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Sample records for rifle surface water

  1. June-July 2015 Groundwater and Surface Water Sampling at the Old and New Rifle, Colorado, Processing Sites

    Office of Legacy Management (LM)

    June-July 2015 Groundwater and Surface Water Sampling at the Old and New Rifle, Colorado, Processing Sites November 2015 LMS/RFL/S00615 This page intentionally left blank U.S. Department of Energy DVP-June and July 2015, Old and New Rifle, Colorado November 2015 RINs 15067100, 15067101, and 15077206 Page i Contents Sampling Event Summary ...............................................................................................................1 New Rifle, Colorado, Processing Site, Planned

  2. EA-1406: Ground Water Compliance at the New Rifle, Colorado, UMTRA Project Site, Rifle, Colorado

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposed compliance strategy of natural flushing combined with institutional controls and continued monitoring for the New Rifle uranium mill...

  3. Work plan for preliminary investigation of organic constituents in ground water at the New Rifle site, Rifle, Colorado. Revision 2

    SciTech Connect (OSTI)

    1996-01-01

    A special study screening for Appendix 9 (40 CFR Part 264) analytes identified the New Rifle site as a target for additional screening for organic constituents. Because of this recommendation and the findings in a recent independent technical review, the US Department of Energy (DOE) has requested that the Technical Assistance Contractor (TAC) perform a preliminary investigation of the potential presence of organic compounds in the ground water at the New Rifle Uranium Mill Tailings Remedial Action (UMTRA) Project site, Rifle, Colorado. From 1958 to 1972, organic chemicals were used in large quantities during ore processing at the New Rifle site, and it is possible that some fraction was released to the environment. Therefore, the primary objective of this investigation is to determine whether organic chemicals used at the milling facility are present in the ground water. The purpose of this document is to describe the work that will be performed and the procedures that will be followed during installation of ground water well points at the New Rifle site. The selection of analytes and the procedures for collecting ground water samples for analysis of organic constituents are also described.

  4. Baseline risk assessment of ground water contamination at the uranium mill tailings sites near Rifle, Colorado. Revision 1

    SciTech Connect (OSTI)

    1995-08-01

    The US Department of Energy (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project consists of the Surface Project (Phase 1) and the Ground Water Project (Phase 2). Under the UMTRA Surface Project, tailings, radioactive contaminated soil, equipment, and materials associated with the former uranium ore processing sites are placed into disposal cells. The cells are designed to reduce radon and other radiation emissions and to prevent further ground water contamination. The Ground Water Project evaluates the nature and extent of ground water contamination resulting from the uranium ore processing activities. Two UMTRA Project sites are near Rifle, Colorado: the Old Rifle site and the New Rifle site. Surface cleanup at the two sites is under way and is scheduled for completion in 1996. The Ground Water Project is in its beginning stages. A risk assessment identifies a source of contamination, how that contamination reaches people and the environment, the amount of contamination to which people or the environment may be exposed, and the health or environmental effects that could result from that exposure. This report is a site-specific document that will be used to evaluate current and future impacts to the public and the environment from exposure to contaminated ground water. This evaluation and further site characterization will be used to determine if action is needed to protect human health or the environment.

  5. Ground Water Compliance Action Plan for the Old Rifle, Colorado, UMTRA Project Site

    Office of Legacy Management (LM)

    GJO-2000-177-TAR MAC-GWRFL 1.9 Ground Water Compliance Action Plan for the Old Rifle, Colorado, UMTRA Project Site December 2001 Work Performed Under DOE Contract No. DE-AC13-96GJ87335 for the U.S. Department of Energy Approved for public release; distribution is unlimited. GJO-2000-177-TAR MAC-GWRFL 1.9 Ground Water Compliance Action Plan for the Old Rifle, Colorado, UMTRA Project Site December 2001 Prepared by U.S. Department of Energy Grand Junction Office Grand Junction, Colorado Project

  6. Baseline risk assessment of ground water contamination at the Uranium Mill Tailings Sites near Rifle, Colorado. Revision 2

    SciTech Connect (OSTI)

    1996-02-01

    The U.S. Department of Energy (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project consists of the Surface Project (Phase I) and the Ground Water Project (Phase II). Under the UMTRA Surface Project, tailings, radioactive contaminated soil, equipment, and materials associated with the former uranium ore processing sites are placed into disposal cells. The cells are designed to reduce radon and other radiation emissions and to prevent further ground water contamination. The Ground Water Project evaluates the nature and extent of ground water contamination resulting from the uranium ore processing activities. Two UMTRA Project sites are near Rifle, Colorado: the Old Rifle site and the New Rifle site. Surface cleanup at the two sites is under way and is scheduled for completion in 1996. The Ground Water Project is in its beginning stages. A risk assessment identifies a source of contamination, how that contamination reaches people and the environment, the amount of contamination to which people or the environment may be exposed, and the health or environmental effects that could result from that exposure. This report is a site-specific document that will be used to evaluate current and future impacts to the public and the environment from exposure to contaminated ground water. This evaluation and further site characterization will be used to determine if action is needed to protect human health or the environment. Human health risk may result from exposure to ground water contaminated from uranium ore processing. Exposure could occur from drinking water obtained from a well placed in the areas of contamination. Furthermore, environmental risk may result from plant or animal exposure to surface water and sediment that have received contaminated ground water.

  7. DOE - Office of Legacy Management -- Rifle_Old

    Office of Legacy Management (LM)

    Old Processing Site Key Documents and Links All documents are Adobe Acrobat files. pdf_icon Key Documents Fact Sheet 2014 Verification Monitoring Report for the Old and New Rifle, Colorado, Processing Sites June-July 2015 Groundwater and Surface Water Sampling at the Old and New Rifle, Colorado, Processing Sites Ground Water Compliance Action Plan for the Old Rifle, Colorado, UMTRA Project Site Please be green. Do not print these documents unless absolutely necessary. Submit a FOIA Request for

  8. DOE - Office of Legacy Management -- Rifle

    Office of Legacy Management (LM)

    Rifle Rifle Sites rifle_map Rifle Disposal Site Rifle New Processing Site Rifle Old Processing Site

  9. RIFLE CO

    Office of Legacy Management (LM)

    UN STGTE smtbFY RIFLE CO lwm CC -.. CmEli m stirx iax ct! Efm .co ' 3 .,, URbVGN m

  10. DOE - Office of Legacy Management -- Rifle_New

    Office of Legacy Management (LM)

    New Processing Site Key Documents and Links All documents are Adobe Acrobat files. pdf_icon Key Documents Fact Sheet June-July 2015 Groundwater and Surface Water Sampling at the Old and New Rifle, Colorado, Processing Sites Please be green. Do not print these documents unless absolutely necessary. Submit a FOIA Request for documents not available through this website. Status of Pending Decision Documents New Rifle Groundwater Compliance Action Plan Under review by U.S. Nuclear Regulatory

  11. rifle.cdr

    Office of Legacy Management (LM)

    JUNCTION RIFLE GRAND DISPOSAL SITE N NEW RIFLE 70 DENVER COLORADO MILLSITE 6 65 MILES 20 10 0 133 30 OLD RIFLE MILLSITE RIFLE C O L O R A D O RIVER 13 R I F L E C R E E K GLENWOOD SPRINGS NEW CASTLE M:\LTS\111\0017\01\S0016200.DWG The Grand Junction Office has provided cost-effective and efficient stewardship for more than 10 years F A C T S H E E T Overview Regulatory Setting Rifle Disposal Site Uranium and vanadium ores were processed at two millsites near Rifle, Colorado, between 1924 through

  12. Public Involvment Plan - Rifle, Colorado

    Office of Legacy Management (LM)

    4-TAR MAC-GWRIF 7.1 UMTRA Ground Water Project Public Involvement Plan for the Environmental Assessment of Ground Water Compliance at the New and Old Rifle, Colorado, Uranium Mill Tailings Sites May 1999 Prepared by U.S. Department of Energy Grand Junction Office Grand Junction, Colorado Work performed under DOE Contract No. DE-AC13-96GJ87335 Public Involvement Plan for the Rifle UMTRA Sites Page 2 Introduction This Public Involvement Plan is tiered to the Uranium Mill Tailings Remedial Action

  13. Baseline risk assessment of ground water contamination at the Uranium Mill Tailings Sites near Rifle, Colorado

    SciTech Connect (OSTI)

    1995-05-01

    The ground water project evaluates the nature and extent of ground water contamination resulting from the uranium ore processing activities. This report is a site specific document that will be used to evaluate current and future impacts to the public and the environment from exposure to contaminated ground water. Currently, no one is using the ground water and therefore, no one is at risk. However, the land will probably be developed in the future and so the possibility of people using the ground water does exist. This report examines the future possibility of health hazards resulting from the ingestion of contaminated drinking water, skin contact, fish ingestion, or contact with surface waters and sediments.

  14. Radiological survey of the inactive uranium-mill tailings at Rifle, Colorado

    SciTech Connect (OSTI)

    Haywood, F.F.; Jacobs, D.J.; Ellis, B.S.; Hubbard, H.M. Jr.; Shinpaugh, W.H.

    1980-06-01

    Results of radiological surveys of two inactive uranium-mill sites near Rifle, Colorado, in May 1976 are presented. These sites are referred to as Old Rifle and New Rifle. The calculated /sup 226/Ra inventory of the latter site is much higher than at the older mill location. Data on above-ground measurements of gamma exposure rates, surface and near-surface concentration of /sup 226/Ra in soil and sediment samples, concentration of /sup 226/Ra in water, calculated subsurface distribution of /sup 226/Ra, and particulate radionuclide concentrations in air samples are given. The data serve to define the extent of contamination in the vicinity of the mill sites and their immediate surrounding areas with tailings particles. Results of these measurements were utilized as technical input for an engineering assessment of these two sites.

  15. DOE - Office of Legacy Management -- Rifle_D

    Office of Legacy Management (LM)

    Rifle, Colorado, Disposal Site UMTRCA Title I site rifled_map The Rifle Disposal Site, an Uranium Mill Tailings Radiation Control Act (UMTRCA) Title I disposal site, is licensed to DOE for long-term custody and managed by the Office of Legacy Management. The site transferred to the Office of Legacy Management in 2003 and requires routine inspection and maintenance, records-related activities, and stakeholder support. For more information about the Rifle site, view the fact sheet. Site Documents

  16. Microsoft Word - New Rifle EA.doc

    Office of Legacy Management (LM)

    DOE/EA-1406 Final Environmental Assessment of Ground Water Compliance at the New Rifle, Colorado, UMTRA Project Site July 2003 Work Performed Under DOE Contract No. DE-AC13-02GJ79491 for the U.S. Department of Energy Approved for public release; distribution is unlimited. U01341 DOE/EA-1406 Rev. 0 Final Environmental Assessment of Ground Water Compliance at the New Rifle, Colorado, UMTRA Project Site July 2003 Prepared by U.S. Department of Energy Grand Junction Office Grand Junction, Colorado

  17. DOE - Office of Legacy Management -- Rifle_D

    Office of Legacy Management (LM)

    Disposal Site Key Documents and Links All documents are Adobe Acrobat files. pdf_icon Key Documents Fact Sheet 2014 Annual Site Inspection and Monitoring Report for Uranium Mill Tailings Radiation Control Act Title I Disposal Sites-Rifle, Colorado, Disposal Site Long-Term Surveillance Plan for the Estes Gulch Disposal Site Near Rifle, Colorado Please be green. Do not print these documents unless absolutely necessary. Submit a FOIA Request for documents not available through this website. All

  18. DOE - Office of Legacy Management -- Rifle_Old

    Office of Legacy Management (LM)

    Old Rifle, Colorado, Processing Site UMTRCA Title I site rifleold_map The Old Rifle processing site, a Uranium Mill Tailings Radiation Control Act (UMTRCA) Title I site, is licensed to DOE for long-term custody and managed by the Office of Legacy Management. The site transferred to the Office of Legacy Management in 2003 and requires routine inspection and maintenance, records-related activities, and stakeholder support. For more information about the Old Rifle site, view the fact sheet. Site

  19. DOE - Office of Legacy Management -- Rifle_New

    Office of Legacy Management (LM)

    New Rifle, Colorado, Processing Site UMTRCA Title I site Rifle_New_Map_11/30/2011 The New Rifle processing site, a Uranium Mill Tailings Radiation Control Act (UMTRCA) Title I site, is licensed to DOE for long-term custody and managed by the Office of Legacy Management. The site transferred to the Office of Legacy Management in 2003 and requires routine inspection and maintenance, records-related activities, and stakeholder support. For more information about the New Rifle site, view the fact

  20. DOE - Office of Legacy Management -- Rifle Mill Site - CO 0-11

    Office of Legacy Management (LM)

    Rifle Mill Site - CO 0-11 FUSRAP Considered Sites Site: Rifle Mill Site (CO.0-11 ) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition: Radioactive Materials Handled: Primary Radioactive Materials Handled: Radiological Survey(s): Site Status: Also see Rifle, Colorado, New Processing Site Rifle, Colorado, Old Processing Site Documents Related to Rifle Mill Site 2009 Verification Monitoring Report for the Old and New Rifle, Colorado, Processing Sites;

  1. Spatial distribution of an uranium-respiring betaproteobacterium at the Rifle, CO field research site

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Koribanics, Nicole M.; Tuorto, Steven J.; Lopez-Chiaffarelli, Nora; McGuinness, Lora R.; Häggblom, Max M.; Williams, Kenneth H.; Long, Philip E.; Kerkhof, Lee J.; Morais, Paula V

    2015-04-13

    The Department of Energy’s Integrated Field-Scale Subsurface Research Challenge Site (IFRC) at Rifle, Colorado was created to address the gaps in knowledge on the mechanisms and rates of U(VI) bioreduction in alluvial sediments. Previous studies at the Rifle IFRC have linked microbial processes to uranium immobilization during acetate amendment. Several key bacteria believed to be involved in radionuclide containment have been described; however, most of the evidence implicating uranium reduction with specific microbiota has been indirect. Here, we report on the cultivation of a microorganism from the Rifle IFRC that reduces uranium and appears to utilize it as a terminalmore » electron acceptor for respiration with acetate as electron donor. Furthermore, this bacterium constitutes a significant proportion of the subsurface sediment community prior to biostimulation based on TRFLP profiling of 16S rRNA genes. 16S rRNA gene sequence analysis indicates that the microorganism is a betaproteobacterium with a high similarity to Burkholderia fungorum. This is, to our knowledge, the first report of a betaproteobacterium capable of uranium respiration. Our results indicate that this microorganism occurs commonly in alluvial sediments located between 3-6 m below ground surface at Rifle and may play a role in the initial reduction of uranium at the site.« less

  2. Spatial distribution of an uranium-respiring betaproteobacterium at the Rifle, CO field research site

    SciTech Connect (OSTI)

    Koribanics, Nicole M.; Tuorto, Steven J.; Lopez-Chiaffarelli, Nora; McGuinness, Lora R.; Hggblom, Max M.; Williams, Kenneth H.; Long, Philip E.; Kerkhof, Lee J.; Morais, Paula V

    2015-04-13

    The Department of Energys Integrated Field-Scale Subsurface Research Challenge Site (IFRC) at Rifle, Colorado was created to address the gaps in knowledge on the mechanisms and rates of U(VI) bioreduction in alluvial sediments. Previous studies at the Rifle IFRC have linked microbial processes to uranium immobilization during acetate amendment. Several key bacteria believed to be involved in radionuclide containment have been described; however, most of the evidence implicating uranium reduction with specific microbiota has been indirect. Here, we report on the cultivation of a microorganism from the Rifle IFRC that reduces uranium and appears to utilize it as a terminal electron acceptor for respiration with acetate as electron donor. Furthermore, this bacterium constitutes a significant proportion of the subsurface sediment community prior to biostimulation based on TRFLP profiling of 16S rRNA genes. 16S rRNA gene sequence analysis indicates that the microorganism is a betaproteobacterium with a high similarity to Burkholderia fungorum. This is, to our knowledge, the first report of a betaproteobacterium capable of uranium respiration. Our results indicate that this microorganism occurs commonly in alluvial sediments located between 3-6 m below ground surface at Rifle and may play a role in the initial reduction of uranium at the site.

  3. Rifle, Colorado, Processing Sites and Disposal Site Fact Sheet

    Office of Legacy Management (LM)

    5 Fact Sheet UMTRCA Title I UMTRCA Title I Rifle, Colorado, Processing Sites and Disposal Site This fact sheet provides information about the Uranium Mill Tailings Radiation Control Act of 1978 Title I processing sites and disposal site near Rifle, Colorado. These sites are managed by the U.S. Department of Energy Office of Legacy Management. Locations of the Rife Processing Sites and Disposal Site Site Description and History Two former uranium and vanadium processing sites are located near the

  4. Experimental investigation on heat transfer and frictional characteristics of vertical upward rifled tube in supercritical CFB boiler

    SciTech Connect (OSTI)

    Yang, Dong; Pan, Jie; Zhu, Xiaojing; Bi, Qincheng; Chen, Tingkuan; Zhou, Chenn Q.

    2011-02-15

    Water wall design is a key issue for supercritical Circulating Fluidized Bed (CFB) boiler. On account of the good heat transfer performance, rifled tube is applied in the water wall design of a 600 MW supercritical CFB boiler in China. In order to investigate the heat transfer and frictional characteristics of the rifled tube with vertical upward flow, an in-depth experiment was conducted in the range of pressure from 12 to 30 MPa, mass flux from 230 to 1200 kg/(m{sup 2} s), and inner wall heat flux from 130 to 720 kW/m{sup 2}. The wall temperature distribution and pressure drop in the rifled tube were obtained in the experiment. The normal, enhanced and deteriorated heat transfer characteristics were also captured. In this paper, the effects of pressure, inner wall heat flux and mass flux on heat transfer characteristics are analyzed, the heat transfer mechanism and the frictional resistance performance are discussed, and the corresponding empirical correlations are presented. The experimental results show that the rifled tube can effectively prevent the occurrence of departure from nucleate boiling (DNB) and keep the tube wall temperature in a permissible range under the operating condition of supercritical CFB boiler. (author)

  5. Remedial action plan and site design for stabilization of the inactive uranium mill tailings sites at Rifle, Colorado: Final report

    SciTech Connect (OSTI)

    Not Available

    1992-02-01

    This volume contains Appendix F, bid schedule and specifications for remedial action on three sites: Old Rifle processing site; New Rifle processing site and Estes Gulch disposal site.

  6. Surface Water Sampling | Open Energy Information

    Open Energy Info (EERE)

    Surface Water Sampling Details Activities (3) Areas (2) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Field Techniques Exploration Sub Group: Field...

  7. Category:Surface Water Sampling | Open Energy Information

    Open Energy Info (EERE)

    Surface Water Sampling Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Surface Water Sampling page? For detailed information on...

  8. Ecological Screening Values for Surface Water, Sediment, and...

    Office of Scientific and Technical Information (OSTI)

    Ecological Screening Values for Surface Water, Sediment, and Soil Friday, G. P. 54 ENVIRONMENTAL SCIENCES; SOILS; SURFACE WATERS; SEDIMENTS; ECOLOGICAL CONCENTRATION; ENVIRONMENTAL...

  9. Remedial action plan and site design for stabilization of the inactive uranium mill tailings sites at Rifle, Colorado: Final report. Volume 3, Appendix F, Final design, specifications, and drawings

    SciTech Connect (OSTI)

    Not Available

    1992-02-01

    This volume contains Appendix F, bid schedule and specifications for remedial action on three sites: Old Rifle processing site; New Rifle processing site and Estes Gulch disposal site.

  10. Water Quality Surface and Ground | Open Energy Information

    Open Energy Info (EERE)

    Water Quality Surface and Ground Jump to: navigation, search Retrieved from "http:en.openei.orgwindex.php?titleWaterQualitySurfaceandGround&oldid612197" Feedback...

  11. Appendix D Surface Water and Ground Water Time-Concentration Plots,

    Office of Legacy Management (LM)

    Surface Water and Ground Water Time-Concentration Plots, Stream Discharge Measurements, Ground Water Level Data, and Ground Water Well Hydrographs This page intentionally left blank Contents Section .................................................................................. Surface Water Time-Concentration Plots D1.O ............................................................................................... Stream Discharge Measurements D2.0

  12. Texas Surface Water Quality Standards Webpage | Open Energy Informatio...

    Open Energy Info (EERE)

    Not Provided DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for Texas Surface Water Quality Standards Webpage Citation Texas Commission on...

  13. Montana Surface Water Application for Beneficial Use (DNRC Form...

    Open Energy Info (EERE)

    for Beneficial Use (DNRC Form 600 GW) Citation Montana Department of Natural Resources & Conservation. Form: Montana Surface Water Application for Beneficial Use (DNRC Form 600...

  14. Montana Surface Water Application for Beneficial Use (DNRC Form...

    Open Energy Info (EERE)

    Beneficial Use (DNRC Form 600 SW) Citation Montana Department of Natural Resources and Conservation. Form: Montana Surface Water Application for Beneficial Use (DNRC Form 600...

  15. Surface Water Sampling At Raft River Geothermal Area (1973) ...

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Water Sampling At Raft River Geothermal Area (1973) Exploration Activity Details Location...

  16. Surface Water Sampling At Chena Geothermal Area (Holdmann, Et...

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Water Sampling At Chena Geothermal Area (Holdmann, Et Al., 2006) Exploration Activity...

  17. Solar Water Splitting: Putting an Extra "Eye" on Surface Reactions...

    Office of Science (SC) Website

    Solar Water Splitting: Putting an Extra "Eye" on Surface Reactions that Store Sunlight as Fuel Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights ...

  18. EIS-0132: Remedial Actions at the Former Union Carbide Corp. Uranium Mill Sites, Rifle, Garfield County, Colorado

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy developed this statement to evaluate and compare the environmental impacts of remediating the residual radioactive materials left at the inactive uranium tailing sites in Rifle, Colorado.

  19. Structure of water adsorbed on a mica surface

    SciTech Connect (OSTI)

    Park, Sung-Ho; Sposito, Garrison

    2002-01-29

    Monte Carlo simulations of hydration water on the mica (001) surface under ambient conditions revealed water molecules bound closely to the ditrigonal cavities in the surface, with a lateral distribution of approximately one per cavity, and water molecules interposed between K{sup +} counter ions in a layer situated about 2.5 {angstrom} from a surface O along a direction normal to the (001) plane. The calculated water O density profile was in quantitative agreement with recent X-ray reflectivity measurements indicating strong lateral ordering of the hydration water but liquid-like disorder otherwise.

  20. Remedial action plan and site design for stabilization of the inactive uranium mill tailings sites at Rifle, Colorado

    SciTech Connect (OSTI)

    Not Available

    1992-02-01

    This appendix assesses the present conditions and data gathered about the two inactive uranium mill tailings sites near Rifle, Colorado, and the designated disposal site six miles north of Rifle in the area of Estes Gulch. It consolidates available engineering, radiological, geotechnical, hydrological, meteorological, and other information pertinent to the design of the Remedial Action Plan (RAP). The data characterize conditions at the mill, tailings, and disposal site so that the Remedial Action Contractor (RAC) may complete final designs for the remedial actions.

  1. Speciation of Uranium in Biologically Reduced Sediments in the Old Rifle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aquifer | Stanford Synchrotron Radiation Lightsource Speciation of Uranium in Biologically Reduced Sediments in the Old Rifle Aquifer Wednesday, May 16, 2012 - 1:30pm SSRL Conference Room 137-322 Juan S. Lezama Pacheco The speciation and dynamics of Uranium(IV) in naturally and artificially bioreduced sediments, as well as its local nanometer-to-millimeter scale physical and chemical environment, controls its stability, susceptibility to oxidation, and subsequent transport behavior in

  2. WAC - 173-210A Water Quality Standards for Surface Waters of...

    Open Energy Info (EERE)

    0A Water Quality Standards for Surface Waters of the State of Washington Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation:...

  3. Nano-Cone Textures Generate Extremely "Robust" Water- Repellant Surfaces

    SciTech Connect (OSTI)

    2013-10-30

    High-speed video of water droplets bouncing off a surface textured with nanocones.The scientists filmed the droplets using a camera capable of capturing 30,000 frames per second.

  4. Hawaii Application for Surface Water Use Permit for Proposed...

    Open Energy Info (EERE)

    for Proposed New Use in a Designated Surface Water Management Area (DLNR Form SWUPA-N) Jump to: navigation, search OpenEI Reference LibraryAdd to library Form: Hawaii...

  5. EA-1093: Surface Water Drainage System, Golden, Colorado

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of the proposal to correct deficiencies in, and then to maintain, the surface water drainage system serving the U.S. Department of Energy's Rocky Flats...

  6. New Mexico Surface Water Quality Bureau Federal Dredge and Fill...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: New Mexico Surface Water Quality Bureau Federal Dredge and Fill Permits webpage Author New Mexico...

  7. Fermilab | Tritium at Fermilab | Tritium in Surface Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Water Fermilab map Fermilab has conducted an environmental monitoring program on site for roughly 40 years. In November of 2005, for the first time, we detected low levels of tritium in Indian Creek, one of three creeks that travel through the Fermilab site. Low but measurable levels of tritium continue to be detected in Indian Creek. All tritium levels found on site are well below any federal health and environmental standards. The Department of Energy standard for surface water is

  8. An Ontology Design Pattern for Surface Water Features

    SciTech Connect (OSTI)

    Sinha, Gaurav; Mark, David; Kolas, Dave; Varanka, Dalia; Romero, Boleslo E; Feng, Chen-Chieh; Usery, Lynn; Liebermann, Joshua; Sorokine, Alexandre

    2014-01-01

    Surface water is a primary concept of human experience but concepts are captured in cultures and languages in many different ways. Still, many commonalities can be found due to the physical basis of many of the properties and categories. An abstract ontology of surface water features based only on those physical properties of landscape features has the best potential for serving as a foundational domain ontology. It can then be used to systematically incor-porate concepts that are specific to a culture, language, or scientific domain. The Surface Water ontology design pattern was developed both for domain knowledge distillation and to serve as a conceptual building-block for more complex surface water ontologies. A fundamental distinction is made in this on-tology between landscape features that act as containers (e.g., stream channels, basins) and the bodies of water (e.g., rivers, lakes) that occupy those containers. Concave (container) landforms semantics are specified in a Dry module and the semantics of contained bodies of water in a Wet module. The pattern is imple-mented in OWL, but Description Logic axioms and a detailed explanation is provided. The OWL ontology will be an important contribution to Semantic Web vocabulary for annotating surface water feature datasets. A discussion about why there is a need to complement the pattern with other ontologies, es-pecially the previously developed Surface Network pattern is also provided. Fi-nally, the practical value of the pattern in semantic querying of surface water datasets is illustrated through a few queries and annotated geospatial datasets.

  9. EIS-0112: Rifle to San Juan 345-kV Transmission Line and Associated Facilities

    Broader source: Energy.gov [DOE]

    The U.S. Department of Agriculture - Rural Electrification Administration developed this statement to evaluate the environmental impacts of the Colorado-Ute Electric Association Inc. and the U.s. Department of Energy's Western Area Power Administration (WAPA) constructing and operating a 345-kilovolt transmission line from Rifle, Colorado, to the San Juan Generating Station near Farmington, New Mexico. WAPA served as a cooperating agency in the preparation of this statement and adopted it on 10/30/1984. WAPA assumed the lead role for project implementation after issuance of the final statement.

  10. Energy Landscape of Water and Ethanol on Silica Surfaces

    SciTech Connect (OSTI)

    Wu, Di; Guo, Xiaofeng; Sun, Hui; Navrotsky, Alexandra

    2015-06-26

    Fundamental understanding of small moleculesilica surface interactions at their interfaces is essential for the scientific, technological, and medical communities. We report direct enthalpy of adsorption (?hads) measurements for ethanol and water vapor on porous silica glass (CPG-10), in both hydroxylated and dehydroxylated (hydrophobic) forms. Results suggest a spectrum of energetics as a function of coverage, stepwise for ethanol but continuous for water. The zero-coverage enthalpy of adsorption for hydroxylated silica shows the most exothermic enthalpies for both water (-72.7 3.1 kJ/mol water) and ethanol (-78.0 1.9 kJ/mol ethanol). The water adsorption enthalpy becomes less exothermic gradually until reaching its only plateau (-20.7 2.2 kJ/mol water) reflecting water clustering on a largely hydrophobic surface, while the enthalpy of ethanol adsorption profile presents two well separated plateaus, corresponding to strong chemisorption of ethanol on adsorbate-free silica surface (-66.4 4.8 kJ/mol ethanol), and weak physisorption of ethanol on ethanol covered silica (-4.0 1.6 kJ/mol ethanol). On the other hand, dehydroxylation leads to missing watersilica interactions, whereas the number of ethanol binding sites is not impacted. The isotherms and partial molar properties of adsorption suggest that water may only bind strongly onto the silanols (which are a minor species on silica glass), whereas ethanol can interact strongly with both silanols and the hydrophobic areas of the silica surface.

  11. Energy Landscape of Water and Ethanol on Silica Surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Di; Guo, Xiaofeng; Sun, Hui; Navrotsky, Alexandra

    2015-06-26

    Fundamental understanding of small molecule–silica surface interactions at their interfaces is essential for the scientific, technological, and medical communities. We report direct enthalpy of adsorption (Δhads) measurements for ethanol and water vapor on porous silica glass (CPG-10), in both hydroxylated and dehydroxylated (hydrophobic) forms. Results suggest a spectrum of energetics as a function of coverage, stepwise for ethanol but continuous for water. The zero-coverage enthalpy of adsorption for hydroxylated silica shows the most exothermic enthalpies for both water (-72.7 ± 3.1 kJ/mol water) and ethanol (-78.0 ± 1.9 kJ/mol ethanol). The water adsorption enthalpy becomes less exothermic gradually until reachingmore » its only plateau (-20.7 ± 2.2 kJ/mol water) reflecting water clustering on a largely hydrophobic surface, while the enthalpy of ethanol adsorption profile presents two well separated plateaus, corresponding to strong chemisorption of ethanol on adsorbate-free silica surface (-66.4 ± 4.8 kJ/mol ethanol), and weak physisorption of ethanol on ethanol covered silica (-4.0 ± 1.6 kJ/mol ethanol). On the other hand, dehydroxylation leads to missing water–silica interactions, whereas the number of ethanol binding sites is not impacted. The isotherms and partial molar properties of adsorption suggest that water may only bind strongly onto the silanols (which are a minor species on silica glass), whereas ethanol can interact strongly with both silanols and the hydrophobic areas of the silica surface.« less

  12. Radiolysis Concerns for Water Shielding in Fission Surface Power Applications

    SciTech Connect (OSTI)

    Schoenfeld, Michael P.; Anghaie, Samim

    2008-01-21

    This paper presents an overview of radiolysis concerns with regard to water shields for fission surface power. A review of the radiolysis process is presented and key parameters and trends are identified. From this understanding of the radiolytic decomposition of water, shield pressurization and corrosion are identified as the primary concerns. Existing experimental and modeling data addressing concerns are summarized. It was found that radiolysis of pure water in a closed volume results in minimal, if any net decomposition, and therefore reduces the potential for shield pressurization and corrosion.

  13. Water and Carbon Dioxide Adsorption at Olivine Surfaces

    SciTech Connect (OSTI)

    Kerisit, Sebastien N.; Bylaska, Eric J.; Felmy, Andrew R.

    2013-11-14

    Plane-wave density functional theory (DFT) calculations were performed to simulate water and carbon dioxide adsorption at the (010) surface of five olivine minerals, namely, forsterite (Mg2SiO4), calcio-olivine (Ca2SiO4), tephroite (Mn2SiO4), fayalite (Fe2SiO4), and Co-olivine (Co2SiO4). Adsorption energies per water molecule obtained from energy minimizations varied from -78 kJ mol-1 for fayalite to -128 kJ mol-1 for calcio-olivine at sub-monolayer coverage and became less exothermic as coverage increased. In contrast, carbon dioxide adsorption energies at sub-monolayer coverage ranged from -20 kJ mol-1 for fayalite to -59 kJ mol-1 for calcio-olivine. Therefore, the DFT calculations show a strong driving force for carbon dioxide displacement by water at the surface of all olivine minerals in a competitive adsorption scenario. Additionally, adsorption energies for both water and carbon dioxide were found to be more exothermic for the alkaline-earth (AE) olivines than for the transition-metal (TM) olivines and to not correlate with the solvation enthalpies of the corresponding divalent cations. However, a correlation was obtained with the charge of the surface divalent cation indicating that the more ionic character of the AE cations in the olivine structure relative to the TM cations leads to greater interactions with adsorbed water and carbon dioxide molecules at the surface and thus more exothermic adsorption energies for the AE olivines. For calcio-olivine, which exhibits the highest divalent cation charge of the five olivines, ab initio molecular dynamics simulations showed that this effect leads both water and carbon dioxide to react with the surface and form hydroxyl groups and a carbonate-like species, respectively.

  14. Surface Water Data at Los Alamos National Laboratory 1998 Water Year

    SciTech Connect (OSTI)

    D. A. Shaull; M. R. Alexander; R. P. Reynolds; C. T. McLean; R. P. Romero

    1999-02-01

    The principal investigators collected and computed surface water discharge data from 19 stream-gaging stations that cover most of Los Alamos National Laboratory. Also included are discharge data from three springs that flow into Caiion de Vane.

  15. Heterogeneous nucleation of naphthalene vapor on water surface

    SciTech Connect (OSTI)

    Smolik, J.; Schwarz, J.

    1997-01-15

    Transfer processes between drops and gas play an important role in many natural and industrial processes, as absorption of gaseous pollutants by water drops in the atmosphere, combustion of fuel droplets, spray drying, synthesis of nanopowders, wet-dry desulfurization or extinguishing of hot combustion gases. The evaporation of a water drop into a ternary gaseous mixture of air, steam, and naphthalene vapor was investigated. The experimental results were compared with a theoretical prediction based on a numerical solution of coupled boundary layer equations for heat and mass transfer from a drop moving in ternary gas. In the experiments the naphthalene vapor condensed on the water drop as a supercooled liquid even at temperatures far below the melting point of naphthalene. The condensation on drop surface is discussed in terms of classical theory of heterogeneous nucleation on smooth surfaces.

  16. Surface Water Data at Los Alamos National Laboratory 2000 Water Year

    SciTech Connect (OSTI)

    D.A.Shaull; M.R.Alexander; R.P.Reynolds; R.P.Romero; E.T.Riebsomer; C.T.McLean

    2001-06-02

    The principal investigators collected and computed surface water discharge data from 23 stream-gaging stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs, two that flow into Canon del Valle and one that flows into Water Canyon.

  17. Surface Water Data at Los Alamos National Laboratory 2006 Water Year

    SciTech Connect (OSTI)

    R.P. Romero, D. Ortiz, G. Kuyumjian

    2007-08-01

    The principal investigators collected and computed surface water discharge data from 44 stream-gaging stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs--two that flow into Canon de Valle and one that flows into Water Canyon--and peak flow data for 44 stations.

  18. Surface Water Data at Los Alamos National Laboratory: 2002 Water Year

    SciTech Connect (OSTI)

    D.A. Shaull; D. Ortiz; M.R. Alexander; R.P. Romero

    2003-03-03

    The principal investigators collected and computed surface water discharge data from 34 stream-gaging stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs--two that flow into Canon de Valle and one that flows into Water Canyon--and peak flow data from 16 stations.

  19. Surface Water Data at Los Alamos National Laboratory: 1999 Water Year

    SciTech Connect (OSTI)

    D. A. Shaull; M. R. Alexander; R. P. Reynolds; C. T. McLean; R. P. Romero

    2000-04-01

    The principal investigators collected and computed surface water discharge data from 22 stream-gaging stations that cover most of Los Alamos National Laboratory with one at Bandelier National Monument. Also included are discharge data from three springs that flow into Canon de Valle and nine partial-record storm water stations.

  20. Surface water data at Los Alamos National Laboratory: 2009 water year

    SciTech Connect (OSTI)

    Ortiz, David; McCullough, Betsy

    2010-05-01

    The principal investigators collected and computed surface water discharge data from 73 stream-gage stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs two that flow into Caon de Valle and one that flows into Water Canyon.

  1. Surface water data at Los Alamos National Laboratory: 2008 water year

    SciTech Connect (OSTI)

    Ortiz, David; Cata, Betsy; Kuyumjian, Gregory

    2009-09-01

    The principal investigators collected and computed surface water discharge data from 69 stream-gage stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs two that flow into Caon de Valle and one that flows into Water Canyon.

  2. Observation of dynamic water microadsorption on Au surface

    SciTech Connect (OSTI)

    Huang, Xiaokang, E-mail: xiaokang.huang@tqs.com; Gupta, Gaurav; Gao, Weixiang; Tran, Van; Nguyen, Bang; McCormick, Eric; Cui, Yongjie; Yang, Yinbao; Hall, Craig; Isom, Harold [TriQuint Semiconductor, Inc., 500 W Renner Road, Richardson, Texas 75080 (United States)

    2014-05-15

    Experimental and theoretical research on water wettability, adsorption, and condensation on solid surfaces has been ongoing for many decades because of the availability of new materials, new detection and measurement techniques, novel applications, and different scales of dimensions. Au is a metal of special interest because it is chemically inert, has a high surface energy, is highly conductive, and has a relatively high melting point. It has wide applications in semiconductor integrated circuitry, microelectromechanical systems, microfluidics, biochips, jewelry, coinage, and even dental restoration. Therefore, its surface condition, wettability, wear resistance, lubrication, and friction attract a lot of attention from both scientists and engineers. In this paper, the authors experimentally investigated Au{sub 2}O{sub 3} growth, wettability, roughness, and adsorption utilizing atomic force microscopy, scanning electron microscopy, reflectance spectrometry, and contact angle measurement. Samples were made using a GaAs substrate. Utilizing a super-hydrophilic Au surface and the proper surface conditions of the surrounding GaAs, dynamic microadsorption of water on the Au surface was observed in a clean room environment. The Au surface area can be as small as 12??m{sup 2}. The adsorbed water was collected by the GaAs groove structure and then redistributed around the structure. A model was developed to qualitatively describe the dynamic microadsorption process. The effective adsorption rate was estimated by modeling and experimental data. Devices for moisture collection and a liquid channel can be made by properly arranging the wettabilities or contact angles of different materials. These novel devices will be very useful in microfluid applications or biochips.

  3. Remedial action plan and site design for stabilization of the inactive uranium mill tailings sites at Rifle, Colorado. Volume 2, Appendices D and E: Final report

    SciTech Connect (OSTI)

    Not Available

    1992-02-01

    This appendix assesses the present conditions and data gathered about the two inactive uranium mill tailings sites near Rifle, Colorado, and the designated disposal site six miles north of Rifle in the area of Estes Gulch. It consolidates available engineering, radiological, geotechnical, hydrological, meteorological, and other information pertinent to the design of the Remedial Action Plan (RAP). The data characterize conditions at the mill, tailings, and disposal site so that the Remedial Action Contractor (RAC) may complete final designs for the remedial actions.

  4. Sedimentology of the Mesaverde Formation at Rifle Gap, Colorado and implications for gas-bearing intervals in the subsurface

    SciTech Connect (OSTI)

    Lorenz, J.C.

    1982-03-01

    The exposures of the Mesaverde Formation at Rifle Gap, Colorado, are of a regressive series of marine to fluvial deposits about 1650 m (5000 ft) thick. Grading up out of the marine Mancos Shale, the blanket shoreline sandstones of the Corcoran, Cozzette, and Rollins Sandstones record substages of the regression as delta lobes were activated and abandoned in northwestern Colorado during Late Cretaceous time. The overlying coals, sandstones, and carbonaceous mudstones were deposited on the paludal lower delta plain behind the shoreline. Meandering fluvial systems prograded over the paludal deposits. These systems deposited point-bar sandstones and overbank mudstones and siltstones in composite meander-belt trends, some of which are now gas-bearing, low-permeability reservoirs. Reorientation of the paleogeography during the Laramide orogeny (contemporaneous with fluvial deposition) probably changed the orientation of the meander belt trends. The uppermost sandstones at Rifle Gap, including the Ohio Creek conglomerate, are interpreted as shoreline deposits of a transgression that has been previously unrecognized in the area. Most of the record of this transgression has been destroyed by pre-Eocene erosion. The outcrops at Rifle Gap provide a basis for interpreting subsurface deposis in the Department of Energy's Western Gas Sands Project Multi-Well Experiment, 12 miles away.

  5. Oil spreading in surface waters with an ice cover

    SciTech Connect (OSTI)

    Yapa, P.D.; Weerasuriya, S.A.; Belaskas, D.P.; Chowdhury, T.

    1993-02-01

    A study of oil spreading in surface waters in the presence of a floating ice cover is presented. The ice can be solid or fragmented. Both axi-symmetrical and uni-directional spreading are studied. The report describes the analytical and numerical model development, the experimental set-up, results from the laboratory experiments, and their comparison with the derived theory and the numerical simulation. To analyze the spreading of oil under solid ice, new equations are derived. These equations consider gravity (buoyancy) - inertia phase, gravity (buoyancy) - viscous phase, and the termination of spreading during the buoyancy - surface tension phase. The derivation considers both the constant discharge mode and the constant volume mode. Therefore, a complete description of the spreading phenomena from the time of initial spill to termination of spreading is presented. The emphasis of the study is on the dominant spreading mechanism for oil under ice, which is the buoyancy-viscous phase.

  6. Novel Americium Treatment Process for Surface Water and Dust Suppression Water

    SciTech Connect (OSTI)

    Tiepel, E.W.; Pigeon, P.; Nesta, S.; Anderson, J.

    2006-07-01

    The Rocky Flats Environmental Technology Site (RFETS), a former nuclear weapons production plant, has been remediated under CERCLA and decommissioned to become a National Wildlife Refuge. The site conducted this cleanup effort under the Rocky Flats Cleanup Agreement (RFCA) that established limits for the discharge of surface and process waters from the site. At the end of 2004, while a number of process buildings were undergoing decommissioning, routine monitoring of a discharge pond (Pond A-4) containing approximately 28 million gallons of water was discovered to have been contaminated with a trace amount of Americium-241 (Am-241). While the amount of Am-241 in the pond waters was very low (0.5 - 0.7 pCi/l), it was above the established Colorado stream standard of 0.15 pCi/l for release to off site drainage waters. The rapid successful treatment of these waters to the regulatory limit was important to the site for two reasons. The first was that the pond was approaching its hold-up limit. Without rapid treatment and release of the Pond A-4 water, typical spring run-off would require water management actions to other drainages onsite or a mass shuttling of water for disposal. The second reason was that this type of contaminated water had not been treated to the stringent stream standard at Rocky Flats before. Technical challenges in treatment could translate to impacts on water and secondary waste management, and ultimately, cost impacts. All of the technical challenges and specific site criteria led to the conclusion that a different approach to the treatment of this problem was necessary and a crash treatability program to identify applicable treatment techniques was undertaken. The goal of this program was to develop treatment options that could be implemented very quickly and would result in the generation of no high volume secondary waste that would be costly to dispose. A novel chemical treatment system was developed and implemented at the RFETS to treat Am-241 contaminated pond water, surface run-off and D and D dust suppression water during the later stages of the D and D effort at Rocky Flats. This novel chemical treatment system allowed for highly efficient, high-volume treatment of all contaminated waste waters to the very low stream standard of 0.15 pCi/1 with strict compliance to the RFCA discharge criteria for release to off-site surface waters. The rapid development and implementation of the treatment system avoided water management issues that would have had to be addressed if contaminated water had remained in Pond A-4 into the Spring of 2005. Implementation of this treatment system for the Pond A-4 waters and the D and D waters from Buildings 776 and 371 enabled the site to achieve cost-effective treatment that minimized secondary waste generation, avoiding the need for expensive off-site water disposal. Water treatment was conducted for a cost of less than $0.20/gal which included all development costs, capital costs and operational costs. This innovative and rapid response effort saved the RFETS cleanup program well in excess of $30 million for the potential cost of off-site transportation and treatment of radioactive liquid waste. (authors)

  7. Surface Chemistry of GaP(001) and InP(001) in Contact with Water...

    Office of Scientific and Technical Information (OSTI)

    Surface Chemistry of GaP(001) and InP(001) in Contact with Water Citation Details In-Document Search Title: Surface Chemistry of GaP(001) and InP(001) in Contact with Water You...

  8. Diagnosis of Solar Water Heaters Using Solar Storage Tank Surface Temperature Data: Preprint

    SciTech Connect (OSTI)

    Burch, J.; Magnuson, L.; Barker, G.; Bullwinkel, M.

    2009-04-01

    Study of solar water heaters by using surface temperature data of solar storage tanks to diagnose proper operations.

  9. Linear relationship between water wetting behavior and microscopic interactions of super-hydrophilic surfaces

    SciTech Connect (OSTI)

    Liu, Jian; Guo, Pan; University of Chinese Academy of Sciences, Beijing 100049 ; Wang, Chunlei; Shi, Guosheng Fang, Haiping

    2013-12-21

    Using molecular dynamics simulations, we show a fine linear relationship between surface energies and microscopic Lennard-Jones parameters of super-hydrophilic surfaces. The linear slope of the super-hydrophilic surfaces is consistent with the linear slope of the super-hydrophobic, hydrophobic, and hydrophilic surfaces where stable water droplets can stand, indicating that there is a universal linear behavior of the surface energies with the water-surface van der Waals interaction that extends from the super-hydrophobic to super-hydrophilic surfaces. Moreover, we find that the linear relationship exists for various substrate types, and the linear slopes of these different types of substrates are dependent on the surface atom density, i.e., higher surface atom densities correspond to larger linear slopes. These results enrich our understanding of water behavior on solid surfaces, especially the water wetting behaviors on uncharged super-hydrophilic metal surfaces.

  10. Microbiological, Geochemical and Hydrologic Processes Controlling Uranium Mobility: An Integrated Field-Scale Subsurface Research Challenge Site at Rifle, Colorado, Quality Assurance Project Plan

    SciTech Connect (OSTI)

    Fix, N. J.

    2008-01-07

    The U.S. Department of Energy (DOE) is cleaning up and/or monitoring large, dilute plumes contaminated by metals, such as uranium and chromium, whose mobility and solubility change with redox status. Field-scale experiments with acetate as the electron donor have stimulated metal-reducing bacteria to effectively remove uranium [U(VI)] from groundwater at the Uranium Mill Tailings Site in Rifle, Colorado. The Pacific Northwest National Laboratory and a multidisciplinary team of national laboratory and academic collaborators has embarked on a research proposed for the Rifle site, the object of which is to gain a comprehensive and mechanistic understanding of the microbial factors and associated geochemistry controlling uranium mobility so that DOE can confidently remediate uranium plumes as well as support stewardship of uranium-contaminated sites. This Quality Assurance Project Plan provides the quality assurance requirements and processes that will be followed by the Rifle Integrated Field-Scale Subsurface Research Challenge Project.

