National Library of Energy BETA

Sample records for rh rh rh

  1. RH Packaging Program Guidance

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2008-01-12

    The purpose of this program guidance document is to provide the technical requirements for use, operation, inspection, and maintenance of the RH-TRU 72-B Waste Shipping Package (also known as the "RH-TRU 72-B cask") and directly related components. This document complies with the requirements as specified in the RH-TRU 72-B Safety Analysis Report for Packaging (SARP), and Nuclear Regulatory Commission (NRC) Certificate of Compliance (C of C) 9212. If there is a conflict between this document and the SARP and/or C of C, the C of C shall govern. The C of C states: "...each package must be prepared for shipment and operated in accordance with the procedures described in Chapter 7.0, Operating Procedures, of the application." It further states: "...each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application." Chapter 9.0 of the SARP tasks the Waste Isolation Pilot Plant (WIPP) Management and Operating (M&O) Contractor with assuring the packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with Title 10 Code of Federal Regulations (CFR) §71.8, "Deliberate Misconduct." Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the U.S. Department of Energy (DOE) Carlsbad Field Office (CBFO) shall be notified immediately. The CBFO will evaluate the issue and notify the NRC if required.In accordance with 10 CFR Part 71, "Packaging and Transportation of Radioactive Material," certificate holders, packaging users, and contractors or subcontractors who use, design, fabricate, test, maintain, or modify the packaging shall post copies of (1) 10 CFR Part 21, "Reporting of Defects and Noncompliance," regulations, (2) Section 206 of the Energy Reorganization Act of 1974, and (3) NRC Form 3, Notice to Employees. These documents must be posted in a conspicuous location where the activities subject to these regulations are conducted. This document details the instructions to be followed to operate, maintain, and test the RH-TRU 72-B packaging. This Program Guidance standardizes instructions for all users. Users shall follow these instructions or equivalent approved instructions. Following these instructions assures that operations meet the requirements of the SARP.

  2. RH-TRU Waste Content Codes (RH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2007-08-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: • A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. • A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is “3.” The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR limits based on a 10-day shipping period (rather than the standard 60-day shipping period) may be used as specified in an approved content code. Requests for new or revised content codes may be submitted to the WIPP RH-TRU Payload Engineer for review and approval, provided all RH-TRAMPAC requirements are met.

  3. RH Packaging Program Guidance

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2006-11-07

    The purpose of this program guidance document is to provide the technical requirements for use, operation, inspection, and maintenance of the RH-TRU 72-B Waste Shipping Package and directly related components. This document complies with the requirements as specified in the RH-TRU 72-B Safety Analysis Report for Packaging (SARP), and Nuclear Regulatory Commission (NRC) Certificate of Compliance (C of C) 9212. If there is a conflict between this document and the SARP and/or C of C, the C of C shall govern. The C of C states: "...each package must be prepared for shipment and operated in accordance with the procedures described in Chapter 7.0, Operating Procedures, of the application." It further states: "...each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application." Chapter 9.0 of the SARP tasks the Waste Isolation Pilot Plant (WIPP) Management and Operating (M&O) Contractor with assuring the packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with 10 Code of Federal Regulations (CFR) §71.8, "Deliberate Misconduct." Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the U.S. Department of Energy (DOE) Carlsbad Field Office (CBFO) shall be notified immediately. CBFO will evaluate the issue and notify the NRC if required. In accordance with 10 CFR Part 71, "Packaging and Transportation of Radioactive Material," certificate holders, packaging users, and contractors or subcontractors who use, design, fabricate, test, maintain, or modify the packaging shall post copies of (1) 10 CFR Part 21, "Reporting of Defects and Noncompliance," regulations, (2) Section 206 of the Energy Reorganization Act of 1974, and (3) NRC Form 3, Notice to Employees. These documents must be posted in a conspicuous location where the activities subject to these regulations are conducted. This document details the instructions to be followed to operate, maintain, and test the RH-TRU 72-B packaging. This Program Guidance standardizes instructions for all users. Users shall follow these instructions or equivalent approved instructions. Following these instructions assures that operations meet the requirements of the SARP.

  4. RH-TRU Waste Content Codes (RH TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions

    2007-05-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: • A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. • A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is “3.” The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR limits based on a 10-day shipping period (rather than the standard 60-day shipping period) may be used as specified in an approved content code.

  5. Comment on "Catalytic Activity of the Rh Surface Oxide: CO Oxidation over Rh(111)

    E-Print Network [OSTI]

    Goodman, Wayne

    . Obviously, heating Rh in pure oxygen to T ) 230 °C and above will lead to the formation of surface Rh oxideComment on "Catalytic Activity of the Rh Surface Oxide: CO Oxidation over Rh(111) under Realistic suggest the importance of a surface oxide phase for high CO2 formation in CO-O2 reactions. However

  6. Radiosondes Corrected for Inaccuracy in RH Measurements

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Miloshevich, Larry

    2008-01-15

    Corrections for inaccuracy in Vaisala radiosonde RH measurements have been applied to ARM SGP radiosonde soundings. The magnitude of the corrections can vary considerably between soundings. The radiosonde measurement accuracy, and therefore the correction magnitude, is a function of atmospheric conditions, mainly T, RH, and dRH/dt (humidity gradient). The corrections are also very sensitive to the RH sensor type, and there are 3 Vaisala sensor types represented in this dataset (RS80-H, RS90, and RS92). Depending on the sensor type and the radiosonde production date, one or more of the following three corrections were applied to the RH data: Temperature-Dependence correction (TD), Contamination-Dry Bias correction (C), Time Lag correction (TL). The estimated absolute accuracy of NIGHTTIME corrected and uncorrected Vaisala RH measurements, as determined by comparison to simultaneous reference-quality measurements from Holger Voemel's (CU/CIRES) cryogenic frostpoint hygrometer (CFH), is given by Miloshevich et al. (2006).

  7. Radiosondes Corrected for Inaccuracy in RH Measurements

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Miloshevich, Larry

    Corrections for inaccuracy in Vaisala radiosonde RH measurements have been applied to ARM SGP radiosonde soundings. The magnitude of the corrections can vary considerably between soundings. The radiosonde measurement accuracy, and therefore the correction magnitude, is a function of atmospheric conditions, mainly T, RH, and dRH/dt (humidity gradient). The corrections are also very sensitive to the RH sensor type, and there are 3 Vaisala sensor types represented in this dataset (RS80-H, RS90, and RS92). Depending on the sensor type and the radiosonde production date, one or more of the following three corrections were applied to the RH data: Temperature-Dependence correction (TD), Contamination-Dry Bias correction (C), Time Lag correction (TL). The estimated absolute accuracy of NIGHTTIME corrected and uncorrected Vaisala RH measurements, as determined by comparison to simultaneous reference-quality measurements from Holger Voemel's (CU/CIRES) cryogenic frostpoint hygrometer (CFH), is given by Miloshevich et al. (2006).

  8. RH-TRU Waste Content Codes

    SciTech Connect (OSTI)

    Washington TRU Solutions

    2007-07-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: • A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. • A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is “3.” The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR limits based on a 10-day shipping period (rather than the standard 60-day shipping period) may be used as specified in an approved content code. Requests for new or revised content codes may be submitted to the WIPP RH-TRU Payload Engineer for review and approval, provided all RH-TRAMPAC requirements are met.

  9. Check for chirality in {sup 102}Rh

    SciTech Connect (OSTI)

    Tonev, D.; Goutev, N.; Yavahchova, M. S.; Petkov, P.; Angelis, G. de; Bhowmik, R. K.; Singh, R. P.; Muralithar, S.; Madhavan, N.; Kumar, R.; Raju, M. Kumar; Kaur, J.; Mahanto, G.; Singh, A.; Kaur, N.; Garg, R.; Sukla, A.; Marinov, Ts. K.; Brant, S.

    2012-10-20

    Excited states in {sup 102}Rh, populated by the fusion-evaporation reaction {sup 94}Zr({sup 11}B,3n){sup 102}Rh at a beam energy of 36 MeV, were studied using the INGA spectrometer at IUAC, New Delhi. The angular correlations and the electromagnetic character of some of the gamma-ray transitions observed were investigated in details. A new chiral candidate sister band was found in the level-scheme of {sup 102}Rh. Lifetimes of exited states in {sup 102}Rh were measured by means of the Doppler-shift attenuation technique. The experimental results do not support the presence of static chirality in {sup 102}Rh.

  10. University Policy No.: RH8205 Classification: Research

    E-Print Network [OSTI]

    Victoria, University of

    which requires, as a condition of deducting expenses, that the type of research carried out under the #12;research project be a type of research that is different from the type of research work ordinarilyUniversity Policy No.: RH8205 Classification: Research RESEARCH GRANTS IN LIEU OF Approving

  11. Porous Alumina Based Capacitive MEMS RH Sensor

    E-Print Network [OSTI]

    Juhasz, L; Timar-Horvath, Veronika; Desmulliez, Marc; Dhariwal, Resh

    2008-01-01

    The aim of a joint research and development project at the BME and HWU is to produce a cheap, reliable, low-power and CMOS-MEMS process compatible capacitive type relative humidity (RH) sensor that can be incorporated into a state-of-the-art, wireless sensor network. In this paper we discuss the preparation of our new capacitive structure based on post-CMOS MEMS processes and the methods which were used to characterize the thin film porous alumina sensing layer. The average sensitivity is approx. 15 pF/RH% which is more than a magnitude higher than the values found in the literature. The sensor is equipped with integrated resistive heating, which can be used for maintenance to reduce drift, or for keeping the sensing layer at elevated temperature, as an alternative method for temperature-dependence cancellation.

  12. Chemical and Morphological Evolution of Nanoporous Pd/Rh Alloy...

    Office of Scientific and Technical Information (OSTI)

    Chemical and Morphological Evolution of Nanoporous PdRh Alloy Particles for Hydrogen Storage. Citation Details In-Document Search Title: Chemical and Morphological Evolution of...

  13. Anomalous emissions of 103mRh biphoton transitions

    E-Print Network [OSTI]

    Yao Cheng; Bing Xia

    2009-08-06

    In this report, the anomalous emissions, centered on the one half transition energy 39.76/2 keV, are observed from the long-lived Mossbauer state of 103mRh excited by bremsstrahlung exposure. Strong coupling with identical nuclei in Rh crystals opens cascade channels for biphoton transitions.

  14. Origin of room temperature ferromagnetic moment in Rh-rich Rh/Fe multilayer thin films

    E-Print Network [OSTI]

    Laughlin, David E.

    doing the magnetic measure- ments, a constant in-plane field of 0.8 T was applied to satu- rate the film in the antiferromagnetic AFM to ferromagnetic FM state on heating above 350 K and switch back on cooling, with a hysteresis. This property makes FeRh a very attractive choice as a write-assist layer material for low temperature heat

  15. Effects of social cues on GnRH-I, GnRH-II, and reproductive physiology in female house

    E-Print Network [OSTI]

    Murphy, Troy G.

    Effects of social cues on GnRH-I, GnRH-II, and reproductive physiology in female house sparrows Neuroscience Institute, University of California, Berkeley, USA c Department of Animal Physiology(s) of male social cues on the peripheral and neural responses of female house sparrows (Passer domesticus

  16. Ethanol Oxidation on the Ternary Pt–Rh–SnO2/C Electrocatalysts with Varied Pt:Rh:Sn ratios

    SciTech Connect (OSTI)

    Adzic, R.R.; Li, M.; Kowal, A.; Sasaki, K.; Marinkovic, N.; Su, D.; Korach, E.; Liu, P.

    2010-05-30

    Ternary Pt-Rh-SnO{sub 2}/C electrocatalysts with the atomic ratio Pt:Rh:Sn = 3:1:x, where x varies from 2 to 6, were synthesized using the modified polyol method followed by thermal treatment. Several techniques used to characterize these electrocatalysts showed they were composed of homogeneous PtRh alloy and SnO{sub 2}, having all three constituents coexisting in single nanoparticles with the average particle size around 1.4 nm and a narrow size distribution. While all the electrocatalysts investigated exhibited high catalytic activity for ethanol oxidation, the most active one had the composition with the Pt:Rh:Sn = 3:1:4 atomic ratio. These ternary-electrocatalysts effectively split the C-C bond in ethanol at room temperature in acidic solutions, which is verified using the in situ IRRAS technique.

  17. RESEARCH INVOLVING HUMANS University Policy No.: RH8105

    E-Print Network [OSTI]

    Victoria, University of

    1 RESEARCH INVOLVING HUMANS University Policy No.: RH8105 Classification: Research Approving: Mandated Review: September, 2017 Associated Procedures Procedures for Conducting Human Research PURPOSE 1.00 The purpose of this policy is to: a) set out provisions to ensure Research Involving Human Participants

  18. Quantitative EDS Analysis of Nanometer-Scale Core/Shell Pd/Rh...

    Office of Scientific and Technical Information (OSTI)

    Quantitative EDS Analysis of Nanometer-Scale CoreShell PdRh Structures. Citation Details In-Document Search Title: Quantitative EDS Analysis of Nanometer-Scale CoreShell PdRh...

  19. Superconductivity versus structural phase transition in the closely related Bi2Rh3.5S2 and Bi2Rh3S2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kaluarachchi, Udhara S.; Xie, Weiwei; Lin, Qisheng; Taufour, Valentin; Bud'ko, Sergey L.; Miller, Gordon J.; Canfield, Paul C.

    2015-05-19

    Single crystals of Bi2Rh3S2 and Bi2Rh3.5S2 were synthesized by solution growth, and the crystal structures and thermodynamic and transport properties of both compounds were studied. In the case of Bi2Rh3S2, a structural first-order transition at around 165 K is identified by single-crystal diffraction experiments, with clear signatures visible in resistivity, magnetization, and specific heat data. No superconducting transition for Bi2Rh3S2 was observed down to 0.5 K. In contrast, no structural phase transition at high temperature was observed for Bi2Rh3.5S2; however, bulk superconductivity with a critical temperature, Tc ? 1.7 K, was observed. The Sommerfeld coefficient ? and the Debye temperaturemore »(?D) were found to be 9.41 mJ mol–1K–2 and 209 K, respectively, for Bi2Rh3S2, and 22 mJ mol–1K–2 and 196 K, respectively, for Bi2Rh3.5S2. As a result, the study of the specific heat in the superconducting state of Bi2Rh3.5S2 suggests that Bi2Rh3.5S2 is a weakly coupled, BCS superconductor.« less

  20. Towards tailoring the magnetocaloric response in FeRh-based ternary compounds

    SciTech Connect (OSTI)

    Barua, Radhika Jiménez-Villacorta, Félix; Lewis, L. H.

    2014-05-07

    In this work, we demonstrate that the magnetocaloric response of FeRh-based compounds may be tailored for potential magnetic refrigeration applications by chemical modification of the FeRh lattice. Alloys of composition Fe(Rh{sub 1?x}A{sub x}) or (Fe{sub 1?x}B{sub x})Rh (A?=?Cu, Pd; B?=?Ni; 0?Rh-based systems were determined using isothermal M(H) curves measured in the vicinity of the magnetostructural temperature (T{sub t}). It is found that the FeRh working temperature range (?T{sub FWHM}) may be chemically tuned over a wide temperature range, 100?K???T???400?K. While elemental substitution consistently decreases the magnetic entropy change (?S{sub mag}) of the FeRh-based ternary alloys from that of the parent FeRh compound (?S{sub mag},{sub FeRh}???17?J/kg?K; ?S{sub mag,FeRh-ternary?=}?7–14?J/kg?K at H{sub app}?=?2?T), the net refrigeration capacity (RC), defined as the amount of heat that can be transferred during one magnetic refrigeration cycle, of the modified systems is significantly higher (RC{sub FeRh}???150?J/kg; RC{sub FeRh-ternary?=}?170–210?J/kg at H{sub app}?=?2?T). These results are attributed to stoichiometry-induced changes in the FeRh electronic band structure and beneficial broadening of the magnetostructural transition due to local chemical disorder.

  1. Electronic structure and magnetism of the Rh[l brace]001[r brace] surface

    SciTech Connect (OSTI)

    Wu, S.C. Physics Department, Peking University, Beijing 100871 ); Garrison, K. ); Begley, A.M.; Jona, F. ); Johnson, P.D. )

    1994-05-15

    Spin-polarized-photoemission experiments on clean Rh[l brace]001[r brace] show that the surface resonance at the [ital [bar M

  2. Evidence for Methane -Complexes in Reductive Elimination Reactions from TpRh(L)(CH3)H

    E-Print Network [OSTI]

    Jones, William D.

    Evidence for Methane -Complexes in Reductive Elimination Reactions from TpRh(L)(CH3)H Douglas D of methane from TpRh(L)(CH3)H in benzene/perfluorobenzene solvent mixtures is found to be dependent upon the concentration of benzene, indicating an associative component to the reductive elimination of methane. Both

  3. Bimetallic Ni-Rh catalysts with low amounts of Rh for the steam and autothermal reforming of n-butane for fuel-cell applications.

    SciTech Connect (OSTI)

    Ferrandon, M.; Kropf, A. J.; Krause, T.; Chemical Sciences and Engineering Division

    2010-05-15

    Mono-metallic nickel and rhodium catalysts and bimetallic Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}, CeZrO{sub 2} and CeMgOx were prepared and evaluated for catalyzing the steam and autothermal reforming of n-butane. The binary Ni-Rh supported on La-Al{sub 2}O{sub 3} catalysts with low weight loading of rhodium exhibited higher H{sub 2} yields than Ni or Rh alone. The Ni-Rh/CeZrO{sub 2} catalyst exhibited higher performance and no coke formation, compared to the same metals on other supports. A NiAl{sub 2}O{sub 4} spinel phase was obtained on all Ni and Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}. The presence of rhodium stabilized the spinel phase as well as NiOx species upon reforming while Ni alone was mostly reduced into metallic species. Extended X-ray absorption fine-structure analysis showed evidence of Ni-Rh alloy during preparation and even further after an accelerated aging at 900C in a H{sub 2}/H{sub 2}O atmosphere.

  4. Decomposition pathways of C2 oxygenates on Rh-modified tungsten carbide surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kelly, Thomas G.; Ren, Hui; Chen, Jingguang G.

    2015-03-27

    Ethanol decomposition on tungsten monocarbide (WC) and Rh-modified WC was investigated using ultrahigh vacuum (UHV) surface science experiments and density functional theory (DFT) calculations. DFT calculations indicated that the binding energies of ethanol and its decomposition intermediates on WC(0001) were modified by Rh, with Rh/WC(0001) showing similar values to those on Rh(111). Through temperature-programmed desorption (TPD) experiments on polycrystalline WC and Rh-modified WC, it was shown that the selectivity for ethanol decomposition was different on these surfaces. On WC, the C-O bond of ethanol was preferentially broken to produce ethylene; on Rh-modified WC, the C-C bond was broken to producemore »carbon monoxide and methane. In addition, high-resolution electron energy loss spectroscopy (HREELS) was used to determine likely surface intermediates. On Rh-modified WC, ethanol first formed ethoxy through O-H scission, then reacted through an aldehyde intermediate to form the C1 products.« less

  5. The effect of Fe-Rh alloying on CO hydrogenation to C2+ oxygenates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Palomino, Robert; Magee, Joseph W.; Llorca, Jordi; Senanayake, Sanjaya D.; White, Michael G.

    2015-05-20

    A combination of reactivity and structural studies using X-ray diffraction (XRD), pair distribution function (PDF), and transmission electron microscopy (TEM) was used to identify the active phases of Fe-modified Rh/TiO2 catalysts for the synthesis of ethanol and other C2+ oxygenates from CO hydrogenation. XRD and TEM confirm the existence of Fe–Rh alloys for catalyst with 1–7 wt% Fe and ~2 wt% Rh. Rietveld refinements show that FeRh alloy content increases with Fe loading up to ~4 wt%, beyond which segregation to metallic Fe becomes favored over alloy formation. Catalysts that contain Fe metal after reduction exhibit some carburization as evidencedmore »by the formation of small amounts of Fe3C during CO hydrogenation. Analysis of the total Fe content of the catalysts also suggests the presence of FeOx also increased under reaction conditions. Reactivity studies show that enhancement of ethanol selectivity with Fe loading is accompanied by a significant drop in CO conversion. Comparison of the XRD phase analyses with selectivity suggests that higher ethanol selectivity is correlated with the presence of Fe–Rh alloy phases. As a result, the interface between Fe and Rh serves to enhance the selectivity of ethanol, but suppresses the activity of the catalyst which is attributed to the blocking or modifying of Rh active sites.« less

  6. Magnitude of the magnetic exchange interaction in the heavy-fermion antiferromagnet CeRhIn?

    SciTech Connect (OSTI)

    Das, Pinaki [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Lin, S. -Z. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Ghimire, N.? J. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Huang, K. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Univ. of California, San Diego, La Jolla, CA (United States); Ronning, F. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Bauer, E.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Thompson, J.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Batista, C.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Ehlers, G. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Janoschek, M. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

    2014-12-01

    We have used high-resolution neutron spectroscopy experiments to determine the complete spin wave spectrum of the heavy-fermion antiferromagnet CeRhIn?. The spin wave dispersion can be quantitatively reproduced with a simple frustrated J??J? model that also naturally explains the magnetic spin-spiral ground state of CeRhIn? and yields a dominant in-plane nearest-neighbor magnetic exchange constant J?=0.74(3)??meV. Our results pave the way to a quantitative understanding of the rich low-temperature phase diagram of the prominent CeTIn? (T = Co, Rh, Ir) class of heavy-fermion materials.

  7. The valence band structure of Ag{sub x}Rh{sub 1–x} alloy nanoparticles

    SciTech Connect (OSTI)

    Yang, Anli; Sakata, Osami; Kusada, Kohei; Kobayashi, Hirokazu; Yayama, Tomoe; Ishimoto, Takayoshi; Yoshikawa, Hideki; Koyama, Michihisa; and others

    2014-10-13

    The valence band (VB) structures of face-centered-cubic Ag-Rh alloy nanoparticles (NPs), which are known to have excellent hydrogen-storage properties, were investigated using bulk-sensitive hard x-ray photoelectron spectroscopy. The observed VB spectra profiles of the Ag-Rh alloy NPs do not resemble simple linear combinations of the VB spectra of Ag and Rh NPs. The observed VB hybridization was qualitatively reproduced via a first-principles calculation. The electronic structure of the Ag{sub 0.5}Rh{sub 0.5} alloy NPs near the Fermi edge was strikingly similar to that of Pd NPs, whose superior hydrogen-storage properties are well known.

  8. W.T.; Rainey, R.H. 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS;...

    Office of Scientific and Technical Information (OSTI)

    thorium fuel reprocessing experience Brooksbank, R.E.; McDuffee, W.T.; Rainey, R.H. 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; NUCLEAR MATERIALS DIVERSION; SAFEGUARDS; SPENT FUELS;...

  9. Model for the Prediction of the Hydriding Thermodynamics of Pd-Rh-Co Ternary Alloys

    SciTech Connect (OSTI)

    Teter, D.F.; Thoma, D.J.

    1999-03-01

    A dilute solution model (with respect to the substitutional alloying elements) has been developed, which accurately predicts the hydride formation and decomposition thermodynamics and the storage capacities of dilute ternary Pd-Rh-Co alloys. The effect of varying the rhodium and cobalt compositions on the thermodynamics of hydride formation and decomposition and hydrogen capacity of several palladium-rhodium-cobalt ternary alloys has been investigated using pressure-composition (PC) isotherms. Alloying in the dilute regime (<10 at.%) causes the enthalpy for hydride formation to linearly decrease with increasing alloying content. Cobalt has a stronger effect on the reduction in enthalpy than rhodium for equivalent alloying amounts. Also, cobalt reduces the hydrogen storage capacity with increasing alloying content. The plateau thermodynamics are strongly linked to the lattice parameters of the alloys. A near-linear dependence of the enthalpy of hydride formation on the lattice parameter was observed for both the binary Pd-Rh and Pd-Co alloys, as well as for the ternary Pd-Rh-Co alloys. The Pd-5Rh-3Co (at. %) alloy was found to have similar plateau thermodynamics as a Pd-10Rh alloy, however, this ternary alloy had a diminished hydrogen storage capacity relative to Pd-10Rh.

  10. Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts

    SciTech Connect (OSTI)

    Mei, Donghai; Lebarbier, Vanessa MC; Rousseau, Roger J.; Glezakou, Vassiliki Alexandra; Albrecht, Karl O.; Kovarik, Libor; Flake, Matthew D.; Dagle, Robert A.

    2013-06-01

    In a combined experimental and first-principles density functional theory (DFT) study, benzene steam reforming (BSR) over MgAl2O4 supported Rh and Ir catalysts was investigated. Experimentally, it has been found that both highly dispersed Rh and Ir clusters (1-2 nm) on the MgAl2O4 spinel support are stable during the BSR in the temperature range of 700-850?C. Compared to the Ir/MgAl2O4 catalyst, the Rh/MgAl2O4 catalyst is more active with higher benzene turnover frequency and conversion. At typical steam conditions with the steam-to-carbon ratio > 12, the benzene conversion is only a weak function of the H2O concentration in the feed. This suggests that the initial benzene decomposition step rather than the benzene adsorption is most likely the rate-determined step in BSR over supported Rh and Ir catalysts. In order to understand the differences between the two catalysts, we followed with a comparative DFT study of initial benzene decomposition pathways over two representative model systems for each supported metal (Rh and Ir) catalysts. A periodic terrace (111) surface and an amorphous 50-atom metal cluster with a diameter of 1.0 nm were used to represent the two supported model catalysts under low and high dispersion conditions. Our DFT results show that the decreasing catalyst particle size enhances the benzene decomposition on supported Rh catalysts by lowering both C-C and C-H bond scission. The activation barriers of the C-C and the C-H bond scission decrease from 1.60 and 1.61 eV on the Rh(111) surface to 1.34 and 1.26 eV on the Rh50 cluster. For supported Ir catalysts, the decreasing particle size only affects the C-C scission. The activation barrier of the C-C scission of benzene decreases from 1.60 eV on the Ir(111) surface to 1.35 eV on the Ir50 cluster while the barriers of the C-H scission are practically the same. The experimentally measured higher BSR activity on the supported highly dispersed Rh catalyst can be rationalized by the thermodynamic limitation for the very first C-C bond scission of benzene on the small Ir50 catalyst. The C-C bond scission of benzene on the small Ir50 catalyst is highly endothermic although the barrier is competitive with the barriers of both the C-C and the C-H bond-breakings on the small Rh50 catalyst. The calculations also imply that, for the supported Rh catalysts the C-C and C-H bond scissions are competitive, independently of the Rh cluster sizes. After the initial dissociation step via either the C-C or the C-H bond scission, the C-H bond breaking seems to be more favorable rather than the C-C bond breaking on the larger Rh terrace surface. This work was financially supported by the United States Department of Energy’s Office of Biomass Program’s. Computing time was granted by a user project at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  11. Behavior of trace and companion elements of ULC-IF steel grades during RH-treatment

    SciTech Connect (OSTI)

    Jungreithmeier, A.; Viertauer, A.; Presslinger, H. [Voest-Alpine Stahl Linz GmbH (Austria)

    1996-12-31

    A large number of metallurgical reactions are caused by lowering the partial pressure during vacuum treatment. One of these reactions is the volatilization of elements with high vapor pressure. The concentration of trace and companion elements during RH-treatment mostly changes because of cooling scrap, deoxidation agents and ferro-alloy additions, slag/metal reactions, vaporization and also because of reactions with the RH-vessel lining. These changes in the concentration of trace and companion elements during RH-treatment are exemplified for ULC-IF (ultra low carbon--interstitial free) steel grades. The elements which are considered are chromium, nickel, molybdenum, copper, vanadium, tin, zinc, lead, phosphorus, sulfur and nitrogen. Calculations of the theoretical equilibrium solubility using thermodynamic data--in dependence of pressure and temperature--correspond well with the values obtained during steel production operations. 67 refs.

  12. Cooling effect in emissions of 103mRh excited by bremsstrahlung

    E-Print Network [OSTI]

    Yao Cheng; Bing Xia; Chinping Chen

    2009-04-29

    Nonlinear characteristic emissions of K alpha, K beta and gamma with a significant triplet splitting at room temperature are observed from the long-lived nuclear state of 103mRh excited by bremsstrahlung irradiation. A pronounced phase-transition-like narrowing of the emission profiles occurs immediately after the sample is cooled down to 77 K. The room temperature profiles reappear again abruptly and almost reversibly as the temperature drifts freely back to approximately the ice point after the filling of liquid nitrogen is stopped. These emission properties at 300 K and at low temperature may indicate that the 103mRh nuclei are in collective states.

  13. Rh-Based Mixed Alcohol Synthesis Catalysts: Characterization and Computational Report

    SciTech Connect (OSTI)

    Albrecht, Karl O.; Glezakou, Vassiliki Alexandra; Rousseau, Roger J.; Engelhard, Mark H.; Varga, Tamas; Colby, Robert J.; Jaffe, John E.; Li, Xiaohong S.; Mei, Donghai; Windisch, Charles F.; Kathmann, Shawn M.; Lemmon, Teresa L.; Gray, Michel J.; Hart, Todd R.; Thompson, Becky L.; Gerber, Mark A.

    2013-08-01

    The U.S. Department of Energy is conducting a program focused on developing a process for the conversion of biomass to bio-based fuels and co-products. Biomass-derived syngas is converted thermochemically within a temperature range of 240 to 330°C and at elevated pressure (e.g., 1200 psig) over a catalyst. Ethanol is the desired reaction product, although other side compounds are produced, including C3 to C5 alcohols; higher (i.e., greater than C1) oxygenates such as methyl acetate, ethyl acetate, acetic acid and acetaldehyde; and higher hydrocarbon gases such as methane, ethane/ethene, propane/propene, etc. Saturated hydrocarbon gases (especially methane) are undesirable because they represent a diminished yield of carbon to the desired ethanol product and represent compounds that must be steam reformed at high energy cost to reproduce CO and H2. Ethanol produced by the thermochemical reaction of syngas could be separated and blended directly with gasoline to produce a liquid transportation fuel. Additionally, higher oxygenates and unsaturated hydrocarbon side products such as olefins also could be further processed to liquid fuels. The goal of the current project is the development of a Rh-based catalyst with high activity and selectivity to C2+ oxygenates. This report chronicles an effort to characterize numerous supports and catalysts to identify particular traits that could be correlated with the most active and/or selective catalysts. Carbon and silica supports and catalysts were analyzed. Generally, analyses provided guidance in the selection of acceptable catalyst supports. For example, supports with high surface areas due to a high number of micropores were generally found to be poor at producing oxygenates, possibly because of mass transfer limitations of the products formed out of the micropores. To probe fundamental aspects of the complicated reaction network of CO with H2, a computational/ theoretical investigation using quantum mechanical and ab initio molecular dynamics calculations was initiated in 2009. Computational investigations were performed first to elucidate understanding of the nature of the catalytically active site. Thermodynamic calculations revealed that Mn likely exists as a metallic alloy with Rh in Rh-rich environments under reducing conditions at the temperatures of interest. After determining that reduced Rh-Mn alloy metal clusters were in a reduced state, the activation energy barriers of numerous transition state species on the catalytically active metal particles were calculated to compute the activation barriers of several reaction pathways that are possible on the catalyst surface. Comparison of calculations with a Rh nanoparticle versus a Rh-Mn nanoparticle revealed that the presence of Mn enabled the reaction pathway of CH with CO to form an adsorbed CHCO species, which was a precursor to C2+ oxygenates. The presence of Mn did not have a significant effect on the rate of CH4 production. Ir was observed during empirical catalyst screening experiments to improve the activity and selectivity of Rh-Mn catalysts. Thus, the addition of Ir to the Rh-Mn nanoparticles also was probed computationally. Simulations of Rh-Mn-Ir nanoparticles revealed that, with sufficient Ir concentrations, the Rh, Mn and Ir presumably would be well mixed within a nanoparticle. Activation barriers were calculated for Rh-Mn-Ir nanoparticles for several C-, H-, and O-containing transitional species on the nanoparticle surface. It was found that the presence of Ir opened yet another reactive pathway whereby HCO is formed and may undergo insertion with CHx surface moieties. The reaction pathway opened by the presence of Ir is in addition to the CO + CH pathway opened by the presence of Mn. Similar to Mn, the presence of Ir was not found to not affect the rate of CH4 production.

  14. Electronic Effects of Rh(II)-Mediated Carbenoid Intramolecular C-H Insertion: A Linear Free Energy Correlation Study

    E-Print Network [OSTI]

    Wang, Jianbo

    Electronic Effects of Rh(II)-Mediated Carbenoid Intramolecular C-H Insertion: A Linear Free Energy. The mechanistic significance of these Hammett correlations is discussed. Introduction The electronic effects of Rh is enhanced by an electron-donating group while an electron-withdrawing group retards the C-H insertion, thus

  15. Dynamics of NO reduction by H2 on Rh(111): Velocity and angular distributions of the N2 product

    E-Print Network [OSTI]

    Sibener, Steven

    examine the dynamics of the NO H2 reaction on the Rh 111 surface by measuring the velocity distribution. Product velocity distributions have been measured for a number of surface reactions, and show a wideDynamics of NO reduction by H2 on Rh(111): Velocity and angular distributions of the N2 product J

  16. David A. DeLambo, Rh.D., CRC Department of Rehabilitation and Counseling

    E-Print Network [OSTI]

    Wu, Mingshen

    David A. DeLambo, Rh.D., CRC Department of Rehabilitation and Counseling University of Wisconsin-Stout 231a Vocational Rehabilitation Building Menomonie, WI 54751 delambod@uwstout.edu (715) 232-2499 Education 1997 Doctor of Rehabilitation/Rehabilitation Southern Illinois University Carbondale

  17. Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation

    E-Print Network [OSTI]

    Jones, William D.

    Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation between] in interaction with propane. Two complexes have been found as minima coordinated through either a methyl the methylene complex of propane into a methyl complex of pro- pane. This latter reaction has a much lower

  18. Carbon monoxide oxidation on Rh(111): Velocity and angular distributions of the CO2 product

    E-Print Network [OSTI]

    Sibener, Steven

    Carbon monoxide oxidation on Rh(111): Velocity and angular distributions of the CO2 product J. I of surface temperature and oxygen coverage. Both the velocity and angular distributions are bimodal without first accommodating on the surface, the velocity, angular, and internal state distributions may

  19. Balloon-borne sounding system (BBSS): Vaisala-processed winds, press., temp, and RH

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Coulter, Richard; Ritsche, Michael

    Balloon-borne sounding system (BBSS): Vaisala-processed winds, press., temp, and RH. The balloon-borne sounding system (SONDE) provides in situ measurements (vertical profiles) of both the thermodynamic state of the atmosphere, and the wind speed and direction.

  20. Waste Isolation Pilot Plant simulated RH TRU waste experiments: Data and interpretation pilot

    SciTech Connect (OSTI)

    Molecke, M.A.; Argueello, G.J.; Beraun, R.

    1993-04-01

    The simulated, i.e., nonradioactive remote-handled transuranic waste (RH TRU) experiments being conducted underground in the Waste Isolation Pilot Plant (WIPP) were emplaced in mid-1986 and have been in heated test operation since 9/23/86. These experiments involve the in situ, waste package performance testing of eight full-size, reference RH TRU containers emplaced in horizontal, unlined test holes in the rock salt ribs (walls) of WIPP Room T. All of the test containers have internal electrical heaters; four of the test emplacements were filled with bentonite and silica sand backfill materials. We designed test conditions to be ``near-reference`` with respect to anticipated thermal outputs of RH TRU canisters and their geometrical spacing or layout in WIPP repository rooms, with RH TRU waste reference conditions current as of the start date of this test program. We also conducted some thermal overtest evaluations. This paper provides a: detailed test overview; comprehensive data update for the first 5 years of test operations; summary of experiment observations; initial data interpretations; and, several status; experimental objectives -- how these tests support WIPP TRU waste acceptance, performance assessment studies, underground operations, and the overall WIPP mission; and, in situ performance evaluations of RH TRU waste package materials plus design details and options. We provide instrument data and results for in situ waste container and borehole temperatures, pressures exerted on test containers through the backfill materials, and vertical and horizontal borehole-closure measurements and rates. The effects of heat on borehole closure, fracturing, and near-field materials (metals, backfills, rock salt, and intruding brine) interactions were closely monitored and are summarized, as are assorted test observations. Predictive 3-dimensional thermal and structural modeling studies of borehole and room closures and temperature fields were also performed.

  1. Effect of prostaglandin E? (PGE?) on the release of gonadotropin-releasing hormone (GnRH) from infundibular explants of cattle 

    E-Print Network [OSTI]

    Stephens, Tyler Paul

    2001-01-01

    GnRH neuronal terminals located in the infundibulum of rodents have been shown to release GnRH when stimulated with PGE? in vivo and in vitro. The effect of PGE? on the release of GnRH has not been determined in cattle. Thus, the objective...

  2. Association of intracellular calcium oscillations with release of gonadotropin-releasing hormone (GnRH) from GT1-1 neuronal cells 

    E-Print Network [OSTI]

    Gilmore, Chrystal Dawn

    1999-01-01

    the relationship of GnRH release with [Ca²?][] oscillations using the GT1-1 neuronal cell line. GnRH release was measured by radioimmunoassay of media incubated with GT1-1 neuronal cells for 1 hr with control or test substances to induce release of GnRH. [Ca...

  3. Is It Homogeneous or Heterogeneous Catalysis Derived from [RhCp*Cl2]2? In Operando-XAFS, Kinetic and Crucial Kinetic Poisoning Evidence for Subnanometer Rh4 Cluster-Based Benzene Hydrogenation Catalysis

    SciTech Connect (OSTI)

    Bayram, Ercan; Linehan, John C.; Fulton, John L.; Roberts, John A.; Szymczak, Nathaniel; Smurthwaite, Tricia D.; Ozkar, Saim; Balasubramanian, Mahalingam; Finke, Richard G.

    2011-11-23

    Determining the true, kinetically dominant catalytically active species, in the classic benzene hydrogenation system pioneered by Maitlis and co-workers 34 years ago starting with [RhCp*Cl2]2 (Cp* = [{eta}5-C5(CH3)5]), has proven to be one of the most challenging case studies in the quest to distinguish single-metal-based 'homogeneous' from polymetallic, 'heterogeneous' catalysis. The reason, this study will show, is the previous failure to use the proper combination of (i) operando spectroscopy to determine the dominant form(s) of the precatalyst's mass under catalysis (i.e., operating) conditions, plus then and crucially also (ii) the previous lack of the necessary kinetic studies, catalysis being a 'wholly kinetic phenomenon' as J. Halpern long ago noted. An important contribution from this study will be to reveal the power of quantitiative kinetic poisoning experiments for distinguishing single-metal, or in this case subnanometer Rh4 cluster-based catalysis from larger, polymetallic Rh(0)n nanoparticle catalysis, at least under favorable conditions. The combined operando-XAFS (X-ray absorption fine structure) spectroscopy and kinetic evidences provide a compelling case for Rh4-based, with average stoichiometry 'Rh4Cp*2.4Cl4Hc', benzene hydrogenation catalysis in 2-propanol with added Et3N and at 100 C and 50 atm initial H2 pressure. The results also reveal, however, that if even ca. 1.4% of the total soluble Rh(0)n had formed nanoparticles, then those Rh(0)n nanoparticles would have been able to account for all the observed benzene hydrogenation catalytic rate (using commercial, ca. 2 nm, polyethyleneglycol-dodecylether hydrosol stabilized Rh(0)n nanoparticles as a model system). The results 'especially the poisoning methodology developed and employed' are of significant, broader interest since determining the nature of the true catalyst continues to be a central, often vexing issue in any and all catalytic reactions. The results are also of fundamental interest in that they add to a growing body of evidence indicating that certain, appropriately ligated, coordinatively unsaturated, subnanometer M4 transition-metal clusters can be relatively robust catalysts. Also demonstrated herein is that Rh4 clusters are poisoned by Hg(0), demonstrating for the first time that the classic Hg(0) poisoning test of 'homogeneous' vs 'heterogeneous'catalysts cannot distinguish Rh4-based subnanometer catalysts from Rh(0)n nanoparticle catalysts, at least for the present examples of these two specific, Rh-based catalysts.

  4. Synthesis of few-walled carbon nanotube-Rh nanoparticles by arc discharge: Effect of selective oxidation

    SciTech Connect (OSTI)

    Zhang Yanfeng

    2012-06-15

    Highly crystalline rhodium (Rh) nanoparticles supported on carbon nanotubes were prepared by selective oxidation method. Carbon nanotubes and FeRh nanoparticles were simultaneously generated in hydrogen arc plasma. The as-grown nanomaterials can be purified by heat treatment in open air and by soaking in HCl. X-ray diffraction and selected area electron diffraction results reveal that as-grown FeRh nanoparticles have a typical chemical CsCl-type structure which can be transformed into a face-centered cubic structure by thermal annealing in the purification process. The purification process is selective toward the removal of the amorphous carbon coating the nanoparticles, and transforms Fe to Fe{sub 2}O{sub 3}. Fe{sub 2}O{sub 3} can be easily dissolved in hydrochloric acid, leaving carbon nanotubes-Rh nanoparticles. Rh nanoparticles with diameters of 2-60 nm are deposited uniformly on the surface of the carbon nanotube bundles. This simple and selective chemistry offers a new process for synthesizing and controlling Fe content in carbon nanotube-FeRh nanoparticles. Highlights: Black-Right-Pointing-Pointer High-crystallinity CNTs and FeRh nanoparticles were simultaneously generated in arc plasma. Black-Right-Pointing-Pointer The diameter distribution of CNTs depends on different gases. Black-Right-Pointing-Pointer Heat treatment in open air and soaking in HCl can convert CNTs-FeRh to CNTs-Rh. Black-Right-Pointing-Pointer The selective oxidation mechanisms of metal nanoparticles and carbon materials differ.

  5. Magnitude of the magnetic exchange interaction in the heavy-fermion antiferromagnet CeRhIn5

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Das, Pinaki; Lin, S. -Z.; Ghimire, N. J.; Huang, K.; Ronning, F.; Bauer, E. D.; Thompson, J. D.; Batista, C. D.; Ehlers, G.; Janoschek, M.

