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1

Effect of V and Ta on the precipitation behavior of 12%Cr reduced activation ferrite/martensite steel  

SciTech Connect (OSTI)

12%Cr reduced activation ferrite/martensite steels are promising candidate materials for good corrosion and irradiation resistance used for supercritical water-cooled reactor cladding and in-core components. V and Ta are considered to have improved the creep strength of high Cr steels by precipitating as MX phase. In this paper, a series of trial products microalloyed with V and V–Ta are produced, and the microstructure is characterized after quenching at 1050 °C and tempering at 780 °C by using TEM method to investigate the effect of these elements on the precipitation behavior of 12%Cr reduced activation ferrite/martensite steel. The results from both the experimental observations and thermodynamic and kinetic calculations reveal that V and V–Ta can promote the stable MX precipitation instead of M{sub 2}X, thus increasing the volume fraction of M{sub 23}C{sub 6}. Two-phase separation behavior of the (Ta, V)(C, N) carbonitride into a Ta(V)C(N) phase and a V(Ta)N(C) phase in 12Cr3WVTa steel is observed and further discussed. - Highlights: • Microalloyed with V and V-Ta can promote the precipitation of MX instead of M{sub 2}X. • The presence of delta-ferrite in microstructure affects the morphology of MX. • Two-phase separation of MX carbonitride was observed in 12Cr3WVTa steel.

Xiao, Xiang [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Liu, Guoquan, E-mail: g.liu@ustb.edu.cn [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083 (China); Hu, Benfu; Wang, Jinsan [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Ullah, Asad [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Department of Mathematics, Karakoram International University, Gilgit-Baltistan (Pakistan)

2013-08-15T23:59:59.000Z

2

Directed-energy electron-beam processing of a hypoeutectic Cr/sub 90/Ta/sub 10/ alloy  

SciTech Connect (OSTI)

A hypoeutectic Cr/sub 90/Ta/sub 10/ alloy was processed using a directed-energy electron-beam surface melting and resolidification technique to study its microstructure evolution during rapid solidification. The power of the electron beam was 2500 W and the scan speed ranged from 0.13 to 2.0 m/sec. Microstructure characteristics such as transitions from planar front to dendritic growth, and from cellular to dendritic growth were observed. At low solidification rate, the interdendritic regions are characterized by the Cr/Cr/sub 2/Ta eutectic, and at high solidification rate the intercellular regions are characterized by a Cr/sub 2/Ta phase. For the latter, the distribution of Ta-solute across the interior of a cell is very uniform. In a given sample, the primary cell spacing increases as the solidification front moves from the substrate/regrowth interface toward the surface. The solidification parameters, i.e., temperature gradient and growth velocity, were determined with finite-element heat flow analyses. The observed microstructure characteristics were correlated to these parameters using available theoretical models. 9 refs., 11 figs., 1 tab.

Huang, J.S.; Kaufmann, E.N.

1987-09-01T23:59:59.000Z

3

Nickel Alloy, Corrosion and Heat-Resistant, Sheet, Strip, and Plate 72Ni - 15.5Cr - 0.95 (Cb (Nb) + Ta) - 2.5Ti - 0.70Al - 7.0Fe Consumable Electrode, Remelted or Vacuum Induction Melted, Solution Heat Treated, Precipitation-Hardenable  

E-Print Network [OSTI]

Nickel Alloy, Corrosion and Heat-Resistant, Sheet, Strip, and Plate 72Ni - 15.5Cr - 0.95 (Cb (Nb) + Ta) - 2.5Ti - 0.70Al - 7.0Fe Consumable Electrode, Remelted or Vacuum Induction Melted, Solution Heat Treated, Precipitation-Hardenable

SAE Aerospace Standards. London

2012-01-01T23:59:59.000Z

4

National Aeronautics and Space Administration TA01 TA02 TA03 TA04  

E-Print Network [OSTI]

Launch/DropSystems · SpaceTetherAssist · BeamedEnergy/Energy Addition · Nuclear · HighEnergyDensity MaterialsFission · BreakthroughPropulsion SuPPoRting technologieS · PropellantStorage&Transfer TA03 · sPace Power & energy storageNational Aeronautics and Space Administration TA01 TA02 TA03 TA04 TA05 TA06 TA07 TA08 s TA01

Waliser, Duane E.

5

CMSC 412101 (Spring 1996) Professor: TA: TA  

E-Print Network [OSTI]

CMSC 412­101 (Spring 1996) Professor: TA: TA: Dr. Jeff Hollingsworth Charles Lin Alex Kaplunovich 4161 AV Williams 1109 A V Williams 1109 A V Williams (40) 5­2708 hollings@cs.umd.edu clin

Hollingsworth, Jeffrey K.

6

CMSC 412 (Spring 2002) Professor: TA: TA  

E-Print Network [OSTI]

CMSC 412 (Spring 2002) Professor: TA: TA: Dr. Jeff Hollingsworth Abdel-Hameed Badawy Cemal Yilmaz 4161 AV Williams 1151 A V Williams 1151 A V Williams (40) 5-2708 hollings@cs.umd.edu absalam

Hollingsworth, Jeffrey K.

7

Blanchard Cr JohnsonGulch  

E-Print Network [OSTI]

Dirt yfaceCr Sheep Cr Essex Cr Dic key Cr Paola Cr Cr ystalCr Deerlick Cr Howe Cr M id dle Fork FlatheadRiver Mid dle Fork Bowl C r So u th Fork Scalp Cr West Fork WhistlerCr GraniteCr DodgeCr Flathea d

8

TA-55 change control manual  

SciTech Connect (OSTI)

This manual is the guide for initiating change at the Plutonium Facility, which handles the processing of plutonium as well as research on plutonium metallurgy. It describes the change and work control processes employed at TA-55 to ensure that all proposed changes are properly identified, reviewed, approved, implemented, tested, and documented so that operations are maintained within the approved safety envelope. All Laboratory groups, their contractors, and subcontractors doing work at TA-55 follow requirements set forth herein. This manual applies to all new and modified processes and experiments inside the TA-55 Plutonium Facility; general plant project (GPP) and line item funded construction projects at TA-55; temporary and permanent changes that directly or indirectly affect structures, systems, or components (SSCs) as described in the safety analysis, including Facility Control System (FCS) software; and major modifications to procedures. This manual does not apply to maintenance performed on process equipment or facility SSCs or the replacement of SSCs or equipment with documented approved equivalents.

Blum, T.W.; Selvage, R.D.; Courtney, K.H.

1997-11-01T23:59:59.000Z

9

Blanchard Cr West Fk Clearwater R  

E-Print Network [OSTI]

Dirt yfaceCr Sheep Cr Essex Cr Dick ey Cr Paola Cr Cry stalCr Deerlick Cr Howe Cr M id dle Fork FlatheadRiver Mid dle Fork Bowl Cr So u th Fork Scalp Cr West Fork WhistlerCr GraniteCr DodgeCr Flathead

10

CRAD, Quality Assurance - Los Alamos National Laboratory TA 55...  

Broader source: Energy.gov (indexed) [DOE]

CRAD, Emergency Management - Los Alamos National Laboratory TA 55 SST Facility CRAD, Conduct of Operations - Los Alamos National Laboratory TA 55 SST Facility CRAD,...

11

Thermodynamic modelling of Cr-bearing garnets with implications for diamond inclusions and peridotite xenoliths  

E-Print Network [OSTI]

, Zürich, Switzerland e Geological Survey of Western Australia, Mineral House, 100 Plain Street, East Perth, WA 6004, Australia a b s t r a c ta r t i c l e i n f o Article history: Received 8 September 2008 using free energy minimization techniques. Here we present calculated phase relations in Cr-rich mantle

12

Characterization of Rh films on Ta(110)  

SciTech Connect (OSTI)

The surface and electronic structure of Rh films on Ta(110) up to several monolayers thick on Ta(110) are characterized by photoemission, Auger emission, low energy electron diffraction and low energy ion scattering. From the variation of the Rh Auger peak-to-peak intensity as a function of evaporation time, Rh/Ta(110) appears to grow in the Stranski-Krastanov mode at room temperature. However, the LEIS data show that the Rh adatoms begin to cluster on Ta(110) before growth of the monolayer is completed. Diffuse LEED scattering suggests that the Rh films are disordered. Photoemission shows that Rh chemisorption on Ta(110) generates two peaks located at 1.2 and 2. 5 eV binding energy during the initial phase of thin film growth (0 < {Theta} < 0.5 ML). By 0.75 ML Rh coverage, those states merge into a broad structure centered near 2 eV binding energy. Photoemission peaks typical of a Rh(111) surface are seen at higher coverages ({Theta} > 3.7 ML). Photoemission data for CO covered surfaces show that CO dissociates on the Rh/Ta(110) surface for Rh coverages less than 2.5 ML and also show that the Rh clusters develop at least one site capable of molecular CO adsorption above 0.3 ML Rh coverage. 38 refs., 5 figs.

Jiang, L.Q.; Ruckman, M.W.; Strongin, M.

1989-01-01T23:59:59.000Z

13

2014/2015 TA Training Program Page 1 of 4 Call for Proposals for 2014/2015 TA Training Programs  

E-Print Network [OSTI]

2014/2015 TA Training Program Page 1 of 4 Call for Proposals for 2014/2015 TA Training Programs, the University is committed to providing educational programs specifically addressing TAs needs. The TA Training for the development, delivery, and assessment of TA training programs. In so doing, we expect a significant increase

Handy, Todd C.

14

MA 125-4 CR PH 105-4 CR  

E-Print Network [OSTI]

490-3 CR Mechanical Engineering Design I I Proj Lab Proj Lab MA 125-4 CR Calculus I or Equivalent M MEMA 125-4 CR Calculus I or Equivalent PH 105-4 CR Gen Physics with Calculus MA 126-4 CR Calculus I I or Equivalent M Required Course Elective Course Prerequisite NS M W LAB Proj Lab Natural Science Mathematics

Carver, Jeffrey C.

15

Unexpected formation of a trinuclear complex containing a Ta(IV)-Ta(IV) bond in the reactions of ButN=Ta(NMe2)3 with silanes  

SciTech Connect (OSTI)

A new trinuclear species containing a Ta(IV)-Ta(IV) bond, Ta{sub 3}({mu}-H)({mu}-NMe{sub 2})({mu}NBu{sup t}){sub 2}(NBu{sup t})(NMe{sub 2}){sub 5}, has been formed by reductive elimination of H{sub 2}. Ta{sub 2}H{sub 2}({mu}-NMe{sub 2}){sub 2}(NMe{sub 2}){sub 2}(NBu{sup t}){sub 2} has also been isolated. O{sub 2} oxidizes the Ta(IV)-Ta(IV) bond to yield Ta{sub 3}({mu}{sub 3}-O)(H)({mu}NBu{sup t})({mu}-NMe{sub 2}){sub 2}(NMe{sub 2}){sub 4}(NBu{sup t}){sub 2} under ligand exchange. Delocalization of d electrons is discussed.

Cheng, Shu-Jian [University of Tennessee, Knoxville (UTK); Dougan, Brenda A. [University of Tennessee, Knoxville (UTK); Steren, Carlos A. [University of Tennessee, Knoxville (UTK); Wang, Xiaoping [ORNL; Chen, Xue-Tai [University of Tennessee, Knoxville (UTK); Lin, Zhenyang [University of Tennessee, Knoxville (UTK); Xue, Zi-Ling [University of Tennessee, Knoxville (UTK)

2011-01-01T23:59:59.000Z

16

CMSC 311101 (Fall 1995) Professor: TA  

E-Print Network [OSTI]

CMSC 311­101 (Fall 1995) Professor: TA: Dr. Jeff Hollingsworth Shekhar Patankar 4161 AV Williams 1109 A V Williams (40) 5­2708 hollings@cs.umd.edu shekhar@cs.umd.edu Office Hours: Tu 1:00­2:30 W 10

Hollingsworth, Jeffrey K.

17

CRAD, Training - Los Alamos National Laboratory TA 55 SST Facility...  

Broader source: Energy.gov (indexed) [DOE]

Training - Los Alamos National Laboratory TA 55 SST Facility CRAD, Training - Los Alamos National Laboratory TA 55 SST Facility A section of Appendix C to DOE G 226.1-2 "Federal...

18

Oxidation behavior of Cr-Cr{sub 2}Nb alloys  

SciTech Connect (OSTI)

Oxidation of hypoeutectic Cr-Cr{sub 2}Nb alloys containing 6 and 12% Nb at 950 C resulted in formation of a multiproduct scale consisting of a continuous Cr{sub 2}O{sub 3} outer layer and an inner region of discrete CrNbO{sub 4} products interspersed with Cr{sub 2}O{sub 3}. Overall oxidation behavior resembled that of Cr as reactions with the Cr-rich phase tended to dominate. Oxidation resistance, in terms of reaction kinetics and scale adherence, increased with increasing volume fraction of the Cr-Cr{sub 2}Nb eutectic phase. A model for the oxidation of these alloys based on the growth of Cr{sub 2}O{sub 3} on the Cr-rich matrix regions and the formation of a slower growing CrNbO{sub 4} on the Cr{sub 2}Nb-enriched phase can qualitatively explain the development of the multiproduct scale and the observed gravimetric and spallation results. Possible microstructural/compositional modifications to improve oxidation resistance are suggested.

Tortorelli, P.F.; Pint, B.A.

1996-12-31T23:59:59.000Z

19

Electronics I 4 cr with Lab  

E-Print Network [OSTI]

ECE 332 Electronics I 4 cr with Lab ECE 370 Signals & Systems 3 cr co ECE 225 Electric Circuits 3 106 - 4 cr General Physics with Calculus CS 116 - 1 cr Intro to Comp. Program. Lab co MATH 227 4 cr cr Department of Electrical and Computer Engineering -- Department of Physics and Astromony

Carver, Jeffrey C.

20

TA-2 Water Boiler Reactor Decommissioning Project  

SciTech Connect (OSTI)

This final report addresses the Phase 2 decommissioning of the Water Boiler Reactor, biological shield, other components within the biological shield, and piping pits in the floor of the reactor building. External structures and underground piping associated with the gaseous effluent (stack) line from Technical Area 2 (TA-2) Water Boiler Reactor were removed in 1985--1986 as Phase 1 of reactor decommissioning. The cost of Phase 2 was approximately $623K. The decommissioning operation produced 173 m{sup 3} of low-level solid radioactive waste and 35 m{sup 3} of mixed waste. 15 refs., 25 figs., 3 tabs.

Durbin, M.E. (ed.); Montoya, G.M.

1991-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

TA-55: LANL Plutonium-Processing Facilities  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security AdministrationcontrollerNanocrystallineForeign Object DamageSystemsU.S. DepartmentTA-55: LANL

22

e cr d  

E-Print Network [OSTI]

nd er, ept To fu and to death p dopam fected deletio Bax), o by elec cells ex charac larly s ing DN cally s bioche death, broad-bonyl-V Boc-as not att treatm rine-induced apoptotic cell death. Concurrent treat-ment with an inhibitor of macromolecule synthesis such a blocke protein apopto MN9D/ MPP1 t cent pr expres signific death C-term cell de fect. Ta induce both a te de p ium as y W h. pop de is la of l s ro co s a can be blocked by inhibitors of RNA and protein synthe-sis (23). Cysteine proteases encoded by Caenorhabditis

Won- O; Depar Ko; Nerv Ash

23

CRAD, Emergency Management - Los Alamos National Laboratory TA...  

Broader source: Energy.gov (indexed) [DOE]

CRAD, Emergency Management - Office of River Protection K Basin Sludge Waste System CRAD, Conduct of Operations - Los Alamos National Laboratory TA 55 SST Facility CRAD, Training -...

24

Anisotropic Ta{sub 2}O{sub 5} waveguide etching using inductively coupled plasma etching  

SciTech Connect (OSTI)

Smooth and vertical sidewall profiles are required to create low loss rib and ridge waveguides for integrated optical device and solid state laser applications. In this work, inductively coupled plasma (ICP) etching processes are developed to produce high quality low loss tantalum pentoxide (Ta{sub 2}O{sub 5}) waveguides. A mixture of C{sub 4}F{sub 8} and O{sub 2} gas are used in combination with chromium (Cr) hard mask for this purpose. In this paper, the authors make a detailed investigation of the etch process parameter window. Effects of process parameters such as ICP power, platen power, gas flow, and chamber pressure on etch rate and sidewall slope angle are investigated. Chamber pressure is found to be a particularly important factor, which can be used to tune the sidewall slope angle and so prevent undercut.

Muttalib, Muhammad Firdaus A., E-mail: mfam1g08@ecs.soton.ac.uk; Chen, Ruiqi Y.; Pearce, Stuart J.; Charlton, Martin D. B. [Nano Research Group, Electronics and Computer Science, Faculty of Physical and Applied Sciences, University of Southampton, Southampton SO17 1BJ (United Kingdom)

2014-07-01T23:59:59.000Z

25

High Nb, Ta, and Al creep- and oxidation-resistant austenitic stainless steel  

DOE Patents [OSTI]

An austenitic stainless steel HTUPS alloy includes, in weight percent: 15 to 30 Ni; 10 to 15 Cr; 2 to 5 Al; 0.6 to 5 total of at least one of Nb and Ta; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1 W; up to 0.5 Cu; up to 4 Mn; up to 1 Si; 0.05 to 0.15 C; up to 0.15 B; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni wherein said alloy forms an external continuous scale comprising alumina, nanometer scale sized particles distributed throughout the microstructure, said particles comprising at least one composition selected from the group consisting of NbC and TaC, and a stable essentially single phase fcc austenitic matrix microstructure, said austenitic matrix being essentially delta-ferrite-free and essentially BCC-phase-free.

Brady, Michael P (Oak Ridge, TN) [Oak Ridge, TN; Santella, Michael L (Knoxville, TN) [Knoxville, TN; Yamamoto, Yukinori (Oak Ridge, TN) [Oak Ridge, TN; Liu, Chain-tsuan (Oak Ridge, TN) [Oak Ridge, TN

2010-07-13T23:59:59.000Z

26

E-Print Network 3.0 - al hf ta Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

-based gate dielectric for MOSFETs with TaN metal gate. By incorporating Ta into HfO2 films, significant... shift than HfO2 3. In this work, we developed HfTaO gate ......

27

Nanoscale Phase Separation In Epitaxial Cr-Mo and Cr-V Alloy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Separation In Epitaxial Cr-Mo and Cr-V Alloy Thin Films Studied Using Atom Probe Tomography: Comparison Of Nanoscale Phase Separation In Epitaxial Cr-Mo and Cr-V Alloy Thin Films...

28

Mathematics Required Courses Cr. Semester Gr.  

E-Print Network [OSTI]

Discrete Mathematics 3 Math 321 or Math 421 Applied Stat. Methods Stat. Theory I 3 Elective Course* Cr Student: ID# Catalog: Advisor Upper Division Courses* Required Courses Cr. Semester Gr. *20 cr

Delene, David J.

29

Silver delafossite nitride, AgTaN{sub 2}?  

SciTech Connect (OSTI)

A new silver nitride, AgTaN{sub 2}, was synthesized from NaTaN{sub 2} by a cation-exchange reaction, using a AgNO{sub 3}-NH{sub 4}NO{sub 3} flux at 175 {sup o}C. Its crystal structure type is delafossite (R3-bar m) with hexagonal lattice parameters of a=3.141(3) A, c=18.81(2) A, in which silver is linearly coordinated to nitrogen. Energy dispersive X-ray analysis and combustion nitrogen/oxygen analysis gave a composition with atomic ratios of Ag:Ta:N:O as 1.0:1.2(1):2.1(1):0.77(4), which is somewhat Ta rich and indicates some oxide formation. The X-ray photoelectron spectroscopy analysis showed a Ta- and O-rich surface and transmission electron microscope observation exhibited aggregates of ca. 4-5 nm-sized particles on the surface, which are probably related to the composition deviation from a AgTaN{sub 2}. The lattice parameters of stoichiometric AgTaN{sub 2} calculated by density functional theory agree with the experimental ones, but the possibility of some oxygen incorporation and/or silver deficiency is not precluded. -- Graphical abstract: A delafossite silver nitride, AgTaN{sub 2}, was synthesized from NaTaN{sub 2} by a cation-exchange reaction using a AgNO{sub 3}-NH{sub 4}NO{sub 3} flux. It contains N-Ag-N linear bonding. Display Omitted

Miura, Akira [Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen (Germany); Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853 (United States); Lowe, Michael; Leonard, Brian M.; Subban, Chinmayee V. [Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853 (United States); Masubuchi, Yuji; Kikkawa, Shinichi [Graduate School of Engineering, Hokkaido University, N13W8, Kita-ku Sapporo 060-8628 (Japan); Dronskowski, Richard [Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen (Germany); Hennig, Richard G. [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Abruna, Hector D. [Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853 (United States); DiSalvo, Francis J., E-mail: fjd3@cornell.ed [Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853 (United States)

2011-01-15T23:59:59.000Z

30

Visitor Tours at TA-53 TA53-FO-121-001A  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption by sectorlongUpdatesValley winsVideoVisitor Tours at TA-53

31

Microsoft Word - 2010 LASO TA-55 Upgrade Assessment _Activity...  

Broader source: Energy.gov (indexed) [DOE]

of actions being taken to support upgrading and future management of the TA-55 wet-pipe sprinkler system as a safety- class system. This review also satisfies a number of...

32

TA Position Available Fall Quarter 2014 Immediate Opening  

E-Print Network [OSTI]

in the development of course and workshop content and materials · Assist with the identification, invitationTA Position Available ­ Fall Quarter 2014 Immediate Opening Career Transitions with facilitation of panel/group discussions · Prepare and distribute marketing materials to departments

Bogyo, Matthew

33

Resistive switching of a TaO{sub x}/TaON double layer via ionic control of carrier tunneling  

SciTech Connect (OSTI)

Resistance random access memory (RRAM) is an attractive candidate for future non-volatile memory due to its superior features. As the oxide thickness is scaled down, the charge transport mechanism is also subject to the transition from hopping to tunneling dominant process, which is critically related to the interfacial electronic band structure. A TaO{sub x}/TaON double layer-based RRAM is fabricated and characterized in this work. Upon TaON insertion at the lower interface, the improved switching behavior is observed. The TaON at the bottom electrode interface blocks oxygen vacancy percolation due to strong N-O bonds and also modifies interfacial band alignment to lower the injected electron energy from bottom electrode due to higher tunneling barrier height than that of TaO{sub x}/Pt. This study suggested that a defect-minimized insertion layer like TaON with a proper interfacial band alignment is pivotal in RRAM for the effective ionic control of carrier tunneling resulting in non-linear I-V behavior with improved properties.

Jeon, Heeyoung; Park, Jingyu; Kim, Hyunjung [Department of Nano-Scale Semiconductor Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Jang, Woochool; Song, Hyoseok [Division of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Kang, Chunho [Division of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); FAB Manufacturing Division, SK Hynix Inc., 2091, Gyeongchung-daero, Bubal-eub, Icheon-si, Gyeonggi-do 167-701 (Korea, Republic of); Seo, Hyungtak, E-mail: hseo@ajou.ac.kr [Department of Materials Science and Engineering and Department of Energy Systems Research, Ajou University, Suwon 443-739 (Korea, Republic of); Jeon, Hyeongtag, E-mail: hjeon@hanyang.ac.kr [Department of Nano-Scale Semiconductor Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of); Division of Materials Science and Engineering, Hanyang University, Seoul 133-791 (Korea, Republic of)

2014-04-14T23:59:59.000Z

34

Improvement of SOFC Electrodes through Catalyst Infiltration & Control of Cr Volatilization from FeCr Components  

SciTech Connect (OSTI)

This presentation discusses the improvement of SOFC electrodes through catalyst infiltration and control of Cr volatilization from FeCr components.

Visco, S.J.; Jacobson, C.; Kurokawa, H.; Sholklapper, T.; Lu, C.; De Jonghe, L.

2005-01-28T23:59:59.000Z

35

Underpinning Mathematics/Science: (min 40 cr) Mathematics (16 cr)  

E-Print Network [OSTI]

Materials Science and Engineering BS Degree Requirements for students beginning in or after Fall 2011 04 324 Introductory Applied Statistics for Engineers Physics (10 cr) Phys 201 or Phys 207 or Phys 247 Modern Physics for Engineers Phys 235 Introduction to Solid State Electronics Phys 241 Intro to Modern

Wisconsin at Madison, University of

36

Evaluation of airflow patterns in 2706-T and 2706-TA  

SciTech Connect (OSTI)

The purpose of this study was to evaluate the adequacy of the current placement of fixed head air samplers and continuous air monitors (CAMs) in the 2706-T and 2706-TA Complex. The airflow study consisted of 6 configurations of facility HVAC and HEPA filtration equipment to determine impacts on CAM location. The results of this study provide recommendations based on guidance in DOE G 411.1-8 and NUREG-1400 for placement of fixed head air samplers or CAMS within 2706-T and 2706-TA.

DEROSA, D.C.

1999-08-26T23:59:59.000Z

37

DB-Netz AG Offices  

High Performance Buildings Database

Hamm, Germany The new office building for DB Netz AG was designed by the collaborative team of Architrav Architects and the Buildings Physics and Technical Building Services group of the University of Karlsruhe. The team developed an energy efficient building concept for the 64,304 sqft office building, located in Hamm, Germany. The design concept of the building is dominated by architectural solutions for ventilation, cooling and lighting. Use of HVAC and electric lighting is minimized as much as possible.

38

CRAD, Maintenance- Los Alamos National Laboratory TA 55 SST Facility  

Broader source: Energy.gov [DOE]

A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Maintenance program at the Los Alamos National Laboratory TA 55 SST Facility.

39

Compositional depth profiling of TaCN thin films  

SciTech Connect (OSTI)

The composition profiling of thin TaCN films was studied. For the composition profile determination using x-ray photoemission spectrometry (XPS) in combination with Ar sputtering, preferential sputtering effects of N with respect to Ta and C were found to lead to inaccurate elemental concentrations. Sputter yield calculations for the given experimental conditions allowed for the correction of a part of the error, leading to fair accuracy by reference-free measurements. Further improvement of the accuracy was demonstrated by the calibration of the XPS compositions against elastic recoil detection analysis (ERDA) results. For Auger electron spectrometry (AES) in combination with Ar sputtering, accurate results required the calibration against ERDA. Both XPS and AES allowed for a reliable and accurate determination of the compositional profiles of TaCN-based thin films after calibration. Time-of-flight secondary-ion mass spectrometry was also used to assess the composition of the TaCN films. However, the analysis was hampered by large matrix effects due to small unintentional oxygen contents in the films. Energy-dispersive x-ray spectrometry is also discussed, and it is shown that an accurate reference-free measurement of the average film concentration can be achieved.

Adelmann, Christoph; Conard, Thierry; Franquet, Alexis; Brijs, Bert; Munnik, Frans; Burgess, Simon; Witters, Thomas; Meersschaut, Johan; Kittl, Jorge A.; Vandervorst, Wilfried; Van Elshocht, Sven [Imec, B-3001 Leuven (Belgium); Forschungszentrum Dresden-Rossendorf, D-01314 Dresden (Germany); Oxford Instruments NanoAnalysis, High Wycombe, HP12 3SE (United Kingdom); Imec, B-3001 Leuven (Belgium); Imec, B-3001 Leuven, Belgium and Instituut voor Kern- en Stralingsfysica, Katholieke Universiteit Leuven, B-3001 Leuven (Belgium); Imec, B-3001 Leuven (Belgium)

2012-07-15T23:59:59.000Z

40

IWARTIIV IWARIET'TA MARTIN MARIETTA ENERGYSYSTEMS,INC.  

E-Print Network [OSTI]

OAK RIDGE NATIONAL LABORATORY IWARTIIV IWARIET'TA MANAGED BY MARTIN MARIETTA ENERGYSYSTEMS N. E. Clapp C. S. Daw Oak Ridge National Laboratory January 1996 CAUTION This document has not been. Hively N. E. Clapp C. S. Daw Oak Ridge National Laboratory January 1996 Prepared for U.S. Department

Hively, Lee M.

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

al cd cr: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

junctions with CrFe and CrFeCr barriers. Although the exact... Robinson, J. W. A.; Banerjee, N.; Blamire, M. G. 2014-03-05 134 SEM CR GRADE Intro to Chem Eng 1 Engineering...

42

E-Print Network 3.0 - acid ta dryer Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Wang,a Summary: ImmersionElectroless Deposition of Cu on Ta Zuocheng Wang,a Hongqi Li,a Hasan Shodiev,b and Ian... are deposited on Ta by a two-step process; galvanic...

43

Phonon and thermal properties of exfoliated TaSe2 thin films T. R. Pope,2  

E-Print Network [OSTI]

Phonon and thermal properties of exfoliated TaSe2 thin films Z. Yan,1 C. Jiang,1 T. R. Pope,2 C. F diselenide (2H-TaSe2) obtained via the "graphene-like" mechanical exfoliation of crystals grown by chemical films exfoliated from TaSe2 and other metal dichalcogenides, as well as for evaluating self

44

TA-2 water boiler reactor decommissioning (Phase 1)  

SciTech Connect (OSTI)

Removal of external structures and underground piping associated with the gaseous effluent (stack) line from the TA-2 Water Boiler Reactor was performed as Phase I of reactor decommissioning. Six concrete structures were dismantled and 435 ft of contaminated underground piping was removed. Extensive soil contamination by /sup 137/Cs was encountered around structure TA-2-48 and in a suspected leach field near the stream flowing through Los Alamos Canyon. Efforts to remove all contaminated soil were hampered by infiltrating ground water and heavy rains. Methods, cleanup guidelines, and ALARA decisions used to successfully restore the area are described. The cost of the project was approximately $320K; 970 m/sup 3/ of low-level solid radioactive waste resulted from the cleanup operations.

Elder, J.C.; Knoell, C.L.

1986-12-01T23:59:59.000Z

45

Proton induced fission of 181-Ta at relativistic energies  

E-Print Network [OSTI]

Total fission cross sections of 181-Ta induced by protons at different relativistic energies have been measured at GSI, Darmstadt. The inverse kinematics technique used together with a dedicated set-up, made it possible to determine these cross sections with high accuracy. The new data obtained in this experiment will contribute to the understanding of the fission process at high excitation energies. The results are compared with data from previous experiments and systematics for proton-induced fission cross sections.

Y. Ayyad; J. Benlliure; E. Casarejos; H. Álvarez-Pol; A. Bacquias; A. Boudard; M. Caamaño; T. Enqvist; V. Föhr; A. Keli?-Heil; K. Kezzar; S. Leray; C. Paradela; D. Pérez-Loureiro; R. Pleska?; D. Tarrío

2012-03-07T23:59:59.000Z

46

I. NANOSCIENCE COURSE REQUIREMENTS CR A. Communication Skills (8 cr.) CR APSC-101 Applied Science Profession I 1 ENGL-101 Freshman English Composition Required OR 3  

E-Print Network [OSTI]

I. NANOSCIENCE COURSE REQUIREMENTS CR A. Communication Skills (8 cr.) CR APSC-101 Applied Science OF SCIENCE Concentration in Nanoscience University of Wisconsin-Stout 2010-2011 #12;I. MATERIALS SCIENCE

Wu, Mingshen

47

Thermodynamics of Cr2O3, FeCr2O4, ZnCr2O4 and CoCr2O4  

SciTech Connect (OSTI)

High temperature heat capacity measurements were obtained for Cr{sub 2}O{sub 3}, FeCr{sub 2}O{sub 4}, ZnCr{sub 2}O{sub 4} and CoCr{sub 2}O{sub 4} using a differential scanning calorimeter. These data were combined with previously-available, overlapping heat capacity data at temperatures up to 400 K and fitted to 5-parameter Maier-Kelley C{sub p}(T) equations. Expressions for molar entropy were then derived by suitable integration of the Maier-Kelley equations in combination with recent S{sup o}(298) evaluations. Finally, a database of high temperature equilibrium measurements on the formation of these oxides was constructed and critically evaluated. Gibbs energies of Cr{sub 2}O{sub 3}, FeCr{sub 2}O{sub 4} and CoCr{sub 2}O{sub 4} were referenced by averaging the most reliable results at reference temperatures of 1100, 1400 and 1373 K, respectively, while Gibbs energies for ZnCr{sub 2}O{sub 4} were referenced to the results of Jacob [Thermochim. Acta 15 (1976) 79-87] at 1100 K. Thermodynamic extrapolations from the high temperature reference points to 298.15 K by application of the heat capacity correlations gave {Delta}{sub f}G{sup o}(298) = -1049.96, -1339.40, -1428.35 and -1326.75 kJ mol{sup -1} for Cr{sub 2}O{sub 3}, FeCr{sub 2}O{sub 4}, ZnCr{sub 2}O{sub 4} and CoCr{sub 2}O{sub 4}, respectively.

Ziemniak SE, Anovitz LM, Castelli RA, Porter WD

2007-01-09T23:59:59.000Z

48

Relational Database SQL: Querying the Relational DB  

E-Print Network [OSTI]

: auto-completion and command history Weigang Qiu Relational Database & SQL #12;Relational Database SQLRelational Database SQL: Querying the Relational DB Workshop: the "genome" Database Relational Database & SQL Weigang Qiu Department of Biological Sciences Hunter College BIOL 425 Computational

Qiu, Weigang

49

CryptDB: A Practical Encrypted Relational DBMS  

E-Print Network [OSTI]

CryptDB is a DBMS that provides provable and practical privacy in the face of a compromised database server or curious database administrators. CryptDB works by executing SQL queries over encrypted data. At its core are ...

Popa, Raluca Ada

2011-01-26T23:59:59.000Z

50

TaC Studios New Construction Test House  

SciTech Connect (OSTI)

As part of the NAHB Research Center Industry Partnership, Southface partnered with TaC Studios, an Atlanta based architecture firm specializing in residential and light commercial design, on the construction of a new test home in Atlanta, GA in the mixed humid climate zone. This home will serve as a model home for the builder partner and addresses Building America energy savings targets through the planning and implementation of a design package will serve as a basis of design for the builder partner's future homes. As a BA test house, this home will be evaluated to detail whole house energy use, end use loads, and HVAC and hot water efficiency.

Butler, T.; Curtis, O.; Kim, E.; Roberts, S.; Stephenson, R.

2013-03-01T23:59:59.000Z

51

Reduced-temperature processing and consolidation of ultra-refractory Ta4HfC5  

SciTech Connect (OSTI)

TaC, HfC, and WC powders were subjected to high-energy milling and hot pressing to produce Ta4HfC5, a composite of Ta(4)HfC5 + 30 vol.% WC, and a composite of Ta4HfC5 + 50 vol.% WC. Sub-micron powders were examined after four different milling intervals prior to hot pressing. XRD was used to verify proper phase formation. SEM, relative density, and hardness measurements were used to examine the resulting phases. Hot pressed compacts of Ta4HfC5 showed densification as high as 98.6% along with Vickers hardness values of 21.4 GPa. Similarly, Ta4HfC5 + 30 vol.% WC exhibited 99% densification with a Vickers hardness of 22.5 GPa. These levels of densification were achieved at 1500 degrees C, which is lower than any previously reported sintering temperature for Ta4HfC5. Microhardness values measured in this study were higher than those previously reported for Ta4HfC5. The WC additions to Ta4HfC5 were found to improve densification and increase microhardness. (C) 2013 Elsevier Ltd. All rights reserved.

Gaballa, Osama [Ames Laboratory; Cook, B. A. [TRI International; Russell, A. M. [Ames Laboratory

2013-04-26T23:59:59.000Z

52

Watermelon-like iron nanoparticles: Cr doping effect on magnetism...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Watermelon-like iron nanoparticles: Cr doping effect on magnetism and magnetization interaction reversal. Watermelon-like iron nanoparticles: Cr doping effect on magnetism and...

53

AVTA: 2010 Honda CR-Z Hybrid Downloadable Dynamometer Database...  

Energy Savers [EERE]

CR-Z Hybrid Downloadable Dynamometer Database Reports AVTA: 2010 Honda CR-Z Hybrid Downloadable Dynamometer Database Reports The Vehicle Technologies Office's Advanced Vehicle...

54

Geology of the Western Part of Los Alamos National Laboratory (TA-3 to TA-16), Rio Grande Rift, New Mexico  

SciTech Connect (OSTI)

We present data that elucidate the stratigraphy, geomorphology, and structure in the western part of Los Alamos National Laboratory between Technical Areas 3 and 16 (TA-3 and TA-16). Data include those gathered by geologic mapping of surficial, post-Bandelier Tuff strata, conventional and high-precision geologic mapping and geochemical analysis of cooling units within the Bandelier Tuff, logging of boreholes and a gas pipeline trench, and structural analysis using profiles, cross sections, structure contour maps, and stereographic projections. This work contributes to an improved understanding of the paleoseismic and geomorphic history of the area, which will aid in future seismic hazard evaluations and other investigations. The study area lies at the base of the main, 120-m (400-ft) high escarpment formed by the Pajarito fault, an active fault of the Rio Grande rift that bounds Los Alamos National Laboratory on the west. Subsidiary fracturing, faulting, and folding associated with the Pajarito fault zone extends at least 1,500 m (5,000 ft) to the east of the main Pajarito fault escarpment. Stratigraphic units in the study area include upper units of the Tshirege Member of the early Pleistocene Bandelier Tuff, early Pleistocene alluvial fan deposits that predate incision of canyons on this part of the Pajarito Plateau, and younger Pleistocene and Holocene alluvium and colluvium that postdate drainage incision. We discriminate four sets of structures in the area between TA-3 and TA-16: (a) north-striking faults and folds that mark the main zone of deformation, including a graben in the central part of the study area; (b) north-northwest-striking fractures and rare faults that bound the eastern side of the principal zone of deformation and may be the surface expression of deep-seated faulting; (c) rare northeast-striking structures near the northern limit of the area associated with the southern end of the Rendija Canyon fault; and (d) several small east-west-striking faults. We consider all structures to be Quaternary in that they postdate the Tshirege Member (1.22 million years old) of the Bandelier Tuff. Older mesa-top alluvial deposits (Qoal), which may have a large age range but are probably in part about 1.13 million years old, are clearly faulted or deformed by many structures. At two localities, younger alluvial units (Qfo and Qfi) appear to be truncated by faults, but field relations are obscure, and we cannot confirm the presence of fault contacts. The youngest known faulting in the study area occurred in Holocene time on a down-to-the-west fault, recently trenched at the site of a new LANL Emergency Operations Center (Reneau et al. 2002).

C.J.Lewis; A.Lavine; S.L.Reneau; J.N.Gardner; R.Channell; C.W.Criswell

2002-12-01T23:59:59.000Z

55

Mn-Fe base and Mn-Cr-Fe base austenitic alloys  

DOE Patents [OSTI]

Manganese-iron base and manganese-chromium-iron base austenitic alloys designed to have resistance to neutron irradiation induced swelling and low activation have the following compositions (in weight percent): 20 to 40 Mn; up to about 15 Cr; about 0.4 to about 3.0 Si; an austenite stabilizing element selected from C and N, alone or in combination with each other, and in an amount effective to substantially stabilize the austenite phase, but less than about 0.7 C, and less than about 0.3 N; up to about 2.5 V; up to about 0.1 P; up to about 0.01 B; up to about 3.0 Al; up to about 0.5 Ni; up to about 2.0 W; up to about 1.0 Ti; up to about 1.0 Ta; and with the remainder of the alloy being essentially iron.

Brager, Howard R. (Richland, WA); Garner, Francis A. (Richland, WA)

1987-01-01T23:59:59.000Z

56

CR-B-02-01.PDF  

Office of Environmental Management (EM)

CR-B-02-01 AUDIT REPORT FIXED-PRICE CONTRACTING FOR DEPARTMENT OF ENERGY CLEANUP ACTIVITIES OCTOBER 2001 U.S. DEPARTMENT OF ENERGY OFFICE OF INSPECTOR GENERAL OFFICE OF AUDIT...

57

CR-B-02-02.PUB  

Energy Savers [EERE]

CR-B-02-02 AUDIT REPORT U.S. DEPARTMENT OF ENERGY OFFICE OF INSPECTOR GENERAL OFFICE OF AUDIT SERVICES PROCUREMENT ADMINISTRATION AT BROOKHAVEN NATIONAL LABORATORY AUGUST 2002 U....

58

SciDB for Array Data  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmitted for USMaterialstheterahertzon HomeScholarshipsSciDB SciDB Screen

59

Physical and chemical characterization of combinatorial metal gate electrode Ta-C-N library film  

SciTech Connect (OSTI)

This paper reports comprehensive structural and chemical analyses for the combinatorial Ta-C-N/HfO{sub 2} system, crucial data for understanding the electrical properties of Ta-C-N/HfO{sub 2}. Combinatorial Ta-C-N 'library' (composition spread) films were deposited by magnetron sputtering. Electron probe wavelength dispersive spectroscopy and x-ray fluorescence-yield near-edge spectroscopy were used to quantitatively determine the composition across these films. Scanning x-ray microdiffractometry determined that a solid solution of Ta(C,N){sub x} forms and extends to compositions (0.3<=Ta<=0.5 and 0.57<=Ta<=0.67) that were previously unknown. The thermal stability of the Ta-C-N/HfO{sub 2} library was studied using high resolution transmission electron microscopy, which shows Ta-C-N/HfO{sub 2}/SiO{sub 2}/Si exhibiting good thermal stability up to 950 deg. C.

Chang, K.-S. [National Institute of Standards and Technology (NIST), Gaithersburg, Maryland 20899 (United States); Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20742 (United States); Green, M. L.; Levin, I.; Hattrick-Simpers, J. R.; Jaye, C.; Fischer, D. A. [National Institute of Standards and Technology (NIST), Gaithersburg, Maryland 20899 (United States); Takeuchi, I. [Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20742 (United States); De Gendt, S. [IMEC, Kapeldreef 75, B-3001 Leuven, Belgium and Department of Chemistry, KU Leuven, 3000 Leuven (Belgium)

2010-05-10T23:59:59.000Z

60

Triplet pair correlations and nonmonotonic supercurrent decay with Cr thickness in Nb/Cr/Fe/Nb Josephson devices  

E-Print Network [OSTI]

roughness and interdiffusion, an antiferromagnetic spin density wave (SDW) state can still form in Cr close to the interface. Here, we show evidence for triplet pair correlations in Josephson junctions with Cr/Fe and Cr/Fe/Cr barriers. Although the exact...

Robinson, J. W. A.; Banerjee, N.; Blamire, M. G.

2014-03-05T23:59:59.000Z

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Structural studies of the metal-rich region in the ternary Ta-Nb-S system  

SciTech Connect (OSTI)

Six new solid solution type compounds have been prepared using high temperature techniques and characterized by means of single crystal x-ray techniques during a study of the metal-rich region of the ternary Ta-Nb-S system. The structures of Nb{sub x}Ta{sub 11-x}S{sub 4} are reminiscent of niobium-rich sulfides, rather than of tantalum-rich sulfides. The coordinations of sulfur are capped trigonal prismatic while the metal coordinations are capped distorted cubic prismatic for Nb{sub x}Ta{sub 11-x}S{sub 4}, and capped distorted cubic prismatic and pentagonal prismatic for Nb{sub 12-x}Ta{sub x}S{sub 4}. The structures of Nb{sub x}Ta{sub 5-x}S{sub 2} contain homoatomic layers sequenced S-M3-M2-M1-M2-M3-S (M is mixed Nb, Ta) generating six-layer sheets, respectively. Weak S-S interactions at 3.26 and 3.19{Angstrom} between sheets contrast with the M-M binding within and between the sheets in these two novel layered compounds. The former are presumably responsible for the observed graphitic slippage of the samples. Nb{sub 21-x}Ta{sub x}S{sub 8} and Nb{sub x}Ta{sub 2-x}S are isostructural with Nb{sub 21}S{sub 8} and Ta{sub 2}S, respectively. Extended Hueckel band calculations were carried out for two layered compounds, Nb{sub x}Ta{sub 5-x}S{sub 2} (x {approx} 1.72) and Nb{sub x}ta{sub 2-x}S (x {approx} 0.95). Based upon band calculations metallic properties can be expected for these two layered compounds. The relative preference of the metal sites for the two metal elements (Ta, Nb) in two layered compounds is explained by the results of the band calculations. 17 figs., 31 tabs., 80 refs.

Yao, Xiaoqiang.

1991-10-07T23:59:59.000Z

62

V-070: Apache CouchDB Multiple Vulnerabilities | Department of...  

Broader source: Energy.gov (indexed) [DOE]

access files. This can be exploited to disclose the contents of arbitrary files via directory traversal sequences. Only Microsoft Windows versions of Apache CouchDB are affected....

63

-delayed proton emission branches in 43Cr  

SciTech Connect (OSTI)

The + decay of very neutron-deficient 43Cr was studied by means of an imaging time projection chamber that allowed recording tracks of charged particles. Events of -delayed emission of one, two, and three protons were clearly identified. The absolute branching ratios for these channels were determined to be (81 4)%, (7.1 0.4)%, and (0.08 0.03)%, respectively. 43Cr is thus established as the second case in which the -3p decay occurs. Although the feeding to the proton-bound states in 43V is expected to be negligible, the large branching ratio of (12 4)% for decays without proton emission is found.

Pomorski, M. [University of Warsaw; Miernik, K. [University of Warsaw; Dominik, W. [University of Warsaw; Janas, Z. [University of Warsaw; Pfutzner, M. [University of Warsaw; Bingham, C. R. [University of Tennessee, Knoxville (UTK); Czyrkowski, H. [University of Warsaw; Cwiok, Mikolaj [Warsaw University; Darby, Iain [University of Tennessee, Knoxville (UTK); Dabrowski, Ryszard [Warsaw University; Ginter, T. N. [Michigan State University, East Lansing; Grzywacz, Robert Kazimierz [ORNL; Karny, M. [University of Warsaw; Korgul, A. [University of Warsaw; Kusmierz, W. [University of Warsaw; Liddick, Sean [University of Tennessee, Knoxville (UTK); Rajabali, M. M. [University of Tennessee, Knoxville (UTK); Rykaczewski, Krzysztof Piotr [ORNL; Stolz, A. [Michigan State University, East Lansing

2011-01-01T23:59:59.000Z

64

Influence of shockwave obliquity on deformation twin formation in Ta  

SciTech Connect (OSTI)

Energetic loading subjects a material to a 'Taylor wave' (triangular wave) loading profile that experiences an evolving balance of hydrostatic (spherical) and deviatoric stresses. While much has been learned over the past five decades concerning the propensity of deformation twinning in samples shockloaded using 'square-topped' profiles as a function of peak stress, achieved most commonly via flyer plate loading, less is known concerning twinning propensity during non-I-dimensional sweeping detonation wave loading. Systematic small-scale energetically-driven shock loading experiments were conducted on Ta samples shock loaded with PEFN that was edge detonated. Deformation twinning was quantified in post-mortem samples as a function of detonation geometry and radial position. In the edge detonated loading geometry examined in this paper, the average volume fraction of deformation twins was observed to drastically increase with increasing shock obliquity. The results of this study are discussed in light of the formation mechanisms of deformation twins, previous literature studies of twinning in shocked materials, and modeling of the effects of shock obliquity on the evolution of the stress tensor during shock loading.

Gray, George T., III [Los Alamos National Laboratory; Livescu, V [Los Alamos National Laboratory; Cerreta, E K [Los Alamos National Laboratory; Mason, T A [Los Alamos National Laboratory; Maudlin, P J [RETIRED; Bingert, J F [Los Alamos National Laboratory

2009-02-18T23:59:59.000Z

65

Morphology, deformation, and defect structures of TiCr{sub 2} in Ti-Cr alloys  

SciTech Connect (OSTI)

The morphologies and defect structures of TiCr{sub 2} in several Ti-Cr alloys have been examined by optical metallography, x-ray diffraction, and transmission electron microscopy (TEM), in order to explore the room-temperature deformability of the Laves phase TiCr{sub 2}. The morphology of the Laves phase was found to be dependent upon alloy composition and annealing temperature. Samples deformed by compression have also been studied using TEM. Comparisons of microstructures before and after deformation suggest an increase in twin, stacking fault, and dislocation density within the Laves phase, indicating some but not extensive room-temperature deformability.

Chen, K.C.; Allen, S.M.; Livingston, J.D.

1992-12-31T23:59:59.000Z

66

Collisional spreading of Enceladus' neutral cloud T.A. Cassidy *, R.E. Johnson  

E-Print Network [OSTI]

Collisional spreading of Enceladus' neutral cloud T.A. Cassidy *, R.E. Johnson Charlottesville exchange momentum, causing deflections whether or not a charge exchange occurs (e.g., Johnson et al., 2006a

Johnson, Robert E.

67

Model independent determination of the spin of the {sup 180}Ta naturally occurring isomer  

SciTech Connect (OSTI)

The hyperfine structures of the 33715.27 cm{sup -1} and 33706.47 cm{sup -1} transitions from the ground state of singly ionized Ta have been measured by collinear laser spectroscopy. The structures were found to contain a large second order contribution. From fitting the observed hyperfine components for both {sup 181}Ta and the {sup 180}Ta naturally occurring isomer it was possible to determine the first and second order hyperfine structure coefficients. As no model independent determination of the nuclear spin of the {sup 180}Ta isomer has been performed, fitting was attempted for a range of spins. A clear chi-squared minimum is obtained for a nuclear spin of 9, in agreement with model dependent measurements.

Bissell, M. L.; Baczynska, K.; Forest, D. H.; Gardner, M. D.; Tungate, G. [School of Physics and Astronomy, The University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom); Billowes, J.; Campbell, P.; Cheal, B.; Tordoff, B. [Schuster Laboratory, The University of Manchester, Manchester M13 9PL (United Kingdom); Eronen, T.; Moore, I. D.; Aeystoe, J. [Department of Physics, University of Jyvaeskylae, PB 35 (YFL), FIN-40014 Jyvaeskylae (Finland)

2006-10-15T23:59:59.000Z

68

Energy-beam processing studies on Ta/U and Ir/Ta systems. [Laser-and electron-beam melting  

SciTech Connect (OSTI)

Films of Ta metal on uranium and of Ir metal on tantalum have been irradiated and melted by pulses from Q-switched Ruby and frequency-doubled Nd:YAG lasers to investigate the nature of the resulting mixtures in light of the very different binary-phase diagrams of the two systems. In addition, a two-phase Ir-Ta alloy has been surface-processed with CW CO/sub 2/-laser radiation and with an electron beam in order to study microstructure refinement and test the advantage of using alloys as opposed to film-on-substrate combinations for the development of claddings.

Kaufmann, E.N.; Peercy, P.S.; Jacobson, D.C.; Draper, C.W.; Huegel, F.J.; Echer, C.J.; Makowiecki, D.M.; Balser, J.D.

1983-11-11T23:59:59.000Z

69

Unique LaTaO[subscript 4] Polymorph for Multiple Energy Applications  

SciTech Connect (OSTI)

Rare-earth niobate and tantalate (RE-Nb/Ta) materials are of considerable interest in environmental and energy-related applications that include phosphors for solid-state lighting, photocatalysts for both contaminant degeneration and H{sub 2} generation, chemically robust hosts for nuclear materials and wastes, and ion conductors for lithium batteries or solid-oxide fuel cells. However, the chemically inert nature limits the synthetic routes available to obtain these materials, which in turn hampers the discovery and development of new RE-Nb/Ta phases. Of the simple orthotantalate, LaTaO{sub 4}, there were three polymorphs known prior. With this paper, we present the structural characterization (from high-resolution X-ray powder diffraction data collected at the APS 11-BM line) of a fourth polymorph. It is obtained only from dehydration of La{sub 2}Ta{sub 2}O{sub 7}(OH){sub 2}, which is in turn synthesized hydrothermally. The structure of the new LaTaO{sub 4} polymorph is distinctive from the others in the arrangement of the alternating La-O polyhedra layers and TaO{sub 6} octahedra layers. Luminescence measurements (Eu-doped) and photocatalysis studies of the new LaTaO{sub 4} polymorph, and comparison to the performance of a previously described LaTaO{sub 4} polymorph reveals enhanced performance of the new polymorph in both applications. This study illustrates the relevance of form-function relationships in solid-state materials, as well as the important role of synthesis in the development of advanced functional materials.

Nyman, May; Rodriguez, Mark A.; Rohwer, Lauren E.S.; Martin, James E.; Waller, Mollie; Osterloh, Frank E.; (Sandia); (UCD)

2009-11-04T23:59:59.000Z

70

NUREG/CR-6870 Consideration of Geochemical  

E-Print Network [OSTI]

in Groundwater Restoration at Uranium In-Situ Leach Mining Facilities Manuscript Completed: December 2006 Date associated with uranium mining sites throughout the United States are also included in this report. A tableNUREG/CR-6870 Consideration of Geochemical Issues in Groundwater Restoration at Uranium In

71

Fluoride (F) is not taken up by Salmonella typhimurium TA98 (TA98), used for Ames mutagenicity test, unless aluminum (Al) is present  

SciTech Connect (OSTI)

TA98 is commonly used for the Ames test to detect frame-shift mutations. Ames test results for fluoride mutagenicity are controversial. Since Al and F, both present in finished drinking water, form a stable complex, the authors determined the effect of Al on F uptake by TA98 to evaluate any Al effect on Ames test results for F. A known number of TA98 in 0.1M potassium phosphate buffer was incubated with various concentrations of Al, F or aluminum fluoride for 1 hr at 37C in a shaking incubator. The cells were washed twice in potassium phosphate buffer and then resuspended in water. After breaking the cells open by sonication, the resulting supernatant was analyzed for Al by graphite furnace atomic absorption and for F using a F ion-selective electrode. Al accumulated in a concentration-dependent manner to 4.5 ppm then decreased rapidly as the Al was increased to 9 ppm. Intracellular F was below the limit of detection even when the medium contained 590 ppm F. However, F was taken up from media containing greater than 200 ppm F, providing that aluminum was also present. The authors conclude that the Ames test, using TA98, is not suitable for the detection of F mutagenicity.

Ahn, H.W.; Jeffery, E.H. (Univ. of Illinois, Urbana (United States))

1991-03-11T23:59:59.000Z

72

E-Print Network 3.0 - aceros al cr-mo-v Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

G. F. Janssens, Dierk Raabe, Ernst Kozeschnik, Mark A. Miodownik, Summary: , ,,Dissimilar 2.25Cr-9Cr and 2Cr-0.5CrMoV steel welds, I. Characterisation of the weld zone and...

73

Cr-doped scandium borate laser  

DOE Patents [OSTI]

A broadly wavelength-tunable laser is provided which comprises as the laser medium a single crystal of MBO.sub.3 :Cr.sup.3+, where M is selected from the group of Sc, In and Lu. The laser may be operated over a broad temperature range from cryogenic temperatures to elevated temperatures. Emission is in a spectral range from red to infrared, and the laser is useful in the fields of defense, communications, isotope separation, photochemistry, etc.

Chai, Bruce H. (Bridgewater, NJ); Lai, Shui T. (Florham Park, NJ); Long, Margaret N. (Landing, NJ)

1989-01-01T23:59:59.000Z

74

Precessional magnetization induced spin current from CoFeB into Ta  

SciTech Connect (OSTI)

The spin dynamics at the interface between the CoFeB and Ta layer has been studied using spin pumping and spin wave characterizations. The spin pumping driven by the ferromagnetic resonance in the CoFeB layer injects a spin current into Ta layer which results in an electromotive force across the Ta layer due to the inverse spin Hall effect. Upon changing the polarity of the bias magnetic field, the polarity of the output voltage inverts and the output voltage increases linearly in respect to the microwave signal power which are consistent with the spin pumping characteristics. The effect of the in-plane magnetization angle on the output voltage has been studied. Furthermore, it is found that the frequency spectrum of the spin Hall voltage is modified by the annealing temperature and the full width at half maximum of the spin pumping increases by more than 40% with the increase of the annealing temperature from 200?°C to 300?°C. The spin Hall angle at the Ta-CoFeB interface is determined to be 0.014, and the damping constant of the CoFeB increases from 0.006 in pure CoFeB to 0.015 in Ta/CoFeB film.