  11. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Old and New Rifle, Colorado, Processing Sites August 2013 LMS/RFN/RFO/S00613 This page intentionally left blank U.S. Department of Energy DVP-June 2013, Rifle, Colorado August 2013 RIN 13065380 Page i Contents Sampling Event Summary ...............................................................................................................1 Sample Location Map, New Rifle, Colorado, Processing Site ........................................................5 Sample Location Map, Old Rifle,

  12. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Rifle, Colorado, New and Old Processing Sites January 2014 LMS/RFN/RFO/S01113 This page intentionally left blank U.S. Department of Energy DVP-November 2013, Rifle, Colorado January 2014 RIN 13115731 Page i Contents Sampling Event Summary ...............................................................................................................1 New Rifle, Colorado, Processing Site, Sample Location Map ........................................................5 Old Rifle, Colorado, Processing

  13. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Old and New Rifle, Colorado, Processing Sites January 2015 LMS/RFN/RFO/S01114 This page intentionally left blank U.S. Department of Energy DVP-November 2014, Rifle, Colorado January 2015 RINs 14106568 and 14106569 Page i Contents Sampling Event Summary ...............................................................................................................1 New Rifle, Colorado, Processing Site, Planned Sampling Map ......................................................3 Old Rifle,

  14. Remedial action plan and site conceptual design for stabilization of the inactive uranium mill tailings sites at Rifle, Colorado. Appendix D, Final report

    SciTech Connect (OSTI)

    1992-02-01

    This appendix assesses the present conditions and data gathered about the two designated inactive uranium mill tailings sites near Rifle, Colorado, and the proposed disposal site six miles north of Rifle in the area of Estes Gulch. It consolidates available engineering, radiological, geotechnical, hydrological, meteorological, and other information pertinent to the design of the Remedial Action Plan (RAP). The data characterize conditions at the mill, tailings, and disposal site so that the Remedial Action Contractor (RAC) may complete final designs for the remedial actions.

  15. Effect of Surface Oxidation on Interfacial Water Structure at a Pyrite (100) Surface as Studied by Molecular Dynamics Simulation

    SciTech Connect (OSTI)

    Jin, Jiaqi; Miller, Jan D.; Dang, Liem X.; Wick, Collin D.

    2015-06-01

    In the first part of this paper, a Scanning Electron Microscopy and contact angle study of a pyrite surface (100) is reported describing the relationship between surface oxidation and the hydrophilic surface state. In addition to these experimental results, the following simulated surface states were examined using Molecular Dynamics Simulation (MDS): fresh unoxidized (100) surface; polysulfide at the (100) surface; elemental sulfur at the (100) surface. Crystal structures for the polysulfide and elemental sulfur at the (100) surface were simulated using Density Functional Theory (DFT) quantum chemical calculations. The well known oxidation mechanism which involves formation of a metal deficient layer was also described with DFT. Our MDS results of the behavior of interfacial water at the fresh and oxidized pyrite (100) surfaces without/with the presence of ferric hydroxide include simulated contact angles, number density distribution for water, water dipole orientation, water residence time, and hydrogen-bonding considerations. The significance of the formation of ferric hydroxide islands in accounting for the corresponding hydrophilic surface state is revealed not only from experimental contact angle measurements but also from simulated contact angle measurements using MDS. The hydrophilic surface state developed at oxidized pyrite surfaces has been described by MDS, on which basis the surface state is explained based on interfacial water structure. The Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences (BES), of the DOE funded work performed by Liem X. Dang. Battelle operates the Pacific Northwest National Laboratory for DOE. The calculations were carried out using computer resources provided by BES.

  16. NMAC 20.6.2 Ground and Surface Water Protection | Open Energy...

    Open Energy Info (EERE)

    6.2 Ground and Surface Water Protection Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: NMAC 20.6.2 Ground and Surface...

  17. Improved Design Tools for Surface Water and Standing Column Well Heat Pump Systems

    Broader source: Energy.gov [DOE]

    This project will improve the capability of engineers to design heat pump systems that utilize surface water or standing column wells (SCW) as their heat sources and sinks.

  18. Microsoft Word - 09112697 DVP.doc

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Rifle (Old), Colorado, Processing Site January 2010 LMS/RFO/S01109 This page intentionally left blank U.S. Department of Energy DVP-November 2009, Rifle, Colorado January 2010 RIN 09112697 Page i Contents Sampling Event Summary ...............................................................................................................1 Old and New Rifle, Colorado, Processing Sites Sample Location Map..........................................3 Data Assessment

  19. Surface Water Sampling At Chena Geothermal Area (Waring, Et Al...

    Open Energy Info (EERE)

    calcium and magnesium concentrations were measured, with elevated levels of silica and sulfate. Surface fumarole gases were tested with a flame to indicate carbon dioxide...

  20. Method of and device for detecting oil pollutions on water surfaces

    DOE Patents [OSTI]

    Belov, Michael Leonidovich; Gorodnichev, Victor Aleksandrovich; Kozintsev, Valentin Ivanovich; Smimova, Olga Alekseevna; Fedotov, Yurii Victorovich; Khroustaleva, Anastasiva Michailovnan

    2008-08-26

    Detection of oil pollution on water surfaces includes providing echo signals obtained from optical radiation of a clean water area at two wavelengths, optically radiating an investigated water area at two wavelengths and obtaining echo signals from the optical radiation of the investigated water area at the two wavelengths, comparing the echo signals obtained from the radiation of the investigated area at two wavelengths with the echo signals obtained from the radiation of the clean water area, and based on the comparison, determining presence or absence of oil pollution in the investigated water area.

  1. Clean Boiler Water-side Heat Transfer Surfaces - Steam Tip Sheet #7

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on cleaning boiler water-side heat transfer surfaces provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  2. 5 CCR 1002-31 Basic Standards and Methodologies for Surface Water...

    Open Energy Info (EERE)

    to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: 5 CCR 1002-31 Basic Standards and Methodologies for Surface Water RegulationLegal Abstract...

  3. NMSA 72-5 Appropriation and Use of Surface Water | Open Energy...

    Open Energy Info (EERE)

    5 Appropriation and Use of Surface Water Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: NMSA 72-5 Appropriation and Use of...

  4. "Nanoengineered Surfaces for Efficiency Enhancements in Energy and Water",

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Professor Kripa Varansi, Massachusetts Institute of Technology | Princeton Plasma Physics Lab October 24, 2012, 4:15pm Colloquia MBG Auditorium "Nanoengineered Surfaces for Efficiency Enhancements in Energy and Water", Professor Kripa Varansi, Massachusetts Institute of Technology Thermal-fluid-surface interactions are ubiquitous in multiple industries including Energy, Water, Agriculture, Transportation, Electronics Cooling, Buildings, etc. Over the years, these systems have been

  5. Molecular Dynamics Simulation and Analysis of Interfacial Water at Selected Sulfide Mineral Surfaces under Anaerobic Conditions

    SciTech Connect (OSTI)

    Jin, Jiaqi; Miller, Jan D.; Dang, Liem X.

    2014-04-10

    In this paper, we report on a molecular dynamics simulation (MDS) study of the behavior of interfacial water at selected sulfide mineral surfaces under anaerobic conditions. The study revealed the interfacial water structure and wetting characteristics of the pyrite (100) surface, galena (100) surface, chalcopyrite (012) surface, sphalerite (110) surface, and molybdenite surfaces (i.e., the face, armchair-edge, and zigzag-edge surfaces), including simulated contact angles, relative number density profiles, water dipole orientations, hydrogen-bonding, and residence times. For force fields of the metal and sulfur atoms in selected sulfide minerals used in the MDS, we used the universal force field (UFF) and another set of force fields optimized by quantum chemical calculations for interactions with interfacial water molecules at selected sulfide mineral surfaces. Simulation results for the structural and dynamic properties of interfacial water molecules indicate the natural hydrophobic character for the selected sulfide mineral surfaces under anaerobic conditions as well as the relatively weak hydrophobicity for the sphalerite (110) surface and two molybdenite edge surfaces. Part of the financial support for this study was provided by the U.S. Department of Energy (DOE) under Basic Science Grant No. DE-FG-03-93ER14315. The Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences (BES), of the DOE, funded work performed by Liem X. Dang. Battelle operates Pacific Northwest National Laboratory for DOE. The calculations were carried out using computer resources provided by BES. The authors are grateful to Professor Tsun-Mei Chang for valuable discussions.

  6. Vapor deposition of water on graphitic surfaces: Formation of amorphous ice, bilayer ice, ice I, and liquid water

    SciTech Connect (OSTI)

    Lupi, Laura; Kastelowitz, Noah; Molinero, Valeria

    2014-11-14

    Carbonaceous surfaces are a major source of atmospheric particles and could play an important role in the formation of ice. Here we investigate through molecular simulations the stability, metastability, and molecular pathways of deposition of amorphous ice, bilayer ice, and ice I from water vapor on graphitic and atomless Lennard-Jones surfaces as a function of temperature. We find that bilayer ice is the most stable ice polymorph for small cluster sizes, nevertheless it can grow metastable well above its region of thermodynamic stability. In agreement with experiments, the simulations predict that on increasing temperature the outcome of water deposition is amorphous ice, bilayer ice, ice I, and liquid water. The deposition nucleation of bilayer ice and ice I is preceded by the formation of small liquid clusters, which have two wetting states: bilayer pancake-like (wetting) at small cluster size and droplet-like (non-wetting) at larger cluster size. The wetting state of liquid clusters determines which ice polymorph is nucleated: bilayer ice nucleates from wetting bilayer liquid clusters and ice I from non-wetting liquid clusters. The maximum temperature for nucleation of bilayer ice on flat surfaces, T{sub B}{sup max} is given by the maximum temperature for which liquid water clusters reach the equilibrium melting line of bilayer ice as wetting bilayer clusters. Increasing water-surface attraction stabilizes the pancake-like wetting state of liquid clusters leading to larger T{sub B}{sup max} for the flat non-hydrogen bonding surfaces of this study. The findings of this study should be of relevance for the understanding of ice formation by deposition mode on carbonaceous atmospheric particles, including soot.

  7. Phase Preference by Active, Acetate-Utilizing Bacteria at the Rifle, CO Integrated Field Research Challenge Site

    SciTech Connect (OSTI)

    Kerkhof, L.; Williams, K.H.; Long, P.E.; McGuinness, L.

    2011-02-21

    Previous experiments at the Rifle, Colorado Integrated Field Research Challenge (IFRC) site demonstrated that field-scale addition of acetate to groundwater reduced the ambient soluble uranium concentration. In this report, sediment samples collected before and after acetate field addition were used to assess the active microbes via {sup 13}C acetate stable isotope probing on 3 phases [coarse sand, fines (8-approximately 150 {micro}m), groundwater (0.2-8 {micro}m)] over a 24-day time frame. TRFLP results generally indicated a stronger signal in {sup 13}C-DNA in the 'fines' fraction compared to the sand and groundwater. Before the field-scale acetate addition, a Geobacter-like group primarily synthesized {sup 13}C-DNA in the groundwater phase, an alpha Proteobacterium primarily grew on the fines/sands, and an Acinetobacter sp. and Decholoromonas-like OTU utilized much of the {sup 13}C acetate in both groundwater and particle-associated phases. At the termination of the field-scale acetate addition, the Geobacter-like species was active on the solid phases rather than the groundwater, while the other bacterial groups had very reduced newly synthesized DNA signal. These findings will help to delineate the acetate utilization patterns of bacteria in the field and can lead to improved methods for stimulating distinct microbial populations in situ.

  8. Uranium Bioreduction Rates across Scales: Biogeochemical Hot Moments and Hot Spots during a Biostimulation Experiment at Rifle, Colorado

    SciTech Connect (OSTI)

    Bao, Chen; Wu, Hongfei; Li, Li; Newcomer, Darrell R.; Long, Philip E.; Williams, Kenneth H.

    2014-09-02

    We aim to understand the scale-dependent evolution of uranium bioreduction during a field experiment at a former uranium mill site near Rifle, Colorado. Acetate was injected to stimulate Fe-reducing bacteria (FeRB) and to immobilize aqueous U(VI) to insoluble U(IV). Bicarbonate was coinjected in half of the domain to mobilize sorbed U(VI). We used reactive transport modeling to integrate hydraulic and geochemical data and to quantify rates at the grid block (0.25 m) and experimental field scale (tens of meters). Although local rates varied by orders of magnitude in conjunction with biostimulation fronts propagating downstream, field-scale rates were dominated by those orders of magnitude higher rates at a few selected hot spots where Fe(III), U(VI), and FeRB were at their maxima in the vicinity of the injection wells. At particular locations, the hot moments with maximum rates negatively corresponded to their distance from the injection wells. Although bicarbonate injection enhanced local rates near the injection wells by a maximum of 39.4%, its effect at the field scale was limited to a maximum of 10.0%. We propose a rate-versus-measurement-length relationship (log R' = -0.63

  9. Surface water supply for the Clearlake, California Hot Dry Rock Geothermal Project

    SciTech Connect (OSTI)

    Jager, A.R.

    1996-03-01

    It is proposed to construct a demonstration Hot Dry Rock (HDR) geothermal plant in the vicinity of the City of Clearlake. An interim evaluation has been made of the availability of surface water to supply the plant. The evaluation has required consideration of the likely water consumption of such a plant. It has also required consideration of population, land, and water uses in the drainage basins adjacent to Clear Lake, where the HDR demonstration project is likely to be located. Five sources were identified that appear to be able to supply water of suitable quality in adequate quantity for initial filling of the reservoir, and on a continuing basis, as makeup for water losses during operation. Those sources are California Cities Water Company, a municipal supplier to the City of Clearlake; Clear Lake, controlled by Yolo County Flood Control and Water Conservation District; Borax Lake, controlled by a local developer; Southeast Regional Wastewater Treatment Plant, controlled by Lake County; and wells, ponds, and streams on private land. The evaluation involved the water uses, water rights, stream flows, precipitation, evaporation, a water balance, and water quality. In spite of California`s prolonged drought, the interim conclusion is that adequate water is available at a reasonable cost to supply the proposed HDR demonstration project.

  10. The effect of plutonium dioxide water surface coverage on the generation of hydrogen and oxygen

    SciTech Connect (OSTI)

    Veirs, Douglas K.; Berg, John M.; Crowder, Mark L.

    2012-06-20

    The conditions for the production of oxygen during radiolysis of water adsorbed onto plutonium dioxide powder are discussed. Studies in the literature investigating the radiolysis of water show that both oxygen and hydrogen can be generated from water adsorbed on high-purity plutonium dioxide powder. These studies indicate that there is a threshold in the amount of water below which oxygen is not generated. The threshold is associated with the number of monolayers of adsorbed water and is shown to occur at approximately two monolayers of molecularly adsorbed water. Material in equilibrium with 50% relative humidity (RH) will be at the threshold for oxygen generation. Using two monolayers of molecularly adsorbed water as the threshold for oxygen production, the total pressure under various conditions is calculated assuming stoichiometric production of hydrogen and oxygen. The specific surface area of the oxide has a strong effect on the final partial pressure. The specific surface areas resulting in the highest pressures within a 3013 container are evaluated. The potential for oxygen generation is mitigated by reduced relative humidity, and hence moisture adsorption, at the oxide surface which occurs if the oxide is warmer than the ambient air. The potential for oxygen generation approaches zero as the temperature difference between the ambient air and the material approaches 6 C.

  11. Studies of the viscoelastic properties of water confined between surfaces of specified chemical nature.

    SciTech Connect (OSTI)

    Houston, Jack E.; Grest, Gary Stephen; Moore, Nathan W.; Feibelman, Peter J.

    2010-09-01

    This report summarizes the work completed under the Laboratory Directed Research and Development (LDRD) project 10-0973 of the same title. Understanding the molecular origin of the no-slip boundary condition remains vitally important for understanding molecular transport in biological, environmental and energy-related processes, with broad technological implications. Moreover, the viscoelastic properties of fluids in nanoconfinement or near surfaces are not well-understood. We have critically reviewed progress in this area, evaluated key experimental and theoretical methods, and made unique and important discoveries addressing these and related scientific questions. Thematically, the discoveries include insight into the orientation of water molecules on metal surfaces, the premelting of ice, the nucleation of water and alcohol vapors between surface asperities and the lubricity of these molecules when confined inside nanopores, the influence of water nucleation on adhesion to salts and silicates, and the growth and superplasticity of NaCl nanowires.

  12. Preliminary examination of oil bonding at sand surfaces and its influence on hot water separation

    SciTech Connect (OSTI)

    Hupka, J.; Budzich, M.; Miller, J.D.

    1991-01-01

    The efficiency of water-based separation of oil from sand particles is dependent on the nature of the oil-sand association and a preliminary examination of this bonding has been completed. The degree of hydration of the sand surface at the time of contact with oil was related to the subsequent efficiency of the oil-sand separation process. Variables which influence hot water separation were correlated by multiple linear regression, and a second order experimental model was obtained. The processing temperature appeared to be the most significant variable, followed by digestion time and pH. Oil-coated sand particles which had intrinsic water left on their surface during sample preparation were easily processed in hot water separation experiments, and 64 to 90% of the oil was removed. On the other hand, only 1 to 23% separation and oil recovery was possible when a calcinated sand-oil mixture was used.

  13. Preliminary examination of oil bonding at sand surfaces and its influence on hot water separation

    SciTech Connect (OSTI)

    Hupka, J.; Budzich, M.; Miller, J.D.

    1991-12-31

    The efficiency of water-based separation of oil from sand particles is dependent on the nature of the oil-sand association and a preliminary examination of this bonding has been completed. The degree of hydration of the sand surface at the time of contact with oil was related to the subsequent efficiency of the oil-sand separation process. Variables which influence hot water separation were correlated by multiple linear regression, and a second order experimental model was obtained. The processing temperature appeared to be the most significant variable, followed by digestion time and pH. Oil-coated sand particles which had intrinsic water left on their surface during sample preparation were easily processed in hot water separation experiments, and 64 to 90% of the oil was removed. On the other hand, only 1 to 23% separation and oil recovery was possible when a calcinated sand-oil mixture was used.

  14. Determination of Ice Water Path Over the ARM SGP Using Combined Surface and Satellite Datasets

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Determination of Ice Water Path Over the ARM SGP Using Combined Surface and Satellite Datasets J. Huang, M. M. Khaiyer, and P. W. Heck Analytical Services & Materials, Inc. Hampton, Virginia P. Minnis and B. Lin Atmospheric Sciences National Aeronautics and Space Administration Langley Research Center Hampton, Virginia T.-F. Fan Science Applications International Corporation Hampton, Virginia Introduction Global information of cloud ice water path (IWP) is urgently needed for testing of

  15. Electric double layer at metal oxide surfaces: Static properties of the cassiterite - Water Interface

    SciTech Connect (OSTI)

    Vlcek, Lukas; Zhang, Zhan; Machesky, Michael L.; Wesolowski, David J

    2007-04-01

    The structure of water at the (110) surface of cassiterite ({alpha}-SnO{sub 2}) at ambient conditions was studied by means of molecular dynamics simulations and X-ray crystal truncation rod experiments and interpreted with the help of the revised MUSIC model of surface protonation. The interactions of the metal oxide in the simulations were described by a recently developed classical force field based on the SPC/E model of water. Two extreme cases of completely hydroxylated and nonhydroxylated surfaces were considered along with a mixed surface with 50% dissociation. To study the dependence of the surface properties on pH, neutral and negatively charged variants of the surfaces were constructed. Axial and lateral density distributions of water for different types of surfaces were compared to each other and to experimental axial density distributions found by X-ray experiments. Although significant differences were found between the structures of the studied interfaces, the axial distances between Sn and O atoms are very similar and therefore could not be clearly distinguished by the diffraction technique. The explanation of structures observed in the density distributions was provided by a detailed analysis of hydrogen bonding in the interfacial region. It revealed qualitatively different hydrating patterns formed at neutral hydroxylated and nonhydroxylated surfaces and suggested a preference for the dissociative adsorption of water. At negatively charged surfaces, however, the situation can be reversed by the electric field stabilizing a hydrogen bond network similar to that found at the neutral nonhydroxylated surface. Comparison with previously studied rutile ({alpha}-TiO{sub 2}) surfaces provided insight into the differences between the hydration of these two metal oxides, and an important role was ascribed to their different lattice parameters. A link to macroscopic properties was provided by the revised MUSIC surface protonation model. Explicit use of the Sn-O bond lengths based on ab initio calculations and H-bond configurations as inputs led to the prediction of a pH of zero net-proton induced surface charge (pH{sub pzc}) that agrees very well with those determined experimentally (about 4.4 at 298 K).

  16. Electric double layer at metal oxide surfaces:static properties of the cassiterite-water interface.

    SciTech Connect (OSTI)

    Vlcek, L.; Zhang, Z.; Machesky, M .L.; Fenter, P.; Rosenqvist, J.; Wesolowski, D. J.; Anovitz, L. M.; Predota, M.; Cummings, P. T.; Vanderbilt Univ.; ORNL; Univ. of South Bohimia; Illinois State Water Survey

    2007-03-24

    The structure of water at the (110) surface of cassiterite ({alpha}-SnO{sub 2}) at ambient conditions was studied by means of molecular dynamics simulations and X-ray crystal truncation rod experiments and interpreted with the help of the revised MUSIC model of surface protonation. The interactions of the metal oxide in the simulations were described by a recently developed classical force field based on the SPC/E model of water. Two extreme cases of completely hydroxylated and nonhydroxylated surfaces were considered along with a mixed surface with 50% dissociation. To study the dependence of the surface properties on pH, neutral and negatively charged variants of the surfaces were constructed. Axial and lateral density distributions of water for different types of surfaces were compared to each other and to experimental axial density distributions found by X-ray experiments. Although significant differences were found between the structures of the studied interfaces, the axial distances between Sn and O atoms are very similar and therefore could not be clearly distinguished by the diffraction technique. The explanation of structures observed in the density distributions was provided by a detailed analysis of hydrogen bonding in the interfacial region. It revealed qualitatively different hydrating patterns formed at neutral hydroxylated and nonhydroxylated surfaces and suggested a preference for the dissociative adsorption of water. At negatively charged surfaces, however, the situation can be reversed by the electric field stabilizing a hydrogen bond network similar to that found at the neutral nonhydroxylated surface. Comparison with previously studied rutile ({alpha}-TiO{sub 2}) surfaces provided insight into the differences between the hydration of these two metal oxides, and an important role was ascribed to their different lattice parameters. A link to macroscopic properties was provided by the revised MUSIC surface protonation model. Explicit use of the Sn-O bond lengths based on ab initio calculations and H-bond configurations as inputs led to the prediction of a pH of zero net-proton induced surface charge (pH{sub pzc}) that agrees very well with those determined experimentally (about 4.4 at 298 K).

  17. Phase Preference by Active, Acetate-Utilizing Bacteria at the Rifle, CO Integrated Field Research Challenge Site

    SciTech Connect (OSTI)

    Kerkhoff, Lee; Williams, Kenneth H.; Long, Philip E.; McGuinness, L.

    2011-02-15

    Uranium contaminated groundwaters are a legacy concern for the U.S. Department of Energy. Previous experiments at the Rifle, Colorado Integrated Field Challenge (IFC) site have demonstrated that field-scale addition of acetate to groundwater reduces the ambient soluable uranium concentration, sequestering the radionuclide as uraninite. However, questions remain regarding which microorganism(s) are consuming this acetate and if active groundwater microorganisms are different from active particle-associated bacteria. In this report, 13-C acetate was used to assess the active microbes that synthesize DNA on 3 size fractions [coarse sand, fines (8-approximately 150 micron), groundwater (0.2-8 micron)] over a 24 -day time frame. Results indicated a stronger signal from 13-C acetate associated with the fines fraction compared with smaller amounts of 13-C uptake on the sand fraction and groundwater samples during the SIP incubations. TRFLP analysis of this 13-C-labeled DNA, indicated 31+ 9 OTU's with 6 peaks dominating the active profiles (166, 187, 210, 212, and 277 bp peaks using MnlI). Cloning/sequencing of the amplification products indicated a Geobacter-like group (187, 210, 212 bp) primarily synthesized DNA from acetate in the groundwater phase, an alpha Proteobacterium (166 bp) primarily grew on the fines/sands, and an Acinetobacter sp. (277 bp) utilized much of the 13C acetate in both groundwater and particle-associated phases. These findings will help to delineate the acetate utilization patterns of bacteria during field-scale acetate addition and can lead to improved methods for stimulating distinct microbial populations in situ.

  18. May and June 2015 Groundwater and Surface Water Sampling at the bluewater, New Mexico, Disposal Site

    Office of Legacy Management (LM)

    May and June 2015 Groundwater and Surface Water Sampling at the Bluewater, New Mexico, Disposal Site August 2015 LMS/BLU/S00515 This page intentionally left blank U.S. Department of Energy DVP-May and June 2015, Bluewater, New Mexico August 2015 RIN 15057015 and 15067154 Page i Contents Sampling Event Summary ...............................................................................................................1 Bluewater, New Mexico, Disposal Site, Sample Location

  19. August 2015 Groundwater and Surface Water Sampling at the Tuba City, Arizona, Disposal Site

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Tuba City, Arizona, Disposal Site November 2015 LMS/TUB/S00815 This page intentionally left blank U.S. Department of Energy DVP-August 2015, Tuba City, Arizona, Disposal Site November 2015 RIN 15087262 Page i Contents Sampling Event Summary ...............................................................................................................1 Tuba City, Arizona, Disposal Site, Sample Location Map

  20. Water balance in the Amazon basin from a land surface model ensemble

    SciTech Connect (OSTI)

    Getirana, Augusto; Dutra, Emanuel; Guimberteau, Matthieu; Kam, Jonghun; Li, Hongyi; Decharme, Bertrand; Zhang, Zhengqiu J.; Ducharne, Agnes; Boone, Aaron; Balsamo, Gianpaolo; Rodell, Matthew; Mounirou Toure, Ally; Xue, Yongkang; Peters-Lidard, Christa D.; Kumar, Sujay V.; Arsenault, Kristi Rae; Drapeau, Guillaume; Leung, Lai-Yung R.; Ronchail, Josyane; Sheffield, Justin

    2014-12-06

    Despite recent advances in modeling and remote sensing of land surfaces, estimates of the global water budget are still fairly uncertain. The objective of this study is to evaluate the water budget of the Amazon basin based on several state-of-the-art land surface model (LSM) outputs. Water budget variables [total water storage (TWS), evapotranspiration (ET), surface runoff (R) and baseflow (B)] are evaluated at the basin scale using both remote sensing and in situ data. Fourteen LSMs were run using meteorological forcings at a 3-hourly time step and 1-degree spatial resolution. Three experiments are performed using precipitation which has been rescaled to match monthly global GPCP and GPCC datasets and the daily HYBAM dataset for the Amazon basin. R and B are used to force the Hydrological Modeling and Analysis Platform (HyMAP) river routing scheme and simulated discharges are compared against observations at 165 gauges. Simulated ET and TWS are compared against FLUXNET and MOD16A2 evapotranspiration, and GRACE TWS estimates in different catchments. At the basin scale, simulated ET ranges from 2.39mm.d-1 to 3.26mm.d-1 and a low spatial correlation between ET and P indicates that evapotranspiration does not depend on water availability over most of the basin. Results also show that other simulated water budget variables vary significantly as a function of both the LSM and precipitation used, but simulated TWS generally agree at the basin scale. The best water budget simulations resulted from experiments using the HYBAM dataset, mostly explained by a denser rainfall gauge network the daily rescaling.

  1. Tuning the interaction between propagating and localized surface plasmons for surface enhanced Raman scattering in water for biomedical and environmental applications

    SciTech Connect (OSTI)

    Shioi, Masahiko; Jans, Hilde; Lodewijks, Kristof; Van Dorpe, Pol; Lagae, Liesbet; Kawamura, Tatsuro

    2014-06-16

    With a view to biomedical and environmental applications, we investigate the plasmonic properties of a rectangular gold nanodisk array in water to boost surface enhanced Raman scattering (SERS) effects. To control the resonance wavelengths of the surface plasmon polariton and the localized surface plasmon, their dependence on the array period and diameter in water is studied in detail using a finite difference time domain method. A good agreement is obtained between calculated resonant wavelengths and those of gold nanodisk arrays fabricated using electron beam lithography. For the optimized structure, a SERS enhancement factor of 7.8 × 10{sup 7} is achieved in water experimentally.

  2. Microsoft Word - RFL 2008-final.doc

    Office of Legacy Management (LM)

    Rifle, Colorado Page 14-1 14.0 Rifle, Colorado, Disposal Site 14.1 Compliance Summary The Rifle, Colorado, Uranium Mill Tailings Radiation Control Act (UMTRCA) Title I Disposal Site was inspected on August 6, 2008. The disposal cell and all associated surface water diversion and drainage structures were in good condition and functioning as designed. Erosion repair of the interceptor trench, undertaken in fall 2005, continues to perform as designed-no new erosion was observed. Pore water

  3. Microbiological, Geochemical and Hydrologic Processes Controlling Uranium Mobility: An Integrated Field Scale Subsurface Research Challenge Site at Rifle, Colorado, February 2011 to January 2012

    SciTech Connect (OSTI)

    Long, Philip E.; Banfield, Jill; Chandler, Darrell P.; Davis, James A.; Hettich, Bob; VerBerkmoes, Nathan; Jaffe, Peter R.; Kerkhof, Lee J.; Kukkadapu, Ravi K.; Lipton, Mary; Peacock, Aaron; Williams, Kenneth H.; Yabusaki, Steven B.

    2012-02-15

    The Rifle IFRC continued to make excellent progress during the last 12 months. As noted above, a key field experiment (Best Western) was performed during 2011 as a logical follow-on to the Super 8 field experiment preformed in 2010. In the Super 8 experiment, we successfully combined desorption and bioreduction and deployed a number of novel tracer techniques to enhance our ability to interpret the biogeochemistry of the experiment. In the Best Western experiment, we used the same experimental plot (Plot C) as was used for Super 8. The overarching objective of the Best Western field experiment was to compared the impacts of abiotic vs. biotic increases in alkalinity and to assess the mass of the sorbed pool of U(VI) at Rifle at the field scale. Both of these objectives were met. Preliminary analysis of the data indicate that the underlying biogeochemical data sets were obtained that will support a mechanistic understanding of the underlying processes, including remarkable insight into previously unrecognized microbial processes taking place during acetate amendment of the subsurface for a second time.

  4. Stable water isotope simulation by current land-surface schemes:Results of IPILPS phase 1

    SciTech Connect (OSTI)

    Henderson-Sellers, A.; Fischer, M.; Aleinov, I.; McGuffie, K.; Riley, W.J.; Schmidt, G.A.; Sturm, K.; Yoshimura, K.; Irannejad, P.

    2005-10-31

    Phase 1 of isotopes in the Project for Intercomparison of Land-surface Parameterization Schemes (iPILPS) compares the simulation of two stable water isotopologues ({sup 1}H{sub 2} {sup 18}O and {sup 1}H{sup 2}H{sup 16}O) at the land-atmosphere interface. The simulations are off-line, with forcing from an isotopically enabled regional model for three locations selected to offer contrasting climates and ecotypes: an evergreen tropical forest, a sclerophyll eucalypt forest and a mixed deciduous wood. Here we report on the experimental framework, the quality control undertaken on the simulation results and the method of intercomparisons employed. The small number of available isotopically-enabled land-surface schemes (ILSSs) limits the drawing of strong conclusions but, despite this, there is shown to be benefit in undertaking this type of isotopic intercomparison. Although validation of isotopic simulations at the land surface must await more, and much more complete, observational campaigns, we find that the empirically-based Craig-Gordon parameterization (of isotopic fractionation during evaporation) gives adequately realistic isotopic simulations when incorporated in a wide range of land-surface codes. By introducing two new tools for understanding isotopic variability from the land surface, the Isotope Transfer Function and the iPILPS plot, we show that different hydrological parameterizations cause very different isotopic responses. We show that ILSS-simulated isotopic equilibrium is independent of the total water and energy budget (with respect to both equilibration time and state), but interestingly the partitioning of available energy and water is a function of the models' complexity.

  5. The ecological evaluation of surface water outfalls at a manufacturing plant in New Jersey

    SciTech Connect (OSTI)

    Harman, C.R.; Gilchrist, W.

    1995-12-31

    Historic metal machining operations at a manufacturing plant in northern New Jersey had resulted in the contamination of three surface water outfalls leading from the plant to a second-order stream used for trout fishing. The outfalls were fed by a combination of non-contact cooling water, stormwater runoff and groundwater infiltration. The outfalls ranged in length from 180 meters to 600 meters. All three of the outfalls pass through forested wetland areas and contained emergent wetland pockets. The ecological evaluation consisted of the collection of sediment samples to evaluate the extent of chemical contamination and the evaluation of the biological integrity of a portion of the surface water outfalls. Additionally, an ecological characterization of the surrounding habitat was prepared. Sediment sampling indicated elevated concentrations of antimony, cadmium, chromium, copper, lead, mercury, nickel, silver, and zinc. Nickel concentrations were the most significant, with concentrations ranging up to 9,850 mg/kg. PCB concentrations ranged between 0.45 mg/kg and 6.4 mg/kg. Elevated concentrations of metals and PCBs were detected to a sediment depth of 45 centimeters. To evaluate the potential for biological impacts from the metals in the sediments, a modified Rapid Bioassessment Protocol 1 evaluation was conducted on the macroinvertebrate population. The results of the evaluation indicated a very sparse macroinvertebrate community. Those organisms that were identified were typical of highly contaminated surface water system. The surrounding wetland systems appeared to be unaffected by the outfall contamination. Based on the results of the first phase of the ecological evaluation, a program of additional sediment sampling and further biological evaluation was prepared.

  6. RIFLE TO SAN JUAN

    Office of Environmental Management (EM)

    Di r ec to r Wes t e r n A r e a - E l ec tric Ru r al E l ec t rifica tio n Adminis t r a tio n 14 th & Inde p e nde nce Ave., S.W. Washi n g ton, D.C. 20250 Tele pho n e:...

  7. Improved Design Tools for Surface Water and Standing Column Well Heat Pump Systems (DE-EE0002961)

    SciTech Connect (OSTI)

    Spitler, J.D.; Culling, J.R.; Conjeevaram, K.; Ramesh, M.; Selvakumar, M.

    2012-11-30

    Ground-source heat pump (GSHP) systems are perhaps the most widely used sustainable heating and cooling systems, with an estimated 1.7 million installed units with total installed heating capacity on the order of 18 GW. They are widely used in residential, commercial, and institutional buildings. Standing column wells (SCW) are one form of ground heat exchanger that, under the right geological conditions, can provide excellent energy efficiency at a relatively low capital cost. Closed-loop surface water heat pump (SWHP) systems utilize surface water heat exchangers (SWHE) to reject or extract heat from nearby surface water bodies. For building near surface water bodies, these systems also offer a high degree of energy efficiency at a low capital cost. However, there have been few design tools available for properly sizing standing column wells or surface water heat exchangers. Nor have tools for analyzing the energy consumption and supporting economics-based design decisions been available. The main contributions of this project lie in providing new tools that support design and energy analysis. These include a design tool for sizing surface water heat exchangers, a design tool for sizing standing column wells, a new model of surface water heat pump systems implemented in EnergyPlus and a new model of standing column wells implemented in EnergyPlus. These tools will better help engineers design these systems and determine the economic and technical feasibility.

  8. ANNUAL COMPLIANCE REPORT

    Office of Legacy Management (LM)

    Rifle, Colorado Page 14-1 14.0 Rifle, Colorado, Disposal Site 14.1 Compliance Summary The Rifle, Colorado, Uranium Mill Tailings Radiation Control Act (UMTRCA) Title I Disposal Site was inspected on June 12, 2014. The disposal cell and all associated surface water diversion and drainage structures were in good condition and functioning as designed. Minor fence repairs will be conducted prior to the next inspection. Two signs on the evaporation pond need to be replaced. Inspectors identified no

  9. Surface Water Transport for the F/H Area Seepage Basins Groundwater Program

    SciTech Connect (OSTI)

    Chen, Kuo-Fu

    1995-08-29

    The contribution of the F- and H-Area Seepage Basins (FHSBs) tritium releases to the tritium concentration in the Savannah River are presented in this report. WASP5 was used to simulate surface water transport for tritium releases from the FHSBs. The WASP5 model was qualified with the 1993 tritium measurements at US Highway 301. The tritium concentrations in Fourmile Branch and the Savannah River were calculated for tritium releases from FHSBs. The calculated tritium concentrations above normal environmental background in the Savannah River, resulting from FHSBs releases, drop from 1.25 pCi/ml (<10% of EPA Drinking Water Guide) in 1995 to 0.0056 pCi/ml in 2045.

  10. May 2013 Groundwater and Surface Water Sampling at the Rio Blanco, Colorado, Site (Data Validation Package)

    SciTech Connect (OSTI)

    2013-10-01

    Annual sampling was conducted at the Rio Blanco, Colorado, site for the Long-Term Hydrologic Monitoring Program May 14-16, 2013, to monitor groundwater and surface water for potential radionuclide contamination. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for the U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). A duplicate sample was collected from location CER #1 Black Sulphur. Samples were analyzed for gamma-emitting radionuclides by high-resolution gamma spectrometry and for tritium using the conventional and enrichment methods.

  11. Overview of groundwater and surface water standards pertinent to the Idaho National Engineering Laboratory. Revision 3

    SciTech Connect (OSTI)

    Lundahl, A.L.; Williams, S.; Grizzle, B.J.

    1995-09-01

    This document presents an overview of groundwater- and surface water-related laws, regulations, agreements, guidance documents, Executive Orders, and DOE orders pertinent to the Idaho National Engineering Laboratory. This document is a summary and is intended to help readers understand which regulatory requirements may apply to their particular circumstances. However, the document is not intended to be used in lieu of applicable regulations. Unless otherwise noted, the information in this report reflects a summary and evaluation completed July 1, 1995. This document is considered a Living Document, and updates on changing laws and regulations will be provided.

  12. Uranium 238U/235U isotope ratios as indicators of reduction: Results from an in situ biostimulation experiment at Rifle, Colorado, USA

    SciTech Connect (OSTI)

    Bopp IV, C.J.; Lundstrom, C.C.; Johnson, T.M.; Sanford, R.A.; Long, P.E.; Williams, K.H.

    2010-02-01

    The attenuation of groundwater contamination via chemical reaction is traditionally evaluated by monitoring contaminant concentration through time. However, this method can be confounded by common transport processes (e.g. dilution, sorption). Isotopic techniques bypass the limits of concentration methods, and so may provide improved accuracy in determining the extent of reaction. We apply measurements of {sup 238}U/{sup 235}U to a U bioremediation field experiment at the Rifle Integrated Field Research Challenge Site in Rifle, Colorado (USA). An array of monitoring and injection wells was installed on a 100 m{sup 2} plot where U(VI) contamination was present in the groundwater. Acetate-amended groundwater was injected along an up-gradient gallery to encourage the growth of dissimilatory metal reducing bacteria (e.g. Geobacter species). During amendment, U concentration dropped by an order of magnitude in the experiment plot. We measured {sup 238}U/{sup 235}U in samples from one monitoring well by MC-ICP-MS using a double isotope tracer method. A significant {approx}1.00{per_thousand} decrease in {sup 238}U/{sup 235}U occurred in the groundwater as U(VI) concentration decreased. The relationship between {sup 238}U/{sup 235}U and concentration corresponds approximately to a Rayleigh distillation curve with an effective fractionation factor ({alpha}) of 1.00046. We attribute the observed U isotope fractionation to a nuclear field shift effect during enzymatic reduction of U(VI){sub (aq)} to U(IV){sub (s)}.

  13. Concentrations of 23 trace elements in ground water and surface water at and near the Idaho National Engineering Laboratory, Idaho, 1988--91

    SciTech Connect (OSTI)

    Liszewski, M.J.; Mann, L.J.

    1993-12-31

    Analytical data for 23 trace elements are reported for ground- and surface-water samples collected at and near the Idaho National Engineering Laboratory during 1988--91. Water samples were collected from 148 wells completed in the Snake River Plain aquifer, 18 wells completed in discontinuous deep perched-water zones, and 1 well completed in an alluvial aquifer. Surface-water samples also were collected from three streams, two springs, two ponds, and one lake. Data are categorized by concentrations of total recoverable of dissolved trace elements. Concentrations of total recoverable trace elements are reported for unfiltered water samples and include results for one or more of the following: aluminum, arsenic, barium, beryllium, cadmium, chromium, cobalt, copper, iron, lead, manganese, mercury, nickel, selenium, silver, and zinc. Concentrations of dissolved trace elements are reported for water samples filtered through a nominal 0.45-micron filter and may also include bromide, fluoride, lithium, molybdenum, strontium, thallium, and vanadium. Concentrations of dissolved hexavalent chromium also are reported for many samples. The water samples were analyzed at the US Geological Survey`s National Water Quality Laboratory in Arvada, Colorado. Methods used to collect the water samples and quality assurance instituted for the sampling program are described. Concentrations of chromium equaled or exceeded the maximum contaminant level at 12 ground-water quality monitoring wells. Other trace elements did not exceed their respective maximum contaminant levels.

  14. Surface water drainage system. Environmental assessment and finding of no significant impact

    SciTech Connect (OSTI)

    1996-05-01

    This Environmental Assessment (EA) is written pursuant to the National Environmental Policy Act (NEPA). The document identifies and evaluates the action proposed to correct deficiencies in, and then to maintain, the surface water drainage system serving the Department of Energy`s Rocky Flats Environmental Technology Site (Site), located north of Golden, Colorado. Many of the activities proposed would not normally be subject to this level of NEPA documentation. However, in many cases, maintenance of the system has been deferred to the point that wetlands vegetation has become established in some ditches and culverts, creating wetlands. The proposed activities would damage or remove some of these wetlands in order to return the drainage system to the point that it would be able to fully serve its intended function - stormwater control. The Department of Energy (DOE) regulations require that activities affecting environmentally sensitive areas like wetlands be the subject of an EA. Most portions of the surface water drainage system are presently inadequate to convey the runoff from a 100-year storm event. As a result, such an event would cause flooding across much of the Site and possibly threaten the integrity of the dams at the terminal ponds. Severe flooding would not only cause damage to facilities and equipment, but could also facilitate the transport of contaminants from individual hazardous substance sites (IHSSs). Uncontrolled flow through the A- and B-series ponds could cause contaminated sediments to become suspended and carried downstream. Additionally, high velocity flood flows significantly increase erosion losses.

  15. Projected Changes in Mean and Interannual Variability of Surface Water over Continental China

    SciTech Connect (OSTI)

    Leng, Guoyong; Tang, Qiuhong; Huang, Maoyi; Hong, Yang; Leung, Lai-Yung R.

    2015-05-01

    Five General Circulation Model (GCM) climate projections under the RCP8.5 emission scenario were used to drive the Variable Infiltration Capacity (VIC) hydrologic model to investigate the impacts of climate change on hydrologic cycle over continental China in the 21st century. The bias-corrected climatic variables were generated for the Fifth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC AR5) by the Inter-Sectoral Impact Model Intercomparison Project (ISI-MIP). Results showed much larger fractional changes of annual mean Evaportranspiration (ET) per unit warming than the corresponding fractional changes of Precipitation (P) per unit warming across the country especially for South China, which led to notable decrease of surface water variability (P-E). Specifically, negative trends for annual mean runoff up to -0.33%/decade and soil moisture trends varying between -0.02 to -0.13%/decade were found for most river basins across China. Coincidentally, interannual variability for both runoff and soil moisture exhibited significant positive trends for almost all river basins across China, implying an increase in extremes relative to the mean conditions. Noticeably, the largest positive trends for runoff variability and soil moisture variability, which were up to 38 0.41%/decade and 0.90%/decade, both occurred in Southwest China. In addition to the regional contrast, intra-seasonal variation was also large for the runoff mean and runoff variability changes, but small for the soil moisture mean and variability changes. Our results suggest that future climate change could further exacerbate existing water-related risks (e.g. floods and droughts) across China as indicated by the marked decrease of surface water amounts combined with steady increase of interannual variability throughout the 21st century. This study highlights the regional contrast and intra-seasonal variations for the projected hydrologic changes and could provide muti-scale guidance for assessing effective adaptation strategies for the country on a river basin, regional, or as whole.

  16. Molecular dynamics study of saltsolution interface: Solubility and surface charge of salt in water

    SciTech Connect (OSTI)

    Kobayashi, Kazuya; Liang, Yunfeng E-mail: matsuoka@earth.kumst.kyoto-u.ac.jp; Matsuoka, Toshifumi E-mail: matsuoka@earth.kumst.kyoto-u.ac.jp; Sakka, Tetsuo

    2014-04-14

    The NaCl saltsolution interface often serves as an example of an uncharged surface. However, recent laser-Doppler electrophoresis has shown some evidence that the NaCl crystal is positively charged in its saturated solution. Using molecular dynamics (MD) simulations, we have investigated the NaCl saltsolution interface system, and calculated the solubility of the salt using the direct method and free energy calculations, which are kinetic and thermodynamic approaches, respectively. The direct method calculation uses a saltsolution combined system. When the system is equilibrated, the concentration in the solution area is the solubility. In the free energy calculation, we separately calculate the chemical potential of NaCl in two systems, the solid and the solution, using thermodynamic integration with MD simulations. When the chemical potential of NaCl in the solution phase is equal to the chemical potential of the solid phase, the concentration of the solution system is the solubility. The advantage of using two different methods is that the computational methods can be mutually verified. We found that a relatively good estimate of the solubility of the system can be obtained through comparison of the two methods. Furthermore, we found using microsecond time-scale MD simulations that the positively charged NaCl surface was induced by a combination of a sodium-rich surface and the orientation of the interfacial water molecules.

  17. Correlation of Oil-Water and Air-Water Contact Angles of Diverse Silanized Surfaces and Relationship to Fluid Interfacial Tensions

    SciTech Connect (OSTI)

    Grate, Jay W.; Dehoff, Karl J.; Warner, Marvin G.; Pittman, Jonathan W.; Wietsma, Thomas W.; Zhang, Changyong; Oostrom, Martinus

    2012-02-24

    The use of air-water, {Theta}{sub wa}, or air-liquid contact angles is customary in surface science, while oil-water contact angles {Theta}{sub ow}, are of paramount importance in subsurface multiphase flow phenomena including petroleum reocovery, nonaqueous phase liquid fate and transport, and geological carbon sequestration. In this paper we determine both the air-water and oil-water contact angles of silica surfaces modified with a diverse selection of silanes, using hexadecane as the oil. The silanes included alkylsilanes, alkylarylsilanes, and silanes with alkyl or aryl groups that are functionalized with heteroatoms such as N, O, and S. These silanes yielded surfaces with wettabilities from water-wet to oil wet, including specific silanized surfaces functionalized with heteroatoms that yield intermediate wet surfaces. The oil-water contact angles for clean and silanized surfaces, excluding one partially fluorinated surface, correlate linearly with air-water contact angles with a slope of 1.41 (R = 0.981, n = 13). These data were used to examine a previously untested theoretical treatment relating air-water and oil-water contact angles in terms of fluid interfacial energies. Plotting the cosines of these contact angles against one another, we obtain a linear relationship in excellent agreement with the theoretical treatment; the data fit cos {Theta}{sub ow} = 0.667 cos {Theta}{sub ow} + 0.384 (R = 0.981, n = 13), intercepting cos {Theta}{sub ow} = -1 at -0.284. The theoretical slope, based on the fluid interfacial tensions {Theta}{sub wa}, {Theta}{sub ow}, and {Theta}{sub oa}, is 0.67. We also demonstrate how silanes can be used to alter the wettability of the interior of a pore network micromodel device constructed in silicon/silica with a glass cover plate. Such micromodels are used to study multiphase flow phenomena. The contact angle of the resulting interior was determined in situ. An intermediate wet micromodel gave a contact angle in excellent agreement with that obtained on an open planar silica surface using the same silane.