    2014-12-08

    We have used high-resolution neutron spectroscopy experiments to determine the complete spin wave spectrum of the heavy-fermion antiferromagnet CeRhIn?. The spin wave dispersion can be quantitatively reproduced with a simple frustrated J?-J? model that also naturally explains the magnetic spin-spiral ground state of CeRhIn? and yields a dominant in-plane nearest-neighbor magnetic exchange constant J?=0.74(3) meV. Our results lead the way to a quantitative understanding of the rich low-temperature phase diagram of the prominent CeTIn? (T = Co, Rh, Ir) class of heavy-fermion materials.

  6. Magnetism and superconductivity in U2PtxRh1?xC2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-09

    We report the phase diagram of the doping series U?PtxRh(1–x)C?, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Néel temperature of U?Rh?C? of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. Additionally, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ? 0.9, with Tc increasing with increasing x. Themore »reduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.« less

  7. Anisotropic intermediate valence in Yb2M3Ga9 (M = Rh, Ir)

    SciTech Connect (OSTI)

    Christianson, A.D.; Lawrence, J.M.; Lobos, A.M.; Aligia, A.A.; Bauer, E.D.; Moreno, N.O.; Booth, C.H.; Goremychkin, E.A.; Sarrao, J.L.; Thompson, J.D.; Batista, C.D.; Trouw, F.R.; Hehlen, M.P.

    2005-04-26

    The intermediate valence compounds Yb{sub 2}M{sub 3}Ga{sub 9} (M = Rh, Ir) exhibit an anisotropic magnetic susceptibility. We report measurements of the temperature dependence of the 4f occupation number, n{sub f}(T), for Yb{sub 2}M{sub 3}Ga{sub 9} as well as the magnetic inelastic neutron scattering spectrum S{sub mag}({Delta}E) at 12 and 300 K for Yb{sub 2}Rh{sub 3}Ga{sub 9}. Both n{sub f}(T) and S{sub mag}({Delta}E) were calculated for the Anderson impurity model with crystal field terms within an approach based on the non-crossing approximation. These results corroborate the importance of crystal field effects in these materials; they also suggest that Anderson lattice effects are important to the physics of Yb{sub 2}M{sub 3}Ga{sub 9}.

  8. Magnetism and superconductivity in U?PtxRh(1–x)C?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-01

    We report the phase diagram of the doping series U?PtxRh(1–x)C?, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Néel temperature of U?Rh?C? of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. In addition, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ? 0.9, with Tc increasing with increasing x.more »The reduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.« less

  9. Electronic structure of U2PtC2 and U2RhC2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ronning, F.; Zhu, J. -X.

    2015-03-18

    In this study, we present density functional theory calculations within the generalized gradient approximation of U2RhC2 and U2PtC2. We find the calculated density of states are significantly less than that measured by specific heat indicating the need for electronic correlations. The mass enhancement found for U2PtC2 is m*/mband ? 4.

  10. 2,3-Migration in Rh(II)-Catalyzed Reactions of -Trifluoroacetamido

    E-Print Network [OSTI]

    Wang, Jianbo

    2,3-Migration in Rh(II)-Catalyzed Reactions of -Trifluoroacetamido r-Diazocarbonyl Compounds Feng(II)-catalyzed reactions of these diazo compounds gave 2,3-migration products in high yields. 1,2-Migration is one,2-migration reactions, the 1,2-hydride migration is generally predominant, but 1,2-alkyl, 1,2-aryl, 1,2-thio

  11. Hydrogen sorption characteristics of nanostructured Pd–10Rh processed by cryomilling

    SciTech Connect (OSTI)

    Yang, Nancy; Yee, Joshua K.; Zhang, Zhihui; Kurmanaeva, Lilia; Cappillino, Patrick; Stavila, Vitalie; Lavernia, Enrique J.; San Marchi, Chris

    2014-10-03

    Palladium and its alloys are model systems for studying solid-state storage of hydrogen. Mechanical milling is commonly used to process complex powder systems for solid-state hydrogen storage; however, milling can also be used to evolve nanostructured powder to modify hydrogen sorption characteristics. In the present study, cryomilling (mechanical attrition milling in a cryogenic liquid) is used to produce nanostructured palladium-rhodium alloy powder. Characterization of the cryomilled Pd-10Rh using electron microscopy, X-ray diffraction, and surface area analysis reveals that (i) particle morphology evolves from spherical to flattened disk-like particles; while the (ii) crystallite size decreases from several microns to less than 100 nm and (iii) dislocation density increases with increased cryomilling time. Hydrogen absorption and desorption isotherms as well as the time scales for absorption were measured for cryomilled Pd-10Rh, and correlated with observed microstructural changes induced by the cryomilling process. In short, as the microstructure of the Pd-10Rh alloy is refined by cryomilling: (i) the maximum hydrogen concentration in the ?-phase increases, (ii) the pressure plateau becomes flatter, and (iii) the equilibrium hydrogen capacity at 760 Torr increases. In addition, the rate of hydrogen absorption was reduced by an order of magnitude compared to non-cryomilled (atomized) powder.

  12. Hydrogen sorption characteristics of nanostructured Pd–10Rh processed by cryomilling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Nancy; Yee, Joshua K.; Zhang, Zhihui; Kurmanaeva, Lilia; Cappillino, Patrick; Stavila, Vitalie; Lavernia, Enrique J.; San Marchi, Chris

    2014-10-03

    Palladium and its alloys are model systems for studying solid-state storage of hydrogen. Mechanical milling is commonly used to process complex powder systems for solid-state hydrogen storage; however, milling can also be used to evolve nanostructured powder to modify hydrogen sorption characteristics. In the present study, cryomilling (mechanical attrition milling in a cryogenic liquid) is used to produce nanostructured palladium-rhodium alloy powder. Characterization of the cryomilled Pd-10Rh using electron microscopy, X-ray diffraction, and surface area analysis reveals that (i) particle morphology evolves from spherical to flattened disk-like particles; while the (ii) crystallite size decreases from several microns to less thanmore »100 nm and (iii) dislocation density increases with increased cryomilling time. Hydrogen absorption and desorption isotherms as well as the time scales for absorption were measured for cryomilled Pd-10Rh, and correlated with observed microstructural changes induced by the cryomilling process. In short, as the microstructure of the Pd-10Rh alloy is refined by cryomilling: (i) the maximum hydrogen concentration in the ?-phase increases, (ii) the pressure plateau becomes flatter, and (iii) the equilibrium hydrogen capacity at 760 Torr increases. In addition, the rate of hydrogen absorption was reduced by an order of magnitude compared to non-cryomilled (atomized) powder.« less

  13. Specific heat of CeRhIn5: Pressure-driven evolution of the ground state from antiferromagnetism to superconductivity

    E-Print Network [OSTI]

    2001-01-01

    Specific Heat of CeRhIn5: Pressure–Driven Evolution of the32306 Measurements of the specific heat of antiferromagneticsee text). Fig. 2. (a) The specific heat, for representative

  14. Ovarian and hormonal events during synchronization of ovulation and timed appointment breeding of Bos indicus-influenced cattle using intravaginal progesterone, GnRH and prostaglandin F2(alpha) 

    E-Print Network [OSTI]

    Saldarriaga Lopez, Juan Pablo

    2007-04-25

    of GnRH (GnRH-1) on day 0, removal of the CIDR and injection of prostaglandin F2a (PGF on d 7, and injection of GnRH (GnRH-2) and TAI 48 h later. In experiment 1 (Exp. 1), 335 females were stratified by BCS, parity and d postpartum before random...

  15. Structural and ferromagnetic properties of an orthorhombic phase of MnBi stabilized with Rh additions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Taufour, Valentin; Thimmaiah, Srinivasa; March, Stephen; Saunders, Scott; Sun, Kewei; Lamichhane, Tej Nath; Kramer, Matthew J.; Bud’ko, Sergey L.; Canfield, Paul C.

    2015-07-28

    The article addresses the possibility of alloy elements in MnBi which may modify the thermodynamic stability of the NiAs-type structure without significantly degrading the magnetic properties. The addition of small amounts of Rh and Mn provides an improvement in the thermal stability with some degradation of the magnetic properties. The small amounts of Rh and Mn additions in MnBi stabilize an orthorhombic phase whose structural and magnetic properties are closely related to the ones of the previously reported high-temperature phase of MnBi (HT MnBi). The properties of the HT MnBi, which is stable between 613 and 719 K, have notmore »been studied in detail because of its transformation to the stable low-temperature MnBi (LT MnBi), making measurements near and below its Curie temperature difficult. The Rh-stabilized MnBi with chemical formula Mn1.0625–xRhxBi [x=0.02(1)] adopts a new superstructure of the NiAs/Ni2In structure family. It is ferromagnetic below a Curie temperature of 416 K. The critical exponents of the ferromagnetic transition are not of the mean-field type but are closer to those associated with the Ising model in three dimensions. The magnetic anisotropy is uniaxial; the anisotropy energy is rather large, and it does not increase when raising the temperature, contrary to what happens in LT MnBi. The saturation magnetization is approximately 3?B/f.u. at low temperatures. Thus, while this exact composition may not be application ready, it does show that alloying is a viable route to modifying the stability of this class of rare-earth-free magnet alloys.« less

  16. GnRH-induced LH release in heifers: effect of nutrient restriction during gestation 

    E-Print Network [OSTI]

    Killen, James Harold

    1983-01-01

    RH-Induced LH Release in Heif era: Effect of Nutrient Restriction During Gestation. (May 1983) James Harold Killen, B. S. , University of Arizona Co-Chairmen of Advisory Committee: Dr. David W. Forrest Dr. Paul G. Harms This study was undertaken.... 4+/-18. 4, 64. 9+/-16. 8, and 29. 6+/-12. 4 ng/ml (P&. 10) for pr spartum heifer s snd 18. 4+/-4. 7, 14. 6+/-S. 4 and 31. 7+/- 5. 7 ng/ml (P&. 10) f or postpartum heifers in the L, M snd G groups, r eepectively. LSM for plasma LH response and peak...

  17. Syngas production from butane using a flame-made Rh/Ce0.5Zr0.5O2 Nico Hotz a

    E-Print Network [OSTI]

    Daraio, Chiara

    Syngas production from butane using a flame-made Rh/Ce0.5Zr0.5O2 catalyst Nico Hotz a , Michael J the production of H2- and CO-rich syngas from butane was investigated for different Rh loadings (0­2.0 wt% Rh for a temperature range from 225 to 750 8C. The main goal of this study was the efficient processing of butane

  18. The influence of nano-architectured CeOx supports in RhPd/CeO? for the catalytic ethanol steam reforming reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Divins, N. J.; Senanayake, S. D.; Casanovas, A.; Xu, W.; Trovarelli, A.; Llorca, J.

    2015-01-19

    The ethanol steam reforming (ESR) reaction has been tested over RhPd supported on polycrystalline ceria in comparison to structured supports composed of nanoshaped CeO? cubes and CeO? rods tailored towards the production of hydrogen. At 650-700 K the hydrogen yield follows the trend RhPd/CeO?-cubes > RhPd/CeO? -rods > RhPd/CeO?- polycrystalline, whereas at temperatures higher than 800 K the catalytic performance of all samples is similar and close to the thermodynamic equilibrium. The improved performance of RhPd/CeO?-cubes and RhPd/CeO? -rods for ESR at low temperature is mainly ascribed to higher water-gas shift activity and a strong interaction between the bimetallic -more »oxide support interaction. STEM analysis shows the existence of RhPd alloyed nanoparticles in all samples, with no apparent relationship between ESR performance and RhPd particle size. X-ray diffraction under operating conditions shows metal reorganization on {100} and {110} ceria crystallographic planes during catalyst activation and ESR, but not on {111} ceria crystallographic planes. The RhPd reconstructing and tuned activation over ceria nanocubes and nanorods is considered the main reason for better catalytic activity with respect to conventional catalysts based on polycrystalline ceria« less

  19. Single to Multiquasiparticle Excitations in the Itinerant Helical Magnet CeRhIn5

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stock, C.; Rodriguez-Rivera, J. A.; Schmalzl, K.; Rodriguez, E. E.; Stunault, A.; Petrovic, C.

    2015-06-19

    Neutron scattering is used to measure the quantum spin fluctuations in CeRhIn5 - the parent material of the eXIn5 superconducting series. Out-of-plane spin fluctuations are gapped and localized in momentum, similar to the spin excitons in CeCoIn5. The in-plane fluctuations consist of sharp spin-wave excitations parameterized by a nearest neighbor exchange JRKKY =0.88 ± 0.05 meV that crossover to a temporally and spatially broad multiparticle spectrum with energies of ~ 2 × JRKKY . This continuum represents composite fluctuations that illustrate the breakdown of single magnons originating from the delicate energy balance between localized 4f and itinerant behavior in amore »heavy metal. The experiment therefore shows how quasiparticle behavior is changed by the close proximity of quantum criticality.« less

  20. Synthesis, NMR spectra, and structure of rhodium hydride complexes with Rh-Sn bonds

    SciTech Connect (OSTI)

    Krut'ko, B.P.; Permin, A.B.; Petrosyan, V.S.; Reutov, O.A.

    1985-06-20

    The authors study the hydride complexes using Sn 119 and H 1 NMR spectroscopy. The spectra were taken in a pulse mode on a Varian FT-80A spectrometer equipped with a wideband system at 29.66 and 79.54 MHz. The Sn 119 and H 1 NMR spectral parameters for a solution of the complex (Bu/sub 4/N)/sub 3/ (HRh(SnCl/sub 3/)/sub 5/) in CD/sub 3/CN are shown, the spectra show that the (HRh(SnCl/sub 3/)/sub 5/)/sup 3 -/ anion has octahedral structure with four equatorial and one axial Rh-Sn bonds. New rhodium hydride complexes with general formula (R/sub 4/N)/sub 3/(HRh(SnCl/sub 3/)/sub 5/) were synthesized.

  1. Dynamics of NO reduction by H2 on Rh(111): Velocity and angular distributions of the N2 product

    E-Print Network [OSTI]

    Sibener, Steven

    Dynamics of NO reduction by H2 on Rh(111): Velocity and angular distributions of the N2 product J; accepted 17 January 1996 The velocity and angular distributions of N2 produced from the reduction temperature. Both the angular and velocity distributions are well fit by bimodal forms. The high energy

  2. Applied reaction dynamics: Efficient synthesis gas production via single collision partial oxidation of methane to CO on Rh,,111...

    E-Print Network [OSTI]

    Sibener, Steven

    the yield of CO from the partial oxidation of CH4 on a Rh 111 catalytic substrate, CH4+ 1/2 O2CO+2H2 to the multistep route to methane utilization, namely, steam reforming coupled with the water gas shift reaction.1

  3. Energetics of C-H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [TpRh(CNneopentyl)] Complex

    E-Print Network [OSTI]

    Jones, William D.

    Energetics of C-H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [Tp activation of fluorinated aromatic hydrocarbons by [TpRh(CNneopentyl)] resulted in the formation of products of homogeneous transition-metal catalysts to activate and functionalize C-H bonds of hydrocarbons for industrial

  4. Structural and magnetic properties in the polymorphs of CeRh{sub 0.5}Ge{sub 1.5}

    SciTech Connect (OSTI)

    Kalsi, Deepti; Subbarao, Udumula [New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064 (India); Rayaprol, Sudhindra [UGC-DAE Consortium for Scientific Research, R-5 Shed, B.A.R.C Campus, Trombay, Mumbai-400085 (India); Peter, Sebastian C., E-mail: sebastiancp@jncasr.ac.in [New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064 (India)

    2014-04-01

    We investigate the structural and magnetic properties in the polymorphs of a new compound CeRh{sub 0.5}Ge{sub 1.5}. Depending upon the starting materials, and the slightly different synthesis method, we find that CeRh{sub 0.5}Ge{sub 1.5} compound exists in two different space groups. The first compound, ?-CeRh{sub 0.5}Ge{sub 1.5} crystallizes in tetragonal ?-ThSi{sub 2} structure type in space group I4{sub 1}/amd with lattice parameters, a=4.2034(6) Å and c=14.770(3) Å. In this structure, the cerium atoms occupy the position between the Rh/Ge tetrahedral layers. On the other hand, the second compound, namely ?-CeRh{sub 0.5}Ge{sub 1.5} crystallizes in the AlB{sub 2} type hexagonal structure in space group P6/mmm, with lattice parameters, a=4.2615(7) Å and c=4.1813(9) Å. The crystal structure of ?-CeRh{sub 0.5}Ge{sub 1.5} consists of two dimensional Rh/Ge hexagonal units and the cerium atoms are sandwiched between them. Magnetization studies exhibit magnetic ordering, as evident from a sharp peak in the plot of magnetic susceptibility measured as a function of temperature in a fixed magnetic field, in ?-CeRh{sub 0.5}Ge{sub 1.5} and ?-CeRh{sub 0.5}Ge{sub 1.5} at 3.6 K and 12 K, respectively. Structural and magnetic properties of both compounds are presented and discussed here. - Graphical abstract: Two polymorphs of a new compound CeRh{sub 0.5}Ge{sub 1.5} in the ?-ThSi{sub 2} and AlB{sub 2} structure types were synthesized by arc melting. The magnetic measurements of both CeRh{sub 0.5}Ge{sub 1.5} phases suggest spin-glass behavior. - Highlights: • A new compound CeRh{sub 0.5}Ge{sub 1.5} in two difference phases was synthesized by arc melting. • The crystal structure of both compounds was determined from the single crystal XRD. • Isothermal relaxation measurements suggesting spin-glass like anomalies in both phases.

  5. Mechanistic aspects of [Rh(nbd)CI][sub 2]initiated oligomerization of new acetylenic monomers

    SciTech Connect (OSTI)

    Densmore, C.G. (Crystal G); Rasmussen, P.G. (Paul G.)

    2004-01-01

    Although a number of papers report the use of rhodium-based initiators, very little has been said about the mechanism of acetylene polymerizations. Kishimoto and coworkers recently proposed an insertion mechanism for the rhodium-initiated polymerization of phenylacetylenes. The initiator consisted of the tetracoordinate rhodium complex, Rh(C{triple_bond}CC{sub 6}H{sub 5})(nbd)(PPh{sub 3}) with 4-(dimethylamino)-pyidine. The product was found to be stereoregular poly(phenylacety1ene) with a cis-transoidal backbone microstructure. Gorman and coworkers found palladium and nickel-based catalysts to be successful in the polymerization of cyanoacetylene. Zhan and Yang addressed the polymerization mechanism of acetylenes using palladium and nickel acetylide catalysts. They propose that the initial activation step, and also the rate-determining step, involve coordination of a nickel or palladium acetylide catalyst with an acetylene. Based on NMR and elemental analysis, we propose a more complete mechanistic picture of acetylene polymerizations, especially those with electron-withdrawing substituents.

  6. Ternary Pt/Rh/SnO2 Electrocatalysts for Oxidizing Ethanol to CO2

    SciTech Connect (OSTI)

    Kowal, A.; Li, M; Shao, M; Sasaki, K; Vukmirovic, M; Zhang, J; Marinkovic, N; Liu, P; Frenkel, A; Adzic, R

    2009-01-01

    Ethanol, with its high energy density, likely production from renewable sources and ease of storage and transportation, is almost the ideal combustible for fuel cells wherein its chemical energy can be converted directly into electrical energy. However, commercialization of direct ethanol fuel cells has been impeded by ethanol's slow, inefficient oxidation even at the best electrocatalysts1, 2. We synthesized a ternary PtRhSnO2/C electrocatalyst by depositing platinum and rhodium atoms on carbon-supported tin dioxide nanoparticles that is capable of oxidizing ethanol with high efficiency and holds great promise for resolving the impediments to developing practical direct ethanol fuel cells. This electrocatalyst effectively splits the C-C bond in ethanol at room temperature in acid solutions, facilitating its oxidation at low potentials to CO2, which has not been achieved with existing catalysts. Our experiments and density functional theory calculations indicate that the electrocatalyst's activity is due to the specific property of each of its constituents, induced by their interactions. These findings help explain the high activity of Pt-Ru for methanol oxidation and the lack of it for ethanol oxidation, and point to the way to accomplishing the C-C bond splitting in other catalytic processes.

  7. Ternary Pt/Rh/SnO2 Electrocatalysts for Oxidizing Ethanol to CO2

    SciTech Connect (OSTI)

    Adzic, R.R.; Kowal, A.; Li, M.; Shao, M.; Sasaki, K.; Vukmirovic, M.B.; Zhang, J.; Marinkovic, N.S. Liu, P.; Frenkel, A.I.

    2009-04-01

    Ethanol, with its high energy density, likely production from renewable sources and ease of storage and transportation, is almost the ideal combustible for fuel cells wherein its chemical energy can be converted directly into electrical energy. However, commercialization of direct ethanol fuel cells has been impeded by ethanol's slow, inefficient oxidation even at the best electrocatalysts. We synthesized a ternary PtRhSnO{sub 2}/C electrocatalyst by depositing platinum and rhodium atoms on carbon-supported tin dioxide nanoparticles that is capable of oxidizing ethanol with high efficiency and holds great promise for resolving the impediments to developing practical direct ethanol fuel cells. This electrocatalyst effectively splits the C-C bond in ethanol at room temperature in acid solutions, facilitating its oxidation at low potentials to CO{sub 2}, which has not been achieved with existing catalysts. Our experiments and density functional theory calculations indicate that the electrocatalyst's activity is due to the specific property of each of its constituents, induced by their interactions. These findings help explain the high activity of Pt-Ru for methanol oxidation and the lack of it for ethanol oxidation, and point to the way to accomplishing the C-C bond splitting in other catalytic processes.

  8. Asymmetric “melting” and “freezing” kinetics of the magnetostructural phase transition in B2-ordered FeRh epilayers

    SciTech Connect (OSTI)

    Vries, M. A. de; Loving, M.; Lewis, L. H.; McLaren, M.; Brydson, R. M. D.; Liu, X.; Langridge, S.; Marrows, C. H.

    2014-06-09

    Synchrotron X-ray diffraction was used to study the phase transformation processes during the magnetostructural transition in a B2-ordered FeRh (001)-oriented epilayer grown on MgO by sputtering. Out-of-plane lattice constant measurements within the hysteretic regime of the transition reveal a microstructure consistent with the coexistence of lattice-expanded and contracted phases in spatially distinct regions. It was found that the phase separation is more pronounced during cooling than heating. Furthermore, whilst lattice-expanded domains that span the height of the film can be undercooled by several kelvins, there is no equivalent superheating. This asymmetry between the cooling and heating processes in FeRh is consistent with the difference in the kinetics of generic freezing and melting transitions.

  9. Magnetism and superconductivity in U?PtxRh(1–x)C?

    SciTech Connect (OSTI)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-01

    We report the phase diagram of the doping series U?PtxRh(1–x)C?, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Néel temperature of U?Rh?C? of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. In addition, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ? 0.9, with Tc increasing with increasing x. The reduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.

  10. Synthesis and crystal structure of two new cerium rhodium oxides: Ce{sub 2/3-x}Rh{sup 3+}{sub 2}O{sub 4} (x{approx}0.12) with Ce mixed valency and Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5}

    SciTech Connect (OSTI)

    Mizoguchi, Hiroshi; Zakharov, L.N.; Bhuvanesh, N.S.P.; Sleight, A.W.; Subramanian, M.A.

    2011-06-15

    The new compounds Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) and CeRh{sub 2}O{sub 5} have been prepared. Their structures were determined from single crystal X-ray diffraction data. Electrical and magnetic properties were also evaluated. Based on the structural analysis and physical properties, oxidation states for CeRh{sub 2}O{sub 5} can be assigned as Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5}. A small variation in x was detected for Ce{sub 2/3-x}Rh{sub 2}O{sub 4} indicating a formula ranging from Ce{sup 3.64+}{sub 0.55}Rh{sup 3+}{sub 2}O{sub 4} to Ce{sup 3.81+}{sub 0.525}Rh{sup 3+}{sub 2}O{sub 4}. - Graphical abstract: The new compounds Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) and CeRh{sub 2}O{sub 5} have been prepared and their structures were determined from single crystal X-ray diffraction data. Electrical and magnetic properties were also evaluated. Highlights: > The new compounds CeRh{sub 2}O{sub 5} and Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) have been prepared. > Their structures were determined from single crystal X-ray diffraction data. > Valence picture is Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5} and Ce{sup 3.64+}{sub 0.55}Rh{sup 3+}{sub 2}O{sub 4} to Ce{sup 3.81+}{sub 0.525}Rh{sup 3+}{sub 2}O{sub 4}.

  11. Excited states in {sup 115}Pd populated in the {beta}{sup -} decay of {sup 115}Rh

    SciTech Connect (OSTI)

    Kurpeta, J.; Plochocki, A. [Faculty of Physics, University of Warsaw, ul. Hoza 69, PL-00-681 Warsaw (Poland); Urban, W. [Faculty of Physics, University of Warsaw, ul. Hoza 69, PL-00-681 Warsaw (Poland); Institut Laue-Langevin, 6 rue J. Horowitz, F-38042 Grenoble (France); Rissanen, J.; Eronen, T.; Hakala, J.; Jokinen, A.; Kankainen, A.; Karvonen, P.; Moore, I. D.; Penttilae, H.; Saastamoinen, A.; Weber, C.; Aeystoe, J. [Department of Physics, University of Jyvaeskylae, P.O. Box 35, FIN-40351, Jyvaeskylae (Finland); Elomaa, V.-V. [Turku PET Centre, Accelerator Laboratory, Abo Akademi University, FIN-20500 Turku (Finland); Rahaman, S. [Physics Division, P-23, Mail Stop H803, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Sonoda, T. [Nishina Center for Accelerator Based Science, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Szerypo, J. [Fakultaet fuer Physik, Ludwig-Maximilians-Universitaet Muenchen, Am Coulombwall 1, D-85748 Garching (Germany)

    2010-08-15

    Excited states in {sup 115}Pd, populated following the {beta}{sup -} decay of {sup 115}Rh have been studied by means of {gamma} spectroscopy after the Penning-trap station at the IGISOL facility, University of Jyvaeskylae. The 1/2{sup +} spin and parity assignment of the ground state of {sup 115}Pd, confirmed in this work, may indicate a transition to an oblate shape in Pd isotopes at high neutron number.

  12. Safety evaluation for packaging (onsite) for the concrete-shielded RH TRU drum for the 327 Postirradiation Testing Laboratory

    SciTech Connect (OSTI)

    Smith, R.J.

    1998-03-31

    This safety evaluation for packaging authorizes onsite transport of Type B quantities of radioactive material in the Concrete Shielded Remote-Handled Transuranic Waste (RH TRU) Drum per HNF-PRO-154, Responsibilities and Procedures for all Hazardous Material Shipments. The drum will be used for transport of 327 Building legacy waste from the 300 Area to a solid waste storage facility on the Hanford Site.

  13. Investigation of the physical properties of the tetragonal CeMAl4Si2 (M = Rh, Ir, Pt) compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ghimire, N. J.; Ronning, F.; Williams, D. J.; Scott, B. L.; Luo, Yongkang; Thompson, J. D.; Bauer, E. D.

    2014-12-15

    The synthesis, crystal structure and physical properties studied by means of x-ray diffraction, magnetic, thermal and transport measurements of CeMAl4Si2 (M = Rh, Ir, Pt) are reported, along with the electronic structure calculations for LaMAl4Si2 (M = Rh, Ir, Pt). These materials adopt a tetragonal crystal structure (space group P4/mmm) comprised of BaAl4 blocks, separated by MAl2 units, stacked along the c-axis. Both CeRhAl4Si2 and CeIrAl4Si2 order antiferromagnetically below TN1 = 14 and 16 K, respectively, and undergo a second antiferromagnetic transitition at lower temperature (TN2 = 9 and 14 K, respectively). CePtAl4Si2 orders ferromagnetically below TC = 3 Kmore »with an ordered moment of ?sat = 0.8 ?B for a magnetic field applied perpendicular to the c-axis. Electronic structure calculations reveal quasi-2D character of the Fermi surface.« less

  14. Features of conduction mechanisms in n-HfNiSn semiconductor heavily doped with a Rh acceptor impurity

    SciTech Connect (OSTI)

    Romaka, V. A.; Rogl, P.; Stadnyk, Yu. V.; Romaka, V. V.; Hlil, E. K.; Krajovskii, V. Ya.; Horyn, A. M.

    2013-09-15

    The crystal structure and electron-density distribution, as well as the energy, kinetic, and magnetic characteristics of n-HfNiSn intermetallic semiconductor heavily doped with a Rh acceptor impurity in the temperature range T = 80-400 K, in the acceptor-concentration range N{sub A}{sup Rh} Almost-Equal-To 9.5 Multiplication-Sign 10{sup 19}-1.9 Multiplication-Sign 10{sup 21} cm{sup -3} (x = 0.005-0.10), and in magnetic fields H {<=} 10 kG are investigated. It is established that doping is accompanied by a simultaneous decrease in concentration, the elimination of donor-type structural defects (to x Almost-Equal-To 0.02), and an increase in the concentration of acceptor-type structural defects (0 < x {<=} 0.10). The dependence of the degree of semiconductor compensation on temperature is revealed. A model of the spatial arrangement of atoms in HfNi{sub 1-x}Rh{sub x}Sn is proposed, and the results of calculating the electron structure based on this model agree with the results of investigations of the kinetic and magnetic characteristics of the semiconductor. The results are discussed within the context of the Shklovskii-Efros model for a heavily doped and compensated semiconductor.

  15. C-H Activation of Phenyl Imines and 2-Phenylpyridines with [Cp*MCl2]2 (M ) Ir, Rh): Regioselectivity, Kinetics, and

    E-Print Network [OSTI]

    Jones, William D.

    both by increasing temperature and by using polar solvents such as methanol. The regioselectivity*RhCl2]2. The regioselectivity was temperature independent for both metals. With added acid, the aromatic

  16. A RhxSy/C Catalyst for the Hydrogen Oxidation and Hydrogen Evolution Reactions in HBr

    SciTech Connect (OSTI)

    Masud, Jahangir; Nguyena, Trung V.; Singh, Nirala; McFarland, Eric; Ikenberry, Myles; Hohn, Keith; Pan, Chun-Jern; Hwang, Bing-Joe

    2015-01-01

    Rhodium sulfide (Rh2S3) on carbon support was synthesized by refluxing rhodium chloride with ammonium thiosulfate. Thermal treatment of Rh2S3 at high temperatures (600°C to 850°C) in presence of argon resulted in the transformation of Rh2S3 into Rh3S4, Rh17S15 and Rh which were characterized by TGA/DTA, XRD, EDX, and deconvolved XPS analyses. The catalyst particle size distribution ranged from 3 to 12 nm. Cyclic voltammetry and rotating disk electrode measurements were used to evaluate the catalytic activity for hydrogen oxidation and evolution reactions in H2SO4 and HBr solutions. The thermally treated catalysts show high activity for the hydrogen reactions. The exchange current densities (io) of the synthesized RhxSy catalysts in H2-saturated 1M H2SO4 and 1M HBr for HER and HOR were 0.9 mA/cm2 to 1.0 mA/cm2 and 0.8 to 0.9 mA/cm2, respectively. The lower io values obtained in 1M HBr solution compared to in H2SO4 might be due to the adsorption of Br- on the active surface. Stable electrochemical active surface area (ECSA) of RhxSy catalyst was obtained for CV scan limits between 0 V and 0.65 V vs. RHE. Scans with upper voltage limit beyond 0.65 V led to decreased and unreproducible ECSA measurements.

  17. Highly Active and Stable MgAl2O4 Supported Rh and Ir Catalysts for Methane Steam Reforming: A Combined Experimental and Theoretical Study

    SciTech Connect (OSTI)

    Mei, Donghai; Glezakou, Vassiliki Alexandra; Lebarbier, Vanessa MC; Kovarik, Libor; Wan, Haiying; Albrecht, Karl O.; Gerber, Mark A.; Rousseau, Roger J.; Dagle, Robert A.

    2014-07-01

    In this work we present a combined experimental and theoretical investigation of stable MgAl2O4 spinel-supported Rh and Ir catalysts for the steam methane reforming (SMR) reaction. Firstly, catalytic performance for a series of noble metal catalysts supported on MgAl2O4 spinel was evaluated for SMR at 600-850°C. Turnover rate at 850°C follows the order: Pd > Pt > Ir > Rh > Ru > Ni. However, Rh and Ir were found to have the best combination of activity and stability for methane steam reforming in the presence of simulated biomass-derived syngas. It was found that highly dispersed ~2 nm Rh and ~1 nm Ir clusters were formed on the MgAl2O4 spinel support. Scanning Transition Electron Microscopy (STEM) images show that excellent dispersion was maintained even under challenging high temperature conditions (e.g. at 850°C in the presence of steam) while Ir and Rh catalysts supported on Al2O3 were observed to sinter at increased rates under the same conditions. These observations were further confirmed by ab initio molecular dynamics (AIMD) simulations which find that ~1 nm Rh and Ir particles (50-atom cluster) bind strongly to the MgAl2O4 surfaces via a redox process leading to a strong metal-support interaction, thus helping anchor the metal clusters and reduce the tendency to sinter. Density functional theory (DFT) calculations suggest that these supported smaller Rh and Ir particles have a lower work function than larger more bulk-like ones, which enables them to activate both water and methane more effectively than larger particles, yet have a minimal influence on the relative stability of coke precursors. In addition, theoretical mechanistic studies were used to probe the relationship between structure and reactivity. Consistent with the experimental observations, our theoretical modeling results also suggest that the small spinel-supported Ir particle catalyst is more active than the counterpart of Rh catalyst for SMR. This work was financially supported by the United States Department of Energy (DOE)’s Bioenergy Technologies Office (BETO) and performed at the Pacific Northwest National Laboratory (PNNL). PNNL is a multi-program national laboratory operated for DOE by Battelle Memorial Institute. Computing time was granted by a user proposal at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) located at PNNL. Part of the computational time was provided by the National Energy Research Scientific Computing Center (NERSC).

  18. Figure S1.Technical diagram of the 1-by-3 tandem differential mobility analyzer (cf. schematic diagram shown in Figure 1). Relative humidity sensors are located at positions RH,

    E-Print Network [OSTI]

    valve used for on-off flow control; MFC, mass flow controller; T, temperature sensor; CA, filtered Diffusion Dryer Pinch Valve Pressure Regulator 3 3 3 Aerosol Out Humidity Conditioner Flow Sheath air out=48% RH0=43% Mobility diameter (nm) Particleconcentration(#cm-3bin-1) Entering DMAmono with RH0 Passing

  19. The effect of GnRH on induction of follicular development and ovulation in anovulatory and ovulatory mares 

    E-Print Network [OSTI]

    Hennington, Debra Louise

    1981-01-01

    pad faq qua!eabeunooua pue aI!oi 'aouaLged unuse gfasEw u! anaL Iaq aw bufqew pue neM aqq. aw 5u!Moqs uo3. noE queqg 'yanqui og 'F, Cfeufg puff . paydwaqge aneq y ge!fg ffe u! qua!eabeunooua pue quoddns 'aoueueaquog ufaqg uog uopbufuuaW I Cassnff... treatment and 70% of the time during GnRH treatment. Control anovulatory mares exhibited estrous behavior 17'K and 15% of the time during the two 25 U1 Q +J Ql Q CL C) c o ) O fO O O Cl col (LUj/6") SN3BOJS3908d 26 courses of sham...

  20. Effects of gonadotropin-releasing hormone (GnRH) on main olfactory input to the medial amygdala in male hamsters. Blake, CB, Meredith, M. Florida State University,

    E-Print Network [OSTI]

    Meredith, Michael

    Effects of gonadotropin-releasing hormone (GnRH) on main olfactory input to the medial amygdala mating behavior is dependent on chemosensory input from the main olfactory and vomeronasal systems, whose. In sexually-naïve males, vomeronasal organ removal (VNX), but not main olfactory lesion, impairs mating

  1. Systematics of the temperature-dependent interplane resistivity in Ba(Fe1-xMx)?As? (M=Co, Rh, Ni, and Pd)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tanatar, M. A.; Ni, N.; Thaler, A.; Bud’ko, S. L.; Canfield, P. C.; Prozorov, R.

    2011-07-27

    Temperature-dependent interplane resistivity ?c(T) was measured systematically as a function of transition-metal substitution in the iron-arsenide superconductors Ba(Fe1-xMx)?As?, M=Ni, Pd, Rh. The data are compared with the behavior found in Ba(Fe1-xCox)?As?, revealing resistive signatures of pseudogap. In all compounds we find resistivity crossover at a characteristic pseudogap temperature T* from nonmetallic to metallic temperature dependence on cooling. Suppression of T* proceeds very similarly in cases of Ni and Pd doping and much faster than in similar cases of Co and Rh doping. In cases of Co and Rh doping an additional minimum in the temperature-dependent ?c emerges for high dopings,more »when superconductivity is completely suppressed. These features are consistent with the existence of a charge gap covering part of the Fermi surface. The part of the Fermi surface affected by this gap is notably larger for Ni- and Pd-doped compositions than in Co- and Rh-doped compounds.« less

  2. DNA Cleavage by Photogenerated Rh2(O2CCH3)4(H2O)2 Patty K.-L. Fu, Patricia M. Bradley, and Claudia Turro*

    E-Print Network [OSTI]

    Turro, Claudia

    the subject of intense investigation since, upon light activation, they can act as reporters of DNA structure and coordination of the dirhodium core to single-stranded oligonucleotides has been observed, the mode of binding-methylpyridinium tetrafluoroborate (py+),17 results in the formation of the one-electron-oxidized complex, Rh2(O2

  3. Oxidation of H on Rh(111): H2O product velocity and angular distributions K. D. Gibson, J. I. Colonell, and S. J. Sibener

    E-Print Network [OSTI]

    Sibener, Steven

    Oxidation of H on Rh(111): H2O product velocity and angular distributions K. D. Gibson, J. I measured the angular dependence of the energy and intensity of the product H2O at Ts 650 K. The velocity distributed. © 1995 American Institute of Physics. INTRODUCTION The angular and velocity distributions

  4. Tuning the Curie temperature of L1{sub 0} ordered FePt thin films through site-specific substitution of Rh

    SciTech Connect (OSTI)

    Xu, Dongbin; Sun, Cheng-Jun E-mail: msecgm@nus.edu.sg; Heald, Steve M.; Chen, Jing-Sheng; Chow, Gan Moog E-mail: msecgm@nus.edu.sg; Zhou, Tie-Jun; Bergman, Anders; Sanyal, Biplab

    2014-10-14

    In structurally ordered magnetic thin films, the Curie temperature (T{sub C}) of ferromagnetic films depends on the exchange integral of the short range ordered neighboring atoms. The exchange integral may be adjusted by controlling the elemental substitutional concentration at the lattice site of interest. We show how to control the T{sub C} in high anisotropy L1{sub 0} Fe{sub 50}Pt{sub 50} magnetic thin films by substituting Rh into the Pt site. Rh substitution in L1{sub 0} FePt modified the local atomic environment and the corresponding electronic properties, while retaining the ordered L1{sub 0} phase. The analysis of extended x-ray Absorption Fine Structure spectra shows that Rh uniformly substitutes for Pt in L1{sub 0} FePt. A model of antiferromagnetic defects caused by controlled Rh substitution of the Pt site, reducing the T{sub C,} is proposed to interpret this phenomenon and its validity is further examined by ab initio density functional calculations.

  5. Kinetic and Performance Studies of the Regeneration Phase of Model Pt/Ba/Rh NOx Traps for Design and Optimization

    SciTech Connect (OSTI)

    Michael Harold; Vemuri Balakotaiah

    2010-05-31

    In this project a combined experimental and theoretical approach was taken to advance our understanding of lean NOx trap (LNT) technology. Fundamental kinetics studies were carried out of model LNT catalysts containing variable loadings of precious metals (Pt, Rh), and storage components (BaO, CeO{sub 2}). The Temporal Analysis of Products (TAP) reactor provided transient data under well-characterized conditions for both powder and monolith catalysts, enabling the identification of key reaction pathways and estimation of the corresponding kinetic parameters. The performance of model NOx storage and reduction (NSR) monolith catalysts were evaluated in a bench scale NOx trap using synthetic exhaust, with attention placed on the effect of the pulse timing and composition on the instantaneous and cycle-averaged product distributions. From these experiments we formulated a global model that predicts the main spatio-temporal features of the LNT and a mechanistic-based microkinetic models that incorporates a detailed understanding of the chemistry and predicts more detailed selectivity features of the LNT. The NOx trap models were used to determine its ability to simulate bench-scale data and ultimately to evaluate alternative LNT designs and operating strategies. The four-year project led to the training of several doctoral students and the dissemination of the findings as 47 presentations in conferences, catalysis societies, and academic departments as well 23 manuscripts in peer-reviewed journals. A condensed review of NOx storage and reduction was published in an encyclopedia of technology.

  6. Effects of GnRH and Prostaglandin Combined with a Short Progestin Regimen on the Synchrony of Estrus and Ovulation in Ewes During the Breeding Season 

    E-Print Network [OSTI]

    Dickison, James William

    2012-02-14

    Approved by: Co-Chairs of Committee, W. Shawn Ramsey David W. Forrest Committee Members, Clay A. Cavinder Glenn A. Holub Chris Boleman Head of Department, Gary Acuff December 2010 Major Subject: Animal Science iii ABSTRACT Effects of Gn... Committee: Dr. W. Shawn Ramsey Dr. David W. Forrest Two trials were conducted to quantify the effects of GnRH and prostaglandin in conjunction with a 7-d CIDR on estrus and on pregnancy rate in comparison with a traditional...

  7. Structure Determination of Ba8CoRh6O21, a New Member of the 2H-Perovskite Related Oxides

    E-Print Network [OSTI]

    zur Loye, Hans-Conrad

    Structure Determination of Ba8CoRh6O21, a New Member of the 2H-Perovskite Related Oxides H.-C. zur of an m = 5, n = 3 member of the A3n+3mA'nB3m+nO9m+6n family of 2H hexagonal perovskite related oxides. For this reason, perovskite and perovskite-related oxides in particular have long provided excellent candidates

  8. Dendrimer Templated Synthesis of One Nanometer Rh and Pt Particles Supported on Mesoporous Silica: Catalytic Activity for Ethylene and Pyrrole Hydrogenation.

    SciTech Connect (OSTI)

    Huang, Wenyu; Kuhn, John N.; Tsung, Chia-Kuang; Zhang, Yawen; Habas, Susan E.; Yang, Peidong; Somorjai, Gabor A.

