National Library of Energy BETA

Sample records for rh ir mt

  1. Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts

    SciTech Connect (OSTI)

    Mei, Donghai; Lebarbier, Vanessa MC; Rousseau, Roger J.; Glezakou, Vassiliki Alexandra; Albrecht, Karl O.; Kovarik, Libor; Flake, Matthew D.; Dagle, Robert A.

    2013-06-01

    In a combined experimental and first-principles density functional theory (DFT) study, benzene steam reforming (BSR) over MgAl2O4 supported Rh and Ir catalysts was investigated. Experimentally, it has been found that both highly dispersed Rh and Ir clusters (1-2 nm) on the MgAl2O4 spinel support are stable during the BSR in the temperature range of 700-850?C. Compared to the Ir/MgAl2O4 catalyst, the Rh/MgAl2O4 catalyst is more active with higher benzene turnover frequency and conversion. At typical steam conditions with the steam-to-carbon ratio > 12, the benzene conversion is only a weak function of the H2O concentration in the feed. This suggests that the initial benzene decomposition step rather than the benzene adsorption is most likely the rate-determined step in BSR over supported Rh and Ir catalysts. In order to understand the differences between the two catalysts, we followed with a comparative DFT study of initial benzene decomposition pathways over two representative model systems for each supported metal (Rh and Ir) catalysts. A periodic terrace (111) surface and an amorphous 50-atom metal cluster with a diameter of 1.0 nm were used to represent the two supported model catalysts under low and high dispersion conditions. Our DFT results show that the decreasing catalyst particle size enhances the benzene decomposition on supported Rh catalysts by lowering both C-C and C-H bond scission. The activation barriers of the C-C and the C-H bond scission decrease from 1.60 and 1.61 eV on the Rh(111) surface to 1.34 and 1.26 eV on the Rh50 cluster. For supported Ir catalysts, the decreasing particle size only affects the C-C scission. The activation barrier of the C-C scission of benzene decreases from 1.60 eV on the Ir(111) surface to 1.35 eV on the Ir50 cluster while the barriers of the C-H scission are practically the same. The experimentally measured higher BSR activity on the supported highly dispersed Rh catalyst can be rationalized by the thermodynamic limitation for the very first C-C bond scission of benzene on the small Ir50 catalyst. The C-C bond scission of benzene on the small Ir50 catalyst is highly endothermic although the barrier is competitive with the barriers of both the C-C and the C-H bond-breakings on the small Rh50 catalyst. The calculations also imply that, for the supported Rh catalysts the C-C and C-H bond scissions are competitive, independently of the Rh cluster sizes. After the initial dissociation step via either the C-C or the C-H bond scission, the C-H bond breaking seems to be more favorable rather than the C-C bond breaking on the larger Rh terrace surface. This work was financially supported by the United States Department of Energy’s Office of Biomass Program’s. Computing time was granted by a user project at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  2. Anisotropic intermediate valence in Yb2M3Ga9 (M = Rh, Ir)

    SciTech Connect (OSTI)

    Christianson, A.D.; Lawrence, J.M.; Lobos, A.M.; Aligia, A.A.; Bauer, E.D.; Moreno, N.O.; Booth, C.H.; Goremychkin, E.A.; Sarrao, J.L.; Thompson, J.D.; Batista, C.D.; Trouw, F.R.; Hehlen, M.P.

    2005-04-26

    The intermediate valence compounds Yb{sub 2}M{sub 3}Ga{sub 9} (M = Rh, Ir) exhibit an anisotropic magnetic susceptibility. We report measurements of the temperature dependence of the 4f occupation number, n{sub f}(T), for Yb{sub 2}M{sub 3}Ga{sub 9} as well as the magnetic inelastic neutron scattering spectrum S{sub mag}({Delta}E) at 12 and 300 K for Yb{sub 2}Rh{sub 3}Ga{sub 9}. Both n{sub f}(T) and S{sub mag}({Delta}E) were calculated for the Anderson impurity model with crystal field terms within an approach based on the non-crossing approximation. These results corroborate the importance of crystal field effects in these materials; they also suggest that Anderson lattice effects are important to the physics of Yb{sub 2}M{sub 3}Ga{sub 9}.

  3. Investigation of the physical properties of the tetragonal CeMAl4Si2 (M = Rh, Ir, Pt) compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ghimire, N. J.; Ronning, F.; Williams, D. J.; Scott, B. L.; Luo, Yongkang; Thompson, J. D.; Bauer, E. D.

    2014-12-15

    The synthesis, crystal structure and physical properties studied by means of x-ray diffraction, magnetic, thermal and transport measurements of CeMAl4Si2 (M = Rh, Ir, Pt) are reported, along with the electronic structure calculations for LaMAl4Si2 (M = Rh, Ir, Pt). These materials adopt a tetragonal crystal structure (space group P4/mmm) comprised of BaAl4 blocks, separated by MAl2 units, stacked along the c-axis. Both CeRhAl4Si2 and CeIrAl4Si2 order antiferromagnetically below TN1 = 14 and 16 K, respectively, and undergo a second antiferromagnetic transitition at lower temperature (TN2 = 9 and 14 K, respectively). CePtAl4Si2 orders ferromagnetically below TC = 3 Kmore »with an ordered moment of ?sat = 0.8 ?B for a magnetic field applied perpendicular to the c-axis. Electronic structure calculations reveal quasi-2D character of the Fermi surface.« less

  4. Highly Active and Stable MgAl2O4 Supported Rh and Ir Catalysts for Methane Steam Reforming: A Combined Experimental and Theoretical Study

    SciTech Connect (OSTI)

    Mei, Donghai; Glezakou, Vassiliki Alexandra; Lebarbier, Vanessa MC; Kovarik, Libor; Wan, Haiying; Albrecht, Karl O.; Gerber, Mark A.; Rousseau, Roger J.; Dagle, Robert A.

    2014-07-01

    In this work we present a combined experimental and theoretical investigation of stable MgAl2O4 spinel-supported Rh and Ir catalysts for the steam methane reforming (SMR) reaction. Firstly, catalytic performance for a series of noble metal catalysts supported on MgAl2O4 spinel was evaluated for SMR at 600-850°C. Turnover rate at 850°C follows the order: Pd > Pt > Ir > Rh > Ru > Ni. However, Rh and Ir were found to have the best combination of activity and stability for methane steam reforming in the presence of simulated biomass-derived syngas. It was found that highly dispersed ~2 nm Rh and ~1 nm Ir clusters were formed on the MgAl2O4 spinel support. Scanning Transition Electron Microscopy (STEM) images show that excellent dispersion was maintained even under challenging high temperature conditions (e.g. at 850°C in the presence of steam) while Ir and Rh catalysts supported on Al2O3 were observed to sinter at increased rates under the same conditions. These observations were further confirmed by ab initio molecular dynamics (AIMD) simulations which find that ~1 nm Rh and Ir particles (50-atom cluster) bind strongly to the MgAl2O4 surfaces via a redox process leading to a strong metal-support interaction, thus helping anchor the metal clusters and reduce the tendency to sinter. Density functional theory (DFT) calculations suggest that these supported smaller Rh and Ir particles have a lower work function than larger more bulk-like ones, which enables them to activate both water and methane more effectively than larger particles, yet have a minimal influence on the relative stability of coke precursors. In addition, theoretical mechanistic studies were used to probe the relationship between structure and reactivity. Consistent with the experimental observations, our theoretical modeling results also suggest that the small spinel-supported Ir particle catalyst is more active than the counterpart of Rh catalyst for SMR. This work was financially supported by the United States Department of Energy (DOE)’s Bioenergy Technologies Office (BETO) and performed at the Pacific Northwest National Laboratory (PNNL). PNNL is a multi-program national laboratory operated for DOE by Battelle Memorial Institute. Computing time was granted by a user proposal at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) located at PNNL. Part of the computational time was provided by the National Energy Research Scientific Computing Center (NERSC).

  5. C-H Activation of Phenyl Imines and 2-Phenylpyridines with [Cp*MCl2]2 (M ) Ir, Rh): Regioselectivity, Kinetics, and

    E-Print Network [OSTI]

    Jones, William D.

    both by increasing temperature and by using polar solvents such as methanol. The regioselectivity*RhCl2]2. The regioselectivity was temperature independent for both metals. With added acid, the aromatic

  6. First-principles studies of structural stabilities and enthalpies of formation of refractory intermetallics: TM and TM3 (T = Ti, Zr, Hf; M = Ru, Rh, Pd, Os, Ir, Pt)

    SciTech Connect (OSTI)

    Xing, Weiwei; Chen, X.; Li, Dianzhong; Li, Y. Y.; Fu, Chong Long; Meschel, S.

    2012-01-01

    Using first-principles local density functional approach, we have calculated the ground-state structural phase stabilities and enthalpies of formation of thirty-six binary transition-metal refractory TM and TM3 compounds formed by Group IV elements T (T = Ti, Zr, Hf) and platinum group elements M (M = Ru, Rh, Pd, Os, Ir, Pt) . We compared our results with the available experimental data and found good agreement between theory and experiment in both the trends of structural stabilities and the magnitudes of formation enthalpies. Moreover, based on our calculated results, an empirical relationship between cohesive energies ( E) and melting temperatures (Tm) was derived as Tm = 0.0292 E/kB (where kB is the Boltzmann constant) for both TM and TM3 compounds.

  7. RH Packaging Program Guidance

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2008-01-12

    The purpose of this program guidance document is to provide the technical requirements for use, operation, inspection, and maintenance of the RH-TRU 72-B Waste Shipping Package (also known as the "RH-TRU 72-B cask") and directly related components. This document complies with the requirements as specified in the RH-TRU 72-B Safety Analysis Report for Packaging (SARP), and Nuclear Regulatory Commission (NRC) Certificate of Compliance (C of C) 9212. If there is a conflict between this document and the SARP and/or C of C, the C of C shall govern. The C of C states: "...each package must be prepared for shipment and operated in accordance with the procedures described in Chapter 7.0, Operating Procedures, of the application." It further states: "...each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application." Chapter 9.0 of the SARP tasks the Waste Isolation Pilot Plant (WIPP) Management and Operating (M&O) Contractor with assuring the packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with Title 10 Code of Federal Regulations (CFR) §71.8, "Deliberate Misconduct." Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the U.S. Department of Energy (DOE) Carlsbad Field Office (CBFO) shall be notified immediately. The CBFO will evaluate the issue and notify the NRC if required.In accordance with 10 CFR Part 71, "Packaging and Transportation of Radioactive Material," certificate holders, packaging users, and contractors or subcontractors who use, design, fabricate, test, maintain, or modify the packaging shall post copies of (1) 10 CFR Part 21, "Reporting of Defects and Noncompliance," regulations, (2) Section 206 of the Energy Reorganization Act of 1974, and (3) NRC Form 3, Notice to Employees. These documents must be posted in a conspicuous location where the activities subject to these regulations are conducted. This document details the instructions to be followed to operate, maintain, and test the RH-TRU 72-B packaging. This Program Guidance standardizes instructions for all users. Users shall follow these instructions or equivalent approved instructions. Following these instructions assures that operations meet the requirements of the SARP.

  8. RH-TRU Waste Content Codes (RH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2007-08-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: • A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. • A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is “3.” The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR limits based on a 10-day shipping period (rather than the standard 60-day shipping period) may be used as specified in an approved content code. Requests for new or revised content codes may be submitted to the WIPP RH-TRU Payload Engineer for review and approval, provided all RH-TRAMPAC requirements are met.

  9. Saving Mt. Fuji

    E-Print Network [OSTI]

    Hacker, Randi

    2013-09-12

    Broadcast Transcript: Mt. Fuji, or Fujisan is it is known here in Japan, has just been added to Unesco's World Heritage list as a cultural asset, honoring it for providing thousands of years of inspiration to artists, poets ...

  10. Pipeline MT Instructions Identification Number

    E-Print Network [OSTI]

    Hong, Don

    Pipeline MT Instructions Identification Number For identification purposes, you will be assigned a special identification number. M# You can activate your MT email, login to PipelineMT to register for classes or pay tuition and fees. Activating the MTSU Email and PipelineMT accounts: Visit the website

  11. RH Packaging Program Guidance

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2006-11-07

    The purpose of this program guidance document is to provide the technical requirements for use, operation, inspection, and maintenance of the RH-TRU 72-B Waste Shipping Package and directly related components. This document complies with the requirements as specified in the RH-TRU 72-B Safety Analysis Report for Packaging (SARP), and Nuclear Regulatory Commission (NRC) Certificate of Compliance (C of C) 9212. If there is a conflict between this document and the SARP and/or C of C, the C of C shall govern. The C of C states: "...each package must be prepared for shipment and operated in accordance with the procedures described in Chapter 7.0, Operating Procedures, of the application." It further states: "...each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application." Chapter 9.0 of the SARP tasks the Waste Isolation Pilot Plant (WIPP) Management and Operating (M&O) Contractor with assuring the packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with 10 Code of Federal Regulations (CFR) §71.8, "Deliberate Misconduct." Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the U.S. Department of Energy (DOE) Carlsbad Field Office (CBFO) shall be notified immediately. CBFO will evaluate the issue and notify the NRC if required. In accordance with 10 CFR Part 71, "Packaging and Transportation of Radioactive Material," certificate holders, packaging users, and contractors or subcontractors who use, design, fabricate, test, maintain, or modify the packaging shall post copies of (1) 10 CFR Part 21, "Reporting of Defects and Noncompliance," regulations, (2) Section 206 of the Energy Reorganization Act of 1974, and (3) NRC Form 3, Notice to Employees. These documents must be posted in a conspicuous location where the activities subject to these regulations are conducted. This document details the instructions to be followed to operate, maintain, and test the RH-TRU 72-B packaging. This Program Guidance standardizes instructions for all users. Users shall follow these instructions or equivalent approved instructions. Following these instructions assures that operations meet the requirements of the SARP.

  12. RH-TRU Waste Content Codes (RH TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions

    2007-05-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: • A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. • A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is “3.” The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR limits based on a 10-day shipping period (rather than the standard 60-day shipping period) may be used as specified in an approved content code.

  13. Magnitude of the magnetic exchange interaction in the heavy-fermion antiferromagnet CeRhIn?

    SciTech Connect (OSTI)

    Das, Pinaki [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Lin, S. -Z. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Ghimire, N.? J. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Huang, K. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Univ. of California, San Diego, La Jolla, CA (United States); Ronning, F. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Bauer, E.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Thompson, J.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Batista, C.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Ehlers, G. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Janoschek, M. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

    2014-12-01

    We have used high-resolution neutron spectroscopy experiments to determine the complete spin wave spectrum of the heavy-fermion antiferromagnet CeRhIn?. The spin wave dispersion can be quantitatively reproduced with a simple frustrated J??J? model that also naturally explains the magnetic spin-spiral ground state of CeRhIn? and yields a dominant in-plane nearest-neighbor magnetic exchange constant J?=0.74(3)??meV. Our results pave the way to a quantitative understanding of the rich low-temperature phase diagram of the prominent CeTIn? (T = Co, Rh, Ir) class of heavy-fermion materials.

  14. Rh-Based Mixed Alcohol Synthesis Catalysts: Characterization and Computational Report

    SciTech Connect (OSTI)

    Albrecht, Karl O.; Glezakou, Vassiliki Alexandra; Rousseau, Roger J.; Engelhard, Mark H.; Varga, Tamas; Colby, Robert J.; Jaffe, John E.; Li, Xiaohong S.; Mei, Donghai; Windisch, Charles F.; Kathmann, Shawn M.; Lemmon, Teresa L.; Gray, Michel J.; Hart, Todd R.; Thompson, Becky L.; Gerber, Mark A.

    2013-08-01

    The U.S. Department of Energy is conducting a program focused on developing a process for the conversion of biomass to bio-based fuels and co-products. Biomass-derived syngas is converted thermochemically within a temperature range of 240 to 330°C and at elevated pressure (e.g., 1200 psig) over a catalyst. Ethanol is the desired reaction product, although other side compounds are produced, including C3 to C5 alcohols; higher (i.e., greater than C1) oxygenates such as methyl acetate, ethyl acetate, acetic acid and acetaldehyde; and higher hydrocarbon gases such as methane, ethane/ethene, propane/propene, etc. Saturated hydrocarbon gases (especially methane) are undesirable because they represent a diminished yield of carbon to the desired ethanol product and represent compounds that must be steam reformed at high energy cost to reproduce CO and H2. Ethanol produced by the thermochemical reaction of syngas could be separated and blended directly with gasoline to produce a liquid transportation fuel. Additionally, higher oxygenates and unsaturated hydrocarbon side products such as olefins also could be further processed to liquid fuels. The goal of the current project is the development of a Rh-based catalyst with high activity and selectivity to C2+ oxygenates. This report chronicles an effort to characterize numerous supports and catalysts to identify particular traits that could be correlated with the most active and/or selective catalysts. Carbon and silica supports and catalysts were analyzed. Generally, analyses provided guidance in the selection of acceptable catalyst supports. For example, supports with high surface areas due to a high number of micropores were generally found to be poor at producing oxygenates, possibly because of mass transfer limitations of the products formed out of the micropores. To probe fundamental aspects of the complicated reaction network of CO with H2, a computational/ theoretical investigation using quantum mechanical and ab initio molecular dynamics calculations was initiated in 2009. Computational investigations were performed first to elucidate understanding of the nature of the catalytically active site. Thermodynamic calculations revealed that Mn likely exists as a metallic alloy with Rh in Rh-rich environments under reducing conditions at the temperatures of interest. After determining that reduced Rh-Mn alloy metal clusters were in a reduced state, the activation energy barriers of numerous transition state species on the catalytically active metal particles were calculated to compute the activation barriers of several reaction pathways that are possible on the catalyst surface. Comparison of calculations with a Rh nanoparticle versus a Rh-Mn nanoparticle revealed that the presence of Mn enabled the reaction pathway of CH with CO to form an adsorbed CHCO species, which was a precursor to C2+ oxygenates. The presence of Mn did not have a significant effect on the rate of CH4 production. Ir was observed during empirical catalyst screening experiments to improve the activity and selectivity of Rh-Mn catalysts. Thus, the addition of Ir to the Rh-Mn nanoparticles also was probed computationally. Simulations of Rh-Mn-Ir nanoparticles revealed that, with sufficient Ir concentrations, the Rh, Mn and Ir presumably would be well mixed within a nanoparticle. Activation barriers were calculated for Rh-Mn-Ir nanoparticles for several C-, H-, and O-containing transitional species on the nanoparticle surface. It was found that the presence of Ir opened yet another reactive pathway whereby HCO is formed and may undergo insertion with CHx surface moieties. The reaction pathway opened by the presence of Ir is in addition to the CO + CH pathway opened by the presence of Mn. Similar to Mn, the presence of Ir was not found to not affect the rate of CH4 production.

  15. Comment on "Catalytic Activity of the Rh Surface Oxide: CO Oxidation over Rh(111)

    E-Print Network [OSTI]

    Goodman, Wayne

    . Obviously, heating Rh in pure oxygen to T ) 230 °C and above will lead to the formation of surface Rh oxideComment on "Catalytic Activity of the Rh Surface Oxide: CO Oxidation over Rh(111) under Realistic suggest the importance of a surface oxide phase for high CO2 formation in CO-O2 reactions. However

  16. Magnitude of the magnetic exchange interaction in the heavy-fermion antiferromagnet CeRhIn5

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Das, Pinaki; Lin, S. -Z.; Ghimire, N. J.; Huang, K.; Ronning, F.; Bauer, E. D.; Thompson, J. D.; Batista, C. D.; Ehlers, G.; Janoschek, M.

    2014-12-08

    We have used high-resolution neutron spectroscopy experiments to determine the complete spin wave spectrum of the heavy-fermion antiferromagnet CeRhIn?. The spin wave dispersion can be quantitatively reproduced with a simple frustrated J?-J? model that also naturally explains the magnetic spin-spiral ground state of CeRhIn? and yields a dominant in-plane nearest-neighbor magnetic exchange constant J?=0.74(3) meV. Our results lead the way to a quantitative understanding of the rich low-temperature phase diagram of the prominent CeTIn? (T = Co, Rh, Ir) class of heavy-fermion materials.

  17. Radiosondes Corrected for Inaccuracy in RH Measurements

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Miloshevich, Larry

    2008-01-15

    Corrections for inaccuracy in Vaisala radiosonde RH measurements have been applied to ARM SGP radiosonde soundings. The magnitude of the corrections can vary considerably between soundings. The radiosonde measurement accuracy, and therefore the correction magnitude, is a function of atmospheric conditions, mainly T, RH, and dRH/dt (humidity gradient). The corrections are also very sensitive to the RH sensor type, and there are 3 Vaisala sensor types represented in this dataset (RS80-H, RS90, and RS92). Depending on the sensor type and the radiosonde production date, one or more of the following three corrections were applied to the RH data: Temperature-Dependence correction (TD), Contamination-Dry Bias correction (C), Time Lag correction (TL). The estimated absolute accuracy of NIGHTTIME corrected and uncorrected Vaisala RH measurements, as determined by comparison to simultaneous reference-quality measurements from Holger Voemel's (CU/CIRES) cryogenic frostpoint hygrometer (CFH), is given by Miloshevich et al. (2006).

  18. Radiosondes Corrected for Inaccuracy in RH Measurements

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Miloshevich, Larry

    Corrections for inaccuracy in Vaisala radiosonde RH measurements have been applied to ARM SGP radiosonde soundings. The magnitude of the corrections can vary considerably between soundings. The radiosonde measurement accuracy, and therefore the correction magnitude, is a function of atmospheric conditions, mainly T, RH, and dRH/dt (humidity gradient). The corrections are also very sensitive to the RH sensor type, and there are 3 Vaisala sensor types represented in this dataset (RS80-H, RS90, and RS92). Depending on the sensor type and the radiosonde production date, one or more of the following three corrections were applied to the RH data: Temperature-Dependence correction (TD), Contamination-Dry Bias correction (C), Time Lag correction (TL). The estimated absolute accuracy of NIGHTTIME corrected and uncorrected Vaisala RH measurements, as determined by comparison to simultaneous reference-quality measurements from Holger Voemel's (CU/CIRES) cryogenic frostpoint hygrometer (CFH), is given by Miloshevich et al. (2006).

  19. RH-TRU Waste Content Codes

    SciTech Connect (OSTI)

    Washington TRU Solutions

    2007-07-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: • A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. • A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is “3.” The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR limits based on a 10-day shipping period (rather than the standard 60-day shipping period) may be used as specified in an approved content code. Requests for new or revised content codes may be submitted to the WIPP RH-TRU Payload Engineer for review and approval, provided all RH-TRAMPAC requirements are met.

  20. Check for chirality in {sup 102}Rh

    SciTech Connect (OSTI)

    Tonev, D.; Goutev, N.; Yavahchova, M. S.; Petkov, P.; Angelis, G. de; Bhowmik, R. K.; Singh, R. P.; Muralithar, S.; Madhavan, N.; Kumar, R.; Raju, M. Kumar; Kaur, J.; Mahanto, G.; Singh, A.; Kaur, N.; Garg, R.; Sukla, A.; Marinov, Ts. K.; Brant, S.

    2012-10-20

    Excited states in {sup 102}Rh, populated by the fusion-evaporation reaction {sup 94}Zr({sup 11}B,3n){sup 102}Rh at a beam energy of 36 MeV, were studied using the INGA spectrometer at IUAC, New Delhi. The angular correlations and the electromagnetic character of some of the gamma-ray transitions observed were investigated in details. A new chiral candidate sister band was found in the level-scheme of {sup 102}Rh. Lifetimes of exited states in {sup 102}Rh were measured by means of the Doppler-shift attenuation technique. The experimental results do not support the presence of static chirality in {sup 102}Rh.

  1. Ternary Electrocatalysts for Oxidizing Ethanol to Carbon Dioxide: Making Ir Capable of Splitting C-C bond

    SciTech Connect (OSTI)

    Li, Meng; Cullen, David A; Sasaki, Kotaro; Marinkovic, N.; More, Karren Leslie; Adzic, Radoslav R.

    2013-01-01

    Splitting the C-C bond is the main obstacle to electroxidation of ethanol (EOR) to CO2. We recently demonstrated that the ternary PtRhSnO2 electrocatalyst can accomplish that reaction at room temperature with Rh having a unique capability to split the C-C bond. In this article we report the finding that Ir can be induced to split the C-C bond as a component of the ternary catalyst. We synthesized, characterized and compared the properties of several ternary electrocatalysts. Carbon-supported nanoparticle (NP) electrocatalysts comprising a SnO2 NP core decorated with multi-metallic nanoislands (MM = PtIr, PtRh, IrRh, PtIrRh) were prepared using a seeded growth approach. An array of characterization techniques were employed to establish the composition and architecture of the synthesized MM /SnO2 NPs, while electrochemical and in situ infrared reflection absorption spectroscopy studies elucidated trends in activity and the nature of the reaction intermediates and products. Both EOR reactivity and selectivity towards CO2 formation of several of these MM /SnO2/C electrocatalysts are significantly higher compared to conventional Pt/C and Pt/SnO2/C catalysts. We demonstrate that the PtIr/SnO2/C catalyst with high Ir content shows outstanding catalytic property with the most negative EOR onset potential and reasonably good selectivity towards ethanol complete oxidation to CO2. PtRh/SnO2/C catalysts with a moderate Rh content exhibit the highest EOR selectivity, as deduced from infrared studies.

  2. University Policy No.: RH8205 Classification: Research

    E-Print Network [OSTI]

    Victoria, University of

    which requires, as a condition of deducting expenses, that the type of research carried out under the #12;research project be a type of research that is different from the type of research work ordinarilyUniversity Policy No.: RH8205 Classification: Research RESEARCH GRANTS IN LIEU OF Approving

  3. Porous Alumina Based Capacitive MEMS RH Sensor

    E-Print Network [OSTI]

    Juhasz, L; Timar-Horvath, Veronika; Desmulliez, Marc; Dhariwal, Resh

    2008-01-01

    The aim of a joint research and development project at the BME and HWU is to produce a cheap, reliable, low-power and CMOS-MEMS process compatible capacitive type relative humidity (RH) sensor that can be incorporated into a state-of-the-art, wireless sensor network. In this paper we discuss the preparation of our new capacitive structure based on post-CMOS MEMS processes and the methods which were used to characterize the thin film porous alumina sensing layer. The average sensitivity is approx. 15 pF/RH% which is more than a magnitude higher than the values found in the literature. The sensor is equipped with integrated resistive heating, which can be used for maintenance to reduce drift, or for keeping the sensing layer at elevated temperature, as an alternative method for temperature-dependence cancellation.

  4. Mt. Baker Geothermal Project | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: EnergyInformationOliver, Pennsylvania:(CTI PFAN) | OpenMt St HelensMt StMt.

  5. Chemical and Morphological Evolution of Nanoporous Pd/Rh Alloy...

    Office of Scientific and Technical Information (OSTI)

    Chemical and Morphological Evolution of Nanoporous PdRh Alloy Particles for Hydrogen Storage. Citation Details In-Document Search Title: Chemical and Morphological Evolution of...

  6. Magnetic order in the frustrated Ising-like chain compound Sr3NiIrO6 E. Lefranois,1, 2, 3,

    E-Print Network [OSTI]

    Boyer, Edmond

    in CsCoCl3 for instance3 . The most studied compound in the frustrated regime is Ca3Co2O6 because of its show that Ca3CoRhO6 5 , Sr3CoIrO6 6 , Sr3NiRhO6 7 and Sr3NiIrO6 6,8,9 have a similar behavior to Ca3Co2 of their unconventional magnetic properties due to the interplay between low dimensionality, magnetic frustration

  7. Mt Rainier Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: EnergyInformationOliver, Pennsylvania:(CTI PFAN) | Open Energy(RECP)MtMt

  8. Anomalous emissions of 103mRh biphoton transitions

    E-Print Network [OSTI]

    Yao Cheng; Bing Xia

    2009-08-06

    In this report, the anomalous emissions, centered on the one half transition energy 39.76/2 keV, are observed from the long-lived Mossbauer state of 103mRh excited by bremsstrahlung exposure. Strong coupling with identical nuclei in Rh crystals opens cascade channels for biphoton transitions.

  9. IR Kuiper Belt Constraints

    E-Print Network [OSTI]

    Teplitz, V L; Anderson, J D; Rosenbaum, D C; Scalise, R J; Wentzler, P; Teplitz, Vigdor L.; Anderson, John D.; Rosenbaum, Doris; Scalise, Randall J.; Wentzler, Paul

    1999-01-01

    We compute the temperature and IR signal of particles of radius $a$ and albedo $\\alpha$ at heliocentric distance $R$, taking into account the emissivity effect, and give an interpolating formula for the result. We compare with analyses of COBE DIRBE data by others (including recent detection of the cosmic IR background) for various values of heliocentric distance, $R$, particle radius, $a$, and particle albedo, $\\alpha$. We then apply these results to a recently-developed picture of the Kuiper belt as a two-sector disk with a nearby, low-density sector (40IR spectra for various parameter v...

  10. Spin-orbit tuned metal-insulator transitions in single-crystal Sr?Ir1–xRhxO? (0?x?1)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Qi, T. F.; Korneta, O. B.; Li, L.; Butrouna, K.; Cao, V. S.; Wan, Xiangang; Schlottmann, P.; Kaul, R. K.; Cao, G.

    2012-09-01

    Sr?IrO? is a magnetic insulator driven by spin-orbit interaction (SOI) whereas the isoelectronic and isostructural Sr?RhO? is a paramagnetic metal. The contrasting ground states have been shown to result from the critical role of the strong SOI in the iridate. Our investigation of structural, transport, magnetic, and thermal properties reveals that substituting 4d Rh?? (4d?) ions for 5d Ir?? (5d?) ions in Sr?IrO? directly reduces the SOI and rebalances the competing energies so profoundly that it generates a rich phase diagram for Sr?Ir1–xRhxO? featuring two major effects: (1) Light Rh doping (0 ? x ? 0.16) prompts a simultaneous andmore »precipitous drop in both the electrical resistivity and the magnetic ordering temperature TC, which is suppressed to zero at x = 0.16 from 240 K at x = 0. (2) However, with heavier Rh doping [0.24 1–xRhxO? is further highlighted by comparison with Sr?Ir1–xRuxO? where Ru?? (4d?) drives a direct crossover from the insulating to metallic states.« less

  11. Origin of room temperature ferromagnetic moment in Rh-rich Rh/Fe multilayer thin films

    E-Print Network [OSTI]

    Laughlin, David E.

    doing the magnetic measure- ments, a constant in-plane field of 0.8 T was applied to satu- rate the film in the antiferromagnetic AFM to ferromagnetic FM state on heating above 350 K and switch back on cooling, with a hysteresis. This property makes FeRh a very attractive choice as a write-assist layer material for low temperature heat

  12. Effects of social cues on GnRH-I, GnRH-II, and reproductive physiology in female house

    E-Print Network [OSTI]

    Murphy, Troy G.

    Effects of social cues on GnRH-I, GnRH-II, and reproductive physiology in female house sparrows Neuroscience Institute, University of California, Berkeley, USA c Department of Animal Physiology(s) of male social cues on the peripheral and neural responses of female house sparrows (Passer domesticus

  13. Developing Mt. Hope: The megawatt line

    SciTech Connect (OSTI)

    Rodzianko, P.; Fisher, F.S.

    1992-12-01

    After facing numerous obstacles, including opposition and competition, the Mt. Hope pumped-storage project in New Jersey has been licensed by FERC. That license will allow a former iron ore mine site to be used in producing a new resource-hydroelectricity. In early August 1992, after more than seven years of effort, the 2,000-MW Mt. Hope Waterpower Project was licensed by the Federal Energy Regulatory Commission (FERC). Getting the $1.8 billion pumped-storage project licensed was not an easy task. It involved 54 submittals to FERC, six public meetings, and costs of more than $12 million. Along the way, the project has withstood competing applications, community opposition, and legal battles. Getting a project of this magnitude off the ground is a challenge for even the most experienced developer. The effort was especially challenging for the Halecrest Company, a local family-owned and operated firm with no previous experience in hydroelectric development. When financing became tight, creative ways were found to raise seed capital for the project. When hydroelectric experience was needed, the company developed a world-class corporate team that carried Mt. Hope through the complexities of the licensing process and beyond. With license now in hand, the project developers are ready to move forward with negotiating power sales contracts and securing construction financing. The resulting project will be the second largest pumped-storage facility in the country-second only to the 2,100-MW Bath County project in Virginia. Mt. Hope will take six years to construct and is scheduled to be phased into operation beginning in 1999.

  14. Ethanol Oxidation on the Ternary Pt–Rh–SnO2/C Electrocatalysts with Varied Pt:Rh:Sn ratios

    SciTech Connect (OSTI)

    Adzic, R.R.; Li, M.; Kowal, A.; Sasaki, K.; Marinkovic, N.; Su, D.; Korach, E.; Liu, P.

    2010-05-30

    Ternary Pt-Rh-SnO{sub 2}/C electrocatalysts with the atomic ratio Pt:Rh:Sn = 3:1:x, where x varies from 2 to 6, were synthesized using the modified polyol method followed by thermal treatment. Several techniques used to characterize these electrocatalysts showed they were composed of homogeneous PtRh alloy and SnO{sub 2}, having all three constituents coexisting in single nanoparticles with the average particle size around 1.4 nm and a narrow size distribution. While all the electrocatalysts investigated exhibited high catalytic activity for ethanol oxidation, the most active one had the composition with the Pt:Rh:Sn = 3:1:4 atomic ratio. These ternary-electrocatalysts effectively split the C-C bond in ethanol at room temperature in acidic solutions, which is verified using the in situ IRRAS technique.

  15. Mt Rainier Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: EnergyInformationOliver, Pennsylvania:(CTI PFAN) | Open Energy(RECP)Mt

  16. Mt Wheeler Power, Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to: navigation,Mereg GmbHMontebalitoMt Princeton Hot Springs

  17. Marysville Mt Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource HistoryScenariosMarysville Mt Geothermal Area Jump to: navigation, search

  18. Mt Signal Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsourceII Jump to: navigation, searchsource HistoryCharleston,Peak Utility Jump to:PosoMt

  19. Water Sampling At Mt Princeton Hot Springs Geothermal Area (Olson...

    Open Energy Info (EERE)

    Water Sampling At Mt Princeton Hot Springs Geothermal Area (Olson & Dellechaie, 1976) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water...

  20. Refraction Survey At Mt Princeton Hot Springs Geothermal Area...

    Open Energy Info (EERE)

    Refraction Survey At Mt Princeton Hot Springs Geothermal Area (Lamb, Et Al., 2012) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Refraction...

  1. 3D Mt Resistivity Imaging For Geothermal Resource Assessment...

    Open Energy Info (EERE)

    3D Mt Resistivity Imaging For Geothermal Resource Assessment And Environmental Mitigation At The Glass Mountain Kgra, California Jump to: navigation, search OpenEI Reference...

  2. Vertical Electrical Sounding Configurations At Mt Princeton Hot...

    Open Energy Info (EERE)

    Vertical Electrical Sounding Configurations At Mt Princeton Hot Springs Geothermal Area (Zohdy, Et Al., 1971) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home...

  3. Direct-Current Resistivity Survey At Mt Princeton Hot Springs...

    Open Energy Info (EERE)

    Direct-Current Resistivity Survey At Mt Princeton Hot Springs Area (Richards, Et Al., 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity:...

  4. Geothermometry At Mt Princeton Hot Springs Geothermal Area (Pearl...

    Open Energy Info (EERE)

    Et Al., 1976) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Mt Princeton Hot Springs Geothermal Area (Pearl, Et Al., 1976)...

  5. MT3DMS v5.3 Supplemental User's Guide

    E-Print Network [OSTI]

    Zheng, Chunmiao

    published by the U.S. Army Corps of Engineers (Zheng and Wang, 1999; available at http://hydro.geo.ua.edu/mt3d). Readers should refer to Zheng and Wang (1999) for complete information on the theoretical Tonkin, Henning Prommer, Chris Langevin, Ned Banta, Eileen Poeter, and Rui Ma in various aspects of MT3

  6. MOBILE INTERACTIVE VISITOR INFORMATION SERVICE: PUKAHA MT. BRUCE TRIAL RESULTS

    E-Print Network [OSTI]

    Zealand Tourism Research Institute Sept 2005 #12;New Zealand Tourism Research Institute September 2005 www Information Service (MIVIS) mobile phones to access audio information at Pukaha Mt Bruce (PMB) were collected and range of visitors using the MIVIS phones in the Pukaha Mt Bruce setting. #12;New Zealand Tourism

  7. WPA Omnibus Award MT Wind Power Outreach

    SciTech Connect (OSTI)

    Brian Spangler, Manager Energy Planning and Renewables

    2012-01-30

    The objective of this grant was to further the development of Montanaâ??s vast wind resources for small, medium, and large scale benefits to Montana and the nation. This was accomplished through collaborative work with wind industry representatives, state and local governments, the agricultural community, and interested citizens. Through these efforts MT Dept Environmental Quality (DEQ) was able to identify development barriers, educate and inform citizens, as well as to participate in regional and national dialogue that will spur the development of wind resources. The scope of DEQâ??s wind outreach effort evolved over the course of this agreement from the development of the Montana Wind Working Group and traditional outreach efforts, to the current focus on working with the stateâ??s university system to deliver a workforce trained to enter the wind industry.

  8. Chi tit mn hc mt bn kia.

    E-Print Network [OSTI]

    California at Davis, University of

    v xã hi, ý n môi trng và sáng to. "Th ô xe p ca Hoa K," Davis là mt cng ng a dng và nng ng chào ón, Phát �m và Nghe Trong Lãnh Vc Hc Tp, và các lãnh vc khác. Ngoài ra cng có nhiu c hi tham gia các t chc ti trng và phc v cng ng. Mun bit ngày tháng, hc phí và các chi tit khác, hãy n: www

  9. RESEARCH INVOLVING HUMANS University Policy No.: RH8105

    E-Print Network [OSTI]

    Victoria, University of

    1 RESEARCH INVOLVING HUMANS University Policy No.: RH8105 Classification: Research Approving: Mandated Review: September, 2017 Associated Procedures Procedures for Conducting Human Research PURPOSE 1.00 The purpose of this policy is to: a) set out provisions to ensure Research Involving Human Participants

  10. Quantitative EDS Analysis of Nanometer-Scale Core/Shell Pd/Rh...

    Office of Scientific and Technical Information (OSTI)

    Quantitative EDS Analysis of Nanometer-Scale CoreShell PdRh Structures. Citation Details In-Document Search Title: Quantitative EDS Analysis of Nanometer-Scale CoreShell PdRh...

  11. IRS-Impersonation SCAMS IRS-Impersonation Telephone Scam

    E-Print Network [OSTI]

    Dennett, Daniel

    making the rounds throughout the country. Callers claim to be employees of the IRS, but are not directory (http://whitepages.tufts.edu) as the fraudulent caller appears to be obtaining mobile phone numbers from this directory. This may help reduce your exposure to telephone scams and other unwanted

  12. Superconductivity versus structural phase transition in the closely related Bi2Rh3.5S2 and Bi2Rh3S2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kaluarachchi, Udhara S.; Xie, Weiwei; Lin, Qisheng; Taufour, Valentin; Bud'ko, Sergey L.; Miller, Gordon J.; Canfield, Paul C.

    2015-05-19

    Single crystals of Bi2Rh3S2 and Bi2Rh3.5S2 were synthesized by solution growth, and the crystal structures and thermodynamic and transport properties of both compounds were studied. In the case of Bi2Rh3S2, a structural first-order transition at around 165 K is identified by single-crystal diffraction experiments, with clear signatures visible in resistivity, magnetization, and specific heat data. No superconducting transition for Bi2Rh3S2 was observed down to 0.5 K. In contrast, no structural phase transition at high temperature was observed for Bi2Rh3.5S2; however, bulk superconductivity with a critical temperature, Tc ? 1.7 K, was observed. The Sommerfeld coefficient ? and the Debye temperaturemore »(?D) were found to be 9.41 mJ mol–1K–2 and 209 K, respectively, for Bi2Rh3S2, and 22 mJ mol–1K–2 and 196 K, respectively, for Bi2Rh3.5S2. As a result, the study of the specific heat in the superconducting state of Bi2Rh3.5S2 suggests that Bi2Rh3.5S2 is a weakly coupled, BCS superconductor.« less

  13. Hybrid density functional calculations of the defect properties of ZnO:Rh and ZnO:Ir

    E-Print Network [OSTI]

    Muñoz Ramo, David; Bristowe, Paul D.

    2014-03-31

    gap region and near the conduction band minimum, with a d-d splitting larger than 2 eV, which helps maintain transparency in the material. Addition of a hole to the simulation cell of both spinels and doped ZnO leads to charge localization...

  14. Recycling Lingware in a Multilingual MT System Steffen Leo Hansen

    E-Print Network [OSTI]

    Recycling Lingware in a Multilingual MT System Steffen Leo Hansen Manny Rayner David Carter Ivan (Rayner and Carter, 1997). The first is the most obvious: we start with a function- ing grammar

  15. Ground Gravity Survey At Mt Princeton Hot Springs Geothermal...

    Open Energy Info (EERE)

    lithologic distrubtions Notes Gravity low associated with Mt. Princeton Batholith; density contrast of -0.5 gcm3 of valley-fill sediments relative to batholith References J.E....

  16. Summary of CARE-HHH IR’07

    E-Print Network [OSTI]

    Scandale, Walter

    2008-01-01

    We summarize the highlights and main conclusions of the CARE-HHH-APD mini-workshop on the LHC Interaction Region (IR) upgrade “IR’07” held in Frascati from the 7th to the 9th of November 2007.

  17. Towards tailoring the magnetocaloric response in FeRh-based ternary compounds

    SciTech Connect (OSTI)

    Barua, Radhika Jiménez-Villacorta, Félix; Lewis, L. H.

    2014-05-07

    In this work, we demonstrate that the magnetocaloric response of FeRh-based compounds may be tailored for potential magnetic refrigeration applications by chemical modification of the FeRh lattice. Alloys of composition Fe(Rh{sub 1?x}A{sub x}) or (Fe{sub 1?x}B{sub x})Rh (A?=?Cu, Pd; B?=?Ni; 0?Rh-based systems were determined using isothermal M(H) curves measured in the vicinity of the magnetostructural temperature (T{sub t}). It is found that the FeRh working temperature range (?T{sub FWHM}) may be chemically tuned over a wide temperature range, 100?K???T???400?K. While elemental substitution consistently decreases the magnetic entropy change (?S{sub mag}) of the FeRh-based ternary alloys from that of the parent FeRh compound (?S{sub mag},{sub FeRh}???17?J/kg?K; ?S{sub mag,FeRh-ternary?=}?7–14?J/kg?K at H{sub app}?=?2?T), the net refrigeration capacity (RC), defined as the amount of heat that can be transferred during one magnetic refrigeration cycle, of the modified systems is significantly higher (RC{sub FeRh}???150?J/kg; RC{sub FeRh-ternary?=}?170–210?J/kg at H{sub app}?=?2?T). These results are attributed to stoichiometry-induced changes in the FeRh electronic band structure and beneficial broadening of the magnetostructural transition due to local chemical disorder.

  18. NEAFS Y-mtDNA Workshop (Butler and Coble) November 1, 2006

    E-Print Network [OSTI]

    NEAFS Y-mtDNA Workshop (Butler and Coble) mtDNA November 1, 2006 http://www.cstl.nist.gov/biotech) mtDNA November 1, 2006 http://www.cstl.nist.gov/biotech/strbase/training.htm 2 Data Review-mtDNA Workshop (Butler and Coble) mtDNA November 1, 2006 http://www.cstl.nist.gov/biotech/strbase/training.htm 3

  19. Temperature dependence of anisotropic magnetoresistance in antiferromagnetic Sr{sub 2}IrO{sub 4}

    SciTech Connect (OSTI)

    Wang, C.; Seinige, H.; Tsoi, M.; Cao, G.; Zhou, J.-S.; Goodenough, J. B.

    2015-05-07

    Temperature-dependent magnetotransport properties of the antiferromagnetic semiconductor Sr{sub 2}IrO{sub 4} are investigated with point-contact devices. The point-contact technique allows to probe very small volumes and, therefore, to look for electronic transport on a microscopic scale. Point-contact measurements with single crystals of Sr{sub 2}IrO{sub 4} were intended to see whether the additional local resistance associated with a small contact area between a sharpened Cu tip and the antiferromagnet shows magnetoresistance (MR) such as that seen in bulk crystals. Point-contact measurements at liquid nitrogen temperature revealed large MRs (up to 28%) for modest magnetic fields (250?mT) applied within an IrO{sub 2} (ab) plane with angular dependence showing a crossover from four-fold to two-fold symmetry with an increasing magnetic field. Point contact measurement exhibits distinctive anisotropic magnetoresistance (AMR) in comparison to a bulk experiment, imposing intriguing questions about the mechanism of AMR in this material. Temperature-dependent MR measurements show that the MR falls to zero at the Neel temperature, but the temperature dependence of the MR ratio differs qualitatively from that of the resistivity. This AMR study helps to unveil the entanglement between electronic transport and magnetism in Sr{sub 2}IrO{sub 4} while the observed magnetoresistive phenomena can be potentially used to sense the antiferromagnetic order parameter in spintronic applications.

  20. IR-2003- | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancingR Walls21, 2012INSPECTION REPORT: DOE/IG-0919IR-2003-

  1. Electronic structure and magnetism of the Rh[l brace]001[r brace] surface

    SciTech Connect (OSTI)

    Wu, S.C. Physics Department, Peking University, Beijing 100871 ); Garrison, K. ); Begley, A.M.; Jona, F. ); Johnson, P.D. )

    1994-05-15

    Spin-polarized-photoemission experiments on clean Rh[l brace]001[r brace] show that the surface resonance at the [ital [bar M

  2. Mt St Helens Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: EnergyInformationOliver, Pennsylvania:(CTI PFAN) | OpenMt St HelensMt St

  3. Probing the lexicon in evaluating commercial MT systems Martin Volk

    E-Print Network [OSTI]

    for self evaluation consisted of technical, linguistic and ergonomic issues. As part of the linguisticProbing the lexicon in evaluating commercial MT systems Martin Volk University of Zurich Department Abstract In the past the evaluation of machine trans- lation systems has focused on single sys- tem

  4. Evidence for Methane -Complexes in Reductive Elimination Reactions from TpRh(L)(CH3)H

    E-Print Network [OSTI]

    Jones, William D.

    Evidence for Methane -Complexes in Reductive Elimination Reactions from TpRh(L)(CH3)H Douglas D of methane from TpRh(L)(CH3)H in benzene/perfluorobenzene solvent mixtures is found to be dependent upon the concentration of benzene, indicating an associative component to the reductive elimination of methane. Both

  5. Bimetallic Ni-Rh catalysts with low amounts of Rh for the steam and autothermal reforming of n-butane for fuel-cell applications.

    SciTech Connect (OSTI)

    Ferrandon, M.; Kropf, A. J.; Krause, T.; Chemical Sciences and Engineering Division

    2010-05-15

    Mono-metallic nickel and rhodium catalysts and bimetallic Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}, CeZrO{sub 2} and CeMgOx were prepared and evaluated for catalyzing the steam and autothermal reforming of n-butane. The binary Ni-Rh supported on La-Al{sub 2}O{sub 3} catalysts with low weight loading of rhodium exhibited higher H{sub 2} yields than Ni or Rh alone. The Ni-Rh/CeZrO{sub 2} catalyst exhibited higher performance and no coke formation, compared to the same metals on other supports. A NiAl{sub 2}O{sub 4} spinel phase was obtained on all Ni and Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}. The presence of rhodium stabilized the spinel phase as well as NiOx species upon reforming while Ni alone was mostly reduced into metallic species. Extended X-ray absorption fine-structure analysis showed evidence of Ni-Rh alloy during preparation and even further after an accelerated aging at 900C in a H{sub 2}/H{sub 2}O atmosphere.

  6. (Have we found the Holy Grail?) Panel at MT-Summit 2003

    E-Print Network [OSTI]

    Wu, Dekai

    (Have we found the Holy Grail?) Panel at MT-Summit 2003 #12;The HKUST Leading Question Translation? If not, is the Holy Grail just around the corner? Translation Are we just about done? #12;Dekai Wu, MT

  7. Decomposition pathways of C2 oxygenates on Rh-modified tungsten carbide surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kelly, Thomas G.; Ren, Hui; Chen, Jingguang G.

    2015-03-27

    Ethanol decomposition on tungsten monocarbide (WC) and Rh-modified WC was investigated using ultrahigh vacuum (UHV) surface science experiments and density functional theory (DFT) calculations. DFT calculations indicated that the binding energies of ethanol and its decomposition intermediates on WC(0001) were modified by Rh, with Rh/WC(0001) showing similar values to those on Rh(111). Through temperature-programmed desorption (TPD) experiments on polycrystalline WC and Rh-modified WC, it was shown that the selectivity for ethanol decomposition was different on these surfaces. On WC, the C-O bond of ethanol was preferentially broken to produce ethylene; on Rh-modified WC, the C-C bond was broken to producemore »carbon monoxide and methane. In addition, high-resolution electron energy loss spectroscopy (HREELS) was used to determine likely surface intermediates. On Rh-modified WC, ethanol first formed ethoxy through O-H scission, then reacted through an aldehyde intermediate to form the C1 products.« less

  8. The effect of Fe-Rh alloying on CO hydrogenation to C2+ oxygenates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Palomino, Robert; Magee, Joseph W.; Llorca, Jordi; Senanayake, Sanjaya D.; White, Michael G.

    2015-05-20

    A combination of reactivity and structural studies using X-ray diffraction (XRD), pair distribution function (PDF), and transmission electron microscopy (TEM) was used to identify the active phases of Fe-modified Rh/TiO2 catalysts for the synthesis of ethanol and other C2+ oxygenates from CO hydrogenation. XRD and TEM confirm the existence of Fe–Rh alloys for catalyst with 1–7 wt% Fe and ~2 wt% Rh. Rietveld refinements show that FeRh alloy content increases with Fe loading up to ~4 wt%, beyond which segregation to metallic Fe becomes favored over alloy formation. Catalysts that contain Fe metal after reduction exhibit some carburization as evidencedmore »by the formation of small amounts of Fe3C during CO hydrogenation. Analysis of the total Fe content of the catalysts also suggests the presence of FeOx also increased under reaction conditions. Reactivity studies show that enhancement of ethanol selectivity with Fe loading is accompanied by a significant drop in CO conversion. Comparison of the XRD phase analyses with selectivity suggests that higher ethanol selectivity is correlated with the presence of Fe–Rh alloy phases. As a result, the interface between Fe and Rh serves to enhance the selectivity of ethanol, but suppresses the activity of the catalyst which is attributed to the blocking or modifying of Rh active sites.« less

  9. Geothermal energy resource investigations at Mt. Spurr, Alaska

    SciTech Connect (OSTI)

    Turner, D.L.; Wescott, E.M. (eds.)

    1986-12-01

    Spurr volcano is a composite Quaternary cone of largely andesitic composition located on the west side of Cook Inlet about 80 miles west of Anchorage and about 40 miles from the Beluga electrical transmission line. Geologic mapping (Plate 1-1) shows that the present summit depression was produced by a Mt. St. Helens-type sector collapse, rather than by a caldera collapse. Geochronologic and previous tephrachronologic studies show that there has been an active magmatic system at Spurr volcano during the late Pleistocene-to-Holocene time interval that is of critical interest for geothermal energy resource assessment. Major effort was devoted to geochemical and geophysical surveys of the accessible area south of Mt. Spurr, in addition to geologic mapping and geochronologic studies. Many coincident mercury and helium anomalies were found, suggesting the presence of geothermal systems at depth. Extremely large electrical self-potential anomalies were also found, together with extensive zones of low resistivity discovered by our controlled-source audiomagnetotelluric survey. The juxtaposition of all of these different types of anomalies at certain areas on the south slope of Crater Peak indicates the presence of a geothermal system which should be accessible by drilling to about 2000 ft depth. It is also evident that there is a strong volcanic hazard to be evaluated in considering any development on the south side of Mt. Spurr. This hazardous situation may require angle drilling of production wells from safer areas and placement of power generation facilities at a considerable distance from hazardous areas.

