National Library of Energy BETA

Sample records for ta ai il

  1. XL-A A.&lx A!i' X!Ii?Z IL';;i'

    Office of Legacy Management (LM)

    -- :I 9 .a # ** ,. . . m . . pJ;-,L' ,' i:-t.T .)r' yjs JzZ~ J~~;L,;.~;r 1:). 2 . m I;S~X:T ?I?. ::.:-25-::%-I.:.Glu~ XL-A A.&lx A!i' X!Ii?Z IL';;i' , X2,-d c i.XZEA?, th At3Ac Z:r.zr.~ f4z22s343n >q3 pquask$ tL,..- psg zd of &,-cc b&ldjmms: >UAeT; :,:,. &&;j L' *r: ! 3 ..m 3CCU"pxy &jJdbc ' Au ..3* 6u, I;..:; ' 2. CL&51, 1;; *-- l - l &j-2+; z5 a?, ft . IALP !13. f&%-i;& 2$&J 3;. ft.1 sq, ft.; &ii+ m* i.3. $+, hZE2X, it >a tmn

  2. IL

    Office of Legacy Management (LM)

    :; / 2. ' b-:-"y .",...4 * .-.a 2 IL !< :. 34 --' -, ' ' < I ,-. g Tvo"l r . . .-i- :- " .1-. . . . . NC0 /L ' J,, ' ;.' , -_I( + ? CENTRAL FILES c -&' { ' c;$y ;;j*' E ,J): ' i' Z, 1; p -^ r-raL-r.nuzT".Fn., , ,..-y - -' -ie .". iJ.&:~e!ct.;;' sf ' ;;i_is ,trip ' JG,' go f-Jj;~ey~ 2123 -:s<j .-&;.z ;y1y rrc&ed recr!p!~-,da.a .b ,&.j.,& .:*3;.. F-Y ' __ ,,,.x+; PC l;ealti: :.2,.i CCI ;et y. tirlr.&g t;1c oy-er at ion c.f sei;a~xl

  3. actos_il_v05.ai

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Administration and project management Acquisition and Project Management Office volunteers get up-close look at Office of Secure Transportation exercise Contracting professionals from the NNSA Acquisition & Project Management (APM) Field Program Section (FPS) recently served as role players for Office of Secure Transportation (OST) training exercises in Arkansas and Oklahoma. OST Federal Agents transport U.S. nuclear weapons, components and... SNL Starting Points Sandia Field Office Home

  4. Acceleratore d Impresa AI | Open Energy Information

    Open Energy Info (EERE)

    Acceleratore d Impresa AI Jump to: navigation, search Name: Acceleratore d'Impresa (AI) Place: Italy Sector: Services Product: General Financial & Legal Services ( Academic ...

  5. VEHICLE ACCESS PORTALS TA-48 Vicinity TA-36 Vicinity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pajarito Corridor (Map 4) VEHICLE ACCESS PORTALS TA-48 Vicinity TA-36 Vicinity Drivers of delivery vehicles entering Pajarito Road bounded by NM Highway 4 and Diamond Drive must...

  6. TA1 Room Layout with Newport Laser

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SCALE: 12" X 12" N S E W 22.50 JUPITER LASER FACILITY TA1 ROOM TA1 CHAMBER WEST BEAM CABLE COVER VISAR VIDMAR C O N T R O L R A C K...

  7. Decontamination and Demolition at TA-21

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TA-21 Demolition Decontamination and Demolition at TA-21 On December 1, 2009, LANL began full-scale demolition at TA-21, the Cold War-era complex of buildings that once housed plutonium production and historic, nonweapons research. August 1, 2013 Water sprayed during demolition to protect air quality Water sprayed during demolition to protect air quality The buildings at TA-21 were built as long ago as the 1940s, replacing Manhattan-era facilities and housing labs, offices, and production

  8. DOE - Office of Legacy Management -- Granite City IL Site - IL...

    Office of Legacy Management (LM)

    Contamination from rubbing off of oxidized uranium during handling. IL.28-3 IL.28-5 ... Aerial photograph of the Granite City, Illinois, Site IL.28-1 - DOE Memo; Wagoner to Price...

  9. TA-55: LANL Plutonium-Processing Facilities

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Facilities » TA-55: LANL Plutonium-Processing Facilities TA-55: LANL Plutonium-Processing Facilities TA-55 supports a wide range of national security programs that involve stockpile stewardship, plutonium processing, nuclear materials stabilization, materials disposition, nuclear forensics, nuclear counter-terrorism, and nuclear energy. ...the only fully operational, full capability plutonium facility in the nation. National Security At the Los Alamos National Laboratory (LANL), virtually all

  10. Decontamination and Demolition at TA-21

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    On December 1, 2009, LANL began full-scale demolition at TA-21, the Cold War-era complex ... labs, offices, and production facilities from the Manhattan Project and Cold War eras. ...

  11. Memo - Legacy Technical Area (TA)-55 Nitrate Salt Wastes at TA...

    Office of Environmental Management (EM)

    Plant on February 14, 2014, report in Attachment F. Bibliography and References, are available on various public websites. Memo - Legacy Technical Area (TA)-55 Nitrate Salt ...

  12. IL FS Ecosmart Ltd | Open Energy Information

    Open Energy Info (EERE)

    Services Product: IL&FS Ecosmart Ltd., a subsidiary of the Infrastructure Leasing & Financial Services (IL&FS) Group, provides environmental services. References: IL&FS...

  13. crd title p1.ai | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    13.66 MB) More Documents & Publications crd title p1.ai Final Supplemental Environmental Impact Statement for a Geologic Repository for the Disposal of Spent Nuclear Fuel and High-Level Radioactive Waste at Yucca Mountain, Nye County, Nevada - Nevada Rail Transportation Corridor DOE/EIS-0250F-S2 and Final En

    24.98 MB) More Documents & Publications crd title p1.ai EIS-0250-S2 and EIS-0369: Amended Notice of Intent To Expand the Scope of the Environmental Impact Statement

  14. AIR M A IL

    Office of Legacy Management (LM)

    MEMORlAL DRIVE AIR M A IL ._~ AtFx=b.-zf .7.-i- M r. s. .II. Gown -~ Gentlemen: Re: A.E.C. Contract No. We assume the weight of the 9-l/2" biscuits will:be 107'poutids approximately; i.e. 100 pounds of thorium per biscuit. A four biscuit charge is not feasible because of crucible dimensions, availability, etc. A three biscuit charge will, when molten, fill the proposed crucible half full. This condition is un- desirable because, due to the low heat of fusion of thorium and the

  15. Lana'ai Hawaii: An Inside Look at the World's Most Advanced Renewable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lana'ai Hawaii: An Inside Look at the World's Most Advanced Renewable Energy MicroGrid Lana'ai Hawaii: An Inside Look at the World's Most Advanced Renewable Energy MicroGrid This ...

  16. NNSA to Start Moving TA-18 Nuclear Materials | National Nuclear...

    National Nuclear Security Administration (NNSA)

    Assembly Facility (DAF) at the Nevada Test Site in anticipation of shifting the TA-18 ... to move TA-18 operations to the Nevada Test Site," said NNSA Administrator Linton F. ...

  17. Oxygen Electroreduction on Nanoscale Pt/[TaOPO4/VC] and Pt/[Ta2O5...

    Office of Scientific and Technical Information (OSTI)

    Oxygen Electroreduction on Nanoscale PtTaOPO4VC and PtTa2O5VC in Alkaline Electrolyte Citation Details In-Document Search Title: Oxygen Electroreduction on Nanoscale Pt...

  18. Extracting uranium from seawater: Promising AI series adsorbents

    SciTech Connect (OSTI)

    Das, Sadananda; Oyola, Y.; Mayes, Richard T.; Janke, Christopher James; Kuo, Li-Jung; Gill, Gary; Wood, Jordana; Dai, Sheng

    2015-11-10

    A series of adsorbent (AI10 through AI17) were successfully developed at ORNL by radiation induced graft polymerization (RIGP) of acrylonitrile (AN) and vinylphosphonic acid (VPA) (at different mole/mole ratios) onto high surface area polyethylene fiber, with higher degree of grafting which ranges from 110 300%. The grafted nitrile groups were converted to amidoxime groups by reaction with 10 wt% hydroxylamine at 80 C for 72 hours. The amidoximated adsorbents were then conditioned with 0.44M KOH at 80 C followed by screening at ORNL with simulated seawater spiked with 8 ppm uranium. Uranium adsorption capacity in simulated seawater screening ranged from 171-187 g-U/kg-ads irrespective of %DOG. The performance of the adsorbents for uranium adsorption in natural seawater was also carried out using flow-through-column at Pacific Northwest National Laboratory (PNNL). The three hours KOH conditioning was better for higher uranium uptake than one hour. The adsorbent AI11 containing AN and VPA at the mole ration of 3.52, emerged as the potential candidate for higher uranium adsorption (3.35 g-U/Kg-ads.) after 56 days of exposure in the seawater in the flow-through-column. The rate vanadium adsorption over uranium was linearly increased throughout the 56 days exposure. The total vanadium uptake was ~5 times over uranium after 56 days.

  19. Extracting uranium from seawater: Promising AI series adsorbents

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Das, Sadananda; Oyola, Y.; Mayes, Richard T.; Janke, Christopher James; Kuo, Li-Jung; Gill, Gary; Wood, Jordana; Dai, Sheng

    2015-11-10

    A series of adsorbent (AI10 through AI17) were successfully developed at ORNL by radiation induced graft polymerization (RIGP) of acrylonitrile (AN) and vinylphosphonic acid (VPA) (at different mole/mole ratios) onto high surface area polyethylene fiber, with higher degree of grafting which ranges from 110 300%. The grafted nitrile groups were converted to amidoxime groups by reaction with 10 wt% hydroxylamine at 80 C for 72 hours. The amidoximated adsorbents were then conditioned with 0.44M KOH at 80 C followed by screening at ORNL with simulated seawater spiked with 8 ppm uranium. Uranium adsorption capacity in simulated seawater screening ranged frommore » 171-187 g-U/kg-ads irrespective of %DOG. The performance of the adsorbents for uranium adsorption in natural seawater was also carried out using flow-through-column at Pacific Northwest National Laboratory (PNNL). The three hours KOH conditioning was better for higher uranium uptake than one hour. The adsorbent AI11 containing AN and VPA at the mole ration of 3.52, emerged as the potential candidate for higher uranium adsorption (3.35 g-U/Kg-ads.) after 56 days of exposure in the seawater in the flow-through-column. The rate vanadium adsorption over uranium was linearly increased throughout the 56 days exposure. The total vanadium uptake was ~5 times over uranium after 56 days.« less

  20. Extracting uranium from seawater: Promising AI series adsorbents

    SciTech Connect (OSTI)

    Das, Sadananda; Oyola, Y.; Mayes, Richard T.; Janke, Christopher James; Kuo, Li-Jung; Gill, Gary; Wood, Jordana; Dai, Sheng

    2015-01-01

    A series of adsorbent (AI10 through AI17) were successfully developed at ORNL by radiation induced graft polymerization (RIGP) of acrylonitrile (AN) and vinylphosphonic acid (VPA) (at different mole/mole ratios) onto high surface area polyethylene fiber, with higher degree of grafting which ranges from 110 300%. The grafted nitrile groups were converted to amidoxime groups by reaction with 10 wt% hydroxylamine at 80 C for 72 hours. The amidoximated adsorbents were then conditioned with 0.44M KOH at 80 C followed by screening at ORNL with simulated seawater spiked with 8 ppm uranium. Uranium adsorption capacity in simulated seawater screening ranged from 171-187 g-U/kg-ads irrespective of %DOG. The performance of the adsorbents for uranium adsorption in natural seawater was also carried out using flow-through-column at Pacific Northwest National Laboratory (PNNL). The three hours KOH conditioning was better for higher uranium uptake than one hour. The adsorbent AI11 containing AN and VPA at the mole ration of 3.52, emerged as the potential candidate for higher uranium adsorption (3.35 g-U/Kg-ads.) after 56 days of exposure in the seawater in the flow-through-column. The rate vanadium adsorption over uranium was linearly increased throughout the 56 days exposure. The total vanadium uptake was ~5 times over uranium after 56 days.

  1. Attachment B Visitor Tours at TA-53 TA53-FO-121-001B.4 Preparation Checklist for Visitor Tours at TA-53

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Attachment B Visitor Tours at TA-53 TA53-FO-121-001B.4 Preparation Checklist for Visitor Tours at TA-53 This checklist provides reminders of safety and security considerations in preparation and implementation of tours at TA-53. Tour Date: Purpose of Tour or Tour Title: Tour Host and Z#: State Time and Approximate Duration: Tour Type Check all that apply: Educational Outreach/Student Tour with Minors Large Group Tour Other Tour High Level or Distinguished Work Related Tour Preparation, Visitor

  2. Category:Chicago, IL | Open Energy Information

    Open Energy Info (EERE)

    74 KB SVHospital Chicago IL Commonwealth Edison Co.png SVHospital Chicago IL ... 68 KB SVLargeHotel Chicago IL Commonwealth Edison Co.png SVLargeHotel Chicago I... 75 KB...

  3. Category:Springfield, IL | Open Energy Information

    Open Energy Info (EERE)

    Springfield IL Commonwealth Edison Co.png SVQuickServiceRestaura... 75 KB SVFullServiceRestaurant Springfield IL Commonwealth Edison Co.png...

  4. TA-2 Water Boiler Reactor Decommissioning Project

    SciTech Connect (OSTI)

    Durbin, M.E.; Montoya, G.M.

    1991-06-01

    This final report addresses the Phase 2 decommissioning of the Water Boiler Reactor, biological shield, other components within the biological shield, and piping pits in the floor of the reactor building. External structures and underground piping associated with the gaseous effluent (stack) line from Technical Area 2 (TA-2) Water Boiler Reactor were removed in 1985--1986 as Phase 1 of reactor decommissioning. The cost of Phase 2 was approximately $623K. The decommissioning operation produced 173 m{sup 3} of low-level solid radioactive waste and 35 m{sup 3} of mixed waste. 15 refs., 25 figs., 3 tabs.

  5. CRAD, Configuration Management - Los Alamos National Laboratory TA 55 SST

    Office of Environmental Management (EM)

    Facility | Department of Energy Configuration Management - Los Alamos National Laboratory TA 55 SST Facility CRAD, Configuration Management - Los Alamos National Laboratory TA 55 SST Facility June 2005 A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Configuration Management program at the Los Alamos National Laboratory, TA

  6. CRAD, Emergency Management - Los Alamos National Laboratory TA 55 SST

    Office of Environmental Management (EM)

    Facility | Department of Energy Emergency Management - Los Alamos National Laboratory TA 55 SST Facility CRAD, Emergency Management - Los Alamos National Laboratory TA 55 SST Facility June 2005 A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Emergency Management program at the Los Alamos National Laboratory TA 55 SST

  7. Microstructural and weldability evaluation of 310TaN

    SciTech Connect (OSTI)

    Lundin, C.D.; Qiao, C.Y.P.; Swindeman, R.W.

    1996-08-01

    Excellent weldability and good microstructural stability of 310TaN, in terms of the formation and growth of secondary phases at elevated temperature, was revealed in this investigation. The interganular stress corrosion resistance of 310TaN is superior to modified 800H and 310HCbN evaluated previously due to the fact that TaC, TaN and Ta(C,N) particles are more stable compared to Nb-rich or Ti-rich carbides, nitrides and carbonitrides presented in the other advanced alloys. Using resistance spot welding technique for which extremely fast cooling is a characteristic, it was found that a very minor amount of gain boundary liquation takes place during welding thermal cycling. The limited grain boundary liquation is of the eutectic type i.e., a low tendency to weld HAZ hot cracking.

  8. Characterization of interleukin-15 (IL-15) and the IL-15 receptor complex

    SciTech Connect (OSTI)

    Kennedy, M.K.; Park, L.S.

    1996-05-01

    IL-15 interacts with a heterotrimeric receptor that consists of the {beta} and {gamma} subunits of the IL-2 receptor (IL-2R) as well as a specific, high-affinity IL-15-binding subunit, which is designated IL-15R{alpha}. Since both the {beta} and the {gamma} subunits of the IL-2R are required for signaling by either IL-2 or IL-15, it is not surprising that these cytokines share many activities in vitro. However, the differential expression of these cytokines and the {alpha} chains of their receptors within various tissues and cell types suggests that IL-2 and IL-15 may perform at least partially distinct physiological functions. The production of IL-15 by macrophages, and possibly other cell types, in response to environmental stimuli and infectious agents suggests that IL-15 may play a role in protective immune responses, allograft rejection, and the pathogenesis of autoimmune diseases. 56 refs.

  9. Kah-nee-ta Pool & Spa Low Temperature Geothermal Facility | Open...

    Open Energy Info (EERE)

    Kah-nee-ta Pool & Spa Low Temperature Geothermal Facility Jump to: navigation, search Name Kah-nee-ta Pool & Spa Low Temperature Geothermal Facility Facility Kah-nee-ta Sector...

  10. V-190: ASUS RT-N66U Router AiCloud Security Bypass Security Issue...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0: ASUS RT-N66U Router AiCloud Security Bypass Security Issue V-190: ASUS RT-N66U Router AiCloud Security Bypass Security Issue July 2, 2013 - 12:38am Addthis PROBLEM: ASUS RT-N66U...

  11. IL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power ...

  12. Il.-'",.'

    Office of Legacy Management (LM)

    ... D&D STATUS REPORT NEW BRUNSWICK LABORATORY NEW JERSEY SITE R. A. Wynveen V. R. Veluri W. H. Smith M. J. Robinet H. J. Moe DECEMBER 1981 INDEX Text D&D ......

  13. CRAD, Training - Los Alamos National Laboratory TA 55 SST Facility |

    Office of Environmental Management (EM)

    Department of Energy Training - Los Alamos National Laboratory TA 55 SST Facility CRAD, Training - Los Alamos National Laboratory TA 55 SST Facility A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Training Program at the Los Alamos National Laboratory TA 55 SST Facility. CRADs provide a recommended approach and the types

  14. Structural and Biophysical Studies of the Human IL-7/IL-7R[alpha] Complex

    SciTech Connect (OSTI)

    McElroy, Craig A.; Dohm, Julie A.; Walsh, Scott T.R.; (OSU); (UPENN)

    2009-03-06

    IL-7 and IL-7R{alpha} bind the {gamma}{sub c} receptor, forming a complex crucial to several signaling cascades leading to the development and homeostasis of T and B cells. We report that the IL-7R{alpha} ectodomain uses glycosylation to modulate its binding constants to IL-7, unlike the other receptors in the {gamma}{sub c} family. IL-7 binds glycosylated IL-7R{alpha} 300-fold more tightly than unglycosylated IL-7R{alpha}, and the enhanced affinity is attributed primarily to an accelerated on rate. Structural comparison of IL-7 in complex to both forms of IL-7R{alpha} reveals that glycosylation does not participate directly in the binding interface. The SCID mutations of IL-7R{alpha} locate outside the binding interface with IL-7, suggesting that the expressed mutations cause protein folding defects in IL-7R{alpha}. The IL-7/IL-7R{alpha} structures provide a window into the molecular recognition events of the IL-7 signaling cascade and provide sites to target for designing new therapeutics to treat IL-7-related diseases.

  15. A model of lipid-free Apolipoprotein A-I revealed by iterative molecular dynamics simulation

    SciTech Connect (OSTI)

    Zhang, Xing; Lei, Dongsheng; Zhang, Lei; Rames, Matthew; Zhang, Shengli

    2015-03-20

    Apolipoprotein A-I (apo A-I), the major protein component of high-density lipoprotein, has been proven inversely correlated to cardiovascular risk in past decades. The lipid-free state of apo A-I is the initial stage which binds to lipids forming high-density lipoprotein. Molecular models of lipid-free apo A-I have been reported by methods like X-ray crystallography and chemical cross-linking/mass spectrometry (CCL/MS). Through structural analysis we found that those current models had limited consistency with other experimental results, such as those from hydrogen exchange with mass spectrometry. Through molecular dynamics simulations, we also found those models could not reach a stable equilibrium state. Therefore, by integrating various experimental results, we proposed a new structural model for lipidfree apo A-I, which contains a bundled four-helix N-terminal domain (1–192) that forms a variable hydrophobic groove and a mobile short hairpin C-terminal domain (193–243). This model exhibits an equilibrium state through molecular dynamics simulation and is consistent with most of the experimental results known from CCL/MS on lysine pairs, fluorescence resonance energy transfer and hydrogen exchange. This solution-state lipid-free apo A-I model may elucidate the possible conformational transitions of apo A-I binding with lipids in high-density lipoprotein formation.

  16. A model of lipid-free Apolipoprotein A-I revealed by iterative molecular dynamics simulation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Xing; Lei, Dongsheng; Zhang, Lei; Rames, Matthew; Zhang, Shengli

    2015-03-20

    Apolipoprotein A-I (apo A-I), the major protein component of high-density lipoprotein, has been proven inversely correlated to cardiovascular risk in past decades. The lipid-free state of apo A-I is the initial stage which binds to lipids forming high-density lipoprotein. Molecular models of lipid-free apo A-I have been reported by methods like X-ray crystallography and chemical cross-linking/mass spectrometry (CCL/MS). Through structural analysis we found that those current models had limited consistency with other experimental results, such as those from hydrogen exchange with mass spectrometry. Through molecular dynamics simulations, we also found those models could not reach a stable equilibrium state. Therefore,more » by integrating various experimental results, we proposed a new structural model for lipidfree apo A-I, which contains a bundled four-helix N-terminal domain (1–192) that forms a variable hydrophobic groove and a mobile short hairpin C-terminal domain (193–243). This model exhibits an equilibrium state through molecular dynamics simulation and is consistent with most of the experimental results known from CCL/MS on lysine pairs, fluorescence resonance energy transfer and hydrogen exchange. This solution-state lipid-free apo A-I model may elucidate the possible conformational transitions of apo A-I binding with lipids in high-density lipoprotein formation.« less

  17. TA-53 UNREVIEWED SAFETY ISSUE SCREENING AND DETERMINATION PROCESS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AND DETERMINATION PROCESS TRAINING WORKSHEET CT-TA53-FRM-505-R00 102011 Page 1 of 3 LA-UR-12-10162 TRAINEE NAME: Z NUMBER: GROUP: PURPOSE AND SCOPE: This worksheet is used to...

  18. Segregation and Influence of Boron on the impact toughness of Ti-6 Pct AI-2 Pct Nb-1 Pct Ta0. 8 Pct Mo welds and castings

    SciTech Connect (OSTI)

    Inouye, H.; Davis, S.A.

    1984-07-01

    Trace levels of boron (>0.0010 pct) lowered the impact toughness of welds and castings of Ti-6211. Because the boron effect is also observed in titanium and other titanium alloys, determining the embrittling mechanism is the objective of a continuing study. This study indicates that impaired toughness may result from preferential segregation of boron to the grain boundaries and/or refinement of the ..cap alpha.. + ..beta.. colony microstructure.

  19. DOE - Office of Legacy Management -- Fansteel Metallurgical Corp - IL 16

    Office of Legacy Management (LM)

    Fansteel Metallurgical Corp - IL 16 FUSRAP Considered Sites Site: Fansteel Metallurgical Corp. (IL.16 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Chicago , Illinois IL.16-1 Evaluation Year: 1987 IL.16-3 Site Operations: Sole producer and supplier of tantalum and columbium metals to the MED. IL.16-1 IL.16-3 Site Disposition: Eliminated - No radioactive materials handled at this site IL.16-2 IL.16-3 Radioactive Materials

  20. DE-AI26-06NT42938 | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    938 Gas Hydrates Research Database and Web Dissemination Channel DE-AI26-06NT42938 Last ... The U.S. Hydrate Database stores information on a relational Oracle based system with Web-...

  1. Optical spectroscopy of the Weyl semimetal TaAs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, B.; Dai, Y. M.; Zhao, L. X.; Wang, K.; Yang, R.; Zhang, W.; Liu, J. Y.; Xiao, H.; Chen, G. F.; Taylor, A. J.; et al

    2016-03-24

    Here, we present a systematic study of both the temperature and frequency dependence of the optical response in TaAs, a material that has recently been realized to host the Weyl semimetal state. Our study reveals that the optical conductivity of TaAs features a narrow Drude response alongside a conspicuous linear dependence on frequency. The weight of the Drude peak decreases upon cooling, following a T2 temperature dependence, in good agreement with theoretical predictions. Two linear components with distinct slopes dominate the low-temperature optical conductivity. A comparison between our experimental results and theoretical calculations suggests that the linear conductivity below ~230more » cm–1 arises purely from interband transitions near the Weyl points, providing rich information about the Weyl semimetal state in TaAs.« less

  2. Refractometric determination of content of aromatic hydrocarbons in AI-93 gasolines

    SciTech Connect (OSTI)

    Kuznetsova, L.M.; Ioffe, B.V.; Mikheeva, E.G.

    1982-11-01

    Investigates the possibility of extending the use of the dispersometric method to the control of aromatic hydrocarbon content in AI-93 gasolines. Uses 4 model blends with aromatics content of 20-40% by weight. Finds that the dispersometric method can be used in analyzing both unleaded and leaded AI-93 gasolines, since the addition of ethyl fluid and dye in formulating the leaded gasolines does not affect the accuracy in determining the aromatic hydrocarbon content. Concludes that the dispersometric method can be used to determine the aromatic hydrocarbon content in AI-93 gasolines to within + or - 1.0% by weight, both in the laboratory (IRF-23M refractometer) and under commercial conditions (in ''Nafta-74'' unit).

  3. CRAD, Maintenance- Los Alamos National Laboratory TA 55 SST Facility

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Maintenance program at the Los Alamos National Laboratory TA 55 SST Facility.

  4. Compositional depth profiling of TaCN thin films

    SciTech Connect (OSTI)

    Adelmann, Christoph; Conard, Thierry; Franquet, Alexis; Brijs, Bert; Munnik, Frans; Burgess, Simon; Witters, Thomas; Meersschaut, Johan; Kittl, Jorge A.; Vandervorst, Wilfried; Van Elshocht, Sven

    2012-07-15

    The composition profiling of thin TaCN films was studied. For the composition profile determination using x-ray photoemission spectrometry (XPS) in combination with Ar sputtering, preferential sputtering effects of N with respect to Ta and C were found to lead to inaccurate elemental concentrations. Sputter yield calculations for the given experimental conditions allowed for the correction of a part of the error, leading to fair accuracy by reference-free measurements. Further improvement of the accuracy was demonstrated by the calibration of the XPS compositions against elastic recoil detection analysis (ERDA) results. For Auger electron spectrometry (AES) in combination with Ar sputtering, accurate results required the calibration against ERDA. Both XPS and AES allowed for a reliable and accurate determination of the compositional profiles of TaCN-based thin films after calibration. Time-of-flight secondary-ion mass spectrometry was also used to assess the composition of the TaCN films. However, the analysis was hampered by large matrix effects due to small unintentional oxygen contents in the films. Energy-dispersive x-ray spectrometry is also discussed, and it is shown that an accurate reference-free measurement of the average film concentration can be achieved.

  5. CRAD, Management- Los Alamos National Laboratory TA 55 SST Facility

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Management at the Los Alamos National Laboratory TA 55 SST Facility.

  6. Electrical conductivity of polycrystalline AI/sub 2/O/sub 3/ doped with silicon

    SciTech Connect (OSTI)

    Lee, C.H.; Kroger, F.A.

    1985-02-01

    Direct current conductivity was measured for polycrystalline AI/sub 2/O/sub 3/ doped with silicon, which is found to act as a single donor, the donor level lying approx. = 165 kJ/mol (approx. =1.7 eV) below the conduction band. Silicon in excess of the solubility limit (approx. =220 ppm at 1500/sup 0/C, 300 ppm at 1600/sup 0/C) is present as a glassy aluminosilicate second phase. Silicon dissolved in AI/sub 2/O/sub 3/ tends to segregate at grain boundaries.

  7. Lana'ai Hawaii: An Inside Look at the World's Most Advanced Renewable

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy MicroGrid | Department of Energy Lana'ai Hawaii: An Inside Look at the World's Most Advanced Renewable Energy MicroGrid Lana'ai Hawaii: An Inside Look at the World's Most Advanced Renewable Energy MicroGrid This is a 47-slide presentation on the performance and operation of the microgrid on the island of Lanai with multi-megawatt solar PV generation. Location Hawaii United States See map: Google Maps Date October 2009 Topic Solar Basics & Educating Consumers Systems Performance

  8. DOE - Office of Legacy Management -- Kankakee Ordnance Plant - IL 32

    Office of Legacy Management (LM)

    Kankakee Ordnance Plant - IL 32 FUSRAP Considered Sites Site: KANKAKEE ORDNANCE PLANT (IL.32 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Kankakee , Illinois IL.32-1 Evaluation Year: 1991 IL.32-1 Site Operations: Kankakee Ordnance Plant was cited as a possible location for the disposal of radioactive waste material. There is no indication that any radioactive waste was brought to Kankakee. IL.32-1 IL.32-2 Site Disposition:

  9. DOE - Office of Legacy Management -- Swenson Evaporator Co - IL 23

    Office of Legacy Management (LM)

    Swenson Evaporator Co - IL 23 FUSRAP Considered Sites Site: SWENSON EVAPORATOR CO. (IL.23 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Harvey , Illinois IL.23-1 Evaluation Year: 1987 IL.23-1 Site Operations: Scheduled a raffinate spray drying test that was later cancelled. IL.23-1 Site Disposition: Eliminated - No indication that radioactive materials were handled at this site IL.23-1 Radioactive Materials Handled: None

  10. DOE - Office of Legacy Management -- Vapofier Corp - IL 25

    Office of Legacy Management (LM)

    Vapofier Corp - IL 25 FUSRAP Considered Sites Site: Vapofier Corp. (IL.25) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: Therm-A-Shield Co. IL.25-1 Location: 11957 Vincennes Avenue , Blue Island , Illinois IL.25-2 Evaluation Year: 1990 IL.25-1 Site Operations: Vapofier Corporation was a subcontractor to the MED during a nine month period in 1944. There is no indication that radioactive materials were handled. IL.25-1 Site Disposition:

  11. DOE - Office of Legacy Management -- Podbeilniac Corp - IL 22

    Office of Legacy Management (LM)

    Podbeilniac Corp - IL 22 FUSRAP Considered Sites Site: PODBEILNIAC CORP. (IL.22) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Chicago , Illinois IL.22-1 Evaluation Year: 1990 IL.22-2 Site Operations: MED used equipment for a uranium extraction experiment in 1957. IL.22-1 Site Disposition: Eliminated - Potential for contamination considered remote due to limited scope of activities performed at the site IL.22-2 IL.22-3 IL.22-4

  12. Finished genome assembly of warm spring isolate Francisella novicida DPG 3A-IS

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Johnson, Shannon L.; Minogue, Timothy D.; Daligault, Hajnalka E.; Wolcott, Mark J.; Teshima, Hazuki; Coyne, Susan R.; Davenport, Karen W.; Jaissle, James G.; Chain, Patrick S.

