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Sample records for routing phone routing

  1. Laboratory Shuttle Bus Routes: Combined Routes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combined Routes & Schedules Blue Route Orange Route Rockridge Route Potter St.JBEI Route Combined Routes and Schedules (On-SiteOff-Site) Scroll down or click here for schedule...

  2. Class network routing

    DOE Patents [OSTI]

    Bhanot, Gyan; Blumrich, Matthias A.; Chen, Dong; Coteus, Paul W.; Gara, Alan G.; Giampapa, Mark E.; Heidelberger, Philip; Steinmacher-Burow, Burkhard D.; Takken, Todd E.; Vranas, Pavlos M.

    2009-09-08

    Class network routing is implemented in a network such as a computer network comprising a plurality of parallel compute processors at nodes thereof. Class network routing allows a compute processor to broadcast a message to a range (one or more) of other compute processors in the computer network, such as processors in a column or a row. Normally this type of operation requires a separate message to be sent to each processor. With class network routing pursuant to the invention, a single message is sufficient, which generally reduces the total number of messages in the network as well as the latency to do a broadcast. Class network routing is also applied to dense matrix inversion algorithms on distributed memory parallel supercomputers with hardware class function (multicast) capability. This is achieved by exploiting the fact that the communication patterns of dense matrix inversion can be served by hardware class functions, which results in faster execution times.

  3. Railroad Routing Model

    Energy Science and Technology Software Center (OSTI)

    1995-01-05

    INTERLINE/PC is an interactive program designed to simulate the routing practices of the United States rail system. The rail industry is divided into a large number of independent competing companies. The INTERLINE data base represents these rail companies as 94 separate subnetworks. An additional two subnetworks represent navigable inland/intracoastal and deep draft marine routes. Interchange points between individual rail systems and waterway systems are also identified.

  4. Collective network routing

    DOE Patents [OSTI]

    Hoenicke, Dirk

    2014-12-02

    Disclosed are a unified method and apparatus to classify, route, and process injected data packets into a network so as to belong to a plurality of logical networks, each implementing a specific flow of data on top of a common physical network. The method allows to locally identify collectives of packets for local processing, such as the computation of the sum, difference, maximum, minimum, or other logical operations among the identified packet collective. Packets are injected together with a class-attribute and an opcode attribute. Network routers, employing the described method, use the packet attributes to look-up the class-specific route information from a local route table, which contains the local incoming and outgoing directions as part of the specifically implemented global data flow of the particular virtual network.

  5. VHDL Control Routing Simulator

    Energy Science and Technology Software Center (OSTI)

    1995-07-10

    The control router simulates a backplane consisting of up to 16 slot. Slot 0, reserved for a control module (cr-ctrl), generates the system clocks and provides the serial interface to the Gating Logic. The remaining 15 slots (1-15) contain routing modules (cr mod), each having up to 64 serial inputs and outputs with FIFOs. Messages to be transmitted to the Control Router are taken from text files. There are currently 17 such source files. Inmore » the model, the serial output of each source is connected to multiple receivers, so that there are 8 identical messages transmitted to the router for each message file entry.« less

  6. RAIL ROUTING PRACTICES AND PROPOSED ALTERNATIVES

    Office of Environmental Management (EM)

    on "Strawman" Report: RAIL ROUTING PRACTICES AND PROPOSED ALTERNATIVES Number Section Comment Response RTG-1-AAR SECTION II Safeguards Routing Regulations, Para. 2 The NRC has identified five types of route characteristics that receive special consideration when NRC staff review routes for approval pursuant to 10 CFR 73: (1) routes through highly populated areas; (2) routes that would place the shipment or escort vehicle in a significantly disadvantageous position (for example, tunnels

  7. TEC Working Group Topic Groups Routing

    Broader source: Energy.gov [DOE]

    The Routing Topic Group has been established to examine topics of interest and relevance concerning routing of shipments of spent nuclear fuel (SNF) and high-level radioactive waste (HLW) to a...

  8. Zone routing in a torus network

    DOE Patents [OSTI]

    Chen, Dong; Heidelberger, Philip; Kumar, Sameer

    2013-01-29

    A system for routing data in a network comprising a network logic device at a sending node for determining a path between the sending node and a receiving node, wherein the network logic device sets one or more selection bits and one or more hint bits within the data packet, a control register for storing one or more masks, wherein the network logic device uses the one or more selection bits to select a mask from the control register and the network logic device applies the selected mask to the hint bits to restrict routing of the data packet to one or more routing directions for the data packet within the network and selects one of the restricted routing directions from the one or more routing directions and sends the data packet along a link in the selected routing direction toward the receiving node.

  9. Westgate Alternate Routes | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Westgate Alternate Routes Avoid the white-knuckled commute and antacids for breakfast! If you take I-55 north to Lemont Road to enter through Westgate in the morning, you may want to consider taking an alternate route in order to avoid potential traffic safety risks. Three alternate routes are mapped out, and turn-by-turn directions are listed below. Alternate Route 1 If you're coming from the north: Head south on I-355, and take either the 75th Street exit heading east or the 87th Street

  10. Which route to coal liquefaction

    SciTech Connect (OSTI)

    Nene, R.G.

    1981-11-01

    Two main methods for producing liquid fuels from coal are currently undergoing intensive evaluation. One, direct liquefaction (e.g., SRC-II, Exxon Donor Solvent (EDS), and H-Coal) produces liquid fuels directly from coal; the other, indirect liquefaction (e.g., Lurgi gasifier followed by Fischer-Tropsch, and Shell-Koppers gasifier followed by methanol synthesis and Mobil's MTG process) first gasifies coal and then converts the gaseous material into liquid products. This paper compares both routes basing its assessment on yields, thermal efficiencies, elemental balances, investment, complexity, and state of development. It is shown that direct liquefaction is more efficient and produces more product per investment dollar. Higher efficiency for direct liquefaction is verified bY stoichiometric and thermodynamic analysis. All approaches require about the same capital investment per unit of feed. Indirect liquefaction can be either more or less complex than direct liquefaction, depending upon the process. Direct liquefaction is least developed. 8 refs.

  11. New route toward integrating large nickel nanocrystals onto mesoporous...

    Office of Scientific and Technical Information (OSTI)

    New route toward integrating large nickel nanocrystals onto mesoporous carbons This content will become publicly available on December 30, 2016 Title: New route toward integrating ...

  12. A Versatile Synthetic Route for the Preparation of Titanium Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Versatile Synthetic Route for the Preparation of Titanium Metal-Organic Frameworks ... A Versatile Synthetic Route for the Preparation of Titanium Metal-Organic Frameworks. ...

  13. A Solution Route to Thermoelectric Oxide Nanoparticles - A Sol...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Solution Route to Thermoelectric Oxide Nanoparticles - A Sol-Gel Process Employing Heterometallic Alkoxides A Solution Route to Thermoelectric Oxide Nanoparticles - A Sol-Gel ...

  14. TEC Working Group Topic Groups Archives Route Identification Process |

    Office of Environmental Management (EM)

    Department of Energy Route Identification Process TEC Working Group Topic Groups Archives Route Identification Process Route Identification Process Items Available for Download Routing Discussion Paper (April 1998) (71.87 KB) More Documents & Publications TEC Meeting Summaries - January 1997 TEC Meeting Summaries - July 1997 TEC Meeting Summaries - January 1998

  15. An Indirect Route for Ethanol Production

    SciTech Connect (OSTI)

    Eggeman, T.; Verser, D.; Weber, E.

    2005-04-29

    The ZeaChem indirect method is a radically new approach to producing fuel ethanol from renewable resources. Sugar and syngas processing platforms are combined in a novel way that allows all fractions of biomass feedstocks (e.g. carbohydrates, lignins, etc.) to contribute their energy directly into the ethanol product via fermentation and hydrogen based chemical process technologies. The goals of this project were: (1) Collect engineering data necessary for scale-up of the indirect route for ethanol production, and (2) Produce process and economic models to guide the development effort. Both goals were successfully accomplished. The projected economics of the Base Case developed in this work are comparable to today's corn based ethanol technology. Sensitivity analysis shows that significant improvements in economics for the indirect route would result if a biomass feedstock rather that starch hydrolyzate were used as the carbohydrate source. The energy ratio, defined as the ratio of green energy produced divided by the amount of fossil energy consumed, is projected to be 3.11 to 12.32 for the indirect route depending upon the details of implementation. Conventional technology has an energy ratio of 1.34, thus the indirect route will have a significant environmental advantage over today's technology. Energy savings of 7.48 trillion Btu/yr will result when 100 MMgal/yr (neat) of ethanol capacity via the indirect route is placed on-line by the year 2010.

  16. A New Route to Nano Self-Assembly

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nano Self-Assembly A New Route to Nano Self-Assembly Print Wednesday, 24 February 2010 00:00 If the promise of nanotechnology is to be fulfilled, nanoparticles will ...

  17. NIST cooperative laboratory for OSI routing technology

    SciTech Connect (OSTI)

    Montgomery, D.

    1994-05-23

    This document is one of two reports on the Integrated ISIS protocol. Required by the IAB/IESG in order for an Internet routing protocol to advance to Draft Standard Status. Integrated ISIS is an Interior Gateway Protocol and is designed to carry both IP and ISO CLNP routing information. Integrated ISIS is currently designated as a Proposed Standard. The protocol was first published in RFC 1195. Internet Draft was published subsequently to RFC 1195 and documents the current version of the protocol. This report documents experience with Integrated ISIS. This includes reports on interoperability testing, field experience and the current state of Integrated ISIS implementations. It also presents a summary of the Integrated ISIS Management Information Base (MIB), and a summary of the Integrated ISIS authentication mechanism.

  18. Charting a New Carbon Route to Development | Open Energy Information

    Open Energy Info (EERE)

    www.beta.undp.orgcontentundpenhomeourworkenvironmentandenergyfo Cost: Free Language: English Charting a New Carbon Route to Development Screenshot "UNDP recognizes the...

  19. DOE HQ Shuttle Bus Schedule and Route | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Shuttle Bus Schedule and Route DOE HQ Shuttle Bus Schedule and Route The DOE Shuttle Buses follow the same schedules between the two main Headquarters locations, Forrestal and Germantown. The buses start their routes at each Headquarters facility at the same times, see the schedule below. The subsequent stops at the other facilities are relative to the departure time of each route. The shuttle bus departure and arrival times may be impacted by traffic, weather, or other logistical interruptions.

  20. Transportation Routing Analysis Geographic Information System (TRAGIS) User's Manual

    SciTech Connect (OSTI)

    Johnson, PE

    2003-09-18

    The Transportation Routing Analysis Geographic Information System (TRAGIS) model is used to calculate highway, rail, or waterway routes within the United States. TRAGIS is a client-server application with the user interface and map data files residing on the user's personal computer and the routing engine and network data files on a network server. The user's manual provides documentation on installation and the use of the many features of the model.

  1. Cost-Effective Fabrication Routes for the Productionof Quantum...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cost-Effective Fabrication Routes for the Production of Quantum Well Type Structures and Recovery of Waste Heat from Heavy Duty Trucks Automotive Thermoelectric Generators and HVAC ...

  2. Bolivia-Brazil gas line route detailed

    SciTech Connect (OSTI)

    Not Available

    1992-05-11

    This paper reports that state oil companies of Brazil and Bolivia have signed an agreement outlining the route for a 2,270 km pipeline system to deliver natural gas from Bolivian fields to Southeast Brazil. The two sides currently are negotiating details about construction costs as well as contract volumes and prices. Capacity is projected at 283-565 MMcfd. No official details are available, but Roberto Y. Hukai, a director of the Sao Paulo engineering company Jaako Poyry/Technoplan, estimates transportation cost of the Bolivian gas at 90 cents/MMBTU. That would be competitive with the price of gas delivered to the Sao Paulo gas utility Comgas, he the. Brazil's Petroleos Brasileiro SA estimates construction of the pipeline on the Brazilian side alone with cost $1.2-1.4 billion. Bolivia's Yacimientos Petroliferos Fiscales Bolivianos (YPFB) is negotiating with private domestic and foreign investors for construction of the Bolivian portion of the project.

  3. TEC Working Group Topic Groups Routing Meeting Summaries | Department of

    Office of Environmental Management (EM)

    Energy Meeting Summaries TEC Working Group Topic Groups Routing Meeting Summaries MEETING SUMMARIES Atlanta TEC Meeting, Routing Topic Group Summary (101.72 KB) More Documents & Publications TEC Meeting Summaries - January - February 2007 TEC Working Group Topic Groups Rail Meeting Summaries TEC Working Group Topic Groups Rail Conference Call Summaries Rail Topic Group

  4. Chemical Routes to Colloidal Chalcogenide Nanosheets

    SciTech Connect (OSTI)

    Schaak, Raymond

    2015-02-19

    This project sought to develop new low-temperature synthetic pathways to intermetallic and chalcogenide nanostructures and powders, with an emphasis on systems that are relevant to advancing the synthesis, processing, and discovery of superconducting materials. The primary synthetic routes involved solution chemistry methods, and several fundamental synthetic challenges that underpinned the formation of these materials were identified and investigated. Methods for incorporating early transition metals and post transition metals into nanoscale and bulk crystals using low-temperature solution chemistry methods were developed and studied, leading to colloidal nanocrystals of elemental indium, manganese, and germanium, as well as nanocrystalline and bulk intermetallic compounds containing germanium, gallium, tin, indium, zinc, bismuth, and lithium. New chemical tools were developed to help target desired phases in complex binary intermetallic and metal chalcogenide systems that contain multiple stable phases, including direct synthesis methods and chemical routes that permit post-synthetic modification. Several phases that are metastable in bulk systems were targeted, synthesized, and characterized as nanocrystalline solids and bulk powders, including the L12-type intermetallic compounds Au3Fe, Au3Ni, and Au3Co, as well as wurtzite-type MnSe. Methods for accessing crystalline metal borides and carbides using direct solution chemistry methods were also developed, with an emphasis on Ni3B and Ni3C, which revealed useful correlations of composition and magnetic properties. Methods for scale-up and nanoparticle purification were explored, providing access to centimeter-scale pressed pellets of polyol-synthesized nanopowders and a bacteriophage-mediated method for separating impure nanoparticle mixtures into their components. Several advances were made in the synthesis of iron selenide and related superconducting materials, including the production of colloidal Fe

  5. System for Import/Export Routing and Recovery Analysis | NISAC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for ImportExport Routing and Recovery Analysis content top Network Optimization Models (RNAS and ATOM) Posted by Admin on Mar 1, 2012 in | Comments 0 comments Many critical...

  6. A New Route to Nano Self-Assembly

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nano Self-Assembly Print If the promise of nanotechnology is to be ... available nanoparticles over multiple length scales, ranging from the nano to the macro. ...

  7. Route-Based Control of Hybrid Electric Vehicles: Preprint

    SciTech Connect (OSTI)

    Gonder, J. D.

    2008-01-01

    Today's hybrid electric vehicle controls cannot always provide maximum fuel savings over all drive cycles. Route-based controls could improve HEV fuel efficiency by 2%-4% and help save nearly 6.5 million gallons of fuel annually.

  8. A Route to Metal-Organic Frameworks through Framework Templating...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Route to Metal-Organic Frameworks through Framework Templating Previous Next List Zhangwen Wei, Weigang Lu, Hai-Long Jiang, and Hong-Cai Zhou, Inorg. Chem., 2013, 52 (3), pp ...

  9. A New Route to Nano Self-Assembly

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nano Self-Assembly Print If the promise of nanotechnology is to be fulfilled, nanoparticles will have to be able to make something of themselves. An important...

  10. NEVADA NATIONAL SECURITY SITE (NNSS) DRIVERS ROUTE/SHIPMENT INFORMATION

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (NNSS) DRIVERS ROUTE/SHIPMENT INFORMATION (12/2014 Log No. 2014-229) NOTE: THIS FORM IS TWO (2) PAGES - YOU MUST COMPLETE BOTH PAGES NNSS SHIPMENT NUMBER: CARRIER NAME: TRACTOR NO.: TRAILER NO.: AT ORIGIN AT NNSS Main Gate NNSS OFFICE USE ONLY DEPARTURE DATE: ARRIVAL DATE: DESTINATION AREA: Area 5 DEPARTURE TIME: ARRIVAL TIME: NNSS DEPARTURE TIME: LOCATION: HELD OVER? No Yes REASON: ROUTE INFORMATION REVIEWED BY: ONSITE SHIPMENT (MAP NOT APPLICABLE) DROP YARD; LEAVE THIS FORM WITH SHIPPING

  11. Systems for the Intermodal Routing of Spent Nuclear Fuel

    SciTech Connect (OSTI)

    Peterson, Steven K; Liu, Cheng

    2015-01-01

    The safe and secure movement of spent nuclear fuel from shutdown and active reactor facilities to intermediate or long term storage sites may, in some instances, require the use of several modes of transportation to accomplish the move. To that end, a fully operable multi-modal routing system is being developed within Oak Ridge National Laboratory s (ORNL) WebTRAGIS (Transportation Routing Analysis Geographic Information System). This study aims to provide an overview of multi-modal routing, the existing state of the TRAGIS networks, the source data needs, and the requirements for developing structural relationships between various modes to create a suitable system for modeling the transport of spent nuclear fuel via a multimodal network. Modern transportation systems are comprised of interconnected, yet separate, modal networks. Efficient transportation networks rely upon the smooth transfer of cargoes at junction points that serve as connectors between modes. A key logistical impediment to the shipment of spent nuclear fuel is the absence of identified or designated transfer locations between transport modes. Understanding the potential network impacts on intermodal transportation of spent nuclear fuel is vital for planning transportation routes from origin to destination. By identifying key locations where modes intersect, routing decisions can be made to prioritize cost savings, optimize transport times and minimize potential risks to the population and environment. In order to facilitate such a process, ORNL began the development of a base intermodal network and associated routing code. The network was developed using previous intermodal networks and information from publicly available data sources to construct a database of potential intermodal transfer locations with likely capability to handle spent nuclear fuel casks. The coding development focused on modifying the existing WebTRAGIS routing code to accommodate intermodal transfers and the selection of

  12. Microsoft Word - Final Temp Route _9_23_08_

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bobby St. John Washington TRU Solutions (575) 234-7348 www.wipp.energy.gov For Immediate Release Temporary Transportation Route Established for WIPP Shipments CARLSBAD, N.M., September 23, 2008 - The U.S. Department of Energy's (DOE) Carlsbad Field Office (CBFO), in conjunction with Texas and New Mexico departments of transportation, has identified a temporary transportation route for waste shipments to the Waste Isolation Pilot Plant (WIPP), due to roadwork in Texas. Currently, transuranic, or

  13. The fuel efficient missile combat crew routing network. Master's thesis

    SciTech Connect (OSTI)

    Jacques, E.O. Jr.; Woolley, M.G.

    1980-06-01

    Missile combat crew vehicles are the highest mileage accumulators within SAC and, in the interest of energy conservation, Vice CINCSAC has initiated a long-term study examining utilization of more fuel efficient crew vehicles. This thesis extends the SAC study by determining if alternate dispatch procedures and routes of travel, using currently assigned vehicles, would result in fuel conservation. A network routing model is used to determine the routes of travel for three deployment strategies and five vehicle types at the Minot AFB, ND test base. Fuel efficiency for these fifteen alternatives, measured as gallons of fuel consumed per passenger, is compared with the existing missile combat crew routing network. This study found that ten of the fifteen vehicle/deployment strategy combinations, when employed over the shortest authorized routes of travel that were developed, provided improvement over the fuel efficiency of the MCC routing system that was in effect as of 31 August 1979. The largest potential savings amounted to 52% or 26,255 gallons of fuel per year.

  14. Synthesis of graphene platelets by chemical and electrochemical route

    SciTech Connect (OSTI)

    Ramachandran, Rajendran; Felix, Sathiyanathan [Centre for Nanotechnology Research, VIT University, Vellore 632014, Tamil Nadu (India); Joshi, Girish M. [Materials Physics Division, School of Advanced Sciences, VIT University, Vellore 632014, Tamil Nadu (India); Raghupathy, Bala P.C., E-mail: balapraveen2000@yahoo.com [Centre for Nanotechnology Research, VIT University, Vellore 632014, Tamil Nadu (India); Research and Advanced Engineering Division (Materials), Renault Nissan Technology and Business Center India (P) Ltd., Chennai, Tamil Nadu (India); Jeong, Soon Kwan, E-mail: jeongsk@kier.re.kr [Climate Change Technology Research Division, Korea Institute of Energy Research, Yuseong-gu, Daejeon 305-343 (Korea, Republic of); Grace, Andrews Nirmala, E-mail: anirmalagrace@vit.ac.in [Centre for Nanotechnology Research, VIT University, Vellore 632014, Tamil Nadu (India); Climate Change Technology Research Division, Korea Institute of Energy Research, Yuseong-gu, Daejeon 305-343 (Korea, Republic of)

    2013-10-15

    Graphical abstract: A schematic showing the overall reduction process of graphite to reduced graphene platelets by chemical and electrochemical route. - Highlights: Graphene was prepared by diverse routes viz. chemical and electrochemical methods. NaBH{sub 4} was effective for removing oxygen functional groups from graphene oxide. Sodium borohydride reduced graphene oxide (SRGO) showed high specific capacitance. Electrochemical rendered a cheap route for production of graphene in powder form. - Abstract: Graphene platelets were synthesized from graphene oxide by chemical and electrochemical route. Under the chemical method, sodium borohydride and hydrazine chloride were used as reductants to produce graphene. In this paper, a novel and cost effective electrochemical method, which can simplify the process of reduction on a larger scale, is demonstrated. The electrochemical method proposed in this paper produces graphene in powder form with good yield. The atomic force microscopic images confirmed that the graphene samples prepared by all the routes have multilayers of graphene. The electrochemical process provided a new route to make relatively larger area graphene sheets, which will have interest for further patterning applications. Attempt was made to quantify the quantum of reduction using cyclic voltammetry and choronopotentiometry techniques on reduced graphene samples. As a measure in reading the specific capacitance values, a maximum specific capacitance value of 265.3 F/g was obtained in sodium borohydride reduced graphene oxide.

  15. Method and apparatus for routing data in an inter-nodal communications lattice of a massively parallel computer system by dynamically adjusting local routing strategies

    DOE Patents [OSTI]

    Archer, Charles Jens; Musselman, Roy Glenn; Peters, Amanda; Pinnow, Kurt Walter; Swartz, Brent Allen; Wallenfelt, Brian Paul

    2010-03-16

    A massively parallel computer system contains an inter-nodal communications network of node-to-node links. Each node implements a respective routing strategy for routing data through the network, the routing strategies not necessarily being the same in every node. The routing strategies implemented in the nodes are dynamically adjusted during application execution to shift network workload as required. Preferably, adjustment of routing policies in selective nodes is performed at synchronization points. The network may be dynamically monitored, and routing strategies adjusted according to detected network conditions.

  16. Method and apparatus for routing data in an inter-nodal communications lattice of a massively parallel computer system by routing through transporter nodes

    DOE Patents [OSTI]

    Archer, Charles Jens; Musselman, Roy Glenn; Peters, Amanda; Pinnow, Kurt Walter; Swartz, Brent Allen; Wallenfelt, Brian Paul

    2010-11-16

    A massively parallel computer system contains an inter-nodal communications network of node-to-node links. An automated routing strategy routes packets through one or more intermediate nodes of the network to reach a destination. Some packets are constrained to be routed through respective designated transporter nodes, the automated routing strategy determining a path from a respective source node to a respective transporter node, and from a respective transporter node to a respective destination node. Preferably, the source node chooses a routing policy from among multiple possible choices, and that policy is followed by all intermediate nodes. The use of transporter nodes allows greater flexibility in routing.

  17. Capacitated arc routing problem and its extensions in waste collection

    SciTech Connect (OSTI)

    Fadzli, Mohammad; Najwa, Nurul; Luis, Martino

    2015-05-15

    Capacitated arc routing problem (CARP) is the youngest generation of graph theory that focuses on solving the edge/arc routing for optimality. Since many years, operational research devoted to CARP counterpart, known as vehicle routing problem (VRP), which does not fit to several real cases such like waste collection problem and road maintenance. In this paper, we highlighted several extensions of capacitated arc routing problem (CARP) that represents the real-life problem of vehicle operation in waste collection. By purpose, CARP is designed to find a set of routes for vehicles that satisfies all pre-setting constraints in such that all vehicles must start and end at a depot, service a set of demands on edges (or arcs) exactly once without exceeding the capacity, thus the total fleet cost is minimized. We also addressed the differentiation between CARP and VRP in waste collection. Several issues have been discussed including stochastic demands and time window problems in order to show the complexity and importance of CARP in the related industry. A mathematical model of CARP and its new version is presented by considering several factors such like delivery cost, lateness penalty and delivery time.

  18. The price of commitment in online stochastic vehicle routing

    SciTech Connect (OSTI)

    Bent, Russell W; Van Hentenryck, Pascal

    2009-01-01

    This paper considers online stochastic multiple vehicle routing with time windows in which requests arrive dynamically and the goal is to maximize the number of serviced customers. Early work has focused on very flexible routing settings where the decision to assign a vehicle to a customer is delayed until a vehicle is actually deployed to the customer. Motivated by real applications that require stability in the decision making, this paper considers a setting where the decision to assign a customer request to a vehicle must be taken when that request is accepted. Experimental results suggest that this constraint severely degrades the performance of existing algorithms. However, the paper shows how the use of stochastic information for vehicle assignment and request acceptance improves decision quality considerably. Moreover, the use of resource augmentation quantifies precisely the cost of commitment in online vehicle routing.

  19. A New Route to Nano Self-Assembly

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nano Self-Assembly A New Route to Nano Self-Assembly Print Wednesday, 24 February 2010 00:00 If the promise of nanotechnology is to be fulfilled, nanoparticles will have to be able to make something of themselves. An important advance toward this goal has been achieved by researchers who have found a simple and yet powerfully robust way to induce nanoparticles to assemble themselves into complex arrays. By adding specific types of small molecules to mixtures of nanoparticles and

  20. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nanoscale Conducting Channels in Insulating Oxides A New Route to Nanoscale Conducting Channels in Insulating Oxides Print Wednesday, 29 August 2012 00:00 Two-dimensional electron gases (2DEGs)-narrow conducting channels at the surfaces and interfaces of semiconductor materials-are the bedrock of conventional electronics. The startling 2004 discovery that such 2DEGs could be engineered at the interface between two insulating transition-metal oxides, SrTiO3 and LaAlO3, initiated a

  1. TEC Working Group Topic Groups Routing Conference Call Summaries |

    Office of Environmental Management (EM)

    Department of Energy Routing Conference Call Summaries TEC Working Group Topic Groups Routing Conference Call Summaries CONFERENCE CALL SUMMARIES January 31, 2008 (11.6 KB) December 6, 2007 (11.96 KB) October 4, 2007 (16.46 KB) August 23, 2007 (26.38 KB) June 21, 2007 (41.02 KB) May 31, 2007 (31.04 KB) January 18, 2007 (93.16 KB) December 19, 2006 (28.83 KB) November 9, 2006 (19.84 KB) More Documents & Publications TEC Working Group Topic Groups Rail Conference Call Summaries Rail Topic

  2. The Adversarial Route Analysis Tool: A Web Application

    SciTech Connect (OSTI)

    Casson, William H. Jr.

    2012-08-02

    The Adversarial Route Analysis Tool is a type of Google maps for adversaries. It's a web-based Geospatial application similar to Google Maps. It helps the U.S. government plan operations that predict where an adversary might be. It's easily accessible and maintainble and it's simple to use without much training.