  10. The valence band structure of Ag{sub x}Rh{sub 1–x} alloy nanoparticles

    SciTech Connect (OSTI)

    Yang, Anli; Sakata, Osami; Kusada, Kohei; Kobayashi, Hirokazu; Yayama, Tomoe; Ishimoto, Takayoshi; Yoshikawa, Hideki; Koyama, Michihisa; and others

    2014-10-13

    The valence band (VB) structures of face-centered-cubic Ag-Rh alloy nanoparticles (NPs), which are known to have excellent hydrogen-storage properties, were investigated using bulk-sensitive hard x-ray photoelectron spectroscopy. The observed VB spectra profiles of the Ag-Rh alloy NPs do not resemble simple linear combinations of the VB spectra of Ag and Rh NPs. The observed VB hybridization was qualitatively reproduced via a first-principles calculation. The electronic structure of the Ag{sub 0.5}Rh{sub 0.5} alloy NPs near the Fermi edge was strikingly similar to that of Pd NPs, whose superior hydrogen-storage properties are well known.

  11. W.T.; Rainey, R.H. 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS;...

    Office of Scientific and Technical Information (OSTI)

    thorium fuel reprocessing experience Brooksbank, R.E.; McDuffee, W.T.; Rainey, R.H. 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; NUCLEAR MATERIALS DIVERSION; SAFEGUARDS; SPENT FUELS;...

  12. Model for the Prediction of the Hydriding Thermodynamics of Pd-Rh-Co Ternary Alloys

    SciTech Connect (OSTI)

    Teter, D.F.; Thoma, D.J.

    1999-03-01

    A dilute solution model (with respect to the substitutional alloying elements) has been developed, which accurately predicts the hydride formation and decomposition thermodynamics and the storage capacities of dilute ternary Pd-Rh-Co alloys. The effect of varying the rhodium and cobalt compositions on the thermodynamics of hydride formation and decomposition and hydrogen capacity of several palladium-rhodium-cobalt ternary alloys has been investigated using pressure-composition (PC) isotherms. Alloying in the dilute regime (<10 at.%) causes the enthalpy for hydride formation to linearly decrease with increasing alloying content. Cobalt has a stronger effect on the reduction in enthalpy than rhodium for equivalent alloying amounts. Also, cobalt reduces the hydrogen storage capacity with increasing alloying content. The plateau thermodynamics are strongly linked to the lattice parameters of the alloys. A near-linear dependence of the enthalpy of hydride formation on the lattice parameter was observed for both the binary Pd-Rh and Pd-Co alloys, as well as for the ternary Pd-Rh-Co alloys. The Pd-5Rh-3Co (at. %) alloy was found to have similar plateau thermodynamics as a Pd-10Rh alloy, however, this ternary alloy had a diminished hydrogen storage capacity relative to Pd-10Rh.

  13. Mt St Helens Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: EnergyInformationOliver, Pennsylvania:(CTI PFAN) | OpenMt St Helens

  14. MT Energie GmbH Co KG | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas:Montezuma,Information MHKMHK5 < MHKKemblaSolar Jump to:Industries Inc JumpMT

  15. RAPID/Roadmap/12-MT-a | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/Water Use/Nevada <UtahMontanasourceWA-aCA-aMT-a <

  16. RAPID/Roadmap/15-MT-a | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/Water Use/Nevadaa < RAPID‎ | RoadmapCO-ceWA-eb <MT-a

  17. RAPID/Roadmap/17-MT-c | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/Water Use/Nevadaa < RAPID‎ |a < RAPID‎CA-aHI-aaMT-c

  18. RAPID/Roadmap/18-MT-b | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/Water Use/Nevadaa < RAPID‎ |a <-AK-b <CO-badMT-b

  19. RAPID/Roadmap/4-MT-a | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/Water Use/Nevadaa < RAPID‎f <CA-aab <cdMT-a <

  20. RAPID/Roadmap/6-MT-d | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/Water Use/Nevadaa < RAPID‎fRAPID/Roadmap/6-CO-bacMT-d

  1. RAPID/Roadmap/6-MT-f | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/Water Use/Nevadaa < RAPID‎fRAPID/Roadmap/6-CO-bacMT-df

  2. City of Mt Pleasant, Utah (Utility Company) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar EnergyLawler, Iowa (UtilityIowa Phone Number: (319) 385-2121City of Mt

  3. Mt Princeton Hot Springs Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to: navigation,Mereg GmbHMontebalitoMt Princeton Hot Springs Geothermal

  4. RAPID/Roadmap/14-MT-b | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-b < RAPID‎ | Roadmap JumpNV-a <CA-cID-aMT-b <

  5. RAPID/Roadmap/14-MT-c | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-b < RAPID‎ | Roadmap JumpNV-a <CA-cID-aMT-b

  6. RAPID/Roadmap/14-MT-d | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-b < RAPID‎ | Roadmap JumpNV-a <CA-cID-aMT-bd

  7. RAPID/Roadmap/17-MT-d | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-b < RAPID‎ | Roadmap JumpNV-ad-MT-d < RAPID‎ |

  8. RAPID/Roadmap/20-MT-a | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-b < RAPID‎ | RoadmapAK-a < RAPID‎ |MT-a <

  9. RAPID/Roadmap/8-MT-a | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-b < RAPID‎ | RoadmapAK-abFD-a < RAPID‎ID-eMT-a

  10. Micro-Earthquake At Marysville Mt Area (Blackwell) | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource HistoryScenariosMarysville MtMedicalInformation 2-2005)1995) |Information

  11. HERO Ski Trip to Mt. Hood Meadows February

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Lowï‚— WeUpdateScienceForTrip to Mt. Hood Meadows

  12. Which Oxidation State Leads to O-O Bond Formation in Cp*Ir(bpy)Cl-Catalyzed Water Oxidation, Ir(V), Ir(VI), or Ir(VII)?

    E-Print Network [OSTI]

    Liao, Rongzhen

    the catalytic IrIII species. Water oxidation at IrVII has a slightly higher barrier, but it may also contributeWhich Oxidation State Leads to O-O Bond Formation in Cp*Ir(bpy)Cl-Catalyzed Water Oxidation, Ir: Density functional calculations are used to revisit the reaction mechanism of water oxidation catalyzed

  13. IRS Warns of Pervasive Telephone Scam IRS YouTube Video

    E-Print Network [OSTI]

    Bermúdez, José Luis

    as described above), then call and report the incident to the Treasury Inspector General for Tax Administration use fake names and IRS badge numbers. They generally use common names and surnames to identify in the message. Instead, forward the e-mail to phishing@irs.gov. More information on how to report phishing scams

  14. Getting Our Feet Wet: Water Management at Mt. Laguna in Cleveland National Forest

    E-Print Network [OSTI]

    Mumby, William Cade

    2013-01-01

    Strategies for Rural Communities. ” National Conference onallocation facing the rural community of Mt. Laguna? (EquityStrategies for Rural Communities. ” National Conference on

  15. DC Resistivity Survey (Dipole-Dipole Array) At Mt Princeton Hot...

    Open Energy Info (EERE)

    1971) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: DC Resistivity Survey (Dipole-Dipole Array) At Mt Princeton Hot Springs Geothermal Area...

  16. Behavior of trace and companion elements of ULC-IF steel grades during RH-treatment

    SciTech Connect (OSTI)

    Jungreithmeier, A.; Viertauer, A.; Presslinger, H. [Voest-Alpine Stahl Linz GmbH (Austria)

    1996-12-31

    A large number of metallurgical reactions are caused by lowering the partial pressure during vacuum treatment. One of these reactions is the volatilization of elements with high vapor pressure. The concentration of trace and companion elements during RH-treatment mostly changes because of cooling scrap, deoxidation agents and ferro-alloy additions, slag/metal reactions, vaporization and also because of reactions with the RH-vessel lining. These changes in the concentration of trace and companion elements during RH-treatment are exemplified for ULC-IF (ultra low carbon--interstitial free) steel grades. The elements which are considered are chromium, nickel, molybdenum, copper, vanadium, tin, zinc, lead, phosphorus, sulfur and nitrogen. Calculations of the theoretical equilibrium solubility using thermodynamic data--in dependence of pressure and temperature--correspond well with the values obtained during steel production operations. 67 refs.

  17. Visual Field Maps, Population Receptive Field Sizes, and Visual Field Coverage in the Human MT Complex

    E-Print Network [OSTI]

    Dumoulin, Serge O.

    of processing in human motion-selective cortex. I N T R O D U C T I O N Neuroimaging experiments localize human by additional experiments. Defining human MT based on stimulus selectivity means that the identificationVisual Field Maps, Population Receptive Field Sizes, and Visual Field Coverage in the Human MT

  18. Bitcoin Transaction Malleability and MtGox Christian Decker and Roger Wattenhofer

    E-Print Network [OSTI]

    Bitcoin Transaction Malleability and MtGox Christian Decker and Roger Wattenhofer ETH Zurich International Publishing Switzerland 2014 #12;314 C. Decker and R. Wattenhofer exchanges its monopoly slowly doubled the withdrawn bitcoins, once from the withdrawal and once on its account on MtGox. In this work we

  19. An assessment of regional climate trends and changes to the Mt. Jaya glaciers of Irian Jaya 

    E-Print Network [OSTI]

    Kincaid, Joni L.

    2007-09-17

    on the Mt. Jaya glaciers has been lacking since the early 1970s. Using IKONOS satellite images, the ice extents of the Mt. Jaya glaciers in 2000, 2002, 2003, 2004, and 2005 were mapped. The mapping indicates that the recessional trend which began in the mid...

  20. Mt. Etna tropospheric ash retrieval and sensitivity analysis using Moderate Resolution Imaging

    E-Print Network [OSTI]

    Oxford, University of

    Mt. Etna tropospheric ash retrieval and sensitivity analysis using Moderate Resolution Imaging.pugnaghi@unimore.it, gabriele.gangale@unimore.it Abstract. A retrieval of tropospheric volcanic ash from Mt Etna has been. In order to derive the ash plume optical thickness, the particle effective radius and the total mass

  1. A MT System from Turkmen to Turkish Employing Finite State and Statistical Methods

    E-Print Network [OSTI]

    Yanikoglu, Berrin

    between close language pairs can be relatively easier and can still benefit from simple(r) paradigms in MT with a disambiguation post-processing stage based on statistical language models. The very productive inflectionalA MT System from Turkmen to Turkish Employing Finite State and Statistical Methods A. Cüneyd TANTU

  2. Cooling effect in emissions of 103mRh excited by bremsstrahlung

    E-Print Network [OSTI]

    Yao Cheng; Bing Xia; Chinping Chen

    2009-04-29

    Nonlinear characteristic emissions of K alpha, K beta and gamma with a significant triplet splitting at room temperature are observed from the long-lived nuclear state of 103mRh excited by bremsstrahlung irradiation. A pronounced phase-transition-like narrowing of the emission profiles occurs immediately after the sample is cooled down to 77 K. The room temperature profiles reappear again abruptly and almost reversibly as the temperature drifts freely back to approximately the ice point after the filling of liquid nitrogen is stopped. These emission properties at 300 K and at low temperature may indicate that the 103mRh nuclei are in collective states.

  3. Vehicle Technologies Office Merit Review 2015: IR Thermography...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    IR Thermography as a Non-Destructive Evaluation (NDE) Tool for Lithium-Ion Battery Manufacturing Vehicle Technologies Office Merit Review 2015: IR Thermography as a Non-Destructive...

  4. Electronic Effects of Rh(II)-Mediated Carbenoid Intramolecular C-H Insertion: A Linear Free Energy Correlation Study

    E-Print Network [OSTI]

    Wang, Jianbo

    Electronic Effects of Rh(II)-Mediated Carbenoid Intramolecular C-H Insertion: A Linear Free Energy. The mechanistic significance of these Hammett correlations is discussed. Introduction The electronic effects of Rh is enhanced by an electron-donating group while an electron-withdrawing group retards the C-H insertion, thus

  5. Dynamics of NO reduction by H2 on Rh(111): Velocity and angular distributions of the N2 product

    E-Print Network [OSTI]

    Sibener, Steven

    examine the dynamics of the NO H2 reaction on the Rh 111 surface by measuring the velocity distribution. Product velocity distributions have been measured for a number of surface reactions, and show a wideDynamics of NO reduction by H2 on Rh(111): Velocity and angular distributions of the N2 product J

  6. David A. DeLambo, Rh.D., CRC Department of Rehabilitation and Counseling

    E-Print Network [OSTI]

    Wu, Mingshen

    David A. DeLambo, Rh.D., CRC Department of Rehabilitation and Counseling University of Wisconsin-Stout 231a Vocational Rehabilitation Building Menomonie, WI 54751 delambod@uwstout.edu (715) 232-2499 Education 1997 Doctor of Rehabilitation/Rehabilitation Southern Illinois University Carbondale

  7. Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation

    E-Print Network [OSTI]

    Jones, William D.

    Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation between] in interaction with propane. Two complexes have been found as minima coordinated through either a methyl the methylene complex of propane into a methyl complex of pro- pane. This latter reaction has a much lower

  8. Carbon monoxide oxidation on Rh(111): Velocity and angular distributions of the CO2 product

    E-Print Network [OSTI]

    Sibener, Steven

    Carbon monoxide oxidation on Rh(111): Velocity and angular distributions of the CO2 product J. I of surface temperature and oxygen coverage. Both the velocity and angular distributions are bimodal without first accommodating on the surface, the velocity, angular, and internal state distributions may

  9. Balloon-borne sounding system (BBSS): Vaisala-processed winds, press., temp, and RH

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Coulter, Richard; Ritsche, Michael

    Balloon-borne sounding system (BBSS): Vaisala-processed winds, press., temp, and RH. The balloon-borne sounding system (SONDE) provides in situ measurements (vertical profiles) of both the thermodynamic state of the atmosphere, and the wind speed and direction.

  10. Oxidation of Methanol on 2nd and 3rd Row Group VIII Transition Metals (Pt, Ir, Os, Pd, Rh, and Ru): Application to Direct Methanol

    E-Print Network [OSTI]

    Goddard III, William A.

    this problem; however, extracting molecular hydrogen from a liquid fuel requires a reformer. This greatly parameters for com- mercial use are now achievable with modern catalytic formula- tions and cell designs.1 by a proton- exchange membrane such as Nafion. Platinum-based electrodes demonstrate the highest catalytic

  11. Waste Isolation Pilot Plant simulated RH TRU waste experiments: Data and interpretation pilot

    SciTech Connect (OSTI)

    Molecke, M.A.; Argueello, G.J.; Beraun, R.

    1993-04-01

    The simulated, i.e., nonradioactive remote-handled transuranic waste (RH TRU) experiments being conducted underground in the Waste Isolation Pilot Plant (WIPP) were emplaced in mid-1986 and have been in heated test operation since 9/23/86. These experiments involve the in situ, waste package performance testing of eight full-size, reference RH TRU containers emplaced in horizontal, unlined test holes in the rock salt ribs (walls) of WIPP Room T. All of the test containers have internal electrical heaters; four of the test emplacements were filled with bentonite and silica sand backfill materials. We designed test conditions to be ``near-reference`` with respect to anticipated thermal outputs of RH TRU canisters and their geometrical spacing or layout in WIPP repository rooms, with RH TRU waste reference conditions current as of the start date of this test program. We also conducted some thermal overtest evaluations. This paper provides a: detailed test overview; comprehensive data update for the first 5 years of test operations; summary of experiment observations; initial data interpretations; and, several status; experimental objectives -- how these tests support WIPP TRU waste acceptance, performance assessment studies, underground operations, and the overall WIPP mission; and, in situ performance evaluations of RH TRU waste package materials plus design details and options. We provide instrument data and results for in situ waste container and borehole temperatures, pressures exerted on test containers through the backfill materials, and vertical and horizontal borehole-closure measurements and rates. The effects of heat on borehole closure, fracturing, and near-field materials (metals, backfills, rock salt, and intruding brine) interactions were closely monitored and are summarized, as are assorted test observations. Predictive 3-dimensional thermal and structural modeling studies of borehole and room closures and temperature fields were also performed.

  12. MT3D: a 3 dimensional magnetotelluric modeling program (user's guide and documentation for Rev. 1)

    SciTech Connect (OSTI)

    Nutter, C.; Wannamaker, P.E.

    1980-11-01

    MT3D.REV1 is a non-interactive computer program written in FORTRAN to do 3-dimensional magnetotelluric modeling. A 3-D volume integral equation has been adapted to simulate the MT response of a 3D body in the earth. An integro-difference scheme has been incorporated to increase the accuracy. This is a user's guide for MT3D.REV1 on the University of Utah Research Institute's (UURI) PRIME 400 computer operating under PRIMOS IV, Rev. 17.

  13. Effect of prostaglandin E? (PGE?) on the release of gonadotropin-releasing hormone (GnRH) from infundibular explants of cattle 

    E-Print Network [OSTI]

    Stephens, Tyler Paul

    2001-01-01

    GnRH neuronal terminals located in the infundibulum of rodents have been shown to release GnRH when stimulated with PGE? in vivo and in vitro. The effect of PGE? on the release of GnRH has not been determined in cattle. Thus, the objective...

  14. Association of intracellular calcium oscillations with release of gonadotropin-releasing hormone (GnRH) from GT1-1 neuronal cells 

    E-Print Network [OSTI]

    Gilmore, Chrystal Dawn

    1999-01-01

    the relationship of GnRH release with [Ca²?][] oscillations using the GT1-1 neuronal cell line. GnRH release was measured by radioimmunoassay of media incubated with GT1-1 neuronal cells for 1 hr with control or test substances to induce release of GnRH. [Ca...

  15. Is It Homogeneous or Heterogeneous Catalysis Derived from [RhCp*Cl2]2? In Operando-XAFS, Kinetic and Crucial Kinetic Poisoning Evidence for Subnanometer Rh4 Cluster-Based Benzene Hydrogenation Catalysis

    SciTech Connect (OSTI)

    Bayram, Ercan; Linehan, John C.; Fulton, John L.; Roberts, John A.; Szymczak, Nathaniel; Smurthwaite, Tricia D.; Ozkar, Saim; Balasubramanian, Mahalingam; Finke, Richard G.

    2011-11-23

    Determining the true, kinetically dominant catalytically active species, in the classic benzene hydrogenation system pioneered by Maitlis and co-workers 34 years ago starting with [RhCp*Cl2]2 (Cp* = [{eta}5-C5(CH3)5]), has proven to be one of the most challenging case studies in the quest to distinguish single-metal-based 'homogeneous' from polymetallic, 'heterogeneous' catalysis. The reason, this study will show, is the previous failure to use the proper combination of (i) operando spectroscopy to determine the dominant form(s) of the precatalyst's mass under catalysis (i.e., operating) conditions, plus then and crucially also (ii) the previous lack of the necessary kinetic studies, catalysis being a 'wholly kinetic phenomenon' as J. Halpern long ago noted. An important contribution from this study will be to reveal the power of quantitiative kinetic poisoning experiments for distinguishing single-metal, or in this case subnanometer Rh4 cluster-based catalysis from larger, polymetallic Rh(0)n nanoparticle catalysis, at least under favorable conditions. The combined operando-XAFS (X-ray absorption fine structure) spectroscopy and kinetic evidences provide a compelling case for Rh4-based, with average stoichiometry 'Rh4Cp*2.4Cl4Hc', benzene hydrogenation catalysis in 2-propanol with added Et3N and at 100 C and 50 atm initial H2 pressure. The results also reveal, however, that if even ca. 1.4% of the total soluble Rh(0)n had formed nanoparticles, then those Rh(0)n nanoparticles would have been able to account for all the observed benzene hydrogenation catalytic rate (using commercial, ca. 2 nm, polyethyleneglycol-dodecylether hydrosol stabilized Rh(0)n nanoparticles as a model system). The results 'especially the poisoning methodology developed and employed' are of significant, broader interest since determining the nature of the true catalyst continues to be a central, often vexing issue in any and all catalytic reactions. The results are also of fundamental interest in that they add to a growing body of evidence indicating that certain, appropriately ligated, coordinatively unsaturated, subnanometer M4 transition-metal clusters can be relatively robust catalysts. Also demonstrated herein is that Rh4 clusters are poisoned by Hg(0), demonstrating for the first time that the classic Hg(0) poisoning test of 'homogeneous' vs 'heterogeneous'catalysts cannot distinguish Rh4-based subnanometer catalysts from Rh(0)n nanoparticle catalysts, at least for the present examples of these two specific, Rh-based catalysts.

  16. Two Keggin-type heteropolytungstates with transition metal as a central atom: Crystal structure and magnetic study with 2D-IR correlation spectroscopy

    SciTech Connect (OSTI)

    Chai, Feng [Department of Chemistry, Fuzhou University, Fuzhou 350108 (China); Chen, YiPing, E-mail: ypchen007@sina.com [Department of Chemistry, Fuzhou University, Fuzhou 350108 (China); State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); You, ZhuChai; Xia, ZeMin; Ge, SuZhi; Sun, YanQiong; Huang, BiHua [Department of Chemistry, Fuzhou University, Fuzhou 350108 (China)

    2013-06-01

    Two Keggin-type heteropolytungstates, [Co(phen)?]?[CoW??O??]·9H?O 1 (phen=1,10-phenanthroline) and [Fe(phen)?]?[FeW??O??]·H?O·H?O 2, have been synthesized via the hydrothermal technique and characterized by single crystal X-ray diffraction analyses, IR, XPS, TG analysis, UV–DRS, XRD, thermal-dependent and magnetic-dependent 2D-COS IR (two-dimensional infrared correlation spectroscopy). Crystal structure analysis reveals that the polyanions in compound 1 are linked into 3D supramolecule through hydrogen bonding interactions between lattice water molecules and terminal oxygen atoms of polyanion units, and [Co(phen)?]²? cations distributed in the polyanion framework with many hydrogen bonding interactions. The XPS spectra indicate that all the Co atoms in 1 are +2 oxidation state, the Fe atoms in 2 existing with +2 and +3 mixed oxidation states. - Graphical abstract: The magnetic-dependent synchronous 2D correlation IR spectra of 1 (a), 2 (b) over 0–50 mT in the range of 600–1000 cm?¹, the obvious response indicate two Keggin polyanions skeleton susceptible to applied magnetic field. Highlights: • Two Keggin-type heteropolytungstates with transition metal as a central atom has been obtained. • Compound 1 forms into 3D supramolecular architecture through hydrogen bonding between water molecules and polyanions. • Magnetic-dependent 2D-IR correlation spectroscopy was introduced to discuss the magnetism of polyoxometalate.

  17. NEAFS Y-mtDNA Workshop (Butler and Coble) Markers, Core Loci, and Kits

    E-Print Network [OSTI]

    ) ­ Ann Gross (MN) ­ Jill Smerick (FBI) ­ Sam Baechtel (FBI) ­ Roger Frappier (CFS) ­ Phil Kinsey (OR now MT) ­ Gary Sims (CA DOJ) ­ George Carmody (retired) ­ Mike Adamowicz (CT) ­ Bruce Budowle (FBI

  18. TIME-VARIABLEFILTERING OF MtTLTI[CHANNELSIGNALS USING MULTIPLE WINDOWS COHERENCEAND THE WEYL TRANSFORM

    E-Print Network [OSTI]

    Sandsten, Maria

    TIME-VARIABLEFILTERING OF MtTLTI[CHANNELSIGNALS USING MULTIPLE WINDOWS COHERENCEAND THE WEYL between all channel pairs. Time-frequency coherence functions are estimated using the multiple window

  19. The Genetic Structure of the Kuwaiti Population: mtDNA Inter- and Intra-population Variation

    E-Print Network [OSTI]

    Theyab, Jasem; Al-Bustan, Suzanne; Crawford, Michael H.

    2012-08-01

    it to their neighboring populations. These subpopulations were tested for genetic homogeneity and shown to be heterogeneous. Restriction fragment length polymorphism (RFLP) and mtDNA sequencing analyses of HVRI were used to reconstruct the genetic structure of Kuwait...

  20. Synthesis of few-walled carbon nanotube-Rh nanoparticles by arc discharge: Effect of selective oxidation

    SciTech Connect (OSTI)

    Zhang Yanfeng

    2012-06-15

    Highly crystalline rhodium (Rh) nanoparticles supported on carbon nanotubes were prepared by selective oxidation method. Carbon nanotubes and FeRh nanoparticles were simultaneously generated in hydrogen arc plasma. The as-grown nanomaterials can be purified by heat treatment in open air and by soaking in HCl. X-ray diffraction and selected area electron diffraction results reveal that as-grown FeRh nanoparticles have a typical chemical CsCl-type structure which can be transformed into a face-centered cubic structure by thermal annealing in the purification process. The purification process is selective toward the removal of the amorphous carbon coating the nanoparticles, and transforms Fe to Fe{sub 2}O{sub 3}. Fe{sub 2}O{sub 3} can be easily dissolved in hydrochloric acid, leaving carbon nanotubes-Rh nanoparticles. Rh nanoparticles with diameters of 2-60 nm are deposited uniformly on the surface of the carbon nanotube bundles. This simple and selective chemistry offers a new process for synthesizing and controlling Fe content in carbon nanotube-FeRh nanoparticles. Highlights: Black-Right-Pointing-Pointer High-crystallinity CNTs and FeRh nanoparticles were simultaneously generated in arc plasma. Black-Right-Pointing-Pointer The diameter distribution of CNTs depends on different gases. Black-Right-Pointing-Pointer Heat treatment in open air and soaking in HCl can convert CNTs-FeRh to CNTs-Rh. Black-Right-Pointing-Pointer The selective oxidation mechanisms of metal nanoparticles and carbon materials differ.

  1. Implied motion activation in cortical area MT can be explained by visual low-level features

    E-Print Network [OSTI]

    Oram, Mike

    ForReview Only Implied motion activation in cortical area MT can be explained by visual low Neuroscience #12;ForReview Only 1 Implied motion activation in cortical area MT can be explained by visual low, The Netherlands Page 1 of 51 Jounal of Cognitive Neuroscience 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

  2. Investigation of CaIr1-xPtxO3 and CaIr0.5Rh0.5O3 : structural properties, physical properties and stabilising conditions for post-perovskite oxides 

    E-Print Network [OSTI]

    Hirai, Shigeto

    2011-06-28

    Our understanding of the nature of Earth’s D” region was changed significantly by a recent finding by Murakami et al. (2004), who revealed a phase transition from perovskite to post-perovskite structure in MgSiO3 at about 125 GPa and 2500 K...

  3. Magnetism and superconductivity in U2PtxRh1?xC2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-09

    We report the phase diagram of the doping series U?PtxRh(1–x)C?, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Néel temperature of U?Rh?C? of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. Additionally, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ? 0.9, with Tc increasing with increasing x. Themore »reduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.« less

  4. Magnetism and superconductivity in U?PtxRh(1–x)C?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-01

    We report the phase diagram of the doping series U?PtxRh(1–x)C?, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Néel temperature of U?Rh?C? of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. In addition, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ? 0.9, with Tc increasing with increasing x.more »The reduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.« less

  5. Electronic structure of U2PtC2 and U2RhC2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ronning, F.; Zhu, J. -X.

    2015-03-18

    In this study, we present density functional theory calculations within the generalized gradient approximation of U2RhC2 and U2PtC2. We find the calculated density of states are significantly less than that measured by specific heat indicating the need for electronic correlations. The mass enhancement found for U2PtC2 is m*/mband ? 4.

  6. 2,3-Migration in Rh(II)-Catalyzed Reactions of -Trifluoroacetamido

    E-Print Network [OSTI]

    Wang, Jianbo

    2,3-Migration in Rh(II)-Catalyzed Reactions of -Trifluoroacetamido r-Diazocarbonyl Compounds Feng(II)-catalyzed reactions of these diazo compounds gave 2,3-migration products in high yields. 1,2-Migration is one,2-migration reactions, the 1,2-hydride migration is generally predominant, but 1,2-alkyl, 1,2-aryl, 1,2-thio

  7. Hydrogen sorption characteristics of nanostructured Pd–10Rh processed by cryomilling

    SciTech Connect (OSTI)

    Yang, Nancy; Yee, Joshua K.; Zhang, Zhihui; Kurmanaeva, Lilia; Cappillino, Patrick; Stavila, Vitalie; Lavernia, Enrique J.; San Marchi, Chris

    2014-10-03

    Palladium and its alloys are model systems for studying solid-state storage of hydrogen. Mechanical milling is commonly used to process complex powder systems for solid-state hydrogen storage; however, milling can also be used to evolve nanostructured powder to modify hydrogen sorption characteristics. In the present study, cryomilling (mechanical attrition milling in a cryogenic liquid) is used to produce nanostructured palladium-rhodium alloy powder. Characterization of the cryomilled Pd-10Rh using electron microscopy, X-ray diffraction, and surface area analysis reveals that (i) particle morphology evolves from spherical to flattened disk-like particles; while the (ii) crystallite size decreases from several microns to less than 100 nm and (iii) dislocation density increases with increased cryomilling time. Hydrogen absorption and desorption isotherms as well as the time scales for absorption were measured for cryomilled Pd-10Rh, and correlated with observed microstructural changes induced by the cryomilling process. In short, as the microstructure of the Pd-10Rh alloy is refined by cryomilling: (i) the maximum hydrogen concentration in the ?-phase increases, (ii) the pressure plateau becomes flatter, and (iii) the equilibrium hydrogen capacity at 760 Torr increases. In addition, the rate of hydrogen absorption was reduced by an order of magnitude compared to non-cryomilled (atomized) powder.

  8. Hydrogen sorption characteristics of nanostructured Pd–10Rh processed by cryomilling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Nancy; Yee, Joshua K.; Zhang, Zhihui; Kurmanaeva, Lilia; Cappillino, Patrick; Stavila, Vitalie; Lavernia, Enrique J.; San Marchi, Chris

    2014-10-03

    Palladium and its alloys are model systems for studying solid-state storage of hydrogen. Mechanical milling is commonly used to process complex powder systems for solid-state hydrogen storage; however, milling can also be used to evolve nanostructured powder to modify hydrogen sorption characteristics. In the present study, cryomilling (mechanical attrition milling in a cryogenic liquid) is used to produce nanostructured palladium-rhodium alloy powder. Characterization of the cryomilled Pd-10Rh using electron microscopy, X-ray diffraction, and surface area analysis reveals that (i) particle morphology evolves from spherical to flattened disk-like particles; while the (ii) crystallite size decreases from several microns to less thanmore »100 nm and (iii) dislocation density increases with increased cryomilling time. Hydrogen absorption and desorption isotherms as well as the time scales for absorption were measured for cryomilled Pd-10Rh, and correlated with observed microstructural changes induced by the cryomilling process. In short, as the microstructure of the Pd-10Rh alloy is refined by cryomilling: (i) the maximum hydrogen concentration in the ?-phase increases, (ii) the pressure plateau becomes flatter, and (iii) the equilibrium hydrogen capacity at 760 Torr increases. In addition, the rate of hydrogen absorption was reduced by an order of magnitude compared to non-cryomilled (atomized) powder.« less

  9. Specific heat of CeRhIn5: Pressure-driven evolution of the ground state from antiferromagnetism to superconductivity

    E-Print Network [OSTI]

    2001-01-01

    Specific Heat of CeRhIn5: Pressure–Driven Evolution of the32306 Measurements of the specific heat of antiferromagneticsee text). Fig. 2. (a) The specific heat, for representative

  10. Summary of the Optics, IR, Injection, Operations, Reliability...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Summary of the Optics, IR, Injection, Operations, Reliability and Instrumentation Working Group Citation Details In-Document Search Title: Summary of the Optics,...

  11. Ir-based alloys for ultra-high temperature applications

    DOE Patents [OSTI]

    Liu, Chain T.; George, Easo P.; Bloom, Everett E.

    2006-01-03

    An alloy composition includes, in atomic percent: about 1 to about 10% of at least one element selected from the group consisting of Zr and Hf, balance Ir.

  12. Ovarian and hormonal events during synchronization of ovulation and timed appointment breeding of Bos indicus-influenced cattle using intravaginal progesterone, GnRH and prostaglandin F2(alpha) 

    E-Print Network [OSTI]

    Saldarriaga Lopez, Juan Pablo

    2007-04-25

    of GnRH (GnRH-1) on day 0, removal of the CIDR and injection of prostaglandin F2a (PGF on d 7, and injection of GnRH (GnRH-2) and TAI 48 h later. In experiment 1 (Exp. 1), 335 females were stratified by BCS, parity and d postpartum before random...

  13. Moving Object Detection and Compression in IR Sequences

    E-Print Network [OSTI]

    Agrawal, Amit

    infrared (IR) sensors. The aim is to use IR image sequences to detect moving objects (humans or vehicles computational power of computing devices attached to the sensor, the algorithms should be computationally simple implemented in C/C++ and their performance has been evaluated the using Hitachi's SH4 platform with software

  14. A New DBMS Architecture for DB-IR Integration

    E-Print Network [OSTI]

    Whang, Kyu-Young

    A New DBMS Architecture for DB-IR Integration Kyu-Young Whang Computer Science Department. Nowadays, as there is an increasing need to integrate the DBMS (for structured data) with Information is required. In this talk, we present a new DBMS architecture applica- ble to DB-IR integration, which we call

  15. Modeling IR Radiative Loss from Eppley PSP Pyranometers Frank Vignola

    E-Print Network [OSTI]

    Oregon, University of

    Renewable Energy Laboratory ABSTRACT A method has been developed to estimate IR radiative losses using solar, irradiance, IR, modeling, global, diffuse, PSP 1. INTRODUCTION Since the 1970s, solar radiation data has been Energy Laboratory (NREL) data page3 along with the original global data. Corrections to the PSP

  16. Simultaneous multi-beam planar array IR (pair) spectroscopy

    DOE Patents [OSTI]

    Elmore, Douglas L.; Rabolt, John F.; Tsao, Mei-Wei

    2005-09-13

    An apparatus and method capable of providing spatially multiplexed IR spectral information simultaneously in real-time for multiple samples or multiple spatial areas of one sample using IR absorption phenomena requires no moving parts or Fourier Transform during operation, and self-compensates for background spectra and degradation of component performance over time. IR spectral information and chemical analysis of the samples is determined by using one or more IR sources, sampling accessories for positioning the samples, optically dispersive elements, a focal plane array (FPA) arranged to detect the dispersed light beams, and a processor and display to control the FPA, and display an IR spectrograph. Fiber-optic coupling can be used to allow remote sensing. Portability, reliability, and ruggedness is enhanced due to the no-moving part construction. Applications include determining time-resolved orientation and characteristics of materials, including polymer monolayers. Orthogonal polarizers may be used to determine certain material characteristics.

  17. NaIrO3—A Pentavalent Post-perovskite

    SciTech Connect (OSTI)

    M Bremholm; S Dutton; P Stephens; R Cava

    2011-12-31

    Sodium iridium (V) oxide, NaIrO{sub 3}, was synthesized by a high pressure solid state method and recovered to ambient conditions. It is found to be isostructural with CaIrO{sub 3}, the much-studied structural analog of the high-pressure post-perovskite phase of MgSiO{sub 3}. Among the oxide post-perovskites, NaIrO{sub 3} is the first example with a pentavalent cation. The structure consists of layers of corner- and edge-sharing IrO{sub 6} octahedra separated by layers of NaO{sub 8} bicapped trigonal prisms. NaIrO{sub 3} shows no magnetic ordering and resistivity measurements show non-metallic behavior. The crystal structure, electrical and magnetic properties are discussed and compared to known post-perovskites and pentavalent perovskite metal oxides.

  18. Structural and ferromagnetic properties of an orthorhombic phase of MnBi stabilized with Rh additions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Taufour, Valentin; Thimmaiah, Srinivasa; March, Stephen; Saunders, Scott; Sun, Kewei; Lamichhane, Tej Nath; Kramer, Matthew J.; Bud’ko, Sergey L.; Canfield, Paul C.

    2015-07-28

    The article addresses the possibility of alloy elements in MnBi which may modify the thermodynamic stability of the NiAs-type structure without significantly degrading the magnetic properties. The addition of small amounts of Rh and Mn provides an improvement in the thermal stability with some degradation of the magnetic properties. The small amounts of Rh and Mn additions in MnBi stabilize an orthorhombic phase whose structural and magnetic properties are closely related to the ones of the previously reported high-temperature phase of MnBi (HT MnBi). The properties of the HT MnBi, which is stable between 613 and 719 K, have notmore »been studied in detail because of its transformation to the stable low-temperature MnBi (LT MnBi), making measurements near and below its Curie temperature difficult. The Rh-stabilized MnBi with chemical formula Mn1.0625–xRhxBi [x=0.02(1)] adopts a new superstructure of the NiAs/Ni2In structure family. It is ferromagnetic below a Curie temperature of 416 K. The critical exponents of the ferromagnetic transition are not of the mean-field type but are closer to those associated with the Ising model in three dimensions. The magnetic anisotropy is uniaxial; the anisotropy energy is rather large, and it does not increase when raising the temperature, contrary to what happens in LT MnBi. The saturation magnetization is approximately 3?B/f.u. at low temperatures. Thus, while this exact composition may not be application ready, it does show that alloying is a viable route to modifying the stability of this class of rare-earth-free magnet alloys.« less

  19. Experiment operations plan for the MT-4 experiment in the NRU reactor. [PWR

    SciTech Connect (OSTI)

    Russcher, G.E.; Wilson, C.L.; Parchen, L.J.; Marshall, R.K.; Hesson, G.M.; Webb, B.J.; Freshley, M.D.

    1983-06-01

    A series of thermal-hydraulic and cladding materials deformation experiments were conducted using light-water reactor fuel bundles as part of the Pacific Northwest Laboratory Loss-of-Coolant Accident (LOCA) Simulation Program. This report is the formal operations plan for MT-4 - the fourth materials deformation experiment conducted in the National Research Universal (NRU) reactor, Chalk River, Ontario, Canada. A major objective of MT-4 was to simulate a pressurized water reactor LOCA that could induce fuel rod cladding deformation and rupture due to a short-term adiabatic transient and a peak fuel cladding temperature of 1200K (1700/sup 0/F).

  20. GnRH-induced LH release in heifers: effect of nutrient restriction during gestation 

    E-Print Network [OSTI]

    Killen, James Harold

    1983-01-01

    RH-Induced LH Release in Heif era: Effect of Nutrient Restriction During Gestation. (May 1983) James Harold Killen, B. S. , University of Arizona Co-Chairmen of Advisory Committee: Dr. David W. Forrest Dr. Paul G. Harms This study was undertaken.... 4+/-18. 4, 64. 9+/-16. 8, and 29. 6+/-12. 4 ng/ml (P&. 10) for pr spartum heifer s snd 18. 4+/-4. 7, 14. 6+/-S. 4 and 31. 7+/- 5. 7 ng/ml (P&. 10) f or postpartum heifers in the L, M snd G groups, r eepectively. LSM for plasma LH response and peak...

  1. Syngas production from butane using a flame-made Rh/Ce0.5Zr0.5O2 Nico Hotz a

    E-Print Network [OSTI]

    Daraio, Chiara

    Syngas production from butane using a flame-made Rh/Ce0.5Zr0.5O2 catalyst Nico Hotz a , Michael J the production of H2- and CO-rich syngas from butane was investigated for different Rh loadings (0­2.0 wt% Rh for a temperature range from 225 to 750 8C. The main goal of this study was the efficient processing of butane

  2. The influence of nano-architectured CeOx supports in RhPd/CeO? for the catalytic ethanol steam reforming reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Divins, N. J.; Senanayake, S. D.; Casanovas, A.; Xu, W.; Trovarelli, A.; Llorca, J.

    2015-01-19

    The ethanol steam reforming (ESR) reaction has been tested over RhPd supported on polycrystalline ceria in comparison to structured supports composed of nanoshaped CeO? cubes and CeO? rods tailored towards the production of hydrogen. At 650-700 K the hydrogen yield follows the trend RhPd/CeO?-cubes > RhPd/CeO? -rods > RhPd/CeO?- polycrystalline, whereas at temperatures higher than 800 K the catalytic performance of all samples is similar and close to the thermodynamic equilibrium. The improved performance of RhPd/CeO?-cubes and RhPd/CeO? -rods for ESR at low temperature is mainly ascribed to higher water-gas shift activity and a strong interaction between the bimetallic -more »oxide support interaction. STEM analysis shows the existence of RhPd alloyed nanoparticles in all samples, with no apparent relationship between ESR performance and RhPd particle size. X-ray diffraction under operating conditions shows metal reorganization on {100} and {110} ceria crystallographic planes during catalyst activation and ESR, but not on {111} ceria crystallographic planes. The RhPd reconstructing and tuned activation over ceria nanocubes and nanorods is considered the main reason for better catalytic activity with respect to conventional catalysts based on polycrystalline ceria« less

  3. Dr. Joseph A. Shaw Electrical & Computer Engineering Dept., Montana State University, Bozeman, MT 59717

    E-Print Network [OSTI]

    Lawrence, Rick L.

    Dr. Joseph A. Shaw Electrical & Computer Engineering Dept., Montana State University, Bozeman, MT M.S. Electrical Engineering University of Utah 1987 B.S. Electrical Engineering University of Alaska Experience: 2008 ­ present Professor ­ Electrical & Computer Engineering (ECE) Department, Montana State

  4. Synchronous Dependency Insertion Grammars A Grammar Formalism for Syntax Based Statistical MT

    E-Print Network [OSTI]

    Synchronous Dependency Insertion Grammars A Grammar Formalism for Syntax Based Statistical MT Yuan formalism specifically designed for syntax-based sta- tistical machine translation. The synchro- nous between lan- guages, which many other synchronous grammars are unable to model. A Depend- ency Insertion

  5. MONTANA OUTDOORS 3130 MARCH APRIL 2014 FWP.MT.GOV/MTOUTDOORS Why mountain bluebirds

    E-Print Network [OSTI]

    Duckworth, Renée

    MONTANA OUTDOORS 3130 MARCH APRIL 2014 FWP.MT.GOV/MTOUTDOORS TURF WAR TWIST Why mountain bluebirds are good for this species in western Montana valleys but don't benefit, in the long run, mountain bluebirds. Although mountain blue- birds also lost nesting sites, they had evolved to also use habitats at higher

  6. Intermountain GIS Conference. April 1923 2010, Bozeman, MT. Patrick Lawrence, Maxwell BD, Rew LJ

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    Intermountain GIS Conference. April 1923 2010, Bozeman, MT. Patrick Lawrence, Maxwell BD, Rew in the Python programming language, drawing on Python's builtin library, the RPy extension, ArcGIS geoprocessing and ArcGIS Server. As inputs, it accepts transect shapefiles, transect text files, or point

  7. MT3DMS, A Modular Three-Dimensional Multispecies Transport Model User Guide to the

    E-Print Network [OSTI]

    Zheng, Chunmiao

    .M. Cozzarelli, M.H. Lahvis, and B.A. Bekins. 1998. Ground water contamination by crude oil near Bemidji (LNAPL) contaminant through the unsaturated zone and the formation of an oil lens on the water tableMT3DMS, A Modular Three-Dimensional Multispecies Transport Model ­ User Guide to the Hydrocarbon

  8. Hybrid Rule-Based Example-Based MT: Feeding Apertium with Sub-sentential Translation Units

    E-Print Network [OSTI]

    Way, Andy

    Hybrid Rule-Based ­ Example-Based MT: Feeding Apertium with Sub-sentential Translation Units Felipe S´anchez-Mart´inez Mikel L. Forcada Andy Way Dept. Llenguatges i Sistemes Inform`atics Universitat University Dublin 9, Ireland {mforcada,away}@computing.dcu.ie Abstract This paper describes a hybrid machine

  9. Stress magnitude and its temporal variation at Mt. Asama Volcano, Japan, from seismic anisotropy and GPS

    E-Print Network [OSTI]

    Utrecht, Universiteit

    Stress magnitude and its temporal variation at Mt. Asama Volcano, Japan, from seismic anisotropy stress Japan The Earth's stress regime is fundamental to its physical processes, yet few methods can determine absolute stress, and measurements of temporal variations in stress are controversial. The Global

  10. Some Effects of Mt. St. Helens Volcanic Ash on Juvenile Salmon Smolts

    E-Print Network [OSTI]

    Some Effects of Mt. St. Helens Volcanic Ash on Juvenile Salmon Smolts TIMOTHY W. NEWCOMB and THOMAS. Helens, which was completely decimated with vol- canic ash and mud slides. Heavy sediment loads smolts were exposed to various concentrations ofairborne volcanic ash from the 18 May 1980 eruption

  11. High-latitude vegetation dynamics: 850 years of vegetation development on Mt Hekla, Iceland 

    E-Print Network [OSTI]

    Cutler, Nick

    2008-01-01

    on Mt Hekla in south-central Iceland. The chronosequence approach was used to infer 850 years of vegetation development from a suite of 14 lava flows (five of which had been disturbed by the deposition of volcanic tephra). The thesis is organised around...

  12. Geophys. 1. R. astr. Soc. (1987),89,7-18 MT and reflection: an essential combination

    E-Print Network [OSTI]

    Jones, Alan G.

    1987-01-01

    ) studies and seismic reflection profiles conducted. Unfortunately, over many more regions the seismic of the magnetotelluric (MT) technique as having a vertical resolution equivalent to the seismic refraction method, in almost every case, be made wherever a seismic reflection survey is undertaken. Examples are shown from

  13. IRS Announces New Tribal Economic Development Bond Allocation Guidance

    Broader source: Energy.gov [DOE]

    Treasury and the IRS published new guidance today allocating Tribal Economic Development Bonds (TEDBs) for Tribes that have projects that are in the final stages of going to the market to receive financing.

  14. DWEA Webinar: IRS Guidance for Small Wind Turbines

    Broader source: Energy.gov [DOE]

    The U.S. Internal Revenue Service (IRS) has issued Notice 2015-4 providing new performance and quality standards of small wind turbines – defined as having a nameplate capacity of up to 100 kW – in...

  15. New IRS Rules for Small and Medium Wind Turbines

    Broader source: Energy.gov [DOE]

    The Small Wind Certification Council (SWCC) will host a webinar on how certification is being used to meet the new Internal Revenue Service (IRS) requirements for small and medium wind turbines...

  16. IR-laser initiated combustion -- A step toward complete combustion

    SciTech Connect (OSTI)

    Laghai, A.; Nabavi, S.H.; Servati, H.B.; Syed, F.

    1996-09-01

    The new global environmental regulations for reducing the engine emissions from both moving and stationary sources, as well as improvement in fuel economy are the major motifs to obtain a perfect combustion process and exhaust aftertreatment methods. Infrared (IR)-Laser initiated combustion provides a very high initial temperature, which produces propagation of a turbulent thermopressure pulse that results in a fast burning and improved combustion. The role of IR is to maximize the heat generation efficiency.

  17. Liquid chromatography/Fourier transform IR spectrometry interface flow cell

    DOE Patents [OSTI]

    Johnson, Charles C. (Fairfield, OH); Taylor, Larry T. (Blacksburg, VA)

    1986-01-01

    A zero dead volume (ZDV) microbore high performance liquid chromatography (.mu.HPLC)/Fourier transform infrared (FTIR) interface flow cell includes an IR transparent crystal having a small diameter bore therein through which a sample liquid is passed. The interface flow cell further includes a metal holder in combination with a pair of inner, compressible seals for directly coupling the thus configured spectrometric flow cell to the outlet of a .mu.HPLC column end fitting to minimize the transfer volume of the effluents exiting the .mu.HPLC column which exhibit excellent flow characteristics due to the essentially unencumbered, open-flow design. The IR beam passes transverse to the sample flow through the circular bore within the IR transparent crystal, which is preferably comprised of potassium bromide (KBr) or calcium fluoride (CaF.sub.2), so as to minimize interference patterns and vignetting encountered in conventional parallel-plate IR cells. The long IR beam pathlength and lensing effect of the circular cross-section of the sample volume in combination with the refractive index differences between the solvent and the transparent crystal serve to focus the IR beam in enhancing sample detection sensitivity by an order of magnitude.

  18. Liquid chromatography/Fourier transform IR spectrometry interface flow cell

    DOE Patents [OSTI]

    Johnson, C.C.; Taylor, L.T.

    1985-01-04

    A zero dead volume (ZDV) microbore high performance liquid chromatography (..mu.. HPLC)/Fourier transform infrared (FTIR) interface flow cell includes an IR transparent crystal having a small diameter bore therein through which a sample liquid is passed. The interface flow cell further includes a metal holder in combination with a pair of inner, compressible seals for directly coupling the thus configured spectrometric flow cell to the outlet of a ..mu.. HPLC column end fitting to minimize the transfer volume of the effluents exiting the ..mu.. HPLC column which exhibit excellent flow characteristics due to the essentially unencumbered, open-flow design. The IR beam passes transverse to the sample flow through the circular bore within the IR transparent crystal, which is preferably comprised of potassium bromide (KBr) or calcium fluoride (CaF/sub 2/), so as to minimize interference patterns and vignetting encountered in conventional parallel-plate IR cells. The long IR beam pathlength and lensing effect of the circular cross-section of the sample volume in combination with the refractive index differences between the solvent and the transparent crystal serve to focus the IR beam in enhancing sample detection sensitivity by an order of magnitude.

  19. NGC 7538 : Multiwavelength Study of Stellar Cluster Regions associated with IRS 1-3 and IRS 9 sources

    E-Print Network [OSTI]

    Mallick, K K; Tamura, M; Pandey, A K; Dib, S; Ghosh, S K; Sunada, K; Zinchenko, I; Pirogov, L; Tsujimoto, M

    2014-01-01

    We present deep and high-resolution (FWHM ~ 0.4 arcsec) near-infrared (NIR) imaging observations of the NGC 7538 IRS 1-3 region (in JHK bands), and IRS 9 region (in HK bands) using the 8.2m Subaru telescope. The NIR analysis is complemented with GMRT low-frequency observations at 325, 610, and 1280 MHz, molecular line observations of H13CO+ (J=1-0), and archival Chandra X-ray observations. Using the 'J-H/H-K' diagram, 144 Class II and 24 Class I young stellar object (YSO) candidates are identified in the IRS 1-3 region. Further analysis using 'K/H-K' diagram yields 145 and 96 red sources in the IRS 1-3 and IRS 9 regions, respectively. A total of 27 sources are found to have X-ray counterparts. The YSO mass function (MF), constructed using a theoretical mass-luminosity relation, shows peaks at substellar (~0.08-0.18 Msolar) and intermediate (~1-1.78 Msolar) mass ranges for the IRS 1-3 region. The MF can be fitted by a power law in the low mass regime with a slope of Gamma ~ 0.54-0.75, which is much shallower t...

  20. Single to Multiquasiparticle Excitations in the Itinerant Helical Magnet CeRhIn5

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stock, C.; Rodriguez-Rivera, J. A.; Schmalzl, K.; Rodriguez, E. E.; Stunault, A.; Petrovic, C.

    2015-06-19

    Neutron scattering is used to measure the quantum spin fluctuations in CeRhIn5 - the parent material of the eXIn5 superconducting series. Out-of-plane spin fluctuations are gapped and localized in momentum, similar to the spin excitons in CeCoIn5. The in-plane fluctuations consist of sharp spin-wave excitations parameterized by a nearest neighbor exchange JRKKY =0.88 ± 0.05 meV that crossover to a temporally and spatially broad multiparticle spectrum with energies of ~ 2 × JRKKY . This continuum represents composite fluctuations that illustrate the breakdown of single magnons originating from the delicate energy balance between localized 4f and itinerant behavior in amore »heavy metal. The experiment therefore shows how quasiparticle behavior is changed by the close proximity of quantum criticality.« less

  1. Synthesis, NMR spectra, and structure of rhodium hydride complexes with Rh-Sn bonds

    SciTech Connect (OSTI)

    Krut'ko, B.P.; Permin, A.B.; Petrosyan, V.S.; Reutov, O.A.

    1985-06-20

    The authors study the hydride complexes using Sn 119 and H 1 NMR spectroscopy. The spectra were taken in a pulse mode on a Varian FT-80A spectrometer equipped with a wideband system at 29.66 and 79.54 MHz. The Sn 119 and H 1 NMR spectral parameters for a solution of the complex (Bu/sub 4/N)/sub 3/ (HRh(SnCl/sub 3/)/sub 5/) in CD/sub 3/CN are shown, the spectra show that the (HRh(SnCl/sub 3/)/sub 5/)/sup 3 -/ anion has octahedral structure with four equatorial and one axial Rh-Sn bonds. New rhodium hydride complexes with general formula (R/sub 4/N)/sub 3/(HRh(SnCl/sub 3/)/sub 5/) were synthesized.

  2. Dynamics of NO reduction by H2 on Rh(111): Velocity and angular distributions of the N2 product

    E-Print Network [OSTI]

    Sibener, Steven

    Dynamics of NO reduction by H2 on Rh(111): Velocity and angular distributions of the N2 product J; accepted 17 January 1996 The velocity and angular distributions of N2 produced from the reduction temperature. Both the angular and velocity distributions are well fit by bimodal forms. The high energy

  3. Applied reaction dynamics: Efficient synthesis gas production via single collision partial oxidation of methane to CO on Rh,,111...

