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1

Fabrication of a Miniaturized Room Temperature Ionic Liquid Gas Sensor for Human Health and  

E-Print Network (OSTI)

Fabrication of a Miniaturized Room Temperature Ionic Liquid Gas Sensor for Human Health and Safety temperature ionic liquid (RTIL) gas sensors utilizing electrochemical instrumentation demonstrate promising that enables miniaturized, rapid response, gas sensors to be realized using RTIL interfaces on a permeable

Mason, Andrew

2

Electrochemical Windows of Room-Temperature Ionic Liquids from Molecular Dynamics and Density Functional Theory Calculations  

E-Print Network (OSTI)

We investigated the cathodic and anodic limits of six room-temperature ionic liquids (ILs) formed from a combination of two common cations, 1-butyl-3-methylimidazolium (BMIM) and N,N-propylmethylpyrrolidinium (P13), and ...

Ong, Shyue Ping

3

Benzyl-Functionalized Room Temperature Ionic Liquids for CO2/N2 Separation  

Science Conference Proceedings (OSTI)

In this work, three classes of room temperature ionic liquids (RTILs), including imidazolium, pyridinium, and pyrrolidinium ionic liquids with a benzyl group appended to the cation, were synthesized and tested for their performance in separating CO{sub 2} and N{sub 2}. All RTILs contained the bis(trifluoromethylsulfonyl)imide anion, permitting us to distinguish the impact of the benzyl moiety attached to the cation on gas separation performance. In general, the attachment of the benzyl group increased the viscosity of the ionic liquid compared with the unfunctionalized analogs and decreased the CO{sub 2} permeability. However, all of the benzyl-modified ionic liquids exhibited enhanced CO{sub 2}/N{sub 2} selectivities compared with alkyl-based ionic liquids, with values ranging from 22.0 to 33.1. In addition, CO{sub 2} solubilities in the form of Henry's constants were also measured and compared with unfunctionalized analogs. Results of the membrane performance tests and CO{sub 2} solubility measurements demonstrate that the benzyl-functionalized RTILs have significant potential for use in the separation of carbon dioxide from combustion products.

Mahurin, Shannon Mark [ORNL; Dai, Thomas N [ORNL; Yeary, Joshua S [ORNL; Luo, Huimin [ORNL; Dai, Sheng [ORNL

2011-01-01T23:59:59.000Z

4

Supported Room Temperature Ionic Liquid Membranes for CO{sub 2}/CH{sub 4} Separation  

SciTech Connect

Room temperature ionic liquids (RTILs) are organic salts which are liquid at or around room temperature. These compounds exhibit many outstanding physical properties such as great thermal stability and no measurable vapor pressure. In this work supported ionic liquid membranes (SILMs) were prepared by impregnating pores of ?-alumina inorganic supports with various ionic liquids. In addition to membranes prepared with pure RTILs we were able to synthesize membranes with RTIL mixtures using 1-aminopyridinium iodide dissolved in 1-butyl-4-methylpyridinium tetrafluoroborate or methyltrioctylammonium bis(trifluoromethylsulfonyl)imide. This combination of an RTIL with an organic salt containing an amine group dramatically improved the membrane separation properties. The SILMs displayed CO{sub 2} permeance on the order of 5 × 10{sup ?10} to 5 × 10{sup ?9} mol m{sup ?2} s{sup ?1} Pa{sup ?1} combined with CO{sub 2}/CH{sub 4} selectivity of 5–30. Although these values are comparable with the current systems for CO{sub 2} purification, CO{sub 2} permeance is still rather low for these compounds.

Iarikov, D. D.; Hacarlioglu, P.; Oyama, S. T.

2011-01-01T23:59:59.000Z

5

From molten salts to room temperature ionic liquids: Simulation studies on chloroaluminate systems  

E-Print Network (OSTI)

An interaction potential including chloride anion polarization effects, constructed from first-principles calculations, is used to examine the structure and transport properties of a series of chloroaluminate melts. A particular emphasis was given to the study of the equimolar mixture of aluminium chloride with 1-ethyl-3-methylimidazolium chloride, which forms a room temperature ionic liquid EMI-AlCl 4. The structure yielded by the classical simulations performed within the framework of the polarizable ion model is compared to the results obtained from entirely electronic structure-based simulations: An excellent agreement between the two flavors of molecular dynamics is observed. When changing the organic cation EMI+ by an inorganic cation with a smaller ionic radius (Li+, Na+, K+), the chloroaluminate speciation becomes more complex, with the formation of Al2Cl 7- in small amounts. The calculated transport properties (diffusion coefficients, electrical conductivity and viscosity) of EMI-AlCl4 are in good ag...

Salanne, Mathieu; Seitsonen, Ari P; Madden, Paul A; Kirchner, Barbara; 10.1039/C1FD00053E

2013-01-01T23:59:59.000Z

6

Ionic liquid pretreatment of poplar wood at room temperature: swelling and incorporation of nanoparticles  

DOE Green Energy (OSTI)

Lignocellulosic biomass represents a potentially sustainable source of liquid fuels and commodity chemicals. It could satisfy the energy needs for transportation and electricity generation, while contributing substantially to carbon sequestration and limiting the accumulation of greenhouse gases in the atmosphere. Potential feedstocks are abundant and include crops, agricultural wastes, forest products, grasses, and algae. Among those feedstocks, wood is mainly constituted of three components: cellulose, hemicellulose, and lignin. The conversion process of lignocellulosic biomass typically consists of three steps: (1) pretreatment; (2) hydrolysis of cellulose and hemicellulose into fermentable sugars; and (3) fermentation of the sugars into liquid fuels (ethanol) and other commodity chemicals. The pretreatment step is necessary due to the complex structure of the plant cell wall and the chemical resistance of lignin. Most current pretreatments are energy-intensive and/or polluting. So it is imperative to develop new pretreatments that are economically viable and environmentally friendly. Recently, ionic liquids have attracted considerable interest, due to their ability to dissolve biopolymers, such as cellulose, lignin, native switchgrass, and others. Ionic liquids are also considered green solvents, since they have been successfully recycled at high yields for further use with limited efficiency loss. Also, a few microbial cellulases remain active at high ionic liquid concentration. However, all studies on the dissolution of wood in ionic liquids have been conducted so far at high temperatures, typically above 90 C. Development of alternative pretreatments at room temperature is desirable to eliminate the additional energy cost. In this study, thin sections of poplar wood were swollen at room temperature by a 3 h ionic liquid (1-ethyl-3-methylimidazolium acetate or EMIMAc) pretreatment. The pretreated sample was then exposed to an aqueous suspension of nanoparticles that resulted in the sample contraction and the deposition of nanoparticles onto the surface and embedded into the cell wall. To date, both silver and gold particles ranging in size from 40-100 nm have been incorporated into wood. Penetration of gold nanoparticles of 100 nm diameter in the cell walls was best confirmed by near-infrared confocal Raman microscopy, since the deposition of gold nanoparticles induces a significant enhancement of the Raman signal from the wood in their close proximity, an enhancement attributed to the surface-enhanced Raman effect (SERS). After rinsing with water, scanning electron microscopy (SEM) and Raman images of the same areas show that most nanoparticles remained on the pretreated sample. Raman images at different depths reveal that a significant number of nanoparticles were incorporated into the wood sample, at depths up to 4 {micro}m, or 40 times the diameter of the nanoparticles. Control experiments on an untreated wood sample resulted in the deposition of nanoparticles only at the surface and most nanoparticles were removed upon rinsing. This particle incorporation process enables the development of new pretreatments, since the nanoparticles have a high surface-to-volume ratio and could be chemically functionalized. Other potential applications for the incorporated nanoparticles include isotope tracing, catalysis, imaging agents, drug-delivery systems, energy-storage devices, and chemical sensors.

Lucas, Marcel [Los Alamos National Laboratory; Macdonald, Brian A [Los Alamos National Laboratory; Wagner, Gregory L [Los Alamos National Laboratory; Joyce, Steven A [Los Alamos National Laboratory; Rector, Kirk D [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

7

Synthesis and Characterization of Thiazolium-Based Room Temperature Ionic Liquids for Gas Separations  

SciTech Connect

A series of novel thiazolium-bis(triflamide) based ionic liquids has been synthesized and characterized. Physicochemical properties of the ionic liquids such as thermal stability, phase transitions, and infrared spectra were analysed and compared to the imidazolium-based congeners. Several unique classes of ancillary substitutions are examined with respect to impacts on overall structure, in addition to their carbon dioxide absorption properties in supported ionic-liquid membranes for gas separation.

Hillesheim, Patrick C [ORNL; Mahurin, Shannon Mark [ORNL; Fulvio, Pasquale F [ORNL; Yeary, Joshua S [ORNL; Oyola, Yatsandra [ORNL; Jiang, Deen [ORNL; Dai, Sheng [ORNL

2012-01-01T23:59:59.000Z

8

Investigation of the Effect of Functional Group Substitutions on the Gas-Phase Electron Affinities and Ionization Energies of Room-Temperature Ionic Liquids Ions using Density Functional Theory  

E-Print Network (OSTI)

The cathodic and anodic stabilities of room-temperature ionic liquids (ILs) are important factors in their applications in electrochemical devices. In this work, we investigated the electron affinities of cations and ...

Ong, Shyue Ping

9

Dispenser Printed Zinc Microbattery with an Ionic Liquid Gel Electrolyte  

E-Print Network (OSTI)

Ionic liquids are molten salts with high ionic conductivity,ionic liquids are aprotic molten salts at room temperatures

Ho, Christine Chihfan

2010-01-01T23:59:59.000Z

10

Room temperature terahertz polariton emitter  

SciTech Connect

Terahertz (THz) range electroluminescence from intersubband polariton states is observed in the ultra strong coupling regime, where the interaction energy between the collective excitation of a dense electron gas and a photonic mode is a significant portion of the uncoupled excitation energy. The polariton's increased emission efficiency along with a parabolic electron confinement potential allows operation up to room temperature in a nonresonant pumping scheme. This observation of room temperature electroluminescence of an intersubband device in the THz range is a promising proof of concept for more powerful THz sources.

Geiser, Markus; Scalari, Giacomo; Castellano, Fabrizio; Beck, Mattias; Faist, Jerome [Institute for Quantum Electronics, ETH Zurich, Wolfgang-Pauli-Strasse 16, 8093 Zurich (Switzerland)

2012-10-01T23:59:59.000Z

11

Novel room temperature ferromagnetic semiconductors  

SciTech Connect

Today's information world, bits of data are processed by semiconductor chips, and stored in the magnetic disk drives. But tomorrow's information technology may see magnetism (spin) and semiconductivity (charge) combined in one 'spintronic' device that exploits both charge and 'spin' to carry data (the best of two worlds). Spintronic devices such as spin valve transistors, spin light emitting diodes, non-volatile memory, logic devices, optical isolators and ultra-fast optical switches are some of the areas of interest for introducing the ferromagnetic properties at room temperature in a semiconductor to make it multifunctional. The potential advantages of such spintronic devices will be higher speed, greater efficiency, and better stability at a reduced power consumption. This Thesis contains two main topics: In-depth understanding of magnetism in Mn doped ZnO, and our search and identification of at least six new above room temperature ferromagnetic semiconductors. Both complex doped ZnO based new materials, as well as a number of nonoxides like phosphides, and sulfides suitably doped with Mn or Cu are shown to give rise to ferromagnetism above room temperature. Some of the highlights of this work are discovery of room temperature ferromagnetism in: (1) ZnO:Mn (paper in Nature Materials, Oct issue, 2003); (2) ZnO doped with Cu (containing no magnetic elements in it); (3) GaP doped with Cu (again containing no magnetic elements in it); (4) Enhancement of Magnetization by Cu co-doping in ZnO:Mn; (5) CdS doped with Mn, and a few others not reported in this thesis. We discuss in detail the first observation of ferromagnetism above room temperature in the form of powder, bulk pellets, in 2-3 mu-m thick transparent pulsed laser deposited films of the Mn (<4 at. percent) doped ZnO. High-resolution transmission electron microscopy (HRTEM) and electron energy loss spectroscopy (EELS) spectra recorded from 2 to 200nm areas showed homogeneous distribution of Mn substituting for Zn a 2+ state in the ZnO lattice. Ferromagnetic Resonance (FMR) technique is used to confirm the existence of ferromagnetic ordering at temperatures as high as 425K. The ab initio calculations were found to be consistent with the observation of ferromagnetism arising from fully polarized Mn 2+ state. The key to observed room temperature ferromagnetism in this system is the low temperature processing, which prevents formation of clusters, secondary phases and the host ZnO from becoming n-type. The electronic structure of the same Mn doped ZnO thin films studied using XAS, XES and RIXS, revealed a strong hybridization between Mn 3d and O 2p states, which is an important characteristic of a Dilute magnetic Semiconductor (DMS). It is shown that the various processing conditions like sintering temperature, dopant concentration and the properties of precursors used for making of DMS have a great influence on the final properties. Use of various experimental techniques to verify the physical properties, and to understand the mechanism involved to give rise to ferromagnetism is presented. Methods to improve the magnetic moment in Mn doped ZnO are also described. New promising DMS materials (such as Cu doped ZnO are explored). The demonstrated new capability to fabricate powder, pellets, and thin films of room temperature ferromagnetic semiconductors thus makes possible the realization of a wide range of complex elements for a variety of new multifunctional phenomena related to Spintronic devices as well as magneto-optic components.

Gupta, Amita

2004-11-01T23:59:59.000Z

12

Room temperature nano- and microstructure photon detectors  

Science Conference Proceedings (OSTI)

The development of room temperature infrared (IR) detectors for wavelengths beyond NIR will open up many applications that are currently limited due to cooling requirements. Three approaches are discussed, which show promise for room temperature IR detection. ... Keywords: Infrared, PbS quantum dot, Room temperature detector, Split-off band, Tunneling quantum dot

A. G. U. Perera; P. V. V. Jayaweera; G. Ariyawansa; S. G. Matsik; K. Tennakone; M. Buchanan; H. C. Liu; X. H. Su; P. Bhattacharya

2009-03-01T23:59:59.000Z

13

Electrorecovery of actinides at room temperature  

Science Conference Proceedings (OSTI)

There are a large number of purification and processing operations involving actinide species that rely on high-temperature molten salts as the solvent medium. One such application is the electrorefining of impure actinide metals to provide high purity material for subsequent applications. There are some drawbacks to the electrodeposition of actinides in molten salts including relatively low yields, lack of accurate potential control, maintaining efficiency in a highly corrosive environment, and failed runs. With these issues in mind we have been investigating the electrodeposition of actinide metals, mainly uranium, from room temperature ionic liquids (RTILs) and relatively high-boiling organic solvents. The RTILs we have focused on are comprised of 1,3-dialkylimidazolium or quaternary ammonium cations and mainly the {sup -}N(SO{sub 2}CF{sub 3}){sub 2} anion [bis(trif1uoromethylsulfonyl)imide {equivalent_to} {sup -}NTf{sub 2}]. These materials represent a class of solvents that possess great potential for use in applications employing electrochemical procedures. In order to ascertain the feasibility of using RTILs for bulk electrodeposition of actinide metals our research team has been exploring the electron transfer behavior of simple coordination complexes of uranium dissolved in the RTIL solutions. More recently we have begun some fundamental electrochemical studies on the behavior of uranium and plutonium complexes in the organic solvents N-methylpyrrolidone (NMP) and dimethylsulfoxide (DMSO). Our most recent results concerning electrodeposition will be presented in this account. The electrochemical behavior of U(IV) and U(III) species in RTILs and the relatively low vapor pressure solvents NMP and DMSO is described. These studies have been ongoing in our laboratory to uncover conditions that will lead to the successful bulk electrodeposition of actinide metals at a working electrode surface at room temperature or slightly elevated temperatures. The RTILs we have focused on thus far are based on 1,3-dialkylimidazolium or quaternary ammonium cations and {sup -}N(SO{sub 2}CF{sub 3}){sub 2} anions. Our results from XPS studies of e1ectrooxidized uranium metal surfaces indicate that uranium metal reacts with the anion from the RTIL, most likely through an initial f1uoride abstraction, forming decomposition products that inhibit the bulk electrodeposition of uranium metal. Similar results were found when the organic solvents were used with TBA[B(C{sub 6}F{sub 5}){sub 4}] as the supporting electrolyte, although the voltammetric data of uranium ions in these solutions is more encouraging in relation to electrodeposition of uranium metal. Preliminary results on the voltammetric behavior and bulk electrodeposition of plutonium species are also presented.

Stoll, Michael E [Los Alamos National Laboratory; Oldham, Warren J [Los Alamos National Laboratory; Costa, David A [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

14

Low Temperature Reduction of Alumina Using Fluorine Containing Ionic Liquids  

SciTech Connect

The major objective of the project is to establish the feasibility of using specific ionic liquids capable of sustaining aluminum electrolysis near room temperature at laboratory and batch recirculation scales. It will explore new technologies for aluminum and other valuable metal extraction and process methods. The new technology will overcome many of the limitations associated with high temperatures processes such as high energy consumption and corrosion attack. Furthermore, ionic liquids are non-toxic and could be recycled after purification, thus minimizing extraction reagent losses and environmental pollutant emissions. Ionic liquids are mixture of inorganic and organic salts which are liquid at room temperature and have wide operational temperature range. During the last several years, they were emerging as novel electrolytes for extracting and refining of aluminum metals and/or alloys, which are otherwise impossible using aqueous media. The superior high temperature characteristics and high solvating capabilities of ionic liquids provide a unique solution to high temperature organic solvent problems associated with device internal pressure build-up, corrosion, and thermal stability. However their applications have not yet been fully implemented due to the insufficient understanding of the electrochemical mechanisms involved in processing of aluminum with ionic liquids. Laboratory aluminum electrodeposition in ionic liquids has been investigated in chloride and bis (trifluoromethylsulfonyl) imide based ionic liquids. The electrowinning process yielded current density in the range of 200-500 A/m2, and current efficiency of about 90%. The results indicated that high purity aluminum (>99.99%) can be obtained as cathodic deposits. Cyclic voltammetry and chronoamperometry studies have shown that initial stages of aluminum electrodeposition in ionic liquid electrolyte at 30°C was found to be quasi-reversible, with the charge transfer coefficient (0.40). Nucleation phenomena involved in aluminum deposition on copper in AlCl3-BMIMCl electrolyte was found to be instantaneous followed by diffusion controlled three-dimensional growth of nuclei. Diffusion coefficient (Do) of the electroactive species Al2Cl7¯ ion was in the range from 6.5 to 3.9×10–7 cm2?s–1 at a temperature of 30°C. Relatively little research efforts have been made toward the fundamental understanding and modeling of the species transport and transformation information involved in ionic liquid mixtures, which eventually could lead to quantification of electrochemical properties. Except that experimental work in this aspect usually is time consuming and expensive, certain characteristics of ionic liquids also made barriers for such analyses. Low vapor pressure and high viscosity make them not suitable for atomic absorption spectroscopic measurement. In addition, aluminum electrodeposition in ionic liquid electrolytes are considered to be governed by multi-component mass, heat and charge transport in laminar and turbulent flows that are often multi-phase due to the gas evolution at the electrodes. The kinetics of the electrochemical reactions is in general complex. Furthermore, the mass transfer boundary layer is about one order of magnitude smaller than the thermal and hydrodynamic boundary layer (Re=10,000). Other phenomena that frequently occur are side reactions and temperature or concentration driven natural convection. As a result of this complexity, quantitative knowledge of the local parameters (current densities, ion concentrations, electrical potential, temperature, etc.) is very difficult to obtain. This situation is a serious obstacle for improving the quality of products, efficiency of manufacturing and energy consumption. The gap between laboratory/batch scale processing with global process control and nanoscale deposit surface and materials specifications needs to be bridged. A breakthrough can only be realized if on each scale the occurring phenomena are understood and quantified. Multiscale numerical modeling nevertheless can help t

Dr. R. G. Reddy

2007-09-01T23:59:59.000Z

15

Thermostat response and room temperature control  

Science Conference Proceedings (OSTI)

This article examines the impact to thermal comfort of the operation of the room thermostat. The topics of the article include types of thermostat response, reset response, proportional response, digital systems, system response, verification of building temperatures, thermal comfort analysis, and productivity costs of implementing mandated setpoints.

Int-Hout, D. (Carrier Corp., Syracuse, NY (United States))

1994-01-01T23:59:59.000Z

16

Matchstick: A Room-to-Room Thermal Model for Predicting Indoor Temperature from Wireless Sensor Data  

E-Print Network (OSTI)

Matchstick: A Room-to-Room Thermal Model for Predicting Indoor Temperature from Wireless Sensor present a room-to-room thermal model used to accurately predict temperatures in residential buildings. We that our model can predict future indoor temperature trends with a 90th percentile aggregate error between

Hazas, Mike

17

Ionic liquids for rechargeable lithium batteries  

E-Print Network (OSTI)

M. Armand, “Room temperature molten salts as lithium batteryZ. Suarez, “Ionic liquid (molten salt) phase organometallic

Salminen, Justin; Papaiconomou, Nicolas; Kerr, John; Prausnitz, John; Newman, John

2008-01-01T23:59:59.000Z

18

Ionic Solid Oxides for High Temperature Optical Gas Sensing in ...  

Science Conference Proceedings (OSTI)

Presentation Title, Ionic Solid Oxides for High Temperature Optical Gas Sensing in Fossil Fuel Based Power Plants. Author(s), Junhang Dong, Xiling Tang, Kurtis  ...

19

Absorber Materials at Room and Cryogenic Temperatures  

Science Conference Proceedings (OSTI)

We recently reported on investigations of RF absorber materials at cryogenic temperatures conducted at Jefferson Laboratory (JLab). The work was initiated to find a replacement material for the 2 Kelvin low power waveguide Higher Order Mode (HOM) absorbers employed within the original cavity cryomodules of the Continuous Electron Beam Accelerator Facility (CEBAF). This effort eventually led to suitable candidates as reported in this paper. Furthermore, though constrained by small funds for labor and resources, we have analyzed a variety of lossy ceramic materials, several of which could be usable as HOM absorbers for both normal conducting and superconducting RF structures, e.g. as loads in cavity waveguides and beam tubes either at room or cryogenic temperatures and, depending on cooling measures, low to high operational power levels.

F. Marhauser, T.S. Elliott, A.T. Wu, E.P. Chojnacki, E. Savrun

2011-09-01T23:59:59.000Z

20

Carbon promoted water electrolysis to produce hydrogen at room temperature.  

E-Print Network (OSTI)

??The objective of the work was to conduct water electrolysis at room temperature with reduced energy costs for hydrogen production. The electrochemical gasification of carbons… (more)

Ranganathan, Sukanya.

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Matchstick: a room-to-room thermal model for predicting indoor temperature from wireless sensor data  

Science Conference Proceedings (OSTI)

In this paper we present a room-to-room thermal model used to accurately predict temperatures in residential buildings. We evaluate the accuracy of this model with ground truth data from four occupied family homes (two in the UK and two in the US). The ... Keywords: forced air, home automation, prediction, radiators, thermal modelling, underfloor heating

Carl Ellis; Mike Hazas; James Scott

2013-04-01T23:59:59.000Z

22

Quantitative room-temperature mineralization of airborne formaldehyde using  

NLE Websites -- All DOE Office Websites (Extended Search)

Quantitative room-temperature mineralization of airborne formaldehyde using Quantitative room-temperature mineralization of airborne formaldehyde using manganese oxide catalysts Title Quantitative room-temperature mineralization of airborne formaldehyde using manganese oxide catalysts Publication Type Journal Article Year of Publication 2011 Authors Sidheswaran, Meera A., Hugo Destaillats, Douglas P. Sullivan, Joern Larsen, and William J. Fisk Journal Applied Catalysis B - Environmental Issue 107 Pagination 34-41 Date Published 2011 Keywords commercial building ventilation & indoor environmental quality group, commercial building ventilation and indoor environmental quality group, energy analysis and environmental impacts department, indoor environment department, indoor environment group DOI 10.1016/j.apcatb.2011.06.032 Attachment Size

23

Near room temperature lithographically processed metal-oxide transistors  

E-Print Network (OSTI)

A fully lithographic process at near-room-temperature was developed for the purpose of fabricating transistors based on metal-oxide channel materials. The combination of indium tin oxide (ITO) as the source/drain electrodes, ...

Tang, Hui, M. Eng. Massachusetts Institute of Technology

2008-01-01T23:59:59.000Z

24

Control and Room Temperature Optimization of Energy Efficient Buildings  

SciTech Connect

The building sector consumes a large part of the energy used in the United States and is responsible for nearly 40% of greenhouse gas emissions. It is therefore economically and environmentally important to reduce the building energy consumption to realize massive energy savings. In this paper, a method to control room temperature in buildings is proposed. The approach is based on a distributed parameter model represented by a three dimensional (3D) heat equation in a room with heater/cooler located at ceiling. The latter is resolved using finite element methods, and results in a model for room temperature with thousands of states. The latter is not amenable to control design. A reduced order model of only few states is then derived using Proper Orthogonal Decomposition (POD). A Linear Quadratic Regulator (LQR) is computed based on the reduced model, and applied to the full order model to control room temperature.

Djouadi, Seddik M [ORNL; Kuruganti, Phani Teja [ORNL

2012-01-01T23:59:59.000Z

25

Ionic liquid ion source emitter arrays fabricated on bulk porous substrates for spacecraft propulsion  

E-Print Network (OSTI)

Ionic Liquid Ion Sources (ILIS) are a subset of electrospray capable of producing bipolar beams of pure ions from ionic liquids. Ionic liquids are room temperature molten salts, characterized by negligible vapor pressures, ...

Courtney, Daniel George

2011-01-01T23:59:59.000Z

26

Determination of the Acceptable Room Temperature Range for Local Cooling  

E-Print Network (OSTI)

Determination of the acceptable room temperature range is a key problem in satisfactory design of local cooling for energy savings. At the room temperatures ranging from neutral to warm, three sensitive body parts-the face, chest and back-were each exposed to local cooling airflow, where temperatures were 22, 25 and 28°C. Thirty randomly-selected male subjects, dressed in shorts, were exposed to each condition for 30 minutes. Data were collected on their local thermal sensations of each body part, overall thermal sensation, and overall thermal acceptability on voting scales at regular intervals during the exposure. Results show that the non-uniformity of thermal sensation is a key factor affecting thermal acceptability except for overall thermal sensation. A new assessment model for local cooling was proposed. The model shows that face cooling can improve thermal acceptability more than chest or back cooling, and the upper boundary of the acceptable range of room temperature can be shifted from 26°C to 30.5°C when face cooling is provided.

Zhang, Y.; Zhao, R.

2006-01-01T23:59:59.000Z

27

Energy Consumption Estimation for Room Air-conditioners Using Room Temperature Simulation with One-Minute Intervals  

E-Print Network (OSTI)

For the purpose of developing optimized control algorithm for room air-conditioners to ensure their energy efficiency, a short time interval (i.e., one minute) simulation of building thermal performance is necessary because the sampling time interval for room air-conditioner control is one minute in general. This paper studies the short-time interval room air temperature simulation method using the response factor method. Using the simulated room air temperature, an air-conditioner's running time can be known so that its energy consumption can be estimated accurately. In order to verify the simulation accuracy, an actual room equipped with a gas-engine heat pump (GHP) air-conditioning system is studied by both simulation and measurement. The cooling amount produced by the GHP is calculated using measured refrigerant pressure and temperature at condenser and evaporator respectively. The Root Mean Square Error (RMSE) between measured cooling amount and simulated cooling load is 18.9 percent of the average measured value. The profile of simulated room air temperature in both air-conditioned daytime and nighttime without air-conditioning can match the measured room air temperature. With respect to the estimated energy consumption, the profile of simulated energy consumption can match the measured data. The simulation accuracy of room air temperature and energy consumption during the air-conditioner start-up period is not good and needs to be improved in future research. But in general, the verification shows that this energy consumption simulation method is acceptable for evaluating the energy performance of a room air-conditioner, and can also be a useful tool for commissioning room air-conditioners.

Wang, F.; Yoshida, H.; Matsumoto, K.

2006-01-01T23:59:59.000Z

28

Generation of coherent terahertz pulses in ruby at room temperature  

Science Conference Proceedings (OSTI)

We have shown that a coherently driven solid state medium can potentially produce strong controllable short pulses of THz radiation. The high efficiency of the technique is based on excitation of maximal THz coherence by applying resonant optical pulses to the medium. The excited coherence in the medium is connected to macroscopic polarization coupled to THz radiation. We have performed detailed simulations by solving the coupled density matrix and Maxwell equations. By using a simple V-type energy scheme for ruby, we have demonstrated that the energy of generated THz pulses ranges from hundreds of pico-Joules to nano-Joules at room temperature and micro-Joules at liquid helium temperature, with pulse durations from picoseconds to tens of nanoseconds. We have also suggested a coherent ruby source that lases on two optical wavelengths and simultaneously generates THz radiation. We discussed also possibilities of extension of the technique to different solid-state materials.

Kuznetsova, Elena; Rostovtsev, Yuri; Kalugin, Nikolai G.; Kolesov, Roman; Kocharovskaya, Olga [Institute for Quantum Studies and Department of Physics, Texas A and M University, College Station, Texas 77843 (United States); Scully, Marlan O. [Institute for Quantum Studies and Department of Physics, Texas A and M University, College Station, Texas 77843 (United States); Princeton Institute for Material Science and Department of Mechanical and Aerospace Engineering, Princeton University, New Jersey 08544 (United States)

2006-08-15T23:59:59.000Z

29

Observation of visible luminescence from indium nitride at room temperature  

SciTech Connect

InN films were grown on sapphire substrates with AlN buffer layers by reactive sputtering. C-axis-oriented crystalline InN films with a wurtzite structure were confirmed by x-ray diffraction and Raman scattering. Strong photoluminescence (PL) at 1.87 eV, together with a clear absorption edge at 1.97 eV, was observed at room temperature, which clearly demonstrates that it is not accurate in the previous assignment of an {approx}0.7 eV fundamental band gap for intrinsic InN simply from PL and absorption data. The possible origin of the present large band gap was discussed in terms of the effects of oxygen and the Burstein-Moss shift.

Guo, Q.X.; Tanaka, T.; Nishio, M.; Ogawa, H.; Pu, X.D.; Shen, W.Z. [Department of Electrical and Electronic Engineering, Saga University, Saga 840-8502 (Japan); Laboratory of Condensed Matter Spectroscopy and Opto-Electronic Physics, Department of Physics, Shanghai Jiao Tong University, 1954 Hua Shan Road, Shanghai 200030 (China)

2005-06-06T23:59:59.000Z

30

200-GeV ISA with room temperature magnets  

SciTech Connect

A conceptual design study of 200-GeV proton intersecting storage accclerators with room temperature magnets is presented. The key to this study was thc desire to keep the electric power consumptiom to an acceptable level (40 MW). The design has been optimized by choosing small-gap (4 cm) aluminum coil dipoles operating at about 15 kG. The luminosity of this machine is limited to about 10/sup 32/ cm-/sup -2/ sec/sup -1/ by transverse space-charg e effects. An order of magnitude higher luminositics can be obtained by adding a booster of modest cost. A novel vacuum system using distributed Ti-sublimation pumps results in considerable savings. A cost comparison with a high-luminosity superconducting machine is given. (auth)

Willis, W.J.; Danby, G.T.; Hahn, H.; Halama, H.J.; Maschke, A.W.; Month, M.; Parzen, G.; Polk, I.

1974-02-11T23:59:59.000Z

31

Road to room-temperature superconductivity: A universal model  

E-Print Network (OSTI)

In a semiclassical view superconductivity is attributed exclusively to the advance of atoms' outer s electrons through the nuclei of neighbor atoms in a solid. The necessary progression of holes in the opposite direction has the electric and magnetic effect as if two electrons were advancing instead of each actual one. Superconductivity ceases when the associated lateral oscillation of the outer s electrons extends between neighbor atoms. If such overswing occurs already at T = 0, then the material is a normal conductor. Otherwise, lateral overswing can be caused by lattice vibrations at a critical temperature Tc or by a critical magnetic field Bc. Lateral electron oscillations are reduced - and Tc is increased - when the atoms of the outer s electrons are squeezed, be it in the bulk crystal, in a thin film, or under external pressure on the sample. The model is applied to alkali metals and alkali-doped fullerenes. Aluminum serves as an example of a simple metal with superconductivity. Application of the model to transition metals, intertransitional alloys and compounds of transition metals with other elements sheds light on the pattern of their critical temperature. More examples of the squeeze effect are provided by the superconductivity of PdH, MgB2, borocarbides, ferropnictides, and organic charge-transfer salts. The model also provides the superconduction mechanism in the oxide superconductors, exemplified by YBa2Cu3O7. Finally the model suggests which steps to take in order to reach superconductivity at room temperature and above.

Manfred Bucher

2013-02-15T23:59:59.000Z

32

Pysico-chemical properties of hydrophobic ionic liquids containing 1-octylpyridinium, 1-octyl-2-methylpyridinium or 1-octyl-4-methylpyridinium cations  

E-Print Network (OSTI)

P. A. Z. Ionic liquid (molten salt) phase organometallicambient-temperature molten salts. Inorg. Chem. 1996, 35,are room-temperature molten salts with melting points near

Papaiconomou, Nicolas; Salminen, Justin; Lee, Jong-Min; Prausnitz, John M.

2006-01-01T23:59:59.000Z

33

Synthesis of ionic liquids  

DOE Patents (OSTI)

Ionic compounds which are liquids at room temperature are formed by the method of mixing a neutral organic ligand with the salt of a metal cation and its conjugate anion. The liquids are hydrophobic, conductive and stable and have uses as solvents and in electrochemical devices.

Dai, Sheng (Knoxville, TN); Luo, Huimin (Knoxville, TN)

2011-11-01T23:59:59.000Z

34

BSA 07-22: Compact Room-Temperature Radiation Detector for Oil ...  

These small, solid-state radiation detectors can be used at room temperature, making them more practical, mobile, and cost-effective than existing devices.

35

10:20AM, P1 Room Temperature Lasing From Excited Stated of ...  

Science Conference Proceedings (OSTI)

Quantum dots formed by highly strained epilayers undergoing a ... The quantum dots demonstrate room temperature photoluminescence at 1.32 um with a full ...

36

BSA 07-22: Compact Room-Temperature Radiation Detector for Oil ...  

BSA 07-22: Compact Room-Temperature Radiation Detector for Oil & Gas Exploration. BNL Reference Number: BSA 07-22. Patent Status: U.S. Patent ...

37

Ionic liquids and ionic liquid acids with high temperature stability for fuel cell and other high temperature applications, method of making and cell employing same  

DOE Patents (OSTI)

Disclosed are developments in high temperature fuel cells including ionic liquids with high temperature stability and the storage of inorganic acids as di-anion salts of low volatility. The formation of ionically conducting liquids of this type having conductivities of unprecedented magnitude for non-aqueous systems is described. The stability of the di-anion configuration is shown to play a role in the high performance of the non-corrosive proton-transfer ionic liquids as high temperature fuel cell electrolytes. Performance of simple H.sub.2(g) electrolyte/O.sub.2(g) fuel cells with the new electrolytes is described. Superior performance both at ambient temperature and temperatures up to and above 200.degree. C. are achieved. Both neutral proton transfer salts and the acid salts with HSO.sup.-.sub.4 anions, give good results, the bisulphate case being particularly good at low temperatures and very high temperatures. The performance of all electrolytes is improved by the addition of a small amount of involatile base of pK.sub.a value intermediate between those of the acid and base that make the bulk electrolyte. The preferred case is the imidazole-doped ethylammonium hydrogensulfate which yields behavior superior in all respects to that of the industry standard phosphoric acid electrolyte.

Angell, C. Austen (Mesa, AZ); Xu, Wu (Broadview Heights, OH); Belieres, Jean-Philippe (Chandler, AZ); Yoshizawa, Masahiro (Tokyo, JP)

2011-01-11T23:59:59.000Z

38

The Influence of Operating Modes, Room Temperature Set Point and Curtain Styles on Energy Consumption of Room Air Conditioner  

E-Print Network (OSTI)

A field investigation was carried out in an office building of Changsha city in winter and summer, the influence of different running modes, curtain styles and room temperature set point on energy consumption of room air conditioner (RAC) was studied. The results show that: In summer automatic speed mode consumes the least refrigerating energy in different running modes, compared with low speed and high speed modes, it can conserve energy for 27.3% and 15.8%, respectively. In the same running mode, setting outer curtain can conserve energy for 40.9% and 20.4% compared with no curtain and inner curtain states, respectively. In winter high speed mode is the most efficient for saving energy which can decrease 40.3% and 30.9% compared with low speed and automatic speed modes. In the same running mode, setting inner curtain state makes the least heating energy consumption in cloudy day, about 10.8% and 2.7% less than no curtain and outer curtain states. However, it is not obvious when the day is fine. The heating energy consumption decreases as room temperature set point falls, compared with the energy consumption at 20.5 C and 19.5 C, it is decreases for 34.1% and17.0 % at 18.5 C, respectively. All the results will be the reference of environment design and control for air conditioning room.

Yu, J.; Yang, C.; Guo, R.; Wu, D.; Chen, H.

2006-01-01T23:59:59.000Z

39

Route to Room-Temperature Superconductivity from a Practical Point of View  

E-Print Network (OSTI)

To synthesize a new superconductor which has a critical temperature, Tc, exceeding the room temperature, one needs to know what chemical components to start with. This chapter presents analysis of experimental data which allow one to draw a conclusion about components and the structure of a potential room-temperature superconductor. The two essential components of a roomtemperature superconductor are large organic molecules (polymers, tissues) and atoms/molecules which are magnetic in the intercalated state. This conclusion is fully based on experimental facts known today, and does not require any assumptions about the mechanism of room-temperature superconductivity. This, however, does not mean that to synthesize a room-temperature superconductor is an easy task. Never let them persuade you that things are too difficult or impossible.

A. Mourachkine

2007-01-01T23:59:59.000Z

40

Time Dependent Deformation of Metals at Room Temperature  

Science Conference Proceedings (OSTI)

Results have been compared to previous work on logarithmic and power law ... into a Solid State Coating Process for High Temperature and Marine Application.

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Optical gain and lasing from band-engineered Ge-on-Si at room temperature  

E-Print Network (OSTI)

We present theoretical modeling and experimental results of optical gain and lasing from tensile-strained, n[superscript +] Ge-on-Si at room temperature. Compatible with silicon CMOS, these devices are ideal for large-scale ...

Liu, Jifeng

42

Room-temperature direct bandgap electroluminesence from Ge-on-Si light-emitting diodes  

E-Print Network (OSTI)

We report what we believe to be the first demonstration of direct bandgap electroluminescence (EL) from Ge/Si heterojunction light-emitting diodes (LEDs) at room temperature. In-plane biaxial tensile strain is used to ...

Sun, Xiaochen

43

Ionic liquid ion sources as a unique and versatile option in FIB applications  

Science Conference Proceedings (OSTI)

This work discusses the potential applicability of point sources to focused ion beam (FIB) technology based on molten salts at room temperature, known as ionic liquid ion sources (ILIS). The beam shape and divergence angles for ILIS using the ionic liquid ... Keywords: Focused ion beam, High brightness, Ion etching, Ion source, Ionic liquid, Reactive ion

Carla Perez-Martinez; Stéphane Guilet; Jacques Gierak; Paulo Lozano

2011-08-01T23:59:59.000Z

44

Room Temperature Aging Study of Butyl O-rings  

Science Conference Proceedings (OSTI)

During testing under the Enhanced Surveillance Campaign in 2001, preliminary data detected a previously unknown and potentially serious concern with recently procured butyl o-rings. All butyl o-rings molded from a proprietary formulation throughout the period circa 1999 through 2001 had less than a full cure. Tests showed that sealing force values for these suspect o-rings were much lower than expected and their physical properties were very sensitive to further post curing at elevated temperatures. Further testing confirmed that these o-rings were approximately 50% cured versus the typical industry standard of > 90% cured. Despite this condition, all suspect o-rings fully conformed to their QC acceptance requirements, including their individual product drawing requirements.

Mark Wilson

2009-08-07T23:59:59.000Z

45

The role of hydrogen in room-temperature ferromagnetism at graphite surfaces  

DOE Green Energy (OSTI)

We present a x-ray dichroism study of graphite surfaces that addresses the origin and magnitude of ferromagnetism in metal-free carbon. We find that, in addition to carbon {pi} states, also hydrogen-mediated electronic states exhibit a net spin polarization with significant magnetic remanence at room temperature. The observed magnetism is restricted to the top {approx}10 nm of the irradiated sample where the actual magnetization reaches {approx_equal} 15 emu/g at room temperature. We prove that the ferromagnetism found in metal-free untreated graphite is intrinsic and has a similar origin as the one found in proton bombarded graphite.

Ohldag, Hendrik

2011-08-12T23:59:59.000Z

46

Lithium ion conducting ionic electrolytes  

DOE Patents (OSTI)

A liquid, predominantly lithium-conducting, ionic electrolyte is described which has exceptionally high conductivity at temperatures of 100.degree. C. or lower, including room temperature. It comprises molten lithium salts or salt mixtures in which a small amount of an anionic polymer lithium salt is dissolved to stabilize the liquid against recrystallization. Further, a liquid ionic electrolyte which has been rubberized by addition of an extra proportion of anionic polymer, and which has good chemical and electrochemical stability, is described. This presents an attractive alternative to conventional salt-in-polymer electrolytes which are not cationic conductors.

Angell, C. Austen (Mesa, AZ); Xu, Kang (Tempe, AZ); Liu, Changle (Tulsa, OK)

1996-01-01T23:59:59.000Z

47

Room-temperature electric-field controlled spin dynamics in ,,110... InAs quantum wells  

E-Print Network (OSTI)

Room-temperature electric-field controlled spin dynamics in ,,110... InAs quantum wells K. C. Halla pseudomagnetic fields exceeding 1 T when only 140 mV is applied across a single quantum well. Using this large­11 and the influence of the Rashba pseudomagnetic fields on the electron spin relaxation time in GaAs quantum wells

Flatte, Michael E.

48

Room-temperature oxygen sensitization in highly textured, nanocrystalline PbTe films: A mechanistic study  

E-Print Network (OSTI)

In this paper, we report large mid-wave infrared photoconductivity in highly textured, nanocrystalline PbTe films thermally evaporated on Si at room temperature. Responsivity as high as 25 V/W is measured at the 3.5 ?m ...

Wang, Jianfei

49

Electrical properties of room temperature sputtered Y2O3and MOSFET characteristics  

Science Conference Proceedings (OSTI)

We closely evaluated the properties of Y2O3 deposited by RF sputter system at room temperature for the application to a transparent thin film transistor. Although the leakage current density hardly depends on the deposition conditions, ... Keywords: IGZO, TTFT(transparent thin film transistor), Y2O3, electrical characterization, gate oxide, leakage current

Young-Je Cho; Ji-Hoon Shin; Jae-Kyu Lee; Young-Bae Kim; Duck-Kyun Choi

2008-02-01T23:59:59.000Z

50

A room temperature CuO nanowire sensor for organic volatile gases  

Science Conference Proceedings (OSTI)

CuO nanowires have been synthesised by the thermal method in 100% oxygen ambient at 600°C. Gas sensing property has been examined by measuring the resistance change of the materials to 1% of butane gas and 1% of ethanol vapour separately under the ... Keywords: copper oxide (CuO) nanowires, room temperature gas sensor and organic volatile gas

C. F. Dee; T. Y. Tiong; M. M. Salleh; M. M. Yahya; B. Y. Majlis

2011-02-01T23:59:59.000Z

51

Raman and IR spectra of butane: Anharmonic calculations and interpretation of room temperature spectra  

E-Print Network (OSTI)

Raman and IR spectra of butane: Anharmonic calculations and interpretation of room temperature-principles anharmonic calculations are carried out for the IR and Raman spectra of the CAH stretch- ing bands in butane.V. All rights reserved. 1. Introduction n-Butane is of great importance in several disciplines

Potma, Eric Olaf

52

Room temperature 1.6 m electroluminescence from Ge light emitting diode on Si substrate  

E-Print Network (OSTI)

Room temperature 1.6 µm electroluminescence from Ge light emitting diode on Si substrate Szu n+/p light emitting diode on a Si substrate. Unlike normal electrically pumped devices, this device.4670) Optical materials; (230.3670) Light-emitting diodes. References and links 1. L. C. Kimerling, "Silicon

Vuckovic, Jelena

53

Room-temperature mid-infrared laser sensor for trace gas detection  

E-Print Network (OSTI)

, and pipeline leak detection. Applications such as landfill emissions monitoring require measurements of gasRoom-temperature mid-infrared laser sensor for trace gas detection Thomas To¨ pfer, Konstantin P. Petrov, Yasuharu Mine, Dieter Jundt, Robert F. Curl, and Frank K. Tittel Design and operation

54

Dye-doped cholesteric-liquid-crystal room-temperature single-photon source*  

E-Print Network (OSTI)

Dye-doped cholesteric-liquid-crystal room-temperature single-photon source* SVETLANA G. LUKISHOVAy, 250 East River Road, Rochester, New York 14623-1299, USA (Received 30 June 2003) Abstract. Fluorescence antibunching from single terrylene molecules embedded in a cholesteric-liquid-crystal host is used

Stroud, Carlos R.

55

Mirror thermal noise in laser interferometer gravitational wave detectors operating at room and cryogenic temperature  

E-Print Network (OSTI)

Mirror thermal noise is and will remain one of the main limitations to the sensitivity of gravitational wave detectors based on laser interferometers. We report about projected mirror thermal noise due to losses in the mirror coatings and substrates. The evaluation includes all kind of thermal noises presently known. Several of the envisaged substrate and coating materials are considered. The results for mirrors operated at room temperature and at cryogenic temperature are reported.

Janyce Franc; Nazario Morgado; Raffaele Flaminio; Ronny Nawrodt; Iain Martin; Liam Cunningham; Alan Cumming; Sheila Rowan; James Hough

2009-12-01T23:59:59.000Z

56

Oxygen Reordering Near Room temperature in YBa2Cu3O6+x: A Thermodynamic Model  

SciTech Connect

We propose a thermodynamic model to explain an unusual phase transformation occurring near room temperature in YBa{sub 2}Cu{sub 3}O{sub 6+x} that greatly affects properties of the superconductor. Based on our model, the material's thermodynamic response functions, specific heat, thermal-expansion coefficient, and elastic compliances are deduced at the critical temperature of the phase transformation. We discuss the change of critical temperature with stress, and analyze the anomaly of specific heat in critical temperature of the phase transformation.

Meng, Q.; Welch, D.; Zhu, Y.

2011-04-14T23:59:59.000Z

57

The role of hydrogen in room-temperature ferromagnetism at graphite surfaces  

DOE Green Energy (OSTI)

We present a x-ray dichroism study of graphite surfaces that addresses the origin and magnitude of ferromagnetism in metal-free carbon. We find that, in addition to carbon {pi} states, also hydrogen-mediated electronic states exhibit a net spin polarization with significant magnetic remanence at room temperature. The observed magnetism is restricted to the top {approx}10 nm of the irradiated sample where the average magnetization reaches {approx_equal} 15 emu/g at room temperature. We prove that the ferromagnetism found in metal-free untreated graphite is intrinsic and has a similar origin as the one found in proton bombarded graphite. Also, our findings show that the magnetic properties of graphite surfaces, thin films or two dimensional graphene samples can be reliably studied using soft x-ray dichroism. Fundamental new insight into the magnetic properties of carbon based systems can thus be obtained.

Ohldag, H.; Esquinazi, P.; Arenholz, E.; Spemann, D.; Rothermel, M.; Setzer, A.; Butz, T.