  3. Optimal routing of IP packets to multi-homed servers

    SciTech Connect (OSTI)

    Swartz, K.L.

    1992-08-01

    Multi-homing, or direct attachment to multiple networks, offers both performance and availability benefits for important servers on busy networks. Exploiting these benefits to their fullest requires a modicum of routing knowledge in the clients. Careful policy control must also be reflected in the routing used within the network to make best use of specialized and often scarce resources. While relatively straightforward in theory, this problem becomes much more difficult to solve in a real network containing often intractable implementations from a variety of vendors. This paper presents an analysis of the problem and proposes a useful solution for a typical campus network. Application of this solution at the Stanford Linear Accelerator Center is studied and the problems and pitfalls encountered are discussed, as are the workarounds used to make the system work in the real world.

  4. Exploration of Melt Spinning as a Route to Large Volume Production of Skutterudite Thermoelectric Materials

    Broader source: Energy.gov [DOE]

    Melt spinning combined with Spark Plasma Sintering provides a potential route to the mass production of Skutterudite based thermoelectric materials

  5. A New Route to Nano Self-Assembly

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nano Self-Assembly Print If the promise of nanotechnology is to be fulfilled, nanoparticles will have to be able to make something of themselves. An important advance toward this goal has been achieved by researchers who have found a simple and yet powerfully robust way to induce nanoparticles to assemble themselves into complex arrays. By adding specific types of small molecules to mixtures of nanoparticles and polymers, they were able to direct the self-assembly of the

  6. A New Route to Nano Self-Assembly

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nano Self-Assembly Print If the promise of nanotechnology is to be fulfilled, nanoparticles will have to be able to make something of themselves. An important advance toward this goal has been achieved by researchers who have found a simple and yet powerfully robust way to induce nanoparticles to assemble themselves into complex arrays. By adding specific types of small molecules to mixtures of nanoparticles and polymers, they were able to direct the self-assembly of the

  7. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nanoscale Conducting Channels in Insulating Oxides Print Two-dimensional electron gases (2DEGs)-narrow conducting channels at the surfaces and interfaces of semiconductor materials-are the bedrock of conventional electronics. The startling 2004 discovery that such 2DEGs could be engineered at the interface between two insulating transition-metal oxides, SrTiO3 and LaAlO3, initiated a worldwide effort to harness the functionality of oxide materials for advanced electronic

  8. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Route to Nanoscale Conducting Channels in Insulating Oxides Print Two-dimensional electron gases (2DEGs)-narrow conducting channels at the surfaces and interfaces of semiconductor materials-are the bedrock of conventional electronics. The startling 2004 discovery that such 2DEGs could be engineered at the interface between two insulating transition-metal oxides, SrTiO3 and LaAlO3, initiated a worldwide effort to harness the functionality of oxide materials for advanced electronic

  9. A New Route to Nano Self-Assembly

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nano Self-Assembly Print If the promise of nanotechnology is to be fulfilled, nanoparticles will have to be able to make something of themselves. An important advance toward this goal has been achieved by researchers who have found a simple and yet powerfully robust way to induce nanoparticles to assemble themselves into complex arrays. By adding specific types of small molecules to mixtures of nanoparticles and polymers, they were able to direct the self-assembly of the

  10. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nanoscale Conducting Channels in Insulating Oxides Print Two-dimensional electron gases (2DEGs)-narrow conducting channels at the surfaces and interfaces of semiconductor materials-are the bedrock of conventional electronics. The startling 2004 discovery that such 2DEGs could be engineered at the interface between two insulating transition-metal oxides, SrTiO3 and LaAlO3, initiated a worldwide effort to harness the functionality of oxide materials for advanced electronic

  11. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nanoscale Conducting Channels in Insulating Oxides Print Two-dimensional electron gases (2DEGs)-narrow conducting channels at the surfaces and interfaces of semiconductor materials-are the bedrock of conventional electronics. The startling 2004 discovery that such 2DEGs could be engineered at the interface between two insulating transition-metal oxides, SrTiO3 and LaAlO3, initiated a worldwide effort to harness the functionality of oxide materials for advanced electronic

  12. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nanoscale Conducting Channels in Insulating Oxides Print Two-dimensional electron gases (2DEGs)-narrow conducting channels at the surfaces and interfaces of semiconductor materials-are the bedrock of conventional electronics. The startling 2004 discovery that such 2DEGs could be engineered at the interface between two insulating transition-metal oxides, SrTiO3 and LaAlO3, initiated a worldwide effort to harness the functionality of oxide materials for advanced electronic

  13. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nanoscale Conducting Channels in Insulating Oxides Print Two-dimensional electron gases (2DEGs)-narrow conducting channels at the surfaces and interfaces of semiconductor materials-are the bedrock of conventional electronics. The startling 2004 discovery that such 2DEGs could be engineered at the interface between two insulating transition-metal oxides, SrTiO3 and LaAlO3, initiated a worldwide effort to harness the functionality of oxide materials for advanced electronic

  14. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nanoscale Conducting Channels in Insulating Oxides Print Two-dimensional electron gases (2DEGs)-narrow conducting channels at the surfaces and interfaces of semiconductor materials-are the bedrock of conventional electronics. The startling 2004 discovery that such 2DEGs could be engineered at the interface between two insulating transition-metal oxides, SrTiO3 and LaAlO3, initiated a worldwide effort to harness the functionality of oxide materials for advanced electronic

  15. A Hybrid Catalytic Route to Fuels from Biomass Syngas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    May 21, 2013 Gasification Mike Schultz, PhD., Project PI A Hybrid Catalytic Route to Fuels from Biomass Syngas Project Goal A hybrid biorefinery design that enables the production of jet fuel and other hydrocarbon fuels from waste biomass System Integration, Optimization and Analysis Integration Gasification & Syngas Conditioning Fermentation & Alcohol Recovery Catalysis Catalysis Gasoline Jet Fuel Diesel Butadiene MEK EtOH 2,3BD Wood Stover Switchgrass Improve Economics and Process

  16. Holey Germanium - New Routes to Ordered Nanoporous Semiconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Holey Germanium - New Routes to Ordered Nanoporous Semiconductors Nanoporous or mesoporous inorganic materials with homogeneous pore sizes have found broad applications in separations, as supports for size selective catalysis, and as low dielectric materials. For all of these applications, it is the pore space that is important, and so the inorganic framework is generally formed from a simple material like silica or another oxide. In an effort to extend the range of potential applications for

  17. Polar Gas to pick route for Arctic Y Line

    SciTech Connect (OSTI)

    Not Available

    1980-05-26

    Polar Gas Project is considering four possible Y line routes to move gas reserves from the Arctic Islands and the MacKenzie Delta/Beaufort Sea areas to southern Canada. All four routes are west of the single line route proposed by Polar Gas Ltd. in 1977 to run from the Arctic Islands to Longlac, Ontario, and would connect with existing pipelines at either Longlac, Winnipeg, Calgary, or Edmonton. Marketable reserves in the High Arctic Islands are estimated at 12.7 trillion cubic feet, not counting 3-6 trillion cubic feet probably contained in recent discoveries; the MacKenzie Delta reserves are estimated at 5.8 trillion cubic feet. The gas will be chilled to 0C for passage through permafrost regions, to prevent thawing of the soil, but the gas will be at higher temperatures in other areas, with various construction techniques used to protect the area of discontinuous permafrost from thawing. More than $70 million has been spent on project studies. An application will be filed in 1981, and the pipeline could be completed in 7-10 years.

  18. TEC Working Group Topic Groups Routing Key Documents | Department of Energy

    Office of Environmental Management (EM)

    Key Documents TEC Working Group Topic Groups Routing Key Documents KEY DOCUMENTS Proposed Task Plan - Routing Topic Group (53.69 KB) More Documents & Publications TEC Working Group Topic Groups Routing Conference Call Summaries TEC Working Group Topic Groups Rail Key Documents TEC Meeting Summaries - September 2006

  19. Routes to spatiotemporal chaos in Kerr optical frequency combs

    SciTech Connect (OSTI)

    Coillet, Aurélien; Chembo, Yanne K.

    2014-03-15

    We investigate the various routes to spatiotemporal chaos in Kerr optical frequency combs, obtained through pumping an ultra-high Q-factor whispering-gallery mode resonator with a continuous-wave laser. The Lugiato–Lefever model is used to build bifurcation diagrams with regards to the parameters that are externally controllable, namely, the frequency and the power of the pumping laser. We show that the spatiotemporal chaos emerging from Turing patterns and solitons display distinctive dynamical features. Experimental spectra of chaotic Kerr combs are also presented for both cases, in excellent agreement with theoretical spectra.

  20. Fabrication Routes for High Strength High Conductivity Wires

    SciTech Connect (OSTI)

    Han, K.; Embury, J.D.; Sims, J.R.; Pantsyrnyi, V.I.; Shikov, A.; Bochvar, A.A.

    1998-10-01

    The development of suitable wires for magnet windings requires both the attainment of suitable combinations of properties (electrical conductivity and strength), the development of a production route capable of fabricating suitable quantity of wire of required dimension (5.2x7.6mm{sup 2} cross-section and 120 m in length) and a product with acceptable fabricability, joinability and service life. In this survey, the authors consider methods of producing suitable wire products by the codeformation of in-situ composites. This will include details of the quality control of the processing of Cu-Ag and Cu-Nb and the assessment of their detailed mechanical properties.

  1. Modeling and Tool Wear in Routing of CFRP

    SciTech Connect (OSTI)

    Iliescu, D.; Fernandez, A.; Gutierrez-Orrantia, M. E.; Lopez de Lacalle, L. N.

    2011-01-17

    This paper presents the prediction and evaluation of feed force in routing of carbon composite material. In order to extend tool life and improve quality of the machined surface, a better understanding of uncoated and coated tool behaviors is required. This work describes (1) the optimization of the geometry of multiple teeth tools minimizing the tool wear and the feed force, (2) the optimization of tool coating and (3) the development of a phenomenological model between the feed force, the routing parameters and the tool wear. The experimental results indicate that the feed rate, the cutting speed and the tool wear are the most significant factors affecting the feed force. In the case of multiple teeth tools, a particular geometry with 14 teeth right helix right cut and 11 teeth left helix right cut gives the best results. A thick AlTiN coating or a diamond coating can dramatically improve the tool life while minimizing the axial force, roughness and delamination. A wear model has then been developed based on an abrasive behavior of the tool. The model links the feed rate to the tool geometry parameters (tool diameter), to the process parameters (feed rate, cutting speed and depth of cut) and to the wear. The model presented has been verified by experimental tests.

  2. Optimization of municipal solid waste collection and transportation routes

    SciTech Connect (OSTI)

    Das, Swapan Bhattacharyya, Bidyut Kr.

    2015-09-15

    Graphical abstract: Display Omitted - Highlights: • Profitable integrated solid waste management system. • Optimal municipal waste collection scheme between the sources and waste collection centres. • Optimal path calculation between waste collection centres and transfer stations. • Optimal waste routing between the transfer stations and processing plants. - Abstract: Optimization of municipal solid waste (MSW) collection and transportation through source separation becomes one of the major concerns in the MSW management system design, due to the fact that the existing MSW management systems suffer by the high collection and transportation cost. Generally, in a city different waste sources scatter throughout the city in heterogeneous way that increase waste collection and transportation cost in the waste management system. Therefore, a shortest waste collection and transportation strategy can effectively reduce waste collection and transportation cost. In this paper, we propose an optimal MSW collection and transportation scheme that focus on the problem of minimizing the length of each waste collection and transportation route. We first formulize the MSW collection and transportation problem into a mixed integer program. Moreover, we propose a heuristic solution for the waste collection and transportation problem that can provide an optimal way for waste collection and transportation. Extensive simulations and real testbed results show that the proposed solution can significantly improve the MSW performance. Results show that the proposed scheme is able to reduce more than 30% of the total waste collection path length.

  3. Vehicle routing for the last mile of power system restoration

    SciTech Connect (OSTI)

    Bent, Russell W; Coffrin, Carleton; Van Hentenryck, Pascal

    2010-11-23

    This paper studied a novel problem in power system restoration: the Power Restoration Vehicle Routing Problem (PRVRP). The goal of PRVRPs is to decide how coordinate repair crews effectively in order to recover from blackouts as fast as possible after a disaster has occurred. PRVRPs are complex problems that combine vehicle routing and power restoration scheduling problems. The paper proposed a multi-stage optimization algorithm based on the idea of constraint injection that meets the aggressive runtime constraints necessary for disaster recovery. The algorithms were validated on benchmarks produced by the Los Alamos National Laboratory, using the infrastructure of the United States. The disaster scenarios were generated by state-of-the-art hurricane simulation tools similar to those used by the National Hurricane Center. Experimental results show that the constraint-injection algorithms can reduce the blackouts by 50% or more over field practices. Moreover, the results show that the constraint-injection algorithm using large neighborhood search over a blackbox simulator provide competitive quality and scales better than using a MIP solver on the subproblems.

  4. DOE_HQ_Shuttle_Bus_Route-and-Schedule (05-2016).docx

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    May, 2016 DOE HQ Shuttle Bus Route and Schedule The DOE Shuttle Buses follow the same schedules between the two main Headquarters locations, Forrestal and Germantown. The buses start their routes at each Headquarters facility at the same times, see the schedule below. The subsequent stops at the other facilities are relative to the departure time of each route. Headquarters employees are reminded of the statutory provisions that authorize and limit the use of the shuttle bus service. Specific

  5. Exploration of Melt Spinning as a Route to Large Volume Production...

    Broader source: Energy.gov (indexed) [DOE]

    Melt spinning combined with Spark Plasma Sintering provides a potential route to the mass production of Skutterudite based thermoelectric materials salvador.pdf (5.17 MB) More ...

  6. Synthesis of carbon micro-rods via a solvothermal route

    SciTech Connect (OSTI)

    Mi Yuanzhu Hu Weibing; Dan Youmeng

    2009-04-02

    Novel carbon micro-rods with regular and uniform shape have been synthesized in high yield by magnesium acetate and n-butyl alcohol as the precursors via a solvothermal route. The resulting products were characterized by combined techniques including X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray (EDX) and Raman spectroscopy. The carbon micro-rods exhibit diameters ranging from 500 nm to 1 {mu}m and up to 5-10 {mu}m in length. We have found that the optimal reaction conditions for the growth of the carbon micro-rods were 500 deg. C and 12 h.

  7. Solvothermal routes for synthesis of zinc oxide nanorods.

    SciTech Connect (OSTI)

    Bell, Nelson Simmons

    2005-03-01

    Control of the synthesis of nanomaterials to produce morphologies exhibiting quantized properties will enable device integration of several novel applications including biosensors, catalysis, and optical devices. In this work, solvothermal routes to produce zinc oxide nanorods are explored. Much previous work has relied on the addition of growth directing/inhibiting agents to control morphology. It was found in coarsening studies that zinc oxide nanodots will ripen to nanorod morphologies at temperatures of 90 to 120 C. The resulting nanorods have widths of 9-12 nm average dimension, which is smaller than current methods for nanorod synthesis. Use of nanodots as nuclei may be an approach that will allow for controlled growth of higher aspect ratio nanorods.

  8. Tuple spaces in hardware for accelerated implicit routing

    SciTech Connect (OSTI)

    Baker, Zachary Kent; Tripp, Justin

    2010-12-01

    Organizing and optimizing data objects on networks with support for data migration and failing nodes is a complicated problem to handle as systems grow. The goal of this work is to demonstrate that high levels of speedup can be achieved by moving responsibility for finding, fetching, and staging data into an FPGA-based network card. We present a system for implicit routing of data via FPGA-based network cards. In this system, data structures are requested by name, and the network of FPGAs finds the data within the network and relays the structure to the requester. This is acheived through successive examination of hardware hash tables implemented in the FPGA. By avoiding software stacks between nodes, the data is quickly fetched entirely through FPGA-FPGA interaction. The performance of this system is orders of magnitude faster than software implementations due to the improved speed of the hash tables and lowered latency between the network nodes.

  9. EIA cites importance of key world shipping routes

    SciTech Connect (OSTI)

    Not Available

    1994-03-07

    A disruption of crude oil or products shipments through any of six world chokepoints would cause a spike in oil prices, the US Energy Information Administration (EIA) warns. The strategic importance of each major shipping lane varies because of differing oil volumes and access to other transportation routes. But nearly half of the 66 million b/d of oil consumed worldwide flows through one or more of these key tanker routes, involving: 14 million b/d through the Strait of Hormuz from the Persian Gulf to the Gulf of Oman and Arabian Sea; 7 million b/d through the Strait of Malacca from the northern Indian Ocean into the South China Sea and Pacific Ocean; 1.6 million b/d through the Bosporus from the Black Sea to the Mediterranean Sea; 900,000 b/d through the Suez Canal from the Red Sea to the Mediterranean Sea; 600,000 b/d through Rotterdam Harbor from the North Sea to Dutch and German refineries on or near the Rhine River; and 500,000 b/d through the Panama Canal from the Pacific Ocean to the Caribbean Sea. In today's highly interdependent oil markets, the mere perception of less secure oil supplies is enough to boost oil prices, EIA said. Growing oil and product tanker traffic is increasing the likelihood of supply disruptions through oil arteries because of bad weather, tanker collisions, or acts of piracy, terrorism, or war. What's more, the increasing age of the world tanker fleet and dependability of navigational equipment could increase chances of accidents and, therefore, oil supply disruptions.

  10. Behavior-dependent Routing: Responding to Anomalies with Automated Low-cost Measures

    SciTech Connect (OSTI)

    Oehmen, Christopher S.; Carroll, Thomas E.; Paulson, Patrick R.; Best, Daniel M.; Noonan, Christine F.; Thompson, Seth R.; Jensen, Jeffrey L.; Fink, Glenn A.; Peterson, Elena S.

    2015-10-12

    This is a conference paper submission describing research and software implementation of a cybersecurity concept that uses behavior models to trigger changes in routing of network traffic. As user behavior deviates more and more from baseline models, traffic is routed through more elevated layers of analysis and control.

  11. 3D Torus Routing Engine Module for OFA OpenSM v. 1.0

    Energy Science and Technology Software Center (OSTI)

    2009-11-12

    This OpenFabrics Alliance (OFA) OpenSM routing engine module provides credit-loop-free routing while supporting two quality of service (QoS) levels for an InfiniBand fabric with a 3D torus topology. In addition it is able to route around multiple failed fabric links or a single failed fabric switch without introducing credit loops, and without changing path Service Level (SL) values granted before the failure.This OFA OpenSM routing engine module improves the operational characteristics of a parallel computermore » built using an InfiniBand fabric with a 3D torus topology. By providing two QoS levels, it allows system administrators to prevent application interprocess communication and file system communication from impacting each other. By providing the capability to route traffic around failed fabric components, it enables repair of failed components without impacting jobs running on the computer system.« less

  12. Crystallization engineering as a route to epitaxial strain control

    SciTech Connect (OSTI)

    Akbashev, Andrew R.; Plokhikh, Aleksandr V.; Barbash, Dmitri; Lofland, Samuel E.; Spanier, Jonathan E.

    2015-10-01

    The controlled synthesis of epitaxial thin films offers opportunities for tuning their functional properties via enabling or suppressing strain relaxation. Examining differences in the epitaxial crystallization of amorphous oxide films, we report on an alternate, low-temperature route for strain engineering. Thin films of amorphous Bi–Fe–O were grown on (001)SrTiO{sub 3} and (001)LaAlO{sub 3} substrates via atomic layer deposition. In situ X-ray diffraction and X-ray photoelectron spectroscopy studies of the crystallization of the amorphous films into the epitaxial (001)BiFeO{sub 3} phase reveal distinct evolution profiles of crystallinity with temperature. While growth on (001)SrTiO{sub 3} results in a coherently strained film, the same films obtained on (001)LaAlO{sub 3} showed an unstrained, dislocation-rich interface, with an even lower temperature onset of the perovskite phase crystallization than in the case of (001)SrTiO{sub 3}. Our results demonstrate how the strain control in an epitaxial film can be accomplished via its crystallization from the amorphous state.

  13. Recent Advances on Carbon Nanospheres. Synthetic Routes and Applications

    SciTech Connect (OSTI)

    Zhang, Pengfei; Qiao, Zhenan; Dai, Sheng

    2015-04-02

    Carbon-based materials are the most popular material types in both fundamental research and industrial applications, partly because of their well-controlled nano-morphologies. In the past two decades, we have witnessed a number of breakthroughs in carbon research: fullerenes, carbon nanotubes, and more recently graphene. Nowadays, carbon nanospheres are attracting more and more attention worldwide due to their excellent performance in various fields: drug delivery, heterogeneous catalysis, encapsulation of support and electrode materials. Actually, spherical carbon is an old material, whereas controlling carbon spheres in the nanometer range is a recent story. In the past 5 years, it has become possible to precisely control the particle size, surface area, pore size, chemical composition, and dispersity of carbon nanospheres. Toward this end, a number of synthetic strategies are emerging, such as hydrothermal carbonization of biomass-based resources, extended Stöber synthesis, and organic–organic self-assembly via different binding methods. In this feature article, we summarize recent routes for carbon nanospheres and briefly touch on their applications to shed light on the potential of this field. Throughout this article, a special emphasis is placed on the possible modulation of spherical structures at the nanoscale, and we wish to inspire many more designs and applications of carbon nanostructures in the near future.

  14. Recent Advances on Carbon Nanospheres. Synthetic Routes and Applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Pengfei; Qiao, Zhenan; Dai, Sheng

    2015-04-02

    Carbon-based materials are the most popular material types in both fundamental research and industrial applications, partly because of their well-controlled nano-morphologies. In the past two decades, we have witnessed a number of breakthroughs in carbon research: fullerenes, carbon nanotubes, and more recently graphene. Nowadays, carbon nanospheres are attracting more and more attention worldwide due to their excellent performance in various fields: drug delivery, heterogeneous catalysis, encapsulation of support and electrode materials. Actually, spherical carbon is an old material, whereas controlling carbon spheres in the nanometer range is a recent story. In the past 5 years, it has become possible tomore » precisely control the particle size, surface area, pore size, chemical composition, and dispersity of carbon nanospheres. Toward this end, a number of synthetic strategies are emerging, such as hydrothermal carbonization of biomass-based resources, extended Stöber synthesis, and organic–organic self-assembly via different binding methods. In this feature article, we summarize recent routes for carbon nanospheres and briefly touch on their applications to shed light on the potential of this field. Throughout this article, a special emphasis is placed on the possible modulation of spherical structures at the nanoscale, and we wish to inspire many more designs and applications of carbon nanostructures in the near future.« less

  15. A simple route to synthesize manganese germanate nanorods

    SciTech Connect (OSTI)

    Pei, L.Z. Yang, Y.; Yuan, C.Z.; Duan Taike; Zhang Qianfeng

    2011-06-15

    Manganese germanate nanorods have been synthesized by a simple route using germanium dioxide and manganese acetate as the source materials. X-ray diffraction observation shows that the nanorods are composed of orthorhombic and monoclinic manganese germanate phases. Scanning electron microscopy and transmission electron microscopy observations display that the manganese germanate nanorods have flat tips with the length of longer than 10 micrometers and diameter of 60-350 nm, respectively. The role of the growth conditions on the formation of the manganese germanate nanorods shows that the proper selection and combination of the growth conditions are the key factor for controlling the formation of the manganese germanate nanorods. The photoluminescence spectrum of the manganese germanate nanorods exhibits four fluorescence emission peaks centered at 422 nm, 472 nm, 487 nm and 530 nm showing the application potential for the optical devices. - Research Highlights: {yields} Manganese germanate nanorods have been synthesized by simple hydrothermal process. {yields} The formation of manganese germanate nanorods can be controlled by growth conditions. {yields} Manganese germanate nanorods exhibit good PL emission ability for optical device.

  16. Evaluation of alternate routes for the synthesis of methyl methacrylate

    SciTech Connect (OSTI)

    Spivey, J.J.; Gogate, M.R.; Zoeller, J.R.; Colberg, R.D.; Choi, G.N.

    1998-12-31

    The use of coal-derived syngas to produce high value chemicals is an important means of upgrading this resource. One example of a chemical that can be produced from coal-derived syngas is methyl methacrylate (MMA). Poly-methyl methacrylate is widely used in coatings and in various industrial molded products. The most widely practiced commercial technology for the synthesis of MMA is the acetone cyanohydrin (ACH) process. This process requires handling of large quantities of toxic hydrogen cyanide and generates one mole of ammonium bisulfate waste per mole of MMA. This bisulfate must either be regenerated or discarded, either of which substantially increases the cost. The ACH technology is thus environmentally and economically untenable for any new MMA plant expansions that would be needed to meet increasing demand. The RTI-Eastman-Bechtel research team is developing an alternative, environmentally benign route to MMA consisting of three steps; (step 1) synthesis of a propionate from ethylene, carbon monoxide, and steam, (step 2) condensation of this propionate with formaldehyde, and (step 3) esterification of resulting methacrylic acid with methanol to form MMA. This paper describes the preliminary economics of the overall process compared to other emerging processes, and focuses on step 2, including long term testing of catalysts for the condensation of propionic acid with formaldehyde to form MAA.

  17. Connectivity-Enhanced Route Selection and Adaptive Control for the Chevrolet Volt: Preprint

    SciTech Connect (OSTI)

    Gonder, J.; Wood, E.; Rajagopalan, S.

    2014-09-01

    The National Renewable Energy Laboratory and General Motors evaluated connectivity-enabled efficiency enhancements for the Chevrolet Volt. A high-level model was developed to predict vehicle fuel and electricity consumption based on driving characteristics and vehicle state inputs. These techniques were leveraged to optimize energy efficiency via green routing and intelligent control mode scheduling, which were evaluated using prospective driving routes between tens of thousands of real-world origin/destination pairs. The overall energy savings potential of green routing and intelligent mode scheduling was estimated at 5% and 3% respectively. These represent substantial opportunities considering that they only require software adjustments to implement.

  18. Connectivity-enhanced route selection and adaptive control for the Chevrolet Volt

    SciTech Connect (OSTI)

    Gonder, Jeffrey; Wood, Eric; Rajagopalan, Sai

    2016-01-01

    The National Renewable Energy Laboratory and General Motors evaluated connectivity-enabled efficiency enhancements for the Chevrolet Volt. A high-level model was developed to predict vehicle fuel and electricity consumption based on driving characteristics and vehicle state inputs. These techniques were leveraged to optimize energy efficiency via green routing and intelligent control mode scheduling, which were evaluated using prospective driving routes between tens of thousands of real-world origin/destination pairs. The overall energy savings potential of green routing and intelligent mode scheduling was estimated at 5% and 3%, respectively. Furthermore, these represent substantial opportunities considering that they only require software adjustments to implement.

  19. A survey of routing techniques in store-and-forward and wormhole interconnects.

    SciTech Connect (OSTI)

    Holman, David Michael; Lee, David S.

    2008-01-01

    This paper presents an overview of algorithms for directing messages through networks of varying topology. These are commonly referred to as routing algorithms in the literature that is presented. In addition to providing background on networking terminology and router basics, the paper explains the issues of deadlock and livelock as they apply to routing. After this, there is a discussion of routing algorithms for both store-and-forward and wormhole-switched networks. The paper covers both algorithms that do and do not adapt to conditions in the network. Techniques targeting structured as well as irregular topologies are discussed. Following this, strategies for routing in the presence of faulty nodes and links in the network are described.

