National Library of Energy BETA

Sample records for residual distillate lpg

  1. "Table A10. Total Consumption of LPG, Distillate Fuel Oil, and Residual Fuel"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page|Monthly","10/2015","1/15/1981"0. Total Consumption of LPG, Distillate Fuel Oil, and Residual

  2. "Table A2. Total Consumption of LPG, Distillate Fuel Oil, and Residual Fuel"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page|Monthly","10/2015","1/15/1981"0. Total Consumption of LPG, Distillate Fuel Oil, and6.. Total

  3. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    U.S. Energy Information Administration (EIA) Indexed Site

    AdministrationPetroleum Marketing Annual 1999 441 Table A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon...

  4. Catalytic conversion of LPG

    SciTech Connect (OSTI)

    Pujado, P.R.; Vora, B.V.; Mowry, J.R.; Anderson, R.F.

    1986-01-01

    The low reactivity of light paraffins has long hindered their utilization as petrochemical feedstocks. Except for their use in ethylene crackers, LPG fractions have traditionally been consumed as fuel. New catalytic processes now being commercialized open new avenues for the utilization of LPG as sources of valuable petrochemical intermediates. This paper discusses processes for the dehydrogenation and aromatization of LPG.

  5. LPG in Venezuela

    SciTech Connect (OSTI)

    Romero, O.

    1986-01-01

    The use of LPG for domestic consumption in Venezuela began in late 1929 when LPG was imported in lots of 500 cylinders. These cylinders were then returned to the U.S. for refilling. Total consumption at that time was some 40M/sup 3/ (250 barrels) per year and by 1937 had grown to some 540M/sup 3/ (3,400 barrels) per year. Local production of LPG from gas began in the mid thirties with a small cooling plant in the Mene Grande Field in the Lake Maracaibo area, the first field to produce oil in Venezuela (1914). This plant produced gasoline for a refinery and some of the first LPG used in Venezuela for domestic consumption. The capacity of this plant was insufficient to satisfy the growing demand for LPG which was supplied from refinery production until the development of the natural gas processing industry. At the present time, Venezuelan refineries are net consumers of LPG.

  6. Make aromatics from LPG

    SciTech Connect (OSTI)

    Doolan, P.C. ); Pujado, P.R. )

    1989-09-01

    Liquefied petroleum gas (LPG) consists mainly of the propane and butane fraction recovered from gas fields, associated petroleum gas and refinery operations. Apart from its use in steam cracking and stream reforming, LPG has few petrochemical applications. The relative abundance of LPG and the strong demand for aromatics - benzene, toluene and xylenes (BTX) - make it economically attractive to produce aromatics via the aromatization of propane and butanes. This paper describes the Cyclar process, which is based on a catalyst formulation developed by BP and which uses UOP's CCR catalyst regeneration technology, converts propane, butanes or mixtures thereof to petrochemical-quality aromatics in a single step.

  7. LPG emergency response training

    SciTech Connect (OSTI)

    Dix, R.B.; Newton, B.

    1995-12-31

    ROVER (Roll Over Vehicle for Emergency Response) is a specially designed and constructed unit built to allow emergency response personnel and LPG industry employees to get ``up close and personal`` with the type of equipment used for the highway transportation of liquefied petroleum gas (LPG). This trailer was constructed to simulate an MC 331 LPG trailer. It has all the valves, piping and emergency fittings found on highway tankers. What makes this unit different is that it rolls over and opens up to allow program attendees to climb inside the trailer and see it in a way they have never seen one before. The half-day training session is composed of a classroom portion during which attendees will participate in a discussion of hazardous material safety, cargo tank identification and construction. The specific properties of LPG, and the correct procedures for dealing with an LPG emergency. Attendees will then move outside to ROVER, where they will participate in a walkaround inspection of the rolled over unit. All fittings and piping will be representative of both modern and older equipment. Participants will also be able to climb inside the unit through a specially constructed hatch to view cutaway valves and interior construction. While the possibility of an LPG emergency remains remote, ROVER represents Amoco`s continuing commitment to community, education, and safety.

  8. The SONATRACH jumbo LPG plant

    SciTech Connect (OSTI)

    Ahmed Khodja, A.; Bennaceur, A.

    1988-01-01

    The authors aim is to give to the 17 TH world gas conference a general idea on SONATRACH LPG PLANT which is located in the ARZEW area. They develop this communication as follows: general presentation of LPG plant: During the communication, the author's will give the assistance all the information concerning the contractions the erection's date and the LPG PLANT process, start-up of the plant: In this chapter, the authors's will describe the start-up condition, the performance test result, the flexibility test result and the total mechanical achievement of the plant; operation by SONATRACH: After the success that obtained during the mechanical achievement and performance test, the contractor handed over the plant to SONATRACH.

  9. Industrial cooperation in the field of LPG

    SciTech Connect (OSTI)

    Stefano, M.; Trollux, J.; Dune, J.J.

    1988-01-01

    The years to come should confirm the availability of LPG worldwide and enable future users in developing countries to satisfy energy requirements which today are only partly covered, if at all. This paper is designed to point the benefits that these new LPG markets could derive from active cooperation with experienced companies operating in mature LPG markets.

  10. Utilization of LPG for vehicles in Japan

    SciTech Connect (OSTI)

    Kusakabe, M.; Makino, M.; Tokunoh, M.

    1988-01-01

    LPG demand for vehicles amounts to 1.8 MM tons annually, equivalent to about 11% of the total LPG consumption in Japan. The feature which dominates the demand of LPG as a vehicle fuel in Japan is the high penetration of LPG powered vehicles into taxi fleets. This has been made possible following the rationalization in the taxi business in the early 1960s. Today, three quarters of LPG vehicles, numbering some 235,000 while representing only about 1% of the total number of vehicles, account for nearly 93% of all taxicabs.

  11. Numerical Simulations of Leakage from Underground LPG Storage Caverns

    E-Print Network [OSTI]

    Yamamoto, Hajime; Pruess, Karsten

    2004-01-01

    U. Case History: Blowout at an LPG Storage Cavern in Sweden,and Heads at an Underground LPG Storage Cavern Site, Journalof Leakage from Underground LPG Storage Caverns Hajime

  12. LPG dealers, manufacturers report diverse effects of recession and war

    SciTech Connect (OSTI)

    Prowler, S.

    1991-01-01

    The author presents a survey of LPG marketers. The effects of the Persian Gulf War and U.S. recession on the LPG industry are discussed.

  13. Algeria LPG pipeline is build by Bechtel

    SciTech Connect (OSTI)

    Horner, C.

    1984-08-01

    The construction of the 313 mile long, 24 in. LPG pipeline from Hassi R'Mel to Arzew, Algeria is described. The pipeline was designed to deliver 6 million tons of LPG annually using one pumping station. Eventually an additional pumping station will be added to raise the system capacity to 9 million tons annually.

  14. Africa gaining importance in world LPG trade

    SciTech Connect (OSTI)

    Haun, R.R.; Otto, K.W.; Whitley, S.C.

    1997-05-12

    Major LPG projects planned or under way in Africa will increase the importance of that region`s presence in world LPG trade. Supplies will nearly double between 1995 and 2005, at which time they will remain steady for at least 10 years. At the same time that exports are leveling, however, increasing domestic demand for PG is likely to reduce export-market participation by Algeria, Nigeria, Egypt, and Libya. The growth of Africa`s participation in world LPG supply is reflected in comparisons for the next 15--20 years. Total world supply of LPG in 1995 was about 165 million metric tons (tonnes), of which Africans share was 7.8 million tonnes. By 2000, world supply will grow to slightly more than 200 million tonnes, with Africa`s share expected to increase to 13.2 million tonnes (6.6%). And by 2005, world LPG supply will reach nearly 230 million tonnes; Africa`s overall supply volumes by that year will be nearly 16.2 million tonnes (7%). World LPG supply for export in 1995 was on order of 44 million tonnes with Africa supply about 4 million tonnes (9%). By 2005, world export volumes of LPG will reach nearly 70 million tonnes; Africa`s share will have grown by nearly 10 million tonnes (14.3%).

  15. Emissions from ethanol and LPG fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1992-12-31

    This paper addresses the environmental concerns of using neat ethanol and liquified petroleum gas (LPG) as transportation fuels in the US Low-level blends of ethanol (10%) with gasoline have been used as fuels in the US for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the US, but its use has been limited primarily to converted fleet vehicles. Increasing US interest in alternative fuels has raised the possibility of introducing neat ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles and increased production and consumption of fuel ethanol and LPG will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural emissions from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG compared to other transportation fuels. The environmental concerns are reviewed and summarized, but the only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat ethanol fueled vehicles or the increase in LPG fueled vehicles.

  16. Emissions from ethanol and LPG fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1992-01-01

    This paper addresses the environmental concerns of using neat ethanol and liquified petroleum gas (LPG) as transportation fuels in the US Low-level blends of ethanol (10%) with gasoline have been used as fuels in the US for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the US, but its use has been limited primarily to converted fleet vehicles. Increasing US interest in alternative fuels has raised the possibility of introducing neat ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles and increased production and consumption of fuel ethanol and LPG will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural emissions from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG compared to other transportation fuels. The environmental concerns are reviewed and summarized, but the only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat ethanol fueled vehicles or the increase in LPG fueled vehicles.

  17. Overfilling of cavern blamed for LPG blasts

    SciTech Connect (OSTI)

    Not Available

    1992-07-06

    Three explosions and a fire Apr. 7 at an LPG salt dome storage cavern near Brenham, Tex., were triggered when the cavern was overfilled, the Texas Railroad Commission (TRC) has reported. This paper reports that a TRC investigation found that LPG escaped to the surface at the Brenham site through brine injection tubing after excessive fill from an LPG line forced the cavern's water level below the brine tubing's bottom. At the surface, LPG was released into a brine storage pit where it turned into a dense, explosive vapor. At 7:08 a.m., the vapor was ignited by an unknown source. The resulting blast killed three persons and injured 19 and brought operations at the site to a halt.

  18. LPG odorization with an audit trail

    SciTech Connect (OSTI)

    Astala, A.A.

    1995-12-01

    In this article I have tried to cover a very broad subject in a very limited time while only touching on a few of the ways you could odorize LPG and have an audit trail. I would recommend that if you are interested in this type of odorizing for LPG, you contact your odorant manufacturer and two or three odorant equipment manufacturers and talk to them about what you would like and get their recommendations. By talking to more then one manufacturer you may want to incorporate the ideals of two or three manufacturers into your odorant system to have a system that meets all your needs and requirements.

  19. On Managing Temporal Information for Handling Durative Actions in LPG

    E-Print Network [OSTI]

    Gerevini, Alfonso E.

    On Managing Temporal Information for Handling Durative Actions in LPG Alfonso Gerevini, Alessandro Branze 38, 25123 Brescia, Italy fgerevini,saetti,serinag@ing.unibs.it Abstract. LPG is a recent planner good performance. This paper focuses on how LPG represents and manages temporal information to handle

  20. Product transfer service chosen over LPG flaring

    SciTech Connect (OSTI)

    Horn, J.; Powers, M.

    1994-07-01

    Seadrift Pipeline Corp. recently decommissioned its Ella Pipeline, an 108-mile, 8-in. line between the King Ranch and a Union Carbide plant at Seadrift, Texas. The pipeline company opted for the product transfer services of pipeline Dehydrators Inc. to evacuate the ethane-rich LPG mixture from the pipeline instead of flaring the LPG or displacing it with nitrogen at operating pressures into another pipeline. The product transfer system of Pipeline Dehydrators incorporates the use of highly specialized portable compressors, heat exchangers and interconnected piping. The product transfer process of evacuating a pipeline is an economically viable method that safely recovers a very high percentage of the product while maintaining product purity. Using positive-displacement compressors, PLD transferred the LPG from the idled 8-in. Ella line into an adjacent 12-in. ethane pipeline that remained in service at approximately 800 psig. Approximately 4.3 million lb of LPG (97% ethane, 2.7% methane and 0.3% propane) were transferred into the ethane pipeline, lowering the pressure on the Ella Pipeline from 800 psig to 65 psig.

  1. Fire safety of LPG in marine transportation

    SciTech Connect (OSTI)

    Martinsen, W.E.; Johnson, D.W.; Welker, J.R.

    1980-08-01

    This report contains an analytical examination of cargo spill and fire hazard potential associated with the marine handling of liquefied petroleum gas (LPG) as cargo. Principal emphasis was on cargo transfer operations for ships unloading at receiving terminals, and barges loading or unloading at a terminal. Major safety systems, including emergency shutdown systems, hazard detection systems, and fire extinguishment and control systems were included in the analysis. Spill probabilities were obtained from fault tree analyses utilizing composite LPG tank ship and barge designs. Failure rates for hardware in the analyses were generally taken from historical data on similar generic classes of hardware, there being very little historical data on the specific items involved. Potential consequences of cargo spills of various sizes are discussed and compared to actual LPG vapor cloud incidents. The usefulness of hazard mitigation systems (particularly dry chemical fire extinguishers and water spray systems) in controlling the hazards posed by LPG spills and spill fires is also discussed. The analysis estimates the probability of fatality for a terminal operator is about 10/sup -6/ to 10/sup -5/ per cargo transfer operation. The probability of fatality for the general public is substantially less.

  2. U.S. LPG pipeline begins deliveries to Pemex terminal

    SciTech Connect (OSTI)

    Bodenhamer, K.C.

    1997-08-11

    LPG deliveries began this spring to the new Mendez LPG receiving terminal near Juarez, State of Chihuahua, Mexico. Supplying the terminal is the 265-mile, 8-in. Rio Grande Pipeline that includes a reconditioned 217-mile, 8-in. former refined-products pipeline from near Odessa, Texas, and a new 48-mile, 8-in. line beginning in Hudspeth County and crossing the US-Mexico border near San Elizario, Texas. Capacity of the pipeline is 24,000 b/d. The LPG supplied to Mexico is a blend of approximately 85% propane and 15% butane. Before construction and operation of the pipeline, PGPB blended the propane-butane mix at a truck dock during loading. Demand for LPG in northern Mexico is strong. Less than 5% of the homes in Juarez have natural gas, making LPG the predominant energy source for cooking and heating in a city of more than 1 million. LPG also is widely used as a motor fuel.

  3. LPG Electrical, Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: EnergyKulpsville,LEDSGP/activities <LEDSGP/hometrainingLPG Electrical, Inc Jump

  4. Legal nature of LPG (liquefied petroleum gas) regulation

    SciTech Connect (OSTI)

    Liddell, G.

    1986-08-01

    The commercial exploitation of Liquefied Petroleum Gas (LPG) in New Zealand has occurred without a particular and comprehensive concern for any legal implications. The paper in Part I examines definitional questions, assesses in Part II the ability of courts and quasi-courts to evaluate risks associated with the product, examines in Part III the utility of common law remedies for injuries or associated with or arising from LPG, analyzes in Part IV the statutory regulation of LPG, concentrating particularly on the Dangerous Goods (Class 2 - Gases) Regulations 1980, discusses in Part V recent planning case-law concerning LPG development, and concludes that some reform is necessary to produce a more-coherent and precise regulatory regime that takes into account both the needs of developers and those affected by the development of LPG.

  5. Charcoal versus LPG grilling: A carbon-footprint comparison

    SciTech Connect (OSTI)

    Johnson, Eric

    2009-11-15

    Undoubtedly, grilling is popular. Britons fire up their barbeques some 60 million times a year, consuming many thousands of tonnes of fuel. In milder climates consumption is even higher, and in the developing world, charcoal continues to be an essential cooking fuel. So it is worth comparing the carbon footprints of the two major grill types, charcoal and LPG, and that was the purpose of the study this paper documents. Charcoal and LPG grill systems were defined, and their carbon footprints were calculated for a base case and for some plausible variations to that base case. In the base case, the charcoal grilling footprint of 998 kg CO{sub 2}e is almost three times as large as that for LPG grilling, 349 kg CO{sub 2}e. The relationship is robust under all plausible sensitivities. The overwhelming factors are that as a fuel, LPG is dramatically more efficient than charcoal in its production and considerably more efficient in cooking. Secondary factors are: use of firelighters, which LPG does not need; LPG's use of a heavier, more complicated grill; and LPG's use of cylinders that charcoal does not need.

  6. Emissions from ethanol- and LPG-fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1995-06-01

    This paper addresses the environmental concerns of using neat ethanol and liquefied petroleum gas (LPG) as transportation fuels in the United States. Low-level blends of ethanol (10%) with gasoline have been used as fuels in the United States for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the United States, but its use has been limited primarily to converted fleet vehicles. Increasing U.S. interest in alternative fuels has raised the possibility of introducing neat-ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles, and increased production and consumption of fuel ethanol and LPG, will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat-ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural impacts from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG as compared with other transportation fuels. The environmental concerns are reviewed and summarized, but only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat-ethanol-fueled vehicles or the increase in LPG-fueled vehicles.

  7. Cylinder surface, temperature may affect LPG odorization

    SciTech Connect (OSTI)

    McWilliams, H.

    1988-01-01

    A study of possible odorant fade in propane by the Arthur D. Little Co. (Boston) has indicated that oxidation of interior surfaces of LPG containers may cause the odorant, ethyl mercaptan, to fade. The oxidation, ferous oxide, is a black, easily oxidizable powder that is the monoxide of iron. The study, contracted for by the Consumer Product Safety Commission (CPSC), is part of that agency's study of residential LP-gas systems. Another study is currently underway by an NLPGA task force headed by Bob Reid of Petrolane (Long Beach, Calif.). It may not be finished until the end of next year. Recently, the Propane Gas Association of Canada completed a study of odorant fade with the conclusion that much more study is needed on the subject. In addition to the cylinder surface problem, the CPSC study indicated that ambient temperatures might also affect the presence of odorant in product. This article reviews some of the results.

  8. Molecular & Biochemical Parasitology 136 (2004) 1123 The LPG1 gene family of Leishmania major

    E-Print Network [OSTI]

    Beverley, Stephen M.

    2004-01-01

    Molecular & Biochemical Parasitology 136 (2004) 11­23 The LPG1 gene family of Leishmania major Kai lipophosphoglycan (LPG) is structurally related to that of the smaller glyco- sylinositolphospholipids (GIPLs Galf -transferase (Galf T) LPG1 affected Galf incorporation in LPG but not GIPLs. We hypothesized

  9. The role(s) of lipophosphoglycan (LPG) in the establishment of Leishmania major

    E-Print Network [OSTI]

    Beverley, Stephen M.

    The role(s) of lipophosphoglycan (LPG) in the establishment of Leishmania major infections) The abundant cell surface glycolipid lipophosphoglycan (LPG) was implicated in many steps of the Leishmania sharing LPG domains, however, has led to uncertainty about the relative contribution of LPG in vivo. Here

  10. Monitoring, safety systems for LNG and LPG operators

    SciTech Connect (OSTI)

    True, W.R.

    1998-11-16

    Operators in Korea and Australia have chosen monitoring and control systems in recent contracts for LNG and LPG storage. Korea Gas Corp. (Kogas) has hired Whessoe Varec, Calais, to provide monitoring systems for four LNG storage tanks being built at Kogas` Inchon terminal. For Elgas Ltd., Port Botany, Australia, Whessoe Varec has already shipped a safety valve-shutdown system to a new LPG cavern-storage facility under construction. The paper describes the systems, terminal monitoring, dynamic approach to tank management, and meeting the growing demand for LPG.

  11. LPG-recovery processes for baseload LNG plants examined

    SciTech Connect (OSTI)

    Chiu, C.H.

    1997-11-24

    With demand on the rise, LPG produced from a baseload LNG plant becomes more attractive as a revenue-earning product similar to LNG. Efficient use of gas expanders in baseload LNG plants for LPG production therefore becomes more important. Several process variations for LPG recovery in baseload LNG plants are reviewed here. Exergy analysis (based on the Second Law of Thermodynamics) is applied to three cases to compare energy efficiency resulting from integration with the main liquefaction process. The paper discusses extraction in a baseload plant, extraction requirements, process recovery parameters, extraction process variations, and exergy analysis.

  12. LPG export growth will exceed demand by 2000

    SciTech Connect (OSTI)

    True, W.R.

    1994-08-08

    LPG supplies for international trade will increase sharply through 2000 and begin to outstrip demand by 1997 or 1998. This outlook depends on several production projects proceeding as planned. Leading the way to increased volumes are projects in Algeria, Nigeria, and Australia, among others. Purvin and Gertz, Dallas, projected this trend earlier this year at an international LPG seminar near Houston. Representatives from LPG-supplying countries also presented information to support this view and subsequently supplied more specifics to OGJ in response to questions. This paper discusses this information. Trends in Africa, Australia, North America, and South America are forecast.

  13. World`s LPG supply picture will change by 2000

    SciTech Connect (OSTI)

    True, W.R.

    1995-11-06

    Middle East LPG producers will continue to dominate world export markets in 1996. Led by Saudi Arabia, the Middle East will produce nearly 26 million metric tons of LPG in million metric tons of LPG in 1996, more than 54% of the world`s almost 48 million metric tons of export LPG. In 2000, however, with world exports of LPG expanding to 58.9 million metric tons, Middle East suppliers; share will have remained flat, making up 31.7 million metric tons, or 53.9%. Saudi Arabia`s contribution will exceed 15 million metric tons, reflecting essentially no growth since 1995. These and other patterns, from data compiled by Purvin and Gertz, Dallas, and published earlier this year, show other suppliers of LPG, especially African (Algeria/Nigeria), North Sea, and Latin American (Venezuela/Argentina), picking up larger shares in the last 5 years of this decade. This scenario assumes completion of several major supply projects that are either panned, under construction, or nearing start up in most of these areas. The paper discusses the global picture, the supply situation in the Middle East, Africa, the North Sea, and South America.

  14. Indonesia's Arun LPG plant production is unique in Far East markets

    SciTech Connect (OSTI)

    Naklie, M.M.; Penick, D.P.; Denton, L.A.; Kartiyoso, I.

    1987-08-03

    Entry of the Arun (Indonesia) LNG plant into the LPG Far East markets is significant because its supplies for those markets are not tied to gas being extracted in association with crude oil. Arun LPG products are extracted from gas that is processed into and marketed as LNG. This article on the Arun LNG plant analyzes its LPG process and the significance of the LPG project on the plant's markets. Particular attention is paid to: 1.) LPG recovery; 2.) LPG fractionation; and 3.) Far East trade.

  15. The importance of FCC catalyst selection on LPG profitability

    SciTech Connect (OSTI)

    Keyworth, D.A.; Gilman, R.; Pearce, J.R. )

    1989-01-01

    Recently the value of LPG in chemical operations downstream of the FCC unit has increased. Such downstream operations utilize propylene not only in alkylate, but also in rapid growth petrochemical applications such as for a raw material in the manufacture of polypropylene and propylene oxide. Isobutane and the butenes (particularly butene-2 in sulfuric acid catalyzed alkylation units) are prized for alkylate feed. The profit potential and incentives to use other LPG components such as isobutene to make MTBE is now increased because of legislative actions and increased octane performance demand; and because of the greater isobutene content in the LPG from the new FCC octane catalysts. A low non-framework alumina (NFA) zeolite studied made a more olefinic LPG with higher iso-to normal C4 ratio than the other zeolites. Pilot plant data has also shown the new low NFA zeolite gave not only outstanding motor octane (MON) performance, but produced an LPG with better propylene to propane ratio, more isobutene, more n-butenes and more C4 branching than other RE promoted zeolite catalysts. Commercial results have verified the improved performance and profitability for the new low-NFA type zeolite catalysts. Three commercial examples are described.

  16. Low temperature type new TMCP steel plate for LPG carriers

    SciTech Connect (OSTI)

    Suzuki, Shuichi; Bessyo, Kiyoshi; Arimochi, Kazushige; Yajima, Hiroshi; Tada, Masuo; Sakai, Daisuke

    1994-12-31

    New Thermo-Mechanical Control Process (TMCP) steel plate for LPG carriers of completely liquefied type was developed with non-nickel chemistry. The new steel plate has a capability to arrest a long running brittle crack at {minus}46 C (which is the design temperature of the liquefied LPG tanks). A high heat-input one-pass welding can be applied to this steel despite its nickel-less chemistry. These capabilities were enabled by microalloying technology with low aluminum-medium nitrogen-boron, as well as by the advanced Thermo-Mechanical Control Process. This paper describes the new concept of utilizing the trace elements and the evaluation test results as the steel plate for the LPG tank and hull, especially from the standpoints of the fracture safe reliability at high heat input welding and from that of the shop workability.

  17. Cascaded'' pilot regulators help reduce LPG loss in hot weather

    SciTech Connect (OSTI)

    Not Available

    1994-08-08

    Fina Oil and Chemical Co. and Fisher Controls International used engineering resourcefulness to overcome heat-induced product loss from LPG storage bullets at Fina's Port Arthur, Tex., refinery. Fina had installed Fisher's Easy Joe 399A-6365, a pilot-operated, back-pressure-type regulator, on its LPG storage facility in 1991 as part of a fuel products modernization project. The regulators helped control the accumulation of noncondensible vapors, which collect in the storage bullets above the LPG. But summer heat extremes and surges in the tanks and lines made it possible for the operating pressure to increase so that the safety relief valve was activated before the pilot regulator was able to stabilize the pressure. The installation of pilot-type regulators, in cascaded, or series, formation, reduced product venting through relief valves.

  18. Demand for petrochem feedstock to buoy world LPG industry

    SciTech Connect (OSTI)

    Not Available

    1992-05-18

    This paper reports that use of liquefied petroleum gas as petrochemical feedstock will increase worldwide, providing major growth opportunities for LPG producers. World exports of liquefied petroleum gas will increase more slowly than production as producers choose to use LPG locally as chemical feedstock and export in value added forms such as polyethylene. So predicts Poten and Partners Inc., New York. Poten forecasts LPG production in exporting countries will jump to 95 million tons in 2010 from 45 million tons in 1990. However, local and regional demand will climb to 60 million tons/year from 23 million tons/year during the same period. So supplies available for export will rise to 35 million tons in 2010 from 22 million tons in 1990.

  19. Determination of usage patterns and emissions for propane/LPG in California. Final report

    SciTech Connect (OSTI)

    Sullivan, M.

    1992-05-01

    The purpose of the study was to determine California usage patterns of Liquified Petroleum Gas (LPG), and to estimate propane emissions resulting from LPG transfer operations statewide, and by county and air basin. The study is the first attempt to quantify LPG transfer emissions for California. This was accomplished by analyzing data from a telephone survey of California businesses that use LPG, by extracting information from existing databases.

  20. Experience with Bi-Fuel LPG Pickups in Texas

    SciTech Connect (OSTI)

    Whalen, P.

    1999-05-12

    The State of Texas requires state agencies to purchase alternative fuel vehicles (AFVs). In 1996, Texas Department of Transportation (TxDOT) representatives added about 400 bi-fuel liquefied petroleum gas (LPG) pickup trucks to their fleet. The fleet managers were willing to share information about their fleets and the operation of these vehicles, so a study was launched to collect operations, maintenance, and cost data for selected LPG and gasoline vehicles (as controls) throughout 18 months of vehicle operation. This case study presents the results of that data collection and its subsequent analysis.

  1. Assessment of research and development (R and D) needs in LPG safety and environmental control

    SciTech Connect (OSTI)

    DeSteese, J.G.

    1982-05-01

    The report characterizes the LPG industry covering all operations from production to end use, reviews current knowledge of LPG release phenomenology, summarizes the status of current LPG release prevention and control methodology, and identifies any remaining safety and environmental problems and recommends R and D strategies that may mitigate these problems. (ACR)

  2. Expansion fractionation capacity of the LPG-ULE plant

    SciTech Connect (OSTI)

    Morin, L.M.C.

    1999-07-01

    The Western Division of PDVSA has among other facilities a NGL Fractionation Complex located onshore in Ul'e. The complex consists of three plants, the first and second older plants, LPG-1 and LPG-2, which fractionate the NGL to produce propane, a butane mix and natural gasoline. The third plant, LPG-3, fractionates the butane mix from the LPG-1 and 2 plants to produce iso and normal butane. Several optimization projects already in progress will increase the NGL production to 12,200 b/d. For this reason it was decided to conduct a study of the existing fractionation facilities and utilities systems to determine their capacities. This evaluation revealed that some of the fractionation towers would have some limitations in the processing of the expected additional production. The study recommended an option to increase the capacity of the fractionation towers by lowering their operating pressure, in order to take advantage of relative volatility increase between the key components, which allows easier separation, as well as reducing the heat duty required. The completed study also determined that this option is more economically convenient than the replacement of the existing fractionation towers.

  3. Control and extinguishment of LPG fires. Final report

    SciTech Connect (OSTI)

    Johnson, D.W.; Martinsen, W.E.; Cavin, W.D.; Chilton, P.D.; Lawson, H.P.; Welker, J.R.

    1980-08-01

    Approximately 100 fire control and fire extinguishment tests were run on free-burning liquefied petroleum gases (LPG) pool fires from 25 ft/sup 2/ to 1600 ft/sup 2/ in area. The LPG was contained in concrete pits, and the pit floors were allowed to cool before the fires were ignited so that the burning rates were not influenced by boiloff from the warm floor. High expansion foam was used for fire control. The foam was applied from fixed generators located on the upwind side of the pit. Fires were controlled after foam application of less than a minute to about 10 minutes, depending on the application rate. Fires were extinguished with dry chemical agents applied through fixed piping systems with tankside nozzles and by manual application using hoselines and portable extinguishers. Fires could readily be extinguished in times ranging from a few seconds to about half a minute, depending on the application rate, system design, and ambient conditions. Additional tests were conducted in 1-ft/sup 2/ and 5-ft/sup 2/ pits to determine the boiloff rates for LPG spilled on concrete, a sand/soil mix, and polyurethane foam substrates. Burning rates for free-burning LPG pool fires from 1 ft/sup 2/ to 1600 ft/sup 2/ in area are also reported.

  4. Control and extinguishment of LPG fires. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    Approximately 100 fire control and fire extinguishment tests were run on free-burning LPG pool fires from 25 ft/sup 2/ to 1600 ft/sup 2/ in area. The LPG was contained in concrete pits, and the pit floors were allowed to cool before the fires were ignited so that the burning rates were not influenced by boiloff from the warm floor. High expansion foam was used for fire control. The foam was applied from fixed generators located on the upwind side of the pit. Fires were controlled after foam application of less than a minute to about 10 minutes, depending on the application rate. Fires were extinguished with dry chemical agents applied through fixed piping systems with tankside nozzles and by manual application using hoselines and portable extinguishers. Fires could readily be extinguished in times ranging from a few seconds to about half a minute, depending on the application rate, system design, and ambient conditions. Additional tests were conducted in 1-ft/sup 2/ and 5-ft/sup 2/ pits to determine the boiloff rates for LPG spilled on concrete, a sand/soil mix, and polyurethane foam substrates. Burning rates for free-burning LPG pool fires from 1 ft/sup 2/ to 1600 ft/sup 2/ in area are also reported.

  5. Fire safety of LPG in marine transportation. Final report

    SciTech Connect (OSTI)

    Martinsen, W.E.; Johnson, D.W.; Welker, J.R.

    1980-06-01

    This report contains an analytical examination of cargo spill and fire hazard potential associated with the marine handling of liquefied petroleum gas (LPG) as cargo. Principal emphasis was on cargo transfer operations for ships unloading at receiving terminals, and barges loading or unloading at a terminal. Major safety systems, including emergency shutdown systems, hazard detection systems, and fire extinguishment and control systems were included in the analysis. Spill probabilities were obtained from fault tree analyses utilizing composite LPG tank ship and barge designs. Failure rates for hardware in the analyses were generally taken from historical data on similar generic classes of hardware, there being very little historical data on the specific items involved. Potential consequences of cargo spills of various sizes are discussed and compared to actual LPG vapor cloud incidents. The usefulness of hazard mitigation systems (particularly dry chemical fire extinguishers and water spray systems) in controlling the hazards posed by LPG spills and spill fires is also discussed. The analysis estimates the probability of fatality for a terminal operator is about 10/sup -6/ to 10/sup -5/ per cargo transfer operation. The probability of fatality for the general public is substantially less.

  6. Numerical Simulations of Leakage from Underground LPG Storage Caverns

    SciTech Connect (OSTI)

    Yamamoto, Hajime; Pruess, Karsten

    2004-09-01

    To secure a stable supply of petroleum gas, underground storage caverns for liquified petroleum gas (LPG) are commonly used in many countries worldwide. Storing LPG in underground caverns requires that the surrounding rock mass remain saturated with groundwater and that the water pressure be higher than the liquid pressure inside the cavern. In previous studies, gas containment criteria for underground gas storage based on hydraulic gradient and pressure have been discussed, but these studies do not consider the physicochemical characteristics and behavior of LPG such as vaporization and dissolution in groundwater. Therefore, while these studies are very useful for designing storage caverns, they do not provide better understanding of the either the environmental effects of gas contamination or the behavior of vaporized LPG. In this study, we have performed three-phase fluid flow simulations of gas leakage from underground LPG storage caverns, using the multiphase multicomponent nonisothermal simulator TMVOC (Pruess and Battistelli, 2002), which is capable of solving the three-phase nonisothermal flow of water, gas, and a multicomponent mixture of volatile organic chemicals (VOCs) in multidimensional heterogeneous porous media. A two-dimensional cross-sectional model resembling an actual underground LPG facility in Japan was developed, and gas leakage phenomena were simulated for three different permeability models: (1) a homogeneous model, (2) a single-fault model, and (3) a heterogeneous model. In addition, the behavior of stored LPG was studied for the special case of a water curtain suddenly losing its function because of operational problems, or because of long-term effects such as clogging of boreholes. The results of the study indicate the following: (1) The water curtain system is a very powerful means for preventing gas leakage from underground storage facilities. By operating with appropriate pressure and layout, gas containment can be ensured. (2) However , in highly heterogeneous media such as fractured rock and fault zones, local flow paths within which the gas containment criterion is not satisfied could be formed. To eliminate such zones, treatments such as pre/post grouting or an additional installment of water-curtain boreholes are essential. (3) Along highly conductive features such as faults, even partially saturated zones possess certain effects that can retard or prevent gas leakage, while a fully unsaturated fault connected to the storage cavern can quickly cause a gas blowout. This possibility strongly suggests that ensuring water saturation of the rock surrounding the cavern is a very important requirement. (4) Even if an accident should suddenly impair the water curtain, the gas plume does not quickly penetrate the ground surface. In these simulations, the plume takes several months to reach the ground surface.

  7. Carbon footprints of heating oil and LPG heating systems

    SciTech Connect (OSTI)

    Johnson, Eric P.

    2012-07-15

    For European homes without access to the natural gas grid, the main fuels-of-choice for heating are heating oil and LPG. How do the carbon footprints of these compare? Existing literature does not clearly answer this, so the current study was undertaken to fill this gap. Footprints were estimated in seven countries that are representative of the EU and constitute two-thirds of the EU-27 population: Belgium, France, Germany, Ireland, Italy, Poland and the UK. Novelties of the assessment were: systems were defined using the EcoBoiler model; well-to-tank data were updated according to most-recent research; and combustion emission factors were used that were derived from a survey conducted for this study. The key finding is that new residential heating systems fuelled by LPG are 20% lower carbon and 15% lower overall-environmental-impact than those fuelled by heating oil. An unexpected finding was that an LPG system's environmental impact is about the same as that of a bio heating oil system fuelled by 100% rapeseed methyl ester, Europe's predominant biofuel. Moreover, a 20/80 blend (by energy content) with conventional heating oil, a bio-heating-oil system generates a footprint about 15% higher than an LPG system's. The final finding is that fuel switching can pay off in carbon terms. If a new LPG heating system replaces an ageing oil-fired one for the final five years of its service life, the carbon footprint of the system's final five years is reduced by more than 50%.

  8. Upgrading Fischer-Tropsch LPG (liquefied petroleum gas) with the Cyclar process

    SciTech Connect (OSTI)

    Gregor, J.H.; Gosling, C.D.; Fullerton, H.E.

    1989-04-28

    The use of the UOP/BP Cyclar{reg sign} process for upgrading Fischer-Tropsch (F-T) liquefied petroleum gas (LPG) was studied at UOP{reg sign}. The Cyclar process converts LPG into aromatics. The LPG derived from F-T is highly olefinic. Two routes for upgrading F-T LPG were investigated. In one route, olefinic LPG was fed directly to a Cyclar unit (Direct Cyclar). The alternative flow scheme used the Huels CSP process to saturate LPG olefins upstream of the Cyclar unit (Indirect Cyclar). An 18-run pilot plant study verified that each route is technically feasible. An economic evaluation procedure was designed to choose between the Direct and Indirect Cyclar options for upgrading LPG. Four situations involving three different F-T reactor technologies were defined. The main distinction between the cases was the degree of olefinicity, which ranged between 32 and 84 wt % of the fresh feed. 8 refs., 80 figs., 44 tabs.

  9. Canonical Distillation of Entanglement

    E-Print Network [OSTI]

    Tamoghna Das; Asutosh Kumar; Amit Kumar Pal; Namrata Shukla; Aditi Sen De; Ujjwal Sen

    2015-02-10

    Distilling highly entangled quantum states from weaker ones is a process that is crucial for efficient and long-distance quantum communication, and has implications for several other quantum information protocols. We introduce the notion of distillation under limited resources, and specifically focus on the energy constraint. The corresponding protocol, which we call the canonical distillation of entanglement, naturally leads to the set of canonically distillable states. We show that for non-interacting Hamiltonians, almost no states are canonically distillable, while the situation can be drastically different for interacting ones. Several paradigmatic Hamiltonians are considered for bipartite as well as multipartite canonical distillability. The results have potential applications for practical quantum communication devices.

  10. Canonical Distillation of Entanglement

    E-Print Network [OSTI]

    Tamoghna Das; Asutosh Kumar; Amit Kumar Pal; Namrata Shukla; Aditi Sen De; Ujjwal Sen

    2015-09-08

    Distilling highly entangled quantum states from weaker ones is a process that is crucial for efficient and long-distance quantum communication, and has implications for several other quantum information protocols. We introduce the notion of distillation under limited resources, and specifically focus on the energy constraint. The corresponding protocol, which we call the canonical distillation of entanglement, naturally leads to the set of canonically distillable states. We show that for non-interacting Hamiltonians, almost no states are canonically distillable, while the situation can be drastically different for interacting ones. Several paradigmatic Hamiltonians are considered for bipartite as well as multipartite canonical distillability. The results have potential applications for practical quantum communication devices.

  11. Atomic Force Microscopy Studies of Lipophosphoglycan (LPG) Molecules in Lipid Bilayers

    SciTech Connect (OSTI)

    LAST, JULIE A.; HUBER, TINA; SASAKI, DARRYL Y.; SALVATORE, BRIAN; TURCO, SALVATORE J.

    2003-03-01

    Lipophosphoglycan (LPG) is a lypopolysaccharide found on the surface of the parasite Leishmania donovani that is thought to play an essential role in the infection of humans with leishamniasis. LPG acts as an adhesion point for the parasite to the gut of the sand fly, whose bite is responsible for transmitting the disease. In addition, LPG acts to inhibit protein kinase C (PKC) in the human macrophage, possibly by structural changes in the membrane. The Ca{sup 2+} ion is believed to play a role in the infection cycle, acting both as a crosslinker between LPG molecules and by playing a part in modulating PKC activity. To gain insight into the structure of LPG within a supported lipid membrane and into the structural changes that occur due to Ca{sup 2+} ions, we have employed the atomic force microscope (AFM). We have observed that the LPG molecules inhibit bilayer fusion, resulting in bilayer islands on the mica surface. One experiment suggests that the LPG molecules are parallel to the mica surface and that the structure of the LPG changes upon addition of Ca{sup 2+}, with an increase in the height of the LPG molecules from the bilayer surface and an almost complete coverage of LPG on the bilayer island.

  12. Far East LPG sales will grow faster than in West

    SciTech Connect (OSTI)

    1996-12-30

    LPG sales through 2010 in regions east of the Suez Canal (East of Suez) will grow at more than twice those in regions west of the canal. East-of-Suez sales will grow at more than 4.0%/year, compared to slightly less than 2.0%/year growth in sales West of Suez. East-of-Suez sales will reach 92 million tons/year (tpy) by 2010, accounting for 39% of the worldwide total. This share was 31% in1995 and only 27% in 1990. LPG sales worldwide will reach 192 million tons in 2000 and 243 million tpy by 2010. In 1995, they were 163 million tons. These are some of the major conclusions of a recent study by Frank R. Spadine, Christine Kozar, and Rudy Clark of New York City-based consultant Poten and Partners Inc. Details of the study are in the fall report ``World Trade in LPG 1990--2010``. This paper discusses demand segments, seaborne balance, Western sources, largest trading region, North American supplies, and other supplies.

  13. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX)

    1982-01-01

    A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  14. Additional Development of a Dedicated Liquefied Petroleum Gas (LPG) Ultra Low Emissions Vehicle (ULEV)

    SciTech Connect (OSTI)

    IMPCO Technologies

    1998-10-28

    This report describes the last in a series of three projects designed to develop a commercially competitive LPG light-duty passenger car that meets California ULEV standards and corporate average fuel economy (CAFE) energy efficiency guidelines for such a vehicle. In this project, IMPCO upgraded the vehicle's LPG vapor fuel injection system and performed emissions testing. The vehicle met the 1998 ULEV standards successfully, demonstrating the feasibility of meeting ULEV standards with a dedicated LPG vehicle.

  15. Asia, North America lead way in growth of NGL, LPG trade

    SciTech Connect (OSTI)

    Otto, K.; Gist, R.; Whitley, C.; Haun, R.

    1998-01-12

    Recent analyses of world NGL trade indicate that important changes in LPG supply and demand are under way in Asia and North America. LPG markets in the 1990s reflect a rapidly shifting balance between East-of-Suez and West-of-Suez markets. This shift has increased concern about availability of future LPG supplies for Asia. The paper discusses world developments, East versus West of Suez, end uses and supplies in Asia, Canadian ethane, propane, butane, and natural gasoline, Mexican ethane, LPG, and natural gasoline, US ethane, propane, butanes, and iso-C{sub 4} and C{sub 5}.