    2008-05-09

    Monodisperse rhodium (Rh) and platinum (Pt) nanoparticles as small as {approx}1 nm were synthesized within a fourth generation polyaminoamide (PAMAM) dendrimer, a hyperbranched polymer, in aqueous solution and immobilized by depositing onto a high-surface-area SBA-15 mesoporous support. X-ray photoelectron spectroscopy indicated that the as-synthesized Rh and Pt nanoparticles were mostly oxidized. Catalytic activity of the SBA-15 supported Rh and Pt nanoparticles was studied with ethylene hydrogenation at 273 and 293 K in 10 torr of ethylene and 100 torr of H{sub 2} after reduction (76 torr of H{sub 2} mixed with 690 torr of He) at different temperatures. Catalysts were active without removing the dendrimer capping but reached their highest activity after hydrogen reduction at a moderate temperature (423 K). When treated at a higher temperature (473, 573, and 673 K) in hydrogen, catalytic activity decreased. By using the same treatment that led to maximum ethylene hydrogenation activity, catalytic activity was also evaluated for pyrrole hydrogenation.

  9. First Measurement of the $^{96}$Ru(p,$?$)$^{97}$Rh Cross Section for the p-Process with a Storage Ring

    E-Print Network [OSTI]

    Bo Mei; Thomas Aumann; Shawn Bishop; Klaus Blaum; Konstanze Boretzky; Fritz Bosch; Carsten Brandau; Harald Bräuning; Thomas Davinson; Iris Dillmann; Christina Dimopoulou; Olga Ershova; Zsolt Fülöp; Hans Geissel; Jan Glorius; György Gyürky; Michael Heil; Franz Käppeler; Aleksandra Kelic-Heil; Christophor Kozhuharov; Christoph Langer; Tudi Le Bleis; Yuri Litvinov; Gavin Lotay; Justyna Marganiec; Gottfried Münzenberg; Fritz Nolden; Nikolaos Petridis; Ralf Plag; Ulrich Popp; Ganna Rastrepina; René Reifarth; Björn Riese; Catherine Rigollet; Christoph Scheidenberger; Haik Simon; Kerstin Sonnabend; Markus Steck; Thomas Stöhlke; Tamás Szücs; Klaus Sümmerer; Günter Weber; Helmut Weick; Danyal Winters; Natalya Winters; Philip Woods; Qiping Zhong

    2015-07-10

    This work presents a direct measurement of the $^{96}$Ru($p, \\gamma$)$^{97}$Rh cross section via a novel technique using a storage ring, which opens opportunities for reaction measurements on unstable nuclei. A proof-of-principle experiment was performed at the storage ring ESR at GSI in Darmstadt, where circulating $^{96}$Ru ions interacted repeatedly with a hydrogen target. The $^{96}$Ru($p, \\gamma$)$^{97}$Rh cross section between 9 and 11 MeV has been determined using two independent normalization methods. As key ingredients in Hauser-Feshbach calculations, the $\\gamma$-ray strength function as well as the level density model can be pinned down with the measured ($p, \\gamma$) cross section. Furthermore, the proton optical potential can be optimized after the uncertainties from the $\\gamma$-ray strength function and the level density have been removed. As a result, a constrained $^{96}$Ru($p, \\gamma$)$^{97}$Rh reaction rate over a wide temperature range is recommended for $p$-process network calculations.

  10. First Measurement of the $^{96}$Ru(p,$\\gamma$)$^{97}$Rh Cross Section for the p-Process with a Storage Ring

    E-Print Network [OSTI]

    Mei, Bo; Bishop, Shawn; Blaum, Klaus; Boretzky, Konstanze; Bosch, Fritz; Brandau, Carsten; Bräuning, Harald; Davinson, Thomas; Dillmann, Iris; Dimopoulou, Christina; Ershova, Olga; Fülöp, Zsolt; Geissel, Hans; Glorius, Jan; Gyürky, György; Heil, Michael; Käppeler, Franz; Kelic-Heil, Aleksandra; Kozhuharov, Christophor; Langer, Christoph; Bleis, Tudi Le; Litvinov, Yuri; Lotay, Gavin; Marganiec, Justyna; Münzenberg, Gottfried; Nolden, Fritz; Petridis, Nikolaos; Plag, Ralf; Popp, Ulrich; Rastrepina, Ganna; Reifarth, René; Riese, Björn; Rigollet, Catherine; Scheidenberger, Christoph; Simon, Haik; Sonnabend, Kerstin; Steck, Markus; Stöhlke, Thomas; Szücs, Tamás; Sümmerer, Klaus; Weber, Günter; Weick, Helmut; Winters, Danyal; Winters, Natalya; Woods, Philip; Zhong, Qiping

    2015-01-01

    This work presents a direct measurement of the $^{96}$Ru($p, \\gamma$)$^{97}$Rh cross section via a novel technique using a storage ring, which opens opportunities for reaction measurements on unstable nuclei. A proof-of-principle experiment was performed at the storage ring ESR at GSI in Darmstadt, where circulating $^{96}$Ru ions interacted repeatedly with a hydrogen target. The $^{96}$Ru($p, \\gamma$)$^{97}$Rh cross section between 9 and 11 MeV has been determined using two independent normalization methods. As key ingredients in Hauser-Feshbach calculations, the $\\gamma$-ray strength function as well as the level density model can be pinned down with the measured ($p, \\gamma$) cross section. Furthermore, the proton optical potential can be optimized after the uncertainties from the $\\gamma$-ray strength function and the level density have been removed. As a result, a constrained $^{96}$Ru($p, \\gamma$)$^{97}$Rh reaction rate over a wide temperature range is recommended for $p$-process network calculations.

  11. Wiedemann-Franz law and nonvanishing temperature scale across the field-tuned quantum critical point of YbRh2Si2

    SciTech Connect (OSTI)

    Reid, J.-Ph.; Tanatar, Makariy; Daou, R.; Hu, Rongwei; Petrovic, C.; Taillefer, Louis

    2014-01-23

    The in-plane thermal conductivity kappa and electrical resistivity rho of the heavy-fermion metal YbRh2Si2 were measured down to 50 mK for magnetic fields H parallel and perpendicular to the tetragonal c axis, through the field-tuned quantum critical point H-c, at which antiferromagnetic order ends. The thermal and electrical resistivities, w L0T/kappa and rho, show a linear temperature dependence below 1 K, typical of the non-Fermi-liquid behavior found near antiferromagnetic quantum critical points, but this dependence does not persist down to T = 0. Below a characteristic temperature T-star similar or equal to 0.35 K, which depends weakly on H, w(T) and rho(T) both deviate downward and converge as T -> 0. We propose that T-star marks the onset of short-range magnetic correlations, persisting beyond H-c. By comparing samples of different purity, we conclude that the Wiedemann-Franz law holds in YbRh2Si2, even at H-c, implying that no fundamental breakdown of quasiparticle behavior occurs in this material. The overall phenomenology of heat and charge transport in YbRh2Si2 is similar to that observed in the heavy-fermion metal CeCoIn5, near its own field-tuned quantum critical point.

  12. Temperature and RH Targets

    Broader source: Energy.gov [DOE]

    Presented by Vishal O Mittal of the Florida Solar Energy Center at the High Temperature Membrane Working Group Meeting, San Francisco, September 14, 2006.

  13. Microsoft Word - ORNL RH

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGE OFDetection of Hydrates on Gas5 15NEWS MEDIA CONTACT: March

  14. Microsoft Word - SRS RH

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGE OFDetection of Hydrates7 UnlimitedSupply6254 3.95AprTheFOR

  15. RH_SRS_Shipment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMassR&D100 Winners * Impacts on Global TechnologyProceeding SignPrice Volatility

  16. RH TRU Waste Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) by Carbon-RichProton Delivery andInnovations INFORMATION ExplainMadison

  17. Bioorganometallic chemistry: biocatalytic oxidation reactions with biomimetic nad+/nadh co-factors and [cp*rh(bpy)h]+ for selective organic synthesis

    SciTech Connect (OSTI)

    Lutz, Jochen; Hollman, Frank; Ho, The Vinh; Schnyder, Adrian; Fish, Richard H.; Schmid, Andreas

    2004-03-09

    The biocatalytic, regioselective hydroxylation of 2-hydroxybiphenyl to the corresponding catechol was accomplished utilizing the monooxygenase 2-hydroxybiphenyl 3-monooxygenase (HbpA). The necessary natural nicotinamide adenine dinucleotide (NAD{sup +}) co-factor for this biocatalytic process was replaced by a biomimetic co-factor, N-benzylnicotinamide bromide, 1a. The interaction between the flavin (FAD) containing HbpA enzyme and the corresponding biomimetic NADH compound, N-benzyl-1,4-dihdronicotinamide, 1b, for hydride transfers, was shown to readily occur. The in situ recycling of the reduced NADH biomimic 1b from 1a was accomplished with [Cp*Rh(bpy)H](Cl); however, productive coupling of this regeneration reaction to the enzymatic hydroxylation reaction was not totally successful, due to a deactivation process concerning the HbpA enzyme peripheral groups; i.e., -SH or -NH{sub 2} possibly reacting with the precatalyst, [Cp*Rh(bpy)(H{sub 2}O)](Cl){sub 2}, and thus inhibiting the co-factor regeneration process. The deactivation mechanism was studied, and a promising strategy of derivatizing these peripheral -SH or -NH{sub 2} groups with a polymer containing epoxide was successful in circumventing the undesired interaction between HbpA and the precatalyst. This latter strategy allowed tandem co-factor regeneration using 1a or 2a, [Cp*Rh(bpy)(H2O)](Cl){sub 2}, and formate ion, in conjunction with the polymer bound, FAD containing HbpA enzyme to provide the catechol product.

  18. Fits to the Fermi-LAT GeV excess with RH sneutrino dark matter: implications for direct and indirect dark matter searches and the LHC

    E-Print Network [OSTI]

    Cerdeno, D G; Robles, S

    2015-01-01

    We show that the right-handed (RH) sneutrino in the NMSSM can account for the observed excess in the Fermi-LAT spectrum of gamma rays from the Galactic Centre, while fulfilling all the current experimental constraints from the LHC as well as from direct and indirect dark matter searches. We have explored the parameter space of this scenario, computed the gamma ray spectrum for each phenomenologically viable solution and then performed a chi^2 fit to the excess. Unlike previous studies based on model independent interpretations, we have taken into account the full annihilation spectrum, without assuming pure annihilation channels. Furthermore, we have incorporated limits from direct detection experiments, LHC bounds and also the constraints from Fermi-LAT on dwarf spheroidal galaxies (dSphs) and gamma ray spectral lines. In addition, we have estimated the effect of the most recent Fermi-LAT reprocessed data (Pass~8). In general, we obtain good fits to the GCE when the RH sneutrino annihilates mainly into pairs...

  19. Electronic structure of Ce?RhIn?: A two-dimensional heavy-fermion system studied by angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Rui; Petrovic, C.; Mou, Daixing; Liu, Chang; Zhao, Xin; Yao, Yongxin; Ryu, Hyejin; Ho, Kai -Ming; Kaminski, Adam

    2015-04-01

    We use angle-resolved photoemission spectroscopy (ARPES) to study the 2D heavy fermion superconductor, Ce?RhIn?. The Fermi surface is rather complicated and consists of several hole and electron pockets with one of the sheets displaying strong nesting properties with a q-vector of (0.32, 0.32) ?/a. We do not observe kz dispersion of the Fermi sheets, which is consistent with the expected 2D character of the electronic structure. Comparison of the ARPES data to band structure calculations suggests that a localized picture of the f-electrons works best. While there is some agreement in the overall band dispersion and location of the Fermimore »sheets, the model does not reproduce all observed bands and is not completely accurate for those it does. Our data paves the way for improving the band structure calculations and the general understanding of the transport and thermodynamical properties of this material.« less

  20. Electronic structure of Ce2RhIn8: A two-dimensional heavy-fermion system studied by angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Rui; Mou, Daixing; Liu, Chang; Zhao, Xin; Yao, Yongxin; Ryu, Hyejin; Petrovic, C.; Ho, Kai -Ming; Kaminski, Adam

    2015-04-01

    We use angle-resolved photoemission spectroscopy (ARPES) to study the 2D heavy fermion superconductor, Ce?RhIn?. The Fermi surface is rather complicated and consists of several hole and electron pockets with one of the sheets displaying strong nesting properties with a q-vector of (0.32, 0.32) ?/a. We do not observe kz dispersion of the Fermi sheets, which is consistent with the expected 2D character of the electronic structure. Comparison of the ARPES data to band structure calculations suggests that a localized picture of the f-electrons works best. While there is some agreement in the overall band dispersion and location of the Fermimore »sheets, the model does not reproduce all observed bands and is not completely accurate for those it does. As a result, our data paves the way for improving the band structure calculations and the general understanding of the transport and thermodynamical properties of this material.« less

  1. Observation of a Large Magnetic Anisotropy in the New 2H-Perovskite Related Oxide Ba8CoRh6O21: Magnetic Measurements on Aligned Single Crystals

    E-Print Network [OSTI]

    zur Loye, Hans-Conrad

    Observation of a Large Magnetic Anisotropy in the New 2H-Perovskite Related Oxide Ba8CoRh6O21 of the A3n+3mAnB3m+nO9m+6n family of 2H hexagonal perovskite related oxides and contains chains consisting, perovskite and perovskite-related oxides in particular have long provided excellent candidates for structural

  2. Change in magnetic and structural properties of FeRh thin films by gold cluster ion beam irradiation with the energy of 1.67?MeV/atom

    SciTech Connect (OSTI)

    Koide, T.; Iwase, A. [Department of Materials Science, Osaka Prefecture University, Sakai, Osaka 599-8531 (Japan); Saitoh, Y. [Japan Atomic Energy Agency, Takasaki, Gunma 370-1292 (Japan); Sakamaki, M.; Amemiya, K. [High Energy Accelerator Research Organization, Tsukuba, Ibaraki 305-0801 (Japan); Matsui, T., E-mail: t-matsui@21c.osakafu-u.ac.jp [Research Organization for the 21st Century, Osaka Prefecture University Sakai, Osaka 599-8531 (Japan)

    2014-05-07

    The effect of energetic cluster ion beam irradiation on magnetic and structural properties of FeRh thin films have been investigated. The cluster ions used in the present studies consist of a few gold atoms with the energy of 1.67?MeV/gold atom. Saturation magnetization of the sample irradiated with Au3 cluster ion beam (280?emu/cc) is larger than that for the irradiated sample with Au1 ion beam (240?emu/cc) for the same irradiation ion fluence. These results can also be confirmed by the X-ray magnetic circular dichroism (XMCD) measurement; the XMCD signal for Au3 cluster ion irradiation is larger than that for Au1 ion irradiation. Since the ion beam irradiation induced magnetization of FeRh is significantly correlated with the amount of the lattice defects in the samples, cluster ion beam irradiation can be considered to effectively introduce the lattice defects in B2-type FeRh rather than the single ion beam. Consequently, cluster ion irradiation is better than single ion irradiation for the viewpoint of saturation magnetization, even if the same irradiation energy is deposited in the samples.

  3. Synthesis, structure and chemical bonding of CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x=0, 1.32, and 2) and SrCo{sub 2}Si{sub 2}

    SciTech Connect (OSTI)

    Hlukhyy, Viktor Hoffmann, Andrea V.; Fässler, Thomas F.

    2013-07-15

    The finding of superconductivity in Ba{sub 0.6}K{sub 0.4}Fe{sub 2}As{sub 2} put the attention on the investigation of compounds that crystallize with ThCr{sub 2}Si{sub 2} structure type such as AT{sub 2}X{sub 2} (A=alkali/alkaline earth/rare earth element; T=transition metal and X=element of the 13–15th group). In this context the silicides CaFe{sub 2}Si{sub 2}, CaFe{sub 0.68(6)}Rh{sub 1.32(6)}Si{sub 2}, CaRh{sub 2}Si{sub 2} and SrCo{sub 2}Si{sub 2} have been synthesized by reaction of the elements under an argon atmosphere. Single crystals were obtained by special heat treatment in welded niobium/tantalum ampoules. The compounds were investigated by means of powder and single crystal X-ray diffraction. All compounds crystallize in the ThCr{sub 2}Si{sub 2}-type structure with space group I4/mmm (No. 139): a=3.939(1) Å, c=10.185(1) Å, R{sub 1}=0.045, 85 F{sup 2} values, 8 variable parameters for CaFe{sub 2}Si{sub 2}; a=4.0590(2) Å, c=9.9390(8) Å, R{sub 1}=0.030, 90 F{sup 2} values, 10 variable parameters for CaFe{sub 0.68(6)}Rh{sub 1.32(6)}Si{sub 2}; a=4.0695(1) Å, c=9.9841(3) Å, R{sub 1}=0.031, 114 F{sup 2} values, 9 variable parameters for CaRh{sub 2}Si{sub 2}; and a=3.974(1) Å, c=10.395(1) Å, R{sub 1}=0.036, 95 F{sup 2} values, 8 variable parameters for SrCo{sub 2}Si{sub 2}. The structure of SrCo{sub 2}Si{sub 2} contains isolated [Co{sub 2}Si{sub 2}]{sup 2?} 2D-layers in the ab-plane whereas in CaFe{sub 2?x}Rh{sub x}Si{sub 2} the [T{sub 2}Si{sub 2}] layers (T=Fe and Rh) are interconnected along the c-axis via Si3Si bonds resulting in a three-dimentional (3D) [T{sub 2}Si{sub 2}]{sup 2?} polyanions and therefore belong to the so-called collapsed form of the ThCr{sub 2}Si{sub 2}-type structure. The SrCo{sub 2}Si{sub 2} and CaRh{sub 2}Si{sub 2} are isoelectronic to the parent 122 iron–pnictide superconductors AeFe{sub 2}As{sub 2} (Ae=alkaline earth elements), whereas CaFe{sub 2}Si{sub 2} is a full substituted variant (As/Si) of CaFe{sub 2}As{sub 2}. The crystal chemistry and chemical bonding in the title compounds are discussed in terms of LMTO band structure calculations and a topological analysis using the Electron Localization Function (ELF). - Graphical abstract: The SrCo{sub 2}Si{sub 2} and CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x==0, 1.32, and 2) crystallize in the ThCr{sub 2}Si{sub 2}-type. The structure of SrCo{sub 2}Si{sub 2} contains isolated [Co{sub 2}Si{sub 2}]{sup 2?} layers in the ab-plane, whereas the [T{sub 2}Si{sub 2}] layers in CaFe{sub 2?x}Rh{sub x}Si{sub 2} are interconnected along the c-axis via Si3Si bonds resulting in a [T{sub 2}Si{sub 2}]{sup 2?} network. - Highlights: • Synthesis and structure of ternary silicides SrCo{sub 2}Si{sub 2} and CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x=0, 1.32, and 2). • The SrCo{sub 2}Si{sub 2} and CaRh{sub 2}Si{sub 2} are isoelectronic to the parent 122 iron–pnictide superconductors AeFe{sub 2}As{sub 2}. • CaFe{sub 2}Si{sub 2} is a full substituted variant (As/Si) of superconductor CaFe{sub 2}As{sub 2}. • The title compounds demonstrate the tunable Si3Si distances.

  4. High Hydrogen Concentrations Detected In The Underground Vaults For RH-TRU Waste At INEEL Compared With Calculated Values Using The INEEL-Developed Computer Code

    SciTech Connect (OSTI)

    Rajiv Bhatt; Soli Khericha

    2005-02-01

    About 700 remote-handled transuranic (RH-TRU) waste drums are stored in about 144 underground vaults at the Intermediate-Level Transuranic Storage Facility at the Idaho National Environmental and Engineering Laboratory’s (INEEL’s) Radioactive Waste Management Complex (RWMC). These drums were shipped to the INEEL from 1976 through 1996. During recent monitoring, concentrations of hydrogen were found to be in excess of lower explosive limits. The hydrogen concentration in one vault was detected to be as high as 18% (by volume). This condition required evaluation of the safety basis for the facility. The INEEL has developed a computer program to estimate the hydrogen gas generation as a function of time and diffusion through a series of layers (volumes), with a maximum five layers plus a sink/environment. The program solves the first-order diffusion equations as a function of time. The current version of the code is more flexible in terms of user input. The program allows the user to estimate hydrogen concentrations in the different layers of a configuration and then change the configuration after a given time; e.g.; installation of a filter on an unvented drum or placed in a vault or in a shipping cask. The code has been used to predict vault concentrations and to identify potential problems during retrieval and aboveground storage. The code has generally predicted higher hydrogen concentrations than the measured values, particularly for the drums older than 20 year, which could be due to uncertainty and conservative assumptions in drum age, heat generation rate, hydrogen generation rate, Geff, and diffusion rates through the layers.

  5. Role of the reaction intermediates in determining PHIP (parahydrogen induced polarization) effect in the hydrogenation of acetylene dicarboxylic acid with the complex [Rh (dppb)]{sup +} (dppb: 1,4-bis(diphenylphosphino)butane)

    SciTech Connect (OSTI)

    Reineri, F.; Aime, S.; Gobetto, R.; Nervi, C.

    2014-03-07

    This study deals with the parahydrogenation of the symmetric substrate acetylene dicarboxylic acid catalyzed by a Rh(I) complex bearing the chelating diphosphine dppb (1,4-bis(diphenylphosphino)butane). The two magnetically equivalent protons of the product yield a hyperpolarized emission signal in the {sup 1}H-NMR spectrum. Their polarization intensity varies upon changing the reaction solvent from methanol to acetone. A detailed analysis of the hydrogenation pathway is carried out by means of density functional theory calculations to assess the structure of hydrogenation intermediates and their stability in the two solvents. The observed polarization effects have been accounted on the basis of the obtained structures. Insights into the lifetime of a short-lived reaction intermediate are also obtained.

  6. First-principles studies of structural stabilities and enthalpies of formation of refractory intermetallics: TM and TM3 (T = Ti, Zr, Hf; M = Ru, Rh, Pd, Os, Ir, Pt)

    SciTech Connect (OSTI)

    Xing, Weiwei; Chen, X.; Li, Dianzhong; Li, Y. Y.; Fu, Chong Long; Meschel, S.

    2012-01-01

    Using first-principles local density functional approach, we have calculated the ground-state structural phase stabilities and enthalpies of formation of thirty-six binary transition-metal refractory TM and TM3 compounds formed by Group IV elements T (T = Ti, Zr, Hf) and platinum group elements M (M = Ru, Rh, Pd, Os, Ir, Pt) . We compared our results with the available experimental data and found good agreement between theory and experiment in both the trends of structural stabilities and the magnitudes of formation enthalpies. Moreover, based on our calculated results, an empirical relationship between cohesive energies ( E) and melting temperatures (Tm) was derived as Tm = 0.0292 E/kB (where kB is the Boltzmann constant) for both TM and TM3 compounds.

  7. S-H bond activation in H{sub 2}S and thiols by [RhMn(CO){sub 4}(Ph{sub 2}PCH{sub 2}PPh{sub 2}){sub 2}]. Compounds containing terminal or bridging sulfhydryl and thiolato groups

    SciTech Connect (OSTI)

    Li-Sheng Wang; McDonald, R.; Cowie, M. [Univ. of Alberta, Edmonton (Canada)

    1994-08-17

    A rhodium-magnesium carbonyl-phosphines reacted with thiols to yield the products of S-H addition. Further reactions result in bridging sulfide can be alkylated or protonated at the sulfur. The compound, [RhMn(CO){sub 4}({mu}-S)(dppm){sub 2}], was structurally characterized by X-ray crystallography.

  8. VOLUME 87, NUMBER 19 P H Y S I C A L R E V I E W L E T T E R S 5 NOVEMBER 2001 Distinct Reaction Mechanisms in the Catalytic Oxidation of Carbon Monoxide on Rh(110)

    E-Print Network [OSTI]

    Hla, Saw-Wai

    Mechanisms in the Catalytic Oxidation of Carbon Monoxide on Rh(110): Scanning Tunneling Microscopy for catalytic oxidation of hydrogen on a platinum surface [3]. In the latter case, the two different mechanisms calculations, we identify the reaction mechanism for the oxidation of carbon monoxide to carbon dioxide

  9. Dimethyl sulfide substituted mixed-metal clusters: Synthesis, structure, and characterization of HRuCo sub 3 (CO) sub 11 (SMe sub 2 ) and (HRuRh sub 3 (CO) sub 9 ) sub 2 (SMe sub 2 ) sub 3

    SciTech Connect (OSTI)

    Rossi, S.; Pursianinen, J.; Ahlgren, M.; Pakkanen, T.A. (Univ. of Joensuu (Finland))

    1990-02-01

    Ligand substitution reactions of dimethyl sulfide with mixed-metal clusters are described. The clusters HRuCo{sub 3}(CO){sub 11}(SMe{sub 2}) (1) and (HRuRh{sub 3}(CO){sub 9}){sub 2}(SMe{sub 2}){sub 3} (2) have been prepared by reactions of SMe{sub 2} with the neutral parent clusters. Their crystal structures have been established: 1, monoclinic, space group P2{sub 1}/n, a = 11.459 (5) {angstrom}, b = 12.484 (4) {angstrom}, c = 14.384 (4) {angstrom}, {beta} = 96.40 (3){degree}, Z = 4; 2, trigonal, space group R3c, a = 13.181 (7) {angstrom}, {alpha} = 75.54 (5){degree}, Z = 2. Dimethyl sulfide coordinates terminally as a two-electron donor on basal cobalt in 1 and as a bridging four-electron donor causing unusual dimerization of clusters in 2. The carbonyl arrangement of the parent clusters was not changed during the ligand substitution, and hydride ligands bridge the three basal metals in both compounds.

  10. IPP RH-TRU Waste Study - Summary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (JournalvivoHighHussein KhalilResearch8

  11. Retrieval and Repackaging of RH-TRU Waste - General Presentation...

    Office of Environmental Management (EM)

    * Characterization : - HGRS ( High Resolution Gamma Spectroscopy) - IPAN ( Imaging Passive- Active Neutron) * Packaging (if needed) Control Room Electrical Rooms Ventilation...

  12. Step enhanced dehydrogenation of ethanol on Rh Andrea Resta a

    E-Print Network [OSTI]

    Li, Weixue

    , Lund University, Box 118, S-22100 Lund, Sweden b State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China a r t i c l e i n f

  13. R.H. Ottewill A.B. Schofield

    E-Print Network [OSTI]

    Schofield, Andrew B.

    -[butylmethacrylate] particles as the host material and poly-[styrene] particles for engulf- ment. Initially, anionic poly-[styrene occurred. Key words Engulfment ­ interfacial energy ­ heterocoagulation ­ Poly- [styrene] ­ Poly to be engulfed were poly-(styrene), PS, prepared by an emulsion polym

  14. WIPP RH-TRU Waste Study - Notice To Users

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired SolarAbout /Two0 -UsingHeatInformationDevelopmentProgram*5

  15. ARM - PI Product - Radiosondes Corrected for Inaccuracy in RH Measurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow, Alaska OutreachCalendar NSAProductsMerged and correctedProductsRadiosondes

  16. Microsoft Word - MPUR_Feb2011_final_rh.docx

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets See(STEO) Highlights1 M68October7 1071

  17. K. Baird, F.-J. Decker, M. J. Hogan* , R.H. Iverson, P. Raimondi, R.H. Siemann, D. Walz

    E-Print Network [OSTI]

    in components or systems that could be part of an operating accelerator. This is a proposal to study key acceleration by an electron beam-driven plasma wave. E-157 data taking was completed in the Spring of 2000 Linear Accelerator Center B.E. Blue, C.E. Clayton, E.S. Dodd, C. Joshi* , K.A. Marsh, W.B. Mori, S. Wang

  18. Effects of Bone Morphogenetic Protein (rhBMP-2) and Platelet Derived Growth Factor (rhPDGF-BB) on Ectopic Bone Formation In Rats

    E-Print Network [OSTI]

    Mardirosian, Martin Harootune

    2012-01-01

    in the treatment of certain periodontal defects when used inshown improvement in periodontal defects, which has lead tocarrier for periodontal intrabony defects in a product

  19. Materials Data on Ca(GeRh)2 (SG:139) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  20. Materials Data on LaGe3Rh (SG:107) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  1. Materials Data on CeGe3Rh (SG:107) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  2. Materials Data on Np(GeRh)2 (SG:139) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  3. Materials Data on La3(GeRh)4 (SG:71) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  4. Materials Data on La3(GeRh)4 (SG:71) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  5. Materials Data on PrGe3Rh (SG:107) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  6. Materials Data on ThSbRh (SG:216) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  7. Materials Data on Sr(GeRh)2 (SG:139) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  8. Materials Data on U3Sn13Rh4 (SG:223) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  9. Materials Data on Pu(SiRh)2 (SG:139) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  10. Materials Data on Np(GeRh)2 (SG:139) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  11. 1,2-Thio Group Migration in Rh(II) Carbene Reactions

    E-Print Network [OSTI]

    Wang, Jianbo

    Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry of these compounds gave 1,2-thio group migration products. No 1,2-hydride or 1,2- aryl migration products were in certain cases. Among the 1,2-migration reac- tions, the 1,2-hydride migration is generally predomi- nant

  12. Materials Data on Rh3(PbS)2 (SG:166) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  13. Materials Data on Pr(GeRh)2 (SG:139) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  14. Materials Data on Tb(GeRh)2 (SG:139) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  15. Materials Data on U12Rh4Se31 (SG:139) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  16. Transuranic Waste Processing Center (TWPC) Legacy Tank RH-TRU Sludge Processing and Compliance Strategy - 13255

    SciTech Connect (OSTI)

    Rogers, Ben C.; Heacker, Fred K.; Shannon, Christopher [Wastren Advantage, Inc., Transuranic Waste Processing Center, 100 WIPP Road, Lenoir City, Tennessee 37771 (United States)] [Wastren Advantage, Inc., Transuranic Waste Processing Center, 100 WIPP Road, Lenoir City, Tennessee 37771 (United States); and others

    2013-07-01

    The U.S. Department of Energy (DOE) needs to safely and efficiently treat its 'legacy' transuranic (TRU) waste and mixed low-level waste (LLW) from past research and defense activities at the Oak Ridge National Laboratory (ORNL) so that the waste is prepared for safe and secure disposal. The TWPC operates an Environmental Management (EM) waste processing facility on the Oak Ridge Reservation (ORR). The TWPC is classified as a Hazard Category 2, non-reactor nuclear facility. This facility receives, treats, and packages low-level waste and TRU waste stored at various facilities on the ORR for eventual off-site disposal at various DOE sites and commercial facilities. The Remote Handled TRU Waste Sludge held in the Melton Valley Storage Tanks (MVSTs) was produced as a result of the collection, treatment, and storage of liquid radioactive waste originating from the ORNL radiochemical processing and radioisotope production programs. The MVSTs contain most of the associated waste from the Gunite and Associated Tanks (GAAT) in the ORNL's Tank Farms in Bethel Valley and the sludge (SL) and associated waste from the Old Hydro-fracture Facility tanks and other Federal Facility Agreement (FFA) tanks. The SL Processing Facility Build-outs (SL-PFB) Project is integral to the EM cleanup mission at ORNL and is being accelerated by DOE to meet updated regulatory commitments in the Site Treatment Plan. To meet these commitments a Baseline (BL) Change Proposal (BCP) is being submitted to provide continued spending authority as the project re-initiation extends across fiscal year 2012 (FY2012) into fiscal year 2013. Future waste from the ORNL Building 3019 U-233 Disposition project, in the form of U-233 dissolved in nitric acid and water, down-blended with depleted uranyl nitrate solution is also expected to be transferred to the 7856 MVST Annex Facility (formally the Capacity Increase Project (CIP) Tanks) for co-processing with the SL. The SL-PFB project will construct and install the necessary integrated systems to process the accumulated MVST Facilities SL inventory at the TWPC thus enabling safe and effective disposal of the waste. This BCP does not include work to support current MVST Facility Surveillance and Maintenance programs or the ORNL Building 3019 U-233 Disposition project, since they are not currently part of the TWPC prime contract. The purpose of the environmental compliance strategy is to identify the environmental permits and other required regulatory documents necessary for the construction and operation of the SL- PFB at the TWPC, Oak Ridge, TN. The permits and other regulatory documents identified are necessary to comply with the environmental laws and regulations of DOE Orders, and other requirements documented in the SL-PFB, Safety Design Strategy (SDS), SL-A-AD-002, R0 draft, and the Systems, Function and Requirements Document (SFRD), SL-X-AD-002, R1 draft. This compliance strategy is considered a 'living strategy' and it is anticipated that it will be revised as design progresses and more detail is known. The design basis on which this environmental permitting and compliance strategy is based is the Wastren Advantage, Inc., (WAI), TWPC, SL-PFB (WAI-BL-B.01.06) baseline. (authors)

  17. Materials Data on Np(SiRh)2 (SG:139) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  18. Materials Data on Mg(P2Rh3)2 (SG:187) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  19. Materials Data on Ca5P12Rh19 (SG:189) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  20. Surface Science Letters P) reactions with small alkenes adsorbed on Rh, Au, and ice

    E-Print Network [OSTI]

    Sibener, Steven

    of the excess energy. For low gas pressures, the products of vapor phase reactions are associated or diluted in propane, or as a solution with liquid nitrogen using sev- eral Torr of ambient oxygen atoms [7

  1. Materials Data on Li4H4Rh (SG:87) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  2. S.L. AVES and R.H. JOHNSONDecember 2008 919 1. Introduction

    E-Print Network [OSTI]

    Johnson, Richard H.

    generates significant diurnal variations in vertical motion, diabatic heating, and circulation patterns of the Meteorological Society of Japan, Vol. 86, No. 6, pp. 919-934, 2008 The, suggesting gravity wave dynamics, possibly associated with discrete propagation, as a factor in the system

  3. Materials Data on Ni(RhSe2)2 (SG:12) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  4. Materials Data on Sr2In3Rh2 (SG:12) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  5. Materials Data on Ba(RhPb2)3 (SG:63) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2015-03-09

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  6. Materials Data on CuSnRh2 (SG:225) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  7. Materials Data on La3Sn13Rh4 (SG:223) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  8. Atomic and molecular adsorption on RhMn alloy surface: A first principles study

    E-Print Network [OSTI]

    Li, Weixue

    of Physics. DOI: 10.1063/1.3046691 I. INTRODUCTION Catalytic conversion of syngas carbon monoxide and hydrogen from reforming of natural gas and coal to hydro- carbon Fishcher-Tropsch synthesis and oxygenates-containing compounds, such as acetic acid, ethanol, and acetaldehyde.1,2 Moreover, it is found that the catalytic

  9. Materials Data on Sr2H5Rh (SG:107) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  10. Materials Data on Rh2O3 (SG:60) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  11. Materials Data on LiRhO2 (SG:166) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  12. Materials Data on LiGeRh2 (SG:225) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  13. Materials Data on PuRh3 (SG:221) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  14. Materials Data on H12RhC8NO6 (SG:62) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  15. Materials Data on ZrSnRh (SG:190) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    2015-01-27

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  16. Materials Data on Y6Te2Rh (SG:62) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  17. Materials Data on HfRh3 (SG:221) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  18. plant systems Hossner, L.R.; Loeppert, R.H.; Newton, R.J. [Texas...

    Office of Scientific and Technical Information (OSTI)

    combines the disciplines of plant physiology, soil chemistry, and soil microbiology. Metal hyperaccumulator plants are attracting increasing attention because of their potential...

  19. Phantom Energy and the Cosmic Horizon: Rh is still not a horizon!

    E-Print Network [OSTI]

    Geraint F. Lewis

    2013-01-02

    There has been a recent spate of papers on the Cosmic Horizon, an apparently fundamental, although unrecognised, property of the universe. The misunderstanding of this horizon, it is claimed, demonstrates that our determination of the cosmological makeup of the universe is incorrect, although several papers have pointed out key flaws in these arguments. Here, we identify additional flaws in the most recent claims of the properties of the Cosmic Horizon in the presence of phantom energy, simply demonstrating that it does not act as a horizon, and that its limiting of our view of the universe is a trivial statement.

  20. Materials Data on GdRh (SG:221) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  1. Materials Data on H12RhC8NO6 (SG:62) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  2. Materials Data on ZrSnRh (SG:190) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  3. Rapid generation of molecular complexity under Pd(II) and Rh(III) catalysis 

    E-Print Network [OSTI]

    Kujawa, Szymon

    2015-11-26

    1. Enantioselective Pd(II)-Catalysed Nucleophilic Additions of 2- Alkylazaarenes The first project deals with enantio- and diastereoselective palladium(II)-catalysed nucleophilic additions of 2-alkylazaarenes to N-Boc ...

  4. Carbon-Heteroatom Reductive Elimination and Catalysis Utilizing (POCOP)Rh and (POCOP)Co Complexes 

    E-Print Network [OSTI]

    Timpa, Samuel D

    2014-07-29

    great that the work of Heck, Negishi, and Suzuki was acknowledged with the 2010 Nobel Prize in chemistry “for palladium-catalyzed cross-coupling in organic synthesis.”6 Many of these reactions are now used in the industrial production of a number...

  5. ?ot8rh QI ahnloal Corporation In Hart IUnover, Ma86rohusett8,

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and Myers Co -VANaval Ordnance,:n5.5.8GE 1 ;"

  6. Chemical and Morphological Evolution of Nanoporous Pd/Rh Alloy Particles

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing Bacteria (TechnicalTransmission,TextitSciTechin Complex Interfacial

  7. Quantitative EDS Analysis of Nanometer-Scale Core/Shell Pd/Rh Structures.

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTech ConnectSpeedingConnect Pulse energy measurement athemorrhagic

  8. Kinetic and Performance Studies of the Regeneration Phase of Model Pt/Rh/Ba

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICE INDUSTRIALU.S. DepartmentJeanKey Meeting Takeaways

  9. Electronic structure of Cu1xNixRh2S4 and CuRh2Se4: Band-structure calculations, x-ray photoemission, and fluorescence measurements

    E-Print Network [OSTI]

    Hart, Gus

    of Sciences­Ural Division, 620219 Yekaterinburg GSP-170, Russia D. Hartmann and M. Neumann Department

  10. THE DUTCH OPEN TELESCOPE R.J. RUTTEN, R.H. HAMMERSCHLAG AND F.M. BETTONVIL

    E-Print Network [OSTI]

    Rutten, Rob

    Islands were selected as the premier European site for optical solar ob- servation. Originally envisaged. The hour angle and declination drives are considerably overdimensioned to avoid local heat dissipation

  11. Fabrication Control Plan for ORNL RH-LOCA ATF Test Specimens to be Irradiated in the ATR

    SciTech Connect (OSTI)

    Kevin G. Field; Richard Howard; Michael Teague

    2014-06-01

    The purpose of this fabrication plan is (1) to summarize the design of a set of rodlets that will be fabricated and then irradiated in the Advanced Test Reactor (ATR) and (2) provide requirements for fabrication and acceptance criteria for inspections of the Light Water Reactor (LWR) – Accident Tolerant Fuels (ATF) rodlet components. The functional and operational (F&OR) requirements for the ATF program are identified in the ATF Test Plan. The scope of this document only covers fabrication and inspections of rodlet components detailed in drawings 604496 and 604497. It does not cover the assembly of these items to form a completed test irradiation assembly or the inspection of the final assembly, which will be included in a separate INL final test assembly specification/inspection document. The controls support the requirements that the test irradiations must be performed safely and that subsequent examinations must provide valid results.

  12. ETME 422 -REFRIGERATION & HVAC SYSTEMS FALL 2011 LEC -10:00 -10:50am M W F RH 312

    E-Print Network [OSTI]

    Dyer, Bill

    , fans, compressors, heat exchangers, heaters, refrigerators, etc.) of heating, ventilation, air Load - Introduction HVAC Systems Comfort and Health Solar Radiation Radiant Time Series Method Moist

  13. Role of metal-support interactions on the activity of Pt and Rh catalysts for reforming methane and butane.

    SciTech Connect (OSTI)

    Rossignol, C.; Krause, T.; Krumpelt, M.

    2002-01-11

    For residential fuel cell systems, reforming of natural gas is one option being considered for providing the H{sub 2} necessary for the fuel cell to operate. Industrially, natural gas is reformed using Ni-based catalysts supported on an alumina substrate, which has been modified to inhibit coke formation. At Argonne National Laboratory, we have developed a new family of catalysts derived from solid oxide fuel cell technology for reforming hydrocarbon fuels to generate H{sub 2}. These catalysts consist of a transition metal supported on an oxide-ion-conducting substrate, such as ceria, that has been doped with a small amount of a non-reducible element, such as gadolinium, samarium, or zirconium. Unlike alumina, the oxide-ion-conducting substrate has been shown to induce strong metal-support interactions. Metal-support interactions are known to play an important role in influencing the catalytic activity of many metals supported on oxide supports. Based on results from temperature-programmed reduction/oxidation and kinetic reaction studies, this paper discusses the role of the metal and the substrate in the metal-support interactions, and how these interactions influence the activity and the selectivity of the catalyst in reforming methane and butane to hydrogen for use in fuel cell power systems.

  14. Colloidally Synthesized Monodisperse Rh Nanoparticles Supported on SBA-15 for Size- and Pretreatment-Dependent Studies of CO Oxidation

    E-Print Network [OSTI]

    Grass, Michael E.

    2010-01-01

    1 . 2.3 CO Oxidation measurements Catalytic measurementsand catalytic properties for CO oxidation of a series of PVP3: Summary of catalytic results for CO oxidation Apparent E

  15. Indirect hydrogen versus helium or nitrogen cooling for fusion cryogenic and magnet systems Clarke R.H1

    E-Print Network [OSTI]

    Glowacki, Bartek A.

    347 Indirect hydrogen versus helium or nitrogen cooling for fusion cryogenic and magnet systems in fusion cryogenic and magnet systems may be possible through the use of 15-20 K cooling. This approach there is no substitute. By using an intermediate, leak-tight, pressurised helium loop the benefits of 15-20 K cooling can

  16. Hybrid density functional calculations of the defect properties of ZnO:Rh and ZnO:Ir

    E-Print Network [OSTI]

    Muñoz Ramo, David; Bristowe, Paul D.

    2014-03-31

    gap region and near the conduction band minimum, with a d-d splitting larger than 2 eV, which helps maintain transparency in the material. Addition of a hole to the simulation cell of both spinels and doped ZnO leads to charge localization...