  20. Constraint-Based Routing Models for the Transport of Radioactive Materials

    SciTech Connect (OSTI)

    Peterson, Steven K

    2015-01-01

    The Department of Energy (DOE) has a historic programmatic interest in the safe and secure routing, tracking, and transportation risk analysis of radiological materials in the United States. In order to address these program goals, DOE has funded the development of several tools and related systems designed to provide insight to planners and other professionals handling radioactive materials shipments. These systems include the WebTRAGIS (Transportation Routing Analysis Geographic Information System) platform. WebTRAGIS is a browser-based routing application developed at Oak Ridge National Laboratory (ORNL) focused primarily on the safe transport of spent nuclear fuel from US nuclear reactors via railway, highway, or waterway. It is also used for the transport planning of low-level radiological waste to depositories such as the Waste Isolation Pilot Plant (WIPP) facility. One particular feature of WebTRAGIS is its coupling with high-resolution population data from ORNL s LandScan project. This allows users to obtain highly accurate population count and density information for use in route planning and risk analysis. To perform the routing and risk analysis WebTRAGIS incorporates a basic routing model methodology, with the additional application of various constraints designed to mimic US Department of Transportation (DOT), DOE, and Nuclear Regulatory Commission (NRC) regulations. Aside from the routing models available in WebTRAGIS, the system relies on detailed or specialized modal networks for the route solutions. These include a highly detailed network model of the US railroad system, the inland and coastal waterways, and a specialized highway network that focuses on the US interstate system and the designated hazardous materials and Highway Route Controlled Quantity (HRCQ) -designated roadways. The route constraints in WebTRAGIS rely upon a series of attributes assigned to the various components of the different modal networks. Routes are determined via a

  1. Method and apparatus for routing data in an inter-nodal communications lattice of a massively parallel computer system by semi-randomly varying routing policies for different packets

    DOE Patents [OSTI]

    Archer, Charles Jens; Musselman, Roy Glenn; Peters, Amanda; Pinnow, Kurt Walter; Swartz, Brent Allen; Wallenfelt, Brian Paul

    2010-11-23

    A massively parallel computer system contains an inter-nodal communications network of node-to-node links. Nodes vary a choice of routing policy for routing data in the network in a semi-random manner, so that similarly situated packets are not always routed along the same path. Semi-random variation of the routing policy tends to avoid certain local hot spots of network activity, which might otherwise arise using more consistent routing determinations. Preferably, the originating node chooses a routing policy for a packet, and all intermediate nodes in the path route the packet according to that policy. Policies may be rotated on a round-robin basis, selected by generating a random number, or otherwise varied.

  2. A lower bound for routing on a completely connected optical communication parallel computer

    SciTech Connect (OSTI)

    Goldberg, L.A.; Jerrum, M.; MacKenzie, P.D.

    1993-08-03

    The task of routing a 2-relation on an n-processor completely connected optical communication parallel computer (OCPC) is considered. A lower bound is presented that applies to any randomized distributed algorithm for this task: specifically, it is shown that the expected number of steps required to route a 2-relation is {Omega}({radical} log log n) in the worst case. For comparison, the best upper bound known is O(log log n).

  3. A Hybrid Catalytic Route to Fuels from Biomass Syngas Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    LanzaTech. All rights reserved. 1 A Hybrid Catalytic Route to Fuels from Biomass Syngas BETO's Project Peer Review, March 2015 Alexandria, VA Alice Havill Senior Process Engineer Project Principle Investigator Hybrid Catalytic Route to Fuels from Biomass Syngas Project Objective: develop a hybrid conversion technology for catalytic upgrading of biomass- derived syngas to jet fuel and chemicals while ensure the cost, quality and environmental requirements of the aviation industry are met System

  4. Composition and microstructure of zirconium and hafnium germanates obtained by different chemical routes

    SciTech Connect (OSTI)

    Utkin, A.V. Prokip, V.E.; Baklanova, N.I.

    2014-01-15

    The phase composition and morphology of zirconium and hafnium germanates synthesized by ceramic and co-precipitation routes were studied. The products were characterized using high-temperature X-ray diffraction analysis (XRD), Raman spectroscopy, scanning electron microscopy (SEM) and thermal (TG/DTA) analysis. To investigate the phase composition and stoichiometry of compounds the unit cell parameters were refined by full-profile Rietveld XRD analysis. The morphology of products and its evolution during high-temperature treatment was examined by SEM analysis. It was stated that there is the strong dependence of the phase composition and morphology of products on the preparation route. The ceramic route requires a multi-stage high-temperature treatment to obtain zirconium and hafnium germanates of 95% purity or more. Also, there are strong diffusion limitations to obtain hafnium germanate Hf{sub 3}GeO{sub 8} by ceramic route. On the contrary, the co-precipitation route leads to the formation of nanocrystalline single phase germanates of stoichiometric composition at a relatively low temperatures (less than 1000 C). The results of quantitative XRD analysis showed the hafnium germanates are stoichiometric compounds in contrast to zirconium germanates that form a set of solid solutions. This distinction may be related to the difference in the ion radii of Zr and Hf. - Graphical abstract: The phase composition and morphology of zirconium and hafnium germanates synthesized by ceramic and co-precipitation routes were studied. It was stated that there is the strong dependence of the phase composition and morphology of products on the preparation route. Display Omitted - Highlights: Zr and Hf germanates were synthesized by ceramic and co-precipitation routes. The morphology of products depends on the synthesis parameters. Zirconium germanates forms a set of solid solutions. Hafnium germanates are stoichiometric compounds.

  5. INTERLINE 5. 0 -- An expanded railroad routing model: Program description, methodology, and revised user's manual

    SciTech Connect (OSTI)

    Johnson, P.E.; Joy, D.S. ); Clarke, D.B.; Jacobi, J.M. . Transportation Center)

    1993-03-01

    A rail routine model, INTERLINE, has been developed at the Oak Ridge National Laboratory to investigate potential routes for transporting radioactive materials. In Version 5.0, the INTERLINE routing algorithms have been enhanced to include the ability to predict alternative routes, barge routes, and population statistics for any route. The INTERLINE railroad network is essentially a computerized rail atlas describing the US railroad system. All rail lines, with the exception of industrial spurs, are included in the network. Inland waterways and deep water routes along with their interchange points with the US railroadsystem are also included. The network contains over 15,000 rail and barge segments (links) and over 13,000 stations, interchange points, ports, and other locations (nodes). The INTERLINE model has been converted to operate on an IBM-compatible personal computer. At least a 286 computer with a hard disk containing approximately 6 MB of free space is recommended. Enhanced program performance will be obtained by using arandom-access memory drive on a 386 or 486 computer.

  6. Baseline requirements of the proposed action for the Transportation Management Division routing models

    SciTech Connect (OSTI)

    Johnson, P.E.; Joy, D.S.

    1995-02-01

    The potential impacts associated with the transportation of hazardous materials are important to shippers, carriers, and the general public. This is particularly true for shipments of radioactive material. The shippers are primarily concerned with safety, security, efficiency, and equipment requirements. The carriers are concerned with the potential impact that radioactive shipments may have on their operations--particularly if such materials are involved in an accident. The general public has also expressed concerns regarding the safety of transporting radioactive and other hazardous materials through their communities. Because transportation routes are a central concern in hazardous material transport, the prediction of likely routes is the first step toward resolution of these issues. In response to these routing needs, several models have been developed over the past fifteen years at Oak Ridge National Laboratory (ORNL). The HIGHWAY routing model is used to predict routes for truck transportation, the INTERLINE routing model is used to predict both rail and barge routes, and the AIRPORT locator model is used to determine airports with specified criteria near a specific location. As part of the ongoing improvement of the US Department of Energy`s (DOE) Environmental Management Transportation Management Division`s (EM-261) computer systems and development efforts, a Baseline Requirements Assessment Session on the HIGHWAY, INTERLINE, and AIRPORT models was held at ORNL on April 27, 1994. The purpose of this meeting was to discuss the existing capabilities of the models and data bases and to review enhancements of the models and data bases to expand their usefulness. The results of the Baseline Requirements Assessment Section will be discussed in this report. The discussions pertaining to the different models are contained in separate sections.

  7. A Physically Based Runoff Routing Model for Land Surface and Earth System Models

    SciTech Connect (OSTI)

    Li, Hongyi; Wigmosta, Mark S.; Wu, Huan; Huang, Maoyi; Ke, Yinghai; Coleman, Andre M.; Leung, Lai-Yung R.

    2013-06-13

    A new physically based runoff routing model, called the Model for Scale Adaptive River Transport (MOSART), has been developed to be applicable across local, regional, and global scales. Within each spatial unit, surface runoff is first routed across hillslopes and then discharged along with subsurface runoff into a tributary subnetwork before entering the main channel. The spatial units are thus linked via routing through the main channel network, which is constructed in a scale-consistent way across different spatial resolutions. All model parameters are physically based, and only a small subset requires calibration.MOSART has been applied to the Columbia River basin at 1/ 168, 1/ 88, 1/ 48, and 1/ 28 spatial resolutions and was evaluated using naturalized or observed streamflow at a number of gauge stations. MOSART is compared to two other routing models widely used with land surface models, the River Transport Model (RTM) in the Community Land Model (CLM) and the Lohmann routing model, included as a postprocessor in the Variable Infiltration Capacity (VIC) model package, yielding consistent performance at multiple resolutions. MOSART is further evaluated using the channel velocities derived from field measurements or a hydraulic model at various locations and is shown to be capable of producing the seasonal variation and magnitude of channel velocities reasonably well at different resolutions. Moreover, the impacts of spatial resolution on model simulations are systematically examined at local and regional scales. Finally, the limitations ofMOSART and future directions for improvements are discussed.

  8. L-connect routing of die surface pads to the die edge for stacking in a 3D array

    DOE Patents [OSTI]

    Petersen, Robert W.

    2000-01-01

    Integrated circuit chips and method of routing the interface pads from the face of the chip or die to one or more sidewall surfaces of the die. The interconnection is routed from the face of the die to one or more edges of the die, then routed over the edge of the die and onto the side surface. A new pad is then formed on the sidewall surface, which allows multiple die or chips to be stacked in a three-dimensional array, while enabling follow-on signal routing from the sidewall pads. The routing of the interconnects and formation of the sidewall pads can be carried out in an L-connect or L-shaped routing configuration, using a metalization process such as laser pantography.

  9. Deadlock-free class routes for collective communications embedded in a multi-dimensional torus network

    SciTech Connect (OSTI)

    Chen, Dong; Eisley, Noel A.; Steinmacher-Burow, Burkhard; Heidelberger, Philip

    2013-01-29

    A computer implemented method and a system for routing data packets in a multi-dimensional computer network. The method comprises routing a data packet among nodes along one dimension towards a root node, each node having input and output communication links, said root node not having any outgoing uplinks, and determining at each node if the data packet has reached a predefined coordinate for the dimension or an edge of the subrectangle for the dimension, and if the data packet has reached the predefined coordinate for the dimension or the edge of the subrectangle for the dimension, determining if the data packet has reached the root node, and if the data packet has not reached the root node, routing the data packet among nodes along another dimension towards the root node.

  10. Kinetic, Spectroscopic, and Theoretical Assessment of Associative and Dissociative Methanol Dehydration Routes in Zeolites

    SciTech Connect (OSTI)

    Jones, Andrew J.; Iglesia, Enrique

    2014-11-03

    Mechanistic interpretations of rates and in situ IR spectra combined with density functionals that account for van der Waals interactions of intermediates and transition states within confining voids show that associative routes mediate the formation of dimethyl ether from methanol on zeolitic acids at the temperatures and pressures of practical dehydration catalysis. Methoxy-mediated dissociative routes become prevalent at higher temperatures and lower pressures, because they involve smaller transition states with higher enthalpy, but also higher entropy, than those in associative routes. These enthalpyentropy trade-offs merely reflect the intervening role of temperature in activation free energies and the prevalence of more complex transition states at low temperatures and high pressures. This work provides a foundation for further inquiry into the contributions of H-bonded methanol and methoxy species in homologation and hydrocarbon synthesis reactions from methanol.

  11. Automating Risk Assessments of Hazardous Material Shipments for Transportation Routes and Mode Selection

    SciTech Connect (OSTI)

    Barbara H. Dolphin; William D. RIchins; Stephen R. Novascone

    2010-10-01

    The METEOR project at Idaho National Laboratory (INL) successfully addresses the difficult problem in risk assessment analyses of combining the results from bounding deterministic simulation results with probabilistic (Monte Carlo) risk assessment techniques. This paper describes a software suite designed to perform sensitivity and cost/benefit analyses on selected transportation routes and vehicles to minimize risk associated with the shipment of hazardous materials. METEOR uses Monte Carlo techniques to estimate the probability of an accidental release of a hazardous substance along a proposed transportation route. A METEOR user selects the mode of transportation, origin and destination points, and charts the route using interactive graphics. Inputs to METEOR (many selections built in) include crash rates for the specific aircraft, soil/rock type and population densities over the proposed route, and bounding limits for potential accident types (velocity, temperature, etc.). New vehicle, materials, and location data are added when available. If the risk estimates are unacceptable, the risks associated with alternate transportation modes or routes can be quickly evaluated and compared. Systematic optimizing methods will provide the user with the route and vehicle selection identified with the lowest risk of hazardous material release. The effects of a selected range of potential accidents such as vehicle impact, fire, fuel explosions, excessive containment pressure, flooding, etc. are evaluated primarily using hydrocodes capable of accurately simulating the material response of critical containment components. Bounding conditions that represent credible accidents (i.e; for an impact event, velocity, orientations, and soil conditions) are used as input parameters to the hydrocode models yielding correlation functions relating accident parameters to component damage. The Monte Carlo algorithms use random number generators to make selections at the various decision

  12. On-chip electrically controlled routing of photons from a single quantum dot

    SciTech Connect (OSTI)

    Bentham, C.; Coles, R. J.; Royall, B.; O'Hara, J.; Prtljaga, N.; Fox, A. M.; Skolnick, M. S.; Wilson, L. R.; Itskevich, I. E.; Clarke, E.

    2015-06-01

    Electrical control of on-chip routing of photons emitted by a single InAs/GaAs self-assembled quantum dot (SAQD) is demonstrated in a photonic crystal cavity-waveguide system. The SAQD is located inside an H1 cavity, which is coupled to two photonic crystal waveguides. The SAQD emission wavelength is electrically tunable by the quantum-confined Stark effect. When the SAQD emission is brought into resonance with one of two H1 cavity modes, it is preferentially routed to the waveguide to which that mode is selectively coupled. This proof of concept provides the basis for scalable, low-power, high-speed operation of single-photon routers for use in integrated quantum photonic circuits.

  13. Cost-Effective Fabrication Routes for the Productionof Quantum-Well-Type

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Structures and Recovoery of Waste Heat from Heavy-Duty Trucks | Department of Energy Productionof Quantum-Well-Type Structures and Recovoery of Waste Heat from Heavy-Duty Trucks Cost-Effective Fabrication Routes for the Productionof Quantum-Well-Type Structures and Recovoery of Waste Heat from Heavy-Duty Trucks 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005_deer_willigan.pdf (494.58 KB) More Documents & Publications Cost-Effective Fabrication

  14. A novel solution-phase route for the synthesis of crystalline silver nanowires

    SciTech Connect (OSTI)

    Liu Yang; Chu Ying . E-mail: chuying@nenu.edu.cn; Yang Likun; Han Dongxue; Lue Zhongxian

    2005-10-06

    A unique solution-phase route was devised to synthesize crystal Ag nanowires with high aspect-ratio (8-10 nm in diameter and length up to 10 {mu}m) by the reduction of AgNO{sub 3} with Vitamin C in SDS/ethanol solution. The resultant nanoproducts were characterized by transmission electron microscope (TEM), X-ray diffraction (XRD) and electron diffraction (ED). A soft template mechanism was put forward to interpret the formation of metal Ag nanowires.

  15. Treatment of Portosystemic Shunt Myelopathy with a Stent Graft Deployed through a Transjugular Intrahepatic Route

    SciTech Connect (OSTI)

    Jain, Deepak Arora, Ankur; Deka, Pranjal; Mukund, Amar Bhatnagar, Shorav; Jindal, Deepti Kumar, Niteen Pamecha, Viniyendra

    2013-08-01

    A case of surgically created splenorenal shunt complicated with shunt myelopathy was successfully managed by placement of a stent graft within the splenic vein to close the portosystemic shunt and alleviate myelopathy. To our knowledge, this is the first report of a case of shunt myelopathy in a patient with noncirrhotic portal fibrosis without cirrhosis treated by a novel technique wherein a transjugular intrahepatic route was adopted to deploy the stent graft.

  16. Transit Routes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  17. Crossing Active Faults on the Sakhalin II Onshore Pipeline Route: Analysis Methodology and Basic Design

    SciTech Connect (OSTI)

    Vitali, Luigino; Mattiozzi, Pierpaolo

    2008-07-08

    Twin oil (20 and 24 inch) and gas (20 and 48 inch) pipeline systems stretching 800 km are being constructed to connect offshore hydrocarbon deposits from the Sakhalin II concession in the North to an LNG plant and oil export terminal in the South of Sakhalin island. The onshore pipeline route follows a regional fault zone and crosses individual active faults at 19 locations. Sakhalin Energy, Design and Construction companies took significant care to ensure the integrity of the pipelines, should large seismic induced ground movements occur during the Operational life of the facilities. Complex investigations including the identification of the active faults, their precise location, their particular displacement values and assessment of the fault kinematics were carried out to provide input data for unique design solutions. Lateral and reverse offset displacements of 5.5 and 4.5 m respectively were determined as the single-event values for the design level earthquake (DLE)--the 1000-year return period event. Within the constraints of a pipeline route largely fixed, the underground pipeline fault crossing design was developed to define the optimum routing which would minimize stresses and strain using linepipe materials which had been ordered prior to the completion of detailed design, and to specify requirements for pipe trenching shape, materials, drainage system, etc. This Paper describes the steps followed to formulate the concept of the special trenches and the analytical characteristics of the Model.

  18. Crossing Active Faults on the Sakhalin II Onshore Pipeline Route: Pipeline Design and Risk Analysis

    SciTech Connect (OSTI)

    Mattiozzi, Pierpaolo; Strom, Alexander

    2008-07-08

    Twin oil (20 and 24 inch) and gas (20 and 48 inch) pipeline systems stretching 800 km are being constructed to connect offshore hydrocarbon deposits from the Sakhalin II concession in the North to an LNG plant and oil export terminal in the South of Sakhalin island. The onshore pipeline route follows a regional fault zone and crosses individual active faults at 19 locations. Sakhalin Energy, Design and Construction companies took significant care to ensure the integrity of the pipelines, should large seismic induced ground movements occur during the Operational life of the facilities. Complex investigations including the identification of the active faults, their precise location, their particular displacement values and assessment of the fault kinematics were carried out to provide input data for unique design solutions. Lateral and reverse offset displacements of 5.5 and 4.5 m respectively were determined as the single-event values for the design level earthquake (DLE) - the 1000-year return period event. Within the constraints of a pipeline route largely fixed, the underground pipeline fault crossing design was developed to define the optimum routing which would minimize stresses and strain using linepipe materials which had been ordered prior to the completion of detailed design, and to specify requirements for pipe trenching shape, materials, drainage system, etc. Detailed Design was performed with due regard to actual topography and to avoid the possibility of the trenches freezing in winter, the implementation of specific drainage solutions and thermal protection measures.

  19. EA-0904: Access Road from State Route 240 to the 200 West Area Hanford Site, Richland, Washington

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to construct an access road on the U.S. Department of Energy's Hanford Site in Richland, Washington, from State Route 240 to Beloit Avenue...

  20. En Route to the Clinic: Diagnostic Sequencing Applications Using the Ion Torrent ( 7th Annual SFAF Meeting, 2012)

    ScienceCinema (OSTI)

    Muzny, Donna [Baylor College of Medicine

    2013-03-22

    Donna Muzny on "En route to the clinic: Diagnostic sequencing applications using the Ion Torrent" at the 2012 Sequencing, Finishing, Analysis in the Future Meeting held June 5-7, 2012 in Santa Fe, New Mexico.

  1. INTERLINE 5.0 -- An expanded railroad routing model: Program description, methodology, and revised user`s manual

    SciTech Connect (OSTI)

    Johnson, P.E.; Joy, D.S.; Clarke, D.B.; Jacobi, J.M.

    1993-03-01

    A rail routine model, INTERLINE, has been developed at the Oak Ridge National Laboratory to investigate potential routes for transporting radioactive materials. In Version 5.0, the INTERLINE routing algorithms have been enhanced to include the ability to predict alternative routes, barge routes, and population statistics for any route. The INTERLINE railroad network is essentially a computerized rail atlas describing the US railroad system. All rail lines, with the exception of industrial spurs, are included in the network. Inland waterways and deep water routes along with their interchange points with the US railroadsystem are also included. The network contains over 15,000 rail and barge segments (links) and over 13,000 stations, interchange points, ports, and other locations (nodes). The INTERLINE model has been converted to operate on an IBM-compatible personal computer. At least a 286 computer with a hard disk containing approximately 6 MB of free space is recommended. Enhanced program performance will be obtained by using arandom-access memory drive on a 386 or 486 computer.

  2. Synthesis of Sol-Gel Matrices for Encapsulation of Enzymes Using an Aqueous Route

    SciTech Connect (OSTI)

    Ashley, C.S.; Bhatia, R.B.; Brinker, C.J.; Harris, T.M.

    1998-11-23

    Sol-gel matrices are promising host materials for potential chemical and biosensor applications. Previous studies have focused on modified sol-gel routes using alkoxides for encapsulation of enzymes. However the formation of alcohol as a byproduct during hydrolysis and condensation reactions poses limitations. We report the immobilization of glucose oxidase and peroxidase in silica prepared by an aqueous route which may provide a more favorable environment for the biomolecules. A two step aqueous sol-gel procedure using sodium silicate as the precursor was developed to encapsulate the enzymes and the dye precursor, o-dianisidine. Glucose oxidase catalyzes the oxidation of glucose to give gluconic acid and hydrogen peroxide. Peroxidase then catalyzes the reaction of the dye precursor with hydrogen peroxide to produce a colored product. The kinetics of the coupled enzymatic reactions were monitored by optical spectroscopy and compared to those occurring in tetramethyl orthosilicate (TMOS) derived silica matrices developed by Yamanaka. Enhanced kinetics in the aqueous silicate matrices were related to differences in the host microstructure as elucidated by microstructural comparisons of the corresponding aerogels.

  3. Estimate of air carrier and air taxi crash frequencies from high altitude en route flight operations

    SciTech Connect (OSTI)

    Sanzo, D.; Kimura, C.Y.; Prassinos, P.G.

    1996-06-03

    In estimating the frequency of an aircraft crashing into a facility, it has been found convenient to break the problem down into two broad categories. One category estimates the aircraft crash frequency due to air traffic from nearby airports, the so-called near-airport environment. The other category estimates the aircraft crash frequency onto facilities due to air traffic from airways, jet routes, and other traffic flying outside the near-airport environment The total aircraft crash frequency is the summation of the crash frequencies from each airport near the facility under evaluation and from all airways, jet routes, and other traffic near the facility of interest. This paper will examine the problems associated with the determining the aircraft crash frequencies onto facilities outside the near-airport environment. This paper will further concentrate on the estimating the risk of aircraft crashes to ground facilities due to high altitude air carrier and air taxi traffic. High altitude air carrier and air taxi traffic will be defined as all air carrier and air taxi flights above 18,000 feet Mean Sea Level (MSL).

  4. A case study of pipeline route selection and design through discontinuous permafrost terrain in northwestern Alberta

    SciTech Connect (OSTI)

    Wiechnik, C.; Boivin, R.; Henderson, J.; Bowman, M.

    1996-12-31

    As the natural gas pipeline system in Western Canada expands northward, it traverses the discontinuous permafrost zone. As the ground temperature of the frozen soil in this zone is just below freezing, it can be expected that within the design life of a pipeline the permafrost adjacent to it will melt due to the disturbance of the insulating cover by construction activities. Differential settlement at the thawing frozen/unfrozen soil interfaces gives rise to pipeline strain. Based on the calculated settlement and resulting strain level, a cost effective mechanical or civil design solution can be selected to mitigate the differential settlement problem. Since these design solutions can be costly, it is desirable to combine them with a pipeline route that traverses the least amount of discontinuous permafrost terrain while minimizing the overall length of the pipeline. This paper will detail the framework utilized to select the routing for a package of pipeline projects in northwestern Alberta. It is believed that the increased front end effort will result in lower operating costs and an overall reduced life-cycle cost. This basic design methodology can be applied to any project that traverses discontinuous permafrost terrain.

  5. A Time-Slotted On-Demand Routing Protocol for Mobile Ad Hoc Unmanned Vehicle Systems

    SciTech Connect (OSTI)

    Hope Forsmann; Robert Hiromoto; John Svoboda

    2007-04-01

    The popularity of UAVs has increased dramatically because of their successful deployment in military operations, their ability to preserve human life, and the continual improvements in wireless communication that serves to increase their capabilities. We believe the usefulness of UAVs would be dramatically increased if formation flight were added to the list of capabilities. Currently, sustained formation flight with a cluster of UAVs has only been achieved with two nodes by the Multi-UAV Testbed at the Massachusetts Institute of Technology. (Park, 2004) Formation flight is a complex operation requiring the ability to adjust the flight patterns on the fly and correct for wind gusts, terrain, and differences in node equipment. All of which increases the amount of inner node communication. Since one of the problems with MANET communication is network congestion, we believe a first step towards formation flight can be made through improved inner node communication. We have investigated current communication routing protocols and developed an altered hybrid routing protocol in order to provide communication with less network congestion.

  6. Grain boundary character distribution in nanocrystalline metals produced by different processing routes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bober, David B.; Kumar, Mukal; Rupert, Timothy J.; Khalajhedayati, Amirhossein

    2015-12-28

    Nanocrystalline materials are defined by their fine grain size, but details of the grain boundary character distribution should also be important. Grain boundary character distributions are reported for ball-milled, sputter-deposited, and electrodeposited Ni and Ni-based alloys, all with average grain sizes of ~20 nm, to study the influence of processing route. The two deposited materials had nearly identical grain boundary character distributions, both marked by a Σ3 length percentage of 23 to 25 pct. In contrast, the ball-milled material had only 3 pct Σ3-type grain boundaries and a large fraction of low-angle boundaries (16 pct), with the remainder being predominantlymore » random high angle (73 pct). Furthermore, these grain boundary character measurements are connected to the physical events that control their respective processing routes. Consequences for material properties are also discussed with a focus on nanocrystalline corrosion. As a whole, the results presented here show that grain boundary character distribution, which has often been overlooked in nanocrystalline metals, can vary significantly and influence material properties in profound ways.« less

  7. Emerging patterns in intercontinental air linkages and implications for international route allocation policy

    SciTech Connect (OSTI)

    Oum, Tae Hoon; Taylor, A.J.