2010-05-01T23:59:59.000Z

58

Room temperature ferromagnetism in Mn, Ni and Co ions doped Cu{sub 2}O nanorods  

SciTech Connect

Here we report the synthesis and characterization of Cu{sub 2}O nanorods doped with Mn, Ni and Co transition metal ions and the study of their magnetic properties. Synthesis of the nanorods was carried out by the modified polyol method. Powder X-ray diffraction patterns clearly showed them to be polycrystalline single phase material. They exhibited ferromagnetic behavior at room temperature, however no such behavior was observed for the reference undoped sample, which indicated that unintentionally introduced magnetic impurities were not responsible for the observed phenomenon. Ferromagnetic behavior was found to be dependent on the dopant concentration and increased consistently with its increment in the material. The total magnetic moments contribution was calculated for the dopant concentration and was found to be insignificant to account for the observed ferromagnetism, therefore it was suggested that ferromagnetism could have conjured up from the induced magnetic moment in the defects created as cation vacancies in the material. The presence of the defects was supported by the room temperature photoluminescence study which showed that intensity of the peaks was dependent on the dopant concentration and increased consistently with it. There was strong correlation between the magnitude of the photoluminescence peak and the observed ferromagnetic property in the doped samples. -- Graphical Abstract: Room temperature ferromagnetism was observed in the Cu{sub 2}O nanorods doped with Mn, Ni and Co ions. The origin seems to be the defects of cation vacancies created by the dopant ions. Display Omitted

Ahmed, Asar [Department of Chemistry, SL-214, Southern Lab, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh (India); Gajbhiye, Namdeo S., E-mail: nsg@iitk.ac.i [Department of Chemistry, SL-214, Southern Lab, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh (India)

2010-12-15T23:59:59.000Z

59

Room-Temperature Ferromagnetism in Ion-Implanted Co-Doped TiO?(110) Rutile  

SciTech Connect

Interest in diluted magnetic semiconductros (DMS) is growing rapidly within the emerging field of spintronics. For example, the ability to efficiently inject spin-polarized carriers into nonmagnetic semiconductor heterostructures creates new and exciting possibilities for utilizing DMS materials in spin-based devices. Several III-V and II-VI semiconductor materials doped with magnetic transition metal elements have been explored. Although these materials show promising behavior in some cases, most exhibit Curie temperatures of ~170 K or less. It has recently been shown that certain oxide semiconductors doped with magnetic transition elements show room-temperature ferromagnetism.

Shutthanandan, V.; Thevuthasan, Suntharampillai; Heald, Steve M.; Droubay, Timothy; Engelhard, Mark H.; Kaspar, Tiffany C.; McCready, David E.; Saraf, Laxmikant V.; Chambers, Scott A.; Mun, B. S.; Hamdan, N. M.; Nachimuthu, Ponnusamy; Taylor, B.; Sears, R.; Sinkovic, Boris

2004-05-31T23:59:59.000Z

60

The use of ionic liquid ion sources (ILIS) in FIB applications  

E-Print Network (OSTI)

A new monoenergetic, high-brightness ion source can be constructed using an arrangement similar to liquid metal ion sources (LMIS) by substituting the liquid metal with an ionic liquid, or room temperature molten salt. Ion ...

Zorzos, Anthony Nicholas

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Scanning tunneling microscopy reveals LiMnAs is a room temperature anti-ferromagnetic semiconductor  

SciTech Connect

We performed scanning tunneling microscopy and spectroscopy on a LiMnAs(001) thin film epitaxially grown on an InAs(001) substrate by molecular beam epitaxy. While the in situ cleavage exposed only the InAs(110) non-polar planes, the cleavage continued into the LiMnAs thin layer across several facets. We combined both topography and current mappings to confirm that the facets correspond to LiMnAs. By spectroscopy we show that LiMnAs has a band gap. The band gap evidenced in this study, combined with the known Neel temperature well above room temperature, confirms that LiMnAs is a promising candidate for exploring the concepts of high temperature semiconductor spintronics based on antiferromagnets.

Wijnheijmer, A. P.; Koenraad, P. M. [COBRA Inter-University Research Institute, Department of Applied Physics, Eindhoven University of Technology, P. O. Box 513, NL-5600 MB Eindhoven (Netherlands); Marti, X. [Faculty of Mathematics and Physics, Charles University in Prague, Ke Karlovu 3, 121 16 Prague 2 (Czech Republic); Institute of Physics ASCR, v.v.i., Cukrovarnicka 10, 162 53 Prague 6 (Czech Republic); Holy, V. [Faculty of Mathematics and Physics, Charles University in Prague, Ke Karlovu 3, 121 16 Prague 2 (Czech Republic); Cukr, M.; Novak, V. [Institute of Physics ASCR, v.v.i., Cukrovarnicka 10, 162 53 Prague 6 (Czech Republic); Jungwirth, T. [Institute of Physics ASCR, v.v.i., Cukrovarnicka 10, 162 53 Prague 6 (Czech Republic); School of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD (United Kingdom)

2012-03-12T23:59:59.000Z

62

Room-Temperature Ferromagnetism in Chemically Synthesized Sn?-xCox O? Powders  

SciTech Connect

Room temperature ferromagnetism is observed in chemically synthesized powder samples of Sn??xCox O? with x = 0.005 and 0.01. Magnetic hysteresis loops are ovserved at 300K with coercivity Hc ~ 630 Oe, saturation magnetization Ms ~0.133?? and about 31% remenance. Analyses of the magnetization data of paramagnetic samples with x = 0.01 and 0.03, measured as a function of temperature (3-330K) and magnetic field (up to 50kOe), indicated the presence of Co²? ions with spin S = 3/2. Magnetic data obtained from samples prepared at different temperatures indicate that the observed ferromagnetism for x ? 0.01 might have been triggered by changes in the oxygen stiochiometry.

Punnoose, Alex; Hays, Jason S.; Gopal, Vidyut; Shutthanandan, V.

2004-08-30T23:59:59.000Z

63

Floatabilities of treated coal in water at room temperature. Annual topical report, September 1992--August 1993  

SciTech Connect

This report contains a research paper entitled ``Floatability of Treated Coal in Water at Room Temperature.`` Experimental data on equilibrium adsorption loadings of probe compounds on coal, and flotation of raw coals as well as treated coal were obtained, using Illinois No. 6 coal (PSOC-1539), Adaville No. 1 coal (PSOC-1544), Wyodak coal (PSOC-1545) and Pittsburgh No. 8 coal (PSOC-1549). The raw data of this Annual Topical Report are also available in the Quarterly Progress Report for the period April--June 1993 and the Quarterly Progress Report July--September 1993.

Kwon, K.C. [Tuskegee Univ., AL (United States). Dept. of Chemical Engineering; Rohrer, R.L.; Lai, R.W.; Finseth, D.H. [USDOE Pittsburgh Energy Technology Center, PA (United States)

1993-12-31T23:59:59.000Z

64

Enhanced room temperature electronic and thermoelectric properties of the dilute bismuthide InGaBiAs  

SciTech Connect

We report room temperature electronic and thermoelectric properties of Si-doped In{sub 0.52}Ga{sub 0.48}Bi{sub y}As{sub 1-y} with varying Bi concentrations. These films were grown epitaxially on a semi-insulating InP substrate by molecular beam epitaxy. We show that low Bi concentrations are optimal in improving the conductivity, Seebeck coefficient, and thermoelectric power factor, possibly due to the surfactant effects of bismuth. We observed a reduction in thermal conductivity with increasing Bi concentration, which is expected because of alloy scattering. We report a peak ZT of 0.23 at 300 K.

Dongmo, Pernell; Zhong Yujun; Bomberger, Cory; Zide, Joshua [Department of Materials Science and Engineering, University of Delaware, Newark, Delaware 19716 (United States); Attia, Peter [Department of Chemical Engineering, University of Delaware, Newark, Delaware 19716 (United States); Cheaito, Ramez; Hopkins, Patrick E. [Department of Mechanical and Aerospace Engineering, University of Virginia, Charlottesville, Virginia 2294 (United States); Ihlefeld, Jon F. [Sandia National Laboratories, P.O. Box 5800, M.S. 1069, Albuquerque, New Mexico 87185 (United States)

2012-11-01T23:59:59.000Z

65

Physical Properties of Ionic Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

Physical Properties of Ionic Liquids Consisting of the Physical Properties of Ionic Liquids Consisting of the 1-Butyl-3-Methylimidazolium Cation with Various Anions and the Bis(trifluoromethylsulfonyl)imide Anion with Various Cations Hui Jin, Bernie O'Hare, Jing Dong, Sergei Arzhantsev, Gary A. Baker, James F. Wishart, Alan J. Benesi, and Mark Maroncelli J. Phys. Chem. B 112, 81-92 (2008). [Find paper at ACS Publications] Abstract: Physical properties of 4 room-temperature ionic liquids consisting of the 1-butyl-3-methylimidazolium cation with various perfluorinated anions and the bis(trifluoromethylsulfonyl)imide (Tf2N-) anion with 12 pyrrolidinium-, ammonium-, and hydroxyl-containing cations are reported. Electronic structure methods are used to calculate properties related to the size, shape, and dipole moment of individual ions. Experimental measurements of

66

Room temperature all-silicon photonic crystal nanocavity light emitting diode at sub-bandgap wavelengths  

E-Print Network (OSTI)

Silicon is now firmly established as a high performance photonic material. Its only weakness is the lack of a native electrically driven light emitter that operates CW at room temperature, exhibits a narrow linewidth in the technologically important 1300- 1600 nm wavelength window, is small and operates with low power consumption. Here, an electrically pumped all-silicon nano light source around 1300-1600 nm range is demonstrated at room temperature. Using hydrogen plasma treatment, nano-scale optically active defects are introduced into silicon, which then feed the photonic crystal nanocavity to enahnce the electrically driven emission in a device via Purcell effect. A narrow ({\\Delta}{\\lambda} = 0.5 nm) emission line at 1515 nm wavelength with a power density of 0.4 mW/cm2 is observed, which represents the highest spectral power density ever reported from any silicon emitter. A number of possible improvements are also discussed, that make this scheme a very promising light source for optical interconnects a...

Shakoor, A; Cardile, P; Portalupi, S L; Gerace, D; Welna, K; Boninelli, S; Franzo, G; Priolo, F; Krauss, T F; Galli, M; Faolain, L O

2013-01-01T23:59:59.000Z

67

Room-temperature diluted magnetic semiconductors p-(Ga,Ni)N  

SciTech Connect

High concentration (5 at. %) Ni was incorporated into a chemical vapor deposition-grown GaN film by using a thin protecting Ni layer on top of the GaN film during ion implantation. After etching off the protecting layer, subsequent annealing up to 800 deg. C under flowing N{sub 2} resulted in a p-type GaN with apparent ferromagnetic behavior up to {approx}320 K. In addition, the ferromagnetic behavior became more manifest with increasing annealing temperature that increases hole concentration. No presence of any other second phases nor clusters in the Ni-implanted region was identifiable, at least to the 0.2 nm point-to-point resolution of high resolution transmission electron microscopy. This novel indirect implantation process that being easy to implement appears promising for attaining room-temperature diluted magnetic semiconductors which are applicable to magnetotransport, magneto-optical and spintronics devices, among others.

Huang, R.-T.; Hsu, C.-F.; Kai, J.-J.; Chen, F.-R.; Chin, T.-S. [Department of Engineering and System Science, National Tsing-Hua University, Hsinchu 300, Taiwan (China); Department of Materials Science and Engineering, National Tsing-Hua University, Hsinchu 300, Taiwan (China)

2005-11-14T23:59:59.000Z

68

Unusual Room Temperature Ferromagnetism in Bulk Sintered GaP Doped with Copper  

Science Conference Proceedings (OSTI)

Robust room temperature ferromagnetism is obtained in single phase Gallium Phosphide doped with Cu{sup 2+} prepared by simple solid state reaction route. The saturation magnetization at 300 K is 1.5 times 10{sup -2} emu/g and the coercivity was found to be 125 Oe. A strong ferromagnetic resonance signal confirms the long range magnetic order which persists to temperatures as high as 739 K. X-ray absorption spectroscopy (XAS) indicate that Cu is in a +2 state. Ab initio calculations also show that the ferromagnetic ordering is energetically favorable in Cu doped GaP. When the spin-orbit coupling is included we get an enhanced total magnetic moment of 0.31 muB with a local moment on Cu 0.082 and on P 0.204 mu{sub B}. per atom.

Owens, F. J.; Gupta, A.; Rao, K. V.; Iqbal, Z.; Osorio Guillen, J. M.; Ahuja, R.; Guo, J.-H.

2007-06-01T23:59:59.000Z

69

Room Temperature Control During Season Switchover with Single Duct Variable Air Volume System Without Reheat  

E-Print Network (OSTI)

The Langford “A” building houses the College of Architecture on TAMU campus. There are ten singleduct variable air volume (VAV) air-handling units (AHUs) without reheat serving the building. The local pneumatic thermostats modulate the dampers of VAV boxes to maintain room temperature at their setpoints. The thermostat action is switched from direct acting (DA) to reverse acting (RA) when the season changes from fall to winter and vice versa from winter to spring, based on the out side air temperature, when season changes. This results in various parts of the building ether too cold or too hot during the season change. This paper presents that the thermostat action will be switched according to cooling loads or discharge air temperature, instead of outside air temperature. For the interior zone, thermostat action does not need to be switched at all. The comfort is improved and savings is achieved by the new control scheme. Because some air-handling units (AHUs) serve both interior and exterior zones, this system never worked as intended. The system must be modified to have zone reheat and the AHUs discharge air temperature is set below dew point for humidity control.

Liu, C.; Deng, S.; Claridge, D. E.; Turner, W. D.; Bruner, H.

2003-01-01T23:59:59.000Z

70

Direct Observation of Room-Temperature Polar Ordering in Colloidal GeTe Nanocrystals  

SciTech Connect

Ferroelectrics and other materials that exhibit spontaneous polar ordering have demonstrated immense promise for applications ranging from non-volatile memories to microelectromechanical systems. However, experimental evidence of polar ordering and effective synthetic strategies for accessing these materials are lacking for low-dimensional nanomaterials. Here, we demonstrate the synthesis of size-controlled nanocrystals of the polar material germanium telluride (GeTe) using colloidal chemistry and provide the first direct evidence of room-temperature polar ordering in nanocrystals less than 5 nm in size using aberration-corrected transmission electron microscopy. Synchrotron x-ray diffraction and Raman studies demonstrate a sizeable polar distortion and a reversible size-dependent polar phase transition in these nanocrystals. The stability of polar ordering in solution-processible nanomaterials suggests an economical avenue to Tbit/in2-density non-volatile memory devices and other applications.

Polking, Mark J.; Zheng, Haimei; Urban, Jeffrey J.; Milliron, Delia J.; Chan, Emory; Caldwell, Marissa A.; Raoux, Simone; Kisielowski, Christian F.; Ager III, Joel W.; Ramesh, Ramamoorthy; Alivisatos, A.P.

2009-12-07T23:59:59.000Z

71

Method for stabilizing low-level mixed wastes at room temperature  

DOE Patents (OSTI)

A method to stabilize solid and liquid waste at room temperature is provided comprising combining solid waste with a starter oxide to obtain a powder, contacting the powder with an acid solution to create a slurry, said acid solution containing the liquid waste, shaping the now-mixed slurry into a predetermined form, and allowing the now-formed slurry to set. The invention also provides for a method to encapsulate and stabilize waste containing cesium comprising combining the waste with Zr(OH).sub.4 to create a solid-phase mixture, mixing phosphoric acid with the solid-phase mixture to create a slurry, subjecting the slurry to pressure; and allowing the now pressurized slurry to set. Lastly, the invention provides for a method to stabilize liquid waste, comprising supplying a powder containing magnesium, sodium and phosphate in predetermined proportions, mixing said powder with the liquid waste, such as tritium, and allowing the resulting slurry to set.

Wagh, Arun S. (Joliet, IL); Singh, Dileep (Westmont, IL)

1997-01-01T23:59:59.000Z

72

Method for stabilizing low-level mixed wastes at room temperature  

DOE Patents (OSTI)

A method to stabilize solid and liquid waste at room temperature is provided comprising combining solid waste with a starter oxide to obtain a powder, contacting the powder with an acid solution to create a slurry, said acid solution containing the liquid waste, shaping the now-mixed slurry into a predetermined form, and allowing the now-formed slurry to set. The invention also provides for a method to encapsulate and stabilize waste containing cesium comprising combining the waste with Zr(OH){sub 4} to create a solid-phase mixture, mixing phosphoric acid with the solid-phase mixture to create a slurry, subjecting the slurry to pressure; and allowing the now pressurized slurry to set. Lastly, the invention provides for a method to stabilize liquid waste, comprising supplying a powder containing magnesium, sodium and phosphate in predetermined proportions, mixing said powder with the liquid waste, such as tritium, and allowing the resulting slurry to set. 4 figs.

Wagh, A.S.; Singh, D.

1997-07-08T23:59:59.000Z

73

Energy Savings in Buildings Using Air Movement and Allowing Floating Temperature in Rooms  

E-Print Network (OSTI)

The purpose of the research study was to determine if building loads could be reduced by using an intelligent controller rather than a thermostatic controller to operate heating and air conditioning equipment. In order to switch the equipment on and off at the proper times, the intelligent controller calculated temperature limits using a mathematical procedure that determined the percentage of people who would be comfortable in rooms of the building. Simulations showed the annual cost savings from intelligent controllers ranged from 6 to 37 percent for residences and from 6 to 29 percent for the offices. An ancillary study showed that a ceiling fan provided comfort in a 112 square foot floor area to 85 F and in a 200 to 250 square foot area to 82 F.

Spain, S.

1985-01-01T23:59:59.000Z

74

Conjectured explanation for room-temperature superconductivity in narrow channels in oxidized polypropylene  

SciTech Connect

Two groups of scientists have observed conductivity at least five orders of magnitude higher than that of copper at room temperature in narrow channels perpendicular to surfaces of films in oxidized polypropylene. For pulsed currents, this conductivity starts at a minimum value of applied current, and is destroyed at a current of about 30-60 times this value. Because of the existence of an upper critical current and of the observation that electronic thermal conductivity is negligible in the channels, it is thought that the channels are superconducting. A study is made of the hypothesis that these results are due to enhanced pairing, as first suggested by Parameter, when the drift velocity of current carriers becomes close to the velocity of sound or, in work by Hone and by the present author, to an appropriate phase velocity of optical phonons. Such enhancements can be expected to be larger in quasi-one-dimensional systems. 10 refs.

Eagles, D.M. (NASA Marshall Space Flight Center, Huntsville, AL (United States))

1994-06-01T23:59:59.000Z

75

Experimental Observation of the Inverse Spin Hall Effect at Room Temperature  

SciTech Connect

We observe the inverse spin Hall effect in a two-dimensional electron gas confined in Al-GaAs/InGaAs quantum wells. Specifically, they find that an inhomogeneous spin density induced by the optical injection gives rise to an electric current transverse to both the spin polarization and its gradient. The spin Hall conductivity can be inferred from such a measurement through the Einstein relation and the onsager relation, and is found to have the order of magnitude of 0.5(e{sup 2}/h). The observation is made at the room temperature and in samples with macroscopic sizes, suggesting that the inverse spin Hall effects is a robust macroscopic transport phenomenon.

Liu, Baoli; Shi, Junren; Wang, Wenxin; Zhao, Hongming; Li, Dafang; /Beijing, Inst. Phys.; Zhang, Shoucheng; /Stanford U., Phys. Dept.; Xue, Qikun; Chen, Dongmin; /Beijing, Inst. Phys.

2010-03-16T23:59:59.000Z

76

CDZNTE ROOM-TEMPERATURE SEMICONDUCTOR GAMMA-RAY DETECTOR FOR NATIONAL-SECURITY APPLICATIONS.  

Science Conference Proceedings (OSTI)

One important mission of the Department of Energy's National Nuclear Security Administration is to develop reliable gamma-ray detectors to meet the widespread needs of users for effective techniques to detect and identify special nuclear- and radioactive-materials. Accordingly, the Nonproliferation and National Security Department at Brookhaven National Laboratory was tasked to evaluate existing technology and to develop improved room-temperature detectors based on semiconductors, such as CdZnTe (CZT). Our research covers two important areas: Improving the quality of CZT material, and exploring new CZT-based gamma-ray detectors. In this paper, we report on our recent findings from the material characterization and tests of actual CZT devices fabricated in our laboratory and from materials/detectors supplied by different commercial vendors. In particular, we emphasize the critical role of secondary phases in the current CZT material and issues in fabricating the CZT detectors, both of which affect their performance.

CAMARDA,G.S.; BOLOTNIKOV, A.E.; CUI, Y.; HOSSAIN, A.; KOHMAN, K.T.; JAMES, R.B.

2007-05-04T23:59:59.000Z

77

SRNL PHASE II SHELF LIFE STUDIES - SERIES 1 ROOM TEMPERATURE AND HIGH RELATIVE HUMIDITY  

SciTech Connect

The Savannah River National Laboratory (SRNL) Phase II, Series 1 shelf-life corrosion testing for the Department of Energy Standard 3013 container is presented and discussed in terms of the localized corrosion behavior of Type 304 stainless steel in contact with moist plutonium oxide and chloride salt mixtures and the potential impact to the 3013 inner container. This testing was designed to address the influence of temperature, salt composition, initial salt moisture, residual stress and type of oxide/salt contact on the relative humidity inside a 3013 container and the initiation and propagation of localized corrosion, especially stress corrosion cracking. The integrated plan is being conducted by Los Alamos National Laboratory and SRNL. SRNL is responsible for conducting a corrosion study in small scale vessels containing plutonium oxide and chloride salts under conditions of humidity, temperature and oxide/salt compositions both within the limits of 3013 storage conditions as well as beyond the 3013 storage requirements to identify margins for minimizing the initiation of stress corrosion cracking. These worst case conditions provide data that bound the material packaged in 3013 containers. Phase I of this testing was completed in 2010. The Phase II, Series 1 testing was performed to verify previous results from Phase I testing and extend our understanding about the initiation of stress corrosion cracking and pitting that occur in 304L under conditions of room temperature, high humidity, and a specific plutonium oxide/salt chemistry. These results will aid in bounding the safe storage conditions of plutonium oxides in 3013 containers. A substantial change in the testing was the addition of the capability to monitor relative humidity during test exposure. The results show that under conditions of high initial moisture ({approx}0.5 wt%) and room temperature stress corrosion cracking occurred in 304L teardrop coupons in contact with the oxide/salt mixture at times as short as 85 days. In all cases, the cracking appeared to be associated with pitting or localized general corrosion. Crack initiation at other sites, such as surface imperfections or inclusions, cannot be excluded. Cracks appear in most cases to initiate through an intergranular mode and transition to a transgranular mode.

Mickalonis, J.; Duffey, J.

2012-09-12T23:59:59.000Z

78

Impact Testing of Stainless Steel Material at Room and Elevated Temperatures  

SciTech Connect

Stainless steels are used for the construction of numerous spent nuclear fuel or radioactive material containers that may be subjected to high strains and moderate strain rates during accidental drop events. Mechanical characteristics of these base materials and their welds under dynamic loads in the strain rate range of concern are not well documented. However, three previous papers [1, 2, 3] reported on impact testing and analysis results performed at the Idaho National Laboratory using 304/304L and 316/316L stainless steel base material specimens that began the investigation of these characteristics. The goal of the work presented herein is to add the results of additional tensile impact testing for 304/304L and 316/316L stainless steel material specimens. Utilizing a drop-weight impact test machine and 1/4-inch to 1/2-inch thick dog-bone shaped test specimens, additional tests achieved target strain rates of 5, 10, and 22 per second at room temperature, 300, and 600 degrees Fahrenheit. Elevated true stress-strain curves for these materials at each designated strain rate and temperature are presented herein.

Dana K. Morton; Spencer D. Snow; Tom E. Rahl; Robert K. Blandford

2007-07-01T23:59:59.000Z

79

Large Room Temperature Magnetoresistance in FeCo-SiN Granular ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Large magnetoresistance (MR) materials have broad applications in ... Giant Low-Field Magnetocaloric Effect with Small Hysteresis Near Room ...

80

Absence of molecular deuterium dissociation during room-temperature permeation into polystyrene ICF target shells  

DOE Green Energy (OSTI)

Polystyrene microshells filled with deuterium and tritium gas are important target shells for inertially confined fusion (ICF) and are particularly promising for target containing spin-polarized hydrogens fuels. A currently active approach to the latter uses polarized D in HD, in a method which requires preservation of the high purity of the initially prepared HD (very low specified H{sub 2} and D{sub 2} concentrations). This would not be possible if dissociation should occur during permeation into the target shells. We have thus tested polystyrene shells using a novel method which employs very pure polystyrene shells using a novel method which employs very pure ortho-D{sub 2} as the test gas. An upper limit of 6 {times} 10{sup {minus}4} was deduced for the dissociation of D{sub 2} upon room temperature permeation through an approximately 8 um wall of polystyrene, clearing the way for use of polystyrene target shells for ICF fusion experiments with spin-polarized hydrogens fuels. 19 refs., 1 fig.

Honig, A.; Alexander, N.; Fan, Q. (Syracuse Univ., NY (USA). Dept. of Physics); Gram, R.; Kim, H. (Rochester Univ., NY (USA). Lab. for Laser Energetics)

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Room temperature green light emission from nonpolar cubic InGaN/GaN multi-quantum-wells  

E-Print Network (OSTI)

Room temperature green light emission from nonpolar cubic InGaN/GaN multi-quantum-wells Shunfeng Li Cubic InGaN/GaN multi-quantum-wells MQWs with high structural and optical quality are achieved by utilizing freestanding 3C-SiC 001 substrates and optimizing InGaN quantum well growth. Superlattice peaks up

As, Donat Josef

82

Room-temperature electroluminescence from germanium in an Al0.3Ga0.7As/Ge heterojunction  

E-Print Network (OSTI)

.7As/Ge heterojunction light-emitting diode without any complicated manipulation for alternating. ©2012 Optical Society of America OCIS codes: (230.3670) Light-emitting diodes; (230.3990) Micro. Vuckovi, and Y. Nishi, "Room temperature 1.6 microm electroluminescence from Ge light emitting diode on Si

Kolner, Brian H.

83

Estimation of Thermal Resistance from Room Temperature Electrical Resistance Measurements for Different LHC Beam Screen Support Systems  

E-Print Network (OSTI)

In this note the thermal resistance between the LHC beam screen and cold bore is estimated from room temperature electrical resistance measurements. The results indicate that the beam screen without supports should have a comparable, if not better, thermal performance than the one with the existing spring supports. This prediction from electrical resistance measurements is confirmed by recent preliminary thermal measurements.

Jenninger, B

1999-01-01T23:59:59.000Z

84

Multilayered YSZ/GZO films with greatly enhanced ionic conduction for low temperature solid oxide fuel cells  

Science Conference Proceedings (OSTI)

Strain confinement in heterostructured films significantly affects ionic conductivity of the electrolytes for solid oxide fuel cells based on a multi-layered design strategy. Nearly ideal tensile strain can be achieved by a dedicated manipulation of the lattice mismatch between adjacent layers and fine control of the layer thicknesses to minimize the formation of dislocations and thus to achieve optimized ionic conduction. This strategy was demonstrated by a model system of multilayered 8 mol%Y2O3 stabilized ZrO2 (YSZ) with Gd2Zr2O7 (GZO) films, which were epitaxially grown on Al2O3 (0001) substrates by pulsed laser deposition (PLD) with the {111} planes of YSZ/GZO along the Al2O3 [0 1 ?1 0] direction. The tensile strain (3%) resulting from the lattice mismatch can be confined in individual YSZ layers with the formation of a coherent, dislocation-free interface upon the manipulation of the layer thickness below a critical value, e.g., down to 5 nm. The strained heterostructure displays a two order-of-magnitude increase in oxide-ion conductivity as compared with bulk YSZ, and a high ionic conductivity of 0.01 S cm?1 at 475 °C can be achieved, five times greater than that of Gd-doped ceria/zirconia. The approach of strain confinement by fine control of lattice mismatch and layer thickness represents a promising strategy in developing advanced electrolytes enabling the miniaturization of solid-state ionic devices that can be operated at low temperatures below 500 °C.

Li, Bin; Zhang, Jiaming; Kaspar, Tiffany C.; Shutthanandan, V.; Ewing, Rodney C.; Lian, Jie

2013-01-01T23:59:59.000Z

85

Charge trapping in imidazolium ionic liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

trapping in imidazolium ionic liquids trapping in imidazolium ionic liquids I. A. Shkrob and J. F. Wishart J. Phys. Chem. B 113, 5582-5592 (2009). [Find paper at ACS Publications] or use ACS Articles on Request Abstract: Room-temperature ionic liquids (ILs) are a promising class of solvents for applications ranging from photovoltaics to solvent extractions. Some of these applications involve the exposure of the ILs to ionizing radiation, which stimulates interest in their radiation and photo- chemistry. In the case of ILs consisting of 1,3-dialkylimidazolium cations and hydrophobic anions, ionization, charge transfer and redox reactions yield charge-trapped species thought to be radicals resulting from neutralization of the constituent ions. Using computational chemistry methods and the recent results on electron spin resonance (ESR) and transient absorption

86

Room Temperature ppb Level Chlorine Gas Sensor Based on Copper (II) 1, 4, 8, 11, 15, 18, 22, 25-octabutoxy-29 H, 31 H-phthalocyanine Films  

SciTech Connect

Spin coating technique has been used to fabricate room temperature chlorine gas sensor based on copper (II) 1, 4, 8, 11, 15, 18, 22, 25-octabutoxy-29 H, 31 H-phthalocyanine (CuPc(OBu){sub 8}) films. Gas sensor shows a response of 185% to few parts per billion level of Cl{sub 2} gas with response time of 9.5 minutes at room temperature. The interactions between sensor and analytes followed first order kinetics with rate constant 0.01{<=}k{<=}0.02. The chemiresistive sensor showed very good stability at room temperature over a long period of time.

Bedi, R. K.; Saini, Rajan; Mahajan, Aman [Material Science Laboratory, Department of PhysicsGuru Nanak Dev University, Amritsar-143005 (India)

2010-12-01T23:59:59.000Z

87

Room Temperature Formability of Alloys 625LCF™, 718 and 718SPF  

Science Conference Proceedings (OSTI)

Dover, NJ 07801 ... affects the FLD is the work-hardening rate of the material. The plastic ... In metal-forming operations the strain rate and temperature can also.

88

Synthesis of Room-Temperature Ferromagnetic Cr-doped TiO?(110) Rutile Single Crystals using Ion Implantation  

SciTech Connect

Ferromagnetic Cr-doped rutile TiO? single crystals were synthesized by high-temperature ion implantation. The associated structural, compositional and magnetic properties were studied by x-ray photoelectron spectroscopy, Rutherford backscattering spectrometry, proton induced x-ray emission, x-ray diffraction, Cr K- and L-shell near-edge x-ray absorption spectroscopy, and vibrating sample magnetometry. Cr was distributed uniformly to the depth of about 300 nm with an average concentration of ~1 at. %. The samples are semiconducting and ferromagnetic as implanted, with a saturation magnetization of 0.29???B/Cr atom at room temperature. Cr is in a formal oxidation state of +3 throughout the implanted region, and no CrO? is detected.

Shutthanandan, V.; Thevuthasan, Suntharampillai; Droubay, Timothy; Heald, Steve M.; Engelhard, Mark H.; McCready, David E.; Chambers, Scott A.; Nachimuthu, Ponnusamy; Mun, B. S.

2006-01-01T23:59:59.000Z

89

Dynamic polarization of single nuclear spins by optical pumping of NV color centers in diamond at room temperature  

E-Print Network (OSTI)

We report a versatile method to efficiently polarize single nuclear spins in diamond, which is based on optical pumping of a single NV color center and mediated by a level-anti crossing in its excited state. A nuclear spin polarization higher than 98% is achieved at room temperature for the 15N nuclear spin associated to the NV center, corresponding to $\\mu$K effective nuclear spin temperature. We then show simultaneous deterministic initialization of two nuclear spins (13C and 15N) in close vicinity to a NV defect. Such robust control of nuclear spin states is a key ingredient for further scaling up of nuclear-spin based quantum registers in diamond.

V. Jacques; P. Neumann; J. Beck; M. Markham; D. Twitchen; J. Meijer; F. Kaiser; G. Balasubramanian; F. Jelezko; J. Wrachtrup

2008-08-01T23:59:59.000Z

90

Searching for room temperature ferromagnetism in transition metal implanted ZnO and GaN  

Science Conference Proceedings (OSTI)

Significant progress in the field of wide-gap dilute magnetic semiconductors (DMS) depends on the discovery of a material system which not only shows high-temperature ferromagnetism but is also simple to prepare and thus easy to reproduce. In this context

L. M. C. Pereira; J. P. Araújo; U. Wahl; S. Decoster; M. J. Van Bael; K. Temst; A. Vantomme

2013-01-01T23:59:59.000Z

91

VOC and HAP recovery using ionic liquids  

SciTech Connect

During the manufacture of wood composites, paper, and to a lesser extent, lumber, large amounts of volatile organic compounds (VOCs) such as terpenes, formaldehyde, and methanol are emitted to air. Some of these compounds are hazardous air pollutants (HAPs). The air pollutants produced in the forest products industry are difficult to manage because the concentrations are very low. Presently, regenerative thermal oxidizers (RTOs and RCOs) are commonly used for the destruction of VOCs and HAPs. RTOs consume large amounts of natural gas to heat air and moisture. The combustion of natural gas generates increased CO2 and NOx, which have negative implications for global warming and air quality. The aforementioned problems are addressed by an absorption system containing a room-temperature ionic liquid (RTIL) as an absorbent. RTILs are salts, but are in liquid states at room temperature. RTILs, an emerging technology, are receiving much attention as replacements for organic solvents in industrial processes with significant cost and environmental benefits. Some of these processes include organic synthesis, extraction, and metal deposition. RTILs would be excellent absorbents for exhausts from wood products facilities because of their unique properties: no measurable vapor pressure, high solubility of wide range of organic compounds, thermal stability to 200°C (almost 400°F), and immisciblity with water. Room temperature ionic liquids were tested as possible absorbents. Four were imidizolium-based and were eight phosphonium-based. The imidizolium-based ionic liquids proved to be unstable at the conditions tested and in the presence of water. The phosphonium-based ionic liquids were stable. Most were good absorbents; however, cleaning the contaminates from the ionic liquids was problematic. This was overcome with a higher temperature (120°C) than originally proposed and a very low pressure (1 kPa. Absorption trials were conducted with tetradecy(trihexyl)phosphonium dicyanamide as the RTIL. It was determined that it has good absorption properties for methanol and ?-pinene, is thermally stable, and is relatively easy to synthesize. It has a density of 0.89 g/mL at 20°C and a molecular weight of 549.9 g/mol. Trials were conducted with a small absorption system and a larger absorption system. Methanol, formaldehyde, and other HAPs were absorbed well, nearly 100%. Acetaldehyde was difficult to capture. Total VOC capture, while satisfactory on methanol and ?-pinene in a lab system, was less than expected in the field, 60-80%. The inability to capture the broad spectrum of total organics is likely due to difficulties in cleaning them from the ionic liquid rather than the ability of the ionic liquid to absorb. It’s likely that a commercial system could be constructed to remove 90 to 100% of the gas contaminates. Selecting the correct ionic liquid would be key to this. Absorption may not be the main selection criterion, but rather how easily the ionic liquid can be cleaned is very important. The ionic liquid absorption system might work very well in a system with a limited spectrum of pollutants, such as a paint spray line, where there are not very high molecular weight, non volatile, compounds in the exhaust.

Michael R. Milota : Kaichang Li

2007-05-29T23:59:59.000Z

92

Thin film growth and characterization of Potassium-Tantalate-Niobate room temperature ferroelectric  

E-Print Network (OSTI)

The primary objective in fabricating ferroelectric thin films is to duplicate the polar properties and characteristics of the corresponding bulk material. Potassium Tantalate-Niobate (KTN), KTa(,-,)Nb,03-, is a continuous solid solution between the perovskite compounds KNbO3 and KTaO3. The Curie temperature of KTN can be varied by a4justing x i.e.., the composition of niobium. In the vicinity of the ferroto-paraelectric phase transition, high dielectric permittivities, large pyroelectric as well as electro-optical and nonlinear optical coefficients can be observed. Bulk KTN single crystals synthesized from high temperature melts have limited device utility due to the occurence of lamellar growth, twins, etc. For these reasons thin films of KTN find enormous applications in spatial light modulators., pyroelectric devices, holographic storage., parametric oscillators and variable delay lines. The research undertaken involved the growth of KTN thin films on lattice matched substrates. The preferential groath directions, optimum growth conditions, ideal charge composition, and ideal regime in phase diagram were established. Liquidphase epitaxy (LPE) was the technique employed for the growth of thin films. The as grown films were optically and electrically characterized.

Muntha, Nageswara Rao Venkat

1995-01-01T23:59:59.000Z

93

Hydrogen incorporation induced metal-semiconductor transition in ZnO:H thin films sputtered at room temperature  

Science Conference Proceedings (OSTI)

The room temperature deposited ZnO:H thin films having high conductivity of 500 Ohm-Sign {sup -1} cm{sup -1} and carrier concentration reaching 1.23 Multiplication-Sign 10{sup 20} cm{sup -3} were reactively sputter deposited on glass substrates in the presence of O{sub 2} and 5% H{sub 2} in Ar. A metal-semiconductor transition at 165 K is induced by the increasing hydrogen incorporation in the films. Hydrogen forms shallow donor complex with activation energy of {approx}10-20 meV at oxygen vacancies (V{sub O}) leading to increase in carrier concentration. Hydrogen also passivates V{sub O} and V{sub Zn} causing {approx}4 times enhancement of mobility to 25.4 cm{sup 2}/V s. These films have potential for use in transparent flexible electronics.

Singh, Anil; Chaudhary, Sujeet; Pandya, D. K. [Thin Film Laboratory, Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016 (India)] [Thin Film Laboratory, Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016 (India)

2013-04-29T23:59:59.000Z

94

Photothermal and thermo-refractive effects in high reflectivity mirrors at room and cryogenic temperature  

E-Print Network (OSTI)

Increasing requirements in the sensitivity of interferometric measurements is a common feature of several research fields, from gravitational wave detection to quantum optics. This motivates refined studies of high reflectivity mirrors and of noise sources that are tightly related to their structure. In this work we present an experimental characterization of photothermal and thermo-refractive effects in high reflectivity mirrors, i.e., of the variations in the position of their effective reflection plane due to weak residual power absorption. The measurements are performed by modulating the impinging power in the range 10 Hz $\\div$ 100 kHz. The experimental results are compared with an expressly derived theoretical model in order to fully understand the phenomena and exploit them to extract useful effective thermo-mechanical parameters of the coating. The measurements are extended at cryogenic temperature, where most high sensitivity experiments are performed (or planned in future versions) and where characterizations of dielectric film coatings are still poor.

Alessandro Farsi; Mario Siciliani de Cumis; Francesco Marino; Francesco Marin

2011-09-21T23:59:59.000Z

95

Photothermal and thermo-refractive effects in high reflectivity mirrors at room and cryogenic temperature  

E-Print Network (OSTI)

Increasing requirements in the sensitivity of interferometric measurements is a common feature of several research fields, from gravitational wave detection to quantum optics. This motivates refined studies of high reflectivity mirrors and of noise sources that are tightly related to their structure. In this work we present an experimental characterization of photothermal and thermo-refractive effects in high reflectivity mirrors, i.e., of the variations in the position of their effective reflection plane due to weak residual power absorption. The measurements are performed by modulating the impinging power in the range 10 Hz $\\div$ 100 kHz. The experimental results are compared with an expressly derived theoretical model in order to fully understand the phenomena and exploit them to extract useful effective thermo-mechanical parameters of the coating. The measurements are extended at cryogenic temperature, where most high sensitivity experiments are performed (or planned in future versions) and where charact...

Farsi, Alessandro; Marino, Francesco; Marin, Francesco

2011-01-01T23:59:59.000Z

96

Photoluminescence in the Ca{sub x}Sr{sub 1-x}WO{sub 4} system at room temperature  

Science Conference Proceedings (OSTI)

In this work, a study was undertaken about the structural and photoluminescent properties, at room temperature, of powder samples from the Ca{sub x}Sr{sub 1-x}WO{sub 4} (x=0-1.0) system, synthesized by a soft chemical method and heat treated between 400 and 700 deg. C. The material was characterized using Infrared, UV-vis and Raman spectroscopy and XRD. The most intense PL emission was obtained for the sample calcined at 600 deg. C, which is neither highly disordered (400-500 deg. C), nor completely ordered (700 deg. C). Corroborating the role of disorder in the PL phenomenon, the most intense PL response was not observed for pure CaWO{sub 4} or SrWO{sub 4}, but for Ca{sub 0.6}Sr{sub 0.4}WO{sub 4}. The PL emission spectra could be separated into two Gaussian curves. The lower wavelength peak is placed around 530 nm, and the higher wavelength peak at about 690 nm. Similar results were reported in the literature for both CaWO{sub 4} and SrWO{sub 4}. - Graphical abstract: The structural and room temperature photoluminescence of Ca{sub x}Sr{sub 1-x}WO4 synthesized by a soft chemical method was studied. The most intense PL emission was obtained for the sample calcined at 600 deg. C, that is neither highly disordered (400-500 deg. C), nor completely ordered (700 deg. C). Corroborating the role of disorder in the PL phenomenon, the most intense PL response was not observed for pure CaWO{sub 4} or SrWO{sub 4}, but for Ca{sub 0.6}Sr{sub 0.4}WO{sub 4}.

Porto, S.L. [Laboratorio de Combustiveis e Materiais (LACOM/DQ/CCEN), Universidade Federal da Paraiba, Campus I, Cidade Universitaria, Joao Pessoa, PB, CEP 58059-900 (Brazil); Longo, E. [CMDMC/LIEC, Instituto de Quimica, UNESP-Araraquara, Rua Prof. Francisco Degni s/n, Araraquara, SP, CEP 14800-900 (Brazil); Pizani, P.S.; Boschi, T.M. [Departamento de Fisica, Universidade Federal de Sao Carlos, Sao Carlos, Rodovia Washington Luiz km 235, SP, CEP 13565-905 (Brazil); Simoes, L.G.P. [Centro Multidisciplinar de Desenvolvimento de Materiais Ceramicos (LIEC/DQ), Universidade Federal de Sao Carlos, Rodovia Washington Luiz km 235, Sao Carlos, SP, CEP 13565-905 (Brazil); Lima, S.J.G. [Laboratorio de Solidificacao Rapida, Departamento de Tecnologia Mecanica (LSR/DTM/CT), Universidade Federal da Paraiba, Campus I, Cidade Universitaria, Joao Pessoa, PB, CEP 58059-900 (Brazil); Ferreira, J.M. [Laboratorio de Combustiveis e Materiais (LACOM/DQ/CCEN), Universidade Federal da Paraiba, Campus I, Cidade Universitaria, Joao Pessoa, PB, CEP 58059-900 (Brazil); COAMA, Area de Meio Ambiente, Centro Federal de Educacao Tecnologica da Paraiba, Av. 1o de Maio 720, Jaguaribe, Joao Pessoa, PB, CEP 58015-430 (Brazil); Soledade, L.E.B.; Espinoza, J.W.M.; Cassia-Santos, M.R.; Maurera, M.A.M.A. [Laboratorio de Combustiveis e Materiais (LACOM/DQ/CCEN), Universidade Federal da Paraiba, Campus I, Cidade Universitaria, Joao Pessoa, PB, CEP 58059-900 (Brazil); Paskocimas, C.A. [Departamento de Engenharia Mecanica, Universidade Federal do Rio Grande do Norte, Natal, RN, CEP 59072-970 (Brazil); Santos, I.M.G. [Laboratorio de Combustiveis e Materiais (LACOM/DQ/CCEN), Universidade Federal da Paraiba, Campus I, Cidade Universitaria, Joao Pessoa, PB, CEP 58059-900 (Brazil)], E-mail: ieda@quimica.ufpb.br; Souza, A.G. [Laboratorio de Combustiveis e Materiais (LACOM/DQ/CCEN), Universidade Federal da Paraiba, Campus I, Cidade Universitaria, Joao Pessoa, PB, CEP 58059-900 (Brazil)

2008-08-15T23:59:59.000Z

97

Physical properties of Ce3-xTe4 below room temperature  

Science Conference Proceedings (OSTI)

The physical properties of polycrystalline Ce{sub 3-x}Te{sub 4} were investigated by measurements of the thermoelectric properties, Hall coefficient, heat capacity, and magnetization. The fully filled, metallic x = 0 compound displays a soft ferromagnetic transition near 4 K, and analysis of the corresponding heat capacity anomaly suggests a doublet ground state for Ce{sup 3+}. The transition is suppressed to below 2 K in the insulating x = 0.33 composition, revealing that magnetic order in Ce{sub 3-x}Te{sub 4} is driven by a Ruderman-Kittel-Kasuya-Yosida (RKKY)-type interaction. The thermoelectric properties trend with composition as expected from simple electron counting, and the transport properties in Ce{sub 3}Te{sub 4} are observed to be similar to those in La{sub 3}Te{sub 4}. Trends in the low-temperature thermal conductivity data reveal that the phonons are efficiently scattered by electrons, while all compositions examined have a lattice thermal conductivity near 1.2 W/m K{sup -1} at 200 K.

May, Andrew F [ORNL; McGuire, Michael A [ORNL; Cantoni, Claudia [ORNL; Sales, Brian C [ORNL

2012-01-01T23:59:59.000Z

98

Interaction of Plutonium with Diverse Materials in Moist Air and Nitrogen-Argon Atmospheres at Room Temperature  

DOE Green Energy (OSTI)

Chemical and radiolytic interactions of weapons-grade plutonium with metallic, inorganic, and hydrogenous materials in atmospheres containing moist air-argon mixtures have been characterized at room temperature from pressure-volume-temperature and mass spectrometric measurements of the gas phase. A reaction sequence controlled by kinetics and gas-phase composition is defined by correlating observed and known reaction rates. In all cases, O{sub 2} is eliminated first by the water-catalyzed Pu + O{sub 2} reaction and H{sub 2}O is then consumed by the Pu + H{sub 2}O reaction, producing a gas mixture of N{sub 2}, argon, and H{sub 2}. Hydrogen formed by the reaction of water and concurrent radiolysis of hydrogenous materials either reacts to form PuH{sub 2} or accumulates in the system. Accumulation of H{sub 2} is correlated with the presence of hydrogenous materials in liquid and volatile forms that are readily distributed over the plutonium surface. Areal rates of radiolytic H{sub 2} generation are determined and applied in showing that modest extents of H{sub 2} production are expected for hydrogenous solids if the contact area with plutonium is limited. The unpredictable nature of complex chemical systems is demonstrated by occurrence of the chloride-catalyzed Pu + H{sub 2}O reaction in some tests and hydride-catalyzed nitriding in another.

John M. Haschke; Raymond J. Martinez; Robert E. Pruner II; Barbara Martinez; Thomas H. Allen

2001-04-01T23:59:59.000Z

99

Radiation Stability of Cations in Ionic Liquids. 2. Charge Delocalization  

NLE Websites -- All DOE Office Websites (Extended Search)

Stability of Cations in Ionic Liquids. 2. Improved Radiation Stability of Cations in Ionic Liquids. 2. Improved Radiation Resistance Through Charge Delocalization in 1-Benzylpyridinium Ilya A. Shkrob, Timothy W. Marin, Jasmine L. Hatcher, Andrew R. Cook, Tomasz Szreder and James F. Wishart J. Phys. Chem. B 117, Just Accepted (2013). [Find paper at ACS Publications]. Abstract: Hydrophobic room-temperature ionic liquids (ILs) hold promise as replacements for molecular diluents for processing of used nuclear fuel as well as for the development of alternative separations processes, provided that the solvent can be made resistant to ionizing radiation. We demonstrate that 1-benzylpyridinium cations are uniquely suited as radiation resistant cations due to the occurrence of charge delocalization both in their reduced and oxidized form in the ILs. It is suggested that

100

Strong room-temperature ferromagnetism of high-quality lightly Mn-doped ZnO grown by molecular beam epitaxy  

Science Conference Proceedings (OSTI)

Strong room-temperature ferromagnetism is demonstrated in single crystalline Mn-doped ZnO grown by molecular beam epitaxy. With a low Mn concentration of 2 Multiplication-Sign 10{sup 19} cm{sup -3}, Mn-doped ZnO films exhibited room-temperature ferromagnetism with a coercivity field larger than 200 Oe, a large saturation moment of 6 {mu}{sub B}/ion, and a large residue moment that is {approx}70% of the saturation magnetization. Isolated ions with long range carrier mediated spin-spin coupling may be responsible for the intrinsic ferromagnetism.