    E-Print Network [OSTI]

    Sibener, Steven

    the yield of CO from the partial oxidation of CH4 on a Rh 111 catalytic substrate, CH4+ 1/2 O2CO+2H2 to the multistep route to methane utilization, namely, steam reforming coupled with the water gas shift reaction.1

  4. Energetics of C-H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [TpRh(CNneopentyl)] Complex

    E-Print Network [OSTI]

    Jones, William D.

    Energetics of C-H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [Tp activation of fluorinated aromatic hydrocarbons by [TpRh(CNneopentyl)] resulted in the formation of products of homogeneous transition-metal catalysts to activate and functionalize C-H bonds of hydrocarbons for industrial

  5. Hazard assessment in geothermal exploration: The case of Mt. Parker, Southern Philippines

    SciTech Connect (OSTI)

    Delfin, F.G. Jr.; Salonga, N.D.; Bayon, F.E.B.

    1996-12-31

    Hazard assessment of the Mt. Parker geothermal prospect, conducted in parallel with the surface exploration from 1992 to 1994, was undertaken to determine the long-term suitability of the prospect for development. By comparison with other acidic magmatic-hydrothermal systems in the Philippines, the geochemical data indicated minimal input of acidic magmatic fluids into Mt. Parker`s hydrothermal system. This system was regarded to be a neutral-pH and high-enthalpy chloride reservoir with temperature of at least 200-250{degrees}C. These favorable geochemical indications contrasted sharply with the C-14 and volcanological data indicating a shallow magmatic body with a potential for future eruption. This hazard led PNOC EDC to discontinue the survey and abandon the prospect by late 1994. On September 6, 1995, a flashflood of non-volcanic origin from the caldera lake killed nearly 100 people on the volcano`s northwestern flank.

  6. Superconducting and magnetic properties of Sr?Ir?Sn??

    SciTech Connect (OSTI)

    Biswas, P. K. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Wang, Kefeng [Brookhaven National Lab. (BNL), Upton, NY (United States); Amato, A. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Khasanov, R. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Luetkens, H. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Petrovic, C. [Brookhaven National Lab. (BNL), Upton, NY (United States); Cook, R. M. [Univ. of Warwick, Coventry (United Kingdom); Lees, M. R. [Univ. of Warwick, Coventry (United Kingdom); Morenzoni, E. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    2014-10-01

    Magnetization and muon spin relaxation or rotation (µSR) measurements have been performed to study the superconducting and magnetic properties of Sr?Ir?Sn??. From magnetization measurements the lower and upper critical fields of Sr?Ir?Sn?? are found to be 81(1) Oe and 14.4(2) kOe, respectively. Zero-field µSR data show no sign of any magnetic ordering or weak magnetism in Sr?Ir?Sn??. Transverse-field µSR measurements in the vortex state provided the temperature dependence of the magnetic penetration depth ?. The dependence of ??² with temperature is consistent with the existence of single s-wave energy gap in the superconducting state of Sr?Ir?Sn?? with a gap value of 0.82(2) meV at absolute zero temperature. The magnetic penetration depth at zero temperature ?(0) is 291(3) nm. The ratio ?(0)/kBTc = 2.1(1) indicates that Sr?Ir?Sn?? should be considered as a strong-coupling superconductor.

  7. Superconducting and magnetic properties of Sr?Ir?Sn??

    SciTech Connect (OSTI)

    Biswas, P. K.; Wang, Kefeng; Amato, A.; Khasanov, R.; Luetkens, H.; Petrovic, C.; Cook, R. M.; Lees, M. R.; Morenzoni, E.

    2014-10-10

    Magnetization and muon spin relaxation or rotation (µSR) measurements have been performed to study the superconducting and magnetic properties of Sr?Ir?Sn??. From magnetization measurements the lower and upper critical fields of Sr?Ir?Sn?? are found to be 81(1) Oe and 14.4(2) kOe, respectively. Zero-field µSR data show no sign of any magnetic ordering or weak magnetism in Sr?Ir?Sn??. Transverse-field µSR measurements in the vortex state provided the temperature dependence of the magnetic penetration depth ?. The dependence of ??² with temperature is consistent with the existence of single s-wave energy gap in the superconducting state of Sr?Ir?Sn?? with a gap value of 0.82(2) meV at absolute zero temperature. The magnetic penetration depth at zero temperature ?(0) is 291(3) nm. The ratio ?(0)/kBTc = 2.1(1) indicates that Sr?Ir?Sn?? should be considered as a strong-coupling superconductor.

  8. Superconducting and magnetic properties of Sr?Ir?Sn??

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Biswas, P. K.; Wang, Kefeng; Amato, A.; Khasanov, R.; Luetkens, H.; Petrovic, C.; Cook, R. M.; Lees, M. R.; Morenzoni, E.

    2014-10-10

    Magnetization and muon spin relaxation or rotation (µSR) measurements have been performed to study the superconducting and magnetic properties of Sr?Ir?Sn??. From magnetization measurements the lower and upper critical fields of Sr?Ir?Sn?? are found to be 81(1) Oe and 14.4(2) kOe, respectively. Zero-field µSR data show no sign of any magnetic ordering or weak magnetism in Sr?Ir?Sn??. Transverse-field µSR measurements in the vortex state provided the temperature dependence of the magnetic penetration depth ?. The dependence of ??² with temperature is consistent with the existence of single s-wave energy gap in the superconducting state of Sr?Ir?Sn?? with a gap valuemore »of 0.82(2) meV at absolute zero temperature. The magnetic penetration depth at zero temperature ?(0) is 291(3) nm. The ratio ?(0)/kBTc = 2.1(1) indicates that Sr?Ir?Sn?? should be considered as a strong-coupling superconductor.« less

  9. Rock Sampling At Mt Ranier Area (Frank, 1995) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/ColoradoRemsenburg-Speonk, NewMichigan: Energy Resources JumpMt Ranier Area (Frank, 1995)

  10. EC305 Problem Set 1 1. Let x(t) = m(t) cos 2fct, where m(t) is a real lowpass signal with bandwidth W and

    E-Print Network [OSTI]

    Bhashyam, Srikrishna

    EC305 Problem Set 1 1. Let x(t) = m(t) cos 2fct, where m(t) is a real lowpass signal with bandwidth a bandpass signal x(t) = m1(t) cos 2fct - m2(t) sin 2fct. (a) Determine the in-phase and quadrature components of this signal when the local os- cillators used have a phase offset of , i.e., they are cos (2fct

  11. Tidally dominated depositional environment for the Mt. Simon Sandstone in central Illinois

    SciTech Connect (OSTI)

    Sargent, M.L.; Lasemi, Z. (Illinois State Geological Survey, Champaign, IL (United States))

    1993-03-01

    Several hundred feet of core from the upper part of the Mt. Simon in central Illinois have been examined macroscopically. Grain sizes and their systematics, bedding characteristics, sedimentary structures, and relationships among beds show that the upper Mt. Simon Sandstone is composed of a series of fining-upward cycles up to 10 m (30 feet) thick. A typical cycle consists, in ascending order, of a sandy subtidal facies, a mixed sand and mud intertidal-flat facies, and a muddy upper tidal-flat facies upward through the succession, the maximum and average grain size becomes progressively finer and the cycles thinner. The lower sandstone of each cycle contains beds that are massive to cross bedded and cross laminated; some beds show scoured reactivation surfaces. A few cycles contain a middle unit characterized by flaser and lenticular bedding and abundant mudcracks. Mudcracks also are common in the shale beds at the top of each cycle. Sedimentary structures such as reactivation surfaces, flaser and lenticular bedding, and mudcracks suggest that these cycles were deposited in peritidal environments. The presence of Skolithos in some cycles suggests very shallow marine conditions. The within-cycle upward fining is caused by regression or progradation that reflects a progressive decrease in current velocity from subtidal to intertidal parts of the tidal flat. Frequent flooding of the tidal flat resulted in repeated fining-upward cycles within the upper part of the Mt. Simon Sandstone.

  12. Application of Remote Sensing Technology and Ecological Modeling of Forest Carbon Stocks in Mt. Apo Natural Park, Philippines 

    E-Print Network [OSTI]

    Leal, Ligaya Rubas

    2015-01-23

    This dissertation work explored the application of remote sensing technology for the assessment of forest carbon storage in Mt. Apo Natural Park. Biomass estimation is traditionally conducted using destructive sampling with high levels...

  13. Sequence Stratigraphy and Detrital Zircon Geochronology of Middle-Late Ordovician Mt. Wilson Quartzite, British Columbia, Canada 

    E-Print Network [OSTI]

    Hutto, Andrew Paul

    2012-07-16

    STRATIGRAPHY AND DETRITAL ZIRCON GEOCHRONOLOGY OF MIDDLE-LATE ORDOVICIAN MT. WILSON QUARTZITE, BRITISH COLUMBIA CANADA A Thesis by ANDREW PAUL HUTTO Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 2012 Major Subject: Geology Sequence Stratigraphy and Detrital Zircon Geochronology of Middle-Late Ordovician Mt. Wilson...

  14. Low Dose IR Creates an Oncogenic Microenvironment by Inducing Premature

    SciTech Connect (OSTI)

    Yuan, Zhi-Min

    2013-04-28

    Introduction Much of the work addressing ionizing radiation-induced cellular response has been carried out mainly with the traditional cell culture technique involving only one cell type, how cellular response to IR is influenced by the tissue microenvironment remains elusive. By use of a three-dimensional (3D) co-culture system to model critical interactions of different cell types with their neighbors and with their environment, we recently showed that low-dose IR-induced extracellular signaling via the tissue environment affects profoundly cellular responses. This proposal aims at determining the response of mammary epithelial cells in a tissue-like setting.

  15. Structural and magnetic properties in the polymorphs of CeRh{sub 0.5}Ge{sub 1.5}

    SciTech Connect (OSTI)

    Kalsi, Deepti; Subbarao, Udumula [New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064 (India); Rayaprol, Sudhindra [UGC-DAE Consortium for Scientific Research, R-5 Shed, B.A.R.C Campus, Trombay, Mumbai-400085 (India); Peter, Sebastian C., E-mail: sebastiancp@jncasr.ac.in [New Chemistry Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore-560064 (India)

    2014-04-01

    We investigate the structural and magnetic properties in the polymorphs of a new compound CeRh{sub 0.5}Ge{sub 1.5}. Depending upon the starting materials, and the slightly different synthesis method, we find that CeRh{sub 0.5}Ge{sub 1.5} compound exists in two different space groups. The first compound, ?-CeRh{sub 0.5}Ge{sub 1.5} crystallizes in tetragonal ?-ThSi{sub 2} structure type in space group I4{sub 1}/amd with lattice parameters, a=4.2034(6) Å and c=14.770(3) Å. In this structure, the cerium atoms occupy the position between the Rh/Ge tetrahedral layers. On the other hand, the second compound, namely ?-CeRh{sub 0.5}Ge{sub 1.5} crystallizes in the AlB{sub 2} type hexagonal structure in space group P6/mmm, with lattice parameters, a=4.2615(7) Å and c=4.1813(9) Å. The crystal structure of ?-CeRh{sub 0.5}Ge{sub 1.5} consists of two dimensional Rh/Ge hexagonal units and the cerium atoms are sandwiched between them. Magnetization studies exhibit magnetic ordering, as evident from a sharp peak in the plot of magnetic susceptibility measured as a function of temperature in a fixed magnetic field, in ?-CeRh{sub 0.5}Ge{sub 1.5} and ?-CeRh{sub 0.5}Ge{sub 1.5} at 3.6 K and 12 K, respectively. Structural and magnetic properties of both compounds are presented and discussed here. - Graphical abstract: Two polymorphs of a new compound CeRh{sub 0.5}Ge{sub 1.5} in the ?-ThSi{sub 2} and AlB{sub 2} structure types were synthesized by arc melting. The magnetic measurements of both CeRh{sub 0.5}Ge{sub 1.5} phases suggest spin-glass behavior. - Highlights: • A new compound CeRh{sub 0.5}Ge{sub 1.5} in two difference phases was synthesized by arc melting. • The crystal structure of both compounds was determined from the single crystal XRD. • Isothermal relaxation measurements suggesting spin-glass like anomalies in both phases.

  16. Saving and accessing the old IR literature Donna Harman

    E-Print Network [OSTI]

    Hiemstra, Djoerd

    there are many scanning projects underway, such as Google books and the Open Library Alliance, these projects library for just us IR folks. The ACM digital library had little interest in what they called the "grey they maintain their library in a proprietary format that would not allow us to insert our own search engine (or

  17. Growth of graphene on Ir(111) Johann Coraux1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    a renewed interest as a route towards high quality graphene prepared in a reproducible manner. Here weC) substrate has attracted much interest. Whatever the recent progress in the preparation of grapheneGrowth of graphene on Ir(111) Johann Coraux1 ,, Alpha T. N'Diaye1 §, Martin Engler1 , Carsten Busse

  18. Experiment 6. QUANTINTATIVE ANALYSIS OF XYLENES USING IR SPECTROSCOPY

    E-Print Network [OSTI]

    Nazarenko, Alexander

    with a syringe full of the solvent. Dry the cell. 2. Refill the clean, dry sample cell with solution #1 and run syringe for loading sealed infrared cells. 4. A 0.1 mm sealed IR cell. These cells are kept version of the baseline technique to the unknown and standards. II Sealed Cells. The sealed cells used

  19. Resources for Chinese-English Cross-Language IR

    E-Print Network [OSTI]

    Oard, Doug

    1 Resources for Chinese-English Cross-Language IR Douglas W. Oard College of Library supported in part by DARPA contract N6600197C8540 #12;2 Part I. Introduction Specific evaluation criteria for resource selection and for gap analysis to focus additional search for specific resources that could

  20. Periodic Accretion Instabilities in the Protostar L1634 IRS 7

    E-Print Network [OSTI]

    Hodapp, Klaus W

    2015-01-01

    The small molecular cloud Lynds 1634 contains at least three outflow sources. We found one of these, IRS 7, to be variable with a period of 37.14 +/- 0.04 days and an amplitude of approximately 2 mag in the Ks band. The light curve consists of a quiescent phase with little or no variation, and a rapid outburst phase. During the outburst phase, the rapid brightness variation generates light echoes that propagate into the surrounding molecular cloud, allowing a measurement of the distance to IRS 7 of 404 pc +/- 35 pc. We observed only a marginally significant change in the H - K color during the outburst phase. The K-band spectrum of IRS 7 shows CO bandhead emission but its equivalent width does not change significantly with the phase of the light curve. The H_2 1-0 S(1) line emission does not follow the variability of the continuum flux. We also used the imaging data for a proper motion study of the outflows originating from the IRS 7 and the FIR source IRAS 05173-0555, and confirm that these are indeed distin...

  1. Sr2IrO4: Gateway to cuprate superconductivity?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mitchell, J. F.

    2015-06-05

    High temperature superconductivity in cuprates remains a defining challenge in condensed matter physics. Recently, a new set of related compounds based on Ir rather than Cu has been discovered that may be on the verge of superconductivity themselves or be able to shed new light on the underlying interactions responsible for superconductivity in the cuprates.

  2. Testing a model of IR radiative losses Frank Vignola

    E-Print Network [OSTI]

    Oregon, University of

    losses associated with the pyranometers. High quality data from the Solar Radiation Research Laboratory Energy Laboratory (NREL) operates a very high quality solar monitoring station at the Solar Radiation Energy Laboratory ABSTRACT Thermopile pyranometers exhibit IR radiative losses that affect global

  3. Score Region Algebra: Building a Transparent XML-IR Database

    E-Print Network [OSTI]

    Hiemstra, Djoerd

    imple- mented the algebra operators in a prototype system on top of a low-level database kernel algebra framework on top of any low-level physical database engine or existing RDBMS, allowing a more sysScore Region Algebra: Building a Transparent XML-IR Database Vojkan Mihajlovi´c Henk Ernst Blok

  4. Mechanistic aspects of [Rh(nbd)CI][sub 2]initiated oligomerization of new acetylenic monomers

    SciTech Connect (OSTI)

    Densmore, C.G. (Crystal G); Rasmussen, P.G. (Paul G.)

    2004-01-01

    Although a number of papers report the use of rhodium-based initiators, very little has been said about the mechanism of acetylene polymerizations. Kishimoto and coworkers recently proposed an insertion mechanism for the rhodium-initiated polymerization of phenylacetylenes. The initiator consisted of the tetracoordinate rhodium complex, Rh(C{triple_bond}CC{sub 6}H{sub 5})(nbd)(PPh{sub 3}) with 4-(dimethylamino)-pyidine. The product was found to be stereoregular poly(phenylacety1ene) with a cis-transoidal backbone microstructure. Gorman and coworkers found palladium and nickel-based catalysts to be successful in the polymerization of cyanoacetylene. Zhan and Yang addressed the polymerization mechanism of acetylenes using palladium and nickel acetylide catalysts. They propose that the initial activation step, and also the rate-determining step, involve coordination of a nickel or palladium acetylide catalyst with an acetylene. Based on NMR and elemental analysis, we propose a more complete mechanistic picture of acetylene polymerizations, especially those with electron-withdrawing substituents.

  5. Ternary Pt/Rh/SnO2 Electrocatalysts for Oxidizing Ethanol to CO2

    SciTech Connect (OSTI)

    Kowal, A.; Li, M; Shao, M; Sasaki, K; Vukmirovic, M; Zhang, J; Marinkovic, N; Liu, P; Frenkel, A; Adzic, R

    2009-01-01

    Ethanol, with its high energy density, likely production from renewable sources and ease of storage and transportation, is almost the ideal combustible for fuel cells wherein its chemical energy can be converted directly into electrical energy. However, commercialization of direct ethanol fuel cells has been impeded by ethanol's slow, inefficient oxidation even at the best electrocatalysts1, 2. We synthesized a ternary PtRhSnO2/C electrocatalyst by depositing platinum and rhodium atoms on carbon-supported tin dioxide nanoparticles that is capable of oxidizing ethanol with high efficiency and holds great promise for resolving the impediments to developing practical direct ethanol fuel cells. This electrocatalyst effectively splits the C-C bond in ethanol at room temperature in acid solutions, facilitating its oxidation at low potentials to CO2, which has not been achieved with existing catalysts. Our experiments and density functional theory calculations indicate that the electrocatalyst's activity is due to the specific property of each of its constituents, induced by their interactions. These findings help explain the high activity of Pt-Ru for methanol oxidation and the lack of it for ethanol oxidation, and point to the way to accomplishing the C-C bond splitting in other catalytic processes.

  6. Ternary Pt/Rh/SnO2 Electrocatalysts for Oxidizing Ethanol to CO2

    SciTech Connect (OSTI)

    Adzic, R.R.; Kowal, A.; Li, M.; Shao, M.; Sasaki, K.; Vukmirovic, M.B.; Zhang, J.; Marinkovic, N.S. Liu, P.; Frenkel, A.I.

    2009-04-01

    Ethanol, with its high energy density, likely production from renewable sources and ease of storage and transportation, is almost the ideal combustible for fuel cells wherein its chemical energy can be converted directly into electrical energy. However, commercialization of direct ethanol fuel cells has been impeded by ethanol's slow, inefficient oxidation even at the best electrocatalysts. We synthesized a ternary PtRhSnO{sub 2}/C electrocatalyst by depositing platinum and rhodium atoms on carbon-supported tin dioxide nanoparticles that is capable of oxidizing ethanol with high efficiency and holds great promise for resolving the impediments to developing practical direct ethanol fuel cells. This electrocatalyst effectively splits the C-C bond in ethanol at room temperature in acid solutions, facilitating its oxidation at low potentials to CO{sub 2}, which has not been achieved with existing catalysts. Our experiments and density functional theory calculations indicate that the electrocatalyst's activity is due to the specific property of each of its constituents, induced by their interactions. These findings help explain the high activity of Pt-Ru for methanol oxidation and the lack of it for ethanol oxidation, and point to the way to accomplishing the C-C bond splitting in other catalytic processes.

  7. Asymmetric “melting” and “freezing” kinetics of the magnetostructural phase transition in B2-ordered FeRh epilayers

    SciTech Connect (OSTI)

    Vries, M. A. de; Loving, M.; Lewis, L. H.; McLaren, M.; Brydson, R. M. D.; Liu, X.; Langridge, S.; Marrows, C. H.

    2014-06-09

    Synchrotron X-ray diffraction was used to study the phase transformation processes during the magnetostructural transition in a B2-ordered FeRh (001)-oriented epilayer grown on MgO by sputtering. Out-of-plane lattice constant measurements within the hysteretic regime of the transition reveal a microstructure consistent with the coexistence of lattice-expanded and contracted phases in spatially distinct regions. It was found that the phase separation is more pronounced during cooling than heating. Furthermore, whilst lattice-expanded domains that span the height of the film can be undercooled by several kelvins, there is no equivalent superheating. This asymmetry between the cooling and heating processes in FeRh is consistent with the difference in the kinetics of generic freezing and melting transitions.

  8. Magnetism and superconductivity in U?PtxRh(1–x)C?

    SciTech Connect (OSTI)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-01

    We report the phase diagram of the doping series U?PtxRh(1–x)C?, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Néel temperature of U?Rh?C? of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. In addition, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ? 0.9, with Tc increasing with increasing x. The reduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.

  9. Synthesis and crystal structure of two new cerium rhodium oxides: Ce{sub 2/3-x}Rh{sup 3+}{sub 2}O{sub 4} (x{approx}0.12) with Ce mixed valency and Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5}

    SciTech Connect (OSTI)

    Mizoguchi, Hiroshi; Zakharov, L.N.; Bhuvanesh, N.S.P.; Sleight, A.W.; Subramanian, M.A.

    2011-06-15

    The new compounds Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) and CeRh{sub 2}O{sub 5} have been prepared. Their structures were determined from single crystal X-ray diffraction data. Electrical and magnetic properties were also evaluated. Based on the structural analysis and physical properties, oxidation states for CeRh{sub 2}O{sub 5} can be assigned as Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5}. A small variation in x was detected for Ce{sub 2/3-x}Rh{sub 2}O{sub 4} indicating a formula ranging from Ce{sup 3.64+}{sub 0.55}Rh{sup 3+}{sub 2}O{sub 4} to Ce{sup 3.81+}{sub 0.525}Rh{sup 3+}{sub 2}O{sub 4}. - Graphical abstract: The new compounds Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) and CeRh{sub 2}O{sub 5} have been prepared and their structures were determined from single crystal X-ray diffraction data. Electrical and magnetic properties were also evaluated. Highlights: > The new compounds CeRh{sub 2}O{sub 5} and Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) have been prepared. > Their structures were determined from single crystal X-ray diffraction data. > Valence picture is Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5} and Ce{sup 3.64+}{sub 0.55}Rh{sup 3+}{sub 2}O{sub 4} to Ce{sup 3.81+}{sub 0.525}Rh{sup 3+}{sub 2}O{sub 4}.

  10. Excited states in {sup 115}Pd populated in the {beta}{sup -} decay of {sup 115}Rh

    SciTech Connect (OSTI)

    Kurpeta, J.; Plochocki, A. [Faculty of Physics, University of Warsaw, ul. Hoza 69, PL-00-681 Warsaw (Poland); Urban, W. [Faculty of Physics, University of Warsaw, ul. Hoza 69, PL-00-681 Warsaw (Poland); Institut Laue-Langevin, 6 rue J. Horowitz, F-38042 Grenoble (France); Rissanen, J.; Eronen, T.; Hakala, J.; Jokinen, A.; Kankainen, A.; Karvonen, P.; Moore, I. D.; Penttilae, H.; Saastamoinen, A.; Weber, C.; Aeystoe, J. [Department of Physics, University of Jyvaeskylae, P.O. Box 35, FIN-40351, Jyvaeskylae (Finland); Elomaa, V.-V. [Turku PET Centre, Accelerator Laboratory, Abo Akademi University, FIN-20500 Turku (Finland); Rahaman, S. [Physics Division, P-23, Mail Stop H803, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Sonoda, T. [Nishina Center for Accelerator Based Science, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Szerypo, J. [Fakultaet fuer Physik, Ludwig-Maximilians-Universitaet Muenchen, Am Coulombwall 1, D-85748 Garching (Germany)

    2010-08-15

    Excited states in {sup 115}Pd, populated following the {beta}{sup -} decay of {sup 115}Rh have been studied by means of {gamma} spectroscopy after the Penning-trap station at the IGISOL facility, University of Jyvaeskylae. The 1/2{sup +} spin and parity assignment of the ground state of {sup 115}Pd, confirmed in this work, may indicate a transition to an oblate shape in Pd isotopes at high neutron number.

  11. Safety evaluation for packaging (onsite) for the concrete-shielded RH TRU drum for the 327 Postirradiation Testing Laboratory

    SciTech Connect (OSTI)

    Smith, R.J.

    1998-03-31

    This safety evaluation for packaging authorizes onsite transport of Type B quantities of radioactive material in the Concrete Shielded Remote-Handled Transuranic Waste (RH TRU) Drum per HNF-PRO-154, Responsibilities and Procedures for all Hazardous Material Shipments. The drum will be used for transport of 327 Building legacy waste from the 300 Area to a solid waste storage facility on the Hanford Site.

  12. Features of conduction mechanisms in n-HfNiSn semiconductor heavily doped with a Rh acceptor impurity

    SciTech Connect (OSTI)

    Romaka, V. A.; Rogl, P.; Stadnyk, Yu. V.; Romaka, V. V.; Hlil, E. K.; Krajovskii, V. Ya.; Horyn, A. M.

    2013-09-15

    The crystal structure and electron-density distribution, as well as the energy, kinetic, and magnetic characteristics of n-HfNiSn intermetallic semiconductor heavily doped with a Rh acceptor impurity in the temperature range T = 80-400 K, in the acceptor-concentration range N{sub A}{sup Rh} Almost-Equal-To 9.5 Multiplication-Sign 10{sup 19}-1.9 Multiplication-Sign 10{sup 21} cm{sup -3} (x = 0.005-0.10), and in magnetic fields H {<=} 10 kG are investigated. It is established that doping is accompanied by a simultaneous decrease in concentration, the elimination of donor-type structural defects (to x Almost-Equal-To 0.02), and an increase in the concentration of acceptor-type structural defects (0 < x {<=} 0.10). The dependence of the degree of semiconductor compensation on temperature is revealed. A model of the spatial arrangement of atoms in HfNi{sub 1-x}Rh{sub x}Sn is proposed, and the results of calculating the electron structure based on this model agree with the results of investigations of the kinetic and magnetic characteristics of the semiconductor. The results are discussed within the context of the Shklovskii-Efros model for a heavily doped and compensated semiconductor.

  13. Havre, MT Natural Gas Pipeline Imports From Canada (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969CentralWellsMillion Cubic Feet) Havre, MT Natural Gas Pipeline

  14. The IR-resummed Effective Field Theory of Large Scale Structures...

    Office of Scientific and Technical Information (OSTI)

    The IR-resummed Effective Field Theory of Large Scale Structures Citation Details In-Document Search Title: The IR-resummed Effective Field Theory of Large Scale Structures We...

  15. 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles: Comparison to Reference Methods 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles:...

  16. SESAM FT-IR: A Comparison of the R&D Workhorse to Standard Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SESAM FT-IR: A Comparison of the R&D Workhorse to Standard Emission Benches SESAM FT-IR: A Comparison of the R&D Workhorse to Standard Emission Benches Data for a number of...

  17. Novel Techniques for Single-Pulse Spectrum and Pulsewidth Measurements for an IR-FEL

    E-Print Network [OSTI]

    Leemans, W.P.

    2011-01-01

    ofthe LBL/Stanford diagnostics. FEL Thespectral andtemporalMeasurements for an IR-FEL W.P. Leemans, J.A. Edighoffer, K-Measurements for an IR-FEL* W. P. Leemans, J. A. Edighoffer,

  18. Relative Infrared (IR) and Terahertz (THz) Signatures of Common Explosives

    SciTech Connect (OSTI)

    Sharpe, Steven W.; Johnson, Timothy J.; Sheen, David M.; Atkinson, David A.

    2006-11-13

    Pacific Northwest National Laboratory (PNNL) has recently recorded the infrared (IR) and far-infrared (sometimes called the terahertz, THz) spectral signatures of four common explosives, in the condensed phase. The signatures of RDX, PETN, TNT and Tetryl were recorded both in the infrared and the THz domains, using Fourier transform infrared (FTIR) spectroscopy. Samples consisted of thin films and were made by depositing and subsequent evaporation of an acetone-explosive mixture. The complete spectrum spanned the range from 4,000 to 8 cm-1 at 2.0 cm-1 spectral resolution. Preliminary results in the infrared agree with those of previous workers, while the THz signatures are one order of magnitude weaker than the strongest IR bands.

  19. Carbon-Supported IrNi Core-Shell Nanoparticles: Synthesis Characterization and Catalytic Activity

    SciTech Connect (OSTI)

    K Sasaki; K Kuttiyiel; L Barrio; D Su; A Frenkel; N Marinkovic; D Mahajan; R Adzic

    2011-12-31

    We synthesized carbon-supported IrNi core-shell nanoparticles by chemical reduction and subsequent thermal annealing in H{sub 2}, and verified the formation of Ir shells on IrNi solid solution alloy cores by various experimental methods. The EXAFS analysis is consistent with the model wherein the IrNi nanoparticles are composed of two-layer Ir shells and IrNi alloy cores. In situ XAS revealed that the Ir shells completely protect Ni atoms in the cores from oxidation or dissolution in an acid electrolyte under elevated potentials. The formation of Ir shell during annealing due to thermal segregation is monitored by time-resolved synchrotron XRD measurements, coupled with Rietveld refinement analyses. The H{sub 2} oxidation activity of the IrNi nanoparticles was found to be higher than that of a commercial Pt/C catalyst. This is predominantly due to Ni-core-induced Ir shell contraction that makes the surface less reactive for IrOH formation, and the resulting more metallic Ir surface becomes more active for H{sub 2} oxidation. This new class of core-shell nanoparticles appears promising for application as hydrogen anode fuel cell electrocatalysts.

  20. Spatially Resolved Observations of the Galactic Center Source, IRS 21

    E-Print Network [OSTI]

    Tanner, A; Morris, M; Becklin, E E; Cotera, A S; Ressler, M E; Werner, M; Wizinowich, P

    2002-01-01

    We present diffraction-limited 2-25 micron images obtained with the W. M. Keck 10-m telescopes that spatially resolve the cool source, IRS 21, one of a small group of enigmatic objects in the central parsec of our Galaxy that have eluded classification. Modeled as a Gaussian, the azimuthally-averaged intensity profile of IRS 21 has a half-width half-maximum (HWHM) size of 650+/-80 AU at 2.2 microns and an average HWHM size of 1600+/-200 AU at mid-infrared wavelengths. These large apparent sizes imply an extended distribution of dust. The mid-infrared color map indicates that IRS 21 is a self-luminous source rather than an externally heated dust clump as originally suggested. The spectral energy distribution has distinct near- and mid-infrared components. A simple radiative transfer code, which simultaneously fits the near- and mid- infrared photometry and intensity profiles, supports a model in which the near-infrared radiation is scattered and extincted light from an embedded central source, while the mid-in...

  1. An IR study of pure and ion irradiated frozen formamide

    E-Print Network [OSTI]

    John R. Brucato; Giuseppa A. Baratta; Giovanni Strazzulla

    2006-04-28

    Context. The chemical evolution of formamide (HCONH2), a molecule of astrobiological interest that has been tentatively identified in interstellar ices and in cometary coma, has been studied in laboratory under simulated astrophysical conditions such as ion irradiation at low temperature. Aims. To evaluate the abundances of formamide observed in space or in laboratory, the integrated absorbances for all the principal IR features of frozen amorphous pure formamide deposited at 20 K were measured. Further evidence that energetic processing of ices occurring in space is extremely relevant both to astrochemistry and to astrobiology has been found, showing that new molecular species are synthesized by ion irradiation at a low temperature. Methods. Pure formamide were deposited at 20 K and IR transmission spectra measured for different ice thicknesses. The ice thickness was derived by looking at the interference pattern (intensity versus time) of a He-Ne laser beam reflected at an angle of 45 deg by the vacuum-film and film-substrate interfaces. Samples of formamide ice were irradiated with 200 keV H+ ions and IR spectra recorded at different ion fluences. Results. New molecules were synthesized among which are CO, CO2, N2O, isocyanic acid (HNCO), and ammonium cyanate (NH4+OCN-). Some of these species remain stable after warming up to room temperature.

  2. Uncooled thin film pyroelectric IR detector with aerogel thermal isolation

    SciTech Connect (OSTI)

    Ruffner, J.A.; Clem, P.G.; Tuttle, B.A. [and others

    1998-01-01

    Uncooled pyroelectric IR imaging systems, such as night vision goggles, offer important strategic advantages in battlefield scenarios and reconnaissance surveys. Until now, the current technology for fabricating these devices has been limited by low throughput and high cost which ultimately limit the availability of these sensor devices. We have developed and fabricated an alternative design for pyroelectric IR imaging sensors that utilizes a multilayered thin film deposition scheme to create a monolithic thin film imaging element on an active silicon substrate for the first time. This approach combines a thin film pyroelectric imaging element with a thermally insulating SiO{sub 2} aerogel thin film to produce a new type of uncooled IR sensor that offers significantly higher thermal, spatial, and temporal resolutions at a substantially lower cost per unit. This report describes the deposition, characterization and optimization of the aerogel thermal isolation layer and an appropriate pyroelectric imaging element. It also describes the overall integration of these components along with the appropriate planarization, etch stop, adhesion, electrode, and blacking agent thin film layers into a monolithic structure. 19 refs., 8 figs., 6 tabs.

  3. MT1-MMP promotes cell growth and ERK activation through c-Src and paxillin in three-dimensional collagen matrix

    SciTech Connect (OSTI)

    Takino, Takahisa; Tsuge, Hisashi; Ozawa, Terumasa [Department of Molecular Virology and Oncology, Cancer Research Institute, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 (Japan)] [Department of Molecular Virology and Oncology, Cancer Research Institute, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 (Japan); Sato, Hiroshi, E-mail: vhsato@kenroku.kanazawa-u.ac.jp [Department of Molecular Virology and Oncology, Cancer Research Institute, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 (Japan)] [Department of Molecular Virology and Oncology, Cancer Research Institute, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 (Japan)

    2010-06-11

    Membrane-type 1 matrix metalloproteinase (MT1-MMP) is essential for tumor invasion and growth. We show here that MT1-MMP induces extracellular signal-regulated kinase (ERK) activation in cancer cells cultured in collagen gel, which is indispensable for their proliferation. Inhibition of MT1-MMP by MMP inhibitor or small interfering RNA suppressed activation of focal adhesion kinase (FAK) and ERK in MT1-MMP-expressing cancer cells, which resulted in up-regulation of p21{sup WAF1} and suppression of cell growth in collagen gel. Cell proliferation was also abrogated by the inhibitor against ERK pathway without affecting FAK phosphorylation. MT1-MMP and integrin {alpha}{sub v}{beta}{sub 3} were shown to be involved in c-Src activation, which induced FAK and ERK activation in collagen gel. These MT1-MMP-mediated signal transductions were paxillin dependent, as knockdown of paxillin reduced cell growth and ERK activation, and co-expression of MT1-MMP with paxillin induced ERK activation. The results suggest that MT1-MMP contributes to proliferation of cancer cells in the extracellular matrix by activating ERK through c-Src and paxillin.

  4. Uranium hydrogeochemical and stream sediment reconnaissance of the Mt. Hayes NTMS quadrangle, Alaska

    SciTech Connect (OSTI)

    Not Available

    1981-05-01

    Results of a hydrogeochemical and stream sediment reconnaissance of the Mt. Hayes quadrangle, Alaska, are presented. In addition to this abbreviated data release, more complete data are available to the public in machine-readable form. In this data release are location data, field analyses, and Laboratory analyses of several different sample media. For the sake of brevity, many field site observations have not been included in this volume. These data are, however, available on the magnetic tape. Appendices A to D describe the sample media and summarize the analytical results for each medium. The data were subsetted by one of the Los Alamos National Laboratory (LANL) sorting programs into groups of stream sediment, lake sediment, stream water, lake water, and ground water samples. For each group which contains a sufficient number of observations, statistical tables, tables of raw data, and 1:1000000 scale maps of pertinent elements have been included in this report.

  5. Theoretical Investigation of Iridium (II) Sulfides Ir2(?-S)2(PH3)4 AND Ir2(?-S)2(PPh3)4 

    E-Print Network [OSTI]

    Kritikou, Stella

    2014-02-27

    Density functional theory results of the electronic structure of an iridium sulfide, Ir_(2)S_(2)(PPh_(3))_(4) (2), are presented here, along with a discussion of the reaction mechanism of dihydrogen activation on this sulfide. This Ir (II...

  6. EIS-0092: Conversion to Coal, Holyoke Water Power Company, Mt. Tom Generating Station Unit 1 Holyoke, Hampden County, Massachusetts

    Broader source: Energy.gov [DOE]

    The Economic Regulatory Administration prepared this statement to assess the environmental impacts of prohibiting Unit 1 of the Mt. Tom Generation Station Unit 1 from using either natural gas or petroleum products as a primary energy source, which would result in the utility burning low-sulfur coal.

  7. The Mechanism of Inhibition of Antibody-based Inhibitors of Membrane-type Serine Protease 1 (MT-SP1)

    E-Print Network [OSTI]

    Craik, Charles S.

    The Mechanism of Inhibition of Antibody-based Inhibitors of Membrane-type Serine Protease 1 (MT-SP1, 600 16th St. Genentech Hall, San Francisco, CA 94143, USA The mechanisms of inhibition of two novel sc-SP1 at low pH, and is a standard mechanism inhibitor of the protease. The mechanisms of inhibition

  8. IR Spectral Bands and Performance | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View NewGuam:on Openei | Open Energy2010) |OutlookINDEX JumpIR Spectral

  9. Large exchange bias enhancement in (Pt(or Pd)/Co)/IrMn/Co trilayers with ultrathin IrMn thanks to interfacial Cu dusting

    SciTech Connect (OSTI)

    Vinai, G. [SPINTEC, UMR 8191 CEA/CNRS/UJF/Grenoble-INP, CEA/INAC, 17, rue des Martyrs, 38054 Grenoble (France); Crocus Technology, 4 Place Robert Schuman, 38054 Grenoble (France); Moritz, J. [Institut Jean Lamour, UMR 7198 CNRS - Université de Lorraine, Bd des Aiguillettes, BP 70239, F-54506 Vandoeuvre-les-Nancy Cedex (France); Bandiera, S. [Crocus Technology, 4 Place Robert Schuman, 38054 Grenoble (France); Prejbeanu, I. L.; Dieny, B. [SPINTEC, UMR 8191 CEA/CNRS/UJF/Grenoble-INP, CEA/INAC, 17, rue des Martyrs, 38054 Grenoble (France)

    2014-04-21

    The magnitude of exchange bias (H{sub ex}) at room temperature can be significantly enhanced in IrMn/Co and (Pt(or Pd)/Co)/IrMn/Co structures thanks to the insertion of an ultrathin Cu dusting layer at the IrMn/Co interface. The combination of trilayer structure and interfacial Cu dusting leads to a three-fold increase in H{sub ex} as compared to the conventional IrMn/Co bilayer structure, with an increased blocking temperature (T{sub B}) and a concave curvature of the temperature dependence H{sub ex}(T), ideal for improved Thermally Assisted-Magnetic Random Access Memory storage layer. This exchange bias enhancement is ascribed to a reduction of the spin frustration at the IrMn/Co interface thanks to interfacial Cu addition.

  10. Time dynamics of photothermal vs optoacoustic response in mid IR nanoscale biospectroscopy

    E-Print Network [OSTI]

    Tovee, Peter D; Kjoller, Kevin; Allsop, David; Weightman, Peter; Surman, Mark; Siggel-King, Michele R F; Wolski, Andy; Kolosov, Oleg V

    2015-01-01

    Infrared (IR) spectroscopy, a well established tool for chemical analysis of diverse materials, has significant potential in biomedical applications. While the spatial resolution of traditional IR spectroscopy is limited by the wavelength of the IR light to the few micrometres, it has been shown that nanoscale chemical analysis can be obtained by detecting IR induced local heating photothermal response via Scanning Thermal Microscopy (SThM) or local thermomechanical expansion using Atomic Force Microscopy (AFM). This paper explores the potential of a pulsed ps pulse duration high power free electron laser (FEL) light source for AFM-IR and SThM-IR spectroscopy employing standard AFM and SThM probes. The SThM-IR response was found to have a detrimental strong background signal due to the direct heating of the probe, whereas the AFM IR thermomechanical response allowed to eliminate such a problem for both top down and bottom up illuminations with the FEL IR source. The SThM IR characteristic response time was ap...

  11. The Chandra COSMOS Legacy survey: optical/IR identifications

    E-Print Network [OSTI]

    Marchesi, S; Elvis, M; Salvato, M; Brusa, M; Comastri, A; Gilli, R; Hasinger, G; Lanzuisi, G; Miyaji, T; Treister, E; Urry, C M; Vignali, C; Zamorani, G; Allevato, V; Cappelluti, N; Cardamone, C; Finoguenov, A; Griffiths, R E; Karim, A; Laigle, C; LaMassa, S M; Jahnke, K; Ranalli, P; Schawinski, K; Schinnerer, E; Silverman, J D; Smolcic, V; Suh, H; Trakhtenbrot, B

    2015-01-01

    We present the catalog of optical and infrared counterparts of the Chandra COSMOS-Legacy Survey, a 4.6 Ms Chandra program on the 2.2 square degrees of the COSMOS field, combination of 56 new overlapping observations obtained in Cycle 14 with the previous C-COSMOS survey. In this Paper we report the i, K, and 3.6 micron identifications of the 2273 X-ray point sources detected in the new Cycle 14 observations. We use the likelihood ratio technique to derive the association of optical/infrared (IR) counterparts for 97% of the X-ray sources. We also update the information for the 1743 sources detected in C-COSMOS, using new K and 3.6 micron information not available when the C-COSMOS analysis was performed. The final catalog contains 4016 X-ray sources, 97% of which have an optical/IR counterpart and a photometric redshift, while 54% of the sources have a spectroscopic redshift. The full catalog, including spectroscopic and photometric redshifts and optical and X-ray properties described here in detail, is availa...

  12. Qualification tests for {sup 192}Ir sealed sources

    SciTech Connect (OSTI)

    Iancso, Georgeta Iliescu, Elena Iancu, Rodica

    2013-12-16

    This paper describes the results of qualification tests for {sup 192}Ir sealed sources, available in Testing and Nuclear Expertise Laboratory of National Institute for Physics and Nuclear Engineering 'Horia Hulubei' (I.F.I.N.-HH), Romania. These sources had to be produced in I.F.I.N.-HH and were tested in order to obtain the authorization from The National Commission for Nuclear Activities Control (CNCAN). The sources are used for gammagraphy procedures or in gammadefectoscopy equipments. Tests, measurement methods and equipments used, comply with CNCAN, AIEA and International Quality Standards and regulations. The qualification tests are: 1. Radiological tests and measurements: dose equivalent rate at 1 m; tightness; dose equivalent rate at the surface of the transport and storage container; external unfixed contamination of the container surface. 2. Mechanical and climatic tests: thermal shock; external pressure; mechanic shock; vibrations; boring; thermal conditions for storage and transportation. Passing all tests, it was obtained the Radiological Security Authorization for producing the {sup 192}Ir sealed sources. Now IFIN-HH can meet many demands for this sealed sources, as the only manufacturer in Romania.

  13. A RhxSy/C Catalyst for the Hydrogen Oxidation and Hydrogen Evolution Reactions in HBr

    SciTech Connect (OSTI)

    Masud, Jahangir; Nguyena, Trung V.; Singh, Nirala; McFarland, Eric; Ikenberry, Myles; Hohn, Keith; Pan, Chun-Jern; Hwang, Bing-Joe

    2015-01-01

    Rhodium sulfide (Rh2S3) on carbon support was synthesized by refluxing rhodium chloride with ammonium thiosulfate. Thermal treatment of Rh2S3 at high temperatures (600°C to 850°C) in presence of argon resulted in the transformation of Rh2S3 into Rh3S4, Rh17S15 and Rh which were characterized by TGA/DTA, XRD, EDX, and deconvolved XPS analyses. The catalyst particle size distribution ranged from 3 to 12 nm. Cyclic voltammetry and rotating disk electrode measurements were used to evaluate the catalytic activity for hydrogen oxidation and evolution reactions in H2SO4 and HBr solutions. The thermally treated catalysts show high activity for the hydrogen reactions. The exchange current densities (io) of the synthesized RhxSy catalysts in H2-saturated 1M H2SO4 and 1M HBr for HER and HOR were 0.9 mA/cm2 to 1.0 mA/cm2 and 0.8 to 0.9 mA/cm2, respectively. The lower io values obtained in 1M HBr solution compared to in H2SO4 might be due to the adsorption of Br- on the active surface. Stable electrochemical active surface area (ECSA) of RhxSy catalyst was obtained for CV scan limits between 0 V and 0.65 V vs. RHE. Scans with upper voltage limit beyond 0.65 V led to decreased and unreproducible ECSA measurements.

  14. Asymptotic freedom and IR freezing in QCD: the role of gluon paramagnetism

    E-Print Network [OSTI]

    Yu. A. Simonov

    2010-11-24

    Paramagnetism of gluons is shown to play the basic role in establishing main properties of QCD: IR freezing and asymptotic freedom (AF). Starting with Polyakov background field approach the first terms of background perturbation theory are calculated and shown to ensure not only the classical result of AF but also IR freezing. For the latter only the confining property of the background is needed, and the effective mass entering the IR freezing logarithms is calculated in good agreement with phenomenology and lattice data.

  15. IR ranking proposal and new beam parameter sets for the LHC upgrade the view of HHH

    E-Print Network [OSTI]

    Scandale, Walter

    2007-01-01

    We propose a ranking for the interaction-region (IR) optics based on the presentations and results from the first two days of the LUMI’06 workshop.

  16. Platinum Monolayer on IrFe Core–Shell Nanoparticle Electrocatalysts for the Oxygen Reduction Reaction

    SciTech Connect (OSTI)

    Sasaki K.; Kuttiyiel, K.A.; Su, D.; Adzic, R.R.

    2012-04-19

    We synthesized high activity and stability platinum monolayer on IrFe core-shell nanoparticle electrocatalysts. Carbon-supported IrFe core-shell nanoparticles were synthesized by chemical reduction and subsequent thermal annealing. The formation of Ir shells on IrFe solid-solution alloy cores has been verified by scanning transmission electron microscopy coupled with energy-loss spectroscopy (EELS) and in situ X-ray absorption spectroscopy. The Pt monolayers were deposited on IrFe core-shell nanoparticles by galvanic replacement of underpotentially deposited Cu adatoms on the Ir shell surfaces. The specific and Pt mass activities for the ORR on the Pt monolayer on IrFe core-shell nanoparticle electrocatalyst are 0.46 mA/cm{sup 2} and 1.1 A/mg{sub Pt}, which are much higher than those on a commercial Pt/C electrocatalyst. High durability of Pt{sub ML}/IrFe/C has also been demonstrated by potential cycling tests. These high activity and durability observed can be ascribed to the structural and electronic interaction between the Pt monolayer and the IrFe core-shell nanoparticles.

  17. Evaluation of PC-ISO for customized, 3D printed, gynecologic 192Ir HDR brachytherapy applicators

    E-Print Network [OSTI]

    2015-01-01

    equiva- lent to water within the energy range of interest,properties to water at 192 Ir energies to be compatible with

  18. Figure S1.Technical diagram of the 1-by-3 tandem differential mobility analyzer (cf. schematic diagram shown in Figure 1). Relative humidity sensors are located at positions RH,

    E-Print Network [OSTI]

    valve used for on-off flow control; MFC, mass flow controller; T, temperature sensor; CA, filtered Diffusion Dryer Pinch Valve Pressure Regulator 3 3 3 Aerosol Out Humidity Conditioner Flow Sheath air out=48% RH0=43% Mobility diameter (nm) Particleconcentration(#cm-3bin-1) Entering DMAmono with RH0 Passing

  19. Applications of stable isotopes in hydrological studies of Mt. Apo geothermal field, Philippines

    SciTech Connect (OSTI)

    Salonga, N.D.; Aragon, G.M.; Nogara, J.B.; Sambrano, B.G.

    1996-12-31

    The local precipitation in Mt. Apo is depleted of heavy isotopes owing to high elevation and landward location of the field. Rainwaters infiltrate the shallow grounds, circulate in short distances with almost no interaction with the host bed rocks, and effuse in the surface as cold springs. Lakes and rivers are affected by surface evaporation while the acid SO{sub 4} springs are affected by both evaporation and steam-heating. Only the neutral-pH Cl springs have the signature of the deep thermal fluids. The parent fluids of the deep thermal brine contain Cl of 4,800 to 5,000 mg/kg, {delta}{sup 18}O of -4.62 to -4.13 {per_thousand} and {delta}{sup 2}H of -60.0 to -57.8 {per_thousand}. Inside the Sandawa Collapse, boiling of the parent fluids resulted in a two-phase reservoir with lighter isotope contents. The thermal fluids laterally flow towards the west where they are affected by cooling and mixing of cold waters. Deep water recharge has {delta}{sup 18}O of -10.00 {per_thousand} and {delta}{sup 2}H = -61.20 {per_thousand} which come from the upper slopes of Sandawa Collapse (1580-1700 mASL).

  20. Four-year prospective study of the respiratory effects of volcanic ash from Mt. St. Helens

    SciTech Connect (OSTI)

    Buist, A.S.; Vollmer, W.M.; Johnson, L.R.; Bernstein, R.S.; McCamant, L.E.

    1986-04-01

    This report describes the 4-yr follow-up of 712 loggers exposed over an extended period to varying levels of fresh volcanic ash from the 1980 eruptions of Mt. St. Helens. Concerns related to the irritant effect the ash might have on the airways and also to its fibrogenic potential if exposures were intense and continued over many years. Our subjects were divided into 3 groups: high, low, and no exposure. Baseline testing was begun in June 1980, 1 month after the major eruption, and follow-up testing continued on an annual basis through 1984; 88% of the loggers have been tested at least 3 times. Analysis of lung function data showed that a significant, exposure-related decline in FEV1 occurred during the first year after the eruption. The decline was short-lived, however, and by 1984 the differences between exposure groups were no longer significant. Self-reported symptoms of cough, phlegm, and wheeze showed a similar pattern. No ash-related changes were seen in chest roentgenograms taken in 1980 and in 1984. Our findings are consistent with the hypothesis that the inhaled ash caused mucus hypersecretion and/or airway inflammation that reversed when the exposure levels decreased. The ash levels to which the loggers were exposed were low compared with permissible occupational levels for nuisance dusts, but generally higher than the total suspended particulate levels permissible in ambient air.

  1. CO2 flood tests on whole core samples of the Mt. Simon sandstone, Illinois Basin

    SciTech Connect (OSTI)

    O'Connor, William K.; Rush, Gilbert E.

    2005-09-01

    Geological sequestration of CO2, whether by enhanced oil recovery (EOR), coal-bed methane (CBM) recovery, or saline aquifer injection is a promising near-term sequestration methodology. While tremendous experience exists for EOR, and CBM recovery has been demonstrated in existing fields, saline aquifer injection studies have only recently been initiated. Studies evaluating the availability of saline aquifers suitable for CO2 injection show great potential, however, the long-term fate of the CO2 injected into these ancient aqueous systems is still uncertain. For the subject study, a series of laboratory-scale CO2 flood tests were conducted on whole core samples of the Mt. Simon sandstone from the Illinois Basin. By conducting these tests on whole core samples rather than crushed core, an evaluation of the impact of the CO2 flood on the rock mechanics properties as well as the geochemistry of the core and brine solution has been possible. This empirical data could provide a valuable resource for the validation of reservoir models under development for these engineered CO2 systems.

  2. The effect of GnRH on induction of follicular development and ovulation in anovulatory and ovulatory mares 

    E-Print Network [OSTI]

    Hennington, Debra Louise

    1981-01-01

    pad faq qua!eabeunooua pue aI!oi 'aouaLged unuse gfasEw u! anaL Iaq aw bufqew pue neM aqq. aw 5u!Moqs uo3. noE queqg 'yanqui og 'F, Cfeufg puff . paydwaqge aneq y ge!fg ffe u! qua!eabeunooua pue quoddns 'aoueueaquog ufaqg uog uopbufuuaW I Cassnff... treatment and 70% of the time during GnRH treatment. Control anovulatory mares exhibited estrous behavior 17'K and 15% of the time during the two 25 U1 Q +J Ql Q CL C) c o ) O fO O O Cl col (LUj/6") SN3BOJS3908d 26 courses of sham...