    1995-12-31

    The effects of deregulation, or liberalization of the domestic airline market, in the US, Canada, Australia, New Zealand, and Europe have been described by many authors. It is generally acknowledged that deregulation fostored airline efficiency through the formation of domestic hub-and-spoke networks and established market conditions that encouraged the emergence of the mega-carriers (United, American, and Delta Airlines). Predictions have been made that similar effects will be observed in the intercontinental markets as liberalization is extended to these markets, and that globalized service networks will appear through strong alliances between major carriers based on different continents. These global service networks will be created by linking up the continental hubs of the partners` networks, in order to provide frequent and efficient services. A nation may be able to influence the formation of the global networks through the appropriate selection of policies for the industry structure and international route allocation. Sections of this paper review the important features of the imminent globalization of airline networks, and describe the emerging patterns of intercontinental linkages being adopted by some major carriers in the US and Europe. Later, alternative route allocation policies are defined, and the policies being followed by the US, Japan, Canada, and Korea are analyzed.

  8. Grain boundary character distribution in nanocrystalline metals produced by different processing routes

    SciTech Connect (OSTI)

    Bober, David B.; Kumar, Mukal; Rupert, Timothy J.; Khalajhedayati, Amirhossein

    2015-12-28

    Nanocrystalline materials are defined by their fine grain size, but details of the grain boundary character distribution should also be important. Grain boundary character distributions are reported for ball-milled, sputter-deposited, and electrodeposited Ni and Ni-based alloys, all with average grain sizes of ~20 nm, to study the influence of processing route. The two deposited materials had nearly identical grain boundary character distributions, both marked by a Σ3 length percentage of 23 to 25 pct. In contrast, the ball-milled material had only 3 pct Σ3-type grain boundaries and a large fraction of low-angle boundaries (16 pct), with the remainder being predominantly random high angle (73 pct). Furthermore, these grain boundary character measurements are connected to the physical events that control their respective processing routes. Consequences for material properties are also discussed with a focus on nanocrystalline corrosion. As a whole, the results presented here show that grain boundary character distribution, which has often been overlooked in nanocrystalline metals, can vary significantly and influence material properties in profound ways.

  9. Factors affecting route selection and survival of steelhead kelts at Snake River dams in 2012 and 2013

    SciTech Connect (OSTI)

    Harnish, Ryan A.; Colotelo, Alison H. A.; Li, Xinya; Fu, Tao; Ham, Kenneth D.; Deng, Zhiqun; Green, Ethan D.

    2015-03-31

    In 2012 and 2013, Pacific Northwest National Laboratory (PNNL) conducted a study that summarized the passage route proportions and route-specific survival rates of steelhead kelts that passed through Federal Columbia River Power System (FCRPS) dams. To accomplish this, a total of 811 steelhead kelts were tagged with Juvenile Salmon Acoustic Telemetry System (JSATS) transmitters. Acoustic receivers, both autonomous and cabled, were deployed throughout the FCRPS to monitor the downstream movements of tagged kelts. Kelts were also tagged with passive integrated transponder tags to monitor passage through juvenile bypass systems (JBS) and detect returning fish. The current study evaluated data collected in 2012 and 2013 to identify environmental, temporal, operational, individual, and behavioral variables that were related to forebay residence time, route of passage, and survival of steelhead kelts at FCRPS dams on the Snake River. Multiple approaches, including 3-D tracking, bivariate and multivariable regression modeling, and decision tree analyses were used to identify the environmental, temporal, operational, individual, and behavioral variables that had the greatest effect on forebay residence time, route of passage, and route-specific and overall dam passage survival probabilities for tagged kelts at Lower Granite (LGR), Little Goose (LGS), and Lower Monumental (LMN) dams. In general, kelt behavior and discharge appeared to work independently to affect forebay residence times. Kelt behavior, primarily approach location, migration depth, and “searching” activities in the forebay, was found to have the greatest influence on their route of passage. The condition of kelts was the single most important factor affecting their survival. The information gathered in this study may be used by dam operators and fisheries managers to identify potential management actions to improve in-river survival of kelts or collection methods for kelt reconditioning programs to aid

  10. Method and apparatus for routing data in an inter-nodal communications lattice of a massively parallel computer system by employing bandwidth shells at areas of overutilization

    DOE Patents [OSTI]

    Archer, Charles Jens; Musselman, Roy Glenn; Peters, Amanda; Pinnow, Kurt Walter; Swartz, Brent Allen; Wallenfelt, Brian Paul

    2010-04-27

    A massively parallel computer system contains an inter-nodal communications network of node-to-node links. An automated routing strategy routes packets through one or more intermediate nodes of the network to reach a final destination. The default routing strategy is altered responsive to detection of overutilization of a particular path of one or more links, and at least some traffic is re-routed by distributing the traffic among multiple paths (which may include the default path). An alternative path may require a greater number of link traversals to reach the destination node.

  11. Allocating application to group of consecutive processors in fault-tolerant deadlock-free routing path defined by routers obeying same rules for path selection

    DOE Patents [OSTI]

    Leung, Vitus J.; Phillips, Cynthia A.; Bender, Michael A.; Bunde, David P.

    2009-07-21

    In a multiple processor computing apparatus, directional routing restrictions and a logical channel construct permit fault tolerant, deadlock-free routing. Processor allocation can be performed by creating a linear ordering of the processors based on routing rules used for routing communications between the processors. The linear ordering can assume a loop configuration, and bin-packing is applied to this loop configuration. The interconnection of the processors can be conceptualized as a generally rectangular 3-dimensional grid, and the MC allocation algorithm is applied with respect to the 3-dimensional grid.

  12. Diffraction limited focusing and routing of gap plasmons by a metal-dielectric-metal lens

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dennis, Brian S.; Czaplewski, David A.; Haftel, Michael I.; Lopez, Daniel; Blumberg, Girsh; Aksyuk, Vladimir

    2015-08-12

    Passive optical elements can play key roles in photonic applications such as plasmonic integrated circuits. Here we experimentally demonstrate passive gap-plasmon focusing and routing in two-dimensions. This is accomplished using a high numerical-aperture metal-dielectric-metal lens incorporated into a planar-waveguide device. Fabrication via metal sputtering, oxide deposition, electron- and focused-ion- beam lithography, and argon ion-milling is reported on in detail. Diffraction-limited focusing is optically characterized by sampling out-coupled light with a microscope. The measured focal distance and full-width-half-maximum spot size agree well with the calculated lens performance. The surface plasmon polariton propagation length is measured by sampling light from multiple out-couplermoreslits.less

  13. Apparatus and method for routing a transmission line through a downhole tool

    DOE Patents [OSTI]

    Hall, David R.; Hall, Jr., H. Tracy; Pixton, David S.; Briscoe, Michael; Reynolds, Jay

    2006-07-04

    A method for routing a transmission line through a tool joint having a primary and secondary shoulder, a central bore, and a longitudinal axis, includes drilling a straight channel, at a positive, nominal angle with respect to the longitudinal axis, through the tool joint from the secondary shoulder to a point proximate the inside wall of the centtral bore. The method further includes milling back, from within the central bore, a second channel to merge with the straight channel, thereby forming a continuous channel from the secondary shoulder to the central bore. In selected embodiments, drilling is accomplished by gun-drilling the straight channel. In other embodiments, the method includes tilting the tool joint before drilling to produce the positive, nominal angle. In selected embodiments, the positive, nominal angle is less than or equal to 15 degrees.

  14. A simple route to the synthesis of single crystalline copper metagermanate nanowires

    SciTech Connect (OSTI)

    Pei, L.Z.; Zhao, H.S.; Tan, W.; Yu, H.Y.; Chen, Y.W.; Zhang Qianfeng; Fan, C.G.

    2009-12-15

    Single crystalline copper metagermanate (CuGeO{sub 3}) nanowires with the diameter of 30-300 nm and length of longer than 100 {mu}m have been prepared by a simple hydrothermal deposition route. X-ray diffraction (XRD), selected area electron diffraction (SAED), high-resolution transmission electron microscopy (HRTEM) and Raman analyses confirm that the nanowires are orthorhombic single crystals with a main growth direction along <101>. Room temperature photoluminescence (PL) measurement shows a strong blue emission peak at 442 nm with a broad emission band. The blue emission may be ascribed to radiative recombination of oxygen vacancies and oxygen-germanium vacancies. The formation process of CuGeO{sub 3} nanowires is also discussed.

  15. Production of high quality steels using the scrap/electric arc furnace route

    SciTech Connect (OSTI)

    Houpert, C.; Lanteri, V.; Jolivet, J.M.; Guttmann, M.; Birat, J.P.; Jallon, M.; Confente, M.

    1996-12-31

    Europe, after North America, is increasing the share of electric arc furnace steelmaking at the expense of integrated steel production and the trend appears to be long term. The driving forces for this change are strong: availability of scrap, social pressure to recycle materials and economic benefits to be reaped from the small structure associated with this short and slim production route. The increasing use of scrap does raise some problems however, in terms of the tramp element build up within the scrap deposit over time. Scrap pretreatment, which aims at separating steel from non-ferrous material during preparation, is thus attracting a lot of attention. The purpose of the present work was to investigate quantitatively the potential problems related to increased levels in tramp elements, with two objectives: identify, on a case by case basis, the currently existing practical limits and devise countermeasures to further extend these limits by better controlling process parameters for instance.

  16. Distributed Power Flow Control: Distributed Power Flow Control using Smart Wires for Energy Routing

    SciTech Connect (OSTI)

    2012-04-24

    GENI Project: Smart Wire Grid is developing a solution for controlling power flow within the electric grid to better manage unused and overall transmission capacity. The 300,000 miles of high-voltage transmission line in the U.S. today are congested and inefficient, with only around 50% of all transmission capacity utilized at any given time. Increased consumer demand should be met in part with more efficient and an economical power flow. Smart Wire Grid’s devices clamp onto existing transmission lines and control the flow of power within—much like how internet routers help allocate bandwidth throughout the web. Smart wires could support greater use of renewable energy by providing more consistent control over how that energy is routed within the grid on a real-time basis. This would lessen the concerns surrounding the grid’s inability to effectively store intermittent energy from renewables for later use.

  17. A novel process route for the production of spherical SLS polymer powders

    SciTech Connect (OSTI)

    Schmidt, Jochen; Sachs, Marius; Blümel, Christina; Winzer, Bettina; Toni, Franziska; Wirth, Karl-Ernst; Peukert, Wolfgang

    2015-05-22

    Currently, rapid prototyping gradually is transferred to additive manufacturing opening new applications. Especially selective laser sintering (SLS) is promising. One drawback is the limited choice of polymer materials available as optimized powders. Powders produced by cryogenic grinding show poor powder flowability resulting in poor device quality. Within this account we present a novel process route for the production of spherical polymer micron-sized particles of good flowability. The feasibility of the process chain is demonstrated for polystyrene e. In a first step polymer microparticles are produced by a wet grinding method. By this approach the mean particle size and the particle size distribution can be tuned between a few microns and several 10 microns. The applicability of this method will be discussed for different polymers and the dependencies of product particle size distribution on stressing conditions and process temperature will be outlined. The comminution products consist of microparticles of irregular shape and poor powder flowability. An improvement of flowability of the ground particles is achieved by changing their shape: they are rounded using a heated downer reactor. The influence of temperature profile and residence time on the product properties will be addressed applying a viscous-flow sintering model. To further improve the flowability of the cohesive spherical polymer particles nanoparticles are adhered onto the microparticles’ surface. The improvement of flowability is remarkable: rounded and dry-coated powders exhibit a strongly reduced tensile strength as compared to the comminution product. The improved polymer powders obtained by the process route proposed open new possibilities in SLS processing including the usage of much smaller polymer beads.

  18. Investigation of nanocrystalline zinc chromite obtained by two soft chemical routes

    SciTech Connect (OSTI)

    Gingasu, Dana; Mindru, Ioana; Culita, Daniela C.; Patron, Luminita; Calderon-Moreno, Jose Maria; Preda, Silviu; Oprea, Ovidiu; Osiceanu, Petre; Morena Pineda, Eufemio

    2014-01-01

    Graphical abstract: - Highlights: • Two soft chemical routes to synthesize zinc chromites are described. • Glycine is used as chelating agent (precursor method) and fuel (solution combustion method). • The synthesized chromites have crystallite size in the range of 18–27 nm. • An antiferromagnetic (AFM) transition is observed at about T{sub N} ∼ 18 K. - Abstract: Zinc chromite (ZnCr{sub 2}O{sub 4}) nanocrystalline powders were obtained by two different chemical routes: the precursor method and the solution combustion method involving glycine-nitrates. The complex compound precursors, [ZnCr{sub 2}(NH{sub 2}CH{sub 2}COO){sub 8}]·9H{sub 2}O and [ZnCr{sub 2}(NH{sub 2}CH{sub 2}COOH){sub 4.5}]·(NO{sub 3}){sub 8}·6H{sub 2}O, were characterized by chemical analysis, infrared spectroscopy (IR), ultraviolet–visible spectroscopy (UV–vis) and thermal analysis. The structure, morphology, surface chemistry and magnetic properties of ZnCr{sub 2}O{sub 4} powders were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), infrared and Raman spectroscopy (RS), ultraviolet–visible spectroscopy (UV–vis) and magnetic measurements. X-ray diffraction patterns indicated the chromite spinel phase with good crystallinity and an average crystallite size of approximately 18–27 nm. The band gap values ranged between 3.31 and 3.33 eV. The magnetic measurements indicated an antiferromagnetic transition at T{sub N} ∼ 17.5/18 K.

  19. Generalized chemical route to develop fatty acid capped highly dispersed semiconducting metal sulphide nanocrystals

    SciTech Connect (OSTI)

    Patel, Jayesh D.; Chemical Engineering Department, University of Laval, Quebec, QC, G1K 7P4 ; Mighri, Frej; Chemical Engineering Department, University of Laval, Quebec, QC, G1K 7P4 ; Ajji, Abdellah; Chemical Engineering Department, Ecole Polytechnique, C.P. 6079, Succ. Centre-Ville Montreal, QC, H3C 3A7

    2012-08-15

    Highlights: ► Chemical route for the synthesis of OA-capped CdS, ZnS and PbS at low temperature. ► Synthesized nanocrystals via thermolysis of their metal–oleate complexes. ► Size quantized nanocrystals were highly dispersed and stable at room temperature. -- Abstract: This work deals with the synthesis of highly dispersed semiconducting nanocrystals (NCs) of cadmium sulphide (CdS), zinc sulphide (ZnS) and lead sulphide (PbS) through a simple and generalized process using oleic acid (OA) as surfactant. To synthesize these NCs, metal–oleate (M–O) complexes were obtained from the reaction at 140 °C between metal acetates and OA in hexanes media. Subsequently, M–O complexes were sulphurized using thioacetamide at the same temperature. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) characterizations show that the synthesized products are of nanoscale-size with highly crystalline cubic phase. The optical absorption of OA-capped metal sulphide NCs confirms that their size quantization induced a large shift towards visible region. Photoluminescence (PL) spectrum of CdS NCs shows a broad band-edge emission with shallow and deep-trap emissions, while PL spectrum of ZnS NCs reveals a broad emission due to defects states on the surface. The thermogravimetric analysis (TGA) and Fourier transform infrared (FTIR) spectroscopy indicate that fatty acid monolayers were bound strongly on the nanocrystal surface as a carboxylate and the two oxygen atoms of the carboxylate were coordinated symmetrically to the surface of the NCs. The strong binding between the fatty acid and the NCs surface enhances the stability of NCs colloids. In general, this generalized route has a great potential in developing nanoscale metal sulphides for opto-electronic devices.

  20. Yucca Mountain transportation routes: Preliminary characterization and risk analysis; Volume 2, Figures [and] Volume 3, Technical Appendices

    SciTech Connect (OSTI)

    Souleyrette, R.R. II; Sathisan, S.K.; di Bartolo, R.

    1991-05-31

    This report presents appendices related to the preliminary assessment and risk analysis for high-level radioactive waste transportation routes to the proposed Yucca Mountain Project repository. Information includes data on population density, traffic volume, ecologically sensitive areas, and accident history.

  1. Factors Affecting Route Selection and Survival of Steelhead Kelts at Snake River Dams in 2012 and 2013

    SciTech Connect (OSTI)

    Harnish, Ryan A.; Colotelo, Alison HA; Li, Xinya; Ham, Kenneth D.; Deng, Zhiqun

    2014-12-15

    In 2012 and 2013, Pacific Northwest National Laboratory conducted a study that summarized the passage proportions and route-specific survival rates of steelhead kelts that passed through Federal Columbia River Power System (FCRPS) dams. To accomplish this, a total of 811 steelhead kelts were tagged with Juvenile Salmon Acoustic Telemetry System (JSATS) transmitters. Acoustic receivers, both autonomous and cabled, were deployed throughout the FCRPS to monitor the downstream movements of tagged-kelts. Kelts were also tagged with Passive Integrated Transponder tags to monitor passage through juvenile bypass systems and detect returning fish. The current study evaluated data collected in 2012 and 2013 to identify individual, behavioral, environmental and dam operation variables that were related to passage and survival of steelhead kelts that passed through FCRPS dams. Bayesian model averaging of multivariable logistic regression models was used to identify the environmental, temporal, operational, individual, and behavioral variables that had the highest probability of influencing the route of passage and the route-specific survival probabilities for kelts that passed Lower Granite (LGR), Little Goose (LGS), and Lower Monumental (LMN) dams in 2012 and 2013. The posterior probabilities of the best models for predicting route of passage ranged from 0.106 for traditional spill at LMN to 0.720 for turbine passage at LGS. Generally, the behavior (depth and near-dam searching activity) of kelts in the forebay appeared to have the greatest influence on their route of passage. Shallower-migrating kelts had a higher probability of passing via the weir and deeper-migrating kelts had a higher probability of passing via the JBS and turbines than other routes. Kelts that displayed a higher level of near-dam searching activity had a higher probability of passing via the spillway weir and those that did less near-dam searching had a higher probability of passing via the JBS and

  2. Simple route for the synthesis of supercapacitive Co-Ni mixed hydroxide thin films

    SciTech Connect (OSTI)

    Dubal, D.P.; Department of Materials Science and Engineering, Gwangju Institute of Science and Technology, 261 Cheomdan-gwagiro, Buk-gu, Gwangju 500-712 ; Jagadale, A.D.; Patil, S.V.; Lokhande, C.D.

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer Novel method for deposition of Co-Ni mixed hydroxide. Black-Right-Pointing-Pointer Nanoparticle network of Co-Ni hydroxide. Black-Right-Pointing-Pointer High specific capacitance of 672 F g{sup -1}. Black-Right-Pointing-Pointer High discharge/charge rates. -- Abstract: Facile synthesis of Co-Ni mixed hydroxides films with interconnected nanoparticles networks through two step route is successfully established. These films have been characterized by X-ray diffraction (XRD), Fourier transform infrared technique (FTIR), scanning electron microscopy (SEM) and wettability test. Co-Ni film formation is confirmed from XRD and FTIR study. SEM shows that the surface of Co-Ni films is composed of interconnected nanoparticles. Contact angle measurement revealed the hydrophilic nature of films which is feasible for the supercapacitor. The electrochemical performance of the film is evaluated by cyclic voltammetry, and constant-current charge/discharge cycling techniques. Specific capacitance of the Co-Ni mixed hydroxide electrode achieved 672 F g{sup -1}. Impedance analysis shows that Co-Ni mixed hydroxide electrode provides less resistance for the intercalation and de-intercalation of ions. The Co-Ni mixed electrode exhibited good charge/discharge rate at different current densities. The results demonstrated that Co-Ni mixed hydroxide composite is very promising for the next generation high performance electrochemical supercapacitors.

  3. Functionalization of SBA-15 mesoporous silica by Cu-phosphonate units: Probing of synthesis route

    SciTech Connect (OSTI)

    Laskowski, Lukasz; Laskowska, Magdalena

    2014-12-15

    Mesoporous silica SBA-15 containing propyl-copper phosphonate units was investigated. The structure of mesoporous samples was tested by N{sub 2} isothermal sorption (BET and BHJ analysis), TEM microscopy and X-Ray scattering. Quantitative analysis EDX has given information about proportions between component atoms in the sample. Quantitative elemental analysis has been carried out to support EDX. To examine bounding between copper atoms and phosphonic units the Raman spectroscopy was carried out. As a support of Raman scattering, the theoretical calculations were made based on density functional theory, with the B3LYP method. By comparison of the calculated vibrational spectra of the molecule with experimental results, distribution of the active units inside silica matrix has been determined. - Graphical abstract: The present study is devoted to mesoporous silica SBA-15 containing propyl-copper phosphonate units. The species were investigated to confirm of synthesis procedure correctness by the micro-Raman technique combined with DFT numerical simulations. Complementary research was carried out to test the structure of mesoporous samples. - Highlights: • SBA-15 silica functionalized with propyl-copper phosphonate units was synthesized. • Synthesis efficiency probed by Raman study supported with DFT simulations. • Homogenous distribution of active units was proved. • Synthesis route enables precise control of distance between copper ions.

  4. Ion-assisted phase separation in compound films: An alternate route to ordered nanostructures

    SciTech Connect (OSTI)

    Norris, Scott A.

    2013-11-28

    In recent years, observations of highly ordered, hexagonal arrays of self-organized nanostructures on binary or impurity-laced targets under normal-incidence ion irradiation have excited interest in this phenomenon as a potential route to high-throughput, low-cost manufacture of nanoscale devices or nanostructured coatings. The currently prominent explanation for these structures is a morphological instability driven by ion erosion discovered by Bradley and Shipman; however, recent parameter estimates via molecular dynamics simulations suggest that this erosive instability may not be active for the representative GaSb system in which hexagonal structures were first observed. Motivated by recent experimental and numerical evidence suggesting the likely importance of phase separation during thin-film processing, we here generalize the Bradley-Shipman theory to include the effect of ion-assisted phase separation. The resulting system admits a chemically driven finite-wavelength instability that can explain the order of observed patterns even when the erosive Bradley-Shipman instability is inactive. In a relevant simplifying limit, it also provides an intuitive instability criterion similar to results in thin-film deposition, as well as predictions on pattern wavelengths that agree qualitatively with experimental observations. Finally, we identify a characteristic experimental signature that distinguishes the chemical and morphological instabilities and highlights the need for specific additional experimental data on the GaSb system.

  5. The role of processing route on the microstructure of 14YWT nanostructured ferritic alloy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mazumder, B.; Parish, C. M.; Bei, H.; Miller, M. K.

    2015-06-03

    Nanostructured ferritic alloys (NFAs) have outstanding high temperature creep properties and extreme tolerance to radiation damage. To achieve these properties, NFAs are fabricated by mechanical alloying of metallic and yttria powders. Atom probe tomography has demonstrated that milling times of at least 40 h are required to produce a uniform distribution of solutes in the flakes. After milling and hot extrusion, the microstructure consists of -Fe, high number densities of Ti-Y-O-vacancy-enriched nanoclusters, and coarse Y2Ti2O7 and Ti(O,C,N) precipitates on the grain boundaries. In contrast, the as-cast condition consists of -Fe with 50-100 m irregularly-shaped Y2Ti2O7 pyrochlore precipitates with smaller embeddedmore » precipitates with the Al5Y3O12 (yttrium-aluminum garnet) crystal structure indicating that this traditional processing route is not a viable approach to achieve the desired microstructure. The nano-hardnesses were also substantially different, i.e., 4 and 8 GPa for the as-cast and as-extruded conditions, respectively. These differences can be explained by the differences in the microstructure and the effects of the high vacancy content introduced by mechanical alloying, and the strong binding energy of vacancies with O, Ti, and Y atoms retarding diffusion.« less

  6. Robust Maximum Lifetime Routing and Energy Allocation in Wireless Sensor Networks

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Paschalidis, Ioannis Ch.; Wu, Ruomin

    2012-01-01

    We consider the maximum lifetime routing problem in wireless sensor networks in two settings: (a) when nodes’ initial energy is given and (b) when it is subject to optimization. The optimal solution and objective value provide optimal flows and the corresponding predicted lifetime, respectively. We stipulate that there is uncertainty in various network parameters (available energy and energy depletion rates). In setting (a) we show that for specific, yet typical, network topologies, the actual network lifetime will reach the predicted value with a probability that converges to zero as the number of nodes grows large. In setting (b) the samemore » result holds for all topologies. We develop a series of robust problem formulations, ranging from pessimistic to optimistic. A set of parameters enable the tuning of the conservatism of the formulation to obtain network flows with a desirably high probability that the corresponding lifetime prediction is achieved. We establish a number of properties for the robust network flows and energy allocations and provide numerical results to highlight the tradeoff between predicted lifetime and the probability achieved. Further, we analyze an interesting limiting regime of massively deployed sensor networks and essentially solve a continuous version of the problem.« less

  7. Computational Investigations of Trichoderma Reesei Cel7A Suggest New Routes for Enzyme Activity Improvements

    SciTech Connect (OSTI)

    Beckham, G. T.; Payne, C. M.; Bu, L.; Taylor, C. B.; McCabe, C.; Chu, J. W.; Himmel, M. E.; Crowley, M. F.

    2012-01-01

    The Trichoderma reesei Family 7 cellulase (Cel7A) is a key industrial enzyme in the production of biofuels from lignocellulosic biomass. It is a multi-modular enzyme with a Family 1 carbohydrate-binding module, a flexible O-glycosylated linker, and a large catalytic domain. We have used simulation to elucidate new functions for the 3 sub-domains, which suggests new routes to increase the activity of this central enzyme. These findings include new roles for glycosylation, which we have shown can be used to tune the binding affinity. We have also examined the structures of the catalytically-active complex of Cel7A and its non-processive counterpart, Cel7B, engaged on cellulose, which suggests allosteric mechanisms involved in chain binding when these cellulases are complexed on cellulose. Our computational results also suggest that product inhibition varies significantly between Cel7A and Cel7B, and we offer a molecular-level explanation for this observation. Finally, we discuss simulations of the absolute and relative binding free energy of cellulose ligands and various mutations along the CD tunnel, which will affect processivity and the ability of Cel7A (and related enzymes) to digest cellulose. These results highlight new considerations in protein engineering for processive and non-processive cellulases for production of lignocellulosic biofuels.

  8. Evolution of microstructure, texture and inhibitor along the processing route for grain-oriented electrical steels using strip casting

    SciTech Connect (OSTI)

    Liu, Hai-Tao; Yao, Sheng-Jie; Sun, Yu; Gao, Fei; Song, Hong-Yu; Liu, Guo-Huai; Li, Lei; Geng, Dian-Qiao; Liu, Zhen-Yu; Wang, Guo-Dong

    2015-08-15

    In the present work, a regular grade GO sheet was produced successively by strip casting, hot rolling, normalizing annealing, two-stage cold rolling with intermediate annealing, primary recrystallization annealing, secondary recrystallization annealing and purification. The aim of this paper was to characterize the evolution of microstructure, texture and inhibitor along the new processing route by comprehensive utilization of optical microscopy, X-ray diffraction and transmission electron microscopy. It was found that a fine microstructure with the ferrite grain size range of 7–12 μm could be obtained in the primary recrystallization annealed sheet though a very coarse microstructure was produced in the initial as-cast strip. The main finding was that the “texture memory” effect on Goss texture started on the through-thickness intermediate annealed strip after first cold rolling, which was not similar to the “texture memory” effect on Goss texture starting on the surface layers of the hot rolled strip in the conventional production route. As a result, the origin of Goss nuclei capable of secondary recrystallization lied in the grains already presented in Goss orientation in the intermediate annealed strip after first cold rolling. Another finding was that fine and dispersive inhibitors (mainly AlN) were easy to be produced in the primary recrystallization microstructure due to the initial rapid solidification during strip casting and the subsequent rapid cooling, and the very high temperature reheating usually used before hot rolling in the conventional production route could be avoided. - Highlights: • A regular grade grain-oriented electrical steel was produced. • Evolution of microstructure, texture and inhibitor was characterized. • Origin of Goss nuclei lied in the intermediate annealed strip. • A fine primary recrystallization microstructure could be produced. • Effective inhibitors were easy to be obtained in the new processing route.