Zuo Zheng; Zhou Huimei; Olmedo, Mario J.; Kong Jieying; Liu Jianlin [Quantum Structures Laboratory, Department of Electrical Engineering, University of California - Riverside, Riverside, California 92521 (United States); Beyermann, Ward P. [Department of Physics and Astronomy, University of California - Riverside, Riverside, California 92521 (United States); Zheng Jianguo [Laboratory for Electron and X-ray Instrumentation, California Institute for Telecommunications and Information Technology, University of California - Irvine, Irvine, California 92697 (United States); Xin Yan [NHMFL, Florida State University, 1800 E. Paul Dirac Dr., Tallahassee, Florida 32310-3706 (United States)

2012-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Phase-Changing Ionic Liquids: CO2 Capture with Ionic Liquids Involving Phase Change  

Science Conference Proceedings (OSTI)

IMPACCT Project: Notre Dame is developing a new CO2 capture process that uses special ionic liquids (ILs) to remove CO2 from the gas exhaust of coal-fired power plants. ILs are salts that are normally liquid at room temperature, but Notre Dame has discovered a new class of ILs that are solid at room temperature and change to liquid when they bind to CO2. Upon heating, the CO2 is released for storage, and the ILs re-solidify and donate some of the heat generated in the process to facilitate further CO2 release. These new ILs can reduce the energy required to capture CO2 from the exhaust stream of a coal-fired power plant when compared to state-ofthe- art technology.

None

2010-07-01T23:59:59.000Z

102

The 3rd International Conference of IIR on Magnetic Refrigeration at Room Temperature, Des Moines, Iowa, U.S.A, 11-15 May 2009  

E-Print Network (OSTI)

REFRIGERATION SYSTEMS USING DESIGN OF EXPERIMENTS J. ROUDAUT1,2,* , H. BOUCHEKARA1 , A. KEDOUS-LEBOUC1 , J of Design of Experiments (DOE) method in magnetic refrigeration (MR) understanding and optimizationThe 3rd International Conference of IIR on Magnetic Refrigeration at Room Temperature, Des Moines

Paris-Sud XI, Université de

103

Optically pumped InxGa?â??xN/InyGa?â??yN multiple quantum well vertical cavity surface emitting laser operating at room temperature.  

E-Print Network (OSTI)

Room temperature vertical cavity lasing at the wavelength of 433nm has been successfully realized in InxGa?â??xN/InyGa?â??yN multiple quantum well without Bragg mirrors under photo-excitation. At high excitation intensity, ...

Chen, Zhen

104

Ionic Liquid Membranes for Carbon Dioxide Separation  

SciTech Connect

Recent scientific studies are rapidly advancing novel technological improvements and engineering developments that demonstrate the ability to minimize, eliminate, or facilitate the removal of various contaminants and green house gas emissions in power generation. The Integrated Gasification Combined Cycle (IGCC) shows promise for carbon dioxide mitigation not only because of its higher efficiency as compared to conventional coal firing plants, but also due to a higher driving force in the form of high partial pressure. One of the novel technological concepts currently being developed and investigated is membranes for carbon dioxide (CO2) separation, due to simplicity and ease of scaling. A challenge in using membranes for CO2 capture in IGCC is the possibility of failure at elevated temperatures or pressures. Our earlier research studies examined the use of ionic liquids on various supports for CO2 separation over the temperature range, 37°C-300°C. The ionic liquid, 1-hexyl-3methylimidazolium Bis(trifluoromethylsulfonyl)imide, ([hmim][Tf2N]), was chosen for our initial studies with the following supports: polysulfone (PSF), poly(ether sulfone) (PES), and cross-linked nylon. The PSF and PES supports had similar performance at room temperature, but increasing temperature caused the supported membranes to fail. The ionic liquid with the PES support greatly affected the glass transition temperature, while with the PSF, the glass transition temperature was only slightly depressed. The cross-linked nylon support maintained performance without degradation over the temperature range 37-300°C with respect to its permeability and selectivity. However, while the cross-linked nylon support was able to withstand temperatures, the permeability continued to increase and the selectivity decreased with increasing temperature. Our studies indicated that further testing should examine the use of other ionic liquids, including those that form chemical complexes with CO2 based on amine interactions. The hypothesis is that the performance at the elevated temperatures could be improved by allowing a facilitated transport mechanism to become dominant. Several amine-based ionic liquids were tested on the cross-linked nylon support. It was found that using the amine-based ionic liquid did improve selectivity and permeability at higher temperature. The hypothesis was confirmed, and it was determined that the type of amine used also played a role in facilitated transport. Given the appropriate aminated ionic liquid with the cross-linked nylon support, it is possible to have a membrane capable of separating CO2 at IGCC conditions. With this being the case, the research has expanded to include separation of other constituents besides CO2 (CO, H2S, etc.) and if they play a role in membrane poisoning or degradation. This communication will discuss the operation of the recently fabricated ionic liquid membranes and the impact of gaseous components other than CO2 on their performance and stability.

Myers, C.R.; Ilconich, J.B.; Luebke, D.R.; Pennline, H.W.

2008-07-12T23:59:59.000Z

105

Core-shell multi-quantum wells in ZnO / ZnMgO nanowires with high optical efficiency at room temperature  

E-Print Network (OSTI)

Nanowire-based light-emitting devices require multi-quantum well heterostructures with high room temperature optical efficiencies. We demonstrate that such efficiencies can be attained through the use of ZnO/Zn(1-x)MgxO core shell quantum well heterostructures grown by metal organic vapour phase epitaxy. Varying the barrier Mg concentration from x=0.15 to x=0.3 leads to the formation of misfit induced dislocations in the multi quantum wells. Correlatively, temperature dependant photoluminescence reveals that the radial well luminescence intensity decreases much less rapidly with increasing temperature for the lower Mg concentration. Indeed, about 54% of the 10K intensity is retained at room temperature with x=0.15, against 2% with x=0.30. Those results open the way to the realization of high optical efficiency nanowire-based light emitting diodes.

Thierry, Robin; Jouneau, Pierre-Henri; Ferret, Pierre; Feuillet, Guy; 10.1088/0957-4484/23/8/085705

2013-01-01T23:59:59.000Z

106

Above room-temperature operation of InAs/AlGaSb superlattice quantum cascade lasers emitting at 12 {mu}m  

SciTech Connect

The authors report on above-room-temperature operation of InAs/AlGaSb quantum cascade lasers emitting at 12 {mu}m. The laser structures are grown on a n-InAs (100) substrate using solid-source molecular beam epitaxy. An InAs/AlGaSb superlattice is used as an active part and an InAs double plasmon waveguide is used for optical confinement. Results show that increased doping concentration in the injection part of the active region expands the current operation range of the devices, allowing laser operation at and above room temperature. The observed threshold current density is 4.0 kA/cm{sup 2} at 300 K; the maximum operation temperature is 340 K.

Ohtani, K.; Moriyasu, Y.; Ohnishi, H.; Ohno, H. [Laboratory for Nanoelectronics and Semiconductor Spintronics, Research Institute of Electrical Communication, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai 980-8577 (Japan)

2007-06-25T23:59:59.000Z

107

Strength and ductility of room-dry and water-saturated igneous rocks at low pressures and temperatures to partial melting. Final report  

DOE Green Energy (OSTI)

Rock types that are likely candidates for drilling were tested. Reported herein are the short-time ultimate strengths and ductilities determined at temperatures of 25/sup 0/ to 1050/sup 0/C and a strain rate of 10/sup -4/s/sup -1/ of (a) room-dry Mt. Hood Andesite, Cuerbio Basalt, and Charcoal (St. Cloud Gray) Granodiorite at confining pressures of 0, 50, and 100 MPa, (b) water-saturated specimens of the same three rocks at zero effective pressure (both pore and confining pressures of 50 MPa), and (c) room-dry Newberry Rhyolite Obsidian at 0 and 50 MPa. These strengths are then compared with the stresses developed at the wall of a borehole in an elastic medium at the appropriate temperatures and mean pressures to assess the problem of borehole stability. (MHR)

Friedman, M.; Handin, J.; Higgs, N.G.; Lantz, J.R.; Bauer, S.J.

1980-11-01T23:59:59.000Z

108

Effect of small additions of silicon, iron, and aluminum on the room-temperature tensile properties of high-purity uranium  

DOE Green Energy (OSTI)

Eleven binary and ternary alloys of uranium and very low concentrations of iron, silicon, and aluminum were prepared and tested for room-temperature tensile properties after various heat treatments. A yield strength approximately double that of high-purity derby uranium was obtained from a U-400 ppM Si-200 ppM Fe alloy after beta solution treatment and alpha aging. Higher silicon plus iron alloy contents resulted in increased yield strength, but showed an unacceptable loss of ductility.

Ludwig, R.L.

1983-11-14T23:59:59.000Z

109

Sb[subscript 2]Te[subscript 3] and Bi[subscript 2]Te[subscript 3] Thin Films Grown by Room-Temperature MBE  

Science Conference Proceedings (OSTI)

Sb{sub 2}Te3 and Bi{sub 2}Te3 thin films were grown on SiO{sub 2} and BaF{sub 2} substrates at room temperature using molecular beam epitaxy. Metallic layers with thicknesses of 0.2 nm were alternately deposited at room temperature, and the films were subsequently annealed at 250 C for 2 h. x-Ray diffraction and energy-filtered transmission electron microscopy (TEM) combined with high-accuracy energy-dispersive x-ray spectrometry revealed stoichiometric films, grain sizes of less than 500 nm, and a texture. High-quality in-plane thermoelectric properties were obtained for Sb{sub 2}Te3 films at room temperature, i.e., low charge carrier density (2.6 x 10{sup 19} cm{sup -3}, large thermopower (130 {micro}V K{sup -1}), large charge carrier mobility (402 cm{sup 2} V{sup -1} s{sup -1}), and resulting large power factor (29 {micro}W cm{sup -1} K{sup -2}). Bi{sub 2}Te3 films also showed low charge carrier density (2.7 x 10{sup 19} cm{sup -3}), moderate thermopower (-153 {micro}V K{sup -1}), but very low charge carrier mobility (80 cm{sup 2} V{sup -1} s{sup -1}), yielding low power factor (8 {micro}W cm{sup -1} K{sup -2}). The low mobilities were attributed to Bi-rich grain boundary phases identified by analytical energy-filtered TEM.

Aabdin, Z.; Peranio, N.; Winkler, M.; Bessas, D.; König, J.; Hermann, R.P.; Böttner, H.; Eibl, O. (Julich); (Tubingen); (Fraunhofer)

2012-10-23T23:59:59.000Z

110

Solid particle erosion behavior of an Si{sub 3}N{sub 4}-MoSi{sub 2} composite at room and elevated temperatures  

SciTech Connect

The solid particle erosion behavior at room and elevated temperatures (180, 500, 700 and 900 C) of an Si{sub 3}N{sub 4}-MoSi{sub 2} composite was studied. Alumina particles entrained in a stream of nitrogen gas impacted the target material at a velocity of 40 m/s. Impingement angles of either 60, 75 or 90{degree} were used. It was found that the erosion rate for the Si{sub 3}N{sub 4}-MoSi{sub 2} composite (measured at room temperature) was a maximum at the 90{degree} incident angle, erosion behavior typical of brittle materials. The erosion rate of the composite at a 75{degree} impingement angle increased slightly with increasing test temperature up to 700 C (i.e. from 4.1 to 4.9 mm{sup 3}/g). At 900 C, the measured erosion rate decreased to 2.9 mm{sup 3}/g. The erosion behavior of the Si{sub 3}N{sub 4}-MoSi{sub 2} composite was compared to that of commercially available Si{sub 3}N{sub 4}, WC-6%Co, 304 SS, IN-800 (Ni-Fe-Cr alloy) and Stellite-6B (Co-Cr-W-Mo alloy).

Alman, D.E.; Tylczak, J.H.; Hawk, J.A.; Hebsur, M.G.

1999-03-15T23:59:59.000Z

111

Solid particle erosion behavior of an Si[sub 3]N[sub 4]-MoSi[sub 2] composite at room and elevated temperatures  

SciTech Connect

The solid particle erosion behavior at room and elevated temperatures (180, 500, 700 and 900 C) of an Si[sub 3]N[sub 4]-MoSi[sub 2] composite was studied. Alumina particles entrained in a stream of nitrogen gas impacted the target material at a velocity of 40 m/s. Impingement angles of either 60, 75 or 90[degree] were used. It was found that the erosion rate for the Si[sub 3]N[sub 4]-MoSi[sub 2] composite (measured at room temperature) was a maximum at the 90[degree] incident angle, erosion behavior typical of brittle materials. The erosion rate of the composite at a 75[degree] impingement angle increased slightly with increasing test temperature up to 700 C (i.e. from 4.1 to 4.9 mm[sup 3]/g). At 900 C, the measured erosion rate decreased to 2.9 mm[sup 3]/g. The erosion behavior of the Si[sub 3]N[sub 4]-MoSi[sub 22048mposite was compared to that of commercially available Si[sub 3]N[sub 4], WC-6%Co, 304 SS, IN-800 (Ni-Fe-Cr alloy) and Stellite-6B (Co-Cr-W-Mo alloy).

Alman, D.E.; Tylczak, J.H.; Hawk, J.A.; Hebsur, M.G.

1999-03-15T23:59:59.000Z

112

Novel hydrophobic ionic liquids electrolyte based on cyclic sulfonium used in dye-sensitized solar cells  

Science Conference Proceedings (OSTI)

A novel series of hydrophobic room temperature ionic liquids based on six cyclic sulfonium cations were first time synthesized and applied in dye-sensitized solar cells as pure solvents for electrolyte system. The chronoamperograms result showed that the length of substituent on sulfonium cations could inhibit the I{sub 3}{sup -} diffusion and the five-ring structure of sulfonium was benefit for fast triiodide ion diffusion. The electrochemical impendence spectra measurement of dye-sensitized solar cells with these ionic liquid electrolytes was carried out and the result indicated that the cations' structure had indeed influence on the cells' performance especially for the fill factor, which was further proved by the measurement result of I-V curves of these dye-sensitized solar cells. The conclusion was obtained that the electron exchange reaction on Pt counter electrode/electrolyte interface dominated the cells' performance for these ionic liquid electrolyte-based DSCs. (author)

Guo, Lei; Pan, Xu; Wang, Meng; Zhang, Changneng; Fang, Xiaqin; Chen, Shuanghong; Dai, Songyuan [Key Lab of Novel Thin Film Solar Cells, Institute of Plasma Physics, Chinese Academy of Sciences, P.O. Box 1126, Hefei, Anhui 230031 (China)

2011-01-15T23:59:59.000Z

113

Stress-induced VO{sub 2} films with M2 monoclinic phase stable at room temperature grown by inductively coupled plasma-assisted reactive sputtering  

SciTech Connect

We report on growth of VO{sub 2} films with M2 monoclinic phase stable at room temperature under atmospheric pressure. The films were grown on quartz glass and Si substrates by using an inductively coupled plasma-assisted reactive sputtering method. XRD-sin{sup 2}{Psi} measurements revealed that the films with M2 phase are under compressive stress in contrast to tensile stress of films with M1 phase. Scanning electron microscopy observations revealed characteristic crystal grain aspects with formation of periodical twin structure of M2 phase. Structural phase transition from M2 to tetragonal phases, accompanied by a resistance change, was confirmed to occur as the temperature rises. Growth of VO{sub 2} films composed of M2 phase crystalline is of strong interest for clarifying nature of Mott transition of strongly correlated materials.

Okimura, Kunio; Watanabe, Tomo [School of Engineering, Tokai University, 4-1-1 Kitakaname, Hiratsuka, Kanagawa 259-1292 (Japan); Sakai, Joe [GREMAN, UMR 7347 CNRS, Universite Francois Rabelais de Tours, Parc de Grandmont 37200 Tours (France)

2012-04-01T23:59:59.000Z

114

Giant tunneling magnetoresistance up to 410% at room temperature in fully epitaxial Co/MgO/Co magnetic tunnel junctions with bcc Co(001) electrodes  

SciTech Connect

Fully epitaxial Co(001)/MgO(001)/Co(001) magnetic tunnel junctions (MTJs) with metastable bcc Co(001) electrodes were fabricated with molecular beam epitaxy. The MTJs exhibited giant magnetoresistance (MR) ratios up to 410% at room temperature, the highest value reported to date. Temperature dependence of the MR ratio was observed to be very small compared with fully epitaxial Fe/MgO/Fe and textured CoFeB/MgO/CoFeB MTJs. The MR ratio of the Co/MgO/Co MTJ showed larger bias voltage dependence than that of the epitaxial Fe/MgO/Fe MTJs, which probably reflects the band structures of bcc Co and Fe for the k{sub parallel}=0 direction.

Yuasa, Shinji; Fukushima, Akio; Kubota, Hitoshi; Suzuki, Yoshishige; Ando, Koji [National Institute of Advanced Industrial Science and Technology (AIST), Nanoelectronics Research Institute, Tsukuba, Ibaraki 305-8568 (Japan) and SORST, Japan Science and Technology Agency (JST), Kawaguchi, Saitama 332-0012 (Japan); National Institute of Advanced Industrial Science and Technology (AIST), Nanoelectronics Research Institute, Tsukuba, Ibaraki 305-8568 (Japan)

2006-07-24T23:59:59.000Z

115

Anomalous high ionic conductivity of nanoporous -Li3PS4  

Science Conference Proceedings (OSTI)

Lithium-ion conducting solid electrolytes hold the promise for enabling high-energy battery chemistries and circumventing safety issues of conventional lithium batteries1-3. Achieving the combination of high ionic conductivity and broad electrochemical window in solid electrolytes is a grand challenge for the synthesis of battery materials. Herein we show an enhancement of room-temperature lithium-ion conductivity of 3 orders of magnitude by creating nanostructured Li3PS4. This material has a wide (5V) electrochemical window and superior chemical stability against lithium metal. The nanoporous structure of Li3PS4 reconciles two vital effects that enhance ionic conductivity: (1) The reduced dimension to nanometer-sized framework stabilizes the high conduction beta phase that occurs at elevated temperatures1,4; and (2) The high surface-to-bulk ratio of nanoporous -Li3PS4 promotes surface conduction5,6. Manipulating the ionic conductivity of solid electrolytes has far-reaching implications for materials design and synthesis in a broad range of applications such as batteries, fuel-cells, sensors, photovoltaic systems, and so forth3,7.

Liu, Zengcai [ORNL; Fu, Wujun [ORNL; Payzant, E Andrew [ORNL; Yu, Xiang [ORNL; Wu, Zili [ORNL; Dudney, Nancy J [ORNL; Kiggans, Jim [ORNL; Hong, Kunlun [ORNL; Rondinone, Adam Justin [ORNL; Liang, Chengdu [ORNL

2013-01-01T23:59:59.000Z

116

Sub-250 nm room-temperature optical gain from AlGaN/AlN multiple quantum wells with strong band-structure potential fluctuations  

Science Conference Proceedings (OSTI)

Deep-UV optical gain has been demonstrated in Al{sub 0.7}Ga{sub 0.3}N/AlN multiple quantum wells under femtosecond optical pumping. Samples were grown by molecular beam epitaxy under a growth mode that introduces band structure potential fluctuations and high-density nanocluster-like features within the AlGaN wells. A maximum net modal gain value of 118 {+-} 9 cm{sup -1} has been measured and the transparency threshold of 5 {+-} 1 {mu}J/cm{sup 2} was experimentally determined, corresponding to 1.4 x 10{sup 17} cm{sup -3} excited carriers. These findings pave the way for the demonstration of solid-state lasers with sub-250 nm emission at room temperature.

Francesco Pecora, Emanuele; Zhang Wei; Nikiforov, A.Yu.; Yin Jian; Paiella, Roberto; Dal Negro, Luca; Moustakas, T. D. [Department of Electrical and Computer Engineering and Photonics Center, Boston University, 8 Saint Mary's Street, Boston, Massachusetts 02215 (United States); Zhou Lin; Smith, David J. [Department of Physics, Arizona State University, Tempe, Arizona 85287 (United States)

2012-02-06T23:59:59.000Z

117

X-ray spectroscopic study of the charge state and local orderingof room-temperature ferromagnetic Mn oped ZnO  

Science Conference Proceedings (OSTI)

The charge state and local ordering of Mn doped into a pulsed laser deposited single-phase thin film of ZnO are investigated by using X-ray absorption spectroscopy at the O K-, Mn K- and L-edges, and X-ray emission spectroscopy at the O K- and Mn L-edge. This film is found to be ferromagnetic at room temperature. EXAFS measurement shows that Mn{sup 2+} replaces Zn site in tetrahedral symmetry, and there is no evidence for either metallic Mn or MnO in the film. Upon Mn doping, the top of O 2p valence band extends into the bandgap indicating additional charge carries being created.

Guo, J.-H.; Gupta, Amita; Sharma, Parmanand; Rao, K.V.; Marcus,M.A.; Dong, C.L.; Guillen, J.M.O.; Butorin, S.M.; Mattesini, M.; Glans,P.A.; Smith, K.E.; Chang, C.L.; Ahuja, R.

2007-08-07T23:59:59.000Z

118

Photoluminescence recovery by in-situ exposure of plasma-damaged n-GaN to atomic hydrogen at room temperature  

Science Conference Proceedings (OSTI)

The effect of in-situ exposure of n-GaN damaged by Cl{sub 2} plasma to atomic hydrogen (H radicals) at room temperature was investigated. We found that the PL intensities of the band-edge emission, which had been drastically reduced by plasma-beam irradiation at a Cl ion dose of 5 Multiplication-Sign 10{sup 16} cm{sup -2}, recovered to values close to those of as-grown samples after H radical exposure at a dose of 3.8 Multiplication-Sign 10{sup 17} cm{sup -2}. XPS revealed the appearance of a peak at a binding energy of 18.3 eV, which is tentatively assigned to Ga-H, and confirmed the removal of Cl after H radical exposure.

Chen, Shang; Lu, Yi; Kometani, Ryosuke; Ishikawa, Kenji; Kondo, Hiroki; Sekine, Makoto; Hori, Masaru [Nagoya University, Furo, Chikusa, Nagoya 464-8603 (Japan); Tokuda, Yutaka [Aichi Institute of Technology, Yakusa, Toyota 470-0392 (Japan)

2012-06-15T23:59:59.000Z

119

Giant tunneling magnetoresistance up to 330% at room temperature in sputter deposited Co{sub 2}FeAl/MgO/CoFe magnetic tunnel junctions  

Science Conference Proceedings (OSTI)

Magnetoresistance ratio up to 330% at room temperature (700% at 10 K) has been obtained in a spin-valve-type magnetic tunnel junction (MTJ) consisting of a full-Heusler alloy Co{sub 2}FeAl electrode and a MgO tunnel barrier fabricated on a single crystal MgO (001) substrate by sputtering method. The output voltage of the MTJ at one-half of the zero-bias value was found to be as high as 425 mV, which is the largest reported to date in MTJs using Heusler alloy electrodes. The present finding suggests that Co{sub 2}FeAl may be one of the most promising candidates for future spintronics devices applications.

Wang Wenhong; Sukegawa, Hiroaki; Shan, Rong; Mitani, Seiji; Inomata, Koichiro [Magnetic Materials Center, National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba 305-0047 (Japan)

2009-11-02T23:59:59.000Z

120

Highest transmittance and high-mobility amorphous indium gallium zinc oxide films on flexible substrate by room-temperature deposition and post-deposition anneals  

Science Conference Proceedings (OSTI)

Amorphous indium gallium zinc oxide (a-IGZO) thin films of the highest transmittance reported in literature were initially deposited onto flexible polymer substrates at room temperature. The films were annealed in vacuum, air, and oxygen to enhance their electrical and optical performances. Electrical and optical characterizations were done before and after anneals. A partial reversal of the degradation in electrical properties upon annealing in oxygen was achieved by subjecting the films to subsequent vacuum anneals. A model was developed based on film texture and structural defects which showed close agreement between the measured and calculated carrier mobility values at low carrier concentrations (2-6 x 10{sup 19} cm{sup -3}).

Gadre, Mandar J. [School for Engineering of Matter, Transport and Energy, Arizona State University, Tempe, Arizona 85287 (United States); Alford, T. L. [School for Engineering of Matter, Transport and Energy, Arizona State University, Tempe, Arizona 85287 (United States); Flexible Display Center at Arizona State University, Tempe, Arizona 85284 (United States)

2011-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Structure, optical, and electrical properties of indium tin oxide thin films prepared by sputtering at room temperature and annealed in air or nitrogen  

Science Conference Proceedings (OSTI)

Indium tin oxide (ITO) thin films have been grown onto soda-lime glass substrates by sputtering at room temperature with various oxygen to argon partial pressure ratios. After deposition, the samples have been annealed at temperatures ranging from 100 to 500 degree sign C in nitrogen or in air. The structure, optical, and electrical characteristics of the ITO coatings have been analyzed as a function of the deposition and the annealing parameters by x-ray diffraction, spectrophotometry, and Hall effect measurements. It has been found that the as-grown amorphous layers crystallize in the cubic structure by heating above 200 degree sign C. Simultaneously, the visible optical transmittance increases and the electrical resistance decreases, in proportions that depend mainly on the sputtering conditions. The lowest resistivity values have been obtained by annealing at 400 degree sign C in nitrogen, where the highest carrier concentrations are achieved, related to oxygen vacancy creation. Some relationships between the analyzed properties have been established, showing the dependence of the cubic lattice distortion and the infrared optical characteristics on the carrier concentration.

Guillen, C.; Herrero, J. [Departamento de Energia, CIEMAT, Avda Complutense 22, 28040 Madrid (Spain)

2007-04-01T23:59:59.000Z

122

Polymeric electrolytes for ambient temperature lithium batteries  

DOE Green Energy (OSTI)

A new type of highly conductive Li{sup +} polymer electrolyte, referred to as the Innovision polymer electrolyte, is completely amorphous at room temperature and has an ionic conductivity in the range of 10{sup {minus}3} S/cm. This report discusses the electrochemical characteristics (lithium oxidation and reduction), conductivity, and physical properties of Innovision electrolytes containing various dissolved salts. These electrolytes are particularly interesting since they appear to have some of the highest room-temperature lithium ion conductivities yet observed among polymer electrolytes. 13 refs. 11 figs., 2 tabs.

Farrington, G.C. (Pennsylvania Univ., Philadelphia, PA (United States). Dept. of Materials Science and Engineering)

1991-07-01T23:59:59.000Z

123

Novel room temperature ferromagnetic semiconductors  

E-Print Network (OSTI)

would reduce the device size, power consumption, and exploitdevices will be higher speed, greater efficiency, and better stability at a reduced power consumption.

Gupta, Amita

2004-01-01T23:59:59.000Z

124

Heating remote rooms in passive solar buildings  

DOE Green Energy (OSTI)

Remote rooms can be effectively heated by convection through a connecting doorway. A simple steady-state equation is developed for design purposes. Validation of a dynamic model is achieved using data obtained over a 13-day period. Dynamic effects are investigated using a simulation analysis for three different cases of driving temperature; the effect is to reduce the temperature difference between the driving room and the remote room compared to the steady-state model. For large temperature swings in the driving room a strategy which uses the intervening door in a diode mode is effective. The importance of heat-storing mass in the remote room is investigated.

Balcomb, J.D.

1981-01-01T23:59:59.000Z

125

Room temperature metathetic synthesis and characterization of {alpha}-hopeite, Zn{sub 3}(PO{sub 4}){sub 2}.4H{sub 2}O  

SciTech Connect

The synthesis of crystalline zinc phosphates ({alpha}-hopeite phase) through the metathetic pathway has been investigated. The reaction has been carried out by room-temperature grinding. High lattice energy of the by-product NaCl has driven the reaction in the forward direction, and as a result, stable phosphate phases have been synthesized. Reaction of a different phosphorus source (like Na{sub 3}PO{sub 4}, Na{sub 2}HPO{sub 4}, NaH{sub 2}PO{sub 4}, and K{sub 2}HPO{sub 4}) with ZnCl{sub 2} has been attempted. The structural, vibrational, thermal, optical, and chemical properties of synthesized powders are determined by powder X-ray diffraction (XRD), scanning electron microscope (SEM), thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR) and diffused reflectance spectra (DR) in the UV-vis range. The direct band gap of the title compound was determined to be 3.6 {+-} 0.2 eV.

Parhi, Purnendu [Department of Mechanical Engineering, Colorado State University, Fort Collins, CO 80523 (United States); Manivannan, V. [Department of Mechanical Engineering, Colorado State University, Fort Collins, CO 80523 (United States)], E-mail: mani@engr.colostate.edu; Kohli, Sandeep; McCurdy, Patrick [Department of Chemistry, Colorado State University, Fort Collins, CO 80523 (United States)

2008-07-01T23:59:59.000Z

126

In-situ Analysis of Zinc Electrodeposition within an Ionic Liquid Electrolyte  

E-Print Network (OSTI)

chloride low temperature molten salt. Electrochimica Acta,room temperature molten salt. Journal of the Electrochemical

Keist, Jayme

2013-01-01T23:59:59.000Z

127

The Current-voltage Characteristics of Grain Boundaries in Ionic ...  

Science Conference Proceedings (OSTI)

Presentation Title, The Current-voltage Characteristics of Grain Boundaries in Ionic ... A High-temperature Mössbauer Study of Iron-doped Ruddlesden-popper  ...

128

Ultrastable Superbase-Derived Protic Ionic Liquids - Energy ...  

Description Protic ionic liquids have had a propensity to degrade over time and in high temperature ... capacitors, metal finishing) Dye ... Development Stage

129

Supported Ionic Liquid Membranes for Gas Separation  

SciTech Connect

Ionic liquids have been rapidly gaining attention for various applications including solvent separation and gas capture. These substances are noted for extremely low vapor pressure and high CO2 solubility making them ideal as transport or capture media for CO2 abatement in power generation applications. Ionic liquids, combined with various supports to form membranes, have been proven selective in CO2 separation. Several ionic liquids and a variety of polymer supports have been studied over a temperature range from 37°C to 300°C and have been optimized for stability. The membranes have demonstrated high permeability and high selectivity since the supported ionic liquid membranes incorporate functionality capable of chemically complexing CO2. A study aimed at improving supported ionic liquid membranes will examine their durability with greater transmembrane pressures and the effects on CO2 permeance, CO2/H2 selectivity and thermal stability.

Myers, C.R.; Ilconich, J.B.; Pennline, H.W.; Luebke, D.R.

2007-08-01T23:59:59.000Z

130

Checkerboard Self-Patterning of an Ionic Liquid Film on Mercury  

SciTech Connect

{angstrom}-resolution studies of room temperature ionic liquid (RTIL) interfaces are scarce, in spite of their long-recognized importance for the science and many applications of RTILs. We present an {angstrom}-resolution x-ray study of a Langmuir film of an RTIL on mercury. At low (high) coverage [90 (50) {angstrom}{sup 2}/molecule] a mono-(bi)layer of surface-parallel molecules is found. The molecules self-assemble in a lateral ionic checkerboard pattern, unlike the uniform-charge, alternate-ion layers of this RTIL at its bulk-solid interface. A 2D-smectic order is found, with molecules packed in parallel stripes, forming long-range order normal to, but none along, the stripes.

L Tamam; B Ocko; H Reichert; M Deutsch

2011-12-31T23:59:59.000Z

131

Checkerboard Self-Patterning of an Ionic Liquid Film on Mercury  

Science Conference Proceedings (OSTI)

{angstrom}-resolution studies of room temperature ionic liquid (RTIL) interfaces are scarce, in spite of their long-recognized importance for the science and many applications of RTILs. We present an {angstrom}-resolution x-ray study of a Langmuir film of an RTIL on mercury. At low (high) coverage [90 (50) {angstrom}{sup 2}/molecule] a mono-(bi)layer of surface-parallel molecules is found. The molecules self-assemble in a lateral ionic checkerboard pattern, unlike the uniform-charge, alternate-ion layers of this RTIL at its bulk-solid interface. A 2D-smectic order is found, with molecules packed in parallel stripes, forming long-range order normal to, but none along, the stripes.

Ocko, B.M.; Tamam, L.; Reichert, H.; Deutsch, M.

2011-05-10T23:59:59.000Z

132

Role of Amorphous Boundary Layer in Enhancing Ionic Conductivity of Lithium–lanthanum–titanate Electrolyte  

DOE Green Energy (OSTI)

The low ionic conductivity is a bottleneck of the inorganic solid state electrolyte used for lithium ion battery. In ceramic electrolytes, grain boundary usually dominates the total conductivity. In order to improve the grain boundary effect, an amorphous silica layer is introduced into grain boundary of ceramic electrolytes based on lithium-lanthanum-titanate, as evidenced by electron microscopy. The results showed that the total ionic conductivity could be to be enhanced over 1 x 10{sup -4} S/cm at room temperature. The reasons can be attributed to removing the anisotropy of outer-shell of grains, supplement of lithium ions in various sites in grain boundary and close bindings among grains by the amorphous boundary layer among grains.

Mei, A.; Wang, X.; Lana, J.-L.; Fenga, Y.-C.; Genga, H.-X.; Lina, Y.-H.; Nana, C.-W.

2010-03-01T23:59:59.000Z

133

Molecular mechanism of gas adsorption into ionic liquids: A molecular dynamics study  

Science Conference Proceedings (OSTI)

Room temperature ionic liquids (RTILs) have been shown to be versatile and tunable solvents that can be used in many chemical applications. In this study, we developed a dynamical, molecular-scale picture of the gas dissolution and interfacial processes in RTILs using molecular simulations. These simulations can provide the free energies associated with transporting a gas solute across various RTIL interfaces and physical insights into the interfacial properties and transport molecular mechanism of gas sorption processes. For CO2 sorption, the features in the potential of mean force (PMF) of CO2 using both polarizable and non-polarizable force fields are similar qualitatively. However, we observed some quantitative differences, and we describe the causes of these differences in this paper. We also show the significant impact of ionic-liquid chemical structures on the gas sorption process, and we discuss their influence on the H2O transport mechanism.

Dang, Liem X.; Chang, Tsun-Mei

2012-01-19T23:59:59.000Z

134

Ionic Liquids for Utilization of Waste Heat from Distributed Power Generation Systems  

Science Conference Proceedings (OSTI)

The objective of this research project was the development of ionic liquids to capture and utilize waste heat from distributed power generation systems. Ionic Liquids (ILs) are organic salts that are liquid at room temperature and they have the potential to make fundamental and far-reaching changes in the way we use energy. In particular, the focus of this project was fundamental research on the potential use of IL/CO2 mixtures in absorption-refrigeration systems. Such systems can provide cooling by utilizing waste heat from various sources, including distributed power generation. The basic objectives of the research were to design and synthesize ILs appropriate for the task, to measure and model thermophysical properties and phase behavior of ILs and IL/CO2 mixtures, and to model the performance of IL/CO2 absorption-refrigeration systems.

Joan F. Brennecke; Mihir Sen; Edward J. Maginn; Samuel Paolucci; Mark A. Stadtherr; Peter T. Disser; Mike Zdyb

2009-01-11T23:59:59.000Z

135

Ionic conductors for solid oxide fuel cells  

DOE Patents (OSTI)

An electrolyte that operates at temperatures ranging from 600{degree}C to 800{degree}C is discussed. The electrolyte conducts charge ionically as well as electronically. The ionic conductors include molecular framework structures having planes or channels large enough to transport oxides or hydrated protons and having net-positive or net-negative charges. Representative molecular framework structures include substituted aluminum phosphates, orthosilicates, silicoaluminates, cordierites, apatites, sodalites, and hollandites.

Krumpelt, M.; Bloom, I.D.; Pullockaran, J.D.; Myles, K.M.

1991-12-31T23:59:59.000Z

136

Partially fluorinated ionic compounds  

DOE Patents (OSTI)

Partially fluorinated ionic compounds are prepared. They are useful in the preparation of partially fluorinated dienes, in which the repeat units are cycloaliphatic.

Han, legal representative, Amy Qi (Hockessin, DE); Yang, Zhen-Yu (Hockessin, DE)

2008-11-25T23:59:59.000Z

137

SRO : single room occupancy  

E-Print Network (OSTI)

During August of 1996, I stayed in a series of SRO hotels in New York City leaving a book and diary behind when I checked out of each room. The books that were left in the rooms differ from one room to the other but all ...

Shimada, Taketo

1997-01-01T23:59:59.000Z

138

Brownian dynamics determine universality of charge transport in ionic liquids  

Science Conference Proceedings (OSTI)

Broadband dielectric spectroscopy is employed to investigate charge transport in a variety of glass-forming ionic liquids over wide frequency, temperature and pressure ranges. Using a combination of Einstein, Einstein-Smoluchowski, and Langevin relations, the observed universal scaling of charge transport in ionic liquids is traced back to the dominant role of Brownian dynamics.

Sangoro, Joshua R [ORNL; Iacob, Ciprian [University of Leipzig; Mierzwa, Michal [University of Silesia, Uniwersytecka, Katowice, Poland; Paluch, Marian [University of Silesia, Uniwersytecka, Katowice, Poland; Kremer, Friedrich [University of Leipzig

2012-01-01T23:59:59.000Z

139

Public Reading Room  

Office of Legacy Management (LM)

has established a Public Reading Room at 955 has established a Public Reading Room at 955 Mound Road, Miamisburg, Ohio, which contains documents and information related to Mound as required under Section 117(d) of SARA. Copies of key Mound records, including the CERCLA Administrative Record and Information Repository, are kept in the Public Reading Room. The Administrative Record and Information Repository for Mound are updated as new documents are created and an index of documents in the complete collections accompanies each update. The Public Reading Room also contains reference items consisting of technical documents, news clippings, videotapes, journal articles, annual reports, and environmental restoration and decontamination and decommissioning decisional documents. Stakeholders are

140

Room Air Conditioners  

NLE Websites -- All DOE Office Websites (Extended Search)

of Superefficient Room Air Conditioners year month keywords appliance energy efficiency energy efficiency incentives Market Transformation standards url https isswprod lbl gov...

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Demolishing Searle's Chinese Room  

E-Print Network (OSTI)

Searle's Chinese Room argument is refuted by showing that he has actually given two different versions of the room, which fail for different reasons. Hence, Searle does not achieve his stated goal of showing ``that a system could have input and output capabilities that duplicated those of a native Chinese speaker and still not understand Chinese''.

Wolfram Schmied

2004-03-08T23:59:59.000Z

142

Formation of an SEI on a LiMn(2)O(4) Cathode during Room Temperature Charge-Discharge Cycling Studied by Soft X-Ray Absorption Spectroscopy at the Fluorine K-edge  

DOE Green Energy (OSTI)

The solid electrolyte interface (SEI) formation on the surface of LiMn{sub 2}O{sub 4} electrodes during room temperature charge-discharge cycling was studied using soft X-ray absorption spectroscopy at the Fluorine (F) K-edge. LiMn{sub 2}O{sub 4} electrodes without any binder were prepared by electrostatic spray deposition to eliminate the signal originating from the PVDF binder in the F K-edge X-ray absorption spectra. The F K-edge absorption spectra show that the SEI layer forms at a very early stage of cycling. SEI growth takes place during discharge. In addition, LiF formation is accelerated if the discharge step follows a charge step. The F K-edge absorption spectra suggest that the major component of the SEI is LiF.

Chung, K.Y.; Yang, X.; Yoon, W.-S.; Kim, K.-B.; Cho, B.-W.

2011-11-01T23:59:59.000Z

143

One-step synthesis of lightly doped porous silicon nanowires in HF/AgNO{sub 3}/H{sub 2}O{sub 2} solution at room temperature  

SciTech Connect

One-step synthesis of lightly doped porous silicon nanowire arrays was achieved by etching the silicon wafer in HF/AgNO{sub 3}/H{sub 2}O{sub 2} solution at room temperature. The lightly doped porous silicon nanowires (pNWs) have circular nanopores on the sidewall, which can emit strong green fluorescence. The surface morphologies of these nanowires could be controlled by simply adjusting the concentration of H{sub 2}O{sub 2}, which influences the distribution of silver nanoparticles (Ag NPs) along the nanowire axis. A mechanism based on Ag NPs-induced lateral etching of nanowires was proposed to explain the formation of pNWs. The controllable and widely applicable synthesis of pNWs will open their potential application to nanoscale photoluminescence devices. - Graphical abstract: The one-step synthesis of porous silicon nanowire arrays is achieved by chemical etching of the lightly doped p-type Si (100) wafer at room temperature. These nanowires exhibit strong green photoluminescence. SEM, TEM, HRTEM and photoluminescence images of pNWs. The scale bars of SEM, TEM HRTEM and photoluminescence are 10 {mu}m, 20 nm, 10 nm, and 1 {mu}m, respectively. Highlights: Black-Right-Pointing-Pointer Simple one-step synthesis of lightly doped porous silicon nanowire arrays is achieved at RT. Black-Right-Pointing-Pointer Etching process and mechanism are illustrated with etching model from a novel standpoint. Black-Right-Pointing-Pointer As-prepared porous silicon nanowire emits strong green fluorescence, proving unique property.

Bai, Fan [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 165001 (China) [School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 165001 (China); State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, North China Electric Power University, Beijing 102206 (China); Li, Meicheng, E-mail: mcli@ncepu.edu.cn [State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, North China Electric Power University, Beijing 102206 (China) [State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, North China Electric Power University, Beijing 102206 (China); Su Zhou Institute, North China Electric Power University, Suzhou 215123 (China); Song, Dandan; Yu, Hang; Jiang, Bing; Li, Yingfeng [State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, North China Electric Power University, Beijing 102206 (China)] [State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, North China Electric Power University, Beijing 102206 (China)

2012-12-15T23:59:59.000Z

144

SRNL - News Room  

NLE Websites -- All DOE Office Websites (Extended Search)

& Development Projects in the "Press Room" at www.doe.gov for further details.) Expected funding for the SRNL project is estimated at approximately one-half million dollars a year...

145

Raman Investigation of The Uranium Compounds U3O8, UF4, UH3 and UO3 under Pressure at Room Temperature  

DOE Green Energy (OSTI)

Our current state-of-the-art X-ray diffraction experiments are primarily sensitive to the position of the uranium atom. While the uranium - low-Z element bond (such as U-H or U-F) changes under pressure and temperature the X-ray diffraction investigations do not reveal information about the bonding or the stoichiometry. Questions that can be answered by Raman spectroscopy are (i) whether the bonding strength changes under pressure, as observed by either blue- or red-shifted peaks of the Raman active bands in the spectrum and (ii) whether the low-Z element will eventually be liberated and leave the host lattice, i.e. do the fluorine, oxygen, or hydrogen atoms form dimers after breaking the bond to the uranium atom. Therefore Raman spectra were also collected in the range where those decomposition products would appear. Raman is particularly well suited to these types of investigations due to its sensitivity to trace amounts of materials. One challenge for Raman investigations of the uranium compounds is that they are opaque to visible light. They absorb the incoming radiation and quickly heat up to the point of decomposition. This has been dealt with in the past by keeping the incoming laser power to very low levels on the tens of milliWatt range consequently affecting signal to noise. Recent modern investigations also used very small laser spot sizes (micrometer range) but ran again into the problem of heating and chemical sensitivity to the environment. In the studies presented here (in contrast to all other studies that were performed at ambient conditions only) we employ micro-Raman spectroscopy of samples situated in a diamond anvil cell. This increases the trustworthiness of the obtained data in several key-aspects: (a) We surrounded the samples in the DAC with neon as a pressure transmitting medium, a noble gas that is absolutely chemically inert. (b) Through the medium the sample is thermally heat sunk to the diamond anvils, diamond of course possessing the very best heat conductivity of any material. Therefore local heating and decomposition are avoided, a big challenge with other approaches casting doubts on their results. (c) This in turn benefits the signal/noise ratio tremendously since the Raman features of uranium-compounds are very small. The placement of the samples in DACs allows for higher laser powers to impinge on the sample spot while keeping the spot-size larger than in previous studies and keep the samples from heating up. Raman spectroscopy is a very sensitive non-invasive technique and we will show that it is even possible to distinguish the materials by their origin / manufacturer as we have studied samples from Cameco (Canada) and IBI-Labs (US-Florida) and can compare with ambient literature data for samples from Strem (US-MA) and Areva (Pierrelatte, France).

Lipp, M J; Jenei, Z; Park-Klepeis, J; Evans, W J

2011-12-15T23:59:59.000Z

146

REALIZING PRESSURE, TEMPERATURE, AND LENGTH ...  

Science Conference Proceedings (OSTI)

... The basic concept behind the proposed apparatus is illustrated in ... at room temperature, requiring realization of thermodynamic temperature near 23 ...

2013-07-10T23:59:59.000Z

147

Room temperature ferroelectric and magnetic investigations and detailed phase analysis of Aurivillius phase Bi{sub 5}Ti{sub 3}Fe{sub 0.7}Co{sub 0.3}O{sub 15} thin films  

Science Conference Proceedings (OSTI)

Aurivillius phase Bi{sub 5}Ti{sub 3}Fe{sub 0.7}Co{sub 0.3}O{sub 15} (BTF7C3O) thin films on {alpha}-quartz substrates were fabricated by a chemical solution deposition method and the room temperature ferroelectric and magnetic properties of this candidate multiferroic were compared with those of thin films of Mn{sup 3+} substituted, Bi{sub 5}Ti{sub 3}Fe{sub 0.7}Mn{sub 0.3}O{sub 15} (BTF7M3O). Vertical and lateral piezoresponse force microscopy (PFM) measurements of the films conclusively demonstrate that BTF7C3O and BTF7M3O thin films are piezoelectric and ferroelectric at room temperature, with the major polarization vector in the lateral plane of the films. No net magnetization was observed for the in-plane superconducting quantum interference device (SQUID) magnetometry measurements of BTF7M3O thin films. In contrast, SQUID measurements of the BTF7C3O films clearly demonstrated ferromagnetic behavior, with a remanent magnetization, B{sub r}, of 6.37 emu/cm{sup 3} (or 804 memu/g), remanent moment = 4.99 Multiplication-Sign 10{sup -5} emu. The BTF7C3O films were scrutinized by x-ray diffraction, high resolution transmission electron microscopy, scanning transmission electron microscopy, and energy dispersive x-ray analysis mapping to assess the prospect of the observed multiferroic properties being intrinsic to the main phase. The results of extensive micro-structural phase analysis demonstrated that the BTF7C3O films comprised of a 3.95% Fe/Co-rich spinel phase, likely CoFe{sub 2-x}Ti{sub x}O{sub 4}, which would account for the observed magnetic moment in the films. Additionally, x-ray magnetic circular dichroism photoemission electron microscopy (XMCD-PEEM) imaging confirmed that the majority of magnetic response arises from the Fe sites of Fe/Co-rich spinel phase inclusions. While the magnetic contribution from the main phase could not be determined by the XMCD-PEEM images, these data however imply that the Bi{sub 5}Ti{sub 3}Fe{sub 0.7}Co{sub 0.3}O{sub 15} thin films are likely not single phase multiferroics at room temperature. The PFM results presented demonstrate that the naturally 2D nanostructured Bi{sub 5}Ti{sub 3}Fe{sub 0.7}Co{sub 0.3}O{sub 15} phase is a novel ferroelectric and has potential commercial applications in high temperature piezoelectric and ferroelectric memory technologies. The implications for the conclusive demonstration of ferroelectric and ferromagnetic properties in single-phase materials of this type are discussed.

Keeney, Lynette; Kulkarni, Santosh; Deepak, Nitin; Schmidt, Michael; Petkov, Nikolay; Zhang, Panfeng F.; Roy, Saibal; Pemble, Martyn E.; Whatmore, Roger W. [Tyndall National Institute, University College Cork, 'Lee Maltings', Dyke Parade, Cork (Ireland); Cavill, Stuart [Diamond Light Source Ltd., Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0DE (United Kingdom)

2012-09-01T23:59:59.000Z

148

DOE Solar Decathlon: Press Room  

NLE Websites -- All DOE Office Websites (Extended Search)

Bios Press Releases Photos Videos Education Sponsors Volunteers History FAQs Contacts Solar Decathlon Press Room The U.S. Department of Energy Solar Decathlon press room provides...

149

Preparation and purification of ionic liquids and precursors  

DOE Patents (OSTI)

Substantially pure ionic liquids and ionic liquid precursors were prepared. The substantially pure ionic liquid precursors were used to prepare substantially pure ionic liquids.

Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McCleskey, T. Mark (Los Alamos, NM); Agrawal, Anoop (Tucson, AZ)

2010-07-27T23:59:59.000Z

150

Room Temperature Single Phase Multiferroics for Multifunctional ...  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2013. Symposium, Advances in Dielectric Materials and Electronic Devices. Presentation Title ...

151

Room Temperature Dispenser Photocathode Using Elemental Cesium  

NLE Websites -- All DOE Office Websites (Extended Search)

of devices depending upon the application, while offering a considerable reduction in power consumption and maintenance costs. Typically, alkali-metal coatings with generally...

152

Room Temperature Mechanical Properties of Tin Telluride ...  

Science Conference Proceedings (OSTI)

High Thermal Energy Storage Density LiNO3-KNO3-NaNO2-KNO2 Quaternary Molten Salt System for Parabolic Trough Concentrating Solar Power Generation.