    2015-09-17

    We sequenced the complete genome of Francisella novicida DPG 3A-IS to closed and finished status. This is a warm spring isolate recovered from Hobo Warm Spring (Utah, USA). The last assembly is available in NCBI under accession number CP012037.

  13. Anomalous electronic structure and magnetoresistance in TaAs2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luo, Yongkang; McDonald, R. D.; Rosa, P. F. S.; Scott, B.; Wakeham, N.; Ghimire, N. J.; Bauer, E. D.; Thompson, J. D.; Ronning, F.

    2016-06-07

    We report that the change in resistance of a material in a magnetic field reflects its electronic state. In metals with weakly- or non-interacting electrons, the resistance typically increases upon the application of a magnetic field. In contrast, negative magnetoresistance may appear under some circumstances, e.g., in metals with anisotropic Fermi surfaces or with spin-disorder scattering and semimetals with Dirac or Weyl electronic structures. Here we show that the non-magnetic semimetal TaAs2 possesses a very large negative magnetoresistance, with an unknown scattering mechanism. In conclusion, density functional calculations find that TaAs2 is a new topological semimetal [Z2 invariant (0;111)] withoutmore » Dirac dispersion, demonstrating that a negative magnetoresistance in non-magnetic semimetals cannot be attributed uniquely to the Adler-Bell-Jackiw chiral anomaly of bulk Dirac/Weyl fermions.« less

  14. Technical Area V (TA-V) transformation project close-out report.

    SciTech Connect (OSTI)

    Not Available

    2010-07-01

    Sandia National Laboratories (SNL) Technical Area V (TA-V) has provided unique nuclear experimental environments for decades. The technologies tested in TA-V facilities have furthered the United States Nuclear Weapons program and has contributed to the national energy and homeland security mission. The importance of TA-V working efficiently to produce an attractive and effective platform for experiments should not be underestimated. Throughout its brief history, TA-V has evolved to address multiple and diverse sets of requirements. These requirements evolved over many years; however, the requirements had not been managed nor communicated comprehensively or effectively. A series of programmatic findings over several years of external audits was evidence of this downfall. Today, these same requirements flow down through a new TA-V management system that produces consistently applied and reproducible approaches to work practices. In 2008, the TA-V department managers assessed the state of TA-V services and work activities to understand how to improve customer interfaces, stakeholders perceptions, and workforce efficiencies. The TA-V management team initiated the TA-V Transformation Project after they deemed the pre-June 2008 operational model to be ineffective in managing work and in providing integrated, continuous improvement to TA-V processes. This report summarizes the TA-V Transformation Project goals, activities, and accomplishments.

  15. Facility Representative, Technical Area (TA-55) Plutonium Facility, Los

    National Nuclear Security Administration (NNSA)

    Alamos Site Office | National Nuclear Security Administration | (NNSA) Facility Representative, Technical Area (TA-55) Plutonium Facility, Los Alamos Site Office John Krepps John Krepps June 2010 U.S. Department of Energy Facility Representative of the Year John Krepps, a facility representative for the National Nuclear Security Administration's (NNSA) Los Alamos Site Office, received the Department of Energy's top award for oversight of nuclear and non-nuclear facilities. Krepps, a Los

  16. Issues for reuse of gloveboxes at LANL TA-55

    SciTech Connect (OSTI)

    Cadwallader, L.C.; Pinson, P.A.; Miller, C.F.

    1998-08-01

    This report is a summary of issues that face plutonium glovebox designers and users at the Los Alamos National Laboratory (LANL) Technical Area 55 (TA-55). Characterizing the issues is a step in the task of enhancing the next generation glovebox design to minimize waste streams while providing the other design functions. This report gives an initial assessment of eight important design and operation issues that can benefit from waste minimization.

  17. DOE - Office of Legacy Management -- Armour Research Foundation - IL 17

    Office of Legacy Management (LM)

    Research Foundation - IL 17 FUSRAP Considered Sites Site: Armour Research Foundation of the Illinois Institute of Technology (IL.17 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: Illinois Institute of Technology IL.17-1 Location: Technological Center, 10 West 35th Street , Chicago , Illinois IL.17-1 Evaluation Year: 1985 IL.17-3 Site Operations: Facility operated a research reactor and conducted associated research for the AEC beginning in

  18. DOE - Office of Legacy Management -- Blockson Chemical Co - IL 07

    Office of Legacy Management (LM)

    Blockson Chemical Co - IL 07 FUSRAP Considered Sites Site: Blockson Chemical Co. (IL.07) Eliminated from consideration under FUSRAP - Referred to US EPA Region V and the State of Illinios Designated Name: Not Designated Alternate Name: Olin Corporation IL.07-1 Location: Patterson Road , Joliet , Illinois IL.07-2 Evaluation Year: 1985 IL.07-1 Site Operations: Process development studies and pilot plant testing of uranium recovery from phosphoric acid during the 1950s. Site Disposition: Eliminated

  19. DOE - Office of Legacy Management -- Kaiser Aluminum Corp - IL 19

    Office of Legacy Management (LM)

    Kaiser Aluminum Corp - IL 19 FUSRAP Considered Sites Site: KAISER ALUMINUM CORP. (IL.19 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Dolton , Illinois IL.19-2 Evaluation Year: 1987 IL.19-2 Site Operations: Performed limited duration work extruding uranium billets into three CP-5 fuel elements, circa 1959. IL.19-2 Site Disposition: Eliminated - Potential for contamination considered remote due to limited scope of activities

  20. DOE - Office of Legacy Management -- Precision Extrusion Co - IL 20

    Office of Legacy Management (LM)

    Precision Extrusion Co - IL 20 FUSRAP Considered Sites Site: PRECISION EXTRUSION CO. (IL.20) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 720 East Green Avenue , Bensenville , Illinois IL.20-1 Evaluation Year: 1987 IL.20-2 Site Operations: 1956-1959, metal fabrication - extruded uranium billets. IL.20-1 Site Disposition: Eliminated - Potential for contamination considered remote based on limited quantities of materials handled

  1. DE-AI26-06NT42878 - Alaminos Canyon Task | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alaminos Canyon Task Geochemical Evaluation of Deep Sediment Hydrate Deposits in Alaminos Canyon, Block 818, Texas-Louisiana Shelf DE-AI26-06NT42878 - Alaminos Canyon Task Project Goal This project was intended to test the usefulness of shallow geochemistry and heat flow data acquisition as an aid in the delineation of deeper, concentrated gas hydrate accumulations. NRL scientists conducted geochemical and heat flow surveys of selected sites in Alaminos Canyon Block 818, to support 1) DOE/

  2. DE-AI26-06NT42878 - New Zealand Task | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Zealand Task Gas Hydrate Research in Deep Sea Sediments - New Zealand Task DE-AI26-06NT42878 Project Goal The objective of this research is to determine the extent and dynamics of gas hydrate deposits and their relation to areas of focused fluid flux at and beneath the seafloor. Specific objectives include: a). Refine geophysical, geochemical and microbiological technologies for prospecting hydrate distribution and content; b). Contribute to establishing high-priority geographical regions of

  3. DE-AI26-06NT42878 | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gas Hydrate Research in Deep Sea Sediments - Chatham Rise, New Zealand Task Last Reviewed 5/13/2014 DE-AI26-06NT42878 Goal The goal of the Interagency Agreement between the National Energy Technology Laboratory and the Naval Research Laboratory is to conduct research to enhance understanding of the extent and dynamics of gas hydrate deposits and their relation to areas of focused fluid flux at and beneath the seafloor. Performer Marine Biogeochemistry Section, Naval Research Laboratory,

  4. Apolipoprotein A-I mutant proteins having cysteine substitutions and polynucleotides encoding same

    DOE Patents [OSTI]

    Oda, Michael N.; Forte, Trudy M.

    2007-05-29

    Functional Apolipoprotein A-I mutant proteins, having one or more cysteine substitutions and polynucleotides encoding same, can be used to modulate paraoxonase's arylesterase activity. These ApoA-I mutant proteins can be used as therapeutic agents to combat cardiovascular disease, atherosclerosis, acute phase response and other inflammatory related diseases. The invention also includes modifications and optimizations of the ApoA-I nucleotide sequence for purposes of increasing protein expression and optimization.

  5. TaC Studios New Construction Test House

    SciTech Connect (OSTI)

    Butler, T.; Curtis, O.; Kim, E.; Roberts, S.; Stephenson, R.

    2013-03-01

    As part of the NAHB Research Center Industry Partnership, Southface partnered with TaC Studios, an Atlanta based architecture firm specializing in residential and light commercial design, on the construction of a new test home in Atlanta, GA in the mixed humid climate zone. This home will serve as a model home for the builder partner and addresses Building America energy savings targets through the planning and implementation of a design package will serve as a basis of design for the builder partner's future homes. As a BA test house, this home will be evaluated to detail whole house energy use, end use loads, and HVAC and hot water efficiency.

  6. TaC Studios New Construction Test House

    SciTech Connect (OSTI)

    Butler, T.; Curtis, O.; Kim, E.; Roberts, S.; Stephenson, R.

    2013-03-01

    As part of the NAHB Research Center Industry Partnership, Southface partnered with TaC Studios, an Atlanta based architecture firm specializing in residential and light commercial design, on the construction of a new test home in Atlanta, GA, in the mixed humid climate zone. This home will serve as a model home for the builder partner and addresses Building America energy savings targets through the planning and implementation of a design package will serve as a basis of design for the builder partner’s future homes. As a BA test house, this home will be evaluated to detail whole house energy use, end use loads, and HVAC and hot water efficiency.

  7. Nucleation of fcc Ta when heating thin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Janish, Matthew T.; Mook, William M.; Carter, C. Barry

    2014-10-25

    Thin tantalum films have been studied during in-situ heating in a transmission electron microscope. Diffraction patterns from the as-deposited films were typical of amorphous materials. Crystalline grains were observed to form when the specimen was annealed in-situ at 450°C. Particular attention was addressed to the formation and growth of grains with the face-centered cubic (fcc) crystal structure. As a result, these observations are discussed in relation to prior work on the formation of fcc Ta by deformation and during thin film deposition.

  8. Curcumin blocks interleukin (IL)-2 signaling in T-lymphocytes by inhibiting IL-2 synthesis, CD25 expression, and IL-2 receptor signaling

    SciTech Connect (OSTI)

    Forward, Nicholas A.; Conrad, David M.; Power Coombs, Melanie R.; Doucette, Carolyn D.; Furlong, Suzanne J.; Lin, Tong-Jun; Department of Pediatrics, Dalhousie University, Halifax, Nova Scotia ; Hoskin, David W.

    2011-04-22

    Highlights: {yields} Curcumin inhibits CD4{sup +} T-lymphocyte proliferation. {yields} Curcumin inhibits interleukin-2 (IL-2) synthesis and CD25 expression by CD4{sup +} T-lymphocytes. {yields} Curcumin interferes with IL-2 receptor signaling by inhibiting JAK3 and STAT5 phosphorylation. {yields} IL-2-dependent regulatory T-lymphocyte function and Foxp3 expression is downregulated by curcumin. -- Abstract: Curcumin (diferulomethane) is the principal curcuminoid in the spice tumeric and a potent inhibitor of activation-induced T-lymphocyte proliferation; however, the molecular basis of this immunosuppressive effect has not been well studied. Here we show that micromolar concentrations of curcumin inhibited DNA synthesis by mouse CD4{sup +} T-lymphocytes, as well as interleukin-2 (IL-2) and CD25 ({alpha} chain of the high affinity IL-2 receptor) expression in response to antibody-mediated cross-linking of CD3 and CD28. Curcumin acted downstream of protein kinase C activation and intracellular Ca{sup 2+} release to inhibit I{kappa}B phosphorylation, which is required for nuclear translocation of the transcription factor NF{kappa}B. In addition, IL-2-dependent DNA synthesis by mouse CTLL-2 cells, but not constitutive CD25 expression, was impaired in the presence of curcumin, which demonstrated an inhibitory effect on IL-2 receptor (IL-2R) signaling. IL-2-induced phosphorylation of STAT5A and JAK3, but not JAK1, was diminished in the presence of curcumin, indicating inhibition of critical proximal events in IL-2R signaling. In line with the inhibitory action of curcumin on IL-2R signaling, pretreatment of CD4{sup +}CD25{sup +} regulatory T-cells with curcumin downregulated suppressor function, as well as forkhead box p3 (Foxp3) expression. We conclude that curcumin inhibits IL-2 signaling by reducing available IL-2 and high affinity IL-2R, as well as interfering with IL-2R signaling.

  9. Magnetotransport measurements of current induced effective fields in Ta/CoFeB/MgO

    SciTech Connect (OSTI)

    Zhang, Chaoliang; Yamanouchi, Michihiko Ikeda, Shoji; Center for Spintronics Integrated Systems, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 ; Sato, Hideo; Fukami, Shunsuke; Matsukura, Fumihiro; Ohno, Hideo; Center for Spintronics Integrated Systems, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577; WPI Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577

    2013-12-23

    We evaluate current-induced effective magnetic fields in perpendicularly magnetized Ta/CoFeB/MgO structures from the external magnetic field angle dependence of the Hall resistance. We confirm the presence of two components of effective fields. The dependence of their magnitudes on Ta thickness implies that both components are related to the spin current in Ta layer generated by the spin Hall effect.

  10. DOE - Office of Legacy Management -- Heavy Minerals Inc - IL 14

    Office of Legacy Management (LM)

    Heavy Minerals Inc - IL 14 FUSRAP Considered Sites Site: Heavy Minerals, Inc. ( IL.14 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: W.R. Grace Company IL.14-1 Location: 836 South Michigan Avenue , Chicago , Illinois IL.14-2 Evaluation Year: 1990 IL.14-1 Site Operations: Submitted a proposal to supply thorium hydroxide to the AEC; no indication that the bid was accepted. IL.14-2 Site Disposition: Eliminated - No indication of work done with

  11. Magnetization reversal induced by in-plane current in Ta/CoFeB...

    Office of Scientific and Technical Information (OSTI)

    current are accordance with those for magnetization reversal by spin transfer torque originated from the spin Hall effect in the Ta layer. Authors: Zhang, C. 1 ;...

  12. Technical Area (TA)-54 Area G Nitrate-Salt Waste Container Response...

    Broader source: Energy.gov (indexed) [DOE]

    Pilot Plant on February 14, 2014, report in Attachment F. Bibliography and References, are available on various public websites. Technical Area (TA)-54 Area G Nitrate-Salt ...

  13. Geology of the Western Part of Los Alamos National Laboratory (TA-3 to TA-16), Rio Grande Rift, New Mexico

    SciTech Connect (OSTI)

    C.J.Lewis; A.Lavine; S.L.Reneau; J.N.Gardner; R.Channell; C.W.Criswell

    2002-12-01

    We present data that elucidate the stratigraphy, geomorphology, and structure in the western part of Los Alamos National Laboratory between Technical Areas 3 and 16 (TA-3 and TA-16). Data include those gathered by geologic mapping of surficial, post-Bandelier Tuff strata, conventional and high-precision geologic mapping and geochemical analysis of cooling units within the Bandelier Tuff, logging of boreholes and a gas pipeline trench, and structural analysis using profiles, cross sections, structure contour maps, and stereographic projections. This work contributes to an improved understanding of the paleoseismic and geomorphic history of the area, which will aid in future seismic hazard evaluations and other investigations. The study area lies at the base of the main, 120-m (400-ft) high escarpment formed by the Pajarito fault, an active fault of the Rio Grande rift that bounds Los Alamos National Laboratory on the west. Subsidiary fracturing, faulting, and folding associated with the Pajarito fault zone extends at least 1,500 m (5,000 ft) to the east of the main Pajarito fault escarpment. Stratigraphic units in the study area include upper units of the Tshirege Member of the early Pleistocene Bandelier Tuff, early Pleistocene alluvial fan deposits that predate incision of canyons on this part of the Pajarito Plateau, and younger Pleistocene and Holocene alluvium and colluvium that postdate drainage incision. We discriminate four sets of structures in the area between TA-3 and TA-16: (a) north-striking faults and folds that mark the main zone of deformation, including a graben in the central part of the study area; (b) north-northwest-striking fractures and rare faults that bound the eastern side of the principal zone of deformation and may be the surface expression of deep-seated faulting; (c) rare northeast-striking structures near the northern limit of the area associated with the southern end of the Rendija Canyon fault; and (d) several small east

  14. DOE - Office of Legacy Management -- Chicago North IL Site -...

    Office of Legacy Management (LM)

    IL.05-1 - DOE Letter; Whitman to Wallo; Subject: Authority decisions regarding several sites; October 28, 1985 IL.05-2 - DOE Letter; DeLaney to Holesinger; Subject: Radiological ...

  15. DOE - Office of Legacy Management -- Rock Island Arsenal - IL...

    Office of Legacy Management (LM)

    to DOD Designated Name: Not Designated Alternate Name: None Location: Rock Island , Illinois IL.09-1 Evaluation Year: 1987 IL.09-2 Site Operations: Site located on a DOD ...

  16. Il Woong Jung | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Il Woong Jung Assistant Scientist Education Ph.D., Electrical Engineering, Stanford University Research Summary Research interests are in photonic applications for micro- and nano-mechanical devices. Current research focuses on the manipulation of light-matter interaction at the nanoscale, specifically using micro- and nano-mechanical devices to control the optical properties of photonic nanostructures. The aim is to integrate optical nanostructures and nanomechanical devices to create novel

  17. DOE - Office of Legacy Management -- International Register - IL 15

    Office of Legacy Management (LM)

    Register - IL 15 Site ID (CSD Index Number): IL.15 Site Name: International Register Site Summary: Site Link: External Site Link: Alternate Name(s): Intermatic Inc. Alternate Name Documents: Location: Chicago, Illinois Location Documents: IL.15-1 Historical Operations (describe contaminants): Limited testing of centerless grinding techniques for uranium metal for the AEC. Historical Operations Documents: IL.15-2 Eligibility Determination: Eliminated - Potential for contamination considered

  18. Suboxide/subnitride formation on Ta masks during magnetic material etching by reactive plasmas

    SciTech Connect (OSTI)

    Li, Hu; Muraki, Yu; Karahashi, Kazuhiro; Hamaguchi, Satoshi

    2015-07-15

    Etching characteristics of tantalum (Ta) masks used in magnetoresistive random-access memory etching processes by carbon monoxide and ammonium (CO/NH{sub 3}) or methanol (CH{sub 3}OH) plasmas have been examined by mass-selected ion beam experiments with in-situ surface analyses. It has been suggested in earlier studies that etching of magnetic materials, i.e., Fe, Ni, Co, and their alloys, by such plasmas is mostly due to physical sputtering and etch selectivity of the process arises from etch resistance (i.e., low-sputtering yield) of the hard mask materials such as Ta. In this study, it is shown that, during Ta etching by energetic CO{sup +} or N{sup +} ions, suboxides or subnitrides are formed on the Ta surface, which reduces the apparent sputtering yield of Ta. It is also shown that the sputtering yield of Ta by energetic CO{sup +} or N{sup +} ions has a strong dependence on the angle of ion incidence, which suggests a correlation between the sputtering yield and the oxidation states of Ta in the suboxide or subnitride; the higher the oxidation state of Ta, the lower is the sputtering yield. These data account for the observed etch selectivity by CO/NH{sub 3} and CH{sub 3}OH plasmas.

  19. Preparation and performances of nanosized Ta{sub 2}O{sub 5} powder photocatalyst

    SciTech Connect (OSTI)

    Zhu Yongfa . E-mail: zhuyf@chem.tsinghua.edu.cn; Yu Fang; Man, Yi; Tian, Qingyong; He Yu; Wu Nianzu

    2005-01-15

    Nanosized-Ta{sub 2}O{sub 5} powder photocatalyst was successfully synthesized by using sol-gel method via TaCl{sub 5} butanol solution as a precursor. Ta{sub 2}O{sub 5} species can be formed under 500 deg. C via the decomposition of the precursor. The crystalline phase of Ta{sub 2}O{sub 5} powder photocatalyst can be obtained after being calcined above 600 deg. C for 4h. The crystal size and particle size of Ta{sub 2}O{sub 5} powder photocatalyst was about 50nm. A good photocatalytic performance for the degradation of gaseous formaldehyde was obtained for the nanosized-Ta{sub 2}O{sub 5} powder. The Ta{sub 2}O{sub 5} powder formed at 700 deg. C for 4h and at 650 deg. C for 12h showed the best performance. The calcination temperature and time play an important role in the crystallization and photocatalytical performance of nanosized-Ta{sub 2}O{sub 5} powder.

  20. DE-AI26-06NT42878 - Bottom Source Task | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bottom Source Task Gas Hydrate Research in Deep Sea Sediments DE-AI26-06NT42878 - Bottom Source Task Last Reviewed 11/7/2011 Project Goal The objective of this project is to develop and test a bottom-mounted seismic source for mapping gas hydrates in marine environments. The Naval Research Laboratory (NRL) will modify their existing Helmholtz resonator seismic source, which generates both compressional and shear waves, and develop a system for mounting it onto the seafloor. The resulting

  1. Electron Cloud at Low Emittance in CesrTA

    SciTech Connect (OSTI)

    Palmer, Mark; Alexander, James; Billing, Michael; Calvey, Joseph; Conolly, Christopher; Crittenden, James; Dobbins, John; Dugan, Gerald; Eggert, Nicholas; Fontes, Ernest; Forster, Michael; Gallagher, Richard; Gray, Steven; Greenwald, Shlomo; Hartill, Donald; Hopkins, Walter; Kreinick, David; Kreis, Benjamin; Leong, Zhidong; Li, Yulin; Liu, Xianghong; /more authors..

    2012-07-06

    The Cornell Electron Storage Ring (CESR) has been reconfigured as a test accelerator (CesrTA) for a program of electron cloud (EC) research at ultra low emittance. The instrumentation in the ring has been upgraded with local diagnostics for measurement of cloud density and with improved beam diagnostics for the characterization of both the low emittance performance and the beam dynamics of high intensity bunch trains interacting with the cloud. A range of EC mitigation methods have been deployed and tested and their effectiveness is discussed. Measurements of the electron cloud's effect on the beam under a range of conditions are discussed along with the simulations being used to quantitatively understand these results.

  2. DOE - Office of Legacy Management -- Crane Co - IL 13

    Office of Legacy Management (LM)

    Crane Co - IL 13 FUSRAP Considered Sites Site: Crane Co. (IL.13 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Chicago , Illinois IL.13-2 Evaluation Year: 1987 IL.13-2 Site Operations: MED activities during late-1940s to early/mid-1950s included the development of valves and possibly the use of test quantities of normal uranium in the development process. IL.13-4 Site Disposition: Eliminated - Potential for contamination remote due to

  3. Regulation of Yersina pestis Virulence by AI-2 Mediated Quorum Sensing

    SciTech Connect (OSTI)

    Segelke, B; Hok, S; Lao, V; Corzett, M; Garcia, E

    2010-03-29

    The proposed research was motivated by an interest in understanding Y. pestis virulence mechanisms and bacteria cell-cell communication. It is expected that a greater understanding of virulence mechanisms will ultimately lead to biothreat countermeasures and novel therapeutics. Y. pestis is the etiological agent of plague, the most devastating disease in human history. Y. pestis infection has a high mortality rate and a short incubation before mortality. There is no widely available and effective vaccine for Y. pestis and multi-drug resistant strains are emerging. Y. pestis is a recognized biothreat agent based on the wide distribution of the bacteria in research laboratories around the world and on the knowledge that methods exist to produce and aerosolize large amounts of bacteria. We hypothesized that cell-cell communication via signaling molecules, or quorum sensing, by Y. pestis is important for the regulation of virulence factor gene expression during host invasion, though a causative link had never been established. Quorum sensing is a mode of intercellular communication which enables orchestration of gene expression for many bacteria as a function of population density and available evidence suggests there may be a link between quorum sensing and regulation of Y. pesits virulence. Several pathogenic bacteria have been shown to regulate expression of virulence factor genes, including genes encoding type III secretion, via quorum sensing. The Y. pestis genome encodes several cell-cell signaling pathways and the interaction of at least three of these are thought to be involved in one or more modes of host invasion. Furthermore, Y. pestis gene expression array studies carried out at LLNL have established a correlation between expression of known virulence factors and genes involved in processing of the AI-2 quorum sensing signal. This was a basic research project that was intended to provide new insights into bacterial intercellular communication and how it is

  4. DOE - Office of Legacy Management -- GSA 39th Street Warehouse - IL 02

    Office of Legacy Management (LM)

    GSA 39th Street Warehouse - IL 02 FUSRAP Considered Sites Site: GSA 39TH STREET WAREHOUSE (IL.02 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 1716 West Pershing Road , Chicago , Illinois IL.02-1 Evaluation Year: 1985 IL.02-2 IL.02-3 Site Operations: Stored radioactive materials. IL.02-1 IL.02-2 Site Disposition: Eliminated - Radiation levels below criteria IL.02-1 Radioactive Materials Handled: Yes Primary Radioactive Materials

  5. Chemical Concentrations in Field Mice from Open-Detonation Firing Sites TA-36 Minie and TA-39 Point 6 at Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Fresquez, Philip R.

    2011-01-01

    Field mice (mostly Peromyscus spp.) were collected at two open-detonation (high explosive) firing sites - Minie at Technical Area (TA) 36 and Point 6 at TA-39 - at Los Alamos National Laboratory in August of 2010 and in February of 2011 for chemical analysis. Samples of whole body field mice from both sites were analyzed for target analyte list elements (mostly metals), dioxin/furans, polychlorinated biphenyl congeners, high explosives, and perchlorate. In addition, uranium isotopes were analyzed in a composite sample collected from TA-36 Minie. In general, all constituents, with the exception of lead at TA-39 Point 6, in whole body field mice samples collected from these two open-detonation firing sites were either not detected or they were detected below regional statistical reference levels (99% confidence level), biota dose screening levels, and/or soil ecological chemical screening levels. The amount of lead in field mice tissue collected from TA-39 Point 6 was higher than regional background, and some lead levels in the soil were higher than the ecological screening level for the field mouse; however, these levels are not expected to affect the viability of the populations over the site as a whole.

  6. Influence of shockwave obliquity on deformation twin formation in Ta

    SciTech Connect (OSTI)

    Gray, George T., III; Livescu, V; Cerreta, E K; Mason, T A; Maudlin, P J; Bingert, J F

    2009-02-18

    Energetic loading subjects a material to a 'Taylor wave' (triangular wave) loading profile that experiences an evolving balance of hydrostatic (spherical) and deviatoric stresses. While much has been learned over the past five decades concerning the propensity of deformation twinning in samples shockloaded using 'square-topped' profiles as a function of peak stress, achieved most commonly via flyer plate loading, less is known concerning twinning propensity during non-I-dimensional sweeping detonation wave loading. Systematic small-scale energetically-driven shock loading experiments were conducted on Ta samples shock loaded with PEFN that was edge detonated. Deformation twinning was quantified in post-mortem samples as a function of detonation geometry and radial position. In the edge detonated loading geometry examined in this paper, the average volume fraction of deformation twins was observed to drastically increase with increasing shock obliquity. The results of this study are discussed in light of the formation mechanisms of deformation twins, previous literature studies of twinning in shocked materials, and modeling of the effects of shock obliquity on the evolution of the stress tensor during shock loading.

  7. Precision dilatometry of Nb, Ta, and Lu tritides

    SciTech Connect (OSTI)

    Schober, T.; Dieker, C.; Lasser, R.; Trinkaus, H.

    1989-07-15

    Applying buoyancy dilatometry at room temperature toNbT/sub 0.0253/ and strain-gauge dilatometry at roomtemperature and 78 K to TaT/sub 0.0744/ andLuT/sub 0.15/, respectively, we have measured the swelling ofthese tritides due to the transmutation of T to /sup 3/He in the firsttwo years after T charging. For all three tritides almost linear swelling isfound, indicating approximately constant /sup 3/He densities inbubbles. The corresponding values for the volume requirement of a/sup 3/He atom in a bubble are around 8 A/sup 3/.Associated pressure values are derived with the aid of an equation of state for/sup 3/He adapted to recent high-pressure x-ray-diffractionmeasurements on solid /sup 4/He. With increasing /sup 3/Heconcentration the pressure seems to converge to about 0.2 of the shear modulusof the metal, in accordance with recent theoretical results concerning thethreshold pressure for dislocation-loop punching by bubbles.

  8. DOE - Office of Legacy Management -- Madison - IL 26

    Office of Legacy Management (LM)

    Historical Operations: Conducted experimental work in natural uranium metal extrusion. ... 1992 IL.26-2 - DOE Memorandum; Wagoner to Price (OR); Authorization for Remedial Action at ...