Jamali, Mahdi; Klemm, Angeline; Wang, Jian-Ping, E-mail: jpwang@umn.edu [Department of Electrical and Computer Engineering, University of Minnesota, 4-174 200 Union Street SE, Minneapolis, Minnesota 55455 (United States)] [Department of Electrical and Computer Engineering, University of Minnesota, 4-174 200 Union Street SE, Minneapolis, Minnesota 55455 (United States)

2013-12-16T23:59:59.000Z

75

Carbon migration in 5Cr-0.5Mo/21Cr-12Ni dissimilar metal welds  

SciTech Connect (OSTI)

The carbon migration between a ferritic steel and an austenitic steel was studied in submerged arc-welded 5Cr-0.5Mo/21Cr-12Ni dissimilar metal welds (DMWs) after aging at 500 C for various times and after long-term service in technical practice. The distribution of carbon, chromium, nickel, and iron in the areas around the weld interface was determined by electron probe microanalysis, and the microstructural aspect in the carbon-depleted/enriched zone was characterized by optical microscopy and transmission electron microscopy (TEM). Furthermore, the precipitation sequences and composition characteristics of the carbides were identified by diffraction pattern microanalysis and energy-dispersive X-ray (EDX) microanalysis. It was found (1) that there exists a coherent relationship between intracrystalline M{sub 23}C{sub 6} and the austenitic matrix; (2) that the composition of M{sub 23}C{sub 6} in the carbon-enriched zone is independent of the duration of aging and service; (3) that the maximum carbon concentration is determined by the carbide type, the composition characteristic of precipitated carbides, and the concentration of carbide-forming Cr adjacent to the weld interface in the carbon-enriched zone; and (4) that the carbon migration in the 5Cr-0.5Mo/21Cr-12Ni DMWs can be described by a diffusion model.

Huang, M.L.; Wang, L. [Dalian Univ. of Technology (China). Dept. of Materials Engineering

1998-12-01T23:59:59.000Z

76

Role of spin mixing conductance in spin pumping: Enhancement of spin pumping efficiency in Ta/Cu/Py structures  

SciTech Connect (OSTI)

From spin pumping measurements in Ta/Py devices for different thicknesses of Ta, we determine the spin Hall angle to be 0.021–0.033 and spin diffusion length to be 8?nm in Ta. We have also studied the effect of changing the properties of non-magnet/ferromagnet interface by adding a Cu interlayer. The experimental results show that the effective spin mixing conductance increases in the presence of Cu interlayer for Ta/Cu/Py devices whereas it decreases in Pt/Cu/Py devices. Our findings allow the tunability of the spin pumping efficiency by adding a thin interlayer at the non-magnet/ferromagnet interface.

Deorani, Praveen; Yang, Hyunsoo, E-mail: eleyang@nus.edu.sg [Department of Electrical and Computer Engineering, National University of Singapore, 117576 Singapore (Singapore)] [Department of Electrical and Computer Engineering, National University of Singapore, 117576 Singapore (Singapore)

2013-12-02T23:59:59.000Z

77

A COMPREHENSIVE SPECTROSCOPIC ANALYSIS OF DB WHITE DWARFS  

SciTech Connect (OSTI)

We present a detailed analysis of 108 helium-line (DB) white dwarfs based on model atmosphere fits to high signal-to-noise optical spectroscopy. We derive a mean mass of 0.67 M{sub sun} for our sample, with a dispersion of only 0.09 M{sub sun}. White dwarfs also showing hydrogen lines, the DBA stars, comprise 44% of our sample, and their mass distribution appears similar to that of DB stars. As in our previous investigation, we find no evidence for the existence of low-mass (M < 0.5 M{sub sun}) DB white dwarfs. We derive a luminosity function based on a subset of DB white dwarfs identified in the Palomar-Green Survey. We show that 20% of all white dwarfs in the temperature range of interest are DB stars, although the fraction drops to half this value above T{sub eff} {approx} 20,000 K. We also show that the persistence of DB stars with no hydrogen features at low temperatures is difficult to reconcile with a scenario involving accretion from the interstellar medium, often invoked to account for the observed hydrogen abundances in DBA stars. We present evidence for the existence of two different evolutionary channels that produce DB white dwarfs: the standard model where DA stars are transformed into DB stars through the convective dilution of a thin hydrogen layer and a second channel where DB stars retain a helium atmosphere throughout their evolution. We finally demonstrate that the instability strip of pulsating V777 Her white dwarfs contains no non-variables, if the hydrogen content of these stars is properly accounted for.

Bergeron, P.; Wesemael, F.; Dufour, Pierre; Beauchamp, A.; Hunter, C.; Gianninas, A.; Limoges, M.-M.; Dufour, Patrick; Fontaine, G. [Departement de Physique, Universite de Montreal, C.P. 6128, Succ. Centre-Ville, Montreal, QC H3C 3J7 (Canada); Saffer, Rex A. [Strayer University, 234 Mall Boulevard, Suite G-50, King of Prussia, PA 19406 (United States); Ruiz, M. T. [Departamento de Astronomia, Universidad de Chile, Casilla 36-D, Santiago (Chile); Liebert, James, E-mail: bergeron@astro.umontreal.ca, E-mail: wesemael@astro.umontreal.ca, E-mail: gianninas@astro.umontreal.ca, E-mail: limoges@astro.umontreal.ca, E-mail: dufourpa@astro.umontreal.ca, E-mail: fontaine@astro.umontreal.ca, E-mail: alain.beauchamp@fti-ibis.com, E-mail: chris.hunter@yale.edu, E-mail: rex.saffer@strayer.edu, E-mail: mtruiz@das.uchile.cl [Steward Observatory, University of Arizona, Tucson, AZ 85721 (United States)

2011-08-10T23:59:59.000Z

78

Page 1 of 11 The Value of IBM's DB2 Utilities and Tools in 2011 The Value of IBM's DB2 Utilities and Tools in 2011  

E-Print Network [OSTI]

Page 1 of 11 The Value of IBM's DB2 Utilities and Tools in 2011 The Value of IBM's DB2 Utilities The Value of IBM's DB2 Utilities and Tools in 2011 Table of Contents I. EXECUTIVE SUMMARY.................................................................................... 5 IV. UTILITY PERFORMANCE AND TOTAL COST OF OWNERSHIP

79

The effect of Ta interface on the crystallization of amorphous phase change material thin films  

SciTech Connect (OSTI)

The crystallization of amorphous GeTe and Ge{sub 2}Sb{sub 2}Te{sub 5} phase change material films, with thickness between 10 and 100?nm, sandwiched between either Ta or SiO{sub 2} layers, was investigated by optical reflectivity. Ta cladding layers were found to increase the crystallization temperature, even for films as thick as 100?nm. X-Ray diffraction investigations of crystallized GeTe films showed a very weak texture in Ta cladded films, in contrast with the strong texture observed for SiO{sub 2} cladding layers. This study shows that crystallization mechanism of phase change materials can be highly impacted by interface effects, even for relatively thick films.

Ghezzi, G. E. [CEA-LETI, MINATEC campus, 17 rue des Martyrs, F 38054 Grenoble (France); LMGP, CNRS Grenoble-INP, MINATEC, 3 parvis Louis Néel, F 38016 Grenoble (France); Noé, P., E-mail: pierre.noe@cea.fr; Marra, M.; Sabbione, C.; Fillot, F.; Bernier, N.; Ferrand, J.; Maîtrejean, S. [CEA-LETI, MINATEC campus, 17 rue des Martyrs, F 38054 Grenoble (France); Hippert, F. [LMGP, CNRS Grenoble-INP, MINATEC, 3 parvis Louis Néel, F 38016 Grenoble (France); LNCMI (CNRS, UJF, UPS, INSA), 25 rue des Martyrs, F 38042 Grenoble Cedex 9 (France)

2014-06-02T23:59:59.000Z

80

Role of structural factors in formation of chiral magnetic soliton lattice in Cr{sub 1/3}NbS{sub 2}  

SciTech Connect (OSTI)

The sign and strength of magnetic interactions not only between nearest neighbors, but also for longer-range neighbors in the Cr{sub 1/3}NbS{sub 2} intercalation compound have been calculated on the basis of structural data. It has been found that left-handed spin helices in Cr{sub 1/3}NbS{sub 2} are formed from strength-dominant at low temperatures antiferromagnetic (AFM) interactions between triangular planes of Cr{sup 3+} ions through the plane of just one of two crystallographically equivalent diagonals of side faces of embedded into each other trigonal prisms building up the crystal lattice of magnetic Cr{sup 3+} ions. These helices are oriented along the c axis and packed into two-dimensional triangular lattices in planes perpendicular to these helices directions and lay one upon each other with a displacement. The competition of the above AFM helices with weaker inter-helix AFM interactions could promote the emergence of a long-period helical spin structure. One can assume that in this case, the role of Dzyaloshinskii-Moriya interaction consists of final ordering and stabilization of chiral spin helices into a chiral magnetic soliton lattice. The possibility of emergence of solitons in M{sub 1/3}NbX{sub 2} and M{sub 1/3}TaX{sub 2} (M?=?Cr, V, Ti, Rh, Ni, Co, Fe, and Mn; X?=?S and Se) intercalate compounds has been examined. Two important factors caused by the crystal structure (predominant chiral magnetic helices and their competition with weaker inter-helix interactions not destructing the system quasi-one-dimensional character) can be used for the crystal chemistry search of solitons.

Volkova, L. M.; Marinin, D. V. [Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences, 690022 Vladivostok (Russian Federation)

2014-10-07T23:59:59.000Z

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Atomic and vacancy ordering in carbide {zeta}-Ta{sub 4}C{sub 3-x} (0.28{<=}x{<=}0.40) and phase equilibria in the Ta-C system  

SciTech Connect (OSTI)

The structure of nonstoichiometric carbide phase {zeta}-Ta{sub 4}C{sub 3-x} formed in the tantalum-carbon (Ta-C) system is studied by X-ray and neutron powder diffraction and metallography. Investigated carbide {zeta}-TaC{sub 0.67} crystallizes in a trigonal (rhombohedral) space group R3-barm with cell parameters a{sub tr}=1.0180(1) nm, {alpha}{sub tr}=17.64 deg. (or a{sub h}=0.31216(2) nm, c{sub h}=3.0058(1) nm in hexagonal axes). The closely packed metal sublattice in carbide {zeta}-Ta{sub 4}C{sub 3-x} consists of alternating blocks where metal atoms are located in the same manner as on the FCC sublattice of the cubic carbide TaC{sub y} and the HCP sublattice of the hexagonal carbide Ta{sub 2}C{sub y}. This metal sublattice represents a transition sublattice between these FCC and HCP sublattices. An ordered distribution of atoms C and structural vacancies in carbide {zeta}-Ta{sub 4}C{sub 3-x} is revealed and the distribution function of atoms C is calculated for nonmetal sublattice sites, on which ordering takes place. It is shown that one long-range order parameter {eta} describes the ordering of {zeta}-carbide and the {eta} value in the investigated {zeta}-Ta{sub 4}C{sub 3-x} phase does not exceed 0.7. Carbide {zeta}-Ta{sub 4}C{sub 3-x} is stable in bulk and powdered states over a wide temperature interval of 300 to {approx}2400 K and has a narrow homogeneity interval from TaC{sub 0.65} to TaC{sub 0.68}. Microhardness of disordered and ordered tantalum carbide TaC{sub y} with the basic B1 structure and trigonal carbide {zeta}-Ta{sub 4}C{sub 3-x} is measured. The phase diagram of the Ta-C system is refined considering data obtained for the {zeta}-Ta{sub 4}C{sub 3-x} phase. - Graphical abstract: Ordered distribution of carbon atoms C and structural vacancies in a unit cell of the trigonal (space group R3-barm) {zeta}-Ta{sub 4}C{sub 3-x} phase. The closely packed metal sublattice in carbide {zeta}-Ta{sub 4}C{sub 3-x} consists of alternating blocks where Ta atoms are located in the same manner as on the FCC sublattice of the cubic carbide TaC{sub y} and the HCP sublattice of the hexagonal carbide Ta{sub 2}C{sub y}.

Gusev, A.I. [Institute of Solid State Chemistry, Ural Division of the Russian Academy of Sciences, 620041 Yekaterinburg (Russian Federation)], E-mail: gusev@ihim.uran.ru; Kurlov, A.S.; Lipatnikov, V.N. [Institute of Solid State Chemistry, Ural Division of the Russian Academy of Sciences, 620041 Yekaterinburg (Russian Federation)

2007-11-15T23:59:59.000Z

82

BayesDB : querying the probable implications of tabular data  

E-Print Network [OSTI]

BayesDB, a Bayesian database table, lets users query the probable implications of their tabular data as easily as an SQL database lets them query the data itself. Using the built-in Bayesian Query Language (BQL), users ...

Baxter, Jay

2014-01-01T23:59:59.000Z

83

Remote data access and analysis using SciDB  

E-Print Network [OSTI]

SciDB is an innovative data analysis system that provides fast querying and manipulation of large amounts of time-series, scientific data. This thesis describes the design of a framework that provides a user interface to ...

Anderson, Alan M., M. Eng. Massachusetts Institute of Technology

2012-01-01T23:59:59.000Z

84

The following 24 credits are required. Course Cr Semester Course Cr Semester  

E-Print Network [OSTI]

Fundamentals of Pest Management 3 Soil and Water Science Minor 15 credits required Course Cr Required SWS Agriculture & Environmental Quality 3 SWS2007 World of Water 3 SWS2008 Humans, Soils, & Environmental Impact 3 SWS3023L Soil Judging 2 SWS4116 Environmental Nutrient Management 3 SWS4223 Environmental

Watson, Craig A.

85

CR mammography: Design and implementation of a quality control program  

SciTech Connect (OSTI)

Despite the recent acquisition of significant quantities of computed radiography CR equipment for mammography, Mexican regulations do not specify the performance requirements for digital systems such as those of CR type. The design of a quality control program QCP specific for CR mammography systems was thus considered relevant. International protocols were taken as reference to define tests, procedures and acceptance criteria. The designed QCP was applied in three CR mammography facilities. Important deficiencies in spatial resolution, noise, image receptor homogeneity, artifacts and breast thickness compensation were detected.

Moreno-Ramirez, A.; Brandan, M. E.; Villasenor-Navarro, Y.; Galvan, H. A.; Ruiz-Trejo, C. [Instituto de Fisica, Universidad Nacional Autonoma de Mexico, DF 04510 (Mexico); Departamento de Radiodiagnostico, Instituto Nacional de Cancerologia, DF 14080 (Mexico); Instituto de Fisica, Universidad Nacional Autonoma de Mexico, DF 04510 (Mexico)

2012-10-23T23:59:59.000Z

86

Precipitation sensitivity to alloy composition in Fe-Cr-Mn austenitic steels developed for reduced activation for fusion application  

SciTech Connect (OSTI)

Special austenitic steels are being designed in which alloying elements like Mo, Nb, and Ni are replaced with Mn, W, V, Ti, and/or Ta to reduce the long-term radioactivity induced by fusion reactor irradiation. However, the new steels still need to have properties otherwise similar to commercial steels like type 316. Precipitation strongly affects strength and radiation-resistance in austenitic steels during irradiation at 400--600/degree/C, and precipitation is also usually quite sensitive to alloy composition. The initial stage of development was to define a base Fe-Cr-Mn-C composition that formed stable austenite after annealing and cold-working, and resisted recovery or excessive formation of coarse carbide and intermetallic phases during elevated temperature annealing. These studies produced a Fe-12Cr-20Mn-0.25C base alloy. The next stage was to add the minor alloying elements W, Ti, V, P, and B for more strength and radiation-resistance. One of the goals was to produce fine MC precipitation behavior similar to the Ti-modified Fe-Cr-Ni prime candidate alloy (PCA). Additions of Ti+V+P+B produced fine MC precipitation along network dislocations and recovery/recrystallization resistance in 20% cold worked material aged at 800/degree/C for 166h, whereas W, Ti, W+Ti, or Ti+P+B additions did not. Addition of W+Ti+V+P+B also produced fine MC, but caused some sigma phase formation and more recrystallization as well. 29 refs., 14 figs., 9 tabs.

Maziasz, P.J.; Klueh, R.L.

1988-01-01T23:59:59.000Z

87

An investigation of current noise measurement on hybrid Ta?N-Cr-Au thin film resistors and their relationship to film adhesion  

E-Print Network [OSTI]

after approximately 5. 0 hours of exposure to the gold etch ambient. Therefore, the decision was made to implement this controlled procedure of "de-adhesion" for the noise studies on the thin film resistor samples. 21 At first this contaminating... The results for each sample of this study are shown as a graph of noise index versus hours exposure to the gold etch ambient. The entire set of 28 graphs has been divided 0 into two process groups: one for the 200 C samples and one for the 350 C samples...

Bibeau, Wayne Edward

1978-01-01T23:59:59.000Z

88

Nonlinear effects in collision cascades and high energy shock waves during ta-C:H growth  

SciTech Connect (OSTI)

The surface topography of hydrogenated tetrahedral amorphous carbon (ta-C:H) is critical for various applications such as microelectromechanical devices, magnetic and optical storage devices, and medical implants. The surface topography of ta-C:H films deposited by distributed electron cyclotron resonance plasma from C{sub 2}H{sub 2} gas precursor was investigated. The effects of pressure, together with ion flux and energy, are studied by atomic force microscopy in relation to the structural evolution of the films. The results are compared with the predictions of the Edward-Wilkinson model [Proc. R. Soc. London, Ser. A 44, 1039 (1966)] recently proposed to account for ta-C:H growth and with previous interpretations based on hypersonic shock waves. The random hillocks observed on the smooth surfaces of ta-C:H films deposited at high pressure are thought to result from the interference of high energy shock waves triggered by C{sub 4}H{sub x}{sup +} ions that produce overlapping collision cascades and induce nonlinear effects.

Piazza, F.; Resto, O.; Morell, G. [Department of Physics, University of Puerto Rico, P.O. Box 23343, San Juan, 00931 (Puerto Rico)

2007-07-01T23:59:59.000Z

89

TA B L E O F CO N T E N T S Mechanical Engineering  

E-Print Network [OSTI]

TA B L E O F CO N T E N T S Annual Report LEADERSHIP IMPACT Innovation Mechanical Engineering to the Ann Arbor area during the summer of 2000. In this 1999­2000 Annual Report for the Department, which from what they once were. Cars are hybrid electric, powered by fuel cells and with computer

Ulsoy, A. Galip

90

CRAD, Conduct of Operations- Los Alamos National Laboratory TA 55 SST Facility  

Broader source: Energy.gov [DOE]

A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Conduct of Operations program at the Los Alamos National Laboratory, TA 55 SST Facility.

91

Better condensers and new extractors from Parvaresh-Vardy codes Amnon Ta-Shma  

E-Print Network [OSTI]

Better condensers and new extractors from Parvaresh-Vardy codes Amnon Ta-Shma Tel-Aviv University, 2011 Abstract We give a new construction of condensers based on Parvaresh-Vardy codes [PV05]. Our condensers have entropy rate (1 - ) for subconstant (in contrast to [GUV09] which required constant

Ta-Shma, Amnon

92

CRAD, Radiological Controls- Los Alamos National Laboratory TA 55 SST Facility  

Broader source: Energy.gov [DOE]

A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Radiation Protection Program at the Los Alamos National Laboratory TA 55 SST Facility.

93

ACTIVITY, MOVEMENTS, AND FEEDING BEHAVIOR OF THE CUNNER, TA UTOGOLABRUS ADSPERSUS, AND COMPARISON OF  

E-Print Network [OSTI]

ACTIVITY, MOVEMENTS, AND FEEDING BEHAVIOR OF THE CUNNER, TA UTOGOLABRUS ADSPERSUS, AND COMPARISON providing the nighttime shelter. The fish overwinter within their home territory in a torpid, nonfeeding of young tautog of similar size. 'This work was supported in part by a grant from the U.S. Atomic Energy

94

CRAD, Occupational Safety & Health- Los Alamos National Laboratory TA 55 SST Facility  

Broader source: Energy.gov [DOE]

A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Industrial Hygiene program at the Los Alamos National Laboratory TA 55 SST Facility.

95

High-pressure shock behavior of WC and Ta2O5 powders.  

SciTech Connect (OSTI)

Planar shock experiments were conducted on granular tungsten carbide (WC) and tantalum oxide (Ta{sub 2}O{sub 5}) using the Z machine and a 2-stage gas gun. Additional shock experiments were also conducted on a nearly fully dense form of Ta{sub 2}O{sub 5}. The experiments on WC yield some of the highest pressure results for granular materials obtained to date. Because of the high distention of Ta{sub 2}O{sub 5}, the pressures obtained were significantly lower, but the very high temperatures generated led to large contributions of thermal energy to the material response. These experiments demonstrate that the Z machine can be used to obtain accurate shock data on granular materials. The data on Ta{sub 2}O{sub 5} were utilized in making improvements to the P-{lambda} model for high pressures; the model is found to capture the results not only of the Z and gas gun experiments but also those from laser experiments on low density aerogels. The results are also used to illustrate an approach for generating an equation of state using only the limited data coming from nanoindentation. Although the EOS generated in this manner is rather simplistic, for this material it gives reasonably good results.

Knudson, Marcus D. (Sandia National Laboratories, Albuquerque, NM); Reinhart, William Dodd (Sandia National Laboratories, Albuquerque, NM); Vogler, Tracy John; Root, Seth (Sandia National Laboratories, Albuquerque, NM)

2011-10-01T23:59:59.000Z

96

Dig-ta Video, Learn-ng Styes, and Student Understanding of Kinematics Graphs  

E-Print Network [OSTI]

Dig-ta Video, Learn-ng Styes, and Student Understanding of Kinematics Graphs Teresa Larkin Video, Learning Styles, and Student Understanding of Kinematics Graphs Introduction Student learning interactive digital video as well preferences and student understanding and their ability to interpret motion

Zollman, Dean

97

CRAD, Emergency Management- Los Alamos National Laboratory TA 55 SST Facility  

Broader source: Energy.gov [DOE]

A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Emergency Management program at the Los Alamos National Laboratory TA 55 SST Facility.

98

Measuring the fracture toughness of ultra-thin films with application to AlTa coatings  

E-Print Network [OSTI]

1 Measuring the fracture toughness of ultra-thin films with application to AlTa coatings Yong Xiang Abstract An experimental technique is presented for measuring the fracture toughness of brittle thin films with a focused ion beam and the membranes are pressurized until rupture. The fracture stress of the membrane

99

CLOUD GAMING ONWARD: RESEARCH OPPORTUNITIES AND OUTLOOK Kuan-Ta Chen1  

E-Print Network [OSTI]

CLOUD GAMING ONWARD: RESEARCH OPPORTUNITIES AND OUTLOOK Kuan-Ta Chen1 , Chun-Ying Huang2 ABSTRACT Cloud gaming has become increasingly more popular in the academia and the industry, evident by the large numbers of related research papers and startup companies. Some pub- lic cloud gaming services have

Chen, Sheng-Wei

100

TA Orientation 2004 Activity 5 (2 points). Teaching Discussion Sessions at UMn  

E-Print Network [OSTI]

questions and comments (2) The Mentor TA will lead a class discussion about your questions. Write important & Useful Information (one per person) OR of useful information to put on board Photocopies of Answer Sheet) passing out Problem & Useful Information and Answer Sheet. · Students sitting and listening · Students

Minnesota, University of

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Bare-Handed Electronic Voting with Pre-processing , Amnon Ta-Shma2  

E-Print Network [OSTI]

Bare-Handed Electronic Voting with Pre-processing Ben Riva1 , Amnon Ta-Shma2 School of Computer Many electronic voting schemes assume the user votes with some computing device. This raises, proposed what we call bare-handed electronic voting, where voters do not need any computational power

Ta-Shma, Amnon

102

Production ratio of meta-stable isomer in {sup 180}Ta by neutrino-induced reactions  

SciTech Connect (OSTI)

The nucleosynthesis of {sup 180}Ta has remained an unsolved problem and as its origin many nucleosynthesis mechanisms have been proposed. This isotope has the unique feature that the naturally occurring abundance of {sup 180}Ta is actually a meta-stable isomer (half-life of >=10{sup 15} yr), while the ground state is a 1{sup +} unstable state which beta-decays with a half-life of only 8.15 hr. We have made a new time-dependent calculation of {sup 180}Ta meta-stable isomer residual ratio after supernova neutrino-induced reactions. This isomer residual ratio is crucial for understanding the production and survival of this naturally occurring rare isotope. We have constructed a new model under temperature evolution after type II supernova explosion. We include the explicit linking between the isomer and all known excited states and found that the residual ratio is insensitive to astrophysical parameters such as neutrino energy spectrum, explosion energy, decay time constant. We find that the explicit time evolution of the synthesis of {sup 180}Ta avoids the overproduction relative to {sup 138}La for a neutrino process neutrino temperature of 4 MeV.

Hayakawa, Takehito [Japan Atomic Energy Agency, Kizugawa, Kyoto 619-0215 (Japan); Kajino, Toshitaka [National Astronomical Observatory, Osawa, Mitaka, Tokyo 181-8588 (Japan); Chiba, Satoshi [Japan Atomic Energy Agency, Tokai, Naka, Ibaraki 319-11 (Japan); Mathews, Grant [Astrophysics, Department of Physics, University of Notre Dame, Notre Dame, IN 46556 (United States)

2010-05-12T23:59:59.000Z

103

Isomer residual ratio of odd-odd isotope {sup 180}Ta in supernova nucleosynthsis  

SciTech Connect (OSTI)

The nucleosynthesis of {sup 180}Ta has remained an unsolved problem and as its origin many nucleosynthesis mechanisms have been proposed. This isotope has the unique feature that the naturally occurring abundance of {sup 180}Ta is actually a meta-stable isomer (half-life of >=10{sup 15} yr), while the ground state is a 1{sup +} unstable state which beta-decays with a half-life of only 8.15 hr. We have made a new time-dependent calculation of {sup 180}Ta meta-stable isomer residual ratio after supernova neutrino-induced reactions. This residual isomer ratio is crucial for understanding the production and survival of this naturally occurring rare isotope. We have constructed a new model under temperature evolution after type II supernova explosion. We include the explicit linking between the isomer and all known excited states and found that the residual ratio is insensitive to astrophysical parameters such as neutrino energy spectrum, explosion energy, decay time constant. We find that the explicit time evolution of the synthesis of {sup 180}Ta avoids the overproduction relative to {sup 138}La for a neutrino process neutrino temperature of 4 MeV.

Hayakawa, Takehito [Japan Atomic Energy Agency, Kizugawa, Kyoto 619-0215 (Japan); Kajino, Toshitaka [National Astronomical Observatory, Osawa, Mitaka, Tokyo 181-8588 (Japan); Chiba, Satoshi [Japan Atomic Energy Agency, Tokai, Naka, Ibaraki 319-11 (Japan); Mathews, Grant [Enter for Astrophysics, Department of Physics, University of Notre Dame, Notre Dame, IN 46556 (United States)

2010-06-01T23:59:59.000Z

104

Product Reviews in Mobile Decision Aid Systems Rene T.A. Wietsma  

E-Print Network [OSTI]

Product Reviews in Mobile Decision Aid Systems Ren´e T.A. Wietsma and Francesco Ricci e- bile product recommender system which incorporates both structured (supplier driven) product://ectrl.itc.it ABSTRACT Recommender systems provide decision aid and information filtering functions that have a great

Ricci, Francesco

105

TA-55 Final Safety Analysis Report Comparison Document and DOE Safety Evaluation Report Requirements  

SciTech Connect (OSTI)

This document provides an overview of changes to the currently approved TA-55 Final Safety Analysis Report (FSAR) that are included in the upgraded FSAR. The DOE Safety Evaluation Report (SER) requirements that are incorporated into the upgraded FSAR are briefly discussed to provide the starting point in the FSAR with respect to the SER requirements.

Alan Bond

2001-04-01T23:59:59.000Z

106

taBLe of Contents 2 Find a Job or Internship  

E-Print Network [OSTI]

spring 2013 program of events #12;taBLe of Contents 2 Find a Job or Internship 4 All Students, 2013 Deadline to accept internship offers from previous summer internships March 15, 2013 Deadline to accept internship offers received during Spring Semester OCR Employer Info Sessions Employer Info

Hone, James

107

Applied Reactor Physics TA RG E T AU D I E N C E  

E-Print Network [OSTI]

devoted to the study of interactions between neutrons and matter in a nuclear reactor. Such an interaction be obtained using a variety of numerical techniques, as described in the book. Reactor physics is approachedApplied Reactor Physics TA RG E T AU D I E N C E Applied Reactor Physics is designed for an audi

Meunier, Michel

108

CRAD, Criticality Safety- Los Alamos National Laboratory TA 55 SST Facility  

Broader source: Energy.gov [DOE]

A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Criticality Safety program at the Los Alamos National Laboratory, TA 55 SST Facility.

109

GRAIN BOUNDARY EVOLUTION: NEW PERSPECTIVES M. EMELIANENKO, D. GOLOVATY, D. KINDERLEHRER, AND S. TA'ASAN  

E-Print Network [OSTI]

that they are robust but they are not strongly related to energetics. Recent work has provided us with a new statisticGRAIN BOUNDARY EVOLUTION: NEW PERSPECTIVES M. EMELIANENKO, D. GOLOVATY, D. KINDERLEHRER, AND S. TA boundaries. The energetics and connectivity of the net- work of boundaries are implicated in many properties

110

CRAD, Configuration Management- Los Alamos National Laboratory TA 55 SST Facility  

Broader source: Energy.gov [DOE]

A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Configuration Management program at the Los Alamos National Laboratory, TA 55 SST Facility.

111

CRAD, Quality Assurance- Los Alamos National Laboratory TA 55 SST Facility  

Broader source: Energy.gov [DOE]

A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Quality Assurance Program at the Los Alamos National Laboratory TA 55 SST Facility.

112

Risk-assessment-methodology development for waste isolation in geologic media. Technical review of documents NUREG/CR-0394, NUREG/CR-0424, NUREG/CR-0458  

SciTech Connect (OSTI)

A review of five documents that were prepared for the USNRC by Sandia Laboratories is presented in this report. The documents covered in the present review include: NUREG/CR-1262, NUREG/CR-1376, NUREG/CR-1377, NUREG/CR-1397 and NUREG/CR-1608. This constitutes the second phase of the review; the first phase was reported in Volume 1 of NUREG/CR-1672, November 1980. Two of the documents concern simplified computational methods illustrative of the calculations necessary to produce a response surface. Three of the reports pertain to statistical methods, including the application of Latin hypercube Sampling (LHS). The following observations have been made relative to the above reports: (1) the reports are, in general, difficult to read, due, in part, to unnecessarily complicated notation and lack of adequate explanation and examples, (2) the relationship of the work to similar work in the US and abroad is not discussed, and (3) limitations of the LHS method are not discussed in sufficient depth. The Sandia's response to this review is published as NUREG/CR-2428. Volume 1 is scheduled for completion in June 1982.

Stevens, C.A.; Fullwood, R.R.; Basin, S.L.

1980-11-01T23:59:59.000Z

113

Nanoclustering of hydrogen in ion-implanted and plasma-grown amorphous silicon Debye Institute, Utrecht University, P.O. Box 80000, 3508 TA Utrecht, The Netherlands  

E-Print Network [OSTI]

Institute, Utrecht University, P.O. Box 80000, 3508 TA Utrecht, The Netherlands D. L. Williamson Department. van der Weg Debye Institute, Utrecht University, P.O. Box 80000, 3508 TA Utrecht, The Netherlands A

Polman, Albert

114

Solar Energy Materials & Solar Cells 91 (2007) 17261732 Optical and structural properties of Ta2O5CeO2 thin films  

E-Print Network [OSTI]

Solar Energy Materials & Solar Cells 91 (2007) 1726­1732 Optical and structural properties of Ta2O5

Thirumalai, Devarajan

115

NUREG/CR-6911 Tests of Uranium (VI) Adsorption  

E-Print Network [OSTI]

NUREG/CR-6911 Tests of Uranium (VI) Adsorption Models in a Field Setting U.S. Geological Survey U/CR-6911 Tests of Uranium (VI) Adsorption Models in a Field Setting Manuscript Completed: August 2006 Date Published: August 2006 Prepared by G. P. Curtis, J. A. Davis Water Resources Division U.S. Geological Survey

116

The Conversion of CESR to Operate as the Test Accelerator, CesrTA, Part 1: Overview  

E-Print Network [OSTI]

Cornell's electron/positron storage ring (CESR) was modified over a series of accelerator shutdowns beginning in May 2008, which substantially improves its capability for research and development for particle accelerators. CESR's energy span from 1.8 to 5.6 GeV with both electrons and positrons makes it ideal for the study of a wide spectrum of accelerator physics issues and instrumentation related to present light sources and future lepton damping rings. Additionally a number of these are also relevant for the beam physics of proton accelerators. This paper outlines the motivation, design and conversion of CESR to a test accelerator, CesrTA, enhanced to study such subjects as low emittance tuning methods, electron cloud (EC) effects, intra-beam scattering, fast ion instabilities as well as general improvements to beam instrumentation. While the initial studies of CesrTA focussed on questions related to the International Linear Collider (ILC) damping ring design, CesrTA is a very flexible storage ring, capabl...

Billing, M G

2015-01-01T23:59:59.000Z

117

Regulation study for the facility control system design at the Facility Operations Center at TA55  

SciTech Connect (OSTI)

NMT-8 is proposing to upgrade the existing Facility Control System (FCS) located within the Facility Operations Center (FOC) at the TA-55 Plutonium Processing and Handling Facility (PPHF). The FCS modifications will upgrade the existing electronics to provide better reliability of system functions. Changes include replacement of the FCS computers and field multiplex units which are used for transmitting systems data. Data collected at the FCS include temperature, pressure, contact closures, etc., and are used for monitoring and/or control of key systems at TA-55. Monitoring is provided for the electrical power system status, PF-4 HVAC air balance status (Static Differential pressure), HVAC fan system status, site chill water return temperature, fire system information, and radioactive constant air monitors alarm information, site compressed air pressure and other key systems used at TA-55. Control output signals are provided for PF-4 HVAC systems, and selected alarms for criticality, fire, loss of pressure in confinement systems. A detailed description of the FCS modifications is provided in Section 2.

NONE

1994-03-16T23:59:59.000Z

118

Usnesen ze 4. zasedn Vdeck rady AV CR konanho dne 10. z 1. Oven a kontrola zpisu z 3. zasedn  

E-Print Network [OSTI]

reform terciárního vzdlávání. Vdecká rada AV CR bere se souhlasem na vdomí stanovisko AR AV CR k reform

Tebbens, Jurjen Duintjer

119

Structure and physical properties of EuTa{sub 2}O{sub 6} tungsten bronze polymorph  

SciTech Connect (OSTI)

A tetragonal tungsten bronze (TTB) polymorph of EuTa{sub 2}O{sub 6} was prepared and analyzed. EuTa{sub 2}O{sub 6} crystallizes in the centrosymmetric Pnam space group (with unit cell: a?=?12.3693, b?=?12.4254, and c?=?7.7228?Å) isomorphous with orthorhombic ?-SrTa{sub 2}O{sub 6}. In contrast to early reports, we see no evidence of deviation from paramagnetic Curie-Weiss behavior among the Eu{sup 2+} 4f{sup 7}spins in EuTa{sub 2}O{sub 6} down to 2?K. Dielectric constant shows a broad peak at ca. 50?K with dielectric dispersion resembling diffuse phase transition. The relaxation time, however, follows a simple (non-freezing) thermally activated process with an activation energy of 92?meV and an attempt frequency of f{sub 0}?=?5.79?×?10{sup 12?}Hz. A thermal conductivity of EuTa{sub 2}O{sub 6} shows a low-temperature (T???30?K) “plateau” region reminiscent of a glass-like behaviour in Nb-based TTB compounds. This behaviour can be attributed to the loosely bound Eu{sup 2+} ions occupying large tricapped trigonal prismatic sites in the EuTa{sub 2}O{sub 6} structure.

Kolodiazhnyi, T., E-mail: kolodiazhnyi.taras@nims.go.jp; Sakurai, H.; Vasylkiv, O.; Borodianska, H. [National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Forbes, S.; Mozharivskyj, Y. [Department of Chemistry and Chemical Biology, McMaster University, 1280 Main Street West, Hamilton, Ontario L8S4M1 (Canada)

2014-08-11T23:59:59.000Z

120

9 Cr-- 1 Mo steel material for high temperature application  

DOE Patents [OSTI]

One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 .mu.m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.

Jablonski, Paul D; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

2012-11-27T23:59:59.000Z

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

TI--CR--AL--O thin film resistors  

DOE Patents [OSTI]

Thin films of Ti--Cr--Al--O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti--Cr--Al--O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti--Cr--Al--O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti--Cr--Al--O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

Jankowski, Alan F. (Livermore, CA); Schmid, Anthony P. (Solana Beach, CA)

2000-01-01T23:59:59.000Z

122

COURSE OR OR CR. MATH 201f 3  

E-Print Network [OSTI]

P.O.Box: CR. 30 COURSE OR OR CR. MATH 201f 3 MATH 210f 3 MATH 218 MATH 219 3 STAT 233 f 3 STAT 234 f 3 STAT 235 f 3 STAT 236 f 3 STAT 237 f 3 STAT 238 f 3 ELECT .1 3 ELECT .2 3 ELECT .3 3 36 CMPS 200 : NAME: Tel #: ID #: MAY NOT ENROLL IN CVSP 203 OR 204 OR VICE VERSA. 3 ELECTIVES IN HUMANITIES OR SOCIAL

Shihadeh, Alan

123

COURSE OR OR CR. MATH 201f 3  

E-Print Network [OSTI]

P.O.Box: CR. 30 COURSE OR OR CR. MATH 201f 3 MATH 210f 3 MATH 219 3 STAT 233f 3 STAT 234f 3 STAT 235f 3 STAT 236f 3 STAT 237f 3 STAT 238f 3 ELECT. 1 3 ELECT. 2 3 ELECT. 3 3 36 CMPS 200 4 ELECT. 1 3 OR EQUIVALENTa : NAME: Tel #: ID #: E-mail: @aub.edu.lb DIPLOMA TYPE : ENTRY LEVEL: FR SO JR SR COMMENTS Total

Shihadeh, Alan

124

COURSE OR OR CR. STAT 235f 3  

E-Print Network [OSTI]

P.O.Box: CR. 30 COURSE OR OR CR. MATH 201 f 3 MATH 210 f 3 MATH 219 3 STAT 233 f 3 STAT 234 f 3 STAT 235f 3 STAT 236 f 3 STAT 237f 3 STAT 238f 3 ELECT. 1 3 ELECT. 2 3 ELECT. 3 3 36 CMPS 200 4 ELECT WHO ELECT CVSP 206 FRESHMAN CLASS OR EQUIVALENT a : NAME: Tel #: ID #: E-mail: @aub.edu.lb DIPLOMA

Shihadeh, Alan

125

COURSE or or CR. MATH 218 MATH 219 3  

E-Print Network [OSTI]

P.O.Box: CR. 30 COURSE or or CR. MATH 201 e 3 MATH 210 e 3 MATH 218 MATH 219 3 STAT 233e 3 STAT 234e 3 STAT 235e 3 STAT 236e 3 STAT 237e 3 STAT 238e 3 ELECT .1 3 ELECT .2 3 ELECT .3 3 36 ELECT. 1 3 3 credits requirement for graduation. ID #: E-mail: @aub.edu.lb DIPLOMA TYPE : ENTRY LEVEL: FR SO JR SR

Shihadeh, Alan

126

COURSE OR OR CR. MATH 201f 3  

E-Print Network [OSTI]

P.O.Box: CR. 30 COURSE OR OR CR. MATH 201f 3 MATH 210 f 3 MATH 219 3 STAT 233f 3 STAT 234 f 3 STAT 235 f 3 STAT 236 f 3 STAT 237 f 3 STAT 238 f 3 ELECT. 1 3 ELECT. 2 3 ELECT. 3 3 36 CMPS 200 4 ELECT. 1 CVSP 206 FRESHMAN CLASS OR EQUIVALENTa : NAME: Tel #: ID #: E-mail: @aub.edu.lb DIPLOMA TYPE : ENTRY

Shihadeh, Alan

127

COURSE OR OR CR. MATH 201f 3  

E-Print Network [OSTI]

P.O.Box: CR. 30 COURSE OR OR CR. MATH 201f 3 MATH 210f 3 MATH 218 MATH 219 3 STAT 233f 3 STAT 234f 3 STAT 235f 3 STAT 236f 3 STAT 237f 3 STAT 238f 3 ELECT .1 3 ELECT .2 3 ELECT .3 3 36 CMPS 200 4 REQUIRMENTS FRESHMAN CLASS OR EQUIVALENTa : NAME: Tel #: ID #: MAY NOT ENROLL IN CVSP 203 OR 204 OR VICE VERSA

Shihadeh, Alan

128

COURSE OR OR CR. MATH 201g 3  

E-Print Network [OSTI]

P.O.Box: CR. 30 COURSE OR OR CR. MATH 201g 3 MATH 210g 3 MATH 219 3 STAT 233g 3 STAT 234g 3 STAT 235g 3 STAT 236g 3 STAT 237g 3 STAT 238g 3 ELECT. 1 3 ELECT. 2 3 ELECT. 3 3 36 CMPS 200 4 ELECT. 1 3: Tel #: ID #: Total Credits in Major: E-mail: @aub.edu.lb DIPLOMA TYPE : ENTRY LEVEL: FR SO JR SR

Shihadeh, Alan

129

Atom probe: a direct technique for kinetic measurements. [Fe-24Cr; Fe-32Cr; Fe-28. 5Cr-10. 6Co  

SciTech Connect (OSTI)

The atom probe has been used to study the phase transformations occurring within the low-temperature miscibility gaps in Fe-Cr and Fe-Cr-Co alloys. The morphology of the two-phase microstructure resulting from phase separation deep within the miscibility gaps was found to be highly interconnected and charactristic of an isotropic spinodal reaction. The characteristic dimensions of the microstructure and the changes in composition were measured as a function of aging. The coarsening of the network structures could be fitted with a power law with time exponents that were significantly less than the classical Lifshitz-Slyozov-Wagner value of one-third.

Miller, M.K.; Brenner, S.S.; Camus, P.P.; Soffa, W.A.

1984-04-04T23:59:59.000Z

130

Roles of Fe2+, Fe3+, and Cr3+ Surface Sites in the Oxidation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fe3+, and Cr3+ Surface Sites in the Oxidation of NO on the (Fe,Cr)3O4(1 1 1) Surface Termination of an -(Fe,Cr Roles of Fe2+, Fe3+, and Cr3+ Surface Sites in the Oxidation of NO...

131

BACHELOR OF ARTS IN GEOLOGY (UNOFFICIAL) CATALOG 129 Fall (Th-Pr) Cr Spring (Th-Pr) Cr  

E-Print Network [OSTI]

BACHELOR OF ARTS IN GEOLOGY (UNOFFICIAL) CATALOG 129 Fall (Th-Pr) Cr Spring (Th-Pr) Cr Freshman Geology (3-3) 4 GEOL 106 Historical Geology (3-3) 4 MATH 166 Topics in Cont. Math II 1 (3-0) 3 MATH 131-3) 4 GEOP 341 Introduction to Global Geophysics (3-0) 3 GEOL 309 Introduction to Geologic Field Methods

132

Characterization of the CR-39 neutron track etch dosimeter and evaluation of a combination CR-39/thermoluminescent dosimeter badge  

E-Print Network [OSTI]

. . . . . . . Objectives . THEORY 2 5 9 12 14 Charged Particle Interactions and Damage Track Formation Neutron Converters The Etching Process Background Effects The Quality Factor MATERIALS AND METHODS 14 16 18 21 22 31 CR-39 Supply . CR-39... effectiveness and used for calculating the dose equivalent (H) of exposed personnel, do not offer the same margin of safety for all radiations, including neutrons. The result is a proposed increase in applied Q values to assure comparable safety in all...

Hoover, Paul Steven

1989-01-01T23:59:59.000Z

133

GhostDB: Hiding Data from Prying Eyes Christophe Salperwyck*  

E-Print Network [OSTI]

one direction: from public to private. This demonstration shows GhostDB's query processing in action Imagine that you have been entrusted with private data, such as corporate product information, sensitive queries whose result will combine private and public data, but private data must not be revealed, say

Paris-Sud XI, Université de

134

Anti-diabetic and hypolipidemic effects of Sargassum yezoense in db/db mice  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer Sargassum yezoense (SY) treatment improved glucose and lipid impairment in vivo. Black-Right-Pointing-Pointer This pharmacological action is associated with PPAR{alpha}/{gamma} dual activation. Black-Right-Pointing-Pointer It decreases the expression of G6Pase for gluconeogenesis in liver. Black-Right-Pointing-Pointer It increases the expression of UCP3 for lipid metabolism in adipose tissue. Black-Right-Pointing-Pointer There are no significant side effects such as body weight gain and hepatomegaly. -- Abstract: Peroxisome proliferator-activated receptors (PPARs) have been considered to be desirable targets for metabolic syndrome, even though their specific agonists have several side effects including body weight gain, edema and tissue failure. Previously, we have reported in vitro effects of Sargassum yezoense (SY) and its ingredients, sargaquinoic acid (SQA) and sargahydroquinoic acid (SHQA), on PPAR{alpha}/{gamma} dual transcriptional activation. In this study, we describe in vivo pharmacological property of SY on metabolic disorders. SY treatment significantly improved glucose and lipid impairment in db/db mice model. More importantly, there are no significant side effects such as body weight gain and hepatomegaly in SY-treated animals, indicating little side effects of SY in liver and lipid metabolism. In addition, SY led to a decrease in the expression of G6Pase for gluconeogenesis in liver responsible for lowering blood glucose level and an increase in the expression of UCP3 in adipose tissue for the reduction of total and LDL-cholesterol level. Altogether, our data suggest that SY would be a potential therapeutic agent against type 2 diabetes and related metabolic disorders by ameliorating the glucose and lipid metabolism.

Kim, Su-Nam, E-mail: snkim@kist.re.kr [Natural Medicine Center, KIST Gangneung Institute, Gangneung 210-340 (Korea, Republic of)] [Natural Medicine Center, KIST Gangneung Institute, Gangneung 210-340 (Korea, Republic of); Lee, Woojung [Natural Medicine Center, KIST Gangneung Institute, Gangneung 210-340 (Korea, Republic of)] [Natural Medicine Center, KIST Gangneung Institute, Gangneung 210-340 (Korea, Republic of); Bae, Gyu-Un [College of Pharmacy, Sookmyung Women's University, Seoul 140-742 (Korea, Republic of) [College of Pharmacy, Sookmyung Women's University, Seoul 140-742 (Korea, Republic of); Research Center for Cell Fate Control, Sookmyung Women's University, Seoul 140-742 (Korea, Republic of); Kim, Yong Kee, E-mail: yksnbk@sookmyung.ac.kr [College of Pharmacy, Sookmyung Women's University, Seoul 140-742 (Korea, Republic of)

2012-08-10T23:59:59.000Z

135

Model for projectile fragmentation: case study for Ni on Ta, Be and Xe on Al  

E-Print Network [OSTI]

For projectile fragmentation we work out details of a model whose origin can be traced back to the Bevalac era. The model positions itself between the phenomenological EPAX parametrization and microscopic transport models like "Heavy Ion Phase Space Exploration Model" (HIPSE) and antisymmetrised molecular dynamics(AMD). We apply the model to some recent data of projectile fragmentation of Ni on Ta and Be at beam energy 140 MeV/nucleon and some older data of Xe on Al at beam energy 790 MeV/nucleon. Reasonable values of cross-sections for various composites populated in the reactions are obtained.

S. Mallik; G. Chaudhuri; S. Das Gupta

2010-12-30T23:59:59.000Z

136

DOE - Office of Legacy Management -- TA-1 Manhattan Laboratory - NM 11  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou areDowntown Site - MO 02Sutton Steele andPlant -TA-1

137

Seismic Vulnerability Assessment Waste Characterization Reduction and Repackaging Building, TA-50-69  

SciTech Connect (OSTI)

This report presents the results of the seismic structural analyses completed on the Waste Characterization Reduction and Repackaging (WCRR) Building in support of ongoing safety analyses. WCRR is designated as TA-50-69 at Los Alamos National Laboratory, Los Alamos, New Mexico. The facility has been evaluated against Department of Energy (DOE) seismic criteria for Natural Phenomena Hazards (NPH) Performance Category II (PC 2). The seismic capacities of two subsystems within the WCRR building, the material handling glove box and the lift rack immediately adjacent to the Glove Box are also documented, and the results are presented.

M.W.Sullivan; J.Ruminer; I.Cuesta

2003-02-02T23:59:59.000Z

138

Effect of the magnetic phase transition on the charge transport in layered semiconductor ferromagnets TlCrS{sub 2} and TlCrSe{sub 2}  

SciTech Connect (OSTI)

TlCrS{sub 2} and TlCrSe{sub 2} crystals were synthesized by solid-state reaction. X-ray diffraction analysis showed that TlCrS{sub 2} and TlCrSe{sub 2} compounds crystallize in the hexagonal crystal system with lattice parameters a = 3.538 A, c = 21.962 A, c/a {approx} 6.207, z = 3; a = 3.6999 A, c = 22.6901 A, c/a {approx} 6.133, z = 3; and X-ray densities {rho}{sub x} = 6.705 and 6.209 g/cm{sup 3}, respectively. Magnetic and electric studies in a temperature range of 77-400 K showed that TlCrS{sub 2} and TlCrSe{sub 2} are semiconductor ferromagnets. Rather large deviations of the experimental effective magnetic moment of TlCrS{sub 2} (3.26 {mu}{sub B}) and TlCrSe{sub 2} (3.05 {mu}{sub B}) from the theoretical one (3.85 {mu}{sub B}) are attributed to two-dimensional magnetic ordering in the paramagnetic region of strongly layered ferromagnets TlCrS{sub 2} and TlCrSe{sub 2}. The effect of the magnetic phase's transition on the charge transport in TlCrS{sub 2} and TlCrSe{sub 2} is detected.

Veliyev, R. G.; Sadikhov, R. Z.; Kerimova, E. M., E-mail: ekerimova@physics.ab.az; Asadov, Yu. G.; Jabbarov, A. I. [Azerbaijan National Academy of Sciences, Institute of Physics (Azerbaijan)

2009-09-15T23:59:59.000Z

139

T-594: IBM solidDB Password Hash Authentication Bypass Vulnerability  

Broader source: Energy.gov [DOE]

This vulnerability could allow remote attackers to execute arbitrary code on vulnerable installations of IBM solidDB. Authentication is not required to exploit this vulnerability.

140

High spin states in {sup 175}Ta: An acute example of delayed crossing frequency  

SciTech Connect (OSTI)

High spin states in {sup 175}Ta are populated by the {sup 160}Gd ({sup 19}F,4{ital n}) {sup 175}Ta reaction. This experiment, carried out at the HI-13 tandem accelerator at the China Institute of Atomic Energy which measured the {gamma}-{gamma} coincidences, gives rise to a new level scheme. Two important new features are embedded in this scheme. First, the seven decay sequences built on 1/2 [541], 7/2 [404], 5/2 [402], and 9/2 [514] proton Nilsson configurations are significantly extended to higher spins. For example, for the 1/2 [541] band, the levels have extended from 33/2{sup {minus}} to 61/2{sup {minus}} and, for the 7/2 [404] band, from 21/2{sup {minus}} to 41/2{sup {minus}}. Second, compared to the neighboring even-even nuclides, the neutron {ital AB} crossing frequency built on the {ital h}{sub 9/2} proton Nilsson state 1/2 [541] is significantly larger, which according to the conventional cranking shell model (CSM) is an anomaly. In this paper, this large crossing frequency is also discussed within the framework of the projected shell model. It is shown that this anomaly found in CSM can be satisfactorily explained, thus suggesting an alternative understanding. {copyright} {ital 1996 The American Physical Society.}

Wen, S.; Zheng, H.; Li, S.; Li, G.; Yuan, G.; Hua, P.; Weng, P.; Zhang, L.; Yu, P.; Yang, C. [China Institute of Atomic Energy, P.O. Box 275, Beijing 102413, People`s Republic of (China)] [China Institute of Atomic Energy, P.O. Box 275, Beijing 102413, People`s Republic of (China); Sun, H.; Liu, Y.; Liu, Y. [Department of Physics, Jilin University, Changchun, Jilin 130023, People`s Republic of (China)] [Department of Physics, Jilin University, Changchun, Jilin 130023, People`s Republic of (China); Sun, Y.; Feng, D.H. [Department of Physics and Atmospheric Science, Drexel University, Philadelphia, Pennsylvania 19104 (United States)] [Department of Physics and Atmospheric Science, Drexel University, Philadelphia, Pennsylvania 19104 (United States)

1996-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Crystal structure determination of the oxynitride Sr{sub 2}TaO{sub 3}N  

SciTech Connect (OSTI)

The crystal structure of the strontium tantalum oxynitride Sr{sub 2}TaO{sub 3}N has been resolved by Rietveld refinement using time-of-flight neutron powder diffraction data. The structure is of the K{sub 2}NiF{sub 4} type with a partially ordered anion sublattice (tetragonal, I4/mmm, a = 4.04127(3) {angstrom}, c = 12.6073(2) {angstrom}, c/a = 3.120, Z = 2). The tantalum atoms are at the center of TaO{sub 2}(O, N){sub 4} octahedra built up from two oxygen atoms at the apexes and four (N + O) atoms statistically forming the median plane. The strontium atoms have a coordination number of nine: SrO{sub 5}(O, N){sub 4}. The profile agreement factors are R{sub p} = 0.022, R{sub wp} = 0.016, R{sub exp} = 0.012, and R{sub 1} = 0.063.

Diot, N.; Marchand, R. [Univ. de Rennes 1 (France). Lab. Verres et Ceramiques] [Univ. de Rennes 1 (France). Lab. Verres et Ceramiques; Haines, J.; Leger, J.M. [CNRS, Meudon (France). Lab. de Physicochimie des Materiaux] [CNRS, Meudon (France). Lab. de Physicochimie des Materiaux; Macaudiere, P. [Centre de Recherches d`Aubervilliers (France)] [Centre de Recherches d`Aubervilliers (France); Hull, S. [Rutherford Appleton Lab., Didcot (United Kingdom). ISIS Science Div.] [Rutherford Appleton Lab., Didcot (United Kingdom). ISIS Science Div.

1999-09-01T23:59:59.000Z

142

Crystal structure determination of the oxynitride Sr[sub 2]TaO[sub 3]N  

SciTech Connect (OSTI)

The crystal structure of the strontium tantalum oxynitride Sr[sub 2]TaO[sub 3]N has been resolved by Rietveld refinement using time-of-flight neutron powder diffraction data. The structure is of the K[sub 2]NiF[sub 4] type with a partially ordered anion sublattice (tetragonal, I4/mmm, a = 4.04127(3) [angstrom], c = 12.6073(2) [angstrom], c/a = 3.120, Z = 2). The tantalum atoms are at the center of TaO[sub 2](O, N)[sub 4] octahedra built up from two oxygen atoms at the apexes and four (N + O) atoms statistically forming the median plane. The strontium atoms have a coordination number of nine: SrO[sub 5](O, N)[sub 4]. The profile agreement factors are R[sub p] = 0.022, R[sub wp] = 0.016, R[sub exp] = 0.012, and R[sub 1] = 0.063.

Diot, N.; Marchand, R. (Univ. de Rennes 1 (France). Lab. Verres et Ceramiques); Haines, J.; Leger, J.M. (CNRS, Meudon (France). Lab. de Physicochimie des Materiaux); Macaudiere, P. (Centre de Recherches d'Aubervilliers (France)); Hull, S. (Rutherford Appleton Lab., Didcot (United Kingdom). ISIS Science Div.)