  3. Effects of gonadotropin-releasing hormone (GnRH) on main olfactory input to the medial amygdala in male hamsters. Blake, CB, Meredith, M. Florida State University,

    E-Print Network [OSTI]

    Meredith, Michael

    Effects of gonadotropin-releasing hormone (GnRH) on main olfactory input to the medial amygdala mating behavior is dependent on chemosensory input from the main olfactory and vomeronasal systems, whose. In sexually-naïve males, vomeronasal organ removal (VNX), but not main olfactory lesion, impairs mating

  4. Systematics of the temperature-dependent interplane resistivity in Ba(Fe1-xMx)?As? (M=Co, Rh, Ni, and Pd)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tanatar, M. A.; Ni, N.; Thaler, A.; Bud’ko, S. L.; Canfield, P. C.; Prozorov, R.

    2011-07-27

    Temperature-dependent interplane resistivity ?c(T) was measured systematically as a function of transition-metal substitution in the iron-arsenide superconductors Ba(Fe1-xMx)?As?, M=Ni, Pd, Rh. The data are compared with the behavior found in Ba(Fe1-xCox)?As?, revealing resistive signatures of pseudogap. In all compounds we find resistivity crossover at a characteristic pseudogap temperature T* from nonmetallic to metallic temperature dependence on cooling. Suppression of T* proceeds very similarly in cases of Ni and Pd doping and much faster than in similar cases of Co and Rh doping. In cases of Co and Rh doping an additional minimum in the temperature-dependent ?c emerges for high dopings,more »when superconductivity is completely suppressed. These features are consistent with the existence of a charge gap covering part of the Fermi surface. The part of the Fermi surface affected by this gap is notably larger for Ni- and Pd-doped compositions than in Co- and Rh-doped compounds.« less

  5. DNA Cleavage by Photogenerated Rh2(O2CCH3)4(H2O)2 Patty K.-L. Fu, Patricia M. Bradley, and Claudia Turro*

    E-Print Network [OSTI]

    Turro, Claudia

    the subject of intense investigation since, upon light activation, they can act as reporters of DNA structure and coordination of the dirhodium core to single-stranded oligonucleotides has been observed, the mode of binding-methylpyridinium tetrafluoroborate (py+),17 results in the formation of the one-electron-oxidized complex, Rh2(O2

  6. Oxidation of H on Rh(111): H2O product velocity and angular distributions K. D. Gibson, J. I. Colonell, and S. J. Sibener

    E-Print Network [OSTI]

    Sibener, Steven

    Oxidation of H on Rh(111): H2O product velocity and angular distributions K. D. Gibson, J. I measured the angular dependence of the energy and intensity of the product H2O at Ts 650 K. The velocity distributed. © 1995 American Institute of Physics. INTRODUCTION The angular and velocity distributions

  7. Tuning the Curie temperature of L1{sub 0} ordered FePt thin films through site-specific substitution of Rh

    SciTech Connect (OSTI)

    Xu, Dongbin; Sun, Cheng-Jun E-mail: msecgm@nus.edu.sg; Heald, Steve M.; Chen, Jing-Sheng; Chow, Gan Moog E-mail: msecgm@nus.edu.sg; Zhou, Tie-Jun; Bergman, Anders; Sanyal, Biplab

    2014-10-14

    In structurally ordered magnetic thin films, the Curie temperature (T{sub C}) of ferromagnetic films depends on the exchange integral of the short range ordered neighboring atoms. The exchange integral may be adjusted by controlling the elemental substitutional concentration at the lattice site of interest. We show how to control the T{sub C} in high anisotropy L1{sub 0} Fe{sub 50}Pt{sub 50} magnetic thin films by substituting Rh into the Pt site. Rh substitution in L1{sub 0} FePt modified the local atomic environment and the corresponding electronic properties, while retaining the ordered L1{sub 0} phase. The analysis of extended x-ray Absorption Fine Structure spectra shows that Rh uniformly substitutes for Pt in L1{sub 0} FePt. A model of antiferromagnetic defects caused by controlled Rh substitution of the Pt site, reducing the T{sub C,} is proposed to interpret this phenomenon and its validity is further examined by ab initio density functional calculations.

  8. Assignment 4 BS4a Actuarial Science Oxford MT 2011 IX A.4 Inflation, taxation and project appraisal

    E-Print Network [OSTI]

    Winkel, Matthias

    Assignment 4 ­ BS4a Actuarial Science ­ Oxford MT 2011 IX A.4 Inflation, taxation and project are indexed by reference to the value of a retail price index with a time lag of 8 months. The retail price index value in September 1996 was Q(-8/12) = 200 and in March 1997 was Q(-2/12) = 206. The issue price

  9. Mechanism of Homogeneous Ir(III) Catalyzed Regioselective Arylation of Olefins

    E-Print Network [OSTI]

    Goddard III, William A.

    . On the basis of this mechanism, we suggest new catalysts expected to have improved activity. Initiation by reduction. Recently, Matsumoto2-4 and Periana5 reported the synthesis of a novel Ir complex, [Ir (turn- over-frequency (TOF) of 10-3 s-1 at 200 °C), but there are also problems with selectivity, cost

  10. Raman and IR spectra of butane: Anharmonic calculations and interpretation of room temperature spectra

    E-Print Network [OSTI]

    Potma, Eric Olaf

    Raman and IR spectra of butane: Anharmonic calculations and interpretation of room temperature-principles anharmonic calculations are carried out for the IR and Raman spectra of the CAH stretch- ing bands in butane.V. All rights reserved. 1. Introduction n-Butane is of great importance in several disciplines

  11. Monitoring Nonadiabatic Dynamics of the RNA Base Uracil by UV Pump-IR Probe Spectroscopy

    E-Print Network [OSTI]

    Mukamel, Shaul

    Monitoring Nonadiabatic Dynamics of the RNA Base Uracil by UV Pump-IR Probe Spectroscopy Benjamin P dynamics simulations of the UV pump-IR probe signal of the pyrimidine nucleobase uracil using a novel or visible pump-probe or photoelectron spectroscopy offer a high sub-100 fs temporal resolution.9

  12. NaIrO{sub 3}-A pentavalent post-perovskite

    SciTech Connect (OSTI)

    Bremholm, M.; Dutton, S.E.; Stephens, P.W.; Cava, R.J.

    2011-03-15

    Sodium iridium (V) oxide, NaIrO{sub 3,} was synthesized by a high pressure solid state method and recovered to ambient conditions. It is found to be isostructural with CaIrO{sub 3}, the much-studied structural analog of the high-pressure post-perovskite phase of MgSiO{sub 3}. Among the oxide post-perovskites, NaIrO{sub 3} is the first example with a pentavalent cation. The structure consists of layers of corner- and edge-sharing IrO{sub 6} octahedra separated by layers of NaO{sub 8} bicapped trigonal prisms. NaIrO{sub 3} shows no magnetic ordering and resistivity measurements show non-metallic behavior. The crystal structure, electrical and magnetic properties are discussed and compared to known post-perovskites and pentavalent perovskite metal oxides. -- Graphical abstract: Sodium iridium(V) oxide, NaIrO{sub 3}, synthesized by a high pressure solid state method and recovered to ambient conditions is found to crystallize as the post-perovskite structure and is the first example of a pentavalent ABO{sub 3} post-perovskite. Research highlights: {yields} NaIrO{sub 3} post-perovskite stabilized by pressure. {yields} First example of a pentavalent oxide post-perovskite. {yields} Non-metallic and non-magnetic behavior of NaIrO{sub 3}.

  13. ORIGINAL PAPER Thermal equation of state of CaIrO3 post-perovskite

    E-Print Network [OSTI]

    Duffy, Thomas S.

    ORIGINAL PAPER Thermal equation of state of CaIrO3 post-perovskite Wei Liu · Matthew L. Whitaker-Verlag 2011 Abstract The pressure­volume­temperature (P­V­T) relation of CaIrO3 post-perovskite (ppv for several oxide post-perovskites can be described approximately by the relationship KT0 = 5406.0/ V

  14. Evaluation of Methods to Correct for IR Loss in Eppley PSP Diffuse Measurements

    E-Print Network [OSTI]

    Oregon, University of

    is proportional to the incident solar radiation. Since both the black and white surfaces radiate approximately the same amount of IR, the measured solar radiation does not significantly suffer from the IR radiation irradiance were uncovered by the Atmospheric Radiation Measurement (ARM) Program during comparisons between

  15. Dark Matter Particle Spectroscopy at the LHC: Generalizing M(T2) to Asymmetric Event Topologies

    SciTech Connect (OSTI)

    Konar, Partha; Kong, Kyoungchul; Matchev, Konstantin T.; Park, Myeonghun; /Florida U.

    2012-04-03

    We consider SUSY-like missing energy events at hadron colliders and critically examine the common assumption that the missing energy is the result of two identical missing particles. In order to experimentally test this hypothesis, we generalize the subsystem M{sub T2} variable to the case of asymmetric event topologies, where the two SUSY decay chains terminate in different 'children' particles. In this more general approach, the endpoint M{sub T2(max)} of the M{sub T2} distribution now gives the mass {tilde M}p({tilde M}{sub c}{sup (a)}, {tilde M}{sub c}{sup (b)}) of the parent particles as a function of two input children masses {tilde M}{sub c}{sup (a)} and {tilde M}{sub c}{sup (b)}. We propose two methods for an independent determination of the individual children masses M{sub c}{sup (a)} and M{sub c}{sup (b)}. First, in the presence of upstream transverse momentum PUTM the corresponding function {tilde M}p({tilde M}{sub c}{sup (a)}, {tilde M}{sub c}{sup (b)}, P{sub UTM}) is independent of P{sub UTM} at precisely the right values of the children masses. Second, the previously discussed MT2 'kink' is now generalized to a 'ridge' on the 2-dimensional surface {tilde M}p({tilde M}{sub c}{sup (a)}, {tilde M}{sub c}{sup (b)}). As we show in several examples, quite often there is a special point along that ridge which marks the true values of the children masses. Our results allow collider experiments to probe a multi-component dark matter sector directly and without any theoretical prejudice.

  16. Uranium hydrogeochemical and stream-sediment reconnaissance of the Mt. Michelson NTMS quadrangle, Alaska

    SciTech Connect (OSTI)

    Zinkl, R.J.; Shettel, D.L. Jr.; Langfeldt, S.L.; Hardy, L.C.; D'Andrea, R.F. Jr.

    1982-04-01

    This report presents results of a Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) of the Mt. Michelson NTMS quadrangle, Alaska. In addition to this abbreviated data release, more complete data are available to the public in machine-readable form. These machine-readable data, as well as quarterly or semiannual program progress reports containing further information on the HSSR program in general, or on the Los Alamos National Laboratory (LANL) portion of the program in particular, are available from DOE's Technical Library at its Grand Junction Area Office. Presented in this data release are location data, field analyses, and laboratory analyses of several different sample media. For the sake of brevity, many field site observations have not been included in this volume; these data are, however, available on the magnetic tape. Appendices A and B describe the sample media and summarize the analytical results for each medium. The data have been subdivided by one of the Los Alamos National Laboratory sorting programs of Zinkl and others (1981a) into groups of stream-sediment and lake-sediment samples. For each group which contains a sufficient number of observations, statistical tables, tables of raw data, and 1:1,000,000 scale maps of pertinent elements have been included in this report. Also included are maps showing results of multivariate statistical analyses. Information on the field and analytical procedures used by the Los Alamos National Laboratory during sample collection and analysis may be found in any HSSR data release prepared by the Laboratory and will not be included in this report.

  17. Warm formaldehyde in the Oph IRS 48 transitional disk

    E-Print Network [OSTI]

    van der Marel, Nienke; Bruderer, Simon; van Kempen, Tim A

    2014-01-01

    Simple molecules like H2CO and CH3OH in protoplanetary disks are the starting point for the production of more complex organic molecules. So far, the observed chemical complexity in disks has been limited due to freeze out of molecules onto grains in the bulk of the cold outer disk. Complex molecules can be studied more directly in transitional disks with large inner holes, as these have a higher potential of detection, through UV heating of the outer disk and the directly exposed midplane at the wall. We use Atacama Large Millimeter/submillimeter Array (ALMA) Band 9 (~680 GHz) line data of the transitional disk Oph IRS 48, previously shown to have a large dust trap, to search for complex molecules in regions where planetesimals are forming. We report the detection of the H2CO 9(1,8)-8(1,7) line at 674 GHz, which is spatially resolved as a semi-ring at ~60 AU radius centered south from the star. The inferred H2CO abundance is ~10^{-8} derived by combining a physical disk model of the source with a non-LTE exc...

  18. US-LARP Progress on LHC IR Upgrades Tanaji Sen, John Johnstone, Nikolai Mokhov, FNAL, Batavia, IL 60510

    E-Print Network [OSTI]

    Sen, Tanaji

    of a long-range interaction on the beams. IR DESIGNS Design and construction of next generation IR magnets in determining these parameters. The required field quality is another key input to the magnet designers. An IR to higher luminosity. In the designs to be presented here, we consider the inner triplet magnets

  19. Synchrotron IR microspectroscopy for protein structure analysis: Potential and questions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Peiqiang

    2006-01-01

    Synchrotron radiation-based Fourier transform infrared microspectroscopy (S-FTIR) has been developed as a rapid, direct, non-destructive, bioanalytical technique. This technique takes advantage of synchrotron light brightness and small effective source size and is capable of exploring the molecular chemical make-up within microstructures of a biological tissue without destruction of inherent structures at ultra-spatial resolutions within cellular dimension. To date there has been very little application of this advanced technique to the study of pure protein inherent structure at a cellular level in biological tissues. In this review, a novel approach was introduced to show the potential of the newly developed, advancedmore »synchrotron-based analytical technology, which can be used to localize relatively “pure“ protein in the plant tissues and relatively reveal protein inherent structure and protein molecular chemical make-up within intact tissue at cellular and subcellular levels. Several complex protein IR spectra data analytical techniques (Gaussian and Lorentzian multi-component peak modeling, univariate and multivariate analysis, principal component analysis (PCA), and hierarchical cluster analysis (CLA) are employed to relatively reveal features of protein inherent structure and distinguish protein inherent structure differences between varieties/species and treatments in plant tissues. By using a multi-peak modeling procedure, RELATIVE estimates (but not EXACT determinations) for protein secondary structure analysis can be made for comparison purpose. The issues of pro- and anti-multi-peaking modeling/fitting procedure for relative estimation of protein structure were discussed. By using the PCA and CLA analyses, the plant molecular structure can be qualitatively separate one group from another, statistically, even though the spectral assignments are not known. The synchrotron-based technology provides a new approach for protein structure research in biological tissues at ultraspatial resolutions.« less

  20. PAH chemistry and IR emission from circumstellar disks

    E-Print Network [OSTI]

    R. Visser; V. C. Geers; C. P. Dullemond; J. -C. Augereau; K. M. Pontoppidan; E. F. van Dishoeck

    2007-01-22

    Aims. The chemistry of, and infrared (IR) emission from, polycyclic aromatic hydrocarbons (PAHs) in disks around Herbig Ae/Be and T Tauri stars are investigated. The equilibrium distribution of the PAHs over all accessible charge/hydrogenation states depends on the size and shape of the PAHs and on the physical properties of the star and surrounding disk. Methods. A chemistry model is created to calculate this equilibrium distribution. Destruction of PAHs by ultraviolet (UV) photons, possibly in multi-photon absorption events, is taken into account. The chemistry model is coupled to a radiative transfer code to provide the physical parameters and to combine the PAH emission with the spectral energy distribution (SED) from the star+disk system. Results. Normally hydrogenated PAHs in Herbig Ae/Be disks account for most of the observed PAH emission, with neutral and positively ionized species contributing in roughly equal amounts. Close to the midplane, the PAHs are more strongly hydrogenated and negatively ionized, but these species do not contribute to the overall emission because of the low UV/optical flux deep inside the disk. PAHs of 50 carbon atoms are destroyed out to 100 AU in the disk's surface layer, and the resulting spatial extent of the emission does not agree well with observations. Rather, PAHs of about 100 carbon atoms or more are predicted to cause most of the observed emission. The emission is extended on a scale similar to that of the size of the disk. Furthermore, the emission from T Tauri disks is much weaker and concentrated more towards the central star than that from Herbig Ae/Be disks. Positively ionized PAHs are predicted to be largely absent in T Tauri disks because of the weaker radiation field.

  1. Kinetic and Performance Studies of the Regeneration Phase of Model Pt/Ba/Rh NOx Traps for Design and Optimization

    SciTech Connect (OSTI)

    Michael Harold; Vemuri Balakotaiah

    2010-05-31

    In this project a combined experimental and theoretical approach was taken to advance our understanding of lean NOx trap (LNT) technology. Fundamental kinetics studies were carried out of model LNT catalysts containing variable loadings of precious metals (Pt, Rh), and storage components (BaO, CeO{sub 2}). The Temporal Analysis of Products (TAP) reactor provided transient data under well-characterized conditions for both powder and monolith catalysts, enabling the identification of key reaction pathways and estimation of the corresponding kinetic parameters. The performance of model NOx storage and reduction (NSR) monolith catalysts were evaluated in a bench scale NOx trap using synthetic exhaust, with attention placed on the effect of the pulse timing and composition on the instantaneous and cycle-averaged product distributions. From these experiments we formulated a global model that predicts the main spatio-temporal features of the LNT and a mechanistic-based microkinetic models that incorporates a detailed understanding of the chemistry and predicts more detailed selectivity features of the LNT. The NOx trap models were used to determine its ability to simulate bench-scale data and ultimately to evaluate alternative LNT designs and operating strategies. The four-year project led to the training of several doctoral students and the dissemination of the findings as 47 presentations in conferences, catalysis societies, and academic departments as well 23 manuscripts in peer-reviewed journals. A condensed review of NOx storage and reduction was published in an encyclopedia of technology.

  2. MRI of the lung using hyperpolarized He-3 at very low magnetic field (3 mT)

    E-Print Network [OSTI]

    Bidinosti, C P; Tastevin, G; Vignaud, A; Nacher, P J

    2004-01-01

    Optical pumping of He-3 produces large (hyper) nuclear-spin polarizations independent of the magnetic resonance imaging (MRI) field strength. This allows lung MRI to be performed at reduced fields with many associated benefits, such as lower tissue susceptibility gradients and decreased power absorption rates. Here we present results of 2D imaging as well as accurate 1D gas diffusion mapping of the human lung using He-3 at very low field (3 mT). Furthermore, measurements of transverse relaxation in zero applied gradient are shown to accurately track pulmonary oxygen partial pressure, opening the way for novel imaging sequences.

  3. Effects of GnRH and Prostaglandin Combined with a Short Progestin Regimen on the Synchrony of Estrus and Ovulation in Ewes During the Breeding Season 

    E-Print Network [OSTI]

    Dickison, James William

    2012-02-14

    Approved by: Co-Chairs of Committee, W. Shawn Ramsey David W. Forrest Committee Members, Clay A. Cavinder Glenn A. Holub Chris Boleman Head of Department, Gary Acuff December 2010 Major Subject: Animal Science iii ABSTRACT Effects of Gn... Committee: Dr. W. Shawn Ramsey Dr. David W. Forrest Two trials were conducted to quantify the effects of GnRH and prostaglandin in conjunction with a 7-d CIDR on estrus and on pregnancy rate in comparison with a traditional...

  4. Structure Determination of Ba8CoRh6O21, a New Member of the 2H-Perovskite Related Oxides

    E-Print Network [OSTI]

    zur Loye, Hans-Conrad

    Structure Determination of Ba8CoRh6O21, a New Member of the 2H-Perovskite Related Oxides H.-C. zur of an m = 5, n = 3 member of the A3n+3mA'nB3m+nO9m+6n family of 2H hexagonal perovskite related oxides. For this reason, perovskite and perovskite-related oxides in particular have long provided excellent candidates

  5. A polymorphism in metallothionein 1A (MT1A) is associated with cadmium-related excretion of urinary beta 2?microglobulin

    SciTech Connect (OSTI)

    Lei, Lijian; Department of Epidemiology, School of Public Health, Shanxi Medical University, Shanxi ; Chang, Xiuli; Rentschler, Gerda; Tian, Liting; Zhu, Guoying; Chen, Xiao; Jin, Taiyi; Broberg, Karin

    2012-12-15

    Objectives: Cadmium (Cd) toxicity of the kidney varies between individuals despite similar exposure levels. In humans Cd is mainly bound to metallothioneins (MT), which scavenge its toxic effects. Here we analyzed whether polymorphisms in MT genes MT1A and MT2A influence Cd-related kidney damage. Methods: In a cross-sectional study N = 512 volunteers were selected from three areas in South-Eastern China, which to varying degree were Cd-polluted from a smelter (control area [median Cd in urine U-Cd = 2.67 ?g/L], moderately [U-Cd = 4.23 ?g/L] and highly [U-Cd = 9.13 ?g/L] polluted areas). U-Cd and blood Cd (B-Cd) concentrations were measured by graphite-furnace atomic absorption spectrometry. MT1A rs11076161 (G/A), MT2A rs10636 (G/C) and MT2A rs28366003 (A/G) were determined by Taqman assays; urinary N-Acetyl-beta-(D)-Glucosaminidase (UNAG) by spectrometry, and urinary ?2-microglobulin (UB2M) by ELISA. Results: Higher B-Cd (natural log-transformed) with increasing number of MT1A rs11076161 A-alleles was found in the highly polluted group (p-value trend = 0.033; all p-values adjusted for age, sex, and smoking). In a linear model a significant interaction between rs11076161 genotype and B-Cd was found for UNAG (p = 0.001) and UB2M concentrations (p = 0.001). Carriers of the rs11076161 AA genotype showed steeper slopes for the associations between Cd in blood and natural log-transformed UB2M (? = 1.2, 95% CI 0.72–1.6) compared to GG carriers (? = 0.30, 95% CI 0.15–0.45). Also for UNAG (natural log-transformed) carriers of the AA genotype had steeper slopes (? = 0.55, 95% CI 0.27–0.84) compared to GG carriers (? = 0.018, 95% CI ? 0.79–0.11). Conclusions: MT1A rs11076161 was associated with B-Cd concentrations and Cd-induced kidney toxicity at high exposure levels. -- Highlights: ? Cadmium is toxic to the kidney but the susceptibility differs between individuals. ? The toxic effect of cadmium is scavenged by metallothioneins. ? A common variant of metallothionein 1A was genotyped in 512 cadmium exposed humans. ? Variant carriers of this polymorphism showed more kidney damage from cadmium. ? The frequency of these variants needs to be taken into account in risk assessment.

  6. Dendrimer Templated Synthesis of One Nanometer Rh and Pt Particles Supported on Mesoporous Silica: Catalytic Activity for Ethylene and Pyrrole Hydrogenation.

    SciTech Connect (OSTI)

    Huang, Wenyu; Kuhn, John N.; Tsung, Chia-Kuang; Zhang, Yawen; Habas, Susan E.; Yang, Peidong; Somorjai, Gabor A.

    2008-05-09

    Monodisperse rhodium (Rh) and platinum (Pt) nanoparticles as small as {approx}1 nm were synthesized within a fourth generation polyaminoamide (PAMAM) dendrimer, a hyperbranched polymer, in aqueous solution and immobilized by depositing onto a high-surface-area SBA-15 mesoporous support. X-ray photoelectron spectroscopy indicated that the as-synthesized Rh and Pt nanoparticles were mostly oxidized. Catalytic activity of the SBA-15 supported Rh and Pt nanoparticles was studied with ethylene hydrogenation at 273 and 293 K in 10 torr of ethylene and 100 torr of H{sub 2} after reduction (76 torr of H{sub 2} mixed with 690 torr of He) at different temperatures. Catalysts were active without removing the dendrimer capping but reached their highest activity after hydrogen reduction at a moderate temperature (423 K). When treated at a higher temperature (473, 573, and 673 K) in hydrogen, catalytic activity decreased. By using the same treatment that led to maximum ethylene hydrogenation activity, catalytic activity was also evaluated for pyrrole hydrogenation.

  7. First Measurement of the $^{96}$Ru(p,$?$)$^{97}$Rh Cross Section for the p-Process with a Storage Ring

    E-Print Network [OSTI]

    Bo Mei; Thomas Aumann; Shawn Bishop; Klaus Blaum; Konstanze Boretzky; Fritz Bosch; Carsten Brandau; Harald Bräuning; Thomas Davinson; Iris Dillmann; Christina Dimopoulou; Olga Ershova; Zsolt Fülöp; Hans Geissel; Jan Glorius; György Gyürky; Michael Heil; Franz Käppeler; Aleksandra Kelic-Heil; Christophor Kozhuharov; Christoph Langer; Tudi Le Bleis; Yuri Litvinov; Gavin Lotay; Justyna Marganiec; Gottfried Münzenberg; Fritz Nolden; Nikolaos Petridis; Ralf Plag; Ulrich Popp; Ganna Rastrepina; René Reifarth; Björn Riese; Catherine Rigollet; Christoph Scheidenberger; Haik Simon; Kerstin Sonnabend; Markus Steck; Thomas Stöhlke; Tamás Szücs; Klaus Sümmerer; Günter Weber; Helmut Weick; Danyal Winters; Natalya Winters; Philip Woods; Qiping Zhong

    2015-07-10

    This work presents a direct measurement of the $^{96}$Ru($p, \\gamma$)$^{97}$Rh cross section via a novel technique using a storage ring, which opens opportunities for reaction measurements on unstable nuclei. A proof-of-principle experiment was performed at the storage ring ESR at GSI in Darmstadt, where circulating $^{96}$Ru ions interacted repeatedly with a hydrogen target. The $^{96}$Ru($p, \\gamma$)$^{97}$Rh cross section between 9 and 11 MeV has been determined using two independent normalization methods. As key ingredients in Hauser-Feshbach calculations, the $\\gamma$-ray strength function as well as the level density model can be pinned down with the measured ($p, \\gamma$) cross section. Furthermore, the proton optical potential can be optimized after the uncertainties from the $\\gamma$-ray strength function and the level density have been removed. As a result, a constrained $^{96}$Ru($p, \\gamma$)$^{97}$Rh reaction rate over a wide temperature range is recommended for $p$-process network calculations.

  8. First Measurement of the $^{96}$Ru(p,$\\gamma$)$^{97}$Rh Cross Section for the p-Process with a Storage Ring

    E-Print Network [OSTI]

    Mei, Bo; Bishop, Shawn; Blaum, Klaus; Boretzky, Konstanze; Bosch, Fritz; Brandau, Carsten; Bräuning, Harald; Davinson, Thomas; Dillmann, Iris; Dimopoulou, Christina; Ershova, Olga; Fülöp, Zsolt; Geissel, Hans; Glorius, Jan; Gyürky, György; Heil, Michael; Käppeler, Franz; Kelic-Heil, Aleksandra; Kozhuharov, Christophor; Langer, Christoph; Bleis, Tudi Le; Litvinov, Yuri; Lotay, Gavin; Marganiec, Justyna; Münzenberg, Gottfried; Nolden, Fritz; Petridis, Nikolaos; Plag, Ralf; Popp, Ulrich; Rastrepina, Ganna; Reifarth, René; Riese, Björn; Rigollet, Catherine; Scheidenberger, Christoph; Simon, Haik; Sonnabend, Kerstin; Steck, Markus; Stöhlke, Thomas; Szücs, Tamás; Sümmerer, Klaus; Weber, Günter; Weick, Helmut; Winters, Danyal; Winters, Natalya; Woods, Philip; Zhong, Qiping

    2015-01-01

    This work presents a direct measurement of the $^{96}$Ru($p, \\gamma$)$^{97}$Rh cross section via a novel technique using a storage ring, which opens opportunities for reaction measurements on unstable nuclei. A proof-of-principle experiment was performed at the storage ring ESR at GSI in Darmstadt, where circulating $^{96}$Ru ions interacted repeatedly with a hydrogen target. The $^{96}$Ru($p, \\gamma$)$^{97}$Rh cross section between 9 and 11 MeV has been determined using two independent normalization methods. As key ingredients in Hauser-Feshbach calculations, the $\\gamma$-ray strength function as well as the level density model can be pinned down with the measured ($p, \\gamma$) cross section. Furthermore, the proton optical potential can be optimized after the uncertainties from the $\\gamma$-ray strength function and the level density have been removed. As a result, a constrained $^{96}$Ru($p, \\gamma$)$^{97}$Rh reaction rate over a wide temperature range is recommended for $p$-process network calculations.

  9. Wiedemann-Franz law and nonvanishing temperature scale across the field-tuned quantum critical point of YbRh2Si2

    SciTech Connect (OSTI)

    Reid, J.-Ph.; Tanatar, Makariy; Daou, R.; Hu, Rongwei; Petrovic, C.; Taillefer, Louis

    2014-01-23

    The in-plane thermal conductivity kappa and electrical resistivity rho of the heavy-fermion metal YbRh2Si2 were measured down to 50 mK for magnetic fields H parallel and perpendicular to the tetragonal c axis, through the field-tuned quantum critical point H-c, at which antiferromagnetic order ends. The thermal and electrical resistivities, w L0T/kappa and rho, show a linear temperature dependence below 1 K, typical of the non-Fermi-liquid behavior found near antiferromagnetic quantum critical points, but this dependence does not persist down to T = 0. Below a characteristic temperature T-star similar or equal to 0.35 K, which depends weakly on H, w(T) and rho(T) both deviate downward and converge as T -> 0. We propose that T-star marks the onset of short-range magnetic correlations, persisting beyond H-c. By comparing samples of different purity, we conclude that the Wiedemann-Franz law holds in YbRh2Si2, even at H-c, implying that no fundamental breakdown of quasiparticle behavior occurs in this material. The overall phenomenology of heat and charge transport in YbRh2Si2 is similar to that observed in the heavy-fermion metal CeCoIn5, near its own field-tuned quantum critical point.

  10. Mid-IR Fiber-Based Light Sources (~2 to 6.5 microns)

    E-Print Network [OSTI]

    Cafarella, Michael J.

    1 Mid-IR Fiber-Based Light Sources (~2 to 6.5 microns) Prof. Mohammed N. Islam Department) Combustion Monitoring Infr (Cha Cone Penetrometer Contaminated Soil In L SCAPS* truck * (Site

  11. A Calibrated Measurement of the Near-IR Continuum Sky Brightness Using Magellan/FIRE

    E-Print Network [OSTI]

    Sullivan, Peter William

    We characterize the near-IR sky background from 308 observations with the Folded-port InfraRed Echellette (FIRE) spectrograph at Magellan. A subset of 105 observations selected to minimize lunar and thermal effects gives ...

  12. An IR-based Evaluation Framework for Web Search Query Segmentation

    E-Print Network [OSTI]

    Ganguly, Niloy

    An IR-based Evaluation Framework for Web Search Query Segmentation Author 1 Author 1 Affiliation Author 1 Address Author 1 Email Author 2 Author 2 Affiliation Author 2 Address Author 2 Email ABSTRACT

  13. DESIGN AND CONSTRUCTION OF A 15 T, 120 MM BORE IR QUADRUPOLE MAGNET FOR LARP

    E-Print Network [OSTI]

    Caspi, S.

    2011-01-01

    is developing a large bore (120 mm) IR quadrupole ( H Q )quadrupole ( H Q ) that extends the bore size from 90 mm to120 mm and pushes the field at the conductor just over 15 T.

  14. Hydrogen Bond Rearrangements in Water Probed with Temperature-Dependent 2D IR

    E-Print Network [OSTI]

    Nicodemus, Rebecca A.

    We use temperature-dependent two-dimensional infrared spectroscopy (2D IR) of dilute HOD in H2O to investigate hydrogen bond rearrangements in water. The OD stretching frequency is sensitive to its environment, and loss ...

  15. Giantically blue-shifted visible light in femtosecond mid-IR filament in fluorides

    E-Print Network [OSTI]

    Dormidonov, A E; Chekalin, S V; Kandidov, V P

    2015-01-01

    A giant blue shift of an isolated visible band of supercontinuum was discovered and studied in the single filament regime of Mid-IR femtosecond laser pulse at powers slightly exceeding critical power for self-focusing in fluorides.

  16. While catching estrildids for the Museum's Aviary along the Vaal River ir Acacla veld

    E-Print Network [OSTI]

    de Villiers, Marienne

    While catching estrildids for the Museum's Aviary along the Vaal River ir Acacla veld at the farm trained'. Well, a staternent like that rnade our irnacirrations run wild. TIrere you are u ith a silall r

  17. FT-IR spectroscopy technology, market evolution and future strategies of Bruker Optics Inc.

    E-Print Network [OSTI]

    Higdon, Thomas (Thomas Charles)

    2010-01-01

    This thesis explores the technology and market evolution of FT-IR spectroscopy over its nearly forty year history to aid in determining future product design and marketing strategies for an industry-leading firm, Bruker ...

  18. Estimated IR and phosphorescence emission fluxes for specific Polycyclic Aromatic Hydrocarbons in the Red Rectangle

    E-Print Network [OSTI]

    G. Mulas; G. Malloci; C. Joblin; D. Toublanc

    2005-09-20

    Following the tentative identification of the blue luminescence in the Red Rectangle by Vijh et al. (2005), we compute absolute fluxes for the vibrational IR emission and phosphorescence bands of three small polycyclic aromatic hydrocarbons. The calculated IR spectra are compared with available ISO observations. A subset of the emission bands are predicted to be observable using presently available facilities, and can be used for an immediate, independent, discriminating test on their alleged presence in this well-known astronomical object.

  19. DRIVER ACCELERATOR DESIGN FOR THE 10 KW UPGRADE OF THE JEFFERSON LAB IR FEL

    E-Print Network [OSTI]

    DRIVER ACCELERATOR DESIGN FOR THE 10 KW UPGRADE OF THE JEFFERSON LAB IR FEL D. Douglas, S. V, Newport News, VA23606, USA Abstract An upgrade of the Jefferson Lab IR FEL [1] is now un- der construction. It will provide 10 kW output light power in a wavelength range of 2­10 µm. The FEL will be driven by a modest

  20. LENS MODELS OF HERSCHEL-SELECTED GALAXIES FROM HIGH-RESOLUTION NEAR-IR OBSERVATIONS

    SciTech Connect (OSTI)

    Calanog, J. A.; Cooray, A.; Ma, B.; Casey, C. M. [Department of Physics and Astronomy, University of California, Irvine, CA 92697 (United States); Fu, Hai [Department of Physics and Astronomy, University of Iowa, Van Allen Hall, Iowa City, IA 52242 (United States); Wardlow, J. [Dark Cosmology Centre, Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, DK-2100 Copenhagen (Denmark); Amber, S. [Department of Physical Sciences, The Open University, Milton Keynes MK7 6AA (United Kingdom); Baker, A. J. [Department of Physics and Astronomy, Rutgers, The State University of New Jersey, 136 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Baes, M. [1 Sterrenkundig Observatorium, Universiteit Gent, Krijgslaan 281, B-9000 Gent (Belgium); Bock, J. [California Institute of Technology, 1200 E. California Blvd., Pasadena, CA 91125 (United States); Bourne, N.; Dye, S. [School of Physics and Astronomy, University of Nottingham, NG7 2RD (United Kingdom); Bussmann, R. S. [Department of Astronomy, Space Science Building, Cornell University, Ithaca, NY 14853-6801 (United States); Chapman, S. C. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 0HA (United Kingdom); Clements, D. L. [Astrophysics Group, Imperial College London, Blackett Laboratory, Prince Consort Road, London SW7 2AZ (United Kingdom); Conley, A. [Center for Astrophysics and Space Astronomy 389-UCB, University of Colorado, Boulder, CO 80309 (United States); Dannerbauer, H. [Laboratoire AIM-Paris-Saclay, CEA/DSM/Irfu-CNRS-Université Paris Diderot, CE-Saclay, pt courrier 131, F-91191 Gif-sur-Yvette (France); De Zotti, G. [INAF-Osservatorio Astronomico di Padova, Vicolo dell'Osservatorio 5, I-35122 Padova (Italy); Dunne, L.; Eales, S. [School of Physics and Astronomy, Cardiff University, Queens Buildings, The Parade, Cardiff CF24 3AA (United Kingdom); and others

    2014-12-20

    We present Keck-Adaptive Optics and Hubble Space Telescope high resolution near-infrared (IR) imaging for 500 ?m bright candidate lensing systems identified by the Herschel Multi-tiered Extragalactic Survey and Herschel Astrophysical Terahertz Large Area Survey. Out of 87 candidates with near-IR imaging, 15 (?17%) display clear near-IR lensing morphologies. We present near-IR lens models to reconstruct and recover basic rest-frame optical morphological properties of the background galaxies from 12 new systems. Sources with the largest near-IR magnification factors also tend to be the most compact, consistent with the size bias predicted from simulations and previous lensing models for submillimeter galaxies (SMGs). For four new sources that also have high-resolution submillimeter maps, we test for differential lensing between the stellar and dust components and find that the 880 ?m magnification factor (?{sub 880}) is ?1.5 times higher than the near-IR magnification factor (?{sub NIR}), on average. We also find that the stellar emission is ?2 times more extended in size than dust. The rest-frame optical properties of our sample of Herschel-selected lensed SMGs are consistent with those of unlensed SMGs, which suggests that the two populations are similar.

  1. New insulating antiferromagnetic quaternary iridates MLa10Ir4O24 (M=Sr, Ba)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, Qingbiao; Han, Fei; Stoumpos, Constantinos C.; Han, Tian -Heng; Li, Hao; Mitchell, J. F.

    2015-07-01

    Recently, oxides of Ir4+ have received renewed attention in the condensed matter physics community, as it has been reported that certain iridates have a strongly spin-orbital coupled (SOC) electronic state, Jeff = ½, that defines the electronic and magnetic properties. The canonical example is the Ruddlesden-Popper compound Sr2IrO4, which has been suggested as a potential route to a new class of high temperature superconductor due to the formal analogy between Jeff = ½ and the S = ½ state of the cuprate superconductors. The quest for other iridium oxides that present tests of the underlying SOC physics is underway. Inmore »this spirit, here we report the synthesis and physical properties of two new quaternary tetravalent iridates, MLa10Ir4O24 (M = Sr, Ba). The crystal structure of both compounds features isolated IrO6 octahedra in which the electronic configuration of Ir is d5. As a result, both compounds order antiferromagnetically despite the lack of obvious superexchange pathways, and resistivity measurement shows that SrLa10Ir4O24 is an insulator.« less

  2. LOCA simulation in the national research universal reactor program: postirradiation examination results for the third materials experiment (MT-3)

    SciTech Connect (OSTI)

    Rausch, W.N.

    1984-04-01

    A series of in-reactor experiments were conducted using full-length 32-rod pressurized water reactor (PWR) fuel bundles as part of the Loss-of-Coolant Accident (LOCA) Simulation Program. The third materials experiment (MT-3) was the sixth in the series of thermal-hydraulic and materials deformation/rutpure experiments conducted in the National Research Universal (NRU) reactor, Chalk River, Ontario, Canada. The main objective of the experiment was to evaluate ballooning and rupture during active two-phase cooling in the temperature range from 1400 to 1500/sup 0/F (1030 to 1090 K). The 12 test rods in the center of the 32-rod bundle were initially pressurized to 550 psi (3.8 MPa) to insure rupture in the correct temperature range. All 12 of the rods ruptured, with an average peak bundle strain of approx. 55%. The UKAEA also funded destructive postirradiation examination (PIE) of several of the ruptured rods from the MT-3 experiment. This report describes the work performed and presents the PIE results. Information obtained during the PIE included cladding thickness measurements metallography, and particle size analysis of the cracked and broken fuel pellets.

  3. Searches for supersymmetry using the MT2 variable in hadronic events produced in pp collisions at 8 TeV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khachatryan, V.

    2015-05-15

    Searches for supersymmetry (SUSY) are performed using a sample of hadronic events produced in 8 TeV pp collisions at the CERN LHC. The searches are based on the MT2 variable, which is a measure of the transverse momentum imbalance in an event. The data were collected with the CMS detector and correspond to an integrated luminosity of 19.5 fb?¹. Two related searches are performed. The first is an inclusive search based on signal regions defined by the value of the MT2 variable, the hadronic energy in the event, the jet multiplicity, and the number of jets identified as originating frommore »bottom quarks. The second is a search for a mass peak corresponding to a Higgs boson decaying to a bottom quark-antiquark pair, where the Higgs boson is produced as a decay product of a SUSY particle. For both searches, the principal backgrounds are evaluated with data control samples. No significant excess over the expected number of background events is observed, and exclusion limits on various SUSY models are derived.« less

  4. Temperature and RH Targets

    Broader source: Energy.gov [DOE]

    Presented by Vishal O Mittal of the Florida Solar Energy Center at the High Temperature Membrane Working Group Meeting, San Francisco, September 14, 2006.

  5. Microsoft Word - ORNL RH

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGE OFDetection of Hydrates on Gas5 15NEWS MEDIA CONTACT: March

  6. Microsoft Word - SRS RH

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGE OFDetection of Hydrates7 UnlimitedSupply6254 3.95AprTheFOR

  7. RH_SRS_Shipment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMassR&D100 Winners * Impacts on Global TechnologyProceeding SignPrice Volatility

  8. RH TRU Waste Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) by Carbon-RichProton Delivery andInnovations INFORMATION ExplainMadison

  9. Superconducting and magnetic properties of Sr3Ir4Sn13

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Biswas, P. K.; Amato, A.; Khasanov, R.; Luetkens, H.; Wang, Kefeng; Petrovic, C.; Cook, R. M.; Lees, M. R.; Morenzoni, E.

    2014-10-10

    In this research, magnetization and muon spin relaxation or rotation (µSR) measurements have been performed to study the superconducting and magnetic properties of Sr?Ir?Sn??. From magnetization measurements the lower and upper critical fields of Sr?Ir?Sn?? are found to be 81(1) Oe and 14.4(2) kOe, respectively. Zero-field µSR data show no sign of any magnetic ordering or weak magnetism in Sr?Ir?Sn??. Transverse-field µSR measurements in the vortex state provided the temperature dependence of the magnetic penetration depth ?. The dependence of ??² with temperature is consistent with the existence of single s-wave energy gap in the superconducting state of Sr?Ir?Sn?? withmore »a gap value of 0.82(2) meV at absolute zero temperature. The magnetic penetration depth at zero temperature ?(0) is 291(3) nm. The ratio ?(0)/kBTc = 2.1(1) indicates that Sr?Ir?Sn?? should be considered as a strong-coupling superconductor.« less

  10. Bioorganometallic chemistry: biocatalytic oxidation reactions with biomimetic nad+/nadh co-factors and [cp*rh(bpy)h]+ for selective organic synthesis

    SciTech Connect (OSTI)

    Lutz, Jochen; Hollman, Frank; Ho, The Vinh; Schnyder, Adrian; Fish, Richard H.; Schmid, Andreas

    2004-03-09

    The biocatalytic, regioselective hydroxylation of 2-hydroxybiphenyl to the corresponding catechol was accomplished utilizing the monooxygenase 2-hydroxybiphenyl 3-monooxygenase (HbpA). The necessary natural nicotinamide adenine dinucleotide (NAD{sup +}) co-factor for this biocatalytic process was replaced by a biomimetic co-factor, N-benzylnicotinamide bromide, 1a. The interaction between the flavin (FAD) containing HbpA enzyme and the corresponding biomimetic NADH compound, N-benzyl-1,4-dihdronicotinamide, 1b, for hydride transfers, was shown to readily occur. The in situ recycling of the reduced NADH biomimic 1b from 1a was accomplished with [Cp*Rh(bpy)H](Cl); however, productive coupling of this regeneration reaction to the enzymatic hydroxylation reaction was not totally successful, due to a deactivation process concerning the HbpA enzyme peripheral groups; i.e., -SH or -NH{sub 2} possibly reacting with the precatalyst, [Cp*Rh(bpy)(H{sub 2}O)](Cl){sub 2}, and thus inhibiting the co-factor regeneration process. The deactivation mechanism was studied, and a promising strategy of derivatizing these peripheral -SH or -NH{sub 2} groups with a polymer containing epoxide was successful in circumventing the undesired interaction between HbpA and the precatalyst. This latter strategy allowed tandem co-factor regeneration using 1a or 2a, [Cp*Rh(bpy)(H2O)](Cl){sub 2}, and formate ion, in conjunction with the polymer bound, FAD containing HbpA enzyme to provide the catechol product.

  11. Soil Science Society of America Journal This work was presented at the 12th North American Forest Soils Conference, Whitefish, MT, 1620

    E-Print Network [OSTI]

    Martin, Timothy

    Soils Conference, Whitefish, MT, 16­20 June 2013, in the Production Systems for Biomass and Bioenergy silvicultural practices used, and when combined with suitable site preparation techniques and the deployment fourfold higher aboveground pine biomass than the C treatment (7.7 Mg ha-1); the untreated CF (17.9 Mg ha-1

  12. NEAFS Y-mtDNA Workshop (Butler and Coble) November 1, 2006 http://www.cstl.nist.gov/biotech/strbase/training.htm 1

    E-Print Network [OSTI]

    NEAFS Y-mtDNA Workshop (Butler and Coble) November 1, 2006 http://www.cstl.nist.gov/biotech textbook (now in its 2nd Edition) · STRBase website: http://www.cstl.nist.gov/biotech/strbase/ · Family: wife Terilynne and 6 children · Hobbies: reading and writing http://www.cstl.nist.gov/biotech

  13. Comment on ``A modified leapfrog scheme for shallow water equations'' by Wen-Yih Sun and Oliver M.T. Sun

    E-Print Network [OSTI]

    Williams, Paul

    Commentary Comment on ``A modified leapfrog scheme for shallow water equations'' by Wen-Yih Sun and Oliver M.T. Sun Paul D. Williams Department of Meteorology, University of Reading, UK a r t i c l e i n f integration of the shallow-water equa- tions using the leapfrog time-stepping scheme [Sun Wen-Yih, Sun Oliver

  14. Modulated IR radiometry for determining thermal properties and basic characteristics of titanium thin films

    SciTech Connect (OSTI)

    Apreutesei, Mihai; Lopes, Claudia; Vaz, Filipe; Macedo, Francisco; Borges, Joel

    2014-07-01

    Titanium thin films of different thicknesses were prepared by direct current magnetron sputtering to study modulated infrared (IR) radiometry as a tool for analyzing film thickness. Thickness was varied by regularly increasing the deposition time, keeping all the other deposition parameters constant. The influence of film thickness on morphological, structural, and electrical properties of the titanium coatings also was investigated. The experimental results revealed a systematic grain growth with increasing film thickness, along with enhanced film crystallinity, which led to increased electrical conductivity. Using the results obtained by modulated IR radiometry, the thickness of each thin film was calculated. These thickness values were then compared with the coating thickness measurements obtained by scanning electron microscopy. The values confirmed the reliability of modulated IR radiometry as an analysis tool for thin films and coatings, and for determining thicknesses in the micrometer range, in particular.

  15. Handling collision debris in quad- and dipole-first LHC IR options

    SciTech Connect (OSTI)

    Mokhov, N.V.; Rakhno, I.L.; /Fermilab

    2006-12-01

    Detailed MARS15 Monte Carlo energy deposition calculations are performed for two main designs of the LHC interaction regions (IR) capable to achieve a luminosity of 10{sup 35} cm{sup -2} s{sup -1}: a traditional quadrupole-first scheme and the one with a dual-bore inner triplet with separation dipoles placed in front of the quadrupoles. It is shown that with the appropriate design of the Nb3Sn magnets, IR layout and a number of protective measures implemented, both schemes are feasible for the LHC luminosity upgrade up to 10{sup 35} cm{sup -2} s{sup -1}.

  16. Mechanism of Efficient Anti-Markovnikov Olefin Hydroarylation Catalyzed by Homogeneous Ir(III) Complexes

    SciTech Connect (OSTI)

    Bhalla, Gaurav; Bischof, Steven M; Ganesh, Somesh K; Liu, Xiang Y; Jones, C J; Borzenko, Andrey; Tenn, William J; Ess, Daniel H; Hashiguchi, Brian G; Lokare, Kapil S; Leung, Chin Hin; Oxgaard, Jonas; Goddard, William A; Periana, Roy A

    2011-01-01

    The mechanism of the hydroarylation reaction between unactivated olefins (ethylene, propylene, and styrene) and benzene catalyzed by [(R)Ir(?-acac-O,O,C{sup 3})-(acac-O,O){sub 2}]{sub 2} and [R-Ir(acac-O,O){sub 2}(L)] (R = acetylacetonato, CH{sub 3}, CH{sub 2}CH{sub 3}, Ph, or CH{sub 2}CH{sub 2}Ph, and L = H{sub 2}O or pyridine) Ir(III) complexes was studied by experimental methods. The system is selective for generating the anti-Markovnikov product of linear alkylarenes (61:39 for benzene + propylene and 98:2 for benzene + styrene). The reaction mechanism was found to follow a rate law with first-order dependence on benzene and catalyst, but a non-linear dependence on olefin. {sup 13}C-labelling studies with CH{sub 3}{sup 13}CH{sub 2}-Ir-Py showed that reversible ?-hydride elimination is facile, but unproductive, giving exclusively saturated alkylarene products. The migration of the {sup 13}C-label from the ? to ?-positions was found to be slower than the C–H activation of benzene (and thus formation of ethane and Ph-d{sub 5}-Ir-Py). Kinetic analysis under steady state conditions gave a ratio of the rate constants for CH activation and ?-hydride elimination (k{sub CH}: k{sub ?}) of ~0.5. The comparable magnitude of these rates suggests a common rate determining transition state/intermediate, which has been shown previously with B3LYP density functional theory (DFT) calculations. Overall, the mechanism of hydroarylation proceeds through a series of pre-equilibrium dissociative steps involving rupture of the dinuclear species or the loss of L from Ph-Ir-L to the solvento, 16-electron species, Ph-Ir(acac-O,O){sub 2}-Sol (where Sol refers to coordinated solvent). This species then undergoes trans to cisisomerization of the acetylacetonato ligand to yield the pseudo octahedral species cis-Ph-Ir-Sol, which is followed by olefin insertion (the regioselective and rate determining step), and then activation of the C–H bond of an incoming benzene to generate the product and regenerate the catalyst.

  17. Filamentation of IR and UV femtosecond pulses upon focusing in air

    SciTech Connect (OSTI)

    Dergachev, A A; Ionin, Andrei A; Kandidov, V P; Seleznev, L V; Sinitsyn, D V; Sunchugasheva, E S; Shlenov, Svyatoslav A

    2013-01-31

    The filamentation of IR and UV laser pulses has been studied numerically and experimentally for different initial beam focusing geometries, and linear electron density profiles along the plasma channel of filaments have been obtained. The results demonstrate that changes in laser beam focusing have a stronger effect on filament and plasma channel parameters for UV radiation than for IR radiation. Focusing causes individual high fluence regions produced by refocusing to merge to form a continuous extended filament with a continuous plasma channel. (nonlinear optical phenomena)

  18. Origin of the phase transition in IrTe2: structural modulation and local bonding instability

    SciTech Connect (OSTI)

    Cao, Huibo [ORNL; Chakoumakos, Bryan C [ORNL; Yan, Jiaqiang [ORNL; Zhou, Haidong [ORNL; Custelcean, Radu [ORNL; Mandrus, D. [University of Tennessee (UTK) and Oak Ridge National Laboratory (ORNL); McGuire, Michael A [ORNL; Singh, David J [ORNL; Chen, Xin [ORNL; Yang, Hui [University of Tennessee, Knoxville (UTK)

    2013-01-01

    We used X-ray/neutron diffraction to determine the low temperature (LT) structure of IrTe2. A structural modulation was observed with a wavevector of k =(1/5, 0, 1/5) below Ts285 K, accompanied by a structural transition from a trigonal to a triclinic lattice. We also performed the first principles calculations for high temperature (HT) and LT structures, which elucidate the nature of the phase transition and the LT structure. A local bonding instability associated with the Te 5p states is likely the origin of the structural phase transition in IrTe2.

  19. Fits to the Fermi-LAT GeV excess with RH sneutrino dark matter: implications for direct and indirect dark matter searches and the LHC

    E-Print Network [OSTI]

    Cerdeno, D G; Robles, S

    2015-01-01

    We show that the right-handed (RH) sneutrino in the NMSSM can account for the observed excess in the Fermi-LAT spectrum of gamma rays from the Galactic Centre, while fulfilling all the current experimental constraints from the LHC as well as from direct and indirect dark matter searches. We have explored the parameter space of this scenario, computed the gamma ray spectrum for each phenomenologically viable solution and then performed a chi^2 fit to the excess. Unlike previous studies based on model independent interpretations, we have taken into account the full annihilation spectrum, without assuming pure annihilation channels. Furthermore, we have incorporated limits from direct detection experiments, LHC bounds and also the constraints from Fermi-LAT on dwarf spheroidal galaxies (dSphs) and gamma ray spectral lines. In addition, we have estimated the effect of the most recent Fermi-LAT reprocessed data (Pass~8). In general, we obtain good fits to the GCE when the RH sneutrino annihilates mainly into pairs...