  9. EP-AREAG-PLAN-1248, R.0 TA-54 Area G Nitrate-Salt Waste Container...

    Office of Environmental Management (EM)

    EP-AREAG-PLAN-1248, R.0 TA-54 Area G Nitrate-Salt Waste Container Response Instructions Effective Date: 5282014 The Responsible Manager has determined that the following...

  10. Preparation of W-Ta thin-film thermocouple on diamond anvil cell...

    Office of Scientific and Technical Information (OSTI)

    Preparation of W-Ta thin-film thermocouple on diamond anvil cell for in-situ temperature measurement under high pressure Citation Details In-Document Search Title: Preparation of W...

  11. [Inspection of gas cylinders in storage at TA-54, Area L]. Volume 2, Final report

    SciTech Connect (OSTI)

    1994-06-23

    ERC sampled, analyzed, and rcontainerized when necessary gas cylinders containing various chemicals in storage at LANL TA-54 Area L. This report summarizes the operation. This is Volume 2 of five volumes.

  12. Atmospheric Dispersion and Consequence Analysis at Sandia's TA-V Nuclear Facilities

    Office of Environmental Management (EM)

    Atmospheric Dispersion and Consequence Analysis at Sandia's TA-V Nuclear Facilities Jim Dahl Manager, Nuclear Safety Analysis Sandia National Laboratories Office: 505-284-9067 Email: jjdahl@sandia.gov SAND2012-4478P Sandia is a multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. 2 Dispersion and Consequence Analysis at Sandia's TA-V Topics: * Site

  13. Technical Area (TA)-54 Area G Nitrate-Salt Waste Container Response

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Instructions | Department of Energy Technical Area (TA)-54 Area G Nitrate-Salt Waste Container Response Instructions Technical Area (TA)-54 Area G Nitrate-Salt Waste Container Response Instructions This document was used to determine facts and conditions during the Department of Energy Accident Investigation Board's investigation into the radiological release event at the Waste Isolation Pilot Plant. Additional documents referenced and listed in the Phase 2 Radiological Release Event at the

  14. Visible Light Assisted Photocatalytic Hydrogen Generation by Ta2O5/Bi2O3, TaON/Bi2O3, and Ta3N5/Bi2O3 Composites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Adhikari, Shiba; Hood, Zachary D.; More, Karren Leslie; Ivanov, Ilia N.; Zhang, Lifeng; Gross, Michael; Lachgar, Abdou

    2015-06-15

    Composites comprised of two semiconducting materials with suitable band gaps and band positions have been reported to be effective at enhancing photocatalytic activity in the visible light region of the electromagnetic spectrum. Here, we report the synthesis, complete structural and physical characterizations, and photocatalytic performance of a series of semiconducting oxide composites. UV light active tantalum oxide (Ta2O5) and visible light active tantalum oxynitride (TaON) and tantalum nitride (Ta3N5) were synthesized, and their composites with Bi2O3 were prepared in situ using benzyl alcohol as solvent. The composite prepared using equimolar amounts of Bi2O3 and Ta2O5 leads to the formation ofmore » the ternary oxide, bismuth tantalate (BiTaO4) upon calcination at 1000 °C. The composites and single phase bismuth tantalate formed were characterized by powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), Brunauer–Emmett–Teller (BET) surface area measurement, scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–Vis diffuse reflectance spectroscopy, and photoluminescence. The photocatalytic activities of the catalysts were evaluated for generation of hydrogen using aqueous methanol solution under visible light irradiation (λ ≥ 420 nm). The results show that as-prepared composite photocatalysts extend the light absorption range and restrict photogenerated charge-carrier recombination, resulting in enhanced photocatalytic activity compared to individual phases. The mechanism for the enhanced photocatalytic activity for the heterostructured composites is elucidated based on observed activity, band positions calculations, and photoluminescence data.« less

  15. C E N T R A L F IL E S

    Office of Legacy Management (LM)

    ;zJy, y J l . T;? : Tflj~j : - ..- ":'cyi$:T,;L . . :z*:, 0 , _ _ : 7 r;-2 :: '7 .' . A 1 :- :-; '3 s:s:a *;iy,:;.~ ~ r.3 , :,& . fJ . A . -y& ~ :.-, ;,!*3 , J. -. v :+ tn g C E N T R A L F IL E S ~ > m cTpnz '3 F T E iP T h e o b ;ectl'.'e o f th e ? = r i ~ ';lila to d 9 c u s s th e h e a l th a n d s a fe ty a s p e c ts o f a - p r O p O S e d O f? -31'te te s t involving electro n b e a m m e l tin g o f s o l & 2 a m n l u m n e tal a t th e S ta u ffer-Temescal C o m

  16. Finished genome assembly of warm spring isolate Francisella novicida DPG 3A-IS

    SciTech Connect (OSTI)

    Johnson, Shannon L.; Minogue, Timothy D.; Daligault, Hajnalka E.; Wolcott, Mark J.; Teshima, Hazuki; Coyne, Susan R.; Davenport, Karen W.; Jaissle, James G.; Chain, Patrick S.

    2015-09-17

    We sequenced the complete genome of Francisella novicida DPG 3A-IS to closed and finished status. This is a warm spring isolate recovered from Hobo Warm Spring (Utah, USA). The last assembly is available in NCBI under accession number CP012037.

  17. Growth of single crystalline TaON on yttria-stabilized zirconia (YSZ)

    SciTech Connect (OSTI)

    Tao, Junguang Chai, J.W.; Wong, L.M.; Zhang, Z.; Pan, J.S.; Wang, S.J.

    2013-08-15

    Owing to its high stability in aqueous solution and high quantum efficiency, tantalum based oxyntride (TaON) has attracted increasing attentions for application as visible light photocatalyst. However, despite the recent progress in photocatalytic studies, its bulk charge transport mechanisms are yet to be discovered because of the lack of single crystal sample. In this paper, high quality single crystalline TaON(100) thin film was prepared on cubic YSZ(100) surface by reactive RF magnetron sputtering to avail the understandings of charge transport mechanism so as to improve the device efficiency. The stoichiometry, crystal phase and structure were examined in situ by x-ray photoelectron spectroscopy (XPS) and ex situ by x-ray diffraction (XRD) and transmission electron microscopy (TEM). The TaON film crystallizes in monoclinic ?-phase with its [010]/[001] directions aligned to those of the substrate. The small band gap of 2.5 eV as well as the high structure perfection suggests better performance for visible light water splitting. The method can be used to prepare other surface orientations to elucidate fundamental surface structure dependent photoactivities. - Graphical abstract: Structure of single crystalline ?-TaON and its diffraction pole figure. Highlights: High quality single crystal TaON(100) thin film were grown on YSZ(100) surface. ?-phase monoclinic TaON film is formed. Its [010]/[001] directions are aligned to those of the substrate. The small band gap and structure perfection suggest visible light photo-activity.

  18. DOE - Office of Legacy Management -- American Machine and Metals Inc - IL

    Office of Legacy Management (LM)

    24 Metals Inc - IL 24 FUSRAP Considered Sites Site: American Machine and Metals Inc (IL.24 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: E. Moline , Illinois IL.24-1 Evaluation Year: 1994 IL.24-2 IL.24-3 Site Operations: Tested process for dewatering green salt by centrifugation. IL.24-1 IL.24-2 Site Disposition: Eliminated - Potential for contamination considered remote due to limited amount of radioactive materials handled

  19. DOE - Office of Legacy Management -- Lindsay Light and Chemical Co - IL 10

    Office of Legacy Management (LM)

    Lindsay Light and Chemical Co - IL 10 FUSRAP Considered Sites Site: LINDSAY LIGHT AND CHEMICAL CO. ( IL.10 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: West Chicago , Illinois IL.10-3 Evaluation Year: 1995 IL.10-4 Site Operations: Processed thorium ores - chiefly monazite sands - for thorium and rare earth metals. IL.10-1 IL.10-2 Site Disposition: Eliminated - No Authority - NRC licensed operation IL.10-4 Radioactive Materials

  20. DOE - Office of Legacy Management -- W E Pratt Manufacturing Co - IL 12

    Office of Legacy Management (LM)

    E Pratt Manufacturing Co - IL 12 FUSRAP Considered Sites Site: W.E. PRATT MANUFACTURING CO. (IL.12) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: William E. Pratt Manufacturing Co. Klassing Handbrake Company IL.12-1 IL.12-2 Location: 18 Henderson Street , Joliet , Illinois IL.12-3 Evaluation Year: 1990 IL.12-4 IL.12-5 Site Operations: Performed metal fabrication tasks (machining and grinding). IL.12-1 IL.12-4 Site Disposition: Eliminated - Radiation

  1. Bixbyite- and anatase-type phases in the system Sc-Ta-O-N

    SciTech Connect (OSTI)

    Stork, A.; Schilling, H.; Wessel, C.; Wolff, H.; Boerger, A.; Baehtz, C.; Becker, K.-D.; Dronskowski, R.; Lerch, M.

    2010-09-15

    The aim of our study was to modify the basis compound ss-TaON, which crystallizes in the monoclinic baddeleyite-type, by incorporation of appropriate dopant ions, in order to obtain anion-deficient cubic fluorite-type phases, which are of interest as solids with mobile nitrogen ions. For this purpose, scandium-doped tantalum oxide nitrides were prepared by ammonolysis of amorphous oxide precursors. An unexpected variety of phases with different structural features was observed: bixbyite-type phases of general composition Sc{sub x}Ta{sub 1-x}(O,N){sub y} with 0.33{<=}x{<=}1 and 1.7{<=}y{<=}1.9, yellow colored metastable anatase-type phases such as Sc{sub 0.1}Ta{sub 0.9}O{sub 1.2}N{sub 0.8} or Sc{sub 0.15}Ta{sub 0.85}O{sub 1.3}N{sub 0.7} and, additionally, anosovite-type phases Sc{sub x}Ta{sub 3-x}O{sub 2x}N{sub 5-2x} with 0{<=}x{<=}1.05. Selected phases were investigated by UV/vis spectroscopy. Anatase- and anosovite-type compounds show brilliant colors. In the anatase-type phase, a possible anion ordering was examined by theoretical methods. Additionally, energy calculations on phase stability were performed for Sc{sub x}Ta{sub 1-x}O{sub 1+2x}N{sub 1-2x} in the baddeleyite, rutile, and anatase structure types with varying amounts of dopants. - Graphical abstract: New anatase- and bixbyite-type phases obtained as single-phase samples in the system Sc-Ta-O-N.

  2. Effects of annealing on antiwear and antibacteria behaviors of TaN-Cu nanocomposite thin films

    SciTech Connect (OSTI)

    Hsieh, J. H.; Cheng, M. K.; Chang, Y. K.; Li, C.; Chang, C. L.; Liu, P. C.

    2008-07-15

    TaN-Cu nanocomposite films were deposited by reactive cosputtering on Si and tool steel substrates. The films were then annealed using rapid thermal annealing (RTA) at 400 deg. C for 2, 4, and 8 min, respectively, to induce the nucleation and growth of Cu particles in TaN matrix and on film surface. Field emission scanning electron microscopy was applied to characterize Cu nanoparticles emerged on the surface of TaN-Cu thin films. The effects of annealing on the antiwear and antibacterial properties of these films were studied. The results reveal that annealing by RTA can cause Cu nanoparticles to form on the TaN surface. Consequently, the tribological behaviors, as well as the antibacterial behavior may vary depending on particle size, particle distribution, and total exposed Cu amount. For the samples with large Cu particles, the reduction of averaged friction and wear rate is obvious. Apparently, it is due to the smeared Cu particles adhered onto the wear tracks. This Cu layer may act as a solid lubricant. From the antibacterial testing results, it is found that both Cu particle size and total exposed Cu amount are critical in making short-term antibacterial effect. Overall, all the annealed TaN-Cu samples can reach >99% antibacterial efficiency in 24 h, with respect to uncoated Si substrate.

  3. Precessional magnetization induced spin current from CoFeB into Ta

    SciTech Connect (OSTI)

    Jamali, Mahdi; Klemm, Angeline; Wang, Jian-Ping

    2013-12-16

    The spin dynamics at the interface between the CoFeB and Ta layer has been studied using spin pumping and spin wave characterizations. The spin pumping driven by the ferromagnetic resonance in the CoFeB layer injects a spin current into Ta layer which results in an electromotive force across the Ta layer due to the inverse spin Hall effect. Upon changing the polarity of the bias magnetic field, the polarity of the output voltage inverts and the output voltage increases linearly in respect to the microwave signal power which are consistent with the spin pumping characteristics. The effect of the in-plane magnetization angle on the output voltage has been studied. Furthermore, it is found that the frequency spectrum of the spin Hall voltage is modified by the annealing temperature and the full width at half maximum of the spin pumping increases by more than 40% with the increase of the annealing temperature from 200 °C to 300 °C. The spin Hall angle at the Ta-CoFeB interface is determined to be 0.014, and the damping constant of the CoFeB increases from 0.006 in pure CoFeB to 0.015 in Ta/CoFeB film.

  4. Intrathymic radioresistant stem cells follow an IL-2/IL-2R pathway during thymic regeneration after sublethal irradiation

    SciTech Connect (OSTI)

    Zuniga-Pfluecker, J.C.K.; Kruisbeek, A.M. )

    1990-05-15

    Sublethally irradiated mice undergo thymic regeneration which follows a phenotypic pattern of events similar to that observed during normal fetal development. Thymic regeneration after irradiation is the product of a limited pool of intrathymic radioresistant stem cells undergoing simultaneous differentiation. We show that in this model of T cell development, thymic regeneration follows a pathway in which the IL-2R is transiently expressed on CD4-/CD8- cells. IL-2R expression occurred during the exponential growth period of thymic regeneration, and IL-2R blocking prevented this explosive growth. Flow cytometry analysis revealed that the IL-2R blockade affected primarily the development of the immature CD3-/CD4-/CD8- (triple negative) cells and their ability to generate CD3+/CD4+/CD8+ or CD3+/CD4+/CD8- and CD3+/CD4-/CD8+ thymocytes. Thus, our findings demonstrate that blocking of the IL-2R resulted in an arrest in proliferation and differentiation by intrathymic radioresistant stem cells, indicating that the IL-2/IL-2R pathway is necessary for the expansion of immature triple negative T cells.

  5. DOE - Office of Legacy Management -- Great Lakes Carbon Corp - IL 21

    Office of Legacy Management (LM)

    Great Lakes Carbon Corp - IL 21 FUSRAP Considered Sites Site: GREAT LAKES CARBON CORP. ( IL.21 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 333 North Michigan Avenue , Chicago , Illinois IL.21-1 Evaluation Year: 1987 IL.21-1 Site Operations: Facility performed a limited amount of nuclear fuel fabrication in the 1950s. Facility also developed graphite production under an AEC contract. IL.21-1 IL.21-3 Site Disposition:

  6. DOE - Office of Legacy Management -- Chicago South IL Site -...

    Office of Legacy Management (LM)

    This site is managed by the U.S. Department of Energy Office of Legacy Management. IL.06-1 - DOE Memorandum; Coffman to LaGrone; Subject: Designation of the University of Chicago ...

  7. Crystal structures and phase transitions in Ba{sub 2}HoTaO{sub 6}

    SciTech Connect (OSTI)

    Kennedy, Brendan J. Saines, Paul J.; Kubota, Yoshiki; Minakata, Chiharu; Hano, Hiroko; Kato, Kenichi; Takata, Masaki

    2007-11-06

    The structure of the cation-ordered double perovskite Ba{sub 2}HoTaO{sub 6} was examined using synchrotron X-ray powder diffraction at fine temperature intervals over the range of 90-300 K. Ba{sub 2}HoTaO{sub 6} has a cubic structure in space group Fm3-barm at room temperature. A proper ferroelastic phase transition to I4/m tetragonal symmetry occurs near approximately 260 K. Analysis of the spontaneous tetragonal strain versus temperature indicated that the phase transition is second order in nature.

  8. Survey of Technologies to Support Reuse of Gloveboxes at LANL TA-55

    SciTech Connect (OSTI)

    L. C. Cadwallader; P. A. Pinson.

    1998-11-01

    This report is a summary of ideas and technologies available to support reuse of plutonium gloveboxes at the Los Alamos National Laboratory (LANL) Technical Area 55 (TA-55). This work is the second of two deliverables in the task to enhance glovebox design for longevity and reusability at TA-55. The report presents several design change suggestions to be evaulated for their feasibility by LANL glovebox designers. The report also describes some techniques to be evaluated by LANL for their usefulness in reducing glovebox waste.

  9. DOE - Office of Legacy Management -- TA-1 Manhattan Laboratory - NM 11

    Office of Legacy Management (LM)

    TA-1 Manhattan Laboratory - NM 11 FUSRAP Considered Sites Site: TA-1 MANHATTAN LABORATORY (NM.11 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Main Technical Area LASL LANL NM.11-1 NM.11-2 NM.11-3 Location: Los Alamos , New Mexico NM.11-3 Evaluation Year: 1985 NM.11-1 Site Operations: Nuclear weapons research and development. NM.11-1 NM.11-3 Site Disposition: Site Disposition NM.11-1 Radioactive Materials Handled: Yes Primary Radioactive Materials

  10. Preparation, characterization and photocatalytic property of nanosized K-Ta mixed oxides via a sol-gel method

    SciTech Connect (OSTI)

    Zhang, Gaoke; Jiang, Wei; Yu, Shujie

    2010-11-15

    Pyrochlore-type K{sub 2}Ta{sub 2}O{sub 6} compound cannot be obtained by a conventional solid-state reaction. Here, we report the synthesis of K{sub 2}Ta{sub 2}O{sub 6} and tetragonal tungsten bronze (TTB)-type K{sub 6}Ta{sub 10.8}O{sub 30} nanopowders using a facile and low-cost sol-gel method at low temperature. The as-prepared samples were characterized by XRD, TG-DSC, FESEM, UV-vis diffuse reflectance spectrum and XPS. The compound K{sub 2}Ta{sub 2}O{sub 6} was formed at 700 {sup o}C and reached complete crystallization at 750 {sup o}C, and decomposed into pure K{sub 6}Ta{sub 10.8}O{sub 30} with the volatilization of K{sub 2}O at 900 {sup o}C. The transformation of K{sub 2}Ta{sub 2}O{sub 6} to K{sub 6}Ta{sub 10.8}O{sub 30} is reported for the first time. The band gap of the pure K{sub 2}Ta{sub 2}O{sub 6} and K{sub 6}Ta{sub 10.8}O{sub 30} samples was found to be about 4.16 and 3.63 eV, respectively. The as-prepared K{sub 2}Ta{sub 2}O{sub 6} sample exhibited an efficient photocatalytic activity for the decomposition of azo dye acid red G (ARG) and 4-nitrophenol (4-NP, a typical persistent organic pollutant) solution under UV irradiation. According to the experimental results, the mechanism of the photocatalytic reaction over K{sub 2}Ta{sub 2}O{sub 6} was discussed.

  11. Origin State>> CA ID ID IL IL KY NM NM NV NY OH TN TN TN, WA,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IL IL KY NM NM NV NY OH TN TN TN, WA, CA TN TN TN TN Total Shipments by Route Lawrence Livermore National Laboratory Batelle Energy Alliance Idaho National Laboratory Energx Argonne National Laboratory Argonne National Laboratory Paducah Gaseous Diffusion Plant Sandia National Laboratory Los Alamos National Laboratory National Security Technologies West Valley Environmental Services Portsmouth Gaseous Diffusion Plant Duratek/Energy Solutions Babcox & Wilcox Technical Services Y-12 Plant

  12. Interleukin-2 (IL-2) dependent expression of biologically relevant IL-2 receptors: uncoupling of anti-T3 induced receptor expression with cyclosporin

    SciTech Connect (OSTI)

    Gitter, A.B.D.; Labus, J.M.; Butler, L.D.

    1986-03-01

    Human peripheral blood T cell expression of IL-2 receptors (IL-2R), detected by both immunocytofluorometry and /sup 125/I-IL-2 binding, was studied using lymphocytes stimulated with monoclonal anti-T3 antibodies (Leu-4, OKT3). Lymphocytes, isolated from healthy individuals, were prescreened and classified as Leu-4 responders or non-responders according to 72 h /sup 3/H-thymidine incorporation experiments. Leu-4 non-responder lymphocytes, though capable of normal IL-2R expression and IL-2 secretion when cultured with OKT3 (IgG2a), expressed little to no IL-2R nor secreted IL-2 when stimulated with Leu-4 (IgG1). In addition, the amount of IL-2 secreted by Leu-4 stimulated, Leu-4 responder cells, was one-third- to one-fifth of that detected when OKT3 was used as the stimulant. The addition of recombinant IL-2 (rIL-2) to a Leu-4 stimulated, Leu-4 non-responder lymphocyte culture, resulted in the expression of IL-2R and cellular proliferation, indicating that IL-2 upregulated its biologically relevant receptor. As expected, cyclosporin-A (CSA) inhibited the secretion of IL-2 and subsequent proliferation of Leu-4 stimulated, Leu-4 responder cells. Unexpectedly, however, the expression of IL-2R was also blocked. Exogenous rIL-2 partially reversed the effect of CSA on IL-2R expression and proliferation. The results indicate that IL-2 may provide an additional, required signal for optimal IL-2R expression.

  13. TA-55 Final Safety Analysis Report Comparison Document and DOE Safety Evaluation Report Requirements

    SciTech Connect (OSTI)

    Alan Bond

    2001-04-01

    This document provides an overview of changes to the currently approved TA-55 Final Safety Analysis Report (FSAR) that are included in the upgraded FSAR. The DOE Safety Evaluation Report (SER) requirements that are incorporated into the upgraded FSAR are briefly discussed to provide the starting point in the FSAR with respect to the SER requirements.

  14. CRAD, Radiological Controls- Los Alamos National Laboratory TA 55 SST Facility

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Radiation Protection Program at the Los Alamos National Laboratory TA 55 SST Facility.

  15. High-pressure shock behavior of WC and Ta2O5 powders.

    SciTech Connect (OSTI)

    Knudson, Marcus D.; Reinhart, William Dodd; Vogler, Tracy John; Root, Seth

    2011-10-01

    Planar shock experiments were conducted on granular tungsten carbide (WC) and tantalum oxide (Ta{sub 2}O{sub 5}) using the Z machine and a 2-stage gas gun. Additional shock experiments were also conducted on a nearly fully dense form of Ta{sub 2}O{sub 5}. The experiments on WC yield some of the highest pressure results for granular materials obtained to date. Because of the high distention of Ta{sub 2}O{sub 5}, the pressures obtained were significantly lower, but the very high temperatures generated led to large contributions of thermal energy to the material response. These experiments demonstrate that the Z machine can be used to obtain accurate shock data on granular materials. The data on Ta{sub 2}O{sub 5} were utilized in making improvements to the P-{lambda} model for high pressures; the model is found to capture the results not only of the Z and gas gun experiments but also those from laser experiments on low density aerogels. The results are also used to illustrate an approach for generating an equation of state using only the limited data coming from nanoindentation. Although the EOS generated in this manner is rather simplistic, for this material it gives reasonably good results.

  16. CRAD, Criticality Safety- Los Alamos National Laboratory TA 55 SST Facility

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Criticality Safety program at the Los Alamos National Laboratory, TA 55 SST Facility.

  17. CRAD, Conduct of Operations- Los Alamos National Laboratory TA 55 SST Facility

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Conduct of Operations program at the Los Alamos National Laboratory, TA 55 SST Facility.

  18. CRAD, Quality Assurance- Los Alamos National Laboratory TA 55 SST Facility

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Quality Assurance Program at the Los Alamos National Laboratory TA 55 SST Facility.

  19. CRAD, Safety Basis- Los Alamos National Laboratory TA 55 SST Facility

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for an assessment of the Safety Basis at the Los Alamos National Laboratory TA 55 SST Facility.

  20. Landslides and other mass movements near TA-33, northern White Rock Canyon, New Mexico. Final report

    SciTech Connect (OSTI)

    Dethier, D.P.

    1993-09-01

    Massive slump complexes and at least two rock avalanches flank the eastern rim of the Pajarito Plateau along northern White Rock Canyon, north of TA-33. Landslides failed along mechanically weak rocks in the Santa Fe Group, within the Puye Formation, or in Pliocene alluvial and lacustrine units. The landslides are mainly of early or middle Pleistocene age. The toe area of at least,one slump complex has been active in the late Pleistocene, damming White Rock Canyon near the mouth of Water Canyon. Lacustrine sediment that filled this lake, or series of lakes, to an elevation of at least 1710 m is preserved at a number of upstream sites, including a deposit near the Buckman townsite that exposes 30 m of lacustrine sediment. Charcoal collected at several sites has been submitted for {sup 14}C dating. Landslides, however, probably do not represent a significant short-term threat to the material disposal areas at TA-33. Bedrock that lies beneath the TA-33 mesa is relatively stable, the mesa shows no signs of incipient failure, and past periods of slide activity were responses to rapid downcutting of the Rio Grande and climate change, probably over periods of several decades, at least. Rockfall and headward erosion of gullies do not represent significant decadal hazards on canyon rims near TA-33. Gully migration near MDA-K is a potential threat, but the gullies were not examined in detail. A system of north-trending faults, at least one of which displays Pleistocene activity, bisects the TA-33 mesa. If these faults are capable of producing significant seismic shaking, generalizations about landslide and rockfall hazards must be reevaluated.

  1. The Use of TaBoRR as a Heavy Oil Upgrader

    SciTech Connect (OSTI)

    Lee Brecher; Charles Mones

    2009-02-05

    Preliminary testing has shown that Western Research Institute's (WRI) Tank Bottom Recovery and Remediation (TaBoRR{reg_sign}) technology shows promise for heavy oil upgrading. Approximately 70 to 75 wt% of a Canadian Cold Lake bitumen feed was converted to a partially upgraded overhead product that could be transported directly by pipeline or blended with the parent bitumen to produce transportable crude. TaBoRR{reg_sign} was originally developed to remediate tank bottom wastes by producing a distillate product and solid waste. TaBoRR{reg_sign}'s processing steps include breaking a water-oil emulsion, recovering a light hydrocarbon fraction by distillation in a stripper unit, and pyrolyzing the residua reducing it to additional overhead and a benign coke for disposal. Cold Lake bitumen was tested in WRI's bench-scale equipment to evaluate the potential use of TaBoRR{reg_sign} technology for heavy oil upgrading to produce a stable, partially (or fully) upgraded product that will allow diluent-reduced or diluent-free transportation of bitumen or ultra-heavy crudes to market. Runs were conducted at temperatures of low, intermediate and high severity in the stripper to produce stripper overhead and bottoms. The bottoms from each of these runs were processed further in a 6-inch screw pyrolyzer to produce pyrolyzer overhead for blending with the corresponding stripper overheads. Proceeding in this fashion yielded three partially upgraded crudes. The products from TaBoRR{reg_sign} processing, the parent bitumen, and bitumen blends were subjected to stability and compatibility testing at the National Centre for Upgrading Technology (NCUT). Chemical analyses of the overhead product blends have met pipeline specifications for viscosity and density; however the bromine number does not, which might indicate the need for mild hydrotreating. Storage stability tests showed the blends to be stable. The blends were also soluble and compatible with most other Alberta crudes.

  2. DOE - Office of Legacy Management -- Quality Hardware and Machine Co - IL

    Office of Legacy Management (LM)

    11 Quality Hardware and Machine Co - IL 11 FUSRAP Considered Sites Site: QUALITY HARDWARE AND MACHINE CO. (IL.11) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Ravenswood Venture Marden Manufacturing Co. IL.11-1 IL.11-2 Location: 5823/5849 North Ravenswood Avenue , Chicago , Illinois IL.11-3 Evaluation Year: 1990 IL.11-4 IL.11-5 Site Operations: From 1944 to 1945, entered into subcontracts with the University of Chicago to furnish personnel,

  3. DOE - Office of Legacy Management -- C-B Tool Products Co - IL 31

    Office of Legacy Management (LM)

    C-B Tool Products Co - IL 31 FUSRAP Considered Sites Site: C-B Tool Products Co. (IL.31 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 956 East 58th Street , Chicago , Illinois IL.31-1 Evaluation Year: 1990 IL.31-2 Site Operations: Provided personnel, facilities, and equipment to produce special machining of parts for special equipment from materials furnished by the University. IL.31-4 Site Disposition: Eliminated - Potential for

  4. DOE - Office of Legacy Management -- Era Tool and Engineering Co - IL 29

    Office of Legacy Management (LM)

    Era Tool and Engineering Co - IL 29 FUSRAP Considered Sites Site: Era Tool and Engineering Co. (IL.29 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Audi-Tex Industries, Incorporated IL.29-1 Location: 4555 West Addison Street , Chicago , Illinois IL.29-2 Evaluation Year: 1989 IL.29-3 Site Operations: From February 1944 through June 1944, provided personnel, facilities, and equipment to produce machined parts for special equipment, tools, jigs,

  5. DOE - Office of Legacy Management -- Max Zuckerman and Sons - IL 30

    Office of Legacy Management (LM)

    - IL 30 FUSRAP Considered Sites Site: MAX ZUCKERMAN & SONS (IL.30 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 1925 N. Kenmore Avenue , Chicago , Illinois IL.30-1 Evaluation Year: 1994 IL.30-2 Site Operations: Sample sized quantities of radioactive materials were shipped through this location; broker arranged purchases of materials for third party buyers. IL.30-2 Site Disposition: Eliminated - Potential for contamination

  6. DOE - Office of Legacy Management -- Museum of Science and Industry - IL 03

    Office of Legacy Management (LM)

    Museum of Science and Industry - IL 03 FUSRAP Considered Sites Site: MUSEUM OF SCIENCE AND INDUSTRY ( IL.03 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 57th Street and Lake Shore Drive , Chicago , Illinois IL.03-1 Evaluation Year: 1985 IL.03-2 IL.03-3 Site Operations: The Metallurgical Laboratory and Argonne National Laboratory occupied space in the Museum of Science and Industry from August 15, 1946 to July 15, 1953. Some handling

  7. Electronic and optical properties of TaO{sub 1-x}N{sub 1+x}-based alloys

    SciTech Connect (OSTI)

    Al-Aqtash, Nabil; Apostol, Florin; Mei, Wai-Ning; Sabirianov, Renat F.; Nebraska Center for Materials and Nanoscience, University of Nebraska, Lincoln, NE 68588

    2013-02-15

    TaON is considered as a potential candidate as a visible-light responsive photocatalyst. We report the results of ab initio studies of electronic structure of TaON-based alloys. Specifically, we show that the position of conduction and valence band can be modified by varying the oxygen and nitrogen concentrations in TaO{sub 1-x}N{sub 1+x}. We find that the band gap decreases monotonically with the increase of N/O ratio. The band gap energy is decreased in monoclinic TaON from near 2.3 eV to just over 1.7 eV (i.e., by 35%) when N/O ratio is increased from 3/5 to 5/3. Our calculations show that the band gap reduces in a series of experimentally fabricated alloys ZrTa{sub 3}O{sub 5}N{sub 3}{yields}TaON{yields}YTa{sub 7}O{sub 7}N{sub 8}. The band gap reduction is mostly associated with the change in the position of the valence band due to the hybridization of N 2p states, while the conduction band consisting mostly of Ta 5d-states is not sensitive to N content. The calculated optical absorption spectra show reduction in the optical band gap with increasing N/O ratio. - Graphical abstract: Band gap energy of TaO{sub 1-x}N{sub 1+x} as a function of N/O ratio. Highlights: Black-Right-Pointing-Pointer The electronic and optical properties of TaON-based alloys are studied using DFT. Black-Right-Pointing-Pointer The position of conduction and valence bands can be modified by varying N/O ratio. Black-Right-Pointing-Pointer The band gap decreases monotonically with the increase of N/O ratio in TaO{sub 1-x}N{sub 1+x}. Black-Right-Pointing-Pointer The band gap reduces in a series of fabricated alloys ZrTa{sub 3}O{sub 5}N{sub 3}{yields}TaON{yields}YTa{sub 7}O{sub 7}N{sub 8}. Black-Right-Pointing-Pointer The optical band gap decreases with the increase of N/O ratio.