153

098 Room Temperature Multiferroism in Nanocapacitors  

Science Conference Proceedings (OSTI)

129 Minimization of Diametric Tolerance of U3O8-added UO2 Annular Pellet .... 220 Microwave Processing of Polymer Coatings on Instrument-Grade Wood.

154

Methods of using ionic liquids having a fluoride anion as solvents  

SciTech Connect

A method in one embodiment includes contacting a strongly hydrogen bonded organic material with an ionic liquid having a fluoride anion for solubilizing the strongly hydrogen bonded organic material; and maintaining the ionic liquid at a temperature of about 90.degree. C. or less during the contacting. A method in another embodiment includes contacting a strongly hydrogen bonded organic material with an ionic liquid having an acetate or formate anion for solubilizing the strongly hydrogen bonded organic material; and maintaining the ionic liquid at a temperature of less than about 90.degree. C. during the contacting.

Pagoria, Philip (Livermore, CA); Maiti, Amitesh (San Ramon, CA); Gash, Alexander (Brentwood, CA); Han, Thomas Yong (Pleasanton, CA); Orme, Christine (Oakland, CA); Fried, Laurence (Livermore, CA)

2011-12-06T23:59:59.000Z

155

Development of Practical Supported Ionic Liquid Membranes: A Systematic Approach  

DOE Green Energy (OSTI)

Supported liquid membranes (SLMs) are a class of materials that allow the researcher to utilize the wealth of knowledge available on liquid properties to optimize membrane performance. These membranes also have the advantage of liquid phase diffusivities, which are higher than those observed in polymers and grant proportionally greater permeabilities. The primary shortcoming of the supported liquid membranes demonstrated in past research has been the lack of stability caused by volatilization of the transport liquid. Ionic liquids, which may possess high CO2 solubility relative to light gases such as H2, are excellent candidates for this type of membrane since they are stable at elevated temperatures and have negligible vapor pressure. A study has been conducted evaluating the use of a variety of ionic liquids in supported ionic liquid membranes for the capture of CO2 from streams containing H2. In a joint project, researchers at the University of Notre Dame synthesized and characterized ionic liquids, and researchers at the National Energy Technology Laboratory incorporated candidate ionic liquids into supports and evaluated membrane performance for the resulting materials. Several steps have been taken in the development of practical supported ionic liquid membranes. Proof-of-concept was established by showing that ionic liquids could be used as the transport media in SLMs. Results showed that ionic liquids are suitable media for gas transport, but the preferred polymeric supports were not stable at temperatures above 135oC. The use of cross-linked nylon66 supports was found to produce membranes mechanically stable at temperatures exceeding 300oC but CO2/H2 selectivity was poor. An ionic liquid whose selectivity does not decrease with increasing temperature was needed, and a functionalized ionic liquid that complexes with CO2 was used. An increase in CO2/H2 selectivity with increasing temperature over the range of 37 to 85oC was observed and the dominance of a facilitated transport mechanism established. The presentation will detail membrane development, the effect of increasing transmembrane pressure, and preliminary results dealing with other gas pairs and contaminants.

Luebke, D.R.; Ilconich, J.B.; Myers, C.R.; Pennline, H.W.

2007-11-01T23:59:59.000Z

156

Electronic Reading Room  

NLE Websites -- All DOE Office Websites (Extended Search)

Electronic Reading Room - making information about the Freedom of Information Act (FOIA) and Privacy Act process accessible to the public electronically. Electronic Reading Room - making information about the Freedom of Information Act (FOIA) and Privacy Act process accessible to the public electronically. Major Information Systems - Final Opinions - [5 USC 552 (a)(2)](A) final opinions, including concurring and dissenting opinions, as well as orders, made in the adjudication of cases within the Office of Hearings and Appeals Statements of Policy and Interpretation and Administrative Staff Manuals and Instructions - [5 USC 552 (a)(2)](B) those statements of policy and interpretation which have been adopted by the agency and are not published in the Federal Register - Directives, DOE Orders, Headquarters Orders, Secretarial Notices, Technical Standards, Forms, Delegations, Electronic Library Public Reading Facilities - making information available for public inspection and copying

157

Reading Room Locations  

NLE Websites -- All DOE Office Websites (Extended Search)

FOIA Offices and Reading Rooms FOIA Offices and Reading Rooms FOIA Office Locations Our FOIA Officers are located at various sites throughout the DOE complex, each with responsibility for records located at or under the jurisdiction of the site. We recommend that you send your request directly to that specific site. This will shorten the processing time. However, if you do not know which location has responsive records, you may either call the Headquarters FOIA office at (202) 586-5955 to determine the appropriate office, or mail the request to the Headquarters FOIA office. Other records are publicly available in the facilities listed below: Headquarters U.S. Department of Energy FOIA/Privacy Act Group 1000 Independence Avenue, SW Washington, D.C. 20585 Phone: 202-586-5955 Fax: 202-586-0575

158

Energy Harvesting Applications of Ionic Polymers.  

E-Print Network (OSTI)

??Energy Harvesting Applications of Ionic Polymers Benjamin R. Martin Abstract The purpose of this thesis is the development and analysis of applications for ionic polymers… (more)

Martin, Benjamin Ryan

2005-01-01T23:59:59.000Z

159

journal Solid State Ionics  

NLE Websites -- All DOE Office Websites (Extended Search)

Structural and transport properties of Nafion in hydrobromic Structural and transport properties of Nafion in hydrobromic acid solutions journal Solid State Ionics year month abstract p Proton exchange membranes are key solid state ion carriers in many relevant energy technologies including flow batteries fuel cells and solar fuel generators In many of these systems the membranes are in contact with electrolyte solutions In this paper we focus on the impact of different HBr a flow battery and exemplary acid electrolyte external concentrations on the conductivity of Nafion a perfluorosulfonic acid membrane that is commonly used in many energy related applications The peak and then decrease in conductivity is correlated with measured changes in the water and HBr content within the membrane In addition small angle x ray scattering is used to probe the nanostructure to

160

Room-temperature MBE deposition, thermoelectric properties, and advanced structural characterization of binary Bi[subscript 2]Te[subscript 3] and Sb[subscript 2]Te[subscript 3] thin films  

Science Conference Proceedings (OSTI)

Sb{sub 2}Te{sub 3} and Bi{sub 2}Te{sub 3} thin films were grown at room temperature on SiO{sub 2} and BaF{sub 2} substrates using molecular beam epitaxy. A layer-by-layer growth was achieved such that metallic layers of the elements with 0.2 nm thickness were deposited. The layer structure in the as-deposited films was confirmed by X-ray diffraction and was seen more clearly in Sb{sub 2}Te{sub 3} thin films. Subsequent annealing was done at 250 C for 2 h and produced the Sb{sub 2}Te{sub 3} and Bi{sub 2}Te{sub 3} crystal structure as confirmed by high-energy X-ray diffraction. This preparation process is referred to as nano-alloying and it was demonstrated to yield single-phase thin films of these compounds. In the thin films a significant texture could be identified with the crystal c axis being almost parallel to the growth direction for Sb{sub 2}Te{sub 3} and tilted by about 30{sup o} for Bi{sub 2}Te{sub 3} thin films. In-plane transport properties were measured for the annealed films at room temperature. Both films yielded a charge carrier density of about 2.6 x 10{sup 19} cm{sup -3}. The Sb{sub 2}Te{sub 3} films were p-type, had a thermopower of +130 {micro}V K{sup -1}, and surprisingly high mobilities of 402 cm{sup 2} V{sup -1} s{sup -1}. The Bi{sub 2}Te{sub 3} films were n-type, showed a thermopower of -153 {micro}V K{sup -1}, and yielded significantly smaller mobilities of 80 cm2 V{sup -1} s{sup -1}. The chemical composition and microstructure of the films were investigated by transmission electron microscopy (TEM) on cross sections of the thin films. The grain sizes were about 500 nm for the Sb{sub 2}Te{sub 3} and 250 nm for the Bi{sub 2}Te{sub 3} films. In the Bi{sub 2}Te{sub 3} thin film, energy-filtered TEM allowed to image a Bi-rich grain boundary phase, several nanometers thick. This secondary phase explains the poor mobilities of the Bi{sub 2}Te{sub 3} thin film. With these results the high potential of the nano-alloying deposition technique for growing films with a more complex layer architecture is demonstrated.

Peranio, N.; Winkler, M.; Bessas, D.; Aabdin, Z.; König, J.; Böttner, H.; Hermann, R.P.; Eibl, O. (Julich); (Tubingen); (Fraunhofer)

2012-10-23T23:59:59.000Z

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Energy Efficient Electrochromic Windows Incorporating Ionic Liquids  

SciTech Connect

One approach to increasing the energy efficiency of windows is to control the amount of solar radiation transmitted through a window by using electrochromic technology. What is unique about this project is that the electrochromic is based on the reduction/oxidation reactions of cathodic and anodic organic semi-conducting polymers using room temperature ionic liquids as ion transport electrolytes. It is believed that these types of coatings would be a lower cost alternative to traditional all inorganic thin film based electrochromic technologies. Although there are patents1 based on the proposed technology, it has never been reduced to practice and thoroughly evaluated (i.e. durability and performance) in a window application. We demonstrate that by using organic semi-conductive polymers, specific bands of the solar spectrum (specifically visible and near infrared) can be targeted for electrochemical variable transmittance responsiveness. In addition, when the technology is incorporated into an insulating glass unit, the energy parameters such as the solar heat gain coefficient and the light to solar gain ratio are improved over that of a typical insulating glass unit comprised of glass with a low emissivity coating. A minimum of {approx}0.02 quads of energy savings per year with a reduction of carbon emissions for electricity of {approx}320 MKg/yr benefit is achieved over that of a typical insulating glass unit including a double silver low-E coating. Note that these values include a penalty in the heating season. If this penalty is removed (i.e. in southern climates or commercial structures where cooling is predominate year-round) a maximum energy savings of {approx}0.05 quad per year and {approx}801 MKg/yr can be achieved over that of a typical insulating glass unit including a double silver low-E coating. In its current state, the technology is not durable enough for an exterior window application. The primary downfall is that the redox chemistry fails to recover to a bleached state upon exposure to heat and solar radiation while being cycled over time from the bleached to the dark state. Most likely the polymers are undergoing degradation reactions which are accelerated by heat and solar exposure while in either the reduced or oxidized states and the performance of the polymers is greatly reduced over time. For this technology to succeed in an exterior window application, there needs to be more work done to understand the degradation of the polymers under real-life application conditions such as elevated temperatures and solar exposure so that recommendations for improvements in to the overall system can be made. This will be the key to utilizing this type of technology in any future real-life applications.

Cheri Boykin; James Finley; Donald Anthony; Julianna Knowles; Richard Markovic; Michael Buchanan; Mary Ann Fuhry; Lisa Perrine

2008-11-30T23:59:59.000Z

162

Radiation Chemistry of Ionic Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquids Liquids James F. Wishart, Alison M. Funston, and Tomasz Szreder in "Molten Salts XIV" Mantz, R. A., et al., Eds.; The Electrochemical Society, Pennington, NJ, (2006) pp. 802-813. [Information about the volume (look just above this link)] Abstract: Ionic liquids have potentially important applications in nuclear fuel and waste processing, energy production, improving the efficiency and safety of industrial chemical processes, and pollution prevention. Successful use of ionic liquids in radiation-filled environments will require an understanding of ionic liquid radiation chemistry. For example, characterizing the primary steps of ionic liquid radiolysis will reveal radiolytic degradation pathways and suggest ways to prevent them or mitigate their effects on the properties of the material

163

Simulation of a mannequin's thermal plume in a small room  

Science Conference Proceedings (OSTI)

Simulation results are presented for the buoyancy-driven flow in a small room containing a seated mannequin that is maintained at a constant temperature. The study was motivated, in part, by a published experimental study of the thermal plume around ... Keywords: Heated mannequin, Lattice Boltzmann method, Particle trajectories, Small room, Thermal plume

Xinli Jia; John B. Mclaughlin; Jos Derksen; Goodarz Ahmadi

2013-01-01T23:59:59.000Z

164

Hydrophobic ionic liquids  

DOE Patents (OSTI)

Ionic liquids having improved properties for application in non-aqueous batteries, electrochemical capacitors, electroplating, catalysis and chemical separations are disclosed. Exemplary compounds have one of the following formulas shown in a diagram wherein R{sub 1}, R{sub 2}, R{sub 3}, R{sub 4}, R{sub 5}, and R{sub 6} are either H; F; separate alkyl groups of from 1 to 4 carbon atoms, respectively, or joined together to constitute a unitary alkylene radical of from 2 to 4 carbon atoms forming a ring structure converging on N; or separate phenyl groups; and wherein the alkyl groups, alkylene radicals or phenyl groups may be substituted with electron withdrawing groups, preferably F-, Cl-, CF{sub 3}-, SF{sub 5}-, CF{sub 3}S-, (CF{sub 3}){sub 2}CHS- or (CF{sub 3}){sub 3}CS-; and X{sup {minus}} is a non-Lewis acid-containing polyatomic anion having a van der Waals volume exceeding 100 {angstrom}{sup 3}. 4 figs.

Koch, V.R.; Nanjundiah, C.; Carlin, R.T.

1998-10-27T23:59:59.000Z

165

Hydrophobic ionic liquids  

DOE Patents (OSTI)

Ionic liquids having improved properties for application in non-aqueous batteries, electrochemical capacitors, electroplating, catalysis and chemical separations are disclosed. Exemplary compounds have one of the following formulas: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are either H; F; separate alkyl groups of from 1 to 4 carbon atoms, respectively, or joined together to constitute a unitary alkylene radical of from 2 to 4 carbon atoms forming a ring structure converging on N; or separate phenyl groups; and wherein the alkyl groups, alkylene radicals or phenyl groups may be substituted with electron withdrawing groups, preferably F--, Cl--, CF.sub.3 --, SF.sub.5 --, CF.sub.3 S--, (CF.sub.3).sub.2 CHS-- or (CF.sub.3).sub.3 CS--; and X.sup.- is a non-Lewis acid-containing polyatomic anion having a van der Waals volume exceeding 100 .ANG..sup.3.

Koch, Victor R. (Lincoln, MA); Nanjundiah, Chenniah (Lynn, MA); Carlin, Richard T. (Nashua, NH)

1998-01-01T23:59:59.000Z

166

Research on Thermal Properties in a Phase Change Wallboard Room Based on Air Conditioning Cold Storage  

E-Print Network (OSTI)

After comparing the thermal performance parameters of an ordinary wall room to a phase change wall (PCW) room, we learn that phase change wallboard affects the fluctuation of temperature in air-conditioning room in the summer. We built a PCW room and an ordinary wall room, which are cooled by an air-conditioner. We used differential scanning calorimetry (DSC) to test the temperature field and heat flow fluctuation in these rooms. Through analyzing the data tested, we found that the mean temperature of PCW is lower than that of ordinary wall room by 1 to 2?, and PCW can lower the heat flow by 4.6W/m2. Combining phase change material with the building envelope can lower the indoor temperature, make the room thermally comfortable, and cut down the turn-on-and-off frequency of the air-conditioner and the primary investment and operating costs. It alleviates the urgent need for electricity.

Feng, G.; Li, W.; Chen, X.

2006-01-01T23:59:59.000Z

167

Media Room | National Nuclear Security Administration  

NLE Websites -- All DOE Office Websites (Extended Search)

Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog The National Nuclear Security Administration Media Room Home > Media Room Media Room NNSA's Office of...

168

Carbon Dioxide Separation with Supported Ionic Liquid Membranes  

SciTech Connect

A practical form of CO2 capture at water-gas shift conditions in the IGCC process could serve the dual function of producing a pure CO2 stream for sequestration and forcing the equilibrium-limited shift reaction to completion enriching the stream in H2. The shift temperatures, ranging from the low temperature shift condition of 260°C to the gasification condition of 900°C, limit capture options by diminishing associative interactions which favor removal of CO2 from the gas stream. Certain sorption interactions, such as carbonate formation, remain available but generally involve exceptionally high sorbent regeneration energies that contribute heavily to parasitic power losses. Carbon dioxide selective membranes need only establish an equilibrium between the gas phase and sorption states in order to transport CO2, giving them a potential energetic advantage over other technologies. Supported liquid membranes take advantage of high, liquid phase diffusivities and a solution diffusion mechanism similar to that observed in polymeric membranes to achieve superior permeabilities and selectivites. The primary shortcoming of the supported liquid membranes demonstrated in past research has been the lack of stability caused by volatilization of the transport liquid. Ionic liquids, which possess high CO2 solubility relative to light gases such as H2, are excellent candidates for this type of membrane since they have negligible vapor pressure and are not susceptible to evaporation. A study has been conducted evaluating the use of ionic liquids including 1-hexyl-3-methyl-imidazolium bis(trifuoromethylsulfonyl)imide in supported ionic liquid membranes for the capture of CO2 from streams containing H2. In a joint project, researchers at the University of Notre Dame synthesized and characterized ionic liquids, and researchers at the National Energy Technology Laboratory incorporated candidate ionic liquids into supports and evaluated the resulting materials for membrane performance. Improvements to the ionic liquid and support have allowed testing of these supported ionic liquid membranes at temperatures up to 300°C without loss of support mechanical stability or degradation of the ionic liquid. Substantial improvements in selectivity have also been observed at elevated temperature with the best membrane currently achieving optimum performance at 75°C.

Luebke, D.R.; Ilconich, J.B.; Pennline, H.W.; Myers, C.R.

2007-05-01T23:59:59.000Z

169

Ionic Liquid and Supercritical Fluid Hyphenated Techniques for Dissolution and Separation of Lanthanides, Actinides, and Fission Products  

SciTech Connect

This project is investigating techniques involving ionic liquids (IL) and supercritical (SC) fluids for dissolution and separation of lanthanides, actinides, and fission products. The research project consists of the following tasks: Study direct dissolution of lanthanide oxides, uranium dioxide and other actinide oxides in [bmin][Tf{sub 2}N] with TBP(HNO{sub 3}){sub 1.8}(H{sub 2}O){sub 0.6} and similar types of Lewis acid-Lewis base complexing agents; Measure distributions of dissolved metal species between the IL and the sc-CO{sub 2} phases under various temperature and pressure conditions; Investigate the chemistry of the dissolved metal species in both IL and sc-CO{sub 2} phases using spectroscopic and chemical methods; Evaluate potential applications of the new extraction techniques for nuclear waste management and for other projects. Supercritical carbon dioxide (sc-CO{sub 2}) and ionic liquids are considered green solvents for chemical reactions and separations. Above the critical point, CO{sub 2} has both gas- and liquid-like properties, making it capable of penetrating small pores of solids and dissolving organic compounds in the solid matrix. One application of sc-CO{sub 2} extraction technology is nuclear waste management. Ionic liquids are low-melting salts composed of an organic cation and an anion of various forms, with unique properties making them attractive replacements for the volatile organic solvents traditionally used in liquid-liquid extraction processes. One type of room temperature ionic liquid (RTIL) based on the 1-alkyl-3-methylimidazolium cation [bmin] with bis(trifluoromethylsulfonyl)imide anion [Tf{sub 2}N] is of particular interest for extraction of metal ions due to its water stability, relative low viscosity, high conductivity, and good electrochemical and thermal stability. Recent studies indicate that a coupled IL sc-CO{sub 2} extraction system can effectively transfer trivalent lanthanide and uranyl ions from nitric acid solutions. Advantages of this technique include operation at ambient temperature and pressure, selective extraction due to tunable sc-CO{sub 2} solvation strength, no IL loss during back-extraction, and no organic solvent introduced into the IL phase.

Wai, Chien M. [Univ. of Idaho, Moscow, ID (United States); Bruce Mincher

2012-12-01T23:59:59.000Z

170

Computational Studies on Oxygen-ionic Conduction in Rare-earth ...  

Science Conference Proceedings (OSTI)

Development of oxygen-ionic conductors which have low activation energies in ... for reducing the lower limit of operating temperatures of solid oxide fuel cells. ... electronic densities of states, oxygen migration paths and activation energies in ...

171

Physical Chemistry of Ionic Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

Ionic liquids are experiencing explosive growth in many areas of research Ionic liquids are experiencing explosive growth in many areas of research and practical applications. They present a wide range of complex physical and chemical behaviors, including ambient vapor pressures ranging from UHV to weakly volatile, a substantial variety of distinct condensed phases, including multiple crystal isomorphs, glasses, amorphous plastic and liquid crystal phases, deep supercooling, and interesting dynamical and transport phenomena. Experiments and simulations have shown that their intrinsic self-organization at the nanoscale is responsible for several of these properties. The symposium will assemble an international array of speakers to discuss ionic liquids in the context of their heterogeneous environments, solvation, dynamics and transport, interfacial properties,

172

SRNL - News Room  

NLE Websites -- All DOE Office Websites (Extended Search)

Coveted R&D 100 Award Coveted R&D 100 Award ( PDF button Download printer-friendly, PDF version) SRNL Wins Coveted R&D 100 Award AIKEN, S.C. (Sept. 12, 2006) - Researchers at the Savannah River National Laboratory, along with team members from the Massachusetts Institute of Technology (MIT) and the Pacific Northwest National Laboratory, have been named winners of an R&D 100 Award for their invention, the MilliWave Thermal Analyzer. The R&D 100 awards, considered the "Oscars of research and development," are presented each year by R&D magazine to the 100 most technologically significant inventions of the year. The MilliWave Thermal Analyzer, developed by SRNL's Gene Daniel and Don Miller and their colleagues, uses millimeter-wave electromagnetic radiation for non-contact, real-time measurements of temperature, amount of energy emitted, and physical changes of materials under extreme temperatures or corrosive environments.

173

Physical Chemistry of Ionic Liquids Symposium Schedule  

NLE Websites -- All DOE Office Websites (Extended Search)

(Tentative Schedule, locations and times to be determined) (Tentative Schedule, locations and times to be determined) Sunday Morning Structure and Heterogeneity of Ionic Liquids I. James Wishart and Edward Castner Introductory Remarks Andre Pinkert Hydroxyamine ionic liquids and their properties Thomas Strassner TAAILs - Tunable Aryl-Alkyl Ionic Liquids: A new generation of ionic liquids Laura Sprunger Grubbs Thermodynamic Properties of New Generation Ionic Liquids Christopher Hardacre Prediction methods for physical properties of ionic liquids BREAK Patricia Hunt What happens when you functionalise an ionic liquid with a "silicone" side chain? Edward L Quitevis Effect of cation symmetry and nanoscale segregation on the morphology, physical properties, and low-frequency vibrational dynamics of 1,3-dialkylimidazolium cation ionic liquids

174

Fractionation and Removal of Solutes from Ionic Liquids ...  

Recovers biomass solids from ionic liquids without formation of gel phase intermediates; Tested on several ionic liquids; Applications and Industries.

175

Humidity-resistant ambient-temperature solid-electrolyte amperometric sensing apparatus  

DOE Patents (OSTI)

Apparatus and methods for detecting selected chemical compounds in air or other gas streams at room or ambient temperature includes a liquid-free humidity-resistant amperometric sensor comprising a sensing electrode and a counter and reference electrode separated by a solid electrolyte. The sensing electrode preferably contains a noble metal, such as Pt black. The electrolyte is water-free, non-hygroscopic, and substantially water-insoluble, and has a room temperature ionic conductivity [>=]10[sup [minus]4] (ohm-cm)[sup [minus]1], and preferably [>=]0.01 (ohm-cm)[sup [minus]1]. The conductivity may be due predominantly to Ag[sup +] ions, as in Ag[sub 2]WO[sub 4], or to F[sup [minus

Zaromb, S.

1994-06-21T23:59:59.000Z

176

Carbon Dioxide Separation with Supported Ionic Liquid Membranes  

DOE Green Energy (OSTI)

Supported liquid membranes are a class of materials that allow the researcher to utilize the wealth of knowledge available on liquid properties as a direct guide in the development of a capture technology. These membranes also have the advantage of liquid phase diffusivities higher than those observed in polymeric membranes which grant proportionally greater permeabilities. The primary shortcoming of the supported liquid membranes demonstrated in past research has been the lack of stability caused by volatilization of the transport liquid. Ionic liquids, which possess high carbon dioxide solubility relative to light gases such as hydrogen, are an excellent candidate for this type of membrane since they have negligible vapor pressure and are not susceptible to evaporation. A study has been conducted evaluating the use of several ionic liquids, including 1-hexyl-3-methyl-imidazolium bis(trifuoromethylsulfonyl)imide, 1-butyl-3-methyl-imidazolium nitrate, and 1-ethyl-3-methyl-imidazolium sulfate in supported ionic liquid membranes for the capture of carbon dioxide from streams containing hydrogen. In a joint project, researchers at the University of Notre Dame lent expertise in ionic liquid synthesis and characterization, and researchers at the National Energy Technology Laboratory incorporated candidate ionic liquids into supports and evaluated the resulting materials for membrane performance. Initial results have been very promising with carbon dioxide permeabilities as high as 950 barrers and significant improvements in carbon dioxide/hydrogen selectivity over conventional polymers at 37C and at elevated temperatures. Results include a comparison of the performance of several ionic liquids and a number of supports as well as a discussion of innovative fabrication techniques currently under development.

Luebke, D.R.; Ilconich, J.B.; Myers, C.R.; Pennline, H.W.

2007-04-01T23:59:59.000Z

177

Hypercomputation in the Chinese Room  

Science Conference Proceedings (OSTI)

I rehearse a number of objections to John Searle's famous Chinese room argument. One is the 'hypercomputational objection' (Copeland 2002a). Hypercomputation is the computation of functions that cannot be computed in the sense of Turing (1936); the term ...

B. Jack Copeland

2002-10-01T23:59:59.000Z

178

Nuclear reactor control room construction  

DOE Patents (OSTI)

A control room for a nuclear plant is disclosed. In the control room, objects labelled 12, 20, 22, 26, 30 in the drawing are no less than four inches from walls labelled 10.2. A ceiling contains cooling fins that extend downwards toward the floor from metal plates. A concrete slab is poured over the plates. Studs are welded to the plates and are encased in the concrete. 6 figures.

Lamuro, R.C.; Orr, R.

1993-11-16T23:59:59.000Z

179

Ionic Power Systems Ltd | Open Energy Information  

Open Energy Info (EERE)

Ionic Power Systems Ltd Ionic Power Systems Ltd Jump to: navigation, search Name Ionic Power Systems Ltd. Place San Diego, California Zip 92126 Product Ionix Power Systems, Ltd. is a developer of new and innovative products and tools designed to aid in the development of next-generation energy technologies such as batteries, fuel cells, and advanced capacitors. References Ionic Power Systems Ltd.[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Ionic Power Systems Ltd. is a company located in San Diego, California . References ↑ "Ionic Power Systems Ltd." Retrieved from "http://en.openei.org/w/index.php?title=Ionic_Power_Systems_Ltd&oldid=347099" Categories:

180

Enhanced ionic conductivity in oxide heterostructures  

SciTech Connect

Fuel cells are electrochemical devices used to generate energy out of hydrogen. In a fuel cell, two conducting electrodes are separated by an electrolyte that is permeable to ions (either hydrogen or oxygen, depending on the fuel-cell category) but not to electrons. An electrode catalytic process yields the ionic species, which are transported through the electrolyte, while electrons blocked by the electrolyte pass through the external circuit. Polymeric membrane (PEMFC) or phosphoric acid fuel cells (PAFC) operating at low temperatures are the preferred option for transportation because of their quite large efficiencies (50%), compared with gasoline combustion engines (25%). Other uses are also being considered, such as battery replacements for personal electronics and stationary or portable emergency power. Solid-oxide fuel cells (SOFCs), operating at high temperatures, are a better option for stationary power generation because of their scalability. Here O{sup 2-} ions are the mobile species that travel at elevated temperatures (800-1000 C) through a solid electrolyte material to react with H{sup +} ions in the anode to produce water (Fig. 1). The high operating temperatures of solid oxide fuel cells are a major impediment to their widespread use in power generation. Thus, reducing this operating temperature is currently a major materials research goal, involving the search for novel electrolytes as well as active catalysts for electrode kinetics (oxygen reduction and hydrogen oxidation). Among oxide-ion conductors, those of anion-deficient fluorite structures such as yttria-stabilized zirconia (YSZ), xY{sub 2}O{sub 3}:(1-x) ZrO{sub 2}, are extensively used as electrolytes in SOFCs. Doping with Y{sub 2}O{sub 3} is known to stabilize the cubic fluorite structure of ZrO{sub 2} and to supply the oxygen vacancies responsible for the ionic conduction. These materials are characterized by a large number of mobile oxygen vacancies, which are randomly distributed in the structure, and thus give rise to a completely disordered anion (oxygen) sublattice. Traditionally, the main strategy to reduce the operating temperature has been to search for novel electrolyte materials with larger oxide-ion conductivity values. Only recently has the use of artificial nanostructures appeared as a promising new direction for dramatically improved properties.

Garcia-Barriocanal, Javier [Universidad Complutense, Spain; Rivera-Calzada, Alberto [Universidad Complutense, Spain; Varela del Arco, Maria [ORNL; Sefrioui, Z. [Universidad Complutense, Spain; Iborra, Enrique [Universidad Politecnica de Madrid, Spain; Leon, C. [Universidad Complutense, Spain; Pennycook, Stephen J [ORNL; Santamaria, J. [Universidad Complutense, Spain

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Lithium-sulfur batteries based on nitrogen-doped carbon and ionic liquid electrolyte  

Science Conference Proceedings (OSTI)

Nitrogen-doped mesoporous carbon (NC) and sulfur were used to prepare an NC/S composite cathode, which was evaluated in an ionic liquid electrolyte of 0.5 M lithium bis(trifluoromethane sulfonyl)imide (LiTFSI) in methylpropylpyrrolidinium bis(trifluoromethane sulfonyl)imide (MPPY.TFSI) by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and cycle testing. To facilitate the comparison, a C/S composite based on activated carbon (AC) without nitrogen doping was also fabricated under the same conditions as those for the NC/S composite. Compared with the AC/S composite, the NC/S composite showed enhanced activity toward sulfur reduction, as evidenced by the early onset sulfur reduction potential, higher redox current density in the CV test, and faster charge transfer kinetics as indicated by EIS measurement. At room temperature under a current density of 84 mA g-1 (C/20), the battery based on the NC/S composite exhibited higher discharge potential and an initial capacity of 1420 mAh g-1 whereas that based on the AC/S composite showed lower discharge potential and an initial capacity of 1120 mAh g-1. Both batteries showed similar capacity fading with cycling due to the intrinsic polysulfide solubility and the polysulfide shuttle mechanism; the capacity fading can be improved by further modification of the cathode.

Sun, Xiao-Guang [ORNL; Wang, Xiqing [ORNL; Mayes, Richard T [ORNL; Dai, Sheng [ORNL

2012-01-01T23:59:59.000Z

182

Reduction of Metal Oxide to Metal using Ionic Liquids  

Science Conference Proceedings (OSTI)

A novel pathway for the high efficiency production of metal from metal oxide means of electrolysis in ionic liquids at low temperature was investigated. The main emphasis was to eliminate the use of carbon and high temperature application in the reduction of metal oxides to metals. The emphasis of this research was to produce metals such as Zn, and Pb that are normally produced by the application of very high temperatures. The reduction of zinc oxide to zinc and lead oxide to lead were investigated. This study involved three steps in accomplishing the final goal of reduction of metal oxide to metal using ionic liquids: 1) Dissolution of metal oxide in an ionic liquid, 2) Determination of reduction potential using cyclic voltammetry (CV) and 3) Reduction of the dissolved metal oxide. Ionic liquids provide additional advantage by offering a wide potential range for the deposition. In each and every step of the process, more than one process variable has been examined. Experimental results for electrochemical extraction of Zn from ZnO and Pb from PbO using eutectic mixtures of Urea ((NH2)2CO) and Choline chloride (HOC2H4N(CH3)3+Cl-) or (ChCl) in a molar ratio 2:1, varying voltage and temperatures were carried out. Fourier Transform Infra-Red (FTIR) spectroscopy studies of ionic liquids with and without metal oxide additions were conducted. FTIR and induction coupled plasma spectroscopy (ICPS) was used in the characterization of the metal oxide dissolved ionic liquid. Electrochemical experiments were conducted using EG&G potentiostat/galvanostat with three electrode cell systems. Cyclic voltammetry was used in the determination of reduction potentials for the deposition of metals. Chronoamperometric experiments were carried out in the potential range of -0.6V to -1.9V for lead and -1.4V to -1.9V for zinc. The deposits were characterized using XRD and SEM-EDS for phase, morphological and elemental analysis. The results showed that pure metal was deposited on the cathode. Successful extraction of metal from metal oxide dissolved in Urea/ChCl (2:1) was accomplished. The current efficiencies were relatively high in both the metal deposition processes with current efficiency greater than 86% for lead and 95% for zinc. This technology will advance the metal oxide reduction process by increasing the process efficiency and also eliminate the production of CO2 which makes this an environmentally benign technology for metal extraction.

Dr. Ramana Reddy

2012-04-12T23:59:59.000Z

183

The Effect of Orientation, Temperature and Gamma Prime Size on ...  

Science Conference Proceedings (OSTI)

along the to Oil> boundry of the standard stereographic triangle ..... strength results between room temperature and the peak temperature since.

184

Reading Room | Department of Energy  

NLE Websites -- All DOE Office Websites (Extended Search)

Freedom of Information Act » Reading Freedom of Information Act » Reading Room Reading Room Welcome to the Freedom of Information Act (FOIA) Electronic Reading Room for the Department of Energy at Headquarters. The FOIA requires certain kinds of documents to be made available to the public for inspection and copying. This is a requirement for agencies of the executive branch of the federal government. The documents that are required to be made available by the FOIA are: Final Opinions [5 USC 552 (a)(2)](A) final opinions, including concurring and dissenting opinions, as well as orders, made in the adjudication of cases. Office of Hearings and Appeal - FOIA Appeals Initial agency determinations in response to FOIA and Privacy Act requests may be appealed to the Office of Hearings and Appeals (OHA). Decisions of

185

Reading Room | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Reading Reading Room Reading Room Welcome to the Freedom of Information Act (FOIA) Electronic Reading Room for the Department of Energy at Headquarters. The FOIA requires certain kinds of documents to be made available to the public for inspection and copying. This is a requirement for agencies of the executive branch of the federal government. The documents that are required to be made available by the FOIA are: Final Opinions [5 USC 552 (a)(2)](A) final opinions, including concurring and dissenting opinions, as well as orders, made in the adjudication of cases. Office of Hearings and Appeal - FOIA Appeals Initial agency determinations in response to FOIA and Privacy Act requests may be appealed to the Office of Hearings and Appeals (OHA). Decisions of the OHA constitute the agency's final determinations on requests made under

186

Ultrafast Dynamics of Pyrrolidinium Ionic Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

Ultrafast Dynamics of Pyrrolidinium Cation Ionic Liquids Hideaki Shirota, Alison M. Funston, James F. Wishart, Edward W. Castner, Jr. J. Chem. Phys. 122, 184512 (2005). Find paper...

187

ADSORPTION SEPARATION PROCESSES FOR IONIC LIQUID CATALYTIC ...  

Presently disclosed are methods and apparatus for separation of reaction products from reaction mixtures in an ionic liquid catalysis process, particularly in ...

188

Ultrastable Superbase-derived Protic Ionic Liquids  

pot reactor) CHEMICALS Ultrastable Superbase-derived Protic Ionic Liquids ORNL-2213 Contact: Greg Flickinger Oak Ridge National Laboratory P.O. Box ...

189

Radiation Chemistry and Photochemistry of Ionic Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

the nuclear fuel cycle. Therefore, an understanding of the interactions of ionizing radiation and photons with ionic liquids is strongly needed. However, the radiation chemistry...

190

SLAC National Accelerator Laboratory - Meeting Rooms  

NLE Websites -- All DOE Office Websites (Extended Search)

41 144D 3117 30-C Blue Room (20) 41 207 2868 30-C Castle Craigs Conference Room 280B 241 2804 29-D Cedar Room (15) 48 101 3485 30-B CEF Conference Room 35 4A 3534 27-E Controls...

191

Carbon Ionic Conductors for use in Novel Carbon-Ion Fuel Cells  

DOE Green Energy (OSTI)

Carbon-consuming fuel cells have many potential advantages, including increased efficiency and reduced pollution in power generation from coal. A large amount of work has already been done on coal fuel cells that utilize yttria-stabilized zirconium carbide as an oxygen-ion superionic membrane material. But high-temperature fuel cells utilizing yttria-stabilized zirconium require partial combustion of coal to carbon monoxide before final oxidation to carbon dioxide occurs via utilization of the oxygen- ion zirconia membrane. A carbon-ion superionic membrane material would enable an entirely new class of carbon fuel cell to be developed, one that would use coal directly as the fuel source, without any intervening combustion process. However, a superionic membrane material for carbon ions has not yet been found. Because no partial combustion of coal would be required, a carbon-ion superionic conductor would allow the direct conversion of coal to electricity and pure CO{sub 2} without the formation of gaseous pollutants. The objective of this research was to investigate ionic lanthanide carbides, which have an unusually high carbon-bond ionicity as potential superionic carbide-ion conductors. A first step in this process is the stabilization of these carbides in the cubic structure, and this stabilization has been achieved via the preparation of pseudobinary lanthanide carbides. The diffusion rates of carbon have been measured in these carbides as stabilized to preserve the high temperature cubic structure down to room temperature. To prepare these new compounds and measure these diffusion rates, a novel, oxide-based preparation method and a new C{sup 13}/C{sup 12} diffusion technique have been developed. The carbon diffusion rates in La{sup 0.5}Er{sup 0.5}C{sub 2}, Ce{sup 0.5}Er{sup 0.5}C{sub 2}, and La{sup 0.5}Y{sup 0.5}C{sub 2}, and Ce{sup 0.5}Tm0.5C{sub 2} modified by the addition of 5 wt %Be{sub 2}C, have been determined at temperatures from 850 C to 1150 C. The resulting diffusion constants as measured were all less than 10{sup -11} cm{sup 2}/sec, and therefore these compounds are not superionic. However, there remain a large number of potentially superionic pseudobinary lanthanide compounds and a number of alternate ionic carbides which might act as dopants to produce vacancies on the carbon-ion sublattice and thereby increase carbon-ion diffusion rates. The discovery of a superionic carbon conductor would usher in a truly revolutionary new coal technology, and could dramatically improve the way in which we generate electricity from coal. The work completed to date is a promising first step towards this end.

Franklin H. Cocks; W. Neal Simmons; Paul A. Klenk

2005-11-01T23:59:59.000Z

192

Free energy of ionic hydration  

SciTech Connect

The hydration free energies of ions exhibit an approximately quadratic dependence on the ionic charge, as predicted by the Born model. We analyze this behavior using second-order perturbation theory. The average and the fluctuation of the electrostatic potential at charge sites appear as the first coefficients in a Taylor expansion of the free energy of charging. Combining the data from different charge states (e.g., charged and uncharged) allows calculation of free-energy profiles as a function of the ionic charge. The first two Taylor coefficients of the free-energy profiles can be computed accurately from equilibrium simulations, but they are affected by a strong system-size dependence. We apply corrections for these finite-size effects by using Ewald lattice summation and adding the self-interactions consistently. An analogous procedure is used for the reaction-field electrostatics. Results are presented for a model ion with methane-like Lennard-Jones parameters in simple point charge water. We find two very closely quadratic regimes with different parameters for positive and negative ions. We also studied the hydration free energy of potassium, calcium, fluoride, chloride, and bromide ions. We find negative ions to be solvated more strongly (as measured by hydration free energies) compared to positive ions of equal size, in agreement with experimental data. 56 refs., 6 figs., 8 tabs.

Hummer, G.; Pratt, L.R.; Garcia, A.E. [Los Alamos National Lab., NM (United States)

1996-01-25T23:59:59.000Z

193

High-temperature Material Systems for Energy Conversion and ...  

Science Conference Proceedings (OSTI)

Ionic Solid Oxides for High Temperature Optical Gas Sensing in Fossil Fuel Based Power Plants · Mitigation of Chromium Poisoning in Solid Oxide Fuel Cell

194

DOE Solar Decathlon: Press Room  

NLE Websites -- All DOE Office Websites (Extended Search)

Press Room Press Room The U.S. Department of Energy Solar Decathlon is an award-winning program that challenges collegiate teams to design, build, and operate solar-powered houses that are cost-effective, energy-efficient, and attractive. The winner of the competition is the team that best blends affordability, consumer appeal, and design excellence with optimal energy production and maximum efficiency. The first Solar Decathlon was held in 2002; the competition has since occurred every two years in 2005, 2007, 2009, and 2011. The last event was held at the National Mall's West Potomac Park in Washington, D.C., Sept. 23-Oct. 2, 2011. Solar Decathlon 2013 takes place Oct. 3-13, 2013, at Orange County Great Park in Irvine, California. Open to the public free of charge, the Solar Decathlon gives visitors the

195

News Room | Argonne National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

News Room News Room In a 3D structure of the protein, the binding site is shown in pink, representing a potential drug target. The green molecule shows binding of an antibiotic to the protein. Click to enlarge. Image courtesy of Wladek Minor. Newly ID'd protein provides target for antibiotic-resistant hospital bacterium Full Story » Researchers have made inroads into tackling a bacterium that plagues hospitals and is highly resistant to most antibiotics. Andrey Elagin (left), postdoctoral scholar at the Enrico Fermi Institute at the University of Chicago, and Matthew Wetstein, the Grainger Postdoctoral Fellow at the Enrico Fermi Institute at the University of Chicago, adjust the optics in the Large Area Picosecond Photodetector testing facility. The facility uses extremely short laser pulses to precisely measure the time resolution of the photodetectors. Click to enlarge.

196

Forecasting Uncertain Hotel Room Demand  

E-Print Network (OSTI)

Economic systems are characterized by increasing uncertainty in their dynamics. This increasing uncertainty is likely to incur bad decisions that can be costly in financial terms. This makes forecasting of uncertain economic variables an instrumental activity in any organization. This paper takes the hotel industry as a practical application of forecasting using the Holt-Winters method. The problem here is to forecast the uncertain demand for rooms at a hotel for each arrival day. Forecasting is part of hotel revenue management system whose objective is to maximize the revenue by making decisions regarding when to make rooms available for customers and at what price. The forecast approach discussed in this paper is based on quantitative models and does not incorporate management expertise. Even though, forecast results are found to be satisfactory for certain days, this is not the case for other arrival days. It is believed that human judgment is important when dealing with ...

Mihir Rajopadhye Mounir; Mounir Ben Ghaliay; Paul P. Wang; Timothy Baker; Craig V. Eister

2001-01-01T23:59:59.000Z

197

NETL: NewsRoom - Multimedia  

NLE Websites -- All DOE Office Websites (Extended Search)

NewsRoom NewsRoom Multimedia Now you can download videos to your computer by right clicking the "download" link and selecting the "Save target as" option. It is suggested that mac users use this link. Carbon Cycle Animation Carbon Cycle Animation - 2012 Animation that depicts the carbon cycle as it relates to nature, land use, and energy production. Movie Icon Windows Media Video (WMV-5.7MB) [ view | download ] Earth Day Animation Earth Day Animation - 2011 A compilation of three Earth Day animations that demonstrate being green around your home, office, and community Movie Icon Windows Media Video (WMV-16MB) [ view | download ] Interview with Anthony Cugini Interview with Anthony Cugini - 2011 Interview at the International Pittsburgh Coal Conference with Dr. Cugini regarding Carbon Capture Utilization and Storage technologies.

198

Model of gypsum, calcite and silica solubilities for application to geothermal waters over a wide range of temperature, P/sub CO/sub 2// and ionic strength. Final technical report, October 1, 1983-September 30, 1984  

DOE Green Energy (OSTI)

This report describes the construction of a high temperature (25 to 250/sup 0/C), variable P/sub CO/sub 2// (1 to 40 atm), chemical model of mineral (including gypsum, calcite and amorphous silica) solubilities in the system: Na-K-Ca-H-Cl-SO/sub 4/-HCO/sub 3/-CO/sub 3/-CO/sub 2/-SiO/sub 2/-H/sub 2/O. This model was designed to support geothermal energy production needs.

Not Available

1984-01-01T23:59:59.000Z

199

New Ionic Liquids with Diverse Properties - Energy Innovation ...  

Hundreds of new ionic liquids can be synthesized using a method invented by ORNL researchers. This innovation makes it possible to produce ionic liqui ...

200

Classified Reading Room Instructions/Guidelines  

NLE Websites -- All DOE Office Websites (Extended Search)

Classified Reading Room Instructions/Guidelines Classified Reading Room Instructions/Guidelines * Reading Room Points of Contact: Milesha Grier, (202) 586-8210, milesha.gier@nnsa.doe.gov Reading Room Location: DOE Forrestal Building, 1000 Independence Ave., Washington, D.C. Room 4A-045, 4 th Floor, "A" Corridor, Behind Glass Doors, dial 6-8210 Reading Room Availability: By Appointment - Reading Room will be available until RFP Closes except (12/5/11 thru 12/16/11, December 23, January 2, 2012 and January 16, 2012). Reading Room Hours: Morning, 9:00 a.m. - 11:30 a.m.; and Afternoon 1:00 p.m. - 3:30 p.m. Reading Room Will Accommodate: Up to 5-6 people * All personnel must: a. submit a formal Intent to Bid IAW Section L of the RFP, via email to: SEB1@doeal.gov

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201

Room Air Conditioners | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Room Air Conditioners Room Air Conditioners Room Air Conditioners July 1, 2012 - 5:35pm Addthis A window air conditioner is one solution to cooling part of a house. | Photo courtesy of ©iStockphoto/kschulze. A window air conditioner is one solution to cooling part of a house. | Photo courtesy of ©iStockphoto/kschulze. What does this mean for me? Room air conditioners are less expensive and disruptive to install than central air conditioning systems. Room air conditioners can be a cost-effective alternative to central air conditioning systems. How does it work? Room air conditioners work by cooling one part of your home. Room or window air conditioners cool rooms rather than the entire home or business. If they provide cooling only where they're needed, room air conditioners are less expensive to operate than central units, even though

202

Media Room | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

Media Room | National Nuclear Security Administration Media Room | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog The National Nuclear Security Administration Media Room Home > Media Room Media Room NNSA's Office of Congressional, Intergovernmental, and Public Affairs regularly updates the web site with current press releases, newsletters,

203

Ionic liquids for rechargeable lithium batteries  

SciTech Connect

We have investigated possible anticipated advantages of ionic-liquid electrolytes for use in lithium-ion batteries. Thermal stabilities and phase behavior were studied by thermal gravimetric analysis and differential scanning calorimetry. The ionic liquids studied include various imidazoliumTFSI systems, pyrrolidiniumTFSI, BMIMPF{sub 6}, BMIMBF{sub 4}, and BMIMTf. Thermal stabilities were measured for neat ionic liquids and for BMIMBF{sub 4}-LiBF{sub 4}, BMIMTf-LiTf, BMIMTFSI-LiTFSI mixtures. Conductivities have been measured for various ionic-liquid lithium-salt systems. We show the development of interfacial impedance in a Li|BMIMBF{sub 4} + LiBF{sub 4}|Li cell and we report results from cycling experiments for a Li|BMIMBF{sub 4} + 1 mol/kg LIBF{sub 4}|C cell. The interfacial resistance increases with time and the ionic liquid reacts with the lithium electrode. As expected, imidazolium-based ionic liquids react with lithium electrodes. We seek new ionic liquids that have better chemical stabilities.

Salminen, Justin; Papaiconomou, Nicolas; Kerr, John; Prausnitz,John; Newman, John

2005-09-29T23:59:59.000Z

204

Tuning the Physicochemical Properties of Diverse Phenolic Ionic Liquids for Equimolar CO2 Capture by the Substituent on the Anion  

SciTech Connect

Phenolic ionic liquids for the efficient and reversible capture of CO{sub 2} were designed and prepared from phosphonium hydroxide and substituted phenols. The electron-withdrawing or electron-donating ability, position, and number of the substituents on the anion of these ionic liquids were correlated with the physicochemical properties of the ionic liquids. The results show that the stability, viscosity, and CO{sub 2}-capturing ability of these ionic liquids were significantly affected by the substituents. Furthermore, the relationship between the decomposition temperature, the CO{sub 2}-absorption capacity, and the basicity of these ionic liquids was quantitatively correlated and further rationalized by theoretical calculation. Indeed, these ionic liquids showed good stability, high absorption capacity, and low absorption enthalpy for CO{sub 2} capture. This method, which tunes the physicochemical properties by making use of substituent effects in the anion of the ionic liquid, is important for the design of highly efficient and reversible methods for CO{sub 2}-capture. This CO{sub 2} capture process using diverse phenolic ionic liquids is a promising potential method for CO{sub 2} absorption with both high absorption capacity and good reversibility.