  18. Polycyclic aromatic hydrocarbons in surface waters of Alessandria District, South Eastern Piedmont (Italy)

    SciTech Connect (OSTI)

    Trova, C.; Cossa, G.; Gandolfo, G.

    1992-10-01

    Polynuclear aromatic hydrocarbons (PAHs) are ubiquitous environmental pollutants. Because of the high toxicity of some polycyclic compounds, such as benzopyrenes, the determination of their levels in air, water, soil and aquatic organisms was the object of several papers. Anthropogenic pyrolitic and combustion processes, related to industrial plants, domestic heating, automobile traffic, are the major sources of these compounds; from these sources they enter atmospheric environment where their concentration is reduced by scavenging during precipitation events: rain, snow and fog in urban areas usually show high contents of PAHs. Dry and wet atmospheric polluted depositions effluents transport appreciable amounts of PAHs to aquatic environment, where they are rapidly taken up and accumulated by both fish and shellfish. Alessandria District, in South-Eastern Piedmont (Italy), lies in the middle of Torino-Milano-Genova industrial area: in addition to local sources, a relatively long range transport of polluted air masses may conduct to this region atmospheric contaminants, such as polynuclear compounds, that can enter fluvial environments through meteoric precipitation. The object of this work was to evaluate PAH content in surface waters flowing across the described territory. Samplings were carried on during winter season, when the concentration of these pollutants usually reaches the highest levels. 8 refs., 4 figs., 2 tabs.

  19. The effects of Fe-oxidizing microorganisms on post-biostimulation permeability reduction and oxidative processes at the Rifle IFRC site

    SciTech Connect (OSTI)

    Chan, Clara Sze-Yue

    2015-07-02

    Fe oxidation and biomineral formation is important in aquifers because the highly-reactive oxides can control the mobility of nutrients (e.g. phosphate, C) and metals (e.g. arsenic, uranium). Mineral formation also has the potential to affect hydrology, depending on the volume and distribution in pore spaces. In this exploratory study, we sought to understand how microbial Fe-oxidizers and their biominerals affect, and are affected by groundwater flow. As part of work at the Rifle aquifer in Colorado, we initially hypothesized that Fe-oxidizers were contributing to aquifer clogging problems associated with enhanced bioremediation. To demonstrate the presence of Fe-oxidizers in the Rifle aquifer, we enriched FeOM from groundwater samples, and isolated two novel chemolithotrophic, microaerophilic Fe-oxidizing Betaproteobacteria, Hydrogenophaga sp. P101 and Curvibacter sp. CD03. To image cells and biominerals in the context of pores, we developed a micro-aquifer, a sand-filled flow-through culture chamber that allows for imaging of sediment pore space with multiphoton confocal microscopy. Fe oxide biofilms formed on sand grains, demonstrating that FeOM produce Fe oxide sand coatings. Fe coatings are common on aquifer sands, and tend to sequester contaminants; however, it has never previously been shown that microbes are responsible for their formation. In contrast to our original hypothesis, the biominerals did not clog the mini-aquifer. Instead, Fe biofilm distribution was dynamic: they grew as coatings, then periodically sloughed off sand grains, with some flocs later caught in pore throats. This has implications for physical hydrology, including pore scale architecture, and element transport. The sloughing of coatings likely prevents the biominerals from clogging wells and aquifers, at least initially. Although attached biomineral coatings sequester Fe-associated elements (e.g. P, As, C, U), when biominerals detach, these elements are transported as particles through the aquifer. Our work shows that microbial mineralization impacts in aquifers are dynamic, and that the fate and transport of biomineral-associated elements depend not only on geochemical conditions, but also physical pore-scale processes.

  20. Ground-water flow and ground- and surface-water interaction at the Weldon Spring quarry, St. Charles County, Missouri

    SciTech Connect (OSTI)

    Imes, J.L.; Kleeschulte, M.J.

    1997-12-31

    Ground-water-level measurements to support remedial actions were made in 37 piezometers and 19 monitoring wells during a 19-month period to assess the potential for ground-water flow from an abandoned quarry to the nearby St. Charles County well field, which withdraws water from the base of the alluvial aquifer. From 1957 to 1966, low-level radioactive waste products from the Weldon Spring chemical plant were placed in the quarry a few hundred feet north of the Missouri River alluvial plain. Uranium-based contaminants subsequently were detected in alluvial ground water south of the quarry. During all but flood conditions, lateral ground-water flow in the bedrock from the quarry, as interpreted from water-table maps, generally is southwest toward Little Femme Osage Creek or south into the alluvial aquifer. After entering the alluvial aquifer, the ground water flows southeast to east toward a ground-water depression presumably produced by pumping at the St. Charles County well field. The depression position varies depending on the Missouri River stage and probably the number and location of active wells in the St. Charles County well field.

  1. Surface Chemistry of GaP(001) and InP(001) in Contact with Water (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Surface Chemistry of GaP(001) and InP(001) in Contact with Water Citation Details In-Document Search Title: Surface Chemistry of GaP(001) and InP(001) in Contact with Water Authors: Wood, B C ; Schwegler, E ; Choi, W ; Ogitsu, T Publication Date: 2013-09-20 OSTI Identifier: 1130018 Report Number(s): LLNL-JRNL-644315 DOE Contract Number: W-7405-ENG-48 Resource Type: Journal Article Resource Relation: Journal Name: Journal of Physical Chemistry C, vol. 118, no. 2,

  2. Hydrated goethite ([alpha]-FeOOH) (1 0 0 ) interface structure: Ordered water and surface functional groups

    SciTech Connect (OSTI)

    Ghose, Sanjit K.; Waychunas, Glenn A.; Trainor, Thomas P.; Eng, Peter J.

    2010-03-16

    Goethite({alpha}-FeOOH), an abundant and highly reactive iron oxyhydroxide mineral, has been the subject of numerous studies of environmental interface reactivity. However, such studies have been hampered by the lack of experimental constraints on aqueous interface structure, and especially of the surface water molecular arrangements. Structural information of this type is crucial because reactivity is dictated by the nature of the surface functional groups and the structure or distribution of water and electrolyte at the solid-solution interface. In this study we have investigated the goethite (1 0 0) surface using surface diffraction techniques, and have determined the relaxed surface structure, the surface functional groups, and the three dimensional nature of two distinct sorbed water layers. The crystal truncation rod (CTR) results show that the interface structure consists of a double hydroxyl, double water terminated interface with significant atom relaxations. Further, the double hydroxyl terminated surface dominates with an 89% contribution having a chiral subdomain structure on the (1 0 0) cleavage faces. The proposed interface stoichiometry is ((H{sub 2}O)-(H{sub 2}O)-OH{sub 2}-OH-Fe-O-O-Fe-R) with two types of terminal hydroxyls; a bidentate (B-type) hydroxo group and a monodentate (A-type) aquo group. Using the bond-valence approach the protonation states of the terminal hydroxyls are predicted to be OH type (bidentate hydroxyl with oxygen coupled to two Fe{sup 3+} ions) and OH{sub 2} type (monodentate hydroxyl with oxygen tied to only one Fe{sup 3+}). A double layer three dimensional ordered water structure at the interface was determined from refinement of fits to the experimental data. Application of bond-valence constraints to the terminal hydroxyls with appropriate rotation of the water dipole moments allowed a plausible dipole orientation model as predicted. The structural results are discussed in terms of protonation and H-bonding at the interface, and the results provide an ideal basis for testing theoretical predictions of characteristic surface properties such as pK{sub a}, sorption equilibria, and surface water permittivity.

  3. Applying GIS characterizing and modeling contaminant transport in surface water at Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Becker, N.M.; Van Eeckhout, E.; David, N.A.; Irvine, J.M.

    1995-10-01

    During World War II, Los Alamos, New Mexico was chosen as the site for the secret development of the first atomic bomb. The remote location in the southwestern United States was ideal for such a project. After the war, research activities continued at the Los Alamos installation, focusing on new nuclear weapons models as well as greater effectiveness and reliability of existing weapons. Due to the emphasis on nuclear and non-nuclear weapons development as well as associated nuclear research, a large inventory of radionuclides and heavy metals have been tested, expended, and disposed of in the local environment, a high plateau of tuffaceous volcanic rocks incised by deep canyons in a semi-arid climate. In recent years an intensive evaluation of the environmental, impact of weapons testing at Los Alamos and elsewhere has been undertaken. GIS system utilization and image processing of past and current data has been an important part of this evaluation. Important problems can be more easily displayed and understood using this methodology. The main objective in this paper is to illustrate how transport of depleted uranium and associated heavy metals (copper in this case) used in dynamic testing of weapons components at open air firing sites can be evaluated and visualized. In our studies, surface water has been found to be the predominant transport mechanism. We have sampled soils, sediments, fallout, runoff water and snowmelt over a number of years in order to understand contaminant transport on- and offsite. Statistical analyses of these data have assisted in our characterization of issues such as contaminant variability, spatially and temporally, as well as in development of transport rates.

  4. Wetland Water Cooling Partnership: The Use of Constructed Wetlands to Enhance Thermoelectric Power Plant Cooling and Mitigate the Demand of Surface Water Use

    SciTech Connect (OSTI)

    Apfelbaum, Steven; Duvall, Kenneth; Nelson, Theresa; Mensing, Douglas; Bengtson, Harlan; Eppich, John; Penhallegon, Clayton; Thompson, Ry

    2013-09-30

    Through the Phase I study segment of contract #DE-NT0006644 with the U.S. Department of Energy’s National Energy Technology Laboratory, Applied Ecological Services, Inc. and Sterling Energy Services, LLC (the AES/SES Team) explored the use of constructed wetlands to help address stresses on surface water and groundwater resources from thermoelectric power plant cooling and makeup water requirements. The project objectives were crafted to explore and develop implementable water conservation and cooling strategies using constructed wetlands (not existing, naturally occurring wetlands), with the goal of determining if this strategy has the potential to reduce surface water and groundwater withdrawals of thermoelectric power plants throughout the country. Our team’s exploratory work has documented what appears to be a significant and practical potential for augmenting power plant cooling water resources for makeup supply at many, but not all, thermoelectric power plant sites. The intent is to help alleviate stress on existing surface water and groundwater resources through harvesting, storing, polishing and beneficially re-using critical water resources. Through literature review, development of conceptual created wetland plans, and STELLA-based modeling, the AES/SES team has developed heat and water balances for conventional thermoelectric power plants to evaluate wetland size requirements, water use, and comparative cooling technology costs. The ecological literature on organism tolerances to heated waters was used to understand the range of ecological outcomes achievable in created wetlands. This study suggests that wetlands and water harvesting can provide a practical and cost-effective strategy to augment cooling waters for thermoelectric power plants in many geographic settings of the United States, particularly east of the 100th meridian, and in coastal and riverine locations. The study concluded that constructed wetlands can have significant positive ancillary socio-economic, ecosystem, and water treatment/polishing benefits when used to complement water resources at thermoelectric power plants. Through the Phase II pilot study segment of the contract, the project team partnered with Progress Energy Florida (now Duke Energy Florida) to quantify the wetland water cooling benefits at their Hines Energy Complex in Bartow, Florida. The project was designed to test the wetland’s ability to cool and cleanse power plant cooling pond water while providing wildlife habitat and water harvesting benefits. Data collected during the monitoring period was used to calibrate a STELLA model developed for the site. It was also used to inform management recommendations for the demonstration site, and to provide guidance on the use of cooling wetlands for other power plants around the country. As a part of the pilot study, Duke Energy is scaling up the demonstration project to a larger, commercial scale wetland instrumented with monitoring equipment. Construction is expected to be finalized in early 2014.

  5. Y-12 Groundwater Protection Program Groundwater And Surface Water Sampling And Analysis Plan For Calendar Year 2014

    SciTech Connect (OSTI)

    2013-09-01

    This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2014 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring is performed by the GWPP during CY 2014 to achieve the following goals: 􀁸 to protect the worker, the public, and the environment; 􀁸 to maintain surveillance of existing and potential groundwater contamination sources; 􀁸 to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; 􀁸 to identify and characterize long-term trends in groundwater quality at Y-12; and 􀁸 to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring will be performed in three hydrogeologic regimes at Y-12.

  6. Cumulative hydrologic impact assessments on surface-water in northeastern Wyoming using HEC-1; a pilot study

    SciTech Connect (OSTI)

    Anderson, A.J.; Eastwood, D.C.; Anderson, M.E.

    1997-12-31

    The Surface Mining Control and Reclamation Act of 1977 requires that areas in which multiple mines will affect one watershed be analyzed and the cumulative impacts of all mining on the watershed be assessed. The purpose of the subject study was to conduct a cumulative hydrologic impact assessment (CHIA) for surface-water on a watershed in northeastern Wyoming that is currently being impacted by three mines. An assessment of the mining impact`s affect on the total discharge of the watershed is required to determine whether or not material damage to downstream water rights is likely to occur as a result of surface mining and reclamation. The surface-water model HEC-1 was used to model four separate rainfall-runoff events that occurred in the study basin over three years (1978-1980). Although these storms were used to represent pre-mining conditions, they occurred during the early stages of mining and the models were adjusted accordingly. The events were selected for completeness of record and antecedent moisture conditions (AMC). Models were calibrated to the study events and model inputs were altered to reflect post-mining conditions. The same events were then analyzed with the new model inputs. The results were compared with the pre-mining calibration. Peak flow, total discharge and timing of flows were compared for pre-mining and post-mining models. Data were turned over to the State of Wyoming for assessment of whether material damage to downstream water rights is likely to occur.

  7. Leakage and Sepage of CO2 from Geologic Carbon SequestrationSites: CO2 Migration into Surface Water

    SciTech Connect (OSTI)

    Oldenburg, Curt M.; Lewicki, Jennifer L.

    2005-06-17

    Geologic carbon sequestration is the capture of anthropogenic carbon dioxide (CO{sub 2}) and its storage in deep geologic formations. One of the concerns of geologic carbon sequestration is that injected CO{sub 2} may leak out of the intended storage formation, migrate to the near-surface environment, and seep out of the ground or into surface water. In this research, we investigate the process of CO{sub 2} leakage and seepage into saturated sediments and overlying surface water bodies such as rivers, lakes, wetlands, and continental shelf marine environments. Natural CO{sub 2} and CH{sub 4} fluxes are well studied and provide insight into the expected transport mechanisms and fate of seepage fluxes of similar magnitude. Also, natural CO{sub 2} and CH{sub 4} fluxes are pervasive in surface water environments at levels that may mask low-level carbon sequestration leakage and seepage. Extreme examples are the well known volcanic lakes in Cameroon where lake water supersaturated with respect to CO{sub 2} overturned and degassed with lethal effects. Standard bubble formation and hydrostatics are applicable to CO{sub 2} bubbles in surface water. Bubble-rise velocity in surface water is a function of bubble size and reaches a maximum of approximately 30 cm s{sup -1} at a bubble radius of 0.7 mm. Bubble rise in saturated porous media below surface water is affected by surface tension and buoyancy forces, along with the solid matrix pore structure. For medium and fine grain sizes, surface tension forces dominate and gas transport tends to occur as channel flow rather than bubble flow. For coarse porous media such as gravels and coarse sand, buoyancy dominates and the maximum bubble rise velocity is predicted to be approximately 18 cm s{sup -1}. Liquid CO{sub 2} bubbles rise slower in water than gaseous CO{sub 2} bubbles due to the smaller density contrast. A comparison of ebullition (i.e., bubble formation) and resulting bubble flow versus dispersive gas transport for CO{sub 2} and CH{sub 4} at three different seepage rates reveals that ebullition and bubble flow will be the dominant form of gas transport in surface water for all but the smallest seepage fluxes or shallowest water bodies. The solubility of the gas species in water plays a fundamental role in whether ebullition occurs. We used a solubility model to examine CO{sub 2} solubility in waters with varying salinity as a function of depth below a 200 m-deep surface water body. In this system, liquid CO{sub 2} is stable between the deep regions where supercritical CO{sub 2} is stable and the shallow regions where gaseous CO{sub 2} is stable. The transition from liquid to gaseous CO{sub 2} is associated with a large change in density, with corresponding large change in bubble buoyancy. The solubility of CO{sub 2} is lower in high-salinity waters such as might be encountered in the deep subsurface. Therefore, as CO{sub 2} migrates upward through the deep subsurface, it will likely encounter less saline water with increasing capacity to dissolve CO{sub 2} potentially preventing ebullition, depending on the CO{sub 2} leakage flux. However, as CO{sub 2} continues to move upward through shallower depths, CO{sub 2} solubility in water decreases strongly leading to greater likelihood of ebullition and bubble flow in surface water. In the case of deep density-stratified lakes in which ebullition is suppressed, enhanced mixing and man-made degassing schemes can alleviate the buildup of CO{sub 2} and related risk of dangerous rapid discharges. Future research efforts are needed to increase understanding of CO{sub 2} leakage and seepage in surface water and saturated porous media. For example, we recommend experiments and field tests of CO{sub 2} migration in saturated systems to formulate bubble-driven water-displacement models and relative permeability functions that can be used in simulation models.

  8. Influence of particle size and water coverage on the thermodynamic properties of water confined on the surface of SnO2 cassiterite nanoparticles

    SciTech Connect (OSTI)

    Spencer, Elinor; Ross, Dr. Nancy; Parker, Stewart F.; Kolesnikov, Alexander I; Woodfield, Brian; Woodfield, K; Rytting, M; Boerio-Goates, Juliana; Navrotsky, Alexandra

    2011-01-01

    Inelastic neutron scattering (INS) data for SnO2 nanoparticles of three different sizes and varying hydration levels are presented. Data were recorded on five nanoparticle samples that had the following compositions: 2 nm SnO2*0.82H2O, 6 nm SnO2*0.055H2O, 6 nm SnO2*0.095H2O, 20 nm SnO2*0.072H2O, and 20 nm SnO2*0.092H2O. The isochoric heat capacity and vibrational entropy values at 298 K for the water confined on the surface of these nanoparticles were calculated from the vibrational density of states that were extracted from the INS data. This study has shown that the hydration level of the SnO2 nanoparticles influences the thermodynamic properties of the water layers and, most importantly, that there appears to be a critical size limit for SnO2 between 2 and 6 nm below which the particle size also affects these properties and above which it does not. These results have been compared with those for isostructural rutile-TiO2 nanoparticles [TiO2*0.22H2O and TiO2*0.37H2O], which indicated that water on the surface of TiO2 nanoparticles is more tightly bound and experiences a greater degree of restricted motion with respect to water on the surface of SnO2 nanoparticles. This is believed to be a consequence of the difference in chemical composition, and hence surface properties, of these metal oxide nanoparticles.

  9. Effect of surface free energies on the heterogeneous nucleation of water droplet: A molecular dynamics simulation approach

    SciTech Connect (OSTI)

    Xu, W.; Lan, Z.; Peng, B. L.; Wen, R. F.; Ma, X. H.

    2015-02-07

    Heterogeneous nucleation of water droplet on surfaces with different solid-liquid interaction intensities is investigated by molecular dynamics simulation. The interaction potentials between surface atoms and vapor molecules are adjusted to obtain various surface free energies, and the nucleation process and wetting state of nuclei on surfaces are investigated. The results indicate that near-constant contact angles are already established for nano-scale nuclei on various surfaces, with the contact angle decreasing with solid-liquid interaction intensities linearly. Meanwhile, noticeable fluctuation of vapor-liquid interfaces can be observed for the nuclei that deposited on surfaces, which is caused by the asymmetric forces from vapor molecules. The formation and growth rate of nuclei are increasing with the solid-liquid interaction intensities. For low energy surface, the attraction of surface atoms to water molecules is comparably weak, and the pre-existing clusters can depart from the surface and enter into the bulk vapor phase. The distribution of clusters within the bulk vapor phase becomes competitive as compared with that absorbed on surface. For moderate energy surfaces, heterogeneous nucleation predominates and the formation of clusters within bulk vapor phase is suppressed. The effect of high energy particles that embedded in low energy surface is also discussed under the same simulation system. The nucleation preferably initiates on the high energy particles, and the clusters that formed on the heterogeneous particles are trapped around their original positions instead of migrating around as that observed on smooth surfaces. This feature makes it possible for the heterogeneous particles to act as fixed nucleation sites, and simulation results also suggest that the number of nuclei increases monotonously with the number of high energy particles. The growth of nuclei on high energy particles can be divided into three sub-stages, beginning with the formation of a wet-spot, increase of contact angle with near-constant contact line, and finally growth with constant contact angle. The growth rate of nuclei also increases with the size of high energy particles.

  10. Environmental geochemistry for surface and subsurface waters in the Pajarito Plateau and outlying areas, New Mexico

    SciTech Connect (OSTI)

    Blake, W.D.; Goff, F.; Adams, A.I.; Counce, D.

    1995-05-01

    This report provides background information on waters in the Los Alamos and Santa Fe regions of northern New Mexico. Specifically, the presented data include major element, trace element, and isotope analyses of 130 water samples from 94 different springs, wells, and water bodies in the area. The region considered in this study extends from the western edge of the Valles Caldera to as far east as Santa Fe Lake. For each sample, the presented analysis includes fourteen different major elements, twenty-six trace elements, up to five stable isotopes, and tritium. In addition, this data base contains certain characteristics of the water that are calculated from the aforementioned raw data, including the water`s maximum and minimum residence times, as found from tritium levels assuming no contamination, the water`s recharge elevation, as found from stable isotopes, and the charge balance of the water. The data in this report are meant to provide background information for investigations in groundwater hydrology and geochemistry, and for environmental projects. For the latter projects, the presented information would be useful for determining the presence of contamination it any one location by enabling one to compare potential contaminant levels to the background levels presented here. Likely locations of interest are those possibly effected by anthropogenic activities, including locations in and around Los Alamos National Laboratory, White Rock Canyon, and developed areas in the Rio Grande Valley.

  11. Surface topography of a palladium cathode after electrolysis in heavy water

    SciTech Connect (OSTI)

    Silver, D.S. ); Dash, J.; Keefe, P.S. )

    1993-12-01

    Electrolysis was performed with a palladium cathode and an electrolyte containing both hydrogen and deuterium ions. The cathode bends toward the anode during this process. Examination of both the concave and the convex surfaces with the scanning electron microscope, scanning tunneling microscope, and atomic force microscope shows unusual surface characteristics. Rimmed craters with faceted crystals inside and multitextural surfaces were observed on an electrolyzed palladium cathode but not on palladium that has not been electrolyzed. 9 refs., 9 figs.

  12. 3D Simulation of Missing Pellet Surface Defects in Light Water Reactor Fuel Rods

    SciTech Connect (OSTI)

    B.W. Spencer; J.D. Hales; S.R. Novascone; R.L. Williamson

    2012-09-01

    The cladding on light water reactor (LWR) fuel rods provides a stable enclosure for fuel pellets and serves as a first barrier against fission product release. Consequently, it is important to design fuel to prevent cladding failure due to mechanical interactions with fuel pellets. Cladding stresses can be effectively limited by controlling power increase rates. However, it has been shown that local geometric irregularities caused by manufacturing defects known as missing pellet surfaces (MPS) in fuel pellets can lead to elevated cladding stresses that are sufficiently high to cause cladding failure. Accurate modeling of these defects can help prevent these types of failures. Nuclear fuel performance codes commonly use a 1.5D (axisymmetric, axially-stacked, one-dimensional radial) or 2D axisymmetric representation of the fuel rod. To study the effects of MPS defects, results from 1.5D or 2D fuel performance analyses are typically mapped to thermo-mechanical models that consist of a 2D plane-strain slice or a full 3D representation of the geometry of the pellet and clad in the region of the defect. The BISON fuel performance code developed at Idaho National Laboratory employs either a 2D axisymmetric or 3D representation of the full fuel rod. This allows for a computational model of the full fuel rod to include local defects. A 3D thermo-mechanical model is used to simulate the global fuel rod behavior, and includes effects on the thermal and mechanical behavior of the fuel due to accumulation of fission products, fission gas production and release, and the effects of fission gas accumulation on thermal conductivity across the fuel-clad gap. Local defects can be modeled simply by including them in the 3D fuel rod model, without the need for mapping between two separate models. This allows for the complete set of physics used in a fuel performance analysis to be included naturally in the computational representation of the local defect, and for the effects of the local defect to be coupled with the global fuel rod model. This approach for modeling fuel with MPS defects is demonstrated and compared with alternative techniques. The effects of varying parameters of the MPS defect are studied using this technique and presented here.

  13. COMPARISON OF RESULTS FOR QUARTER 5 SURFACE WATER SPLIT SAMPLES COLLECTED AT THE NUCLEAR FUEL SERVICES SITE ERWIN TENNESSEE

    SciTech Connect (OSTI)

    2013-09-23

    Oak Ridge Associated Universities (ORAU), under the Oak Ridge Institute for Science and Education (ORISE) contract, collected split surface water samples with Nuclear Fuel Services (NFS) representatives on August 21, 2013. Representatives from the U.S. Nuclear Regulatory Commission (NRC) and the Tennessee Department of Environment and Conservation were also in attendance. Samples were collected at four surface water stations, as required in the approved Request for Technical Assistance number 11-018. These stations included Nolichucky River upstream (NRU), Nolichucky River downstream (NRD), Martin Creek upstream (MCU), and Martin Creek downstream (MCD). Both ORAU and NFS performed gross alpha and gross beta analyses, and the comparison of results using the duplicate error ratio (DER), also known as the normalized absolute difference, are tabulated. All DER values were less than 3 and results are consistent with low (e.g., background) concentrations.

  14. COMPOUNDING EFFECTS OF FLUID CONFINEMENT AND SURFACE STRAIN ON THE WET-DRY TRANSITION AND DYNAMICS OF GRAPHENE-WATER SYSTEMS

    SciTech Connect (OSTI)

    Chialvo, Ariel A; Vlcek, Lukas; Cummings, Peter

    2015-01-01

    We studied the link between the water-mediated (tensile or compressive) strain-driven hydration free energy changes in the association process involving finite-size graphene surfaces, the resulting water-graphene interfacial behavior, and the combined effect of surface strain and fluid confinement on the thermodynamic response functions and the dynamics of water. We found that either small surface corrugation (compressive strain) or surface stretching (tensile strain) is able to enhance significantly the water-graphene hydrophobicity relative to that of the unstrained surface, an effect that exacerbates the confinement impact on the isothermal compressibility and isobaric thermal expansivity of confined water, as well as on the slowing down of its dynamics that gives rise to anomalous diffusivity.

  15. COMPOUNDING EFFECTS OF FLUID CONFINEMENT AND SURFACE STRAIN ON THE WET-DRY TRANSITION AND DYNAMICS OF GRAPHENE-WATER SYSTEMS

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chialvo, Ariel A; Vlcek, Lukas; Cummings, Peter

    2015-01-01

    We studied the link between the water-mediated (tensile or compressive) strain-driven hydration free energy changes in the association process involving finite-size graphene surfaces, the resulting water-graphene interfacial behavior, and the combined effect of surface strain and fluid confinement on the thermodynamic response functions and the dynamics of water. We found that either small surface corrugation (compressive strain) or surface stretching (tensile strain) is able to enhance significantly the water-graphene hydrophobicity relative to that of the unstrained surface, an effect that exacerbates the confinement impact on the isothermal compressibility and isobaric thermal expansivity of confined water, as well as on themoreslowing down of its dynamics that gives rise to anomalous diffusivity.less

  16. Water Quality

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Quality Water Quality We protect water quality through stormwater control measures and an extensive network of monitoring wells and stations encompassing groundwater, surface...

  17. Surface water processes in the Indonesian Throughflow as documented by a high-resolution coral (Delta)14C record

    SciTech Connect (OSTI)

    Fallon, S J; Guilderson, T P

    2008-04-23

    To explore the seasonal to decadal variability in surface water masses that contribute to the Indonesian Throughflow we have generated a 115-year bi-monthly coral-based radiocarbon time-series from a coral in the Makassar Straits. In the pre-bomb (pre-1955) era from 1890 to 1954, the radiocarbon time series occasionally displays a small seasonal signal (10-15{per_thousand}). After 1954 the radiocarbon record increases rapidly, in response to the increased atmospheric {sup 14}C content caused by nuclear weapons testing. From 1957 to 1986 the record displays clear seasonal variability from 15 to 60{per_thousand} and the post-bomb peak (163 per mil) occurred in 1974. The seasonal cycle of radiocarbon can be attributed to variations of surface waters passing through South Makassar Strait. Southern Makassar is under the influence of the Northwest Monsoon, which is responsible for the high Austral summer radiocarbon (North Pacific waters) and the Southeast Monsoon that flushes back a mixture of low (South Pacific and upwelling altered) radiocarbon water from the Banda Sea. The coral record also shows a significant {sup 14}C peak in 1955 due to bomb {sup 14}C water advected into this region in the form of CaCO{sub 3} particles (this implies that the particles were advected intact and then become entrapped in the coral skeleton--is this what we really mean? Wouldn't even fine particles settle out over the inferred transit time from Bikini to MAK?) or water particles with dissolved labeled CO{sub 2} produced during fallout from the Castle tests in 1954.

  18. User`s Guide: Database of literature pertaining to the unsaturated zone and surface water-ground water interactions at the Idaho National Engineering Laboratory

    SciTech Connect (OSTI)

    Hall, L.F.

    1993-05-01

    Since its beginnings in 1949, hydrogeologic investigations at the Idaho National Engineering Laboratory (INEL) have resulted in an extensive collection of technical publications providing information concerning ground water hydraulics and contaminant transport within the unsaturated zone. Funding has been provided by the Department of Energy through the Department of Energy Idaho Field Office in a grant to compile an INEL-wide summary of unsaturated zone studies based on a literature search. University of Idaho researchers are conducting a review of technical documents produced at or pertaining to the INEL, which present or discuss processes in the unsaturated zone and surface water-ground water interactions. Results of this review are being compiled as an electronic database. Fields are available in this database for document title and associated identification number, author, source, abstract, and summary of information (including types of data and parameters). AskSam{reg_sign}, a text-based database system, was chosen. WordPerfect 5.1{copyright} is being used as a text-editor to input data records into askSam.

  19. Decoupling Bulk and Surface Contributions in Water- Splitting Photocatalysts by In Situ Ultrafast Spectroscopy

    SciTech Connect (OSTI)

    Appavoo, Kannatassen; Mingzhao, Liu; Black, Charles T.; Sfeir, Matthew Y.

    2015-05-10

    By performing ultrafast emission spectroscopy in an operating, bias-controlled photoelectrochemical cell, we distinguish between bulk (charge transport) and surface (chemical reaction) recombination processes in a nanostructured photocatalyst and correlate its electronic properties directly with its incident-photon-to-current efficiency.

  20. Y-12 Groundwater Protection Program Groundwater And Surface Water Sampling And Analysis Plan For Calendar Year 2012

    SciTech Connect (OSTI)

    Elvado Environmental, LLC

    2011-09-01

    This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2012 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring performed by the GWPP during CY 2012 is in accordance with the following goals: (1) to protect the worker, the public, and the environment; (2) to maintain surveillance of existing and potential groundwater contamination sources; (3) to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; (4) to identify and characterize long-term trends in groundwater quality at Y-12; and (5) to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring will be performed in three hydrogeologic regimes at Y-12: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley and the Chestnut Ridge Regime is located south of Y-12 (Figure A.1). Additional surface water monitoring will be performed north of Pine Ridge along the boundary of the Oak Ridge Reservation. Modifications to the CY 2012 monitoring program may be necessary during implementation. Changes in programmatic requirements may alter the analytes specified for selected monitoring wells or may add or remove wells from the planned monitoring network. Each modification to the monitoring program will be approved by the Y-12 GWPP manager and documented as an addendum to this sampling and analysis plan. The following sections of this report provide details regarding the CY 2012 groundwater and surface water monitoring activities. Section 2 describes the monitoring locations in each regime and the processes used to select the sampling locations. A description of the field measurements and laboratory analytes is provided in Section 3. Sample collection methods and procedures are described in Section 4, and Section 5 lists the documents cited for more detailed operational and technical information. The narrative sections of the report reference several appendices. Figures (maps and diagrams) and tables (excluding a data summary table presented in Section 4) are in Appendix A and Appendix B, respectively. Groundwater Monitoring Schedules (when issued throughout CY 2012) will be inserted in Appendix C, and addenda to this plan (if issued) will be inserted in Appendix D. Laboratory requirements (bottle lists, holding times, etc.) are provided in Appendix E, and an approved Waste Management Plan is provided in Appendix F.

  1. Literature and data review for the surface-water pathway: Columbia River and adjacent coastal areas

    SciTech Connect (OSTI)

    Walters, W.H.; Dirkes, R.L.; Napier, B.A.

    1992-04-01

    As part of the Hanford Environmental Dose Reconstruction Project, Pacific Northwest Laboratory reviewed literature and data on radionuclide concentrations and distribution in the water, sediment, and biota of the Columbia River and adjacent coastal areas. Over 600 documents were reviewed including Hanford reports, reports by offsite agencies, journal articles, and graduate theses. Certain radionuclide concentration data were used in preliminary estimates of individual dose for the 1964--1966 time period. This report summarizes the literature and database review and the results of the preliminary dose estimates.

  2. COMPARISON OF RESULTS FOR QUARTER 2 SURFACE WATER SPLIT SAMPLES COLLECTED AT THE NUCLEAR FUEL SERVICES SITE, ERWIN, TENNESSEE

    SciTech Connect (OSTI)

    2013-01-21

    Oak Ridge Associated Universities (ORAU), under the Oak Ridge Institute for Science and Education (ORISE) contract, collected split surface water samples with Nuclear Fuel Services (NFS) representatives on November 15, 2012. Representatives from the U.S. Nuclear Regulatory Commission and Tennessee Department of Environment and Conservation were also in attendance. Samples were collected at four surface water stations, as required in the approved Request for Technical Assistance number 11-018. These stations included Nolichucky River upstream (NRU), Nolichucky River downstream (NRD), Martin Creek upstream (MCU), and Martin Creek downstream (MCD). Both ORAU and NFS performed gross alpha and gross beta analyses, and the results are compared using the duplicate error ratio (DER), also known as the normalized absolute difference. A DER {<=} 3 indicates that, at a 99% confidence interval, split sample results do not differ significantly when compared to their respective one standard deviation (sigma) uncertainty (ANSI N42.22). The NFS split sample report does not specify the confidence level of reported uncertainties (NFS 2012). Therefore, standard two sigma reporting is assumed and uncertainty values were divided by 1.96. In conclusion, all DER values were less than 3 and results are consistent with low (e.g., background) concentrations.

  3. Modelling On Photogeneration Of Hydroxyl Radical In Surface Waters And Its Reactivity Towards Pharmaceutical Wastes

    SciTech Connect (OSTI)

    Das, Radha; Vione, Davide; Rubertelli, Francesca; Maurino, Valter; Minero, Claudio; Barbati, Stephane; Chiron, Serge

    2010-10-26

    This paper reports a simple model to describe the formation and reactivity of hydroxyl radicals in the whole column of freshwater lakes. It is based on empirical irradiation data and is a function of the water chemical composition (the photochemically significant parameters NPOC, nitrate, nitrite, carbonate and bicarbonate), the lake conformation best expressed as the average depth, and the water absorption spectrum in a simplified Lambert-Beer approach. The purpose is to derive the lifetime of dissolved molecules, due to reaction with OH, on the basis of their second-order rate constants with the hydroxyl radical. The model was applied to two compounds of pharmaceutical wastes ibuprofen and carbamazepine, for which the second-order rate constants for reaction with the hydroxyl radical were measured by means of the competition kinetics with 2-propanol. The measured values of the rate constants are 1.0x10{sup 10} and 1.6x10{sup 10} M{sup -1} s{sup -1} for ibuprofen and carbamazepine, respectively. The model suggests that the lifetime of a given compound can be very variable in different lakes, even more than the lifetime of different compounds in the same lake. It can be concluded that as far as the reaction with OH, is concerned the concepts of photolability and photostability, traditionally attached to definite compounds, are ecosystem-dependent at least as much as they depend on the molecule under consideration.

  4. Use of Remote Technology in the Surface Water Environmental Monitoring Program at SRS Reducing Measurements in the Field - 13336

    SciTech Connect (OSTI)

    Eddy, T.; Terry, B.; Meyer, A.; Hall, J.; Allen, P.; Hughey, D.; Hartley, T.

    2013-07-01

    There are a wide range of sensor and remote technology applications available for use in environmental monitoring programs. Each application has its own set of limitations and can be challenging when attempting to utilize it under diverse environmental field conditions. The Savannah River Site Environmental Monitoring Program has implemented several remote sensing and surface water flow technologies that have increased the quality of the data while reducing the number of field measurements. Implementation of this technology reduced the field time for personnel that commute across the Savannah River Site (SRS) over a span of 310 square miles. The wireless surface water flow technology allows for immediate notification of changing field conditions or equipment failure thus reducing data-loss or erroneous field data and improving data-quality. This wireless flow technology uses the stage-to-flow methodology coupled with implementation of a robust highly accurate Acoustic Doppler Profiler system for measuring discharge under various field conditions. Savings for implementation of the wireless flow application and Flowlink{sup R} technology equates to approximately 1175 hours annually for the radiological liquid effluent and surveillance programs. The SonTek River Suveyor and Flowtracker technologies are utilized for calibration of the wireless flow monitoring devices in the site streams and validation of effluent flows at the SRS. Implementation of similar wireless devices is also planned in the National Pollutant Discharge Elimination System (NPDES) Storm-water Monitoring Program. SRS personnel have been developing a unique flow actuator device. This device activates an ISCO{sup TM} automated sampler under flowing conditions at storm-water outfall locations across the site. This technology is unique in that it was designed to be used under field conditions with rapid changes in flow and sedimentation where traditional actuators have been unsuccessful in tripping the automated sampler. In addition, automated rain gauges will be tied into this technology for immediate notification of rain at storm-water locations further enhancing the automation of environmental data collection. These technological improvements at SRS have led to data-quality improvements while reducing the field technician time in the field and costs for maintaining the traditional environmental monitoring applications. (authors)

  5. A modeling study of irrigation effects on global surface water and groundwater resources under a changing climate

    SciTech Connect (OSTI)

    Leng, Guoyong; Huang, Maoyi; Tang, Qiuhong; Leung, Lai-Yung R.

    2015-08-25

    Abstract In this study, the effects of irrigation on global surface water (SW) and groundwater (GW) resources are investigated by performing simulations using Community Land Model 4.0 (CLM4) at 0.5-degree resolution driven by downscaled/bias-corrected historical simulations and future projections from five General Circulation Models (GCMs) for 1950-2099. For each climate scenario, three sets of numerical experiments were configured: (1) a control experiment (CTRL) in which all crops are assumed to be rainfed; (2) an irrigation experiment (IRRIG) in which the irrigation module using only SW for irrigation is activated; and (3) a groundwater pumping experiment (PUMP) in which a groundwater pumping scheme coupled with the irrigation module is activated for conjunctive use of SW and GW for irrigation. The parameters associated with irrigation and groundwater pumping are calibrated based on a global inventory of census-based SW and GW use compiled by the Food and Agricultural Organization (FAO). Our results suggest that irrigation could lead to two major opposing effects: SW depletion/GW accumulation in regions with irrigation primarily fed by SW, and SW accumulation/GW depletion in regions with irrigation fed primarily by GW. Furthermore, irrigation depending primarily on SW tends to have larger impacts on low-flow than high-flow conditions, suggesting the potential to increase vulnerability to drought. By the end of the 21st century (2070-2099), climate change significantly increases (relative to 1971-2000) irrigation water demand across the world. Combined with the increased temporal-spatial variability of water supply, this may lead to severe issues of local water scarcity for irrigation. Regionally, irrigation has the potential to aggravate/alleviate climate-induced changes of SW/GW although such effects are negligible when averaged globally. Our results emphasize the importance of accounting for irrigation effects and irrigation sources in regional climate change impact assessment.

  6. Determination of Large-Scale Cloud Ice Water Concentration by Combining Surface Radar and Satellite Data in Support of ARM SCM Activities

    SciTech Connect (OSTI)

    Liu, Guosheng

    2013-03-15

    Single-column modeling (SCM) is one of the key elements of Atmospheric Radiation Measurement (ARM) research initiatives for the development and testing of various physical parameterizations to be used in general circulation models (GCMs). The data required for use with an SCM include observed vertical profiles of temperature, water vapor, and condensed water, as well as the large-scale vertical motion and tendencies of temperature, water vapor, and condensed water due to horizontal advection. Surface-based measurements operated at ARM sites and upper-air sounding networks supply most of the required variables for model inputs, but do not provide the horizontal advection term of condensed water. Since surface cloud radar and microwave radiometer observations at ARM sites are single-point measurements, they can provide the amount of condensed water at the location of observation sites, but not a horizontal distribution of condensed water contents. Consequently, observational data for the large-scale advection tendencies of condensed water have not been available to the ARM cloud modeling community based on surface observations alone. This lack of advection data of water condensate could cause large uncertainties in SCM simulations. Additionally, to evaluate GCMs’ cloud physical parameterization, we need to compare GCM results with observed cloud water amounts over a scale that is large enough to be comparable to what a GCM grid represents. To this end, the point-measurements at ARM surface sites are again not adequate. Therefore, cloud water observations over a large area are needed. The main goal of this project is to retrieve ice water contents over an area of 10 x 10 deg. surrounding the ARM sites by combining surface and satellite observations. Built on the progress made during previous ARM research, we have conducted the retrievals of 3-dimensional ice water content by combining surface radar/radiometer and satellite measurements, and have produced 3-D cloud ice water contents in support of cloud modeling activities. The approach of the study is to expand a (surface) point measurement to an (satellite) area measurement. That is, the study takes the advantage of the high quality cloud measurements (particularly cloud radar and microwave radiometer measurements) at the point of the ARM sites. We use the cloud ice water characteristics derived from the point measurement to guide/constrain a satellite retrieval algorithm, then use the satellite algorithm to derive the 3-D cloud ice water distributions within an 10° (latitude) x 10° (longitude) area. During the research period, we have developed, validated and improved our cloud ice water retrievals, and have produced and archived at ARM website as a PI-product of the 3-D cloud ice water contents using combined satellite high-frequency microwave and surface radar observations for SGP March 2000 IOP and TWP-ICE 2006 IOP over 10 deg. x 10 deg. area centered at ARM SGP central facility and Darwin sites. We have also worked on validation of the 3-D ice water product by CloudSat data, synergy with visible/infrared cloud ice water retrievals for better results at low ice water conditions, and created a long-term (several years) of ice water climatology in 10 x 10 deg. area of ARM SGP and TWP sites and then compared it with GCMs.

  7. COMPARISON OF RESULTS FOR QUARTER 4 SURFACE WATER SPLIT SAMPLES COLLECTED AT THE NUCLEAR FUELS SERVICES SITE, ERWIN, TN

    SciTech Connect (OSTI)

    none,

    2013-08-15

    Oak Ridge Associated Universities (ORAU), under the Oak Ridge Institute for Science and Education (ORISE) contract, collected split surface water samples with Nuclear Fuel Services (NFS) representatives on June 12, 2013. Representatives from the U.S. Nuclear Regulatory Commission (NRC) and the Tennessee Department of Environment and Conservation were also in attendance. Samples were collected at four surface water stations, as required in the approved Request for Technical Assistance number 11-018. These stations included Nolichucky River upstream (NRU), Nolichucky River downstream (NRD), Martin Creek upstream (MCU), and Martin Creek downstream (MCD). Both ORAU and NFS performed gross alpha and gross beta analyses, and Table 1 presents the comparison of results using the duplicate error ratio (DER), also known as the normalized absolute difference. A DER ≤ 3 indicates at a 99% confidence interval that split sample results do not differ significantly when compared to their respective one standard deviation (sigma) uncertainty (ANSI N42.22). The NFS split sample report specifies 95% confidence level of reported uncertainties (NFS 2013). Therefore, standard two sigma reporting values were divided by 1.96. In conclusion, most DER values were less than 3 and results are consistent with low (e.g., background) concentrations. The gross beta result for sample 5198W0014 was the exception. The ORAU gross beta result of 6.30 ± 0.65 pCi/L from location NRD is well above NFS's non-detected result of 1.56 ± 0.59 pCi/L. NFS's data package includes no detected result for any radionuclide at location NRD. At NRC's request, ORAU performed gamma spectroscopic analysis of sample 5198W0014 to identify analytes contributing to the relatively elevated gross beta results. This analysis identified detected amounts of naturally-occurring constituents, most notably Ac-228 from the thorium decay series, and does not suggest the presence of site-related contamination.

  8. Surface Environmental Surveillance Project: Locations Manual Volume 1 Air and Water Volume 2 Farm Products, Soil & Vegetation, and Wildlife

    SciTech Connect (OSTI)

    Fritz, Brad G.; Patton, Gregory W.; Stegen, Amanda; Poston, Ted M.

    2009-01-01

    This report describes all environmental monitoring locations associated with the Surface Environmental Surveillance Project. Environmental surveillance of the Hanford site and surrounding areas is conducted by the Pacific Northwest National Laboratory (PNNL) for the U.S. Department of Energy (DOE). Sampling is conducted to evaluate levels of radioactive and nonradioactive pollutants in the Hanford environs, as required in DOE Order 450.1, Environmental Protection Program, and DOE Order 5400.5, Radiation Protection of the Public and the Environment. The environmental surveillance sampling design is described in the Hanford Site Environmental Monitoring Plan, United States Department of Energy, Richland Operation Office (DOE/RL-91-50). This document contains the locations of sites used to collect samples for the Surface Environmental Surveillance Project (SESP). Each section includes directions, maps, and pictures of the locations. A general knowledge of roads and highways on and around the Hanford Site is necessary to successfully use this manual. Supplemental information (Maps, Gazetteer, etc.) may be necessary if user is unfamiliar with local routes. The SESP is a multimedia environmental surveillance effort to measure the concentrations of radionuclides and chemicals in environmental media to demonstrate compliance with applicable environmental quality standards and public exposure limits, and assessing environmental impacts. Project personnel annually collect selected samples of ambient air, surface water, agricultural products, fish, wildlife, and sediments. Soil and vegetation samples are collected approximately every 5 years. Analytical capabilities include the measurement of radionuclides at very low environmental concentrations and, in selected media, nonradiological chemicals including metals, anions, volatile organic compounds, and total organic carbon.

