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Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
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1

State Restrictions on Methyl Tertiary Butyl Ether (released in AEO2006)  

Reports and Publications (EIA)

By the end of 2005, 25 states had barred, or passed laws banning, any more than trace levels of methyl tertiary butyl ether (MTBE) in their gasoline supplies, and legislation to ban MTBE was pending in 4 others. Some state laws address only MTBE; others also address ethers such as ethyl tertiary butyl ether (ETBE) and tertiary amyl methyl ether (TAME). Annual Energy Outlook 2006 assumes that all state MTBE bans prohibit the use of all ethers for gasoline blending.

2006-01-01T23:59:59.000Z

2

Use of superconductor type catalysts in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide  

SciTech Connect

In a method wherein a solution of a tertiary butyl hydroperoxide charge stock in tertiary butyl alcohol is brought into contact with a catalytically effective amount of a hydroperoxide decomposition catalyst in a hydroperoxide decomposition reaction zone in liquid phase with agitation to convert said tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol, the improvement is described which comprises: (a) using a superconductor as said hydroperoxide decomposition catalyst, and (b) recovering tertiary butyl alcohol from the products of said hydroperoxide decomposition reaction.

Sanderson, J.R.; Stockton, M.E.

1993-08-17T23:59:59.000Z

3

Catalytic distillation for the synthesis of tertiary butyl alcohol.  

E-Print Network (OSTI)

??Catalytic Distillation for the synthesis of tertiary butyl alcohol (TBA) is investigated in this thesis. The solvent, ethylene glycol, is proposed as a means of… (more)

Safinski, Tomasz

2005-01-01T23:59:59.000Z

4

Anhydrous aluminum chloride as an alkylation catalyst: identification of mono- and dialkyl-benzenes from the condensation of tertiary butyl alcohol with benzene.  

E-Print Network (OSTI)

LIBRARY a a w c"I. I. SI - O~ TI:YAf ANHYDROUS ALUMINUM CHLORIDE AS AN ALKYLATION CATALYST: IDENTIFICATION OF MONO- AND DIALKYIZENZENES FROM THE CONDENSATION QF TERTIARY BUTYL ALCOHOL WITH BENKENE IACEY EUGENE SCOGGINS 4 A Thesis Submitted...: IDENTIFICATION OF MONO- AND DI~NZZNES FROM THE CONDENSATION OF TERTIARY BUTYL ALCOHOL WITH BENZENE A Thesis By LACEY EUGENE SCOGGINS Approved as to style and content hy: Chairman of Committee Head of Chemistry Department 1959 ACKNOWLEDGME1VTS The author...

Scoggins, Lacey E

1959-01-01T23:59:59.000Z

5

Ditertiary butyl peroxide recovery  

SciTech Connect

A process is described wherein a feed material comprising significant amounts of tertiary butyl hydroperoxide and tertiary butyl alcohol and minor amounts of ditertiary butyl peroxide and other impurities is charged to a reactor together with propylene and a soluble epoxidation catalyst. At least a portion of the tertiary butyl hydroperoxide is reacted in the reactor with the propylene to form a reaction product composed of unreacted feed components, propylene oxide, an additional quantity of tertiary butyl alcohol, and impurities, including a minor amount of ditertiary butyl peroxide. The improvement for recovering substantially pure ditertiary butyl peroxide from the reaction product after the reaction product is discharged from the reactor comprises the steps of: charging the reaction product to a first distillation zone and separating therein a first unreacted propylene distillate recycle fraction, charging the remaining heavier components of the reaction product from the first distillation zone to a second distillation zone and separating a second propylene oxide distillate product fraction therein charging the heavier components from the second distillation zone to a third distillation zone and separating a third distillate fraction comprising a major amount of tertiary butyl alcohol and a minor amount of ditertiary butyl peroxide, and recovering the second propylene oxide distillate fraction, the heavier tertiary butyl alcohol product fraction and the ditertiary butyl peroxide raffinate fraction.

Sanderson, J.R.; Meyer, R.A.; Smith, W.A.; Marquis, E.T.

1989-03-07T23:59:59.000Z

6

TAMING MATLAB Anton Dubrau  

E-Print Network (OSTI)

TAMING MATLAB by Anton Dubrau School of Computer Science McGill University, Montréal Friday, April OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF SCIENCE Copyright © 2012 Anton Dubrau #12;#12;Abstract MATLAB is a dynamic scientific language used by scientists, engineers and students worldwide. Although MATLAB is very

Verbrugge, Clark

7

Protein folding tames chaos  

E-Print Network (OSTI)

Protein folding produces characteristic and functional three-dimensional structures from unfolded polypeptides or disordered coils. The emergence of extraordinary complexity in the protein folding process poses astonishing challenges to theoretical modeling and computer simulations. The present work introduces molecular nonlinear dynamics (MND), or molecular chaotic dynamics, as a theoretical framework for describing and analyzing protein folding. We unveil the existence of intrinsically low dimensional manifolds (ILDMs) in the chaotic dynamics of folded proteins. Additionally, we reveal that the transition from disordered to ordered conformations in protein folding increases the transverse stability of the ILDM. Stated differently, protein folding reduces the chaoticity of the nonlinear dynamical system, and a folded protein has the best ability to tame chaos. Additionally, we bring to light the connection between the ILDM stability and the thermodynamic stability, which enables us to quantify the disorderli...

Xia, Kelin

2013-01-01T23:59:59.000Z

8

REVIEW ARTICLE Taming molecular beams  

E-Print Network (OSTI)

REVIEW ARTICLE Taming molecular beams The motion of neutral molecules in a beam can be manipulated time-varying fields can be used to decelerate or accelerate beams of molecules to any desired velocity. We review the possibilities that this molecular-beam technology offers, ranging from ultrahigh

Loss, Daniel

9

SciTech Connect: Taming the Grid: Dynamic Load Composition Quantificat...  

Office of Scientific and Technical Information (OSTI)

Taming the Grid: Dynamic Load Composition Quantification at the Distribution-Transformer Level Citation Details In-Document Search Title: Taming the Grid: Dynamic Load Composition...

10

Taming MATLAB Anton Dubrau and Laurie Hendren  

E-Print Network (OSTI)

Taming MATLAB Anton Dubrau and Laurie Hendren McGill University anton.dubrau@mail.mcgill.ca, hendren@cs.mcgill.ca Abstract MATLAB is a dynamic scientific language used by scientists, engineers and students worldwide. Although MATLAB is very suitable for rapid prototyping and development, MAT- LAB users

11

Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process  

E-Print Network (OSTI)

, methanol recovery 1. Introduction A process of producing TAME via reactive distillation has been presented the bulk of the reaction between C5 and methanol to produce TAME and a reactive distillation. MethanolDesign of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

Al-Arfaj, Muhammad A.

12

Spitsbergen Tertiary Coal Fossils  

Science Journals Connector (OSTI)

... grains and spores to be observed in coal deposits of Tertiary age in west Spitsbergen (Norsk Polarinstitutt, Med. 79, pp. 1-9; 1954; English summary).

1955-08-06T23:59:59.000Z

13

Taming Hurricanes With Arrays of Offshore Wind Turbines  

E-Print Network (OSTI)

Taming Hurricanes With Arrays of Offshore Wind Turbines Mark Z. Jacobson Cristina Archer, Willet #12;Representation of a vertically-resolved wind turbine in model Lines are model layers) or 50 m/s (destruction) speed. Can Walls of Offshore Wind Turbines Dissipate Hurricanes? #12;Katrina

Firestone, Jeremy

14

Taming water waves Case study: Surface Water Waves  

E-Print Network (OSTI)

Taming water waves Case study: Surface Water Waves Few things in nature are as dramatic, and potentially dangerous, as ocean waves. The impact they have on our daily lives extends from shipping to the role they play in driving the global climate. From a theoretical viewpoint water waves pose rich

15

A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh...  

NLE Websites -- All DOE Office Websites (Extended Search)

A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion Plasmas Recent experiments have confirmed the great potential of a novel plasma-material interface concept....

16

Taming rogue waves in vector Bose-Einstein condensates  

Science Journals Connector (OSTI)

Using gauge transformation method, we generate rogue waves for the two-component Bose-Einstein condensates (BECs) governed by the symmetric coupled Gross-Pitaevskii (GP) equations and study their dynamics. We also suggest a mechanism to tame the rogue waves either by manipulating the scattering length through Feshbach resonance or the trapping frequency, a phenomenon not witnessed in the domain of BECs, and we believe that these results may have wider ramifications in the management of rogons.

P. S. Vinayagam; R. Radha; K. Porsezian

2013-10-11T23:59:59.000Z

17

REDUCED, TAME, AND EXOTIC FUSION SYSTEMS KASPER ANDERSEN, BOB OLIVER, AND JOANA VENTURA  

E-Print Network (OSTI)

-groups) of a given type, one must first find a way to limit the types of fusion systems under consideration, and doREDUCED, TAME, AND EXOTIC FUSION SYSTEMS KASPER ANDERSEN, BOB OLIVER, AND JOANA VENTURA Abstract. We define here two new classes of saturated fusion systems, reduced fusion systems and tame fusion

Ventura, Joana

18

Accelerated aging of EPDM and butyl elastomers  

SciTech Connect

This study was composed of three parts: a post cure study to optimize final properties of an ethylene-propylene-diene (EPDM) formulation, an accelerated aging study to compare the stress relaxation behavior of a butyl and an EPDM elastomer under compression, and a cursory evaluation of a new 70 Shore A EPDM. The optimum postcure for the EPDM was found to be 2 to 4 hours at 182{degrees}C in a vacuum. The EPDM was also shown to have superior aging characteristics compared to the butyl and is recommended for use instead of the butyl material. The physical properties for new 70 Shore A EPDM are satisfactory, and the stress relaxation behavior was only slightly inferior to the other EPDM.

Wilson, M.H.

1996-06-01T23:59:59.000Z

19

A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion  

NLE Websites -- All DOE Office Websites (Extended Search)

A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion Plasmas Fusion Energy Sciences (FES) FES Home About Research Facilities Science Highlights Benefits of FES Funding Opportunities Fusion Energy Sciences Advisory Committee (FESAC) News & Resources Contact Information Fusion Energy Sciences U.S. Department of Energy SC-24/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-4941 F: (301) 903-8584 E: sc.fes@science.doe.gov More Information » October 2012 A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion Plasmas Recent experiments have confirmed the great potential of a novel plasma-material interface concept. Print Text Size: A A A Subscribe FeedbackShare Page Click to enlarge photo. Enlarge Photo

20

A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion  

NLE Websites -- All DOE Office Websites (Extended Search)

A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion A Snowflake-Shaped Magnetic Field Holds Promise for Taming Harsh Fusion Plasmas Recent experiments have confirmed the great potential of a novel plasma-material interface concept. By U.S Department of Energy Office of Science October 31, 2012 Tweet Widget Facebook Like Google Plus One National Spherical Torus Experiment (Photo by Elle Starkman, Office of Communications, PPPL) National Spherical Torus Experiment The Science Heat escaping from the core of a twelve-million degree nuclear fusion plasma device was successfully contained by a snowflake-shaped magnetic field to mitigate its impact on device walls. The Impact One of the grand challenges of the magnetic fusion research is to "tame the plasma-material interface"-to develop an interface between the hot

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

E-Print Network 3.0 - ammoniated glycyrrhizin butylated Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

ammoniated glycyrrhizin butylated Search Powered by Explorit Topic List Advanced Search Sample search results for: ammoniated glycyrrhizin butylated Page: << < 1 2 3 4 5 > >> 1...

22

Concentrating aqueous acetate solutions with tertiary amines  

E-Print Network (OSTI)

Water may be extracted from aqueous calcium acetate or sodium acetate solutions using low miscibility, low molecular weight tertiary amines, e.g. triethylamine (TEA) and N,N- dietliylmethylaniine (DEMA). This novel extraction technology...

Lee, Champion

2012-06-07T23:59:59.000Z

23

Induction of Methyl Tertiary Butyl Ether (MTBE)-Oxidizing Activity in Mycobacterium vaccae JOB5 by MTBE  

Science Journals Connector (OSTI)

...directly from the culture vessels. In experiments that followed...time course of organic acid consumption as well as MTBE oxidation...determine the extent of MTBE consumption and the accumulation of TBA...detectable growth or MTBE consumption occurred when cells were incubated...

Erika L. Johnson; Christy A. Smith; Kirk T. O'Reilly; Michael R. Hyman

2004-02-01T23:59:59.000Z

24

Measurement of Trihalomethanes and Methyl Tertiary-Butyl Ether in Tap Water Using Solid-Phase Microextraction GC-MS  

Science Journals Connector (OSTI)

......ductive age living in Corpus Christi, Texas and Cobb...micro extraction with gas chromatography-mass...determinations using gas chromatog- raphy...of fulvic acids in natural waters. Env. Sci...trihalomethane by headspace-gas chromatog- raphy......

Frederick L. Cardinali; David L. Ashley; John C. Morrow; Deborah M. Moll; Benjamin C. Blount

2004-04-01T23:59:59.000Z

25

Control Study of Ethyl tert-Butyl Ether Reactive Distillation Muhammad A. Al-Arfaj  

E-Print Network (OSTI)

-butyl ether (ETBE) for gasoline blending as a replacement for methyl tert-butyl ether (MTBE) because and be blended with ETBE in the gasoline pool. Even for neat operation, if the conversion is low, the unconverted

Al-Arfaj, Muhammad A.

26

NETL: News Release - Florida Demo Tames High Sulfur Coal: Delivers Power at  

NLE Websites -- All DOE Office Websites (Extended Search)

March 11, 2005 March 11, 2005 Florida Demo Tames High Sulfur Coal: Delivers Power at Very Low Emissions Shows that New Technology Cuts Pollutants to Fractions of Federal Clean Air Limits JACKSONVILLE, FL - Recent tests with one of the nation's mid- to high-sulfur coals have further verified that a new electric generation technology in its first large-scale utility demonstration here is one of the world's cleanest coal-based power plants. This city's municipal utility JEA logged the achievement at its Northside Generating Station using Illinois No. 6 coal in a 300 megawatt demonstration of circulating fluidized bed (CFB) combustion, which is the largest application yet of the new form in the United States. It almost triples the size of a previous demonstration and scales up the technology to the sizes preferred for adding new plants and replacing old ones, also called repowering.

27

Quarterly Technical Progress Report - West Hackberry Tertiary Project  

SciTech Connect

The West Hackberry Tertiary Project is a field test of the concept that air injection can generate tertiary oil recovery through the Double Displacement Process is the gas displacement of a water invaded oil column for the purpose of recovering tertiary oil through gravity discharge. The novel aspect of this project is the use of air as the injection fluid.

Demetrois Yannimaras; Travis Gillham

1998-04-15T23:59:59.000Z

28

Quarterly Technical Progress Report - West Hackberry Tertiary Project  

SciTech Connect

The West Hackberry Tertiary Project is a field test of the concept that air injection can generate tertiary oil recovery through the Double Displacement Process is the gas displacement of a water invaded oil column for the purpose of recovering tertiary oil through gravity discharge. The novel aspect of this project is the use of air as the injection fluid.

Bruce Cerveny; Tor Kragas; Travis Gillham

1998-01-13T23:59:59.000Z

29

A SUMMARY OF COAL IN THE COALMONT FORMATION (TERTIARY),  

E-Print Network (OSTI)

Chapter SN A SUMMARY OF COAL IN THE COALMONT FORMATION (TERTIARY), NORTH PARK BASIN, COLORADO By S assessment of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great

30

Taming Matlab.  

E-Print Network (OSTI)

??MATLAB is a dynamic scientific language used by scientists, engineers and students worldwide. Although MATLAB is very suitable for rapid prototyping and development, MATLAB users… (more)

Dubrau, Anton

2012-01-01T23:59:59.000Z

31

Densities and isobaric vapor-liquid equilibria for the mixtures formed by four butyl esters and 1-butanol  

SciTech Connect

Densities of 298.15 K and the vapor-liquid equilibria for 1-butanol + butyl methanoate, + butyl ethanoate, + butyl propanoate, and + butyl butanoate have been measured at 101.32 kPa in small capacity ebulliometer. All results were found to be thermodynamically consistent with a point-to-point test. The mixtures containing butyl methanoate and butyl ethanoate show azeotropes at T = 379.14 K, x = 0.871 and T = 389.64 K, x = 0.222, respectively. Different group-contribution methods were applied to these mixtures.

Gonzalez, E.; Ortega, J. [Univ. of Las Palmas de Gran Canaria (Spain)] [Univ. of Las Palmas de Gran Canaria (Spain)

1996-01-01T23:59:59.000Z

32

Asymmetric synthesis of both enantiomers of esters and ?-lactones from optically active 1-chlorovinyl p-tolyl sulfoxides and lithium ester enolates with the formation of a tertiary or a quaternary carbon stereogenic center at the ?-position  

Science Journals Connector (OSTI)

Treatment of optically active 1-chlorovinyl p-tolyl sulfoxides having two different substituents at the 2-position, which were synthesized from aldehydes or unsymmetrical ketones and (R)-(?)-chloromethyl p-tolyl sulfoxide in two or three steps, with the lithium enolate of tert-butyl acetate gave optically active adducts in 99% chiral induction from the sulfur stereogenic center. The adducts were converted to optically active esters, carboxylic acids, and ?-lactones, which have a tertiary or a quaternary carbon stereogenic center at the ?-position. A synthesis of optically active spiro-lactones was realized starting from 2-cyclohexenone by this method.

Shimpei Sugiyama; Tsuyoshi Satoh

2005-01-01T23:59:59.000Z

33

TAME: A PVS Interface to Simplify Proofs for Automata Models Presented at UITP 98, Eindhoven, Netherlands, July 13-15, 1998  

E-Print Network (OSTI)

to provide theorem proving support for the SCR Software Cost Reduction requirements method, a method the SCR toolset 9, 6, 7 . The SCR tools are designed to support editing and performing various kinds into the SCR toolset, the user who wishes to apply TAME to an SCR speci cation will have rst-level interface

34

Shear viscosity measurements in the binary mixture butyl cellosolve-water near its upper and lower critical consolute points  

E-Print Network (OSTI)

has been measured for a two-component critical liquid system, butyl cellosolve-water, in the region to report measurements of the shear viscosity of critical binary mixture butyl cello- solve (2-n353 Shear viscosity measurements in the binary mixture butyl cellosolve-water near its upper

Boyer, Edmond

35

Aqueous flooding methods for tertiary oil recovery  

DOE Patents (OSTI)

A method of aqueous flooding of subterranean oil bearing formation for tertiary oil recovery involves injecting through a well into the formation a low alkaline pH aqueous sodium bicarbonate flooding solution. The flooding solution's pH ranges from about 8.25 to 9.25 and comprises from 0.25 to 5 weight percent and preferably about 0.75 to 3.0 weight percent of sodium bicarbonate and includes a petroleum recovery surfactant of 0.05 to 1.0 weight percent and between 1 and 20 weight percent of sodium chloride. After flooding, an oil and water mixture is withdrawn from the well and the oil is separated from the oil and water mixture.

Peru, Deborah A. (Bartlesville, OK)

1989-01-01T23:59:59.000Z

36

Blended language learning in tertiary education  

Science Journals Connector (OSTI)

This paper examines the supporting and enhancing role of technology in language learning and teaching in a higher education institution in Slovenia. Despite the fact that the vast majority of foreign language teaching is still carried out in face-to-face environments, a growing extent of foreign language teaching in a number of tertiary education institutions has moved, at least partly, online. In this paper, the development of e-learning practices in Slovenia is described first, together with the evolution of computer technologies – from multimedia to the internet – and their potential for language learning and teaching purposes. Against this background, the practical application of the Blended Language Learning (BLL) experience at the Faculty of Management Koper is discussed. The paper also addresses the changing role of teachers in blended language teaching/learning environments and analyses the opinions of students who participated in a combination of Face-to-Face (F2F) and Computer-Assisted Language Learning (CALL) courses and expressed their opinions on the BLL experience in a questionnaire.

Igor Riznar

2009-01-01T23:59:59.000Z

37

Effects of simulant mixed waste on EPDM and butyl rubber  

SciTech Connect

The authors have developed a Chemical Compatibility Testing Program for the evaluation of plastic packaging components which may be used in transporting mixed waste forms. In this program, they have screened 10 plastic materials in four liquid mixed waste simulants. These plastics were butadiene-acrylonitrile copolymer (Nitrile) rubber, cross-linked polyethylene, epichlorohydrin rubber, ethylene-propylene (EPDM) rubber, fluorocarbons (Viton and Kel-F{trademark}), polytetrafluoro-ethylene (Teflon), high-density polyethylene, isobutylene-isoprene copolymer (Butyl) rubber, polypropylene, and styrene-butadiene (SBR) rubber. The selected simulant mixed wastes were (1) an aqueous alkaline mixture of sodium nitrate and sodium nitrite; (2) a chlorinated hydrocarbon mixture; (3) a simulant liquid scintillation fluid; and (4) a mixture of ketones. The screening testing protocol involved exposing the respective materials to approximately 3 kGy of gamma radiation followed by 14-day exposures to the waste simulants at 60 C. The rubber materials or elastomers were tested using Vapor Transport Rate measurements while the liner materials were tested using specific gravity as a metric. The authors have developed a chemical compatibility program for the evaluation of plastic packaging components which may be incorporated in packaging for transporting mixed waste forms. From the data analyses performed to date, they have identified the thermoplastic, polychlorotrifluoroethylene, as having the greatest chemical compatibility after having been exposed to gamma radiation followed by exposure to the Hanford Tank simulant mixed waste. The most striking observation from this study was the poor performance of polytetrafluoroethylene under these conditions. In the evaluation of the two elastomeric materials they have concluded that while both materials exhibit remarkable resistance to these environmental conditions, EPDM has a greater resistance to this corrosive simulant mixed waste.

Nigrey, P.J.; Dickens, T.G.

1997-11-01T23:59:59.000Z

38

The Effect of the Di-Tertiary Butyl Peroxide (DTBP) additive on HCCI Combustion of Fuel Blends of Ethanol and Diethyl Ether  

E-Print Network (OSTI)

Ignition Using Isooctane, Ethanol and Natural Gas - AModel for High Temperature Ethanol Oxidation," Internationalof Bio-Derived Carbon from Ethanol-in-Diesel Blends in the

Mack, John Hunter; Buchholz, Bruce A; Flowers, Daniel L; Dibble, Robert W

2005-01-01T23:59:59.000Z

39

A SUMMARY OF COAL IN THE FORT UNION FORMATION (TERTIARY), BIGHORN BASIN,  

E-Print Network (OSTI)

Chapter SB A SUMMARY OF COAL IN THE FORT UNION FORMATION (TERTIARY), BIGHORN BASIN, WYOMING assessment of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U...........................................................................................................................SB-1 Coal Production History

40

E-Print Network 3.0 - australian tertiary referral Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Darwin Institution Programme Summary: ANUTECH (Australian National University) Foundation Studies Program Australian National University... for Tertiary Studies) Batchelor...

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE  

E-Print Network (OSTI)

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE SURVEYS By Michael J. Moran, Rick M. Clawges, and John S. Zogorski U.S. Geological Survey 1608 Mt. View Rapid City, SD 57702 Methyl tert-butyl ether (MTBE) is commonly added to gasoline

42

EXECUTIVE SUMMARY TERTIARY COAL RESOURCES IN THE NORTHERN  

E-Print Network (OSTI)

EXECUTIVE SUMMARY TERTIARY COAL RESOURCES IN THE NORTHERN ROCKY MOUNTAINS AND GREAT PLAINS REGION RockyMountains and Great Plains region, U.S. Geological Survey Professional Paper 1625-A Click here in the Northern Rocky Mountains and Great Plains region, U.S. Geological Survey Professional Paper 1625-A #12;ES

43

Separation of methyl t-butyl ether from close boiling C[sub 5] hydrocarbons by extractive distillation  

SciTech Connect

A method for recovering methyl t-butyl ether from a mixture of methyl t-butyl ether and 1-pentene which comprises distilling a mixture of methyl t-butyl ether and 1-pentene in the presence of about one part of an extractive agent per part of methyl t-butyl ether -- 1-pentene mixture, recovering the 1-pentene as overhead product and obtaining the methyl t-butyl ether and the extractive agent from the still pot, wherein said extractive agent consists of one material selected from the group consisting of sulfolane, nitroethane, t-butanol, ethylene glycol diacetate, 1-methoxy-2-propanol acetate, methyl isoamyl ketone, ethylene glycol methyl ether, propylene glycol phenyl ether and diethyl malonate.

Berg, L.

1993-07-20T23:59:59.000Z

44

Palladium/Tris(tert-butyl)phosphine-Catalyzed Suzuki Cross-Couplings in the Presence of Water  

E-Print Network (OSTI)

Dipalladiumtris(dibenzylideneacetone)/tris(tert-butyl)phosphonium tetrafluoroborate/potassium fluoride dihydrate [Pd2(dba)3/[HP(t-Bu)3]BF4/KF?2?H2O] serves as a mild, robust, and user-friendly method for the efficient ...

Lou, Sha

45

Pool octanes via oxygenates  

SciTech Connect

Increasingly stringent antipollution regulations placed on automobile exhaust gases with consequent reduction or complete lead ban from motor gasoline result in octane shortage at many manufacturing sites. Attractive solutions to this problem, especially in conjunction with abundant methanol supplies, are the hydration and etherification of olefins contained in light product streams from cracking unit or produced by field gas dehydrogenation. A comparison is made between oxygenates octane-volume pool contributions and established refinery technologies. Process reviews for bulk manufacture of fuel-grade isopropanol (IPA), secondary butanol (SBA), tertiary butanol (TBA), methyl tertiary butyl ether (MTBE) and tertiary amyl methyl ether (TAME) are presented together with the characteristic investment and operating data. The implantation of these processes into a typical FCCU refinery complex with the resulting octane-pool improvement possibilities is descried.

Prezelj, M.

1987-09-01T23:59:59.000Z

46

Extraction of Plutonium into 30 Percent Tri-Butyl Phosphate from Nitric Acid Solution Containing Fluoride, Aluminum, and Boron  

SciTech Connect

This work consists of experimental batch extraction data for plutonium into 30 volume-percent tri-butyl phosphate at ambient temperature from such a solution matrix and a model of this data using complexation constants from the literature.

Kyser, E.A.

2000-01-06T23:59:59.000Z

47

Whole-Genome Analysis of Methyl tert-Butyl Ether-Degrading Beta-Proteobacterium Methylibium petroleiphilum PM1  

E-Print Network (OSTI)

Sato, and N. Kato. 2003. Propane monooxygenase and NAD + -alcohol dehydrogenase in propane metabolism by Gordonia sp.tert-butyl ether by propane-grown Mycobacterium vaccae JOB5.

2007-01-01T23:59:59.000Z

48

Aging of Weapon Seals – An Update on Butyl O-ring Issues  

SciTech Connect

During testing under the Enhanced Surveillance Campaign in 2001, preliminary data detected a previously unknown and potentially serious concern with recently procured butyl o-rings on several programs. All butyl o-rings molded from a proprietary formulation throughout the period circa 1999 through 2001 had less than a full cure. Engineering judgment was that under curing is detrimental and could possibly lead to sub-optimum performance or, in the worst case, premature seal failure. An aging study was undertaken to ensure that suspect o-rings installed in the stockpile will retain sufficient sealing force for a minimum ten-year service life. A new prediction model developed for this study indicates suspect o-rings do not need to be replaced before the ten-year service life. Long-term testing results are reported on a yearly basis to validate the prediction model. This report documents the aging results for the period September 2002 to January 2011.

Wilson, Mark H.

2011-07-13T23:59:59.000Z

49

Dynamic Simulation of Startup in Ethyl tert-Butyl Ether Reactive Distillation with Input Multiplicity  

Science Journals Connector (OSTI)

Dynamic Simulation of Startup in Ethyl tert-Butyl Ether Reactive Distillation with Input Multiplicity ... However, smaller internal rates inside the column that result from lower reboiler and condenser duty could increase the potential risk of flooding in the column and reduce the availability of reactants in the reactive section. ... Column simulations performed using both Pro/II and SpeedUp showed excellent agreement with previously published exptl. ...

Budi H. Bisowarno; Moses O. Tadé

2000-05-09T23:59:59.000Z

50

Reverse osmosis performance with solutions containing tri-n-butyl phosphate  

SciTech Connect

Tests were conducted to determine whether the reverse osmosis (RO) units at the F/H Effluent Treatment Facility (ETF) at the Savannah River could be made to process solutions containing tri-n-butyl phosphate (TBP). It was desired to test whether operation at a feed pH other than neutral would improve performance. Test results are discussed in this report and indicate that little improvement in the water flux can be expected at other pH values.

Siler, J.L.

1991-10-22T23:59:59.000Z

51

Batch polymerization of styrene initiated by n-butyl lithium in a cyclohexane solvent  

E-Print Network (OSTI)

anionic mechanism. A mathematical model is de- veloped and the predicted values are compared with their corresponding experimental values. Initiator and monomer concentrations are varied and their conversion time profiles are studied. A G&el... and Storage Vessels Purification of Monomer Purification of Solvent Polymerization Reaction Scavenger Level Analysis o f Butyl Lithium Analysis of Molecular Weight Distributions by the Use of Gel Permeation Technique 10 19 19 ZO Zl ZZ 24 25 25...

Landon, Thomas Rodman

1971-01-01T23:59:59.000Z

52

E-Print Network 3.0 - academic tertiary care Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

of Rochester, Rochester, New York 14627 (Received 1 April 1996) Tertiary protons with birth... targets, such as those planned for the National Ignition Facility. Measurement of...

53

An investigation into diglossia, literacy, and tertiary-level EFL classes in the Arabian Gulf States.  

E-Print Network (OSTI)

??This study investigates whether the remedial tertiary-level EFL classes in the Arabian Gulf States optimize the process of acquiring English for the majority of the… (more)

Rivard, Jane Nathalie.

2006-01-01T23:59:59.000Z

54

E-Print Network 3.0 - alcohols aromatic tertiary Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: in their synthesis include the use of a nucleophilic aromatic substitution reaction to construct the chiral tertiary... of 13-membered macrolactams that possess a...

55

E-Print Network 3.0 - aromatic tertiary alcohols Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: in their synthesis include the use of a nucleophilic aromatic substitution reaction to construct the chiral tertiary... of 13-membered macrolactams that possess a...

56

The identification of recurrent tertiary motifs by interactions of protein secondary structure units  

E-Print Network (OSTI)

. Through an informatics analysis of recurrent tertiary contacts, we have derived a database of recurrent tertiary motifs. A group of 691 high-resolution, non-redundant protein structures was obtained. For each protein in this source data, we found all...

Hodges, Hamilton Courtney

2013-02-22T23:59:59.000Z

57

Test of Orientation/Stretch-Induced Reduction of Friction via Primitive Chain Network Simulations for Polystyrene, Polyisoprene, and Poly(n-butyl acrylate)  

Science Journals Connector (OSTI)

Test of Orientation/Stretch-Induced Reduction of Friction via Primitive Chain Network Simulations for Polystyrene, Polyisoprene, and Poly(n-butyl acrylate) ...

Yuichi Masubuchi; Yumi Matsumiya; Hiroshi Watanabe

2014-09-24T23:59:59.000Z

58

Synthesis and Evaluation of 3',5'-Di-tert-butyl-4'-hydroxyflavones as Potential Inhibitors of Low Density Lipoprotein (LDL) Oxidation  

Science Journals Connector (OSTI)

Synthesis and Evaluation of 3',5'-Di-tert-butyl-4'-hydroxyflavones as Potential Inhibitors of Low Density Lipoprotein (LDL) Oxidation ...

Guy Lewin; Yves Rolland; Sylvie Privat; Christine Breugnot; Albert Lenaers; Jean Paul Vilaine; Jean-Pierre Baltaze; Jacques Poisson

1995-12-01T23:59:59.000Z

59

Detection and Quantification of Methyl tert-Butyl Ether-Degrading Strain PM1 by Real-Time TaqMan PCR  

Science Journals Connector (OSTI)

...purification Fresh Water microbiology Geologic...Polymerase metabolism Water Pollution, Chemical...bioremediation detection ethers ground water hydrocarbons methyl tert-butyl...pollutants pollution remediation sampling water resources...

Krassimira R. Hristova; Christian M. Lutenegger; Kate M. Scow

2001-11-01T23:59:59.000Z

60

1,4,7-Trimethyloxatriquinane: SN2 Reaction at Tertiary Carbon Mark Mascal,* Nema Hafezi, and Michael D. Toney  

E-Print Network (OSTI)

1,4,7-Trimethyloxatriquinane: SN2 Reaction at Tertiary Carbon Mark Mascal,* Nema Hafezi for the reaction between 1 and N3 - is SN2, despite the fact that substitution is occurring at a tertiary carbon chemistry textbooks, is that bimolecular nucleophilic substitution (SN2) reactions do not occur at tertiary

Toney, Michael

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Batch polymerization of styrene and isoprene by n-butyl lithium initiator  

E-Print Network (OSTI)

-20). Analysis of products consists of determining the point at which no free lithium alkyl remains. Thus if a butyl lithium initiated polymerization were terminated with water, butane would be evolved as long as the initiator were present. The butane...? agent were evaporated under a hood. Finally the polymer. was dried in a vacuum oven at about 50'C and under a vacuum of 30 inches of gg for about 30 hours. The weight of polymer formed was determined by final weighing. 25 The monomer conversion...

Hasan, Sayeed

1970-01-01T23:59:59.000Z

62

Isobaric vapor-liquid equilibria in the system methyl propanoate + n-butyl alcohol  

SciTech Connect

Isobaric vapor-liquid equilibria were determined at 74.66, 101.32, and 127.99 kPa for binary mixtures containing methyl propanoate + n-butyl alcohol by using a dynamic still with vapor and liquid circulation. No azeotrope was detected. The data were found to be thermodynamically consistent according to the point to point test. Application of the group-contribution models ASOG, UNIFAC, and modified UNIFAC to the activity coefficients at the three pressures studied gives average errors of less than 10%, 11%, and 3%, respectively.

Susial, P.; Ortega, J. (Univ. de Las Palmas de Gran Canaria, Canary Islands (Spain). Lab. de Termodinamica y Fisicoquimica)

1993-10-01T23:59:59.000Z

63

Origin of gaseous hydrocarbons from Upper Cretaceous and Tertiary strata in the Piceance basin, western Colorado  

E-Print Network (OSTI)

Natural gas samples were collected for geochemical analyses from Upper Cretaceous and Tertiary strata of the Piceance basin in western Colorado to: 1) determine the origin of gases (i.e., microbial versus thermogenic), 2) determine the thermogenic...

Katz, David Jonathan

2012-06-07T23:59:59.000Z

64

Petrogenesis of voluminous mid-Tertiary ignimbrites of the Sierra Madre Occidental, Chihuahua, Mexico  

Science Journals Connector (OSTI)

The mid-Tertiary ignimbrites of the Sierra Madre Occidental of western Mexico constitute the largest continuous rhyolitic province in the world. The rhyolites appear to represent part of a continental magmatic...

Maryellen Cameron; William C. Bagby…

1980-10-01T23:59:59.000Z

65

Radiation dose levels during interventional cardiology procedures in a tertiary care hospital  

Science Journals Connector (OSTI)

......cardiology procedures in a tertiary care hospital O. Dragusin 1 W. Desmet 2 H. Heidbuchel...Department of Radiology, University Hospital Gasthuisberg, Herestraat 49, B-3000...Department of Cardiology, University Hospital Gasthuisberg, Herestraat 49, B-3000......

O. Dragusin; W. Desmet; H. Heidbuchel; R. Padovani; H. Bosmans

2005-12-01T23:59:59.000Z

66

A SUMMARY OF TERTIARY COAL RESOURCES OF THE RATON BASIN, COLORADO AND NEW MEXICO  

E-Print Network (OSTI)

............................................................................................................SR-13 Coal-bed Methane and potential coal-bed methane production in Raton Basin. Adapted from Hemborg (1996). 1999 RChapter SR A SUMMARY OF TERTIARY COAL RESOURCES OF THE RATON BASIN, COLORADO AND NEW MEXICO By R

67

Stochastic Programming Approach to Hydraulic Fracture Design for the Lower Tertiary Gulf of Mexico  

E-Print Network (OSTI)

In this work, we present methodologies for optimization of hydraulic fracturing design under uncertainty specifically with reference to the thick and anisotropic reservoirs in the Lower Tertiary Gulf of Mexico. In this analysis we apply a stochastic...

Podhoretz, Seth

2013-07-27T23:59:59.000Z

68

Nonlinear viscoelastic response of carbon black-filled butyl rubber and implications for o-ring aging  

SciTech Connect

Butyl rubber, unfortunately, has pronounced nonlinear viscoelastic behavior, which may be modelled by a separable KBKZ formalism. While these effects seem to have minimal impact on accelerated sealing force measurements, they do severely impact compression set tests. Therefore, a new test is suggested for evaluating field-return o-rings which is free from such confounding effects.

Adolf, D.

1997-11-01T23:59:59.000Z

69

Rate dependent finite deformation stressstrain behavior of an ethylene methacrylic acid copolymer and an ethylene methacrylic acid butyl  

E-Print Network (OSTI)

Rate dependent finite deformation stress­strain behavior of an ethylene methacrylic acid copolymer and an ethylene methacrylic acid butyl acrylate copolymer S. Deschanel a,*, B.P. Greviskes a , K. Bertoldi a , S dependence a b s t r a c t The large strain deformation behaviors of an ethylene methacrylic acid (EMAA

70

Ultrasonic absorption associated with tertiary butanol complex formation in normal-hexane solutions  

E-Print Network (OSTI)

ULTRASONIC ABSORPTION ASSOCIATED WITH TERTIARY BUTANOL COMPLEX FORMATION IN NORMAL-HEXANE SOLUTIONS A Thesis by SALIM MICHEL BUCARAM Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 196l Major Subject; Physics ULTRASONIC ABSORPTION ASSOCIATED WITH TERTIARY BUTANOL COMPLEX FORMATION IN NORMAL-HEXANE SOLUTIONS A Thesis by SALIM MICHEL BUCARAM Approved as to style and content by...

Bucaram, Salim Michel

2012-06-07T23:59:59.000Z

71

Liquid phase oxidation of thiophene compounds by tert-butyl hydroperoxide  

SciTech Connect

Oxidative instability problems in both shale and petroleum-derived middle distillate fuels are related to the presence of hydroperoxides. Although a good body of knowledge exists concerning the formation of peroxides in the liquid phase, relatively little is known about the reaction/decomposition pathways when other functional groups are present. One of the significant and undesirable problems is the formation of solid deposits which can plug nozzles and filters and coal heat exchanger surfaces. Deposit formation in fuels is triggered by autoxidation reactions and is closely associated with elemental oxygen and/or hydroperoxide concentration. This paper reports on the reaction between a primary autoxidation product, a hydroperoxide, and sulfur compounds of the type present in petroleum-derived middle distillate fuels. Specifically, we examine the t-butyl hydroperoxide oxidation of thiophene, 2, 5-dimethylthiophene, tetrahydrothiophene and benzothiophene in a deaerated model fuel, tetradecane, at 120{degree}C.

Mushrush, G.W.; Watkins, J.M. Jr.; Hazlett, R.N.; Hardy, D.R.; Eaton, H.G. (Naval Research Laboratory, Washington, DC (USA))

1987-08-01T23:59:59.000Z

72

Fuel instability studies; Liquid phase oxidation of tetrahydrothiophene by tert-butyl hydroperoxide  

SciTech Connect

The reactions that lead to fuel instability are the subject of conflicting reports in the literature. Confusion results from the difficulty in relating differences in fuel composition, temperature, surface effects and dissolved oxygen content that comprise the multitude of reported studies. Model studies offer a means by chic the mechanism of an individual reaction can be related to a simple system and then extended to the more complex fuel media. This paper reports a model oxidation study of a species, t-butyl hydroperoxide under mild reaction conditions, 120{degrees}C, in a tetradecane model fuel. The major oxidation product was tetrahydrothiophene sulfoxide from the sulfide and t-butanol from the hydroperoxide. The complete suite of products is reported.

Mushrush, G.W.; Pellenbarg, R.E.; Hazlett, R.N.; Morris, R.E.; Hardy, D.R. (Fuels Section, Code 6180, Naval Research Lab., Washington, DC (US))

1991-01-01T23:59:59.000Z

73

Tests for mutagenic effects of ammoniated glycyrrhizin, butylated hydroxytoluene, and gum arabic in roden germ cells  

SciTech Connect

Ammoniated glycyrrhizin, butylated hydroxytoluene, and gum Arabic are generally recognized as safe (GRAS) substances that are used primarily as additives in foods. These substances were incorporated into rodent diets and fed to male rats and mice for 10 and 8 wk, respectively. The treated male mice and rats were then tested for dominant lethal effects. The mice were also tested for induced heritable translocation. Results of the rat studies indicated a statistically significant dominant lethal effect of each of the compounds tested; however, the biological significance of this response is not known. Results of the mouse dominant lethal and heritable translocation studies, on the other hand, indicated no adverse effects of the compounds tested.

Sheu, C.W.; Cain, K.T.; Rushbrook, C.J.; Jorgenson, T.A.; Generoso, W.M.

1986-01-01T23:59:59.000Z

74

Butyl rubber O-ring seals: Revision of test procedures for stockpile materials  

SciTech Connect

Extensive testing showed little correlation between test slab and O-ring performance. New procedures, comparable to those used with the traditional test slabs, were defined for hardness, compression set, and tensile property testing on sacrificial O-ring specimens. Changes in target performance values were made as needed and were, in one case, tightened to reflect the O-ring performance data. An additional study was carried out on O-ring and slab performance vs cure cycle and showed little sensitivity of material performance to large changes in curing time. Aging and spectra of certain materials indicated that two sets of test slabs from current vendor were accidently made from EPDM rather than butyl rubber. Random testing found no O-rings made from EPDM. As a result, and additional spectroscope test will be added to the product acceptance procedures to verify the type of rubber compound used.

Domeier, L.A.; Wagter, K.R.

1996-12-01T23:59:59.000Z

75

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction  

SciTech Connect

In a review of the safety basis for solvent extraction processes at the Department of Energy's Savannah River Site, a question was raised concerning the safety margin associated with a postulated accident involving a runaway tri-n-butyl phosphate (TBP)/nitric acid reaction due to the inadvertent heating of a tank. The safety margin was based on studies which showed the maximum temperature would not exceed 128 degrees Celsius compared to 130 degrees Celsius, the minimum initiation temperature for runaway reaction established in the 1950's following damaging incidents at the Savannah River and Hanford Sites. The reviewers were concerned the minimum temperature was not conservative since data for solutions containing 20 wt percent dissolved solids showed initiation temperatures at or below 130 degrees Celsius and process solutions normally contain some dissolved solids.

Rudisill, T.S.

2001-09-14T23:59:59.000Z

76

A thermodynamic model of nitric acid extraction by tri-n-butyl phosphate  

SciTech Connect

A thermodynamic model is presented for nitric acid extraction by tri-n-butyl phosphate (TBP). This model is based on the formation of the organic phase species: TBP.HNO/sub 3/ and (TBP)/sub 2/.HNO/sub 3/. The model works successfully at TBP concentrations of 5 to 100 vol% and was found to be effective at predicting the extraction of HNO/sub 3/ from HNO/sub 3//NaNO/sub 3/ and HNO/sub 3//LiNO/sub 3/ solutions. Within the TBP concentration range of 5 to 30%, a single set of extraction constants was sufficient to fit extraction data. Stoichiometric activity coefficients of nitric acid in HNO/sub 3//NaNO/sub 3/ and HNO/sub 3//LiNO/sub 3/ mixtures were calculated using a model developed by Bromley.

Chaiko, D.J.; Vandegrift, G.F.