Dai, Sheng [ORNL; Luo, Huimin [ORNL; Yu, Bo [ORNL; Li, Haoran [Zhejiang University; Wang, Congmin [ORNL

2012-01-01T23:59:59.000Z

205

Energy Integration Visualization Room (Fact Sheet)  

SciTech Connect

This two-page fact sheet describes the new Energy Integration Visualization Room in the ESIF and talks about some of the capabilities and unique visualization features of the the room.

Not Available

2012-08-01T23:59:59.000Z

206

The room noise criteria (RNC) metric.  

Science Conference Proceedings (OSTI)

The recent ANSI S12.2:2008 room noise criteria contains both a survey and an engineering method to specify room noise criteria. The methods use A?weighting and extended NC

2009-01-01T23:59:59.000Z

207

FOIA Reading Room - privacy act  

NLE Websites -- All DOE Office Websites (Extended Search)

Reading Room - pricacy act Reading Room - pricacy act CH Frequently Requested Documents Under FOIA Administrative Electronic FOIA Form Privacy Act Advisory (Microsoft Word(tm) document) DOE-CH Government Purchase Card Cardholders: December 2012 CH Organizational Chart: Current Version Policies and Procedures - Office of Science (including Chicago Office) Office of Hearings and Appeals Decisions Department of Justice Cases and Legal Documents Department of Energy Directives DOE Office of Inspector General Reports Responses Under FOIA FY10 Management and Operating Contracts "FY2012 Laboratory Performance Report Cards" The following management and operating prime contracts under the jurisdiction of DOE-CH have been renewed and posted for your convenience. Modifications that change, delete, or add language to any portion of these contracts (referred to as "M" Mods) will be posted as expeditiously as possible after execution. It is at the discretion of the Contractors whether or not they include modifications that change the amount obligated by the Government. Ames Laboratory - Contract No. No.DE-AC02-07CH11358

208

Chapter 45 - SANS FROM IONIC MICELLES Ionic micelles ...  

Science Conference Proceedings (OSTI)

... ? is seen to decrease with temperature as tabulated (CRC Handbook, 1984). Page 8. 55 60 65 70 75 80 85 90 0 20 40 60 80 Published Data ...

2009-11-29T23:59:59.000Z

209

Ionic Liquids Based on Polynitrile Anions  

NLE Websites -- All DOE Office Websites (Extended Search)

W. Marin, and James F. Wishart J. Phys. Chem. B 117, 7084-7094 (2013). Find paper at ACS Publications or use ACS Articles on Request. Abstract: Ionic liquids (IL) are being...

210

Dynamics of Fast Reactions in Ionic Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

in "Ionic Liquids IIIA: Properties and Structure" Rogers, R. D. and Seddon, K. R., Eds.; ACS Symp. Ser. 901, Ch. 8, American Chemical Society, Washington, DC, 2005, pp. x-x., in...

211

Synthesis of ionic liquids - Energy Innovation Portal  

New Ionic Liquids with ... was made with United States Government support under Contract No. DE-AC05-960R 22725 between the United States Department of Energy and ...

212

Enzyme activity in dialkylphosphate ionic liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

Enzyme activity in dialkylphosphate ionic liquids Enzyme activity in dialkylphosphate ionic liquids M. F. Thomas, L. Li, J. Handley-Pendleton, D. van der Lelie, J. J. Dunn and J. F. Wishart Bioresource Technology 102, in press. [Find paper at Science Direct] Abstract: The activity of four metagenomic enzymes and an enzyme cloned from the straw mushroom, Volvariella volvacea were studied in the following ionic liquids, 1,3-dimethylimidazolium dimethyl phosphate, [mmim][dmp], 1-ethyl-3-methylimidazolium dimethyl phosphate, [emim][dmp], 1-ethyl-3-methylimidazolium diethyl phosphate, [emim][dep] and 1-ethyl-3-methylimidazolium acetate, [emim][OAc]. Activity was determined by analyzing the hydrolysis of para-nitrobenzene carbohydrate derivatives. In general, the enzymes were most active in the dimethyl phosphate ionic

213

Reading Room | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

Reading Room | National Nuclear Security Administration Reading Room | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog The National Nuclear Security Administration Reading Room Home > About Us > Our Operations > Acquisition and Project Management > Major Contract Solicitations > Environmental Program Services Contract > Reading Room

214

Carbon Dioxide Selective Supported Ionic Liquid Membranes: The Effect of Contaminants  

SciTech Connect

The integrated gasification combined cycle (IGCC) is widely viewed as a promising technology for the large scale production of energy in a carbon constrained world. These cycles, which include gasification, contaminant removal, water-gas shift, CO2 capture and compression, and combustion of the reduced-carbon fuel gas in a turbine, often have significant efficiency advantages over conventional combustion technologies. A CO2 selective membrane capable of maintaining performance at conditions approaching those of low temperature water-gas shift (260oC) could facilitate the production of carbon-neutral energy by simultaneously driving the shift reaction to completion and concentrating CO2 for sequestration. Supported ionic liquid membranes (SILMs) have been previously evaluated for this application and determined to be physically and chemically stable to temperatures in excess of 300oC. These membranes were based on ionic liquids which interacted physically with CO2 and diminished considerably in selectivity at higher temperatures. To alleviate this problem, the original ionic liquids were replaced with ionic liquids able to form chemical complexes with CO2. These complexing ionic liquid membranes have a local maximum in selectivity which is observed at increasing temperatures for more stable complexes. Efforts are currently underway to develop ionic liquids with selectivity maxima at temperatures greater than 75oC, the best result to date, but other practical concerns must also be addressed if the membrane is to be realistically expected to function under water-gas shift conditions. A CO2 selective membrane must function not only at high temperature, but also in the presence of all the reactants and contaminants likely to be present in coal-derived fuel gas, including water, CO, and H2S. A study has been undertaken which examines the effects of each of these gases on both complexing and physically interacting supported liquid membranes. In a joint project, researchers at the University of Notre Dame synthesized and characterized ionic liquids, and researchers at the National Energy Technology Laboratory incorporated candidate ionic liquids into supports and evaluated the resulting materials for membrane performance.

Luebke, D.R.; Ilconich, J.B.; Myers, C.R.; Pennline, H.W.

2008-04-01T23:59:59.000Z

215

Superbase-derived protic ionic liquids  

DOE Patents (OSTI)

Protic ionic liquids having a composition of formula (A.sup.-)(BH.sup.+) wherein A.sup.- is a conjugate base of an acid HA, and BH.sup.+ is a conjugate acid of a superbase B. In particular embodiments, BH.sup.+ is selected from phosphazenium species and guanidinium species encompassed, respectively, by the general formulas: ##STR00001## The invention is also directed to films and membranes containing these protic ionic liquids, with particular application as proton exchange membranes for fuel cells.

Dai, Sheng; Luo, Huimin; Baker, Gary A.

2013-09-03T23:59:59.000Z

216

Spray Cooling in Room Fires  

Science Conference Proceedings (OSTI)

... power of the volumetric median drop diameter* of the spray. ... The temperature, velocity and concentrations (CO, CO2, 02 and total hydro- ...

2008-12-05T23:59:59.000Z

217

Public Reading Room: Environmental Documents, Reports  

NLE Websites -- All DOE Office Websites (Extended Search)

Public Reading Room: Environmental Documents, Reports Public Reading Room: Environmental Documents, Reports Public Reading Room: Environmental Documents, Reports Environmental documents and reports are available online. Hard copies are available at the Laboratory's Public Reading Room in Pojoaque, New Mexico. Contact Environmental Communication & Public Involvement P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email Public Reading Room: Environmental Documents, Reports Online Annual Environmental Report Electronic Public Reading Room (EPRR) Plans, Procedures A listing of procedures available in the EPRR Hard copy Public Reading Room 94 Cities of Gold Road Pojoaque, NM Vie Screen reader users: click here for plain HTML Go to Google Maps Home 94 cities of gold Road, Pojoaque, NM Loading... Map Sat Ter Did you mean a different:

218

Numerical method for computing nonlinear, time dependent, buoyant circulation of air in rooms  

Science Conference Proceedings (OSTI)

A method is described which solves the dynamic equations for air circulation at Grashof numbers that are in the range of environmental temperatures of rooms. Previous two-dimensional computation techniques were limited to G ? 105 ...

J. E. Fromm

1971-05-01T23:59:59.000Z

219

NEPA Reading Room | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

Reading Room | National Nuclear Security Administration Reading Room | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog NEPA Reading Room Home > About Us > Our Operations > NNSA Office of General Counsel > National Environmental Policy Act (NEPA) > NEPA Reading Room NEPA Reading Room Welcome to the National Nuclear Security Administration's NEPA Reading

220

026- Room Temperature Properties of Electrical Contacts to Alumina ...  

Science Conference Proceedings (OSTI)

125- Influence of Gas Flow Rate Ratio on the Structural Properties of a-SiC:H Prepared by ... 145- The Synergy of XRD and XRF in a Shale and Slate Analysis.

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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221

HVAC Room Temperature Prediction Control Based on Neural Network Model  

Science Conference Proceedings (OSTI)

HVAC (Heating Ventilating &Air-conditioning) system is a nonlinear complex system with delay. It is very difficult to build a mathematical model of HVAC and implement model-based control. Since a BP (Back Propagation) neural network can fully approximate ... Keywords: BP neural network, predictive control, HVAC, least squares method

Shujiang Li, Shuang Ren, Xiangdong Wang

2013-01-01T23:59:59.000Z

222

Room Temperature Hydrogen Storage in Nano-Confined Liquids -...  

NLE Websites -- All DOE Office Websites (Extended Search)

measurements of * hydrogen solubility in volatile liquid solvents in both bulk form and nano-confined liquidscaffold composites. Demonstrate volumetric measurements of hydrogen *...

223

Numerical modelling and analysis of a room temperature magnetic  

E-Print Network (OSTI)

are separated by channels of a heat transfer fluid. The time-dependent model solves the momentum and continuity equations of the flow of the heat transfer fluid and the coupled energy equations of the heat transfer and it was concluded that the model has energy conservation and that the solution is independent of the chosen grid

224

Communications to the Editor Room-Temperature Desulfurization of  

E-Print Network (OSTI)

difficult to remove in the hydroprocessing of crude oil.3 In homogeneous models, orga- nometallic nickel of polynuclear complexes in the desulfurization of various thiophenes,6 led us to prepare a dinuclear nickel

Jones, William D.

225

FEATURE ARTICLE Room Temperature Ballistic Conduction in Carbon Nanotubes  

E-Print Network (OSTI)

of tens of microns. The measurements are performed both in air and in high vacuum in the transmission scattering can explain why the measured conductances are about half of the expected theoretical value of 2 G0) and anomalous I-V dependences result from impurities and surfactants on the tubes. Evidence is presented

Wang, Zhong L.

226

Structural, optical and transport properties of room temperature ...  

Science Conference Proceedings (OSTI)

Simplex Network Modeling for Press-Molded Ceramic Bodies Incorporated with Granite Waste · Solidification mechanisms of carbon as graphene, graphite and ...

227

Crystallite Size Study of Room-Temperature Tetragonal Zirconia ...  

Science Conference Proceedings (OSTI)

Biological Properties of Zinc Oxide-Coated Anodized Aluminum Oxide ... Zirconia Stabilisation Nano-Confined by Using Electroless Nickel Cladding .... Metal Oxide Nanofibers Produced by a ForceSpinning Method for Battery Electrodes.

228

Novel Fission-Product Separation Based on Room Temperature ...  

macrocyclic extractants and transport in new ... Future Research Plans 1. Synthesis and Optimization of ILs Tailored for Solvent Extraction of Fission ...

229

Method of Production of Pure Hydrogen Near Room Temperature ...  

Energy Storage ... The described method of hydrogen production is useful for energy conversion and production technologies that consume pure gaseous h ...

230

AB Electronic Tubes and Quasi-Superconductivity at Room Temperature  

E-Print Network (OSTI)

Author offers and researches a new idea - filling tubes by electronic gases. He shows: If the insulating envelope (cover) of the tube is charged positively, the electrons within the tube are not attracted to covering. Tube (as a whole) remains a neutral (uncharged) body. The electron gas in the tube has very low density and very high conductivity, close to superconductivity. If we take the density (pressure) of electron gas as equal to atmospheric pressure, the thickness of insulator film may be very small and the resulting tube is very light. Author shows the offered tubes can be applied to many technical fields. For example: (1) Transfer of energy over very long distance with very small electric losses. (2) Design of cheap high altitude electric lines without masts. (3) Transfer of energy from one continent to another continent through the ionosphere. (4) Transfer of a plasma beam (which can convey thrust and energy) from Earth surface to a space ship. (5) Observation of the sky by telescope without atmospheric hindrances. (6) Dirigibles (air balloons) of the highest lift force. (7) Increasing of gun range severalfold. (8) Transfer of matter. And so on. Key words: AB tubes, electronic tubes, superconductivity, transmission energy.

Alexander Bolonkin

2008-05-02T23:59:59.000Z

231

Evaluation of Station Post Porcelain Insulators with Room Temperature  

E-Print Network (OSTI)

. Industrial environment include sources of soluble pollution from steel mills, refineries or sources of inert research on challenges facing the electric power industry and educating the next generation of power&E for their assistance in this project. PSERC is a National Science Foundation Industry/University Cooperative Research

232

Ge-on-Si laser operating at room temperature  

E-Print Network (OSTI)

Monolithic lasers on Si are ideal for high-volume and large-scale electronic–photonic integration. Ge is an interesting candidate owing to its pseudodirect gap properties and compatibility with Si complementary metal oxide ...

Liu, Jifeng

233

Method of production of pure hydrogen near room temperature from ...  

The present invention provides a cost-effective method of producing pure hydrogen gas from hydride-based solid materials. The hydride-based solid material is ...

234

Aluminum Recycling Via Near Room Temperature Electrolysis In ...  

Science Conference Proceedings (OSTI)

Aug 1, 2000 ... At a cell voltage of 1 volt, the energy consumption of about 3 kWh/kg-Al was obtained. The process has advantages of low energy consumption ...

235

Recent Advances in Temperature Dependent Ionic Radii Using the ...  

Science Conference Proceedings (OSTI)

Energy Landscape in Frustrated Systems: Cation Hopping and Relaxation in Pyrochlores ... Lead-free Piezoelectric Films for Transducer Applications.

236

Plenary session Room F2 Chairman: Doc. J. Langer  

E-Print Network (OSTI)

. O Modeling of Bacterial Chemotaxis in Steady-state System 17:15 Poster Session Symposium Room M1., Glosik J. O State-selective Recombination of H3 + Ions with Electrons at Temperatures 50­300 K 14:55 f2 Referee: Prof. F. Marsik 13:30 f11 Netusil M. O Modeling of Arterial Wall ­ The Current State of Knowledge

237

Data for Room Fire Model Comparisons  

Science Conference Proceedings (OSTI)

... of the burn room; and, possibly, a load platform. ... by the use of the oxygen consumption principle ... be used to estimate the rate of energy production of ...

2004-10-05T23:59:59.000Z

238

NEPA Reading Room | National Nuclear Security Administration  

NLE Websites -- All DOE Office Websites (Extended Search)

NEPA Reading Room | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing...

239

NEPA Reading Room | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

Reading Room | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our...

240

The Live Room: transducing resonant architectures  

Science Conference Proceedings (OSTI)

The Live Room was a temporary site-specific installation presented in building N51, room 117 on the MIT campus on 7 May 1998 and concluded on 10 June 1998. Using small acoustic-intensifying equipment which mounted directly to the structure of ...

Mark Bain

2003-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

DOE-ID FOIA Reading Room  

NLE Websites -- All DOE Office Websites (Extended Search)

Reading Room Reading Room READING ROOM Eectronic Freedom of Information Act, E-FOIA RECORDS UNDER THE E-FOIA The Electronic Freedom of Information Act Amendments of 1996 addresses the issues and procedural aspects of FOIA administration. The amendment: defines the term "record" as including "any information that would be an agency record subject to the requirements of the FOIA when maintained by an agency in any format, including an electronic format; addresses the form or format in which a requested record is disclosed providing the record is readily reproducible by the agency in the requestor's desired form or format; directs Federal agencies to maintain both conventional reading rooms and electronic reading rooms to meet FOIA responsibilities.

242

Los Alamos test-room results  

DOE Green Energy (OSTI)

Fourteen Los Alamos test rooms have been operated for several years; this paper covers operation during the winters of 1980-81 and 1981-82. Extensive data have been taken and computer analyzed to determine performance parameters such as efficiency, solar savings fraction, and comfort index. The rooms are directly comparable because each has the same net coefficient and solar collection area and thus the same load collector ratio. Configurations include direct gain, unvented Trombe walls, water walls, phase change walls, and two sunspace geometries. Strategies for reducing heat loss include selective surfaces, two brands of superglazing windows, a heat pipe system, and convection-suppression baffles. Significant differences in both backup heat and comfort are observed among the various rooms. The results are useful, not only for direct room-to-room comparisons, but also to provide data for validation of computer simulation programs.

McFarland, R.D.; Balcomb, J.D.

1982-01-01T23:59:59.000Z

243

Design and Evaluation of Ionic Liquids as Novel Absorbents  

NLE Websites -- All DOE Office Websites (Extended Search)

- ionic liquids - for the capture of CO 2 from the flue gas from coal and natural gas-fired power plants. The success of ionic liquids technology will be based on...

244

Carbon Films Produced from Ionic Liquid Precursors - Energy ...  

Energy Storage Carbon Films Produced from Ionic Liquid Precursors Oak Ridge National Laboratory. Contact ORNL About This Technology Technology Marketing ...

245

Ionic electrostatic excitations along biological membranes  

Science Conference Proceedings (OSTI)

A theoretical analysis of ionic electrostatic excitations of a charged biological membrane is presented within the framework of the fluid theory for surface ions inside and outside the cell, in conjunction with the Poisson's equation. General expressions of dispersion relations are obtained for electrostatic oscillations of intrinsic cellular with different shapes and symmetries.

Moradi, Afshin [Department of Nano Science, Kermanshah University of Technology, Kermanshah 67178-63766 (Iran, Islamic Republic of) and Department of Nano Science, Institute for Studies in Theoretical Physics and Mathematics (IPM), Tehran 19395-5531 (Iran, Islamic Republic of)

2011-02-15T23:59:59.000Z

246

Sorption of organic gases in residential rooms  

NLE Websites -- All DOE Office Websites (Extended Search)

residential rooms residential rooms Title Sorption of organic gases in residential rooms Publication Type Journal Article LBNL Report Number LBNL-59303 Year of Publication 2007 Authors Singer, Brett C., Alfred T. Hodgson, Toshifumi Hotchi, Katherine Y. Ming, Richard G. Sextro, Emily E. Wood, and Nancy J. Brown Journal Atmospheric Environment Volume 41 Start Page Chapter Pagination 3251-3265 Keywords adsorption, hazardous air pollutants, nerve agents, sink effect, volatile organic compounds Abstract Experiments were conducted to characterize organic gas sorption in residential rooms studied ''as-is'' with furnishings and material surfaces unaltered and in a furnished chamber designed to simulate a residential room. Results are presented for 10 rooms (five bedrooms, two bathrooms, a home office, and two multi-function spaces) and the chamber. Exposed materials were characterized and areas quantified. A mixture of volatile organic compounds (VOCs) was rapidly volatilized within each room as it was closed and sealed for a 5-h Adsorb phase; this was followed by 30-min Flush and 2-h closed-room Desorb phases. Included were alkane, aromatic, and oxygenated VOCs representing a range of ambient and indoor air pollutants. Three organophosphorus compounds served as surrogates for Sarin-like nerve agents. Measured gas-phase concentrations were fit to three variations of a mathematical model that considers sorption occurring at a surface sink and potentially a second, embedded sink. The 3-parameter sink-diffusion model provided acceptable fits for most compounds and the 4-parameter two-sink model provided acceptable fits for the others. Initial adsorption rates and sorptive partitioning increased with decreasing vapor pressure for the alkanes, aromatics and oxygenated VOCs. Best-fit sorption parameters obtained from experimental data from the chamber produced best-fit sorption parameters similar to those obtained from the residential rooms

247

Structure, ionic Conductivity and mobile Carrier Density in Fast Ionic Conducting Chalcogenide Glasses  

SciTech Connect

This thesis consists of six sections. The first section gives the basic research background on the ionic conduction mechanism in glass, polarization in the glass, and the method of determining the mobile carrier density in glass. The proposed work is also included in this section. The second section is a paper that characterizes the structure of MI + M{sub 2}S + (0.1 Ga{sub 2}S{sub 3} + 0.9 GeS{sub 2}) (M = Li, Na, K and Cs) glasses using Raman and IR spectroscopy. Since the ionic radius plays an important role in determining the ionic conductivity in glasses, the glass forming range for the addition of different alkalis into the basic glass forming system 0.1 Ga{sub 2}S{sub 3} + 0.9 GeS{sub 2} was studied. The study found that the change of the alkali radius for the same nominal composition causes significant structure change to the glasses. The third section is a paper that investigates the ionic conductivity of MI + M{sub 2}S + (0.1Ga{sub 2}S{sub 3} + 0.9 GeS{sub 2}) (M = Li, Na, K and Cs) glasses system. Corresponding to the compositional changes in these fast ionic conducting glasses, the ionic conductivity shows changes due to the induced structural changes. The ionic radius effect on the ionic conductivity in these glasses was investigated. The fourth section is a paper that examines the mobile carrier density based upon the measurements of space charge polarization. For the first time, the charge carrier number density in fast ionic conducting chalcogenide glasses was determined. The experimental impedance data were fitted using equivalent circuits and the obtained parameters were used to determine the mobile carrier density. The influence of mobile carrier density and mobility on the ionic conductivity was separated. The fifth section is a paper that studies the structures of low-alkali-content Na{sub 2}S + B{sub 2}S{sub 3} (x {le} 0.2) glasses by neutron and synchrotron x-ray diffraction. Similar results were obtained both in neutron and synchrotron x-ray diffraction experiments. The results provide direct structural evidence that doping B{sub 2}S{sub 3} with Na{sub 2}S creates a large fraction of tetrahedrally coordinated boron in the glass. The final section is the general conclusion of this thesis and the suggested future work that could be conducted to expand upon this research.

Wenlong Yao

2006-12-12T23:59:59.000Z

248

Room Air Conditioners | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

you need to mount the air conditioner at the narrow end of a long room, then look for a fan control known as "Power Thrust" or "Super Thrust" that sends the cooled air farther...

249

Design of the CTX diagnostics screen room  

DOE Green Energy (OSTI)

The design of a shielded enclosure (or screen room) to house data acquisition equipment in an area in which substantial, time varying magnetic fields are present and capable of producing significant interference is described.

Chandler, G.I. II

1981-01-01T23:59:59.000Z

250

Ionic Liquids: Structure and Photochemical Reactions  

NLE Websites -- All DOE Office Websites (Extended Search)

Structure and Photochemical Reactions Structure and Photochemical Reactions E. W. Castner, Jr., C. J. Margulis, M. Maroncelli, and J. F. Wishart in "Annual Reviews of Physical Chemistry, Vol. 62"; Annual Reviews, Palo Alto, CA, (2011) pp. 85-105. [Find paper at Annual Reviews] Abstract: Ionic liquids are subjects of intense current interest within the physical chemistry community. A great deal of progress has been made in just the past five years toward identifying the factors that cause these salts to have low melting points and other useful properties. Supramolecular structure and organization have emerged as important and complicated topics that may be key to understanding how chemical reactions and other processes are affected by ionic liquids. New questions are posed, and an active

251

Software Support during a Control Room Upgrade  

SciTech Connect

In 2004, after 14 years of accelerator operations and commissioning, Jefferson Lab renovated its main control room. Changes in technology and lessons learned during those 14 years drove the control room redesign in a new direction, one that optimizes workflow and makes critical information and controls available to everyone in the control room. Fundamental changes in a variety of software applications were required to facilitate the new operating paradigm. A critical component of the new control room design is a large-format video wall that is used to make a variety of operating information available to everyone in the room. Analog devices such as oscilloscopes and function generators are now displayed on the video wall through two crosspoint switchers: one for analog signals and another for video signals. A new software GUI replaces manual configuration of the oscilloscopes and function generators and helps automate setup. Monitoring screens, customized for the video wall, now make important operating information visible to everyone, not just a single operator. New alarm handler software gives any operator, on any workstation, access to all alarm handler functionality, and multiple users can now contribute to a single electronic logbook entry. To further support the shift to distributed access and control, many applications have been redesigned to run on servers instead of on individual workstations.

Michele Joyce; Michael Spata; Thomas Oren; Anthony Cuffe; Theo McGuckin; Isadoro Carlino; C. Higgins; Harry Fanning; Matthew Bickley; Brian Bevins

2005-09-21T23:59:59.000Z

252

Method of remotely constructing a room  

DOE Patents (OSTI)

The testing of nuclear devices of high explosive yield has required that cavities of relatively large size be provided at considerable distances below the surface of the earth for the pre-detonation emplacement of the device. The construction of an essentially watertight chamber or room in the cavity is generally required for the actual emplacement of the device. A method is described of constructing such a room deep within the earth by personnel at the surface. A dual wall bladder of a watertight, pliable fabric material is lowered down a shaft into a selected position. The bladder is filled with a concrete grout while a heavy fluid having essentially the same density as the grout is maintained on both sides of the bladder, to facilitate complete deployment of the bladder by the grout to form a room of desired configuration. (10 claims)

Michie, J.D.; De Hart, R.C.

1971-10-05T23:59:59.000Z

253

Carbon War Room | Open Energy Information  

Open Energy Info (EERE)

War Room War Room Jump to: navigation, search Name Carbon War Room Place Washington, DC Number of employees 1-10 Website http://www.carbonwarroom.com/ Coordinates 38.8951118°, -77.0363658° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":38.8951118,"lon":-77.0363658,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

254

A New Control Room for SLAC Accelerators  

SciTech Connect

We are planning to construct a new control room at SLAC to unify and improve the operation of the LCLS, SPEAR3, and FACET accelerator facilities, and to provide the space and flexibility needed to support the LCLS-II and proposed new test beam facilities. The existing control rooms for the linac and SPEAR3 have been upgraded in various ways over the last decade, but their basic features have remained unchanged. We propose to build a larger modern Accelerator Control Room (ACR) in the new Research Support Building (RSB) which is currently under construction at SLAC. Shifting the center of control for the accelerator facilities entails both technical and administrative challenges. In this paper, we describe the history, concept, and status of this project.

Erickson, Roger; Guerra, E.; Stanek, M.; Hoover, Z.Van; Warren, J.; /SLAC

2012-06-04T23:59:59.000Z

255

Humidity-resistant ambient-temperature solid-electrolyte amperometric sensing apparatus and methods  

DOE Patents (OSTI)

Apparatus and methods for detecting selected chemical compounds in air or other gas streams at room or ambient temperature includes a liquid-free humidity-resistant amperometric sensor comprising a sensing electrode and a counter and reference electrode separated by a solid electrolyte. The sensing electrode preferably contains a noble metal, such as Pt black. The electrolyte is water-free, non-hygroscopic, and substantially water-insoluble, and has a room temperature ionic conductivity .gtoreq.10.sup.-4 (ohm-cm).sup.-1, and preferably .gtoreq.0.01 (ohm-cm).sup.-1. The conductivity may be due predominantly to Ag+ ions, as in Ag.sub.2 WO.sub.4.4AgI, or to F- ions, as in Ce.sub.0.95 Ca.sub.0.05 F.sub.2.95. Electrical contacts serve to connect the electrodes to potentiostating and detecting circuitry which controls the potential of the sensing electrode relative to the reference electrode, detects the signal generated by the sensor, and indicates the detected signal.

Zaromb, Solomon (9 S 706 William Dr., Hinsdale, IL 60521)

2001-01-01T23:59:59.000Z

256

Humidity-resistant ambient-temperature solid-electrolyte amperometric sensing apparatus  

DOE Patents (OSTI)

Apparatus and methods for detecting selected chemical compounds in air or other gas streams at room or ambient temperature includes a liquid-free humidity-resistant amperometric sensor comprising a sensing electrode and a counter and reference electrode separated by a solid electrolyte. The sensing electrode preferably contains a noble metal, such as Pt black. The electrolyte is water-free, non-hygroscopic, and substantially water-insoluble, and has a room temperature ionic conductivity .gtoreq.10.sup.-4 (ohm-cm).sup.-1, and preferably .gtoreq.0.01 (ohm-cm).sup.-1. The conductivity may be due predominantly to Ag+ ions, as in Ag.sub.2 WO.sub.4.4AgI, or to F- ions, as in Ce.sub.0.95 Ca.sub.0.05 F.sub.2.95. Electrical contacts serve to connect the electrodes to potentiostating and detecting circuitry which controls the potential of the sensing electrode relative to the reference electrode, detects the signal generated by the sensor, and indicates the detected signal.

Zaromb, Solomon (9S 706 William Dr., Hinsdale, IL 60521)

1994-01-01T23:59:59.000Z

257

Carbon Films Produced from Ionic Liquid Carbon Precursors ...  

The invention is directed to a method for producing a film of porous carbon, the method comprising carbonizing a film of an ionic liquid, wherein the ...

258

Spheroid-Encapsulated Ionic Liquids for Gas Separation Opportunity  

NLE Websites -- All DOE Office Websites (Extended Search)

Spheroid-Encapsulated Ionic Liquids for Gas Separation Opportunity An innovative approach has been developed allowing the use of high viscosity for gas separations. The method...

259

New Web Database Improves Access to Ionic Liquid Data  

Science Conference Proceedings (OSTI)

New Web Database Improves Access to Ionic Liquid Data. ... The ILThermo portal on the web is at http://ilthermo.boulder.nist.gov.

2013-08-22T23:59:59.000Z

260

Ionic Liquids as New Solvents for Improved Separation of ...  

A series of ionic liquids (ILs) have recently been applied as new solvents for potentially effective separation of different medical isotopes at ORNL. ...

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Available Technologies: Ionic Liquids from Lignin-derived ...  

Researchers at the Joint BioEnergy Institute (JBEI) have developed a technology to convert chemicals derived from lignin into ionic liquids for use in ...

262

Lipid extraction from microalgae using a single ionic liquid  

DOE Patents (OSTI)

A one-step process for the lysis of microalgae cell walls and separation of the cellular lipids for use in biofuel production by utilizing a hydrophilic ionic liquid, 1-butyl-3-methylimidazolium. The hydrophilic ionic liquid both lyses the microalgae cell walls and forms two immiscible layers, one of which consists of the lipid contents of the lysed cells. After mixture of the hydrophilic ionic liquid with a suspension of microalgae cells, gravity causes a hydrophobic lipid phase to move to a top phase where it is removed from the mixture and purified. The hydrophilic ionic liquid is recycled to lyse new microalgae suspensions.

Salvo, Roberto Di; Reich, Alton; Dykes, Jr., H. Waite H.; Teixeira, Rodrigo

2013-05-28T23:59:59.000Z

263

Utilizing Nanoscale Interfacial Films to Tailor Battery and Other Ionic ...  

Science Conference Proceedings (OSTI)

Such nanoscale intergranular and surficial films can be utilized to engineer lithium-ion battery cathode and anode materials, as well as solid-state ionic ...

264

Nanoscale Interfacial Films in Battery and Ionic Materials  

Science Conference Proceedings (OSTI)

Presentation Title, Nanoscale Interfacial Films in Battery and Ionic Materials. Author(s), Jian Luo, Jiajia Huang, Mojtaba Samiee. On-Site Speaker (Planned) ...

265

Ionic Liquids as Lubricants or Additives - Energy Innovation ...  

New ionic liquids invented at ORNL show great promise as lubricants for aluminum and steel in combustion engines, bearings, and microelectromechanical systems (MEMS).

266

Soft ionization of thermally evaporated hypergolic ionic liquid aerosols  

E-Print Network (OSTI)

+ ][Dca ? ]. Figure 2. Aerosol particle size distribution ofhypergolic ionic liquid aerosols Christine J. Koh † , Chen-ionization of evaporated IL aerosols Isolated ion pairs of a

Koh, Christine J.

2013-01-01T23:59:59.000Z

267

Ionic (Proton) Transport Hydrogen Separation Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

(Proton) (Proton) Transport Hydrogen Separation Systems Summary Session Participants -- Ionic Transport Balachandran, Balu Cornelius, Chris Fleming, Greg Glass, Robert Hartvigsen, Joseph Higgins, Richard King, David Paster, Mark Paul, Dilo Robbins, John Samells, Anthony Schwartz, Michael Schinski, Bill Smith, Ronald Van Bibber, Lawrence Zalesky, Rick Argonne National Laboratory Sandia National Laboratory Air Liquide Lawrence Livermore National Laboratory Cerametec, Inc. CeraMem Corporation Battelle, PNNL DOE Science Applications International Corporation ExxonMobil Eltron Research, Inc. ITN Energy Systems ChevronTexaco SRI Consulting SAIC ChevronTexaco Technology Ventures Performance Goals 4-5 years (5 years upper limit) (100,000 hrs is 12 years) High durability 250-350

268

Texas Union Pizza Order Form ROOM RESERVED ______________________________________________________  

E-Print Network (OSTI)

#12;#12;Texas Union Pizza Order Form ROOM RESERVED: ________________________________________________________________________________________________ ________________________________________________________________________________________________ ________________________________________________________________________________________________ ________________________________________________________________________________________________ ________________________________________________________________________________________________ ________________________________________________________________________________________________ ________________________________________________________________________________________________ ________________________________________________________________________________________________ Pick-up All orders are to be picked up at the Texas Union Hospitality Center desk in the south end West with the Texas Union Policies and Procedures. I understand that I will be held responsible for any debts incurred

Texas at Austin, University of

269

Advanced nuclear plant control room complex  

DOE Patents (OSTI)

An advanced control room complex for a nuclear power plant, including a discrete indicator and alarm system (72) which is nuclear qualified for rapid response to changes in plant parameters and a component control system (64) which together provide a discrete monitoring and control capability at a panel (14-22, 26, 28) in the control room (10). A separate data processing system (70), which need not be nuclear qualified, provides integrated and overview information to the control room and to each panel, through CRTs (84) and a large, overhead integrated process status overview board (24). The discrete indicator and alarm system (72) and the data processing system (70) receive inputs from common plant sensors and validate the sensor outputs to arrive at a representative value of the parameter for use by the operator during both normal and accident conditions, thereby avoiding the need for him to assimilate data from each sensor individually. The integrated process status board (24) is at the apex of an information hierarchy that extends through four levels and provides access at each panel to the full display hierarchy. The control room panels are preferably of a modular construction, permitting the definition of inputs and outputs, the man machine interface, and the plant specific algorithms, to proceed in parallel with the fabrication of the panels, the installation of the equipment and the generic testing thereof.

Scarola, Kenneth (Windsor, CT); Jamison, David S. (Windsor, CT); Manazir, Richard M. (North Canton, CT); Rescorl, Robert L. (Vernon, CT); Harmon, Daryl L. (Enfield, CT)

1993-01-01T23:59:59.000Z

270

Operating Room Pooling and Parallel Surgery Processing Under Uncertainty  

Science Conference Proceedings (OSTI)

Operating room (OR) scheduling is an important operational problem for most hospitals. In this study, we present a novel two-stage stochastic mixed-integer programming model to minimize total expected operating cost given that scheduling decisions are ... Keywords: multiple operating rooms, operating room pooling, operating room scheduling, parallel surgery processing, two-stage stochastic mixed-integer programs

Sakine Batun; Brian T. Denton; Todd R. Huschka; Andrew J. Schaefer

2011-04-01T23:59:59.000Z

271

Fluorescent temperature sensor  

Science Conference Proceedings (OSTI)

The present invention is a fluorescent temperature sensor or optical thermometer. The sensor includes a solution of 1,3-bis(1-pyrenyl)propane within a 1-butyl-1-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid solvent. The 1,3-bis(1-pyrenyl)propane remains unassociated when in the ground state while in solution. When subjected to UV light, an excited state is produced that exists in equilibrium with an excimer. The position of the equilibrium between the two excited states is temperature dependent.

Baker, Gary A [Los Alamos, NM; Baker, Sheila N [Los Alamos, NM; McCleskey, T Mark [Los Alamos, NM

2009-03-03T23:59:59.000Z

272

Solubilities of Solutes in Ionic Liquids from a SimplePerturbed-Hard-Sphere Theory  

SciTech Connect

In recent years, several publications have provided solubilities of ordinary gases and liquids in ionic liquids. This work reports an initial attempt to correlate the experimental data using a perturbed-hard-sphere theory; the perturbation is based on well-known molecular physics when the solution is considered as a dielectric continuum. For this correlation, the most important input parameters are hard-sphere diameters of the solute and of the cation and anion that constitute the ionic liquid. In addition, the correlation uses the solvent density and the solute's polarizability and dipole and quadrupole moments, if any. Dispersion-energy parameters are obtained from global correlation of solubility data. Results are given for twenty solutes in several ionic liquids at normal temperatures; in addition, some results are given for gases in two molten salts at very high temperatures. Because the theory used here is much simplified, and because experimental uncertainties (especially for gaseous solutes) are often large, the accuracy of the correlation presented here is not high; in general, predicted solubilities (Henry's constants) agree with experiment to within roughly {+-} 70%. As more reliable experimental data become available, modifications in the characterizing parameters are likely to improve accuracy. Nevertheless, even in its present form, the correlation may be useful for solvent screening in engineering design.

Qin, Yuan; Prausnitz, John M.

2005-09-20T23:59:59.000Z

273

THERMOPHYSICAL PROPERTIES OF NANOPARTICLE-ENHANCED IONIC LIQUIDS HEAT TRANSFER FLUIDS  

SciTech Connect

An experimental investigation was completed on nanoparticle enhanced ionic liquid heat transfer fluids as an alternative to conventional organic based heat transfer fluids (HTFs). These nanoparticle-based HTFs have the potential to deliver higher thermal conductivity than the base fluid without a significant increase in viscosity at elevated temperatures. The effect of nanoparticle morphology and chemistry on thermophysical properties was examined. Whisker shaped nanomaterials were found to have the largest thermal conductivity temperature dependence and were also less likely to agglomerate in the base fluid than spherical shaped nanomaterials.

Fox, E.

2013-04-15T23:59:59.000Z

274

Phytoremediation of Ionic and Methyl Mercury P  

DOE Green Energy (OSTI)

Our long-term goal is to enable highly productive plant species to extract, resist, detoxify, and/or sequester toxic heavy metal pollutants as an environmentally friendly alternative to physical remediation methods. We have focused this phytoremediation research on soil and water-borne ionic and methylmercury. Mercury pollution is a serious world-wide problem affecting the health of human and wild-life populations. Methylmercury, produced by native bacteria at mercury-contaminated wetland sites, is a particularly serious problem due to its extreme toxicity and efficient biomagnification in the food chain. We engineered several plant species (e.g., Arabidopsis, tobacco, canola, yellow poplar, rice) to express the bacterial genes, merB and/or merA, under the control of plant regulatory sequences. These transgenic plants acquired remarkable properties for mercury remediation. (1) Transgenic plants expressing merB (organomercury lyase) extract methylmercury from their growth substrate and degrade it to less toxic ionic mercury. They grow on concentrations of methylmercury that kill normal plants and accumulate low levels of ionic mercury. (2) Transgenic plants expressing merA (mercuric ion reductase) extract and electrochemically reduce toxic, reactive ionic mercury to much less toxic and volatile metallic mercury. This metal transformation is driven by the powerful photosynthetic reducing capacity of higher plants that generates excess NADPH using solar energy. MerA plants grow vigorously on levels of ionic mercury that kill control plants. Plants expressing both merB and merA degrade high levels of methylmercury and volatilize metallic mercury. These properties were shown to be genetically stable for several generations in the two plant species examined. Our work demonstrates that native trees, shrubs, and grasses can be engineered to remediate the most abundant toxic mercury pollutants. Building on these data our working hypothesis for the next grant period is that transgenic plants expressing the bacterial merB and merA genes will (a) remove mercury from polluted soil and water and (b) prevent methylmercury from entering the food chain. Our specific aims center on understanding the mechanisms by which plants process the various forms of mercury and volatilize or transpire mercury vapor. This information will allow us to improve the design of our current phytoremediation strategies. As an alternative to volatilizing mercury, we are using several new genes to construct plants that will hyperaccumulate mercury in above-ground tissues for later harvest. The Department of Energy's Oak Ridge National Laboratory and Brookhaven National Laboratory have sites with significant levels of mercury contamination that could be cleaned by applying the scientific discoveries and new phytoremediation technologies described in this proposal. The knowledge and expertise gained by engineering plants to hyperaccumulate mercury can be applied to the remediation of other heavy metals pollutants (e.g., arsenic, cesium, cadmium, chromium, lead, strontium, technetium, uranium) found at several DOE facilities.

Meagher, Richard B.

1999-06-01T23:59:59.000Z

275

Measurement of pH in high ionic strength solutions  

DOE Patents (OSTI)

A practical method is described for measuring pH in solutions of high ionic strength (e.g., brines, process solutions). The pH is determined by integratively measuring the potential due to H{sup +} and the potential due to another cation or anion and relating the combined electrical potential to a calculated pH for high ionic strength solutions.

Knauss, K.G.; Wolery, T.J.; Jackson, K.J.

1991-12-31T23:59:59.000Z

276

Intermolecular Dynamics, Interactions and Solvation in Ionic Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

Dynamics, Interactions and Solvation in Ionic Liquids Dynamics, Interactions and Solvation in Ionic Liquids Edward W. Castner, Jr., James F. Wishart, and Hideaki Shirota Acc. Chem. Res. 40, 1217-1227 (2007). [Find paper at ACS Publications] Abstract: Ionic liquids can simultaneously assume multiple solvent roles, because they are strongly polar and polarizable solvents and binary solutions and frequently contain very hydrophobic components. When the cation and anion functional groups are tuned appropriately, ionic liquids can be used as designer solvents for a broad range of applications. In this Account, we discuss our spectroscopic studies on the intermolecular interactions, dynamics, solvation, transport, and friction in ionic liquids, as compared with information obtained from macroscopic experiments including viscometry

277

Recovery of Sugars from Ionic Liquid Biomass Liquor by Solvent Extraction  

E-Print Network (OSTI)

from Ionic Liquid Biomass Liquor by Solvent ExtractionAbstract The dissolution of biomass into ionic liquids (ILs)be a promising alternative biomass pretreatment technology,

Brennan, Timothy C.; Datta, Supratim; Blanch, Harvey W.; Simmons, Blake A.; Holmes, Bradley M.

2010-01-01T23:59:59.000Z

278

Priority coding for control room alarms  

SciTech Connect

Indicating the priority of a spatially fixed, activated alarm tile on an alarm tile array by a shape coding at the tile, and preferably using the same shape coding wherever the same alarm condition is indicated elsewhere in the control room. The status of an alarm tile can change automatically or by operator acknowledgement, but tones and/or flashing cues continue to provide status information to the operator.

Scarola, Kenneth (Windsor, CT); Jamison, David S. (Windsor, CT); Manazir, Richard M. (North Canton, CT); Rescorl, Robert L. (Vernon, CT); Harmon, Daryl L. (Enfield, CT)

1994-01-01T23:59:59.000Z

279

Carbon Dioxide and Ionic Liquid Refrigerants: Compact, Efficient Air Conditioning with Ionic Liquid-Based Refrigerants  

SciTech Connect

BEETIT Project: Notre Dame is developing an air-conditioning system with a new ionic liquid and CO2 as the working fluid. Synthetic refrigerants used in air conditioning and refrigeration systems are potent GHGs and can trap 1,000 times more heat in the atmosphere than CO2 alone—making CO2 an attractive alternative for synthetic refrigerants in cooling systems. However, operating cooling systems with pure CO2 requires prohibitively high pressures and expensive hardware. Notre Dame is creating a new fluid made of CO2 and ionic liquid that enables the use of CO2 at low pressures and requires minimal changes to existing hardware and production lines. This new fluid also produces no harmful emissions and can improve the efficiency of air conditioning systems— enabling new use of CO2 as a refrigerant in cooling systems.

2010-10-01T23:59:59.000Z

280

Designing for man: advances in control room operation  

SciTech Connect

Considers the human factor in nuclear power plants in relation to improving control room and maintenance operations. Control room operators face thousands of dials, meters, and indicator lights dispersed over large control boards. Components may not be arranged in clearly identifiable panels of related elements; sometimes related controls may not be near each other. Extensive alarm systems may sometimes confuse rather than alert the operators; communications with other parts of the plant may be difficult. Maintenance personnel may have to squeeze past pipes and similar obstructions to make repairs while carrying equipment and tools, sometimes while wearing protective gear. EPRI has developed a cool suit consisting of 16 pounds of water-filled compartments built into a two-piece repair suit that can be frozen to keep body temperatures at acceptable levels for up to 2 hrs. in high-heat areas of the plant. An ergonomics guide, which examines alternative solutions to heat stress (such as rest cycles and worker screening) is also being developed. Because few new nuclear plants are currently being built, many of the improvements will be retrofits in existing plants. EPRI's human factors work emphasizes thorough validation of new techniques through simulators and mockups.

Lihach, N.

1982-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Structure and Dynamics of N, N-diethyl-N-methylammonium Triflate Ionic Liquid, Neat and with Water, from Molecular Dynamics Simulations  

DOE Green Energy (OSTI)

We investigated by means of molecular dynamics simulations the properties (structure, thermodynamics, ion transport, and dynamics) of the protic ionic liquid N,N-diethyl-N-methyl-ammonium triflate (dema:Tfl) and of selected aqueous mixtures of dema:Tfl. This ionic liquid, a good candidate for a water-free proton exchange membrane, is shown to exhibit high ion mobility and conductivity. For bulk melts in the temperature range of 303-453K, both liquid densities and enthalpies of vaporization are found to decrease roughly linearly with increasing temperature. The radial distribution functions reveal a significant long-range structural correlation. The ammonium cations [dema]+ are found to diffuse slightly faster than the triflate anions [Tfl]-, and both types of ions exhibit enhanced mobility at higher temperatures, leading to higher ionic conductivity of these ionic liquids. Analysis of the dynamics of ion pairing clearly points to the existence of long-lived contact ion pairs in this ionic liquid. We also examined the effects of water on the ionic properties of dema:Tfl-water mixtures. From the structural analysis it was found that water molecules tend to replace counter ions in the coordination shell and hydrogen bond to both ions, thus weakening their mutual association. As water concentration increases, water molecules start to connect with each other and eventually form a large network that percolates through the system. It is also found that water has a strong influence on the ion dynamics in the mixtures. As the concentration of water increases, both translational and rotational motion of [dema]+ and [Tfl]- are significantly enhanced. As a result, higher ionic conductivity is observed with increased hydration level. This work was supported by the US Department of Energy Basic Energy Sciences' Chemical Sciences, Geosciences & Biosciences Division. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

Chang, Tsun-Mei; Dang, Liem X.; Devanathan, Ramaswami; Dupuis, Michel

2010-12-09T23:59:59.000Z

282

Soft ionization of thermally evaporated hypergolic ionic liquid aerosols  

Science Conference Proceedings (OSTI)

Isolated ion pairs of a conventional ionic liquid, 1-Ethyl-3-Methyl-Imidazolium Bis(trifluoromethylsulfonyl)imide ([Emim+][Tf2N?]), and a reactive hypergolic ionic liquid, 1-Butyl-3-Methyl-Imidazolium Dicyanamide ([Bmim+][Dca?]), are generated by vaporizing ionic liquid submicron aerosol particles for the first time; the vaporized species are investigated by dissociative ionization with tunable vacuum ultraviolet (VUV) light, exhibiting clear intact cations, Emim+ and Bmim+, presumably originating from intact ion pairs. Mass spectra of ion pair vapor from an effusive source of the hypergolic ionic liquid show substantial reactive decomposition due to the internal energy of the molecules emanating from the source. Photoionization efficiency curves in the near threshold ionization region of isolated ion pairs of [Emim+][Tf2N?]ionic liquid vapor are compared for an aerosol source and an effusive source, revealing changes in the appearance energy due to the amount of internal energy in the ion pairs. The aerosol source has a shift to higher threshold energy (~;;0.3 eV), attributed to reduced internal energy of the isolated ion pairs. The method of ionic liquid submicron aerosol particle vaporization, for reactive ionic liquids such as hypergolic species, is a convenient, thermally ?cooler? source of isolated intact ion pairs in the gas phase compared to effusive sources.