  9. Route to polarization switching induced by optical injection in vertical-cavity surface-emitting lasers

    SciTech Connect (OSTI)

    Sciamanna, M.; Panajotov, K.

    2006-02-15

    We perform a theoretical investigation of the polarization dynamics in a vertical-cavity surface-emitting laser (VCSEL) subject to orthogonal optical injection, i.e., the injected field has a linear polarization (LP) orthogonal to that of the free-running VCSEL. In agreement with previous experiments [Z. G. Pan et al., Appl. Phys. Lett. 63, 2999 (1993)], an increase of the injection strength may lead to a polarization switching accompanied by an injection locking. We find that this route to polarization switching is typically accompanied by a cascade of bifurcations to wave-mixing dynamics and time-periodic and possibly chaotic regimes. A detailed mapping of the polarization dynamics in the plane of the injection parameters (detuning, injection strength) unveils a large richness of dynamical scenarios. Of particular interest is the existence of another injection-locked solution for which the two LP modes both lock to the master laser frequency, i.e., an elliptically polarized injection-locked (EPIL) steady state. Modern continuation techniques allow us to unveil an unfolding mechanism of the EPIL solution as the detuning varies and also to link the existence of the EPIL solution to a resonance condition between the master laser frequency and the free-running frequency of the normally depressed LP mode in the slave laser. We furthermore report an additional case of bistability, in which the EPIL solution may coexist with the second injection-locked solution (the one being locked to the master polarization). This case of bistability is a result of the interaction between optical injection and the two-polarization-mode characteristics of VCSEL devices.

  10. Facile route of biopolymer mediated ferrocene (FO) nanoparticles in aqueous dispersion

    SciTech Connect (OSTI)

    Kaus, Noor Haida Mohd.; Collins, A. M.; Mann, S.

    2014-10-24

    In this paper, we present a facile method for production stable aqueous dispersion of ferrocene (FO) nanoparticles. Ferrocene compounds were employed to achieve stable nanodispersions, stabilized with three different biopolymers namely, alginate, CM-dextran and chitosan. The nanoparticles produce are spherical, less than 10 nm in mean diameter and highly stable without any sedimentation. Fourier infrared transform (FTIR) and X-ray diffraction (XRD) studies confirmed the purity of ferrocene nanoparticles there is no modifications occur during the preparation route. FTIR spectra results were consistent with the presence of absorption band of cyclopentadienyl ring (C{sub 5}H{sub 5}{sup −} ion) which assigned to ν(C-C) vibrations (1409 cm-1), δ(C-H) stretching at 1001 cm{sup −1} and π(C-H) vibrations at 812 cm{sup −1}. Furthermore, all functional group for biopolymers such as CO from carboxyl group of CM-dextran and sodium alginate appears at 1712 cm{sup −1} and 1709 cm{sup −1} respectively, indicating there are steric repulsion interactions for particles stabilization. Powder X-ray diffraction patterns of sedimented samples of the biopolymers-stabilized ferrocene (FO) showed all reflections which were indexed respectively to the (−110), (001), (−201), (−111), (200), (−211), (210), (120) and (111) according to the monoclinic phase ferrocene. This confirmed that the products obtained were of high purity of Fe and EDAX analysis also suggests that the presence of the Fe element in the colloidal dispersion.

  11. Landslide remediation on Ohio State Route 83 using clean coal combustion by-products

    SciTech Connect (OSTI)

    Payette, R.; Chen, X.Y.; Wolfe, W.; Beeghly, J.

    1995-12-31

    In the present work, a flue gas desulfurization (FGD) by-product was used to reconstruct the failed portion of a highway embankment. The construction process and the stability of the repaired embankment are examined. State Route 83 in Cumberland, Ohio has been damaged by a slow moving slide which has forced the Ohio Department of Transportation to repair the roadway several times. In the most recent repair FGD by-products obtained from American Electric Power`s Tidd PFBC plant were used to construct a wall through the failure plane to prevent further slippage. In order to evaluate the utility of using coal combustion by-products in this type of highway project the site was divided into three test sections. In the first repair section, natural soil removed form the slide area was recompacted and replaced according to standard ODOT construction practices. In the second section the natural soil was field mixed with the Tidd PFBC ash in approximately equal proportions. The third section was all Tidd ash. The three test sections were capped by a layer of compacted Tidd ash or crushed stone to provide a wearing surface to allow ODOT to open the roadway before applying a permanent asphalt surface. Measurement of slope movement as well as water levels and quality have begun at the site in order to evaluate long term project performance. The completion of this project should lead to increased acceptance of FGD materials in construction projects. Monetary savings will be realized in avoiding some of the disposal costs for the waste, as well as in the reduced reliance on alternative engineering materials.

  12. Synthesis of sulfonated porous carbon nanospheres solid acid by a facile chemical activation route

    SciTech Connect (OSTI)

    Chang, Binbin Guo, Yanzhen; Yin, Hang; Zhang, Shouren; Yang, Baocheng

    2015-01-15

    Generally, porous carbon nanospheres materials are usually prepared via a template method, which is a multi-steps and high-cost strategy. Here, we reported a porous carbon nanosphere solid acid with high surface area and superior porosity, as well as uniform nanospheical morphology, which prepared by a facile chemical activation with ZnCl{sub 2} using resorcinol-formaldehyde (RF) resins spheres as precursor. The activation of RF resins spheres by ZnCl{sub 2} at 400 C brought high surface area and large volume, and simultaneously retained numerous oxygen-containing and hydrogen-containing groups due to the relatively low processing temperature. The presence of these functional groups is favorable for the modification of SO{sub 3}H groups by a followed sulfonation treating with sulphuric acid and organic sulfonic acid. The results of N{sub 2} adsorptiondesorption and electron microscopy clearly showed the preservation of porous structure and nanospherical morphology. Infrared spectra certified the variation of surface functional groups after activation and the successful modification of SO{sub 3}H groups after sulfonation. The acidities of catalysts were estimated by an indirect titration method and the modified amount of SO{sub 3}H groups were examined by energy dispersive spectra. The results suggested sulfonated porous carbon nanospheres catalysts possessed high acidities and SO{sub 3}H densities, which endowed their significantly catalytic activities for biodiesel production. Furthermore, their excellent stability and recycling property were also demonstrated by five consecutive cycles. - Graphical abstract: Sulfonated porous carbon nanospheres with high surface area and superior catalytic performance were prepared by a facile chemical activation route. - Highlights: Porous carbon spheres solid acid prepared by a facile chemical activation. It owns high surface area, superior porosity and uniform spherical morphology. It possesses high acidity and

  13. Facile route to hierarchical silver microstructures with high catalytic activity for the reduction of p-nitrophenol

    SciTech Connect (OSTI)

    Gu, Sasa; Wang, Wei Tan, Fatang; Gu, Jian; Qiao, Xueliang; Chen, Jianguo

    2014-01-01

    Graphical abstract: - Highlights: • A facile route was developed to prepare hierarchical silver microstructures. • The shape and size of secondary units can be tailed by varying reaction conditions. • Hierarchical silver microstructures have excellent catalytic activity. • The morphology and crystallinity of silver particles affect the catalytic activity. - Abstract: A facile, cost-effective and environmentally friendly route was developed to synthesize hierarchical silver microstructures consisting of different shaped secondary units through reducing concentrated silver nitrate with ascorbic acid in the absence of any surfactant. The as-obtained samples were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). The investigation on the morphology evolution revealed that the molar ratio of ascorbic acid to silver nitrate was critical to control the shape of secondary structures. The length of plate-like secondary structures which composed hierarchical silver particles could be controlled by changing the reactant concentrations, and it had a key relationship with the catalytic activity for the reduction of p-nitrophenol by NaBH{sub 4}. The catalytic activity of these surfactant-free silver microstructures was about ten times higher than that of silver nanoparticles, and even comparable to that of gold nanoplates, which indicates that the as-obtained silver microstructures are very promising candidates for the catalytic reduction of p-nitrophenol due to the simple synthesis route and high catalytic activity.

  14. Solar UV radiation exposure of seamen - Measurements, calibration and model calculations of erythemal irradiance along ship routes

    SciTech Connect (OSTI)

    Feister, Uwe; Meyer, Gabriele; Kirst, Ulrich

    2013-05-10

    Seamen working on vessels that go along tropical and subtropical routes are at risk to receive high doses of solar erythemal radiation. Due to small solar zenith angles and low ozone values, UV index and erythemal dose are much higher than at mid-and high latitudes. UV index values at tropical and subtropical Oceans can exceed UVI = 20, which is more than double of typical mid-latitude UV index values. Daily erythemal dose can exceed the 30-fold of typical midlatitude winter values. Measurements of erythemal exposure of different body parts on seamen have been performed along 4 routes of merchant vessels. The data base has been extended by two years of continuous solar irradiance measurements taken on the mast top of RV METEOR. Radiative transfer model calculations for clear sky along the ship routes have been performed that use satellite-based input for ozone and aerosols to provide maximum erythemal irradiance and dose. The whole data base is intended to be used to derive individual erythemal exposure of seamen during work-time.

  15. Method and apparatus for routing data in an inter-nodal communications lattice of a massively parallel computer system by dynamic global mapping of contended links

    DOE Patents [OSTI]

    Archer, Charles Jens; Musselman, Roy Glenn; Peters, Amanda; Pinnow, Kurt Walter; Swartz, Brent Allen; Wallenfelt, Brian Paul

    2011-10-04

    A massively parallel nodal computer system periodically collects and broadcasts usage data for an internal communications network. A node sending data over the network makes a global routing determination using the network usage data. Preferably, network usage data comprises an N-bit usage value for each output buffer associated with a network link. An optimum routing is determined by summing the N-bit values associated with each link through which a data packet must pass, and comparing the sums associated with different possible routes.

  16. An aqueous route to [Ta6O19]8- and solid-state studies of isostructural niobium and tantalum oxide complexes.

    SciTech Connect (OSTI)

    Nyman, May D.; Anderson, Travis Mark; Alam, Todd M.; Rodriguez, Mark Andrew; Joel N. Bixler; Francois Bonhomme

    2007-10-01

    Tantalate materials play a vital role in our high technology society: tantalum capacitors are found in virtually every cell phone. Furthermore, electronic characteristics and the incredibly inert nature of tantalates renders them ideal for applications such as biomedical implants, nuclear waste forms, ferroelectrics, piezoelectrics, photocatalysts and optical coatings. The inert and insoluble nature of tantalates is not fundamentally understood; and furthermore poor solubility renders fabrication of novel or optimized tantalates very difficult. We have developed a soft chemical route to water-soluble tantalum oxide clusters that can serve as both precursors for novel tantalate materials and ideal models for experimental and computational approaches to understanding the unusually inert behavior of tantalates. The water soluble cluster, [Ta6O19]8- is small, highly symmetric, and contains the representative oxygen types of a metal oxide surface, and thus ideally mimics a complex tantalate surface in a simplistic form that can be studied unambiguously. Furthermore; in aqueous solution, these highly charged and super-basic clusters orchestrate surprising acid-base behavior that most likely plays an important role in the inertness of related oxide surfaces. Our unique synthetic approach to the [Ta6O19]8- cluster allowed for unprecedented enrichment with isotopic labels (17O), enabling detailed kinetic and mechanistic studies of the behavior of cluster oxygens, as well as their acid-base behavior. This SAND report is a collection of two publications that resulted from these efforts.

  17. Evaluation of oil tanker routing per section 4111(b)(7) of the Oil Pollution Act of 1990. Part 1. Pacific coast. Final report

    SciTech Connect (OSTI)

    1996-02-01

    The purpose of this study is to evaluate oil tanker routing along the Pacific Coast to determine whether areas of navigable waters and the Exclusive Economic Zone should be restricted to oil tankers.

  18. Evaluation of oil tanker routing per section 4111(b)(7) Oil Pollution Act of 1990. Part 2. Atlantic and Florida Gulf coasts. Final report

    SciTech Connect (OSTI)

    1996-08-01

    The purpose of this study is to evaluate oil tanker routing along the east coast and Florida Gulf Coast. It discusses whether areas of navigable waters and the Exclusive Economic Zone should be restricted to oil tankers.

  19. Methanol Oxidative Dehydrogenation on Oxide Catalysts: Molecular and Dissociative Routes and Hydrogen Addition Energies as Descriptors of Reactivity

    SciTech Connect (OSTI)

    Deshlahra, Prashant; Iglesia, Enrique

    2014-11-13

    The oxidative dehydrogenation (ODH) of alkanols on oxide catalysts is generally described as involving H-abstraction from alkoxy species formed via OH dissociation. Kinetic and isotopic data cannot discern between such routes and those involving kinetically-relevant H-abstraction from undissociated alkanols. Here, we combine such experiments with theoretical estimates of activation energies and entropies to show that the latter molecular routes prevail over dissociative routes for methanol reactions on polyoxometalate (POM) clusters at all practical reaction temperatures. The stability of the late transition states that mediate H-abstraction depend predominantly on the stability of the OH bond formed, making H-addition energies (HAE) accurate and single-valued descriptors of reactivity. Density functional theory-derived activation energies depend linearly on HAE values at each O-atom location on clusters with a range of composition (H3PMo12, H4SiMo12, H3PW12, H4PV1Mo11, and H4PV1W11); both barriers and HAE values reflect the lowest unoccupied molecular orbital energy of metal centers that accept the electron and the protonation energy of O-atoms that accept the proton involved in the H-atom transfer. Bridging O-atoms form OH bonds that are stronger than those of terminal atoms and therefore exhibit more negative HAE values and higher ODH reactivity on all POM clusters. For each cluster composition, ODH turnover rates reflect the reactivity-averaged HAE of all accessible O-atoms, which can be evaluated for each cluster composition to provide a rigorous and accurate predictor of ODH reactivity for catalysts with known structure. These relations together with oxidation reactivity measurements can then be used to estimate HAE values and to infer plausible structures for catalysts with uncertain active site structures.

  20. The effect of different annealing temperatures on tin and cadmium telluride phases obtained by a modified chemical route

    SciTech Connect (OSTI)

    Mesquita, Anderson Fuzer; Porto, Arilza de Oliveira; Magela de Lima, Geraldo; Paniago, Roberto; Ardisson, Jos Domingos

    2012-11-15

    Graphical abstract: Display Omitted Highlights: ? Synthesis of cadmium and tin telluride. ? Chemical route to obtain pure crystalline cadmium and tin telluride. ? Effect of the annealing temperature on the crystalline phases. ? Removal of tin oxide as side product through thermal treatment. -- Abstract: In this work tin and cadmium telluride were prepared by a modification of a chemical route reported in the literature to obtain metallacycles formed by oxidative addition of tin-tellurium bonds to platinum (II). Through this procedure it was possible to obtain tin and cadmium telluride. X-ray diffraction and X-ray photoelectron spectroscopy were used to identify the crystalline phases obtained as well as the presence of side products. In the case of tin telluride it was identified potassium chloride, metallic tellurium and tin oxide as contaminants. The tin oxidation states were also monitored by {sup 119}Sn Mssbauer spectroscopy. The annealing in hydrogen atmosphere was chosen as a strategy to reduce the tin oxide and promote its reaction with the excess of tellurium present in the medium. The evolution of this tin oxide phase was studied through the annealing of the sample at different temperatures. Cadmium telluride was obtained with high degree of purity (98.5% relative weight fraction) according to the Rietveld refinement of X-ray diffraction data. The modified procedure showed to be very effective to obtain amorphous tin and cadmium telluride and the annealing at 450 C has proven to be useful to reduce the amount of oxide produced as side product.

  1. Preparation of Al{sub 2}O{sub 3}/Mo nanocomposite powder via chemical route and spray drying

    SciTech Connect (OSTI)

    Lo, M.; Cheng, F.; Wei, W.J.

    1996-08-01

    A route to prepare nanometer-sized Mo particulates in Al{sub 2}O{sub 3} was attempted by a combination of solution reactions in molecular scale and forcing precipitation by a spray-drying technique. MoO{sub 3} was first dissolved in ammonia water and then added in the slurry with high purity, submicrometer Al{sub 2}O{sub 3} powder. Mixed suspension was spray-dried, and then the dried granules were reduced by hydrogen gas and further hot-pressing to a bulky composite at various temperatures. Dissolution of Mo oxide, adsorption reactions on alumina surface, and surface potential of alumina particles in homogeneous ammonia suspension were studied. Characterization of the granules, including compactability, flowing properties, surface morphology, grain growth of Mo and Al{sub 2}O{sub 3}, and mixing homogeneity, were examined. Homogeneity of the spray-dried granules was determined by the calculation of mixing index and the observation of the microstructure of sintered body. The existence of intergranular, intragranular, and nanosized Mo particulates within Al{sub 2}O{sub 3} grains was observed by transmission electron microscopy (TEM). All the evidences revealed that homogeneous composites with nanometer-sized Mo had been successfully prepared by this attempt with the proposed chemical route and following spray-drying process. {copyright}{ital 1996 Materials Research Society.}

  2. Dual reorientation relaxation routes of water molecules in oxyanion’s hydration shell: A molecular geometry perspective

    SciTech Connect (OSTI)

    Xie, Wen Jun; Yang, Yi Isaac; Gao, Yi Qin

    2015-12-14

    In this study, we examine how complex ions such as oxyanions influence the dynamic properties of water and whether differences exist between simple halide anions and oxyanions. Nitrate anion is taken as an example to investigate the hydration properties of oxyanions. Reorientation relaxation of its hydration water can occur through two different routes: water can either break its hydrogen bond with the nitrate to form one with another water or switch between two oxygen atoms of the same nitrate. The latter molecular mechanism increases the residence time of oxyanion’s hydration water and thus nitrate anion slows down the translational motion of neighbouring water. But it is also a “structure breaker” in that it accelerates the reorientation relaxation of hydration water. Such a result illustrates that differences do exist between the hydration of oxyanions and simple halide anions as a result of different molecular geometries. Furthermore, the rotation of the nitrate solute is coupled with the hydrogen bond rearrangement of its hydration water. The nitrate anion can either tilt along the axis perpendicularly to the plane or rotate in the plane. We find that the two reorientation relaxation routes of the hydration water lead to different relaxation dynamics in each of the two above movements of the nitrate solute. The current study suggests that molecular geometry could play an important role in solute hydration and dynamics.

  3. Structural and optical properties of ZnO: K synthesized by sol-gel auto-combustion route

    SciTech Connect (OSTI)

    Krithiga, R. Sankar, S.; Subhashree, G.; Bharathi, R. Niruban

    2015-06-24

    The structural and optical behavior of ZnO and ZnO doped with K synthesized by solution combustion route is reported in this article. The XRD patterns confirm the substitution of K atoms into ZnO lattice. There are no secondary peaks observed in the XRD patterns. The band gap of the K doped samples show a red shift on comparison with the bandgap of ZnO. The photoluminescence spectral study discloses the quenching behavior of UV emission and the aggrandizing blue emission when K content increases. The rich presence of defects is confirmed from the optical analysis and a practical mechanism, involving Zn{sub i} for the origin of the blue emission in ZnO is discussed here.

  4. Walk the Line: The Development of Route Selection Standards for Spent Nuclear Fuel and High-level Radioactive Waste in the United States - 13519

    SciTech Connect (OSTI)

    Dilger, Fred; Halstead, Robert J.; Ballard, James D.

    2013-07-01

    Although storage facilities for spent nuclear fuel (SNF) and high-level radioactive waste (HLRW) are widely dispersed throughout the United States, these materials are also relatively concentrated in terms of geographic area. That is, the impacts of storage occur in a very small geographic space. Once shipments begin to a national repository or centralized interim storage facility, the impacts of SNF and HLRW will become more geographically distributed, more publicly visible, and almost certainly more contentious. The selection of shipping routes will likely be a major source of controversy. This paper describes the development of procedures, regulations, and standards for the selection of routes used to ship spent nuclear fuel and high-level radioactive waste in the United States. The paper begins by reviewing the circumstances around the development of HM-164 routing guidelines. The paper discusses the significance of New York City versus the Department of Transportation and application of HM-164. The paper describes the methods used to implement those regulations. The paper will also describe the current HM-164 designated routes and will provide a summary data analysis of their characteristics. This analysis will reveal the relatively small spatial scale of the effects of HM 164. The paper will then describe subsequent developments that have affected route selection for these materials. These developments include the use of 'representative routes' found in the Department of Energy (DOE) 2008 Supplemental Environmental Impact Statement for the formerly proposed Yucca Mountain geologic repository. The paper will describe recommendations related to route selection found in the National Academy of Sciences 2006 report Going the Distance, as well as recommendations found in the 2012 Final Report of the Blue Ribbon Commission on America's Nuclear Future. The paper will examine recently promulgated federal regulations (HM-232) for selection of rail routes for hazardous

  5. Real-time global flood estimation using satellite-based precipitation and a coupled land surface and routing model

    SciTech Connect (OSTI)

    Wu, Huan; Adler, Robert F.; Tian, Yudong; Huffman, George J.; Li, Hongyi; Wang, JianJian

    2014-03-01

    A widely used land surface model, the Variable Infiltration Capacity (VIC) model, is coupled with a newly developed hierarchical dominant river tracing-based runoff-routing model to form the Dominant river tracing-Routing Integrated with VIC Environment (DRIVE) model, which serves as the new core of the real-time Global Flood Monitoring System (GFMS). The GFMS uses real-time satellite-based precipitation to derive flood monitoring parameters for the latitude band 50°N–50°S at relatively high spatial (~12 km) and temporal (3 hourly) resolution. Examples of model results for recent flood events are computed using the real-time GFMS (http://flood.umd.edu). To evaluate the accuracy of the new GFMS, the DRIVE model is run retrospectively for 15 years using both research-quality and real-time satellite precipitation products. Evaluation results are slightly better for the research-quality input and significantly better for longer duration events (3 day events versus 1 day events). Basins with fewer dams tend to provide lower false alarm ratios. For events longer than three days in areas with few dams, the probability of detection is ~0.9 and the false alarm ratio is ~0.6. In general, these statistical results are better than those of the previous system. Streamflow was evaluated at 1121 river gauges across the quasi-global domain. Validation using real-time precipitation across the tropics (30°S–30°N) gives positive daily Nash-Sutcliffe Coefficients for 107 out of 375 (28%) stations with a mean of 0.19 and 51% of the same gauges at monthly scale with a mean of 0.33. Finally, there were poorer results in higher latitudes, probably due to larger errors in the satellite precipitation input.

  6. A sol-gel route for the development of rare-earth aluminum borate nanopowders and transparent thin films

    SciTech Connect (OSTI)

    Maia, Lauro J.Q. Mastelaro, Valmor R.; Hernandes, Antonio C.

    2007-02-15

    A new sol-gel route was applied to obtain Y{sub 0.9}Er{sub 0.1}Al{sub 3}(BO{sub 3}){sub 4} crystalline powders and amorphous thin films by using Al(acac){sub 3}, B(OPr {sup i}){sub 3}, Y(NO{sub 3}){sub 3}.6H{sub 2}O, and Er(NO{sub 3}){sub 3}.5H{sub 2}O as starting materials dissolved in propionic acid and ethyl alcohol mixtures. Our study shows that propionic acid acts as good chelant agent for yttrium and erbium ions while ethyl alcohol allows to dissolve Al(acac){sub 3}. This process makes the resulting sols very stable to obtain homogeneous gels and transparent amorphous thin films. In addition, the propionic acid prevents the sol precipitation, making easy porous- and crack-free thin film depositions. Chemical reactions involved in the complexation were discussed. As-prepared powders and films are amorphous and present a good thermal stability due to their high glass transition (746 deg. C) and crystallization temperatures (830 deg. C). This new sol-gel route showed to be adequate to obtain dense and crack-free thin films free of organic and hydroxyl groups that can be considered as promising materials to be used in integrated optical systems. - Graphical abstract: SEM micrograph of Y{sub 0.9}Er{sub 0.1}Al{sub 3}(BO{sub 3}){sub 4} powders calcined at 400 and 700 deg. C during 24 h and heat-treated at 1150 deg. C.

  7. Route-Specific Passage Proportions and Survival Rates for Fish Passing through John Day Dam, The Dalles Dam, and Bonneville Dam in 2010 and 2011

    SciTech Connect (OSTI)

    Ploskey, Gene R.; Weiland, Mark A.; Carlson, Thomas J.

    2012-06-04

    This report fulfills a request of the U.S. Army Engineer District, Portland, Oregon, to produce an interim report of estimates of route-specific fish passage proportions and survival rates for lower Columbia River dams in 2010 and 2011. The estimates are needed to update the Compass Model for the Columbia River Treaty and the new Biological Opinion before detail technical reports are published in late 2012. This report tabulates route-specific fish-passage proportions and survival rates for steelhead and Chinook salmon smolts passing through various sampled routes at John Day Dam, The Dalles Dam, and Bonneville Dam in 2010 and 2011. Results were compiled from analyses of data acquired in spring 2010 and 2011 studies that were specifically designed to estimate dam-passage and forebay-to-tailrace survival rates, travel time metrics, and spill passage efficiency, as stipulated by the 2008 Federal Columbia River Power System Biological Opinion and the Columbia Basin Fish Accords. The study designs allowed for estimation of route-specific fish passage proportions and survival rates as well as estimation of forebay-passage survival, all of which are summarized herein.

  8. Phase stability, mechanical properties, hardness, and possible reactive routing of chromium triboride from first-principle investigations

    SciTech Connect (OSTI)

    Zhong, Ming-Min; Kuang, Xiao-Yu Wang, Zhen-Hua; Shao, Peng; Ding, Li-Ping; Huang, Xiao-Fen

    2013-12-21

    The first-principles calculations are employed to provide a fundamental understanding of the structural features and relative stability, mechanical and electronic properties, and possible reactive route for chromium triboride. The predicted new phase of CrB{sub 3} belongs to the rhombohedral phase with R-3m symmetry and it transforms into a hexagonal phase with P-6m2 symmetry at 64 GPa. The mechanical and thermodynamic stabilities of CrB{sub 3} are verified by the calculated elastic constants and formation enthalpies. Also, the full phonon dispersion calculations confirm the dynamic stability of predicted CrB{sub 3}. Considering the role of metallic contributions, the calculated hardness values from our semiempirical method for rhombohedral and hexagonal phases are 23.8 GPa and 22.1 GPa, respectively. In addition, the large shear moduli, Young's moduli, low Poisson's ratios, and small B/G ratios indicate that they are potential hard materials. Relative enthalpy calculations with respect to possible constituents are also investigated to assess the prospects for phase formation and an attempt at high-pressure synthesis is suggested to obtain chromium triboride.

  9. Azine bridged silver coordination polymers: Powder X-ray diffraction route to crystal structure determination of silver benzotriazole

    SciTech Connect (OSTI)

    Rajeswaran, Manju . E-mail: manju.rajeswaran@kodak.com; Blanton, Thomas N.; Giesen, David J.; Whitcomb, David R.; Zumbulyadis, Nicholas; Antalek, Brian J.; Neumann, Marcus M.; Misture, Scott T.