1988-07-01T23:59:59.000Z

77

Atmospheric chemistry of diethyl ether and ethyl tert-butyl ether  

SciTech Connect

The mechanisms for the Cl-initiated and OH-initiated atmospheric oxidation of diethyl ether and ethyl tert-butyl ether (ETBE) have been determined. For diethyl ether the products are ethyl formate and formaldehyde and its atmospheric oxidation can be represented by C{sub 2}H{sub 5}OC{sub 2}H{sub 5} + OH + 2NO {yields} C{sub 2}H{sub 5}OC(O)H + HCHO + 2NO{sub 2} + HO{sub 2}. The mechanism for the atmospheric oxidation of ETBE is more complex, with 80% of the reaction being accounted for in terms of tert-butyl formate and formaldehyde. The remaining 20% the authors ascribe to 2-ethoxy-2-methylpropanal. The atmospheric oxidation of ETBE can be represented by ETBE + OH + 1.8NO {yields} 0.8HCOOC(CH{sub 3}){sub 3} + 0.2C{sub 2}H{sub 5}OC(CH{sub 3}){sub 2}CHO + HO{sub 2} + 0.8HCHO + 1.8NO{sub 2}. THe subsequent atmospheric chemistry of 2-ethoxy-2-methylpropanal the authors estimate to be represented by C{sub 2}H{sub 5}OC(CH{sub 3}){sub 2}CHO + OH + 3NO {yields} CO{sub 2} + H{sub 2}CO + C{sub 2}H{sub 5}OC(O)CH{sub 3} + HO{sub 2} + 3NO{sub 2}. These results are discussed in terms of the reactivity of these compounds in urban atmospheres.

Wallington, T.J.; Japar, S.M. (Ford Motor Company, Dearborn, MI (USA))

1991-03-01T23:59:59.000Z

78

A review of Tertiary climate changes in southern South America and the Antarctic Peninsula. Part 1: Oceanic conditions .  

E-Print Network (OSTI)

??Oceanic conditions around southern South America and the Antarctic Peninsula have a major influence on climate patterns in these subcontinents. During the Tertiary, changes in… (more)

Le Roux, J. P.

2012-01-01T23:59:59.000Z

79

Hydrolysis of cellulose to produce glucose with solid acid catalysts in 1-butyl-3-methyl-imidazolium chloride ([bmIm][Cl]) with sequential water addition  

Science Journals Connector (OSTI)

Selective glucose production by cellulose hydrolysis with initial or sequential water addition in the presence of solid acid catalysts in 1-butyl-3-methyl-imidazolium chloride ([bmIm][Cl]) under microwave irra...

Kaori Ishida; Shiho Matsuda; Masaru Watanabe…

2014-12-01T23:59:59.000Z

80

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction  

SciTech Connect

During a review of the H-Canyon authorization basis, Defense Nuclear Facility Safety Board (DNFSB) staff members questioned the margin of safety associated with a postulated tri-n-butyl phosphate (TBP)/nitric acid runaway reaction due to the inadvertent heating of a canyon tank containing greater than 3000 lbs (1362 kg) of TBP. The margin of safety was partially based on experiments and calculations performed by the Actinide Technology Section (ATS) to support deletion of indication of tank agitation as a Safety Class System. In the technical basis for deletion of this system, ATS personnel conservatively calculated the equilibrium temperature distribution of a canyon tank containing TBP and nitric acid layers which were inadvertently heated by a steam jet left on following a transfer. The maximum calculated temperature (128 degrees C) was compared to the minimum initiation temperature for a runaway reaction (greater than 130 degrees C) documented by experimental work in the mid 195 0s. In this work, the initiation temperature as a function of nitric acid concentration was measured for 0 and 20 wt percent dissolved solids. The DNFSB staff members were concerned that data for 0 wt percent dissolved solids were not conservative given the facts that data for 20 wt percent dissolved solids show initiation temperatures at or below 130 degrees C and H-Canyon solutions normally contained a small amount of dissolved solids.

Rudisill, T.S.

2000-11-28T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Thorium ions transport across Tri-n-butyl phosphate-benzene based supported liquid membranes  

SciTech Connect

Transport of Th(IV) ions across tri-n-butyl phosphate (TBP) benzene based liquid membranes supported in microporous hydrophobic polypropylene film (MHPF) has been studied. Various parameters such as variation of nitric acid concentration in the feed, TBP concentration in the membrane, and temperature on the given metal ions transport have been investigated. The effects of nitric acid and TBP concentrations on the distribution coefficient were also studied, and the data obtained were used to determine the Th ions-TBP complex diffusion coefficient in the membrane. Permeability coefficients of Th(IV) ions were also determined as a function of the TBP and nitric acid concentrations. The optimal conditions for the transport of Th(IV) ions across the membrane are 6 mol{sm_bullet}dm{sup -3} HNO{sub 3} concentration, 2.188 mol {center_dot} dm{sup -3} TBP concentration, and 25{degrees}C. The stoichiometry of the chemical species involved in chemical reaction during the transport of Th(IV) ions has also been studied.

Rasul, G.; Chaudry, M.A. [Pakistan Institute of Nuclear Chemistry, Islamabad (Pakistan); Afzal, M. [Quaid-I-Azam Univ., Islamabad (Pakistan)

1995-12-01T23:59:59.000Z

82

Short report Doctors leaving 12 tertiary hospitals in Iraq, 20042007q  

E-Print Network (OSTI)

Short report Doctors leaving 12 tertiary hospitals in Iraq, 2004­2007q Gilbert M. Burnham a 21205, USA b Al Mustansiriya, Baghdad, Iraq a r t i c l e i n f o Article history: Available online 6 June 2009 Keywords: Iraq Doctors Violence Doctor migration Hospitals Medical workforce a b s t r a c

Scharfstein, Daniel

83

New surfactant classes for enhanced oil recovery and their tertiary oil recovery potential  

E-Print Network (OSTI)

commercial scale projects were also executed. Nowadays, because of the high oil price, this technology hasNew surfactant classes for enhanced oil recovery and their tertiary oil recovery potential Stefan States a b s t r a c ta r t i c l e i n f o Article history: Received 23 February 2009 Accepted 14

Goddard III, William A.

84

Interplay between Secondary and Tertiary Structure Formation in Protein Folding Cooperativity  

E-Print Network (OSTI)

Interplay between Secondary and Tertiary Structure Formation in Protein Folding Cooperativity¨lich, 52425 Ju¨lich, Germany Received June 14, 2010; E-mail: deserno@andrew.cmu.edu Abstract: Protein folding be difficult to measure. Therefore, protein folding cooperativity is often probed using the calorimetric

Bachmann, Michael

85

Occurrence and Implication of dissolved organic phosphorus (DOP) in tertiary wastewater Effluents Page 1 of 6  

E-Print Network (OSTI)

GU, APRIL Occurrence and Implication of dissolved organic phosphorus (DOP) in tertiary wastewater wastewater effluents L. Liu1 , D. S. Smith2 , M. Bracken3 , J.B. Neethling4 , H.D. Stensel5 and S. Murthy6 levels (e.g. TPwastewater treatment plants. A few previous studies (Benisch et al., 2007

Brody, James P.

86

An Efficient Genetic Algorithm for Predicting Protein Tertiary Structures in the 2D HP Model  

E-Print Network (OSTI)

, predicting its tertiary structure is known as the protein folding problem. This problem has been widely genetic algo- rithm for the protein folding problem under the HP model in the two-dimensional square Genetic Algorithm, Protein Folding Problem, 2D HP Model 1. INTRODUCTION Amino acids are the building

Istrail, Sorin

87

Soluble, Infrared-Absorbing Croconate Dyes from 2,6-Di-tert-butyl-4-methylchalcogenopyrylium Salts  

Science Journals Connector (OSTI)

1 Although many squarylium dyes have limited solubility in organic solvents or in coated organic films, squarylium dyes 1 (Chart 1) derived from 2,6-di-tert-butyl-4-methylchalcogenopyrylium salts (2)3 are soluble and have been coated in organic thin films for a variety of applications. ... The croconates are readily prepared, are soluble in organic solvents, and have absorption maxima that cover a broad range of laser emission lines from gallium?arsenide diode lasers (?820 nm) to the neodinium-YAG laser (1064 nm). ... The reaction mixture was poured into water (50 mL), and the product was extracted with hexanes (3 × 25 mL). ...

Todd P. Simard; Jian H. Yu; Jennifer M. Zebrowski-Young; Neil F. Haley; Michael R. Detty

2000-03-03T23:59:59.000Z

88

MTBE Production Economics (Released in the STEO April 2001)  

Reports and Publications (EIA)

The purpose of this analysis is to evaluate the causes of methyl tertiary butyl ether (MTBE) price increases in 2000.

2001-01-01T23:59:59.000Z

89

Play analysis and stratigraphic position of Uinta Basin tertiary - age oil and gas fields  

SciTech Connect

Tertiary-age sediments in the Uinta basin produce hydrocarbons from five types of plays. These play types were determined by hydrocarbon type, formation, depositional environment, rock type, porosity, permeability, source, and per-well recovery. Each well was reviewed to determine the stratigraphic position and producing characteristics of each producing interval. The five types of plays are as follows: (1) naturally fractured oil reservoirs, (2) low-permeability oil reservoirs, (3) high-permeability of oil reservoirs, (4) low-permeability gas reservoirs, and (5) tight gas sands. Several fields produce from multiple plays, which made it necessary to segregate the hydrocarbon production into several plays. The stratigraphic position of the main producing intervals is shown on a basin-wide cross section, which is color-coded by play type. This 61-well cross section has several wells from each significant Tertiary oil and gas field in the Uinta basin.

Williams, R.A. (Pennzoil Exploration and Production Co., Houston, TX (United States))

1993-08-01T23:59:59.000Z

90

Concentrating aqueous volatile fatty acid salt solutions using a tertiary amine mixture  

E-Print Network (OSTI)

, and that reaction is difficult to reverse (Streitwieser and Heathcock, 1976; King and Poole, 1994). Tertiary amines (R, N) do not form amides but generally give lower K, values than secondary amines. For the extraction of undissociated carboxylic acids, aliphatic... by acidifying with carbon dioxide under pressure in the presence of a suitable solvent (Busche, 1988). Gregor has used electrodialysis to recover acetic acid from dilute (1-5 wt%) acetate solutions. With newer membranes, acid concentrations up to 30% were...

Gaskin, David J

1997-01-01T23:59:59.000Z

91

Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-  

E-Print Network (OSTI)

Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

92

Molybdenum recovery  

SciTech Connect

This patent describes a process for the preparation of propylene oxide and tertiary butyl alcohol. It comprises: propylene and tertiary butyl hydroperoxide are reacted in an epoxidation reaction zone in solution in tertiary butyl alcohol in the presence of a soluble molybdenum catalyst to provide an epoxidation reaction product comprising unreacted propylene, unreacted tertiary butyl hydroperoxide, propylene oxide, tertiary butyl alcohol, dissolved molybdenum catalyst and impurities, including lower aliphatic C{sub 1}-C{sub 4} carboxylic acids, and wherein the epoxidation reaction product is resolved into product fractions in a distillation zone including a distillate propylene fraction.

Meyer, R.A.; Marquis, E.T.

1992-03-31T23:59:59.000Z

93

Has the National Health Insurance improved the inequality in the use of tertiary-care hospitals in Korea?  

Science Journals Connector (OSTI)

AbstractBackground To improve financial protection against catastrophic illness, the Korean government expanded the benefit coverage of the National Health Insurance (NHI) for cancer patients in 2005. This paper examined whether the policy has reduced income-inequality in the use of tertiary care hospitals. Methods We evaluated the effect of the policy on income-inequalities in outpatient visits and inpatient admissions to tertiary care hospitals, based on triple difference estimators. Using nationwide claims data of the NHI from 2002 to 2010, we compared cancer patients as a treatment group with liver disease and cardio-cerebrovascular disease as control groups and the lower-income with the highest-income group. Results Before the introduction of the policy, lower-income cancer patients utilized less inpatient and outpatient services in tertiary care hospitals than high-income patients did. After the benefit coverage was expanded, while the incidence and total number of inpatient admissions to tertiary care hospitals increased among cancer patients compared with liver diseases, lower-income cancer patients experienced a greater increase than those of higher-income did compared with both diseases. The use of outpatient services increased more in cancer patients than those of both diseases; however, the gap between the highest- and the lowest-income rarely decreased, except the incidence of visits when compared to liver disease. Conclusion Our findings indicated that the expanded NHI benefits coverage partially improved income-related inequalities in inpatient admissions to tertiary-care hospital, but not in outpatient visits.

Sujin Kim; Soonman Kwon

2014-01-01T23:59:59.000Z

94

Plant observation report and evaluation, Pennwalt Corporation, secondary and tertiary aliphatic monoamines  

SciTech Connect

A site visit was made to the amine manufacturing facility of the Pennwalt Corporation, Wyandotte, Michigan, to evaluate the facility in regard to the Secondary and Tertiary Aliphatic Monoamines Criteria Document. A total of 21 people were directly in contact with the amine production process. Two to four of the maintenance personnel may also come in contact with the process. Maintenance workers ran the risk of exposure not only to primary, secondary and tertiary amine compounds, but also to several other chemicals being used in the process. The processes used to unload raw materials are described, along with reactor operations, decanter and recycling operations, distillation operations, product storage and shipping. Medical monitoring at the facility included chest x-ray, respiratory function tests, sight screening, urinalysis, and back x-rays. Restricted and potentially hazardous area signs were clearly posted. Employees wore hard hats and safety glasses on the job as well as gloves, rubber boots, face shields, goggles, and respirators as necessary. Emergency procedures are described, including fire protection. Sanitation and personal hygiene are discussed, along with monitoring of the workplace conditions.

Not Available

1980-08-27T23:59:59.000Z

95

Environmental actions of agrochemicals 2. Histological effects of the herbicide/insecticide dinoseb-acetate (2-sec-butyl-4,6-dinitrophenyl acetate) on the spider miteTetranychus urticae (Acari: Tetranychidae) reared on herbicidetreatedPhaseolus vulgaris  

Science Journals Connector (OSTI)

The pure herbicidal compound dinoseb-acetate (2-sec-butyl-4,6-dinitrophenyl acetate) and its commercial formulation Aretit® were tested for their effects on the spider miteTetranychus urticae L. (Acari, Tetranych...

Ursula Mothes-Wagner; Harald K. Reitze…

1990-10-01T23:59:59.000Z

96

Densities and isobaric vapor-liquid equilibria of butyl esters (methanoate to butanoate) with ethanol at 101.32 kPa  

SciTech Connect

Vapor-liquid equilibrium and densities at 101.32 kPa have been determined for the binary systems formed by four butyl esters (from methanoate to butanoate) with ethanol. The four systems exhibit positive deviations from ideal behavior, and all data (p-T-x-y) were found to be thermodynamically consistent. The activity coefficients and the dimensionless function G{sup E}/RT of the solution were correlated with its concentration by different equations. Am azeotrope was found in the mixture butyl methanoate (1) + ethanol (2) at T = 350.9 K and x{sub 1} = y{sub 1} = 0.088. The group contribution models ASOG and modified UNIFAC gave fair predictions.

Gonzalez, E.; Ortega, J. [Univ. of Las Palmas de Gran Canaria (Spain)

1995-11-01T23:59:59.000Z

97

Use of ferric sulfate: acid media for the desulfurization of model compounds of coal. [Dibenzothiophene, diphenyl sulfide, di-n-butyl sulfide  

SciTech Connect

The objective of this work has been to investigate the ability of ferric sulfate-acid leach systems to oxidize the sulfur in model compounds of coal. Ferric iron-acid leach systems have been shown to be quite effective at removal of inorganic sulfur in coal. In this study, the oxidative effect of ferric iron in acid-leach systems was studied using dibenzothiophene, diphenyl sulfide, and di-n-butyl sulfide as models of organic sulfur groups in coal. Nitrogen and oxygen, as well as various transition metal catalysts and oxidants, were utilized in this investigation. Dibenzothiophene was found to be quite refractory to oxidation, except in the case where metavanadate was added, where it appears that 40% oxidation to sulfone could have occurred per hour at 150/sup 0/C and mild oxygen pressure. Diphenyl sulfide was selectively oxidized to sulfoxide and sulfone in an iron and oxygen system. Approximately 15% conversion to sulfone occurred per hour under these conditions. Some of the di-n-butyl sulfide was cracked to 1-butene and 1-butanethiol under similar conditions. Zinc chloride and ferric iron were used at 200/sup 0/C in an attempt to desulfonate dibenzothiophene sulfone, diphenyl sulfone, and di-n-butyl sulfone. Di-n-butyl sulfone was completely desulfurized on one hour and fragmented to oxidized parafins, while dibenzothiophene sulfone and diphenyl sulfone were unaffected. These results suggest that an iron-acid leach process could only selectively oxidize aryl sulfides under mild conditions, representing only 20% of the organic sulfur in coal (8% of the total sulfur). Removal through desulfonation once selective sulfur oxidation had occurred was only demonstrated for alkyl sulfones, with severe oxidation of the fragmented paraffins also occurring in one hour.

Clary, L.R.; Vermeulen, T.; Lynn, S.

1980-12-01T23:59:59.000Z

98

Identification of volatile butyl rubber thermal-oxidative degradation products by cryofocusing gas chromatography/mass spectrometry (cryo-GC/MS).  

SciTech Connect

Chemical structure and physical properties of materials, such as polymers, can be altered as aging progresses, which may result in a material that is ineffective for its envisioned intent. Butyl rubber formulations, starting material, and additives were aged under thermal-oxidative conditions for up to 413 total days at up to 124 %C2%B0C. Samples included: two formulations developed at Kansas City Plant (KCP) (%236 and %2310), one commercially available formulation (%2321), Laxness bromobutyl 2030 starting material, and two additives (polyethylene AC-617 and Vanax MBM). The low-molecular weight volatile thermal-oxidative degradation products that collected in the headspace over the samples were preconcentrated, separated, and detected using cryofocusing gas chromatography mass spectrometry (cryo-GC/MS). The majority of identified degradation species were alkanes, alkenes, alcohols, ketones, and aldehydes. Observations for Butyl %2310 aged in an oxygen-18 enriched atmosphere (18O2) were used to verify when the source of oxygen in the applicable degradation products was from the gaseous environment rather than the polymeric mixture. For comparison purposes, Butyl %2310 was also aged under non-oxidative thermal conditions using an argon atmosphere.

Smith, Jonell Nicole; White, Michael Irvin; Bernstein, Robert; Hochrein, James Michael

2013-02-01T23:59:59.000Z

99

Reaction of trans-dichloro-bis[N(1)-methyl-2-(arylazo)imidazole] ruthenium(II) with tertiary phosphines  

Science Journals Connector (OSTI)

Trans-dichloro-bis[N(1)-methyl-2-(arylazo)imidazol e] ruthenium(II) (tcc-Ru(MeL)2Cl2) reacts with tertiary phosphines giving rise to species of type [RuCl(P)-(MeL)2]+ and [Ru(P-P)(MeL)2]2+ in which Cl, P and P...

Tarun Kumar Misra; Chittaranjan Sinha

1999-04-01T23:59:59.000Z

100

Isotopic Data Bearing on the Origin of Mesozoic and Tertiary Granitic Rocks in the Western United States  

Science Journals Connector (OSTI)

...Granitic Rocks in the Western United States D. J...Utah, Arizona, and Colorado. The plutons, which...Utah, Arizona and Colorado. The plutons, which...California Cenozoic Colorado crust differentiation...Tertiary United States Utah Western U.S. 1983 03 23 The...

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Magnetostratigraphy of Tertiary sediments from the Hoh Xil Basin: implications for the Cenozoic tectonic history of the Tibetan Plateau  

Science Journals Connector (OSTI)

......consists mainly of the lake carbonate with some black oil shale (Liu Wang 1999). It disconformably overlies the Fenghuoshan...A, 326, 177-188. Liu Z. , Wang C., 1999. Oil shale in the Tertiary Hoh Xil basin, northern Qinghai-Tibet......

Zhifei Liu; Xixi Zhao; Chengshan Wang; Shun Liu; Haisheng Yi

2003-08-01T23:59:59.000Z

102

Alteration of the tertiary structure of the major bee venom allergen Api m 1 by multiple mutations is  

E-Print Network (OSTI)

Alteration of the tertiary structure of the major bee venom allergen Api m 1 by multiple mutations a recombinant form of the major bee venom allergen (Api m 1) with the final goal of reducing its IgE reactivity. This molecule (Api mut) contains 24 mutations and one deletion of 10 amino acids. The successive introduction

Gelb, Michael

103

Tectonostratigraphic reconstruction and lithofacies distribution of tertiary slope sedimentary rocks in the Western Mississippi Canyon area  

SciTech Connect

The distribution of upper Tertiary, sandstone-prone, deep-water sedimentary rocks from the vicinity of Cognac field, Mississippi Canyon (MC) 194, south of Mars field (MC763) is presented based on an integrated sequence stratigraphic analysis of seismic, well log, and biostratigraphic data. Paleo-salt distributions were reconstructed by plotting the changing positions of depocenters on five isopach maps generated from six key sequence boundaries. Depositional trends, projected under allochthonous salt sheets, indicated subsalt prospectivity. Sixteen sequences were interpreted and subdivided into three lowstand depositional units (basin-floor fan, slope fan, and prograding wedge). Thirty isochron/seismic facies maps were made to reveal the stratigraphic pattern through the late Tertiary. During the early Miocene, a salt-rimmed syncline centered north of Mars field in MC455 accumulated sediments. The salt rim collapsed, creating a middle Miocene turtle structure. Middle-late Miocene sand-rich turbidites bypassed this structure and were deposited to the south around Mars field and beyond. At the same time, another depotrough 30 mi east of Mars field channeled deep-water sands to the MC730 area. A late Miocene-early Pliocene counterregional fault striking parallel to the shelf edge formed as salt evacuated the area on the south side of the Cognac (MC194) and Lena (MC280) fields. This fault trapped the Pliocene reservoir sandstones that produce in these fields. Sedimentation during the late Pliocene-early Pleistocene was very slow (0.2m/1,000 yr) and characterized by thin, stacked, condensed sections of hemipelagic shale. Since the mid-Pleistocene, the Mississippi River has supplied sediments to the Mississippi Canyon area that have induced salt deformation that has in turn affected recent sedimentation.

Hannan, A.E.; Risch, D.L.; Chowdhury, A.N. [Geco-Prakla, Inc., Houston, TX (United States)

1994-12-31T23:59:59.000Z

104

Solvent Extraction Behavior of Neptunium (IV) Ions between Nitric Acid and Diluted 30% Tri-butyl Phosphate in the Presence of Simple Hydroxamic Acids  

SciTech Connect

Formo- and aceto-hydroxamic acids are very effective reagents for stripping tetravalent actinide ions such as Np(IV) and Pu(IV) ions from a tri-butyl phosphate phase into nitric acid. Distribution data for Np(IV) in the presence of these hydroxamate ions have now been accumulated and trends established. Stability constants for aceto-hydroxamate complexes of Np(IV) and Np(V) ions have also been determined in a perchlorate medium, and these reaffirm the affinity of hydroxamate ligands for actinide (IV) ions over actinyl (V,VI) ions.

Taylor, Robin J.; Sinkov, Sergey I.; Choppin, Gregory R.; May, Iain

2008-01-15T23:59:59.000Z

105

An evaluation of the 3M Organic Vapor Monitor #3500 as a short term exposure limit sampling device for acetone, methyl ethyl ketone, and methyl iso butyl ketone  

E-Print Network (OSTI)

. An exploded view of the monitor is illustrated in Figure 1. The theory of diffusive sampling considers a concentration gra- dient between the ambient air and the adsorbent to be the driving force for sampling. For the adsorption to be controlled by diffu...AN EVALUATION OF THE 3M ORGANIC VAPOR MONITOR 43500 AS A SHOR'I TERM EXPOSURE LIMIT SAMPLING DEVICE FOR ACETONE, METHYL ETHYL KETONE, AND METHYL ISO BUTYL KETONE A Thesis by LLOYD B. ANDREW III Submitted to the Graduate College of Texas ASM...

Andrew, Lloyd B.

2012-06-07T23:59:59.000Z

106

A New Flow Control Technique Using Diluted Epinephrine in the N-butyl-2-cyanoacrylate Embolization of Visceral Artery Pseudoaneurysms Secondary to Chronic Pancreatitis  

SciTech Connect

Although n-butyl-2-cyanoacrylate (NBCA) has been used as an effective liquid embolization material, its indication for pseudoaneurysms has seemingly been limited because of the technical difficulties of using NBCA, such as reflux to the parent artery and causing significant infarction. Thus, considerable skill in using NBCA or a device to control blood flow during its polymerization is required to achieve embolization without severe complications. We report our new technique for controlling blood flow using diluted epinephrine in transcatheter arterial NBCA embolization of five pseudoaneurysms in four cases secondary to hemosuccus pancreaticus.

Morishita, Hiroyuki, E-mail: hmorif@koto.kpu-m.ac.jp [Japan Red Cross Kyoto Daiichi Hospital, Department of Diagnostic Radiology (Japan); Yamagami, Takuji [Kyoto Prefectural University of Medicine, Department of Radiology, Graduate School of Medical Science (Japan); Takeuchi, Yoshito [National Cancer Center, Division of Diagnostic Radiology (Japan); Matsumoto, Tomohiro; Asai, Shunsuke; Masui, Koji [Japan Red Cross Kyoto Daiichi Hospital, Department of Diagnostic Radiology (Japan); Sato, Hideki [Japan Red Cross Kyoto Daiichi Hospital, Department of Gastroenterology (Japan); Taniguchi, Fumihiro [Japan Red Cross Kyoto Daiichi Hospital, Department of Surgery (Japan); Sato, Osamu [Japan Red Cross Kyoto Daiichi Hospital, Department of Diagnostic Radiology (Japan); Nishimura, Tsunehiko [Kyoto Prefectural University of Medicine, Department of Radiology, Graduate School of Medical Science (Japan)

2012-08-15T23:59:59.000Z

107

Natural gas accumulations in low-permeability Tertiary, and Cretaceous (Campanian and Maastrichtian) rock, Uinta Basin, Utah  

SciTech Connect

This report characterizes Upper Cretaceous Campanian and Maastrichtian, and lower Tertiary gas-bearing rocks in the Uinta Basin with special emphasis on those units that contain gas in reservoirs that have been described as being tight. The report was prepared for the USDOE whose Western Tight Gas Sandstone Program cofunded much of this research in conjunction with the US Geological Survey's Evolution of Sedimentary Basins, and Onshore Oil and Gas Programs. (VC)

Fouch, T.D.; Wandrey, C.J.; Pitman, J.K.; Nuccio, V.F.; Schmoker, J.W.; Rice, D.D.; Johnson, R.C.; Dolton, G.L.

1992-02-01T23:59:59.000Z

108

Natural gas accumulations in low-permeability Tertiary, and Cretaceous (Campanian and Maastrichtian) rock, Uinta Basin, Utah. Final report  

SciTech Connect

This report characterizes Upper Cretaceous Campanian and Maastrichtian, and lower Tertiary gas-bearing rocks in the Uinta Basin with special emphasis on those units that contain gas in reservoirs that have been described as being tight. The report was prepared for the USDOE whose Western Tight Gas Sandstone Program cofunded much of this research in conjunction with the US Geological Survey`s Evolution of Sedimentary Basins, and Onshore Oil and Gas Programs. (VC)

Fouch, T.D.; Wandrey, C.J.; Pitman, J.K.; Nuccio, V.F.; Schmoker, J.W.; Rice, D.D.; Johnson, R.C.; Dolton, G.L.

1992-02-01T23:59:59.000Z

109

Average Conformations Determined from PRE Data Provide High-Resolution Maps of Transient Tertiary Interactions in Disordered Proteins  

Science Journals Connector (OSTI)

In the last decade it has become evident that disordered states of proteins play important physiological and pathological roles and that the transient tertiary interactions often present in these systems can play a role in their biological activity. The structural characterization of such states has so far largely relied on ensemble representations, which in principle account for both their local and global structural features. However, these approaches are inherently of low resolution due to the large number of degrees of freedom of conformational ensembles and to the sparse nature of the experimental data used to determine them. Here, we overcome these limitations by showing that tertiary interactions in disordered states can be mapped at high resolution by fitting paramagnetic relaxation enhancement data to a small number of conformations, which can be as low as one. This result opens up the possibility of determining the topology of cooperatively collapsed and hidden folded states when these are present in the vast conformational landscape accessible to disordered states of proteins. As a first application, we study the long-range tertiary interactions of acid-unfolded apomyoglobin from experimentally measured paramagnetic relaxation enhancement data.

Jordi Silvestre-Ryan; Carlos W. Bertoncini; Robert Bryn Fenwick; Santiago Esteban-Martin; Xavier Salvatella

2013-01-01T23:59:59.000Z

110

Seismic reflection evidence for two phase development of Tertiary basins from east-central Nevada  

SciTech Connect

Two east-west seismic reflection profiles crossing Antelope Valley, Smokey Valley, Railroad Valley and Big Sand Springs Valley demonstrate the evolution of Tertiary extension from broad sags to narrow, fault-bounded basins. Seismic reflection data was acquired for the Anschutz Corporation by the Digicon Corporation during the winter of 1988/1989. Reprocessing of a 480 channel, 60 fold, dynamite source experiment enabled good imaging of the basin stratigraphy. These data suggest two distinct phases of basin development occurred, separated by a regional unconformity. The early phase is characterized by development of a broad basin riddled with many small offset normal faults. The later phase shows a narrowing of the basin and subsidence along one dominant structure, an apparent planar normal fault. The unconformity separating the two phases of extension marks a transition from broad subsidence to local asymmetric tilting that took place over a short period of time relative to sedimentation rates. Antelope Valley and Railroad Valley clearly show strong evidence for two phase development, whereas Smokey Valley represents mostly the early phase and Big Sand Springs Valley represents only the later phase of extension. The absence of dating within the basins precludes the authors from determining if the abrupt tectonic transition within the basins resulted from differences in local strain rates or amounts, or was due to changes in regional stress fields.

Liberty, L.M.; Heller, P.L.; Smithson, S.B. (Univ. of Wyoming, Laramie, WY (United States). Dept. of Geology and Geophysics)

1993-04-01T23:59:59.000Z

111

Maturation of Tertiary sediments in the Asian Continental Margins: A basis for hydrocarbon generation studies  

SciTech Connect

In the marginal areas of the Asian continent, the Paleogene and Miocene coal-bearing formations are sporadically distributed. In some areas, particularly in the sea regions, their equivalents are possibly explored for oil and gas. The basins mainly formed as tectonic depressions, and are filled with fluvial to marine clastic rocks. The formations show marked lateral variation in thickness, lithology, and sediment characteristics, which are related to the geotectonic settings of the basins at active plate margins. Remarkable accumulation of overburden and high paleogeothermal conditions, which are marked in northern Kyushu, Japan, and Thailand, influenced diagenesis. Organic and inorganic maturation studies in northern Kyushu reveal a progress of diagenesis from the inland of Kyushu toward the sea region essentially controlled by additional heat supply from the sea region during and after sedimentation. The sediments on the land surface are chiefly overmatured, and/or contain minor amounts of organic carbon. High paleogeothermal influence on Tertiary maturation is clear also in northern Thailand. The high paleotemperature conditions in these areas may be related to tectonic interaction between the oceanic and continental plates.

Miki, Takashi (Kyushu Univ., Fukuoka (Japan))

1994-07-01T23:59:59.000Z

112

Factors controlling reservoir quality in tertiary sandstones and their significance to geopressured geothermal production  

SciTech Connect

Variable intensity of diagenesis is the factor primarily responsible for contrasting regional reservoir quality of Tertiary sandstones from the upper and lower Texas coast. Detailed comparison of Frio sandstone from the Chocolate Bayou/Danbury Dome area, Brazoria County, and Vicksburg sandstones from the McAllen Ranch Field area, Hidalgo County, reveals that extent of diagenetic modification is most strongly influenced by (1) detrital mineralogy and (2) regional geothermal gradients. The regional reservoir quality of Frio sandstones from Brazoria County is far better than that characterizing Vicksburg sandstones from Hidalgo County, especially at depths suitable for geopressured geothermal energy production. However, in predicting reservoir quality on a site-specific basis, locally variable factors such as relative proportions for porosity types, pore geometry as related to permeability, and local depositional environment must also be considered. Even in an area of regionally favorable reservoir quality, such local factors can significantly affect reservoir quality and, hence, the geothermal production potential of a specific sandstone unit.

Loucks, R.G.; Richmann, D.L.; Milliken, K.L.

1981-01-01T23:59:59.000Z

113

Interplay between Secondary and Tertiary Structure Formation in Protein Folding Cooperativity  

E-Print Network (OSTI)

Protein folding cooperativity is defined by the nature of the finite-size thermodynamic transition exhibited upon folding: two-state transitions show a free energy barrier between the folded and unfolded ensembles, while downhill folding is barrierless. A microcanonical analysis, where the energy is the natural variable, has shown better suited to unambiguously characterize the nature of the transition compared to its canonical counterpart. Replica exchange molecular dynamics simulations of a high resolution coarse-grained model allow for the accurate evaluation of the density of states, in order to extract precise thermodynamic information, and measure its impact on structural features. The method is applied to three helical peptides: a short helix shows sharp features of a two-state folder, while a longer helix and a three-helix bundle exhibit downhill and two-state transitions, respectively. Extending the results of lattice simulations and theoretical models, we find that it is the interplay between secondary structure and the loss of non-native tertiary contacts which determines the nature of the transition.

Tristan Bereau; Michael Bachmann; Markus Deserno

2011-07-01T23:59:59.000Z

114

THE TRENDS HIGH-CONTRAST IMAGING SURVEY. II. DIRECT DETECTION OF THE HD 8375 TERTIARY  

SciTech Connect

We present the direct imaging detection of a faint tertiary companion to the single-lined spectroscopic binary HD 8375 AB. Initially noticed as an 53 m s{sup -1} yr{sup -1} Doppler acceleration by Bowler et al., we have obtained high-contrast adaptive optics observations at Keck using NIRC2 that spatially resolve HD 8375 C from its host(s). Astrometric measurements demonstrate that the companion shares a common proper-motion. We detect orbital motion in a clockwise direction. Multiband relative photometry measurements are consistent with an early M-dwarf spectral type ({approx}M1V). Our combined Doppler and imaging observations place a lower-limit of m {>=} 0.297 M{sub Sun} on its dynamical mass. We also provide a refined orbit for the inner pair using recent radial velocity measurements obtained with the High Resolution Echelle Spectrometer. HD 8375 is one of many triple-star systems that are apparently missing in the solar neighborhood.

Crepp, Justin R. [Department of Physics, University of Notre Dame, 225 Nieuwland Science Hall, Notre Dame, IN 46556 (United States); Johnson, John Asher; Yantek, Scott M. [Department of Astronomy, California Institute of Technology, 1200 E. California Blvd., Pasadena, CA 91125 (United States); Howard, Andrew W. [Institute for Astronomy, University of Hawaii, 2680 Woodlawn Drive, Honolulu, HI 96822 (United States); Marcy, Geoff W.; Isaacson, Howard [Department of Astronomy, University of California, Berkeley, CA 94720 (United States); Fischer, Debra A. [Department of Physics, Yale University, New Haven, CT 06511 (United States); Wright, Jason T.; Feng Ying, E-mail: jcrepp@nd.edu [Department of Astronomy and Astrophysics, The Pennsylvania State University, University Park, PA 16802 (United States)

2013-07-01T23:59:59.000Z

115

Effect of varying polyacrylamide molecular weight on tertiary oil recovery from porous media of varying permeability  

SciTech Connect

Three different molecular weight emulsion polyacrylamides (PAA) have been tested for their ability to recover oil from a multi-permeability Berea core system. Injection of a 6.5 x 10/sup 6/, 17 x 10/sup 6/, and 36 x 10/sup 6/ molecular weight PAA resulted in oil recovery from the multiple permeability core systems of 53.4, 63.7, and 57.2 percent of the waterflood residual oil, respectively. In tests with 15 g/kg Na/sub 2/CO/sub 3/, injection of the polymer systems resulted in recoveries of 65.6, 75.3, and 68.0 percent of the waterflood residual oil, respectively. In the presence of alkali, the injection of high molecular weight PAA resulted in the reduction of fluid flow into the medium and low permeability cores with 70 to 75 percent of the tertiary oil being recovered from the high permeability core. Decreasing the PAA molecular weight to 17 x 10/sup 6/ and subsequently to 6.5 x 10/sup 6/ resulted in an increasing amount of fluid flowing through the low and medium permeability cores. While decreasing the molecular weight of the PAA resulted in increased fluid diversion, the 6.5 x 10/sup 6/ molecular weight PAA recovery efficiency was less than either of the other two polymers in the high permeability core. The data indicates selection of too large a polymer can result in less than maximum oil recovery from a heterogeneous permeability reservoir as a result of lower sweep efficiency. Selection of too small a polymer can result in less than maximum oil recovery from a heterogeneous permeability reservoir as a result of decreased oil recovery from the high permeability zones. Proper selection of polyacrylamide for a heterogeneous permeability reservoir either in the presence or in the absence of alkali will maximize oil recovery.

Ball, J.T.; Pitts, M.J.

1984-04-01T23:59:59.000Z

116

Use of Treated Municipal Wastewater as Power Plant Cooling System Makeup Water: Tertiary Treatment versus Expanded Chemical Regimen for Recirculating Water Quality Management  

SciTech Connect

Treated municipal wastewater is a common, widely available alternative source of cooling water for thermoelectric power plants across the U.S. However, the biodegradable organic matter, ammonia-nitrogen, carbonate and phosphates in the treated wastewater pose challenges with respect to enhanced biofouling, corrosion, and scaling, respectively. The overall objective of this study was to evaluate the benefits and life cycle costs of implementing tertiary treatment of secondary treated municipal wastewater prior to use in recirculating cooling systems. The study comprised bench- and pilot-scale experimental studies with three different tertiary treated municipal wastewaters, and life cycle costing and environmental analyses of various tertiary treatment schemes. Sustainability factors and metrics for reuse of treated wastewater in power plant cooling systems were also evaluated. The three tertiary treated wastewaters studied were: secondary treated municipal wastewater subjected to acid addition for pH control (MWW_pH); secondary treated municipal wastewater subjected to nitrification and sand filtration (MWW_NF); and secondary treated municipal wastewater subjected nitrification, sand filtration, and GAC adsorption (MWW_NFG). Tertiary treatment was determined to be essential to achieve appropriate corrosion, scaling, and biofouling control for use of secondary treated municipal wastewater in power plant cooling systems. The ability to control scaling, in particular, was found to be significantly enhanced with tertiary treated wastewater compared to secondary treated wastewater. MWW_pH treated water (adjustment to pH 7.8) was effective in reducing scale formation, but increased corrosion and the amount of biocide required to achieve appropriate biofouling control. Corrosion could be adequately controlled with tolytriazole addition (4-5 ppm TTA), however, which was the case for all of the tertiary treated waters. For MWW_NF treated water, the removal of ammonia by nitrification helped to reduce the corrosivity and biocide demand. Also, the lower pH and alkalinity resulting from nitrification reduced the scaling to an acceptable level, without the addition of anti-scalant chemicals. Additional GAC adsorption treatment, MWW_NFG, yielded no net benefit. Removal of organic matter resulted in pitting corrosion in copper and cupronickel alloys. Negligible improvement was observed in scaling control and biofouling control. For all of the tertiary treatments, biofouling control was achievable, and most effectively with pre-formed monochloramine (2-3 ppm) in comparison with NaOCl and ClO2. Life cycle cost (LCC) analyses were performed for the tertiary treatment systems studied experimentally and for several other treatment options. A public domain conceptual costing tool (LC3 model) was developed for this purpose. MWW_SF (lime softening and sand filtration) and MWW_NF were the most cost-effective treatment options among the tertiary treatment alternatives considered because of the higher effluent quality with moderate infrastructure costs and the relatively low doses of conditioning chemicals required. Life cycle inventory (LCI) analysis along with integration of external costs of emissions with direct costs was performed to evaluate relative emissions to the environment and external costs associated with construction and operation of tertiary treatment alternatives. Integrated LCI and LCC analysis indicated that three-tiered treatment alternatives such as MWW_NSF and MWW_NFG, with regular chemical addition for treatment and conditioning and/or regeneration, tend to increase the impact costs and in turn the overall costs of tertiary treatment. River water supply and MWW_F alternatives with a single step of tertiary treatment were associated with lower impact costs, but the contribution of impact costs to overall annual costs was higher than all other treatment alternatives. MWW_NF and MWW_SF alternatives exhibited moderate external impact costs with moderate infrastructure and chemical conditioner dosing, which makes them (especially

David Dzombak; Radisav Vidic; Amy Landis

2012-06-30T23:59:59.000Z

117

TABLE33.CHP:Corel VENTURA  

Annual Energy Outlook 2012 (EIA)

products are reported by the PAD District of entry. b Includes crude oil imported for storage in the Strategic Petroleum Reserve. c Includes ethyl tertiary butyl ether (ETBE),...

118

TABLE34.CHP:Corel VENTURA  

Gasoline and Diesel Fuel Update (EIA)

products are reported by the PAD District of entry. b Includes crude oil imported for storage in the Strategic Petroleum Reserve. c Includes ethyl tertiary butyl ether (ETBE),...

119

Modeling of the simultaneous extraction of nitric acid and uranyl nitrate with tri-n-butyl phosphate. Application to extraction operation  

SciTech Connect

A mathematical model developed for the equilibrium HNO{sub 3}-UO{sub 2}(NO{sub 3}){sub 2}-tri-n-butyl phosphate (TBP)-diluent is the basis of the computation of distribution isotherms. The isotherms are used to study the influence of TBP concentration on two chosen operation parameters, distribution coefficients and number of theoretical stages, for the selected flow sheets. It is established that an increase in TBP concentration leads to a decrease in the number of theoretical stages for the extraction flow sheets but to their increase for the striping flow sheets. Given diagrams can be used to determine the efficiency of extraction processes. Agreement with available literature calculations on the number of theoretical stages supports the use of the model in the computation of distribution isotherms, of the system quoted above, in a wide range of nitric acid, uranyl nitrate, and TBP concentrations.

Comor, J.J.; Tolic, A.S.; Kopecni, M.M.; Petkovic, D.M. [Vinca Inst. of Nuclear Sciences, Belgrade (Yugoslavia). Chemical Dynamics Lab.] [Vinca Inst. of Nuclear Sciences, Belgrade (Yugoslavia). Chemical Dynamics Lab.

1999-01-01T23:59:59.000Z

120

Investigating Sequestration Potential of Carbonate Rocks during Tertiary Recovery from a Billion Barrel Oil Field, Weyburn, Saskatchewan: the Geoscience Framework (IEA Weyburn CO2 Monitoring Project)  

NLE Websites -- All DOE Office Websites (Extended Search)

Sequestration Potential of Carbonate Rocks during Tertiary Sequestration Potential of Carbonate Rocks during Tertiary Recovery from a Billion Barrel Oil Field, Weyburn, Saskatchewan: the Geoscience Framework (IEA Weyburn CO 2 Monitoring and Storage Project) G. Burrowes (Geoffrey_Burrowes@pancanadian.ca; 403-290-2796) PanCanadian Resources 150 - 9 th Avenue S.W., P.O. Box 2850 Calgary, Alberta, Canada T2P 2S5 C. Gilboy (cgilboy@sem.gov.sk.ca; 306-787-2573) Petroleum Geology Branch, Saskatchewan Energy and Mines 201 Dewdney Avenue East Regina, Saskatchewan, Canada S4N 4G3 Introduction In Western Canada the application of CO 2 injection for enhanced, 'tertiary' oil recovery is a relatively recent addition to the arsenal available to reservoir engineers. The first successful application of CO 2 as a miscible fluid in Western Canada began in 1984 at Joffre Field, a

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

High energy beam impact tests on a LHC tertiary collimator at the CERN high-radiation to materials facility  

Science Journals Connector (OSTI)

The correct functioning of a collimation system is crucial to safely operate highly energetic particle accelerators, such as the Large Hadron Collider (LHC). The requirements to handle high intensity beams can be demanding. In this respect, investigating the consequences of LHC particle beams hitting tertiary collimators (TCTs) in the experimental regions is a fundamental issue for machine protection. An experimental test was designed to investigate the robustness and effects of beam accidents on a fully assembled collimator, based on accident scenarios in the LHC. This experiment, carried out at the CERN High-Radiation to Materials (HiRadMat) facility, involved 440 GeV proton beam impacts of different intensities on the jaws of a horizontal TCT. This paper presents the experimental setup and the preliminary results obtained, together with some first outcomes from visual inspection and a comparison of such results with numerical simulations.

