. On the contrary, if the Cretaceous shales are present and sealing, then the underlying Mesozoic sequence is attractive and may trap hydrocarbon, if supported by the other geologic factors.

Samuel, L.; Kartanegara, L. (PERTAMINA, Jakarta (Indonesia))

1991-03-01T23:59:59.000Z

407

Completion Report for Well Cluster ER-6-1  

SciTech Connect

Well Cluster ER-6-1 was constructed for the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office in support of the Nevada Environmental Restoration Division at the Nevada Test Site, Nye County, Nevada. This work was initiated as part of the Groundwater Characterization Project, now known as the Underground Test Area Project. The well cluster is located in southeastern Yucca Flat. Detailed lithologic descriptions with stratigraphic assignments for Well Cluster ER-6-1 are included in this report. These are based on composite drill cuttings collected every 3 meters and conventional core samples taken below 639 meters, supplemented by geophysical log data. Detailed petrographic, chemical, and mineralogical studies of rock samples were conducted on 11 samples to resolve complex interrelationships between several of the Tertiary tuff units. Additionally, paleontological analyses by the U.S. Geological Survey confirmed the stratigraphic assignments below 539 meters within the Paleozoic sedimentary section. All three wells in the Well ER-6-1 cluster were drilled within the Quaternary and Tertiary alluvium section, the Tertiary volcanic section, and into the Paleozoic sedimentary section.

Bechtel Nevada

2004-10-01T23:59:59.000Z

408

Coanda injection system for axially staged low emission combustors  

SciTech Connect

The low emission combustor includes a combustor housing defining a combustion chamber having a plurality of combustion zones. A liner sleeve is disposed in the combustion housing with a gap formed between the liner sleeve and the combustor housing. A secondary nozzle is disposed along a centerline of the combustion chamber and configured to inject a first fluid comprising air, at least one diluent, fuel, or combinations thereof to a downstream side of a first combustion zone among the plurality of combustion zones. A plurality of primary fuel nozzles is disposed proximate to an upstream side of the combustion chamber and located around the secondary nozzle and configured to inject a second fluid comprising air and fuel to an upstream side of the first combustion zone. The combustor also includes a plurality of tertiary coanda nozzles. Each tertiary coanda nozzle is coupled to a respective dilution hole. The tertiary coanda nozzles are configured to inject a third fluid comprising air, at least one other diluent, fuel, or combinations thereof to one or more remaining combustion zones among the plurality of combustion zones.

Evulet, Andrei Tristan (Clifton Park, NY); Varatharajan, Balachandar (Cincinnati, OH); Kraemer, Gilbert Otto (Greer, SC); ElKady, Ahmed Mostafa (Niskayuna, NY); Lacy, Benjamin Paul (Greer, SC)

2012-05-15T23:59:59.000Z

409

Process for stabilization of coal liquid fractions  

SciTech Connect

Coal liquid fractions to be used as fuels are stabilized against gum formation and viscosity increases during storage, permitting the fuel to be burned as is, without further expensive treatments to remove gums or gum-forming materials. Stabilization is accomplished by addition of cyclohexanol or other simple inexpensive secondary and tertiary alcohols, secondary and tertiary amines, and ketones to such coal liquids at levels of 5-25% by weight with respect to the coal liquid being treated. Cyclohexanol is a particularly effective and cost-efficient stabilizer. Other stabilizers are isopropanol, diphenylmethanol, tertiary butanol, dipropylamine, triethylamine, diphenylamine, ethylmethylketone, cyclohexanone, methylphenylketone, and benzophenone. Experimental data indicate that stabilization is achieved by breaking hydrogen bonds between phenols in the coal liquid, thereby preventing or retarding oxidative coupling. In addition, it has been found that coal liquid fractions stabilized according to the invention can be mixed with petroleum-derived liquid fuels to produce mixtures in which gum deposition is prevented or reduced relative to similar mixtures not containing stabilizer.

Davies, Geoffrey (Boston, MA); El-Toukhy, Ahmed (Alexandria, EG)

1987-01-01T23:59:59.000Z

410

Completion Report for Well Cluster ER-5-4  

Science Conference Proceedings (OSTI)

Well Cluster ER-5-4 was drilled for the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office, in support of the Nevada Environmental Restoration Project at the Nevada Test Site, Nye County, Nevada. The cluster consists of two wells, positioned about 30 meters apart on the same drill pad, constructed as part of a hydrogeologic investigation program for Frenchman Flat at the Nevada Test Site. Detailed lithologic descriptions with preliminary stratigraphic assignments for the well cluster are included in this report. These are based on composite drill cuttings collected every 3 meters, and 156 sidewall samples taken at various depths below 192 meters in both boreholes, supplemented by geophysical log data. Detailed petrographic, chemical, and mineralogical studies of rock samples were conducted on 122 samples. Well ER-5-4 penetrated approximately 1,120 meters of Quaternary and Tertiary alluvium before reaching total depth in Tertiary volcanic rocks at 1,137.5 meters. The deeper Well ER-5-4 No.2 penetrated 1,120.4 meters of alluvial sediments, and was terminated within Tertiary volcanic rocks at a depth of 2,133.6 meters, indicating that Paleozoic rocks are deeper than expected at this site.

U.S. Department of Energy, National Nuclear Security Administration, Nevada Site Office; Bechtel Nevada

2005-02-01T23:59:59.000Z

411

Resource Assessment of the In-Place and Potentially Recoverable Deep Natural Gas Resource of the Onshore Interior Salt Basins, North Central and Northeastern Gulf of Mexico  

SciTech Connect

The principal research effort for Year 2 of the project has been petroleum system characterization and modeling. Understanding the burial, thermal maturation, and hydrocarbon expulsion histories of the strata in the onshore interior salt basins of the North Central and Northeastern Gulf of Mexico areas is important in hydrocarbon resource assessment. The underburden and overburden rocks in these basins and subbasins are a product of their rift-related geohistory. Petroleum source rock analysis and initial thermal maturation and hydrocarbon expulsion modeling indicated that an effective regional petroleum source rock in the onshore interior salt basins and subbasins, the North Louisiana Salt Basin, Mississippi Interior Salt Basin, Manila Subbasin and Conecuh Subbasin, was Upper Jurassic Smackover lime mudstone. The initial modeling also indicated that hydrocarbon generation and expulsion were initiated in the Early Cretaceous and continued into the Tertiary in the North Louisiana Salt Basin and the Mississippi Interior Salt Basin and that hydrocarbon generation and expulsion were initiated in the Late Cretaceous and continued into the Tertiary in the Manila Subbasin and Conecuh Subbasin. Refined thermal maturation and hydrocarbon expulsion modeling and additional petroleum source rock analysis have confirmed that the major source rock in the onshore interior salt basins and subbasins is Upper Jurassic Smackover lime mudstone. Hydrocarbon generation and expulsion were initiated in the Early to Late Cretaceous and continued into the Tertiary.

Ernest A. Mancini; Paul Aharon; Donald A. Goddard; Roger Barnaby

2005-10-28T23:59:59.000Z

412

Microfossils from Cerro Prieto geothermal wells, Baja California, Mexico  

DOE Green Energy (OSTI)

To aid in a paleoenvironmental and age reconstruction of the Cerro Prieto reservoir system, 59 samples of well cuttings were analyzed for microfossils. The cuttings were obtained at depths from 351 to 3495 m in 14 geothermal wells in the Cerro Prieto field, Baja California, Mexico. We found foraminifera in 6 samples, ostracodes in 19 samples, and nannoplankton as coccoliths in 24 samples. Other groups, such as molluscs, insects, fish skeletal parts, and plant material were occasionally present. Detailed interpretations are not possible at this time because of poor preservation of samples. This is primarily due to causes: dissolution by geothermal fluids that reach 350{sup 0}C, and the extensive mixing of filled Cretaceous forms (reworked from the Colorado Plateau region) with Tertiary species during drilling. Further studies of ostracodes and foraminifera from colder portions of the wells are needed. The abundant and well-preserved ostracodes indicate marine to brackish water environments that correspond, in part, to lagoonal or estuarine facies. The presence of the mid-Tertiary (15-My-old) marine foraminifera, Cassigerinela chipolensis, in wells M-11 and M-38, 350 to 500 m deep, is perplexing. These are not laboratory contaminates and, as yet, have not been found in the drilling mud. If further studies confirm their presence at Cerro Prieto, established ideas about the opening of the Gulf of California and about Pacific Coast mid-Tertiary history will need to be rewritten.

Cotton, M.L.; Vonder Haar, S.

1980-01-01T23:59:59.000Z

413

Long-life high performance fuel cell program. Interim Report, 28 May 1981-31 October 1984  

SciTech Connect

A multihundred kilowatt Regenerative Fuel Cell for use in a space station is envisioned. Three 0.508 sq ft (471.9 cm) active area multicell stacks were assembled and endurance tested. The long term performance stability of the platinum on carbon catalyst configuration suitability of the lightweight graphite electrolyte reservoir plate, the stability of the free standing butyl bonded potassium titanate matrix structure, and the long life potential of a hybrid polysulfone cell edge frame construction were demonstrated. A 18,000 hour demonstration test of multicell stack to a continuous cyclical load profile was conducted. A total of 12,000 cycles was completed, confirming the ability of the alkaline fuel cell to operate to a load profile simulating Regenerative Fuel Cell operation. An orbiter production hydrogen recirculation pump employed in support of the cyclical load profile test completed 13,000 hours of maintenance free operation. Laboratory endurance tests demonstrated the suitability of the butyl bonded potassium matrix, perforated nickel foil electrode substrates, and carbon ribbed substrate anode for use in the alkaline fuel cell. Corrosion testing of materials at 250 F (121.1 C) in 42% wgt. potassium identified ceria, zirconia, strontium titanate, strontium zirconate and lithium cobaltate as candidate matrix materials.

Martin, R.E.