University of California; ERC, Incorporated, Edwards Air Force Base; Air Force Research Laboratory, Edwards Air Force Base; National Synchrotron Radiation Research Center (NSRRC); Institute of Chemistry, Hebrew University; Koh, Christine J.; Liu, Chen-Lin; Harmon, Christopher W.; Strasser, Daniel; Golan, Amir; Kostko, Oleg; Chambreau, Steven D.; Vaghjiani, Ghanshyam L.; Leone, Stephen R.

2011-07-19T23:59:59.000Z

283

Strongly coupled ionic mixtures and the H/He EOS  

DOE Green Energy (OSTI)

This paper summarizes recent work on the strongly coupled OCP and Binary Ionic Mixture equation of state and other thermodynamic quantities in white dwarf interior conditions for both fluid and solid phases with the assumption of a uniform background. Conditions for phase separation of different elements in fluid or solid phases is strongly dependent on deviations from the linear mixing rule which gives the equation of state as an additive function of the OCP equation of state. These deviations turn out to be small (a few parts in 10{sup 5}) and always positive including the case where the fraction of the higher Z component approaches 0. Also the equation of state of strongly coupled light elements (H and He particularly) obtained from simulations with a linear response description of the electrons is given for conditions appropriate to brown dwarf star interiors. Recent Livermore work on a band structure calculation of the enthalpy of H and He mixtures under jovian conditions is discussed. This work leads to a prediction of a high temperature (15,000 K) for miscibility of He in ionized H at 10 Mb.

DeWitt, H.E.

1993-12-02T23:59:59.000Z

284

Federal Energy Management Program: Covered Product Category: Room Air  

NLE Websites -- All DOE Office Websites (Extended Search)

Room Air Conditioners to someone by E-mail Room Air Conditioners to someone by E-mail Share Federal Energy Management Program: Covered Product Category: Room Air Conditioners on Facebook Tweet about Federal Energy Management Program: Covered Product Category: Room Air Conditioners on Twitter Bookmark Federal Energy Management Program: Covered Product Category: Room Air Conditioners on Google Bookmark Federal Energy Management Program: Covered Product Category: Room Air Conditioners on Delicious Rank Federal Energy Management Program: Covered Product Category: Room Air Conditioners on Digg Find More places to share Federal Energy Management Program: Covered Product Category: Room Air Conditioners on AddThis.com... Energy-Efficient Products Federal Requirements Covered Product Categories Product Designation Process

285

Release of DRAFT RFP Headquarters Reading Room Instructions/Guidelines  

NLE Websites -- All DOE Office Websites (Extended Search)

Release of DRAFT RFP Release of DRAFT RFP Headquarters Reading Room Instructions/Guidelines 1. Reading Room Points of Contact: 7/21 - 8/8, Mike Baehre, (202) 586-6575 8/9 - Close of Draft RFP, John Bernier, (202) 586-6416 Reading Room Availability: By Appointment - Reading Room will be available until DRAFT RFP Closes. Reading Room Hours: Morning, 9:00 a.m. - 11:30 a.m.; and Afternoon 1:00 p.m. - 3:30 p.m. Reading Room Will Accommodate: Up to 5-6 people 2. All personnel must: a. Sign-in b. Identify their Company or Firm they work for or are affiliated c. Indicate if they have a "Q" clearance 3. Personnel must stay in the Reading Room to view documents. The "A" corridor is inside a classified area and all visitors to the Reading Room must be escorted at all times.

286

Evaluation of Energy-Efficiency Standards for Room Air Conditioners...  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy-Efficiency Standards for Room Air Conditioners in the US Title Evaluation of Energy-Efficiency Standards for Room Air Conditioners in the US Publication Type Journal Article...

287

Valance heating/cooling system attains largest application in 1,000-room hotel  

SciTech Connect

Room temperatures in the 1,000 guest rooms of Chicago's Hyatt Regency Hotel are controlled by a valance heating and cooling system that functions by means of radiation and convection. The valances are mounted below the ceiling and consists of finned tubes and a drain tube contained within a wall-mounted enclosure. The finned tubes and drain are connected to a riser system, that is connected to a hot and cold water supply. The economics of the system is discussed and with no fans, motors, or blowers to run, energy is conserved. (MCW)

1976-08-01T23:59:59.000Z

288

Structural simulations of nanomaterials self-assembled from ionic macrocycles.  

DOE Green Energy (OSTI)

Recent research at Sandia has discovered a new class of organic binary ionic solids with tunable optical, electronic, and photochemical properties. These nanomaterials, consisting of a novel class of organic binary ionic solids, are currently being developed at Sandia for applications in batteries, supercapacitors, and solar energy technologies. They are composed of self-assembled oligomeric arrays of very large anions and large cations, but their crucial internal arrangement is thus far unknown. This report describes (a) the development of a relevant model of nonconvex particles decorated with ions interacting through short-ranged Yukawa potentials, and (b) the results of initial Monte Carlo simulations of the self-assembly binary ionic solids.

van Swol, Frank B.; Medforth, Craig John (University of New Mexico, Albuquerque, NM)

2010-10-01T23:59:59.000Z

289

THE CONSTRUCTION AND OPERATION OF EXPERIMENTAL ROOMS FOR THE STUDY OF AIR-BORNE INFECTION*  

E-Print Network (OSTI)

In order to carry out adequately controlled studies on the effects of temperature and humidity on the behavior of bacteria and viruses suspended in the air under various experimental conditions, it became necessary to have available enclosed spaces in which any desired atmospheric state could be produced and maintained. The use of conventional methods of air conditioning is unsuitable for this purpose because all of these depend upon exchange of the air inside the experimental space with conditioned air. Hence, two identical air-tight, glass-walled rooms 8 feet X 10 feet and 8 feet high were built each within a separate air-conditioned shell which can be kept constantly at any temperature and relative humidity likely to be encountered in spaces occupied by human beings. Rapid circulation of the conditioned air over all surfaces of the inner room provides a sufficiently high rate of heat transfer to insure constant temperature conditions within that space. The relative humidity of the inner room can be maintained at the same level as the air of the outer shell or can be increased by the introduction of steam. Two rooms provide much greater

O. H. Robertson; Theodore T. Puck, Ph.D.; Henry Wise

1946-01-01T23:59:59.000Z

290

Commissioning Tools for Heating/Cooling System in Residence - Verification of Floor Heating System and Room Air Conditioning System Performance  

E-Print Network (OSTI)

Tools of evaluating the performance of floor heating and room air conditioner are examined as a commissioning tool. Simple method is needed to check these performance while in use by residents, because evaluation currently requires significant time and effort. Therefore, this paper proposes a) two methods of evaluating the floor heating efficiency from the room / crawl space temperature and the energy consumption and b) method of evaluating COP of the room air conditioner from the data measured at the external unit. Case studies in which these tools were applied to actual residences are presented to demonstrate their effectiveness.

Miura, H.; Hokoi, S.; Iwamae, A.; Umeno, T.; Kondo, S.

2004-01-01T23:59:59.000Z

291

Pre-validation of nuclear power plant control room design  

Science Conference Proceedings (OSTI)

Evaluation of the design of complex automation and control room systems is an essential phase in the design process in the nuclear field. For example, in order to meet the nuclear regulatory requirements, the new control room systems have to be evaluated ... Keywords: concept of operations, control room, pre-validation, verification & validation

Jari Laarni; Paula Savioja; Hannu Karvonen; Leena Norros

2011-07-01T23:59:59.000Z

292

Tritium Room Air Monitor Operating Experience Review  

SciTech Connect

Monitoring the breathing air in tritium facility rooms for airborne tritium is a radiological safety requirement and a best practice for personnel safety. Besides audible alarms for room evacuation, these monitors often send signals for process shutdown, ventilation isolation, and cleanup system actuation to mitigate releases and prevent tritium spread to the environment. Therefore, these monitors are important not only to personnel safety but also to public safety and environmental protection. This paper presents an operating experience review of tritium monitor performance on demand during small (1 mCi to 1 Ci) operational releases, and intentional airborne inroom tritium release tests. The tritium tests provide monitor operation data to allow calculation of a statistical estimate for the reliability of monitors annunciating in actual tritium gas airborne release situations. The data show a failure to operate rate of 3.5E-06/monitor-hr with an upper bound of 4.7E-06, a failure to alarm on demand rate of 1.4E-02/demand with an upper bound of 4.4E-02, and a spurious alarm rate of 0.1 to 0.2/monitor-yr.

L. C. Cadwallader; B. J. Denny

2008-09-01T23:59:59.000Z

293

Method for measuring surface temperature  

DOE Patents (OSTI)

The present invention relates to a method for measuring a surface temperature using is a fluorescent temperature sensor or optical thermometer. The sensor includes a solution of 1,3-bis(1-pyrenyl)propane within a 1-butyl-1-1-methyl pyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid solvent. The 1,3-bis(1-pyrenyl)propane remains unassociated when in the ground state while in solution. When subjected to UV light, an excited state is produced that exists in equilibrium with an excimer. The position of the equilibrium between the two excited states is temperature dependent.

Baker, Gary A. (Los Alamos, NM); Baker, Sheila N. (Los Alamos, NM); McCleskey, T. Mark (Los Alamos, NM)

2009-07-28T23:59:59.000Z

294

Method and apparatus using an active ionic liquid for algae biofuel harvest and extraction  

Science Conference Proceedings (OSTI)

The invention relates to use of an active ionic liquid to dissolve algae cell walls. The ionic liquid is used to, in an energy efficient manner, dissolve and/or lyse an algae cell walls, which releases algae constituents used in the creation of energy, fuel, and/or cosmetic components. The ionic liquids include ionic salts having multiple charge centers, low, very low, and ultra low melting point ionic liquids, and combinations of ionic liquids. An algae treatment system is described, which processes wet algae in a lysing reactor, separates out algae constituent products, and optionally recovers the ionic liquid in an energy efficient manner.

Salvo, Roberto Di; Reich, Alton; Dykes, Jr., H. Waite H.; Teixeira, Rodrigo

2012-11-06T23:59:59.000Z

295

Effects of Structural Modification on Ionic Liquid Physical Properties  

NLE Websites -- All DOE Office Websites (Extended Search)

Effect of Structural Modification on the Physical Properties Effect of Structural Modification on the Physical Properties of Various Ionic Liquids S. I. Lall-Ramnarine, J. L. Hatcher, A. Castano, M. F. Thomas, and J. F. Wishart in "ECS Transactions - Las Vegas, NV, Vol. 33, Molten Salts and Ionic Liquids 17" D. Fox et al., Eds.; The Electrochemical Society, Pennington, NJ, (2010) pp 659 - 665. [Find paper at ECS] Abstract: A few classes of ionic liquids were synthesized and investigated for their physical properties as a function of structural variation. Bis(oxalato)borate (BOB) and bis(trifluoromethylsulfonyl)imide (NTf2) ionic liquids (ILs) containing pyridinium, 4-dimethylaminopyridinium (DMAP) and pyrrolidinium cations bearing alkyl, benzyl, hydroxyalkyl and alkoxy substituents, were prepared from the corresponding halide salts. The

296

Design and Evaluation of Ionic Liquids as Novel Absorbents  

NLE Websites -- All DOE Office Websites (Extended Search)

Design anD evaluation of ionic liquiDs Design anD evaluation of ionic liquiDs as novel absorbents Background There is growing concern among climate scientists that the buildup of greenhouse gases (GHG), particularly carbon dioxide (CO 2 ), in the atmosphere is affecting the global climate in ways that could have serious consequences. One approach to reducing GHG emissions is to scrub CO 2 from the flue gas of power plants and sequester it in geologic formations. Although it is technically feasible to remove CO 2 from flue gas, current processes are too expensive. New, less expensive processes are needed. This project is investigating the feasibility of using a novel class of compounds - ionic liquids - for the capture of CO 2 from the flue gas from coal and natural gas-fired power plants. The success of ionic liquids technology

297

Heavy Atom Substitution Effects in Non-Aromatic Ionic Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

Atom Substitution Effects in Non-Aromatic Ionic Liquids: Ultrafast Dynamics and Physical Properties H. Shirota, H. Fukazawa, T. Fujisawa, and J. F. Wishart J. Phys. Chem. B 114,...

298

Radiation Chemistry of Ionic Liquids: Reactivity of Primary Species  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquids: Reactivity of Primary Species Liquids: Reactivity of Primary Species James F. Wishart In "Ionic Liquids as Green Solvents: Progress and Prospects" Rogers, R. D. and Seddon, K. R. , Eds.; ACS Symp. Ser. 856, Ch. 31, pp. 381-395, American Chemical Society, Washington, DC, 2003. (ISBN 0-84123-856-1) [Information about the book] Abstract: An understanding of the radiation chemistry of ionic liquids is important for development of their applications in radioactive material processing and for the application of pulse radiolysis techniques to the general study of chemical reactivity in ionic liquids. The distribution of primary radiolytic species and their reactivities determine the yields of ultimate products and the radiation stability of a particular ionic liquid. This chapter introduces some principles of radiation chemistry and the

299

Trialkylammonio-Dodecaborates: Anions for Ionic Liquids with...  

NLE Websites -- All DOE Office Websites (Extended Search)

Trialkylammonio-Dodecaborates: Anions for Ionic Liquids with Potassium, Lithium and Proton as Cations E. Justus, K. Rischka, J. F. Wishart, K. Werner and D. Gabel Chem. Eur. J. 14,...

300

Toward Radiation-Resistant Ionic Liquids. Radiation Stability...  

NLE Websites -- All DOE Office Websites (Extended Search)

Radiation-Resistant Ionic Liquids. Radiation Stability of Sulfonyl Imide Anions I. A. Shkrob, T. W. Marin, Sergey D. Chemerisov, J. L. Hatcher, and J. F. Wishart J. Phys. Chem. B...

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Spheroid-Encapsulated Ionic Liquids for Gas Separation  

  An innovative approach has been developed allowing the use of high viscosity for gas separations. The method involves the encapsulation of ionic liquids (ILs) into polymer spheroids, taking advantage of the gas-absorbing properties and ...

302

Shear and Extensional Rheology of Cellulose/Ionic Liquid Solutions  

E-Print Network (OSTI)

In this study, we characterize the shear and extensional rheology of dilute to semidilute solutions of cellulose in the ionic liquid 1-ethyl-3-methylimidazolium acetate (EMIAc). In steady shear flow, the semidilute solutions ...

Haward, Simon J.

303

Bioreduction and precipitation of uranium in ionic liquid aqueous...  

NLE Websites -- All DOE Office Websites (Extended Search)

Nuclear Engineering, Pohang University of Science and Technology, Pohang 790-784, South Korea h i g h l i g h t s &21; Uranium forms various complexes with ionic liquids. &21; Uranium...

304

Energy and critical ionic-bond parameter of a 3D large-radius bipolaron  

Science Conference Proceedings (OSTI)

A theory of a strong-coupling large-radius bipolaron has been developed. The possibility of the formation of 3D bipolarons in high-temperature superconductors is discussed. For the bipolaron energy, the lowest variational estimate has been obtained at {alpha} > 8, where {alpha} is the electron-phonon coupling constant. The critical ionic-bond parameter {eta}{sub c} = {epsilon}{sub {infinity}/{epsilon}0}, where {epsilon}{sub {infinity}} and {epsilon}{sub 0} are the high-frequency and static dielectric constants, has been found to be {eta}{sub c} = 0.2496.

Lakhno, V. D., E-mail: lak@impb.psn.r [Russian Academy of Sciences, Institute of Mathematical Problems of Biology (Russian Federation)

2010-05-15T23:59:59.000Z

305

Brazing a Mixed Ionic/Electronic Conductor to an Oxidation Resistant Metal  

DOE Green Energy (OSTI)

Mixed ionically/electrically conducting oxides such as lanthanum calcium manganate are currently being investigated for use as electrodes in a number of high temperature devices, including solid oxide fuel cells. Traditionally, glass seals have been employed as a means of hermetically joining the ceramic components that lie at the heart of these devices to the heat resistant metal frame that gives the device its structural integrity. The present paper outlines an alternative brazing technique for joining these dissimilar materials and discusses recent findings regarding the wettability of the braze on the two joining surfaces, as well as the strength of the resulting joint.

Weil, K. Scott; Hardy, John S.

2003-09-05T23:59:59.000Z

306

Laser sheet light flow visualization for evaluating room air flowsfrom Registers  

SciTech Connect

Forced air heating and cooling systems and whole house ventilation systems deliver air to individual rooms in a house via supply registers located on walls ceilings or floors; and occasionally less straightforward locations like toe-kicks below cabinets. Ideally, the air velocity out of the registers combined with the turbulence of the flow, vectoring of air by register vanes and geometry of register placement combine to mix the supply air within the room. A particular issue that has been raised recently is the performance of multiple capacity and air flow HVAC systems. These systems vary the air flow rate through the distribution system depending on the system load, or if operating in a ventilation rather than a space conditioning mode. These systems have been developed to maximize equipment efficiency, however, the high efficiency ratings do not include any room mixing effects. At lower air flow rates, there is the possibility that room air will be poorly mixed, leading to thermal stratification and reduced comfort for occupants. This can lead to increased energy use as the occupants adjust the thermostat settings to compensate and parts of the conditioned space have higher envelope temperature differences than for the well mixed case. In addition, lack of comfort can be a barrier to market acceptance of these higher efficiency systems To investigate the effect on room mixing of reduced air flow rates requires the measurement of mixing of supply air with room air throughout the space to be conditioned. This is a particularly difficult exercise if we want to determine the transient performance of the space conditioning system. Full scale experiments can be done in special test chambers, but the spatial resolution required to fully examine the mixing problem is usually limited by the sheer number of thermal sensors required. Current full-scale laboratory testing is therefore severely limited in its resolution. As an alternative, we used a water-filled scale model of a room in which whole-field supply air mixing maps of two vertical planes were measured using a Planar Laser-Induced Fluorescence (PLIF) measurement technique. Water marked with fluorescent dye was used to simulate the supply airflow; and the resulting concentrations within the water filled model show how the supply air mixes with the room air and are an analog for temperature (for thermal loads) or fresh air (for ventilation). In addition to performing experiments over a range of flow rates, we also changed register locations and examined the effects for both heating and cooling operation by changing the water density (simulating air density changes due to temperature changes) using dissolved salt.

Walker, Iain S.; Claret, Valerie; Smith, Brian

2006-04-01T23:59:59.000Z

307

Chromatin ionic atmosphere analyzed by a mesoscale electrostatic approach  

E-Print Network (OSTI)

ABSTRACT Characterizing the ionic distribution around chromatin is important for understanding the electrostatic forces governing chromatin structure and function. Here we develop an electrostatic model to handle multivalent ions and compute the ionic distribution around a mesoscale chromatin model as a function of conformation, number of nucleosome cores, and ionic strength and species using Poisson-Boltzmann theory. This approach enables us to visualize and measure the complex patterns of counterion condensation around chromatin by examining ionic densities, free energies, shielding charges, and correlations of shielding charges around the nucleosome core and various oligonucleosome conformations. We show that: counterions, especially divalent cations, predominantly condense around the nucleosomal and linker DNA, unburied regions of histone tails, and exposed chromatin surfaces; ionic screening is sensitively influenced by local and global conformations, with a wide ranging net nucleosome core screening charge (56–100e); and screening charge correlations reveal conformational flexibility and interactions among chromatin subunits, especially between the histone tails and parental nucleosome cores. These results provide complementary and detailed views of ionic effects on chromatin structure for modest computational resources. The electrostatic model developed here is applicable to other coarse-grained macromolecular complexes.

Hin Hark Gan; Tamar Schlick

2010-01-01T23:59:59.000Z

308

NETL: NewsRoom - LabNotes  

NLE Websites -- All DOE Office Websites (Extended Search)

LabNotes LabNotes NewsRoom LabNotes January 2014 Chemical Looping 101: The Basics NETL's Chemical Looping Research Facilities Oxygen Carriers in Chemical Looping Combustion Chemical Looping Modeling and Simulation Research at NETL December 2013 Foamed Cement Can Seal Tricky Oil and Gas Wells November 2013 High-Performance Rechargeable Batteries May Help Keep the Lights On Rocks Demystified in Geomechanical Properties Lab October 2013 NETL's Morgantown Supercomputer Sets a High Bar for Energy Efficiency September 2013 NETL's Energy Data Exchange (EDX): Providing Access to Quality Energy Data Sorbents Capturing CO2 Will Make Power Plants Cleaner August 2013 Collaborative Technology Demonstrates Potential in Diabetes Testing Quantifying Uncertainty in Computer Model Predictions

309

Room air monitor for radioactive aerosols  

DOE Patents (OSTI)

A housing assembly for use with a room air monitor for simultaneous collection and counting of suspended particles includes a casing containing a combination detector-preamplifier system at one end, a filter system at the other end, and an air flow system consisting of an air inlet formed in the casing between the detector-preamplifier system and the filter system and an air passageway extending from the air inlet through the casing and out the end opposite the detector-preamplifier combination. The filter system collects suspended particles transported directly through the housing by means of the air flow system, and these particles are detected and examined for radioactivity by the detector-pre The U.S. Government has rights in this invention pursuant to Contract No. DE-AC04-76DP03533 between the Department of Energy and Rockwell International Corporation.

Balmer, David K. (Broomfield, CO); Tyree, William H. (Boulder, CO)

1989-04-11T23:59:59.000Z

310

Room air monitor for radioactive aerosols  

DOE Patents (OSTI)

A housing assembly for use with a room air monitor for simultaneous collection and counting of suspended particles includes a casing containing a combination detector-preamplifier system at one end, a filter system at the other end, and an air flow system consisting of an air inlet formed in the casing between the detector-preamplifier system and the filter system and an air passageway extending from the air inlet through the casing and out the end opposite the detector-preamplifier combination. The filter system collects suspended particles transported directly through the housing by means of the air flow system, and these particles are detected and examined for radioactivity by the detector-preamplifier combination. 2 figs.

Balmer, D.K.; Tyree, W.H.

1987-03-23T23:59:59.000Z

311

Mixed Ionic and Electonic Conductors for Hydrogen Generation and Separation: A New Approach  

DOE Green Energy (OSTI)

Composite mixed conductors comprising one electronic conducting phase, and one ionic conducting phase (MIECs) have been developed in this work. Such MIECs have applications in generating and separating hydrogen from hydrocarbon fuels at high process rates and high purities. The ionic conducting phase comprises of rare-earth doped ceria and the electronic conducting phase of rare-earth doped strontium titanate. These compositions are ideally suited for the hydrogen separation application. In the process studied in this project, steam at high temperatures is fed to one side of the MIEC membrane and hydrocarbon fuel or reformed hydrocarbon fuel to the other side of the membrane. Oxygen is transported from the steam side to the fuel side down the electrochemical potential gradient thereby enriching the steam side flow in hydrogen. The remnant water vapor can then be condensed to obtain high purity hydrogen. In this work we have shown that two-phase MIECs comprising rare-earth ceria as the ionic conductor and doped-strontium titanate as the electronic conductor are stable in the operating environment of the MIEC. Further, no adverse reaction products are formed when these phases are in contact at elevated temperatures. The composite MIECs have been characterized using a transient electrical conductivity relaxation technique to measure the oxygen chemical diffusivity and the surface exchange coefficient. Oxygen permeation and hydrogen generation rates have been measured under a range of process conditions and the results have been fit to a model which incorporates the oxygen chemical diffusivity and the surface exchange coefficient from the transient measurements.

Srikanth Gopalan

2006-12-31T23:59:59.000Z

312

Theoretical Investigations on Nanoporpus Materials and Ionic Liquids for Energy Storage  

E-Print Network (OSTI)

In the current context of rapidly depleting petroleum resources and growing environmental concerns, it is important to develop materials to harvest and store energy from renewable and sustainable sources. Hydrogen has the potential to be an alternative energy source, since it has higher energy content than petroleum. However, since hydrogen has very low volumetric energy density, hence it is important to design nano porous materials which can efficiently store large volumes of hydrogen gas by adsorption. In this regard carbon nanotube and Metal Organic Framework (MOFs) based materials are worth studying. Ionic liquids (IL) are potential electrolytes that can improve energy storage capacity and safety in Li ion batteries. Therefore it is important to understand IL's thermodynamic and transport properties, especially when it is in contact with electrode surface and mixed with Li salt, as happens in the battery application. This dissertation presents computation and simulation based studies on: 1. Hydrogen storage in carbon nanotube scaffold. 2. Mechanical property and stability of various nanoporous Metal Organic Frameworks. 3. Thermodynamic and transport properties of [BMIM][BF4] ionic liquid in bulk, in Li Salt mixture, on graphite surface and under nanoconfinement. In the first study, we report the effects of carbon nanotube diameter, tube chirality, tube spacer distance, tube functionalization and presence of Li on hydrogen sorption capacity and thermodynamics at different temperature and pressure. In the second one, we observe high pressure induced structural transformation of 6 isoreticular MOFs: IRMOF-1. IRMOF-3, IRMOF-6, IRMOF-8, IRMOF-10 and IRMOF-14, explore the deformation mechanism and effect of Hydrogen inside crystal lattice. In the third study, we observe the equilibrium thermodynamic and transport properties of [BMIM][BF4] ionic liquid. The temperature dependence of ion diffusion, conductivity, dielectric constant, dipole relaxation time and viscosity have been observed and found similar behavior to those of supercooled liquid. The ion diffusion on graphite surfaces and under nanoconfinement was found to be higher compared to those in bulk.

Mani Biswas, Mousumi

2011-12-01T23:59:59.000Z

313

Ionic Liquids as Novel Lubricants and /or Lubricant Additives  

SciTech Connect

This ORNL-GM CRADA developed ionic liquids (ILs) as novel lubricants or oil additives for engine lubrication. A new group of oil-miscible ILs have been designed and synthesized with high thermal stability, non-corrosiveness, excellent wettability, and most importantly effective anti-scuffing/anti-wear and friction reduction characteristics. Mechanistic analysis attributes the superior lubricating performance of IL additives to their physical and chemical interactions with metallic surfaces. Working with a leading lubricant formulation company, the team has successfully developed a prototype low-viscosity engine oil using a phosphonium-phosphate IL as an anti-wear additive. Tribological bench tests of the IL-additized formulated oil showed 20-33% lower friction in mixed and elastohydrodynamic lubrication and 38-92% lower wear in boundary lubrication when compared with commercial Mobil 1 and Mobil Clean 5W-30 engine oils. High-temperature, high load (HTHL) full-size engine tests confirmed the excellent anti-wear performance for the IL-additized engine oil. Sequence VID engine dynamometer tests demonstrated an improved fuel economy by >2% for this IL-additized engine oil benchmarked against the Mobil 1 5W-30 oil. In addition, accelerated catalyst aging tests suggest that the IL additive may potentially have less adverse impact on three-way catalysts compared to the conventional ZDDP. Follow-on research is needed for further development and optimization of IL chemistry and oil formulation to fully meet ILSAC GF-5 specifications and further enhance the automotive engine efficiency and durability.

Qu, J. [ORNL] [ORNL; Viola, M. B. [General Motors Company] [General Motors Company

2013-10-31T23:59:59.000Z

314

Degradation of Ionic Pathway in PEM Fuel Cell Cathode  

SciTech Connect

The degradation of the ionic pathway throughout the catalyst layer in proton exchange membrane fuel cells was studied under an accelerated stress test of catalyst support (potential hold at 1.2 V). Electrochemical behaviors of the cathode based on graphitic mesoporous carbon supported Pt catalyst were examined using electrochemical impedance spectroscopy and cyclic voltammetry. Impedance data were plotted and expressed in the complex capacitance form to determine useful parameters in the transmission line model: the double-layer capacitance, peak frequency, and ionic resistance. Electrochemical surface area and hydrogen crossover current through the membrane were estimated from cyclic voltammogram, while cathode Faradaic resistance was compared with ionic resistance as a function of test time. It was observed that during an accelerated stress test of catalyst support, graphitic mesoporous carbon becomes hydrophilic which increases interfacial area between the ionomer and the catalyst up to 100 h. However, the ionic resistance in the catalyst layer drastically increases after 100 h with further carbon support oxidation. The underlying mechanism has been studied and it was found that significant degradation of ionic pathway throughout the catalyst layer due to catalyst support corrosion induces uneven hydration and mechanical stress in the ionomer.

Park, Seh Kyu; Shao, Yuyan; Wan, Haiying; Viswanathan, Vilayanur V.; Towne, Silas A.; Rieke, Peter C.; Liu, Jun; Wang, Yong

2011-11-12T23:59:59.000Z

315

Building Energy Software Tools Directory: Cold Room Calc  

NLE Websites -- All DOE Office Websites (Extended Search)

skills helpful but not required. Users More than 200 around the world. Audience Cold room design engineers, refrigeration equipment suppliers and contractors, owners of...

316

A holistic investigation of complexity sources in nuclear power plant control rooms  

E-Print Network (OSTI)

The nuclear power community in the United States is moving to modernize aging power plant control rooms as well as develop control rooms for new reactors. New generation control rooms, along with modernized control rooms, ...

Sasangohar, Farzan

2011-01-01T23:59:59.000Z

317

Ionic Liquids and Ionizing Radiation: Reactivity of Highly Energetic  

NLE Websites -- All DOE Office Websites (Extended Search)

Ionizing Radiation: Reactivity of Highly Energetic Ionizing Radiation: Reactivity of Highly Energetic Species James F. Wishart J. Phys. Chem. Lett. 1, 3225-3231 (2010). [Find paper at ACS Publications] or use ACS Articles on Request View the video on this Perspective article at The Journal of Physical Chemistry Letters (5:03) Selected for the ACS Special Virtual Issue on Ionic Liquids (March 2011). Abstract: Due to their unique properties, ionic liquids present many opportunities for basic research on the interactions of radiation with materials under conditions not previously available. At the same time, there are practical applied reasons for characterizing, understanding, and being able to predict how ionic-liquid-based devices and industrial-scale systems will perform under conditions of extreme reactivity, including radiation. This

318

Bicyclic imidazolium ionic liquids as potential electrolytes for rechargeable lithium ion batteries  

Science Conference Proceedings (OSTI)

A bicyclic imidazolium ionic liquids, 1-ethyl-2,3-trimethyleneimidazolium bis(tri fluoromethane sulfonyl)imide ([ETMIm][TFSI]), and reference imidazolium compounds, 1-ethyl-3-methylimidazolium bis(trifluoromethane sulfonyl)imide ([EMIm][TFSI]) and 1, 2-dimethyl-3-butylimidazolium bis(trifluoromethane sulfonyl)imide ([DMBIm][TFSI]), were synthesized and investigated as solvents for lithium ion batteries. Although the alkylation at the C-2 position of the imidazolium ring does not affect the thermal stability of the ionic liquids, with or without the presence of 0.5 molar lithium bis(trifluoromethane sulfonyl)imide (LiTFSI), the stereochemical structure of the molecules has shown profound influences on the electrochemical properties of the corresponding ionic liquids. [ETMIm][TFSI] shows better reduction stability than do [EMIm][TFSI] and [DMBIm][TFSI], as confirmed by both linear sweep voltammery (LSV) and theoretical calculation. The Li||Li cell impedance of 0.5M LiTFSI/[ETMIm][TFSI] is stabilized, whereas that of 0.5M LiTFSI/[DMBIm][TFSI] is still fluctuating after 20 hours, indicating a relatively stable solid electrolyte interphase (SEI) is formed in the former. Furthermore, the Li||graphite half-cell based on 0.5M LiTFSI/[BTMIm][TFSI] exhibits reversible capacity of 250mAh g-1 and 70mAh g-1 at 25 C, which increases to 330 mAh g-1 and 250 mAh g-1 at 50 C, under the current rate of C/20 and C/10, respectively. For comparison, the Li||graphite half-cell based on 0.5M LiTFSI/[DMBIm][TFSI] exhibits poor capacity retention under the same current rate at both temperatures.

Liao, Chen [ORNL; Shao, Nan [ORNL; Bell, Jason R [ORNL; Guo, Bingkun [ORNL; Luo, Huimin [ORNL; Jiang, Deen [ORNL; Dai, Sheng [ORNL

2013-01-01T23:59:59.000Z

319

Composite mixed oxide ionic and electronic conductors for hydrogen separation  

DOE Patents (OSTI)

A mixed ionic and electronic conducting membrane includes a two-phase solid state ceramic composite, wherein the first phase comprises an oxygen ion conductor and the second phase comprises an n-type electronically conductive oxide, wherein the electronically conductive oxide is stable at an oxygen partial pressure as low as 10.sup.-20 atm and has an electronic conductivity of at least 1 S/cm. A hydrogen separation system and related methods using the mixed ionic and electronic conducting membrane are described.

Gopalan, Srikanth (Westborough, MA); Pal, Uday B. (Dover, MA); Karthikeyan, Annamalai (Quincy, MA); Hengdong, Cui (Allston, MA)

2009-09-15T23:59:59.000Z

320

Physical Education Building Building Room Material Amount Percentage Priority Action  

E-Print Network (OSTI)

Physical Education Building Building Room Material Amount Percentage Priority Action Phys Ed Level Mechanical Insulation 250 LF 70.00 P6 Manage Phys Ed Level 1 East PE1H2 Pipe Fitting Mud 6 each 85.00 P5 #12;Building Room Material Amount Percentage Priority Action Phys Ed Level 2 West PE200 Pipe Fitting

Seldin, Jonathan P.

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Service Building 4 Building Room Material Amount Percentage Priority Action  

E-Print Network (OSTI)

Service Building 4 Building Room Material Amount Percentage Priority Action Service Building 4 S160 65 sqft 15.00 P5 Manage S1J74 Friday, February 18, 2011 Page 1 of 2 #12;Building Room Material Amount Manage Mechanical Insulation 100 LF 55.00 P5 Manage Service Buliding 4 S16H6A Gypsum Wallboard Joint

Seldin, Jonathan P.

322

ENERGY STAR Qualified Room Air Conditioners | Data.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

Room Air Conditioners Room Air Conditioners Consumer Data Apps Challenges Resources About Blogs Let's Talk Feedback Consumer You are here Data.gov » Communities » Consumer » Data ENERGY STAR Qualified Room Air Conditioners Dataset Summary Description Room Air Conditioners that have earned the ENERGY STAR are more efficient than standard models. ENERGY STAR is the trusted symbol for energy efficiency helping consumers save money and protect the environment through energy-efficient products and practices. More information on ENERGY STAR is available at www.energystar.gov. Tags {"Room Air Conditioners","Energy Star",products,"energy efficiency",efficient,"greenhouse gas emissions",climate,utility,utilities,household,savings,labels,partners,certification}

323

Building Energy Software Tools Directory: Room Air Conditioner Cost  

NLE Websites -- All DOE Office Websites (Extended Search)

Room Air Conditioner Cost Estimator Room Air Conditioner Cost Estimator Screen capture of Room Air Conditioner Cost Estimator The cost estimator compares high-efficiency room air conditioners to standard equipment in terms of life cycle cost. It provides an alternative to complicated building simulation models, while offering more precision than simplified estimating tools that are commonly available. The cost estimator assists decision-making regarding the purchase or replacement of room air conditioning equipment, by estimating a product�s lifetime energy cost savings at various efficiency levels. Screen Shots Keywords air conditioner, life-cycle cost, energy performance, residential buildings, energy savings Validation/Testing Internal reviews at Pacific Northwest National Laboratory.

324

Reversible Ionic Liquids as Double-Action Solvents for Efficient CO2 Capture  

SciTech Connect

We have developed a novel class of CO{sub 2} capture solvents, Reversible Ionic Liquids (RevILs), that offer high absorption capacity through two modes of capture: chemical reaction (chemisorption) and physical solubility (physisorption). These solvents are silicon containing alkaline compounds such as silylamines that form a liquid salt (ionic liquid) upon reaction with CO{sub 2}. Subsequently, modest elevations in temperature reverse the reaction and yield pure CO{sub 2} for sequestration. By incorporating Si in the molecules we have reduced the viscosity, thereby improving the mass transfer rates of CO{sub 2} absorption/desorption and decreasing the processing costs for pumping the solvent. In this project, we have made systematic changes to the structure of these compounds to improve several physical and thermodynamic properties important for CO{sub 2} capture. Through these structure-property paradigms, we have obtained a RevIL which requires only a third of the energy required by conventional aqueous MEA process for 90% CO{sub 2} capture.

Eckert, Charles; Liotta, Charles

2011-09-30T23:59:59.000Z

325

Reversible Ionic Liquids as Double-Action Solvents for Efficient CO{sub 2} Capture  

SciTech Connect

We have developed a novel class of CO{sub 2} capture solvents, Reversible Ionic Liquids (RevILs), that offer high absorption capacity through two modes of capture: chemical reaction (chemisorption) and physical solubility (physisorption). These solvents are silicon containing alkaline compounds such as silylamines that form a liquid salt (ionic liquid) upon reaction with CO{sub 2}. Subsequently, modest elevations in temperature reverse the reaction and yield pure CO{sub 2} for sequestration. By incorporating Si in the molecules we have reduced the viscosity, thereby improving the mass transfer rates of CO{sub 2} absorption/desorption and decreasing the processing costs for pumping the solvent. In this project, we have made systematic changes to the structure of these compounds to improve several physical and thermodynamic properties important for CO{sub 2} capture. Through these structure-property paradigms, we have obtained a RevIL which requires only a third of the energy required by conventional aqueous MEA process for 90% CO{sub 2} capture.

Charles Eckert; Charles Liotta

2011-09-30T23:59:59.000Z

326

Polyhedral Ionic Molecules Alexander I. Boldyrev and Jack Simons*  

E-Print Network (OSTI)

of Chemistry, The UniVersity of Utah, Salt Lake City, Utah 84112 ReceiVed NoVember 25, 1996. ReVised Manuscript species composed of closed-shell atomic ions are known to prefer densely packed structures similar, for example, in alkali halide tetramers, no other ionic polyhedral structures containing only atomic ions

Simons, Jack

327

High performance ultracapacitors with carbon nanomaterials and ionic liquids  

DOE Patents (OSTI)

The present invention is directed to the use of carbon nanotubes and/or electrolyte structures in various electrochemical devices, such as ultracapacitors having an ionic liquid electrolyte. The carbon nanotubes are preferably aligned carbon nanotubes. Compared to randomly entangled carbon nanotubes, aligned carbon nanotubes can have better defined pore structures and higher specific surface areas.

Lu, Wen; Henry, Kent Douglas

2012-10-09T23:59:59.000Z

328

High performance batteries with carbon nanomaterials and ionic liquids  

SciTech Connect

The present invention is directed to lithium-ion batteries in general and more particularly to lithium-ion batteries based on aligned graphene ribbon anodes, V.sub.2O.sub.5 graphene ribbon composite cathodes, and ionic liquid electrolytes. The lithium-ion batteries have excellent performance metrics of cell voltages, energy densities, and power densities.

Lu, Wen (Littleton, CO)

2012-08-07T23:59:59.000Z

329

EXPERIMENTAL INVESTIGATION OF NATURAL CONVECTION HEAT TRANSFER OF IONIC LIQUID IN A RECTANGULAR ENCLOSURE HEATED FROM BELOW  

Science Conference Proceedings (OSTI)

This paper presents an experimental study of natural convection heat transfer for an Ionic Liquid. The experiments were performed for 1-butyl-2, 3-dimethylimidazolium bis(trifluoromethylsulfonyl)imide, ([C{sub 4}mmim][NTf{sub 2}]) at a Raleigh number range of 1.26 x 10{sup 7} to 8.3 x 10{sup 7}. In addition to determining the convective heat transfer coefficients, this study also included experimental determination of thermophysical properties of [C{sub 4}mmim][NTf{sub 2}] such as, density, viscosity, heat capacity, and thermal conductivity. The results show that the density of [C{sub 4}mmim][NTf{sub 2}] varies from 1.437-1.396 g/cm{sup 3} within the temperature range of 10-50 C, the thermal conductivity varies from 0.105-0.116 W/m.K between a temperature of 10 to 60 C, the heat capacity varies from 1.015 J/g.K - 1.760 J/g.K within temperature range of 25-340 C and the viscosity varies from 18cp-243cp within temperature range 10-75 C. The results for density, thermal conductivity, heat capacity, and viscosity were in close agreement with the values in the literature. Measured dimensionless Nusselt number was observed to be higher for the ionic liquid than that of DI water. This is expected as Nusselt number is the ratio of heat transfer by convection to conduction and the ionic liquid has lower thermal conductivity (approximately 18%) than DI water.

Fox, E.; Visser, A.; Bridges, N.

2011-07-18T23:59:59.000Z

330

Monitoring radioactive xenon gas in room air using activated charcoal  

SciTech Connect

A method for monitoring room air for radioactive xenon gas is described. It uses activated charcoal vials, a vacuum source and a well-type scintillation counter. The method may be adapted for detection and identification of any radioactive gas excluding those with ultra-short half-lives. Sampling room air during xenon-133 ({sup 133}Xe) ventilation lung studies was performed using this technique. The results show that low concentrations of {sup 133}Xe in room air can be reliably detected and that staff exposure to {sup 133}Xe at this institution was within ICRP recommendations.

Langford, J.; Thompson, G. (Princess Margaret Hospital for Children, Perth (Australia) Sir Charles Gairdner Hospital, Perth (Australia))

1990-03-01T23:59:59.000Z

331

How much sense do room occupancy sensor controls make  

SciTech Connect

Hotel operators are faced with a confusing array of both remote and local guest room energy control devices. A wide variety of decentralized electronic room controllers, each with its own control logic and vendor claims are in competition with remote front desk microprocessor controls which are essentially ''blind'' to actual occupancy. This paper is a review of the characteristics of various controllers, their behaviour with different in-room environmental equipment, and guest reactions to the potpourri of available devices.

Becker, H.P.

1986-01-01T23:59:59.000Z

332

Attendee Introduction  

NLE Websites -- All DOE Office Websites (Extended Search)

2 selectivity could significantly reduce cost of post-combustion carbon capture from flue gas Room-temperature ionic liquids (RTILs) are attractive materials due to high...

333

Can Ionic Liquids Be Used As Templating Agents For Controlled Design of Uranium-Containing Nanomaterials?  

SciTech Connect

Nanostructured uranium oxides have been prepared in ionic liquids as templating agents. Using the ionic liquids as reaction media for inorganic nanomaterials takes advantage of the pre-organized structure of the ionic liquids which in turn controls the morphology of the inorganic nanomaterials. Variation of ionic liquid cation structure was investigated to determine the impact on the uranium oxide morphologies. For two ionic liquid cations, increasing the alkyl chain length increases the aspect ratio of the resulting nanostructured oxides. Understanding the resulting metal oxide morphologies could enhance fuel stability and design.

Visser, A.; Bridges, N.; Tosten, M.

2013-04-09T23:59:59.000Z

334

Investigation of transport and mechnical properties for hollow fibers containing ionic liquids for pre-combustion CO2 capture  

SciTech Connect

Currently available techniques for CO{sub 2} separation from flue or fuel gas cannot economically capture CO{sub 2} for sequestration. Membranes offer several advantages in CO{sub 2} separation such as simple operation, low water consumption, and in some cases higher energy efficiency. However, traditional polymer membranes are limited by the separation characteristics of the polymer and often suffer from low permeability and selectivity. Several research groups have attempted to overcome these limitations by using supported ionic liquid membranes (SILMs) in which an ionic liquid (IL) is suspended within the pores of a membrane support and serves as the active gas separation component of the membrane. For industrial applications, hollow fibers are preferred over flat membranes due to their smaller footprint, ease of high efficiency module design and low fabrication cost. In an attempt to investigate and address these issues, polymeric hollow fiber-based ionic liquid membranes were fabricated. Matrimid® and [hmim][Tf{sub 2}N] (1-hexyl-3-methylimidalzolium bis(trifluoromethyl sulfonyl) imide) were selected as the polymeric and ionic liquid materials, and the fibers were fabricated via nonsolvent-induced phase separation/extraction, employing a single layer spinneret extrusion system. The system takes advantage of the fiber morphology to enable more efficient mass transfer than traditional membranes geometries. CO{sub 2} and H{sub 2} transport properties will be reported for the Matrimid hollow fibers from 37 to 150 {degrees}C. Also, several mechanical properties such as tensile strength, modulus, and glass transition temperature have been measured for the fiber using dynamic mechanical analysis.

Hopkinson, D., Wickramanayake, S., Myers, C., Sui, L., Nicola, M., Luebke, D.

2011-01-01T23:59:59.000Z

335

WIPP Reaches Milestone „ First Disposal Room Filled  

NLE Websites -- All DOE Office Websites (Extended Search)

WIPP Reaches Milestone - First Disposal Room Filled CARLSBAD, N.M., September 4, 2001 - The U.S. Department of Energy's (DOE) Carlsbad Field Office today announced that Room 7 of Panel 1 at the Waste Isolation Pilot Plant (WIPP), the first underground room used for disposal operations, has been filled to capacity with transuranic waste. The milestone was reached at about 3:30 p.m. on August 24, as Waste Handling personnel emplaced a shipment of waste from the Idaho National Engineering and Environmental Laboratory. On August 25, Underground Operations personnel completed installation of a chain link mesh barrier and cloth drape across the entrance to the room to officially declare the area "closed." The first shipment of waste, which came

336

Dorm Room Idea Now Revolutionizing Energy | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Dorm Room Idea Now Revolutionizing Energy Dorm Room Idea Now Revolutionizing Energy Dorm Room Idea Now Revolutionizing Energy April 16, 2010 - 11:07am Addthis Joshua DeLung What does this project do? Princeton Power Systems is currently installing a 200-kW solar array and advanced battery system on company grounds to provide clean power to its building and to showcase advancements in renewable energy technology to businesses, municipalities and utilities that may be curious about renewable energy projects. While many college students might spend their time playing Ultimate Frisbee or enjoying the nightlife, Darren Hammell and several other Princeton University classmates transformed an idea fostered in a dorm room into one of the fastest-growing businesses in the energy industry, creating jobs and

337

Virtual Reading Room prior to 2000 | National Nuclear Security  

National Nuclear Security Administration (NNSA)

prior to 2000 | National Nuclear Security prior to 2000 | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog Virtual Reading Room prior to 2000 Home > About Us > Our Operations > NNSA Office of General Counsel > Freedom of Information Act (FOIA) > Virtual Reading Room prior to 2000 Virtual Reading Room prior to 2000 Printer-friendly version Printer-friendly version

338

Covered Product Category: Room Air Conditioners | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Room Air Conditioners Room Air Conditioners Covered Product Category: Room Air Conditioners October 7, 2013 - 10:40am Addthis ENERGY STAR Qualified Products FEMP provides acquisition guidance across a variety of product categories, including room air conditioners, which are an ENERGY STAR®-qualified product category. Federal laws and executive orders mandate that agencies meet these efficiency requirements in all procurement and acquisition actions that are not specifically exempted by law. Most manufacturers display the ENERGY STAR label on complying models. For a model not displaying this label, check the manufacturer's literature to determine if it meets the efficiency requirements outlined by ENERGY STAR. Performance Requirements for Federal Purchases For the most up-to-date efficiency levels required by ENERGY STAR, look for

339

Demonstration of Intelligent Control and Fan Improvements in Computer Room  

NLE Websites -- All DOE Office Websites (Extended Search)

Demonstration of Intelligent Control and Fan Improvements in Computer Room Demonstration of Intelligent Control and Fan Improvements in Computer Room Air Handlers Title Demonstration of Intelligent Control and Fan Improvements in Computer Room Air Handlers Publication Type Report Refereed Designation Unknown LBNL Report Number LBNL-6007E Year of Publication 2012 Authors Coles, Henry C., Steve E. Greenberg, and Corrine Vita Document Number LBNL-6007E Date Published 12/2012 Publisher Lawrence Berkeley National Laboratory City Berkeley, CA Keywords air distribution, building technology and urban systems department, computer room air handler, crah control, data center, data center crah, ec fan, ecm, ecm fan, fan speed control, high tech and industrial systems group, plug fan, variable frequency drive, vfd, wireless control Abstract

340

Covered Product Category: Room Air Conditioners | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Room Air Conditioners Room Air Conditioners Covered Product Category: Room Air Conditioners October 7, 2013 - 10:40am Addthis ENERGY STAR Qualified Products FEMP provides acquisition guidance across a variety of product categories, including room air conditioners, which are an ENERGY STAR®-qualified product category. Federal laws and executive orders mandate that agencies meet these efficiency requirements in all procurement and acquisition actions that are not specifically exempted by law. Most manufacturers display the ENERGY STAR label on complying models. For a model not displaying this label, check the manufacturer's literature to determine if it meets the efficiency requirements outlined by ENERGY STAR. Performance Requirements for Federal Purchases For the most up-to-date efficiency levels required by ENERGY STAR, look for

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

MODELING OF HEAT TRANSFER IN ROOMS IN THE MODELICA  

NLE Websites -- All DOE Office Websites (Extended Search)

MODELING MODELING OF HEAT TRANSFER IN ROOMS IN THE MODELICA "BUILDINGS" LIBRARY Michael Wetter, Wangda Zuo, Thierry Stephane Nouidui Simulation Research Group, Building Technologies Department Environmental Energy Technologies Division, Lawrence Berkeley National Laboratory Berkeley, CA 94720, USA ABSTRACT This paper describes the implementation of the room heat transfer model in the free open-source Modelica "Buildings" library. The model can be used as a single room or to compose a multizone building model. We discuss how the model is de- composed into submodels for the individual heat transfer phenomena. We also discuss the main physical assumptions. The room model can be parameterized to use di↵erent modeling assump- tions, leading to linear or non-linear di↵erential algebraic systems of equations. We present nu- merical experiments that show

342

Press Room - U.S. Energy Information Administration (EIA)  

U.S. Energy Information Administration (EIA)

Search EIA.gov. A-Z Index; A-Z Index A B C D E F G H I J K L M N O P Q R S T U V W XYZ. Press Room. Glossary ...