Marija Cauchi; O. Aberle; R.?W. Assmann; A. Bertarelli; F. Carra; K. Cornelis; A. Dallocchio; D. Deboy; L. Lari; S. Redaelli; A. Rossi; B. Salvachua; P. Mollicone; N. Sammut

2014-02-24T23:59:59.000Z

122

Review and reconnaissance of the hydrogeology of Tertiary sedimentary rocks in the vicinity of Frenchman Flat, Nevada Test Site  

SciTech Connect

Work is currently underway within the Underground Test Area (UGTA) subproject of the US Department of Energy/Nevada Operations Office Environmental Restoration Program to develop corrective action plans in support of the overall corrective action strategy for the Nevada Test Site (NTS) as established in the Federal Facility Agreement and Consent Order (FFACO, 1996). A closure plan is currently being developed for Frenchman Flat, which has been identified in the FFACO as a Corrective Action Unit (CAU). Part of this effort requires that hydrogeologic data be compiled for inclusion in a CAU-specific hydrologic flow and transport model that will be used to predict contaminant boundaries. Hydrogeologic maps and cross sections are currently being prepared for use in the model to define the nature and extent of aquifers and confining units that might influence the flow of contaminated groundwater from underground nuclear tests conducted in Frenchman Flat. During this effort, it has been found that older Tertiary-age sediments might be hydrogeologically important in the Frenchman Flat model area. Although the character and extent of these units are poorly known, there is reason to believe that in some parts of Frenchman Flat they may lie between the regional Lower Carbonate Aquifer (LCA) and the younger Tertiary saturated alluvium and volcanic units in which several underground nuclear tests were conducted. It was not possible to quickly determine their extent, or ascertain whether or not these units might act as confining units or aquifers. The work described in this report was done to gain a better understanding of the hydrogeology of these rocks.

Prothro, L.B.; Drellack, S.L. Jr.

1997-09-01T23:59:59.000Z

123

Contrasting styles of Pre-Cenozoic and mid-Tertiary crustal evolution in northern Mexico: Evidence from deep crustal xenoliths from La Olivina  

SciTech Connect

The principal deep crustal rock types found at the La Olivina xenolith locality in southeastern Chihuahua, Mexico, are mafic granulites, paragneisses, and intermediate- to silicic-composition orthogneisses. These granulite facies xenoliths are interpreted in terms of two age groups, pre-Cenozoic and mid-Tertiary, based on previous ion probe dating of zircons from the xenoliths and on isotopic comparisons of the xenoliths to rocks of known age. The mafic granulites have Pb, Nd, and Sr isotopic compositions identical to those of Oligocene volcanic rocks from the La Olivina region. Compositionally, they are olivine-normative gabbroic cumulates, and they precipitated from two or more mid-Tertiary basalt to dacite or rhyolite assimilation/fractional crystallization series. Mineral assemblages in the xenoliths record pressures of {le} 7.2 kbar or depths of < 25 km. If these are the maximum pressures the rocks experienced and if the crust was > 35 km thick in Oligocene time as inferred from regional tectonic considerations, then the mafic granulites cannot be samples of basaltic magmas underplated near the crust-mantle boundary. The cumulate protoliths for the mafic granulites probably formed in magma chambers well above the Moho. The mafic granulites are plausibly ignimbrite fields of Mexico. Pre-Cenozoic and mid-Tertiary crustal evolution followed very different paths in northern Mexico. For example, Nd isotopic evidence for crustal recycling is much more evident in rocks associated with the Paleozoic convergence than in rocks produced during mid-Tertiary magmatism. Furthermore, mafic rocks are very rare in the pre-Cenozoic xenolith suite, but they dominate the mid-Tertiary one. The rarity of pre-Cenozoic mafic xenoliths suggests that Proterozoic and Paleozoic lower crust may have delaminated in response to crustal overthickening associated with the Ouachita collision event. 97 refs., 14 figs., 5 tabs.

Cameron, K.L.; Robinson, J.V.; Kuentz, D.C.; Collerson, K.D. [Univ. of California, Santa Cruz, CA (United States); Niemeyer, S. [Lawrence Livermore National Lab., CA (United States); Harmon, R.S. [NERC Isotope Geosciences Lab., Keyworth (United Kingdom); Bohlen, S.R. [Geological Survey, Menlo Park, CA (United States)

1992-11-10T23:59:59.000Z

124

Taming Past LTL and Flat Counter Systems  

E-Print Network (OSTI)

Reachability and LTL model-checking problems for flat counter systems are known to be decidable but whereas the reachability problem can be shown in NP, the best known complexity upper bound for the latter problem is made of a tower of several exponentials. Herein, we show that the problem is only NP-complete even if LTL admits past-time operators and arithmetical constraints on counters. Actually, the NP upper bound is shown by adequately combining a new stuttering theorem for Past LTL and the property of small integer solutions for quantifier-free Presburger formulae. Other complexity results are proved, for instance for restricted classes of flat counter systems.

Demri, Stéphane; sangnier, Arnaud

2012-01-01T23:59:59.000Z

125

Taming the Runaway Problem of Inflationary Landscapes  

SciTech Connect

A wide variety of vacua, and their cosmological realization, may provide an explanation for the apparently anthropic choices of some parameters of particle physics and cosmology. If the probability on various parameters is weighted by volume, a flat potential for slow-roll inflation is also naturally understood, since the flatter the potential the larger the volume of the sub-universe. However, such inflationary landscapes have a serious problem, predicting an environment that makes it exponentially hard for observers to exist and giving an exponentially small probability for a moderate universe like ours. A general solution to this problem is proposed, and is illustrated in the context of inflaton decay and leptogenesis, leading to an upper bound on the reheating temperature in our sub-universe. In a particular scenario of chaotic inflation and non-thermal leptogenesis, predictions can be made for the size of CP violating phases, the rate of neutrinoless double beta decay and, in the case of theories with gauge-mediated weak scale supersymmetry, for the fundamental scale of supersymmetry breaking.

Hall, Lawrence J.; Watari, Taizan; Yanagida, T. T.

2006-03-15T23:59:59.000Z

126

High Temperature Superconductivity: Taming Serendipity (Thursday...  

NLE Websites -- All DOE Office Websites (Extended Search)

predictive design of new families of superconductors. She is recognized for her work on superconductorsemiconductor proximity effects, elucidating the physical properties of the...

127

Oil recovery; Technology that tames large spills  

SciTech Connect

This paper reports that the threat of oil spills is growing with the increasing use of larger tankers, the expansion of offshore oil exploration, and-as was demonstrated recently in the Persian Gulf-the dangers of war and terrorism. Aware of the environmental havoc that massive spills can cause, engineers are working hard to devise effective methods of scooping oil from the water's surface and cleaning contaminated shorelines. Techniques are being developed, which combine mechanical, chemical, and biological processes to contain spills.

Valenti, M.

1991-05-01T23:59:59.000Z

128

Taming the Runaway Problem of Inflationary Landscapes  

E-Print Network (OSTI)

Predictions on the neutrinoless double beta decay from thethe rate of neutrinoless double beta decay and, in the caseon the rate of neutrinoless double beta decay are available

Hall, Lawrence J.

2009-01-01T23:59:59.000Z

129

Fluctuating micro-heterogeneity in water–tert-butyl alcohol mixtures and lambda-type divergence of the mean cluster size with phase transition-like multiple anomalies  

SciTech Connect

Water–tert-butyl alcohol (TBA) binary mixture exhibits a large number of thermodynamic and dynamic anomalies. These anomalies are observed at surprisingly low TBA mole fraction, with x{sub TBA} ? 0.03–0.07. We demonstrate here that the origin of the anomalies lies in the local structural changes that occur due to self-aggregation of TBA molecules. We observe a percolation transition of the TBA molecules at x{sub TBA} ? 0.05. We note that “islands” of TBA clusters form even below this mole fraction, while a large spanning cluster emerges above that mole fraction. At this percolation threshold, we observe a lambda-type divergence in the fluctuation of the size of the largest TBA cluster, reminiscent of a critical point. Alongside, the structure of water is also perturbed, albeit weakly, by the aggregation of TBA molecules. There is a monotonic decrease in the tetrahedral order parameter of water, while the dipole moment correlation shows a weak nonlinearity. Interestingly, water molecules themselves exhibit a reverse percolation transition at higher TBA concentration, x{sub TBA} ? 0.45, where large spanning water clusters now break-up into small clusters. This is accompanied by significant divergence of the fluctuations in the size of largest water cluster. This second transition gives rise to another set of anomalies around. Both the percolation transitions can be regarded as manifestations of Janus effect at small molecular level.

Banerjee, Saikat; Furtado, Jonathan; Bagchi, Biman, E-mail: bbagchi@sscu.iisc.ernet.in [SSCU, Indian Institute of Science, Bangalore 560012 (India)] [SSCU, Indian Institute of Science, Bangalore 560012 (India)

2014-05-21T23:59:59.000Z

130

Transport study of hafnium(IV) and zirconium(IV) ions mutual separation by using Tri-n-butyl phosphate-xylene-based supported liquid membranes  

SciTech Connect

A Hf transport study through supported liquid membranes has been carried out to determine flux and permeability data for this metal ion. Tri-n-butyl phosphate (TBP)-xylene-based liquid membranes supported in polypropylene hydrophobic microporous film have been used. These data for hafnium and the previous data for zirconium have furnished the Zr to Hf flux ratio (S) as a function of nitric acid and TBP concentrations of the order of 12 in a single stage at room temperature. Optimum conditions for the separation of these two metal ions appear to 5-6 TBP mol/dm{sup 3} HNO{sub 3}, concentrations {le} 2.93 mol/dm{sup 3}, and 10C. The value of S from an aqueous solution containing 2.4% Hf with respect to Zr has been found to be >125 at 10C and 1.78 mol/dm{sup 3} TBP concentration in the membrane. The technique appears to be feasible for purification of Zr respect to Hf or vice versa.

Chaudry, M.A.; Ahmed, B. (Pakistan Inst. of Nuclear Science and Technology, Islamabad (Pakistan))

1992-02-01T23:59:59.000Z

131

Low-temperature CVD of iron, cobalt, and nickel nitride thin films from bis[di(tert-butyl)amido]metal(II) precursors and ammonia  

SciTech Connect

Thin films of late transition metal nitrides (where the metal is iron, cobalt, or nickel) are grown by low-pressure metalorganic chemical vapor deposition from bis[di(tert-butyl)amido]metal(II) precursors and ammonia. These metal nitrides are known to have useful mechanical and magnetic properties, but there are few thin film growth techniques to produce them based on a single precursor family. The authors report the deposition of metal nitride thin films below 300?°C from three recently synthesized M[N(t-Bu){sub 2}]{sub 2} precursors, where M?=?Fe, Co, and Ni, with growth onset as low as room temperature. Metal-rich phases are obtained with constant nitrogen content from growth onset to 200?°C over a range of feedstock partial pressures. Carbon contamination in the films is minimal for iron and cobalt nitride, but similar to the nitrogen concentration for nickel nitride. X-ray photoelectron spectroscopy indicates that the incorporated nitrogen is present as metal nitride, even for films grown at the reaction onset temperature. Deposition rates of up to 18?nm/min are observed. The film morphologies, growth rates, and compositions are consistent with a gas-phase transamination reaction that produces precursor species with high sticking coefficients and low surface mobilities.

Cloud, Andrew N.; Abelson, John R., E-mail: abelson@illinois.edu [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 201 Materials Science and Engineering Building, 1304 W. Green St., Urbana, Illinois 61801 (United States); Davis, Luke M.; Girolami, Gregory S., E-mail: girolami@scs.illinois.edu [School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Ave., Urbana, Illinois 61801 (United States)

2014-03-15T23:59:59.000Z

132

Fluctuating micro-heterogeneity in water - tert-butyl alcohol mixtures and lambda-type divergence of the mean cluster size with phase transition-like multiple anomalies  

E-Print Network (OSTI)

Water - tert-butyl alcohol (TBA) binary mixture exhibits a large number of thermodynamic and dynamic anomalies. These anomalies are observed at surprisingly low TBA mole fraction, with $x_{\\text{TBA}} \\approx 0.03 - 0.07$. We demonstrate here that the origin of the anomalies lies in the local structural changes that occur due to self-aggregation of TBA molecules. We observe a percolation transition of the TBA molecules at $x_{\\text{TBA}} \\approx 0.05$. We note that "islands" of TBA clusters form even below this mole fraction, while a large spanning cluster emerges above that mole fraction. At this percolation threshold, we observe a lambda-type divergence in the fluctuation of the size of the largest TBA cluster, reminiscent of a critical point. Alongside, the structure of water is also perturbed, albeit weakly, by the aggregation of TBA molecules. There is a monotonic decrease in the tetrahedral order parameter of water, while the dipole moment correlation shows a weak non-linearity. Interestingly, water molecules themselves exhibit a reverse percolation transition at higher TBA concentration, $x_{\\text{TBA}} \\approx 0.45$, where large spanning water clusters now break-up into small clusters. This is accompanied by significant divergence of the fluctuations in the size of largest water cluster. This second transition gives rise to another set of anomalies around. Both the percolation transitions can be regarded as manifestations of Janus effect at small molecular level.

Saikat Banerjee; Jonathan Furtado; Biman Bagchi

2014-02-20T23:59:59.000Z

133

Solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen in 1-butyl-1-methylpyrrolidinium and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate (eFAP) ionic liquids  

Science Journals Connector (OSTI)

The density and viscosity of the ionic liquids 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate [C1C4Pyrro][eFAP] and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate [P66614][eFAP] were measured as a function of temperature and pressure and as a function of temperature, respectively. These two ionic liquids are more viscous than those based in the same anion associated to imidazolium cations. The effect of the addition of water on the density and viscosity of [P66614][eFAP] was studied at pressures close to atmospheric and as a function of the temperature. This ionic liquid is only partially miscible with water, its solubility being of around X H 2 O = 0.2 in the range of (303 to 315) K. Experimental values of the solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen were obtained as a function of temperature and at pressures close to atmospheric. Carbon dioxide and nitrous oxide are the more soluble gases with mole fraction solubilities up to 7 · 10?2. Ethane is four times and 1.3 times less soluble than carbon dioxide in [C1C4Pyrro][eFAP] and [P66614][eFAP], respectively. Nitrogen is one order of magnitude less soluble than the others gases in the two ionic liquids studied. In order to understand behavior of the different gases with these ionic liquids, the thermodynamic functions of solvation such as enthalpy and entropy were calculated from the variation of the Henry’s law constant with temperature. It is shown that the more favorable interactions of the gases with the ionic liquid explain the larger solubility of carbon dioxide and nitrous oxide in [C1C4Pyrro][eFAP]. In the case of [P66614][eFAP], it is the less favorable entropic contribution that explains the lower solubility of ethane in this ionic liquid.

S. Stevanovic; M.F. Costa Gomes

2013-01-01T23:59:59.000Z

134

Distribution of hazardous air pollutant trace elements, total sulfur, and ash in coals from five Tertiary basins in the Rocky Mountain Region  

SciTech Connect

Arithmetic mean values of the contents of hazardous air pollutant (HAP) trace elements named in the 1990 Clean Air Act Amendments (antimony, arsenic, beryllium, cadmium, chromium, cobalt, lead, manganese, mercury, nickel, selenium, and uranium), ash, and total sulfur were statistically compared on a whole-coal basis for Paleocene coals from five Tertiary basins in the Rocky Mountain Region. The study of proximate and elemental analyses indicate a relationship between trace element contents and paleogeography.

Ellis, M.S.; Stricker, G.D.; Flores, R.M. [Geological Survey, Denver, CO (United States)

1994-12-31T23:59:59.000Z

135

Biostratigraphic, chronostratigraphic, and stratigraphic sequence analysis of Lower Tertiary marine sediments of Alabama for indicators of sea-level change  

SciTech Connect

Early Eocene to late Oligocene marine sedimentary units in southwestern Alabama were sampled at closely spaced intervals to derive a precise time-stratigraphic framework and to determine the paleoecological and mineralogical responses to fluctuations in sea level. Paleontologic control consisted of planktonic, smaller and larger benthonic foraminifera, calcareous nannofossils, dinoflagellates, and megafossils. Paleomagnetic reversals were delineated in two boreholes which, when supplemented by strontium isotope dates and the biostratigraphic control, provided a robust in situ chronostratigraphy for the Gulf Coast lower Tertiary. Paleoecologic trends in regression and transgression can be clearly correlated across major regional facies changes. Using the chronostratigraphy developed here, the second-, third-, and fourth-orders of Vail's global sea-level cycles can be recognized and demonstrate the influence of sea-level change on sedimentation. Stratigraphic systems tracts (SSTs) and bounding surfaces in outcrop were determined by lithologic variations and paleoecologic trends, and additionally by gamma logs in the cores. The lower sequence boundary occurs at a contact where an older, relatively fine-grained, deep-water, fossiliferous unit was abruptly succeeded by a coarse-grained, shallow-water, poorly fossiliferous unit. The transgressive surface occurs at the base of a fining- and deepening-upwards unit that was commonly glauconitic and very fossiliferous. Transgression culminated with a pulse of planktonic microfossils in a bed having reduced clastic sedimentation; on the log the surface of maximum starvation was marked by a gamma spike.

Thompson, P.R. (ARCO Oil and Gas Co., Plano, TX (United States)); Baum, G.R. (ARCO Alaska, Inc., Anchorage (United States))

1991-03-01T23:59:59.000Z

136

Biofouling of reverse-osmosis membranes under different shear rates during tertiary wastewater desalination: Microbial community composition  

Science Journals Connector (OSTI)

Abstract We investigated the influence of feed-water shear rate during reverse-osmosis (RO) desalination on biofouling with respect to microbial community composition developed on the membrane surface. The RO membrane biofilm's microbial community profile was elucidated during desalination of tertiary wastewater effluent in a flat-sheet lab-scale system operated under high (555.6 s?1), medium (370.4 s?1), or low (185.2 s?1) shear rates, corresponding to average velocities of 27.8, 18.5, and 9.3 cm s?1, respectively. Bacterial diversity was highest when medium shear was applied (Shannon–Weaver diversity index H' = 4.30 ± 0.04) compared to RO-membrane biofilm developed under lower and higher shear rates (H? = 3.80 ± 0.26 and H? = 3.42 ± 0.38, respectively). At the medium shear rate, RO-membrane biofilms were dominated by Betaproteobacteria, whereas under lower and higher shear rates, the biofilms were dominated by Alpha- and Gamma- Proteobacteria, and the latter biofilms also contained Deltaproteobacteria. Bacterial abundance on the RO membrane was higher at low and medium shear rates compared to the high shear rate: 8.97 × 108 ± 1.03 × 103, 4.70 × 108 ± 1.70 × 103 and 5.72 × 106 ± 2.09 × 103 copy number per cm2, respectively. Interestingly, at the high shear rate, the RO-membrane biofilm's bacterial community consisted mainly of populations known to excrete high amounts of extracellular polymeric substances. Our results suggest that the RO-membrane biofilm's community composition, structure and abundance differ in accordance with applied shear rate. These results shed new light on the biofouling phenomenon and are important for further development of antibiofouling strategies for RO membranes.

Ashraf Al Ashhab; Osnat Gillor; Moshe Herzberg

2014-01-01T23:59:59.000Z

137

Hospital-acquired infection rate in a tertiary care teaching hospital in China: a cross-sectional survey involving 2434 inpatients  

Science Journals Connector (OSTI)

Summary A single-day hospital-acquired infections (HAIs) point prevalence study was conducted in a tertiary care hospital in China. The overall prevalence rate of \\{HAIs\\} was 3.53% (95% confidence interval 2.80–4.26%) among 2434 inpatients surveyed. Respiratory system infection was the most common type of HAI (49.43%), followed by surgical site infection (22.99%). The pathogen detection results for 50 patients showed Pseudomonas aeruginosa to account for 24.00% of isolates, followed by Klebsiella pneumoniae (14.00%) and Escherichia coli (14.00%).

Xiu-Bin Tao; Li-Hua Qian; Yan Li; Qun Wu; Jing-Jing Ruan; Dong-Zhen Cai; Hui Peng

2014-01-01T23:59:59.000Z

138

Sub-crop geologic map of pre-Tertiary rocks in the Yucca Flat and northern Frenchman Flat areas, Nevada Test Site, southern Nevada  

SciTech Connect

This map displays interpreted structural and stratigraphic relations among the Paleozoic and older rocks of the Nevada Test Site region beneath the Miocene volcanic rocks and younger alluvium in the Yucca Flat and northern Frenchman Flat basins. These interpretations are based on a comprehensive examination and review of data for more than 77 drillholes that penetrated part of the pre-Tertiary basement beneath these post-middle Miocene structural basins. Biostratigraphic data from conodont fossils were newly obtained for 31 of these holes, and a thorough review of all prior microfossil paleontologic data is incorporated in the analysis. Subsurface relationships are interpreted in light of a revised regional geologic framework synthesized from detailed geologic mapping in the ranges surrounding Yucca Flat, from comprehensive stratigraphic studies in the region, and from additional detailed field studies on and around the Nevada Test Site. All available data indicate the subsurface geology of Yucca Flat is considerably more complicated than previous interpretations have suggested. The western part of the basin, in particular, is underlain by relics of the eastward-vergent Belted Range thrust system that are folded back toward the west and thrust by local, west-vergent contractional structures of the CP thrust system. Field evidence from the ranges surrounding the north end of Yucca Flat indicate that two significant strike-slip faults track southward beneath the post-middle Miocene basin fill, but their subsurface traces cannot be closely defined from the available evidence. In contrast, the eastern part of the Yucca Flat basin is interpreted to be underlain by a fairly simple north-trending, broad syncline in the pre-Tertiary units. Far fewer data are available for the northern Frenchman Flat basin, but regional analysis indicates the pre-Tertiary structure there should also be relatively simple and not affected by thrusting. This new interpretation has implications for ground water flow through pre-Tertiary rocks beneath the Yucca Flat and northern Frenchman Flat areas, and has consequences for ground water modeling and model validation. Our data indicate that the Mississippian Chainman Shale is not laterally extensive confining unit in the western part of the basin because it is folded back onto itself by the convergent structures of the Belted Range and CP thrust systems. Early and Middle Paleozoic limestone and dolomite are present beneath most of both basins and, regardless of structural complications, are interpreted to form a laterally continuous and extensive carbonate aquifer. Structural culmination that marks the French Peak accommodation zone along the topographic divide between the two basins provides a lateral pathway through highly fractured rock between the volcanic aquifers of Yucca Flat and the regional carbonate aquifer. This pathway may accelerate the migration of ground-water contaminants introduced by underground nuclear testing toward discharge areas beyond the Nevada Test Site boundaries. Predictive three-dimensional models of hydrostratigraphic units and ground-water flow in the pre-Tertiary rocks of subsurface Yucca Flat are likely to be unrealistic due to the extreme structural complexities. The interpretation of hydrologic and geochemical data obtained from monitoring wells will be difficult to extrapolate through the flow system until more is known about the continuity of hydrostratigraphic units. 1 plate

Cole, J.C.; Harris, A.G.; Wahl, R.R.

1997-10-02T23:59:59.000Z

139

Variations in Mg/Ca as a control on distribution of strontium concentrations and delta/sup 18/O in upper Tertiary dolomites from Bahamas  

SciTech Connect

Strontium concentrations and delta/sup 18/O are commonly used to infer the gross composition of dolomitizing waters, yet the bases for such inferences are not firmly established. A new approach to calibrating these 2 parameters is suggested from analyses of a section of upper Tertiary dolomites from the Bahamas. In an interval of dolomite, 120 m (394 ft) from a core taken on San Salvador Island, mole % MgCO/sub 3/ is correlated positively with delta/sup 18/O, and negatively with strontium. Strontium substitutes mainly for calcium, thus the negative correlation with mole % MgCO/sub 3/. Dolomites are enriched between 3 to 7% in delta/sup 18/O as compared with coprecipitated calcite, and thus the positive correlation. These two covariations indicate the need to consider the stoichiometric coefficient of dolomites, and to normalize strontium concentrations and delta/sup 18/O with their respective stoichiometric coefficients before inferring their relationship with fluid composition.

Swart, P.K.; Dawans, J.M.

1984-04-01T23:59:59.000Z

140

Nonassociated gas resources in low-permeability sandstone reservoirs, lower tertiary Wasatch Formation, and upper Cretaceous Mesaverde Group, Uinta Basin, Utah  

SciTech Connect

The US Geological Survey recognizes six major plays for nonassociated gas in Tertiary and Upper Cretaceous low-permeability strata of the Uinta Basin, Utah. For purposes of this study, plays without gas/water contacts are separated from those with such contacts. Continuous-saturation accumulations are essentially single fields, so large in areal extent and so heterogeneous that their development cannot be properly modeled as field growth. Fields developed in gas-saturated plays are not restricted to structural or stratigraphic traps and they are developed in any structural position where permeability conduits occur such as that provided by natural open fractures. Other fields in the basin have gas/water contacts and the rocks are water-bearing away from structural culmination`s. The plays can be assigned to two groups. Group 1 plays are those in which gas/water contacts are rare to absent and the strata are gas saturated. Group 2 plays contain reservoirs in which both gas-saturated strata and rocks with gas/water contacts seem to coexist. Most units in the basin that have received a Federal Energy Regulatory Commission (FERC) designation as tight are in the main producing areas and are within Group 1 plays. Some rocks in Group 2 plays may not meet FERC requirements as tight reservoirs. However, we suggest that in the Uinta Basin that the extent of low-permeability rocks, and therefore resources, extends well beyond the limits of current FERC designated boundaries for tight reservoirs. Potential additions to gas reserves from gas-saturated tight reservoirs in the Tertiary Wasatch Formation and Cretaceous Mesaverde Group in the Uinta Basin, Utah is 10 TCF. If the potential additions to reserves in strata in which both gas-saturated and free water-bearing rocks exist are added to those of Group 1 plays, the volume is 13 TCF.

Fouch, T.D.; Schmoker, J.W.; Boone, L.E.; Wandrey, C.J.; Crovelli, R.A.; Butler, W.C.

1994-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Synthesis, structures, and properties of novel aminodisilanes bearing bulky substituents: 1,2-bis(1,1,2-trimethylpropyl)-1,1,2,2-tetrakis(diethylamino) disilane and 1,2-di-tert-butyl-1,1,2,2-tetrakis(diethylamino) disilane  

Science Journals Connector (OSTI)

Two novel tetraaminodisilanes, 1,2-bis(1,1,2-trimethylpropyl)-1,1,2,2-tetrakis(diethylamino)disilane (1) and 1,2-di-tert-butyl-1,1,2,2-tetrakis(diethylamino)disilane (2) were synthesized and X-ray crystallography analyses of these compounds were carried out. Reflecting the steric congestion, the Si?Si bonds are very long: 2.539(2) Å for bis(1,1,2-trimethylpropyl)disilane, and 2.4764(9) Å for di-tert-butyl-disilane. UV spectra and oxidation potentials of several tetraaminodialkyldisilanes are compared and discussed. In addition, in the chlorination of 1 with HCl, 1,1,2,2-tetrachloro-1,2-bis(1,1,2-trimethylpropyl)disilane (6) was obtained with a 72% yield.

Masafumi Unno; Mina Saito; Hideyuki Matsumoto

1995-01-01T23:59:59.000Z

142

APPENDXD.CHP:Corel VENTURA  

Gasoline and Diesel Fuel Update (EIA)

Report The Form EIA-819, "Monthly Oxygenate Report" provides production data for fuel ethanol and methyl tertiary butyl ether (MTBE). End-of-month stock data held at ethanol...

143

The feasibility of ethanol production in Texas  

E-Print Network (OSTI)

Agricultural interests across Texas are looking at the possibility of an ethanol industry in Texas. Continued conflict in the Middle East, the ban of methyl tertiary butyl ether (MTBE) in California, and low commodity prices have all lead...

Herbst, Brian Keith

2012-06-07T23:59:59.000Z

144

Factors controlling reservoir quality in tertiary sandstones and their significance to geopressured geothermal production. Annual report, May 1, 1979-May 31, 1980  

SciTech Connect

Differing extents of diagenetic modification is the factor primarily responsible for contrasting regional reservoir quality of Tertiary sandstones from the Upper and Lower Texas Gulf Coast. Detailed comparison of Frio sandstones from the Chocolate Bayou/Danbury Dome area, Brazoria County, and Vicksburg sandstones from the McAllen Ranch Field area, Hidalgo County, reveals that extent of diagenetic modification is most strongly influenced by (1) detrital mineralogy and (2) regional geothermal gradients. Vicksburg sandstones from the McAllen Ranch Field area are less stable, chemically and mechanically, than Frio sandstones from the Chocolate Bayou/Danbury dome area. Vicksburg sandstones are mineralogically immature and contain greater proportions of feldspars and rock fragments than do Frio sandstones. Thr reactive detrital assemblage of Vicksubrg sandstones is highly susceptible to diagenetic modification. Susceptibility is enhanced by higher than normal geothermal gradients in the McAllen Ranch Field area. Thus, consolidation of Vicksburg sandstones began at shallower depth of burial and precipitation of authigenic phases (especially calcite) was more pervasive than in Frio sandstones. Moreover, the late-stage episode of ferroan calcite precipitation that occluded most secondary porosity in Vicksburg sandstones did not occur significantly in Frio sandstones. Therefore, regional reservoir quality of Frio sandstones from Brazoria County is far better than that characterizing Vicksburg sandstones from Hidalgo County, especially at depths suitable for geopressured geothermal energy production.

Loucks, R.G.; Richmann, D.L.; Milliken, K.L.

1980-07-01T23:59:59.000Z

145

Compound “J” in Late Cretaceous/Tertiary terrigenous oils revisited: Structure elucidation of a rearranged oleanane coeluting on GC with 18?(H)-oleanane  

Science Journals Connector (OSTI)

Abstract A C30 pentacyclic triterpane eluting slightly after 18?(H)-oleanane in the m/z 191 mass chromatograms of Late Cretaceous/Tertiary terrigenous oils (peak “J” in the early literature) has been isolated from a Niger Delta oil and identified using NMR spectroscopy as 3?-methyl-24-nor-18?(H)-oleanane. The previous assignment as 18?(H)-oleanane is therefore partly erroneous. 3?-Methyl-24-nor-18?(H)-oleanane affords a larger m/z 412 ? 356 response than the oleananes and the relative contribution of 3?-methyl-24-nor-18?(H)-oleanane to the 412 ? 191 “oleanane peak” can be roughly estimated from comparison of the 412 ? 356/412 ? 191 ratio from the oleanane peak with that of the pure compounds. 3?-Methyl-24-nor-18?(H)-oleanane can be as abundant as 18?(H)-oleanane in oils having a high concentration of early eluting rearranged oleananes. 3?-Methyl-24-nor-19?(H)-taraxastane was also tentatively assigned in the oils on the basis of its mass spectrum as well as its gas chromatography and high performance liquid chromatography retention times. 3?-Methyl-24-nor-gammacerane was tentatively assigned in a similar way in an oil containing gammacerane. All 3?-methyl-24-nor-triterpanes could be formed via dehydration, rearrangement and hydrogenation of triterpenoids having an OH group at C-3.

Hans Peter Nytoft; Geir Kildahl-Andersen; Tatjana Šolevi? Knudsen; Ksenija Stojanovi?; Frode Rise

2014-01-01T23:59:59.000Z

146

Comment on "Taming the Pion Cloud of the Nucleon"  

SciTech Connect

A Comment on the Letter by M. Alberg and G.?A. Miller, Phys. Rev. Lett. 108 172001 (2012) The authors of the Letter offer a Reply.

Ji, Chueng Ryong [North Carolina State U.; Melnitchouk, Wally [JLAB; Thomas, Anthony W. [Adelaide U.

2013-04-01T23:59:59.000Z

147

Taming Density Functional Theory by Coarse-Graining  

E-Print Network (OSTI)

The standard (``fine-grained'') interpretation of quantum density functional theory, in which densities are specified with infinitely-fine spatial resolution, is mathematically unruly. Here, a coarse-grained version of DFT, featuring limited spatial resolution, and its relation to the fine-grained theory in the $L^1\\cap L^3$ formulation of Lieb, is studied, with the object of showing it to be not only mathematically well-behaved, but consonant with the spirit of DFT, practically (computationally) adequate and sufficiently close to the standard interpretation as to accurately reflect its non-pathological properties. The coarse-grained interpretation is shown to be a good model of formal DFT in the sense that: all densities are (ensemble)-V-representable; the intrinsic energy functional $F$ is a continuous function of the density and the representing external potential is the (directional) functional derivative of the intrinsic energy. Also, the representing potential $v[\\rho]$ is quasi-continuous, in that $v[\\rho]\\rho$ is continuous as a function of $\\rho$. The limit of coarse-graining scale going to zero is studied to see if convergence to the non-pathological aspects of the fine-grained theory is adequate to justify regarding coarse-graining as a good approximation. Suitable limiting behaviors or intrinsic energy, densities and representing potentials are found. Intrinsic energy converges monotonically, coarse-grained densities converge uniformly strongly to their low-intrinsic-energy fine-grainings, and $L^{3/2}+L^\\infty$ representability of a density is equivalent to the existence of a convergent sequence of coarse-grained potential/ground-state density pairs.

Paul E. Lammert

2010-08-10T23:59:59.000Z

148

TAME SETS, DOMINATING MAPS, AND COMPLEX TORI 1 ...  

E-Print Network (OSTI)

Dec 18, 2002 ... lattice in C and a lattice in Cn?1, then ? is ?-avoidable, and even ...... and Dynamics (Electron. J. Amer. Math. Soc.) 2 (1998), 45–55. MR.

2003-02-22T23:59:59.000Z

149

Taming the Wild World of Management, Performance and Communication - 13459  

SciTech Connect

Management has evolved a long way from its original meaning of 'governing a horse'. The industrial revolution fostered 'scientific management'; 1930's Hawthorne studies discovered that people's social interactions could alter productivity; and the dawn of the computer age in the post-war 1950's brought general systems theory into management thinking. Today, mobile wireless connectivity aims to transform ever-changing networks of players, mandates, and markets into something that can be 'managed'. So why is there no clear and simple recipe for how to practice management? We talk about financial management, safety management, and operations management, but surely the 'management' part of those endeavors will share the same set of practices. Instead, we are still arguing for 'management' to include everything from developing people to negotiating contracts. A manager's job may include many things, but one of them, the job of management, needs to be nailed down. Three standard practices for managing in a network are developed: (a) support the dialogues that connect people vital to accomplishing a goal or objective; (b) develop and sustain the scoreboards that serve as a road-map to reach the goal; and (c) control the feedback to 'govern the horse'. These three practices are useful for more than reaching goals, as they also support coordinating across boundaries and running productive meetings. The dialogues for productive relationships, scoreboards for goals and deliverables, and feedback for performance together constitute a recipe for managing in a networked world. (authors)

Ford, Laurie [Critical Path Consultants, 3101 Splitrock Road, Columbus Ohio 43221 (United States)] [Critical Path Consultants, 3101 Splitrock Road, Columbus Ohio 43221 (United States)

2013-07-01T23:59:59.000Z

150

MATHEMATICAE On the tameness of trivial extension algebras  

E-Print Network (OSTI)

of an alge- bra A, a tilting module TA and B = End T. For a tilting triple (B, T, A), Tachikawa and Wakamatsu

de la Peña, José Antonio

151

LANXESS Global Butyl Rubber Research Facility  

E-Print Network (OSTI)

Park, in partnership with Surface Science Western $10million City of London Investment in Fraunhofer- fraunhofer Agreement chosen to highlight celebrations for 40th Anniversary of Canada-Germany cooperation fuel cluster in Sarnia-Lambton, said Sarnia Mayor Mike Bradley, noting the Bioindustrial Innovation

Denham, Graham

152

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Ethanol Plant Production Ethanol Plant Production Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Fuel Ethanol An anhydrous alcohol (ethanol with less than 1% water) intended for gasoline blending as described in the Oxygenates definition. Oxygenates Substances which, when added to gasoline, increase the amount of oxygen in that gasoline blend. Ethanol, Methyl Tertiary Butyl Ether (MTBE), Ethyl Tertiary Butyl Ether (ETBE), and methanol are common oxygenates. Fuel Ethanol: Blends of up to 10 percent by volume anhydrous ethanol (200 proof) (commonly referred to as the "gasohol waiver"). Methanol: Blends of methanol and gasoline-grade tertiary butyl alcohol (GTBA) such that the total oxygen content does not exceed 3.5 percent by weight and the ratio of methanol to GTBA is less than or equal to 1. It is also specified that this blended fuel must meet ASTM volatility specifications (commonly referred to as the "ARCO" waiver).

153

Mechanisms of gas permeation through polymer membranes. Progress report, July 1, 1985-May 31, 1986. [CH/sub 4/, C/sub 2/H/sub 6/, n-C/sub 4/H/sub 10/, CO/sub 2/ in poly(n-butyl methacrylate)  

SciTech Connect

The work described is concerned with the significant changes in these mechanisms in the glass-transition range. Permeability, diffusion, and solubility coefficients for CH/sub 4/, C/sub 2/H/sub 4/, C/sub 2/H/sub 6/, and n-C/sub 4/H/sub 10/ in poly(n-butyl methacrylate) (PnBMA) were determined at pressures up to 25 atm and from -14/sup 0/ to 50/sup 0/C. Solubility was also determined for CO/sub 2/ in PnBMA at pressures up to 25 atm and at -10/sup 0/ and 30/sup 0/C. No significant changes were observed in the pressure (or concentration) and temperature dependence of the permeability, diffusion, and solubility coefficients for CH/sub 4/, C/sub 2/H/sub 6/, and n-C/sub 4/H/sub 10/ in the glass-transition range of PnBMA, or when the temperature was lowered below T/sub g/. Moreover, these gas/polymer systems do not exhibit below T/sub g/ the usual ''dual-mode'' sorption behavior of gases in glassy polymers. The solubility isotherm for CO/sub 2/ in PnBMA at -10/sup 0/C and lower pressures suggests incipient dual-mode sorption. Results are exceptions to dual-mode sorption behavior and may be due to small difference in the coefficients of thermal expansion of PnBMA above and below T/sub g/. This indicates that the unrelaxed domains in glassy PnBMA are very small. A ''free-volume'' mechanism describes the dependence of C/sub 2/H/sub 6/ permeability on P, T both above and below the glass transition of PnBMA. Adsorption/desorption kinetics are Fickian.

Stern, S.A.; Vakil, U.; Zhou, S.

1986-05-01T23:59:59.000Z

154

Simultaneous Efficiency, NOx, and Smoke Improvements through Diesel/Gasoline Dual-Fuel Operation in a Diesel Engine  

E-Print Network (OSTI)

or liquefied petroleum gas, natural gas, biogas, hydrogen, and alcohols such as methanol, ethanol, iso-propanol, and n-butanol), and fuel additives (MTBE or methyl tertiary-butyl ether, H2O2 or hydrogen peroxide, 2-EHN or ethylhexyl nitrate and DTBP or di...

Sun, Jiafeng

2014-08-05T23:59:59.000Z

155

Drinking Water Problems: MTBE  

E-Print Network (OSTI)

Methyl tertiary-butyl ether, a gasoline additive commonly known as MTBE, can contaminate ground water and cause health problems for those exposed to it for a long time. However, filtering devices can remove this and other additives from well water...

Dozier, Monty; Lesikar, Bruce J.

2008-08-28T23:59:59.000Z

156

Role of Volatilization in Changing TBA and MTBE Concentrations at  

E-Print Network (OSTI)

a low affinity for gasoline (low Kfw, Table 1). Therefore, minute amounts of TBA in the MTBE blended tertiary butyl ether (MTBE) added to gasoline. Frequent observations of high TBA, and especially rising TBA/MTBE concentration ratios, in groundwater at gasoline spill sites are generally attributed to microbial conversion

157

Water Research 37 (2003) 37563766 Seasonal and daily variations in concentrations of methyl-  

E-Print Network (OSTI)

by volume to gasoline from November to February, and blending 11% MTBE by volume during the rest of the year; accepted 24 March 2003 Abstract Methyl-tertiary-butyl ether (MTBE), an additive used to oxygenate gasoline of gasoline-powered watercraft. This paper documents and explains both seasonal and daily variations in MTBE

Toran, Laura

158

UMass builds bugs to eat MTBE ByAuriaCimino  

E-Print Network (OSTI)

a toxic gasoline component might be just what the doctor ordered for Maine's con- taminated groundwater with methyl tertiary butyl ether (MTBE), which is found in gasoline. Once the first field trial is complete out of the reformulated gasoline pro- gram (RFG) .The gasoline, which con- tains 11 percent MTBE

Lovley, Derek

159

Motor Gasoline Outlook and State MTBE Bans  

Reports and Publications (EIA)

The U.S. is beginning the summer 2003 driving season with lower gasoline inventories and higher prices than last year. Recovery from this tight gasoline market could be made more difficult by impending state bans on the blending of methyl tertiary butyl ether (MTBE) into gasoline that are scheduled to begin later this year.

2003-01-01T23:59:59.000Z

160

Later Tertiary Leporidae of North America  

E-Print Network (OSTI)

Saskatchewan. Generic characters. Compared with Megalagus brachyodon, cheek-teeth less hypsodont, molarization of premolars less advanced, molars less reduced, and maxilla and mandibular ramus narrower in premolar region; P3-P4 each having shallow hypostria... the Myton Pocket in Utah and M. wyomingensis from Badwater Creek, Wyoming, specimens from the Wagonhound member of the Uinta Eocene, the Duchesne River (Rand- lett horizon), and the Swift Current Creek beds of Saskatchewan have been referred to this genus...

Dawson, M. R.

1958-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Tertiary paleomagnetic results from east Kalimantan  

E-Print Network (OSTI)

0 Fig. l. Major transcurrent faults in Southeast Asia. Ic = Indochina; M = Malaysia; SCS = South China Sea; B = Kalimantan; J = Java Sea; S = Sulawesi. eastern Kalimantsn ranging from Eocene to Plio ? Pleistocene age. The result of this study... al. , 1983), the Philippines (McCabe et al. , 1987), Sulawesi (Haile, 1978; Sasajima et al. , 1980; Otofuji et al. , 1981) and Indochina (Giang, 1982; McCabe et sl. , 1988). The pole from this study is indistin- guisha. ble at the 95% confidence...

Lumadyo, Leonard E. D

2012-06-07T23:59:59.000Z

162

Ion exchange as a tertiary treatment  

E-Print Network (OSTI)

that these treatment methods are capable of removing an appreciable amount of objection? able dissolved organic and inorganic materi aJ s from the final effluent. Color and turbidity were greatly reduced and an appreciable amount of the suspended solids were... Demand Re Resin A General Anion mg. /1. MLVSS psi gpm Milligrams per I. iter Mixed Liquor Volatile Suspended Solids Pounds per Square Inch Gallons per Minute. mm Mi llimeters kgr meq ml Kilogram Milliequilavent Millimeter S. S. BV...