  20. NISTIR 8056 http://dx.doi.org/10.6028/NIST.IR.8056

    E-Print Network [OSTI]

    Summary of Activities for Fiscal Year 2014 #12;#12;NISTIR 8056 Applied and Computational Mathematics Division Summary of Activities for Fiscal Year 2014 Ronald F. Boisvert, Editor Applied and Computational Mathematics Division Information Technology Laboratory http://dx.doi.org/10.6028/NIST.IR.8056 April 2015 U

  1. ELSEVIER International Journal of Industrial Ergonomics 17 (1996) 285-290 Ir~ernattonatlournalc~

    E-Print Network [OSTI]

    Radwin, Robert G.

    1996-01-01

    ELSEVIER International Journal of Industrial Ergonomics 17 (1996) 285-290 Ir~ernattonatlournalc~ Industrial Ergonomics Short communication A new method for extending the range of conductive polymer sensors measurement instruments are important for providing ergonomics practitioners with a quantitative means

  2. Effective temperatures and radii of planet-hosting stars from IR photometry

    E-Print Network [OSTI]

    I. Ribas; E. Solano; E. Masana; A. Gimenez

    2003-10-16

    In this paper we present and analyse determinations of effective temperatures of planet-hosting stars using infrared (IR) photometry. One of our goals is the comparison with spectroscopic temperatures to evaluate the presence of systematic effects that could alter the determination of metal abundances. To estimate the stellar temperatures we have followed a new approach based on fitting the observed 2MASS IR photometry with accurately calibrated synthetic photometry. Special care has been put in evaluating all sources of possible errors and incorporating them in the analysis. A comparison of our temperature determinations with spectroscopic temperatures published by different groups reveals the presence of no systematic trends and a scatter compatible with the quoted uncertainties of 0.5-1.3%. This mutual agreement strengthens the results of both the spectroscopic and IR photometry analyses. Comparisons with other photometric temperature calibrations, generally with poorer performances, are also presented. In addition, the method employed of fitting IR photometry naturally yields determinations of the stellar semi-angular diameters, which, when combined with the distances, results in estimations of the stellar radii with remarkable accuracies of ~2-4%. A comparison with the only star in the sample with an empirically determined radius (HD 209458 -- from transit photometry) indicates excellent agreement.

  3. Trans Mountain Response to SFU IR No. 2 Trans Mountain Pipeline ULC

    E-Print Network [OSTI]

    Kavanagh, Karen L.

    Trans Mountain Response to SFU IR No. 2 Trans Mountain Pipeline ULC Trans Mountain Expansion Terminal as well as key civil tasks. Request: (1) Please advise whether Trans Mountain has investigated Way and Burnaby Mountain Parkway either during normal operation of the tank farm, or in the event

  4. Water Dynamics in Salt Solutions Studied with Ultrafast Two-Dimensional Infrared (2D IR)

    E-Print Network [OSTI]

    Fayer, Michael D.

    Water Dynamics in Salt Solutions Studied with Ultrafast Two-Dimensional Infrared (2D IR. Many of these species are charged. In the ocean, water interacts with dissolved salts. In biological systems, water interacts with dissolved salts as well as charged amino acids, the zwitterionic head groups

  5. Hydrogen Bond Migration between Molecular Sites Observed with Ultrafast 2D IR Chemical Exchange Spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Migration between Molecular Sites Observed with Ultrafast 2D IR Chemical ExchangeVed: January 12, 2010 Hydrogen-bonded complexes between phenol and phenylacetylene are studied using ultrafast hydrogen bonding acceptor sites (phenyl or acetylene) that compete for hydrogen bond donors in solution

  6. AutomaticallyExtracted Thesauri for CrossLanguage IR: When Better is Worse

    E-Print Network [OSTI]

    Brown, Ralf

    the accuracy of the extracted thesaurus can in fact reduce the performance of an IR system using it to perform et al., 1997) was a corpus­based bilingual term­substitution thesaurus, called EBT (for example this thesaurus (Brown, 1997) was originally developed for use in word­ level alignment in an example

  7. Advantageous GOES IR results for ash mapping at high latitudes: Cleveland eruptions 2001

    E-Print Network [OSTI]

    Bluth, Gregg

    Advantageous GOES IR results for ash mapping at high latitudes: Cleveland eruptions 2001 Yingxin Gu] The February 2001 eruption of Cleveland Volcano, Alaska allowed for comparisons of volcanic ash detection using angle also influences the results. The MODIS and AVHRR data give consistent retrievals of the ash cloud

  8. The chemical instability of Na{sub 2}IrO{sub 3} in air

    SciTech Connect (OSTI)

    Krizan, J.W., E-mail: jkrizan@princeton.edu; Roudebush, J.H.; Fox, G.M.; Cava, R.J.

    2014-04-01

    Highlights: • Na{sub 2}IrO{sub 3} decomposes rapidly in laboratory air. • The decomposition requires the simultaneous presence of CO{sub 2} and H{sub 2}O. • Decomposition results in a dramatic change in the magnetic properties. • Second 5 K feature in magnetic susceptibility not previously reported. - Abstract: We report that Na{sub 2}IrO{sub 3}, which has a layered honeycomb iridium oxide sublattice interleaved by Na planes, decomposes in laboratory air while maintaining the same basic crystal structure. The decomposition reaction was monitored by time-dependent powder X-ray diffraction under different ambient atmospheres, through which it was determined that it occurs only in the simultaneous presence of both CO{sub 2} and H{sub 2}O. A hydrated sodium carbonate is the primary decomposition product along with altered Na{sub 2}IrO{sub 3}. The diffraction signature of the altered Na{sub 2}IrO{sub 3} is quite similar to that of the pristine material, which makes the detection of decomposition difficult in a sample handled under ordinary laboratory conditions. The decomposed samples show a significantly decreased magnetic susceptibility and the disappearance of the low temperature antiferromagnetic transition considered to be characteristic of the phase. Samples that have never been exposed to air after synthesis display a previously unreported magnetic transition at 5 K.

  9. The mid-IR spectra of 9-ethyl guanine, guanosine, and 2-deoxyguanosine

    E-Print Network [OSTI]

    de Vries, Mattanjah S.

    they are blind to species with sub picosecond lifetime excited states. The detection in helium droplets relies. Choi and Miller have observed the keto tautomers in helium droplets, showing their IR frequencies between the R2PI and the helium droplet work is not only in the degree of cooling but also

  10. The system for delivery of IR laser radiaton into high vacuum

    E-Print Network [OSTI]

    Abakumova, E V; Krasnov, A A; Muchnoi, N Yu; Pyata, E E

    2015-01-01

    The system for insertion of a laser beam into the vacuum chamber of high-energy storage ring is described. The main part of the system is the high-vacuum viewport for the IR radiation, based on ZnSe or GaAs crystals. The design of the viewports is presented.

  11. Neuroglobin dynamics observed with ultrafast 2D-IR vibrational echo spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Neuroglobin dynamics observed with ultrafast 2D-IR vibrational echo spectroscopy Haruto Ishikawa Contributed by Michael D. Fayer, August 15, 2007 (sent for review July 25, 2007) Neuroglobin (Ngb), a protein energy minimum. myoglobin mutants protein dynamics energy landscape Neuroglobin (Ngb) is a recently

  12. The TIJAH XML-IR system at INEX 2003 Johan List1

    E-Print Network [OSTI]

    Hiemstra, Djoerd

    its mapping into a query execution strategy. The logical layer exploits probabilistic region algebra components. The logical algebra expressions are mapped into efficient rela- tional algebra expressions over participated with the TIJAH XML-IR retrieval system, a research pro- totype built on top of the Monet

  13. Ion Impacts on Graphene/Ir(111): Interface Channeling, Vacancy Funnels, and a Nanomesh

    E-Print Network [OSTI]

    Krasheninnikov, Arkady V.

    simulations we study the production of defects in graphene on Ir(111) under grazing incidence of low energy Xe Koln, Zulpicher Straße 77, 50937 Koln, Germany Department of Physics, University of Helsinki, P.O. Box of Materials Science, University of Ulm, 89081 Ulm, Germany Department of Physics, University of Vienna

  14. Minimizing Energy Consumption in IR-UWB Based Wireless Sensor Networks

    E-Print Network [OSTI]

    Heinzelman, Wendi

    Minimizing Energy Consumption in IR-UWB Based Wireless Sensor Networks Tianqi Wang, Wendi communications systems, where transmit power can be flexibly adjusted to minimize the energy consumption [3] [4 Heinzelman and Alireza Seyedi Department of Electrical and Computer Engineering, University of Rochester

  15. Synthesis, Structure, and Reactivity of O-Donor Ir(III) Complexes: C-H Activation Studies with Benzene

    E-Print Network [OSTI]

    Goddard III, William A.

    with Benzene Gaurav Bhalla, Xiang Yang Liu, Jonas Oxgaard, William A. Goddard, III, and Roy A. Periana. All the R-Ir-Py complexes undergo quantitative, intermolecular CH activation reactions with benzene to benzene to generate a discrete benzene complex, cis-R-Ir-PhH; and (D) rapid C-H cleavage. Kinetic isotope

  16. Big picture Ads Duplicate detection Spam Web IR Size of the web Web Search and Text Mining

    E-Print Network [OSTI]

    Gray, Alexander

    Big picture Ads Duplicate detection Spam Web IR Size of the web Web Search and Text Mining http://www.cc.gatech.edu/~agray/6240spr11 IIR 19: Web Search Basics Alexander Gray Georgia Institute of Technology, College of Computing 2011 Gray: Web Search Basics 1 / 117 #12;Big picture Ads Duplicate detection Spam Web IR Size

  17. Paving the road in virtual spaces IRS Workshop Territoriality of the Commons 29.-30. Sept.2011 Rainer Kuhlen

    E-Print Network [OSTI]

    Kuhlen, Rainer

    Paving the road in virtual spaces­ IRS Workshop Territoriality of the Commons 29.-30. Sept.2011 the road in virtual spaces How to materialize rights to immaterial commons #12;Openness ­ Grundprinzip des;Openness ­ Grundprinzip des Handelns in elektronischen Räumen 4 #12;Paving the road in virtual spaces­ IRS

  18. An X-ray, IR, and Submillimeter Flare of Sagittarius A*

    E-Print Network [OSTI]

    D. P. Marrone; F. K. Baganoff; M. R. Morris; J. M. Moran; A. M. Ghez; S. D. Hornstein; C. D. Dowell; D. J. Munoz; M. W. Bautz; G. R. Ricker; W. N. Brandt; G. P. Garmire; J. R. Lu; K. Matthews; J. -H. Zhao; R. Rao; G. C. Bower

    2008-07-14

    Energetic flares are observed in the Galactic supermassive black hole Sagittarius A* from radio to X-ray wavelengths. On a few occasions, simultaneous flares have been detected in IR and X-ray observations, but clear counterparts at longer wavelengths have not been seen. We present a flare observed over several hours on 2006 July 17 with the Chandra X-Ray Observatory, the Keck II telescope, the Caltech Submillimeter Observatory, and the Submillimeter Array. All telescopes observed strong flare events, but the submillimeter peak is found to occur nearly 100 minutes after the X-ray peak. Submillimeter polarization data show linear polarization in the excess flare emission, increasing from 9% to 17% as the flare passes through its peak, consistent with a transition from optically thick to thin synchrotron emission. The temporal and spectral behavior of the flare require that the energetic electrons responsible for the emission cool faster than expected from their radiative output. This is consistent with adiabatic cooling in an expanding emission region, with X-rays produced through self-Compton scattering, although not consistent with the simplest model of such expansion. We also present a submillimeter flare that followed a bright IR flare on 2005 July 31. Compared to 2006, this event had a larger peak IR flux and similar submillimeter flux, but it lacked measurable X-ray emission. It also showed a shorter delay between the IR and submillimeter peaks. Based on these events we propose a synchrotron and self-Compton model to relate the submillimeter lag and the variable IR/X-ray luminosity ratio.

  19. Platinum-monolayer Electrocatalysts: Palladium Interlayer on IrCo Alloy Core Improves Activity in Oxygen-reduction Reaction

    SciTech Connect (OSTI)

    Gong, K.; Chen, W.-F.; Sasaki, K.; Su, D.; Vukmirovic, M.B.; Zhou, W.; Izzo, E.L.; Perez-Acosta, C.; Hirunsit, P.; Balbuena, P.B.; Adzic, R.R.

    2010-11-15

    We describe the synthesis and electrocatalytic properties of a new low-Pt electrocatalyst consisting of an IrCo core, a Pd interlayer, and a surface Pt monolayer, emphasizing the interlayer's role in improving electrocatalytic activity for the oxygen-reduction reaction on Pt in HClO{sub 4} solution. We prepared the IrCo alloys by decomposing, at 800 C, hexacyanometalate, KCoIr(CN){sub 6}, adsorbed on the carbon surfaces. The synthesis of Ir{sub 3}Co/C involved heating a mix of metal salts and carbon in hydrogen at 500 C. Thereafter, we placed a palladium and/or platinum monolayer on them via the galvanic displacement of an underpotentially deposited copper monolayer. The electrocatalysts were characterized using structural- and electrochemical-techniques. For PtML/PdML/IrCo/C, we observed a Pt mass activity of 1.18 A/mg{sub (Pt)} and the platinum-group-metals mass of 0.16 A/mg{sub (Pt, Pd, Ir)}. In comparison, without a Pd interlayer, i.e., Pt{sub ML}/IrCo/C, the activities of 0.15 A/mg{sub (Pt)} and 0.036 A/mg{sub (Pt, Pd, Ir)} were considerably lower. We consider that the palladium interlayer plays an essential role in achieving high catalytic activity by adjusting the electronic interaction of the platinum monolayer with the IrCo core, so that it accelerates the kinetics of adsorption and desorption of the intermediates of oxygen reduction. A similar trend was observed for Pt{sub ML}/Pd{sub ML} and Pt{sub ML} deposited on Ir{sub 3}Co/C alloy core. We used density functional theory to interpret the observed phenomena.

  20. Improvements in the M-T relation and mass function and the measured Omega_m through clusters evolution

    E-Print Network [OSTI]

    A. Del Popolo

    2003-09-05

    In this paper, I revisit the constraints obtained by several authors (Reichart et al. 1999; Eke et al. 1998; Henry 2000) on the estimated values of Omega_m, n and sigma_8 in the light of recent theoretical developments: 1) new theoretical mass functions (Sheth & Tormen 1999, Sheth, Mo & Tormen 1999, Del Popolo 2002b); 2) a more accurate mass-temperature relation, also determined for arbitrary Omega_m and Omega_{\\Lambda} (Voit 2000, Pierpaoli et al. 2001, Del Popolo 2002a). Firstly, using the quoted improvements, I re-derive an expression for the X-ray Luminosity Function (XLF), similarly to Reichart et al. (1999), and then I get some constraints to \\Omega_m and n, by using the ROSAT BCS and EMSS samples and maximum-likelihood analysis. Then I re-derive the X-ray Temperature Function (XTF), similarly to Henry (2000) and Eke et al. (1999), re-obtaining the constraints on Omega_m, n, sigma_8. Both in the case of the XLF and XTF, the changes in the mass function and M-T relation produces an increase in Omega_m of \\simeq 20% and similar results in sigma_8 and n.

  1. A Complete Solution Classification and Unified Algorithmic Treatment for the One- and Two-Step Asymmetric S-Transverse Mass (MT2) Event Scale Statistic

    E-Print Network [OSTI]

    Joel W. Walker

    2014-08-29

    The MT2 or "s-transverse mass" statistic was developed to associate a parent mass scale to a missing transverse energy signature, given that escaping particles are generally expected in pairs, while collider experiments are sensitive to just a single transverse momentum vector sum. This document focuses on the generalized extension of that statistic to asymmetric one- and two-step decay chains, with arbitrary child particle masses and upstream missing transverse momentum. It provides a unified theoretical formulation, complete solution classification, taxonomy of critical points, and technical algorithmic prescription for treatment of the MT2 event scale. An implementation of the described algorithm is available for download, and is also a deployable component of the author's selection cut software package AEACuS (Algorithmic Event Arbiter and Cut Selector). Appendices address combinatoric event assembly, algorithm validation, and a complete pseudocode.

  2. Probing the Mechanism of the Mycobacterium tuberculosis [beta]-Ketoacyl-Acyl Carrier Protein Synthase III mtFabH: Factors Influencing Catalysis and Substrate Specificity

    SciTech Connect (OSTI)

    Brown, Alistair K.; Sridharan, Sudharsan; Kremer, Laurent; Lindenberg, Sandra; Dover, Lynn G.; Sacchettini, James C.; Besra, Gurdyal S.

    2010-11-30

    Mycolic acids are the dominant feature of the Mycobacterium tuberculosis cell wall. These {alpha}-alkyl, {beta}-hydroxy fatty acids are formed by the condensation of two fatty acids, a long meromycolic acid and a shorter C{sub 24}-C{sub 26} fatty acid. The component fatty acids are produced via a combination of type I and II fatty acid synthases (FAS) with FAS-I products being elongated by FAS-II toward meromycolic acids. The {beta}-ketoacyl-acyl carrier protein (ACP) synthase III encoded by mtfabH (mtFabH) links FAS-I and FAS-II, catalyzing the condensation of FAS-I-derived acyl-CoAs with malonyl-acyl carrier protein (ACP). The acyl-CoA chain length specificity of mtFabH was assessed in vitro; the enzyme extended longer, physiologically relevant acyl-CoA primers when paired with AcpM, its natural partner, than with Escherichia coli ACP. The ability of the enzyme to use E. coli ACP suggests that a similar mode of binding is likely with both ACPs, yet it is clear that unique factors inherent to AcpM modulate the substrate specificity of mtFabH. Mutation of proposed key mtFabH residues was used to define their catalytic roles. Substitution of supposed acyl-CoA binding residues reduced transacylation, with double substitutions totally abrogating activity. Mutation of Arg{sup 46} revealed its more critical role in malonyl-AcpM decarboxylation than in the acyl-CoA binding role. Interestingly, this effect was suppressed intragenically by Arg{sup 161} {yields} Ala substitution. Our structural studies suggested that His{sup 258}, previously implicated in malonyl-ACP decarboxylation, also acts as an anchor point for a network of water molecules that we propose promotes deprotonation and transacylation of Cys{sup 122}.

  3. Structural and tectonic implications of pre-Mt. Simon strata -- or a lack of such -- in the western part of the Illinois basin

    SciTech Connect (OSTI)

    Sargent, M.L. (Illinois State Geological Survey, Champaign, IL (United States))

    1993-03-01

    The discovery of a pre-Mt. Simon lithic arenite (arkose) in southwestern Ohio has lead to reevaluation of many basement tests in the region. Several boreholes in adjacent states have been reexamined by others and are now believed to bottom in the Middle Run Formation. Seismic-reflection sections in western Ohio and Indiana have indicated pre-Mt. Simon basins filled with layered rocks that are interpreted to be Middle Run, however, the pre-Mt. Simon basins and east of Illinois. Samples from Illinois basement tests were reexamined to determine whether they had encountered similar strata. All reported crystalline-basement tests in Illinois show diagnostic igneous textures and mineralogical associations. Coarsely crystalline samples in cores show intergrown subhedral grains of quartz, microcline, and sodic plagioclase. Medium-crystalline rocks in cuttings samples show numerous examples of micrographic intergrowths of quartz and K-feldspar. This texture cannot be authigenically grown in a sediment and probably could not have survived a single cycle of erosion and deposition. Aphanitic rocks show porphyritic and spherulitic textures that are distinctly igneous and would be destroyed by weathering. Substantial relief on the Precambrian crystalline surface in Illinois is postulated for major structural features like the LaSalle Anticlinorium, the Sparta Shelf, the Ste. Genevieve Fault zone, etc. Paleotopographic relief up to 300 m (1,000 feet) is documented from drilling on the western flank of the basin.

  4. Electronic structure of Ce?RhIn?: A two-dimensional heavy-fermion system studied by angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Rui; Petrovic, C.; Mou, Daixing; Liu, Chang; Zhao, Xin; Yao, Yongxin; Ryu, Hyejin; Ho, Kai -Ming; Kaminski, Adam

    2015-04-01

    We use angle-resolved photoemission spectroscopy (ARPES) to study the 2D heavy fermion superconductor, Ce?RhIn?. The Fermi surface is rather complicated and consists of several hole and electron pockets with one of the sheets displaying strong nesting properties with a q-vector of (0.32, 0.32) ?/a. We do not observe kz dispersion of the Fermi sheets, which is consistent with the expected 2D character of the electronic structure. Comparison of the ARPES data to band structure calculations suggests that a localized picture of the f-electrons works best. While there is some agreement in the overall band dispersion and location of the Fermimore »sheets, the model does not reproduce all observed bands and is not completely accurate for those it does. Our data paves the way for improving the band structure calculations and the general understanding of the transport and thermodynamical properties of this material.« less

  5. Electronic structure of Ce2RhIn8: A two-dimensional heavy-fermion system studied by angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Rui; Mou, Daixing; Liu, Chang; Zhao, Xin; Yao, Yongxin; Ryu, Hyejin; Petrovic, C.; Ho, Kai -Ming; Kaminski, Adam

    2015-04-01

    We use angle-resolved photoemission spectroscopy (ARPES) to study the 2D heavy fermion superconductor, Ce?RhIn?. The Fermi surface is rather complicated and consists of several hole and electron pockets with one of the sheets displaying strong nesting properties with a q-vector of (0.32, 0.32) ?/a. We do not observe kz dispersion of the Fermi sheets, which is consistent with the expected 2D character of the electronic structure. Comparison of the ARPES data to band structure calculations suggests that a localized picture of the f-electrons works best. While there is some agreement in the overall band dispersion and location of the Fermimore »sheets, the model does not reproduce all observed bands and is not completely accurate for those it does. As a result, our data paves the way for improving the band structure calculations and the general understanding of the transport and thermodynamical properties of this material.« less

  6. Frying Doughnuts: What can the reprocessing of X-rays to IR tell us about the AGN environment?

    E-Print Network [OSTI]

    B. McKernan; K. E. S. Ford; N. Chang; C. S. Reynolds

    2008-12-04

    Active galactic nuclei (AGN) produce vast amounts of high energy radiation deep in their central engines. X-rays either escape the AGN or are absorbed and re-emitted mostly as IR. By studying the dispersion in the ratio of observed mid-IR luminosity to observed 2-10keV X-ray luminosity (R_{ir/x}) in AGN we can investigate the reprocessing material (possibly a torus or donut of dust) in the AGN central engine, independent of model assumptions. We studied the ratio of observed mid-IR and 2-10keV X-ray luminosities in a heterogeneous sample of 245 AGN from the literature. We found that when we removed AGN with prominent jets, ~90% of Type I AGN lay within a very tight dispersion in luminosity ratio (1ir/x}<30). This implies that the AGN central engine is extremely uniform and models of the physical AGN environment (e.g. cloud cover, turbulent disk, opening angle of absorbing structures such as dusty tori) must span a very narrow range of parameters. We also found that the far-IR(100um) to mid-IR (12um) observed luminosity ratio is an effective descriminator between heavily obscured AGN and relatively unobscured AGN.

  7. Spitzer-IRS Sectroscopy of the Prototype Wolf-Rayet star EZ CMa (HD 50896)

    E-Print Network [OSTI]

    P W Morris; P A Crowther; J R Houck

    2004-06-03

    We present mid-infrared Spitzer-IRS spectroscopy of the prototype WN star EZ CMa (HD50896, WN4b). Numerous stellar wind lines of HeII are revealed, plus fine-structure lines of [NeIII] 15.5um and [OIV] 25.9um. We carry out a spectroscopic analysis of HD50896 allowing for line blanketing and clumping, which is compared to the mid-IR observations. We make use of these stellar properties to accurately derive Ne/He=1.2-1.8E-4 and O/He=4.2-4.8E-5 by number, for the first time in an early WN star. In addition, we obtain N/C=40 and N/O=50 by number, values in perfect agreement with current predictions for rotating massive stars at the end of interior hydrogen burning.

  8. Probing the Invisible Universe: The Case for Far-IR/Submillimeter Interferometry

    E-Print Network [OSTI]

    D. Leisawitz; T. Armstrong; D. Benford; A. Blain; K. Borne W. Danchi; N. Evans; J. Gardner; D. Gezari; M. Harwit; A. Kashlinsky; W. Langer; C. Lawrence; P. Lawson; D. Lester; J. Mather; S. H. Moseley; L. Mundy; G. Rieke; S. Rinehart; M. Shao; R. Silverberg; D. Spergel; J. Staguhn; M. Swain; W. Traub; S. Unwin; E. Wright; H. Yorke

    2002-02-04

    The question "How did we get here and what will the future bring?" captures the human imagination and the attention of the National Academy of Science's Astronomy and Astrophysics Survey Commitee (AASC). Fulfillment of this "fundamental goal" requires astronomers to have sensitive, high angular and spectral resolution observations in the far-infrared/submillimeter (far-IR/sub-mm) spectral region. With half the luminosity of the universe and vital information about galaxy, star and planet formation, observations in this spectral region require capabilities similar to those currently available or planned at shorter wavelengths. In this paper we summarize the scientific motivation, some mission concepts and technology requirements for far-IR/sub-mm space interferometers that can be developed in the 2010-2020 timeframe.

  9. Curing the UV/IR mixing for field theories with translation-invariant star products

    SciTech Connect (OSTI)

    Tanasa, Adrian; Vitale, Patrizia

    2010-03-15

    The ultraviolet/infrared (UV/IR) mixing of noncommutative field theories has been recently shown to be a generic feature of translation-invariant associative products. In this paper we propose to take into account the quantum corrections of the model to modify in this way the noncommutative action. This idea was already used to cure the UV/IR mixing for theories on Moyal space. We show that in the present framework also, this proposal proves successful for curing the mixing. We achieve this task by explicit calculations of one and higher loops Feynman amplitudes. For the sake of completeness, we compute the form of the new action in the matrix base for the Wick-Voros product.

  10. Structurally Integrated Coatings for Wear and Corrosion (SICWC): Arc Lamp, InfraRed (IR) Thermal Processing

    SciTech Connect (OSTI)

    Mackiewicz-Ludtka, G.; Sebright, J.

    2007-12-15

    The primary goal of this Cooperative Research and Development Agreement (CRADA) betwe1311 UT-Battelle (Contractor) and Caterpillar Inc. (Participant) was to develop the plasma arc lamp (PAL), infrared (IR) thermal processing technology 1.) to enhance surface coating performance by improving the interfacial bond strength between selected coatings and substrates; and 2.) to extend this technology base for transitioning of the arc lamp processing to the industrial Participant. Completion of the following three key technical tasks (described below) was necessary in order to accomplish this goal. First, thermophysical property data sets were successfully determined for composite coatings applied to 1010 steel substrates, with a more limited data set successfully measured for free-standing coatings. These data are necessary for the computer modeling simulations and parametric studies to; A.) simulate PAL IR processing, facilitating the development of the initial processing parameters; and B.) help develop a better understanding of the basic PAL IR fusing process fundamentals, including predicting the influence of melt pool stirring and heat tnmsfar characteristics introduced during plasma arc lamp infrared (IR) processing; Second, a methodology and a set of procedures were successfully developed and the plasma arc lamp (PAL) power profiles were successfully mapped as a function of PAL power level for the ORNL PAL. The latter data also are necessary input for the computer model to accurately simulate PAL processing during process modeling simulations, and to facilitate a better understand of the fusing process fundamentals. Third, several computer modeling codes have been evaluated as to their capabilities and accuracy in being able to capture and simulate convective mixing that may occur during PAL thermal processing. The results from these evaluation efforts are summarized in this report. The intention of this project was to extend the technology base and provide for transitioning of the arc lamp processing to the industrial Participant.

  11. Practical Analysis of materials with depth varying compositions using FT-IR photoacoustic spectroscopy (PAS)

    SciTech Connect (OSTI)

    J.F. McClelland; R.W. Jones; Siquan Luo

    2004-09-30

    FT-IR photoacoustic spectroscopy (PAS) is discussed as a nondestructive method to probe the molecular composition of materials versus depth on the basis of the analysis of layers of experimentally controllable thickness, which are measured from the sample surface to depths of some tens of micrometers, depending on optical and thermal properties. Computational methods are described to process photoacoustic amplitude and phase spectra for both semi-quantitative and quantitative depth analyses. These methods are demonstrated on layered and gradient samples.

  12. Axion decay and anisotropy of near-IR extragalactic background light

    E-Print Network [OSTI]

    Yan Gong; Asantha Cooray; Ketron Mitchell-Wynne; Xuelei Chen; Michael Zemcov; Joseph Smidt

    2015-11-05

    The extragalactic background light is expected to be comprised of the cumulative radiation from all galaxies and active galactic nuclei over the cosmic history. In addition to point sources, EBL also contains information from diffuse sources of radiation. An example is the intra-halo light, associated with diffuse stars in dark matter halos resulting from galaxy mergers and tidal interactions, identified based on measurements involving the angular power spectrum of infrared background anisotropies. The angular power spectra of the near-infrared intensities could still contain additional signals and a complete understanding of the nature of the IR background is still lacking in the literature. Here we explore the constraints that can be placed on the decay products associated with particle decays, especially candidate dark matter models involving axions that trace dark matter halos of galaxies. Axions with a mass around a few eV will decay via two photons with wavelengths in the near-IR band, and will leave a signature in the IR background intensity power spectrum. Using recent power spectra measurements from the Hubble Space Telescope (HST) and Cosmic Infrared Background Experiment (CIBER), we find that the 0.6 to 1.6 micron power spectra can be explained with an axion mass of around 4 eV and a total axion abundance as a fractional energy density Omega_a~0.05. Such an abundance is comparable to the baryon density of the Universe. The absolute EBL intensity of axion decay photons is slightly below 1 nW m^-2 sr^-1 at near-IR wavelengths, roughly a factor of 10 to 20 below the total integrated light from galaxies. The suggested axion mass and abundance are not ruled out by existing cosmological observations.

  13. Light-Like Noncommutativity, Light-Front Quantization and New Light on UV/IR Mixing

    E-Print Network [OSTI]

    M. M. Sheikh-Jabbari; A. Tureanu

    2010-10-02

    We revisit the problem of quantizing field theories on noncommutative Moyal spacetime with \\emph{light-like} noncommutativity. To tackle the issues arising from noncommuting and hence nonlocal time, we argue that for this case light-front quantization procedure should be employed. In this appropriate quantization scheme we perform the non-planar loop analysis for the light-like noncommutative field theories. One of the important and peculiar features of light-front quantization is that the UV cutoff of the light-cone Hamiltonian manifests itself as an IR cutoff for the light-cone momentum, $p^+$. Due to this feature, the naive results of covariant quantization for the light-like case allude to the absence of the UV/IR mixing in the light-front quantization. However, by a careful analysis of non-planar loop integrals we show that this is not the case and the UV/IR mixing persists. In addition, we argue in favour of the perturbative unitarity of light-like noncommutative field theories in the light-front quantization scheme.

  14. NGC 7538 IRS. 1. Interaction of a polarized dust spiral and a molecular outflow

    SciTech Connect (OSTI)

    Wright, M. C. H.; Hull, Charles L. H. [Department of Astronomy, University of California, Berkeley, CA 94720 (United States); Pillai, Thushara [Max Planck Institut für Radioastronomie, Auf dem Hügel 69, D-53121 Bonn (Germany); Zhao, Jun-Hui [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Sandell, Göran, E-mail: jzhao@cfa.harvard.edu [SOFIA-USRA, NASA Ames Research Center, MS 232-12, Building N232, Room 146, PO Box 1, Moffett Field, CA 94035-0001 (United States)

    2014-12-01

    We present dust polarization and CO molecular line images of NGC 7538 IRS 1. We combined data from the Submillimeter Array, the Combined Array for Research in Millimeter-wave Astronomy, and the James Clerk Maxwell Telescope to make images with ?2.''5 resolution at 230 and 345 GHz. The images show a remarkable spiral pattern in both the dust polarization and molecular outflow. These data dramatically illustrate the interplay between a high infall rate onto IRS 1 and a powerful outflow disrupting the dense, clumpy medium surrounding the star. The images of the dust polarization and the CO outflow presented here provide observational evidence for the exchange of energy and angular momentum between the infall and the outflow. The spiral dust pattern, which rotates through over 180° from IRS 1, may be a clumpy filament wound up by conservation of angular momentum in the infalling material. The redshifted CO emission ridge traces the dust spiral closely through the MM dust cores, several of which may contain protostars. We propose that the CO maps the boundary layer where the outflow is ablating gas from the dense gas in the spiral.

  15. Emergent IR dual 2d CFTs in charged AdS5 black holes

    E-Print Network [OSTI]

    Jan de Boer; Maria Johnstone; M. M. Sheikh-Jabbari; Joan Simon

    2011-12-20

    We study the possible dynamical emergence of IR conformal invariance describing the low energy excitations of near-extremal R-charged global AdS5 black holes. We find interesting behavior especially when we tune parameters in such a way that the relevant extremal black holes have classically vanishing horizon area, i.e. no classical ground-state entropy, and when we combine the low energy limit with a large N limit of the dual gauge theory. We consider both near-BPS and non-BPS regimes and their near horizon limits, emphasize the differences between the local AdS3 throats emerging in either case, and discuss potential dual IR 2d CFTs for each case. We compare our results with the predictions obtained from the Kerr/CFT correspondence, and obtain a natural quantization for the central charge of the near-BPS emergent IR CFT which we interpret in terms of the open strings stretched between giant gravitons.

  16. FT-IR Study of CO2 Interaction with Na-rich Montmorillonite

    SciTech Connect (OSTI)

    Krukowski, Elizabeth G [ORNL; Goodman, Angela [National Energy Technology Laboratory (NETL); Rother, Gernot [ORNL; Ilton, Eugene [Pacific Northwest National Laboratory (PNNL); Guthrie, George [National Energy Technology Laboratory (NETL); Bodnar, Robert [Virginia Polytechnic Institute and State University

    2015-01-01

    Carbon capture, utilization and storage (CCUS) in saline reservoirs in sedimentary formations has the potential to reduce the impact of fossil fuel combustion on climate change by reducing CO2 emissions to the atmosphere and storing the CO2 in geologic formations in perpetuity. At pressure and temperature (PT) conditions relevant to CCUS, CO2 is less dense than the pre-existing brine in the formation, and the more buoyant CO2 will migrate to the top of the formation where it will be in contact with cap rock. Interactions between clay-rich shale cap rocks and CO2 are poorly understood at PT conditions appropriate for CCUS in saline formations. In this study, the interaction of CO2 with clay minerals in the cap rock overlying a saline formation has been examined using Na+ exchanged montmorillonite (Mt) (Na+-STx-1) (Na+ Mt) as an analog for clay-rich shale. Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR) was used to discern mechanistic information for CO2 interaction with hydrated (both one- and two-water layers) and relatively dehydrated (both dehydrated layers and one-water layers) Na+-STx-1 at 35 C and 50 C and CO2 pressure from 0 5.9 MPa. CO2-induced perturbations associated with the water layer and Na+-STx-1 vibrational modes such as AlAlOH and AlMgOH were examined. Data indicate that CO2 is preferentially incorporated into the interlayer space, with relatively dehydrated Na+-STx-1 capable of incorporating more CO2 compared to hydrated Na+-STx-1. Spectroscopic data provide no evidence of formation of carbonate minerals or the interaction of CO2 with sodium cations in the Na+-STx-1 structure.

  17. PECULIAR OPTICAL AND IR BEHAVIOUR IN TYPE I SUPERNOVAE, AND THE ORIGIN OF THE 1.2 ABSORPTION

    E-Print Network [OSTI]

    Graham, J.R.

    2011-01-01

    Wheeler, le. , 1984. In "Supernovae as distance indicators",lR. , 1985. In "Dust in supernovae and supernova remnants",and IR behaviour in type I supernovae, and the origin of the

  18. Littleton Mt. Washington

    E-Print Network [OSTI]

    Pringle, James "Jamie"

    · Across New Hampshire IN TRAVELING NEW HAMPSHIRE HIGHWAYS AND BACK ROADS, you'll discover New Hampshire, Keene Nashua Community College, Nashua BAE Systems of N.A., Nashua University of New Hampshire, Durham Great Bay Community College, Portsmouth New Hampshire Space grant Consortium 1 23 4 56 7 8 9 10 11 12 13

  19. versity (MT Assistant o

    E-Print Network [OSTI]

    discipline um vitae, s and contac electronica cmsearch@ 2011, an trategic Fac nitiative ates are en rsities

  20. Understanding the water emission in the mid- and far-IR from protoplanetary disks around T~Tauri stars

    E-Print Network [OSTI]

    Antonellini, S; Riviere-Marichalar, P; Meijerink, R; Woitke, P; Thi, W -F; Spaans, M; Aresu, G; Lee, G

    2015-01-01

    We investigate which properties of protoplanetary disks around T Tauri stars affect the physics and chemistry in the regions where mid- and far-IR water lines originate and their respective line fluxes. We search for diagnostics for future observations. With the code ProDiMo, we build a series of models exploring a large parameter space, computing rotational and rovibrational transitions of water in nonlocal thermodynamic equilibrium (non-LTE). We select a sample of transitions in the mid- IR regime and the fundamental ortho and para water transitions in the far-IR. We investigate the chemistry and the local physical conditions in the line emitting regions. We calculate Spitzer spectra for each model and compare far-IR and mid-IR lines. In addition, we use mid-IR colors to tie the water line predictions to the dust continuum. Parameters affecting the water line fluxes in disks by more than a factor of three are : the disk gas mass, the dust-to-gas mass ratio, the dust maximum grain size, ISM(InterStellarMediu...

  1. Transition from the infalling envelope to the Keplerian disk around L1551 IRS 5

    SciTech Connect (OSTI)

    Chou, Ti-Lin [Department of Physics, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 106, Taiwan (China); Takakuwa, Shigehisa; Yen, Hsi-Wei; Ohashi, Nagayoshi; Ho, Paul T. P., E-mail: tlchou@asiaa.sinica.edu.tw [Academia Sinica Institute of Astronomy and Astrophysics, P. O. Box 23-141, Taipei 10617, Taiwan (China)

    2014-11-20

    We present combined Submillimeter Array (SMA) +Atacama Submillimeter Telescope Experiment (ASTE) images of the Class I protobinary L1551 IRS 5 in the CS (J = 7-6) line, the submillimeter images of L1551 IRS 5 with the most complete spatial sampling ever achieved (0.''9-36''). The SMA image of L1551 IRS 5 in the 343 GHz dust-continuum emission is also presented, which shows an elongated feature along the northwest to southeast direction (?160 AU × 80 AU), perpendicular to the associated radio jets. The combined SMA+ASTE images show that the high-velocity (?1.5 km s{sup –1}) CS emission traces the structure of the dust component and shows a velocity gradient along the major axis, which is reproduced by a geometrically thin Keplerian-disk model with a central stellar mass of ?0.5 M {sub ?}. The low-velocity (?1.3 km s{sup –1}) CS emission shows an extended (?1000 AU) feature that exhibits slight south (blueshifted) to north (redshifted) emission offsets, which is modeled with a rotating and infalling envelope with a conserved angular momentum. The rotational motion of the envelope connects smoothly to the inner Keplerian rotation at a radius of ?64 AU. The infalling velocity of the envelope is ?three times lower than the free-fall velocity toward the central stellar mass of 0.5 M {sub ?}. These results demonstrate transition from the infalling envelope to the Keplerian disk, consistent with the latest theoretical studies of disk formation. We suggest that sizable (r ? 50-200 AU) Keplerian disks are already formed when the protostars are still deeply embedded in the envelopes.

  2. An Optical Offgas Sensor Network Incorporating a HG Cavity Ringdown Spectrometer and IR Diode Lasers

    SciTech Connect (OSTI)

    George P. Miller

    2007-12-30

    A multi-element cavity ringdown system was evaluated with the objective of developing an intelligent sensor network to be incorporated into the control systems for advanced coal combustion facilities. Using a combination of a YAG-pumped dye laser and a tunable NIR/IR laser a dual cavity was constructed and a labview program was developed to provide multi-channel, real-time data to permit the real-time monitoring of typical exhaust emission gases, (for example: CO{sub 2}, SO{sub 2}, and mercury) of concern to the next generation of coal-powered facilities.

  3. Observations of the 6 Centimeter Lines of OH in Evolved (OH/IR) Stars

    E-Print Network [OSTI]

    Vincent L. Fish; Laura K. Zschaechner; Loránt O. Sjouwerman; Ylva M. Pihlström; Mark J. Claussen

    2006-10-24

    Recent observational and theoretical advances have called into question traditional OH maser pumping models in evolved (OH/IR) stars. The detection of excited-state OH lines would provide additional constraints to discriminate amongst these theoretical models. In this Letter, we report on VLA observations of the 4750 MHz and 4765 MHz lines of OH toward 45 sources, mostly evolved stars. We detect 4765 MHz emission in the star forming regions Mon R2 and LDN 1084, but we do not detect excited-state emission in any evolved stars. The flux density and velocity of the 4765 MHz detection in Mon R2 suggests that a new flaring event has begun.

  4. Phase-matched generation of coherent soft and hard X-rays using IR lasers

    DOE Patents [OSTI]

    Popmintchev, Tenio V.; Chen, Ming-Chang; Bahabad, Alon; Murnane, Margaret M.; Kapteyn, Henry C.

    2013-06-11

    Phase-matched high-order harmonic generation of soft and hard X-rays is accomplished using infrared driving lasers in a high-pressure non-linear medium. The pressure of the non-linear medium is increased to multi-atmospheres and a mid-IR (or higher) laser device provides the driving pulse. Based on this scaling, also a general method for global optimization of the flux of phase-matched high-order harmonic generation at a desired wavelength is designed.

  5. Near-UV to near-IR disk-averaged Earth's spectra from Moon's Earthshine observations

    E-Print Network [OSTI]

    S. Hamdani; L. Arnold; C. Foellmi; J. Berthier; D. Briot; P. Francois; P. Riaud; J. Schneider

    2005-10-13

    We discuss a series of Earthshine spectra obtained with the NTT/EMMI instrument between 320nm and 1020nm with a resolution of R~450 in the blue and R~250 in the red. These ascending and descending Moon's Earthshine spectra taken from Chile give disk-averaged spectra for two different Earth's phases. The spectra show the ozone (Huggins and Chappuis bands), oxygen and water vapour absorption bands, and also the stronger Rayleigh scattering in the blue. Removing the known telluric absorptions reveals a spectral feature around 700nm which is attributed to the vegetation stronger reflectivity in the near-IR, so-called vegetation red-edge.

  6. Integrating Interactive Visualizations in the Search Process of Digital Libraries and IR Systems

    E-Print Network [OSTI]

    Hienert, Daniel; Schaer, Philipp; Mayr, Philipp

    2012-01-01

    Interactive visualizations for exploring and retrieval have not yet become an integral part of digital libraries and information retrieval systems. We have integrated a set of interactive graphics in a real world social science digital library. These visualizations support the exploration of search queries, results and authors, can filter search results, show trends in the database and can support the creation of new search queries. The use of weighted brushing supports the identification of related metadata for search facets. We discuss some use cases of the combination of IR systems and interactive graphics. In a user study we verify that users can gain insights from statistical graphics intuitively and can adopt interaction techniques.

  7. On-Line Weld NDE with IR Thermography | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills and ReduceNovemberDOE'sManagement ofOh,ofOn-Line Weld NDE with IR

  8. Axion decay and anisotropy of near-IR extragalactic background light

    E-Print Network [OSTI]

    Gong, Yan; Mitchell-Wynne, Ketron; Chen, Xuelei; Zemcov, Michael; Smidt, Joseph

    2015-01-01

    The extragalactic background light is expected to be comprised of the cumulative radiation from all galaxies and active galactic nuclei over the cosmic history. In addition to point sources, EBL also contains information from diffuse sources of radiation. An example is the intra-halo light, associated with diffuse stars in dark matter halos resulting from galaxy mergers and tidal interactions, identified based on measurements involving the angular power spectrum of infrared background anisotropies. The angular power spectra of the near-infrared intensities could still contain additional signals and a complete understanding of the nature of the IR background is still lacking in the literature. Here we explore the constraints that can be placed on the decay products associated with particle decays, especially candidate dark matter models involving axions that trace dark matter halos of galaxies. Axions with a mass around a few eV will decay via two photons with wavelengths in the near-IR band, and will leave a ...

  9. IRS Spectra of Debris Disks in the Scorpius-Centaurus OB Association

    E-Print Network [OSTI]

    Jang-Condell, Hannah; Manoj, P; Watson, Dan; Lisse, Carey M; Nesvold, Erika; Kuchner, Marc

    2015-01-01

    We analyze Spitzer/IRS spectra of 110 B-, A-, F-, and G-type stars with optically thin infrared excess in the Scorpius-Centaurus (ScoCen) OB association. The age of these stars ranges from 11-17 Myr. We fit the infrared excesses observed in these sources by Spitzer/IRS and Spitzer/MIPS to simple dust models according to Mie theory. We find that nearly all the objects in our study can be fit by one or two belts of dust. Dust around lower mass stars appears to be closer in than around higher mass stars, particularly for the warm dust component in the two-belt systems, suggesting mass-dependent evolution of debris disks around young stars. For those objects with stellar companions, all dust distances are consistent with trunction of the debris disk by the binary companion. The gaps between several of the two-belt systems can place limits on the planets that might lie between the belts, potentially constraining the mass and locations of planets that may be forming around these stars.

  10. Spatially Resolved Spitzer-IRS Spectral Maps of the Superwind in M82

    E-Print Network [OSTI]

    Beirão, P; Lehnert, M D; Guillard, P; Heckman, T; Draine, B; Hollenbach, D; Walter, F; Sheth, K; Smith, J D; Shopbell, P; Boulanger, F; Surace, J; Hoopes, C; Engelbracht, C

    2015-01-01

    We have mapped the superwind/halo region of the nearby starburst galaxy M82 in the mid-infrared with $Spitzer-IRS$. The spectral regions covered include the H$_2 S(1)-S(3)$, [NeII], [NeIII] emission lines and PAH features. We estimate the total warm H$_2$ mass and the kinetic energy of the outflowing warm molecular gas to be between $M_{warm}\\sim5-17\\times10^6$ M$_{\\odot}$ and $E_{K}\\sim6-20\\times10^{53}$ erg. Using the ratios of the 6.2, 7.7 and 11.3 micron PAH features in the IRS spectra, we are able to estimate the average size and ionization state of the small grains in the superwind. There are large variations in the PAH flux ratios throughout the outflow. The 11.3/7.7 and the 6.2/7.7 PAH ratios both vary by more than a factor of five across the wind region. The Northern part of the wind has a significant population of PAH's with smaller 6.2/7.7 ratios than either the starburst disk or the Southern wind, indicating that on average, PAH emitters are larger and more ionized. The warm molecular gas to PAH f...

  11. New algorithms and technologies for the un-supervised reduction of Optical/IR images

    E-Print Network [OSTI]

    Benoit Vandame

    2002-08-12

    This paper presents some of the main aspects of the software library that has been developed for the reduction of optical and infrared images, an integral part of the end-to-end survey system being built to support public imaging surveys at ESO. Some of the highlights of the new library are: unbiased estimates of the background, critical for deep IR observations; efficient and accurate astrometric solutions, using multi-resolution techniques; automatic identification and masking of satellite tracks; weighted co-addition of images; creation of optical/IR mosaics, and appropriate management of multi-chip instruments. These various elements have been integrated into a system using XML technology for setting input parameters, driving the various processes, producing comprehensive history logs and storing the results, binding them to the supporting database and to the web. The system has been extensively tested using deep images as well as images of crowded fields (e.g. globular clusters, LMC), processing at a rate of 0.5 Mega-pixels per second using a DS20E ALPHA computer with two processors. The goal of this presentation is to review some of the main features of this package.

  12. Sonic IR crack detection of aircraft turbine engine blades with multi-frequency ultrasound excitations

    SciTech Connect (OSTI)

    Zhang, Ding; Han, Xiaoyan; Newaz, Golam

    2014-02-18

    Effectively and accurately detecting cracks or defects in critical engine components, such as turbine engine blades, is very important for aircraft safety. Sonic Infrared (IR) Imaging is such a technology with great potential for these applications. This technology combines ultrasound excitation and IR imaging to identify cracks and flaws in targets. In general, failure of engine components, such as blades, begins with tiny cracks. Since the attenuation of the ultrasound wave propagation in turbine engine blades is small, the efficiency of crack detection in turbine engine blades can be quite high. The authors at Wayne State University have been developing the technology as a reliable tool for the future field use in aircraft engines and engine parts. One part of the development is to use finite element modeling to assist our understanding of effects of different parameters on crack heating while experimentally hard to achieve. The development has been focused with single frequency ultrasound excitation and some results have been presented in a previous conference. We are currently working on multi-frequency excitation models. The study will provide results and insights of the efficiency of different frequency excitation sources to foster the development of the technology for crack detection in aircraft engine components.

  13. Observation of a Large Magnetic Anisotropy in the New 2H-Perovskite Related Oxide Ba8CoRh6O21: Magnetic Measurements on Aligned Single Crystals

    E-Print Network [OSTI]

    zur Loye, Hans-Conrad

    Observation of a Large Magnetic Anisotropy in the New 2H-Perovskite Related Oxide Ba8CoRh6O21 of the A3n+3mAnB3m+nO9m+6n family of 2H hexagonal perovskite related oxides and contains chains consisting, perovskite and perovskite-related oxides in particular have long provided excellent candidates for structural

  14. Change in magnetic and structural properties of FeRh thin films by gold cluster ion beam irradiation with the energy of 1.67?MeV/atom

    SciTech Connect (OSTI)

    Koide, T.; Iwase, A. [Department of Materials Science, Osaka Prefecture University, Sakai, Osaka 599-8531 (Japan); Saitoh, Y. [Japan Atomic Energy Agency, Takasaki, Gunma 370-1292 (Japan); Sakamaki, M.; Amemiya, K. [High Energy Accelerator Research Organization, Tsukuba, Ibaraki 305-0801 (Japan); Matsui, T., E-mail: t-matsui@21c.osakafu-u.ac.jp [Research Organization for the 21st Century, Osaka Prefecture University Sakai, Osaka 599-8531 (Japan)

    2014-05-07

    The effect of energetic cluster ion beam irradiation on magnetic and structural properties of FeRh thin films have been investigated. The cluster ions used in the present studies consist of a few gold atoms with the energy of 1.67?MeV/gold atom. Saturation magnetization of the sample irradiated with Au3 cluster ion beam (280?emu/cc) is larger than that for the irradiated sample with Au1 ion beam (240?emu/cc) for the same irradiation ion fluence. These results can also be confirmed by the X-ray magnetic circular dichroism (XMCD) measurement; the XMCD signal for Au3 cluster ion irradiation is larger than that for Au1 ion irradiation. Since the ion beam irradiation induced magnetization of FeRh is significantly correlated with the amount of the lattice defects in the samples, cluster ion beam irradiation can be considered to effectively introduce the lattice defects in B2-type FeRh rather than the single ion beam. Consequently, cluster ion irradiation is better than single ion irradiation for the viewpoint of saturation magnetization, even if the same irradiation energy is deposited in the samples.

  15. Synthesis, structure and chemical bonding of CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x=0, 1.32, and 2) and SrCo{sub 2}Si{sub 2}

    SciTech Connect (OSTI)

    Hlukhyy, Viktor Hoffmann, Andrea V.; Fässler, Thomas F.