  9. Characterization of Surface Water/Groundwater Exchange Regulating Uranium Transport Using Electrical Imaging and Distributed Temperature Sensing Methods

    SciTech Connect (OSTI)

    Lee D. Slater; Dimitrios Ntarlagiannis; Fred Day-Lewis; Kisa Mwakanyamale; Roelof J Versteeg; Andy Ward; Christopher Strickland; Carole D. Johnson; John Lane

    2010-10-01

    A critical challenge in advancing prediction of solute transport between contaminated aquifers and rivers is improving understanding of how fluctuations in river stage, combined with subsurface heterogeneity, impart spatiotemporal complexity to solute exchange along river corridors. Here, we explored the use of continuous waterborne electrical imaging (CWEI), in conjunction with fiber-optic distributed temperature sensor (FO-DTS) monitoring, to improve the conceptual model for uranium transport within the river corridor at the Hanford 300 Area. We first inverted CWEI (resistivity and induced polarization) datasets for distributions of electrical resistivity and polarizability, from which the spatial complexity of the primary hydrogeologic units was reconstructed. Variations in the depth to the interface between the overlying coarse-grained, high permeability Hanford formation and the underlying finer grained, less permeable Ringold formation, an important contact that limits vertical migration of contaminants, were resolved along ~3 km of the river corridor centered on the 300 Area. Polarizability images were translated into lithologic images using established relationships between polarizability and surface area normalized to pore volume (Spor). Spatial variability in the thickness of the Hanford formation captured in the CWEI datasets indicates that previous studies based on borehole projections and drive-point and multi-level sampling overestimate the contributing area for uranium exchange within the Columbia River at the Hanford 300 Area. The FO- DTS data recorded along a 1.5 km of cable with a 1-m spatial resolution and 5-minute sampling interval revealed sub-reaches showing (1) temperature anomalies (relatively warm in winter and cool in summer) and, (2) a strong correlation between temperature and river stage (negative in winter and positive in summer), both indicative of reaches of enhanced surface water/groundwater exchange. The FO-DTS datasets confirm the hydrologic significance of the variability identified in the CWEI and reveal a pattern of highly focused exchange, with exchange concentrated at springs where the Hanford formation is thick, and coinciding with a paleochannel identified in ground penetrating radar surveys at one location. No evidence for focused exchange is observed in the FO-DTS data where the Ringold unit is in contact with the riverbed or the Hanford formation is thin. Our findings illustrate how the combination of CWEI and FO-DTS technologies can characterize surface water/groundwater exchange in a complex, coupled river-aquifer system.

  10. Communication: Salt-induced water orientation at a surface of non-ionic surfactant in relation to a mechanism of Hofmeister effect

    SciTech Connect (OSTI)

    Hishida, Mafumi; Kaneko, Yohei; Okuno, Masanari; Yamamura, Yasuhisa; Ishibashi, Taka-aki; Saito, Kazuya

    2015-05-07

    The behavior of water molecules at the surface of nonionic surfactant (monomyristolein) and effects of monovalent ions on the behavior are investigated using the heterodyne-detected vibrational sum frequency generation spectroscopy. It is found that water molecules at the surface are oriented with their hydrogen atoms pointing to the bulk, and that the degree of orientation depends on the anion strongly but weakly on the cation. With measured surface potentials in those saline solutions, it is concluded that the heterogeneous distribution of anions and cations in combination with the nonionic surfactant causes the water orientation. This heterogeneous distribution well explains the contrasting order of anions and cations with respect to the ion size in the Hofmeister series.

  11. COMPARISON OF RESULTS FOR QUARTER 3 SURFACE WATER SPLIT SAMPLES COLLECTED AT THE NUCLEAR FUEL SERVICES SITE, ERWIN, TENNESSEE

    SciTech Connect (OSTI)

    none,

    2013-05-28

    Oak Ridge Associated Universities (ORAU), under the Oak Ridge Institute for Science and Education (ORISE) contract, collected split surface water samples with Nuclear Fuel Services (NFS) representatives on March 20, 2013. Representatives from the U.S. Nuclear Regulatory Commission and the Tennessee Department of Environment and Conservation were also in attendance. Samples were collected at four surface water stations, as required in the approved Request for Technical Assistance number 11-018. These stations included Nolichucky River upstream (NRU), Nolichucky River downstream (NRD), Martin Creek upstream (MCU), and Martin Creek downstream (MCD). Both ORAU and NFS performed gross alpha and gross beta analyses, and Table 1 presents the comparison of results using the duplicate error ratio (DER), also known as the normalized absolute difference. A DER {<=} 3 indicates that at a 99% confidence interval, split sample results do not differ significantly when compared to their respective one standard deviation (sigma) uncertainty (ANSI N42.22). The NFS split sample report does not specify the confidence level of reported uncertainties (NFS 2013). Therefore, standard two sigma reporting is assumed and uncertainty values were divided by 1.96. In conclusion, most DER values were less than 3 and results are consistent with low (e.g., background) concentrations. The gross beta result for sample 5198W0012 was the exception. The ORAU result of 9.23 ± 0.73 pCi/L from location MCD is well above NFS's result of -0.567 ± 0.63 pCi/L (non-detected). NFS's data package included a detected result for U-233/234, but no other uranium or plutonium detection, and nothing that would suggest the presence of beta-emitting radionuclides. The ORAU laboratory reanalyzed sample 5198W0012 using the remaining portion of the sample volume and a result of 11.3 ± 1.1 pCi/L was determined. As directed, the laboratory also counted the filtrate using gamma spectrometry analysis and identified only naturally occurring or ubiquitous man-made constituents, including beta emitters that are presumably responsible for the elevated gross beta values.

  12. Environmental impact of APC residues from municipal solid waste incineration: Reuse assessment based on soil and surface water protection criteria

    SciTech Connect (OSTI)

    Quina, Margarida J.; Bordado, Joao C.M.; Quinta-Ferreira, Rosa M.

    2011-09-15

    Highlights: > The Dutch Building Material Decree (BMD) was used to APC residues from MSWI. > BMD is a straightforward tool to calculate expectable loads to the environment of common pollutants. > Chloride load to the environment lead to classification of building material not allowed. > At least a pre-treatment (e.g. washing) is required in order to remove soluble salts. > The stabilization with phosphates or silicates eliminate the problem of heavy metals. - Abstract: Waste management and environmental protection are mandatory requirements of modern society. In our study, air pollution control (APC) residues from municipal solid waste incinerators (MSWI) were considered as a mixture of fly ash and fine particulate solids collected in scrubbers and fabric filters. These are hazardous wastes and require treatment before landfill. Although there are a number of treatment options, it is highly recommended to find practical applications rather than just dump them in landfill sites. In general, for using a construction material, beyond technical specifications also soil and surface water criteria may be used to ensure environmental protection. The Dutch Building Materials Decree (BMD) is a valuable tool in this respect and it was used to investigate which properties do not meet the threshold criteria so that APC residues can be further used as secondary building material. To this end, some scenarios were evaluated by considering release of inorganic species from unmoulded and moulded applications. The main conclusion is that the high amount of soluble salts makes the APC residues a building material prohibited in any of the conditions tested. In case of moulding materials, the limits of heavy metals are complied, and their use in Category 1 would be allowed. However, also in this case, the soluble salts lead to the classification of 'building material not allowed'. The treatments with phosphates or silicates are able to solve the problem of heavy metals, but difficulties with the soluble salts are still observed. This analysis suggests that for APC residues to comply with soil and surface water protection criteria to be further used as building material at least a pre-treating for removing soluble salts is absolutely required.

  13. Quantum calculations of the IR spectrum of liquid water using ab initio and model potential and dipole moment surfaces and comparison with experiment

    SciTech Connect (OSTI)

    Liu, Hanchao; Wang, Yimin; Bowman, Joel M.

    2015-05-21

    The calculation and characterization of the IR spectrum of liquid water have remained a challenge for theory. In this paper, we address this challenge using a combination of ab initio approaches, namely, a quantum treatment of IR spectrum using the ab initio WHBB water potential energy surface and a refined ab initio dipole moment surface. The quantum treatment is based on the embedded local monomer method, in which the three intramolecular modes of each embedded H{sub 2}O monomer are fully coupled and also coupled singly to each of six intermolecular modes. The new dipole moment surface consists of a previous spectroscopically accurate 1-body dipole moment surface and a newly fitted ab initio intrinsic 2-body dipole moment. A detailed analysis of the new dipole moment surface in terms of the coordinate dependence of the effective atomic charges is done along with tests of it for the water dimer and prism hexamer double-harmonic spectra against direct ab initio calculations. The liquid configurations are taken from previous molecular dynamics calculations of Skinner and co-workers, using the TIP4P plus E3B rigid monomer water potential. The IR spectrum of water at 300 K in the range of 04000 cm{sup ?1} is calculated and compared with experiment, using the ab initio WHBB potential and new ab initio dipole moment, the q-TIP4P/F potential, which has a fixed-charged description of the dipole moment, and the TTM3-F potential and dipole moment surfaces. The newly calculated ab initio spectrum is in very good agreement with experiment throughout the above spectral range, both in band positions and intensities. This contrasts to results with the other potentials and dipole moments, especially the fixed-charge q-TIP4P/F model, which gives unrealistic intensities. The calculated ab initio spectrum is analyzed by examining the contribution of various transitions to each band.

  14. A NEW SOURCE OF CO{sub 2} IN THE UNIVERSE: A PHOTOACTIVATED ELEY-RIDEAL SURFACE REACTION ON WATER ICES

    SciTech Connect (OSTI)

    Yuan, Chunqing; Cooke, Ilsa R.; Yates, John T. Jr.

    2014-08-20

    CO{sub 2} is one of the most abundant components of ices in the interstellar medium; however, its formation mechanism has not been clearly identified. Here we report an experimental observation of an Eley-Rideal-type reaction on a water ice surface, where CO gas molecules react by direct collisions with surface OH radicals, made by photodissociation of H{sub 2}O molecules, to produce CO{sub 2} ice on the surface. The discovery of this source of CO{sub 2} provides a new mechanism to explain the high relative abundance of CO{sub 2} ice in space.

  15. Time-resolved surface infrared spectroscopy during atomic layer deposition of TiO{sub 2} using tetrakis(dimethylamido)titanium and water

    SciTech Connect (OSTI)

    Sperling, Brent A. Hoang, John; Kimes, William A.; Maslar, James E.; Steffens, Kristen L.; Nguyen, Nhan V.

    2014-05-15

    Atomic layer deposition of titanium dioxide using tetrakis(dimethylamido)titanium (TDMAT) and water vapor is studied by reflection-absorption infrared spectroscopy (RAIRS) with a time resolution of 120?ms. At 190?C and 240?C, a decrease in the absorption from adsorbed TDMAT is observed without any evidence of an adsorbed product. Ex situ measurements indicate that this behavior is not associated with an increase in the impurity concentration or a dramatic change in the growth rate. A desorbing decomposition product is consistent with these observations. RAIRS also indicates that dehydroxylation of the growth surface occurs only among one type of surface hydroxyl groups. Molecular water is observed to remain on the surface and participates in reactions even at a relatively high temperature (110?C) and with long purge times (30?s)

  16. MEASUREMENTS OF PAST 14C LEVELS AND 13C/12C RATIOS IN THE SURFACE WATERS OF THE WORLD'S SUBPOLAR OCEANS.

    SciTech Connect (OSTI)

    Brown, T A

    2010-04-22

    Under this project we have developed methods that allow the reconstruction of past {sup 14}C levels of the surface waters of the subpolar North Pacific Ocean by measuring the {sup 14}C contents of archived salmon scales. The overall goal of this research was to reduce of the uncertainty in the uptake of fossil CO{sub 2} by the oceans and thereby improve the quantification of the global carbon cycle and to elucidate the fate of anthropogenic CO{sub 2}. Ocean General Circulation Models (OGCMs), with their three dimensional global spatial coverage and temporal modeling capabilities, provide the best route to accurately calculating the total uptake of CO{sub 2} by the oceans and, hence, to achieving the desired reduction in uncertainty. {sup 14}C has played, and continues to play, a central role in the validation of the OGCMs calculations, particularly with respect to those model components which govern the uptake of CO{sub 2} from the atmosphere and the transport of this carbon within the oceans. Under this project, we have developed time-series records of the {sup 14}C levels of the surface waters of three areas of the subpolar North Pacific Ocean. As the previously available data on the time-history of oceanic surface water {sup 14}C levels are very limited, these time-series records provide significant new {sup 14}C data to constrain and validate the OGCMs.

  17. Materials for light-induced water splitting: In situ controlled surface preparation of GaPN epilayers grown lattice-matched on Si(100)

    SciTech Connect (OSTI)

    Supplie, Oliver; May, Matthias M.; Stange, Helena; Hhn, Christian; Lewerenz, Hans-Joachim; Hannappel, Thomas

    2014-03-21

    Energy storage is a key challenge in solar-driven renewable energy conversion. We promote a photochemical diode based on dilute nitride GaPN grown lattice-matched on Si(100), which could reach both high photovoltaic efficiencies and evolve hydrogen directly without external bias. Homoepitaxial GaP(100) surface preparation was shown to have a significant impact on the semiconductor-water interface formation. Here, we grow a thin, pseudomorphic GaP nucleation buffer on almost single-domain Si(100) prior to GaPN growth and compare the GaP{sub 0.98}N{sub 0.02}/Si(100) surface preparation to established P- and Ga-rich surfaces of GaP/Si(100). We apply reflection anisotropy spectroscopy to study the surface preparation of GaP{sub 0.98}N{sub 0.02} in situ in vapor phase epitaxy ambient and benchmark the signals to low energy electron diffraction, photoelectron spectroscopy, and x-ray diffraction. While the preparation of the Ga-rich surface is hardly influenced by the presence of the nitrogen precursor 1,1-dimethylhydrazine (UDMH), we find that stabilization with UDMH after growth hinders well-defined formation of the V-rich GaP{sub 0.98}N{sub 0.02}/Si(100) surface. Additional features in the reflection anisotropy spectra are suggested to be related to nitrogen incorporation in the GaP bulk.

  18. Water Security

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Security Home/Water Security - Electricity use by water service sector and county. Shown are electricity use by (a) large-scale conveyance, (b) groundwater irrigation pumping, (c) surface water irrigation pumping, (d) drinking water, and (e) wastewater. Aggregate electricity use across these sectors (f) is also mapped. Permalink Gallery Sandians Recognized in Environmental Science & Technology's Best Paper Competition Analysis, Capabilities, Energy, Energy-Water Nexus, Global, Global,

  19. ARM - Measurement - Sea surface temperature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sea surface temperature The temperature of sea water near the surface. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the...

  20. Surface Complexation of Neodymium at the Rutile-Water Interface: A Potentiometric and Modeling Study in NaCl Media to 250C

    SciTech Connect (OSTI)

    Ridley, Mora K.; Machesky, Michael L.; Wesolowski, David J; Palmer, Donald

    2005-01-01

    The adsorption of Nd{sup 3+} onto rutile surfaces was examined by potentiometric titration from 25 to 250 C, in 0.03 and 0.30m NaCl background electrolyte. Experimental results show that Nd{sup 3+} sorbs strongly, even at low temperature, with adsorption commencing below the pHznpc of rutile. In addition, there is a systematic increase in Nd{sup 3+} adsorption with increasing temperature. The experimental results were rationalized and described using surface oxygen proton affinities computed from the MUlti SIte Complexation or MUSIC model, coupled with a Stern-based three-layer description of the oxide/water interface. Moreover, molecular-scale information was incorporated successfully into the surface complexation model, providing a unique geometry for the adsorption of Nd{sup 3+} on rutile. The primary mode of Nd{sup 3+} adsorption was assumed to be the tetradentate configuration found for Y{sup 3+} adsorption on the rutile (110) surface from previously described in situ X-ray standing wave experiments, wherein the sorbing cations bond directly with two adjacent ''terminal'' and two adjacent ''bridging'' surface oxygen atoms. Similarly, the adsorption of Na{sup +} counterions was also assumed to be tetradentate, as supported by MD simulations of Na{sup +} interactions with the rutile (110) surface, and by analogous X-ray standing wave results for Rb{sup +} adsorption on rutile. Fitting parameters for Nd{sup 3+} adsorption included binding constants for the tetradentate adsorption complex and capacitance values for the inner-sphere binding plane. In addition, hydrolysis of the tetradentate adsorption complex was permitted and resulted in significantly improved model fits at higher temperature and pH values. The modeling results indicate that the Stern-based MUSIC surface-complexation model adequately accommodates molecular-scale information to uniquely rationalize and describe multivalent ion adsorption systematically into the hydrothermal regime.

  1. Water adsorption onto Y and V sites at the surface of the YVO{sub 4} photocatalyst and related electronic properties

    SciTech Connect (OSTI)

    Oshikiri, Mitsutake; Matsushita, Akiyuki; Ye, Jinhua; Boero, Mauro

    2009-07-21

    The dynamics of water molecules and the adsorption properties at the V and Y sites on the surface of the photocatalyst YVO{sub 4} have been investigated by first principles molecular dynamics. This system has shown an excellent performance in the production of both hydrogen and oxygen in the ultraviolet region. Yet, its catalytic properties, related to the electronic structure, are poorly understood. Here we show that imperfectly oxygen coordinated V sites (i.e., not fourfold oxygen coordinated vanadium but threefold oxygen coordinated vanadium) exposed on the catalyst surface play a central role in the dissociation of water molecules. By simulating the H{sub 2}O adsorption process and by performing an analysis of the electronic structure of the unoccupied orbitals corresponding to the lowest unoccupied energy level of the system, we can infer that the dissociation of water at these imperfectly oxygen coordinated V sites can promote the proton reduction and is expected to trigger the H{sub 2} generation.

  2. Site characterization summary report for dry weather surface water sampling upper East Fork Poplar Creek characterization area Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    NONE

    1996-08-01

    This report describes activities associated with conducting dry weather surface water sampling of Upper East Fork Poplar Creek (UEFPC) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee. This activity is a portion of the work to be performed at UEFPC Operable Unit (OU) 1 [now known as the UEFPC Characterization Area (CA)], as described in the RCRA Facility Investigation Plan for Group 4 at the Oak- Ridge Y-12 Plant, Oak Ridge, Tennessee and in the Response to Comments and Recommendations on RCRA Facility Investigation Plan for Group 4 at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee, Volume 1, Operable Unit 1. Because these documents contained sensitive information, they were labeled as unclassified controlled nuclear information and as such are not readily available for public review. To address this issue the U.S. Department of Energy (DOE) published an unclassified, nonsensitive version of the initial plan, text and appendixes, of this Resource Conservation and Recovery Act (RCRA) Facility Investigation (RFI) Plan in early 1994. These documents describe a program for collecting four rounds of wet weather and dry weather surface water samples and one round of sediment samples from UEFPC. They provide the strategy for the overall sample collection program including dry weather sampling, wet weather sampling, and sediment sampling. Figure 1.1 is a schematic flowchart of the overall sampling strategy and other associated activities. A Quality Assurance Project Plan (QAPJP) was prepared to specifically address four rounds of dry weather surface water sampling and one round of sediment sampling. For a variety of reasons, sediment sampling has not been conducted and has been deferred to the UEFPC CA Remedial Investigation (RI), as has wet weather sampling.

  3. Water Quality

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Quality Water Quality We protect water quality through stormwater control measures and an extensive network of monitoring wells and stations encompassing groundwater, surface water, storm water and springs. April 12, 2012 Quarterly Groundwater monitoring attended by LANL managers and the Northern New Mexico Citizens Advisory Board LANL scientists brief the Northern New Mexico Citizens Advisory Board during quarterly groundwater monitoring of the well network around Area G. Contact

  4. Water Security

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SunShot Grand Challenge: Regional Test Centers Water Security Home/Tag:Water Security - Electricity use by water service sector and county. Shown are electricity use by (a) large-scale conveyance, (b) groundwater irrigation pumping, (c) surface water irrigation pumping, (d) drinking water, and (e) wastewater. Aggregate electricity use across these sectors (f) is also mapped. Permalink Gallery Sandians Recognized in Environmental Science & Technology's Best Paper Competition Analysis,

  5. inner-sphere complexation of cations at the rutile-water interface: A concise surface structural interpretation with the CD and MUSIC model

    SciTech Connect (OSTI)

    Ridley, Mora K.; Hiemstra, T; Van Riemsdijk, Willem H.; Machesky, Michael L.

    2009-01-01

    Acid base reactivity and ion-interaction between mineral surfaces and aqueous solutions is most frequently investigated at the macroscopic scale as a function of pH. Experimental data are then rationalized by a variety of surface complexation models. These models are thermodynamically based which in principle does not require a molecular picture. The models are typically calibrated to relatively simple solid-electrolyte solution pairs and may provide poor descriptions of complex multicomponent mineral aqueous solutions, including those found in natural environments. Surface complexation models may be improved by incorporating molecular-scale surface structural information to constrain the modeling efforts. Here, we apply a concise, molecularly-constrained surface complexation model to a diverse suite of surface titration data for rutile and thereby begin to address the complexity of multi-component systems. Primary surface charging curves in NaCl, KCl, and RbCl electrolyte media were fit simultaneously using a charge distribution (CD) and multisite complexation (MUSIC) model [Hiemstra T. and Van Riemsdijk W. H. (1996) A surface structural approach to ion adsorption: the charge distribution (CD) model. J. Colloid Interf. Sci. 179, 488 508], coupled with a Basic Stern layer description of the electric double layer. In addition, data for the specific interaction of Ca2+ and Sr2+ with rutile, in NaCl and RbCl media, were modeled. In recent developments, spectroscopy, quantum calculations, and molecular simulations have shown that electrolyte and divalent cations are principally adsorbed in various inner-sphere configurations on the rutile 110 surface [Zhang Z., Fenter P., Cheng L., Sturchio N. C., Bedzyk M. J., Pr edota M., Bandura A., Kubicki J., Lvov S. N., Cummings P. T., Chialvo A. A., Ridley M. K., Be ne zeth P., Anovitz L., Palmer D. A., Machesky M. L. and Wesolowski D. J. (2004) Ion adsorption at the rutile water interface: linking molecular and macroscopic properties. Langmuir 20, 4954 4969]. Our CD modeling results are consistent with these adsorbed configurations provided adsorbed cation charge is allowed to be distributed between the surface (0-plane) and Stern plane (1-plane). Additionally, a complete description of our titration data required inclusion of outer-sphere binding, principally for Cl which was common to all solutions, but also for Rb+ and K+. These outer-sphere species were treated as point charges positioned at the Stern layer, and hence determined the Stern layer capacitance value. The modeling results demonstrate that a multi-component suite of experimental data can be successfully rationalized within a CD and MUSIC model using a Stern-based description of the EDL. Furthermore, the fitted CD values of the various inner-sphere complexes of the mono- and divalent ions can be linked to the microscopic structure of the surface complexes and other data found by spectroscopy as well as molecular dynamics (MD). For the Na+ ion, the fitted CD value points to the presence of bidenate inner-sphere complexation as suggested by a recent MD study. Moreover, its MD dominance quantitatively agrees with the CD model prediction. For Rb+, the presence of a tetradentate complex, as found by spectroscopy, agreed well with the fitted CD and its predicted presence was quantitatively in very good agreement with the amount found by spectroscopy.

  6. Analysis of the toxicity in Rocky Flats Plant surface water through a correlation between the whole effluent toxicity test and the Microtox assay

    SciTech Connect (OSTI)

    Ford, S.M.; Wolaver, H.A.; Figueroa, L.A.

    1992-07-01

    Results were correlated from the Microtox assay and the whole effluent acute toxicity test for effluents from the (1) wastewater treatment plant (WWTP) and (2) terminal ponds located at the Rocky Flats Plant. Literature reviews indicate that Photobacterium phosphoreum (Microtox assay) may be used as screening test for the reaction of Ceriodaphnia dubia and Pimephales promelas to toxins present in effluents. This study indicates that the Microtox is less sensitive to toxins present in the WWTP effluent than other test organisms (Ceriodaphnia dubia and Pimephales promelas). Toxicity appears to be from unionized ammonia. Ten months of data reveal that the surface water effluents which leave Rocky Flats boundaries are non-toxic when judged by all three test organisms.

  7. Analysis of the toxicity in Rocky Flats Plant surface water through a correlation between the whole effluent toxicity test and the Microtox assay

    SciTech Connect (OSTI)

    Ford, S.M.; Wolaver, H.A. ); Figueroa, L.A. )

    1992-01-01

    Results were correlated from the Microtox assay and the whole effluent acute toxicity test for effluents from the (1) wastewater treatment plant (WWTP) and (2) terminal ponds located at the Rocky Flats Plant. Literature reviews indicate that Photobacterium phosphoreum (Microtox assay) may be used as screening test for the reaction of Ceriodaphnia dubia and Pimephales promelas to toxins present in effluents. This study indicates that the Microtox is less sensitive to toxins present in the WWTP effluent than other test organisms (Ceriodaphnia dubia and Pimephales promelas). Toxicity appears to be from unionized ammonia. Ten months of data reveal that the surface water effluents which leave Rocky Flats boundaries are non-toxic when judged by all three test organisms.

  8. Transport diffusion of liquid water and methanol through membranes...

    Office of Scientific and Technical Information (OSTI)

    DIFFUSION; MEMBRANES; METHANOL; TRANSPORT; WATER; GOLD; SURFACES; COMPUTER CALCULATIONS DIFFUSION; WATER; METHANOL; GOLD; MEMBRANES; SURFACES; COMPUTER CALCULATIONS Word Cloud ...

  9. Insights into the effect of dilute acid, hot water and alkaline pretreatment on cellulose accessible surface area and overall porosity of Populus

    SciTech Connect (OSTI)

    Meng, Xianzhi; Wells, Tyrone; Sun, Qining; Huang, Fang; Ragauskas, Arthur J.

    2015-06-19

    Pretreatment is known to render biomass more reactive to cellulase by altering the chemical compositions as well as physical structures of biomass. Simons stain technique along with mercury porosimetry were applied on the acid, neutral, and alkaline pretreated materials to measure the accessible surface area of cellulose and pore size distribution of Populus. Results indicated that acid pretreatment is much more effective than water and alkaline pretreatment in terms of cellulose accessibility increase. Further investigation suggests that lignin does not dictate cellulose accessibility to the extent that hemicellulose does, but it does restrict xylan accessibility which in turn controls the access of cellulase to cellulose. The most interesting finding is that severe acid pretreatment significantly decreases the average pore size, i.e., 90% average size decrease could be observed after 60 min dilute acid pretreatment at 160 oC; however, the nano-pore space formed between coated microfibrils is increased after pretreatment, especially for the acid pretreatment, suggesting this particular type of biomass porosity is probably the most fundamental barrier to effective enzymatic hydrolysis.

  10. Insights into the effect of dilute acid, hot water and alkaline pretreatment on cellulose accessible surface area and overall porosity of Populus

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meng, Xianzhi; Wells, Tyrone; Sun, Qining; Huang, Fang; Ragauskas, Arthur J.

    2015-06-19

    Pretreatment is known to render biomass more reactive to cellulase by altering the chemical compositions as well as physical structures of biomass. Simons stain technique along with mercury porosimetry were applied on the acid, neutral, and alkaline pretreated materials to measure the accessible surface area of cellulose and pore size distribution of Populus. Results indicated that acid pretreatment is much more effective than water and alkaline pretreatment in terms of cellulose accessibility increase. Further investigation suggests that lignin does not dictate cellulose accessibility to the extent that hemicellulose does, but it does restrict xylan accessibility which in turn controls themore » access of cellulase to cellulose. The most interesting finding is that severe acid pretreatment significantly decreases the average pore size, i.e., 90% average size decrease could be observed after 60 min dilute acid pretreatment at 160 °C; moreover, the nano-pore space formed between coated microfibrils is increased after pretreatment, especially for the acid pretreatment, suggesting this particular type of biomass porosity is probably the most fundamental barrier to effective enzymatic hydrolysis.« less

  11. Characterization of Free Surface-Bound and Entrapped Water Environments in Poly(N-Isopropyl Acrylamide) Hydrogels via 1H HRMAS PFG NMR Spectroscopy

    SciTech Connect (OSTI)

    Alam, Todd Michael; Childress, Kimberly Kay; Pastoor, Kevin; Rice, Charles

    2014-09-19

    We found that different water environments in poly(N-isopropyl acrylamide) (PNIPAAm) hydrogels are identified and characterized using 1H high resolution magic angle spinning (HRMAS) nuclear magnetic resonance (NMR). Local water environments corresponding to a “free” highly mobile species, along with waters showing restricted dynamics are resolved in these swollen hydro-gels. For photo-initiated polymerized PNIPAAm gels, an additional entrapped water species is observed. Spin–spin R2 relaxation experiments support the argument of reduced mobility in the restricted and entrapped water species. Furthermore, by combining pulse field gradient techniques with HRMAS NMR it is possible to directly measure the self-diffusion rate for these different water environments. The behavior of the heterogeneous water environments through the lower critical solution temperature transition is described.

  12. Characterization of Free Surface-Bound and Entrapped Water Environments in Poly(N-Isopropyl Acrylamide) Hydrogels via 1H HRMAS PFG NMR Spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Alam, Todd Michael; Childress, Kimberly Kay; Pastoor, Kevin; Rice, Charles

    2014-09-19

    We found that different water environments in poly(N-isopropyl acrylamide) (PNIPAAm) hydrogels are identified and characterized using 1H high resolution magic angle spinning (HRMAS) nuclear magnetic resonance (NMR). Local water environments corresponding to a “free” highly mobile species, along with waters showing restricted dynamics are resolved in these swollen hydro-gels. For photo-initiated polymerized PNIPAAm gels, an additional entrapped water species is observed. Spin–spin R2 relaxation experiments support the argument of reduced mobility in the restricted and entrapped water species. Furthermore, by combining pulse field gradient techniques with HRMAS NMR it is possible to directly measure the self-diffusion rate for these differentmore » water environments. The behavior of the heterogeneous water environments through the lower critical solution temperature transition is described.« less

  13. The nonlinear Schrödinger equation and the propagation of weakly nonlinear waves in optical fibers and on the water surface

    SciTech Connect (OSTI)

    Chabchoub, A.; Kibler, B.; Finot, C.; Millot, G.; Onorato, M.; Dudley, J.M.; Babanin, A.V.

    2015-10-15

    The dynamics of waves in weakly nonlinear dispersive media can be described by the nonlinear Schrödinger equation (NLSE). An important feature of the equation is that it can be derived in a number of different physical contexts; therefore, analogies between different fields, such as for example fiber optics, water waves, plasma waves and Bose–Einstein condensates, can be established. Here, we investigate the similarities between wave propagation in optical Kerr media and water waves. In particular, we discuss the modulation instability (MI) in both media. In analogy to the water wave problem, we derive for Kerr-media the Benjamin–Feir index, i.e. a nondimensional parameter related to the probability of formation of rogue waves in incoherent wave trains.

  14. Field Summary Report for Remedial Investigation of Hanford Site Releases to the Columbia River, Hanford Site, Washington, Collection of Surface Water, River Sediments, and Island Soils

    SciTech Connect (OSTI)

    L. C. Hulstrom

    2009-09-28

    This report has been prepared in support of the remedial investigation of Hanford Site Releases to the Columbia River and describes the 2008/2009 data collection efforts. This report documents field activities associated with collection of sediment, river water, and soil in and adjacent to the Columbia River near the Hanford Site and in nearby tributaries.

  15. Cooling water distribution system

    DOE Patents [OSTI]

    Orr, Richard

    1994-01-01

    A passive containment cooling system for a nuclear reactor containment vessel. Disclosed is a cooling water distribution system for introducing cooling water by gravity uniformly over the outer surface of a steel containment vessel using an interconnected series of radial guide elements, a plurality of circumferential collector elements and collector boxes to collect and feed the cooling water into distribution channels extending along the curved surface of the steel containment vessel. The cooling water is uniformly distributed over the curved surface by a plurality of weirs in the distribution channels.

  16. Pulse studies to decipher the role of surface morphology in CuO/CeO₂ nanocatalysts for the water gas shift reaction

    SciTech Connect (OSTI)

    Rodriguez, Jose A.; Zhao, Fuzhen; Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Si, Rui; Johnston-Peck, Aaron C.; Martinez-Arias, Arturo; Hanson, Jonathan C.; Senanayake, Sanjaya D.

    2015-01-23

    The water-gas shift reaction (WGS, CO + H₂O → CO₂) was studied over CuO/CeO₂ catalysts with two different ceria particle morphohologies, in the form of nanospheres (ns) and nanocubes (nc). To understand the strong dependence of the WGS reaction activity on the ceria nanoshapes, pulses of CO (without and with water vapor) were employed during in situ X-ray diffraction (XRD) and X-ray absoprtion near edge structure (XANES) measurements done to characterize the catalysts. The results showed that CuO/CeO₂ (ns) exhibited a substantially better activity than CuO/CeO₂ (nc). The higher activity was associated with the unique properties of CuO/CeO₂ (ns), such as the easier reduction of highly dispersed CuO to metallic Cu, the stability of metallic Cu and a larger concentration Ce³⁺ in CeO₂ (ns).

  17. Pulse studies to decipher the role of surface morphology in CuO/CeO₂ nanocatalysts for the water gas shift reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A.; Zhao, Fuzhen; Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Si, Rui; Johnston-Peck, Aaron C.; Martinez-Arias, Arturo; Hanson, Jonathan C.; Senanayake, Sanjaya D.

    2015-01-23

    The water-gas shift reaction (WGS, CO + H₂O → CO₂) was studied over CuO/CeO₂ catalysts with two different ceria particle morphohologies, in the form of nanospheres (ns) and nanocubes (nc). To understand the strong dependence of the WGS reaction activity on the ceria nanoshapes, pulses of CO (without and with water vapor) were employed during in situ X-ray diffraction (XRD) and X-ray absoprtion near edge structure (XANES) measurements done to characterize the catalysts. The results showed that CuO/CeO₂ (ns) exhibited a substantially better activity than CuO/CeO₂ (nc). The higher activity was associated with the unique properties of CuO/CeO₂ (ns), suchmore » as the easier reduction of highly dispersed CuO to metallic Cu, the stability of metallic Cu and a larger concentration Ce³⁺ in CeO₂ (ns).« less

  18. Innovative Use of Cr(VI) Plume Depictions and Pump-and-Treat Capture Analysis to Estimate Risks of Contaminant Discharge to Surface Water at Hanford Reactor Areas

    SciTech Connect (OSTI)

    Miller, Chuck W.; Hanson, James P.; Ivarson, Kristine A.; Tonkin, M.

    2015-01-14

    The Hanford Site nuclear reactor operations required large quantities of high-quality cooling water, which was treated with chemicals including sodium dichromate dihydrate for corrosion control. Cooling water leakage, as well as intentional discharge of cooling water to ground during upset conditions, produced extensive groundwater recharge mounds consisting largely of contaminated cooling water and resulted in wide distribution of hexavalent chromium (Cr[VI]) contamination in the unconfined aquifer. The 2013 Cr(VI) groundwater plumes in the 100 Areas cover approximately 6 km2 (1500 acres), primarily in the 100-HR-3 and 100-KR-4 groundwater operable units (OUs). The Columbia River is a groundwater discharge boundary; where the plumes are adjacent to the Columbia River there remains a potential to discharge Cr(VI) to the river at concentrations above water quality criteria. The pump-and-treat systems along the River Corridor are operating with two main goals: 1) protection of the Columbia River, and 2) recovery of contaminant mass. An evaluation of the effectiveness of the pump-and-treat systems was needed to determine if the Columbia River was protected from contamination, and also to determine where additional system modifications may be needed. In response to this need, a technique for assessing the river protection was developed which takes into consideration seasonal migration of the plume and hydraulic performance of the operating well fields. Groundwater contaminant plume maps are generated across the Hanford Site on an annual basis. The assessment technique overlays the annual plume and the capture efficiency maps for the various pump and treat systems. The river protection analysis technique was prepared for use at the Hanford site and is described in detail in M.J. Tonkin, 2013. Interpolated capture frequency maps, based on mapping dynamic water level observed in observation wells and derived water levels in the vicinity of extraction and injection wells, are developed initially. Second, simulated capture frequency maps are developed, based on transport modelling results. Both interpolated and simulated capture frequency maps are based on operation of the systems over a full year. These two capture maps are then overlaid on the plume distribution maps for inspection of the relative orientation of the contaminant plumes with the capture frequency. To quantify the relative degree of protection of the river from discharges of Cr(VI) (and conversely, the degree of threat) at any particular location, a systematic method of evaluating and mapping the plume/capture relationship was developed. By comparing the spatial relationship between contaminant plumes and hydraulic capture frequency, an index of relative protectiveness is developed and the results posted on the combined plume/capture plan view map. Areas exhibiting lesser degrees of river protection are identified for remedial process optimization actions to control plumes and prevent continuing discharge of Cr(VI) to the river.

  19. Literature and data review for the surface-water pathway: Columbia River and adjacent coastal areas. Hanford Environmental Dose Reconstruction Project

    SciTech Connect (OSTI)

    Walters, W.H.; Dirkes, R.L.; Napier, B.A.

    1992-04-01

    As part of the Hanford Environmental Dose Reconstruction Project, Pacific Northwest Laboratory reviewed literature and data on radionuclide concentrations and distribution in the water, sediment, and biota of the Columbia River and adjacent coastal areas. Over 600 documents were reviewed including Hanford reports, reports by offsite agencies, journal articles, and graduate theses. Certain radionuclide concentration data were used in preliminary estimates of individual dose for the 1964--1966 time period. This report summarizes the literature and database review and the results of the preliminary dose estimates.

  20. Water-Stable Zirconium-Based Metal-Organic Framework Material with High-Surface Area and Gas-Storage Capacities

    SciTech Connect (OSTI)

    Gutov, OV; Bury, W; Gomez-Gualdron, DA; Krungleviciute, V; Fairen-Jimenez, D; Mondloch, JE; Sarjeant, AA; Al-Juaid, SS; Snurr, RQ; Hupp, JT; Yildirim, T; Farha, OK

    2014-08-14

    We designed, synthesized, and characterized a new Zr-based metal-organic framework material, NU-1100, with a pore volume of 1.53 ccg(-1) and Brunauer-Emmett-Teller (BET) surface area of 4020 m(2)g(-1); to our knowledge, currently the highest published for Zr-based MOFs. CH4/CO2/H-2 adsorption isotherms were obtained over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65 bar and 77 K is 0.092 gg(-1), which corresponds to 43 gL(-1). The volumetric and gravimetric methane-storage capacities at 65 bar and 298 K are approximately 180 v(STP)/v and 0.27 gg(-1), respectively.

  1. Carderock Circulating Water Channel | Open Energy Information

    Open Energy Info (EERE)

    Features The Circulating Water Channel is a vertical plane, open to the atmosphere test section with a free surface in a closed recirculating water circuit, variable speed,...

  2. Vadose zone water fluxmeter

    DOE Patents [OSTI]

    Faybishenko, Boris A.

    2005-10-25

    A Vadose Zone Water Fluxmeter (WFM) or Direct Measurement WFM provides direct measurement of unsaturated water flow in the vadose zone. The fluxmeter is a cylindrical device that fits in a borehole or can be installed near the surface, or in pits, or in pile structures. The fluxmeter is primarily a combination of tensiometers and a porous element or plate in a water cell that is used for water injection or extraction under field conditions. The same water pressure measured outside and inside of the soil sheltered by the lower cylinder of the fluxmeter indicates that the water flux through the lower cylinder is similar to the water flux in the surrounding soil. The fluxmeter provides direct measurement of the water flow rate in the unsaturated soils and then determines the water flux, i.e. the water flow rate per unit area.

  3. Use of Electrical Imaging and Distributed Temperature Sensing Methods to Characterize Surface Water-Groundwater Exchange Regulating Uranium Transport at the Hanford 300 Area, Washington

    SciTech Connect (OSTI)

    Slater, Lee; Ntarlagiannis, Dimitrios; Day-Lewis, Frederick D.; Mwakanyamale, Kisa; Versteeg, Roelof J.; Ward, Anderson L.; Strickland, Christopher E.; Johnson, Carole D.; Lane, John W.

    2010-10-31

    A critical challenge in advancing prediction of solute transport between contaminated aquifers and rivers is improving understanding of how fluctuations in river stage, combined with subsurface heterogeneity, impart spatiotemporal complexity to solute exchange along river corridors. Here, we explored the use of waterborne geoelectrical imaging, in conjunction with fiber-optic distributed temperature sensor (DTS) monitoring, to improve the conceptual model for uranium transport within the hyporheic corridor at the Hanford 300 Area. We first inverted waterborne geoelectrical (resistivity and induced polarization) datasets for distributions of electrical resistivity and polarizability, from which the spatial complexity of the primary hydrogeologic units was reconstructed. Variations in the depth to the interface between the overlying coarse-grained, high permeability Hanford formation and the underlying finer-grained, less permeable Ringold formation, an important contact that limits vertical migration of contaminants, were resolved along ~3 km of the river corridor centered on the 300 Area. Polarizability images were translated into lithologic images using established relationships between polarizability and surface area normalized to pore volume (Spor). The spatial variability captured in the geoelectrical datasets indicates that previous studies based on borehole projections and point probing overestimate the contributing area for uranium exchange within the Columbia River at the Hanford 300 Area. The DTS data recorded on 1. 5 km of cable with a 1 m spatial resolution and 5 minute sampling interval revealed sub-reaches showing (1) high temperature anomalies and, (2) a strong negative correlation between temperature and river stage, both indicative of groundwater influxes during winter months. The DTS datasets confirm the hydrologic significance of the variability identified in the geoelectrical imaging and reveal a pattern of highly focused hyporheic exchange, with exchange concentrated at springs where the Hanford formation is thick, and coinciding with a paleochannel identified in ground penetrating radar surveys at one location. No evidence for focused hyporheic exchange is observed in the DTS data where the Ringold unit is in contact with the riverbed. Our findings illustrate how the combination of waterborne geoelectrical imaging and DTS technologies can characterize hyporheic exchange in a complex, coupled river-aquifer system.

  4. Field-deployable, nano-sensing approach for real-time detection of free mercury, speciation and quantification in surface stream waters and groundwater samples at the U.S. Department of Energy contaminated sites

    SciTech Connect (OSTI)

    Campiglia, Andres D.; Hernandez, Florencio E.

    2014-08-28

    The detrimental effects on human health caused by long-term exposure to trace contamination of toxic metals have been documented in numerous epidemiological and toxicological studies. The fact that metals are non-biodegradable and accumulate in the food chain poses a severe threat to the environment and human health. Their monitoring in drinking water, aquatic ecosystems, food and biological fluids samples is then essential for global sustainability. While research efforts employing established methodology continue to advance conceptual/computational models of contaminant behavior, the increasing awareness and public concern with environmental and occupational exposure to toxic metals calls for sensing devices capable to handle on-site elemental analysis in short analysis time. Field analysis with potable methodology prevents unnecessary scrutiny of un-contaminated samples via laboratory-bound methods, reduces analysis cost and expedites turnaround time for decision making and remediation purposes. Of particular toxicological interest are mercury and its species. Mercury is recognized as a major environmental pollution issue. The field-portable sensor developed in this project provides a unique and valuable tool for the on-site, real-time determination of inorganic mercury in surface waters. The ability to perform on-site analysis of mercury should prove useful in remote locations with difficult accessibility. It should facilitate data collection from statistically meaningful population sizes for a better understanding of the dose-effect role and the water-soil-plant-animal-human transfer mechanisms. The acquired knowledge should benefit the development of efficient environmental remediation processes, which is extremely relevant for a globally sustainable environment.

  5. EA-1406-FEA-2003.pdf

    Office of Environmental Management (EM)

    Mill Tailings Remedial Action (Project) UMTRCA Uranium Mill Tailings Radiation Control Act EA of Ground Water Compliance at the New Rifle Site DOE Grand Junction Office Page viii...

  6. Vibrational spectroscopy of water interfaces

    SciTech Connect (OSTI)

    Du, Q.

    1994-12-01

    The second order nonlinear optical processes of second harmonic generation and sum frequency generation are powerful and versatile tools for studying all kinds of surfaces. They possess unusual surface sensitivity due to the symmetry properties of the second order nonlinear susceptibility. The technique of infrared-visible sum frequency generation (SFG) is particularly attractive because it offers a viable way to do vibrational spectroscopy on any surfaces accessible to light with submonolayer sensitivity. In this thesis, the author applies SFG to study a number of important water interfaces. At the air/water interface, hydrophobic solid/water and liquid/water interfaces, it was found that approximately 25% of surface water molecules have one of their hydrogen pointing away from the liquid water. The large number of unsatisfied hydrogen bonds contributes significantly to the large interfacial energy of the hydrophobic surfaces. At the hydrophilic fused quartz/water interface and a fatty acid monolayer covered water surface, the structure and orientation of surface water molecules are controlled by the hydrogen bonding of water molecules with the surface OH groups and the electrostatic interaction with the surface field from the ionization of surface groups. A change of pH value in the bulk water can significantly change the relative importance of the two interactions and cause a drastic change in orientation of the surface water molecules. SFG has also been applied to study the tribological response of some model lubricant films. Monolayers of Langmuir-Blodgett films were found to disorder orientationaly under mildly high pressure and recover promptly upon removal of the applied pressure.

  7. Clean Water Act and Regulations (EPA)

    Broader source: Energy.gov [DOE]

    The Clean Water Act (CWA; 33 U.S.C. §1251 et seq.) establishes the basic structure for regulating discharges of pollutants into the waters of the United States and regulating quality standards for surface waters.

  8. Enhanced Pool-Boiling Heat Transfer Using Nanostructured Surfaces...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    creates optimal surface wettability characteristics that allow better capillary flow of water on the liquid boiling surfaces often used to cool electronics. the dense...

  9. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Groundwater, Surface Water, and Alternate Water Supply System Sampling at the Riverton, Wyoming, Processing Site December 2013 LMS/RVT/S00913 This page intentionally left blank U.S. Department of Energy DVP-September 2013, Riverton, Wyoming December 2013 RIN 13095603 Page i Contents Sampling Event Summary ...............................................................................................................1 Riverton, Wyoming, Sample Location Map

  10. EA-1406-FONSI-2003

    Office of Environmental Management (EM)

    Finding of No Significant Impact for Ground Water Compliance at the New Rifle, Colorado, UMTRA Project Site AGENCY: U.S. DEPARTMENT OF ENERGY ACTION: FINDING OF NO SIGNIFICANT IMPACT (FONSI) SUMMARY: The U.S. Department of Energy (DOE) plans to implement a ground water cleanup compliance strategy for the New Rifle Uranium Mill Tailings Radiation Control Act (UMTRCA) former processing site. The proposed compliance strategy at the New Rifle site is passive remediation by natural flushing with

  11. Tritium on Metal Surfaces | Department of Energy

    Office of Environmental Management (EM)

    on Metal Surfaces Tritium on Metal Surfaces Presentation from the 34th Tritium Focus Group Meeting held in Idaho Falls, Idaho on September 23-25, 2014. PDF icon Tritium on Metal Surfaces More Documents & Publications Modeling Tritium on Metal Surfaces Tritium Plasma Experiment and Its Role in PHENIX Program Light Water Detritiation using the CECE Process

  12. Snapshots of Proton Accommodation at a Microscopic Water Surface: Understanding the Vibrational Spectral Signatures of the Charge Defect in Cryogenically Cooled H+(H2O)n=2 28 Clusters

    SciTech Connect (OSTI)

    Fournier, Joseph A.; Wolke, Conrad T.; Johnson, Mark A.; Odbadrakh, Tuguldur T.; Jordan, Kenneth D.; Kathmann, Shawn M.; Xantheas, Sotiris S.