Westervelt, Ronald David

1968-01-01T23:59:59.000Z

163

Synthesis and characterization of hybrid materials based on 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid and Dawson-type tungstophosphate K{sub 7}[H{sub 4}PW{sub 18}O{sub 62}].18H{sub 2}O and K{sub 6}[P{sub 2}W{sub 18}O{sub 62}].13H{sub 2}O  

SciTech Connect

In this study, we synthesized hybrid materials using well-Dawson polyoxometalates (POMs), K{sub 7}[H{sub 4}PW{sub 18}O{sub 62}].18H{sub 2}O or K{sub 6}[P{sub 2}W{sub 18}O{sub 62}].13H{sub 2}O and a room temperature ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF{sub 4}]). K, W, P and CHN elemental analysis showed that one mole of [H{sub 4}PW{sub 18}O{sub 62}]{sup 7-} reacts with 6 moles of BMIM{sup +} and one mole of [P{sub 2}W{sub 18}O{sub 62}]{sup 6-} reacts with 4 moles of BMIM{sup +} to form, respectively, K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} and K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62}. X-ray diffraction illustrated amorphous structure of the hybrid materials. FT-IR spectra showed the presence of both 1-butyl-3-methylimidazolium cation and the Dawson anion. TG analysis displayed a relative thermal stability of the hybrid materials compared to the parents Dawson POMs. Cyclic voltammetry showed that the reduction peak potentials of the Dawson anion in the hybrid materials shift towards negative values and the shift is more pronounced for K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} compared to K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62}. This was attributed to a decrease in the acidity of the Dawson POM anion in the hybrid material. -- Graphical abstract: Powder XRD patterns of (a) PW{sub 18}, (b) K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62}, (c) P{sub 2}W{sub 18}, and (d) K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62}. Display Omitted Research highlights: {yields} 1-butyl-3-methylimidazolium tetrafluoroborate([BMIM][BF{sub 4}]) reacts with K{sub 7}[H{sub 4}PW{sub 18}O{sub 62}].18H{sub 2}O to form K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62}. {yields} [BMIM][BF{sub 4}] reacts with K{sub 6}[P{sub 2}W{sub 18}O{sub 62}].13H{sub 2}O to form K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62}. {yields} K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} and K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62} displayed amorphous structures. {yields} K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} and K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62} illustrated low water content. {yields} K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} and K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62} showed improved thermal stability.

Ammam, Malika, E-mail: m78ammam@yahoo.f [Department of Metallurgy and Materials Engineering (MTM), K.U Leuven, Kasteelpark Arenberg 44, B-3001 Heverlee (Belgium); Fransaer, Jan [Department of Metallurgy and Materials Engineering (MTM), K.U Leuven, Kasteelpark Arenberg 44, B-3001 Heverlee (Belgium)

2011-04-15T23:59:59.000Z

164

Reactivity of the Quinone Methide of Butylated hydroxytoluene in Solution  

E-Print Network (OSTI)

BHT is a common antioxidant in pharmaceutical formulations and when oxidized it forms a quinone methide (QM). QM is a highly reactive electrophilic species which can undergo nucleophilic addition. This research investigated ...

Willcockson, Maren Gulsrud

2011-08-31T23:59:59.000Z

165

Taming Wild Horses: The Need for Virtual Time-based Scheduling of VMs in Network Simulations  

SciTech Connect

The next generation of scalable network simulators employ virtual machines (VMs) to act as high-fidelity models of traffic producer/consumer nodes in simulated networks. However, network simulations could be inaccurate if VMs are not scheduled according to virtual time, especially when many VMs are hosted per simulator core in a multi-core simulator environment. Since VMs are by default free-running, on the outset, it is not clear if, and to what extent, their untamed execution affects the results in simulated scenarios. Here, we provide the first quantitative basis for establishing the need for generalized virtual time scheduling of VMs in network simulators, based on an actual prototyped implementations. To exercise breadth, our system is tested with multiple disparate applications: (a) a set of message passing parallel programs, (b) a computer worm propagation phenomenon, and (c) a mobile ad-hoc wireless network simulation. We define and use error metrics and benchmarks in scaled tests to empirically report the poor match of traditional, fairness-based VM scheduling to VM-based network simulation, and also clearly show the better performance of our simulation-specific scheduler, with up to 64 VMs hosted on a 12-core simulator node.

Yoginath, Srikanth B [ORNL; Perumalla, Kalyan S [ORNL; Henz, Brian J [ORNL

2012-01-01T23:59:59.000Z

166

The New Administration: A Report on Education; Taming the Rules Committee; Disarmament Activity  

Science Journals Connector (OSTI)

...Russians, will probably want to overcome domes-tic opposition to that agreement before...from awbroad will incluide Jamnshed R. Tata, Wenner-Grens Institute, Stockholm...floor to be drilled. In March, test drillings are scheduled to begin in the project...

1961-01-13T23:59:59.000Z

167

Renormalization of the strongly attractive inverse square potential: Taming the singularity  

E-Print Network (OSTI)

Quantum anomalies in the inverse square potential are well known and widely investigated. Most prominent is the unbounded increase in oscillations of the particle's state as it approaches the origin when the attractive coupling parameter is greater than the critical value of 1/4. Due to this unphysical divergence in oscillations, we are proposing that the interaction gets screened at short distances making the coupling parameter acquire an effective (renormalized) value that falls within the weak range 0 to 1/4. This prevents the oscillations form growing without limit giving a lower bound to the energy spectrum and forcing the Hamiltonian of the system to be self-adjoint. Technically, this translates into a regularization scheme whereby the inverse square potential is replaced near the origin by another that has the same singularity but with a weak coupling strength. Here, we take the Eckart as the regularizing potential and obtain the corresponding solutions (discrete bound states and continuum scattering states).

A. D. Alhaidari

2014-06-14T23:59:59.000Z

168

Taming Single-Thread Program Performance on Many Distributed On-Chip L2 Caches  

E-Print Network (OSTI)

and instruction-level parallelism is running out of steam, and the power and energy consumption has be- come, this "oracle" scheme outperforms the conventional shared caching scheme by up to 208% with an average of 45- ment scheme that determines the home cache slice and cache bin for memory pages without any static

Cho, Sangyeun

169

Tame zebra mussels at lower cost using ClO{sub 2}  

SciTech Connect

A potential cost-effective alternative to other oxidizing molluscicides, chlorine dioxide applied intermittently apparently achieves equivalent control of veliger settlement in cooling systems. Various techniques have been used with success for controlling zebra mussel infestation. Powerplant owners, however, continue to search for methods to minimize treatment costs. One example is a nuclear station located on the eastern shore of Lake Michigan, which has been able to control the mollusk with chlorine (in the form of sodium hypochlorite, generated on-site), non-oxidizing biocide, and mechanical removal of adult mussels. Recently, the plant evaluated the possibility of substituting chlorine dioxide (ClO{sub 2}) to achieve the same result more economically, without additional impact on the environment. Results indicate that initial shock treatment with ClO{sub 2} followed by intermittent application during the spawning season can provide adequate control at a lower cost.

Freymark, S.; Hale, L.

1996-01-01T23:59:59.000Z

170

Tameness and stress physiology in a predator-naive island species confronted with novel predation threat  

Science Journals Connector (OSTI)

...Evolutionary Biology, Princeton UniversityPrinceton...hormones in the blood plasma, even under field conditions...circulating levels of plasma corticosterone (CORT...about 200g for 5min. The plasma was then transferred...C and transported to Princeton University on dry ice...

2007-01-01T23:59:59.000Z

171

Taming light with cold atoms: light at bicycle speed.… and slower yet!  

Science Journals Connector (OSTI)

The latest results from our Slow Light/Bose-Einstein condensation experiment will be presented. ... bottle. We have succeeded in reducing the light speed in a Bose condensate to the speed of a bicycle by using th...

L. Hau

2003-01-01T23:59:59.000Z

172

Insuring climate change? Science, fear, and value in reinsurance markets  

E-Print Network (OSTI)

Oxford University Press. Hacking, I. 1990. The Taming ofof liberal governance (Hacking 1990; Rose 1999; Ewald 1991;historian of science Ian Hacking (1990) calls “the taming of

Johnson, Leigh Taylor

2011-01-01T23:59:59.000Z

173

Weekly Petroleum Status Report  

U.S. Energy Information Administration (EIA) Indexed Site

5 5 Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH3-(CH2)n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usually refers to the high octane product from alkylation units. This alkylate is used in

174

hotspots and BEAST  

SciTech Connect

Hotspots Tamed by BEAST -- Secrets of Mysterious Metal Hotspots Uncovered by New Single Molecule Imaging Technique

None

2010-01-01T23:59:59.000Z

175

TAMING THE INVISIBLE MONSTER: SYSTEM PARAMETER CONSTRAINTS FOR {epsilon} AURIGAE FROM THE FAR-ULTRAVIOLET TO THE MID-INFRARED  

SciTech Connect

We have assembled new Spitzer Space Telescope IRAC observations of the mysterious binary star {epsilon} Aurigae, along with archival far-ultraviolet to mid-infrared data, to form an unprecedented spectral energy distribution (SED) spanning 3 orders of magnitude in wavelength from 0.1 {mu}m to 100 {mu}m. The observed SED can be reproduced using a three-component model consisting of a 2.2{sup +0.9}{sub -0.8} M{sub sun} F-type post-asymptotic giant branch star, and a 5.9 {+-} 0.8 M{sub sun} B5{+-}1 type main-sequence star that is surrounded by a geometrically thick, but partially transparent, disk of gas and dust. At the nominal HIPPARCOS parallax distance of 625 pc, the model normalization yields a radius of 135 {+-} 5 R{sub sun} for the F star, consistent with published interferometric observations. The dusty disk is constrained to be viewed at an inclination of i {approx_gt} 87{sup 0}, and has an effective temperature of 550 {+-} 50 K with an outer radius of 3.8 AU and a thickness of 0.95 AU. The dust content of the disk must be largely confined to grains larger than {approx}10 {mu}m in order to produce the observed gray optical-infrared eclipses and the lack of broad dust emission features in the archival Spitzer mid-infrared spectra. The total mass of the disk, even considering a potential gaseous contribution in addition to the dust that produces the observed infrared excess, is <<1 M{sub sun}. We discuss evolutionary scenarios for this system that could lead to the current status of the stellar components and suggest possibilities for its future evolution, as well as potential observational tests of our model.

Hoard, D. W. [Spitzer Science Center, California Institute of Technology, Pasadena, CA 91125 (United States); Howell, S. B. [National Optical Astronomy Observatory, Tucson, AZ 85719 (United States); Stencel, R. E. [Department of Physics and Astronomy, University of Denver, Denver, CO 80208 (United States)

2010-05-01T23:59:59.000Z

176

Influence of taming on the episodic pattern of LH in peripheral plasma of percentage-Brahman heifers  

E-Print Network (OSTI)

by Hendricks (1970), Swanson and Hafs (1971) and Snook et al. (1971). The profiles observed using infrequent sampling indicated basal levels of LH (1-4 ng/ml) throughout the estrous cycle, except for a surge (7-50 ng/ml) near the onset of estrus (Snook et al... in this area to determine how stress can affect the endocrine system. Such knowledge will hopefully lead to more productive and rewarding management practices. 34 LITERATURE CI'ZED Ajika, K. , S. P. Xalra, C. P, Fawcett, L. Krulich and J. M. McCann. 1972...

Henricks, Rohn Hayden

2012-06-07T23:59:59.000Z

177

PUBLISHED ONLINE: 26 FEBRUARY 2014 | DOI: 10.1038/NCLIMATE2120 Taming hurricanes with arrays of o shore  

E-Print Network (OSTI)

of wind turbines installed offshore in front of major cities and along key coastal areas can extract to coastal structures as well as to the offshore turbines themselves. Unlike sea walls, offshore wind with arrays of o shore wind turbines Mark Z. Jacobson1 *, Cristina L. Archer2 and Willett Kempton3 Hurricanes

178

Taming hot CF3 radicals: incrementally tuned families of polyarene acceptors for air-stable molecular optoelectronics  

SciTech Connect

Breakthroughs in molecular optoelectronics await the availability of new families of air-stable polyaromatic hydrocarbon (PAH) acceptors with incrementally- and predictably-tunable electron affinities and structures capable of inducing desirable solid-state morphologies in hybrid materials. Although the addition of electron withdrawing groups to PAHs has been studied for decades, producing new compounds from time to time, a generic one-step synthetic methodology applicable to potentially all PAH substrates has been, until now, an impossible dream. We herein report that at least seventeen common PAHs and polyheterocyclics can be trifluoromethylated by a new procedure to yield families of PAH(CF3)n acceptors with (i) n = 4-8, (ii) multiple isomers for particular n values, (iii) gas-phase experimental electron affinities as high as 3.32 eV and shifted from the respective PAH precursor as a linear function of n, and (iv) various solid-state morphologies, including the ability to form alternating ? stacked hybrid crystals with aromatic donors.

Kuvychko, Igor V.; Castro, Karlee P.; Deng, Shihu; Wang, Xue B.; Strauss, Steven H.; Boltalina, Olga V.

2013-04-26T23:59:59.000Z

179

Process for tertiary oil recovery using tall oil pitch  

DOE Patents (OSTI)

A process and compositions for enhancing the recovery of acid crudes are disclosed. The process involves injecting caustic solutions into the reservoir to maintain a pH of 11 to 13. The fluid contains an effective amount of multivalent cation for inhibiting alkaline silica dissolution with the reservoir. A tall oil pitch soap is added as a polymeric mobility control agent. (DMC)

Radke, C.J.

1983-07-25T23:59:59.000Z

180

The Existence of Man in the Tertiary Epoch  

Science Journals Connector (OSTI)

... IN the Bibliothèque Universelle et Revue Suisse for the 15 th February, M. Favre, in an article ...

1870-04-07T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Cosolvent-induced transformation of a death domain tertiary structure  

Science Journals Connector (OSTI)

...Density modification using SOLOMON (17) increased the figure of merit from 0.70 to 0.82 at 2.7-a resolution. A...S. W. ( 1993 ) Proteins 17,75 -86. 8234246 We thank Nick Pace for a critical reading of the manuscript, A. Loew, D...

Tsan Xiao; Kevin H. Gardner; Stephen R. Sprang

2002-01-01T23:59:59.000Z

182

THE EARLY TERTIARY VOLCAINOES OF THE ABSAROKA RANGE  

Science Journals Connector (OSTI)

...interbedded breecias pass into sheets, and later again assume the...varied modifications of eruptive energy, a bold stock, Clouds Home...examples of a massive interbedded sheet extends for a mile or more along...Beyond this point eruptive energy gradually dies out, and is...

Arnold Hague

1899-03-24T23:59:59.000Z

183

Freezing-induced perturbation of tertiary structure of monoclonal antibody  

E-Print Network (OSTI)

-30 -20 -10 0 10 20 Temperature (C) E m i ssi o n p eak p o s i t i o n ( n m) IgG+KCl Pre-frozen 20C Frozen -30C Post-thawed 20C Peak shift due to freez- ing pH8 338.4 ? 0.1 nm 338.7 ? 0.0 nm 338.0 ? 0.1 nm 0.3 nm pH3 340.7 ? 0.5 nm...

Liu, Lu; Kueltzo, L. A.; Jones, L. S.; Carpenter, J. F.

2006-10-25T23:59:59.000Z

184

Low Barrier Hydrogen Bonds in Acyclic Tertiary Diamines  

E-Print Network (OSTI)

B: synthesis of diamide with phosphorous pentoxide, and C:synthesis uses phosphorous pentoxide and dimethylformamide (B: synthesis of diamide with phosphorous pentoxide, and C:

Khodagholian, Sevana

2010-01-01T23:59:59.000Z

185

Impacts of Ethanol on Anaerobic Production of Tert-Butyl Alcohol (TBA) from Methyl Tert-Butyl Ether (MTBE) in Groundwater  

E-Print Network (OSTI)

Project title: Impacts of Ethanol on Anaerobic Production oftert-butanol (TBA). As ethanol is being promoted as ainvestigate the effect of ethanol release on existing MTBE

Scow, K M; MacKay, Douglas

2008-01-01T23:59:59.000Z

186

Solubility of Solid tert-Butyl Mercaptan in Liquid Methane and an LNG Mixture  

Science Journals Connector (OSTI)

Knowledge of the solubility limit of heavy hydrocarbons in liquid methane is of practical interest in the liquefaction of natural gas. Data for several binary systems were given in previous publications [1,2].The...

G. P. Kuebler; C. McKinley

1980-01-01T23:59:59.000Z

187

The K-band microwave spectra of t-butyl halides  

E-Print Network (OSTI)

1954 Major Subjeet: Chemistry ACKNOWLEDGMENT The author wishes to express his appreciation to Dr. Fred W. Jensen for his help and encouragement during the oourse of this investigation. To the author's wife, Helen Louise, goes the credit for most...) as 100%. 10 Transition nvun.be r assignments and frequencies of the unperturbed rotational lines aa given abova ware calculated by Methods described in the following seotion. 11 DISCUSSION 12 The fundamental process of energy absorption...

Crook, George Hardy

2013-10-04T23:59:59.000Z

188

E-Print Network 3.0 - alkyl tert-butyl ether Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

> >> 1 7198 J. Org. Chem. 1995,60, 7198-7208 Gas Phase Decomposition of Conjugate Acid Ions of Simple Summary: .S.Patent 5,091,590,1992. 0 1995American Chemical Society...

189

E-Print Network 3.0 - aluminum triso-ethylphosphonate butylate...  

NLE Websites -- All DOE Office Websites (Extended Search)

Resistance Advancements: Dr. Dragan CurcijaDr. Dragan Curcija Summary: -Expanded (EPS) Pine or Douglas Fir Frame Cavity Polyfoam tape Urethane Sealant Silicone...

190

THERMODYNAMICS OF EXTRACTION OF NITRIC ACID BY TRI-n-BUTYL PHOSPHATE--HYDROCARBON DILUENT SOLUTIONS  

E-Print Network (OSTI)

the mean act ivi ty coefficient T of TBP and TBP.H20 i n the acid-free, water-saturated organic phase

Wallace Davis

1961-01-01T23:59:59.000Z

191

Safe conditions for contacting nitric acid or nitrates with tri-n-butyl phosphate (TBP)  

SciTech Connect

In response to a request from DOE-SR, the current state of knowledge of the reactions between TBP and aqueous nitrate solutions is critically reviewed, and recommendations are made for the safe operation of SRS separations equipment in which this combination of chemicals may be present. The existing limits for evaporation are validated. Guidelines are presented for cases in which general limits do not apply. The rate of reaction between nitric acid and TBP appears to be controlled by the rate of TBP hydrolysis. The hydrolysis reaction produces dibutyl phosphate and n-butanol. The hydrolysis rate is a strong function of temperature, and becomes very fast at temperatures in the range 130{degrees} to 150{degrees}C. The resulting n-butanol is volatile at high temperatures, boiling at 117.5{degrees}C, but is also subject to exothermic oxidation by nitric acid or nitrates. If oxidation occurs before the n-butanol evaporates, the heat of oxidation may exceed local cooling by convection. The resulting heating will further accelerate the reaction, leading to an energetic runaway and possibly (in confined systems) an explosion. Extensive experiments and practice have shown that in a well-mixed and well-vented aqueous system such as an evaporator, at moderate acidities and temperatures below 130{degrees}C, the heat of reaction is adequately removed by vaporization of steam. In general, the heating will be so slow that natural processes provide adequate cooling at temperatures below 80{degrees}C. Above this temperature, care should be taken to ensure that adequate cooling is available for the amount of TBP that may be present. Experiments suggest that in well-ventilated systems n-butanol evaporation and convective cooling are sufficient to control the reaction at temperatures up to 120{degrees}C.

Hyder, M.L

1994-01-01T23:59:59.000Z

192

Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 1.  

E-Print Network (OSTI)

because of its low cost and blending characteristics. Depending on the season, reformulated gasoline of reactor per hour, a value comparable to other gasoline constituents. Such high performance could enhancer in gasoline. The use of MTBE increased rapidly after the 1990 Clean Air Act Amendments required

193

Optical fibers by butyl methacrylate reactive extrusion Berthet Romuald, Chalamet Yvan, Taha Mohamed*, Zerroukhi Amar  

E-Print Network (OSTI)

limitations. Reactive extrusion experiments were carried out in a twin-screw extruder and the effect optical fibbers, polymethacrylate. Introduction Twin screw extruders are playing an increasing role of reactive extrusion is explained by the different advantages offered by the use of the twin-screw extruders

Paris-Sud XI, Université de

194

E-Print Network 3.0 - acaricide tri-n-butyl tin Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

of California, Davis; Seybold, Steven J. - Departments of Entomology and Forest Resources, University of Minnesota Collection: Biotechnology ; Environmental Sciences and...

195

Environmental Microbiology (2001) 3(6), 407416 Methyl tert-butyl ether (MTBE) degradation by a  

E-Print Network (OSTI)

Tank (LUFT) remediation programme. A recent USGS study has estimated that as many as 9000 community, remediation actions are implemented at costs usually 10± 30% higher than those at sites without MTBE contamina- tion. The evaluation of innovative and cost-effective treatment such as bioremediation for MTBE spills

196

Biodegradation of Methyl tert-Butyl Ether by a Pure Bacterial Culture  

Science Journals Connector (OSTI)

...identify cost-effective remediation technologies. Relatively...treated with ENV735 as a remediation biocatalyst, but the strain...through the Small Business Innovative Research program (grant...situ bioaugmentation for remediation of chlorinated solvents in...

Paul B. Hatzinger; Kevin McClay; Simon Vainberg; Marina Tugusheva; Charles W. Condee; Robert J. Steffan

2001-12-01T23:59:59.000Z

197

Treatment of Methyl tert-Butyl Ether Contaminated Water Using a Dense  

E-Print Network (OSTI)

discharge of organic compounds require that new, innovative tech- nologies and methods of remediation dioxide, making the DMP reactor a promising tool in the future remediation of water. Chemical and physical is transformed into a more toxic material or a substance that is more difficult to remediate, the treatment

Dandy, David

198

Oxidative desulfurization of dibenzothiophene with tert-butyl hydro peroxide in a photochemical micro-reactor.  

E-Print Network (OSTI)

??Sulfur content in fuels is an increasingly critical environmental issue. Hydrodesulfurization removes sulfur from hydrocarbons; however, further desulfurization is necessary in fuels. New methods are… (more)

Hebert, Eilleen M.

2007-01-01T23:59:59.000Z

199

Frontside versus backside reactivity in electron transfer to oriented tert butyl bromide and methyl bromide  

E-Print Network (OSTI)

by bimolecular nucleophilic substitution (SN2) reactions, such as Cl CH3BrClCH3 Br . 1 These reactions proceedH9Br. © 2002 American Institute of Physics. DOI: 10.1063/1.1496477 I. INTRODUCTION Chemical reaction decreases the reaction rate by orders of magnitude because the larger CH3 groups impede the inversion

Brooks, Philip R.

200

Saponification rates of isomeric butyl esters in aqueous 1,4-dioxane  

E-Print Network (OSTI)

, "Handbuch der Organischen Chemie," l*th ed., Vol. II, J. Springer, Berlin, 1920 (see also 1st and 2nd supplements); %. Schlenk, Jr., Ann., 573, 1^2(1951). 26 V. 1,4-Dioxane. The 1,4-dioxane (Matheson Co.) used in this research was specified...

Ruhnke, Edward Vincent

2013-10-04T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

E-Print Network 3.0 - antioxidant butylated hydroxytoluene Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

University Collection: Environmental Sciences and Ecology ; Biology and Medicine 5 Evaluation of Potential Therapies for a Mouse Model of Human Age-Related Macular Degeneration...

202

E-Print Network 3.0 - acid t-butyl ester Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

at Berkeley Collection: Materials Science ; Chemistry 67 Management of Hazardous Waste A Policy and Procedures Manual Summary: . It can be substituted by...

203

Native Americans and Type 2 Diabetes: The Discourse of Predisposition and its Politics  

E-Print Network (OSTI)

Research 53(3):207-210. Hacking, Ian 1990 The Taming ofIn The Taming of Chance, Ian Hacking writes of the rise ofthe division of populations. Hacking believed that these “

McGuire, Laurette Ann

2012-01-01T23:59:59.000Z

204

Petroleum Supply Monthly  

Gasoline and Diesel Fuel Update (EIA)

0 0 December 2011 Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH3-(CH2)n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usually refers to the high octane product from alkylation units. This alkylate is used in blending high octane gasoline. Alkylation. A refining process for chemically combining isobutane with olefin hydrocarbons (e.g., propylene, butylene) through the control of temperature and pressure in the presence of an acid catalyst,

205

Petroleum Supply Monthly  

U.S. Energy Information Administration (EIA) Indexed Site

September 2013 September 2013 Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH3-(CH2)n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usually refers to the high octane product from alkylation units. This alkylate is used in blending high octane gasoline. Alkylation. A refining process for chemically combining isobutane with olefin hydrocarbons (e.g., propylene, butylene) through the control of temperature and pressure in the presence of an acid catalyst,

206

MTBE, Oxygenates, and Motor Gasoline (Released in the STEO October 1999)  

Reports and Publications (EIA)

The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an increase in MTBE production between 1990 and 1994. MTBE demand increased from 83,000 in 1990 to 161,000 barrels per day in 1994. The reformulated gasoline (RFG) program provided a further boost to oxygenate blending. The MTBE contained in motor gasoline increased to 269,000 barrels per day by 1997.

1999-01-01T23:59:59.000Z

207

Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model (Released in the STEO March 1998)  

Reports and Publications (EIA)

The blending of oxygenates, such as fuel ethanol and methyl tertiary butyl ether (MTBE), into motor gasoline has increased dramatically in the last few years because of the oxygenated and reformulated gasoline programs. Because of the significant role oxygenates now have in petroleum product markets, the Short-Term Integrated Forecasting System (STIFS) was revised to include supply and demand balances for fuel ethanol and MTBE. The STIFS model is used for producing forecasts in the Short-Term Energy Outlook. A review of the historical data sources and forecasting methodology for oxygenate production, imports, inventories, and demand is presented in this report.

1998-01-01T23:59:59.000Z

208

California's Move Toward E10 (released in AEO2009)  

Reports and Publications (EIA)

In Annual Energy Outlook 2009, (AEO) E10–a gasoline blend containing 10% ethanol–is assumed to be the maximum ethanol blend allowed in California erformulated gasoline (RFG), as opposed to the 5.7% blend assumed in earlier AEOs. The 5.7% blend had reflected decisions made when California decided to phase out use of the additive methyl tertiary butyl ether in its RFG program in 2003, opting instead to use ethanol in the minimum amount that would meet the requirement for 2.0% oxygen content under the Clean Air Act provisions in effect at that time.

2009-01-01T23:59:59.000Z

209

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Inputs & Utilization Inputs & Utilization Definitions Key Terms Definition All Other Motor Gasoline Blending Components Naphthas (e.g. straight-run gasoline, alkylate, reformate, benzene, toluene, xylene) used for blending or compounding into finished motor gasoline. Includes receipts and inputs of Gasoline Treated as Blendstock (GTAB). Excludes conventional blendstock for oxygenate blending (CBOB), reformulated blendstock for oxygenate blending, oxygenates (e.g. fuel ethanol and methyl tertiary butyl ether), butane, and pentanes plus. Barrel A unit of volume equal to 42 U.S. gallons. Blending Plant A facility which has no refining capability but is either capable of producing finished motor gasoline through mechanical blending or blends oxygenates with motor gasoline.

210

The effect of confinement in metabolism stalls on the cortisol, antibody production, and antibody-dependent cell-mediated cytotoxicity of tame lambs  

E-Print Network (OSTI)

and behavioral factors should be measured to determine whether an animal is experiencing stress (Moberg, 1985). Methods of assessing Format follows the style of the Journal of Animal Science. chronic stress include measurement of the responsiveness... and behavioral factors should be measured to determine whether an animal is experiencing stress (Moberg, 1985). Methods of assessing Format follows the style of the Journal of Animal Science. chronic stress include measurement of the responsiveness...

Hsieh, Man-Ling

2012-06-07T23:59:59.000Z

211

Fuel Ethanol Oxygenate Production  

Gasoline and Diesel Fuel Update (EIA)

Product: Fuel Ethanol Methyl Tertiary Butyl Ether Merchant Plants Captive Plants Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day Product: Fuel Ethanol Methyl Tertiary Butyl Ether Merchant Plants Captive Plants Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area May-13 Jun-13 Jul-13 Aug-13 Sep-13 Oct-13 View History U.S. 27,197 26,722 26,923 26,320 25,564 27,995 1981-2013 East Coast (PADD 1) 628 784 836 842 527 636 2004-2013 Midwest (PADD 2) 25,209 24,689 24,786 24,186 23,810 26,040 2004-2013 Gulf Coast (PADD 3) 523 404 487 460 431 473 2004-2013 Rocky Mountain (PADD 4) 450 432 430 432 415 429 2004-2013 West Coast (PADD 5)

212

Effect of use of low oxygenate gasoline blends upon emissions from California vehicles. Final report  

SciTech Connect

The objective of this project was to investigate the emissions effects of low-oxygenate gasoline blends on exhaust and evaporative emissions from a test fleet of California certified light-duty autos. Thirteen vehicles were procured and tested using four gasoline-oxygenate blends over three test cycles. The four gasoline blends were: Methyl Tertiary Butyl Ether (MTBE), Ethyl Tertiary Butyl Ether (ETBE), and 'match' and 'splash' blends of ethanol (in the 'match' blend the fuel Reid Vapor Pressure (RVP) is held constant, while in the 'splash' blend the fuel RVP is allowed to increase). Hydrocarbon and carbon monoxide exhaust emissions were generally reduced for the oxygenated blends, the exception being the 'splash-blended' ethanol gasoline which showed mixed results. Older technology vehicles (e.g., non-catalyst and oxidation catalyst) showed the greatest emissions reductions regardless of gasoline blend, while later technology vehicles showed the smallest reductions. Evaporative emissions and toxics were generally reduced for ETBE, while results for the other blends were mixed.

Born, G.L.; Lucas, S.V.; Scott, R.D.; DeFries, T.H.; Kishan, S.

1994-02-01T23:59:59.000Z

213

THE JOURNAL OF CHEMICAL PHYSICS 139, 014704 (2013) Molecular dynamics simulations of n-hexane at 1-butyl-3-  

E-Print Network (OSTI)

pharmaceutical ingredients, solvents for green processing, purification processes, supercritical fluid applica

Lisal, Martin

214

Effect of Butylated Hydroxytoluene (BHT) on the Aerobic Biodegradation of a Model Vegetable Oil in Aquatic Media  

Science Journals Connector (OSTI)

Becker, P.; Koster, D.; Popov, M. N.; Markossian, S.; Antranikian, G.; Markl, H.The biodegradation of olive oil and the treatment of lipid-rich wool scouring wastewater under aerobic thermophilic conditions Water Resour. ... The biodegradation of olive oil and the treatment of lipid-rich wool scouring wastewater under aerobic thermophilic conditions ... The biodegrdn. of olive oil and the treatment of the lipid-rich wool scouring wastewater were studied under aerobic thermophilic (65°) conditions using Bacillus thermoleovorans IHI-91. ...

Darine A. Salam; Makram T. Suidan; Albert D. Venosa

2012-06-01T23:59:59.000Z

215

Biodegradation of Methyl tert-Butyl Ether and Other Fuel Oxygenates by a New Strain, Mycobacterium austroafricanum IFP 2012  

Science Journals Connector (OSTI)

...and the O2 consumption rate was measured with a 12-mm...France). The measured rates were corrected for endogenous...Cells were broken by three passes through a French press...from 105 to 200C at a rate of 10C/min. Helium...flushed with a Spectra-Physics SCM 400 vacuum flusher...

Alan François; Hugues Mathis; Davy Godefroy; Pascal Piveteau; Françoise Fayolle; Frédéric Monot

2002-06-01T23:59:59.000Z

216

Acta Cryst. (1983). C39, 985-987 Structureof Benzoyl(tert-butyl isocyanide)(carbonyl)bis(dimethylphenyl-  

E-Print Network (OSTI)

.375(3) and 2.362 (4) ]~; -COPh is trans to --CNC(Me) 3 with Ru-COPh and Ru-CNC(Me) 3 distances of 2.142 (15 with equimolar quantities of the isocyanide Me3CNC. From the analytical data for the products it was difficult obtained by reaction of [Ru(CO)2Ph 2- (PMe2Ph)2] and Me3CNC. It seemed possible that the resonance was due

217

On the structural and impedance characteristics of Li- doped PEO, using n-butyl lithium in hexane as dopant  

SciTech Connect

Nowadays polymer based solid state electrolytes for applications in rechargeable battery systems are highly sought after materials, pursued extensively by various research groups worldwide. Numerous methods are discussed in literature to improve the fundamental properties like electrical conductivity, mechanical stability and interfacial stability of polymer based electrolytes. The application of these electrolytes in Li-ion cells is still in the amateur state, due to low ionic conductivity, low lithium transport number and the processing difficulties. The present work is an attempt to study the effects of Li doping on the structural and transport properties of the polymer electrolyte, poly-ethelene oxide (PEO) (Molecular weight: 200,000). Li doped PEO was obtained by treating PEO with n-Butyllithium in hexane for different doping concentrations. Structural characterization of the samples was done by XRD and FTIR techniques. Impedance measurements were carried out to estimate the ionic conductivity of Li doped PEO samples. It is seen that, the crystallinity of the doped PEO decreases on increasing the doping concentration. XRD and FTIR studies support this observation. It is inferred that, ionic conductivity of the sample is increasing on increasing the doping concentration since less crystallinity permits more ionic transport. Impedance measurements confirm the results quantitatively.

Anand, P. B., E-mail: anandputhirath@gmail.com, E-mail: jayalekshmi@cusat.ac.in; Jayalekshmi, S., E-mail: anandputhirath@gmail.com, E-mail: jayalekshmi@cusat.ac.in [Division for Research in Advanced Materials Department of Physics Cochin University of Science and Technology Cochin 22, Kerala (India)

2014-01-28T23:59:59.000Z

218

Safety of Tri-n-butyl phosphate (TBP) and nitric acid solutions in two-phase systems at elevated temperatures  

SciTech Connect

This paper addresses the prevention of self-accelerating oxidation of nitric acid and tributyl phosphate (TBP). An accident of this type, which occurred at Tomsk-7, Russia, in 1993, resulted from a slow chemical reaction occurring initially at sub-boiling temperatures. The accumulating heat and vapors overpressurized and burst a process tank. Two safety issues are addressed in this summary of experimental data: circumstances under which convection or radiation cooling of vessels will exceed reaction heat, and measures which can prevent or mitigate such reactions. Heat generations rates have been found to range widely. Thermodynamic calculations confirm that heat generation is reduced by a large factor when nitrogen oxides are able to escape from the reaction mixure. Scoping calculations show that the evaporation of water is potentially the most effective mechanism for heat removal in a large vessel, and experiments have demonstrated that water evaporation is effective for preventing runaway reactions in a vented, two-phase system operated below about 120 C. These data indicate that venting is the key to controlling runaway reactions. However, other experiments have indicated that the self-heating reaction did not present a danger, even if reaction heating led to an accelerating reaction, in a sufficiently vented system. To determine how much venting was required, experiments were performed with pure organic phase and two-phase TBP-nitric acid mixtures. Data show a critical ratio of organic mass to vent area, above which the reacting system can reach potentially dangerous pressures. Experiments show runaway reactions occurring in vented systems only as the temperature approaches 130 C. These results clearly indicate that adequate venting of vessels containing heated TBP and nitrate is the key to controlling their reaction.

Hyder, M.L.; Paddleford, D.F.; Thompson, M.C. [Westinghouse Savannah River Company, Aiken, SC (United States)

1995-12-31T23:59:59.000Z

219

Enhancing Transport of Hydrogenophaga flava ENV735 for Bioaugmentation of Aquifers Contaminated with Methyl tert-Butyl Ether  

Science Journals Connector (OSTI)

...column was washed with the surfactant solution. d The sand was prewashed with the surfactant solution, and the cells...washed with BSM without surfactant. This work was supported...bacteria through a sandy soil. Appl. Environ. Microbiol...

Sheryl H. Streger; Simon Vainberg; Hailiang Dong; Paul B. Hatzinger

2002-11-01T23:59:59.000Z

220

An experimental system for the n-butyl-lithium initiated polymerization of styrene in a multi-sampled batch reactor  

E-Print Network (OSTI)

. The power to the water heater is controlled by a Fisher Proportional Temperature Control (Catalog P3 TENPERATURE CONTROLLER CONSTANT TENPERATURE BATH P2 CHILLER ELECTRICAL HEATER Figure 3. Schematic of Reactor Temperature Control System 20... successful column; i, e, , extremely high pressure drops and low plate counts were observed in these columns. As a last measure, the gel was stirred in a hot, concen- trated sodium hydroxide solution (approximately pH 13) for ten hours. The excess sodium...

Cox, James Harvey

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Treatment of methyl t-butyl ether contaminated water using a dense medium plasma reactor, a mechanistic and kinetic investigation  

E-Print Network (OSTI)

, a mechanistic and kinetic investigation Derek C. Johnson1 , Vasgen A. Shamamian2 , John H. Callahan2 , Ferencz S in the future remediation of water. Chemical and physical mechanisms, together with carbon balances, are used

Dandy, David

222

Effects of Gasoline Formulation on Methyl tert-Butyl Ether (MTBE) Contamination in Private Wells near Gasoline Stations  

Science Journals Connector (OSTI)

New York State Department of Health, Bureau of Environmental Exposure Investigation, 547 River Street, Room 300, Troy, New York 12180, and New York State Department of Health, Wadsworth Center for Laboratories and Research, P.O. ... Wells with contamination of ?20 ?g/L were scheduled for periodic or follow-up sampling by local county health departments or scheduled for remedial action, as appropriate. ... (13)?Delzer, G. C.; Zogorski, J. S.; Lopes, T. J.; Bosshart, R. L. Occurrence of the gasoline Oxygenate MTBE and BTEX compounds in urban stormwater in the United States, 1991?1995; U.S. Geologic Survey Water-Resources Investigations Report, WRIR 96-4145, Rapid City, SD, 1996. ...

Daniel P. Lince; Lloyd R. Wilson; Gordon A. Carlson; Anthony Bucciferro

2001-02-10T23:59:59.000Z

223

Enhancing Transport of Hydrogenophaga flava ENV735 for Bioaugmentation of Aquifers Contaminated with Methyl tert-Butyl Ether  

Science Journals Connector (OSTI)

...National Science Foundation Small Business Innovative Research (SBIR) program (award no...Ontario, Canada. Ground Water Monit. Remediation 18: 113-122. 52 Scholl, M. A...evaluation of in situ bioaugmentation for remediation of chlorinated solvents in groundwater...

Sheryl H. Streger; Simon Vainberg; Hailiang Dong; Paul B. Hatzinger

2002-11-01T23:59:59.000Z

224

TERTIARY AND QUATERNARY GEOLOGY OF THE LOWER RIO PUERCO AREA, NEW MEXICO  

Science Journals Connector (OSTI)

...hogbacks east of Lucero Mesa, where resistant...fig. 2). The Chupadera formation may be...backs east of Lucero Mesa, and most of the...Andres member of the Chupadera formation consists...Santa Fe time the Chupadera was exposed in the...the lava-capped mesas and the alluvium...

225

Early Tertiary Age of Pitchstone in the Northern Black Hills, South Dakota  

Science Journals Connector (OSTI)

...the glass is isotropic but has tiny anisotropic particles. Some of these particles are...offossil-iferous Upper Cretaceous Carlile shale. The Carlile is about 1100 m stratigraphi-cally...xiii). Drake supposed that the Carlile shale fragments had been acquired from steep...

JACK A. REDDEN; JOHN D. OBRADOVICH; CHARLES W. NAESER; ROBERT E. ZARTMAN; JAMES J. NORTON

1983-06-10T23:59:59.000Z

226

Micropaleontology and mineralogy of a tertiary sediment core from the Sigsbee knolls, Gulf of Mexico  

E-Print Network (OSTI)

PLATES ~ ~ o ~ a ~ o ~ e e ~ o o a a ~ ~ o ~ 91 LIST OF FIQEES Figure Page 1 Physiographic provinces of the Western Gulf of Mexico showing location of the Sigsbee knolls. . . . . 16 2 Bathymetry of the Sigsbee knolls ~ e o a a e a o ~ o ~ 18 3 X..., size analyses, and water content . 14 2 Distribution of calcareous nannoplankton in core 64& 9 SE e ~ o o e o o o o o ~ o e a a o ~ e o o e ~ ~ 35 3 Interpretation of X-ray diffractogoams ~ . . ~. . . . 50 LIST OF PLATES Plate 1 Ihotognaph of core...

Pyle, Thomas Edward

2012-06-07T23:59:59.000Z

227

Palaeomagnetism and radiometric dating of the British Tertiary Igneous Province: Muck and Eigg  

Science Journals Connector (OSTI)

......Vaternish dyke swarm on North Skye, Scotland, Geophys...sediments on the shore of Camas Mor in Muck and Cretaceous...M O R G A B B R O The Camas Mdr Gabbro was sampled...1 for locations). North Cliffs Cleadale- Laig...lava succession, at the north of Eigg, has an age spectrum......

P. Dagley; A. E. Mussett

1986-04-01T23:59:59.000Z

228

Monitoring Electricity Consumption in the Tertiary Sector- A Project within the Intelligent Energy Europe Program  

E-Print Network (OSTI)

Services and Energydesign, Technical University of Braunschweig, Germany Univ.-Prof. Dr.-Ing. M. Norbert Fisch Head of Institute IGS ? Institute of Building Services and Energydesign, Technical University of Braunschweig, Germany Edelgard Gruber... Competence Centre Energy Policy and Energy Systems, Fraunhofer Institute for Systems and Innovation Research, Karlsruhe, Germany Barbara Schlomann Competence Centre Energy Policy and Energy Systems, Fraunhofer Institute for Systems and Innovation...

Plesser, S.; Fisch, M. N.; Gruber, E.; Schlomann, B.

229

Mineralogy and diagenesis of Gulf Coast Tertiary shales Ann-Mag Field, Brooks County, Texas  

E-Print Network (OSTI)

basins containing sediments of the same age (Bruce, 19S4). Shale dehydration and subsequent fluid movement has also been proposed as a mechanism to redistribute ions and form cements ( Towe, 1962; Boles and pranks, 1979) and authi genic minerals... composition with increasing depth of burial provides evidence of systematic diagenetic conversions (Boles and Franks, 1979; Hower et al. , 1976; Perry and Hower, 1972; Weaver and Beck, 1971; Dunoyer De Segonzac, 1970; Burst, 1969; Powers, 1967). When...

Bott, Winston Frederick

1985-01-01T23:59:59.000Z

230

40Ar/39Ar Age of Cretaceous-Tertiary Boundary Tektites from Haiti  

Science Journals Connector (OSTI)

...90G15K obtained with laser system and for...ultrason-ically in dilute HF (-5%) for removal...size for total-fusion and incremental-heating...We determined laser total fusion 'Ar/ 39Ar ages...mean of the four laser-fusion plateau ages at...

G. A. IZETT; G. B. DALRYMPLE; L. W. SNEE

1991-06-14T23:59:59.000Z

231

The effect of solids retention time on tertiary ozonation and carbon adsorption of petrochemical wastewaters  

E-Print Network (OSTI)

and biochemical oxygen demands were measured before and after ozaontion as well as the amount of ozone consumed. Non-adsorbable COD was measured and a comparison of ozonized and unozonized wastewater made. BOD concentration rose after ozonation, but decreased... of solids retention time on nonadsorbable COD, with and without ozonation. 39 LIST OF TABLES Table Page Biochemical and chemical oxygen demand data. COD removal and ozone consumption data 21 26 iVon-adsorbable COD data for bio-oxidized effluent. . 3O...

Buys, Ronald Earl

2012-06-07T23:59:59.000Z

232

Yoon et al. 1 Research Article: Tertiary Endosymbiosis Driven Genome Evolution in  

E-Print Network (OSTI)

apoprotein; PsbD, photosystem II D2 reaction center protein; PsbO, oxygen-evolving enhancer protein 1 MBE, 2 and Debashish Bhattacharya 1 * 1 Department of Biological Sciences and Roy J. Carver Center, NOAA National Ocean Service, Center for Coastal Environmental Health and Biomolecular Research

Bhattacharya, Debashish

233

Calcareous nannofossils from the uppermost Cretaceous and the lowermost Tertiary of central Texas  

E-Print Network (OSTI)

noflagellates, successively dominate the nanno- fossil assemblage immed1ately above the boundary. The opportunistic of small placolith species, such as Cruci lacolithus sp. cf. C. primus, C ocl la 11th p I, else t p. f. I!. ~di h d T wef s p tat, hl h t lty... yl ld t p dly I I s m I Pal o nannoflora. This boundary succession is nearly ident1cal to the boundary succession documented in detail 1n Spain and 1s most reasonably inter- preted as representing a continuous sect1on because there is no ev1dence...

Jiang, Ming-Jung

2012-06-07T23:59:59.000Z

234

An investigation into student academic help seeking behaviours in a tertiary institution's learning support centre.  