  16. Advanced Distillation Final Report

    SciTech Connect (OSTI)

    Maddalena Fanelli; Ravi Arora; Annalee Tonkovich; Jennifer Marco; Ed Rode

    2010-03-24

    The Advanced Distillation project was concluded on December 31, 2009. This U.S. Department of Energy (DOE) funded project was completed successfully and within budget during a timeline approved by DOE project managers, which included a one year extension to the initial ending date. The subject technology, Microchannel Process Technology (MPT) distillation, was expected to provide both capital and operating cost savings compared to conventional distillation technology. With efforts from Velocys and its project partners, MPT distillation was successfully demonstrated at a laboratory scale and its energy savings potential was calculated. While many objectives established at the beginning of the project were met, the project was only partially successful. At the conclusion, it appears that MPT distillation is not a good fit for the targeted separation of ethane and ethylene in large-scale ethylene production facilities, as greater advantages were seen for smaller scale distillations. Early in the project, work involved flowsheet analyses to discern the economic viability of ethane-ethylene MPT distillation and develop strategies for maximizing its impact on the economics of the process. This study confirmed that through modification to standard operating processes, MPT can enable net energy savings in excess of 20%. This advantage was used by ABB Lumus to determine the potential impact of MPT distillation on the ethane-ethylene market. The study indicated that a substantial market exists if the energy saving could be realized and if installed capital cost of MPT distillation was on par or less than conventional technology. Unfortunately, it was determined that the large number of MPT distillation units needed to perform ethane-ethylene separation for world-scale ethylene facilities, makes the targeted separation a poor fit for the technology in this application at the current state of manufacturing costs. Over the course of the project, distillation experiments were performed with the targeted mixture, ethane-ethylene, as well as with analogous low relative volatility systems: cyclohexane-hexane and cyclopentane-pentane. Devices and test stands were specifically designed for these efforts. Development progressed from experiments and models considering sections of a full scale device to the design, fabrication, and operation of a single-channel distillation unit with integrated heat transfer. Throughout the project, analytical and numerical models and Computational Fluid Dynamics (CFD) simulations were validated with experiments in the process of developing this platform technology. Experimental trials demonstrated steady and controllable distillation for a variety of process conditions. Values of Height-to-an-Equivalent Theoretical Plate (HETP) ranging from less than 0.5 inch to a few inches were experimentally proven, demonstrating a ten-fold performance enhancement relative to conventional distillation. This improvement, while substantial, is not sufficient for MPT distillation to displace very large scale distillation trains. Fortunately, parallel efforts in the area of business development have yielded other applications for MPT distillation, including smaller scale separations that benefit from the flowsheet flexibility offered by the technology. Talks with multiple potential partners are underway. Their outcome will also help determine the path ahead for MPT distillation.

  17. Fuel switching from wood to LPG can benefit the environment

    SciTech Connect (OSTI)

    Nautiyal, Sunil Kaechele, Harald

    2008-11-15

    The Himalaya in India is one of the world's biodiversity hotspots. Various scientific studies have reported and proven that many factors are responsible for the tremendous decline of the Himalayan forests. Extraction of wood biomass from the forests for fuel is one of the factors, as rural households rely entirely on this for their domestic energy. Efforts continue for both conservation and development of the Himalayan forests and landscape. It has been reported that people are still looking for more viable solutions that could help them to improve their lifestyle as well as facilitate ecosystem conservation and preservation of existing biodiversity. In this direction, we have documented the potential of the introduction of liquefied petroleum gas (LPG), which is one of the solutions that have been offered to the local people as a substitute for woodfuel to help meet their domestic energy demand. The results of the current study found dramatic change in per capita woodfuel consumption in the last two decades in the villages where people are using LPG. The outcome showed that woodfuel consumption had been about 475 kg per capita per year in the region, but after introduction of LPG, this was reduced to 285 kg per capita per year in 1990-1995, and was further reduced to 46 kg per capita per year in 2000-2005. Besides improving the living conditions of the local people, this transformation has had great environmental consequences. Empirical evidence shows that this new paradigm shift is having positive external effects on the surrounding forests. Consequently, we have observed a high density of tree saplings and seedlings in adjacent forests, which serves as an assessment indicator of forest health. With the help of the current study, we propose that when thinking about a top-down approach to conservation, better solutions, which are often ignored, should be offered to local people.

  18. System and method for converting wellhead gas to liquefied petroleum gases (LPG)

    SciTech Connect (OSTI)

    May, R.L.; Sinclair, B.W.

    1984-07-31

    A method of converting natural wellhead gas to liquefied petroleum gases (LPG) may comprise the steps of: separating natural gas from petroleum fluids exiting a wellhead; compressing the natural gas; refrigerating the natural gas, liquefying at least a portion thereof; separating LPG from gas vapors of the refrigerated natural gas; storing the separated LPG in a storage tank with a vapor space therein; and recirculating a portion of the LPG vapors in the storage tank with the natural gas exiting the wellhead to enhance recovery of LPG. A system for performing the method may comprise: a two-stage gas compressor connected to the wellhead; a refrigeration unit downstream of the gas compressor for refrigerating the compressed gases therefrom; at least one product separator downstream of the refrigerator unit for receiving refrigerated and compressed gases discharged from the refrigerator unit and separating LPG therein from gases remaining in vapor form; and a storage tank for receiving and storing the separated LPG therein, the storage tank having a vapor space therein connected upstream of the gas compressor through a pressure regulator allowing recirculation of some LPG vapors with the natural gases through said system.

  19. New pemex agency, smog checks greet Mexican LPG vehicle users

    SciTech Connect (OSTI)

    Not Available

    1992-10-01

    This paper reports that the relaxation of prohibitions on the use of propane as a motor fuel has spurred sizeable business activity in carburetion and higher demand for LPG throughout Mexico and particularly in Mexico City. However, a number of unforeseen problems have developed that required tough, immediate solutions. After the alternative fuels project began at city hall in Mexico City, publicity spread nationwide, reportedly spurring conversion activity in many other cities. That led to additional demand for fuel of a magnitude that few people had anticipated. In order to assume control of the situation, the national oil company, Pemex, established an official LPG Motor Fuel Department on June 1. Operating in conjunction with the Ministry of Industry, the new department has been busy registering every major propane-powered fleet in the country. Most important, the rate of conversion work must now be pegged to the availability of fuel. It is believed that conversion activity has become more evenly paced since the new Pemex agency took over.over.

  20. Next generation processes for NGL/LPG recovery

    SciTech Connect (OSTI)

    Pitman, R.N.; Hudson, H.M.; Wilkinson, J.D.; Cuellar, K.T.

    1998-12-31

    Up to now, Ortloff`s Gas Subcooled Process (GSP) and OverHead Recycle Process (OHR) have been the state-of-the-art for efficient NGL/LPG recovery from natural gas, particularly for those gases containing significant concentrations of carbon dioxide (CO{sub 2}). Ortloff has recently developed new NGL recovery processes that advance the start-of-the-art by offering higher recovery levels, improved efficiency, and even better CO{sub 2} tolerance. The simplicity of the new process designs and the significantly lower gas compression requirements of the new processes reduce the investment and operating costs for gas processing plants. For gas streams containing significant amounts of carbon dioxide, the CO{sub 2} removal equipment upstream of the NGL recovery plant can be smaller or eliminated entirely, reducing both the investment cost and the operating cost for gas processing companies. In addition, the new liquids extraction processes can be designed to efficiently recover or reject ethane, allowing the gas processor to respond quickly to changing market conditions. This next generation of NGL/LPG recovery processes is now being applied to natural gas processing here in the US and abroad. Two of the new plants currently under construction provide practical examples of the benefits of the new processes.

  1. Alternative fuel information: Facts about CNG and LPG conversion

    SciTech Connect (OSTI)

    O`Connor, K.

    1994-06-01

    As new environmental and energy related laws begin to take effect, increasing numbers of alternative fuel vehicles (AFVs) will be required in federal, state, municipal, and private fleets across the country. The National Energy Policy Act of 1992 and the Clean Air Act Amendments of 1990, along with several new state and local laws, will require fleet managers to either purchase original equipment manufacturer (OEM) vehicles, which are produced by automakers, or convert existing vehicles to run on alternative fuels. Because there is a limited availability and selection of OEM vehicles, conversions are seen as a transition to the time when automakers will produce more AFVs for public sale. A converted vehicle is any vehicle that originally was designed to operate on gasoline, and has been altered to run on an alternative fuel such as compressed natural gas (CNG) or propane (liquefied petroleum gas -- LPG), the two most common types of fuel conversions. In the United States, more than 25,000 vehicles already have been converted to COG, and 300,000 have been converted to LPG.

  2. The Leishmania GDP-Mannose Transporter Is an Autonomous, Multi-specific, Hexameric Complex of LPG2 Subunits

    E-Print Network [OSTI]

    Beverley, Stephen M.

    The Leishmania GDP-Mannose Transporter Is an Autonomous, Multi-specific, Hexameric Complex of LPG2Vised Manuscript ReceiVed NoVember 29, 1999 ABSTRACT: LPG2 (a gene involved in lipophosphoglycan assembly) encodes lack a GDP-Man NST, thereby providing an ideal heterologous system for probing the LPG2 structure

  3. 2100 JOURNAL OF LIGHTWAVE TECHNOLOGY, VOL. 27, NO. 12, JUNE 15, 2009 Simultaneous Interrogation of a Hybrid FBG/LPG

    E-Print Network [OSTI]

    Yao, Jianping

    of a Hybrid FBG/LPG Sensor Pair Using a Monolithically Integrated Echelle Diffractive Grating Honglei Guo--A simultaneous interrogation technique of a hybrid fiber Bragg grating (FBG) and long-period grating (LPG) sensor to interrogate hybrid FBG/LPG-based sensor pairs for the discrimination of refractive index (RI)/tem- perature

  4. Novel coiled tubing application controls large LPG storage well fire

    SciTech Connect (OSTI)

    Gebhardt, F.; Eby, D.; Barnett, D.

    1996-06-01

    Conventional well control techniques for normal oil and gas wells are widely known and have been presented on numerous occasions. However, LPG storage (or cavern) wells rarely blow out and/or catch on fire. As a result, little information has been presented on the topic of well control for these types of wells. This article chronicles a case history of a high-volume liquid propane storage well fire. Because conventional wellhead removal methods could not be applied in this case, the capping/kill plan called for use of coiled tubing in a novel manner to cut the tubing downhole and install an inflatable packer to shut off propane flow. The plan was successfully executed, saving the operator millions of dollars in LPC product loss and cost of control.

  5. Golgi GDP-mannose Uptake Requires Leishmania LPG2 A MEMBER OF A EUKARYOTIC FAMILY OF PUTATIVE NUCLEOTIDE-SUGAR TRANSPORTERS*

    E-Print Network [OSTI]

    Beverley, Stephen M.

    Golgi GDP-mannose Uptake Requires Leishmania LPG2 A MEMBER OF A EUKARYOTIC FAMILY OF PUTATIVE as a donor substrate for lipophosphoglycan (LPG) synthesis. A lpg2 deletion mutant showed loss of GDP- Man but not UDP-Gal uptake, which was restored by introduction of the gene LPG2. Immunoelectron micros- copy

  6. Fire protection considerations for the design and operation of liquefied petroleum gas (LPG) storage facilities

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    This standard addresses the design, operation, and maintenance of LPG storage facilities from the standpoint of prevention and control of releases, fire-protection design, and fire-control measures, as well as the history of LPG storage facility failure, facility design philosophy, operating and maintenance procedures, and various fire-protection and firefighting approaches and presentations. The storage facilities covered are LPG installations (storage vessels and associated loading/unloading/transfer systems) at marine and pipeline terminals, natural gas processing plants, refineries, petrochemical plants, and tank farms.

  7. Influence of H{sub 2}O{sub 2} on LPG fuel performance evaluation

    SciTech Connect (OSTI)

    Khan, Muhammad Saad Ahmed, Iqbal Mutalib, Mohammad Ibrahim bin Abdul Nadeem, Saad Ali, Shahid

    2014-10-24

    The objective of this mode of combustion is to insertion of hydrogen peroxide (H{sub 2}O{sub 2}) to the Liquefied Petroleum Gas (LPG) combustion on spark plug ignition engines. The addition of hydrogen peroxide may probably decrease the formation of NO{sub x}, CO{sub x} and unburned hydrocarbons. Hypothetically, Studies have shown that addition of hydrogen peroxide to examine the performance of LPG/H{sub 2}O{sub 2} mixture in numerous volumetric compositions starting from lean LPG until obtaining a better composition can reduce the LPG fuel consumption. The theory behind this idea is that, the addition of H{sub 2}O{sub 2} can cover the lean operation limit, increase the lean burn ability, diminution the burn duration along with controlling the exhaust emission by significantly reducing the greenhouse gaseous.

  8. Evaluation of aftermarket LPG conversion kits in light-duty vehicle applications. Final report

    SciTech Connect (OSTI)

    Bass, E.A.

    1993-06-01

    SwRI was contracted by NREL to evaluate three LPG conversion kits on a Chevrolet Lumina. The objective of the project was to measure the Federal Test Procedure (FTP) emissions and fuel economy of these kits, and compare their performance to gasoline-fueled operation and to each other. Varying LPG fuel blends allowed a preliminary look at the potential for fuel system disturbance. The project required kit installation and adjustment according to manufacturer`s instructions. A limited amount of trouble diagnosis was also performed on the fuel systems. A simultaneous contract from the Texas Railroad Commission, in cooperation with NREL, provided funds for additional testing with market fuels (HD5 propane and industry average gasoline) and hydrocarbon (HC) emissions speciation to determine the ozone-forming potential of LPG HC emissions. This report documents the procurement, installation, and testing of these LPG conversion kits.

  9. Hydrocracking distillate feedstocks

    SciTech Connect (OSTI)

    Kurganov, V.M.; Gorshtein, A.B.; Shkol'nik, B.L.; Shtein, V.I.

    1987-05-01

    The main shortcoming of single-stage hydrocracking is the very high level of feedstock cracking. The authors discuss the development of multistage technology in which each stage can operate under optimal conditions at a moderate conversion level, better flexibility in process control, and better process indexes. The main feature of the multistage technology is the preliminary hydrogenation of the original feed. The composition of the original feed and the middle distillate cuts obtaining in two-stage hydrocracking of a vacuum distillate from West Siberian crude, using cobalt-molybdenum oxide catalyst in the first stage and a zeolitic catalyst in the second stage is presented. Data is provided on the influence of pressure on the hydrocracking indexes.

  10. An analysis of weep holes as a product detection device for underground compensated LPG storage systems

    SciTech Connect (OSTI)

    Sarica, C.; Demir, H.M.; Brill, J.P.

    1996-09-01

    Weep holes have been used widely to detect the presence of Liquefied Petroleum Gases (LPG) in brine for underground compensated storage systems. When the brine level drops below the weep hole, LPG product enters the brine production system causing an increase in both tubing head pressure and flow rate. To prevent cavern overfill, a cavern shutdown is initiated upon detection of LPG in the surface brine system by pressure or flow instruments at the tubing head. In this study, we have investigated the multiphase flow characteristics of weep hole LPG detection systems to correctly estimate the operating limits. A simple and easy to use model has been developed to predict the tubing head pressure and flow rate increases. The model can be used to implement safer and more efficient operation procedures for underground compensated LPG storage systems. The model predictions for a typical field case are presented. An analysis of weep holes as product detection devices for LPG storage reservoirs has been carried out. It was found that the increases in pressure and flow rates at the tubing head change as a function of injection flow rate of the product. Therefore, a thorough consideration of cavern operating parameters is necessary to evaluate the use constant pressure and flow rate values to initiate emergency shut down of the cavern.

  11. Offshore refrigerated LPG loading/unloading terminal using a CALM buoy

    SciTech Connect (OSTI)

    Bonjour, E.L.; Simon, J.M.

    1985-03-01

    In existing Liquefied Petroleum Gases terminals, the transfer of liquefied gases to the tanker is performed via articulated loading arms or flexible hoses, working under quasistatic conditions. The tanker has to be firmly moored alongside a jetty or a process barge in a protected area (such as a harbour in most cases). This paper gives the main results of the development of an offshore refrigerated LPG (-48/sup 0/C) loading/unloading system, using a CALM buoy and LPG floating hoses working under dynamic conditions. The aim of this new concept is to replace the standard harbour structure for loading/unloading refrigerated LPG and to provide a considerable reduction in investments and a greater flexibility regarding the terminal location. The main components of that terminal have been designed so as to enable the loading of a 75 000 cubic meter LPG carrier in 15 hours. The results of static and dynamic low temperature tests on a LPG swivel joint for CALM buoy and LPG floating hoses show that such a SPM terminal is now a realistic solution.

  12. The Products of the Destructive Distillation of Keratin in the Form of Leather

    E-Print Network [OSTI]

    Rose, Reed Phillips

    1913-01-01

    are treated under the same conditions* Prom our knowledge of the de­ structive distillation of organic substances, the most common of which are coal, wood, bones, peat and lignite, it is reasonable to conclude also that the destructive distillation... the question as to what are the char­ acteristic properties of the two carbon residues 20 obtained from the decomposition of carbonaceous materials, termed coke and charcoal. Some author­ ities use the term coke for the carbon residue from coal and call all...

  13. Data acquisition, distillation,Data acquisition, distillation, and storageand storage

    E-Print Network [OSTI]

    ' to executeDetermines `best time' to execute a program based on weather,a program based on weather, arrayData acquisition, distillation,Data acquisition, distillation, and storageand storage · FASR will produce ~10 Tbyte/day at maturity · "Raw" data products include visibility data, M&C data, calibration

  14. A simple correlation to predict the hydrate quadruple point temperature for LPG mixtures

    SciTech Connect (OSTI)

    Yousif, M.H.

    1997-12-31

    A simple correlation to predict the hydrate upper quadruple point temperature, T{sub Q2B} for liquefied petroleum gas (LPG) mixtures was developed. It was developed for use as a part of a modeling and control system for a LPG pipeline in Russia. For performance reasons, a simple hydrate prediction correlation was required that could be incorporated into the real-time and predictive pipeline simulation models. The operating company required both real time and predictive simulation tools be developed to assist in preventing hydrate blockages while minimizing the use of methanol. In this particular pipeline, LPG fluid moves through the pipeline as a single phase liquid above its bubble point pressure. Because of the very low flow rates, the trace amount of water present in the LPG drops out and creates water pools at low points in the pipeline. The pipeline pressure and seasonal temperatures are conducive for hydrate formation in these pools. Methanol and monoethylene glycol (MEG) are injected in the pipeline to help prevent hydrate formation. The newly developed correlation predicts the hydrate quadruple point temperature using only the composition and the molecular weight of the LPG mixture while retaining an accuracy comparable to the statistical thermodynamic models throughout the range of normal operating conditions.

  15. Determination of combustion products from alternative fuels - part 1. LPG and CNG combustion products

    SciTech Connect (OSTI)

    Whitney, K.A.; Bailey, B.K.

    1994-10-01

    This paper describes efforts underway to identify volatile organic exhaust species generated by a light-duty vehicle operating over the Federal Test Procedure (FTP) on CNG and LPG, and to compare them to exhaust constituents generated from the same vehicle operating on a fuel blended to meet California Phase 2 specifications. The exhaust species from this vehicle were identified and quantified for fuel/air equivalence ratios of 0.8, 1.0, and 1.2, nominally, and were analyzed with and without the vehicle`s catalytic converter in place to determine the influence of the vehicle`s catalyst on species formation. Speciation data showed greater than 87 percent of all LPG and greater than 95 percent of all CNG hydrocarbon exhaust constituents to be composed of C{sub 1} to C{sub 3} compounds. In addition, toxic emissions from the combustion of CNG and LPG were as low as 10 percent of those generated by combustion of gasoline. A comparison of ozone forming potential of the three fuels was made based on the Maximum Incremental Reactivity scale used by the California Air Resources Board. Post-catalyst results from stoichiometric operation indicated that LPG and CNG produced 63 percent and 88 percent less potential ozone than reformulated gasoline, respectively. On average over all equivalence ratios, CNG and LPG exhaust constituents were approximately 65 percent less reactive than those from reformulated gasoline. 4 refs., 3 figs., 14 tabs.

  16. New Design Methods And Algorithms For High Energy-Efficient And Low-cost Distillation Processes

    SciTech Connect (OSTI)

    Agrawal, Rakesh

    2013-11-21

    This project sought and successfully answered two big challenges facing the creation of low-energy, cost-effective, zeotropic multi-component distillation processes: first, identification of an efficient search space that includes all the useful distillation configurations and no undesired configurations; second, development of an algorithm to search the space efficiently and generate an array of low-energy options for industrial multi-component mixtures. Such mixtures are found in large-scale chemical and petroleum plants. Commercialization of our results was addressed by building a user interface allowing practical application of our methods for industrial problems by anyone with basic knowledge of distillation for a given problem. We also provided our algorithm to a major U.S. Chemical Company for use by the practitioners. The successful execution of this program has provided methods and algorithms at the disposal of process engineers to readily generate low-energy solutions for a large class of multicomponent distillation problems in a typical chemical and petrochemical plant. In a petrochemical complex, the distillation trains within crude oil processing, hydrotreating units containing alkylation, isomerization, reformer, LPG (liquefied petroleum gas) and NGL (natural gas liquids) processing units can benefit from our results. Effluents from naphtha crackers and ethane-propane crackers typically contain mixtures of methane, ethylene, ethane, propylene, propane, butane and heavier hydrocarbons. We have shown that our systematic search method with a more complete search space, along with the optimization algorithm, has a potential to yield low-energy distillation configurations for all such applications with energy savings up to 50%.

  17. Distributive Distillation Enabled by Microchannel Process Technology...

    Office of Scientific and Technical Information (OSTI)

    distillation for new plants. A design concept for a modular microchannel distillation unit was developed in Task 3. In Task 4, Ultrasonic Additive Machining (UAM) was evaluated...

  18. New and existing gas wells promise bountiful LPG output in Michigan

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    Michigan remains the leading LP-gas producer in the Northeast quadrant of the U.S. This paper reports that boosted by a number of new natural gas wells and a couple of new gas processing plants, the state is firmly anchored in the butane/propane production business. Since 1981, more than 100 deep gas wells, most in excess of 8000 feet in depth, have been completed as indicated producers in the state. Many of these are yielding LPG-grade stock. So, combined with LPG-grade production from shallower geologic formations, the supply picture in this area looks promising for the rest of the country.

  19. Ageing effect in spray pyrolysed B:SnO{sub 2} thin films for LPG sensing

    SciTech Connect (OSTI)

    Skariah, Benoy E-mail: dr.boben1@gmail.com; Thomas, Boben E-mail: dr.boben1@gmail.com

    2014-10-15

    For LPG sensing, boron doped (0.2 to 0.8 wt. %) polycrystalline tin oxide thin films are deposited by spray pyrolysis in the temperature range 325 - 430 °C. Sensor response of 56 % is achieved for 1000 ppm of LPG, at an operating temperature of 350 °C. The effects of ageing under ambient conditions on the sensor response are investigated for a storage period of six years. Ageing increases the film resistance but the gas response is lowered. XRD, SEM, FESEM, FTIR and XPS are utilized for structural, morphological and compositional charaterisations.

  20. SRC Residual fuel oils

    DOE Patents [OSTI]

    Tewari, Krishna C. (Whitehall, PA); Foster, Edward P. (Macungie, PA)

    1985-01-01

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  1. SRC residual fuel oils

    SciTech Connect (OSTI)

    Tewari, K.C.; Foster, E.P.

    1985-10-15

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  2. Optimal Control of Distillation Systems 

    E-Print Network [OSTI]

    Chatterjee, N.; Suchdeo, S. R.

    1984-01-01

    The optimum performance of a distillation system can be evaluated by examining the product purities, the product recoveries, and the system's capability to respond to small or large, expected or unexpected, plant disturbances. An optimal control...

  3. Planning Through Stochastic Local Search and Temporal Action Graphs in LPG

    E-Print Network [OSTI]

    Gerevini, A; Serina, I; 10.1613/jair.1183

    2011-01-01

    We present some techniques for planning in domains specified with the recent standard language PDDL2.1, supporting 'durative actions' and numerical quantities. These techniques are implemented in LPG, a domain-independent planner that took part in the 3rd International Planning Competition (IPC). LPG is an incremental, any time system producing multi-criteria quality plans. The core of the system is based on a stochastic local search method and on a graph-based representation called 'Temporal Action Graphs' (TA-graphs). This paper focuses on temporal planning, introducing TA-graphs and proposing some techniques to guide the search in LPG using this representation. The experimental results of the 3rd IPC, as well as further results presented in this paper, show that our techniques can be very effective. Often LPG outperforms all other fully-automated planners of the 3rd IPC in terms of speed to derive a solution, or quality of the solutions that can be produced.

  4. Distillation process using microchannel technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Dublin, OH); Simmons, Wayne W. (Dublin, OH); Silva, Laura J. (Dublin, OH); Qiu, Dongming (Carbondale, IL); Perry, Steven T. (Galloway, OH); Yuschak, Thomas (Dublin, OH); Hickey, Thomas P. (Dublin, OH); Arora, Ravi (Dublin, OH); Smith, Amanda (Galloway, OH); Litt, Robert Dwayne (Westerville, OH); Neagle, Paul (Westerville, OH)

    2009-11-03

    The disclosed invention relates to a distillation process for separating two or more components having different volatilities from a liquid mixture containing the components. The process employs microchannel technology for effecting the distillation and is particularly suitable for conducting difficult separations, such as the separation of ethane from ethylene, wherein the individual components are characterized by having volatilities that are very close to one another.

  5. Distillation Column Flooding Predictor

    SciTech Connect (OSTI)

    George E. Dzyacky

    2010-11-23

    The Flooding Predictor™ is a patented advanced control technology proven in research at the Separations Research Program, University of Texas at Austin, to increase distillation column throughput by over 6%, while also increasing energy efficiency by 10%. The research was conducted under a U. S. Department of Energy Cooperative Agreement awarded to George Dzyacky of 2ndpoint, LLC. The Flooding Predictor™ works by detecting the incipient flood point and controlling the column closer to its actual hydraulic limit than historical practices have allowed. Further, the technology uses existing column instrumentation, meaning no additional refining infrastructure is required. Refiners often push distillation columns to maximize throughput, improve separation, or simply to achieve day-to-day optimization. Attempting to achieve such operating objectives is a tricky undertaking that can result in flooding. Operators and advanced control strategies alike rely on the conventional use of delta-pressure instrumentation to approximate the column’s approach to flood. But column delta-pressure is more an inference of the column’s approach to flood than it is an actual measurement of it. As a consequence, delta pressure limits are established conservatively in order to operate in a regime where the column is never expected to flood. As a result, there is much “left on the table” when operating in such a regime, i.e. the capacity difference between controlling the column to an upper delta-pressure limit and controlling it to the actual hydraulic limit. The Flooding Predictor™, an innovative pattern recognition technology, controls columns at their actual hydraulic limit, which research shows leads to a throughput increase of over 6%. Controlling closer to the hydraulic limit also permits operation in a sweet spot of increased energy-efficiency. In this region of increased column loading, the Flooding Predictor is able to exploit the benefits of higher liquid/vapor traffic that produce increased contact area and lead to substantial increases in separation efficiency – which translates to a 10% increase in energy efficiency on a BTU/bbl basis. The Flooding Predictor™ operates on the principle that between five to sixty minutes in advance of a flooding event, certain column variables experience an oscillation, a pre-flood pattern. The pattern recognition system of the Flooding Predictor™ utilizes the mathematical first derivative of certain column variables to identify the column’s pre-flood pattern(s). This pattern is a very brief, highly repeatable, simultaneous movement among the derivative values of certain column variables. While all column variables experience negligible random noise generated from the natural frequency of the process, subtle pre-flood patterns are revealed among sub-sets of the derivative values of column variables as the column approaches its hydraulic limit. The sub-set of column variables that comprise the pre-flood pattern is identified empirically through in a two-step process. First, 2ndpoint’s proprietary off-line analysis tool is used to mine historical data for pre-flood patterns. Second, the column is flood-tested to fine-tune the pattern recognition for commissioning. Then the Flooding Predictor™ is implemented as closed-loop advanced control strategy on the plant’s distributed control system (DCS), thus automating control of the column at its hydraulic limit.

  6. Technical evaluation and assessment of CNG/LPG bi-fuel and flex-fuel vehicle viability

    SciTech Connect (OSTI)

    Sinor, J E

    1994-05-01

    This report compares vehicles using compressed natural gas (CNG), liquefied petroleum gas (LPG), and combinations of the two in bi-fuel or flex-fuel configurations. Evidence shows that environmental and energy advantages can be gained by replacing two-fuel CNG/gasoline vehicles with two-fuel or flex-fuel systems to be economically competitive, it is necessary to develop a universal CNG/LPG pressure-regulator-injector and engine control module to switch from one tank to the other. For flex-fuel CNG/LPG designs, appropriate composition sensors, refueling pumps, fuel tanks, and vaporizers are necessary.

  7. New Design Methods and Algorithms for Multi-component Distillation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    isomerization, reforming, and the processing of crude oil, liquefied petroleum gas (LPG), and natural gas liquids (NGL). Project Description The main goal of this research...

  8. LIQUID PROPANE GAS (LPG) STORAGE AREA BOILING LIQUID EXPANDING VAPOR EXPLOSION (BLEVE) ANALYSIS

    SciTech Connect (OSTI)

    PACE, M.E.

    2004-01-13

    The PHA and the FHAs for the SWOC MDSA (HNF-14741) identified multiple accident scenarios in which vehicles powered by flammable gases (e.g., propane), or combustible or flammable liquids (e.g., gasoline, LPG) are involved in accidents that result in an unconfined vapor cloud explosion (UVCE) or in a boiling liquid expanding vapor explosion (BLEVE), respectively. These accident scenarios are binned in the Bridge document as FIR-9 scenarios. They are postulated to occur in any of the MDSA facilities. The LPG storage area will be in the southeast corner of CWC that is relatively remote from store distaged MAR. The location is approximately 30 feet south of MO-289 and 250 feet east of 2401-W by CWC Gate 10 in a large staging area for unused pallets and equipment.

  9. Converting LPG caverns to natural-gas storage permits fast response to market

    SciTech Connect (OSTI)

    Crossley, N.G.

    1996-02-19

    Deregulation of Canada`s natural-gas industry in the late 1980s led to a very competitive North American natural-gas storage market. TransGas Ltd., Regina, Sask., began looking for method for developing cost-effective storage while at the same time responding to new market-development opportunities and incentives. Conversion of existing LPG-storage salt caverns to natural-gas storage is one method of providing new storage. To supply SaskEnergy Inc., the province`s local distribution company, and Saskatchewan customers, TransGas previously had developed solution-mined salt storage caverns from start to finish. Two Regina North case histories illustrate TransGas` experiences with conversion of LPG salt caverns to gas storage. This paper provides the testing procedures for the various caverns, cross-sectional diagrams of each cavern, and outlines for cavern conversion. It also lists storage capacities of these caverns.

  10. Full Report.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    g,h Retail Electricity Total Energy g,i Coal Natural Gas a Petroleum Nuclear Fuel Biomass Total g,h,i Distillate Fuel Oil Jet Fuel b LPG c Motor Gasoline d Residual Fuel Oil...

  11. Assisted distillation of quantum coherence

    E-Print Network [OSTI]

    Chitambar, E; Rana, S; Bera, M N; Adesso, G; Lewenstein, M

    2015-01-01

    We introduce and study the task of assisted coherence distillation. This task arises naturally in bipartite systems where both parties work together to generate the maximal possible coherence on one of the subsystems. Only incoherent operations are allowed on the target system while general local quantum operations are permitted on the other, an operational paradigm that we call local quantum-incoherent operations and classical communication (LQICC). We show that the asymptotic rate of assisted coherence distillation for pure states is equal to the coherence of assistance, a direct analog of the entanglement of assistance, whose properties we characterize. Our findings imply a novel interpretation of the von Neumann entropy: it quantifies the maximum amount of extra quantum coherence a system can gain when receiving assistance from a collaborative party. Our results are generalized to coherence localization in a multipartite setting and possible applications are discussed.

  12. Mild hydrocracking: a low cost route to more distillate

    SciTech Connect (OSTI)

    Kalnes, T.N.; Lamb, P.R.; Pegg, D.R.; Tajbl, D.G.

    1984-03-01

    The UOP MHC Unibon process, a relatively new application of distillate hydrocracking technology, combines the features of desulfurization and hydrocracking to provide a useful tool to aid the refiner in meeting future product demand trends. Already commercialized in four locations, the process is particularly attractive to those refiners who do not have residual conversion capacity. Pay backs of less than one year are common. In addition, the process can provide the FCC refiner with added capability for adjusting the product slate to meet seasonal demands.

  13. Distributive Distillation Enabled by Microchannel Process Technology...

    Office of Scientific and Technical Information (OSTI)

    a modular microchannel distillation unit was developed in Task 3. In Task 4, Ultrasonic Additive Machining (UAM) was evaluated as a manufacturing method for microchannel...

  14. Energy Recovery in Industrial Distillation Processes 

    E-Print Network [OSTI]

    Paul, D. B.

    1983-01-01

    Distillation processes are energy intensive separation processes which present attractive opportunities for energy conservation. Through the use of multistage vapor recompression, heat which is normally unavailable can be ...

  15. Evaluation of aftermarket fuel delivery systems for natural gas and LPG vehicles

    SciTech Connect (OSTI)

    Willson, B.

    1992-09-01

    This study was designed to evaluate the effectiveness of aftermarket fuel delivery systems for vehicles fueled by compressed natural gas (CNG) and liquefied petroleum gas (LPG). Most of the CNG and LPG vehicles studied were converted to the alternative fuel after purchase. There are wide variations in the quality of the conversion hardware and the installation. This leads to questions about the overall quality of the converted vehicles, in terms of emissions, safety, and performance. There is a considerable body of emissions data for converted light-duty vehicles, and a smaller amount for medium- and heavy-duty vehicles. However, very few of these data involve real world conditions, and there is growing concern about in-use emissions. This report also attempts to assess factors that could allow in-use emissions to vary from the ``best-case`` results normally reported. The study also addresses issues of fuel supply, fuel composition, performance, safety, and warranty waivers. The report is based on an extensive literature and product survey and on the author`s experience with fuel delivery systems for light-duty vehicles.

  16. Evaluation of aftermarket fuel delivery systems for natural gas and LPG vehicles

    SciTech Connect (OSTI)

    Willson, B. )

    1992-09-01

    This study was designed to evaluate the effectiveness of aftermarket fuel delivery systems for vehicles fueled by compressed natural gas (CNG) and liquefied petroleum gas (LPG). Most of the CNG and LPG vehicles studied were converted to the alternative fuel after purchase. There are wide variations in the quality of the conversion hardware and the installation. This leads to questions about the overall quality of the converted vehicles, in terms of emissions, safety, and performance. There is a considerable body of emissions data for converted light-duty vehicles, and a smaller amount for medium- and heavy-duty vehicles. However, very few of these data involve real world conditions, and there is growing concern about in-use emissions. This report also attempts to assess factors that could allow in-use emissions to vary from the best-case'' results normally reported. The study also addresses issues of fuel supply, fuel composition, performance, safety, and warranty waivers. The report is based on an extensive literature and product survey and on the author's experience with fuel delivery systems for light-duty vehicles.

  17. Analysis and Control of Heteroazeotropic Batch Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    , called an entrainer, has to be added to facilitate separation and enhance distillation. When a heavy entrainer is added continuously in the top section of the batch column the process is called extractive batch distillation. When an entrainer is added batchwise to the original mixture we simply call

  18. Investigation on effects of surface morphologies on response of LPG sensor based on nanostructured copper ferrite system

    SciTech Connect (OSTI)

    Singh, Satyendra; Yadav, B.C.; Gupta, V.D.; Dwivedi, Prabhat K.

    2012-11-15

    Graphical abstract: Figure shows the variations in resistance with time for copper ferrite system synthesized in various molar ratio. A maximum variation in resistance was observed for copper ferrite prepared in 1:1 molar ratio. Highlights: ? Evaluation of structural, optical and surface morphologies. ? Significant variation in LPG sensing properties. ? Surface modification of ferric oxide pellet by copper ferrite. ? CuFe{sub 2}O{sub 4} pellets for LPG sensing at room temperature. -- Abstract: Synthesis of a copper ferrite system (CuFe{sub 2}O{sub 4}) via chemical co-precipitation method is characterized by X-ray diffraction, surface morphology (scanning electron microscope) and optical absorption spectroscopy. These characteristics show their dependence on the relative compositions of the two subsystems. They are further confirmed by the variation in the band gap. A study of gas sensing properties shows the spinel CuFe{sub 2}O{sub 4} synthesized in 1:1 molar ratio exhibit best response to LPG adsorption/resistance measurement. Thus resistance based LPG sensor is found robust, cheap and may be applied for kitchens and industrial applications.

  19. 2015 NIST EPO No. 26 LPG Liquid Measuring Systems (Rev (09/14) Page 1 of 6

    E-Print Network [OSTI]

    particular attention to the condition of the product storage tank and valves. - Check to be certain around in wet, slippery areas and in climbing on prover, storage tanks, and vehicles. - Use personal for the type of inspection activity. H-44 General Code and LPG and Anhydrous Ammonia LMD Code References - 2015

  20. Absorptive Recycle of Distillation Waste Heat 

    E-Print Network [OSTI]

    Erickson, D. C.; Lutz, E. J., Jr.

    1982-01-01

    condenser operates above ambient temperature, the rejected heat also contains unused availability. By incorporating an absorption heat pump (AHP) into the distillation process, these sources of unused availability can be tapped so as to recycle (and hence...

  1. An improved model for multiple effect distillation

    E-Print Network [OSTI]

    Mistry, Karan H.

    Increasing global demand for fresh water is driving research and development of advanced desalination technologies. As a result, a detailed model of multiple effect distillation (MED) is developed that is flexible, simple ...

  2. Development of energy efficient membrane distillation systems

    E-Print Network [OSTI]

    Summers, Edward K

    2013-01-01

    Membrane distillation (MD) has shown potential as a means of desalination and water purification. As a thermally driven membrane technology which runs at relatively low pressure, which can withstand high salinity feed ...

  3. Minimizing corrosion in coal liquid distillation

    DOE Patents [OSTI]

    Baumert, Kenneth L. (Emmaus, PA); Sagues, Alberto A. (Lexington, KY); Davis, Burtron H. (Georgetown, KY)

    1985-01-01

    In an atmospheric distillation tower of a coal liquefaction process, tower materials corrosion is reduced or eliminated by introduction of boiling point differentiated streams to boiling point differentiated tower regions.

  4. Electric Driven Heat Pumps in Distillation Processes 

    E-Print Network [OSTI]

    Harris, G. E.

    1983-01-01

    Radian Corporation, under contract to the Electric Power Research Institute, has recently completed a study of the potential range of application for retrofitting electric driven heat pumps to existing distillation columns. ...

  5. Blog Distillation via Sentiment-Sensitive Link Analysis

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Blog Distillation via Sentiment-Sensitive Link Analysis Giacomo Berardi, Andrea Esuli, Fabrizio blog distillation by adding a link analysis phase to the standard retrieval-by-topicality phase, where in blog distillation. 1 Introduction Blog distillation is a subtask of blog search. It is defined

  6. Nonresidential buildings energy consumption survey: 1979 consumption and expenditures. Part 2. Steam, fuel oil, LPG, and all fuels

    SciTech Connect (OSTI)

    Patinkin, L.

    1983-12-01

    This report presents data on square footage and on total energy consumption and expenditures for commercial buildings in the contiguous United States. Also included are detailed consumption and expenditures tables for fuel oil or kerosene, liquid petroleum gas (LPG), and purchased steam. Commercial buildings include all nonresidential buildings with the exception of those where industrial activities occupy more of the total square footage than any other type of activity. 7 figures, 23 tables.

  7. Inventory of China's Energy-Related CO2 Emissions in 2008

    E-Print Network [OSTI]

    Fridley, David

    2011-01-01

    Diesel Oil Fuel Oil LPG Refinery Gas Other Petroleumgas/diesel oil residual fuel oil LPG ethane naphtha bitumenand fuel oil (residual), LPG, refinery gas/still gas,

  8. Entanglement distillation in optomechanics via unsharp measurements

    E-Print Network [OSTI]

    Víctor Montenegro; Alessandro Ferraro; Sougato Bose

    2015-03-15

    Quantum technologies based on optical Gaussian states have proven very promising in terms of scalability. However, their use in quantum networking is hindered by the fact that Gaussian entanglement cannot be distilled via Gaussian operations. We take advantage of hybrid optomechanical systems to address this problem, proposing a scheme to distill optical two-mode squeezed vacua via unsharp measurements. Here, one of the optical modes is injected into a single sided Fabry-P\\'{e}rot cavity and non-linearly coupled to a mechanical oscillator. Afterwards, the position of the oscillator is measured using pulsed optomechanics and homodyne detection. Our results show that this measurement can conditionally increase the initial entanglement under an optimal radiation-pressure interaction strength, which corresponds to an effective unsharp non-Gaussian measurement of the photon number inside the cavity. We show how the resulting entanglement distillation can be verified by using a standard quantum teleportation procedure.

  9. Integrated C3 Feedstock and Aggregated Distillation Model for

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Zamarripa, Pablo A. Marchetti, Ignacio E. Grossmann Department of Chemical Engineering Carnegie Mellon Polypropylene Propane return Reactor effluent Distillation Polymerization FeedTank Propylene (91%) Goal: Select rates Constraints on composition of Propane Return, Distillation Overhead & Reactor Feed Limits

  10. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01

    homes in the United States use middle distillate as a primary energy source for heating. -homes in the United States use middle distillate as their primary energy source for heating. -

  11. A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2012-01-01

    Fuel oil Distillate Fuel Oil LPG Other washed coal Crude oildistillate fuel oil IEA value for LPG is a typical value andFuel Distillate Fuel oil Oil LPG For this study, the

  12. Crude Distillation Unit Heat Recovery Study 

    E-Print Network [OSTI]

    John, P.

    1979-01-01

    Baytown's Pipe Still 3 is a 95,000 barrel per day crude distillation unit. A comprehensive heat recovery and energy utilization study was done on Pipe Still 3 after a preliminary cursory study had indicated that an overall look at the total picture...

  13. Intelligent fuzzy supervisory control for distillation columns 

    E-Print Network [OSTI]

    Santhanam, Srinivasan

    1993-01-01

    (disturbance) and the response of the top tray temperature(controlled variable). This thesis will also outline a simulation software to characterize a benzene-toluene binary distillation column and an X-window based Graphical User Interface to run the simulation....