  8. Acidic environment augments FcεRI-mediated production of IL-6 and IL-13 in mast cells

    SciTech Connect (OSTI)

    Kamide, Yosuke; Ishizuka, Tamotsu; Tobo, Masayuki; Tsurumaki, Hiroaki; Aoki, Haruka; Mogi, Chihiro; Nakakura, Takashi; Yatomi, Masakiyo; Ono, Akihiro; Koga, Yasuhiko; Sato, Koichi; Hisada, Takeshi; Dobashi, Kunio; Yamada, Masanobu; Okajima, Fumikazu

    2015-08-28

    Although blood pH is maintained in a narrow range of around pH 7.4 in living organisms, inflammatory loci are characterized by acidic conditions. Mast cells tend to reside close to the surface of the body in areas such as the mucosa and skin where they may be exposed to exogenous acids, and they play an important role in immune responses. However, little is known about the effects of extracellular acidification on the functions of mast cell. Here, we found that extracellular acidification increased the dinitrophenyl-conjugated human serum albumin (DNP-HSA)-induced production of interleukin (IL)-6 and IL-13 in MC/9 cells or bone marrow-derived mouse mast cells sensitized with anti-DNP IgE. Extracellular acidification also inhibited migration of MC/9 cells toward DNP-HSA. In addition, acidic pH stimulated antigen-induced activation of p38 mitogen-activated protein kinase (MAPK) and protein kinase B (Akt). These findings suggest that extracellular acidification augmented antigen/IgE-induced and FcεRI-mediated production of IL-6 and IL-13 in mast cells, and that this was associated with the enhancement of p38 MAPK and Akt activation. - Highlights: • Antigen-induced IL-6 and IL-13 production was augmented by acidic pH in mast cells. • Acidic pH-induced actions were associated with activation of p38 MAPK and Akt. • Inhibition of p38 MAPK and Akt attenuated cytokine responses to acidic pH. • Acidic pH effects are not attributable to actions of known proton-sensing GPCRs.

  9. Competing decay modes of a high-spin isomer in the proton-unbound nucleus ??Ta*

    SciTech Connect (OSTI)

    Carroll, R. J.; Page, R. D.; Joss, D. T.; Uusitalo, J.; Darby, I. G.; Andgren, K.; Cederwall, B.; Eeckhaudt, S.; Grahn, T.; Gray-Jones, C.; Greenlees, P. T.; Hadinia, B.; Jones, P. M.; Julin, R.; Juutinen, S.; Leino, M.; Leppnen, A. -P.; Nyman, M.; O'Donnell, D.; Pakarinen, J.; Rahkila, P.; Sandzelius, M.; Sarn, J.; Scholey, C.; Seweryniak, D.; Simpson, J.

    2015-01-01

    An isomeric state at high spin and excitation energy was recently observed in the proton-unbound nucleus 158Ta. This state was observed to decay by both ? and ? decay modes. The large spin change required to decay via ?-ray emission incurs a lifetime long enough for ? decay to compete. The ? decay has an energy of 8644(11) keV, which is among the highest observed in the region, a partial half-life of 440(70) ?s and changes the spin by 11?. In this study, additional evidence supporting the assignment of this ? decay to the high-spin isomer in 158Ta will be presented.

  10. Reliability analysis for the facility data acquisition interface system upgrade at TA-55

    SciTech Connect (OSTI)

    Turner, W.J.; Pope, N.G.; Brown, R.E.

    1995-05-01

    Because replacement parts for the existing facility data acquisition interface system at TA-55 have become scarce and are no longer being manufactured, reliability studies were conducted to assess various possible replacement systems. A new control system, based on Allen-Bradley Programmable Logic Controllers (PLCs), was found to have a likely reliability 10 times that of the present system, if the existing Continuous Air Monitors (CAMS) were used. Replacement of the old CAMs with new CAMs will result in even greater reliability as these are gradually phased in. The new PLC-based system would provide for hot standby processors, redundant communications paths, and redundant power supplies, and would be expandable and easily maintained, as well as much more reliable. TA-55 is the Plutonium Processing Facility which processes and recovers Pu-239 from scrap materials.

  11. Multiband Te p Based Superconductivity of Ta4Pd3Te16

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Singh, David J.

    2014-10-06

    We recently discovered that Ta4Pd3Te16 is a superconductor that has been suggested to be an unconventional superconductor near magnetism. Here, we report electronic structure calculations showing that despite the layered crystal structure the material is an anisotropic three-dimensional (3D) metal. The Fermi surface contains prominent one-dimensional (1D) and two-dimensional (2D) features, including nested 1D sheets, a 2D cylindrical section, and a 3D sheet. Moreover, the electronic states that make up the Fermi surface are mostly derived from Te p states with small Ta d and Pd d contributions. This places the compound far from magnetic instabilities. The results are discussedmore » in terms of multiband superconductivity.« less

  12. Preliminary results for HIP bonding Ta to W targets for the materials test station

    SciTech Connect (OSTI)

    Dombrowski, David E; Maloy, Stuart A

    2009-01-01

    Tungsten targets for the Materials Test Station (MTS) were clad with thin tantalum cover plates and a tantalum frame using hot isostatic pressing (HIP). A preliminary HIP parameter study showed good bonding and intimate mechanical contact for Ta cover plate thicknesses of 0.25 mm (0.010 inch) and 0.38 mm (0.015 inch). HIP temperatures of full HIP runs were 1500 C (2732 F). HIP pressure was 203 MPa (30 ksi).

  13. Regulation study for the facility control system design at the Facility Operations Center at TA55

    SciTech Connect (OSTI)

    1994-03-16

    NMT-8 is proposing to upgrade the existing Facility Control System (FCS) located within the Facility Operations Center (FOC) at the TA-55 Plutonium Processing and Handling Facility (PPHF). The FCS modifications will upgrade the existing electronics to provide better reliability of system functions. Changes include replacement of the FCS computers and field multiplex units which are used for transmitting systems data. Data collected at the FCS include temperature, pressure, contact closures, etc., and are used for monitoring and/or control of key systems at TA-55. Monitoring is provided for the electrical power system status, PF-4 HVAC air balance status (Static Differential pressure), HVAC fan system status, site chill water return temperature, fire system information, and radioactive constant air monitors alarm information, site compressed air pressure and other key systems used at TA-55. Control output signals are provided for PF-4 HVAC systems, and selected alarms for criticality, fire, loss of pressure in confinement systems. A detailed description of the FCS modifications is provided in Section 2.

  14. Pressure-induced amorphization of La{sub 1/3}TaO{sub 3}

    SciTech Connect (OSTI)

    Noked, O.; Melchior, A.; Shuker, R.; Livneh, T.; Steininger, R.; Kennedy, B.J.; Sterer, E.

    2013-06-15

    La{sub 1/3}TaO{sub 3}, an A-site cation deficient perovskite, has been studied under pressure by synchrotron X-ray powder diffraction and Raman spectroscopy. It undergoes irreversible pressure induced amorphization at P=18.5 GPa. An almost linear unit cell volume decrease vs. pressure is observed from ambient pressure up to the phase transition. The Raman spectroscopy also shows amorphization at the same pressure, with positive shifts of all modes as a function of pressure. The pressure dependence of the E{sub g} and A{sub 1g} Raman modes arising from the octahedral oxygen network is discussed. - Graphical abstract: La{sub 1/3}Tao{sub 3} exhibits linear pressure–volume relation until irreversible pressure induced amorphization at 18.5 Gpa. - Highlights: • La{sub 1/3}TaO{sub 3} has been studied under pressure by synchrotron XRD and Raman spectroscopy. • La{sub 1/3}TaO{sub 3} undergoes irreversible pressure induced amorphization around 18.5 GPa. • The transition is manifested in both XRD and Raman measurements. • A linear P–V relation is observed from ambient pressure up to the phase transition.

  15. Isothermal oxidation behavior and microstructure of plasma surface Ta coating on ?-TiAl

    SciTech Connect (OSTI)

    Song, Jian; Zhang, Ping-Ze Wei, Dong-Bo; Wei, Xiang-Fei; Wang, Ya

    2014-12-15

    The oxidation behavior of ?-TiAl with Ta surface coating fabricated by double glow plasma surface alloying technology was investigated by thermogravimetric method. Oxidation experiments were carried out at 750 C and 850 C in air for 100 h. The modification layer was comprised of deposition layer and diffusion layer, which metallurgically adhered to the substrate. Tantalum element decreased with the case depth. The oxidation morphology was studied by a scanning electron microscope and X-ray diffraction. The results highlighted that in the oxidizing process of the oxidation, the phase containing Ta-richer may restrain diffusing outward of the element Al in the matrix. Ti diffused outward, and formed the TiO{sub 2} scales, while the middle layer was rich in Al, and formed the continuous Al{sub 2}O{sub 3} scales after oxidation, which was effective to prevent further infiltration of oxygen atoms, and as a result the oxidation resistance increased immensely. - Highlights: A Ta modified coating was prepared on ?-TiAl using DGP surface alloying technology. The modification layer metallurgically adhered to the substrate. The bonding force is about 60 N, satisfying the demands of practical use. The oxidation resistance increased immensely at 750 C and 850 C.

  16. DOE - Office of Legacy Management -- Eimco Corp - IL 0-01

    Office of Legacy Management (LM)

    Eimco Corp - IL 0-01 FUSRAP Considered Sites Site: Eimco Corp. (IL.0-01 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Palatine , Illinois IL.0-01-1 Evaluation Year: 1987 IL.0-01-1 Site Operations: Conducted laboratory leaf filtration tests IL.0-01-1 Site Disposition: Eliminated - Potential for contamination considered remote based on the limited scope of activities at the site IL.0-01-1 Radioactive Materials Handled: Yes Primary

  17. DOE - Office of Legacy Management -- Granite City Army Depot - IL 0-02

    Office of Legacy Management (LM)

    Granite City Army Depot - IL 0-02 FUSRAP Considered Sites Site: GRANITE CITY ARMY DEPOT ( IL.0-02 ) Eliminated from consideration under FUSRAP - Referred to DOD Designated Name: Not Designated Alternate Name: None Location: Granite City , Illinois IL.0-02-1 Evaluation Year: 1987 IL.0-02-1 Site Operations: Site was used for storage of GSA thorium residues until circa 1964. IL.0-02-1 Site Disposition: Eliminated - Referred to DOD IL.0-02-1 Radioactive Materials Handled: Yes Primary Radioactive

  18. DOE - Office of Legacy Management -- Midwest Manufacturing Co - IL 0-04

    Office of Legacy Management (LM)

    Midwest Manufacturing Co - IL 0-04 FUSRAP Considered Sites Site: MIDWEST MANUFACTURING CO (IL.0-04 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Evaluation Year: 1987 IL.0-04-3 Site Operations: Research and development on deep drawing of sheet metal in the mid- 1940s. IL.0-04-3 Site Disposition: Site Disposition IL.0-04-1 IL.0-04-3 Radioactive Materials Handled: None Indicated Primary Radioactive Materials Handled: None Indicated

  19. DOE - Office of Legacy Management -- Sciaky Brothers Inc - IL 0-06

    Office of Legacy Management (LM)

    Sciaky Brothers Inc - IL 0-06 FUSRAP Considered Sites Site: SCIAKY BROTHERS, INC (IL.0-06 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 4915 West 67th Street , Chicago , Illinois IL.0-06-1 Evaluation Year: 1987 IL.0-06-2 Site Operations: One time operation involving stitch welding of uranium in 1953. IL.0-06-1 IL.0-06-2 Site Disposition: Eliminated - Potential for contamination considered remote based on limited operations at the site

  20. Structure, magnetism, specific heat, and dielectric properties of Eu{sub 2}Ta{sub 2}O{sub 7}

    SciTech Connect (OSTI)

    Kolodiazhnyi, T. Sakurai, H.; Matsushita, Y.

    2014-11-17

    Polycrystalline Eu{sub 2}Ta{sub 2}O{sub 7} containing layered perovskite slabs was prepared and analyzed. Eu{sub 2}Ta{sub 2}O{sub 7} crystallizes in the orthorhombic centrosymmetric Cmcm space group (with unit cell: a?=?3.95156(9), b?=?27.0775(6), and c?=?5.68279(13) ) isomorphous with high-temperature Sr{sub 2}Ta{sub 2}O{sub 7}. Dielectric measurements reveal that, in contrast to Sr{sub 2}Ta{sub 2}O{sub 7} which is ferroelectric below 166?K, Eu{sub 2}Ta{sub 2}O{sub 7} remains paraelectric down to at least 0.45?K and shows no magneto-dielectric coupling. Magnetic data in the 2400?K range indicate an antiferromagnetic phase transition with a sharp susceptibility peak at 2.71(5) K. Further analysis using specific heat measurements reveals that the second magnetic phase transition occurs at 1.10(5) K and dominates the spin entropy of the Eu{sup 2+} 4f{sup 7} ions. The possible origin of the two successive magnetic phase transitions in Eu{sub 2}Ta{sub 2}O{sub 7} requires further studies.

  1. In Situ Photoelectron Emission Microscopy of a Thermally Induced Martensitic Transformation in a CuZnAI Shape Memory Alloy

    SciTech Connect (OSTI)

    Xiong, Gang; Joly, Alan G.; Beck, Kenneth M.; Hess, Wayne P.; Cai, Mingdong; Langford, Stephen C.; Dickinson, J T.

    2006-02-27

    Photoemission electron microscopy, in conjunction with photoemission spectroscopy, reflectivity, and surface roughness measurements, is used to study the thermally-induced martensitic transformation in a CuZnAI shape memory alloy. Real-time phase transformation is observed as a nearly instantaneous change of photoelectron intensity, accompanied by microstructural deformation and displacement due to the shape memory effect. The difference in the photoelectron intensity before and after the phase transformation is attributed to the concomitant change of work function as measured by photoelectron spectroscopy. Photoemission electron microscopy is shown to be a valuable new technique facilitating the study of phase transformations in shape memory alloys, and provides real-time information on microstructural changes and phase-dependent electronic properties.

  2. Observation of surface to bulk interatomic Auger decay from Ta(100)

    SciTech Connect (OSTI)

    Jensen, E. ); Bartynski, R.A. ); Weinert, M. ); Hulbert, S.L.; Johnson, E.D.; Garrett, R.F. )

    1990-06-15

    Core-valence-valence ({ital CVV}) Auger spectra from Ta(100) taken in coincidence with bulk and surface-shifted 4{ital f}{sub 7/2} core-level emission are presented. These data are compared with self-convolutions of calculations of the {ital d}-band densities of states for the surface and subsurface layers of a nine-layer slab. Agreement of the bulk spectrum with the calculation is good; agreement for the surface spectrum is very poor. These data are explained by proposing an interatomic surface to bulk Auger decay mode for the surface core hole that is competitive with the conventional {ital CVV} decay process.

  3. Seismic Vulnerability Assessment Waste Characterization Reduction and Repackaging Building, TA-50-69

    SciTech Connect (OSTI)

    M.W.Sullivan; J.Ruminer; I.Cuesta

    2003-02-02

    This report presents the results of the seismic structural analyses completed on the Waste Characterization Reduction and Repackaging (WCRR) Building in support of ongoing safety analyses. WCRR is designated as TA-50-69 at Los Alamos National Laboratory, Los Alamos, New Mexico. The facility has been evaluated against Department of Energy (DOE) seismic criteria for Natural Phenomena Hazards (NPH) Performance Category II (PC 2). The seismic capacities of two subsystems within the WCRR building, the material handling glove box and the lift rack immediately adjacent to the Glove Box are also documented, and the results are presented.

  4. Multiband semimetallic electronic structure of superconducting Ta2PdSe5

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Singh, David Joseph

    2015-04-24

    We report the electronic structure and related properties of the superconductor Ta2PdSe5 as determined from density functional calculations. The Fermi surface has two disconnected sheets, both derived from bands of primarily chalcogenide p states. These are a corrugated hole cylinder and a heavier complex shaped electron sheet. The sheets contain 0.048 holes and a compensating number of electrons per formula unit, making the material a semimetallic superconductor. The results support the presence of two band superconductivity, although a discrepancy in the specific heat is noted. This discrepancy is discussed as a possible consequence of Pd deficiency in samples.

  5. Water Resistant Container Technical Basis Document for the TA-55 Criticality Safety Program

    SciTech Connect (OSTI)

    Smith, Paul Herrick; Teague, Jonathan Gayle

    2015-04-30

    Criticality safety at TA-55 relies on nuclear material containers that are water resistant to prevent significant amounts of water from coming into contact with fissile material in the event of a fire that causes a breach of glovevbox confinement and subsequent fire water ingress. A “water tight container” is a container that will not allow more than 50ml of water ingress when fully submerged, except when under sufficient pressure to produce structural discontinuity. There are many types of containers, welded containers, hermetically sealed containers, filtered containers, etc.

  6. Magnetization reversal induced by in-plane current in Ta/CoFeB/MgO structures with perpendicular magnetic easy axis

    SciTech Connect (OSTI)

    Zhang, C.; Yamanouchi, M. Ikeda, S.; Sato, H.; Fukami, S.; Matsukura, F.; Ohno, H.

    2014-05-07

    We investigate in-plane current-induced magnetization reversal under an in-plane magnetic field in Hall bar shaped devices composed of Ta/CoFeB/MgO structures with perpendicular magnetic easy axis. The observed relationship between the directions of current and magnetization switching and Ta thickness dependence of magnetization switching current are accordance with those for magnetization reversal by spin transfer torque originated from the spin Hall effect in the Ta layer.

  7. DOE - Office of Legacy Management -- Morse Chemical Co - IL 0-05

    Office of Legacy Management (LM)

    Morse Chemical Co - IL 0-05 FUSRAP Considered Sites Site: MORSE CHEMICAL CO. (IL.0-05 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 8 South Michigan Avenue , Chicago , Illinois IL.05-1 Evaluation Year: 1987 IL.05-3 Site Operations: Submitted a bid to AEC for thorium work; proposal was not accepted; no indication work done for a DOE predecessor at this site. IL.05-3 Site Disposition: Eliminated - No Authority - No work for a DOE

  8. Preparation, characterization of the Ta-doped ZnO nanoparticles and their photocatalytic activity under visible-light illumination

    SciTech Connect (OSTI)

    Kong Jizhou; Li Aidong; Zhai Haifa; Gong Youpin; Li Hui; Wu Di

    2009-08-15

    This paper describes a novel catalyst of the Ta-doped ZnO nanocrystals prepared by a modified polymerizable complex method using the water-soluble tantalum precursor as the sources of Ta. The catalysts were characterized by means of various analytical techniques as a function of Ta content (x=0-4 mol%) systematically. A remarkable advantage of the results was confirmed that dopant Ta enhanced the visible-light absorption of ZnO and the low-solubility tantalum doping could restrain the growth of crystal and minish the particle size. The relationship between the physicochemical property and the photocatalytic performance was discussed, and it was found that the photocatalytic activity in the photochemical degradation of methylene blue under visible-light irradiation (lambda>=420 nm) was dependent on the contents of the dopant, which could affect the particle size, concentration of surface hydroxyl groups and active hydrogen-related defect sites, and the visible-light absorption. The highest photocatalytic activity was obtained for the 1.0 mol% Ta-doped ZnO sample. - Graphical abstract: The addition of the tantalum into ZnO prepared by a modified polymerizable complex method not only restrains the growth of crystal, minish the particle size, but also changes the nanocrystal morphology.

  9. Dependence of inverse-spin Hall effect and spin-rectified voltage on tantalum thickness in Ta/CoFeB bilayer structure

    SciTech Connect (OSTI)

    Kim, Sang-Il; Seo, Min-Su; Park, Seung-Young; Kim, Dong-Jun; Park, Byong-Guk

    2015-01-19

    Ta-layer thickness (t{sub Ta}) dependence of the measured DC voltage V from the inverse-spin Hall effect (ISHE) in Ta/CoFeB bilayer structure is experimentally investigated using the ferromagnetic resonance in the TE{sub 011} resonant cavity. The ISHE signals excluding the spin-rectified effect (SRE) were separated from the fitted curve of V against t{sub Ta}. For t{sub Ta} ≈ λ{sub Ta} (Ta-spin diffusion length = 2.7 nm), the deviation in ISHE voltage V{sub ISH} between the experimental and theoretical values is significantly increased because of the large SRE contribution, which also results in a large deviation in the spin Hall angle θ{sub SH} (from 10% to 40%). However, when t{sub Ta} ≫ λ{sub Ta}, the V{sub ISH} values are consistent with theoretical values because the SRE terms become negligible, which subsequently improves the accuracy of the obtained θ{sub SH} within 4% deviation. The results will provide an outline for an accurate estimation of the θ{sub SH} for materials with small λ value, which would be useful for utilizing the spin Hall effect in a 3-terminal spintronic devices in which magnetization can be controlled by in-plane current.

  10. High Nb, Ta, and Al creep- and oxidation-resistant austenitic stainless steel

    DOE Patents [OSTI]

    Brady, Michael P [Oak Ridge, TN; Santella, Michael L [Knoxville, TN; Yamamoto, Yukinori [Oak Ridge, TN; Liu, Chain-tsuan [Oak Ridge, TN

    2010-07-13

    An austenitic stainless steel HTUPS alloy includes, in weight percent: 15 to 30 Ni; 10 to 15 Cr; 2 to 5 Al; 0.6 to 5 total of at least one of Nb and Ta; no more than 0.3 of combined Ti+V; up to 3 Mo; up to 3 Co; up to 1 W; up to 0.5 Cu; up to 4 Mn; up to 1 Si; 0.05 to 0.15 C; up to 0.15 B; up to 0.05 P; up to 1 total of at least one of Y, La, Ce, Hf, and Zr; less than 0.05 N; and base Fe, wherein the weight percent Fe is greater than the weight percent Ni wherein said alloy forms an external continuous scale comprising alumina, nanometer scale sized particles distributed throughout the microstructure, said particles comprising at least one composition selected from the group consisting of NbC and TaC, and a stable essentially single phase fcc austenitic matrix microstructure, said austenitic matrix being essentially delta-ferrite-free and essentially BCC-phase-free.

  11. A new anatase-type phase in the system Mg-Ta-O-N

    SciTech Connect (OSTI)

    Schilling, H.; Lerch, M. . E-mail: lerch@chem.tu-berlin.de; Boerger, A.; Becker, K.-D.; Wolff, H.; Dronskowski, R.; Bredow, T.; Tovar, M.; Baehtz, C.

    2006-08-15

    Magnesium doped tantalum oxynitrides were prepared by ammonolysis of amorphous mixed oxides. An orange colored anatase-type phase with the composition Mg{sub 0.05}Ta{sub 0.95}O{sub 1.15}N{sub 0.85} was found. It is metastable and undergoes a phase transformation to a baddeleyite-type phase between 900 and 1000deg. C. X-ray diffraction measurements indicate spacegroup I4{sub 1}/amd with lattice parameters a=391.986(6)pm and c=1011.19(3)pm. A possible anion ordering was examined by theoretical methods and neutron diffraction experiments. In addition, anosovite-type (Ti{sub 3}O{sub 5}) phases Mg{sub x}Ta{sub 3-x}O{sub 3x}N{sub 5-3x}; 0=

  12. Microstructure and mechanical properties of Ti-35Nb-6Ta alloy after thermomechanical treatment

    SciTech Connect (OSTI)

    Malek, J.; Hnilica, F.; Vesely, J.; Smola, B.; Bartakova, S.; Vanek, J.

    2012-04-15

    The influence of thermo-mechanical treatment on microstructure and mechanical properties of T-35Nb-6Ta has been studied. The thermo-mechanical treatment was chosen to correspond to the production of wire with suitable mechanical properties for dental implants. After casting the alloy was hot forged (700-900 Degree-Sign C), solution treated (850 Degree-Sign C/30 min, water quenched) and cold swaged (reductions up to 91%). The annealing (700 Degree-Sign C/3 h/furnace) or aging (450 Degree-Sign C/8 h/furnace) was used as final heat treatment. The microstructure was studied by using light microscopy, scanning electron microscopy, transmission electron microscopy and XRD analysis. Cold swaging introduces microstructure consisting of highly deformed {beta}-phase grains with dislocation tangles and twins, which ensures high tensile strength about 820 MPa, low Young's modulus ({approx} 50 GPa) and good ductility {approx} 10%. Subsequent aging increases tensile strength (1000 MPa) as well as Young's modulus (75 GPa) without diminishing ductility. Annealing at 700 Degree-Sign C slightly decreases tensile strength (730 MPa) and increases the ductility and Young's modulus (17% and 62 GPa respectively). The mechanical properties attained recommend the thermo-mechanical treatment for production of wires for dental implants. - Highlights: Black-Right-Pointing-Pointer Ti35Nb6Ta alloy prepared via arc melting. Black-Right-Pointing-Pointer Thermo mechanical treatment. Black-Right-Pointing-Pointer Microstructural changes. Black-Right-Pointing-Pointer Mechanical properties.

  13. Charge trapping of Ge-nanocrystals embedded in TaZrO{sub x} dielectric films

    SciTech Connect (OSTI)

    Lehninger, D. Seidel, P.; Geyer, M.; Schneider, F.; Heitmann, J.; Klemm, V.; Rafaja, D.; Borany, J. von

    2015-01-12

    Ge-nanocrystals (NCs) were synthesized in amorphous TaZrO{sub x} by thermal annealing of co-sputtered Ge-TaZrO{sub x} layers. Formation of spherical shaped Ge-NCs with small variation of size, areal density, and depth distribution was confirmed by high-resolution transmission electron microscopy. The charge storage characteristics of the Ge-NCs were investigated by capacitance-voltage and constant-capacity measurements using metal-insulator-semiconductor structures. Samples with Ge-NCs exhibit a maximum memory window of 5 V by sweeping the bias voltage from −7 V to 7 V and back. Below this maximum, the width of the memory window can be controlled by the bias voltage. The fitted slope of the memory window versus bias voltage characteristics is very close to 1 for samples with one layer Ge-NCs. A second layer Ge-NCs does not result in a second flat stair in the memory window characteristics. Constant-capacity measurements indicate charge storage in trapping centers at the interfaces between the Ge-NCs and the surrounding materials (amorphous matrix/tunneling oxide). Charge loss occurs by thermal detrapping and subsequent band-to-band tunneling. Reference samples without Ge-NCs do not show any memory window.

  14. Development of Ta-based Superconducting Tunnel Junction X-ray Detectors for Fluorescence XAS

    SciTech Connect (OSTI)

    Friedrich, S; Drury, O; Hall, J; Cantor, R

    2009-09-23

    We are developing superconducting tunnel junction (STJ) soft X-ray detectors for chemical analysis of dilute samples by fluorescence-detected X-ray absorption spectroscopy (XAS). Our 36-pixel Nb-based STJ spectrometer covers a solid angle {Omega}/4{pi} {approx} 10{sup -3}, offers an energy resolution of {approx}10-20 eV FWHM for energies up to {approx}1 keV, and can be operated at total count rates of {approx}10{sup 6} counts/s. For increased quantum efficiency and cleaner response function, we have now started the development of Ta-based STJ detector arrays. Initial devices modeled after our Nb-based STJs have an energy resolution below 10 eV FWHM for X-ray energies below 1 keV, and pulse rise time discrimination can be used to improve their response function for energies up to several keV. We discuss the performance of the Ta-STJs and outline steps towards the next-generation of large STJ detector arrays with higher sensitivity.