E-Print Network (OSTI)

??The majority of academic help seeking studies worldwide have predominantly used the quantitative paradigm and have been undertaken in the secondary and primary sector. This… (more)

Protheroe, Mervyn

2009-01-01T23:59:59.000Z

235

Late Tertiary/Quaternary volcanics of southern Costa Rica and northern Panama  

SciTech Connect

The recent tectonic evolution of the Isthmus of Panama is marked by a complexity imparted by a subduction zone - magmatic arc, a transform plate boundary, and the attempted subduction of an aseismic ridge. In northern Panama andesites form the morphologically young Chiriqui stratovolcano, while in southern Costa Rica they are found interbedded with thick lahars. Two groups of andesites occur in the region. One is low in Si and K (Group I); the other high in Si and K (Group II). The Panamanian andesites belong to both the groups, while Costa Rican andesites are restricted to Group II. Group I andesites are glassy, plagioclase-phyric (An45 rims), and contain abundant augite (Wo46En46Fs8) and magnetite. Rare, resorbed olivine (Fo82) and amphibole are occasionally observed. The Group II andesites have similar mineralogy but also contain abundant pargasitic hornblende and minor orthopyroxene or pigeonite. Xenoliths are common in the Group II andesites of Chiriqui Volcano. Two types of xenoliths are recognized. Cumulate-textured, hornblende gabbro xenoliths vary from nearly pure plagioclase to nearly pure amphibole. These gabbroic xenoliths contain plagioclase (An90 cores to An53 rims), augite, and pargasitic hornblende often displaying the same reaction products as found in the andesites. These xenoliths are interpreted as cognate. These andesites are all characterized by high alkalis and alkali earths; Group II have over 1500 ppm Ba and 1000 ppm Sr. They are apparently produced by partial melting of a highly metasomatised mantle followed by high-pressure fractionation dominated by hornblende.

Roy, A.; Byerly, G.R.

1985-01-01T23:59:59.000Z

236

1208 Organometallics1988,7,1208-1213 Copper(I) Alkyls. Synthesis and Characterization of Tertiary  

E-Print Network (OSTI)

-Champaign, Urbana, Illinois 61801 Received December 28. 1986 Alkylation of copper(I1)acetate reflections and 62 variables. Introduction Lithium dialkylcuprates, LiCuR2,are used extensively in organic

Girolami, Gregory S.

237

Application of a moving bed biofilm reactor for tertiary ammonia treatment in high temperature industrial wastewater  

E-Print Network (OSTI)

industrial wastewater Jennifer L. Shore a,b , William S. M'Coy b , Claudia K. Gunsch a , Marc A. Deshusses a 2012 Available online 17 February 2012 Keywords: Moving bed biofilm reactor Industrial wastewater and industrial wastewater. No biotreatment was observed at 45 °C, although effective nitrification was rapidly

238

Palaeobotanical evidence for a June 'impact winter' at the Cretaceous/Tertiary boundary  

Science Journals Connector (OSTI)

... , well preserved palynomorphs, 91% of which are one type of fern spore. Near Teapot Dome, 100 km west of the Dogie Creek site, the fern spike also occurs ... has physical evidence of early fallout from bolide impact. But detailed palaeobotanical analysis of the Teapot Dome section (Fig. 2), which is the only western interior section that preserves ...

Jack A. Wolfe

1991-08-01T23:59:59.000Z

239

Petrophysical and sedimentological evaluation of the Tertiary sandstones of Barua-Motatan, Eastern Zulia  

SciTech Connect

The combined application of conventional well logs such as resistivity, gamma ray, neutron density and sonic, and specialized logs such as acoustic image and analysis of fluid and rotary coring tool samples are excellent means of evaluating reservoir rock quality, fluid saturations, and hole conditions. This paper describes the application of such a technique and presents the results thereof of reservoir characterization as applied to an exploration well PAA-1X in the eastern coast of the Maracaibo Lake, Venezuela. The PAA-1X well was drilled on the flank of a monocline west of Mene Grande fault near the border of Mene Grande field to explore the Misca Formation of Eocene age. Intermediate and Basal Pauji sandstones were not present in PAA-1X well, contrary to our expectations. The similarity of well logs and geological columns with an earlier exploration well, Tom-3X, confirmed this finding. The sandstones are medium to fine grained, with porosities of 5-21% and permeabilities of 0.02-0.8 md. The acoustic image log shows an ovalness of the hole, a characteristic typical of silty and shaly formations. The interpretation with the aforementioned tools indicates that the exploratory well has very few thin productive intervals and is therefore likely to be deemed uneconomic. This is corroborated by the DST of the upper part of the Misoa Formation that produced only water. The study does indicate that this set of tools can be used very effectively in an integrated manner to accurately assess and evaluate prospects.

Carmona, R.; Mederos, S. [Maraven S.A., Caracas (Venezuela)

1996-08-01T23:59:59.000Z

240

E-Print Network 3.0 - african tertiary institution Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

and Medicine 3 GRADUATE STUDY IN AFRICAN AND AFRICAN-AMERICAN STUDIES "...We are where Africa, Summary: GRADUATE STUDY IN AFRICAN AND AFRICAN-AMERICAN STUDIES "...We are where...

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

E-Print Network 3.0 - african tertiary teaching Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

and Medicine 2 GRADUATE STUDY IN AFRICAN AND AFRICAN-AMERICAN STUDIES "...We are where Africa, Summary: :www.ku.eduafs. MeganMcAteeKUUniversityRelations Professor Elizabeth...

242

Late Tertiary paleomagnetic data from Leyte, Philippines: implications for Philippine fault zone motion  

E-Print Network (OSTI)

= 20. 1' (oss ? 6. 6', le ? 29. 9) and a paleomagnetic pole A ? 89. 0" N, P ? 10. 4'E (Ass ? 4. 8', K ? 55. 3). Eight early Neogene sites (3 normal polarity and 5 reversed polarity) give a mean direction D = 23. 2', I = 13. 9' (oss ? 9. 3', k = 36.... 2) and a paleomagnetic pole A = 66. 5'N, 6 = 220. 5'E (Ass ? 7. 1', It = 62. 0). The late Veogene pole is indistinguishable at the 95% confidence level from published Plio-Pleistocene poles from the entire Philippines and the late Miocene pole...

Cole, Jay Timothy

1988-01-01T23:59:59.000Z

243

Hydrogeologic characterization of the cretaceous-tertiary Coastal Plain sequence at the Savannah River Site  

SciTech Connect

Several hydrostratigraphic classification schemes have been devised to describe the hydrogeology at the Savannah River Site SRS. Central to these schemes is the one-to-one fixed relationship between the hydrostratigraphic units and the lithostratigraphic units currently favored for the Site. This fixed relationship has proven difficult to apply in studies of widely separated locations at the Site due to the various facies observed in the updip Coastal Plain sequence. A detailed analysis and synthesis of the geophysical, core, and hydrologic data available from more than 164 deep wells from 23 cluster locations both on the Site and in the surrounding region was conducted to provide the basis for a hydrostratigraphic classification scheme which could be applied to the entire SRS region. As a result, an interim hydrostratigraphic classification was developed that defines the regional hydrogeologic characteristics of the aquifers underlying the Site (Aadland et al., 1990). The hydrostratigraphic code accounts for and accommodates the rapid lateral variation in lithofacies observed in the region, and eliminates all formal'' connection between the hydrostratigraphic nomenclature and the lithostratigraphic nomenclature. The code is robust and can be made as detailed as is needed to characterize the aquifer units and aquifer zones described in Site-specific studies. 15 refs., 2 figs.

Aadland, R.K.

1990-01-01T23:59:59.000Z

244

Health Citizenship: Essays in Social Medicine and Biomedical Politics  

E-Print Network (OSTI)

Place (London, Routledge, 2006) Hacking, I. , The Taming ofof science, Ian Hacking, identified the institutionalizationHealth Citizenship Hacking that the institutionalization of

Porter, Dorothy PhD

2011-01-01T23:59:59.000Z

245

Rule by Aesthetics: World-Class City Making in Delhi  

E-Print Network (OSTI)

Oxford University Press. Hacking, I. (1990). The Taming ofCambridge University Press. Hacking, I. (1992). Statisticalnumbers,” to borrow Ian Hacking’s phrase? when there is no “

Ghertner, David Asher

2010-01-01T23:59:59.000Z

246

Fixing famine : the politics of information in famine early warning  

E-Print Network (OSTI)

World Food Programme. Hacking, I. (1990) The Taming ofCambridge University Press. Hacking, I. (1991). How shouldsee Desrosières (1998), Hacking (1990) and Porter (1995),

Burg, Suzanne M. M.

2008-01-01T23:59:59.000Z

247

The Sanitized City and Other Urban Myths: Fantasies of Risk and Illness in the Twentieth Century Metropolis  

E-Print Network (OSTI)

New York: Routledge, 94) Hacking, Ian. Rewriting the Soul:University Press, 1995. 95) Hacking, Ian. The Taming ofto determine. Ian Hacking tackles a similar problem in his

Youssef, David

2012-01-01T23:59:59.000Z

248

@Title = Definitions of Petroleum Products and Other Terms  

U.S. Energy Information Administration (EIA) Indexed Site

Definitions of Petroleum Products and Other Terms (Revised January 2010) Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH 3 - (CH 2 )n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usually refers to the high octane product from alkylation units. This alkylate is used in blending high octane gasoline. Alkylation. A refining process for chemically combining isobutane with olefin hydrocarbons (e.g., propylene, butylene) through the control of temperature and pressure in the presence of an acid catalyst, usually sulfuric acid or hydrofluoric acid. The product, alkylate, an

249

MTBE Production Economics  

Gasoline and Diesel Fuel Update (EIA)

MTBE Production MTBE Production Economics Tancred C. M. Lidderdale Contents 1. Summary 2. MTBE Production Costs 3. Relationship between price of MTBE and Reformulated Gasoline 4. Influence of Natural Gas Prices on the Gasoline Market 5. Regression Results 6. Data Sources 7. End Notes 1. Summary Last year the price of MTBE (methyl tertiary butyl ether) increased dramatically on two occasions (Figure 1) (see Data Sources at end of article.): 1. Between April and June 2000, the price (U.S. Gulf Coast waterborne market) of MTBE rose from $1.00 per gallon to over $1.60 per gallon. This represented an increase in the price premium for MTBE over the wholesale price of conventional gasoline from its normal (1995 though 2000 average) $0.26 per gallon to $0.60 per gallon. The MTBE

250

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Total Stocks Total Stocks Definitions Key Terms Definition All Other Motor Gasoline Blending Components Naphthas (e.g. straight-run gasoline, alkylate, reformate, benzene, toluene, xylene) used for blending or compounding into finished motor gasoline. Includes receipts and inputs of Gasoline Treated as Blendstock (GTAB). Excludes conventional blendstock for oxygenate blending (CBOB), reformulated blendstock for oxygenate blending, oxygenates (e.g. fuel ethanol and methyl tertiary butyl ether), butane, and pentanes plus. Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels per short ton.

251

Annual Energy Outlook 2005-Acronyms  

Gasoline and Diesel Fuel Update (EIA)

AD AD Associated-dissolved (natural gas) AEO2004 Annual Energy Outlook 2004 AEO2005 Annual Energy Outlook 2005 Altos Altos Partners AMT Alternative Minimum Tax ANWR Arctic National Wildlife Refuge Btu British thermal unit CAFE Corporate average fuel economy CAMR Clean Air Mercury Rule CARB California Air Resources Board CBECS Commercial Buildings Energy Consumption Survey (EIA) CBO Congressional Budget Office CCCC Climate Change Credit Corporation CH 4 Methane CHP Combined heat and power CO 2 Carbon dioxide CTL Coal-to-liquids DB Deutsche Bank, A.G. E85 Fuel containing a blend of 70 to 85 percent ethanol and 30 to 15 percent gasoline by volume EEA Energy and Environmental Analysis, Inc. EIA Energy Information Administration EPA U.S. Environmental Protection Agency EPACT Energy Policy Act of 1992 ETBE Ethyl tertiary butyl ether EVA Energy Ventures Analysis, Incorporated FERC

252

Word Pro - Untitled1  

U.S. Energy Information Administration (EIA) Indexed Site

chemical compounds composed of chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group: CH 3 -(CH 2 )n-OH (e.g., metha- nol, ethanol, and tertiary butyl alcohol). See Fuel Ethanol. Alternative Fuel: Alternative fuels, for transportation applications, include the following: methanol; denatured ethanol, and other alcohols; fuel mixtures contain- ing 85 percent or more by volume of methanol, denatured ethanol, and other alco- hols with motor gasoline or other fuels; natural gas; liquefied petroleum gas (propane); hydrogen; coal-derived liquid fuels; fuels (other than alcohol) derived from biological materials (biofuels such as soy diesel fuel); electricity (including electricity from solar energy); and "... any other fuel the Secretary determines, by

253

Status and Impact of State MTBE Bans  

Gasoline and Diesel Fuel Update (EIA)

Status and Impact of State MTBE Bans Status and Impact of State MTBE Bans Background As a result of the Clean Air Act Amendments of 1990 (CAAA90), the year-round use of reformulated gasoline (RFG) has been required in cities with the worst smog problems since 1995 (Figure 1). One of the requirements of RFG specified by CAAA90 is a 2- percent oxygen requirement, which is met by blending "oxygenates," 1 including methyl tertiary butyl ether (MTBE) and ethanol, into the gasoline. MTBE is the oxygenate used in almost all RFG outside of the Midwest. Ethanol is currently used in the Midwest as an oxygenate in RFG and as an octane booster and volume extender in conventional gasoline. Several years ago, MTBE was detected in water supplies scattered throughout the country, but predominantly in areas using RFG. MTBE from RFG was apparently

254

MTBE, Oxygenates, and Motor Gasoline  

Gasoline and Diesel Fuel Update (EIA)

MTBE, Oxygenates, and MTBE, Oxygenates, and Motor Gasoline Contents * Introduction * Federal gasoline product quality regulations * What are oxygenates? * Who gets gasoline with oxygenates? * Which areas get MTBE? * How much has been invested in MTBE production capacity? * What does new Ethanol capacity cost? * What would an MTBE ban cost? * On-line information resources * Endnotes * Summary of revisions to this analysis Introduction The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an

255

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Weekly Supply Estimates Weekly Supply Estimates Definitions Key Terms Definition All Other Motor Gasoline Blending Components Naphthas (e.g. straight-run gasoline, alkylate, reformate, benzene, toluene, xylene) used for blending or compounding into finished motor gasoline. Includes receipts and inputs of Gasoline Treated as Blendstock (GTAB). Excludes conventional blendstock for oxygenate blending (CBOB), reformulated blendstock for oxygenate blending, oxygenates (e.g. fuel ethanol and methyl tertiary butyl ether), butane, and pentanes plus. Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels per short ton.

256

Annual Energy Outlook 2000 - Acronyms  

Gasoline and Diesel Fuel Update (EIA)

Homepage Homepage ACEEE American Council for an Energy-Efficient Economy AD Associated-dissolved (natural gas) AEO Annual Energy Outlook AGA American Gas Association ANWR Arctic National Wildlife Refuge API American Petroleum Institute BRP Blue Ribbon Panel Btu British thermal unit CAAA90 Clean Air Act Amendments of 1990 CARB California Air Resources Board CCAP Climate Change Action Plan CDM Clean Development Mechanism CECA Comprehensive Electricity Competition Act CIDI Compression ignition direct injection CO Carbon monoxide DBAB Deutsche Banc Alex. Brown DOE U.S. Department of Energy DRI Standard & Poor’s DRI EIA Energy Information Administration EOR Enhanced oil recovery EPA U.S. Environmental Protection Agency EPACT Energy Policy Act of 1992 ETBE Ethyl tertiary butyl ether

257

Appendix A - Acronyms  

NLE Websites -- All DOE Office Websites (Extended Search)

A - ACRONYMS A - ACRONYMS AASHTO American Association of State Highway and Transportation Officials CNG Compressed Natural Gases CVO Commercial Vehicle Operation DOE Department of Energy DOT Department of Transportation E85 85% Ethanol, 15% Gasoline EPA Environmental Protection Agency ExFIRS Excise Files Information Retrieval System ExSTARS Excise Summary Terminal Activity Reporting System FHWA Federal Highway Administration FTA Federation of Tax Administrators GAO General Accounting Office HTF Highway Trust Fund IFTA International Fuel Tax Agreement IM Interstate Maintenance IRS Internal Revenue Service LNG Liquid Natural Gases LPG Liquefied Petroleum Gases M85 85% Methanol, 15% Gasoline MTBE Methyl Tertiary Butyl Ether NHS National Highway System ORNL Oak Ridge National Laboratory STP Surface Transportation Program

258

Word Pro - Untitled1  

U.S. Energy Information Administration (EIA) Indexed Site

chemical chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH(3)-(CH(2)) n -OH (e.g., methanol, ethanol, and tertiary butyl alcohol). See Fuel Ethanol. Alternative Fuel: Alternative fuels, for transportation applications, include the following: methanol; denatured ethanol, and other alcohols; fuel mixtures containing 85 percent or more by volume of methanol, denatured ethanol, and other alcohols with motor gasoline or other fuels; natural gas; liquefied petroleum gas (propane); hydro- gen; coal-derived liquid fuels; fuels (other than alcohol) derived from biological materials (biofuels such as soy diesel fuel); electricity (including electricity from solar

259

Total Blender Net Input of Petroleum Products  

U.S. Energy Information Administration (EIA) Indexed Site

Input Input Product: Total Input Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquid Petroleum Gases Normal Butane Isobutane Other Liquids Oxygenates/Renewables Methyl Tertiary Butyl Ether (MTBE) Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Unfinished Oils (net) Unfinished Oils, Naphthas and Lighter Unfinished Oils, Kerosene and Light Gas Oils Unfinished Oils, Heavy Gas Oils Residuum Motor Gasoline Blending Components (MGBC) (net) MGBC - Reformulated MGBC - Reformulated - RBOB MGBC - Reformulated, RBOB for Blending w/ Alcohol MGBC - Reformulated, RBOB for Blending w/ Ether MGBC - Reformulated, GTAB MGBC - Conventional MGBC - Conventional, CBOB MGBC - Conventional, GTAB MGBC - Other Conventional Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

260

Motor Gasoline Outlook and State MTBE Bans  

Gasoline and Diesel Fuel Update (EIA)

Motor Gasoline Outlook Motor Gasoline Outlook and State MTBE Bans Tancred Lidderdale Contents 1. Summary 2. MTBE Supply and Demand 3. Ethanol Supply 4. Gasoline Supply 5. Gasoline Prices A. Long-Term Equilibrium Price Analysis B. Short-Term Price Volatility 6. Conclusion 7. Appendix A. Estimating MTBE Consumption by State 8. Appendix B. MTBE Imports and Exports 9. Appendix C. Glossary of Terms 10. End Notes 11. References 1. Summary The U.S. is beginning the summer 2003 driving season with lower gasoline inventories and higher prices than last year. Recovery from this tight gasoline market could be made more difficult by impending State bans on the blending of methyl tertiary butyl ether (MTBE) into gasoline that are scheduled to begin later this year. Three impending State bans on MTBE blending could significantly affect gasoline

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Imports & Exports Imports & Exports Definitions Key Terms Definition All Other Motor Gasoline Blending Components Naphthas (e.g. straight-run gasoline, alkylate, reformate, benzene, toluene, xylene) used for blending or compounding into finished motor gasoline. Includes receipts and inputs of Gasoline Treated as Blendstock (GTAB). Excludes conventional blendstock for oxygenate blending (CBOB), reformulated blendstock for oxygenate blending, oxygenates (e.g. fuel ethanol and methyl tertiary butyl ether), butane, and pentanes plus. Barrel A unit of volume equal to 42 U.S. gallons. Conventional Blendstock for Oxygenate Blending (CBOB) Motor gasoline blending components intended for blending with oxygenates to produce finished conventional motor gasoline. Conventional Gasoline Finished motor gasoline not included in the oxygenated or reformulated gasoline categories. Excludes reformulated gasoline blendstock for oxygenate blending (RBOB) as well as other blendstock.

262

PSADEFS.CHP:Corel VENTURA  

Gasoline and Diesel Fuel Update (EIA)

Definitions Definitions of Petroleum Products and Other Terms Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH 3 - (CH 2 )n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usu- ally refers to the high octane product from alkylation units. This alkylate is used in blending high octane gaso- line. Alkylation. A refining process for chemically combining isobutane with olefin hydrocarbons (e.g., propylene, buty- lene) through the control of temperature and pressure in the presence of an acid catalyst, usually sulfuric acid or hydrofluoric acid. The product, alkylate, an isoparaffin, has high octane value and is blended with motor and aviation gasoline to improve the antiknock

263

Eliminating MTBE in Gasoline in 2006  

Gasoline and Diesel Fuel Update (EIA)

02/22/2006 02/22/2006 Eliminating MTBE in Gasoline in 2006 Summary In 2005, a number of petroleum companies announced their intent to remove methyl tertiary-butyl ether (MTBE) from their gasoline in 2006. Companies' decisions to eliminate MTBE have been driven by State bans due to water contamination concerns, continuing liability exposure from adding MTBE to gasoline, and perceived potential for increased liability exposure due to the elimination of the oxygen content requirement for reformulated gasoline (RFG) included in the Energy Policy Act of 2005. EIA's informal discussions with a number of suppliers indicate that most of the industry is trying to move away from MTBE before the 2006 summer driving season. Currently, the largest use of MTBE is in RFG consumed on the East Coast outside of

264

Annual Energy Outlook 1999 - Acronyms  

Gasoline and Diesel Fuel Update (EIA)

acronyms.gif (3491 bytes) acronyms.gif (3491 bytes) AD - Associated/dissolved natural gas AEO98 - Annual Energy Outlook 1998 AEO99 - Annual Energy Outlook 1999 AFVs - Alternative-fuel vehicles AGA - American Gas Association API - American Petroleum Institute BTAB - BT Alex Brown CAAA90 - Clean Air Act Amendments of 1990 CCAP - Climate Change Action Plan CDM - Clean Development Mechanism CFCs - Chlorofluorocarbons CNG - Compressed natural gas CO - Carbon monoxide CO2 - Carbon dioxide DOE - U.S. Department of Energy DRI - DRI/McGraw-Hill EIA - Energy Information Administration EOR - Enhanced oil recovery EPA - U.S. Environmental Protection Agency EPACT - Energy Policy Act of 1992 ETBE - Ethyl tertiary butyl ether EU - European Union FERC - Federal Energy Regulatory Commission GDP - Gross domestic product

265

Total Refinery Net Input of Crude Oil and Petroleum Products  

U.S. Energy Information Administration (EIA) Indexed Site

Input Input Product: Total Crude Oil & Petroleum Products Crude Oil Natural Gas Plant Liquids Pentanes Plus Liquefied Petroleum Gases Normal Butane Isobutane Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Hydrogen Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils (net) Unfinished Oils, Naphthas and Lighter Unfinished Oils, Kerosene and Light Gas Oils Unfinished Oils, Heavy Gas Oils Residuum Motor Gasoline Blending Components (MGBC) (net) MGBC - Reformulated MGBC - Reformulated - RBOB MGBC - Reformulated, RBOB for Blending w/ Alcohol MGBC - Reformulated, RBOB for Blending w/ Ether MGBC - Conventional MGBC - CBOB MGBC - Conventional, GTAB MGBC - Other Conventional Aviation Gasoline Blending Components (net) Alaskan Crude Oil Receipts Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

266

Glossary - U.S. Energy Information Administration (EIA)  

U.S. Energy Information Administration (EIA) Indexed Site

petroleum petroleum Alcohol: The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH(3)-(CH(2))n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate: The product of an alkylation reaction. It usually refers to the high-octane product from alkylation units. This alkylate is used in blending high octane gasoline. Alkylation: A refining process for chemically combining isobutane with olefin hydrocarbons (e.g., propylene, butylene) through the control of temperature and pressure in the presence of anacid catalyst, usually sulfuric acid or hydrofluoric acid. The product alkylate, an isoparaffin, has high octane value and is blended with motor and aviation gasoline to

267

Assessment of Summer RBOB Supply for NY & CT  

Gasoline and Diesel Fuel Update (EIA)

Update of Summer Reformulated Gasoline Supply Update of Summer Reformulated Gasoline Supply Assessment for New York and Connecticut May 5, 2004 In October 2003, EIA published a review of the status of the methyl tertiary butyl ether (MTBE) ban transition in New York (NY) and Connecticut (CT) 1 that noted significant uncertainties in gasoline supply for those States for the summer of 2004. To obtain updated information, EIA spoke to major suppliers to the two States over the past several months as the petroleum industry began the switch from winter- to summer-grade gasoline. As discussed on our earlier report, the NY and CT bans on MTBE mainly affect reformulated gasoline (RFG), which in recent years has been provided by domestic refineries on the East Coast (PADD 1) and imports. Our recent findings indicate that

268

Catalytic distillation process  

DOE Patents (OSTI)

A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

Smith, L.A. Jr.

1982-06-22T23:59:59.000Z

269

Catalytic distillation process  

DOE Patents (OSTI)

A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

Smith, Jr., Lawrence A. (Bellaire, TX)

1982-01-01T23:59:59.000Z

270

Refinery & Blenders Net Input of Crude Oil  

U.S. Energy Information Administration (EIA) Indexed Site

Input Input Product: Total Crude Oil & Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane Normal Butane Isobutane Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Hydrogen Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils (net) Unfinished Oils, Naphthas and Lighter Unfinished Oils, Kerosene and Light Gas Oils Unfinished Oils, Heavy Gas Oils Residuum Motor Gasoline Blending Components (MGBC) (net) MGBC - Reformulated MGBC - Reformulated - RBOB MGBC - Reformulated, RBOB for Blending w/ Alcohol MGBC - Reformulated, RBOB for Blending w/ Ether MGBC - Reformulated, GTAB MGBC - Conventional MGBC - CBOB MGBC - Conventional, GTAB MGBC - Other Conventional Aviation Gasoline Blending Components (net) Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

271

Process for producing high purity isoolefins and dimers thereof by dissociation of ethers  

DOE Patents (OSTI)

Alkyl tertiary butyl ether or alkyl tertiary amyl ether is dissociated by vapor phase contact with a cation acidic exchange resin at temperatures in the range of 150 to 250 F at LHSV of 0.1 to 20 to produce a stream consisting of unreacted ether, isobutene or isoamylene and an alcohol corresponding to the alkyl radical. After the alcohol is removed, the ether/isoolefin stream may be fractionated to obtain a high purity isoolefin (99+%) or the ether/isoolefin stream can be contacted in liquid phase with a cation acidic exchange resin to selectively dimerize the isoolefin in a highly exothermic reaction, followed by fractionation of the dimerization product to produce high purity diisoolefin (97+%). In the case where the alkyl is C[sub 3] to C[sub 6] and the corresponding alcohol is produced on dissociation of the ether, combined dissociation-distillation may be carried out such that isoolefin is the overhead product and alcohol the bottom. 2 figs.

Smith, L.A. Jr.; Jones, E.M. Jr.; Hearn, D.

1984-05-08T23:59:59.000Z

272

CRC fuel rating program: road octane performance of oxygenates in 1982 model cars  

SciTech Connect

Because of the widespread interest in the use of alcohols and ethers as gasoline blending components, this program was conducted to evaluate the effects of several oxygenates on gasoline octane performance and to evaluate the effects of car design features such as engine and transmission type. Five oxygenates were evaluated at two nominal concentrations, 5 and 10 volume%, at both regular- and premium-grade octane levels: methanol (MeOH), ethanol (ETOH), isopropanol (IPA), tertiary butanol (TBA), and methyl tertiary butyl ether (MTBE). A blend of 5% MeOH and 5 percent TBA was also tested at both octane levels. Twenty-eight unleaded fuels, including four hydrocarbon fuels, two hydrocarbon fuels plus toluene, and twenty-two oxygenated fuels, were rated in duplicate in thirty-eight cars using the Modified Uniontown Technique (CRC Designation F-28-75 described in Appendix C), plus some additional instructions. All testing was done on chassis dynamometers. Ratings were obtained at full throttle with all thirty-eight cars, and at the most critical part-throttle condition (occurring with manifold vacuum of 4 in. Hg (13.5 kPa) or greater above the full-throttle vacuum) with nine cars.

Not Available

1985-07-01T23:59:59.000Z

273

Molecular organization in the native state of woody tissue: Studies of tertiary structure using the Raman microprobe solid state 13C NMR and biomimetic tertiary aggregates. Progress report, July 1, 1989--June 30, 1993  

SciTech Connect

We have previously shown that all relatively pure plant and bacterial celluloses are, in their native states, composites of two lattice forms, I{sub {alpha}} and I{sub {beta}}, and that the two forms possess molecular chains in the same conformations but with different hydrogen bonding patterns. In the current period we have demonstrated that in higher plant cell wall matrices, the hemicelluloses are likely to have a regulatory function during the aggregation of cellulose. Different hemicelluloses appear to influence the aggregation in different ways. We have also developed preliminary evidence indicating the hemicelluloses may have a protective function against the action of some cellulolytic enzymes. The specific accomplishments during the current period are detailed. Demonstration that hemicelluloses present during biogenesis can transform bacterial cellulose into a cellulose typical of higher plant celluloses, and that each hemicellulose has a different effect on the pattern of aggregation. Evidence is presented that the hemicelluloses may limit the action of certain cellulolytic enzymes, suggesting that their function may go beyond regulation to include passive resistance to cellulolytic pathogens. Enhancing the potential of the Raman microprobe technique for mapping variability of lignin in the cell wall by identifying the contribution of the different substructures of lignin to the intensity of the key band in the Raman spectrum of lignin. Mapping of the variability of lignin across two cell wall sections. The mappings have convoluted within them both composition and concentration, but they demonstrate the potential of the method and point to the improvements we are now making so as to distinguish between variability of concentration and variability of composition.

Atalla, R.H.

1993-12-31T23:59:59.000Z

274

GEOLOGY, TAPHONOMY, AND PALEOECOLOGY OF A UNIQUE UPPER CRETACEOUS BONEBED NEAR THE CRETACEOUS-TERTIARY BOUNDARY IN SOUTH DAKOTA  

E-Print Network (OSTI)

remains……………………………..100 Figure 3.36 Fused hadrosaur caudal vertebrae with embedded theropod tooth………………..104 Figure 3.37 Pristine bone compared to one with “sun cracks”…………………………………105 Figure 3.38 Graph comparing number of specimens collected...

DePalma, Robert Anthony

2010-04-27T23:59:59.000Z

275

Tertiary development of heavy oil sands through thermal stimulation in the Wilmington Oil Field, California: A geological perspective  

SciTech Connect

In 1995, a DOE cost share project was initiated to extend thermal recovery in the Tar Zone, Fault Block 11 of the West Wilmington Oil Field, California. The project involved the collection of old oil well data and the construction of a modern digital data base in order to develop a deterministic geological model. The plan was to rigorously define the geology such that horizontal wells could be accurately placed within the sands containing heavy oil to facilitate gravity drainage. A detailed deterministic geological model was constructed using a state of the art 3D mapping and modeling package. Beginning in July, 1995, five observation wells were drilled. Data inconsistencies were revealed when core hole OB2-003 was drilled. It was discovered that the data used to make the maps was corrupted; as a result, the predicted coring point was missed by more than 20'. Significant modifications to the data base were required due to inaccurate subsidence corrections in the original data set. Horizontal wells were then laid out based on the revised data and the geological model was completely reconstructed. Detailed cross sections extracted from the model were use for geosteering. These cross sections proved to be highly accurate and five more wells are now planned for the target sands. This detailed deterministic model will be further refined and combined with our geostatistical mode for geological control in an advanced reservoir simulator. If successful, the thermal stimulation project will be expanded to other fault blocks.

Clarke, D.D. (Department of Oil Properties, Long Beach, CA (United States)); Henry, M.J.; Strehle, R.W. (Dept. of Oil Properties, Long Beach, CA (United States))

1996-01-01T23:59:59.000Z

276

Tertiary development of heavy oil sands through thermal stimulation in the Wilmington Oil Field, California: A geological perspective  

SciTech Connect

In 1995, a DOE cost share project was initiated to extend thermal recovery in the Tar Zone, Fault Block 11 of the West Wilmington Oil Field, California. The project involved the collection of old oil well data and the construction of a modern digital data base in order to develop a deterministic geological model. The plan was to rigorously define the geology such that horizontal wells could be accurately placed within the sands containing heavy oil to facilitate gravity drainage. A detailed deterministic geological model was constructed using a state of the art 3D mapping and modeling package. Beginning in July, 1995, five observation wells were drilled. Data inconsistencies were revealed when core hole OB2-003 was drilled. It was discovered that the data used to make the maps was corrupted; as a result, the predicted coring point was missed by more than 20`. Significant modifications to the data base were required due to inaccurate subsidence corrections in the original data set. Horizontal wells were then laid out based on the revised data and the geological model was completely reconstructed. Detailed cross sections extracted from the model were use for geosteering. These cross sections proved to be highly accurate and five more wells are now planned for the target sands. This detailed deterministic model will be further refined and combined with our geostatistical mode for geological control in an advanced reservoir simulator. If successful, the thermal stimulation project will be expanded to other fault blocks.

Clarke, D.D. [Department of Oil Properties, Long Beach, CA (United States); Henry, M.J.; Strehle, R.W. [Dept. of Oil Properties, Long Beach, CA (United States)

1996-12-31T23:59:59.000Z

277

Outbreak of Pichia anomala Infection in the Pediatric Service of a Tertiary-Care Center in Northern India  

Science Journals Connector (OSTI)

...intensified hospital-wide health education campaign with poster displays, formal lectures...be controlled after a health education campaign to improve hand-washing...Postgraduate Institute of Medical Education and Research, Chandigarh 160012...

A. Chakrabarti; K. Singh; A. Narang; S. Singhi; R. Batra; K. L. N. Rao; P. Ray; S. Gopalan; S. Das; V. Gupta; A. K. Gupta; S. M. Bose; M. M. McNeil

2001-05-01T23:59:59.000Z

278

Healthcare associated bloodstream infections – secular trends of 8 years hospital-wide surveillance in a tertiary care university hospital  

Science Journals Connector (OSTI)

Introduced 1995 in acute care, prospective and systematic BSI surveillance at the University of Geneva hospitals was extended to a hospital-wide survey in 2003. Positive blood culture...

M-N Chraiti; W Zingg; V Sauvan; D Pittet

2011-06-01T23:59:59.000Z

279

P261: Study of hospital associated infections (HAI) at tertiary hospital in India; economic implication for developing countries  

Science Journals Connector (OSTI)

Over 1.4 million people worldwide suffer from HAI at any given time. Hospital wide prevalence of HAI varies from 5....1...]. This study focuses on the economic consequences and social burden of HAI cases in a ter...

S Satpathy; A Chaudhry; SK Gupta; A Kapil

2013-06-01T23:59:59.000Z

280

Volume and accessibility of entrained (solution) methane in deep geopressured reservoirs - tertiary formations of the Texas Gulf Coast. Final report  

SciTech Connect

The objective of this project was to appraise the total volume of in-place methane dissolved in formation waters of deep sandstone reservoirs of the onshore Texas Gulf Coast within the stratigraphic section extending from the base of significant hydrocarbon production (8000 ft)* to the deepest significant sandstone occurrence. The area of investigation is about 50,000 mi/sup 2/. Factors that determine the total methane resource are reservoir bulk volume, porosity, and methane solubility; the latter is controlled by the temperature, pressure, and salinity of formation waters. Regional assessment of the volume and the distribution of potential sandstone reservoirs was made from a data base of 880 electrical well logs, from which a grid of 24 dip cross sections and 4 strike cross sections was constructed. Solution methane content in each of nine formations or divisions of formations was determined for each subdivision. The distribution of solution methane in the Gulf Coast was described on the basis of five reservoir models. Each model was characterized by depositional environment, reservoir continuity, porosity, permeability, and methane solubility.

Gregory, A.R.; Dodge, M.M.; Posey, J.S.; Morton, R.A.

1980-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Tunable Energy Transfer Rates via Control of Primary, Secondary, and Tertiary Structure of a Coiled Coil Peptide Scaffold  

Science Journals Connector (OSTI)

Dale J. Wilger †, Stephanie E. Bettis †, Christopher K. Materese †, Maria Minakova †, Garegin A. Papoian *‡, John M. Papanikolas *†, and Marcey L. Waters *† ... M. Kyle Brennaman, Cavan N. Fleming, Cheryl A. Slate, Scafford A. Serron, Stephanie E. Bettis, Bruce W. Erickson, John M. Papanikolas, and Thomas J. Meyer ... M. Kyle Brennaman, Cavan N. Fleming, Cheryl A. Slate, Scafford A. Serron, Stephanie E. Bettis, Bruce W. Erickson, John M. Papanikolas, and Thomas J. Meyer ...

Dale J. Wilger; Stephanie E. Bettis; Christopher K. Materese; Maria Minakova; Garegin A. Papoian; John M. Papanikolas; Marcey L. Waters

2012-06-08T23:59:59.000Z

282

Proportions of coarse and fine clay across the Cretaceous-Tertiary boundary in Milam, Falls, and Travis Counties, Texas  

E-Print Network (OSTI)

and are of little value. It is concluded that the method proposed in this thesis is capable of detecting small differences between clay sampi es at a = ingle locai ity, but prob. bly cannot be used to correlate samples f'rom one locality to another. i&1tlloagh... making dispersion and I'rac- tionation difficult. The efficiency of the X-ray diffraction t, echniques is also improved when these constituents are removed. As a simplified means of comp:rison, the various procedures performed on each sample...

Smith, John Charles

1966-01-01T23:59:59.000Z

283

A Major Meteorite Impact on the Earth 65 Million Years Ago: Evidence from the Cretaceous-Tertiary Boundary Clay  

Science Journals Connector (OSTI)

...and are normally depleted on the terrestrial...ISOTOPIC COMPOSITION OF URANIUM IN CHONDRITIC METEORITES...GRAZING ANIMALS, HEALTH PHYSICS 30 : 345...and are normally depleted on the terrestrial...since Pd is not depleted to the same extent...elements such as uranium in certain meteorites...

R. GANAPATHY

1980-08-22T23:59:59.000Z

284

Fistulotomy in the Tertiary Setting can Achieve High Rates of Fistula Cure with an Acceptable Risk of Deterioration in Continence  

Science Journals Connector (OSTI)

Surgery is the mainstay of treatment of anal fistulas. Low fistulas are often laid open, but higher fistulas present a more difficult problem. Patient choice centres on a compromise between risk of recurrence ...

P. Tozer; S. Sala; V. Cianci; K. Kalmar; G. K. Atkin…

2013-11-01T23:59:59.000Z

285

Stratigraphic and structural analysis of Shannon Sandstone, Teapot Dome field: implications for secondary and tertiary oil recovery  

SciTech Connect

The Department of Energy and Lawrence-Allison Associates have initiated three enhanced oil recovery (EOR) pilot projects in the last 4 years in the Shannon Sandstone at the Teapot Dome field. Performance of these pilot projects has generally been poor. As a result, a reevaluation of the geology for the entire field and for the pilot areas was conducted in an attempt to explain the pilots' performances. Based on core descriptions, conceptual reservoir flow patterns, and post-fireflood coring, only the bar-margin facies was found amenable to fluid displacement processes for oil recovery. This results in 25 million bbl of oil originally in place vs 180 million bbl of oil originally in place as a target for EOR. Stratigraphy alone does not explain the observed production patterns and simulation of the reservoir. Faulting and fracturing are extensive. Based on faults mapped in the in-situ pilot area, 12 to 16 northeast-trending normal faults per mile can be projected. Fracture orientations were obtained by mapping calcareous streaks in the upper and lower Shannon. These orientations confirm directions of premature fluid breakthroughs observed in the pilot projects and in the old East Teapot waterflood. Water resistivities and total dissolved solids measurements, water-cut maps, and daily oil production maps suggest that some faults are partial to total barriers to fluid flow across the field.

Chappelle, H.; Emsurak, G.; Obernyer, S.

1986-08-01T23:59:59.000Z

286

Reconstruction of Tertiary Metasequoia forests. II. Structure, biomass, and productivity of Eocene floodplain forests in the Canadian Arctic  

Science Journals Connector (OSTI)

...estimates of fossil biomass and productivity...Metasequoia had higher wood density than...branchwood and foliar biomass we relied on...closed-canopy plantations. This is a standard...Metasequoia had higher wood density than...branchwood and foliar biomass we relied on...closed-cano-py plantations. This is a standard...

Christopher J. Williams; Arthur H. Johnson; Ben A. LePage; David R. Vann; Tatsuo Sweda

287

Reconstruction of Tertiary Metasequoia forests. I. Test of a method for biomass determination based on stem dimensions  

Science Journals Connector (OSTI)

...crown in the Tanashi plantation. We developed branch...for foliage and branch wood of canopy branches cut from a variety of plantation-grown Metasequoia...the standard for forest biomass calculations (Sprugel...to analysis. Branch wood and foliage dry weights...

Christopher J. Williams; Arthur H. Johnson; Ben A. LePage; David R. Vann; Karen D. Taylor

288

Simultaneous Speciation of Butyl-, Phenyl-, and Cyclohexyltin Compounds in Aqueous Matrices Using Ethylation Followed by Solid-Phase Trace Enrichment, SFE, and GC Determination  

Science Journals Connector (OSTI)

......TCyT), and their degradation products (1,2...the extraction cell had an internal volume...respectively. Flows of fuel gases were 120 mL...into the extraction cell, which contained...butyltin and its degradation products from seawater......

Yong Cai; Josep M. Bayona

1995-03-01T23:59:59.000Z

289

Effect of in-situ bonding system and surface modification of montmorillonite on the properties of butyl rubber/MMT composites  

Science Journals Connector (OSTI)

Isobutylene-isoprene rubber (IIR)/nanoclay composites were prepared by solution intercalation method. Cloisite Na + nanoclays and organo-modified montmorillonite (OMT) Cloisite 10 A .15 A and 20 A were used in this study. The effect of In-situ bonding system HRH (hexametylene tetramine: resorcinol: hydrated silica) on the dispersion of used nanoclays in the rubber matrix were examined by X-ray diffraction and atomic force microscopy (AFM). Characterization of the prepared composites was performed by studying the rheometeric and mechanical properties. The burning out behavior of the nanocomposites with and without the bonding system was also measured.

2012-01-01T23:59:59.000Z

290

Differential Gene Expression To Investigate the Effect of (5Z)-4-Bromo- 5-(Bromomethylene)-3-Butyl-2(5H)-Furanone on Bacillus subtilis  

Science Journals Connector (OSTI)

...PL APO 100/1.4 numerical aperture oil immersion objective (true confocal system...Acad. Sci. USA 91: 5788-5792. 23 Price, C. W. 2002. General stress response...of Chemical Engineering, University of Connecticut, 191 Auditorium Rd., U-3222, Storrs...

Dacheng Ren; Laura A. Bedzyk; Peter Setlow; Dacre F. England; Staffan Kjelleberg; Stuart M. Thomas; Rick W. Ye; Thomas K. Wood

2004-08-01T23:59:59.000Z

291

RELATIONS BETWEEN THE DETECTION OF METHYL TERT-BUTYL ETHER (MTBE) IN SURFACE AND GROUND WATER AND ITS CONTENT IN GASOLINE  

E-Print Network (OSTI)

AND ITS CONTENT IN GASOLINE By Michael J. Moran, Mike J. Halde, Rick M. Clawges and John S. Zogorski U in the United States as an octane enhancer and oxygenate in gasoline. Octane enhancement began in the late 1970's with the phase-out of tetraethyl lead from gasoline. The use of oxygenates was expanded

292

Nationalizing statistics : a comparative study of the development of official statistics during the 20th century in Israel-Palestine and Canada  

E-Print Network (OSTI)

Boston, Beacon Press. Hacking, I. (1987). Prussian NumbersBook MIT Press: 377-393. Hacking, I. (1990). The Taming ofCambridge University Press. Hacking, I. (1992a). Statistical

Leibler, Anat Elza

2008-01-01T23:59:59.000Z

293

Bringing climate change down to earth : science and participation in Canadian and Australian climate change campaigns  

E-Print Network (OSTI)

McCarthy. London: Heinemann. Hacking, Ian. 1986. Making UpStanford University Press. Hacking, Ian. 1990. The Taming ofCambridge University Press. Hacking, Ian. 1995. The Looping

Padolsky, Miriam Elana

2006-01-01T23:59:59.000Z

294

The Cell Phone and the Crowd: Messianic Politics in the Contemporary Philippines  

E-Print Network (OSTI)

16. Tan, “Taming the Cell Phone”; De Quiros, “UndiscoveredOverwhelm Cops. ” The Cell Phone and the Crowd Publicnew or different about The Cell Phone and the Crowd of 16

Rafael, Vicente L.