1985-02-01T23:59:59.000Z

414

Physicochemical properties and toxicities of hydrophobic piperidinium and  

NLE Websites -- All DOE Office Websites (Extended Search)

Physicochemical properties and toxicities of hydrophobic piperidinium and Physicochemical properties and toxicities of hydrophobic piperidinium and pyrrolidinium ionic liquids Title Physicochemical properties and toxicities of hydrophobic piperidinium and pyrrolidinium ionic liquids Publication Type Journal Article Year of Publication 2007 Authors Salminen, Justin, Nicolas Papaiconomou, Anand R. Kumar, Jong-Min Lee, John B. Kerr, John S. Newman, and John M. Prausnitz Journal Fluid Phase Equilibria Volume 261 Pagination 421-426 Keywords hydrophobic, ionic liquids, piperidinium, properties, pyrrolidinium, safety, toxicity Abstract Some properties are reported for hydrophobic ionic liquids (IL) containing 1-methyl-1-propyl pyrrolidinium [MPPyrro]+, 1-methyl-1-butyl pyrrolidinium [MBPyrro]+, 1-methyl-1-propyl piperidinium [MPPip]+, 1-methyl-1-butyl piperidinium [MBPip]+, 1-methyl-1-octyl pyrrolidinium [MOPyrro]+ and 1-methyl-1-octyl piperidinium [MOPip]+ cations. These liquids provide new alternatives to pyridinium and imidazolium ILs. High thermal stability of an ionic liquid increases safety in applications like rechargeable lithium-ion batteries and other electrochemical devices. Thermal properties, ionic conductivities, viscosities, and mutual solubilities with water are reported. In addition, toxicities of selected ionic liquids have been measured using a human cancer cell line. The ILs studied here are sparingly soluble in water but hygroscopic. We show some structure-property relationships that may help to design green solvents for specific applications. While ionic liquids are claimed to be environmentally benign solvents, as yet few data have been published to support these claims.

415

Fused ring and linking groups effect on overcharge protection for lithium-ion batteries.  

DOE Green Energy (OSTI)

The derivatives of 1,3-benzodioxan (DBBD1) and 1,4-benzodioxan (DBBD2) bearing two tert-butyl groups have been synthesized as new redox shuttle additives for overcharge protection of lithium-ion batteries. Both compounds exhibit a reversible redox wave over 4 V vs Li/Li{sup +} with better solubility in a commercial electrolyte (1.2 M LiPF{sub 6}) dissolved in ethylene carbonate/ethyl methyl carbonate (EC/EMC 3/7) than the di-tert-butyl-substituted 1,4-dimethoxybenzene (DDB). The electrochemical stability of DBBD1 and DBBD2 was tested under charge/discharge cycles with 100% overcharge at each cycle in MCMB/LiFePO{sub 4} and Li{sub 4}Ti{sub 5}O{sub 12}/LiFePO{sub 4} cells. DBBD2 shows significantly better performance than DBBD1 for both cell chemistries. The structural difference and reaction energies for decomposition have been studied by density functional calculations.

Weng, W.; Zhang, Z.; Redfern, P. C.; Curtiss, L. A.; Amine, K.

2011-02-01T23:59:59.000Z

416

Catalytic conversion of light alkanes - phase V. Topical report, February 1993--October 1994  

SciTech Connect

We have made excellent progress toward a practical route from field butanes to MTBE, the oxygenate of choice for high-octane, clean-burning, environmentally acceptable reformulated gasoline. We have evaluated two proprietary process possibilities with a potential commercial partner and have conducted a joint catalyst evaluation program. The first of the two potential processes considered during the past quarter utilizes a two-step route from isobutane to tert-butyl alcohol, TBA. Not only is TBA an intermediate for MTBE production but is equally applicable for ETBE-an oxygenate which utilizes renewable ethanol in its` manufacture. In the two-step process, isobutane is oxidized in a non-catalytic reaction to a roughly equal mixture of TBA and tert-butyl hydroperoxide. TBHP, eq. 1. We have developed an inexpensive new catalyst system based on an electron-deficient macrocyclic metal complex that selectively converts TBHP to TBA, eq. 2, and meets or exceeds all of the process criteria that we have set.

1998-12-31T23:59:59.000Z

417

Arco chimie focuses on PA at FOS  

Science Conference Proceedings (OSTI)

Arco Chimie France (Fos-sur-Mer), at a recent meeting at its southern France manufacturing site, emphasized that future strategy is strongly focused on its propylene oxide (PO) and derivatives activities. The F2.5 billion ($466 million)-Fe billion/year operation manufactures 200,000 m.t./year of PO, about 70% for captive use and the balance for the merchant market; 550,000 m.t./year of methyl tert butyl ether (MTBE); 97,000 m.t./year of polyols; and 70,000 m.t./year of propylene glycols. There has been talk of Arco modifying its Fos MTBE plant to make it flexible for ethyl tert-butyl ether (ETBE) output; the parent company already operates an MTBE/ETBE pilot unit at Corpus Christi, TX. But Arco Chimie notes there is insufficient bioethanol feedstock availability to convert all production to ETBE. The company would also require investment in new storage capacity for ethanol and ETBE. However, France's biofuels program is not yet clearly defined, and it is politically sensitive because it depends heavily on government subsidies offered to farmers. That, says Arco, makes it impossible to have an accurate idea of how much ethanol will be available.

Jackson, D.

1992-12-02T23:59:59.000Z

418

Phase selectively soluble polymer supports to facilitate homogeneous catalysis  

E-Print Network (OSTI)

Soluble polymers that have phase selective solubility are useful in synthesis because they simplify purification and separation. Such selectively soluble polymers simplify catalyst, reagent, and product recovery and enable the use of Green chemistry principles in homogeneous catalysis. However, while homopolymers have been reported that have excellent thermal and phase-dependent solubility, less is known about copolymers. Also, less is known about the phase selective solubility of polar aprotic N,N-dialkyl polyacrylamides. This work describes a library synthesis of dye-labeled poly(N-n-octadecylacrylamide-co-N-n-butylacrylamide) copolymers and study of the effects of polymer composition in phase selective solubility of these copolymers. To study the relative importance of n-octadecyl versus n-butyl groups, copolymers with different ratios of n-octadecylacrylamide and n-butylacrylamide but with similar degrees of polymerization and polydispersity were prepared by a split-pool synthesis using a highly soluble poly(N-acryloxy-2-dodecylsuccinimide) as the precursor. Polymer sequestrants were used to remove excess amines and the byproduct N-hydroxyl-2- dodecylsuccinimide without fractionation of the polyacrylamides. Results demonstrated that poly(N-n-octadecylacrylamide-co-N-n-butylacrylamide) copolymers’ phase selective solubility is equally dependant of the polar n-butyl and nonpolar n-octadecyl groups on the copolymers. Dye-labeled poly(N,N-dialkylacrylamide)s prepared by the polymerization of N,N-dialkylacrylamides monomers with methyl, ethyl, propyl, butyl, hexyl, and dodecyl N-alkyl groups in a variety of thermomorphic or latent biphasic polar/nonpolar solvent mixtures were also prepared. Studies showed that poly(N,N-dialkylacrylamide)s have phase selective solubility that is highly dependent of the size of the N-alkyl group. Soluble polymers are known to be useful supports for catalysts. This thesis also describes approaches to immobilization of a variety of catalysts on polyisobutylene (PIB). The most effective of these catalysts were analogs of pyridyl N-oxides that have been used as organocatalysts for the catalytic allylation of a variety of aromatic aldehydes. PIB-supported N-oxide promoted the allylation of aldehydes in up to 99% isolated yield. The products were isolated in the polar phase of a thermomorphic system and the catalyst was recycled through five cycles.

Ortiz-Acosta, Denisse

2007-12-01T23:59:59.000Z

419

Biomimetic oxidation studies. 11: Alkane functionalization in aqueous solution utilizing in situ formed [Fe{sub 2}O({eta}{sup 1}-H{sub 2}O)({eta}{sup 1}-OAc)(TPA){sub 2}]{sup 3+}, as an MMO model precatalyst, embedded in surface-derivatized silica and contained in micelles  

Science Conference Proceedings (OSTI)

The biomimetic, methane monooxygenase enzyme (MMO) precatalyst, [Fe{sub 2}O({eta}{sup 1}-H{sub 2}O)({eta}{sup 1}-OAc)(TPA){sub 2}]{sup 3+} (TPA = tris[(2-pyridyl)methyl]amine), 1, formed in situ at pH 4.2 from [Fe{sub 2}O({mu}-OAc)(TPA){sub 2}]{sup 3+}, 2, was embedded in an amorphous silicate surface modified by a combination of hydrophilic poly(ethylene oxide) and hydrophobic poly(propylene oxide). The resulting catalytic assembly was found to be a biomimetic model for the MMO active site within a hydrophobic macroenvironment, allowing alkane functionalization with tert-butyl hydroperoxide (TBHP)/O{sub 2} in an aqueous reaction medium (pH 4.2). For example, cyclohexane was oxidized to a mixture of cyclohexanone, cyclohexanol, and cyclohexyl-tert-butyl peroxide, in a ratio of {approximately}3:1:2. The balance between poly(ethylene oxide) and poly(propylene oxide), tethered on the silica surface, was crucial for maximizing the catalytic activity. The silica-based catalytic assembly showed reactivity somewhat higher in comparison to an aqueous micelle system utilizing the surfactant, cetyltrimethylammonium hydrogen sulfate at its critical micelle concentration, in which functionalization of cyclohexane with TBHP/O{sub 2} in the presence of 1 was also studied at pH 4.2 and was found to provide similar products: cyclohexanol, cyclohexanone, and cyclohexyl-tert-butyl peroxide, in a ratio of {approximately}2:3:1. Moreover, the mechanism for both the silica-based catalytic assembly and the aqueous micelle system was found to occur via the Haber-Weiss process, in which redox chemistry between 1 and TBHP provides both the t-BuO{sup {sm_bullet}} and t-BuOO{sup {sm_bullet}} radicals. The t-BuO{sup {sm_bullet}} radical initiates the C-H functionalization reaction to form the carbon radical, followed by O{sub 2} trapping, to provide cyclohexyl hydroperoxide, which produces the cyclohexanol and cyclohexanone in the presence of 1, whereas the coupling product emanates from t-BuOO{sup {sm_bullet}} and cyclohexyl radicals. A discussion concerning both approaches for alkane functionalization in water will be presented.