1999-09-01T23:59:59.000Z

143

Grain boundary depletion and migration during selective oxidation of Cr in a Ni-5Cr binary alloy exposed to high-temperature hydrogenated water  

SciTech Connect (OSTI)

High-resolution microscopy of a high-purity Ni-5Cr alloy exposed to 360°C hydrogenated water reveals intergranular selective oxidation of Cr accompanied by local Cr depletion and diffusion-induced grain boundary migration (DIGM). The corrosion-product oxide consists of a porous, interconnected network of Cr2O3 platelets with no further O ingress into the metal ahead. Extensive grain boundary depletion of Cr (to <0.05at.%) is observed typically 20–100 nm wide as a result of DIGM and reaching depths of many micrometers beyond the oxidation front.

Schreiber, Daniel K.; Olszta, Matthew J.; Bruemmer, Stephen M.

2014-10-15T23:59:59.000Z

144

Supernova 1996cr: SN 1987A's Wild Cousin?  

E-Print Network [OSTI]

We report on new VLT optical spectroscopic and multi-wavelength archival observations of SN1996cr, a previously identified ULX known as Circinus Galaxy X-2. Our optical spectrum confirms SN1996cr as a bona fide type IIn SN, while archival imaging isolates its explosion date to between 1995-02-28 and 1996-03-16. SN1996cr is one of the closest SNe (~3.8 Mpc) in the last several decades and in terms of flux ranks among the brightest radio and X-ray SNe ever detected. The wealth of optical, X-ray, and radio observations that exist for this source provide relatively detailed constraints on its post-explosion expansion and progenitor history, including an preliminary angular size constaint from VLBI. The archival X-ray and radio data imply that the progenitor of SN1996cr evacuated a large cavity just prior to exploding: the blast wave likely expanded for ~1-2 yrs before eventually striking the dense circumstellar material which surrounds SN1996cr. The X-ray and radio emission, which trace the progenitor mass-loss rate, have respectively risen by a factor of ~2 and remained roughly constant over the past 7 yr. This behavior is reminiscent of the late rise of SN1987A, but 1000 times more luminous and much more rapid to onset. Complex Oxygen line emission in the optical spectrum further hints at a possible concentric shell or ring-like structure. The discovery of SN1996cr suggests that a substantial fraction of the closest SNe observed in the last several decades have occurred in wind-blown bubbles. An Interplanetary Network position allows us to reject a tentative GRB association with BATSE 4B960202. [Abridged

F. E. Bauer; V. V. Dwarkadas; W. N. Brandt; S. Immler; S. Smartt; N. Bartel; M. F. Bietenholz

2008-05-06T23:59:59.000Z

145

The problem of intermixing of metals possessing no mutual solubility upon explosion welding (Cu-Ta, Fe-Ag, Al-Ta)  

SciTech Connect (OSTI)

On the basis of the results obtained for joints of dissimilar metals such as copper-tantalum and iron-silver, the reason of immiscible suspensions mixing upon explosion welding has been cleared out. It has been found that the interface (plain or wavy) is not smooth and contains inhomogeneities, namely, cusps and local melting zones. The role of granulating fragmentation providing partitioning of initial materials as a main channel of input energy dissipation has been revealed. It has been shown that in joints of metals possessing normal solubility the local melting zones are true solutions, but if metals possess no mutual solubility the local melting zones are colloidal solutions. Realization of either emulsion or suspension variant takes place. The results can be used in the development of new joints of metals possessing no mutual solubility. - Highlights: Black-Right-Pointing-Pointer Immiscible pairs Ta/Cu and Fe/Ag are welded successfully by explosive welding. Black-Right-Pointing-Pointer Fragmentation provides for partitioning as the main energy dissipation channel. Black-Right-Pointing-Pointer Immiscible metals form colloidal solid solutions during solidification. Black-Right-Pointing-Pointer Melting and boiling temperatures ratio determines the colloidal solution type. Black-Right-Pointing-Pointer Local melting zones being in suspension form enhance welds hardening.

Greenberg, B.A., E-mail: bella@imp.uran.ru [Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, S. Kovalevskoi str. 18, Ekaterinburg, 620990 (Russian Federation); Ivanov, M.A. [Kurdyumov Institute of Metal Physics, National Academy of Sciences of Ukraine, Vernadskogo blvd. 36, Kiev, 03680 (Ukraine)] [Kurdyumov Institute of Metal Physics, National Academy of Sciences of Ukraine, Vernadskogo blvd. 36, Kiev, 03680 (Ukraine); Rybin, V.V. [State Polytechnical University, Politekhnicheskaya str. 29, St. Petersburg, 195251 (Russian Federation)] [State Polytechnical University, Politekhnicheskaya str. 29, St. Petersburg, 195251 (Russian Federation); Elkina, O.A.; Antonova, O.V.; Patselov, A.M.; Inozemtsev, A.V.; Plotnikov, A.V.; Volkova, A.Yu. [Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, S. Kovalevskoi str. 18, Ekaterinburg, 620990 (Russian Federation)] [Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, S. Kovalevskoi str. 18, Ekaterinburg, 620990 (Russian Federation); Besshaposhnikov, Yu.P. [OJSC Ural Chemical Machine Building Plant, Khibinogorskii Lane 33, Ekaterinburg, 620010 (Russian Federation)] [OJSC Ural Chemical Machine Building Plant, Khibinogorskii Lane 33, Ekaterinburg, 620010 (Russian Federation)

2013-01-15T23:59:59.000Z

146

COURSE or or CR. MATH 201e 3  

E-Print Network [OSTI]

P.O.Box: CR. 30 COURSE or or CR. MATH 201e 3 MATH 210e 3 MATH 218 MATH 219 3 STAT 233e 3 STAT 234e 3 STAT 235e 3 STAT 236e 3 STAT 237e 3 STAT 238e 3 ELECT .1 3 ELECT .2 3 ELECT .3 3 36 ELECT. 1 3 3 or any 207 (A,B,C...) TOTAL CREDITS NEEDED for GRADUATION HUMANITIES LIST I OR IIc ,f ID #: E-mail: @aub

Shihadeh, Alan

147

Nitrate Enhanced Microbial Cr(VI) Reduction-Final Report  

SciTech Connect (OSTI)

A major challenge for the bioremediation of radionuclides (i.e., uranium, technetium) and metals (i.e., Cr(VI), Hg) is the co-occurrence of nitrate as it can inhibit metal transformation. Denitrification (nitrate reduction to dinitrogen gas) is considered the most important ecological process. For many metal and metalloid reducing bacteria, however, ammonia is the end product through respiratory nitrate reduction (RNRA). The focus of this work was to determine how RNRA impacts Cr(VI) transformation. The goal was to elucidate the specific mechanism(s) that limits Cr(VI) reduction in the presence of nitrate and to use this information to develop strategies that enhance Cr(VI) reduction (and thus detoxification). Our central hypothesis is that nitrate impacts the biotransformation of metals and metalloids in three ways 1) as a competitive alternative electron acceptor (inhibiting transformation), 2) as a co-metabolite (i.e., concomitant reduction, stimulating transformation), and 3) as an inducer of specific proteins and pathways involved in oxidation/reduction reactions (stimulating transformation). We have identified three model organisms, Geobacter metallireducens (mechanism 1), Sulfurospirillum barnesii, (mechasism 2), and Desulfovibrio desulfuricans (mechanisms 3). Our specific aims were to 1) investigate the role of Cr(VI) concentration on the kinetics of both growth and reduction of nitrate, nitrite, and Cr(VI) in these three organisms; 2) develop a profile of bacterial enzymes involved in nitrate transformation (e.g., oxidoreductases) using a proteomic approach; 3) investigate the function of periplasmic nitrite reductase (Nrf) as a chromate reductase; and 4) develop a strategy to maximize microbial chromium reduction in the presence of nitrate. We found that growth on nitrate by G. metallireducens was inhibited by Cr(VI). Over 240 proteins were identified by LC/MS-MS. Redox active proteins, outer membrane heavy metal efflux proteins, and chemotaxis sensory proteins (Gmet_2478 and Gmet_1641) were up-regulated with exposure to Cr(VI). A nine-heme cytochrome C was purified that could reduce nitrite and could be oxidized by Cr(VI). For D. desulfuricans, we found that confirmed that Cr(VI) induced a prolonged lag period when Cr(VI) was reduced. Over three hundred proteins were unequivocally identified by LC/MS-MS and a significant number of down-regulated proteins for which the levels were changed >2 fold compared to control. Sulfite reductase levels were similar, however, nitrate and nitrite reductase were down-regulated. The supernatant of spent cultures was found to contain a filterable, heat stable compound that rapidly reduced Cr(VI). In addition, desulfoviridin was purified from nitrate grown cells and shown to have nitrite reductase activity that was inhibited by Cr(VI). For S. barnesii, periplasmic nitrate reductase (Nap), nitrite reductase (Nrf), and the metalloid reductase (Rar) were purified and characterized. The supernatant of spent cultures was also found to contain a filterable, heat stable compound that rapidly reduced Cr(VI) but that Rar also reduced Cr(VI). Our results from specific aims 1 through 3 indicate that for G. metallireducens, Cr(VI) inhibits nitrate respiration as it oxidizes cytochromes involved in nitrate respiration. Iron reduction is apparently not affected and the inhibitory affects of Cr(VI) may be attenuated by the addition of sufficient Fe(III) to generate Fe(II) that abiotically reduces the chromium. For S. barnesii, although the enzyme assays indicate that the components of the respiratory pathway for nitrate (e.g. Nap and Nrf) are inhibited by chromate, the organism has a mechanism to prevent this from actually occurring. Our current hypothesis is that the non-specific metalloid reductase (Rar) is providing resistance by reducing the Cr(VI). The strategy here would be to enhance its growth and metabolism in the natural setting. Lactate is a suitable electron donor for S. barnesii but other donors are possible. Although the version of the Phylochip used for monitoring the microb

John F. Stolz

2011-06-15T23:59:59.000Z

148

Selective etching of TiN over TaN and vice versa in chlorine-containing Hyungjoo Shin,a)  

E-Print Network [OSTI]

Selective etching of TiN over TaN and vice versa in chlorine-containing plasmas Hyungjoo Shin 1 April 2013; published 18 April 2013) Selectivity of etching between physical vapor-deposited TiN selectivity of etching TiN over TaN by adding small amounts (

Economou, Demetre J.

149

13.21 Geochemistry of the Rare-Earth Element, Nb, Ta, Hf, and Zr Deposits RL Linnen, University of Western Ontario, London, ON, Canada  

E-Print Network [OSTI]

13.21 Geochemistry of the Rare-Earth Element, Nb, Ta, Hf, and Zr Deposits RL Linnen, University to Y, the rare- earth elements (REE, La to Lu), Zr, Hf, Nb, and Ta. The rare elements, Canada ã 2014 Elsevier Ltd. All rights reserved. 13.21.1 Introduction 543 13.21.1.1 Uses of Rare Elements

Chakhmouradian, Anton

150

Structural relaxation around substitutional Cr3+ in pyrope garnet  

E-Print Network [OSTI]

the spinel- garnet transformation -a major phase boundary in the Earth's upper mantle- to pressures as high shells of neighbors (Mg and Si) relax only partially. Site relaxation is accommodated by strain diamonds (Irifune et al. 1982). In the garnet structure (Novak and Gibbs 1971), Cr3+ is small enough

151

Aquatic Chemistry Course Id: CHEM 605 (3 cr.)  

E-Print Network [OSTI]

Aquatic Chemistry Fall 2010 Course Id: CHEM 605 (3 cr.) Lecture: TR 3:40-5:20pm, REIC 165 of this course is to introduce students to the concepts and models used in aquatic chemistry while providing-base chemistry, complexation, precipitation-dissolution and reduction-oxidation reactions. Student Learning

Wagner, Diane

152

March 23, 2008 Databases: Practical DB Design 1 Practical Database Design  

E-Print Network [OSTI]

approach towards development of information system, called, Information System Development Life Cycle. #12 of Information Systems in Organizations + Why Organizations Use DB Systems + Information System Life Cycle System Life Cycle ... Database DBMS Users Users #12;March 23, 2008 Databases: Practical DB Design 8

Adam, Salah

153

CryptDB: A Practical Encrypted Relational DBMS Raluca Ada Popa, Nickolai Zeldovich, and Hari Balakrishnan  

E-Print Network [OSTI]

CryptDB: A Practical Encrypted Relational DBMS Raluca Ada Popa, Nickolai Zeldovich, and Hari Balakrishnan {raluca, nickolai, hari}@csail.mit.edu ABSTRACT CryptDB is a DBMS that provides provable. When individual users or enterprises store their sensitive data in a DBMS today, they must trust

Sabatini, David M.

154

Chapter 5: The Single Nucleotide Polymorphism Database (dbSNP) of Nucleotide Sequence Variation  

E-Print Network [OSTI]

Chapter 5: The Single Nucleotide Polymorphism Database (dbSNP) of Nucleotide Sequence Variation, and performance of functional studies. The Single Nucleotide Polymorphism database (dbSNP) is a public single-base nucleotide substitutions (also known as single nucleotide polymorphisms or SNPs), small

Levin, Judith G.

155

ABSORPTION-DELAY MODELS OF HEAT TRANSPORT R.E. SHOWALTER AND D.B. VISARRAGA  

E-Print Network [OSTI]

ABSORPTION-DELAY MODELS OF HEAT TRANSPORT R.E. SHOWALTER AND D.B. VISARRAGA Abstract. A temperature jump in the water traveling through a pipe is delayed by the absorption of heat into the pipe wall transfer, absorption, memory, kinetic models, approximation. 1 #12;2 R.E. SHOWALTER AND D.B. VISARRAGA 1

156

Performance Evaluation of a MongoDB and Hadoop Platform for Scientific Data Analysis  

E-Print Network [OSTI]

Project are using MongoDB, a document oriented NoSQL store. However, there is a limited understanding- laborators are added onto the project over time. MongoDB provides an appropriate data model and query language for this application. However, the project also needs to perform complex statistical data mining

157

Complete genome sequence of Tolumonas auensis type strain (TA 4T)  

SciTech Connect (OSTI)

Tolumonas auensis (Fischer-Romero et al. 1996) is currently the only validly named species of the genus Tolumonas in the family Aeromonadaceae. The strain is of interest because of its ability to produce toluene from phenylalanine and other phenyl precursors, as well as phenol from tyrosine. This is of interest because toluene is normally considered to be a tracer of anthropogenic pollution in lakes, but T. auensis represents a biogenic source of toluene. Other than Aeromonas hydrophila subsp. hydrophila, T. auensis strain TA 4T is the only other member in the family Aeromonadaceae with a completely sequenced type-strain genome. The 3,471,292-bp chromosome with a total of 3,288 protein-coding and 116 RNA genes was sequenced as part of the DOE Joint Genome Institute Program JBEI 2008.

Chertkov, Olga; Copeland, Alex; Lucas1, Susa; Lapidus, Alla; Berry, KerrieW.; Detter, JohnC.; Glavina Del Rio, Tijana; Hammon, Nancy; Dalin, Eileen; Tice, Hope; Pitluck, Sam; Richardson, Paul; Bruce, David; Goodwin, Lynne; Han, Cliff; Tapia, Roxanne; Saunders, Elizabeth; Schmutz, Jeremy; Brettin, Thomas; Larimer, Frank; Land, Miriam; Hauser, Loren; Spring, Stefan; Rohde, Manfred; Kyrpides, NikosC.; Ivanova, Natalia; Göker, Markus; Beller, HarryR.; Klenk, Hans-Peter; Woyke, Tanja

2011-10-04T23:59:59.000Z

158

Preparation and characterisation of isotopically enriched Ta$_2$O$_5$ targets for nuclear astrophysics studies  

E-Print Network [OSTI]

The direct measurement of reaction cross sections at astrophysical energies often requires the use of solid targets of known thickness, isotopic composition, and stoichiometry that are able to withstand high beam currents for extended periods of time. Here, we report on the production and characterisation of isotopically enriched Ta$_2$O$_5$ targets for the study of proton-induced reactions at the Laboratory for Underground Nuclear Astrophysics facility of the Laboratori Nazionali del Gran Sasso. The targets were prepared by anodisation of tantalum backings in enriched water (up to 66% in $^{17}$O and up to 96% in $^{18}$O). Special care was devoted to minimising the presence of any contaminants that could induce unwanted background reactions with the beam in the energy region of astrophysical interest. Results from target characterisation measurements are reported, and the conclusions for proton capture measurements with these targets are drawn.

A. Caciolli; D. A. Scott; A. Di Leva; A. Formicola; M. Aliotta; M. Anders; A. Bellini; D. Bemmerer; C. Broggini; M. Campeggio; P. Corvisiero; R. Depalo; Z. Elekes; Zs. Fülöp; G. Gervino; A. Guglielmetti; C. Gustavino; Gy. Gyürky; G. Imbriani; M. Junker; M. Marta; R. Menegazzo; E. Napolitani; P. Prati; V. Rigato; V. Roca; C. Rolfs; C. Rossi Alvarez; E. Somorjai; C. Salvo; O. Straniero; F. Strieder; T. Szücs; F. Terrasi; H. P. Trautvetter; D. Trezzi

2012-10-01T23:59:59.000Z

159

Equation-of-State Measurements in Ta2O5 Aerogel  

SciTech Connect (OSTI)

Highly porous samples of tantalum pentoxide (Ta2O5) aerogel were compressed from initial densities of 0.1, 0.15, and 0.25 g/cm^3 by shock waves with strengths between 0.3 and 3 Mbar. The compressed material was between 5 and 15 times as dense as the unshocked aerogels with temperatures ~5 eV (~58,000 K). These strong shock loadings were produced by the OMEGA Laser System at the Laboratory of Laser Energetics. The shocked states were diagnosed with the OMEGA velocity interferometer system for any reflector. When the compression measurements are compared to an available high-energy-density equation-of-state model, it is found that the model underestimates the level of compression achieved by shock loading below a Mbar.

Miller, J.E.; Boehly, T.R.; Meyerhofer, D.D.; Eggert, J.H.

2008-01-14T23:59:59.000Z

160

Thermal stability and oxidation resistance of TiCrAlYO coatings...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

stability and oxidation resistance of TiCrAlYO coatings on SS430 for solid oxide fuel cell interconnect applications. Thermal stability and oxidation resistance of TiCrAlYO...

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Reduction of Health Risks Due to Chromium(VI)Using Mesquite: A Potential Cr Phytoremediator  

SciTech Connect (OSTI)

Chromium is a transition metal extensively used in industry. Cr mining and industrial operations account for chromium wastes at Superfund sites in the United States. A study was performed to investigate the possibility of using mesquite (Prosopis spp.), which is an indigenous desert plant species, to remove Cr from contaminated sites. In this study, mesquite plants were grown in an agar-based medium containing 75 mg L-1 and 125 mg L-1 of Cr(VI). The Cr content of leaf tissue (992 mg kg-1 of dry weight, from 125 mg L-1 of Cr(VI)) indicated that mesquite could be classified as a chromium hyperaccumulator. X-ray absorption spectroscopy (XAS) studies performed to experimental samples showed that mesquite roots absorbed some of the supplied Cr(VI). However, the data analyses of plant tissues demonstrated that the absorbed Cr(VI) was fully reduced to Cr(III) in the leaf tissue.

Gardea-Torresdey, Jorge L.; Aldrich, Mary V.; Peralta-Videa, Jose R.; Parsons, Jason G.

2004-03-29T23:59:59.000Z

162

Surface structure of ?-Cr2O3(0001) after activated oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Surface structure of ?-Cr2O3(0001) after activated oxygen exposure. Surface structure of ?-Cr2O3(0001) after activated oxygen exposure. Abstract: The surface structure...

163

Growth of Cr-doped TiO Films in the Rutile and Anatase Structures...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Cr-doped TiO Films in the Rutile and Anatase Structures by Oxygen Plasma Assisted Molecular Beam Epitaxy . Growth of Cr-doped TiO Films in the Rutile and Anatase Structures by...

164

Excited Carrier Dynamics of ?-Cr2O3/?-Fe2O3 Core...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Excited Carrier Dynamics of ?-Cr2O3?-Fe2O3 Core-Shell Nanostructures. Abstract: In this work ?-Cr2O3?-Fe2O3 core-shell polycrystalline...

165

Integrated Ecogenomics Study for Bioremediation of Cr(VI) at Hanford 100H Area  

E-Print Network [OSTI]

reducer isolated from the Hanford 100H site capable of Iron(study for bioremediation of Cr(VI) at Hanford 100H area RomyVI)contamination at Hanford ?? Cr(VI) highly soluble, toxic

Chakraborty, Romy

2008-01-01T23:59:59.000Z

166

Radionuclide contaminant analysis of small mammals at Area G, TA-54, 1994  

SciTech Connect (OSTI)

Small mammals were sampled at two waste burial sites (1 and 2) at Area G, TA-54 and a control site outside Area G (Site 3) to identify radionuclides that are present within surface and subsurface soils at waste burial sites, to compare the amount of radionuclide uptake by small mammals at waste burial sites to a control site, and to identify the primary mode of contamination to small mammals, either through surface contact or ingestion/inhalation. Three composite samples of at least five animals per sample were collected at each site. Pelts and carcasses of each animal were separated and analyzed independently. Samples were analyzed for {sup 241}Am, {sup 90}Sr, {sup 238}Pu, {sup 239}Pu, total U, and gamma spectroscopy (including {sup 137}Cs). Significantly higher (parametric t-test at p = 0.05) levels of total U, {sup 241}Am, {sup 238}Pu, {sup 239}Pu, and {sup 40}K were detected in pelts as compared to the carcasses of small mammals at TA-54. Concentrations of other measured radionuclides in carcasses were nearly equal to or exceeded the mean concentrations in the pelts. The authors results show higher concentrations in pelts compared to carcasses which is similar to what has been found at waste burial/contaminated sites outside of Los Alamos National Laboratory. Site 1 had significantly higher (alpha = 0.05, F = 0.0095) total U concentrations in carcasses than Sites 2 and 3. Site 2 had significantly higher (alpha = 0.05, F = 0.0195) {sup 239}Pu concentrations in carcasses than either Site 1 or Site 3. A significant difference in {sup 90}Sr concentration existed between Sites 1 and 2 (alpha = 0.05, F = 0.0681) and concentrations of {sup 40}K at Site 1 were significantly different from Site 3.

Biggs, J.; Bennett, K.; Fresquez, P.

1995-09-01T23:59:59.000Z

167

Does Online Mobile Gaming Overcharge You for De-Yu Chen, Po-Ching Lin, and Kuan-Ta Chen  

E-Print Network [OSTI]

Does Online Mobile Gaming Overcharge You for The Fun? De-Yu Chen, Po-Ching Lin, and Kuan-Ta Chen, National Chung Cheng University Abstract--With the growing popularity of online mobile games, the network traffic generated by them accounts for an increas- ingly significant proportion of mobile Internet traffic

Chen, Sheng-Wei

168

Application of cluster-plus-glue-atom model to barrierless Cu–Ni–Ti and Cu–Ni–Ta films  

SciTech Connect (OSTI)

To improve the thermal stability of copper and avoid its diffusion into surrounding dielectrics or interfacial reactions with them, the authors applied the cluster-plus-glue-atom model to investigate barrierless Cu–Ni–M (M?=?Ti or Ta) seed layers. The dissolution of the third element (Ti or Ta) in the Cu lattice with the aid of Ni significantly improved the thermal stability of the Cu seed layer. The appropriate M/Ni (M?=?Ti or Ta) ratio was selected to obtain a low resistivity: the resistivity was as low as 2.5??? cm for the (Ti{sub 1.5/13.5}Ni{sub 12/13.5}){sub 0.3}Cu{sub 99.7} film and 2.8??? cm for the (Ta{sub 1.1/13.1}Ni{sub 12/13.1}){sub 0.4}Cu{sub 99.6} film after annealing at 500?°C for 1?h. After annealing at 500?°C for 40?h, the two films remained stable without forming a Cu{sub 3}Si compound. The authors confirmed that the range of applications of the cluster-plus-glue-atom model could be extended. Therefore, a third element M with negative enthalpies of mixing with both Cu and Ni could be selected, under the premise that the mixing enthalpy of M–Ni is more negative than that of M–Cu.

Li, Xiaona, E-mail: lixiaona@dlut.edu.cn; Ding, Jianxin; Wang, Miao; Dong, Chuang [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Dalian University of Technology), Ministry of Education, Dalian 116024 (China); Chu, Jinn P. [Department of Materials Science and Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan (China)

2014-11-01T23:59:59.000Z

169

Two Particle Azimuthal Correlations in C+Ta Collisions at 4.2A GeV  

SciTech Connect (OSTI)

In this report we present study of two particle azimuthal correlations for protons and negative pions in 4.2A GeV C+Ta collisions. Obtained results are compared with the analysis of azimuthal distribution of particles with respect to the reaction plane.

Simic, Lj. [Institute of Physics, Belgrade (Serbia and Montenegro); Jotanovic, O. [Faculty of natural science, Banja Luka (Bosnia and Herzegowina)

2007-04-23T23:59:59.000Z

170

Origin of internal field and visualization of 180 domains in congruent LiTaO3 crystals  

E-Print Network [OSTI]

. Infrared absorption studies suggest that domain inversion as well as the heating of LiTaO3 crystal induce observed a strong correlation between the internal fields and the infrared absorption spectra of OH ions of the infrared absorption bands of OH ions at 3462, 3476, and 3490 cm 1 change, and c the 180° domain walls

Gopalan, Venkatraman

171

The newesT addiTion To The UniversiTy of MinnesoTa's BioMedical  

E-Print Network [OSTI]

The newesT addiTion To The UniversiTy of MinnesoTa's BioMedical discovery disTricT is designed The BUilding's collegial and physical relaTionship To neighBoring faciliTies in The U's BioMedical discovery in the U's Biomedical Discovery District. "The brick, precast concrete, and curtain wall vocabulary

Weiblen, George D

172

A study on in situ growth of TaC whiskers in Al{sub 2}O{sub 3} matrix powder for ceramic cutting tools  

SciTech Connect (OSTI)

Graphical abstract: In situ growth of TaC whiskers (TaC{sub w}) was synthesized in an ?-Al{sub 2}O{sub 3} matrix powder via a carbothermal reduction technique. The whiskers were 0.2–0.5 ?m in diameter and 5–15 ?m in length; they were straight and had smooth surfaces. Highlights: ? In situ growth of TaC whiskers was synthesized in an ?-Al{sub 2}O{sub 3} matrix powder. ? The wet mixing method and 1450 °C were suitable for whiskers growth. ? The growth of TaC whiskers is not influenced by the Al{sub 2}O{sub 3} powder. ? The major impurities were TaC particles, nickel and unreacted carbon. -- Abstract: In situ growth of tantalum carbide (TaC) whiskers was synthesized in an ?-Al{sub 2}O{sub 3} matrix powder via a carbothermal reduction technique within a temperature range of 1350–1500 °C in an argon atmosphere. The starting materials consisted of Ta{sub 2}O{sub 5}, C, Ni and NaCl powders. Different mixing methods and various reaction temperatures were employed. Most of the prepared whiskers were 0.2–0.5 ?m in diameter and 5–15 ?m in length. The reaction temperature of 1400–1450 °C was suitable for the growth of TaC whiskers and a wet mixing method was beneficial to increase the whisker yield. Some of the whiskers exhibited the needle shape while others exhibited the screw shape. The growth mechanism of the whiskers was a complex mechanism involving a helical screw dislocation mechanism and a vapor–liquid–solid process. No obvious influences of the Al{sub 2}O{sub 3} matrix powder on the growth of TaC whiskers were found and the major impurities in the obtained powder were TaC particles, nickel and unreacted carbon.

Zhao, Guolong [Centre for Advanced Jet Engineering Technologies (CaJET), School of Mechanical Engineering, Shandong University, Jinan 250061 (China) [Centre for Advanced Jet Engineering Technologies (CaJET), School of Mechanical Engineering, Shandong University, Jinan 250061 (China); Key Laboratory of High-efficiency and Clean Mechanical Manufacture (Shandong University), Ministry of Education (China); Huang, Chuanzhen, E-mail: chuanzhenh@sdu.edu.cn [Centre for Advanced Jet Engineering Technologies (CaJET), School of Mechanical Engineering, Shandong University, Jinan 250061 (China) [Centre for Advanced Jet Engineering Technologies (CaJET), School of Mechanical Engineering, Shandong University, Jinan 250061 (China); Key Laboratory of High-efficiency and Clean Mechanical Manufacture (Shandong University), Ministry of Education (China); Liu, Hanlian; Xu, Liang; Chong, Xuewen; Zou, Bin; Zhu, Hongtao [Centre for Advanced Jet Engineering Technologies (CaJET), School of Mechanical Engineering, Shandong University, Jinan 250061 (China) [Centre for Advanced Jet Engineering Technologies (CaJET), School of Mechanical Engineering, Shandong University, Jinan 250061 (China); Key Laboratory of High-efficiency and Clean Mechanical Manufacture (Shandong University), Ministry of Education (China)

2012-08-15T23:59:59.000Z

173

Lightest Isotope of Bh Produced Via the 209Bi(52Cr,n)260Bh Reaction  

E-Print Network [OSTI]

models. For many years, “cold fusion” reactions utilizingproduced via the new “cold fusion” reaction 209 Bi( 52 Cr,

2007-01-01T23:59:59.000Z

174

Radiation effects on interface reactions of U/Fe, U/(Fe + Cr), and U/(Fe + Cr + Ni)  

SciTech Connect (OSTI)

We study the effects of radiation damage on interdiffusion and intermetallic phase formation at the interfaces of U/Fe, U/(Fe + Cr), and U/(Fe + Cr + Ni) diffusion couples. Magnetron sputtering is used to deposit thin films of Fe, Fe + Cr, or Fe + Cr + Ni on U substrates to form the diffusion couples. One set of samples are thermally annealed under high vacuum at 450 C or 550 C for one hour. A second set of samples are annealed identically but with concurrent 3.5 MeV Fe++ ion irradiation. The Fe++ ion penetration depth is sufficient to reach the original interfaces. Rutherford backscattering spectrometry analysis with high fidelity spectral simulations is used to obtain interdiffusion profiles, which are used to examine differences in U diffusion and intermetallic phase formation at the buried interfaces. For all three diffusion systems, Fe++ ion irradiations enhance U diffusion. Furthermore, the irradiations accelerate the formation of intermetallic phases. In U/Fe couples, for example, the unirradiated samples show typical interdiffusion governed by Fick’s laws, while the irradiated ones show step-like profiles influenced by Gibbs phase rules.

KUn Shao; Di Chen; Chaochen Wei; Michael S. Martin; Xuemei Wang; Youngjoo Park; Ed Dein; Kevin R. Coffey; b , Yongho Sohn; Bulent H. Sencer; J. Rory Kennedy

2014-09-01T23:59:59.000Z

175

Non-classical nuclei and growth kinetics of Cr precipitates in FeCr alloys during ageing  

SciTech Connect (OSTI)

In this manuscript, we quantitatively calculated the thermodynamic properties of critical nuclei of Cr precipitates in FeCr alloys. The concentration profiles of the critical nuclei and nucleation energy barriers were predicted by the constrained shrinking dimer dynamics (CSDD) method. It is found that Cr concentration distribution in the critical nuclei strongly depend on the overall Cr concentration as well as temperature. The critical nuclei are non-classical because the concentration in the nuclei is smaller than the thermodynamic equilibrium value. These results are in agreement with atomic probe observation. The growth kinetics of both classical and non-classical nuclei was investigated by the phase field approach. The simulations of critical nucleus evolution showed a number of interesting phenomena: 1) a critical classical nucleus first shrinks toward its non-classical nucleus and then grows; 2) a non-classical nucleus has much slower growth kinetics at its earlier growth stage compared to the diffusion-controlled growth kinetics. 3) a critical classical nucleus grows faster at the earlier growth stage than the non-classical nucleus. All of these results demonstrate that it is critical to introduce the correct critical nuclei in order to correctly capture the kinetics of precipitation.

Li, Yulan; Hu, Shenyang Y.; Zhang, Lei; Sun, Xin

2014-01-10T23:59:59.000Z

176

austenitnoj cr-mn stali: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

cr-mn stali First Page Previous Page 1 2 3 4 5 6 Next Page Last Page Topic Index 1 Cavitation erosion of laser processed Fe-Cr-Mn and Fe-Cr-Co alloys CiteSeer Summary: Received...

177

High coercivity CoCrPt films achieved by post-deposition rapid thermal annealing  

E-Print Network [OSTI]

layer, a CoCrPt mag- netic layer, a capping Mn diffusion layer, and a final CrTi oxidation protection conditions were stud- ied. II. EXPERIMENT All layers were deposited onto glass substrates by rf di- ode, and CrTi oxida- tion protection layer were all 200 Ã? thick. Post-deposition annealing was performed

Laughlin, David E.

178

Surface half-metallicity of CrS thin films and perfect spin filtering and spin diode effects of CrS/ZnSe heterostructure  

SciTech Connect (OSTI)

Recently, ferromagnetic zinc-blende Mn{sub 1?x}Cr{sub x}S thin films (above x?=?0.5) were fabricated experimentally on ZnSe substrate, which confirmed the previous theoretical prediction of half-metallic ferromagnetism in zinc-blende CrS. Here, we theoretically reveal that both Cr- and S-terminated (001) surfaces of the CrS thin films retain the half-metallicity. The CrS/ZnSe(001) heterogeneous junction exhibits excellent spin filtering and spin diode effects, which are explained by the calculated band structure and transmission spectra. The perfect spin transport properties indicate the potential applications of half-metallic CrS in spintronic devices. All computational results are obtained by using the density functional theory combined with nonequilibrium Green's function.

Gao, G. Y., E-mail: guoying-gao@mail.hust.edu.cn; Yao, K. L., E-mail: klyao@mail.hust.edu.cn [School of Physics and Wuhan National High Magnetic Field Center, Huazhong University of Science and Technology, Wuhan 430074 (China)

2014-11-03T23:59:59.000Z

179

Grain boundary migration induced segregation in V-Cr-Ti alloys  

SciTech Connect (OSTI)

Analytical electron microscopy results are reported for a series of vanadium alloys irradiated in the HFIR JP23 experiment at 500{degrees}C. Alloys were V-5Cr-5Ti and pure vanadium which are expected to have transmuted to V-15Cr-5Ti and V-10Cr following irradiation. Analytical microscopy confirmed the expected transmutation occurred and showed redistribution of Cr and Ti resulting from grain boundary migration in V-5Cr-5Ti, but in pure V, segregation was reduced and no clear trends as a function of position near a boundary were identified.

Gelles, D.S. [Pacific Northwest National Lab., Richland, WA (United States); Ohnuki, S.; Takahashi, H. [Univ. of Hokkaido (Japan)

1996-10-01T23:59:59.000Z

180

Partially filled intermediate band of Cr-doped GaN films  

SciTech Connect (OSTI)

We investigated the band structure of sputtered Cr-doped GaN (GaCrN) films using optical absorption, photoelectron yield spectroscopy, and charge transport measurements. It was found that an additional energy band is formed in the intrinsic band gap of GaN upon Cr doping, and that charge carriers in the material move in the inserted band. Prototype solar cells showed enhanced short circuit current and open circuit voltage in the n-GaN/GaCrN/p-GaN structure compared to the GaCrN/p-GaN structure, which validates the proposed concept of an intermediate-band solar cell.

Sonoda, S. [Department of Electronics, Kyoto Institute of Technology, Kyoto 606-8585 (Japan)

2012-05-14T23:59:59.000Z

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Cr{sub 2}Nb-based alloy development  

SciTech Connect (OSTI)

This paper summarizes recent progress in developing Cr{sub 2}Nb/Cr(Nb) alloys for structural use in advanced fossil energy conversion systems. Alloy additions were added to control the microstructure and mechanical properties. Two beneficial elements have been identified among all alloying additions added to the alloys. One element is effective in refining the coarse eutectic structure and thus substantially improves the compressive strength and ductility of the alloys. The other element enhances oxidation resistance without sacrificing the ductility. The tensile properties are sensitive to cast defects, which can not be effectively reduced by HIPping at 1450-1580{degrees}C and/or directionally solidifying via a floating zone remelting method.

Liu, C.T.; Horton, J.A.; Carmichael, C.A.

1996-05-01T23:59:59.000Z

182

Gestion d'un cache Loris Marchal CR08 ordonnancement  

E-Print Network [OSTI]

Gestion d'un cache Loris Marchal ­ CR08 ordonnancement 30 novembre 2011 1 Introduction On s'int´eresse au probl`eme de la gestion d'une m´emoire temporaire, couramment ap- pel´ee cache. Plut^ot qu´etitivit´e On consid`ere le cas offline, c'est-`a-dire qu'on conna^it `a l'avance toute la s´equence des requ

Marchal, Loris

183

Gestion d'un cache Loris Marchal CR07 ordonnancement  

E-Print Network [OSTI]

Gestion d'un cache Loris Marchal ­ CR07 ordonnancement 17 d´ecembre 2012 1 Introduction On s'int´eresse au probl`eme de la gestion d'une m´emoire temporaire, couramment ap- pel´ee cache. Plut^ot qu´etitivit´e On consid`ere le cas offline, c'est-`a-dire qu'on conna^it `a l'avance toute la s´equence des requ

Marchal, Loris

184

Improving thermostability of CrO{sub 2} thin films by doping with Sn  

SciTech Connect (OSTI)

Chromium dioxide (CrO{sub 2}) is an ideal material for spin electronic devices since it has almost 100% spin polarization near Fermi level. However, it is thermally unstable and easily decomposes to Cr{sub 2}O{sub 3} even at room temperature. In this study, we try to improve the thermal stability of CrO{sub 2} thin films by doping with Sn whose oxide has the same structure as CrO{sub 2}. High quality epitaxial CrO{sub 2} and Sn-doped CrO{sub 2} films were grown on single crystalline TiO{sub 2} (100) substrates by chemical vapor deposition. Sn{sup 4+} ions were believed to be doped into CrO{sub 2} lattice and take the lattice positions of Cr{sup 4+}. The magnetic measurements show that Sn-doping leads to a decrease of magnetocrystalline anisotropy. The thermal stabilities of the films were evaluated by annealing the films at different temperatures. Sn-doped films can withstand a temperature up to 510?°C, significantly higher than what undoped films can do (lower than 435?°C), which suggests that Sn-doping indeed enhances the thermal stability of CrO{sub 2} films. Our study also indicates that Sn-doping may not change the essential half metallic properties of CrO{sub 2}. Therefore, Sn-doped CrO{sub 2} is expected to be very promising for applications in spintronic devices.

Ding, Yi; Wang, Ziyu; Liu, Shuo; Shi, Jing; Yin, Di, E-mail: dyin@whu.edu.cn [Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education, School of Physics and Technology, Wuhan University, Wuhan 430072 (China); Yuan, Cheng; Lu, Zhihong, E-mail: zludavid@live.com [School of Materials and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081 (China); Xiong, Rui, E-mail: xiongrui@whu.edu.cn [Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education, School of Physics and Technology, Wuhan University, Wuhan 430072 (China); Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Wuhan 430062 (China)

2014-09-01T23:59:59.000Z

185

Long-term corrosion of Cr-Mo steels in superheated steam at 482 and 538/sup 0/C. [21/4 Cr-1 Mo; 9 Cr-1 Mo; Sumitomo 9 Cr-2 Mo; Sandvik HT-9  

SciTech Connect (OSTI)

The corrosion of several Cr-Mo ferritic steels was investigated in superheated steam at an operating power plant. Tests were conducted at 482 and 538/sup 0/C (900 and 1000/sup 0/F) in a once-through loop for times up to 28,000 h. Chromium concentrations ranged from 2.0 to 11.3%, and the effect of surface preparation on corrosion was investigated. Only one of many specimens showed evidence of exfoliation at 482/sup 0/C, but at 538/sup 0/C exfoliation occurred on at least some of the specimens of most materials; the exceptions were the alloy with the highest chromium content (Sandvik HT-9), one heat of 9 Cr-1 Mo steel with the highest silicon content, and Sumitomo 9 Cr-2 Mo steel, which was in test for only 19,000 h. Parabolic oxidation kinetics adequately described the corrosion process for about the first year, after which corrosion rates were constant and lower than predicted from extrapolation of the initial part of the penetration versus time curves. With chromium concentrations between 2 and 9%, corrosion behavior was independent of chromium content, and corrosion was only slightly less with Sandvik HT-9. Corrosion was nearly independent of surface preparation, but in two cases the presence of mill scale on the surface prior to steam exposure seemed to retard oxidation in steam. 11 figures, 5 tables.

Griess, J.C.; DeVan, J.H.; Maxwell, W.A.

1980-01-01T23:59:59.000Z

186

DB Climate Change Advisors DBCCA | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentratingRenewable Solutions LLC JumpCrow Lake Wind JumpCuttings Analysis AtCycloceanCropsDB

187

Where is DB config stored? | OpenEI Community  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160 East 300 South Place: SaltTroyer & AssociatesWestIL NumberPowerWheegoDB config

188

Room Temperature, Intrinsic Vacancy Mediated Ferromagnetism in Cr:Ga2Se3/Si E. N. Yitamben,1,  

E-Print Network [OSTI]

Room Temperature, Intrinsic Vacancy Mediated Ferromagnetism in Cr:Ga2Se3/Si E. N. Yitamben,1, T. C of 4 µB/Cr. The intrinsic- vacancy structure of defected-zinc-blende -Ga2Se3 enables Cr incorporation, as well as strong overlap between Cr 3d states and the Se 4p states lining the intrinsic vacancy rows, ob

Olmstead, Marjorie

189

Low-cost, highly efficient, and tunable ultrafast laser technology based on directly diode-pumped Cr:Colquiriites  

E-Print Network [OSTI]

This doctoral project aims to develop robust, ultra low-cost ($5,000-20,000), highly-efficient, and tunable femtosecond laser technology based on diode-pumped Cr:Colquiriite gain media (Cr:LiCAF, Cr3+:LiSAF and Cr:LiSGaF). ...

Demirbas, Umit

2010-01-01T23:59:59.000Z

190

MgO seed layers for CoCrPt/Cr longitudinal magnetic recording media Li-Lien Lee, B. K. Cheong,a)  

E-Print Network [OSTI]

MgO seed layers for CoCrPt/Cr longitudinal magnetic recording media Li-Lien Lee, B. K. Cheong,a) D, the industry is still in the process of search- ing for a better seed layer. MgO is an ionic crystal that has

Laughlin, David E.

191

Vibronic spectroscopy of unsaturated transition metal complexes: CrC2H, CrCH3 , and NiCH3  

E-Print Network [OSTI]

to characterize diatomic transition metal oxides, nitrides, and carbides.8­22 In addition to these pure metallicVibronic spectroscopy of unsaturated transition metal complexes: CrC2H, CrCH3 , and NiCH3 Dale J investigation of small transition metal clusters and organo- metallic radicals is that these species serve

Morse, Michael D.

192

Study of possible systematics in the L*X - Ta* correlation of Gamma Ray Bursts  

E-Print Network [OSTI]

Gamma Ray Bursts (GRBs) are the most energetic sources in the universe and among the farthest known astrophysical sources. These features make them appealing candidates as standard candles for cosmological applications so that studying the physical mechanisms for the origin of the emission and correlations among their observable properties is an interesting task. We consider here the luminosity L*X - break time Ta* (hereafter LT) correlation and investigate whether there are systematics induced by selection effects or redshift dependent calibra- tion. We perform this analysis both for the full sample of 77 GRBs with known redshift and for the subsample of GRBs having canonical X-ray light curves, hereafter called U0095 sample. We do not find any systematic bias thus con- firming the existence of physical GRB subclasses revealed by tight correlations of their afterglow properties. Furthermore, we study the possibility of applying the LT correlation as a redshift estimator both for the full distribution and for the canonical lightcurves. The large uncertainties and the non negligible intrin- sic scatter make the results not so encouraging, but there are nevertheless some hints motivating a further analysis with an increased U0095 sample.

M. G. Dainotti; V. F. Cardone; S. Capozziello; M. Ostrowski; R. Willingale

2011-01-09T23:59:59.000Z

193

The effect of Ta doping in polycrystalline TiO{sub x} and the associated thin film transistor properties  

SciTech Connect (OSTI)

Tantalum (Ta) is suggested to act as an electron donor and crystal phase stabilizer in titanium oxide (TiO{sub x}). A transition occurs from an amorphous state to a crystalline phase at an annealing temperature above 300?°C in a vacuum ambient. As the annealing temperature increases from 300?°C to 450?°C, the mobility increases drastically from 0.07 cm{sup 2}/Vs to 0.61 cm{sup 2}/Vs. The remarkable enhancement of thin film transistor performance is suggested to be due to the splitting of Ti 3d band orbitals as well as the increase in Ta{sup 5+} ions that can act as electron donors.

Ok, Kyung-Chul, E-mail: kchul2926@naver.com; Park, Yoseb, E-mail: jozeph.park@gmail.com; Park, Jin-Seong, E-mail: kbchung@dankook.ac.kr, E-mail: jsparklime@hanyang.ac.kr [Division of Materials Science and Engineering, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 133-791 (Korea, Republic of)] [Division of Materials Science and Engineering, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 133-791 (Korea, Republic of); Chung, Kwun-Bum, E-mail: kbchung@dankook.ac.kr, E-mail: jsparklime@hanyang.ac.kr [Department of Physics, Dankook University, 119 Dandae-ro, Dongnam-gu, Cheonan 330-714 (Korea, Republic of)] [Department of Physics, Dankook University, 119 Dandae-ro, Dongnam-gu, Cheonan 330-714 (Korea, Republic of)

2013-11-18T23:59:59.000Z

194

Ab initio density functional studies of stepped TaC surfaces V. B. Shenoy and C. V. Ciobanu  

E-Print Network [OSTI]

RevB.67.081402 PACS number s : 68.35.Bs, 68.35.Md, 73.20.At The stepped surfaces of transition-metal carbides TiC, TaC, etc. are technologically important due to their applica- tions as surface catalysts as they provide a rich ground for studying faceting transitions that involve single- and multiple-height steps

Ciobanu, Cristian

195

Soft zone formation in dissimilar welds between two Cr-Mo steels  

SciTech Connect (OSTI)

Two dissimilar weldments between 9Cr-1Mo and 2.25Cr-1Mo ferritic steels have been characterized for their microstructural stability during various postweld heat treatments (PWHTs). The samples for the investigation were extracted from bead-on-plate weldments made by depositing 2.25Cr-1Mo weld metal on 9Cr-1Mo base plate and vice versa. Subsequent application of PWHT resulted in the formation of a soft zone in the low Cr ferritic steel weld or base plate. A carbide-rich hard zone, adjoining the soft zone, was also detected in the high Cr side of the weldment. Unmixed zones in the weld metal provided additional soft and hard zones in the weld metals. The migration of carbon from low-Cr steel to high-Cr steel, driven by the carbon activity gradient, has been shown to be responsible for the formation of soft and hard zones. A carbon activity diagram for 2.25Cr-1Mo/9Cr-1Mo weldments has been proposed to aid in the selection of welding consumables for reducing or preventing the soft zone formation.

Albert, S.K.; Gill, T.P.S.; Tyagi, A.K.; Mannan, S.L.; Rodriguez, P. [Indira Gandhi Centre for Atomic Research, Kalpakkam (India); Kulkarni, S.D. [Indian Inst. of Tech., Bombay (India)

1997-03-01T23:59:59.000Z

196

Microstructural analyses of Cr(VI) speciation in chromite ore processing Residue (COPR)  

SciTech Connect (OSTI)

The speciation and distribution of Cr(VI) in the solid phase was investigated for two types of chromite ore processing residue (COPR) found at two deposition sites in the United States: gray-black (GB) granular and hard brown (HB) cemented COPR. COPR chemistry and mineralogy were investigated using micro-X-ray absorption spectroscopy and micro-X-ray diffraction, complemented by laboratory analyses. GB COPR contained 30percent of its total Cr(VI) (6000 mg/kg) as large crystals(>20 ?m diameter) of a previously unreported Na-rich analog of calcium aluminum chromate hydrates. These Cr(VI)-rich phases are thought to be vulnerable to reductive and pH treatments. More than 50percent of the Cr(VI) was located within nodules, not easily accessible to dissolved reductants, and bound to Fe-rich hydrogarnet, hydrotalcite, and possibly brucite. These phases are stable over a large pH range, thus harder to dissolve. Brownmilleritewasalso likely associated with physical entrapment of Cr(VI) in the interior of nodules. HB COPR contained no Cr(VI)-rich phases; all Cr(VI) was diffuse within the nodules and absent from the cementing matrix, with hydrogarnet and hydrotalcite being the main Cr(VI) binding phases. Treatment ofHBCOPRis challenging in terms of dissolving the acidity-resistant, inaccessible Cr(VI) compounds; the same applies to ~;;50percent of Cr(VI) in GB COPR.

CHRYSOCHOOU, MARIA; FAKRA, SIRINE C .; Marcus, Matthew A.; Moon, Deok Hyun; Dermatas, Dimitris

2010-03-01T23:59:59.000Z

197

Floodplain Assessment for the Proposed Outdoor Fire Range Upgrades at TA-72 in Lower Sandia Canyon, Los Alamos National Laboratory  

SciTech Connect (OSTI)

Los Alamos National Laboratory (LANL) is preparing to implement actions in Sandia Canyon at Technical Area (TA) 72. Los Alamos National Security (LANS) biologists conducted a floodplain determination and this project is partially located within a 100-year floodplain. The proposed project is to upgrade the existing outdoor shooting range facilities at TA-72. These upgrades will result in increased safety and efficiencies in the training for Protective Force personnel. In order to remain current on training requirements, the firing ranges at TA-72 will be upgraded which will result in increased safety and efficiencies in the training for Protective Force personnel (Figure 1). These upgrades will allow for an increase in class size and more people to be qualified at the ranges. Some of these upgrades will be built within the 100-year floodplain. The upgrades include: concrete pads for turning target systems and shooting positions, new lighting to illuminate the firing range for night fire, a new speaker system for range operations, canopies at two locations, an impact berm at the far end of the 300-yard mark, and a block wall for road protection.

Hathcock, Charles D. [Los Alamos National Laboratory

2012-08-27T23:59:59.000Z

198

Infrared optical properties of amorphous and nanocrystalline Ta{sub 2}O{sub 5} thin films  

SciTech Connect (OSTI)

The optical constants of tantalum pentoxide (Ta{sub 2}O{sub 5}) are determined in a broad spectral region from the visible to the far infrared. Ta{sub 2}O{sub 5} films of various thicknesses from approximately 170 to 1600 nm are deposited using reactive magnetron sputtering on Si substrates. X-ray diffraction shows that the as-deposited films are amorphous, and annealing in air at 800 °C results in the formation of nanocrystalline Ta{sub 2}O{sub 5}. Ellipsometry is used to obtain the dispersion in the visible and near-infrared. Two Fourier-transform infrared spectrometers are used to measure the transmittance and reflectance at wavelengths from 1 to 1000 ?m. The surface topography and microstructure of the samples are examined using atomic force microscopy, confocal microscopy, and scanning electron microscopy. Classical Lorentz oscillators are employed to model the absorption bands due to phonons and impurities. A simple model is introduced to account for light scattering in the annealed films, which contain micro-cracks. For the unannealed samples, an effective-medium approximation is used to take into account the adsorbed moisture in the film and a Drude free-electron term is also added to model the broad background absorption.

Bright, T. J.; Watjen, J. I.; Zhang, Z. M. [George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States)] [George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); Muratore, C. [Nanoelectronic Materials Branch, Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright Patterson AFB, Ohio 45433 (United States) [Nanoelectronic Materials Branch, Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright Patterson AFB, Ohio 45433 (United States); Department of Chemical and Materials Engineering, University of Dayton, Dayton, Ohio 45469 (United States); Voevodin, A. A. [Nanoelectronic Materials Branch, Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright Patterson AFB, Ohio 45433 (United States)] [Nanoelectronic Materials Branch, Materials and Manufacturing Directorate, Air Force Research Laboratory, Wright Patterson AFB, Ohio 45433 (United States); Koukis, D. I.; Tanner, D. B. [Department of Physics, University of Florida, Gainesville, Florida 32611 (United States)] [Department of Physics, University of Florida, Gainesville, Florida 32611 (United States); Arenas, D. J. [Department of Physics, University of North Florida, Jacksonville, Florida 32254 (United States)] [Department of Physics, University of North Florida, Jacksonville, Florida 32254 (United States)

2013-08-28T23:59:59.000Z

199

The BridgeDb framework: standardized access to gene, protein and metabolite identifier mapping services  

E-Print Network [OSTI]

addition to the Java API, we provide a REST-based interface.REST) and is suitable for all other programming languages. BridgeDb Java APIAPI. IH improved the Ensembl ETL process and developed the REST

2010-01-01T23:59:59.000Z

200

Improved oxidation sulfidation resistance of Fe-Cr-Ni alloys  

DOE Patents [OSTI]

High temperature resistance of Fe-Cr-Ni alloy compositions to oxidative and/or sulfidative conditions is provided by the incorporation of about 1 to 8 wt % of Zr or Nb and results in a two-phase composition having an alloy matrix as the first phase and a fine grained intermetallic composition as the second phase. The presence and location of the intermetallic composition between grains of the matrix provides mechanical strength, enhanced surface scale adhesion, and resistance to corrosive attack between grains of the alloy matrix at temperatures of 500 to 1000/sup 0/C.

Natesan, K.; Baxter, D.J.

1983-07-26T23:59:59.000Z

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Oxidation sulfidation resistance of Fe-Cr-Ni alloys  

DOE Patents [OSTI]

High temperature resistance of Fe-Cr-Ni alloy compositions to oxidative and/or sulfidative conditions is provided by the incorporation of about 1-8 wt. % of Zr or Nb and results in a two-phase composition having an alloy matrix as the first phase and a fine grained intermetallic composition as the second phase. The presence and location of the intermetallic composition between grains of the matrix provides mechanical strength, enhanced surface scale adhesion, and resistance to corrosive attack between grains of the alloy matrix at temperatures of 500.degree.-1000.degree. C.

Natesan, Ken (Naperville, IL); Baxter, David J. (Woodridge, IL)

1984-01-01T23:59:59.000Z

202

SF6432-CR (02-01-13) Cost Reimbursement  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar HomePromisingStoriesSANDIA REPORT SANDSDNTM (04-95)7/31/137/31/13 PageCR

203

The response of CR-39 nuclear track detector to 1–9 MeV protons  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

The response of CR-39 nuclear track detector (TasTrak®) to protons in the energy range of 0.92–9.28 MeV has been studied. Previous studies of the CR-39 response to protons have been extended by examining the piece-to-piece variability in addition to the effects of etch time and etchant temperature; it is shown that the shape of the CR-39 response curve to protons can vary from piece-to-piece. Effects due to the age of CR-39 have also been studied using 5.5 MeV alpha particles over a 5-year period. Track diameters were found to degrade with the age of the CR-39 itself rather than the age of the tracks, consistent with previous studies utilizing different CR-39 over shorter time periods.

Sinenian, N.; Rosenberg, M. J.; Manuel, M.; McDuffee, S. C.; Casey, D. T.; Zylstra, A. B.; Rinderknecht, H. G.; Gatu Johnson, M.; Séguin, F. H.; Frenje, J. A.; Li, C. K.; Petrasso, R. D.

2011-10-28T23:59:59.000Z

204

Radionuclide contaminant analysis of small mammals at Area G, TA-54, Los Alamos National Laboratory, 1995  

SciTech Connect (OSTI)

At Los Alamos National Laboratory, small mammals were sampled at two waste burial sites (Site 1-recently disturbed and Site 2-partially disturbed) at Area G, Technical Area 54 and a control site on Frijoles Mesa (Site 4) in 1995. Our objectives were (1) to identify radionuclides that are present within surface and subsurface soils at waste burial sites, (2) to compare the amount of radionuclide uptake by small mammals at waste burial sites to a control site, and (3) to identify if the primary mode of contamination to small mammals is by surface contact or ingestion/inhalation. Three composite samples of at least rive animals per sample were collected at each site. Pelts and carcasses of each animal were separated and analyzed independently. Samples were analyzed for {sup 241}Am, {sup 90}Sr , {sup 238}Pu, {sup 239}Pu, total U, {sup 137}Cs, and {sup 3}H. Significantly higher (parametric West at p=0.05) levels of total U, {sup 241}Am, {sup 238}Pu and {sup 239}Pu were detected in pelts than in carcasses of small mammals at TA-54. Concentrations of other measured radionuclides in carcasses were nearly equal to or exceeded the mean concentrations in the pelts. Our results show higher concentrations in pelts compared to carcasses, which is similar to what has been found at waste burial/contaminated sites outside of Los Alamos National Laboratory. Site 1 had a significantly higher (alpha=0.05, P=0.0125) mean tritium concentration in carcasses than Site 2 or Site 4. In addition Site 1 also had a significantly higher (alpha=0.05, p=0.0024) mean tritium concentration in pelts than Site 2 or Site 4. Site 2 had a significantly higher (alpha=0.05, P=0.0499) mean {sup 239}Pu concentration in carcasses than either Site 1 or Site 4.