2003-01-01T23:59:59.000Z

295

ii Ann. SC. math. Qubec, 1988, vol. 12, no 2, pp. 275-285 MOTS CIRCULAIRESET POLYNMES IRRDUCTIBLES  

E-Print Network (OSTI)

~yuto"m~ (en uw wti6.h) im4%fu~6~~ eft: uti- &WLU (i..e. de /tame dominant 1) de de@ n AUA Fq8 #12;278 PREUVE

Reutenauer, Christophe

296

JAPAN’S STRUGGLES CONTINUE  

Science Journals Connector (OSTI)

JAPAN EXPERIENCED progress and setbacks last week in its continuing struggle to recover from the devastating March 11 earthquake and tsunami. Frontline workers at the crippled Fukushima Daiichi Nuclear Power Station again risked their lives to tame ...

BRITT ERICKSON; JEFF JOHNSON; JEAN-FRANÇOIS TREMBLAY

2011-03-28T23:59:59.000Z

297

Anthropology in Madras  

Science Journals Connector (OSTI)

... among the natives pf Southern India, both tame and wild. It has recently beeifi saifi 'that "there will be plenty of money and people available.for anthropological research when ...

EDGAR THURSTON

1898-05-26T23:59:59.000Z

298

8180 Phys. Chem. Chem. Phys., 2011, 13, 81808185 This journal is c the Owner Societies 2011 Cite this: Phys. Chem. Chem. Phys., 2011, 13, 81808185  

E-Print Network (OSTI)

photofragment translational spectroscopy. The tert-butyl radical was produced from flash pyrolysis of azo

Neumark, Daniel M.

299

Home > Greenhouse > Chapters > 8 Pesticides Labeled for Arthropod Control > Table 8.2. Insecticides for control of arthropod pests of ornamentals, listed by product trade name  

E-Print Network (OSTI)

*Lada 2F Magus *Marathon 1G *Marathon 60WP *Marathon II *Mavrik Aquaflow *Menace GC 7.9% Flowable Merlin SG Sanmite ScanMask *Scimitar GC Shuttle O Sirocco Sluggo Ag SuffOil-X *Talstar S *Talus 70 DF *Tame 2.4EC Tame/Orthene TR *TetraSan Triact 70 TriStar 30 SG TriStar 70 WSP Ultra-Pure Oil *Up-Star SC

Blanchette, Robert A.

300

Annual Energy Outlook 2000 - Legislation & Regulations  

Gasoline and Diesel Fuel Update (EIA)

leg_reg.gif (4810 bytes) Climate Change Action Plan Comprehensive Electricity Competition Act Tier 2 Vehicle Emissions and Gasoline Sulfur Standards California Ban of Methyl Tertiary Butyl Ether Low-Emission Vehicle Program Introduction Because analyses by the Energy Information Administration (EIA) are required to be policy-neutral, the projections in this Annual Energy Outlook 2000 (AEO2000) are based on Federal, State, and local laws and regulations in effect on July 1, 1999. The potential impacts of pending or proposed legislation, regulations, and standards and sections of existing legislation for which funds have not been appropriated are not reflected in the projections. Federal legislation incorporated in the projections includes the Omnibus Budget Reconciliation Act of 1993, which adds 4.3 cents per gallon to the Federal tax on highway fuels [1]; the National Appliance Energy Conservation Act of 1987; the Clean Air Act Amendments of 1990 (CAAA90); the Energy Policy Act of 1992 (EPACT); the Outer Continental Shelf Deep Water Royalty Relief Act of 1995; the Tax Payer Relief Act of 1997; and the Federal Highway Bill of 1998, which includes an extension of the ethanol tax credit. AEO2000 assumes the continuation of the ethanol tax credit through 2020.

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

The National Energy Modeling System: An Overview 2000 - International  

Gasoline and Diesel Fuel Update (EIA)

international energy module (IEM) consists of four submodules (Figure 4) that perform the following functions: international energy module (IEM) consists of four submodules (Figure 4) that perform the following functions: world oil market submodule—calculates the average annual world oil price (imported refiner acquisition cost) that is consistent with worldwide petroleum demand and supply availability crude oil supply submodule—provides im- ported crude oil supply curves for five crude oil quality classes petroleum products supply submodule—pro- vides imported refined product supply curves for eleven types of refined products oxygenates supply submodule—provides imported oxygenates supply curves for methyl tertiary butyl ether (MTBE) and methanol. Figure 4. International Energy Module Structure The world oil price that is generated by the world oil market submodule is used by all the modules of NEMS as well as the other submodules of IEM. The import supply curves for crude oils, refined products, and oxygenates are used by the petroleum market module.

302

Word Pro - Untitled1  

U.S. Energy Information Administration (EIA) Indexed Site

1 1 Table 10.5 Estimated Number of Alternative-Fueled Vehicles in Use and Fuel Consumption, 1992-2010 Year Alternative and Replacement Fuels 1 Liquefied Petroleum Gases Compressed Natural Gas Liquefied Natural Gas Methanol, 85 Percent (M85) 3 Methanol, Neat (M100) 4 Ethanol, 85 Percent (E85) 3,5 Ethanol, 95 Percent (E95) 3 Elec- tricity 6 Hydro- gen Other Fuels 7 Subtotal Oxygenates 2 Bio- diesel 10 Total Methyl Tertiary Butyl Ether 8 Ethanol in Gasohol 9 Total Alternative-Fueled Vehicles in Use 11 (number) 1992 NA 23,191 90 4,850 404 172 38 1,607 NA NA NA NA NA NA NA NA 1993 NA 32,714 299 10,263 414 441 27 1,690 NA NA NA NA NA NA NA NA 1994 NA 41,227 484 15,484 415 605 33 2,224 NA NA NA NA NA NA NA NA 1995 172,806 50,218 603 18,319 386 1,527

303

Refinery Stocks of Crude Oil and Petroleum Products  

Gasoline and Diesel Fuel Update (EIA)

Product: Crude Oil and Petroleum Products Crude Oil Petroleum Products Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) All Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils Naphthas and Lighter Kerosene and Light Gas Oils Heavy Gas Oils Residuum Motor Gasoline Blending Components MGBC - Reformulated MGBC - Reformulated - RBOB MGBC - RBOB for Blending with Alcohol* MGBC - RBOB for Blending with Ether* MGBC - Conventional MGBC - Conventional CBOB MGBC - Conventional GTAB MGBC - Conventional Other Aviation Gasoline Blending Components Finished Motor Gasoline Reformulated Reformulated Blended with Fuel Ethanol Reformulated, Other Conventional Gasoline Conventional Gasoline Blended with Fuel Ethanol Conventional Gasoline Blended with Fuel Ethanol, Ed55 and Lower Conventional Other Gasoline Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Distillate Fuel Oil Distillate Fuel Oil, 15 ppm and Under Distillate Fuel Oil, Greater than 15 ppm to 500 ppm Distillate Fuel Oil, Greater than 500 ppm Residual Fuel Oil Less than 0.31 Percent Sulfur 0.31 to 1.00 Percent Sulfur Greater than 1.00 Percent Sulfur Petrochemical Feedstocks Naphtha for Petrochemical Feedstock Use Other Oils for Petrochemical Feedstock Use Special Naphthas Lubricants Waxes Petroleum Coke Marketable Coke Asphalt and Road Oil Miscellaneous Products Period-Units: Monthly-Thousand Barrels Annual-Thousand Barrels

304

U.S. Blender Net Input  

U.S. Energy Information Administration (EIA) Indexed Site

2007 2008 2009 2010 2011 2012 View 2007 2008 2009 2010 2011 2012 View History Total Input 1,184,435 1,522,193 1,850,204 2,166,784 2,331,109 2,399,318 2005-2012 Natural Gas Plant Liquids and Liquefied Refinery Gases 3,445 5,686 6,538 7,810 10,663 2008-2012 Pentanes Plus 2,012 474 1,808 1,989 2,326 4,164 2005-2012 Liquid Petroleum Gases 2,971 3,878 4,549 5,484 6,499 2008-2012 Normal Butane 2,943 2,971 3,878 4,549 5,484 6,499 2005-2012 Isobutane 2005-2006 Other Liquids 1,518,748 1,844,518 2,160,246 2,323,299 2,388,655 2008-2012 Oxygenates/Renewables 234,047 274,974 286,837 295,004 2009-2012 Methyl Tertiary Butyl Ether (MTBE) 2005-2006 Renewable Fuels (incl. Fuel Ethanol) 234,047 274,974 286,837 295,004 2009-2012 Fuel Ethanol 131,810 182,772 232,677 273,107 281,507 287,433 2005-2012

305

U.S. Blender Net Input  

U.S. Energy Information Administration (EIA) Indexed Site

Apr-13 May-13 Jun-13 Jul-13 Aug-13 Sep-13 View Apr-13 May-13 Jun-13 Jul-13 Aug-13 Sep-13 View History Total Input 206,541 217,867 212,114 216,075 219,783 208,203 2005-2013 Natural Gas Plant Liquids and Liquefied Refinery Gases 891 352 376 196 383 1,397 2008-2013 Pentanes Plus 261 301 313 67 287 393 2005-2013 Liquid Petroleum Gases 630 51 63 129 96 1,004 2008-2013 Normal Butane 630 51 63 129 96 1,004 2005-2013 Isobutane 2005-2006 Other Liquids 205,650 217,515 211,738 215,879 219,400 206,806 2008-2013 Oxygenates/Renewables 25,156 26,576 26,253 26,905 27,788 25,795 2009-2013 Methyl Tertiary Butyl Ether (MTBE) 2005-2006 Renewable Fuels (incl. Fuel Ethanol) 25,156 26,576 26,253 26,905 27,788 25,795 2009-2013 Fuel Ethanol 24,163 25,526 24,804 25,491 25,970 24,116 2005-2013

306

Assessing and Managing the Risks of Fuel Compounds: Ethanol Case Study  

SciTech Connect

We have implemented a suite of chemical transport and fate models that provide diagnostic information about the behavior of ethanol (denoted EtOH) and other fuel-related chemicals released to the environment. Our principal focus is on the impacts to water resources, as this has been one of the key issues facing the introduction of new fuels and additives. We present analyses comparing the transport and fate of EtOH, methyl tertiary butyl ether (MTBE), and 2,2,4 trimethyl pentane (TMP) for the following cases (1) discharges to stratified lakes, subsurface release in a surficial soil, (3) cross-media transfer from air to ground water, and (4) fate in a regional landscape. These compounds have significantly different properties that directly influence their behavior in the environment. EtOH, for example, has a low Henry's law constant, which means that it preferentially partitions to the water phase instead of air. An advantageous characteristic of EtOH is its rapid biodegradation rate in water; unlike MTBE or TMP, which degrade slowly. As a consequence, EtOH does not pose a significant risk to water resources. Preliminary health-protective limits for EtOH in drinking water suggest that routine releases to the environment will not result in levels that threaten human health.

Layton, D.W.; Rice, D.W.

2002-02-04T23:59:59.000Z

307

The conversion of natural gas to liquid fuels using the Sasol Slurry Phase Distillate Process  

SciTech Connect

The natural gas and energy industries have long sought an economically attractive means of converting remote gas reserves into transportable products, such as fuels or petrochemicals. Applicable gas sources include: undeveloped gas fields in locations so remote that pipeline construction is prohibitively expensive and associated gas from oil wells that is either flared, which is becoming environmentally unacceptable in many parts of the world, or reinjected, which is costly. Projects which have been developed to exploit such feeds typically have converted the gas into one of the following: (1) liquefied natural gas (LNG)--the process plants for LNG production are expensive, need to be very large to be economically viable, have costly dedicated shipping requirements, and suffer from a limited market concentrated in few countries; (2) methanol--the market for petrochemical feedstock methanol is limited, for use as a fuel, further downstream processing is needed, for example in a methyl tertiary butyl ether (MTBE) or methanol to gasoline (MTG) unit. Clearly, there is a need for an alternative that produces high quality fuels or value added products that can be transported to far-off markets, while yielding an attractive return on the developers` investment. The Sasol Slurry Phase Distillate Process will fulfill this need.

Silverman, R.W. [Raytheon Engineers and Constructors, Cambridge, MA (United States); Hill, C.R. [Sastech, Johannesburg (South Africa)

1997-12-31T23:59:59.000Z

308

High octane ethers from synthesis gas-derived alcohols. Final technical report, September 25, 1990--December 24, 1993  

SciTech Connect

The objective of the research was to develop the methodology for the catalytic synthesis of ethers, primarily methyl isobutyl ether (MIBE) and methyl tertiary butyl ether (MTBE), directly from alcohol mixtures that are rich in methanol and 2-methyl-1-propanol (isobutanol). The overall scheme involves gasification of coal, purification and shifting of the synthesis gas, higher alcohol synthesis, and direct synthesis of ethers. The last stage of the synthesis involves direct coupling of synthesis gas-derived methanol and isobutanol that has been previously demonstrated by us to occur over superacid catalysts to yield MIBE and smaller amounts of MTBE at moderate pressures and a mixture of methanol and isobutene at low pressures. A wide range of organic resin catalysts and inorganic oxide and zeolite catalysts have been investigated for activity and selectivity in directly coupling alcohols, principally methanol and isobutanol, to form ethers and in the dehydration of isobutanol to isobutene in the presence of methanol. All of these catalysts are strong acids, and it was found that the organic and inorganic catalysts operate in different, but overlapping, temperature ranges, i.e. mainly 60--120{degrees}C for the organic resins and 90--175{degrees}C for the inorganic catalysts. For both types of catalysts, the presence of strong acid centers is required for catalytic activity, as was demonstrated by lack of activity of fully K{sup +} ion exchanged Nafion resin and zirconia prior to being sulfated by treatment with sulfuric acid.

Klier, K.; Herman, R.G.

1994-05-01T23:59:59.000Z

309

Total Crude Oil and Petroleum Products Exports  

U.S. Energy Information Administration (EIA) Indexed Site

Exports Exports Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Motor Gasoline Blend. Comp. (MGBC) MGBC - Reformulated MGBC - Conventional Aviation Gasoline Blend. Comp. Finished Petroleum Products Finished Motor Gasoline Reformulated Gasoline Conventional Gasoline Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., Greater than 15 to 500 ppm Distillate F.O., Greater than 500 ppm Residual Fuel Oil Naphtha for Petro. Feed. Use Other Oils Petro. Feed. Use Special Naphthas Lubricants Waxes Petroleum Coke Asphalt and Road Oil Miscellaneous Products Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

310

Tertiary Volcanic Rocks, Mogollon-Datil Province, New Mexico, and Surrounding Region: K-Ar Dates, Patterns of Eruption, and Periods of Mineralization  

Science Journals Connector (OSTI)

...poor run. Intrudes Spears and Hells Mesa Formations (nos. 2, 3, 4, 5...Correlation uncertain Caps Hells Mesa and younger rocks in type section...Los Pi os Mountains, and North Chupadera Mesa, Valencia, Torrance, and Socorro...

311

Southern Cordilleran Basaltic Andesite suite, southern Chihuahua, Mexico: A link between Tertiary continental arc and flood basalt magmatism in the North America  

SciTech Connect

Mid-Cenozoic orogenic andesites and ignimbrites of western Mexico, southwestern New Mexico, and Arizona are commonly capped by basaltic andesites, most from 29--20 Ma. We refer to these mafic lavas as the Southern Cordilleran Basaltic Andesite (SCORBA) suite, and they may constitute the most extensive Cenozoic basaltic suite in North America. The SCORBA suite has trace element and isotopic characteristics of orogenic (arc) rocks (i.g., Ba/Nb/gt/40), and silica content (53--56% SiO/sub 2/) like the Grande Ronde Basalt, which represents about 80% of the volume of the Columbia River Group. Geochemical and isotopic data are presented on SCORBA lavas and rare mafic lavas (PRE-SCORBA) interlayered with older ignimbrites from a 700-km-long NE-SW transect of southern Chihuahua, Mexico. SCORBA and PRE-SCORBA lavas with relatively low K/P (/lt/7) and differing Ba/Nd (50 versus 18) have similar isotopic compositions, arguing against their isotopic signatures being controlled by crustal assimilation. Along the entire length of the transect, the basaltic rocks have /var epsilon//sub Nd/ and /sup 87/Sr//sup 86/Sr near bulk Earth and /sup 206/Pb//sup 204/Pb and /sup 207/Pb//sup 204/Pb ratios that lie along a 1.7 Ga pseudoisochron. The Pb isotopic variation is geographically controlled, becoming more radiogenic from east to west, reflecting mixing in mantle source regions. The eastern mantle source has low/sup 206/Pb//sup 204/Pb and is a mixture of an enriched, enriched-mantle-like (EMI) component with one or more depleted components, which could include an intraplate component with relatively high Nb/Y (/gt/0.8).

Cameron, K. L.; Nimz, G. J.; Kuentz, D.; Niemeyer, S.; Gunn, S.

1989-06-10T23:59:59.000Z

312

Comparison of maternal and neonatal outcome before and after the availability of a rapid assay for fetal fibronectin at a tertiary level maternity hospital  

E-Print Network (OSTI)

in decisions to admit to hospital for preterm labor. Clinlabour at Middlemore Hospital, New Zealand. Pathology, 37, (negative predictive value for hospital admission after fetal

Poeltler, Debra Ann Milbert

2010-01-01T23:59:59.000Z

313

Investigating Returns to Investments in Education: An Empirical Study Estimating Returns to Primary, Secondary and Tertiary Education for Countries at Different Levels of Economic Development  

E-Print Network (OSTI)

refer to where in education governments should invest in order to obtain the highest returns, based on the specific characteristics of their countries (i.e. level of economic development). The purpose of this dissertation is to estimate and determine...

Lozano, Ricardo Viviano

2012-07-16T23:59:59.000Z

314

Advances in mass storage technology are producing devices capable of holding terabytes of data. These new devices, often called tertiary storage devices, have dramatically different performance  

E-Print Network (OSTI)

-overwrite technique for managing storage. This technique allows the user to see the entire history of the database of the database at any moment in history. This capability is referred to as time travel. Since only the start time characteristics than magnetic disks. Conventional database systems include explicit dependen- cies on magnetic

California at Irvine, University of

315

Study of the kinetics of the gas-phase, iodine catalyzed elimination of HBr from isobutylbromide: the tertiary C-H bond dissociation energy in isobutylbromide.  

E-Print Network (OSTI)

, (with the possible exception of the very electronegative F atom) unless the substituent can delocalize the odd electron such as with the vinyI substituent, i. e. the allyl radical. The stabi'Iization energy is defined as the difference between... of formation of the radical. f s indicated in section (II); the stabilization energy of bromine bridged radical by the delocalization of tne odd electron can be obtained by comparisior, with a localized free radical. Thus, the stabi11zat1on energy...

Jirustithipong, Pongsiri

2012-06-07T23:59:59.000Z

316

Occurrence of Tertiary Lymphoid Tissue Is Associated with T-Cell Infiltration and Predicts Better Prognosis in Early-Stage Colorectal Cancers  

Science Journals Connector (OSTI)

...obtained from the Institutional Intranet; please refer to Supplementary...data from the institutional intranet (Supplementary Table S1...and CD3+ TILs, baseline characteristics and tumor features of patient...the patient histopathologic characteristics are described in Supplementary...

Giuseppe Di Caro; Francesca Bergomas; Fabio Grizzi; Andrea Doni; Paolo Bianchi; Alberto Malesci; Luigi Laghi; Paola Allavena; Alberto Mantovani; and Federica Marchesi

2014-04-15T23:59:59.000Z

317

Occurrence of female genital tuberculosis among infertile women: a study from a tertiary maternal health care research centre in South India  

Science Journals Connector (OSTI)

The purpose of this investigation was to estimate the proportion of female genital tuberculosis (FGTB) among infertile women, along with the mean cost of diagnosis by different methods. The study was carried o...

V. Bhanothu; J. P. Theophilus; P. K. Reddy…

2014-11-01T23:59:59.000Z

318

Linking Low-Level Stable Isotope Fractionation to Expression of the Cytochrome P450 Monooxygenase-Encoding ethB Gene for Elucidation of Methyl tert-Butyl Ether Biodegradation in Aerated Treatment Pond Systems  

Science Journals Connector (OSTI)

...application of CSIA in field investigations to detect biodegradation...52). An alternative remedial strategy could be the use...application of CSIA in field investigations to detect biodegradation may lead to...application of CSIA in field investigations to detect biodegradation...

Sven Jechalke; Mònica Rosell; Paula M. Martínez-Lavanchy; Paola Pérez-Leiva; Thore Rohwerder; Carsten Vogt; Hans H. Richnow

2010-12-10T23:59:59.000Z

319

Highly Regioselective [2 + 2 + 2] Cycloaddition of Terminal Alkynes Catalyzed by ?6-Arene Complexes of Titanium Supported by Dimethylsilyl-Bridged p-tert-Butyl Calix[4]arene Ligand  

Science Journals Connector (OSTI)

Two new Ti??6-arene complexes [(DMSC)Ti{?6-1,2,4-C6H3(SiMe3)3}] (6) and [(DMSC)Ti{?6-1,3,5-C6H3But3}] (7) containing 1,2-alternate, Me2Si-bridged p-tert-butylcalix[4]arene (DMSC) ancillary ligand have been synthesized. ... The high selectivity for 1,2,4-substituted benzene may be understood in terms of the directing influence of the DMSC ligand. ... For example, the two chloride ligands in (DMSC)TiCl2 (1) (DMSC = 1,2-alternate Me2Si-bridged p-tert-butylcalix[4]arene) exist in different stereochemical environments. ...

Oleg V. Ozerov; Brian O. Patrick; Folami T. Ladipo

2000-06-21T23:59:59.000Z

320

C(sp2)?C(sp3) Rotational Barriers in Simple Amides:? H2N?C(O)R (R = Methyl, Ethyl, i-Propyl, tert-Butyl)  

Science Journals Connector (OSTI)

(a) Cuillerdier, C.; Musikas, C.; Hoel, P.; Nigond, L.; Vitart, X. Sep. ... (f) Cuillerdier, C.; Musikas, C.; Nigond, L. Sep. ... (i) Nigond, L.; Musikas, C.; Cuillerdier, C. Solv. ...

Giovanni Sandrone; David A. Dixon; Benjamin P. Hay

1999-02-03T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Photoluminescence properties of polynapthalenevinylene (PNV) homopolymers and block copolymers by ring–opening metathesis polymerization (ROMP) and study of their photoluminescence properties  

Science Journals Connector (OSTI)

...6-tetrafluorobenzene, 6, reacts with butyl lithium to yield a benzyne intermediate which...second metal halide exchange using butyl lithium at low temperature yielded the lithium adduct. Addition of an excess of alkyl iodide and gradual warming...

1997-01-01T23:59:59.000Z

322

E-Print Network 3.0 - acrylic acid grafted Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

& acronyms 11 PPPP PAA Poly(acrylic acid) PBMA Poly(butyl methacrylate) PE Polyethylene PHEMA Poly... ......

323

An elusive species with many different traits.  

E-Print Network (OSTI)

-Pase detection of HSOH: Synthesis by Flash Vacuum Pyrolysis of ditert-butyl-sulfoxide and rotational- torsional

Giesen, Thomas

324

Dynamics of conserved waters in human Hsp90: implications for drug design  

Science Journals Connector (OSTI)

...43 0.80 3 H H OMe H H n-butyl 3.17 0.88 4 H H OCH2O bridge H n-butyl 0.46 0.78 5 H OMe H H OMe n-butyl 0...F OMe H H OMe 1-pentynyl 0.53 1.25 12 F H OCH2O bridge H n-butyl 0.45 0.53 a RMS: docking result when four...

2008-01-01T23:59:59.000Z

325

Total Synthesis of Amphilectolide, Sandresolide B, Archazolid B and towards Archazolid A and Caribenol A  

E-Print Network (OSTI)

The presence of an excess of lithium chloride acceleratesusing an excess of tert-butyl lithium and trimethylsilyl

Chen, Ingrid T.

2011-01-01T23:59:59.000Z

326

BulletinofMathematicalBiologyVol.47,No.3,pp.367 407,1985. PrintedinGreatBritain  

E-Print Network (OSTI)

the tertiary structure. Five proteins, parvalbumin, hemerythrin, human hemoglobin, lamprey hemoglobin

Cariani, Peter

327

The Development and Application of Gold(I)-Catalyzed Cyclization Cascades  

E-Print Network (OSTI)

lithium trimethylsilylacetylide to give tertiary alcohol 4.43. Deprotection and esterification then provided acetate

Sethofer, Steven Gregory

2011-01-01T23:59:59.000Z

328

The process of developing a strategy of sustainable development in the Pamir  

E-Print Network (OSTI)

activities such as mineral exploitation and hydroelectricity genera- tion. Tertiary sector activities

Richner, Heinz

329

Odorization system upgrades gas utility`s pipelines  

SciTech Connect

Mountain Fuel Supply Co., a subsidiary of Questar Corp., salt Lake City, is a natural gas holding company with $1.6 billion in assets. From 1929 to 1984, Mountain Fuel Supply Co. owned and operated many natural gas wells, gathering systems, and transmission pipelines to serve its Utah and Wyoming customers. Gas is odorized at convenient points on the transmission lines and at each downstream location where unodorized gas entered the system. Since 40 to 60% of the gas delivered to the company`s customers passes through Coalville Station, it was vital that a reliable, state-of-the-art odorant station be constructed at this site. Construction began during the summer of 1994 and the system came on line Sept. 1, 1994. The station odorized 435 MMcfd with 330 lbs. of odorant during last winter`s peak day, a mild winter. Mountain Fuel is subject to Department of Transportation (DOT) codes which mandate that gas be readily detectable at one fifth the lower explosive limit (LEL), or about 1% gas in air. However, the company strives to maintain a readily detectable odor at 0.25% of gas in air as measured by odormeter tests throughout the distribution system. Experience has shown that maintaining an odorant injection rate of 0.75 lbs/MMcf provides adequate odor levels. A blend of odorant consisting of 50% tertiary butyl mercaptan (TBM) and 50% tetrahydrothiophene (THT) was used for many years by Questar Pipeline. Presently, it is used at all Mountain Fuel stations. This paper reviews the design and operation of this odorization station.

Niebergall, B. [Mountain Fuel Supply, Salt Lake City, UT (United States)

1995-07-01T23:59:59.000Z

330

Dehydration of isobutanol to isobutene in a slurry reactor  

SciTech Connect

The April 1990 Alternative Fuels Proposal to the Department of Energy involved the development of new technology, based on the liquid phase process, for conversion of coal-derived synthesis gas to oxygenated hydrocarbon fuels, fuel additives, and fuel intermediates. The objective of this work was to develop a slurry reactor based process for the dehydration of isobutanol to isobutene. The isobutene can serve as a feedstock for the high octane oxygenated fuel additive methyl tertiary-butyl either (MTBE). Alumina catalysts were investigated because of their wide use as a dehydration catalyst. Four commercially available alumina catalysts (Catapal B, Versal B, Versal GH, and Al-3996R) were evaluated for both activity and selectivity to the branched olefin. All four catalysts demonstrated conversions greater than 80% at 290 C, while conversions of near 100% could be obtained at 330 C. The reaction favors low pressures and moderate to low space velocities. A yield of 0.90 mole isobutene per mole reacted isobutanol or better was obtained at conversions of 60--70% and higher. From 75 to 98% conversion, the four catalysts all provide isobutene yields ranging from 0.92 to 0.94 with the maximum occurring around 90% conversion. At low conversions, the concentration of diisobutyl ether becomes significant while the concentration of linear butenes is essentially a linear function of isobutanol conversion. Doping the catalyst with up to 0.8 wt % potassium showed a modest increase in isobutene selectivity; however, this increase was more than offset by a reduction in activity. Investigations using a mixed alcohols feed (consistent with isobutanol synthesis from syngas) demonstrated a small increase in the C4 iso-olefin selectivity over that observed for a pure isobutanol feed. 55 refs.

Latshaw, B.E.

1994-02-01T23:59:59.000Z

331

Alperin's Fusion Theorem and Fusion Systems David A. Craven  

E-Print Network (OSTI)

-called domestic intersections, which are special types of tame intersections that should play a role in fusionAlperin's Fusion Theorem and Fusion Systems David A. Craven September 2010 Abstract This short note provides a new and straightforward proof of the original fusion theorem of Alperin, then considers so

Craven, David A.

332

Book Reviews  

Science Journals Connector (OSTI)

...might have social arid political...concern for the ethical questions...study of the social implications...numbers, from business and economics...who scorned theory and extolled...im-portant role in taming...of small theories about such topics as social influence...and the perception of other...catalytic role in bringing...

1973-05-11T23:59:59.000Z

333

THE DEPARTMENT OF ELECTRICAL ENGINEERING AND COMPUTER SCIENCE, CS DIVISION Presents the Spring 2014 EECS Seminar Series  

E-Print Network (OSTI)

EECS Seminar Series Xiangnan Kong University of Illinois at Chicago "Taming Big Data Variety: From decade, we are experiencing big data challenges in various research domains. The data nowa- days involve introduce the big data landscape and present two projects that help us be er understand how to solve data

Stanley, Kenneth O.

334

Current perspectives and the future of domestication studies  

Science Journals Connector (OSTI)

...shifts and atmospheric gas concentrations on...Press , Cambridge ). 3 Price D, Bar-Yosef O eds...of Species by Means of Natural Selection, or the Preservation of Favoured...for early cat taming in Egypt. J Archaeol Sci 34...Southwestern desert, Egypt. Geoarchaeology 16...

Greger Larson; Dolores R. Piperno; Robin G. Allaby; Michael D. Purugganan; Leif Andersson; Manuel Arroyo-Kalin; Loukas Barton; Cynthia Climer Vigueira; Tim Denham; Keith Dobney; Andrew N. Doust; Paul Gepts; M. Thomas P. Gilbert; Kristen J. Gremillion; Leilani Lucas; Lewis Lukens; Fiona B. Marshall; Kenneth M. Olsen; J. Chris Pires; Peter J. Richerson; Rafael Rubio de Casas; Oris I. Sanjur; Mark G. Thomas; Dorian Q. Fuller

2014-01-01T23:59:59.000Z

335

Comparison of Gas Chromatographic and Pyrolytic Methods for the Determination of Total Oxygen in Gasolines  

Science Journals Connector (OSTI)

......gasoline; and low water solubility. A number of...inert carrier gas, and the products...used in the nitrogen gas delivery line...LECO FP-428 nitrogen analyzer. Figure...place to avoid gas leaks. All...remove traces of water. ETBE and TAME......

R.E. Pauls; J.D. Northing; G.J. Weight

1994-01-01T23:59:59.000Z

336

Sydney Rex Tims  

Science Journals Connector (OSTI)

......obituary OBITUARIES Sydney Rex Tims D. B. Scott SYDNEY REX TIMS (born 21 December...1972), 100-101] SYDNEY REX TIMS 101 fraternisation...strong reservations about Opera which was perhaps too...tamed, the first real house of their own. His widow......

D. B. Scott

1972-03-01T23:59:59.000Z

337

bitcoin.BitMint Bitcoin.BitMint  

E-Print Network (OSTI)

® bitcoin.BitMint 1 Bitcoin.BitMint Reconciling Bitcoin with Central Banks Volatility - No Samid BitMint, LLC * Gideon@BitMint.com The sweeping success of the original (2008) bitcoin protocol indicates an overshoot. We propose to tame bitcoin into bitcoin.BitMint: keeping the bitcoin excitement

338

Resolving issues of imprecise and habitat-biased locations in ecological analyses using GPS telemetry data  

Science Journals Connector (OSTI)

...a GPS device to a human, vehicle or tame animal generally moving...limited range of behaviour and ecological conditions compared with free-ranging...using devices affixed to a vehicle moving approximately 10 kph...the toolbox of solutions for ecological analyses (a) Resource selection...

2010-01-01T23:59:59.000Z

339

Chemical behavior of degradation products of tributylphosphate in purex reprocessing  

SciTech Connect

Chemical behavior of butyl nitrate/butyl alcohol, degradation products from dealkylation of tri-n-butylphosphate(TBP) in PUREX reprocessing, which has not so far been reported, was investigated. No accumulation of those compounds in the organic phase of TBP(30%)-dodecane was observed in any separation cycle of PUREX despite the fact that the apparent distribution of the compounds lies to the organic phase at their high concentrations. The distribution of butyl nitrate/butyl alcohol between organic/aqueous phases is found to be dependent on their concentrations and on nitric acid concentration, which could explain the above phenomena. Only butyl nitrate of the above two compounds was slightly detected in the organic streams. It is probable from this investigation that butyl nitrate is removed into aqueous waste stream primarily through alkali scrubber.

Kuno, Y.; Sato, S.; Masui, J. [Power Reactor and Nuclear Fuel Development Corp., Ibaraki (Japan)] [and others

1995-12-01T23:59:59.000Z

340

Nonphosphate Degradation Products of Tributyl Phosphate and Their Reactivities in Purex Media Under Extreme Conditions  

SciTech Connect

The chemical degradation of tributyl phosphate (TBP) in liquid systems, where TBP was in contact with aqueous solutions containing nitric acid and/or uranyl nitrate, was studied experimentally to clarify the mechanisms of the formation and successive reactions of nonphosphate products under atmospheric pressure. Butyl nitrate, propionic acid, acetic acid, butric acid, and butyl alcohol were formed as the nonphosphate butyl products derived from the butyl-groups of TBP in an open system. The total amount of these products almost equals the amount of the major intermediate phosphate products reduced, i.e., di- and monobutyl phosphates and phosphoric acid. Butyl alcohol was found to be the precursor of the other nonphosphate products.Even when the extremely degraded solvent was further contacted with 10 M nitric acid at 90 deg. C, no significant heat evolution was observed at atmospheric pressure. Only butyl alcohol changed into carboxylic acids by exothermic oxidative reactions.

Tashiro, Yoshikazu [Sumitomo Metal Mining Company, Ltd. (Japan); Kodama, Ryuji [Sumitomo Metal Mining Company, Ltd. (Japan); Sugai, Hiroshi [Sumitomo Metal Mining Company, Ltd. (Japan); Suzuki, Katsuhiko [Japan Nuclear Fuel, Ltd. (Japan); Matsuoka, Shingo [Japan Nuclear Fuel, Ltd. (Japan)

2000-01-15T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

A Novel Method for Separation and Identification of Sulphur Compounds in Naphtha (30–200°C) and Middle Distillate (200–350°C) Fractions of Lloydminster Heavy Oil by GC/MS  

Science Journals Connector (OSTI)

......5-diethylthiophene thiophene diethyl sulphide tetrahydrothiophene ethyl phenyl sulphide naphthalene...benzothiophene dibenzothiophene methyl tetrahydrothiophene methyl tetrahydrothiopyran dimethyl tetrahydrothiophene ethyl butyl sulphide amyl ethyl......

M.A. Poirier; G.T. Smiley

1984-07-01T23:59:59.000Z

342

Download  

Science Journals Connector (OSTI)

Aug 6, 1979 ... Photosynthetic bacterial production in lakes: The effects of ... bacterial production of total production .... water was injected into a butyl rubber-.

2000-01-12T23:59:59.000Z

343

E-Print Network 3.0 - allyl methacrylate styrene Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Tetrachloroethylene () Cyclohexanol () Cyclohexanone ()1- 1-Butyl alcohol ()2... ;() Acrolein () Acrylic acid () Allyl zlcohol () Allyl chloride () Allyl glycidyl ether(AGE) ()2-...

344

Early opening history of the North Atlantic — I. Structure and origin of the Faeroe—Shetland Escarpment  

Science Journals Connector (OSTI)

......Faeroe-Shetland Trough and More Basin. References Am K...NW-European Tertiary basin, Newsl. Strat., 8...Australia: Great Australian Bight and western sections...NW-European Tertiary basin, Newsl. Strat., 8...Australia: Great Australian Bight and western sections......

D. K. Smythe; J. A. Chalmers; A. G. Skuce; A. Dobinson; A. S. Mould

1983-02-01T23:59:59.000Z

345

Early opening history of the North Atlantic — I. Structure and origin of the Faeroe—Shetland Escarpment  

Science Journals Connector (OSTI)

......Trough and More Basin. References Am...NW-European Tertiary basin, Newsl. Strat...of Australia: Great Australian Bight and western sections...NW-European Tertiary basin, Newsl. Strat...of Australia: Great Australian Bight and western sections......

D. K. Smythe; J. A. Chalmers; A. G. Skuce; A. Dobinson; A. S. Mould

1983-02-01T23:59:59.000Z

346

BIOINFORMATICS Vol. 20 no. 10 2004, pages 16031611  

E-Print Network (OSTI)

that the majority of most proteins fold via a cooperative process where secondary and tertiary structure form

347

U.S. Department of the Interior U.S. Geological Survey  

E-Print Network (OSTI)

Basin are unconsolidated deposits of the Tertiary Santa Fe Group. Post-Santa Fe Group deposits (piedmont

348

2 CHANCELLOR'S INTRODUCTION SECTION 01. OVERVIEW  

E-Print Network (OSTI)

with the Government's tertiary reforms, in the hope that these reforms would assist the University in meeting its of the Education (Tertiary Reform) Amendment Bill. Those provisions, if enacted, would have given the government. Other aspects of this engagement were less encouraging. It seems clear that the current tertiary reforms

Goodman, James R.

349

Inhibition of Cell Cycle Kinetics and Proliferation by the Androgen 5?-Dihydrotestosterone and Antiestrogen N,n-Butyl-N-methyl-11-[16??-chloro-3?,17?-dihydroxy-estra-1?,3?,5?-(10?)triene-7??-yl] Undecanamide in Human Breast Cancer ZR-75-1 Cells  

Science Journals Connector (OSTI)

...Phila.), 47: 2319-2326, 1981. 3. Poulin, R., and Labrie, F. Stimulation of...London: McMillan Press, 1981. 8. Poulin, R., M rand,Y., Poirier, D...Endocrinology, 126: 3223-3231. 1989. 11. Poulin. R., Baker, D.. and Labrie. F...

Yvan de Launoit; Sophie Dauvois; Maurice Dufour; Jacques Simard; Fernand Labrie

1991-06-01T23:59:59.000Z

350

Microsoft Word - MRCSP Phase III FactSheet _09-08_ _2_.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

MRCSP Large Scale CO2 Storage in the Mount Simon Reservoir 1 MRCSP Large Scale CO2 Storage in the Mount Simon Reservoir 1 FACT SHEET FOR PARTNERSHIP FIELD VALIDATION TEST Midwest Regional Carbon Sequestration Partnership (MRCSP) NETL Cooperative Agreement DE-FC26-05NT42589 DOE/NETL Project Manager: Lynn Brickett, Lynn.Brickett@NETL.DOE.GOV Submitted by Battelle September 2008 MRCSP Phase III Large Scale Geologic Injection Test Principal Investigator Dave Ball, Battelle (614)-424-4901; balld@battelle.org) Test Location Primary Site: The Andersons Marathon Ethanol (TAME) Plant, Greenville, Ohio. Optional Site: Duke IGCC plant, Edwardsport, Indiana Amount and Source of CO 2 Primary Site: 1,000,000 tons CO 2 over 4 years. Source, TAME Ethanol Plant Optional Site: 2,000,000 tons CO 2 over 4 years. Source, Duke IGCC

351

Design, construction, and service behavior of selected pavements in district 17 of the Texas Highway Department  

E-Print Network (OSTI)

Q. ta of these maaavremanba ~M tb 4 Caa5 zaeolta an Shiv material axe sheen Ln TaMe 3, 8~ The ~nations iAK; -l8 7YPlTiAT? JGB C' J'T9iGL T~T PZOKJ'TG 9:l F. l&?yO8 ' ' 5 Bet 4' tteti5'oh . ' ' Plastgojt~ LimseA' ' ' T'~be ' -Og '2~ixx jonah Kmh Vo...Q. ta of these maaavremanba ~M tb 4 Caa5 zaeolta an Shiv material axe sheen Ln TaMe 3, 8~ The ~nations iAK; -l8 7YPlTiAT? JGB C' J'T9iGL T~T PZOKJ'TG 9:l F. l&?yO8 ' ' 5 Bet 4' tteti5'oh . ' ' Plastgojt~ LimseA' ' ' T'~be ' -Og '2~ixx jonah Kmh Vo...

Long, Robert Eugene

2012-06-07T23:59:59.000Z

352

Effect of xenobiotics on the respiratory activity of rat heart mitochondria and the concomitant formation of superoxide radicals  

SciTech Connect

The effects of the xenobiotics atrazine, benzene, butylated hydroxyanisole (BHA), butylated hydroxytoluene (BHT), lindane, toluene, and xylenol on the respiration of isolated rate heart mitochondria were studied. Bioenergetic parameters such as respiratory control (RC) and ATP/oxygen (P/O) values decreased considerably in the presence of these substances, and a concomitant increase of superoxide radical (O[sub 2][sup [minus

Stolze, K.; Nohl, H. (Univ. of Vienna (Austria). Inst. of Pharmacology and Toxicology)

1994-03-01T23:59:59.000Z

353

SPME in Environmental Analysis: Biotransformation Pathways  

Science Journals Connector (OSTI)

......SPMEGCMS to study the degradation of ethyl benzene using...methyl-t-butyl ether and its degradation products, t-butyl...food by determining degradation products and other released...Bitumen is a fossil fuel rich in sulfur, which...Aliquots of the cell suspension (2 mL......

Annamaria Halasz; Jalal Hawari

2006-08-01T23:59:59.000Z

354

2D Kagom´e ordering in the 3D frustrated spinel Li2Mn2O4  

NLE Websites -- All DOE Office Websites (Extended Search)

12.5 ml of 16 M n-butyl lithium in 40 ml of sodium-dried hexane. This provides a slight excess of n-butyl lithium. After gentle heating at 40 C for 5 days, the final product...

355

Inhibition of biofilm formation and swarming of Bacillus subtilis by (5Z)-4-bromo-5-(bromomethylene)-  

E-Print Network (OSTI)

)- 3-butyl-2(5H)-furanone D. Ren1 , J.J. Sims2 and T.K. Wood1 1 Departments of Chemical Engineering. REN, J.J. SIMS AND T.K. WOOD. 2002. Aims: (5Z)-4-Bromo-5-(bromomethylene)-3-butyl-2(5H

Wood, Thomas K.

356

Reviving Cold Fusion  

Science Journals Connector (OSTI)

Reviving Cold Fusion ... In March 1989, electrochemists B. Stanley Pons and Martin Fleischmann announced at a press conference at the University of Utah that they had tamed the power of nuclear fusion in a benchtop electrolysis experiment. ... The discovery of cold fusion, as it came to be called, held the promise of endless amounts of pollution-free energy being generated from the natural deuterium in water. ...

STEPHEN K. RITTER

2012-05-14T23:59:59.000Z

357

[Research and workshop on alternative fuels for aviation. Final report  

SciTech Connect

The Renewable Aviation Fuels Development Center (RAFDC) at Baylor University was granted U. S. Department of Energy (US DOE) and Federal Aviation Administration (FAA) funds for research and development to improve the efficiency in ethanol powered aircraft, measure performance and compare emissions of ethanol, Ethyl Tertiary Butyl Ether (ETBE) and 100 LL aviation gasoline. The premise of the initial proposal was to use a test stand owned by Engine Components Inc. (ECI) based in San Antonio, Texas. After the grant was awarded, ECI decided to close down its test stand facility. Since there were no other test stands available at that time, RAFDC was forced to find additional support to build its own test stand. Baylor University provided initial funds for the test stand building. Other obstacles had to be overcome in order to initiate the program. The price of the emission testing equipment had increased substantially beyond the initial quote. Rosemount Analytical Inc. gave RAFDC an estimate of $120,000.00 for a basic emission testing package. RAFDC had to find additional funding to purchase this equipment. The electronic ignition unit also presented a series of time consuming problems. Since at that time there were no off-the-shelf units of this type available, one had to be specially ordered and developed. FAA funds were used to purchase a Super Flow dynamometer. Due to the many unforeseen obstacles, much more time and effort than originally anticipated had to be dedicated to the project, with much of the work done on a volunteer basis. Many people contributed their time to the program. One person, mainly responsible for the initial design of the test stand, was a retired engineer from Allison with extensive aircraft engine test stand experience. Also, many Baylor students volunteered to assemble the. test stand and continue to be involved in the current test program. Although the program presented many challenges, which resulted in delays, the RAFDC's test stand is an asset which provides an ongoing research capability dedicated to the testing of alternative fuels for aircraft engines. The test stand is now entirely functional with the exception of the electronic ignition unit which still needs adjustments.