    2015-07-09

    In this Article, we review the role of gas-phase, size-selected protonated water clusters, H+(H2O)n, in the analysis of the microscopic mechanics responsible for the behavior of the excess proton in bulk water. We extend upon previous studies of the smaller, two-dimensional sheet-like structures to larger (n?10) assemblies with three-dimensional cage morphologies which better mimic the bulk environment. Indeed, clusters in which a complete second solvation shell forms around a surface-embedded hydronium ion yield vibrational spectra where the signatures of the proton defect display strikingly similar positions and breadth to those observed in dilute acids. We investigate effects of the local structure and intermolecular interactions on the large red shifts observed in the proton vibrational signature upon cluster growth using various theoretical methods. We show that, in addition to sizeable anharmonic couplings, the position of the excess proton vibration can be traced to large increases in the electric field exerted on the embedded hydronium ion upon formation of the first and second solvation shells. MAJ acknowledges support from the U.S. Department of Energy under Grant No. DE-FG02- 06ER15800 as well as the facilities and staff of the Yale University Faculty of Arts and Sciences High Performance Computing Center, and by the National Science Foundation under Grant No. CNS 08-21132 that partially funded acquisition of the facilities. SMK and SSX acknowledge support from the US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle. This research used resources of the National Energy Research Scientific Computing Center, which is supported by the Office of Science of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231.

  13. Heavy-metal contamination on training ranges at the Grafenwoehr Training Area, Germany

    SciTech Connect (OSTI)

    Zellmer, S.D.; Schneider, J.F.

    1993-05-01

    Large quantities of lead and other heavy metals are deposited in the environment of weapons ranges during training exercises. This study was conducted to determine the type, degree, and extent of heavy-metal contamination on selected handgun, rifle, and hand-grenade ranges at Grafenwoehr Training Area, Germany. Soil, vegetation, and surface-water samples were collected and analyzed using the inductively-coupled plasma atomic-emission spectroscopy (ICP-AES) method and the toxic characterization leaching procedure (TCLP). The ICP-AES results show that above-normal levels of lead and copper are in the surface soil at the handgun range, high concentrations of lead and copper are in the berm and soil surface at the rifle range, and elevated levels of cadmium and above-normal concentrations of arsenic, copper, and zinc are present in the surface soil at the hand-grenade range. The TCLP results show that surface soils can be considered hazardous waste because of lead content at the rifle range and because of cadmium concentration at the hand-grenade range. Vegetation at the handgun and rifle ranges has above-normal concentrations of lead. At the hand-grenade range, both vegetation and surface water have high levels of cadmium. A hand-held X-ray fluorescence (XRF) spectrum analyzer was used to measure lead concentrations in soils in a field test of the method. Comparison of XRF readings with ICP-AES results for lead indicate that the accuracy and precision of the hand-held XRF unit must improve before the unit can be used as more than a screening tool. Results of this study show that heavy-metal contamination at all three ranges is limited to the surface soil; heavy metals are not being leached into the soil profile or transported into adjacent areas.

  14. Best Management Practices for Surface Water Protection

    Broader source: Energy.gov [DOE]

    Presenter: Mick Wiest, B&W Y-12 Technical Services, L.L.C., Y-12 National Security Complex Track 7-8

  15. AGENDA ADEP Surface Water Protection Project NPDES Storm Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Permit Bi-Annual Update Public Meeting January 22, 2014 5:30-7:30 p.m. Cities of Gold Conference Center Pojoaque, New Mexico 5:30 p.m. Poster Session 5:50 p.m. Welcome Steve...

  16. S. 943: A Bill to amend the Surface Mining Control and Reclamation Act of 1977 to facilitate the use of abandoned mine reclamation fund moneys to replace water supplies that have been contaminated or diminished by coal mining practices. Introduced in the Senate of the United States, One Hundred First Congress, First Session, May 9, 1989

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    The bill describes mandatory and discretionary allocations of funds to a state or Indian reservation for the purpose of water reclamation. The stated objectives of the Surface Mining Control and Reclamation Act are amended to allow 50 percent of a state's mandatory allocation to be used for the construction of public water treatment plants and distribution facilities to take the place of water supplies that have been contaminated as a result of coal practices undertaken prior to August 3, 1977, regardless of whether the contamination has been exacerbated by coal mining practices since that date, when construction would be more economical than repair of existing facilities.

  17. Superhydrophobic surfaces

    DOE Patents [OSTI]

    Wang, Evelyn N; McCarthy, Matthew; Enright, Ryan; Culver, James N; Gerasopoulos, Konstantinos; Ghodssi, Reza

    2015-03-24

    Surfaces having a hierarchical structure--having features of both microscale and nanoscale dimensions--can exhibit superhydrophobic properties and advantageous condensation and heat transfer properties. The hierarchical surfaces can be fabricated using biological nanostructures, such as viruses as a self-assembled nanoscale template.

  18. Recent California water transfers: Emerging options in water management. Final report

    SciTech Connect (OSTI)

    Lund, J.R.; Israel, M.

    1992-12-01

    Report examines the recent use of water transfers in California. Emphasis is on the use of water transfers during the current drought and how planners and operators of federal, state, and local systems can integrate water transfers into the planning and operations of their systems. Through the California experience, the study identifies motivations for incorporating water transfers into water supply systems, reviews a variety of water transfer types, and discusses the integration of water transfers with traditional supply argumentation and water conservation measures. Limitations, constraints, and difficulties for employing water transfers within existing systems are also discussed. The study focuses primarily on the technical, planning, and operational aspects of water transfers, rather than the legal, economic, and social implications. Water transfers, Water management, Water bank, Water supply, Water use, Water institutions, Infrastructure, California state water project, Water rights, Drought, Surface water, Groundwater.

  19. Surface Soil

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Soil Surface Soil We compare local soil samples with samples collected from northern New Mexico locations that are beyond the range of potential influence from normal Laboratory operations. April 12, 2012 Farm soil sampling Two LANL environmental field team members take soil samples from a farm. Contact Environmental Communication & Public Involvement P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email Measurements are compared to samples from the regional sites and

  20. Surface and groundwater management in surface mined-land reclamation

    SciTech Connect (OSTI)

    Evoy, B.; Holland, M.

    1990-06-01

    This report provides information on surface water and groundwater management for use in the mined-land reclamation planning process in California. Mined-land reclamation, as defined by the California Surface Mining and Reclamation Act, is the combination of land treatments which prevent or minimize water degradation, air pollution, damage to aquatic or wildlife habitat, and erosion resulting from a surface mining operation. Surface water and groundwater management play an integral role in nearly every reclamation plan. Groundwater and surface water runoff (both onto and off of the site) must often be evaluated (1) to design flooding and erosion protection measures such as drainage channels, levees, culverts, or riprap; (2) to prepare and carry out a successful revegetation program; (3) to design stable final slopes; (4) to maximize potential available water for the operation and reclamation stages; (5) to prevent the discharge of contaminants from mine processes or from mined areas; and (6) to limit long-term leachate formation and movement from tailings, pit, or waste rock disposal areas. This report is a guide for mine operators, local government, planners, and plan reviewers.

  1. Synchrotrons Explore Water's Molecular Mysteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synchrotrons Explore Water's Molecular Mysteries Synchrotrons Explore Water's Molecular Mysteries Print Friday, 01 February 2013 00:00 In experiments at SLAC National Accelerator Laboratory and Lawrence Berkeley National Laboratory's Advanced Light Source, scientists observed a surprisingly dense form of water that remained liquid well beyond its typical freezing point. Researchers applied a superthin coating of water-no deeper than a few molecules-to the surface of a barium fluoride crystal.

  2. Estimated Water Flows in 2005: United States

    SciTech Connect (OSTI)

    Smith, C A; Belles, R D; Simon, A J

    2011-03-16

    Flow charts depicting water use in the United States have been constructed from publicly available data and estimates of water use patterns. Approximately 410,500 million gallons per day of water are managed throughout the United States for use in farming, power production, residential, commercial, and industrial applications. Water is obtained from four major resource classes: fresh surface-water, saline (ocean) surface-water, fresh groundwater and saline (brackish) groundwater. Water that is not consumed or evaporated during its use is returned to surface bodies of water. The flow patterns are represented in a compact 'visual atlas' of 52 state-level (all 50 states in addition to Puerto Rico and the Virgin Islands) and one national water flow chart representing a comprehensive systems view of national water resources, use, and disposition.

  3. Nationwide water availability data for energy-water modeling.

    SciTech Connect (OSTI)

    Tidwell, Vincent Carroll; Zemlick, Katie M.; Klise, Geoffrey Taylor

    2013-11-01

    The purpose of this effort is to explore where the availability of water could be a limiting factor in the siting of new electric power generation. To support this analysis, water availability is mapped at the county level for the conterminous United States (3109 counties). Five water sources are individually considered, including unappropriated surface water, unappropriated groundwater, appropriated water (western U.S. only), municipal wastewater and brackish groundwater. Also mapped is projected growth in non-thermoelectric consumptive water demand to 2035. Finally, the water availability metrics are accompanied by estimated costs associated with utilizing that particular supply of water. Ultimately these data sets are being developed for use in the National Renewable Energy Laboratories' (NREL) Regional Energy Deployment System (ReEDS) model, designed to investigate the likely deployment of new energy installations in the U.S., subject to a number of constraints, particularly water.

  4. Water resources data for Louisiana, water year 1996. Water-data report (Annual), 1 October 1995-30 September 1996

    SciTech Connect (OSTI)

    Garrison, C.R.; Lovelace, W.M.; Montgomery, P.A.

    1997-05-01

    The report contains records for water discharge at 64 gaging stations; stage only for 41 gaging stations and 5 lakes; water quality for 38 surface-water stations (including 22 gage stations) and 100 wells; and water levels for 235 observation wells. Also included are data for 117 crest-stage and flood-profile partial-record stations.

  5. Pump station for radioactive waste water

    DOE Patents [OSTI]

    Whitton, John P.; Klos, Dean M.; Carrara, Danny T.; Minno, John J.

    2003-11-18

    A pump station for transferring radioactive particle containing waste water, includes: (a.) an enclosed sump having a vertically elongated right frusto conical wall surface and a bottom surface and (b.) a submersible volute centrifugal pump having a horizontally rotating impeller and a volute exterior surface. The sump interior surface, the bottom surface and the volute exterior surface are made of stainless steel having a 30 Ra or finer surface finish. A 15 Ra finish has been found to be most cost effective. The pump station is used for transferring waste water, without accumulation of radioactive fines.

  6. Remediation of Uranium-Contaminated Ground Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    costs, are highly energy efficient, and require no surface facilities or ground water pumpingrecharge (Freethey et al., 2002; Morrison and Spangler, 1992; Shoemaker et al., 1995). ...

  7. September 2004 Water Sampling

    Office of Legacy Management (LM)

    February 2015 Groundwater and Surface Water Sampling at the Grand Junction, Colorado, Site April 2015 LMS/GJO/S00215 This page intentionally left blank U.S. Department of Energy DVP-February 2015, Grand Junction, Colorado, Site April 2015 RIN 15026795 Page i Contents Sampling Event Summary ...............................................................................................................1 Grand Junction, Colorado, Site Sample Location Map

  8. September 2004 Water Sampling

    Office of Legacy Management (LM)

    4 Groundwater and Surface Water Sampling at the Gunnison, Colorado, Processing Site September 2014 LMS/GUP/S00414 This page intentionally left blank U.S. Department of Energy DVP-April and June 2014, Gunnison, Colorado September 2014 RIN 14046058 and 14066262 Page i Contents Sampling Event Summary ...............................................................................................................1 Gunnison, Colorado, Processing Site Planned Sampling Map

  9. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Naturita, Colorado Processing Site October 2013 LMS/NAP/S00713 This page intentionally left blank U.S. Department of Energy DVP-July 2013, Naturita, Colorado October 2013 RIN 13075483 Page i Contents Sampling Event Summary ...............................................................................................................1 Naturita, Colorado, Sample Location Map ......................................................................................3

  10. September 2004 Water Sampling

    Office of Legacy Management (LM)

    4 Groundwater and Surface Water Sampling at the Slick Rock, Colorado, Processing Sites December 2014 LMS/SRW/SRE/S00914 This page intentionally left blank U.S. Department of Energy DVP-September 2014, Slick Rock, Colorado December 2014 RIN 14096456 Page i Contents Sampling Event Summary ...............................................................................................................1 Slick Rock, Colorado, Processing Sites, Sample Location Map

  11. September 2004 Water Sampling

    Office of Legacy Management (LM)

    5 Groundwater and Surface Water Sampling at the Slick Rock, Colorado, Processing Sites January 2016 LMS/SRE/SRW/S00915 This page intentionally left blank U.S. Department of Energy DVP-September 2015, Slick Rock, Colorado January 2016 RINs 15087319 and 15107424 Page i Contents Sampling Event Summary ...............................................................................................................1 Slick Rock, Colorado, Processing Sites, Sample Location Map

  12. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Groundwater and Surface Water Sampling at the Slick Rock East and West, Colorado, Processing Sites November 2013 LMS/SRE/SRW/S0913 This page intentionally left blank U.S. Department of Energy DVP-September 2013, Slick Rock, Colorado November 2013 RIN 13095593 Page i Contents Sampling Event Summary ...............................................................................................................1 Slick Rock East and West, Colorado, Processing Sites, Sample Location Map

  13. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Green River, Utah, Disposal Site August 2014 LMS/GRN/S00614 This page intentionally left blank U.S. Department of Energy DVP-June 2014, Green River, Utah August 2014 RIN 14066228 Page i Contents Sampling Event Summary ...............................................................................................................1 Green River, Utah, Disposal Site Sample Location Map ................................................................5 Data Assessment

  14. September 2004 Water Sampling

    Office of Legacy Management (LM)

    3 Groundwater and Surface Water Sampling at the Monument Valley, Arizona, Processing Site March 2014 LMS/MON/S01213 This page intentionally left blank U.S. Department of Energy DVP-December 2013, Monument Valley, Arizona March 2014 RIN 13125794 Page i Contents Sampling Event Summary ...............................................................................................................1 Monument Valley, Arizona, Processing Site, Sample Location Map

  15. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Monument Valley, Arizona, Processing Site February 2015 LMS/MON/S01214 This page intentionally left blank U.S. Department of Energy DVP-December 2014, Monument Valley, Arizona February 2015 RIN 14126645 Page i Contents Sampling Event Summary ...............................................................................................................1 Monument Valley, Arizona, Disposal Site Sample Location Map ..................................................5

  16. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Monticello, Utah, Processing Site July 2014 LMS/MNT/S00414 This page intentionally left blank U.S. Department of Energy DVP-April 2014, Monticello, Utah July 2014 RIN 14046077 Page i Contents Sampling Event Summary ...............................................................................................................1 Planned Sampling Map, April 2014, Monticello, Utah, Processing Site .........................................5 Data Assessment Summary

  17. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Monticello, Utah, Processing Site July 2015 LMS/MNT/S00415 This page intentionally left blank U.S. Department of Energy DVP-April 2015, Monticello, Utah July 2015 RIN 15046927 Page i Contents Sampling Event Summary ...............................................................................................................1 Monticello, Utah, Processing Site Sample Location Map ...............................................................5 Data Assessment

  18. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and May 2014 Groundwater and Surface Water Sampling at the Shiprock, New Mexico, Disposal Site June 2014 LMS/SHP/S00314 This page intentionally left blank U.S. Department of Energy DVP-March and May 2014, Shiprock, New Mexico June 2014 RIN 14036011, 14036013, and 14056142 Page i Contents Sampling Event Summary ...............................................................................................................1 Shiprock, New Mexico, Disposal Site, Sample Location Map

  19. September 2004 Water Sampling

    Office of Legacy Management (LM)

    2015 Groundwater and Surface Water Sampling at the Shiprock, New Mexico, Disposal Site June 2015 LMS/SHP/S00315 This page intentionally left blank U.S. Department of Energy DVP-March 2015, Shiprock, New Mexico June 2015 RIN 15036862 and 15036863 Page i Contents Sampling Event Summary ...............................................................................................................1 Planned Sampling Map Shiprock, New Mexico, Disposal Site

  20. September 2004 Water Sampling

    Office of Legacy Management (LM)

    5 Groundwater and Surface Water Sampling at the Tuba City, Arizona Disposal Site June 2015 LMS/TUB/S00215 This page intentionally left blank U.S. Department of Energy DVP-February 2015, Tuba City, Arizona June 2015 RIN 15026775 Page i Contents Sampling Event Summary ...............................................................................................................1 Planned Sampling Map Tuba City, AZ, Disposal Site February 2015 ............................................5 Data

  1. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Tuba City, Arizona, Disposal Site November 2013 LMS/TUB/S00813 This page intentionally left blank U.S. Department of Energy DVP-August 2013, Tuba City, Arizona November 2013 RIN 13085553 Page i Contents Sampling Event Summary ...............................................................................................................1 Tuba City, Arizona, Disposal Site, Sample Location Map ..............................................................7 Data

  2. Heterogeneous Catalysis and Surface Science - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heterogeneous Catalysis and Surface Science / Part I: Surface Science in JCAP Laboratories Heterogeneous Catalysis and Surface Science research in JCAP focuses on the basic understanding of the relationships among the structure, composition, and reactivity of electrocatalysts. Knowledge gained from surface science experimentation can be implemented toward the discovery of better heterogeneous catalysts for solar-fuel production from carbon dioxide and water. REFERENCE Soriaga, M. P. et al.

  3. Water Efficiency

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency Hosted by: FEDERAL UTILITY PARTNERSHIP WORKING GROUP SEMINAR November 5-6, 2014 Cape Canaveral, Florida WATER EFFICIENCY Federal Utility Partnership Working Group November 5-6, 2014 Cape Canaveral, FL * Kate McMordie Stoughton - Pacific Northwest National Laboratory * kate.mcmordie@pnnl.gov * Francis Wheeler - Water Savers, LLC * fwheeler@watersaversllc.com Topics * Performance contracting analysis * Water industry terms * Federal reduction goals * Water balance * Water efficiency

  4. Surface mining

    SciTech Connect (OSTI)

    Not Available

    1989-06-01

    This paper reports on a GAO study of attorney and expert witness fees awarded as a result of litigation brought under the Surface Mining Control and Reclamation Act. As of March 24, 1989, a total of about $1.4 million had been awarded in attorney fees and expenses - about $1.3 subject to the provisions of the Employee Retirement Income Security Act, a comparison of its features with provisions of ERISA showed that the plan differed from ERISA provisions in areas such as eligibility, funding, and contribution limits.

  5. Reusing Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reusing Water Reusing Water Millions of gallons of industrial wastewater is recycled at LANL by virtue of a long-term strategy to treat wastewater rather than discharging it into...

  6. Clean Boiler Waterside Heat Transfer Surfaces

    Broader source: Energy.gov [DOE]

    This tip sheet on cleaning boiler water-side heat transfer surfaces provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  7. ARM - Sea Surface and Sea Level

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... On the other hand, under the changes in the level of the ocean surface, melting glaciers and ice sheets, ocean currents, daily tides, expansion or contraction of water based upon ...

  8. Sheet1 Water Availability Metric (Acre-Feet/Yr) Water Cost Metric ($/Acre-Foot)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sheet1 Water Availability Metric (Acre-Feet/Yr) Water Cost Metric ($/Acre-Foot) Current Water Use (Acre-Feet/Yr) Projected Use in 2030 (Acre-Feet/Yr) HUC_8 STATE BASIN SUBBASIN UNAPPROPRIATED SURFACE WATER METRIC UNAPPROPRIATED GROUNDWATER METRIC APPROPRIATED WATER METRIC BRACKISH GROUNDWATER METRIC WASTEWATER METRIC UNAPPROPRIATED GROUNDWATER COST METRIC APPROPRIATED WATER COST METRIC BRACKISH GROUNDWATER COST METRIC WASTEWATER COST METRIC M&I_2012 AG_2012 ENVIRONMENT 2012 THERMOELECTIC

  9. Water resources data for Louisiana, water year 1995. Water data report (Annual), 1 October 1994-30 September 1995

    SciTech Connect (OSTI)

    Garrison, C.R.; Lovelace, W.M.; Montgomery, P.A.

    1996-05-01

    Water resources data for the 1995 water year for Louisiana consists of records of stage, discharge, and water quality of streams; stage, contents, and water quality of lakes and reservoirs; and water levels and water quality of ground water. This report contains records for water discharge at 65 gaging stations; stage only for 40 gaging stations and 6 lakes; water quality for 45 surface-water stations (including 23 gage stations) and 76 wells; and water levels for 217 observation wells. Also included are data for 113 crest-stage and flood-profile partial-record stations. Additional water data were collected at various sites not involved in the systematic data-collection program, and are published as miscellaneous measurements.

  10. Water resources data for Louisiana, water year 1994. Water-data report (Annual), 1 October 1993-30 September 1994

    SciTech Connect (OSTI)

    Garrison, C.R.; Lovelace, W.M.; Montgomery, P.A.

    1995-03-01

    Water resources data for the 1994 water year for Louisiana consists of records for stage, discharge, and water quality of streams; stage, contents, and water quality of lakes and reservoirs; and water levels and water quality of ground water. This report contains records for water discharge at 64 gaging stations; stage only for 45 gaging stations and 6 lakes; water quality for 51 surface-water stations (including 24 gage stations) and 84 wells; and water levels for 209 observations wells. Also included are data for 115 crest-stage and flood-profile partial-record stations. Additional water data were collected at various sites not involved in the systematic data-collection program, and are published as miscellaneous measurements.

  11. WATER-TRAPPED WORLDS

    SciTech Connect (OSTI)

    Menou, Kristen [Department of Astronomy, Columbia University, 550 West 120th Street, New York, NY 10027 (United States)

    2013-09-01

    Although tidally locked habitable planets orbiting nearby M-dwarf stars are among the best astronomical targets to search for extrasolar life, they may also be deficient in volatiles and water. Climate models for this class of planets show atmospheric transport of water from the dayside to the nightside, where it is precipitated as snow and trapped as ice. Since ice only slowly flows back to the dayside upon accumulation, the resulting hydrological cycle can trap a large amount of water in the form of nightside ice. Using ice sheet dynamical and thermodynamical constraints, I illustrate how planets with less than about a quarter the Earth's oceans could trap most of their surface water on the nightside. This would leave their dayside, where habitable conditions are met, potentially dry. The amount and distribution of residual liquid water on the dayside depend on a variety of geophysical factors, including the efficiency of rock weathering at regulating atmospheric CO{sub 2} as dayside ocean basins dry up. Water-trapped worlds with dry daysides may offer similar advantages as land planets for habitability, by contrast with worlds where more abundant water freely flows around the globe.

  12. ITP Nanomanufacturing: Manufacturing of Surfaces with Nanoscale and Microscale Features

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Surfaces with Nanoscale and Microscale Features Enhanced Boiling, Condensation, and Water Repellency through the Fabrication of Structured Surfaces In nature, extremely hydrophobic surfaces such as the lotus plant leaf are called superhydrophobic (SHP). These surfaces appear to be macroscopically smooth, but are actually composed of nano- and micro-structured surfaces, the key to their SHP prop- erties. The industrial production of SHP surfaces, which are not yet available commercially, would

  13. Surface Gas Sampling At Lightning Dock Area (Norman & Moore,...

    Open Energy Info (EERE)

    Surface Gas Sampling At Lightning Dock Area (Norman & Moore, 2004) (Redirected from Water-Gas Samples At Lightning Dock Area (Norman & Moore, 2004)) Jump to: navigation, search...

  14. September 2004 Water Sampling

    Office of Legacy Management (LM)

    2014 Groundwater, Surface Water, Produced Water, and Natural Gas Sampling at the Gasbuggy, New Mexico, Site October 2014 LMS/GSB/S00614 Available for sale to the public from: U.S. Department of Commerce National Technical Information Service 5301 Shawnee Road Alexandria, VA 22312 Telephone: 800.553.6847 Fax: 703.605.6900 E-mail: orders@ntis.gov Online Ordering: http://www.ntis.gov/help/ordermethods.aspx Available electronically at http://www.osti.gov/scitech/ Available for a processing fee to

  15. Water Power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Power - NearyFig1 Permalink Gallery University of Illinois uses Sandia Labs' reference hydrokinetic turbine to study potential bed erosion effects Energy, Modeling & Analysis, News, Partnership, Renewable Energy, Water Power University of Illinois uses Sandia Labs' reference hydrokinetic turbine to study potential bed erosion effects Sandia Labs Water Power Technologies Department promotes open-source marine hydrokinetic research by disseminating information on MHK technology designs

  16. Water Power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stationary Power/Energy Conversion Efficiency/Water Power - Water PowerTara Camacho-Lopez2016-02-16T18:27:48+00:00 Enabling a successful water power industry. Hydropower Optimization Developing tools for optimizing the U.S. hydropower fleet's performance with minimal environmental impact. Technology Development Improving the power performance and reliability of marine hydrokinetic technologies. Market Acceleration & Deployment Addressing barriers to development, deployment, and evaluation of

  17. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and September 2013 Groundwater and Surface Water Sampling at the Durango, Colorado, Disposal and Processing Sites March 2014 LMS/DUD/DUP/S00613 This page intentionally left blank U.S. Department of Energy DVP-June and September 2013, Durango, Colorado March 2014 RIN 13055370 and 13085577 Page i Contents Sampling Event Summary ...............................................................................................................1 Durango, Colorado, Disposal Site Sample Location Map-June

  18. air_water.cdr

    Office of Legacy Management (LM)

    12/2011 Air Monitoring Groundwater Monitoring Surface Water Monitoring A continuously operating air monitoring network was in place from 1986 through 2000 for the Weldon Spring Site Remedial Action Project (WSSRAP) to measure levels of gamma radiation, radioactive dust particles, radon gas, and asbestos. With remediation of contaminated materials essentially complete and measurements indistinguishable from background, the U.S. Department of Energy (DOE) ceased perimeter and offsite air

  19. Water Power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water ...

  20. Reusing Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reusing Water Reusing Water Millions of gallons of industrial wastewater is recycled at LANL by virtue of a long-term strategy to treat wastewater rather than discharging it into the environment. April 12, 2012 Water from cooling the supercomputer is release to maintain a healthy wetland. Contact Environmental Communication & Public Involvement P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email We reuse the same water up to six times before releasing it back into the environment

  1. Polishing compound for plastic surfaces

    DOE Patents [OSTI]

    Stowell, M.S.

    1995-08-22

    A polishing compound for plastic surfaces is disclosed. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains fine particles silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS{trademark}, LEXAN{trademark}, LUCITE{trademark}, polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired. 5 figs.

  2. Polishing compound for plastic surfaces

    DOE Patents [OSTI]

    Stowell, Michael S. (New Ellenton, SC)

    1995-01-01

    A polishing compound for plastic surfaces. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains fine particles silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS.TM., LEXAN.TM., LUCITE.TM., polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired.

  3. Polishing compound for plastic surfaces

    DOE Patents [OSTI]

    Stowell, M.S.

    1993-01-01

    A polishing compound for plastic surfaces is disclosed. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains colloidal silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS{sup TM}, LEXAN{sup TM}, LUCITE{sup TM}, polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired.

  4. Are surface coal mine sediment ponds working

    SciTech Connect (OSTI)

    Poe, M.L.; Betson, R.P.

    1985-12-09

    Flowrates and storm generated water quality data were collected at sedimentation ponds on four surface mines in the states of Pennsylvania, Maryland, and West Virginia. The water quality data were analyzed for suspended solids and settleable solids content, and particle size distribution. The results were compared to the effluent limitations guidelines for total suspended solids as promulgated under the Clean Water Act for Coal Mining Point Source Category and adopted under the Surface Mine Control and Reclamation Act of 1977 and the resulting state regulatory programs. 3 references, 1 figure, 2 tables.

  5. Water Wars

    Energy Science and Technology Software Center (OSTI)

    2012-09-11

    Sandia National Laboratories and Intel Corporation are cooperating on a project aimed at developing serious games to assist in resource planners in conducting open and participatory projects. Water Wars serves as a prototype game focused on water issues. Water Wars is a multi-player, online role-playing "serious game" combining large-scale simulation (e.g. SimCity), with strategy and interpersonal interaction (e.g. Diplomacy). The game is about water use set in present-day New Mexico. Players enact various stakeholder rolesmore » and compete for water while simultaneously cooperating to prevent environmental collapse. The gamespace utilizes immersive 3D graphics to bring the problem alive. The game integrates Intel's OpenSim visualization engine with Sandia developed agent-based and system dynamics models.« less

  6. Water Resources Data Ohio: Water year 1994. Volume 1, Ohio River Basin excluding Project Data

    SciTech Connect (OSTI)

    1994-12-31

    The Water Resources Division of the US Geological Survey (USGS) in cooperation with State agencies, obtains a large amount of data each water year (a water year is the 12-month period from October 1 through September 30 and is identified by the calendar year in which it ends) pertaining to the water resources of Ohio. These data, accumulated during many years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make these data readily available to interested parties outside the USGS, they are published annually in this report series entitled ``Water Resources Data--Ohio.`` This report (in two volumes) includes records on surface water and ground water in the State. Specifically, it contains: (1) Discharge records for streamflow-gaging stations, miscellaneous sites, and crest-stage stations; (2) stage and content records for streams, lakes, and reservoirs; (3) water-quality data for streamflow-gaging stations, wells, synoptic sites, and partial-record sit -aid (4) water-level data for observation wells. Locations of lake-and streamflow-gaging stations, water-quality stations, and observation wells for which data are presented in this volume are shown in figures 8a through 8b. The data in this report represent that part of the National Water Data System collected by the USGS and cooperating State and Federal agencies in Ohio. This series of annual reports for Ohio began with the 1961 water year with a report that contained only data relating to the quantities of surface water. For the 1964 water year, a similar report was introduced that contained only data relating to water quality. Beginning with the 1975 water year, the report was changed to present (in two or three volumes) data on quantities of surface water, quality of surface and ground water, and ground-water levels.

  7. Water Clustering on Nanostructured Iron Oxide Films

    SciTech Connect (OSTI)

    Merte, L. R.; Bechstein, Ralf; Peng, Guowen; Rieboldt, Felix; Farberow, Carrie A.; Zeuthen, Helene; Knudsen, Jan; Laegsgaard, E.; Wendt, Stefen; Mavrikakis, Manos; Besenbacher, Fleming

    2014-06-30

    The adhesion of water to solid surfaces is characterized by the tendency to balance competing moleculemolecule and moleculesurface interactions. Hydroxyl groups form strong hydrogen bonds to water molecules and are known to substantially influence the wetting behaviour of oxide surfaces, but it is not well-understood how these hydroxyl groups and their distribution on a surface affect the molecular-scale structure at the interface. Here we report a study of water clustering on a moire-structured iron oxide thin film with a controlled density of hydroxyl groups. While large amorphous monolayer islands form on the are film, the hydroxylated iron oxide film acts as a hydrophilic nanotemplate, causing the formation of a regular array of ice-like hexameric nanoclusters. The formation of this ordered phase is localized at the nanometre scale; with increasing water coverage, ordered and amorphous water are found to coexist at adjacent hydroxylated and hydroxyl-free domains of the moire structure.

  8. Surface modification of polyethylene by functionalized plasma

    SciTech Connect (OSTI)

    Yuan, S.; Marchant, R.E.

    1993-12-31

    The surface of low density polyethylene(PE) has been modified by functionalized plasma-polymerized N-vinyl-2-pyrrolidone (PPNVP) and allyl alcohol(PPAA) thin films, PPNVP and PPAA(approx. 100 nm). The surface structure and functional groups of modified surfaces were characterized by water contact angle, ATR/FTIR and ESCA techniques. Plasma polymer modified PE surfaces exhibited significant water contact angle hysteresis and a much lower value of advancing water contact angle than that of unmodified polyethylene. Reduction of PPNVP and PPAA modified surfaces by sodium borohydride coverted into hydroxyl groups. The determined concentrations of hydroxyl groups on the reduced PPNVP and PPAA modified surfaces by ESCA after gas-phase derivatization with trifluoroacetic anhydride (TFAA) were about 25% and 30% of total oxygen content, respectively. Finally, the amine containing molecules such as amine-terminated polyethylene oxide (PEO) and 3-aminopropyltriethoxysilane (APTS) were coupled to the hydroxylated surfaces. These novel modified PE surfaces are suitable for immobilization of biomolecules.

  9. SUPERHEATING IN A BOILING WATER REACTOR

    DOE Patents [OSTI]

    Treshow, M.

    1960-05-31

    A boiling-water reactor is described in which the steam developed in the reactor is superheated in the reactor. This is accomplished by providing means for separating the steam from the water and passing the steam over a surface of the fissionable material which is not in contact with the water. Specifically water is boiled on the outside of tubular fuel elements and the steam is superheated on the inside of the fuel elements.

  10. Mitigation of radiation induced surface contamination

    DOE Patents [OSTI]

    Klebanoff, Leonard E. (Dublin, CA); Stulen, Richard H. (Livermore, CA)

    2003-01-01

    A process for mitigating or eliminating contamination and/or degradation of surfaces having common, adventitious atmospheric contaminants adsorbed thereon and exposed to radiation. A gas or a mixture of gases is introduced into the environment of a surface(s) to be protected. The choice of the gaseous species to be introduced (typically a hydrocarbon gas, water vapor, or oxygen or mixtures thereof) is dependent upon the contaminant as well as the ability of the gaseous species to bind to the surface to be protected. When the surface and associated bound species are exposed to radiation reactive species are formed that react with surface contaminants such as carbon or oxide films to form volatile products (e.g., CO, CO.sub.2) which desorb from the surface.

  11. Water inventory management in condenser pool of boiling water reactor

    DOE Patents [OSTI]

    Gluntz, Douglas M.

    1996-01-01

    An improved system for managing the water inventory in the condenser pool of a boiling water reactor has means for raising the level of the upper surface of the condenser pool water without adding water to the isolation pool. A tank filled with water is installed in a chamber of the condenser pool. The water-filled tank contains one or more holes or openings at its lowermost periphery and is connected via piping and a passive-type valve (e.g., squib valve) to a high-pressure gas-charged pneumatic tank of appropriate volume. The valve is normally closed, but can be opened at an appropriate time following a loss-of-coolant accident. When the valve opens, high-pressure gas inside the pneumatic tank is released to flow passively through the piping to pressurize the interior of the water-filled tank. In so doing, the initial water contents of the tank are expelled through the openings, causing the water level in the condenser pool to rise. This increases the volume of water available to be boiled off by heat conducted from the passive containment cooling heat exchangers. 4 figs.

  12. Water inventory management in condenser pool of boiling water reactor

    DOE Patents [OSTI]

    Gluntz, D.M.

    1996-03-12

    An improved system for managing the water inventory in the condenser pool of a boiling water reactor has means for raising the level of the upper surface of the condenser pool water without adding water to the isolation pool. A tank filled with water is installed in a chamber of the condenser pool. The water-filled tank contains one or more holes or openings at its lowermost periphery and is connected via piping and a passive-type valve (e.g., squib valve) to a high-pressure gas-charged pneumatic tank of appropriate volume. The valve is normally closed, but can be opened at an appropriate time following a loss-of-coolant accident. When the valve opens, high-pressure gas inside the pneumatic tank is released to flow passively through the piping to pressurize the interior of the water-filled tank. In so doing, the initial water contents of the tank are expelled through the openings, causing the water level in the condenser pool to rise. This increases the volume of water available to be boiled off by heat conducted from the passive containment cooling heat exchangers. 4 figs.

  13. Portable solar water heater

    SciTech Connect (OSTI)

    Borodulin, G.; Baron, R.; Shkolnik, A.

    1985-11-12

    A combined table and portable solar water heater comprises a suitcase-like rigid casing molded from a rigid plastic material which contains a pair of solar collector panels and connected in series. The panels can be exposed to solar radiation when the casing is opened. Each collector panel or is formed by a copper plate with the solar radiation absorbing surface and copper pipe coil or in heat-transferring relationship with said copper plate. The casing is provided with compartments for accessories, such as adjustable legs for supporting the casing, adjusting its angle to incident sunlight, and for converting the casing into a table; containers for feeding cold water to the solar collector and for receiving hot water from the collector; and a tripod stand for supporting the feeding container at the level above the collector and for arranging a shower set. Temperature-insulating layers of the collectors are formed by separate pieces of rigid material which can be removed from the casing and assembled into a box-shaped container which can be utilized for maintaining water heated by means of the solar water heater at an elevated temperature.

  14. drinking water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    drinking water - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear

  15. Passive containment cooling water distribution device

    DOE Patents [OSTI]

    Conway, Lawrence E.; Fanto, Susan V.

    1994-01-01

    A passive containment cooling system for a nuclear reactor containment vessel. Disclosed is a cooling water distribution system for introducing cooling water by gravity uniformly over the outer surface of a steel containment vessel using a series of radial guide elements and cascading weir boxes to collect and then distribute the cooling water into a series of distribution areas through a plurality of cascading weirs. The cooling water is then uniformly distributed over the curved surface by a plurality of weir notches in the face plate of the weir box.

  16. Sweet Surface Area

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sweet Surface Area Sweet Surface Area Create a delicious root beer float and learn sophisticated science concepts at the same time. Sweet Surface Area Science is all around us, so...

  17. Surface functionalized mesoporous material and method of making same

    DOE Patents [OSTI]

    Feng, Xiangdong [West Richland, WA; Liu, Jun [West Richland, WA; Fryxell, Glen E. [Kennewick, WA

    2001-12-04

    According to the present invention, an organized assembly of functional molecules with specific interfacial functionality (functional group(s)) is attached to available surfaces including within mesopores of a mesoporous material. The method of the present invention avoids the standard base soak that would digest the walls between the mesopores by boiling the mesoporous material in water for surface preparation then removing all but one or two layers of water molecules on the internal surface of a pore. Suitable functional molecule precursor is then applied to permeate the hydrated pores and the precursor then undergoes condensation to form the functional molecules on the interior surface(s) of the pore(s).

  18. Task 6 - Subtask 1: PNNL Visit by JAEA Researchers to Evaluate the Feasibility of the FLESCOT Code for the Future JAEA Use for the Fukushima Surface Water Environmental Assessment

    SciTech Connect (OSTI)

    Onishi, Yasuo

    2014-01-01

    Four Japan Atomic Energy Agency (JAEA) researchers visited Pacific Northwest National Laboratory (PNNL) for seven working days and have evaluated the suitability and adaptability of FLESCOT to a JAEA’s supercomputer system to effectively simulate cesium behavior in dam reservoirs, river mouths, and coastal areas in Fukushima contaminated by the Fukushima Daiichi nuclear accident. PNNL showed the following to JAEA visitors during the seven-working day period: • FLESCOT source code • User’s manual • FLESCOT description – Program structure – Algorism – Solver – Boundary condition handling – Data definition – Input and output methods – How to run. During the visit, JAEA had access to FLESCOT to run with an input data set to evaluate the capacity and feasibility of adapting it to a JAEA super computer with massive parallel processors. As a part of this evaluation, PNNL ran FLESCOT for sample cases of the contaminant migration simulation to further describe FLESCOT in action. JAEA and PNNL researchers also evaluated time spent for each subroutine of FLESCOT, and the JAEA researcher implemented some initial parallelization schemes to FLESCOT. Based on this code evaluation, JAEA and PNNL determined that FLESCOT is • applicable to Fukushima lakes/dam reservoirs, river mouth areas, and coastal water • feasible to implement parallelization for the JAEA supercomputer. In addition, PNNL and JAEA researchers discussed molecular modeling approaches on cesium adsorption mechanisms to enhance the JAEA molecular modeling activities. PNNL and JAEA also discussed specific collaboration of molecular and computational modeling activities.

  19. Numerical simulation of the environmental impact of hydraulic fracturing of tight/shale gas reservoirs on near-surface groundwater: Background, base cases, shallow reservoirs, short-term gas, and water transport

    SciTech Connect (OSTI)

    Reagan, Matthew T.; Moridis, George J.; Keen, Noel D.; Johnson, Jeffrey N.

    2015-04-18

    Hydrocarbon production from unconventional resources and the use of reservoir stimulation techniques, such as hydraulic fracturing, has grown explosively over the last decade. However, concerns have arisen that reservoir stimulation creates significant environmental threats through the creation of permeable pathways connecting the stimulated reservoir with shallower freshwater aquifers, thus resulting in the contamination of potable groundwater by escaping hydrocarbons or other reservoir fluids. This study investigates, by numerical simulation, gas and water transport between a shallow tight-gas reservoir and a shallower overlying freshwater aquifer following hydraulic fracturing operations, if such a connecting pathway has been created. We focus on two general failure scenarios: (1) communication between the reservoir and aquifer via a connecting fracture or fault and (2) communication via a deteriorated, preexisting nearby well. We conclude that the key factors driving short-term transport of gas include high permeability for the connecting pathway and the overall volume of the connecting feature. Production from the reservoir is likely to mitigate release through reduction of available free gas and lowering of reservoir pressure, and not producing may increase the potential for release. We also find that hydrostatic tight-gas reservoirs are unlikely to act as a continuing source of migrating gas, as gas contained within the newly formed hydraulic fracture is the primary source for potential contamination. Such incidents of gas escape are likely to be limited in duration and scope for hydrostatic reservoirs. Reliable field and laboratory data must be acquired to constrain the factors and determine the likelihood of these outcomes.

  20. High temperature low friction surface coating

    DOE Patents [OSTI]

    Bhushan, Bharat (Watervliet, NY)

    1980-01-01

    A high temperature, low friction, flexible coating for metal surfaces which are subject to rubbing contact includes a mixture of three parts graphite and one part cadmium oxide, ball milled in water for four hours, then mixed with thirty percent by weight of sodium silicate in water solution and a few drops of wetting agent. The mixture is sprayed 12-15 microns thick onto an electro-etched metal surface and air dried for thirty minutes, then baked for two hours at 65.degree. C. to remove the water and wetting agent, and baked for an additional eight hours at about 150.degree. C. to produce the optimum bond with the metal surface. The coating is afterwards burnished to a thickness of about 7-10 microns.

  1. Numerical simulation of the environmental impact of hydraulic fracturing of tight/shale gas reservoirs on near-surface groundwater: Background, base cases, shallow reservoirs, short-term gas, and water transport

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Reagan, Matthew T.; Moridis, George J.; Keen, Noel D.; Johnson, Jeffrey N.

    2015-04-18

    Hydrocarbon production from unconventional resources and the use of reservoir stimulation techniques, such as hydraulic fracturing, has grown explosively over the last decade. However, concerns have arisen that reservoir stimulation creates significant environmental threats through the creation of permeable pathways connecting the stimulated reservoir with shallower freshwater aquifers, thus resulting in the contamination of potable groundwater by escaping hydrocarbons or other reservoir fluids. This study investigates, by numerical simulation, gas and water transport between a shallow tight-gas reservoir and a shallower overlying freshwater aquifer following hydraulic fracturing operations, if such a connecting pathway has been created. We focus on twomore » general failure scenarios: (1) communication between the reservoir and aquifer via a connecting fracture or fault and (2) communication via a deteriorated, preexisting nearby well. We conclude that the key factors driving short-term transport of gas include high permeability for the connecting pathway and the overall volume of the connecting feature. Production from the reservoir is likely to mitigate release through reduction of available free gas and lowering of reservoir pressure, and not producing may increase the potential for release. We also find that hydrostatic tight-gas reservoirs are unlikely to act as a continuing source of migrating gas, as gas contained within the newly formed hydraulic fracture is the primary source for potential contamination. Such incidents of gas escape are likely to be limited in duration and scope for hydrostatic reservoirs. Reliable field and laboratory data must be acquired to constrain the factors and determine the likelihood of these outcomes.« less

  2. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Molecular Structure of Water at Gold Electrodes Revealed Print Wednesday, 25 March 2015 00:00 The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to it when a surface is introduced. ALS researchers have now made a first-ever observation of the molecular structure of liquid water at a gold surface under different charging conditions. This marks the first time that the scientific

  3. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Rio Blanco, Colorado, Site October 2014 LMS/RBL/S00514 Available for sale to the public from: U.S. Department of Commerce National Technical Information Service 5301 Shawnee Road Alexandria, VA 22312 Telephone: 800.553.6847 Fax: 703.605.6900 E-mail: orders@ntis.gov Online Ordering: http://www.ntis.gov/help/ordermethods.aspx Available electronically at http://www.osti.gov/scitech/ Available for a processing fee to U.S. Department of Energy and its contractors, in

  4. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Groundwater and Surface Water Sampling at the Rio Blanco, Colorado, Site October 2015 LMS/RBL/S00515 Available for sale to the public from: U.S. Department of Commerce National Technical Information Service 5301 Shawnee Road Alexandria, VA 22312 Telephone: 800.553.6847 Fax: 703.605.6900 E-mail: orders@ntis.gov Online Ordering: http://www.ntis.gov/help/ordermethods.aspx Available electronically at http://www.osti.gov/scitech/ Available for a processing fee to U.S. Department of Energy and its

  5. September 2004 Water Sampling

    Office of Legacy Management (LM)

    5 Groundwater and Surface Water Sampling at the Rulison, Colorado, Site October 2015 LMS/RUL/S00515 Available for sale to the public from: U.S. Department of Commerce National Technical Information Service 5301 Shawnee Road Alexandria, VA 22312 Telephone: 800.553.6847 Fax: 703.605.6900 E-mail: orders@ntis.gov Online Ordering: http://www.ntis.gov/help/ordermethods.aspx Available electronically at http://www.osti.gov/scitech/ Available for a processing fee to U.S. Department of Energy and its

  6. Check Heat Transfer Surfaces

    Broader source: Energy.gov [DOE]

    This tip sheet discusses the importance of checking heat transfer surfaces in process heating systems.

  7. Actinide Dioxides in Water: Interactions at the Interface

    SciTech Connect (OSTI)

    Alexandrov, Vitaly; Shvareva, Tatiana Y.; Hayun, Shmuel; Asta, Mark; Navrotsky, Alexandra

    2011-12-15

    A comprehensive understanding of chemical interactions between water and actinide dioxide surfaces is critical for safe operation and storage of nuclear fuels. Despite substantial previous research, understanding the nature of these interactions remains incomplete. In this work, we combine accurate calorimetric measurements with first-principles computational studies to characterize surface energies and adsorption enthalpies of water on two fluorite-structured compounds, ThO? and CeO?, that are relevant for understanding the behavior of water on actinide oxide surfaces more generally. We determine coverage-dependent adsorption enthalpies and demonstrate a mixed molecular and dissociative structure for the first hydration layer. The results show a correlation between the magnitude of the anhydrous surface energy and the water adsorption enthalpy. Further, they suggest a structural model featuring one adsorbed water molecule per one surface cation on the most stable facet that is expected to be a common structural signature of water adsorbed on actinide dioxide compounds.

  8. Polishing compound for plastic surfaces

    DOE Patents [OSTI]

    Stowell, M.S.