  14. Energy Conservation Options in Distillation Processes 

    E-Print Network [OSTI]

    Harris, G. E.; Hearn, W. R.; Blythe, G. M.; Stuart, J. M.

    1980-01-01

    of theoretical trays in any re boiled distillation column. Columns in which all of the required heat enters with the feed cannot achieve i I I ....e-.........c..._. I "

  15. Complex Distillation Arrangements : Extending the Petlyuk Ideas

    E-Print Network [OSTI]

    Skogestad, Sigurd

    and Technology N--7034 Trondheim Norway Abstract The task of separating a multicomponent mixture into streams shell using dividing walls or vertical partitions. INTRODUCTION Industrial distillation processes is also known as the Petlyuk column, due to a theoretical study of Pet­ lyuk et al. (1965), or as a fully

  16. Complex Distillation Arrangements : Extending the Petlyuk Ideas

    E-Print Network [OSTI]

    Skogestad, Sigurd

    and Technology N­7034 Trondheim Norway Abstract The task of separating a multicomponent mixture intostreams shell using dividing walls or vertical partitions. INTRODUCTION Industrial distillation processes is also known as the Petlyuk column, due to a theoretical study of Pet- lyuk et al. (1965), or as a fully

  17. Advanced Distillation: Programs Proposed to DOE 

    E-Print Network [OSTI]

    Woinsky, S. G.

    2001-01-01

    to the foremost practitioner of the Advanced Distillation art, due to a 30 year continuity in Ule area as both a consultant and a university professor. His consulting assignments lu1ve been long-ternl companies such as M, W, Kellogg... when a plgasoline have lead...

  18. New Design Methods and Algorithms for Multi-component Distillation...

    Broader source: Energy.gov (indexed) [DOE]

    multicomponent.pdf More Documents & Publications CX-100137 Categorical Exclusion Determination ITP Chemicals: Hybripd SeparationsDistillation Technology. Research Opportunities...

  19. CHEM333: Lab Experiment 3: Distillation and Gas Chromatography

    E-Print Network [OSTI]

    Taber, Douglass

    . Distillation is used to isolate many of life's essentials such as gasoline from oil or brandy from wineCHEM­333: Lab Experiment 3: Distillation and Gas Chromatography: Prelab-Assignment: read Chapters 5 and 6. Distillation is one of the most powerful techniques for purifying volatile organic compounds

  20. Clean air program: Design guidelines for bus transit systems using liquefied petroleum gas (LPG) as an alternative fuel. Final report, July 1995-April 1996

    SciTech Connect (OSTI)

    Raj, P.K.; Hathaway, W.T.; Kangas, R.

    1996-09-01

    The Federal Transit Administration (FTA) has initiated the development of `Design Guidelines for Bus Transit Systems Using Alternative Fuels.` This report provides design guidelines for the safe uses of Liquefied Petroleum Gas (LPG). It forms a part of the series of individual monographs being published by the FTA on (the guidelines for the safe use of) Compressed Natural Gas (CNG), Liquefied Natural Gas (LNG), Liquefied Petroleum Gas (LPG) and alcohol fuels (Methanol and Ethanol). Each report in this series describes for the subject fuel the important fuel properties, guidelines for the design and operation of bus fueling, storage and maintenance facilities, issues on personnel training and emergency preparedness.

  1. Production of gasoline and distillate fuels from light cycle oil

    SciTech Connect (OSTI)

    Derr, W.R. Jr.; Owens, P.J.; Sarli, M.S.

    1991-01-15

    This patent describes a process for the co-production of high quality gasoline and distillate products from catalytically cracked feedstocks. It comprises: hydrocracking a substantially dealkylated feedstock with a hydrocracking catalyst at a hydrogen partial pressure not greater than 1200 psig and a conversion to gasoline boiling range products not more than 75 wt. percent; separating the products of hydrocracking into a gasoline boiling range fraction, a first distillate range fraction boiling immediately above the gasoline fraction with an end point in the range of 450{degrees} to 500{degrees} F. and a second distillate fraction boiling above the first distillate fraction; recycling at least a portion of the first distillate fraction to the hydrocracking step to effect saturation and partial cracking of aromatics in the recycled fraction to increase the paraffin content of the second distillate fraction; recovering the second distillate fraction.

  2. Apparatus for distilling shale oil from oil shale

    SciTech Connect (OSTI)

    Shishido, T.; Sato, Y.

    1984-02-14

    An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

  3. Cr-free Fe-based metal oxide catalysts for high temperature water gas shift reaction of fuel processor using LPG

    SciTech Connect (OSTI)

    lee, Joon Y.; Lee, Dae-Won; Lee, Kwan Young; Wang, Yong

    2009-08-15

    The goal of this study was to identify the most suitable chromium-free iron-based catalysts for the HTS (high temperature shift) reaction of a fuel processor using LPG. Hexavalent chromium (Cr6+) in the commercial HTS catalyst has been regarded as hazardous material. We selected Ni and Co as the substitution for chromium in the Fe-based HTS catalyst and investigated the HTS activities of these Crfree catalysts at LPG reformate condition. Cr-free Fe-based catalysts which contain Ni, Zn, or Co instead of Cr were prepared by coprecipitation method and the performance of the catalysts in HTS was evaluated under gas mixture conditions (42% H2, 10% CO, 37% H2O, 8% CO2, and 3% CH4; R (reduction factor): about 1.2) similar to the gases from steam reforming of LPG (100% conversion at steam/carbon ratio = 3), which is higher than R (under 1) of typically studied LNG reformate condition. Among the prepared Cr-free Febased catalysts, the 5 wt%-Co/Fe/20 wt%-Ni and 5 wt%-Zn/Fe/20 wt%-Ni catalysts showed good catalytic activity under this reaction condition simulating LPG reformate gas.

  4. Zn-doped and undoped SnO{sub 2} nanoparticles: A comparative structural, optical and LPG sensing properties study

    SciTech Connect (OSTI)

    Mishra, R.K.; Sahay, P.P.

    2012-12-15

    Graphical abstract: The X-ray diffraction (XRD) analyses confirm that all the materials prepared are polycrystalline SnO{sub 2} possessing tetragonal rutile structure. On Zn-doping, the crystallite size has been found to decrease from 25 nm (undoped sample) to 13 nm (1 at% Zn-doped sample). Display Omitted Highlights: ? Zn-doped SnO{sub 2} nanoparticles show smaller crystallite size (11–17 nm). ? Optical band gap in SnO{sub 2} nanoparticles increases on Zn-doping. ? 2 at% Zn-doped sample show minimum room temperature resistivity. ? LPG response of the Zn-doped SnO{sub 2} nanoparticles increases considerably. ? 1 at% Zn-doped sample shows maximum response (87%) at 300 °C to 1 vol% concentration. -- Abstract: SnO{sub 2} nanoparticles were prepared by the co-precipitation method with SnCl{sub 4}·5H{sub 2}O as the starting material and Zn(CH{sub 3}COO){sub 2}·2H{sub 2}O as the source of dopant. All the materials prepared have been found to be polycrystalline SnO{sub 2} possessing tetragonal rutile structure with crystallite sizes in the range 11–25 nm. Optical analyses reveal that for the SnO{sub 2} nanoparticles, both undoped and Zn-doped, direct transition occurs with the bandgap energies in the range 3.05–3.41 eV. Variation in the room temperature resistivity of the SnO{sub 2} nanoparticles as a function of dopant concentration has been explained on the basis of two competitive processes: (i) replacement of Sn{sup 4+} ion by an added Zn{sup 2+} ion, and (ii) ionic compensation of Zn{sup 2+} by the formation of oxygen vacancies. Among all the samples examined for LPG sensing, the 1 at% Zn-doped sample exhibits fast and maximum response (?87%) at 300 °C for 1 vol% concentration of LPG in air.

  5. Production of gasoline and distillate fuels from light cycle oil

    SciTech Connect (OSTI)

    Derr, W.R. Jr.; Owens, P.J.; Sarli, M.S.

    1991-02-05

    This patent describes a process for the co-production of high quality gasoline and distillate products from catalytically cracked feedstocks. It comprises catalytically cracking a hydrocarbon feedstock to produce a substantially dealkylated cracked product, hydrocracking the substantially dealkylated product with a hydrocracking catalyst at a hydrogen partial pressure not greater than 1200 psig and a conversion to gasoline boiling range products not more than 75 wt. percent; separating the products of hydrocracking into a gasoline boiling range fraction, a first distillate range fraction boiling immediately above the gasoline fraction with an end point in the range of 450{degrees} to 500{degrees} F and a second, higher boiling distillate fraction which is more paraffinic than the first distillate fraction; recycling at least a portion of the first, lower boiling distillate fraction to the catalytic cracking step, recovering the second, higher boiling distillate fraction.

  6. Unifying classical and quantum key distillation

    E-Print Network [OSTI]

    Matthias Christandl; Artur Ekert; Michal Horodecki; Pawel Horodecki; Jonathan Oppenheim; Renato Renner

    2007-02-28

    Assume that two distant parties, Alice and Bob, as well as an adversary, Eve, have access to (quantum) systems prepared jointly according to a tripartite state. In addition, Alice and Bob can use local operations and authenticated public classical communication. Their goal is to establish a key which is unknown to Eve. We initiate the study of this scenario as a unification of two standard scenarios: (i) key distillation (agreement) from classical correlations and (ii) key distillation from pure tripartite quantum states. Firstly, we obtain generalisations of fundamental results related to scenarios (i) and (ii), including upper bounds on the key rate. Moreover, based on an embedding of classical distributions into quantum states, we are able to find new connections between protocols and quantities in the standard scenarios (i) and (ii). Secondly, we study specific properties of key distillation protocols. In particular, we show that every protocol that makes use of pre-shared key can be transformed into an equally efficient protocol which needs no pre-shared key. This result is of practical significance as it applies to quantum key distribution (QKD) protocols, but it also implies that the key rate cannot be locked with information on Eve's side. Finally, we exhibit an arbitrarily large separation between the key rate in the standard setting where Eve is equipped with quantum memory and the key rate in a setting where Eve is only given classical memory. This shows that assumptions on the nature of Eve's memory are important in order to determine the correct security threshold in QKD.

  7. American Distillation Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAand DaltonSolarOpen5AllEnergyAmeriPower LLC Jump to:Distillation Inc Jump

  8. Increasing Distillate Production at U.S. Refineries

    Reports and Publications (EIA)

    2010-01-01

    Paper explores the potential for U.S. refiners to create more distillate and less gasoline without major additional investments beyond those already planned.

  9. Volatile organic emissions from the distillation and pyrolysis of vegetation

    E-Print Network [OSTI]

    Greenberg, T

    2006-01-01

    emissions from vegetation pyrolysis Comprehensive laboratoryfrom the distillation and pyrolysis of vegetation J. P.J. Anal. and Appl. Pyrolysis, 60, 123–130, 2000. Fall, R. :

  10. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1999 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  11. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1998 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  12. Blog Distillation via Sentiment-Sensitive Link Analysis

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Blog Distillation via Sentiment-Sensitive Link Analysis Giacomo Berardi, Andrea Esuli, Fabrizio report a new approach to blog distillation, defined as the task in which, given a user query, the system ranks the blogs in descending order of relevance to the query topic. Our approach is based on the idea

  13. EXPERIMENTAL SIMULATION OF DISTILLATION COLUMN PROFILE MAPS

    E-Print Network [OSTI]

    Skogestad, Sigurd

    into one or more high-purity products. Several technologies are feasible for this task, either alone the most widely spread and has a long history in chemical technology. However, until recently, there has in accordance with theoretical predictions of CPM theory. #12;iv Residue curves (RCs) and pinch point curves

  14. Synthesis and design of optimal thermal membrane distillation networks 

    E-Print Network [OSTI]

    Nyapathi Seshu, Madhav

    2006-10-30

    Thermal membrane distillation is one of the novel separation methods in the process industry. It involves the simultaneous heat and mass transfer through a hydrophobic semipermeable membrane through the use of thermal energy to bring about...

  15. Membrane augmented distillation to separate solvents from water

    DOE Patents [OSTI]

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  16. Energy Saving in Distillation Using Structured Packing and Vapor Recompression 

    E-Print Network [OSTI]

    Hill, J.H.

    1987-01-01

    "Distillation is a big consumer of energy in process plant operations. A first step to energy cost savings is the use of high efficiency structured packing in place of trays or dumped packings in conventionally operated ...

  17. Energy Use in Distillation Operation: Nonlinear Economic Effects 

    E-Print Network [OSTI]

    White, D. C.

    2010-01-01

    Distillation operations are major consumers of energy, by some estimates comprising forty percent of the energy usage in the refining and chemicals industry. Obtaining the maximum energy efficiency from this unit operation is obviously very...

  18. Heat Integrated Distillation through Use of Microchannel Technology

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose goal is to develop a breakthrough distillation process using Microchannel Process Technology to integrate heat transfer and separation into a single unit operation.

  19. Absorption Cycle Fundamentals and Applications Guidelines for Distillation Energy Savings 

    E-Print Network [OSTI]

    Erickson, D. C.; Davidson, W. F.

    1984-01-01

    of applications, embody characteristics that inherently make them economic candidates for absorption cycle heat upgrading. Practical applications to current U.S. distillations could save 30 trillion BTU per year, at payback periods ranging from 1 to 3 years. So...

  20. Integrated Thermal and Hydraulic Analysis of Distillation Columns 

    E-Print Network [OSTI]

    Samant, K.; Sinclair, I.; Keady, G.

    2002-01-01

    and Hydraulic Analysis of Distillation Columns Ketan Samant, Aspen Technology Ian Sinclair, Aspen Technology Ginger Keady, Aspen Technology This paper outlines the implementation of column thermal and hydraulic analysis in a simulation environment...

  1. Energy Efficiency in Cryogenic Fractionation Through Distributive Distillation 

    E-Print Network [OSTI]

    Carradine, C. R.; McCue, R. H.

    1992-01-01

    The Advanced Recovery System (ARS) is a patented process that uses the principle of distributed distillation to achieve energy efficiency in the olefins process. This paper describes the concept of ARS and how, by integrating the chill...

  2. Heat Recovery in Distillation by Mechanical Vapor Recompression 

    E-Print Network [OSTI]

    Becker, F. E.; Zakak, A. I.

    1986-01-01

    IN DISTILLATION BY MECHANICAL VAPOR RECOMPRESSION Frederick E. Becker and Alexandra I. Zakak Tecogen, Inc., A Subsidiary of Thermo Electron Corporation Waltham, Massachusetts ABSTRACT A significant reduction in distillation tower energy requirements can..., and then recompressing the low-pressure bottom vapors and injecting them directly into the column bottom. The choice of either scheme is a function of the physical properties of the vapors; i.e., the specific volume of the top or bottom vapors may dictate the most...

  3. Table A3. Refiner/Reseller Prices of Distillate and Residual Fuel Oils,

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24,4,630.22 ConsumptionNonfuel"

  4. Table A3. Refiner/Reseller Prices of Distillate and Residual Fuel Oils,

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015" ,"Release7CubicthroughtheSeptember 24,4,630.22 ConsumptionNonfuel" PAD

  5. Biomass from Logging Residue and Mill Residue

    E-Print Network [OSTI]

    Biomass from Logging Residue and Mill Residue in East Texas, 2008 by Curtis L. VanderSchaaf, Forest Resource Analyst October 2009 #12;N Introduction The abundance of woody biomass from East Texas forests. This report represents the most current data on the availability of woody biomass in the form of logging

  6. Catalyst deactivation model for residual oil hydrodesulfurization

    SciTech Connect (OSTI)

    Takatsuka, T.; Higasino, S.; Hirohama, S. [Chiyoda Corporation, Yokohama (Japan)] [and others

    1995-12-31

    Hydrodesulfurization process plays a dominant role in the modern refineries to upgrade residual oil either by removing heterogeneous atoms or by hydrocracking the bottom to distillates products. The practical model is proposed to predict a catalyst life which is the most concern in the process. The catalyst is deactivated in the early stage of the operation by coke deposition on the catalyst active site. The ultimate catalyst life is determined by pore mouth plugging depending on its metal capacity. The phenomena are mathematically described by losses of catalyst surface area and effective diffusivity of feedstock molecules in catalyst pore. The model parameters were collected through the pilot plant tests with different types of catalysts and feedstocks.

  7. Distillation and Dehydro Reactors Advanced Process Conrol Freeport Texas PLant 

    E-Print Network [OSTI]

    Eisele, D.

    2014-01-01

    Reactors Advanced Process Control Freeport Texas Plant ESL-IE-14-05-16 Proceedings of the Thrity-Sixth Industrial Energy Technology Conference New Orleans, LA. May 20-23, 2014 G-KTI, Polyamide and Intermediates Distillation APC 6/2/2014 INTERNAL... Conference New Orleans, LA. May 20-23, 2014 G-KTI, Polyamide and Intermediates Distillation APC – Control Matrix 6/2/2014 INTERNAL; CONFIDENTIAL 3 ESL-IE-14-05-16 Proceedings of the Thrity-Sixth Industrial Energy Technology Conference New Orleans, LA. May 20...

  8. Automated Dispersive Solid Phase Extraction of Pesticide Residues in Botanicals using Triple Quadrupole LC/MS/MS

    E-Print Network [OSTI]

    Heller, Barbara

    /g ·Distilled water (10 mL) was added to the sample and mixed for 1min. ·Samples were then extracted using 10 mAutomated Dispersive Solid Phase Extraction of Pesticide Residues in Botanicals using Triple analysis in food and food products. These methods use acetonitrile extraction followed by salting out

  9. Application of a Plantwide Control Design Procedure to a Distillation Column with Heat Pump

    E-Print Network [OSTI]

    Skogestad, Sigurd

    (Larsson & Skogestad 2001) to a distillation column heat-integrated by using a heatpump. Top-down analysis) and apply it to a distillation column with heatpump. Plantwide control design should start by formulating

  10. Solar thermal powered desalination: membrane versus distillation technologies

    E-Print Network [OSTI]

    thermal energy (e.g. Koschikowski et al, 2003): #12;Solar thermal powered desalination: reviewSolar thermal powered desalination: membrane versus distillation technologies G. Burgess and K considered to be the desalination technology most suited to integration with concentrating solar thermal

  11. Energy efficient distillation Ivar J. Halvorsen a,*, Sigurd Skogestad b

    E-Print Network [OSTI]

    Skogestad, Sigurd

    savings in energy consumption and reduction of investment cost. In this paper we give an overview of some and calculate energy requirements and provide a basis for detailed design. Reduced CO2 emission is an additional, and to carry out this separation with a minimum cost and energy consumption. Distillation is the most widely

  12. Hydrocracking process with integrated distillate product hydrogenation reactor

    SciTech Connect (OSTI)

    Hoehn, R.K.; Reno, M.E.

    1991-06-25

    This patent describes a hydrocracking process. It comprises passing a feed stream which comprises an admixture of hydrocarbons boiling above 240 degrees Centigrade and hydrogen through a hydrocracking reaction zone maintained at hydrocracking conditions and producing a mixed-phase hydrocracking reaction zone effluent stream; separating the mixed-phase hydrocracking reaction zone effluent stream into a first vapor stream, which comprises hydrogen, light hydrocarbons and distillate hydrocarbons, and a first liquid stream, which comprises distillate hydrocarbons; forming a second vapor stream and a second liquid, stream by partially condensing the first vapor stream, with the second liquid stream comprising distillate hydrocarbons and having a lower average boiling point than the first liquid stream; passing the second liquid stream and added hydrogen through a hydrogenation reaction zone maintained at hydrogenation conditions and producing a hydrogenation zone effluent stream; and, passing distillate hydrocarbons present in the hydrogenation zone effluent stream and the first liquid stream into a fractionation zone, and recovering a hydrocracking zone product stream.

  13. ORIGINAL PAPER Twin-Screw Extrusion Processing of Distillers Dried

    E-Print Network [OSTI]

    ORIGINAL PAPER Twin-Screw Extrusion Processing of Distillers Dried Grains with Solubles (DDGS. Twin- screw extrusion studies were performed to investigate the production of nutritionally balanced amounts of fish meal, fish oil, whole wheat flour, corn gluten meal, and vitamin and mineral premixes

  14. Solar thermal powered desalination: membrane versus distillation technologies

    E-Print Network [OSTI]

    . The daily desalinated water output per square metre of solar collector area is estimated for a number suited to integration with concentrating solar thermal concentrating collectors on a medium to largeSolar thermal powered desalination: membrane versus distillation technologies G. Burgess and K

  15. Improved Analysis and Understanding of the Petlyuk Distillation Column

    E-Print Network [OSTI]

    Skogestad, Sigurd

    of the energy consumption. When the column is oper­ ated optimally, the infinite staged Petlyuk column always Extended Abstract The Petlyuk (Petlyuk 1965) arrangement for separation of a ternary mixture into three pure product streams has the potential of 20­50% energy savings compared to conventional distillation

  16. Improved Analysis and Understanding of the Petlyuk Distillation Column

    E-Print Network [OSTI]

    Skogestad, Sigurd

    of the energy consumption. When the column is oper- ated optimally, the infinite staged Petlyuk column always Extended Abstract The Petlyuk (Petlyuk 1965) arrangement for separation of a ternary mixture into three pure product streams has the potential of 20-50% energy savings compared to conventional distillation

  17. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation 

    E-Print Network [OSTI]

    Jaiswal, Namit

    2007-09-17

    the synthetic sample and experimental study previously carried out. (e) To correlate steam-propane distillation yields for some crude oils and synthetic hydrocarbons to generate steam-propane distillation data that could be used to develop the input data... there is need to develop a model to predict distillate yield under any set of conditions for any heavy oil, requiring only the simulated distillation (SIMDIS) trace (i.e. percent off vs. normal boiling temperature) of the oil. The expected deliverables from...

  18. Control of a Industrial Heat Integrated Distillation Column T. Larsson and S. Skogestad

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Control of a Industrial Heat Integrated Distillation Column T. Larsson and S. Skogestad Department. It is well known which variables to control in normal distillation columns. But for heat integrated for heat integrated distillation columns. We will use the concept of self­optimizing control (Skogestad et

  19. Control of a Industrial Heat Integrated Distillation Column T. Larsson and S. Skogestad

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Control of a Industrial Heat Integrated Distillation Column T. Larsson and S. Skogestad Department. It is well known which variables to control in normal distillation columns. But for heat integrated for heat integrated distillation columns. We will use the concept of self-optimizing control (Skogestad et

  20. Duality, Residues, Fundamental class

    E-Print Network [OSTI]

    2011-05-22

    May 22, 2011 ... Duality, Residues, Fundamental class. Joseph Lipman. Purdue University. Department of Mathematics lipman@math.purdue.edu. May 22 ...

  1. Integrated process of distillation with side reactors for synthesis of organic acid esters

    DOE Patents [OSTI]

    Panchal, Chandrakant B; Prindle, John C; Kolah, Aspri; Miller, Dennis J; Lira, Carl T

    2015-11-04

    An integrated process and system for synthesis of organic-acid esters is provided. The method of synthesizing combines reaction and distillation where an organic acid and alcohol composition are passed through a distillation chamber having a plurality of zones. Side reactors are used for drawing off portions of the composition and then recycling them to the distillation column for further purification. Water is removed from a pre-reactor prior to insertion into the distillation column. An integrated heat integration system is contained within the distillation column for further purification and optimizing efficiency in the obtaining of the final product.

  2. New developments in deep hydroconversion of heavy residues with dispersed catalysts

    SciTech Connect (OSTI)

    Del Bianco, A.; Zangirolami, A.; Di Carlo, S. [Enricerche and EURON, Donato (Italy)

    1993-12-31

    Hydrocracking processes utilizing finely dispersed hydrogenation catalysts are particularly suited to upgrade heavy oils and petroleum residues which generally contain high concentrations of heteroatoms, metals and asphaltenes. With this study, the authors observed the effect of the reaction conditions on products yield and quality for hydrocracking experiments performed on a vacuum residue (VR) of Belaym crude (Egypt) in the presence of Mo-naphtenate and within a wide range of severities (410-470{degrees}C, 15-240 minutes). The experimental results demonstrate that the catalyst provides hydrogen in an active form for stabilization of the free radicals produced by thermal cracking so that distillate yields greater than 80% can be obtained with minimum coke production. The data describing the influence of the reaction condition on distillate and gas composition as well as asphaltene conversion are discussed and a preliminary kinetic analysis of the VR conversion reaction is presented.

  3. Biomass from Logging Residue and Mill Residue

    E-Print Network [OSTI]

    as a renewable energy resource or for chemical extraction. This report represents the most current data harvesting or are cut off the central stem of the tree due to a merchantability standard. Limbs refer for energy production or chemical extraction. Table 1 shows the logging residue available in East Texas

  4. Enhanced Separation Efficiency in Olefin/Paraffin Distillation

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose main objective is to develop technologies to enhance separation efficiencies by replacing the conventional packing materials with hollow fiber membranes, which have a high specific area and separated channels for both liquid and vapor phases. The use of hollow fibers in distillation columns can help refineries decrease operating costs, reduce greenhouse gas emissions through reduced heating costs, and help expand U.S. refining capacity through improvements to existing sites, without large scale capital investment.

  5. Entanglement cost and distillable entanglement of symmetric states

    E-Print Network [OSTI]

    Keiji Matsumoto

    2007-08-23

    We compute entanglement cost and distillable entanglement of states supported on symmetric subspace. Not only giving general formula, we apply them to the output states of optimal cloning machines. Surprisingly, under some settings, the optimal n to m clone and true m copies are the same in entanglement measures. However, they differ in the error exponent of entanglement dilution. We also presented a general theory of entanglement dilution which is applicable to any non-i.i.d sequence of states.

  6. Reactive Distillation for Esterification of Bio-based Organic Acids

    SciTech Connect (OSTI)

    Fields, Nathan; Miller, Dennis J.; Asthana, Navinchandra S.; Kolah, Aspi K.; Vu, Dung; Lira, Carl T.

    2008-09-23

    The following is the final report of the three year research program to convert organic acids to their ethyl esters using reactive distillation. This report details the complete technical activities of research completed at Michigan State University for the period of October 1, 2003 to September 30, 2006, covering both reactive distillation research and development and the underlying thermodynamic and kinetic data required for successful and rigorous design of reactive distillation esterification processes. Specifically, this project has led to the development of economical, technically viable processes for ethyl lactate, triethyl citrate and diethyl succinate production, and on a larger scale has added to the overall body of knowledge on applying fermentation based organic acids as platform chemicals in the emerging biorefinery. Organic acid esters constitute an attractive class of biorenewable chemicals that are made from corn or other renewable biomass carbohydrate feedstocks and replace analogous petroleum-based compounds, thus lessening U.S. dependence on foreign petroleum and enhancing overall biorefinery viability through production of value-added chemicals in parallel with biofuels production. Further, many of these ester products are candidates for fuel (particularly biodiesel) components, and thus will serve dual roles as both industrial chemicals and fuel enhancers in the emerging bioeconomy. The technical report from MSU is organized around the ethyl esters of four important biorenewables-based acids: lactic acid, citric acid, succinic acid, and propionic acid. Literature background on esterification and reactive distillation has been provided in Section One. Work on lactic acid is covered in Sections Two through Five, citric acid esterification in Sections Six and Seven, succinic acid in Section Eight, and propionic acid in Section Nine. Section Ten covers modeling of ester and organic acid vapor pressure properties using the SPEAD (Step Potential Equilibrium and Dynamics) method.

  7. Hanford Tank Waste Residuals

    Office of Environmental Management (EM)

    Hanford Tank Waste Residuals DOE HLW Corporate Board November 6, 2008 Chris Kemp, DOE ORP Bill Hewitt, YAHSGS LLC Hanford Tanks & Tank Waste * Single-Shell Tanks (SSTs) - 27...

  8. PEMEX selects the H-Oil{reg_sign} process for their hydrodesulfurization residue complex at the Miguel Hidalgo Refinery

    SciTech Connect (OSTI)

    Wisdom, L.I.; Colyar, J.J. [Hydrocarbon Research, Inc., Princeton, NJ (United States)

    1995-12-31

    Petroleos Mexicanos (PEMEX) has selected the H-Oil Process for the conversion and upgrading of a blend of Maya and Isthmus vacuum residua at the Miguel Hidalgo Refinery. The 8,450 metric ton/day (50,000 bpsd) H-Oil Plant will produce a low sulfur (0.8 wt%) fuel oil, diesel, naphtha, and LPG. The H-Oil Plant will be a key component of the Hydrodesulfurization Residue (HDR) Complex which will be located at the Miguel Hidalgo Refinery in Tula, State of Hidalgo, Mexico. The project is part of PEMEX`s Ecology Projects currently underway in Mexico. This paper describes the HDR Complex and the design basis of the H-Oil Plant and provides the current status of this project.

  9. An approach for solvent selection in extractive distillation systems including safety considerations

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    of bioethanol, for which solvents that offer the best cost-safety compromise are identified. Keywords. Extractive distillation; Multiobjective optimization; Process safety; Solvents; Bioethanol 1. Introduction

  10. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    Petroleum Marketing Annual 1998 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  11. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    U.S. Energy Information Administration (EIA) Indexed Site

    Petroleum Marketing Annual 1999 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  12. GDP Formulation of a segmented CDU Swing Cut Model for Refinery Planning

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    REFINERY FUEL RG LPG LN HN KN GO1 GO2 VGO VR1 VR2 C1 LPG LIGHT NAPHTHA PMS 98 MOGAS 95 JET FUEL AGO HGO HFO RG LPG R95 R100 RG LPG CN CGO RG Refinery Operation and Management - J.P. Favennec Crude Distillation

  13. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01

    dislocation-of crude oil and products could jeopardize theoil, residual fuel oil and petroleum products and resultantof users of such oil or product." 34 The EPCA also provided

  14. A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis

    E-Print Network [OSTI]

    Farrell, Alexander E.; Sperling, Dan

    2007-01-01

    and diesel fuel, but not LPG, jet fuel, residual oil, orbaseline year, 2004 Fuel LPG Motor gasoline Jet fuel Dieseland diesel fuel, but not LPG, A Low Carbon Fuel Standard For

  15. A Low-Carbon Fuel Standard for California Part 1: Technical Analysis

    E-Print Network [OSTI]

    2007-01-01

    and diesel fuel, but not LPG, jet fuel, residual oil, orbaseline year, 2004 Fuel LPG Motor gasoline Jet fuel Dieseland diesel fuel, but not LPG, A Low Carbon Fuel Standard For

  16. COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM

    E-Print Network [OSTI]

    Gandhi, Shamim Ahmed

    2013-01-01

    Additional products line gas, LPG, F, phenolsv and ammonia.Purified gas coal 4'JI,. LPG L_J" _ _, Sulfm Fractionatorcooled and separated into LPG and pipeline gas. The residue

  17. Endorsements and rebuttals in blog distillation q Giacomo Berardi, Andrea Esuli, Fabrizio Sebastiani

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Endorsements and rebuttals in blog distillation q Giacomo Berardi, Andrea Esuli, Fabrizio in revised form 10 May 2013 Accepted 30 May 2013 Available online 14 June 2013 Keywords: Blog distillation Blog search Link analysis Sentiment analysis a b s t r a c t In this paper we test a new approach

  18. Scaling control during membrane distillation of coal seam gas reverse osmosis brine

    E-Print Network [OSTI]

    Scaling control during membrane distillation of coal seam gas reverse osmosis brine Hung C. Duong during membrane distillation (MD) of brine from reverse osmosis (RO) treatment of coal seam gas (CSG. During CSG production, both gas and water are extracted to the surface. Gas is commonly separated from

  19. T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial

    E-Print Network [OSTI]

    Skogestad, Sigurd

    T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control. Larsson, S. Skogestad Control of a industrial heat integrated distillation column The process Q H columnPROMS. AIChE 1999 Annual meeting / 11.03.99 2 NTNU #12; T. Larsson, S. Skogestad Control of a industrial heat

  20. T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial

    E-Print Network [OSTI]

    Skogestad, Sigurd

    T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control. Larsson, S. Skogestad Control of a industrial heat integrated distillation column The process QH columnE 1999 Annual meeting / 11.03.99 2 NTNU #12;T. Larsson, S. Skogestad Control of a industrial heat

  1. Integrated Column Designs for Minimum Energy and Entropy Requirements in Multicomponent Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Distillation Ivar J. Halvorsen1 and Sigurd Skogestad Norwegian University of Science and Technology, Department Also at SINTEF Electronics and Cybernetics, 7465 Trondheim, Norway Prepared for presentation at the Topical conference on Separations Technology, Session 23 - Distillation Modeling and Processes II. 2001

  2. Optimization of Distillation Processes. Jos A. Caballero* and Ignacio E. Grossmann**

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    that handle more than 90% of separations and purifications. The capital investment for these distillation.87 million TJ) per year, or to a power consumption of 91 GW, or 54 million tons of crude oil. Distillation conditions to minimize the total investment and operating cost. Continuous decisions are related

  3. Low capital implementation of distributed distillation in ethylene recovery

    DOE Patents [OSTI]

    Reyneke, Rian; Foral, Michael J.; Lee, Guang-Chung

    2006-10-31

    An apparatus for recovering ethylene from a hydrocarbon feed stream, where the apparatus is a single distillation column pressure shell encasing an upper region and a lower region. The upper region houses an ethylene distributor rectifying section and the lower region houses a C2 distributor section and an ethylene distributor stripping section. Vapor passes from the lower region into the upper region, and liquid passes from the upper region to the lower region. The process for recovering the ethylene is also disclosed. The hydrocarbon feed stream is introduced into the C2 distributor section, and after a series of stripping and refluxing steps, distinct hydrocarbon products are recovered from the C2 distributor section, the ethylene distributor stripping section, and the ethylene distributor rectifying section, respectively.

  4. Effects of system densities on distillation column performance

    SciTech Connect (OSTI)

    Fasesan, S.O.; Sanni, S.A.; Taiwo, E.A. [Obafemi Awolowo Univ., Ile-Ife (Nigeria). Dept. of Chemical Engineering

    1998-06-01

    Distillation experiments were carried out on three binary systems (ethanol-butanol, ethanol-propan-2-ol, and propan-2-ol-butanol) in a 0.1-m internal diameter glass column packed with 8 mm diameter Raschig rings. The experiments were performed under total reflux conditions and at atmospheric pressure. The data collected on column performance showed that performance declined with increasing average bulk liquid density. The results also lend credence to earlier reports on the behavior of column performance with respect to component concentration in the feed mixtures. The system densities of the three binary systems were measured at four different temperatures, 30, 40, 50, and 60 C. The data were compared with the predicted data of Yen-Woods and Multifluid models. The accuracy of the predictions of the Yen-Woods model was rather poor while that of the Multifluid model was very encouraging.

  5. An experimental and mathematical investigation of hydrocarbon steam distillation 

    E-Print Network [OSTI]

    Langhoff, John Allan

    1984-01-01

    I LIJ D D CO D CIC D P1a L), OOLQLI [ [ LQS LQ WP8Q$ ?7) I/I I?I hl m ~ III O I?I I/I O & P) ?I- 0 O nj (Z) 4J Q O E III ID Cl ?I ?I Q ?/ ??: PJ Cl C C I?l ICl E ?J ??I I III 0 az I? I W K Q3 Ctl IQ C) PV... decreases near the end of the run. Th1s occurs when the volume of hydrocarbon 1n the 11quid phase of the distillation cell becomes small and cannot support 1ts vapor pressure. 07 C5 0 III QI 5- I/I QI 5- 0- 5- 0 CL IQ ) 0 CQ Ol O 0 4J Itl...

  6. Refiner/marketer targets production of transportation fuels and distillates

    SciTech Connect (OSTI)

    Thompson, J.E.

    1997-01-01

    Citgo Petroleum Corp., the wholly owned subsidiary of Petroleos de Venezuela, S.A. (PDVSA), the Venezuelan national oil company, owns two gasoline producing refineries, a 305,000-b/d system in Lake Charles, La., and a 130,000-b/d facility in Corpus Christi, Texas. Each is considered a deep conversion facility capable of converting heavy, sour crudes into a high percentage of transportation fuels and distillates. Two smaller refineries, one in Paulsboro, N.J., and one in Savannah, GA., have the capacity to process 40,000 b/d and 28,000 b/d of crude, respectively, for asphalt products. In the past two years, Citgo`s light oils refineries operated safely and reliably with a minimum of unscheduled shutdowns. An ongoing emphasis to increase reliability has resulted in extended run lengths at the refineries. Citgo has invested $314 million at its facilities in 1995, much of this toward environmental and regulatory projects, such as the new waste water treatment unit at the Lake Charles refinery. Over the next few years, Citgo expects to complete $1.5 billion in capital spending for major processing units such as a 60,000-b/d FCC feed hydrotreater unit at the Lake Charles refinery and crude expansion at the Corpus Christi refinery. Product exchanges and expanded transport agreements are allowing Citgo to extend its marketing reach.

  7. Simple rules help select best hydrocarbon distillation scheme

    SciTech Connect (OSTI)

    Sanchezllanes, M.T.; Perez, A.L.; Martinez, M.P.; Aguilar-Rodriguez, E.; Rosal, R. del )

    1993-12-06

    Separation economics depend mainly on investment for major equipment and energy consumption. This relationship, together with the fact that, in most cases, many alternative schemes will be proposed, make it essential to find an optimum scheme that minimizes overall costs. Practical solutions are found by applying heuristics -- exploratory problem-solving techniques that eliminate alternatives without applying rigorous mathematical procedures. These techniques have been applied to a case study. In the case study, a hydrocarbon mixture will be transported through a pipeline to a fractionation plant, where it will be separated into commercial products for distribution. The fractionation will consist of a simple train of distillation columns, the sequence of which will be defined by applying heuristic rules and determining the required thermal duties for each column. The facility must separate ethane, propane and mixed butanes, natural gasoline (light straight-run, or LSR, gasoline), and condensate (heavy naphtha). The ethane will be delivered to an ethylene plant as a gaseous stream, the propane and butanes will be stored in cryogenic tanks, and the gasoline and heavy naphtha also will be stored.

  8. Use of extractive distillation to produce concentrated nitric acid

    SciTech Connect (OSTI)

    Campbell, P.C.; Griffin, T.P.; Irwin, C.F.

    1981-04-01

    Concentrated nitric acid (> 95 wt %) is needed for the treatment of off-gases from a fuels-reprocessing plant. The production of concentrated nitric acid by means of extractive distillation in the two-pot apparatus was studied to determine the steady-state behavior of the system. Four parameters, EDP volume (V/sub EDP/) and temperature (T/sub EDP/), acid feed rate, and solvent recycle, were independently varied. The major response factors were percent recovery (CPRR) and product purity (CCP). Stage efficiencies also provided information about the system response. Correlations developed for the response parameters are: CPRR = 0.02(V/sub EDP/ - 800 cc) + 53.5; CCP = -0.87 (T/sub EDP/ - 140/sup 0/C) + 81; eta/sub V,EDP/ = 9.1(F/sub feed/ - 11.5 cc/min) - 0.047(V/sub EDP/ - 800 cc) - 2.8(F/sub Mg(NO/sub 3/)/sub 2// - 50 cc/min) + 390; and eta/sub L,EDP/ = 1.9(T/sub EDP/ - 140/sup 0/C) + 79. A computer simulation of the process capable of predicting steady-state conditions was developed, but it requires further work.

  9. Distillation sequence for the purification and recovery of hydrocarbons

    DOE Patents [OSTI]

    Reyneke, Rian (Katy, TX); Foral, Michael (Aurora, IL); Papadopoulos, Christos G. (Naperville, IL); Logsdon, Jeffrey S. (Naperville, IL); Eng, Wayne W. Y. (League City, TX); Lee, Guang-Chung (Houston, TX); Sinclair, Ian (Warrington, GB)

    2007-12-25

    This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

  10. A heat & mass integration approach to reduce capital and operating costs of a distillation configuration

    SciTech Connect (OSTI)

    Madenoor Ramapriya, Gautham; Jiang, Zheyu; Tawarmalani, Mohit; Agrawal, Rakesh

    2015-11-11

    We propose a general method to consolidate distillation columns of a distillation configuration using heat and mass integration. The proposed method encompasses all heat and mass integrations known till date, and includes many more. Each heat and mass integration eliminates a distillation column, a condenser, a reboiler and the heat duty associated with a reboiler. Thus, heat and mass integration can potentially offer significant capital and operating cost benefits. In this talk, we will study the various possible heat and mass integrations in detail, and demonstrate their benefits using case studies. This work will lay out a framework to synthesize an entire new class of useful configurations based on heat and mass integration of distillation columns.

  11. DYNAMIC MODELING AND CONTROL OF REACTIVE DISTILLATION FOR HYDROGENATION OF BENZENE 

    E-Print Network [OSTI]

    Aluko, Obanifemi

    2010-01-16

    This work presents a modeling and control study of a reactive distillation column used for hydrogenation of benzene. A steady state and a dynamic model have been developed to investigate control structures for the column. ...

  12. Water distillation using waste engine heat from an internal combustion engine

    E-Print Network [OSTI]

    Mears, Kevin S

    2006-01-01

    To meet the needs of forward deployed soldiers and disaster relief personnel, a mobile water distillation system was designed and tested. This system uses waste engine heat from the exhaust flow of an internal combustion ...

  13. High Performance Trays and Heat Exchangers in Heat Pumped Distillation Columns 

    E-Print Network [OSTI]

    Wisz, M. W.; Antonelli, R.; Ragi, E. G.

    1981-01-01

    exchangers and distillation trays permits additional energy savings by lower reboiler temperature differences, and reduced reflux requirements for a fixed column height, due to closer tray spacings. This paper surveys the heat pump systems currently...

  14. ,"U.S. Distillate Fuel Oil and Kerosene Sales by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    Distillate Fuel Oil and Kerosene Sales by End Use" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

  15. Characteristics of various methods for solving steady state and unsteady state distillation problems 

    E-Print Network [OSTI]

    Coco, Vincent Joseph

    1965-01-01

    CHARACTERISTICS OF VARIOUS METHODS FOR SOLVING STEADY STATE AND UNSTEADY STATE DISTILLATION PROBLEMS A Thesis By VINCENT JOSEPH COCO Submitted to the Graduate College of the Texas ASM University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1965 Major Subject: Chemical Engineering CHARACTERISTICS OF VARIOUS METHODS FOR SOLVING STEADY STATE AND UNSTEADY STATE DISTILLATION PROBLEMS A Thesis By VINCENT JOSEPH COCO Approved as to style and content by...