Neimann, K.; Neumann, R. [Hebrew Univ., Jerusalem (Israel); Rabion, A. [Lawrence Berkeley National Lab., CA (United States)]|[Groupement de Recherche de Lacq, Artix (France); Buchanan, R.M. [Univ. of Louisville, KY (United States). Dept. of Chemistry; Fish, R.H. [Lawrence Berkeley National Lab., CA (United States)

1999-07-26T23:59:59.000Z

420

NETL: Water-Energy Interface - Power Plant Water Management  

NLE Websites -- All DOE Office Websites (Extended Search)

Use of Treated Municipal Wastewater as Power Plant Cooling System Makeup Water: Tertiary Treatment versus Expanded Chemical Regimen for Recirculating Water Quality Management Use of Treated Municipal Wastewater as Power Plant Cooling System Makeup Water: Tertiary Treatment versus Expanded Chemical Regimen for Recirculating Water Quality Management Carnegie Mellon University, in a joint effort with the University of Pittsburgh, is conducting a study of the use of treated municipal wastewater as cooling system makeup for coal fired power plants. This project builds upon a study sponsored by the U.S. Department of Energy entitled, "Reuse of Treated Internal or External Wastewaters in the Cooling Systems of Coal-Based Thermoelectric Power Plants," which showed that treated municipal wastewater is the most common and widespread source in the United States. Data analysis revealed that 81 percent of power plants proposed for construction by the Energy Information Administration (EIA) would have sufficient cooling water supply from one to two publicly owned treatment works (POTW) within a 10-mile radius, while 97 percent of the proposed power plants would be able to meet their cooling water needs with one to two POTWs within 25 miles of these plants. Thus, municipal wastewater will be the impaired water source most likely to be locally available in sufficient and reliable quantities for power plants. Results of initial studies indicate that it is feasible to use secondary treated municipal wastewater as cooling system makeup. The biodegradable organic matter, ammonia-nitrogen, and phosphorus in the treated wastewater pose challenges with respect to enhanced biofouling, corrosion, and scaling, although current research is demonstrating that these problems can be controlled through aggressive chemical management. It is currently unclear whether tertiary treatment of municipal waste water prior to its re-use can be a cost-effective option to aggressive chemical management of the bulk cooling water volume.

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Verification of Allowable Stresses In ASME Section III Subsection NH For Grade 91 Steel & Alloy 800H  

Science Conference Proceedings (OSTI)

The database for the creep-rupture of 9Cr-1Mo-V (Grade 91) steel was collected and reviewed to determine if it met the needs for recommending time-dependent strength values, S{sub t}, for coverage in ASME Section III Subsection NH (ASME III-NH) to 650 C (1200 F) and 600,000 hours. The accumulated database included over 300 tests for 1% total strain, nearly 400 tests for tertiary creep, and nearly 1700 tests to rupture. Procedures for analyzing creep and rupture data for ASME III-NH were reviewed and compared to the procedures used to develop the current allowable stress values for Gr 91 for ASME II-D. The criteria in ASME III-NH for estimating S{sub t} included the average strength for 1% total strain for times to 600,000 hours, 80% of the minimum strength for tertiary creep for times to 600,000 hours, and 67% of the minimum rupture strength values for times to 600,000 hours. Time-temperature-stress parametric formulations were selected to correlate the data and make predictions of the long-time strength. It was found that the stress corresponding to 1% total strain and the initiation of tertiary creep were not the controlling criteria over the temperature-time range of concern. It was found that small adjustments to the current values in III-NH could be introduced but that the existing values were conservative and could be retained. The existing database was found to be adequate to extend the coverage to 600,000 hours for temperatures below 650 C (1200 F).

R. W. Swindeman; M. J. Swindeman; B. W. Roberts; B. E. Thurgood; D. L. Marriott

2007-11-30T23:59:59.000Z

422

Completion Report for Well ER-12-3 Corrective Action Unit 99: Rainier Mesa - Shoshone Mountain  

Science Conference Proceedings (OSTI)

Well ER-12-3 was drilled for the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office, in support of the Nevada Environmental Restoration Project at the Nevada Test Site, Nye County, Nevada. The well was drilled in March and April 2005 as part of a hydrogeologic investigation program for the Rainier Mesa-Shoshone Mountain Corrective Action Unit. The overall purpose of the well was to gather subsurface data to better characterize the hydrogeology of central Rainier Mesa, especially in the older Tertiary volcanic rocks and Paleozoic sedimentary rocks. The main 47.0-centimeter hole was drilled to a depth of 799.2 meters and cased with 33.97-centimeter casing to 743.1 meters. The hole diameter was then decreased to 31.1 centimeters, and the well was drilled to a total depth of 1,496.0 meters. The completion string consisted of 13.97-centimeter stainless steel casing, with two slotted intervals open to the lower carbonate aquifer, suspended from 19.37-centimeter carbon steel casing. A piezometer string was installed outside the 33.97-centimeter casing to a depth of 467.1 meters to monitor a zone of perched water within the Tertiary volcanic section. Data gathered during and shortly after hole construction include composite drill cuttings samples collected every 3 meters (extra cuttings samples were collected from the Paleozoic rocks for paleontological analyses), sidewall core samples from 35 depths, various geophysical logs, and water level measurements. These data indicate that the well penetrated 674.2 meters of Tertiary volcanic rocks and 821.7 meters of Paleozoic dolomite and limestone. Forty-nine days after the well was completed, but prior to well development and testing, the water level inside the main hole was tagged at the depth of 949.1 meters, and the water level inside the piezometer string was tagged at 379.9 meters.

U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office; Bechtel Nevada Corporation

2006-05-01T23:59:59.000Z

423

Uranium potential of southwestern New Mexico (southern Hidalgo County), including observations on crystallization history of lavas and ash tuffs and the release of uranium from them. Final report  

SciTech Connect

Geological environments present in southwestern New Mexico include thick sequences of sedimentary rock including limestone, conglomerates, sandstone, and shale: igneous intrusions with associated metal deposits; caldera centers, margins, and outflow facies; and basins with marginal faults and thick late Cenozoic sedimentary fillings. Predominant rock types are Paleozoic carbonates, Mesozoic terrigeneous rocks and carbonates, and Cenozoic volcanic rocks and basin-filling terrigeneous rocks. Consideration of information available in Preliminary Reconnaissance Reports and in Hydrogeochemical and Stream Reconnaissance Reports together with 347 new whole rock chemical analyses points to three areas of anomalous uranium abundance in Hidalgo County, New Mexico. The area has experienced three major periods of igneous activity in Phanerozoic time: one associated with the Laramide cycle of the Late Cretaceous and early Tertiary, mid-Tertiary cycle of silicic volcanism with abundant calderas, and a late Tertiary cycle of mafic volcanism. Silicic volcanic rocks are the most common exposed rock type in the area, and the most enriched in uranium (range, 0.4 to 19 ppM). The most likely source for any uranium ore-forming solutions lies with this cycle of volcanism. Solutions might have been introduced during volcanism or formed later by groundwater leaching of cooled volcanic rocks. Results indicate that groundwater leaching of cooled volcanic rocks was not an effective means of mobilizing uranium in the area. Study of several rhyolite lava flows indicates that they were emplaced in supercooled condition and may have crystallized completely at temperatures well below their liquids, or they may have warmed as crystallization released latent heat. Statistical comparison of the uranium concentration revealed no differences between vitrophyres and associated felsites.

Walton, A.W.; Salter, T.L.; Zetterlund, D.

1980-08-01T23:59:59.000Z

424

Why Sequence Pseudonocardia dioxanivorans?  

NLE Websites -- All DOE Office Websites (Extended Search)

Pseudonocardia dioxanivorans? Pseudonocardia dioxanivorans? Ethers such as 1,4-dioxane, tetrahydrofuran, and methyl tert-butyl ether are widespread contaminants of groundwater resources. 1,4-Dioxane is widely used as a stabilizer for chlorinated solvents such as 1,1,1-trichloroethane (TCA). 1,4-Dioxane is a carcinogen, and causes acute toxic effects on the nervous system, liver, and kidneys. One promising approach for remediating 1,4-dioxane-impacted water supplies is in-situ bioremediation using aerobic bacteria. Pseudonocardia dioxanivorans CB1190 is a unique bacterial strain that can grow using 1,4-dioxane as a sole source of carbon and energy. It can degrade several other water contaminants and also fix dinitrogen, making it an attractive bioaugmentation culture even for nitrogen-limited

425

A Comparison of Electron-Transfer Dynamics in Ionic Liquids and Neutral  

NLE Websites -- All DOE Office Websites (Extended Search)

Electron-Transfer Dynamics in Ionic Liquids and Neutral Electron-Transfer Dynamics in Ionic Liquids and Neutral Solvents Heather Y. Lee, Joseph B. Issa, Stephan S. Isied, Edward W. Castner, Jr., Yunfeng Pan, Charles L. Hussey, Kwang Soon Lee, and James F. Wishart J. Phys. Chem. C 116, 5197-5208 (2012). [Find paper at ACS Publications] or use ACS Articles on Request. Abstract: The effect of ionic liquids on photoinduced electron-transfer reactions in a donor-bridge-acceptor system is examined for two ionic liquid solvents, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide and tributylmethylammonium bis(trifluoromethyl¬sulfonyl)¬amide. The results are compared with those for the same system in methanol and acetonitrile solution. Electron-transfer rates were measured using time-resolved fluorescence quenching for the donor-bridge-acceptor system comprising a

426

fulltext.pdf  

NLE Websites -- All DOE Office Websites (Extended Search)

Cellulose Cellulose solvent-based pretreatment for corn stover and avicel: concentrated phosphoric acid versus ionic liquid [BMIM]Cl Noppadon Sathitsuksanoh * Zhiguang Zhu * Y.-H. Percival Zhang Received: 27 October 2011 / Accepted: 26 April 2012 Ó Springer Science+Business Media B.V. 2012 Abstract Since cellulose accessibility has become more recognized as the major substrate characteristic limiting hydrolysis rates and glucan digestibilities, cellulose solvent-based lignocellulose pretreatments have gained attention. In this study, we employed cellulose solvent- and organic solvent-based lignocel- lulose fractionation using two cellulose solvents: concentrated phosphoric acid [*85 % (w/w) H 3 PO 4 ] and an ionic liquid Butyl-3-methylimidazolium chlo- ride ([BMIM]Cl). Enzymatic glucan digestibilities of concentrated phosphoric acid- and [BMIM]Cl-pre- treated

427

Why sequence ethene and vinyl chloride-oxidizing Mycobacterium strains?  

NLE Websites -- All DOE Office Websites (Extended Search)

sequence ethene and vinyl sequence ethene and vinyl chloride-oxidizing Mycobacterium strains? Mycobacteria are known for causing human and animal diseases but they are also important degraders of hard-to-break-down water contaminants such as polyaromatic hydrocarbons (PAHs) and methyl tert-butyl ether (MTBE). So far the handful of bacterial species representing the Mycobacterium genus that have been sequenced all break down PAHs. In this project, researchers focus on the genomes of mycobacterial species isolated from soil, freshwater and marine environments that use the alkene compounds ethene and vinyl chloride as carbon sources. Chlorinated ethene compounds are difficult to remove from contaminated groundwater but necessary because of their toxicity. Additionally these compounds reduce the ozone levels in the atmosphere.