Bennett, K.; Biggs, J.; Fresquez, P.

1997-01-01T23:59:59.000Z

205

Bulk and track etch properties of CR-39 SSNTD etched in NaOH/ethanol  

E-Print Network [OSTI]

Bulk and track etch properties of CR-39 SSNTD etched in NaOH/ethanol K.F. Chan, F.M.F. Ng, D. described the use of NaOH/ethanol as an etchant for the CR-39 detector, and have determined the corre and track etch properties of CR- 39 in NaOH/ethanol were derived from direct measurements. The bulk etch

Yu, K.N.

206

CORROSION OF Fe-10Al-Cr ALLOYS BY COAL CHAR  

E-Print Network [OSTI]

off-gas from a typical gasifier contains large percentagesIOAl-Cr alloys at coal-gasifier This FeS and CaS0 operating

Gordon, B.A.

2011-01-01T23:59:59.000Z

207

Proton spectroscopy of 48Ni, 46Fe, and 44Cr  

E-Print Network [OSTI]

Results of decay spectroscopy on nuclei in vicinity of the doubly magic 48Ni are presented. The measurements were performed with a Time Projection Chamber with optical readout which records tracks of ions and protons in the gaseous volume. Six decays of 48Ni including four events of two-proton ground-state radioactivity were recorded. An advanced reconstruction procedure yielded the 2p decay energy for 48Ni of Q2p = 1.29(4) MeV. In addition, the energy spectra of \\b{eta}-delayed protons emitted in the decays of 44Cr and 46Fe, as well as half-lives and branching ratios were determined. The results were found to be consistent with the previous measurements made with Si detectors. A new proton line in the decay of 44Cr corresponding to the decay energy of 760 keV is reported. The first evidence for the \\b{eta}2p decay of 46 Fe, based on one clear event, is shown.

M. Pomorski; M. Pfützner; W. Dominik; R. Grzywacz; A. Stolz; T. Baumann; J. S. Berryman; H. Czyrkowski; R. D?browski; A. Fija?kowska; T. Ginter; J. Johnson; G. Kami?ski; N. Larson; S. N. Liddick; M. Madurga; C. Mazzocchi; S. Mianowski; K. Miernik; D. Miller; S. Paulauskas; J. Pereira; K. P. Rykaczewski; S. Suchyta

2014-07-06T23:59:59.000Z

208

Postirradiation deformation of ferritic Fe-Cr binary alloys  

SciTech Connect (OSTI)

Six binary Fe-Cr alloys ranging from 3 to 18% chromium were irradiated in the form of miniature tensile specimens in the Fast Flux Test Facility and tested at room temperature. The irradiation conditions produced 7 to 30 dpa at 365 to 574{degrees}C. The major purpose of the experiment was to compare the behavior of these simple alloys with that of more complex commercial alloys, The tensile data obtained on these specimens at room temperature are discussed with appropriate fractographic and microstructural support. Previous studies on similar materials had revealed the presence of a feature typically exhibited in channel fractures: elongated voids were evident in shear bands of an irradiated and deformed TEM disk of a binary Fe-6Cr alloy. An additional purpose of the experiment was therefore to provide a better understanding of the potential contribution of channel fracture to deformation in ferritic alloys. No evidence for channel fracture was found, however. 14 refs., 6 figs., 2 tabs.

Hamilton, M.L.; Gelles, D.S.

1991-06-01T23:59:59.000Z

209

Precipitation in 9Ni-12Cr-2Cu maraging steels  

SciTech Connect (OSTI)

Two maraging steels with the compositions 9Ni-12Cr-2Cu-4Mo (wt%) and 9Ni-12Cr-2Cu and with small additions of Al and Ti were investigated using atom probe field ion microscopy. Tomographic atom probe investigations were performed to clarify the spatial distribution of elements in and close to the precipitates. Materials heat treated at 475 C for 5, 25 min, 1, 2, 4 and 400 h were analyzed. Precipitates in the Mo-rich material were observed already after 5 min of aging, while in the material without MO, precipitation started later. In both materials precipitation begins with the formation of Cu-rich particles which work as nucleation sites for a Ni-rich phase of type Ni{sub 3}(Ti,Al). A Mo-rich phase was detected in the Mo-rich steel after 2 h of aging. The distribution of alloying elements in the precipitates, their role in the precipitation process, and the mechanism of hardening in the two materials are discussed.

Stiller, K.; Haettestrand, M. [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Physics] [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Physics; Danoix, F. [Univ. de Rouen, Mont Saint Aignan (France). Lab. de Microscopie Ionique] [Univ. de Rouen, Mont Saint Aignan (France). Lab. de Microscopie Ionique

1998-11-02T23:59:59.000Z

210

Corrosion resistance evaluation of 22Cr duplex stainless steel weldments  

SciTech Connect (OSTI)

Among the alternatives for the materials to be used for the construction of two flowlines 22Cr duplex stainless steel was taken into consideration. Corrosion resistance of the welds when exposed to the produced sour fluids was considered as the most critical point, so a program of corrosion testing on the 22Cr duplex stainless steel welds was developed. Three different welding procedures were used and tested in two different laboratories; specimens belonging to one of the welding procedures were also tested after a pre-strain to assess the effect of the deformation induced in the pipe by the wrapping in a reel. Tests were performed in an environment simulating the expected flowlines internal service conditions. Several testing procedures were used. Pitting test according to ASTM G48 Standard were carried out in order to rank welds and exposure tests in simulated field conditions were performed to assess stress corrosion and localized corrosion resistance. Test results showed that all the welds passed the tests and were applicable as corrosion resistant in the service environment. A ranking of the weld procedure based on their corrosion resistance has been determined.

Kopliku, A. [AGIP S.p.A., Milan (Italy); Bell, D. [AGIP UK, London (United Kingdom); Barteri, M. [C.S.M., Rome (Italy); Fowler, C. [CAPCIS, Manchester (United Kingdom)

1996-12-01T23:59:59.000Z

211

Data:23bc19a5-a508-4ca0-b7da-2d3c1db7db71 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of48d9ff47edf3 No revision5af6d400c2d4-4797-b850-d42be48a30cf No revision has been approvedd3c1db7db71 No

212

Effect of Cr2O3 on the 18O Tracer Incorporation in SOFC Materials  

SciTech Connect (OSTI)

Investigations of the impact of Cr{sub 2}O{sub 3} overlayers on the oxygen self diffusion in two SOFC materials were conducted to gain insight into the Cr poisoning mechanism at the cathode side of solid oxide fuel cells (SOFCs) with stainless steel interconnects. High density Y{sub 0.15}Zr{sub 0.85}O{sub 2} (YSZ) and La{sub 0.6}Sr{sub 0.4}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (LSCF) sintered pellets were covered with 3 to 30 nm Cr overlayers that were subsequently oxidized, forming Cr{sub 2}O{sub 3}. Standard {sup 18}O tracer diffusion experiments at 800 C were performed and ToF-SIMS profiling revealed that the oxygen ion diffusion coefficients were unaffected by the thin Cr{sub 2}O{sub 3} overlayers, which is predictable since they are a bulk property, but the extracted effective surface exchange coefficients varied with Cr{sub 2}O{sub 3} overlayer thickness. Solid-state reaction measurements and electronic structure considerations concerning the surface exchange, led to the conclusion that the observed oxygen uptake hindrance for Cr{sub 2}O{sub 3} capped LSCF and the slight increase of the surface exchange coefficient for Cr{sub 2}O{sub 3} capped YSZ can be attributed to the electronic properties of Cr{sub 2}O{sub 3}. A critical thickness for Cr{sub 2}O{sub 3} was determined to be 12 nm where the transition from decreasing cathode-performance to a Cr{sub 2}O{sub 3}-property-governed regime occurs.

Finsterbusch, M.; Lussier, A; Negusse, E; Zhu, Z; Smith, R; Schaefer, J; Idzerda, Y

2010-01-01T23:59:59.000Z

213

Corrosion Behavior of Solution-Annealed CoCrMo Medical Implant  

E-Print Network [OSTI]

! ! ! Corrosion Behavior of Solution- Annealed CoCrMo Medical Implant Alloys Pooja Panigrahi University June 6, 2011 #12;! ! ""! Corrosion Behavior of Solution-Annealed CoCrMo Medical Implant Alloys and Applied Sciences Northwestern University June 6, 2011 Abstract Corrosion behavior of solution annealed

Shull, Kenneth R.

214

ENDOR study of Cr3 centers substituting for lithium in lithium niobate  

E-Print Network [OSTI]

ENDOR study of Cr3¿ centers substituting for lithium in lithium niobate G. Malovichko,1, * V centers in lithium niobate crystals were investigated with the help of electron nuclear double resonance and the parameters of hyperfine and quadrupole interactions were determined. It is found that Cr3 substitutes for Li

Malovichko, Galina

215

MAGNESIUM ISOTOPIC COMPOSITION OF CAIs AND CHONDRULES FROM CR CHONDRITES. B. , M. Gounelle1  

E-Print Network [OSTI]

MAGNESIUM ISOTOPIC COMPOSITION OF CAIs AND CHONDRULES FROM CR CHONDRITES. B. Mimoun1 , M. Gounelle1. Introduction: The magnesium isotopic composi- tion of primitive extraterrestrial materials is worth measuring.g. 10]. Figure 1: The magnesium isotopic composition of CAIs in CR chondrites. Error bars are 1

Technische Universiteit Delft

216

EPR, ENDOR, and optical-absorption study of Cr3 centers substituting  

E-Print Network [OSTI]

ARTICLES EPR, ENDOR, and optical-absorption study of Cr3¿ centers substituting for niobium in Li of Sciences, Kiev, Ukraine Received 6 January 2000; revised manuscript received 3 May 2000 A triplet of EPR % of Cr. Detailed investigations of the angular dependencies of EPR and electron nuclear double

Malovichko, Galina

217

Field Investigations of Lactate-Stimulated Bioreduction of Cr(VI) at Hanford 100H  

SciTech Connect (OSTI)

The overall objective of this paper is to carry out field investigations to assess the potential for immobilizing and detoxifying chromium-contaminated groundwater using lactate-stimulated bioreduction of Cr(VI) to Cr(III) at the Hanford 100H site.

T. C. Hazen; B. Faybishenko; D. Joyner; S. Borglin; E. Brodie; S.; K. Williams; J. Peterson; J. Wan; T. Tokunaga; M.; P. E. Long; Resch, C.T.; Newcomer, D.; Koenigsberg, S.; Willet, A.

2005-04-20T23:59:59.000Z

218

Precipitation in a Cu–Cr–Zr–Mg alloy during aging  

SciTech Connect (OSTI)

The precipitation processes in a Cu-0.69Cr-0.10Zr-0.02Mg alloy aged at 450 °C and 550 °C have been investigated by transmission electron microscopy and high resolution transmission electron microscopy. The precipitation sequence in this alloy aged at 450 °C is: supersaturated solid solution ? Guinier–Preston zone (fcc Cr-rich phase) ? ordered fcc Cr-rich phase ? ordered bcc Cr-rich phase. The precipitation sequence in this alloy aged at 550 °C is: supersaturated solid solution ? ordered fcc Cr-rich phase ? ordered bcc Cr-rich phase. In the evolution of decomposition, the orientation relationship between the precipitates and the Cu matrix changes from cube-on-cube to Nishiyama–Wassermann orientation. The ordering of Cr-rich precipitates facilitates the formation of the bcc precipitates and promotes the development of Nishiyama–Wassermann orientation. - Highlights: • Two different precipitation sequences in the Cu–Cr–Zr–Mg alloy are proposed. • The changes in orientation relationship of the precipitates are presented. • The roles of ordering and coherent interface of the precipitates are discussed.

Cheng, J.Y., E-mail: bigchengjianyi@163.com; Shen, B.; Yu, F.X.

2013-07-15T23:59:59.000Z

219

New high pressure rare earth tantalates RE{sub x}Ta{sub 2}O{sub 5+1.5x} (RE=La, Eu, Yb)  

SciTech Connect (OSTI)

Rare earth tantalates La{sub 0.075}Ta{sub 2}O{sub 5.113}, Eu{sub 0.089}Ta{sub 2}O{sub 5.134} and Yb{sub 0.051}Ta{sub 2}O{sub 5.077} have been prepared by solid state reaction at P=7.0 GPa and T=1050–1100 °C and studied by X-ray diffraction, thermal analysis and electron microscopy. Low hydrated amorphous tantalum, lanthanum, europium and ytterbium hydroxides were used as starting materials. Aqueous as well as anhydrous compounds were obtained. Title tantalates are crystallized in the structure type of F–Ta{sub 2}O{sub 5} [Zibrov et al. Russ. J. Inorg. Chem. 48 (2003) 464–471] [5]. The structure was refined by the Rietveld method from X-ray powder diffractometer data: La{sub 0.075}Ta{sub 2}O{sub 5.113}, a=10.5099(2), b=7.2679(1), c=6.9765(1) Å, V=532.90(1) Å{sup 3}, Z=6, space group Ibam; Eu{sub 0.089}Ta{sub 2}O{sub 5.134}, a=10.4182(3), b=7.2685(1), c=6.9832(1) Å, V=528.80(2) Å{sup 3}, Z=6, space group Ibam; Yb{sub 0.051}Ta{sub 2}O{sub 5.077}, a=10.4557(2), b=7.3853(1), c=6.8923(1) Å, V=532.21(1) Å{sup 3}, Z=6, space group Ibam. RE atoms do not replace the tantalum in its positions but the only water in the channels of the structure. Highly charged cations RE{sup +3} compress the unit cell so that its volume becomes less than that of F–Ta{sub 2}O{sub 5}. Significant decrease of the unit cell volume after water removal from the structure is possible due to the puckering of pentagonal bipyramid layers and change of the corrugation angle in the layer. - Graphical abstract: The structure of RE{sub x}Ta{sub 2}O{sub 5+1.5x} and its HRTEM image (“A” arrows show empty channel, “B” arrows show filled channel). - Highlights: • We synthesized new tantalates of RE under high pressure high temperature conditions. • RE atoms replace water molecules in the channels of the structure. • Aqueous as well as anhydrous tantalates were obtained. • Highly charged cations RE{sup +3} compress the unit cell decreasing RE–O distances.

Zibrov, Igor P., E-mail: zibrov@mail.ru [Institute for High Pressure Physics, Russian Academy of Sciences, Kaluzhskoe Highway 14, Troitsk, Moscow 142190 (Russian Federation); Filonenko, Vladimir P., E-mail: filv@hppi.troitsk.ru [Institute for High Pressure Physics, Russian Academy of Sciences, Kaluzhskoe Highway 14, Troitsk, Moscow 142190 (Russian Federation); Zakharov, Nikolai D., E-mail: zakharov@mpi-halle.mpg.de [Max Planck Institute for Microstructure Physics, Weinberg 2, D-06120 Halle/Saale (Germany); Werner, Peter, E-mail: werner@mpi-halle.mpg.de [Max Planck Institute for Microstructure Physics, Weinberg 2, D-06120 Halle/Saale (Germany); Drobot, Dmitrii V., E-mail: dvdrobot@mail.ru [Lomonosov Moscow University of Fine Chemical Technology, Prospect Vernadskogo 86, Moscow 119571 (Russian Federation); Nikishina, Elena E.; Lebedeva, Elena N., E-mail: helena_nick@mail.ru [Lomonosov Moscow University of Fine Chemical Technology, Prospect Vernadskogo 86, Moscow 119571 (Russian Federation)

2013-07-15T23:59:59.000Z

220

Postirradiation deformation behavior in ferritic Fe-Cr alloys  

SciTech Connect (OSTI)

It has been demonstrated that fast neutron irradiation produces significant hardening in simple Fe(3-18)Cr binary alloys irradiated to about 35 dpa in the temperature range 365 to 420{degrees}C, whereas irradiation at 574{degrees}C produces hardening only for 15% or more chromium. The irradiation-induced changes in tensile properties are discussed in terms of changes in the power law work hardening exponent. The work hardening exponent of the lower chromium alloys decreased significantly after low temperature irradiation ({le}420{degrees}C) but increased after irradiation at 574{degrees}C. The higher chromium alloys failed either in cleavage or in a mixed ductile/brittle fashion. Deformation microstructures are presented to support the tensile behavior.

Hamilton, M.L.; Gelles, D.S. [Pacific Northwest Lab., Richland, VA (United States); Gardner, P.L. [Univ. of Missouri, Rolla (United States)

1992-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Postirradiation deformation behavior in ferritic Fe-Cr alloys  

SciTech Connect (OSTI)

It has been demonstrated that fast-neutron irradiation produces significant hardening in simple Fe-(3-18)Cr binary alloys irradiated to about 35 dpa in the temperature range 365 to 420{degrees}C, whereas irradiation at 574{degrees}C produces hardening only for 15% or more chromium. The irradiation-induced changes in tensile properties are discussed in terms of changes in the power law work-hardening exponent. The work-hardening exponent of the lower chromium alloys decreased significantly after low-temperature irradiation ({le} 420{degrees}C) but increased after irradiation at 574{degrees}C. The higher chromium alloys failed either in cleavage or in a mixed ductile/brittle fashion. Deformation microstructures are presented to support the tensile behavior.

Hamilton, M.L.; Gelles, D.S. [Pacific Northwest Lab., Richland, WA (United States); Gardner, P.L. [Missouri Univ., Rolla, MO (United States)

1992-06-01T23:59:59.000Z

222

Postirradiation deformation behavior in ferritic Fe-Cr alloys  

SciTech Connect (OSTI)

It has been demonstrated that fast-neutron irradiation produces significant hardening in simple Fe-(3-18)Cr binary alloys irradiated to about 35 dpa in the temperature range 365 to 420[degrees]C, whereas irradiation at 574[degrees]C produces hardening only for 15% or more chromium. The irradiation-induced changes in tensile properties are discussed in terms of changes in the power law work-hardening exponent. The work-hardening exponent of the lower chromium alloys decreased significantly after low-temperature irradiation ([le] 420[degrees]C) but increased after irradiation at 574[degrees]C. The higher chromium alloys failed either in cleavage or in a mixed ductile/brittle fashion. Deformation microstructures are presented to support the tensile behavior.

Hamilton, M.L.; Gelles, D.S. (Pacific Northwest Lab., Richland, WA (United States)); Gardner, P.L. (Missouri Univ., Rolla, MO (United States))

1992-06-01T23:59:59.000Z

223

STARDUST INVESTIGATION INTO THE CR CHONDRITE GROVE MOUNTAIN 021710  

SciTech Connect (OSTI)

We report the presolar grain inventory of the CR chondrite Grove Mountain 021710. A total of 35 C-anomalous grains ({approx}236 ppm) and 112 O-anomalous grains ({approx}189 ppm) were identified in situ using NanoSIMS ion imaging. Of 35 C-anomalous grains, 28 were determined to be SiC grains by Auger spectroscopy. Seven of the SiC grains were subsequently measured for N and Si isotopes, allowing classification as one nova grain, one Y grain, one Z grain, and four mainstream grains. Eighty-nine out of 112 O-anomalous grains belong to Group 1, indicating origins in low-to-intermediate-mass red giant and asymptotic giant branch stars. Twenty-one are Group 4 grains and have origins in supernovae. Auger spectroscopic elemental measurements of 35 O-anomalous grains show that 33 of them are ferromagnesian silicates. They have higher Mg/(Mg+Fe) ratios than those reported in other meteorites, suggesting a lower degree of alteration in the nebula and/or asteroid parent bodies. Only two oxide grains were identified, with stoichiometric compositions of MgAl{sub 2}O{sub 4} and SiO{sub 2}, respectively. The presolar silicate/oxide ratio of GRV 021710 is comparable with those of the CR3 chondrites (QUE 99177 and MET 00426) and primitive interplanetary dust particles. In order to search for presolar sulfides, the meteorite was also mapped for S isotopes. However, no presolar sulfides were found, suggesting a maximum abundance of 2 ppm. The scarcity of presolar sulfides may be due to their much faster sputtering rate by cosmic rays compared to silicates.

Zhao Xuchao; Lin Yangting [Key Laboratory of the Earth's Deep Interior, Institute of Geology and Geophysics, Chinese Academy of Sciences, 19 Beituchengxi Road, Beijing 100029 (China); Floss, Christine [Laboratory for Space Sciences and Physics Department, Washington University, One Brookings Drive, St. Louis, MO 63130 (United States); Bose, Maitrayee, E-mail: linyt@mail.igcas.ac.cn [Department of Chemistry and Biochemistry, Arizona State University, P.O. Box 871604, Tempe, AZ 85287 (United States)

2013-05-20T23:59:59.000Z

224

Solid state phase equilibria and intermetallic compounds of the Al-Cr-Ho system  

SciTech Connect (OSTI)

The solid state phase equilibria of the Al-Cr-Ho ternary system at 500 Degree-Sign C were experimentally investigated. The phase relations at 500 Degree-Sign C are governed by 14 three-phase regions, 29 two-phase regions and 15 single-phase regions. The existences of 10 binary compounds and 2 ternary phases have been confirmed. Al{sub 11}Cr{sub 2}, Al{sub 11}Cr{sub 4} and Al{sub 17}Ho{sub 2} were not found at 500 Degree-Sign C. Crystal structures of Al{sub 9}Cr{sub 4} and Al{sub 8}Cr{sub 4}Ho were determined by the Rietveld X-ray powder data refinement. Al{sub 9}Cr{sub 4} was found to exhibit cubic structure with space group I4-bar 3m (no. 217) and lattice parameters a=0.9107(5) nm. Al{sub 8}Cr{sub 4}Ho crystallizes in ThMn{sub 12} structure type with space group I4/mmm (no. 139) and lattice parameters a=0.8909(4) nm, c=0.5120(5) nm. It is concluded that the obtained Al{sub 4}Cr phase in this work should be {mu}-Al{sub 4}Cr by comparing with XRD pattern of the hexagonal {mu}-Al{sub 4}Mn compound. - Graphical abstract: The solid state phase equilibria of the Al-Cr-Ho ternary system at 500 Degree-Sign C. Highlights: Black-Right-Pointing-Pointer Al-Cr-Ho system has been investigated. Black-Right-Pointing-Pointer Al{sub 9}Cr{sub 4} has cubic structure with space group I4-bar 3m. Black-Right-Pointing-Pointer Al{sub 8}Cr{sub 4}Ho crystallizes in ThMn{sub 12} type with space group I4/mmm. Black-Right-Pointing-Pointer Al{sub 4}Cr phase is {mu}-type at 500 Degree-Sign C.

Pang, Mingjun [Laboratory of Nonferrous Metal Materials and New Processing Technology, Ministry of Education, Guangxi University, Nanning, Guangxi 530004 (China) [Laboratory of Nonferrous Metal Materials and New Processing Technology, Ministry of Education, Guangxi University, Nanning, Guangxi 530004 (China); SAIC-GM-Wuling Automobile Co., Ltd., Liuzhou, Guangxi 545007 (China); Zhan, Yongzhong, E-mail: zyzmatres@yahoo.com.cn [Laboratory of Nonferrous Metal Materials and New Processing Technology, Ministry of Education, Guangxi University, Nanning, Guangxi 530004 (China)] [Laboratory of Nonferrous Metal Materials and New Processing Technology, Ministry of Education, Guangxi University, Nanning, Guangxi 530004 (China); Du, Yong [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China)] [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China)

2013-02-15T23:59:59.000Z

225

Safety, Pharmacokinetic, and Efficacy Studies of Oral DB868 in a First Stage Vervet Monkey Model of Human African Trypanosomiasis  

E-Print Network [OSTI]

-pyridyl]furan (DB868; CPD-007-10), in the vervet monkey model of first stage HAT. DB868 was well tolerated at a dose up to 30 mg/kg/day for 10 days, a cumulative dose of 300 mg/kg. Mean plasma levels of biomarkers indicative of liver injury (alanine...

Thutia, John K.; Wolf, Kristina K.; Murilla, Grace A.; Liu, Qiang; Mutuku, James N.; Chen, Yao; Bridges, Arlene S.; Mdachi, Raymond E.; Ismail, Mohamed A.; Ching, Shelley; Boykin, David W.; Hall, James E.; Tidwell, Richard R.; Paine, Mary F.; Burn, Reto; Wang, Michael Z.

2013-06-06T23:59:59.000Z

226

Mesoporous carbon -Cr2O3 composite as an anode material for lithium ion batteries  

SciTech Connect (OSTI)

Mesoporous carbon-Cr2O3 (M-C-Cr2O3) composite was prepared by co-assembly of in-situ formed phenolic resin, chromium precursor, and Pluronic block copolymer under acidic conditions, followed by carbonization at 750oC under Argon. The TEM results confirmed that the Cr2O3 nanoparticles, ranging from 10 to 20 nm, were well dispersed in the matrix of mesoporous carbon. The composite exhibited an initial reversible capacity of 710 mAh g-1 and good cycling stability, which is mainly due to the synergic effects of carbons within the composites, i.e. confining the crystal growth of Cr2O3 during the high temperature treatment step and buffering the volume change of Cr2O3 during the cycling step. This composite material is a promising anode material for lithium ion batteries.

Guo, Bingkun [ORNL; Chi, Miaofang [ORNL; Sun, Xiao-Guang [ORNL; Dai, Sheng [ORNL

2012-01-01T23:59:59.000Z

227

Void swelling resistance in Fe-Cr alloys at 200 dpa  

SciTech Connect (OSTI)

Microstructural examinations have been performed on a serious of binary Fe-cr alloys irradiated to 200 dpa at 425 C in a fast breeder reactor. The alloy compositions ranged from 3% to 18% Cr in 3% Cr increments, and the irradiation temperature corresponded to the peak swelling condition for this alloy class. Density measurements showed swelling levels as high as 7.4%, with the highest swelling found in the Fe-9Cr and Fe-6Cr alloys. Microstructural examinations revealed that the highest swelling conditions contained well-developed voids, often as large as 100 nm, and a dislocation network comprised of both a/2<111> and a<100> Burgers vectors. Swelling was lower in the other alloys, and the swelling reduction could be correlated with increased precipitation. These results are considered in light of the current theories for low swelling in ferritic alloys, but no theory is available to completely explain the results.

Gelles, D.S. [Pacific Northwest Lab., Richland, WA (United States)

1995-09-01T23:59:59.000Z

228

The resistance to cavitation erosion of CrMnN stainless steels  

SciTech Connect (OSTI)

The resistance to cavitation erosion (CE) was measured using a magnetostrictive device and a rotating disk device for some CrMnN stainless steels (Chinese patent ZL 90 1 02197.0). The microstructural changes in the surface layer before and after CE were analyzed by use of Mossbauer spectra. Results show that the resistance to CE of duplex austenitic-martensitic CrMnN stainless steels is much better than that of ZG0Cr13Ni4-6Mo and ZG0Cr16Ni5Mo steel, which are in common use for hydraulic turbine runners. The metastable austenite and its changes in the process of CE are the key factors why the CrMnN stainless steels have excellent resistance to cavitation erosion.

Fu, W.T. [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering] [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering; [Harbin Inst. of Tech. (China); Jing, T.F.; Zheng, Y.Z. [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering] [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering; Yang, Y.B. [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering] [Yanshan Univ., Qinhuangdao (China). Dept. of Materials Engineering; [Bohai Aluminum Industries Co., Ltd., Qinhuangdao (China); Yao, M. [Harbin Inst. of Tech. (China)] [Harbin Inst. of Tech. (China)

1998-12-01T23:59:59.000Z

229

Electron concentration and phase stability in NbCr2-based Laves phase alloys  

SciTech Connect (OSTI)

Phase stability in NbCr{sub 2}-based transition-metal Laves phases was studied, based on the data reported for binary X-Cr, Nb-X, and ternary Nb-Cr-X phase diagrams. It was shown that when the atomic size ratios are kept identical, the average electron concentration factor, e/a, is the dominating factor in controlling the phase stability of NbCr{sub 2}-based transition-metal Laves phases. The e/a ratios for different Laves polytypes were determined as followed: with e/a < 5.76, the C15 structure is stabilized; at an e/a range of 5.88--7.53, the C14 structure is stabilized; with e/a > 7.65, the C15 structure is stabilized again. A further increase in the electron concentration factor (e/a > 8) leads to the disordering of the alloy. The electron concentration effect on the phase stability of Mg-based Laves phases and transition-metal A{sub 3}B intermetallic compounds is also reviewed and compared with the present observations in transition-metal Laves phases. In order to verify the e/a/phase stability relationship experimentally, additions of Cu (with e/a = 11) were selected to replace Cr in the NbCr{sub 2} Laves phase. Experimental results for the ternary Nb-Cr-Cu system are reported and discussed in terms of the correlation between the e/a ratio and phase stability in NbCr{sub 2}-based Laves phases. A new phase was found, which has an average composition of Nb-47Cr-3Cu. Within the solubility limit, the electron concentration and phase stability relationship is obeyed in the Nb-Cr-Cu system.

Zhu, J.H.; Liaw, P.K. [Univ. of Tennessee, Knoxville, TN (United States). Dept. of Materials Science and Engineering; Liu, C.T. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

1997-05-12T23:59:59.000Z

230

Integrated Ecogenomics Study for Bioremediation of Cr(VI) at Hanford 100H Area  

SciTech Connect (OSTI)

Hexavalent chromium is a widespread contaminant found in groundwater. In order to stimulate microbially mediated Cr(VI)-reduction, a poly-lactate compound was injected into Cr(VI)-contaminated aquifers at site 100H at Hanford. Investigation of bacterial community composition using high-density DNA microarray analysis of 16S rRNA gene products revealed a stimulation of Pseudomonas, Desulfovibrio and Geobacter species amongst others. Enrichment of these organisms coincided with continued Cr(VI) depletion. Functional gene-array analysis of DNA from monitoring well indicated high abundance of genes involved in nitrate-reduction, sulfate-reduction, iron-reduction, methanogenesis, chromium tolerance/reduction. Clone-library data revealed Psedomonas was the dominant genus in these samples. Based on above results, we conducted lab investigations to study the dominant anaerobic culturable microbial populations present at this site and their role in Cr(VI)-reduction. Enrichments using defined anaerobic media resulted in isolation of an iron-reducing, a sulfate-reducing and a nitrate-reducing isolate among several others. Preliminary 16S rDNA sequence analysis identified the isolates as Geobacter metallireducens, Pseudomonas stutzeri and Desulfovibrio vulgaris species respectively. The Pseudomonas isolate utilized acetate, lactate, glycerol and pyruvate as alternative carbon sources, and reduced Cr(VI). Anaerobic washed cell suspension of strain HLN reduced almost 95?M Cr(VI) within 4 hr. Further, with 100?M Cr(VI) as sole electron-acceptor, cells grew to 4.05 x 107 /ml over 24 h after an initial lag, demonstrating direct enzymatic Cr(VI) reduction coupled to growth. These results demonstrate that Cr(VI)-immobilization at Hanford 100H site could be mediated by direct microbial metabolism in addition to indirect chemical reduction of Cr(VI) by end-products of microbial activity.

Chakraborty, Romy; Chakraborty, Romy

2008-08-12T23:59:59.000Z

231

Simulation of Reduction of Cr(VI) by Fe(II) Produced Electrochemically in a Parallel-Plate Electrochemical Reactor  

E-Print Network [OSTI]

at the cathode, electrocoagulation uses electricity to produce a reducing agent ferrous ions from an iron anode the reduction of Cr VI by permeable reactive barriers. Gheju and Lovi7 reported that the re- duction of Cr VI

232

Implementation of scattering pinhole diagnostic for detection of fusion products on CR-39 at high particle fluence  

E-Print Network [OSTI]

Many Inertial Confinement Fusion (ICF) experiments use solid-state nuclear track detector CR-39 as a means to detect different types of nuclear products. Until recently, it was difficult to use CR-39 in experiments with ...

Orozco, David, S.B. Massachusetts Institute of Technology

2014-01-01T23:59:59.000Z

233

Floodplain Assessment for the Proposed Engineered Erosion Controls at TA-72 in Lower Sandia Canyon, Los Alamos National Laboratory  

SciTech Connect (OSTI)

Los Alamos National Laboratory (LANL) is preparing to implement engineering controls in Sandia Canyon at Technical Area (TA) 72. Los Alamos National Security (LANS) biologists conducted a floodplain determination and this project is located within a 100-year floodplain. The proposed project is to rehabilitate the degraded channel in lower Sandia Canyon where it crosses through the outdoor firing range at TA-72 to limit the loss of sediment and dissipate floodwater leaving LANL property (Figure 1). The proposed construction of these engineered controls is part of the New Mexico Environment Department's (NMED) approved LANL Individual Storm Water Permit. The purpose of this project is to install storm water controls at Sandia Watershed Site Monitoring Area 6 (S-SMA-6). Storm water controls will be designed and installed to meet the requirements of NPDES Permit No. NM0030759, commonly referred to as the LANL Individual Storm Water Permit (IP). The storm water control measures address storm water mitigation for the area within the boundary of Area of Concern (AOC) 72-001. This action meets the requirements of the IP for S-SMA-6 for storm water controls by a combination of: preventing exposure of upstream storm water and storm water generated within the channel to the AOC and totally retaining storm water falling outside the channel but within the AOC.

Hathcock, Charles D. [Los Alamos National Laboratory

2012-08-27T23:59:59.000Z

234

Characteristics of phase nucleation and growth during oriented crystallization of alloys of the Si-TaSi/sub 2/ and Si-NbSi/sub 2/ eutectic systems  

SciTech Connect (OSTI)

The authors investigate the effect of the nucleation conditions and the initial concentration of the components on the nature of the change in the phase composition and structure along the length of the directionally crystallized bars of alloys in the Si-TaSi/sub 2/ and Si-NbSi/sub 2/ eutectic systems. The compositions of the investigated alloys are given. The starting materials were silicon of semiconductor purity, tantalum, and niobium produced by electron beam melting. The alloys were crystallized directionally by the Czochralski method. The nature of the structure and the volume ratio of the phases in the investigated alloys depend significantly on the type of seed, i.e., on the nucleation conditions of the eutectic grain. The basic phases in the eutectic alloys of the Si-TaSi/sub 2/ and Si-NbSi/sub 2/ systems are the disilicides TaSi/sub 2/ and NbSi/sub 2/ respectively.

Grabovetskaya, G.P.; Butkevich, L.M.

1987-07-01T23:59:59.000Z

235

A new model to account for track overlap in CR-39 data A.B. Zylstra a,n  

E-Print Network [OSTI]

in revised form 3 April 2012 Accepted 3 April 2012 Available online 19 April 2012 Keywords: CR-39 Nuclear track detectors Inertial confinement fusion a b s t r a c t The solid-state nuclear track detector CR-39 such as neutron dosimetry and radon detection. The upper limit of detectable charged-particle fluence on CR-39

236

Role of Embedded Clustering in Dilute Magnetic Semiconductors: Cr Doped GaN X. Y. Cui,1  

E-Print Network [OSTI]

, typically 5 (20­30) times smaller for Cr-based (Mn-based) III-V DMS than the value expected, 3 B= Cr4 BRole of Embedded Clustering in Dilute Magnetic Semiconductors: Cr Doped GaN X. Y. Cui,1 J. E configurations coexist and the statistical distribution and associated magnetism will depend sensitively

Medvedeva, Julia E.

237

Differential isotopic fractionation during Cr(VI) reduction by an aquifer-derived bacterium under arobic versus denitrifying conditions  

SciTech Connect (OSTI)

We studied Cr isotopic fractionation during Cr(VI) reduction by Pseudomonas stutzeri strain RCH2. Despite the fact that strain RCH2 reduces Cr(VI) co-metabolically under both aerobic and denitrifying conditions and at similar specific rates, fractionation was markedly different under these two conditions (ε ~2? aerobically and ~0.4? under denitrifying conditions).

Han, R.; Qin, L.; Brown, S. T.; Christensen, J. N.; Beller, H. R.

2012-02-01T23:59:59.000Z

238

Cr-Ga-N materials for negative electrodes in Li rechargeable batteries : structure, synthesis and electrochemical performance  

E-Print Network [OSTI]

Electrochemical performances of two ternary compounds (Cr2GaN and Cr3GaN) in the Cr-Ga-N system as possible future anode materials for lithium rechargeable batteries were studied. Motivation for this study was dealt in ...

Kim, Miso

2007-01-01T23:59:59.000Z

239

Nanoscale Phase Separation In Epitaxial Cr-Mo and Cr-V Alloy Thin Films Studied Using Atom Probe Tomography: Comparison Of Experiments And Simulation  

SciTech Connect (OSTI)

Tailored metal alloy thin film-oxide interfaces generated using molecular beam epitaxial (MBE) deposition of alloy thin films on a single crystalline oxide substrate can be used for detailed studies of irradiation damage response on the interface structure. However presence of nanoscale phase separation in the MBE grown alloy thin films can impact the metal-oxide interface structure. Due to nanoscale domain size of such phase separation it is very challenging to characterize by conventional techniques. Therefor laser assisted atom probe tomography (APT) was utilized to study the phase separation in epitaxial Cr0.61Mo0.39, Cr0.77Mo0.23, and Cr0.32V0.68 alloy thin films grown by MBE on MgO(001) single crystal substrates. Statistical analysis, namely frequency distribution analysis and Pearson coefficient analysis of experimental data was compared with similar analyses conducted on simulated APT datasets with known extent of phase separation. Thus the presence of phase separation in Cr-Mo films, even when phase separation was not clearly observed by x-ray diffraction, and the absence of phase separation in the Cr-V film were thus confirmed.

Devaraj, Arun; Kaspar, Tiffany C.; Ramanan, Sathvik; Walvekar, Sarita K.; Bowden, Mark E.; Shutthanandan, V.; Kurtz, Richard J.

2014-11-21T23:59:59.000Z

240

Ni-Cr-P plating bath time dependent characterization by ion chromatography  

E-Print Network [OSTI]

analysis of Cr VII. HPIC gradient eluation program for anions VIII. HPIC eluation program for HsBOs IX. A method comparison of initial Ni-Cr-P plating bath ionic species concentrations as determined by weight measurement and HPIC analysis. X. Ni... the rate constants for compound C. 40 44 79 80 CHAPTER I INTRODUCTION Amorphous Nickel-Chromium-Phosphorus (Ni-Cr-P) alloys have outstand- ing corrosion resistance, which is even superior to that of Hastelloy C-276 (1). This corrosion resistance...

Faxel, Ralph Edward

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

High temperature oxidation behavior of Fe-Cr-Al foils  

SciTech Connect (OSTI)

Metallic catalytic converters for automotive emission control is becoming an important application for heat resistant alloys as more design opportunities are realized. The service conditions and design of metallic catalytic converters require the alloy to be highly oxidation resistant at gauges typically at 50 microns or less. For conventional heat resistant alloy design the goal is to form a well adherent scale on the alloy surface to protect the alloy matrix from being oxidized. However, the thin gauge results in a limited supply of alloying elements that can form the protective scale on the surface. The alloy chemistry has to be optimized to have the minimum oxidation while maintaining processing characteristics. Furthermore, the ratio of scale thickness to foil gauge is significant and the stress state between them introduces measurable permanent distortion of the foil. In this study, the effect of alloying elements on the oxidation behavior of commonly used Fe-Cr-Al alloys was quantified by the oxidation weight gain and length change measurements.

Chang, C.S.; Jha, B. [Texas Instruments, Inc., Attleboro, MA (United States)

1998-12-31T23:59:59.000Z

242

Steamside Oxidation Behavior of Experimental 9%Cr Steels  

SciTech Connect (OSTI)

Reducing emissions and increasing economic competitiveness require more efficient steam power plants that utilize fossil fuels. One of the major challenges in designing these plants is the availability of materials that can stand the supercritical and ultra-supercritical steam conditions at a competitive cost. There are several programs around the world developing new ferritic and austenitic steels for superheater and reheater tubes exposed to the advanced steam conditions. The new steels must possess properties better than current steels in terms of creep strength, steamside oxidation resistance, fireside corrosion resistance, and thermal fatigue resistance. This paper introduces a series of experimental 9%Cr steels containing Cu, Co, and Ti. Stability of the phases in the new steels is discussed and compared to the phases in the commercially available materials. The steels were tested under both the dry and moist conditions at 650ºC for their cyclical oxidation resistance. Results of oxidation tests are presented. Under the moist conditions, the experimental steels exhibited significantly less mass gain compared to the commercial P91 steel. Microstructural characterization of the scale revealed different oxide compositions.

Dogan, O.N.; Holcomb, G.R.; Alman, D.E.; Jablonski, P.D.

2007-10-01T23:59:59.000Z

243

Electrochemical Testing of Ni-Cr-Mo-Gd Alloys  

SciTech Connect (OSTI)

The waste package site recommendation design specified a boron-containing stainless steel, Neutronit 976/978, for fabrication of the internal baskets that will be used as a corrosion-resistant neutron-absorbing material. Recent corrosion test results gave higher-than-expected corrosion rates for this material. The material callout for these components has been changed to a Ni-Cr-Mo-Gd alloy (ASTM-B 932-04, UNS N06464) that is being developed at the Idaho National Laboratory. This report discusses the results of initial corrosion testing of this material in simulated in-package environments that could contact the fuel baskets after breach of the waste package outer barrier. The corrosion test matrix was executed using the potentiodynamic and potentiostatic electrochemical test techniques. The alloy performance shows low rates of general corrosion after initial removal of a gadolinium-rich second phase that intersects the surface. The high halide-containing test solutions exhibited greater tendencies toward initiation of crevice corrosion.

T. E. Lister; R. E. Mizia; H. Tian

2005-10-01T23:59:59.000Z

244

Two-particle azimuthal correlations in 4.2A GeV C+Ta collisions  

SciTech Connect (OSTI)

Two particle azimuthal correlations are studied in 4.2A GeV C+Ta collisions observed with the 2-m propane bubble chamber exposed at JINR Dubna Synchrophasotron. The correlations are analyzed both for protons and negative pions, and their dependence on the collision centrality, rapidity and rapidity difference is investigated. It is found that protons show a weak back-to-back correlations, while a side-by-side correlations are observed for negative pions. Restricting both protons to the target or projectile fragmentation region, the side-by-side correlations are observed for protons also. Using the two particle correlation function, the flow analysis is performed and intensity of directed flow is determined without event-by event estimation of the reaction plane.

Simic, Lj.; Mendas, I. [Institute of Physics, P.O. Box 68, 11081 Belgrade, Serbia (Serbia and Montenegro); Jotanovic, O. [Faculty of Natural Science, Banja Luka (Bosnia and Herzegowina); Milosevic, J. [Department of Physics, University of Oslo, Oslo (Norway)

2007-10-15T23:59:59.000Z

245

Building America Case Study: Ground Source Heat Pump Research, TaC Studios Residence, Atlanta, Georigia (Fact Sheet)  

SciTech Connect (OSTI)

As part of the NAHB Research Center Industry Partnership, Southface partnered with TaC Studios, an Atlanta based architecture firm specializing in residential and light commercial design, on the construction of a new test home in Atlanta, GA in the mixed-humid climate. This home serves as a residence and home office for the firm's owners, as well as a demonstration of their design approach to potential and current clients. Southface believes the home demonstrates current best practices for the mixed-humid climate, including a building envelope featuring advanced air sealing details and low density spray foam insulation, glazing that exceeds ENERGY STAR requirements, and a high performance heating and cooling system. Construction quality and execution was a high priority for TaC Studios and was ensured by a third party review process. Post construction testing showed that the project met stated goals for envelope performance, an air infiltration rate of 2.15 ACH50. The homeowner's wished to further validate whole house energy savings through the project's involvement with Building America and this long-term monitoring effort. As a Building America test home, this home was evaluated to detail whole house energy use, end use loads, and the efficiency and operation of the ground source heat pump and associated systems. Given that the home includes many non-typical end use loads including a home office, pool, landscape water feature, and other luxury features not accounted for in Building America modeling tools, these end uses were separately monitored to determine their impact on overall energy consumption.

Not Available

2014-09-01T23:59:59.000Z

246

CORROSION OF Fe-10Al-Cr ALLOYS BY COAL CHAR  

E-Print Network [OSTI]

owned rights. LBL-6946 Corrosion of Fe-lOAl-Cr Alloys byOctober, 1977 Abstract Corrosion of iron-base alloys at 982°high-temperature induced corrosion are probably sulfides and

Gordon, B.A.

2011-01-01T23:59:59.000Z

247

Structure, Magnetism, and Transport of CuCr2Se4 Thin Films  

E-Print Network [OSTI]

Structure, Magnetism, and Transport of CuCr 2 Se 4 Thindichroism shows that the magnetism persists to the surfacesuch as the nature of magnetism at surfaces and interfaces.

2008-01-01T23:59:59.000Z

248

E-Print Network 3.0 - austenitic fe-cr-ni alloys Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

than at 650C. Therefore, for these Fe-Cr-Ni model alloys, increasing... Figure 5 shows LM of the samples after 100x1h cycles at 650C for representative ... Source: Pint, Bruce...

249

C/CrC nanocomposite coating deposited by magnetron sputtering at high ion irradiation conditions  

SciTech Connect (OSTI)

CrC with the fcc NaCl (B1) structure is a metastable phase that can be obtained under the non-equilibrium conditions of high ion irradiation. A nano-composite coating consisting of amorphous carbon embedded in a CrC matrix was prepared via the unbalanced magnetron sputtering of graphite and Cr metal targets in Ar gas with a high ionized flux (ion-to-neutral ratio Ji/Jn = 6). The nanoscale amorphous carbon clusters self-assembled into layers alternated by CrC, giving the composite a multilayer structure. The phase, microstructure, and composition of the coating were characterized using x-ray diffraction, transmission electron microscopy, and aberration corrected scanning transmission electron microscopy coupled with electron energy loss spectroscopy. The interpretation of the true coating structure, in particular the carbide type, is discussed.

Zhou, Z.; Rainforth, W. M. [Department of Materials Science and Engineering, University of Sheffield, Sheffield, S1 3JD (United Kingdom); Gass, M. H.; Bleloch, A. [SuperSTEM at Daresbury Laboratory, Daresbury, Cheshire, WA4 4AD (United Kingdom); Ehiassarian, A. P.; Hovsepian, P. Eh. [Materials Engineering Research Institute, Sheffield Hallam University, Sheffield, S1 1WB (United Kingdom)

2011-10-01T23:59:59.000Z

250

Process for producing Ti-Cr-Al-O thin film resistors  

DOE Patents [OSTI]

Thin films of Ti-Cr-Al-O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti-Cr-Al-O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti-Cr-Al-O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti-Cr-Al-O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

Jankowski, Alan F. (Livermore, CA); Schmid, Anthony P. (Solana Beach, CA)

2001-01-01T23:59:59.000Z

251

Flat panel display using Ti-Cr-Al-O thin film  

DOE Patents [OSTI]

Thin films of Ti--Cr--Al--O are used as a resistor material. The films are rf sputter deposited from ceramic targets using a reactive working gas mixture of Ar and O.sub.2. Resistivity values from 10.sup.4 to 10.sup.10 Ohm-cm have been measured for Ti--Cr--Al--O film <1 .mu.m thick. The film resistivity can be discretely selected through control of the target composition and the deposition parameters. The application of Ti--Cr--Al--O as a thin film resistor has been found to be thermodynamically stable, unlike other metal-oxide films. The Ti--Cr--Al--O film can be used as a vertical or lateral resistor, for example, as a layer beneath a field emission cathode in a flat panel display; or used to control surface emissivity, for example, as a coating on an insulating material such as vertical wall supports in flat panel displays.

Jankowski, Alan F. (Livermore, CA); Schmid, Anthony P. (Solan Beach, CA)

2002-01-01T23:59:59.000Z

252

Cr(VI) reduction in aqueous solutions by using copper smelter slag  

SciTech Connect (OSTI)

The ability of Copper Smelter Slag (CSS) to reduce Cr(VI) in aqueous solutions has been investigated. The extent of reduction if dependent on the amounts of acid and reductant, contact time, Cr(VI) concentration, temperature of the solution and particle size of CSS. The amount of acid is the most important variable affecting the reduction process. When twice the amount of acid required with respect to Cr(VI) was used, Cr(VI) in 100 ml solution (100 mg/l) was completely reduced in a contact period less than 5 min by a 10 g/l dosage of CSS. Reduction efficiency increased with increase in temperature of solution, showing that the process is endothermic. Reduced chromium, and iron and other metals dissolved from CSS were effectively precipitated by using NaOH or calcinated carbonation sludge from sugar plant.

Kiyak, B.; Oezer, A.; Altundogan, H.S.; Erdem, M.; Tuemen, F. (Firat Univ., Elazig (Turkey))

1999-01-01T23:59:59.000Z

253

Cr(VI) reduction in aqueous solutions by using copper smelter slag  

SciTech Connect (OSTI)

The ability of Copper Smelter Slag (CSS) to reduce Cr(VI) in aqueous solutions has been investigated. The extent of reduction if dependent on the amounts of acid and reductant, contact time, Cr(VI) concentration, temperature of the solution and particle size of CSS. The amount of acid is the most important variable affecting the reduction process. When twice the amount of acid required with respect to Cr(VI) was used, Cr(VI) in 100 ml solution (100 mg/l) was completely reduced in a contact period less than 5 min by a 10 g/l dosage of CSS. Reduction efficiency increased with increase in temperature of solution, showing that the process is endothermic. Reduced chromium, and iron and other metals dissolved from CSS were effectively precipitated by using NaOH or calcinated carbonation sludge from sugar plant.

Kiyak, B.; Oezer, A.; Altundogan, H.S.; Erdem, M.; Tuemen, F. [Firat Univ., Elazig (Turkey)] [Firat Univ., Elazig (Turkey)

1999-11-01T23:59:59.000Z

254

Microstructures of Metallic NiCrBSi Coatings Manufactured via Hybrid Plasma Spray  

E-Print Network [OSTI]

, nanoindentation, NiCrBSi, plasma-laser hybrid process, scratch testing 1. Introduction Electrodeposited hard, uniform microstructure, high hardness, and highly adhesive bonding to the substrate (Ref 8). Nickel

Paris-Sud XI, Université de

255

Electronic Structure of CrN: from Macro to Nano | Argonne National...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electronic Structure of CrN: from Macro to Nano January 28, 2015 11:00AM to 12:00PM Presenter Antia Sanchez Botana, University of California, Davis Location Building 223, Room S105...

256

A few-cycle Cr??:YAG laser and optical studies of photonic crystals  

E-Print Network [OSTI]

A prismless Cr4+:YAG laser was used to generate 20 fs pulses at 1450 nm with a bandwidth of 190 nm FWHM. Intracavity group velocity dispersion was compensated with double-chirped mirrors. Pulse spectrum was observable from ...

Ripin, Daniel Jacob, 1973-

2002-01-01T23:59:59.000Z

257

CORROSION OF Fe-10Al-Cr ALLOYS BY COAL CHAR  

E-Print Network [OSTI]

Potent.ials Encountered in Coal Conversion Systems", NASA TNof Illinois #6 ash and coal char. Figure 1. Cross sectionsof Fe-lOAl-Cr Alloys by Coal Char B. A. Gordon and V.

Gordon, B.A.

2011-01-01T23:59:59.000Z

258

Peer Reviewed Publications 7 October 2011 41 Chilson, PB, WF Frick, JF Kelly, KW Howard, RP Larkin, RH Diehl, JK Westbrook, TA  

E-Print Network [OSTI]

Peer Reviewed Publications 7 October 2011 41 Chilson, PB, WF Frick, JF Kelly, KW Howard, RP Larkin, RH Diehl, JK Westbrook, TA Kelly, TH Kunz. In Press. Partly cloudy with a chance of migration, MS Bowlin, PB Chilson, RH Diehl, RW Fléron, P Hartl, R Kays, JF Kelly, WD Robinson, M Wikelski. 2011

Kelly, Jeff

259

R E S E A R C H L E T T E R Toxin^antitoxin (TA) systems are prevalent and transcribed  

E-Print Network [OSTI]

problematic hospital and community- acquired pathogens are methicillin-resistant Staphylococcus aureus (MRSA bacteria; however, the prevalence and identity of TA systems in clinical isolates of MRSA and PA has not been defined. We isolated DNA from 78 MRSA and 42 PA clinical isolates and used PCR to probe

Hergenrother, Paul J.

260

Activation cross sections of $?$-particle induced nuclear reactions on hafnium and deuteron induced nuclear reaction on tantalum: production of $^{178}$W/$^{178m}$Ta generator  

E-Print Network [OSTI]

In the frame of a systematic study of charged particle production routes of medically relevant radionuclei, the excitation function for indirect production of $^{178m}$Ta through $^{nat}$Hf($\\alpha$,xn)$^{178}$W-$^{178m}$Ta nuclear reaction was measured for the first time up to 40 MeV. In parallel, the side reactions $^{nat}$Hf($\\alpha$,x)$^{179,177,176,175}$W, $^{183,182,178g,177,176,175}$Ta, $^{179m,177m,175}$Hf were also assessed. Stacked foil irradiation technique and $\\gamma$-ray spectrometry were used. New experimental cross section data for the $^{nat}$Ta(d,xn)$^{178}$W reaction are also reported up to 40 MeV. The measured excitation functions are compared with the results of the ALICE-IPPE, and EMPIRE nuclear reaction model codes and with the TALYS 1.4 based data in the TENDL-2013 library. The thick target yields were deduced and compared with yields of other charged particle ((p,4n), (d,5n) and ($^3$He,x)) production routes for $^{178}$W.

F. Tárk'anyi; S. Tak'acs; F. Ditrói; A. Hermanne; A. V. Ignatyuk; M. S. Uddin

2014-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Synthesis, Exfoliation, and Electronic/Protonic Conductivity of the Dion-Jacobson Phase Layer Perovskite HLa2TiTa2O10  

E-Print Network [OSTI]

Synthesis, Exfoliation, and Electronic/Protonic Conductivity of the Dion-Jacobson Phase Layer-based method. When prepared by the precursor method, HLa2Ti2TaO10·nH2O (n = 1-2) could be exfoliated

262

Proton-Conducting Films of Nanoscale Ribbons Formed by Exfoliation of the Layer Perovskite H2SrTa2O7  

E-Print Network [OSTI]

Proton-Conducting Films of Nanoscale Ribbons Formed by Exfoliation of the Layer Perovskite H2SrTa2OTa2O7 were grown and characterized as solid-state proton conductors. The ribbons, made by exfoliation membranes made from layered materials such as exfoliated zirconium phosphate.12 Unfortunately, the proton

263

Page 6 T H E E N V I R O N M E N TA L F O R U M Managing Water Demand  

E-Print Network [OSTI]

Page 6 T H E E N V I R O N M E N TA L F O R U M Managing Water Demand: Price vs. Non to the effective management of water systems. Even green solutions or low-impact development techniques that seek-efficientfixturesanddrought- resistant plantings. "Water management has typically been approached as an engineering problem, rather than

Shapiro, Benjamin

264

Surface modification to improve fireside corrosion resistance of Fe-Cr ferritic steels  

DOE Patents [OSTI]

An article of manufacture and a method for providing an Fe--Cr ferritic steel article of manufacture having a surface layer modification for corrosion resistance. Fe--Cr ferritic steels can be modified to enhance their corrosion resistance to liquid coal ash and other chemical environments, which have chlorides or sulfates containing active species. The steel is modified to form an aluminide/silicide passivating layer to reduce such corrosion.