    1991-01-01

    This invention is comprised of a polishing compound for plastic materials. The compound includes approximately by approximately by weight 25 to 80 parts at least one petroleum distillate lubricant, 1 to 12 parts mineral spirits, 50 to 155 parts abrasive paste, and 15 to 60 parts water. Preferably, the compound includes approximately 37 to 42 parts at least one petroleum distillate lubricant, up to 8 parts mineral spirits, 95 to 110 parts abrasive paste, and 50 to 55 parts water. The proportions of the ingredients are varied in accordance with the particular application. The compound is used on PLEXIGLAS{trademark}, LEXAN{trademark}, LUCITE{trademark}, polyvinyl chloride (PVC), and similar plastic materials whenever a smooth, clear polished surface is desired.

  9. water infrastructure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    infrastructure - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear

  10. water savings

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    savings - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  11. water scarcity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    scarcity - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  12. Fluorinated silica microchannel surfaces

    DOE Patents [OSTI]

    Kirby, Brian J.; Shepodd, Timothy Jon

    2005-03-15

    A method for surface modification of microchannels and capillaries. The method produces a chemically inert surface having a lowered surface free energy and improved frictional properties by attaching a fluorinated alkane group to the surface. The coating is produced by hydrolysis of a silane agent that is functionalized with either alkoxy or chloro ligands and an uncharged C.sub.3 -C.sub.10 fluorinated alkane chain. It has been found that the extent of surface coverage can be controlled by controlling the contact time from a minimum of about 2 minutes to a maximum of 120 minutes for complete surface coverage.

  13. Tritiated Water Interaction with Stainless Steel

    SciTech Connect (OSTI)

    Glen R. Longhurst

    2007-05-01

    Experiments conducted to study tritium permeation of stainless steel at ambient and elevated temperatures revealed that HT converts relatively quickly to HTO. Further, the HTO partial pressure contributes essentially equally with elemental tritium gas in driving permeation through the stainless steel. Such permeation appears to be due to dissociation of the water molecule on the hot stainless steel surface. There is an equilibrium concentration of HTO vapor above adsorbed gas on the walls of the experimental apparatus evident from freezing transients. The uptake process of tritium from the carrier gas involves both surface adsorption and isotopic exchange with surface bound water.

  14. Towards a unified picture of the water self-ions at the air-water...

    Office of Scientific and Technical Information (OSTI)

    OH- prefer to be at the water surface or in the bulk. Here we report a molecular dynamics simulation study of the bulk vs. interfacial behavior of H3O+ and OH- that employs forces...

  15. ARM - Measurement - Liquid water path

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    path ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Liquid water path A measure of the weight of the liquid water droplets in the atmosphere above a unit surface area on the earth, given in units of kg m-2. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument

  16. Surface Gas Sampling At Lightning Dock Area (Norman, Et Al.,...

    Open Energy Info (EERE)

    Surface Gas Sampling At Lightning Dock Area (Norman, Et Al., 2002) (Redirected from Water-Gas Samples At Lightning Dock Area (Norman, Et Al., 2002)) Jump to: navigation, search...

  17. Surface cleanliness measurement procedure

    DOE Patents [OSTI]

    Schroder, Mark Stewart; Woodmansee, Donald Ernest; Beadie, Douglas Frank

    2002-01-01

    A procedure and tools for quantifying surface cleanliness are described. Cleanliness of a target surface is quantified by wiping a prescribed area of the surface with a flexible, bright white cloth swatch, preferably mounted on a special tool. The cloth picks up a substantial amount of any particulate surface contamination. The amount of contamination is determined by measuring the reflectivity loss of the cloth before and after wiping on the contaminated system and comparing that loss to a previous calibration with similar contamination. In the alternative, a visual comparison of the contaminated cloth to a contamination key provides an indication of the surface cleanliness.

  18. Efficient Water Use & Management

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Use Goal 4: Efficient Water Use & Management Aware of the arid climate of northern New Mexico, water reduction and conservation remains a primary concern at LANL. Energy...

  19. Perspective: Water cluster mediated atmospheric chemistry

    SciTech Connect (OSTI)

    Vaida, Veronica

    2011-07-14

    The importance of water in atmospheric and environmental chemistry initiated recent studies with results documenting catalysis, suppression and anti-catalysis of thermal and photochemical reactions due to hydrogen bonding of reagents with water. Water, even one water molecule in binary complexes, has been shown by quantum chemistry to stabilize the transition state and lower its energy. However, new results underscore the need to evaluate the relative competing rates between reaction and dissipation to elucidate the role of water in chemistry. Water clusters have been used successfully as models for reactions in gas-phase, in aqueous condensed phases and at aqueous surfaces. Opportunities for experimental and theoretical chemical physics to make fundamental new discoveries abound. Work in this field is timely given the importance of water in atmospheric and environmental chemistry.

  20. Submersible purification system for radioactive water

    DOE Patents [OSTI]

    Abbott, Michael L.; Lewis, Donald R.

    1989-01-01

    A portable, submersible water purification system for use in a pool of water containing radioactive contamination includes a prefilter for filtering particulates from the water. A resin bed is then provided for removal of remaining dissolved, particulate, organic, and colloidal impurities from the prefiltered water. A sterilizer then sterilizes the water. The prefilter and resin bed are suitably contained and are submerged in the pool. The sterilizer is water tight and located at the surface of the pool. The water is circulated from the pool through the prefilter, resin bed, and sterilizer by suitable pump or the like. In the preferred embodiment, the resin bed is contained within a tank which stands on the bottom of the pool and to which a base mounting the prefilter and pump is attached. An inlet for the pump is provided adjacent the bottom of the pool, while the sterilizer and outlet for the system is located adjacent the top of the pool.

  1. Conjunctive Surface and Groundwater Management in Utah: Implications for

    Office of Scientific and Technical Information (OSTI)

    Oil Shale and Oil Sands Development (Technical Report) | SciTech Connect Conjunctive Surface and Groundwater Management in Utah: Implications for Oil Shale and Oil Sands Development Citation Details In-Document Search Title: Conjunctive Surface and Groundwater Management in Utah: Implications for Oil Shale and Oil Sands Development Unconventional fuel development will require scarce water resources. In an environment characterized by scarcity, and where most water resources are fully

  2. Produced Water Management and Beneficial Use

    SciTech Connect (OSTI)

    Terry Brown; Carol Frost; Thomas Hayes; Leo Heath; Drew Johnson; David Lopez; Demian Saffer; Michael Urynowicz; John Wheaton; Mark Zoback

    2007-10-31

    Large quantities of water are associated with the production of coalbed methane (CBM) in the Powder River Basin (PRB) of Wyoming. The chemistry of co-produced water often makes it unsuitable for subsequent uses such as irrigated agriculture. However, co-produced waters have substantial potential for a variety of beneficial uses. Achieving this potential requires the development of appropriate water management strategies. There are several unique characteristics of co-produced water that make development of such management strategies a challenge. The production of CBM water follows an inverse pattern compared to traditional wells. CBM wells need to maintain low reservoir pressures to promote gas production. This need renders the reinjection of co-produced waters counterproductive. The unique water chemistry of co-produced water can reduce soil permeability, making surface disposal difficult. Unlike traditional petroleum operations where co-produced water is an undesirable by-product, co-produced water in the PRB often is potable, making it a highly valued resource in arid western states. This research project developed and evaluated a number of water management options potentially available to CBM operators. These options, which focus on cost-effective and environmentally-sound practices, fall into five topic areas: Minimization of Produced Water, Surface Disposal, Beneficial Use, Disposal by Injection and Water Treatment. The research project was managed by the Colorado Energy Research Institute (CERI) at the Colorado School of Mines (CSM) and involved personnel located at CERI, CSM, Stanford University, Pennsylvania State University, the University of Wyoming, the Argonne National Laboratory, the Gas Technology Institute, the Montana Bureau of Mining and Geology and PVES Inc., a private firm.

  3. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to it when a surface is introduced. ALS researchers have now made a first-ever observation of the molecular structure of liquid water at a gold surface under different charging conditions. This marks the first time that the scientific community has shown such high sensitivity in an in-situ environment under working

  4. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to it when a surface is introduced. ALS researchers have now made a first-ever observation of the molecular structure of liquid water at a gold surface under different charging conditions. This marks the first time that the scientific community has shown such high sensitivity in an in-situ environment under working

  5. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to it when a surface is introduced. ALS researchers have now made a first-ever observation of the molecular structure of liquid water at a gold surface under different charging conditions. This marks the first time that the scientific community has shown such high sensitivity in an in-situ environment under working

  6. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to it when a surface is introduced. ALS researchers have now made a first-ever observation of the molecular structure of liquid water at a gold surface under different charging conditions. This marks the first time that the scientific community has shown such high sensitivity in an in-situ environment under working

  7. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to it when a surface is introduced. ALS researchers have now made a first-ever observation of the molecular structure of liquid water at a gold surface under different charging conditions. This marks the first time that the scientific community has shown such high sensitivity in an in-situ environment under working

  8. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to it when a surface is introduced. ALS researchers have now made a first-ever observation of the molecular structure of liquid water at a gold surface under different charging conditions. This marks the first time that the scientific community has shown such high sensitivity in an in-situ environment under working

  9. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to it when a surface is introduced. ALS researchers have now made a first-ever observation of the molecular structure of liquid water at a gold surface under different charging conditions. This marks the first time that the scientific community has shown such high sensitivity in an in-situ environment under working

  10. DNA ELECTROPHORESIS AT SURFACES

    SciTech Connect (OSTI)

    RAFAILOVICH, MIRIAM; SOKOLOV, JONATHAN; GERSAPPE, DILIP

    2003-09-01

    During this year we performed two major projects: I. We developed a detailed theoretical model which complements our experiments on surface DNA electrophoresis. We found that it was possible to enhance the separation of DNA chains by imposing a chemical nanoscale pattern on the surface. This approach utilized the surface interaction effect of the DNA chains with the substrate and is a refinement to our previous method in which DNA chains were separated on homogeneous flat surfaces. By introducing the nano-patterns on the surface, the conformational changes of DNA chains of different lengths can be amplified, which results in the different friction strengths with the substrate surface. Our results also show that, when compared to the DNA electrophoresis performed on homogeneous flat surfaces, nanopatterned surfaces offer a larger window in choosing different surface interactions to achieve separation. II. In collaboration with a large international manufacturer of skin care products we also embarked on a project involving photo toxicity of titanium dioxide nanoparticles, which are a key ingredient in sunscreen and cosmetic lotions. The results clearly implicated the nanoparticles in catalyzing damage to chromosomal DNA. We then used this knowledge to develop a polymer/anti-oxidant coating which prevented the photocatalytic reaction on DNA while still retaining the UV absorptive properties of the nanoparticles. The standard gel electrophoresis was not sufficient in determining the extent of the DNA damage. The conclusions of this study were based predominantly on analysis obtained with the surface electrophoresis method.

  11. Viscosity of interfacial water regulates ice nucleation

    SciTech Connect (OSTI)

    Li, Kaiyong; Chen, Jing; Zhang, Qiaolan; Zhang, Yifan; University of Chinese Academy of Sciences, Beijing 100049 ; Xu, Shun; Zhou, Xin; Cui, Dapeng; Wang, Jianjun Song, Yanlin

    2014-03-10

    Ice formation on solid surfaces is an important phenomenon in many fields, such as cloud formation and atmospheric icing, and a key factor for applications in preventing freezing. Here, we report temperature-dependent nucleation rates of ice for hydrophilic and hydrophobic surfaces. The results show that hydrophilic surface presents a lower ice nucleation rate. We develop a strategy to extract the thermodynamic parameters, J{sub 0} and ?, in the context of classical nucleation theory. From the extracted J{sub 0} and ?, we reveal the dominant role played by interfacial water. The results provide an insight into freezing mechanism on solid surfaces.

  12. Waters LANL Protects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Waters LANL Protects Waters LANL Protects LANL watersheds source in the Jemez Mountains and end at the Rio Grande.

  13. DROPWISE CONDENSATION ON MICRO- AND NANOSTRUCTURED SURFACES

    SciTech Connect (OSTI)

    Enright, R; Miljkovic, N; Alvarado, JL; Kim, K; Rose, JW

    2014-07-23

    In this review we cover recent developments in the area of surface-enhanced dropwise condensation against the background of earlier work. The development of fabrication techniques to create surface structures at the micro-and nanoscale using both bottom-up and top-down approaches has led to increased study of complex interfacial phenomena. In the heat transfer community, researchers have been extensively exploring the use of advanced surface structuring techniques to enhance phase-change heat transfer processes. In particular, the field of vapor-to-liquid condensation and especially that of water condensation has experienced a renaissance due to the promise of further optimizing this process at the micro-and nanoscale by exploiting advances in surface engineering developed over the last several decades.

  14. Silane Modification of Glass and Silica Surfaces to Obtain Equally Oil-Wet Surfaces in Glass-Covered Silicon Micromodel Applications

    SciTech Connect (OSTI)

    Grate, Jay W.; Warner, Marvin G.; Pittman, Jonathan W.; Dehoff, Karl J.; Wietsma, Thomas W.; Zhang, Changyong; Oostrom, Martinus

    2013-08-05

    The wettability of silicon and glass surfaces can be modified by silanization. However, similar treatments of glass and silica surfaces using the same silane do not necessarily yield the same wettability as determined by the oil-water contact angle. In this technical note, surface cleaning pretreatments were investigated to determine conditions that would yield oil-wet surfaces on glass with similar wettability to silica surfaces treated with the same silane, and both air-water and oil-water contact angles were determined. Air-water contact angles were less sensitive to differences between silanized silica and glass surfaces, often yielding similar values while the oil-water contact angles were quite different. Borosilicate glass surfaces cleaned with standard cleaning solution 1 (SC1) yield intermediate-wet surfaces when silanized with hexamethyldisilazane, while the same cleaning and silanization yields oil-wet surfaces on silica. However, cleaning glass in boiling concentrated nitric acid creates a surface that can be silanized to obtain oil-wet surfaces using HDMS. Moreover, this method is effective on glass with prior thermal treatment at an elevated temperature of 400oC. In this way, silica and glass can be silanized to obtain equally oil-wet surfaces using HMDS. It is demonstrated that pretreatment and silanization is feasible in silicon-silica/glass micromodels previously assembled by anodic bonding, and that the change in wettability has a significant observable effect on immiscisble fluid displacements in the pore network.

  15. Surface modification to waveguides

    DOE Patents [OSTI]

    Timberlake, John R. (Allentown, NJ); Ruzic, David N. (Kendall Park, NJ); Moore, Richard L. (Princeton, NJ); Cohen, Samuel A. (Pennington, NJ); Manos, Dennis M. (Lawrenceville, NJ)

    1983-01-01

    A method of treating the interior surfaces of a waveguide to improve power transmission comprising the steps of mechanically polishing to remove surface protrusions; electropolishing to remove embedded particles; ultrasonically cleaning to remove any residue; coating the interior waveguide surfaces with an alkyd resin solution or electrophoretically depositing carbon lamp black suspended in an alkyd resin solution to form a 1.mu. to 5.mu. thick film; vacuum pyrolyzing the film to form a uniform adherent carbon coating.

  16. Surface modification to waveguides

    DOE Patents [OSTI]

    Timberlake, J.R.; Ruzic, D.N.; Moore, R.L.; Cohen, S.A.; Manos, D.M.

    1982-06-16

    A method is described for treating the interior surfaces of a waveguide to improve power transmission comprising the steps of mechanically polishing to remove surface protrusions; electropolishing to remove embedded particles; ultrasonically cleaning to remove any residue; coating the interior waveguide surfaces with an alkyd resin solution or electrophoretically depositing carbon lamp black suspended in an alkyd resin solution to form a 1..mu.. to 5..mu.. thick film; vacuum pyrolyzing the film to form a uniform adherent carbon coating.

  17. Incompressible Flows Free Surfaces

    Energy Science and Technology Software Center (OSTI)

    1992-02-01

    NASA-VOF3D is a three-dimensional, transient, free surface, incompressible fluid dynamics program. It is specifically designed to calculate confined flows in a low gravity environment in which surface physics must be accurately treated. It allows multiple free surfaces with surface tension and wall adhesion and includes a partial cell treatment that allows curved boundaries and internal obstacles. Variable mesh spacing is permitted in all three coordinate directions. Boundary conditions available are rigid free-slip wall, rigid no-slipmore » wall, continuative, periodic, and specified pressure outflow boundary.« less

  18. ARM - Measurement - Surface albedo

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    albedo ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Surface albedo The fraction of incoming solar radiation at a surface (i.e. land, cloud top) that is effectively reflected by that surface. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of

  19. Appendix PORSURF: Porosity Surface

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    BRAGFLO constrained to fall on this surface. Various techniques described in Freeze, Larson, and Davies (Freeze, Larson, and Davies 1995) were used to check the validity of this...

  20. ARM - Measurement - Surface condition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Weather Forecasts Model Data LANDCOVER-SAT : Landcover Derived From Satellite Data RSP : Research Scanning Polarimeter MET : Surface Meteorological Instrumentation VEGWATER-SAT :...

  1. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maria Cadeddu

    2004-02-19

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  2. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maria Cadeddu

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  3. Water Heating | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Public Services Homes Water Heating Water Heating Infographic: Water Heaters 101 Infographic: Water Heaters 101 Everything you need to know about saving money on water...

  4. Solar absorption surface panel

    DOE Patents [OSTI]

    Santala, Teuvo J.

    1978-01-01

    A composite metal of aluminum and nickel is used to form an economical solar absorption surface for a collector plate wherein an intermetallic compound of the aluminum and nickel provides a surface morphology with high absorptance and relatively low infrared emittance along with good durability.

  5. EA-1406: Finding of No Significant Impact | Department of Energy

    Office of Environmental Management (EM)

    06: Finding of No Significant Impact EA-1406: Finding of No Significant Impact Ground Water Compliance at the New Rifle, Colorado, UMTRA Project Site On the basis of the Environmental Assessment. which analyzed relevant environmental issues and addressed the concerns of stakeholders, DOE finds that no significant impact will result from implementing the planned action at the New Rifle site. This FONSI is documented pursuant to NEPA, the Council on Environmental Quality's "Regulations for

  6. EA-1406: Final Environmental Assessment | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6: Final Environmental Assessment EA-1406: Final Environmental Assessment Ground Water Compliance at the New Rifle, Colorado, UMTRA Project Site This EA evaluates the environmental impacts for the proposed compliance strategy of natural flushing combined with institutional controls and continued monitoring for the New Rifle uranium mill tailings site. PDF icon EA-1406-FEA-2003.pdf More Documents & Publications Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New

  7. Frontiers of interfacial water research :workshop report.

    SciTech Connect (OSTI)

    Cygan, Randall Timothy; Greathouse, Jeffery A.

    2005-10-01

    Water is the critical natural resource of the new century. Significant improvements in traditional water treatment processes require novel approaches based on a fundamental understanding of nanoscale and atomic interactions at interfaces between aqueous solution and materials. To better understand these critical issues and to promote an open dialog among leading international experts in water-related specialties, Sandia National Laboratories sponsored a workshop on April 24-26, 2005 in Santa Fe, New Mexico. The ''Frontiers of Interfacial Water Research Workshop'' provided attendees with a critical review of water technologies and emphasized the new advances in surface and interfacial microscopy, spectroscopy, diffraction, and computer simulation needed for the development of new materials for water treatment.

  8. LANL Water Protection Status Report - FY12 3rd Qtr. (Apr thru Jun 2012)

    SciTech Connect (OSTI)

    Douglass, Craig R.

    2012-07-12

    Continued monitoring of the Buckman Direct Diversion and Los Alamos County Water Supply Wells; Groundwater Protection - Continued implementation of the Interim Facility-Wide Groundwater Monitoring Plan (IFGMP); Surface Water Protection - Continued protection of surface water through implementation of the Individual Stormwater Permit (IP); Buckman Early Notification System operability at 100% per MOU Requirements.

  9. Method For Creating Corrosion Resistant Surface On An Aluminum Copper Alloy

    DOE Patents [OSTI]

    Mansfeld, Florian B. (Playa del Rey, CA); Wang, You (Jingshou, CN); Lin, Simon H. (San Dimas, CA)

    1997-06-03

    A method for treating the surface of aluminum alloys hang a relatively high copper content is provided which includes the steps of removing substantially all of the copper from the surface, contacting the surface with a first solution containing cerium, electrically charging the surface while contacting the surface in an aqueous molybdate solution, and contacting the surface with a second solution containing cerium. The copper is substantially removed from the surface in the first step either by (i) contacting the surface with an acidic chromate solution or by (ii) contacting the surface with an acidic nitrate solution while subjecting the surface to an electric potential. The corrosion-resistant surface resulting from the invention is excellent, consistent and uniform throughout the surface. Surfaces treated by the invention may often be certified for use in salt-water services.

  10. New Surface Meteorological Measurements at SGP,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NM, March 22 - 26, 2004 1 New Surface Meteorological Measurements at SGP, and Their Use for Assessing Radiosonde Measurement Accuracy L.M. Miloshevich National Center for Atmospheric Research Boulder, Colorado B.M. Lesht and M. Ritche Argonne National Laboratory Argonne, Illinois Introduction Several recent ARM investigations have been directed toward characterizing and improving the accuracy of ARM radiosonde water vapor measurements. Tobin et al. (2002) showed that calculating the downwelling

  11. Exploiting interfacial water properties for desalination and purification applications.

    SciTech Connect (OSTI)

    Xu, Hongwu; Varma, Sameer; Nyman, May Devan; Alam, Todd Michael; Thuermer, Konrad; Holland, Gregory P.; Leung, Kevin; Liu, Nanguo; Xomeritakis, George K.; Frankamp, Benjamin L.; Siepmann, J. Ilja; Cygan, Randall Timothy; Hartl, Monika A.; Travesset, Alex; Anderson, Joshua A.; Huber, Dale L.; Kissel, David J.; Bunker, Bruce Conrad; Lorenz, Christian Douglas; Major, Ryan C.; McGrath, Matthew J.; Farrow, Darcie; Cecchi, Joseph L.; van Swol, Frank B.; Singh, Seema; Rempe, Susan B.; Brinker, C. Jeffrey; Clawson, Jacalyn S.; Feibelman, Peter Julian; Houston, Jack E.; Crozier, Paul Stewart; Criscenti, Louise Jacqueline; Chen, Zhu; Zhu, Xiaoyang; Dunphy, Darren Robert; Orendorff, Christopher J.; Pless, Jason D.; Daemen, Luke L.; Gerung, Henry; Ockwig, Nathan W.; Nenoff, Tina Maria; Jiang, Ying-Bing; Stevens, Mark Jackson

    2008-09-01

    A molecular-scale interpretation of interfacial processes is often downplayed in the analysis of traditional water treatment methods. However, such an approach is critical for the development of enhanced performance in traditional desalination and water treatments. Water confined between surfaces, within channels, or in pores is ubiquitous in technology and nature. Its physical and chemical properties in such environments are unpredictably different from bulk water. As a result, advances in water desalination and purification methods may be accomplished through an improved analysis of water behavior in these challenging environments using state-of-the-art microscopy, spectroscopy, experimental, and computational methods.

  12. Multifunctional thin film surface

    DOE Patents [OSTI]

    Brozik, Susan M.; Harper, Jason C.; Polsky, Ronen; Wheeler, David R.; Arango, Dulce C.; Dirk, Shawn M.

    2015-10-13

    A thin film with multiple binding functionality can be prepared on an electrode surface via consecutive electroreduction of two or more aryl-onium salts with different functional groups. This versatile and simple method for forming multifunctional surfaces provides an effective means for immobilization of diverse molecules at close proximities. The multifunctional thin film has applications in bioelectronics, molecular electronics, clinical diagnostics, and chemical and biological sensing.

  13. Handsfree Surface Analysis

    Energy Science and Technology Software Center (OSTI)

    2006-11-01

    The HANDSFREE SURFACE ANALYSIS software code enables unattended analysis of surfaces by desorption electrospray (DESI) and liquid-junction surface sampling probe (SSP) mass spectrometry. The software allows automated lane scanning, imaging (e.g. lane rastering), spot and array sampling, and array scanning methods by controlling the movement of the sample attached to a computer-controlled stage. The software is able to collect, visualize and analyze mass spectrometry data real-time for surface analysis purposes by interacting with mass spectrometrymore » instrumentation software. The software also enables data post processing for imaging and other analytical purposes. The software also contains image analysis approaches to control the sampling capillary-to-surface distance when used with DESI, and for automated formation and real-time reoptimization of the sampling probe-to-surface liquid microjunction when used with SSP. Control of these distances is essential to automated, hands-free operation of a DESI or SSP mass spectrometry system.« less

  14. Clean Water Act Section 401 Water Quality Certification: A Water...

    Open Energy Info (EERE)

    Certification: A Water Quality Protection Tool for States and Tribes Jump to: navigation, search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - Guide...

  15. Clean Water Act Section 401 Water Quality Certification A Water...

    Open Energy Info (EERE)

    Certification A Water Quality Protection Tool for States and Tribes Jump to: navigation, search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - Guide...

  16. Sandia Energy Water Security

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    doe-eere-technologist-in-residence-pilotfeed 0 Sandia Team Attends World Water Week in Stockholm http:energy.sandia.govsandia-team-attends-world-water-week-in-sto...

  17. Heat Pump Water Heaters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & Events Expand News & Events Skip navigation links Residential Residential Lighting Energy Star Appliances Consumer Electronics Heat Pump Water Heaters Electric Storage Water...

  18. Electric Storage Water Heaters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & Events Expand News & Events Skip navigation links Residential Residential Lighting Energy Star Appliances Consumer Electronics Heat Pump Water Heaters Electric Storage Water...

  19. Residential Absorption Water Heater

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Residential Absorption Water Heater 2014 Building Technologies Office Peer Review Kyle ... Target MarketAudience: Residential gas water heating Key Partners: GE CRADA partner SRA ...

  20. Bioenergy Impacts … Water

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    biofuel production on water quality and quantity, and determine which biofuel crops are best suited to different geographic locations. Biofuel research is enabling wise water use

  1. Surface Treatment And Protection Method For Cadium Zinc Telluride Crystals

    DOE Patents [OSTI]

    Wright, Gomez W.; James, Ralph B.; Burger, Arnold; Chinn, Douglas A.

    2006-02-21

    A method for treatment of the surface of a CdZnTe (CZT) crystal that provides a native dielectric coating to reduce surface leakage currents and thereby, improve the resolution of instruments incorporating detectors using CZT crystals. A two step process is disclosed, etching the surface of a CZT crystal with a solution of the conventional bromine/methanol etch treatment, and after attachment of electrical contacts, passivating the CZT crystal surface with a solution of 10 w/o NH4F and 10 w/o H2O2 in water.

  2. Surface treatment and protection method for cadmium zinc telluride crystals

    DOE Patents [OSTI]

    Wright, Gomez W.; James, Ralph B.; Burger, Arnold; Chinn, Douglas A.

    2003-01-01

    A method for treatment of the surface of a CdZnTe (CZT) crystal that provides a native dielectric coating to reduce surface leakage currents and thereby, improve the resolution of instruments incorporating detectors using CZT crystals. A two step process is disclosed, etching the surface of a CZT crystal with a solution of the conventional bromine/methanol etch treatment, and after attachment of electrical contacts, passivating the CZT crystal surface with a solution of 10 w/o NH.sub.4 F and 10 w/o H.sub.2 O.sub.2 in water.

  3. Large Scale Ice Water Path and 3-D Ice Water Content

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Liu, Guosheng

    2008-01-15

    Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM program. In addition to the vertical profiles of temperature, water vapor and condensed water at the model grids, large-scale horizontal advective tendencies of these variables are also required as forcing terms in the single-column models. Observed horizontal advection of condensed water has not been available because the radar/lidar/radiometer observations at the ARM site are single-point measurement, therefore, do not provide horizontal distribution of condensed water. The intention of this product is to provide large-scale distribution of cloud ice water by merging available surface and satellite measurements. The satellite cloud ice water algorithm uses ARM ground-based measurements as baseline, produces datasets for 3-D cloud ice water distributions in a 10 deg x 10 deg area near ARM site. The approach of the study is to expand a (surface) point measurement to an (satellite) areal measurement. That is, this study takes the advantage of the high quality cloud measurements at the point of ARM site. We use the cloud characteristics derived from the point measurement to guide/constrain satellite retrieval, then use the satellite algorithm to derive the cloud ice water distributions within an area, i.e., 10 deg x 10 deg centered at ARM site.

  4. Large Scale Ice Water Path and 3-D Ice Water Content

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Liu, Guosheng

    Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM program. In addition to the vertical profiles of temperature, water vapor and condensed water at the model grids, large-scale horizontal advective tendencies of these variables are also required as forcing terms in the single-column models. Observed horizontal advection of condensed water has not been available because the radar/lidar/radiometer observations at the ARM site are single-point measurement, therefore, do not provide horizontal distribution of condensed water. The intention of this product is to provide large-scale distribution of cloud ice water by merging available surface and satellite measurements. The satellite cloud ice water algorithm uses ARM ground-based measurements as baseline, produces datasets for 3-D cloud ice water distributions in a 10 deg x 10 deg area near ARM site. The approach of the study is to expand a (surface) point measurement to an (satellite) areal measurement. That is, this study takes the advantage of the high quality cloud measurements at the point of ARM site. We use the cloud characteristics derived from the point measurement to guide/constrain satellite retrieval, then use the satellite algorithm to derive the cloud ice water distributions within an area, i.e., 10 deg x 10 deg centered at ARM site.

  5. Water-heating dehumidifier

    DOE Patents [OSTI]

    Tomlinson, John J.

    2006-04-18

    A water-heating dehumidifier includes a refrigerant loop including a compressor, at least one condenser, an expansion device and an evaporator including an evaporator fan. The condenser includes a water inlet and a water outlet for flowing water therethrough or proximate thereto, or is affixed to the tank or immersed into the tank to effect water heating without flowing water. The immersed condenser design includes a self-insulated capillary tube expansion device for simplicity and high efficiency. In a water heating mode air is drawn by the evaporator fan across the evaporator to produce cooled and dehumidified air and heat taken from the air is absorbed by the refrigerant at the evaporator and is pumped to the condenser, where water is heated. When the tank of water heater is full of hot water or a humidistat set point is reached, the water-heating dehumidifier can switch to run as a dehumidifier.

  6. Geochemistry Of Waters In The Valley Of Ten Thousand Smokes Region...

    Open Energy Info (EERE)

    tuff lens deep in the 1912 ash-flow sheet of the upper River Lethe area. Bicarbonate-sulfate waters resulting from interaction of near-surface waters and the cooling 1953-1968...

  7. Microsoft Word - 2014_1Qtr_Water_Protection_010914.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EP2014-0002 LA-UR-14-20093 Groundwater Protection Surface Water Protection LANL Water Protection Status Report - Fiscal Year 2014 First Quarter (October to December 2013) * An...

  8. Far-infrared surface emissivity and climate

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Feldman, Daniel R.; Collins, William D.; Pincus, Robert; Huang, Xianglei; Chen, Xiuhong

    2014-11-03

    Presently, there are no global measurement constraints on the surface emissivity at wavelengths longer than 15 μm, even though this surface property in this far-IR region has a direct impact on the outgoing longwave radiation (OLR) and infrared cooling rates where the column precipitable water vapor (PWV) is less than 1 mm. Such dry conditions are common for high-altitude and high-latitude locations, with the potential for modeled climate to be impacted by uncertain surface characteristics. This paper explores the sensitivity of instantaneous OLR and cooling rates to changes in far-IR surface emissivity and how this unconstrained property impacts climate modelmore » projections. At high latitudes and altitudes, a 0.05 change in emissivity due to mineralogy and snow grain size can cause a 1.8–2.0 W m⁻² difference in the instantaneous clear-sky OLR. A variety of radiative transfer techniques have been used to model the far-IR spectral emissivities of surface types defined by the International Geosphere-Biosphere Program. Incorporating these far-IR surface emissivities into the Representative Concentration Pathway (RCP) 8.5 scenario of the Community Earth System Model leads to discernible changes in the spatial patterns of surface temperature, OLR, and frozen surface extent. The model results differ at high latitudes by as much as 2°K, 10 W m⁻², and 15%, respectively, after only 25 y of integration. The calculated difference in far-IR emissivity between ocean and sea ice of between 0.1 and 0.2, suggests the potential for a far-IR positive feedback for polar climate change.« less

  9. Far-infrared surface emissivity and climate

    SciTech Connect (OSTI)

    Feldman, Daniel R.; Collins, William D.; Pincus, Robert; Huang, Xianglei; Chen, Xiuhong

    2014-11-03

    Presently, there are no global measurement constraints on the surface emissivity at wavelengths longer than 15 ?m, even though this surface property in this far-IR region has a direct impact on the outgoing longwave radiation (OLR) and infrared cooling rates where the column precipitable water vapor (PWV) is less than 1 mm. Such dry conditions are common for high-altitude and high-latitude locations, with the potential for modeled climate to be impacted by uncertain surface characteristics. This paper explores the sensitivity of instantaneous OLR and cooling rates to changes in far-IR surface emissivity and how this unconstrained property impacts climate model projections. At high latitudes and altitudes, a 0.05 change in emissivity due to mineralogy and snow grain size can cause a 1.82.0 W m? difference in the instantaneous clear-sky OLR. A variety of radiative transfer techniques have been used to model the far-IR spectral emissivities of surface types defined by the International Geosphere-Biosphere Program. Incorporating these far-IR surface emissivities into the Representative Concentration Pathway (RCP) 8.5 scenario of the Community Earth System Model leads to discernible changes in the spatial patterns of surface temperature, OLR, and frozen surface extent. The model results differ at high latitudes by as much as 2K, 10 W m?, and 15%, respectively, after only 25 y of integration. The calculated difference in far-IR emissivity between ocean and sea ice of between 0.1 and 0.2, suggests the potential for a far-IR positive feedback for polar climate change.

  10. Dual surface interferometer

    DOE Patents [OSTI]

    Pardue, R.M.; Williams, R.R.

    1980-09-12

    A double-pass interferometer is provided which allows direct measurement of relative displacement between opposed surfaces. A conventional plane mirror interferometer may be modified by replacing the beam-measuring path cube-corner reflector with an additional quarterwave plate. The beam path is altered to extend to an opposed plane mirrored surface and the reflected beam is placed in interference with a retained reference beam split from dual-beam source and retroreflected by a reference cube-corner reflector mounted stationary with the interferometer housing. This permits direct measurement of opposed mirror surfaces by laser interferometry while doubling the resolution as with a conventional double-pass plane mirror laser interferometer system.

  11. Water-Gas Samples At Fenton Hill Hdr Geothermal Area (Goff &...

    Open Energy Info (EERE)

    Water-Gas Samples At Fenton Hill Hdr Geothermal Area (Goff & Janik, 2002) Redirect page Jump to: navigation, search REDIRECT Surface Gas Sampling At Fenton Hill Hdr Geothermal...

  12. Chemical analyses and preliminary interpretation of waters collected...

    Open Energy Info (EERE)

    system appears to be a hot water type. The surface expression of fumarole and acid sulfate pools and shallow steam wells gives a false indication of an extensive vapor...

  13. Compliant layer chucking surface

    DOE Patents [OSTI]

    Blaedel, Kenneth L. (Dublin, CA); Spence, Paul A. (Pleasanton, CA); Thompson, Samuel L. (Pleasanton, CA)

    2004-12-28

    A method and apparatus are described wherein a thin layer of complaint material is deposited on the surface of a chuck to mitigate the deformation that an entrapped particle might cause in the part, such as a mask or a wafer, that is clamped to the chuck. The harder particle will embed into the softer layer as the clamping pressure is applied. The material composing the thin layer could be a metal or a polymer for vacuum or electrostatic chucks. It may be deposited in various patterns to affect an interrupted surface, such as that of a "pin" chuck, thereby reducing the probability of entrapping a particle.

  14. Surface controlled blade stabilizer

    DOE Patents [OSTI]

    Russell, Larry R. (6025 Edgemor, Suite C, Houston, TX 77081)

    1983-01-01

    Drill string stabilizer apparatus, controllable to expand and retract entirely from the surface by control of drill string pressure, wherein increase of drill string pressure from the surface closes a valve to create a piston means which is moved down by drill string pressure to expand the stabilizer blades, said valve being opened and the piston moving upward upon reduction of drill string pressure to retract the stabilizer blades. Upward and downward movements of the piston and an actuator sleeve therebelow are controlled by a barrel cam acting between the housing and the actuator sleeve.

  15. ARM - Measurement - Ice water path

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    path ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Ice water path A measure of the weight of the ice particles in the atmosphere above a unit surface area in kg m-2. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements,

  16. Surface Tension Estimates for Droplet Formation in Slurries with Low Concentrations of Hydrophobic Particles, Polymer Flocculants or Surface-Active Contaminants

    SciTech Connect (OSTI)

    Gauglitz, Phillip A.; Mahoney, Lenna A.; Blanchard, Jeremy; Bamberger, Judith A.

    2011-06-10

    In support of the K-Basin project, Pacific Northwest National Laboratory (PNNL) was requested to evaluate the appropriate surface tension value to use in models predicting the formation of droplets from spray leaks of K-Basin slurries. The specific issue was whether it was more appropriate to use the surface tension of pure water in model predictions for all plausible spray leaks or to use a lower value. The surface tension of K-Basin slurries is potentially affected not only by particles but by low concentrations of nonionic polyacrylamide flocculant and perhaps by contaminants with surfactant properties, which could decrease the surface tension below that of water. A lower surface tension value typically results in smaller droplets being formed with a larger fraction of droplets in the respirable size range, so using the higher surface tension value of pure water is not conservative and thus needs a strong technical basis.

  17. Fluid Dynamics with Free Surfaces

    Energy Science and Technology Software Center (OSTI)

    1992-02-01

    RIPPLE is a two-dimensional, transient, free surface incompressible fluid dynamics program. It allows multiple free surfaces with surface tension and wall adhesion forces and has a partial cell treatment which allows curved boundaries and interior obstacles.

  18. Water Distribution and Removal Model

    SciTech Connect (OSTI)

    Y. Deng; N. Chipman; E.L. Hardin

    2005-08-26

    The design of the Yucca Mountain high level radioactive waste repository depends on the performance of the engineered barrier system (EBS). To support the total system performance assessment (TSPA), the Engineered Barrier System Degradation, Flow, and Transport Process Model Report (EBS PMR) is developed to describe the thermal, mechanical, chemical, hydrological, biological, and radionuclide transport processes within the emplacement drifts, which includes the following major analysis/model reports (AMRs): (1) EBS Water Distribution and Removal (WD&R) Model; (2) EBS Physical and Chemical Environment (P&CE) Model; (3) EBS Radionuclide Transport (EBS RNT) Model; and (4) EBS Multiscale Thermohydrologic (TH) Model. Technical information, including data, analyses, models, software, and supporting documents will be provided to defend the applicability of these models for their intended purpose of evaluating the postclosure performance of the Yucca Mountain repository system. The WD&R model ARM is important to the site recommendation. Water distribution and removal represents one component of the overall EBS. Under some conditions, liquid water will seep into emplacement drifts through fractures in the host rock and move generally downward, potentially contacting waste packages. After waste packages are breached by corrosion, some of this seepage water will contact the waste, dissolve or suspend radionuclides, and ultimately carry radionuclides through the EBS to the near-field host rock. Lateral diversion of liquid water within the drift will occur at the inner drift surface, and more significantly from the operation of engineered structures such as drip shields and the outer surface of waste packages. If most of the seepage flux can be diverted laterally and removed from the drifts before contacting the wastes, the release of radionuclides from the EBS can be controlled, resulting in a proportional reduction in dose release at the accessible environment. The purposes of this WD&R model (CRWMS M&O 2000b) are to quantify and evaluate the distribution and drainage of seepage water within emplacement drifts during the period of compliance for post-closure performance. The model bounds the fraction of water entering the drift that will be prevented from contacting the waste by the combined effects of engineered controls on water distribution and on water removal. For example, water can be removed during pre-closure operation by ventilation and after closure by natural drainage into the fractured rock. Engineered drains could be used, if demonstrated to be necessary and effective, to ensure that adequate drainage capacity is provided. This report provides the screening arguments for certain Features, Events, and Processes (FEPs) that are related to water distribution and removal in the EBS. Applicable acceptance criteria from the Issue Resolution Status Reports (IRSRs) developed by the U.S. Nuclear Regulatory Commission (NRC 1999a; 1999b; 1999c; and 1999d) are also addressed in this document.

  19. Ground water and energy

    SciTech Connect (OSTI)

    Not Available

    1980-11-01

    This national workshop on ground water and energy was conceived by the US Department of Energy's Office of Environmental Assessments. Generally, OEA needed to know what data are available on ground water, what information is still needed, and how DOE can best utilize what has already been learned. The workshop focussed on three areas: (1) ground water supply; (2) conflicts and barriers to ground water use; and (3) alternatives or solutions to the various issues relating to ground water. (ACR)

  20. Energy-Water Overview

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Emerging Issues and Challenges DOE/EIA 2010 Energy Conference Mike Hightower Sandia National Laboratories mmhight@sandia.gov, 505-844-5499 Energy and Water are ... Interdependent Water for Energy and Energy for Water Energy and power production require water: * Thermoelectric cooling * Hydropower * Energy minerals extraction/mining * Fuel Production (fossil fuels, H 2 , biofuels) * Emission control Water production, processing, distribution, and end-use require energy: * Pumping * Conveyance and

  1. Decontaminating metal surfaces

    DOE Patents [OSTI]

    Childs, E.L.

    1984-01-23

    Radioactively contaminated surfaces can be electrolytically decontaminated with greatly increased efficiencies by using electrolytes containing higher than heretofore conventional amounts of nitrate, e.g., >600 g/1 of NaNO/sub 3/, or by using nitrate-containing electrolytes which are acidic, e.g., of a pH < 6.

  2. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Large Magnetization at Carbon Surfaces Print Wednesday, 31 August 2011 00:00 From organic matter to pencil lead, carbon is a versatile...

  3. Natural radionuclides in Hanford site ground waters

    SciTech Connect (OSTI)

    Smith, M.R.; Laul, J.C.; Johnson, V.G.

    1987-10-01

    Uranium, Th, Ra, Rn, Pb and Po radionuclide concentrations in ground waters from the Hanford Site indicate that U, Th, and Ra are highly sorbed. Relative to Rn, these radionuclides are low by factors of 10/sup -3/ to 10/sup -6/. Uranium sorption is likely due to its reduction from the +6 state, where it is introduced via surface waters, to the +4 state found in the confined aquifers. The distribution of radionuclides is very similar in all of the confined aquifers and significantly different from the distribution observed in the unconfined and surface waters. Barium correlates well with Ra over three orders of magnitude, indicating that stable element analogs may be useful for inferring the behavior of radioactive waste radionuclides in this candidate geologic repository. 8 refs., 7 figs., 1 tab.

  4. Fruition and greater struggle: water pollution in the 1980s

    SciTech Connect (OSTI)

    Harris, R.H.

    1980-01-01

    Examples of the elimination or reduction of pollution in lakes and rivers during recent years are given. A shift in emphasis from visible to nonvisible chemical pollution of surface waters was the result of release of the report on the EPA study on New Orleans drinking water in 1974. Passage of the Safe Drinking Water Act followed. Toxic chemicals in drinking water result from two primary sources: accidental or purposeful discharge and efforts to purify water through chlorination. Evidence is given as to the serious nature of the problem. (JGB)

  5. Reactor water cleanup system

    DOE Patents [OSTI]

    Gluntz, D.M.; Taft, W.E.

    1994-12-20

    A reactor water cleanup system includes a reactor pressure vessel containing a reactor core submerged in reactor water. First and second parallel cleanup trains are provided for extracting portions of the reactor water from the pressure vessel, cleaning the extracted water, and returning the cleaned water to the pressure vessel. Each of the cleanup trains includes a heat exchanger for cooling the reactor water, and a cleaner for cleaning the cooled reactor water. A return line is disposed between the cleaner and the pressure vessel for channeling the cleaned water thereto in a first mode of operation. A portion of the cooled water is bypassed around the cleaner during a second mode of operation and returned through the pressure vessel for shutdown cooling. 1 figure.

  6. Reactor water cleanup system

    DOE Patents [OSTI]

    Gluntz, Douglas M.; Taft, William E.

    1994-01-01

    A reactor water cleanup system includes a reactor pressure vessel containing a reactor core submerged in reactor water. First and second parallel cleanup trains are provided for extracting portions of the reactor water from the pressure vessel, cleaning the extracted water, and returning the cleaned water to the pressure vessel. Each of the cleanup trains includes a heat exchanger for cooling the reactor water, and a cleaner for cleaning the cooled reactor water. A return line is disposed between the cleaner and the pressure vessel for channeling the cleaned water thereto in a first mode of operation. A portion of the cooled water is bypassed around the cleaner during a second mode of operation and returned through the pressure vessel for shutdown cooling.

  7. Nonhazardous solvent composition and method for cleaning metal surfaces

    DOE Patents [OSTI]

    Googin, John M.; Simandl, Ronald F.; Thompson, Lisa M.

    1993-01-01

    A solvent composition for displacing greasy and oily contaminants as well as water and/or aqueous residue from metallic surfaces, especially surfaces of radioactive materials so that such surfaces can be wiped clean of the displaced contaminants, water and/or aqueous residue. The solvent composition consists essentially of a blend of nonpolar aliphatic hydrocarbon solvent having a minimum flash point of about 140.degree. F. and 2 to 25 volume percent of a polar solvent having a flash point sufficiently high so as to provide the solvent composition with a minimum flash point of at least 140.degree. F. The solvent composition is nonhazardous so that when it is used to clean the surfaces of radioactive materials the waste in the form of paper or cloth wipes, lab coats and the like used in the cleaning operation is not considered to be mixed waste composed of a hazardous solvent and a radioactive material.

  8. Nonhazardous solvent composition and method for cleaning metal surfaces

    DOE Patents [OSTI]

    Googin, J.M.; Simandl, R.F.; Thompson, L.M.

    1993-05-04

    A solvent composition for displacing greasy and oily contaminants as well as water and/or aqueous residue from metallic surfaces, especially surfaces of radioactive materials so that such surfaces can be wiped clean of the displaced contaminants, water and/or aqueous residue. The solvent composition consists essentially of a blend of nonpolar aliphatic hydrocarbon solvent having a minimum flash point of about 140 F and 2 to 25 volume percent of a polar solvent having a flash point sufficiently high so as to provide the solvent composition with a minimum flash point of at least 140 F. The solvent composition is nonhazardous so that when it is used to clean the surfaces of radioactive materials the waste in the form of paper or cloth wipes, lab coats and the like used in the cleaning operation is not considered to be mixed waste composed of a hazardous solvent and a radioactive material.

  9. UMTRA water sampling and analysis plan, Green River, Utah

    SciTech Connect (OSTI)

    Papusch, R.

    1993-12-01

    The purpose of this water sampling and analysis plan (WSAP) is to provide a basis for groundwater and surface water sampling at the Green River Uranium Mill Tailing Remedial Action (UMTRA) Project site. This WSAP identifies and justifies the sampling locations, analytical parameters, detection limits, and sampling frequency for the monitoring locations.