    2006-04-15

    In continuation of our interest in solid-state structures of silver complexes of photographic importance, the structure for silver benzotriazole (AgBZT), has now been obtained. The preferred method for solving crystal structures is via single-crystal X-ray diffraction (XRD). However, for some materials, growing single crystals of appropriate size and quality is often difficult or even impossible. AgBZT is an example of such a silver complex with poor solubility. The usual routes to preparing single crystals using recrystallization from a cooperating solvent resulted in polycrystalline powder samples. We propose a crystal structure for AgBZT, solved from synchrotron X-ray powder diffraction data, using a direct-space Monte Carlo simulated annealing approach. AgBZT crystals are monoclinic (P2{sub 1} /c), with unit cell dimensions, a=14.8052(3) A, b=3.7498(4) A, c=12.3495(12) A, and {beta}=114.200(6){sup o}. The AgBZT complex is constructed from all three of the Benzotriazole (BZT) nitrogens bonding to a separate silver atom. As a consequence of this bonding mode, the structure is a highly cross-linked, coordination polymer.

  10. Route-Specific Passage and Survival of Steelhead Kelts at The Dalles and Bonneville Dams, 2012 - Final Report

    SciTech Connect (OSTI)

    Rayamajhi, Bishes; Ploskey, Gene R.; Woodley, Christa M.; Weiland, Mark A.; Faber, Derek M.; Kim, Jin A.; Colotelo, Alison HA; Deng, Zhiqun; Fu, Tao

    2013-07-31

    This study was mainly focused on evaluating the route-specific passage and migration success of steelhead kelts passing downstream through The Dalles Dam (TDA) and Bonneville Dam (BON) at Columbia River (CR) river kilometers 309 and 234 respectively. Oregon Department of Fish and Wildlife (ODFW) personnel collected, tagged and released out-migrating steelhead kelts in the tributaries of the Deschutes River, 15 Mile Creek and Hood River between April 14 and June 4, 2012. A PIT tag was injected into each kelt’s dorsal sinus whereas a Juvenile Salmon Acoustic Telemetry System (JSATS) acoustic micro-transmitter was attached to an external FLoy T-bar tag and inserted into the dorsal back musculature using a Floy tagging gun. JSATS cabled arrays were deployed at TDA and BON and autonomous node arrays were deployed near Celilo, Oregon (CR325); the BON forebay (CR236); the BON tailrace (CR233); near Knapp, Washington (CR156); and near Kalama, Washington (CR113) to monitor the kelts movement while passing through the dams and above mentioned river cross-sections.

  11. New sol-gel synthetic route to transition and main-group metal oxide aerogels using inorganic salt precursors

    SciTech Connect (OSTI)

    Gash, A E; Tillotson, T M; Satcher Jr, J H; Hrubesh, L W; Simpson, R L

    2000-09-12

    We have developed a new sol-gel route to synthesize several transition and main-group metal oxide aerogels. The approach is straightforward, inexpensive, versatile, and it produces monolithic microporous materials with high surface areas. Specifically, we report the use of epoxides as gelation agents for the sol-gel synthesis of chromia aerogels and xerogels from simple Cr(III) inorganic salts. The dependence of both gel formation and its rate was studied by varying the solvent used, the Cr(III) precursor salt, the epoxide/Cr(III) ratio, as well as the type of epoxide employed. All of these variables were shown to affect the rate of gel formation and provide a convenient control of this parameter. Dried chromia aerogels were characterized by high-resolution transmission electron microscopy (HRTEM) and nitrogen adsorption/desorption analyses, results of which will be presented. Our studies have shown that rigid monolithic gels can be prepared from many different metal ions salts, provided the formal oxidation state of the metal ion is greater than or equal to +3. Conversely, when di-valent transition metal salts are used precipitated solids are the products.

  12. The Microscopic Magnetic Properties of W-type Hexaferrite Powder Prepared by A Sol-Gel Route

    SciTech Connect (OSTI)

    Jotania, Rajshree; Chauhan, Chetna; Sharma, Pooja

    2010-12-01

    Magnetic particles of W-type barium-calcium hexaferrite (BaCa{sub 2}Fe{sub 16}O{sub 27}) have been synthesized using a Stearic acid gel route. The gel precursors were dried at 100 deg. C for 2 hrs and then calcinated at 650 deg. C, 750 deg. C, 850 deg. C and 950 deg. C for 4 hrs in a furnace and slowly cooled to room temperature in order to obtain barium-calcium hexaferrite particles. The microscopic magnetic properties of prepared samples studying using Moessbauer spectroscopy. Moessbauer spectra of all samples were recorded at room temperature. Mossbauer parameters like Isomer shift, Quadruple splitting etc. were calculated with respect to iron foil. Barium calcium hexaferrite samples heated at 650 deg. C, 750 deg. C, 850 deg. C show relaxation type Moessbauer spectra along with paramagnetic doublet. The intensity of paramagnetic doublet increases with temperature confirm the presence of ferrous ions in the samples, where as sample calcinated at 950 deg. C confirm the presence of ferrimagnetic phase with partial super paramagnetic nature of prepared hexaferrite sample.

  13. Facile synthesis of Ba1-xKxFe?As? superconductors via hydride route

    SciTech Connect (OSTI)

    Zaikina, Julia V. [Univ. of California at Davis, Davis, CA (United States); Batuk, Maria [Univ. of Antwerp, Antwerp (Belgium); Abakumov, Artem M. [Univ. of Antwerp, Antwerp (Belgium); Navrotsky, Alexandra [Univ. of California at Davis, Davis, CA (United States); Kauzlarich, Susan M. [Univ. of California at Davis, Davis, CA (United States)

    2014-12-03

    We have developed a fast, easy, and scalable synthesis method for Ba1-xKxFe?As? (0 ? x ? 1) superconductors using hydrides BaH? and KH as a source of barium and potassium metals. Synthesis from hydrides provides better mixing and easier handling of the starting materials, consequently leading to faster reactions and/or lower synthesis temperatures. The reducing atmosphere provided by the evolved hydrogen facilitates preparation of oxygen-free powders. By a combination of methods we have shown that Ba1-xKxFe?As? obtained via hydride route has the same characteristics as when it is prepared by traditional solid-state synthesis. Refinement from synchrotron powder X-ray diffraction data confirms a linear dependence of unit cell parameters upon K content as well as the tetragonal to orthorhombic transition at low temperatures for compositions with x < 0.2. Magnetic measurements revealed dome-like dependence of superconducting transition temperature Tc upon K content with a maximum of 38 K for x close to 0.4. Electron diffraction and high-resolution high-angle annular dark-field scanning transmission electron microscopy indicates an absence of Ba/K ordering, while local inhomogeneity in the Ba/K distribution takes place at a scale of several angstroms along [110] crystallographic direction.

  14. Tracking a defined route for O[subscript 2] migration in a dioxygen-activating diiron enzyme

    SciTech Connect (OSTI)

    Song, Woon Ju; Gucinski, Grant; Sazinsky, Matthew H.; Lippard, Stephen J. (MIT); (Pomona)

    2011-09-08

    For numerous enzymes reactive toward small gaseous compounds, growing evidence indicates that these substrates diffuse into active site pockets through defined pathways in the protein matrix. Toluene/o-xylene monooxygenase hydroxylase is a dioxygen-activating enzyme. Structural analysis suggests two possible pathways for dioxygen access through the {alpha}-subunit to the diiron center: a channel or a series of hydrophobic cavities. To distinguish which is utilized as the O{sub 2} migration pathway, the dimensions of the cavities and the channel were independently varied by site-directed mutagenesis and confirmed by X-ray crystallography. The rate constants for dioxygen access to the diiron center were derived from the formation rates of a peroxodiiron(III) intermediate, generated upon treatment of the diiron(II) enzyme with O2. This reaction depends on the concentration of dioxygen to the first order. Altering the dimensions of the cavities, but not the channel, changed the rate of dioxygen reactivity with the enzyme. These results strongly suggest that voids comprising the cavities in toluene/o-xylene monooxygenase hydroxylase are not artifacts of protein packing/folding, but rather programmed routes for dioxygen migration through the protein matrix. Because the cavities are not fully connected into the diiron active center in the enzyme resting state, conformational changes will be required to facilitate dioxygen access to the diiron center. We propose that such temporary opening and closing of the cavities may occur in all bacterial multicomponent monooxygenases to control O{sub 2} consumption for efficient catalysis. Our findings suggest that other gas-utilizing enzymes may employ similar structural features to effect substrate passage through a protein matrix.

  15. Route Type Determination Analysis

    SciTech Connect (OSTI)

    Brett Stone

    2011-09-01

    According to the 2009 National Household Travel Survey 44.4 percent of all miles travelled by Americans in 2009 (including airplanes, trains, boats, golf carts, subways, bikes, etc.) were travelled in cars. If vans, SUV's and pickup trucks are included, that level increases to 86 percent. We do a lot of travelling on the road in personal vehicles - it's important to be able to understand how we get there and how to rate the fuel economy of our trips. An essential part of this is knowing how to decide if a trip is a city or highway trip.

  16. Laboratory Shuttle Bus Routes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    UC Campus, Downtown Berkeley BART, and Rockridge BART stations. Shuttles offer free wifi onboard. Riders are asked to adhere to riding instructions. Active shuttle stops are...

  17. Electron beam induced structural evolution in Fe{sub 3}O{sub 4}/SiO{sub 2} particles: A new route to obtain movable core structures

    SciTech Connect (OSTI)

    Lv, Baoliang; Xu, Yao; Wu, Dong; Sun, Yuhan; Low Carbon Conversion Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201203

    2011-06-15

    Graphical abstract: SiO{sub 2} hollow spheres with movable Fe{sub 3}O{sub 4} cores were obtained by exposing the Fe{sub 3}O{sub 4}/SiO{sub 2} particles to the electron beam of TEM. It is a new route to obtain movable core nanostructures. Research highlights: {yields} SiO{sub 2} hollow particles with movable Fe{sub 3}O{sub 4} cores were obtained. {yields} Irradiation of electron beam induced the structural evolution. {yields} A new route to obtain hollow particles with movable core. -- Abstract: SiO{sub 2} hollow spheres with movable Fe{sub 3}O{sub 4} core were obtained by exposing the pre-synthesized Fe{sub 3}O{sub 4}/SiO{sub 2} particles (with an adsorption interlayer of ethylene glycol) under the irradiation of electron beam inside transmission electron micrograph (TEM). In the formation process, the evaporation of adsorbed ethylene glycol and the evolution of amorphous SiO{sub 2} layer played important roles, and that should be attributed to the high temperature and trapped charges induced by the irradiation of electron beam. This work provided a new route to obtain particles with movable core structure and extended the applications of electron beam.

  18. Lambda network having 2.sup.m-1 nodes in each of m stages with each node coupled to four other nodes for bidirectional routing of data packets between nodes

    DOE Patents [OSTI]

    Napolitano, Jr., Leonard M.

    1995-01-01

    The Lambda network is a single stage, packet-switched interprocessor communication network for a distributed memory, parallel processor computer. Its design arises from the desired network characteristics of minimizing mean and maximum packet transfer time, local routing, expandability, deadlock avoidance, and fault tolerance. The network is based on fixed degree nodes and has mean and maximum packet transfer distances where n is the number of processors. The routing method is detailed, as are methods for expandability, deadlock avoidance, and fault tolerance.

  19. A new continuous two-step molecular precursor route to rare-earth oxysulfides Ln{sub 2}O{sub 2}S

    SciTech Connect (OSTI)

    De Crom, N.

    2012-07-15

    A continuous two-step molecular precursor pathway is designed for the preparation of rare-earth oxysulfides Ln{sub 2}O{sub 2}S (Ln=Y, La, Pr, Nd, Sm-Lu). This new route involves a first oxidation step leading to the rare-earth oxysulfate Ln{sub 2}O{sub 2}SO{sub 4} which is subsequently reduced to the rare-earth oxysulfide Ln{sub 2}O{sub 2}S by switching to a H{sub 2}-Ar atmosphere. The whole process occurs at a temperature significantly lower than usual solid state synthesis (T{<=}650 Degree-Sign C) and avoids the use of dangerous sulfur-based gases, providing a convenient route to the synthesis of the entire series of Ln{sub 2}O{sub 2}S. The molecular precursors consist in heteroleptic dithiocarbamate complexes [Ln(Et{sub 2}dtc){sub 3}(phen)] and [Ln(Et{sub 2}dtc){sub 3}(bipy)] (Et{sub 2}dtc=N,N-diethyldithiocarbamate; phen=1,10-phenanthroline; bipy=2,2 Prime -bipyridine) and were synthesized by a new high yield and high purity synthesis route. The nature of the molecular precursor determines the minimum synthesis temperature and influences therefore the purity of the final Ln{sub 2}O{sub 2}S crystalline phase. - Graphical abstract: A continuous two-step molecular precursor pathway was designed for the preparation of rare-earth oxysulfides Ln{sub 2}O{sub 2}S (Ln=Y, La, Pr, Nd, Sm-Lu), starting from heteroleptic dithiocarbamate complexes. The influence of the nature of the molecular precursor on the minimum synthesis temperature and on the purity of the final Ln{sub 2}O{sub 2}S crystalline phase is discussed. Highlights: Black-Right-Pointing-Pointer A new high yield and high purity synthesis route of rare earth dithiocarbamates is described. Black-Right-Pointing-Pointer These compounds are used as precursors in a continuous process leading to rare-earth oxysulfides. Black-Right-Pointing-Pointer The oxysulfides are obtained under much more moderate conditions than previously described.

  20. A facile gel-combustion route for fine particle synthesis of spinel ferrichromite: X-ray and Mssbauer study on effect of Mg and Ni content

    SciTech Connect (OSTI)

    Vader, V.T.; Achary, S.N.; Meena, S.S.

    2014-02-01

    Highlights: A novel and facile synthesis route. Transformation of system from random to inverse spinel. Appearance of superparamagnetism phase. - Abstract: A novel nitratecitrate gel combustion route was used to prepare fine particle of a series Mg{sub 1?x}Ni{sub x}FeCrO{sub 4} (0.0 ? x ? 1.0) and its structural properties were investigated. The in situ oxidizing environment provided by the nitrate ions in the gel increases the rate of oxidation and lowers the decomposition temperature of component. All the samples after sintering were characterized at room temperature by X-ray diffraction (XRD) method and Mssbauer spectroscopy techniques. The X-ray and Mssbauer studies confirmed the single phase cubic spinel structure with all Fe ions in 3+ charge state. XRD and Mssbauer studies revealed that the samples of x = 0.0, and 0.2 are random spinel and show rather broad lines, while x = 0.41.0 are inverse spinel.

  1. Low-field magnetoresistance up to 400 K in double perovskite Sr{sub 2}FeMoO{sub 6} synthesized by a citrate route

    SciTech Connect (OSTI)

    Harnagea, L.; Jurca, B.; Berthet, P.

    2014-03-15

    A wet-chemistry technique, namely the citrate route, has been used to prepare high-quality polycrystalline samples of double perovskite Sr{sub 2}FeMoO{sub 6}. We report on the evolution of magnetic and magnetoresistive properties of the synthesized samples as a function of three parameters (i) the pH of the starting solution, (ii) the decomposition temperature of the citrate precursors and (iii) the sintering conditions. The low-field magnetoresistance (LFMR) value of our best samples is as high as 5% at room temperature for an applied magnetic field of 1 kOe. Additionally, the distinguishing feature of these samples is the persistence of LFMR, with a reasonably large value, up to 400 K which is a crucial parameter for any practical application. Our study indicates that the enhancement of LFMR observed is due to a good compromise between the grain size distribution and their magnetic polarization. -- Graphical abstract: The microstructure (left panel) and corresponding low-field magnetoresistance of one of the Sr{sub 2}FeMoO{sub 6} samples synthesized in the course of this work. Highlights: Samples of Sr{sub 2}FeMoO{sub 6} are prepared using a citrate route under varying conditions. Magnetoresistive properties are improved and optimized. Low-field magnetoresitence values as large as 5% at 300 K/1 kOe are reported. Persistence of low-field magnetoresistance up to 400 K.

  2. An anion substitution route to low loss colossal dielectric CaCu{sub 3}Ti{sub 4}O{sub 12}

    SciTech Connect (OSTI)

    Smith, Andrew E.; Calvarese, T.G.; Sleight, A.W.; Subramanian, M.A.

    2009-02-15

    An anion substitution route was utilized for lowering the dielectric loss in CaCu{sub 3}Ti{sub 4}O{sub 12} (CCTO) by partial replacement of oxygen by fluorine. This substitution reduced the dielectric loss, and retained a high dielectric constant that was essentially temperature independent from 25 to 200 deg. C. In particular, CaCu{sub 3}Ti{sub 4}O{sub 11.7}F{sub 0.3} exhibited a giant dielectric constant over 6000 and low dielectric loss below 0.075 at 100 kHz within a temperature range of 25-200 deg. C. Fluorine analysis confirmed the presence of fluorine in all samples measured. - Grapical Abstract: An anion substitution route was utilized for lowering the dielectric loss in CaCu{sub 3}Ti{sub 4}O{sub 12} (CCTO) by partial replacement of oxygen by fluorine. This substitution, confirmed by fluorine analysis, reduced tan {delta}, and retained a high dielectric constant that was essentially temperature independent from 25 to 200 deg. C at 100 kHz.

  3. Neutron structural characterization, inversion degree and transport properties of NiMn{sub 2}O{sub 4} spinel prepared by the hydroxide route

    SciTech Connect (OSTI)

    Sagua, A.; Lescano, Gabriela M.; Alonso, J.A.; Martínez-Coronado, R.; Fernández-Díaz, M.T.; Morán, E.

    2012-06-15

    Graphical abstract: A pure specimen has been synthesized by the hydroxide route. This spinel, studied by NPD, shows an important inversion degree, λ = 0.80. A bond-valence study shows that the tetrahedral Mn ions are divalent whereas the octahedral Mn and Ni are slightly oxidized from the expected 3+ and 2+ values, respectively. The mixed valence Mn{sup 3+}/Mn{sup 4+} accounts for a hopping mechanism between adjacent octahedral sites, leading to a significant conductivity. Highlights: ► A low-temperature hydroxide route allowed preparing almost pure specimens of NiMn{sub 2}O{sub 4}. ► NPD essential to determine inversion degree; contrasting Ni and Mn for neutrons. ► Bond valence establishes valence state of octahedral and tetrahedral Ni and Mn ions. ► Thermal analysis, transport measurements complement characterization of this oxide. ► A structure–properties relationship is established. -- Abstract: The title compound has been synthesized by the hydroxide route. The crystal structure has been investigated at room temperature from high-resolution neutron powder diffraction (NPD) data. It crystallizes in a cubic spinel structure, space group Fd3{sup ¯}m, Z = 8, with a = 8.3940(2) Å at 295 K. The crystallographic formula is (Ni{sub 0.202(1)}Mn{sub 0.798(1)}){sub 8a}(Ni{sub 0.790(1)}Mn{sub 1.210(1)}){sub 16d}O{sub 4} where 8a and 16d stand for the tetrahedral and octahedral sites of the spinel structure, respectively. There is a significant inversion degree of the spinel structure, λ = 0.80. In fact, the variable parameter for the oxygen position, u = 0.2636(4), is far from that expected (u = 0.25) for normal spinels. From a bond-valence study, it seems that the valence distribution in NiMn{sub 2}O{sub 4} spinel is not as trivial as expected (Ni{sup 2+} and Mn{sup 3+}), but clearly the tetrahedral Mn ions are divalent whereas the octahedral Mn and Ni are slightly oxidized from the expected +3 and +2 values, respectively. The mixed valence observed at

  4. Eliminating livelock by assigning the same priority state to each message that is inputted into a flushable routing system during N time intervals

    DOE Patents [OSTI]

    Faber, Vance

    1994-01-01

    Livelock-free message routing is provided in a network of interconnected nodes that is flushable in time T. An input message processor generates sequences of at least N time intervals, each of duration T. An input register provides for receiving and holding each input message, where the message is assigned a priority state p during an nth one of the N time intervals. At each of the network nodes a message processor reads the assigned priority state and awards priority to messages with priority state (p-1) during an nth time interval and to messages with priority state p during an (n+1) th time interval. The messages that are awarded priority are output on an output path toward the addressed output message processor. Thus, no message remains in the network for a time longer than T.

  5. Eliminating livelock by assigning the same priority state to each message that is input into a flushable routing system during N time intervals

    DOE Patents [OSTI]

    Faber, V.

    1994-11-29

    Livelock-free message routing is provided in a network of interconnected nodes that is flushable in time T. An input message processor generates sequences of at least N time intervals, each of duration T. An input register provides for receiving and holding each input message, where the message is assigned a priority state p during an nth one of the N time intervals. At each of the network nodes a message processor reads the assigned priority state and awards priority to messages with priority state (p-1) during an nth time interval and to messages with priority state p during an (n+1) th time interval. The messages that are awarded priority are output on an output path toward the addressed output message processor. Thus, no message remains in the network for a time longer than T. 4 figures.

  6. Controlled synthesis of highly ordered LaFeO{sub 3} nanowires using a citrate-based sol-gel route

    SciTech Connect (OSTI)

    Yang Zhi; Huang Yi; Dong Bin; Li Hulin . E-mail: lihl@lzu.edu.cn

    2006-02-02

    Highly ordered LaFeO{sub 3} nanowires of complex oxide were controlled synthesized with a porous anodic aluminum oxide (AAO) template by a citrate-based sol-gel route. The results of scanning electron microscopy (SEM) and transmission electron microscopy (TEM) revealed that the LaFeO{sub 3} nanowires formed a uniform length and diameter, which were determined by the thickness and the pore diameter of the AAO template, respectively. The results of X-ray diffraction (XRD) and the selected area electron diffraction (SAED) indicated that the LaFeO{sub 3} nanowires had a perovskite-type crystal structure. Furthermore, X-ray photoelectron spectroscopy (XPS) demonstrated that stoichiometric LaFeO{sub 3} was formed.

  7. Systems configured to distribute a telephone call, communication systems, communication methods and methods of routing a telephone call to a service representative

    DOE Patents [OSTI]

    Harris, Scott H.; Johnson, Joel A.; Neiswanger, Jeffery R.; Twitchell, Kevin E.

    2004-03-09

    The present invention includes systems configured to distribute a telephone call, communication systems, communication methods and methods of routing a telephone call to a customer service representative. In one embodiment of the invention, a system configured to distribute a telephone call within a network includes a distributor adapted to connect with a telephone system, the distributor being configured to connect a telephone call using the telephone system and output the telephone call and associated data of the telephone call; and a plurality of customer service representative terminals connected with the distributor and a selected customer service representative terminal being configured to receive the telephone call and the associated data, the distributor and the selected customer service representative terminal being configured to synchronize, application of the telephone call and associated data from the distributor to the selected customer service representative terminal.

  8. Dielectric studies of BaTi{sub 0.96}Co{sub 0.04}O{sub 3} prepared via solid state route

    SciTech Connect (OSTI)

    Mishra, Ashutosh Mishra, Niyati Jarabana, Kanaka Mahalakshmi Bisen, Supriya

    2014-04-24

    The synthesis and characterization of cobalt doped barium titanate; BaTi{sub 0.96}Co{sub 0.04}O{sub 3} was investigated with a view to understand its structural and dielectric properties. A finest possible sample of Cobalt doped micro particles of BaTiO{sub 3} (BTO) with possible cubic structure via a solid-state route was prepared. Prepared samples were structural characterized by X-ray diffraction (XRD). The dielectric constant measurements of the sample above and below the Curie temperature were carried out at various frequencies. The Transition temperature is found shifted towards lower side from that of pure BaTiO{sub 3}.

  9. Lambda network having 2{sup m{minus}1} nodes in each of m stages with each node coupled to four other nodes for bidirectional routing of data packets between nodes

    DOE Patents [OSTI]

    Napolitano, L.M. Jr.

    1995-11-28

    The Lambda network is a single stage, packet-switched interprocessor communication network for a distributed memory, parallel processor computer. Its design arises from the desired network characteristics of minimizing mean and maximum packet transfer time, local routing, expandability, deadlock avoidance, and fault tolerance. The network is based on fixed degree nodes and has mean and maximum packet transfer distances where n is the number of processors. The routing method is detailed, as are methods for expandability, deadlock avoidance, and fault tolerance. 14 figs.

  10. Characterization of Cu–Ni nanostructured alloys obtained by a chemical route. Influence of the complexing agent content in the starting solution

    SciTech Connect (OSTI)

    Carreras, Alejo C.

    2015-03-15

    The influence of the amount of complexing agent added to the starting solution on the physicochemical properties of Cu–Ni nanostructured alloys obtained through a chemical route, was studied. For this purpose, three Cu–Ni nanoalloy samples were synthesized by a previously developed procedure, starting from solutions with citric acid to metal molar ratios (C/Me) of 0.73, 1.00 and 1.50. The synthesis technique consisted in preparing a precursor via the citrate-gel method, and carrying out subsequent thermal treatments in controlled atmospheres. Sample characterization was performed by scanning electron microscopy, X-ray microanalysis, X-ray diffraction, transmission electron microscopy, X-ray nanoanalysis and electron diffraction. In the three cases, copper and nickel formed a solid solution with a Cu/Ni atomic ratio close to 50/50, and free of impurities inside the crystal structure. The citric acid content of the starting solution proved to have an important influence on the morphology, size distribution, porosity, and crystallinity of the Cu–Ni alloy microparticles obtained, but a lesser influence on their chemical composition. The molar ratio C/Me = 1.00 resulted in the alloy with the Cu/Ni atomic ratio closest to 50/50. - Highlights: • We synthesize Cu–Ni nanoalloys by a chemical route based on the citrate-gel method. • We study the influence of the complexing agent content of the starting solution. • We characterize the samples by electron microscopy and X-ray techniques. • Citric acid influences the shape, size, porosity and crystallinity of the alloys.

  11. Influence of crystalline phase and defects in the ZrO{sub 2} nanoparticles synthesized by thermal plasma route on its photocatalytic properties

    SciTech Connect (OSTI)

    Nawale, Ashok B.; Kanhe, Nilesh S.; Bhoraskar, S.V.; Mathe, V.L.; Das, A.K.

    2012-11-15

    Graphical abstract: Thermal plasma synthesized nanophase zirconia showing the blue shift in the band gap of monoclinic phase as found from the photoabsorption spectroscopy was found to be the dominant parameter for the enhancement in its photocatalytic activity. The existence of different defect states and their concentration in as synthesized samples also inferred from the photoabsorption measurements were also found to be responsible for the enhanced photocatalytic activity of the samples. Highlights: ? Phase controlled structural formation of nanophase ZrO{sub 2} by thermal plasma route. ? Enhanced photocatalytic degradation rate of methylene blue dye. ? The blue shift in the band gap of monoclinic phase of nanocrystalline ZrO{sub 2}. ? Existence of different defect states in the as synthesized nano phase ZrO{sub 2}. ? Several competing processes which controls the photocatalytic degradation rate. -- Abstract: The photocatalytic activity of pure ZrO{sub 2} samples, prepared by a thermal plasma route, and characterized by X-ray diffraction technique was tested for the degradation of methylene blue, which is known to be a hazardous dye. Although, all these samples synthesized at different operating pressures of the thermal plasma reactor showed the photocatalytic activity; the sample synthesized at 1.33 bar of operating pressure showed the highest photocatalytic activity. The blue shift in the band gap of monoclinic phase, as observed from the photo-absorption spectroscopy, may be attributed to the enhanced photocatalytic activity. The existence of different defect states and their concentration as, inferred from the photo-absorption measurements were also found to be responsible for the enhanced photocatalytic activity of the as synthesized samples.