    2013-07-15

    The finding of superconductivity in Ba{sub 0.6}K{sub 0.4}Fe{sub 2}As{sub 2} put the attention on the investigation of compounds that crystallize with ThCr{sub 2}Si{sub 2} structure type such as AT{sub 2}X{sub 2} (A=alkali/alkaline earth/rare earth element; T=transition metal and X=element of the 13–15th group). In this context the silicides CaFe{sub 2}Si{sub 2}, CaFe{sub 0.68(6)}Rh{sub 1.32(6)}Si{sub 2}, CaRh{sub 2}Si{sub 2} and SrCo{sub 2}Si{sub 2} have been synthesized by reaction of the elements under an argon atmosphere. Single crystals were obtained by special heat treatment in welded niobium/tantalum ampoules. The compounds were investigated by means of powder and single crystal X-ray diffraction. All compounds crystallize in the ThCr{sub 2}Si{sub 2}-type structure with space group I4/mmm (No. 139): a=3.939(1) Å, c=10.185(1) Å, R{sub 1}=0.045, 85 F{sup 2} values, 8 variable parameters for CaFe{sub 2}Si{sub 2}; a=4.0590(2) Å, c=9.9390(8) Å, R{sub 1}=0.030, 90 F{sup 2} values, 10 variable parameters for CaFe{sub 0.68(6)}Rh{sub 1.32(6)}Si{sub 2}; a=4.0695(1) Å, c=9.9841(3) Å, R{sub 1}=0.031, 114 F{sup 2} values, 9 variable parameters for CaRh{sub 2}Si{sub 2}; and a=3.974(1) Å, c=10.395(1) Å, R{sub 1}=0.036, 95 F{sup 2} values, 8 variable parameters for SrCo{sub 2}Si{sub 2}. The structure of SrCo{sub 2}Si{sub 2} contains isolated [Co{sub 2}Si{sub 2}]{sup 2?} 2D-layers in the ab-plane whereas in CaFe{sub 2?x}Rh{sub x}Si{sub 2} the [T{sub 2}Si{sub 2}] layers (T=Fe and Rh) are interconnected along the c-axis via Si3Si bonds resulting in a three-dimentional (3D) [T{sub 2}Si{sub 2}]{sup 2?} polyanions and therefore belong to the so-called collapsed form of the ThCr{sub 2}Si{sub 2}-type structure. The SrCo{sub 2}Si{sub 2} and CaRh{sub 2}Si{sub 2} are isoelectronic to the parent 122 iron–pnictide superconductors AeFe{sub 2}As{sub 2} (Ae=alkaline earth elements), whereas CaFe{sub 2}Si{sub 2} is a full substituted variant (As/Si) of CaFe{sub 2}As{sub 2}. The crystal chemistry and chemical bonding in the title compounds are discussed in terms of LMTO band structure calculations and a topological analysis using the Electron Localization Function (ELF). - Graphical abstract: The SrCo{sub 2}Si{sub 2} and CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x==0, 1.32, and 2) crystallize in the ThCr{sub 2}Si{sub 2}-type. The structure of SrCo{sub 2}Si{sub 2} contains isolated [Co{sub 2}Si{sub 2}]{sup 2?} layers in the ab-plane, whereas the [T{sub 2}Si{sub 2}] layers in CaFe{sub 2?x}Rh{sub x}Si{sub 2} are interconnected along the c-axis via Si3Si bonds resulting in a [T{sub 2}Si{sub 2}]{sup 2?} network. - Highlights: • Synthesis and structure of ternary silicides SrCo{sub 2}Si{sub 2} and CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x=0, 1.32, and 2). • The SrCo{sub 2}Si{sub 2} and CaRh{sub 2}Si{sub 2} are isoelectronic to the parent 122 iron–pnictide superconductors AeFe{sub 2}As{sub 2}. • CaFe{sub 2}Si{sub 2} is a full substituted variant (As/Si) of superconductor CaFe{sub 2}As{sub 2}. • The title compounds demonstrate the tunable Si3Si distances.

  16. On the Relative Utility of Infrared (IR) versus Terahertz (THz) for Optical Sensors

    SciTech Connect (OSTI)

    Johnson, Timothy J.; Valentine, Nancy B.; Gassman, Paul L.; Atkinson, David A.; Sharpe, Steven W.; Williams, Stephen D.

    2007-11-30

    Pacific Northwest National Laboratory (PNNL) has active programs investigating the optical absorption strengths of several types of molecules including toxic industrial chemicals (TICs), microbiological threats such as bacteria, as well as explosives such as RDX, PETN and TNT. While most of our work has centered on the mid-infrared domain (600 to 6,500 cm-1), more recent work has also included work in the far-infrared, also called the terahertz (THz) region (500 to ~8 cm-1). Using Fourier transform infrared spectroscopy, we have been able to compare the relative, and in some cases absolute, IR/THz cross sections of a number of species in the solid and liquid phases. The relative band strengths of a number of species of interest are discussed in terms of both experimental and computational results.

  17. Far-UV to mid-IR properties of nearby radio galaxies

    E-Print Network [OSTI]

    de Ruiter, Hans R; Fanti, Roberto; Fanti, Carla

    2015-01-01

    We investigate whether the far-UV continuum of nearby radio galaxies reveals evidence for the presence of star forming or non-stellar components. If a UV excess due to an extra radiation component exists we compare this with other properties such as radio power, optical spectral type and the strength of the emission lines. We also discuss the possible correlation between the ultra-violet flux, IR properties and central black hole mass. We use two sampes of low luminosity radio galaxies with comparable redshifts ($z measures the excess slope of the UV continuum between 4500 and 2000 \\AA, with respect to the UV radiation produced by the underlying old galaxy component. We find that the UV excess is usually small or absent in low luminosity sources, but sets in abruptly at the transition radio power above which we find mostly FRII sources. $XUV$ beh...

  18. Spitzer IRS Spectra and Envelope Models of Class I Protostars in Taurus

    E-Print Network [OSTI]

    E. Furlan; M. McClure; N. Calvet; L. Hartmann; P. D'Alessio; W. J. Forrest; D. M. Watson; K. I. Uchida; B. Sargent; J. D. Green; T. L. Herter

    2007-11-26

    We present Spitzer Infrared Spectrograph spectra of 28 Class I protostars in the Taurus star-forming region. The 5 to 36 micron spectra reveal excess emission from the inner regions of the envelope and accretion disk surrounding these predecessors of low-mass stars, as well as absorption features due to silicates and ices. Together with shorter- and longer-wavelength data from the literature, we construct spectral energy distributions and fit envelope models to 22 protostars of our sample, most of which are well-constrained due to the availability of the IRS spectra. We infer that the envelopes of the Class I objects in our sample cover a wide range in parameter space, particularly in density and centrifugal radius, implying different initial conditions for the collapse of protostellar cores.

  19. High-resolution IR absorption spectroscopy of polycyclic aromatic hydrocarbons: the realm of anharmonicity

    E-Print Network [OSTI]

    Maltseva, Elena; Candian, Alessandra; Mackie, Cameron J; Huang, Xinchuan; Lee, Timothy J; Tielens, Alexander G G M; Oomens, Jos; Buma, Wybren Jan

    2015-01-01

    We report on an experimental and theoretical investigation of the importance of anharmonicity in the 3 micron CH stretching region of Polycyclic Aromatic Hydrocarbon (PAH) molecules. We present mass-resolved, high-resolution spectra of the gas-phase cold (~4K) linear PAH molecules naphthalene, anthracene, and tetracene. The measured IR spectra show a surprisingly high number of strong vibrational bands. For naphthalene, the observed bands are well separated and limited by the rotational contour, revealing the band symmetries. Comparisons are made to the harmonic and anharmonic approaches of the widely used Gaussian software. We also present calculated spectra of these acenes using the computational program SPECTRO, providing anharmonic predictions enhanced with a Fermi-resonance treatment that utilises intensity redistribution. We demonstrate that the anharmonicity of the investigated acenes is strong, dominated by Fermi resonances between the fundamental and double combination modes, with triple combination ...

  20. Water Absorption from Gas Very Near the Massive Protostar AFGL 2136 IRS 1

    E-Print Network [OSTI]

    Indriolo, Nick; Seifahrt, A; Richter, M J

    2013-01-01

    We present ground-based observations of the nu_1 and nu_3 fundamental bands of H2O toward the massive protostar AFGL 2136 IRS 1, identifying absorption features due to 47 different ro-vibrational transitions between 2.468 micron and 2.561 micron. Analysis of these features indicates the absorption arises in warm (T=506+-25 K), very dense (n(H2)>5*10^9 cm^-3) gas, suggesting an origin close to the central protostar. The total column density of warm water is estimated to be N(H2O)=(1.02+-0.02)*10^19 cm^-2, giving a relative abundance of N(H2O)/N(H2)~10^-4. Our study represents the first extensive use of water vapor absorption lines in the near infrared, and demonstrates the utility of such observations in deriving physical parameters.

  1. Graphene-silicon layered structures on single-crystalline Ir(111) thin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Que, Yande D.; Tao, Jing; Zhang, Yong; Wang, Yeliang L.; Wu, Lijun J.; Zhu, Yimei M.; Kim, Kisslinger; Weinl, Michael; Schreck, Matthias; Shen, Chengmin M.; et al

    2015-01-20

    Epitaxial growth of graphene on transition metal crystals, such as Ru,?¹?³? Ir,????? and Ni,??? provides large-area, uniform graphene layers with controllable defect density, which is crucial for practical applications in future devices. To decrease the high cost of single-crystalline metal bulks, single-crystalline metal films are strongly suggested as the substrates for epitaxial growth large-scale high-quality graphene.???¹?? Moreover, in order to weaken the interactions of graphene with its metal host, which may result in a suppression of the intrinsic properties of graphene,?¹¹ ¹²? the method of element intercalation of semiconductors at the interface between an epitaxial graphene layer and a transitionmore »metal substrate has been successfully realized.?¹³?¹??« less

  2. Neutronic safety and transient analyses for potential LEU conversion of the IR-8 research reactor.

    SciTech Connect (OSTI)

    Deen, J. R.; Hanan, N. A.; Smith, R. S.; Matos, J. E.; Egorenkov, P. M.; Nasonov, V. A.

    1999-09-27

    Kinetic parameters, isothermal reactivity feedback coefficients and three transients for the IR-8 research reactor cores loaded with either HEU(90%), HEU(36%), or LEU (19.75%) fuel assemblies (FA) were calculated using three dimensional diffusion theory flux solutions, RELAP5/MOD3.2 and PARET. The prompt neutron generation time and effective delayed neutron fractions were calculated for fresh and beginning-of-equilibrium-cycle cores. Isothermal reactivity feedback coefficients were calculated for changes in coolant density, coolant temperature and fuel temperature in fresh and equilibrium cores. These kinetic parameters and reactivity coefficients were used in transient analysis models to predict power histories, and peak fuel, clad and coolant temperatures. The transients modeled were a rapid and slow loss-of-flow, a slow reactivity insertion, and a fast reactivity insertion.

  3. Effect of Field Errors in Muon Collider IR Magnets on Beam Dynamics

    SciTech Connect (OSTI)

    Alexahin, Y.; Gianfelice-Wendt, E.; Kapin, V.V.; /Fermilab

    2012-05-01

    In order to achieve peak luminosity of a Muon Collider (MC) in the 10{sup 35} cm{sup -2}s{sup -1} range very small values of beta-function at the interaction point (IP) are necessary ({beta}* {le} 1 cm) while the distance from IP to the first quadrupole can not be made shorter than {approx}6 m as dictated by the necessity of detector protection from backgrounds. In the result the beta-function at the final focus quadrupoles can reach 100 km making beam dynamics very sensitive to all kind of errors. In the present report we consider the effects on momentum acceptance and dynamic aperture of multipole field errors in the body of IR dipoles as well as of fringe-fields in both dipoles and quadrupoles in the ase of 1.5 TeV (c.o.m.) MC. Analysis shows these effects to be strong but correctable with dedicated multipole correctors.

  4. Regular "Breathing" of Single-Cycle Light Bullets in Mid-IR Filament

    E-Print Network [OSTI]

    Chekalin, S V; Kuznetzov, A V; Dormidonov, A E; Shlenov, S A; Kandidov, V P

    2015-01-01

    Experimental and numerical studies of a temporal evolution of a light bullet formed in isotropic LiF by Mid IR femtosecond pulse (2500 to 3250 nm) of power, slightly exceeding the critical power for self-focusing, are presented. For the first time regular oscillations of the light bullet intensity during its propagation in a filament were registered by investigation of induced color centers in LiF. It was revealed that color centers in a single laser pulse filament have a strictly periodic structure with a length of separate sections about 30 mcm, which increases with a laser pulse wavelength decreasing. It was shown that the origin of light bullet modulation is a periodical change of the light field amplitude of an extremely compressed single cycle wave packet in a filament, due to the difference of the wave packet group velocity and the carrier wave phase velocity.

  5. Express quality analysis of coal concentrates by diffuse reflection IR spectroscopy

    SciTech Connect (OSTI)

    V.N. Egorov; I.I. Mel'nikov; N.A. Tarasov; V.I. Butakova; Y.M. Posokhov [ZAO RMK (Russian Federation)

    2007-07-01

    Ongoing quality monitoring of coal concentrates is important today on account of instability in the raw materials for coking at OAO Magnitogorskii Metallurgicheskii Kombinat (MMK) and the variable composition of the coal batch for enrichment plants. Currently, numerous standardized methods permit the determination of the classificational and quality characteristics of coal and batch. These methods are slow, laborious, and relatively ineffective in industrial conditions. In May 2005, an automated Spektrotest express-analysis system developed by ECCI was installed in the coke laboratory at ZAO RMK in order to determine the quality of the coal concentrate and batch. The basic equipment is an IR spectrometer with a unit for Fourier transformation and a special optical module yielding the reflect on spectra of the pulverized coal. A control station based on a high-speed computer runs an algorithm for information analysis and storage and for printing out the test protocol. The Spektrotest system includes complex algorithms and software specially developed at ECCI.

  6. Interaction of mineral surfaces with simple organci molecules by diffuse reflectance IR spectroscopy (DRIFT)

    SciTech Connect (OSTI)

    Joan Thomas; Michael Kelley

    2007-06-18

    Diffuse reflectance Fourier-transform infrared spectroscopy (DRIFTS) was used to characterize multi-layers of lysine, glutamic acid and salicylic acid on ?-alumina and kaolinite surfaces. The results agreed well with those previously obtained by ATR-IR in aqueous media where available, indicating that DRIFT may be regarded as effectively an in-situ spectroscopy for these materials. In the case of salicylic acid adsorption onto ?-alumina, DRIFTS was used to identify monolayer coverage and to detect molecules down to coverage of 3% of a monolayer. The spectroscopic results as to coverage were confirmed by analysis of the solutions used for treatment. The spectra obtained allowed identification of changes in the bonding environment with increasing surface coverage. DRIFTS, offers several advantages in terms of materials, experimental technique and data treatment, motivating further investigations.

  7. In Situ Diffuse Reflectance IR Spectroscopy and X-ray Absorption Spectroscopy for Fast Catalytic Processes

    SciTech Connect (OSTI)

    N Marinkovic; Q Wang; A Frenkel

    2011-12-31

    A new instrument for synchronous in situ investigations of catalytic materials by IR and X-ray absorption spectroscopies was designed and built at the X18A beamline of the National Synchrotron Light Source of Brookhaven National Laboratory. It provides analytical tools for solving structural, electronic and kinetic problems in catalysis science by two complementary methods. Among the features attractive for catalysis research are the broad range of catalytically active elements that can be investigated (starting with Ni and beyond), the wide range of reaction conditions (temperatures up to 873 K, various reactive gases) and time scales (starting from tens of seconds). The results of several representative experiments that illustrate the attractive capabilities of the new set-up are discussed.

  8. High Hydrogen Concentrations Detected In The Underground Vaults For RH-TRU Waste At INEEL Compared With Calculated Values Using The INEEL-Developed Computer Code

    SciTech Connect (OSTI)

    Rajiv Bhatt; Soli Khericha

    2005-02-01

    About 700 remote-handled transuranic (RH-TRU) waste drums are stored in about 144 underground vaults at the Intermediate-Level Transuranic Storage Facility at the Idaho National Environmental and Engineering Laboratory’s (INEEL’s) Radioactive Waste Management Complex (RWMC). These drums were shipped to the INEEL from 1976 through 1996. During recent monitoring, concentrations of hydrogen were found to be in excess of lower explosive limits. The hydrogen concentration in one vault was detected to be as high as 18% (by volume). This condition required evaluation of the safety basis for the facility. The INEEL has developed a computer program to estimate the hydrogen gas generation as a function of time and diffusion through a series of layers (volumes), with a maximum five layers plus a sink/environment. The program solves the first-order diffusion equations as a function of time. The current version of the code is more flexible in terms of user input. The program allows the user to estimate hydrogen concentrations in the different layers of a configuration and then change the configuration after a given time; e.g.; installation of a filter on an unvented drum or placed in a vault or in a shipping cask. The code has been used to predict vault concentrations and to identify potential problems during retrieval and aboveground storage. The code has generally predicted higher hydrogen concentrations than the measured values, particularly for the drums older than 20 year, which could be due to uncertainty and conservative assumptions in drum age, heat generation rate, hydrogen generation rate, Geff, and diffusion rates through the layers.

  9. Conceptual design study of Nb3Sn low-beta quadrupoles for 2nd generation LHC IRs

    SciTech Connect (OSTI)

    Alexander V Zlobin et al.

    2002-10-22

    Conceptual designs of 90-mm aperture high-gradient quadrupoles based on the Nb{sub 3}Sn superconductor, are being developed at Fermilab for possible 2nd generation IRs with the similar optics as in the current low-beta insertions. Magnet designs and results of magnetic, mechanical, thermal and quench protection analysis for these magnets are presented and discussed.

  10. Review of exposure limits and experimental data for corneal and lenticular damage from short pulsed UV and IR laser radiation

    E-Print Network [OSTI]

    at the international level by ICNIRP the International Commission on Non-Ionizing Radiation Protection.1,2 Other Commission on Non-Ionizing Radiation Protection are compared to relevant experimental animal injury data UV and IR laser radiation Karl Schulmeistera Austrian Research Centers, A-2444 Seibersdorf, Austria

  11. On-chip methane sensing by near-IR absorption signatures in a photonic crystal slot waveguide

    E-Print Network [OSTI]

    Chen, Ray

    On-chip methane sensing by near-IR absorption signatures in a photonic crystal slot waveguide Wei­Lambert law for the detection of methane gas. The device combines slow light in a PC waveguide with high absorption path length. A methane concentration of 100 ppm (parts per million) in nitrogen was measured

  12. Transposing Molecular Fluorescent Switches into the Near-IR: Development of Luminogenic Reporter Substrates for Redox Metabolism

    E-Print Network [OSTI]

    Turro, Nicholas J.

    Transposing Molecular Fluorescent Switches into the Near-IR: Development of Luminogenic Reporter communicate the development of a NIR luminescent redox switch, based on a Nd(III) complex, that serves to afford a good luminescent switch.9 Since the sensitization of lanthanide metals is assumed to occur via

  13. Photometric and Near-IR Spectroscopic Observations of a D-type Asteroid, 773 Irmintraud, by SUBARU / IRCS

    E-Print Network [OSTI]

    Hiroi, Takahiro

    / IRCS A. Kanno (Univ. of Tokyo), T. Hiroi (Brown Univ.), R. Nakamura(NASDA), M. Abe(ISAS), M. Ishiguro-IR photometric and spectroscopic observations of 773 Irmintraud by SUBARU/IRCS on February 23rd, 2002 (UT). We to the lightcurve and the rotation period, we calibrated the data taken with SUBARU/IRCS by removing the effect

  14. Crystalline ZnMgSe:Cr2+: a new material for active elements of tunable IR-lasers

    E-Print Network [OSTI]

    Yu. A. Zagoruiko; N. O. Kovalenko; O. A. Fedorenko; V. A. Khristyan

    2008-07-01

    Obtained is a new thermostable material for active elements of tunable IR-lasers - Zn1-xMgxSe:Cr2+ single crystals. The position of the absorption band of Cr2+ ions in wurtzite-type Zn0.8Mg0.2Se matrix is established.

  15. Electrophoresis 1997, IR, 1259-1313 Predicted versus observed E. c d i proteins 1259 Andrew J. Link'*

    E-Print Network [OSTI]

    Church, George M.

    Electrophoresis 1997, IR, 1259-1313 Predicted versus observed E. c d i proteins 1259 Andrew J. Link Medical School, Boston, MA, USA Comparing the predicted and observed properties of proteins encoded proteins for their mature N-termini, in vivo abundances, isoelectric points, molecular masses, and cellular

  16. Hydrogen Bond Lifetimes and Energetics for Solute/Solvent Complexes Studied with 2D-IR Vibrational Echo Spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Lifetimes and Energetics for Solute/Solvent Complexes Studied with 2D-IR Vibrational@stanford.edu Abstract: Weak hydrogen-bonded solute/solvent complexes are studied with ultrafast two the dissociation and formation rates of the hydrogen-bonded complexes. The dissociation rates of the weak hydrogen

  17. Solute-Solvent Complex Kinetics and Thermodynamics Probed by 2D-IR Vibrational Echo Chemical Exchange Spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Solute-Solvent Complex Kinetics and Thermodynamics Probed by 2D-IR Vibrational Echo Chemical, 2008 The formation and dissociation kinetics of a series of triethylsilanol/solvent weakly hydrogen with previous observations on eight phenol/solvent complexes with enthalpies of formation from -0.6 to -2.5 kcal

  18. IR laser ablative desulfurization of poly(1,4-phenylene sulfide) Sardar M.A. Durani a

    E-Print Network [OSTI]

    Masoudi, Husain M.

    IR laser ablative desulfurization of poly(1,4-phenylene sulfide) Sardar M.A. Durani a , Ehsan E,* a Center for Applied Physical Sciences, Research Institute, King Fahd University of Petroleum and Minerals similar to those in PPS. The PLAD of PPS thus represents a unique example of the desulfurization of S

  19. Ultrafast UV Pump/IR Probe Studies of C-H Activation in Linear, Cyclic, and Aryl Hydrocarbons

    E-Print Network [OSTI]

    Harris, Charles B.

    Ultrafast UV Pump/IR Probe Studies of C-H Activation in Linear, Cyclic, and Aryl Hydrocarbons, cyclic, and aromatic hydrocarbon solvents on a femtosecond to microsecond time scale. These results have revealed that the structure of the hydrocarbon substrate affects the final C-H bond activation step, which

  20. Quantifying Uncertainty in Chemical Systems Modeling M.T. Reagan1, H.N. Najm1, P.P. Pebay1, O.M. Knio2 and R.G. Ghanem2

    E-Print Network [OSTI]

    Frey, Pascal

    Quantifying Uncertainty in Chemical Systems Modeling M.T. Reagan1, H.N. Najm1, P.P. P´ebay1, O The Johns Hopkins University, Baltimore, MD 21218, USA Abstract. This study compares two techniques of Chemical Kinetics 1. Introduction Chemical kinetics computations require the specification of a number

  1. A new A&P Food Market in Mt. Kisco, New York, is enjoying annual energy cost savings of nearly $130,000 with the installation of an integrated microturbine power system

    E-Print Network [OSTI]

    Pennycook, Steve

    Background A new A&P Food Market in Mt. Kisco, New York, is enjoying annual energy cost savings, heating and power solutions, was installed in 2005 in the 57,000- square-foot facility. The New York supermarket was the first U.S. customer to take delivery of the new system. The PureComfort system is designed

  2. Visualizing the Surface Infrastructure Used to Move 2 MtCO2/year from the Dakota Gasification Company to the Weyburn CO2 Enhanced Oil Recovery Project: Version of July 1, 2009

    SciTech Connect (OSTI)

    Dooley, James J.

    2009-07-09

    Google Earth Pro has been employed to create an interactive flyover of the world’s largest operational carbon dioxide capture and storage project. The visualization focuses on the transport and storage of 2 MtCO2/year which is captured from the Dakota Gasification Facility (Beula, North Dakota) and transported 205 miles and injected into the Weyburn oil field in Southeastern Saskatchewan.

  3. Comparison of junction temperature evaluations in a power IGBT module using an IR camera and three thermo-sensitive electrical parameters

    E-Print Network [OSTI]

    and electrical methods. The main optical methods are local infrared sensors [3,4], optical fibers [5], infraredComparison of junction temperature evaluations in a power IGBT module using an IR camera and three information of the actual chip temperature distribution. In this paper, we propose to use infrared (IR

  4. Zelftest chemie voor 1 Ba Bio-ir, Chemie, Fysica en sterrenkunde Voor meer informatie: contacteer csb.etterbeek@vub.ac.be

    E-Print Network [OSTI]

    Einmahl, Uwe

    Zelftest chemie voor 1 Ba Bio-ir, Chemie, Fysica en sterrenkunde Voor meer informatie: contacteer opgenomen in het bijhorend overzicht van de verwachte voorkennis chemie. 1. Elementaire chemie en chemisch, whisky, fruitsap met pulp, keukenzout #12;Zelftest chemie voor 1 Ba Bio-ir, Chemie, Fysica en

  5. PHYSICAL REVIEW B 88, 144102 (2013) Mechanism of the CaIrO3 post-perovskite phase transition under pressure

    E-Print Network [OSTI]

    Henkelman, Graeme

    2013-01-01

    PHYSICAL REVIEW B 88, 144102 (2013) Mechanism of the CaIrO3 post-perovskite phase transition under that the perovskite to post-perovskite phase transformation in CaIrO3 occurs more readily at room temperature when mantle, MgSiO3 perovskite (Pv), was recently found to transform into a post-perovskite (pPv) structure

  6. Symmetry Analysis for Tetrahedrane Tetrahedrane, C4H4, belongs to the Td point group. Use group theory to predict the number of IR and Raman

    E-Print Network [OSTI]

    Rioux, Frank

    Symmetry Analysis for Tetrahedrane Tetrahedrane, C4H4, belongs to the Td point group. Use group have three IR active modes (3T2) and seven Raman active modes (2A1 + 2E + 3T2). Two of the IR modes

  7. SCATTERING POLARIZATION OF THE Ca II IR TRIPLET FOR PROBING THE QUIET SOLAR CHROMOSPHERE

    SciTech Connect (OSTI)

    Manso Sainz, R.; Trujillo Bueno, J., E-mail: rsainz@iac.e, E-mail: jtb@iac.e [Instituto de Astrofisica de Canarias, E-38205 La Laguna, Tenerife (Spain)

    2010-10-20

    The chromosphere of the quiet Sun is a very important stellar atmospheric region whose thermal and magnetic structure we need to decipher in order to unlock new discoveries in solar and stellar physics. To this end, we need to identify and exploit observables sensitive to weak magnetic fields (B {approx}< 100 G) and to the presence of cool and hot gas in the bulk of the solar chromosphere. Here, we report on an investigation of the Hanle effect in two semi-empirical models of the quiet solar atmosphere with different chromospheric thermal structures. Our study reveals that the linear polarization profiles produced by scattering in the Ca II IR triplet have thermal and magnetic sensitivities potentially of great diagnostic value. The linear polarization in the 8498 A line shows a strong sensitivity to inclined magnetic fields with strengths between 0.001 and 10 G, while the emergent linear polarization in the 8542 A and 8662 A lines is mainly sensitive to magnetic fields with strengths between 0.001 and 0.1 G. The reason for this is that the scattering polarization of the 8542 A and 8662 A lines, unlike the 8498 A line, is controlled mainly by the Hanle effect in their (metastable) lower levels. Therefore, in regions with magnetic strengths noticeably larger than 1 G, their Stokes Q and U profiles are sensitive only to the orientation of the magnetic field vector. We also find that for given magnetic field configurations the sign of the Q/I and U/I profiles of the 8542 A and 8662 A lines is the same in both atmospheric models, while the sign of the linear polarization profile of the 8498 A line turns out to be very sensitive to the thermal structure of the lower chromosphere. We suggest that spectropolarimetric observations providing information on the relative scattering polarization amplitudes of the Ca II IR triplet will be very useful to improve our empirical understanding of the thermal and magnetic structure of the quiet chromosphere.

  8. Molecular gas and star formation towards the IR dust bubble S24 and its environs

    E-Print Network [OSTI]

    Cappa, C E; Firpo, V; Vasquez, J; López-Caraballo, C H; Rubio, M; Vazzano, M M

    2015-01-01

    We present a multi-wavelength analysis of the infrared dust bubble S24, and its environs, with the aim of investigating the characteristics of the molecular gas and the interstellar dust linked to them, and analyzing the evolutionary status of the young stellar objects (YSOs) identified there. Using APEX data, we mapped the molecular emission in the CO(2-1), $^{13}$CO(2-1), C$^{18}$O(2-1), and $^{13}$CO(3-2) lines in a region of about 5'x 5' in size around the bubble. The cold dust distribution was analyzed using ATLASGAL and Herschel images. Complementary IR and radio data were also used.The molecular gas linked to the S24 bubble, G341.220-0.213, and G341.217-0.237 has velocities between -48.0 km sec$^{-1}$ and -40.0 km sec$^{-1}$. The gas distribution reveals a shell-like molecular structure of $\\sim$0.8 pc in radius bordering the bubble. A cold dust counterpart of the shell is detected in the LABOCA and Herschel images.The presence of extended emission at 24 $\\mu$m and radio continuum emission inside the b...

  9. Wrinkles of graphene on Ir(111): Macroscopic network ordering and internal multi-lobed structure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Petrovic, Marin; Sadowski, Jerzy T.; Siber, Antonio; Kralj, Marko

    2015-07-17

    The large-scale production of graphene monolayer greatly relies on epitaxial samples which often display stress-relaxation features in the form of wrinkles. Wrinkles of graphene on Ir(111) are found to exhibit a fairly well ordered interconnecting network which is characterized by low-energy electron microscopy (LEEM). The high degree of quasi-hexagonal network arrangement for the graphene aligned to the underlying substrate can be well described as a (non-Poissonian) Voronoi partition of a plane. The results obtained strongly suggest that the wrinkle network is frustrated at low temperatures, retaining the order inherited from elevated temperatures when the wrinkles interconnect in junctions which mostmore »often join three wrinkles. Such frustration favors the formation of multi-lobed wrinkles which are found in scanning tunneling microscopy (STM) measurements. The existence of multiple lobes is explained within a model accounting for the interplay of the van der Waals attraction between graphene and iridium and bending energy of the wrinkle. The presented study provides new insights into wrinkling of epitaxial graphene and can be exploited to further expedite its application.« less

  10. ARCONS: A highly multiplexed superconducting optical to near-IR camera

    E-Print Network [OSTI]

    Mazin, Benjamin A; McHugh, Sean; Bumble, Bruce; Moore, David; Golwala, Sunil; Zmuidzinas, Jonas

    2010-01-01

    We report on the development of ARCONS, the ARray Camera for Optical to Near-IR Spectrophotometry. This photon counting integral field unit (IFU), being built at UCSB and Caltech with detectors fabricated at JPL, will use a unique, highly multiplexed low temperature detector technology known as Microwave Kinetic Inductance Detectors (MKIDs). These detectors, which operate at 100 mK, should provide photon counting with energy resolution of R = E/{\\delta}E > 20 and time resolution of a microsecond, with a quantum efficiency of around 50%. We expect to field the instrument at the Palomar 200" telescope in the first quarter of 2011 with an array containing 1024 pixels in a 32x32 pixel form factor to yield a field of view of approximately 10x10 arcseconds. The bandwidth of the camera is limited by the rising sky count rate at longer wavelengths, but we anticipate a bandwidth of 0.35 to 1.35 {\\mu}m will be achievable. A simple optical path and compact dewar utilizing a cryogen-free adiabatic demagnetization refridg...

  11. IPHAS A-type Stars with Mid-IR Excesses in Spitzer Surveys

    E-Print Network [OSTI]

    Hales, Antonio S; Drew, Janet E; Unruh, Yvonne C; Greimel, Robert; Irwin, Michael J; Gonzalez-Solares, Eduardo

    2009-01-01

    We have identified 17 A-type stars in the Galactic Plane that have mid-IR excesses at 8 micron. From the observed colors in the (r'-H_alpha)-(r'-i') plane, we first identified 23050 early A-type main sequence (MS) star candidates in the Isaac Newton Photometric H-Alpha Survey (IPHAS) point source database that are located in Spitzer GLIMPSE Galactic Plane fields. Imposing the requirement that they be detected in all seven 2MASS and IRAC bands led to a sample of 2692 candidate A-type stars with fully sampled 0.6 to 8 micron SEDs. Optical classification spectra of 18 of the IPHAS candidate A-type MS stars showed that all but one could be well fitted using main sequence A-type templates, with the other being an A-type supergiant. Out of the 2692 A-type candidates 17 (0.6%) were found to have 8-micron excesses above the expected photospheric values. Taking into account non-A-Type contamination estimates, the 8-micron excess fraction is adjusted to ~0.7%. The distances to these sources range from 0.7-2.5 kpc. Only...

  12. SIZE AND TEMPERATURE DEPENDENCE IN THE FAR-IR SPECTRA OF WATER ICE PARTICLES

    SciTech Connect (OSTI)

    Medcraft, Chris; McNaughton, Don; Thompson, Chris D. [School of Chemistry, Monash University, Wellington Road, Clayton, Victoria 3800 (Australia); Appadoo, Dominique [Australian Synchrotron, Blackburn Road, Clayton, Victoria 3168 (Australia); Bauerecker, Sigurd [Institut fuer Physikalische und Theoretische Chemie, Technische Universitaet Braunschweig, Hans-Sommer-Strasse 10, D-38106 Braunschweig (Germany); Robertson, Evan G., E-mail: E.Robertson@latrobe.edu.au [Department of Chemistry and La Trobe Institute of Molecular Sciences, La Trobe University, Bundoora, Victoria 3086 (Australia)

    2012-10-10

    Spectra of water-ice aerosol particles have been measured in the far-IR region using synchrotron radiation. The particles in the nanoscale size regime of 1-100 nm were formed by rapid collisional cooling at temperatures ranging from 4 to 190 K. The spectra show the characteristic bands centered near 44 {mu}m (230 cm{sup -1}) and 62 {mu}m (160 cm{sup -1}) associated with the intermolecular lattice modes of crystalline ice at all temperatures, in contrast to previous studies of thin films formed by vapor deposition where amorphous ice is generated below 140 K. The bands shift to higher wavenumber values as the temperature is reduced, consistent with the trend seen in earlier studies, but in our experiments the actual peak positions in the aerosol particle spectra are consistently higher by ca. 4 cm{sup -1}. This finding has implications for the potential use of these spectral features as a temperature probe. The particle sizes are small enough for their spectra to be free of scattering effects, and therefore provide a means to assess imaginary refractive index values obtained through Kramers-Kronig analyses of thin film spectra.

  13. Thermonuclear Supernovae: Probing Magnetic Fields by Late-Time IR Line Profiles

    E-Print Network [OSTI]

    Penney, R

    2014-01-01

    We study the imprint of magnetic fields B on late-time IR line profiles and light curves of Type Ia Supernovae. As a benchmark, we use the explosion of a Chandrasekhar mass M_{Ch White Dwarf (WD) and, specifically, a delayed detonation model. We assume WDs with initial magnetic surface fields between 1 and 1E9G. We discuss large-scale dipole and small-scale magnetic fields. We find that the [Fe II] line at 1.644 mu can be used to analyze the overall chemical and density structure of the exploding WD up to day 200 without considering B. Subsequently, positron transport and magnetic field effects become important. By day 500, the profile becomes sensitive to the morphology of B and directional dependent for dipole fields. Small or no directional dependence of the spectra is found for small-scale B. After about 200 days, persistent broad-line, flat-topped or stumpy profiles require high density burning which is the signature of a WD close to M_Ch. Narrow peaked profiles are a signature of chemical mixing or sub-...

  14. Structural, electronic and magnetic properties of the series of double perovskites (Ca,Sr){sub 2?x}La{sub x}FeIrO{sub 6}

    SciTech Connect (OSTI)

    Bufaiçal, L.; Adriano, C.; Lora-Serrano, R.; Duque, J.G.S.; Mendonça-Ferreira, L.; Rojas-Ayala, C.; Baggio-Saitovitch, E.; Bittar, E.M.; Pagliuso, P.G.

    2014-04-01

    Polycrystalline samples of the series of double perovskites Sr{sub 2?x}La{sub x}FeIrO{sub 6} were synthesized. Their structural, electronic and magnetic properties were investigated by X-ray powder diffraction, Mössbauer spectroscopy, magnetic susceptibility, heat capacity and electrical resistivity experiments. The compounds crystallize in a monoclinic structure and were fitted in space group P2{sub 1}/n, with a significant degree of Fe/Ir cationic disorder. As in Ca{sub 2?x}La{sub x}FeIrO{sub 6} the Sr-based system seems to evolve from an antiferromagnetic ground state for the end members (x=0.0 and x=2.0) to a ferrimagnetic order in the intermediate regions (x?1). Since Mössbauer spectra indicate that Fe valence remains 3+ with doping, this tendency of change in the nature of the microscopic interaction could be attributed to Ir valence changes, induced by La{sup 3+} electrical doping. Upon comparing both Ca and Sr series, Sr{sub 2?x}La{sub x}FeIrO{sub 6} is more structurally homogenous and presents higher magnetization and transition temperatures. Magnetic susceptibility measurements at high temperatures on Sr{sub 1.2}La{sub 0.8}FeIrO{sub 6} indicate a very high ferrimagnetic Curie temperature T{sub C}?700K. For the Sr{sub 2}FeIrO{sub 6} compound, electrical resistivity experiments under applied pressure suggest that this material might be a Mott insulator. - Graphical abstract: The Weiss constant as a function of La doping for the (Ca,Sr){sub 2?x}La{sub x}FeIrO{sub 6} series, indicating changes in Fe–Ir magnetic coupling on both families. - Highlights: • The double perovskite series (Ca,Sr){sub 2?x}La{sub x}FeIrO{sub 6} were synthesized. • Changes in the Fe-Ir magnetic coupling due to La doping on both series. • Evidence of high T{sub C} on Sr{sub 1.2}La{sub 0.8}FeIrO{sub 6}. • Indication of Mott insulator behavior on Sr{sub 2}FeIrO{sub 6}.

  15. A deep look at the nuclear region of UGC 5101 through high angular resolution mid-IR data with GTC/CanariCam

    E-Print Network [OSTI]

    Martínez-Paredes, M; Aretxaga, I; Almeida, C Ramos; Hernán-Caballero, A; González-Martín, O; Pereira-Santaella, M; Packham, C; Ramos, A Asensio; Díaz-Santos, T; Elitzur, M; Esquej, P; García-Bernete, I; Imanishi, M; Levenson, N A; Espinosa, J M Rodríguez

    2015-01-01

    We present an analysis of the nuclear infrared (IR, 1.6 to 18 $\\mu$m) emission of the ultraluminous IR galaxy UGC 5101 to derive the properties of its active galactic nucleus (AGN) and its obscuring material. We use new mid-IR high angular resolution ($0.3-0.5$ arcsec) imaging using the Si-2 filter ($\\lambda_{C}=8.7\\, \\mu$m) and $7.5-13$ $\\mu$m spectroscopy taken with CanariCam (CC) on the 10.4m Gran Telescopio CANARIAS. We also use archival HST/NICMOS and Subaru/COMICS imaging and Spitzer/IRS spectroscopy. We estimate the near- and mid-IR unresolved nuclear emission by modelling the imaging data with GALFIT. We decompose the Spitzer/IRS and CC spectra using a power-law component, which represents the emission due to dust heated by the AGN, and a starburst component, both affected by foreground extinction. We model the resulting unresolved near- and mid-IR, and the starburst subtracted CC spectrum with the CLUMPY torus models of Nenkova et al. The derived geometrical properties of the torus, including the lar...

  16. The role of the (111) texture on the exchange bias and interlayer coupling effects observed in sputtered NiFe/IrMn/Co trilayers

    SciTech Connect (OSTI)

    Castro, I. L.; Nascimento, V. P.; Passamani, E. C.; Takeuchi, A. Y.; Larica, C.; Tafur, M.; Pelegrini, F.

    2013-05-28

    Magnetic properties of sputtered NiFe/IrMn/Co trilayers grown on different seed layers (Cu or Ta) deposited on Si (100) substrates were investigated by magnetometry and ferromagnetic resonance measurements. Exchange bias effect and magnetic spring behavior have been studied by changing the IrMn thickness. As shown by X-ray diffraction, Ta and Cu seed layers provoke different degrees of (111) fcc-texture that directly affect the exchange bias and indirectly modify the exchange spring coupling behavior. Increasing the IrMn thickness, it was observed that the coupling angle between the Co and NiFe ferromagnetic layers increases for the Cu seed system, but it reduces for the Ta case. The results were explained considering (i) different anisotropies of the Co and IrMn layers induced by the different degree of the (111) texture and (ii) the distinct exchange bias set at the NiFe/IrMn and IrMn/Co interfaces in both systems. The NiFe and Co interlayer coupling angle is strongly correlated with both exchange bias and exchange magnetic spring phenomena. It was also shown that the highest exchange bias field occurs when an unstressed L1{sub 2} IrMn structure is stabilized.

  17. Comparison between Single Shot Micromachining of Silicon with Nanosecond Pulse Shaped IR Fibre Laser and DPSS UV Laser

    E-Print Network [OSTI]

    Li, Kun; Sparkes, Martin; O'Neill, William

    2014-02-19

    were focussed onto the surface of a polished single crystalline Si wafer, 650 µm thick, with a crystallographic orientation. Samples were examined using a Veeco NT3300 white light interferometer for profile, and a Zeiss 1640 cross beam... show a greater number of micron and sub-micron condensed particles which are formed later in time as the plasma expands and cools. The nanosecond energy enriched long tail of IR laser is thought to establish a long-persistence plasma similar...

  18. Thermonuclear supernovae: probing magnetic fields by positrons and late-time IR line profiles

    SciTech Connect (OSTI)

    Penney, R.; Hoeflich, P., E-mail: phoeflich77@gmail.com, E-mail: rpenney@g.clemson.edu [Department of Physics, Florida State University, Tallahassee, FL 32305 (United States)

    2014-11-01

    We show the importance of ? and positron transport for the formation of late-time spectra in Type Ia supernovae (SNe Ia). The goal is to study the imprint of magnetic fields (B) on late-time IR line profiles, particularly the [Fe II] feature at 1.644 ?m, which becomes prominent two to three months after the explosion. As a benchmark, we use the explosion of a Chandrasekhar mass (M {sub Ch}) white dwarf (WD) and, specifically, a delayed detonation model that can reproduce the light curves and spectra for a Branch-normal SN Ia. We assume WDs with initial magnetic surface fields between 1 and 10{sup 9} G. We discuss large-scale dipole and small-scale magnetic fields. We show that positron transport effects must be taken into account for the interpretation of emission features starting at about one to two years after maximum light, depending on the size of B. The [Fe II] line profile and its evolution with time can be understood in terms of the overall energy input by radioactive decay and the transition from a ?-ray to a positron-dominated regime. We find that the [Fe II] line at 1.644 ?m can be used to analyze the overall chemical and density structure of the exploding WD up to day 200 without considering B. At later times, positron transport and magnetic field effects become important. After about day 300, the line profile allows one to probe the size of the B-field. The profile becomes sensitive to the morphology of B at about day 500. In the presence of a large-scale dipole field, a broad line is produced in M {sub Ch} mass explosions that may appear flat-topped or rounded depending on the inclination at which the SN is observed. Small or no directional dependence of the spectra is found for small-scale B. We note that narrow-line profiles require central {sup 56}Ni as shown in our previous studies. Persistent broad-line, flat-topped profiles require high-density burning, which is the signature of a WD close to M {sub Ch}. Good time coverage is required to separate the effects of optical depth, the size and morphology of B, and the aspect angle of the observer. The spectra require a resolution of about 500 km s{sup –1} and a signal-to-noise ratio of about 20%. Two other strong near-IR spectral features at about 1.5 and 1.8 ?m are used to demonstrate the importance of line blending, which may invalidate a kinematic interpretation of emission lines. Flat-topped line profiles between 300 and 400 days have been observed and reported in the literature. They lend support for M {sub Ch} mass explosions in at least some cases and require magnetic fields equal to or in excess of 10{sup 6} G. We briefly discuss the effects of the size and morphology of B on light curves, as well as limitations. We argue that line profiles are a more direct measurement of B than light curves because they measure both the distribution of {sup 56}Ni and the redistribution of the energy input by positrons rather than the total energy input. Finally, we discuss possible mechanisms for the formation of high B-fields and the limitations of our analysis.

  19. The AGN content in luminous IR galaxies at z\\sim2 from a global SED analysis including Herschel data

    E-Print Network [OSTI]

    Pozzi, F; Gruppioni, C; Feltre, A; Fritz, J; Fadda, D; Andreani, P; Berta, S; Cimatti, A; Delvecchio, I; Lutz, D; Magnelli, B; Maiolino, R; Nordon, R; Popesso, P; Rodighiero, G; Rosario, D; Santini, P; Vaccari, M

    2012-01-01

    We use Herschel-PACS far-infrared data, combined with previous multi-band information and mid-IR spectra, to properly account for the presence of an active nucleus and constrain its energetic contribution in luminous infrared (IR) sources at z\\sim2. The sample is composed of 24 sources in the GOODS-South field, with typical IR luminosity of 10^{12} Lo. Data from the 4 Ms Chandra X-ray imaging in this field are also used to identify and characterize AGN emission. We reproduce the observed spectral energy distribution (SED), decomposed into a host-galaxy and an AGN component. A smooth-torus model for circum-nuclear dust is used to account for the direct and re-processed contribution from the AGN. We confirm that galaxies with typical L_{8-1000um}\\sim10^{12}Lo at z\\sim2 are powered predominantly by star-formation. An AGN component is present in nine objects (\\sim35% of the sample) at the 3sigma confidence level, but its contribution to the 8-1000 um emission accounts for only \\sim5% of the energy budget. The AGN...

  20. R{sub 4}Ir{sub 13}Ge{sub 9} (R=La, Ce, Pr, Nd, Sm) and RIr{sub 3}Ge{sub 2} (R=La, Ce, Pr, Nd): Crystal structures with nets of Ir atoms

    SciTech Connect (OSTI)

    Yarema, Maksym [Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya Str, 6, UA-79005 Lviv (Ukraine) [Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya Str, 6, UA-79005 Lviv (Ukraine); Swiss Federal Laboratories for Materials Science and Technology (EMPA), Ueberlandstr. 129, CH-8600 Duebendorf (Switzerland); Zaremba, Oksana; Gladyshevskii, Roman [Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya Str, 6, UA-79005 Lviv (Ukraine)] [Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla i Mefodiya Str, 6, UA-79005 Lviv (Ukraine); Hlukhyy, Viktor, E-mail: viktor.hlukhyy@lrz.tu-muenchen.de [Department Chemie, Technische Universitaet Muenchen, Lichtenbergstr. 4, D-85747 Garching (Germany)] [Department Chemie, Technische Universitaet Muenchen, Lichtenbergstr. 4, D-85747 Garching (Germany); Faessler, Thomas F. [Department Chemie, Technische Universitaet Muenchen, Lichtenbergstr. 4, D-85747 Garching (Germany)] [Department Chemie, Technische Universitaet Muenchen, Lichtenbergstr. 4, D-85747 Garching (Germany)

    2012-12-15

    The crystal structures of the new ternary compounds Sm{sub 4}Ir{sub 13}Ge{sub 9} and LaIr{sub 3}Ge{sub 2} were determined and refined on the basis of single-crystal X-ray diffraction data. They belong to the Ho{sub 4}Ir{sub 13}Ge{sub 9} (oP52, Pmmn) and CeCo{sub 3}B{sub 2} (hP5, P6/mmm) structure types, respectively. The formation of isotypic compounds R{sub 4}Ir{sub 13}Ge{sub 9} with R=La, Ce, Pr, Nd, and RIr{sub 3}Ge{sub 2} with R=Ce, Pr, Nd, was established by powder X-ray diffraction. The RIr{sub 3}Ge{sub 2} (R=La, Ce, Pr, Nd) compounds exist only in as-cast samples and decompose during annealing at 800 Degree-Sign C with the formation of R{sub 4}Ir{sub 13}Ge{sub 9}. The structure of Sm{sub 4}Ir{sub 13}Ge{sub 9} contains intersecting, slightly puckered nets of Ir atoms (4{sup 4})(4{sup 3}.6){sub 2}(4.6{sup 2}){sub 2} and (4{sup 4}){sub 2}(4{sup 3}.6){sub 4}(4.6{sup 2}){sub 2} that are perpendicular to [0 1 1] as well as to [0 -1 1] and [0 0 1]. The Ir atoms are surrounded by Ge atoms that form tetrahedra or square pyramids (where the layers intersect). The Sm and additional Ir atoms (in trigonal-planar coordination) are situated in channels along [1 0 0] (short translation vector). In the structure of LaIr{sub 3}Ge{sub 2} the Ir atoms form planar Kagome nets (3.6.3.6) perpendicular to [0 0 1]. These nets alternate along the short translation vector with layers of La and Ge atoms. - Graphical abstract: The crystal structures contain the nets of Ir atoms as main structural motif: R{sub 4}Ir{sub 13}Ge{sub 9} contains intersecting slightly puckered nets of Ir atoms, whereas in the structure of RIr{sub 3}Ge{sub 2} the Ir atoms form planar Kagome nets. Highlights: Black-Right-Pointing-Pointer The Ir-rich ternary germanides R{sub 4}Ir{sub 13}Ge{sub 9} (R=La, Ce, Pr, Nd, Sm) and RIr{sub 3}Ge{sub 2} (R=La, Ce, Pr, Nd) have been synthesized. Black-Right-Pointing-Pointer The RIr{sub 3}Ge{sub 2} compounds exist only in as-cast samples and decompose during annealing at 800 Degree-Sign C with the formation of R{sub 4}Ir{sub 13}Ge{sub 9}. Black-Right-Pointing-Pointer The structure of R{sub 4}Ir{sub 13}Ge{sub 9} contains intersecting slightly puckered nets of Ir atoms. Black-Right-Pointing-Pointer In the structure of RIr{sub 3}Ge{sub 2} the Ir atoms form planar Kagome nets.

  1. Phone Scams Continue to be Serious Threat, Remain on IRS "Dirty Dozen" List of Tax Scams for the 2015 Filing Season

    E-Print Network [OSTI]

    Rock, Chris

    to be IRS officials and demanding that they send them cash via prepaid debit cards. Protect Yourself, such as a prepaid debit card. · Ask for credit or debit card numbers over the phone. · Threaten to bring in local

  2. Vehicle Technologies Office Merit Review 2015: IR Thermography as a Non-Destructive Evaluation (NDE) Tool for Lithium-Ion Battery Manufacturing

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about IR thermography...

  3. Guest Lecturer/Performer Agreement NAME OF GUEST LECTURER/PERFORMER 1 TAXPAYER ID OR SOCIAL SECURITY NUMBER FROM AN IRS FORM W-9

    E-Print Network [OSTI]

    Clayton, Dale H.

    Guest Lecturer/Performer Agreement NAME OF GUEST LECTURER/PERFORMER 1 TAXPAYER ID OR SOCIAL A taxpayer ID is required for this vendor. Ask the vendor or their agent to complete an IRS Form W-9

  4. Near-IR spectroscopic monitoring of CLASS I protostars: Variability of accretion and wind indicators

    SciTech Connect (OSTI)

    Connelley, Michael S.; Greene, Thomas P.

    2014-06-01

    We present the results of a program that monitored the near-IR spectroscopic variability of a sample of 19 embedded protostars. Spectra were taken on time intervals from 2 days to 3 yr, over a wavelength range from 0.85 ?m to 2.45 ?m, for 4-9 epochs of observations per target. We found that the spectra of all targets are variable and that every emission feature observed is also variable (although not for all targets). With one exception, there were no drastic changes in the continua of the spectra, nor did any line completely disappear, nor did any line appear that was not previously apparent. This analysis focuses on understanding the connection between accretion (traced by H Br ? and CO) and the wind (traced by He I, [Fe II], and sometimes H{sub 2}). For both accretion and wind tracers, the median variability was constant versus the time interval between observations; however, the maximum variability that we observed increased with the time interval between observations. Extinction is observed to vary within the minimum sampling time of 2 days, suggesting extinguishing material within a few stellar radii at high disk latitudes. The variability of [Fe II] and H{sub 2} were correlated for most (but not all) of the 7 young stellar objects showing both features, and the amplitude of the variability depends on the veiling. Although the occurrence of CO and Br ? emission are connected, their variability is uncorrelated, suggesting that these emissions originate in separate regions near the protostar (e.g., disk and wind). The variability of Br ? and wind tracers were found to be positively correlated, negatively correlated, or uncorrelated, depending on the target. The variability of Br ?, [Fe II], and H{sub 2} always lies on a plane, although the orientation of the plane in three dimensions depends on the target. While we do not understand all interactions behind the variability that we observed, we have shown that spectroscopic variability is a powerful tool toward understanding the star formation process.