428

10.1007%2Fs10570-013-0018-0.pdf  

NLE Websites -- All DOE Office Websites (Extended Search)

Simulation Simulation of a cellulose fiber in ionic liquid suggests a synergistic approach to dissolution Barmak Mostofian * Jeremy C. Smith * Xiaolin Cheng Received: 24 April 2013 / Accepted: 1 August 2013 Ó Springer Science+Business Media Dordrecht (outside the USA) 2013 Abstract Ionic liquids dissolve cellulose in a more efficient and environmentally acceptable way than conventional methods in aqueous solution. An under- standing of how ionic liquids act on cellulose is essential for improving pretreatment conditions and thus detailed knowledge of the interactions between the cations, anions and cellulose is necessary. Here, to explore ionic liquid effects, we perform all-atom molecular dynamics simulations of a cellulose microfibril in 1-butyl-3- methylimidazolium chloride and analyze site-site inter- actions and cation orientations at the solute-solvent interface. The

429

Chain Transfer of Vegetable Oil Macromonomers in Acrylic Solution Copolymerization  

Science Conference Proceedings (OSTI)

Use of vegetable oil macromonomers (VOMMs) as comonomers in emulsion polymerization enables good film coalescence without the addition of solvents that constitute volatile organic compounds (VOCs). VOMMs are derived from renewable resources and offer the potential of post-application crosslinking via auto-oxidation. However, chain transfer reactions of VOMMs with initiator and/or polymer radicals during emulsion polymerization reduce the amount of allylic hydrogen atoms available for primary auto-oxidation during drying. Vegetable oils and derivatives were reacted in combination with butyl acrylate and methyl methacrylate via solution polymerization. The copolymerization was monitored using in situ infrared spectroscopy to determine the extent of chain transfer. 1H NMR spectroscopy was used to determine the loci of chain transfer and the molecular weight characteristics of the polymers were characterized by SEC. Solution polymerization was utilized to minimize temperature fluctuations and maintain polymer solubility during the initial characterization.

Black, Micah [University of Southern Mississippi, The; Messman, Jamie M [ORNL; Rawlins, James [University of Southern Mississippi, The

2011-01-01T23:59:59.000Z

430

Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

19 results: 19 results: BibTex RIS RTF XML Sort by: Author Title Type [ Year (Desc) ] Filters: Author is John B. Kerr [Clear All Filters] 2012 Zhu, Xiaobing, John B. Kerr, Qinggang He, Gi Suk Hwang, Zulima Martin, Kyle Clark, Adam Z. Weber, and Nana Zhao. "Bridge to Fuel Cell Molecular Catalysis: 3D Non-Platinum Group Metal Catalyst in MEAs." ECS Transactions 45, no. 2 (2012): 143-152. 2008 Shin, Joon Ho, Pratyay Basak, John B. Kerr, and Elton J. Cairns. "Rechargeable Li/LiFePO4 Cells Using N-Methyl-N-butyl pyrrolidinium Bis(trifluoromethane sulfonyl)imide-LiTFSI Electrolyte Incorporating Polymer Additives." Electrochimica Acta 54, no. 2 (2008): 410-414. Hardwick, Laurence J., Marek Marcinek, Leanne Beer, John B. Kerr, and Robert Kostecki. "An Investigation of the effect of graphite degradation on

431

Alternative Fuels Data Center: Biobutanol  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Biobutanol to someone Biobutanol to someone by E-mail Share Alternative Fuels Data Center: Biobutanol on Facebook Tweet about Alternative Fuels Data Center: Biobutanol on Twitter Bookmark Alternative Fuels Data Center: Biobutanol on Google Bookmark Alternative Fuels Data Center: Biobutanol on Delicious Rank Alternative Fuels Data Center: Biobutanol on Digg Find More places to share Alternative Fuels Data Center: Biobutanol on AddThis.com... More in this section... Biobutanol Drop-In Biofuels Methanol P-Series Renewable Natural Gas xTL Fuels Biobutanol Biobutanol is a 4-carbon alcohol (butyl alcohol) produced from the same feedstocks as ethanol including corn, sugar beets, and other biomass feedstocks. Butanol is generally used as an industrial solvent in products such as lacquers and enamels, but it also can be blended with other fuels

432

Ecological hazards of MTBE exposure: A research agenda  

DOE Green Energy (OSTI)

Fuel oxygenates are used in metropolitan areas across the United States in order to reduce the amount of carbon monoxide released into the atmosphere during the winter. The most commonly used fuel oxygenate is Methyl tert-butyl ether (MTBE). Its widespread use has resulted in releases into the environment. To date there has been only minimal effort to investigate ecological impacts caused by exposure to concentrations of MTBE typically found in environmental media. Research into the potential for MTBE to adversely affect ecological receptors is essential. Acquisition of such baselines data is especially critical in light of continuing inputs and potential accumulation of MTBE in environmental media. A research Agenda is included in this report and addresses: Assessing Ecological Impacts, Potential Ecological Impacts of MTBE (aquatic organisms, terrestrial organisms), Potential Ecological Endpoints, and A Summary of Research Needs.

Carlsen, T.; Hall, L.; Rice, D.

1997-03-01T23:59:59.000Z

433

Haze Formation and Behavior in Liquid-Liquid Extraction Processes  

Science Conference Proceedings (OSTI)

Aqueous haze formation and behavior was studied in the liquid-liquid system tri-n-butyl phosphate in odorless kerosene and 3M nitric acid with uranyl nitrate and cesium nitrate representing the major solute and an impurity, respectively. A pulsed column, mixer-settler and centrifugal contactor were chosen to investigate the effect of different turbulence characteristics on the manifestation of haze since these contactors exhibit distinct mixing phenomena. The dispersive processes of drop coalescence and breakage, and water precipitation in the organic phase were observed to lead to the formation of haze drops of {approx}1 um in diameter. The interaction between the haze and primary drops of the dispersion was critical to the separation efficiency of the liquid-liquid extraction equipment. Conditions of high power input and spatially homogeneous mixing enabled the haze drops to become rapidly assimilated within the dispersion to maximize the scrub performance and separation efficiency of the equipment.

Arm, Stuart T.; Jenkins, J. A.

2006-07-31T23:59:59.000Z

434

Method for cleaning solution used in nuclear-fuel reprocessing. [DOE patent application  

DOE Patents (OSTI)

A nuclear fuel processing solution containing: (1) hydrocarbon diluent; (2) tri-n-butyl phosphate or tri-2-ethylhexyl phosphate; and (3) monobutyl phosphate, dibutyl phosphate, mono-2-ethylhexyl phosphate, di-2-ethylhexyl phosphate, or a complex formed by plutonium, uranium, or a fission product thereof with monobutyl phosphate, dibutyl phosphate, mono-2-ethylhexyl phosphate, or di-2-ethylhexyl phosphate is contacted with silica gel having alkali ions absorbed thereon to remove any degradation products from said solution. The principal impurities removed from TBP solvent by the process of this invention are monobutyl phosphate, dibutyl phosphate, UO/sub 2//sup 2 +/, Pu/sup 4 +/, and fission products of plutonium and uranium complexed with monobutyl phosphate or dibutyl phosphate. Nitric acid is also removed from the TBP solution by the treated silica gel. Conventional adsorption column techniques are applicable for the process of the invention.

Tallent, O.K.; Dodson, K.E.; Mailen, J.C.

1981-05-12T23:59:59.000Z

435

APPLICATIONS OF LAYERED DOUBLE HYDROXIDES IN REMOVING OXYANIONS FROM OIL REFINING AND COAL MINING WASTEWATER  

SciTech Connect

Western Research Institute (WRI), in conjunction with the U.S. Department of Energy (DOE), conducted a study of using the layered double hydroxides (LDH) as filter material to remove microorganisms, large biological molecules, certain anions and toxic oxyanions from various waste streams, including wastewater from refineries. Results demonstrate that LDH has a high adsorbing capability to those compounds with negative surface charge. Constituents studied include model bacteria, viruses, arsenic, selenium, vanadium, diesel range hydrocarbons, methyl tert-butyl ether (MTBE), mixed petroleum constituents, humic materials and anions. This project also attempted to modify the physical structure of LDH for the application as a filtration material. Flow characterizations of the modified LDH materials were also investigated. Results to date indicate that LDH is a cost-effective new material to be used for wastewater treatment, especially for the treatment of anions and oxyanions.

Song Jin; Paul Fallgren

2006-03-01T23:59:59.000Z

436

Delayed cure bismaleimide resins  

DOE Patents (OSTI)

Polybismaleimides prepared by delayed curing of bis-imides having the formula ##STR1## wherein R.sub.1 and R.sub.2 each independently is H, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, Cl or Br, or R.sub.1 and R.sub.2 together form a fused 6-membered hydrocarbon aromatic ring, with the proviso that R.sub.1 and R.sub.2 are not t-butyl or t-butoxy; X is O, S or Se; n is 1-3; and the --(CH.sub.2).sub.n -- group, optionally, is substituted by 1-3 methyl groups or by fluorine.

Adams, Johnnie E. (Grandview, MO); Jamieson, Donald R. (Merriam, KS)

1984-08-07T23:59:59.000Z

437

Bismaleimide compounds  

DOE Patents (OSTI)

Bismaleimides of the formula ##STR1## wherein R.sub.1 and R.sub.2 each independently is H, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, C1 or Br, or R.sub.1 and R.sub.2 together form a fused 6-membered hydrocarbon aromatic ring, with the proviso that R.sub.1 and R.sub.2 are not t-butyl or t-butoxy; X is O, S or Se; n is 1-3; and the alkylene bridging group, optionally, is substituted by 1-3 methyl groups or by fluorine, form polybismaleimide resins which have valuable physical properties. Uniquely, these compounds permit extended cure times, i.e., they remain fluid for a time sufficient to permit the formation of a homogeneous melt prior to curing.