343

Design of a multisystem remote maintenance control room  

SciTech Connect

The Remote Systems Development Section of the Consolidated Fuel Reprocessing Program at the Oak Ridge National Laboratory (ORNL) and Japan's Power Reactor and Nuclear Fuel Development Corporation (PNC) recently collaborated in the development of a control room concept for remote operations. This report describes design methods and the resulting control room concept. The design project included five stages. The first was compilation of a complete function list; functions are tasks performed by operators in the control room while operating equipment located in the remote area. The second step was organization of the function list into ''function groups;'' function groups are sets of functions that operate one piece of equipment. The third stage was determination of crew size and requirements for supervision. The fourth stage was development of conceptual designs of displays and controls. The fifth stage was development of plans for placement of crew stations within the control room. 5 figs., 1 tab.

Draper, J.V.; Handel, S.J.; Kring, C.T.; Kawatsuma, S.

1988-01-01T23:59:59.000Z

344

Jeremiah Holzbauer Michigan State University Bldg. 401, Room...  

NLE Websites -- All DOE Office Websites (Extended Search)

Jeremiah Holzbauer Michigan State University Bldg. 401, Room B-4100 Wednesday February 8, 1:30 pm Host: Ali Nassiri The Beams and Applications Seminar Series For more information...

345

Grid Support for Collaborative Control Room in Fusion Science  

Science Conference Proceedings (OSTI)

The National Fusion Collaboratory project seeks to enable fusion scientists to exploit Grid capabilities in support of experimental science. To this end we are exploring the concept of a collaborative control room that harnesses Grid and collaborative ...

K. Keahey; M. E. Papka; Q. Peng; D. Schissel; G. Abla; T. Araki; J. Burruss; E. Feibush; P. Lane; S. Klasky; T. Leggett; D. Mccune; L. Randerson

2005-10-01T23:59:59.000Z

346

NETL: NewsRoom - This Week at NETL  

NLE Websites -- All DOE Office Websites (Extended Search)

NewsRoom This Week at NETL 2013 October September August July October 15, 2013 October 7, 2013 September 30, 2013 September 23, 2013 September 16, 2013 September 9, 2013 September...

347

Second Panel of Disposal Rooms Completed in WIPP Underground  

NLE Websites -- All DOE Office Websites (Extended Search)

Isolation Pilot Plant P.O. Box 3090 Carlsbad, New Mexico 88221 DOENews -2- Underground waste disposal panels are arranged in parallel sets of seven rooms each. Each set of seven...

348

Variable Speed Fan Retrofits for Computer Room Air Conditioners  

NLE Websites -- All DOE Office Websites (Extended Search)

Variable-Speed Fan Retrofits for Computer-Room Air Conditioners Prepared for the U.S. Department of Energy Federal Energy Management Program Technology Case Study Bulletin By...

349

Five ENERGY STAR Room Air Conditioners Fail Testing  

Energy.gov (U.S. Department of Energy (DOE))

The U.S. Department of Energy's Office of Enforcement announced today that DOE testing has identified five Friedrich room air conditioners that do not meet the ENERGY STAR Program’s energy...

350

Virtual Reading Room after to 2000 | National Nuclear Security  

National Nuclear Security Administration (NNSA)

after to 2000 | National Nuclear Security after to 2000 | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog Virtual Reading Room after to 2000 Home > About Us > Our Operations > NNSA Office of General Counsel > Freedom of Information Act (FOIA) > Virtual Reading Room after to 2000 Virtual Reading Room after to 2000 Printer-friendly version Printer-friendly version

351

How the Number and Placement of Sensors Controlling Room Air Distribution Systems Affect Energy Use and Comfort  

E-Print Network (OSTI)

This study assesses the impact of sensor number and placement on the energy needed to condition a typical office using several likely variants of an underfloor air distribution system (UFAD). The study uses an empirical-based room stratification model developed from full-scale tests of UFAD systems. Annual energy consumption is calculated for an interior zone using outside air temperature bin data. The comfort criteria are taken from ASHRAE standard 55-92. The simulations indicate that there are benefits derived from using more than one temperature sensor to control conditions in the occupied zone of a room. Among these are: 1. By adjusting both supply air temperature and volume to maintain the maximum allowable thermal gradient in the occupied (lower) part of the room, an optimal supply air condition can reduce energy use (relative to the best arrangement of a single sensor) while maintaining comfort; 2. Discomfort caused by stratification can be detected by having one of the sensors located at foot level; 3. For the simulated UFAD interior zone of a typical office building in Sacramento, an overall energy saving of 8%/24% (VAV/CAV respectively) can be achieved when two sensors as opposed to one are used to control room conditions.

Wang, D.; Arens, E.; Webster, T.; Shi, M.

2002-01-01T23:59:59.000Z

352

Tertiary Containment in a Multi-Room Tritium Facility  

SciTech Connect

An experimental system to provide tertiary containment at Mound has been upgraded to support a new multi-room tritium handling facility. This system is used to remove tritium from room air in the event of primary (process) and secondary (glovebox) containment failure. The upgraded system includes a faster response time, piping and valves that are more leaktight, and a new control panel that better indicates the system status and operating conditions.

Kent, L. R.

1985-04-01T23:59:59.000Z

353

How (and where) to book rooms This guide will tell you how and where to book rooms and spaces in the Students'  

E-Print Network (OSTI)

How (and where) to book rooms This guide will tell you how and where to book rooms and spaces are completely FREE to use for societies and committees. All you need is a current Room Booking Card to show per society/committee). If you want a valid room booking card for the academic year 12/13 you MUST

Dixon, Peter

354

Strain effects on the ionic conductivity of Y-doped ceria: A simulation study  

E-Print Network (OSTI)

In this paper we report a computational study of the effects of strain on the conductivity of Y-doped ceria (YDC). This material was chosen as it is of technological interest in the field of Solid Oxide Fuel Cells (SOFCs). The simulations were performed under realistic operational temperatures and strain (\\epsilon) levels. For bulk and thin film YDC, the results show that tensile strain leads to conductivity enhancements of up to 3.5x and 1.44x, respectively. The magnitude of these enhancements is in agreement with recent experimental and computational evidence. In addition, the methods presented herein allowed us to identify enhanced ionic conductivity in the surface regions of YDC slabs and its anisotropic character.

Burbano, Mario; Watson, Graeme W

2013-01-01T23:59:59.000Z

355

Using a Research Simulator for Validating Control Room Modernization Concepts  

SciTech Connect

The Light Water Reactor Sustainability Program is a research, development, and deployment program sponsored by the United States Department of Energy. The program is operated in close collaboration with industry research and development programs to provide the technical foundations for licensing and managing the long-term, safe, and economical operation of nuclear power plants that are currently in operation. Advanced instrumentation and control (I&C) technologies are needed to support the continued safe and reliable production of power from nuclear energy systems during sustained periods of operation up to and beyond their expected licensed lifetime. This requires that new capabilities to achieve process control be developed and eventually implemented in existing nuclear control rooms. It also requires that approaches be developed and proven to achieve sustainability of I&C systems throughout the period of extended operation. Idaho National Laboratory (INL) is working closely with nuclear utilities to develop technologies and solutions to help ensure the safe life extension of current reactors. One of the main areas of focus is control room modernization. Current analog control rooms are growing obsolete, and it is difficult for utilities to maintain them. Using its reconfigurable control room simulator adapted from a training simulator, INL serves as a neutral test bed for implementing new control room system technologies and assisting in control room modernization efforts across.

Ronald L. Boring; Vivek Agarwal; Julius J. Persensky; Jeffrey C. Joe

2012-05-01T23:59:59.000Z

356

Ionically Conducting Membranes for Hydrogen Production and Separation  

NLE Websites -- All DOE Office Websites (Extended Search)

IONICALLY CONDUCTING MEMBRANES IONICALLY CONDUCTING MEMBRANES FOR HYDROGEN PRODUCTION AND SEPARATION Presented by Tony Sammells Eltron Research Inc. Boulder, Colorado www.eltronresearch.com Presented at DOE Hydrogen Separations Workshop Arlington, Virginia September 8, 2004 ELTRON RESEARCH INC. TO BE DISCUSSED * Membranes for Hydrogen Production - Compositions - Feedstocks - Performance - Key Technical Hurdles * Membranes for Hydrogen Separation - Compositions - Ex Situ vs. In Situ WGS - Performance - Key Technical Hurdles ELTRON RESEARCH INC. OVERALL SCHEME FOR CONVERTING FEEDSTOCK TO HYDROGEN WITH SIMULTANEOUS CARBON DIOXIDE SEQUESTRATION Oxygen Transport Membrane Hydrogen Transport Membrane Natural Gas Coal Biomass Syngas CO/H 2 WGS H 2 O CO 2 /H 2 1618afs.dsf H 2 CO 2 ELTRON RESEARCH INC. INCENTIVES FOR OXYGEN TRANSPORT MEMBRANES FOR

357

Carbon films produced from ionic liquid carbon precursors  

Science Conference Proceedings (OSTI)

The invention is directed to a method for producing a film of porous carbon, the method comprising carbonizing a film of an ionic liquid, wherein the ionic liquid has the general formula (X.sup.+a).sub.x(Y.sup.-b).sub.y, wherein the variables a and b are, independently, non-zero integers, and the subscript variables x and y are, independently, non-zero integers, such that ax=by, and at least one of X.sup.+ and Y.sup.- possesses at least one carbon-nitrogen unsaturated bond. The invention is also directed to a composition comprising a porous carbon film possessing a nitrogen content of at least 10 atom %.

Dai, Sheng; Luo, Huimin; Lee, Je Seung

2013-11-05T23:59:59.000Z

358

Extraordinarily Efficient Conduction in a Redox-Active Ionic Liquid  

E-Print Network (OSTI)

Iodine added to iodide-based ionic liquids leads to extraordinarily efficient charge transport, vastly exceeding that expected for such viscous systems. Using terahertz time-domain spectroscopy, in conjunction with dc conductivity, diffusivity and viscosity measurements we unravel the conductivity pathways in 1-methyl-3-propylimidazolium iodide melts. This study presents evidence of the Grotthuss mechanism as a significant contributor to the conductivity, and provides new insights into ion pairing processes as well as the formation of polyiodides. The terahertz and transport results are reunited in a model providing a quantitative description of the conduction by physical diffusion and the Grotthuss bond-exchange process. These novel results are important for the fundamental understanding of conduction in molten salts and for applications where ionic liquids are used as charge-transporting media such as in batteries and dye-sensitized solar cells.

Verner K. Thorsmølle; Guido Rothenberger; Daniel Topgaard; Jan C. Brauer; Dai-Bin Kuang; Shaik M. Zakeeruddin; Björn Lindman; Michael Grätzel; Jacques-E. Moser

2010-11-09T23:59:59.000Z

359

MINOR ACTINIDE SEPARATIONS USING ION EXCHANGERS OR IONIC LIQUIDS  

SciTech Connect

This project seeks to determine if (1) inorganic-based ion exchange materials or (2) electrochemical methods in ionic liquids can be exploited to provide effective Am and Cm separations. Specifically, we seek to understand the fundamental structural and chemical factors responsible for the selectivity of inorganic-based ion-exchange materials for actinide and lanthanide ions. Furthermore, we seek to determine whether ionic liquids can serve as the electrolyte that would enable formation of higher oxidation states of Am and other actinides. Experiments indicated that pH, presence of complexants and Am oxidation state exhibit significant influence on the uptake of actinides and lanthanides by layered sodium titanate and hybrid zirconium and tin phosphonate ion exchangers. The affinity of the ion exchangers increased with increasing pH. Greater selectivity among Ln(III) ions with sodium titanate materials occurs at a pH close to the isoelectric potential of the ion exchanger. The addition of DTPA decreased uptake of Am and Ln, whereas the addition of TPEN generally increases uptake of Am and Ln ions by sodium titanate. Testing confirmed two different methods for producing Am(IV) by oxidation of Am(III) in ionic liquids (ILs). Experimental results suggest that the unique coordination environment of ionic liquids inhibits the direct electrochemical oxidation of Am(III). The non-coordinating environment increases the oxidation potential to a higher value, while making it difficult to remove the inner coordination of water. Both confirmed cases of Am(IV) were from the in-situ formation of strong chemical oxidizers.

Hobbs, D.; Visser, A.; Bridges, N.

2011-09-20T23:59:59.000Z

360

ARIEL: automatic wi-fi based room fingerprinting for indoor localization  

Science Conference Proceedings (OSTI)

People spend the majority of their time indoors, and human indoor activities are strongly correlated with the rooms they are in. Room localization, which identifies the room a person or mobile phone is in, provides a powerful tool for characterizing ...

Yifei Jiang; Xin Pan; Kun Li; Qin Lv; Robert P. Dick; Michael Hannigan; Li Shang

2012-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Temperature induced immiscibility in the NaCl?H[subscript 2]O system at high pressure  

SciTech Connect

High-pressure polymorphs of H{sub 2}O are a major component in many outer planets, extra solar bodies, and icy satellites. This study sought to examine the influence of ionic impurities on the phase stability, thermal expansion, and melting curve of ice VII. Powder diffraction patterns of ice VII formed from pure H{sub 2}O and 5 wt.% NaCl aqueous solutions were taken at room temperature up to 11.1 {+-} 0.3 and 26.6 {+-} 0.4 GPa, respectively. Thermal expansions, {alpha}, of all ice VII samples were recorded and modeled up to the melting point of the samples. Ice VII formed from a NaCl-bearing aqueous solution at pressures greater than 2.2 GPa and less than 500 K can be indexed by ice VII only, whereas at temperatures greater than 500 K, diffraction lines indicative of halite (NaCl) are observed and become more intense with increasing temperature and only disappear at the melting point of the high-pressure ice. This phenomenon was observed in all NaCl-bearing ice samples that were heated to greater than 500 K. The melting curves of ice VII formed from pure H{sub 2}O and a 5 wt.% NaCl aqueous solution suggest that the presence of Na{sup +} and Cl{sup -} in the ice VII structure results in a depression of the melting curve by approximately 40 K. The exsolution of halite from the NaCl-doped ice VII and the depression of the ice VII melting curve suggest that the presence of ionic impurities in ice VII may promote the formation of a self-segregating zone deep within ice-rich bodies. This zone could initiate the formation of solute-rich melt pockets that may ascend toward the surface and result in surface manifestations such as solute-bearing aqueous vents, unexplained domes/diapirism, and/or salt-rich regions.

Frank, M.R.; Scott, H.P.; Maglio, S.J.; Prakapenka, V.B.; Shen, G. (NIU); (CIW); (UC); (Indiana)

2008-10-09T23:59:59.000Z

362

Pilot Study: Measurement of Room Illuminance to Assess Automatic Brightness  

NLE Websites -- All DOE Office Websites (Extended Search)

Study: Measurement of Room Illuminance to Assess Automatic Brightness Study: Measurement of Room Illuminance to Assess Automatic Brightness Control in Televisions Title Pilot Study: Measurement of Room Illuminance to Assess Automatic Brightness Control in Televisions Publication Type Conference Proceedings Year of Publication 2012 Authors Greenblatt, Jeffery B., Mia Forbes Pirie, Louis-Benoit Desroches, Sally M. Donovan, Clancy Donnelly, Craig Billingsley, and Chris Calwell Pagination 13 Date Published August 12 Conference Location Berkeley Abstract Automatic brightness control (ABC) is an increasingly common feature found in newtelevisions (TVs) and computer monitors. ABC is intended to adjust TV screen brightness(luminance) according to the ambient light level (room illuminance). When implementedcorrectly, this can both reduce energy consumption and improve viewing quality. The currentENERGY STAR test procedure provides for a more favorable energy use rating for TVs withABC, by measuring power consumption at two light levels (0 and 300 lux) and reporting aweighted-average energy use. However, this and other studies suggest that these levels are notrepresentative of actual TV viewing conditions.As there were currently only limited data available concerning room illuminance, weundertook a small pilot study in 2011 to begin to answer two key questions: 1. To what extent doroom illuminance levels vary depending on the location of measurement (e.g., center of theroom, on the couch, or at the TV)? 2. What room illuminance conditions are prevalent whenpeople watch TV?We measured room illuminance in the homes of nine volunteers in California andColorado to begin addressing the above two questions. Although the study had the usualdrawbacks of a pilot (limited sample size, time duration, etc.), it has, nonetheless, yielded usefulresults. The study shows definitively that there is large variability between measurements madeat different locations in the room and, therefore, that location of room illuminance measurementsis critical. Moreover, the majority (over 75%) of TV viewing occurred at illuminance levels ofless than 50 lux (though measurements of up to several hundred lux were also recorded), a resultthat was consistent with subsequent larger-scale studies. This type of information can helpdetermine how ABC-enabled TVs should be tested to best represent actual viewing conditions.

363

When Emergency Rooms Close: Ambulance Diversion in the West San Fernando Valley  

E-Print Network (OSTI)

Multiple critical patients APP: When Emergency Rooms Closeparamedics sit in a crowded emergency room. 16 These waitsS. Chan. “The effect of emergency department crowding on

Natasha Mihal; Renee Moilanen

2005-01-01T23:59:59.000Z

364

Review of Dynamic Recovery Effects on Ion Irradiation Damage in Ionic-Covalent Materials  

SciTech Connect

Single crystalline samples of highly ionic Ca2La8(SiO4)6O2 and covalent 6H–SiC have been irradiated with different ions/energies to study the effects of dose, temperature, damage-energy density, and in-cascade ionization rate on the dynamics of irradiation-induced amorphization. Above temperatures of 100–150 K, the dose for complete amorphization, D, increases with temperature in a single stage and exhibits a strong dependence on the ratio of in-cascade recovery to displacement cross sections, ?r/?d. A fit of a dynamic model for amorphization to these data indicates that irradiation-induced dynamicrecovery occurs with an activation energy of 0.15 ± 0.02 and 0.12 ± 0.01 eV for Ca2La8(SiO4)6O2 and 6H–SiC, respectively. Analysis of these data reveals that ionization processes are the dominant contributor to in-cascade recovery in Ca2La8(SiO4)6O2; while in 6H–SiC, ionization processes are less dominant.

Weber, William J.; Zhang, Yanwen; Wang, Lumin M.

2012-04-05T23:59:59.000Z

365

Community Activity Room (CAR) Painter, Version 4.0  

Science Conference Proceedings (OSTI)

The CAR V4 software visualizes transmission congestion and grid reliability in both a two-dimensional painting and a three-dimension rendering of walls enclosing a Community Activity Room. EPRI developed the concept of the Community Activity Room in the spring of 2002. It was implemented in the CAR Painter software. A demonstration software was issued in September 2002. In April, 2004, version 2.0 was released with many features added to the CAR Painter, including a 3-D visualization module. Version 3.0 ...

2005-11-30T23:59:59.000Z

366

Lithium Super-Ionic Sulfide Carbon (LiSISC) Composite for Li-S ...  

Lithium Super-Ionic Sulfide Carbon (LiSISC) Composite for Li-S Batteries Note: The technology described above is an early stage opportunity. Licensing ...

367

Electrochemical comparison and deposition of lithium and potassium from phosphonium- and ammonium-tfsi ionic liquids .  

E-Print Network (OSTI)

??In this work, ionic liquids (ILs) were investigated for use as battery electrolytes. The ILs were synthesized from quaternary ammonium and phosphonium salts and TFSI-.… (more)

Vega, Jose A.

2009-01-01T23:59:59.000Z

368

Ionic Liquid Materials as Gas Chromatography Stationary Phases and Sorbent Coatings in Solid-Phase Microextraction.  

E-Print Network (OSTI)

??Ionic liquids (ILs) are a class of molten salts with melting points below 100 °C. Their unique properties including high thermal stability, wide viscosity range,… (more)

Zhao, Qichao

2011-01-01T23:59:59.000Z

369

Investigating the Effects of Radiation on Phosphonium-Based Ionic Liquids.  

E-Print Network (OSTI)

??This thesis presents work on the understanding of the effects of ionizing radiation on phosphonium-based ionic liquids (ILs). The capability of ILs to dissolve a… (more)

Howett, Susan

2013-01-01T23:59:59.000Z

370

High CO2 Solubility, Permeability and Selectivity in Ionic Liquids with the Tetracyanoborate Anion  

SciTech Connect

Five different ionic liquids containing the tetracyanoborate anion were synthesized and evaluated for CO2 separation performance. Measured CO2 solubility values were exceptionally high compared to analogous ionic liquids with different anions and ranged from 0.128 mol L-1 atm-1 to 0.148 mol L-1 atm-1. In addition, CO2 permeability and CO2/N2 selectivity values were measured using a supported ionic liquid membrane architecture and the separations performance of the ionic liquid membranes exceeded the Robeson upper bound. These results establish the distinct potential of the tetracyanoborate, [B(CN)4], anion for the separation of CO2.

Mahurin, Shannon Mark [ORNL; Hillesheim, Patrick C [ORNL; Yeary, Joshua S [ORNL; Jiang, Deen [ORNL; Dai, Sheng [ORNL

2012-01-01T23:59:59.000Z

371

Recent developments in high-temperature photonic crystals for energy conversion  

E-Print Network (OSTI)

After decades of intense studies focused on cryogenic and room temperature nanophotonics, scientific interest is also growing in high-temperature nanophotonics aimed at solid-state energy conversion. These latest extensive ...

Rinnerbauer, Veronika

372

A New Method of Metal Temperature Estimation for Service-Run ...  

Science Conference Proceedings (OSTI)

phase fields between room temperature and 1200ºC. The largest changes ... beta phase depletion over the temperature range 865ºC to 1050ºC have shown that ...

373

An analysis of the impact of datacenter temperature on energy efficiency  

E-Print Network (OSTI)

The optimal air temperature for datacenters is one of ways to improve energy efficiency of datacenter cooling systems. Many datacenter owners have been interested in raising the room temperature as a quick and simple method ...

Lee, Heechang

2012-01-01T23:59:59.000Z

374

Room-temperature fuel cells and their integration into portable and embedded systems  

Science Conference Proceedings (OSTI)

Direct methanol fuel cells (DMFCs) are a promising nextgeneration energy source for portable applications, due to their high energy density and the ease of handling of the liquid fuel. However, the limited range of output power obtainable from a fuel ...

Naehyuck Chang; Jueun Seo; Donghwa Shin; Younghyun Kim

2010-01-01T23:59:59.000Z

375

Quantitative room-temperature mineralization of airborne formaldehyde using manganese oxide catalysts  

E-Print Network (OSTI)

extent of mineralization Carbon dioxide levels produced as athe formation of carbon dioxide and water. The concentrationformaldehyde and carbon dioxide concentrations were recorded

Sidheswaran, Meera A.

2012-01-01T23:59:59.000Z

376

Room Temperature Magneto-caloric Effect In Fe Substituted Ni-Mn ...  

Science Conference Proceedings (OSTI)

Bonded Magnetocaloric Powders for the Refrigeration Application · Coercivity ... Industrial Needs and Applications for Soft Magnetic Materials · Industrial ...

377

Electrodeposition of cobalt and cobalt-aluminum alloys from a room temperature chloroaluminate molten salt  

Science Conference Proceedings (OSTI)

The electrodeposition of magnetic cobalt-aluminum alloys was investigated in the Lewis acidic aluminum chloride-1-methyl-3-ethylimidazolium chloride [60.0--40.0 mole percent (m/o)] molten salt containing electrogenerated Co(II) at 25 C. rotating disk electrode voltammetry indicated that it is possible to produce alloy deposits containing up to 62 atomic (a/o) aluminum at potentials positive of that for the bulk deposition of aluminum. The onset of the underpotential-driven aluminum codeposition process occurred at around 0.40 V vs. the Al/Al(III) couple in a 5.00 mmol/liter Co(II) solution but decreased as the Co(II) concentration increased. The Co-Al alloy composition displayed an inverse dependence on the Co(II) concentration but tended to become independent of concentration as the potential was decreased to 0 V. A rotating ring-disk electrode voltammetry technique was developed to analyze the composition and structure of the Co-Al alloy deposits. This technique takes advantage of the fact that the mass-transport-limited reduction of cobalt(II) occurs at potentials considerably more positive than that at which aluminum codeposition occurs. Scanning electron microscopy and energy dispersive X-ray analysis of bulk electrodeposits revealed that deposit morphology depends strongly upon aluminum content/deposition potential; deposits produced at 0.40 V from 50.0 mmol/liter Co(II) solutions consisted of 10 to 20 {micro}m diam multifaceted nodules of pure hcp cobalt, whereas those obtained at 0.20 V were dense and fine grained, containing about 4 a/o Al. Deposits produced at 0 V had the visual appearance of a loosely adherent black powder. X-ray diffraction measurements revealed a lattice expansion and a decrease in grain size as the hcp cobalt was alloyed with increasing amounts of aluminum.

Mitchell, J.A.; Pitner, W.R.; Hussey, C.L. [Univ. of Mississippi, University, MS (United States). Dept. of Chemistry; Stafford, G.R. [National Inst. of Standards and Technology, Gaithersburg, MD (United States). Materials Science and Engineering Lab.

1996-11-01T23:59:59.000Z

378

Short-Term Solubility of Eight Alloys Circulating in Mercury at Room Temperature  

E-Print Network (OSTI)

on the alloy. To make the posttest mass measurements, those samples that were compatible with nitric acid were briefly rinsed in 8N nitric acid, washed in water and alcohol, and then dried. This was not possible in Table 2. Although the copper and aluminum experienced considerable mass loss due to dissolution

McDonald, Kirk

379

Room temperature study of a strain-induced electronic superstructure on a magnetite (111) surface  

E-Print Network (OSTI)

A magnetite (Fe3O4) single crystal (111) surface has been studied at various oxygen-iron surface stoichiometries. The stoichiometry was modified by controlling the in-situ sample anneal conditions. We have found the conditions that lead to the formation of an oxygen-rich surface that forms a quasi-hexagonal superstructure with a 42A periodicity. The superstructure is highly regular and was observed by both LEED and STM. The superstructure consists of three regions, two of which have identical atomic scale structures with a periodicity of 2.8A, and a third having a periodicity that is about 10% larger (3.1A). The subtle difference in the atomic periodicities between the three areas results from the modulation of intrinsic strain developed along the surface. The superstructure results from electronic effects rather than being a mosaic of different iron oxide terminations. The onset of the superstructure is sensitive to the surface stoichiometry. From our results we could estimate the critical density of defects leading to the disappearance of the superstructure. We have modelled the experimental results and calculated the electron density using a DFT algorithm. The model clearly shows the development of strain along the surface.

N. Berdunov; S. Murphy; G. Mariotto; I. V. Shvets

2004-03-09T23:59:59.000Z

380

Studies of Room Temperature Accelerator Structures for the ILC Positron Source  

SciTech Connect

There are many challenges in the design of the normal-conducting portion of the ILC positron injector system such as achieving adequate cooling with the high RF and particle loss heating, and sustaining high accelerator gradients during millisecond-long pulses in a strong magnetic field. The proposed design for the positron injector contains both standing-wave and traveling-wave L-band accelerator structures for high RF efficiency, low cost and ease of fabrication. This paper presents results from several studies including particle energy deposition for both undulator based and conventional positron sources, cooling system design, accelerator structure optimization, RF pulse heating, cavity frequency stabilization, and RF feed system design.

Wang, J.W.; Adolphsen, C.; Bharadwaj, V.; Bowden, G.B.; Dolgashev, V.A.; Jones, R.M.; Jongewaard, E.N.; Lewandowski, J.R.; Li, Z.; Miller, R.H.; /SLAC

2006-03-15T23:59:59.000Z

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Characterization of Thallium Bromide (TlBr) for Room Temperature Radiation Detectors  

E-Print Network (OSTI)

1.1 Motivation: Radiation Detection for HomelandSecurity . . . . . . . . . . 1.2 Semiconductor Radiationand related features of radiation ionization energies in

Smith, Holland McTyeire

2013-01-01T23:59:59.000Z

382

Crystal structure of graphite under room-temperature compression and decompression  

Science Conference Proceedings (OSTI)

Recently, sophisticated theoretical computational studies have proposed several new crystal structures of carbon (e.g., bct-C{sub 4}, H-, M-, R-, S-, W-, and Z-carbon). However, until now, there lacked experimental evidence to verify the predicted high-pressure structures for cold-compressed elemental carbon at least up to 50 GPa. Here we present direct experimental evidence that this enigmatic high-pressure structure is currently only consistent with M-carbon, one of the proposed carbon structures. Furthermore, we show that this phase transition is extremely sluggish, which led to the observed broad x-ray diffraction peaks in previous studies and hindered the proper identification of the post-graphite phase in cold-compressed carbon.

Wang, Yuejian; Panzik, Joseph E.; Kiefer, Boris; Lee, Kanani K.M. (Yale); (New Mexico State)

2012-10-23T23:59:59.000Z

383

The role of hydrogen in room-temperature ferromagnetism at graphite surfaces  

E-Print Network (OSTI)

and stimulating discussions. SSRL and ALS are national userO?ce of Basic Energy Sciences. SSRL is operated by Stanford

Ohldag, H.

2011-01-01T23:59:59.000Z

384

ANL/APS/TB-19 A Finite Element Analysis of Room Temperature Silicon...  

NLE Websites -- All DOE Office Websites (Extended Search)

M. Mills Contents I. Introduction 1 II. Parameters Used for FEA Calculations 2 A. The heat transfer coefficient 2 B. Materials properties 3 III. The Bending Magnet...

385

MANUFACTURER OF THE FIRST 100% ROOM TEMPERATURE nc-Si SOLAR PV ...  

Nanoparticle quantum conf. Monolithic printed layers. Sintering min. ~400 ºC. PV Effic.: 5 – 19%. Economic Advantages ...

386

Atomic magnetic gradiometer for room temperature high sensitivity magnetic field detection  

DOE Patents (OSTI)

A laser-based atomic magnetometer (LBAM) apparatus measures magnetic fields, comprising: a plurality of polarization detector cells to detect magnetic fields; a laser source optically coupled to the polarization detector cells; and a signal detector that measures the laser source after being coupled to the polarization detector cells, which may be alkali cells. A single polarization cell may be used for nuclear magnetic resonance (NMR) by prepolarizing the nuclear spins of an analyte, encoding spectroscopic and/or spatial information, and detecting NMR signals from the analyte with a laser-based atomic magnetometer to form NMR spectra and/or magnetic resonance images (MRI). There is no need of a magnetic field or cryogenics in the detection step, as it is detected through the LBAM.

Xu,Shoujun (Berkeley, CA); Lowery, Thomas L. (Belmont, MA); Budker, Dmitry (El Cerrito, CA); Yashchuk, Valeriy V. (Richmond, CA); Wemmer, David E. (Berkeley, CA); Pines, Alexander (Berkeley, CA)

2009-08-11T23:59:59.000Z

387

Experimental Results in the Comparison of Search Algorithms Used with Room Temperature Detectors  

Science Conference Proceedings (OSTI)

Analysis of time sequence data was run for several higher resolution scintillation detectors using a variety of search algorithms, and results were obtained in predicting the relative performance for these detectors, which included a slightly superior performance by CeBr{sub 3}. Analysis of several search algorithms shows that inclusion of the RSPRT methodology can improve sensitivity.

Guss, P., Yuan, D., Cutler, M., Beller, D.

2010-11-01T23:59:59.000Z

388

Patient/Family Waiting Room Analysis For Susquehanna Health's  

E-Print Network (OSTI)

for WRMC against others in the industry, the team found that the industry average cost was $1.57 per square objectives included measuring the square footage of the waiting rooms, researching utility costs, utilization foot. This value is less than the WRMC maintenance costs, so the team provided recommendations

Demirel, Melik C.

389

Information Foraging in Nuclear Power Plant Control Rooms  

SciTech Connect

nformation foraging theory articulates the role of the human as an 'informavore' that seeks information and follows optimal foraging strategies (i.e., the 'information scent') to find meaningful information. This paper briefly reviews the findings from information foraging theory outside the nuclear domain and then discusses the types of information foraging strategies operators employ for normal and off-normal operations in the control room. For example, operators may employ a predatory 'wolf' strategy of hunting for information in the face of a plant upset. However, during routine operations, the operators may employ a trapping 'spider' strategy of waiting for relevant indicators to appear. This delineation corresponds to information pull and push strategies, respectively. No studies have been conducted to determine explicitly the characteristics of a control room interface that is optimized for both push and pull information foraging strategies, nor has there been empirical work to validate operator performance when transitioning between push and pull strategies. This paper explores examples of control room operators as wolves vs. spiders and con- cludes by proposing a set of research questions to investigate information foraging in control room settings.

R.L. Boring

2011-09-01T23:59:59.000Z

390

Measurement of Absorption in Rooms with Sound Absorbing Ceilings  

Science Conference Proceedings (OSTI)

Serious difficulties have been encountered in attempts to measure the absorption coefficients of sound absorbing ceilings in large offices. An analysis of the sound field is made and it is concluded (1) that the reverberation time formula is usually invalid if the absorption is concentrated on one surface of the room

J. R. Power

1938-01-01T23:59:59.000Z

391

Science Career & Cooperative Education Burke Science Building Room 127  

E-Print Network (OSTI)

Science Career & Cooperative Education Burke Science Building Room 127 www.science event. Visit the SCCE website to find event dates and details: www.science.mcmaster.ca/scce Attend a Co visit: www.science.mcmaster.ca/scce Enroll in SCIENCE 2C00 to learn the skills for career success

Hitchcock, Adam P.

392

Press Room - Testimony - U.S. Energy Information Administration (EIA)  

U.S. Energy Information Administration (EIA)

A B C D E F G H I J K L M N O P Q R S T U V W XYZ. Press Room. ... Subcommittee on Energy Committee on Science, Space and Technology U.S. House of Representatives ...

393

FUEL HANDLING FACILITY BACKUP CENTRAL COMMUNICATIONS ROOM SPACE REQUIREMENTS CALCULATION  

SciTech Connect

The purpose of the Fuel Handling Facility Backup Central Communications Room Space Requirements Calculation is to determine a preliminary estimate of the space required to house the backup central communications room in the Fuel Handling Facility (FHF). This room provides backup communications capability to the primary communication systems located in the Central Control Center Facility. This calculation will help guide FHF designers in allocating adequate space for communications system equipment in the FHF. This is a preliminary calculation determining preliminary estimates based on the assumptions listed in Section 4. As such, there are currently no limitations on the use of this preliminary calculation. The calculations contained in this document were developed by Design and Engineering and are intended solely for the use of Design and Engineering in its work regarding the FHF Backup Central Communications Room Space Requirements. Yucca Mountain Project personnel from Design and Engineering should be consulted before the use of the calculations for purposes other than those stated herein or use by individuals other than authorized personnel in Design and Engineering.

B. SZALEWSKI

2005-03-22T23:59:59.000Z

394

China Energy Efficiency Round Robin Testing Results for Room  

E-Print Network (OSTI)

LBNL-3502E China Energy Efficiency Round Robin Testing Results for Room Air Conditioners Nan Zhou Round Robin Testing Results and Analysis by China National Institute of Standardization..................................................................................................................... 1 I.1.1 China's Energy Constraint Problem and the Need to Improve the Energy Efficiency of Energy

395

Golden Sections of Interatomic Distances as Exact Ionic Radii and Additivity of Atomic and Ionic Radii in Chemical Bonds  

E-Print Network (OSTI)

The Golden ratio which appears in the geometry of a variety of creations in Nature is found to arise right in the Bohr radius of the hydrogen atom due to the opposite charges of the electron and proton. The bond length of the hydrogen molecule is the diagonal of a square on the Bohr radius and hence also has two Golden sections, which form the cationic and anionic radii of hydrogen. It is shown here that these radii account for the bond lengths of many hydrides when added to the atomic and Golden ratio based ionic radii of many other atoms.

Raji Heyrovska

2009-02-06T23:59:59.000Z

396

Airflow Simulation and Energy Analysis in Ventilated Room with a New Type of Air Conditioning  

E-Print Network (OSTI)

Airflow simulation in one ventilated room with radiant heating and natural ventilation has been carried out. Three cases are compared: the closed room, the room with full openings, and the room with small openings. The radiator heating room with small openings is recommended. The airflow and thermal comfort are discussed for the last case. It is suitable for two kinds of civil buildings, housing buildings and office buildings, which take up the largest part of all functional buildings.

Liu, D.; Tang, G.; Zhao, F.

2006-01-01T23:59:59.000Z

397

Interactions of Ionic Liquids with Uranium and its Bioreduction  

Science Conference Proceedings (OSTI)

We investigated the influence of ionic liquids (ILs) 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM]{sup +}[PF{sub 6}]{sup -}, N-ethylpyridinium trifluoroacetate [EtPy]{sup +}[CF{sub 3}COO]{sup -} and N-ethylpyridinium tetrafluoroborate [Et-Py]{sup +}[BF{sub 4}]{sup -} on uranium reduction by Clostridium sp. under anaerobic conditions. Potentiometric titration, UV-vis spectrophotometry, LC-MS and EXAFS analyses showed monodentate complexation between uranyl and BF{sub 4}{sup -} PF{sub 6}{sup -}; and bidentate complexation with CF{sub 3}COO{sup -}. Ionic liquids affected the growth of Clostridium sp. as evidenced by decrease in optical density, changes in pH, gas production, and the extent of U(VI) reduction and precipitation of U(IV) from solution. Reduction of U(VI) to U(IV) was observed in the presence of [EtPy][BF{sub 4}] and [BMIM][PF{sub 6}] but not with [EtPy][CF{sub 3}COO].

Zhang, C.; Francis, A.

2012-09-18T23:59:59.000Z

398

Separation of gases with solid electrolyte ionic conductors  

DOE Green Energy (OSTI)

The authors have developed a novel method of gas separation based on electrolyte ionic membrane technology. Separation of one gas from another occurs through an ion-conducting membrane by the passage of selected ions. Most systems studied have focused on oxygen ion conduction for the separation of oxygen from air, although protonic and halide-conducting solid materials also exist. As an example of this system, this paper concentrates on a study of a membrane reactor used in the production of syngas (CO + H{sub 2}) from methane. The membrane material is a modified perovskite-type oxide exhibiting mixed (electronic/ionic) conductivity. Mixed-conductivity oxides are promising materials for oxygen-permeating membranes that can operate without electrodes or external electrical circuitry. Extruded tubes of this material have been evaluated in a reactor operating at {approx} 850 C for partial oxidation of methane into syngas in the presence of a reforming catalyst. Separated oxygen on one side of the reactor wall was obtained from air on the other side. Methane conversion efficiencies of > 99% were observed, and some of the reactor tubes have been operated for > 1,000 h. Membrane tubes were fabricated from calcined powders by a plastic extrusion technique. Characterization of the mechanical, physical, and chemical properties of this material confirmed the stability exhibited in the reactor.

Balachandran, U.; Dusek, J.T.; Maiya, P.S.; Mieville, R.L.; Ma, B. [Argonne National Lab., IL (United States); Kleefisch, M.S.; Udovich, C.A. [Amoco Exploration and Production, Naperville, IL (United States)

1996-11-01T23:59:59.000Z

399

Using Ionic Liquids in Selective Hydrocarbon Conversion Processes  

DOE Green Energy (OSTI)

This is the Final Report of the five-year project Using Ionic Liquids in Selective Hydrocarbon Conversion Processes (DE-FC36-04GO14276, July 1, 2004- June 30, 2009), in which we present our major accomplishments with detailed descriptions of our experimental and theoretical efforts. Upon the successful conduction of this project, we have followed our proposed breakdown work structure completing most of the technical tasks. Finally, we have developed and demonstrated several optimized homogenously catalytic methane conversion systems involving applications of novel ionic liquids, which present much more superior performance than the Catalytica system (the best-to-date system) in terms of three times higher reaction rates and longer catalysts lifetime and much stronger resistance to water deactivation. We have developed in-depth mechanistic understandings on the complicated chemistry involved in homogenously catalytic methane oxidation as well as developed the unique yet effective experimental protocols (reactors, analytical tools and screening methodologies) for achieving a highly efficient yet economically feasible and environmentally friendly catalytic methane conversion system. The most important findings have been published, patented as well as reported to DOE in this Final Report and our 20 Quarterly Reports.

Tang, Yongchun; Periana, Roy; Chen, Weiqun; van Duin, Adri; Nielsen, Robert; Shuler, Patrick; Ma, Qisheng; Blanco, Mario; Li, Zaiwei; Oxgaard, Jonas; Cheng, Jihong; Cheung, Sam; Pudar, Sanja

2009-09-28T23:59:59.000Z

400

AGING EFFECTS ON THE PROPERTIES OF IMIDAZOLIUM, QUATERNARY AMMONIUM, PYRIDINIUM AND PYRROLIDINIUM-BASED IONIC LIQUIDS USED IN FUEL AND ENERGY PRODUCTION  

Science Conference Proceedings (OSTI)

Ionic liquids are often cited for their excellent thermal stability, a key property for their use as solvents and in the chemical processing of biofuels. However, there has been little supporting data on the long term aging effect of temperature on these materials. Imizadolium, quaternary ammonium, pyridinium, and pyrrolidnium-based ionic liquids with the bis(trifluoromethylsulfonyl)imide and bis(perfluoroethylsulfonyl)imide anions were aged for 2520 hours (15 weeks) at 200?C in air to determine the effects of an oxidizing environment on their chemical structure and thermal stability over time. It was found that the minor changes in the cation chemistry could greatly affect the properties of the ILs over time.

Fox, E.

2013-08-13T23:59:59.000Z

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

The Fluctuations of Blocked Ionic Current Reveal the Instantaneous Statuses of DNA in Graphene Nanopore  

E-Print Network (OSTI)

Extracting the sequence information of DNA from the blocked ionic current is the crucial step of the ionic current-based nanopore sequencing approaches. The thinnest graphene nanopore, which contained only one layer of carbon atoms, potentially has ultra-high DNA sequencing sensitivity. However, the dynamical translocation information of DNA contained in the blocked ionic current has not been well understood to date. In this letter, an assessment to the sensitivity of ionic current-based graphene nanopore DNA sensing approach was carried out using molecular dynamics simulations. By filtering the molecular thermal motion induced noise of ionic current, we found that the instantaneous conformational variations of DNA in graphene nanopore could be revealed from the fluctuations of the denoised ionic current. However, the blockage of ionic current which induced by the proximity of the DNA base-pairs to the nanopore (within 1.5 nm) was also observed. Although the expected single-base resolution of graphene nanopore should be enhanced by further studies, our findings indicated that the ionic current-based graphene nanopore sensing approach has high sensitivity to the instantaneous translocation status of DNA.

Wenping Lv; Ren'an Wu

2013-02-15T23:59:59.000Z

402

NETL: IEP – Post-Combustion CO2 Emissions Control - Ionic Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

Ionic Liquids Ionic Liquids Project No.: FC26-07NT43091 Model of CO2 absorption by an ionic liquid. Model of CO2 absorption by an IL. The model shows that the anions are controlling absorption in ILs. The green units represent anions and the grey units represent cations. The University of Notre Dame is conducting the Ionic Liquids: Breakthrough Absorption Technology for Post-Combustion CO2 Capture project (FC26-07NT43091), that builds on the work of its earlier project (FG26-04NT42122), to provide a comprehensive evaluation of the feasibility of using a novel class of compounds - ionic liquids (ILs) - for the capture of carbon dioxide (CO2) from the flue gas of coal-fired power plants. Initial efforts focused on "proof-of-concept" exploration, followed by a laboratory-/bench-scale effort. ILs include a broad category

403

The radiation chemistry of ionic liquids and its implications for their use  

NLE Websites -- All DOE Office Websites (Extended Search)

radiation chemistry of ionic liquids and its implications for their use radiation chemistry of ionic liquids and its implications for their use in nuclear fuel processing J. F. Wishart and I. A. Shkrob in "Ionic Liquids: From Knowledge to Application" Rogers, R. D., Plechkova, N. V., and Seddon, K. R., Eds.; ACS Symp. Ser. 1030, Ch. 8, American Chemical Society, Washington, DC, 2009, pp 119-134. (ISBN 978-0-8412-6997-2) [Find chapter at ACS Publications] Abstract: Using ionic liquids as a medium for the processing of spent nuclear fuel, where their safety and process improvement advantages could be significant, promises to substantially contribute to the development of advanced nuclear fuel cycles to improve the world's energy posture. It is therefore important to study the radiation chemistry of ionic liquids, to determine

404

Press Room - Radio - U.S. Energy Information Administration (EIA)  

U.S. Energy Information Administration (EIA) Indexed Site

Press Room Press Room Glossary › FAQS › Overview Press Releases Testimony Presentations Radio Events Radio Spots Ready-to-broadcast news stories. Transcripts provided so radio spots can be re-recorded in whole or in part. Residential heating oil prices virtually unchanged mp3 Date: December 18, 2013 Description: The average retail price for home heating oil fell 4-tenths of a penny from a week ago to $3.95 per gallon. That's down 8-tenths of a penny from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region rose 3.92 per gallon, up 3-tenths of a cent from last week, and up 3 cents from a year ago. Contact/Author: Amerine Woodyard, 202-586-1256 Transcript: http://www.eia.gov/radio/transcript/heating_oil_prices_12182013.pdf

405

List of Room Air Conditioners Incentives | Open Energy Information  

Open Energy Info (EERE)

Conditioners Incentives Conditioners Incentives Jump to: navigation, search The following contains the list of 112 Room Air Conditioners Incentives. CSV (rows 1 - 112) Incentive Incentive Type Place Applicable Sector Eligible Technologies Active AEP Ohio - Commercial New Construction Energy Efficiency Rebate Program (Ohio) Utility Rebate Program Ohio Commercial Industrial Local Government Municipal Utility Nonprofit Schools State Government Central Air conditioners Chillers Comprehensive Measures/Whole Building Custom/Others pending approval Energy Mgmt. Systems/Building Controls Heat pumps Lighting Lighting Controls/Sensors Motor VFDs Motors Water Heaters Commercial Cooking Equipment Commercial Refrigeration Equipment Room Air Conditioners Yes Alexandria Light and Power - Residential Energy Efficiency Rebate Program (Minnesota) Utility Rebate Program Minnesota Residential Central Air conditioners

406

Press Room - U.S. Energy Information Administration (EIA)  

U.S. Energy Information Administration (EIA) Indexed Site

Press Room Press Room Glossary › FAQS › Overview Press Releases Testimony Presentations Radio Events Press Releases State Energy Profiles enhanced and renewables sections added December 19, 2013 Growing oil and natural gas production continues to reshape the U.S. energy economy December 16, 2013 MEDIA ADVISORY: EIA to Release Updated Energy Forecasts to 2040 December 4, 2013 EIA initiates new monthly Drilling Productivity Report October 22, 2013 More press releases... Congressional Testimony U.S. petroleum supply system pdf Subject: EIA, Petroleum Presented by: Adam Sieminski, Administrator Presented to: Committee on Energy and Natural Resources U.S. Senate Washington, DC-July 16, 2013 Renewable Fuel Standard (RFS) program pdf Subject: EIA, Renewable, Forecasts Presented by: Adam Sieminski, Administrator

407

Sorption of organic gases in a furnished room  

NLE Websites -- All DOE Office Websites (Extended Search)

a furnished room a furnished room Title Sorption of organic gases in a furnished room Publication Type Journal Article LBNL Report Number LBNL-53943 Year of Publication 2004 Authors Singer, Brett C., Kenneth L. Revzan, Toshifumi Hotchi, Alfred T. Hodgson, and Nancy J. Brown Journal Atmospheric Environment Volume 38 Start Page Chapter Issue 16 Pagination 2483-2494 Abstract We present experimental data and semi-empirical models describing the sorption of organic gases in a simulated indoor residential environment. Two replicate experiments were conducted with 20 volatile organic compounds (VOCs) in a 50-m3 room finished with painted wallboard, carpet and cushion, draperies and furnishings. The VOCs span a wide volatility range and include ten Hazardous Air Pollutants. VOCs were introduced to the static chamber as a pulse and their gas-phase concentrations were measured during a net adsorption period and a subsequent net desorption period. Three sorption models were fit to the measured concentrations for each compound to determine the simplest formulation needed to adequately describe the observed behavior. Sorption parameter values were determined by fitting the models to adsorption period data then checked by comparing measured and predicted behavior during desorption. The adequacy of each model was evaluated using a goodness of fit parameter calculated for each period. Results indicate that sorption usually does not greatly affect indoor concentrations of methyl-tert-butyl ether, 2-butanone, isoprene and benzene. In contrast, sorption appears to be a relevant indoor process for many of the VOCs studied, including C8-C10 aromatic hydrocarbons (HC), terpenes, and pyridine. These compounds sorbed at rates close to typical residential air change rates and exhibited substantial sorptive partitioning at equilibrium. Polycyclic aromatic HCs, aromatic alcohols, ethenylpyridine and nicotine initially adsorbed to surfaces at rates of 1.5 to >6 h-1 and partitioned 95 to >99% in the sorbed phase at equilibrium

408

Room Air Conditioning Energy Efficiency and Demand Response Potential  

Science Conference Proceedings (OSTI)

Room or window air conditioners are a common appliance in parts of the United States residential sector for providing summertime cooling. The technology is based on the same vapor compression cycle common in central air conditioning and refrigeration applications, but with all system components in one enclosure, which is generally small and comparatively inexpensive. The systems are simple and modular enough to be installed by the homeowner, and can be installed in windows without major modification, or ...