  5. The application of the Mid-IR radio correlation to the $\\hat{G}$ sample and the search for advanced extraterrestrial civilisations

    E-Print Network [OSTI]

    Garrett, Michael

    2015-01-01

    Wright et al. 2014 have embarked on a search for advanced Karadashev Type III civilisations via the compilation of a sample of sources with extreme mid-IR emission and colours. In this scenario, the mid-IR emission is then primarily associated with waste heat energy by-products. I apply the Mid-IR radio correlation to this $\\hat{G}$ sample (Griffith et al. 2015). I demonstrate that the mid-IR and radio luminosities are correlated for the sample with $q_{22}=1.35\\pm0.42 $. By comparison, the First Look Survey (FLS) has $q_{22}=0.87\\pm0.27$. The fact that the G-HAT sample largely follows the Mid-IR radio correlation, strongly suggests the vast majority of these sources are associated with galaxies in which natural astrophysical processes are dominant. This simple application of the mid-IR radio correlation can substantially reduce the number of false positives in the $\\hat{G}$ catalogue, since galaxies occupied by advanced Kardashev Type III civilisations would be expected to exhibit very high values of $q$. In...

  6. New insulating antiferromagnetic quaternary iridates MLa10Ir4O24 (M=Sr, Ba)

    SciTech Connect (OSTI)

    Zhao, Qingbiao; Han, Fei; Stoumpos, Constantinos C.; Han, Tian -Heng; Li, Hao; Mitchell, J. F.

    2015-07-01

    Recently, oxides of Ir4+ have received renewed attention in the condensed matter physics community, as it has been reported that certain iridates have a strongly spin-orbital coupled (SOC) electronic state, Jeff = ½, that defines the electronic and magnetic properties. The canonical example is the Ruddlesden-Popper compound Sr2IrO4, which has been suggested as a potential route to a new class of high temperature superconductor due to the formal analogy between Jeff = ½ and the S = ½ state of the cuprate superconductors. The quest for other iridium oxides that present tests of the underlying SOC physics is underway. In this spirit, here we report the synthesis and physical properties of two new quaternary tetravalent iridates, MLa10Ir4O24 (M = Sr, Ba). The crystal structure of both compounds features isolated IrO6 octahedra in which the electronic configuration of Ir is d5. As a result, both compounds order antiferromagnetically despite the lack of obvious superexchange pathways, and resistivity measurement shows that SrLa10Ir4O24 is an insulator.

  7. Role of the reaction intermediates in determining PHIP (parahydrogen induced polarization) effect in the hydrogenation of acetylene dicarboxylic acid with the complex [Rh (dppb)]{sup +} (dppb: 1,4-bis(diphenylphosphino)butane)

    SciTech Connect (OSTI)

    Reineri, F.; Aime, S.; Gobetto, R.; Nervi, C.

    2014-03-07

    This study deals with the parahydrogenation of the symmetric substrate acetylene dicarboxylic acid catalyzed by a Rh(I) complex bearing the chelating diphosphine dppb (1,4-bis(diphenylphosphino)butane). The two magnetically equivalent protons of the product yield a hyperpolarized emission signal in the {sup 1}H-NMR spectrum. Their polarization intensity varies upon changing the reaction solvent from methanol to acetone. A detailed analysis of the hydrogenation pathway is carried out by means of density functional theory calculations to assess the structure of hydrogenation intermediates and their stability in the two solvents. The observed polarization effects have been accounted on the basis of the obtained structures. Insights into the lifetime of a short-lived reaction intermediate are also obtained.

  8. A test of arm induced star formation in spiral galaxies from near-IR and H?imaging

    E-Print Network [OSTI]

    M. S. Seigar; P. A. James

    2000-07-27

    We have imaged a sample of 20 face-on spiral galaxies in H\\alpha and in the near-IR K-band (2.2 microns), in order to determine the location and strength of star formation with respect to perturbations in the old stellar population. We found that star formation rates are significantly enhanced near K-band arms. If K-band light is dominated by emission from old stars, this shows that density waves trigger star formation. However, no significant correlation was found between the global underlying disk properties of spiral galaxies and their total star formation rates.

  9. S-H bond activation in H{sub 2}S and thiols by [RhMn(CO){sub 4}(Ph{sub 2}PCH{sub 2}PPh{sub 2}){sub 2}]. Compounds containing terminal or bridging sulfhydryl and thiolato groups

    SciTech Connect (OSTI)

    Li-Sheng Wang; McDonald, R.; Cowie, M. [Univ. of Alberta, Edmonton (Canada)

    1994-08-17

    A rhodium-magnesium carbonyl-phosphines reacted with thiols to yield the products of S-H addition. Further reactions result in bridging sulfide can be alkylated or protonated at the sulfur. The compound, [RhMn(CO){sub 4}({mu}-S)(dppm){sub 2}], was structurally characterized by X-ray crystallography.

  10. VOLUME 87, NUMBER 19 P H Y S I C A L R E V I E W L E T T E R S 5 NOVEMBER 2001 Distinct Reaction Mechanisms in the Catalytic Oxidation of Carbon Monoxide on Rh(110)

    E-Print Network [OSTI]

    Hla, Saw-Wai

    Mechanisms in the Catalytic Oxidation of Carbon Monoxide on Rh(110): Scanning Tunneling Microscopy for catalytic oxidation of hydrogen on a platinum surface [3]. In the latter case, the two different mechanisms calculations, we identify the reaction mechanism for the oxidation of carbon monoxide to carbon dioxide

  11. Characterizing the Habitable Zones of Exoplanetary Systems with a Large Ultraviolet/Visible/Near-IR Space Observatory

    E-Print Network [OSTI]

    France, Kevin; Linsky, Jeffrey; Roberge, Aki; Ayres, Thomas; Barman, Travis; Brown, Alexander; Davenport, James; Desert, Jean-Michel; Domagal-Goldman, Shawn; Fleming, Brian; Fontenla, Juan; Fossati, Luca; Froning, Cynthia; Hallinan, Gregg; Hawley, Suzanne; Hu, Renyu; Kaltenegger, Lisa; Kasting, James; Kowlaski, Adam; Loyd, Parke; Mauas, Pablo; Miguel, Yamila; Osten, Rachel; Redfield, Seth; Rugheimer, Sarah; Schneider, Christian; Segura, Antigona; Stocke, John; Tian, Feng; Tumlinson, Jason; Vieytes, Mariela; Walkowicz, Lucianne; Wood, Brian; Youngblood, Allison

    2015-01-01

    Understanding the surface and atmospheric conditions of Earth-size, rocky planets in the habitable zones (HZs) of low-mass stars is currently one of the greatest astronomical endeavors. Knowledge of the planetary effective surface temperature alone is insufficient to accurately interpret biosignature gases when they are observed in the coming decades. The UV stellar spectrum drives and regulates the upper atmospheric heating and chemistry on Earth-like planets, is critical to the definition and interpretation of biosignature gases, and may even produce false-positives in our search for biologic activity. This white paper briefly describes the scientific motivation for panchromatic observations of exoplanetary systems as a whole (star and planet), argues that a future NASA UV/Vis/near-IR space observatory is well-suited to carry out this work, and describes technology development goals that can be achieved in the next decade to support the development of a UV/Vis/near-IR flagship mission in the 2020s.

  12. Molecular origin of the difference in the HOH bend of the IR spectra between liquid water and ice

    SciTech Connect (OSTI)

    Imoto, Sho; Xantheas, Sotiris S.; Saito, Shinji

    2013-02-07

    The intensity of the HOH bend in the IR spectrum of ice is significantly smaller than the corresponding one in liquid water. This difference in the IR intensities of the HOH bend in the two systems is investigated using MD simulations with the flexible, polarizable, ab-initio based TTM3-F model for water, a potential that correctly reproduces the experimentally observed increase of the HOH bend in liquid water and ice from the water monomer value. We have identified two factors that are responsible for the difference in the intensity of the HOH bend in liquid water and ice: (i) the decrease of the intensity of the HOH bend in ice caused by the strong anti-correlation between the permanent dipole moment of a molecule and the induced dipole moment of a neighboring hydrogen bond acceptor molecule and (ii) the weakening of this anti-correlation by the disordered hydrogen bond network in liquid water. The presence of the anti-correlation in ice is further confirmed by ab initio electronic structure calculations of water pentamer clusters extracted from the trajectories of the MD simulations for ice and liquid water.

  13. Accelerated Aging of BKC 44306-10 Rigid Polyurethane Foam: FT-IR Spectroscopy, Dimensional Analysis, and Micro Computed Tomography

    SciTech Connect (OSTI)

    Gilbertson, Robert D.; Patterson, Brian M.; Smith, Zachary

    2014-01-02

    An accelerated aging study of BKC 44306-10 rigid polyurethane foam was carried out. Foam samples were aged in a nitrogen atmosphere at three different temperatures: 50 °C, 65 °C, and 80 °C. Foam samples were periodically removed from the aging canisters at 1, 3, 6, 9, 12, and 15 month intervals when FT-IR spectroscopy, dimensional analysis, and mechanical testing experiments were performed. Micro Computed Tomography imaging was also employed to study the morphology of the foams. Over the course of the aging study the foams the decreased in size by a magnitude of 0.001 inches per inch of foam. Micro CT showed the heterogeneous nature of the foam structure likely resulting from flow effects during the molding process. The effect of aging on the compression and tensile strength of the foam was minor and no cause for concern. FT-IR spectroscopy was used to follow the foam chemistry. However, it was difficult to draw definitive conclusions about the changes in chemical nature of the materials due to large variability throughout the samples.

  14. The ITER VIS/IR wide angle viewing system: Challenges and on-going R and D

    SciTech Connect (OSTI)

    Travere, J. M.; Aumeunier, M. H.; Joanny, M.; Jouve, M.; Martin, V.; Moncada, V.; Salasca, S.; Marot, L.; Chabaud, D.; Ferme, J. J.; Bremond, F.; Thonnat, M.

    2011-07-01

    The ITER tokamak is the next generation fusion device which will allow studying burning plasma obtained by a Deuterium-Tritium (D-T) fusion reaction during hundreds of seconds. ITER vacuum vessel real-time protection will be mandatory during plasma operation to avoid water leaks and critical plasma facing components degradation. The protection system will be based on a wide angle viewing system (WAVS) composed with 18 visible (VIS) and 18 infrared (IR) cameras covering 80 % of the vacuum vessel which will be one of the major imaging systems of ITER. Compared to protection systems routinely used on current tokamaks and based on imaging (VIS and/or IR), new constraints must be taken into account because of their influence on the system performance: the harsh environment (high neutron flux) and the metallic plasma facing components (both first wall and divertor). In this new demanding context, we have achieved three mandatory R and D studies starting from the understanding of the source of signals by using realistic photonic simulation up to real-time processing strategy taken into account first order optical design constraints to define what type of performance could be reached for ITER vacuum vessel protection. (authors)

  15. NEAR-IR TWO PHOTON MICROSCOPY IMAGING OF SILICA NANOPARTICLES FUNCTIONALIZED WITH ISOLATED SENSITIZED Yb(III) CENTERS

    SciTech Connect (OSTI)

    Lapadula, Giuseppe; Bourdolle, Adrien; Allouche, Florian; Conley, Matthew P.; Maron, Laurent; Lukens, Wayne W.; Guyot, Yannick; Andraud, Chantal; Brasselet, Sophie; Copé; ret, Christophe; Maury, Olivier; Andersen, Richard A.

    2013-01-12

    Bright nano objects emitting in the near infrared with a maximal cross section of 41.4 x 103 GM (Goppert Mayer), were prepared by implanting ca. 180 4,4 diethylaminostyryl 2,2 bipyridine (DEAS) Yb(III) complexes on the surface of 12 nm silica nanoparticles. The surface complexes ([DEAS Ln SiO2], Ln =Y,Yb) were characterized using IR, solid state NMR, UV Vis, EXAFS spectroscopies in combination with the preparation and characterization of similar molecular analogues by analytical techniques (IR, solution NMR, UV Vis, X ray crystallography) as well as DFT calculations. Starting from the partial dehydroxylation of the silica at 700 C on high vacuum having 0.8 OH.nm 2, the grafting of Ln(N(SiMe3)2)3 generate ?SiO Ln(N(SiMe3)2)2, which upon thermal step and coordination of the DEAS chromophore yields (?SiO)3Ln(DEAS). Surface and molecular analogues display similar properties, in terms of DEAS binding constants absorption maxima and luminescence properties (intense emission band assigned to a ligand centered CT fluorescence and life time) in the solid state, consistent with the molecular nature of the surface species. The densely functionalized nanoparticles can be dispersed via ultra-sonication in small ca. 15-20 nm aggregates (1 to 6 elementary particles) that were detected using two photon microscopy imaging at 720 nm excitation, making them promising nano objects for bio imaging.

  16. Galaxy And Mass Assembly (GAMA): The Bright Void Galaxy Population in the Optical and Mid-IR

    E-Print Network [OSTI]

    Penny, S J; Pimbblet, K A; Cluver, M E; Croton, D J; Owers, M S; Lange, R; Alpaslan, M; Baldry, I; Bland-Hawthorn, J; Brough, S; Driver, S P; Holwerda, B W; Hopkins, A M; Jarrett, T H; Jones, D Heath; Kelvin, L S; Lara-Lopez, M A; Liske, J; Lopez-Sanchez, A R; Loveday, J; Meyer, M; Norberg, P; Robotham, A S G; Rodrigues, M

    2015-01-01

    We examine the properties of galaxies in the Galaxies and Mass Assembly (GAMA) survey located in voids with radii $>10~h^{-1}$ Mpc. Utilising the GAMA equatorial survey, 592 void galaxies are identified out to z~0.1 brighter than $M_{r} = -18.4$, our magnitude completeness limit. Using the $W_{\\rm{H\\alpha}}$ vs. [NII]/H$\\alpha$ (WHAN) line strength diagnostic diagram, we classify their spectra as star forming, AGN, or dominated by old stellar populations. For objects more massive than $5\\times10^{9}$ M$_{\\odot}$, we identify a sample of 26 void galaxies with old stellar populations classed as passive and retired galaxies in the WHAN diagnostic diagram, else they lack any emission lines in their spectra. When matched to WISE mid-IR photometry, these passive and retired galaxies exhibit a range of mid-IR colour, with a number of void galaxies exhibiting [4.6]-[12] colours inconsistent with completely quenched stellar populations, with a similar spread in colour seen for a randomly drawn non-void comparison samp...

  17. Mixing antiferromagnets to tune NiFe-[IrMn/FeMn] interfacial spin-glasses, grains thermal stability, and related exchange bias properties

    SciTech Connect (OSTI)

    Akmaldinov, K.; Ducruet, C.; Portemont, C.; Joumard, I.; Prejbeanu, I. L.; Dieny, B.; Baltz, V.

    2014-05-07

    Spintronics devices and in particular thermally assisted magnetic random access memories require a wide range of ferromagnetic/antiferromagnetic (F/AF) exchange bias (EB) properties and subsequently of AF materials to fulfil diverse functionality requirements for the reference and storage. For the reference layer, large EB energies and high blocking temperature (T{sub B}) are required. In contrast, for the storage layer, mostly moderate T{sub B} are needed. One of the present issues is to find a storage layer with properties intermediate between those of IrMn and FeMn and in particular: (i) with a T{sub B} larger than FeMn for better stability at rest-T but lower than IrMn to reduce power consumption at write-T and (ii) with improved magnetic interfacial quality, i.e., with reduced interfacial glassy character for lower properties dispersions. To address this issue, the EB properties of F/AF based stacks were studied for various mixed [IrMn/FeMn] AFs. In addition to EB loop shifts, the F/AF magnetic interfacial qualities and the AF grains thermal stability are probed via measurements of the low- and high-temperature contributions to the T{sub B} distributions, respectively. A tuning of the above three parameters is observed when evolving from IrMn to FeMn via [IrMn/FeMn] repetitions.

  18. Study on the reduction of atmospheric mercury emissions from mine waste enriched soils through native grass cover in the Mt. Amiata region of Italy

    SciTech Connect (OSTI)

    Fantozzi, L., E-mail: l.fantozzi@iia.cnr.it [CNR-Institute of Atmospheric Pollution Research, c/o: UNICAL-Polifunzionale, 87036 Rende (Italy); Ferrara, R., E-mail: romano.ferrara@pi.ibf.cnr.it [CNR-Institute of Biophysics, San Cataldo Research Area, Via G. Moruzzi 1, 56124 Pisa (Italy); Dini, F., E-mail: fdiniprotisti@gmail.com [University of Pisa, Department of Biology, Via A. Volta 4, 56126 Pisa (Italy); Tamburello, L., E-mail: ltamburello@biologia.unipi.it [University of Pisa, Department of Biology, Via Derna 1, I-56126 Pisa (Italy); Pirrone, N.; Sprovieri, F. [CNR-Institute of Atmospheric Pollution Research, c/o: UNICAL-Polifunzionale, 87036 Rende (Italy)] [CNR-Institute of Atmospheric Pollution Research, c/o: UNICAL-Polifunzionale, 87036 Rende (Italy)

    2013-08-15

    Atmospheric mercury emissions from mine-waste enriched soils were measured in order to compare the mercury fluxes of bare soils with those from other soils covered by native grasses. Our research was conducted near Mt. Amiata in central Italy, an area that was one of the largest and most productive mining centers in Europe up into the 1980s. To determine in situ mercury emissions, we used a Plexiglas flux chamber connected to a portable mercury analyzer (Lumex RA-915+). This allowed us to detect, in real time, the mercury vapor in the air, and to correlate this with the meteorological parameters that we examined (solar radiation, soil temperature, and humidity). The highest mercury flux values (8000 ng m{sup ?2} h{sup ?1}) were observed on bare soils during the hours of maximum insulation, while lower values (250 ng m{sup ?2} h{sup ?1}) were observed on soils covered by native grasses. Our results indicate that two main environmental variables affect mercury emission: solar radiation intensity and soil temperature. The presence of native vegetation, which can shield soil surfaces from incident light, reduced mercury emissions, a result that we attribute to a drop in the efficiency of mercury photoreduction processes rather than to decreases in soil temperature. This finding is consistent with decreases in mercury flux values down to 3500 ng m{sup ?2} h{sup ?1}, which occurred under cloudy conditions despite high soil temperatures. Moreover, when the soil temperature was 28 °C and the vegetation was removed from the experimental site, mercury emissions increased almost four-fold. This increase occurred almost immediately after the grasses were cut, and was approximately eight-fold after 20 h. Thus, this study demonstrates that enhancing wild vegetation cover could be an inexpensive and effective approach in fostering a natural, self-renewing reduction of mercury emissions from mercury-contaminated soils. -- Highlights: ? Mercury air/surface exchange from grass covered soil is different from bare soil. ? Light enhances mercury emissions and is the main parameter driving the process. ? The presence of wild vegetation covering the soil reduces mercury emission. ? Vegetative covers could be a solution to reduce atmospheric mercury pollution.

  19. Inland EmpIrE mErchandIsE Exports calIfornIa statE UnIvErsIty fUllErton

    E-Print Network [OSTI]

    de Lijser, Peter

    Inland EmpIrE mErchandIsE Exports calIfornIa statE UnIvErsIty fUllErton 20122012 CSUF Mihaylo University, Fullerton An Overview and Analysis of Inland Empire Exports #12;novEmbEr 2011 InstItUtE for EconomIc and EnvIronmEntal stUdIEs33 #12;Inland EmpIrE mErchandIsE Exports calIfornIa statE UnIvErsIty f

  20. Probing single magnon excitations in Sr?IrO? using O K-edge resonant inelastic x-ray scattering

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, X.; Dean, M. P. M.; Liu, J.; Chiuzbaian, S. G.; Jaouen, N.; Nicolaou, A.; Yin, W. G.; Rayan Serrao, C.; Ramesh, R.; Ding, H.; et al

    2015-04-28

    Resonant inelastic X-ray scattering (RIXS) at the L-edge of transition metal elements is now commonly used to probe single magnon excitations. Here we show that single magnon excitations can also be measured with RIXS at the K-edge of the surrounding ligand atoms when the center heavy metal elements have strong spin-orbit coupling. This is demonstrated with oxygen K-edge RIXS experiments on the perovskite Sr?IrO?, where low energy peaks from single magnon excitations were observed. This new application of RIXS has excellent potential to be applied to a wide range of magnetic systems based on heavy elements, for which the L-edgemore »RIXS energy resolutions in the hard X-ray region is usually poor.« less

  1. Probing single magnon excitations in Sr?IrO? using O K-edge resonant inelastic x-ray scattering

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, X. [Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics (BNLCP-CAS); Brookhaven National Lab. (BNL), Upton, NY (United States); Collaborative Innovation Center of Quantum Matter, Beijing (China); Dean, M. P. M. [Brookhaven National Lab. (BNL), Upton, NY (United States); Liu, J. [Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chiuzbaian, S. G. [Sorbonne Univ., Paris (France); Synchrotron SOLEIL, Saint-Aubin (France); Jaouen, N. [Synchrotron SOLEIL, Saint-Aubin (France); Nicolaou, A. [Synchrotron SOLEIL, Saint-Aubin (France); Yin, W. G. [Brookhaven National Lab. (BNL), Upton, NY (United States); Rayan Serrao, C. [Univ. of California, Berkeley, CA (United States); Ramesh, R. [Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Ding, H. [Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics (BNLCP-CAS); Collaborative Innovation Center of Quantum Matter, Beijing (China); Hill, J. P. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-05-27

    Resonant inelastic X-ray scattering (RIXS) at the L-edge of transition metal elements is now commonly used to probe single magnon excitations. Here we show that single magnon excitations can also be measured with RIXS at the K-edge of the surrounding ligand atoms when the center heavy metal elements have strong spin-orbit coupling. This is demonstrated with oxygen K-edge RIXS experiments on the perovskite Sr?IrO?, where low energy peaks from single magnon excitations were observed. This new application of RIXS has excellent potential to be applied to a wide range of magnetic systems based on heavy elements, for which the L-edge RIXS energy resolutions in the hard X-ray region is usually poor.

  2. Electron band theory predictions and the construction of phase diagrams. [HfPt; TaIr; WOs

    SciTech Connect (OSTI)

    Watson, R.E.; Bennett, L.H.; Davenport, J.W.; Weinert, M.

    1985-01-01

    The a priori theory of metals is yielding energy results which are relevant to the construction of phase diagrams - to the solution phases as well as to line compounds. There is a wide range in the rigor of the calculations currently being done and this is discussed. Calculations for the structural stabilities (fcc vs bcc vs hcp) of the elemental metals, quantities which are employed in the constructs of the terminal phases, are reviewed and shown to be inconsistent with the values currently employed in such constructs (also see Miodownik elsewhere in this volume). Finally, as an example, the calculated heats of formation are compared with experiment for PtHf, IrTa and OsW, three compounds with the same electron to atom ratio but different bonding properties.

  3. Terawatt-level few-cycle mid-IR pulses through nonlinear self-compression in bulk

    E-Print Network [OSTI]

    Shumakova, V; Ališauskas, S; Zheltikov, A Voronin A M; Faccio, D; Kartashov, D; Baltuška, A; Pugžlys, A

    2015-01-01

    The physics of strong-field applications requires driver laser pulses that are both energetic and extremely short. Whereas optical amplifiers, laser and parametric, boost the energy, their gain bandwidth restricts the attainable pulse duration, requiring additional nonlinear spectral broadening to enable few or even single cycle compression and a corresponding peak power increase. In the mid-IR wavelength range that is critically important for scaling the ponderomotive energy in strong-field interactions, we demonstrate a remarkably simple energy-efficient and scalable soliton-like pulse compression in a mm-long YAG crystal with no additional dispersion management. Sub-three-cycle pulses with >0.65 TW peak power are compressed and extracted before the onset of modulation instability and multiple filamentation as a result of a favorable interplay between strong anomalous dispersion and optical nonlinearity around the wavelength of 3900 nm. As a striking manifestation of the increased peak power, we show the ev...

  4. Formation of a Keplerian disk in the infalling envelope around L1527 IRS: transformation from infalling motions to Kepler motions

    SciTech Connect (OSTI)

    Ohashi, Nagayoshi [Subaru Telescope, National Astronomical Observatory of Japan, 650 North A'ohoku Place, Hilo, HI 96720 (United States); Saigo, Kazuya [Chile Observatory, National Astronomical Observatory of Japan, Osawa 2-21-1, Mitaka, Tokyo 181-8588 (Japan); Aso, Yusuke; Koyamatsu, Shin [Department of Astronomy, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan); Aikawa, Yuri [Department of Earth and Planetary Sciences, Kobe University, Kobe 657-8501 (Japan); Machida, Masahiro N. [Department of Earth and Planetary Sciences, Faculty of Sciences, Kyushu University, Fukuoka 812-8581 (Japan); Saito, Masao [Joint ALMA Observatory, Ave. Alonso de Cordova 3107, Vitacura, Santiago (Chile); Takahashi, Sanemichi Z. [Department of Physics, Kyoto University, Oiwake-cho, Kitashirakawa, Sakyo-ku, Kyoto 606-8502 (Japan); Takakuwa, Shigehisa; Yen, Hsi-Wei [Academia Sinica Institute of Astronomy and Astrophysics, PO Box 23-141, Taipei 10617, Taiwan (China); Tomida, Kengo [Department of Astronomical Science, Princeton University, Princeton, NJ 08544 (United States); Tomisaka, Kohji, E-mail: nohashi@naoj.org [National Astronomical Observatory of Japan, Osawa 2-21-1, Mitaka, Tokyo 181-8588 (Japan)

    2014-12-01

    We report Atacama Large Millimeter/submillimeter Array (ALMA) cycle 0 observations of the C{sup 18}O (J = 2-1), SO (J{sub N} = 6{sub 5}-5{sub 4}), and the 1.3 mm dust continuum toward L1527 IRS, a class 0 solar-type protostar surrounded by an infalling and rotating envelope. C{sup 18}O emission shows strong redshifted absorption against the bright continuum emission associated with L1527 IRS, strongly suggesting infall motions in the C{sup 18}O envelope. The C{sup 18}O envelope also rotates with a velocity mostly proportional to r {sup –1}, where r is the radius, whereas the rotation profile at the innermost radius (?54 AU) may be shallower than r {sup –1}, suggestive of formation of a Keplerian disk around the central protostar of ?0.3 M {sub ?} in dynamical mass. SO emission arising from the inner part of the C{sup 18}O envelope also shows rotation in the same direction as the C{sup 18}O envelope. The rotation is, however, rigid-body-like, which is very different from the differential rotation shown by C{sup 18}O. In order to explain the line profiles and the position-velocity (PV) diagrams of C{sup 18}O and SO observed, simple models composed of an infalling envelope surrounding a Keplerian disk of 54 AU in radius orbiting a star of 0.3 M {sub ?} are examined. It is found that in order to reproduce characteristic features of the observed line profiles and PV diagrams, the infall velocity in the model has to be smaller than the free-fall velocity yielded by a star of 0.3 M {sub ?}. Possible reasons for the reduced infall velocities are discussed.

  5. A new architecture as transparent electrodes for solar and IR applications based on photonic structures via soft lithography

    SciTech Connect (OSTI)

    Kuang, Ping

    2011-05-15

    Transparent conducting electrodes with the combination of high optical transmission and good electrical conductivity are essential for solar energy harvesting and electric lighting devices. Currently, indium tin oxide (ITO) is used because ITO offers relatively high transparency (>80%) to visible light and low sheet resistance (R{sub s} = 10 ohms/square ({Omega}#2;/?)) for electrical conduction. However, ITO is costly due to limited indium reserves, and it is brittle. These disadvantages have motivated the search for other conducting electrodes with similar or better properties. There has been research on a variety of electrode structures involving carbon nanotube networks, graphene films, nanowire and nanopatterned meshes and grids. Due to their novel characteristics in light manipulation and collection, photonic crystal structures show promise for further improvement. Here, we report on a new architecture consisting of nanoscale high aspect ratio metallic photonic structures as transparent electrodes fabricated via a combination of processes. For (Au) and silver (Ag) structures, the visible light transmission can reach as high as 80%, and the sheet resistance of the structure can be as low as 3.2{Omega}#2;/?. The optical transparency of the high aspect ratio metal structures at visible wavelength range is comparable to that of ITO glass, while their sheet resistance is more than 3 times lower, which indicates a much higher electrical conductivity of the metal structures. Furthermore, the high aspect ratio metal structures have very high infrared (IR) reflection (90%) for the transverse magnetic (TM) mode, which can lead to the development of fabrication of metallic structures as IR filters for heat control applications. Investigations of interdigitated structures based on the high aspect ratio metal electrodes are ongoing to study the feasibility in smart window applications in light transmission modulation.

  6. Dimethyl sulfide substituted mixed-metal clusters: Synthesis, structure, and characterization of HRuCo sub 3 (CO) sub 11 (SMe sub 2 ) and (HRuRh sub 3 (CO) sub 9 ) sub 2 (SMe sub 2 ) sub 3

    SciTech Connect (OSTI)

    Rossi, S.; Pursianinen, J.; Ahlgren, M.; Pakkanen, T.A. (Univ. of Joensuu (Finland))

    1990-02-01

    Ligand substitution reactions of dimethyl sulfide with mixed-metal clusters are described. The clusters HRuCo{sub 3}(CO){sub 11}(SMe{sub 2}) (1) and (HRuRh{sub 3}(CO){sub 9}){sub 2}(SMe{sub 2}){sub 3} (2) have been prepared by reactions of SMe{sub 2} with the neutral parent clusters. Their crystal structures have been established: 1, monoclinic, space group P2{sub 1}/n, a = 11.459 (5) {angstrom}, b = 12.484 (4) {angstrom}, c = 14.384 (4) {angstrom}, {beta} = 96.40 (3){degree}, Z = 4; 2, trigonal, space group R3c, a = 13.181 (7) {angstrom}, {alpha} = 75.54 (5){degree}, Z = 2. Dimethyl sulfide coordinates terminally as a two-electron donor on basal cobalt in 1 and as a bridging four-electron donor causing unusual dimerization of clusters in 2. The carbonyl arrangement of the parent clusters was not changed during the ligand substitution, and hydride ligands bridge the three basal metals in both compounds.

  7. Geva, Shlomo (2007) GPX -Gardens Point XML IR at INEX 2006. In Fuhr, Norbert and Lalmas, Mounia and Trotman, Andrew, Eds.

    E-Print Network [OSTI]

    Liang, Huizhi "Elly"

    2007-01-01

    and its evolution documented in the annual workshop proceedings. The reader is invited to read the 2004 XML IR. The choice is motivated by the extensive off the shelf functionality of a DBMS and ease mechanisms that the DBMS supports by using minimal footprint embedded mode executables. The software that we

  8. Voorkennis chemie voor 1 Ba Bio-ir, Chemie, Fysica en sterrenkunde Voor meer informatie: contacteer csb.etterbeek@vub.ac.be

    E-Print Network [OSTI]

    Einmahl, Uwe

    Voorkennis chemie voor 1 Ba Bio-ir, Chemie, Fysica en sterrenkunde Voor meer informatie: contacteer verwacht wordt bij aanvang van een studie bachelor Bio-ingenieurswetenschappen, Chemie of Fysica en, telkens geïllustreerd met een of meerdere voorbeeldopgaven. 1. Elementaire chemie en chemisch rekenen 1

  9. Growth of Dome-Shaped Carbon Nanoislands on Ir(111): The Intermediate between Carbidic Clusters and Quasi-Free-Standing Graphene

    E-Print Network [OSTI]

    Alfè, Dario

    and Quasi-Free-Standing Graphene Paolo Lacovig,1 Monica Pozzo,2 Dario Alfe`,2 Paolo Vilmercati,3 of a long-range ordered graphene layer on Ir(111) assume a peculiar domelike shape. The understanding coupled carbidic carbon and a quasi-free-standing graphene layer, can provide information for a rational

  10. arXiv:1307.1718v1[cs.IR]5Jul2013 Graph-based Approach to Automatic Taxonomy Generation (GraBTax)

    E-Print Network [OSTI]

    Giles, C. Lee

    arXiv:1307.1718v1[cs.IR]5Jul2013 Graph-based Approach to Automatic Taxonomy Generation (Gra in optimizing the structure of the taxonomy. To automatically generate topic-dependent taxonomies from a large with Wikipedia categories. 1 Introduction A taxonomy organizes concepts into a hierarchical structure, where

  11. Precise measurement of alpha(K) for the M4 transition from Ir-193(m): A test of internal-conversion theory 

    E-Print Network [OSTI]

    Nica, N.; Hardy, John C.; Iacob, VE; Raman, S.; Nestor, CW; Trzhaskovskaya, MB.

    2004-01-01

    The 10.5-day isomer in Ir-193 decays by a single 80.2-keV M4 transition directly to the ground state of that nucleus. We have measured the total intensity of K x rays relative to 80.2-keV gamma rays for this transition to ...

  12. Mid-IR spectra of Pre-Main Sequence Herbig stars: an explanation for the non-detections of water lines

    E-Print Network [OSTI]

    Antonellini, S; Lahuis, F; Woitke, P; Thi, W -F; Meijerink, R; Aresu, G; Spaans, M; Güdel, M; Liebhart, A

    2015-01-01

    The mid-IR detection rate of water lines in disks around Herbig stars disks is about 5\\%, while it is around 50\\% for disks around TTauri stars. The reason for this is still unclear. In this study, we want to find an explanation for the different detection rates between low mass and high mass pre-main-sequence stars (PMSs) in the mid-IR regime. We run disk models with stellar parameters adjusted to spectral types B9 through M2, using the radiation thermo-chemical disk modeling code ProDiMo. We produce convolved spectra at the resolution of Spitzer IRS, JWST MIRI and VLT VISIR spectrographs. We apply random noise derived from typical Spitzer spectra for a direct comparison with observations. The strength of the mid-IR water lines correlates directly with the luminosity of the central star. We explored a small parameter space around a standard disk model, considering dust-to-gas mass ratio, disk gas mass, mixing coefficient for dust settling, flaring index, dust maximum size and size power law distribution inde...

  13. Study on the occurrence of spontaneously established perpendicular exchange bias in Co{sub 49}Pt{sub 51}/IrMn bilayers

    SciTech Connect (OSTI)

    Tsai, C. Y.; Lin, K. F. [Graduate Institute of Materials Science and Engineering, National Taiwan University, Taipei 106, Taiwan (China); Hsu, Jen-Hwa, E-mail: jhhsu@phys.ntu.edu.tw [Department of Physics, National Taiwan University, Taipei 106, Taiwan (China); Saravanan, P. [Department of Physics, National Taiwan University, Taipei 106, Taiwan (China); Defence Metallurgical Research Laboratory, Hyderabad 500058 (India)

    2014-05-07

    In this study, perpendicular exchange bias (PEB) effect in the as-grown Co{sub 49}Pt{sub 51}/IrMn bilayers was demonstrated at room temperature using single-layered Co{sub 49}Pt{sub 51} alloy thin film as ferromagnetic (FM) layer. Several unusual features were observed in this system, viz.,: (i) the PEB was spontaneously established without any external magnetic field treatments, (ii) single-shifted loops were obtained rather than double-shifted ones, and (iii) the spontaneous PEB effect was accompanied by a reduction in perpendicular coercivity, H{sub c?} from 1024 to 632?Oe. The results of x–ray diffraction revealed the formation of IrMn (111) texture. Training effect studies indicate that the PEB effect is stable in this system with less than 5% variation in PEB value within 15 repetitive scans. Significant reduction in the PEB effect was found for the CoPt/IrMn films either grown or subjected to post-annealing under external magnetic field (H{sub ind}). The thickness dependence of PEB effect with respect to the FM and antiferromagnetic layers were also investigated and a largest PEB value of 533?Oe was obtained for the sample grown with 3-nm thick CoPt and 10-nm thick IrMn layers. The results of present study thus establish an opportunity to realize PEB effect in the absence of external field during fabrication.

  14. Structure and infrared (IR) assignments for the OLED material: N,N-diphenyl-N,N-bis(1-naphthyl)-1,1-biphenyl-4,4/-diamine

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    May 2001 Organic light-emitting diodes (OLEDs) are currently under intense investigation for useStructure and infrared (IR) assignments for the OLED material: N,Nº-diphenyl-N,Nº-bis(1-naphthyl)-1 in OLEDs, such as structure and vibrational modes, will help provide experimental probes which are required

  15. Up-regulation of K{sub ir}2.1 by ER stress facilitates cell death of brain capillary endothelial cells

    SciTech Connect (OSTI)

    Kito, Hiroaki; Yamazaki, Daiju; Department of Biological Chemistry, Kyoto University, Graduate School of Pharmaceutical Sciences, Kyoto; Department of Molecular Neurobiology, Graduate School of Medical Sciences, Nagoya City University, Nagoya ; Ohya, Susumu; Yamamura, Hisao; Asai, Kiyofumi; Imaizumi, Yuji

    2011-07-29

    Highlights: {yields} We found that application of endoplasmic reticulum (ER) stress with tunicamycin to brain capillary endothelial cells (BCECs) induced cell death. {yields} The ER stress facilitated the expression of inward rectifier K{sup +} channel (K{sub ir}2.1) and induced sustained membrane hyperpolarization. {yields} The membrane hyperpolarization induced sustained Ca{sup 2+} entry through voltage-independent nonspecific cation channels and consequently facilitated cell death. {yields} The K{sub ir}2.1 up-regulation by ER stress is, at least in part, responsible for cell death of BCECs under pathological conditions. -- Abstract: Brain capillary endothelial cells (BCECs) form blood brain barrier (BBB) to maintain brain homeostasis. Cell turnover of BCECs by the balance of cell proliferation and cell death is critical for maintaining the integrity of BBB. Here we found that stimuli with tunicamycin, endoplasmic reticulum (ER) stress inducer, up-regulated inward rectifier K{sup +} channel (K{sub ir}2.1) and facilitated cell death in t-BBEC117, a cell line derived from bovine BCECs. The activation of K{sub ir} channels contributed to the establishment of deeply negative resting membrane potential in t-BBEC117. The deep resting membrane potential increased the resting intracellular Ca{sup 2+} concentration due to Ca{sup 2+} influx through non-selective cation channels and thereby partly but significantly regulated cell death in t-BBEC117. The present results suggest that the up-regulation of K{sub ir}2.1 is, at least in part, responsible for cell death/cell turnover of BCECs induced by a variety of cellular stresses, particularly ER stress, under pathological conditions.

  16. The structure and IR signatures of the arginine-glutamate salt bridge. Insights from the classical MD simulations

    SciTech Connect (OSTI)

    Vener, M. V.; Odinokov, A. V.; Wehmeyer, C.; Sebastiani, D.

    2015-06-07

    Salt bridges and ionic interactions play an important role in protein stability, protein-protein interactions, and protein folding. Here, we provide the classical MD simulations of the structure and IR signatures of the arginine (Arg)–glutamate (Glu) salt bridge. The Arg-Glu model is based on the infinite polyalanine antiparallel two-stranded ?-sheet structure. The 1 ?s NPT simulations show that it preferably exists as a salt bridge (a contact ion pair). Bidentate (the end-on and side-on structures) and monodentate (the backside structure) configurations are localized [Donald et al., Proteins 79, 898–915 (2011)]. These structures are stabilized by the short {sup +}N–H?O{sup ?} bonds. Their relative stability depends on a force field used in the MD simulations. The side-on structure is the most stable in terms of the OPLS-AA force field. If AMBER ff99SB-ILDN is used, the backside structure is the most stable. Compared with experimental data, simulations using the OPLS all-atom (OPLS-AA) force field describe the stability of the salt bridge structures quite realistically. It decreases in the following order: side-on > end-on > backside. The most stable side-on structure lives several nanoseconds. The less stable backside structure exists a few tenth of a nanosecond. Several short-living species (solvent shared, completely separately solvated ionic groups ion pairs, etc.) are also localized. Their lifetime is a few tens of picoseconds or less. Conformational flexibility of amino acids forming the salt bridge is investigated. The spectral signature of the Arg-Glu salt bridge is the IR-intensive band around 2200 cm{sup ?1}. It is caused by the asymmetric stretching vibrations of the {sup +}N–H?O{sup ?} fragment. Result of the present paper suggests that infrared spectroscopy in the 2000–2800 frequency region may be a rapid and quantitative method for the study of salt bridges in peptides and ionic interactions between proteins. This region is usually not considered in spectroscopic studies of peptides and proteins.

  17. IRS 16SW - A New Comoving Group of Young Stars in the Central Parsec of the Milky Way

    E-Print Network [OSTI]

    J. R. Lu; A. M. Ghez; S. D. Hornstein; M. Morris; E. E. Becklin

    2005-04-12

    One of the most perplexing problems associated with the supermassive black hole at the center of our Galaxy is the origin of the young stars in its close vicinity. Using proper motion measurements and stellar number density counts based on 9 years of diffraction-limited K(2.2 micron)-band speckle imaging at the W. M. Keck 10-meter telescopes, we have identified a new comoving group of stars, which we call the IRS 16SW comoving group, located 1.9" (0.08 pc, in projection) from the central black hole. Four of the five members of this comoving group have been spectroscopically identified as massive young stars, specifically He I emission-line stars and OBN stars. This is the second young comoving group within the central parsec of the Milky Way to be recognized and is the closest, by a factor of 2, in projection to the central black hole. These comoving groups may be the surviving cores of massive infalling star clusters that are undergoing disruption in the strong tidal field of the central supermassive black hole.

  18. MARCS-Model Stellar Atmospheres, and Their Application to the Photometric Calibration of the Spitzer-IRS

    E-Print Network [OSTI]

    L. Decin; P. W. Morris; P. N. Appleton; V. Charmandaris; L. Armus; J. R. Houck

    2004-06-03

    We describe state-of-the-art MARCS-code model atmospheres generated for a group of A dwarf, G dwarf, and late-G to mid-K giant standard stars, selected to photometrically calibrate the Spitzer-IRS, and compare the synthetic spectra to observations of HR 6688, HR 6705, and HR 7891. The general calibration processes and uncertainties are briefly described, and the differences between various templated composite spectra of the standards are addressed. In particular, a contrast between up-to-date model atmospheres and previously published composite and synthetic spectra is illustrated for wavelength ranges around 8um (where the SiO Delta(v) = 1 band occurs for the cooler standards) and lambda greater than 20um, where the use of the Engelke function will lead to increasingly large discrepancies due to the neglect of gravity in cool stars. At this point, radiometric requirements are being met, absolute flux calibration uncertainties (1-sigma) are ~20% in the SH and LH, and ~15% in the SL and LL data, and order-to-order flux uncertainties are ~10% or less. Iteration between the MARCS model atmosphere inputs and the data processing will improve the S/N ratios and calibration accuracies.

  19. A 0.2 solar mass protostar with a Keplerian disk in the very young L1527 IRS system

    E-Print Network [OSTI]

    Tobin, John J; Chiang, Hsin-Fang; Wilner, David J; Looney, Leslie W; Loinard, Laurent; Calvet, Nuria; D'Alessio, Paola

    2012-01-01

    In their earliest stages, protostars accrete mass from their surrounding envelopes through circumstellar disks. Until now, the smallest observed protostar/envelope mass ratio was ~2.1. The protostar L1527 IRS is thought to be in the earliest stages of star formation. Its envelope contains ~1 solar mass of material within a ~0.05 pc radius, and earlier observations suggested the presence of an edge-on disk. Here we report observations of dust continuum emission and 13CO (J=2-1) line emission from the disk around L1527, from which we determine a protostellar mass of M = 0.19 +/- 0.04 solar masses and a protostar/envelope mass ratio of ~0.2. We conclude that most of the luminosity is generated through the accretion process, with an accretion rate of ~6.6 x 10^-7 solar masses per year. If it has been accreting at that rate through much of its life, its age is ~300,000 yr, though theory suggests larger accretion rates earlier, so it may be younger. The presence of a rotationally--supported disk is confirmed and si...

  20. Noncollinear ferromagnetic easy axes in Py/Ru/FeCo/IrMn spin valves induced by oblique deposition

    SciTech Connect (OSTI)

    Bueno, T. E. P.; Parreiras, D. E.; Gomes, G. F. M.; Krambrock, K.; Paniago, R. [Departamento de Física, ICEx, Universidade Federal de Minas Gerais, 31270-901 Belo Horizonte, MG (Brazil); Michea, S.; Rodríguez-Suárez, R. L. [Centro de Investigación en Nanotecnología y Materiales Avanzados “CIEN-UC,” Pontifícia Universidad Católica de Chile, Casilla 306, Santiago (Chile); Filho, M. S. Araújo; Macedo, W. A. A. [Laboratório de Física Aplicada, Centro de Desenvolvimento da Tecnologia Nuclear, 30123-970 Belo Horizonte, MG (Brazil)

    2014-06-16

    We present an investigation on the magnetic properties of Py/Ru/FeCo/IrMn spin valves grown by dc magnetron sputtering. The sample fabrication setup has two important features, (i) the five magnetron sputtering sources are placed in a cluster flange 72° from each other, and (ii) each source is tilted with respect to the sample normal. In-plane angular dependence of the ferromagnetic resonance (FMR) was used to obtain the relevant magnetic anisotropies, such as uniaxial and exchange bias fields. The oblique deposition geometry employed has induced non-collinear easy axes of the two ferromagnetic (FM) layers, with high uniaxial field strengths. The symmetry shift of the angular dependence of the FMR resonances of the two FM layers gives us directly the angle between the easy axes of FM{sub 1} (Py) and FM{sub 2} (FeCo), which turned out to be the angle between two adjacent sputtering sources. The observations of the present study suggest that, by combining oblique deposition and appropriate angles of incidence of the deposition flux, the uniaxial (and unidirectional) axes of individual FM layers can be precisely engineered in spin valve fabrication.

  1. Using FUV to IR Variability to Probe the Star-Disk Connection in the Transitional Disk of GM Aur

    E-Print Network [OSTI]

    Ingleby, Laura; Calvet, Nuria; Sitko, Michael; Russell, Ray; Champney, Elizabeth

    2015-01-01

    We analyze 3 epochs of ultraviolet (UV), optical and near-infrared (NIR) observations of the Taurus transitional disk GM Aur using the Hubble Space Telescope Imaging Spectrograph (STIS) and the Infrared Telescope Facility SpeX spectrograph. Observations were separated by one week and 3 months in order to study variability over multiple timescales. We calculate accretion rates for each epoch of observations using the STIS spectra and find that those separated by one week had similar accretion rates (~1E-8 solar masses/yr) while the epoch obtained 3 months later had a substantially lower accretion rate (~4E-9 solar masses/yr). We find that the decline in accretion rate is caused by lower densities of material in the accretion flows, as opposed to a lower surface coverage of the accretion columns. During the low accretion rate epoch we also observe lower fluxes at both far UV (FUV) and IR wavelengths, which trace molecular gas and dust in the disk, respectively. We find that this can be explained by a lower dust...

  2. Reliable Identification of Compton-thick Quasars at z~2: Spitzer Mid-IR spectroscopy of HDF-oMD49

    E-Print Network [OSTI]

    D. M. Alexander; R. R. Chary; A. Pope; F. E. Bauer; W. N. Brandt; E. Daddi; M. Dickinson; D. Elbaz; N. A. Reddy

    2008-07-15

    Many models that seek to explain the origin of the unresolved X-ray background predict that Compton-thick Active Galactic Nuclei (AGNs) are ubiquitious at high redshift. However, few distant Compton-thick AGNs have been reliably identified to date. Here we present Spitzer-IRS spectroscopy and 3.6-70um photometry of a z=2.2 optically identified AGN (HDF-oMD49) that is formally undetected in the 2Ms Chandra Deep Field-North (CDF-N) survey. The Spitzer-IRS spectrum and spectral energy distribution of this object is AGN dominated, and a comparison of the energetics at X-ray wavelengths to those derived from mid-infrared (mid-IR) and optical spectroscopy shows that the AGN is intrinsically luminous (L_X~3x10^44 erg/s) but heavily absorbed by Compton-thick material (N_H>>10^24 cm^{-2}); i.e., this object is a Compton-thick quasar. Adopting the same approach that we applied to HDF-oMD49, we found a further six objects at z~2-2.5 in the literature that are also X-ray weak/undetected but have evidence for AGN activity from optical and/or mid-IR spectroscopy, and show that all of these sources are also Compton-thick quasars with L_X>10^44 erg/s. On the basis of the definition of Daddi etal. (2007), these Compton-thick quasars would be classified as mid-IR excess galaxies, and our study provides the first spectroscopic confirmation of Compton-thick AGN activity in a subsample of these z~2 mid-IR bright galaxies. Using the four objects that lie in the CDF-N field, we estimate the space-density of Compton-thick quasars [Phi~(0.7-2.5)x10^-5 Mpc^-3 for L_X>10^44 erg/s objects at z~2-2.5] and show that Compton-thick accretion is as ubiquitious as unobscured accretion in the distant Universe.

  3. THE HST EXTREME DEEP FIELD (XDF): COMBINING ALL ACS AND WFC3/IR DATA ON THE HUDF REGION INTO THE DEEPEST FIELD EVER

    SciTech Connect (OSTI)

    Illingworth, G. D.; Magee, D.; Oesch, P. A. [UCO/Lick Observatory, University of California, Santa Cruz, CA 95064 (United States); Bouwens, R. J.; Labbé, I.; Franx, M. [Leiden Observatory, Leiden University, NL-2300 RA Leiden (Netherlands); Stiavelli, M. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Van Dokkum, P. G. [Department of Astronomy, Yale University, New Haven, CT 06520 (United States); Trenti, M. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 0HA (United Kingdom); Carollo, C. M. [Institute for Astronomy, ETH Zurich, 8092 Zurich (Switzerland); Gonzalez, V., E-mail: gdi@ucolick.org [University of California, Riverside, 900 University Avenue, Riverside, CA 92507 (United States)

    2013-11-01

    The eXtreme Deep Field (XDF) combines data from 10 years of observations with the Hubble Space Telescope Advanced Camera for Surveys (ACS) and the Wide-Field Camera 3 Infra-Red (WFC3/IR) into the deepest image of the sky ever in the optical/near-IR. Since the initial observations of the Hubble Ultra-Deep Field (HUDF) in 2003, numerous surveys and programs, including supernovae follow-up, HUDF09, CANDELS, and HUDF12, have contributed additional imaging data across this region. However, these images have never been combined and made available as one complete ultra-deep image dataset. We combine them now with the XDF program. Our new and improved processing techniques provide higher quality reductions of the total dataset. All WFC3/IR and optical ACS data sets have been fully combined and accurately matched, resulting in the deepest imaging ever taken at these wavelengths, ranging from 29.1 to 30.3 AB mag (5? in a 0.''35 diameter aperture) in 9 filters. The combined image therefore reaches to 31.2 AB mag 5? (32.9 at 1?) for a flat f {sub ?} source. The gains in the optical for the four filters done in the original ACS HUDF correspond to a typical improvement of 0.15 mag, with gains of 0.25 mag in the deepest areas. Such gains are equivalent to adding ?130 to ?240 orbits of ACS data to the HUDF. Improved processing alone results in a typical gain of ?0.1 mag. Our 5? (optical+near-IR) SExtractor catalogs reveal about 14,140 sources in the full field and about 7121 galaxies in the deepest part of the XDF.

  4. A Q-switched Ho:YAG laser assisted nanosecond time-resolved T-jump transient mid-IR absorbance spectroscopy with high sensitivity

    E-Print Network [OSTI]

    Wang, Wei Hua

    dynamical structures and the folding/unfolding kinetics of proteins in solution. A home-built setup of T is composed of a Q-switched Cr, Tm, Ho:YAG laser with an output wavelength at 2.09 µm as the T-jump heating source, and a continuous working CO laser tunable from 1580 to 1980 cm-1 as the IR probe. The results

  5. Near-IR supercontinuum generation based on a telecom single-mode fibre in an all-fibre format, and its power combining

    SciTech Connect (OSTI)

    Rumao Tao; Xiaolin Wang; Xiao, H; Zhou, P; Jing Hou [College of Optoelectronics Science and Engineering, National University of Defense Technology, Changsha, Hunan, 410073 (China)

    2014-04-28

    Near-IR supercontinuum (SC) is generated based on a standard telecommunication single-mode (SM) fibre in an all-fibre format. The observed spectrum covers the spectral range from 1050 nm to 1700 nm. High-efficiency combining of the SC power is demonstrated for the first time, and the spectral SC properties are shown to be maintained after power combining. The results may find applications in sensing, spectroscopy and medicine. (control of laser radiation parameters)

  6. Emission intensity in the visible and IR spectral ranges from Si-based structures formed by direct bonding with simultaneous doping with erbium (Er) and europium (Eu)

    SciTech Connect (OSTI)

    Mezdrogina, M. M., E-mail: margaret.m@mail.ioffe.ru; Kostina, L. S.; Beliakova, E. I.; Kuzmin, R. V. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)] [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)

    2013-09-15

    The photo- and electroluminescence spectra of silicon-based structures formed by direct bonding with simultaneous doping with rare-earth metals are studied. It is shown that emission in the visible and IR spectral ranges can be obtained from n-Si:Er/p-Si and n-Si:Eu/p-Si structures fabricated by the method suggested in the study. The results obtained make this method promising for the fabrication of optoelectronic devices.