Adams, Johnnie E. (Grandview, MO); Jamieson, Donald R. (Merriam, KS)

1986-01-14T23:59:59.000Z

438

High temperature concrete composites containing organosiloxane crosslinked copolymers  

DOE Patents (OSTI)

This invention relates to high temperature polymer concrete composites comprising about 10-30% by weight of a liquid monomer mixture consisting essentially of an organosiloxane polymer crosslinked with an olefinically unsaturated monomer selected from the group consisting of styrene, methyl methacrylate, trimethylolpropane trimethacrylate, triallyl cyanurate, n-phenylmalimide, divinyl benzene and mixtures theroef; and about 70-90% by weight of an inert inorganic filler system containing silica sand and preferably a member selected from the group consisting of portland cement, Fe.sub.2 O.sub.3, carbon black and mixtures thereof; and optionally a free radical initiator such as di-tert-butyl peroxide, azobisisobutyronitrile, benzoyl peroxide, lauryl peroxide and other organic peroxides to initiate crosspolymerization of the monomer mixture in the presence of the inorganic filler.

Zeldin, Arkady (Rego Park, NY); Carciello, Neal (Patchogue, NY); Kukacka, Lawrence (Port Jefferson, NY); Fontana, Jack (Shoreham, NY)

1980-01-01T23:59:59.000Z

439

PREPARATION OF HIGH PURITY UF$sub 4$  

DOE Patents (OSTI)

S>A process for preparing very highly pure uranous tetrafluoride from impure uranium laden solvent extraction strip solutions, ion exchange process and resin-inpulp process eluate solutions which are at least 8M in hydrochloric acid is described. The process first comprises treating any of the above-mentioned solutions with a reducing agent to reduce the uranium to the + 4 oxidation state, and then contacting the reduced solution with an extractant phase comprising about 10 to 70% of tri-butyl phosphate in an organic solvent-diluent selected from benzene, ethyl-benzene, chlorobenzene, xylene, kerosene, or the like. The uranium is extracted into the extractant phase and is subsequently precipitated by treating the extractant with an aqueous fluoride solution. The highly pure uranous tetrafluoride precipitate is separated from the phases and recovered for subsequent utilization. (AEC)

Magner, J.E.; Long, R.S.; Ellis, D.A.; Grinstead, R.R.

1962-04-17T23:59:59.000Z

440

The Influence of the Linker Geometry in Bis(3-hydroxy-N-methyl-pyridin-2-one) Ligands on Solution-Phase Uranyl Affinity  

SciTech Connect

Seven water-soluble, tetradentate bis(3-hydroxy-N-methyl-pyridin-2-one) (bis-Me-3,2-HOPO) ligands were synthesized that vary only in linker geometry and rigidity. Solution phase thermodynamic measurements were conducted between pH 1.6 and pH 9.0 to determine the effects of these variations on proton and uranyl cation affinity. Proton affinity decreases by introduction of the solubilizing triethylene glycol group as compared to un-substituted reference ligands. Uranyl affinity was found to follow no discernable trends with incremental geometric modification. The butyl-linked 4Li-Me-3,2-HOPO ligand exhibited the highest uranyl affinity, consistent with prior in vivo decorporation results. Of the rigidly-linked ligands, the o-phenylene linker imparted the best uranyl affinity to the bis-Me-3,2-HOPO ligand platform.

Szigethy, Geza; Raymond, Kenneth

2010-08-12T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Regenerative mode photo electrochemical cells in molten salt electrolytes. 1st four monthly report (1/31/80)  

DOE Green Energy (OSTI)

The most promising photoelectrodes selected for use in the butyl pyridinium chloride-aluminum chloride room temperature molten salt are n-type silicon, gallium arsenide and cadmium telluride. The solubilities of these semiconductors are low, and their conduction and valence band edges are favorably located. Cadmium selenide and sulfide showed significant solubility in the melt, and the conduction band edge for p-type cadmium telluride was too close to the aluminum deposition potential. Several reversible redox couples have been identified, which could potentially be used in a photoelectrochemical cell. These include W/sup 5 +//W/sup 6 +/ and Eu/sup 2 +//Eu/sup 3 +/ as well as ferrocene and its derivatives.

Not Available

1980-01-01T23:59:59.000Z

442

Microwave-assisted fast vapor-phase transport synthesis of MnAPO-5 molecular sieves  

Science Conference Proceedings (OSTI)

MnAPO-5 was prepared by a microwave-assisted vapor-phase transport method at 180 deg. C in short times. The products were characterized by X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectra, UV-vis spectroscopic measurement, NH{sub 3}-temperature-programmed desorption and esterification reaction. It was found that dry gels prepared with aluminum isopropoxide, phosphoric acid and manganese acetate could be transferred to MnAPO-5 in the vapors of triethylamine and water by the microwave-assisted vapor-phase transport method at 180 deg. C for less than 30 min. The crystallization time was greatly reduced by the microwave heating compared with the conventional heating. The resulting MnAPO-5 exhibited much smaller particle sizes, higher surface areas and slightly higher catalytic activity in the esterification of acetic acid and butyl alcohol than those prepared by the conventional vapor-phase transport method and hydrothermal synthesis.

Shao Hui [State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009 (China); Department of Chemical Engineering, Jiangsu Polytechnic University, Changzhou 213016 (China); Yao Jianfeng; Ke Xuebin [State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009 (China); Zhang Lixiong [State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009 (China)], E-mail: lixiongzhang@yahoo.com; Xu Nanping [State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009 (China)

2009-04-02T23:59:59.000Z

443

Disorder-to-order transitions induced by alkyne/azide click chemistry in diblock copolymer thin films.  

Science Conference Proceedings (OSTI)

We investigated thin film morphologies of binary blends of alkyne-functionalized diblock copolymer poly(ethylene oxide)-block-poly(n-butyl methacrylate-random-propargyl methacrylate) (PEO-b-P(nBMA-r-PgMA)) and Rhodamine B azide, where the thermal alkyne/azide click reaction between the two components induced a disorder-to-order transition (DOT) of the copolymer. By controlling the composition of the neat copolymers and the mole ratio between the alkyne and azide groups, different microphase separated morphologies were achieved. At higher azide loading ratios, a perpendicular orientation of the microdomains was observed with wide accessible film thickness window. As less azide was incorporated, the microdomains have a stronger tendency to be parallel to the substrate, and the film thickness window for perpendicular orientation also became narrower.

Wei, X.; Gu, W.; Chen, W.; Shen, X.; Liu, F.; Strzalka, J. W.; Jiang, Z.; Russell, T. P. (Center for Nanoscale Materials); ( XSD); (Univ. of Massachusetts)

2012-01-01T23:59:59.000Z

444

Catalytic conversion of light alkanes-proof-of-concept stage -- Phase 6. Final report, February 1--October 31, 1994  

DOE Green Energy (OSTI)

During the course of the first three years of the Cooperative Agreement, the authors uncovered a family of metal perhaloporphyrin complexes which had unprecedented activity for the selective air-oxidation of light alkanes to alcohols. The reactivity of light hydrocarbon substrates with air or oxygen was in the order: isobutane > propane > ethane > methane, in accord with their homolytic bond dissociation energies. Isobutane was so reactive that the proof-of-concept stage of a process for producing tert-butyl alcohol from isobutane was begun (Phase 5). It was proposed that as more active catalytic systems were developed (Phases 4, 6), propane, then ethane and finally methane oxidations will move into this stage (Phases 7 through 9). As of this writing, however, the program has been terminated during the later stages of Phase 5 and 6 so that further work is not anticipated. 72 refs.

NONE

1994-12-31T23:59:59.000Z

445

Modified cellulose synthase gene from Arabidopsis thaliana confers herbicide resistance to plants  

DOE Patents (OSTI)

Cellulose synthase ("CS"), a key enzyme in the biosynthesis of cellulose in plants is inhibited by herbicides comprising thiazolidinones such as 5-tert-butyl-carbamoyloxy-3-(3-trifluromethyl)phenyl-4-thiazolidinone (TZ), isoxaben and 2,6-dichlorobenzonitrile (DCB). Two mutant genes encoding isoxaben and TZ-resistant cellulose synthase have been isolated from isoxaben and TZ-resistant Arabidopsis thaliana mutants. When compared with the gene coding for isoxaben or TZ-sensitive cellulose synthase, one of the resistant CS genes contains a point mutation, wherein glycine residue 998 is replaced by an aspartic acid. The other resistant mutation is due to a threonine to isoleucine change at amino acid residue 942. The mutant CS gene can be used to impart herbicide resistance to a plant; thereby permitting the utilization of the herbicide as a single application at a concentration which ensures the complete or substantially complete killing of weeds, while leaving the transgenic crop plant essentially undamaged.

Somerville, Chris R. (Portola Valley, CA); Scheible, Wolf (Golm, DE)

2007-07-10T23:59:59.000Z

446

Biological production of liquid fuels from biomass  

DOE Green Energy (OSTI)

A scheme for the production of liquid fuels from renewable resources such as poplar wood and lignocellulosic wastes from a refuse hydropulper was investigated. The particular scheme being studied involves the conversion of a cellulosic residue, resulting from a solvent delignified lignocellulosic feed, into either high concentration sugar syrups or into ethyl and/or butyl alcohol. The construction of a pilot apparatus for solvent delignifying 150 g samples of lignocellulosic feeds was completed. Also, an analysis method for characterizing the delignified product has been selected and tested. This is a method recommended in the Forage Fiber Handbook. Delignified samples are now being prepared and tested for their extent of delignification and susceptibility to enzyme hydrolysis. Work is continuing on characterizing the cellulase and cellobiase enzyme systems derived from the YX strain of Thermomonospora.

Not Available

447

Biological production of liquid fuels from biomass. Annual report, September 1, 1978-August 31, 1979  

DOE Green Energy (OSTI)

The production of liquid fuels from renewable resources such as poplar wood and lignocellulosic wastes from a refuse hydropulper were studied. The particular scheme being studied involves the conversion of a cellulosic residue, resulting from a solvent delignified lignocellulosic feed, into either high concentration sugar syrups or into ethyl and/or butyl alcohol. The process is aimed at achieving total raw material utilization and maximization of high value by-product recovery. Specific goals of the investigation are the demonstration of the process technical feasibility and economic practicality and its optimization for maximum economic yield and efficiency. The construction of a pilot apparatus for solvent delignifying 150g samples of lignocellulosic feeds has been completed. Also, an analysis method for characterizing the delignified product has been selected and tested. Delignified samples are now being prepared and tested for their extent of delignification and susceptibility to enzyme hydrolysis.

Pye, E.K.; Humphrey, A.E.