  16. PILOT-SCALE REMOVAL OF FLUORIDE FROM LEGACY PLUTONIUM MATERIALS USING VACUUM SALT DISTILLATION

    SciTech Connect (OSTI)

    Pierce, R. A.; Pak, D. J.

    2012-09-11

    Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. In 2011, SRNL adapted the technology for the removal of fluoride from fluoride-bearing salts. The method involved an in situ reaction between potassium hydroxide (KOH) and the fluoride salt to yield potassium fluoride (KF) and the corresponding oxide. The KF and excess KOH can be distilled below 1000{deg}C using vacuum salt distillation (VSD). The apparatus for vacuum distillation contains a zone heated by a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attaned, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile material in the feed boat. Studies discussed in this report were performed involving the use of non-radioactive simulants in small-scale and pilot-scale systems as well as radioactive testing of a small-scale system with plutonium-bearing materials. Aspects of interest include removable liner design considerations, boat materials, in-line moisture absorption, and salt deposition.

  17. Materials recovery from shredder residues

    SciTech Connect (OSTI)

    Daniels, E. J.; Jody, B. J.; Pomykala, J., Jr.

    2000-07-24

    Each year, about five (5) million ton of shredder residues are landfilled in the US. Similar quantities are landfilled in Europe and the Pacific Rim. Landfilling of these residues results in a cost to the existing recycling industry and also represents a loss of material resources that are otherwise recyclable. In this paper, the authors outline the resources recoverable from typical shredder residues and describe technology that they have developed to recover these resources.

  18. Residuals, Sludge, and Composting (Maine)

    Broader source: Energy.gov [DOE]

    The Maine Department of Environmental Protection's Residuals, Sludge, and Composting program regulates the land application and post-processing of organic wastes, including sewage sludge, septage,...

  19. New coal-derived catalyst for transfer hydrocracking of vacuum residue

    SciTech Connect (OSTI)

    Nakamura, Ikusei; Fujimoto, Kaoru [Univ. of Tokyo (Japan)

    1995-12-31

    Liquid phase hydrocracking of Arabian Heavy vacuum residue conducted in the presence of metal supported active carbon catalyst gave large amount of distillates (70%) with small hydrogen consumption. Especially the Yallourn coal derived active carbon catalyst showed high activity for the cracking of Arabian Heavy vacuum residue. The yield of asphaltene in the product oil was very low, whereas the coke yield was relatively high (about 4 wt%). In the metal-free active carbon system, the coke yield and the content of olefins, sulfur compounds, and asphaltene in the product oil were higher than those of the metal-supported active carbon system. These results suggest that asphaltene in feed oil was adsorbed on the metal supported active carbon catalyst and was decomposed or dehydrogenated on it to form coke and hydrogen atoms. The hydrogen atoms formed migrated on the carbon surface to reach the metal site and transferred to free radicals, olefins, or organo sulfur compounds.

  20. The cough response to ultrasonically nebulized distilled water in heart-lung transplantation patients

    SciTech Connect (OSTI)

    Higenbottam, T.; Jackson, M.; Woolman, P.; Lowry, R.; Wallwork, J.

    1989-07-01

    As a result of clinical heart-lung transplantation, the lungs are denervated below the level of the tracheal anastomosis. It has been questioned whether afferent vagal reinnervation occurs after surgery. Here we report the cough frequency, during inhalation of ultrasonically nebulized distilled water, of 15 heart-lung transplant patients studied 6 wk to 36 months after surgery. They were compared with 15 normal subjects of a similar age and sex. The distribution of the aerosol was studied in five normal subjects using /sup 99m/technetium diethylene triamine pentaacetate (/sup 99m/Tc-DTPA) in saline. In seven patients, the sensitivity of the laryngeal mucosa to instilled distilled water (0.2 ml) was tested at the time of fiberoptic bronchoscopy by recording the cough response. Ten percent of the aerosol was deposited onto the larynx and trachea, 56% on the central airways, and 34% in the periphery of the lung. The cough response to the aerosol was strikingly diminished in the patients compared with normal subjects (p less than 0.001), but all seven patients coughed when distilled water was instilled onto the larynx. As expected, the laryngeal mucosa of heart-lung transplant patients remains sensitive to distilled water. However, the diminished coughing when the distilled water is distributed by aerosol to the central airways supports the view that vagal afferent nerves do not reinnervate the lungs after heart-lung transplantation, up to 36 months after surgery.

  1. DEVELOPMENT AND DEPLOYMENT OF VACUUM SALT DISTILLATION AT THE SAVANNAH RIVER SITE

    SciTech Connect (OSTI)

    Pierce, R.; Pak, D.; Edwards, T.

    2010-10-28

    The Savannah River Site has a mission to dissolve fissile materials and disposition them. The primary fissile material is plutonium dioxide (PuO{sub 2}). To support dissolution of these materials, the Savannah River National Laboratory (SRNL) designed and demonstrated a vacuum salt distillation (VSD) apparatus using both representative radioactive samples and non-radioactive simulant materials. Vacuum salt distillation, through the removal of chloride salts, increases the quantity of materials suitable for processing in the site's HB-Line Facility. Small-scale non-radioactive experiments at 900-950 C show that >99.8 wt % of the initial charge of chloride salt distilled from the sample boat with recovery of >99.8 wt % of the ceric oxide (CeO{sub 2}) - the surrogate for PuO{sub 2} - as a non-chloride bearing 'product'. Small-scale radioactive testing in a glovebox demonstrated the removal of sodium chloride (NaCl) and potassium chloride (KCl) from 13 PuO{sub 2} samples. Chloride concentrations were distilled from a starting concentration of 1.8-10.8 wt % to a final concentration <500 mg/kg chloride. Initial testing of a non-radioactive, full-scale production prototype is complete. A designed experiment evaluated the impact of distillation temperature, time at temperature, vacuum, product depth, and presence of a boat cover. Significant effort has been devoted to mechanical considerations to facilitate simplified operation in a glovebox.

  2. Process for converting heavy oil deposited on coal to distillable oil in a low severity process

    DOE Patents [OSTI]

    Ignasiak, Teresa (417 Heffernan Drive, Edmonton, Alberta, CA); Strausz, Otto (13119 Grand View Drive, Edmonton, Alberta, CA); Ignasiak, Boleslaw (417 heffernan Drive, Edmonton, Alberta, CA); Janiak, Jerzy (17820 - 76 Ave., Edmonton, Alberta, CA); Pawlak, Wanda (3046 - 11465 - 41 Avenue, Edmonton, Alberta, CA); Szymocha, Kazimierz (3125 - 109 Street, Edmonton, Alberta, CA); Turak, Ali A. (Edmonton, CA)

    1994-01-01

    A process for removing oil from coal fines that have been agglomerated or blended with heavy oil comprises the steps of heating the coal fines to temperatures over 350.degree. C. up to 450.degree. C. in an inert atmosphere, such as steam or nitrogen, to convert some of the heavy oil to lighter, and distilling and collecting the lighter oils. The pressure at which the process is carried out can be from atmospheric to 100 atmospheres. A hydrogen donor can be added to the oil prior to deposition on the coal surface to increase the yield of distillable oil.

  3. Systems and methods for reactive distillation with recirculation of light components

    DOE Patents [OSTI]

    Stickney, Michael J. (Nassau Bay, TX); Jones, Jr., Edward M. (Friendswood, TX)

    2011-07-26

    Systems and methods for producing gas-to-liquids products using reactive distillation are provided. The method for producing gas-to-liquids products can include reacting a feedstock in a column having a distillation zone and a reaction zone to provide a bottoms stream and an overhead stream. A first portion of the overhead stream can be recycled to the column at the top of the reaction zone and second portion of the overhead stream can be recycled to the column at the bottom of the reaction zone.

  4. Identification of Genes Encoding Arabinosyltransferases (SCA) Mediating Developmental Modifications of Lipophosphoglycan

    E-Print Network [OSTI]

    Beverley, Stephen M.

    (LPG). Release is mediated by arabinosyl (Ara) capping of LPG sc Gal residues upon differentiation to the infective me- tacyclic stage. We used intraspecific polymorphisms of LPG structure to develop a genetic strategy leading to the identification of two genes (SCA1/2) mediating scAra capping. These LPG side chain

  5. Effect of Narrow Cut Oil Shale Distillates on HCCI Engine Performance

    SciTech Connect (OSTI)

    Eaton, Scott J; Bunting, Bruce G; Lewis Sr, Samuel Arthur; Fairbridge, Craig

    2009-01-01

    In this investigation, oil shale crude obtained from the Green River Formation in Colorado using Paraho Direct retorting was mildly hydrotreated and distilled to produce 7 narrow boiling point fuels of equal volumes. The resulting derived cetane numbers ranged between 38.3 and 43.9. Fuel chemistry and bulk properties strongly correlated with boiling point.

  6. Hybrid Separations/Distillation Technology. Research Opportunities for Energy and Emissions Reduction

    SciTech Connect (OSTI)

    Eldridge, R. Bruce; Seibert, A. Frank; Robinson, Sharon; Rogers, Jo

    2005-04-01

    This report focuses on improving the existing separations systems for the two largest energy-consuming sectors: the chemicals and petroleum refining industries. It identifies the technical challenges and research needs for improving the efficiency of distillation systems. Areas of growth are also highlighted.

  7. Hydrocracking process with improved distillate selectivity with high silica large pore zeolites

    SciTech Connect (OSTI)

    Partridge, R.D.; LaPierre, R.B.

    1989-04-11

    A process is described for increasing the selectivity of the production of higher boiling distillate range product in hydrocracking reactions which can produce gasoline boiling range product and higher boiling distillate range product, which process comprises: contacting a feedstock to be hydrocracked in a hydrocracking, in the presence of hydrogen and under hydrocracking conditions, with a catalyst comprising a hydrogenation component and a zeolite which has a porous lattice structure having pores with a dimension greater than 6 Angstroms and a hydrocarbon sorption capacity for hexane of at least 6 percent and has a framework silica:alumina ratio of at least about 50:1, whereby the selectivity of the process for production of the higher boiling distillate range product is preferentially increased, wherein the distillate selectivity is defined by reference to the amounts of the 165/sup 0/C-343/sup 0/C (330 F-650/sup 0/F) fraction and the total 343/sup 0/C-fraction in the hydrocracker effluent.

  8. Evaluation of Intake Limiting Agents in a Self-fed Dried Distillers' Supplement 

    E-Print Network [OSTI]

    Sugg, Joel D

    2013-08-14

    Response to range supplementation is in part driven by level of supplement consumed and amount of associated variation. In order to evaluate intake limiting agents in a self-fed dried distillers’ grain supplement (DDG), heifers (n=59) in Trial 1...

  9. Hybrid magic state distillation for universal fault-tolerant quantum computation

    E-Print Network [OSTI]

    Wenqiang Zheng; Yafei Yu; Jian Pan; Jingfu Zhang; Jun Li; Zhaokai Li; Dieter Suter; Xianyi Zhou; Xinhua Peng; Jiangfeng Du

    2014-12-11

    A set of stabilizer operations augmented by some special initial states known as 'magic states', gives the possibility of universal fault-tolerant quantum computation. However, magic state preparation inevitably involves nonideal operations that introduce noise. The most common method to eliminate the noise is magic state distillation (MSD) by stabilizer operations. Here we propose a hybrid MSD protocol by connecting a four-qubit H-type MSD with a five-qubit T-type MSD, in order to overcome some disadvantages of the previous MSD protocols. The hybrid MSD protocol further integrates distillable ranges of different existing MSD protocols and extends the T-type distillable range to the stabilizer octahedron edges. And it provides considerable improvement in qubit cost for almost all of the distillable range. Moreover, we experimentally demonstrate the four-qubit H-type MSD protocol using nuclear magnetic resonance technology, together with the previous five-qubit MSD experiment, to show the feasibility of the hybrid MSD protocol.

  10. HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT

    E-Print Network [OSTI]

    Titov, Anatoly

    321 HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT I.A. Alekseev, E hydrogen gas (so- called protium) must be used. It is necessary to avoid transfers of - to impurities imposes strict and critical requirements on the hydrogen gas system supporting the detector. Desirable

  11. Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process, Dhahran, 31261, Saudi Arabia Abstract This paper studies the synthesis and the design of methanol recovery that methanol could be recovered completely from the hydrocarbon when 5 equilibrium trays in the extraction

  12. Optimal Allocation of Heat Exchanger Inventory in a Serial Type Diabatic Distillation Column

    E-Print Network [OSTI]

    Salamon, Peter

    Optimal Allocation of Heat Exchanger Inventory in a Serial Type Diabatic Distillation Column Edward the column . We have previously shown (Jimenez et al. 2003) that optimaloperation of serial heat exchangers total heat exchanger area in different trays and calculate the optimal allocation of a given heat

  13. Black-Box Identification for PLC based MPC of a Binary Distillation Column

    E-Print Network [OSTI]

    Black-Box Identification for PLC based MPC of a Binary Distillation Column B. Huyck ,, F. Logist J is to upgrade the control system with a linear MPC running on a PLC. However, before a model based controller can be used on a PLC, an accurate (but simple) process model has to be constructed. Hence, the aim

  14. The examination of residual plots

    E-Print Network [OSTI]

    Tsai, Chih-Ling; Cai, Zongwu; Wu, Xizhi

    1998-01-01

    , then equations (14) and (18) indicate that the plot of eˆ(i) (or eˆi) versus yˆi might not reveal a nonlinear pattern even though the true mean function includes the nonlinear component, g(Z). Cook’s Example 7.1 (1994) illustrates this point. In practice...), Examples 7.1 and 7.2) has shown that this type of plot may provide misleading information when fitted values are used, we therefore suggest using the linear residual plot (residuals versus explanatory variables case) for the detection of nonlinearity...

  15. Future perspectives of using hollow fibers as structured packings in light hydrocarbon distillation

    SciTech Connect (OSTI)

    Yang, Dali; Orler, Bruce; Tornga, Stephanie; Welch, Cindy

    2011-01-26

    Olefin and paraffin are the largest chemical commodities. Furthermore, they are major building blocks for the petrochemical industry. Each year, petroleum refining, consumes 4,500 TBtu/yr in separation energy, making it one of the most energy-intensive industries in the United States). Just considering liquefied petroleum gas (ethane/propane/butane) and olefins (ethylene and propylene) alone, the distillation energy consumption is about 400 TBtu/yr in the US. Since petroleum distillation is a mature technology, incremental improvements in column/tray design will only provide a few percent improvements in the performance. However, each percent saving in net energy use amounts to savings of 10 TBtu/yr and reduces CO{sub 2} emissions by 0.2 MTon/yr. In practice, distillation columns require 100 to 200 trays to achieve the desired separation. The height of a transfer unit (HTU) of conventional packings is typical in the range of 36-60 inch. Since 2006, we had explored using several non-selective membranes as the structured packings to replace the conventional packing materials used in propane and propylene distillation. We obtained the lowest HTU of < 8 inch for the hollow fiber column, which was >5 times shorter than that of the conventional packing materials. In 2008, we also investigated this type of packing materials in iso-/n-butane distillation. Because of a slightly larger relative volatility of iso-/n-butane than that of propane/propylene, a wider and a more stable operational range was obtained for the iso-/n-butane pair. However, all of the experiments were conducted on a small scale with flowrate of < 25 gram/min. Recently, we demonstrated this technology on a larger scale (<250 gram/min). Within the loading range of F-factor < 2.2 Pa{sup 0.5}, a pressure drop on the vapor side is below 50 mbar/m, which suggests that the pressure drop of hollow fibers packings is not an engineering barrier for the applications in distillations. The thermal stability study suggests that polypropylene hollow fibers are stable after a long time exposure to C{sub 2} - C{sub 4} mixtures. The effects of packing density on the separation efficiency will be discussed.

  16. APPLICATION OF VACUUM SALT DISTILLATION TECHNOLOGY FOR THE REMOVAL OF FLUORIDE

    SciTech Connect (OSTI)

    Pierce, R.; Pak, D.

    2011-08-10

    Vacuum distillation of chloride salts from plutonium oxide (PuO{sub 2}) and simulant PuO{sub 2} has been previously demonstrated at Department of Energy (DOE) sites using kilogram quantities of chloride salt. The apparatus for vacuum distillation contains a zone heated using a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attained, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile materials in the feed boat. The application of vacuum salt distillation (VSD) is of interest to the HB-Line Facility and the MOX Fuel Fabrication Facility (MFFF) at the Savannah River Site (SRS). Both facilities are involved in efforts to disposition excess fissile materials. Many of these materials contain chloride and fluoride salt concentrations which make them unsuitable for dissolution without prior removal of the chloride and fluoride salts. Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. Subsequent efforts are attempting to adapt the technology for the removal of fluoride. Fluoride salts of interest are less-volatile than the corresponding chloride salts. Consequently, an alternate approach is required for the removal of fluoride without significantly increasing the operating temperature. HB-Line Engineering requested SRNL to evaluate and demonstrate the feasibility of an alternate approach using both non-radioactive simulants and plutonium-bearing materials. Whereas the earlier developments targeted the removal of sodium chloride (NaCl) and potassium chloride (KCl), the current activities are concerned with the removal of the halide ions associated with plutonium trifluoride (PuF{sub 3}), plutonium tetrafluoride (PuF{sub 4}), calcium fluoride (CaF{sub 2}), and calcium chloride (CaCl{sub 2}). This report discusses non-radioactive testing of small-scale and pilot-scale systems and radioactive testing of a small-scale system. Experiments focused on demonstrating the chemistry for halide removal and addressing the primary engineering questions associated with a change in the process chemistry.

  17. Evaluation of residue drum storage safety risks

    SciTech Connect (OSTI)

    Conner, W.V.

    1994-06-17

    A study was conducted to determine if any potential safety problems exist in the residue drum backlog at the Rocky Flats Plant. Plutonium residues stored in 55-gallon drums were packaged for short-term storage until the residues could be processed for plutonium recovery. These residues have now been determined by the Department of Energy to be waste materials, and the residues will remain in storage until plans for disposal of the material can be developed. The packaging configurations which were safe for short-term storage may not be safe for long-term storage. Interviews with Rocky Flats personnel involved with packaging the residues reveal that more than one packaging configuration was used for some of the residues. A tabulation of packaging configurations was developed based on the information obtained from the interviews. A number of potential safety problems were identified during this study, including hydrogen generation from some residues and residue packaging materials, contamination containment loss, metal residue packaging container corrosion, and pyrophoric plutonium compound formation. Risk factors were developed for evaluating the risk potential of the various residue categories, and the residues in storage at Rocky Flats were ranked by risk potential. Preliminary drum head space gas sampling studies have demonstrated the potential for formation of flammable hydrogen-oxygen mixtures in some residue drums.

  18. Energy Savings Accomplished by Replacing Steam Ejectors with Electric Driven Vacuum Pumps in Crude Distillation Vacuum Towers 

    E-Print Network [OSTI]

    Nelson, R. E.

    1982-01-01

    The low cost of steam combined with the maintenance free operation of steam ejectors has assured their unquestioned use in providing the necessary vacuum for crude distillation vacuum towers. However, the cost of steam production has risen...

  19. Transforms for prediction residuals in video coding

    E-Print Network [OSTI]

    Kam??l?, Fatih

    2010-01-01

    Typically the same transform, the 2-D Discrete Cosine Transform (DCT), is used to compress both image intensities in image coding and prediction residuals in video coding. Major prediction residuals include the motion ...

  20. Residue management at Rocky Flats

    SciTech Connect (OSTI)

    Olencz, J.

    1995-12-31

    Past plutonium production and manufacturing operations conducted at the Rocky Flats Environmental Technology Site (RFETS) produced a variety of plutonium-contaminated by-product materials. Residues are a category of these materials and were categorized as {open_quotes}materials in-process{close_quotes} to be recovered due to their inherent plutonium concentrations. In 1989 all RFETS plutonium production and manufacturing operations were curtailed. This report describes the management of plutonium bearing liquid and solid wastes.

  1. Vitrification of NAC process residue

    SciTech Connect (OSTI)

    Merrill, R.A.; Whittington, K.F.; Peters, R.D. [Pacific Northwest Lab., Richland, WA (United States)

    1995-12-31

    Vitrification tests have been performed with simulated waste compositions formulated to represent the residue which would be obtained from the treatment of low-level, nitrate wastes from Hanford and Oak Ridge by the nitrate to ammonia and ceramic (NAC) process. The tests were designed to demonstrate the feasibility of vitrifying NAC residue and to quantify the impact of the NAC process on the volume of vitrified waste. The residue from NAC treatment of low-level nitrate wastes consists primarily of oxides of aluminum and sodium. High alumina glasses were formulated to maximize the waste loading of the NAC product. Transparent glasses with up to 35 wt% alumina, and even higher contents in opaque glasses, were obtained at melting temperatures of 1,200 C to 1,400 C. A modified TCLP leach test showed the high alumina glasses to have good chemical durability, leaching significantly less than either the ARM-1 or the DWPF-EA high-level waste reference glasses. A significant increase in the final waste volume would be a major result of the NAC process on LLW vitrification. For Hanford wastes, NAC-treatment of nitrate wastes followed by vitrification of the residue will increase the final volume of vitrified waste by 50% to 90%; for Melton Valley waste from Oak Ridge, the increase in final glass volume will be 260% to 280%. The increase in volume is relative to direct vitrification of the waste in a 20 wt% Na{sub 2}O glass formulation. The increase in waste volume directly affects not only disposal costs, but also operating and/or capital costs. Larger plant size, longer operating time, and additional energy and additive costs are direct results of increases in waste volume. Such increases may be balanced by beneficial impacts on the vitrification process; however, those effects are outside the scope of this report.

  2. Vitrification of NAC process residue

    SciTech Connect (OSTI)

    Merrill, R.A.; Whittington, K.F.; Peters, R.D.

    1995-09-01

    Vitrification tests have been performed with simulated waste compositions formulated to represent the residue which would be obtained from the treatment of low-level, nitrate wastes from Hanford and Oak Ridge by the nitrate to ammonia and ceramic (NAC) process. The tests were designed to demonstrate the feasibility of vitrifying NAC residue and to quantify the impact of the NAC process on the volume of vitrified waste. The residue from NAC treatment of low-level nitrate wastes consists primarily of oxides of aluminum and sodium. High alumina glasses were formulated to maximize the waste loading of the NAC product. Transparent glasses with up to 35 wt% alumina, and even higher contents in opaque glasses, were obtained at melting temperatures of 1200{degrees}C to 1400{degrees}C. A modified TCLP leach test showed the high alumina glasses to have good chemical durability, leaching significantly less than either the ARM-1 or the DWPF-EA high-level waste reference glasses. A significant increase in the final waste volume would be a major result of the NAC process on LLW vitrification. For Hanford wastes, NAC-treatment of nitrate wastes followed by vitrification of the residue will increase the final volume of vitrified waste by 50% to 90%; for Melton Valley waste from Oak Ridge, the increase in final glass volume will be 260% to 280%. The increase in volume is relative to direct vitrification of the waste in a 20 wt% Na{sub 2}O glass formulation. The increase in waste volume directly affects not only disposal costs, but also operating and/or capital costs. Larger plant size, longer operating time, and additional energy and additive costs are direct results of increases in waste volume. Such increases may be balanced by beneficial impacts on the vitrification process; however, those effects are outside the scope of this report.

  3. Composition-explicit distillation curves of aviation fuel JP-8 and a coal-based jet fuel

    SciTech Connect (OSTI)

    Beverly L. Smith; Thomas J. Bruno [National Institute of Standards and Technology, Boulder, CO (United States). Physical and Chemical Properties Division

    2007-09-15

    We have recently introduced several important improvements in the measurement of distillation curves for complex fluids. The modifications to the classical measurement provide for (1) a composition explicit data channel for each distillate fraction (for both qualitative and quantitative analysis); (2) temperature measurements that are true thermodynamic state points; (3) temperature, volume, and pressure measurements of low uncertainty suitable for an equation of state development; (4) consistency with a century of historical data; (5) an assessment of the energy content of each distillate fraction; (6) a trace chemical analysis of each distillate fraction; and (7) a corrosivity assessment of each distillate fraction. The most significant modification is achieved with a new sampling approach that allows precise qualitative as well as quantitative analyses of each fraction, on the fly. We have applied the new method to the measurement of rocket propellant, gasoline, and jet fuels. In this paper, we present the application of the technique to representative batches of the military aviation fuel JP-8, and also to a coal-derived fuel developed as a potential substitute. We present not only the distillation curves but also a chemical characterization of each fraction and discuss the contrasts between the two fluids. 26 refs., 5 figs., 6 tabs.

  4. Process to recycle shredder residue

    DOE Patents [OSTI]

    Jody, Bassam J. (Chicago, IL); Daniels, Edward J. (Oak Lawn, IL); Bonsignore, Patrick V. (Channahon, IL)

    2001-01-01

    A system and process for recycling shredder residue, in which separating any polyurethane foam materials are first separated. Then separate a fines fraction of less than about 1/4 inch leaving a plastics-rich fraction. Thereafter, the plastics rich fraction is sequentially contacted with a series of solvents beginning with one or more of hexane or an alcohol to remove automotive fluids; acetone to remove ABS; one or more of EDC, THF or a ketone having a boiling point of not greater than about 125.degree. C. to remove PVC; and one or more of xylene or toluene to remove polypropylene and polyethylene. The solvents are recovered and recycled.

  5. RESIDUAL STRESSES IN 3013 CONTAINERS

    SciTech Connect (OSTI)

    Mickalonis, J.; Dunn, K.

    2009-11-10

    The DOE Complex is packaging plutonium-bearing materials for storage and eventual disposition or disposal. The materials are handled according to the DOE-STD-3013 which outlines general requirements for stabilization, packaging and long-term storage. The storage vessels for the plutonium-bearing materials are termed 3013 containers. Stress corrosion cracking has been identified as a potential container degradation mode and this work determined that the residual stresses in the containers are sufficient to support such cracking. Sections of the 3013 outer, inner, and convenience containers, in both the as-fabricated condition and the closure welded condition, were evaluated per ASTM standard G-36. The standard requires exposure to a boiling magnesium chloride solution, which is an aggressive testing solution. Tests in a less aggressive 40% calcium chloride solution were also conducted. These tests were used to reveal the relative stress corrosion cracking susceptibility of the as fabricated 3013 containers. Significant cracking was observed in all containers in areas near welds and transitions in the container diameter. Stress corrosion cracks developed in both the lid and the body of gas tungsten arc welded and laser closure welded containers. The development of stress corrosion cracks in the as-fabricated and in the closure welded container samples demonstrates that the residual stresses in the 3013 containers are sufficient to support stress corrosion cracking if the environmental conditions inside the containers do not preclude the cracking process.

  6. Vacuum Distillation

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal,Demand Module of theCubicEstimation ResultsYear JanYearDay) Process: Vacuum

  7. Design, start up, and three years operating experience of an ammonia scrubbing, distillation, and destruction plant

    SciTech Connect (OSTI)

    Gambert, G.

    1996-12-31

    When the rebuilt Coke Plant started operations in November of 1992, it featured a completely new closed circuit secondary cooler, ammonia scrubbing, ammonia distillation, and ammonia destruction plants. This is the second plant of this type to be built in North America. To remove the ammonia from the gas, it is scrubbed with three liquids: Approximately 185 gallons/minute of cooled stripped liquor from the ammonia stills; Light oil plant condensate; and Optionally, excess flushing liquor. These scrubbers typically reduce ammonia content in the gas from 270 Grains/100 standard cubic feet to 0.2 Grains/100 standard cubic feet.

  8. ,"U.S. Adjusted Sales of Distillate Fuel Oil by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative FuelsMonthly","10/2015"Monthly","10/2015" ,"ReleaseMonthly","10/2015"Net Receipts byDistillate Fuel

  9. Synthesis of zeolite from Italian coal fly ash: Differences in crystallization temperature using seawater instead of distilled water

    SciTech Connect (OSTI)

    Belviso, Claudia; Cavalcante, Francesco; Fiore, Saverio

    2010-05-15

    In this study Italian coal fly ash was converted into several types of zeolite in laboratory experiments with temperatures of crystallization ranging from 35 up to 90 deg. C. Distilled and seawater were used during the hydrothermal synthesis process in separate experiments, after a pre-treatment fusion with NaOH. The results indicate that zeolites could be formed from different kind of Italian coal fly ash at low temperature of crystallization using both distilled and seawater. SEM data and the powder patterns of X-ray diffraction analysis show that faujasite, zeolite ZK-5 and sodalite were synthesized when using both distilled and seawater; zeolite A crystallized only using distilled water. In particular the experiments indicate that the synthesis of zeolite X and zeolite ZK-5 takes place at lower temperatures when using seawater (35 and 45 deg. C, respectively). The formation of sodalite is always competitive with zeolite X which shows a metastable behaviour at higher temperatures (70-90 deg. C). The chemical composition of the fly ash source could be responsible of the differences on the starting time of synthesized zeolite with distilled water, in any case our data show that the formation of specific zeolites takes place always at lower temperatures when using seawater.

  10. Particulate residue separators for harvesting devices

    DOE Patents [OSTI]

    Hoskinson, Reed L.; Kenney, Kevin L.; Wright, Christopher T.; Hess, John R.

    2010-06-29

    A particulate residue separator and a method for separating a particulate residue stream may include a plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams which are formed by the harvesting device and which travel, at least in part, along the plenum and in a direction of the second, exhaust end; and a baffle assembly which is located in partially occluding relation relative to the plenum, and which substantially separates the first and second particulate residue air streams.

  11. Methods of separating particulate residue streams

    DOE Patents [OSTI]

    Hoskinson, Reed L. (Rigby, ID); Kenney, Kevin L. (Idaho Falls, ID); Wright, Christopher T. (Idaho Falls, ID); Hess, J. Richard (Idaho Falls, ID)

    2011-04-05

    A particulate residue separator and a method for separating a particulate residue stream may include an air plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams that are formed by the harvesting device and that travel, at least in part, along the air plenum and in a direction of the second, exhaust end; and a baffle assembly that is located in partially occluding relation relative to the air plenum and that substantially separates the first and second particulate residue air streams.

  12. Advanced Multi-Effect Distillation System for Desalination Using Waste Heat fromGas Brayton Cycles

    SciTech Connect (OSTI)

    Haihua Zhao; Per F. Peterson

    2012-10-01

    Generation IV high temperature reactor systems use closed gas Brayton Cycles to realize high thermal efficiency in the range of 40% to 60%. The waste heat is removed through coolers by water at substantially greater average temperature than in conventional Rankine steam cycles. This paper introduces an innovative Advanced Multi-Effect Distillation (AMED) design that can enable the production of substantial quantities of low-cost desalinated water using waste heat from closed gas Brayton cycles. A reference AMED design configuration, optimization models, and simplified economics analysis are presented. By using an AMED distillation system the waste heat from closed gas Brayton cycles can be fully utilized to desalinate brackish water and seawater without affecting the cycle thermal efficiency. Analysis shows that cogeneration of electricity and desalinated water can increase net revenues for several Brayton cycles while generating large quantities of potable water. The AMED combining with closed gas Brayton cycles could significantly improve the sustainability and economics of Generation IV high temperature reactors.

  13. FCC Tail Gas olefins conversion to gasoline via catalytic distillation with aromatics

    SciTech Connect (OSTI)

    Partin, E.E. (Brown and Root U.S.A., Inc., Houston, TX (US))

    1988-01-01

    The goal of every refiner is to continually improve profitability by such means as increasing gasoline production, increasing gasoline octane pool and in cases where fuel balance becomes a problem, decreasing refinery fuel gas production. A new refinery process is currently being developed which accomplish these goals. Chemical Research and Licensing Company (CR and L) developed Catalytic Distillation technology in 1978 to produce MTBE. They have since used the Catalytic Distillation technique to produce cumene. CR and L has further developed this technology to convert olefin gases currently consumed as refinery fuel, to high octane gasoline components. The process, known as CATSTILL, alkylates olefin gases such as ethylene, propylene and butylene, present in FCC Tail Gas with light aromatics such as benzene, toluene and xylene, present in reformate, to produce additional quantities of high octane gasoline components. A portable CATSTILL demonstration plant has been constructed by Brown and Root U.S.A., under an agreement with CR and L, for placement in a refinery to further develop data necessary to design commercial plants. This paper presents current data relative to the CATSTILL development.

  14. Magic State Distillation and Gate Compilation in Quantum Algorithms for Quantum Chemistry

    E-Print Network [OSTI]

    Colin J. Trout; Kenneth R. Brown

    2015-01-29

    Quantum algorithms for quantum chemistry map the dynamics of electrons in a molecule to the dynamics of a coupled spin system. To reach chemical accuracy for interesting molecules, a large number of quantum gates must be applied which implies the need for quantum error correction and fault-tolerant quantum computation. Arbitrary fault-tolerant operations can be constructed from a small, universal set of fault-tolerant operations by gate compilation. Quantum chemistry algorithms are compiled by decomposing the dynamics of the coupled spin-system using a Trotter formula, synthesizing the decomposed dynamics using Clifford operations and single-qubit rotations, and finally approximating the single-qubit rotations by a sequence of fault-tolerant single-qubit gates. Certain fault-tolerant gates rely on the preparation of specific single-qubit states referred to as magic states. As a result, gate compilation and magic state distillation are critical for solving quantum chemistry problems on a quantum computer. We review recent progress that has improved the efficiency of gate compilation and magic state distillation by orders of magnitude.

  15. Suppression of sludge formation by two-stage hydrocracking of vacuum residue at high conversion

    SciTech Connect (OSTI)

    Mochida, I.; Zhao, X.; Sakanishi, K. (Inst. of Advanced Material Study, Kyushu Univ., Kasuga, Fukuoka 816 (JP))

    1990-12-01

    This paper reports on hydrocracked products from Arabian light vacuum residue at high conversion into distillate ({gt}50%) that were analyzed in order to reveal how sludge formation was suppressed in the two-stage reaction. Although the asphaltene in the starting residue was highly soluble in the starting maltene in spite of is largest molecular weight, single-stage hydrocracking at a higher temperature of 420{degrees}C increased the aromaticity of the asphaltene through extensive deaklylation and dehydrogenation, leading to sludge formation. In contrast, two-stage hydrocracking at 390{degrees}C--3 h/420{degrees}C--1/h accomplished effective depolymerization of the asphaltene, high conversion being achieved without sludge. The carbon aromaticity (f{sub a}) of the produced asphaltene was maintained rather low, although its amount in the product was much the same regardless of the reaction conditions. The heptane-soluble maltenes in the hydrocracked oils exhibited variable dissolving abilities against the asphaltene according to the content and aromaticity of its aromatic fraction, also influencing sludge formation. Hydrocracking produced paraffins through the hydrogenative deaklylation of long-chain alkylbenzenes, decreasing f{sub a} and the dissolving ability of the hydrocracked maltene.

  16. Characterization Report on Sand, Slag, and Crucible Residues and on Fluoride Residues

    SciTech Connect (OSTI)

    Murray, A.M.

    1999-02-10

    This paper reports on the chemical characterization of the sand, slag, and crucible (SS and C) residues and the fluoride residues that may be shipped from the Rocky Flats Environmental Technology Site (RFETS) to Savannah River Site (SRS).

  17. A Benchmark Study on Casting Residual Stress

    SciTech Connect (OSTI)

    Johnson, Eric M. [John Deere -- Moline Tech Center; Watkins, Thomas R [ORNL; Schmidlin, Joshua E [ORNL; Dutler, S. A. [MAGMA Foundry Technologies, Inc.

    2012-01-01

    Stringent regulatory requirements, such as Tier IV norms, have pushed the cast iron for automotive applications to its limit. The castings need to be designed with closer tolerances by incorporating hitherto unknowns, such as residual stresses arising due to thermal gradients, phase and microstructural changes during solidification phenomenon. Residual stresses were earlier neglected in the casting designs by incorporating large factors of safety. Experimental measurement of residual stress in a casting through neutron or X-ray diffraction, sectioning or hole drilling, magnetic, electric or photoelastic measurements is very difficult and time consuming exercise. A detailed multi-physics model, incorporating thermo-mechanical and phase transformation phenomenon, provides an attractive alternative to assess the residual stresses generated during casting. However, before relying on the simulation methodology, it is important to rigorously validate the prediction capability by comparing it to experimental measurements. In the present work, a benchmark study was undertaken for casting residual stress measurements through neutron diffraction, which was subsequently used to validate the accuracy of simulation prediction. The stress lattice specimen geometry was designed such that subsequent castings would generate adequate residual stresses during solidification and cooling, without any cracks. The residual stresses in the cast specimen were measured using neutron diffraction. Considering the difficulty in accessing the neutron diffraction facility, these measurements can be considered as benchmark for casting simulation validations. Simulations were performed using the identical specimen geometry and casting conditions for predictions of residual stresses. The simulation predictions were found to agree well with the experimentally measured residual stresses. The experimentally validated model can be subsequently used to predict residual stresses in different cast components. This enables incorporation of the residual stresses at the design phase along with external loads for accurate predictions of fatigue and fracture performance of the cast components.

  18. "Table A11. Total Primary Consumption of Combustible Energy for Nonfuel"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page|Monthly","10/2015","1/15/1981"0. Total Consumption of LPG, Distillate Fuel Oil, and Residual1.

  19. Residual Toxicities of Insecticides to Cotton Insects. 

    E-Print Network [OSTI]

    Hightower, B. G.; Gaines, J. C.

    1960-01-01

    -ITHION. The residual toxicity of para- rliioti to the tumid spider mite was not affected by ~i1nul;ttetl rain when the spray was applied at a dosage c.cluiv;~lcnt to 0.3 pound of toxicant per acre. Kill5 or the cotton aphid on spray residues of 1),11;1thion were...

  20. Tank 12H residuals sample analysis report

    SciTech Connect (OSTI)

    Oji, L. N.; Shine, E. P.; Diprete, D. P.; Coleman, C. J.; Hay, M. S.

    2015-06-11

    The Savannah River National Laboratory (SRNL) was requested by Savannah River Remediation (SRR) to provide sample preparation and analysis of the Tank 12H final characterization samples to determine the residual tank inventory prior to grouting. Eleven Tank 12H floor and mound residual material samples and three cooling coil scrape samples were collected and delivered to SRNL between May and August of 2014.

  1. Effects of Ruminally Degradable Nitrogen in Diets Containing Wet Distiller’s Grains with Solubles and Steam-flaked Corn on Feedlot Cattle Performance and Carcass Characteristics 

    E-Print Network [OSTI]

    Ponce, Christian

    2010-10-12

    process (67% of total ethanol production). The process involves five general steps: grinding, cooking, liquefaction, saccharification, and fermentation. Endproducts of this process include ethanol, carbon dioxide, residual grain particles, and yeast... to approximately 100?C to generate 4 4 4 4 soluble dextrins and destroy any preexisting microogranims. Liquefaction of this treated mash is accomplished by holding the temperature at 85?C and adding additional alpha- amylase for at least 30 minutes...

  2. Experimental study of oil yields and properties of light and medium Venezuelan crude oils under steam and steam-propane distillation 

    E-Print Network [OSTI]

    Plazas Garcia, Joyce Vivia

    2002-01-01

    Six experimental runs were carried out to study the yields for a light crude oil (34.2°API) and an intermediate crude oil (25.1°API) under steam distillation and steam-propane distillation. Yields, were measured at five temperatures, 110, 150, 200...

  3. Catalyst deactivation in residue hydrocracking

    SciTech Connect (OSTI)

    Oballa, M.C.; Wong, C.; Krzywicki, A. [Novacor Research and Technology Corp., Calgary, Alberta (Canada)

    1994-12-31

    The existence of a computer-controlled bench scale hydrocracking units at the authors site has made cheaper the non-stop running of experiments for long periods of time. It was, therefore possible to show, at minimal costs, when three hydrocracking catalysts in service reach their maximum lifetime. Different parameters which are helpful for catalyst life and activity predictions were calculated, e.g., relative catalyst age and the effectiveness factor. Experimental results compared well with model, giving them the minimum and maximum catalyst lifetime, as well as the deactivation profile with regard to sulfur and metals removal. Reaction rate constants for demetallization and desulfurization were also determined. Six commercial catalysts were evaluated at short term runs and the three most active were used for long term runs. Out of three catalysts tested for deactivation at long term runs, it was possible to choose one whose useful life was higher than the others. All runs were carried out in a Robinson-Mahoney continuous flow stirred tank reactor, using 50/50 volumetric mixture of Cold Lake/Lloydminster atmospheric residue and NiMo/Al{sub 2}O{sub 3} catalyst.

  4. Distillation efficiencies of an industrial-scale i-butane/n-butane fractionator

    SciTech Connect (OSTI)

    Klemola, K.T.; Ilme, J.K.

    1996-12-01

    Rarely published industrial-scale distillation efficiency data are presented. The Murphree tray efficiencies are determined from the i-butane/n-butane fractionator performance data. Point efficiencies, numbers of overall vapor phase transfer units, numbers of vapor and liquid phase transfer units, and liquid phase resistances of mass transfer are backcalculated from the Murphree tray efficiencies. Various efficiency prediction and scale-up methods have been tested against experimental results. A new model for the prediction of the numbers of vapor and liquid phase transfer units has been developed. The model can be applied to hydrocarbon systems at high pressure. The influence of the mass-transfer coefficients, the interfacial area, and the vapor and liquid residence times on mass transfer has been analyzed separately, and as a result the NTU correlations for vapor and liquid phases are obtained. The constants of the model can be obtained by fitting the model to experimental efficiency data from a similar system.

  5. Colorimetric Determination of Nitrite in Foods Principle: The sample is extracted with distilled water and the aqueous extract clarified

    E-Print Network [OSTI]

    Nazarenko, Alexander

    water and the aqueous extract clarified with zinc hydroxide. Sulfanilic acid is diazotisedColorimetric Determination of Nitrite in Foods Principle: The sample is extracted with distilled/50 mL. The absorbance range should extend from 0 to 0.6 approx. E. Extraction Procedure Weigh ca 100g

  6. APPLICATION OF VACUUM SALT DISTILLATION TECHNOLOGY FOR THE REMOVAL OF FLUORIDE AND CHLORIDE FROM LEGACY FISSILE MATERIALS

    SciTech Connect (OSTI)

    Pierce, R.; Peters, T.