  15. Preliminary assessment of numerical data requirements TA-73 landfill Los Alamos, New Mexico

    SciTech Connect (OSTI)

    Not Available

    1993-11-19

    A numerical model, TOUGH2, was selected for describing liquid- and gas-phase flow in the unsaturated tuff underlying the TA-73 landfill. The model was selected primarily for its ability to simulate the significant mechanisms that may affect transport of contaminants through the vadose zone at the TA-73 landfill, including non-isothermal flow through fractured media. TOUGH2 is the best documented, verified, and validated model capable of performing the required simulations. The sensitivity analyses that were performed and describes in this report identified the input parameters that the selected numerical model is most sensitive to. The input parameters analyzed were saturated hydraulic conductivity, van Genuchten {alpha} and n, residual and saturated moisture contents, infiltration rate, fracture spacing and permeability, atmospheric pressure, and temperature. The sensitivity analyses were performed using a model grid that was designed to incorporate the regions in the landfill vicinity where contaminant transport is likely to occur and where the physical processes affecting flow and transport are the most dynamic. The sensitivity analyses performed suggest that the model is quite sensitive to a number of input parameters, including saturated hydraulic conductivity, the van Genuchten parameters {alpha} and n (for both the tuff matrix and fractures), fracture density and aperture, and atmospheric pressure. The results indicate that additional site-specific hydraulic properties and fracture data should be obtained before attempting to perform predictive, numerical simulations of gas- and liquid-phase flow beneath the landfill.

  16. Synthesis and magnetic properties of Ta/NdFeB-based composite microwires

    SciTech Connect (OSTI)

    Szary, P. Prigo, E. A.; Michels, A.; Luciu, I.; Duday, D.; Wirtz, T.; Choquet, P.

    2015-05-07

    Magnetic NdFeB-based microwire composites have been prepared by the direct current magnetron sputtering technique in a specifically designed sputtering chamber for thin-film deposition in wire geometry. As substrate wire material, we have employed steel and Ta. Annealing of the substrate wires during the deposition process was performed by ohmic heating through the application of a direct current. Samples were characterized by means of vibrating sample magnetometry (VSM) and scanning electron microscopy. Best properties have been encountered when using Ta wires as core (substrate) material. The VSM data show a dramatic impact of the current applied during the deposition process on the magnetic properties. For higher current values, i.e., higher annealing temperatures, the wires exhibit a reversal process that is typical for a two-phase system. Moreover, an increase of the coercive field (and remanent magnetization) is observed, which is ascribed to a modification of the magnetic phase present in the sample due to the annealing. We find an indication for the formation of a magnetic easy-axis direction which is azimuthally oriented around the wire axis.

  17. Polytypism, polymorphism, and superconductivity in TaSe2–xTex

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luo, Huixia; Xie, Weiwei; Tao, Jing; Inoue, Hiroyuki; Gyenis, András; Krizan, Jason W.; Yazdani, Ali; Zhu, Yimei; Cava, Robert Joseph

    2015-03-03

    Polymorphism in materials often leads to significantly different physical properties - the rutile and anatase polymorphs of TiO₂ are a prime example. Polytypism is a special type of polymorphism, occurring in layered materials when the geometry of a repeating structural layer is maintained but the layer stacking sequence of the overall crystal structure can be varied; SiC is an example of a material with many polytypes. Although polymorphs can have radically different physical properties, it is much rarer for polytypism to impact physical properties in a dramatic fashion. Here we study the effects of polytypism and polymorphism on the superconductivitymore » of TaSe₂, one of the archetypal members of the large family of layered dichalcogenides. We show that it is possible to access 2 stable polytypes and 2 stable polymorphs in the TaSe2-xTex solid solution, and find that the 3R polytype shows a superconducting transition temperature that is between 6 and 17 times higher than that of the much more commonly found 2H polytype. Thus, the reason for this dramatic change is not apparent, but we propose that it arises either from a remarkable dependence of Tc on subtle differences in the characteristics of the single layers present, or from a surprising effect of the layer stacking sequence on electronic properties that instead are expected to be dominated by the properties of a single layer in materials of this kind.« less

  18. Polytypism, polymorphism, and superconductivity in TaSe2-xTex

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luo, Huixia; Tao, Jing; Xie, Weiwei; Inoue, Hiroyuki; Gyenis, Andras; Krizan, Jason W.; Yazdani, Ali; Zhu, Yimei; Cava, R. J.

    2015-03-17

    Polymorphism in materials often leads to significantly different physical properties - the rutile and anatase polymorphs of TiO? are a prime example. Polytypism is a special type of polymorphism, occurring in layered materials when the geometry of a repeating structural layer is maintained but the layer stacking sequence of the overall crystal structure can be varied; SiC is an example of a material with many polytypes. Although polymorphs can have radically different physical properties, it is much rarer for polytypism to impact physical properties in a dramatic fashion. Here we study the effects of polytypism and polymorphism on the superconductivitymoreof TaSe?, one of the archetypal members of the large family of layered dichalcogenides. We show that it is possible to access 2 stable polytypes and 2 stable polymorphs in the TaSe2-xTex solid solution, and find that the 3R polytype shows a superconducting transition temperature that is between 6 and 17 times higher than that of the much more commonly found 2H polytype. The reason for this dramatic change is not apparent, but we propose that it arises either from a remarkable dependence of Tc on subtle differences in the characteristics of the single layers present, or from a surprising effect of the layer stacking sequence on electronic properties that instead are expected to be dominated by the properties of a single layer in materials of this kind.less

  19. #iWNCD W ONTAININO Il@MQWm;

    Office of Legacy Management (LM)

    decontmlmtlon proceam takee longer than originally anticipated 'U&e order .are urgently required to prevent a shutdown. "Z, mo-1 ' 2lda.p - from 4a6-55 to a possible 4-5-55 based on the receipt of vendor's plantby 1-22-55. #iWNCD W ONTAININO Il@MQWm; ;g hours worked; Hours worked will be observed and under the control of . . M%-.'E.Section . (Copy of Vendorts letter of quotation dated l/5/55 is VAWNWWXlINALORDEt :Y $ u(,507.60 upoDRpuiI9APPROPAk &movND* 0 3375.00 (rllaxlmum) Field

  20. The problem of intermixing of metals possessing no mutual solubility upon explosion welding (Cu-Ta, Fe-Ag, Al-Ta)

    SciTech Connect (OSTI)

    Greenberg, B.A.; Ivanov, M.A.; Rybin, V.V.; Elkina, O.A.; Antonova, O.V.; Patselov, A.M.; Inozemtsev, A.V.; Plotnikov, A.V.; Volkova, A.Yu.; Besshaposhnikov, Yu.P.

    2013-01-15

    On the basis of the results obtained for joints of dissimilar metals such as copper-tantalum and iron-silver, the reason of immiscible suspensions mixing upon explosion welding has been cleared out. It has been found that the interface (plain or wavy) is not smooth and contains inhomogeneities, namely, cusps and local melting zones. The role of granulating fragmentation providing partitioning of initial materials as a main channel of input energy dissipation has been revealed. It has been shown that in joints of metals possessing normal solubility the local melting zones are true solutions, but if metals possess no mutual solubility the local melting zones are colloidal solutions. Realization of either emulsion or suspension variant takes place. The results can be used in the development of new joints of metals possessing no mutual solubility. - Highlights: Black-Right-Pointing-Pointer Immiscible pairs Ta/Cu and Fe/Ag are welded successfully by explosive welding. Black-Right-Pointing-Pointer Fragmentation provides for partitioning as the main energy dissipation channel. Black-Right-Pointing-Pointer Immiscible metals form colloidal solid solutions during solidification. Black-Right-Pointing-Pointer Melting and boiling temperatures ratio determines the colloidal solution type. Black-Right-Pointing-Pointer Local melting zones being in suspension form enhance welds hardening.

  1. Chemical stability of highly (0001) textured Sm(CoCu){sub 5} thin films with a thin Ta capping layer

    SciTech Connect (OSTI)

    Zhao Haibao; Wang Hao; Liu Xiaoqi; Wang Jianping; Zhang Tao

    2011-04-01

    With the highest magnetocrystalline anisotropy constant (Ku) among practical magnetic materials, SmCo{sub 5} could be a very attractive candidate for future high areal density magnetic recording. However, its corrosion resistance is always a concern in recording media applications. In this paper, the chemical stability and microstructures of highly (0001) textured Sm(CoCu){sub 5} thin films with and without a 3 nm Ta capping layer were reported. For Sm(CoCu){sub 5} thin films without a capping layer, the coercivity decreases significantly (from 8kOe to 1kOe) within one month. Sm(CoCu){sub 5} thin films capped with a thin Ta layer (3 nm) behave differently. Even exposed to a laboratory environment (25 deg. C) over 3 years, the Ta-capped Sm(CoCu){sub 5} thin films are stable in terms of structural and magnetic properties, i.e., there were no changes in X-ray diffraction peaks and vibrating sample magnetometer hysteresis loops. Microstructure of Ta-capped Sm(CoCu){sub 5} thin films showed that Sm(CoCu){sub 5} formed a domelike particle assembly structure on a smooth Ru underlayer and were well covered by partially oxidized Ta capping layer, as shown by TEM cross-section micrographs. Accelerated corrosion treatment (130 deg. C, 95% relative humidity, 6 h) was performed on Ta-capped Sm(CoCu){sub 5} thin films. X-ray photoelectron spectroscopy (XPS) results showed that no Co was detected on the sample surface before the corrosion treatment, but strong XPS signals of CoOx and Co(OH)x were observed after treatment. Therefore, none of our Sm(CoCu){sub 5} thin films can pass the accelerated corrosion test. Hcp-phased CoPt-alloys are proposed as better capping materials for Sm(CoCu){sub 5} thin films in future high-density magnetic recording applications.

  2. Synthesis of high-strength W-Ta ultrafine-grain composites

    SciTech Connect (OSTI)

    Ott, R. T.; Yang, X. Y.; Guyer, D. E.; Chauhan, S.; Sordelet, D. J.

    2015-09-30

    Bulk samples of an ultrafine-grained tungstentantalum composite alloy have been synthesized by consolidating mechanically milled composite powders. The grain growth during densification is limited due to the submicron-scale layering of the individual metals in the composite particles and the relatively low sintering temperature (1300 C). The ultrafine microstructure of the high-density (~99% theoretical density) samples leads to a high yield stress of ~3 GPa under quasi-static uniaxial compression. A tendency for Ta-rich solid-solution formation during densification was observed, and the high-temperature phase equilibria in the composite powders were examined further using high-energy x-ray diffraction at temperatures up to 1300 C.

  3. Preparation and photocatalytic activity for water splitting of Pt-Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays

    SciTech Connect (OSTI)

    Liu, Jing; Liu, Jiawen; Li, Zhonghua

    2013-02-15

    Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays were prepared by hydrothermal method from Ta{sub 2}O{sub 5} nanotube arrays, obtained by anodization of Ta foils, in Na{sub 2}CO{sub 3} solution at 150 Degree-Sign C. The as-synthesized samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), UV-vis diffuse reflectance spectra (UV-DRS) and X-ray photoelectron spectroscopy (XPS). Analysis results show that pyrochlore structure Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays have been successfully fabricated. The diameters and lengths of Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays are 50 nm and 4 {mu}m, respectively. The photocatalytic hydrogen production activities of the as-synthesized Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays are highly dependent on the hydrothermal reaction time and Na{sub 2}CO{sub 3} concentration, optimized reaction parameters are obtained. To further improve the photocatalytic activity for hydrogen evolution, Pt loaded Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays are prepared by photochemical reduction method. The Pt loaded samples exhibit much higher activity for hydrogen evolution than pure Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays. Moreover, the photocatalytic hydrogen properties are rather stable. - Graphical abstract: Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays were synthesized by hydrothermal method using Ta{sub 2}O{sub 5} nanotube arrays as a precursor. The loaded Pt enhances the photocatalytic activity for water splitting of Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays. Highlights: Black-Right-Pointing-Pointer Novel Na{sub 2}Ta{sub 2}O{sub 6} nanotube array films with pyrochlore structure were synthesized. Black-Right-Pointing-Pointer Na{sub 2}Ta{sub 2}O{sub 6} nanotube arrays are active for H{sub 2} evolution from aqueous CH{sub 3}OH solution. Black-Right-Pointing-Pointer The effect of hydrothermal conditions on photocatalytic activity was investigated. Black-Right-Pointing-Pointer Pt loading can improve the

  4. Measured Whole-House Performance of TaC Studios Test Home

    SciTech Connect (OSTI)

    Butler, T.; Curtis, O.; Stephenson, R.

    2013-12-01

    As part of the NAHB Research Center Industry Partnership, Southface partnered with TaC Studios, an Atlanta-based architecture firm specializing in residential and light commercial design, on the construction of a new test home in Atlanta, GA in the mixed humid climate. This home serves as a residence and home office for the firm's owners, as well as a demonstration of their design approach topotential and current clients. Southface believes the home demonstrates current best practices for the mixed-humid climate, including a building envelope featuring advanced air sealing details and low density spray foam insulation, glazing that exceeds ENERGY STAR requirements, and a high performance heating and cooling system. Construction quality and execution was a high priority for TaCStudios and was ensured by a third party review process. Post-construction testing showed that the project met stated goals for envelope performance, an air infiltration rate of 2.15 ACH50. The homeowners wished to further validate whole house energy savings through the project's involvement with Building America and this long-term monitoring effort. As a Building America test home, this homewas evaluated to detail whole house energy use, end use loads, and the efficiency and operation of the ground source heat pump and associated systems. Given that the home includes many non-typical end use loads including a home office, pool, landscape water feature, and other luxury features not accounted for in Building America modeling tools, these end uses were separately monitored todetermine their impact on overall energy consumption.

  5. Measured Whole-House Performance of TaC Studios Test Home

    SciTech Connect (OSTI)

    Butler, T.; Curtis, O.; Stephenson, R.

    2013-12-01

    As part of the NAHB Research Center Industry Partnership, Southface partnered with TaC Studios, an Atlanta-based architecture firm specializing in residential and light commercial design, on the construction of a new test home in Atlanta, GA, in the mixed humid climate. This home serves as a residence and home office for the firm's owners, as well as a demonstration of their design approach to potential and current clients. Southface believes the home demonstrates current best practices for the mixed-humid climate, including a building envelope featuring advanced air sealing details and low density spray foam insulation, glazing that exceeds ENERGY STAR requirements, and a high performance heating and cooling system. Construction quality and execution was a high priority for TaC Studios and was ensured by a third party review process. Post-construction testing showed that the project met stated goals for envelope performance, an air infiltration rate of 2.15 ACH50. The homeowners wished to further validate whole house energy savings through the project's involvement with Building America and this long-term monitoring effort. As a Building America test home, this home was evaluated to detail whole house energy use, end use loads, and the efficiency and operation of the ground source heat pump and associated systems. Given that the home includes many non-typical end use loads including a home office, pool, landscape water feature, and other luxury features not accounted for in Building America modeling tools, these end uses were separately monitored to determine their impact on overall energy consumption.

  6. Properties of Ta{sub 2}O{sub 5} thin films prepared by ion-assisted deposition

    SciTech Connect (OSTI)

    Farhan, Mansour S.; Zalnezhad, E.; Bushroa, A.R.

    2013-10-15

    Graphical abstract: - Highlights: • Investigating the effect of ion-beam parameters on optical properties. • Exploring the effect of ion-beam parameters on structural properties. • Studying XRD patterns of Ta{sub 2}O{sub 5} films deposited at different ion energies. - Abstract: Tantalum penta-oxide (Ta{sub 2}O{sub 5}) thin films were deposited onto highly polished and clean, fused silica glass substrates via ion beam-assisted deposition at room temperature using a high-vacuum coater equipped with an electron beam gun. The effects of ion beam parameters, oxygen flow rate, and deposition rate on the optical and structural properties as well as the stress of Ta{sub 2}O{sub 5} films were studied. It has been revealed that Ta{sub 2}O{sub 5} thin films deposited at 300 eV ion beam energy, 60 μA/cm{sup 2} ion current density, 20 sccm oxygen flow rate and 0.6 nm/s deposition rate demonstrated excellent optical, structural and compressive stress.

  7. Application of cluster-plus-glue-atom model to barrierless CuNiTi and CuNiTa films

    SciTech Connect (OSTI)

    Li, Xiaona, E-mail: lixiaona@dlut.edu.cn; Ding, Jianxin; Wang, Miao; Dong, Chuang [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Dalian University of Technology), Ministry of Education, Dalian 116024 (China); Chu, Jinn P. [Department of Materials Science and Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan (China)

    2014-11-01

    To improve the thermal stability of copper and avoid its diffusion into surrounding dielectrics or interfacial reactions with them, the authors applied the cluster-plus-glue-atom model to investigate barrierless CuNiM (M?=?Ti or Ta) seed layers. The dissolution of the third element (Ti or Ta) in the Cu lattice with the aid of Ni significantly improved the thermal stability of the Cu seed layer. The appropriate M/Ni (M?=?Ti or Ta) ratio was selected to obtain a low resistivity: the resistivity was as low as 2.5??? cm for the (Ti{sub 1.5/13.5}Ni{sub 12/13.5}){sub 0.3}Cu{sub 99.7} film and 2.8??? cm for the (Ta{sub 1.1/13.1}Ni{sub 12/13.1}){sub 0.4}Cu{sub 99.6} film after annealing at 500?C for 1?h. After annealing at 500?C for 40?h, the two films remained stable without forming a Cu{sub 3}Si compound. The authors confirmed that the range of applications of the cluster-plus-glue-atom model could be extended. Therefore, a third element M with negative enthalpies of mixing with both Cu and Ni could be selected, under the premise that the mixing enthalpy of MNi is more negative than that of MCu.

  8. Association study of schizophrenia and IL-2 receptor {beta} chain gene

    SciTech Connect (OSTI)

    Nimgaonkar, V.L.; Yang, Z.W.; Zhang, X.R.; Brar, J.S.

    1995-10-09

    A case-control association study was conducted in Caucasian patients with schizophrenia (DSM-III-R, n = 42) and unaffected controls (n = 47) matched for ethnicity and area of residence. Serum interleukin-2 receptor (IL-2R) concentrations, as well as a dinucleotide repeat polymorphism in the IL-2RP chain gene, were examined in both groups. No significant differences in IL-2R concentrations or in the distribution of the polymorphism were noted. This study does not support an association between schizophrenia and the IL-2RP gene locus, contrary to the suggestive evidence from linkage analysis in multicase families. 17 refs., 2 tabs.

  9. ENVIRONMENTAL IlONITORING REPORT FOR THE NEVADA TEST SITE AND...

    Office of Legacy Management (LM)

    IlONITORING REPORT FOR THE NEVADA TEST SITE AND OTHER TEST AREAS USED FOR UNDERGROUND NUCLEAR DETONATIONS January through December 1975 Nonitoring Operations Division Environmental ...

  10. handout.ai

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and error estimation from radiation measurements. SOME SPECIFICS Stephen E. Schwartz ses@bnl.gov http:www.ecd.bnl.govsteve Measurement-based determination of aerosol...

  11. arm_07.ai

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    be bullet rosettes. The vertical flux of water can be computed using the radar measured vertical velocity and the lidar-radar derived water content . The flux of water computed...

  12. ARM Poster 2007.ai

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    20 40 60 80 100120 Number Density (L -1 ) 3 4 5 6 7 8 9 Altitude (km) Further Development of Multi-Instrument Multi-Parameter Cloud Retrievals Richard Austin, Norm Wood, and Graeme...

  13. Visible Light Assisted Photocatalytic Hydrogen Generation by Ta2O5/Bi2O3, TaON/Bi2O3, and Ta3N5/Bi2O3 Composites

    SciTech Connect (OSTI)

    Adhikari, Shiba; Hood, Zachary D.; More, Karren Leslie; Ivanov, Ilia N.; Zhang, Lifeng; Gross, Michael; Lachgar, Abdou

    2015-06-15

    Composites comprised of two semiconducting materials with suitable band gaps and band positions have been reported to be effective at enhancing photocatalytic activity in the visible light region of the electromagnetic spectrum. Here, we report the synthesis, complete structural and physical characterizations, and photocatalytic performance of a series of semiconducting oxide composites. UV light active tantalum oxide (Ta2O5) and visible light active tantalum oxynitride (TaON) and tantalum nitride (Ta3N5) were synthesized, and their composites with Bi2O3 were prepared in situ using benzyl alcohol as solvent. The composite prepared using equimolar amounts of Bi2O3 and Ta2O5 leads to the formation of the ternary oxide, bismuth tantalate (BiTaO4) upon calcination at 1000 °C. The composites and single phase bismuth tantalate formed were characterized by powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), Brunauer–Emmett–Teller (BET) surface area measurement, scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–Vis diffuse reflectance spectroscopy, and photoluminescence. The photocatalytic activities of the catalysts were evaluated for generation of hydrogen using aqueous methanol solution under visible light irradiation (λ ≥ 420 nm). The results show that as-prepared composite photocatalysts extend the light absorption range and restrict photogenerated charge-carrier recombination, resulting in enhanced photocatalytic activity compared to individual phases. The mechanism for the enhanced photocatalytic activity for the heterostructured composites is elucidated based on observed activity, band positions calculations, and photoluminescence data.

  14. Cell type-specific roles of Jak3 in IL-2-induced proliferative signal transduction

    SciTech Connect (OSTI)

    Fujii, Hodaka . E-mail: hodaka@med.nyu.edu

    2007-03-16

    Binding of interleukin-2 (IL-2) to its specific receptor induces activation of two members of Jak family protein tyrosine kinases, Jak1 and Jak3. An IL-2 receptor (IL-2R)-reconstituted NIH 3T3 fibroblast cell line proliferates in response to IL-2 only when hematopoietic lineage-specific Jak3 is ectopically expressed. However, the mechanism of Jak3-dependent proliferation in the fibroblast cell line is not known. Here, I showed that Jak3 expression is dispensable for IL-2-induced activation of Jak1 and Stat proteins and expression of nuclear proto-oncogenes in the IL-2R-reconstituted fibroblast cell line. Jak3 expression markedly enhanced these IL-2-induced signaling events. In contrast, Jak3 expression was essential for induction of cyclin genes involved in the G1-S transition. These data suggest a critical role of Jak3 in IL-2 signaling in the fibroblast cell line and may provide further insight into the cell type-specific mechanism of cytokine signaling.

  15. Irreversible inhibition of RANK expression as a possible mechanism for IL-3 inhibition of RANKL-induced osteoclastogenesis

    SciTech Connect (OSTI)

    Khapli, Shruti M.; Tomar, Geetanjali B.; Barhanpurkar, Amruta P.; Gupta, Navita; Yogesha, S.D.; Pote, Satish T.; Wani, Mohan R.

    2010-09-03

    Research highlights: {yields} IL-3 inhibits receptor activator of NF-{kappa}B ligand (RANKL)-induced osteoclastogenesis. {yields} IL-3 inhibits RANKL-induced JNK activation. {yields} IL-3 down-regulates expression of c-Fos and NFATc1 transcription factors. {yields} IL-3 down-regulates RANK expression posttranscriptionally and irreversibly. {yields} IL-3 inhibits in vivo RANK expression. -- Abstract: IL-3, a cytokine secreted by activated T lymphocytes, stimulates the proliferation, differentiation and survival of pluripotent hematopoietic stem cells. In this study, we investigated the mechanism of inhibitory action of IL-3 on osteoclast differentiation. We show here that IL-3 significantly inhibits receptor activator of NF-{kappa}B (RANK) ligand (RANKL)-induced activation of c-Jun N-terminal kinase (JNK). IL-3 down-regulates expression of c-Fos and nuclear factor of activated T cells (NFATc1) transcription factors. In addition, IL-3 down-regulates RANK expression posttranscriptionally in both purified osteoclast precursors and whole bone marrow cells. Furthermore, the inhibitory effect of IL-3 on RANK expression was irreversible. Interestingly, IL-3 inhibits in vivo RANK expression in mice. Thus, we provide the first evidence that IL-3 irreversibly inhibits RANK expression that results in inhibition of important signaling molecules induced by RANKL.

  16. Strain control magnetocrystalline anisotropy of Ta/FeCo/MgO heterostructures

    SciTech Connect (OSTI)

    Ong, P. V.; Kioussis, Nicholas; Amiri, P. Khalili; Wang, K. L.; Carman, Gregory P.

    2015-05-07

    Using ab initio electronic structure calculations, we have investigated the effect of epitaxial strain on magnetocrystalline anisotropy (MCA) of Ta/FeCo/MgO heterostructure. At small expansive strains on the FeCo layer, the system exhibits perpendicular MCA (PMA). Strain not only has a profound effect on the value of MCA but also induces a switching of magnetic easy axis. Analysis of the energy- and k-resolved distribution of orbital characters of the minority-spin band reveals that a significant contribution to PMA at zero strain arises from the spin-orbit coupling between occupied d{sub x{sup 2}−y{sup 2}} and unoccupied d{sub xy} states, derived from Fe at the FeCo/MgO interface. The strain effect is attributed to strain-induced shifts of spin-orbit coupled d-states. Our work demonstrates that strain engineering can open a viable pathway towards tailoring magnetic properties for spintronic applications.

  17. Progress in Studies of Electron-Cloud-Induced Optics Distortions at CesrTA

    SciTech Connect (OSTI)

    Crittenden, James; Calvey, Joseph; Dugan, Gerald; Kreinick, David; Leong, Zhidong; Livezey, Jesse; Palmer, Mark; Rubin, David; Sagan, David; Furman, Miguel; Penn, Gregory; Venturini, Marco; Harkay, Katherine; Holtzapple, Robert; Pivi, Mauro; Wang, Lanfa; /SLAC

    2012-06-25

    The Cornell Electron Storage Ring Test Accelerator (CesrTA) program has included extensive measurements of coherent betatron tune shifts for a variety of electron and positron beam energies, bunch population levels, and bunch train configurations. The tune shifts have been shown to result primarily from the interaction of the beam with the space-charge field of the beam-induced low-energy electron cloud in the vacuum chamber. Comparison to several advanced electron cloud simulation codes has allowed determination of the sensitivity of these measurements to physical parameters characterizing the synchrotron radiation flux, the production of photo-electrons on the vacuum chamber wall, the beam emittance, lattice optics, and the secondary-electron yield model. We report on progress in understanding the cloud buildup and decay mechanisms in magnetic fields and in field-free regions, addressing quantitatively the precise determination of the physical parameters of the modeling. Validation of these models will serve as essential input in the design of damping rings for future high-energy linear colliders.

  18. Competing decay modes of a high-spin isomer in the proton-unbound nucleus ¹⁵⁸Ta*

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Carroll, R. J.; Page, R. D.; Joss, D. T.; Uusitalo, J.; Darby, I. G.; Andgren, K.; Cederwall, B.; Eeckhaudt, S.; Grahn, T.; Gray-Jones, C.; et al

    2015-01-01

    An isomeric state at high spin and excitation energy was recently observed in the proton-unbound nucleus 158Ta. This state was observed to decay by both α and γ decay modes. The large spin change required to decay via γ-ray emission incurs a lifetime long enough for α decay to compete. The α decay has an energy of 8644(11) keV, which is among the highest observed in the region, a partial half-life of 440(70) μs and changes the spin by 11ℏ. In this study, additional evidence supporting the assignment of this α decay to the high-spin isomer in 158Ta will bemore » presented.« less

  19. Electronic structure reconstruction across the antiferromagnetic transition in TaFe₁̣₂₃Te₃ spin ladder

    SciTech Connect (OSTI)

    Xu, Min; Wang, Li -Min; Peng, Rui; Ge, Qing -Qin; Chen, Fei; Ye, Zi -Rong; Zhang, Yan; Chen, Su -Di; Xia, Miao; Liu, Rong -Hua; Arita, M.; Shimada, K.; Namatame, H.; Taniguchi, M.; Matsunami, M.; Kimura, S.; Shi, Ming; Chen, Xian -Hui; Yin, Wei -Guo; Ku, Wei; Xie, Bin -Ping; Feng, Dong -Lai

    2015-02-01

    With angle-resolved photoemission spectroscopy, we studied the electronic structure of TaFe₁̣₂₃Te₃, a two-leg spin ladder compound with a novel antiferromagnetic ground state. Quasi-two-dimensional Fermi surface is observed, with sizable inter-ladder hopping. Moreover, instead of observing an energy gap at the Fermi surface in the antiferromagnetic state, we observed the shifts of various bands. Combining these observations with density-functional-theory calculations, we propose that the large scale reconstruction of the electronic structure, caused by the interactions between coexisting itinerant electrons and local moments, is most likely the driving force of the magnetic transition. Thus TaFe₁̣₂₃Te₃ serves as a simpler platform that contains similar ingredients as the parent compounds of iron-based superconductors.

  20. All-metallic electrically gated 2H-TaSe{sub 2} thin-film switches and logic circuits

    SciTech Connect (OSTI)

    Renteria, J.; Jiang, C.; Yan, Z.; Samnakay, R.; Goli, P.; Pope, T. R.; Salguero, T. T.; Wickramaratne, D.; Lake, R. K.; Khitun, A. G.; Balandin, A. A.

    2014-01-21

    We report the fabrication and performance of all-metallic three-terminal devices with tantalum diselenide thin-film conducting channels. For this proof-of-concept demonstration, the layers of 2H-TaSe{sub 2} were exfoliated mechanically from single crystals grown by the chemical vapor transport method. Devices with nanometer-scale thicknesses exhibit strongly non-linear current-voltage characteristics, unusual optical response, and electrical gating at room temperature. We have found that the drain-source current in thin-film 2H-TaSe{sub 2}Ti/Au devices reproducibly shows an abrupt transition from a highly resistive to a conductive state, with the threshold tunable via the gate voltage. Such current-voltage characteristics can be used, in principle, for implementing radiation-hard all-metallic logic circuits. These results may open new application space for thin films of van der Waals materials.