1979-01-01T23:59:59.000Z

448

A Hydrostratigraphic Model and Alternatives for the Groundwater Flow and Contaminant Transport Model of Corrective Action Unit 97: Yucca Flat-Climax Mine, Lincoln and Nye Counties, Nevada  

SciTech Connect

A new three-dimensional hydrostratigraphic framework model for the Yucca Flat-Climax Mine Corrective Action Unit was completed in 2005. The model area includes Yucca Flat and Climax Mine, former nuclear testing areas at the Nevada Test Site, and proximal areas. The model area is approximately 1,250 square kilometers in size and is geologically complex. Yucca Flat is a topographically closed basin typical of many valleys in the Basin and Range province. Faulted and tilted blocks of Tertiary-age volcanic rocks and underlying Proterozoic and Paleozoic sedimentary rocks form low ranges around the structural basin. During the Cretaceous Period a granitic intrusive was emplaced at the north end of Yucca Flat. A diverse set of geological and geophysical data collected over the past 50 years was used to develop a structural model and hydrostratigraphic system for the basin. These were integrated using EarthVision? software to develop the 3-dimensional hydrostratigraphic framework model. Fifty-six stratigraphic units in the model area were grouped into 25 hydrostratigraphic units based on each unit's propensity toward aquifer or aquitard characteristics. The authors organized the alluvial section into 3 hydrostratigraphic units including 2 aquifers and 1 confining unit. The volcanic units in the model area are organized into 13 hydrostratigraphic units that include 8 aquifers and 5 confining units. The underlying pre-Tertiary rocks are divided into 7 hydrostratigraphic units, including 3 aquifers and 4 confining units. Other units include 1 Tertiary-age sedimentary confining unit and 1 Mesozoic-age granitic confining unit. The model depicts the thickness, extent, and geometric relationships of these hydrostratigraphic units (''layers'' in the model) along with the major structural features (i.e., faults). The model incorporates 178 high-angle normal faults of Tertiary age and 2 low-angle thrust faults of Mesozoic age. The complexity of the model area and the non-uniqueness of some of the interpretations incorporated into the base model made it necessary to formulate alternative interpretations for some of the major features in the model. Five of these alternatives were developed so they could be modeled in the same fashion as the base model. This work was done for the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office in support of the Underground Test Area subproject of the Environmental Restoration Project.

Geotechnical Sciences Group Bechtel Nevada

2006-01-01T23:59:59.000Z

449

Aeromagnetic Survey At Lightning Dock Area (Cunniff & Bowers, 2005) | Open  

Open Energy Info (EERE)

Cunniff & Bowers, 2005) Cunniff & Bowers, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Aeromagnetic Survey At Lightning Dock Area (Cunniff & Bowers, 2005) Exploration Activity Details Location Lightning Dock Area Exploration Technique Aeromagnetic Survey Activity Date Usefulness useful DOE-funding Unknown Notes In October 2001, TerraCon, Inc. (2001) of Arlington, Texas conducted the highresolution aeromagnetic survey that was designed to explore the known, shallow geothermal resource and surrounding area. Shallow-subsurface Tertiary volcanic rocks were used as a magnetic basis for mapping structures References Roy A. Cunniff, Roger L. Bowers (2005) Final Technical Report, Geothermal Resource Evaluation And Definitioni (Gred) Program-Phases I, Ii,

450

Geology and alteration of the Raft River geothermal system, Idaho | Open  

Open Energy Info (EERE)

alteration of the Raft River geothermal system, Idaho alteration of the Raft River geothermal system, Idaho Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Proceedings: Geology and alteration of the Raft River geothermal system, Idaho Details Activities (1) Areas (1) Regions (0) Abstract: analcime; Cassia County Idaho; Cenozoic; chlorite; chlorite group; clay minerals; economic geology; exploration; framework silicates; geothermal energy; Idaho; illite; kaolinite; laumontite; montmorillonite; Neogene; Precambrian; Raft Formation; Raft River KGRA; Salt Lake Formation; sheet silicates; silicates; Tertiary; United States; wairakite; wells; zeolite group Author(s): Blackett, R.E.; Kolesar, P.T. Published: Geothermal Resource Council Transactions 1983, 1/1/1983 Document Number: Unavailable DOI: Unavailable

451

Calcium-tolerant N-substituted acrylamides as thickeners for aqueous systems  

DOE Patents (OSTI)

A water-soluble ionically-charged random copolymer of acrylamide and an alkaline or alkali metal 3-acrylamido-3-methylbutanoate having an average molecular weight of greater than about 50,000 has been found to maintain unusually stable and effective viscosities in the presence of salts such as NaCl and CaCl[sub 2] when added to water in minor amounts, thus making it a highly effective mobility control agent for secondary and tertiary oil recovery methods. Also within the scope of the invention are terpolymers which additionally contain olefinically unsaturated monomers such as acrylic acid or sodium acrylate.

McCormick, C.L.; Blackmon, K.P.

1986-04-22T23:59:59.000Z

452

Exploring nonlinear regression methods, with application to association studies  

E-Print Network (OSTI)

Glossary of Symbols Below is an outline of the notation I use throughout this thesis. Data Variables n - number of samples, indexed by the variable i. N - number of predictors, indexed by the variable g. X - predictor matrix (size n×N). Y - response vector... can also be applied to non-tertiary predictors, carries out MCMC sampling with the addition of Sampling Stage Four. iv Contents Summary i Glossary of Symbols ii List of Abbreviations iii Algorithm Schematic iv 1 Introduction 1 1.1 Regression Notation...

Speed, Douglas Christopher

2011-07-12T23:59:59.000Z

453

Regenerable solid imine sorbents  

DOE Patents (OSTI)

Two new classes of amine-based sorbents are disclosed. The first class comprises new polymer-immobilized tertiary amine sorbents; the second class new polymer-bound amine sorbents. Both classes are tailored to facilitate removal of acid anhydrides, especially carbon dioxide (CO.sub.2), from effluent gases. The amines adsorb acid anhydrides in a 1:1 molar ratio. Both classes of amine sorbents adsorb in the temperature range from about 20.degree. C. upwards to 90.degree. C. and can be regenerated by heating upwards to 100.degree. C.

Gray, McMahan; Champagne, Kenneth J.; Fauth, Daniel; Beckman, Eric

2013-09-10T23:59:59.000Z

454

Evaluation of the pollution abatement technologies available for treatment of wastewater from oil shale processing  

SciTech Connect

A review covers the conventional and in-situ oil shale processing technologies and their status of development; the sources and characteristics of the wastewaters from oil shale retorting operation, from leaching of spent shale, from cooling tower and boiler blowdowns, from oil refining operations, from saline aquifer, and from minor sources, such as from air pollution control equipment, runoff from dust control, and sanitary wastewaters; and wastewater treatment methods applicable for treating wastewater from oil shale processes including physical, chemical, biological, and tertiary treatment methods and specific processes for removing specific pollutants (e.g., phenols, cyanides, heavy metals) from wastewaters. 31 references.

Sung, R.D.; Prien, C.H.

1977-01-01T23:59:59.000Z

455

FGD wastewater treatment still has a way to go  

SciTech Connect

The power industry should jointly address questions about FGD water treatment and share the lessons it has learned so far. The article describes a scheme developed by CH2M Hill to treat FGD wastewater and remove heavy metals. The process desaturates the waste water of sulfates and removes the bulk of the insoluble suspended solids prior to tertiary treatment of heavy metals using a chemical/physical treatment process. Additional treatment could be provided (for example, anoxic biological treatment) for selenium, nitrates and organics. 2 figs.

Higgins, T.; Givens, S.; Sandy, T. [CH2M Hill (United States)

2008-01-15T23:59:59.000Z

456

Method for providing a low density high strength polyurethane foam  

SciTech Connect

Disclosed is a method for making a polyurethane closed-cell foam material exhibiting a bulk density below 4 lbs/ft.sup.3 and high strength. The present embodiment uses the reaction product of a modified MDI and a sucrose/glycerine based polyether polyol resin wherein a small measured quantity of the polyol resin is "pre-reacted" with a larger quantity of the isocyanate in a defined ratio such that when the necessary remaining quantity of the polyol resin is added to the "pre-reacted" resin together with a tertiary amine catalyst and water as a blowing agent, the polymerization proceeds slowly enough to provide a stable foam body.

Whinnery, Jr., Leroy L.; Goods, Steven H.; Skala, Dawn M.; Henderson, Craig C.; Keifer, Patrick N.

2013-06-18T23:59:59.000Z

457

Substituent Effects In a Series of 1,7-C60(RF)2 Compounds (RF = CF3, C2F5, n-C3F7, i-C3F7, n-C4F9, s-C4F9, n-C8F17): Electron Affinities, Reduction Potentials, and E(LUMO) Values Are Not Always Correlated  

SciTech Connect

Substituent effects are of paramount importance in virtually all fields of fundamental and applied chemistry. Classical and modern examples can be found in organic chemistry (Hammett parameters and Charton steric parameters), inorganic chemistry (trans effect and trans influence), organometallic chemistry (phosphine cone angles), physical chemistry (linear free energy relationships and DFT), biochemistry (protein tertiary structure), medicinal chemistry (SAR maps and BioMAP analysis), polymer chemistry (nonlinear optical and permeation properties and glass transition temperatures), and materials chemistry (stability and luminescent properties of electroluminescent devices and light-to-power conversion efficiencies of fullerene-derivative-based OPV devices).

Kuvychko, Igor V.; Whitaker, James B.; Larson, Bryon W.; Folsom, Travis; Shustova, Natalia; Avdoshenko, Stanislav; Chen, Yu-Sheng; Wen, Hui; Wang, Xue B.; Dunsch, Lothar; Popov, Alexey A.; Boltalina, Olga V.; Strauss, Steven H.

2012-05-01T23:59:59.000Z

458

Completion Report for Well ER-20-4 Corrective Action Units 101 and 102: Central and Western Pahute Mesa  

SciTech Connect

Well ER-20-4 was drilled for the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office in support of the Nevada Environmental Restoration Project at the Nevada National Security Site, Nye County, Nevada. The well was drilled in August and September 2010 as part of the Pahute Mesa Phase II drilling program. The primary purpose of the well was to investigate the possibility of radionuclide transport from up-gradient underground nuclear tests conducted in central Pahute Mesa. This well also provided detailed hydrogeologic information in the Tertiary volcanic section that will help reduce uncertainties within the Pahute Mesa-Oasis Valley hydrostratigraphic framework model.