  17. Materials Data on H22RhC3(N3O4)2 (SG:58) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  18. Density functional theory study of CHx ,,x=13... adsorption on clean and CO precovered Rh,,111... surfaces

    E-Print Network [OSTI]

    Li, Weixue

    ... surfaces Ming-Mei Yang State Key Laboratory Of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China and Graduate School of the Chinese Academy of Sciences, Beijing 100039, China Xin-He Bao State Key Laboratory Of Catalysis, Dalian Institute of Chemical

  19. Mesoporous Silica-Supported Metal Oxide-Promoted Rh Nanocatalyst for Selective Production of Ethanol from Syngas

    SciTech Connect (OSTI)

    George Kraus

    2010-09-30

    The objective is to develop a process that will convert synthesis gas from coal into ethanol and then transform the ethanol into hydrogen. Principal investigators from Iowa State University include Dr. George Kraus, Dr. Victor Lin, Marek Pruski, and Dr. Robert Brown. Task 1 involves catalyst development and catalyst scale up. Mesoporous manganese silicate mixed oxide materials will be synthesized, characterized and evaluated. The first-and secondgeneration catalysts have been prepared and scaled up for use in Task 2. The construction of a high-pressure reactor system for producing synthetic liquid fuel from simulated synthesis gas stream has been completed as the first step in Task 2. Using the first- and second generation catalysts, the reactor has demonstrated the production of synthetic liquid fuel from a simulated synthesis gas stream.

  20. Kinetic and Performance Studies of the Regeneration Phase of Model Pt/Rh/Ba NOx Traps for Design and Optimization

    Broader source: Energy.gov [DOE]

    Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review 2008 on February 25, 2008 in Bethesda, Maryland.

  1. Catalytic conversion of syngas into C2 oxygenates over Rh-based catalysts--Effect of carbon supports

    E-Print Network [OSTI]

    Bao, Xinhe

    . Introduction Ethanol attracts increasing attention as a clean fuel or an additive to gasoline [1 from natural gas, coal and biomass [3]. This process was first patented by Union Carbide Corporation T Ethanol is considered as a potential alternative synthetic fuel to be used in automobiles

  2. Failure of Functionally Graded Materials G.H. PAULINO,Z.-H. JIN, and R.H. DODDS,Jr.

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    .13.5.1 Metal/Ceramic FGM Fracture Specimen 638 2.13.5.2 Precracking of Metal/Ceramic FGMs 639 2 of reinforcement and matrix (base) materials in a continuous manner as illustrated by Figure 1. This new concept by providing a compositional distribution function, C(x), consistent with these condi- tions. For instance

  3. Simplifying strong electronic correlations in uranium: Localized uranium heavy-fermion UM2Zn20 (M=Co,Rh) compounds

    E-Print Network [OSTI]

    Lawrence, Jon

    Simplifying strong electronic correlations in uranium: Localized uranium heavy-fermion UM2Zn20 (M Atómica, 8400 Bariloche, Argentina 6 Department of Chemistry and Biochemistry, University of Delaware-field effects corroborate an ionic-like uranium electronic configura- tion in UM2Zn20. DOI: 10.1103/PhysRevB.78

  4. Materials Data on H22RhC3(N3O4)2 (SG:58) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  5. RH-LLW Disposal Facility Project CD-2/3 to Design/Build Proposal Reconciliation Report

    SciTech Connect (OSTI)

    Annette L. Schafer

    2012-06-01

    A reconciliation plan was developed and implemented to address potential gaps and responses to gaps between the design/build vendor proposals and the Critical Decision-2/3 approval request package for the Remote-Handled Low Level Waste Disposal Facility Project. The plan and results of the plan implementation included development of a reconciliation team comprised of subject matter experts from Battelle Energy Alliance and the Department of Energy Idaho Operations Office, identification of reconciliation questions, reconciliation by the team, identification of unresolved/remaining issues, and identification of follow-up actions and subsequent approvals of responses. The plan addressed the potential for gaps to exist in the following areas: • Department of Energy Order 435.1, “Radioactive Waste Management,” requirements, including the performance assessment, composite analysis, monitoring plan, performance assessment/composite analysis maintenance plan, and closure plan • Environmental assessment supporting the National Environmental Policy Act • Nuclear safety • Safeguards and security • Emplacement operations • Requirements for commissioning • General project implementation. The reconciliation plan and results of the plan implementation are provided in a business-sensitive project file. This report provides the reconciliation plan and non-business sensitive summary responses to identified gaps.

  6. Microsoft Word - 06-1532dsm ltr to Zappe INL-CCP RH A-07-16 Report.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on darkMicroorganismsnowReportJ.NextWater VaporASME/AIAA Wind1,

  7. Summary of EXAFS results on Cd-doped PuRhIn5 (Technical Report) | SciTech

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail. (Conference)Feedback System inStatus ofSmall GTPasesmirroranΦ¹²Special

  8. Summary of EXAFS results on Cd-doped PuRhIn5 (Technical Report) | SciTech

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail. (Conference)Feedback System inStatus ofSmall GTPasesmirroranΦ¹²SpecialConnect

  9. Advanced Machine Learning MEHRYAR MOHRI MOHRI@

    E-Print Network [OSTI]

    Mohri, Mehryar

    hope to bound; for ERM, bounded by two times gen. bound: 3 h H R(h) R = [R(h) R(h )] estimation + [R(h ) R ] approximation . H best in class R(hERM) R(h ) = R(hERM) R(hERM) + R(hERM) R(h ) R(hERM) R(hERM

  10. Synthesis and characterization of the hexagonal prismatic cage {THF7[PhB(CN)3]6[Cp*Rh]6}6+

    E-Print Network [OSTI]

    Rauchfuss, Thomas B.

    tectons or building blocks that have geometrically well-defined bridging tendencies.6­8 Through systematic the reaction of PhBCl2 and three equiv. of [K- 18-crown-6]CN in THF solution. This air stable, colorless salt

  11. Probing the localization length of photo-generated charges in organic materials. A.D. Chepelianskii, J. Wang and R.H. Friend

    E-Print Network [OSTI]

    Shepelyansky, Dima

    of these materials is crucial to the improvement of their power conversion efficien- cies. Research in this direction

  12. The U. S. Department of Energy (DOE) has submitted a planned change request to use shielded containers for emplacement of selected remote-handled (RH) transuranic

    E-Print Network [OSTI]

    1 Summary The U. S. Department of Energy (DOE) has submitted a planned change request to use specifications and the U.S. Nuclear Regulatory Commission (NRC) Type B specifications for shipping in the Half capabilities under normal or accident conditions. These results ensure that the shielded container is safe

  13. A Reactive Oxide Overlayer on Rh Nanoparticles during CO Oxidation and Its Size Dependence Studied by in Situ Ambient Pressure XPS

    E-Print Network [OSTI]

    Grass, Michael E.

    2010-01-01

    then the thickness of the oxide layer formed can be roughlyof the surface oxide layer and affect the interaction of COillustrated here with the oxide layers shown to scale, as

  14. Selectivity of chemisorbed oxygen in CH bond activation and CO oxidation and kinetic consequences for CH4O2 catalysis on Pt and Rh clusters

    E-Print Network [OSTI]

    Iglesia, Enrique

    Available online 12 August 2011 Keywords: CH4 Catalytic partial oxidation Methane combustion Platinum, thus confirming that direct catalytic partial oxidation of CH4 to CO (and H2) does not occur the sequential reforming steps. Ó 2011 Elsevier Inc. All rights reser

  15. Oxidation of Methanol on 2nd and 3rd Row Group VIII Transition Metals (Pt, Ir, Os, Pd, Rh, and Ru): Application to Direct Methanol

    E-Print Network [OSTI]

    Goddard III, William A.

    this problem; however, extracting molecular hydrogen from a liquid fuel requires a reformer. This greatly parameters for com- mercial use are now achievable with modern catalytic formula- tions and cell designs.1 by a proton- exchange membrane such as Nafion. Platinum-based electrodes demonstrate the highest catalytic

  16. First Principle Study of Ethanol Adsorption and Formation of Hydrogen Bond on Rh(111) Ming-Mei Yang,, Xin-He Bao,*, and Wei-Xue Li*,,

    E-Print Network [OSTI]

    Li, Weixue

    -Mei Yang,, Xin-He Bao,*, and Wei-Xue Li*,,§ State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China, Center for Theoretical and Computational Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China

  17. Kinetic and Thermodynamic Selectivity of Intermolecular C-H Activation at [TpRh(PMe3)]. How Does the Ancillary Ligand Affect

    E-Print Network [OSTI]

    Jones, William D.

    the Ancillary Ligand Affect the Metal-Carbon Bond Strength? Yunzhe Jiao, James Morris, William W. Brennessel

  18. Endogenous Cortisol, Luteinizing Hormone, and Testosterone Secretion and GnRH-induced Luteinizing Hormone and Testosterone Secretion in Prenatally Stressed Sexually Mature Brahman Bulls 

    E-Print Network [OSTI]

    Littlejohn, Brittni Paige

    2014-12-12

    reported to be harder to manage, have compromised immune function, reduced growth rate, and inferior carcass characteristics (Voisinet et al., 1997; Fell, 1999; King et al., 2006; Cafe et al., 2010). Specifically, temperamental cattle have been reported...

  19. Dilepton events with displaced vertices, double beta decay, and resonant leptogenesis with Type-II seesaw dominance, TeV scale $Z'$ and RH neutrinos

    E-Print Network [OSTI]

    Nayak, Bidyut Prava

    2015-01-01

    In a class of Type-II seesaw dominated $SO(10)$ models proposed recently with heavy neutrinos, extra $Z'$ boson, and resonant leptogenesis, at first we show that the lightest first generation sterile neutrino that mediates dominant contributions to neutrinoless double beta decay also generates the displaced vertex leading to verifiable like-sign di-electron as well as di-muon production events outside the LHC detectors having suppressed standard model back-ground and missing energy. Resonant leptogenesis in this case is implemented by a pair of quasi-degenerate sterile neutrinos of the second and the third generations having masses of ${\\cal O}(500)$ GeV. Then we predict a new alternative scenario where the models allow the second generation sterile neutrino mass to be ${\\cal O}(10)$ GeV capable of mediating the dominant double beta decay as well as the displaced vertices for significantly improved number of like-sign dilepton events in different channels. Resonant leptogenesis in this alternative scenario is...

  20. Rhamm-/- mice are defective in skin wound repair due to aberrant ERK1,2 signaling in fibroblast migration

    E-Print Network [OSTI]

    2006-01-01

    gel (Fig. 5B). Migration of primary Rh-/- dermal fibroblastsRhamm Reduces Migration and Invasion of Wt and Rh-/- PrimaryRhamm Reduces Migration and Invasion of Wt and Rh-/- Primary

  1. Simulating Nonuniform Properties in Polymer-Electrolyte Fuel Cells

    E-Print Network [OSTI]

    Weber, A.Z.; Newman, J.

    2006-01-01

    2-D approach, both coflow and crossflow Membrane thickness (deviation (%) Sat Low RH Crossflow (low RH) Sat Low RH Dist.feed case using a crossflow instead of coflow configuration.

  2. JOURNAL DE PHYSIQUE IV Colloque C5, supplkment au Journal de Physique 11, Volume 5,juin 1995

    E-Print Network [OSTI]

    Boyer, Edmond

    ~ ] ~ [Rh(C0)2F312 Rh(CO)z(aa) Rh(CO)2~n(s) compounds (COD)Rh(hfa) (dicn)Rh(aa) (dien)Rh(Cp) complexes ( C R on synthesis, thermal properties and saturated vapour pressure of volatile compounds of noble metals derivatives due to their thermal properties are thc most suitable ior deposition of noble metal thick films. 1

  3. CERTS Microgrid Laboratory Test Bed - PIER Final Project Report

    E-Print Network [OSTI]

    Eto, Joseph H.

    2008-01-01

    3 pages. Lasseter, R.H. 2007. “Microgrids and Distributed3 pages. Lasseter, R.H. 2007. “Microgrids and Distributed2006. Autonomous Control of Microgrids. IEEE PES Meeting,

  4. Pheromonal bile acid 3-ketopetromyzonol sulfate primes the neuroendocrine system in sea lamprey

    E-Print Network [OSTI]

    2013-01-01

    neurons in the hypothalamus. lGnRH-I -immunoreactiveneurons in the hypothalamus. lGnRH-III -immunoreactivehormone in the anterior hypothalamus of female rats during

  5. Molecular Analysis of Replication and Packaging Mechanism of Satellite Tobacco Mosaic Virus

    E-Print Network [OSTI]

    Sivanandam, Venkatesh

    2013-01-01

    RH, Symons RH. Cucumber mosaic virus contains a functionallycowpea chlorotic mottle viruses exhibit neutral effects inof satellite tobacco mosaic virus and its helper virus in

  6. Formations pluridisciplinaires Sant au travail

    E-Print Network [OSTI]

    Mesbah, Mounir

    . Personnels animant des équipes. Médecin du Travail Infirmier(e) du Travail Responsable RH Responsable

  7. Intern experience at Gulf States Utility Company: an internship report 

    E-Print Network [OSTI]

    Laub, Thomas William, 1958-

    2013-03-13

    -chairman Student?s Advisory Committee Dr. D.A. Dubofsky, F; Committee Member / 2 L(/ J.E.Mr/J.E Booker, GSU Internship Supervisor Dr\\ L.s. Fletcher, Asso. Dean College of Engineering ABSTRACT Internship Experience at Gulf States Utilities Company (May 1985... cd ?H rH ?H ? ? CQ 0 ? ? cd -P ? 3 Q Q 0 ?H h0 0 T3 -P Q w P I ? ? O ? ? cd S ? 0 O M S -P -p ?P 0 > 0 0 0 ?p rH ?H TJ TJ T3 rH rH rH T3 M 0 ?P cd cd cd rH i?1 rH 0 S3 O rH rH rH 0 0 0 - 0...

  8. Structural/magnetic phase transitions and superconductivity in Ba(Fe1-xTMx)2As2 (TM=Co, Ni, Cu, Co/Cu, Rh and Pd) single crystals

    SciTech Connect (OSTI)

    Ni, Ni

    2009-08-15

    Since its discovery in 1911, superconductivity has been one of the most actively studied fields in condensed matter physics and has attracted immense experimental and theoretical effort. At this point in time, with more and more superconductors discovered in elements, alloys, intermetallic compounds and oxides, it is becoming clear that superconductivity is actually not so rare in nature. Almost half of the elements in the periodic table and hundreds of compounds have been found to be superconducting. Fig. 1.1 shows the milestones in discovering higher T{sub c} superconductors. Among the elemental superconductors, Niobium has the highest superconducting transition temperature, T{sub c}, of 9.5 K. This record held for more than ten years, until the discovery of niobium nitride which superconducts below 16 K. It took another thirty years for T{sub c} to increase from 16 K in niobium nitride to 23 K in niobium germanium.

  9. 3/3/2014 Big ideas for tinywindmills at UTA | Arlington | News from Fort Worth, Dallas, Arlingto... http://www.star-telegram.com/2014/03/02/5614443/tiny-windmills-could-save-bridges.html?rh=1 1/2

    E-Print Network [OSTI]

    Chiao, Jung-Chih

    mnagy@star-telegram.com ARLINGTON -- Millions of tiny windmills could one day power wireless sensors where they could be useful. Because companies already craft all types of charging devices for cellphones, such as powering wireless sensors located in places where making repairs might be problematic. An example would

  10. R.H. Williams, Decarbonized fossil energy carriers and their energy technological competitors, prepared for the IPCC Workshop on Carbon Capture and Storage, Regina, Saskatchewan, Canada, 18-21 November 2002 (1/22/03).

    E-Print Network [OSTI]

    = higher heating value NGCC = natural gas combined cycle CAES = compressed air energy storage ICE option for reducing emissions from the power sector, but there are alternative non from water using carbon-free (renewable or nuclear) electricity or heat sources. Although CO2 capture

  11. Investigation of CaIr1-xPtxO3 and CaIr0.5Rh0.5O3 : structural properties, physical properties and stabilising conditions for post-perovskite oxides 

    E-Print Network [OSTI]

    Hirai, Shigeto

    2011-06-28

    Our understanding of the nature of Earth’s D” region was changed significantly by a recent finding by Murakami et al. (2004), who revealed a phase transition from perovskite to post-perovskite structure in MgSiO3 at about 125 GPa and 2500 K...

  12. Heat transport in the North Atlantic Ocean 

    E-Print Network [OSTI]

    Jung, Glenn Harold

    1955-01-01

    l l gHfQO 3 S g ** cl 0bO 0 ft o IBCO CQ o co 0 0> iH rH 5 *?> rH i?I 2J cn> o cd co O OS 3 rH 0 o rH f f f J CO *? CO 00 rH P ?H O 0 I 3 o go co 3 h o CD -P 03 ?rH ? ?v O H * 0 *o > J5? C0? to d d 0 ? 00 1 oo to ?*H CQ -P QJ CO ? - CO H 00 ? ?H...

  13. Southern California Channel Islands Bibliography, through 1992

    E-Print Network [OSTI]

    Channel Islands National Marine Sanctuary

    1992-01-01

    RH. Habitat preferences of feral hogs, deer, and cattle on a446. Barrett RH. The feral Hog on the Dye Creek Ranch,hogs on private lands. 8 pp; unpublished manuscript. SCIR feral

  14. Rhamm-/- mice are defective in skin wound repair due to aberrant ERK1,2 signaling in fibroblast migration

    E-Print Network [OSTI]

    Tolg, Cornelia; Hamilton, Sara R.; Kooshesh, Pari; McCarthy, James B.; Bissell, Mina J.; Turley, Eva A.

    2006-01-01

    gel (Fig. 5B). Migration of primary Rh-/- dermal fibroblastsRhamm reduces migration and invasion of primary fibroblasts.showing the migration and invasion of primary Wt and Rh-/-

  15. Formula Page

    E-Print Network [OSTI]

    1910-91-13

    MA 22300 FORMULA SHEET. Volume & Surface Area. Right Circular Cylinder. V = ?r2h. SA = {. 2?r2 + 2?rh ?r2 + 2?rh. Sphere. V = 4. 3 ?r3. SA = 4?r2.

  16. The Interactive Effects of Multifactor Global Change Were Evaluated for a Range of Ecosystems

    E-Print Network [OSTI]

    ) on net primary production (NPP), heterotrophic respiration (Rh), net ecosystem production (NEP) transpiration and runoff We examined those responses in sevenecosystem production (NEP), transpiration ecosystems. However, two-way interactive effects on NPP, Rh, and NEP were generally positive (i

  17. i=2 - Purdue University

    E-Print Network [OSTI]

    (12). As a manifold, G = N R + . We shall denote the R+ coordinate by 'y' and the ..... We de ne subgroups ~K and A of S by exponentiating RH0 and RH2 ...

  18. Assoc. Director for Programs

    E-Print Network [OSTI]

    . Director for RH Operations Building Managers Operations and Events Coor. (2) Event Services Coordinator Assistant Director for RH Operations Information Center Attendants Game Room Attendants Fiscal Assistant for Facilities Athletic Training Director Business Manager Maintenance Supervisor Maintenance Workers Assist. Dir

  19. Sandia National Laboratories: News: Publications: Lab News

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    greater than uranium (transuranic). RH-TRU waste produces a higher dose rate than CH-TRU waste at the surface of the disposal container, but when transported RH- and CH-TRU waste...

  20. Kinetic and Performance Studies of the Regeneration Phase of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Studies of the Regeneration Phase of Model PtRhBa NOx Traps for Design and Optimization Kinetic and Performance Studies of the Regeneration Phase of Model PtRhBa NOx...

  1. Goserelin for ovarian protection during breast-cancer adjuvant chemotherapy

    E-Print Network [OSTI]

    2015-01-01

    GnRH) agonist with adju- vant chemotherapy for the purposeovarian failure after adju- vant or neoadjuvant treatment of

  2. Scale dependence in multitemporal mapping of forest fragmentation in Bolivia: implications for explaining temporal

    E-Print Network [OSTI]

    , Leicester, UK, LE1 7RH b Centro de Biodiversidad y Genetica, Universidad Mayor San Simon, Cochabamba

  3. The role of the rhesus macaque (macaca mulatta) apolipoprotein B mRNA-editing enzyme catalytic polypeptide-like 3 (APOBEC3) in lentiviral replication and persistence

    E-Print Network [OSTI]

    Schmitt, Kimberly Patricia

    2012-05-31

    SHIV?vif similar to rhA3G, rhA3A produced an approximately 5-fold decrease in the number of G-to-A mutations compared to rhA3G. Unlike hA3A, rhA3A did not inhibit adeno-associated virus 2 (AAV-2) replication and L1 retrotransposition. This data suggests...

  4. High-throughput metal nanoparticle catalysis by pulsed laser ablation Selim Senkan a,*, Michael Kahn a

    E-Print Network [OSTI]

    Senkan, Selim M.

    -PLA were also screened for their catalytic activities and selectivities for the partial oxidation for catalytic applications. Catalytic materials containing Rh, bimetallic Rh/Pt and trimetallic Rh of propylene. In less than a day, over 40 different catalytic materials of nanoparticles supported on g-Al2O3

  5. Developing models of aerosol representation to investigate composition, evolution, optical properties, and CCN spectra using measurements of size-resolved hygroscopicity 

    E-Print Network [OSTI]

    Gasparini, Roberto

    2006-08-16

    , size and hygroscopicity information were combined to model the aerosol as a population of multi-component particles. With this model, the aerosol hygroscopic growth factor f(RH), relating the submicron scattering at high RH to that at low RH...

  6. Comparative Study on the Sulfur Tolerance and Carbon Resistance of Supported Noble Metal Catalysts in Steam Reforming of Liquid Hydrocarbon Fuel

    SciTech Connect (OSTI)

    Xie, Chao; Chen, Yongsheng; Engelhard, Mark H.; Song, Chunshan

    2012-04-18

    This work was conducted to clarify the influence of the type of metal and support on the sulfur tolerance and carbon resistance of supported noble metal catalysts in steam reforming of liquid hydrocarbons. Al2O3-supported noble metal catalysts (Rh, Ru, Pt, and Pd), Rh catalysts on different supports (Al2O3, CeO2, SiO2, and MgO), and Pt catalyst supported on CeO2 and Al2O3, were examined for steam reforming of a liquid hydrocarbon fuel (Norpar13 from Exxon Mobil) at 800 C for 55 h. The results indicate that (1) Rh/Al2O3 shows higher sulfur tolerance than the Ru, Pt, and Pd catalysts on the same support; (2) both Al2O3 and CeO2 are promising supports for Rh catalyst to process sulfur-containing hydrocarbons; and (3) Pt/CeO2 exhibits better catalytic performance than Pt/Al2O3 in the reaction with sulfur. TEM results demonstrate that the metal particles in Rh/Al2O3 were better dispersed (mostly in 1-3 nm) compared with the other catalysts after reforming the sulfur-containing feed. As revealed by XPS, the binding energy of Rh 3d for Rh/Al2O3 is notably higher than that for Rh/CeO2, implying the formation of electron-deficient Rh particles in the former. The strong sulfur tolerance of Rh/Al2O3 may be related to the formation of well-dispersed electron-deficient Rh particles on the Al2O3 support. Sulfur K-edge XANES illustrates the preferential formation of sulfonate and sulfate on Rh/Al2O3, which is believed to be beneficial for improving its sulfur tolerance as their oxygen-shielded sulfur structure may hinder direct Rh-S interaction. Due to its strong sulfur tolerance, the carbon deposition on Rh/Al2O3 was significantly lower than that on the Al2O3-supported Ru, Pt, and Pd catalysts after the reaction with sulfur. The superior catalytic performance of CeO2-supported Rh and Pt catalysts in the presence of sulfur can be ascribed mainly to the promotion effect of CeO2 on carbon gasification, leading to much lower carbon deposition compared with the Rh/Al2O3, Rh/MgO, Rh/SiO2 and Pt/Al2O3 catalysts.

  7. The adsorption of water on Cu2O and Al2O3 thin films

    SciTech Connect (OSTI)

    Deng, Xingyi; Herranz, Tirma; Weis, Christoph; Bluhm, Hendrik; Salmeron, Miquel

    2008-06-27

    The initial stages of water condensation, approximately 6 molecular layers, on two oxide surfaces, Cu{sub 2}O and Al{sub 2}O{sub 3}, have been investigated by using ambient pressure X-ray photoelectron spectroscopy at relative humidity values (RH) from 0 to >90%. Water adsorbs first dissociatively on oxygen vacancies producing adsorbed hydroxyl groups in a stoichiometric reaction: O{sub lattic} + vacancies + H{sub 2}O = 2OH. The reaction is completed at {approx}1% RH and is followed by adsorption of molecular water. The thickness of the water film grows with increasing RH. The first monolayer is completed at {approx}15% RH on both oxides and is followed by a second layer at 35-40% RH. At 90% RH, about 6 layers of H{sub 2}O film have been formed on Al{sub 2}O{sub 3}.

  8. Effects of PV Module Soiling on Glass Surface Resistance and Potential-Induced Degradation: Preprint

    SciTech Connect (OSTI)

    Hacke, Peter; Burton, Patrick; Hendrickson, Alex; Spartaru, Sergiu; Glick, Stephen; Terwilliger, Kent

    2015-12-03

    The sheet resistance of three soil types (Arizona road dust, soot, and sea salt) on glass were measured by the transmission line method as a function of relative humidity (RH) between 39% and 95% at 60 degrees C. Sea salt yielded a 3.5 order of magnitude decrease in resistance on the glass surface when the RH was increased over this RH range. Arizona road dust showed reduced sheet resistance at lower RH, but with less humidity sensitivity over the range tested. The soot sample did not show significant resistivity change compared to the unsoiled control. Photovoltaic modules with sea salt on their faces were step-stressed between 25% and 95% RH at 60 degrees C applying -1000 V bias to the active cell circuit. Leakage current from the cell circuit to ground ranged between two and ten times higher than that of the unsoiled controls. Degradation rate of modules with salt on the surface increased with increasing RH and time.

  9. Role of Si/Al Ratio on Immobilization and Stability of Rhodium Complexes on ZSM-5

    E-Print Network [OSTI]

    Long, Brandon

    2009-01-01

    Rhodium complexes within the pores of zeolite ZSM-5 with varying Si/Al ratios (Si/Al 23, Si/Al 50, and Si/Al 280) were prepared from Rh1+(CO)2(C5H7O2), Rh22+(CO2CH3)4, and Rh3+(C5H7O2)3 followed by thermal treatment in He. IR results indicate...

  10. Hydrogen Gas Generation Model for Fuel-Based Remote-Handled Transuranic Waste Stored at the INEEL

    SciTech Connect (OSTI)

    Khericha, S.; Bhatt, R.; Liekhus, K.

    2003-01-14

    The Idaho National Environmental and Engineering Laboratory (INEEL) initiated efforts to calculate the hydrogen gas generation in remote-handled transuranic (RH-TRU) containers in order to evaluate continued storage of unvented RH-TRU containers in vaults and to identify any potential problems during retrieval and aboveground storage. A computer code is developed to calculate the hydrogen concentration in the stored RH-TRU waste drums for known configuration, waste matrix, and radionuclide inventories as a function of time.

  11. Hydrogen Gas Generation Model for Fuel Based Remote Handled TRU Waste Stored at INEEL

    SciTech Connect (OSTI)

    Soli T. Khericha; Rajiv N. Bhatt; Kevin Liekhus

    2003-02-01

    The Idaho National Environmental and Engineering Laboratory (INEEL) initiated efforts to calculate the hydrogen gas generation in remote-handled transuranic (RH-TRU) containers in order to evaluate continued storage of unvented RH-TRU containers in vaults and to identify any potential problems during retrieval and aboveground storage. A computer code is developed to calculate the hydrogen concentration in the stored RH-TRU waste drums for known configuration, waste matrix, and radionuclide inventories as a function of time.

  12. Yeki bud, yeki nabud: Essays on the Archaeoogy of Iran in Honor of William M. Sumner

    E-Print Network [OSTI]

    2003-01-01

    Henry T. Wright and Elizabeth Caner RH—9 6.13 l.arg(*1'lliiqht and Elizabeth Caner covered l)y our air photographs

  13. Large linguistically-processed Web corpora for multiple languages Marco Baroni

    E-Print Network [OSTI]

    on a server running RH Fedora Core 3 with 4 GB RAM, Dual Xeon 4.3 GHz CPUs and about 2.5 TB hard disk space

  14. Sex differences in hypothalamic astrocyte response to estradiol stimulation

    E-Print Network [OSTI]

    Kuo, John; Hamid, Naheed; Bondar, Galyna; Dewing, Phoebe; Clarkson, Jenny; Micevych, Paul

    2010-01-01

    kisspeptin neurons in mouse hypothalamus; sexual dimorphismfunctions controlled by the hypothalamus are highly sexuallyGnRH release from the hypothalamus and gonadotropin release

  15. Transcriptional control of the gonadotropin-releasing hormone gene in development

    E-Print Network [OSTI]

    Miller, Nichol L. G.

    2008-01-01

    dispersed throughout the hypothalamus. Research in the fieldGnRH) neurons of the hypothalamus are the primary regulatorsof neurons within the hypothalamus. These studies elucidate

  16. Hormonal interactions in progesterone regulation of gonadotropin gene expression

    E-Print Network [OSTI]

    Ghochani, Yasmin

    2009-01-01

    axis, consisting of the hypothalamus, anterior pituitary,specific neurons in the hypothalamus into the hypophysealanterior pituitary and hypothalamus further regulate GnRH,

  17. The Role of the Circadian System in Reproductive, Neural, and Immune Health

    E-Print Network [OSTI]

    Gibson, Erin Marie

    2011-01-01

    of the GnRH neurons in the hypothalamus rather than at theto the dorsomedial hypothalamus (DMH) in hamsters, rats, andkisspeptin neurons in mouse hypothalamus; sexual dimorphism

  18. Contrasting controls on wildland fires in Southern California during periods with and without Santa Ana winds

    E-Print Network [OSTI]

    Jin, Yufang; Randerson, James T; Faivre, Nicolas; Capps, Scott; Hall, Alex; Goulden, Michael L

    2014-01-01

    humidity (RH) and strong offshore ?ow, can result inconditions, when strong offshore winds and low humidity leadare typically driven by strong offshore Santa Ana winds, and

  19. Reaction-Driven Restructuring of Bimetallic Nanoparticle Catalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Rh and Pd under alternating oxidizing and catalytic conditions. Measurements for each system began with as-prepared samples at room temperature in ultrahigh vacuum and...

  20. DOE/SC-ARM-14-010 ARM Data File Standards

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to aot) * precip precipitation * rh relative humidity * wspd wind speed * wdir wind direction. 7.4.2.3 Subcategory Qualifier * low lower * high higher * up ...

  1. Comparative genomics of metabolic capacities of regulons controlled by cis-regulatory RNA motifs in bacteria

    E-Print Network [OSTI]

    Sun, Eric I; Leyn, Semen A; Kazanov, Marat D; Saier, Milton H; Novichkov, Pavel S; Rodionov, Dmitry A

    2013-01-01

    RH, Breaker RR: Comparative genomics reveals 104 candidateof transporters. BMC Genomics 2008, 9:330. 16. Green NJ,in proteobacteria: comparative genomics analysis. FEMS

  2. My Publications

    E-Print Network [OSTI]

    •Kenney, R.H. (In Press). Investigating a Link Between Pre-Calculus Students' Uses of Graphing Calculators and Their Understanding of Mathematical Symbols

  3. Recovery Act Provides Big Boost with a Nanoscale Focus | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    House to Focus on Programmatic Successes Achieved Under ARRA Funding An operator uses robotic manipulators to process RH TRU. WASTE DISPOSITION PROJECT MAKES GREAT STRIDES AT THE...

  4. Structure Property Relationships for Dirhodium Antitumor Active Compounds: Reactions with Biomolecules and In Cellulo Studies 

    E-Print Network [OSTI]

    Aguirre-Flores, Jessica Dafhne

    2011-02-22

    synthesized and characterized. In cis-[Rh2(?-OAc)2(np)2]2+ (np = 1,8- naphthyridine) both axial sites are available for coordination, whereas for cis-[Rh2(?-OAc)2(np)(pynp)]+2 (pynp = 2-(2-pyridyl)1,8-naphthyridine) and cis-[Rh2(?-OAc)2(pynp)2]+2... lines, with [Rh2(?-O2CCH3)2(?1-O2CCH3)(dppz)]+ being the most effective compound of the series. Results of the comet assay indicate that all of the mono- substituted complexes studied damage nuclear DNA, although in different degrees. The cytotoxic...

  5. --No Title--

    National Nuclear Security Administration (NNSA)

    Keywords: vegetation*, nutritiondiet*, radiation* 489 NISHITA, H., R.H. MOORE, R.J. BECKMAN, and M. HAMILTON. 1975. Decay characteristics of soil thermoluminescence. Soil...

  6. Studies in High Current Density Ion Sources for Heavy Ion Fusion Applications

    E-Print Network [OSTI]

    Chacon-Golcher, E.

    2002-01-01

    a multiple filament heating module was designed. Fourcentimeters away from the heating module, these Mo-Rh leadsthese pages required a heating module capable of achieving

  7. Role of leptin in regulating the bovine hypothalamic-gonadotropic axis 

    E-Print Network [OSTI]

    Amstalden, Marcel

    2004-09-30

    that determines future reproductive potential of beef cows (Schillo et al., 1992). In mature beef cows, rebreeding within 80 to 90 days post-partum is crucial to maximize annual calf production (Williams, 1990). The identification, study, and understanding...RH, the origin of the pulsatile nature of release is not well understood. Observations that murine GnRH-secreting immortalized cells, GT1 cells, secrete GnRH in a pulsatile mode (Martinez de la Escalera et al., 1992), suggest that GnRH neurons have an intrinsic...

  8. CX-009632: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    INTEC – Suspect RH-TRU (AMWTP) CX(s) Applied: NO CX GIVEN Date: 11/23/2012 Location(s): Idaho Offices(s): Idaho Operations Office

  9. Identification and Mechanism of Small Molecule Inhibitors of RNA Interference

    E-Print Network [OSTI]

    Elkashef, Samer

    2011-01-01

    193-8. Tijsterman M, May RC, Simmer F, Okihara KL, PlasterkTops BB, Tabara H, Sijen T, Simmer F, Mello CC, Plasterk RH,

  10. Performance analysis of an integrated UFAD and radiant hydronic slab system

    E-Print Network [OSTI]

    Raftery, Paul; Ho Lee, Kwang; Webster, Tom; Bauman, Fred

    2011-01-01

    validation of the EnergyPlus low-temperature radiantbuilding>. [19] US DOE. EnergyPlus: building technologiesenergy.gov/buildings/energyplus/>. [20] Henninger RH, Witte

  11. Utilization of CO2 as cushion gas for porous media compressed air energy storage

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2014-01-01

    of compressed air energy storage electric power systems.RH, Compressed Air Energy Storage: Theory, Resources, andmedia compressed air energy storage (PM-CAES): theory and

  12. NELL-1 regulates BMSC osteogenic and adipogenic differentiation by interacting with Integrin and regulating cell focal adhesion

    E-Print Network [OSTI]

    Chung, Jong Uk

    2012-01-01

    a potential complication of off-label PLIF/TLIF use of bonecomplications associated with off- label usage of rhBMP-2 in

  13. Oligocene-Miocene Sedimentary and Volcanic Strata of the Vincent Gap Region, Eastern San Gabriel Mountains, Southern California, USA, and Their Tectonic Significance

    E-Print Network [OSTI]

    Coffey, Kevin Thomas

    2015-01-01

    Nevada: tectonics, stratigraphy and hydrogeology: PacificT.W. , Jr. , 1958, Stratigraphy of the Cuyama Valley-Jahns, R.H. , 1940, Stratigraphy of the easternmost Ventura

  14. Toward a consistency cross-check of eddy covariance flux–based and biometric estimates of ecosystem carbon balance

    E-Print Network [OSTI]

    2009-01-01

    of this figure in the HTML. as GPP – NPP + Rh. Because theof this figure in the HTML. [ 39 ] Ideally the Ra/GPP and

  15. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    July 2010 Chemical and Morphological Evolution of Nanoporous PdRh Alloy Particles for Hydrogen Storage. Robinson, David ; Jacobs, Ben W. ; Sugar, Joshua Daniel Abstract not...

  16. Development of a Humid Climate Definition 

    E-Print Network [OSTI]

    Hedrick, R. L.; Shirey, D. B.

    1998-01-01

    are the number of hours per year with space humidity above 60% RH and the number of occupied hours with space humidity above 60% RH. TMY2 weather data (NREL 1995) for 10 cities was used for the annual building energy simulations. TMY2 data was also used...

  17. Catalytic Porous Ceramic Prepared In-Situ by Sol-Gelation for Butane-to-Syngas Processing

    E-Print Network [OSTI]

    Daraio, Chiara

    Catalytic Porous Ceramic Prepared In-Situ by Sol-Gelation for Butane-to-Syngas Processing­1859, 2009 Keywords: catalytic porous ceramic, butane-to-syngas processing, catalytic foam, sol-gelation, Rh containing cat- alytic Rh/ceria/zirconia nanoparticles is tested by its catalytic performance for butane

  18. Potentials of Mean Force and Permeabilities for Carbon Dioxide, Ammonia, and Water Flux across a Rhesus Protein

    E-Print Network [OSTI]

    de Groot, Bert

    Potentials of Mean Force and Permeabilities for Carbon Dioxide, Ammonia, and Water Flux across events of ammonia and carbon dioxide across Rh50 from Nitrosomonas europaea. The simulations show that Rh proteins facilitate carbon dioxide (CO2) transport, and indeed this has been speculated to be their genuine

  19. Modeling endocrine control of the pituitary-ovarian axis: Androgenic

    E-Print Network [OSTI]

    : aohendri@ncsu.edu 1 #12;Abstract Mathematical models of the hypothalamus-pituitary-ovarian axis in women. Gonadotropin-releasing hormone (GnRH) from the hypothalamus prompts the pituitary to produce follicle and on the ovaries. Pulses of gonadotropin-releasing hormone (GnRH) produced by the hypothalamus on a time scale

  20. A Simulation of Moisture Diffusion Process in Furniture-Grade

    E-Print Network [OSTI]

    made for solid wood along the three principal directions Partial vapor pressure ­ the most proper for the moisture diffusion process through MDF using partial vapor pressure as the driving force, and (c/cm/mmHg/Hr) P = partial vapor pressure (mmHg) X = dimension coordinate (cm) Diffusion Cell RH1, P1 RH2, P2 Salt

  1. 2000 S.KargerAG,Basel Fax +41 61 306 12 34

    E-Print Network [OSTI]

    Boyd, Sunny K.

    forms and brain distribution of gonado- tropin-releasing hormone (GnRH) have been well stud- ied a pro- posed salmonid-like GnRH form [Eiden et al., 1982; Sher- wood et al., 1986b; King et al., 1994

  2. Pulse Sensitivity of the Luteinizing Hormone Promoter Is Determined by a Negative Feedback

    E-Print Network [OSTI]

    Lawson, Mark A.

    Pulse Sensitivity of the Luteinizing Hormone Promoter Is Determined by a Negative Feedback LoopRH. Alterations in pulse frequency and amplitude alter the relative levels of gonado- tropin synthesis and release. The mechanism of interpretation of GnRH pulse frequency and ampli- tude by gonadotropes is not understood. We

  3. Color vision is achieved by comparing the inputs from retinal photoreceptor neurons that differ in their wavelength

    E-Print Network [OSTI]

    Desplan, Claude

    objects lacks UV and is composed pre- dominantly of green/yellow middle-energy wavelengths. Therefore green-light-sensitive cone R photoreceptor cell Rh rhodopsin Rh1 blue/green-sensitive opsin S cone blue to UV and green wavelengths [1]. This two-pigment system may have evolved into a broader range

  4. Planned Change Request for Shielded Containers

    E-Print Network [OSTI]

    of the RH TRU waste can be received and emplaced at the WIPP. The shielded containers will be transported to WIPP in the HalfPACT transportation container. The shielded containers will be managed and emplaced inventory for the WIPP. Candidate RH waste streams for shipment and disposal in shielded containers have

  5. ORIGINAL PAPER Tunability of Propane Conversion over Alumina Supported

    E-Print Network [OSTI]

    ORIGINAL PAPER Tunability of Propane Conversion over Alumina Supported Pt and Rh Catalysts William Propane conversion over alumina supported Pt and Rh (1 wt% metals loading) was examined under fuel rich conversion and almost complete propane conversion) so long as the metal particle size was sufficiently low

  6. Conventional Facilities Chapter 13: Code Analysis 13-1 NSLS-II Preliminary Design Report

    E-Print Network [OSTI]

    Ohta, Shigemi

    Room 976 9761 OPS-106 2nd Floor Toilet & Shower 76 1522 OPS-107 Entrance Lobby & Vestibule 2,415 2. Allocated Space : 6,688 1 6,688NSF x Rooms Reqd. = Total Net Square Feet Walls: Paint Floors: Sealed Criteria EMI Criteria Cooling Cooling 78 30 1.8 10 F +/- RH +/- F RH Heating Heating Vibration Requirements

  7. January 9, 2004 Radio Observations of Rapid Acceleration in a Slow Filament Eruption/Fast

    E-Print Network [OSTI]

    White, Stephen

    January 9, 2004 Radio Observations of Rapid Acceleration in a Slow Filament Eruption/Fast CME Event, Navrang-pura, Ahmedabad-380009, India ABSTRACT We discuss a filament eruption/coronal mass ejection (CME was observed by the Nobeyama RadioHeliograph (NoRH) at 17 and 34 GHz. NoRH ob- serves the filament during its

  8. Adaptor synthesis for real-time components Massimo Tivoli1

    E-Print Network [OSTI]

    Girault, Alain

    @di.univaq.it 2 INRIA Rh^one-Alpes - POP ART project 655 avenue de l'Europe, 38330 Montbonnot, France {Pascal author was a postdoctoral fellow in the Pop Art project team at INRIA Rh^one-Alpes. #12;2 Tivoli, Fradet

  9. 26th Symposium on Fusion Technology SOFT2010, Porto, Portugal The Remote Handling Systems for ITER

    E-Print Network [OSTI]

    Ribeiro,Isabel

    - for removal of components Refurbishment or disposal as radwaste is introduced through the ports at the three levels RH Equipment #12;RH Systems for ITER 5 Hot Cell Building (HCB) Refurbishment or disposal to HCB for refurbishment (First Wall exchange) or disposal as radwaste ­ Bolting/unbolting ­ Cooling

  10. Evidence for Insulin Suppression of Baseline Luteinizing Hormone in Women with Polycystic

    E-Print Network [OSTI]

    Lawson, Mark A.

    doses of GnRH during a fixed rate of insulin infusion and LH responses to a fixed dose of GnRH during varying doses of insulin infusion were analyzed for contributing factors. Patients and Setting: Eighteen and during insulin infusion at theGeneral Clinical Research Center, University of California, San Diego. Main

  11. Relations as patterns: bridging the gap between OBO and OWL

    E-Print Network [OSTI]

    Hoehndorf, Robert; Oellrich, Anika; Dumontier, Michel; Kelso, Janet; Rebholz-Schuhmann, Dietrich; Herre, Heinrich

    2010-08-31

    University, 1125 Colonel By Drive, Ottawa, Ontario K1 S 5B6, Canada. 5Department of Genetics, University of Cambridge, Downing Street, Cambridge CB2 3EH, UK. Authors’ contributions RH conceived of the project and drafted the paper. HH and RH developed...