  12. Influence of processing route on electrical properties of Bi{sub 4}Ti{sub 3}O{sub 12} ceramics obtained by tape-casting technology

    SciTech Connect (OSTI)

    Ranieri, M.G.A.; Aguiar, E.C.; Cilense, M.; Stojanovic, B.D.; Simões, A.Z.; Varela, J.A.

    2015-10-15

    Highlights: • Bi{sub 4}Ti{sub 3}O{sub 12} thick films were obtained by SSR and PPM methods. • Both systems crystallize in an orthorhombic structure. • Textured characteristics were evidenced. • Grain morphology affects the P–E loops. - Abstract: Bismuth titanate powders (Bi{sub 4}Ti{sub 3}O{sub 12}-BIT) were fabricated by solid state reaction (SSR) and polymeric precursor method (PPM). From these powders, Bi{sub 4}Ti{sub 3}O{sub 12} pellets were obtained by tape-casting using plate-like templates particles prepared by a molten salt method. The BIT phase crystallizes in an orthorhombic structure type with space group Fmmm. Agglomeration of the particles, which affects the densification of the ceramic, electrical conduction and leakage current at high electric fields, was monitored by transmission electronic microscopy (TEM) analyses. FEG-SEM indicated that different shape of grains of BIT ceramics was influenced by the processing route. Both SSR and PPM methods lead to unsaturated P–E loops of BIT ceramics originating from the highly c-axis orientation and high conductivity which was affected by charge carriers flowing normally to the grain boundary of the crystal lattice.

  13. Simultaneous use of camera and probe diagnostics to unambiguously identify and study the dynamics of multiple underlying instabilities during the route to plasma turbulence

    SciTech Connect (OSTI)

    Thakur, S. C. Tynan, G. R.; Brandt, C.; Cui, L.; Gosselin, J. J.; Light, A.

    2014-11-15

    We use multiple-tip Langmuir probes and fast imaging to unambiguously identify and study the dynamics of underlying instabilities during the controlled route to fully-developed plasma turbulence in a linear magnetized helicon plasma device. Langmuir probes measure radial profiles of electron temperature, plasma density and potential; from which we compute linear growth rates of instabilities, cross-phase between density and potential fluctuations, Reynold's stress, particle flux, vorticity, time-delay estimated velocity, etc. Fast imaging complements the 1D probe measurements by providing temporally and spatially resolved 2D details of plasma structures associated with the instabilities. We find that three radially separated plasma instabilities exist simultaneously. Density gradient driven resistive drift waves propagating in the electron diamagnetic drift direction separate the plasma into an edge region dominated by strong, velocity shear driven Kelvin-Helmholtz instabilities and a central core region which shows coherent Rayleigh-Taylor modes propagating in the ion diamagnetic drift direction. The simultaneous, complementary use of both probes and camera was crucial to identify the instabilities and understand the details of the very rich plasma dynamics.

  14. Developing health-based pre-planning clearance goals for airport remediation following a chemical terrorist attack: Decision criteria for multipathway exposure routes

    SciTech Connect (OSTI)

    Watson, Annetta Paule; Dolislager, Frederick; Hall, Dr. Linda; Hauschild, Veronique; Raber, Ellen; Love, Dr. Adam

    2011-01-01

    In the event of a chemical terrorist attack on a transportation hub, post-event remediation and restoration activities necessary to attain unrestricted facility re-use and re-entry could require hours to multiple days. While timeframes are dependent on numerous variables, a primary controlling factor is the level of pre-planning and decision-making completed prior to chemical release. What follows is the second of a two-part analysis identifying key considerations, critical information and decision criteria to facilitate post-attack and post-decontamination consequence management activities. Decision criteria analysis presented here provides first-time, open-literature documentation of multi-pathway, health-based remediation exposure guidelines for selected toxic industrial compounds, chemical warfare agents, and agent degradation products for pre-planning application in anticipation of a chemical terrorist attack. Guideline values are provided for inhalation and direct ocular vapor exposure routes as well as percutaneous vapor, surface contact, and ingestion. Target populations include various employees as well as transit passengers. This work has been performed as a national case study conducted in partnership with the Los Angeles International Airport and The Bradley International Terminal. All recommended guidelines have been selected for consistency with airport scenario release parameters of a one-time, short-duration, finite airborne release from a single source followed by compound-specific decontamination.

  15. A facile and scalable route to nano-crystallized kesterite Cu{sub 2}ZnSnS{sub 4} fibers via electrospinning/sulfurization

    SciTech Connect (OSTI)

    Song, Yuanqiang Liu, Aifang; Mu, Chunhong; Huo, Weirong; Lv, Weiqiang; He, Weidong

    2015-01-15

    Detailed characterization of the microstructure and its properties have been done on the nanocrystallized CZTS nanofibers fabricated via electrospinning following sulfurization. The fiber growth mechanism is proposed to explain the spontaneous reaction and crystallization of CZTS, as confirmed by the thermodynamic calculations. - Abstract: In this work, we report facile route to quaternary kesterite Cu{sub 2}ZnSnS{sub 4} (CZTS) microfibers through electrospinning method. Precursor fibers are electrospun from the solution composed of Cu(CH{sub 3}COO){sub 2}, Zn(CH{sub 3}COO){sub 2{sup ,}} and SnCl{sub 4} as the solutes, ethylene glycol methyl ether as the solvent, and polyvinylpyrrolidone (PVP) as the plasticizer. CZTS fibers are obtained after annealing at 773 K for 40 min in a sulfur ambient. Characterization including scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and Raman spectra, confirm the formation of single-phased, well-crystallized CZTS fibers, with a band gap of about 1.48 eV estimated from the optical absorption curve. In addition, the fiber growth mechanism is proposed to explain the spontaneous reaction and crystallization of CZTS, as confirmed by the thermodynamic calculations.

  16. The Sasol route to fuels

    SciTech Connect (OSTI)

    Dry, M.E.

    1982-12-01

    Details are given of the Sasol operation in South Africa. Flow sheets are provided for Sasol 1 and Sasol 2 and 3. The Sasol 1 plant produces waxes, liquid fuels, pipeline gas and chemicals; the Sasol 2 and 3 plants primarily produce ethylene, gasoline and diesel fuel. The versatility of the process is emphasized. The product selectivities of the fixed bed and Synthol reactors are shown and the properties of the products are compared. The influence of the catalyst on selectivity is examined.

  17. Alternate Routes to Enter Westgate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  18. Nanocrystalline Sm{sub 0.5}Sr{sub 0.5}CoO{sub 3−δ} synthesized using a chelating route for use in IT-SOFC cathodes: Microstructure, surface chemistry and electrical conductivity

    SciTech Connect (OSTI)

    Scurtu, Rares; Somacescu, Simona; Calderon-Moreno, Jose Maria; Culita, Daniela; Bulimestru, Ion; Popa, Nelea; Gulea, Aurelian; Osiceanu, Petre

    2014-02-15

    Nanocrystalline Sm{sub 0.5}Sr{sub 0.5}CoO{sub 3−δ} powders were synthesized by a chelating route using different polyfunctional H{sub x}APC acids (APC=aminopolycarboxylate; x=3, 4, 5). Different homologous aminopolycarboxylic acids, namely nitrilotriacetic (H{sub 3}nta), ethylenediaminetetraacetic (H{sub 4}edta), 1,2-cyclohexanediaminetetracetic (H{sub 4}cdta) and diethylenetriaminepentaacetic (H{sub 5}dtpa) acid, were used as chelating agents to combine Sm, Sr, Co elements into a perovskite structure. The effects of the chelating agents on the crystalline structure, porosity, surface chemistry and electrical properties were investigated. The electrical properties of the perovskite-type materials emphasized that their conductivities in the temperature range of interest (600–800 °C) depend on the nature of the precursors as well as on the presence of a residual Co oxide phase as shown by XRD and XPS analysis. The surface chemistry and the surface stoichiometries were determined by XPS revealing a complex chemical behavior of Sr that exhibits a peculiar “surface phase” and “bulk phase” chemistry within the detected volume (<10 nm). - Graphical abstract: Synthesis of nanocrystalline Sm{sub 0.5}Sr{sub 0.5}CoO{sub 3−δ} powders by a chelating route and the investigation of the microstructure, surface chemistry and electrical properties. Display Omitted - Highlights: • Nanocrystalline Sm{sub 0.5}Sr{sub 0.5}CoO{sub 3−δ} obtained by a chelating synthesis route. • Cubic perovskite structures with crystallite sizes ∼23±2 nm. • The porous nature revealed by N{sub 2} adsorption/desorption (BET). • The surface chemistry and the surface stoichiometries highlighted by XPS. • A complex chemical behavior of Sr exhibits a peculiar “surface phase” and “bulk phase” chemistry.

  19. Minimally Invasive Magnetic Resonance Imaging-Guided Free-Hand Aspiration of Symptomatic Nerve Route Compressing Lumbosacral Cysts Using a 1.0-Tesla Open Magnetic Resonance Imaging System

    SciTech Connect (OSTI)

    Bucourt, Maximilian de Streitparth, Florian Collettini, Federico; Guettler, Felix; Rathke, Hendrik; Lorenz, Britta; Rump, Jens; Hamm, Bernd; Teichgraeber, U. K.

    2012-02-15

    Purpose: To evaluate the feasibility of minimally invasive magnetic resonance imaging (MRI)-guided free-hand aspiration of symptomatic nerve route compressing lumbosacral cysts in a 1.0-Tesla (T) open MRI system using a tailored interactive sequence. Materials and Methods: Eleven patients with MRI-evident symptomatic cysts in the lumbosacral region and possible nerve route compressing character were referred to a 1.0-T open MRI system. For MRI interventional cyst aspiration, an interactive sequence was used, allowing for near real-time position validation of the needle in any desired three-dimensional plane. Results: Seven of 11 cysts in the lumbosacral region were successfully aspirated (average 10.1 mm [SD {+-} 1.9]). After successful cyst aspiration, each patient reported speedy relief of initial symptoms. Average cyst size was 9.6 mm ({+-}2.6 mm). Four cysts (8.8 {+-} 3.8 mm) could not be aspirated. Conclusion: Open MRI systems with tailored interactive sequences have great potential for cyst aspiration in the lumbosacral region. The authors perceive major advantages of the MR-guided cyst aspiration in its minimally invasive character compared to direct and open surgical options along with consecutive less trauma, less stress, and also less side-effects for the patient.

  20. Reasons for decision in the matter of Sable Offshore Energy Inc., application dated 9 June 1998 for approval of the plan, profile and book of reference respecting the detailed route of a subsea pipeline from the Thebaud platform to a landfall near Goldboro, Nova Scotia, and an onshore pipeline from the landfall point to the inlet of the gas processing plant located east of Goldboro, Nova Scotia: MH-4-98

    SciTech Connect (OSTI)

    1998-12-31

    The National Energy Board approved a natural gas pipeline to be built by the proponents of the Sable Offshore Energy Project within a specified 500-meter-wide corridor. The pipeline will run from an offshore platform near Sable Island to a gas plant on the Nova Scotia mainland. This report summarizes proceedings of hearings held to determine the detailed route of the pipeline within the specified corridor and to consider the most appropriate methods and timing of constructing the pipeline. Specific objections to the detailed route from holders of mineral rights licenses are noted and a Board decision on the detailed route is presented.

  1. New scheelite-type oxynitrides in systems RWO{sub 3}N-AWO{sub 4} (R = rare-earth element; A = Ca, Sr) from precursors obtained by the citrate route

    SciTech Connect (OSTI)

    Chevire, Francois; Tessier, Franck; Marchand, Roger

    2004-06-08

    RWO{sub 3}N oxynitrides were isolated as single phases for R=Nd and Pr, after thermal ammonolysis of reactive precursors prepared using the citrate complexation/calcination route. Both stoichiometric compounds crystallize with a scheelite-type tetragonal unit cell, with a=5.2821(3) A, c=11.5893(8) A (NdWO{sub 3}N) and a=5.299(3) A, c=11.631(9) A (PrWO{sub 3}N). Neutron diffraction experiments performed on the Nd-phase did not evidence any oxygen/nitrogen order within the scheelite anionic subnetwork (space group: I4{sub 1}/a). (Nd,A)W(O,N){sub 4} (A=Ca, Sr) solid solution domains were identified between NdWO{sub 3}N and the AWO{sub 4} oxide composition.

  2. Synthesis of nanocrystalline REBO{sub 3} (RE=Y, Nd, Sm, Eu, Gd, Ho) and YBO{sub 3}:Eu using a borohydride-based solution precursor route

    SciTech Connect (OSTI)

    Henkes, Amanda E.; Schaak, Raymond E.

    2008-12-15

    A solution precursor route has been used to synthesize a series of nanocrystalline rare-earth borates. Amorphous precursor powders are precipitated during an aqueous reaction between RE{sup 3+} and NaBH{sub 4}, and the isolated powders can be annealed in air at 700 deg. C to form YBO{sub 3}, NdBO{sub 3}, SmBO{sub 3}, EuBO{sub 3}, GdBO{sub 3}, and HoBO{sub 3}. YBO{sub 3}:Eu formed using this strategy shows red-orange emission properties that are similar to high-quality nanocrystals prepared by other methods. The materials have been characterized by FTIR spectroscopy, powder XRD, SEM, DSC, UV-Vis fluorimetry, and TEM with EDS and element mapping. - Graphical abstract: Amorphous nanoscopic precursor powders are formed through the aqueous reaction of RE{sup 3+} with NaBH{sub 4}. Once isolated, the powders can be annealed at 700 deg. C in air to form a series of nanocrystalline REBO{sub 3} orthoborates. Nanocrystalline YBO{sub 3}:Eu formed using this strategy shows red-orange emission properties when excited with UV light.

  3. Cell Phone Detection Techniques

    SciTech Connect (OSTI)

    Pratt, Richard M.; Bunch, Kyle J.; Puzycki, David J.; Slaugh, Ryan W.; Good, Morris S.; McMakin, Douglas L.

    2007-10-01

    A team composed of Rick Pratt, Dave Puczyki, Kyle Bunch, Ryan Slaugh, Morris Good, and Doug McMakin teamed together to attempt to exploit cellular telephone features and detect if a person was carrying a cellular telephone into a Limited Area. The cell phones electromagnetic properties were measured, analyzed, and tested in over 10 different ways to determine if an exploitable signature exists. The method that appears to have the most potential for success without adding an external tag is to measure the RF spectrum, not in the cell phone band, but between 240 and 400MHz. Figures 1- 7 show the detected signal levels from cell phones from three different manufacturers.

  4. DOE HQ Shuttle Bus Route and Schedule

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at 1201 Maryland Ave., S.W. > L'Enfant Plaza - Opposite side of the roadway in front of ... leaving from the Forrestal and L'Enfant Plaza facilities should contact (202) 586-5235. ...

  5. Analysis shows revamp route to naphtha feed

    SciTech Connect (OSTI)

    Aguilar, E.; Ortiz, C.H.; Arzate, E. )

    1988-11-21

    An existing ethylene plant was studied, using a computer-simulated flexibility analysis, to determine the changes required to convert one of the cracking furnaces from ethane feed to naphtha feed. The simulation determined the changes in flow rate, operating temperature, and steam/hydrocarbon ratio that would result from the liquid feed.

  6. Route profile analysis system and method

    DOE Patents [OSTI]

    Mullenhoff, D.J.; Wilson, S.W.

    1982-07-29

    A system for recording terrain profile information is disclosed. The system accurately senses incremental distances traveled by a vehicle along with vehicle inclination, recording both with elapsed time. The incremental distances can subsequently be differentiated with respect to time to obtain acceleration. The computer acceleration can then be used to correct the sensed inclination.

  7. Route profile analysis system and method

    DOE Patents [OSTI]

    Mullenhoff, Donald J.; Wilson, Stephen W.

    1986-01-01

    A system for recording terrain profile information is disclosed. The system accurately senses incremental distances traveled by a vehicle along with vehicle inclination, recording both with elapsed time. The incremental distances can subsequently be differentiated with respect to time to obtain acceleration. The acceleration can then be used by the computer to correct the sensed inclination.

  8. Liquid Silane Routes to Electronic Materials

    SciTech Connect (OSTI)

    Douglas L. Schulz; Xuliang Dai; Kendric J. Nelson; Konstantin Pokhodnya; Justin M. Hoey; Iskander S. Akhatov; Orven F. Swenson; Jeremiah Smith; John Lovaasen; Matt Robinson; Scott Payne; Philip R. Boudjouk

    2008-12-04

    New chemistries based upon liquid cyclohexasilane (Si{sub 6}H{sub 12} or CHS) have been used as precursors to silicon-containing electronic materials. Spin-coating of CHS-based inks with subsequent UV light and/or thermal treatment yielded amorphous silicon (a-Si:H) films. While initial ink chemistries gave a-Si:H with high resistivity (i.e., > 10{sup 6} {Omega}.cm), several doping strategies are under development to address this limitation. In this contribution, the current status of solution processed rectifying diodes and field effect transistors fabricated from CHS-based inks will be presented. Additionally, a new printing approach termed collimated aerosol beam direct write (CAB-DW{sup TM}) was developed that allows the deposition of printed Ag lines 5 {mu}m in width. A status update will be given where CHS-based inks have been used to CAB-DW silicon-based features with linewidths <10 {mu}m. Assuming silicon thin film materials with good electrical properties will be developed, there may be significant cost advantages associated with the ability to controllably deposit the semiconductor in a metered fashion.

  9. Low temperature route to uranium nitride

    DOE Patents [OSTI]

    Burrell, Anthony K.; Sattelberger, Alfred P.; Yeamans, Charles; Hartmann, Thomas; Silva, G. W. Chinthaka; Cerefice, Gary; Czerwinski, Kenneth R.

    2009-09-01

    A method of preparing an actinide nitride fuel for nuclear reactors is provided. The method comprises the steps of a) providing at least one actinide oxide and optionally zirconium oxide; b) mixing the oxide with a source of hydrogen fluoride for a period of time and at a temperature sufficient to convert the oxide to a fluoride salt; c) heating the fluoride salt to remove water; d) heating the fluoride salt in a nitrogen atmosphere for a period of time and at a temperature sufficient to convert the fluorides to nitrides; and e) heating the nitrides under vacuum and/or inert atmosphere for a period of time sufficient to convert the nitrides to mononitrides.

  10. Pumping-route-dependent concentration quenching and temperature effect of green up- and down-conversion luminescence in Er{sup 3+}/Yb{sup 3+} co-doped Gd{sub 2}(WO{sub 4}){sub 3} phosphors

    SciTech Connect (OSTI)

    Li, Jingjing; Sun, Jiashi [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China); Liu, Jutao [College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China); Li, Xiangping; Zhang, Jinsu [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China); Tian, Yue [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China); College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China); Fu, Shaobo; Cheng, Lihong; Zhong, Haiyang [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China); Xia, Haiping [Key laboratory of Photo-electronic Materials, Ningbo University, Ningbo, Zhejiang 315211 (China); Chen, Baojiu, E-mail: chenmbj@sohu.com [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China)

    2013-06-01

    Graphical abstract: A comparative study on the concentration quenching behaviors of green down- and up-conversion emissions was carried out for the first time, and the different concentration quenching mechanisms were analyzed. Secondly, the thermal effect induced by 980 nm LD irradiation was investigated, it was observed that the equilibrium temperature of Gd{sub 2}(WO{sub 4}){sub 3}:Er{sup 3+}/Yb{sup 3+} sample was decided by both the excitation power and Er{sup 3+} doping concentration. Highlights: ? Gd{sub 2}(WO{sub 4}){sub 3}:Er/Yb phosphors were prepared via a co-precipitation reaction. ? Morphology and structure of the phosphors were characterized by XRD and SEM. ? Concentration quenching mechanisms for down and up emissions were studied. ? Thermal effect induced by laser irradiation was studied via temperature sensing tech. - Abstract: Gd{sub 2}(WO{sub 4}){sub 3} phosphors with various Er{sup 3+} concentrations and fixed Yb{sup 3+} concentration were synthesized via a co-precipitation method, and their crystal structure and morphology were characterized by using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The concentration quenching behaviors of green up- and down-conversion emissions of Er{sup 3+} were analyzed, and it was confirmed that the difference between quenching concentration for up- and down-conversion emissions resulted from the different population routes. The temperature sensing properties of the Gd{sub 2}(WO{sub 4}){sub 3}:Er{sup 3+}/Yb{sup 3+} phosphors were studied, and it was found that the Er{sup 3+} doping concentration slightly affected the sensitivity, and Gd{sub 2}(WO{sub 4}){sub 3}:Er{sup 3+}/Yb{sup 3+} phosphors could be used in a broad temperature region for detecting temperature. Finally, the thermal effect induced by 980 nm LD irradiation was investigated, it was observed that the equilibrium temperature of Gd{sub 2}(WO{sub 4}){sub 3}:Er{sup 3+}/Yb{sup 3+} sample was decided by both the excitation power and Er

  11. TTO Phone List | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    TTO Phone List TTO Phone List TTO Phone List Revised 04/02/2014 TTO Phone List Revised 04-02-14.docx (23.97 KB) More Documents & Publications Technology Transfer Reporting Form Vehicle Technologies Office Merit Review 2015: High Energy High Power Battery Exceeding PHEV-40 Requirements Technical Standards Managers Contact List

  12. Mobile phone and my health

    SciTech Connect (OSTI)

    Surducan, Aneta; Dabala, Dana; Neamtu, Camelia Surducan, Vasile Surducan, Emanoil

    2013-11-13

    The interaction of the microwave radiation emitted by mobile phones with the user's body is analyzed from the International Commission on Non-Ionizing Radiation Protection (ICNIRP) recommendations perspective as a correlation between the specific absorption ratio (SAR) of the mobile phone and the call duration. The relative position of the cell phone to the user's body, the dielectric properties of the exposed body parts, the SAR value and the call duration are considered in the local body temperature rise due to the microwave heating effect. The recommended local temperature rise limit in the human body is evaluated according to standards. The aim of this study is to disseminate information to young people, especially high school students, about the microwave thermal effects on the human body, to make them aware of the environmental electromagnetic pollution and to offer them a simple method of biological self protection.

  13. Recovery of lithium and cobalt from waste lithium ion batteries of mobile phone

    SciTech Connect (OSTI)

    Jha, Manis Kumar, E-mail: mkjha@nmlindia.org; Kumari, Anjan; Jha, Amrita Kumari; Kumar, Vinay; Hait, Jhumki; Pandey, Banshi Dhar

    2013-09-15

    Graphical abstract: Recovery of valuable metals from scrap batteries of mobile phone. - Highlights: Recovery of Co and Li from spent LIBs was performed by hydrometallurgical route. Under the optimum condition, 99.1% of lithium and 70.0% of cobalt were leached. The mechanism of the dissolution of lithium and cobalt was studied. Activation energy for lithium and cobalt were found to be 32.4 kJ/mol and 59.81 kJ/mol, respectively. After metal recovery, residue was washed before disposal to the environment. - Abstract: In view of the stringent environmental regulations, availability of limited natural resources and ever increasing need of alternative energy critical elements, an environmental eco-friendly leaching process is reported for the recovery of lithium and cobalt from the cathode active materials of spent lithium-ion batteries of mobile phones. The experiments were carried out to optimize the process parameters for the recovery of lithium and cobalt by varying the concentration of leachant, pulp density, reductant volume and temperature. Leaching with 2 M sulfuric acid with the addition of 5% H{sub 2}O{sub 2} (v/v) at a pulp density of 100 g/L and 75 C resulted in the recovery of 99.1% lithium and 70.0% cobalt in 60 min. H{sub 2}O{sub 2} in sulfuric acid solution acts as an effective reducing agent, which enhance the percentage leaching of metals. Leaching kinetics of lithium in sulfuric acid fitted well to the chemical controlled reaction model i.e. 1 ? (1 ? X){sup 1/3} = k{sub c}t. Leaching kinetics of cobalt fitted well to the model ash diffusion control dense constant sizes spherical particles i.e. 1 ? 3(1 ? X){sup 2/3} + 2(1 ? X) = k{sub c}t. Metals could subsequently be separated selectively from the leach liquor by solvent extraction process to produce their salts by crystallization process from the purified solution.

  14. CB-EMIS CELL PHONE CLIENT

    Energy Science and Technology Software Center (OSTI)

    2007-01-02

    The cell phone software allows any Java enabled cell phone to view sensor and meteorological data via an internet connection using a secure connection to the CB-EMIS Web Service. Users with appropriate privileges can monitor the state of the sensors and perform simple maintenance tasks remotely. All sensitive data is downloaded from the web service, thus protecting sensitive data in the event a cell phone is lost.

  15. A New Route to Nano Self-Assembly

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    potential for breakthroughs that reverberate through nearly every sector of the economy (medicine, computing, energy, homeland security) is so great that it has already...

  16. A Route Towards Sustainability Through Engineered Polymeric Interfaces

    SciTech Connect (OSTI)

    Reeja-Jayan, B; Kovacik, P; Yang, R; Sojoudi, H; Ugur, A; Kim, DH; Petruczok, CD; Wang, XX; Liu, AD; Gleason, KK

    2014-05-30

    Chemical vapor deposition (CVD) of polymer films represent the marriage of two of the most important technological innovations of the modern age. CVD as a mature technology for growing inorganic thin films is already a workhorse technology of the microfabrication industry and easily scalable from bench to plant. The low cost, mechanical flexibility, and varied functionality offered by polymer thin films make them attractive for both macro and micro scale applications. This review article focuses on two energy and resource efficient CVD polymerization methods, initiated Chemical Vapor Deposition (iCVD) and oxidative Chemical Vapor Deposition (oCVD). These solvent-free, substrate independent techniques engineer multi-scale, multi-functional and conformal polymer thin film surfaces and interfaces for applications that can address the main sustainability challenges faced by the world today.

  17. Diffusionless fluid transport and routing using novel microfluidic devices.

    SciTech Connect (OSTI)

    Barrett, Louise Mary; Shediac, Renee; Reichmuth, David S.

    2006-11-01

    Microfluidic devices have been proposed for 'Lab-on-a-Chip' applications for nearly a decade. Despite the unquestionable promise of these devices to allow rapid, sensitive and portable biochemical analysis, few practical devices exist. It is often difficult to adapt current laboratory techniques to the microscale because bench-top methods use discrete liquid volumes, while most current microfluidic devices employ streams of liquid confined in a branching network of micron-scale channels. The goal of this research was to use two phase liquid flows, creating discrete packets of liquid. Once divided into discrete packets, the packets can be moved controllably within the microchannels without loss of material. Each packet is equivalent to a minute test tube, holding a fraction from a separation or an aliquot to be reacted. We report on the fabrication of glass and PDMS (polydimethylsiloxane) devices that create and store packets.

  18. A New Route to Nano Self-Assembly

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    critical to tailoring the macroscopic properties during nanoparticle assembly. Although DNA has been used to induce self-assembly of nanoparticles with a high degree of...

  19. Biological and Biomimetic Low-Temperature Routes to Materials...

    Broader source: Energy.gov (indexed) [DOE]

    es047morse2012p.pdf (5.3 MB) More Documents & Publications Nano-scale Composite Hetero-structures: Novel High Capacity Reversible Anodes for Lithium-ion Batteries Novel Lithium ...

  20. Innovative Nano-structuring Routes for Novel ThermoelectricMaterials...

    Broader source: Energy.gov (indexed) [DOE]

    Presents new concepts for high performance nanostructured bulk thermoelectric materials lee.pdf (1.98 MB) More Documents & Publications Thermoelectric Materials for Automotive ...