  1. Electronic structure reconstruction across the antiferromagnetic transition in TaFe₁̣₂₃Te₃ spin ladder

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, Min; Wang, Li -Min; Peng, Rui; Ge, Qing -Qin; Chen, Fei; Ye, Zi -Rong; Zhang, Yan; Chen, Su -Di; Xia, Miao; Liu, Rong -Hua; et al

    2015-02-01

    With angle-resolved photoemission spectroscopy, we studied the electronic structure of TaFe₁̣₂₃Te₃, a two-leg spin ladder compound with a novel antiferromagnetic ground state. Quasi-two-dimensional Fermi surface is observed, with sizable inter-ladder hopping. Moreover, instead of observing an energy gap at the Fermi surface in the antiferromagnetic state, we observed the shifts of various bands. Combining these observations with density-functional-theory calculations, we propose that the large scale reconstruction of the electronic structure, caused by the interactions between coexisting itinerant electrons and local moments, is most likely the driving force of the magnetic transition. Thus TaFe₁̣₂₃Te₃ serves as a simpler platform that containsmore » similar ingredients as the parent compounds of iron-based superconductors.« less

  2. Improvement of the photoluminescent intensity of ZnTa{sub 2}O{sub 6}:Pr{sup 3+} phosphor

    SciTech Connect (OSTI)

    Noto, L.L. Ntwaeaborwa, O.M.; Yagoub, M.Y.A.; Swart, H.C.

    2014-07-01

    Highlights: The optimal luminescence intensity was obtained for 0.4 mol% Pr{sup 3+} doped ZnTa{sub 2}O{sub 6}. The ZnTa{sub 2}O{sub 6}:Pr{sup 3+} has a colour index matching an ideal red emission. The cross relaxation process led to a decrease in red emission at higher Pr{sup 3+} concentrations. The blue emission continues to increase at higher Pr{sup 3+} concentrations. The persistent luminescent increases with an increase in Pr{sup 3+} concentration. - Abstract: A red emitting ZnTa{sub 2}O{sub 6}:Pr{sup 3+} phosphor with Commission Internationale de lEclairage coordinates that match those of an ideal red emission was prepared by solid state chemical reaction. X-ray diffraction confirmed that a pure orthorhombic phase of ZnTa{sub 2}O{sub 6} was crystallized. A homogeneous distribution of the Pr{sup 3+} ions was confirmed from the analysis of the time of flight secondary ion mass spectroscopy overlay images. In addition to the reflectance at 259 nm associated with band-to-band absorption, minor reflectance peaks associated with f-f transitions of Pr{sup 3+} were observed at 420500 nm. The main red emission peak was split into minor peaks located at 608, 619 and 639 nm that were assigned to {sup 1}D{sub 2} ? {sup 3}H{sub 4}, {sup 3}P{sub 0} ? {sup 3}H{sub 6} and {sup 3}P{sub 0} ? {sup 3}F{sub 2} transitions of Pr{sup 3+}, respectively. With increasing concentration of Pr{sup 3+}, a relatively weak blue emission was observed at 488 nm and this phenomenon maybe attributed to virtual charge transfer or/and inter cross relaxation effects. The decay characteristics of the persistent emission were also calculated.

  3. EP-AREAG-PLAN-1248, R.0 TA-54 Area G Nitrate-Salt Waste Container Response Instructions

    Office of Environmental Management (EM)

    EP-AREAG-PLAN-1248, R.0 TA-54 Area G Nitrate-Salt Waste Container Response Instructions Effective Date: 5/28/2014 The Responsible Manager has determined that the following organizations' review/concurrence is required for the initial document and for major revisions a same type and level review is required. Review documentation is contained in the Document History File: EWMO Engineering LANL TRU Programs - Shipping and Safe Storage Disposition LANL TRU Programs - Drum Disposition Project LANL

  4. Significant enhancement of compositional and superconducting homogeneity in Ti rather than Ta-doped Nb3Sn

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tarantini, C.; Sung, Z. -H.; Lee, P. J.; Ghosh, A. K.; Larbalestier, D. C.

    2016-01-25

    Nb3Sn wires are now very close to their final optimization but despite its classical nature, detailed understanding of the role of Ta and Ti doping in the A15 is not fully understood. Long thought to be essentially equivalent in their influence on Hc2, they were interchangeably applied. Here we show that Ti produces significantly more homogeneous chemical and superconducting properties. Despite Ta-doped samples having a slightly higher Tc onset in zero-field, they always have a wider Tc-distribution. In particular, whereas the Ta-doped A15 has a Tc-distribution extending from 18 down to 5-6 K (the lowest expected Tc for the binarymore » A15 phase), the Ti-doped samples have no A15 phase with Tc below ~12 K. The much narrower Tc distribution in the Ti-doped samples has a positive effect on their in-field Tc-distribution too, leading to an extrapolated μ0Hc2(0) 2 Tesla larger than the Ta-doped one. Ti-doping also appears to be very homogeneous even when the Sn content is reduced in order to inhibit breakdown of the diffusion barriers in very high Jc conductors. As a result, the enhanced homogeneity of the Ti-doped samples appears to result from its assistance of rapid diffusion of Sn into the filaments and by its incorporation into the A15 phase interchangeably with Sn on the Sn sites of the A15 phase.« less

  5. Radionuclide contaminant analysis of small mammals at Area G, TA-54, Los Alamos National Laboratory, 1995

    SciTech Connect (OSTI)

    Bennett, K.; Biggs, J.; Fresquez, P.

    1997-01-01

    At Los Alamos National Laboratory, small mammals were sampled at two waste burial sites (Site 1-recently disturbed and Site 2-partially disturbed) at Area G, Technical Area 54 and a control site on Frijoles Mesa (Site 4) in 1995. Our objectives were (1) to identify radionuclides that are present within surface and subsurface soils at waste burial sites, (2) to compare the amount of radionuclide uptake by small mammals at waste burial sites to a control site, and (3) to identify if the primary mode of contamination to small mammals is by surface contact or ingestion/inhalation. Three composite samples of at least rive animals per sample were collected at each site. Pelts and carcasses of each animal were separated and analyzed independently. Samples were analyzed for {sup 241}Am, {sup 90}Sr , {sup 238}Pu, {sup 239}Pu, total U, {sup 137}Cs, and {sup 3}H. Significantly higher (parametric West at p=0.05) levels of total U, {sup 241}Am, {sup 238}Pu and {sup 239}Pu were detected in pelts than in carcasses of small mammals at TA-54. Concentrations of other measured radionuclides in carcasses were nearly equal to or exceeded the mean concentrations in the pelts. Our results show higher concentrations in pelts compared to carcasses, which is similar to what has been found at waste burial/contaminated sites outside of Los Alamos National Laboratory. Site 1 had a significantly higher (alpha=0.05, P=0.0125) mean tritium concentration in carcasses than Site 2 or Site 4. In addition Site 1 also had a significantly higher (alpha=0.05, p=0.0024) mean tritium concentration in pelts than Site 2 or Site 4. Site 2 had a significantly higher (alpha=0.05, P=0.0499) mean {sup 239}Pu concentration in carcasses than either Site 1 or Site 4.

  6. File:USDA-CE-Production-GIFmaps-IL.pdf | Open Energy Information

    Open Energy Info (EERE)

    IL.pdf Jump to: navigation, search File File history File usage Illinois Ethanol Plant Locations Size of this preview: 463 599 pixels. Other resolution: 464 600 pixels. Full...

  7. DOE - Office of Legacy Management -- Hydroblast Corp - IL 0-03

    Office of Legacy Management (LM)

    FUSRAP Also see Documents Related to HYDROBLAST CORP. IL.0-03-1 - AEC Memorandum; Smith to Malone; Subject: Shipment of Bethlehem Rods, Reference NYC-504; June 22, 1951 ...

  8. Photocatalytic hydrogen production using visible-light-responsive Ta{sub 3}N{sub 5} photocatalyst supported on monodisperse spherical SiO{sub 2} particulates

    SciTech Connect (OSTI)

    Liu, Xiaoming; Zhao, Lan; Domen, Kazunari; Takanabe, Kazuhiro

    2014-01-01

    Graphical abstract: A simple and effective solgel process followed by nitridation in an NH{sub 3} flow has been developed to deposit Ta{sub 3}N{sub 5} semiconductor photocatalyst layers onto monodisperse spherical SiO{sub 2} particles. The obtained Ta{sub 3}N{sub 5}/SiO{sub 2} particles maintain an original spherical morphology of SiO{sub 2} and a sub-micrometer size with a narrow size distribution and without aggregation. The presence of SiO{sub 2} support shows at least no detrimental effects on photocatalytic activity, but tunes the secondary particle size to control dispersibility of the photocatalyst in the solution. - Highlights: Fine nanoparticles of Ta{sub 3}N{sub 5} were immobilized on the surfaces of SiO{sub 2} giving SiO{sub 2}@Ta{sub 3}N{sub 5} coreshell spheres successfully produced H{sub 2} from methanol solution under visible light. The presence of support (SiO{sub 2}) ensures the dispersion of the particulate in solution maintaining high photocatalytic activity of Ta{sub 3}N{sub 5}. The obtained supported photocatalyst gives uniform size distribution and control the degree of dispersibility in the solution, which may control nature of light absorption and reflection of the photoreactor. - Abstract: Fine nanoparticles of Ta{sub 3}N{sub 5} (1020 nm) were synthesized on the surfaces of SiO{sub 2} spheres with a diameter of ?550 nm. A solgel method was used to modify the surface of SiO{sub 2} with Ta{sub 2}O{sub 5} from TaCl{sub 5} dissolved in ethanol in the presence of citric acid and polyethylene glycol. The resulting oxide composites were treated in an NH{sub 3} flow at 1123 K to form coreshell structured Ta{sub 3}N{sub 5}/SiO{sub 2} sub-microspheres. The obtained samples were characterized using powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectra (EDX), transmission electron microscopy (TEM), and photocatalytic activity

  9. IL-33 inhibits RANKL-induced osteoclast formation through the regulation of Blimp-1 and IRF-8 expression

    SciTech Connect (OSTI)

    Kiyomiya, Hiroyasu; Ariyoshi, Wataru; Okinaga, Toshinori; Kaneuji, Takeshi; Mitsugi, Sho; Sakurai, Takuma; Habu, Manabu; Yoshioka, Izumi; Tominaga, Kazuhiro; and others

    2015-05-01

    Interleukin (IL)-33 is a recently discovered proinflammatory cytokine that belongs to the IL-1 family. Several studies have reported that IL-33 inhibits osteoclast differentiation. However, the mechanism of IL-33 regulation of osteoclastogenesis remains unclear. In the present study, we examined the effect of IL-33 on osteoclast formation in vitro. IL-33 suppressed osteoclast formation in both mouse bone marrow cells and monocyte/macrophage cell line RAW264.7 cells induced by receptor activator of NF-κB ligand (RANKL) and/or macrophage stimulating factor (M-CSF). IL-33 also inhibited the expression of RANKL-induced nuclear factor of activated T-cell cytoplasmic 1 (NFATc1), thereby decreasing the expression of osteoclastogenesis-related marker genes, including Cathepsin K, Osteoclast stimulatory transmembrane protein (Oc-stamp) and Tartrate-resistant acid phosphatase (Trap). Blockage of IL-33-ST2 binding suppressed the IL-33-mediated inhibition of NFATc1. RANKL-induced B-lymphocyte-induced maturation protein-1 (Blimp-1) expression was also suppressed by IL-33, which was followed by the stimulation of anti-osteoclastic genes such as interferon regulatory factor-8 (IRF-8). These results suggest that IL-33-ST2 interactions down-regulate both RANKL-induced NFATc1 activation and osteoclast differentiation via the regulation of Blimp-1 and IRF-8 expression. - Highlights: • IL-33 inhibits RANKL-induced osteoclast formation. • IL-33 has inhibitory effect on the RANKL-induced NFATc1 expression. • IL-33-induced NFATc1 suppression depends on the regulation of Blimp-1 and IRF-8.

  10. Novel defect pyrochlores ABi/sub 2/B/sub 5/O/sub 16/ (A = Cs, Rb; B = Ta, Nb)

    SciTech Connect (OSTI)

    Ehlert, M.K., Greedan, J.E.; Subramanian, M.A.

    1988-07-01

    The crystal structures of three oxides with compositions CsBi/sub 2/Nb/sub 5/O/sub 16/, CsBi/sub 2/Ta/sub 5/O/sub 16/, and RbBi/sub 2/Ta/sub 5/O/sub 16/ have been determined from powder neutron diffraction data. A common structure of the defect pyrochlore types has been found. Atomic positions in space group Fd3m are 3.2 O and 3.2 Cs(Rb) in 8b, 6.4 Bi in 16d, 16 Ta(Nb) in 16c, and 48 O in 48f. There is some evidence that the Rb atoms actually occupy 32e sites. On electrostatic grounds it is highly unlikely that the Cs(Rb) and O atoms are randomly distributed in 8b. Evidence for short-range order is apparent in the X-ray powder diffraction data. Cell constants are 10.528(1) A (Cs, Nb), 10.504(1) A (Cs, Ta), and 10.510(2) A (Rb, Ta), respectively, with 48f x parameters 0.3139(2) (Cs, Nb), 0.3152(2) (Cs, Ta), and 0.3153(2) (Rb, Ta). Isotropic temperature factors for the 8b and 16d site atoms ranged from 3 to 6 (A)/sup 2/. These large values suggest anharmonic behavior or high mobility for some of the ions. Evidence for this is found in the presence of significant dielectric loss effects in all of the compounds studied.

  11. Structure of Mesita del Buey at TA-54, Los Alamos National Laboratory, New Mexico

    SciTech Connect (OSTI)

    Reneau, S.L.; Broxton, D.E.; Carney, J.S.; LaDelfe, C.

    1998-04-23

    The geological structure of Mesita del Buey at Technical Area 54 (TA-54) was examined using precise surveying of the contact between units 1v and 2 of the Tshirege Member of the Bandelier Tuff at 3.5 km along the north wall of Pajarito Canyon and 0.6 km along the north wall of a tributary to Canada del Buey. Estimated structure contours on this contact indicate typical strikes of N40E to N70E along this part of Mesita del Buey, although the apparent strike of the tuff is E-W at the western part of the survey. Typical dips are 1.0{degree} to 2.0{degree} to the east or southeast, with an estimated maximum dip of 3.2{degree} near the west end of Material Disposal Area G. Thirty seven faults with vertical displacements of 5 to 65 cm were observed in outcrop along the Pajarito Canyon traverse, and, due to the incomplete exposure of the unit 1v-unit 2 contact, many more faults of this magnitude undoubtedly exist. The faults have a wide range in strike and have either down-to-the-west and down-to-the-east components of offset, although about 65% of the observed displacement is down-to-the-west or northwest. These faults are not clearly associated with major fault zones, indicated by the general absence of larger-scale offsets or inflections along the unit 1v-unit 2 contact in areas where the small-scale faults were observed; they may instead record distributed secondary deformation across the Pajarito Plateau associated with large earthquakes on the main Pajarito fault zone 8--11 km to the west, or perhaps other faults in the region. The survey data also suggest that a 150--250 m wide zone of greater magnitude faulting is present near the west end of the traverse associated with a horst-and-graben structure displaying about 1.5--3.5 m of offset on individual faults, although the total amount of offset across this structure and its orientation are not known.

  12. Ambient Air Radionuclide Concentrations at and near TA-50 from 2003 through the First Quarter of 2004

    SciTech Connect (OSTI)

    K.W. Jacobson; C.F. Eberhart

    2005-09-05

    The Meteorology and Air Quality (MAQ) group at Los Alamos National Laboratory maintains and operates a large network of environmental air samplers called AIRNET. Some of these samplers are located near Material Disposal Area C at TA-50, a low-level radioactive waste burial site in the semiarid environment of the Pajarito Plateau, near Los Alamos. AIRNET sampling media consist of a filter and silica gel. They are exchanged once every 2 weeks. Presented are 5 months of air sampling results for 5 stations operating in the vicinity of Material Disposal Area C.

  13. High-quality permanent draft genome sequence of Bradyrhizobium sp. Ai1a-2; a microsymbiont of Andira inermis discovered in Costa Rica

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tian, Rui; Parker, Matthew; Seshadri, Rekha; Reddy, T. B. K.; Markowitz, Victor; Ivanova, Natalia; Pati, Amrita; Woyke, Tanja; Baeshen, Mohammed; Baeshen, Nabih; et al

    2015-06-14

    Bradyrhizobium sp. Ai1a-2 is is an aerobic, motile, Gram-negative, non-spore-forming rod that was isolated from an effective nitrogen fixing root nodule of Andira inermis collected from Tres Piedras in Costa Rica. In this report we describe, for the first time, the genome sequence information and annotation of this legume microsymbiont. The 9,029,266 bp genome has a GC content of 62.56% with 247 contigs arranged into 246 scaffolds. The assembled genome contains 8,482 protein-coding genes and 102 RNA-only encoding genes. Lastly, this rhizobial genome was sequenced as part of the DOE Joint Genome Institute 2010 Genomic Encyclopedia for Bacteria and Archaea-Rootmore » Nodule Bacteria (GEBA-RNB) project proposal.« less

  14. Floodplain Assessment for the Proposed Engineered Erosion Controls at TA-72 in Lower Sandia Canyon, Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Hathcock, Charles D.

    2012-08-27

    Los Alamos National Laboratory (LANL) is preparing to implement engineering controls in Sandia Canyon at Technical Area (TA) 72. Los Alamos National Security (LANS) biologists conducted a floodplain determination and this project is located within a 100-year floodplain. The proposed project is to rehabilitate the degraded channel in lower Sandia Canyon where it crosses through the outdoor firing range at TA-72 to limit the loss of sediment and dissipate floodwater leaving LANL property (Figure 1). The proposed construction of these engineered controls is part of the New Mexico Environment Department's (NMED) approved LANL Individual Storm Water Permit. The purpose of this project is to install storm water controls at Sandia Watershed Site Monitoring Area 6 (S-SMA-6). Storm water controls will be designed and installed to meet the requirements of NPDES Permit No. NM0030759, commonly referred to as the LANL Individual Storm Water Permit (IP). The storm water control measures address storm water mitigation for the area within the boundary of Area of Concern (AOC) 72-001. This action meets the requirements of the IP for S-SMA-6 for storm water controls by a combination of: preventing exposure of upstream storm water and storm water generated within the channel to the AOC and totally retaining storm water falling outside the channel but within the AOC.

  15. Polytypism, polymorphism, and superconductivity in TaSe2–xTex

    SciTech Connect (OSTI)

    Luo, Huixia; Xie, Weiwei; Tao, Jing; Inoue, Hiroyuki; Gyenis, András; Krizan, Jason W.; Yazdani, Ali; Zhu, Yimei; Cava, Robert Joseph

    2015-03-03

    Polymorphism in materials often leads to significantly different physical properties - the rutile and anatase polymorphs of TiO₂ are a prime example. Polytypism is a special type of polymorphism, occurring in layered materials when the geometry of a repeating structural layer is maintained but the layer stacking sequence of the overall crystal structure can be varied; SiC is an example of a material with many polytypes. Although polymorphs can have radically different physical properties, it is much rarer for polytypism to impact physical properties in a dramatic fashion. Here we study the effects of polytypism and polymorphism on the superconductivity of TaSe₂, one of the archetypal members of the large family of layered dichalcogenides. We show that it is possible to access 2 stable polytypes and 2 stable polymorphs in the TaSe2-xTex solid solution, and find that the 3R polytype shows a superconducting transition temperature that is between 6 and 17 times higher than that of the much more commonly found 2H polytype. Thus, the reason for this dramatic change is not apparent, but we propose that it arises either from a remarkable dependence of Tc on subtle differences in the characteristics of the single layers present, or from a surprising effect of the layer stacking sequence on electronic properties that instead are expected to be dominated by the properties of a single layer in materials of this kind.

  16. Structural and thermal studies of H{sub 2}La{sub 2/3}Ta{sub 2}O{sub 7}, a protonated layered perovskite

    SciTech Connect (OSTI)

    Le Berre, F.; Crosnier-Lopez, M.P.; Fourquet, J.L.

    2006-04-13

    We have synthesised the new protonated layered perovskite H{sub 2}La{sub 2/3}Ta{sub 2}O{sub 7} which is related to the Ruddlesden-Popper family. This compound is obtained by ionic exchange starting from Li{sub 2}La{sub 2/3}Ta{sub 2}O{sub 7} maintained in dilute HNO{sub 3} at 60 deg. C. Thermal X-ray diffraction and DTA/TGA revealed interesting dehydration properties with formation of a layered anhydrous phase leading at higher temperature (1550 deg. C) to La{sub 1/3}TaO{sub 3}. This latter compound exhibits the original lanthanum ordering expected similarly to that of the Li form, while at 900 deg. C a metastable form, presenting a disordered La distribution, is observed.

  17. Signature-Dependent Electromagnetic Transition Rates in the {pi}h{sub 11/2} Rotational Sequence of {sub 73}{sup 167}Ta

    SciTech Connect (OSTI)

    R. Chapman; K.-M. Spohr; M.B. Smith; R.A. Bark; G.J. Campbell; G.B. Hagemann; N. Keeley; D.J. Middleton; H. Ryde; P.O. Tjom

    1999-12-31

    Excited states in {sup 167}Ta, populated in the {sup 141}Pr({sup 30}Si, 4n){sup 167}Ta reaction, have been studied using the NORDBALL Ge detector array. For the {pi}h{sub 11/2}[514]{sub 2}{sup 9}{sup -} decay sequence, strong signature-dependent effects in the transition quadrupole moment ratio, Q{sub 1}(I {yields} I - 1)/Q{sub 2}(I {yields} I - 2), have been observed over the spin range {sub 2}{sup 21}{<=}I{<=}{sub 2}{sup 39} which encompasses a BC neutron alignment. This is interpreted as strong evidence for departure from axial symmetry.

  18. Signature-dependent electromagnetic transition rates in the {pi}h{sub 11/2} rotational sequence of {sub 73}{sup 167}Ta

    SciTech Connect (OSTI)

    Chapman, R.; Spohr, K.-M.; Smith, M. B.; Campbell, G. J.; Middleton, D. J.; Bark, R. A.; Ryde, H.; Hagemann, G. B.; Keeley, N.; Tjoem, P. O.

    1999-11-16

    Excited states in {sup 167}Ta, populated in the {sup 141}Pr({sup 30}Si,4n){sup 167}Ta reaction, have been studied using the NORDBALL Ge detector array. For the {pi}h{sub 11/2}[514]9/2{sup -} decay sequence, strong signature-dependent effects in the transition quadrupole moment ratio, Q{sub 1}(I{yields}I-1)/Q{sub 2}(I{yields}I-2), have been observed over the spin range 21/2{<=}I{<=}39/2 which encompasses a BC neutron alignment. This is interpreted as strong evidence for departure from axial symmetry.

  19. Synthesis, properties and phase transitions of pyrochlore- and fluorite-like Ln{sub 2}RMO{sub 7} (Ln = Sm, Ho; R = Lu, Sc; M = Nb, Ta)

    SciTech Connect (OSTI)

    Shlyakhtina, A.V.; Belov, D.A.; Pigalskiy, K.S.; Shchegolikhin, A.N.; Kolbanev, I.V.; Karyagina, O.K.

    2014-01-01

    Graphical abstract: Temperature dependences of bulk conductivity for Sm{sub 2}ScTaO{sub 7} pyrochlore prepared at (1) 1400 °C, 20 h; and (2) 1200 °C, 40 h. - Highlights: • The phase formation of Ln{sub 2}RMO{sub 7} (Ln = Sm, Ho; R = Lu, Sc; M = Nb, Ta) at 1200–1600 °C. • The bulk conductivity and magnetic susceptibility were measured. • The bulk conductivity of Sm{sub 2}ScTaO{sub 7} has oxygen ion type at T ≥ 750 °C. • The first-order structural phase transition was observed in Sm{sub 2}ScTaO{sub 7} at ∼650–700 °C. • This phase transformation is not typical for defect fluorites. - Abstract: We have studied the new compounds with fluorite-like (Ho{sub 2}RNbO{sub 7} (R = Lu, Sc)) and pyrochlore-like (Sm{sub 2}ScTaO{sub 7}) structure as potential oxide ion conductors. The phase formation process (from 1200 to 1600 °C) and physical properties (electrical, thermo mechanical, and magnetic) for these compounds were investigated. Among the niobate materials the highest bulk conductivity is offered by the fluorite-like Ho{sub 2}ScNbO{sub 7} synthesized at 1600 °C: 3.8 × 10{sup −5} S/cm at 750 °C, whereas in Sm system the highest bulk conductivity, 7.3 × 10{sup −6} S/cm at 750 °C, is offered by the pyrochlore Sm{sub 2}ScTaO{sub 7} synthesized at 1400 °C. In Sm{sub 2}ScTaO{sub 7} pyrochlore we have observed the first-order phase transformation at ∼650–700 °C is related to rearrangement process in the oxygen sublattice of the pyrochlore structure containing B-site cations in different valence state and actually is absent in the defect fluorites. The two holmium niobates show Curie–Weiss paramagnetic behavior, with the prevalence of antiferromagnetic coupling. The magnetic susceptibility of Sm{sub 2}ScTaO{sub 7} is a weak function of temperature, corresponding to Van Vleck paramagnetism.

  20. Secretary Chu Announces Agreement on FutureGen Project in Mattoon, IL |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Agreement on FutureGen Project in Mattoon, IL Secretary Chu Announces Agreement on FutureGen Project in Mattoon, IL June 12, 2009 - 12:00am Addthis Washington, D.C. - U.S. Secretary of Energy Steven Chu today announced an agreement with the FutureGen Alliance that advances the construction of the first commercial scale, fully integrated, carbon capture and sequestration project in the country in Mattoon, Illinois. "This important step forward for FutureGen reflects

  1. Spin Hall switching of the magnetization in Ta/TbFeCo structures with bulk perpendicular anisotropy

    SciTech Connect (OSTI)

    Zhao, Zhengyang; Jamali, Mahdi; Smith, Angeline K.; Wang, Jian-Ping

    2015-03-30

    Spin-orbit torques are studied in Ta/TbFeCo/MgO patterned structures, where the ferrimagnetic material TbFeCo provides a strong bulk perpendicular magnetic anisotropy (bulk-PMA) independent of the interfaces. The current-induced magnetization switching in TbFeCo is investigated in the presence of a perpendicular, longitudinal, or transverse field. An unexpected partial-switching phenomenon is observed in the presence of a transverse field unique to our bulk-PMA material. It is found that the anti-damping torque related with spin Hall effect is very strong, and a spin Hall angle is determined to be 0.12. The field-like torque related with Rashba effect is unobservable, suggesting that the interface play a significant role in Rashba-like torque.

  2. Resistance controllability and variability improvement in a TaO{sub x}-based resistive memory for multilevel storage application

    SciTech Connect (OSTI)

    Prakash, A. E-mail: amit.knp02@gmail.com Song, J.; Hwang, H. E-mail: amit.knp02@gmail.com; Deleruyelle, D.; Bocquet, M.

    2015-06-08

    In order to obtain reliable multilevel cell (MLC) characteristics, resistance controllability between the different resistance levels is required especially in resistive random access memory (RRAM), which is prone to resistance variability mainly due to its intrinsic random nature of defect generation and filament formation. In this study, we have thoroughly investigated the multilevel resistance variability in a TaO{sub x}-based nanoscale (<30 nm) RRAM operated in MLC mode. It is found that the resistance variability not only depends on the conductive filament size but also is a strong function of oxygen vacancy concentration in it. Based on the gained insights through experimental observations and simulation, it is suggested that forming thinner but denser conductive filament may greatly improve the temporal resistance variability even at low operation current despite the inherent stochastic nature of resistance switching process.

  3. Building America Case Study: Ground Source Heat Pump Research, TaC Studios Residence, Atlanta, Georigia (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-09-01

    As part of the NAHB Research Center Industry Partnership, Southface partnered with TaC Studios, an Atlanta based architecture firm specializing in residential and light commercial design, on the construction of a new test home in Atlanta, GA in the mixed-humid climate. This home serves as a residence and home office for the firm's owners, as well as a demonstration of their design approach to potential and current clients. Southface believes the home demonstrates current best practices for the mixed-humid climate, including a building envelope featuring advanced air sealing details and low density spray foam insulation, glazing that exceeds ENERGY STAR requirements, and a high performance heating and cooling system. Construction quality and execution was a high priority for TaC Studios and was ensured by a third party review process. Post construction testing showed that the project met stated goals for envelope performance, an air infiltration rate of 2.15 ACH50. The homeowner's wished to further validate whole house energy savings through the project's involvement with Building America and this long-term monitoring effort. As a Building America test home, this home was evaluated to detail whole house energy use, end use loads, and the efficiency and operation of the ground source heat pump and associated systems. Given that the home includes many non-typical end use loads including a home office, pool, landscape water feature, and other luxury features not accounted for in Building America modeling tools, these end uses were separately monitored to determine their impact on overall energy consumption.

  4. The susceptibility of TaOx-based memristors to high dose rate ionizing radiation and total ionizing dose

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLain, Michael Lee; Sheridan, Timothy J.; Hjalmarson, Harold Paul; Mickel, Patrick R.; Hanson, Donald J.; McDonald, Joseph K.; Hughart, David Russell; Marinella, Matthew J.