  12. Neural NILM: Deep Neural Networks Applied to Energy Disaggregation

    E-Print Network [OSTI]

    Knottenbelt, William J.

    of Computing Imperial College London 180 Queen's Gate, London, SW7 2RH, UK jack.kelly@imperial.ac.uk William Knottenbelt Department of Computing Imperial College London 180 Queen's Gate, London, SW7 2RH, UK w) denoising autoencoders; and 3) a network which regresses the start time, end time and average power demand

  13. Remote-Handled Transuranic Content Codes

    SciTech Connect (OSTI)

    Washington TRU Solutions

    2006-12-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: • A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. • A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is “3.” The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR limits based on a 10-day shipping period (rather than the standard 60-day shipping period) may be used as specified in an approved content code.

  14. Interactive Roles of Gonadotropin-Releasing Hormone and RF-Amide Related Peptide 3 in Adenohypophyseal Physiology and Reporduction in the Mare 

    E-Print Network [OSTI]

    Thorson, Jennifer Frances

    2013-01-28

    reduced hypothalamic GnRH content (Strauss et al, 1979) it did not alter circulating LH concentrations in ovariectomized or intact pony mares (Peltier et al., 1997). The report of Strauss et al. (1979) can be interpreted to indicate that GnRH synthesis... is reduced due to the effects of melatonin which may result in a similar decline in GnRH release. However, this does not address the failure of exogenous melatonin to suppress circulating concentrations of LH (Peltier et al., 1997) which would...

  15. Stimulation of Hepatoma Cell Invasiveness and Metastatic Potential by Proteins Secreted From Irradiated Nonparenchymal Cells

    SciTech Connect (OSTI)

    Zhou Leyuan [Department of Radiation Oncology, Zhongshan Hospital, Fudan University, Shanghai (China)] [Department of Radiation Oncology, Zhongshan Hospital, Fudan University, Shanghai (China); Wang Zhiming [Department of Medical Oncology, Zhongshan Hospital, Fudan University, Shanghai (China)] [Department of Medical Oncology, Zhongshan Hospital, Fudan University, Shanghai (China); Gao Yabo [Department of Radiation Oncology, Zhongshan Hospital, Fudan University, Shanghai (China)] [Department of Radiation Oncology, Zhongshan Hospital, Fudan University, Shanghai (China); Wang Lingyan [Experimental Research Center, Zhongshan Hospital, Fudan University, Shanghai (China)] [Experimental Research Center, Zhongshan Hospital, Fudan University, Shanghai (China); Zeng Zhaochong, E-mail: zeng.zhaochong@zs-hospital.sh.cn [Department of Radiation Oncology, Zhongshan Hospital, Fudan University, Shanghai (China)

    2012-11-01

    Purpose: To determine whether factors secreted by irradiated liver nonparenchymal cells (NPCs) may influence invasiveness and/or metastatic potential of hepatocellular carcinoma (HCC) cells and to elucidate a possible mechanism for such effect. Methods and Materials: Primary rat NPCs were cultured and divided into irradiated (10-Gy X-ray) and nonirradiated groups. Forty-eight hours after irradiation, conditioned medium from irradiated (SR) or nonirradiated (SnonR) cultures were collected and added to sublethally irradiated cultures of the hepatoma McA-RH7777 cell line. Then, hepatoma cells were continuously passaged for eight generations (RH10Gy-SR and RH10Gy-SnonR). The invasiveness and metastatic potential of McA-RH7777, RH10Gy-SnonR, and RH10Gy-SR cells were evaluated using an in vitro gelatinous protein (Matrigel) invasion and an in vivo metastasis assay. In addition, SR and SnonR were tested using rat cytokine antibody arrays and enzyme-linked immunosorbent assay (ELISA). Results: In vitro gelatinous protein invasion assay indicated that the numbers of invading cells was significantly higher in RH10Gy-SR (40 {+-} 4.74) than in RH10Gy-SnonR (30.6 {+-} 3.85) cells, and lowest in McA-RH7777 (11.4 {+-} 3.56) cells. The same pattern was observed in vivo in a lung metastasis assay, as evaluated by number of metastatic lung nodules seen with RH10Gy-SR (28.83 {+-} 5.38), RH10Gy-SnonR (22.17 {+-} 4.26), and McA-RH7777 (8.3 {+-} 3.8) cells. Rat cytokine antibody arrays and ELISA demonstrated that metastasis-promoting cytokines (tumor necrosis factor-{alpha} and interleukin-6), circulating growth factors (vascular endothelial growth factor and epidermal growth factor), and metalloproteinases (MMP-2 and MMP-9) were upregulated in SR compared with SnonR. Conclusions: Radiation can increase invasiveness and metastatic potential of sublethally irradiated hepatoma cells, and soluble mediators released from irradiated NPCs promote this potential. Increased secretion of metastasis-related cytokines and factors from NPCs after irradiation may be a possible mechanism for the radiation-induced invasiveness and metastatic potential of HCC.

  16. Generation of Long-Lived Isomeric States via Bremsstrahlung Irradiation

    E-Print Network [OSTI]

    Yao Cheng; Bing Xia; Chuanxiang Tang; Yinong Liu; Qingxiu Jin

    2006-11-08

    A method to generate long-lived isomeric states effectively for Mossbauer applications is reported. We demonstrate that this method is better and easier to provide highly sensitive Mossbauer effect of long-lived isomers (>1ms) such as 103Rh. Excitation of (gamma,gamma) process by synchrotron radiation is painful due mainly to their limited linewidth. Instead,(gamma,gamma') process of bremsstrahlung excitation is applied to create these long-lived isomers. Isomers of 45Sc, 107Ag, 109Ag, and 103Rh have been generated from this method. Among them, 103Rh is the only one that we have obtained the gravitational effect at room temperature.

  17. Mon. Not. R. Astron. Soc. 341, 870890 (2003) Heavy-element abundance patterns in hot DA white dwarfs

    E-Print Network [OSTI]

    Burleigh, Matt

    2003-01-01

    , Leicester LE1 7RH 2Lunar and Planetary Laboratory, University of Arizona, Tucson, AZ 85721, USA 3NASA white dwarfs, having ei- ther hydrogen-rich or helium-rich atmospheres is now, qualitatively at least

  18. Two Software Normal Basis Multiplication Algorithms for GF(2n Haining Fan and Yiqi Dai

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    attention for efficient implementation. For portability as well as for price reasons, it is often is that the size of lookup tables of Algorithm 1 is larger than that of the RH algorithm. The total number

  19. Tritium Leak Detection: Strategies and Applications

    Office of Environmental Management (EM)

    (0.3 DAC) 15 second time constant no offset in 5 mRh field suppression circuit ensures noise free operation better than 2 Cim 3 14 Gas Calibration of Model 2x200-LD Note: After...

  20. Characterization of Biopolymers for Use as Matrices for Encapsulation of Hydrophobic Compounds 

    E-Print Network [OSTI]

    Puerta-Gomez, Alex F.

    2014-01-15

    % RH. The effectiveness of inexpensive encapsulating method based in self-assemble interaction of pure and combination of amphiphilic biopolymers in aqueous system was assessed using both fluorescent spectroscopy and rheological principles. Structure...

  1. Measuring Advances in HVAC Distribution System Design

    E-Print Network [OSTI]

    Franconi, E.

    2011-01-01

    lIIvall RH avail Thermal Energy Thermal Avail Input energythermal based index EDE and thermal energy end-use indices.Thus mechanical and thermal energy sources can be combined

  2. INTERCOMPARISON STUDY OF ELEMENTAL ABUNDANCES IN RAW AND SPENT OIL SHALES

    E-Print Network [OSTI]

    Fox, J.P.

    2011-01-01

    A. Robb, and T. J. Spedding. Minor Elements ~n Oil Shale andOil-Shale Products. LERC RI-77/1, 1977. Wildeman, T. R.H. Meglen. The Analysis of Oil-Shale Materials for Element

  3. TRANSLATIONAL AND CLINICAL RESEARCH Reversing Bone Loss by Directing Mesenchymal Stem

    E-Print Network [OSTI]

    Ritchie, Robert

    due to the inability to control the MSCs' commitment, growth, and differentiation into functional and is approved by Food and Drug Administration is teriparatide (recombinant human parathyroid hormone 1-34; rh

  4. Rhodium-Catalyzed Asymmetric Intramolecular Hydroamination of Unactivated Alkenes

    E-Print Network [OSTI]

    Shen, Xiaoqiang

    One for the Rh(oad): The first rhodium-catalyzed asymmetric intramolecular hydroamination of unactivated olefins was developed by using dialkylbiaryl phosphine ligands (see scheme; cod=1,5-cyclooctadiene, Cy=cyclohexyl). ...

  5. Reproductive neuroendocrine function in the mare as reflected in the intercavernous sinus during ovulatory, anovulatory, and transitional seasons 

    E-Print Network [OSTI]

    Cooper, Dee A

    2006-08-16

    We hypothesized that marked reductions in secretion of luteinizing hormone (LH) during transitional and anovulatory periods can be accounted for by similar reductions in hypothalamic gonadotropin-releasing hormone (GnRH) ...

  6. Effects of continuous treatment with gonadotropin-releasing hormone during the anovulatory season on gonadotropin secretion, follicular dynamics and ovulation in the mare 

    E-Print Network [OSTI]

    Morton, Stephanie

    2005-02-17

    Objectives were to determine if low-dose, continuous infusion of GnRH from Fall to Spring, would prevent seasonal anovulation in mares. Twenty Quarter Horse mares, ages 18 mo to 24 yrs, were stratified by age and body ...

  7. MATHEMATICS MAJOR CONCENTRATION/SPECIALIZATION APPLICATION FORM

    E-Print Network [OSTI]

    Loudon, Catherine

    MATHEMATICS MAJOR CONCENTRATION/SPECIALIZATION APPLICATION FORM Date _______________ Last Name/Year) __________ Check One Concentration/Specialization: Concentration in Mathematics for Education/Secondary Teaching, apantano@uci.edu) Specialization in Applied Computational Mathematics. Advisor: Professor Hongkai Zhao (RH

  8. MATHEMATICS MAJOR CONCENTRATION/SPECIALIZATION APPLICATION FORM

    E-Print Network [OSTI]

    Loudon, Catherine

    MATHEMATICS MAJOR CONCENTRATION/SPECIALIZATION APPLICATION FORM Date _______________ Last Name/Year) __________ Check One Concentration/Specialization: Concentration in Mathematical Finance. Advisor: Professor Matthew Foreman (RH 440A, mforeman@math.uci.edu) Concentration in Mathematics for Education

  9. Asymptotic Accuracy of the Equilibrium Diffusion Approximation and Semi-analytic Solutions of Radiating Shocks 

    E-Print Network [OSTI]

    Ferguson, Jim Michael

    2014-01-10

    Radiation hydrodynamics (RH) provides a theoretical description for many astrophysical events spanning a wide range of observable phenomena. It is the goal of high-energy-density laboratory astrophysics (HEDLA) to reproduce some of these events...

  10. Introgression & mapping Fiber cell

    E-Print Network [OSTI]

    Germplasm Introgression Genomics & mapping Fiber cell initiation Radiation hybrid (RH) mapping and breeding. Research activities commonly include plant breeding, genetics, genomics, cytogenetics, molecular methods. (C, S) · Contribute uniquely to genomics and its relevance to genetic improvement (C,S) · Harness

  11. Cultivar and E-Beam irradiation effects on phytochemical content and antioxidant properties of pecan kernels 

    E-Print Network [OSTI]

    Villarreal Lozoya, Jose Emilio

    2009-05-15

    °C and 55% R.H.). Changes in phytochemical profile and antioxidant properties were monitored for 134 days. Cultivars differed greatly in their phytochemical content. Total extractable phenolic content (TP) ranged from 62 to 106 milligrams of chlorogenic acid...

  12. Title 40 CFR Part 191 Subparts B and C

    E-Print Network [OSTI]

    -3503 Section 27-201427-vi Elements and Chemical Compounds CO2 carbon dioxide MgO magnesium oxide #12;Title 40 RHPIP Remote-Handled TRU Waste Characterization Program Implementation Plan RH remote-handled RSI

  13. Role of an Equine Homologue of Gonadotropin-Inhibiting Hormone in Controlling Sectretion of Luteinizing Hormone in the Mare 

    E-Print Network [OSTI]

    Prezotto, Ligia Dias

    2012-07-16

    Four experiments were conducted to test the hypothesis that RF-amide related peptide 3 (RFRP3) negatively regulate the secretion of LH in mares. In Exp. 1, mares received native gonadotropin-releasing hormone (GnRH) ...

  14. This article was downloaded by: [University Of Maryland] On: 05 May 2012, At: 10:16

    E-Print Network [OSTI]

    Li, Zhanqing

    ://www.tandfonline.com/loi/tres20 SPOT VEGETATION for characterizing boreal forest fires R.H. Fraser a , Z. Li b & R. Landry b. Landry (2000): SPOT VEGETATION for characterizing boreal forest fires, International Journal of Remote

  15. Testing Modules for Potential-Induced Degradation - A Status Update of IEC 62804 (Presentation)

    SciTech Connect (OSTI)

    Hacke, P.

    2014-03-01

    Stresses and degradation rates for the 25 degrees C with foil and the 60 degrees C/85% RH damp heat tests are compared, the Illumination factor on PID rate is evaluated, and measurement techniques and stress levels are discussed.

  16. Redistricting and the U.S. House of Representatives : illuminating electoral bias with the Brookes Method

    E-Print Network [OSTI]

    Hill, Tony L.

    2010-01-01

    This dissertation analyzes the effects of Congressional redistricting in the United States using the Brookes Method, developed by R.H. Brookes, a New Zealand political scientist. The Brookes Method disaggregates electoral ...

  17. Monodisperse metal nanoparticle catalysts on silica mesoporous supports: synthesis, characterizations, and catalytic reactions

    E-Print Network [OSTI]

    Somorjai, G.A.

    2010-01-01

    by Rh/SBA-15 The catalytic oxidation of CO to CO 2 has beencatalytic activity in high temperature CO oxidation. Thecatalytic activity as high as bare Pt nanoparticles in CO oxidation,

  18. This

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inc. spectrometer and a ca. 1.85 GBq 57 CoRh source. The samples were mounted in a polyethylene cell. The sample thickness was about 10 mgcm 2 Fe. The line width of the -Fe...

  19. Evidence for a gonadotropin inhibitory hormone (GnIH) system in the vertebrate gonads

    E-Print Network [OSTI]

    McGuire, Nicolette

    2011-01-01

    cells in the hypothalamus of the brain produce and secretepreoptic area of the hypothalamus of mammals and birds (7-secretion of GnRH from the hypothalamus and LH and FSH from

  20. The functional significance of neurokinin 3 receptor signaling in gonadotropin-releasing hormone neurons

    E-Print Network [OSTI]

    Shao, Paul Peng Lin

    2012-01-01

    expression in the rat hypothalamus. Brain Res. 1026: 307-12,3 receptor in the rat hypothalamus following acuteabout 800 neurons in the hypothalamus. GnRH is released from

  1. A&A 439, 987996 (2005) DOI: 10.1051/0004-6361:20053107

    E-Print Network [OSTI]

    Smith, Ian Andrew

    2005-01-01

    , University of Leicester, Leicester LE1 7RH, UK 8 NASA Marshall Space Flight Center, SD-50, NSSTC, 320 for future observations in the Swift era. None of these GRBs had significant sub-millimeter emission from

  2. Solutions to Surgical Suite Temperature and Humidity Control 

    E-Print Network [OSTI]

    Crooks, K. W.

    1996-01-01

    . Relative humidity (RH) must still be controlled at these lower temperatures per code guidelines and poses a major hurdle for facilities located throughout the southeastern United States. Heating, ventilating and air conditioning (HVAC) equipment designed...

  3. Synchronization of follicular wave emergence, luteal regression, and ovulation for fixed-time artificial insemination in beef cows and heifers 

    E-Print Network [OSTI]

    Stutts, Kyle Jeffrey

    2006-10-30

    Two experiments tested the efficacy of gonadotropin-releasing hormone (GnRH) or estradiol cypionate (ECP) administration in combination with controlled internal drug release (CIDR) inserts on pregnancy rate to fixed-time artificial insemination...

  4. Investigation of the optical and cloud forming properties of pollution, biomass burning, and mineral dust aerosols 

    E-Print Network [OSTI]

    Lee, Yong Seob

    2006-08-16

    that were observed during this period. The predicted cloud condensation nuclei concentrations were used in a cloud model to determine the impact of the different aerosol types on the expected cloud droplet concentration. RH-dependent aerosol extinction...

  5. An Experimental Evaluation of Duct-Mounted Relative Humidity Sensors: Part 1 – Test and Evaluation Procedures 

    E-Print Network [OSTI]

    Joshi, S.N.; Pate, M.B.; Nelson, R.M.; House, R.H.; Klaasen, C.J.

    2005-01-01

    In this dissertation, catalytic C-F bond activation mediated by alumenium and silylium species, improved methods for the synthesis of highly chlorinated carboranes and dodecaborates, new type of P2Si= pincer silylene Pt complexes and PBP pincer Rh...

  6. Control of new follicular wave emergence and rate of follicular maturation in bos indicus-influenced cattle with estradiol benzoate, temporary calf removal and progesterone 

    E-Print Network [OSTI]

    Pack, Julie Diane

    2009-05-15

    Objectives were to determine: 1) whether estradiol benzoate (EB) provides a superior alternative to GnRH for synchronizing emergence, growth and maturation of a new follicular wave for fixed timed AI (TAI) in Bos ...

  7. Dimensions are shown in inch (mm ) Dimensions subject to change

    E-Print Network [OSTI]

    Berns, Hans-Gerd

    at 40°C, 93% RH SALT MIST RESISTANCE: 96 hours Materials COVER & BASE: Thermoplastic PPS ACTUATOR: PA Thermoplastic KNOB: Thermoplastic MOVABLE CONTACTS: Brass, gold or silver plated. STATIONARY CONTACTS: Brass

  8. An experimental study of OH uptake by surfaces of tropospheric importance under dry and wet conditions

    E-Print Network [OSTI]

    Park, Jong-Ho, 1973-

    2008-01-01

    The effect of relative humidity (RH) on OH uptake by surfaces of tropospheric importance was investigated. Due to diffusion limitation conditions, experiments were performed with parallel reactors packed with beads and ...

  9. The role of primate superior colliculus in the selection of visual objects for action

    E-Print Network [OSTI]

    Nummela, Samuel Uno

    2010-01-01

    Methods 107: 81-85, Chou I, Sommer MA, Schiller PH. ExpressJ Neurophysiol 80: 458- Sommer MA, Tehovnik EJ. ReversibleRes 116: 229-249, 1997. Sommer MA, Wurtz RH. What the brain

  10. A sensitizing regimen of methamphetamine causes impairments in a novelty preference task of object recognition

    E-Print Network [OSTI]

    Belcher, Annabelle M; O'Dell, Steven J; Marshall, John F

    2006-01-01

    affinity binding of [ 125 I]RTI-55 to dopamine and serotoninOR, object recognition; pRh, perirhinal cortex; RTI, [ 125I]RTI-55; SAL, saline; SERT, serotonin transporter; STM,

  11. INTERCOMPARISON STUDY OF ELEMENTAL ABUNDANCES IN RAW AND SPENT OIL SHALES

    E-Print Network [OSTI]

    Fox, J.P.

    2011-01-01

    W. A. Robb, and T. J. Spedding. Minor Elements ~n Oil Shaleand Oil-Shale Products. LERC RI-77/1, 1977. Wildeman, T. R.H. Meglen. The Analysis of Oil-Shale Materials for Element

  12. Regulation of ESR1 in Kisspeptin Neurons during Reproductive Maturation in Ewe Lambs 

    E-Print Network [OSTI]

    Bedenbaugh, Michelle Nichole

    2014-08-28

    The pubertal initiation of a high-frequency, pulsatile release of gonadotropin-releasing hormone (GnRH) involves an escape from estradiol negative feedback. Kisspeptin neurons are proposed to mediate the effects of estradiol, ...

  13. Kiss1 Gene Expression and the Effects of Kisspeptin During Pubertal Development in the Ewe Lamb 

    E-Print Network [OSTI]

    Redmond, Jeremy Scott

    2012-02-14

    Increased pulsatile release of gonadotropin-releasing hormone (GnRH) and luteinizing hormone (LH) is critical for pubertal initiation of ovarian cycles in female mammals. Kisspeptin, a peptide product of the Kiss1 gene, ...

  14. Rhodium-catalyzed epoxide-opening cascades toward brevisin and hemibrevetoxin B

    E-Print Network [OSTI]

    Armbrust, Kurt W. (Kurt Willes)

    2014-01-01

    CHAPTER I. Rhodium-Catalyzed Epoxide-Opening Cascades: Formal Synthesis of (-)-Brevisin [chemical formula inserted] [Rh(CO)?Cl]? was found to be an effective catalyst for endo-selective cyclizations and cascades of ...

  15. Evaporation/ Solution Droplet

    E-Print Network [OSTI]

    Suslick, Kenneth S.

    Solvent Evaporation/ Reactions Precursor Solution Droplet Product Densification Product Collection Production of Nano-Materials microporous shell internal macropores Hierarchically Porous Carbons Brandon Ito (20 ppm) Formaldehyde (20 ppm) Control (50% RH) Maryam SayyahKaty Filson Wei Jiang Mechanoluminescence

  16. A generalized land use study of the San Jacinto River watershed of Texas 

    E-Print Network [OSTI]

    Buckley, Frank A.

    1951-01-01

    .H U o CO -* i>> -P nrt Pi Pi ? CS O w CM 0 , ? j i -p o 1 M H?H P I 03 X ) Pi 05 m g 6 u PQ CM . . LO CM CO CT5 ?i CD CM CM ? Pi !>s ?H 'a ; L GS ? CQ CO O "d O ? 1--1 O UD r~! o o w -P 1 r... s? erf O ca 24 S i O -P ? ?Sa? n > aS ? ^4T aS CO i?i 1?1 X5 ?H O X i CQ ? rO 0 ?rH C0 CO cS nL 0 rH W rH 10 03 > )H d > r *h w Fl O ctf CO fci?) CO pQ Pi 0 ?H rd ca 'd ? 0 U ? rH O CO o ? Pi O ? ?H O...

  17. March 2015 Most Viewed Documents for Energy Storage, Conversion...

    Office of Scientific and Technical Information (OSTI)

    Seiber, L.E.; Marlino, L.D.; Staunton, R.H.; Cunningham, J.P. (2008) 113 Seventh Edition Fuel Cell Handbook NETL (2004) 111 New Regenerative Cycle for Vapor Compression...

  18. Electrocatalyst for alcohol oxidation at fuel cell anodes

    DOE Patents [OSTI]

    Adzic, Radoslav (East Setauket, NY); Kowal, Andrzej (Cracow, PL)

    2011-11-02

    In some embodiments a ternary electrocatalyst is provided. The electrocatalyst can be used in an anode for oxidizing alcohol in a fuel cell. In some embodiments, the ternary electrocatalyst may include a noble metal particle having a surface decorated with clusters of SnO.sub.2 and Rh. The noble metal particles may include platinum, palladium, ruthenium, iridium, gold, and combinations thereof. In some embodiments, the ternary electrocatalyst includes SnO.sub.2 particles having a surface decorated with clusters of a noble metal and Rh. Some ternary electrocatalysts include noble metal particles with clusters of SnO.sub.2 and Rh at their surfaces. In some embodiments the electrocatalyst particle cores are nanoparticles. Some embodiments of the invention provide a fuel cell including an anode incorporating the ternary electrocatalyst. In some aspects a method of using ternary electrocatalysts of Pt, Rh, and SnO.sub.2 to oxidize an alcohol in a fuel cell is described.

  19. Development of novel metal-catalysed methods for the transformation of Ynamides 

    E-Print Network [OSTI]

    Smith, Donna Lee

    2013-11-28

    I. Rhodium-Catalysed Carbometalation of Ynamides using Organoboron Reagents. As an expansion of existing procedures for the carbometalation of ynamides, it was discovered that [Rh(cod)(MeCN)2]BF4 successfully promotes the ...

  20. Stabilities of the Aqueous Complexes Cm(CO3)3 and Am(CO3)3

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    /T reflecting negligible temperature influence on the corresponding molar enthalpy change rH3 = 12+ (28%), Pu(OH)2 + (21%) and PuCO3 + (19%). Thermochemical databases have been constructed from

  1. Growth and structure of water on SiO2 films on Si investigated by Kelvin probe microscopy and in situ X-ray Spectroscopies

    E-Print Network [OSTI]

    Verdaguer, A.; Weis, C.; Oncins, G.; Ketteler, G.; Bluhm, H.; Salmeron, M.

    2008-01-01

    Growth and Structure of water on SiO 2 films on Simbsalmeron@lbl.gov The growth of water on thin SiO 2 films75% relative humidity (RH) water adsorbs forming a uniform

  2. Nanocomposites for nitrogen oxide emissions control in lean-burn engines

    E-Print Network [OSTI]

    Pitukmanorom, Pemakorn, 1976-

    2004-01-01

    (cont.) reducing agent than propane in the SCR of NO. Pt-Rh/CuO/A1?O? nanocomposites capable of adsorbing SO? in oxygen-rich environment as metal sulfates and releasing SO? in reducing atmosphere were synthesized with ...

  3. Side-Jump Effect in Paramagnetic Amorphous Metals 

    E-Print Network [OSTI]

    RHIE, K.; Naugle, Donald G.; O, BH; MARKERT, JT.

    1993-01-01

    A systematic study of the resistivity (rho), the Hall coefficients (R(H)), and the magnetic susceptibilities (chi) of the Zr-based paramagnetic amorphous alloys suggests a self-consistent explanation for the frequently observed positive values of R...

  4. Gene loss, adaptive evolution and the co-evolution of plumage coloration genes

    E-Print Network [OSTI]

    Jarvis, Erich D.

    importance of vision in birds. Visual conopsins sw1, sw2 and lw evolved under negative selection, while the dim-light RH1 photopigment diversified. The evolutionary patterns of sw1 and of violet

  5. Proceedings of the Symposium on Recent Advances in Geotechnical Centrifuge Modeling

    E-Print Network [OSTI]

    Center for Geotechnical Modeling, Department of Civil Engineering, University of California Davis

    1984-01-01

    S. Bang and J.F. Mitchell, "Centrifuge Modeling of a LateralJ.A. Cheney, "Drum Centrifuge Studies of Overconsolidatedand R.H. Bassett, "Centrifuge Testing in Geotechnical

  6. Relative humidity and its effect on aerosol optical depth in the vicinity of convective clouds

    E-Print Network [OSTI]

    Altaratz, O

    The hygroscopic growth of aerosols is controlled by the relative humidity (RH) and changes the aerosols' physical and hence optical properties. Observational studies of aerosol–cloud interactions evaluate the aerosol ...

  7. OPTOGENETIC CONTROL OF MOTOR COORDINATION BY Gi/o PROTEIN-COUPLED VERTEBRATE RHODOPSIN IN CEREBELLAR PURKINJE CELLS.

    E-Print Network [OSTI]

    pertussis toxin-sensitive Gi/o protein-mediated signaling (3). Therefore, vRh may allow for the precise and synaptic plasticity. It has been recognized that the code for motor coordination and balance lies within

  8. C-H vs C-C Bond Activation of Acetonitrile and Benzonitrile via Oxidative Addition: Rhodium vs Nickel and Cp* vs Tp

    E-Print Network [OSTI]

    Jones, William D.

    or benzene leads to thermal rearrangement to the C-C activation product, (C5Me5)Rh(PMe3)(CH3)(CN) (4C-H vs C-C Bond Activation of Acetonitrile and Benzonitrile via Oxidative Addition: Rhodium vs of the C-H activation product, (C5Me5)Rh(PMe3)(CH2CN)H (2). Thermolysis of this product in acetonitrile

  9. Augmenter of liver regeneration causes different kinetics of ERK1/2 and Akt/PKB phosphorylation than EGF and induces hepatocyte proliferation in an EGF receptor independent and liver specific manner

    SciTech Connect (OSTI)

    Ilowski, Maren; Putz, Christine [Department of Surgery, Ludwig-Maximilians-University of Munich Hospital Grosshadern, Munich (Germany)] [Department of Surgery, Ludwig-Maximilians-University of Munich Hospital Grosshadern, Munich (Germany); Weiss, Thomas S. [Department of Surgery, University of Regensburg Hospital, Regensburg (Germany)] [Department of Surgery, University of Regensburg Hospital, Regensburg (Germany); Brand, Stephan [Department of Internal Medicine II, Ludwig-Maximilians-University of Munich Hospital Grosshadern, Munich (Germany)] [Department of Internal Medicine II, Ludwig-Maximilians-University of Munich Hospital Grosshadern, Munich (Germany); Jauch, Karl-Walter [Department of Surgery, Ludwig-Maximilians-University of Munich Hospital Grosshadern, Munich (Germany)] [Department of Surgery, Ludwig-Maximilians-University of Munich Hospital Grosshadern, Munich (Germany); Hengstler, Jan G. [Leibniz Research Centre for Working Environment and Human Factors, TU Dortmund University, Dortmund (Germany)] [Leibniz Research Centre for Working Environment and Human Factors, TU Dortmund University, Dortmund (Germany); Thasler, Wolfgang Erwin, E-mail: wolfgang.thasler@med.uni-muenchen.de [Department of Surgery, Ludwig-Maximilians-University of Munich Hospital Grosshadern, Munich (Germany)

    2010-04-16

    Background/Aim: Augmenter of liver regeneration (ALR) is a potent growth factor which supports liver regeneration in experimental animals. The aim of this study was to compare proliferation as well as the kinetics of ERK1/2 and Akt/PKB phosphorylation by recombinant human ALR (rhALR) and EGF in human hepatocytes and extrahepatic cells. Methods: Kinetics of ERK1/2 and Akt/PKB phosphorylation were determined in primary human hepatocytes (phh) after stimulation with rhALR and EGF. Induction of proliferation was analyzed in phh and several cell lines of hepatic and extrahepatic origin by the MTT and [{sup 3}H]-thymidine assay. Results: The kinetics of ERK phosphorylation showed clear differences, whereby rhALR caused a transient and EGF a permanent increase during the observation period of 60 min. For both, Akt and ERK phosphorylation, EGF caused a faster effect with maximal levels observed already after 2 min, whereas rhALR caused maximal phosphorylation between 10 and 15 min. Using the EGF receptor inhibitor AG1478 we provide evidence of an EGF receptor independent induction of proliferation by rhALR. Furthermore, rhALR induced proliferation only in phh and the human liver derived cell lines HepG2 and Chang. In contrast, EGF enhanced proliferation in all analyzed cell types including cell lines of colon, bronchial, pancreatic and gastric origin (SW480, BC1, L36PL and GC1). Conclusion: rhALR and EGF induce different kinetics of ERK and Akt phosphorylation in human hepatocytes. The mitogenic effect of rhALR is liver specific and seems to be at least partially independent from EGF receptor mediated signaling.

  10. A Quick Overview of the Art of Humidity Measurement 

    E-Print Network [OSTI]

    Brownawell, M.

    1989-01-01

    for 300 hours. R.H. 72 ESL-IE-89-09-14 Proceedings from the Eleventh National Industrial Energy Technology Conference, Houston, TX, September 12-14, 1989 ..., Houston, TX, September 12-14, 1989 % RH, RELATIVE HUMIDITY Relative humidity is measured in many ways. The expansion and contraction of many materials with changes in relative humidity are well known. This phenomenon is used in the hair hygrometers...

  11. Application of a ratiometric laser induced fluorescence (LIF) thermometry for micro-scale temperature measurement for natural convection flows 

    E-Print Network [OSTI]

    Lee, Heon Ju

    2004-11-15

    ????????????????????????. x CHAPTER I INTRODUCTION??????????????????? 1 1.1 Literature Review??????????..???????. 1 1.2 Summary of Present Study??????????.....??? 2 II BACKGROUND???????????????????? 4 2.1 Principle of Fluorescence & Ratiometric LIF... Process: The White Arrows Represent That Water Circulates the Thermo-baths to Maintain Isothermal Conditions.. 10 3.2 Temperature Dependence of Fluorescence Images of Rh-B (column (a)), Rh-110 (column (b)) and Their Ratiometric Images (column (c...

  12. Contact-Handled and Remote-Handled Transuranic Waste Packaging

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2011-08-09

    Provides specific instructions for packaging and/or repackaging contact-handled transuranic (CH-TRU) and remote-handled transuranic (RH-TRU) waste in a manner consistent with DOE O 435.1, Radioactive Waste Management, DOE M 435.1-1 Chg 1, Radioactive Waste Management Manual, CH-TRU and RH-TRU waste transportation requirements, and Waste Isolation Pilot Plant (WIPP) programmatic requirements. Does not cancel/supersede other directives.

  13. Mechanistic investigation of vinylic carbonfluorine bond activation of perfluorinated cycloalkenes using Cp*2ZrH2 and Cp*2ZrHF

    E-Print Network [OSTI]

    Jones, William D.

    using Cp*2ZrH2 and Cp*2ZrHF Bradley M. Kraft a , Eric Clot b , Odile Eisenstein b , William W behaves similarly [4]. In contrast, Cp*Rh(PMe3)H2 reacts with C6F6 by way of an SNAr2 attack by its conjugate base to give Cp*Rh(PMe3)(C6F5)H and fluoride ion, resulting in an autocatalytic reaction [5]. Cp

  14. A RhxSy/C Catalyst for the Hydrogen Oxidation and Hydrogen Evolution Reactions in HBr

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Masud, Jahangir [Univ. of Kansas, Lawrence, KS (United States); Nguyena, Trung V. [Univ. of Kansas, Lawrence, KS (United States); Singh, Nirala [Univ. of California, Santa Barbara, CA (United States); McFarland, Eric [Univ. of California, Santa Barbara, CA (United States); Ikenberry, Myles [Kansas State Univ., Manhattan, KS (United States); Hohn, Keith [Kansas State Univ., Manhattan, KS (United States); Pan, Chun-Jern [National Taiwan University of Science & Technology, Tapei (Taiwan); Hwang, Bing-Joe [National Taiwan University of Science & Technology, Tapei (Taiwan)

    2015-01-01

    Rhodium sulfide (Rh2S3) on carbon support was synthesized by refluxing rhodium chloride with ammonium thiosulfate. Thermal treatment of Rh2S3 at high temperatures (600°C to 850°C) in presence of argon resulted in the transformation of Rh2S3 into Rh3S4, Rh17S15 and Rh which were characterized by TGA/DTA, XRD, EDX, and deconvolved XPS analyses. The catalyst particle size distribution ranged from 3 to 12 nm. Cyclic voltammetry and rotating disk electrode measurements were used to evaluate the catalytic activity for hydrogen oxidation and evolution reactions in H2SO4 and HBr solutions. The thermally treated catalysts show high activity for the hydrogen reactions. The exchange current densities (io) of the synthesized RhxSy catalysts in H2-saturated 1M H2SO4 and 1M HBr for HER and HOR were 0.9 mA/cm2 to 1.0 mA/cm2 and 0.8 to 0.9 mA/cm2, respectively. The lower io values obtained in 1M HBr solution compared to in H2SO4 might be due to the adsorption of Br- on the active surface. Stable electrochemical active surface area (ECSA) of RhxSy catalyst was obtained for CV scan limits between 0 V and 0.65 V vs. RHE. Scans with upper voltage limit beyond 0.65 V led to decreased and unreproducible ECSA measurements.

  15. Process for functionalizing alkanes

    DOE Patents [OSTI]

    Bergman, Robert G. (Kensington, CA); Janowicz, Andrew H. (Wilmington, DE); Periana-Pillai, Roy A. (Berkeley, CA)

    1985-01-01

    Process for functionalizing saturated hydrocarbons selectively in the terminal position comprising: (a) reacting said saturated hydrocarbons of the formula: RH where: H represents a hydrogen atom, and R represents a saturated hydrocarbon radical, with a metal complex of the formula: CpRhPMe.sub.3 H.sub.2 where: Cp represents a pentamethylated cyclopentadienyl radical, Rh represents a rhodium atom, P represents a phosphorous atom, Me represents a methyl group, H represents a hydrogen atom, in the presence of ultraviolet radiation at a temperature maintained at about -60.degree. to -17.degree. C. to form a hydridoalkyl complex of the formula: CpRhPMe.sub.3 RH (b) reacting said hydridoalkyl complex with a haloform of the formula: CHX.sub.3 where: X represents a bromine, iodine or chlorine atom, at a temperature in the range of about -60.degree. to -17.degree. C. to form the corresponding haloalkyl complex of step (a) having the formula: CpRhPMe.sub.3 RX; and, (c) reacting said haloalkyl complex formed in (b) with halogen (X.sub.2) at a temperature in the range of about -60.degree. to 25.degree. C. (i.e. ambient) to form a functional haloalkyl compound.

  16. Viscosity of ?-pinene secondary organic material and implications for particle growth and reactivity

    SciTech Connect (OSTI)

    Renbaum-Wolff, Lindsay; Grayson, James W.; Bateman, Adam P.; Kuwata, Mikinori; Sellier, Mathieu; Murray, Benjamin J.; Shilling, John E.; Martin, Scot T.; Bertram, Allan K.

    2013-05-14

    Particles composed of secondary organic material (SOM) are abundant in the lower troposphere and play important roles in climate, air quality, and health. The viscosity of these particles is a fundamental property that is presently poorly quantified for conditions relevant to the lower troposphere. Using two new techniques, namely a bead-mobility technique and a poke-flow technique, in conjunction with simulations of fluid flow, we measure the viscosity of the watersoluble component of SOM produced by ?-pinene ozonolysis. The viscosity is comparable to that of honey at 90% relative humidity (RH), comparable to that of peanut butter at 70% RH and greater than or comparable to that of bitumen for ? 30% RH, implying that the studied SOM ranges from liquid to semisolid/solid at ambient relative humidities. With the Stokes-Einstein relation, the measured viscosities further imply that the growth and evaporation of SOM by the exchange of organic molecules between the gas and condensed phases may be confined to the surface region when RH ? 30%, suggesting the importance of an adsorption-type mechanism for partitioning in this regime. By comparison, for RH ? 70% partitioning of organic molecules may effectively occur by an absorption mechanism throughout the bulk of the particle. Finally, the net uptake rates of semi-reactive atmospheric oxidants such as O3 are expected to decrease by two to five orders of magnitude for a change in RH from 90% to ? 30% RH, with possible implications for the rates of chemical aging of SOM particles in the atmosphere.

  17. Ternary Electrocatalysts for Oxidizing Ethanol to Carbon Dioxide: Making Ir Capable of Splitting C-C bond

    SciTech Connect (OSTI)

    Li, Meng; Cullen, David A; Sasaki, Kotaro; Marinkovic, N.; More, Karren Leslie; Adzic, Radoslav R.

    2013-01-01

    Splitting the C-C bond is the main obstacle to electroxidation of ethanol (EOR) to CO2. We recently demonstrated that the ternary PtRhSnO2 electrocatalyst can accomplish that reaction at room temperature with Rh having a unique capability to split the C-C bond. In this article we report the finding that Ir can be induced to split the C-C bond as a component of the ternary catalyst. We synthesized, characterized and compared the properties of several ternary electrocatalysts. Carbon-supported nanoparticle (NP) electrocatalysts comprising a SnO2 NP core decorated with multi-metallic nanoislands (MM = PtIr, PtRh, IrRh, PtIrRh) were prepared using a seeded growth approach. An array of characterization techniques were employed to establish the composition and architecture of the synthesized MM /SnO2 NPs, while electrochemical and in situ infrared reflection absorption spectroscopy studies elucidated trends in activity and the nature of the reaction intermediates and products. Both EOR reactivity and selectivity towards CO2 formation of several of these MM /SnO2/C electrocatalysts are significantly higher compared to conventional Pt/C and Pt/SnO2/C catalysts. We demonstrate that the PtIr/SnO2/C catalyst with high Ir content shows outstanding catalytic property with the most negative EOR onset potential and reasonably good selectivity towards ethanol complete oxidation to CO2. PtRh/SnO2/C catalysts with a moderate Rh content exhibit the highest EOR selectivity, as deduced from infrared studies.