  1. Metallurgical Route to Produce Upgraded Silicon and Monosilane

    SciTech Connect (OSTI)

    Mukashev, B. N.; Abdullin, Kh A.; Tamendarov, M. F.; Turmagambetov, T. S.; Beketov, B. A.; Page, M. R.; Kline, D. M.

    2009-01-01

    We studied alumothermic reduction of silica from silicate slag to obtain silicon-containing Alloy-I and Alloy-II. Phosphorous industry waste and synthetic slag are used as a silicate slag that consists of more than 90% silicon and calcium oxides and less than l0% other elemental oxides. Silicon-containing Alloy-I was upgraded by acid leaching to silicon of a fine powder structure. Using this powder, we grew poly- and mono-crystalline p-type silicon, with resistivity of 0.24 {Omega} cm, by the Czochralski method. Silicon-containing Alloy-II was used for obtaining monosilane by aqueous treatment with hydrochloric acid under atmospheric conditions and without any catalyst. There was no trace of diborane, which is a common source for boron contamination in crude silane.

  2. Exhibit 2 - General Area Map of Proposed Route.pdf

    Office of Environmental Management (EM)

  3. Benzene reduction in RFG, a new low cost route

    SciTech Connect (OSTI)

    Gildert, R.; Gildert, G.

    1994-12-31

    Benzene has been targeted for reduction in reformulated gasoline because it is the largest single contributor to the toxic emissions group. This presentation describes processes of benzene removal for the petroleum refiner. By making maximum use of existing equipment, the refiner can minimize the changes necessary to produce reformulated gasoline with a reduction in benzene levels.

  4. DOE HQ Shuttle Bus Route and Schedule, April 2016

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The bus stops are located at: > Germantown - East side of Germantown building (cafeteria side) > Cloverleaf Building* - Front entrance (end of sidewalk near the roadway) * Note: At ...

  5. Photochemical route to actinide-transition metal bonds: synthesis...

    Office of Scientific and Technical Information (OSTI)

    bonds: synthesis, characterization and reactivity of a series of thorium and uranium ... bonds: synthesis, characterization and reactivity of a series of thorium and uranium ...

  6. Routing performance analysis and optimization within a massively parallel computer

    DOE Patents [OSTI]

    Archer, Charles Jens; Peters, Amanda; Pinnow, Kurt Walter; Swartz, Brent Allen

    2013-04-16

    An apparatus, program product and method optimize the operation of a massively parallel computer system by, in part, receiving actual performance data concerning an application executed by the plurality of interconnected nodes, and analyzing the actual performance data to identify an actual performance pattern. A desired performance pattern may be determined for the application, and an algorithm may be selected from among a plurality of algorithms stored within a memory, the algorithm being configured to achieve the desired performance pattern based on the actual performance data.

  7. Enhancing Railroad Hazardous Materials Transportation Safety Rail Routing |

    Office of Environmental Management (EM)

    Multiple Users | Department of Energy Enhancements to System for Tracking Radioactive Waste Shipments Benefit Multiple Users Enhancements to System for Tracking Radioactive Waste Shipments Benefit Multiple Users January 30, 2013 - 12:00pm Addthis Transportation Tracking and Communication System users can now track shipments of radioactive materials and access transportation information on mobile devices. Transportation Tracking and Communication System users can now track shipments of

  8. Innovative Nano-structuring Routes for Novel Thermoelectric

    Broader source: Energy.gov (indexed) [DOE]

    Materials;Phonon Blocking & DOS Engineering | Department of Energy Presents new concepts for high performance nanostructured bulk thermoelectric materials lee.pdf (1.98 MB) More Documents & Publications Thermoelectric Materials for Automotive Applications The Bottom-Up Approach forThermoelectric Nanocomposites, plusƒ Glass-like thermal conductivity in high efficiency thermoelectric materials

  9. BWXT Pantex, LLC Route 726, Mt. Athos Road

    National Nuclear Security Administration (NNSA)

    9B. DATED (SEE E M 11) I 1 DE-ACO4-OOALO6020 10s. DATED (SEE ITEM 13) I . CONTRACT ID CODE PAGE I OF 2 PAGES 2. AMENDMENT/MODlFlCATlON NO. MO99 Offers must acknowledge receipt of this amendment priw to the hour and date specifid in the solicitation a s amended. by one of the fdlovving methods: (a) By completing Items 8 and 15, and returning - copies of the amendmmS (b) By acknwuledglng receipt of this amendment on each oopy of the offer submitted; or (c) By separate letttx or tdegram which

  10. BWXT Pantex, LLC Route 726, Mt. Athos Road

    National Nuclear Security Administration (NNSA)

    9B. DATED (SEE ITEM 11) I I DE-AC04-00AL66620 10B. DATED (SEE ITEM 13) CONTRACT ID CODE PAGE I OF 2 PAGES 2. AMENDMENTIMODIFICATION NO. MI18 extended. CODE I FACILITY CODE Offers must acknowledge receipt of this amendment prior to the hour and date specified in the solicitation as amended, by one of the following methods: (a) By completing Items 8 and 15, and returning - copies of the amendment; (b) By acknowledging receipt of this amendment on each copy of the offer submitted; or (c) By

  11. Preparation of thin ceramic films via an aqueous solution route

    DOE Patents [OSTI]

    Pederson, Larry R.; Chick, Lawrence A.; Exarhos, Gregory J.

    1989-01-01

    A new chemical method of forming thin ceramic films has been developed. An aqueous solution of metal nitrates or other soluble metal salts and a low molecular weight amino acid is coated onto a substrate and pyrolyzed. The amino acid serves to prevent precipitation of individual solution components, forming a very viscous, glass-like material as excess water is evaporated. Using metal nitrates and glycine, the method has been demonstrated for zirconia with various levels of yttria stabilization, for lanthanum-strontium chromites, and for yttrium-barium-copper oxide superconductors on various substrates.

  12. Bio-inspired routes for synthesizing efficient nanoscale platinum electrocatalysts

    SciTech Connect (OSTI)

    Cha, Jennifer N.; Wang, Joseph

    2014-08-31

    The overall objective of the proposed research is to use fundamental advances in bionanotechnology to design powerful platinum nanocrystal electrocatalysts for fuel cell applications. The new economically-viable, environmentally-friendly, bottom-up biochemical synthetic strategy will produce platinum nanocrystals with tailored size, shape and crystal orientation, hence leading to a maximum electrochemical reactivity. There are five specific aims to the proposed bio-inspired strategy for synthesizing efficient electrocatalytic platinum nanocrystals: (1) isolate peptides that both selectively bind particular crystal faces of platinum and promote the nucleation and growth of particular nanocrystal morphologies, (2) pattern nanoscale 2-dimensional arrays of platinum nucleating peptides from DNA scaffolds, (3) investigate the combined use of substrate patterned peptides and soluble peptides on nanocrystal morphology and growth (4) synthesize platinum crystals on planar and large-area carbon electrode supports, and (5) perform detailed characterization of the electrocatalytic behavior as a function of catalyst size, shape and morphology. Project Description and Impact: This bio-inspired collaborative research effort will address key challenges in designing powerful electrocatalysts for fuel cell applications by employing nucleic acid scaffolds in combination with peptides to perform specific, environmentally-friendly, simultaneous bottom-up biochemical synthesis and patterned assembly of highly uniform and efficient platinum nanocrystal catalysts. Bulk synthesis of nanoparticles usually produces a range of sizes, accessible catalytic sites, crystal morphologies, and orientations, all of which lead to inconsistent catalytic activities. In contrast, biological systems routinely demonstrate exquisite control over inorganic syntheses at neutral pH and ambient temperature and pressures. Because the orientation and arrangement of the templating biomolecules can be precisely controlled, the nanocrystals boast a defined shape, morphology, orientation and size and are synthesized at benign reaction conditions. Adapting the methods of biomineralization towards the synthesis of platinum nanocrystals will allow effective control at a molecular level of the synthesis of highly active metal electrocatalysts, with readily tailored properties, through tuning of the biochemical inputs. The proposed research will incorporate many facets of biomineralization by: (1) isolating peptides that selectively bind particular crystal faces of platinum (2) isolating peptides that promote the nucleation and growth of particular nanocrystal morphologies (3) using two-dimensional DNA scaffolds to control the spatial orientation and density of the platinum nucleating peptides, and (4) combining bio-templating and soluble peptides to control crystal nucleation, orientation, and morphology. The resulting platinum nanocrystals will be evaluated for their electrocatalytic behavior (on common carbon supports) to determine their optimal size, morphology and crystal structure. We expect that such rational biochemical design will lead to highly uniform and efficient platinum nanocrystal catalysts for fuel cell applications.

  13. Low cost routes to high purity silicon and derivatives thereof

    DOE Patents [OSTI]

    Laine, Richard M; Krug, David James; Marchal, Julien Claudius; Mccolm, Andrew Stewart

    2013-07-02

    The present invention is directed to a method for providing an agricultural waste product having amorphous silica, carbon, and impurities; extracting from the agricultural waste product an amount of the impurities; changing the ratio of carbon to silica; and reducing the silica to a high purity silicon (e.g., to photovoltaic silicon).

  14. NAVIGATING A QUALITY ROUTE TO A NATIONAL SAFETY AWARD

    SciTech Connect (OSTI)

    PREVETTE SS

    2009-05-26

    Deming quality methodologies applied to safety are recognized with the National Safety Council's annual Robert W. Campbell Award. Over the last ten years, the implementation of Statistical Process Control and quality methodologies at the U.S. Department of Energy's Hanford Site have contributed to improved safety. Improvements attributed to Statistical Process Control are evidenced in Occupational Safety and Health records and documented through several articles in Quality Progress and the American Society of Safety Engineers publication, Professional Safety. Statistical trending of safety, quality, and occurrence data continues to playa key role in improving safety and quality at what has been called the world's largest environmental cleanup project. DOE's Hanford Site played a pivotal role in the nation's defense beginning in the 1940s, when it was established as part of the Manhattan Project. After more than 50 years of producing material for nuclear weapons, Hanford, which covers 586 square miles in southeastern Washington state, is now focused on three outcomes: (1) Restoring the Columbia River corridor for multiple uses; (2) Transitioning the central plateau to support long-term waste management; and (3) Putting DOE assets to work for the future. The current environmental cleanup mission faces challenges of overlapping technical, political, regulatory, environmental, and cultural interests. From Oct. 1, 1996 through Sept. 30, 2008, Fluor Hanford was a prime contractor to the Department of Energy's Richland Operations Office. In this role, Fluor Hanford managed several major cleanup activities that included dismantling former nuclear-processing facilities, cleaning up the Site's contaminated groundwater, retrieving and processing transuranic waste for shipment and disposal off-site, maintaining the Site's infrastructure, providing security and fire protection, and operating the Volpentest HAMMER Training and Education Center. On October 1,2008, a transition occurred that changed Fluor's role at Hanford. Fluor's work at Hanford was split in two with the technical scope being assumed by the CH2M HILL Plateau Remediation Company (CHPRC) CHPRC is now spearheading much of the cleanup work associated with former nuclear-processing facilities, contaminated groundwater, and transuranic waste. Fluor is an integrated subcontractor to CH PRC in this effort. In addition, at the time of this writing, while the final outcome is being determined for the new Mission Support Contract, Fluor Hanford has had its contract extended to provide site-wide services that include security, fire protection, infrastructure, and operating the HAMMER facility. The emphasis has to be on doing work safely, delivering quality work, controlling costs, and meeting deadlines. Statistical support is provided by Fluor to the PRC, within Fluor Hanford, and to a third contractor, Washington Closure Hanford, which is tasked with cleaning up approximately 210 square miles designated as the Columbia River corridor along the outer edge of the Hanford Site. The closing months of Fluor Hanford's 12 year contract were busy, characterized by special events that capped its work as a prime cleanup contractor, transitions of work scope and personnel, and the completion numerous activities. At this time, Fluor's work and approach to safety were featured in state and national forums. A 'Blockbuster' presentation at the Washington State Governor's Industrial Safety Conference in September 2008 featured Fluor Hanford's Chief Operating Officer, a company Safety Representative, and me. Simultaneously, an award ceremony in Anaheim, Calif. recognized Fluor Hanford as the winner of the 2008 Robert W. Campbell Award. The Robert W. Campbell Award is co-sponsored by Exxon Mobil Corporation and the National Safety Council. Named after a pioneer of industrial safety, the Campbell Award recognizes organizations that demonstrate how integration of environmental, health and safety (EHS) management into business operations is a cornerstone of their corporate success. Fluor Hanford received the award for corporations with more than 1,000 employees. Campbell Award winners undergo rigorous assessments that include site visits and comprehensive evaluations of their commitment to, and implementation of, EHS practices. Award winners work with an international partnership of 21 organizations to develop case studies that illustrate their superior EHS programs and best practices, for use by top business and engineering schools worldwide. Quality methodologies in place at Fluor Hanford played a key role in the award process. Fluor Hanford's integrated use of Statistical Process Control and Pareto Charts for analyzing and displaying EHS performance were viewed favorably by the award judges.

  15. Cost-Effective Fabrication Routes for the Production of Quantum...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Quantum-Well-Type Structures and Recovoery of Waste Heat from Heavy-Duty Trucks Thermoelectric Developments for Vehicular Applications Automotive Thermoelectric Generators and HVAC

  16. A New Route to Nano Self-Assembly

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to the surface of a block copolymer and be repositioned to another location along the polymeric chain. SAXS studies of the samples, performed at ALS Beamline 7.3.3, confirmed...

  17. Recent Advances on Carbon Nanospheres. Synthetic Routes and Applicatio...

    Office of Scientific and Technical Information (OSTI)

    Throughout this article, a special emphasis is placed on the possible modulation of spherical structures at the nanoscale, and we wish to inspire many more designs and applications ...

  18. A New Route to Nano Self-Assembly

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Japan). Research funding: Army Research Office; National Science Foundation; DuPont; 3M; Japan Ministry of Education, Science, Sports, and Culture; and the U.S....

  19. Diffraction limited focusing and routing of gap plasmons by a...

    Office of Scientific and Technical Information (OSTI)

    70NANB14H030; 70NANB14H259; DMR-1104884 Type: Accepted Manuscript Journal Name: Optics Express Additional Journal Information: Journal Volume: 23; Journal Issue: 17; Journal...

  20. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    interacting, electrons could hold the key to engineering novel functionality into a new generation of all-oxide electronic devices. ARPES measurements of a 2DEG in SrTiO3 and...

  1. RAIL ROUTING - CURRENT PRACTICES FOR SPENT NUCLEAR FUEL AND HIGH...

    Office of Environmental Management (EM)

    Two types of highly radioactive materials are spent nuclear fuel and high-level radioactive waste that resulted from reprocessing spent fuel. Transportation of these radioactive ...

  2. An Unlikely Route to Ferroelectricity | Advanced Photon Source

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    memory chips and highly sensitive magnetic field sensors. The crystalline material lutetium-iron-oxide (LuFe2O4) has, in turn, garnered much attention due to its purported...

  3. Niowave Develops Production Route for Medical Radioisotopes with...

    Office of Science (SC) Website

    The lack of a domestic supply and current use of techniques requiring weapons grade uranium led Congress to pass the American Medical Isotope Production Act in 2013. The Act ...

  4. A New Route to Nano Self-Assembly

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Nano Self-Assembly Print If the promise of nanotechnology is to be fulfilled, nanoparticles will have to be able to make something of themselves. An important advance toward...

  5. BWXT Pantex, LLC Route 726, Mt. Athos Road

    National Nuclear Security Administration (NNSA)

    THE CONTRACT ORDER NO. IN ITEM 10A. 5. PROJECT NO. (If applicable) B. THE ABOVE-NUMBERED ... Engineering Manager Applied TechnologyR&D Manager Maintenance Manager Environment, ...

  6. BWXT Pantex, LLC Route 726, Mt. Athos Road Lynchburg, V

    National Nuclear Security Administration (NNSA)

    and this amendment, and is received 5. PROJECT NO. (If applicable) July 28,2000 - -- ... Engineering Manager Applied TechnologyR&D Manager Maintenance Manager Environment, ...

  7. There's More Than One Route to the Marketplace

    SciTech Connect (OSTI)

    Lambert, Christy M.

    2008-03-01

    PNNL software takes unconventional commercialization path with serial entrepreneur With thousands of researchers working in national laboratories across the country, innovations happen almost every day. Yet many of these innovations never see the light of day. Luckily, when it came to commercializing the much lauded Starlight™ software, Pacific Northwest National Laboratory developed a solution almost as innovative as the technology itself.

  8. A versatile synthetic route for the preparation of titanium metal...

    Office of Scientific and Technical Information (OSTI)

    to mention a general synthetic strategy for various kinds of Ti-MOFs in the literature. ... Sponsoring Org: DOE - BASIC ENERGY SCIENCES Country of Publication: United States Language...

  9. BWXT Pantex, LLC Route 726, Mt. Athos Road

    National Nuclear Security Administration (NNSA)

    ... In the event that overpayment results from the payment of fee on a provisional basis, the Contractor shall reimburse such overpayment to the Government upon demand, payable with ...

  10. An alkyne metathesis-based route toortho-dehydrobenzannulenes

    SciTech Connect (OSTI)

    Miljanic, Ognjen S.; Vollhardt, Peter C.; Whitener, Glenn D.

    2002-11-07

    An application of alkyne metathesis to 1,2-di(prop-1-ynyl)arenes, producing dehydrobenzannulenes, is described. An efficient method for selective Sonogashira couplings of bromoiodoarenes under conditions of microwave irradiation is also reported.

  11. Routes to Ultrahigh Efficiency Photovoltaic and Photoelectrochemical Devices

    SciTech Connect (OSTI)

    Eisler, Carissa; Lloyd, John; Flowers, Cris; Darbe, Sunita; Warmann, Emily; Verlage, Erik; Fountaine, Kate; Hu, Shu; Lewis, Nathan; Atwater, Harry

    2014-10-15

    We discuss ‘full spectrum’ photovoltaic modules that leverage low-cost III-V compound semiconductor cells, efficient optics and unconventional fabrication/assembly methods, and discuss advances in photoelectrochemical water-splitting with high efficiency.

  12. A New Route to Nano Self-Assembly

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... National Science Foundation; DuPont; 3M; Japan Ministry of Education, Science, Sports, and Culture; and the U.S. Department of Energy, Office of Basic Energy Sciences (BES). ...

  13. A New Route to Nano Self-Assembly

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office; National Science Foundation; DuPont; 3M; Japan Ministry of Education, Science, Sports, and Culture; and the U.S. Department of Energy, Office of Basic Energy Sciences...

  14. Diffraction limited focusing and routing of gap plasmons by a

    Office of Scientific and Technical Information (OSTI)

    Nanoscale Science and Technology. 42 ENGINEERING electro-optical devices; integrated optics devices; optical microelectromechanical devices; plasmonics; nanophotonics and...

  15. Routes to trans A,B-substituted bacteriochlorins

    DOE Patents [OSTI]

    Lindsey, Jonathan S.; Mass, Olga

    2016-06-14

    Bacteriochlorin of Formula I: wherein R is H or silyl are described, along with compositions containing the same and methods of making and using the same. ##STR00001##

  16. BWXT Pantex, LLC Route 726, Mt. Athos Road

    National Nuclear Security Administration (NNSA)

    ... Discharge Elimination System 40 CFR 131 Water Quality Standards 40 CFR 133 Secondary ... 40 CFR 141 National Primary Drinking Water Regulations 40 CFR 142 National Primary ...

  17. Property:Incentive/Cont3Phone | Open Energy Information

    Open Energy Info (EERE)

    Cont3Phone Jump to: navigation, search Property Name IncentiveCont3Phone Property Type String Pages using the property "IncentiveCont3Phone" Showing 25 pages using this property....

  18. Property:OutagePhoneNumber | Open Energy Information

    Open Energy Info (EERE)

    OutagePhoneNumber Jump to: navigation, search Property Name OutagePhoneNumber Property Type String Description An outage hotline or 24-hour customer service number Note: uses...

  19. The new phone books are here! | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The new phone books are here In the days of Google search, you may not get as excited as Navin R. Johnson (Steve Martin's character in "The Jerk") that the new phone books are...

  20. Phone List | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phone List SLAC Site Office (SSO) SSO Home About Organization Chart .pdf file (155KB) Phone List Jobs Projects Contract Management NEPA Documents Contact Information SLAC Site Office U.S. Department of Energy Bldg 41, M/S 08A 2575 Sand Hill Road Menlo Park, CA 94025 P: (650) 926-2505 About Phone List Print Text Size: A A A FeedbackShare Page Name Office Phone Other Phone Bazzell, Kevin (650) 926-2513 C: (510) 292-0586 Burke, Patrick (650) 926-8573 C:(510) 459-3184 / BSO: (510) 486-7203 Golan,

  1. Geo Hydro Supply | Open Energy Information

    Open Energy Info (EERE)

    Hydro Supply Jump to: navigation, search Name: Geo Hydro Supply Address: 997 State Route 93 NW Place: Sugarcreek, Ohio Zip: 44681 Sector: Geothermal energy Phone Number:...

  2. Austin Energy Dials Down Home Energy Use With Smart Phones |...

    Energy Savers [EERE]

    Austin Energy Dials Down Home Energy Use With Smart Phones bbrnstoriesaustinenergy9-2-14.jpg Better Buildings Residential Network member Austin Energy used summer's ...

  3. Property:Incentive/ContPhone | Open Energy Information

    Open Energy Info (EERE)

    Type String Pages using the property "IncentiveContPhone" Showing 25 pages using this property. (previous 25) (next 25) 3 30% Business Tax Credit for Solar (Vermont) + (802)...

  4. Phone Numbers for Beam Lines and Other Services | Stanford Synchrotron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Radiation Lightsource Phone Numbers for Beam Lines and Other Services The local area code for SSRL is 650. All numbers listed below should be dialed as 650-926-xxxx from other area codes. When calling an onsite location from within SSRL simply dial the 4-digit extension. When calling an offsite number within the 650 area code dial, dial 9 plus the 7-digit number. To call a number in another area code dial 9-1-area code - phone number. Beam Lines Beam Line Extension 1-4 5214 1-5 5215 2-1 5221

  5. Other Contracting Authority NNSA ORGANIZATION HCA LIMIT PHONE NUMBER

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Other Contracting Authority NNSA ORGANIZATION HCA LIMIT PHONE NUMBER NNSA HQ, NA-63, Deputy Director, Office of Acquisition and Supply Management Barbara H. Stearrett > $25M 202-586-7439 NNSA Service Center, Associate Director, Office of Business Services, Albuquerque, NM Donald J. Garcia < or equal to $25M 505-845-5878 Site offices do not have any HCA authority. NNSA SITE OFFICE CO NAME PHONE M&O CONTRACTOR NAME Bettis/Knolls Atomic Power Laboratory Mark Dickinson 202-781-6237 Bechtel

  6. DOE Office of Nuclear Energy Transportation Planning, Route Selection, and Rail Issues

    Broader source: Energy.gov [DOE]

    Presentation made by Judith Holm, Alex Thrower, Mark Abkowitz, and Tim Runyon for the NTSF annual meeting held from May 14-16, 2013 in Buffalo, NY.

  7. Investigation of some new hydro(solvo)thermal synthesis routes to nanostructured mixed-metal oxides

    SciTech Connect (OSTI)

    Burnett, David L.; Harunsani, Mohammad H.; Kashtiban, Reza J.; Playford, Helen Y.; Sloan, Jeremy; Hannon, Alex C.; Walton, Richard I.

    2014-06-01

    We present a study of two new solvothermal synthesis approaches to mixed-metal oxide materials and structural characterisation of the products formed. The solvothermal oxidation of metallic gallium by a diethanolamine solution of iron(II) chloride at 240 °C produces a crystalline sample of a spinel-structured material, made up of nano-scale particles typically 20 nm in dimension. XANES spectroscopy at the K-edge shows that the material contains predominantly Fe{sup 2+} in an octahedral environment, but that a small amount of Fe{sup 3+} is also present. Careful analysis using transmission electron microscopy and powder neutron diffraction shows that the sample is actually a mixture of two spinel materials: predominantly (>97%) an Fe{sup 2+} phase Ga{sub 1.8}Fe{sub 1.2}O{sub 3.9}, but with a minor impurity phase that is iron-rich. In contrast, the hydrothermal reaction of titanium bis(ammonium lactato)dihydroxide in water with increasing amounts of Sn(IV) acetate allows nanocrystalline samples of the SnO{sub 2}–TiO{sub 2} solid solution to be prepared directly, as proved by powder XRD and Raman spectroscopy. - Graphical abstract: New solvothermal synthesis approaches to spinel and rutile mixed-metal oxides are reported. - Highlights: • Solvothermal oxidation of gallium metal in organic iron(II) solution gives a novel iron gallate spinel. • Hydrothermal reaction of titanium(IV) complex and tin(IV) acetate produces the complete SnO{sub 2}–TiO{sub 2} solid solution. • Nanostructured mixed-metal oxide phases are produced directly from solution.

  8. Immobilization as a route to surplus fissile materials disposition. Revision 1

    SciTech Connect (OSTI)

    Gray, L.W.; Kan, T.; McKibben, J.M.

    1996-03-15

    The safe management of surplus weapons plutonium is a very important and urgent task with profound environmental, national and international security implications. In the aftermath of the Cold War, Presidential Police Directive 13 and various analysis by renown scientific, technical and international policy organizations have brought about a focused effort within the Department of Energy to identify and implement paths forward for the long term disposition of surplus weapons usable plutonium. The central, overarching goal is to render surplus weapons plutonium as inaccessible and unattractive for reuse in nuclear weapons, as the much larger and growing stock of plutonium contained in civilian spent reactor fuel. One disposition alternative considered for surplus Pu is immobilization, in which plutonium would be emplaced in glass, ceramic or glass-bonded zeolite. This option, along with some of the progress over the last year is discussed.

  9. A Route to Scale up DNA Origami Using DNA Tiles as Folding Staples

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemie International Edition Year: 2010 Volume: 49 Pages: 1414-1417 ABSTRACT: A new strategy is presented to scale up DNA origami using multi-helical DNA tiles as folding...

  10. Lambda Station: On-demand flow based routing for data intensive Grid applications over multitopology networks

    SciTech Connect (OSTI)

    Bobyshev, A.; Crawford, M.; DeMar, P.; Grigaliunas, V.; Grigoriev, M.; Moibenko, A.; Petravick, D.; Rechenmacher, R.; Newman, H.; Bunn, J.; Van Lingen, F.; Nae, D.; Ravot, S.; Steenberg, C.; Su, X.; Thomas, M.; Xia, Y.; /Caltech

    2006-08-01

    Lambda Station is an ongoing project of Fermi National Accelerator Laboratory and the California Institute of Technology. The goal of this project is to design, develop and deploy network services for path selection, admission control and flow based forwarding of traffic among data-intensive Grid applications such as are used in High Energy Physics and other communities. Lambda Station deals with the last-mile problem in local area networks, connecting production clusters through a rich array of wide area networks. Selective forwarding of traffic is controlled dynamically at the demand of applications. This paper introduces the motivation of this project, design principles and current status. Integration of Lambda Station client API with the essential Grid middleware such as the dCache/SRM Storage Resource Manager is also described. Finally, the results of applying Lambda Station services to development and production clusters at Fermilab and Caltech over advanced networks such as DOE's UltraScience Net and NSF's UltraLight is covered.