Park, Jong-Hee (Clarendon Hills, IL); Natesan, Krishnamurti (Naperville, IL); Rink, David L. (Mokena, IL)

2010-03-16T23:59:59.000Z

265

Heat treatment of NiCrFe alloy to optimize resistance to intergrannular stress corrosion  

DOE Patents [OSTI]

A process of producing a NiCrFe alloy having a high resistance to stress corrosion cracking comprising heating a NiCrFe alloy to a temperature sufficient to enable the carbon present in the alloy body in the form of carbide deposits to enter into solution, rapidly cool the alloy body, and heat the cooled body to a temperature between 1100.degree. to 1500.degree. F. for about 1 to 30 hours.

Steeves, Arthur F. (Schenectady, NY); Bibb, Albert E. (Clifton Park, NY)

1984-01-01T23:59:59.000Z

266

Optimizing Cr(VI) and Tc(VII) remediation through nano-scale biomineral engineering  

SciTech Connect (OSTI)

To optimize the production of biomagnetite for the bioremediation of metal oxyanion contaminated waters, the reduction of aqueous Cr(VI) to Cr(III) by two biogenic magnetites and a synthetic magnetite was evaluated under batch and continuous flow conditions. Results indicate that nano-scale biogenic magnetite produced by incubating synthetic schwertmannite powder in cell suspensions of Geobacter sulfurreducens is more efficient at reducing Cr(VI) than either biogenic nano-magnetite produced from a suspension of ferrihydrite 'gel' or synthetic nano-scale Fe{sub 3}O{sub 4} powder. Although X-ray Photoelectron Spectroscopy (XPS) measurements obtained from post-exposure magnetite samples reveal that both Cr(III) and Cr(VI) are associated with nanoparticle surfaces, X-ray Magnetic Circular Dichroism (XMCD) studies indicate that some Cr(III) has replaced octahedrally coordinated Fe in the lattice of the magnetite. Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) measurements of total aqueous Cr in the associated solution phase indicated that, although the majority of Cr(III) was incorporated within or adsorbed to the magnetite samples, a proportion ({approx}10-15 %) was released back into solution. Studies of Tc(VII) uptake by magnetites produced via the different synthesis routes also revealed significant differences between them as regards effectiveness for remediation. In addition, column studies using a {gamma}-camera to obtain real time images of a {sup 99m}Tc(VII) radiotracer were performed to visualize directly the relative performances of the magnetite sorbents against ultra-trace concentrations of metal oxyanion contaminants. Again, the magnetite produced from schwertmannite proved capable of retaining more ({approx}20%) {sup 99m}Tc(VII) than the magnetite produced from ferrihydrite, confirming that biomagnetite production for efficient environmental remediation can be fine-tuned through careful selection of the initial Fe(III) mineral substrate supplied to Fe(III)-reducing bacteria.

Cutting, R. S.; Coker, V. S.; Telling, N. D.; Kimber, R. L.; Pearce, C. I.; Ellis, B.; Lawson, R; van der Laan, G.; Pattrick, R.A.D.; Vaughan, D.J.; Arenholz, E.; Lloyd, J. R.

2009-09-09T23:59:59.000Z

267

Event-by-event study of CR composition with the SPHERE experiment using the 2013 data  

E-Print Network [OSTI]

We present an event-by-event study of cosmic ray (CR) composition with the reflected Cherenkov light method. The fraction of CR light component above 5 PeV was reconstructed using the 2013 run data of the SPHERE experiment which observed optical Vavilov-Cherenkov radiation of extensive air showers, reflected from snow surface of Lake Baikal. Additionally, we discuss a possibility to improve the elemental groups separability by means of multidimensional criteria.

Antonov, R A; Bonvech, E A; Chernov, D V; Dzhatdoev, T A; Finger, Mich; Finger, Mir; Galkin, V I; Podgrudkov, D A; Roganova, T M

2015-01-01T23:59:59.000Z

268

PVD synthesis and high-throughput property characterization of Ni?Fe?Cr alloy libraries  

SciTech Connect (OSTI)

Three methods of alloy library synthesis, thick-layer deposition followed by interdiffusion, composition-spread codeposition and electron-beam melting of thick deposited layers, have been applied to Ni-Fe-Cr ternary and Ni-Cr binary alloys. Structural XRD mapping and mechanical characterization by means of nanoindentation have been used to characterize the properties of the libraries. The library synthesis methods are compared from the point of view of the structural and mechanical information they can provide.

Rar, A.; Frafjord, J.J.; Fowlkes, Jason D.; Specht, E.D.; Rack, P.D.; Santella, M.L.; Bei, H.; George, E.P.; Pharr, G.M. (Tennessee-K); (Tennessee-K); (ORNL)

2010-11-10T23:59:59.000Z

269

High-pressure structure of half-metallic CrO2 B. R. Maddox  

E-Print Network [OSTI]

transition from rutile -CrO2 phase I P42/mnm to orthorhombic -CrO2 phase II CaCl2-like, Pnnm is presented. The transition to the CaCl2 structure, which appears to be second order, occurs at 12±3 GPa without any typically transforms to another sixfold-coordinated structure, CaCl2, or the -PbO2 structure found in shock

Pickett, Warren

270

Microstructure and Mechanical Property Studies on Neutron-Irradiated Ferritic Fe-Cr Model Alloys  

SciTech Connect (OSTI)

Model Fe, Fe-10Cr and Fe-14Cr alloys were irradiated in Advanced Test Reactor at 300°C and 450°C to target doses of 0.01, 0.1 and 1 dpa. The microstructure and the mechanical property of irradiated specimens were investigated using TEM, APT and hardness measurements. The irradiation-induced hardening was consistent with the observed microstructures. For lower doses of 0.01 and 0.1 dpa, the formation of dislocation loops was the primarily contributor to the hardening; no a’ precipitates of resolvable sizes were observed. By 1 dpa, additional increase in hardening were attributed to the formation of a high density of 1-2 nm a' precipitates. In Fe, the hardness increased less as a function of irradiation dose compared to Fe-Cr alloys because of the lack of a' precipitation and differences in loop structures. Three single-parameter effects have been studied: the Cr content, the irradiation temperature and the grain size. The addition of Cr reduced the mobility of both ½<111> and <100> dislocation loops, leading to a smaller loop size and higher loop density. Also, the Cr contents were positively correlated to the density of a' precipitates, but were less relevant to the precipitate size. Higher irradiation temperature of 450°C resulted in a preferential production of the immobile <100> loops over the mobile ½<111> loops (ex. a ratio of 8:1 in Fe-10Cr irradiated 450°C to 0.01 dpa). At lower temperature of 300°C, heterogeneous formation of dislocation loops at the vicinity of line dislocations frequently. In Fe, the development of dislocation loops was suppressed (compared to Fe-Cr alloys) due to a combination of smaller grain size, high initial dislocation density and high defect mobility.

Jian Gan; Maria Okuniewski; Wei-Ying Chen; Yinbin Miao; Carolyn A. Tomchik; James F. Stubbins; Y. Q. Wu; Stu A. Maloy

2014-06-01T23:59:59.000Z

271

Oxidation behavior of arc evaporated Al-Cr-Si-N thin films  

SciTech Connect (OSTI)

The impact of Al and Si on the oxidation behavior of Al-Cr-(Si)-N thin films synthesized by arc evaporation of powder metallurgically prepared Al{sub x}Cr{sub 1-x} targets with x = Al/(Al + Cr) of 0.5, 0.6, and 0.7 and (Al{sub 0.5}Cr{sub 0.5}){sub 1-z}Si{sub z} targets with Si contents of z = 0.05, 0.1, and 0.2 in N{sub 2} atmosphere was studied in detail by means of differential scanning calorimetry, thermogravimetric analysis (TGA), x-ray diffraction, and Raman spectroscopy. Dynamical measurements in synthetic air (up to 1440 Degree-Sign C) revealed the highest onset temperature of pronounced oxidation for nitride coatings prepared from the Al{sub 0.4}Cr{sub 0.4}Si{sub 0.2} target. Isothermal TGA at 1100, 1200, 1250, and 1300 Degree-Sign C highlight the pronounced improvement of the oxidation resistance of Al{sub x}Cr{sub 1-x}N coatings by the addition of Si. The results show that Si promotes the formation of a dense coating morphology as well as a dense oxide scale when exposed to air.

Tritremmel, Christian; Daniel, Rostislav; Mitterer, Christian; Mayrhofer, Paul H.; Lechthaler, Markus; Polcik, Peter [Christian Doppler Laboratory for Advanced Hard Coatings, Department of Physical Metallurgy and Materials Testing, Montanuniversitaet Leoben, Franz-Josef-Strasse 18, A-8700 Leoben (Austria); Christian Doppler Laboratory for Application Oriented Coating Development, Department of Physical Metallurgy and Materials Testing, Montanuniversitaet Leoben, Franz-Josef-Strasse 18, A-8700 Leoben (Austria); OC Oerlikon Balzers AG, Iramali 18, LI-9496 Balzers (Liechtenstein); PLANSEE Composite Materials GmbH, Siebenbuergerstrasse 23, D-86983 Lechbruck am See (Germany)

2012-11-15T23:59:59.000Z

272

Microstructure and Mechanical Properties of n-irradiated Fe-Cr Model Alloys  

SciTech Connect (OSTI)

High chromium ( 9-12 wt %) ferritic/martensitic steels are candidate structural materials for future fusion reactors and other advanced systems such as accelerator driven systems (ADS). Their use for these applications requires a careful assessment of their mechanical stability under high energy neutron irradiation and in aggressive environments. In particular, the Cr concentration has been shown to be a key parameter to be optimized in order to guarantee the best corrosion and swelling resistance, together with the least embrittlement. In this work, the characterization of the neutron irradiated Fe-Cr model alloys with different Cr % with respect to microstructure and mechanical tests will be presented. The behavior of Fe-Cr alloys have been studied using tensile tests at different temperature range ( from -160 deg. C to 300 deg. C). Irradiation-induced microstructure changes have been studied by TEM for two different irradiation doses at 300 deg. C. The density and the size distribution of the defects induced have been determined. The tensile test results indicate that Cr content affects the hardening behavior of Fe-Cr binary alloys. Hardening mechanisms are discussed in terms of Orowan type of approach by correlating TEM data to the measured irradiation hardening. (authors)

Matijasevic, Milena; Al Mazouzi, Abderrahim [Reactor materials research, SCK-CEN, Mol (Belgium)

2008-07-01T23:59:59.000Z

273

http://www-db.in.tum.de/research/projects/StreamGlobe Optimization Techniques  

E-Print Network [OSTI]

: Redundant transmission of data streams Redundant execution of stream transforming operators Transmissionhttp://www-db.in.tum.de/research/projects/StreamGlobe Optimization Techniques: In-network query processing o Distribute query processing operators in the network (query shipping) o Early filtering

Kemper, Alfons

274

Electromagnetic interference shielding reaching 70 dB in steel fiber cement  

E-Print Network [OSTI]

Electromagnetic interference shielding reaching 70 dB in steel fiber cement Sihai Wen, D.D.L. Chung; Silica fume; Shielding 1. Introduction Electromagnetic interference (EMI) shielding [1­4] is in critical, NY 14260-4400, USA Received 9 January 2002; accepted 14 August 2003 Abstract An electromagnetic

Chung, Deborah D.L.

275

MvirDB: Microbial Database of Protein Toxins, Virulence Factors and Antibiotic Resistance Genes for Bio-Defense Applications  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

MvirDB is a cenntralized resource (data warehouse) comprising all publicly accessible, organized sequence data for protein toxins, virulence factors, and antibiotic resistance genes. Protein entries in MvirDB are annotated using a high-throughput, fully automated computational annotation system; annotations are updated periodically to ensure that results are derived using current public database and open-source tool releases. Tools provided for using MvirDB include a web-based browser tool and BLAST interfaces. MvirDB serves researchers in the bio-defense and medical fields. (taken from page 3 of PI's paper of same title published in Nucleic Acids Research, 2007, Vol.35, Database Issue (Open Source)

Zhou, C. E.; Smith, J.; Lam, M.; Zemla, M. D.; Slezak, T.

276

Detection of charge transfer processes in Cr-doped SrTiO{sub 3} single crystals  

SciTech Connect (OSTI)

An insulator-to-metal transition is observed in Cr-doped SrTiO{sub 3} single crystals upon extended exposure to a high electric field, namely, electroconditioning (EC). Electron paramagnetic resonance (EPR) and transport measurements under laser irradiation show anticorrelation between the Cr{sup 3+} EPR signal and the electrical current. This proves that the Cr{sup 3+} ions are responsible for the photocurrent that initiates the EC process. We observe the presence of Cr{sup 3+}/Cr{sup 4+} mixed valencies in the bulk in the conducting state. The EPR characterization of the spectra in the conducting state excludes the possibility of a Cr{sup 3+}-oxygen vacancy complex in the bulk as a result of the EC.

La Mattina, F. [Physik-Institut der Universitaet Zuerich, Winterthurerstr. 190, CH-8057 Zuerich (Switzerland); IBM Research, Zurich Research Laboratory, Saeumerstr. 4, CH-8803 Rueschlikon (Switzerland); Bednorz, J. G.; Alvarado, S. F. [IBM Research, Zurich Research Laboratory, Saeumerstr. 4, CH-8803 Rueschlikon (Switzerland); Shengelaya, A. [Physics Institute of Tbilisi State University, Chavchavadze 3, GE-0128, Tbilisi (Georgia); Keller, H. [Physik-Institut der Universitaet Zuerich, Winterthurerstr. 190, CH-8057 Zuerich (Switzerland)

2008-07-14T23:59:59.000Z

277

Comparative studies of etching mechanisms of CR-39 in NaOH/H2O and NaOH/ethanol  

E-Print Network [OSTI]

Comparative studies of etching mechanisms of CR-39 in NaOH/H2O and NaOH/ethanol K.C.C. Tse, D Avenue, Kowloon Tong, Hong Kong Available online 13 May 2007 Abstract The bulk etch rate for CR-39 in NaOH/ethanol accumulates on the surface of CR-39 detector during etching in NaOH/ethanol, which is absent during etching

Yu, K.N.

278

Void swelling in binary Fe-Cr alloys at 200 dpa  

SciTech Connect (OSTI)

Microstructural examinations have been performed on a series of binary Fe-Cr alloys irradiated in the FFTF/MOTA at 425{degrees}C to 200 dpa. The data represent the highest swelling levels reported in neutron irradiated ferritic alloys. The alloy compositions ranged from 3% to 18% Cr in 3% Cr increments, and the irradiation temperature corresponded to the peak swelling condition for this alloy class. Density measurements showed swelling levels as high as 7.4%, with the highest swelling found in the Fe-9Cr and Fe-6Cr alloys. Microstructural examinations revealed that the highest swelling conditions contained well-developed voids, often as large as 100 nm, and a dislocation network comprised of both a/2<111> and a<100> Burgers vectors. Swelling was lower in the other alloys, and the swelling reduction could be correlated with increased precipitation. These results are considered in light of the current theories for low swelling in ferritic alloys, but no theory is available to completely explain the results.

Gelles, D.S. [Pacific Northwest Lab., Richland, WA (United States)

1994-09-01T23:59:59.000Z

279

Void swelling in binary Fe-Cr alloys at 200 DPA  

SciTech Connect (OSTI)

Microstructural examinations have been performed on a series of binary Fe-Cr alloys irradiated in the FFTF/MOTA at 425C to 200 dpa. The data represent the highest swelling levels reported in neutron irradiated ferritic alloys. The alloy compositions ranged from 3 to 18% Cr in 3% Cr increments, and the irradiation temperature corresponded to the peak swelling condition for this alloy class. Density measurements showed swelling levels as high as 7.4%, with the highest swelling found in the Fe-9Cr and Fe-6Cr alloys. Microstructural examinations revealed that the highest swelling conditions contained well-developed voids, often as large as 100 nm, and a dislocation network comprised of both {sub 2}{sup a}<111> and a<100> Burgers vectors. Swelling was lower in the other alloys, and the swelling reduction could be correlated with increased precipitation. These results are considered in light of current theories for low swelling in ferritic alloys, but no theory is available to completely explain the results.

Gelles, D.S.

1994-06-01T23:59:59.000Z

280

Reduced-activation austenitic stainless steels: The Fe--Mn--Cr--C system  

SciTech Connect (OSTI)

Nickel-free manganese-stabilized steels are being developed for fusion-reactor applications. As the first part of this effort, the austenite-stable region in the Fe--Mn--Cr--C system was determined. Results indicated that the Schaeffler diagram developed for Fe--Ni--Cr--C alloys cannot be used to predict the constituents expected for high-manganese steels. This is true because manganese is not as strong an austenite stabilizer relative to delta-ferrite formation as predicted by the diagram, but it is a stronger austenite stabilizer relative to martensite than predicted. Therefore, the austenite-stable region for Ne--Mn--Cr--C alloys occurs at lower chromium and hugher combinations of manganese and carbon than predicted by the Schaeffler diagram. Development of a manganese-stabilized stainless steel should be possible in the composition range of 20 to 25% Mn, 10 to 15% Cr, and 0.01 to 0.25%C. Tensile behavior of an Fe--20%Mn--12%Cr--0.25%C alloy was determined. The strength and ductility of this possible base composition was comparable to type 316 stainless steel in both the solution-annealed and cold-worked condition.

Klueh, R.L.; Maziasz, P.J.

1988-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Recent developments in Cr{sup 2+}-doped II-VI compound lasers  

SciTech Connect (OSTI)

Transition-metal-doped zinc chalcogenide crystals have recently been investigated as potential mid-IR lasers. Tetrahedrally-coordinated Cr{sup 2+} ions are especially attractive as lasants on account of high luminescence quantum yields for emission in the 2000-3000 nm range. {sup 5}E radiative lifetimes and emission cross sections are respectively {approximately}10 {mu}sec and {approximately}10{sup -18} cm{sup 2}. The associated absorption band peaked at {approximately}1800 nm enables laser-diode pumping of the Cr{sup 2+} systems. Laser demonstrations with ZnS:Cr and ZnSe:Cr (using a MgF{sub 2}:Co{sup 2+} laser pump source) gave slope efficiencies up to 30%. Excited-state-absorption losses appear small, and passive losses dominate. Tuning experiments with a birefringent filter evidence a tuning range covering at least 2280 - 2530 nm. Cr-doped laser samples can be produced by Bridgman growth, seeded physical vapor transport, or diffusion doping.

Page, R.H.; DeLoach, L.D.; Schaffers, K.I., Patel, F.D.; Beach, R.J.; Payne, S.A.; Krupke, W.F. [Lawrence Livermore National Lab., CA (United States); Burger, A. [Fisk Univ., Nashville, TN (United States). Center for Photonic Materials and Devices

1996-09-01T23:59:59.000Z

282

Visible Light-Driven Water Oxidation by Ir oxide Clusters Coupledto Single Cr Centers in Mesoporous Silica  

SciTech Connect (OSTI)

Visible light-induced water oxidation has been demonstrated at an Ir oxide nanocluster coupled to a single Cr{sup VI} site on the pore surface of MCM-41 mesoporous silica. The photocatalytic unit was assembled by the reaction of surface Cr=O groups with Ir(acac){sub 3} precursor followed by calcination at 300 C and bond formation monitored by FT-Raman and FT-IR spectroscopy. High-resolution Z-contrast electron micrographs of the calcined material combined with energy-dispersive X-ray spot analysis confirmed the occlusion of Ir oxide nanoparticles inside the mesopores. Oxygen evolution of an aqueous suspension of the Ir{sub x}O{sub y}-CrMCM-41 upon visible light irradiation of the Cr{sup VI}-O ligand-to-metal charge-transfer absorption was monitored mass-spectrometrically. Comparison of the product yields for samples with low Cr content (Cr/Si {le} 0.02) and high Cr content (Cr/Si = 0.05) indicates that only isolated Cr centers are capable of extracting electrons from Ir oxide clusters, while di- or polychromate species are not. Water oxidation at a multielectron-transfer catalyst coupled to a single metal center has not been demonstrated before. The ability to drive water oxidation with a single metal center as electron pump offers opportunities for coupling the oxygen-evolving photocatalytic unit to reducing sites in the nanoporous scaffold.

Nakamura, Ryuhei; Frei, Heinz

2006-07-10T23:59:59.000Z

283

Reduction of Cr(VI) under acidic conditions by the facultative Fe(III)-reducing bacterium Acidiphilium cryptum  

SciTech Connect (OSTI)

The potential for biological reduction of Cr(VI) under acidic conditions was evaluated with the acidophilic, facultatively metal-reducing bacterium Acidiphilium cryptum strain JF-5 to explore the role of acidophilic microorganisms in the Cr cycle in low-pH environments. An anaerobic suspension of washed A. cryptum cells rapidly reduced 50 M Cr(VI) at pH 3.2; biological reduction was detected from pH 1.7-4.7. The reduction product, confirmed by XANES analysis, was entirely Cr(III) that was associated predominantly with the cell biomass (70-80%) with the residual residing in the aqueous phase. Reduction of Cr(VI) showed a pH optimum similar to that for growth and was inhibited by 5 mM HgCl2, suggesting that the reaction was enzyme-mediated. Introduction of O2 into the reaction medium slowed the reduction rate only slightly, whereas soluble Fe(III) (as ferric sulfate) increased the rate dramatically, presumably by the shuttling of electrons from bioreduced Fe(II) to Cr(VI) in a coupled biotic-abiotic cycle. Starved cells could not reduce Cr(VI) when provided as sole electron acceptor, indicating that Cr(VI) reduction is not an energy-conserving process in A. cryptum. We speculate, rather, that Cr(VI) reduction is used here as a detoxification mechanism.

David E. Cummings; Scott Fendorf; Rajesh K. Sani; Brent M. Peyton; Timothy S. Magnuson

2007-01-01T23:59:59.000Z

284

Dissimilar-weld failure analysis and development. Comparative behavior of similar and dissimilar welds. Final report. [Welds of 2-1/4Cr-1Mo to 2-1/4Cr-1Mo using 2-1/4Cr-1Mo filler material; and austenitic to ferritic steel welds made by fusion welding alloy-800H to 2-1/4Cr-1Mo using nickel base filler metal ERNiCr-3  

SciTech Connect (OSTI)

The 593/sup 0/C (1100/sup 0/F) stress rupture behavior of similar metal welds (SMWs) and dissimilar metal welds (DMWs) was investigated under cyclic load and cyclic temperature conditions to provide insight into the question, ''Why do DMWs fail sooner than SMWs in the fossil fuel boilers.'' The weld joints of interest were an all ferritic steel SMW made by fusion welding 2-1/4Cr-1Mo to 2-1/4Cr-1Mo using 2-1/4Cr-1Mo filler metal and an austenitic to ferritic steel DMW made by fusion welding Alloy-800H to 2-1/4Cr-1Mo using a nickel base filler metal ERNiCr-3. The stress rupture behavior obtained on cross weld specimens was similar for both types of welds with only a 20% reduction in rupture life for the DMW. For rupture times less than 1500 hours, failures occurred in the 2-1/4Cr-1Mo base metal whereas, for rupture times greater than 1500 hours, failures occurred in the 2-1/4Cr-1Mo heat affected zone (HAZ). The HAZ failures exhibited a more brittle appearance than the base metal failures for both types of welds and it appears that the life of both joints was limited by the stress rupture properties of the HAZ. These results support the hypothesis that increased residual stresses due to abrupt changes in hardness (strength) of metals involved are the major contributors to the reduction in life of DMWs as compared to SMWs. 10 refs., 15 figs., 7 tabs.

Busboom, H.; Ring, P.J.

1986-07-01T23:59:59.000Z

285

CrRb: A molecule with large magnetic and electric dipole moments  

SciTech Connect (OSTI)

We report calculations of Born-Oppenheimer potential energy curves of the chromium-rubidium heteronuclear molecule ({sup 52}Cr{sup 87}Rb), and the long-range dispersion coefficient for the interaction between ground state Cr and Rb atoms. Our calculated van der Waals coefficient (C{sub 6}=1770 a.u.) has an expected error of 3%. The ground state {sup 6{Sigma}+} molecule at its equilibrium separation has a permanent electric dipole moment of d{sub e}(R{sub e}=3.34Angstrom)=2.90 D. We investigate the hyperfine and dipolar collisions between trapped Cr and Rb atoms, finding elastic to inelastic cross section ratio of 10{sup 2}-10{sup 3}.

Pavlovic, Z. [ITAMP, Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, Massachusetts 02138 (United States); Department of Physics, University of Connecticut, Storrs, Connecticut 06269-3046 (United States); Sadeghpour, H. R. [ITAMP, Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, Massachusetts 02138 (United States); Cote, R. [Department of Physics, University of Connecticut, Storrs, Connecticut 06269-3046 (United States); Roos, B. O. [Department of Theoretical Chemistry, University of Lund, S-221 00 Lund (Sweden)

2010-05-15T23:59:59.000Z

286

Testing of welded 13% Cr grades martensitic stainless steels for sour service applications  

SciTech Connect (OSTI)

The application of 13% Cr grade stainless steels is increasing mainly due to the introduction of higher alloyed and weldable grades with carbon content as low as 0.01 %, and the very favorable costs compared to alternative materials as the 22Cr duplex stainless steel. Therefore these steels now have been subject to a major evaluation for transport of oil and gas offshore in the North Sea. This paper discusses aspects of testing required to assess their corrosion properties and their susceptibility to environment assisted cracking (EAC), caused by both H{sub 2}S internally and cathodic protection externally. Testing is discussed with emphasis on test parameters for welded 13% Cr steel using different types of consumables.

Rogne, T.; Bjordal, M. [SINTEF Materials Technology, Trondheim (Norway)

1997-08-01T23:59:59.000Z

287

The Effect of Water Vapor on Cr Depletion in Advanced Recuperator Alloys  

SciTech Connect (OSTI)

Durable alloy foils are needed for gas turbine recuperators operating at 650--700 C. It has been established that water vapor in the exhaust gas causes more rapid consumption of Cr in austenitic stainless steels leading to a reduction in operating lifetime of these thin-walled components. Laboratory testing at 650--800 C of commercial and model alloys is being used to develop a better understanding of the long-term rate of Cr consumption in these environments. Results are presented for commercial alloys 709, 120 and 625. After 10,000h exposures at 650 C and 700 C in humid air, grain boundary Cr depletion was observed near the surface of all these materials. In the Fe-base alloys, 709 and 120, this depletion led to localized Fe-rich nodule formation. This information then can be used to develop low-cost alternatives to currently available candidate materials.

Pint, Bruce A [ORNL

2005-01-01T23:59:59.000Z

288

Precipitation behavior of Ni-Cr-22 Fe-18 Mo (Hastelloy-X) and Ni-Cr-22 Co-12 Mo (Inconel-617) after isothermal aging  

SciTech Connect (OSTI)

The precipitation behavior of the nickel-base alloys Ni-Cr-22Fe-18Mo (Hastelloy-X) and Ni-Cr-22Co12Mo (Inconel-617) has been investigated as a function of aging temperature. Hastelloy-X shows that M/sub 6/C and TiN are primary precipitates and M/sub 12/C, A/sub 3/B/sub 2/ (approx. = Fe/sub 3/Mo/sub 2/), and M/sub 23/C/sub 6/ are secondary precipitates, while Inconel-617 also has M/sub 6/C and TiN as primary precipitates and M/sub 23/C/sub 6/, M/sub 12/C, and Ni/sub 3/AlTi as secondary precipitates. The characterization has been carried out by metallographic and transmission electron microscopy investigations and by x-ray examinations of electrochemical isolated precipitates.

Kirchhofer, H.; Nickel, H.; Schubert, F.

1984-07-01T23:59:59.000Z

289

Data:A01db19a-405a-45db-b4cd-4e1783be5856 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 Nod2db5b31cb44 No revision hasdb5-b05c-76b1be5a4007 Nof7ffd374e No revisionf1f306fd8 No

290

Data:8f51bf9d-0209-4db6-afb7-b2db074e9777 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 No revisione0a2d50bdf No18fed1db58-e7b51f638865 Nod57b1532a58f No revision has been approved

291

/sup 51/Cr-EDTA: a marker of early intestinal rejection in the rat  

SciTech Connect (OSTI)

Intestinal permeability was studied after accessory intestinal transplantation in Lewis rats. Five groups were evaluated: Group 1--isografts (N = 6); Group 2--Lewis X Brown Norway F1 (LBN-F1) allografts (N = 6); Group 3--isografts treated with CsA 2 mg/kg/day X 10 days (N = 6); Group 4--LBN-F1 allografts treated with CsA 2 mg/kg/day X 10 days (N = 6); Group 5--LBN-F1 allografts treated with CsA 4 mg/kg/day X 28 days (N = 6). Chromium-labeled ethylenedimianetetraacetate (/sup 51/Cr-EDTA) was given through the proximal stoma of the graft. Renal clearance of /sup 51/Cr-EDTA and mucosal biopsies were followed post-transplant. The biopsies of the intestinal graft showed no rejection in Groups 1, 3, and 5; fulminant rejection in Group 2; and mild atypical rejection in Group 4. /sup 51/Cr-EDTA clearance was elevated in all groups during the first 7 days post-transplant. Thereafter, /sup 51/Cr-EDTA excretion fell to lower levels in the animals with histologically normal grafts (Groups 1, 3, and 5). /sup 51/Cr-EDTA excretion in Group 4 was increased with the first histological evidence of rejection on Day 14 and remained elevated until sacrifice (P less than 0.02 compared to Groups 3 and 5). A transient permeability defect occurs after intestinal grafting. Once the graft has recovered from this injury, /sup 51/Cr-EDTA is a sensitive marker for intestinal rejection.

Grant, D.; Lamont, D.; Zhong, R.; Garcia, B.; Wang, P.; Stiller, C.; Duff, J.

1989-05-01T23:59:59.000Z

292

Magnetic and electrical properties of layered magnets Tl(Cr,Mn,Co)Se{sub 2}  

SciTech Connect (OSTI)

Tl(Cr,Mn,Co)Se{sub 2} crystals were synthesized at T {approx} 1050 K. X-ray diffraction analysis showed that TlCrSe{sub 2}, TlMnSe{sub 2}, and TlCoSe{sub 2} compounds crystallize in the hexagonal crystal system with the lattice parameters: a = 3.6999 A, c = 22.6901 A, c/a {approx} 6.133, z = 3, {rho}{sub x} = 6.209 g/cm{sup 3}; a = 6.53 A, c = 23.96 A, c/a {approx} 3.669, z = 8, {rho}{sub x} = 6.71 g/cm{sup 3}; and a = 3.747 A, c = 22.772 A, c/a {approx} 6.077, z = 3, {rho}{sub x} = 7.577 g/cm{sup 3}, respectively. Magnetic and electrical studies in the temperature range from 80-400 K showed that TlCrSe{sub 2} is a semiconductor ferromagnet, TlMnSe{sub 2} is a semiconductor antiferromagnet, and TlCoSe{sub 2} is a ferrimagnet with a conductivity characteristic of metals. A rather large deviation in the experimental effective magnetic moment for TlCrSe{sub 2} (3.05 {mu}B) from the theoretical value (3.85 {mu}B) is attributed to two-dimensional magnetic ordering in the paramagnetic region of the noticeably layered ferromagnet TlCrSe{sub 2}. In TlCrSe{sub 2}, a correlation between magnetic and electrical properties was detected.

Veliyev, R. G.; Sadikhov, R. Z.; Kerimova, E. M., E-mail: ekerimova@physics.ab.az; Asadov, Yu. G.; Jabbarov, A. I. [National Academy of Sciences of Azerbaijan, Institute of Physics (Azerbaijan)

2009-02-15T23:59:59.000Z

293

Implementing waste minimization at an active plutonium processing facility: Successes and progress at technical area (TA) -55 of the Los Alamos National Laboratory  

SciTech Connect (OSTI)

The Los Alamos National Laboratory has ongoing national security missions that necessitate increased plutonium processing. The bulk of this activity occurs at Technical Area -55 (TA-55), the nations only operable plutonium facility. TA-55 has developed and demonstrated a number of technologies that significantly minimize waste generation in plutonium processing (supercritical CO{sub 2}, Mg(OH){sub 2} precipitation, supercritical H{sub 2}O oxidation, WAND), disposition of excess fissile materials (hydride-dehydride, electrolytic decontamination), disposition of historical waste inventories (salt distillation), and Decontamination & Decommissioning (D&D) of closed nuclear facilities (electrolytic decontamination). Furthermore, TA-55 is in the process of developing additional waste minimization technologies (molten salt oxidation, nitric acid recycle, americium extraction) that will significantly reduce ongoing waste generation rates and allow volume reduction of existing waste streams. Cost savings from reduction in waste volumes to be managed and disposed far exceed development and deployment costs in every case. Waste minimization is also important because it reduces occupational exposure to ionizing radiation, risks of transportation accidents, and transfer of burdens from current nuclear operations to future generations.

Balkey, J.J.; Robinson, M.A.; Boak, J.

1997-12-01T23:59:59.000Z

294

C O N TA C T > Lee Ann Ciarlette | 630.252.4835 | leeann@anl.gov | Nuclear Engineering Division | students.ne.anl.gov Argonne National Laboratory, 9700 South Cass Avenue, Lemont, IL 60439 November 2012  

E-Print Network [OSTI]

C O N TA C T > Lee Ann Ciarlette | 630.252.4835 | leeann@anl.gov | Nuclear Engineering Division of Massachuse s Lowell · University of Michigan · University of Michigan, Ann Arbor · University of Missouri

Kemner, Ken

295

Toughness of Cr-Mo-V steels for steam-turbine rotors  

SciTech Connect (OSTI)

Cr-Mo-V steels are used extensively as the rotor material in the High Pressure and Intermediate Pressure Sections of modern steam turbines. The toughness of these rotors has a major influence on the reliability and efficiency of the turbine and the overall economy of operation and maintenance of the plant. The metallurgical factors affecting the toughness of the rotors and the methods to improve the toughness are now understood better than ever before. This paper will present a broad overview of the materials and design aspects of the toughness of Cr-Mo-V rotors with emphasis on the salient results of recent research programs aimed at improving their toughness.

Viswanathan, R.; Jaffee, R.I.

1982-04-01T23:59:59.000Z

296

Repassivation of 13% Cr steel dependent on brine pH  

SciTech Connect (OSTI)

A joint laboratory project, involving an oil production and oil well service company, investigated repassivation of martensitic 13% Cr steel. The rate at which this alloy is repassivated after losing its protective passive oxide layer to hydrochloric acid (HCI) depended on the pH of the spent acid returns. Test samples of 13% Cr cut from oilfield tubing were subjected to a fluid sequence of (1) initial brine, (2) HCI, (3) spent acid, and (4) final brine. In 9 days, the samples regained their passive oxide layers. When spent acid was taken out of the fluid sequence, the samples regained passive oxide layers in 3 days.

Skogsberg, J.W.; Walker, M.L.

2000-02-01T23:59:59.000Z

297

Can one identify the intrinsic structure of the yrast states in $^{48}$Cr after the backbending?  

E-Print Network [OSTI]

The backbending phenomenon in $^{48}$Cr has been investigated using the recently developed Projected Configuration Interaction (PCI) method, in which the deformed intrinsic states are directly associated with shell model (SM) wavefunctions. Two previous explanations, (i) $K=0$ band crossing, and (ii) $K=2$ band crossing have been reinvestigated using PCI, and it was found that both explanations can successfully reproduce the experimental backbending. The PCI wavefunctions in the pictures of $K=0$ band crossing and $K=2$ band crossing are highly overlapped. We conclude that there are no unique intrinsic states associated with the yrast states after backbending in $^{48}$Cr.

Gao, Zao-Chun; Chen, Y S; Chen, Y J; Tuya,

2010-01-01T23:59:59.000Z

298

Can one identify the intrinsic structure of the yrast states in $^{48}$Cr after the backbending?  

E-Print Network [OSTI]

The backbending phenomenon in $^{48}$Cr has been investigated using the recently developed Projected Configuration Interaction (PCI) method, in which the deformed intrinsic states are directly associated with shell model (SM) wavefunctions. Two previous explanations, (i) $K=0$ band crossing, and (ii) $K=2$ band crossing have been reinvestigated using PCI, and it was found that both explanations can successfully reproduce the experimental backbending. The PCI wavefunctions in the pictures of $K=0$ band crossing and $K=2$ band crossing are highly overlapped. We conclude that there are no unique intrinsic states associated with the yrast states after backbending in $^{48}$Cr.

Zao-Chun Gao; Mihai Horoi; Y. S. Chen; Y. J. Chen; Tuya

2010-08-02T23:59:59.000Z

299

Microstructure and High Temperature Oxidation Behavior of Cr-W Alloys  

SciTech Connect (OSTI)

Cr alloys containing 0-30%W by weight were investigated for use in elevated temperature applications. The alloys were melted in a water-cooled, copper-hearth arc furnace. Microstructure of the alloys was characterized using x-ray diffraction, scanning electron microscopy, and light microscopy. A pseudocyclic oxidation test was employed to study scale formation at 1000ºC in dry air. The scale was predominantly chromia and spalled upon cooling. Alloying with aluminum up to 8 weight percent reduced the spalling drastically. Furthermore, aluminizing the surface of the Cr-W alloys completely stopped the spalling.

Dogan, O.N.

2007-02-01T23:59:59.000Z

300

Anodonta imbecillis QA Test 4, Clinch River - Environmental restoration program (CR-ERP)  

SciTech Connect (OSTI)

Toxicity testing of split whole sediment samples using juvenile freshwater mussels (Anodonta imbecillis) was conducted by TVA to provide a quality assurance mechanism for test organism quality and overall performance of the test being conducted by CR-ERP personnel as part of the CR-ERP biomonitoring study of Clinch River sediments. Testing of sediment samples collected September 8 from Poplar Creek Miles 6.0 and 1.0 was conducted September 13-22, 1994. Results from this test showed no toxicity (survival effects) to fresh-water mussels during a 9-day exposure to the sediments.

Simbeck, D.J.

1997-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Audit Report: CR-B-97-01 | Department of Energy  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energyon ArmedWaste andAccess to OUO AccessOpportunity | Department7-26CR-B-95-06CR-B-97-01

302

Audit Report: CR-B-99-02 | Department of Energy  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energyon ArmedWaste andAccess to OUO AccessOpportunity |Report: CR-B-97-04 AuditCR-B-99-02

303

Audit Report: CR-MA-95-02 | Department of Energy  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustionImprovement3--Logistical5/08 Attendance List from 12/05/08CR-MA-95-02 Audit Report: CR-MA-95-02

304

Synthesis, crystal structure, spectroscopic and thermal properties of [Et{sub 4}N][Ta{sub 6}Br{sub 12}(H{sub 2}O){sub 6}]Br{sub 4}.4H{sub 2}O (Et=ethyl)-A new compound with the paramagnetic [Ta{sub 6}Br{sub 12}]{sup 3+} cluster core  

SciTech Connect (OSTI)

A new hexanuclear cluster compound, [Et{sub 4}N][Ta{sub 6}Br{sub 12}(H{sub 2}O){sub 6}]Br{sub 4}.4H{sub 2}O (Et=ethyl) (1), with the paramagnetic [Ta{sub 6}Br{sub 12}]{sup 3+} cluster entity, was synthesized and characterized by elemental and TG/DTA analyses, IR and UV/Vis spectroscopy and by a single-crystal X-ray diffraction study. The presence of the paramagnetic [Ta{sub 6}Br{sub 12}]{sup 3+} unit was confirmed also by the room-temperature magnetic and EPR measurements. The compound crystallizes in the tetragonal I4{sub 1}/a space group, with a=14.299(5), c=21.241(5) A, Z=4, R{sub 1}(F)/wR{sub 2}(F{sup 2})=0.0296/0.0811. The structure contains discrete [Ta{sub 6}Br{sub 12}(H{sub 2}O){sub 6}]{sup 3+} cations with an octahedron of metal atoms edge-bridged by bromine atoms and with water molecules occupying all six terminal positions. The cluster units are positioned in the vertices of the three-dimensional (pseudo)diamond lattice. The structure shows similarities with literature reported structures of cluster compounds crystallizing in the diamond (Fd3-barm) space group. - Graphical abstract: Two interpenetrating (pseudo)diamond nets formed by packing of the paramagnetic [Ta{sub 6}Br{sub 12}(H{sub 2}O)]{sup 3+} (octahedral) and diamagnetic [Et{sub 4}N]{sup +} (spheres) cations.

Peric, Berislav, E-mail: bperic@irb.h [Ruder Boskovic Institute, Bijenicka cesta 54, 10000 Zagreb (Croatia); Jozic, Drazan [Ruder Boskovic Institute, Bijenicka cesta 54, 10000 Zagreb (Croatia); Planinic, Pavica, E-mail: planinic@irb.h [Ruder Boskovic Institute, Bijenicka cesta 54, 10000 Zagreb (Croatia); Brnicevic, Nevenka [Ruder Boskovic Institute, Bijenicka cesta 54, 10000 Zagreb (Croatia); Giester, Gerald [Institut fuer Mineralogie und Kristallographie, Universitaet Wien-Geozentrum Althanstrasse, 14, 1090 Wien (Austria)

2009-09-15T23:59:59.000Z

305

Understanding the solidification and microstructure evolution during CSC-MIG welding of Fe–Cr–B-based alloy  

SciTech Connect (OSTI)

The present is a study of the solidification and microstructure of Fe–28.2%Cr–3.8%B–1.5%Si–1.5%Mn (wt.%) alloy deposited onto a 1020 plain carbon steel substrate using the controlled short-circuit metal inert gas welding process. The as-solidified alloy was a metal matrix composite with a hypereutectic microstructure. Thermodynamic calculation based on the Scheil–Gulliver model showed that a primary (Cr,Fe){sub 2}B phase formed first during solidification, followed by an eutectic formation of the (Cr,Fe){sub 2}B phase and a body-centered cubic Fe-based solid solution matrix, which contained Cr, Mn and Si. Microstructure analysis confirmed the formation of these phases and showed that the shape of the (Cr,Fe){sub 2}B phase was irregular plate. As the welding heat input increased, the weld dilution increased and thus the volume fraction of the (Cr,Fe){sub 2}B plates decreased while other microstructural characteristics were similar. - Highlights: • We deposit Fe–Cr–B-based alloy onto plain carbon steel using the CSC-MIG process. • We model the solidification behavior using thermodynamic calculation. • As deposited alloy consists of (Cr,Fe){sub 2}B plates embedded in Fe-based matrix. • We study the effect of the welding heat input on the microstructure.

Sorour, A.A., E-mail: ahmad.sorour@mail.mcgill.ca; Chromik, R.R., E-mail: richard.chromik@mcgill.ca; Gauvin, R., E-mail: raynald.gauvin@mcgill.ca; Jung, I.-H., E-mail: in-ho.jung@mcgill.ca; Brochu, M., E-mail: mathieu.brochu@mcgill.ca

2013-12-15T23:59:59.000Z

306

Spin polarization at Fe/Cr interfaces L. Pizzagalli, M. Freyss, G. Moraitis, D. Stoeffler, C. Demangeat, and H. Dreysse  

E-Print Network [OSTI]

configuration with zero net moment of a thin Fe layer on a Cr surface due to a high step density. © 1997.g., a zero net magnetic moment of a Cr layer grown on a stepped Fe surface.6 It will be shown below how some irregularities at the interfaces. The spin-polarized electronic charge distribution was calculated by using

Bayreuther, Günther

307

Changes induced in a ZnS:Cr-based electroluminescent waveguide structure by intrinsic near-infrared laser radiation  

SciTech Connect (OSTI)

The causes of changes that occur in a thin-film electroluminescent metal-insulator-semiconductor-insulator-metal waveguide structure based on ZnS:Cr (Cr concentration of {approx}4 Multiplication-Sign 10{sup 20} cm{sup -3}) upon lasing ({lambda} Almost-Equal-To 2.6 {mu}m) and that induce lasing cessation are studied. It is established that lasing ceases because of light-scattering inhomogeneities formed in the structure and, hence, optical losses enhance. The origin of the inhomogeneities and the causes of their formation are clarified by studying the surface topology and the crystal structure of constituent layers of the samples before and after lasing. The studies are performed by means of atomic force microscopy and X-ray radiography. It is shown that a substantial increase in the sizes of grains on the surface of the structure is the manifestation of changes induced in the ZnS:Cr film by recrystallization. Recrystallization is initiated by local heating by absorbed laser radiation in existing Cr clusters and quickened by a strong electric field (>1 MV cm{sup -1}). The changes observed in the ZnS:Cr film are as follows: the textured growth of ZnS crystallites, an increase in the content of Cr clusters, and the appearance of some CrS and a rather high ZnO content. Some ways for improving the stability of lasing in the ZnS:Cr-based waveguide structures are proposed.

Vlasenko, N. A., E-mail: vlasenko@isp.kiev.ua; Oleksenko, P. F.; Mukhlyo, M. A.; Veligura, L. I. [National Academy of Sciences of Ukraine, Lashkarev Institute of Semiconductor Physics (Ukraine)] [National Academy of Sciences of Ukraine, Lashkarev Institute of Semiconductor Physics (Ukraine)

2013-08-15T23:59:59.000Z

308

USE OF MICRO X-RAY ABSORPTION SPECTROSCOPY AND DIFFRACTION TO DELINEATE Cr(VI) SPECIATION IN COPR  

SciTech Connect (OSTI)

The speciation of Cr(VI) in Cromite Ore Processing Residue was investigated by means of bulk XRD, and a combination of micro-XRF, -XAS and -XRD at the Advanced Light Source (ALS), Berkeley, CA, U.S.A.. Bulk XRD yielded one group of phases that contained explicitly Cr(VI) in their structure, Calcium Aluminum Chromium Oxide Hydrates, accounting for 60% of the total Cr(VI). Micro-analyses at ALS yielded complimentary information, confirming that hydrogarnets and hydrotalcites, two mineral groups that can host Cr(VI) in their structure by substitution, were indeed Cr(VI) sinks. Chromatite (CaCrO4) was also identified by micro-XRD, which was not possible with bulk methods due to its low content. The acquisition of micro-XRF elemental maps enabled not only the identification of Cr(VI)-binding phases, but also the understanding of their location within the matrix. This information is invaluable when designing Cr(VI) treatment, to optimize release and availability for reduction.

CHRYSOCHOOU, M.; MOON, D. H.; FAKRA, S.; MARCUS, M.; DERMATAS, D.; CHRISTODOULATOS, C.

2010-06-22T23:59:59.000Z

309

Chromium(VI) bioremoval by pseudomonas bacteria: role of microbial exudates for natural attenuation and biotreatment of Cr(VI) contamination  

SciTech Connect (OSTI)

Laboratory batch and column experiments were conducted to investigate the role of microbial exudates, e.g., exopolymeric substance (EPS) and alginic acid, on microbial Cr(VI) reduction by two different Pseudomonas strains (P. putida P18 and P. aeuroginosa P16) as a method for treating subsurface environment contaminated with Cr(VI). Our results indicate that microbial exudates significantly enhanced microbial Cr(VI) reduction rates by forming less toxic and highly soluble organo-Cr(III) complexes despite the fact Cr(III) has a very low solubility under the experimental conditions studied (e.g., pH 7). The formation of soluble organo-Cr(III) complexes led to the protection of the cells and chromate reductases from inactivation. In systems with no organic ligands, soluble organo-Cr(III) end products were formed between Cr(III) and the EPS directly released by bacteria due to cell lysis. Our results also provide evidence that cell lysis played an important role in microbial Cr(VI) reduction by Pseudomonas bacteria due to the release of constitutive reductases that intracellularly and/or extracellularly catalyzed the reduction of Cr(VI) to Cr(III). The overall results highlight the need for incorporation of the release and formation of organo-Cr(III) complexes into reactive transport models to more accurately design and monitor in situ microbial remediation techniques for the treatment of subsurface systems contaminated with Cr(VI).

Dogan, N.M.; Dodge, C.; Kantar, C.; Gulcan, S.; Yilmaz, B.C.; Mazmanci, M.A.

2011-02-14T23:59:59.000Z

310

Chromium(VI) Bioremoval by Pseudomonas Bacteria: Role of Microbial Exudates for Natural Attenuation and Biotreatment of Cr(VI) Contamination  

SciTech Connect (OSTI)

Laboratory batch and column experiments were conducted to investigate the role of microbial exudates, e.g., exopolymeric substance (EPS) and alginic acid, on microbial Cr(VI) reduction by two different Pseudomonas strains (P. putida P18 and P. aeuroginosa P16) as a method for treating subsurface environment contaminated with Cr(VI). Our results indicate that microbial exudates significantly enhanced microbial Cr(VI) reduction rates by forming less toxic and highly soluble organo-Cr(III) complexes despite the fact Cr(III) has a very low solubility under the experimental conditions studied (e.g., pH 7). The formation of soluble organo-Cr(III) complexes led to the protection of the cells and chromate reductases from inactivation. In systems with no organic ligands, soluble organo-Cr(III) end products were formed between Cr(III) and the EPS directly released by bacteria due to cell lysis. Our results also provide evidence that cell lysis played an important role in microbial Cr(VI) reduction by Pseudomonas bacteria due to the release of constitutive reductases that intracellularly and/or extracellularly catalyzed the reduction of Cr(VI) to Cr(III). The overall results highlight the need for incorporation of the release and formation of organo-Cr(III) complexes into reactive transport models to more accurately design and monitor in situ microbial remediation techniques for the treatment of subsurface systems contaminated with Cr(VI).

N Mercan Dogan; C Kantar; S Gulcan; C Dodge; B Coskun Yilmaz; M Ali Mazmanci

2011-12-31T23:59:59.000Z

311

Structural alterations in SiC as a result of Cr/sup +/ and N/sup +/ implantation  

SciTech Connect (OSTI)

Ion scattering and channeling techniques were used to study production of disorder and randomization of SiC by implantation of Cr/sup +/ and N/sup +/ at doses of up to 3 x 10/sup 16/ /cm/sup 2/ for Cr/sup +/ and 8 x 10/sup 16/ /cm/sup 2/ for N/sup +/. Experiments were designed so that the calculated damage energy profiles would be well matched for the two ion species. The results were compared for the degree of effectiveness of Cr/sup +/ and N/sup +/ in producing disorder. At higher doses, Cr/sup +/ was much more effective than N/sup +/ for a given damage energy using the same calculational method for Cr/sup +/ as for N/sup +/. In correlated studies of swelling, both species had about the same effectiveness in producing swelling.

Williams, J.M.; McHargue, C.J.; Appleton, B.R.

1982-01-01T23:59:59.000Z

312

Study of hydrogen and carbon monoxide adsorption on modified Zn/Cr catalysts by adsorption calorimetry  

SciTech Connect (OSTI)

Differential heat of adsorption (q) of hydrogen (a) and carbon monoxide (b) as a function of the adsorbed amount (a) on Zn/Cr catalysts at 463/sup 0/K; 1) unpromoted catalyst, 2) catalyst promoted with 2.5% of K/sub 2/O.

Yoshin, S.V.; Klyacho, A.L.; Kondrat'ev, L.T.; Leonov, V.E.; Skripchenko, G.B.; Sushchaya, L.E.

1986-08-01T23:59:59.000Z

313

AN OBATA-TYPE THEOREM IN CR GEOMETRY SONG-YING LI AND XIAODONG WANG  

E-Print Network [OSTI]

AN OBATA-TYPE THEOREM IN CR GEOMETRY SONG-YING LI AND XIAODONG WANG Abstract. We discuss a sharp. 1 #12;2 SONG-YING LI AND XIAODONG WANG the proof of the Bochner formula in [G]. Due to this error

Wang, Xiaodong

314

G. J. Snyder Page 1 of 6 THERMOELECTRIC PROPERTIES OF CR3S4-TYPE SELENIDES  

E-Print Network [OSTI]

devices depends primarily on increasing the figure of merit, ZT, for thermoelectric materials. The figure thermoelectric materials is to search for semiconductors with low lattice thermal conductivity. In this paper we lower than the state-of-the-art thermoelectric material, Bi2Te3 alloys. The structure of Cr3S4 (Figure 1

315

Limitations for the application of 13Cr steel in oil and gas production environments  

SciTech Connect (OSTI)

A laboratory investigation of application limits of 13Cr steel was carried out for sweet downhole environments in the CO{sub 2} partial pressure regime up to about 10 bar (1 MPa). Two grades of 13Cr steel were studied, one complying with the API 5CT specification and the other a higher carbon version. Polarization curves, taken at various times after immersion of the specimens in simulated brine, revealed an increasing pitting tendency for the higher chloride levels and indicated better performance for the API 5CT grade. This was in agreement with evidence for chromium depleted zones in the higher carbon grade, obtained from polarization curves in sulfuric acid. Weight loss exposure tests, in which the corrosion rate was also monitored by polarization resistance measurements, were performed at temperatures of 100 and 125 C and supplemented with literature data to extend the temperature range. A mathematical formula was derived to describe the corrosion rate as a function of temperature and chloride content. For instance, if 0.1 mm/y is taken as an acceptable corrosion rate, 13Cr steel could be applied up to 125 C in the presence of 150 g/L Cl{sup {minus}}. In the exposure tests, the API 5CT 13Cr steel did not show pitting at the 0.1 mm/y boundary but the higher carbon grade did suffer from this form of attack.

Huizinga, S.; Liek, W.E. [Shell International Oil Products BV, Amsterdam (Netherlands). Shell Research and Technology Centre

1997-08-01T23:59:59.000Z

316

Comparison of SEM and Optical Analysis of DT Neutron Tracks in CR-39 Detectors  

SciTech Connect (OSTI)

A solid state nuclear track detector, CR-39, was exposed to DT neutrons. After etching, the resultant tracks were analyzed using both an optical microscope and a scanning electron microscope (SEM). In this communication, both methods of analyzing DT neutron tracks are discussed.

P.A. Mosier-Boss, L.P.G. Forsley, P. Carbonnelle, M.S. Morey, J.R. Tinsley, J. P. Hurley, F.E. Gordon

2012-01-01T23:59:59.000Z

317

Transmission electron microscopy of oxide development on 9Cr ODS steel in supercritical water  

E-Print Network [OSTI]

Transmission electron microscopy of oxide development on 9Cr ODS steel in supercritical water A strengthened ferritic steel alloys during exposure to 600 °C supercritical water for 2- and 4-weeks were cladding include austenitic stainless steels, solid solution and precipitation-hardened alloys, ferritic

Motta, Arthur T.

318

Magnetic anisotropy in Fe-25Cr-12Co-1Si alloy induced by external magnetic field  

E-Print Network [OSTI]

Magnetic anisotropy in Fe-25Cr-12Co-1Si alloy induced by external magnetic field ZHEN Liang( )1 of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150001, China; 2. Department 27599-3255, USA Received 29 June 2006; accepted 15 January 2007 Abstract: Structural and magnetic

Qin, Lu-Chang

319

Oxidation resistance of 9-12% Cr steels: effect of rare earth surface treatment  

SciTech Connect (OSTI)

Medium Cr steels have been used in fossil fired power plants for many years because of their excellent high temperature stability and mechanical properties. The environment in a fossil fired power plant is extremely aggressive in terms of corrosion, especially oxidation. This is only accelerated as the operating temperature increases to 650C and beyond. For any new steel to be qualified for power plant use, in addition to adequate strength at the operating temperature, material wastage from all corrosion processes must be kept to a minimum acceptable level. The use of medium Cr steels provides a means to improve overall corrosion resistance. Three medium Cr are under development for use as high temperature power plant steels: 0.08C-(9-12)Cr-1.2Ni-0.7Mo-3.0Cu-3.0Co-0.5Ti. Oxidation tests were performed on the steels for times greater than 1000 hours in order to determine the oxidation kinetics and extent of material wastage. Also, rare earth oxides were incorporated into the outer surface layers of the steels to see if the oxidation resistance could be improved. These results will be compared to current power plant steels.

Dogan, Omer N.; Alman, David A.; Jablonski, Paul D.