  7. Unstable spin-ice order in the stuffed metallic pyrochlore Pr2+xIr2-xO7-?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    MacLaughlin, D. E.; Bernal, O. O.; Shu, Lei; Ishikawa, Jun; Matsumoto, Yosuke; Wen, Jia -Jia; Mourigal, Martin P.; Stock, C.; Ehlers, Georg; Broholm, C. L.; et al

    2015-08-24

    Specific heat, elastic neutron scattering, and muon spin rotation experiments have been carried out on a well-characterized sample of “stuffed” (Pr-rich) Pr2+xIr2-xO7-?. Elastic neutron scattering shows the onset of long-range spin-ice “2-in/2-out” magnetic order at 0.93 kelvin, with an ordered moment of 1.7(1) Bohr magnetons per Pr ion at low temperatures. Approximate lower bounds on the correlation length and correlation time in the ordered state are 170 angstroms and 0.7 nanosecond, respectively. Muon spin rotation experiments yield an upper bound 2.6(7) milliteslas on the local field B4floc at the muon site, which is nearly two orders of magnitude smaller thanmore »the expected dipolar field for long-range spin-ice ordering of 1.7-Bohr magneton moments (120–270 milliteslas, depending on the muon site). This shortfall is due in part to splitting of the non-Kramers crystal-field ground-state doublets of near-neighbor Pr3+ ions by the positive-muon-induced lattice distortion. For this to be the only effect, however, ~160 Pr moments out to a distance of ~14 angstroms must be suppressed. An alternative scenario—one consistent with the observed reduced nuclear hyperfine Schottky anomaly in the specific heat—invokes slow correlated Pr-moment fluctuations in the ordered state that average B4floc on the ?SR time scale (~10-7 second), but are static on the time scale of the elastic neutron scattering experiments (~10-9 second). In this picture, the dynamic muon relaxation suggests a Pr3+ 4f correlation time of a few nanoseconds, which should be observable in a neutron spin echo experiment.« less

  8. SU-E-T-457: Design and Characterization of An Economical 192Ir Hemi-Brain Small Animal Irradiator

    SciTech Connect (OSTI)

    Grams, M; Wilson, Z; Sio, T; Beltran, C; Tryggestad, E; Gupta, S; Blackwell, C; McCollough, K; Sarkaria, J; Furutani, K

    2014-06-01

    Purpose: To describe the design and dosimetric characterization of a simple and economical small animal irradiator. Methods: A high dose rate 192Ir brachytherapy source from a commercially available afterloader was used with a 1.3 centimeter thick tungsten collimator to provide sharp beam penumbra suitable for hemi-brain irradiation of mice. The unit is equipped with continuous gas anesthesia to allow robust animal immobilization. Dosimetric characterization of the device was performed with Gafchromic film. The penumbra from the small animal irradiator was compared under similar collimating conditions to the penumbra from 6 MV photons, 6 MeV electrons, and 20 MeV electrons from a linear accelerator as well as 300 kVp photons from an orthovoltage unit and Monte Carlo simulated 90 MeV protons. Results: The tungsten collimator provides a sharp penumbra suitable for hemi-brain irradiation, and dose rates on the order of 200 cGy/minute were achieved. The sharpness of the penumbra attainable with this device compares favorably to those measured experimentally for 6 MV photons, and 6 and 20 MeV electron beams from a linear accelerator. Additionally, the penumbra was comparable to those measured for a 300 kVp orthovoltage beam and a Monte Carlo simulated 90 MeV proton beam. Conclusions: The small animal irradiator described here can be built for under $1,000 and used in conjunction with any commercial brachytherapy afterloader to provide a convenient and cost-effective option for small animal irradiation experiments. The unit offers high dose rate delivery and sharp penumbra, which is ideal for hemi-brain irradiation of mice. With slight modifications to the design, irradiation of sites other than the brain could be accomplished easily. Due to its simplicity and low cost, the apparatus described is an attractive alternative for small animal irradiation experiments requiring a sharp penumbra.

  9. Biomarkers in disk-averaged near-UV to near-IR Earth spectra using Earthshine observations

    E-Print Network [OSTI]

    Slim Hamdani; Luc Arnold; C. Foellmi; J. Berthier; M. Billeres; D. Briot; P. François; P. Riaud; J. Schneider

    2006-09-07

    We analyse the detectability of vegetation on a global scale on Earth's surface. Considering its specific reflectance spectrum showing a sharp edge around 700 nm, vegetation can be considered as a potential global biomarker. This work, based on observational data, aims to characterise and to quantify this signature in the disk-averaged Earth's spectrum. Earthshine spectra have been used to test the detectability of the "Vegetation Red Edge" (VRE) in the Earth spectrum. We obtained reflectance spectra from near UV (320 nm) to near IR (1020 nm) for different Earth phases (continents or oceans seen from the Moon) with EMMI on the NTT at ESO/La Silla, Chile. We accurately correct the sky background and take into account the phase-dependent colour of the Moon. VRE measurements require a correction of the ozone Chappuis absorption band and Rayleigh plus aerosol scattering. Results : The near-UV spectrum shows a dark Earth below 350 nm due to the ozone absorption. The Vegetation Red Edge is observed when forests are present (4.0% for Africa and Europe), and is lower when clouds and oceans are mainly visible (1.3% for the Pacific Ocean). Errors are typically $\\pm0.5$, and $\\pm1.5$ in the worst case. We discuss the different sources of errors and bias and suggest possible improvements. We showed that measuring the VRE or an analog on an Earth-like planet remains very difficult (photometric relative accuracy of 1% or better). It remains a small feature compared to atmospheric absorption lines. A direct monitoring from space of the global (disk-averaged) Earth's spectrum would provide the best VRE follow-up.

  10. IR DIAL performance modeling

    SciTech Connect (OSTI)

    Sharlemann, E.T.

    1994-07-01

    We are developing a DIAL performance model for CALIOPE at LLNL. The intent of the model is to provide quick and interactive parameter sensitivity calculations with immediate graphical output. A brief overview of the features of the performance model is given, along with an example of performance calculations for a non-CALIOPE application.

  11. I\r'

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and MyersHr. Anthony V. Andolina:I *r' ( g-.] ic' fz

  12. Ir I L

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and700, 1.Reports1E~ S·D3GraniteS T *- -I ..' -I

  13. Hf-irJ

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReport for the t-) S/,,5 'a C O M P R E H E N SGwen Nu+'.nop-s'

  14. Ir I L

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReport for the t-) S/,,5 'a C O M P R E H E N SGwen}: .' .LIST OF

  15. IPP RH-TRU Waste Study - Summary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (JournalvivoHighHussein KhalilResearch8

  16. C/2013 R1 (Lovejoy) at IR wavelengths and the variability of CO abundances among Oort Cloud comets

    SciTech Connect (OSTI)

    Paganini, L.; Mumma, M. J.; Villanueva, G. L.; Bonev, B. P.; DiSanti, M. A.; Keane, J. V.; Meech, K. J.; Blake, G. A.; Gibb, E. L.

    2014-08-20

    We report production rates, rotational temperatures, and related parameters for gases in C/2013 R1 (Lovejoy) using the Near InfraRed SPECtrometer at the Keck Observatory, on six UT dates spanning heliocentric distances (R{sub h} ) that decreased from 1.35 AU to 1.16 AU (pre-perihelion). We quantified nine gaseous species (H{sub 2}O, OH*, CO, CH{sub 4}, HCN, C{sub 2}H{sub 6}, CH{sub 3}OH, NH{sub 3}, and NH{sub 2}) and obtained upper limits for two others (C{sub 2}H{sub 2} and H{sub 2}CO). Compared with organics-normal comets, our results reveal highly enriched CO, (at most) slightly enriched CH{sub 3}OH, C{sub 2}H{sub 6}, and HCN, and CH{sub 4} consistent with {sup n}ormal{sup ,} yet depleted, NH{sub 3}, C{sub 2}H{sub 2}, and H{sub 2}CO. Rotational temperatures increased from ?50 K to ?70 K with decreasing R{sub h} , following a power law in R{sub h} of –2.0 ± 0.2, while the water production rate increased from 1.0 to 3.9 × 10{sup 28} molecules s{sup –1}, following a power law in R{sub h} of –4.7 ± 0.9. The ortho-para ratio for H{sub 2}O was 3.01 ± 0.49, corresponding to spin temperatures (T {sub spin}) ? 29 K (at the 1? level). The observed spatial profiles for these emissions showed complex structures, possibly tied to nucleus rotation, although the cadence of our observations limits any definitive conclusions. The retrieved CO abundance in Lovejoy is more than twice the median value for comets in our IR survey, suggesting this comet is enriched in CO. We discuss the enriched value for CO in comet C/2013 R1 in terms of the variability of CO among Oort Cloud comets.

  17. Galaxy And Mass Assembly (GAMA): Panchromatic Data Release (far-UV --- far-IR) and the low-z energy budget

    E-Print Network [OSTI]

    Driver, Simon P; Andrews, Stephen K; Davies, Luke J; Kafle, Prajwal R; Lange, Rebecca; Moffett, Amanda J; Mannering, Elizabeth; Robotham, Aaron S G; Vinsen, Kevin; Alpaslan, Mehmet; Andrae, Ellen; Baldry, Ivan K; Bauer, Amanda E; Bamford, Steven P; Bland-Hawthorn, Joss; Bourne, Nathan; Brough, Sarah; Brown, Michael J I; Cluver, Michelle E; Croom, Scott; Colless, Matthew; Conselice, Christopher J; da Cunha, Elisabete; De Propris, Roberto; Drinkwater, Michael; Dunne, Loretta; Eales, Steve; Edge, Alastair; Frenk, Carlos; Graham, Alister W; Grootes, Meiert; Holwerda, Benne W; Hopkins, Andrew M; Ibar, Edo; van Kampen, Eelco; Kelvin, Lee S; Jarrett, Tom; Jones, D Heath; Lara-Lopez, Maritza A; Lopez-Sanchez, Angel R; Liske, Jochen; Loveday, Jon; Maddox, Steve J; Madore, Barry; Meyer, Martin; Norberg, Peder; Penny, Samantha J; Phillipps, Stephen; Popescu, Cristina; Tuffs, Richard J; Peacock, John A; Pimbblet, Kevin A; Rowlands, Kate; Sansom, Anne E; Seibert, Mark; Smith, Matthew W L; Sutherland, Will J; Taylor, Edward N; Valiante, Elisabetta; Wang, Lingyu; Wilkins, Stephen M; Williams, Richard

    2015-01-01

    We present the GAMA Panchromatic Data Release (PDR) constituting over 230deg$^2$ of imaging with photometry in 21 bands extending from the far-UV to the far-IR. These data complement our spectroscopic campaign of over 300k galaxies, and are compiled from observations with a variety of facilities including: GALEX, SDSS, VISTA, WISE, and Herschel, with the GAMA regions currently being surveyed by VST and scheduled for observations by ASKAP. These data are processed to a common astrometric solution, from which photometry is derived for 221,373 galaxies with renergy balance code MAGPHYS. These measurements are ...

  18. Complete Classification of Four-Dimensional Black Hole and Membrane Solutions in IR-modified Ho\\v{r}ava Gravity

    E-Print Network [OSTI]

    Argüelles, Carlos; Park, Mu-In

    2015-01-01

    Ho\\v{r}ava gravity has been proposed as a renormalizable, higher-derivative gravity without ghost problems, by considering different scaling dimensions for space and time. In the non-relativistic higher-derivative generalization of Einstein gravity, the meaning and physical properties of black hole and membrane space-times are quite different from the conventional ones. Here, we study the singularity and horizon structures of such geometries in IR-modified Ho\\v{r}ava gravity, where the so-called "detailed balance" condition is softly broken in IR. We classify all the viable static solutions without naked singularities and study its close connection to non-singular cosmology solutions. We find that, in addition to the usual point-like singularity at $r=0$, there exists a "surface-like" curvature singularity at finite $r=r_S$ which is the cutting edge of the real-valued space-time. The degree of divergence of such singularities is milder than those of general relativity, and the Hawking temperature of the horiz...

  19. Sub-arcsec mid-IR observations of NGC 1614: Nuclear star-formation or an intrinsically X-ray weak AGN?

    E-Print Network [OSTI]

    Pereira-Santaella, M; Alonso-Herrero, A; Usero, A; Díaz-Santos, T; García-Burillo, S; Alberdi, A; Gonzalez-Martin, O; Herrero-Illana, R; Imanishi, M; Levenson, N A; Pérez-Torres, M A; Almeida, C Ramos

    2015-01-01

    We present new mid-infrared N-band spectroscopy and Q-band photometry of the local luminous infrared galaxy NGC1614, one of the most extreme nearby starbursts. We analyze the mid-IR properties of the nucleus (central 150 pc) and four regions of the bright circumnuclear (diameter~600 pc) star-forming (SF) ring of this object. The nucleus differs from the circumnuclear SF ring by having a strong 8-12 micron continuum (low 11.3 micron PAH equivalent width). These characteristics, together with the nuclear X-ray and sub-mm properties, can be explained by an X-ray weak active galactic nucleus (AGN), or by peculiar SF with a short molecular gas depletion time and producing an enhanced radiation field density. In either case, the nuclear luminosity (L(IR) energy output in this object. We also compare three star-formation rate (SFR) tracers (Pa$\\alpha$, 11.3 micron PAH, and 24 micron emissions) at...

  20. Comparison of 3D dose distributions for HDR {sup 192}Ir brachytherapy sources with normoxic polymer gel dosimetry and treatment planning system

    SciTech Connect (OSTI)

    Senkesen, Oznur; Tezcanli, Evrim; Buyuksarac, Bora; Ozbay, Ismail

    2014-10-01

    Radiation fluence changes caused by the dosimeter itself and poor spatial resolution may lead to lack of 3-dimensional (3D) information depending on the features of the dosimeter and quality assurance of dose distributions for high–dose rate (HDR) iridium-192 ({sup 192}Ir) brachytherapy sources is challenging and experimental dosimetry methods used for brachytherapy sources are limited. In this study, we investigated 3D dose distributions of {sup 192}Ir brachytherapy sources for irradiation with single and multiple dwell positions using a normoxic gel dosimeter and compared them with treatment planning system (TPS) calculations. For dose calibration purposes, 100-mL gel-containing vials were irradiated at predefined doses and then scanned in an magnetic resonance (MR) imaging unit. Gel phantoms prepared in 2 spherical glasses were irradiated with {sup 192}Ir for the calculated dwell positions, and MR scans of the phantoms were obtained. The images were analyzed with MATLAB software. Dose distributions and profiles derived with 1-mm resolution were compared with TPS calculations. Linearity was observed between the delivered dose and the reciprocal of the T2 relaxation time constant of the gel. The x-, y-, and z-axes were defined as the sagittal, coronal, and axial planes, respectively, the sagittal and axial planes were defined parallel to the long axis of the source while the coronal plane was defined horizontally to the long axis of the source. The differences between measured and calculated profile widths of 3-cm source length and point source for 70%, 50%, and 30% isodose lines were evaluated at 3 dose levels using 18 profiles of comparison. The calculations for 3-cm source length revealed a difference of > 3 mm in 1 coordinate at 50% profile width on the sagittal plane and 3 coordinates at 70% profile width and 2 coordinates at 50% and 30% profile widths on the axial plane. Calculations on the coronal plane for 3-cm source length showed > 3-mm difference in 1 coordinate at 50% and 70% and 2 coordinates at 30% profile widths. The point source measurements and calculations for 50% profile widths revealed a difference > 3 mm in 1 coordinate on the sagittal plane and 2 coordinates on the axial plane. The doses of 3 coordinates on the sagittal plane and 4 coordinates on the axial plane could not be evaluated in 30% profile width because of low doses. There was good agreement between the gel dosimetry and TPS results. Gel dosimetry provides dose distributions in all 3 planes at the same time, which enables us to define the dose distributions in any plane with high resolution. It can be used to obtain 3D dose distributions for HDR {sup 192}Ir brachytherapy sources and 3D dose verification of TPS.

  1. Pukaha Mt Bruce Capability Building Project

    E-Print Network [OSTI]

    : _________________________________________________ ISO ID: ____________________________ Department: ___________________________________________ Office Reports Applicant Certification Access privileges are issued to staff members with the understanding

  2. Why Mt Etna? C. Doglioni,1

    E-Print Network [OSTI]

    between these two approaches: (i) evo- lution and dip of the foreland mono- cline are used in Doglioni et

  3. Mt Ranier Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: EnergyInformationOliver, Pennsylvania:(CTI PFAN) | Open

  4. Marysville Mt Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas:Montezuma,InformationIllinois:Martin, Michigan:

  5. Babb, MT Natural Gas Export to Canada

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948 2,724per ThousandLease

  6. Babb, MT Natural Gas Export to Canada

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948 2,724per ThousandLease0 0 20 0 0 122 1996-2014

  7. Havre, MT Natural Gas Exports to Canada

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr MayYear Jan FebMississippi119,456 111,949HOW TO

  8. Havre, MT Natural Gas Exports to Canada

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr MayYear Jan FebMississippi119,456 111,949HOW TO2,504

  9. Controlled Source Audio MT | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, Alabama (Utility Company)| Open(Evans, EtInformation Control of Well KS-8 inSource

  10. Mt Peak Utility | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsourceII Jump to: navigation, searchsource HistoryCharleston,Peak Utility Jump to:

  11. Mt Poso Cogeneration | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsourceII Jump to: navigation, searchsource HistoryCharleston,Peak Utility Jump to:Poso

  12. Category:Billings, MT | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButte County,Camilla, Georgia: Energy014771°,North Dakota:Bonn |NJ

  13. Role of Si/Al Ratio on Immobilization and Stability of Rhodium Complexes on ZSM-5

    E-Print Network [OSTI]

    Long, Brandon

    2009-01-01

    Rhodium complexes within the pores of zeolite ZSM-5 with varying Si/Al ratios (Si/Al 23, Si/Al 50, and Si/Al 280) were prepared from Rh1+(CO)2(C5H7O2), Rh22+(CO2CH3)4, and Rh3+(C5H7O2)3 followed by thermal treatment in He. IR results indicate...

  14. The Calculation Of Absorbing Thin Film Optical Constants And Electronic Structure From Photometric Measures On Domain IR-VIS-UV Using Neural Networks

    SciTech Connect (OSTI)

    Bourouis, Chahrazed [Faculty of science and Engineering University of Guelma, BP 401 Guelma 24000 (Algeria); Meddour, Ahcene [Laboratory of semi conductors, University of Badji Mokhtar, Annaba (Algeria); Moussaoui, Abdelkrim [Electrical Engineering Laboratory (LGEG), University of Guelma, BP 401, 24000 (Algeria)

    2008-09-23

    In this paper a new method using the combination of Neural Networks and the Newton-Raphson algorithm is developped. The technique consists of the use of the solution obtained by Newton-Raphson algorithm between 0.5 and 2.1eV for pure manganese (Mn) and for the amorphous metallic alloy Al{sub 88}Mn{sub 12}, to construct two parts of datasets; the first one is used for training the neural network and the second one for the validation tests. The validated neural network model is applied to the determination of optical constants of the two materials Mn and Al{sub 88}Mn{sub 12} in the range of 0.5 and 6.2eV (IR-VIS-UV). The results obtained over all the studied energy range are used to trace back to dielectric function, optical absorption and electronic structure of the same material. By using the partial solution obtained by Newton-Raphson as a database of the neural network prediction model, it is shown that the obtained results are in accordance with those of the literature which consolidate the efficiency of the suggested approach.

  15. Initial activity of reduced chromia/alumina catalyst in n-butane dehydrogenation monitored by on-line FT-IR gas analysis

    SciTech Connect (OSTI)

    Hakuli, A.; Kytoekivi, A.; Suntola, T.

    1996-06-01

    The initial activity of chromia/alumina catalyst (13 wt% Cr) in n-butane dehydrogenation was studied in a flow reactor at 853 K. The initial activity was determined by on-line FT-IR gas analysis, which enabled sampling of the gaseous product mixture at a time resolution of seconds. The catalysts were processed in repeated cycles of oxidation, reduction, and dehydrogenation using n-butane, methane, hydrogen, or carbon monoxide as reducing agents. With n-butane, methane, and hydrogen and dehydrogenation activity was associated with Cr{sup 3+} species apparently formed in the reduction of high-valence Cr species. The catalyst reduced with carbon monoxide at 853 K showed poor initial selectivity for butenes and, relative to the other catalysts. Simultaneous data relating the initial activity, coke content, and some of the physicochemical properties of the catalyst indicated that the surfaces of all catalysts were modified to some extent by the successive reaction cycles. 33 refs., 7 figs., 2 tabs.

  16. THE NASA AMES PAH IR SPECTROSCOPIC DATABASE VERSION 2.00: UPDATED CONTENT, WEB SITE, AND ON(OFF)LINE TOOLS

    SciTech Connect (OSTI)

    Boersma, C.; Mattioda, A. L.; Allamandola, L. J.; Bauschlicher, C. W. Jr.; Ricca, A.; Cami, J.; Peeters, E.; De Armas, F. Sánchez; Saborido, G. Puerta; Hudgins, D. M.

    2014-03-01

    A significantly updated version of the NASA Ames PAH IR Spectroscopic Database, the first major revision since its release in 2010, is presented. The current version, version 2.00, contains 700 computational and 75 experimental spectra compared, respectively, with 583 and 60 in the initial release. The spectra span the 2.5-4000 ?m (4000-2.5 cm{sup -1}) range. New tools are available on the site that allow one to analyze spectra in the database and compare them with imported astronomical spectra as well as a suite of IDL object classes (a collection of programs utilizing IDL's object-oriented programming capabilities) that permit offline analysis called the AmesPAHdbIDLSuite. Most noteworthy among the additions are the extension of the computational spectroscopic database to include a number of significantly larger polycyclic aromatic hydrocarbons (PAHs), the ability to visualize the molecular atomic motions corresponding to each vibrational mode, and a new tool that allows one to perform a non-negative least-squares fit of an imported astronomical spectrum with PAH spectra in the computational database. Finally, a methodology is described in the Appendix, and implemented using the AmesPAHdbIDLSuite, that allows the user to enforce charge balance during the fitting procedure.

  17. Late time multi wavelength observations of Swift J1644+5734: A luminous optical/IR bump and quiescent X-ray emission

    E-Print Network [OSTI]

    Levan, A J; Brown, G C; Metzger, B D; Page, K L; Cenko, S B; O'Brien, P T; Lyman, J D; Wiersema, K; Stanway, E R; Fruchter, A S; Perley, D A; Bloom, J S

    2015-01-01

    We present late-time multi-wavelength observations of Swift J1644+57, suggested to be a relativistic tidal disruption flare (TDF). Our observations extend to >4 years from discovery, and show that 1.4 years after outburst the relativistic jet switched-off on a timescale less than tens of days, corresponding to a power-law decay faster than $t^{-70}$. Beyond this point weak X-rays continue to be detected at an approximately constant luminosity of $L_X \\sim 5 \\times 10^{42}$ erg s$^{-1}$, and are marginally inconsistent with a continuing decay of $t^{-5/3}$, similar to that seen prior to the switch-off. Host photometry enables us to infer a black hole mass of $M_{BH}=3 \\times 10^6$ M$_{\\odot}$, consistent with the late time X-ray luminosity arising from sub-Eddington accretion onto the black hole in the form of either an unusually optically faint AGN or a slowly varying phase of the transient. Optical/IR observations show a clear bump in the light curve at timescales of 30-50 days, with a peak magnitude (correc...

  18. A near-IR line of Mn I as a diagnostic tool of the average magnetic energy in the solar photosphere

    E-Print Network [OSTI]

    A. Asensio Ramos; M. J. Martinez Gonzalez; A. Lopez Ariste; J. Trujillo Bueno; M. Collados

    2006-12-14

    We report on spectropolarimetric observations of a near-IR line of Mn I located at 15262.702 A whose intensity and polarization profiles are very sensitive to the presence of hyperfine structure. A theoretical investigation of the magnetic sensitivity of this line to the magnetic field uncovers several interesting properties. The most important one is that the presence of strong Paschen-Back perturbations due to the hyperfine structure produces an intensity line profile whose shape changes according to the absolute value of the magnetic field strength. A line ratio technique is developed from the intrinsic variations of the line profile. This line ratio technique is applied to spectropolarimetric observations of the quiet solar photosphere in order to explore the probability distribution function of the magnetic field strength. Particular attention is given to the quietest area of the observed field of view, which was encircled by an enhanced network region. A detailed theoretical investigation shows that the inferred distribution yields information on the average magnetic field strength and the spatial scale at which the magnetic field is organized. A first estimation gives ~250 G for the mean field strength and a tentative value of ~0.45" for the spatial scale at which the observed magnetic field is horizontally organized.

  19. The water abundance behind interstellar shocks: results from $Herschel$/PACS and $Spitzer$/IRS observations of H$_2$O, CO, and H$_2$

    E-Print Network [OSTI]

    Neufeld, David A; Güsten, Rolf; Herczeg, Greg J; Kristensen, Lars; Melnick, Gary J; Nisini, Brunella; Ossenkopf, Volker; Tafalla, Mario; van Dishoeck, Ewine F

    2013-01-01

    We have investigated the water abundance in shock-heated molecular gas, making use of $Herschel$ measurements of far-infrared CO and H$_2$O line emissions in combination with $Spitzer$ measurements of mid-IR H$_2$ rotational emissions. We present far-infrared line spectra obtained with $Herschel$'s PACS instrument in range spectroscopy mode towards two positions in the protostellar outflow NGC 2071 and one position each in the supernova remnants W28 and 3C391. These spectra provide unequivocal detections, at one or more positions, of 12 rotational lines of water, 14 rotational lines of CO, 8 rotational lines of OH (4 lambda doublets), and 7 fine-structure transitions of atoms or atomic ions. We first used a simultaneous fit to the CO line fluxes, along with H$_2$ rotational line fluxes measured previously by $Spitzer$, to constrain the temperature and density distribution within the emitting gas; and we then investigated the water abundances implied by the observed H$_2$O line fluxes. The water line fluxes ar...

  20. Identification of {gamma} rays from {sup 172}Au and {alpha} decays of {sup 172}Au, {sup 168}Ir, and {sup 164}Re

    SciTech Connect (OSTI)

    Hadinia, B.; Cederwall, B.; Andgren, K.; Baeck, T.; Johnson, A.; Khaplanov, A.; Wyss, R.; Page, R. D.; Grahn, T.; Paul, E. S.; Sandzelius, M.; Scholey, C.; Greenlees, P. T.; Jakobsson, U.; Jones, P. M.; Julin, R.; Juutinen, J.; Ketelhut, S.; Leino, M.; Nyman, M.

    2009-12-15

    The very neutron deficient odd-odd nucleus {sup 172}Au was studied in reactions of 342 and 348 MeV {sup 78}Kr beams with an isotopically enriched {sup 96}Ru target. The {alpha} decays previously reported for {sup 172}Au were confirmed and the decay chain extended down to {sup 152}Tm through the discovery of a new {alpha}-decaying state in {sup 164}Re[E{sub {alpha}}=5623(10) keV; t{sub 1/2}=864{sub -110}{sup +150} ms; b{sub {alpha}}=3(1)%]. Fine structure in these {alpha} decays of {sup 172}Au and {sup 168}Ir were identified. A new {alpha}-decaying state was also observed and assigned as the ground state in {sup 172}Au[E{sub {alpha}}=6762(10) keV; t{sub 1/2}=22{sub -5}{sup +6} ms]. This decay chain was also correlated down to {sup 152}Tm through previously reported {alpha} decays. Prompt {gamma} rays from excited states in {sup 172}Au have been identified using the recoil-decay tagging technique. The partial level scheme constructed for {sup 172}Au indicates that it has an irregular structure. Possible configurations of the {alpha}-decaying states in {sup 172}Au are discussed in terms of the systematics of nuclei in this region and total Routhian surface calculations.

  1. Highly robust hydrogen generation by bio-inspired Ir complexes for dehydrogenation of formic acid in water: Experimental and theoretical mechanistic investigations at different pH

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Wan -Hui; Fujita, Etsuko; Ertem, Mehmed Z.; Xu, Shaoan; Onishi, Naoya; Manaka, Yuichi; Suna, Yuki; Kambayashi, Hide; Muckerman, James T.; Himeda, Yuichiro

    2015-07-30

    Hydrogen generation from formic acid (FA), one of the most promising hydrogen storage materials, has attracted much attention due to the demand for the development of renewable energy carriers. Catalytic dehydrogenation of FA in an efficient and green manner remains challenging. Here, we report a series of bio-inspired Ir complexes for highly robust and selective hydrogen production from FA in aqueous solutions without organic solvents or additives. One of these complexes bearing an imidazoline moiety (complex 6) achieved a turnover frequency (TOF) of 322,000 h?¹ at 100 °C, which is higher than ever reported. The novel catalysts are very stablemore »and applicable in highly concentrated FA. For instance, complex 3 (1 ?mol) affords an unprecedented turnover number (TON) of 2,050,000 at 60 °C. Deuterium kinetic isotope effect experiments and density functional theory (DFT) calculations employing a “speciation” approach demonstrated a change in the rate-determining step with increasing solution pH. This study provides not only more insight into the mechanism of dehydrogenation of FA but also offers a new principle for the design of effective homogeneous organometallic catalysts for H? generation from FA.« less

  2. Penetration depth and absorption mechanisms of spin currents in Ir{sub 20}Mn{sub 80} and Fe{sub 50}Mn{sub 50} polycrystalline films by ferromagnetic resonance and spin pumping

    SciTech Connect (OSTI)

    Merodio, P.; Ghosh, A.; Lemonias, C.; Gautier, E.; Ebels, U.; Chshiev, M.; Béa, H. E-mail: helene.bea@cea.fr; Baltz, V. E-mail: helene.bea@cea.fr

    2014-01-20

    Spintronics relies on the spin dependent transport properties of ferromagnets (Fs). Although antiferromagnets (AFs) are used for their magnetic properties only, some fundamental F-spintronics phenomena like spin transfer torque, domain wall motion, and tunnel anisotropic magnetoresistance also occur with AFs, thus making AF-spintronics attractive. Here, room temperature critical depths and absorption mechanisms of spin currents in Ir{sub 20}Mn{sub 80} and Fe{sub 50}Mn{sub 50} are determined by F-resonance and spin pumping. In particular, we find room temperature critical depths originating from different absorption mechanisms: dephasing for Ir{sub 20}Mn{sub 80} and spin flipping for Fe{sub 50}Mn{sub 50}.

  3. Measurement of the 187Re(?,n)190Ir reaction cross section at sub-Coulomb energies using the Cologne Clover Counting Setup

    E-Print Network [OSTI]

    P. Scholz; A. Endres; A. Hennig; L. Netterdon; H. W. Becker; J. Endres; J. Mayer; U. Giesen; D. Rogalla; F. Schlüter; S. G. Pickstone; K. O. Zell; A. Zilges

    2015-01-07

    Uncertainties in adopted models of particle+nucleus optical-model potentials directly influence the accuracy in the theoretical predictions of reaction rates as they are needed for reaction-network calculations in, for instance, {\\gamma}-process nucleosynthesis. The improvement of the {\\alpha}+nucleus optical-model potential is hampered by the lack of experimental data at astrophysically relevant energies especially for heavier nuclei. Measuring the Re187({\\alpha},n)Ir190 reaction cross section at sub-Coulomb energies extends the scarce experimental data available in this mass region and helps understanding the energy dependence of the imaginary part of the {\\alpha}+nucleus optical-model potential at low energies. Applying the activation method, after the irradiation of natural rhenium targets with {\\alpha}-particle energies of 12.4 to 14.1 MeV, the reaction yield and thus the reaction cross section were determined via {\\gamma}-ray spectroscopy by using the Cologne Clover Counting Setup and the method of {\\gamma}{\\gamma} coincidences. Cross-section values at five energies close to the astrophysically relevant energy region were measured. Statistical model calculations revealed discrepancies between the experimental values and predictions based on widely used {\\alpha}+nucleus optical-model potentials. However, an excellent reproduction of the measured cross-section values could be achieved from calculations based on the so-called Sauerwein-Rauscher {\\alpha}+nucleus optical-model potential. The results obtained indicate that the energy dependence of the imaginary part of the {\\alpha}+nucleus optical-model potential can be described by an exponential decrease. Successful reproductions of measured cross sections at low energies for {\\alpha}-induced reactions in the mass range 141{\\leq}A{\\leq}187 confirm the global character of the Sauerwein-Rauscher potential.

  4. Busch Gardens IRS Tax Forms

    E-Print Network [OSTI]

    Sin, Peter

    changes. Day/Time Activity Location/Cost Monday 7pm - 10pm Monday Mixer (Nicole) Meet at the Starbucks 7pm - 10pm Coffee Talk (Luis) Meet at the Starbucks on Archer Rd. Bring $3 - $5 for coffee or food

  5. PuppyIR: Design Report

    E-Print Network [OSTI]

    Glassey, R.

    Glassey,R. Azzopardi,L. Garrido,J. DCS Technical Report Series Dept of Computing Science, University of Glasgow

  6. Broadly tunable picosecond IR source

    DOE Patents [OSTI]

    Campillo, Anthony J. (Nesconset, NY); Hyer, Ronald C. (Los Alamos, NM); Shapiro, Stanley J. (Los Alamos, NM)

    1982-01-01

    A picosecond traveling-wave parametric device capable of controlled spectral bandwidth and wavelength in the infrared is reported. Intense 1.064 .mu.m picosecond pulses (1) pass through a 4.5 cm long LiNbO.sub.3 optical parametric oscillator crystal (2) set at its degeneracy angle. A broad band emerges, and a simple grating (3) and mirror (4) arrangement is used to inject a selected narrow-band into a 2 cm long LiNbO.sub.3 optical parametric amplifier crystal (5) along a second pump line. Typical input energies at 1.064 .mu.m along both pump lines are 6-8 mJ for the oscillator and 10 mJ for the amplifier. This yields 1 mJ of tunable output in the range 1.98 to 2.38 .mu.m which when down-converted in a 1 cm long CdSe crystal mixer (6) gives 2 .mu.J of tunable radiation over the 14.8 to 18.5 .mu.m region. The bandwidth and wavelength of both the 2 and 16 .mu.m radiation output are controlled solely by the diffraction grating.

  7. Broadly tunable picosecond ir source

    DOE Patents [OSTI]

    Campillo, A.J.; Hyer, R.C.; Shapiro, S.L.

    1980-04-23

    A picosecond traveling-wave parametric device capable of controlled spectral bandwidth and wavelength in the infrared is reported. Intense 1.064 ..mu..m picosecond pulses (1) pass through a 4.5 cm long LiNbO/sub 3/ optical parametric oscillator crystal (2) set at its degeneracy angle. A broad band emerges, and a simple grating (3) and mirror (4) arrangement is used to inject a selected narrow-band into a 2 cm long LiNbO/sub 3/ optical parametric amplifier crystal (5) along a second pump line. Typical input energies at 1.064 ..mu..m along both pump lines are 6 to 8 mJ for the oscillator and 10 mJ for the amplifier. This yields 1 mJ of tunable output in the range 1.98 to 2.38 ..mu..m which when down-converted in a 1 cm long CdSe crystal mixer (6) gives 2 ..mu..J of tunable radiation over the 14.8 to 18.5 ..mu..m region. The bandwidth and wavelength of both the 2 and 16 ..mu..m radiation output are controlled solely by the diffraction grating.

  8. Microsoft Word - S07118_IR

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbinsMonumentThird6010 Task U.S. DepartmentCentralAnnual

  9. ARM - Datastreams - goes7ir

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve4AJ01) (See EnergyCurrent : 0.0September4 Documentationir

  10. 2.8 Mt5.6 Mt Turning over a New Leaf

    E-Print Network [OSTI]

    to local communities and other stewards of our natural resources. Forest Trends analyzes strategic market natural ecosystems, which provide life-sustaining processes, by promoting incentives stemming from a broad 19th Street, NW 4th floor Washington, DC 20036 info@ecosystemmarketplace.com www

  11. SU-E-T-223: Investigation of the Accuracy of Two-Dimensional Dose Distributions Measurement From High-Dose-Rate Brachytherapy Ir-192 Source Using Multiple-Diode-Array Detector (MapCheck2)

    SciTech Connect (OSTI)

    Taguenang, J; De La Fuente, T Herman; Ahmad, S; Ali, I [Oklahoma Univ. Health Science Ctr., Oklahoma City, OK (United States)

    2014-06-01

    Purpose: To investigate the dosimetric accuracy of multiple-diode-array detector (Mapcheck2) for high-dose-rate brachytherapy Ir-192 source. The two-dimensional (2D) dose distributions measured with MapCheck2 were validated with EBT2 Gafchromic film measurement and AAPM task-group- 43 (TG-43) modeling. Methods: 2D-dose distributions from Ir-192 source were measured with MapCheck2 and EBT2-films. MapCheck2 response was corrected for effects: directional dependence, diode and phantom heterogeneity. Optical density growth of the film was controlled by synchronized scanning of the film exposed to Ir-192 and calibration films exposed to 6 MV linac beams. Similarly, MapCheck2 response was calibrated to dose using 6 MV beams. An empirical model was developed for the dose distributions measured with Mapcheck2 that considered directional, diode and phantom heterogeneity corrections. The dose deposited in solid-state-detectors was modeled using a cavity theory model for the diode. This model was then validated with measurements using EBT2-films and calculations with TG-43. Results: The response of MapCheck2 has been corrected for different effects including: (a) directional dependence of 0–20% over angular range 0o–90o, (b) phantom heterogeneity (3%) and (c) diode heterogeneity (9%). The corrected dose distributions measured with MapCheck2 agreed well with the measured dose distributions from EBT2-film and with calculations using TG-43 within 5% over a wide range of dose levels and rates. The advantages of MapCheck2 include less noisy, linear and stable response compared with film. The response of MapCheck2 exposed to 192Ir-source showed no energy dependence similar to its response to MV energy beam. Detection spatial-resolution of individual diodes was 0.8×0.8 mm2, however, 2DMapCheck2 resolution is limited by distance between diodes (7.07 mm). Conclusion: The dose distribution measured with MapCheck2 agreed well within 5% with that measured using EBT2-films; and calculations with TG- 43. Considering correction of artifacts, MapCheck2 provides a compact, practical and accurate dosimetric tool for measurement of 2D-dose distributions for brachytherapy Ir-192.

  12. Ternary rare-earth ruthenium and iridium germanides RE{sub 3}M{sub 2}Ge{sub 3} (RE=Y, Gd–Tm, Lu; M=Ru, Ir)

    SciTech Connect (OSTI)

    Oliynyk, Anton O.; Stoyko, Stanislav S.; Mar, Arthur, E-mail: arthur.mar@ualberta.ca

    2013-06-15

    Through arc-melting reactions of the elements and annealing at 800 °C, the ternary rare-earth germanides RE{sub 3}Ru{sub 2}Ge{sub 3} and RE{sub 3}Ir{sub 2}Ge{sub 3} have been prepared for most of the smaller RE components (RE=Y, Gd–Tm, Lu). In the iridium-containing reactions, the new phases RE{sub 2}IrGe{sub 2} were also generally formed as by-products. Powder X-ray diffraction revealed orthorhombic Hf{sub 3}Ni{sub 2}Si{sub 3}-type structures (space group Cmcm, Z=4) for RE{sub 3}M{sub 2}Ge{sub 3} (M=Ru, Ir) and monoclinic Sc{sub 2}CoSi{sub 2}-type structures (space group C2/m, Z=4) for RE{sub 2}IrGe{sub 2}. Full crystal structures were determined by single-crystal X-ray diffraction for all members of RE{sub 3}Ru{sub 2}Ge{sub 3} (a=4.2477(6) Å, b=10.7672(16) Å, c=13.894(2) Å for RE=Y; a=4.2610(3)–4.2045(8) Å, b=10.9103(8)–10.561(2) Å, c=14.0263(10)–13.639(3) Å in the progression of RE from Gd to Lu) and for Tb{sub 3}Ir{sub 2}Ge{sub 3} (a=4.2937(3) Å, b=10.4868(7) Å, c=14.2373(10) Å). Both structures can be described in terms of CrB- and ThCr{sub 2}Si{sub 2}-type slabs built from Ge-centred trigonal prisms. However, band structure calculations on Y{sub 3}Ru{sub 2}Ge{sub 3} support an alternative description for RE{sub 3}M{sub 2}Ge{sub 3} based on [M{sub 2}Ge{sub 3}] layers built from linked MGe{sub 4} tetrahedra, which emphasizes the strong M–Ge covalent bonds present. The temperature dependence of the electrical resistivity of RE{sub 3}Ru{sub 2}Ge{sub 3} generally indicates metallic behaviour but with low-temperature transitions visible for some members (RE=Gd, Tb, Dy) that are probably associated with magnetic ordering of the RE atoms. Anomalously, Y{sub 3}Ru{sub 2}Ge{sub 3} exhibits semiconductor-like behaviour of uncertain origin. Magnetic measurements on Dy{sub 3}Ru{sub 2}Ge{sub 3} reveal antiferromagnetic ordering at 3 K and several unusual field-dependent transitions suggestive of complex spin reorientation processes. - Graphical abstract: RE{sub 3}M{sub 2}Ge{sub 3} (M=Ru, Ir) adopts the Hf{sub 3}Ni{sub 2}Si{sub 3}-type structure containing slabs built up from Ge-centred trigonal prisms. - Highlights: • Crystal structures of RE{sub 3}Ru{sub 2}Ge{sub 3} (RE=Y, Gd–Tm, Lu) and Tb{sub 3}Ir{sub 2}Ge{sub 3} were determined. • Strong M–Ge covalent bonds were confirmed by band structure calculations. • Most RE{sub 3}Ru{sub 2}Ge{sub 3} members except Y{sub 3}Ru{sub 2}Ge{sub 3} exhibit metallic behaviour. • Dy{sub 3}Ru{sub 2}Ge{sub 3} displays unusual field-dependent magnetic transitions.

  13. IRS Updates IRS2Go Smartphone App The IRS recently released IRS2Go 5.0, an update to the only official IRS smartphone

    E-Print Network [OSTI]

    Income Tax Assistance and the Tax Counseling for the Elderly programs offer free tax help for those who during the tax season and three times a week in the summer. Special Edition Tax Tips highlight important

  14. Decay of the 9/2{sup -} isomer in {sup 181}Tl and mass determination of low-lying states in {sup 181}Tl, {sup 177}Au, and {sup 173}Ir

    SciTech Connect (OSTI)

    Andreyev, A. N.; Antalic, S.; Saro, S.; Ackermann, D.; Comas, V. F.; Heinz, S.; Heredia, J. A.; Hessberger, F. P.; Khuyagbaatar, J.; Kojouharov, I.; Kindler, B.; Lommel, B.; Mann, R.; Cocolios, T. E.; Elseviers, J.; Huyse, M.; Van Duppen, P. Van; Venhart, M.; Franchoo, S.; Hofmann, S.

    2009-08-15

    A detailed spectroscopic study of the neutron-deficient isotope {sup 181}Tl and the daughter of its {alpha} decay, {sup 177}Au, has been performed in the complete fusion reaction {sup 40}Ca+{sup 144}Sm{yields}{sup 184}Pb* at the velocity filter SHIP (GSI). The mass excess, excitation energy, and decay scheme of the isomeric 1.40(3) ms, 9/2{sup -} intruder state in {sup 181}Tl have been established for the first time. These results solve a long-standing puzzle of the unrealistically large reduced {alpha}-decay width of this isomer. Based on this, the previously unknown masses of the long-lived isomeric states in {sup 177}Au and {sup 173}Ir have been derived. In turn, it now allows the excitation energies of previously identified bands in {sup 177}Au and {sup 173}Ir to be deduced and compared with theoretical predictions. First measurements of {alpha}-decay branching ratios for {sup 181}Tl{sup m} and {sup 177}Au{sup m,g} are also reported.

  15. Retrieval and Repackaging of RH-TRU Waste - General Presentation...

    Office of Environmental Management (EM)

    * Characterization : - HGRS ( High Resolution Gamma Spectroscopy) - IPAN ( Imaging Passive- Active Neutron) * Packaging (if needed) Control Room Electrical Rooms Ventilation...

  16. Step enhanced dehydrogenation of ethanol on Rh Andrea Resta a

    E-Print Network [OSTI]

    Li, Weixue

    , Lund University, Box 118, S-22100 Lund, Sweden b State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China a r t i c l e i n f

  17. R.H. Ottewill A.B. Schofield

    E-Print Network [OSTI]

    Schofield, Andrew B.

    -[butylmethacrylate] particles as the host material and poly-[styrene] particles for engulf- ment. Initially, anionic poly-[styrene occurred. Key words Engulfment ­ interfacial energy ­ heterocoagulation ­ Poly- [styrene] ­ Poly to be engulfed were poly-(styrene), PS, prepared by an emulsion polym

  18. WIPP RH-TRU Waste Study - Notice To Users

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired SolarAbout /Two0 -UsingHeatInformationDevelopmentProgram*5

  19. ARM - PI Product - Radiosondes Corrected for Inaccuracy in RH Measurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow, Alaska OutreachCalendar NSAProductsMerged and correctedProductsRadiosondes

  20. Microsoft Word - MPUR_Feb2011_final_rh.docx

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets See(STEO) Highlights1 M68October7 1071

  1. Universite Paris 7-Denis Diderot Alg`ebre Annee 2007-08 M1 mathematiques

    E-Print Network [OSTI]

    Merel, Loïc - Institut de Mathématiques de Jussieu, Université Paris 7

    ¦§i ¡¥ ¼ E¸ °5° ¾¤Eh°Q«E%ªEºV¦§¤E¥6 m¥¥b¤h%ªE¦§h¾« o¢¤h °y m¦®T¦ m¦§h ¡ib5 ¡r¤h³¥ Ãæf¾° Ë 5°¹ m¥«h º

  2. Vertical Electrical Sounding Configurations At Mt Princeton Hot Springs

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-EnhancingEt Al.,Turin, NewArkansas:Standards Jump to:VernonWisconsin:Labs LLP

  3. Integrated Dense Array and Transect MT Surveying at Dixie Valley...

    Open Energy Info (EERE)

    Dixie Valley Geothermal Area, Nevada- Structural Controls, Hydrothermal Alteration and Deep Fluid Sources Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  4. Improving Machine Tool Interoperability Using Standardized Interface Protocols: MT Connect

    E-Print Network [OSTI]

    Vijayaraghavan, Athulan; Sobel, Will; Fox, Armando; Dornfeld, David; Warndorf, Paul

    2008-01-01

    23-26, 2008 IMPROVING MACHINE TOOL INTEROPERABILITY USINGMTConnect TM data from a machine tool for process planningpotential of improved machine-tool interoperability through

  5. Compound and Elemental Analysis At Mt St Helens Area (Shevenell...

    Open Energy Info (EERE)

    Date Usefulness not indicated DOE-funding Unknown References L. Shevenell, F. Goff (2000) Temporal Geochemical Variations In Volatile Emissions From Mount St Helens, Usa,...

  6. Northwest Distributed/Community Wind Workgroup Meeting- MT

    Broader source: Energy.gov [DOE]

    The Northwest Wind Resource and Action Center, which is partially funded by the U.S. Department of Energy, will facilitate a workgroup meeting for stakeholders involved in the distributed and...

  7. Thermal Gradient Holes At Mt Princeton Hot Springs Geothermal...

    Open Energy Info (EERE)

    the area References J. Held, F. Henderson (2012) New developments in Colorado geothermal energy projects Additional References Retrieved from "http:en.openei.orgw...

  8. Deriving Semantic Knowledge from Descriptive Texts using an MT System

    E-Print Network [OSTI]

    Spirtes, Peter

    , instantiating concepts in an upper model for the electric power domain. In an extension of the basic system, we statements for entry into the Ontology Works electrical power factbase [9]. The system was extended to allow and textual description for a model of the North­ west electric power grid [10]. A set of texts were written

  9. Improving Machine Tool Interoperability Using Standardized Interface Protocols: MT Connect

    E-Print Network [OSTI]

    Vijayaraghavan, Athulan; Sobel, Will; Fox, Armando; Dornfeld, David; Warndorf, Paul

    2008-01-01

    interoperability enabled by MTConnect TM can provide the mechanism for process and system monitoring and optimization with respect to energy and

  10. Analysis of borehole temperature data from the Mt. Princeton...

    Open Energy Info (EERE)

    Colorado (abstract only) Author P. Morgan Conference AAPG Rocky Mountain Meeting; Salt Lake County, Utah; 10811 Published AAPG Rocky Mountain Meeting, 2013 DOI Not Provided...

  11. Urdu Localization Project: Lexicon, MT and TTS (ULP) Sarmad HUSSAIN

    E-Print Network [OSTI]

    , Pakistan sarmad.hussain@nu.edu.pk Abstract Pakistan has a population of 140 million speaking more than 56, also the national language of Pakistan. Being a developing population, Pakistani people need access-10% of these people are familiar with English. Therefore, Government of Pakistan has embarked on a project which

  12. School of Mathematics and Statistics MT5824 Topics in Groups

    E-Print Network [OSTI]

    St Andrews, University of

    .] Deduce that GpG (G). Use the previous question to show that (G) = GpG. Show that G can be generated

  13. Compound and Elemental Analysis At Mt St Helens Area (Shevenell...

    Open Energy Info (EERE)

    not indicated DOE-funding Unknown References Lisa Shevenell, Fraser Goff (1995) Evolution Of Hydrothermal Waters At Mount St Helens, Washington, Usa Additional References...

  14. Todd J. Kaiser Montana State University, Bozeman, MT

    E-Print Network [OSTI]

    Kaiser, Todd J.

    and Actuators Workshop, pp 85-88, June 2000. E. Selected Invited Presentations · "Solar Cell Basics for Teachers Square Cambridge, MA 02139 C. Selected Journal Publications · "A Wireless Sensor Interrogation Design for Passive Resonant Frequency Sensors using Frequency Modulation Spectroscopy," Brian Peterson, Andrew Olson

  15. DLT -AN INDUSTRIAL R & D PROJECT FOR MULTILINGUAL MT

    E-Print Network [OSTI]

    by an ophthalmo-logist towards the end of the nineteenth century) is not usually considered a respectable object-term development and maintenance of a complex translation and world knowledge system is a task that can only

  16. *MT 4S1SGOO ^ Ris-M-2672

    E-Print Network [OSTI]

    . APPLICATIONS OF NEUTRON RADIOGRAPHY 14 7.1. Nuclear industry 16 Nuclear fuel 16 General 23 7.2. Industrial of application of neutron radiography in industry and the nuclear field. October 1987 Risø National Laboratory 26 Real-time 26 Engine fluids 26 7.3. Non-industrial applications 27 Biology, medicine and dentistry

  17. Extrinsic Evaluation of Patent MT: Review and Commentary

    E-Print Network [OSTI]

    Oard, Doug

    ." The National Institute of Informatics (NII) Testbeds and Community for Information Access Research (NTCIR these tasks into three broad categories (expressed here using specific examples of languages and sources College Park, MD 20742 USA oard@umd.edu Noriko Kando National Institute of Informatics Tokyo, Japan kando

  18. Seismicity induced by seasonal groundwater recharge at Mt. Hood, Oregon

    E-Print Network [OSTI]

    Manga, Michael

    and narrow-width pore-fluid pressure signal. Time delays between this seasonal groundwater recharge-fluid pressure fraction, PP/P0W0.1, of the applied near-surface pore-fluid pressure perturbation, P0W0.1 MPa Elsevier B.V. All rights reserved. Keywords: hydroseismicity; groundwater; pore-£uid pressure; permeability

  19. Statistical Theory MT 2009 Problems 1: Solution sketches

    E-Print Network [OSTI]

    Reinert, Gesine

    =1 Xi and put T = X 1 n-1 n i=1(Xi - X)2 . Show that T is an ancillary statistic. What does this say the distribution of T does not depend on neither; it is an ancillary statistic. Thus a t-test based on exponential of A is independent of (so A is an ancillary statistic). c) Show that any value in the interval x(n) - 1 2 , x(1) + 1

  20. Self Potential At Mt Princeton Hot Springs Geothermal Area (Richards...

    Open Energy Info (EERE)

    2008 - 2010 Usefulness useful DOE-funding Unknown Exploration Basis Determination of groundwater flux patterns Notes Researchers collected 2700 SP measurements. Equilibrium...