  10. ARM Water Vapor IOP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM Water Vapor IOP The SGP CART site will host the third ARM water vapor IOP on September 18-October 8, 2000. The CART site is home to a powerful array of instruments capable of measuring water vapor, making it a prime location for research of this type. The first water vapor IOP, conducted in September 1996, focused on using instruments to measure water vapor and determining the accuracy and calibration of each instrument. The second water vapor IOP, held in September and October of 1997,

  11. ARM - Measurement - Precipitable water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govMeasurementsPrecipitable water ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Precipitable water Total amount of water vapor in a vertical column of air, often expressed as the depth of the layer of water that would be formed if all the water vapor were condensed to liquid water. Categories Atmospheric State Instruments The above measurement is considered scientifically relevant for the following

  12. Radionuclide Sensors for Water Monitoring

    SciTech Connect (OSTI)

    Grate, Jay W.; Egorov, Oleg B.; DeVol, Timothy A.

    2004-06-29

    Radionuclide contamination in the soil and groundwater at U.S. Department of Energy (DOE) sites is a severe problem that requires monitoring and remediation. Radionuclide measurement techniques are needed to monitor surface waters, groundwater, and process waters. Typically, water samples are collected and transported to an analytical laboratory, where costly radiochemical analyses are performed. To date, there has been very little development of selective radionuclide sensors for alpha- and beta-emitting radionuclides such as 90Sr, 99Tc, and various actinides of interest. The objective of this project is to investigate novel sensor concepts and materials for sensitive and selective determination of beta- and alpha-emitting radionuclide contaminants in water. To meet the requirements for low-level, isotope-specific detection, the proposed sensors are based on radiometric detection. As a means to address the fundamental challenge of the short ranges of beta and alpha particle s in water, our overall approach is based on localization of preconcentration/separation chemistries directly on or within the active area of a radioactivity detector. Automated microfluidics is used for sample manipulation and sensor regeneration or renewal. The outcome of these investigations will be the knowledge necessary to choose appropriate chemistries for selective preconcentration of radionuclides from environmental samples, new materials that combine chemical selectivity with scintillating properties, new materials that add chemical selectivity to solid-state diode detectors, new preconcentrating column sensors, and improved instrumentation and signal processing for selective radionuclide sensors. New knowledge will provide the basis for designing effective probes and instrumentation for field and in situ measurements.

  13. Sensor for detection of liquid spills on surfaces

    DOE Patents [OSTI]

    Davis, Brent C. (Oak Ridge, TN); Gayle, Tom M. (Oak Ridge, TN)

    1989-01-01

    A surface liquid detector is disclosed for detecting liquids spilled on surfaces such as floors. A temperature-sensitive thermistor probe is used in a bridge circuit to detect the change in resistance in the thermistor due to the change in thermal conductivity that occurs when a liquid contacts the probe. The device is characterized by the ability to detect either conductive or nonconductive liquids, such as water or oil spills.

  14. Corrosion protection of steel in ammonia/water heat pumps

    DOE Patents [OSTI]

    Mansfeld, Florian B.; Sun, Zhaoli

    2003-10-14

    Corrosion of steel surfaces in a heat pump is inhibited by adding a rare earth metal salt to the heat pump's ammonia/water working fluid. In preferred embodiments, the rare earth metal salt includes cerium, and the steel surfaces are cerated to enhance the corrosion-inhibiting effects.

  15. Pocked surface neutron detector

    DOE Patents [OSTI]

    McGregor, Douglas; Klann, Raymond

    2003-04-08

    The detection efficiency, or sensitivity, of a neutron detector material such as of Si, SiC, amorphous Si, GaAs, or diamond is substantially increased by forming one or more cavities, or holes, in its surface. A neutron reactive material such as of elemental, or any compound of, .sup.10 B, .sup.6 Li, .sup.6 LiF, U, or Gd is deposited on the surface of the detector material so as to be disposed within the cavities therein. The portions of the neutron reactive material extending into the detector material substantially increase the probability of an energetic neutron reaction product in the form of a charged particle being directed into and detected by the neutron detector material.

  16. Smart, passive sun facing surfaces

    DOE Patents [OSTI]

    Hively, L.M.

    1996-04-30

    An article adapted for selectively utilizing solar radiation comprises an absorptive surface and a reflective surface, the absorptive surface and the reflective surface oriented to absorb solar radiation when the sun is in a relatively low position, and to reflect solar radiation when the sun is in a relatively high position. 17 figs.

  17. Surface decontamination compositions and methods

    DOE Patents [OSTI]

    Wright; Karen E.; Cooper, David C.; Peterman, Dean R.; Demmer, Ricky L.; Tripp, Julia L.; Hull, Laurence C.

    2011-03-29

    Clay-based compositions capable of absorbing contaminants from surfaces or objects having surface faces may be applied to a surface and later removed, the removed clay-based compositions absorbing at least a portion of the contaminant from the surface or object to which it was applied.

  18. Smart, passive sun facing surfaces

    DOE Patents [OSTI]

    Hively, Lee M. (Knoxville, TN)

    1996-01-01

    An article adapted for selectively utilizing solar radiation comprises an absorptive surface and a reflective surface, the absorptive surface and the reflective surface oriented to absorb solar radiation when the sun is in a relatively low position, and to reflect solar radiation when the sun is in a relatively high position.

  19. Deep subsurface drip irrigation using coal-bed sodic water: Part I. Water and solute movement

    SciTech Connect (OSTI)

    Bern, Carleton R.; Breit, George N.; Healy, Richard W.; Zupancic, John W.; Hammack, Richard

    2013-02-01

    Water co-produced with coal-bed methane (CBM) in the semi-arid Powder River Basin of Wyoming and Montana commonly has relatively low salinity and high sodium adsorption ratios that can degrade soil permeability where used for irrigation. Nevertheless, a desire to derive beneficial use from the water and a need to dispose of large volumes of it have motivated the design of a deep subsurface drip irrigation (SDI) system capable of utilizing that water. Drip tubing is buried 92 cm deep and irrigates at a relatively constant rate year-round, while evapotranspiration by the alfalfa and grass crops grown is seasonal. We use field data from two sites and computer simulations of unsaturated flow to understand water and solute movements in the SDI fields. Combined irrigation and precipitation exceed potential evapotranspiration by 300480 mm annually. Initially, excess water contributes to increased storage in the unsaturated zone, and then drainage causes cyclical rises in the water table beneath the fields. Native chloride and nitrate below 200 cm depth are leached by the drainage. Some CBM water moves upward from the drip tubing, drawn by drier conditions above. Chloride from CBM water accumulates there as root uptake removes the water. Year over year accumulations indicated by computer simulations illustrate that infiltration of precipitation water from the surface only partially leaches such accumulations away. Field data show that 7% and 27% of added chloride has accumulated above the drip tubing in an alfalfa and grass field, respectively, following 6 years of irrigation. Maximum chloride concentrations in the alfalfa field are around 45 cm depth but reach the surface in parts of the grass field, illustrating differences driven by crop physiology. Deep SDI offers a means of utilizing marginal quality irrigation waters and managing the accumulation of their associated solutes in the crop rooting zone.

  20. Surface profiling interferometer

    DOE Patents [OSTI]

    Takacs, Peter Z. (P.O. Box 385, Upton, NY 11973); Qian, Shi-Nan (Hefei Synchrotron Radiation Laboratory, University of Science and, Hefei, Anhui, CN)

    1989-01-01

    The design of a long-trace surface profiler for the non-contact measurement of surface profile, slope error and curvature on cylindrical synchrotron radiation (SR) mirrors. The optical system is based upon the concept of a pencil-beam interferometer with an inherent large depth-of-field. The key feature of the optical system is the zero-path-difference beam splitter, which separates the laser beam into two colinear, variable-separation probe beams. A linear array detector is used to record the interference fringe in the image, and analysis of the fringe location as a function of scan position allows one to reconstruct the surface profile. The optical head is mounted on an air bearing slide with the capability to measure long aspheric optics, typical of those encountered in SR applications. A novel feature of the optical system is the use of a transverse "outrigger" beam which provides information on the relative alignment of the scan axis to the cylinder optic symmetry axis.

  1. Transport diffusion of liquid water and methanol through membranes (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Transport diffusion of liquid water and methanol through membranes Citation Details In-Document Search Title: Transport diffusion of liquid water and methanol through membranes The authors carried out dual-control-volume grand canonical molecular dynamics simulations of the transport diffusion of liquid water and methanol to vacuum under a fixed chemical potential gradient through a slit pore consisting of Au(111) surfaces covered by -CH{sub 3} and -OH terminated

  2. Investigating the Quartz (1010)/Water Interface using Classical and

    SciTech Connect (OSTI)

    Skelton, A A; Wesolowski, David J; Cummings, Peter T

    2011-01-01

    Two different terminations of the (1010) surface of quartz (R and ) interacting with water are simulated by classical (CMD) (using two different force fields) and ab initio molecular dynamics (AIMD) and compared with previously published X-ray reflectivity (XR) experiments. Radial distribution functions between hydroxyl and water show good agreement between AIMD and CMDusing the ClayFF force field for both terminations. The Lopes et al. (Lopes, P. E. M.; Murashov, V.; Tazi, M.; Demchuk, E.; MacKerell, A. D. J. Phys. Chem. B 2006, 110, 27822792) force field (LFF), however, underestimates the extent of hydroxylwater hydrogen bonding. The termination is found to contain hydroxylhydroxyl hydrogen bonds; the quartz surface hydroxyl hydrogens and oxygens that hydrogen bond with each other exhibit greatly reduced hydrogen bonding to water. Conversely, the hydroxyl hydrogen and oxygens that are not hydrogen bonded to other surface hydroxyls but are connected to those that are show a considerable amount of hydrogen bonding to water. The electron density distribution of an annealed surface of quartz (1010) obtained by XR is in qualitative agreement with electron densities calculated byCMDand AIMD. In all simulation methods, the interfacial water peak appears farther from the surface than observed by XR. Agreement among AIMD, LFF, and XR is observed for the relaxation of the near-surface atoms; however, ClayFF shows a larger discrepancy. Overall, results show that for both terminations of (1010), LFF treats the near-surface structure more accurately whereas ClayFF treats the interfacial water structure more accurately. It is shown that the number of hydroxyl and water hydrogen bonds to the bridging SiOSi oxygens connecting the surface silica groups to the rest of the crystal is much greater for the R than the termination. It is suggested that this may play a role in the greater resistance to dissolution of the termination than that of the R termination.

  3. Apparatus for removing oil and other floating contaminants from a moving body of water

    DOE Patents [OSTI]

    Strohecker, J.W.

    1973-12-18

    The patent describes a process in which floating contaminants such as oil and solid debris are removed from a moving body of water by employing a skimming system which uses the natural gravitational flow of the water. A boom diagonally positioned across the body of water diverts the floating contaminants over a floating weir and into a retention pond where an underflow weir is used to return contaminant-free water to the moving body of water. The floating weir is ballasted to maintain the contaminant-receiving opening therein slightly below the surface of the water during fluctuations in the water level for skimming the contaminants with minimal water removal.

  4. Buildings Energy Data Book: 8.2 Residential Sector Water Consumption

    Buildings Energy Data Book [EERE]

    1 Residential Water Use by Source (Million Gallons per Day) Year 1980 3,400 1985 3,320 1990 3,390 1995 3,390 2000 (3) (3) 3,590 2005 3,830 Note(s): Source(s): 29,430 25,600 1) Public supply water use: water withdrawn by public and private water suppliers that furnish water to at least 25 people or have a minimum of 15 connections. 2) Self-supply water use: Water withdrawn from a groundwater or surface-water source by a user rather than being obtained from a public supply. 3) USGS did not provide

  5. Federal Water Use Indices

    Broader source: Energy.gov [DOE]

    FEMP provides water use indices as a guide for Federal agencies. Note that each is a rough estimate of water usage at different types of sites. Your site may vary considerably.

  6. NDN Water Summit 2015

    Broader source: Energy.gov [DOE]

    The NDN Water Summit is a two-day summit to build tribal executive capacity through a strategic series of forums, events, and sharing of documentation and experiences. Speakers will cover topics on water policy, climate change, and more.

  7. Indian Water 2015

    Office of Energy Efficiency and Renewable Energy (EERE)

    Indian Water is a call to help plan a national water summit. This strategic session consist of a facilitated dialog with tribal leaders on important opportunities, challenges and tactics, which...

  8. Electrolysis of Water

    K-12 Energy Lesson Plans and Activities Web site (EERE)

    Students observe the electrolysis of water using either photovoltaics or a battery as the electric energy source.

  9. Water | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water The Energy Sector withdraws more freshwater than any other sector in the United States The Energy Sector withdraws more freshwater than any other sector in the United States Significant opportunities are emerging in the public and private sector to tackle water stewardship: the U.S. Department of Energy has identified the energy-water nexus as an emerging activity that require substantial R&D investment in the coming years, and DOE's Water Energy Nexus report has identified reclaimed

  10. ARM - Water Vapor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Vapor Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Water Vapor Water vapor is the most effective, fastest changing, and least understood of the greenhouse gases. Water vapor is a powerful greenhouse gas; as a matter of fact, it is the dominant greenhouse gas. But scientists don't

  11. Influence of surface contamination on the wettability of heat transfer surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Forrest, Eric Christopher; Schulze, Roland; Liu, Cheng; Dombrowski, David

    2015-08-08

    In this study, the wettability of heat transfer surfaces plays an important role in liquid–vapor phase change phenomena, including boiling incipience, the critical heat flux, the Leidenfrost transition, and condensation. The influence of adsorbed surface contamination at the nanoscale, though seldom considered, can have a profound impact on wetting behavior. This study quantitatively investigates the impact of contaminant layer thickness on wettability. Various cleaning treatments are explored on zirconium and 6061 aluminum to determine the effect on contaminant and oxide layer thickness. Angle-resolved X-ray photoelectron spectroscopy can be used to measure the thickness of oxide and contaminant layers, which ismore » then correlated to wettability by measuring the equilibrium contact angle. Results indicate that even after solvent cleaning, the contact angle of water on practical heat transfer surfaces is dominated by a hydrocarbon contaminant overlayer around five nanometers thick.« less

  12. Comparison of glass surfaces as a countertop material to existing surfaces

    SciTech Connect (OSTI)

    Turo, Laura A.; Winschell, Abigail E.

    2011-09-01

    Gleen Glass, a small production glass company that creates countertops, was selected for the Technology Assistance Program through Pacific Northwest National Laboratory. Gleen Glass was seeking material property analysis comparing glass as a countertop material to current surfaces (i.e. marble, granite and engineered stone). With samples provided from Gleen Glass, testing was done on granite, marble, and 3 different glass surfaces ('Journey,' 'Pebble,' and 'Gleen'). Results showed the glass surfaces have a lower density, lower water absorption, and are stronger in compressive and flexural tests as compared to granite and marble. Thermal shock tests showed the glass failed when objects with a high thermal mass are placed directly on them, whereas marble and granite did not fracture under these conditions.

  13. Influence of surface contamination on the wettability of heat transfer surfaces

    SciTech Connect (OSTI)

    Forrest, Eric Christopher; Schulze, Roland; Liu, Cheng; Dombrowski, David

    2015-08-08

    In this study, the wettability of heat transfer surfaces plays an important role in liquid–vapor phase change phenomena, including boiling incipience, the critical heat flux, the Leidenfrost transition, and condensation. The influence of adsorbed surface contamination at the nanoscale, though seldom considered, can have a profound impact on wetting behavior. This study quantitatively investigates the impact of contaminant layer thickness on wettability. Various cleaning treatments are explored on zirconium and 6061 aluminum to determine the effect on contaminant and oxide layer thickness. Angle-resolved X-ray photoelectron spectroscopy can be used to measure the thickness of oxide and contaminant layers, which is then correlated to wettability by measuring the equilibrium contact angle. Results indicate that even after solvent cleaning, the contact angle of water on practical heat transfer surfaces is dominated by a hydrocarbon contaminant overlayer around five nanometers thick.

  14. THE INTERIOR DYNAMICS OF WATER PLANETS

    SciTech Connect (OSTI)

    Fu, Roger; O'Connell, Richard J.; Sasselov, Dimitar D. E-mail: richard_oconnell@harvard.ed

    2010-01-10

    The ever-expanding catalog of detected super-Earths calls for theoretical studies of their properties in the case of a substantial water layer. This work considers such water planets with a range of masses and water mass fractions (2-5 M{sub Earth}, 0.02%-50% H{sub 2}O). First, we model the thermal and dynamical structure of the near-surface for icy and oceanic surfaces, finding separate regimes where the planet is expected to maintain a subsurface liquid ocean and where it is expected to exhibit ice tectonics. Newly discovered exoplanets may be placed into one of these regimes given estimates of surface temperature, heat flux, and gravity. Second, we construct a parameterized convection model for the underlying ice mantle of higher ice phases, finding that materials released from the silicate-iron core should traverse the ice mantle on the timescale of 0.1 to 100 megayears. We present the dependence of the overturn times of the ice mantle and the planetary radius on total mass and water mass fraction. Finally, we discuss the implications of these internal processes on atmospheric observables.

  15. Energy-Water Nexus

    SciTech Connect (OSTI)

    Horak, W.

    2010-07-26

    Conclusions of this presentation are: (1) energy and water are interconnected; (2) new energy sources will place increased demands on water supplies; (3) existing energy sources will be subjected to increasing restrictions on their water use; and (4) integrated decision support tools will need to be developed to help policy makers decide which policies and advanced technologies can address these issues.

  16. Water treatment method

    DOE Patents [OSTI]

    Martin, F.S.; Silver, G.L.

    1991-04-30

    A method is described for reducing the concentration of any undesirable metals dissolved in contaminated water, such as waste water. The method involves uniformly reacting the contaminated water with an excess amount of solid particulate calcium sulfite to insolubilize the undesirable metal ions, followed by removal thereof and of the unreacted calcium sulfite.

  17. Water treatment method

    DOE Patents [OSTI]

    Martin, Frank S. (Farmersville, OH); Silver, Gary L. (Centerville, OH)

    1991-04-30

    A method for reducing the concentration of any undesirable metals dissolved in contaminated water, such as waste water. The method involves uniformly reacting the contaminated water with an excess amount of solid particulate calcium sulfite to insolubilize the undesirable metal ions, followed by removal thereof and of the unreacted calcium sulfite.

  18. Saving Water Saves Energy

    SciTech Connect (OSTI)

    McMahon, James E.; Whitehead, Camilla Dunham; Biermayer, Peter

    2006-06-15

    Hot water use in households, for showers and baths as wellas for washing clothes and dishes, is a major driver of household energyconsumption. Other household uses of water (such as irrigatinglandscaping) require additional energy in other sectors to transport andtreat the water before use, and to treat wastewater. In California, 19percent of total electricity for all sectors combined and 32 percent ofnatural gas consumption is related to water. There is a criticalinterdependence between energy and water systems: thermal power plantsrequire cooling water, and water pumping and treatment require energy.Energy efficiency can be increased by a number of means, includingmore-efficient appliances (e.g., clothes washers or dishwashers that useless total water and less heated water), water-conserving plumbingfixtures and fittings (e.g., showerheads, faucets, toilets) and changesin consumer behavior (e.g., lower temperature set points for storagewater heaters, shorter showers). Water- and energy-conserving activitiescan help offset the stress imposed on limited water (and energy) suppliesfrom increasing population in some areas, particularly in drought years,or increased consumption (e.g., some new shower systems) as a result ofincreased wealth. This paper explores the connections between householdwater use and energy, and suggests options for increased efficiencies inboth individual technologies and systems. Studies indicate that urbanwater use can be reduced cost-effectively by up to 30 percent withcommercially available products. The energy savings associated with watersavings may represent a large additional and largely untappedcost-effective opportunity.

  19. Water Security Toolkit

    Energy Science and Technology Software Center (OSTI)

    2012-09-11

    The Water Security Toolkit (WST) provides software for modeling and analyzing water distribution systems to minimize the potential impact of contamination incidents. WST wraps capabilities for contaminant transport, impact assessment, and sensor network design with response action plans, including source identification, rerouting, and decontamination, to provide a range of water security planning and real-time applications.

  20. Geotechnical considerations in surface mine reclamation

    SciTech Connect (OSTI)

    Kuhn, A.K.

    1999-07-01

    Most attention in surface mine reclamation is given to agronomic soils and revegetation, but reclamation success depends on the geotechnical characteristics of the underlying earth. If the soil and rock that underline the surface are not stable, surface treatments lack the dependable foundation needed for them to succeed. Reclamation practioners need to understand those geotechnical considerations--material properties, structure, and processes--that affect stability. properties of rock and soil are altered by mining, and those altered materials together with water and processing waste form often-complex mixtures of materials that must be stabilized in reclamation. Surface mining alters existing landforms and creates new ones such as pit walls, spoil and waste rock piles, tailings impoundments, and earthfills. those structures need to be constructed or stabilized so that they can endure and support successful reclamation. processes that affect material properties and landforms include mechanical breakage, accelerated weathering, erosion, and mass movements. Mechanical breakage and the resulting accelerated weathering combine to change material properties, usually expressed as degraded strength, that can lead to instability of landforms. Erosion, especially that related to extreme storm events, and mass movements in the form of slop failures are the most problematic processes that must be taken into account in reclaiming mined lands. These geotechnical considerations are essential in successful reclamation, and practioners who overlook them may find their work literally sliding down a slippery slope.

  1. Laser heterodyne surface profiler

    DOE Patents [OSTI]

    Sommargren, G.E.

    1980-06-16

    A method and apparatus are disclosed for testing the deviation of the face of an object from a flat smooth surface using a beam of coherent light of two plane-polarized components, one of a frequency constantly greater than the other by a fixed amount to produce a difference frequency with a constant phase to be used as a reference, and splitting the beam into its two components. The separate components are directed onto spaced apart points on the face of the object to be tested for smoothness while the face of the object is rotated on an axis normal to one point, thereby passing the other component over a circular track on the face of the object. The two components are recombined after reflection to produce a reflected frequency difference of a phase proportional to the difference in path length of one component reflected from one point to the other component reflected from the other point. The phase of the reflected frequency difference is compared with the reference phase to produce a signal proportional to the deviation of the height of the surface along the circular track with respect to the fixed point at the center, thereby to produce a signal that is plotted as a profile of the surface along the circular track. The phase detector includes a quarter-wave plate to convert the components of the reference beam into circularly polarized components, a half-wave plate to shift the phase of the circularly polarized components, and a polarizer to produce a signal of a shifted phase for comparison with the phase of the frequency difference of the reflected components detected through a second polarizer. Rotation of the half-wave plate can be used for phase adjustment over a full 360/sup 0/ range.

  2. Stability at the surface

    SciTech Connect (OSTI)

    Chambers, Scott A.

    2014-12-05

    Metal oxides are ubiquitous as minerals in the terrestrial environment, as well as in a variety of technologically important structures such as electronic devices and heterogeneous catalysts. Within these various contexts, interfaces between oxides and gases, liquids and solids drive many critically important phenomena ranging from the uptake of contaminants in groundwater by redox-active minerals to the switching of the millions of transistors found in every cell phone and computer. Function is tied to structure. Therefore, fundamental understanding of the structure of oxide surfaces and interfaces is of crucial importance to the comprehension of a plethora of phenomena involving this broad class of materials.

  3. California State Water Resources Control Board 401 Water Quality...

    Open Energy Info (EERE)

    401 Water Quality Certification Website Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: California State Water Resources Control Board 401 Water...

  4. Colorado Division of Water Resources Substitute Water Supply...

    Open Energy Info (EERE)

    Substitute Water Supply Plans Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Colorado Division of Water Resources Substitute Water Supply...

  5. Buildings","All Buildings with Water Heating","Water-Heating...

    U.S. Energy Information Administration (EIA) Indexed Site

    5. Water-Heating Energy Sources, Number of Buildings, 1999" ,"Number of Buildings (thousand)" ,"All Buildings","All Buildings with Water Heating","Water-Heating Energy Sources Used ...

  6. Water Transport Within the STack: Water Transport Exploratory...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Within the STack: Water Transport Exploratory Studies Water Transport Within the STack: Water Transport Exploratory Studies Part of a 100 million fuel cell award announced by DOE ...

  7. Future water Cherenkov detectors

    SciTech Connect (OSTI)

    Bergevin, Marc

    2015-05-15

    In these proceedings a review of the current proposed large-scale Warer Cherenkov experiments is given. An argument is made that future water Cherenkov detectors would benefit in the investment in neutron detection technology. A brief overview will be given of proposed water Cherenkov experiments such as HYPER-K and MEMPHYS and other R and D experiments to demonstrate neutron capture in water Cherenkov detectors. Finally, innovation developed in the context of the now defunct LBNE Water R and D option to improve Water Cherenkov technology will be described.

  8. Assessment of produced water contaminated soils to determine remediation requirements

    SciTech Connect (OSTI)

    Clodfelter, C.

    1995-12-31

    Produced water and drilling fluids can impact the agricultural properties of soil and result in potential regulatory and legal liabilities. Produced water typically is classified as saline or a brine and affects surface soils by increasing the sodium and chloride content. Sources of produced water which can lead to problems include spills from flowlines and tank batteries, permitted surface water discharges and pit areas, particularly the larger pits including reserve pits, emergency pits and saltwater disposal pits. Methods to assess produced water spills include soil sampling with various chemical analyses and surface geophysical methods. A variety of laboratory analytical methods are available for soil assessment which include electrical conductivity, sodium adsorption ratio, cation exchange capacity, exchangeable sodium percent and others. Limiting the list of analytical parameters to reduce cost and still obtain the data necessary to assess the extent of contamination and determine remediation requirements can be difficult. The advantage to using analytical techniques is that often regulatory remediation standards are tied to soil properties determined from laboratory analysis. Surface geophysical techniques can be an inexpensive method to rapidly determine the extent and relative magnitude of saline soils. Data interpretations can also provide an indication of the horizontal as well as the vertical extent of impacted soils. The following discussion focuses on produced water spills on soil and assessment of the impacted soil. Produced water typically contains dissolved hydrocarbons which are not addressed in this discussion.

  9. WATER TRAPPING ON TIDALLY LOCKED TERRESTRIAL PLANETS REQUIRES SPECIAL CONDITIONS

    SciTech Connect (OSTI)

    Yang, Jun; Abbot, Dorian S.; Liu, Yonggang; Hu, Yongyun

    2014-12-01

    Surface liquid water is essential for standard planetary habitability. Calculations of atmospheric circulation on tidally locked planets around M stars suggest that this peculiar orbital configuration lends itself to the trapping of large amounts of water in kilometers-thick ice on the night side, potentially removing all liquid water from the day side where photosynthesis is possible. We study this problem using a global climate model including coupled atmosphere, ocean, land, and sea ice components as well as a continental ice sheet model driven by the climate model output. For a waterworld, we find that surface winds transport sea ice toward the day side and the ocean carries heat toward the night side. As a result, nightside sea ice remains O(10m) thick and nightside water trapping is insignificant. If a planet has large continents on its night side, they can grow ice sheets O(1000m) thick if the geothermal heat flux is similar to Earth's or smaller. Planets with a water complement similar to Earth's would therefore experience a large decrease in sea level when plate tectonics drives their continents onto the night side, but would not experience complete dayside dessiccation. Only planets with a geothermal heat flux lower than Earth's, much of their surface covered by continents, and a surface water reservoir O(10%) of Earth's would be susceptible to complete water trapping.

  10. Coal-water mixture fuel burner

    DOE Patents [OSTI]

    Brown, T.D.; Reehl, D.P.; Walbert, G.F.

    1985-04-29

    The present invention represents an improvement over the prior art by providing a rotating cup burner arrangement for use with a coal-water mixture fuel which applies a thin, uniform sheet of fuel onto the inner surface of the rotating cup, inhibits the collection of unburned fuel on the inner surface of the cup, reduces the slurry to a collection of fine particles upon discharge from the rotating cup, and further atomizes the fuel as it enters the combustion chamber by subjecting it to the high shear force of a high velocity air flow. Accordingly, it is an object of the present invention to provide for improved combustion of a coal-water mixture fuel. It is another object of the present invention to provide an arrangement for introducing a coal-water mixture fuel into a combustion chamber in a manner which provides improved flame control and stability, more efficient combustion of the hydrocarbon fuel, and continuous, reliable burner operation. Yet another object of the present invention is to provide for the continuous, sustained combustion of a coal-water mixture fuel without the need for a secondary combustion source such as natural gas or a liquid hydrocarbon fuel. Still another object of the present invention is to provide a burner arrangement capable of accommodating a coal-water mixture fuel having a wide range of rheological and combustion characteristics in providing for its efficient combustion. 7 figs.

  11. Geothermal Water Use: Life Cycle Water Consumption, Water Resource Assessment, and Water Policy Framework

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Schroeder, Jenna N.

    2014-06-10

    This report examines life cycle water consumption for various geothermal technologies to better understand factors that affect water consumption across the life cycle (e.g., power plant cooling, belowground fluid losses) and to assess the potential water challenges that future geothermal power generation projects may face. Previous reports in this series quantified the life cycle freshwater requirements of geothermal power-generating systems, explored operational and environmental concerns related to the geochemical composition of geothermal fluids, and assessed future water demand by geothermal power plants according to growth projections for the industry. This report seeks to extend those analyses by including EGS flash, both as part of the life cycle analysis and water resource assessment. A regional water resource assessment based upon the life cycle results is also presented. Finally, the legal framework of water with respect to geothermal resources in the states with active geothermal development is also analyzed.

  12. Geothermal Water Use: Life Cycle Water Consumption, Water Resource Assessment, and Water Policy Framework

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Schroeder, Jenna N.

    This report examines life cycle water consumption for various geothermal technologies to better understand factors that affect water consumption across the life cycle (e.g., power plant cooling, belowground fluid losses) and to assess the potential water challenges that future geothermal power generation projects may face. Previous reports in this series quantified the life cycle freshwater requirements of geothermal power-generating systems, explored operational and environmental concerns related to the geochemical composition of geothermal fluids, and assessed future water demand by geothermal power plants according to growth projections for the industry. This report seeks to extend those analyses by including EGS flash, both as part of the life cycle analysis and water resource assessment. A regional water resource assessment based upon the life cycle results is also presented. Finally, the legal framework of water with respect to geothermal resources in the states with active geothermal development is also analyzed.

  13. Laser heterodyne surface profiler

    DOE Patents [OSTI]

    Sommargren, Gary E. (Livermore, CA)

    1982-01-01

    A method and apparatus is disclosed for testing the deviation of the face of an object from a flat smooth surface using a beam of coherent light of two plane-polarized components, one of a frequency constantly greater than the other by a fixed amount to produce a difference frequency with a constant phase to be used as a reference. The beam also is split into its two components with the separate components directed onto spaced apart points onthe face of the object to be tested for smoothness. The object is rotated on an axis coincident with one component which is directed to the face of the object at the center which constitutes a virtual fixed point. This component also is used as a reference. The other component follows a circular track on the face of the object as the object is rotated. The two components are recombined after reflection to produce a reflected frequency difference of a phase proportional to the difference in path length which is compared with the reference phase to produce a signal proportional to the deviation of the height of the surface along the circular track with respect to the fixed point at the center.

  14. Laser heterodyne surface profiler

    DOE Patents [OSTI]

    Sommargren, Gary E. (Livermore, CA)

    1984-01-01

    Method and apparatus for testing the deviation of the face of an object from a flat smooth surface using a laser beam having two plane-polarized components, one of a frequency greater than the other to produce a difference frequency with a phase to be used as a reference. The beam also is split into its two components which are directed onto spaced apart points on the face of the object. The object is rotated on an axis coincident with one component as a reference. The other component follows a circular track on the face of the object as the object is rotated. The two components are recombined after reflection to produce a difference frequency having a phase that is shifted in an amount that is proportional to the difference in path length as compared to the reference phase to produce an electrical output signal proportional to the deviation of the height of the surface along the circular track. The output signal is generated by means of a phase detector that includes a first photodetector in the path of the recombined components and a second photodetector in the path of the reference phase. The output signal is dependent on the phase difference of the two photodetector signals. A polarizer, a quarter-wave plate and a half-wave plate are in series in the path of the reference phase. Rotation of the half-wave plate can be used for phase adjustment over a full 360.degree. range for initial calibration of the apparatus.

  15. Surface tension of spherical drops from surface of tension

    SciTech Connect (OSTI)

    Homman, A.-A.; Bourasseau, E.; Malfreyt, P.; Strafella, L.; Ghoufi, A.

    2014-01-21

    The determination of surface tension of curved interfaces is a topic that raised many controversies during the last century. Explicit liquid-vapor interface modelling (ELVI) was unable up to now to reproduce interfacial behaviors in drops due to ambiguities in the mechanical definition of the surface tension. In this work, we propose a thermodynamic approach based on the location of surface of tension and its use in the Laplace equation to extract the surface tension of spherical interfaces from ELVI modelling.

  16. Probing the surface structure of divalent transition metals using surface

    Office of Scientific and Technical Information (OSTI)

    specific solid-state NMR spectroscopy (Journal Article) | SciTech Connect Probing the surface structure of divalent transition metals using surface specific solid-state NMR spectroscopy Citation Details In-Document Search Title: Probing the surface structure of divalent transition metals using surface specific solid-state NMR spectroscopy Authors: Mason, H E ; Harley, S J ; Maxwell, R S ; Carroll, S A Publication Date: 2011-12-07 OSTI Identifier: 1107317 Report Number(s): LLNL-JRNL-520237

  17. Materials Characterization Capabilities at the HTML: Surface/Sub-surface

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    dislocation density analysis of forming samples using advanced characterization techniques | Department of Energy HTML: Surface/Sub-surface dislocation density analysis of forming samples using advanced characterization techniques Materials Characterization Capabilities at the HTML: Surface/Sub-surface dislocation density analysis of forming samples using advanced characterization techniques 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and

  18. Test surfaces useful for calibration of surface profilometers

    DOE Patents [OSTI]

    Yashchuk, Valeriy V; McKinney, Wayne R; Takacs, Peter Z

    2013-12-31

    The present invention provides for test surfaces and methods for calibration of surface profilometers, including interferometric and atomic force microscopes. Calibration is performed using a specially designed test surface, or the Binary Pseudo-random (BPR) grating (array). Utilizing the BPR grating (array) to measure the power spectral density (PSD) spectrum, the profilometer is calibrated by determining the instrumental modulation transfer.

  19. Super recycled water: quenching computers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Super recycled water: quenching computers Super recycled water: quenching computers New facility and methods support conserving water and creating recycled products. Using reverse...

  20. Oasys Water | Open Energy Information

    Open Energy Info (EERE)

    Oasys Water Jump to: navigation, search Name: Oasys Water Place: Cambridge, Massachusetts Product: Cambridge-based developer of Engineered Osmosis, desalination and water treatment...

  1. Water Heaters | Open Energy Information

    Open Energy Info (EERE)

    Water Heaters Jump to: navigation, search TODO: Add description List of Water Heaters Incentives Retrieved from "http:en.openei.orgwindex.php?titleWaterHeaters&oldid267202"...

  2. Water Power | Open Energy Information

    Open Energy Info (EERE)

    Get Involved Help Apps Datasets Community Login | Sign Up Search Gateway Edit History Water Power (Redirected from Water) Jump to: navigation, search Water Power Community Forum...

  3. Water Heating | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Water Heating Water Heating Infographic: Water Heaters 101 Infographic: Water Heaters 101 Everything you need to know about saving money on water heating costs. Read more Selecting a New Water Heater Selecting a New Water Heater Tankless? Storage? Solar? Save money on your water heating bill by choosing the right type of energy-efficient water heater for your needs. Read more Sizing a New Water Heater Sizing a New Water Heater When buying a new water heater, bigger is not always better. Learn

  4. Improved LWR Cladding Performance by EPD Surface Modification Technique

    SciTech Connect (OSTI)

    Corradini, Michael; Sridharan, Kumar

    2012-11-26

    This project will utilize the electro-phoretic deposition technique (EPD) in conjunction with nanofluids to deposit oxide coatings on prototypic zirconium alloy cladding surfaces. After demonstrating that this surface modification is reproducible and robust, the team will subject the modified surface to boiling and corrosion tests to characterize the improved nucleate boiling behavior and superior corrosion performance. The scope of work consists of the following three tasks: The first task will employ the EPD surface modification technique to coat the surface of a prototypic set of zirconium alloy cladding tube materials (e.g. Zircaloy and advanced alloys such as M5) with a micron-thick layer of zirconium oxide nanoparticles. The team will characterize the modified surface for uniformity using optical microscopy and scanning-electron microscopy, and for robustness using standard hardness measurements. After zirconium alloy cladding samples have been prepared and characterized using the EPD technique, the team will begin a set of boiling experiments to measure the heat transfer coefficient and critical heat flux (CHF) limit for each prepared sample and its control sample. This work will provide a relative comparison of the heat transfer performance for each alloy and the surface modification technique employed. As the boiling heat transfer experiments begin, the team will also begin corrosion tests for these zirconium alloy samples using a water corrosion test loop that can mimic light water reactor (LWR) operational environments. They will perform extended corrosion tests on the surface-modified zirconium alloy samples and control samples to examine the robustness of the modified surface, as well as the effect on surface oxidation

  5. Chemical enhancement of surface deposition

    DOE Patents [OSTI]

    Patch, K.D.; Morgan, D.T.

    1997-07-29

    A method and apparatus are disclosed for increasing the deposition of ions onto a surface, such as the adsorption of uranium ions on the detecting surface of a radionuclide detector. The method includes the step of exposing the surface to a complexing agent, such as a phosphate ion solution, which has an affinity for the dissolved species to be deposited on the surface. This provides, for example, enhanced sensitivity of the radionuclide detector. 16 figs.

  6. Chemical enhancement of surface deposition

    DOE Patents [OSTI]

    Patch, Keith D. (Lexington, MA); Morgan, Dean T. (Sudbury, MA)

    1997-07-29

    A method and apparatus for increasing the deposition of ions onto a surface, such as the adsorption of uranium ions on the detecting surface of a radionuclide detector. The method includes the step of exposing the surface to a complexing agent, such as a phosphate ion solution, which has an affinity for the dissolved species to be deposited on the surface. This provides, for example, enhanced sensitivity of the radionuclide detector.

  7. Method for lubricating contacting surfaces

    DOE Patents [OSTI]

    Dugger, Michael T. (Tijeras, NM); Ohlhausen, James A. (Albuquerque, NM); Asay, David B. (Boalsburg, PA); Kim, Seong H. (State College, PA)

    2011-12-06

    A method is provided for tribological lubrication of sliding contact surfaces, where two surfaces are in contact and in motion relative to each other, operating in a vapor-phase environment containing at least one alcohol compound at a concentration sufficiently high to provide one monolayer of coverage on at least one of the surfaces, where the alcohol compound continuously reacts at the surface to provide lubrication.

  8. ARM - Measurement - Soil surface temperature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    surface temperature ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Soil surface temperature The temperature of the soil measured near the surface. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those

  9. ARM - Measurement - Surface skin temperature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    skin temperature ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Surface skin temperature The radiative surface skin temperature, from an IR thermometer measuring the narrowband radiating temperature of the ground surface in its field of view. Categories Radiometric, Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the

  10. Tunable surface plasmon devices

    DOE Patents [OSTI]

    Shaner, Eric A. (Rio Rancho, NM); Wasserman, Daniel (Lowell, MA)

    2011-08-30

    A tunable extraordinary optical transmission (EOT) device wherein the tunability derives from controlled variation of the dielectric constant of a semiconducting material (semiconductor) in evanescent-field contact with a metallic array of sub-wavelength apertures. The surface plasmon resonance wavelength can be changed by changing the dielectric constant of the dielectric material. In embodiments of this invention, the dielectric material is a semiconducting material. The dielectric constant of the semiconducting material in the metal/semiconductor interfacial region is controllably adjusted by adjusting one or more of the semiconductor plasma frequency, the concentration and effective mass of free carriers, and the background high-frequency dielectric constant in the interfacial region. Thermal heating and/or voltage-gated carrier-concentration changes may be used to variably adjust the value of the semiconductor dielectric constant.

  11. Laser heterodyne surface profiler

    DOE Patents [OSTI]

    Sommargren, G.E.

    1984-06-26

    Method and apparatus are disclosed for testing the deviation of the face of an object from a flat smooth surface using a laser beam having two plane-polarized components, one of a frequency greater than the other to produce a difference frequency with a phase to be used as a reference. The beam also is split into its two components which are directed onto spaced apart points on the face of the object. The object is rotated on an axis coincident with one component as a reference. The other component follows a circular track on the face of the object as the object is rotated. The two components are recombined after reflection to produce a difference frequency having a phase that is shifted in an amount that is proportional to the difference in path length as compared to the reference phase to produce an electrical output signal proportional to the deviation of the height of the surface along the circular track. The output signal is generated by means of a phase detector that includes a first photodetector in the path of the recombined components and a second photodetector in the path of the reference phase. The output signal is dependent on the phase difference of the two photodetector signals. A polarizer, a quarter-wave plate and a half-wave plate are in series in the path of the reference phase. Rotation of the half-wave plate can be used for phase adjustment over a full 360[degree] range for initial calibration of the apparatus. 12 figs.

  12. Arsenic removal from water

    DOE Patents [OSTI]

    Moore, Robert C.; Anderson, D. Richard

    2007-07-24

    Methods for removing arsenic from water by addition of inexpensive and commonly available magnesium oxide, magnesium hydroxide, calcium oxide, or calcium hydroxide to the water. The hydroxide has a strong chemical affinity for arsenic and rapidly adsorbs arsenic, even in the presence of carbonate in the water. Simple and commercially available mechanical methods for removal of magnesium hydroxide particles with adsorbed arsenic from drinking water can be used, including filtration, dissolved air flotation, vortex separation, or centrifugal separation. A method for continuous removal of arsenic from water is provided. Also provided is a method for concentrating arsenic in a water sample to facilitate quantification of arsenic, by means of magnesium or calcium hydroxide adsorption.

  13. Capacitive deionization of water: An innovative new process

    SciTech Connect (OSTI)

    Farmer, J.; Fix, D.; Mack, G. [and others

    1995-01-09

    The capacitive deionization of water with a stack of carbon aerogel electrodes has been successfully demonstrated for the first time. Unlike ion exchange, one of the more conventional deionization processes, no chemicals were required for regeneration of the system. Electricity was used instead. Water with various anions and cations was pumped through the electrochemical cell. After polarization, ions were electrostatically removed from the water and held in the electric double layers formed at electrode surfaces. The water leaving the cell was purified, as desired.

  14. Water Cooling | Open Energy Information

    Open Energy Info (EERE)

    Water Cooling Jump to: navigation, search Dictionary.png Water Cooling: Water cooling is commonly defined as a method of using water as a heat conduction to remove heat from an...

  15. Water Heating | Department of Energy

    Energy Savers [EERE]

    Water Heating Water Heating September 2, 2015 - 11:07am Addthis Low-flow fixtures will help you reduce your hot water use and save money on your water heating bills. | Photo...

  16. Water Cycle Pilot Study

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Water Cycle Pilot Study To learn more about Earth's water cycle, the U.S. Department of Energy (DOE) has established a multi-laboratory science team representing five DOE national laboratories: Argonne, Brookhaven, Lawrence Berkeley, Los Alamos, and Oak Ridge. The science team will conduct a three- year Water Cycle Pilot Study within the ARM SGP CART site, primarily in the Walnut River Watershed east of Wichita, Kansas. The host facility in the Walnut River Watershed is the Atmospheric

  17. Surface-stabilized gold nanocatalysts

    DOE Patents [OSTI]

    Dai, Sheng [Knoxville, TN; Yan, Wenfu [Oak Ridge, TN

    2009-12-08

    A surface-stabilized gold nanocatalyst includes a solid support having stabilizing surfaces for supporting gold nanoparticles, and a plurality of gold nanoparticles having an average particle size of less than 8 nm disposed on the stabilizing surfaces. The surface-stabilized gold nanocatalyst provides enhanced stability, such as at high temperature under oxygen containing environments. In one embodiment, the solid support is a multi-layer support comprising at least a first layer having a second layer providing the stabilizing surfaces disposed thereon, the first and second layer being chemically distinct.

  18. Tools for measuring surface cleanliness

    DOE Patents [OSTI]

    Schroder, Mark Stewart; Woodmansee, Donald Ernest; Beadie, Douglas Frank

    2002-01-01

    A procedure and tools for quantifying surface cleanliness are described. Cleanliness of a target surface is quantified by wiping a prescribed area of the surface with a flexible, bright white cloth swatch, preferably mounted on a special tool. The cloth picks up a substantial amount of any particulate surface contamination. The amount of contamination is determined by measuring the reflectivity loss of the cloth before and after wiping on the contaminated system and comparing that loss to a previous calibration with similar contamination. In the alternative, a visual comparison of the contaminated cloth to a contamination key provides an indication of the surface cleanliness.

  19. Storm Water Analytical Period

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    water associated with historical industrial activities at LANL from specified solid waste management units and areas of concern, collectively referred to as Sites. Contact...

  20. Sandia Energy - Water Security

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas...

  1. Water Conservation Measures

    Energy Science and Technology Software Center (OSTI)

    2010-12-31

    This software requires inputs of simple water fixture inventory information and calculates the water/energy and cost benefits of various retrofit opportunities. This tool includes water conservation measures for: Low-flow Toilets, Low-flow Urinals, Low-flow Faucets, and Low-flow Showheads. This tool calculates water savings, energy savings, demand reduction, cost savings, and building life cycle costs including: simple payback, discounted payback, net-present value, and savings to investment ratio. In addition this tool also displays the environmental benefits ofmore » a project.« less

  2. Sandia Energy - Water Power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6, a backward--bent duct buoy (BBDB) oscillating water column wave energy converter design. The team from HMRC included Tom Walsh, Brian Holmes, Florent Thiebaut, Neil...

  3. Sandia Energy - Water Power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    News & Events, Partnership, Renewable Energy, Systems Analysis, Systems Engineering, Water Power WEC-Sim Code Development Meeting at the National Renewable Energy Laboratory...

  4. Water Success Stories

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 Water Success Stories en Catching a Wave: Innovative Wave Energy Device Surfs for Power in Hawaii http:energy.goveeresuccess-storiesarticlescatching-wave-innovative-wave-en...

  5. Water Power Program: Publications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2014 Hydropower Market Report Details Bookmark & Share View Related Welcome to the Water Power Program Publication and Product Library. This library will allow you to find...

  6. Water Conservation Measures

    SciTech Connect (OSTI)

    2010-12-31

    This software requires inputs of simple water fixture inventory information and calculates the water/energy and cost benefits of various retrofit opportunities. This tool includes water conservation measures for: Low-flow Toilets, Low-flow Urinals, Low-flow Faucets, and Low-flow Showheads. This tool calculates water savings, energy savings, demand reduction, cost savings, and building life cycle costs including: simple payback, discounted payback, net-present value, and savings to investment ratio. In addition this tool also displays the environmental benefits of a project.

  7. Residential Water Heaters Webinar

    Broader source: Energy.gov (indexed) [DOE]

    ENERGY LABORATORY Technology Overview - Condensing Storage * Fuels: Natural Gas, Propane * Much greater surface area of flue pipe, more heat transfer and combustion gases...