    2014-11-11

    This paper investigates the effects of high dose rate ionizing radiation and total ionizing dose (TID) on tantalum oxide (TaOx) memristors. Transient data were obtained during the pulsed exposures for dose rates ranging from approximately 5.0 ×107 rad(Si)/s to 4.7 ×108 rad(Si)/s and for pulse widths ranging from 50 ns to 50 μs. The cumulative dose in these tests did not appear to impact the observed dose rate response. Static dose rate upset tests were also performed at a dose rate of ~3.0 ×108 rad(Si)/s. This is the first dose rate study on any type of memristive memory technology. Inmore » addition to assessing the tolerance of TaOx memristors to high dose rate ionizing radiation, we also evaluated their susceptibility to TID. The data indicate that it is possible for the devices to switch from a high resistance off-state to a low resistance on-state in both dose rate and TID environments. The observed radiation-induced switching is dependent on the irradiation conditions and bias configuration. Furthermore, the dose rate or ionizing dose level at which a device switches resistance states varies from device to device; the enhanced susceptibility observed in some devices is still under investigation. As a result, numerical simulations are used to qualitatively capture the observed transient radiation response and provide insight into the physics of the induced current/voltages.« less

  5. Probing off-Hugoniot states in Ta, Cu, and Al to 1000 GPa compression with magnetically driven liner implosions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lemke, R. W.; Dolan, D. H.; Dalton, D. G.; Brown, J. L.; Tomlinson, K.; Robertson, G. R.; Knudson, M. D.; Harding, E.; Mattsson, A. E.; Carpenter, J. H.; et al

    2016-01-07

    We report on a new technique for obtaining off-Hugoniot pressure vs. density data for solid metals compressed to extreme pressure by a magnetically driven liner implosion on the Z-machine (Z) at Sandia National Laboratories. In our experiments, the liner comprises inner and outer metal tubes. The inner tube is composed of a sample material (e.g., Ta and Cu) whose compressed state is to be inferred. The outer tube is composed of Al and serves as the current carrying cathode. Another aluminum liner at much larger radius serves as the anode. A shaped current pulse quasi-isentropically compresses the sample as itmore » implodes. The iterative method used to infer pressure vs. density requires two velocity measurements. Photonic Doppler velocimetry probes measure the implosion velocity of the free (inner) surface of the sample material and the explosion velocity of the anode free (outer) surface. These two velocities are used in conjunction with magnetohydrodynamic simulation and mathematical optimization to obtain the current driving the liner implosion, and to infer pressure and density in the sample through maximum compression. This new equation of state calibration technique is illustrated using a simulated experiment with a Cu sample. Monte Carlo uncertainty quantification of synthetic data establishes convergence criteria for experiments. Results are presented from experiments with Al/Ta, Al/Cu, and Al liners. Symmetric liner implosion with quasi-isentropic compression to peak pressure ~1000 GPa is achieved in all cases. Lastly, these experiments exhibit unexpectedly softer behavior above 200 GPa, which we conjecture is related to differences in the actual and modeled properties of aluminum.« less

  6. New high pressure rare earth tantalates RE{sub x}Ta{sub 2}O{sub 5+1.5x} (RE=La, Eu, Yb)

    SciTech Connect (OSTI)

    Zibrov, Igor P.; Filonenko, Vladimir P.; Zakharov, Nikolai D.; Nikishina, Elena E.; Lebedeva, Elena N.

    2013-07-15

    Rare earth tantalates La{sub 0.075}Ta{sub 2}O{sub 5.113}, Eu{sub 0.089}Ta{sub 2}O{sub 5.134} and Yb{sub 0.051}Ta{sub 2}O{sub 5.077} have been prepared by solid state reaction at P=7.0 GPa and T=1050–1100 °C and studied by X-ray diffraction, thermal analysis and electron microscopy. Low hydrated amorphous tantalum, lanthanum, europium and ytterbium hydroxides were used as starting materials. Aqueous as well as anhydrous compounds were obtained. Title tantalates are crystallized in the structure type of F–Ta{sub 2}O{sub 5} [Zibrov et al. Russ. J. Inorg. Chem. 48 (2003) 464–471] [5]. The structure was refined by the Rietveld method from X-ray powder diffractometer data: La{sub 0.075}Ta{sub 2}O{sub 5.113}, a=10.5099(2), b=7.2679(1), c=6.9765(1) Å, V=532.90(1) Å{sup 3}, Z=6, space group Ibam; Eu{sub 0.089}Ta{sub 2}O{sub 5.134}, a=10.4182(3), b=7.2685(1), c=6.9832(1) Å, V=528.80(2) Å{sup 3}, Z=6, space group Ibam; Yb{sub 0.051}Ta{sub 2}O{sub 5.077}, a=10.4557(2), b=7.3853(1), c=6.8923(1) Å, V=532.21(1) Å{sup 3}, Z=6, space group Ibam. RE atoms do not replace the tantalum in its positions but the only water in the channels of the structure. Highly charged cations RE{sup +3} compress the unit cell so that its volume becomes less than that of F–Ta{sub 2}O{sub 5}. Significant decrease of the unit cell volume after water removal from the structure is possible due to the puckering of pentagonal bipyramid layers and change of the corrugation angle in the layer. - Graphical abstract: The structure of RE{sub x}Ta{sub 2}O{sub 5+1.5x} and its HRTEM image (“A” arrows show empty channel, “B” arrows show filled channel). - Highlights: • We synthesized new tantalates of RE under high pressure high temperature conditions. • RE atoms replace water molecules in the channels of the structure. • Aqueous as well as anhydrous tantalates were obtained. • Highly charged cations RE{sup +3} compress the unit cell decreasing RE–O distances.

  7. IL.26

    Office of Legacy Management (LM)

    ... by the AEC Health and Safety Laboratory; (4) establishment of a program for area clearance after each cycle; (5) supply of the uranium billets allocated for a work cycle ...

  8. DOE Zero Energy Ready Home Case Study: StreetScape Development, LLC, Libertyville, IL, Custom

    Broader source: Energy.gov [DOE]

    Case study of a DOE Zero Energy Ready Home in Libertyville, IL, that scored HERS 45 without PV. This 2,763-square-foot custom home has advanced framed walls with R-20 of open-cell spray foam, R-49 open-cell spray-foam sealed attic, an HRV, and a tankless water heater for hydro coil furnace with high-velocity, small-diameter ducts.

  9. Tailoring the magnetic properties of new Fe-Ni-Co-Al-(Ta,Nb)-B superelastic rapidly quenched microwires

    SciTech Connect (OSTI)

    Borza, F. Lupu, N.; Dobrea, V.; Chiriac, H.

    2015-05-07

    Ferromagnetic Fe-Ni-Co-Al-(Ta,Nb)-B microwires with diameters from 170 μm to 50 μm, which possess both superelastic and good magnetic properties, have been prepared by rapid quenching from the melt using the in rotating water spinning technique followed by cold-drawing and ageing. The cold-drawing and annealing processes lead to the initialization of premartensitic phases as confirmed by the X-ray diffraction and scanning transmission electron microscopic investigations, more significantly in the 50 μm cold-drawn microwires. An increase in the coercive field and in the saturation magnetization has been obtained by annealing, more importantly in the case of Nb-containing alloy. Ageing by thermal or current annealing led to the initialization of the superelastic effect. High values of strain of up to 1.8%, very good repeatability under successive loading, and values of superelastic effect of up to 1.2% have been achieved. The structural analysis coupled with the stress-strain data suggests that these materials annealed at 800 °C have superelastic potential at reduced ageing times. The magnetic behavior was found to be easily tailored through both thermal and thermomagnetic treatments with changes in the magnetic parameters which can be contactless detected. The results are important for future applications where both mechanical and magnetic properties matter, i.e., sensing/actuating systems.

  10. Observation of magnon-mediated current drag in Pt/yttrium iron garnet/Pt(Ta) trilayers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Junxue; Xu, Yadong; Aldosary, Mohammed; Tang, Chi; Lin, Zhisheng; Zhang, Shufeng; Lake, Roger; Shi, Jing

    2016-03-02

    Pure spin current, a flow of spin angular momentum without flow of any accompanying net charge, is generated in two common ways. One makes use of the spin Hall effect in normal metals (NM) with strong spin–orbit coupling, such as Pt or Ta. The other utilizes the collective motion of magnetic moments or spin waves with the quasi-particle excitations called magnons. A popular material for the latter is yttrium iron garnet, a magnetic insulator (MI). Here we demonstrate in NM/MI/NM trilayers that these two types of spin currents are interconvertible across the interfaces, predicated as the magnon-mediated current drag phenomenon.more » The transmitted signal scales linearly with the driving current without a threshold and follows the power-law Tn with n ranging from 1.5 to 2.5. Lastly, our results indicate that the NM/MI/NM trilayer structure can serve as a scalable pure spin current valve device which is an essential ingredient in spintronics.« less

  11. Zhurovich_Poster_07.ai

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a) b) particle flux Particle flux (cont'd) * 10 poloidal harmonics; 3 plasma species (electrons, deuterium, boron); ny30, nx135 * Temperature gradients for all species are...

  12. safety newsletter may.AI

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contact: Gyuhae Park gpark@lanl.gov Francesco Lanza di Scalea flanza@ucsd.edu Actuator Sensor Sensor Sensor Multi-Scale Sensing Multi-Scale Sensing Multi-Scale Sensing Active...

  13. safety newsletter may.AI

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aspects of active sensing techniques including a new sensing network paradigm, wireless telemetry, and power harvesting are being investigated for Stuctural Health...

  14. Kay_3034971730_poster.ai

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Kay Kelly About Us Kay Kelly - Clean Cities Project Leader, National Renewable Energy Laboratory Most Recent Reducing Vehicle Idling Time at School Helps Kids-and Parents-Breathe Easier August 1

    radiation anomalies to the 2007 Arctic sea ice minimum 4. Historical Context for 2007 Loss 5. Implications and Future Work In a warmer world with thinner ice, natural cloud and circulation variability will play an increasingly important role in controlling sea ice extent (Kay et al., GRL). We are

  15. crd title p1.ai

    Broader source: Energy.gov (indexed) [DOE]

    491 SPECIAL REPORT MANAGEMENT CHALLENGES AT THE DEPARTMENT OF ENERGY U.S. DEPARTMENT OF ENERGY OFFICE OF INSPECTOR GENERAL OFFICE OF AUDIT SERVICES November 28, 2000 MEMORANDUM FOR THE SECRETARY FROM: Gregory H. Friedman (Signed) Inspector General SUBJECT: INFORMATION: Special Report on "Management Challenges at the Department of Energy" BACKGROUND On October 12, 2000, the Chairmen of several committees of the U.S. Congress requested an assessment by the Office of Inspector General of

  16. Multiband Te p Based Superconductivity of Ta4Pd3Te16

    SciTech Connect (OSTI)

    Singh, David J.

    2014-10-06

    We recently discovered that Ta4Pd3Te16 is a superconductor that has been suggested to be an unconventional superconductor near magnetism. Here, we report electronic structure calculations showing that despite the layered crystal structure the material is an anisotropic three-dimensional (3D) metal. The Fermi surface contains prominent one-dimensional (1D) and two-dimensional (2D) features, including nested 1D sheets, a 2D cylindrical section, and a 3D sheet. Moreover, the electronic states that make up the Fermi surface are mostly derived from Te p states with small Ta d and Pd d contributions. This places the compound far from magnetic instabilities. The results are discussed in terms of multiband superconductivity.

  17. Draft Genome Sequence of thermoalkaliphilic Caldalkalibacillus thermarum strain TA2.A1 Reveals Molecular Adaptations to Extreme pH and Temperature

    SciTech Connect (OSTI)

    Kalamorz, Falk; Keis, Stefanie; Stanton, Jo-Ann; Brown, Steven D; Klingeman, Dawn Marie; Land, Miriam L; Han, Cliff; Martin, S L.; Morgan, Hugh; Cook, Greg

    2011-01-01

    The genes and molecular machines that allow for a thermoalkaliphilic lifestyle have not been defined. To address this goal, we report on the improved high-quality draft genome sequence of Caldalkalibacillus thermarum strain TA2.A1, an obligately aerobic bacterium that grows optimally at pH 9.5 and 65 to 70 C on a wide variety of carbon and energy sources.

  18. Demonstration Assessment of Light-Emitting Diode (LED) Accent Lighting at the Field Museum in Chicago, IL

    SciTech Connect (OSTI)

    Myer, Michael; Kinzey, Bruce R.

    2010-12-10

    This report reviews a demonstration of light-emitting diode (LED) accent lighting compared to halogen (typical) accent lighting in a gallery of the Field Museum in Chicago, IL.

  19. The Effect of Ramp Rate on the C49 to C54 Titanium Disilicide Phase Transformation from Ti and Ti(Ta)

    SciTech Connect (OSTI)

    BAILEY, GLENN A.; HU, YAO ZHI; SMITH, PAUL M.; TAY, SING PIN

    1999-09-22

    The C49 to C54 TiSi{sub 2} transformation temperature is shown to be reduced by increasing the ramp rate during rapid thermal processing and this effect is more pronounced for thinner initial Ti and Ti(Ta) films. Experiments were performed on blanket wafers and on wafers that had patterned polycrystalline Si lines with Si{sub 3}N{sub 4} sidewall spacers. Changing the ramp rate caused no change in the transformation temperature for 60 nm blanket Ti films. For blanket Ti films of 25 or 40 nm, however, increasing the ramp rate from 7 to 180 C/s decreased the transformation temperature by 15 C. Studies of patterned lines indicate that sheet resistance of narrow lines is reduced by increased ramp rates for both Ti and Ti(Ta) films, especially as the linewidths decrease below 0.4 {micro}m. This improvement is particularly pronounced for the thinnest Ti(Ta) films, which exhibited almost no linewidth effect after being annealed with a ramp rate of 75 C/s.

  20. Structural features and enhanced high-temperature oxygen ion transport in SrFe{sub 1-x}Ta{sub x}O{sub 3-{delta}}

    SciTech Connect (OSTI)

    Markov, Alexey A.; Shalaeva, Elizaveta V.; Tyutyunnik, Alexander P.; Kuchin, Vasily V.; Patrakeev, Mikhail V.; Leonidov, Ilya A.; Kozhevnikov, Victor L.

    2013-01-15

    Structural features, oxygen non-stoichiometry and transport properties are studied in the oxide series SrFe{sub 1-x}Ta{sub x}O{sub 3-{delta}}, where x=0.2, 0.3 and 0.4. X-ray diffraction and electron microscopy data evidence formation of the inhomogeneous materials at x=0.3 and 0.4, which include phase constituents with a cubic perovskite and a double perovskite structure types. The composition, the amount and the typical grain size of the phase inhomogeneities are shown to depend both on doping and oxygen content. The increased oxygen-ion conductivity is observed in oxygen depleted materials, which is explained by the increase in the amount of cubic perovskite-like phase and development of interfacial pathways favorable for enhanced oxygen ion transport. - Graphical abstract: The structural studies, oxygen content and conductivity measurements suggest that oxygen depletion from the double perovskite phase constituent of SrFe{sub 1-x}Ta{sub x}O{sub 3-{delta}} for x>0.2 is accompanied by formation of pathways for fast ion transport. Black-Small-Square Highlights: Black-Right-Pointing-Pointer The double perovskite type regions are shown to exist in SrFe{sub 1-x}Ta{sub x}O{sub 3-{delta}}. Black-Right-Pointing-Pointer The oxygen depletion is accompanied with phase separation. Black-Right-Pointing-Pointer The phase separation favors formation of pathways for enhanced oxygen ion transport.

  1. Thermodynamic and mechanical stabilities of α- and β-Ta{sub 4}AlC{sub 3} via first-principles investigations

    SciTech Connect (OSTI)

    Thawabi, Hassan S. Duong, Thien Arróyave, Raymundo

    2013-12-07

    Recently, it has been predicted that Ta{sub 4}AlC{sub 3} is likely to exhibit an (α–β) polymorphic transformation at temperatures above 1873 K. However, recent X-ray diffraction and transmission electron microscopy experiments suggest on the other hand that the α phase remains stable up to temperatures close to the limit of experimental capabilities and no transition has yet been observed. While the matter has already been settled experimentally, in this work, we re-investigate the phase stability problem in Ta{sub 4}AlC{sub 3} by using first-principles methods. The study was carried out by considering both thermodynamic and mechanical stabilities of the Ta{sub 4}AlC{sub 3} polymorphs. Particularly, finite-temperature Gibbs free energies and elastic properties of the polymorphs were calculated using density functional theory. Calculation results reveal that the α phase continue to be stable even at temperatures exceeding 1875 K, which is in agreement with experimental results reported in literature.

  2. Delivery of human NKG2D-IL-15 fusion gene by chitosan nanoparticles to enhance antitumor immunity

    SciTech Connect (OSTI)

    Yan, Chen; Jie, Leng; Yongqi, Wang; Weiming, Xiao; Juqun, Xi; Yanbing, Ding; Li, Qian; Xingyuan, Pan; Mingchun, Ji; Weijuan, Gong

    2015-07-31

    Nanoparticles are becoming promising carriers for gene delivery because of their high capacity in gene loading and low cell cytotoxicity. In this study, a chitosan-based nanoparticle encapsulated within a recombinant pcDNA3.1-dsNKG2D-IL-15 plasmid was generated. The fused dsNKG2D-IL-15 gene fragment consisted of double extracellular domains of NKG2D with IL-15 gene at downstream. The average diameter of the gene nanoparticles ranged from 200 nm to 400 nm, with mean zeta potential value of 53.8 ± 6.56 mV. The nanoparticles which were loaded with the dsNKG2D-IL-15 gene were uptaken by tumor cells with low cytotoxicity. Tumor cells pre-transfected by gene nanopartilces stimulated NK and T cells in vitro. Intramuscular injection of gene nanoparticles suppressed tumor growth and prolonged survival of tumor-bearing mice through activation of NK and CD8{sup +} T cells. Thus, chitosan-based nanoparticle delivery of dsNKG2D-IL-15 gene vaccine can be potentially used for tumor therapy. - Highlights: • Generation of a nanoparticle for delivery of dsNKG2D-IL-15 gene. • Characterization of the gene nanoparticle. • Antitumor activity mediated by the gene nanoparticle.

  3. Synthesis, crystal structure, spectroscopic and thermal properties of [Et{sub 4}N][Ta{sub 6}Br{sub 12}(H{sub 2}O){sub 6}]Br{sub 4}.4H{sub 2}O (Et=ethyl)-A new compound with the paramagnetic [Ta{sub 6}Br{sub 12}]{sup 3+} cluster core

    SciTech Connect (OSTI)

    Peric, Berislav; Jozic, Drazan; Planinic, Pavica; Brnicevic, Nevenka; Giester, Gerald

    2009-09-15

    A new hexanuclear cluster compound, [Et{sub 4}N][Ta{sub 6}Br{sub 12}(H{sub 2}O){sub 6}]Br{sub 4}.4H{sub 2}O (Et=ethyl) (1), with the paramagnetic [Ta{sub 6}Br{sub 12}]{sup 3+} cluster entity, was synthesized and characterized by elemental and TG/DTA analyses, IR and UV/Vis spectroscopy and by a single-crystal X-ray diffraction study. The presence of the paramagnetic [Ta{sub 6}Br{sub 12}]{sup 3+} unit was confirmed also by the room-temperature magnetic and EPR measurements. The compound crystallizes in the tetragonal I4{sub 1}/a space group, with a=14.299(5), c=21.241(5) A, Z=4, R{sub 1}(F)/wR{sub 2}(F{sup 2})=0.0296/0.0811. The structure contains discrete [Ta{sub 6}Br{sub 12}(H{sub 2}O){sub 6}]{sup 3+} cations with an octahedron of metal atoms edge-bridged by bromine atoms and with water molecules occupying all six terminal positions. The cluster units are positioned in the vertices of the three-dimensional (pseudo)diamond lattice. The structure shows similarities with literature reported structures of cluster compounds crystallizing in the diamond (Fd3-barm) space group. - Graphical abstract: Two interpenetrating (pseudo)diamond nets formed by packing of the paramagnetic [Ta{sub 6}Br{sub 12}(H{sub 2}O)]{sup 3+} (octahedral) and diamagnetic [Et{sub 4}N]{sup +} (spheres) cations.

  4. DFPARThIl!NT OF ENERGY EERE PROJECT MANAGEMENT CENTER NEPA DETERlIfiNATION

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    s DFPARThIl!NT OF ENERGY EERE PROJECT MANAGEMENT CENTER NEPA DETERlIfiNATION Page 1 of3 RECIPIENT :State of Hawaii DBEOT STATE : HI PROJECf TITLE: Loan Loss Reserve Funding Opportunity Announc~ment Number DE-FOA-0000052 Procurement Inslrument Number DE-EEOOOO216 NEPA Control Number em Number GF0-0000216-001 GO Based on my review ofthe informalion concerning the proposed aClion, as NEPA Compliance Officer (authorized under DOE Order 451.1A), I have made the following determination: ex, EA, EIS

  5. Photocatalytic splitting of water under visible-light irradiation over the NiOx-loaded Sm{sub 2}InTaO{sub 7} with 4f-d{sup 10}-d{sup 0} configuration

    SciTech Connect (OSTI)

    Tang Xinde; Ye Hongqi; Liu Hui; Ma Chenxia; Zhao Zhi

    2010-01-15

    A new visible-light-response photocatalyst Sm{sub 2}InTaO{sub 7} with 4f-d{sup 10}-d{sup 0} configuration crystallized in a cubic system with the space group Fd3m was synthesized by a solid-state reaction method. NiOx-loaded Sm{sub 2}InTaO{sub 7} showed high photocatalytic activities for H{sub 2} evolution from pure water under visible light irradiation (lambda>400 nm). Changes in the photocatalytic activity with the calcination temperature of Sm{sub 2}InTaO{sub 7} and the amount of NiOx loaded indicated that the combination of highly crystallized Sm{sub 2}InTaO{sub 7} and a high dispersion of NiOx particles led to high photocatalytic activity. The high photocatalytic performance of NiOx-loaded Sm{sub 2}InTaO{sub 7} supported the existing view that the photocatalytic activity correlated with the lattice distortion. Density functional theory calculation indicated that strong dispersion from the hybridized In 5s 5p orbitals at the bottom of the conduction band was responsible for the high activity of photocatalyst Sm{sub 2}InTaO{sub 7}. - Graphical abstract: A new visible-light-response photocatalyst Sm{sub 2}InTaO{sub 7} with 4f-d{sup 10}-d{sup 0} configuration was developed. DFT calculation indicated that strong dispersion from the hybridized In 5s 5p orbitals was responsible for the high photocatalytic activity.

  6. NbF{sub 5} and TaF{sub 5}: Assignment of {sup 19}F NMR resonances and chemical bond analysis from GIPAW calculations

    SciTech Connect (OSTI)

    Biswal, Mamata; Body, Monique; Legein, Christophe; Sadoc, Aymeric; Boucher, Florent

    2013-11-15

    The {sup 19}F isotropic chemical shifts (?{sub iso}) of two isomorphic compounds, NbF{sub 5} and TaF{sub 5}, which involve six nonequivalent fluorine sites, have been experimentally determined from the reconstruction of 1D {sup 19}F MAS NMR spectra. In parallel, the corresponding {sup 19}F chemical shielding tensors have been calculated using the GIPAW method for both experimental and DFT-optimized structures. Furthermore, the [M{sub 4}F{sub 20}] units of NbF{sub 5} and TaF{sub 5} being held together by van der Waals interactions, the relevance of Grimme corrections to the DFT optimization processes has been evaluated. However, the semi-empirical dispersion correction term introduced by such a method does not show any significant improvement. Nonetheless, a complete and convincing assignment of the {sup 19}F NMR lines of NbF{sub 5} and TaF{sub 5} is obtained, ensured by the linearity between experimental {sup 19}F ?{sub iso} values and calculated {sup 19}F isotropic chemical shielding ?{sub iso} values. The effects of the geometry optimizations have been carefully analyzed, confirming among other matters, the inaccuracy of the experimental structure of NbF{sub 5}. The relationships between the fluorine chemical shifts, the nature of the fluorine atoms (bridging or terminal), the position of the terminal ones (opposite or perpendicular to the bridging ones), the fluorine charges, the ionicity and the length of the MF bonds have been established. Additionally, for three of the {sup 19}F NMR lines of NbF{sub 5}, distorted multiplets, arising from {sup 1}J-coupling and residual dipolar coupling between the {sup 19}F and {sup 93}Nb nuclei, were simulated yielding to values of {sup 93}Nb{sup 19}F {sup 1}J-coupling for the corresponding fluorine sites. - Graphical abstract: The complete assignment of the {sup 19}F NMR lines of NbF{sub 5} and TaF{sub 5} allow establishing relationships between the {sup 19}F ?{sub iso} values, the nature of the fluorine atoms (bridging or

  7. Keratinocyte-derived IL-24 plays a role in the positive feedback regulation of epidermal inflammation in response to environmental and endogenous toxic stressors

    SciTech Connect (OSTI)

    Jin, Sun Hee; Choi, Dalwoong; Chun, Young-Jin; Noh, Minsoo

    2014-10-15

    Keratinocytes are the major cellular components of human epidermis and play a key role in the modulating cutaneous inflammation and toxic responses. In human chronic skin diseases, the common skin inflammatory phenotypes like skin barrier disruption and epidermal hyperplasia are manifested in epidermal keratinocytes by interactions with T helper (Th) cells. To find a common gene expression signature of human keratinocytes in chronic skin diseases, we performed a whole genome microarray analysis on normal human epidermal keratinocytes (NHKs) treated with IFNγ, IL-4, IL-17A or IL-22, major cytokines from Th1, Th2, Th17 or Th22 cells, respectively. The microarray results showed that the four genes, IL-24, PDZK1IP1, H19 and filaggrin, had common expression profiles in NHKs exposed to Th cell cytokines. In addition, the acute phase pro-inflammatory cytokines, IL-1β, IL-6 and TNFα, also change the gene transcriptional profile of IL-24, PDZK1IP1, H19, and filaggrin in NHKs as those of Th cytokines. Therefore, the signature gene set, consisting of IL-24, PDZK1IP1, H19, and filaggrin, provides essential insights for understanding the process of cutaneous inflammation and toxic responses. We demonstrate that environmental toxic stressors, such as chemical irritants and ultraviolet irradiation stimulate the production of IL-24 in NHKs. IL-24 stimulates the JAK1-STAT3 and MAPK pathways in NHKs, and promotes the secretion of pro-inflammatory mediators IL-8, PGE2, and MMP-1. These results suggest that keratinocyte-derived IL-24 participates in the positive feedback regulation of epidermal inflammation in response to both endogenous and environmental toxic stressors. - Highlights: • Cutaneous inflammatory gene signature consists of PDZK1IP1, IL-24, H19 and filaggrin. • Pro-inflammatory cytokines increase IL-24 production in human keratinocytes. • Environmental toxic stressors increase IL-24 production in human keratinocytes. • IL-24 stimulates human keratinocytes to

  8. Comparative study of structure formation and mechanical behavior of age-hardened Ti–Nb–Zr and Ti–Nb–Ta shape memory alloys

    SciTech Connect (OSTI)

    Inaekyan, K.; Brailovski, V.; Prokoshkin, S.; Pushin, V.; Dubinskiy, S.; Sheremetyev, V.

    2015-05-15

    This work sets out to study the peculiar effects of aging treatment on the structure and mechanical behavior of cold-rolled and annealed biomedical Ti–21.8Nb–6.0Zr (TNZ) and Ti–19.7Nb–5.8Ta (TNT) (at.%) shape memory alloys by means of transmission electron microscopy, X-ray diffractometry, functional fatigue and thermomechanical testing techniques. Dissimilar effects of aging treatment on the mechanical behavior of Zr- and Ta-doped alloys are explained by the differences in the ω-phase formation rate, precipitate size, fraction and distribution, and by their effect on the alloys' critical stresses and transformation temperatures. Even short-time aging of the TNZ alloy leads to its drastic embrittlement caused by “overaging”. On the contrary, during aging of the TNT alloy, formation of finely dispersed ω-phase precipitates is gradual and controllable, which makes it possible to finely adjust the TNT alloy functional properties using precipitation hardening mechanisms. To create in this alloy nanosubgrained dislocation substructure containing highly-dispersed coherent nanosized ω-phase precipitates, the following optimum thermomechanical treatment is recommended: cold rolling (true strain 0.37), followed by post-deformation annealing (600 °C, 15–30 min) and age-hardening (300 °C, 30 min) thermal treatments. It is shown that in TNT alloy, pre-transition diffraction effects (diffuse reflections) can “mask” the β-phase substructure and morphology of secondary phases. - Highlights: • TNZ alloy is characterized by much higher ω-phase precipitation rate than TNT alloy. • Difference in precipitation rates is linked to the difference in Zr and Ta diffusion mobility. • Aging of nanosubgrained TNZ alloy worsens its properties irrespective of the aging time. • Aging time of nanosubgrained TNT alloy can be optimized to improve its properties.

  9. Magnetic anisotropy in Ta/CoFeB/MgO investigated by x-ray magnetic circular dichroism and first-principles calculation

    SciTech Connect (OSTI)

    Kanai, Shun; Tsujikawa, Masahito; Shirai, Masafumi; Miura, Yoshio; Matsukura, Fumihiro Ohno, Hideo

    2014-12-01

    We study the spin and orbital magnetic moments in Ta/Co{sub 0.4}Fe{sub 0.4}B{sub 0.2}/MgO by x-ray magnetic circular dichroism measurements as well as first-principles calculations, in order to clarify the origin of the perpendicular magnetic anisotropy. Both experimental and theoretical results show that orbital magnetic moment of Fe is more anisotropic than that of Co with respect to the magnetization direction. The anisotropy is larger for thinner CoFeB, indicating that Fe atoms at the interface with MgO contribute more than Co to the observed perpendicular magnetic anisotropy.

  10. Collapse of ferromagnetism in itinerant-electron system: A magnetic, transport properties, and high pressure study of (Hf,Ta)Fe{sub 2} compounds

    SciTech Connect (OSTI)

    Diop, L. V. B. Isnard, O.; Kastil, J.; Arnold, Z.; Kamarad, J.