2005-02-01T23:59:59.000Z

320

Diode-Pumped Gigahertz Repetition Rate Femtosecond Cr:Lisaf Laser  

E-Print Network [OSTI]

We report a low-cost, 1 GHz repetition-rate, diode-pumped, saturable Bragg reflectors mode-locked Cr:LiSAF laser, which generates nearly transform-limited 103-fs long pulses around 866 nm, with a record high peak power of 1.45 kW.

Li, Duo

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Long-term measurements of equilibrium factor with electrochemically etched CR-39 SSNTD  

E-Print Network [OSTI]

.60 Keywords: Radon progeny concentration; Equilibrium factor; CR-39 1. Introduction Inhaled radon (222 Rn cancer [3]. Methods for long-term monitoring of the concentrations of radon progeny, or the equilibrium factor (which surro- gates the ratios of concentrations of radon progeny to the concentration of the 222

Yu, K.N.

322

Project EARTH-11-DP1: Exploring early solar system processes using Cr isotopes  

E-Print Network [OSTI]

Project EARTH-11-DP1: Exploring early solar system processes using Cr isotopes Supervisors: Dr D Porcelli & Dr K Amor Various isotope methods have been recently developed to explore the conditions in the early solar system and the processes that have led to the formation of the terrestrial planets. Stable

Henderson, Gideon

323

Clostridium chromiireducens sp. nov., isolated from Cr(VI)-contaminated soil  

E-Print Network [OSTI]

by its ability to reduce Cr(VI) in low concentrations. Mixed acid fermentation during growth on glucose resulted in accumulation of acetate, butyrate, formate and lactate. Morphological studies indicated the presence of peritrichous flagella, pili and an S-layer. The major cellular fatty acids (.5 %) were C16 : 0

Florida, University of

324

Relation between thermal expansion and interstitial formation energy in pure Fe and Cr  

E-Print Network [OSTI]

Relation between thermal expansion and interstitial formation energy in pure Fe and Cr Janne potentials give lower interstitial formation energy, but predict too small thermal expansion. We also show University, Uppsala, Sweden Abstract By fitting a potential of modified Finnis­Sinclair type to the thermal

325

Investigations of HRC®-Stimulated Bioreduction of Cr(VI) at Hanford 100H  

SciTech Connect (OSTI)

Hypothesis: Lactate (Hydrogen Release Compound-HRC{trademark}) injection into chromium contaminated groundwater through an injection well will cause indirect or direct bioreduction of chromate [Cr(VI)] and precipitation of insoluble species of [Cr(III)] on soil particles, probably catalyzed at oxide surfaces, at the field scale. Objective: Assess the potential for immobilizing and detoxifying chromium-contaminated groundwater using lactate-stimulated bioreduction of Cr(VI) to Cr(III) at the Hanford Site's 100-H Area field site. Types of Research: A three-well system (injection well and upgradient and downgradient monitoring wells) was used for conducting the in situ biostimulation and monitoring. To assess the pre- and post-injection test groundwater conditions, we used an integrated monitoring approach, involving hydraulic, geochemical, microbial, and geophysical techniques and analytical methods, as well as conducted five Br-tracer injection tests and four pumping tests (concurrently with the Br-tracer tests). Groundwater biostimulation was conducted by injection of 40 lbs of {sup 13}C-labeled HRC into the injection well (over the depth interval from 44-50 ft) on 8/3/2004, followed by low-flow pumping (1.2 to 2.5 l/min) through the downgradient well (to ensure capture of groundwater flow lines passing through the injection well) for 27 days. Main Results: Although the total microbial population in sediments is relatively low (<10{sup 5} cells g-1) under background conditions, which is likely insufficient for direct enzymatic Cr(VI) reduction, several types of bacteria, e.g., Bacillus/Arthrobacter and Geobacter, are present in the Hanford sediments, which are known to reduce or sorb hexavalent chromium. The HRC injection stimulated microbial cell counts to reach the maximum of 2 x 10{sup 7} cells g{sup -1} 13-17 days after the injection, and generated highly reducing conditions. Geochemical and isotopic observations confirmed microbial metabolism of HRC. The Cr(VI) concentration in the monitoring and pumping wells decreased below drinking water minimum contaminant limits and remained below background concentrations even after 1.5 years, when redox conditions and microbial densities had returned to background levels. Fe(II) levels have remained high and may account for the continued reduction of Cr(VI).

T.C. Hazen; B. Faybishenko; D. Joyner; S. Borglin; E.Brodie; S. Hubbard; K. Williams; J. Peterson; J. Wan; T. Tokunaga; Long, P.E.; Newcomer, D.; Koenigsberg, S.; Willet, A.

2005-04-18T23:59:59.000Z

326

Investigations of HRC®-Stimulated Bioreduction of Cr(VI) at Hanford 100H  

SciTech Connect (OSTI)

Hypothesis: Lactate (Hydrogen Release Compound-HRC{trademark}) injection into chromium contaminated groundwater through an injection well will cause indirect or direct bioreduction of chromate [Cr(VI)] and precipitation of insoluble species of [Cr(III)] on soil particles, probably catalyzed at oxide surfaces, at the field scale. Objective: Assess the potential for immobilizing and detoxifying chromium-contaminated groundwater using lactate-stimulated bioreduction of Cr(VI) to Cr(III) at the Hanford Site's 100-H Area field site. Types of Research: A three-well system (injection well and upgradient and downgradient monitoring wells) was used for conducting the in situ biostimulation and monitoring. To assess the pre- and post-injection test groundwater conditions, we used an integrated monitoring approach, involving hydraulic, geochemical, microbial, and geophysical techniques and analytical methods, as well as conducted five Br-tracer injection tests and four pumping tests (concurrently with the Br-tracer tests). Groundwater biostimulation was conducted by injection of 40 lbs of {sup 13}C-labeled HRC into the injection well (over the depth interval from 44-50 ft) on 8/3/2004, followed by low-flow pumping (1.2 to 2.5 l/min) through the downgradient well (to ensure capture of groundwater flow lines passing through the injection well) for 27 days. Main Results: Although the total microbial population in sediments is relatively low (<10{sup 5} cells g{sup -1}) under background conditions, which is likely insufficient for direct enzymatic Cr(VI) reduction, several types of bacteria, e.g., Bacillus/Arthrobacter and Geobacter, are present in the Hanford sediments, which are known to reduce or sorb hexavalent chromium. The HRC injection stimulated microbial cell counts to reach the maximum of 2 x 10{sup 7} cells g{sup -1} 13-17 days after the injection, and generated highly reducing conditions. Geochemical and isotopic observations confirmed microbial metabolism of HRC. The CR(VI) concentration in the monitoring and pumping wells decreased below drinking water minimum contaminant limits and remained below background concentrations even after 1.5 years, when redox conditions and microbial densities had returned to background levels. Fe(II) levels have remained high and may account for the continued reduction of Cr(VI).

Hazen, T.C.; Faybishenko, B.; Joyner, D.; Borglin, S.; Brodie, E.; Hubbard, S.; Williams, K.; Peterson, J.; Wan, J.; Tokunaga, T.; Firestone, M.; Long, P.E.; Resch, C.T.; Cantrell, K.; Newcomer, D.; Koenigsberg, S.; Willet, A.

2006-04-05T23:59:59.000Z

327

Originally presented at Photomask Japan '94, Kanagawa Science Park, April, 1994 Attenuated phase-shifting photomasks fabricated from Cr-based embedded shifter blanks  

E-Print Network [OSTI]

the cathode powers and gas mixture. Cr-based films' flexible properties are suitable for several applications

Rollins, Andrew M.

328

NbF{sub 5} and TaF{sub 5}: Assignment of {sup 19}F NMR resonances and chemical bond analysis from GIPAW calculations  

SciTech Connect (OSTI)

The {sup 19}F isotropic chemical shifts (?{sub iso}) of two isomorphic compounds, NbF{sub 5} and TaF{sub 5}, which involve six nonequivalent fluorine sites, have been experimentally determined from the reconstruction of 1D {sup 19}F MAS NMR spectra. In parallel, the corresponding {sup 19}F chemical shielding tensors have been calculated using the GIPAW method for both experimental and DFT-optimized structures. Furthermore, the [M{sub 4}F{sub 20}] units of NbF{sub 5} and TaF{sub 5} being held together by van der Waals interactions, the relevance of Grimme corrections to the DFT optimization processes has been evaluated. However, the semi-empirical dispersion correction term introduced by such a method does not show any significant improvement. Nonetheless, a complete and convincing assignment of the {sup 19}F NMR lines of NbF{sub 5} and TaF{sub 5} is obtained, ensured by the linearity between experimental {sup 19}F ?{sub iso} values and calculated {sup 19}F isotropic chemical shielding ?{sub iso} values. The effects of the geometry optimizations have been carefully analyzed, confirming among other matters, the inaccuracy of the experimental structure of NbF{sub 5}. The relationships between the fluorine chemical shifts, the nature of the fluorine atoms (bridging or terminal), the position of the terminal ones (opposite or perpendicular to the bridging ones), the fluorine charges, the ionicity and the length of the M–F bonds have been established. Additionally, for three of the {sup 19}F NMR lines of NbF{sub 5}, distorted multiplets, arising from {sup 1}J-coupling and residual dipolar coupling between the {sup 19}F and {sup 93}Nb nuclei, were simulated yielding to values of {sup 93}Nb–{sup 19}F {sup 1}J-coupling for the corresponding fluorine sites. - Graphical abstract: The complete assignment of the {sup 19}F NMR lines of NbF{sub 5} and TaF{sub 5} allow establishing relationships between the {sup 19}F ?{sub iso} values, the nature of the fluorine atoms (bridging or terminal), the position of the terminal ones (opposite or perpendicular to the bridging ones), the fluorine charges, the ionicity and the length of the M–F bonds. Display Omitted - Highlights: • The {sup 19}F ?{sub iso} values of NbF{sub 5} and TaF{sub 5} have been determined. • The {sup 19}F chemical shielding tensors have been calculated using the GIPAW method. • A confident assignment of the {sup 19}F NMR lines of NbF{sub 5} and TaF{sub 5} is obtained. • The relationships between the {sup 19}F?{sub iso} values and the M–F bonds features are established.

Biswal, Mamata, E-mail: Mamata.Biswal-Susanta_Kumar_Nayak.Etu@univ-lemans.fr [LUNAM Université, Université du Maine, CNRS UMR 6283, Institut des Molécules et des Matériaux du Mans, Avenue Olivier Messiaen, 72085 Le Mans Cedex 9 (France); Body, Monique, E-mail: monique.body@univ-lemans.fr [LUNAM Université, Université du Maine, CNRS UMR 6283, Institut des Molécules et des Matériaux du Mans, Avenue Olivier Messiaen, 72085 Le Mans Cedex 9 (France); Legein, Christophe, E-mail: christophe.legein@univ-lemans.fr [LUNAM Université, Université du Maine, CNRS UMR 6283, Institut des Molécules et des Matériaux du Mans, Avenue Olivier Messiaen, 72085 Le Mans Cedex 9 (France); Sadoc, Aymeric, E-mail: Aymeric.Sadoc@cnrs-imn.fr [Institut des Matériaux Jean Rouxel (IMN), Université de Nantes, CNRS, 2 rue de la Houssinière, BP 32229, 44322 Nantes Cedex 3 (France); Boucher, Florent, E-mail: Florent.Boucher@cnrs-imn.fr [Institut des Matériaux Jean Rouxel (IMN), Université de Nantes, CNRS, 2 rue de la Houssinière, BP 32229, 44322 Nantes Cedex 3 (France)

2013-11-15T23:59:59.000Z

329

A RD micro accelerometer with 6 lg/HHz resolution and 130 dB dynamic range  

E-Print Network [OSTI]

A RD micro accelerometer with 6 lg/HHz resolution and 130 dB dynamic range Ugur So¨nmez · Haluk Ku,largeareaMEMSsensors.Theproposedsystem can achieve a minimum of 6.0 lg/HHz noise floor, 3.2 lg bias instability, and a maximum of 130 dB DR at 1 Hz. A FSR of ±20 g is reported for 6.2 lg/HHz noise floor. This range can be increased up to ±40 g

Akin, Tayfun

330

Characterization of passive oxide film on a Ti-5%Ta-1.8%Nb alloy on exposure to severe oxidizing conditions  

SciTech Connect (OSTI)

This paper presents the results of a study on the characteristics of the passive oxide film that forms on the surface of an {alpha} + {beta} Ti-5%Ta-1.8%Nb alloy, which possesses good corrosion resistance in severe oxidizing environment of boiling 11.5 M nitric acid. Through systematic structure-property studies, the microstructure with low corrosion rate (< 1 mpy) in liquid, vapor and condensate phases of nitric acid was identified. The characteristics of the passive film, which imparts corrosion resistance to the alloy, are influenced by its microstructure, temperature and concentration of the acid. The microstructure, thickness and composition of the oxide film were characterized using different techniques. TiO{sub 2}, Nb{sub 2}O{sub 5} and Ta{sub 2}O{sub 5} formed on exposure to vapor and condensate phases, while TiO{sub 2} was observed on exposure to the liquid phase. Detailed microstructural studies showed that the passive film consists of nano-crystalline phases of titanium and tantalum oxides, predominantly anatase in an amorphous matrix. Based on these studies, the mechanism of corrosion of the alloy is derived. - Research Highlights: {yields}Liquid phase corrosion results in a thicker and protective oxide film. {yields}Oxide film is a mixture of amorphous and nano-crystalline anatase. {yields}Higher amounts of Nb{sub 2}O{sub 5} and Ta{sub 2}O{sub 5} form on vapor and condensate phase corrosion. {yields}High corrosion rate in condensate phase is due to selective dissolution of Ti in {alpha} phase.

Mythili, R.; Saroja, S., E-mail: saroja@igcar.gov.in; Vijayalakshmi, M.

2010-12-15T23:59:59.000Z

331

Study of spontaneous and induced absorption in amorphous Ta{sub 2}O{sub 5} and SiO{sub 2} dielectric thin films  

SciTech Connect (OSTI)

Tantalum pentoxide (Ta{sub 2}O{sub 5}) and silicon dioxide (SiO{sub 2}) are common high-index and low-index materials used in dielectric optical coatings for high average-power lasers since high-density sputtered oxide films with absorption losses at near- and mid-infrared wavelengths of less than 1 ppm can be obtained. These oxides have been chosen to investigate the spontaneous and optically induced absorption at {lambda}{sub 0} = 1064 nm that occurs due to simultaneous illumination at shorter wavelengths. The effect is measured using the photothermal common-path interferometric technique. This technique is capable of detecting sub-ppm levels of optical absorption and tracking its changes at a given wavelength when a second laser beam is also incident on a thin film oxide sample. In this work, dual beam experiments are employed to assess changes in the optical absorption at {lambda}{sub 0} = 1064 nm in ion beam sputtered Ta{sub 2}O{sub 5} and SiO{sub 2} thin films deposited on fused silica substrates, with stimulating illumination {lambda}{sub 1} ranging from {lambda}{sub 1} = 266 nm to {lambda}{sub 1} = 780 nm. The power and wavelength of the stimulating radiation were found to affect the optical absorption at {lambda}{sub 0} = 1064 nm. Furthermore, the relaxation dynamics of the induced infrared absorption was found to be wavelength dependent and is thought to be associated with various electron traps existing in the forbidden gap that depend essentially on the film's preparation conditions. The significantly greater effect observed in Ta{sub 2}O{sub 5} at {lambda}{sub 1} = 266 nm is attributed to band-to-band transitions.

Markosyan, A. S.; Route, R.; Fejer, M. M. [Department of Applied Physics, E.L. Ginzton Laboratory, Stanford University, Stanford, California 94305 (United States); Patel, D.; Menoni, C. [Department of Electrical and Computer Engineering and NSF ERC for Extreme Ultraviolet Science and Technology, Colorado State University, Fort Collins, Colorado 80523 (United States)

2013-04-07T23:59:59.000Z

332

Structural Properties of the Cr(III)-Fe(III) (Oxy)Hydroxide Compositional Series: Insights for a Nanomaterial “Solid Solution”  

SciTech Connect (OSTI)

Chromium(III) (oxy)hydroxide and mixed Cr(III)-Fe(III) (oxy)hydroxides are environmentally important compounds for controlling chromium speciation and bioaccessibility in soils and aquatic systems and are also industrially important as precursors for materials and catalyst synthesis. However, direct characterization of the atomic arrangements of these materials is complicated because of their amorphous X-ray properties. This study involves synthesis of the complete Cr(III)-Fe(III) (oxy)hydroxide compositional series, and the use of complementary thermal, microscopic, spectroscopic, and scattering techniques for the evaluation of their structural properties. Thermal analysis results show that the Cr end member has a higher hydration state than the Fe end member, likely associated with the difference in water exchange rates in the first hydration spheres of Cr(III) and Fe(III). Three stages of weight loss are observed and are likely related to the loss of surface/structural water and hydroxyl groups. As compared to the Cr end member, the intermediate composition sample shows lower dehydration temperatures and a higher exothermic transition temperature. XANES analysis shows Cr(III) and Fe(III) to be the dominant oxidation states. XANES spectra also show progressive changes in the local structure around Cr and Fe atoms over the series. Pair distribution function (PDF) analysis of synchrotron X-ray total scattering data shows that the Fe end member is nanocrystalline ferrihydrite with an intermediate-range order and average coherent domain size of {approx}27 {angstrom}. The Cr end member, with a coherent domain size of {approx}10 {angstrom}, has only short-range order. The PDFs show progressive structural changes across the compositional series. High-resolution transmission electron microscopy (HRTEM) results also show the loss of structural order with increasing Cr content. These observations provide strong structural evidence of chemical substitution and progressive structural changes along the compositional series.

Tang, Y.; Zhang, L.; Michel, F.M.; Harrington, R.; Parise, J.B.; Reeder, R.J.

2010-05-28T23:59:59.000Z

333

Structural Properties of the Cr(III)-Fe(III) (Oxy)hydroxide Compositional Series: Insights for a Nanomaterial "Solid Solution"  

SciTech Connect (OSTI)

Chromium(III) (oxy)hydroxide and mixed Cr(III)-Fe(III) (oxy)hydroxides are environmentally important compounds for controlling chromium speciation and bioaccessibility in soils and aquatic systems and are also industrially important as precursors for materials and catalyst synthesis. However, direct characterization of the atomic arrangements of these materials is complicated because of their amorphous X-ray properties. This study involves synthesis of the complete Cr(III)-Fe(III) (oxy)hydroxide compositional series, and the use of complementary thermal, microscopic, spectroscopic, and scattering techniques for the evaluation of their structural properties. Thermal analysis results show that the Cr end member has a higher hydration state than the Fe end member, likely associated with the difference in water exchange rates in the first hydration spheres of Cr(III) and Fe(III). Three stages of weight loss are observed and are likely related to the loss of surface/structural water and hydroxyl groups. As compared to the Cr end member, the intermediate composition sample shows lower dehydration temperatures and a higher exothermic transition temperature. XANES analysis shows Cr(III) and Fe(III) to be the dominant oxidation states. XANES spectra also show progressive changes in the local structure around Cr and Fe atoms over the series. Pair distribution function (PDF) analysis of synchrotron X-ray total scattering data shows that the Fe end member is nanocrystalline ferrihydrite with an intermediate-range order and average coherent domain size of 27 {angstrom}. The Cr end member, with a coherent domain size of 10 {angstrom}, has only short-range order. The PDFs show progressive structural changes across the compositional series. High-resolution transmission electron microscopy (HRTEM) results also show the loss of structural order with increasing Cr content. These observations provide strong structural evidence of chemical substitution and progressive structural changes along the compositional series.

Michel, Y.; Michel, F; Zhang, L; Harrington, R; Parise, J; Reeder, R

2010-01-01T23:59:59.000Z

334

Electronic Instability in a Zero-Gap Semiconductor: The Charge-Density Wave in (TaSe4)2I  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

We report a comprehensive study of the paradigmatic quasi-1D compound (TaSe4)2I performed by means of angle-resolved photoemission spectroscopy (ARPES) and first-principles electronic structure calculations. We find it to be a zero-gap semiconductor in the nondistorted structure, with non-negligible interchain coupling. Theory and experiment support a Peierls-like scenario for the charge-density wave formation below TCDW=263??K, where the incommensurability is a direct consequence of the finite interchain coupling. The formation of small polarons, strongly suggested by the ARPES data, explains the puzzling semiconductor-to-semiconductor transition observed in transport at TCDW.

Tournier-Colletta, C.; Moreschini, L.; Autès, G.; Moser, S.; Crepaldi, A.; Berger, H.; Walter, A. L.; Kim, K. S.; Bostwick, A.; Monceau, P.; Rotenberg, E.; Yazyev, O. V.; Grioni, M.

2013-06-01T23:59:59.000Z

335

Prayer to Ta pi hri tsa - A short exposition of the Base, the Path and the Fruit in Bon Dzogchen teachings  

E-Print Network [OSTI]

Prayer to Ta pi hri tsa A short exposition of the Base, the Path and the Fruit in Bon Dzogchen teachings* By Ratka Jurkovic Introduction zogchen (rDzogs pa chen po or in short rDzogs chen), the Great Perfection represents... of the Dzogchen teachings represented through the discussion of Base, Fruit and Path. The six verse form is typical of the kind usually found in the earliest Dzogchen Nyingma text, “The Cuckoo of the Intellect” (Rig pa’i khu byug), a copy of which was among...

Jurkovic, Ratka

2009-01-01T23:59:59.000Z

336

Collapse of ferromagnetism in itinerant-electron system: A magnetic, transport properties, and high pressure study of (Hf,Ta)Fe{sub 2} compounds  

SciTech Connect (OSTI)

The magnetism and transport properties were studied for Laves (Hf,Ta)Fe{sub 2} itinerant-electron compounds, which exhibit a temperature-induced first-order transition from the ferromagnetic (FM) to the antiferromagnetic (AFM) state upon heating. At finite temperatures, the field-induced metamagnetic phase transition between the AFM and FM has considerable effects on the transport properties of these model metamagnetic compounds. A large negative magnetoresistance of about 14% is observed in accordance with the metamagnetic transition. The magnetic phase diagram is determined for the Laves Hf{sub 1?x}Ta{sub x}Fe{sub 2} series and its Ta concentration dependence discussed. An unusual behavior is revealed in the paramagnetic state of intermediate compositions, it gives rise to the rapid increase and saturation of the local spin fluctuations of the 3d electrons. This new result is analysed in the frame of the theory of Moriya. For a chosen composition Hf{sub 0.825}Ta{sub 0.175}Fe{sub 2}, exhibiting such remarkable features, a detailed investigation is carried out under hydrostatic pressure up to 1?GPa in order to investigate the volume effect on the magnetic properties. With increasing pressure, the magnetic transition temperature T{sub FM-AFM} from ferromagnetic to antiferromagnetic order decreases strongly non-linearly and disappears at a critical pressure of 0.75?GPa. In the pressure-induced AFM state, the field-induced first-order AFM-FM transition appears and the complex temperature dependence of the AFM-FM transition field is explained by the contribution from both the magnetic and elastic energies caused by the significant temperature variation of the amplitude of the local Fe magnetic moment. The application of an external pressure leads also to the progressive decrease of the Néel temperature T{sub N}. In addition, a large pressure effect on the spontaneous magnetization M{sub S} for pressures below 0.45?GPa, dln(M{sub s})/dP?=??6.3?×?10{sup ?2?}GPa{sup ?1} was discovered. The presented results are consistent with Moriya's theoretical predictions and can significantly help to better understand the underlying physics of itinerant electron magnetic systems nowadays widely investigated for both fundamental and applications purposes.

Diop, L. V. B., E-mail: leopold.diop@neel.cnrs.fr; Isnard, O. [Univ. Grenoble Alpes, Inst NEEL, F-38042 Grenoble (France); CNRS, Inst NEEL, F-38042 Grenoble (France); Kastil, J. [Univ. Grenoble Alpes, Inst NEEL, F-38042 Grenoble (France); CNRS, Inst NEEL, F-38042 Grenoble (France); Institute of Physics AS CR v.v.i., Na Slovance 2, 182 21 Prague 8 (Czech Republic); Arnold, Z.; Kamarad, J. [Institute of Physics AS CR v.v.i., Na Slovance 2, 182 21 Prague 8 (Czech Republic)

2014-10-28T23:59:59.000Z

337

Properties of triaxial, strongly deformed bands in {sup 167}Ta and {sup 167}Lu and the top-on-top model  

SciTech Connect (OSTI)

Based on the particle-rotor model with one particle coupled to a triaxially deformed rotor, the experimental excitation energy relative to a reference E*-aI(I+1) and the ratio between interband and intraband electromagnetic transitions are well reproduced for {sup 167}Ta with {gamma}=19 deg. The same parameter set for the angular-momentum-dependent rigid-body moments of inertia attains good agreement with experimental data for the positive-parity triaxial, strongly deformed (TSD) band levels in {sup 167}Lu. An attempt is made to investigate the negative-parity TSD band in {sup 167}Lu.

Sugawara-Tanabe, Kazuko [Theoretical Nuclear Physics Laboratory, RIKEN Nishina Center, Wako, Saitama 351-0198 (Japan); Otsuma Women's University, Tama, Tokyo 206-8540 (Japan); Tanabe, Kosai [Theoretical Nuclear Physics Laboratory, RIKEN Nishina Center, Wako, Saitama 351-0198 (Japan); Department of Physics, Saitama University, Sakura-Ku, Saitama 338-8570 (Japan)

2010-11-15T23:59:59.000Z

338

Doubly resonant Raman electron paramagnetic transitions of Cr{sup 3+} in ruby (Al{sub 2}O{sub 3}:Cr{sup 3+}).  

SciTech Connect (OSTI)

We report the Raman electron paramagnetic resonance (EPR) of Cr{sup 3+} in ruby (Al{sub 2}O{sub 3}:Cr{sup 3+}) in the {sup 4}A{sub 2} (ground) and E{sup -} (excited) states of its well-known R{sub 1} emission line. Using tunable dye laser excitation within the range of the Zeeman components of R{sub 1}, we observe highly selective doubly resonant enhancements of the Raman EPR lines. The double resonances confirm the assignments of the Raman EPR lines, and they underscore the simultaneous occurrence of both 'in resonance' and 'out resonance' as visualized in the Kramers-Heisenberg quantum-mechanical picture of inelastic light scattering. The g factors of the {sup 4}A{sub 2} and E{sup -} states are consistent with the observed magnetic field dependence of the Raman EPR shifts. Through the interplay of Raman effect and the sharp Zeeman components of R{sub 1}, the results provide clear insights into the underlying microscopic mechanism of these resonant Raman EPR spectra of ruby.

Lu, X.; Venugopalan, S.; Kim, H.; Grimsditch, M.; Rodriguez, S.; Ramdas, A. K.; Materials Science Division; Purdue Univ.; State Univ. of New York at Binghamton; Sogang Univ.

2009-06-01T23:59:59.000Z

339

Magnetization switching of rare earth orthochromite CeCrO{sub 3}  

SciTech Connect (OSTI)

We report the synthesis of single phase rare earth orthochromite CeCrO{sub 3} and its magnetic properties. A canted antiferromagnetic transition with thermal hysteresis at T?=?260?K is observed, and a magnetic compensation (zero magnetization) near 133?K is attributed to the antiparallel coupling between Ce{sup 3+} and Cr{sup 3+} moments. At low temperature, field induced magnetization reversal starting from 43?K for H?=?1.2 kOe reveals the spin flip driven by Zeeman energy between the net moments and the applied field. These findings may find potential uses in magnetic switching devices such as nonvolatile magnetic memory which facilitates two distinct states of magnetization.

Cao, Yiming; Cao, Shixun, E-mail: sxcao@shu.edu.cn; Ren, Wei; Feng, Zhenjie; Yuan, Shujuan; Kang, Baojuan; Zhang, Jincang [Department of Physics, Shanghai University, Shanghai 200444 (China); Lu, Bo [Laboratory for Microstructures, Shanghai University, Shanghai 200444 (China)

2014-06-09T23:59:59.000Z

340

Irradiation effects on base metal and welds of 9Cr-1Mo (EM10) martensitic steel  

SciTech Connect (OSTI)

9Cr martensitic steels are being developed for core components (wrapper tubes) of fast breeder reactors as well as for fusion reactor structures. Here, the effects of fast neutron irradiation on the mechanical behavior of base metal and welds of 9Cr-1Mo (EM10) martensitic steel have been studied. Two types of weldments have been produced by TIG and electron beam techniques. Half of samples have been post-weld heat treated to produce a stress-relieved structure. The irradiation has been conducted in the Phenix reactor to doses of 63--65 dpa in the temperature range 450--459 C. The characterization of the welds, before and after irradiation, includes metallographic observations, hardness measurements, tensile and Charpy tests. It is shown that the mechanical properties of the welds after irradiation are in general similar to the characteristics obtained on the base metal, which is little affected by neutron irradiation.

Alamo, A.; Seran, J.L.; Rabouille, O.; Brachet, J.C.; Maillard, A.; Touron, H.; Royer, J. [CEA Saclay, Gif-sur-Yvette (France)

1996-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
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341

High-reflectivity Cr/Sc multilayer condenser for compact soft x-ray microscopy  

SciTech Connect (OSTI)

The condenser is a critical component in compact water-window x-ray microscopes as it influences the exposure time via its efficiency and the resolution via its numerical aperture. Normal-incidence multilayer mirrors can reach large geometrical collection efficiencies and match the numerical aperture of the zone plate but require advanced processing for high total reflectivity. In the present article we demonstrate large-diameter normal-incidence spherical Cr/Sc multilayer condensers with high and uniform reflectivity. Dc-magnetron sputtering was used to deposit 300 bilayers of Cr/Sc with a predetermined d-spacing matching the {lambda}=3.374 nm operating wavelength on spherical substrates. The mirrors show a uniform reflectivity of {approx}3% over the full 58 mm diameter condenser area. With these mirrors an improvement in exposure time by a factor of 10 was achieved, thereby improving the performance of the compact x-ray microscope significantly.

Stollberg, H.; Yulin, S.; Takman, P. A. C.; Hertz, H. M. [Biomedical and X-Ray Physics, Department of Applied Physics, KTH-AlbaNova, 10691 Stockholm (Sweden); Fraunhofer-Institut fur Angewandte Optik und Feinmechanik, Albert-Einstein-Strasse 7, 07745 Jena (Germany); Biomedical and X-Ray Physics, Department of Applied Physics, KTH-AlbaNova, 10691 Stockholm (Sweden)

2006-12-15T23:59:59.000Z

342

Development and characterization of PdCr temperature-compensaated wire resistance strain gage  

SciTech Connect (OSTI)

A temperature-compensated resistance static strain gage with potential to be used to 600 C was recently developed. Gages were fabricated from specially developed palladium-13 w/o chromium (Pd-13Cr) wire and platinum (Pt) compensator. When bonded to high temperature Hastelloy X, the apparent strain from room temperature to 600 C was within 400 microstrain for gages with no preheat treatment and within 3500 microstrain for gages with 16 hours prestabilization at 640 C. The apparent strain versus temperature relationship of stabilized PdCr gages were repeatable with the reproducibility within 100 microstrain during three thermal cycles to 600 C and an 11 hours soak at 600 C. The gage fabrication, construction and installation is described. Also, the coating system used for this compensated resistance strain gage is explained. The electrical properties of the strain sensing element and main characteristics of the compensated gage including apparent strain, drift and reproducibility are discussed.

Lei, J.F.

1989-10-01T23:59:59.000Z

343

Absence of long-range chemical ordering in equimolar FeCoCrNi  

SciTech Connect (OSTI)

Equimolar FeCoCrNi alloys have been the topic of recent research as 'high-entropy alloys,' where the name is derived from the high configurational entropy of mixing for a random solid solution. Despite their name, no systematic study of ordering in this alloy system has been performed to date. Here, we present results from anomalous x-ray scattering and neutron scattering on quenched and annealed samples. An alloy of FeNi{sub 3} was prepared in the same manner to act as a control. Evidence of long-range chemical ordering is clearly observed in the annealed FeNi{sub 3} sample from both experimental techniques. The FeCoCrNi sample given the same heat treatment lacks long-range chemical order.

Lucas, M. S. [Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); UTC Inc., 1270 North Fairfield Road, Dayton, Ohio 45432 (United States); Wilks, G. B.; Senkov, O. N. [Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); UES, Inc., 4401 Dayton-Xenia Rd., Dayton, Ohio 45432 (United States); Mauger, L.; Munoz, J. A. [California Institute of Technology, W. M. Keck Laboratory 138-78, Pasadena, California 91125 (United States); Michel, E. [Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); Wright State University, Dayton, Ohio 45435 (United States); Horwath, J.; Semiatin, S. L. [Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); Stone, M. B.; Abernathy, D. L. [Oak Ridge National Laboratory, 1, Bethel Valley Road, Oak Ridge, Tennessee 37831 (United States); Karapetrova, E. [Argonne National Laboratory, Argonne, Illinois 60439 (United States)

2012-06-18T23:59:59.000Z

344

Absence of long-range chemical ordering in equimolar FeCoCrNi  

SciTech Connect (OSTI)

Equimolar FeCoCrNi alloys have been the topic of recent research as high-entropy alloys, where the name is derived from the high configurational entropy of mixing for a random solid solution. Despite their name, no systematic study of ordering in this alloy system has been performed to date. Here we present results from anomalous x-ray scattering and neutron scattering on quenched and annealed samples. An alloy of FeNi3 was prepared in the same manner to act as a control. Evidence of longrange chemical ordering is clearly observed in the annealed FeNi3 sample from both experimental techniques. The FeCoCrNi sample given the same heat treatment lacks long-range chemical order.

Lucas, Matthew [Air Force Research Laboratory, Wright-Patterson AFB, OH; Wilks, G B [Air Force Research Laboratory, Wright-Patterson AFB, OH; Mauger, L [W. M. Keck Laboratory, Pasadena, CA; Munoz, Jorge A. [California Institute of Technology, Pasadena; Senkov, Oleg [ORNL; Michel, E [Air Force Research Laboratory, Wright-Patterson AFB, OH; Horwath, J [Air Force Research Laboratory, Wright-Patterson AFB, OH; Semiatin, S L [Air Force Research Laboratory, Wright-Patterson AFB, OH; Stone, Matthew B [ORNL; Abernathy, Douglas L [ORNL; Karapetrova, Evgenia [University of Illinois, Urbana-Champaign

2012-01-01T23:59:59.000Z

345

MICROSTRUCTURAL EXAMINATION OF V-4CR-4TI PRESSURIZED THERMAL CREEP TUBES  

SciTech Connect (OSTI)

Two further failed thermal creep pressurized tubes of V-4Cr-4Ti tested at 700 and 800 degrees C have been examined using optical microscopy and transmission electron microscopy in order to understand failure and creep mechanisms. These conditions represent lower stress states than were previously examined. Creep deformation at lower stress is shown to be controlled by sub-boundary formation and mis-orientation between sub-grains arising from climb of dislocations within the boundary.

Gelles, David S.

2002-09-01T23:59:59.000Z

346

High pressure synthesis of a new chromite, ScCrO{sub 3}  

SciTech Connect (OSTI)

A new compound, ScCrO{sub 3} has been synthesized at 45 kbar and 1,200 C using the cylindrical type press (USCA-1000). It has Pbnm symmetry with a = 5.0329(2) {angstrom}, b = 5.3602(3) {angstrom}, and c = 7.3790(4) {angstrom}, and its structure has been refined using the Rietveld technique and the synchrotron powder X-ray diffraction data.

Park, J.H.; Parise, J.B. [State Univ. of New York, Stony Brook, NY (United States)] [State Univ. of New York, Stony Brook, NY (United States)

1997-12-01T23:59:59.000Z

347

The energy distribution of beta CrB for the specific stellar abundances  

E-Print Network [OSTI]

The comparison of the observed and computed energy distributions of beta CrB has shown that a model with the specific chemical composition of the star can account for the visual enery distribution, while it is still unable to reproduce ultraviolet observations shortward of 1700 A. Furthermore, the predicted absorption of strong Fe II and Mg II UV lines is much larger than the observed one.

F. Castelli

1998-05-06T23:59:59.000Z

348

The MSFR as a flexible CR reactor: the viewpoint of safety  

SciTech Connect (OSTI)

In this paper, the possibility has first been discussed of using the liquid-fuelled Molten Salt Fast Reactor (MSFR) as a flexible conversion ratio (CR) reactor without design modification. By tuning the reprocessing rate it is possible to determine the content of fission products in the core, which in turn can significantly affect the neutron economy without incurring in solubility problems. The MSFR can thus be operated as U-233 breeder (CR>1), iso-breeder (CR=1) and burner reactor (CR<1). In particular a 40 year doubling time can be achieved, as well as a considerable Transuranics and MA (minor actinide) burning rate equal to about 150 kg{sub HN}/GWE-yr. The safety parameters of the MSFR have then been evaluated for different fuel cycle strategies. Th use and a softer spectrum combine to give a strong Doppler coefficient, one order of magnitude higher compared to traditional fast reactors (FRs). The fuel expansion coefficient is comparable to the Doppler coefficient and is only mildly affected by core compositions, thus assisting the fuel cycle flexibility of the MSFR. ?eff and generation time are comparable to the case of traditional FRs, if a static fuel is assumed. A notable reduction of ?eff is caused by salt circulation, but a low value of this parameter is a limited concern in the MSFR thanks to the lack of a burnup reactivity swing and of positive feedbacks. A simple approach has also been developed to evaluate the MSFR capabilities to withstand all typical double-fault accidents, for different fuel cycle options.

Fiorina, C.; Cammi, A. [Politecnico di Milano, Via La Masa 34, 20136 Milan (Italy); Franceschini, F. [Westinghouse Electric Company LL, 1000 Westinghouse Dr., Cranberry Township, PA 16066 (United States); Krepel, J. [Paul Scherrer Institut, PSI WEST, 5234 Villigen (Switzerland)

2013-07-01T23:59:59.000Z

349

mm-Wave Op-Amps employing simple-Miller compensation, with OIP3/PDC ratios of 211 (10 dB NF) and 144 (6.0 dB NF) at 2 GHz  

E-Print Network [OSTI]

mm-Wave Op-Amps employing simple-Miller compensation, with OIP3/PDC ratios of 211 (10 dB NF/PDC ratio at fs = 2-3 GHz, compared to state-of-the-art. We address considerations important 1000 mW power dissipation PDC . This very high ratio of output-referred third-order-intercept power

Rodwell, Mark J. W.

350

Ferromagnetic ordering of Cr and Fe doped p-type diamond: An ab initio study  

SciTech Connect (OSTI)

Ferromagnetic ordering of transition metal dopants in semiconductors holds the prospect of combining the capabilities of semiconductors and magnetic systems in single hybrid devices for spintronic applications. Various semiconductors have so far been considered for spintronic applications, but low Curie temperatures have hindered room temperature applications. We report ab initio DFT calculations on the stability and magnetic properties of Fe and Cr impurities in diamond, and show that their ground state magnetic ordering and stabilization energies depend strongly on the charge state and type of co-doping. We predict that divacancy Cr{sup +2} and substitutional Fe{sup +1} order ferromagnetically in p-type diamond, with magnetic stabilization energies (and magnetic moment per impurity ion) of 16.9 meV (2.5 ?{sub B}) and 33.3 meV (1.0 ?{sub B}), respectively. These magnetic stabilization energies are much larger than what has been achieved in other semiconductors at comparable impurity concentrations, including the archetypal dilute magnetic semiconductor GaAs:Mn. In addition, substitutional Fe{sup +1} exhibits a strong half-metallic character, with the Fermi level crossing bands in only the spin down channel. These results, combined with diamond’s extreme properties, demonstrate that Cr or Fe dopedp-type diamond may successfully be considered in the search for room temperature spintronic materials.

Benecha, E. M. [Department of Physics, University of South Africa, P.O Box 392, UNISA 0003, Pretoria (South Africa); Lombardi, E. B. [College of Graduate Studies, University of South Africa, P.O Box 392, UNISA 0003, Pretoria (South Africa)

2014-02-21T23:59:59.000Z

351

HUMAN MACHINE INTERFACE (HMI) EVALUATION OF ROOMS TA-50-1-60/60A AT THE RADIOACTIVE LIQUID WASTE TREATMENT FACILITY (RLWTF)  

SciTech Connect (OSTI)

This effort addressed an evaluation of human machine interfaces (HMIs) in Room TA-50-1-60/60A of the Radioactive Liquid Waste Treatment Facility (RLWTF). The evaluation was performed in accordance with guidance outlined in DOE-STD-3009, DOE Standard Preparation Guide for U.S. Department of Energy Nonreactor Nuclear Facility Documented Safety Analyses, 2006 [DOE 2006]. Specifically, Chapter 13 of DOE 2006 highlights the 10 CFR 830, Nuclear Safety Management, 2012, [CFR 2012] and DOE G 421.1-2 [DOE 2001a] requirements as they relate to the human factors process and, in this case, the safety of the RLWTF. The RLWTF is a Hazard Category 3 facility and, consequently, does not have safety-class (SSCs). However, safety-significant SSCs are identified. The transuranic (TRU) wastewater tanks and associated piping are the only safety-significant SSCs in Rooms TA-50-1-60/60A [LANL 2010]. Hence, the human factors evaluation described herein is only applicable to this particular assemblage of tanks and piping.

Gilmore, Walter E. [Los Alamos National Laboratory; Stender, Kerith K. [Los Alamos National Laboratory

2012-08-29T23:59:59.000Z

352

Feasibility study of a 6V-92TA homogeneous auto-ignited two-stroke (HAT) compressed-natural-gas-engine. Topical report, August 1989-May 1990  

SciTech Connect (OSTI)

The objective of the project was to modify a two-stroke 6V-92TA diesel engine to operate on natural gas using a simple system with gas addition to the compressor inlet and a spark plug for cold start and non-autoignition engine operation. The engine was to be operated at most speed-load conditions by autoignition of the premixed gas-air mixture. This concept is referred to as the Homogeneous Auto-Ignited Two-Stroke (HAT). Autoignition of carbureted natural gas was achieved at various loads and speeds in a 6V-92TA engine modified for operating on natural gas with the HAT concept. However, HAT engine operation up to 277 hp at 2100 rpm (diesel coach rating) was not achieved because early ignition in some cylinders caused knock and excessive heat transfer. Instead, the engine was operated up to 226 hp (767 N.m) at 2100 rpm, 181 hp (780 N.m) at 1650 rpm, 130 hp (773 N.m) at 1200 rpm, and 34 hp (368 N.m) at 650 rpm. Maximum brake thermal efficiency measured was 33.4% at 2100 rpm/219 hp. The corrected efficiency (to compensate for the unburned natural gas lost during the scavenging process) was higher than this. Steady-state emissions show very low NOx, total unburned HC lower than expected and reasonable CO levels. The lean air-fuel mixture and unburned exhaust gases in the cylinder resulted in very low NOx emissions.

Kakwani, R.M.; Winsor, R.E.

1990-08-01T23:59:59.000Z

353

In situ X-ray diffraction strain-controlled study of Ti–Nb–Zr and Ti–Nb–Ta shape memory alloys: crystal lattice and transformation features  

SciTech Connect (OSTI)

Phase and structure transformations in biomedical Ti–21.8Nb–6.0Zr (TNZ) and Ti–19.7Nb–5.8Ta (TNT) shape memory alloys (at.%) under and without load in the ? 150 to 100 °S temperature range are studied in situ using an original tensile module for a low-temperature chamber of an X-ray diffractometer. Alpha?- and beta-phase lattice parameters, the crystallographic resource of recovery strain, phase and structure transformation sequences, and microstress appearance and disappearance are examined, compared and discussed. For both alloys, the crystallographic resource of recovery strain decreases with temperature increase to become 4.5% for TNZ and 2.5% for TNT alloy (at RT). Loading at low temperatures leads to additional ??-phase formation and reorientation. Heating under load, as compared to strain-free heating, affects the reverse transformation sequence of both alloys in different ways. For TNZ alloy, strain-free heating results in simultaneous ??? and ???? transformations, whereas during heating under stress, they are sequential: ? + ???? precedes ????. For TNT alloy, strain-free heating results in reverse ???? transformation, whereas during heating under stress, ???? transformation is preceded by ??-phase reorientation. - Highlights: • Comparative in situ XRD analysis of Ti–Nb–Zr(Ta) shape memory alloys is realized. • Lattice parameters of ?- and ??-phases are calculated in the ? 150 to + 100 °C range. • The higher the temperature, the lower the ???? transformation strain. • Loading at low temperatures results in ??-phase formation and reorientation. • Transformation sequences upon heating with and without loading are different.

Dubinskiy, S. [École de technologie supérieure, 1100, Notre-Dame Street West, Montreal, Quebec H3C 1K3 (Canada); National University of Science and Technology “MISIS”, 4, Leninskiy prosp., Moscow 119049 (Russian Federation); Prokoshkin, S. [National University of Science and Technology “MISIS”, 4, Leninskiy prosp., Moscow 119049 (Russian Federation); Brailovski, V., E-mail: vladimir.brailovski@etsmtl.ca [École de technologie supérieure, 1100, Notre-Dame Street West, Montreal, Quebec H3C 1K3 (Canada); Inaekyan, K. [École de technologie supérieure, 1100, Notre-Dame Street West, Montreal, Quebec H3C 1K3 (Canada); Korotitskiy, A. [National University of Science and Technology “MISIS”, 4, Leninskiy prosp., Moscow 119049 (Russian Federation)

2014-02-15T23:59:59.000Z

354

An aqueous route to [Ta6O19]8- and solid-state studies of isostructural niobium and tantalum oxide complexes.  

SciTech Connect (OSTI)

Tantalate materials play a vital role in our high technology society: tantalum capacitors are found in virtually every cell phone. Furthermore, electronic characteristics and the incredibly inert nature of tantalates renders them ideal for applications such as biomedical implants, nuclear waste forms, ferroelectrics, piezoelectrics, photocatalysts and optical coatings. The inert and insoluble nature of tantalates is not fundamentally understood; and furthermore poor solubility renders fabrication of novel or optimized tantalates very difficult. We have developed a soft chemical route to water-soluble tantalum oxide clusters that can serve as both precursors for novel tantalate materials and ideal models for experimental and computational approaches to understanding the unusually inert behavior of tantalates. The water soluble cluster, [Ta6O19]8- is small, highly symmetric, and contains the representative oxygen types of a metal oxide surface, and thus ideally mimics a complex tantalate surface in a simplistic form that can be studied unambiguously. Furthermore; in aqueous solution, these highly charged and super-basic clusters orchestrate surprising acid-base behavior that most likely plays an important role in the inertness of related oxide surfaces. Our unique synthetic approach to the [Ta6O19]8- cluster allowed for unprecedented enrichment with isotopic labels (17O), enabling detailed kinetic and mechanistic studies of the behavior of cluster oxygens, as well as their acid-base behavior. This SAND report is a collection of two publications that resulted from these efforts.

Nyman, May D.; Anderson, Travis Mark [Sandia National Laboratories, Albuquerque, NM; Alam, Todd M. [Sandia National Laboratories, Albuquerque, NM; Rodriguez, Mark Andrew [Sandia National Laboratories, Albuquerque, NM; Joel N. Bixler; Francois Bonhomme

2007-10-01T23:59:59.000Z

355

Joint contributions of Ag ions and oxygen vacancies to conducting filament evolution of Ag/TaO{sub x}/Pt memory device  

SciTech Connect (OSTI)

The electroforming and resistive switching behaviors in the Ag/TaO{sub x}/Pt trilayer structure are investigated under a continual change of temperatures between 300?K and 100?K to distinguish the contributions of Ag ions and oxygen vacancies in developing of conducting filaments. For either electroforming or resistive switching, a significantly higher forming/set voltages is needed as the device is operated at 100?K, as compared to that observed when operating at 300?K. The disparity in forming/set voltages of Ag/TaO{sub x}/Pt operating at 300?K and 100?K is attributed to the contribution of oxygen vacancies, in addition to Ag atoms, in formation of conducting filament at 100?K since the mobilities of oxygen vacancies and Ag ions become comparable at low temperature. The presence of oxygen vacancy segment in the conducting filament also modifies the reset current from a gradually descending behavior (at 300?K) to a sharp drop (at 100?K). Furthermore, the characteristic set voltage and reset current are irreversible as the operation temperature is brought from 100?K back to 300?K, indicating the critical role of filament constituents on the switching behaviors of Ag/oxide/Pt system.

Chung, Yu-Lung; Cheng, Wen-Hui; Chen, Wei-Chih; Jhan, Sheng-An; Chen, Jen-Sue, E-mail: jenschen@mail.ncku.edu.tw [Department of Materials Science and Engineering, National Cheng Kung University, Tainan 701, Taiwan (China); Jeng, Jiann-Shing [Department of Materials Science, National University of Tainan, Tainan 700, Taiwan (China)

2014-10-28T23:59:59.000Z

356

Attribute Cr. Course Name Prereq 4 BIOL 220 (204) Principles of Biology: Organisms, Ecology, Evolution Plus Lab and discussion (Fall)  

E-Print Network [OSTI]

Attribute Cr. Course Name Prereqs Prereq 4 BIOL 220 (204) Principles of Biology: Organisms, Ecology Foundations of Learning and Memory (Fall, Spr) Beh. Elec. 3 PSYC 317 Sensation and Perception (Fall) Beh

Lewis, Robert Michael

357

Raman Spectroscopic and Visible Absorption Investigation of LiCrSi2O6 Pyroxene Under Pressure  

E-Print Network [OSTI]

symmetry.6,7 Spodumene (LiAlSi2O6) and LiCrSi2O6 behave similarly at the phase transition; both go from 6

Downs, Robert T.

358

Auger Nanoprobe analysis of presolar ferromagnesian silicate grains from primitive CR chondrites QUE 99177 and MET 00426  

E-Print Network [OSTI]

Auger Nanoprobe analysis of presolar ferromagnesian silicate grains from primitive CR chondrites inventories are dominated by ferromagnesian silicates with group 1 oxygen isotopic compositions, indicative interstellar silicates have stoichiometries between olivine and pyroxene type silicates. Although structural

359

Microbial community changes during sustained Cr(VI) reduction at the 100H site in Hanford, WA  

E-Print Network [OSTI]

at the 100H site in Hanford, WA Romy Chakraborty 1 , Eoin Lcontaminated aquifer at the Hanford (WA) 100H site in 2004.Cr(VI) reduction at Hanford, and a comparison of the

Chakraborty, Romy

2010-01-01T23:59:59.000Z

360

In situ long-term reductive bioimmobilization of Cr(VI) in groundwater using hydrogen release compound  

E-Print Network [OSTI]

100 H Area of the DOE Hanford Facility, Quantum EngineeringCr-immobilization research site at Hanford 100-H area. Wellexperiment was conducted at the Hanford Site (Washington), a

Faybishenko, B.

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Structure of multilayered Cr(Al)N/SiO{sub x} nanocomposite coatings fabricated by differential pumping co-sputtering  

SciTech Connect (OSTI)

A Cr(Al)N/38 vol. % SiO{sub x} hard coating was prepared on a (001) Si substrate at 250 °C in a differential pumping co-sputtering system, which has two chambers for radio frequency (RF) sputtering and a substrate holder rotating on the chambers. The composite coating was grown by alternate sputter-depositions from CrAl and SiO{sub 2} targets with flows of N{sub 2}+Ar and Ar at RF powers of 200 and 75 W, respectively, on transition layers grown on the substrate. Analytical electron microscopy reveled that the Cr(Al)N/SiO{sub x} coating had a multilayered structure of Cr(Al)N crystal layers ?1.6 nm thick and two-dimensionally dispersed amorphous silicon oxide (a-SiO{sub x}) particles with sizes of ?1 nm or less. The a-SiO{sub x} particles were enclosed with the Cr(Al)N layers. The coating had a low indentation hardness of ?25 GPa at room temperature, due to a high oxide fraction of 38 vol. % and a low substrate rotational speed of 1 rpm. Faster rotation and lower oxide fraction would make a-SiO{sub x} particles smaller, resulting in the formation of Cr(Al)N crystal including the very fine a-SiO{sub x} particles with small number density. They would work as obstacles for the lattice deformation of the Cr(Al)N crystals. We have fabricated a superhard coating of Cr(Al)N/17 vol. % SiO{sub x} with a hardness of 46 GPa prepared at 12 rpm.

Kawasaki, Masahiro [JEOL USA Inc., 11 Dearborn Road, Peabody, Massachusetts 01960 (United States)] [JEOL USA Inc., 11 Dearborn Road, Peabody, Massachusetts 01960 (United States); Nose, Masateru [Faculty of Art and Design, University of Toyama, 180 Futagami-machi, Takaoka 933-8588 (Japan)] [Faculty of Art and Design, University of Toyama, 180 Futagami-machi, Takaoka 933-8588 (Japan); Onishi, Ichiro [JEOL Ltd. 3-1-2 Musashino, Akishima, Tokyo 196-8558 (Japan)] [JEOL Ltd. 3-1-2 Musashino, Akishima, Tokyo 196-8558 (Japan); Shiojiri, Makoto [Kyoto Institute of Technology, Kyoto 606-8585 (Japan)] [Kyoto Institute of Technology, Kyoto 606-8585 (Japan)

2013-11-11T23:59:59.000Z

362

Cr-W-V bainitic/ferritic steel with improved strength and toughness and method of making  

DOE Patents [OSTI]

A high strength, high toughness Cr-W-V ferritic steel composition suitable for fast induced-radioactivity (FIRD) decay after irradiation in a fusion reactor comprises 2.5-3.5 wt % Cr, 2. This invention was made with Government support under contract DE-AC05-840R21400 awarded by the U.S. Department of Energy to Martin Marietta Energy Systems, Inc. and the Government has certain rights in this invention.

Klueh, Ronald L. (Knoxville, TN); Maziasz, Philip J. (Oak Ridge, TN)

1994-01-01T23:59:59.000Z

363

SciDB DBMS Research at M.I.T. Michael Stonebraker, Jennie Duggan, Leilani Battle, Olga Papaemmanouil  

E-Print Network [OSTI]

SciDB DBMS Research at M.I.T. Michael Stonebraker, Jennie Duggan, Leilani Battle, Olga Papaemmanouil {stonebraker, jennie, leilani}@csail.mit.edu, olga@cs.brandeis.edu Abstract This paper presents, and the state of the software at the time of publication. In this paper, we consider a collection of research

364

Transmission electron microscopy of RSP Fe/Cr/Mn/Mo/C alloy. [Fe-3 wt % Cr-2 wt % Mn-0. 5 wt % Mo, -0. 3 wt % C  

SciTech Connect (OSTI)

Rapid solidification processing (RSP) has been carried out on an Fe/Cr/Mn/Mo/C alloy using both electron-beam melting and piston-and-anvil techniques. Preliminary TEM results show RSP produces a refined duplex microstructure of ferrite and martensite, with a typical ferrite grain size of 0.50 - 3.0 microns. This RSP microstructure is significantly different from that observed in the conventionally austenitized and quenched alloys - a lath martensitic microstructure with thin films of retained interlath austenite. The morphological change produced by RSP is accompanied by an increase in hardness from 48R/sub c/ to 61R/sub c/ (approx. 480 to 720 VHN). It is intended to use electron-beam specimens to examine the potential beneficial effect of RSP upon sliding wear resistance and, by careful TEM studies, it will be possible to characterize the microstructure and its role in the hardness and wear behavior of the RSP alloy.

Rayment, J.J.; Thomas, G.

1982-03-01T23:59:59.000Z

365

6/11/13 Print Article: Diploma done, mom's next dream: Doctor www.ocregister.com/common/printer/view.php?db=ocregister&id=512074 1/3  

E-Print Network [OSTI]

6/11/13 Print Article: Diploma done, mom's next dream: Doctor www.ocregister.com/common/printer/view.php: Diploma done, mom's next dream: Doctor www.ocregister.com/common/printer/view.php?db=ocregister&id=512074

Barrett, Jeffrey A.