  8. Selecting a new water heater

    SciTech Connect (OSTI)

    1995-03-01

    This fact sheet describes the types of water heaters available (storage water heaters, demand water heaters, heat pump water heaters, tankless coil and indirect water heaters, and solar water heaters). The criteria for selection are discussed. These are capacity, efficiency rating, and cost. A resource list is provided for further information.

  9. Surface mount component jig

    DOE Patents [OSTI]

    Kronberg, James W. (Beech Island, SC)

    1990-08-07

    A device for bending and trimming the pins of a dual-inline-package component and the like for surface mounting rather than through mounting to a circuit board comprises, in a first part, in pin cutter astride a holder having a recess for holding the component, a first spring therebetween, and, in a second part, two flat members pivotally interconnected by a hinge and urged to an upward peaked position from a downward peaked position by a second spring. As a downward force is applied to the pin cutter it urges the holder downward, assisted by the first spring and a pair of ridges riding on shoulders of the holder, to carry the component against the upward peaked flat members which guide the pins outwardly. As the holder continues downwardly, the flat members pivot to the downward peaked position bending the pins upwardly against the sides of the holder. When the downward movement is met with sufficient resistance, the ridges of the pin cutter ride over the holder's shoulders to continue downward to cut any excess length of pin.

  10. Ceramic coating system or water oxidation environments

    DOE Patents [OSTI]

    Hong, Glenn T. (Tewksbury, MA)

    1996-01-01

    A process for water oxidation of combustible materials in which during at least a part of the oxidation corrosive material is present and makes contact with at least a portion of the apparatus over a contact area on the apparatus. At least a portion of the contact surface area comprises titanium dioxide coated onto a titanium metal substrate. Such ceramic composites have been found to be highly resistant to environments encountered in the process of supercritical water oxidation. Such environments typically contain greater than 50 mole percent water, together with oxygen, carbon dioxide, and a wide range of acids, bases, and salts. Pressures are typically about 27.5 to about 1000 bar while temperatures range as high as 700.degree. C. The ceramic composites are also resistant to degradation mechanisms caused by thermal stresses.

  11. Distribution Category: Water R

    Office of Scientific and Technical Information (OSTI)

    Distribution Category: Water R e a c t o r Safety- R e s e a r c h - - A n a l y s i s ... 8 10 I TOTAL VOLUMETRIC FLUX, ms Fig. 9. Fully Developed Air-Water Flow Data.30 ANL Neg. ...

  12. Purge water management system

    DOE Patents [OSTI]

    Cardoso-Neto, J.E.; Williams, D.W.

    1995-01-01

    A purge water management system is described for effectively eliminating the production of purge water when obtaining a groundwater sample from a monitoring well. In its preferred embodiment, the purge water management system comprises an expandable container, a transportation system, and a return system. The purge water management system is connected to a wellhead sampling configuration, typically permanently installed at the well site. A pump, positioned with the monitoring well, pumps groundwater through the transportation system into the expandable container, which expands in direct proportion with volume of groundwater introduced, usually three or four well volumes, yet prevents the groundwater from coming into contact with the oxygen in the air. After this quantity of groundwater has been removed from the well, a sample is taken from a sampling port, after which the groundwater in the expandable container can be returned to the monitoring well through the return system. The purge water management system prevents the purge water from coming in contact with the outside environment, especially oxygen, which might cause the constituents of the groundwater to oxidize. Therefore, by introducing the purge water back into the monitoring well, the necessity of dealing with the purge water as a hazardous waste under the Resource Conservation and Recovery Act is eliminated.

  13. Purge water management system

    DOE Patents [OSTI]

    Cardoso-Neto, Joao E.; Williams, Daniel W.

    1996-01-01

    A purge water management system for effectively eliminating the production of purge water when obtaining a groundwater sample from a monitoring well. In its preferred embodiment, the purge water management system comprises an expandable container, a transportation system, and a return system. The purge water management system is connected to a wellhead sampling configuration, typically permanently installed at the well site. A pump, positioned with the monitoring well, pumps groundwater through the transportation system into the expandable container, which expands in direct proportion with volume of groundwater introduced, usually three or four well volumes, yet prevents the groundwater from coming into contact with the oxygen in the air. After this quantity of groundwater has been removed from the well, a sample is taken from a sampling port, after which the groundwater in the expandable container can be returned to the monitoring well through the return system. The purge water management system prevents the purge water from coming in contact with the outside environment, especially oxygen, which might cause the constituents of the groundwater to oxidize. Therefore, by introducing the purge water back into the monitoring well, the necessity of dealing with the purge water as a hazardous waste under the Resource Conservation and Recovery Act is eliminated.

  14. UMTRA project water sampling and analysis plan, Monument Valley, Arizona

    SciTech Connect (OSTI)

    Not Available

    1994-04-01

    The Monument Valley Uranium Mill Tailings Remedial Action (UMTRA) Project site in Cane Valley is a former uranium mill that has undergone surface remediation in the form of tailings and contaminated materials removal. Contaminated materials from the Monument Valley (Arizona) UMTRA Project site have been transported to the Mexican Hat (Utah) UMTRA Project site for consolidation with the Mexican Hat tailings. Tailings removal was completed in February 1994. Three geologic units at the site contain water: the unconsolidated eolian and alluvial deposits (alluvial aquifer), the Shinarump Conglomerate (Shinarump Member), and the De Chelly Sandstone. Water quality analyses indicate the contaminant plume has migrated north of the site and is mainly in the alluvial aquifer. An upward hydraulic gradient in the De Chelly Sandstone provides some protection to that aquifer. This water sampling and analysis plan recommends sampling domestic wells, monitor wells, and surface water in April and September 1994. The purpose of sampling is to continue periodic monitoring for the surface program, evaluate changes to water quality for site characterization, and provide data for the baseline risk assessment. Samples taken in April will be representative of high ground water levels and samples taken in September will be representative of low ground water levels. Filtered and nonfiltered samples will be analyzed for plume indicator parameters and baseline risk assessment parameters.

  15. Surface Sensitivity in Cluster-Ion-Induced Sputtering

    SciTech Connect (OSTI)

    Szakal, Christopher; Kozole, Joseph; Russo, Michael F. Jr.; Garrison, Barbara J.; Winograd, Nicholas

    2006-06-02

    The ion beam-induced removal of thin water ice films condensed onto Ag and bombarded by energetic Au, Au{sub 2}, Au{sub 3}, and C{sub 60} projectiles is examined both experimentally and with molecular dynamics computer simulations. For water overlayers of thicknesses greater than 10 A, the yields of sputtered Ag{sup +} secondary ions decay exponentially with increasing ice thickness, revealing characteristic decay lengths of 24, 20, 18, and 7.0 A ring , respectively. It is shown that these values manifest the characteristic depths of projectile energy loss, rather than escape depths of the sputtered Ag atoms through the water ice overlayer. Computer simulations show that the mechanism of ejection involves the sweeping away of overlayer water molecules, allowing for an unimpeded escape of ejected Ag atoms. The relevance of these data with respect to surface sensitivity in secondary ion mass spectrometry is discussed.

  16. ANAEROBIC BIOLOGICAL TREATMENT OF PRODUCED WATER

    SciTech Connect (OSTI)

    John R. Gallagher

    2001-07-31

    During the production of oil and gas, large amounts of water are brought to the surface and must be disposed of in an environmentally sensitive manner. This is an especially difficult problem in offshore production facilities where space is a major constraint. The chief regulatory criterion for produced water is oil and grease. Most facilities have little trouble meeting this criterion using conventional oil-water separation technologies. However, some operations have significant amounts of naphthenic acids in the water that behave as oil and grease but are not well removed by conventional technologies. Aerobic biological treatment of naphthenic acids in simulated-produced water has been demonstrated by others; however, the system was easily overloaded by the large amounts of low-molecular-weight organic acids often found in produced waters. The objective of this research was to determine the ability of an anaerobic biological system to treat these organic acids in a simulated produced water and to examine the potential for biodegradation of the naphthenic acids in the anaerobic environment. A small fixed-film anaerobic biological reactor was constructed and adapted to treat a simulated produced water. The bioreactor was tubular, with a low-density porous glass packing material. The inocula to the reactor was sediment from a produced-water holding pond from a municipal anaerobic digester and two salt-loving methanogenic bacteria. During start-up, the feed to the reactor contained glucose as well as typical produced-water components. When glucose was used, rapid gas production was observed. However, when glucose was eliminated and the major organic component was acetate, little gas was generated. Methane production from acetate may have been inhibited by the high salt concentrations, by sulfide, or because of the lack, despite seeding, of microbes capable of converting acetate to methane. Toluene, a minor component of the produced water (0.1 g/L) was removed in the reactor. Batch tests were conducted to examine naphthenic acid biodegradability under several conditions. The conditions used were seed from the anaerobic reactor, wetland sediments under aerobic and anaerobic conditions, and a sterile control. The naphthenic acid was from a commercial source isolated from Gulf Coast petroleum as was dosed at 2 mg/mL. The incubations were for 30 days at 30 C. The results showed that the naphthenic acids were not biodegraded under anaerobic conditions, but were degraded under aerobic conditions. Despite poor performance of the anaerobic reactor, it remains likely that anaerobic treatment of acetate, toluene, and, potentially, other produced-water components is feasible.

  17. Friction surfaced Stellite6 coatings

    SciTech Connect (OSTI)

    Rao, K. Prasad; Damodaram, R.; Rafi, H. Khalid; Ram, G.D. Janaki; Reddy, G. Madhusudhan; Nagalakshmi, R.

    2012-08-15

    Solid state Stellite6 coatings were deposited on steel substrate by friction surfacing and compared with Stellite6 cast rod and coatings deposited by gas tungsten arc and plasma transferred arc welding processes. Friction surfaced coatings exhibited finer and uniformly distributed carbides and were characterized by the absence of solidification structure and compositional homogeneity compared to cast rod, gas tungsten arc and plasma transferred coatings. Friction surfaced coating showed relatively higher hardness. X-ray diffraction of samples showed only face centered cubic Co peaks while cold worked coating showed hexagonally close packed Co also. - Highlights: Black-Right-Pointing-Pointer Stellite6 used as coating material for friction surfacing. Black-Right-Pointing-Pointer Friction surfaced (FS) coatings compared with casting, GTA and PTA processes. Black-Right-Pointing-Pointer Finer and uniformly distributed carbides in friction surfaced coatings. Black-Right-Pointing-Pointer Absence of melting results compositional homogeneity in FS Stellite6 coatings.

  18. Method of modifying a surface

    DOE Patents [OSTI]

    Renk, Timothy J. (Albuquerque, NM); Sorensen, Neil R. (Albuquerque, NM); Senft, Donna Cowell (Albuquerque, NM); Buchheit, Jr., Rudolph G. (Columbus, OH); Thompson, Michael O. (Ithaca, NY); Grabowski, Kenneth S. (Alexandria, VA)

    2000-01-01

    The present invention provides a surface modification method that provides beneficial changes in surface properties, can modify a surface to a greater depth than previous methods, and that is suitable for industrial application. The present method comprises applying a thin-film coating to a surface of a substrate, then subjecting the coated surface to an ion beam. The ion beam power pulse heats the coated surface, leading to alloying between the material in the coating and the material of the substrate. Rapid cooling of the alloyed layer after an ion beam pulse can lead to formation of metastable alloys and microstructures not accessible by conventional alloying methods or intense ion beam treatment of the substrate alone.

  19. Composition suitable for decontaminating a porous surface contaminated with cesium

    DOE Patents [OSTI]

    Kaminski, Michael D.; Finck, Martha R.; Mertz, Carol J.

    2010-06-15

    A method of decontaminating porous surfaces contaminated with water soluble radionuclides by contacting the contaminated porous surfaces with an ionic solution capable of solubilizing radionuclides present in the porous surfaces followed by contacting the solubilized radionuclides with a gel containing a radionuclide chelator to bind the radionuclides to the gel, and physically removing the gel from the porous surfaces. A dry mix is also disclosed of a cross-linked ionic polymer salt, a linear ionic polymer salt, a radionuclide chelator, and a gel formation controller present in the range of from 0% to about 40% by weight of the dry mix, wherein the ionic polymer salts are granular and the non cross-linked ionic polymer salt is present as a minor constituent.

  20. ARM - Lesson Plans: Surface Currents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Currents Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Lesson Plans: Surface Currents Objective The objective is to demonstrate the simple surface currents and to calculate the speed of current. Materials Each student or group of students will need the following: Books Pencil/pen

  1. ARM - Measurement - Surface energy balance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    energy balance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Surface energy balance The energy balance at the earth's surface between the net radiation and the sensible and latent heat fluxes and ground heat flux. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each

  2. Mapping water availability, projected use and cost in the western United States

    SciTech Connect (OSTI)

    Vincent C. Tidwell; Barbara D. Moreland; Katie M. Zemlick; Barry L. Roberts; Howard D. Passell; Daniel Jensen; Christopher Forsgren; Gerald Sehlke; Margaret A. Cook; Carey W. King

    2014-06-01

    New demands for water can be satisfied through a variety of source options. In some basins surface and/or groundwater may be available through permitting with the state water management agency (termed unappropriated water), alternatively water might be purchased and transferred out of its current use to another (termed appropriated water), or non-traditional water sources can be captured and treated (e.g., wastewater). The relative availability and cost of each source are key factors in the development decision. Unfortunately, these measures are location dependent with no consistent or comparable set of data available for evaluating competing water sources. With the help of western water managers, water availability was mapped for over 1200 watersheds throughout the western US. Five water sources were individually examined, including unappropriated surface water, unappropriated groundwater, appropriated water, municipal wastewater and brackish groundwater. Also mapped was projected change in consumptive water use from 2010 to 2030. Associated costs to acquire, convey and treat the water, as necessary, for each of the five sources were estimated. These metrics were developed to support regional water planning and policy analysis with initial application to electric transmission planning in the western US.

  3. ARM - Surface Aerosol Observing System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2009-2010 Shouxian, China, 2008 Black Forest, Germany, 2007 Niamey, Niger, 2006 Point Reyes, California, 2005 Surface Aerosol Observing System The ARM Mobile Facility (AMF) is...

  4. Materials Characterization Capabilities at the HTML: Surface...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HTML: SurfaceSub-surface dislocation density analysis of forming samples using advanced characterization techniques Materials Characterization Capabilities at the HTML: Surface...

  5. Wind/Water Nexus

    SciTech Connect (OSTI)

    Not Available

    2006-04-01

    Nobel laureate Richard Smalley cited energy and water as among humanity's top problems for the next 50 years as the world's population increases from 6.3 billion to 9 billion. The U.S. Department of Energy's Wind and Hydropower Program has initiated an effort to explore wind energy's role as a technical solution to this critically important issue in the United States and the world. This four-page fact sheet outlines five areas in which wind energy can contribute: thermoelectric power plant/water processes, irrigation, municipal water supply, desalination, and wind/hydropower integration.

  6. Surface Polarity Of Beta-hmx Crystal And The Related Adhesive Forces With Estane Binder

    SciTech Connect (OSTI)

    Yang, Lu; Hanson, David E

    2008-01-01

    Here we present the results on the study of surface properties of {beta}-HMX crystal utilizing molecular simulations. The surface polarity of three principal crystal surfaces are investigated by measuring the water contact angles. The calculated contact angles agree excellently with the values measured by experiment and show that the surface polarity of three crystal surfaces are different. The free energies and forces of detaching an Estane chain with and without nitroplasticizer from the three principal crystal surfaces were calculated using umbrella sampling technique. We find that the detaching free energy/force increases with the increasing HMX surface polarity. In addition, our results also show that nitroplasticizer plays an important role in the adhesion forces between Estane and HMX surfaces.

  7. California State Water Resources Control Board Storm Water Homepage...

    Open Energy Info (EERE)

    State Water Resources Control Board Storm Water Homepage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: California State Water Resources Control Board...

  8. UV water disinfector

    DOE Patents [OSTI]

    Gadgil, A.; Garud, V.

    1998-07-14

    A UV disinfector with a gravity driven feed water delivery system and an air-suspended bare UV lamp are disclosed. The disinfector is hydrodynamically optimized with a laminerizing, perforated baffle wall, beveled treatment chamber, and outlet weir. 7 figs.

  9. Energy and Water Act

    Broader source: Energy.gov (indexed) [DOE]

    Letter 2004-02 - FY 2004 Le2islation Provisions (dated March 1.2004) Energy and Water Act AL-2004-02 provides guidance regarding the implementation of Section 30 I. 304....

  10. Water Power News

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    858936+791+7+343Water Power News en Energy Department Awards 10.5 Million for Next-Generation Marine Energy Systems http:energy.goveerearticlesenergy-department-awards-105-...

  11. Water Sample Concentrator

    ScienceCinema (OSTI)

    Idaho National Laboratory

    2010-01-08

    Automated portable device that concentrates and packages a sample of suspected contaminated water for safe, efficient transport to a qualified analytical laboratory. This technology will help safeguard against pathogen contamination or chemical and biolog

  12. Thermoelectrically cooled water trap

    DOE Patents [OSTI]

    Micheels, Ronald H.

    2006-02-21

    A water trap system based on a thermoelectric cooling device is employed to remove a major fraction of the water from air samples, prior to analysis of these samples for chemical composition, by a variety of analytical techniques where water vapor interferes with the measurement process. These analytical techniques include infrared spectroscopy, mass spectrometry, ion mobility spectrometry and gas chromatography. The thermoelectric system for trapping water present in air samples can substantially improve detection sensitivity in these analytical techniques when it is necessary to measure trace analytes with concentrations in the ppm (parts per million) or ppb (parts per billion) partial pressure range. The thermoelectric trap design is compact and amenable to use in a portable gas monitoring instrumentation.

  13. UV water disinfector

    DOE Patents [OSTI]

    Gadgil, Ashok (El Cerrito, CA); Garud, Vikas (Bombay, IN)

    1998-07-14

    A UV disinfector with a gravity driven feed water delivery system, and an air-suspended bare UV lamp. The disinfector is hydrodynamically optimized with a laminerizing, perforated baffle wall, beveled treatment chamber, and outlet weir.

  14. Storm Water Individual Permit.

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NPDES Storm Water Individual Permit. Wednesday, January 22, 2014 5:30 p.m. Cities of Gold Conference Center 10 Cities of Gold Road, Pojoaque, NM The Individual Permit authorizes...

  15. Electrolysis of Water

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrolysis of Water Grades: 5-8 Topic: Hydrogen and Fuel Cells, Solar Owner: Florida Solar Energy Center This educational material is brought to you by the U.S. Department of...

  16. Water Power Program News

    SciTech Connect (OSTI)

    2012-01-19

    News stories about conventional hydropower and marine and hydrokinetic technologies from the U.S. Department of Energy, the Office of Energy Efficiency and Renewable Energy, the Wind and Water Power Program, and other federal agencies.

  17. Effect of morphology of hydrophobic surfaces on cavitation kinetics

    SciTech Connect (OSTI)

    LUZAR,ALENKA; LEUNG,KEVIN

    2000-04-24

    Cavitation has been suggested to be a possible source of long range interactions between mesoscopic hydrophobic surfaces. While evaporation is predicted by thermodynamics, little is known about its kinetics. Glauber dynamics Monte Carlo simulations of a lattice gas close to liquid-gas coexistence and confined between partially drying surfaces are used to model the effect of water confinement on the dynamics of surface-induced phase transition. Specifically, they examine how kinetics of induced evaporation change as the texture of hydrophobic surfaces is varied. Evaporation rates are considerably slowed with relatively small amount of hydrophilic coverage. However, the distribution of hydrophilic patches is found to be crucial, with the homogeneous one being much more effective in slowing the formation of vapor tubes which triggers the evaporation process. They estimate the free energy barrier of vapor tube formation via transition state theory, using a constrained forward-backward umbrella sampling technique applied to the metastable, confined liquid. Furthermore, to relate simulation rates to experimental ones, they perform simulations using the mass-conserving Kawasaki algorithm. They predict evaporation time scales that range from hundreds of picoseconds in the case of mesoscopic surfaces {approximately} 10{sup 4} nm{sup 2} to tens of nanoseconds for smaller surfaces {approximately} 40 nm{sup 2}, when the two surfaces are {approximately} 10 solvent layers apart. The present study demonstrates that cavitation is kinetically viable in real systems and should be considered in studies of processes at confined geometry.

  18. energy-water interdependency

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    water interdependency - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  19. Purifying contaminated water

    DOE Patents [OSTI]

    Daughton, Christian G. (San Pablo, CA)

    1983-01-01

    Process for removing biorefractory compounds from contaminated water (e.g., oil shale retort waste-water) by contacting same with fragmented raw oil shale. Biorefractory removal is enhanced by preactivating the oil shale with at least one member of the group of carboxylic, acids, alcohols, aldehydes, ketones, ethers, amines, amides, sulfoxides, mixed ether-esters and nitriles. Further purification is obtained by stripping, followed by biodegradation and removal of the cells.

  20. Water Vapor Experiment Concludes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Water Vapor Experiment Concludes The AIRS (atmospheric infrared sounder) Water Vapor Experiment - Ground (AWEX-G) intensive operations period (IOP) at the SGP central facility began on October 27 and ended on November 16, 2003. Researchers David Whiteman and Francis Schmidlin of the National Aeronautics and Space Administration (NASA), Holger Voemel of the National Oceanic and Atmospheric Administration (NOAA), Larry Miloshevich of the National Center for Atmospheric Research, and Barry Lesht

  1. Energy-Water Nexus

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy-Water Nexus - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  2. Water | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Water Water EERE plays a key role in advancing America's "all of the above" energy strategy, leading a large network of researchers and other partners to deliver innovative technologies that will make renewable electricity generation cost-competitive with traditional sources of energy. EERE plays a key role in advancing America's "all of the above" energy strategy, leading a large network of researchers and other partners to deliver innovative technologies that will make

  3. Water | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Water Water This map demonstrates the potential capacity to generate clean hydroelectric energy at existing non-powered dams across the U.S. Learn more. America has vast wave, tidal and hydropower resources - but much of this energy remains untapped. The Energy Department is committed to driving critical research and development efforts to expand electricity generation from these clean energy resources. This includes investments in existing hydropower facilities to equip them with the necessary

  4. Background canceling surface alpha detector

    DOE Patents [OSTI]

    MacArthur, D.W.; Allander, K.S.; Bounds, J.A.

    1996-06-11

    A background canceling long range alpha detector which is capable of providing output proportional to both the alpha radiation emitted from a surface and to radioactive gas emanating from the surface. The detector operates by using an electrical field between first and second signal planes, an enclosure and the surface or substance to be monitored for alpha radiation. The first and second signal planes are maintained at the same voltage with respect to the electrically conductive enclosure, reducing leakage currents. In the presence of alpha radiation and radioactive gas decay, the signal from the first signal plane is proportional to both the surface alpha radiation and to the airborne radioactive gas, while the signal from the second signal plane is proportional only to the airborne radioactive gas. The difference between these two signals is proportional to the surface alpha radiation alone. 5 figs.

  5. Background canceling surface alpha detector

    DOE Patents [OSTI]

    MacArthur, Duncan W. (Los Alamos, NM); Allander, Krag S. (Ojo Caliente, NM); Bounds, John A. (Los Alamos, NM)

    1996-01-01

    A background canceling long range alpha detector which is capable of providing output proportional to both the alpha radiation emitted from a surface and to radioactive gas emanating from the surface. The detector operates by using an electrical field between first and second signal planes, an enclosure and the surface or substance to be monitored for alpha radiation. The first and second signal planes are maintained at the same voltage with respect to the electrically conductive enclosure, reducing leakage currents. In the presence of alpha radiation and radioactive gas decay, the signal from the first signal plane is proportional to both the surface alpha radiation and to the airborne radioactive gas, while the signal from the second signal plane is proportional only to the airborne radioactive gas. The difference between these two signals is proportional to the surface alpha radiation alone.

  6. Demonstration of a plasma mirror based on a laminar flow water film

    SciTech Connect (OSTI)

    Panasenko, Dmitriy; Shu, Anthony; Gonsalves, Anthony; Nakamura, Kei; Matlis, Nicholas; Toth, Csaba; Leemans, Wim

    2011-07-22

    A plasma mirror based on a laminar water film with low flow speed 0.5-2 cm/s has been developed and characterized, for use as an ultrahigh intensity optical reflector. The use of flowing water as atarget surface automatically results in each laser pulse seeing a new interaction surface and avoids the need for mechanical scanning of the target surface. In addition, the breakdown of water does notproduce contaminating debris that can be deleterious to vacuum chamber conditions and optics, such as is the case when using conventional solid targets. The mirror exhibits 70percent reflectivity, whilemaintaining high-quality of the reflected spot.

  7. Demonstration of a plasma mirror based on a laminar flow water film

    SciTech Connect (OSTI)

    Panasenko, Dmitriy; Shu, Anthony J.; Gonsalves, Anthony; Nakamura, Kei; Matlis, Nicholas H.; Toth, Csaba; Leemans, Wim P. [Lawrence Berkeley National Laboratory, University of California, Berkeley, California 94720 (United States)

    2010-08-15

    A plasma mirror based on a laminar water film with low flow speed (0.5-2 cm/s) has been developed and characterized, for use as an ultrahigh intensity optical reflector. The use of flowing water as a target surface automatically results in each laser pulse seeing a new interaction surface and avoids the need for mechanical scanning of the target surface. In addition, the breakdown of water does not produce contaminating debris that can be deleterious to vacuum chamber conditions and optics, such as is the case when using conventional solid targets. The mirror exhibits 70% reflectivity, while maintaining high-quality of the reflected spot.

  8. Wadter Resources Data Ohio: Water year 1994. Volume 2, St. Lawrence River Basin and Statewide Project Data

    SciTech Connect (OSTI)

    1994-12-31

    The Water Resources Division of the US Geological Survey (USGS), in cooperation with State agencies, obtains a large amount of data each water year (a water year is the 12-month period from October 1 through September 30 and is identified by the calendar year in which it ends) pertaining to the water resources of Ohio. These data, accumulated during many years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make these data readily available to interested parties outside the USGS, they are published annually in this report series entitled ``Water Resources Data--Ohio.`` This report (in two volumes) includes records on surface water and ground water in the State. Specifically, it contains: (1) Discharge records for streamflow-gaging stations, miscellaneous sites, and crest-stage stations; (2) stage and content records for streams, lakes, and reservoirs; (3) water-quality data for streamflow-gaging stations, wells, synaptic sites, and partial-record sites; and (4) water-level data for observation wells. Locations of lake- and streamflow-gaging stations, water-quality stations, and observation wells for which data are presented in this volume are shown in figures ga through 8b. The data in this report represent that part of the National Water Data System collected by the USGS and cooperating State and Federal agencies in Ohio. This series of annual reports for Ohio began with the 1961 water year with a report that contained only data relating to the quantities of surface water. For the 1964 water year, a similar report was introduced that contained only data relating to water quality. Beginning with the 1975 water year, the report was changed to present (in two to three volumes) data on quantities of surface water, quality of surface and ground water, and ground-water levels.

  9. Guide to Colorado Well Permits, Water Rights, and Water Administration...

    Open Energy Info (EERE)

    Colorado Well Permits, Water Rights, and Water Administration Jump to: navigation, search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - GuideHandbook:...

  10. Santa Clara Water & Sewer- Solar Water Heating Program

    Broader source: Energy.gov [DOE]

    In 1975, the City of Santa Clara established the nation's first municipal solar utility. Under the Solar Water Heating Program, the Santa Clara Water & Sewer Utilities Department supplies,...

  11. Enhancement of Zirconolite Dissolution Due to Water Radiolysis

    SciTech Connect (OSTI)

    Tribet, Magaly; Moncoffre, Nathalie

    2007-07-01

    Zirconolite is a candidate host material for conditioning minor tri- and tetra-valent actinides arising from enhanced nuclear spent fuel reprocessing and partitioning, in the case of disposal of the nuclear waste. Its chemical durability has been studied here under charged particle-induced radiolysis (He{sup 2+} and proton external beams) to identify the possible effects of water radiolysis on the dissolution rates in pure water and to describe the alteration mechanisms. Two experimental geometries have been used in order to evaluate the influence of the following parameters: solid irradiation, water radiolysis. In the first geometry the beam gets through the sample before stopping at the surface/water interface. In the second one the beam stops before the surface/water interface. Results on the elemental releases due to the enhanced dissolution of the zirconolite surface during charged particle-induced irradiation of water are presented. Under radiolysis, an increase of one order of magnitude is observed in the Ti, Zr and Nd elemental releases. No difference in the total elemental releases can be noticed when the solid is also irradiated. (authors)

  12. Hydrogen Production: Photoelectrochemical Water Splitting

    Broader source: Energy.gov [DOE]

    In photoelectrochemical (PEC) water splitting, hydrogen is produced from water using sunlight and specialized semiconductors called photoelectrochemical materials, which use light energy to directly dissociate water molecules into hydrogen and oxygen.

  13. ITP Nanomanufacturing: Manufacturing of Surfaces with Nanoscale...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Manufacturing of Surfaces with Nanoscale and Microscale Features ITP Nanomanufacturing: Manufacturing of Surfaces with Nanoscale and Microscale Features PDF icon...

  14. Ground-water data for 1990--91 and ground-water withdrawals for 1951--91, Nevada Test Site and vicinity, Nye County, Nevada

    SciTech Connect (OSTI)

    Wood, D.B.; Reiner, S.R.

    1996-12-31

    This report presents selected ground-water data collected from wells and test holes at and in the vicinity of the Nevada Test Site. Depth-to-water measurements were made at 74 sites at and in the vicinity of the Nevada Test Site during water years 1990--91. Measured depths to water ranged from 301 to 2,215 feet below land surface and measured altitudes of the ground-water surface at the Nevada Test Site ranged from 2,091 to 6,083 feet above sea level. Depth-to-water measurements were obtained by a combination of wire-line, electric-tape, iron-horse, and steel-tape methods. Available historic withdrawal and depth-to-water data for ground-water supply wells have been included to show changes through time. Water samples were collected and analyzed for tritium concentrations at 15 sites during water years 1990--91. Tritium concentrations in bailed water samples ranged from below detection limits to 5,550,000 picocuries per liter. Tritium concentrations in samples from three wells exceeded drinking water standards established by the US Environmental Protection Agency. All three wells are separate piezometers contained within a single test hole near an area of extensive underground nuclear testing.

  15. Super recycled water: quenching computers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Super recycled water: quenching computers Super recycled water: quenching computers New facility and methods support conserving water and creating recycled products. Using reverse osmosis to "super purify" water allows the system to reuse water and cool down our powerful yet thirsty computers. January 30, 2014 Super recycled water: quenching computers LANL's Sanitary Effluent Reclamation Facility, key to reducing the Lab's discharge of liquid. Millions of gallons of industrial

  16. Molded polymer solar water heater

    DOE Patents [OSTI]

    Bourne, Richard C.; Lee, Brian E.

    2004-11-09

    A solar water heater has a rotationally-molded water box and a glazing subassembly disposed over the water box that enhances solar gain and provides an insulating air space between the outside environment and the water box. When used with a pressurized water system, an internal heat exchanger is integrally molded within the water box. Mounting and connection hardware is included to provide a rapid and secure method of installation.

  17. NREL: Sustainable NREL - Water Efficiency

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Efficiency A photo of water spilling out of a downspout from the roof of a multi-story office building. NREL conserves water in a number of innovative ways. A photo of water passing through a landscaped area. Rain water from NREL's Research Support Facility passes through landscaped areas before discharging into Lena Gulch. To remain resilient in the arid climate of the southwest, NREL is committed to the efficient use of water throughout the laboratory. Best Practices All new buildings on

  18. Atomic and molecular layer deposition for surface modification

    SciTech Connect (OSTI)

    Vh-Nissi, Mika; Sievnen, Jenni; Salo, Erkki; Heikkil, Pirjo; Kentt, Eija; Johansson, Leena-Sisko; Koskinen, Jorma T.; Harlin, Ali

    2014-06-01

    Atomic and molecular layer deposition (ALD and MLD, respectively) techniques are based on repeated cycles of gassolid surface reactions. A partial monolayer of atoms or molecules is deposited to the surface during a single deposition cycle, enabling tailored film composition in principle down to molecular resolution on ideal surfaces. Typically ALD/MLD has been used for applications where uniform and pinhole free thin film is a necessity even on 3D surfaces. However, thin even non-uniform atomic and molecular deposited layers can also be used to tailor the surface characteristics of different non-ideal substrates. For example, print quality of inkjet printing on polymer films and penetration of water into porous nonwovens can be adjusted with low-temperature deposited metal oxide. In addition, adhesion of extrusion coated biopolymer to inorganic oxides can be improved with a hybrid layer based on lactic acid. - Graphical abstract: Print quality of a polylactide film surface modified with atomic layer deposition prior to inkjet printing (360 dpi) with an aqueous ink. Number of printed dots illustrated as a function of 0, 5, 15 and 25 deposition cycles of trimethylaluminum and water. - Highlights: ALD/MLD can be used to adjust surface characteristics of films and fiber materials. Hydrophobicity after few deposition cycles of Al{sub 2}O{sub 3} due to e.g. complex formation. Same effect on cellulosic fabrics observed with low temperature deposited TiO{sub 2}. Different film growth and oxidation potential with different precursors. Hybrid layer on inorganic layer can be used to improve adhesion of polymer melt.

  19. System for treating produced water

    DOE Patents [OSTI]

    Sullivan, Enid J. (Los Alamos, NM); Katz, Lynn (Austin, TX); Kinney, Kerry (Austin, TX); Bowman, Robert S. (Lemitar, NM); Kwon, Soondong (Kyungbuk, KR)

    2010-08-03

    A system and method were used to treat produced water. Field-testing demonstrated the removal of contaminants from produced water from oil and gas wells.

  20. Water Power | Open Energy Information

    Open Energy Info (EERE)

    Get Involved Help Apps Datasets Community Login | Sign Up Search Gateway Edit History Water Power Jump to: navigation, search Water Power Community Forum Provides the community...

  1. Water and Energy (18 activities)

    K-12 Energy Lesson Plans and Activities Web site (EERE)

    An inquiry-based curriculum that introduces students to the properties of water and using water as an energy source with the following activities

  2. Absorption Heat Pump Water Heater

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Water Heater Kyle Gluesenkamp Building Equipment Group, ETSD gluesenkampk@ornl.gov 865-241-2952 April 3, 2013 CRADA - GE Development of High Performance Residential Gas Water ...

  3. Water Heating | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Water Heating Water Heating Low-flow fixtures will help you reduce your hot water use and save money on your water heating bills. | Photo courtesy of Huntington Veterans Medical Ctr. Low-flow fixtures will help you reduce your hot water use and save money on your water heating bills. | Photo courtesy of Huntington Veterans Medical Ctr. Water heating accounts for about 18% of your home's energy use. Reducing your hot water use, employing energy-saving strategies, and choosing an energy efficient

  4. Embedded fiducials in optical surfaces

    DOE Patents [OSTI]

    Sommargren, Gary E. (Santa Cruz, CA)

    2000-01-01

    Embedded fiducials are provided in optical surfaces and a method for embedding the fiducials. Fiducials, or marks on a surface, are important for optical fabrication and alignment, particularly when individual optical elements are aspheres. Fiducials are used during the course of the polishing process to connect interferometric data, and the equation describing the asphere, to physical points on the optic. By embedding fiducials below the surface of the optic and slightly outside the clear aperture of the optic, the fiducials are not removed by polishing, do not interfere with the polishing process, and do not affect the performance of the finished optic.

  5. Water and Gold: A Promising Mix for Future Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water and Gold: A Promising Mix for Future Batteries Water and Gold: A Promising Mix for Future Batteries Berkeley Lab Study Reveals Molecular Structure of Water at Gold Electrodes October 23, 2014 Contact: Rachel Berkowitz, 510-486-7254, rberkowitz@lbl.gov When a solid material is immersed in a liquid, the liquid immediately next to its surface differs from that of the bulk liquid at the molecular level. This interfacial layer is critical to our understanding of a diverse set of phenomena from

  6. Simple, benign, aqueous-based amination of polycarbonate surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    VanDelinder, Virginia; Wheeler, David R.; Small, Leo J.; Brumbach, Michael T.; Spoerke, Erik D.; Henderson, Ian; Bachand, George D.

    2015-03-18

    Here we report a simple, safe, environmentally-friendly aqueous method that uses diamines to functionalize a polycarbonate surface with amino groups. We demonstrate the ability of this facile method to serve as a foundation upon which other functionalities may be attached, including anti-fouling coatings and oriented membrane proteins. The use of water as the solvent for the functionalization ensures that solvent induced swelling does not affect the optical or mechanical properties of the polycarbonate.

  7. Detachment of Liquid-Water Droplets from Gas-Diffusion Layers

    SciTech Connect (OSTI)

    Das, Prodip K.; Grippin, Adam; Weber, Adam Z.

    2011-07-01

    A critical issue for optimal water management in proton-exchange-membrane fuel cells at lower temperatures is the removal of liquid water from the cell. This pathway is intimately linked with the phenomena of liquid-water droplet removal from surface of the gas-diffusion layer and into the flow channel. Thus, a good understanding of liquid-water transport and droplet growth and detachment from the gas-diffusion layer is critical. In this study, liquid-water droplet growth and detachment on the gas-diffusion layer surfaces are investigated experimentally to improve the understating of water transport through and removal from gas-diffusion layers. An experiment using a sliding-angle measurement is designed and used to quantify and directly measure the adhesion force for liquid-water droplets, and to understand the droplets? growth and detachment from the gas-diffusion layers.

  8. Tribological interaction between polytetrafluoroethylene and silicon oxide surfaces

    SciTech Connect (OSTI)

    Uar, A.; opuro?lu, M.; Suzer, S.; Baykara, M. Z.; Ar?kan, O.

    2014-10-28

    We investigated the tribological interaction between polytetrafluoroethylene (PTFE) and silicon oxide surfaces. A simple rig was designed to bring about a friction between the surfaces via sliding a piece of PTFE on a thermally oxidized silicon wafer specimen. A very mild inclination (?0.5) along the sliding motion was also employed in order to monitor the tribological interaction in a gradual manner as a function of increasing contact force. Additionally, some patterns were sketched on the silicon oxide surface using the PTFE tip to investigate changes produced in the hydrophobicity of the surface, where the approximate water contact angle was 45 before the transfer. The nature of the transferred materials was characterized by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). XPS results revealed that PTFE was faithfully transferred onto the silicon oxide surface upon even at the slightest contact and SEM images demonstrated that stable morphological changes could be imparted onto the surface. The minimum apparent contact pressure to realize the PTFE transfer is estimated as 5 kPa, much lower than reported previously. Stability of the patterns imparted towards many chemical washing processes lead us to postulate that the interaction is most likely to be chemical. Contact angle measurements, which were carried out to characterize and monitor the hydrophobicity of the silicon oxide surface, showed that upon PTFE transfer the hydrophobicity of the SiO{sub 2} surface could be significantly enhanced, which might also depend upon the pattern sketched onto the surface. Contact angle values above 100 were obtained.

  9. Water Transport Within the STack: Water Transport Exploratory Studies |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Within the STack: Water Transport Exploratory Studies Water Transport Within the STack: Water Transport Exploratory Studies Part of a $100 million fuel cell award announced by DOE Secretary Bodman on Oct. 25, 2006. PDF icon 2_lanl.pdf More Documents & Publications Water Transport Exploratory Studies Fuel Cell Kickoff Meeting Agenda

  10. THE STICKINESS OF MICROMETER-SIZED WATER-ICE PARTICLES

    SciTech Connect (OSTI)

    Gundlach, B.; Blum, J.

    2015-01-01

    Water ice is one of the most abundant materials in dense molecular clouds and in the outer reaches of protoplanetary disks. In contrast to other materials (e.g., silicates), water ice is assumed to be stickier due to its higher specific surface energy, leading to faster or more efficient growth in mutual collisions. However, experiments investigating the stickiness of water ice have been scarce, particularly in the astrophysically relevant micrometer-sized region and at low temperatures. In this work, we present an experimental setup to grow aggregates composed of ?m-sized water-ice particles, which we used to measure the sticking and erosion thresholds of the ice particles at different temperatures between 114 K and 260 K. We show with our experiments that for low temperatures (below ?210 K), ?m-sized water-ice particles stick below a threshold velocity of 9.6 m s{sup 1}, which is approximately 10times higher than the sticking threshold of ?m-sized silica particles. Furthermore, erosion of the grown ice aggregates is observed for velocities above 15.3 m s{sup 1}. A comparison of the experimentally derived sticking threshold with model predictions is performed to determine important material properties of water ice, i.e., the specific surface energy and the viscous relaxation time. Our experimental results indicate that the presence of water ice in the outer reaches of protoplanetary disks can enhance the growth of planetesimals by direct sticking of particles.

  11. Small surface coal mine operators handbook. Final report

    SciTech Connect (OSTI)

    Tourbier, J.T.; Westmacott, R.

    1980-06-01

    The purpose of this handbook is to interpret the Regulations of the Surface Mining Control and Reclamation Act of 1977 (Public Law 95-87) (hereafter referred to as the Act) as they affect the operators of small surface coal mines. Further, the purpose of this handbook is to make it easier for the small operator to compare his operation with the act in order to determine compliance with the regulations. Part 795 of the Regulations deals specifically with the Small Operator Assistance Program. This program relieves the operator of the cost of carrying out certain hydrologic and geologic analyses required by the Regulations. The emphasis of this handbook is on the protection of water resources during mining and reclamation operations. As almost all the operations in surface mining directly or indirectly affect water the authors have included some operations which may only marginally affect water quality or hydrology. Anthracite mining, lignite mining, coal processing, refuse disposal, and slurry disposal are not covered in this handbook.

  12. Fuel cell water transport

    DOE Patents [OSTI]

    Vanderborgh, Nicholas E. (Los Alamos, NM); Hedstrom, James C. (Los Alamos, NM)

    1990-01-01

    The moisture content and temperature of hydrogen and oxygen gases is regulated throughout traverse of the gases in a fuel cell incorporating a solid polymer membrane. At least one of the gases traverses a first flow field adjacent the solid polymer membrane, where chemical reactions occur to generate an electrical current. A second flow field is located sequential with the first flow field and incorporates a membrane for effective water transport. A control fluid is then circulated adjacent the second membrane on the face opposite the fuel cell gas wherein moisture is either transported from the control fluid to humidify a fuel gas, e.g., hydrogen, or to the control fluid to prevent excess water buildup in the oxidizer gas, e.g., oxygen. Evaporation of water into the control gas and the control gas temperature act to control the fuel cell gas temperatures throughout the traverse of the fuel cell by the gases.

  13. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    x-ray spectroscopy at ALS Beamline 4.0.2 to study the magnetism of proton-irradiated graphite surfaces in order to understand the effects of hydrogen (i.e. protons) on the...

  14. Surface treatment of ceramic articles

    DOE Patents [OSTI]

    Komvopoulos, K.; Brown, I.G.; Wei, B.; Anders, S.; Anders, A.; Bhatia, C.S.

    1998-12-22

    A process is disclosed for producing an article with improved ceramic surface properties including providing an article having a ceramic surface, and placing the article onto a conductive substrate holder in a hermetic enclosure. Thereafter a low pressure ambient is provided in the hermetic enclosure. A plasma including ions of solid materials is produced the ceramic surface of the article being at least partially immersed in a macroparticle free region of the plasma. While the article is immersed in the macroparticle free region, a bias of the substrate holder is biased between a low voltage at which material from the plasma condenses on the surface of the article and a high negative voltage at which ions from the plasma are implanted into the article. 15 figs.

  15. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Print From organic matter to pencil lead, carbon is a versatile element. Now, another use has been found: magnets. One would not expect pure...

  16. Surface treatment of ceramic articles

    DOE Patents [OSTI]

    Komvopoulos, Kyriakos (Orinda, CA); Brown, Ian G. (Berkeley, CA); Wei, Bo (Daly City, CA); Anders, Simone (Albany, CA); Anders, Andre (Albany, CA); Bhatia, C. Singh (Morgan Hill, CA)

    1998-01-01

    A process for producing an article with improved ceramic surface properties including providing an article having a ceramic surface, and placing the article onto a conductive substrate holder in a hermetic enclosure. Thereafter a low pressure ambient is provided in the hermetic enclosure. A plasma including ions of solid materials is produced the ceramic surface of the article being at least partially immersed in a macroparticle free region of the plasma. While the article is immersed in the macroparticle free region, a bias of the substrate holder is biased between a low voltage at which material from the plasma condenses on the surface of the article and a high negative voltage at which ions from the plasma are implanted into the article.

  17. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Now, researchers are using x-ray spectroscopy at ALS Beamline 4.0.2 to study the magnetism of proton-irradiated graphite surfaces in order to understand the effects of...

  18. Water, law, science

    SciTech Connect (OSTI)

    Narasimhan, T.N.

    2007-10-17

    In a world with water resources severely impacted bytechnology, science must actively contribute to water law. To this end,this paper is an earth scientist s attempt to comprehend essentialelements of water law, and to examine their connections to science.Science and law share a common logical framework of starting with apriori prescribed tenets, and drawing consistent inferences. In science,observationally established physical laws constitute the tenets, while inlaw, they stem from social values. The foundations of modern water law inEurope and the New World were formulated nearly two thousand years ago byRoman jurists who were inspired by Greek philosophy of reason.Recognizing that vital natural elements such as water, air, and the seawere governed by immutable natural laws, they reasoned that theseelements belonged to all humans, and therefore cannot be owned as privateproperty. Legally, such public property was to be governed by jusgentium, the law of all people or the law of all nations. In contrast,jus civile or civil law governed private property. Remarkably, jusgentium continues to be relevant in our contemporary society in whichscience plays a pivotal role in exploiting vital resources common to all.This paper examines the historical roots of modern water law, followstheir evolution through the centuries, and examines how the spirit ofscience inherent in jus gentium is profoundly influencing evolving waterand environmental laws in Europe, the United States and elsewhere. In atechnological world, scientific knowledge has to lie at the core of waterlaw. Yet, science cannot formulate law. It is hoped that a philosophicalunderstanding of the relationships between science and law willcontribute to their constructively coming together in the service ofsociety.

  19. Accelerated Aging of Roofing Surfaces

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Accelerated aging of roofing surfaces Hugo Destaillats, Ph.D. Lawrence Berkeley National Laboratory HDestaillats@LBL.gov (510) 486-5897 http://HeatIsland.LBL.gov April 4, 2013 Development of Advanced Building Envelope Surface Materials & Integration of Artificial Soiling and Weathering in a Commercial Weatherometer New York Times, 30 July 2009 2010 2012 Challenge: speed the development of high performance building envelope materials that resist soiling, maintain high solar reflectance, and

  20. Corrosion-resistant metal surfaces

    DOE Patents [OSTI]

    Sugama, Toshifumi (Wading River, NY)

    2009-03-24

    The present invention relates to metal surfaces having thereon an ultrathin (e.g., less than ten nanometer thickness) corrosion-resistant film, thereby rendering the metal surfaces corrosion-resistant. The corrosion-resistant film includes an at least partially crosslinked amido-functionalized silanol component in combination with rare-earth metal oxide nanoparticles. The invention also relates to methods for producing such corrosion-resistant films.