    2014-10-28

    The magnetism and transport properties were studied for Laves (Hf,Ta)Fe{sub 2} itinerant-electron compounds, which exhibit a temperature-induced first-order transition from the ferromagnetic (FM) to the antiferromagnetic (AFM) state upon heating. At finite temperatures, the field-induced metamagnetic phase transition between the AFM and FM has considerable effects on the transport properties of these model metamagnetic compounds. A large negative magnetoresistance of about 14% is observed in accordance with the metamagnetic transition. The magnetic phase diagram is determined for the Laves Hf{sub 1?x}Ta{sub x}Fe{sub 2} series and its Ta concentration dependence discussed. An unusual behavior is revealed in the paramagnetic state of intermediate compositions, it gives rise to the rapid increase and saturation of the local spin fluctuations of the 3d electrons. This new result is analysed in the frame of the theory of Moriya. For a chosen composition Hf{sub 0.825}Ta{sub 0.175}Fe{sub 2}, exhibiting such remarkable features, a detailed investigation is carried out under hydrostatic pressure up to 1?GPa in order to investigate the volume effect on the magnetic properties. With increasing pressure, the magnetic transition temperature T{sub FM-AFM} from ferromagnetic to antiferromagnetic order decreases strongly non-linearly and disappears at a critical pressure of 0.75?GPa. In the pressure-induced AFM state, the field-induced first-order AFM-FM transition appears and the complex temperature dependence of the AFM-FM transition field is explained by the contribution from both the magnetic and elastic energies caused by the significant temperature variation of the amplitude of the local Fe magnetic moment. The application of an external pressure leads also to the progressive decrease of the Nel temperature T{sub N}. In addition, a large pressure effect on the spontaneous magnetization M{sub S} for pressures below 0.45?GPa, dln(M{sub s})/dP?=??6.3??10{sup ?2?}GPa{sup ?1

  11. Preparation of W-Ta thin-film thermocouple on diamond anvil cell for in-situ temperature measurement under high pressure

    SciTech Connect (OSTI)

    Yang Jie; Li Ming; Zhang Honglin; Gao Chunxiao

    2011-04-15

    In this paper, a W-Ta thin-film thermocouple has been integrated on a diamond anvil cell by thin-film deposition and photolithography methods. The thermocouple was calibrated and its thermal electromotive force was studied under high pressure. The results indicate that the thermal electromotive force of the thermocouple exhibits a linear relationship with temperature and is not associated with pressure. The resistivity measurement of ZnS powders under high pressure at different temperatures shows that the phase transition pressure decreases as the temperature increases.

  12. g-C{sub 3}N{sub 4}/NaTaO{sub 3} organicinorganic hybrid nanocomposite: High-performance and recyclable visible light driven photocatalyst

    SciTech Connect (OSTI)

    Kumar, Santosh; Kumar, Bharat; Surendar, T.; Shanker, Vishnu

    2014-01-01

    Graphical abstract: High-performance and recyclable visible-light driven g-C{sub 3}N{sub 4}/NaTaO{sub 3} hybrid nanocomposite photocatalysts have been prepared by a facile ultrasonic dispersion method. The hybrid nanocomposite photocatalyst can be promising photocatalytic material for practical application in water splitting and environmental remediation. - Highlights: Novel g-C{sub 3}N{sub 4}/NaTaO{sub 3} nanocomposites as a high performance and recyclable photocatalysts. These catalysts exhibited significantly enhanced photocatalytic activity under UVvisible light irradiation. More attractively, dramatic activity is generated under visible light irradiation due to the g-C{sub 3}N{sub 4} loaded. Interestingly, the as-prepared hybrid nanocomposites possess high reusability. - Abstract: Novel g-C{sub 3}N{sub 4}/NaTaO{sub 3} hybrid nanocomposites have been prepared by a facile ultrasonic dispersion method. Our results clearly show the formation of interface between NaTaO{sub 3} and g-C{sub 3}N{sub 4} and further loading of g-C{sub 3}N{sub 4} did not affect the crystal structure and morphology of NaTaO{sub 3}. The g-C{sub 3}N{sub 4}/NaTaO{sub 3} nanocomposites exhibited enhanced photocatalytic performance for the degradation of Rhodamine B under UVvisible and visible light irradiation compared to pure NaTaO{sub 3} and Degussa P25. Interestingly, the visible light photocatalytic activity is generated due to the loading of g-C{sub 3}N{sub 4}. A mechanism is proposed to discuss the enhanced photocatalytic activity based on trapping experiments of photoinduced radicals and holes. Under visible light irradiation, electron excited from the valance band (VB) to conduction band (CB) of g-C{sub 3}N{sub 4} could directly inject into the CB of NaTaO{sub 3}, making g-C{sub 3}N{sub 4}/NaTaO{sub 3} visible light driven photocatalyst. Since the as-prepared hybrid nanocomposites possess high reusability therefore it can be promising photocatalyst for environmental

  13. Human dose assessment for the radionuclides {sup 90}Sr and {sup 90}Y at TA-35 SWMU 35-003 (r) and Ten Site Canyon

    SciTech Connect (OSTI)

    Jarmer, D.; Lyman, J.

    1997-07-01

    This report gives an estimate of the radiological dose to an individual living on or working at a site contaminated with strontium-90 ({sup 90}Sr) and yttrium-90 ({sup 90}Y). The site consists of a small receiving canyon that drains into Ten-Site Canyon at the eastern end of Los Alamos National Laboratory`s technical area 35 (TA-35). Between 1951 and 1963 a wastewater treatment facility located at TA-35 discharged water containing {sup 90}Sr and {sup 90}Y to this receiving canyon. The authors used the RESRAD computer code to calculate the dose to an on-site individual, based on two exposure scenarios: (1) a person working at the site for eight hours a day, five days a week, for twenty-five years and (2) a farmer living at the site twenty four hours a day, seven days a week, for thirty years. The exposure pathways considered were direct exposure to external radiation; inhalation of contaminated dusts; and ingestion of plants, water, and soil. The authors found that the maximum estimated dose rates were 1 and 21 mrem y{sup {minus}1} for the worker and farmer scenarios respectively. The authors have concluded that the value for the worker scenario is well below the DOE dose limit of 100 mrem y{sup {minus}1} but the farmer is overexposed.

  14. HUMAN MACHINE INTERFACE (HMI) EVALUATION OF ROOMS TA-50-1-60/60A AT THE RADIOACTIVE LIQUID WASTE TREATMENT FACILITY (RLWTF)

    SciTech Connect (OSTI)

    Gilmore, Walter E.; Stender, Kerith K.

    2012-08-29

    This effort addressed an evaluation of human machine interfaces (HMIs) in Room TA-50-1-60/60A of the Radioactive Liquid Waste Treatment Facility (RLWTF). The evaluation was performed in accordance with guidance outlined in DOE-STD-3009, DOE Standard Preparation Guide for U.S. Department of Energy Nonreactor Nuclear Facility Documented Safety Analyses, 2006 [DOE 2006]. Specifically, Chapter 13 of DOE 2006 highlights the 10 CFR 830, Nuclear Safety Management, 2012, [CFR 2012] and DOE G 421.1-2 [DOE 2001a] requirements as they relate to the human factors process and, in this case, the safety of the RLWTF. The RLWTF is a Hazard Category 3 facility and, consequently, does not have safety-class (SSCs). However, safety-significant SSCs are identified. The transuranic (TRU) wastewater tanks and associated piping are the only safety-significant SSCs in Rooms TA-50-1-60/60A [LANL 2010]. Hence, the human factors evaluation described herein is only applicable to this particular assemblage of tanks and piping.

  15. An aqueous route to [Ta6O19]8- and solid-state studies of isostructural niobium and tantalum oxide complexes.

    SciTech Connect (OSTI)

    Nyman, May D.; Anderson, Travis Mark; Alam, Todd M.; Rodriguez, Mark Andrew; Joel N. Bixler; Francois Bonhomme

    2007-10-01

    Tantalate materials play a vital role in our high technology society: tantalum capacitors are found in virtually every cell phone. Furthermore, electronic characteristics and the incredibly inert nature of tantalates renders them ideal for applications such as biomedical implants, nuclear waste forms, ferroelectrics, piezoelectrics, photocatalysts and optical coatings. The inert and insoluble nature of tantalates is not fundamentally understood; and furthermore poor solubility renders fabrication of novel or optimized tantalates very difficult. We have developed a soft chemical route to water-soluble tantalum oxide clusters that can serve as both precursors for novel tantalate materials and ideal models for experimental and computational approaches to understanding the unusually inert behavior of tantalates. The water soluble cluster, [Ta6O19]8- is small, highly symmetric, and contains the representative oxygen types of a metal oxide surface, and thus ideally mimics a complex tantalate surface in a simplistic form that can be studied unambiguously. Furthermore; in aqueous solution, these highly charged and super-basic clusters orchestrate surprising acid-base behavior that most likely plays an important role in the inertness of related oxide surfaces. Our unique synthetic approach to the [Ta6O19]8- cluster allowed for unprecedented enrichment with isotopic labels (17O), enabling detailed kinetic and mechanistic studies of the behavior of cluster oxygens, as well as their acid-base behavior. This SAND report is a collection of two publications that resulted from these efforts.

  16. A density-functional study on the stability of anatase-type phases in the system Mg-Ta-O-N

    SciTech Connect (OSTI)

    Wolff, Holger; Lerch, Martin; Schilling, Heikko; Baehtz, Carsten; Dronskowski, Richard

    2008-10-15

    Magnesium-doped tantalum oxynitrides, which were prepared by ammonolysis of amorphous mixed oxides, have been investigated using quantum-theoretical methods. For small magnesium amounts (5 cat%), density-functional total-energy calculations indicate an anatase-type structure consisting of stretched, corner-sharing TaO{sub 3}N{sub 3} octahedra with a tetrahedrally distorted equatorial plane. The calculated structural parameters are in excellent agreement with those obtained using X-ray powder diffraction and synchrotron radiation. Additionally, the quantum-chemical results show a clear preference for an ordered anionic distribution (space group I4{sub 1}md, no. 109) of the host lattice, which is locally disturbed around Mg{sup 2+}. For thermodynamical reasons, the excess oxygen anions, which replace nitrogen on account of the lower charge of the dopant cation, segregate next to magnesium, thus forming local MgO 'domains'. For higher magnesium contents ({>=}10%), minor phases of rutile-type structure have to be expected, which is in good agreement with experimental data. - Density-functional total energy of Mg-doped TaON in several polymorphs, each in its most stable arrangement, as a function of the dopant amount.

  17. Phase transition in the Ruddlesden-Popper layered perovskite Li{sub 2}SrTa{sub 2}O{sub 7}

    SciTech Connect (OSTI)

    Pagnier, T.; Rosman, N.; Galven, C.; Suard, E.; Fourquet, J.L.; Le Berre, F.; Crosnier-Lopez, M.P.

    2009-02-15

    The crystal structure of the Ruddlesden-Popper layered perovskite Li{sub 2}SrTa{sub 2}O{sub 7} has been characterized at various temperatures between -185 and 300 deg. C by several techniques: X-ray and neutron powder diffraction, single crystal diffraction, transmission electron microscopy and Raman spectroscopy. The low temperature structure has been confirmed to be orthorhombic Cmcm with a small octahedra antiphase tilting ({phi}{phi}0) ({phi}{phi}0) inside the perovskite blocks. With temperature, the tilting progressively vanishes leading around 230 deg. C to a tetragonal symmetry (S.G. I4/mmm). This reversible phase transition, followed by X-ray and neutron thermodiffraction and thermal Raman measurements, is considered as of second order. An attribution of the Raman bands based on normal mode analysis is proposed. - Graphical abstract: Thermal evolution of Li{sub 2}SrTa{sub 2}O{sub 7} X-ray powder diffraction patterns showing the structural transformation from orthorhombic to tetragonal cell.

  18. In situ X-ray diffraction strain-controlled study of TiNbZr and TiNbTa shape memory alloys: crystal lattice and transformation features

    SciTech Connect (OSTI)

    Dubinskiy, S.; Prokoshkin, S.; Brailovski, V.; Inaekyan, K.; Korotitskiy, A.

    2014-02-15

    Phase and structure transformations in biomedical Ti21.8Nb6.0Zr (TNZ) and Ti19.7Nb5.8Ta (TNT) shape memory alloys (at.%) under and without load in the ? 150 to 100 S temperature range are studied in situ using an original tensile module for a low-temperature chamber of an X-ray diffractometer. Alpha?- and beta-phase lattice parameters, the crystallographic resource of recovery strain, phase and structure transformation sequences, and microstress appearance and disappearance are examined, compared and discussed. For both alloys, the crystallographic resource of recovery strain decreases with temperature increase to become 4.5% for TNZ and 2.5% for TNT alloy (at RT). Loading at low temperatures leads to additional ??-phase formation and reorientation. Heating under load, as compared to strain-free heating, affects the reverse transformation sequence of both alloys in different ways. For TNZ alloy, strain-free heating results in simultaneous ??? and ???? transformations, whereas during heating under stress, they are sequential: ? + ???? precedes ????. For TNT alloy, strain-free heating results in reverse ???? transformation, whereas during heating under stress, ???? transformation is preceded by ??-phase reorientation. - Highlights: Comparative in situ XRD analysis of TiNbZr(Ta) shape memory alloys is realized. Lattice parameters of ?- and ??-phases are calculated in the ? 150 to + 100 C range. The higher the temperature, the lower the ???? transformation strain. Loading at low temperatures results in ??-phase formation and reorientation. Transformation sequences upon heating with and without loading are different.

  19. Joint contributions of Ag ions and oxygen vacancies to conducting filament evolution of Ag/TaO{sub x}/Pt memory device

    SciTech Connect (OSTI)

    Chung, Yu-Lung; Cheng, Wen-Hui; Chen, Wei-Chih; Jhan, Sheng-An; Chen, Jen-Sue; Jeng, Jiann-Shing

    2014-10-28

    The electroforming and resistive switching behaviors in the Ag/TaO{sub x}/Pt trilayer structure are investigated under a continual change of temperatures between 300?K and 100?K to distinguish the contributions of Ag ions and oxygen vacancies in developing of conducting filaments. For either electroforming or resistive switching, a significantly higher forming/set voltages is needed as the device is operated at 100?K, as compared to that observed when operating at 300?K. The disparity in forming/set voltages of Ag/TaO{sub x}/Pt operating at 300?K and 100?K is attributed to the contribution of oxygen vacancies, in addition to Ag atoms, in formation of conducting filament at 100?K since the mobilities of oxygen vacancies and Ag ions become comparable at low temperature. The presence of oxygen vacancy segment in the conducting filament also modifies the reset current from a gradually descending behavior (at 300?K) to a sharp drop (at 100?K). Furthermore, the characteristic set voltage and reset current are irreversible as the operation temperature is brought from 100?K back to 300?K, indicating the critical role of filament constituents on the switching behaviors of Ag/oxide/Pt system.

  20. Effect of the valence electron concentration on the bulk modulus and chemical bonding in Ta{sub 2}AC and Zr{sub 2}AC (A=Al, Si, and P)

    SciTech Connect (OSTI)

    Schneider, Jochen M.; Music, Denis; Sun Zhimei

    2005-03-15

    We have studied the effect of the valence electron concentration, on the bulk modulus and the chemical bonding in Ta{sub 2}AC and Zr{sub 2}AC (A=Al, Si, and P) by means of ab initio calculations. Our equilibrium volume and the hexagonal ratio (c/a) agree well (within 2.7% and 1.2%, respectively) with previously published experimental data for Ta{sub 2}AlC. The bulk moduli of both Ta{sub 2}AC and Zr{sub 2}AC increase as Al is substituted with Si and P by 13.1% and 20.1%, respectively. This can be understood since the substitution is associated with an increased valence electron concentration, resulting in band filling and an extensive increase in cohesion.

  1. IL1{beta}-mediated Stromal COX-2 signaling mediates proliferation and invasiveness of colonic epithelial cancer cells

    SciTech Connect (OSTI)

    Zhu, Yingting; Tissue Tech Inc, Miami, FL 33173 ; Zhu, Min; Lance, Peter

    2012-11-15

    COX-2 is a major inflammatory mediator implicated in colorectal inflammation and cancer. However, the exact origin and role of COX-2 on colorectal inflammation and carcinogenesis are still not well defined. Recently, we reported that COX-2 and iNOS signalings interact in colonic CCD18Co fibroblasts. In this article, we investigated whether activation of COX-2 signaling by IL1{beta} in primary colonic fibroblasts obtained from normal and cancer patients play a critical role in regulation of proliferation and invasiveness of human colonic epithelial cancer cells. Our results demonstrated that COX-2 level was significantly higher in cancer associated fibroblasts than that in normal fibroblasts with or without stimulation of IL-1{beta}, a powerful stimulator of COX-2. Using in vitro assays for estimating proliferative and invasive potential, we discovered that the proliferation and invasiveness of the epithelial cancer cells were much greater when the cells were co-cultured with cancer associated fibroblasts than with normal fibroblasts, with or without stimulation of IL1{beta}. Further analysis indicated that the major COX-2 product, prostaglandin E{sub 2}, directly enhanced proliferation and invasiveness of the epithelial cancer cells in the absence of fibroblasts. Moreover, a selective COX-2 inhibitor, NS-398, blocked the proliferative and invasive effect of both normal and cancer associate fibroblasts on the epithelial cancer cells, with or without stimulation of IL-1{beta}. Those results indicate that activation of COX-2 signaling in the fibroblasts plays a major role in promoting proliferation and invasiveness of the epithelial cancer cells. In this process, PKC is involved in the activation of COX-2 signaling induced by IL-1{beta} in the fibroblasts.

  2. Expression of low-, intermediate-, and high-affinity IL-2 receptors on B cell lines derived from patients with undifferentiated lymphoma of Burkitt's and non-Burkitt's types

    SciTech Connect (OSTI)

    Benjamin, D.; Rosolen, A.; Wormsley, S.B.; DeBault, L.E.; Colamonici, O.R. )

    1990-08-01

    IL-2 receptors on T cells exist in at least three forms which differ in their ligand-binding affinity. The low-affinity IL-2 receptor (IL-2R) consists of the 55-kDa Tac protein (p55 alpha), the intermediate-affinity site corresponds to the 70-kDa molecule (p70 beta), and the high-affinity IL-2R consists of a noncovalent heterodimeric structure involving both p55 alpha and p70 beta. We studied 24 B cell lines (8 EBV-negative and 16 EBV-positive) for IL-2R expression in the presence or absence of the tumor promoter, teleocidin. 125I-IL-2 radioreceptor binding assays and crosslinking studies demonstrated the sole expression of p55 alpha in EBV-negative cell lines only, whereas p55 alpha present in EBV-positive cell lines was always associated with p70 beta to construct high-affinity IL-2R. p70 beta was not detected in any of the EBV-negative cell lines, but was expressed on most of the EBV-positive cell lines (13 of 16). Our data also indicate that the expression of p55 alpha and p70 beta by radiolabeling correlates with their expression in flow cytometry, and that a large excess of p55 alpha is required to construct high-affinity IL-2R. Coexpression of p55 alpha and p70 beta on human B cells contributed to constructing high-affinity IL-2R hybrid complex as shown by rapid association rate contributed by p55 alpha and slow dissociation rate by p70 beta; teleocidin's ability to induce p55 alpha on cell lines which express p70 beta only, resulting in appearance of high-affinity IL-2R; and blocking p55 alpha by anti-Tac mAb in cell lines which constitutively express high-affinity IL-2R eliminated both high- and low-affinity components. The existence of low, intermediate, and high IL-2R on human B cells bears important future implications for understanding the mechanism of IL-2 signaling and the role of IL-2 in B cell activation, proliferation, and differentiation.

  3. Eu3+ as a dual probe for the determination of IL anion donor power: A combined luminescence spectroscopic and electrochemical approach

    SciTech Connect (OSTI)

    Babai, Arash; Kopiec, Gabriel; Lackmann, Anastasia; Mallick, Bert; Pitula, Slawomir; Tang, Sifu; Mudring, Anja-Verena

    2014-04-01

    This work is aimed at giving proof that Eu(Tf2N)(3) (Tf2N = bis(trifluoromethanesulfonyl)amide) can act as both an optical and electrochemical probe for the determination of the Lewis acidity of an ionic liquid anion. For that reason the luminescence spectra and cyclic voltammograms of dilute solutions of Eu(Tf2N)(3) in various ionic liquids were investigated. The Eu2+/3+ redox potential in the investigated ILs can be related to the Lewis basicity of the IL anion. The IL cation had little influence. The lower the determined halfwave potential, the higher the IL anion basicity. The obtained ranking can be confirmed by luminescence spectroscopy where a bathochromic shift of the D-5(0) -> F-7(4) transition indicates a stronger Lewis basicity of the IL anion. (C) 2014 Published by Elsevier B.V.

  4. Development of a simultaneous Hugoniot and temperature measurement for preheated-metal shock experiments: Melting temperatures of Ta at pressures of 100 GPa

    SciTech Connect (OSTI)

    Li Jun; Zhou Xianming; Li Jiabo; Wu Qiang; Cai Lingcang; Dai Chengda

    2012-05-15

    Equations of state of metals are important issues in earth science and planetary science. A major limitation of them is the lack of experimental data for determining pressure-volume and temperature of shocked metal simultaneously. By measuring them in a single experiment, a major source of systematic error is eliminated in determining from which shock pressure release pressure originates. Hence, a non-contact fast optical method was developed and demonstrated to simultaneously measure a Hugoniot pressure-volume (P{sub H}-V{sub H}) point and interfacial temperature T{sub R} on the release of Hugoniot pressure (P{sub R}) for preheated metals up to 1000 K. Experimental details in our investigation are (i) a Ni-Cr resistance coil field placed around the metal specimen to generate a controllable and stable heating source, (ii) a fiber-optic probe with an optical lens coupling system and optical pyrometer with ns time resolution to carry out non-contact fast optical measurements for determining P{sub H}-V{sub H} and T{sub R}. The shock response of preheated tantalum (Ta) at 773 K was investigated in our work. Measured data for shock velocity versus particle velocity at an initial state of room temperature was in agreement with previous shock compression results, while the measured shock data between 248 and 307 GPa initially heated to 773 K were below the Hugoniot evaluation from its off-Hugoniot states. Obtained interfacial temperatures on release of Hugoniot pressures (100-170 GPa) were in agreement with shock-melting points at initial ambient condition and ab initio calculations of melting curve. It indicates a good consistency for shock melting data of Ta at different initial temperatures. Our combined diagnostics for Hugoniot and temperature provides an important approach for studying EOS and the temperature effect of shocked metals. In particular, our measured melting temperatures of Ta address the current controversy about the difference by more than a factor of 2

  5. Structure of the unique SEFIR domain from human interleukin 17 receptor A reveals a composite ligand-binding site containing a conserved α-helix for Act1 binding and IL-17 signaling

    SciTech Connect (OSTI)

    Zhang, Bing; Liu, Caini; Qian, Wen; Han, Yue; Li, Xiaoxia; Deng, Junpeng

    2014-05-01

    Crystal structure of the SEFIR domain from human IL-17 receptor A provides new insights into IL-17 signaling. Interleukin 17 (IL-17) cytokines play a crucial role in mediating inflammatory and autoimmune diseases. A unique intracellular signaling domain termed SEFIR is found within all IL-17 receptors (IL-17Rs) as well as the key adaptor protein Act1. SEFIR-mediated protein–protein interaction is a crucial step in IL-17 cytokine signaling. Here, the 2.3 Å resolution crystal structure of the SEFIR domain of IL-17RA, the most commonly shared receptor for IL-17 cytokine signaling, is reported. The structure includes the complete SEFIR domain and an additional α-helical C-terminal extension, which pack tightly together to form a compact unit. Structural comparison between the SEFIR domains of IL-17RA and IL-17RB reveals substantial differences in protein topology and folding. The uniquely long insertion between strand βC and helix αC in IL-17RA SEFIR is mostly well ordered, displaying a helix (αCC′{sub ins}) and a flexible loop (CC′). The DD′ loop in the IL-17RA SEFIR structure is much shorter; it rotates nearly 90° with respect to the counterpart in the IL-17RB SEFIR structure and shifts about 12 Å to accommodate the αCC′{sub ins} helix without forming any knots. Helix αC was identified as critical for its interaction with Act1 and IL-17-stimulated gene expression. The data suggest that the heterotypic SEFIR–SEFIR association via helix αC is a conserved and signature mechanism specific for IL-17 signaling. The structure also suggests that the downstream motif of IL-17RA SEFIR together with helix αC could provide a composite ligand-binding surface for recruiting Act1 during IL-17 signaling.

  6. Multiple copies of orbital angular momentum states through second-harmonic generation in a two-dimensional periodically poled LiTaO{sub 3} crystal

    SciTech Connect (OSTI)

    Fang, Xinyuan; Wei, Dunzhao; Liu, Dongmei; Zhong, Weihao; Ni, Rui; Chen, Zhenhua; Hu, Xiaopeng; Zhang, Yong Zhu, S. N.; Xiao, Min

    2015-10-19

    We experimentally demonstrate multiple copies of optical orbital angular momentum (OAM) states through quasi-phase-matched (QPM) second-harmonic (SH) generation in a 2D periodically poled LiTaO{sub 3} (PPLT) crystal. Since the QPM condition is satisfied by involving different reciprocal vectors in the 2D PPLT crystal, collinear and noncollinear SH beams carrying OAMs of l{sub 2} are simultaneously generated by the input fundamental beam with an OAM of l{sub 1}. The OAM conservation law (i.e., l{sub 2} = 2l{sub 1}) holds well in the experiment, which can tolerate certain phase-mismatch between the interacting waves. Our results provide an efficient way to obtain multiple copies of the wavelength-converted OAM states, which can be used to enhance the capacity in optical communications.

  7. Integrated quasi-phase-matched second-harmonic generator and electrooptic scanner on LiTaO{sub 3} single crystals

    SciTech Connect (OSTI)

    Gopalan, V.; Kawas, M.J.; Schlesinger, T.E.; Stancil, D.D.; Gupta, M.C.

    1996-12-01

    The authors report the first integrated quasi-phase-matched second-harmonic generator and electrooptic scanner on ferroelectric Z-cut LiTaO{sub 3}. The quasi-phase-matched second-harmonic generation device frequency doubles the infrared light at 829.7 nm into blue at 414.85 nm with a bulk conversion efficiency of 0.52%/W-cm. The blue light generated in the bulk then passes through an electrooptic scanner, consisting of a series of lithographically defined triangular-shaped domain-inverted regions extending through the thickness of the crystal. A deflection of 12 mrad/kv for the output blue light and 7.4 mrad/kv for the infrared light was observed at the scanner output.

  8. Lattice-level observation of the elastic-to-plastic relaxation process with subnanosecond resolution in shock-compressed Ta using time-resolved in situ Laue diffraction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wehrenberg, C. E.; Comley, A. J.; Barton, N. R.; Coppari, F.; Fratanduono, D.; Huntington, C. M.; Maddox, B. R.; Park, H. -S.; Plechaty, C.; Prisbrey, S. T.; et al

    2015-09-29

    We report direct lattice level measurements of plastic relaxation kinetics through time-resolved, in-situ Laue diffraction of shock-compressed single-crystal [001] Ta at pressures of 27-210 GPa. For a 50 GPa shock, a range of shear strains is observed extending up to the uniaxial limit for early data points (<0.6 ns) and the average shear strain relaxes to a near steady state over ~1 ns. For 80 and 125 GPa shocks, the measured shear strains are fully relaxed already at 200 ps, consistent with rapid relaxation associated with the predicted threshold for homogeneous nucleation of dislocations occurring at shock pressure ~65 GPa.more » The relaxation rate and shear stresses are used to estimate the dislocation density and these quantities are compared to the Livermore Multiscale Strength model as well as various molecular dynamics simulations.« less

  9. Single high-dose irradiation aggravates eosinophil-mediated fibrosis through IL-33 secreted from impaired vessels in the skin compared to fractionated irradiation

    SciTech Connect (OSTI)

    Lee, Eun-Jung; Kim, Jun Won; Yoo, Hyun; Kwak, Woori; Choi, Won Hoon; Cho, Seoae; Choi, Yu Jeong; Lee, Yoon-Jin; Cho, Jaeho

    2015-08-14

    We have revealed in a porcine skin injury model that eosinophil recruitment was dose-dependently enhanced by a single high-dose irradiation. In this study, we investigated the underlying mechanism of eosinophil-associated skin fibrosis and the effect of high-dose-per-fraction radiation. The dorsal skin of a mini-pig was divided into two sections containing 4-cm{sup 2} fields that were irradiated with 30 Gy in a single fraction or 5 fractions and biopsied regularly over 14 weeks. Eosinophil-related Th2 cytokines such as interleukin (IL)-4, IL-5, and C–C motif chemokine-11 (CCL11/eotaxin) were evaluated by quantitative real-time PCR. RNA-sequencing using 30 Gy-irradiated mouse skin and functional assays in a co-culture system of THP-1 and irradiated-human umbilical vein endothelial cells (HUVECs) were performed to investigate the mechanism of eosinophil-mediated radiation fibrosis. Single high-dose-per-fraction irradiation caused pronounced eosinophil accumulation, increased profibrotic factors collagen and transforming growth factor-β, enhanced production of eosinophil-related cytokines including IL-4, IL-5, CCL11, IL-13, and IL-33, and reduced vessels compared with 5-fraction irradiation. IL-33 notably increased in pig and mouse skin vessels after single high-dose irradiation of 30 Gy, as well as in irradiated HUVECs following 12 Gy. Blocking IL-33 suppressed the migration ability of THP-1 cells and cytokine secretion in a co-culture system of THP-1 cells and irradiated HUVECs. Hence, high-dose-per-fraction irradiation appears to enhance eosinophil-mediated fibrotic responses, and IL-33 may be a key molecule operating in eosinophil-mediated fibrosis in high-dose-per fraction irradiated skin. - Highlights: • Single high-dose irradiation aggravates eosinophil-mediated fibrosis through IL-33. • Vascular endothelial cells damaged by high-dose radiation secrete IL-33. • Blocking IL-33 suppressed migration of inflammatory cells and cytokine secretion. • IL

  10. HIA 2015 DOE Zero Energy Ready Home Case Study: Evolutionary Home Builders, The Adaptation Home, Geneva, IL

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Evolutionary Home Builders The Adaptation Home Geneva, IL DOE ZERO ENERGY READY HOME(tm) The U.S. Department of Energy invites home builders across the country to meet the extraordinary levels of excellence and quality specified in DOE's Zero Energy Ready Home program (formerly known as Challenge Home). Every DOE Zero Energy Ready Home starts with ENERGY STAR Certified Homes Version 3.0 for an energy-efficient home built on a solid foundation of building science research. Advanced technologies