    2011-11-01

    Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and the Savannah River Site (SRS) HB-Line Facility designed, developed, tested, and successfully deployed a production-scale system for the distillation of sodium chloride (NaCl) and potassium chloride (KCl) from plutonium oxide (PuO{sub 2}). Subsequent efforts adapted the vacuum salt distillation (VSD) technology for the removal of chloride and fluoride from less-volatile halide salts at the same process temperature and vacuum. Calcium chloride (CaCl{sub 2}), calcium fluoride (CaF{sub 2}), and plutonium fluoride (PuF{sub 3}) were of particular concern. To enable the use of the same operating conditions for the distillation process, SRNL employed in situ exchange reactions to convert the less-volatile halide salts to compounds that facilitated the distillation of halide without removal of plutonium. SRNL demonstrated the removal of halide from CaCl{sub 2}, CaF{sub 2} and PuF{sub 3} below 1000 C using VSD technology.

  7. Arabian crude-oil residues evaluated

    SciTech Connect (OSTI)

    Ali, M.F.; Bukhari, A.; Hasan, M.; Saleem, M.

    1985-08-12

    This article evaluates detailed physical and chemical characteristics for four important Saudi Arabian resids. Petroleum residues are composed of a mixture of large and complex hydrocarbon molecules along with one or more heteroatoms such as sulfur, oxygen, nitrogen, vanadium, and nickel. The amount of residue and its physical and chemical composition depend on the source of the crude oil and methods of processing. Residues from four Saudi Arabian crude oils produced by the Arabian American Oil Co. (Aramco) were evaluated. The crude oils are 38.5 degrees API Arabian Extra Light, 33.8 degrees API Arabian Light, 30.4 degrees Api Arabian Medium, and 28.03 degrees API Arabian Heavy. Results are presented and residue preparation, and physical and chemical characteristics are analyzed.

  8. Residual stress in nanocrystalline nickel tungsten electrodeposits

    E-Print Network [OSTI]

    Ziebell, Tiffany D. (Tiffany Dawn)

    2011-01-01

    Characterizing the residual stress of thick nanocrystalline electrodeposits poses several unique challenges due to their fine grain structure, thickness distribution, and matte surface. We employ a three-dimensional ...

  9. Harvesting Residuals-Economic Energy Link 

    E-Print Network [OSTI]

    Owens, E. T.; Curtis, D. B.

    1986-01-01

    A description of systems used in integrated harvesting of quality and unmerchantable trees is outlined for three areas in New Brunswick, Canada. The silvicultural benefits and the use of residues as an alternative to ...

  10. FINAL REPORT LGP Discrimination and Residual Risk Analysis on Standardized

    E-Print Network [OSTI]

    Fernandez, Thomas

    FINAL REPORT LGP Discrimination and Residual Risk Analysis on Standardized Test Sites ­ Camp Sibert............................................................................................................... 10 2.1.6 Residual Risk Analysis

  11. Investigation of the Potential for Biofuel Blends in Residual Oil-Fired Power Generation Units as an Emissions Reduction Strategy for New York State

    SciTech Connect (OSTI)

    Krishna, C.R.; McDonald, R.

    2009-05-01

    There is a significant amount of oil, about 12.6 million barrels per year, used for power generation in New York State. The majority of it is residual oil. The primary reason for using residual oil probably is economic, as these fuels are cheaper than distillates. However, the stack emissions from the use of such fuels, especially in densely populated urban areas, can be a cause for concern. The emissions of concern include sulfur and nitrogen oxides and particulates, particularly PM 2.5. Blending with distillate (ASTM No.2) fuels may not reduce some or all of these emissions. Hence, a case can be made for blending with biofuels, such as biodiesel, as they tend to have very little fuel bound sulfur and nitrogen and have been shown in prior work at Brookhaven National Laboratory (BNL) to reduce NOx emissions as well in small boilers. Some of the research carried out at CANMET in Canada has shown potential reductions in PM with blending of biodiesel in distillate oil. There is also the benefit obtaining from the renewable nature of biofuels in reducing the net carbon dioxide emitted thus contributing to the reduction of green house gases that would otherwise be emitted to the atmosphere. The present project was conceived to examine the potential for such benefits of blending biofuels with residual oil. A collaboration was developed with personnel at the New York City Poletti Power Plant of the New York Power Authority. Their interest arose from an 800 MW power plant that was using residual oil and which was mandated to be shut down in 2010 because of environmental concerns. A blend of 20% biodiesel in residual oil had also been tested for a short period of about two days in that boiler a couple of years back. In this project, emission measurements including particulate measurements of PM2.5 were made in the commercial boiler test facility at BNL described below. Baseline tests were done using biodiesel as the blending biofuel. Biodiesel is currently and probably in the foreseeable future more expensive than residual fuel. So, another task was to explore potential alternative biofuels that might confer emission benefits similar to those of biodiesel, while being potentially significantly cheaper. Of course, for power plant use, availability in the required quantities is also a significant criterion. A subsidiary study to determine the effect of the temperature of the filter used to collect and measure the PM 2.5 emissions was conducted. This was done for reasons of accuracy in a residential boiler using distillate fuel blends. The present report details the results obtained in these tests with the baseline ASTM No. 6 fuel and blends of biodiesel with it as well as the results of the filter temperature study. The search for the alternative 'cheaper' biofuel identified a potential candidate, but difficulties encountered with the equipment during the testing prevented testing of the alternative biofuel.

  12. Immobilization of Rocky Flats graphite fines residues

    SciTech Connect (OSTI)

    Rudisill, T.S.; Marra, J.C.; Peeler, D.K.

    1999-07-01

    The Savannah River Technology Center (SRTC) is developing an immobilization process for graphite fines residues generated during nuclear materials production activities at the Rocky Flats Environmental Technology Site (Rocky Flats). The continued storage of this material has been identified as an item of concern. The residue was generated during the cleaning of graphite casting molds and potentially contains reactive plutonium metal. The average residue composition is 73 wt% graphite, 15 wt% calcium fluoride (CaF{sub 2}), and 12 wt% plutonium oxide (PuO{sub 2}). Approximately 950 kg of this material are currently stored at Rocky Flats. The strategy of the immobilization process is to microencapsulate the residue by mixing with a sodium borosilicate (NBS) glass frit and heating at nominally 700 C. The resulting waste form would be sent to the Waste Isolation Pilot Plant (WIPP) for disposal. Since the PuO{sub 2} concentration in the residue averages 12 wt%, the immobilization process was required to meet the intent of safeguards termination criteria by limiting plutonium recoverability based on a test developed by Rocky Flats. The test required a plutonium recovery of less than 4 g/kg of waste form when a sample was leached using a nitric acid/CaF{sub 2} dissolution flowsheet. Immobilization experiments were performed using simulated graphite fines with cerium oxide (CeO{sub 2}) as a surrogate for PuO{sub 2} and with actual graphite fines residues. Small-scale surrogate experiments demonstrated that a 4:1 frit to residue ratio was adequate to prevent recovery of greater than 4 g/kg of cerium from simulated waste forms. Additional experiments investigated the impact of varying concentrations of CaF{sub 2} and the temperature/heating time cycle on the cerium recovery. Optimal processing conditions developed during these experiments were subsequently demonstrated at full-scale with surrogate materials and on a smaller scale using actual graphite fines.

  13. Entanglement distillation for continuous-variables under a thermal environment: Effectiveness of a non-Gaussian operation

    E-Print Network [OSTI]

    Jaehak Lee; Hyunchul Nha

    2013-03-31

    We study the task of distilling entanglement by a coherent superposition operation $t\\hat{a}+r\\hat{a}^\\dagger$ applied to a continuous-variable state under a thermal noise. In particular, we compare the performances of two different strategies, i.e., the non-Gaussian operation $t\\hat{a}+r\\hat{a}^\\dagger$ is applied before or after the noisy Gaussian channel. This is closely related to a fundamental problem of whether Gaussian or non-Gaussian entanglement can be more robust under a noisy channel and also provides a useful insight into the practical implementation of entanglement distribution for a long-distance quantum communication. We specifically look into two entanglement characteristics, the logarithmic negativity as a measure of entanglement and the teleportation fidelity as a usefulness of entanglement, for each distilled state. We find that the non-Gaussian operation after (before) the thermal noise becomes more effective in the low (high) temperature regime.

  14. Disposal of Rocky Flats residues as waste

    SciTech Connect (OSTI)

    Dustin, D.F.; Sendelweck, V.S. . Rocky Flats Plant); Rivera, M.A. )

    1993-01-01

    Work is underway at the Rocky Flats Plant to evaluate alternatives for the removal of a large inventory of plutonium-contaminated residues from the plant. One alternative under consideration is to package the residues as transuranic wastes for ultimate shipment to the Waste Isolation Pilot Plant. Current waste acceptance criteria and transportation regulations require that approximately 1000 cubic yards of residues be repackaged to produce over 20,000 cubic yards of WIPP certified waste. The major regulatory drivers leading to this increase in waste volume are the fissile gram equivalent, surface radiation dose rate, and thermal power limits. In the interest of waste minimization, analyses have been conducted to determine, for each residue type, the controlling criterion leading to the volume increase, the impact of relaxing that criterion on subsequent waste volume, and the means by which rules changes may be implemented. The results of this study have identified the most appropriate changes to be proposed in regulatory requirements in order to minimize the costs of disposing of Rocky Flats residues as transuranic wastes.

  15. Disposal of Rocky Flats residues as waste

    SciTech Connect (OSTI)

    Dustin, D.F.; Sendelweck, V.S.; Rivera, M.A.

    1993-03-01

    Work is underway at the Rocky Flats Plant to evaluate alternatives for the removal of a large inventory of plutonium-contaminated residues from the plant. One alternative under consideration is to package the residues as transuranic wastes for ultimate shipment to the Waste Isolation Pilot Plant. Current waste acceptance criteria and transportation regulations require that approximately 1000 cubic yards of residues be repackaged to produce over 20,000 cubic yards of WIPP certified waste. The major regulatory drivers leading to this increase in waste volume are the fissile gram equivalent, surface radiation dose rate, and thermal power limits. In the interest of waste minimization, analyses have been conducted to determine, for each residue type, the controlling criterion leading to the volume increase, the impact of relaxing that criterion on subsequent waste volume, and the means by which rules changes may be implemented. The results of this study have identified the most appropriate changes to be proposed in regulatory requirements in order to minimize the costs of disposing of Rocky Flats residues as transuranic wastes.

  16. Recovery of Navy distillate fuel from reclaimed product. Volume II. Literature review

    SciTech Connect (OSTI)

    Brinkman, D.W.; Whisman, M.L.

    1984-11-01

    In an effort to assist the Navy to better utilize its waste hydrocarbons, NIPER, with support from the US Department of Energy, is conducting research designed to ultimately develop a practical technique for converting Reclaimed Product (RP) into specification Naval Distillate Fuel (F-76). This first phase of the project was focused on reviewing the literature and available information from equipment manufacturers. The literature survey has been carefully culled for methodology applicable to the conversion of RP into diesel fuel suitable for Navy use. Based upon the results of this study, a second phase has been developed and outlined in which experiments will be performed to determine the most practical recycling technologies. It is realized that the final selection of one particular technology may be site-specific due to vast differences in RP volume and available facilities. A final phase, if funded, would involve full-scale testing of one of the recommended techniques at a refueling depot. The Phase I investigations are published in two volumes. Volume 1, Technical Discussion, includes the narrative and Appendices I and II. Appendix III, a detailed Literature Review, includes both a narrative portion and an annotated bibliography containing about 800 references and abstracts. This appendix, because of its volume, has been published separately as Volume 2.

  17. Assigning a Value to Dried Distillers' Grains as a Protein Supplement in Cattle Consuming Low-Quality Forage 

    E-Print Network [OSTI]

    Rambo, Zachary Joseph

    2011-08-08

    - product. Operations using dry grind attempt to maximize ethanol production per unit of energy. Basic steps in the dry grinding process include; grinding, cooking, liquefaction, simultaneous saccharification, fermentation, and distillation. 3... Grinding is accomplished through the use of hammermills or roller mills which reduce particle size and facilitate water penetration. Fines resulting from grinding are mixed with water to create a slurry which is cooked after liquefaction and the addition...

  18. System and method for measuring residual stress

    DOE Patents [OSTI]

    Prime, Michael B. (Los Alamos, NM)

    2002-01-01

    The present invention is a method and system for determining the residual stress within an elastic object. In the method, an elastic object is cut along a path having a known configuration. The cut creates a portion of the object having a new free surface. The free surface then deforms to a contour which is different from the path. Next, the contour is measured to determine how much deformation has occurred across the new free surface. Points defining the contour are collected in an empirical data set. The portion of the object is then modeled in a computer simulator. The points in the empirical data set are entered into the computer simulator. The computer simulator then calculates the residual stress along the path which caused the points within the object to move to the positions measured in the empirical data set. The calculated residual stress is then presented in a useful format to an analyst.

  19. Residual Stresses in Weldments by Neutron Diffraction

    E-Print Network [OSTI]

    Bandara, Arosha

    Residual Stresses in Weldments by Neutron Diffraction Shanmukha Rao M, Jon James, Shirley Northover :- The neutron diffraction is determined from Bragg's law. When neutron propagate through crystal sample, Coherent, Incoherent and Absorption Scattering phenomena take place Weld MaterialsPlate materials Stress

  20. The Significance of Disordered Residues in

    E-Print Network [OSTI]

    Poonen, Bjorn

    RFs are significant in causing drug resistance in bacteria. 2. Protein interactions with a. common b. MoRF c. NonThe Significance of Disordered Residues in: 1) Bacterial Drug Resistance and 2) SNP Interactions #12;Outline 1. Introduction 2. Bacteria Methods 3. Bacteria Results 4. Disease Association Methods 5

  1. Residual Energy Spectrum of Solar Wind Turbulence

    E-Print Network [OSTI]

    Chen, C H K; Salem, C S; Maruca, B A

    2013-01-01

    It has long been known that the energy in velocity and magnetic field fluctuations in the solar wind is not in equipartition. In this paper, we present an analysis of 5 years of Wind data at 1 AU to investigate the reason for this. The residual energy (difference between energy in velocity and magnetic field fluctuations) was calculated using both the standard magnetohydrodynamic (MHD) normalization for the magnetic field and a kinetic version, which includes temperature anisotropies and drifts between particle species. It was found that with the kinetic normalization, the fluctuations are closer to equipartition, with a mean normalized residual energy of sigma_r = -0.19 and mean Alfven ratio of r_A = 0.71. The spectrum of residual energy, in the kinetic normalization, was found to be steeper than both the velocity and magnetic field spectra, consistent with some recent MHD turbulence predictions and numerical simulations, having a spectral index close to -1.9. The local properties of residual energy and cros...

  2. Chemical Stabilization of Hanford Tank Residual Waste

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Um, Wooyong; Williams, Benjamin D.; Bowden, Mark E.; Gartman, Brandy N.; Lukens, Wayne W.; Buck, Edgar C.; Mausolf, Edward J.

    2014-03-01

    Three different chemical treatment methods were tested for their ability to stabilize residual waste from Hanford tank C-202 for reducing contaminant release (Tc, Cr, and U in particular). The three treatment methods tested were lime addition [Ca(OH)2], an in-situ Ceramicrete waste form based on chemically bonded phosphate ceramics, and a ferrous iron/goethite treatment. These approaches rely on formation of insoluble forms of the contaminants of concern (lime addition and ceramicrete) and chemical reduction followed by co-precipitation (ferrous iron/goethite incorporation treatment). The results have demonstrated that release of the three most significant mobile contaminants of concern from tank residual wastes can be dramatically reduced after treatment compared to contact with simulated grout porewater without treatment. For uranium, all three treatments methods reduced the leachable uranium concentrations by well over three orders of magnitude. In the case of uranium and technetium, released concentrations were well below their respective MCLs for the wastes tested. For tank C-202 residual waste, chromium release concentrations were above the MCL but were considerably reduced relative to untreated tank waste. This innovative approach has the potential to revolutionize Hanford’s tank retrieval process, by allowing larger volumes of residual waste to be left in tanks while providing an acceptably low level of risk with respect to contaminant release that is protective of the environment and human health. Such an approach could enable DOE to realize significant cost savings through streamlined retrieval and closure operations.

  3. Data Conversion in Residue Number System

    E-Print Network [OSTI]

    Zilic, Zeljko

    ;2 Abstract This thesis tackles the problem of data conversion in the Residue Number System (RNS). The RNS has the use of RNS at the applications. In this thesis, we aim at developing efficient schemes for the conversion from the conventional representation to the RNS representation and vice versa. The conventional

  4. Update of distillers grains displacement ratios for corn ethanol life-cycle analysis.

    SciTech Connect (OSTI)

    Arora, S.; Wu, M.; Wang, M.; Energy Systems

    2011-02-01

    Production of corn-based ethanol (either by wet milling or by dry milling) yields the following coproducts: distillers grains with solubles (DGS), corn gluten meal (CGM), corn gluten feed (CGF), and corn oil. Of these coproducts, all except corn oil can replace conventional animal feeds, such as corn, soybean meal, and urea. Displacement ratios of corn-ethanol coproducts including DGS, CGM, and CGF were last updated in 1998 at a workshop at Argonne National Laboratory on the basis of input from a group of experts on animal feeds, including Prof. Klopfenstein (University of Nebraska, Lincoln), Prof. Berger (University of Illinois, Urbana-Champaign), Mr. Madson (Rapheal Katzen International Associates, Inc.), and Prof. Trenkle (Iowa State University) (Wang 1999). Table 1 presents current dry milling coproduct displacement ratios being used in the GREET model. The current effort focuses on updating displacement ratios of dry milling corn-ethanol coproducts used in the animal feed industry. Because of the increased availability and use of these coproducts as animal feeds, more information is available on how these coproducts replace conventional animal feeds. To glean this information, it is also important to understand how industry selects feed. Because of the wide variety of available feeds, animal nutritionists use commercial software (such as Brill Formulation{trademark}) for feed formulation. The software recommends feed for the animal on the basis of the nutritional characteristics, availability, and price of various animal feeds, as well as on the nutritional requirements of the animal (Corn Refiners Association 2006). Therefore, feed formulation considers both the economic and the nutritional characteristics of feed products.

  5. Immobilization of Rocky Flats Graphite Fines Residues

    SciTech Connect (OSTI)

    Rudisill, T. S.

    1998-11-06

    The Savannah River Technology Center (SRTC) is developing an immobilization process for graphite fines residues generated during nuclear materials production activities at the Rocky Flats Environmental Technology Site (Rocky Flats). The continued storage of this material has been identified as an item of concern. The residue was generated during the cleaning of graphite casting molds and potentially contains reactive plutonium metal. The average residue composition is 73 wt percent graphite, 15 wt percent calcium fluoride (CaF2), and 12 wt percent plutonium oxide (PuO2). Approximately 950 kilograms of this material are currently stored at Rocky Flats. The strategy of the immobilization process is to microencapsulate the residue by mixing with a sodium borosilicate (NBS) glass frit and heating at nominally 700 degrees C. The resulting waste form would be sent to the Waste Isolation Pilot Plant (WIPP) for disposal. Since the PuO2 concentration in the residue averages 12 wt percent, the immobilization process was required to meet the intent of safeguards termination criteria by limiting plutonium recoverability based on a test developed by Rocky Flats. The test required a plutonium recovery of less than 4 g/kg of waste form when a sample was leached using a nitric acid/CaF2 dissolution flowsheet. Immobilization experiments were performed using simulated graphite fines with cerium oxide (CeO2) as a surrogate for PuO2 and with actual graphite fines residues. Small-scale surrogate experiments demonstrated that a 4:1 frit to residue ratio was adequate to prevent recovery of greater than 4 g/kg of cerium from simulated waste forms. Additional experiments investigated the impact of varying concentrations of CaF2 and the temperature/heating time cycle on the cerium recovery. Optimal processing conditions developed during these experiments were subsequently demonstrated at full-scale with surrogate materials and on a smaller scale using actual graphite fines.In general, the recovery of cerium from the full-scale waste forms was higher than for smaller scale experiments. The presence of CaF2 also caused a dramatic increase in cerium recovery not seen in the small-scale experiments. However, the results from experiments with actual graphite fines were encouraging. A 4:1 frit to residue ratio, a temperature of 700 degrees C, and a 2 hr heating time produced waste forms with plutonium recoveries of 4 plus/minus 1 g/kg. With an increase in the frit to residue ratio, waste forms fabricated at this scale should meet the Rocky Flats product specification. The scale-up of the waste form fabrication process to nominally 3 kg is expected to require a 5:1 to 6:1 frit to residue ratio and maintaining the waste form centerline temperature at 700 degrees C for 2 hr.

  6. Testing regression models with residuals as data by Xia Hua.

    E-Print Network [OSTI]

    Hua, Xia, Ph. D. Massachusetts Institute of Technology

    2010-01-01

    Abstract In polynomial regression ... . In this thesis, I developed a residual based test, the turning point test for residuals, which tests the hypothesis that the kth order polynomial regression holds with ... while the ...

  7. Computer aided analysis for residual stress measurement using ultrasonic techniques 

    E-Print Network [OSTI]

    Kypa, Jagan Mohan

    1999-01-01

    Critically refracted longitudinal (Lcr) waves have been investigated with a computerized data acquisition and analysis technique to evaluate residual stresses present in a residual stress reference standard. This measurement ...

  8. In-situ method for treating residual sodium

    DOE Patents [OSTI]

    Sherman, Steven R. (Idaho Falls, ID); Henslee, S. Paul (Idaho Falls, ID)

    2005-07-19

    A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

  9. FIXED PRICE RESIDUAL FUNDS POLICY Policy dated March 29, 1999

    E-Print Network [OSTI]

    Weston, Ken

    FIXED PRICE RESIDUAL FUNDS POLICY Policy dated March 29, 1999 After completion of all deliverables in this process. May 1, 1999 Amendment to Policy · The first $75,000 of the residual balance will be transferred

  10. 1-D Transforms for the Motion Compensation Residual

    E-Print Network [OSTI]

    Kamisli, Fatih

    Transforms used in image coding are also commonly used to compress prediction residuals in video coding. Prediction residuals have different spatial characteristics from images, and it is useful to develop transforms that ...

  11. In-Situ Method for Treating Residual Sodium

    DOE Patents [OSTI]

    Sherman, Steven R.; Henslee, S. Paul

    2005-07-19

    A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

  12. Analysis of Oxygenated Compounds in Hydrotreated Biomass Fast Pyrolysis Oil Distillate Fractions

    SciTech Connect (OSTI)

    Christensen, Earl D.; Chupka, Gina; Luecke, Jon; Smurthwaite, Tricia D.; Alleman, Teresa L.; Iisa, Kristiina; Franz, James A.; Elliott, Douglas C.; McCormick, Robert L.

    2011-10-06

    Three hydrotreated bio-oils with different oxygen contents (8.2, 4.9, and 0.4 w/w) were distilled to produce Light, Naphtha, Jet, Diesel, and Gasoil boiling range fractions that were characterized for oxygen containing species by a variety of analytical methods. The bio-oils were originally generated from lignocellulosic biomass in an entrained-flow fast pyrolysis reactor. Analyses included elemental composition, carbon type distribution by {sup 13}C NMR, acid number, GC-MS, volatile organic acids by LC, and carbonyl compounds by DNPH derivatization and LC. Acid number titrations employed an improved titrant-electrode combination with faster response that allowed detection of multiple endpoints in many samples and for acid values attributable to carboxylic acids and to phenols to be distinguished. Results of these analyses showed that the highest oxygen content bio-oil fractions contained oxygen as carboxylic acids, carbonyls, aryl ethers, phenols, and alcohols. Carboxylic acids and carbonyl compounds detected in this sample were concentrated in the Light, Naphtha, and Jet fractions (<260 C boiling point). Carboxylic acid content of all of the high oxygen content fractions was likely too high for these materials to be considered as fuel blendstocks although potential for blending with crude oil or refinery intermediate streams may exist for the Diesel and Gasoil fractions. The 4.9 % oxygen sample contained almost exclusively phenolic compounds found to be present throughout the boiling range of this sample, but imparting measurable acidity primarily in the Light, Naphtha and Jet fractions. Additional study is required to understand what levels of the weakly acidic phenols could be tolerated in a refinery feedstock. The Diesel and Gasoil fractions from this upgraded oil had low acidity but still contained 3 to 4 wt% oxygen present as phenols that could not be specifically identified. These materials appear to have excellent potential as refinery feedstocks and some potential for blending into finished fuels. Fractions from the lowest oxygen content oil exhibited some phenolic acidity, but generally contained very low levels of oxygen functional groups. These materials would likely be suitable as refinery feedstocks and potentially as fuel blend components. PIONA analysis of the Light and Naphtha fractions shows benzene content of 0.5 and 0.4 vol%, and predicted (RON + MON)/2 of 63 and 70, respectively.

  13. Thin layer chromatography residue applicator sampler

    DOE Patents [OSTI]

    Nunes, Peter J. (Danville, CA); Kelly, Fredrick R. (Modesto, CA); Haas, Jeffrey S. (San Ramon, CA); Andresen, Brian D. (Livermore, CA)

    2007-07-24

    A thin layer chromatograph residue applicator sampler. The residue applicator sampler provides for rapid analysis of samples containing high explosives, chemical warfare, and other analyses of interest under field conditions. This satisfied the need for a field-deployable, small, hand-held, all-in-one device for efficient sampling, sample dissolution, and sample application to an analytical technique. The residue applicator sampler includes a sampling sponge that is resistant to most chemicals and is fastened via a plastic handle in a hermetically sealed tube containing a known amount of solvent. Upon use, the wetted sponge is removed from the sealed tube and used as a swiping device across an environmental sample. The sponge is then replaced in the hermetically sealed tube where the sample remains contained and dissolved in the solvent. A small pipette tip is removably contained in the hermetically sealed tube. The sponge is removed and placed into the pipette tip where a squeezing-out of the dissolved sample from the sponge into the pipette tip results in a droplet captured in a vial for later instrumental analysis, or applied directly to a thin layer chromatography plate for immediate analysis.

  14. Principle of Least Squares Regression Equations Residuals Correlation and Regression

    E-Print Network [OSTI]

    Watkins, Joseph C.

    Principle of Least Squares Regression Equations Residuals Topic 3 Correlation and Regression Linear Regression I 1 / 15 #12;Principle of Least Squares Regression Equations Residuals Outline Principle of Least Squares Regression Equations Residuals 2 / 15 #12;Principle of Least Squares Regression Equations

  15. RESIDUAL STRESS EFFECTS IN FRACTURE OF COMPOSITES AND ADHESIVES

    E-Print Network [OSTI]

    Nairn, John A.

    RESIDUAL STRESS EFFECTS IN FRACTURE OF COMPOSITES AND ADHESIVES JOHN A. NAIRN ABSTRACT Because by including residual stresses in fracture mechanics models of failure. This chapter gives general results examples of including residual stresses in fracture mechanics interpretation of experimental results

  16. Evaluation of agricultural residues for paper manufacture

    SciTech Connect (OSTI)

    Alcaide, L.J.; Baldovin, F.L.; Herranz, J.L.F. (Univ. of Cordoba (Spain))

    1993-03-01

    Five agricultural residues-olive tree fellings, wheat straw, sunflower stalks, vine shoots, and cotton stalks-were evaluated for use as raw materials for paper manufacture. The untreated raw materials and their pulps were tested for hot-water solubles, 1%-NaOH solubles, alcohol-benzene extractables, ash, holocellulose, lignin, [alpha]-cellulose, and pentosans. Handsheets were tested for breaking length, stretch, burst index, and tear index. The results showed wheat straw to be the most promising material. Vine shoots showed the least promise.

  17. TEXAS LPG FUEL CELL DEVELOPMENT AND DEMONSTRATION PROJECT Full-Text - Submission contains both citation data and full-text of the journal article. Full-text can be either a pre-print or post-print, but not the copyrighted article.

    SciTech Connect (OSTI)

    SOUTHWEST RESEARCH LABORATORY SUBMITTED BY SUBCONTRACTOR, RAILROAD COMMISSION OF TEXAS

    2004-07-26

    The State Energy Conservation Office has executed its first Fuel Cell Project which was awarded under a Department of Energy competitive grant process. The Texas LPG Fuel Processor Development and Fuel Cell Demonstration Program is a broad-based public/private partnership led by the Texas State Energy Conservation Office (SECO). Partners include the Alternative Fuels Research and Education Division (AFRED) of the Railroad Commission of Texas; Plug Power, Inc., Latham, NY, UOP/HyRadix, Des Plaines, IL; Southwest Research Institute (SwRI), San Antonio, TX; the Texas Natural Resource Conservation Commission (TNRCC), and the Texas Department of Transportation (TxDOT). The team proposes to mount a development and demonstration program to field-test and evaluate markets for HyRadix?s LPG fuel processor system integrated into Plug Power?s residential-scale GenSys? 5C (5 kW) PEM fuel cell system in a variety of building types and conditions of service. The program?s primary goal is to develop, test, and install a prototype propane-fueled residential fuel cell power system supplied by Plug Power and HyRadix in Texas. The propane industry is currently funding development of an optimized propane fuel processor by project partner UOP/HyRadix through its national checkoff program, the Propane Education and Research Council (PERC). Following integration and independent verification of performance by Southwest Research Institute, Plug Power and HyRadix will produce a production-ready prototype unit for use in a field demonstration. The demonstration unit produced during this task will be delivered and installed at the Texas Department of Transportation?s TransGuide headquarters in San Antonio, Texas. Simultaneously, the team will undertake a market study aimed at identifying and quantifying early-entry customers, technical and regulatory requirements, and other challenges and opportunities that need to be addressed in planning commercialization of the units. For further information please contact Mary-Jo Rowan at mary-jo.rowan@cpa.state.tx.us

  18. Waste Heat Recovery and Recycling in Thermal Separation Processes: Distillation, Multi-Effect Evaporation (MEE) and Crystallization Processes

    SciTech Connect (OSTI)

    Emmanuel A. Dada; Chandrakant B. Panchal; Luke K. Achenie; Aaron Reichl; Chris C. Thomas

    2012-12-03

    Evaporation and crystallization are key thermal separation processes for concentrating and purifying inorganic and organic products with energy consumption over 1,000 trillion Btu/yr. This project focused on a challenging task of recovering low-temperature latent heat that can have a paradigm shift in the way thermal process units will be designed and operated to achieve high-energy efficiency and significantly reduce the carbon footprint as well as water footprint. Moreover, this project has evaluated the technical merits of waste-heat powered thermal heat pumps for recovery of latent heat from distillation, multi-effect evaporation (MEE), and crystallization processes and recycling into the process. The Project Team has estimated the potential energy, economics and environmental benefits with the focus on reduction in CO2 emissions that can be realized by 2020, assuming successful development and commercialization of the technology being developed. Specifically, with aggressive industry-wide applications of heat recovery and recycling with absorption heat pumps, energy savings of about 26.7 trillion Btu/yr have been estimated for distillation process. The direct environmental benefits of this project are the reduced emissions of combustible products. The estimated major reduction in environmental pollutants in the distillation processes is in CO2 emission equivalent to 3.5 billion lbs/year. Energy consumption associated with water supply and treatments can vary between 1,900 kWh and 23,700 kWh per million-gallon water depending on sources of natural waters [US DOE, 2006]. Successful implementation of this technology would significantly reduce the demand for cooling-tower waters, and thereby the use and discharge of water treatment chemicals. The Project Team has also identified and characterized working fluid pairs for the moderate-temperature heat pump. For an MEE process, the two promising fluids are LiNO3+KNO3+NANO3 (53:28:19 ) and LiNO3+KNO3+NANO2(53:35:12). And for an H2O2 distillation process, the two promising fluids are Trifluoroethanol (TFE) + Triethylene Glycol Dimethyl ether (DMETEG) and Ammonia+ Water. Thermo-physical properties calculated by Aspen+ are reasonably accurate. Documentation of the installation of pilot-plants or full commercial units were not found in the literature for validating thermo-physical properties in an operating unit. Therefore, it is essential to install a pilot-scale unit to verify thermo-physical properties of working fluid pairs and validate the overall efficiency of the thermal heat pump at temperatures typical of distillation processes. For an HO2 process, the ammonia-water heat pump system is more compact and preferable than the TFE-DMETEG heat pump. The ammonia-water heat pump is therefore recommended for the H2O2 process. Based on the complex nature of the heat recovery system, we anticipated that capital costs could make investments financially unattractive where steam costs are low, especially where co-generation is involved. We believe that the enhanced heat transfer equipment has the potential to significantly improve the performance of TEE crystallizers, independent of the absorption heat-pump recovery system. Where steam costs are high, more detailed design/cost engineering will be required to verify the economic viability of the technology. Due to the long payback period estimated for the TEE open system, further studies on the TEE system are not warranted unless there are significant future improvements to heat pump technology. For the H2O2 distillation cycle heat pump waste heat recovery system, there were no significant process constraints and the estimated 5 years payback period is encouraging. We therefore recommend further developments of application of the thermal heat pump in the H2O2 distillation process with the focus on the technical and economic viability of heat exchangers equipped with the state-of-the-art enhancements. This will require additional funding for a prototype unit to validate enhanced thermal performances of heat transfer equipment, evaluat

  19. Quantum Residual Correlation: Interpreting through State Merging

    E-Print Network [OSTI]

    Indranil Chakrabarty; Abhishek Deshpande; Sourav Chatterjee

    2015-03-03

    In this brief report we revisit the concept of "quantum dissension", which was introduced as a natural extension of quantum discord for three qubit system. Here we bring in new expression for quantum dissensions and more interestingly we name one such expression as \\textit{residual correlation}. The basic objective behind the introduction of such a quantity is to capture the extra amount of correlation generated by doing measurement in a correlated system from a situation where we do not bring in a correlated system in the measurement process. Apart from this we also present an operational interpretation of this correlation in context of state merging. Remarkably, we find that for three qubit system if one discards relevant prior information, the change in the cost of state merging ( merging the quantum information of two parties into one) is captured by the \\textit{residual correlation}. In addition to that we found that this quantity can be negative for mixed states. This indeed opens up a new dimension in the tripartite scenario where we can observe situations where there is a decrease in the cost of state merging on discarding relevant prior information. We claim that this result establishes a re conceptualization of information processing tasks in tripartite situations where we can use suitable measurement and states to bring down the cost of the protocol.

  20. Morphing of Geometric Composites via Residual Swelling

    E-Print Network [OSTI]

    Matteo Pezzulla; Steven A. Shillig; Paola Nardinocchi; Douglas P. Holmes

    2015-05-30

    Understanding and controlling the shape of thin, soft objects has been the focus of significant research efforts among physicists, biologists, and engineers in the last decade. These studies aim to utilize advanced materials in novel, adaptive ways such as fabricating smart actuators or mimicking living tissues. Here, we present the controlled growth--like morphing of 2D sheets into 3D shapes by preparing geometric composite structures that deform by residual swelling. The morphing of these geometric composites is dictated by both swelling and geometry, with diffusion controlling the swelling-induced actuation, and geometric confinement dictating the structure's deformed shape. Building on a simple mechanical analog, we present an analytical model that quantitatively describes how the Gaussian and mean curvatures of a thin disk are affected by the interplay among geometry, mechanics, and swelling. This model is in excellent agreement with our experiments and numerics. We show that the dynamics of residual swelling is dictated by a competition between two characteristic diffusive length scales governed by geometry. Our results provide the first 2D analog of Timoshenko's classical formula for the thermal bending of bimetallic beams - our generalization explains how the Gaussian curvature of a 2D geometric composite is affected by geometry and elasticity. The understanding conferred by these results suggests that the controlled shaping of geometric composites may provide a simple complement to traditional manufacturing techniques.

  1. A blending problem (Taha, Example 2.3-7, almost) An oil refinery has three stages of production: a distillation tower, which

    E-Print Network [OSTI]

    Galvin, David

    A blending problem (Taha, Example 2.3-7, almost) An oil refinery has three stages of production: a distillation tower, which takes in crude oil, up to a maximum of 650,000 barrels per day (bbl/day) and produces **" means "**% octane".) Once crude oil enters the system, it goes fully through the process. The refinery

  2. Dissolution and compaction of albite sand in distilled water and pH-buffered carboxylic acid solutions: experiments at 100 degrees and 160 degrees C 

    E-Print Network [OSTI]

    Carpenter, Thomas Doyle

    1995-01-01

    and compaction were monitored to quantify the effects of organic acids on time-dependent compaction rates of albite. The effects of stress and fluid chemistry on the dissolution kinetics were also examined. Compared to distilled water, Si-based dissolution rates...

  3. Bioassays of weathered residues of several organic phosphorus insecticides 

    E-Print Network [OSTI]

    Hightower, Billie Gene

    1959-01-01

    at high temperatures on the residual toxicities of Gut hi on, Sevin, and toxaphene to the boll weevil, Anthonomus grandis Boh........................ . . . . ........ 3^ 3? The effects of simulated wind on the residual toxicities of Guthion, dieldrin..., and toxaphene dusts to the boll weevil, Anthonomus grandis Boh. 36 The effects of high temperatures on the residual toxicities of methyl parathion, malathion, and toxaphene to the boll weevil, Anthonomus grandis Boh...................... 3$ 5. The effects...

  4. A Characterization and Evaluation of Coal Liquefaction Process Streams The Kinetics of Coal Liquefaction Distillation Resid Conversion

    SciTech Connect (OSTI)

    D.Campbell; D.G. Nichols; D.J. Pazuchanics; H.Huang; M.T.Klein; R.A. Winschel; S.D. Brandes; S.Wang; W.H. Calkins

    1998-06-04

    Under subcontract from CONSOL Inc. (DOE Contract N o. DE- AC22- 94PC93054), the University of Delaware studied the mechanism and kinetics of coal liquefaction resid conversion. Th e program at Delaware was conducted be tween August 15, 1994, and April 30, 1997. It consisted of two primary tasks. The first task was to develop an empirical test to measure the reactivit y toward hydrocracking of coal- derived distillation resids. The second task was to formulate a computer model to represent the structure of the resids and a kinetic and mechanistic model of resid reactivity based on the structural representations. An Introduction and Summary of th e project authored by CONSOL and a report of the program findings authored by the University of Delaware researchers are presented here. INTRODUCTION Resid hydrocracking is a key reaction of modern (i. e., distillate- producing) coal liquefactio n processes. Coals are readily converted to resid a nd lighter products in the liquefaction process. The resid is combined with fr esh coal in a ratio often greater than 1: 1, and some vacuum gas oil and is recycled to be further converted. Understanding the chemistry of resids and resi d reactivity is important to improve direct liquefaction process design and to achieve economi c objectives for direct coal liquefaction. Computational models that predict resid conversion from the chemical characteristics of the resids and reaction conditions would be a cost- efficient way to explore process variables. Implementation of such models could aid in the design an d operation of liquefaction facilities.

  5. Wet Gasification of Ethanol Residue: A Preliminary Assessment

    SciTech Connect (OSTI)

    Brown, Michael D.; Elliott, Douglas C.

    2008-09-22

    A preliminary technoeconomic assessment has been made of several options for the application of catalytic hydrothermal gasification (wet gasification) to ethanol processing residues.

  6. ABSTRACT: Bioenergy Harvesting Technologies to Supply Crop Residues...

    Energy Savers [EERE]

    objectives for the integration of advanced logistical systems and focused bioenergy harvesting technologies that supply crop residues and energy crops in a large bale format....

  7. Water dynamics clue to key residues in protein folding

    SciTech Connect (OSTI)

    Gao, Meng [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)] [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China); Zhu, Huaiqiu, E-mail: hqzhu@pku.edu.cn [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)] [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China); Yao, Xin-Qiu [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China) [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China); Department of Biophysics, Kyoto University, Sakyo Kyoto 606-8502 (Japan); She, Zhen-Su, E-mail: she@pku.edu.cn [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)] [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)

    2010-01-29

    A computational method independent of experimental protein structure information is proposed to recognize key residues in protein folding, from the study of hydration water dynamics. Based on all-atom molecular dynamics simulation, two key residues are recognized with distinct water dynamical behavior in a folding process of the Trp-cage protein. The identified key residues are shown to play an essential role in both 3D structure and hydrophobic-induced collapse. With observations on hydration water dynamics around key residues, a dynamical pathway of folding can be interpreted.

  8. Comparison of residual stresses in Inconel 718 simple parts made...

    Office of Scientific and Technical Information (OSTI)

    melting and direct laser metal sintering Residual stress profiles were mapped using neutron diffraction in two simple prism builds of Inconel 718: one fabricated with electron...

  9. Potential of biomass residue availability; The case of Thailand

    SciTech Connect (OSTI)

    Bhattacharya, S.C.; Shrestha, R.M.; Ngamkajornvivat, S. (Energy Technology Div., Asian Institute of Technology, Bangkok 10501 (TH))

    1989-01-01

    An acute shortage of fuel wood and charcoal prevails in many developing countries. A logical approach to the problem places emphasis on the development of alternative energy sources, including use of biomass residues. An assessment of the potential of biomass residues for energy and other uses calls for an estimation of their annual production. Also, because the residues are normally bulky they should be utilized near their place of origin whenever possible to avoid high transportation costs. Thus knowledge of the total national generation of residues per year does not provide enough information for planning residue utilization. This article illustrates a method of residue estimation that takes the case of Thailand as an example. It presents the annual generation of nine agricultural resides (paddy husk, paddy straw, bagasse, cotton stalk, corn cob, groundnut shell, cassava stalk and coconut husk and shell) and one forestry residue (sawdust) in different agroeconomic zones and regions of Thailand. The methodology used for the investigation of crop-to-residue ratios is outlined. The annual generation figures for the different residues along with observations about their traditional uses are presented.

  10. Residual orientation in micro-injection molded parts

    SciTech Connect (OSTI)

    Healy, John; Edward, Graham H.; Knott, Robert B. (Monash); (ANSTO)

    2008-06-30

    The residual orientation following micro-injection molding of small rectangular plates with linear polyethylene has been examined using small-angle neutron scattering, and small- and wide-angle X-ray scattering. The effect of changing the molding conditions has been examined, and the residual chain orientation has been compared to the residual orientation of the crystallites as a function of position in the sample. This study has found that, for micromoldings, the orientation of the crystallites decreases with increasing injection speed and increasing mold thickness. The combined data suggest that the majority of the orientation present comes from oriented crystal growth rather than residual chain orientation.

  11. Residual Stresses for Structural Analysis and Fatigue Life Prediction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Vehicle Components: Success stories from the High Temperature Materials Laboratory (HTML) User Program Residual Stresses for Structural Analysis and Fatigue Life Prediction in...