NONE

1999-09-01T23:59:59.000Z

358

Total Crude Oil and Petroleum Products Imports by Area of Entry  

U.S. Energy Information Administration (EIA) Indexed Site

by Area of Entry by Area of Entry Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane Ethylene Propane Propylene Normal Butane Butylene Isobutane Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Fuel Other Renewable Diesel Fuel Other Renewable Fuels Other Hydrocarbons Unfinished Oils Naphthas and Lighter Kerosene and Light Gas Oils Heavy Gas Oils Residuum Motor Gasoline Blending Components (MGBC) MGBC - Reformulated, RBOB MGBC - Conventional MGBC - Conventional, CBOB MGBC - Conventional, GTAB MGBC - Other Conventional Aviation Gasoline Blending Components Finished Petroleum Products Finished Motor Gasoline Reformulated Gasoline Reformulated Blended w/ Fuel Ethanol Conventional Gasoline Conventional Blended w/ Fuel Ethanol Conventional Blended w/ Fuel Ethanol, Ed55 and Lower Conventional Other Finished Aviation Gasoline Kerosene-Type Jet Fuel Kerosene-Type Bonded Aircraft Fuel Other Bonded Aircraft Fuel Kerosene Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., Bonded, 15 ppm and under Distillate F.O., Other, 15 ppm and under Distillate F.O., Greater than 15 to 500 ppm Distillate F.O., Bonded, Greater than 15 to 500 ppm Distillate F.O., Other, Greater than 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., Greater than 500 to 2000 ppm Distillate F.O., Bonded, Greater than 500 to 2000 ppm Distillate F.O., Other, Greater than 500 ppm to 2000 ppm Distillate F.O., Greater than 2000 ppm Distillate F.O., Bonded, Greater than 2000 ppm Distillate F.O., Other, Greater than 2000 ppm Residual Fuel Oil Residual F.O., Bonded Ship Bunkers, Less than 0.31% Sulfur Residual F.O., Bonded Ship Bunkers, 0.31 to 1.00% Sulfur Residual F.O., Bonded Ship Bunkers, Greater than 1.00% Sulfur Petrochemical Feedstocks Naphtha for Petrochem. Feed. Use Other Oils for Petrochem Feed. Use Special Naphthas Lubricants Waxes Petroleum Coke Asphalt and Road Oil Miscellaneous Products Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels Annual-Thousand Barrels per Day

359

Desorption of carbon monoxide from nickel using mercaptans  

SciTech Connect

An IR spectroscopic study on the displacement of carbon monoxide with 1-propyl, 2-propyl-, 1-butyl-, 2-butyl-, and tert.-butyl mercaptan from nickel foil and silica-supported nickel showed that at low carbon monoxide coverage on supported nickel, mercaptan adsorption initially converted bridged to linear carbon monoxide surface species. At higher mercaptan pressures, carbon monoxide desorbed into the gas phase. A small amount of carbon monoxide remained on the surface when the poisoned sample was evacuated, and additional carbon monoxide adsorbed when 5 mm Hg of carbon monoxide was added to the evacuated sample.

Neff, L.D.; Sturdivant, A.E.; Wallace, J.L.

1980-06-01T23:59:59.000Z

360

--No Title--  

National Nuclear Security Administration (NNSA)

early Permian in age and consist of 22,000 feet of limestone, dolomite, quartzite, shale, and conglomerate beds. The predominantly volcanic Oak Springs formation of Tertiary...

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Title  

National Nuclear Security Administration (NNSA)

early Permian in age and consist of 22,000 feet of limestone, dolomite, quartz- ite, shale, and conglomerate beds. The predominantly volcanic Oak Springs formation of Tertiary...

362

This Week In Petroleum Printer-Friendly Version  

Annual Energy Outlook 2012 (EIA)

or tertiary stock levels. For example, if gasoline stations are drawing down their tanks more than normal in order to postpone purchases (a reasonable strategy when prices are...

363

E-Print Network 3.0 - aliphatic amines extraction Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

; Environmental Sciences and Ecology 37 Exploratory Studies on Fast Pyrolysis Oil Upgrading Summary: using Aliphatic Tertiary Amines... -1 Acetic Acid Recovery from Fast...

364

u42501.PDF  

Office of Legacy Management (LM)

Younger sedimentary rocks overlying the Wasatch Formation are the Tertiary sandstone, oil shale, and marlstone beds of the Green River Formation which crop out almost continuously...

365

Mineralogy and organic petrology of oil shales in the Sangkarewang formation, Ombilin Basin, West Sumatra, Indonesia.  

E-Print Network (OSTI)

??The Ombilin Basin, which lies in Sumatra Island, is one of the Tertiary basins in Indonesia. This basin contains a wide variety of rock units,… (more)

Fatimah, Fatimah

2009-01-01T23:59:59.000Z

366

Fractures of the Dammam Dome Carbonate Outcrops: Their Characterization, Development, and Implications for Subsurface Reservoirs.  

E-Print Network (OSTI)

??The exposed Tertiary carbonates of the Dammam Dome present an opportunity to study fractures in outcrops within the oil-producing region of Eastern Saudi Arabia. The… (more)

Al-Fahmi, Mohammed M

2012-01-01T23:59:59.000Z

367

Relative influence of natural watershed properties and human disturbance on stream solute concentrations in the southwestern  

E-Print Network (OSTI)

balance calculations suggest that supplemental cattle salts could comprise a significant fraction, tertiary sediments or sandstone for a given soil exchangeable cation content in both seasons. Simple mass

Biggs, Trent

368

MULTI-SCALE SIMULATIONS OF INTRINSICALLY DISORDERED PROTEINS AND DEVELOPMENT OF ENHANCED SAMPLING TECHNIQUES.  

E-Print Network (OSTI)

??Intrinsically disordered proteins (IDPs) are functional proteins that lack stable tertiary structures under physiological conditions. IDPs are key components of regulatory networks that dictate various… (more)

Zhang, Weihong

2014-01-01T23:59:59.000Z

369

Mechanisms of binding diversity in protein disorder : molecular recognition features mediating protein interaction networks.  

E-Print Network (OSTI)

??Indiana University-Purdue University Indianapolis (IUPUI) Intrinsically disordered proteins are proteins characterized by lack of stable tertiary structures under physiological conditions. Evidence shows that disordered proteins… (more)

Hsu, Wei-Lun

2014-01-01T23:59:59.000Z

370

Geothermal Literature Review At Lightning Dock Geothermal Area...  

Open Energy Info (EERE)

Evidence for Large-Scale Laramide Tectonic Inversion and a Mid-Tertiary Caldera Ring Fracture Zone at the Lightning Dock Geothermal System, New Mexico Additional References...

371

Retreat of the state and the market: liberalisation and education expansion in Sudan under the NCP.  

E-Print Network (OSTI)

??This thesis is an analysis of two concurrent processes - the liberalisation of the economy and the expansion of the tertiary education system - by… (more)

Mann, Laura Elizabeth

2012-01-01T23:59:59.000Z

372

E-Print Network 3.0 - antigen proteins promotes Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

characteristics is focused on antigenic proteins. Epitopes play... another through protein folding. Thus, the importance of the tertiary conformation of the antigen... that are...

373

E-Print Network 3.0 - antigenic protein fractions Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

characteristics is focused on antigenic proteins. Epitopes play... another through protein folding. Thus, the importance of the tertiary conformation of the antigen... that are...

374

E-Print Network 3.0 - aryl bisdiazeniumdiolates potent Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Hindered Alkyl-Aryl Ethers Thomas F. Woiwode... synthesis.2 Our retrosynthetic analysis of phomopsin A targeted the chiral tertiary alkyl-aryl ether... substitution (SNAr)...

375

Shallow seismic investigations in the Valles Caldera  

E-Print Network (OSTI)

type · Complex shallow structure Davidson, M. Thesis, Perdue Univ. 1999 unconsolidated sediments fill Davidson, M. Thesis, Perdue Univ. 1999 unconsolidated sediments Permian/tertiary sediments

West, Michael

376

E-Print Network 3.0 - acute cardiac care Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: patients are enrolled in cardiac rehabilitation programmes, both from the health care staV and other... being discharged from a tertiary care centre in western...

377

Verification of the need for optical purity measurement of chiral pesticide standards as agricultural reference materials  

Science Journals Connector (OSTI)

In this study, optical purity measurement was performed on eight kinds of commercially available pesticide, namely, Dimethenamid-P, Dichlorprop-P, Fluazifop-P butyl, Indoxacarb, Metalaxyl-M, Mecoprop-P, Quizal...

Koichi Saito; Masakazu Yato; Takeshi Ito…

2008-07-01T23:59:59.000Z

378

Synthesis and elaboration of polyethylene surfaces modified via anionic grafting chemistry  

E-Print Network (OSTI)

) was grafted to polyethylene films using these initiators. Hydrolysis of poly(tert-butyl acrylate) grafted polyethylene films led to a poly(acrylic acid) grafted polyethylene surfaces. Characterization of the grafted films by surface selective techniques...

Bandella, Ashok Krishangopal

2012-06-07T23:59:59.000Z

379

Soluble hyperbranched grafts on polyethylene surfaces  

E-Print Network (OSTI)

Here we report two methods to synthesize hyperbranched poly(acrylic acid) grafts on polyethylene films and powders. The previously reported route using ?,[]-diaminopoly(tert-butyl acrylate) was repeated and all previous results were confirmed...

Britton, Danielle M

2012-06-07T23:59:59.000Z

380

High-resolution infrared measurements on HSOH: Analysis of the OH fundamental vibrational mode  

E-Print Network (OSTI)

-wave spectroscopy on HSOH and H34 SOH [1]. The authors used flash vacuum pyrolysis of di-tert-butyl sulfoxide] identified five of six fundamental vibrational modes of matrix isolated HSOH formed by pyrolysis of di

Giesen, Thomas

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Combination Scattering Meter and Fluorometer  

E-Print Network (OSTI)

-butyl tin (TBT), marine anti- fouling paint, ablative coatings, etc. Please ensure any anti beyond the normal wear and tear of field deployment, or in the event the pressure cans have been opened

Boss, Emmanuel S.

382

A BRIEF HISTORY OF INDUSTRIAL CATALYSIS  

E-Print Network (OSTI)

More recently, Air Products and Chemicals Corporation hasProcess Division of Air Products & Chemicals, Inc. HC Q)air oxidation of isobutane. T-butyl alcohol is a co- product

Heinemann, Heinz

2013-01-01T23:59:59.000Z

383

Metal catalyzed copolymerization processes involving carbon oxides as substrates  

E-Print Network (OSTI)

backbone and electron donating tert-butyl groups in the phenolate rings. This catalyst was used to investigate the effect of altering the nature of the cocatalyst and its concentration. The coupling of carbon monoxide and aziridines has been shown...

Phelps, Andrea Lee

2005-11-01T23:59:59.000Z

384

Cathodic disbondment resistance with reactive ethylene terpolymer blends and composite coatings  

E-Print Network (OSTI)

capability of organo-modified nanoclay offered significantnBA n-butyl acrylate NC natural nanoclay NR natural rubberOC organically modified nanoclay PA6 polyamide 6 (nylon 6)

Love, Corey T.

2008-01-01T23:59:59.000Z

385

Download Full-text PDF  

Science Journals Connector (OSTI)

Production of the compounds ... leased. The rates of CHBr3 and C2H2Br2 production were neg- ... with PTFE-coated butyl rubber seals were equilibrated in the.

1999-07-01T23:59:59.000Z

386

Selectivity Changes During Organic Photooxidation on TiO2: Role...  

NLE Websites -- All DOE Office Websites (Extended Search)

but the t-butyl radical has several options for thermal chemistry. In ultrahigh vacuum (UHV), where the O2 partial pressure is <1x10-10 torr, the TMA photodecomposition results...

387

Tribological Properties of Ionic Liquids Lubricants Containing Nanoparticles  

E-Print Network (OSTI)

is to describe the tribological and rheological properties of mixtures of nanoparticles (NPs) and ionic liquids (ILs), specifically the mixture of bare SiO_(2) (silica) nanoparticles and ionic liquid 1-butyl-3-methylimidazolium (trifluoromethysulfony...

Lu, Wei

2014-05-14T23:59:59.000Z

388

E-Print Network 3.0 - anhydride-vinyl methyl ether Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

4-Methyl-2-pentanol Other secondary alcohols... - quire handling with precautions. Acrolein tert-Butyl methyl ether Di(1-propynl) ether n... Methoxy-1,3,5,7- cyclooctatetraene...

389

Chiral Separations by High-Performance Liquid Chromatography  

Science Journals Connector (OSTI)

......epoxides 76 Scheme 5. Synthesis of oxazolidone CSP...microcrystalline cellulose tri acetate (CTA) can be used...sparteine-n- butyl lithium catalyst. This led...in stere oselective synthesis coupled with ingenious...methods, Asymmetric Synthesis, 1: 87224 (1983......

David R. Taylor; Kevin Maher

1992-03-01T23:59:59.000Z

390

(front end fuel cycle) 2.1 (CANDU  

E-Print Network (OSTI)

.2.1. , , , , . UNH(Uranyl Nitrate Hexahydrate) . UNH TBP(Tri-Butyl Phosphate) TBP . TBP UNH . UNH ADU(Ammonium Diuranate) AUC(Ammonium Uranyl Carbonate) UO2 . #12; UO2 3.3% U

Hong, Deog Ki

391

Permanently charged tamoxifen derivatives: Chemical characterization, transcriptional activity, and biological effects  

Science Journals Connector (OSTI)

...methyl iodide, methyl bromide, ethyl bromide, isopropyl bromide, propyl bromide and butyl bromide) were obtained by SN2 reaction. Chemical structures were determined by NMR, electron microscopy and X-Ray diffraction. Biological effects: Binding...

Claudia Rivera Guevara; Rocio Garcia; Fernando Larrea; Martha S. Morales-Rios; Elizabeth Hermandez-Gallegos; David Barrera; Sandra Valencia; Victor Perez; and Javier Camacho

2007-11-01T23:59:59.000Z

392

TOXICOLOGY AND APPLIED PHARMACOLOGY 81,2 13-2 19 ( 1985) Role of Extracellular Ca*+ in Toxic Liver Injury: Comparative Studies  

E-Print Network (OSTI)

perfused liver and isolated hepatocytes. The toxins t-butyl- hydroperoxide and carbon tetrachloride on extracellular Ca2+ for cytotoxic injury to cultured hepato- cytes caused by carbon tetrachloride (CC&) and 2

California at Berkeley, University of

393

A PROTEOMIC STUDY OF OXIDATIVE STRESS IN ALCOHOLIC LIVER DISEASE  

E-Print Network (OSTI)

to oxidative stress with tert-butyl hydroperoxide (TBHP) contained 17% less carbonylated proteins than the non-fat loaded control. Mass spectrometric analysis of carbonylated proteins indicated that known classical markers of protein carbonylation (e...

Newton, Billy W.

2010-01-16T23:59:59.000Z

394

Method for cleaning solution used in nuclear fuel reprocessing  

DOE Patents (OSTI)

Nuclear fuel processing solution consisting of tri-n-butyl phosphate and dodecane, with a complex of uranium, plutonium, or zirconium and with a solvent degradation product such as di-n-butyl phosphate therein, is contacted with an aqueous solution of a salt formed from hydrazine and either a dicarboxylic acid or a hydroxycarboxylic acid, thereby removing the aforesaid complex from the processing solution.

Tallent, O.K.; Crouse, D.J.; Mailen, J.C.

1980-12-17T23:59:59.000Z

395

Non-phosphate degradation products of tributyl phosphate  

SciTech Connect

Tributyl phosphate(TBP) was compulsively degraded with nitric acid and/or uranium nitrate at elevated temperature around 105{degrees}C. Experimental results indicates major non-phosphate degradation products are butyl nitrate (C{sub 4}H{sub 9}NO{sub 3}), propionic acid (C{sub 2}H{sub 5}COOH), acetic acid (CH{sub 3}COOH), butyric acid (C{sub 3}H{sub 7}COOH) and butyl alcohol (C{sub 4}H{sub 9}OH) in ascending order of quantity. Degrading rate in uranium free system is less than that in uranium coexisting system. Carboxylic acids were not produced in uranium free system, and only acetic acid was identified in case of without supplying nitric acid from aqueous phase. Moreover, from the experimental study on the reactivity of each non-phosphate product with nitric acid, carboxylic acids were identified as byproducts of butyl alcohol and butyl nitrate, and each carboxylic acid was stable in these degrading conditions. Finally, butyl alcohol is considered as one of intermediate products to butyl nitrate and carboxylic acids. From this study, the non-phosphate degradation products of TBP is identified and the degrading reaction pass is proposed. Extraction behavior of each non-phosphate product and reactivity of degraded TBP are also elucidated.

Tashiro, Y.; Kodama, R.; Sugai, H. [Japan Nuclear Fuel Ltd., Aomori (Japan)] [and others

1995-12-01T23:59:59.000Z

396

SSRL HEADLINES April 2008  

NLE Websites -- All DOE Office Websites (Extended Search)

0 April, 2008 0 April, 2008 __________________________________________________________________________ Contents of this Issue: Science Highlight - Faster than the Speed of Melting Science Highlight - Taming Asthma-related Proteins Could Lead to Easier Breathing for Many LCLS Proposal Preparation Workshops Announced Other Upcoming Schools, Users' Meetings and Workshops JCSG Annual Meeting New Sample Preparation Laboratory Access Policies at SSRL User Administration Update __________________________________________________________________________ 1. Science Highlight - Faster than the Speed of Melting (contacts: A.M. Lindenberg, aaronl@slac.stanford.edu and K.J. Gaffney, kgaffney@slac.stanford.edu) The process of melting has long been of interest to scientists. In the case

397

Prediction of diet quality parameters of Rocky Mountain Elk via near infrared reflectance spectroscopy (NIRS) fecal profiling  

E-Print Network (OSTI)

?) of the National Council for Air and Stream Improvement (N.C.A.S.I.) bottle-raised and trained all the tame elk and built the research facilities at Boise Cascade Corporation?s Kamela, Ore., research site and provided needed information on the handling and care... heroes. Austin Blaney was always on hand to grind the many tons of forages or hammer nails in the construction of the elk feeding facility that we built. And to my friends Jim and Blanton Beard of Greenbranch Deer Farm, who loaned me the use...

Keating, Marvin Scott

2006-08-16T23:59:59.000Z

398

Stellar Astrophysics Requirements NERSC Forecast  

NLE Websites -- All DOE Office Websites (Extended Search)

Requirements for Requirements for m461:Stellar Explosions in Three Dimensions Tomek Plewa (Florida State University) + 3 graduate students, Artur Gawryszczak (Warsaw), Konstantinos Kifonidis (Munich), Andrzej Odrzywolek (Cracow), Ju Zhang (FIT), Andrey Zhiglo (Kharkov) 1. m461: Stellar Explosions in Three Dimensions * Summarize your projects and expected scientific objectives through 2014 * Modeling and simulations of transient phenomena in stellar astrophysics driven by either radiation or thermonuclear processes * Numerical solution of a coupled system of PDEs and ODEs * Tame nonlinearity! * Our goal is to ... * Explain observed properties of exploding stellar objects * Present focus is ... * Neutrino-driven core-collapse supernova explosions * In the next 3 years we expect to ...

399

Evidence for high-temperature diffusional creep preserved by rapid cooling of lower crust (North Bohemian shear zone,  

E-Print Network (OSTI)

high-grade orthogneiss, migmatite and granulite (Zartner, 1929), largely covered by Tertiary volcanics´ , 1962). Gran- ulite has been drilled in bore holes and occurs in xenoliths of Tertiary basalts (Kopecky; Kotkova´ et al., 1996). A similar for- mation age has been derived from garnet peridotite from borehole T7

Dörr, Wolfgang

400

COAL RESOURCES, POWDER RIVER BASIN By M.S. Ellis,1  

E-Print Network (OSTI)

Chapter PN COAL RESOURCES, POWDER RIVER BASIN By M.S. Ellis,1 G.L. Gunther,2 A.M. Ochs,2 S, Delaware 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky in the toolbar to return. 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

FORT UNION COAL IN THE GREATER GREEN RIVER BASIN, EAST FLANK OF THE ROCK SPRINGS UPLIFT,  

E-Print Network (OSTI)

Chapter GS FORT UNION COAL IN THE GREATER GREEN RIVER BASIN, EAST FLANK OF THE ROCK SPRINGS UPLIFT 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky in the toolbar to return. 1999 Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky

402

SHERIDAN COALFIELD, POWDER RIVER BASIN: GEOLOGY, COAL QUALITY, AND COAL RESOURCES  

E-Print Network (OSTI)

Chapter PH SHERIDAN COALFIELD, POWDER RIVER BASIN: GEOLOGY, COAL QUALITY, AND COAL RESOURCES By M assessment of selected Tertiary coal beds and zones in the Northern RockyMountains and Great Plains region, U Resource assessment of selected Tertiary coal beds and zones in the Northern Rocky Mountains and Great

403

Accommodation of a highly symmetric core within a symmetric protein superfold  

E-Print Network (OSTI)

threefold symmetry present in the tertiary structure of the protein fold (the -trefoil superfold factor; de novo design; superfold; protein evolution; -trefoil The protein-folding problem is one tertiary structures can be categorized into 1 of 10 fundamental protein folds (Orengo et al. 1994; Thornton

Blaber, Michael

404

IMPACT OF OXYGENATED FUEL ON DIESEL ENGINE PERFORMANCE AND EMISSIONS  

SciTech Connect

As evidenced by recent lawsuits brought against operators of large diesel truck fleets [1] and by the Consent Decree brought against the heavy-duty diesel manufacturers [2], the environmental and health effects of diesel engine emissions continue to be a significant concern. Reduction of diesel engine emissions has traditionally been achieved through a combination of fuel system, combustion chamber, and engine control modifications [3]. Catalytic aftertreatment has become common on modern diesel vehicles, with the predominant device being the diesel oxidation catalytic converter [3]. To enable advanced after-treatment devices and to directly reduce emissions, significant recent interest has focused on reformulation of diesel fuel, particularly the reduction of sulfur content. The EPA has man-dated that diesel fuel will have only 15 ppm sulfur content by 2007, with current diesel specifications requiring around 300 ppm [4]. Reduction of sulfur will permit sulfur-sensitive aftertreatment devices, continuously regenerating particulate traps, NOx control catalysts, and plasma assisted catalysts to be implemented on diesel vehicles [4]. Another method of reformulating diesel fuel to reduce emissions is to incorporate oxygen in the fuel, as was done in the reformulation of gasoline. The use of methyl tertiary butyl ether (MTBE) in reformulated gasoline has resulted in contamination of water resources across the country [5]. Nonetheless, by relying on the lessons learned from MTBE, oxygenation of diesel fuel may be accomplished without compromising water quality. Oxygenation of diesel fuel offers the possibility of reducing particulate matter emissions significantly, even for the current fleet of diesel vehicles. The mechanism by which oxygen content leads to particulate matter reductions is still under debate, but recent evidence shows clearly that ''smokeless'' engine operation is possible when the oxygen content of diesel fuel reaches roughly 38% by weight [6]. The potential improvements in energy efficiency within the transportation section, particularly in sport utility vehicles and light-duty trucks, that can be provided by deployment of diesel engines in passenger cars and trucks is a strong incentive to develop cleaner burning diesel engines and cleaner burning fuels for diesel engines. Thus, serious consideration of oxygenated diesel fuels is of significant practical interest and value to society. In the present work, a diesel fuel reformulating agent, CETANERTM, has been examined in a popular light-medium duty turbodiesel engine over a range of blending ratios. This additive is a mixture of glycol ethers and can be produced from dimethyl ether, which itself can be manufactured from synthesis gas using Air Products' Liquid Phase Dimethyl Ether (LPDME TM) technology. CETANERTM is a liquid, has an oxygen content of 36 wt.%, has a cetane number over 100 and is highly miscible in diesel fuel. This combination of physical and chemical properties makes CETANERTM an attractive agent for oxygenating diesel fuel. The present study considered CETANERTM ratios from 0 to 40 wt.% in a California Air Resources Board (CARB) specification diesel fuel. Particulate matter emissions, gaseous emissions and in-cylinder pressure traces were monitored over the AVL 8-Mode engine test protocol [7]. This paper presents the results from these measurements and discusses the implications of using high cetane number oxygenates in diesel fuel reformulation.

Boehman, Andre L.

2000-08-20T23:59:59.000Z

405

DME-to-oxygenates process studies  

SciTech Connect

The feasibility of the production of hydrocarbons from dimethyl ether (DNM) has been illustrated in a fixed bed micro-reactor as well as a bench scale fluidized bed reactor by the University of Akron/EPRI DME-to-Hydrocarbon (DTG) Process. The DTG process has distinct advantages over its methanol based counterpart. Specifically, the DTG process excels in the area of higher productivity, higher per-pass conversion, and lower heat duties than the MTG process. Also of special importance is the production of oxygenates -- including MTBE, ETBE, and TAME. DME may be reacted with isobutylene to produce a mixture of MTBE and ETBE. The properties of ETBE excel over MTBE in the areas of lower RVP and higher RON. According to industrial reports, MTBE is the fastest growing chemical (1992 US capacity 135,350 BPD, with expected growth of 34%/year to 1997). Also, recent renewed interest as an octane-enhancer and as a source of oxygen has spurred a growing interest in nonrefinery synthesis routes to ETBE. TAME, with its lower RVP and higher RON has proven useful as a gasoline blending agent and octane enhancer and may also be produced directly from DME. DME, therefore, serves as a valuable feedstock in the conversion of may oxygenates with wide-scale industrial importance. It should be also noted that the interest in the utilization of DME as process feedstock is based on the favorable process economics of EPRI/UA`s liquid phase DME process.

Tartamella, T.L.; Sardesai, A.; Lee, S. [Univ. of Akron, OH (United States); Kulik, C.J. [Electric Power Research Inst., Palo Alto, CA (United States)

1994-12-31T23:59:59.000Z

406

Thermodynamic properties of organic oxygen compounds XLIII. Vapour pressures of some ethers  

Science Journals Connector (OSTI)

Vapour pressures of methyl propyl, isopropyl methyl, butyl methyl, ethyl propyl, t-butyl methyl, dipropyl, di-isopropyl, di-t-butyl, and decyl methyl ethers were measured at pressures up to 205 kPa. The measured values were fitted by Antoine and by Chebyshev equations, values already published from this laboratory for three aromatic ethers were recomputed uniformly with the present results, and published values for four additional compounds were incorporated in a scheme for correlation of the vapour pressures of ethers. Estimates were made of the vapour pressures of 10 other ethers. Between 5 and 200 kPa the vapour pressures of ethers may be represented by a single equation in which carbon number or an effective carbon number is a parameter. Chebyshev equations are given for interpolation between the upper bounds of the measurements and the critical pressures of 11 ethers for which this property has been previously determined.

D Ambrose; J.H Ellender; C.H.S Sprake; R Townsend

1976-01-01T23:59:59.000Z

407

Reactivity of tributyl phosphate degradation products with nitric acid: Relevance to the Tomsk-7 accident  

SciTech Connect

The reaction of a degraded tributyl phosphate (TBP) solvent with nitric acid is thought to have caused the chemical explosion at the Tomsk-7 reprocessing plant at Tomsk, Russia in 1993. The estimated temperature of the organic layer was not high eneough to cause significant reaction of nitric acid with TBP or hydrocarbon diluent compounds. A more reactive organic compound was likely present in the organic layer that reacted with sufficient heat generation to raise the temperature to the point where an autocatalytic oxidation of the organic solvent was initiated. Two of the most likely reactive compounds that are present in degraded TBP solvents are n-butanol and n-butyl nitrate. The reactions of these compounds with nitric acid are the subject of this study. The objective of laboratory-scale tests was to identify chemical reactions that occur when n-butanol and n-butyl nitrate contact heated nitric acid solutions. Reaction products were identified and quantitified, the temperatures at which these reactions occur and heats of reaction were measured, and reaction variables (temperature, nitric acid concentration, organic concentration, and reaction time) were evaluated. Data showed that n-butyl nitrate is less reactive than n-butanol. An essentially complete oxidation reaction of n-butanol at 110-120 C produced four major reaction products. Mass spectrometry identified the major inorganic oxidation products for both n-butanol and n-butyl nitrate as nitric oxide and carbon dioxide. Calculated heats of reaction for n-butanol and n-butyl nitrate to form propionic acid, a major reaction product, are -1860 cal/g n-butanol and -953 cal/g n-butyl nitrate. These heats of reaction are significant and could have raised the temperature of the organic layer in the Tomsk-7 tank to the point where autocatalytic oxidation of other organic compounds present resulted in an explosion.

Barney, G.S.; Cooper, T.D. [Westinghouse Hanford Company, Richland, WA (United States)

1995-12-31T23:59:59.000Z

408

Synthesis and Opioid Activity of [d-Pro10]Dynorphin A-(1?11) Analogues with N-Terminal Alkyl Substitution  

Science Journals Connector (OSTI)

Tyrosine tert-butyl ester (0.5?1.0 g, Sigma Chemical Co., St. Louis, MO) was dissolved in DMF (2 mL/mmol TyrOtBu), and N,N-diisopropylethylamine (DIEA, 2.5 equiv) was added to the solution dropwise, followed by alkyl bromide (6?7 equiv). ... The tert-butyl group was cleaved as described above and the free acid crystallized from Et2O (142 mg, 20%):? mp 243?244 °C; FAB-MS 222 (M + 1); HPLC tR = 3.6 min (99% purity). ...

Heekyung Choi; Thomas F. Murray; Gary E. DeLander; William K. Schmidt; Jane V. Aldrich

1997-08-15T23:59:59.000Z

409

Radioisotope Thermoelectric Generator Package O-Ring Seal Material Validation Testing  

SciTech Connect

The Radioisotope Thermoelectric Generator Package O-Ring Seal Material Validation Test was conducted to validate the use of the Butyl material as a primary seal throughout the required temperature range. Three tests were performed at (1) 233 K ({minus}40 {degrees}F), (2) a specified operating temperature, and (3) 244 K ({minus}20 {degrees}F) before returning to room temperature. Helium leak tests were performed at each test point to determine seal performance. The two major test objectives were to establish that butyl rubber material would maintain its integrity under various conditions and within specified parameters and to evaluate changes in material properties.

Adkins, H.E.; Ferrell, P.C.; Knight, R.C.

1994-09-30T23:59:59.000Z

410

Before enzymes and templates: theory of surface metabolism.  

Science Journals Connector (OSTI)

...52, No. 4 MICROBIOLOGICAL REVIEWS, Dec. 1988, p. 452-484...480 LITERATURE CITED...This tertiary source of bioenergy is at first dependent on the...been of immeasurable value. LITERATURE CITED 1. Acevedo, 0. L...

G Wächtershäuser

1988-12-01T23:59:59.000Z

411

The VP4 Peptide of Hepatitis A Virus Ruptures Membranes through Formation of Discrete Pores  

Science Journals Connector (OSTI)

...predicted using Bhageerath-H (a homology ab initio hybrid web server for protein tertiary structure prediction) (22 - 26...D Sahu, and V Pandey. 2006. Bhageerath: an energy based web enabled computer software suite for limiting the search space...

Ashutosh Shukla; Aditya K. Padhi; James Gomes; Manidipa Banerjee

2014-08-13T23:59:59.000Z

412

Deformation, erosion and sedimentation in collisional orogens : case studies from eastern Tibet and southwestern China  

E-Print Network (OSTI)

This dissertation addresses aspects of the tectonics of regions adjacent to the eastern Himalayan syntaxis. The first chapter describes the Tertiary Gonjo basin, includes structural and sedimentologic observations, and ...

Studnicki-Gizbert, Christopher Terrance

2006-01-01T23:59:59.000Z

413

We offer a full range of surgical expertise. Bariatric Surgery  

E-Print Network (OSTI)

CARE MARS Medical Access and Referral System 800-WVA-MARS 800-982-6277 24-hour, 7-day per week are a major tertiary referral center for the region and state, offering the highest level of clinical

Mohaghegh, Shahab

414

Petroleum Supply Monthly  

Gasoline and Diesel Fuel Update (EIA)

or pipeline. Tertiary inventories are held by end users and include fuel in vehicle tanks, heating oil in residential tanks, fuel oil held by utilities, jet fuel stored in...

415

On the Fossil Algae of the Petroleum-Yielding Shales of the Green River Formation of Colorado and Utah  

Science Journals Connector (OSTI)

...georef/georef;1975057021 algae biostratigraphy Cenozoic Colorado Eocene Green River Formation microfossils occurrence oil shale organic residues paleobotany Paleogene Plantae sedimentary rocks Tertiary United States Utah GeoRef, Copyright 2004...

Charles A. Davis

1916-01-01T23:59:59.000Z

416

E-Print Network 3.0 - atlantic igneous province Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

modied from White and McKenzie 1. Also... 70 My prior to the Tertiary eruption of CFB of ... Source: Johnston, Stephen T. - School of Earth and Ocean Sciences, University of...

417

Pediatric Intestinal Failure Associated Liver Disease is Revered with Six Months of Intravenous Fish Oil  

E-Print Network (OSTI)

3. Secondary and tertiary outcomes for the fish oil (FO)and soybean oil (SO) group. Results are either as medianserror of the mean for the fish oil (FO) and soybean oil (SO)

Calkins, Kara

2013-01-01T23:59:59.000Z

418

Optimizing hysteretic power loss of magnetic ferrite nanoparticles  

E-Print Network (OSTI)

This thesis seeks to correlate hysteretic power loss of tertiary ferrite nanoparticles in alternating magnetic fields to trends predicted by physical models. By employing integration of hysteresis loops simulated from ...

Chen, Ritchie

2013-01-01T23:59:59.000Z

419

E-Print Network 3.0 - azeite transtensional shear Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

> >> Page: << < 1 2 3 4 5 > >> 41 Tertiary Evolution of the Three Pagodas Fault, Western Thailand Summary: ductile left-lateral shear zone in a transpressional environment as it...

420

E-Print Network 3.0 - aliphatic alkyl quaternaries Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

to almost... (e.g. Ar-Cl, tertiary amine, quaternary amine) NuH R'R"NH 11CCarbon Monoxide - In ring closure... is a nucleophilic subsitition of bisulfite by 11Ccyanide ion...

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Mechanisms Controlling Phosphorus Retention Capacity in Freshwater Wetlands  

Science Journals Connector (OSTI)

...Wetlands tested as wastewater filtration systems...HOOK, J.E., RECYCLING TREATED MU 148...WETLANDS AS A TERTIARY WASTEWATER-TREATMENT ALTERNATIVE...E. Sopper, in Recycling Treated Municipal Wastewater and Sludge Through...

CURTIS J. RICHARDSON

1985-06-21T23:59:59.000Z

422

Geranic Acid Formation, an Initial Reaction of Anaerobic Monoterpene Metabolism in DenitrifyingAlcaligenes defragrans  

Science Journals Connector (OSTI)

...transformation of a tertiary allylalchol: regioselective isomerisation of linalool to geraniol without nerol formation. . S. Fobeta...alkenoic monoterpenes (()-menthene, a-pinene, 2-carene and a-phellandrene) and nitrate. . G. Fuchs Novel reactions...

Udo Heyen; Jens Harder

2000-07-01T23:59:59.000Z

423

Eocene cooling linked to early flow across the Tasmanian Gateway  

Science Journals Connector (OSTI)

...gradients between oceanic basins lend additional support for increased...Malone MJ ( 2000 ) Great Australian Bight—Cenozoic cool-water...Tertiary of the Gippsland Basin, Victoria . APEA J...Malone MJ (2000) Great Australian Bight--Cenozoic...

Peter K. Bijl; James A. P. Bendle; Steven M. Bohaty; Jörg Pross; Stefan Schouten; Lisa Tauxe; Catherine E. Stickley; Robert M. McKay; Ursula Röhl; Matthew Olney; Appy Sluijs; Carlota Escutia; Henk Brinkhuis; Expedition 318 Scientists

2013-01-01T23:59:59.000Z

424

Membrane Bioreactors: Past, Present and Future?  

E-Print Network (OSTI)

Treatment, Elsevier King County Brightwater WastewaterJudd and Judd, 2006 ], King County, WA, USA (136,000 m3 /d in 2011) [King County] and tertiary treatment at

Hermanowicz, Slav W

2011-01-01T23:59:59.000Z

425

[superscript 15]N-[superscript 15]N Proton Assisted Recoupling in Magic Angle Spinning NMR  

E-Print Network (OSTI)

We describe a new magic angle spinning (MAS) NMR experiment for obtaining [superscript 15]N?[superscript 15]N correlation spectra. The approach yields direct information about the secondary and tertiary structure of proteins, ...

Lewandowski, Jozef R.

426

CX-007922: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Game Changing Technology of Polymeric-Surfactants for Tertiary Oil CX(s) Applied: A9, B3.6 Date: 02/23/2012 Location(s): California Offices(s): National Energy Technology Laboratory

427

CX-007928: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Game Changing Technology of Polymeric-Surfactants for Tertiary Oil CX(s) Applied: A9, B3.6 Date: 02/22/2012 Location(s): Indiana Offices(s): National Energy Technology Laboratory

428

Geological Development of Panama  

Science Journals Connector (OSTI)

The Panama that geologists see today is a young ... /early Tertiary time. The geological development of Panama is a consequence of the relative motions ... igneous rocks that comprise much of present-day Panama f...

Russell S.Harmon

2005-01-01T23:59:59.000Z

429

Salt deformation history and postsalt structural trends, offshore southern Gabon, West Africa  

SciTech Connect

Salt deformation in offshore southern Gabon is represented by mobilization of an Aptian salt layer in reaction to Tertiary clastic progradation. Seismic mapping of salt bodies and associated faulting has resulted in increased understanding of the types and distribution of these salt bodies, their associated faulting patterns, and some aspects of their origin. Away from the Tertiary depocenter, the growth history of salt swells or pillows can be determined by examining onlapping and draping seismic reflectors. Significant Tertiary clastic progradation into the area mobilized the salt and resulted in a series of linear, deep salt walls and asymmetric, basinward-dipping salt rollers, commonly associated with significant up-to-basin faulting dominates the southern Gabon subbasin. The expansion history of associated sediments suggests that these faults expanded episodically throughout the Tertiary, continuing to present-day bathymetric fault scarps. The bias toward up-to-basin faults, to the apparent exclusion of down-to-basin expansion faults, remains enigmatic.

Liro, L.M. [Texaco Exploration and Production Technology Dept., Houston, TX (United States); Coen, R. [British Gas, Houston, TX (United States)

1996-12-31T23:59:59.000Z

430

Gabon, Congo, Cabinda and Zaïre  

Science Journals Connector (OSTI)

The combined coastline of Gabon, Congo, Cabinda (a separate province of...1985...). It forms the oceanic boundary of two Mesozoic and Tertiary sedimentary basins, those of Gabon and the Congo, which are separated...

P. Giresse

2010-01-01T23:59:59.000Z

431

Palaeobotanical studies from tropical Africa: relevance to the evolution of forest, woodland and savannah biomes  

Science Journals Connector (OSTI)

...time interval coincides with the Eocene thermal maximum, a time of warm temperatures...Morley 2000; Sloan & Rea 1995). The thermal budget and dynamics of the hydrological...Tertiary nonmarine sediments of central Sudan. Palynology 13, 7990. Kedves, M...

2004-01-01T23:59:59.000Z

432

Evidence for Large-Scale Laramide Tectonic Inversion and a Mid...  

Open Energy Info (EERE)

Scale Laramide Tectonic Inversion and a Mid-Tertiary Caldera Ring Fracture Zone at the Lightning Dock Geothermal System, New Mexico Jump to: navigation, search OpenEI Reference...

433

Detection of Radon Emission at the Edges of Lunar Maria with the Apollo Alpha-Particle Spectrometer  

Science Journals Connector (OSTI)

...ecological balance away from...by advanced wastewater treatment. Both wastewater...tertiary sewage treatment or change...Physiol. Plant. 23, 828...Both advanced wastewater treatment and 1 FEBRUARY...bombardment or mass slumping...

Paul Gorenstein; Leon Golub; Paul Bjorkholm

1974-02-01T23:59:59.000Z

434

Protein folding and macromolecular dynamics : fundamental limits of length and time scales.  

E-Print Network (OSTI)

??In this thesis, physics-based models of protein folding at the secondary and tertiary level are developed to resolve long-standing issues of protein folding kinetics. As… (more)

Lin, Milo M.

2012-01-01T23:59:59.000Z

435

Adding a Medical Lexicon to an English Parser Peter Szolovits, PhD  

E-Print Network (OSTI)

in the Emergency Department of a large urban tertiary care pediatric hospital (ED), the Link Grammar Parser (LP) [3 summaries, radiology and pathology notes, etc., are nevertheless stored simply as text. 2 This assumes

Szolovits, Peter

436

Volcanology  

Science Journals Connector (OSTI)

...now appears, how-ever, that such heating is probably relatively unimportant...Richey, Scotland: The Tertiary Volcanic Districts (His Majesty's Stationery Office...made by Samuel Strauss, lately of the District of Co-lumbia public school system...

Gordon A. MacDonald

1961-03-10T23:59:59.000Z

437

Tectonic Evolution of the Contaya Arch Ucyali Basin, Peru  

E-Print Network (OSTI)

after deposition of the Pozo Formation sands and shales. To the east of this is the Contaya high. This structure originally formed during the Triassic-Jurassic and was later reactivated in the Tertiary. The easternmost structure, the Moa divisor...

Navarro Zelasco, Luis

2011-08-08T23:59:59.000Z

438

Large Hadron Collider commissioning and first operation  

Science Journals Connector (OSTI)

...systems [4], including the collimation system [5], are crucial in the...finalizing the protection. The collimation system [5] is part of the machine...machine. The hierarchy of the collimation system (primary, secondary and tertiary...

2012-01-01T23:59:59.000Z

439

"Simple paperwork made applying for a loan very easy."  

E-Print Network (OSTI)

Commission Public Programs Office (916) 654-4147 pubprog@energy.state.ca.us See Case Study on Back of Flyer at the adjacent wastewater treatment plant. Recently the city upgraded the plant to tertiary wastewater treatment

440

E-Print Network 3.0 - asymmetric horner-wadsworth-emmons reactions...  

NLE Websites -- All DOE Office Websites (Extended Search)

an Ireland-Claisen rearrangement to install the C7 tertiary alcohol stereocenter, an SN2 reaction... nucleo- phile.14 SN2 reactions of alkoxyalkyl Cu nucleophiles are not well...

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Equilibrium and hydrodynamic studies of water extraction from fermentation broth  

E-Print Network (OSTI)

Previous studies using tertiary amines to extract water from reagent-grade carboxylate salts (calcium acetate, propionate, and butyrate) have shown selectivity for water and not for the carboxylate salts. These results allow the design...

Adorno-Gomez, Wilberto

2012-06-07T23:59:59.000Z

442

GEOLOGY AND HYDROTHERMAL ALTERATION OF THE RAFT RIVER GEOTHERMAL...  

Open Energy Info (EERE)

the base of the Tertiary deposits in RRG-9. The results of thermal and quasi-static mechanical property measurements that were conducted on the core sample are presented. Authors...

443

Petrology of clinopyroxene-amphibole inclusions from the roque nublo volcanics, gran canaria, canary islands  

Science Journals Connector (OSTI)

Inclusions consisting of clinopyroxene, amphibole, Fe-Ti oxides and apatitc are abundant in the Roque Nublo volcanics, a unit of Late Tertiary age that is widespread on Gran Canaria Island. The unit includes alka...