NSTec Environmental Management

2011-04-30T23:59:59.000Z

459

Environmental regulations handbook for enhanced oil recovery. 1983 update  

SciTech Connect

This handbook is intended to serve owners and operators of enhanced oil recovery operations as a guidebook to the environmental laws and regulations which have special significance for enhanced oil recovery (EOR). EOR, as used in this handbook, refers to what is also called tertiary recovery. There are three major categories of EOR processes - thermal (including both steam injection and in-situ combustion), miscible gas, and chemical. These processes are used only after a well or reservoir has ceased to produce oil economically through primary or secondary methods. The primary emphasis in the handbook is on laws and regulations for the control or prevention of pollution. 3 figures, 14 tables.

Wilson, T.D.

1983-10-01T23:59:59.000Z

460

Completion Report for Wells ER-20-8 and ER-20-8#2 Corrective Action Units 101 and 102: Central and Western Pahute Mesa  

SciTech Connect

Wells ER-20-8 and ER-20-8#2 were drilled for the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office in support of the Nevada Environmental Restoration Project at the Nevada National Security Site (formerly Nevada Test Site), Nye County, Nevada. The holes were drilled in July and August 2009, as part of the Pahute Mesa Phase II drilling program. The primary purpose of these wells was to provide detailed hydrogeologic information in the Tertiary volcanic section that will help address uncertainties within the Pahute Mesa–Oasis Valley hydrostratigraphic framework model. They may also be used as long-term monitoring wells.

NSTec Environmental Management

2011-02-28T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Degradation problems with the solvent extraction organic at Roessing uranium  

Science Conference Proceedings (OSTI)

Roessing Uranium Ltd recovers uranium from a low-grade ore in Namibia. Uranium is recovered and purified from an ion-exchange eluate in a solvent-extraction plant. The solvent-extraction plant uses Alamine 336 as the extractant for uranium, with isodecanol used as a phase modifier in Sasol SSX 210, an aliphatic hydrocarbon diluent. Since the plant started in the mid 1970's, there have been a few episodes where the tertiary amine has been quickly and severely degraded when the plant was operated outside certain operating parameters. The Rossing experience is discussed in more detail in this paper. (authors)

Munyungano, Brodrick [Roessing Uranium Ltd, Private Bag 5005, Swakopmund (Namibia); Feather, Angus [Cognis, P. O. Box 361, Honeydew, 2040 (South Africa); Virnig, Michael [Cognis Corporation, 2430 N. Huachuca Dr, Tucson, Az (United States)

2008-07-01T23:59:59.000Z

462

Method and system for ethanol production  

DOE Patents (OSTI)

A transition metal carbonyl and a tertiary amine are employed as a homogeneous catalytic system in methanol or a less volatile solvent to react methanol with carbon monoxide and hydrogen gas producing ethanol and carbon dioxide. The gas contains a high carbon monoxide to hydrogen ratio as is present in a typical gasifier product. The reaction has potential for anhydrous ethanol production as carbon dioxide rather than water is produced. The only other significant by product is methane. Selected transition metal carbonyls include those of iron, ruthenium and possibly manganese and osmium. Selected amines include trimethylamine, N-Methylpyrrolidine, 24-diazabicyclooctane, dimethyneopentylamine and 2-pryidinol.

Feder, Harold M. (Darien, IL); Chen, Michael J. (Darien, IL)

1981-01-01T23:59:59.000Z

463

Method and system for ethanol production  

DOE Patents (OSTI)

A transition metal carbonyl and a tertiary amine are employed as a homogeneous catalytic system in methanol or a less volatile solvent to react methanol with carbon monoxide and hydrogen gas producing ethanol and carbon dioxide. The gas contains a high carbon monoxide to hydrogen ratio as is present in a typical gasifier product. The reaction has potential for anhydrous ethanol production as carbon dioxide rather than water is produced. Selected transition metal carbonyls include those of iron, rhodium ruthenium, manganese in combination with iron and possibly osmium. Selected amines include trimethylamine, N-Methylpyrrolidine, 2,4-diazabicyclooctane, dimethylneopentylamine, N-methylpiperidine and derivatives of N-methylpiperidine.

Feder, Harold M. (Darien, IL); Chen, Michael J. (Darien, IL)

1983-01-01T23:59:59.000Z

464

Method and system for ethanol production  

DOE Patents (OSTI)

A transition metal carbonyl and a tertiary amine are employed as a homogeneous catalytic system in methanol or a less volatile solvent to react methanol with carbon monoxide and hydrogen gas producing ethanol and carbon dioxide. The gas contains a high carbon monoxide to hydrogen ratio as is present in a typical gasifier product. The reaction has potential for anhydrous ethanol production as carbon dioxide rather than water is produced. Selected transition metal carbonyls include those of iron, rhodium, ruthenium, manganese in combination with iron and possibly osmium. Selected amines include trimethylamine, N-Methylpyrrolidine, 2,4-diazabicyclooctane, dimethylneopentylamine, N-methylpiperidine and derivatives of N-methylpiperidine.

Feder, H.M.; Chen, M.J.

1981-09-24T23:59:59.000Z

465

Method and system for ethanol production  

DOE Patents (OSTI)

A transition metal carbonyl and a tertiary amine are employed as a homogeneous catalytic system in methanol or a less volatile solvent to react methanol with carbon monoxide and hydrogen gas producing ethanol and carbon dioxide. The gas contains a high carbon monoxide to hydrogen ratio as is present in a typical gasifier product. The reaction has potential for anhydrous ethanol production as carbon dioxide rather than water is produced. The only other significant by-product is methane. Selected transition metal carbonyls include those of iron, ruthenium and possibly manganese and osmium. Selected amines include trimethylamine, N-Methylpyrrolidine, 24-diazabicyclooctane, dimethyneopentylamine and 2-pryidinol.

Feder, H.M.; Chen, M.J.

1980-05-21T23:59:59.000Z

466

Approaches for regeneration of amine-carboxylic acid extracts  

Science Conference Proceedings (OSTI)

Extraction processes based on reversible chemical complexation can be useful for separation of polar organics from dilute solution. Tertiary amines are effective extractants for the recovery of carboxylic acids from aqueous solution. The regeneration of aminecarboxylic acid extracts is an important step which strongly influences the economic viability of the separation process. Several regeneration methods are critically reviewed, and the factors that affect swing regeneration processes, including temperature-swing, diluent composition-swing and pH-swing with a volatile base are discussed. Interest in this area comes from interest in treatment of waste streams, particularly in petrochemical and fermentation manufacture.

Dai, Y.; King, C.J.

1995-07-01T23:59:59.000Z

467

Aerial gamma ray and magnetic survey: Mississippi and Florida airborne survey, Blytheville quadrangle, Tennessee, Arkansas, Alabama, and Missouri. Final report  

SciTech Connect

The Blytheville quadrangle covers a region east of the Mississippi River in the northernmost Gulf Coastal Province. The Tertiary Mississippi Embayment and the older Black Warrior - Arkoma Basins all shoal to the northeast in this area. Surficial exposures are dominantly Cretaceous or younger. Older strata are exposed in the northeast. A search of available literature revealed no known uranium deposits. Ninety uranium anomalies were detected and are discussed briefly. Few were considered significant,and almost all appear to relate to some cultural feature. Magnetic data appears, for the most part, to be in agreement with existing structural interpretations of the region.

Not Available

1980-09-01T23:59:59.000Z

468

Handbook for personal computer versions enhanced oil recovery predictive models: Supporting technology for enhanced oil recovery  

SciTech Connect

The personal computer (PC) programs described in this handbook were adapted from the Tertiary Oil Recovery Information System (TORIS) enhanced oil recovery (EOR) predictive models. The models, both those developed for the Department of Energy and those developed for the National Petroleum Council (NPC), were designed by Scientific Software-Intercomp and were used in the 1984 NPC study on the national potential for enhanced oil recovery. The Department of Energy, Bartlesville Project Office, supported the NPC study and has maintained the models since the study was completed. 10 refs.

Allison, E.; Waldrop, R.; Ray, R.M.

1988-02-01T23:59:59.000Z

469

Micellar/polymer flooding in the Bradford field  

SciTech Connect

This paper describes the development and operation of a 218-acre (88-ha) micellar/polymer flood in the Bradford field of Pennsylvania. A definite tertiary oil production response occurred after injection of 35% PV of micellar slug and polymer. A total of 191,226 bbl (30.4x10/sup 3/ m/sup 3/), or 3.4% PV, oil was produced, which was significantly less than predicted. The production response occurred later and was lower than expected, and operations were discontinued before the scheduled polymer-injection sequence was completed.

Ondrusek, P.S.

1988-08-01T23:59:59.000Z

470

Development and results of the Hale/Mable leases cooperative polymer EOR injection project, Vacuum (Grayburg-San Andres) field, Lea County, New Mexico  

SciTech Connect

This paper presents a case history of the design, implementation, and results of a tertiary polymer EOR injection project conducted by Phillips Petroleum Co. in their Hale and Mable leases located in the Vacuum (Grayburg-San Andres) field, Lea County, NM. Polymer is being injected at a relatively low concentration, and the paper concludes that, given the reservoir rock and fluid properties prevalent in the Hale and Mable leases, a low-concentration polymer flood is just as effective as a higher-concentration flood as long as the total pounds of polymer injected is the same.

Hovendick, M.D. (Phillips Petroleum Co. (US))

1989-08-01T23:59:59.000Z

471

Hydrology and geochemistry of thermal ground water in southwestern Idaho and north-central Nevada  

DOE Green Energy (OSTI)

The study area occupies about 14,500 square miles in southwestern Idaho and north-central Nevada. Thermal ground water occurs under artesian conditions, in discontinuous or compartmented zones, in igneous or sedimentary rocks of Tertiary age. Ground-water movement is generally northward. Temperatures of the ground water range from about 30/sup 0/ to more than 80/sup 0/C. Chemical analyses of water from 12 wells and 9 springs indicate that nonthermal waters are a calcium bicarbonate type; thermal waters are a sodium bicarbonate type. Chemical geothermometers indicate probable maximum reservoir temperatures are near 100/sup 0/C. Concentration of tritium in the thermal water water is near zero.

Young, H.W.; Lewis, R.E.