  12. Residual Stress Measurements in Side Bonded Resistance Welds

    SciTech Connect (OSTI)

    PAUL, KORINKO

    2005-04-18

    Resistance upset welding is used to attach small diameter machined tubes to small gas vessels. Recently there has been interest in determining the level of residual stresses caused by this attachment method and its influence on environmental interactions. A test program was initiated to determine the residual stresses present due to welding using the nominal weld parameters and varying the interference between the foot and the counter bore. In this paper, the residual stress measurement technique is described, the welding conditions are provided, and the residual stress due to welding at the nominal conditions are presented.

  13. Method For Characterizing Residual Stress In Metals

    DOE Patents [OSTI]

    Jacobson, Loren A. (Santa Fe, NM); Michel, David J. (Alexandria, VA); Wyatt, Jeffrey R. (Burke, VA)

    2002-12-03

    A method is provided for measuring the residual stress in metals. The method includes the steps of drilling one or more holes in a metal workpiece to a preselected depth and mounting one or more acoustic sensors on the metal workpiece and connecting the sensors to an electronic detecting and recording device. A liquid metal capable of penetrating into the metal workpiece placed at the bottom of the hole or holes. A recording is made over a period of time (typically within about two hours) of the magnitude and number of noise events which occur as the liquid metal penetrates into the metal workpiece. The magnitude and number of noise events are then correlated to the internal stress in the region of the workpiece at the bottom of the hole.

  14. Original article Residues in wax and honey after Apilife VAR®

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Residues in wax and honey after Apilife VAR® treatment Stefan Bogdanov Anton and foundation were exposed to the air during storage. © Inra/DIB/AGIB/Elsevier, Paris honey / wax / residue to accumulation of these substances in beeswax and less so in honey [1, 17]. The accumulation in wax depends

  15. Minimization of welding residual stress and distortion in large structures

    E-Print Network [OSTI]

    Michaleris, Panagiotis

    1 Minimization of welding residual stress and distortion in large structures P. Michaleris at Champaign Urbana, Urbana, IL Abstract Welding distortion in large structures is usually caused by buckling due to the residual stress. In cases where the design is fixed and minimum weld size requirements

  16. Thermoacoustic method for relaxation of residual stresses in welded joints

    SciTech Connect (OSTI)

    Koshovyi, V.V.; Pakhn`o, M.I.; Tsykhan, O.I.

    1995-01-01

    We propose a thermoacoustic method for the relaxation of residual stresses in welded joints, present a block diagram of a generator of local thermoacoustic pulses designed for implementation of this method, and describe our experiment aimed at relaxation of residual tensile stresses.

  17. Residual Energy-Aware Cooperative Transmission (REACT) in Wireless Networks

    E-Print Network [OSTI]

    Leung, Kin K.

    Residual Energy-Aware Cooperative Transmission (REACT) in Wireless Networks Erwu Liu, Qinqing Zhang in the network can cooper- ate their transmissions of information to gain energy savings in a distributed network the lifetime of the network and we call the selection method a residual energy-aware cooperative transmission

  18. Parallel FPGA Implementation of RSA with Residue Number Systems

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Multiplication based on Residue Num- ber Systems. Thanks to RNS, we develop a design able to perform an RSA propose a new DPA countermeasure in the framework of RNS. It is only (slightly) memory consuming (1]. That is the reason why Residue Number Systems (RNS for short) can be very useful. RNS have the main advantage of fast

  19. Modular Arithmetic Implementation with the Residue Number System (RNS)

    E-Print Network [OSTI]

    Sousa, Leonel

    Modular Arithmetic Implementation with the Residue Number System (RNS) Samuel Antão and Leonel are the addition/subtraction, multiplication and reduction as well as the conversion of Residue Number System (RNS discussed in the following. 1 RNS Forward/Reverse Conversions Forward conversion corresponds

  20. Parallel FPGA Implementation of RSA with Residue Number Systems

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Multiplication based on Residue Num­ ber Systems. Thanks to RNS, we develop a design able to perform an RSA propose a new DPA countermeasure in the framework of RNS. It is only (slightly) memory consuming (1]. That is the reason why Residue Number Systems (RNS for short) can be very useful. RNS have the main advantage of fast

  1. Identification of family-determining residues in PHD fingers

    E-Print Network [OSTI]

    Geman, Donald

    -evolution in their sequences. We measure the degree to which fixing the amino acid type at one position modifies the frequencies of amino acids at other positions. We then detect those position/amino acid combinations classify PHD fingers into different groups based on the analysis of residue­ residue co

  2. Conversion of direct process high-boiling residue to monosilanes

    DOE Patents [OSTI]

    Brinson, Jonathan Ashley (Vale of Glamorgan, GB); Crum, Bruce Robert (Madison, IN); Jarvis, Jr., Robert Frank (Midland, MI)

    2000-01-01

    A process for the production of monosilanes from the high-boiling residue resulting from the reaction of hydrogen chloride with silicon metalloid in a process typically referred to as the "direct process." The process comprises contacting a high-boiling residue resulting from the reaction of hydrogen chloride and silicon metalloid, with hydrogen gas in the presence of a catalytic amount of aluminum trichloride effective in promoting conversion of the high-boiling residue to monosilanes. The present process results in conversion of the high-boiling residue to monosilanes. At least a portion of the aluminum trichloride catalyst required for conduct of the process may be formed in situ during conduct of the direct process and isolation of the high-boiling residue.

  3. Post-Extraction Algal Residue as a Protein Source for Cattle Consuming Forage 

    E-Print Network [OSTI]

    Drewery, Merritt Leanne 1989-

    2012-11-13

    supplements (dried distillers’ grains, DDG; cottonseed meal, CSM) were offered to steers consuming Bermudagrass to evaluate palatability of PEAR. Supplement completion, time required for consumption, and amount of supplement consumed were recorded...

  4. Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

    2013-11-26

    The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what would be allowed for methanol synthesis alone. Aromatic-rich hydrocarbon liquid (C5+), containing a significant amount of methylated benzenes, was produced under these conditions. However, selectivity control to liquid hydrocarbons was difficult to achieve. Carbon dioxide and methane formation was problematic. Furthermore, saturation of the olefinic intermediates formed in the zeolite, and necessary for gasoline production, occurred over PdZnAl. Thus, yield to desirable hydrocarbon liquid product was limited. Evaluation of other oxygenate-producing catalysts could possibly lead to future advances. Potential exists with discovery of other types of catalysts that suppress carbon dioxide and light hydrocarbon formation. Comparative techno-economics for a single-step syngas-to-distillates process and a more conventional MTG-type process were investigated. Results suggest operating and capital cost savings could only modestly be achieved, given future improvements to catalyst performance. Sensitivity analysis indicated that increased single-pass yield to hydrocarbon liquid is a primary need for this process to achieve cost competiveness.

  5. A Residue Approach to the Finite Field Arithmetics 1/23 A Residue Approach to the Finite Field

    E-Print Network [OSTI]

    as integers. Residue Number System RNS base: a set of coprime numbers (m1, ..., mk ) RNS representation: (a1 of order (f (m)) then in RNS the complexities become (f (log m)). #12;A Residue Approach to the Finite ), we obtain a similar representation as RNS. Operations are made independently on each A(ei ) (like

  6. MINIMIZING WASTE AND COST IN DISPOSITION OF LEGACY RESIDUES

    SciTech Connect (OSTI)

    J. BALKEY; M. ROBINSON

    2001-05-01

    Research is being conducted at the Los Alamos National Laboratory (LANL) which is directed toward development of a quantitative basis for disposition of actinide-bearing process residues (both legacy residues and residues generated from ongoing programmatic operations). This research is focused in two directions: (1) identifying minimum negative consequence (waste, dose, cost) dispositions working within regulatory safeguards termination criteria, and (2) evaluating logistics/consequences of across-the-board residue discards such as authorized at Rocky Flats under a safeguards termination variance. The first approach emphasizes Laboratory commitments to environmental stewardship, worker safety, and fiscal responsibility. This approach has been described as the Plutonium Disposition Methodology (PDM) in deference to direction provided by DOE Albuquerque. The second approach is born of the need to expedite removal of residues from storage for programmatic and reasons and residue storage safety concerns. Any disposition path selected must preserve the legal distinction between residues as Special Nuclear Material (SNM) and discardable materials as waste in order to insure the continuing viability of Laboratory plutonium processing facilities for national security operations.

  7. An urban infill : a residual site in Boston

    E-Print Network [OSTI]

    Savvides, Andreas L. (Andreas Loucas)

    1996-01-01

    This thesis is concerned with the treatment of residual sites in the context of the urban environment and in particular with the wounds inflicted by the passage of the Massachusetts Turnpike through the city of Boston. The ...

  8. Residual zonal flows in tokamaks and stellarators at arbitrary wavelengths

    E-Print Network [OSTI]

    Monreal, P; Sánchez, E; Parra, F I; Bustos, A; Könies, A; Kleiber, R; Görler, T

    2015-01-01

    In the linear collisionless limit, a zonal potential perturbation in a toroidal plasma relaxes, in general, to a non-zero residual value. Expressions for the residual value in tokamak and stellarator geometries, and for arbitrary wavelengths, are derived. These expressions involve averages over the lowest order particle trajectories, that typically cannot be evaluated analytically. In this work, an efficient numerical method for the evaluation of such expressions is reported. It is shown that this method is faster than direct gyrokinetic simulations. Calculations of the residual value in stellarators are provided for much shorter wavelengths than previously available in the literature. Electrons must be treated kinetically in stellarators because, unlike in tokamaks, kinetic electrons modify the residual value even at long wavelengths. This effect, that had already been predicted theoretically, is confirmed by gyrokinetic simulations.

  9. Asphalt landscape after all : residual suburban surface as public infrastructure

    E-Print Network [OSTI]

    O'Connor, Joseph Michael, M. Arch. Massachusetts Institute of Technology

    2011-01-01

    The thesis proposes a hybridized commercial retail strip inserted into a residual suburban condition as a manner of investigating the latent potential of suburban logic, both its constituent elements and its formal rules ...

  10. RetroFILL : residual spaces as urban infill

    E-Print Network [OSTI]

    Kobel, Marika

    2010-01-01

    In any city there are small slivers and chunks of awkward spaces - in between buildings, occupying edge conditions, not large enough to warrant many forms of traditional use - which can be termed residual. These areas of ...

  11. Residual stress in electrodeposited nanocrystalline nickel-tungsten coatings

    E-Print Network [OSTI]

    Ziebell, Tiffany D.

    Characterizing the residual stress of thick nanocrystalline electrodeposits poses several unique challenges due to their fine grain structure, thickness distribution, and matte surface. We use a three-dimensional ...

  12. Modeling, Optimization and Economic Evaluation of Residual Biomass Gasification 

    E-Print Network [OSTI]

    Georgeson, Adam

    2012-02-14

    and product options are available for gasification along with combinations thereof. The objective of this work is to create a systematic method for optimizing the design of a residual biomass gasification unit. In detail, this work involves development...

  13. The determination of thru-thickness residual bending stresses 

    E-Print Network [OSTI]

    Rinehart, Adam James

    2000-01-01

    In order to understand the fatigue behavior of dents in pressurized pipelines it is necessary to understand the residual stresses that result from cyclic plastic bending. Three approaches are taken here in studying a beam cross section: a discrete...

  14. Residue disposal from waste-to-energy facilities

    SciTech Connect (OSTI)

    Walsh, P.; O'Leary, P.; Cross, F.

    1987-05-01

    When considering a waste-to-energy project, some local officials believe that waste-to-energy is a complete alternative to landfilling. While these projects can reduce waste volume substantially, the process will still produce residues that must be properly handled in order to protect the environment. All systems produce fly ash and bottom ash, and some systems also produce wastewater. This article discusses alternative methods for addressing these residue control problems.

  15. Method for residual stress relief and retained austenite destabilization

    DOE Patents [OSTI]

    Ludtka, Gerard M.

    2004-08-10

    A method using of a magnetic field to affect residual stress relief or phase transformations in a metallic material is disclosed. In a first aspect of the method, residual stress relief of a material is achieved at ambient temperatures by placing the material in a magnetic field. In a second aspect of the method, retained austenite stabilization is reversed in a ferrous alloy by applying a magnetic field to the alloy at ambient temperatures.

  16. An investigation of residual stress in welded joints 

    E-Print Network [OSTI]

    Moffat, William Hugh

    1951-01-01

    . flummery and Conclusions VII. '-. &uggested Procedure for I"uture Investigation 18 o i' VIII. ? . Ppendix IX. Bibliography LIST OP EIGURES Ro. Title Page 1. 'welded Plates snd Gptical Gage Used by Soulton and Martin ~ ~ 6 2. Dr. Rao~s Method... AN INVESTIGATION OF RESIDUAL STRESS IN WELDED JOINTS INTRODUCTION The object of the research reported in this paper was to investigate the magnitude of transverse and longi- tudial residual stress in a welded Joint. These are the stresses in a direction...

  17. Absorbing Aerosol Index (AAI) The residue method for the detection of aerosols

    E-Print Network [OSTI]

    Graaf, Martin de

    and calculation Main sensitivities of residue Problems with the residue Conclusions and outlook #12;#12;o = 380 scattering and absorption #12;#12;#12;Nadir View Solar zenith angle = 45o Residue = 3.5 Rayleigh atmosphere View Solar zenith angle = 45o Residue = -1.0 Rayleigh atmosphere, As = 0.16 Scattering aerosol layer

  18. Fault-Tolerant Linear Convolution Using Residue Number M.G.Parker,M.Benaissa

    E-Print Network [OSTI]

    Parker, Matthew Geoffrey

    This paper proposes a Fault-Tolerant Linear Convolution architecture using Residue Number Systems (RNS) and Polynomial Residue Number Systems (PRNS). The RNS and PRNS are both given error-detection capability Residue Number Systems (RNS) [4]. A RNS performs computation over a number of independent residue channels

  19. Measuring depth profiles of residual stress with Raman spectroscopy

    SciTech Connect (OSTI)

    Enloe, W.S.; Sparks, R.G.; Paesler, M.A.

    1988-12-01

    Knowledge of the variation of residual stress is a very important factor in understanding the properties of machined surfaces. The nature of the residual stress can determine a part`s susceptibility to wear deformation, and cracking. Raman spectroscopy is known to be a very useful technique for measuring residual stress in many materials. These measurements are routinely made with a lateral resolution of 1{mu}m and an accuracy of 0.1 kbar. The variation of stress with depth; however, has not received much attention in the past. A novel technique has been developed that allows quantitative measurement of the variation of the residual stress with depth with an accuracy of 10nm in the z direction. Qualitative techniques for determining whether the stress is varying with depth are presented. It is also demonstrated that when the stress is changing over the volume sampled, errors can be introduced if the variation of the stress with depth is ignored. Computer aided data analysis is used to determine the depth dependence of the residual stress.

  20. Characterization of Residual Medium Peptides from Yersinia pestis Cultures

    SciTech Connect (OSTI)

    Clowers, Brian H.; Wunschel, David S.; Kreuzer, Helen W.; Engelmann, Heather E.; Valentine, Nancy B.; Wahl, Karen L.

    2013-04-03

    Using a range of common microbial medium formulations (TSB, BHI, LB, and G-media), two attenuated strains of Y. pestis (KIM D27 (pgm-) and KIMD1 lcr-) were cultivated in triplicate. These cellular suspensions were used to develop a method of extracting residual medium peptides from the final microbial preparation to assess their relative abundance and identity. Across the conditions examined, which included additional cellular washing and different forms of microbial inactivation, residual medium peptides were detected. Despite the range of growth medium sources used and the associated manufacturing processes used in their production, a high degree of peptide similarity was observed for a given medium recipe. These results demonstrate that residual medium peptides are retained using traditional microbial cultivation techniques and may be used to inform forensic investigations with respect to production deduction.

  1. Residual strain mapping of Roman styli from Iulia Concordia, Italy

    SciTech Connect (OSTI)

    Salvemini, Filomena, E-mail: floriana.salvemini@fi.isc.cnr.it [Consiglio Nazionale delle Ricerche, Istituto dei Sistemi Complessi, Sesto Fiorentino, FI (Italy); Università degli Studi di Firenze, Dipartimento di Scienze della Terra (Italy); Grazzi, Francesco [Consiglio Nazionale delle Ricerche, Istituto dei Sistemi Complessi, Sesto Fiorentino, FI (Italy); Angelini, Ivana [Università degli Studi di Padova, Dipartimento di Geoscienze (Italy); Davydov, Vadim; Vontobel, Peter [Paul Scherrer Institut, SINQ Spallation Neutron Source, Villigen (Switzerland); Vigoni, Alberto [Dedalo s.n.c., Vicolo dei Conti 6, I-35122 Padua (Italy); Artioli, Gilberto [Università degli Studi di Padova, Dipartimento di Geoscienze (Italy); Zoppi, Marco [Consiglio Nazionale delle Ricerche, Istituto dei Sistemi Complessi, Sesto Fiorentino, FI (Italy)

    2014-05-01

    Iulia Concordia is an important Roman settlement known for the production of iron objects and weapons during the Roman Empire. A huge number of well-preserved styli were found in the past century in the bed of an old channel. In order to shed light about the production processes used by Roman for stylus manufacturing, a neutron diffraction residual strain analysis was performed on the POLDI materials science diffractometer at the Paul Scherrer Institut in Switzerland. Here, we present results from our investigation conducted on 11 samples, allowing to define, in a non-invasive way, the residual strain map related to the ancient Roman working techniques. - Highlights: • We examined 11 Roman styli from the settlement of Iulia Concordia, Italy. • We performed a neutron diffraction residual strain analysis on POLDI at PSI (CH). • We identified the production processes used by Roman for stylus manufacturing. • We clarified the way and direction of working applied for different classes of styli.

  2. Low Energy Distillation Schemes 

    E-Print Network [OSTI]

    Polley, G. T.

    2002-01-01

    .6 62.7 C/O 80.9 die 17.5 62.7 C/OE AlDC 57.5 5.3 5.3 Table 5. Cumulative Heat Load Table Component Mole Fraction Molal Flow kmol/hr A: Propane 0.05 45.36 B: iso-Butane 0.15 136.08 C: Butane 0.25 226.80 D: iso-Pentane 0.20 181.46 E: Pentane 0...

  3. Distillation: The Efficient Workhorse 

    E-Print Network [OSTI]

    Steinmeyer, D.

    1985-01-01

    ) then gives Efficiency tails off sharply as xl CD drops below 0.1 Maximum Embedded Work-(ln a)RT o (l+(a-l)Xll a-I (7) a ? 1.5 a . 2 a. 4 A second reason for the belief is that plant accounting ~stems normally place a value on utilities that is far... of separation 1.0 : Total embedded work 4.9 n = 1.0 0.2 D BUt most of the embedded work went for driving force losses: Losses for driving f.orces Reflux above the minimum 0.1 Exchanger 6T 2.1 6P in tower 0.5 6P in condenser and piping 0...

  4. A fast minimal residual solver for overlap fermions

    E-Print Network [OSTI]

    Artan Borici; Alban Allkoci

    2006-02-09

    Computing quark propagators with overlap fermions requires the solution of a shifted unitary linear system. Jagels and Reichel have shown that for such systems it is possible to construct a minimal residual algorithm by short recurrences. The J\\"ulich-Wuppertal group have found this algorithm to be the fastest among overlap solvers. In this paper we present a three-term recurrence for the Arnoldi unitary process. Using the new recurrence we construct a minimal residual solver which is the fastest among all Krylov subspace algorithms considered so far for the overlap inversion.

  5. Wood residuals find big uses in small pieces

    SciTech Connect (OSTI)

    Glenn, J.

    1996-12-01

    With a history of finding economic uses for leftovers, the wood industry explores sustainable options for creating higher value products. Years ago, companies saw the use - any use - of residues as a sound, economic business practice. Today, many companies are looking to go beyond low value products such as mulch, animal bedding and fuel, and market to higher value end users. Additionally, with so much material from the primary industries already accounted for, consumers of wood residue are in need of additional supply from sources such as secondary mills (furniture manufacturers, etc.), as wells as the C&D and MSW streams. This paper discusses these products and markets.

  6. A Residual Mass Ballistic Testing Method to Compare Armor Materials or Components (Residual Mass Ballistic Testing Method)

    SciTech Connect (OSTI)

    Benjamin Langhorst; Thomas M Lillo; Henry S Chu

    2014-05-01

    A statistics based ballistic test method is presented for use when comparing multiple groups of test articles of unknown relative ballistic perforation resistance. The method is intended to be more efficient than many traditional methods for research and development testing. To establish the validity of the method, it is employed in this study to compare test groups of known relative ballistic performance. Multiple groups of test articles were perforated using consistent projectiles and impact conditions. Test groups were made of rolled homogeneous armor (RHA) plates and differed in thickness. After perforation, each residual projectile was captured behind the target and its mass was measured. The residual masses measured for each test group were analyzed to provide ballistic performance rankings with associated confidence levels. When compared to traditional V50 methods, the residual mass (RM) method was found to require fewer test events and be more tolerant of variations in impact conditions.

  7. Waste Heat Powered Ammonia Absorption Refrigeration Unit for LPG Recovery

    SciTech Connect (OSTI)

    Donald C, Energy Concepts Co.; Lauber, Eric, Western Refining Co.

    2008-06-20

    An emerging DOE-sponsored technology has been deployed. The technology recovers light ends from a catalytic reformer plant using waste heat powered ammonia absorption refrigeration. It is deployed at the 17,000 bpd Bloomfield, New Mexico refinery of Western Refining Company. The technology recovers approximately 50,000 barrels per year of liquefied petroleum gas that was formerly being flared. The elimination of the flare also reduces CO2 emissions by 17,000 tons per year, plus tons per year reductions in NOx, CO, and VOCs. The waste heat is supplied directly to the absorption unit from the Unifiner effluent. The added cooling of that stream relieves a bottleneck formerly present due to restricted availability of cooling water. The 350oF Unifiner effluent is cooled to 260oF. The catalytic reformer vent gas is directly chilled to minus 25oF, and the FCC column overhead reflux is chilled by 25oF glycol. Notwithstanding a substantial cost overrun and schedule slippage, this project can now be considered a success: it is both profitable and highly beneficial to the environment. The capabilities of directly-integrated waste-heat powered ammonia absorption refrigeration and their benefits to the refining industry have been demonstrated.

  8. Numerical Simulations of Leakage from Underground LPG Storage Caverns

    E-Print Network [OSTI]

    Yamamoto, Hajime; Pruess, Karsten

    2004-01-01

    2.5.6. Saturated vapor pressure of propane Ideal Gas Heatpropane viscosity as a function of temperature, at P = 1.013x10 5 Pa Wagner Equation Saturated Vapor Pressure,pressure suitable for propane is about 0.8 MPa, slightly exceeding the saturated vapor

  9. Application of Energy Saving Concepts to LPG Recovery Plants 

    E-Print Network [OSTI]

    Carpenter, M. J.; Barnwell, J.

    1982-01-01

    inefficient compared to current standards. This paper deals with energy savings that may be effected for one such plant. Three basic ideas are evaluated:- o Use of Multi-Component Chilling (MCC). o Addition of an Expander. o Heat Recovery from Gas Turbine...

  10. Microsoft Word - 0615DOE-LPG-wd6.doc

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOE Safetyof Methane HydrateUpdateBudgetingUtilityisConantDOSSCADA[301]

  11. Leptonic Dirac CP Violation Predictions from Residual Discrete Symmetries

    E-Print Network [OSTI]

    Girardi, I; Stuart, Alexander J; Titov, A V

    2015-01-01

    Assuming that the observed pattern of 3-neutrino mixing is related to the existence of a (lepton) flavour symmetry, corresponding to a non-Abelian discrete symmetry group $G_f$, and that $G_f$ is broken to specific residual symmetries $G_e$ and $G_\

  12. Leptonic Dirac CP Violation Predictions from Residual Discrete Symmetries

    E-Print Network [OSTI]

    I. Girardi; S. T. Petcov; Alexander J. Stuart; A. V. Titov

    2015-09-08

    Assuming that the observed pattern of 3-neutrino mixing is related to the existence of a (lepton) flavour symmetry, corresponding to a non-Abelian discrete symmetry group $G_f$, and that $G_f$ is broken to specific residual symmetries $G_e$ and $G_\

  13. Modeling EU electricity market competition using the residual supply index

    SciTech Connect (OSTI)

    Swinand, Gregory; Scully, Derek; Ffoulkes, Stuart; Kessler, Brian

    2010-11-15

    An econometric approach to related hourly Residual Supply Index to price-cost margins in the major EU electricity generation markets suggests that market structure, as measured by the RSI, is a significant explanatory factor for markups, even when scarcity and other explanatory variables are included. (author)

  14. Technology for treatment of salt residue stored at NPPs

    SciTech Connect (OSTI)

    Kobelev, A.P.; Savkin, A.E.; Sinjakin, O.G.; Kachalova, E.A.; Sorokoletova, A.N.; Nechaev, V.R. [SUE Moscow SIA Radon (Russian Federation)

    2007-07-01

    At Moscow SIA 'Radon', three (3) options for NPP salt residue treatment were developed and tested. Option 1 consists of dissolving the salt residue and subsequent treatment by ozonization, separation of the deposits formed from ozonization and selective cleaning by ferrocyanide sorbents. Option 2 consists of fusion of the salt residue, addition of glass-forming additives and melting of borosilicate glass in a melter such as a 'cold crucible'. Option 3 consists of dissolving the salt residue, oxidation of the solution obtained, removal of radionuclides by collectors and the separate handling of formed deposits and the solution. The deposits containing more than 99 % of the activity are directed to vitrification and the solution is directed either to a concentrates dryer or to cementation. The vitrified waste product is placed in repository for solid radioactive waste storage and the solidified product from the solution goes to an industrial waste disposal site or a repository specially developed at NPP sites for 'exempt waste' products by IAEA classification. (authors)

  15. PRTAD: A DATABASE FOR PROTEIN RESIDUE TORSION ANGLE DISTRIBUTIONS

    E-Print Network [OSTI]

    PRTAD: A DATABASE FOR PROTEIN RESIDUE TORSION ANGLE DISTRIBUTIONS By Xiaoyong Sun Di Wu Robert­0436 Phone: 612-624-6066 Fax: 612-626-7370 URL: http://www.ima.umn.edu #12;PRTAD: A Database for Protein@iastate.edu Abstract PRTAD is a dedicated database and structural bioinformatics system for protein analysis

  16. COMMUNICATION Are Residues in a Protein Folding Nucleus

    E-Print Network [OSTI]

    Dai, Yang

    COMMUNICATION Are Residues in a Protein Folding Nucleus Evolutionarily Conserved? Yan Yuan Tseng is the hallmark of life. It is important to understand how protein folding and evolution influence each other in protein folding nucleus as measured by experi- mental f-value and selection pressure as measured by v

  17. Effective Reverse Conversion in Residue Number System Processors

    E-Print Network [OSTI]

    propose effective Residue Number System (RNS) to Weighted Number System conversion techniques with k being the num- ber of moduli. First, we introduce an RNS to MRC technique, which ad- dresses in an RNS to MRC with an asymptotic complexity, in terms of arithmetic operations, in the order of O

  18. A PROBABILISTIC FINITE ELEMENT ANALYSIS OF RESIDUAL STRESS FORMATION

    E-Print Network [OSTI]

    Grujicic, Mica

    A PROBABILISTIC FINITE ELEMENT ANALYSIS OF RESIDUAL STRESS FORMATION IN SHRINK-FIT CERAMIC shrink fitting of the jacket over the lining is studied using a probabilistic finite element analysis structural analysis approach, known as the Advanced Mean Value (AMV) method, is used which enables

  19. ROBUST RESIDUAL VIBRATION SUPPRESSION USING IIR DIGITAL FILTERS

    E-Print Network [OSTI]

    Mavroidis, Constantinos

    ROBUST RESIDUAL VIBRATION SUPPRESSION USING IIR DIGITAL FILTERS D. Economou a , C. Mavroidis b and I. Antoniadis a a National Technical University of Athens Department of Mechanical Engineering, 9 Rutgers University, The State University of New Jersey, Department of Mechanical and Aerospace Engineering

  20. Residual Reconstruction for Block-Based Compressed Sensing of Video

    E-Print Network [OSTI]

    Fowler, James E.

    -sensing reconstruction for still images is adapted to video. Incorporating reconstruction from a residual arising from thresholding within the framework introduced in [2]. The term block-based CS (BCS) sampling with smooth] revealed that BCS-SPL reconstruction usually offers at least the same quality of recovery as does other

  1. Removal of residual particulate matter from filter media

    DOE Patents [OSTI]

    Almlie, Jay C; Miller, Stanley J

    2014-11-11

    A method for removing residual filter cakes that remain adhered to a filter after typical particulate removal methodologies have been employed, such as pulse-jet filter element cleaning, for all cleanable filters used for air pollution control, dust control, or powder control.

  2. PeriodicitiesinSequenceResidueHydropathyandtheImplicationsonProteinFolds Nancy Zhang

    E-Print Network [OSTI]

    Brutlag, Doug

    1 PeriodicitiesinSequenceResidueHydropathyandtheImplicationsonProteinFolds Nancy Zhang March, 2000 algorithms is that there are hidden variables effecting the protein folding mechanism and explain why it is crucial to a protein's fold. In section III, I will explain how the Fourier transform

  3. Single-Step Syngas-to-Distillates (S2D) Process Based on Biomass-Derived Syngas – A Techno-Economic Analysis

    SciTech Connect (OSTI)

    Zhu, Yunhua; Jones, Susanne B.; Biddy, Mary J.; Dagle, Robert A.; Palo, Daniel R.

    2012-08-01

    This study reports the comparison of biomass gasification based syngas-to-distillate (S2D) systems using techno-economic analysis (TEA). Three cases, state of technology (SOT) case, goal case, and conventional case, were compared in terms of performance and cost. The SOT case and goal case represent technology being developed at Pacific Northwest National Laboratory for a process starting with syngas using a single-step dual-catalyst reactor for distillate generation (S2D process). The conventional case mirrors the two-step S2D process previously utilized and reported by Mobil using natural gas feedstock and consisting of separate syngas-to-methanol and methanol-to-gasoline (MTG) processes. Analysis of the three cases revealed that the goal case could indeed reduce fuel production cost over the conventional case, but that the SOT was still more expensive than the conventional. The SOT case suffers from low one-pass yield and high selectivity to light hydrocarbons, both of which drive up production cost. Sensitivity analysis indicated that light hydrocarbon yield, single pass conversion efficiency, and reactor space velocity are the key factors driving the high cost for the SOT case.

  4. Single-Step Syngas-to-Distillates (S2D) Process Based on Biomass-Derived Syngas - A Techno-Economic Analysis

    SciTech Connect (OSTI)

    Zhu, Y.; Jones, S. B.; Biddy, M. J.; Dagle, R. A.; Palo, D. R.

    2012-08-01

    This study compared biomass gasification based syngas-to-distillate (S2D) systems using techno-economic analysis (TEA). Three cases, state of technology (SOT), goal, and conventional, were compared in terms of performance and cost. The SOT case represented the best available experimental results for a process starting with syngas using a single-step dual-catalyst reactor for distillate generation. The conventional case mirrored a conventional two-step S2D process consisting of separate syngas-to-methanol and methanol-to-gasoline (MTG) processes. The goal case assumed the same performance as the conventional, but with a single-step S2D technology. TEA results revealed that the SOT was more expensive than the conventional and goal cases. The SOT case suffers from low one-pass yield and high selectivity to light hydrocarbons, both of which drive up production cost. Sensitivity analysis indicated that light hydrocarbon yield and single pass conversion efficiency were the key factors driving the high cost for the SOT case.

  5. Residual Stresses in 21-6-9 Stainless Steel Warm Forgings

    SciTech Connect (OSTI)

    Everhart, Wesley A.; Lee, Jordan D.; Broecker, Daniel J.; Bartow, John P.; McQueen, Jamie M.; Switzner, Nathan T.; Neidt, Tod M.; Sisneros, Thomas A.; Brown, Donald W.

    2012-11-14

    Forging residual stresses are detrimental to the production and performance of derived machined parts due to machining distortions, corrosion drivers and fatigue crack drivers. Residual strains in a 21-6-9 stainless steel warm High Energy Rate Forging (HERF) were measured via neutron diffraction. The finite element analysis (FEA) method was used to predict the residual stresses that occur during forging and water quenching. The experimentally measured residual strains were used to calibrate simulations of the three-dimensional residual stress state of the forging. ABAQUS simulation tools predicted residual strains that tend to match with experimental results when varying yield strength is considered.

  6. ,"U.S. Total Sales of Residual Fuel Oil by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    to Oil Company Consumers (Thousand Gallons)","U.S. Residual Fuel Oil SalesDeliveries to Electric Utility Consumers (Thousand Gallons)","U.S. Residual Fuel Oil SalesDeliveries to...

  7. Ma,BonzongoandGao/UniversityofFlorida Characterization and Leachability of Coal Combustion Residues

    E-Print Network [OSTI]

    Ma, Lena

    Ma,BonzongoandGao/UniversityofFlorida Characterization and Leachability of Coal Combustion Residues an important solid waste in Florida, i.e., coal combustion residues (CCR) detailed in #2-4 of the current

  8. Evaluation of residual stress gradients in ductile cast iron using critical refracted longitudinal (Lcr) wave technique 

    E-Print Network [OSTI]

    Pfluger, Ron Atlan

    1995-01-01

    Critically refracted longitudinal (LCR) waves have been investigated as a possible technique for the evaluation of the residual stress gradients present in ductile iron castings. Residual stresses are likely to develop in ductile cast iron during...

  9. Techniques for identifying long-range residue correlations in the fifth binding module of LDLR

    E-Print Network [OSTI]

    Lin, Jennifer W

    2006-01-01

    The study of correlations between residues in distal regions of a protein structure may provide insights into the mechanism of protein folding. Such long-range correlations may exist between distant residues that are ...

  10. Making Photosynthetic Biofuel Renewable: Recovering Phosphorus from Residual Biomass J. M. Gifford and P. Westerhoff

    E-Print Network [OSTI]

    Hall, Sharon J.

    Making Photosynthetic Biofuel Renewable: Recovering Phosphorus from Residual Biomass J. M. Gifford to global warming. Biofuel from phototrophic microbes like algae and bacteria provides a viable substitute improves biofuel sustainability by refining phosphorus recycling. Biomass Production Residual Biomass

  11. Hubble Residuals of Nearby SN Ia Are Correlated with Host Galaxy...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Hubble Residuals of Nearby SN Ia Are Correlated with Host Galaxy Masses Citation Details In-Document Search Title: Hubble Residuals of Nearby SN Ia Are Correlated...

  12. Viscosity stabilization of SRC residual oil. Final technical report

    SciTech Connect (OSTI)

    Tewari, K.C.

    1984-05-01

    The use of SRC residual oils for No. 6 Fuel Oil substitutes has been proposed. The oils exhibit viscosity characteristics at elevated temperatures that allow this substitution with only minor modifications to the existing fuel oil infrastructure. However, loss of low-boiling materials causes an increase in the viscosity of the residual oils that is greater than expected from concentration changes. A process has been developed that minimizes the loss of volatiles and thus maintains the viscosity of these materials. The use of an additive (water, phenol, or an SRC light oil cut rich in low-boiling phenols in amounts up to 2.0 wt %) accomplishes this and hence stabilizes the pumping and atomizing characteristics for an extended period. During the course of the work, the components of the volatiles lost were identified and the viscosity change due to this loss was quantified. 3 references, 6 figures, 9 tables.

  13. Residuals in steel products -- Impacts on properties and measures to minimize them

    SciTech Connect (OSTI)

    Emi, Toshihiko [Tohoku Univ., Sendai (Japan). Inst. for Advanced Materials Processing; Wijk, O. [Royal Inst. of Tech., Stockholm (Sweden). Dept. of Process Metallurgy

    1996-12-31

    The effect of major residual elements on the properties of steel products is summarized. Measures to minimize these elements are discussed including the pretreatment of raw materials, innovative refining processes and environmental issues. This paper addresses (1) scrap situation, (2) upper limit of residual concentrations acceptable for processing and product quality, (3) possible means to reduce the residuals, and (4) consideration on the practicable measures to solve the residuals problem in a systematic way. 52 refs.

  14. Type Ia supernova Hubble residuals and host-galaxy properties

    SciTech Connect (OSTI)

    Kim, A. G.; Aldering, G.; Aragon, C.; Bailey, S.; Fakhouri, H. K. [Physics Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Antilogus, P.; Bongard, S.; Canto, A.; Cellier-Holzem, F.; Fleury, M.; Guy, J. [Laboratoire de Physique Nucléaire et des Hautes Énergies, Université Pierre et Marie Curie Paris 6, Université Paris Diderot Paris 7, CNRS-IN2P3, 4 place Jussieu, F-75252 Paris Cedex 05 (France); Baltay, C. [Department of Physics, Yale University, New Haven, CT 06250-8121 (United States); Buton, C.; Feindt, U.; Greskovic, P.; Kowalski, M. [Physikalisches Institut, Universität Bonn, Nußallee 12, D-53115 Bonn (Germany); Childress, M. [Research School of Astronomy and Astrophysics, Australian National University, Canberra, ACT 2611 (Australia); Chotard, N.; Copin, Y.; Gangler, E. [Université de Lyon, F-69622 Lyon (France); Université de Lyon 1, Villeurbanne (France); CNRS/IN2P3, Institut de Physique Nucléaire de Lyon (France); and others

    2014-03-20

    Kim et al. introduced a new methodology for determining peak-brightness absolute magnitudes of type Ia supernovae from multi-band light curves. We examine the relation between their parameterization of light curves and Hubble residuals, based on photometry synthesized from the Nearby Supernova Factory spectrophotometric time series, with global host-galaxy properties. The K13 Hubble residual step with host mass is 0.013 ± 0.031 mag for a supernova subsample with data coverage corresponding to the K13 training; at <<1?, the step is not significant and lower than previous measurements. Relaxing the data coverage requirement of the Hubble residual step with the host mass is 0.045 ± 0.026 mag for the larger sample; a calculation using the modes of the distributions, less sensitive to outliers, yields a step of 0.019 mag. The analysis of this article uses K13 inferred luminosities, as distinguished from previous works that use magnitude corrections as a function of SALT2 color and stretch parameters: steps at >2? significance are found in SALT2 Hubble residuals in samples split by the values of their K13 x(1) and x(2) light-curve parameters. x(1) affects the light-curve width and color around peak (similar to the ?m {sub 15} and stretch parameters), and x(2) affects colors, the near-UV light-curve width, and the light-curve decline 20-30 days after peak brightness. The novel light-curve analysis, increased parameter set, and magnitude corrections of K13 may be capturing features of SN Ia diversity arising from progenitor stellar evolution.

  15. Spatial autocorrelation approaches to testing residuals from least squares regression

    E-Print Network [OSTI]

    Chen, Yanguang

    2015-01-01

    In statistics, the Durbin-Watson test is always employed to detect the presence of serial correlation of residuals from a least squares regression analysis. However, the Durbin-Watson statistic is only suitable for ordered time or spatial series. If the variables comprise cross-sectional data coming from spatial random sampling, the Durbin-Watson will be ineffectual because the value of Durbin-Watson's statistic depends on the sequences of data point arrangement. Based on the ideas from spatial autocorrelation, this paper presents two new statistics for testing serial correlation of residuals from least squares regression based on spatial samples. By analogy with the new form of Moran's index, an autocorrelation coefficient is defined with a standardized residual vector and a normalized spatial weight matrix. Then on the analogy of the Durbin-Watson statistic, a serial correlation index is constructed. As a case, the two statistics are applied to the spatial sample of 29 China's regions. These results show th...

  16. Residual ferroelectricity in barium strontium titanate thin film tunable dielectrics

    SciTech Connect (OSTI)

    Garten, L. M., E-mail: lmg309@psu.edu; Trolier-McKinstry, S. [Department of Materials Science and Engineering and Materials Research Institute, The Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Lam, P.; Harris, D.; Maria, J.-P. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27607 (United States)

    2014-07-28

    Loss reduction is critical to develop Ba{sub 1?x}Sr{sub x}TiO{sub 3} thin film tunable microwave dielectric components and dielectric energy storage devices. The presence of ferroelectricity, and hence the domain wall contributions to dielectric loss, will degrade the tunable performance in the microwave region. In this work, residual ferroelectricity—a persistent ferroelectric response above the global phase transition temperature—was characterized in tunable dielectrics using Rayleigh analysis. Chemical solution deposited Ba{sub 0.7}Sr{sub 0.3}TiO{sub 3} films, with relative tunabilities of 86% over 250?kV/cm at 100?kHz, demonstrated residual ferroelectricity 65?°C above the ostensible paraelectric transition temperature. Frequency dispersion observed in the dielectric temperature response was consistent with the presence of nanopolar regions as one source of residual ferroelectricity. The application of AC electric field for the Rayleigh analysis of these samples led to a doubling of the dielectric loss for fields over 10?kV/cm at room temperature.

  17. The effect of magnetic flutter on residual flow

    SciTech Connect (OSTI)

    Terry, P. W.; Pueschel, M. J.; Carmody, D. [Department of Physics, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States)] [Department of Physics, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States); Nevins, W. M. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States)] [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States)

    2013-11-15

    The hypothesis that stochastic magnetic fields disrupt zonal flows associated with ion temperature gradient turbulence saturation is investigated analytically with a residual flow calculation in the presence of magnetic flutter. The calculation starts from the time-asymptotic zero-beta residual flow of Rosenbluth and Hinton [Phys. Rev. Lett. 80, 724 (1998)] with the sudden application of an externally imposed, fixed magnetic field perturbation. The short-time electron response from radial charge loss due to magnetic flutter is calculated from the appropriate gyrokinetic equation. The potential evolution has quadratic behavior, with a zero crossing at finite time. The crossing time and its parametric dependencies are compared with numerical results from a gyrokinetic simulation of residual flow in the presence of magnetic flutter. The numerical and analytical results are in good agreement and support the hypothesis that the high-beta runaway of numerical simulations is a result of the disabling of zonal flows by finite-beta charge losses associated with magnetic flutter.

  18. Infrared Spectroscopy of Explosives Residues: Measurement Techniques and Spectral Analysis

    SciTech Connect (OSTI)

    Phillips, Mark C.; Bernacki, Bruce E.