T. Frisch; H. U. Schmincke

1969-01-01T23:59:59.000Z

444

Enhanced Oil Recovery Using the Alkaline-Surfactant-Polymer (ASP)  

E-Print Network (OSTI)

Alkaline Surfactant Polymer (ASP) process is a tertiary method of oil recovery that has promising results for future development. It has already been implemented in different areas of the United States such as Wyoming, west Texas, also in Canada...

Musharova, Darya

2010-07-14T23:59:59.000Z

445

Surfactant-Polymer Interaction for Improved Oil Recovery  

SciTech Connect

The goal of this research was to use the interaction between a surfactant and a polymer for efficient displacement of tertiary oil by improving slug integrity, oil solubility in the displacing fluid and mobility control. Surfactant-polymer flooding has been shown to be highly effective in laboratory-scale linear floods. The focus of this proposal is to design an inexpensive surfactant-polymer mixture that can efficiently recover tertiary oil by avoiding surfactant slug degradation and viscous/heterogeneity fingering.

Gabitto, Jorge; Mohanty, Kishore K.

2002-01-07T23:59:59.000Z

446

Range Con: a management evaluation system for assessing sucess of selected range improvement practices  

E-Print Network (OSTI)

interview, and 80 identified agency/academic and rancher tertiary experts interviewed with a questionnaire. Responses from the tertiary experts were used to assign weight to values of the object/attribute/value triplet. Face validation procedures... success he assigned to the evaluation due to his greater level of knowledge associated with the technology. Range management experts experience the same processes, which often leads them to recommend technology to ranchers that exceeds the ranchers...

Ekblad, Steven Linn

2012-06-07T23:59:59.000Z

447

Cenozoic evidence of displacements along the Meers Fault, southwestern Oklahoma  

E-Print Network (OSTI)

which had been deposited over this Tertiary surface. The remnant pediment surfaces in the Wichita Mountains may then be used as a relative datum horizon in interpreting Tertiary and younger displacements within the region. ACKNOWLEDGEMENTS I would...) Schematic diagram of the Pointer Site Excavations 34 36 10 A) The buried soil and caliche-clay deposits exhibiting plane of compaction between the upper- and lower-orange deposits. 8) Close-up of caliche-clay deposit. . . . . . 38 Photograph comparing...

Kientop, Gregory Allen

2012-06-07T23:59:59.000Z

448

Shallow meteoric alteration and burial diagenesis of massive dolomite in the Castle Reef Formation, northwest Montana  

E-Print Network (OSTI)

Precambrian (750 + 25 Ma; Mudge, et al. , 1968) and very Late Cretaceous to early Tertiary (Mudge, 1972). Any formation or recrystallization of dolomite by hydrothermal fluids must have occurred before the Jurassic since pre-Jurassic dolomite overgrowths... Precambrian (750 + 25 Ma; Mudge, et al. , 1968) and very Late Cretaceous to early Tertiary (Mudge, 1972). Any formation or recrystallization of dolomite by hydrothermal fluids must have occurred before the Jurassic since pre-Jurassic dolomite overgrowths...

Whitsitt, Philip Mark

2012-06-07T23:59:59.000Z

449

Theory Seminar Schedule  

NLE Websites -- All DOE Office Websites (Extended Search)

7-2008 7-2008 Click on a title to read an abstract, if available (underlined). 12 June 2008 Kristina Sviratcheva Louisiana State University kristina@rouge.phys.lsu.edu Symplectic Ab Initio No-Core Shell Model - Taming the Model Space Dilemma 5 June 2008 Wick Haxton INT, University of Washington haxton@u.washington.edu Probing Time-odd Moments in Atoms and Nuclei 1 May 2008 Wolfgang Bentz Tokai University, Japan bentz@keyaki.cc.u-tokai.ac.jp Fragmentation functions in an effective quark theory 17 April 2008 Special Time: 10:30am Dmitry G. Yakovlev Ioffe Physico-Technical Institute, St.Petersburg yak@astro.ioffe.rssi.ru Landau and Neutron Stars Tuesday 15 April 2008 Special Day Jochen Wambach GSI and TU Darmstadt J.Wambach@gsi.de Viscosity in the Nambu--Jona-Lasinio Model Tuesday 8 April 2008

450

MIT Plasma Science & Fusion Center: research, alcator, publications & news,  

NLE Websites -- All DOE Office Websites (Extended Search)

1st Annual Meeting of the APS Division of Plasma Physics, Atlanta, 2009 1st Annual Meeting of the APS Division of Plasma Physics, Atlanta, 2009 Invited Orals I. Cziegler Structures and Velocities of the Edge Turbulence in Alcator C-Mod M. Greenwald Verification and Validation for Magnetic Fusion: Moving Toward Predictive Capability J. Hughes Edge Pedestal and Confinement Regulation on Alcator C-Mod L. Lin Comparison of Experimental Measurements and Gyrokinetic Turbulent Electron Transport Models in Alcator C-Mod Plasmas M. Porkolab Taming Magnetically Confined Plasmas with RF Waves: a Historical Perspective S. Shiraiwa Plasma Wave Simulation Based on a Versatile FEM Solver on Alcator C-Mod D. Whyte Runaway Electron Transport & Disruption Mitigation Optimization on Alcator C-Mod Contributed Orals B. Bose Studies of Filament Formation during Lithium Pellet Injection in Alcator C-Mod

451

Turkeys  

NLE Websites -- All DOE Office Websites (Extended Search)

No. 619 November 26, 1960 No. 619 November 26, 1960 Forest Preserve District of Cook County Daniel Ryan, President Roberts Mann, Conservation Editor David H. Thompson, Senior Naturalist TURKEYS : WILD AND DOMESTICATED The story of the first Thanksgiving in 1621 and of the wild "Turkies" which the Pilgrims hunted to provide meat for the feast is familiar to every American. Today, although very few of us can claim that we had ancestors on the Mayflower, a lot of us imagine that our Thanksgiving bird is descended from those wild turkeys. This is not quite correct. A century before, in Mexico, the early Spanish adventurers had found Indians raising turkeys around their homes. The Aztec emperor, Montezuma, kept them in his famous zoo, it is said, as food for the other animals. It is not known how long those Mexican birds had been tamed and bred but they are the true ancestors of our only domestic animal with an origin in North America.

452

Abstract for Kristina D. Sviratcheva  

NLE Websites -- All DOE Office Websites (Extended Search)

Kristina D. Sviratcheva Kristina D. Sviratcheva Louisiana State University Symplectic Ab Initio No-Core Shell Model - Taming the Model Space Dilemma Understanding the origin, structure, and phases of hadronic matter is a forefront research area in physics. An integral part of this challenge is to achieve realistic modeling of the complex dynamics of atomic nuclei, which is key to comprehending the evolution of the universe from a fundamental quark-gluon level. We recently demonstrated the potential power of an innovative concept, the ab initio symplectic no-core shell model (Sp-NCSM), based on expanding the conventional harmonic oscillator basis in terms of the symmetry-adapted and physically relevant symplectic basis, to reach new domains of nuclear structure. Using realistic interactions tied

453

NREL: News Feature - OpenStudio Visualizes Energy Use in Buildings  

NLE Websites -- All DOE Office Websites (Extended Search)

OpenStudio Visualizes Energy Use in Buildings OpenStudio Visualizes Energy Use in Buildings March 8, 2011 Lo ok around you. Odds are, you are indoors reading this story using a computer or mobile device, perhaps sipping on a favorite cup of coffee. If you are indoors at this moment, you're draining energy from one of the largest consumers of energy in the U.S. - a building. Together, residential and commercial buildings account for a staggering 40 percent of energy use in the United States. However, the U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL) is developing a suite of tools to tame this energy beast - and it is free to anyone who wants to use it. Whether retrofitting existing buildings or designing new buildings, energy modeling is a core component to changing a building from an energy guzzler

454

Top ECMs for Labs and Data Centers  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Top ECMs for Labs and Top ECMs for Labs and Data Centers FUPWG Otto Van Geet, PE October 10, 2012 2 Labs are Energy Hogs! * 3 to 8 times as energy intensive as office buildings Total Site Energy Use Intensity BTU/sf-yr for various laboratories in the Labs21 Benchmarking Database Typical Office Building 3 * Core information resources - Design Guide - Case Studies - Energy Benchmarking - Best Practice Guides - Technical Bulletins * Design process tools - Env. Performance Criteria - Labs21 Process Manual Labs21 Toolkit 4 Six BIG HITS 1. Scrutinize the air changes: Optimize ventilation rates 2. Tame the hoods: Compare exhaust device options 3. Get real with loads: Right-size HVAC systems 4. Just say no to re-heat: Minimize simultaneous heating and cooling 5. Drop the pressure drop:

455

60 Years Since Nuclear Turned on the Lights | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

60 Years Since Nuclear Turned on the Lights 60 Years Since Nuclear Turned on the Lights 60 Years Since Nuclear Turned on the Lights December 20, 2011 - 10:50am Addthis Niketa Kumar Niketa Kumar Public Affairs Specialist, Office of Public Affairs "We have moved far to tame for peaceful uses the mighty forces unloosed when the atom was split." President Johnson, 1966 At 1:23pm on December 20, 1951, Argonne National Laboratory director Walter Zinn scribbled into his log book, "Electricity flows from atomic energy. Rough estimate indicates 45 kw." At that moment, scientists from Argonne and the National Reactor Testing Station, the forerunner to today's Idaho National Laboratory, watched four light bulbs glow, powered by the world's first nuclear reactor to generate electricity. Fifteen years later, in Arco, Idaho, President Johnson stood at this same

456

Influence of the nature of FCC feed on the production of light olefins by catalytic cracking  

SciTech Connect

The 1990 Clean Air Act has act rules for gasoline reformulation, which requires major compositional changes, Including a higher contribution of oxygenated compounds to the gasoline pool. This explains why FCC units are expected to play a major role in the coming years as a producer of light olefins (propylene, butenes and amylenes) to be used as feedstock for oxygenate (MTBE/TAME) production. The impact of the nature of FCC feedstock on light olefins production (C3 to C5 olefins) has been studied using a MAT unit running at various operating conditions (C/O ratio, reactor temperature). Paraffinic feeds are potentially efficient to produce light olefins by catalytic cracking. Heavier paraffinic feeds like mixtures VGO + reside and pure reside have also been evaluated, and compared to naphthenic and aromatic feeds.

Chapus, Th.; Cauffriez, H.; Marcilly, Ch. [Institut Francais du Petrole, Rueil-Malmaison (France)

1996-10-01T23:59:59.000Z

457

American Fusion News | Princeton Plasma Physics Lab  

NLE Websites -- All DOE Office Websites (Extended Search)

American Fusion News American Fusion News General Atomics (GA) December 4, 2012 The Scorpion's Strategy: "Catch and Subdue" December 4, 2012 Frozen Bullets Tame Unruly Edge Plasmas in Fusion Experiment February 15, 2012 General Atomics (GA) Fusion News: A New Spin on Understanding Plasma Confinement See All Massachusetts Institute of Technology (MIT) April 5, 2013 Applying physics, teamwork to fusion energy science February 22, 2013 A Tour of Plasma Physics in Downtown Cambridge December 4, 2012 Placing Fusion Power on a Pedestal September 21, 2012 MASSACHUSETTS INSTITUTUE OF TECHNOLOGY See All National Ignition Facility February 22, 2013 Summary of Assessment of Prospects for Inertial Fusion Energy February 16, 2012 National Ignition Facility (NIF): Under Pressure: Ramp-Compression Smashes

458

Windmills  

NLE Websites -- All DOE Office Websites (Extended Search)

Windmills Windmills Nature Bulletin No. 558-A March 15, 1975 Forest Preserve District of Cook County George W. Dunne, President Roland F. Eisenbeis, Supt. of Conservation WINDMILLS Two products of Yankee ingenuity -- barbed wire and the windmill -- played leading parts in the taming of the Wild West. Windmills made it possible to build the railroads and establish the ranches and farms which now occupy the Great Plains from Canada to Mexico. In that vast territory, once known as "The Great American Desert, " the annual rainfall is less than 20 inches -- frequently much less. Unless you have lived there, you cannot realize how terribly hot and dry that country becomes, nor how hard the winds may blow incessantly for days, weeks or even months. Windmills made it possible to pump, from veins far underground, water that was more precious than gold.

459

Metal–organic frameworks of the MIL-101 family as heterogeneous single-site catalysts  

Science Journals Connector (OSTI)

...of hydrocarbons with green oxidants-O2 and tert-butyl...resistance to common solvents and thermal stability...dAcetone was used as solvent. Table 4. Cyclic carbonate...and Y. Ikushima 2008 Solvent-free allylic oxidation...as starting material. Green Chem 5, 497-507...

2012-01-01T23:59:59.000Z

460

Mechanisms of growth inhibition induced by methylene-substituted and ring-substituted dims in breast cancer cells  

E-Print Network (OSTI)

-MB-231 and MDA-MB-453 breast cancer cell growth was inhibited after treatment with a novel series of methylenesubstituted DIMs (C-DIMs), namely 1,1-bis(3’-indolyl)-1-(p-substitutedphenyl) methanes containing trifluoromethyl (DIM-C-pPhCF3), t-butyl (DIM...

Vanderlaag, Kathryn Elisabeth

2009-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Fatty Acids from Plasmodium falciparum Down-Regulate the Toxic Activity of Malaria Glycosylphosphatidylinositols  

Science Journals Connector (OSTI)

...PI) and less sphingomyelin than the plasma membrane of normal uninfected erythrocytes...volume) by sonication (Branson 3200; 47 MHz), and recovered in the n-butyl alcohol...medium, and incubated at 37C in a 5% CO2 atmosphere for 24 h with medium containing the molecules...

Françoise Debierre-Grockiego; Louis Schofield; Nahid Azzouz; Jörg Schmidt; Cristiana Santos de Macedo; Michael A. J. Ferguson; Ralph T. Schwarz

2006-10-01T23:59:59.000Z

462

Cytoprotective Effects of Dietary Fatty Acids on Oxidative Stress in Hepatocytes  

E-Print Network (OSTI)

common dietary fatty acids to subsequent inflammation and stress. Hepatocytes (HepG2 cell line) were treated with oleic, linoleic and palmitic acid at different concentrations and exposed to the pro-oxidant tert-butyl hydroperoxide (t-BHP) to induce...

Richardson, Thomas C

2012-07-11T23:59:59.000Z

463

E-Print Network 3.0 - alkyl-tert alkyl ethers Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

> >> 1 7198 J. Org. Chem. 1995,60, 7198-7208 Gas Phase Decomposition of Conjugate Acid Ions of Simple Summary: of ProtonatedAlkyl tert-ButylEthers RO(H)C(CH&+ (To.6 Values in meV...

464

An investigation of the burning rates of thin films of some selected composite propellants  

E-Print Network (OSTI)

Ammoni a/Perch 1 ori c Aci d Aluminum Atmospheres butyl Acetate Carbon Glass Cyclo tetramethylenetetrani tr amine L ad Azide IicCormick-Selph Methyl Fthyl Ketone IIitrocelIulose Oxidizer/Fue'I x-104, x-164 NcCormick-Selph material 300, 104...

Sawyer, Miles Lee

1970-01-01T23:59:59.000Z

465

A recoverable versatile photo-polymerization initiator catalyst  

E-Print Network (OSTI)

A photo-polymerization initiator based on an imidazolium and an oxometalate, viz., (BMIm)2(DMIm) PW12O40 (where, BMIm = 1-butyl-3-methylimizodium, DMIm = 3,3'-Dimethyl-1,1'-Diimidazolium) is reported. It polymerizes several industrially important monomers and is recoverable hence can be reused. The Mn and PDI are controlled and a reaction pathway is proposed.

Chen, Dianyu; Roy, Soumyajit

2012-01-01T23:59:59.000Z

466

Analysis of Steam Heating of a Two-Layer TBP/N-Paraffin/Nitric Acid Mixtures  

SciTech Connect

This report presents an analysis of steam heating of a two-layer tri-n-butyl phosphate (TBP)/n-paraffin-nitric acid mixture.The purpose of this study is to determine if the degree of mixing provided by the steam jet or by bubbles generated by the TBP/nitric acid reaction is sufficient to prevent a runaway reaction.

Laurinat, J.E. [Westinghouse Savannah River Company, AIKEN, SC (United States); Hassan, N.M.; Rudisill, T.S.; Askew, N.M.

1998-07-22T23:59:59.000Z

467

Electrolysed palladium has the potential to increase methane production by a mixed rumen population in vitro  

E-Print Network (OSTI)

Electrolysed palladium has the potential to increase methane production by a mixed rumen population the proportion of protozoa with attached methanogens decreased, however no estimate of CH4 production under were re-filled with H2:CO2, sealed with butyl rubber stoppers and incubated at 39�C with shaking

Paris-Sud XI, Université de

468

Features of gadolinium and ytterbium extraction by tributyl phosphate from concentrated nitric acid solutions. I. Compositions of extracted complexes  

SciTech Connect

Distribution of macroquantity (0.3-1.3 M) of Gd and Yb between neat tri-n-butyl phosphate (TBP) and 5-12 M nitric acid solutions has been studied. The species extracted by TBP from 7-12 M nitric acid solutions are rare-earth metal (REM) nitrate trisolvates containing one or several nitric molecules.

Nikitna, G.P.; Seredkina, N.V.; Listopadov, A.A. [Khlopin Radium Institute, St. Petersburg (Russian Federation)

1995-01-01T23:59:59.000Z

469

Investigation of the Performance and Emission Characteristics of Biodiesel Fuel Containing Butanol under the Conditions of Diesel Engine Operation  

Science Journals Connector (OSTI)

(17) However, emissions of engines fueled with multicomponent fuels containing fossil diesel, butanol, and rapeseed oil butyl/methyl esters have not been tested. ... Break specific fuel consumption when engine is fuelled with fossil diesel fuel (n = 1500 min?1). ... For all cases, engine torque was retained the same by adjusting fueling rate. ...

Sergejus Lebedevas; Galina Lebedeva; Egle Sendzikiene; Violeta Makareviciene

2010-07-23T23:59:59.000Z

470

War on Weeds  

Science Journals Connector (OSTI)

...4,5-T, Sizz-weeder, mechanical shredder, 2,4-dinitro-6-sec-butyl phenol...killers. To avoid chronic injury only light-weight oils are used. The best are...accepting a lot and the true quality (fraction defective) of the lot. For most sampling...

E. M. Hildebrand

1946-04-19T23:59:59.000Z

471

High-spin polymeric arylamines  

Science Journals Connector (OSTI)

...polymer 14 could be doped with a large excess of reagent without bipolaron formation...chloroform was oxidized with a 20-fold excess of powdered NOBF4. The UV spectrum of...rigorously dry conditions, n-butyl lithium in hexane (24.5 cm3 , 1.6 M, 37...

1999-01-01T23:59:59.000Z

472

Copyright H. J. Reich 2002 ORGANIC CHEMISTRY ACRONYMS  

E-Print Network (OSTI)

-t-butyl-4-methylphenol) BINALH Lithium 2,2'-dihydroxy-1,1'-binaphthylethoxyaluminum hydride BINAP 2,2'-Bis(p-chlorophenyl)-2,2,2-trichloroethane de Diastereomeric excess DEADCAT Diethyl Azodicarboxylate DET Diethyl Tartrate (opposite, trans) E Methoxycarbonyl CO2CH3 EDTA Ethylenediaminetetraacetic acid ee Enantiomeric Excess EE 1

Meagher, Mary

473

Critical Reviews in Environmental Science and Technology, 00(0):000000 (2001) 1064-3389/01/$.50  

E-Print Network (OSTI)

-3389/01/$.50 © 2001 by CRC Press LLC The Transport and Fate of Ethanol and BTEX in Groundwater Contaminated by Gasohol water contamination by methyl tert-butyl ether (MTBE) have made policymakers more cognizant of the need). It has been discovered that MTBE is a ubiquitous contaminant in surface and ground waters throughout

Alvarez, Pedro J.

474

Adsorption and desorption of atrazine on a melamine-based soil amendment  

E-Print Network (OSTI)

Adsorption kinetics and adsorption-desorption of atrazine on organoclay composites prepared with the surfactant 6-piperazin-1-yl-N,N'-bis-(1,1,3,3-tetramethyl-butyl)-(1,3,5)triazine-2,4-diamine and Houston Black clay were studied using the indirect...

Neitsch, Susan Lynn

2004-09-30T23:59:59.000Z

475

Initial-phase optimization for bioremediation of munition compound-contaminated soils.  

Science Journals Connector (OSTI)

...the aqueous phase and washing of the residue with methanol...COMPOUND-CONTAMINATED SOIL 2175 TABLE 1. '4C label...1992. Bioremediation of soils contaminated with 2-sec-butyl-4...6-Trinitrotoluene- surfactant complexes: decomposition, mutagenicity, and soil leaching studies. Environ...

S B Funk; D J Roberts; D L Crawford; R L Crawford

1993-07-01T23:59:59.000Z

476

Bibliography and Index of the Literature on Gas Chromatography—1964 November 1, 1963 to November 1, 1964  

Science Journals Connector (OSTI)

......CHROMATOG- RAPHY AND GAS-LIQUID CHROMATOGRA...Meyer, A. S., AEC Report ORNL-3619 for period...May 1964) 215 GAS-LIQUID CHROMATOGRAPHIC...6-DI-tert-BUTYL- p-CRESOL IN TURBINE OILS, Braithwaite...July 1964) 757 GAS CHROMATOGRAPHY OF...Sweeley, C. C., Progress in the Chemistry......

Mignon Gill; Seaton T. Preston; Jr.

1964-12-01T23:59:59.000Z

477

Rapid optical method for logging dust concentration versus depth in glacial ice  

E-Print Network (OSTI)

to a cable that can lower the device down a 3-in. 7.5-cm borehole filled with butyl acetate. LED photons to the attenuation by particles.6 The AMANDA collaboration recently completed a large observatory, buried in deep a hot-water drilling tech- nique, they melted cylindrical holes down to depths of 2000 m in which were

Price, P. Buford

478

Interaction forces between oilwater particle interfaces--Non-DLVO forces  

E-Print Network (OSTI)

silica sphere and a butyl or octyl acetate droplet was measured in an aqueous environment using atomic of the water solubility of the organic liquid, in that the same force­distance characteristics were obtained in industrial applications. They include formulation, stability, and rheological properties of emulsions

Chan, Derek Y C

479

J.Org. Chem. 1991,56,4435-4439 4435 themally equilibrated reaction solutioncontained in the cwette  

E-Print Network (OSTI)

constant with potasaium chloride (I = 1.0M), had their pHs adjusted with HC1and sodium acetate (1X l0-l, W. E.J. Chem. Educ. 1966,42,96. On the Structure and Reactivity of Lithium Diisopropylamide (LDA-1301 Received January 9, 1991 Enolizations of ketones, tert-butyl esters, and carboxamidesby solventfree lithium

Collum, David B.

480

Published: December 10, 2010 r 2010 American Chemical Society 933 dx.doi.org/10.1021/ja108205q |J. Am. Chem. Soc. 2011, 133, 933940  

E-Print Network (OSTI)

: Additive-Free Synthesis, Remarkable Crystalline-Phase Stability, and Improved Lithium Insertion Behavior in the tetrabutyl titanate-acetic acid system without any additives under solvothermal conditions. A complex, and entrapment of in situ produced butyl acetate as a porogen was put forward for the formation of the anatase

Qi, Limin

Note: This page contains sample records for the topic "tame tertiary butyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Photoluminescence properties of polynapthalenevinylene (PNV) homopolymers and block copolymers by ring–opening metathesis polymerization (ROMP) and study of their photoluminescence properties  

Science Journals Connector (OSTI)

...barrelene-like monomer containing acetate groups, 1, was polymerized...which was solubilized by the acetate groups and therefore easily...thermal elimination of the acetate moieties. More recently...6-tetrafluorobenzene, 6, reacts with butyl lithium to yield a benzyne intermediate...

1997-01-01T23:59:59.000Z

482

New Perspectives of Curcumin in Cancer Prevention  

Science Journals Connector (OSTI)

...cyclooxygenase-2 (COX-2) inhibitors was shown to have no benefit...p53-independent anticancer effect as an inhibitor of the proteasome pathway...analog GO-Y030 is a novel inhibitor of IKKbeta that suppresses...evaluation of curcumin-loaded chitosan/poly(butyl cyanoacrylate...

Wungki Park; A.R.M. Ruhul Amin; Zhuo Georgia Chen; and Dong M. Shin

2013-05-01T23:59:59.000Z

483

Porous yttria-stabilized zirconia ceramics with ultra-low thermal conductivity  

Science Journals Connector (OSTI)

Porous yttria-stabilized zirconia (ZrO2-8 mol% Y2O3, YSZ) ceramics with ultra-low thermal conductivity (as low as 0.06 W/mK) could be fabricated by tert-butyl alcohol...

LiangFa Hu; Chang-An Wang; Yong Huang

2010-06-01T23:59:59.000Z

484

Efficient Conversion of Fructose to 5-Hydroxymethylfurfural Catalyzed by Sulfated Zirconia in Ionic Liquids  

Science Journals Connector (OSTI)

Efficient Conversion of Fructose to 5-Hydroxymethylfurfural Catalyzed by Sulfated Zirconia in Ionic Liquids ... An efficient process was developed for the dehydration of fructose to 5-hydroxymethylfurfural (5-HMF) in the ionic liquid (IL) 1-butyl-3-methyl imidazolium chloride ([BMIM][Cl]) by using sulfated zirconia as catalyst. ... Sulfated Mesoporous Niobium Oxide Catalyzed 5-Hydroxymethylfurfural Formation from Sugars ...

Xinhua Qi; Haixin Guo; Luyang Li

2011-05-31T23:59:59.000Z

485

he increasing frequency of detection of the widely used gasoline additive methyl tert-  

E-Print Network (OSTI)

T he increasing frequency of detection of the widely used gasoline additive methyl tert- butyl, the September 15, 1999, Report of the Blue Ribbon Panel on Oxygenates in Gasoline (1) states that between 5 with large releases (e.g., LUFTs). Unprecedented growth in use Use of MTBE as a gasoline additive began

486

Water Research Institute Annual Technical Report  

E-Print Network (OSTI)

Air Act mandated oxygenated gasoline containing methyl tert-butyl ether (MtBE) in certain areas percent. The State of Maine elected to use reformulated gasoline (RFG) that contained at least 11 percent and by 1995, oxygenated gasoline use was common in the northeast. Soon after the widespread use of gasoline

487

CHARACTERIZATION OF GLOVEBOX GLOVES FOR THE SAVANNAH RIVER SITE  

SciTech Connect

A task was undertaken to characterize glovebox gloves that are currently used in the facilities at Savannah River Site (SRS) as well as some experimental and advanced compound gloves that have been proposed for use. Gloves from four manufacturers were tested for permeation in hydrogen and air, thermal stability, tensile properties, puncture resistance and dynamic mechanical response. The gloves were compared to each other within the type and also to the butyl rubber glove that is widely used at the SRS. The permeation testing demonstrated that the butyl compounds from three of the vendors behaved similarly and exhibited hydrogen permeabilities of .52‐.84 x10{sup ‐7} cc H{sub 2}*cm / (cm{sup 2}*atm). The Viton? glove performed at the lower edge of this bound, while the more advanced composite gloves exhibited permeabilities greater than a factor of two compared to butyl. Thermogravimetric analysis was used to determine the amount of material lost under slightly aggressive conditions. Glove losses are important since they can affect the life of glovebox stripper systems. During testing at 90, 120, and 150?C, the samples lost most of the mass in the initial 60 minutes of thermal exposure and as expected increasing the temperature increased the mass loss and shortened the time to achieve a steady state loss. The ranking from worst to best was Jung butyl‐Hypalon? with 12.9 %, Piercan Hypalon? with 11.4 %, and Jung butyl‐Viton? with 5.2% mass loss all at approximately 140?C. The smallest mass losses were experienced by the Jung Viton? and the Piercan polyurethane. Tensile properties were measured using a standard dog bone style test. The butyl rubber exhibited tensile strengths of 11‐15 MPa and elongations or 660‐843%. Gloves made from other compounds exhibited lower tensile strengths (5 MPa Viton) to much higher tensile strengths (49 MPa Urethane) with a comparable range of elongation. The puncture resistance of the gloves was measured in agreement with an ASTM standard. The Butyl gloves exhibited puncture resistance from 183 ? 296 lbs/in for samples of 0.020 ? 0.038? thick. Finally, the glass transition temperature and the elastic and viscoelastic properties as a function of temperature up to maximum use temperature were determined for each glove material using Dynamic Mechanical Analysis. The glass transition temperatures of the gloves were ‐60?C for butyl, ‐30?C for polyurethane, ‐ 16?C Hypalon?, ‐16?C for Viton?, and ‐24?C for polyurethane‐Hypalon?. The glass transition was too complex for the butyl‐Hypalon? and butyl‐Viton? composite gloves to be characterized by a single glass transition temperature. All of the glass transition temperatures exceed the vendor projected use temperatures.

Korinko, P.

2013-01-24T23:59:59.000Z

488

An Aerosol Condensation Model for Sulfur Trioxide  

SciTech Connect

This document describes a model for condensation of sulfuric acid aerosol given an initial concentration and/or source of gaseous sulfur trioxide (e.g. fuming from oleum). The model includes the thermochemical effects on aerosol condensation and air parcel buoyancy. Condensation is assumed to occur heterogeneously onto a preexisting background aerosol distribution. The model development is both a revisiting of research initially presented at the Fall 2001 American Geophysical Union Meeting [1] and a further extension to provide new capabilities for current atmospheric dispersion modeling efforts [2]. Sulfuric acid is one of the most widely used of all industrial chemicals. In 1992, world consumption of sulfuric acid was 145 million metric tons, with 42.4 Mt (mega-tons) consumed in the United States [10]. In 2001, of 37.5 Mt consumed in the U.S., 74% went into producing phosphate fertilizers [11]. Another significant use is in mining industries. Lawuyi and Fingas [7] estimate that, in 1996, 68% of use was for fertilizers and 5.8% was for mining. They note that H{sub 2}SO{sub 4} use has been and should continue to be very stable. In the United States, the elimination of MTBE (methyl tertiary-butyl ether) and the use of ethanol for gasoline production are further increasing the demand for petroleum alkylate. Alkylate producers have a choice of either a hydrofluoric acid or sulfuric acid process. Both processes are widely used today. Concerns, however, over the safety or potential regulation of hydrofluoric acid are likely to result in most of the growth being for the sulfuric acid process, further increasing demand [11]. The implication of sulfuric acid being a pervasive industrial chemical is that transport is also pervasive. Often, this is in the form of oleum tankers, having around 30% free sulfur trioxide. Although sulfuric acid itself is not a volatile substance, fuming sulfuric acid (referred to as oleum) is [7], the volatile product being sulfur trioxide. Sulfate aerosols and mist may form in the atmosphere on tank rupture. From chemical spill data from 1990-1996, Lawuyi02 and Fingas [7] prioritize sulfuric acid as sixth most serious. During this period, they note 155 spills totaling 13 Mt, out of a supply volume of 3700 Mt. Lawuyi and Fingas [7] summarize information on three major sulfuric acid spills. On 12 February 1984, 93 tons of sulfuric acid were spilled when 14 railroad cars derailed near MacTier, Parry Sound, Ontario. On 13 December 1978, 51 railroad cars derailed near Springhill, Nova Scotia. One car, containing 93% sulfuric acid, ruptured, spilling nearly its entire contents. In July 1993, 20 to 50 tons of fuming sulfuric acid spilled at the General Chemical Corp. plant in Richmond, California, a major industrial center near San Francisco. The release occurred when oleum was being loaded into a nonfuming acid railroad tank car that contained only a rupture disk as a safety device. The tank car was overheated and this rupture disk blew. The resulting cloud of sulfuric acid drifted northeast with prevailing winds over a number of populated areas. More than 3,000 people subsequently sought medical attention for burning eyes, coughing, headaches, and nausea. Almost all were treated and released on the day of the spill. By the day after the release, another 5,000 people had sought medical attention. The spill forced the closure of five freeways in the region as well as some Bay Area Rapid Transit System stations. Apart from corrosive toxicity, there is the additional hazard that the reactions of sulfur trioxide and sulfuric acid vapors with water are extremely exothermic [10, 11]. While the vapors are intrinsically denser than air, there is thus the likelihood of strong, warming-induced buoyancy from reactions with ambient water vapor, water-containing aerosol droplets, and wet environmental surface. Nordin [12] relates just such an occurrence following the Richmond, CA spill, with the plume observed to rise to 300 m. For all practical purposes, sulfur trioxide was the constituent released from the heated tank

Grant, K E

2008-02-07T23:59:59.000Z

489

Conceptual Model At Raft River Geothermal Area (2011) | Open Energy  

Open Energy Info (EERE)

2011) 2011) Exploration Activity Details Location Raft River Geothermal Area Exploration Technique Conceptual Model Activity Date 2011 Usefulness not indicated DOE-funding Unknown Exploration Basis Explore for development of an EGS demonstration project Notes The reservoir is developed in fractured Proterozoic schist and quartzite, and Archean quartz monzonite cut by younger diabase intrusions. The basement complex was deformed during the mid Tertiary and covered by approximately 5000 ft of late Tertiary sedimentary and volcanic deposits. Listric normal faults of Cenozoic age disrupt the Tertiary deposits but do not offset the basement rocks. RRG-9, the target well, was drilled southwest of the main well field to a measured depth (MD) of 6089 ft. The well is deviated to the west and cased to a depth of 2316 ft MD. It

490

Bifunctional anion-exchange resins with improved selectivity and exchange kinetics  

DOE Patents (OSTI)

Disclosed herein are a class of anion exchange resins containing two different exchange sites with improved selectivity and sorptive capability for chemical species in solution, such as heptavalent technetium (as pertechnetate anion, TcO.sub.4.sup.-). The resins are prepared by first reacting haloalkylated crosslinked copolymer beads with a large tertiary amine in a solvent in which the resin beads can swell, followed by reaction with a second, smaller, tertiary amine to more fully complete the functionalization of the resin. The resins have enhanced selectivity, capacity, and exchange kinetics.

Alexandratos, Spiro D. (Knoxville, TN); Brown, Gilbert M. (Knoxville, TN); Bonnesen, Peter V. (Knoxville, TN); Moyer, Bruce A. (Oak Ridge, TN)

2000-01-01T23:59:59.000Z

491

Coal quality and estimated coal resources in the proposed Colville Mining District, central North Slope, Alaska  

SciTech Connect

The proposed Colville Mining District (CMD) encompasses 27,340 mi{sup 2} (70,800 km{sup 2}) in the central part of the North Slope. Known coal deposits within the proposed district range from Mississippian to Tertiary in age. Available information indicates that neither Mississippian and Tertiary coals in the CMD constitute a significant resource because they are excessively deep, thin, or high in ash content; however, considerable amount of low-sulfur Cretaceous coal is present. The paper briefly describes the geology and quality of these coal reserves. Difficult conditions will restrict mining of these coals in the near future.

Stricker, G.D. [Geological Survey, Denver, CO (United States); Clough, J.G. [Alaska Department of Natural Resources, Fairbanks, AK (United States). Division of Geological and Geophysical Surveys

1994-12-31T23:59:59.000Z

492

Energy Efficiency and Conservation Block Grant Program  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Description Description At the Wastewater Treatment Plant: install dissolved oxygen controls, reprogram wetwell level controls for the tertiary filter pumps, install electric actuators on tertiary filter effluent lines, install power monitors on motors, install standby generator; at the Biosolids Processing Facility and Landfill: install timers or programmable logic controllers (PLC); at the Wastewater Flow Equalization Basin and Pumping Station at Landfill: install timers or PLC, install variable frequency drives on wastewater pumps; at the Water Treatment Plant: install power monitors on motors; at several of the wastewater treatment facilities replace existing interior and exterior lighting fixtures with high efficiency units and provide engineering services.

493

Physical Properties of Ionic Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

Physical Properties of Ionic Liquids Consisting of the Physical Properties of Ionic Liquids Consisting of the 1-Butyl-3-Methylimidazolium Cation with Various Anions and the Bis(trifluoromethylsulfonyl)imide Anion with Various Cations Hui Jin, Bernie O'Hare, Jing Dong, Sergei Arzhantsev, Gary A. Baker, James F. Wishart, Alan J. Benesi, and Mark Maroncelli J. Phys. Chem. B 112, 81-92 (2008). [Find paper at ACS Publications] Abstract: Physical properties of 4 room-temperature ionic liquids consisting of the 1-butyl-3-methylimidazolium cation with various perfluorinated anions and the bis(trifluoromethylsulfonyl)imide (Tf2N-) anion with 12 pyrrolidinium-, ammonium-, and hydroxyl-containing cations are reported. Electronic structure methods are used to calculate properties related to the size, shape, and dipole moment of individual ions. Experimental measurements of

494

Recombination of Photogenerated Lophyl Radicals in Imidazolium-Based ILs  

NLE Websites -- All DOE Office Websites (Extended Search)

Recombination of Photogenerated Lophyl Radicals in Imidazolium-Based Ionic Recombination of Photogenerated Lophyl Radicals in Imidazolium-Based Ionic Liquids V. Strehmel, J. F. Wishart, D. E. Polyansky and B. Strehmel ChemPhysChem 10, 3112-3118 (2009). [Find paper at Wiley] Abstract: Laser flash photolysis is applied to study the recombination reaction of lophyl radicals in ionic liquids in comparison with dimethylsulfoxide as an example of a traditional organic solvent. The latter exhibits a similar micropolarity as the ionic liquids. The ionic liquids investigated are 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (1), 1-hexyl-3-methylimidazolium hexafluorophosphate (2), and 1-butyl-3-methylimidazolium tetafluoroborate (3). The recombination of the photolytic generated lophyl radicals occur significantly faster in the ionic liquids than expected from their

495

Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

7 results: 7 results: BibTex RIS RTF XML Sort by: Author Title Type [ Year (Desc) ] Filters: Author is Elton J. Cairns [Clear All Filters] 2008 Shin, Joon Ho, Pratyay Basak, John B. Kerr, and Elton J. Cairns. "Rechargeable Li/LiFePO4 Cells Using N-Methyl-N-butyl pyrrolidinium Bis(trifluoromethane sulfonyl)imide-LiTFSI Electrolyte Incorporating Polymer Additives." Electrochimica Acta 54, no. 2 (2008): 410-414. Shin, Joon Ho, and Elton J. Cairns. "N-Methyl-(n-butyl)pyrrolidinium bis(trifluoromethanesulfonyl)imide-LiTFSI-poly(ethylene glycol) dimethyl ether mixture as a Li/S cell electrolyte." Journal of Power Sources 177 (2008): 537-545. 2007 Nakahara, Kentaro, Jiro Iriyama, Shigeyuki Iwasa, Masahiro Suguro, Masaharu Satoh, and Elton J. Cairns. "Al-laminated film packaged organic radical

496

Anion effects in the extraction of lanthanide 2-thenoyltrifluoroacetone complexes into an ionic liquid  

SciTech Connect

The extraction of trivalent lanthanides from an aqueous phase containing 1 M NaClO{sub 4} into the room temperature ionic liquid 1-butyl-3-methylimidazolium nonafluoro-1-butane sulfonate by the beta-diketone extractant 2-thenoyltrifluoroacetone (Htta) was studied. Radiotracer distribution, absorption spectroscopy, time-resolved laser-induced fluorescence spectroscopy, and X-ray absorption fine structure measurements point to the extraction of multiple lanthanide species. At low extractant concentrations, fully hydrated aqua cations of the lanthanides are present in the ionic liquid phase. As the extractant concentration is increased 1:2 and 1:3 lanthanide:tta species are observed. In contrast, 1:4 Ln:tta complexes were observed in the extraction of lanthanides by Htta into 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide. (authors)

Jensen, Mark P.; Beitz, James V.; Rickert, Paul G. [Argonne Natl Lab, Chem Sci and Engn Div, Argonne, IL 60439 (United States); Borkowski, Marian [Argonne Natl Lab, Chem Sci and Engn Div, Argonne, IL 60439 (United States); Los Alamos Natl Lab, Earth and Environm Sci Div, Carlsbad, NM, (United States); Laszak, Ivan [Argonne Natl Lab, Chem Sci and Engn Div, Argonne, IL 60439 (United States); Commisariat Energie Atom, DEN DPC SERC LANIE, Gif Sur Yvette, (France); Dietz, Mark L. [Argonne Natl Lab, Chem Sci and Engn Div, Argonne, IL 60439 (United States); Wisconsin-Milwaukee Univ, Department of Chemistry and Biochemistry, Milwaukee, WI, (United States)

2012-07-01T23:59:59.000Z

497

Radioisotope thermoelectric generator package o-ring seal material validation testing  

SciTech Connect

The Radioisotope Thermoelectric Generator Package O-Ring Seal Material Validation Test was conducted to validate the use of the Butyl material as a primary seal throughout the required temperature range. Three tests were performed at (I) 233 K ({minus}40 {degree}F), (2) a specified operating temperature, and (3) 244 K ({minus}20 {degree}F) before returning to room temperature. Helium leak tests were performed at each test point to determine seal performance. The two major test objectives were to establish that butyl rubber material would maintain its integrity under various conditions and within specified parameters and to evaluate changes in material properties. {copyright} {ital 1995} {ital American} {ital Institute} {ital of} {ital Physics}

Adkins, H.E.; Ferrell, P.C.; Knight, R.C. [Westinghouse Hanford Company, P. O. Box 1970, MSIN N1-25, Richland, Washington 99352 (United States)

1995-01-20T23:59:59.000Z

498

Composition and method for encapsulating photovoltaic devices  

DOE Patents (OSTI)

A composition and method for encapsulating a photovoltaic device which minimizes discoloration of the encapsulant. The composition includes an ethylene-vinyl acetate encapsulant, a curing agent, an optional ultraviolet light stabilizer, and/or an optional antioxidant. The curing agent is preferably 1,1-di-(t-butylperoxy)-3,3,5-trimethylcyclohexane; the ultraviolet light stabilizer is bis-(N-octyloxy-tetramethyl) piperidinyl sebacate and the antioxidant is selected from the group consisting of tris (2,4-di-tert-butylphenyl) phosphite, tetrakis methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate) methane, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, and 2,2'-ethylidene bis(4,6-di-t-butylphenyl) fluorophosponite. The composition is applied to a solar cell then cured. The cured product contains a minimal concentration of curing-generated chromophores and resists UV-induced degradation.

Pern, Fu-Jann (Golden, CO)

2000-01-01T23:59:59.000Z

499

Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

3 results: 3 results: BibTex RIS RTF XML Sort by: Author Title Type [ Year (Desc) ] Filters: Author is Joon Ho Shin [Clear All Filters] 2008 Shin, Joon Ho, Pratyay Basak, John B. Kerr, and Elton J. Cairns. "Rechargeable Li/LiFePO4 Cells Using N-Methyl-N-butyl pyrrolidinium Bis(trifluoromethane sulfonyl)imide-LiTFSI Electrolyte Incorporating Polymer Additives." Electrochimica Acta 54, no. 2 (2008): 410-414. Saint, Juliette A., Adam S. Best, Anthony F. Hollenkamp, Joon Ho Shin, and Marca M. Doeff. "Compatibility of Lix TiyMn1-y02 (y=0,0.11) electrode materials with pyrrolidinium-based ionic liquid electrolyte systems." Journal of The Electrochemical Society 155, no. 2 (2008): A172-A180. Shin, Joon Ho, and Elton J. Cairns. "N-Methyl-(n-butyl)pyrrolidinium

500

CONCENTRATES  

Science Journals Connector (OSTI)

SHIN-ETSU MAKES FIRST MAJOR CHINA INVESTMENT ... Although China is a major market for Shin-Etsu, Japan’s most profitable chemical maker, the company has until now refrained from making large investments there because it perceived the political risk to be too great. ... Citing rising global demand from tire makers, Lanxess says it will invest about $25 million to raise butyl and halobutyl rubber capacity at its site in Zwijndrecht, Belgium. ...

2010-07-05T23:59:59.000Z