1980-12-01T23:59:59.000Z

472

Biparticle fluidized bed reactor  

DOE Patents (OSTI)

A fluidized bed reactor system which utilizes a fluid phase, a retained fluidized primary particulate phase, and a migratory second particulate phase. The primary particulate phase is a particle such as a gel bead containing an immobilized biocatalyst. The secondary and tertiary particulate phases, continuously introduced and removed simultaneously in the cocurrent and countercurrent mode, act in a role such as a sorbent to continuously remove a product or by-product constituent from the fluid phase. Means for introducing and removing the sorbent phases include feed screw mechanisms and multivane slurry valves.

Scott, Charles D. (Oak Ridge, TN); Marasco, Joseph A. (Kingston, TN)

1996-01-01T23:59:59.000Z

473

Polyfunctional catalyst for processiing benzene fractions  

SciTech Connect

A by-product of the coke industry is a raw benzene fraction benzene- 1 which may serve as for catalytic processes. The paper reports a study on the influence of the composition and temperatures on the activity and selectivity of NiO-V{sub 2}O{sub 6}-MoO{sub 3}/{gamma}-Al{sub 2}O{sub 3} catalysts and the corresponding binary and tertiary subsystems are studied by a pulse method in model reactions; the hydrodealkylating of toluene and the hydrodesulfurizing of thioprhene. The optimal catalyst composition is established. The new catalyst is compared with industrial catalysts.

G. Byakov; B.D. Zubitskii; B.G. Tryasunov; I.Ya. Petrov [Kuznetsk Basin State Technical University, Kemerovo (Russian Federation)

2009-05-15T23:59:59.000Z

474

pH-sensitive methacrylic copolymer gels and the production thereof  

DOE Patents (OSTI)

The present invention provides novel gel forming methacrylic blocking copolymers that exhibit cationic pH-sensitive behavior as well as good water solubility. The copolymers are constructed by polymerization of a tertiary amine methacrylate with either a (poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) polymer, such as the commercially available Pluronic.RTM. polymers, or a poly(ethylene glycol)methyl ether polymer. The polymers may be used for drug and gene delivery, protein separation, as structural supplements, and more.

Mallapragada, Surya K. (Ames, IA); Anderson, Brian C. (Lake Bluff, IA)

2007-05-15T23:59:59.000Z

475

Enhanced oil-recovery operatiohs in Kansas 1979  

SciTech Connect

Data for 1552 enhanced oil-recovery (EDR) projects are listed in this report and a map shows their distribution. The majority of the EOR projects fall into the categories of pressure maintenance, dump floods, and controlled waterfloods, which are secondary recovery projects. There are several active tertiary projects and a few inactive projects. Active EOR projects are listed alphebetically by county and field. Data on thickness and depth of oil-producing zones or injection horizons, sources of water, and cumulative figures on oil produced and water injected are included. (DMC)

Paul, S.E.; Bahnmaier, E.L.

1981-01-01T23:59:59.000Z

476

Enhanced oil-recovery operations in Kansas, 1979. Energy Resources Series 17  

SciTech Connect

Data for 1552 enhanced oil-recovery (EOR) projects are listed in this report and a map shows their distribution. The majority of the EOR projects fall into the categories of pressure maintenance, dump floods, and controlled waterfloods, which are secondary recovery projects. There are several active tertiary projects and a few inactive projects. Active EOR projects are listed alphabetically by county and field. Data on thickness and depth of oil-producing zones or injection horizons, sources of water, and cumulative figures on oil produced and water injected are included. (DMC)

Paul, S.E.; Bahnmaier, E.L.

1981-01-01T23:59:59.000Z

477

Effect of sorghum bran addition on lipid oxidation and sensory properties of ground beef patties differing in fat levels  

E-Print Network (OSTI)

Oxidation of lipids influences the color and sensory qualities of meat products. Meat with a high fat content, such as ground meat, is susceptible to lipid oxidation that leads to the development of negative flavor and color changes. Antioxidants, such as butylated hydroxanisole (BHA), butylated hydroxytolune (BHT) and extracts of rosemary, are used in meat products to control the effects of lipid oxidation. Awika (2000, 2003) found that sorghum bran phytochemicals have high antioxidant properties. Our objective is to evaluate the pH, color, sensory and antioxidant effect of 10, 20 and 30% ground beef patties containing rosemary, BHA/BHT, and three levels of sorghum bran during 5 d of aerobic storage at 4�°C. Beef trimmings containing either 50% or 90% lean were formulated into three meat blocks containing either 10, 20 or 30% lipid. Within a fat content, ground beef was equally divided into one of six treatments: 1) control-no added ingredients; 2) BHA and BHT at .01% of the meat weight; 3) rosemary at 0.2% of the meat weight; 4) high level of sorghum at 1.0% of the meat weight; 5) medium level of sorghum at 0.5% of the meat weight; and, 6) a low level of sorghum at 0.25% of the meat weight. The ground beef was aerobically packaged and stored for 0, 1, 3, or 5 days at 4�°C. pH, thiobarbituric acid reactive substances (TBARS), fatty acid methyl esters (FAME), sensory color, Minolta color space values and descriptive sensory evaluations were determined. Antioxidant addition reduced TBARS values and increased hardness (P0.05). Moreover, the addition of sorghum bran at low levels can retard oxidative rancidity in ground beef patties without causing detrimental color changes and negatively affecting sensory attributes.

Hemphill, Susan Patricia

2006-08-01T23:59:59.000Z

478

Portal Vein Embolization Before Liver Resection: A Systematic Review  

Science Conference Proceedings (OSTI)

This is a review of literature on the indications, technique, and outcome of portal vein embolization (PVE). A systematic literature search on outcome of PVE from 1990 to 2011 was performed in Medline, Cochrane, and Embase databases. Forty-four articles were selected, including 1,791 patients with a mean age of 61 {+-} 4.1 years. Overall technical success rate was 99.3 %. The mean hypertrophy rate of the FRL after PVE was 37.9 {+-} 0.1 %. In 70 patients (3.9 %), surgery was not performed because of failure of PVE (clinical success rate 96.1 %). In 51 patients (2.8 %), the hypertrophy response was insufficient to perform liver resection. In the other 17 cases, 12 did not technically succeed (0.7 %) and 7 caused a complication leading to unresectability (0.4 %). In 6.1 %, resection was cancelled because of local tumor progression after PVE. Major complications were seen in 2.5 %, and the mortality rate was 0.1 %. A head-to-head comparison shows a negative effect of liver cirrhosis on hypertrophy response. The use of n-butyl cyanoacrylate seems to have a greater effect on hypertrophy, but the difference with other embolization materials did not reach statistical significance. No difference in regeneration is seen in patients with cholestasis or chemotherapy. Preoperative PVE has a high technical and clinical success rate. Liver cirrhosis has a negative effect on regeneration, but cholestasis and chemotherapy do not seem to have an influence on the hypertrophy response. The use of n-butyl cyanoacrylate may result in a greater hypertrophy response compared with other embolization materials used.

Lienden, K. P. van, E-mail: k.p.vanlienden@amc.uva.nl [Academic Medical Center, Department of Radiology (Netherlands)] [Academic Medical Center, Department of Radiology (Netherlands); Esschert, J. W. van den; Graaf, W. de [Academic Medical Center, Department of Surgery (Netherlands)] [Academic Medical Center, Department of Surgery (Netherlands); Bipat, S.; Lameris, J. S. [Academic Medical Center, Department of Radiology (Netherlands)] [Academic Medical Center, Department of Radiology (Netherlands); Gulik, T. M. van [Academic Medical Center, Department of Surgery (Netherlands)] [Academic Medical Center, Department of Surgery (Netherlands); Delden, O. M. van [Academic Medical Center, Department of Radiology (Netherlands)] [Academic Medical Center, Department of Radiology (Netherlands)

2013-02-15T23:59:59.000Z

479

A Hydrostratigraphic Model of the Pahute Mesa - Oasis Valley Area, Nye County, Nevada  

SciTech Connect

A 3-D hydrostratigraphic framework model has been built for the use of hydrologic modelers who are tasked with developing a model to determine how contaminants are transported by groundwater flow in an area of complex geology. The area of interest includes Pahute Mesa, a former nuclear testing area at the Nevada Test Site (NTS), and Oasis Valley, a groundwater discharge area down-gradient from contaminant source areas on Pahute Mesa. To build the framework model, the NTS hydrogeologic framework was integrated with an extensive collection of drill-hole data (stratigraphic, lithologic, and alteration data); a structural model; and several recent geophysical, geological, and hydrological studies to formulate a hydrostratigraphic system. The authors organized the Tertiary volcanic units in the study area into 40 hydrostratigraphic units that include 16 aquifers, 13 confining units, and 11 composite units. The underlying pre-Tertiary rocks were divided into six hydrostratigraphic units, including two aquifers and four confining units. The model depicts the thickness, extent, and geometric relationships of these hydrostratigraphic units (''layers'' in the model) along with all the major structural features that control them, including calderas and faults. The complexity of the model area and the non-uniqueness of some of the interpretations incorporated into the base model made it necessary to address alternative interpretations for some of the major features in the model. Six of these alternatives were developed so they could be modeled in the same fashion as the base model.

S. L. Drellack, Jr.; L. B. Prothro; J. L. Gonzales

2001-12-01T23:59:59.000Z

480

Grid Collector: Facilitating Efficient Selective Access from DataGrids  

Science Conference Proceedings (OSTI)

The Grid Collector is a system that facilitates the effective analysis and spontaneous exploration of scientific data. It combines an efficient indexing technology with a Grid file management technology to speed up common analysis jobs on high-energy physics data and to enable some previously impractical analysis jobs. To analyze a set of high-energy collision events, one typically specifies the files containing the events of interest, reads all the events in the files, and filters out unwanted ones. Since most analysis jobs filter out significant number of events, a considerable amount of time is wasted by reading the unwanted events. The Grid Collector removes this inefficiency by allowing users to specify more precisely what events are of interest and to read only the selected events. This speeds up most analysis jobs. In existing analysis frameworks, the responsibility of bringing files from tertiary storages or remote sites to local disks falls on the users. This forces most of analysis jobs to be performed at centralized computer facilities where commonly used files are kept on large shared file systems. The Grid Collector automates file management tasks and eliminates the labor-intensive manual file transfers. This makes it much easier to perform analyses that require data files on tertiary storages and remote sites. It also makes more computer resources available for analysis jobs since they are no longer bound to the centralized facilities.

Wu, Kesheng; Gu, Junmin; Lauret, Jerome; Poskanzer, Arthur M.; Shoshani, Arie; Sim, Alexander; Zhang, Wei-Ming

2005-05-17T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.