366

Reactive oxygen species mediate Cr(VI)-induced carcinogenesis through PI3K/AKT-dependent activation of GSK-3?/?-catenin signaling  

SciTech Connect (OSTI)

Cr(VI) compounds are known human carcinogens that primarily target the lungs. Cr(VI) produces reactive oxygen species (ROS), but the exact effects of ROS on the signaling molecules involved in Cr(VI)-induced carcinogenesis have not been extensively studied. Chronic exposure of human bronchial epithelial cells to Cr(VI) at nanomolar concentrations (10–100 nM) for 3 months not only induced cell transformation, but also increased the potential of these cells to invade and migrate. Injection of Cr(VI)-stimulated cells into nude mice resulted in the formation of tumors. Chronic exposure to Cr(VI) increased levels of intracellular ROS and antiapoptotic proteins. Transfection with catalase or superoxide dismutase (SOD) prevented Cr(VI)-mediated increases in colony formation, cell invasion, migration, and xenograft tumors. While chronic Cr(VI) exposure led to activation of signaling cascades involving PI3K/AKT/GSK-3?/?-catenin and PI3K/AKT/mTOR, transfection with catalase or SOD markedly inhibited Cr(VI)-mediated activation of these signaling proteins. Inhibitors specific for AKT or ?-catenin almost completely suppressed the Cr(VI)-mediated increase in total and active ?-catenin proteins and colony formation. In particular, Cr(VI) suppressed autophagy of epithelial cells under nutrition deprivation. Furthermore, there was a marked induction of AKT, GSK-3?, ?-catenin, mTOR, and carcinogenic markers in tumor tissues formed in mice after injection with Cr(VI)-stimulated cells. Collectively, our findings suggest that ROS is a key mediator of Cr(VI)-induced carcinogenesis through the activation of PI3K/AKT-dependent GSK-3?/?-catenin signaling and the promotion of cell survival mechanisms via the inhibition of apoptosis and autophagy. - Highlights: • Chronic exposure to Cr(VI) induces carcinogenic properties in BEAS-2B cells. • ROS play an important role in Cr(VI)-induced tumorigenicity of BEAS-2B cells. • PI3K/AKT/GSK-3?/?-catenin signaling involved in Cr(VI) carcinogenesis. • The inhibition of apoptosis and autophagy contributes to Cr(VI) carcinogenesis.

Son, Young-Ok; Pratheeshkumar, Poyil; Wang, Lei; Wang, Xin; Fan, Jia; Kim, Dong-Hern; Lee, Ju-Yeon; Zhang, Zhuo [Graduate Center for Toxicology, College of Medicine, University of Kentucky, Lexington, KY 40536-0305 (United States); Lee, Jeong-Chae [Graduate Center for Toxicology, College of Medicine, University of Kentucky, Lexington, KY 40536-0305 (United States); School of Dentistry and Institute of Oral Biosciences, Research Center of Bioactive Materials, Chonbuk National University, Jeonju 561-756 (Korea, Republic of); Shi, Xianglin, E-mail: xshi5@email.uky.edu [Graduate Center for Toxicology, College of Medicine, University of Kentucky, Lexington, KY 40536-0305 (United States)

2013-09-01T23:59:59.000Z

367

Letter Report Documenting Progress of Second Generation ATF FeCrAl Alloy Fabrication  

SciTech Connect (OSTI)

Development of the 2nd generation ATF FeCrAl alloy has been initiated, and a candidate alloy was selected for trial tube fabrication through hot-extrusion and gun-drilling processes. Four alloys based on Fe-13Cr-4.5Al-0.15Y in weight percent were newly cast with minor alloying additions of Mo, Si, Nb, and C to promote solid-solution and second-phase precipitate strengthening. The alloy compositions were selected with guidance from computational thermodynamic tools. The lab-scale heats of ~ 600g were arc-melted and drop-cast, homogenized, hot-forged and -rolled, and then annealed producing plate shape samples. An alloy with Mo and Nb additions (C35MN) processed at 800°C exhibits very fine sub-grain structure with the sub-grain size of 1-3?m which exhibited more than 25% better yield and tensile strengths together with decent ductility compared to the other FeCrAl alloys at room temperature. It was found that the Nb addition was key to improving thermal stability of the fine sub-grain structure. Optimally, grains of less than 30 microns are desired, with grains up to and order of magnitude in desired produced through Nb addition. Scale-up effort of the C35MN alloy was made in collaboration with a commercial cast company who has a capability of vacuum induction melting. A 39lb columnar ingot with ~81mm diameter and ~305mm height (with hot-top) was commercially cast, homogenized, hot-extruded, and annealed providing 10mm-diameter bar-shape samples with the fine sub-grain structure. This commercial heat proved consistent with materials produced at ORNL at the lab-scale. Tubes and end caps were machined from the bar sample and provided to another work package for the ATF-1 irradiation campaign in the milestone M3FT-14OR0202251.

Yamamoto,, Y. [ORNL] [ORNL; Yang, Y. [ORNL] [ORNL; Field, K. G. [ORNL] [ORNL; Terrani, K. [ORNL] [ORNL; Pint, B. A. [ORNL] [ORNL; Snead, L. L. [ORNL] [ORNL

2014-06-10T23:59:59.000Z

368

CHARACTERIZATION OF PRESOLAR MATERIAL IN THE CR CHONDRITE NORTHWEST AFRICA 852  

SciTech Connect (OSTI)

We investigated the inventory of presolar silicate, oxide, and silicon carbide (SiC) grains in the CR2 chondrite Northwest Africa (NWA) 852. Thirty-one O-anomalous grains were detected: 24 were identified as silicates ({approx}78 ppm); the remaining 7 are Al-rich oxides ({approx}38 ppm). NWA 852 is the first C2 chondrite containing O-anomalous presolar dust in concentrations comparable to other more primitive meteorites. Eight presolar SiC grains have been found, representing the highest abundance ({approx}160 ppm) observed so far in primitive meteorites. {sup 15}N-enriched matter is also present, although very heterogeneously distributed. Twenty-six of the O-anomalous grains are enriched in {sup 17}O, originating from the outflows of low-mass asymptotic giant branch (AGB) stars. We calculate a silicate/oxide abundance ratio of {approx}2, which indicates a higher degree of aqueous alteration than observed for other presolar-grain-rich meteorites. NWA 852 thus stands between the presolar-grain-rich CR3 chondrites (MET 00426, QUE 99177) and CR2 chondrites with low presolar grain abundances (Renazzo, NWA 530). We calculate an initial presolar silicate abundance of {approx}800 ppm for NWA 852, if silicate destruction by aqueous alteration is taken into account. Transmission electron microscope (TEM) investigation of one presolar Al-rich grain of an AGB star origin revealed that the grain mainly consists of a single crystal of hibonite with slightly varying orientations. A distinct subgrain (d < 100 nm) with a Ca/Ti ratio of {approx}1 is located in the central region, most likely indicating a perovskite-like phase. Our data suggest this phase to be a primary condensate and not an alteration product.

Leitner, J.; Hoppe, P. [Max Planck Institute for Chemistry, Particle Chemistry Department, P.O. Box 3060, 55020 Mainz (Germany); Vollmer, C. [Institut fuer Mineralogie, Westfaelische Wilhelms-Universitaet, 48149 Muenster (Germany); Zipfel, J., E-mail: jan.leitner@mpic.de [Forschungsinstitut und Naturmuseum Senckenberg, Sektion Meteoritenforschung, Senckenberganlage 25, 60325 Frankfurt (Germany)

2012-01-20T23:59:59.000Z

369

Microstructural examination of V-(4-5%) Cr-(4-5%)Ti irradiated in X530  

SciTech Connect (OSTI)

Microstructural examination results are reported for two heats of V-(4-5%)Cr-(4-5%)Ti irradiated in the X530 experiment to {approximately}400{degrees}C to provide an understanding of the microstructural evolution that may be associated with degradation of mechanical properties. Fine precipitates were observed in high density intermixed with small defect clusters for all conditions examined following the irradiation. The irradiation-induced precipitation does not appear to be affected by preirradiation heat treatment at 950-1125{degrees}C. There was no evidence for a significant density of large (diameter >10 nm) dislocation loops or network dislocations.

Gelles, D.S. [Pacific Northwest National Lab., Richland, WA (United States); Chung, H.M. [Argonne Natinonal Lab., IL (United States)

1997-08-01T23:59:59.000Z

370

Determination of mechanical properties of Ni-Cr-P amorphous alloys  

E-Print Network [OSTI]

DETERMINATION OF MECHANICAL PROPERTIES OF Ni-Cr-P AMORPHOUS ALLOYS A Thesis by SWAROOP KUMAR R. KONDLAPUDI Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree.... Kondlapudi, B. E. , Qsmania University Co-Chairs of Advisory Committee : Dr. A. wolfenden Dr. R. Griffin A study of the mechanical properties of Ni80 xCrxPgp amorphous alloys (x = 0 to 40 at% in steps of 5. 0) has been undertaken at Texas A&M University...

Kondlapudi, Swaroop Kumar R

2012-06-07T23:59:59.000Z

371

Oxidation Characteristics of Fe-18Cr-18Mn-stainless alloys  

SciTech Connect (OSTI)

Air oxidation studies of Fe-18Cr-18Mn stainless steels were conducted at 525°C, 625°C, and 725°C. Alloys were evaluated with respect to changes in oxidation properties as a result of interstitial additions of nitrogen and carbon and of minor solute additions of silicon, molybdenum, and nickel. Interstitial concentrations possibly had a small, positive effect on oxidation resistance. Minor solute additions significantly improved oxidation resistance but could also reduce interstitial solubility resulting in formation of chromium carbides. Loss of solute chromium resulted in a slight reduction in oxidation protection. Oxidation lasting over 500 hours produced a manganese rich, duplex oxide structure: an outer sesquioxide and an inner spinel oxide.

James Rawers

2010-10-01T23:59:59.000Z

372

Audit Report: CR-B-95-06 | Department of Energy  

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373

Audit Report: CR-B-96-01 | Department of Energy  

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374

Audit Report: CR-B-97-04 | Department of Energy  

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375

Audit Report: CR-B-98-01 | Department of Energy  

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376

Audit Report: CR-B-98-02 | Department of Energy  

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377

Audit Report: CR-FS-96-03 | Department of Energy  

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378

NUREG/CR-0413 ANLlES-67 Distribution Code: RE ARGONNE NATIONAL LABORATORY  

Office of Legacy Management (LM)

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379

Grain boundary depletion and migration during selective oxidation of Cr in  

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380

Audit Report: CR-B-01-01 | Department of Energy  

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Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
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381

Magnetization dynamics and interface studies in ion-beam sputtered Si/CoFeB(8)/MgO(4)/CoFeB(8)/Ta(5) structures  

SciTech Connect (OSTI)

The interface roughness, Boron distribution in bulk CoFeB and at interface, Gilbert damping constant (?), and inhomogeneous broadening in ion-beam sputtered Si/CoFeB(8)/MgO(4)/CoFeB(8)/Ta(5) structures are found to be sensitive to the MgO growth process. The ion-assist and reactive growth processes that result in sharper interfaces of width ?0.5?nm lead to smaller ? of 0.0050?±?0.0003 and 0.0060?±?0.0002 and inhomogeneous broadening ?H{sub 0} of 3?±?0.3 and 1?±?0.3?Oe, respectively. On the other hand, the post-oxidation method results in rough interface and higher retention of Boron in CoFeB leading to higher values for ? and ?H{sub 0} as 0.0080?±?0.0006 and 5?±?0.3?Oe, respectively.

Raju, M.; Behera, Nilamani; Pandya, Dinesh K., E-mail: dkpandya@physics.iitd.ac.in; Chaudhary, Sujeet [Thin Film Laboratory, Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016 (India)

2014-05-07T23:59:59.000Z

382

Optical breakdown threshold in nanosecond high repetition second harmonic generation by periodically poled Mg-doped LiTaO{sub 3} crystal  

SciTech Connect (OSTI)

Our study shows that a local temperature increase of ?1 K in the crystal lattice caused by second harmonic generation (SHG) and two-photon absorption of 532 nm radiation at the rear of periodically poled stoichiometric LiTaO{sub 3} crystal by changing spontaneous polarization induces a pyroelectric field ?10 kV/cm, accelerating free electrons to an energy of ?10 eV, followed by optical breakdown and crystal damage. Theoretical analysis leads to an explicit expression for the threshold laser fluence of optical breakdown giving ?1.2 J/cm{sup 2} for 1064 nm input radiation in 6.8 kHz pulsed SHG operation, agreeing well with the experimentally found value ?1.32 J/cm{sup 2}.

Louchev, Oleg A.; Wada, Satoshi [Center for Advanced Photonics, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan)] [Center for Advanced Photonics, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Hatano, Hideki; Kitamura, Kenji [Division of Environment and Energy Materials, National Institute for Materials Science (NIMS) 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [Division of Environment and Energy Materials, National Institute for Materials Science (NIMS) 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)

2013-08-26T23:59:59.000Z

383

Emissions and engine performance from blends of soya and canola methyl esters with ARB {number_sign}2 diesel in a DCC 6V92TA MUI engine  

SciTech Connect (OSTI)

A Detroit Diesel 6V92TA MUI engine was operated on several blends of EPA No. 2 diesel, California ARB No. 2 diesel, soya methyl ester (SME) and canola methyl ester (CME). Various fuels and fuel blend characteristics were determined and engine emissions from these fuels and blends were compared. Increasing percentages of SME and CME blended with either ARB or EPA diesels led to increased emissions of NO{sub x}, CO{sub 2} and soluble particulate matter. Also noted were reductions in total hydrocarbons, CO and insoluble particulate matter. Chassis dynamometer tests conducted on a 20/80 SME/ARB blend showed similar emissions trends. The data suggest that certain methyl ester/No. 2 diesel blends in conjunction with delays in engine timing and technologies that reduce the soluble fraction of particulate emissions merit further exploration as emissions reducing fuel options for North American mass transits (except in California, which mandates ARB diesel).

Spataru, A.; Romig, C.

1995-12-31T23:59:59.000Z

384

Emissions and engine performance from blends of soya and canola methyl esters with ARB No. 2 diesel in a DDC 6V92TA MUI engine  

SciTech Connect (OSTI)

A Detroit Diesel 6V92TA MUI engine was operated on several blends of EPA No. 2 diesel, soya methyl ester (SME) and canola methyl ester (CME). Various fuels and fuel blend characteristics were determined and engine emissions from these fuels and blends were compared. Increasing percentages of SME and CME blended with either ARB or EPA diesels led to increased emissions of NO{sub x}, CO{sub 2} and soluble particulate matter. Also noted were reductions in total hydrocarbons, CO and insoluble particulate matter. Chassis dynamometer tests conducted on a 20/80 SME/ARB blend showed similar emission trends. The data suggest that certain methyl ester/No. 2 diesel blends in conjunction with technologies that reduce the soluble fraction of particulate emissions merit further exploration as emissions reducing fuel options for North American mass transit sectors (except California, which mandates ARB diesel).

Spataru, A.; Romig, C. [ADEPT Group, Inc., Los Angeles, CA (United States)

1995-11-01T23:59:59.000Z

385

Permeable Reactive Biobarriers for In Situ Cr(VI) Reduction: Bench Scale Tests Using Cellulomonas sp. Strain ES6  

SciTech Connect (OSTI)

Chromate (Cr(VI)) reduction studies were performed in bench scale flow columns using the fermentative subsurface isolate Cellulomonas sp. strain ES6. In these tests, columns packed with either quartz sand or hydrous ferric oxide (HFO)-coated quartz sand, were inoculated with strain ES6 and fed nutrients to stimulate growth before nutrient-free Cr(VI) solutions were injected. Results show that in columns containing quartz sand, a continuous inflow of 2 mg/L Cr(VI) was reduced to below detection limits in the effluent for durations of up to 5.7 residence times after nutrient injection was discontinued proving the ability of strain ES6 to reduce chromate in the absence of an external electron donor. In the HFO-containing columns, Cr(VI) reduction was significantly prolonged and effluent Cr(VI) concentrations remained below detectable levels for periods of up to 66 residence times after nutrient injection was discontinued. Fe was detected in the effluent of the HFO-containing columns throughout the period of Cr(VI) removal indicating that the insoluble Fe(III) bearing solids were being continuously reduced to form soluble Fe(II) resulting in prolonged abiotic Cr(VI) reduction. Thus, growth of Cellulomonas within the soil columns resulted in formation of permeable reactive barriers that could reduce Cr(VI) and Fe(III) for extended periods even in the absence of external electron donors. Other bioremediation systems employing Fe(II)-mediated reactions require a continuous presence of external nutrients to regenerate Fe(II). After depletion of nutrients, contaminant removal within these systems occurs by reaction with surface-associated Fe(II) that can rapidly become inaccessible due to formation of crystalline Fe-minerals or other precipitates. The ability of fermentative organisms like Cellulomonas to reduce metals without continuous nutrient supply in the subsurface offers a viable and economical alternative technology for in situ remediation of Cr(VI)-contaminated groundwater through formation of permeable reactive biobarriers (PRBB).

Sridhar Viamajala; Brent M. Peyton; Robin Gerlach; Vaideeswaran; William A. Apel; James N. Petersen

2008-12-01T23:59:59.000Z

386

Corrosion property of 9Cr-ODS steel in nitric acid solution for spent nuclear fuel reprocessing  

SciTech Connect (OSTI)

Corrosion tests of oxide dispersion strengthened with 9% Cr (9Cr-ODS) steel, which is one of the desirable materials for cladding tube of sodium-cooled fast reactors, in pure nitric acid solution, spent FBR fuel solution, and its simulated solution were performed to understand the corrosion behavior in a spent nuclear fuel reprocessing. In this study, the 9Cr-ODS steel with lower effective chromium content was evaluated to understand the corrosion behavior conservatively. As results, the tube-type specimens of the 9Cr-ODS steels suffered severe weight loss owing to active dissolution at the beginning of the immersion test in pure nitric acid solution in the range from 1 to 3.5 M. In contrast, the weight loss was decreased and they showed a stable corrosion in the higher nitric acid concentration, the dissolved FBR fuel solution, and its simulated solution by passivation. The corrosion rates of the 9Cr-ODS steel in the dissolved FBR fuel solution and its simulated solution were 1-2 mm/y and showed good agreement with each other. The passivation was caused by the shift of corrosion potential to noble side owing to increase in nitric acid concentration or oxidative ions in the dissolved FBR fuel solution and the simulated spent fuel solution. (authors)

Takeuchi, M.; Koizumi, T. [Japan Atomic Energy Agency, Tokai-mura, Naka-gun, Ibaraki 319-1195 (Japan); Inoue, M.; Koyama, S.I. [Japan Atomic Energy Agency, Oarai-machi, Higashi-ibaraki-gun, Ibaraki 311-1393 (Japan)

2013-07-01T23:59:59.000Z

387

Clinch River - Environmental Restoration Program (CR-ERP) study, Ambient water toxicity  

SciTech Connect (OSTI)

Clinch River - Environmental Restoration Program (CR-ERP) personnel and Tennessee Valley Authority (TVA) personnel conducted a study during the week of January 25-February 1, 1994, as described in the Statement of Work (SOW) document. The organisms specified for testing were larval fathead minnows, Pimephales promelas, and the daphnid, Ceriodaphnia dubia. Surface water samples were collected by TVA Field Engineering personnel from Clinch River Mile 9.0, Poplar Creek Mile 1.0, and Poplar Creek Mile 2.9 on January 24, 26, and 28. Samples were partitioned (split) and provided to the CR-ERP and TVA toxicology laboratories for testing. Exposure of test organisms to these samples resulted in no toxicity (survival or growth) to fathead minnows; however, toxicity to daphnids (significantly reduced reproduction) was demonstrated in undiluted samples from Poplar Creek Mile 1.0 in testing conducted by TVA based on hypothesis testing of data. Point estimation (IC{sub 25}) analysis of the data, however, showed no toxicity in PCM 1.0 samples.

Simbeck, D.J.

1997-06-01T23:59:59.000Z

388

Solidification characterization of a new rapidly solidified Ni-Cr-Co based superalloy  

SciTech Connect (OSTI)

The solidification characterization of a new rapidly solidified Ni-Cr-Co based superalloy prepared by plasma rotating electrode process was investigated by means of optical microscope, scanning electron microscope, and transmission electron microscope. The results show that the solidification microstructure changes from dendrites to cellular and microcrystal structures with decreasing powder size. The elements of Co, Cr, W and Ni are enriched in the dendrites, while Mo, Nb and Ti are higher in the interdendritic regions. The relationships between powder size with the average solid-liquid interface moving rate, the average interface temperature gradient and the average cooling rate are established. Microsegregation is increased with larger powder size. The geometric integrity of MC Prime type carbides in the powders changes from regular to diverse with decreasing powder size. The morphology and quantity of carbides depend on the thermal parameters and non-equilibrium solute partition coefficients during rapid solidification. - Highlights: Black-Right-Pointing-Pointer The relations of solidification thermal parameters with powder size are established. Black-Right-Pointing-Pointer The relation of non-equilibrium solute partition with powder size is investigated. Black-Right-Pointing-Pointer The solidification microstructure is related to thermal parameters. Black-Right-Pointing-Pointer The segregation behavior is linked to non-equilibrium partition coefficients. Black-Right-Pointing-Pointer The morphology and quantity of carbides depend on the above combined factors.

Wu, Kai, E-mail: wk-ustb@163.com [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China)] [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Liu, Guoquan [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China) [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083 (China); Hu, Benfu [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China)] [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China); Li, Feng [Department of Materials Science and Metallurgy, University of Cambridge, Cambridge CB2 3QZ (United Kingdom)] [Department of Materials Science and Metallurgy, University of Cambridge, Cambridge CB2 3QZ (United Kingdom); Zhang, Yiwen [School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083 (China) [School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083 (China); High Temperature Materials Research Institution, CISRI, Beijing 100081 (China); Tao, Yu; Liu, Jiantao [High Temperature Materials Research Institution, CISRI, Beijing 100081 (China)] [High Temperature Materials Research Institution, CISRI, Beijing 100081 (China)

2012-11-15T23:59:59.000Z

389

Localized Corrosion of a Neutron Absorbing Ni-Cr-Mo-Gd Alloy  

SciTech Connect (OSTI)

The National Spent Nuclear Fuel Program, located at the Idaho National Laboratory (INL), has developed a new nickel-chromium-molybdenum-gadolinium structural alloy for storage and long-term disposal of spent nuclear fuel (SNF). The new alloy will be used for SNF storage container inserts for nuclear criticality control. Gadolinium has been chosen as the neutron absorption alloying element due to its high thermal neutron absorption cross section. This alloy must be resistant to localized corrosion when exposed to postulated Yucca Mountain in-package chemistries. The corrosion resistance properties of three experimental heats of this alloy are presented. The alloys performance are be compared to Alloy 22 and borated stainless steel. The results show that initially the new Ni-Cr-Mo-Gd alloy is less resistant to corrosion as compared to another Ni-Cr-Mo-Gd alloy (Alloy 22); but when the secondary phase that contains gadolinium (gadolinide) is dissolved, the alloy surface becomes passive. The focus of this work is to qualify these gadolinium containing materials for ASME code qualification and acceptance in the Yucca Mountain Repository.

R.E. Mizia; T. E. Lister; P. J. Pinhero; T. L. Trowbridge

2005-04-01T23:59:59.000Z

390

Discovery of Optical Bursts from MS1603.6+2600 = UW CrB  

E-Print Network [OSTI]

We report the discovery of several optical burst-like events from the low-mass X-ray binary MS1603.6+2600 (UW CrB). The events last for a few tens of seconds, exhibit a very fast rise and slow decay, and involve optical brightening of a factor of 2-3. The flares appear distinct from the lower level flickering and instead strongly resemble reprocessed type-I X-ray bursts as seen in a number of other neutron star low-mass X-ray binaries. In conjunction with the previously reported candidate X-ray burst, these confirm that the compact object in UW CrB is a neutron star. We examine the optical burst brightness and recurrence times and discuss how the nature of the system can be constrained. We conclude that the source is most likely an accretion disk corona source at an intermediate distance, rather than a nearby quiescent system or very distant dipper.

R. I. Hynes; E. L. Robinson; E. Jeffery

2004-05-11T23:59:59.000Z

391

Demonstrations of diode-pumped and grating-tuned ZnSe:Cr{sup 2+} lasers  

SciTech Connect (OSTI)

Within the last few years, divalent-transition-metal-doped II-VI material class has been proposed as source of new tunable mid-IR lasers. Cr{sup 2+} is a prime laser candidate on account of its high luminescence quantum yield and the expectation that ESA would be absent. The first ZnSe:Cr{sup 2+} laser demonstrations were conducted in an end-pumped geometry with a tightly focused (0.2 mm spot) MgF{sub 2}-Co{sup 2+} laser beam, for a peak pump intensity well over 100 kW/cm{sup 2}, so laser threshold was easily reached. Grating tuning experiments were done by replacing the cavity high-reflector with a diffraction grating. The diode array was removed and pump beam from a MgF{sub 2}:Co{sup 2+} laser was focused onto the crystal using the same cylindrical lens. Output wavelengths were checked with a monochromator. The long-wavelength limit of operation was 2799 nm. Short-wavelength cutoff was 2134 nm; even though the emission cross section remains substantial, self-absorption inhibits laser operation.

Page, R.H.; Skidmore, J.A.; Schaffers, K.I.; Beach, R.J.; Payne, S.A.; Krupke, W.F.

1996-09-01T23:59:59.000Z

392

Effect of prior cold work on age hardening of Cu-3Ti-1Cr alloy  

SciTech Connect (OSTI)

The influence of 50%, 75% and 90% cold work on the age hardening behavior of Cu-3Ti-1Cr alloy has been investigated by hardness and tensile tests, and light optical and transmission electron microscopy. Hardness increased from 118 Hv in the solution-treated condition to 373 Hv after 90% cold work and peak aging. Cold deformation reduced the peak aging time and temperature of the alloy. The yield strength and ultimate tensile strength reached a maximum of 1090 and 1110 MPa, respectively, following 90% deformation and peak aging. The microstructure of the deformed alloy exhibited elongated grains and deformation twins. The maximum strength on peak aging was obtained due to precipitation of the ordered, metastable and coherent {beta}'-Cu{sub 4}Ti phase, in addition to high dislocation density and deformation twins. Over-aging resulted in decreases in hardness and strength due to the formation of incoherent and equilibrium {beta}-Cu{sub 3}Ti phase in the form of a cellular structure. However, the morphology of the discontinuous precipitation changed to a globular form on high deformation. The mechanical properties of Cu-3Ti-1Cr alloy are superior to those of Cu-2.7Ti, Cu-3Ti-1Cd and the commercial Cu-0.5Be-2.5Co alloys in the cold-worked and peak-aged condition.

Markandeya, R. [Department of Metallurgical Engineering, College of Engineering, Jawaharlal Nehru Technological University, Kukatpally, Hyderabad-500 072 (India); Nagarjuna, S. [Defence Metallurgical Research Laboratory, Kanchanbagh, Hyderabad-500 058 (India)]. E-mail: snagarjuna1@rediffmail.com; Sarma, D.S. [Department of Metallurgical Engineering, Institute of Technology, Banaras Hindu University, Varanasi-221 005 (India)

2006-12-15T23:59:59.000Z

393

Cation ordering transformations in Ba(Mg{sub 1/3}Ta{sub 2/3})O{sub 3}-BaZrO{sub 3} perovskite solid solutions  

SciTech Connect (OSTI)

The effect of the substitution of BaZrO{sub 3} on the cation ordering in Ba(Mg{sub 1/3}Ta{sub 2/3})O{sub 3} was studied using TEM and X-ray and neutron diffraction. Almost no solubility of Zr was found in the 1:2 ordered, trigonal structure of the Ba(Mg{sub 1/3}Ta{sub 2/3})O{sub 3} end-member (P{bar 3}m1), and a transformation to a 1:1 ordered, cubic (Fm{bar 3}m) phase with a = 2a{sub per} occurs for substitution levels between {approximately}10 and 25 mol% BaZrO{sub 3}. The structure of this Ba({beta}{prime}{sub 1/2}{beta}{double_prime}{sub 1/2})O{sub 3}-type phase consists of two distinct octahedral sites, {beta}{prime} and {beta}{double_prime}. The occupancies of the two cation positions, refined using the Rietveld method, were found to be consistent with a random site model in which {beta}{double_prime} is occupied by Ta, and {beta}{prime} by a random distribution of the remaining cations. The homogeneity range of the 1:1 solid solutions predicted by this model, Ba{l_brace}[Mg{sub (2{minus}y)/3} Ta{sub (1{minus}2y)/3} Zr{sub y}]{sub 1/2}[Ta]{sub 1/2}{r_brace}O{sub 3} (0.0 < y {le} 0.5), is in excellent agreement with that observed experimentally.

Chai, L.; Akbas, M.A.; Davies, P.K. [Univ. of Pennsylvania, Philadelphia, PA (United States). Dept. of Materials Science and Engineering] [Univ. of Pennsylvania, Philadelphia, PA (United States). Dept. of Materials Science and Engineering; Parise, J.B. [Univ. of New York, Stony Brook, NY (United States). Dept. of Earth and Space Sciences] [Univ. of New York, Stony Brook, NY (United States). Dept. of Earth and Space Sciences

1997-09-01T23:59:59.000Z

394

Ab initio study on noncompensated CrO codoping of GaN for enhanced solar energy conversion  

SciTech Connect (OSTI)

We describe a novel photocatalyst obtained by codoping GaN with CrO, according to a new "noncompensated" codoping concept based on first-principles calculations. The approach enables controllable narrowing of the GaN band gap with significantly enhanced carrier mobility and photocatalytic activity in the visible light region and thus offers immense potential for application in solar energy conversion, water splitting, and a variety of solar-assisted photocatalysis. Our calculations indicate that the formation energy for the cation doping is greatly reduced by noncompensated codoping with an anion. Although Cr doping alone can split the band gap with the formation of an intermediate band, the mobility is low due to carrier trapping by the localized states. The first-principles calculations also demonstrate that CrO codoping of GaN shifts the Fermi level into the conduction band resulting in high carrier density and mobility.

Pan, Hui [ORNL; Gu, Baohua [ORNL; Eres, Gyula [ORNL; Zhang, Zhenyu [ORNL

2010-03-01T23:59:59.000Z

395

Data:22824429-7771-47b5-8e7f-4773db5810af | Open Energy Information  

Open Energy Info (EERE)

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396

Spectroscopic Analysis of the DAB White Dwarf PG 1115+166: An Unresolved DA + DB Degenerate Binary  

E-Print Network [OSTI]

A spectroscopic analysis of the DAB white dwarf PG 1115+166 is presented. The observed hydrogen and helium line profiles are shown to be incompatible with model spectra calculated under the assumption of homogeneous or stratified chemical compositions. In contrast, an excellent fit to the optical spectrum of PG 1115+166 can be achieved if the object is interpreted as an unresolved double degenerate composed of a hydrogen-line DA star and a helium-line DB star. The atmospheric parameters obtained from the best fit are Teff=22,090 K and log g=8.12 for the DA star, Teff=16,210 K and log g=8.19 for the DB star. This binary interpretation is consistent with the results recently reported by Burleigh et al. that PG 1115+166 also exhibits radial velocity variations. The implications of this discovery with respect to the DAB spectral class are discussed.

P. Bergeron; James Liebert

2001-10-25T23:59:59.000Z

397

Phase relations of the Li{sub 2}O-Ta{sub 2}O{sub 5}-B{sub 2}O{sub 3} and Li{sub 2}O-WO{sub 3}-B{sub 2}O{sub 3} systems and promising nonlinear optical compounds in K{sub 2}O-Ta{sub 2}O{sub 5}-B{sub 2}O{sub 3} system  

SciTech Connect (OSTI)

The subsolidus phase equilibria of the Li{sub 2}O-Ta{sub 2}O{sub 5}-B{sub 2}O{sub 3}, K{sub 2}O-Ta{sub 2}O{sub 5}-B{sub 2}O{sub 3} and Li{sub 2}O-WO{sub 3}-B{sub 2}O{sub 3} systems have been investigated mainly by means of the powder X-ray diffraction method. Two ternary compounds, KTaB{sub 2}O{sub 6} and K{sub 3}Ta{sub 3}B{sub 2}O{sub 12} were confirmed in the system K{sub 2}O-Ta{sub 2}O{sub 5}-B{sub 2}O{sub 3}. Crystal structure of compound KTaB{sub 2}O{sub 6} has been refined from X-ray powder diffraction data using the Rietveld method. The compound crystallizes in the orthorhombic, space group Pmn2{sub 1} (No. 31), with lattice parameters a = 7.3253(4) A, b = 3.8402(2) A, c = 9.3040(5) A, z = 2 and D{sub calc} = 4.283 g/cm{sup 3}. The powder second harmonic generation (SHG) coefficients of KTaB{sub 2}O{sub 6} and K{sub 3}Ta{sub 3}B{sub 2}O{sub 12} were five times and two times as large as that of KH{sub 2}PO{sub 4} (KDP), respectively.

Cai Gemei; Wang, W.Y.; Li, M. [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, P.O. Box 603, Beijing 100080 (China); Lou, Y.F. [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, P.O. Box 603, Beijing 100080 (China); Center of Condensed Matter and Materials Physics, School of Sciences, Beihang University, Beijing 100083 (China); Sun, Y.P. [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, P.O. Box 603, Beijing 100080 (China); Chen, X.L. [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, P.O. Box 603, Beijing 100080 (China)], E-mail: chenx29@aphy.iphy.ac.cn

2009-01-08T23:59:59.000Z

398

Microbial community changes during sustained Cr(VI) reduction at the 100H site in Hanford, WA  

SciTech Connect (OSTI)

Hexavalent Chromium is a widespread contaminant found in soil, sediment, and groundwater. In order to stimulate microbially-mediated reduction of Cr(VI), a poly-lactate compound (HRC) was injected into the Chromium-contaminated aquifer at the Hanford (WA) 100H site in 2004. Cr(VI) concentrations rapidly declined to below the detection limit and remained so for more than three years after injection. Based on the results of the bacterial community composition using high-density DNA 16S rRNA gene microarrays, we observed the community to transition through denitrifying, ironreducing and sulfate-reducing populations. As a result, we specifically focused isolation efforts on three bacterial species that were significant components of the community. Positive enrichments in defined anaerobic media resulted in the isolation of an iron-reducing Geobacter metallireducens-like isolate, a sulfate-reducing Desulfovibrio vukgaris-like strain and a nitrate-reducing Pseudomonas stutzeri-like isolate among several others. All of these isolates were capable of reducing Cr(VI) anoxically and have been submitted for genome sequencing to JGI. To further characterize the microbial, and geochemical mechanisms associated with in situ Cr(VI) reduction at the site, additional HRC was injected in 2008. The goal was to restimulate the indigenous microbial community and to regenerate the reducing conditions necessary for continued Cr(VI) bio-immobilization in the groundwater. Analysis of the microbial populations post-injection revealed that they recovered to a similar density as after the first injection in 2004. In this study, we present the results from our investigation into microbially-mediated Cr(VI) reduction at Hanford, and a comparison of the microbial community development following two HRC injections four years apart.

Chakraborty, Romy; Brodie, Eoin L; Faybishenko, Boris; Piceno, Yvette M; Tom, Lauren; Choudhuri, Swati; Beller, Harry R; Liu, Jenny; Torok, Tamas; Joyner, Dominique C; Joachimiak, Marcin P; Zhou, Aifen; Van Nostrand, Joy D; Zhou, Joe; Long, Phil E; Newcomer, Darrell R; Andersen, Gary L; Hazen, Terry C.

2010-05-17T23:59:59.000Z

399

Temperature dependence of dynamic Young's modulus and internal friction in three plasma sprayed NiCrAlY coating alloys  

E-Print Network [OSTI]

TEMPERATURE DEPENDENCE OF DYNAM'IIC YOUNG'S MODULUS AND INTERNAL FRICTION IN THREE PLASMA SPRAYED NiCrAlY COATING -ALLOYS A Thesis LLOYD STEVEN COOK Submitted to the 08ice of Graduate Studies of Texas AE M University in part. al full...'illment of the requirement for the degree of MASTER OF SCIENCE August 1989 Itiajor Subject: l'dechanical Engineering TEMPERATURE DEPENDENCE OF DYNAMIC YOUNG'S MODULUS AND INTERNAL FRICTION IN THREE PLASMA SPRAYED NiCrAIY COATING ALLOYS A Thesis by LLOYD STEVEN COOK...

Cook, Lloyd Steven

1989-01-01T23:59:59.000Z

400

Can one identify the intrinsic structure of the yrast states in {sup 48}Cr after the backbending?  

SciTech Connect (OSTI)

The backbending phenomenon in {sup 48}Cr has been investigated using the recently developed projected configuration interaction (PCI) method, in which the deformed intrinsic states are directly associated with shell model wave functions. Two previous explanations, (i) K=0 band crossing and (ii) K=2 band crossing, have been reinvestigated using PCI, and it was found that both explanations can successfully reproduce the experimental backbending. The PCI wave functions in the pictures of K=0 band crossing and K=2 band crossing are highly overlapped. We conclude that there are no unique intrinsic states associated with the yrast states after backbending in {sup 48}Cr.

Gao Zaochun; Chen, Y. S.; Chen, Y. J. [China Institute of Atomic Energy P.O. Box 275-10, Beijing 102413 (China); Horoi, Mihai [Department of Physics, Central Michigan University, Mount Pleasant, Michigan 48859 (United States); Tuya [College of Physics Science and Technology, Shenyang Normal University, ShenYang 110034 (China)

2011-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Development of Low Cost Membranes (Ta, Nb & Cellulose Acetate) for H{sub 2}/CO{sub 2} Separation in WGS Reactors  

SciTech Connect (OSTI)

The main aim of this work is to synthesize low temperature bimetallic nanocatalysts for Water Gas Shift reaction (WGS) for hydrogen production from CO and steam mixture; and develop low-cost metal (Nb/Ta)/ceramic membranes for H{sub 2} separation and Cellulose Acetate membranes for CO{sub 2} separation. Cu-Ni-Ce/alumina, Fe-Ni-Ce/alumina granular WGS catalysts incorporating metal oxide nanoparticles into alumina support were prepared using sol-gel/oil-drop methods. The catalysts were characterized by Powder X-ray Diffractometer (PXRD), Scanning Electron Microscope (SEM), Differential Thermal Analyzer (DTA), Thermal Gravitational Analyzer (TGA), and Brunauer, Emmett and Teller (BET) techniques. TGA shows sharp weight loss at approximately 215°C and DTA shows dehydration of metal hydroxides between 200°C and 250°C. The PXRD spectra show an increase in crystallinity as a result of heating to 1000°C, and indicating a fine dispersion of the metal oxide nanoparticles in alumina supports during the sol-gel synthesis and calcination at 450°C. BET analysis indicated a mesoporous structure of the granules with high surface area. A gas-phase dynamic flow reactor is used to optimize the reaction temperatures. A gas-phase batch reactor was used to obtain kinetic data and the parameters for maximum CO conversion. In Cu-Ni-Ce/alumina category, Cu(0%)Ni(10%)Ce(11%) was found to be the best WGS catalyst among six Low Temperature Shift (LTS) catalysts with optimum temperatures between 200-300�°C, while Ni(5%)Cu(5%)Ce(11%) was found to be the best among four High Temperature Shift (HTS) catalysts with optimum temperature between 350-400°C. In the Fe-Ni-Ce/alumina category catalysts, Fe(8%)Ni(0%)Ce(8%)/alumina and Fe(6%)Ni(2%)Ce(8%)/alumina catalysts showed optimum WGS reaction temperature below 150°C. All Ni(8-x%)Fe(x%)Ce(8%) had lower WGS reaction efficiencies compared to Ni(8-x%)Cu(x%)Ce(8%). Metal (Nb or Ta)/ceramic membranes for hydrogen separation from the WGS reaction gas products have been prepared using a) sputtering and b) aluminothermic techniques. A polyvinyl-glass permeability tester was used with a gas chromatograph (GC) for H{sub 2}/CO permeability testing. Nb films showed a higher permeability than Ta at a given disk porosity. The aluminothermically deposited membranes have higher H{sub 2} permeability compared to the sputtered films, and Nb-film coated disks showed lower H{sub 2} permeability than Ta-film. A three-stage prototype stainless steel reactor with integrated housing for 1) WGS reaction catalysts, 2) H{sub 2}/CO{sub 2} separation metal/ceramic or metal/asbestos membranes, and 3) CO/CO{sub 2} separation cellulose acetate /filter-paper membranes has been designed and tested to have capabilities to perform WGS reactions at temperatures up to 400°C and withstand gas pressures up to 15 bars. The cracking of ceramic disks and gas leaks were successfully prevented by replacing ceramic disks with asbestos sheets that can easily withstand 400°C. Kinetic studies of H{sub 2} and CO permeabilities were performed through the single and double layer Nb and Ta membranes. Cellulose acetate (CA) films with 25% triethyl citrate (TEC) as plasticizer were prepared for H{sub 2}/CO/CO{sub 2} gas separation with varying thickness of the films by acetone solutions at different concentrations and by dip-coating onto filter papers. The AFM analysis of the CA membrane showed that the uniform coating had fewer and smaller pores as the film thickness increased, and corroborated by gas permeability studies. The CO{sub 2} permeability has decreased faster than CO permeability with the CA/TEC membrane thickness, and findings support that the CA membrane could be used to entrap CO{sub 2}. Several CA/TEC membranes were also staked to increase the separation efficiency. Positron Lifetime Spectroscopy (PLS) was used to estimate the micro-porosity (pore size and concentration) and fractional free volume changes of CA/TEC films, and used to understand the variations observed in the CO{sub 2}/CO permeabilities.

Naidu Seetala; Upali Siriwardane

2011-06-30T23:59:59.000Z

402

Quantitative measurement of Cr segregation in Co0.8xCrxPt0.1B0.1 recording media by scatter diagram analysis  

E-Print Network [OSTI]

- trometry or electron energy-loss spectrometry EELS data at each point. In most cases this technique diagram analysis of chemically resolved energy-filtered transmission electron microscopy EFTEM images the Cr enrichment is suf- ficiently high as to render the local Co­Cr composition non- magnetic

Krishnan, Kannan M.

403

Thermally Nitrided Stainless Steels for Polymer Electrolyte Membrane Fuel Cell Bipolar Plates: Part 1 Model Ni-50Cr and Austenitic 349TM alloys  

SciTech Connect (OSTI)

Thermal nitridation of a model Ni-50Cr alloy at 1100 C for 2 h in pure nitrogen resulted in the formation of a continuous, protective CrN/Cr{sub 2}N surface layer with a low interfacial contact resistance. Application of similar nitridation parameters to an austenitic stainless steel, 349{sup TM}, however, resulted in a discontinuous mixture of discrete CrN, Cr{sub 2}N and (Cr,Fe){sub 2}N{sub 1-x} (x = 0--0.5) phase surface particles overlying an exposed {gamma} austenite-based matrix, rather than a continuous nitride surface layer. The interfacial contact resistance of the 349{sup TM} was reduced significantly by the nitridation treatment. However, in the simulated PEMFC environments (1 M H{sub 2}SO{sub 4} + 2 ppm F{sup -} solutions at 70 C sparged with either hydrogen or air), very high corrosion currents were observed under both anodic and cathodic conditions. This poor behavior was linked to the lack of continuity of the Cr-rich nitride surface formed on 349{sup TM} Issues regarding achieving continuous, protective Cr-nitride surface layers on stainless steel alloys are discussed.

Wang, Heli [National Renewable Energy Laboratory (NREL); Brady, Michael P [ORNL; Turner, John [National Renewable Energy Laboratory (NREL)

2004-01-01T23:59:59.000Z

404

Microstructural examination of irradiated V-(4-5%)Cr-(4-5%)Ti.  

SciTech Connect (OSTI)

Microstructural examination results are reported for two heats of V-(4-5%) Cr-(4-5%)Ti irradiated in the EBR-II X530 experiment to 4.5 dpa at {approximately}400 C to provide an understanding of the microstructural evolution that may be associated with degradation of mechanical properties. Fine precipitates were observed in high density intermixed with small defect clusters for all conditions examined following the irradiation. The irradiation-induced precipitation does not appear to be affected by preirradiation heat treatment at 950-1125 C. There was no evidence for a significant density of large (diameter >10 nm) dislocation loops or network dislocations. Analytical investigations successfully demonstrated that the precipitates were enriched in titanium, depleted in vanadium and contained no nitrogen. These results are discussed in terms of future alloy development options.

Gelles, D. S.

1998-05-04T23:59:59.000Z

405

FURTHER OBSERVATIONS ON V-4Cr-4Ti PRESSURIZED CREEP TUBES  

SciTech Connect (OSTI)

Further observations are provided for pressurized thermal creep tubes of V-4Cr-4Ti examined following testing in the range 650 to 800°C for tests lasting up to ~104 h. Precipitate particles have been analyzed by EELS to define interstitial contents, and are shown to be either C or O rich with only minor N contents. Grain shape aspect ratios as a function of strain have been measured and these data shows shape change as a result of effective mid-wall strains as high as 12.7%. Deformation mechanisms are considered to explain Newtonian viscous flow response at 800°C below effective midwall stresses of 70 MPa, and it is concluded that grain boundary sliding probably is the predominant mechanism based on the microstructural information presented here, but there is evidence that Harper-Dorn creep may also be a contributing creep mechanism under these conditions.

Gelles, David S.; Kurtz, Richard J.; Toloczko, Mychailo B.; Thomas, Larry E.

2006-03-01T23:59:59.000Z

406

Microstructural examination of irradiated V-(4-5%)Cr-(4-5%)Ti  

SciTech Connect (OSTI)

Microstructural examination results are reported for two heats of V-(4-5%)Cr-(4-5%)Ti irradiated in the EBR-II X530 experiment to {approximately}4 dpa at {approximately}400 C to provide an understanding of the microstructural evolution that may be associated with degradation of mechanical properties. Fine precipitates were observed in high density intermixed with small defect clusters for all conditions examined following the irradiation. The irradiation-induced precipitation does not appear to b affected by preirradiation heat treatment at 950--1125 C. There was no evidence for a significant density of large (diameter >10 nm) dislocation loops or network dislocations. Analytical investigators successfully demonstrated that the precipitates were enriched in titanium, depleted in vanadium and contained no nitrogen.

Gelles, D.S. [Pacific Northwest National Lab., Richland, WA (United States); Rice, P.M.; Zinkle, S.J. [Oak Ridge National Lab., TN (United States); Chung, H.M. [Argonne National Lab., IL (United States)

1998-03-01T23:59:59.000Z

407

On the origin of the low temperatures resistivity minimum in Cr thin films  

SciTech Connect (OSTI)

We present measurements of the electrical resistivity and Hall coefficient, ? and R{sub H}, in Cr films of different thicknesses grown on MgO (100) substrates, as a function of temperature T and applied magnetic field H. The results show a low temperature minimum in ?(T), which is thickness dependent. From 40?K to 2?K, the Hall coefficient is a monotonous increasing function as T is reduced with no particular signature at the temperature T{sub min} where the minimum develops. We explain the resistivity minimum assuming an imperfect nesting of the Fermi surface leading to small electron and hole pockets. We introduce a phenomenological model which supports this simple physical picture.

Osquiguil, E.; Tosi, L.; Kaul, E. E.; Balseiro, C. A. [Centro Atómico Bariloche and Instituto Balseiro, Comisión Nacional de Energía Atómica, 8400 Bariloche (Argentina)

2013-12-28T23:59:59.000Z

408

2011 HONDA CR-Z 2982 - HYBRID ELECTRIC VEHICLE BATTERY TEST RESULTS  

SciTech Connect (OSTI)

The U.S. Department of Energy’s Advanced Vehicle Testing Activity Program consists of vehicle, battery, and infrastructure testing on advanced technology related to transportation. The activity includes tests on hybrid electric vehicles, including testing traction batteries when both the vehicles and batteries are new and at the conclusion of 160,000 miles of on-road fleet testing. This report documents battery testing performed for the 2011 Honda CR-Z (VIN JHMZF1C64BS002982). Battery testing was performed by Intertek Testing Services NA. The Idaho National Laboratory and Intertek collaborate on the Advanced Vehicle Testing Activity for the Vehicle Technologies Office of the U.S. Department of Energy.

Gray, Tyler [Interek; Shirk, Matthew [Idaho National Laboratory; Wishart, Jeffrey [Interek

2014-09-01T23:59:59.000Z

409

2011 Honda CR-Z 4466 - Hybrid Electric Vehicle Battery Test Results  

SciTech Connect (OSTI)

The U.S. Department of Energy’s Advanced Vehicle Testing Activity Program consists of vehicle, battery, and infrastructure testing on advanced technology related to transportation. The activity includes tests on hybrid electric vehicles, including testing traction batteries when both the vehicles and batteries are new and at the conclusion of 160,000 miles of on-road fleet testing. This report documents battery testing performed for the 2011 Honda CR-Z (VIN JHMZF1C67BS004466). Battery testing was performed by Intertek Testing Services NA. The Idaho National Laboratory and Intertek collaborate on the Advanced Vehicle Testing Activity for the Vehicle Technologies Office of the U.S. Department of Energy.

Tyler Gray; Matthew Shirk; Jeffrey Wishart

2014-09-01T23:59:59.000Z

410

Heat treated 9 Cr-1 Mo steel material for high temperature application  

DOE Patents [OSTI]

The invention relates to a composition and heat treatment for a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The novel combination of composition and heat treatment produces a heat treated material containing both large primary titanium carbides and small secondary titanium carbides. The primary titanium carbides contribute to creep strength while the secondary titanium carbides act to maintain a higher level of chromium in the finished steel for increased oxidation resistance, and strengthen the steel by impeding the movement of dislocations through the crystal structure. The heat treated material provides improved performance at comparable cost to commonly used high-temperature steels such as ASTM P91 and ASTM P92, and requires heat treatment consisting solely of austenization, rapid cooling, tempering, and final cooling, avoiding the need for any hot-working in the austenite temperature range.

Jablonski, Paul D.; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

2012-08-21T23:59:59.000Z

411

Thermodynamic modeling and experimental validation of the Fe-Al-Ni-Cr-Mo alloy system  

SciTech Connect (OSTI)

NiAl-type precipitate-strengthened ferritic steels have been known as potential materials for the steam turbine applications. In this study, thermodynamic descriptions of the B2-NiAl type nano-scaled precipitates and body-centered-cubic (BCC) Fe matrix phase for four alloys based on the Fe-Al-Ni-Cr-Mo system were developed as a function of the alloy composition at the aging temperature. The calculated phase structure, composition, and volume fraction were validated by the experimental investigations using synchrotron X-ray diffraction and atom probe tomography. With the ability to accurately predict the key microstructural features related to the mechanical properties in a given alloy system, the established thermodynamic model in the current study may significantly accelerate the alloy design process of the NiAl-strengthened ferritic steels.

Teng, Zhenke [ORNL; Zhang, F [CompuTherm LLC, Madison, WI; Miller, Michael K [ORNL; Liu, Chain T [Hong Kong Polytechnic University; Huang, Shenyan [ORNL; Chou, Y.T. [Multi-Phase Services Inc., Knoxville; Tien, R [Multi-Phase Services Inc., Knoxville; Chang, Y A [ORNL; Liaw, Peter K [University of Tennessee, Knoxville (UTK)

2012-01-01T23:59:59.000Z

412

Microstructural characterization of as-cast biocompatible Co-Cr-Mo alloys  

SciTech Connect (OSTI)

The microstructure of a cobalt-base alloy (Co-Cr-Mo) obtained by the investment casting process was studied. This alloy complies with the ASTM F75 standard and is widely used in the manufacturing of orthopedic implants because of its high strength, good corrosion resistance and excellent biocompatibility properties. This work focuses on the resulting microstructures arising from samples poured under industrial environment conditions, of three different Co-Cr-Mo alloys. For this purpose, we used: 1) an alloy built up from commercial purity constituents, 2) a remelted alloy and 3) a certified alloy for comparison. The characterization of the samples was achieved by using optical microscopy (OM) with a colorant etchant to identify the present phases and scanning electron microscopy (SE-SEM) and energy dispersion spectrometry (EDS) techniques for a better identification. In general the as-cast microstructure is a Co-fcc dendritic matrix with the presence of a secondary phase, such as the M{sub 23}C{sub 6} carbides precipitated at grain boundaries and interdendritic zones. These precipitates are the main strengthening mechanism in this type of alloys. Other minority phases were also reported and their presence could be linked to the cooling rate and the manufacturing process variables and environment. - Research Highlights: {yields}The solidification microstructure of an ASTM-F75 type alloy were studied. {yields}The alloys were poured under an industrial environment. {yields}Carbides and sigma phase identified by color metallography and scanning microscopy (SEM and EDS). {yields}Two carbide morphologies were detected 'blocky type' and 'pearlite type'. {yields}Minority phases were also detected.

Giacchi, J.V., E-mail: jgiacchi@exa.unicen.edu.ar [Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), Av. Rivadavia 1917, C1033AAJ Buenos Aires (Argentina); Instituto de Fisica de Materiales Tandil (IFIMAT-FCE-CICPBA) Facultad de Ciencias Exactas, Universidad Nacional del Centro de la Provincia de Buenos Aires, Pinto 399 B7000GHG Tandil (Argentina); Morando, C.N.; Fornaro, O. [Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), Av. Rivadavia 1917, C1033AAJ Buenos Aires (Argentina); Instituto de Fisica de Materiales Tandil (IFIMAT-FCE-CICPBA) Facultad de Ciencias Exactas, Universidad Nacional del Centro de la Provincia de Buenos Aires, Pinto 399 B7000GHG Tandil (Argentina); Palacio, H.A. [Comision de Investigaciones Cientificas de la Provincia de Buenos Aires (CICPBA), Calle 526 e/10 y 11 B1096APP La Plata (Argentina); Instituto de Fisica de Materiales Tandil (IFIMAT-FCE-CICPBA) Facultad de Ciencias Exactas, Universidad Nacional del Centro de la Provincia de Buenos Aires, Pinto 399 B7000GHG Tandil (Argentina)

2011-01-15T23:59:59.000Z

413

Transmission infrared spectra (225 lm) of carbonaceous chondrites (CI, CM, CVCK, CR, C2 ungrouped): Mineralogy, water, and asteroidal  

E-Print Network [OSTI]

Transmission infrared spectra (2­25 lm) of carbonaceous chondrites (CI, CM, CV­CK, CR, C2 ungrouped t In this work, infrared transmission spectra (2­25 lm range, 5000­400 cm�1 ) of 40 carbonaceous chon- drites. The variability in the silicate features is correlated with the intensity of an ­OH related absorption at 3-lm

Montes-Hernandez, German

414

Characterization of Gas Metal Arc Welding welds obtained with new high Cr-Mo ferritic stainless steel filler wires  

E-Print Network [OSTI]

1 Characterization of Gas Metal Arc Welding welds obtained with new high Cr-Mo ferritic stainless Several compositions of metal cored filler wire were manufactured to define the best welding conditions for homogeneous welding, by Gas Metal Arc Welding (GMAW) process, of a modified AISI 444 ferritic stainless steel

Paris-Sud XI, Université de

415

Re-Evaluation of Results in NUREG/CR-6674 for Carbon and Low-Alloy Steel Components (MRP-76)  

SciTech Connect (OSTI)

This report evaluates the conservatisms and uncertainties reported in NUREG/CR-6674 that lead to high probabilities of cracking in carbon and low-alloy steel for reactor piping. The report uses additional data generated since the completion of the report to eliminate uncertainties and show lower probabilities of cracking.

A. Deardorff; D. Harris; D. Dedhia

2002-11-30T23:59:59.000Z

416

Combined filtered cathodic arc etching pretreatment-magnetron sputter deposition of highly adherent CrN films  

SciTech Connect (OSTI)

CrN films were prepared on steel substrates by a hybrid method utilizing filtered cathodic arc for Cr ion pretreatment and magnetron sputtering for coating deposition. During pretreatment the substrates were biased to -1200 V and exposed to filtered chromium plasma. The substrate-coating interface formed during the pretreatment contained a Cr-enriched modified layer with composition that was strongly influenced by the temperature of the substrate as observed by scanning transmission electron microscopy--energy dispersive spectroscopy. The modified layer had a nanocrystalline morphology and thickness of 15 nm. The path of formation of the layer is linked to the combined action of implantation, diffusion, and resputtering. The resulting adhesion of 3 {mu}m thick CrN films was very high with scratch test critical load values of 83 N. The morphology of the films was smooth without large scale defects and the microstructure was columnar. The coatings behaved well in dry sliding tests with very low wear coefficients of 2.3x10{sup -16} m{sup 3} N{sup -1} m{sup -1}, which can be linked to the high adhesion and defect-free microstructure. The smooth coatings also had a high resistance to corrosion as demonstrated by potentiodynamic tests with particularly high pitting potentials of +800 mV.