    2015-03-11

    Infrared laser spectroscopy of explosives is a promising technique for standoff and non-contact detection applications. However, the interpretation of spectra obtained in typical standoff measurement configurations presents numerous challenges. Understanding the variability in observed spectra from explosives residues and particles is crucial for design and implementation of detection algorithms with high detection confidence and low false alarm probability. We discuss a series of infrared spectroscopic techniques applied toward measuring and interpreting the reflectance spectra obtained from explosives particles and residues. These techniques utilize the high spectral radiance, broad tuning range, rapid wavelength tuning, high scan reproducibility, and low noise of an external cavity quantum cascade laser (ECQCL) system developed at Pacific Northwest National Laboratory. The ECQCL source permits measurements in configurations which would be either impractical or overly time-consuming with broadband, incoherent infrared sources, and enables a combination of rapid measurement speed and high detection sensitivity. The spectroscopic methods employed include standoff hyperspectral reflectance imaging, quantitative measurements of diffuse reflectance spectra, reflection-absorption infrared spectroscopy, microscopic imaging and spectroscopy, and nano-scale imaging and spectroscopy. Measurements of explosives particles and residues reveal important factors affecting observed reflectance spectra, including measurement geometry, substrate on which the explosives are deposited, and morphological effects such as particle shape, size, orientation, and crystal structure.

  19. Washing of Rocky Flats Combustible Residues (Conducted March - May 1995)

    SciTech Connect (OSTI)

    Mary E. Barr; Ann R. Schake; David A. Romero; Gordon D. Jarvinen

    1999-03-01

    The scope of this project is to determine the feasibility of washing plutonium-containing combustible residues using ultrasonic disruption as a method for dislodging particulate. Removal of plutonium particulate and, to a lesser extent, solubilized plutonium from the organic substrate should substantially reduce potential fire, explosion or radioactive release hazards due to radiolytic hydrogen generation or high flammability. Tests were conducted on polypropylene filters which were used as pre-filters in the rich-residue ion-exchange process at the Los Alamos Plutonium Facility. These filters are similar to the Ful-Flo{reg_sign} cartridges used at Rocky Flats that make up a substantial fraction of the combustible residues with the highest hazard rating. Batch experiments were run on crushed filter material in order to determine the amount of Pu removed by stirring, stirring and sonication, and stirring and sonication with the introduction of Pu-chelating water-soluble polymers or surfactants. Significantly more Pu is removed using sonication and sonication with chelators than is removed with mechanical stirring alone.

  20. Hybrid Pressure Retarded Osmosis-Membrane Distillation System for Power Generation from Low-Grade Heat: Thermodynamic Analysis and Energy Efficiency

    SciTech Connect (OSTI)

    Lin, SH; Yip, NY; Cath, TY; Osuji, CO; Elimelech, M

    2014-05-06

    We present a novel hybrid membrane system that operates as a heat engine capable of utilizing low-grade thermal energy, which is not readily recoverable with existing technologies. The closed-loop system combines membrane distillation (MD), which generates concentrated and pure water streams by thermal separation, and pressure retarded osmosis (PRO), which converts the energy of mixing to electricity by a hydro-turbine. The PRO-MD system was modeled by coupling the mass and energy flows between the thermal separation (MD) and power generation (PRO) stages for heat source temperatures ranging from 40 to 80 degrees C and working concentrations of 1.0, 2.0, and 4.0 mol/kg NaCl. The factors controlling the energy efficiency of the heat engine were evaluated for both limited and unlimited mass and heat transfer kinetics in the thermal separation stage. In both cases, the relative flow rate between the MD permeate (distillate) and feed streams is identified as an important operation parameter. There is an optimal relative flow rate that maximizes the overall energy efficiency of the PRO-MD system for given working temperatures and concentration. In the case of unlimited mass and heat transfer kinetics, the energy efficiency of the system can be analytically determined based on thermodynamics. Our assessment indicates that the hybrid PRO-MD system can theoretically achieve an energy efficiency of 9.8% (81.6% of the Carnot efficiency) with hot and cold working temperatures of 60 and 20 degrees C, respectively, and a working solution of 1.0 M NaCl. When mass and heat transfer kinetics are limited, conditions that more closely represent actual operations, the practical energy efficiency will be lower than the theoretically achievable efficiency. In such practical operations, utilizing a higher working concentration will yield greater energy efficiency. Overall, our study demonstrates the theoretical viability of the PRO-MD system and identifies the key factors for performance optimization.

  1. Definite Integrals, Some Involving Residue Theory Evaluated by Maple Code

    SciTech Connect (OSTI)

    Bowman, Kimiko o [ORNL

    2010-01-01

    The calculus of residue is applied to evaluate certain integrals in the range (-{infinity} to {infinity}) using the Maple symbolic code. These integrals are of the form {integral}{sub -{infinity}}{sup {infinity}} cos(x)/[(x{sup 2} + a{sup 2})(x{sup 2} + b{sup 2}) (x{sup 2} + c{sup 2})]dx and similar extensions. The Maple code is also applied to expressions in maximum likelihood estimator moments when sampling from the negative binomial distribution. In general the Maple code approach to the integrals gives correct answers to specified decimal places, but the symbolic result may be extremely long and complex.

  2. Estimation of uncertainty for contour method residual stress measurements

    SciTech Connect (OSTI)

    Olson, Mitchell D.; DeWald, Adrian T.; Prime, Michael B.; Hill, Michael R.

    2014-12-03

    This paper describes a methodology for the estimation of measurement uncertainty for the contour method, where the contour method is an experimental technique for measuring a two-dimensional map of residual stress over a plane. Random error sources including the error arising from noise in displacement measurements and the smoothing of the displacement surfaces are accounted for in the uncertainty analysis. The output is a two-dimensional, spatially varying uncertainty estimate such that every point on the cross-section where residual stress is determined has a corresponding uncertainty value. Both numerical and physical experiments are reported, which are used to support the usefulness of the proposed uncertainty estimator. The uncertainty estimator shows the contour method to have larger uncertainty near the perimeter of the measurement plane. For the experiments, which were performed on a quenched aluminum bar with a cross section of 51 × 76 mm, the estimated uncertainty was approximately 5 MPa (?/E = 7 · 10??) over the majority of the cross-section, with localized areas of higher uncertainty, up to 10 MPa (?/E = 14 · 10??).

  3. Estimation of uncertainty for contour method residual stress measurements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Olson, Mitchell D.; DeWald, Adrian T.; Prime, Michael B.; Hill, Michael R.

    2014-12-03

    This paper describes a methodology for the estimation of measurement uncertainty for the contour method, where the contour method is an experimental technique for measuring a two-dimensional map of residual stress over a plane. Random error sources including the error arising from noise in displacement measurements and the smoothing of the displacement surfaces are accounted for in the uncertainty analysis. The output is a two-dimensional, spatially varying uncertainty estimate such that every point on the cross-section where residual stress is determined has a corresponding uncertainty value. Both numerical and physical experiments are reported, which are used to support the usefulnessmore »of the proposed uncertainty estimator. The uncertainty estimator shows the contour method to have larger uncertainty near the perimeter of the measurement plane. For the experiments, which were performed on a quenched aluminum bar with a cross section of 51 × 76 mm, the estimated uncertainty was approximately 5 MPa (?/E = 7 · 10??) over the majority of the cross-section, with localized areas of higher uncertainty, up to 10 MPa (?/E = 14 · 10??).« less

  4. Alternative cooling resource for removing the residual heat of reactor

    SciTech Connect (OSTI)

    Park, H. C.; Lee, J. H.; Lee, D. S.; Jung, C. Y.; Choi, K. Y. [Korea Hydro and Nuclear Power Co., Ltd., 260 Naa-ri Yangnam-myeon Gyeongju-si, Gyeonasangbuk-do, 780-815 (Korea, Republic of)

    2012-07-01

    The Recirculated Cooling Water (RCW) system of a Candu reactor is a closed cooling system which delivers demineralized water to coolers and components in the Service Building, the Reactor Building, and the Turbine Building and the recirculated cooling water is designed to be cooled by the Raw Service Water (RSW). During the period of scheduled outage, the RCW system provides cooling water to the heat exchangers of the Shutdown Cooling System (SDCS) in order to remove the residual heat of the reactor, so the RCW heat exchangers have to operate at all times. This makes it very hard to replace the inlet and outlet valves of the RCW heat exchangers because the replacement work requires the isolation of the RCW. A task force was formed to prepare a plan to substitute the recirculated water with the chilled water system in order to cool the SDCS heat exchangers. A verification test conducted in 2007 proved that alternative cooling was possible for the removal of the residual heat of the reactor and in 2008 the replacement of inlet and outlet valves of the RCW heat exchangers for both Wolsong unit 3 and 4 were successfully completed. (authors)

  5. Cementation of residue ion exchange resins at Rocky Flats

    SciTech Connect (OSTI)

    Dustin, D.F.; Beckman, T.D.; Madore, C.M.

    1998-03-03

    Ion exchange resins have been used to purify nitric acid solutions of plutonium at Rocky Flats since the 1950s. Spent ion exchange resins were retained for eventual recovery of residual plutonium, typically by incineration followed by the aqueous extraction of plutonium from the resultant ash. The elimination of incineration as a recovery process in the late 1980s and the absence of a suitable alternative process for plutonium recovery from resins led to a situation where spent ion exchange resins were simply placed into temporary storage. This report describes the method that Rocky Flats is currently using to stabilize residue ion exchange resins. The objective of the resin stabilization program is: (1) to ensure their safety during interim storage at the site, and (2) to prepare them for ultimate shipment to the Waste Isolation Pilot Plant (WIPP) in New Mexico. Included in the discussion is a description of the safety concerns associated with ion exchange resins, alternatives considered for their stabilization, the selection of the preferred treatment method, the means of implementing the preferred option, and the progress to date.

  6. A Multi-Factor Analysis of Sustainable Agricultural Residue Removal Potential

    SciTech Connect (OSTI)

    Jared Abodeely; David Muth; Paul Adler; Eleanor Campbell; Kenneth Mark Bryden

    2012-10-01

    Agricultural residues have significant potential as a near term source of cellulosic biomass for bioenergy production, but sustainable removal of agricultural residues requires consideration of the critical roles that residues play in the agronomic system. Previous work has developed an integrated model to evaluate sustainable agricultural residue removal potential considering soil erosion, soil organic carbon, greenhouse gas emission, and long-term yield impacts of residue removal practices. The integrated model couples the environmental process models WEPS, RUSLE2, SCI, and DAYCENT. This study uses the integrated model to investigate the impact of interval removal practices in Boone County, Iowa, US. Residue removal of 4.5 Mg/ha was performed annually, bi-annually, and tri-annually and were compared to no residue removal. The study is performed at the soil type scale using a national soil survey database assuming a continuous corn rotation with reduced tillage. Results are aggregated across soil types to provide county level estimates of soil organic carbon changes and individual soil type soil organic matter content if interval residue removal were implemented. Results show interval residue removal is possible while improving soil organic matter. Implementation of interval removal practices provide greater increases in soil organic matter while still providing substantial residue for bioenergy production.

  7. Estimating Residual Solids Volume In Underground Storage Tanks

    SciTech Connect (OSTI)

    Clark, Jason L.; Worthy, S. Jason; Martin, Bruce A.; Tihey, John R.

    2014-01-08

    The Savannah River Site liquid waste system consists of multiple facilities to safely receive and store legacy radioactive waste, treat, and permanently dispose waste. The large underground storage tanks and associated equipment, known as the 'tank farms', include a complex interconnected transfer system which includes underground transfer pipelines and ancillary equipment to direct the flow of waste. The waste in the tanks is present in three forms: supernatant, sludge, and salt. The supernatant is a multi-component aqueous mixture, while sludge is a gel-like substance which consists of insoluble solids and entrapped supernatant. The waste from these tanks is retrieved and treated as sludge or salt. The high level (radioactive) fraction of the waste is vitrified into a glass waste form, while the low-level waste is immobilized in a cementitious grout waste form called saltstone. Once the waste is retrieved and processed, the tanks are closed via removing the bulk of the waste, chemical cleaning, heel removal, stabilizing remaining residuals with tailored grout formulations and severing/sealing external penetrations. The comprehensive liquid waste disposition system, currently managed by Savannah River Remediation, consists of 1) safe storage and retrieval of the waste as it is prepared for permanent disposition; (2) definition of the waste processing techniques utilized to separate the high-level waste fraction/low-level waste fraction; (3) disposition of LLW in saltstone; (4) disposition of the HLW in glass; and (5) closure state of the facilities, including tanks. This paper focuses on determining the effectiveness of waste removal campaigns through monitoring the volume of residual solids in the waste tanks. Volume estimates of the residual solids are performed by creating a map of the residual solids on the waste tank bottom using video and still digital images. The map is then used to calculate the volume of solids remaining in the waste tank. The ability to accurately determine a volume is a function of the quantity and quality of the waste tank images. Currently, mapping is performed remotely with closed circuit video cameras and still photograph cameras due to the hazardous environment. There are two methods that can be used to create a solids volume map. These methods are: liquid transfer mapping / post transfer mapping and final residual solids mapping. The task is performed during a transfer because the liquid level (which is a known value determined by a level measurement device) is used as a landmark to indicate solids accumulation heights. The post transfer method is primarily utilized after the majority of waste has been removed. This method relies on video and still digital images of the waste tank after the liquid transfer is complete to obtain the relative height of solids across a waste tank in relation to known and usable landmarks within the waste tank (cooling coils, column base plates, etc.). In order to accurately monitor solids over time across various cleaning campaigns, and provide a technical basis to support final waste tank closure, a consistent methodology for volume determination has been developed and implemented at SRS.

  8. Facile residue analysis of recent and prehistoric cook-stones using handheld Raman spectrometry

    E-Print Network [OSTI]

    Short, Laura; Cao, Bin; Sinyukov, Alexander M; Joshi, Amitabh; Scully, Rob; Sanders, Virgil; Voronine, Dmitri V

    2013-01-01

    We performed food residue analysis of cook-stones from experimental and prehistoric earth ovens using a handheld Raman spectrometry. Progress in modern optical technology provides a facile means of rapid non-destructive identification of residue artifacts from archaeological sites. For this study spectral signatures were obtained on sotol (Dasylirion spp.) experimentally baked in an earth oven as well as sotol residue on an experimentally used processing tool. Inulin was the major residue component. The portable handheld Raman spectrometer also detected traces of inulin on boiling stones used to boil commercially obtained inulin. The Raman spectra of inulin and sotol may be useful as signatures of wild plant residues in archaeology. Spectroscopic analysis of millennia-old cook-stones from prehistoric archaeological sites in Fort Hood, TX revealed the presence of residues whose further identification requires improvement of current optical methods.

  9. Finite element residual stress analysis of induction heating bended ferritic steel piping

    SciTech Connect (OSTI)

    Kima, Jong Sung; Kim, Kyoung-Soo; Oh, Young-Jin; Chang, Hyung-Young; Park, Heung-Bae

    2014-10-06

    Recently, there is a trend to apply the piping bended by induction heating process to nuclear power plants. Residual stress can be generated due to thermo-mechanical mechanism during the induction heating bending process. It is well-known that the residual stress has important effect on crack initiation and growth. The previous studies have focused on the thickness variation. In part, some studies were performed for residual stress evaluation of the austenitic stainless steel piping bended by induction heating. It is difficult to find the residual stresses of the ferritic steel piping bended by the induction heating. The study assessed the residual stresses of induction heating bended ferriticsteel piping via finite element analysis. As a result, it was identified that high residual stresses are generated on local outersurface region of the induction heating bended ferritic piping.

  10. Single-well experimental design for studying residual trapping of superciritcal carbon dioxide

    E-Print Network [OSTI]

    Zhang, Y.

    2010-01-01

    break- through curve (BTC) is measured. Tracer breakthrough1) compar- ison of the BTC from the fully watersaturated system and the BTC from the residual gas ?eld;

  11. The effects of drainage and amendments on the physical and chemical properties of bauxite residue 

    E-Print Network [OSTI]

    Thompson, Thomas Lee

    1987-01-01

    on the properties of the residue were studied. The objective was to improve the properties of the residue before adding it to sandy soils. The CEC increased with pH, as would be expected with variable-charge minerals, and the adsorption of phosphate decreased...), or into the ocean (Baseden, 1976). Baseden (1976) reported that seawater could be mixed with the residue, reducing the pH of the residue by precipitating Ca and Ng carbonates. The resulting supernatant solution was then pumped into the ocean. This method...

  12. Table 42. Residual Fuel Oil Prices by PAD District and State

    U.S. Energy Information Administration (EIA) Indexed Site

    Information AdministrationPetroleum Marketing Annual 1999 203 Table 42. Residual Fuel Oil Prices by PAD District and State (Cents per Gallon Excluding Taxes) - Continued...

  13. Table 42. Residual Fuel Oil Prices by PAD District and State

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Information AdministrationPetroleum Marketing Annual 1998 203 Table 42. Residual Fuel Oil Prices by PAD District and State (Cents per Gallon Excluding Taxes) - Continued...

  14. Residual-energy-applications program: support and integration report

    SciTech Connect (OSTI)

    Not Available

    1980-11-01

    The proposed government-owned EAST Facility at the Savannah River Plant in Aiken, South Carolina, would provide capabilities for development and confidence testing of industrial heat pumps, high temperature bottoming cycles, low temperature Rankine cycle power generation systems, and absorption chillers. This work is one component of the Residual Energy Applications Program (REAP). Other documents provide initial considerations concerning the heat pump and power generation systems to be tested at EAST, policy, objectives and guidelines for operation of the facility, a preliminary conceptual design, and environmental data. This report describes support and integration activities that were performed during the contract year. The various elements that impact on the EAST Facility are discussed and an assessment of the EAST Facility mission is given. The report concludes with proposed milestones, schedules, and costs for design, construction, and operation of the facility.

  15. Erk phosphorylates threonine 42 residue of ribosomal protein S3

    SciTech Connect (OSTI)

    Kim, Hag Dong [Laboratory of Biochemistry, School of Life Sciences and Biotechnology, and BioInstitute, Korea University, Seoul 136-701 (Korea, Republic of); Lee, Jae Yung [Department of Biology, Mokpo National University, Chonnam 534-729 (Korea, Republic of); Kim, Joon [Laboratory of Biochemistry, School of Life Sciences and Biotechnology, and BioInstitute, Korea University, Seoul 136-701 (Korea, Republic of)]. E-mail: joonkim@korea.ac.kr

    2005-07-22

    The ribosomal protein S3 (rpS3) is involved in ribosome biogenesis as a member of ribosomal small subunit and also plays a role in the repair of damaged DNA. Extracellular signal-regulated kinase (Erk), a MAP kinase, is known to play important roles in the regulation of cell growth, differentiation, and apoptosis. In this study, the sequence analysis of rpS3 protein revealed that this protein has a putative FXFP motif which is believed to be an Erk binding site. Indeed, the motif was demonstrated as an Erk binding site by co-immunoprecipitation. In addition to this, it was revealed that Erk specifically phosphorylated Thr 42 residue of rpS3 in vitro and in vivo using the various mutants of rpS3. Taken together, rpS3 appears to be phosphorylated by activated Erk in proliferating cells, resulting in the decreased interaction between two proteins.

  16. Description of the prototype diagnostic residual gas analyzer for ITER

    SciTech Connect (OSTI)

    Younkin, T. R.; Biewer, T. M.; Klepper, C. C.; Marcus, C.

    2014-11-15

    The diagnostic residual gas analyzer (DRGA) system to be used during ITER tokamak operation is being designed at Oak Ridge National Laboratory to measure fuel ratios (deuterium and tritium), fusion ash (helium), and impurities in the plasma. The eventual purpose of this instrument is for machine protection, basic control, and physics on ITER. Prototyping is ongoing to optimize the hardware setup and measurement capabilities. The DRGA prototype is comprised of a vacuum system and measurement technologies that will overlap to meet ITER measurement requirements. Three technologies included in this diagnostic are a quadrupole mass spectrometer, an ion trap mass spectrometer, and an optical penning gauge that are designed to document relative and absolute gas concentrations.

  17. Residual energy in magnetohydrodynamic turbulence and in the solar wind

    E-Print Network [OSTI]

    Stanislav Boldyrev; Jean Carlos Perez; Vladimir Zhdankin

    2011-08-30

    Recent observations indicate that kinetic and magnetic energies are not in equipartition in the solar wind turbulence. Rather, magnetic fluctuations are more energetic and have somewhat steeper energy spectrum compared to the velocity fluctuations. This leads to the presence of the so-called residual energy E_r=E_v-E_b in the inertial interval of turbulence. This puzzling effect is addressed in the present paper in the framework of weak turbulence theory. Using a simple model of weakly colliding Alfv\\'en waves, we demonstrate that the kinetic-magnetic equipartition indeed gets broken as a result of nonlinear interaction of Alfv\\'en waves. We establish that magnetic energy is indeed generated more efficiently as a result of these interactions, which proposes an explanation for the solar wind observations.

  18. Cost Methodology for Biomass Feedstocks: Herbaceous Crops and Agricultural Residues

    SciTech Connect (OSTI)

    Turhollow Jr, Anthony F; Webb, Erin; Sokhansanj, Shahabaddine

    2009-12-01

    This report describes a set of procedures and assumptions used to estimate production and logistics costs of bioenergy feedstocks from herbaceous crops and agricultural residues. The engineering-economic analysis discussed here is based on methodologies developed by the American Society of Agricultural and Biological Engineers (ASABE) and the American Agricultural Economics Association (AAEA). An engineering-economic analysis approach was chosen due to lack of historical cost data for bioenergy feedstocks. Instead, costs are calculated using assumptions for equipment performance, input prices, and yield data derived from equipment manufacturers, research literature, and/or standards. Cost estimates account for fixed and variable costs. Several examples of this costing methodology used to estimate feedstock logistics costs are included at the end of this report.

  19. Gas Generation Test Support for Transportation and Storage of Plutonium Residue Materials - Part 1: Rocky Flats Sand, Slag, and Crucible Residues

    SciTech Connect (OSTI)

    Livingston, R.R.

    1999-08-24

    The purpose of this report is to present experimental results that can be used to establish one segment of the safety basis for transportation and storage of plutonium residue materials.

  20. An Integrated Model for Assessment of Sustainable Agricultural Residue Removal Limits for Bioenergy Systems

    SciTech Connect (OSTI)

    D. Muth; K. M. Bryden

    2003-12-01

    Agricultural residues have been identified as a significant potential resource for bioenergy production, but serious questions remain about the sustainability of harvesting residues. Agricultural residues play an important role in limiting soil erosion from wind and water and in maintaining soil organic carbon. Because of this, multiple factors must be considered when assessing sustainable residue harvest limits. Validated and accepted modeling tools for assessing these impacts include the Revised Universal Soil Loss Equation Version 2 (RUSLE2), the Wind Erosion Prediction System (WEPS), and the Soil Conditioning Index. Currently, these models do not work together as a single integrated model. Rather, use of these models requires manual interaction and data transfer. As a result, it is currently not feasible to use these computational tools to perform detailed sustainable agricultural residue availability assessments across large spatial domains or to consider a broad range of land management practices. This paper presents an integrated modeling strategy that couples existing datasets with the RUSLE2 water erosion, WEPS wind erosion, and Soil Conditioning Index soil carbon modeling tools to create a single integrated residue removal modeling system. This enables the exploration of the detailed sustainable residue harvest scenarios needed to establish sustainable residue availability. Using this computational tool, an assessment study of residue availability for the state of Iowa was performed. This study included all soil types in the state of Iowa, four representative crop rotation schemes, variable crop yields, three tillage management methods, and five residue removal methods. The key conclusions of this study are that under current management practices and crop yields nearly 26.5 million Mg of agricultural residue are sustainably accessible in the state of Iowa, and that through the adoption of no till practices residue removal could sustainably approach 40 million Mg. However, when considering the economics and logistics of residue harvest, yields below 2.25 Mg ha-1 are generally considered to not be viable for a commercial bioenergy system. Applying this constraint, the total agricultural residue resource available in Iowa under current management practices is 19 million Mg. Previously published results have shown residue availability from 22 million Mg to over 50 million Mg in Iowa.

  1. POST-OPERATIONAL TREATMENT OF RESIDUAL NA COOLLANT IN EBR-2 USING CARBONATION

    SciTech Connect (OSTI)

    Sherman, S.; Knight, C.

    2011-03-08

    At the end of 2002, the Experimental Breeder Reactor Two (EBR-II) facility became a U.S. Resource Conservation and Recovery Act (RCRA) permitted site, and the RCRA permit1 compelled further treatment of the residual sodium in order to convert it into a less reactive chemical form and remove the by-products from the facility, so that a state of RCRA 'closure' for the facility may be achieved (42 U.S.C. 6901-6992k, 2002). In response to this regulatory driver, and in recognition of project budgetary and safety constraints, it was decided to treat the residual sodium in the EBR-II primary and secondary sodium systems using a process known as 'carbonation.' In early EBR-II post-operation documentation, this process is also called 'passivation.' In the carbonation process (Sherman and Henslee, 2005), the system containing residual sodium is flushed with humidified carbon dioxide (CO{sub 2}). The water vapor in the flush gas reacts with residual sodium to form sodium hydroxide (NaOH), and the CO{sub 2} in the flush gas reacts with the newly formed NaOH to make sodium bicarbonate (NaHCO{sub 3}). Hydrogen gas (H{sub 2}) is produced as a by-product. The chemical reactions occur at the exposed surface of the residual sodium. The NaHCO{sub 3} layer that forms is porous, and humidified carbon dioxide can penetrate the NaHCO{sub 3} layer to continue reacting residual sodium underneath. The rate of reaction is controlled by the thickness of the NaHCO{sub 3} surface layer, the moisture input rate, and the residual sodium exposed surface area. At the end of carbonation, approximately 780 liters of residual sodium in the EBR-II primary tank ({approx}70% of original inventory), and just under 190 liters of residual sodium in the EBR-II secondary sodium system ({approx}50% of original inventory), were converted into NaHCO{sub 3}. No bare surfaces of residual sodium remained after treatment, and all remaining residual sodium deposits are covered by a layer of NaHCO{sub 3}. From a safety standpoint, the inventory of residual sodium in these systems was greatly reduced by using the carbonation process. From a regulatory standpoint, the process was not able to achieve deactivation of all residual sodium, and other more aggressive measures will be needed if the remaining residual sodium must also be deactivated to meet the requirements of the existing environmental permit. This chapter provides a project history and technical summary of the carbonation of EBR-II residual sodium. Options for future treatment are also discussed.

  2. The influence of quench sensitivity on residual stresses in the aluminium alloys 7010 and 7075

    SciTech Connect (OSTI)

    Robinson, J.S.; Tanner, D.A.; Truman, C.E.; Paradowska, A.M.; Wimpory, R.C.

    2012-03-15

    The most critical stage in the heat treatment of high strength aluminium alloys is the rapid cooling necessary to form a supersaturated solid solution. A disadvantage of quenching is that the thermal gradients can be sufficient to cause inhomogeneous plastic deformation which in turn leads to the development of large residual stresses. Two 215 mm thick rectilinear forgings have been made from 7000 series alloys with widely different quench sensitivity to determine if solute loss in the form of precipitation during quenching can significantly affect residual stress magnitudes. The forgings were heat treated and immersion quenched using cold water to produce large magnitude residual stresses. The through thickness residual stresses were measured by neutron diffraction and incremental deep hole drilling. The distribution of residual stresses was found to be similar for both alloys varying from highly triaxial and tensile in the interior, to a state of biaxial compression in the surface. The 7010 forging exhibited larger tensile stresses in the interior. The microstructural variation from surface to centre for both forgings was determined using optical and transmission electron microscopy. These observations were used to confirm the origin of the hardness variation measured through the forging thickness. When the microstructural changes were accounted for in the through thickness lattice parameter, the residual stresses in the two forgings were found to be very similar. Solute loss in the 7075 forging appeared to have no significant effect on the residual stress magnitudes when compared to 7010. - Highlights: Black-Right-Pointing-Pointer Through thickness residual stress measurements made on large Al alloy forgings. Black-Right-Pointing-Pointer Residual stress characterised using neutron diffraction and deep hole drilling. Black-Right-Pointing-Pointer Biaxial compressive surface and triaxial subsurface residual stresses. Black-Right-Pointing-Pointer Quench sensitivity of 7075 promotes significant microstructural differences to 7010. Black-Right-Pointing-Pointer When precipitation is accounted for, residual stress in both forgings are similar.

  3. Integration of Nonlinear CDU Models in RefineryCDU Models in Refinery

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    naphtha Swing cut model Refinery Production LPG 18 20 Light Naphtha 6 6 Premium Gasoline 20 20 Offers lower net cost & different feed quantities Reg. Gasoline 80 92 Gas Oil 163 170 Fuel Oil 148 160 Net Cost of the refinery Crude distillation unit (CDU) 5 #12;CDU & C d d C lCDU & Cascaded Columns Cascaded Columns

  4. A Lifecycle Emissions Model (LEM): Lifecycle Emissions from Transportation Fuels, Motor Vehicles, Transportation Modes, Electricity Use, Heating and Cooking Fuels, and Materials

    E-Print Network [OSTI]

    Delucchi, Mark

    2003-01-01

    n.e. RFG n.e. dist. n.e. ULSD n.e. fuel oil n.e. LPG n.e.dist. = distillate fuel; ULSD = ultra-low-sulfur distillateultra-low-sulfur diesel (ULSD) with 5 ppm S, then weights

  5. Prospects, technology outlook and expectations AMOS Kick-off Seminar

    E-Print Network [OSTI]

    Nørvåg, Kjetil

    Distillate Fuels LPG GTL CNG Biogas Hydrogen Battery Nuclear Available + established distribution network to offer the same sailing distance Politicians say that biogas might become available in the future Shipping industry doubts that biogas will penetrate any significant share of shipping. Identical systems

  6. Management of high sulfur coal combustion residues, issues and practices: Proceedings

    SciTech Connect (OSTI)

    Chugh, Y.P.; Beasley, G.A. [eds.

    1994-10-01

    Papers presented at the following sessions are included in this proceedings: (1) overview topic; (2) characterization of coal combustion residues; (3) environmental impacts of residues management; (4) materials handling and utilization, Part I; and (5) materials handling and utilization, Part II. Selected paper have been processed separately for inclusion in the Energy Science and Technology Database.

  7. Estimates of the Loss of Main-Chain Conformational Entropy of Different Residues on Protein Folding

    E-Print Network [OSTI]

    Pal, Debnath

    Estimates of the Loss of Main-Chain Conformational Entropy of Different Residues on Protein Folding of the main-chain (torsion angles, and ) conformational entropy by taking its side-chain into account. The analysis shows that the main-chain component of the total conformational entropy loss for a residue

  8. RESIDUAL PREDICTION BASED ON UNIT SELECTION David Sundermann1,2,3

    E-Print Network [OSTI]

    Black, Alan W

    RESIDUAL PREDICTION BASED ON UNIT SELECTION David S¨undermann1,2,3 , Harald H¨oge1 , Antonio Recently, we presented a study on residual prediction tech- niques that can be applied to voice conversion based on lin- ear transformation or hidden Markov model-based speech synthesis. Our voice conversion

  9. Dynamic topography and anomalously negative residual depth of the Argentine Basin G.E. Shephard a,

    E-Print Network [OSTI]

    Liu, Lijun

    GR letter Dynamic topography and anomalously negative residual depth of the Argentine Basin G Handling Editor: A. Aitken Keywords: Dynamic topography Residual basement depth Geodynamic modeling Argentine Basin Subduction Plate tectonics A substantial portion of Earth's topography is known to be caused

  10. Dynamic topography and anomalously negative residual depth of the Argentine Basin G.E. Shephard a,

    E-Print Network [OSTI]

    Müller, Dietmar

    GR letter Dynamic topography and anomalously negative residual depth of the Argentine Basin G: A. Aitken Keywords: Dynamic topography Residual basement depth Geodynamic modeling Argentine Basin Subduction Plate tectonics A substantial portion of Earth's topography is known to be caused by the viscous

  11. Residual-Energy-Activated Cooperative Transmission (REACT) to Avoid the Energy Hole

    E-Print Network [OSTI]

    Ingram, Mary Ann

    Residual-Energy-Activated Cooperative Transmission (REACT) to Avoid the Energy Hole Jin Woo Jung of the excess energy to do cooperative transmission (CT) to hop directly to the Sink, thereby relieving residual energy than the current node. The paper considers several criteria for selecting the cooperators

  12. J. Number Theory 124(2007), no. 1, 5761. SIMPLE ARGUMENTS ON CONSECUTIVE POWER RESIDUES

    E-Print Network [OSTI]

    Sun, Zhi-Wei

    2007-01-01

    J. Number Theory 124(2007), no. 1, 57­61. SIMPLE ARGUMENTS ON CONSECUTIVE POWER RESIDUES Zhi-Wei Sun Department of Mathematics, Nanjing University Nanjing 210093, People's Republic of China zwsun: (i) If n is the least positive kth power non-residue modulo a positive integer m, then the greatest

  13. An Endogenous Drosophila Receptor for Glycans Bearing 1,3-Linked Core Fucose Residues*

    E-Print Network [OSTI]

    An Endogenous Drosophila Receptor for Glycans Bearing 1,3-Linked Core Fucose Residues* Received-terminal C-type carbohydrate-recognition do- main. Expression studies show that the full-length pro- tein-linked glycans bearing 1,3-linked fucose residues. Binding is enhanced by the additional presence of 1,6-linked

  14. FaultTolerant Linear Convolution Using Residue Number M.G.Parker,M.Benaissa

    E-Print Network [OSTI]

    Parker, Matthew Geoffrey

    (RNS) and Polynomial Residue Number Systems (PRNS). The RNS and PRNS are both given error in recent years. Another means of FT uses Residue Number Systems (RNS) [4]. A RNS performs computation over to detect and correct. A scheme similar to MR is therefore applicable using RNS by the addition of extra

  15. Residual stress and self-assembly during deposition and etching of MEMS 

    E-Print Network [OSTI]

    Mani, Sathyanarayanan

    2002-01-01

    with no residual stresses. Residual stresses are investigated as a means of self-assembling MEMS and NEMS during material deposition and etching. The assembly of two components is considered: one component is subjected to deposition or etching and is modeled...

  16. Managing N availability and losses by combining fertilizer-N with different quality residues in Kenya

    E-Print Network [OSTI]

    van Kessel, Chris

    Managing N availability and losses by combining fertilizer-N with different quality residues residues are often not available or affordable in sufficient quantities or qualities to be used alone the use of all available resources within each target environment (Kimani et al., 2003). The ISFM approach

  17. Neutron diffraction measurements of residual stresses in friction stir welding: a review

    SciTech Connect (OSTI)

    Woo, Wan Chuck [ORNL; Feng, Zhili [ORNL; Wang, Xun-Li [ORNL; David, Stan A [ORNL

    2011-01-01

    Significant amounts of residual stresses are often generated during welding and result in critical degradation of the structural integrity and performance of components. Neutron diffraction has become a well established technique for the determination of residual stresses in welds because of the unique deep penetration, three-dimensional mapping capability, and volume averaged bulk measurements characteristic of the scattering neutron beam. Friction stir welding has gained prominence in recent years. The authors reviewed a number of neutron diffraction measurements of residual stresses in friction stir welds and highlighted examples addressing how the microstructures and residual stresses are correlated with each other. An example of in situ neutron diffraction measurement result shows the evolution of the residual stresses during welding.

  18. Tidal Residual Eddies and their Effect on Water Exchange in Puget Sound

    SciTech Connect (OSTI)

    Yang, Zhaoqing; Wang, Taiping

    2013-08-30

    Tidal residual eddies are one of the important hydrodynamic features in tidally dominant estuaries and coastal bays, and they could have significant effects on water exchange in a tidal system. This paper presents a modeling study of tides and tidal residual eddies in Puget Sound, a tidally dominant fjord-like estuary in the Pacific Northwest coast, using a three-dimensional finite-volume coastal ocean model. Mechanisms of vorticity generation and asymmetric distribution patterns around an island/headland were analyzed using the dynamic vorticity transfer approach and numerical experiments. Model results of Puget Sound show that a number of large twin tidal residual eddies exist in the Admiralty Inlet because of the presence of major headlands in the inlet. Simulated residual vorticities near the major headlands indicate that the clockwise tidal residual eddy (negative vorticity) is generally stronger than the anticlockwise eddy (positive vorticity) because of the effect of Coriolis force. The effect of tidal residual eddies on water exchange in Puget Sound and its sub-basins were evaluated by simulations of dye transport. It was found that the strong transverse variability of residual currents in the Admiralty Inlet results in a dominant seaward transport along the eastern shore and a dominant landward transport along the western shore of the Inlet. A similar transport pattern in Hood Canal is caused by the presence of tidal residual eddies near the entrance of the canal. Model results show that tidal residual currents in Whidbey Basin are small in comparison to other sub-basins. A large clockwise residual circulation is formed around Vashon Island near entrance of South Sound, which can potentially constrain the water exchange between the Central Basin and South Sound.

  19. Recovery of alkali metal constituents from catalytic coal conversion residues

    DOE Patents [OSTI]

    Soung, Wen Y. (Houston, TX)

    1984-01-01

    In a coal gasification operation (32) or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by contacting them (46, 53, 61, 69) with water or an aqueous solution to remove water-soluble alkali metal constituents and produce an aqueous solution enriched in said constituents. The aqueous solution thus produced is then contacted with carbon dioxide (63) to precipitate silicon constituents, the pH of the resultant solution is increased (81), preferably to a value in the range between about 12.5 and about 15.0, and the solution of increased pH is evaporated (84) to increase the alkali metal concentration. The concentrated aqueous solution is then recycled to the conversion process (86, 18, 17) where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

  20. Recovery of flexible polyurethane foam from shredder residue.

    SciTech Connect (OSTI)

    Daniels, E. J.; Jody, b. J.

    1999-06-29

    Argonne National Laboratory has developed a patented, continuous process for the recovery of flexible polyurethane foam (PUF) from auto shredder residue (ASR). To test the process, Argonne researchers conceived of, designed, and built a continuous foam washing and drying system that was pilot-tested at a shredder facility for six months. Economic analysis of the process, using manufacturers' quotes and operating data from Argonne's pilot plant, indicates a payback of less than two years for a plant producing about 1,000 ton/yr of foam. Samples of clean foam were shipped to three major foam reprocessors; all three indicated that the quality of the PUF recovered by the Argonne process met their requirements. Tests of the recovered foam by an independent testing laboratory showed that the recycled foam met the specifications for several automotive applications, including carpet padding, headliner, and sound-suppression support materials. Recovery of foam reduces the mass and the volume of material going to the landfill by about 5% and 30%, respectively. Annually, recovery will save about 1.2 x 10{sup 12} Btu of energy, cut the amount of solid waste being landfilled by about 150,000 tons, and eliminate the emission of about 250 tons of volatile organic compounds (VOCs) into the air.

  1. Residual Gas Analysis for Long-Pulse, Advanced Tokamak Operation

    SciTech Connect (OSTI)

    Klepper, C Christopher; Hillis, Donald Lee; Bucalossi, J.; Douai, D.; OddonCEA, IRFM, P.; VartanianCEA-Cadarach, S.; Colas, L.; Manenc, L.; Pegourie, B.

    2010-01-01

    A shielded residual gas analyzer RGA system on Tore Supra can function during plasma operation and is set up to monitor the composition of the neutral gas in one of the pumping ducts of the toroidal pumped limited. This diagnostic RGA has been used in long-pulse up to 6 min discharges for continuous monitoring of up to 15 masses simultaneously. Comparison of the RGA-measured evolution of the H2 /D2 isotopic ratio in the exhaust gas to that measured by an energetic neutral particle analyzer in the plasma core provides a way to monitor the evolution of particle balance. RGA monitoring of corrective H2 injection to maintain proper minority heating is providing a database for improved ion cyclotron resonance heating, potentially with RGA-base feedback control. In very long pulses 4 min absence of significant changes in the RGA-monitored, hydrocarbon particle pressures is an indication of proper operation of the actively cooled, carbon-based plasma facing components. Also H2 could increase due to thermodesorption of overheated plasma facing components. 2010 American Institute of Physics.

  2. Treatment of plutonium process residues by molten salt oxidation

    SciTech Connect (OSTI)

    Stimmel, J.; Wishau, R.; Ramsey, K.B.; Montoya, A.; Brock, J.; Heslop, M.; Wernly, K.

    1999-04-01

    Molten Salt Oxidation (MSO) is a thermal process that can remove more than 99.999% of the organic matrix from combustible {sup 238}Pu material. Plutonium processing residues are injected into a molten salt bed with an excess of air. The salt (sodium carbonate) functions as a catalyst for the conversion of the organic material to carbon dioxide and water. Reactive species such as fluorine, chlorine, bromine, iodine, sulfur, phosphorous and arsenic in the organic waste react with the molten salt to form the corresponding neutralized salts, NaF, NaCl, NaBr, NaI, Na{sub 2}SO{sub 4}, Na{sub 3}PO{sub 4} and NaAsO{sub 2} or Na{sub 3}AsO4. Plutonium and other metals react with the molten salt and air to form metal salts or oxides. Saturated salt will be recycled and aqueous chemical separation will be used to recover the {sup 238}Pu. The Los Alamos National Laboratory system, which is currently in the conceptual design stage, will be scaled down from current systems for use inside a glovebox.

  3. ,"U.S. Adjusted Sales of Residual Fuel Oil by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative FuelsMonthly","10/2015"Monthly","10/2015" ,"ReleaseMonthly","10/2015"Net Receipts byDistillate

  4. ,"U.S. Sales for Resale Refiner Sales Volumes of Aviation Fuels, Kerosene, Propane, No.1 and No. 2 Distillates"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Informationmonthly gasoline price to fall to $3.43U.S.longecReformulated Gasoline RefinerResidual

  5. Microstructure and residual stress evaluation of ductile cast iron using the critically refracted longitudinal (Lcr) wave propagation technique 

    E-Print Network [OSTI]

    Bennett, Robert Jeffrey

    1993-01-01

    Residual stress and microstructure evaluation of ductile cast iron using a nondestructive method (Critically Refracted Longitudinal Ultrasonic Wave Technique) was approached. Residual stresses, both good and bad graphite nodules, and different...

  6. Intermediate Vapor Expansion Distillation and Nested Enrichment Cascade Distillation 

    E-Print Network [OSTI]

    Erickson, D. C.