  18. Lactoferrin inhibits dexamethasone-induced chondrocyte impairment from osteoarthritic cartilage through up-regulation of extracellular signal-regulated kinase 1/2 and suppression of FASL, FAS, and Caspase 3

    SciTech Connect (OSTI)

    Tu, Yihui [Department of Orthopaedics, Yangpu District Central Hospital Affiliated to Tongji University School of Medicine, 450 Tengyue Road, Shanghai (China)] [Department of Orthopaedics, Yangpu District Central Hospital Affiliated to Tongji University School of Medicine, 450 Tengyue Road, Shanghai (China); Xue, Huaming [Department of Orthopaedics, Yangpu District Central Hospital Affiliated to Tongji University School of Medicine, 450 Tengyue Road, Shanghai (China) [Department of Orthopaedics, Yangpu District Central Hospital Affiliated to Tongji University School of Medicine, 450 Tengyue Road, Shanghai (China); Institute of Life Science, College of Medicine, Swansea University, Singleton Park (United Kingdom); Francis, Wendy [Institute of Life Science, College of Medicine, Swansea University, Singleton Park (United Kingdom)] [Institute of Life Science, College of Medicine, Swansea University, Singleton Park (United Kingdom); Davies, Andrew P. [Department of Orthopaedics and Trauma, Moriston Hospital, Swansea (United Kingdom)] [Department of Orthopaedics and Trauma, Moriston Hospital, Swansea (United Kingdom); Pallister, Ian; Kanamarlapudi, Venkateswarlu [Institute of Life Science, College of Medicine, Swansea University, Singleton Park (United Kingdom)] [Institute of Life Science, College of Medicine, Swansea University, Singleton Park (United Kingdom); Xia, Zhidao, E-mail: zhidao.xia@gmail.com [Institute of Life Science, College of Medicine, Swansea University, Singleton Park (United Kingdom)] [Institute of Life Science, College of Medicine, Swansea University, Singleton Park (United Kingdom)

    2013-11-08

    Highlights: •Dex exerts dose-dependant inhibition of HACs viability and induction of apoptosis. •Dex-induced impairment of chondrocytes was attenuated by rhLF. •ERK and FASL/FAS signaling are involved in the effects of rhLF. •OA patients with glucocorticoid-induced cartilage damage may benefit from treatment with rhLF. -- Abstract: Dexamethasone (Dex) is commonly used for osteoarthritis (OA) with excellent anti-inflammatory and analgesic effect. However, Dex also has many side effects following repeated use over prolonged periods mainly through increasing apoptosis and inhibiting proliferation. Lactoferrin (LF) exerts significantly anabolic effect on many cells and little is known about its effect on OA chondrocytes. Therefore, the aim of this study is to investigate whether LF can inhibit Dex-induced OA chondrocytes apoptosis and explore its possible molecular mechanism involved in. MTT assay was used to determine the optimal concentration of Dex and recombinant human LF (rhLF) on chondrocytes at different time and dose points. Chondrocytes were then stimulated with Dex in the absence or presence of optimal concentration of rhLF. Cell proliferation and viability were evaluated using MTT and LIVE/DEAD assay, respectively. Cell apoptosis was evaluated by multi-parameter apoptosis assay kit using both confocal microscopy and flow cytometry, respectively. The expression of extracellular signal-regulated kinase (ERK), FAS, FASL, and Caspase-3 (CASP3) at the mRNA and protein levels were examined by real-time polymerase chain reaction (PCR) and immunocytochemistry, respectively. The optimal concentration of Dex (25 ?g/ml) and rhLF (200 ?g/ml) were chosen for the following experiments. rhLF significantly reversed the detrimental effect of Dex on chondrocytes proliferation, viability, and apoptosis. In addition, rhLF significantly prevented Dex-induced down-regulation of ERK and up-regulation of FAS, FASL, and CASP3. These findings demonstrated that rhLF acts as an anabolic effect on chondrocytes through significantly reversing Dex-induced chondrocytes apoptosis. This study may contribute to further investigating the clinical application of LF on OA.

  19. CHARACTERIZATION THROUGH DATA QUALITY OBJECTIVES AND CERTIFICATION OF REMOTE-HANDLED TRANSURANIC WASTE GENERATOR/STORAGE SITES FOR SHIPMENT TO THE WIPP

    SciTech Connect (OSTI)

    Spangler, L.R.; Most, Wm.A.; Kehrman, R.F.; Gist, C.S.

    2003-02-27

    The Waste Isolation Pilot Plant (WIPP) is operating to receive and dispose of contact-handled (CH) transuranic (TRU) waste. The Department of Energy (DOE) Carlsbad Field Office (CBFO) is seeking approval from the Environmental Protection Agency (EPA) and the New Mexico Environment Department (NMED) of the remote-handled (RH) TRU characterization plan to allow disposal of RH TRU waste in the WIPP repository. In addition, the DOE-CBFO has received approval from the Nuclear Regulatory Commission (NRC) to use two shipping casks for transporting RH TRU waste. Each regulatory agency (i.e., EPA, NMED, and NRC) has different requirements that will have to be met through the use of information collected by characterizing the RH TRU waste. Therefore, the DOE-CBFO has developed a proposed characterization program for obtaining the RH TRU waste information necessary to demonstrate that the waste meets the applicable regulatory requirements. This process involved the development of a comprehensive set of Data Quality Objectives (DQOs) comprising the various regulatory requirements. The DOE-CBFO has identified seven DQOs for use in the RH TRU waste characterization program. These DQOs are defense waste determination, TRU waste determination, RH TRU determination, activity determination, RCRA physical and chemical properties, prohibited item determination, and EPA physical and chemical properties. The selection of the DQOs were based on technical, legal and regulatory drivers that assure the health and safety of the workers, the public, to protect the environment, and to comply with the requirements of the regulatory agencies. The DOE-CBFO also has the responsibility for the certification of generator/storage sites to ship RH TRU mixed waste to the WIPP for disposal. Currently, thirteen sites across the DOE complex are generators of RH TRU waste or store the waste at their location for other generators. Generator/storage site certification involves review and approval of site-specific programmatic documents that demonstrate compliance with the WIPP waste characterization and transportation requirements. Additionally, procedures must be developed to implement programmatic requirements and adequacy of those procedures determined. Finally, on-site audits evaluate the technical and administrative implementation and effectiveness of the operating procedures.

  20. Phenomenology of TeV Right-handed Neutrino and the Dark Matter Model

    E-Print Network [OSTI]

    Kingman Cheung; Osamu Seto

    2004-03-08

    In a model of TeV right-handed (RH) neutrino by Krauss, Nasri, and Trodden, the sub-eV scale neutrino masses are generated via a 3-loop diagram with the vanishing see-saw mass forbidden by a discrete symmetry, and the TeV mass RH neutrino is simultaneously a novel candidate for the cold dark matter. However, we show that with a single RH neutrino it is not possible to generate two mass-square differences as required by the oscillation data. We extend the model by introducing one more TeV RH neutrino and show that it is possible to satisfy the oscillation pattern within the modified model. After studying in detail the constraints coming from the dark matter, lepton flavor violation and the muon anomalous magnetic moment, and the neutrinoless double beta decay, we explore the parameter space and derive predictions of the model. Finally, we study the production and decay signatures of the TeV RH neutrinos at TeV $e^+ e^-/\\mu^+ \\mu^-$ colliders.

  1. Correlation between the extraordinary Hall constant and electrical resistivity minima in Co-rich metallic glasses 

    E-Print Network [OSTI]

    Majumdar, AK; Khatua, PK; Rathnayaka, KDD; Naugle, Donald G.

    2004-01-01

    . INTRODUCTION The Hall resistivity srHd in a crystalline ferromagnet is, for T!Tc, given by1 rH = R0B + m0RsMs, s1d where B is the magnetic induction and m0 is the permeability of free space. The Lorentz force acting on the charge carriers is responsible...- pendicular to the sample plane and so the demagnetization factor N.1. Thus BW =m0fHW applied+ s1?NdMW sg.m0HW applied. rH shows the typical behavior of a ferromagnet for T!Tc =368 K where rH almost saturates beyond a certain B (here 1 T) and varies...

  2. Energy, cost, and CO 2 emission comparison between radiant wall panel systems and radiator systems

    E-Print Network [OSTI]

    Milorad Boji?; Dragan Cvetkovi?; Marko Mileti?; Jovan Maleševi?; Harry Boyer

    2012-12-18

    The main goal of this paper is to evaluate the possibility of application or replacement of radiators with low-temperature radiant panels. This paper shows the comparison results of operations of 4 space heating systems: the low-temperature radiant panel system without any additional thermal insulation of external walls (PH-WOI), the low-temperature radiant panel system with additional thermal insulation of external walls (PH-WI), the radiator system without any additional thermal insulation of external walls (the classical heating system) (RH-WOI), and the radiator system with additional thermal insulation of external walls (RH-WI). The operation of each system is simulated by software EnergyPlus. The investigation shows that the PH-WI gives the best results. The RH-WOI has the largest energy consumption, and the largest pollutant emission. However, the PH-WI requires the highest investment.

  3. Thermal and non-thermal production of dark matter via Z'-portal(s)

    SciTech Connect (OSTI)

    Chu, Xiaoyong; Mambrini, Yann; Quevillon, Jérémie; Zaldívar, Bryan E-mail: yann.mambrini@th.u-psud.fr E-mail: b.zaldivar.m@csic.es

    2014-01-01

    We study the genesis of dark matter in the primordial Universe for representative classes of Z'-portals models. For weak-scale Z' mediators we compute the range of values of the kinetic mixing allowed by WMAP/PLANCK experiments corresponding to a FIMP regime. We show that very small values of ? (10{sup ?12}?RH}, with a weak-scale coupling g{sub D} to ordinary matter. Relic abundance constraints then impose a direct correlation between T{sub RH} and the effective scale ? of the interactions: ? ? 10{sup 3}?10{sup 5} × T{sub RH}. Finally we describe in some detail the process of dark thermalisation and study its consequences on the computation of the relic abundance.

  4. A Mathematical Model for Predicting the Life of PEM Fuel Cell Membranes Subjected to Hydration Cycling

    E-Print Network [OSTI]

    Burlatsky, S F; O'Neill, J; Atrazhev, V V; Varyukhin, A N; Dmitriev, D V; Erikhman, N S

    2013-01-01

    Under typical PEM fuel cell operating conditions, part of membrane electrode assembly is subjected to humidity cycling due to variation of inlet gas RH and/or flow rate. Cyclic membrane hydration/dehydration would cause cyclic swelling/shrinking of the unconstrained membrane. In a constrained membrane, it causes cyclic stress resulting in mechanical failure in the area adjacent to the gas inlet. A mathematical modeling framework for prediction of the lifetime of a PEM FC membrane subjected to hydration cycling is developed in this paper. The model predicts membrane lifetime as a function of RH cycling amplitude and membrane mechanical properties. The modeling framework consists of three model components: a fuel cell RH distribution model, a hydration/dehydration induced stress model that predicts stress distribution in the membrane, and a damage accrual model that predicts membrane life-time. Short descriptions of the model components along with overall framework are presented in the paper. The model was used...

  5. Effect of Hydrogen Passivation on the Electronic Structure of Ionic Semiconductor Nanostructures

    SciTech Connect (OSTI)

    Deng, H. X.; Li, S. S.; Li, J. B.; Wei, S. H.

    2012-05-15

    In theoretical studies of thin film and nanostructured semiconductors, pseudohydrogen (PH) is widely used to passivate the surface dangling bonds. Based on these calculations, it is often believed that nanostructured semiconductors, due to quantum confinement, have a larger band gap than their bulk counterparts. Using first-principles band structure theory calculation and comparing systematically the differences between PH-passivated and real-hydrogen-passivated (RH-passivated) semiconductor surfaces and nanocrystals, we show that, unlike PH passivation that always increases the band gap with respect to the bulk value, RH passivation of the nanostructured semiconductors can either increase or decrease the band gap, depending on the ionicity of the nanocompounds. The differences between PH and RH passivations decreases when the covalency of the semiconductor increases and can be explained using a band coupling model. This observation greatly increases the tunability of nanostructured semiconductor properties, especially for wide-gap ionic semiconductors.

  6. Comparative study of Waste Isolation Pilot Plant (WIPP) transportation alternatives

    SciTech Connect (OSTI)

    Not Available

    1994-02-01

    WIPP transportation studies in the Final Supplement Environmental Impact Statement for WIPP are the baseline for this report. In an attempt to present the most current analysis, this study incorporates the most relevant data available. The following three transportation options are evaluated for the Disposal Phase, which is assumed to be 20 years: Truck shipments, consisting of a tractor and trailer, with three TRUPACT-IIs or one RH-72B; Regular commercial train shipments consisting of up to three railcars carrying up to 18 TRUPACT-IIs or up to six RH-72Bs; Dedicated train shipments consisting of a locomotive, an idle car, railcars carrying 18 TRUPACT-IIs or six RH-72Bs, another idle car, and a caboose or passenger car with an emergency response specialist. No other cargo is carried. This report includes: A consideration of occupational and public risks and exposures, and other environmental impacts; A consideration of emergency response capabilities; and An extimation of comparative costs.

  7. A RhxSy/C Catalyst for the Hydrogen Oxidation and Hydrogen Evolution Reactions in HBr

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Masud, Jahangir; Nguyena, Trung V.; Singh, Nirala; McFarland, Eric; Ikenberry, Myles; Hohn, Keith; Pan, Chun-Jern; Hwang, Bing-Joe

    2015-02-01

    Rhodium sulfide (Rh2S3) on carbon support was synthesized by refluxing rhodium chloride with ammonium thiosulfate. Thermal treatment of Rh2S3 at high temperatures (600°C to 850°C) in presence of argon resulted in the transformation of Rh2S3 into Rh3S4, Rh17S15 and Rh which were characterized by TGA/DTA, XRD, EDX, and deconvolved XPS analyses. The catalyst particle size distribution ranged from 3 to 12 nm. Cyclic voltammetry and rotating disk electrode measurements were used to evaluate the catalytic activity for hydrogen oxidation and evolution reactions in H2SO4 and HBr solutions. The thermally treated catalysts show high activity for the hydrogen reactions. The exchangemore »current densities (io) of the synthesized RhxSy catalysts in H2-saturated 1M H2SO4 and 1M HBr for HER and HOR were 0.9 mA/cm2 to 1.0 mA/cm2 and 0.8 to 0.9 mA/cm2, respectively. The lower io values obtained in 1M HBr solution compared to in H2SO4 might be due to the adsorption of Br- on the active surface. Stable electrochemical active surface area (ECSA) of RhxSy catalyst was obtained for CV scan limits between 0 V and 0.65 V vs. RHE. Scans with upper voltage limit beyond 0.65 V led to decreased and unreproducible ECSA measurements.« less

  8. Material synthesis and hydrogen storage of palladium-rhodium alloy.

    SciTech Connect (OSTI)

    Lavernia, Enrique J.; Yang, Nancy Y. C.; Ong, Markus D.

    2011-08-01

    Pd and Pd alloys are candidate material systems for Tr or H storage. We have actively engaged in material synthesis and studied the material science of hydrogen storage for Pd-Rh alloys. In collaboration with UC Davis, we successfully developed/optimized a supersonic gas atomization system, including its processing parameters, for Pd-Rh-based alloy powders. This optimized system and processing enable us to produce {le} 50-{mu}m powders with suitable metallurgical properties for H-storage R&D. In addition, we studied hydrogen absorption-desorption pressure-composition-temperature (PCT) behavior using these gas-atomized Pd-Rh alloy powders. The study shows that the pressure-composition-temperature (PCT) behavior of Pd-Rh alloys is strongly influenced by its metallurgy. The plateau pressure, slope, and H/metal capacity are highly dependent on alloy composition and its chemical distribution. For the gas-atomized Pd-10 wt% Rh, the absorption plateau pressure is relatively high and consistent. However, the absorption-desorption PCT exhibits a significant hysteresis loop that is not seen from the 30-nm nanopowders produced by chemical precipitation. In addition, we observed that the presence of hydrogen introduces strong lattice strain, plastic deformation, and dislocation networking that lead to material hardening, lattice distortions, and volume expansion. The above observations suggest that the H-induced dislocation networking is responsible for the hysteresis loop seen in the current atomized Pd-10 wt% Rh powders. This conclusion is consistent with the hypothesis suggested by Flanagan and others (Ref 1) that plastic deformation or dislocations control the hysteresis loop.

  9. Applicability of Density Functional Theory in Reproducing Accurate Vibrational Spectra of Surface Bound Species

    SciTech Connect (OSTI)

    Matanovic, Ivana; Atanassov, Plamen; Kiefer, Boris; Garzon, Fernando; Henson, Neil J.

    2014-10-05

    The structural equilibrium parameters, the adsorption energies, and the vibrational frequencies of the nitrogen molecule and the hydrogen atom adsorbed on the (111) surface of rhodium have been investigated using different generalized-gradient approximation (GGA), nonlocal correlation, meta-GGA, and hybrid functionals, namely, Perdew, Burke, and Ernzerhof (PBE), Revised-RPBE, vdW-DF, Tao, Perdew, Staroverov, and Scuseria functional (TPSS), and Heyd, Scuseria, and Ernzerhof (HSE06) functional in the plane wave formalism. Among the five tested functionals, nonlocal vdW-DF and meta-GGA TPSS functionals are most successful in describing energetics of dinitrogen physisorption to the Rh(111) surface, while the PBE functional provides the correct chemisorption energy for the hydrogen atom. It was also found that TPSS functional produces the best vibrational spectra of the nitrogen molecule and the hydrogen atom on rhodium within the harmonic formalism with the error of 22.62 and 21.1% for the NAN stretching and RhAH stretching frequency. Thus, TPSS functional was proposed as a method of choice for obtaining vibrational spectra of low weight adsorbates on metallic surfaces within the harmonic approximation. At the anharmonic level, by decoupling the RhAH and NAN stretching modes from the bulk phonons and by solving one- and two-dimensional Schr€odinger equation associated with the RhAH, RhAN, and NAN potential energy we calculated the anharmonic correction for NAN and RhAH stretching modes as 231 cm21 and 277 cm21 at PBE level. Anharmonic vibrational frequencies calculated with the use of the hybrid HSE06 function are in best agreement with available experiments.

  10. An Experimental Method for Determining the Time Constants of Capacitive Thin-Film Polymer Humidity sensors at Various Duct Air Velocities 

    E-Print Network [OSTI]

    Dooley, B.; O'Neal, D.

    2008-01-01

    of capacitive thin-jïlm polymer humidity sensors to step changes in humidity and temperature as a function of air velocity was investigated. Two duct-mounted humidity sensors (designated Candidate X and Candidate Y) from two manufacturers, each with thin... changes in RH and temperature over a range of air velocities. Duct air velocities ofO (stili air). 200. 500. 800, and UOOft/min (0. 1.0, 2.5. 4.1, and 5.6 m/s) were considered along with .step changes in RH of 20%-40% and step changes in air temperature...

  11. Predicting the Performance of Edge Seal Materials for PV (Presentation)

    SciTech Connect (OSTI)

    Kempe, M.; Panchagade, D.; Dameron, A.; Reese, M.

    2012-03-01

    Edge seal materials were evaluated using a 100-nm film of Ca deposited on glass and laminated to another glass substrate. As moisture penetrates the package it converts the Ca metal to transparent CaOH2 giving a clear indication of the depth to which moisture has entered. Using this method, we have exposed test samples to a variety of temperature and humidity conditions ranging from 45C and 10% RH up to 85C and 85% RH, to ultraviolet radiation and to mechanical stress. We are able to show that edge seal materials are capable of keeping moisture away from sensitive cell materials for the life of a module.

  12. Electronic structures of transition metal to hydrogen bonds: oxidative addition of dihydrogen to a square planar rhodium complex and quantum mechanical prediction of the geometry of a metal hydride 

    E-Print Network [OSTI]

    Halpin, Carolyn F.

    1986-01-01

    CI(CO)(PHs)z by Hz addition yields two isomeric products. The possible pathways of approach for the Hz upon the Rh complex were studied and analyzed. The results of the study showed that the controlling factor governing the most feasible approach... for the activation of hydrogen by RhC1(PHs)s. " The purpose of his study was not to discuss the path of reaction, but to sort out the factors accounting for its feasibility. He felt the activation of the hydrogen could be due to two influences: (1) the transfer...

  13. Economizer Control Using Mixed Air Enthalpy 

    E-Print Network [OSTI]

    Feng, J.; Liu, M.; Pang, W.

    2007-01-01

    121110 2 8 32)( )( (12) () () 2 )( 1 )(62198.0444.01061 dws dws tpp tpt p h ? ×?×+?= ? ? (13) Figure 3(a) shows the uncertainty in enthalpy vs measured enthalpy at different relative humidity (RH) and temperatures (DB-Temp). It is based...%~+10%, the resulting energy consumption effect ranges from 1.2% ~0.8%. Other parameters’ uncertainties are constant based on Table 4. The positive uncertainty in RH results in higher enthalpy value, which equals to the real enthalpy plus enthalpy uncertainty...

  14. Magnetic order in the frustrated Ising-like chain compound Sr3NiIrO6 E. Lefranois,1, 2, 3,

    E-Print Network [OSTI]

    Boyer, Edmond

    in CsCoCl3 for instance3 . The most studied compound in the frustrated regime is Ca3Co2O6 because of its show that Ca3CoRhO6 5 , Sr3CoIrO6 6 , Sr3NiRhO6 7 and Sr3NiIrO6 6,8,9 have a similar behavior to Ca3Co2 of their unconventional magnetic properties due to the interplay between low dimensionality, magnetic frustration

  15. Fresnel Reflection 9.0.3 polarization

    E-Print Network [OSTI]

    Palffy-Muhoray, Peter

    Chapter 9 Fresnel Reflection 9.0.3 polarization: iE rE tE i r t 1 2 iH rH tH iE rE tE i r t 1 2 i that n1 sin i = n2 sin t (9.2) 45 #12;46 CHAPTER 9. FRESNEL REFLECTION Boundary conditions iH rH tH #12;48 CHAPTER 9. FRESNEL REFLECTION and here Ei + Er = Et (9.16) or Hi Z-1 1 + Hr Z-1 1

  16. Implications of the Diboson Excess for Neutrinoless Double Beta Decay and Lepton Flavor Violation in TeV Scale Left Right Symmetric Model

    E-Print Network [OSTI]

    Awasthi, Ram Lal; Mitra, Manimala

    2015-01-01

    Inspired by the recent diboson excess observed at the LHC and possible interpretation within a TeV-scale Left-Right symmetric framework, we explore its implications for low-energy experiments searching for lepton number and flavor violation. Assuming a simple Type-II seesaw mechanism for neutrino masses, we show that for the right-handed (RH) gauge boson mass and coupling values required to explain the LHC anomalies, the RH contribution to the lepton number violating process of neutrinoless double beta decay ($0\

  17. Microwave radiative transfer in the mixed-phase regions of tropical rainfall 

    E-Print Network [OSTI]

    Jin, Kyoung-Wook

    2001-01-01

    /h ' ~ M RR 2e~/h Rh e Rh R J m/l RR 1 10 0 1 2 3 4 5 6 D (mm) 10' 0 1 2 3 4 5 6 D (mm) Figure g. Analysis of drop size distribution (Aug 23 1999; stratiform rainfall case). a) just below the FL, b) below melting layer (bright-band region). 24..., the simplified RTM (Wilheit and Chang 1980) was applied to one of the stratiform rainfall cases (Aug 28 1999) in the analysis. As mentioned in the previous Chapter, the other case (Aug 23 1999) was excluded because there was no microphysical observation ol...

  18. Reactivity and stability of platinum and platinum alloy catalysts toward the oxygen reduction reaction 

    E-Print Network [OSTI]

    Calvo, Sergio Rafael

    2009-05-15

    Density functional theory (DFT) is used to study the reactivity of Pt and Pt-M (M: Pd, Co, Ni, V, and Rh) alloy catalysts towards the oxygen reduction reaction (ORR) as a function of the alloy overall composition and surface atomic distribution...

  19. PROCEDURES FOR ALLOCATION AND AGGREGATION OF RESOURCES

    E-Print Network [OSTI]

    Laughlin, Robert B.

    Chapter AA PROCEDURES FOR ALLOCATION AND AGGREGATION OF RESOURCES By Ronald R. Charpentier, T.......................................................................................................AA-7 Appendix 1 Aggregation of Undiscovered Oil, Gas, and NGL Volumes Of Regions to World Total Monte RH. The separate reporting of onshore versus offshore undiscovered resources is important to economic

  20. SPECTROSCOPIC DETERMINATION OF MASS FOR A SAMPLE OF DAO WHITE DWARFS

    E-Print Network [OSTI]

    Burleigh, Matt

    , Leicester LE1 7RH, UK J. B. HOLBERG AND D. SING Lunar and Planetary Laboratory, University of Arizona are a group of white dwarfs that show both hydrogen and helium in their spectra. Their origin could be explained as an intermediate step be- #12; 2 tween the helium dominated DOs and the hydrogen dominated DAs

  1. arXiv:pending/3017199v13Oct2005Mon. Not. R. Astron. Soc. 000, 19 (2004) Printed 3 October 2005 (MN LaTEX style file v2.2) A search for binarity using FUSE observations of DAO white dwarfs

    E-Print Network [OSTI]

    Burleigh, Matt

    2004-01-01

    , University of Leicester, University Road, Leicester LE1 7RH 2Lunar and Planetary Laboratory, University and helium lines in their optical spectra, in contrast to the more common DAs, which exhibit only hydrogen forces appear to be too low to support sufficient quantities of helium to be able to produce the observed

  2. Mon. Not. R. Astron. Soc. 000, 115 (2004) Printed 23 June 2005 (MN LaTEX style file v2.2) Heavy element abundances in DAO white dwarfs measured from

    E-Print Network [OSTI]

    Burleigh, Matt

    2004-01-01

    of Leicester, University Road, Leicester LE1 7RH ¾Lunar and Planetary Laboratory, University of Arizona, Tucson models that adopted the temperatures, gravities and helium abundances determined from both optical was identified in the nitrogen, oxygen, iron or nickel abundances, and no dependence on gravity or helium

  3. A Brief Comment on Post inversion formula for the Laplace transform

    E-Print Network [OSTI]

    Jose Javier Garcia MOreta

    2007-03-06

    In this paper we comment the Post inversion formula for Laplace transform, and its possible application to the branch of Analytic Number theory (Arithmetical functions, RH and PNT), involving a condition in the form of iterated limit to calculate the Riemann Hypothesis.

  4. Extratropical Dry-Air Intrusions into the West African Monsoon Midtroposphere: An Important Factor for the Convective Activity over the Sahel

    E-Print Network [OSTI]

    Roca, Rémy

    Extratropical Dry-Air Intrusions into the West African Monsoon Midtroposphere: An Important Factor during July to August 1992. The approach documents both the moisture content and the origin of the air analysis reveals that very dry air patches (RH 5%) are located in the immediate midtropospheric environment

  5. STUDIES ON THE GOES-R HYPERSPECTRAL ENVIRONMENTAL SUITE (HES) ON , Timothy, J. Schmit

    E-Print Network [OSTI]

    Li, Jun

    resolution infrared radiances from the Hyperspectral Environmental Suite (HES) on Geostationary Operational with capabilities from current sensors. Corresponding author address: Jun Li, Cooperative Institute and 2 km relative humidity (RH) rms were created to evaluate the retrieval difference between LW + LMW

  6. RICHARD H. GRANT, Professor of Agro-micrometeorology, Department of Agronomy, Purdue University B.S. 1977 Duke University (Distinction) 1974-1977

    E-Print Network [OSTI]

    Jackson, Scott A.

    Management Association International Solar Energy Society Gamma Sigma Delta honorary agriculture research;Research funding Total research funding (as of 2010) of $15.0M, of which $6.3M is/ has been under my control. Current funding for my laboratory (2010): $110K. Refereed Journal Papers 1. Grant, R.H. 1983

  7. Evaluation of Polymer-Supported Rhodium Catalysts in 1-Octene Hydroformylation in Supercritical Carbon Dioxide

    E-Print Network [OSTI]

    Abdou, Hanan E.

    Evaluation of Polymer-Supported Rhodium Catalysts in 1-Octene Hydroformylation in Supercritical Carbon Dioxide Zulema K. Lopez-Castillo, Roberto Flores, Ibrahim Kani,,§ John P. Fackler Jr., and Aydin using a Rh-based catalyst. The catalyst is attached to a polymer backbone that has fluoroacrylate

  8. Anterior Pituitary Responsiveness of the Cyclic and Seasonally Anovulatory Mare to Continuous Infusions of Gonadotropin-Releasing Hormone 

    E-Print Network [OSTI]

    Velez Jaramillo, Isabel C.

    2010-07-14

    In Experiment 1, 12 cyclic mares were assigned randomly to one of two groups (n = 6/group): 1) Control, saline; and 2) GnRH, 100 mu g/h. Between 3 and 6 d after ovulation (Day 0), Alzet osmotic minipumps (Model 2ML1) ...

  9. Solar-assisted hydrogen generation by photoelectrocatalysis. Annual report, 1 October 1983-30 September 1984

    SciTech Connect (OSTI)

    Sammells, A.F.; Wessels, B.W.; Raccah, P.M.; Cook, R.L.; Ang, P.G.P.

    1984-12-01

    This research effort is directed towards gaining basic insight into those factors which will help to improve the efficiency of hydrogen generation in photoelectrochemical cells. Emphasis of the program is on photoelectrode surface modification as an approach to improve such efficiencies. Both electrooptical and photoelectrochemical techniques are being used to characterize photoelectrode surfaces and includes photocapacitance spectroscopy and automatic scanning ellipsometry techniques. For surface modified p-InP the dependency of exchange current density as measured before and after the inception of hydrogen evolution has been examined as a function of incident light intensity. This was performed using the surface modifications Co/Pt, Ru/Pt, Rh/Pt, Ru, Pt, Rh and Co. Experimental results indicated that a progressively lower applied cathodic bias is required for hydrogen evolution in the order Ru/Pt < Rh/Pt < Co/Pt < Rh < Pt < Co < Ru < unmodified. Photoelectrode kinetics on alpha-Fe2O3 based photoanodes can be enhanced by the incorporation of platinum within the thermally grown oxide. A model is evolving which invokes the role surface states play in this order and in determining the shape of the experimental io vs incident light flux curves. The overall solar efficiency, as power savings for photoelectrochemical cells using a p-InP photocathode surface modified by sequential deposited Co and Pt and a platinum counter electrode, have been increased to 16% in alkaline electrolytes by depolarization of the counter electrode with monosaccharides.

  10. NOAA PMEL Station Chemistry Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Quinn, Patricia

    Submicron and supermicron samples are analyzed by ion chromatography for Cl-, NO3-, SO4-2, Na+, NH4+, K+, Mg2+, and Ca+2. The analysis of MSA-, Br-, and oxalate has been added to some stations. Samples also are analyzed for total mass by gravimetric analysis at 55 +/- 5% RH.

  11. Unusual Reaction of -Hydroxy r-Diazo Carbonyl Compounds with Cl3CCN/NaH

    E-Print Network [OSTI]

    Wang, Jianbo

    Wu, Daming Du, and Jianbo Wang*, Key Laboratory of Bioorganic Chemistry and Molecular Engineering-diazo carbonyl compounds.1,2 The migrating group can be a hydride, aryl, or acetoxy group. The Rh2(OAc)4-mediatedV. 1994, 94, 1091. (2) For examples of 1,2-hydride migration, see: (a) Taber, D. F.; Herr, R. J.; Pack, S

  12. DOI: 10.1002/cctc.201300401 New Insights into the Oxidative Coupling of Methane from

    E-Print Network [OSTI]

    Senkan, Selim M.

    DOI: 10.1002/cctc.201300401 New Insights into the Oxidative Coupling of Methane from Spatially coupling of methane (OCM) is a high-temperature process involving the transformation of methane into ethane oxidation of methane to produce CO and H2 in a Pt- and Rh-coated a-Al2O3 foam.[11­13] Experiments were

  13. ASSESSMENT HIERARCHY AND INITIAL PROVINCE By T. R. Klett, James W. Schmoker, and Thomas S. Ahlbrandt

    E-Print Network [OSTI]

    Laughlin, Robert B.

    entities for which assessments of undiscovered oil and gas volumes were made. These are delineated withinChapter RH ASSESSMENT HIERARCHY AND INITIAL PROVINCE RANKING By T. R. Klett, James W. Schmoker or on this symbol in the toolbar to return. U.S. GEOLOGICAL SURVEY WORLD PETROLEUM ASSESSMENT 2000-- DESCRIPTION

  14. A TWODIMENSIONAL MOVING FINITE ELEMENT METHOD WITH LOCAL REFINEMENT BASED ON A POSTERIORI ERROR

    E-Print Network [OSTI]

    Cao, Weiming

    and Flaherty [1] to the two­dimensional case, where clusters of mesh points are built up and moved (middle), and rh­refinement with N = 541 yields e L2() = 1.57E-2 (right). While the r­method wastes too

  15. Coenzyme Q10 prevents insulin signaling dysregulation and inflammation prior to development of insulin resistance in male offspring of a rat model of poor maternal nutrition and accelerated postnatal growth

    E-Print Network [OSTI]

    Tarry-Adkins, Jane; Fernandez-Twinn, Denise; Madsen, Ralitsa; Chen, Jian-Hua; Carpenter, Asha; Hargreaves, Iain; McConnell, Josie; Ozanne, Susan

    2015-07-27

    inflammatory markers in patients with multiple sclerosis: a double blind, placebo, controlled randomised clinical trial. Nutr Neurosci. 2015;18:169–176. 41. Tarry-Adkins JL, Chen JH, Smith NS, Jones RH, Cherif H, Ozanne SE. Poor maternal nutrition followed...

  16. Human Based Cost from Persistent Homology for Bipedal Walking

    E-Print Network [OSTI]

    Ames, Aaron

    of California, Berkeley Texas A&M University Berkeley, CA 94720 College Station, TX 77843 {ramv in this question is the desire to quantify how human-like a certain domain breakdown truly is. Heel-LiftT Lift 46% Heel LiftToe-Lift [ , ]lh lt 19%17% [ , ]lh lt 18% Heel-StrikeToe-Strike [ ]lt[ , , ]lt rh rt Toe

  17. Humidity effects on wire insulation breakdown strength.

    SciTech Connect (OSTI)

    Appelhans, Leah

    2013-08-01

    Methods for the testing of the dielectric breakdown strength of insulation on metal wires under variable humidity conditions were developed. Two methods, an ASTM method and the twisted pair method, were compared to determine if the twisted pair method could be used for determination of breakdown strength under variable humidity conditions. It was concluded that, although there were small differences in outcomes between the two testing methods, the non-standard method (twisted pair) would be appropriate to use for further testing of the effects of humidity on breakdown performance. The dielectric breakdown strength of 34G copper wire insulated with double layer Poly-Thermaleze/Polyamide-imide insulation was measured using the twisted pair method under a variety of relative humidity (RH) conditions and exposure times. Humidity at 50% RH and below was not found to affect the dielectric breakdown strength. At 80% RH the dielectric breakdown strength was significantly diminished. No effect for exposure time up to 140 hours was observed at 50 or 80%RH.

  18. Efficient Region-Based Memory Management for Resource-limited Real-Time Embedded Systems

    E-Print Network [OSTI]

    Salagnac, Guillaume

    , the implementation of efficient garbage collectors (GC) is furthermore hindered by hardware limitations, and embedded collectors can be found in [3]. An appealing solution to the dynamic memory collection issue is to allocate supported by projects DYNAMO (Min. Research, France) and MADEJA (Rh^one-Alpes, France). 1 http://java.sun

  19. Population Structure of the Chenchu and Other South Indian Tribal Groups: Relationships between Genetic, Anthropometric, Dermatoglyphic, Geographic, and Linguistic Distances

    E-Print Network [OSTI]

    Sirajuddin, S. M.; Duggirala, R.; Crawford, Michael H.

    1994-10-01

    We describe the genetic structure and interrelationships of nine south Indian tribal groups (seven from Andhra Pradesh and two from the adjoining states of Tamil Nadu and Kerala) using seven polymorphic loci (ABO, MN, RH, PGM, ACP, PGD, and LDH). R...

  20. Zweben APS_2007_12.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    X-Point of C-Mod S.J. Zweben, J.L. Terry, B. LaBombard, M. Greenwald, O. Grulke, R.H. Cohen, D.D. Ryutov, M. Umansky, J. Krommes, T. Stoltzfus-Dueck, D.P. Stotler PPPL, MIT,...

  1. Water Transport in Hydrophilic Channels of Nafion (DMR 0819860)

    E-Print Network [OSTI]

    Petta, Jason

    (RH) that open up the ion channels for optimal proton transport. Nafion, a polymer used for fuel cells Benziger, Princeton University Sr Fuel cells convert chemical energy to electrical energy by transporting protons through ion conducting channels in polymer membranes. Improving proton conduction will make fuel

  2. Title 40 CFR Part 191 Subparts B and C

    E-Print Network [OSTI]

    Compliance Recertification Application 2009 Elements and Chemical Compounds Am americium CO2 carbon dioxide-4 27.6.2 LANL Remote-Handled TRU Waste Visual Examination Data Verification Peer Review Assurance Program Document RH-TRU remote-handled transuranic RSI Institute for Regulatory Science SNL Sandia

  3. The spatial organization and microbial community structure of an epilithic biofilm

    E-Print Network [OSTI]

    Cutler, Nick A.; Chaput, Dominique L.; Oliver, Anna E.; Viles, Heather A.

    2014-12-15

    prediction theories to integration within an ecological framework. pkNl1sTii 10: 537 995-1015. 538 McNamara CJ & Mitchell R (2005) Microbial deterioration of historic stone. G4N2i1pkNl1539 p23:4N2 3: 445-451. 540 Nilsson RH, Veldre V, Hartmann M 1Ti1tle...

  4. 11704 J. Am. Chem. SOC.1995,117, 11704-11709 Regiochemical Selectivity in the Carbon-Sulfur Bond Cleavage

    E-Print Network [OSTI]

    Jones, William D.

    11704 J. Am. Chem. SOC.1995,117, 11704- 11709 Regiochemical Selectivity in the Carbon- Sulfur Bond the Department of Chemistry, University of Rochester, Rochester, New York 14627 Received May 15,1995. Revised Manuscript Received September 11, 1995@ Abstract: Thermolysis of (CsMes)Rh(PMes)(Ar)(H) (Ar= Ph or 3,5-xylyl

  5. Synthesis, structure and spectroscopic investigations of luminescent heterobimetallic gold(I)-Rhodium(I) species

    E-Print Network [OSTI]

    Dempsey, Jillian Lee

    2005-01-01

    A novel, three-coordinate gold(I) dimer, Au2(tfepm)3Cl2 (la, lb), was synthesized and structurally characterized. Four gold(I)-rhodium(I) heterobimetallic complexes, AuIRh'(tBuNC)2(-dppm)2C12 (2), Au'Rh'(tBuNC)2(u-dmpm)2Cl2 ...

  6. Neuropeptidase activity is down-regulated by estradiol in steroid-sensitive regions of the hypothalamus in female mice

    E-Print Network [OSTI]

    of the hypothalamus in female mice Lisa A. Bruce a , Nicole E. Cyr a,1 , Jana W. Qiao a , Christa C. DeFries a , Marc Hypothalamus GnRH Prolyl endopeptidase Ventromedial nucleus a b s t r a c t Thimet oligopeptidase (TOP of the ventrolmedial nucleus of the hypothalamus (VMHvl) when animals are treated with estradiol (Cyr et al., 2010

  7. Brief Communication: Menarche is Related to Fat Distribution

    E-Print Network [OSTI]

    Cosmides, Leda

    convey information about fat distribution to the hypothalamus during puberty. Fat distribution may hormone (GnRH) pulse generator in the hypothalamus, but the age at menarche varies widely and is delayed in the hypothalamus via leptin receptors in KiSS-1 neurons (Smith et al., 2006). Leptin is required for puberty

  8. The testosterone-dependent and independent transcriptional networks in the hypothalamus of Gpr54 and Kiss1 knockout male mice are not fully equivalent

    E-Print Network [OSTI]

    Prentice, Leah M.; d'Anglemont de Tassigny, Xavier; McKinney, Steven; Ruiz de Algara, Teresa; Yap, Damian; Turashvili, Gulisa; Poon, Steven; Sutcliffe, Margaret; Allard, Pat; Burleigh, Angela; Fee, John; Huntsman, David G.; Colledge, William H.; Aparicio, Samuel

    2011-04-28

    Abstract Background Humans and mice with loss of function mutations in GPR54 (KISS1R) or kisspeptin do not progress through puberty, caused by a failure to release GnRH. The transcriptional networks regulated by these proteins in the hypothalamus...

  9. Fireside Corrosion USC Steering

    SciTech Connect (OSTI)

    G. R. Holcomb; J. Tylczak

    2011-09-07

    Oxy-Fuel Fireside Research goals are: (1) Determine the effect of oxy-fuel combustion on fireside corrosion - (a) Flue gas recycle choice, Staged combustion ramifications, (c) JCOAL Collaboration; and (2) Develop methods to use chromia solubility in ash as an 'ash corrosivity' measurement - (a) Synthetic ashes at first, then boiler and burner rig ashes, (b) Applicable to SH/RH conditions.

  10. Herbivory in the Previous Generation Primes Plants for Enhanced Insect Resistance1[W][OA

    E-Print Network [OSTI]

    Agrawal, Anurag

    Herbivory in the Previous Generation Primes Plants for Enhanced Insect Resistance1[W][OA] Sergio than on control plants, and persisted for two generations in Arabidopsis. Arabidopsis mutants University, Ithaca, New York 14853 (S.R., R.H., A.A.A.); Boyce Thompson Institute for Plant Research, Ithaca

  11. On the occurrence of Radio Halos in galaxy clusters - Insight from a mass-selected sample

    E-Print Network [OSTI]

    Cuciti, V; Brunetti, G; Dallacasa, D; Kale, R; Ettori, S; Venturi, T

    2015-01-01

    Giant radio halos (RH) are diffuse Mpc-scale synchrotron sources detected in a fraction of massive and merging galaxy clusters. An unbiased study of the statistical properties of RHs is crucial to constrain their origin and evolution. We aim at investigating the occurrence of RHs and its dependence on the cluster mass in a SZ-selected sample of galaxy clusters, which is as close as possible to be a mass-selected sample. Moreover, we analyse the connection between RHs and merging clusters. We select from the Planck SZ catalogue (Planck Collaboration XXIX 2014) clusters with $M\\geq 6\\times10^{14} M_\\odot$ at z=0.08-0.33 and we search for the presence of RHs using the NVSS for z<0.2 and the GMRT RH survey (GRHS, Venturi et al. 2007, 2008) and its extension (EGRHS, Kale et al. 2013, 2015) for 0.2RH clusters are merging systems while the majority of clusters without RH are relaxed, thus supp...