2011-06-30T23:59:59.000Z

409

Community Activity Room (CAR) Code, Demo Version 1.0  

Science Conference Proceedings (OSTI)

Examining a computer image akin to a weather map, transmission system operators are now able to visualize congestion on the high voltage power lines that make up our nation's massive regional electricity grids. The multi-dimensional image, which represents power market activities, is made possible by a new software tool called the Community Activity Room, or CAR (TM). The colorful graphic shows the current state of wholesale power transactions and their effect on the reliability of an interconnected powe...

2002-09-10T23:59:59.000Z

410

OSU WEBVIEWER PROVIDING WEB BASED ACCESS TO ROOM SCHEDULING INFORMATION  

E-Print Network (OSTI)

for a specific room. You can also search for an event name. For example, entering ANTH will display all and the starting date of next term's CS 419 course. You'll notice there is no way to filter this search by date be ignored. If we want all 400 level CS courses, we just enter "cs 4". SPACE QUICK SEARCH OR LOOKUP You can

Escher, Christine

411

Effect of H{sub 2}O on the desulfurization of simulated flue gas by an ionic liquid  

SciTech Connect

Functionalized ionic liquids (ILs) have been demonstrated to absorb SO{sub 2} from mixed gases or simulated flue gases efficiently. However, after absorbing a large amount of SO{sub 2}, the viscosity of the ILs increases greatly, which might limit their eventual applications in large-scale desulfurization from mixed gases or flue gases. In this work, the effect of the presence of water in a simulated flue gas on the absorption of SO{sub 2} by a functionalized ionic liquid, 1,1,3,3-tetramethylguanidinium lactate, has been studied at different temperatures. It is found that the presence of water in the simulated flue gas can decrease the viscosity of the IL greatly, and it has no effect on the absorptivity of SO{sub 2} from the flue gas. The densities of the IL absorbing SO{sub 2} from the flue gas with or without water are also studied. They increase with the increase of the amount of SO{sub 2} absorbed from the flue gas in both cases.

Ren, S.H.; Hou, Y.C.; Wu, W.Z.; Chen, X.T.; Fan, J.L.; Zhang, J.W. [Beijing University of Chemical Technology, Beijing (China)

2009-05-15T23:59:59.000Z

412

Multiphysics simulation of corona discharge induced ionic wind  

E-Print Network (OSTI)

Ionic wind devices or electrostatic fluid accelerators are becoming of increasing interest as tools for thermal management, in particular for semiconductor devices. In this work, we present a numerical model for predicting the performance of such devices, whose main benefit is the ability to accurately predict the amount of charge injected at the corona electrode. Our multiphysics numerical model consists of a highly nonlinear strongly coupled set of PDEs including the Navier-Stokes equations for fluid flow, Poisson's equation for electrostatic potential, charge continuity and heat transfer equations. To solve this system we employ a staggered solution algorithm that generalizes Gummel's algorithm for charge transport in semiconductors. Predictions of our simulations are validated by comparison with experimental measurements and are shown to closely match. Finally, our simulation tool is used to estimate the effectiveness of the design of an electrohydrodynamic cooling apparatus for power electronics applicat...

Cagnoni, Davide; Christen, Thomas; de Falco, Carlo; Parolini, Nicola; Stevanovi?, Ivica

2013-01-01T23:59:59.000Z

413

Low temperature high density Si3N4 MIM capacitor technology for MMMIC and RF-MEMs applications  

Science Conference Proceedings (OSTI)

In this work, a novel, high quality, high-density, deposited at room temperature ultra thin 5 nm Si3N4 metal insulator metal (MIM) capacitor process for monolithic millimetre-wave integrated circuit (MMMIC) applications ... Keywords: RF MEMs, RF MIM capacitors, dielectric films, high density capacitors, room temperature ultra thin silicon nitride films metal insulator metal capacitors

K. Elgaid; H. Zhou; C. D. W. Wilkinson; I. G. Thayne

2004-06-01T23:59:59.000Z

414

Radiance Temperature  

Science Conference Proceedings (OSTI)

... Temperature using Detectors Calibrated for Absolute Spectral Power Response, HW ... A Third Generation Water Bath Based Blackbody Source, JB ...

2013-06-27T23:59:59.000Z

415

Tobacco smoke aging in the presence of ozone: a room-sized chamber...  

NLE Websites -- All DOE Office Websites (Extended Search)

Tobacco smoke aging in the presence of ozone: a room-sized chamber study Title Tobacco smoke aging in the presence of ozone: a room-sized chamber study Publication Type Journal...

416

Modeling of Heat Transfer in Rooms in the Modelica Buildings Library  

E-Print Network (OSTI)

for convective and radiative heat transfer yielded a twofoldModeling of Heat Transfer in Rooms in the Modelica “of California. MODELING OF HEAT TRANSFER IN ROOMS IN THE

Wetter, Michael

2013-01-01T23:59:59.000Z

417

How do operators monitor a complex, dynamic work domain? The impact of control room technology  

Science Conference Proceedings (OSTI)

Keywords: cognitive engineering, control rooms, human-machine interface, monitoring, nuclear power plants, process control, supervisory control

2001-06-01T23:59:59.000Z

418

INFORMATION INTEGRATION IN CONTROL ROOMS AND TECHNICAL OFFICES IN NUCLEAR POWER PLANTS  

E-Print Network (OSTI)

Information integration in control rooms and technical offices in nuclear power plants Report prepared within the framework of the

unknown authors

2001-01-01T23:59:59.000Z

419

Fuzzy expert system design for operating room air-condition control systems  

Science Conference Proceedings (OSTI)

In this study, a controlled fuzzy expert system (FES) was designed to provide the conditions necessary for operating rooms. For this purpose, existing operating rooms have been studied to see if there are more useful, reliable and comfortable ones. How ... Keywords: Adaptive fuzzy control, Expert systems, Fuzzy control systems, Operating room control

Nazmi Etik; Novruz Allahverdi; Ibrahim Unal Sert; Ismail Saritas

2009-08-01T23:59:59.000Z

420

Modeling and precision control of ionic polymer metal composite  

E-Print Network (OSTI)

This thesis describes the open-loop behavior of an ionic polymer metal composite (IPMC) strip as a novel actuator, the empirical force and position models, the control system and the improved dynamic characteristics with the feedback control implemented. Ionic polymer metal composite is a novel polymer in the class of electroactive polymers. IPMC consists of a base polymer coated with electrodes made up of highly conducting pure metals such as gold. The actuation behavior of IPMC can be attributed to the bending of an IPMC strip upon application of voltage across its thickness. The main reasons for the bending are ion migration on the application of voltage and swelling and contraction caused by water content. An experimental setup to study the open-loop force and tip displacement of an IPMC strip in a cantilever configuration was developed, and real time controllers were implemented. In open loop, the force response of the IPMC strip of dimensions 25 mm x 3.9 mm x 0.16 mm to a 1.2-V step input is studied. The open-loop rise time was 0.08 s and the percent overshoot was 131.62 %, while the settling time was about 10 s. Based on this open-loop step response using a least-square curve-fitting methodology, a fourth-order empirical transfer function from the voltage input to the force output was derived. The tip displacement response of an IPMC strip of dimensions 23 mm x 3.96 mm x 0.16 mm to a 1.2-V step input was also studied. The step response exhibited a 205.34 % overshoot with a rise time of 0.08 s, and the settling time was 27 s. A fourth-order empirical transfer function from the step input to the tip displacement as output was also derived. Based on the derived transfer functions lead-lag feedback controllers were designed for precision control of both force and displacement. The control objectives were to decrease the settling time and the percent overshoot, and achieve reference input tracking. After implementing the controllers, the percent overshoot decreased to 30% while the settling time was reduced to 1.5 s in case of force control. With position control, the settling time was reduced to 1 s while the percent overshoot decreased to 20%. Precision micro-scale force and position-control capabilities of the IPMC were also demonstrated. A 4 ?N force resolution was achieved, with a force noise of 0.904-?N rms. The position resolution was 20 ?m with a position noise of 7.6-?m rms.

Bhat, Nikhil Dilip

2003-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

A Comparison of Electron-Transfer Dynamics in Ionic Liquids and Neutral  

NLE Websites -- All DOE Office Websites (Extended Search)

Electron-Transfer Dynamics in Ionic Liquids and Neutral Electron-Transfer Dynamics in Ionic Liquids and Neutral Solvents Heather Y. Lee, Joseph B. Issa, Stephan S. Isied, Edward W. Castner, Jr., Yunfeng Pan, Charles L. Hussey, Kwang Soon Lee, and James F. Wishart J. Phys. Chem. C 116, 5197-5208 (2012). [Find paper at ACS Publications] or use ACS Articles on Request. Abstract: The effect of ionic liquids on photoinduced electron-transfer reactions in a donor-bridge-acceptor system is examined for two ionic liquid solvents, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide and tributylmethylammonium bis(trifluoromethyl¬sulfonyl)¬amide. The results are compared with those for the same system in methanol and acetonitrile solution. Electron-transfer rates were measured using time-resolved fluorescence quenching for the donor-bridge-acceptor system comprising a

422

Recovery of Sugars from Ionic Liquid Biomass Liquor by Solvent Extraction  

E-Print Network (OSTI)

chemical catalysis have been employed to enhance the conversion of IL-treated biomasschemical catalysis routes for the breakdown of biomass in ionic liquids would help increase the efficiency of the conversion of biomass

Brennan, Timothy C.; Datta, Supratim; Blanch, Harvey W.; Simmons, Blake A.; Holmes, Bradley M.

2010-01-01T23:59:59.000Z

423

A Microfabricated Planar Electrospray Array Ionic Liquid Ion Source With Integrated Extractor  

E-Print Network (OSTI)

This paper reports the design, fabrication, and experimental characterization of a fully microfabricated planar array of externally fed electrospray emitters that produces heavy molecular ions from the ionic liquids ...

Gassend, Blaise

424

Ionic Liquids: Breakthrough Absorption Technology for Post-Combustion CO2 Capture  

NLE Websites -- All DOE Office Websites (Extended Search)

Ionic Liquids: Breakthrough Absorption Ionic Liquids: Breakthrough Absorption Technology for Post-Combustion CO 2 Capture Background Development of innovative environmental control technologies is key to maintaining coal as an affordable and environmentally sound energy source. Carbon dioxide (CO 2 ) emissions control technologies, specifically post-combustion CO 2 capture, for coal- fired power plants is a major focus area in addressing climate change concerns. Post-

425

Reversible Ionic Liquids as Double-action Solvents for Efficient CO2 Capture  

NLE Websites -- All DOE Office Websites (Extended Search)

Reversible Ionic Liquids as Double-action Reversible Ionic Liquids as Double-action Solvents for Efficient CO 2 Capture Background Post-combustion carbon dioxide (CO 2 ) capture presents technical challenges because the flue gas is at atmospheric pressure and the CO 2 concentration is 10 to 15 volume percent, resulting in a low CO 2 partial pressure and a large volume of gas that needs to be treated. In spite of this difficulty, post-combustion CO 2 capture offers the

426

Model of ionic currents through microtubule nanopores and the lumen  

E-Print Network (OSTI)

It has been suggested that microtubules and other cytoskeletal filaments may act as electrical transmission lines. An electrical circuit model of the microtubule is constructed incorporating features of its cylindrical structure with nanopores in its walls. This model is used to study how ionic conductance along the lumen is affected by flux through the nanopores when an external potential is applied across its two ends. Based on the results of Brownian dynamics simulations, the nanopores were found to have asymmetric inner and outer conductances, manifested as nonlinear IV curves. Our simulations indicate that a combination of this asymmetry and an internal voltage source arising from the motion of the C-terminal tails causes a net current to be pumped across the microtubule wall and propagate down the microtubule through the lumen. This effect is demonstrated to enhance and add directly to the longitudinal current through the lumen resulting from an external voltage source, and could be significant in amplifying low-intensity endogenous currents within the cellular environment or as a nano-bioelectronic device.

Holly Freedman; Vahid Rezania; Avner Priel; Eric Carpenter; Sergei Y. Noskovd; Jack A. Tuszynski

2009-08-10T23:59:59.000Z

427

Glass formation, ionic conductivity, and conductivity/viscosity decoupling, in LiAlCl{sub 4} + LiClO{sub 4} and LiAlCl{sub 4} + LiAlCl{sub 3}{center_dot}imide solutions  

SciTech Connect

As part of a search for chemically and electrochemically stable ambient temperature molten lithium salt systems the authors have investigated the properties of solutions of LiAlCl{sub 4} with various second components. In this paper they review the factors which determine the ambient temperature conductivity and report results for two systems, one of which satisfies the stability requirements although failing to provide the high conductivities which are needed for a successful ambient temperature Li battery electrolyte. These ionic solutions appear to be very fragile liquids. Evidence is found for a mixing incompatibility of polarizable and nonpolarizable components of binary melts.

Videa, M.; Angeli, C.A. [Arizona State Univ., Tempe, AZ (United States). Dept. of Chemistry] [Arizona State Univ., Tempe, AZ (United States). Dept. of Chemistry

1999-05-20T23:59:59.000Z

428

Press Room - Press Releases - U.S. Energy Information ...  

U.S. Energy Information Administration (EIA)

WASHINGTON, DC - As much colder temperatures move into the U.S. Northeast next week, a special supplement released today by the U.S. Energy Information Administration ...

429

Microsoft Word - SmallServerRoomEfficiencyFactSheet.docx  

NLE Websites -- All DOE Office Websites (Extended Search)

5E 5E Fact Sheet: Improving Energy Efficiency for Server Rooms and Closets Hoi Ying (Iris) Cheung, Rod Mahdavi, Steve Greenberg, Rich Brown and William Tschudi, Lawrence Berkeley National Laboratory (LBNL) Pierre Delforge, National Resources Defense Council (NRDC) Joyce Dickerson, Google Environmental Energy Technologies Division September 2012 DISCLAIMER This document was prepared as an account of work sponsored by the United States Government. While this document is believed to contain correct information, neither the United States Government nor any agency thereof, nor The Regents of the University of California, nor any of their employees, makes any warranty, express or implied, or assumes any legal responsibility for the accuracy, completeness, or usefulness of any information,

430

Variable Speed Fan Retrofits for Computer Room Air Conditioners  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Variable-Speed Fan Variable-Speed Fan Retrofits for Computer-Room Air Conditioners Prepared for the U.S. Department of Energy Federal Energy Management Program Technology Case Study Bulletin By Lawrence Berkeley National Laboratory Steve Greenberg September 2013 2 Contacts Steve Greenberg Lawrence Berkeley National Laboratory One Cyclotron Road, 90R3111 Berkeley, California 94720 (510) 486-6971 segreenberg@lbl.gov For more information on FEMP, please contact: Will Lintner, P.E., CEM Federal Energy Management Program U.S. Department of Energy 1000 Independence Ave. S.W. Washington, D. C. 20585-0121 (202) 586-3120 william.lintner@ee.doe.gov 3 Acknowledgements EPRI: Dennis Symanski, Brian Fortenbery Synapsense: Garret Smith, Patricia Nealon Vigilent: Corinne Vita

431

The Committee convened in the Clark Room, Holiday Inn Capitol,  

U.S. Energy Information Administration (EIA) Indexed Site

MEETING MEETING - - - Thursday, April 25, 1996 - - - The Committee convened in the Clark Room, Holiday Inn Capitol, 550 C Street, S.W., Washington, D.C., at 9:00 a.m., Dr. Timothy D. Mount, Chairman, presiding. PRESENT: TIMOTHY D. MOUNT, Chairman SAMPRIT CHATTERJEE BRENDA G. COX JOHN D. GRACE CALVIN KENT GRETA M. LJUNG RICHARD A. LOCKHART DANIEL A. RELLES PRESENT (Continued): BRADLEY O. SKARPNESS G. CAMPBELL WATKINS ALSO PRESENT: RENEE MILLER YVONNE BISHOP MARY HUTZLER JAY HAKES DOUGLAS HALE ART HOLLAND ARTHUR RYPINSKI LOUISE GUEY-LEE JOHN CYMBALSKY ERIN BOEDECKER JERRY COFFEY INDER KUNDRA C O N T E N T S PAGE Presentation by Jay Hakes 6 Presentation by Yvonne Bishop 34 Presentation by Art Rypinski 43 Presentation by Richard A. Lockhart 61 Presentation by Douglas Hale 84

432

COMMERCIAL UTILITY PERSPECTIVES ON NUCLEAR POWER PLANT CONTROL ROOM MODERNIZATION  

SciTech Connect

Commercial nuclear power plants (NPPs) in the United States need to modernize their main control rooms (MCR). Many NPPs have done partial upgrades with some success and with some challenges. The Department of Energy’s (DOE) Light Water Reactor Sustainability (LWRS) Program, and in particular the Advanced Instrumentation and Controls (I&C) and Information Systems Technologies Research and Development (R&D) Pathway within LWRS, is designed to assist commercial nuclear power industry with their MCR modernization efforts. As part of this framework, a survey was issued to utility representatives of the LWRS Program Advanced Instrumentation, Information, and Control Systems/Technologies (II&C) Utility Working Group to obtain their views on a range of issues related to MCR modernization, including: drivers, barriers, and technology options, and the effects these aspects will have on concepts of operations, modernization strategies, and staffing. This paper summarizes the key survey results and discusses their implications.

Jeffrey C. Joe; Ronald L. Boring; Julius J. Persensky

2012-07-01T23:59:59.000Z

433

Use of Ionic Liquids as Physical Solvents for Selective Capture of CO2 from Fuel Gas Streams  

SciTech Connect

This study is to investigate the potential use of ionic liquids (ILs) as physical solvents for selective CO2 capture from post water-gas-shift reactor streams at elevated pressures and temperatures. The equilibrium gas solubility (x*) and the volumetric mass transfer coefficients (kLa) for CO2 and H2 in two different ILs (TEGO IL K5 and TEGO IL P51P) were determined. The data were obtained in an agitated reactor, equipped with sight-windows, in wide ranges of pressures, temperatures, mixing speeds, and liquid heights. Under the operating conditions investigated, the CO2 solubilities in the two ILs increased with pressure at constant temperature and decreased with temperature at constant pressure. Also, the volumetric liquid-side mass transfer coefficients of CO2 increased with mixing speed, pressure, and temperature and decreased with liquid height. The CO2 solubilities in the TEGO IL K5 were greater than those in the other two ILs at 500 K. Under similar operating conditions, the CO2 solubilities in the two ILs were greater than those of H2, which reflects the selective nature of ILs for CO2 capture. In addition, the ILs appeared to have negligible vapor pressure up to 500 K, which presents an advantage over conventional physical solvents currently employed for CO2 capture from post water-gas-shift reactor streams. This study demonstrated the thermal stability of the ILs and highlighted their ability to selectively capture CO2 at temperatures up to 500 K and pressures as high as 30 bars.

Heintz, Y.J.; Sehabiague, L.; Morsi, B.I.; Jones, K.L.; Pennline, H.W.

2008-07-01T23:59:59.000Z

434

Obtaining Mixed Ionic/Electronic Conductivity in Perovskite Oxides in a Reducing Environment: A Computational Prediction for Doped SrTiO3  

Science Conference Proceedings (OSTI)

The electronic conductivity and thermodynamic stability of mixed p- and n-doped SrTiO3 perovskites have been investigated under anodic solid oxide fuel cell conditions using density functional theory (DFT). In particular, constrained ab initio thermodynamic calculations have been performed to evaluate the phase stability of various Ga- and La-doped SrTiO3 at synthesized and anodic SOFC conditions. The density of states (DOS) of these materials was analyzed to determine the number of charge carriers and the degree of electronic conductivity. We find that a mixed ionic/electronic conductor can be obtained when doping SrTiO3 perovskite oxide with both p-type and n-type dopants. Calculations show that 10% Ga- and 20% La-doped SrTiO3 exhibit mixed ionic/electronic conductivity at high temperature and low oxygen partial pressure whereas doping with higher concentrations of Ga, e.g., 20%, diminishes the electronic conductivity of the material. Furthermore, changing the n-dopant from La (A-site) to Nb (B-site) does not significantly affect the reducibility and number of charge carriers in p- and n-doped SrTiO3. However, a higher degree of oxygen vacancy clustering is observed for the La-doped material which reduces the oxygen ion diffusion rate and traps electrons. Nevertheless, our findings suggest that independent of doping site, mixed ionic/ electronic conductivity can be obtained in SrTiO3 perovskite oxides under reducing conditions and high temperatures when using a mixed p- and n-type doping strategy that uses a p-dopant concentration smaller than the n-dopant concentration.

Suthirakun, Suwit; Ammal, Salai Cheettu; Xiao, Guoliang; Chen, Fanglin; Huang, Kevin; zur Loye, Hans-Conrad; Heyden, Andreas

2012-11-30T23:59:59.000Z

435

Mineral phase and physical properties of red mud calcined at different temperatures  

Science Conference Proceedings (OSTI)

Different characterizations were carried out on red mud uncalcined and samples calcined in the range of 100°C-1400°C. In the present paper, the phase composition and structural transition of red mud heated from room temperature are indicated ...

Chuan-sheng Wu, Dong-yan Liu

2012-01-01T23:59:59.000Z

436

Neptunium (V) Adsorption to a Halophilic Bacterium Under High Ionic Strength Conditions: A Surface Complexation Modeling Approach  

Science Conference Proceedings (OSTI)

Rationale for experimental design: Np(V) -- important as analog for Pu(V) and for HLW scenarios; High ionic strength -- relevant to salt-based repositories such as the WIPP; Halophilic microorganisms -- representative of high ionic strength environments. For the first time showed: Significant adsorbant to halophilic microorganisms over entire pH range under high ionic strength conditions; Strong influence of ionic strength with increasing adsorption with increasing ionic strength (in contrast to trends of previous low ionic strength studies); Effect of aqueous Np(V) and bacterial surface site speciation on adsorption; and Developed thermodynamic models that can be incorporated into geochemical speciation models to aid in the prediction of the fate and transport of Np(V) in more complex systems.

Ams, David A [Los Alamos National Laboratory

2012-06-11T23:59:59.000Z

437

Synthesis and Characterization of Polymeric Ionic Liquids and Applications in Solid-Phase Microextraction Coupled with Gas Chromatography.  

E-Print Network (OSTI)

??Ionic liquids (ILs) are a class of molten salts with melting points considerably lower than conventional inorganic salts. Their unique properties make them an ideal… (more)

Meng, Yunjing

2011-01-01T23:59:59.000Z

438

Ring Opened Heterocycles: Promising Ionic Liquids for Gas Separation and Capture  

SciTech Connect

We report on a new class of highly fluid ionic liquids integrating a cation that resembles an opened imidazolium structure with two distinct anions, bis(trifluoromethylsulfonyl)imide, [Tf{sub 2}N], and a nitrile-containing anion, [C(CN)3]. These new ionic liquids show exceptional CO{sub 2} permeability values in liquid membrane gas separations with results that equal or exceed the Robeson upper bound. Moreover, these ionic liquids offer ideal CO{sub 2}/N{sub 2} selectivities competitive with the best results reported to date, exhibiting values that range from 28 to 45. The nitrile containing ionic liquid displayed the highest ideal CO{sub 2}/N{sub 2} selectivity with a value of 45 which primarily results from a reduction in the nitrogen permeability. In addition to permeability results, CO{sub 2} solubilities were also measured for the this new class of ionic liquids with values similar to the popular 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. The CO{sub 2} solubility results were compared to predicted values obtained using both a modified regular solution theory and the quantum chemical Conductor-like Screening Model for Real Solvents (COSMO-RS) method. Agreement between predicted and measured solubility values is also discussed.

Mahurin, Shannon Mark [ORNL; Yeary, Joshua S [ORNL; Baker, Sheila N [ORNL; Jiang, Deen [ORNL; Dai, Sheng [ORNL; Baker, Gary A [ORNL

2012-01-01T23:59:59.000Z

439

Studies of ionic liquids in lithium-ion battery test systems  

SciTech Connect

In this work, thermal and electrochemical properties of neat and mixed ionic liquid - lithium salt systems have been studied. The presence of a lithium salt causes both thermal and phase-behavior changes. Differential scanning calorimeter DSC and thermal gravimetric analysis TGA were used for thermal analysis for several imidazolium bis(trifluoromethylsulfonyl)imide, trifluoromethansulfonate, BF{sub 4}, and PF{sub 6} systems. Conductivities and diffusion coefficient have been measured for some selected systems. Chemical reactions in electrode - ionic liquid electrolyte interfaces were studied by interfacial impedance measurements. Lithium-lithium and lithium-carbon cells were studied at open circuit and a charged system. The ionic liquids studied include various imidazolium systems that are already known to be electrochemically unstable in the presence of lithium metal. In this work the development of interfacial resistance is shown in a Li|BMIMBF{sub 4} + LiBF{sub 4}|Li cell as well as results from some cycling experiments. As the ionic liquid reacts with the lithium electrode the interfacial resistance increases. The results show the magnitude of reactivity due to reduction of the ionic liquid electrolyte that eventually has a detrimental effect on battery performance.

Salminen, Justin; Prausnitz, John M.; Newman, John

2006-06-01T23:59:59.000Z

440

TRENDS: TEMPERATURE  

NLE Websites -- All DOE Office Websites (Extended Search)

Historical Isotopic Temperature Record from the Vostok Ice Core Historical Isotopic Temperature Record from the Vostok Ice Core Graphics Digital Data J.R. Petit, D. Raynaud, and C. Lorius Laboratoire de Glaciogie et Géophysique de l'Environnement, CNRS, Saint Martin d'Hères Cedex, France J. Jouzel and G. Delaygue Laboratoire des Sciences du Climat et de l'Environnement (LSCE), CEA/CNRS, L'Orme des Merisiers, CEA Saclay, 91191 Gif-sur-Yvette Cedex, France N.I. Barkov Arctic and Antarctic Research Institute, Beringa Street 38, 199397 St. Petersburg, Russia V.M. Kotlyakov Institute of Geography, Staromonetny, per 29, Moscow 109017, Russia DOI: 10.3334/CDIAC/cli.006 Period of Record 420,000 years BP-present Methods Because isotopic fractions of the heavier oxygen-18 (18O) and deuterium (D) in snowfall are temperature-dependent and a strong spatial correlation

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Renewable energy has political support, room to grow  

Science Conference Proceedings (OSTI)

Renewable energy sources enjoy growing political support and have plenty of room to grow in the worldwide energy mix. And grow they will, according to most projections. The US Energy Information Administration`s (EIA`s) International Energy Outlook 1997 says consumption of hydroelectricity and other renewables will increase by 56% during 1995--2015. The renewable share of the total energy mix will remain at about current levels, however. The EIA projection includes only renewable fuels used in the generation of electricity. It therefore excludes most biomass energy. Despite the importance of biomass energy, data on consumption of it are sparse. IEA estimates that in the industrialized world, the biomass share of primary energy consumption amounts to 3.5%. Also excluded from EIA`s projection because of insufficiency of data are dispersed renewables, a category that includes energy consumed at the site of production, such as solar panels used for water heating. This paper discusses regional trends, North American activity, Western Europe, Asian developments, and the rest of the world.

NONE

1997-08-11T23:59:59.000Z

442

Design of a ventilation system for carbon dioxide reduction in two gym rooms.  

E-Print Network (OSTI)

?? This project is mainly focused on the improving and design of the ventilation system of two rooms at different levels of a gym (Friskis… (more)

Barroeta, Ander

2013-01-01T23:59:59.000Z

443

The Virtual Control Room for Fusion Energy Sciences (V3) (A24771)  

E-Print Network (OSTI)

Proc. Of The Virtual Control Room For Fusion Energy Sciences (V3)US DOE National Collaboratories Program Meeting(2004) Champaign Illinois, US, 2004999610460

Schissel, D.P.

2004-07-23T23:59:59.000Z

444

Epitaxial oxygen sponges as low temperature catalysts | ornl.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

Functional Materials for Energy Functional Materials for Energy Epitaxial oxygen sponges as low temperature catalysts September 10, 2013 Crystal structure of SrCoO2.5 superimposed on a scanning transmission electron microscopy image of an epitaxially stabilized oxygen sponge. Fast and reversible redox reactions at considerably reduced temperatures are achieved by epitaxial stabilization of multivalent transition metal oxides. This illustrates the unprecedented potential of complex oxides for oxide-ionics, where oxidation state changes are used for energy generation, storage and electrochemical sensing. Thermomechanical degradation reduces the overall performance and lifetime of many perovskite oxides undergoing reversible redox reactions, such as those found in solid oxide fuel cells, rechargeable batteries,

445

Water Recycling removal using temperature-sensitive hydronen  

DOE Green Energy (OSTI)

The overall objective of this project was to study the proposed Water Recycling/Removal Using Temperature-Sensitive Hydrogels. The main element of this technology is the design of a suitable hydrogel that can perform needed water separation for pulp and paper industry. The specific topics studied are to answer following questions: (a) Can water be removed using hydrogel from large molecules such as lignin? (b) Can the rate of separation be made faster? (c) What are the molecular interactions with hydrogel surface? (d) Can a hydrogel be designed for a high ionic strength and high temperature? Summary of the specific results are given.

Rana B. Gupta

2002-10-30T23:59:59.000Z

446

Microsoft Word - Poster Abstract_2010_GATech_Mixed Ionic-Electronic Conductors.docx  

NLE Websites -- All DOE Office Websites (Extended Search)

Investigation of Oxygen Reduction Activity on Mixed Ionic-Electronic Conductors for Investigation of Oxygen Reduction Activity on Mixed Ionic-Electronic Conductors for SOFC Cathodes Matthew E. Lynch, Lei Yang, Meilin Liu Center for Innovative Fuel Cell and Battery Technologies School of Materials Science and Engineering Georgia Institute of Technology 771 Ferst Dr., Atlanta, GA 30332-0245 Telephone: 404-894-6114 Email: meilin.liu@mse.gatech.edu Porous cathodes are of primary importance to the electrochemical operation of a solid oxide fuel cell (SOFC). The compound La 1-x Sr x Co 1-y Fe y O 3-δ (LSCF) is a candidate material for the cathode, and shows good mixed ionic-electronic conductivity as well as good activity toward the oxygen reduction

447

Atomistic-to-Continuum Multiscale Modeling with Long-Range Electrostatic Interactions in Ionic Solids  

E-Print Network (OSTI)

We present a multiscale atomistic-to-continuum method for ionic crystals with defects. Defects often play a central role in ionic and electronic solids, not only to limit reliability, but more importantly to enable the functionalities that make these materials of critical importance. Examples include solid electrolytes that conduct current through the motion of charged point defects, and complex oxide ferroelectrics that display multifunctionality through the motion of domain wall defects. Therefore, it is important to understand the structure of defects and their response to electrical and mechanical fields. A central hurdle, however, is that interactions in ionic solids include both short-range atomic interactions as well as long-range electrostatic interactions. Existing atomistic-to-continuum multi-scale methods, such as the Quasicontinuum method, are applicable only when the atomic interactions are short-range. In addition, empirical reductions of quantum mechanics to density functional models are unable...

Marshall, Jason

2013-01-01T23:59:59.000Z

448

THE POTENTIAL OF NANOPARTICLE ENHANCED IONIC LIQUIDS (NEILS) AS ADVANCED HEAT TRANSFER FLUIDS  

DOE Green Energy (OSTI)

Interest in capturing the energy of the sun is rising as demands for renewable energy sources increase. One area of developing research is the use of concentrating solar power (CSP), where the solar energy is concentrated by using mirrors to direct the sunlight towards a collector filled with a heat transfer fluid (HTF). The HTF transfers the collected energy into pressurized steam, which is used to generate energy. The greater the energy collected by the HTF, the more efficent the electrical energy production is, thus the overall efficiency is controlled by the thermal fluid. Commercial HTFs such as Therminol{reg_sign} (VP-1), which is a blend of biphenyl and diphenyl oxide, have a significant vapor pressure, especially at elevated temperatures. In order for these volatile compounds to be used in CSP systems, the system either has to be engineered to prevent the phase change (i.e., volatilization and condensation) through pressurization of the system, or operate across the phase change. Over thirty years ago, a class of low-melting organic compounds were developed with negligible vapor pressure. These compounds are referred to as ionic liquids (ILs), which are organic-based compounds with discrete charges that cause a significant decrease in their vapor pressure. As a class, ILs are molten salts with a melting point below 100 C and can have a liquidus range approaching 400 C, and in several cases freezing points being below 0 C. Due to the lack of an appreciable vapor pressure, volatilization of an IL is not possible at atmospheric pressure, which would lead to a simplification of the design if used as a thermal fluid and for energy storage materials. Though the lack of a vapor pressure does not make the use of ILs a better HTF, the lack of a vapor pressure is a compliment to their higher heat capacity, higher volummetric density, and thus higher volumetric heat capacity. These favorable physical properties give ILs a pontential advantage over the current commerically used thermal fluids. Also within the past decade nanofluids have gained attention for thermal conductivity enhancment of fluids, but little analysis has been completed on the heat capacity effects of the nanoparticle addition. The idea of ILs or nanofluids as a HTF is not new, as there are several references that have proposed the idea. However, the use of ionic liquid nanofluids containing nanomaterials other than carbon nanotubes has never before been studied. Here, for the first time, nano-particle enhanced ILs (NEILs) have been shown to increase the heat capacity of the IL with no adverse side effects to the ILs thermal stability and, only at high nanoparticle loading, are the IL physical properties affected. An increase of volumetric heat capacity translates into a better heat transfer fluid as more energy is stored per volumetric unit in the solar concentrating section, thus more efficency in increased steam pressure. Results show that the properties of the NEIL are highly dependant on the suspended nanomaterial and careful materials selection is required to fully optimize the nanofluid properties.

Fox, E.; Bridges, N.; Visser, A.

2011-09-14T23:59:59.000Z

449

Catalytic Conversion of Biomass to Fuels and Chemicals Using Ionic Liquids  

DOE Green Energy (OSTI)

This project provides critical innovations and fundamental understandings that enable development of an economically-viable process for catalytic conversion of biomass (sugar) to 5-hydroxymethylfurfural (HMF). A low-cost ionic liquid (Cyphos 106) is discovered for fast conversion of fructose into HMF under moderate reaction conditions without any catalyst. HMF yield from fructose is almost 100% on the carbon molar basis. Adsorbent materials and adsorption process are invented and demonstrated for separation of 99% pure HMF product and recovery of the ionic liquid from the reaction mixtures. The adsorbent material appears very stable in repeated adsorption/regeneration cycles. Novel membrane-coated adsorbent particles are made and demonstrated to achieve excellent adsorption separation performances at low pressure drops. This is very important for a practical adsorption process because ionic liquids are known of high viscosity. Nearly 100% conversion (or dissolution) of cellulose in the catalytic ionic liquid into small molecules was observed. It is promising to produce HMF, sugars and other fermentable species directly from cellulose feedstock. However, several gaps were identified and could not be resolved in this project. Reaction and separation tests at larger scales are needed to minimize impacts of incidental errors on the mass balance and to show 99.9% ionic liquid recovery. The cellulose reaction tests were troubled with poor reproducibility. Further studies on cellulose conversion in ionic liquids under better controlled conditions are necessary to delineate reaction products, dissolution kinetics, effects of mass and heat transfer in the reactor on conversion, and separation of final reaction mixtures.

Liu, Wei; Zheng, Richard; Brown, Heather; Li, Joanne; Holladay, John; Cooper, Alan; Rao, Tony

2012-04-13T23:59:59.000Z

450

Sorption of organic gases in a furnished room  

SciTech Connect

We present experimental data and semi-empirical models describing the sorption of organic gases in a simulated indoor residential environment. Two replicate experiments were conducted with 20 volatile organic compounds (VOCs) in a 50-m{sup 3} room finished with painted wallboard, carpet and cushion, draperies and furnishings. The VOCs span a wide volatility range and include ten Hazardous Air Pollutants. VOCs were introduced to the static chamber as a pulse and their gas-phase concentrations were measured during a net adsorption period and a subsequent net desorption period. Three sorption models were fit to the measured concentrations for each compound to determine the simplest formulation needed to adequately describe the observed behavior. Sorption parameter values were determined by fitting the models to adsorption period data then checked by comparing measured and predicted behavior during desorption. The adequacy of each model was evaluated using a goodness of fit parameter calculated for each period. Results indicate that sorption usually does not greatly affect indoor concentrations of methyl-tert-butyl ether, 2-butanone, isoprene and benzene. In contrast, sorption appears to be a relevant indoor process for many of the VOCs studied, including C{sub 8}-C{sub 10} aromatic hydrocarbons (HC), terpenes, and pyridine. These compounds sorbed at rates close to typical residential air change rates and exhibited substantial sorptive partitioning at equilibrium. Polycyclic aromatic HCs, aromatic alcohols, ethenylpyridine and nicotine initially adsorbed to surfaces at rates of 1.5 to >6 h{sup -1} and partitioned 95 to >99% in the sorbed phase at equilibrium.

Singer, Brett C.; Revzan, Kenneth L.; Hotchi, Toshifumi; Hodgson, Alfred T.; Brown, Nancy J.

2003-11-30T23:59:59.000Z

451

Gelled Ionic Liquid-Based Membranes: Achieving a 10,000 GPU Permeance for Post-Combustion Carbon Capture with Gelled Ionic Liquid-Based Membranes  

Science Conference Proceedings (OSTI)

IMPACCT Project: Alongside Los Alamos National Laboratory and the Electric Power Research Institute, CU-Boulder is developing a membrane made of a gelled ionic liquid to capture CO2 from the exhaust of coal-fired power plants. The membranes are created by spraying the gelled ionic liquids in thin layers onto porous support structures using a specialized coating technique. The new membrane is highly efficient at pulling CO2 out of coal-derived flue gas exhaust while restricting the flow of other materials through it. The design involves few chemicals or moving parts and is more mechanically stable than current technologies. The team is now working to further optimize the gelled materials for CO2 separation and create a membrane layer that is less than 1 micrometer thick.

None

2011-02-02T23:59:59.000Z

452

Effect of room air recirculation delay on the decay rate of tracer gas  

NLE Websites -- All DOE Office Websites (Extended Search)

Effect of room air recirculation delay on the decay rate of tracer gas Effect of room air recirculation delay on the decay rate of tracer gas Title Effect of room air recirculation delay on the decay rate of tracer gas Publication Type Conference Proceedings Year of Publication 2004 Authors Kristoffersen, Astrid H., Ashok J. Gadgil, and David M. Lorenzetti Conference Name 9th International Conference on Air Distribution in Rooms - RoomVent 2004, Pagination pp 6 Date Published September 5-8, 2 Conference Location Coimbra, Portugal Abstract Tracer gas measurements are commonly used to estimate the fresh air exchange rate in a room or building. Published tracer decay methods account for fresh air supply, infiltration, and leaks in ductwork. However, the time delay associated with a ventilation system recirculating tracer back to the room also affects the decay rate. We present an analytical study of tracer gas decay in a well-mixed, mechanically-ventilated room with recirculation. The analysis shows that failing to account for delays can lead to under- or over-estimates of the fresh air supply, depending on whether the decay rate calculation includes the duct volume

453

Boiler Room Coal Drying Heat Exchanger Numerical Computational Simulation and Analysis  

Science Conference Proceedings (OSTI)

Northeast area city district heating boiler room of coal with high moisture content, have caused a large number of waste of coal resources. Boiler coal drying heat exchanger is a long design cycle, testing workload and investment is more equipment. In ... Keywords: District heating boiler room, Dry heat exchanger, Numerical simulation, Heat transfer calculation

Zhao Xuefeng, Xiong Wen-zhuo

2012-07-01T23:59:59.000Z

454

Managing Complexity in TeamRooms, a Tcl-Based Internet Groupware Application  

E-Print Network (OSTI)

Managing Complexity in TeamRooms, a Tcl-Based Internet Groupware Application Mark Roseman Dept@cpsc.ucalgary.ca Abstract This paper describes TeamRooms, a Tcl-based real time groupware application that provides "network the use of several Tcl programming techniques -- meta-architectures, multiple interpreters, and embedded

Greenberg, Saul

455

UC Davis Medical Education Building | 4610 X Street | Room 1222 & 2222 ONLINE REGISTRATION  

E-Print Network (OSTI)

UC Davis Medical Education Building | 4610 X Street | Room 1222 & 2222 ONLINE REGISTRATION/ TECHNOLOGIST SYMPOSIUM Advances In Cardiovascular Medical and Surgical Care SAVE THE DATE Saturday, May 5, 2012-734-5512, janine.neely@ucdmc.ucdavis.edu. LOCATION UC Davis Medical Education Building 4610 X Street, Room 1222

Hammock, Bruce D.

456

Joan Stevens Hall 1st-year students. 242 242 single rooms.  

E-Print Network (OSTI)

single rooms, 38 twin-share places. $170­$213 Yes Yes # Gym area Music room 15 free off-street car parks fee* Electricity included in fee Internet included in fee Facilities available #12;uStay McKenzies = 1

Frean, Marcus

457

Room ventilation and its influence on the performance of fume cupboards: A parametric numerical study  

Science Conference Proceedings (OSTI)

The three-dimensional turbulent flow in a typical chemical laboratory containing two fume cupboards and furniture is investigated numerically in order to obtain detailed information needed for the improved design of ventilating systems for such rooms. The flow inside the two fume cupboards is simulated simultaneously with the room flow, and its dependence on the flow structure in the room is shown. The flow inside the cupboards and in the vicinity of their sash openings has been found to be essentially three-dimensional. Several room parameters are varied, and a quantitative evaluation of their influence on the flow, the comfort characteristics, and the ventilation efficiency is given. Additional ceiling-mounted openings, which extract room air outside the fume cupboards, can affect the capture efficiency of the cupboards, as well as the quality of the air in the room. It has been found also that small changes in the position of the radial inlet ceiling-mounted diffuser can influence the air quality of the room and at the same time the draught risk. These effects are shown for a given room arrangement. To accommodate the complex geometry, the elliptical nature of the mathematical problem, and the use of a turbulence model, a multigrid acceleration method with 245,000 control volumes is used, allowing CPU times on a workstation to become acceptable.

Denev, J.A.; Durst, F.; Mohr, B. [Friedrich Alexander Univ. Erlangen-Nuernberg, Erlangen (Germany)] [Friedrich Alexander Univ. Erlangen-Nuernberg, Erlangen (Germany)

1997-02-01T23:59:59.000Z

458

Human Factors Guidance for Control Room and Digital Human-System Interface Design and Modification  

Science Conference Proceedings (OSTI)

Operators of nuclear power plants face a significant challenge designing and modifying control rooms that will be produced at various stages of instrumentation and control (I&C) modernization. This report provides guidance on planning, specifying, designing, implementing, operating, maintaining, and training for modernized control rooms and digital human-system interfaces.

2005-12-08T23:59:59.000Z

459

Validation and Application of the Room Model of the Modelica Buildings  

NLE Websites -- All DOE Office Websites (Extended Search)

Validation and Application of the Room Model of the Modelica Buildings Validation and Application of the Room Model of the Modelica Buildings Library Title Validation and Application of the Room Model of the Modelica Buildings Library Publication Type Conference Proceedings LBNL Report Number LBNL-5932E Year of Publication 2012 Authors Nouidui, Thierry Stephane, Kaustubh Phalak, Wangda Zuo, and Michael Wetter Conference Name Proc. of the 9th International Modelica Conference Date Published 09/2012 Conference Location Munich, Germany Abstract The Modelica Buildings library contains a package with a model for a thermal zone that computes heat transfer through the building envelope and within a room. It considers various heat transfer phenomena of a room, including conduction, convection, short-wave and long-wave radiation. The first part of this paper describes the physical phenomena considered in the room model. The second part validates the room model by using a standard test suite provided by the American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE). The third part focuses on an application where the room model is used for simulation-based controls of a window shading device to reduce building energy consumption.

460

Calculation of activities and solubilities of alkali metal perchlorates at high ionic strengths in multicomponent aqueous systems  

Science Conference Proceedings (OSTI)

The equations of Nyvlt, of Bromley, and of Pitzer for the representation of activity coefficients of electrolytes in multicomponent ionic systems have been used to fit solubility data for some alkali metal perchlorates and ammonium perchlorate in mixture with other electrolytes at ionic strengths varying from 0.08 mol-kg/sup -1/ to as high as 24 mol-kg/sup -1/. Only the Pitzer equations can be used reliably to fit the solubility data over the whole range of ionic strengths encountered for ternary systems but there are certain limitations and certain assumptions which have to be made concerning the Pitzer ionic interaction parameters. A method is also proposed for the calculation of the Pitzer single electrolyte parameters, ..beta../sup 0/, ..beta../sup 1/, and C/sup phi/, for the less soluble perchlorates from fitting their solubility data over a wide range of high ionic strengths.

Chan, C.; Khoo, K.H.

1988-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "room temperature ionic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

OVERVIEW OF A RECONFIGURABLE SIMULATOR FOR MAIN CONTROL ROOM UPGRADES IN NUCLEAR POWER PLANTS  

SciTech Connect

This paper provides background on a reconfigurable control room simulator for nuclear power plants. The main control rooms in current nuclear power plants feature analog technology that is growing obsolete. The need to upgrade control rooms serves the practical need of maintainability as well as the opportunity to implement newer digital technologies with added functionality. There currently exists no dedicated research simulator for use in human factors design and evaluation activities for nuclear power plant modernization in the U.S. The new research simulator discussed in this paper provides a test bed in which operator performance on new control room concepts can be benchmarked against existing control rooms and in which new technologies can be validated for safety and usability prior to deployment.

Ronald L. Boring

2012-10-01T23:59:59.000Z

462

Finite-Temperature Hydrogen Adsorption/Desorption Thermodynamics Driven by Soft Vibration Modes  

Science Conference Proceedings (OSTI)

It is widely accepted that room-temperature hydrogen storage on nanostructured or porous materials requires enhanced dihydrogen adsorption. In this work we reveal that room-temperature hydrogen storage is possible not only by the enhanced adsorption, but also by making use of the vibrational free energy from soft vibration modes. These modes exist for example in the case of metallo-porphyrin-incorporated graphenes (M-PIGs) with out-of-plane ( buckled ) metal centers. There, the in-plane potential surfaces are flat because of multiple-orbital-coupling between hydrogen molecules and the buckled-metal centers. This study investigates the finite-temperature adsorption/desorption thermodynamics of hydrogen molecules adsorbed on M-PIGs by employing first-principles total energy and vibrational spectrum calculations. Our results suggest that the current design strategy for room-temperature hydrogen storage materials should be modified by explicitly taking finite-temperature vibration thermodynamics into account.

Woo, Sung-Jae [KAIST, Daejeon, Republic of Korea; Lee, Eui-Sup [KAIST, Daejeon, Republic of Korea; Yoon, Mina [ORNL; Yong-Hyun, Kim [KAIST, Daejeon, Republic of Korea

2013-01-01T23:59:59.000Z