Ehiasarian, A. P.; Anders, A.; Petrov, I. [Materials and Engineering Research Institute, Sheffield Hallam University, Howard St., Sheffield S1 1WB (United Kingdom); Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Frederick Seitz Materials Research Laboratory, University of Illinois, Urbana, Illinois 61801 (United States)

2007-05-15T23:59:59.000Z

417

Sputter-Deposited Pt/CrN Nanoparticle PEM Fuel Cell Cathodes: Limited Proton Conductivity Through Electrode  

E-Print Network [OSTI]

Sputter-Deposited Pt/CrN Nanoparticle PEM Fuel Cell Cathodes: Limited Proton Conductivity Through for proton exchange membrane PEM fuel cells. X-ray diffraction and scanning electron microscopy show manuscript received September 17, 2009. Published November 13, 2009. Proton exchange membrane PEM fuel cells

Gall, Daniel

418

The CR 2.0mm (.079") insulation displacement connector features a mounting height as low as  

E-Print Network [OSTI]

7 The CR 2.0mm (.079") insulation displacement connector features a mounting height as low as 6.9mm") pitch insulation displacement connector allows automatic harness production for connection of UL1007 of misinsertion without being permanently distorted. · Twin U-slot insulation displacement section The insulation

Wedeward, Kevin

419

Modulation of physical and photocatalytic properties of (Cr, N) codoped TiO{sub 2} nanorods using soft solution processing  

SciTech Connect (OSTI)

Facile polymerized complex reactions together with a hydrothermal reaction were implemented to make single crystalline TiO{sub 2} nanorods for the first time. Chromium (Cr) and nitrogen (N{sub 2}) co-doping was performed to tailor the physical properties. Transmission electron microscopy and x-ray diffraction study illustrated that highly reactive facets of (101), (111), and (001) dominated rutile TiO{sub 2} nanorods. A growth model, based on formation of complex species, was proposed to elucidate effectiveness of the soft solution processing in making TiO{sub 2} nanorods. X-ray photoelectron spectroscopy analysis and consideration of fundamentals of charge neutrality showed N{sub 2} doping could inhibit formation of Cr{sup 6+} and oxygen vacancies (V{sub O}{sup 2+}). An investigation of the photocatalytic properties exhibited high efficiency of photodegradation of methylene blue in 15?min under pH?=?10, using a nanocomposite of (7% Cr, 0.0021% N) codoped and 3% Cr doped TiO{sub 2} nanorods.

Lu, Wen-Chung [Institute of Nanotechnology and Microsystems Engineering, National Cheng Kung University, No. 1, University Road, Tainan City 70101, Taiwan (China); Department of Materials Science and Engineering, National Cheng Kung University, No. 1, University Road, Tainan City 70101, Taiwan (China); Nguyen, Hoang-Diem; Wu, Chun-Yi [Department of Materials Science and Engineering, National Cheng Kung University, No. 1, University Road, Tainan City 70101, Taiwan (China); Chang, Kao-Shuo, E-mail: kschang@mail.ncku.edu.tw; Yoshimura, Masahiro [Department of Materials Science and Engineering, National Cheng Kung University, No. 1, University Road, Tainan City 70101, Taiwan (China); Promotion Center for Global Materials Research (PCGMR), National Cheng Kung University, No. 1, University Road, Tainan City 70101, Taiwan (China)

2014-04-14T23:59:59.000Z

420

Tunable blue light source by intracavity frequency doubling of a Cr-LiSrAIF6 laser  

E-Print Network [OSTI]

Tunable blue light source by intracavity frequency doubling of a Cr- LiSrAIF6 laser Franqois-switched operation at 10 kHz was intracavity frequency doubled by using a LiIOl crystal. The 230 ns tunable blue lasers emitting in the blue-green wavelength range are expected to be the key components for optical

Paris-Sud XI, Université de

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We encourage you to perform a real-time search of NLEBeta
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421

Targeting Cancer More Effectively CR@B brings together researchers from across the University and the Royal United Hospital, Bath.  

E-Print Network [OSTI]

Targeting Cancer More Effectively CR@B brings together researchers from across the University to find a cure for various types of cancer. 40 academic groups from nearly every department to bedside and back again. Drug Discovery The discovery of a new family of anti-cancer drugs called steroid

Burton, Geoffrey R.

422

Kinetics of oxidation of an organic amine with a Cr(V) salen complex in homogeneous aqueous solution and on the surface of mesoporous silica  

SciTech Connect (OSTI)

A comparative study of catalytic activity under homogeneous and heterogeneous conditions was carried out using the (salen)Cr{sup III}-catalyzed oxidation of tetramethylbenzidine (TMB) with iodosobenzene as a model reaction. Amine-functionalized mesoporous silica nanoparticles (MSN) were synthesized in a co-condensation reaction and functionalized with salen via a covalent Si-C bond. A Cr(III) complex of this supported ligand, MSN-(salen)Cr{sup III}, was prepared and characterized. Data from powder XRD, BET isotherms and BJH pore size distribution all showed that MSN-(salen)Cr{sup III} still had the typical MSN high surface area, narrow pore size distribution, and ordered hexagonal pore structure, which were further confirmed by transmission electron microscopy (TEM) images. {sup 13}C and {sup 29}Si solid-state NMR data provided structural information about the catalyst and verified successful functionalization of the salen ligand and coordination to Cr(III). No unreacted salen or Cr(III) were observed. The loadings of salen and salen-Cr{sup III} complex were determined via TGA and EDX, respectively. Both measurements indicated that approximately 0.5 mmol/g of catalyst was loaded on the surface of MSN. The oxidation of TMB with iodosobenzene using MSN-(salen)Cr{sup III} as a heterogeneous catalyst exhibited both similarities and differences with the analogous homogeneous reaction using (salen)Cr{sup III}(H{sub 2}O){sup +} as a catalyst in aqueous acetonitrile. In the presence of 0.10 M HClO{sub 4}, the two catalytic reactions proceeded at similar rates and generated the doubly oxidized product TMB{sup 2+}. In the absence of acid, the radical cation TMB{sup +} was produced. The kinetics of the heterogeneous reaction in the absence of added acid responded to concentrations of all three reagents, i.e. (salen)Cr{sup III}, TMB, and PhIO.

Szajna-Fuller, Ewa; Huang, Yulin; Rapp, Jennifer L.; Chaka, Gezhegn; Lin, Victor S.Y.; Pruski, Marek; Bakac, Andreja

2009-03-09T23:59:59.000Z

423

Lattice dynamics and low-frequency excitations of transition-metal hydrides:NbD/sub x/, NbH/sub x/, and TaD/sub x/  

SciTech Connect (OSTI)

Phonon dispersion curves have been measured on single crystals of NbD/sub 0.85/ along the (100), (011), and (111) directions. The dispersion curves of the ..cap alpha..' phase of NbD/sub 0.85/ at T=160 /sup 0/C were fit with a Born--von Karman model of the interatomic force constants out to the seventh neighbors. From these constants the acoustic-phonon density of states is calculated. The results are compared with previous measurements on NbD/sub x/ with x=0.45, x=0, and with the Nb-Mo system. A new dispersionless excitation is observed in NbD/sub 0.85/ at h..omega..=18.4 meV. A similar feature is observed in NbH/sub 0.82/ at h..omega..=19.0 meV and in TaD/sub 0.78/ at h..omega..=15.0 meV. The linewidth of this excitation in NbD/sub 0.85/ decreases as the ..beta.. phase is entered and its position shifts slightly to higher energies. A detailed examination of the dispersion curves within the ..beta.. phase reveals interaction between the acoustic modes and this dispersionless excitation. Possible origins of this new feature are discussed. Also observed is an anomalous broadening of the (110) zone-boundary LA phonon within the ..cap alpha..' phase.

Shapiro, S.M.; Richter, D.; Noda, Y.; Birnbaum, H.

1981-02-15T23:59:59.000Z

424

Four magnetic DB white dwarfs discovered by the Hamburg/ESO survey  

E-Print Network [OSTI]

We report on seven peculiar faint blue stars found in the course of the Hamburg/ESO survey (HES) which appear to be magnetic white dwarfs (WDs) with non-hydrogen spectra. We show in particular that four of them (HE 0338-3853, HE 0107-0158, HE 0026-2150, and HE 0003-5701) have He I lines split by magnetic fields of roughly 20MG, since the \\pi components of He I 5876 Angstroem and He I 4929 Angstroem can be identified unambiguously in their spectra, and the $\\sigma^+$, $\\sigma^-$ components can be identified in the spectra of two of these stars (HE 0338-3853 and HE 0003-5701). Besides GD 229, these are the first magnetic DB white dwarfs discovered so far. In addition, three further WDs with broad, unidentifiable features have been found: HE 1043-0502, HE 0236-2656, and HE 0330-0002. We argue that in all three of these stars H I can not be responsible for the broad features, and He I most probably not for the features in HE 0236-2656 and HE 0330-0002, while it still remains possible that the broad features of HE 1043-0502 are due to He I.

D. Reimers; S. Jordan; V. Beckmann; N. Christlieb; L. Wisotzki

1998-07-14T23:59:59.000Z

425

Data:B450787c-60b9-4db5-8d07-40ee55d16e73 | Open Energy Information  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onb5-dcc1fcffd1f2 No revision has38865d08 No revision has been28a07c581c-e2db449df0ab No-4db5-8d07-40ee55d16e73 No

426

Data:5687bd6e-a14f-4fca-a8b6-d9b9782a8db0 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of48d9ff47edf3a87dcc95b3da-78f7ef0b79f6 No revisionc8de9b501c3dd65b9388ca No revision has86292db9782a8db0 No

427

Data:A4ddefe0-db39-48c0-ac98-7941b3451e3c | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 Nod2db5b31cb44 Noddefe0-db39-48c0-ac98-7941b3451e3c No revision has been approved for this page. It is

428

Data:A5db64c6-671c-4162-b2bf-02711bb09a1c | Open Energy Information  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 Nod2db5b31cb44 Noddefe0-db39-48c0-ac98-7941b3451e3c Noa953-7695737b211e Nodc06e0a868 Nofb9b0e

429

Data:A61af82b-acc0-406d-b5bf-f501ff1b01ee | Open Energy Information  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 Nod2db5b31cb44 Noddefe0-db39-48c0-ac98-7941b3451e3cf8e56363f No revision has beenf501ff1b01ee No

430

Data:A64044db-dd8c-4dbb-9ec5-98b3d4e872cf | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 Nod2db5b31cb44 Noddefe0-db39-48c0-ac98-7941b3451e3cf8e56363f No revision hasfe535dd99ec5-98b3d4e872cf

431

Data:A66adac6-ddb6-4529-ae34-db5b20cd220e | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 Nod2db5b31cb44 Noddefe0-db39-48c0-ac98-7941b3451e3cf8e56363f No revisione903b17d302cd18f90e356b

432

Data:A7824421-5cd3-42b5-ae3d-b02b8cf33032 | Open Energy Information  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 Nod2db5b31cb44f-4cd6-87d8-e9253aab8d9c No revision hasf32924 Noda8782 No revisionae3d-b02b8cf33032 No

433

Data:8c43f069-bcc9-447a-90af-4a6e7db5d8e7 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 No revisione0a2d50bdf No18fed1db5 No30e696c No revision has beena6e7db5d8e7 No revision has been

434

Data:9d2b5deb-0dd7-473c-a26c-7e0591db36e1 | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 Nod2db5b31cb44 No revision has been approved095c1f504bccf31-0274-4c1e-93c7-4121ce28476f7e0591db36e1 No

435

Data:8aa53d1d-1865-44a0-b931-f7bfe2db6d86 | Open Energy Information  

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AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office695810186 No revisione0a2d50bdf No18fed1db5 No revision has been approved forbfe2db6d86 No revision has been

436

Microstructure, martensitic transformation and superelasticity of Ti49.6Ni45.1Cu5Cr0.3 shape memory alloy  

E-Print Network [OSTI]

of Western Australia, Crawley, WA 6009, Australia a b s t r a c ta r t i c l e i n f o Article history becomes smaller, with the increase of Cu [4], which means more mechanical energy could be stored to the orthodontic force) and reduce the energy loss by reducing the stress hysteresis; however, these benefits occur

Zheng, Yufeng

437

Impact of x-ray dose on the response of CR-39 to 1-5.5 MeV alphas  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

The CR-39 nuclear track detector is used in many nuclear diagnostics #12;fielded at inertial con#12;nement fusion (ICF) facilities. Large x-ray uences generated by ICF experiments may impact the CR-39 response to incident charged particles. To determine the impact of x-ray exposure on the CR-39 response to alpha particles, a thick-target bremsstrahlung x-ray generator was used to expose CR-39 to various doses of 8 keV Cu-K?#11; and K#12;? x-rays. The CR-39 detectors were then exposed to 1-5.5 MeV alphas from an Am-241 source. The regions of the CR-39 exposed to x-rays showed a smaller track diameter than those not exposed to x-rays: for example, a dose of 3.0#6; ± 0.1 Gy causes a decrease of (19 ± #6;2)% in the track diameter of a 5.5 MeV alpha particle, while a dose of 60.0 ± #6;1.3 Gy results in a decrease of (45 ± #6;5)% in the track diameter. The reduced track diameters were found to be predominantly caused by a comparable reduction in the bulk etch rate of the CR-39 with x-ray dose. A residual eff#11;ect depending on alpha particle energy is characterized using an empirical formula.

Rojas-Herrera, J.; Rinderknecht, H. G.; Zylstra, A. B.; Gatu Johnson, M.; Orozco, D.; Rosenberg, M. J.; Sio, H.; Seguin, F. H.; Frenje, J. A.; Li, C. K.; Petrasso, R. D.

2015-03-01T23:59:59.000Z

438

Microstructural evolution during solution treatment of Co-Cr-Mo-C biocompatible alloys  

SciTech Connect (OSTI)

Three different Co-Cr-Mo-C alloys conforming to ASTM F75 standard were poured in an industrial environment and subjected to a conventional solution treatment at 1225 Degree-Sign C for several time intervals. The microstructural changes and transformations were studied in each case in order to evaluate the way in which treatment time influences the secondary phase fraction and clarify the microstructural changes that could occur. To assess how treatment time affects microstructure, optical microscopy and image analyzer software, scanning electron microscopy and energy dispersion spectrometry analysis were employed. The main phases detected in the as-cast state were: {sigma}-phase, M{sub 6}C, and M{sub 23}C{sub 6} carbides. The latter presented two different morphologies, blocky type and lamellar type. Despite being considered the most detrimental feature to mechanical properties, {sigma}-phase and lamellar carbides dissolution took place in the early stages of solution treatment. M{sub 23}C{sub 6} carbides featured two different behaviors. In the alloy obtained by melting an appropriate quantity of alloyed commercial materials, a decrease in size, spheroidization and transformation into M{sub 6}C carbides were simultaneously observed. In the commercial ASTM F75 alloy, in turn, despite being the same phase, only a marked decrease in precipitates size was noticed. These different behaviors could be ascribed to the initial presence of other phases in the alloy obtained from alloyed materials, such as {sigma}-phase and 'pearlitic' carbides, or to the initial precipitate size which was much larger in the first than in the commercial ASTM F75 alloy studied. M{sub 6}C carbides dissolved directly in the matrix as they could not be detected in samples solution-treated for 15 min. - Highlights: Black-Right-Pointing-Pointer Three different Co-Cr-Mo alloys were poured under an industrial environment. Black-Right-Pointing-Pointer Transformation of existing phases followed during conventional solution treatment. Black-Right-Pointing-Pointer In as-cast/treated samples, phases were identified by color metallography, SEM and EDS. Black-Right-Pointing-Pointer M{sub 23}C{sub 6} {yields} M{sub 6}C transformation was corroborated by SEM and EDS analysis. Black-Right-Pointing-Pointer Carbide spheroidization was also detected prior a noticeably carbide size decreasing.

Giacchi, J.V., E-mail: jgiacchi@exa.unicen.edu.ar [IFIMAT, Instituto de Fisica de Materiales Tandil, Facultad de Ciencias Exactas, Universidad Nacional del Centro de la Provincia de Buenos Aires, Pinto 399, B7000GHG Tandil (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), Av. Rivadavia 1917, C1033AA, Buenos Aires (Argentina); Fornaro, O. [IFIMAT, Instituto de Fisica de Materiales Tandil, Facultad de Ciencias Exactas, Universidad Nacional del Centro de la Provincia de Buenos Aires, Pinto 399, B7000GHG Tandil (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), Av. Rivadavia 1917, C1033AA, Buenos Aires (Argentina); Palacio, H. [IFIMAT, Instituto de Fisica de Materiales Tandil, Facultad de Ciencias Exactas, Universidad Nacional del Centro de la Provincia de Buenos Aires, Pinto 399, B7000GHG Tandil (Argentina); Comision de Investigaciones Cientificas de la Provincia de Buenos Aires (CICPBA), Calle 526 e/10 y 11, B1096APP, La Plata (Argentina)

2012-06-15T23:59:59.000Z

439

Corrosion and Stress Corrosion Cracking of High Cr Ferritic-Martensitic Steels in Supercritical Water  

SciTech Connect (OSTI)

Corrosion behavior of the F-M (ferritic-martensitic) steels (T91, T92, T122) and Fe-base ODS (oxide dispersion strengthened) alloy (MA956{sup TM}) were evaluated in an aerated (8 ppm D.O.) SCW (supercritical water) at the temperature range between 300 and 627 deg C under 25 MPa. In aerated SCW the weight change of the F-M steel specimens became greater as the test temperature increased. However, the extent of the weight change at 350 deg C, just below the critical temperature appeared not to be less than those at 550 deg C. And the weight changes of all the F-M steel specimens in the deaerated SCW (for 347 hrs in 100 ppb D.O. for 347 hrs, and in 10 ppb D.O. for 432 hrs) tended to converge to about 1 mgcm{sup -2}. In aerated or deaerated conditions 20Cr Fe-base ODS alloy appeared to be very resistant to a SCW corrosion at all the test temperatures up to 500 hrs. Stress corrosion cracking (SCC) behavior of 9Cr F-M steels (T91 and T92) was investigated by CERT (Constant Extension Rate Test) in SCW at various temperatures and D.O. levels with different strain rates. T91 did not show any evidence of a SCC in a fully deaerated (below 10 ppb D.O.) SCW at 500, 550, and 600 deg C at the test conditions. T92 specimens were tested at 500 deg C in SCW with different D.O. levels. The strain rate did not seem to affect the SCC behavior of the T92 steel, but D.O. in SCW seems to affect the SCC behavior to some extent. The total elongation of T92 in SCW of 100 ppb or of 500 ppb D.O. was significantly smaller than that at a fully deaerated (below 10 ppb D.O.) SCW (about 15 vs. 20%), and it appears to provide a clue to a SCC on the fracture surface after the CERT test. (authors)

Jinsung, Jang; Seong Sik, Hwang; Chang Hee, Han; Byung Hak, Lee [Korea Atomic Energy Research Institute, 150 Deokjin-dong, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

2006-07-01T23:59:59.000Z

440

Data:Eb22994e-248b-4752-8594-8233db7d9a12 | Open Energy Information  

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While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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441

Data:902905fb-8cbb-457d-9db5-352834999c90 | Open Energy Information  

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442

Data:2f319697-fbbc-4606-87aa-79187db4b99c | Open Energy Information  

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443

Baseline radionuclide concentrations in soils and vegetation around the proposed Weapons Engineering Tritium Facility and the Weapons Subsystems Laboratory at TA-16  

SciTech Connect (OSTI)

A preoperational environmental survey is required by the Department of Energy (DOE) for all federally funded research facilities that have the potential to cause adverse impacts on the environment. Therefore, in accordance with DOE Order 5400.1, an environmental survey was conducted over the proposed sites of the Weapons Engineering Tritium Facility (WETF) and the Weapons Subsystems Laboratory (WSL) at Los Alamos National Laboratory (LANL) at TA-16. Baseline concentrations of tritium ({sup 3}H), plutonium ({sup 238}Pu and {sup 239}Pu) and total uranium were measured in soils, vegetation (pine needles and oak leaves) and ground litter. Tritium was also measured from air samples, while cesium ({sup 137}Cs) was measured in soils. The mean concentration of airborne tritiated water during 1987 was 3.9 pCi/m{sup 3}. Although the mean annual concentration of {sup 3}H in soil moisture at the 0--5 cm (2 in) soil depth was measured at 0.6 pCi/mL, a better background level, based on long-term regional data, was considered to be 2.6 pCi/mL. Mean values for {sup 137}Cs, {sup 218}Pu, {sup 239}Pu, and total uranium in soils collected from the 0--5 cm depth were 1.08 pCi/g, 0.0014 pCi/g, 0.0325 pCi/g, and 4.01 {micro}g/g, respectively. Ponderosa pine (Pinus ponderosa) needles contained higher values of {sup 238}Pu, {sup 239}Pu, and total uranium than did leaves collected from gambel`s oak (Quercus gambelii). In contrast, leaves collected from gambel`s oak contained higher levels of {sup 137}Cs than what pine needles did.

Fresquez, P.R.; Ennis, M.

1995-09-01T23:59:59.000Z

444

ROOM TEMPERATURE COMPRESSION PROPERTIES OF TWO HEATS OF UNIRRADIATED V-4Cr-4Ti  

SciTech Connect (OSTI)

Vanadium alloys are of interest to the Fusion program as potential first wall structural materials. The expected irradiation conditions for the first wall structural material include a range of temperatures where very high hardening caused by a high density of small, but shearable defect clusters results in a type of deformation called "localized deformation". At the onset of yield in a tensile test, a dislocation may move through a grain shearing the obstacles and clearing out a channel. Subsequent dislocations may easily pass through this channel. As the test progresses, more channels form. In the early stages of deformation, it is thought that the plastic deformation is confined to these channels. One important macroscopic result of this deformation behavior is rapid onset of necking in a tensile test and very low uniform elongation. As a means to help understand the range of stress states where localized deformation may adversely affect macroscopic ductility in vanadium alloys, compression test specimens fabricated from two heats of V-4Cr-4Ti are currently under irradiation in the High Flux Isotope Reactor (HFIR). The results of room temperature compression tests on the unirradiated control materials are presented here and compared with uniaxial tensile values from the literature.

Toloczko, Mychailo B.; Kurtz, Richard J.

2004-06-30T23:59:59.000Z

445

Effect of heat treatment on precipitation on V-5Cr-5Ti heat BL63  

SciTech Connect (OSTI)

The microstructures of V-5Cr-5Ti heat BL63 are compared following heat treatments at 1125{degrees}C for 1 h and 1125{degrees}C for 1 h followed by 890{degrees}C for 24 h. Following the 890{degrees}C treatment, precipitate density was increased due to the presence of a moderate density of highly elongated particles. Microchemical analysis showed that these particles often contained both Ti and V, some particles showed minor amounts of Si, S, and P, but it was also possible to show that these precipitates were enriched in O rather than C or N. Following the 1125{degrees}C heat treatment, only Si was found as a minor impurity in large particles, but S could be identified at grain boundaries, which were coated with a fine distribution of precipitates. The embrittlement observed is ascribed to a combination of interstitial solid solution hardening and grain boundary embrittlement, with interstitial hardening likely the dominant factor.

Gelles, D.S.; Li, H. [Pacific Northwest National Laboratory, Richland, WA (United States)

1996-04-01T23:59:59.000Z

446

FURTHER MICROSTRUCTURAL EXAMINATIONS OF V-4Cr-4Ti PRESSURIZED CREEP TUBES  

SciTech Connect (OSTI)

Pressurized thermal creep tubes of V-4Cr-4Ti have been examined following testing in the range 650 to 800°C for tests lasting ~104 h. Creep deformation was found to be controlled by climb-controlled dislocation glide at all temperatures below 800°C whereas at 800°C, sub-grain boundary structure predominated and represented the main obstacle for dislocation motion. At 650 and 700°C after ~104 h an increased density of (Ti,V) oxy-carbo-nitride precipitates near the outer surface extending inwards a distance of 30 and 70 µm, respectively, was found. At 800°C, enhanced (Ti,V) oxy-carbo-nitride precipitation was observed across the entire tube wall thickness and may have affected creep response. Also, evidence for internal precipitation associated with the dislocation structure could be identified. The discussion section addresses differences in the controlling creep mechanisms between grain boundary sliding, sub-grain boundary controlled dislocation climb and individual dislocation climb processes.

Gelles, David S.; Kurtz, Richard J.

2004-06-30T23:59:59.000Z

447

Spatial fractal characteristic of spinodal decomposition in Fe-Cr-Ni duplex stainless steel  

SciTech Connect (OSTI)

Owing to the extensive use of duplex stainless steels in areas like chemical and petrochemical industries, considerable interest has arisen concerning the thermal degradation of these materials during service, and the consequent changes on the mechanical properties. The embrittlement of these steels is basically due to the decomposition of the ferrite phase at elevated temperatures, and duplex steels are seldom used at temperatures above 300 C. Although the microstructure of spinodal decomposition has been studied extensively using atom probe, it is interesting to investigate the development of fractal characteristics in the microstructure during spinodal decomposition. In this paper the authors present part of their recent results in this aspect on a duplex stainless steel. The {alpha} and {alpha}{prime} domains evolved from the primary ferrite phase during spinodal decomposition have different morphologies. The {alpha} (Fe-rich) forms the matrix while the {alpha}{prime} (Cr-rich) domains are developed in the form of discrete regions embedded within the {alpha} matrix. The distribution of these domains follows the fractal-growth characteristics with fractal dimensions ranging from 0.1 to 0.2. In addition, there exists a lower critical dimension beyond which the self-similarity of the domains breaks down.

Shek, C.H.; Wong, K.W.; Lai, J.K.L. [City Univ. of Hong Kong (Hong Kong). Dept. of Physics and Materials Science] [City Univ. of Hong Kong (Hong Kong). Dept. of Physics and Materials Science; Shao, Y.Z. [Zhongshan Univ., Guangzhou (China). Dept. of Physics] [Zhongshan Univ., Guangzhou (China). Dept. of Physics

1997-08-15T23:59:59.000Z

448

Application of NUREG/CR-5999 interim fatigue curves to selected nuclear power plant components  

SciTech Connect (OSTI)

Recent test data indicate that the effects of the light water reactor (LWR) environment could significantly reduce the fatigue resistance of materials used in the reactor coolant pressure boundary components of operating nuclear power plants. Argonne National Laboratory has developed interim fatigue curves based on test data simulating LWR conditions, and published them in NUREG/CR-5999. In order to assess the significance of these interim fatigue curves, fatigue evaluations of a sample of the components in the reactor coolant pressure boundary of LWRs were performed. The sample consists of components from facilities designed by each of the four U.S. nuclear steam supply system vendors. For each facility, six locations were studied, including two locations on the reactor pressure vessel. In addition, there are older vintage plants where components of the reactor coolant pressure boundary were designed to codes that did not require an explicit fatigue analysis of the components. In order to assess the fatigue resistance of the older vintage plants, an evaluation was also conducted on selected components of three of these plants. This report discusses the insights gained from the application of the interim fatigue curves to components of seven operating nuclear power plants.

Ware, A.G.; Morton, D.K.; Nitzel, M.E. [Idaho National Engineering Lab., Idaho Falls, ID (United States)

1995-03-01T23:59:59.000Z

449

Magnetic interactions in CoCrPt-oxide based perpendicular magnetic recording media  

SciTech Connect (OSTI)

First order reversal curves (FORC) method has been reported to be an efficient tool to study interaction between grains and layers of magnetic materials. Although a few studies have been carried out on perpendicular recording media in the past, a study on the effect of systematic variation of exchange interaction in granular perpendicular magnetic recording media on FORC contours has not been carried out in detail. Such a study will help to understand the use of FORC better. In this paper, we have made a systematic set of samples in order to study the variation in exchange coupling and its effect on FORC contours. The pressure during the deposition of the second ruthenium layer and the magnetic layer was varied to alter the separation between the grains and hence the exchange interaction between the grains in the CoCrPt-oxide recording layer. In addition, the thickness of Co-alloy cap layer was used as an additional tool to control the exchange interaction between the magnetic grains. The results indicated that the interaction field obtained from the FORC does not vary in a significant manner when the changes in exchange interaction are small. In comparison, the peak intensity of the FORC shows a clear trend as the exchange coupling is varied, making it a more suitable parameter to study the exchange and magnetostatic interactions in systems such as magnetic recording media.

Tan, H. K.; Varghese, B.; Piramanayagam, S. N., E-mail: prem-SN@dsi.a-star.edu.sg [Data Storage Institute, Agency for Science, Technology and Research (A-STAR), Singapore 117608 (Singapore)

2014-10-28T23:59:59.000Z

450

High-temperature phase transformation in Cr added TiAl base alloy  

SciTech Connect (OSTI)

The authors have investigated a microstructure evolution of a Ti-48Al-3.5Cr (in at.%) alloy at high-temperatures ({gt} 1,473K). In the alloy annealed at 1673K for 1.8ks, followed by air-cooling, a characteristic microstructure with a feathery fashion was uniformly formed. From a cooling-rate-controlling study, it was found that formation of the feathery structure is accomplished during continuous cooling from 1673K to 1573K, within the {alpha} + {gamma} two-phase region. Transmission electron microscopy revealed that the feathery structure is composed of lamellar colonies (5--10{micro}m) which are crystallographically tilted slightly (a few degree) with their neighbors. A surprising fact is that lamellae in each colony are mostly the {gamma} phase with few {alpha}{sub 2} phase less than 5% in volume. This suggests that the feathery structure is a metastable product and has not resulted from the {alpha} {r{underscore}arrow} {alpha} + {gamma} transformation above 1,573 K. Instead, the feathery structure formation should be attributed to the non-equilibrium {alpha} {r{underscore}arrow} {gamma} transformation which occurs at high-temperatures with a small degree of supercooling. The authors discuss this interesting phase transformation in terms of the {alpha} {r{underscore}arrow} {gamma} massive transformation, based on the continuous-cooling-transformation (CCT) diagram constructed for the present alloy.

Abe, E.; Niinobe, K.; Nobuki, M.; Nakamura, M.; Tsujimoto, T.

1999-07-01T23:59:59.000Z

451

Star formation in z>1 3CR host galaxies as seen by Herschel  

E-Print Network [OSTI]

We present Herschel (PACS and SPIRE) far-infrared (FIR) photometry of a complete sample of z>1 3CR sources, from the Herschel GT project The Herschel Legacy of distant radio-loud AGN (PI: Barthel). Combining these with existing Spitzer photometric data, we perform an infrared (IR) spectral energy distribution (SED) analysis of these landmark objects in extragalactic research to study the star formation in the hosts of some of the brightest active galactic nuclei (AGN) known at any epoch. Accounting for the contribution from an AGN-powered warm dust component to the IR SED, about 40% of our objects undergo episodes of prodigious, ULIRG-strength star formation, with rates of hundreds of solar masses per year, coeval with the growth of the central supermassive black hole. Median SEDs imply that the quasar and radio galaxy hosts have similar FIR properties, in agreement with the orientation-based unification for radio-loud AGN. The star-forming properties of the AGN hosts are similar to those of the general popul...

Podigachoski, P; Haas, M; Leipski, C; Wilkes, B; Kuraszkiewicz, J; Westhues, C; Willner, S P; Ashby, M L N; Chini, R; Clements, D L; Fazio, G G; Labiano, A; Lawrence, C; Meisenheimer, K; Peletier, R F; Siebenmorgen, R; Kleijn, G Verdoes

2015-01-01T23:59:59.000Z

452

Phase diagram and magnetocaloric effects in Ni{sub 50}Mn{sub 35}(In{sub 1?x}Cr{sub x}){sub 15} and (Mn{sub 1?x}Cr{sub x})NiGe{sub 1.05} alloys  

SciTech Connect (OSTI)

The magnetocaloric and thermomagnetic properties of Ni{sub 50}Mn{sub 35}(In{sub 1?x}Cr{sub x}){sub 15} and (Mn{sub 1?x}Cr{sub x}) NiGe{sub 1.05} systems for 0???x???0.105 and 0???x???0.1, respectively, have been studied by x-ray diffraction, differential scanning calorimetry, and magnetization measurements. Partial substitution of Cr for Mn in (Mn{sub 1?x}Cr{sub x})NiGe{sub 1.05} results in a first order magnetostructural transition from a hexagonal paramagnetic to an orthorhombic paramagnetic phase near T{sub M}???380?K (for x?=?0.07). Partial substitution of Cr for In in Ni{sub 50}Mn{sub 35}(In{sub 1?x}Cr{sub x}){sub 15} shifts the magnetostructural transition to a higher temperature (T?=?T{sub M}???450?K) for x?=?0.1. Large magnetic entropy changes of ?S?=??12 (J/(kgK)) and ?S?=??11 (J/(kgK)), both for a magnetic field change of 5?T, were observed in the vicinity of T{sub M} for (Mn{sub 1?x}Cr{sub x})NiGe{sub 1.05} and Ni{sub 50}Mn{sub 35}(In{sub 1?x}Cr{sub x}){sub 15}, respectively.

Quetz, Abdiel, E-mail: anorve2002@yahoo.com; Muchharla, Baleeswaraiah; Dubenko, Igor; Talapatra, Saikat; Ali, Naushad [Southern Illinois University, Carbondale, Illinois 62901 (United States); Samanta, Tapas; Stadler, Shane [Department of Physics and Astronomy, Louisiana State University, Baton Rouge, Louisiana 70803 (United States)

2014-05-07T23:59:59.000Z

453

Using CrAIN Multilayer Coatings to Improve Oxidation Resistance of Steel Interconnects for Solid Oxide Fuel Cell Stacks  

SciTech Connect (OSTI)

The requirements of low cost and high-tempurature corrosion resistance for bipolar interconnect plates in solid oxide fuel cell stacks has directed attention to the use of metal plates with oxidation resistant coatings. We have investigatedt he performance of steel plates with multilayer coatings consisting of CrN for electrical conductivity and CrAIN for oxidation resistance. The coatings were deposited usin large area filterd arc deposition technolgy, and subsequently annealed in air for up to 25 hours at 800 degrees celsius. The composition, structer and morphology of the coated plates were characterized using RBS, nuclear reaction analysis, AFM and TEM techniques. By altering the architecture of the layers within the coatings, the rate of oxidation was reduced by more than an order of magnitute. Electrical resistance was measured at room temperature.

Smith, Richard J.; Tripp, C.; Knospe, Anders; Ramana, C. V.; Gorokhovsky, Vladimir I.; Shutthanandan, V.; Gelles, David S.

2004-06-01T23:59:59.000Z

454

Surface structure and electrochemical characteristics of Ti-V-Cr bcc-type solid solution alloys sintered with Ni  

SciTech Connect (OSTI)

Ti-V-Cr bcc-type solid solution alloys can absorb a large amount of hydrogen and be applied to active materials of the negative electrode in Ni-MH batteries. However, because of the insolubility of Ni into these alloys, the electrochemical characteristics like discharge capacity and cycle life were poor. In order to increase the discharge capacity of hydrogen absorbing alloy electrodes, Ti-V-Cr bcc-type alloy powders were sintered with Ni in order to form Ni contained surface layer on the alloy surface. As sintering temperature rose up, the surface composition changed from TiNi to Ti{sub 2}Ni. TiNi surface layer showed better electrochemical characteristics. For the Ni adding method, Ni electroless plating was preferred because of good adhesion. As a result of optimized conditions, a discharge capacity of 570 mAh/g and an improvement of cycle life were achieved.

Tsuji, Yoichiro; Yamamoto, Osamu; Matsuda, Hiromu; Toyoguchi, Yoshinori

2000-07-01T23:59:59.000Z

455

Demonstrations of diode-pumped and grating-tuned ZnSe:Cr{sup 2+} lasers. Revision 1  

SciTech Connect (OSTI)

A diode-side-pumped ZnSe:Cr{sup 2+} laser was operated with a 75 - Watt peak power 1.65 {micro}m InGaAsP/InP pump array. The laser was configured with a ``single-bounce`` architecture to maximize its round-trip gain. Peak output powers of {approx}0.3 Watt were obtained with a 10% - transmitting output coupler and a lightly-doped crystal. The estimated ``mode fill`` of {approx}0.06 will increase with Cr{sup 2+} concentration, raising the output power and extraction efficiency. With a grating tuner and MgF{sub 2}:Co{sup 2+} laser pumping, the laser tuned throughout the 2134 - 2799 nm range.

Page, R.H.; Skidmore, J.A.; Schaffers, K.I.; Beach, R.J.; Payne, S.A.; Krupke, W.F.

1997-02-14T23:59:59.000Z

456

Decay Properties of {sup 266}Bh and {sup 262}Db Produced in the {sup 248}Cm+{sup 23}Na Reaction - Further Confirmation of the {sup 278}113 Decay Chain  

SciTech Connect (OSTI)

Decay properties of an isotope {sup 266}Bh and its daughter nucleus {sup 262}Db produced by the {sup 248}Cm({sup 23}Na,5n) reaction were studied by using a gas-filled recoil separator coupled with a position-sensitive semiconductor detector. {sup 266}Bh was clearly identified from the correlation of the known nuclide, {sup 262}Db. The obtained decay properties of {sup 266}Bh and {sup 262}Db are consistent with those observed in the {sup 278}113 chain by RIKEN collaboration, which provided further confirmation of the discovery of {sup 278}113.

Morita, K.; Morimoto, K.; Kaji, D.; Haba, H.; Ozeki, K.; Kudou, Y.; Yoneda, A.; Ichikawa, T.; Katori, K.; Yoshida, A. [RIKEN Nishina Center, RIKEN, Wako, Saitama 351-0198 (Japan); Sato, N. [RIKEN Nishina Center, RIKEN, Wako, Saitama 351-0198 (Japan); Department of Physics, Tohoku University, Aoba-ku, Sendai 980-8578 (Japan); Sumita, T. [RIKEN Nishina Center, RIKEN, Wako, Saitama 351-0198 (Japan); Faculty of Science and Technology, Tokyo University of Science, Noda, Chiba 278-8510 (Japan); Fujimori, Y.; Tokanai, F. [Department of Physics, Yamagata University, Yamagata 990-8560 (Japan); Goto, S. [Center for Instrumental Analysis, Niigata University, Ikarashi, Nishi-ku, Niigata 950-2181 (Japan); Ideguchi, E. [Center for Nuclear Study, University of Tokyo, Wako, Saitama 351-0198 (Japan); Kasamatsu, Y.; Koura, H.; Tsukada, K. [Japan Atomic Energy Agency, Tokai, Ibaraki 319-1195 (Japan); Komori, Y. [Department of Chemistry, Osaka University, Toyonaka, Osaka 560-0043 (Japan)

2010-06-01T23:59:59.000Z

457

Cr, N-Codoped TiO2 Mesoporous Microspheres for Li-ion Rechargeable Batteries with Enhanced Electrochemical Performance  

SciTech Connect (OSTI)

Cr,N-codoped TiO2 mesoporous microspheres synthesized using hydrothermal and subsequent nitridation treatment, exhibited higher solubility of nitrogen, and improved electrical conductivity than N-doped TiO2, as anode for Lithium-ion rechargeable batteries, which led to improving charge-discharge capacity at 0.1 C and twice higher rate capability compared to that of nitrogen-doped TiO2 mesoporous microsphere at 10 C

Bi, Zhonghe [ORNL] [ORNL; Paranthaman, Mariappan Parans [ORNL] [ORNL; Guo, Bingkun [ORNL] [ORNL; Unocic, Raymond R [ORNL] [ORNL; Meyer III, Harry M [ORNL] [ORNL; Bridges, Craig A [ORNL] [ORNL; Sun, Xiao-Guang [ORNL] [ORNL; Dai, Sheng [ORNL] [ORNL

2014-01-01T23:59:59.000Z

458

Last update: 3/13/12 SYN COURSE SEC TITLE FAC ROOM TY DAY START END CR PREREQ NOTES  

E-Print Network [OSTI]

END CR PREREQ NOTES 9524 ENGL 190A 1W Afro-Caribbean Studies Wilkerson HOLL 217 CLS MWF 03:00PM 04 0 Independent Study Staff 1-4 Permission Required 7186 ENGL 290A 1W American Literary Traditions Askeland HOLL 217 CLS MWF 12:40PM 01:40PM 4 ENGL 170, ENGL 180A or ENGL 190A/C 9599 ENGL 380A 1W The Beat

Bogaerts, Steven

459

AN UNBIASED SPECTRAL LINE SURVEY TOWARD R CrA IRS7B IN THE 345 GHz WINDOW WITH ASTE  

SciTech Connect (OSTI)

We have conducted a spectral line survey in the 332-364 GHz region with the Atacama Submillimeter Telescope Experiment 10 m telescope toward R CrA IRS7B, a low-mass protostar in the Class 0 or Class 0/I transitional stage. We have also performed some supplementary observations in the 450 GHz band. In total, 16 molecular species are identified in the 332-364 GHz region. Strong emission lines of CN and CCH are observed, whereas complex organic molecules and long carbon-chain molecules, which are characteristics of hot corino and warm carbon-chain chemistry (WCCC) source, respectively, are not detected. The rotation temperature of CH{sub 3}OH is evaluated to be 31 K, which is significantly lower than that reported for the prototypical hot corino IRAS 16293-2422 ({approx}85 K). The deuterium fractionation ratios for CCH and H{sub 2}CO are obtained to be 0.038 and 0.050, respectively, which are much lower than those in the hot corino. These results suggest a weak hot corino activity in R CrA IRS7B. On the other hand, the carbon-chain related molecules, CCH and c-C{sub 3}H{sub 2}, are found to be abundant. However, this source cannot be classified as a WCCC source, since long carbon-chain molecules are not detected. If WCCC and hot corino chemistry represent the two extremes in chemical compositions of low-mass Class 0 sources, R CrA IRS7B would be a source with a mixture of these two chemical characteristics. The UV radiation from the nearby Herbig Ae star R CrA may also affect the chemical composition. The present line survey demonstrates further chemical diversity in low-mass star-forming regions.

Watanabe, Yoshimasa; Sakai, Nami; Yamamoto, Satoshi [Department of Physics, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033 (Japan); Lindberg, Johan E.; Bisschop, Suzanne E. [Centre for Star and Planet Formation, Natural History Museum of Denmark, University of Copenhagen, Oster Voldgade 5-7, DK-1350 Copenhagen K. (Denmark); Jorgensen, Jes K. [Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, DK-2100 Copenhagen O. (Denmark)

2012-02-01T23:59:59.000Z

460

Deformation Behavior of Laser Welds in High Temperature Oxidation Resistant Fe-Cr-Al Alloys for Fuel Cladding Applications  

SciTech Connect (OSTI)

Ferritic-structured Fe-Cr-Al alloys are being developed and show promise as oxidation resistant accident tolerant light water reactor fuel cladding. This study focuses on investigating the weldability of three model alloys in a range of Fe-(13-17.5)Cr-(3-4.4)Al in weight percent with a minor addition of yttrium using laser-welding techniques. A detailed study on the mechanical performance of bead-on-plate welds has been carried out to determine the performance of welds as a function of alloy composition. Laser welding resulted in a defect free weld devoid of cracking or inclusions for all alloys studied. Results indicated a reduction in the yield strength within the fusion zone compared to the base metal. Yield strength reduction was found to be primarily constrained to the fusion zone due to grain coarsening with a less severe reduction in the heat affected zone. No significant correlation was found between the deformation behavior/mechanical performance of welds and the level of Cr or Al in the alloy ranges studied.

Field, Kevin G [ORNL; Gussev, Maxim N [ORNL; Yamamoto, Yukinori [ORNL; Snead, Lance Lewis [ORNL

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ta db cr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

High Temperature Thermal Stability and Oxidation Resistance of Magnetron-sputtered Homogeneous CrAlON Coatings on 430 Steel  

SciTech Connect (OSTI)

The requirements of low cost and high-temperature corrosion resistance for bipolar interconnect plates in solid oxide fuel cell stacks has directed attention to the use of metal plates with oxidation resistant coatings. We have investigated the performance of steel plates with homogenous coatings of CrAlON (oxynitrides). The coatings were deposited using RF magnetron sputtering, with Ar as a sputtering gas. Oxygen in these coatings was not intentionally added. Oxygen might have come through contaminated nitrogen gas bottle, leak in the chamber or from the partial pressure of water vapors. Nitrogen was added during the growth process to get oxynitride coating. The Cr/Al composition ratio in the coatings was varied in a combinatorial approach. The coatings were subsequently annealed in air for up to 25 hours at 800 deg. C. The composition of the coated plates and the rate of oxidation were characterized using Rutherford backscattering (RBS) and nuclear reaction analysis (NRA). From our results, we conclude that Al rich coatings are more susceptible to oxidation than Cr rich coatings.

Kayani, A.; Wickey, K. J.; Nandasiri, M. I.; Moore, A.; Garratt, E.; AlFaify, S.; Gao, X. [Western Michigan University-Kalamazoo, MI 49008 (United States); Smith, R. J.; Buchanan, T. L.; Priyantha, W.; Kopczyk, M.; Gannon, P. E. [Montana State University-Bozeman, MT 59717 (United States); Gorokhovsky, V. I. [Arcomac Surface Engineering, LLC-Bozeman, MT 59715 (United States)

2009-03-10T23:59:59.000Z

462

VEHICLE ACCESS PORTALS TA-48 Vicinity TA-36 Vicinity  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism inS-4500II Field EmissionFunctionalPortalV > 1114Pajarito

463

A 220GHz InP HBT Solid-State Power Amplifier MMIC with at 8.2dB Compressed Gain  

E-Print Network [OSTI]

A 220GHz InP HBT Solid-State Power Amplifier MMIC with 90mW POUT at 8.2dB Compressed Gain Thomas B, CA, USA 91360 zgriffith@teledyne-si.com Abstract -- A 220 GHz Solid State Power Amplifer MMIC, Solid State Power Amplifier (SSPA). I. INTRODUCTION Future synthetic aperture radars and high resolution

Rodwell, Mark J. W.

464

Oracle Spatial Data Option Spatial Cartridge Oracle8i SpatialIBM ESRI DB2 Spatial ExtenderInformix Informix Spatial  

E-Print Network [OSTI]

; ---- Oracle Spatial Data Option Spatial Cartridge Oracle8i SpatialIBM ESRI DB2 Spatial ExtenderInformix Informix Spatial Datablade Oracle Oracle8i Spatial Oracle Spatial ----SDO_GEOMETRY SDO_GEOMETRY OracleWeb-Based Three-Dimensional Geo-Referenced Visualization, in Proceedings of International Conference of Spatial

Li, Xiang

465

Heating Greenhouses1 D.E. Buffington, R.A. Bucklin, R.W. Henley and D.B. McConnell2  

E-Print Network [OSTI]

AE11 Heating Greenhouses1 D.E. Buffington, R.A. Bucklin, R.W. Henley and D.B. McConnell2 1 supplemental heat is required. Obviously there are many ways this can be accomplished from the standpoint of these factors be considered when selecting and installing a heating system. HEATING SYSTEMS Greenhouse heating

Watson, Craig A.

466

Formation of Delta Ferrite in 9 Wt Pct Cr Steel Investigated by In-Situ X-Ray Diffraction Using Synchrotron Radiation  

E-Print Network [OSTI]

Formation of Delta Ferrite in 9 Wt Pct Cr Steel Investigatedthe formation of delta ferrite in a martensitic 9 wt pctaustenite, and delta ferrite were measured as a function of

Mayr, P.; Palmer, T.A.; Elmer, J.W.; Specht, E.D.; Allen, S.M.

2010-01-01T23:59:59.000Z

467

QUEST: QUantum Electron Simulation Toolbox C.-R. Lee1,10 S. Chiesa2, C. N. Varney3,4, E. Khatami3, Z. Bai5,  

E-Print Network [OSTI]

QUEST: QUantum Electron Simulation Toolbox C.-R. Lee1,10 S. Chiesa2, C. N. Varney3,4, E. Khatami3 use of standing electromagnetic waves causes the atoms to e

Bai, Zhaojun

468

A Conceptual model of coupled biogeochemical and hydrogeological processes affected by in situ Cr(VI) bioreduction in groundwater at Hanford 100H Site  

E-Print Network [OSTI]

in Groundwater at Hanford 100H Site B.Faybishenko, P.E.Long,Cr(VI) contaminated groundwater at Hanford 100H site. A slowHRC TM ), was injected in Hanford sediments to stimulate

2006-01-01T23:59:59.000Z

469

Role of microbial exopolymeric substances (EPS) on chromium sorption and transport in heterogeneous subsurface soils: I. Cr(III) complexation with EPS in aqueous solution  

SciTech Connect (OSTI)

Chromium (III) binding by exopolymeric substances (EPS) isolated from Pseudomonas putida P18, Pseudomonas aeruginosa P16 and Pseudomonas stutzeri P40 strains were investigated by the determination of conditional stability constants and the concentration of functional groups using the ion-exchange experiments and potentiometric titrations. Spectroscopic (EXAFS) analysis was also used to obtain information on the nature of Cr(III) binding with EPS functional groups. The data from ion-exchange experiments and potentiometric titrations were evaluated using a non-electrostatic discrete ligand approach. The modeling results show that the acid/base properties of EPSs can be best characterized by invoking four different types of acid functional groups with arbitrarily assigned pK{sub a} values of 4, 6, 8 and 10. The analysis of ion-exchange data using the discrete ligand approach suggests that while the Cr binding by EPS from P. aeruginosa can be successfully described based on a reaction stoichiometry of 1:2 between Cr(III) and HL{sub 2} monoprotic ligands, the accurate description of Cr binding by EPSs extracted from P. putida and P. stutzeri requires postulation of 1:1 Cr(III)-ligand complexes with HL{sub 2} and HL{sub 3} monoprotic ligands, respectively. These results indicate that the carboxyl and/or phosphoric acid sites contribute to Cr(III) binding by microbial EPS, as also confirmed by EXAFS analysis performed in the current study. Overall, this study highlights the need for incorporation of Cr-EPS interactions into transport and speciation models to more accurately assess microbial Cr(VI) reduction and chromium transport in subsurface systems, including microbial reactive treatment barriers.

Kantar, C.; Dodge, C.; Demiray, H.; Dogan, N.M.

2011-01-26T23:59:59.000Z

470

Role of Microbial Exopolymeric Substances (EPS) on Chromium Sorption and Transport in Heterogeneous Subsurface Soils: I. Cr(III) Complexation with EPS in Aqueous Solution  

SciTech Connect (OSTI)

Chromium (III) binding by exopolymeric substances (EPS) isolated from Pseudomonas putida P18, Pseudomonas aeruginosa P16 and Pseudomonas stutzeri P40 strains were investigated by the determination of conditional stability constants and the concentration of functional groups using the ion-exchange experiments and potentiometric titrations. Spectroscopic (EXAFS) analysis was also used to obtain information on the nature of Cr(III) binding with EPS functional groups. The data from ion-exchange experiments and potentiometric titrations were evaluated using a non-electrostatic discrete ligand approach. The modeling results show that the acid/base properties of EPSs can be best characterized by invoking four different types of acid functional groups with arbitrarily assigned pK{sub a} values of 4, 6, 8 and 10. The analysis of ion-exchange data using the discrete ligand approach suggests that while the Cr binding by EPS from P. aeruginosa can be successfully described based on a reaction stoichiometry of 1:2 between Cr(III) and HL{sub 2} monoprotic ligands, the accurate description of Cr binding by EPSs extracted from P. putida and P. stutzeri requires postulation of 1:1 Cr(III)-ligand complexes with HL{sub 2} and HL{sub 3} monoprotic ligands, respectively. These results indicate that the carboxyl and/or phosphoric acid sites contribute to Cr(III) binding by microbial EPS, as also confirmed by EXAFS analysis performed in the current study. Overall, this study highlights the need for incorporation of Cr-EPS interactions into transport and speciation models to more accurately assess microbial Cr(VI) reduction and chromium transport in subsurface systems, including microbial reactive treatment barriers.

C Kantar; H Demiray; N Dogan; C Dodge

2011-12-31T23:59:59.000Z

471

X-ray spectroscopic application of Cr/Sc periodic multilayers K. Le Guen, H. Maury, J.-M. Andr, P. Jonnard, A. Hardouin et al.  

E-Print Network [OSTI]

X-ray spectroscopic application of Cr/Sc periodic multilayers K. Le Guen, H. Maury, J.-M. André, P://apl.aip.org/about/rights_and_permissions #12;X-ray spectroscopic application of Cr/Sc periodic multilayers K. Le Guen,a H. Maury, J.-M. André-Paris 6, UMR-CNRS 7614, 11 rue Pierre et Marie Curie, F-75231 Paris Cedex 05, France A. Hardouin, F

472

Giant magnetoresistive structures based on CrO{sub 2} with epitaxial RuO{sub 2} as the spacer layer  

SciTech Connect (OSTI)

Epitaxial ruthenium dioxide (RuO{sub 2})/chromium dioxide(CrO{sub 2}) thin film heterostructures have been grown on (100)-TiO{sub 2} substrates by chemical vapor deposition. Both current-in-plane (CIP) and current-perpendicular-to-plane (CPP) giant magnetoresistive stacks were fabricated with either Co or another epitaxial CrO{sub 2} layer as the top electrode. The Cr{sub 2}O{sub 3} barrier, which forms naturally on CrO{sub 2} surfaces, is no longer present after the RuO{sub 2} deposition, resulting in a highly conductive interface that has a resistance at least four orders of magnitude lower. However, only very limited magnetoresistance (MR) was observed. Such low MR is due to the appearance of a chemically and magnetically disordered layer at the CrO{sub 2} and RuO{sub 2} interfaces when Cr{sub 2}O{sub 3} is transformed into rutile structures during its intermixing with RuO{sub 2}.

Miao, G.X.; Gupta, A.; Sims, H.; Butler, W.H.; Ghosh, S.; Xiao Gang [Physics Department, Brown University, Providence, Rhode Island 02912 (United States); Center for Materials for Information Technology, University of Alabama, Tuscaloosa, Alabama 35487 (United States); Department of Electrical and Computer Engineering, University of Illinois, Chicago, Illinois 60607 (United States); Physics Department, Brown University, Providence, Rhode Island 02912 (United States)

2005-05-15T23:59:59.000Z

473

Investigations of the electronic and magnetic structures of Co{sub 2}YGa (Y=Cr, Mn) Heusler alloys and their (100) surfaces  

SciTech Connect (OSTI)

Density functional theory calculations are performed to investigate the structural, electronic, and magnetic properties of bulk structures of Co{sub 2}YGa (Y?=?Cr, Mn) Heusler alloys and the surfaces along the (100) orientation. The bulk structures of both alloys show a ferromagnetic behavior with total magnetic moments of 3.03?{sub B} and 4.09?{sub B} and high spin polarizations of 99% and 67% for Co{sub 2}CrGa and Co{sub 2}MnGa, respectively. The surfaces are found to exhibit corrugations due to different relaxations of the surface atoms. For the case of Co{sub 2}CrGa, two surfaces preserve the half metallicity, namely those with Cr-Ga and Ga– terminations with high spin polarizations above 90%, whereas it dropped to about 50% for the other surfaces. However, the spin polarizations of Co-Co and Mn-Ga terminated surfaces remain close to that of bulk Co{sub 2}MnGa alloy, whereas it is suppressed down to 17% for Co– termination. The highest local magnetic moments are found to be 3.26??{sub B} and 4.11??{sub B} for Cr and Mn surface atoms in Cr-Ga and Mn– terminated surfaces, respectively.

Hamad, Bothina, E-mail: b.hamad@ju.edu.jo [Physics Department, The University of Jordan, Amman-11942 (Jordan)

2014-03-21T23:59:59.000Z