  12. RESEARCH OR TEACHING INVOLVING ANIMALS

    E-Print Network [OSTI]

    Victoria, University of

    Page 1 RESEARCH OR TEACHING INVOLVING ANIMALS University Policy No: RH8110 Classification: Research Approving Authority: Vice-President Research Effective date: June, 2014 Supersedes: December, 2010 Last for Conducting Research or Teaching Involving Animals Animal Care Committee Terms of Reference PURPOSE 1

  13. Supplement of Atmos. Chem. Phys., 15, 20312049, 2015 http://www.atmos-chem-phys.net/15/2031/2015/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    such as wind and temperature every 1 or 3 h. These data can be accessible via ftp://ftp.ncdc.noaa.gov/pub/data/noaa/. To evaluate the meteorological fields produced by Weather Research and Forecasting (WRF), five meteorological m (RH2), wind speed at 10 m (WS10), wind direction at 10 m (WD10), and daily mean precipitation

  14. Atmos. Chem. Phys., 13, 68076843, 2013 www.atmos-chem-phys.net/13/6807/2013/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    Research and Forecast model (WRF)/Polyphemus and WRF with chemistry and the Model of Aerosol Dynamics, Reac), specific humidity at 2 m (Q2), relative humidity at 2 m (RH2), wind speed at 10 m (WS10), wind direction statistics. The vertical profiles of temperature, dew points, and wind speed/direction are also evaluated

  15. Evolution of Structure-Reactivity Correlations for the Hydrogen Abstraction Reaction by Hydroxyl Radical and Comparison with that by Chlorine Atom

    SciTech Connect (OSTI)

    Poutsma, Marvin L

    2013-01-01

    A structure-reactivity correlation for the reaction (HO + HCR3 HOH + CR3 ) has been formulated: log k298(per H) = 0.000630 rH2 0.151 rH 1.056 F 1.053 R 21.26 (r2 = 0.885; n = 70; mean unsigned deviation = 0.29 log units), where rH is the reaction enthalpy and F and R represent the dissection of Hammett s para constant into its field/inductive and resonance effects, and compared for the analogous case for Cl (ref 1). Although more exothermic, the dependence of HO on rH is somewhat greater than Cl . However the dependence on F and R is much less, suggestive of less charge separation in the transition state for the less electronegative HO . The range of k(OH) is significantly less than that of Cl , i.e., it is less dependent on substrate structure. Yet a cross-over exists such that k(Cl) > k(HO) predominates for more reactive cases whereas k(Cl) < k(OH) characterizes the less reactive. The Arrhenius parameters reveal that this cross-over results from a change in {E(Cl) E(OH)} from negative to positive. In contrast, whereas the A factors for both increase significantly as reactivity increases, {A(Cl) / A(OH)} always exceeds unity.

  16. Korean Chem. Eng. Res., Vol. 42, No. 3, June, 2004, pp. 345-354 Poly(3-Hydroxybutyrate)

    E-Print Network [OSTI]

    , aromatics pheromones chiral building blocks[1-4]. (R)-3-hydroxybutyrate (CH3CHOHCH2COOR, R=H, Na, alkyl : Chloroform PHB, 9.16; 0.2 N NaOH PHB, 3.38; methanol, 0.24; chloroform, 0.70; 1,2-dichloroethane, 1.00;, 0

  17. Late Mesozoic to Early Cenozoic components of vertical separation across the MbreTrbndelag Fault Complex, Norway

    E-Print Network [OSTI]

    Torsvik, Trond Helge

    Complex, Norway T.F. Redfielda,*, A. Braathenb , R.H. Gabrielsenb,1 , P.T. Osmundsena , T.H. Torsvika,c , P.A.M. Andriessend,2 a Center for Geodynamics, Geological Survey of Norway, N-7491 Trondheim, Norway-5007, Bergen c Institute for Petroleum Technology and Applied Geophysics, NTNU, N-7491, NTNU (Norway

  18. 8 References Agee, J.K. 1993. Fire ecology of Pacific Northwest forests. Island Press, Washington, D.C.

    E-Print Network [OSTI]

    , Washington, D.C. Altman, B. 2000. Conservation strategy for landbirds of the east-slope of the Cascade Mountains in Oregon and Washington. Oregon-Washington Partners in Flight. Anderson, M., P. Bourgeron, M. M.S. Thesis, Washington State University, Pullman. WA. Barrett, R.H. 1980. Mammals of California oak

  19. Singular thin viscous sheet Arezki Boudaoud1

    E-Print Network [OSTI]

    dissi- pation h3 /3), being the bending modulus; a stretching shearing deformation has an energy (R/h)2- cous sheet. Thin elastic films, when deformed, suffer two types of deformations: stretching and bending 16 . It is easy to bend a thin elastic sheet and it is difficult to stretch it. Energetically

  20. MNRAS 435, 27532763 (2013) doi:10.1093/mnras/stt1369 Advance Access publication 2013 September 21

    E-Print Network [OSTI]

    Baes, Maarten

    2013-01-01

    .26. For sources for which there is prior information that the H-ATLAS: estimating redshifts of Herschel sources from sub-mm fluxes E. A. Pearson,1, Keble Road, Oxford OX1 3RH, UK 17IRAM, Institut de Radio Astronomie Millimtrique, 300 rue de la Piscine

  1. INRIA, Evaluation of Theme Robotique Project-team e-Motion

    E-Print Network [OSTI]

    Laugier, Christian

    INRIA, Evaluation of Theme Robotique Project-team e-Motion March 2009 Project-team title : e-Motion Scientific leader : Christian Laugier Research center : INRIA Grenoble Rh^one-Alpes Common project 4 1 #12;Changes in staff Number of scientific staff that joined or left the project-team during

  2. ERK Signaling in the Pituitary Is Required for Female But Not Male Fertility

    E-Print Network [OSTI]

    ERK Signaling in the Pituitary Is Required for Female But Not Male Fertility Stuart P. Bliss. Several studies suggest that ERK1 and -2 are essential modulators of hypothalamic GnRH-mediated regulation-specific depletion of ERK1 and 2 and examined a range of physiological parameters including fertility. We find

  3. IN-PLANE DIMENSIONAL STABILITY OF THREE-LAYER ORIENTED STRANDBOARD1

    E-Print Network [OSTI]

    of wood-based materials has always been de- manded since changes in the relative humidity (RH. It has been widely stud- ied by Jorgensen and Ode11 (1961), Johnson (1964), Halligan (1970), Halligan(11. 2002. pp. 77-95 1' 2002 hy thc Society of Wood Sc~rncrand Technology #12;78 WOOD AND FIBER SCIENCE

  4. Atmos. Chem. Phys., 7, 38113821, 2007 www.atmos-chem-phys.net/7/3811/2007/

    E-Print Network [OSTI]

    Stanier, Charlie

    Atmos. Chem. Phys., 7, 3811­3821, 2007 www.atmos-chem-phys.net/7/3811/2007/ © Author(s) 2007: 1) Low NOx, dark, and dry conditions, 2) Low NOx, UV, and dry conditions, 3) Low NOx, dark, and high RH conditions, 4) High NOx, dark, and dry conditions, 5) High NOx, UV, and dry conditions. According

  5. Zeolite Membrane Water Vapor Separation for Building Air-Conditioning and Ventilation Systems 

    E-Print Network [OSTI]

    Tanskyi, Oleksandr

    2015-07-17

    -AR0000138 “High-efficiency, on-line membrane air dehumidifier enabling sensible cooling for warm and humid climates”. 2. Naval Facilities Engineering Command (NAVFAC), Pacific Northwest National Laboratory (PNNL), and Advanced Research Projects Agency... Outdoor air PC Polycarbonate PDMS Polydimethylsiloxane PE Polyethylene PES Polyethersulphone PNNL Pacific Northwest National Laboratory PSF Polysulfone PVDF Polyvinylidenefluoride RH Relative humidity SF Separation factor STP Standard conditions...

  6. Improving chemical aqueous based intervention methods for microorganism elimination from fresh produce surfaces 

    E-Print Network [OSTI]

    Puerta-Gomez, Alex Frank

    2006-04-12

    as model systems on 6 different types of produce to determine the effect of produce surface characteristics on sanitizer effectiveness. Microbial attachment on produce surfaces was induced after 3 h of drying at 24°C and high relative humidity (RH...

  7. Nutritional Programming of Neuroendocrine Pathways Controlling the Onset of Puberty in Heifers 

    E-Print Network [OSTI]

    Alves, Bruna R. C.

    2014-05-01

    Accelerated body weight gain during the juvenile period leads to early maturation of the reproductive neuroendocrine system and puberty by advancing the onset of high-frequency release of gonadotropin-releasing hormone (GnRH). In a series of studies...

  8. Reactivity studies of antitumor active dirhodium compounds with DNA oligonucleotides 

    E-Print Network [OSTI]

    Kang, Mijeong

    2007-04-25

    are clearly less stable. Reaction of cis-[Rh2(DAP)(O2CCH3)3(CH3OH)](O2CCH3) (DAP = 1,12- diazaperylene) with 5'-CTCTCAACTTCC produced a major adduct in which DAP group intercalates between 6A and 7A in the double stranded adduct with the rhodium atom...

  9. pdf file

    E-Print Network [OSTI]

    2008-12-02

    Dec 2, 2008 ... [12] proved that the short time, smooth solution to the equation (1.6) may ...... rH2. L? t L2 x(Pr(0,1)). ? L2r ? ?2. 1(?), as r ?. ?2. 1(?). L2 .

  10. Adaptation of Microvasculature to Pulsatility 

    E-Print Network [OSTI]

    Bimal, Tia

    2013-09-24

    SJ, Lackland DT, Lichtman JH, Lisabeth LD, Mackey RH, Magid DJ, Marcus GM, Marelli A, Matchar DB, McGuire DK, Mohler ER 3rd, Moy CS, Mussolino ME, Neumar RW, Nichol G, Pandey DK, Paynter NP, Reeves MJ, Sorlie PD, Stein J, Towfighi A, Turan TN, Virani...

  11. THERMAL IMPACT OF WASTE EMPLACEMENT AND SURFACE COOLING ASSOCIATED WITH GEOLOGIC DISPOSAL OF NUCLEAR WASTE

    E-Print Network [OSTI]

    Wang, J.S.Y.

    2010-01-01

    f o r 1 0 - y e a r - o l d PWR SF. I n i t i a l Heat G e nt nuclear fuel cycles for a PWR. Decay heat power for d i fKBS LWR MOX NRC NWTS ONWI OWI PWR RH-TRU WIPP b o i l i n g

  12. Title 40 CFR Part 191 Subparts B and C

    E-Print Network [OSTI]

    -2009............................................................................EXECSUM-4 DOE/WIPP-09 Application 2009 This page intentionally left blank. DOE/WIPP-09-3424 EXECSUM-iv Executive Summary-2009 #12 Baseline Calculation T fields transmissivity fields TRU transuranic RH Remote-Handled WIPP Waste Isolation

  13. Title 40 CFR Part 191 Subparts B and C

    E-Print Network [OSTI]

    ­2007).......................................................................................................... 21-5 DOE/WIPP-09-3424 Section 21-200921-iii #12;Title 40 CFR Part 191 Subparts B and C Compliance Recertification Application 2009 This page intentionally left blank. DOE/WIPP-09-3424 Section 21-200921-iv #12 QA quality assurance RH-TRU remote-handled transuranic TRU transuranic WIPP Waste Isolation Pilot

  14. Department of Energy Carlsbad Field Office

    E-Print Network [OSTI]

    ) Transuranic (TRU) Waste in shielded containers in the Waste Isolation Pilot Plant (WIPP). RH TRU waste can/hour. The containers will be transported to WIPP in the Nuclear Regulatory Commission-certified HalfPACT transportation in the WIPP Waste Information System, and the volume ofthe waste will be counted against the limit of 250

  15. THERMAL IMPACT OF WASTE EMPLACEMENT AND SURFACE COOLING ASSOCIATED WITH GEOLOGIC DISPOSAL OF NUCLEAR WASTE

    E-Print Network [OSTI]

    Wang, J.S.Y.

    2010-01-01

    NWTS ONWI OWI PWR RH-TRU WIPP b o i l i n g water reactoro l a t i o n P i l o t Plant (WIPP) s i t e {Hohlfelder andW/m ( 7 5 - k W / a c r e ) WIPP d r i f t . The e f f e c t

  16. Using the Potato Genome Sequence! Robin Buell!

    E-Print Network [OSTI]

    Douches, David S.

    ;· RHPOTKEY BAC library (78000 clones; 9-10 g.e.) · Library clones fingerprinted assembly to new map using different sequence- based marker types: SNP, SSR, DAr--where, what, when -Annotated ~40,000 genes -Used deep transcriptome sequencing (45 libraries from RH and DM

  17. Catalytic oxidation of CO by platinum group metals: from ultrahigh vacuum to elevated pressures

    E-Print Network [OSTI]

    Goodman, Wayne

    oxidation over platinum group metals has been investigated for some eight decades by many researchersCatalytic oxidation of CO by platinum group metals: from ultrahigh vacuum to elevated pressures A Catalytic oxidation of CO over platinum group metals (Pt, Ir, Rh and Pd) has been the subject of many

  18. [Frontiers in Bioscience 4889-4903, May 1, 2008] Selectivity and invariance for visual object perception

    E-Print Network [OSTI]

    Banaji,. Murad

    recognition in the inferotemporal cortex have been described in detail in (7). Here we discuss the basic perception Matias J. Ison, Rodrigo Quian Quiroga Department of Engineering, University of Leicester, LE1 7RH, we discuss basic principles of neural coding for object perception and describe evidence showing

  19. MAGLUE: Measurement and Analysis of bioenergy greenhouse gases: Integrating GHGs

    E-Print Network [OSTI]

    sensors Temp and Rh probe Quantum sensor Rain gauge Wind monitor Soil meta-bar coding and meta by the Energy Technologies Institute (ETI). The Consortium are partners are: · Centre for Ecology and Hydrology and their impact on the UK energy system Integrating GHGs into LCAs and the UK Bioenergy Value Chain Modelling

  20. Implementing Fault-Tolerance in Real-Time Programs by Automatic Program Transformations

    E-Print Network [OSTI]

    Girault, Alain

    (Pop Art team), Inovall´ee, 655 Avenue de l'Europe, 38334 Saint-Ismier cedex, France, Pascal.Fradet@inria.fr. A. Girault, Inria Rh^one-Alpes & LIG (Pop Art team), Inovall´ee, 655 Avenue de l'Europe, 38334 Saint

  1. Adaptor synthesis for realtime components # Massimo Tivoli 1 , Pascal Fradet 2 , Alain Girault 2 , and Gregor Goessler 2

    E-Print Network [OSTI]

    Girault, Alain

    tivoli@di.univaq.it 2 INRIA Rhâ??one­Alpes ­ POP ART project 655 avenue de l'Europe, 38330 Montbonnot been done while the first author was a postdoctoral fellow in the Pop Art project team at INRIA Rh

  2. RAPPORT DE PROJET DE FIN D'ETUDES ESISAR 2003/2004

    E-Print Network [OSTI]

    puce `a base de composants INRIA Rh^one-Alpes Projet POP ART 655 av Europe 38330 Montbonnot Saint remercie ´Eric Rutten pour m'avoir accueilli dans le projet Pop Art. Je tiens `a remercier Gregor G et plus g´en´eralement les membres des projets Pop Art, Mistis, Opale et Bip Pop. Je remercie

  3. Bernard Kippelen kippelen@gatech.edu

    E-Print Network [OSTI]

    Das, Suman

    coating technology for flexible hybrid electronics based on Atomic Layer Deposition Atomic Layer. Delivered on Feb. 24, 2015, Commissioning in progress Organic Vapor Phase Deposition (OVPD) cluster tool Deposition > 500 h @ 85°C and 85% RH Calcium sensors #12;General Information 14 Bernard Kippelen Joseph M

  4. Structure of a Designed, Right-Handed Coiled-Coil Tetramer Containing All Biological Amino Acids

    SciTech Connect (OSTI)

    Sales, M.; Plecs, J.J.; Holton, J.M.; Alber, T.

    2009-06-04

    The previous design of an unprecedented family of two-, three-, and four-helical, right-handed coiled coils utilized nonbiological amino acids to efficiently pack spaces in the oligomer cores. Here we show that a stable, right-handed parallel tetrameric coiled coil, called RH4B, can be designed entirely using biological amino acids. The X-ray crystal structure of RH4B was determined to 1.1 {angstrom} resolution using a designed metal binding site to coordinate a single Yb{sup 2+} ion per 33-amino acid polypeptide chain. The resulting experimental phases were particularly accurate, and the experimental electron density map provided an especially clear, unbiased view of the molecule. The RH4B structure closely matched the design, with equivalent core rotamers and an overall root-mean-square deviation for the N-terminal repeat of the tetramer of 0.24 {angstrom}. The clarity and resolution of the electron density map, however, revealed alternate rotamers and structural differences between the three sequence repeats in the molecule. These results suggest that the RH4B structure populates an unanticipated variety of structures.

  5. Asymmetric Catalysis DOI: 10.1002/anie.200601501

    E-Print Network [OSTI]

    Zhang, Xumu

    at the 3,3'-positions.[7] Inspired by the success of many hybrid C1- symmetric chelating ligands,[8] we of the methoxy methyl (MOM) groups of 2 in HCl/ MeOH, the desired product 1 was prepared by heating 3 of several standard a-aryl enamides. Initial studies on the [Rh/1a] system using the benchmark substrate 4a

  6. Non-Linear Drying Diffusion and Viscoelastic Drying Shrinkage Modeling in Hardened Cement Pastes 

    E-Print Network [OSTI]

    Leung, Chin K.

    2010-07-14

    The present research seeks to study the decrease in diffusivity rate as relative humidity (RH) decreases and modeling drying shrinkage of hardened cement paste as a poroviscoelastic respose. Thin cement paste strips of 0.4 and 0.5 w/c at age 3 and 7...

  7. Title 40 CFR Part 191 Subparts B and C

    E-Print Network [OSTI]

    at the time of disposal. 3 31.2 Background4 The radioactive waste disposal regulations at 40 CFR Part 191 (U.................................................................................................................31-7 List of Tables Table 31-1. Total Radioactivity Associated with CH-TRU and RH-TRU Wastes Waste Inventory Report CARD Compliance Application Review Document CCA Compliance Certification

  8. Status of Directly Driven ICF University of Rochester

    E-Print Network [OSTI]

    NIF Polar Drive OMEGA Experiments 78° 45° 23.5° 30° (45°) 50° (45°) 23.5° 0 0 100 200 300 100 GtRH1-D San Ramon, CA 29 January 2011 #12;TC9179 Directly-driven ignition designs and IFE designs for the NIF on OMEGA ­ experiments are being designed to examine laser­plasma interactions for anticipated NIF

  9. Published: August 10, 2011 r 2011 American Chemical Society 18247 dx.doi.org/10.1021/jp204961g |J. Phys. Chem. C 2011, 115, 1824718256

    E-Print Network [OSTI]

    Li, Weixue

    ) is an important industrial process for the production of clean liquid energy fuels and valuable chemical), produced by CO dissociation followed by hydrogenation (carbide mechan- ism), or vice versa (hydrogen liquid energy fuels and valuable chemical feedstocks that are catalyzed industrially by Rh modified

  10. FROM SMART TECHNOLOGY TO SMART CONSUMERS: FOR BETTER SYSTEM RELIABILITY AND IMPROVED MARKET EFFICIENCY.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    administered by the CAISO. All these elements contributed to shape California's energy strategy, where peak adoption in California, Germany, Illinois and the UK and is articulated in four points. First, it describes'Investissement and the ARC Energy Community of Région Rhône-Alpes. halshs-01011169,version1-23Jun2014 Author manuscript

  11. Increased Luteinizing Hormone Secretion in Women with Polycystic Ovary Syndrome Is Unaltered by

    E-Print Network [OSTI]

    Lawson, Mark A.

    by Prolonged Insulin Infusion KETAN PATEL, MICKEY S. COFFLER, MICHAEL H. DAHAN, RICHARD Y. YOO, MARK A. LAWSON 2) insulin infusion. In phase 1, 11 PCOS and 9 normal women on separate days underwent 1) frequent pulse amplitude. More- over, gonadotropin responses to GnRH were unchanged by insulin infusion. In PCOS

  12. Submillimeter Polarimetry and the Galactic Center Magnetic Field

    E-Print Network [OSTI]

    Novak, Giles

    Submillimeter Polarimetry and the Galactic Center Magnetic Field D.T. Chuss NASA Goddard Space Flight Center C.D. Dowell Jet Propulsion Laboratory R.H. Hildebrand University of Chicago G. Novak that of the magnetic field. In addition, we present new Hertz data on the Dust Ridge, an arched structure

  13. MuMHR: Multi-path, Multi-hop Hierarchical Mohammad Hammoudeh, Alexander Kurz, and Elena Gaura

    E-Print Network [OSTI]

    Kurz, Alexander

    Leicester, LE1 7RH, UK. Email: kurz@mcs.le.ac.uk Abstract-- This paper proposes a self-organizing, cluster the energy consumption in the network. The dynamic cluster- ing brings extra overhead, such as head changes, which may diminish savings in energy consumption. A possible solution which is examined in this paper

  14. Spin-orbit tuned metal-insulator transitions in single-crystal Sr?Ir1–xRhxO? (0?x?1)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Qi, T. F.; Korneta, O. B.; Li, L.; Butrouna, K.; Cao, V. S.; Wan, Xiangang; Schlottmann, P.; Kaul, R. K.; Cao, G.

    2012-09-01

    Sr?IrO? is a magnetic insulator driven by spin-orbit interaction (SOI) whereas the isoelectronic and isostructural Sr?RhO? is a paramagnetic metal. The contrasting ground states have been shown to result from the critical role of the strong SOI in the iridate. Our investigation of structural, transport, magnetic, and thermal properties reveals that substituting 4d Rh?? (4d?) ions for 5d Ir?? (5d?) ions in Sr?IrO? directly reduces the SOI and rebalances the competing energies so profoundly that it generates a rich phase diagram for Sr?Ir1–xRhxO? featuring two major effects: (1) Light Rh doping (0 ? x ? 0.16) prompts a simultaneous andmore »precipitous drop in both the electrical resistivity and the magnetic ordering temperature TC, which is suppressed to zero at x = 0.16 from 240 K at x = 0. (2) However, with heavier Rh doping [0.24 1–xRhxO? is further highlighted by comparison with Sr?Ir1–xRuxO? where Ru?? (4d?) drives a direct crossover from the insulating to metallic states.« less

  15. 5750 J. Am. Chem. SOC.1990, 112, 5750-5759 Bond Strengths of Ethylene and Acetylene

    E-Print Network [OSTI]

    Ellison, Barney

    by which bond strengthscan be determined. Our method uses the thermochemical c y ~ l e ' ~ . ' ~represented(R), which is the enthalpy change for process I , and proton transfer kinetics are used to determine the hydrocarbon gas-phase acidity, Maed(RH), which is the enthalpy change for process 2. Thesevaluescan

  16. Synthesis and Characterization of (Tris(3,5-dimethylpyrazolyl)borato)rhodium Alkyl and Vinyl Chloride Complexes

    E-Print Network [OSTI]

    Jones, William D.

    -reducing side reactions. Additionally, secondary derivatives of normal alkanes cannot be prepared by this method, it is not economical due to the sacrifice of 1 equiv of neopentyl isocyanide. Chambron and co-workers have reported. Powell and co-workers have reported a method for synthesizing a wide range of air-stable Rh

  17. Cover Sheet for Supporting Information (SI) Simulation of aromatic SOA formation using the lumping model integrated

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    ). The GC oven temperature was fixed at 110 °C and the carrier gas (nitrogen) flow rate was 10.0 mL min-1 measured using Temp/RH sensors (Campbellscientific, CS215-L) for both chambers. The solar UV radiation

  18. A sintering model for thermal barrier coatings R.G. Hutchinson a

    E-Print Network [OSTI]

    Fleck, Norman A.

    a Cambridge University Engineering Department, Trumpington Street, Cambridge CB2 1PZ, UK b Department of Engineering, Leicester University, Leicester LE1 7RH, UK Received 15 September 2005; received in revised form-PVD coatings comprise a 100­200 lm thick layer of columnar yttria-stabilised zirconia (typically, 7YSZ

  19. Two-electron mixed-valence complexes small molecule activation and photocatalytic hydrogen production

    E-Print Network [OSTI]

    Heyduk, Alan F. (Alan Frank), 1974-

    2001-01-01

    Two-electron mixed-valence complexes of rhodium may be supported by diphosphazane ligands (RN(PY2)2). Whereas diphosphazane ligands with strongly [pi]-acidic phosphine groups (Y = F, OCH2CF3) react with RhI starting materials ...

  20. Alcohol synthesis from CO or CO.sub.2

    DOE Patents [OSTI]

    Hu, Jianli [Kennewick, WA; Dagle, Robert A [Richland, WA; Holladay, Jamelyn D [Kennewick, WA; Cao, Chunshe [Houston, TX; Wang, Yong [Richland, WA; White, James F [Richland, WA; Elliott, Douglas C [Richland, WA; Stevens, Don J [Richland, WA

    2010-12-28

    Methods for producing alcohols from CO or CO.sub.2 and H.sub.2 utilizing a palladium-zinc on alumina catalyst are described. Methods of synthesizing alcohols over various catalysts in microchannels are also described. Ethanol, higher alcohols, and other C.sub.2+ oxygenates can produced utilizing Rh--Mn or a Fisher-Tropsch catalyst.

  1. Shielded Payload Containers Will Enhance the Safety and

    E-Print Network [OSTI]

    Absorber #12;Radial Shock Absorber #12;Container Testing DOT Type 7A Certification ­ Shielded Container 4, 2008 #12;Shielded Containers - Approach · Candidate waste streams to be characterized and certified and the requirements of the LWA for RH TRU waste will continue to be met · All waste received in shielded containers

  2. Performance and mass transport in open metallic element architecture fuel cells at ultra-high current density

    E-Print Network [OSTI]

    Mench, Matthew M.

    transport Mass transport Flooding Diffusion a b s t r a c t Performance and mass transport of a polymer at extremely high currents. Ó 2012 Elsevier B.V. All rights reserved. 1. Introduction The polymer electrolyte metallic element; PEFC, polymer electrolyte fuel cell; RH,

  3. A Self-sufficient Cytochrome P450 with a Primary Structural Organization That Includes a Flavin Domain and a [2Fe-2S] Redox Center 

    E-Print Network [OSTI]

    Roberts, Gareth A; Celik, Ayhan; Hunter, Dominic JB; Ost, Tobias WB; White, John H; Chapman, Stephen K; Turner, Nicholas J; Flitsch, Sabine L

    2003-09-27

    P450 RhF from Rhodococcus sp. NCIMB 9784 is the first example of a new class of cytochrome P450 in which electrons are supplied by a novel, FMN- and Fe/S-containing, reductase partner in a fused arrangement. We have ...

  4. reiner@hartenstein.de 17 May 2013

    E-Print Network [OSTI]

    Hartenstein, Reiner

    of Oil Reiner Hartenstein TU Kaiserslautern http://hartenstein.de FET Proactive­ FP7 Call 4 Workshop consumption affordable energy consumption © 2007, reiner@hartenstein.de [R.H.] http://hartenstein.de TU Computing via FET affordable energy consumption affordable energy consumption under affordable cost under

  5. Modeled interactive effects of precipitation, temperature, and [CO2] on ecosystem carbon and water dynamics in

    E-Print Network [OSTI]

    Dukes, Jeffrey

    , Fort Collins, CO 80523, USA, }Biosystems Department, Ris National Laboratory for Sustainable Energy, Technical University of Denmark, Building BIO-309, Frederiksborgvej 399, 4000 Roskilde, Denmark, k), and elevated [CO2] (C) on net primary production (NPP), heterotrophic respiration (Rh), net ecosystem

  6. Separation of intact phenol cells from waterhyacinth leaves: characterization of their phenolic content and the effect of some phenolic acids on two potential biological control agents 

    E-Print Network [OSTI]

    Cody, Yvonne Susan

    1979-01-01

    to cause d1seases of waterhyac1nths include Fusarium roseum, Rh1zocton1a solani, Acremonium zonatum, hrrotheci ortdium ra . ei hho iae, marut ieitua ioode a, hite a ia ichhoroiae, d ~te co o a rodmaoii i16. 36). Many of these organisms are host specific...

  7. Universite Paris 7-Denis Diderot Alg`ebre Annee 2007-08 M1 mathematiques

    E-Print Network [OSTI]

    Merel, Loïc - Institut de Mathématiques de Jussieu, Université Paris 7

    ¦§i ¡¥ ¼ E¸ °5° ¾¤Eh°Q«E%ªEºV¦§¤E¥6 m¥¥b¤h%ªE¦§h¾« o¢¤h °y m¦®T¦ m¦§h ¡ib5 ¡r¤h³¥ Ãæf¾° Ë 5°¹ m¥«h º

  8. Probing water transport in polymer electrolyte fuel cells with neutron radiography

    E-Print Network [OSTI]

    Mench, Matthew M.

    Probing water transport in polymer electrolyte fuel cells with neutron radiography Kyu Taek Cho a freezing [5­7]. Cho et al. [6] observed no performance degradation after freeze/thaw cycling when the cell no performance loss and no damage to the CL after 20 freeze/thaw cycles in a cell purged with RH 58% gas. Several

  9. Process for functionalizing alkanes

    DOE Patents [OSTI]

    Bergman, Robert G. (Kensington, CA); Janowicz, Andrew H. (Wilmington, DE); Periana, Roy A. (Berkeley, CA)

    1988-01-01

    Process for functionalizing saturated hydrocarbons comprising: (a) reacting said saturated hydrocarbons of the formula: R.sub.1 H wherein H represents a hydrogen atom; and R.sub.1 represents a saturated hydrocarbon radical, with a metal complex of the formula: CpRh[P(R.sub.2).sub.3 ]H.sub.2 wherein Cp represents a cyclopentadienyl or alkylcyclopentadienyl radical; Rh represents a rhodium atom; P represents a phosphorus atom; R.sub.2 represents a hydrocarbon radical; H represents a hydrogen atom, in the presence of ultraviolet radiation to form a hydridoalkyl complex of the formula: CpRh[P(R.sub.2).sub.3 ](R.sub.1)H (b) reacting said hydridoalkyl complex with an organic halogenating agent such as a tetrahalomethane or a haloform of the formulas: CX'X''X'''X'''' or CHX'X''X''' wherein X', X'', X'", X"" represent halogens selected from bromine, iodine or chlorine atom, at a temperature in the range of about -60.degree. to -17.degree. C. to form the corresponding haloalkyl complex of step (a) having the formula: CpRhPMe.sub.3 RX; and, (c) reacting said haloalkyl complex formed in (b) with halogen (X.sub.2) at a temperature in the range of about -60.degree. to 25.degree. C. (i.e., ambient) to form a functional haloalkyl compound.

  10. Process for functionalizing alkanes

    DOE Patents [OSTI]

    Bergman, R.G.; Janowicz, A.H.; Periana, R.A.

    1988-05-24

    Process for functionalizing saturated hydrocarbons comprises: (a) reacting said saturated hydrocarbons of the formula: R[sub 1]H wherein H represents a hydrogen atom; and R[sub 1] represents a saturated hydrocarbon radical, with a metal complex of the formula: CpRh[P(R[sub 2])[sub 3

  11. Proceedings of DETC'97 1997 ASME Design Engineering Technical Conferences

    E-Print Network [OSTI]

    Rand, Richard H.

    ALGEBRA A.D. Blackowiak Intel Corporation Santa Clara, CA 95052 R.H. Rand Dept.Theoretical & Applied of the slow ow are obtained in symbolic form through the use of computer algebra, thus permitting spun like a top on a at surface, has a characteristic tendency to prefer only one direction of spin

  12. Preparation of highly dispersed PEM fuel cell catalysts using electroless deposition methods

    E-Print Network [OSTI]

    Van Zee, John W.

    (DMAB) on a Rh-seeded carbon support has been developed for electrochemical and fuel cell applications With the growing commercialization of fuel cells and subsequent attempts to make the technology economicallyPreparation of highly dispersed PEM fuel cell catalysts using electroless deposition methods K

  13. Atmos. Chem. Phys., 10, 1109711114, 2010 www.atmos-chem-phys.net/10/11097/2010/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    (RH), rain rate, and wind speed were predicted to increase in the future cli- mate while the ultra violet (UV) radiation was predicted to decrease in major urban areas in the San Joaquin Valley (SJV in California outside of coastal + central Los Angeles, and a small region around the port of Oakland in the San

  14. Nuclear spin-density wave theory

    E-Print Network [OSTI]

    Yao Cheng

    2009-09-15

    Recently [arXiv:0906.5417], we reported a quantum phase transition of 103mRh excited by bremsstrahlung pumping. The long-lived Moessbauer excitation is delocalized as a neutral quasiparticle carrying a spin current. This letter gives a general theory for a nuclear spin-density wave propagating on crystals consisting of identical nuclei with a multipolar transition.

  15. Yurok Retroflection and Vowel Symbolism in Proto-Algic

    E-Print Network [OSTI]

    Proulx, Paul

    1982-01-01

    ), and by the Melville and Elizabeth Jacobs Research Fund, Whatcom Museum Foundation, Bellingham, Washington. The principle informant was Mrs. Florence Shaughnessy of Requoi (who also served as principle informant to R.H. Robins in the 1950's, and to Howard Berman...

  16. List updated 7/26/2013 BLDG. # BLDG. CODE BUILDING NAME

    E-Print Network [OSTI]

    Fernandez, Eduardo

    List updated 7/26/2013 BLDG. # BLDG. CODE BUILDING NAME MC01 HC HARRIET L. WILKES HONORS COLLEGE MC02 AD MACARTHUR ADMINISTRATION/CLASSROOM BUILDING MC03 SR STUDENT RESOURCES & CLASSROOM BUILDING MC04 BUILDING MC08 HM HIBEL MUSEUM OF ART MC09 RH MACARTHUR RESIDENCE HALL II MC10 PL POOL EQUIPMENT

  17. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    Review of thorium fuel reprocessing experience","Brooksbank, R.E.; McDuffee, W.T.; Rainey, R.H.","1978-01-01T05:00:00Z",5080081,,"CONF-780223-3","W-7405-ENG-26","TRN:...

  18. ENS'05 Paris, France, 14-16 December 2005 STRUCTURE, MAGNETISM AND DYNAMICS OF

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    the development of recording media and devices with always bigger storage capacities. In this context, magneticENS'05 Paris, France, 14-16 December 2005 STRUCTURE, MAGNETISM AND DYNAMICS OF NANOSTRUCTURED on nanostructured materials including i) magnetic alloyed CoRh nanoparticles that are good candidates to combine

  19. NOAA PMEL Station Chemistry Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Quinn, Patricia

    2008-04-04

    Submicron and supermicron samples are analyzed by ion chromatography for Cl-, NO3-, SO4-2, Na+, NH4+, K+, Mg2+, and Ca+2. The analysis of MSA-, Br-, and oxalate has been added to some stations. Samples also are analyzed for total mass by gravimetric analysis at 55 +/- 5% RH.

  20. Updated 9/18/2008 COURSE SYLLABUS

    E-Print Network [OSTI]

    Leach, Jennie B.

    and are on reserve in the UMBC library. · R.H. Perry and D.W. Green. Chemical Engineers' Handbook. (any edition) New. Fundamentals of Momentum, Heat, and Mass Transfer. (any edition) New York: John Wiley & Sons. R.W. Fox, A.T. Mc, science and chemical engineering courses to analyze and interpret information acquired by operating

  1. This content has been downloaded from IOPscience. Please scroll down to see the full text. Download details

    E-Print Network [OSTI]

    Raffray, A. René

    on the first wall RH remote handling SB shield block SDC-IC (ITER) structural design criteria for in that terms and conditions apply. The ITER blanket system design challenge View the table of contents;| International Atomic Energy Agency Nuclear Fusion Nucl. Fusion 54 (2014) 033004 (18pp) doi:10

  2. Poly(cyclohexadiene)-Based Polymer Electrolyte Membranes for Fuel Cell Applications

    SciTech Connect (OSTI)

    Mays, Jimmy W.

    2011-03-07

    The goal of this research project was to create and develop fuel cell membranes having high proton conductivity at high temperatures and high chemical and mechanical durability. Poly(1,3-cyclohexadiene) (PCHD) is of interest as an alternative polymer electrolyte membrane (PEM) material due to its ring-like structure which is expected to impart superior mechanical and thermal properties, and due to the fact that PCHD can readily be incorporated into a range of homopolymer and copolymer structures. PCHD can be aromatized, sulfonated, or fluorinated, allowing for tuning of key performance structure and properties. These factors include good proton transport, hydrophilicity, permeability (including fuel gas impermeability), good mechanical properties, morphology, thermal stability, crystallinity, and cost. The basic building block, 1,3-cyclohexadiene, is a hydrocarbon monomer that could be inexpensively produced on a commercial scale (pricing typical of other hydrocarbon monomers). Optimal material properties will result in novel low cost PEM membranes engineered for high conductivity at elevated temperatures and low relative humidities, as well as good performance and durability. The primary objectives of this project were: (1) To design, synthesize and characterize new non-Nafion PEM materials that conduct protons at low (25-50%) RH and at temperatures ranging from room temperature to 120 C; and (2) To achieve these objectives, a range of homopolymer and copolymer materials incorporating poly(cyclohexadiene) (PCHD) will be synthesized, derivatized, and characterized. These two objectives have been achieved. Sulfonated and crosslinked PCHD homopolymer membranes exhibit proton conductivities similar to Nafion in the mid-RH range, are superior to Nafion at higher RH, but are poorer than Nafion at RH < 50%. Thus to further improve proton conductivity, particularly at low RH, poly(ethylene glycol) (PEG) was incorporated into the membrane by blending and by copolymerization. Conductivity measurements at 120 C over RH ranging from 20 to 100% using the BekkTech protocol showed much improved proton conductivities. Conductivities for the best of these new membranes exceed the DOE Year 3 milestone of 100 mS/cm at 50% RH at 120 C. Further optimization of these very promising low cost membranes could be pursued in the future.

  3. Rhodium Catalysts in the Oxidation of CO by O2 and NO: Shape, Composition, and Hot Electron Generation

    SciTech Connect (OSTI)

    Renzas, James R.

    2010-03-08

    It is well known that the activity, selectivity, and deactivation behavior of heterogeneous catalysts are strongly affected by a wide variety of parameters, including but not limited to nanoparticle size, shape, composition, support, pretreatment conditions, oxidation state, and electronic state. Enormous effort has been expended in an attempt to understand the role of these factors on catalytic behavior, but much still remains to be discovered. In this work, we have focused on deepening the present understanding of the role of nanoparticle shape, nanoparticle composition, and hot electrons on heterogeneous catalysis in the oxidation of carbon monoxide by molecular oxygen and nitric oxide. These reactions were chosen because they are important for environmental applications, such as in the catalytic converter, and because there is a wide range of experimental and theoretical insight from previous single crystal work as well as experimental data on nanoparticles obtained using new state-of-the-art techniques that aid greatly in the interpretation of results on complex nanoparticle systems. In particular, the studies presented in this work involve three types of samples: {approx} 6.5 nm Rh nanoparticles of different shapes, {approx} 15 nm Rh1-xPdx core-shell bimetallic polyhedra nanoparticles, and Rh ultra-thin film ({approx} 5 nm) catalytic nanodiodes. The colloidal nanoparticle samples were synthesized using a co-reduction of metal salts in alcohol and supported on silicon wafers using the Langmuir-Blodgett technique. This synthetic strategy enables tremendous control of nanoparticle size, shape, and composition. Nanoparticle shape was controlled through the use of different organic polymer capping layers. Bimetallic core-shell nanoparticles were synthesized by careful choice of metal salt precursors. Rh/TiO{sub x} and Rh/GaN catalytic nanodiodes were fabricated using a variety of thin film device fabrication techniques, including reactive DC magnetron sputtering, electron beam evaporation, and rapid thermal annealing. The combination of these techniques enabled control of catalytic nanodiode morphology, geometry, and electrical properties.

  4. Rhodium mediated bond activation: from synthesis to catalysis

    SciTech Connect (OSTI)

    Ho, Hung-An

    2012-03-06

    Recently, our lab has developed monoanionic tridentate ligand, To{sup R}, showing the corresponding coordination chemistry and catalyst reactivity of magnesium, zirconium, zinc and iridium complexes. This thesis details synthetic chemistry, structural study and catalytic reactivity of the To{sup R}-supported rhodium compounds. Tl[To{sup R}] has been proved to be a superior ligand transfer agent for synthesizing rhodium complexes. The salt metathesis route of Tl[To{sup M}] with [Rh({mu}-Cl)(CO)]{sub 2} and [Rh({mu}- Cl)(COE)]{sub 2} gives To{sup M}Rh(CO){sub 2} (2.2) and To{sup M}RhH({eta}{sup 3}-C{sub 8}H{sub 13}) (3.1) respectively while Tl[To{sup P}] with [Rh({mu}-Cl)(CO)]{sub 2} affords To{sup P}Rh(CO){sub 2} (2.3). 2.2 reacts with both strong and weak electrophiles, resulting in the oxazoline N-attacked and the metal center-attacked compounds correspondingly. Using one of the metal center-attacked electrophiles, 2.3 was demonstrated to give high diastereoselectivity. Parallel to COE allylic C-H activation complex 3.1, the propene and allylbenzene allylic C-H activation products have also been synthesized. The subsequent functionalization attempts have been examined by treating with Brønsted acids, Lewis acids, electrophiles, nucleophiles, 1,3-dipolar reagents and reagents containing multiple bonds able to be inserted. Various related complexes have been obtained under these conditions, in which one of the azide insertion compounds reductively eliminates to give an allylic functionalization product stoichiometrically. 3.1 reacts with various primary alcohols to give the decarbonylation dihydride complex To{sup M}Rh(H){sub 2}CO (4.1). 4.1 shows catalytic reactivity for primary alcohol decarbonylation under a photolytic condition. Meanwhile, 2.2 has been found to be more reactive than 4.1 for catalytic alcohol decarbonylation under the same condition. Various complexes and primary alcohols have been investigated as well. The proposed mechanism is based on the stochiometric reactions of the possible metal and organic intermediates. Primary amines, hypothesized to undergo a similar reaction pathway, have been verified to give dehydrogenative coupling product, imines. In the end, the well-developed neutral tridentate Tpm coordinates to the rhodium bis(ethylene) dimer in the presence of TlPF{sub 6} to give the cationic complex, [TpmRh(C{sub 2}H{sub 4}){sub 2}][PF{sub 6}] (5.1). 5.1 serves as the first example of explicit determination of the solid state hapticity, evidenced by X-ray structure, among all the cationic Tpm{sup R}M(C{sub 2}H{sub 4}){sub 2}{sup +} (Tpm{sup R} = Tpm, Tpm*, M = Rh, Ir) derivatives. The substitution chemistry of this compound has been studied by treating with soft and hard donors. The trimethylphosphine-sbustituted complex activates molecular hydrogen to give the dihydride compound.

  5. The Direct Path To WIPP - 12471

    SciTech Connect (OSTI)

    Spoerner, M.T.; Burger, M.J.; Garcia, J. [Sandia National Laboratories (United States); Humphrey, B.J. [Weston Solutions, Inc. (United States); Rast, D. [National Nuclear Security Administration, Sandia Site Office (United States)

    2012-07-01

    Sandia National Laboratories/New Mexico (SNL/NM), designated as a small quantity site (SQS) by the National TRU Program (NTP), generated contact-handled (CH) and remote-handled (RH) transuranic (TRU) waste primarily from the decontamination and clean-out of glove boxes at the Hot Cell Facility (HCF) at Technical Area (TA) V. All of the waste required repackaging, with the CH TRU waste being repackaged from late 2007 through 2011. Three shipments of CH were completed in October 2011, which de-inventoried SNL/NM's legacy TRU waste. In FY11, RH TRU waste was repackaged at the Auxiliary Hot Cell Facility (AHCF) located in TAV with the support of the Central Characterization Project (CCP). The waste was originally packaged in SNL/NM fabricated casks, cement or lead-lined 55-gallon drums, or 30-gallon drums. The AHCF is a small hot cell, with access only through a roof port which presented challenges for inserting and removing waste from the hot cell. The CCP provided visual examination operators (VEOs) to observe and document each waste item repackaged, removal of prohibited items, and radiological sampling. Dose-to-Curie measurements were calculated by CCP after a radiological report was prepared using scaling factors determined by the analysis of swipe samples. Finally, headspace gas samples were taken and sent to the Advanced Mixed Waste Treatment Project (AMWTP) for analysis. Despite the challenges, the RH waste is on track to be shipped to WIPP in early FY12. The processes used and procedures developed to conduct the repackaging operations, the issues identified and mitigated were challenging but the cooperation between SNL/NM and the Central Characterization Program (CCP) enabled SNL/NM to complete the repackaging and support the characterization and shipment. An inventory list, identification of the campaigns, discussion of the challenges and mitigations, and the final loading of the RH 72-B casks at TA-V for direct shipment to the Waste Isolation Pilot Plant (WIPP) will be discussed. Lessons learned from the RH campaigns are: - Some containers that were originally identified as HC-3 have been re-evaluated and became < HC-3 due to the conservative estimates made by the original generators - Operators at the AHCF were not accustomed to the detail required by the VE operators. However, they worked well together and the repackaging was completed ahead of schedule. - The AK was not always accurate as was demonstrated by the solid waste found in the drum during the first visit by EPA. That waste has since been determined to be low-level. - Two drums originally thought to be RH turned out to be CH and arrangement for RTR had to be made quickly. - Six of the original RH repacked drums became low level. - Lessons learned from the CH campaigns were helpful in avoiding many issues. The RH repackaging effort has been a success due to the expertise of the AHCF operators, supervisor, and manager, the conscientious attention to detail of the CCP VE operators, the experience of the CCP DTC and headspace gas sampling staff, and the guidance and support from CCP and CBFO. Sometimes schedules had to be adjusted, processes updated, and issues discussed, but the communication between CCP and SNL/NM was good. SNL/NM hopes to have the legacy RH TRU waste shipped off-site by early 2012. (authors)

  6. Mixed N-Heterocyclic Carbene-Bis(oxazolinyl)borato Rhodium and Iridium Complexes in Photochemical and Thermal Oxidative Addition Reactions

    SciTech Connect (OSTI)

    Xu, Songchen; Manna, Kuntal; Ellern, Arkady; Sadow, Aaron D

    2014-12-08

    In order to facilitate oxidative addition chemistry of fac-coordinated rhodium(I) and iridium(I) compounds, carbene–bis(oxazolinyl)phenylborate proligands have been synthesized and reacted with organometallic precursors. Two proligands, PhB(OxMe2)2(ImtBuH) (H[1]; OxMe2 = 4,4-dimethyl-2-oxazoline; ImtBuH = 1-tert-butylimidazole) and PhB(OxMe2)2(ImMesH) (H[2]; ImMesH = 1-mesitylimidazole), are deprotonated with potassium benzyl to generate K[1] and K[2], and these potassium compounds serve as reagents for the synthesis of a series of rhodium and iridium complexes. Cyclooctadiene and dicarbonyl compounds {PhB(OxMe2)2ImtBu}Rh(?4-C8H12) (3), {PhB(OxMe2)2ImMes}Rh(?4-C8H12) (4), {PhB(OxMe2)2ImMes}Rh(CO)2 (5), {PhB(OxMe2)2ImMes}Ir(?4-C8H12) (6), and {PhB(OxMe2)2ImMes}Ir(CO)2 (7) are synthesized along with ToMM(?4-C8H12) (M = Rh (8); M = Ir (9); ToM = tris(4,4-dimethyl-2-oxazolinyl)phenylborate). The spectroscopic and structural properties and reactivity of this series of compounds show electronic and steric effects of substituents on the imidazole (tert-butyl vs mesityl), effects of replacing an oxazoline in ToM with a carbene donor, and the influence of the donor ligand (CO vs C8H12). The reactions of K[2] and [M(?-Cl)(?2-C8H14)2]2 (M = Rh, Ir) provide {?4-PhB(OxMe2)2ImMes?CH2}Rh(?-H)(?-Cl)Rh(?2-C8H14)2 (10) and {PhB(OxMe2)2ImMes}IrH(?3-C8H13) (11). In the former compound, a spontaneous oxidative addition of a mesityl ortho-methyl to give a mixed-valent dirhodium species is observed, while the iridium compound forms a monometallic allyl hydride. Photochemical reactions of dicarbonyl compounds 5 and 7 result in C–H bond oxidative addition providing the compounds {?4-PhB(OxMe2)2ImMes?CH2}RhH(CO) (12) and {PhB(OxMe2)2ImMes}IrH(Ph)CO (13). In 12, oxidative addition results in cyclometalation of the mesityl ortho-methyl similar to 10, whereas the iridium compound reacts with the benzene solvent to give a rare crystallographically characterized cis-[Ir](H)(Ph) complex. Alternatively, the rhodium carbonyl 5 or iridium isocyanide {PhB(OxMe2)2ImMes}Ir(CO)CNtBu (15) reacts with PhSiH3 in the dark to form the silyl compound {PhB(OxMe2)2ImMes}RhH(SiH2Ph)CO (14) or {PhB(OxMe2)2ImMes}IrH(SiH2Ph)CNtBu (17). These examples demonstrate the enhanced thermal reactivity of {PhB(OxMe2)2ImMes}-supported iridium and rhodium carbonyl compounds in comparison to tris(oxazolinyl)borate, tris(pyrazolyl)borate, and cyclopentadienyl-supported compounds.

  7. Optical Properties of Moderately-Absorbing Organic and Mixed Organic/Inorganic Particles at Very High Humidities

    SciTech Connect (OSTI)

    Bond, Tami C; Rood, Mark J; Brem, Benjamin T; Mena-Gonzalez, Francisco C; Chen, Yanju

    2012-04-16

    Relative humidity (RH) affects the water content of an aerosol, altering its ability to scatter and absorb light, which is important for aerosol effects on climate and visibility. This project involves in situ measurement and modeling of aerosol optical properties including absorption, scattering and extinction at three visible wavelengths (467, 530, 660 nm), for organic carbon (OC) generated by pyrolysis of biomass, ammonium sulfate and sodium chloride, and their mixtures at controlled RH conditions. Novel components of this project include investigation of: (1) Changes in all three of these optical properties at scanned RH conditions; (2) Optical properties at RH values up to 95%, which are usually extrapolated instead of measured; and (3) Examination of aerosols generated by the pyrolysis of wood, which is representative of primary atmospheric organic carbon, and its mixture with inorganic aerosol. Scattering and extinction values were used to determine light absorption by difference and single scattering albedo values. Extensive instrumentation development and benchmarking with independently measured and modeled values were used to obtain and evaluate these new results. The single scattering albedo value for a dry absorbing polystyrene microsphere benchmark agreed within 0.02 (absolute value) with independently published results at 530 nm. Light absorption by a nigrosin (sample light-absorbing) benchmark increased by a factor of 1.24 +/-0.06 at all wavelengths as RH increased from 38 to 95%. Closure modeling with Mie theory was able to reproduce this increase with the linear volume average (LVA) refractive index mixing rule for this water soluble compound. Absorption by biomass OC aerosol increased by a factor of 2.1 +/- 0.7 and 2.3 +/- 1.2 between 32 and 95% RH at 467 nm and 530 nm, but there was no detectable absorption at 660 nm. Additionally, the spectral dependence of absorption by OC that was observed with filter measurements was confirmed qualitatively in situ at 467 and 530 nm. Closure modeling with the dynamic effective medium approximation (DEMA) refractive index model was able to capture the increasing absorption trend with RH indicating that the droplets were heterogeneously mixed while containing dispersed insoluble absorbing material within those droplets. Seven other refractive index mixing models including LVA did not adequately describe the measurements for OC. Mixing the biomass OC aerosol with select mass fractions of ammonium sulfate ranging from 25 to 36% and sodium chloride ranging from 21 to 30% resulted in an increase in light scattering and extinction with RH and inorganic mass fraction. However, no detectable difference in light absorption behavior in comparison to pure biomass OC was observed. The main finding of this research is a measured increase in absorption with increasing RH, which is currently not represented in radiative transfer models even though biomass burning produces most of the primary OC aerosol in the atmosphere.

  8. Novel Approaches to Immobilized Heteropoly Acid Systems for High Temperature, Low Relative Humidity Polymer-Type Membranes - Final Report

    SciTech Connect (OSTI)

    Herring, Andrew M; Horan, James L; Aieta, Niccolo V; Sachdeva, Sonny; Kuo, Mei-Chen; Ren, Hui; Lingutla, Anitha; Emery, Michael; Haugen, Gregory M; Yandrasits, Michael A; Sharma, Neeraj; Coggio, William D; Hamrock, Steven J; Frey, Matthew H

    2012-05-20

    Original research was carried out at the CSM and the 3M Company from March 2007 through September 2011. The research was aimed at developing new to the world proton electrolyte materials for use in hydrogen fuel cells, in particular with high proton conductivity under hot and dry conditions (>100mS/cm at 120°C and 50%RH). Broadly stated, the research at 3M and between 3M and CSM that led to new materials took place in two phases: In the first phase, hydrocarbon membranes that could be formed by photopolymerization of monomer mixtures were developed for the purpose of determining the technical feasibility of achieving the program's Go/No-Go decision conductivity target of >100mS/cm at 120°C and 50%RH. In the second phase, attempts were made to extend the achieved conductivity level to fluorinated material systems with the expectation that durability and stability would be improved (over the hydrocarbon material). Highlights included: Multiple lots of an HPA-immobilized photocurable terpolymer derived from di-vinyl-silicotungstic acid (85%), n-butyl acrylate, and hexanediol diacrylate were prepared at 3M and characterized at 3M to exhibit an initial conductivity of 107mS/cm at 120°C and 47%RH (PolyPOM85v) using a Bekktech LLC sample fixture and TestEquity oven. Later independent testing by Bekktech LLC, using a different preheating protocol, on the same material, yielded a conductivity value of approximately 20mS/cm at 120°C and 50%RH. The difference in measured values is likely to have been the result of an instability of properties for the material or a difference in the measurement method. A dispersed catalyst fuel cell was fabricated and tested using a 150¼m thick HPA-based photocurable membrane (above, PolyPOM75v), exhibiting a current density of greater than 300mA/cm2 at 0.5V (H2/Air 800/1800sccm 70°C/75%RH ambient outlet pressure). Multiple lots of a co-polymer based on poly-trifluorovinylether (TFVE) derived HPA were synthesized and fabricated into films, Generation II films. These materials showed proton conductivities as high as 1 S/cm under high RH conditions. However, the materials suffered from compromised properties due to impure monomers and low molecular weights. Multiple lots of an HPA-immobilized fluoropolymer derived from preformed PVDF-HFP (Generation III films) were synthesized and formed into membranes at 3M and characterized at 3M to exhibit conductivity reaching approximately 75mS/cm at 120°C/40%RH using a Bekktech sample fixture and TestEquity oven (optimized membrane, at close of program). Initial fuel cell fabrication and testing for this new class of membrane yielded negative results (no measureable proton conductivity); however, the specific early membrane that was used for the two 5cm2 MEAs was later determined to have <1 mS/cm at 80°C/80%RH using the Bekktech fixture, vs. ca. 200 mS/cm at 80°C/80%RH for samples of the later-optimized type described above. Future work in this area (beyond the presently reported contract) should include additional attempts to fabricate and test fuel cells based on the later-optimized Generation II and III polymer. A manufacturing study was performed which predicted no difficulties in any future scale up of the materials.

  9. Synthesis and reactions of Cp-linked phosphine complexes of rhodium

    SciTech Connect (OSTI)

    Lefort, L.; Crane, T.W.; Farwell, M.D.; Baruch, D.M.; Kaeuper, J.A.; Lachicotte, R.J.; Jones, W.D.

    1998-08-31

    The linked Cp ligand [C{sub 5}H{sub 4}SiMe{sub 2}CH{sub 2}PPh{sub 2}]{sup {minus}} has been used to synthesize several rhodium derivatives. Reaction with [RhClL{sub 2}]{sub 2} where L = C{sub 2}H{sub 4}, C{sub 8}H{sub 14}, or CO, gives ({eta}{sup 5}:{eta}{sup 1}-C{sub 5}H{sub 4}SiMe{sub 2}-CH{sub 2}PPh{sub 2})Rh(L) complexes, which have been characterized by single-crystal X-ray diffraction. Reaction of the ethylene complex with CO or PMe{sub 3} gives the carbonyl- and phosphine-substituted derivatives, respectively. Irradiation of the ethylene complex in the presence of hydrogen gives a new binuclear polyhydride, also structurally characterized, in which the chelating ligand spans the two metal centers. Reaction of the ethylene complex with iodine leads to the formation of the diiodide ({eta}{sup 5}:{eta}{sup 1}-C{sub 5}H{sub 4}SiMe{sub 2}CH{sub 2}PPh{sub 2})RhI{sub 2}, which in turn can be converted to the dihydride ({eta}{sup 5}:{eta}{sup 1}-C{sub 5}H{sub 4}SiMe{sub 2}CH{sub 2}PPh{sub 2})RhH{sub 2} by reaction with NaAl(OCH{sub 2}CH{sub 2}OCH{sub 3}){sub 2}H{sub 2}. The reactivity of the dihydride toward C-H bond activation has been investigated. While benzene does not give a stable oxidative addition adduct, pentafluorobenzene yields ({eta}{sup 5}:{eta}{sup 1}-C{sub 5}H{sub 4}SiMe{sub 2}CH{sub 2}PPh{sub 2})Rh(C{sub 6}F{sub 5})H, which was structurally characterized as its chloro derivative. Reaction of the dihydride with C{sub 6}F{sub 6} gives the {eta}{sup 2} complex ({eta}{sup 5}:{eta}{sup 1}-C{sub 5}H{sub 4}SiMe{sub 2}CH{sub 2}PPh{sub 2})Rh({eta}{sup 2}-C{sub 6}F{sub 6}), also structurally characterized.

  10. Nanoamorphous carbon-based photonic crystal infrared emitters

    DOE Patents [OSTI]

    Norwood, Robert A. (Tucson, AZ); Skotheim, Terje (Tucson, AZ)

    2011-12-13

    Provided is a tunable radiation emitting structure comprising: a nanoamorphous carbon structure having a plurality of relief features provided in a periodic spatial configuration, wherein the relief features are separated from each other by adjacent recessed features, and wherein the nanoamorphous carbon comprises a total of from 0 to 60 atomic percent of one or more dopants of the dopant group consisting of: transition metals, lanthanoids, electro-conductive carbides, silicides and nitrides. In one embodiment, a dopant is selected from the group consisting of: Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, La and other lanthanides, Hf, Ta, W, Rh, Os, Ir, Pt, Au, and Hg. In one embodiment, a dopant is selected from the group consisting of: electro-conductive carbides (like Mo.sub.2C), silicides (like MoSi.sub.2) and nitrides (like TiN).

  11. Investigation of electroreduction kinetics on modified p-InP in alkaline electrolyte

    SciTech Connect (OSTI)

    Cook, R.L.; Dempsey, P.P.; Sammells, A.F.

    1985-06-01

    The electroreduction kinetics of surface modified p-InP were investigated. The surface was modifie by electrodeposition of Co, Ru, Rh, Pt, Co/Pt, Ru/Pt, and Rh/Pt. Exchange current densities (i/sub 0/) for hydrogen evolution were obtained both in the dark and under 100 mW/cm/sub 2/ illumination. For sequentially deposited metals i/sub 0/ values are lower compared to individually deposited metals during hydrogen evolution. Cathodic currents observed positive of the hydrogen-evolution region can be explained by electron-transfer processes involving p-InP surface states. In this latter potential region, i/sub 0/ values are higher for the sequentially deposited metals.

  12. Time-resolved photoelectrochemical measurements on surface-modified n- and p-InP electrodes

    SciTech Connect (OSTI)

    Cook, R.L.; Dempsey, P.F.; Sammells, A.F.

    1986-11-01

    Time-resolved photoelectrochemical measurements following illumination with a pulsed laser source have been performed on surface-modified n- and p-InP photoelectrodes. The rate of the initial fast transient photopotential decay was shown to be sensitive to the nature of the surface modification used. The chemisorption of Ru ions onto the n-InP surface reduced the rapid initial decay of the transient photopotential response observed on the unmodified n-InP surface. It is proposed that Ru/sup 3+/ chemisorption may effectively reduce surface trap density at the interface region. For p-InP either unmodified or modified by Co, Rh, Pt, Pb, Rh/Pt, or Co/Pt, the transient photopotential decay exhibited a two segment response. The fast initial decay was found dependent on the previous surface treatment of the p-InP electrode. The second slower decay, however, was found independent of previous surface treatments.

  13. Materials Testing for PV Module Encapsulation

    SciTech Connect (OSTI)

    Jorgensen, G.; Terwilliger, K.; Glick, S.; Pern, J.; McMahon, T.

    2003-05-01

    Important physical properties of materials used in PV module packaging are presented. High-moisture-barrier, high-resistivity, adhesion-promoting coatings on polyethyl-ene terephthalate (PET) films have been fabricated and characterized for use in PV module application and com-pared to standard polymer backsheet materials. Ethylene vinyl acetate (EVA) and an encapsulant replacement for EVA are studied for their water vapor transmission rate (WVTR) and adhesion properties. WVTR, at test conditions up to 85C/100% relative humidity (RH), and adhesion val-ues are measured before and after filtered xenon arc lamp ultraviolet (UV) exposure and damp heat exposure at 85C/85% RH. Water ingress is quantified by weight gain and embedded humidity sensors.

  14. Genetic Evidence for the Phylogenetic Relationship between Na-Dene and Yeniseian Speakers

    E-Print Network [OSTI]

    Rubicz, Rohina; Melvin, Kristin L.; Crawford, Michael H.

    2002-12-01

    *O, MN*M, RH*R1, RH*R2, GM*AG, GM*AXG, KM*]) from three blood group systems and immunoglobulins. The first principal component accounts for 55.8% of the total variation and separates the Na-Dene (AP, DG, HA, and NV) from the Siberian populations (AE, CC..., EK, FN, KT, and 748 / RUBICZ ET AL. 0.3 NG FN '-. 0.2 - C..' 0 0.1 DG a) c HA *L) 0.0 -. ,---- ,---,,,,,---- ,,,,---- ,-- ,,,-,,,,,---,,,,,,,----............ AE NV CC -0.1 -EK * AP A~KT -0.2 -0.1 0.0 0.1 0.2 0.3 0.4 Eigenvector 1 - 55.8% Figure 2...

  15. Case Studies of Commissioning HVAC Systems 

    E-Print Network [OSTI]

    Browning, B. K.

    2001-01-01

    and changed in character, but not eliminated. As shown by Figure 3, the space relative humidity was still very high, but now the problem was primarily during unoccupied periods. 70.0 72.5 75.0 77.5 60 70 80 60 80 17 Sun 18 Mon 19 Tue 20 Wed 21 Thu 22 Fri 23... & condenser. He felt it was wise to check before starting the system. 70 75 80 60 70 80 60 70 80 29 Sat May 99 30 Sun 31 Mon 1 Jun 2 Wed 3 Thu 4 Fri Deg FDeg F% RH se7.pl1 Space Temp 1-2 Supply Temp Space RH Figure 6 - Space Temp, Supply Temp, & Relative...

  16. Enantioselective Intramolecular Hydroarylation of Alkenes via Directed C-H Bond Activation

    SciTech Connect (OSTI)

    Harada, Hitoshi; Thalji, Reema; Bergman, Robert; Ellman, Jonathan

    2008-05-22

    Highly enantioselective catalytic intramolecular ortho-alkylation of aromatic imines containing alkenyl groups tethered at the meta position relative to the imine directing group has been achieved using [RhCl(coe){sub 2}]{sub 2} and chiral phosphoramidite ligands. Cyclization of substrates containing 1,1- and 1,2-disubstituted as well as trisubstituted alkenes were achieved with enantioselectivities >90% ee for each substrate class. Cyclization of substrates with Z-alkene isomers proceeded much more efficiently than substrates with E-alkene isomers. This further enabled the highly stereoselective intramolecular alkylation of certain substrates containing Z/E-alkene mixtures via a Rh-catalyzed alkene isomerization with preferential cyclization of the Z-isomer.

  17. Contributions to Intertemporal Models in Financial Economics

    E-Print Network [OSTI]

    Gopalan, Ramu

    2008-08-15

    space is RL, where L = H D. An element x in RL is called a consumption, that is x = (x( )) 2D2RL, where x( ) = (x(h; ))h2H2RH, for every 2D. We denote by p = (p( )) 2D 2 RL the vector of spot prices and p( ) = (p(h; ))h2H2RH is called the spot price... at node . The spot price p(h; ) is the price paid, at date t( ), for the delivery of one unit of the physical good h at node . Thus the value of the consumption x( ) at node 2D (evaluated in unit of account of node ) is p( ) H x( ) = X h2H p(h; )x...

  18. ASME 

    E-Print Network [OSTI]

    Unknown

    2011-08-17

    CROMER CYCLE AIR CONDITIONER: A STUDY TO CONFIRM TARGET PERFORMANCE Charles J. Cromer, Ph.D., P.E., Program Director, Florida Solar Energy Center, Cocoa, FL ABSTRACT The Cromer cycle uses a desiccant wheel operating in conjunction with a... on Standard AC System. Day Time Amb F Watt-hr Cfm InRH OutRH In F Out F 52 1410 95.227 3230.0 943.20 45.600 99.934 80.925 56.243 52 1420 95.128 3230.0 944.83 45.868 99.930 80.846 56.213 52 1430 95.238 3230.0 943.20 46.086 99.926 80.658 56...

  19. Commercial Feedings Stuffs 1913: Feed Law. 

    E-Print Network [OSTI]

    Youngblood, B.

    1914-01-01

    EXPERIMENT STATION B u l l e t in Bul eti A p r i l , 1914 FEED CONTROL SERVICE Commercial Feeding Stuffs 1913 FEED LAW nAprA,,E.Hs .uLLJaJ pRTRSuWm KyTouP .uCWRhm rJgTPl 3AB KA0.0OMBBIFABHp .Alm ndEBrHdpm MfprEBm rH1Mp AGRICULTURAL AND MECHANICAL... COLLEGE OF TEXAS . 9 T y L J P n C y h J T y m President Pro Tern. rH1Mp M4dE.fxrfdMx H1nHdEOHBr prMrEAB BOARD OF DIRECTORS Hl Kl . CP9SWam Presidentm GuCPRuWllll lllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllllll r...

  20. Optimization of Rhodium-Based Catalysts for Mixed Alcohol Synthesis -- 2011 Progress Report

    SciTech Connect (OSTI)

    Gerber, Mark A.; Gray, Michel J.; Albrecht, Karl O.; Rummel, Becky L.

    2011-10-01

    Pacific Northwest National Laboratory has been conducting research to investigate the feasibility of producing mixed alcohols from biomass-derived synthesis gas (syngas). In recent years, this research has primarily involved the further development of catalysts containing rhodium and manganese based on the results of earlier catalyst screening tests. Research during FY 2011 continued to examine the performance of RhMn catalysts on alternative supports including selected zeolite, silica, and carbon supports. Catalyst optimization continued using both the Davisil 645 and Merck Grade 7734 silica supports. Research also was initiated in FY 2011, using the both Davisil 645 silica and Hyperion CS-02C-063 carbon supports, to evaluate the potential for further improving catalyst performance, through the addition of one or two additional metals as promoters to the catalysts containing Rh, Mn, and Ir.

  1. Effect of humid air exposure on photoemissive and structural properties of KBr thin film photocathode

    E-Print Network [OSTI]

    Rai, R; Ghosh, N; Singh, B K

    2014-01-01

    We have investigated the influence of water molecule absorption on photoemissive and structural properties of potassium bromide (KBr) thin film photocathode under humid air exposure at relative humidity (RH) 65%. It is evident from photoemission measurement that the photoelectron yield of KBr photocathode is degraded exponentially with humid air exposed time. Structural studies of the "as-deposited" and "humid air aged" films reveal that there is no effect of RH on film's crystalline face centered cubic (fcc) structure. However, the average crystallite size of "humid air exposed film" KBr film has been increased as compared to "as-deposited". In addition, topographical properties of KBr film are also examined by means of scanning electron microscope (SEM), transmission electron microscope (TEM) and atomic force microscope (AFM) and it is observed that granular characteristic of film has been altered, even for short exposure to humid air.

  2. Optimization of Rhodium-Based Catalysts for Mixed Alcohol Synthesis – 2012 Progress Report

    SciTech Connect (OSTI)

    Gerber, Mark A.; Gray, Michel J.; Albrecht, Karl O.; Thompson, Becky L.

    2012-11-01

    Pacific Northwest National Laboratory has been conducting research to investigate the feasibility of producing mixed alcohols from biomass-derived synthesis gas (syngas). In recent years, this research has primarily involved the further development of catalysts containing rhodium and manganese based on the results of earlier catalyst screening tests. Testing continued in FY 2012 to further improve the Ir-promoted RhMn catalysts on both silica and carbon supports for producing mixed oxygenates from synthesis gas. This testing re-examined selected alternative silica and carbon supports to follow up on some uncertainties in the results with previous test results. Additional tests were conducted to further optimize the total and relative concentrations of Rh, Mn, and Ir, and to examine selected promoters and promoter combinations based on earlier results. To establish optimum operating conditions, the effects of the process pressure and the feed gas composition also were evaluated.

  3. MeV sterile neutrinos in low reheating temperature cosmological scenarios

    SciTech Connect (OSTI)

    Gelmini, Graciela; Osoba, Efunwande [Department of Physics and Astronomy, UCLA, Los Angeles, CA 90095 (United States)] [Department of Physics and Astronomy, UCLA, Los Angeles, CA 90095 (United States); Palomares-Ruiz, Sergio; Pascoli, Silvia, E-mail: gelmini@physics.ucla.edu, E-mail: eosoba@ucla.edu, E-mail: sergio.palomares-ruiz@durham.ac.uk, E-mail: sergio.palomares.ruiz@ist.utl.pt, E-mail: silvia.pascoli@durham.ac.uk [IPPP, Department of Physics, Durham University, Durham DH1 3LE (United Kingdom)] [IPPP, Department of Physics, Durham University, Durham DH1 3LE (United Kingdom)

    2008-10-15

    It is commonly assumed that the cosmological and astrophysical bounds on the mixings of sterile with active neutrinos are much more stringent than those obtained from laboratory measurements. We point out that in scenarios with a very low reheating temperature T{sub RH}<<100 MeV at the end of (the last episode of) inflation or entropy creation, the abundance of sterile neutrinos becomes greatly suppressed with respect to that obtained within the standard framework. Thus, in this case cosmological bounds become much less stringent than usually assumed, allowing sterile neutrinos to be 'visible' in future experiments. Here, we concentrate on massive (mostly sterile) neutrinos with masses m{sub s}>1 MeV for T{sub RH}{<=}m{sub s}.

  4. Fluidized bed boiler having a segmented grate

    DOE Patents [OSTI]

    Waryasz, Richard E. (Longmeadow, MA)

    1984-01-01

    A fluidized bed furnace (10) is provided having a perforate grate (9) within a housing which supports a bed of particulate material including some combustibles. The grate is divided into a plurality of segments (E2-E6, SH1-SH5, RH1-RH5), with the airflow to each segment being independently controlled. Some of the segments have evaporating surface imbedded in the particulate material above them, while other segments are below superheater surface or reheater surface. Some of the segments (E1, E7) have no surface above them, and there are ignitor combustors (32, 34) directed to fire into the segments, for fast startup of the furnace without causing damage to any heating surface.

  5. Fresnel Reection 9.0.1 polarization

    E-Print Network [OSTI]

    Palffy-Muhoray, Peter

    Chapter 9 Fresnel Reection 9.0.1 polarization: iE rE tE i r t 1 2 iH rH tH iE rE tE i r t 1 2 iH r t (9.2) 1 #12;2 CHAPTER 9. FRESNEL REFLECTION Boundary conditions for the tangential components of H For polarization, we have #12;4 CHAPTER 9. FRESNEL REFLECTION iE rE tE i r t 1 2 iH rH tH iE rE tE i r t 1 2 iH r

  6. Pathogenic variation and morphological studies of Macrophomina phaseolina (Tassi) Goid 

    E-Print Network [OSTI]

    Diourte, Mamourou

    1987-01-01

    . 00g). 0 Ii, th g t p ntag c y af ti. Oh iin from nonlesion areas than lesion areas {Table 4 and b). The single exception was for the sorghum isolate (lg(P16) on sorghum (Table 4). Tabl 4, P t g fetofey f~hho i gh se li f o splhtfootsof~shb l... atesa Cultivars Control MPT MPR MPC TX 7000 R9188 CSM63 1. 2' 1. 3 3. 0 1. 0 1. 4 4. 4 1. 8 I. g 7. 3 1. 1 1. 0 4. 4 MPT= ~dh i Rh 9 oil ~ a is 1 t d f hlti TRT000 Mpt= ~hh 1 Rh ofi 1 t d fro c itis tsM63 MPR= ~hho i ~hs oil 1 1 t d f lti...

  7. Effect of electrical stimulation on bacteria of meats 

    E-Print Network [OSTI]

    Mrigadat, Boosya

    1979-01-01

    0 rH rd 0 rd 0 Qj K 0j 0 rtf 0 'U Qt 0 0 JQ 0 'tf Ql 0 Cl I 0 0 rH rd 0 0J 0 IQ U 0 I Cj '0 M rd O 0 M rd Z Qj 0 rtf 0 rd Qt C 0 W tH '0 A rd 0 Qj 0 rd E 0 0 dj JJ W JJ td Qi W Ut 0 Qj Ql JQ St 0 '0 Qj... '0 rd 0 rd U Ul Qj K td 0 Qt Ql 0 4 ~ j 0 tQ K 0 0 0 rd rd 0 Qf a 0 rd dj Qj 0r 0 JJ rtf E Qj 0 IQ I round (adductor and semimembranosus) and subprimal por tions of rib (9th, 10th and 11th rib section) and loin (2nd ? 5...

  8. Experimental study of the structure of rich premixed 1,3-butadiene/CH4/O2/Ar flame

    E-Print Network [OSTI]

    Gueniche, Hadj-Ali; Fournet, René; Battin-Leclerc, Frédérique

    2006-01-01

    The structure of a laminar rich premixed 1,3-C4H6/CH4/O2/Ar flame have been investigated. 1,3-Butadiene, methane, oxygen and argon mole fractions are 0.033; 0.2073; 0.3315, and 0.4280, respectively, for an equivalent ratio of 1.80. The flame has been stabilized on a burner at a pressure of 6.7 kPa (50 Torr). The concentration profiles of stable species were measured by gas chromatography after sampling with a quartz probe. Quantified species included carbon monoxide and dioxide, methane, oxygen, hydrogen, ethane, ethylene, acetylene, propyne, allene, propene, cyclopropane, 1,3-butadiene, butenes, 1-butyne, vinylacetylene, diacetylene, C5 compounds, benzene, and toluene. The temperature was measured thanks to a thermocouple in PtRh (6%)-PtRh (30%) settled inside the enclosure and ranged from 900 K close to the burner up to 2100 K.

  9. Photoinduced Ligand Exchange and Covalent DNA Binding by Two New Dirhodium Bis-Amidato Complexes

    E-Print Network [OSTI]

    Turro, Claudia

    : Two new dirhodium complexes, the head-to-tail (H,T) and head-to-head (H,H) isomers of cis-[Rh2(HNOCCH3 to the amidato nitrogen atoms, CH3CNeq N . When aqueous solutions of the complexes are irradiated with low energy]2+ ; importantly, no ligand exchange is observed when the complexes are kept in the dark. Finally, low energy

  10. Laser photoelectron spectroscopy of ions

    SciTech Connect (OSTI)

    Ellison, G.B. [Univ. of Colorado, Boulder (United States)

    1993-12-01

    During the last year the author has (a) completed a review article that critically contrasts three methods to measure R-H bond energies, (b) finished a spectroscopic study of the phenylnitrene anion, and (c) successfully completed an overhaul of the light source of the photodetachment spectrometer. The new light source is based on an Ar III laser that provides approximately 100 W of 3.531 eV photons.

  11. OPERATIONAL NOTE EFFICACY OF DUETTM

    E-Print Network [OSTI]

    of a truck-mounted ultra-low volume (ULV) cold aerosol sprayer at the rate of 90.6 ml/ha. Cages were placed against caged Ae. albopictus (F1 generation) placed up to a distance of 91.5 m with the use of a truck humidity (RH), and 16 light:8 dark photoperiod. Ultra-low volume ground applica- tions were conducted over

  12. Rose F. Kennedy Center is located north of Van Etten, amid

    E-Print Network [OSTI]

    Bukauskas, Feliksas

    NORTH CAMPUS SOUTH CAMPUS Rose F. Kennedy Center is located north of Van Etten, amid Jacobi Medical Pavilion (1301 Morris Park Ave.) VE Van Etten Building (1225 Morris Park Ave.) KE Rose F. Kennedy Center RH E S H I V A U N I V E R S I T Y Albert Einstein College of Medicine P LE CC LW H To Kennedy Center

  13. Directions to the Ecole Normale Suprieure de Lyon The Ecole Normale Suprieure de Lyon

    E-Print Network [OSTI]

    Dauxois, Thierry

    Directions to the Ecole Normale Supérieure de Lyon The Ecole Normale Supérieure de Lyon is located in Gerland, a neighborhood in the southern part of Lyon, not far from the Rhône river and the Halle Tony. How to get to l'ENS-Lyon ... #12;· From Lyon-Saint Exupéry (Satolas) airport Every 20 min, a shuttle

  14. Luminescence imaging for aerodynamic temperature and pressure measurements

    SciTech Connect (OSTI)

    Gallery, J.M.

    1993-01-01

    A luminescent temperature sensitive paint containing the molecule rhodamine B base (rhBb) is described whose emission intensity can be monitored by video camera to produce qualitative and quantitative two dimensional surface temperature maps. This paint was designed for use with the pressure sensitive paint containing platinum octaethylporphyrin (PtOEP), but is also a useful tool when used alone in the measurement of heat flow, boundary layer transition, and quantitative surface temperature during wind tunnel studies. The ability of the rhBb paint to produce a continuous temperature map makes it possible to locate structures in the temperature field on an airfoil that are otherwise undetected by surface mounted thermocouples spaced a finite distance apart. A dual temperature/pressure sensitive paint was investigated with both the rhBb and PtOEP dyes incorporated into the silicone polymer paint base of the pressure sensor. Photodegradation and batch variations in the polymer were found to compromise the calibration parameters of the PtOEP paint and therefore the accuracy of pressure predictions. Suggestions are made for improving the prediction ability of the paint. The molecule europium(III) thenoyltrifluoroacetonate (EuTTA) is also discussed as a temperature sensor for a two layer temperature/pressure paint. EuTTA can not be directly incorporated into the silicone paint base of the PtOEP paint (as the rhBp paint can), but performs well in non-oxygenpermeable coatings. Benefits of the EuTTA temperature paint include: (1) decreased photodegradation, (2) very bright luminescence intensity, and (3) long luminescent lifetime (several hundred microseconds). The long lifetime facilitates lifetime imaging, a technique currently under development as an alternative detection method where luminescent lifetimes rather than emission intensity are related to temperature and pressure.

  15. Studies of Immobilized Homogeneous Metal Catalysts on Silica Supports

    SciTech Connect (OSTI)

    Keith James Stanger

    2003-05-31

    The tethered, chiral, chelating diphosphine rhodium complex, which catalyzes the enantioselective hydrogenation of methyl-{alpha}-acetamidocinnamate (MAC), has the illustrated structure as established by {sup 31}P NMR and IR studies. Spectral and catalytic investigations also suggest that the mechanism of action of the tethered complex is the same as that of the untethered complex in solution. The rhodium complexes, [Rh(COD)H]{sub 4}, [Rh(COD){sub 2}]{sup +}BF{sub 4}{sup -}, [Rh(COD)Cl]{sub 2}, and RhCl{sub 3} {center_dot} 3H{sub 2}O, adsorbed on SiO{sub 2} are optimally activated for toluene hydrogenation by pretreatment with H{sub 2} at 200 C. The same complexes on Pd-SiO{sub 2} are equally active without pretreatments. The active species in all cases is rhodium metal. The catalysts were characterized by XPS, TEM, DRIFTS, and mercury poisoning experiments. Rhodium on silica catalyzes the hydrogenation of fluorobenzene to produce predominantly fluorocyclohexane in heptane and 1,2-dichloroethane solvents. In heptane/methanol and heptane/water solvents, hydrodefluorination to benzene and subsequent hydrogenation to cyclohexane occurs exclusively. Benzene inhibits the hydrodefluorination of fluorobenzene. In DCE or heptane solvents, fluorocyclohexane reacts with hydrogen fluoride to form cyclohexene. Reaction conditions can be chosen to selectively yield fluorocyclohexane, cyclohexene, benzene, or cyclohexane. The oxorhenium(V) dithiolate catalyst [-S(CH{sub 2}){sub 3}s-]Re(O)(Me)(PPh{sub 3}) was modified by linking it to a tether that could be attached to a silica support. Spectroscopic investigation and catalytic oxidation reactivity showed the heterogenized catalyst's structure and reactivity to be similar to its homogeneous analog. However, the immobilized catalyst offered additional advantages of recyclability, extended stability, and increased resistance to deactivation.

  16. Port Orford folio, Oregon. 

    E-Print Network [OSTI]

    Diller, J. S. (Joseph Silas), b. 1850.

    1903-01-01

    Active Surface for CO Oxidation ........................................... 52 CO Oxidation on Pt(100) at CO:O 2 Ratios of 1:1, 1:5, 1:10..... 56 V Pd(100) OXIDATION AND CO OXIDATION ON Pd(100) ........ 66 Introduction... of temperature of a clean Rh single crystal exposed to 1:1 CO:O 2 at a total pressure of 2x10 -7 torr. R max denotes the temperature with the highest CO 2 formation. ...................................................... 39 Figure 14 XPS...

  17. Solid Waste Processing Center Primary Opening Cells Systems, Equipment and Tools

    SciTech Connect (OSTI)

    Bailey, Sharon A.; Baker, Carl P.; Mullen, O Dennis; Valdez, Patrick LJ

    2006-04-17

    This document addresses the remote systems and design integration aspects of the development of the Solid Waste Processing Center (SWPC), a facility to remotely open, sort, size reduce, and repackage mixed low-level waste (MLLW) and transuranic (TRU)/TRU mixed waste that is either contact-handled (CH) waste in large containers or remote-handled (RH) waste in various-sized packages.

  18. Hydroformylation of Mixed Octenes Using RhodiumBulky Phosphonite Complexes with Excellent Catalytic Activity and Stability

    E-Print Network [OSTI]

    Kim, Ji Man

    , and 20.7 wt % of normal octenes. Rh2(CH3CO2)4 was added to a SUS-316 autoclave reactor (300 m via butene dimerization. A C4 fraction obtained by removing butadiene and isobutene from a naphtha,11 After reac- tion, the product containing C4-, C8-, and C12 fraction was dis- tilled to separate a C8

  19. Defense Remote Handled Transuranic Waste Cost/Schedule Optimization Study

    SciTech Connect (OSTI)

    Pierce, G.D. . Joint Integration Office); Beaulieu, D.H. ); Wolaver, R.W.; Carson, P.H. Corp., Boulder, CO )

    1986-11-01

    The purpose of this study is to provide the DOE information with which it can establish the most efficient program for the long management and disposal, in the Waste Isolation Pilot Plant (WIPP), of remote handled (RH) transuranic (TRU) waste. To fulfill this purpose, a comprehensive review of waste characteristics, existing and projected waste inventories, processing and transportation options, and WIPP requirements was made. Cost differences between waste management alternatives were analyzed and compared to an established baseline. The result of this study is an information package that DOE can use as the basis for policy decisions. As part of this study, a comprehensive list of alternatives for each element of the baseline was developed and reviewed with the sites. The principle conclusions of the study follow. A single processing facility for RH TRU waste is both necessary and sufficient. The RH TRU processing facility should be located at Oak Ridge National Laboratory (ORNL). Shielding of RH TRU to contact handled levels is not an economic alternative in general, but is an acceptable alternative for specific waste streams. Compaction is only cost effective at the ORNL processing facility, with a possible exception at Hanford for small compaction of paint cans of newly generated glovebox waste. It is more cost effective to ship certified waste to WIPP in 55-gal drums than in canisters, assuming a suitable drum cask becomes available. Some waste forms cannot be packaged in drums, a canister/shielded cask capability is also required. To achieve the desired disposal rate, the ORNL processing facility must be operational by 1996. Implementing the conclusions of this study can save approximately $110 million, compared to the baseline, in facility, transportation, and interim storage costs through the year 2013. 10 figs., 28 tabs.

  20. A Note on Ramsey Size-Linear Graphs

    E-Print Network [OSTI]

    Simonovits, Miklós

    A Note on Ramsey Size-Linear Graphs P.N. Balister,1 R.H. Schelp,1 and M. Simonovits1,2 1 DEPARTMENT is a Ramsey size-linear graph and x,y 2 V(G ) then if we add a sufficiently long path between x and y we obtain a new Ramsey size-linear graph. As a consequence we show that if G is any graph such that every