    1986-01-01

    shaft power is being substituted for heat which in many cases may be extremely low valued. Th~ next section describes how to avoid that problem, and even turn it to advantage. 136 ESL-IE-86-06-25 Proceedings from the Eighth Annual Industrial... will improve column efficiency by 15 to 100%, there has been little use of this technique to date." Intermediate vapor compression heat pumping was recently introduced as one practical means of achieving this benefit. Introduced in this paper are two new...

  7. DistillationTheory.fm 2 September 1999 Distillation Theory.

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Skogestad Norwegian University of Science and Technology Department of Chemical Engineering 7491 Trondheim) . . . . . . . . . . . . . . . . . . . . . 13 Typical Column Profiles -- Pinch

  8. Community-wide benefits of targeted indoor residual spray for malaria control in the Western Kenya Highland

    E-Print Network [OSTI]

    Zhou, Guofa; Githeko, Andrew K; Minakawa, Noboru; Yan, Guiyun

    2010-01-01

    ecological settings [4]. Among those control measures, insecticide- treated bed nets (ITNs) and indoor residual-house

  9. Auto shredder residue recycling: Mechanical separation and pyrolysis

    SciTech Connect (OSTI)

    Santini, Alessandro; Passarini, Fabrizio; Vassura, Ivano; Serrano, David; Dufour, Javier

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer In this work, we exploited mechanical separation and pyrolysis to recycle ASR. Black-Right-Pointing-Pointer Pyrolysis of the floating organic fraction is promising in reaching ELV Directive targets. Black-Right-Pointing-Pointer Zeolite catalyst improve pyrolysis oil and gas yield. - Abstract: sets a goal of 85% material recycling from end-of-life vehicles (ELVs) by the end of 2015. The current ELV recycling rate is around 80%, while the remaining waste is called automotive shredder residue (ASR), or car fluff. In Europe, this is mainly landfilled because it is extremely heterogeneous and often polluted with car fluids. Despite technical difficulties, in the coming years it will be necessary to recover materials from car fluff in order to meet the ELV Directive requirement. This study deals with ASR pretreatment and pyrolysis, and aims to determine whether the ELV material recycling target may be achieved by car fluff mechanical separation followed by pyrolysis with a bench scale reactor. Results show that flotation followed by pyrolysis of the light, organic fraction may be a suitable ASR recycling technique if the oil can be further refined and used as a chemical. Moreover, metals are liberated during thermal cracking and can be easily separated from the pyrolysis char, amounting to roughly 5% in mass. Lastly, pyrolysis can be a good starting point from a 'waste-to-chemicals' perspective, but further research should be done with a focus on oil and gas refining, in order both to make products suitable for the chemical industry and to render the whole recycling process economically feasible.

  10. Proposed plant will turn wood residues into synfuel

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    A group of entrepreneurs plan to have a plant operating in Burney, CA. The projected facility will produce an estimated 21,000 gallons of oil per day, converting about 300 tons of raw material. Converting cellulose into synthetic fuel is superior to alcohol production. The process yields approximately 84 gallons of synthetic fuel per ton of raw material. The entire LHG (liquid hydrogen gas) patented facility is self-sufficient and releases only carbon dioxide into the atmosphere. Synfuel production is a three-phase process. First, butyl alcohol (butanol) and acetone are produced from a portion of the raw material. This is facilitated by adding to the raw material a bacteria culture. The planned facility in Burney will have thirty-five 2100 gallon fermentation tanks and will produce 1.25 million gallons of butanol. Next, organic material is blended with water and is pumped into patented LHG catalytic converters, charged with carbon monoxide gas as a catalyst and then heated to 350 degrees C at 2000 to 5000 psi. Here, the organic material is converted to No. 4 oil with bituminous tar as a residue. A patented gasifier system produces the carbon monoxide catalyst plus COH (carbon hydroxide) gas. The COH is used to power a gas turbine driving a 100 kW generator and a central hydraulic pump. The facility, which will be energy self-sufficient, will have approximately 50 kW of excess power to sell to the local utility power grid. Finally, the No. 4 oil, butanol and liquified COH gas are blended to produce any grade fuel oil or a gasoline substitute of very high octane.

  11. Residual stress within nanoscale metallic multilayer systems during thermal cycling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Economy, David Ross; Cordill, Megan Jo; Payzant, E. Andrew; Kennedy, Marian S.

    2015-09-21

    Projected applications for nanoscale metallic multilayers will include wide temperature ranges. Since film residual stress has been known to alter system reliability, stress development within new film structures with high interfacial densities should be characterized to identify potential long-term performance barriers. To understand factors contributing to thermal stress evolution within nanoscale metallic multilayers, stress in Cu/Nb systems adhered to Si substrates was calculated from curvature measurements collected during cycling between 25 °C and 400 °C. Additionally, stress within each type of component layers was calculated from shifts in the primary peak position from in-situ heated X-ray diffraction. The effects ofmore »both film architecture (layer thickness) and layer order in metallic multilayers were tracked and compared with monolithic Cu and Nb films. Analysis indicated that the thermoelastic slope of nanoscale metallic multilayer films depends on thermal expansion mismatch, elastic modulus of the components, and also interfacial density. The layer thickness (i.e. interfacial density) affected thermoelastic slope magnitude while layer order had minimal impact on stress responses after the initial thermal cycle. When comparing stress responses of monolithic Cu and Nb films to those of the Cu/Nb systems, the nanoscale metallic multilayers show a similar increase in stress above 200 °C to the Nb monolithic films, indicating that Nb components play a larger role in stress development than Cu. Local stress calculations from X-ray diffraction peak shifts collected during heating reveal that the component layers within a multilayer film respond similarly to their monolithic counterparts.« less

  12. Onsager's symmetry relation and the residual parallel Reynolds stress in a magnetized plasma with electrostatic turbulence

    SciTech Connect (OSTI)

    Zuo, Yang, E-mail: yangzustc@gmail.com; Wang, Shaojie [Department of Modern Physics, University of Science and Technology of China, Hefei 230026 (China)

    2014-09-15

    The physics of the residual parallel Reynolds stress in a rotating plasma with electrostatic turbulence is explicitly identified by using the transport formulation of the gyrokinetic turbulence. It is clarified that the residual stress consists of four terms, among which are the cross terms due to the pressure gradient and the temperature gradient and the terms related to the turbulent acceleration impulse and the turbulent heating rate. The last two terms are identified for the first time, and are shown to cause analogous residual term in the heat flux. Meanwhile, the transport matrix reveals diffusion in the phase space. The transport matrix is demonstrated to satisfy the Onsager's symmetry relation.

  13. Element composition and mineralogical characterisation of air pollution control residue from UK energy-from-waste facilities

    E-Print Network [OSTI]

    Crawford, Ian

    Element composition and mineralogical characterisation of air pollution control residue from UKE) Air pollution control residue (APC) Waste characterisation a b s t r a c t Air pollution control (APC://creativecommons.org/licenses/by-nc-nd/3.0/). 1. Introduction 1.1. Background Air pollution control (APC) residues from energy

  14. Evaluation of low-residue soldering for military and commercial applications: A report from the Low-Residue Soldering Task Force

    SciTech Connect (OSTI)

    Iman, R.L.; Anderson, D.J.; Burress, R.V.

    1995-06-01

    The LRSTF combined the efforts of industry, military, and government to evaluate low-residue soldering processes for military and commercial applications. These processes were selected for evaluation because they provide a means for the military to support the presidential mandate while producing reliable hardware at a lower cost. This report presents the complete details and results of a testing program conducted by the LRSTF to evaluate low-residue soldering for printed wiring assemblies. A previous informal document provided details of the test plan used in this evaluation. Many of the details of that test plan are contained in this report. The test data are too massive to include in this report, however, these data are available on disk as Excel spreadsheets upon request. The main purpose of low-residue soldering is to eliminate waste streams during the manufacturing process.

  15. Momentive Performance Materials Distillation Intercharger 

    E-Print Network [OSTI]

    Boucher, N.; Baisley, T.; Beers, C.; Cameron, R.; Holman, K.; Kotkoskie, T.; Norris, K.

    2013-01-01

    Program ? Lower Cost Hydropower Purchase from NY Power Authority ? River Water Pump Optimization Project ? proposed project ? Technology Building HVAC System Upgrade ? proposed project ? Air Compressor Upgrade ? proposed project ? Waste heat recovery...,000 customers from 100+ production facilities around the world with 10,000 associates ? Balanced geographic portfolio ? Sales of over $7 billion ? Ability to serve global customers in all major regions worldwide ? New Product Development opportunities...

  16. Key Blog Distillation: Ranking Aggregates

    E-Print Network [OSTI]

    Macdonald, C.; Ounis, I.

    Macdonald,C. Ounis,I. In Proceedings of the 17th ACM Conference on Information and Knowledge Management (CIKM 2008), Napa Valley, California, USA, October 26-30, 2008 ACM Press

  17. No. 2 Distillate Prices - Industrial

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6Year JanperGas1.878

  18. No. 2 Distillate Prices - Residential

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6Year JanperGas1.8782.386

  19. Stocks of Distillate Fuel Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices Global Crude Oil Prices Brent crudeEnvironment144,415

  20. No. 2 Distillate Prices - Residential

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets16 (next20, 200820087 DOE/NASEONA NA NA

  1. Imports of Distillate Fuel Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets See full Hydrocarbon7,747 8,021 8,312218

  2. Ultrasonic measurement of the residual stresses in patch welded steel plates 

    E-Print Network [OSTI]

    Junghans, Paul Gerard

    1994-01-01

    This study begins with a review of the nature and origins of residual stresses and the techniques currently used to measure these stresses, both destructive and nondestructive. The theory of ultrasonic stress measurement, ...

  3. Evaluation of Postpartum Reproductive Performance in Brahman Females with Divergent Residual Feed Intake 

    E-Print Network [OSTI]

    Poovey, Anna Kathryn

    2011-10-21

    These studies were designed to evaluate the relationships that exist between residual feed intake, parity, rate of return to estrous cyclicity and nonesterified fatty acid (NEFA) concentrations, as well as changes in ...

  4. Insulin Sensitivity in Tropically Adapted Cattle With Divergent Residual Feed Intake 

    E-Print Network [OSTI]

    Shafer, Gentrie

    2012-10-19

    Residual feed intake (RFI) is one method to identify feed efficient animals; however, this method is costly and time consuming therefore, identifying an indirect measure of RFI is important. Evaluating the glucoregulatory ...

  5. Ultrasonic measurement of residual stress relaxation in welded steel plates using critically refracted longitudinal waves 

    E-Print Network [OSTI]

    Chance, Brent Houston

    2000-01-01

    This study investigates whether or not there is a measurable amount of residual transverse stress relaxation in welded steel. This was determined by using two different methods of stress measurement. These methods involved ...

  6. Disposal of tritium residues at the Los Alamos National Laboratory. Audit repost

    SciTech Connect (OSTI)

    NONE

    1998-07-01

    The objective of this audit was to determine whether Los Alamos disposed of wastewater containing tritium residues in a safe and cost-effective manner subsequent to an October 1991 report reviewing tritium facility management practices.

  7. Variation in energy expenditures between growing steers with divergent residual feed intakes 

    E-Print Network [OSTI]

    White, Monte Blaine III

    2006-04-12

    Objectives of this study were to determine if variation in energy expenditures contributed to differences in feed efficiency between low and high RFI steers. Nine steers with the lowest and highest residual feed intakes (RFI) were selected from 169...

  8. Sources of biological variation in residual feed intake in growing and finishing steers 

    E-Print Network [OSTI]

    Brown, Erin Gwen

    2006-04-12

    Objectives of this research were to characterize residual feed intake (RFI) in growing and finishing steers and examine phenotypic correlations between performance, feed efficiency, carcass, digestib ility, and physiological indicator traits...

  9. Roles of key active-site residues in flavocytochrome P450 BM3

    E-Print Network [OSTI]

    Noble, Michael A.; Miles, Caroline S.; Chapman, Stephen K.; Lysek, Dominikus A.; MacKay, Angela C.; Reid, Graeme A.; Hanzlik, Robert P.; Munro, Andrew W.

    1999-01-01

    The effects of mutation of key active-site residues (Arg-47, Tyr-51, Phe-42 and Phe-87) in Bacillus megaterium flavocytochrome P450 BM3 were investigated. Kinetic studies on the oxidation of laurate and arachidonate showed ...

  10. Root cause analysis of solder flux residue incidence in the manufacture of electronic power modules

    E-Print Network [OSTI]

    Jain, Pranav

    2011-01-01

    This work investigates the root causes of the incidence of solder flux residue underneath electronic components in the manufacture of power modules. The existing deionized water-based centrifugal cleaning process was ...

  11. Polymorphisms at amino acid residues 141 and 154 influence conformational variation in ovine PrP

    E-Print Network [OSTI]

    Yang, Sujeong; Thackray, Alana M.; Hopkins, Lee; Monie, Tom P.; Burke, David F.; Bujdoso, Raymond

    2014-07-14

    transmissible between sheep, whereas this may not be the case with atypical scrapie. Critical amino acid residues will determine the range or stability of structural changes within the ovine prion protein or its functional interaction with potential cofactors...

  12. Protein fold recognition by alignment of amino acid residues using kernelized dynamic time warping

    E-Print Network [OSTI]

    Protein fold recognition by alignment of amino acid residues using kernelized dynamic time warping distances between proteins. This method shows significant improvement in protein fold recognition. Overall March 2014 Keywords: Protein sequence Fold recognition Alignment method Feature extraction

  13. Vehicle Technologies Office Merit Review 2014: Residual Stress of Bimetallic Joints and Characterization

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about residual stress...

  14. Characterization of residual stress relaxation in welded steel plate using TAP-NDE and wavelets 

    E-Print Network [OSTI]

    Jhun, Choon-Sik

    2001-01-01

    This thesis presents the characterization of residual stress relaxation in a welded ASTM 1018 steel plate by using the Thermo-Acousto-Photonic Nondestructive Evaluation (TAP-NDE) technique and the Gabor Wavelet Transform (GWT) which together produce...

  15. The influence of calcium on the inhibition of arsenic desorption from treatment residuals in extreme environments 

    E-Print Network [OSTI]

    Camacho, Julianna G.

    2006-04-12

    the surface properties of the oxy-hydroxide solid in solution. Results show that calcium enhances the removal by iron oxides and prevents the leaching of arsenic from the residuals. Isotherm experiments show that arsenic adsorption can be described...

  16. Measuring the Residual Ferrite Content of Rapidly Solidified Stainless Steel Alloys-

    E-Print Network [OSTI]

    Eagar, Thomas W.

    ) ) Measuring the Residual Ferrite Content of Rapidly Solidified Stainless Steel Alloys. Electron beam welds, laser beam welds and rapidly solidified stainless steel alloys have small physical Fe content by measur- ing the magnetic properties of fully ferritic stainless steel specimens

  17. Determination of nonuniform residual stress using the ring-core method

    SciTech Connect (OSTI)

    Ajovalasit, A.; Petrucci, G.; Zuccarello, B.

    1996-04-01

    This paper considers residual stress analysis using the ring-core method. In particular, the so-called integral equation method is applied to evaluate nonuniform residual stress fields. The proposed method overcomes typical drawbacks of the incremental strain method which lead to incorrect results for strongly varying stress fields. The experimental results obtained with a specimen subjected to a bending load confirm the theoretical predictions.

  18. Evaluation of Residual Stress Levels in Plasma Electrolytic Oxidation Coatings using a Curvature Method

    E-Print Network [OSTI]

    Dean, J.; Gu, T.; Clyne, T. W.

    2014-11-09

    of the residual substrate was obtained, via SEM microscopy of polished cross-sections. 2.3. Curvature measurement Residual stress in coatings formed on such thin strips will tend to give rise to curvature, which can be measured in order to obtain information about... plasma channels through to the substrate, combination of themetalwith oxygen in the vapour phase and melting of surrounding regions, followed by rapid condensation and solidification, and the creation of porosity and micro-cracks. Furthermore, even...

  19. Sand pack residual oil saturations as affected by extraction with various solvents 

    E-Print Network [OSTI]

    Murray, Clarence

    1958-01-01

    LIBRARY S 4 M COLLEGE OF TEXAS SAND PACK RESIDUAL OIL SATURATIONS AS AFFECTED BY EXTRACTION WITH VARIOUS SOLVENTS A Thesis CLARENCE MURRAY, JR. Submitted to the Graduate School of The Agricultural and Mechanical College of Texas in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE August, I958 Major Subject: Petroleum Engineering SAND PACK RESIDUAL OIL SAT URATIONS AS AFFECTED BY EXTRACTION WITH VARIOUS SOLVENTS A Thesis By CLARENCE MURRAY, JR. Approved...

  20. Deformations associated with relaxation of residual stresses in the Barre Granite of Vermont 

    E-Print Network [OSTI]

    Nichols, Thomas Chester

    1972-01-01

    DEFORMATIONS ASSOCIATED WITH RELAXATION OF RESIDUAL STRESSES IN THE BARRE GRANITE OF VERMONT A Thesis by THOMAS CHESTER NICHOLS, JR. Submitted to the Graduate College of Texas AfM University in Partial fulfillment of the requirements... for the degree of MASTER QF SCIENCE May, 1972 Major Subject: Geology DEFORMATIONS ASSOCIATED WITH RELAXATION OF RESIDUAL STRESSES IN THE BARRE GRANITE OF VERMONT A Thesis THOMAS CHESTER NICHOLS, JR. Approved as to style and content by: airman o Committee...

  1. Residual thermal stresses in an unsymmetrical cross-ply graphite/epoxy laminate 

    E-Print Network [OSTI]

    Harper, Brian Douglas

    1980-01-01

    RESIDUAL THERMAL STRESSES IN AN UNSYMMETRICAL CROSS-PLY GRAPHITE/EPOXY LAMINATE A Thesis by BRIAN DOUGLAS HARPER Submitted to the Graduate College of Texas A&M University in parrial fulfillment of the requirement for the degree of MASTER... OF SCIENCE August 1980 Major Subject: Mechanical Engineering RESIDUAL THERMAL STRESSES IN AN UNSYMMETRICAL CROSS-PLY GRAPHITE/EPOXY LAMINATE A Thesis by BRIAN DOUGLAS HARPER Approved as to style and content by: r. Y. N itsman (Chair of Committee) Dr...

  2. Removal of aqueous rinsable flux residues in a batch spray dishwater

    SciTech Connect (OSTI)

    Slanina, J.T.

    1992-02-01

    An alkaline detergent solution used in an industrial dishwasher was evaluated to remove aqueous rinsable flux residues on printed wiring boards (PWBs) after hot air solder leveling and hot oil solder dip and leveling. The dishwasher, a batch cleaning process, was compared to an existing conveyorized aqueous cleaning process. The aqueous soluble flux residues from both soldering processes were removed with a solution of a mild alkaline detergent dissolved in hot deionized (DI) water.

  3. Determine metrics and set targets for soil quality on agriculture residue and energy crop pathways

    SciTech Connect (OSTI)

    Ian Bonner; David Muth

    2013-09-01

    There are three objectives for this project: 1) support OBP in meeting MYPP stated performance goals for the Sustainability Platform, 2) develop integrated feedstock production system designs that increase total productivity of the land, decrease delivered feedstock cost to the conversion facilities, and increase environmental performance of the production system, and 3) deliver to the bioenergy community robust datasets and flexible analysis tools for establishing sustainable and viable use of agricultural residues and dedicated energy crops. The key project outcome to date has been the development and deployment of a sustainable agricultural residue removal decision support framework. The modeling framework has been used to produce a revised national assessment of sustainable residue removal potential. The national assessment datasets are being used to update national resource assessment supply curves using POLYSIS. The residue removal modeling framework has also been enhanced to support high fidelity sub-field scale sustainable removal analyses. The framework has been deployed through a web application and a mobile application. The mobile application is being used extensively in the field with industry, research, and USDA NRCS partners to support and validate sustainable residue removal decisions. The results detailed in this report have set targets for increasing soil sustainability by focusing on primary soil quality indicators (total organic carbon and erosion) in two agricultural residue management pathways and a dedicated energy crop pathway. The two residue pathway targets were set to, 1) increase residue removal by 50% while maintaining soil quality, and 2) increase soil quality by 5% as measured by Soil Management Assessment Framework indicators. The energy crop pathway was set to increase soil quality by 10% using these same indicators. To demonstrate the feasibility and impact of each of these targets, seven case studies spanning the US are presented. The analysis has shown that the feedstock production systems are capable of simultaneously increasing productivity and soil sustainability.

  4. Japan's Residential Energy Demand Outlook to 2030 Considering Energy Efficiency Standards "Top-Runner Approach"

    E-Print Network [OSTI]

    Komiyama, Ryoichi

    2008-01-01

    water heater, Gas water heater, LPG water heater Hot WaterCooling Space Heating Coal LPG Kerosene Projection * “Mtoe”Renewable Gas Kerosene LPG Coal LPG Electricity Coal

  5. All auto shredding: evaluation of automotive shredder residue generated by shredding only vehicles.

    SciTech Connect (OSTI)

    Duranceau, C. M.; Spangenberger, J. S.

    2011-09-26

    A well developed infrastructure exists for the reuse and recycling of automotive parts and materials. At the end of a vehicle's useful life many parts are removed and sold for reuse and fluids are recovered for recycling or proper disposal. What remains is shredded, along with other metal bearing scrap such as home appliances, demolition debris and process equipment, and the metals are separated out and recycled. The remainder of the vehicle materials is call shredder residue which ends up in the landfill. As energy and natural resources becomes more treasured, increased effort has been afforded to find ways to reduce energy consumption and minimize the use of our limited resources. Many of the materials found in shredder residue could be recovered and help offset the use of energy and material consumption. For example, the energy content of the plastics and rubbers currently landfilled with the shredder residue is equivalent to 16 million barrels of oil per year. However, in the United States, the recovered materials, primarily polymers, cannot be recycled due to current regulatory barriers which preclude the re-introduction into commerce of certain materials because of residual contamination with substances of concern (SOCs) such as polychlorinated biphenyls (PCBs). The source of the PCBs is not well understood. Old transformers, capacitors, white goods and ballasts from lighting fixtures are likely contributing factors. The project was designed to evaluate whether vehicles of varying age and manufacturing origin contribute to the PCB content in shredder residue. Additionally, the project was designed to determine if there are any trends in material composition of the shredder residue from varied age and manufacturing groups. This information would aid in future material recovery facility strategy and design. The test utilized a newly installed shredder plant to shred four categories of automobiles. The categories were defined by vehicle age and the manufacturing company and location. Each category of vehicles was processed individually through the shredder plant and the resulting shredder residue was analyzed for its materials composition and presence of PCBs and leachable metals. The results show that shredder residue from all vehicle categories tested are not significant contributors of PCBs and leachable metals. It was evident that leachable cadmium levels have decreased in newer vehicles. The composition of the shredder residue from each of the four categories is similar to the others. In addition, these compositions are approximately equal to the composition of typical shredder residues, not limited to automotive materials.

  6. Gyrokinetic simulation of momentum transport with residual stress from diamagnetic level velocity shears

    SciTech Connect (OSTI)

    Waltz, R. E.; Staebler, G. M.; Solomon, W. M.

    2011-04-15

    Residual stress refers to the remaining toroidal angular momentum (TAM) flux (divided by major radius) when the shear in the equilibrium fluid toroidal velocity (and the velocity itself) vanishes. Previously [Waltz et al., Phys. Plasmas 14, 122507 (2007); errata 16, 079902 (2009)], we demonstrated with GYRO [Candy and Waltz, J. Comp. Phys. 186, 545 (2003)] gyrokinetic simulations that TAM pinching from (ion pressure gradient supported or diamagnetic level) equilibrium ExB velocity shear could provide some of the residual stress needed to support spontaneous toroidal rotation against normal diffusive loss. Here we show that diamagnetic level shear in the intrinsic drift wave velocities (or ''profile shear'' in the ion and electron density and temperature gradients) provides a comparable residual stress. The individual signed contributions of these small (rho-star level) ExB and profile velocity shear rates to the turbulence level and (rho-star squared) ion energy transport stabilization are additive if the rates are of the same sign. However because of the additive stabilization effect, the contributions to the small (rho-star cubed) residual stress is not always simply additive. If the rates differ in sign, the residual stress from one can buck out that from the other (and in some cases reduce the stabilization.) The residual stress from these diamagnetic velocity shear rates is quantified by the ratio of TAM flow to ion energy (power) flow (M/P) in a global GYRO core simulation of a ''null'' toroidal rotation DIII-D [Mahdavi and Luxon, Fusion Sci. Technol. 48, 2 (2005)] discharge by matching M/P profiles within experimental uncertainty. Comparison of global GYRO (ion and electron energy as well as particle) transport flow balance simulations of TAM transport flow in a high-rotation DIII-D L-mode quantifies and isolates the ExB shear and parallel velocity (Coriolis force) pinching components from the larger ''diffusive'' parallel velocity shear driven component and the much smaller profile shear residual stress component.

  7. Stabilization of Rocky Flats combustible residues contaminated with plutonium metal and organic solvents

    SciTech Connect (OSTI)

    Bowen, S.M.; Cisneros, M.R.; Jacobson, L.L.; Schroeder, N.C.; Ames, R.L.

    1998-09-30

    This report describes tests on a proposed flowsheet designed to stabilize combustible residues that were generated at the Rocky Flats Environmental Technology Site (RFETS) during the machining of plutonium metal. Combustible residues are essentially laboratory trash contaminated with halogenated organic solvents and plutonium metal. The proposed flowsheet, designed by RFETS, follows a glovebox procedure that includes (1) the sorting and shredding of materials, (2) a low temperature thermal desorption of solvents from the combustible materials, (3) an oxidation of plutonium metal with steam, and (4) packaging of the stabilized residues. The role of Los Alamos National Laboratory (LANL) in this study was to determine parameters for the low temperature thermal desorption and steam oxidation steps. Thermal desorption of carbon tetrachloride (CCl{sub 4}) was examined using a heated air stream on a Rocky Flats combustible residue surrogate contaminated with CCl{sub 4}. Three types of plutonium metal were oxidized with steam in a LANL glovebox to determine the effectiveness of this procedure for residue stabilization. The results from these LANL experiments are used to recommend parameters for the proposed RFETS stabilization flowsheet.

  8. Summary of the engineering assessment of radioactive sands and residues, Lowman Site, Lowman, Idaho

    SciTech Connect (OSTI)

    none,

    1981-09-01

    Ford, Bacon and Davis Utah Inc. has reevaluated the Lowman site in order to revise the December 1977 engineering assessment of the problems resulting from the existence of radioactive sands and residues at Lowman, Idaho. This engineering assessment has included the preparation of topographic maps, the performance of core drillings and radiometric measurements sufficient to determine areas and volumes of radioactive sands and residues and radiation exposures of individuals and nearby populations, the investigations of site hydrology and meteorology, and the evaluation and costing of alternative corrective actions. Radon gas released from the 191,000 tons of radioactive sands, residues, and contaminated soils at the Lowman site constitutes the most significant environmental impact, although windblown radioactive sands and external gamma radiation also are factors.

  9. Recovery of Plutonium from Refractory Residues Using a Sodium Peroxide Pretreatment Process

    SciTech Connect (OSTI)

    Rudisill, T.S.

    2003-10-23

    The recycle of plutonium from refractory residues is a necessary activity for the nuclear weapon production complex. Traditionally, high-fired plutonium oxide (PuO2) was leached from the residue matrix using a nitric acid/fluoride dissolving flowsheet. The recovery operations were time consuming and often required multiple contacts with fresh dissolving solution to reduce the plutonium concentration to levels where residual solids could be discarded. Due to these drawbacks, the development of an efficient process for the recovery of plutonium from refractory materials is desirable. To address this need, a pretreatment process was developed. The development program utilized a series of small-scale experiments to optimize processing conditions for the fusion process and demonstrate the plutonium recovery efficiency using ceramic materials developed as potential long-term storage forms for PuO2 and an incinerator ash from the Rocky Flats Environmental Technology Site (Rocky Flats) as te st materials.

  10. Diagnosing residual motion via the x-ray self emission from indirectly driven inertial confinement implosions

    SciTech Connect (OSTI)

    Pak, A., E-mail: pak5@llnl.gov; Field, J. E.; Benedetti, L. R.; Caggiano, J.; Hatarik, R.; Izumi, N.; Khan, S. F.; Ma, T.; Spears, B. K.; Town, R. P. J.; Bradley, D. K. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Knauer, J. [Laboratory for Laser Energetics, Rochester, New York 14623 (United States)

    2014-11-15

    In an indirectly driven implosion, non-radial translational motion of the compressed fusion capsule is a signature of residual kinetic energy not coupled into the compressional heating of the target. A reduction in compression reduces the peak pressure and nuclear performance of the implosion. Measuring and reducing the residual motion of the implosion is therefore necessary to improve performance and isolate other effects that degrade performance. Using the gated x-ray diagnostic, the x-ray Bremsstrahlung emission from the compressed capsule is spatially and temporally resolved at x-ray energies of >8.7 keV, allowing for measurements of the residual velocity. Here details of the x-ray velocity measurement and fitting routine will be discussed and measurements will be compared to the velocities inferred from the neutron time of flight detectors.

  11. The National Nuclear Laboratory's Approach to Processing Mixed Wastes and Residues - 13080

    SciTech Connect (OSTI)

    Greenwood, Howard; Docrat, Tahera; Allinson, Sarah J.; Coppersthwaite, Duncan P.; Sultan, Ruqayyah; May, Sarah [National Nuclear Laboratory, Springfields, Preston, UK, PR4 0XJ (United Kingdom)] [National Nuclear Laboratory, Springfields, Preston, UK, PR4 0XJ (United Kingdom)

    2013-07-01

    The National Nuclear Laboratory (NNL) treats a wide variety of materials produced as by-products of the nuclear fuel cycle, mostly from uranium purification and fuel manufacture but also including materials from uranium enrichment and from the decommissioning of obsolete plants. In the context of this paper, treatment is defined as recovery of uranium or other activity from residues, the recycle of uranium to the fuel cycle or preparation for long term storage and the final disposal or discharge to the environment of the remainder of the material. NNL's systematic but flexible approach to residue assessment and treatment is described in this paper. The approach typically comprises up to five main phases. The benefits of a systematic approach to waste and residue assessments and processing are described in this paper with examples used to illustrate each phase of work. Benefits include early identification of processing routes or processing issues and the avoidance of investment in inappropriate and costly plant or processes. (authors)

  12. INTERFACE RESIDUAL STRESSES IN DENTAL ZIRCONIA USING LAUE MICRO-DIFFRACTION

    SciTech Connect (OSTI)

    Bale, H. A.; Tamura, N.; Coelho, P.G.; Hanan, J. C.

    2009-01-01

    Due to their aesthetic value and high compressive strength, dentists have recently employed ceramics for restoration materials. Among the ceramic materials, zirconia provides high toughness and crack resistant characteristics. Residual stresses develop in processing due to factors including grain anisotropy and thermal coefficient mismatch. In the present study, polychromatic X-ray (Laue) micro-diffraction provided grain orientation and residual stresses on a clinically relevant zirconia model ceramic disk. A 0.5 mm x 0.024 mm region on zirconia was examined on a 500 nm scale for residual stresses using a focused poly-chromatic synchrotron X-ray beam. Large stresses ranging from - to + 1GPa were observed at some grains. On average, the method suggests a relatively small compressive stress at the surface between 47 and 75 MPa depending on direction.

  13. Method for using global optimization to the estimation of surface-consistent residual statics

    DOE Patents [OSTI]

    Reister, David B. (Knoxville, TN); Barhen, Jacob (Oak Ridge, TN); Oblow, Edward M. (Knoxville, TN)

    2001-01-01

    An efficient method for generating residual statics corrections to compensate for surface-consistent static time shifts in stacked seismic traces. The method includes a step of framing the residual static corrections as a global optimization problem in a parameter space. The method also includes decoupling the global optimization problem involving all seismic traces into several one-dimensional problems. The method further utilizes a Stochastic Pijavskij Tunneling search to eliminate regions in the parameter space where a global minimum is unlikely to exist so that the global minimum may be quickly discovered. The method finds the residual statics corrections by maximizing the total stack power. The stack power is a measure of seismic energy transferred from energy sources to receivers.

  14. Use of Residual Solids from Pulp and Paper Mills for Enhancing Strength and Durability of Ready-Mixed Concrete

    SciTech Connect (OSTI)

    Tarun R. Naik; Yoon-moon Chun; Rudolph N. Kraus

    2003-09-18

    This research was conducted to establish mixture proportioning and production technologies for ready-mixed concrete containing pulp and paper mill residual solids and to study technical, economical, and performance benefits of using the residual solids in the concrete. Fibrous residuals generated from pulp and paper mills were used, and concrete mixture proportions and productions technologies were first optimized under controlled laboratory conditions. Based on the mixture proportions established in the laboratory, prototype field concrete mixtures were manufactured at a ready-mixed concrete plant. Afterward, a field construction demonstration was held to demonstrate the production and placement of structural-grade cold-weather-resistant concrete containing residual solids.

  15. A Macro-perspective of Forest and Residuals Resources and Availability in the U.S. South

    E-Print Network [OSTI]

    A Macro-perspective of Forest and Residuals Resources and Availability in the U.S. South Prepared.................................................................................................................19 Alabama Wood Biomass Availability....

  16. Apparatus and method for rapid detection of explosives residue from the deflagration signature thereof

    DOE Patents [OSTI]

    Funsten, Herbert O. (Los Alamos, NM); McComas, David J. (Los Alamos, NM)

    1997-01-01

    Apparatus and method for rapid detection of explosives residue from the deflagration signature thereof. A property inherent to most explosives is their stickiness, resulting in a strong tendency of explosive particulate to contaminate the environment of a bulk explosive. An apparatus for collection of residue particulate, burning the collected particulate, and measurement of the optical emission produced thereby is described. The present invention can be utilized for real-time screening of personnel, cars, packages, suspected devices, etc., and provides an inexpensive, portable, and noninvasive means for detecting explosives.

  17. Apparatus and method for rapid detection of explosives residue from the deflagration signature thereof

    DOE Patents [OSTI]

    Funsten, H.O.; McComas, D.J.

    1999-06-15

    Apparatus and method are disclosed for rapid detection of explosives residue from the deflagration signature thereof. A property inherent to most explosives is their stickiness, resulting in a strong tendency of explosive particulate to contaminate the environment of a bulk explosive. An apparatus for collection of residue particulate, burning the collected particulate, and measurement of the ultraviolet emission produced thereby, is described. The present invention can be utilized for real-time screening of personnel, cars, packages, suspected devices, etc., and provides an inexpensive, portable, and noninvasive means for detecting explosives. 4 figs.

  18. Apparatus and method for rapid detection of explosives residue from the deflagration signature thereof

    DOE Patents [OSTI]

    Funsten, Herbert O. (Los Alamos, NM); McComas, David J. (Los Alamos, NM)

    1999-01-01

    Apparatus and method for rapid detection of explosives residue from the deflagration signature thereof. A property inherent to most explosives is their stickiness, resulting in a strong tendency of explosive particulate to contaminate the environment of a bulk explosive. An apparatus for collection of residue particulate, burning the collected particulate, and measurement of the ultraviolet emission produced thereby, is described. The present invention can be utilized for real-time screening of personnel, cars, packages, suspected devices, etc., and provides an inexpensive, portable, and noninvasive means for detecting explosives.

  19. An active carbon catalyst prevents coke formation from asphaltenes during the hydrocracking of vacuum residue

    SciTech Connect (OSTI)

    Fukuyama, H.; Terai, S. [Toyo Engineering Corp., Chiba (Japan). Technological Research Center

    2007-07-01

    Active carbons were prepared by the steam activation of a brown coal char. The active carbon with mesopores showed greater adsorption selectivity for asphaltenes. The active carbon was effective at suppressing coke formation, even with the high hydrocracking conversion of vacuum residue. The analysis of the change in the composition of saturates, aromatics, resins, and asphaltenes in the cracked residue with conversion demonstrated the ability of active carbon to restrict the transformation of asphaltenes to coke. The active carbon that was richer in mesopores was presumably more effective at providing adsorption sites for the hydrocarbon free-radicals generated initially during thermal cracking to prevent them from coupling and polycondensing.

  20. Sequence composition and environment effects on residue fluctuations in protein structures

    E-Print Network [OSTI]

    Ruvinsky, Anatoly M.; Vakser, Ilya A.

    2010-10-15

    . Figure 5 illustrates high stability #2;gray surface#3; of a binding groove in the porcine pancreatic #2;-amylase. The groove contains three catalytic residues Asp197, Glu233, and Asp300, which showed low mobility ratios. The binding site is surrounded... pancreatic #2;-amylase in complex with the microbial inhibitor Tendamistat #2;blue#3; #2;Ref. 88#3;. Highly fluctuating #2;R 1#3;, moderately fluctuating #2;R=0.7–1.0#3; and weakly fluctuating #2;R#12;0.7#3; residues of the hydrolase are in red, pink...

  1. Fast bias inversion of a double well without residual particle excitation

    E-Print Network [OSTI]

    S. Martínez-Garaot; M. Palmero; D. Guéry-Odelin; J. G. Muga

    2015-07-14

    We design fast bias inversions of an asymmetric double well so that the lowest states in each well remain so and free from residual motional excitation. This cannot be done adiabatically, and a sudden bias switch produces in general motional excitation. The residual excitation is suppressed by complementing a predetermined fast bias change with a linear ramp whose time-dependent slope compensates for the displacement of the wells. The process, combined with vibrational multiplexing and demultiplexing, can produce vibrational state inversion without exciting internal states, just by deforming the trap.

  2. The investigation of the effects of wettability on residual oil after water flooding 

    E-Print Network [OSTI]

    Burja, Edward Oscar

    1953-01-01

    THE INVESTIGATION OF THE EFFECTS OF WETTABILITY ON RESIDUAL OIL AFTER WATER FLOODING A Thesis BY E. 0, BUR JA Approved as to style and content by: (Cha rman of C mmittee (Head of Department) (Mo th (Year) THE INVESTIGATION OF THE EFFECTS... OF WETTABILITY ON RESIDUAL OIL AFTER WATER FLOODING By E. O. Burja A Thesis Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Major Subject...

  3. Cracking in liquid petroleum gas Horton spheres

    SciTech Connect (OSTI)

    Trivedi, D.K. Gupta, S.C.

    1997-07-01

    A gas processing plant on the western coast of India produces sweet gas after processing sour natural gas. Liquid petroleum gas (LPG) is recovered from the sweet gas. The LPG, containing a H{sub 2}S concentration of 10 ppm to 20 ppm, is stored in Horton spheres, each 17 m in diameter with a capacity of {minus}27 C to 55 C. Horton spheres for containing liquid petroleum gas (LPG) were fabricated on-site using prestressed plates of high-strength carbon steel (CS) SA 537 Class-1 with post-weld heat treatment. High-residual tensile stresses and hydrogen absorption from H{sub 2}S present in LPG could be the cause of cracking at weld and heat-affected zone interfaces at high hardness locations. Recommendations are given for inspection and use of lower-strength CS and improved welding procedures.

  4. The effect of residuals on the presence of intergranular surface cracks on continuously cast billets

    SciTech Connect (OSTI)

    Wijngaarden, M.J.U.T. van; Visagie, G.P.

    1996-12-31

    During 1991, Iscor Vereeniging experienced a dramatic increase in the rejection rate of specialty steel bars rolled from continuously cast billets due to the presence of seams on the bars. The seams originated from tearing of the billets during the first 2 passes in the roughing mill during hot rolling. The defective billets were found to contain fine intergranular cracks on the surface. Such cracks have been described in the literature and have been attributed to the presence of high levels of residuals resulting in the well-known phenomenon of surface hot shortness which results from the enrichment of residuals at the grain boundaries after preferential oxidation of iron during scaling of the steel. The present investigation revealed that the effect of residuals on intergranular surface cracking is a complex interaction between steel composition and casting conditions such as casting speed, intensity of secondary cooling, section size, and mold type. This paper quantifies the effect of residuals on the intergranular surface cracking of continuously cast billets and quantitatively relates the incidence of these cracks to parameters which can be controlled during steelmaking and continuous casting.

  5. Residual BoseEinstein Correlations in Inclusive + \\Gamma Systems and the ae(770) 0 Line

    E-Print Network [OSTI]

    Residual Bose­Einstein Correlations in Inclusive ß + ß \\Gamma Systems and the ae(770) 0 Line Shape of multihadronic Z 0 decay, Bose­Einstein correlations acting between identical pions may have significant indirect on experimental studies of Bose­Einstein correlations, particularly with regard to the use of ß + ß \\Gamma

  6. Residual Stress and Microstructure of Electroplated Cu Film on Different Barrier Layers Alex A. Volinsky1

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Residual Stress and Microstructure of Electroplated Cu Film on Different Barrier Layers Alex A.2 and 2 microns were electroplated on adhesion-promoting TiW and Ta barrier layers on single crystal from a leading semiconductor manufacturer such as Motorola that contains electroplated Cu interconnects

  7. Salivary influences upon levels of certain chemical constituents in forage residues collected from esophageally cannulated sheep 

    E-Print Network [OSTI]

    Radde, Kenneth Albert

    1967-01-01

    - hydrate content of the offered fo. ames PercentaSe incre, e in ash exnressed on a dry matter basis 24 +- CVG x 100 ? Level of water soluble carbohydrates in foraGe residues relative to calculated level of inc:ested w. . ter soluble carbohydrates...

  8. Acrinathrin, effective varroacide and its residues in stores, honey and wax

    E-Print Network [OSTI]

    Boyer, Edmond

    Acrinathrin, effective varroacide and its residues in stores, honey and wax Synthetic pyrethroids in honey, stores and wax. Honey and stores were extracted by hexane, wax was dissolved in acetonitrile quantity of acrinathrin into the untreated honey and wax. After 25 d exposure of the preparation

  9. ORGANOCHLORINE RESIDUES IN FISHES FROM THE NORTHWEST ATLANTIC OCEAN AND GULF OF MEXICO

    E-Print Network [OSTI]

    southeastern United States. Species with lowest oil content «3%)-gag, Mycteroperca microlepis; black grouper, M amounts of chlorinated hydrocarbon residues. Species with higher oil content- king mackerel, Scomberomorus chemical, DDT, became the magic tool of the medical profession, deeply concerned with preventing outbreaks

  10. 2006-01-3276 Residual Gas Fraction Measurement and Estimation on a

    E-Print Network [OSTI]

    Cambridge, University of

    and in combination with CO2 concentration measurements in the exhaust stroke, cyclic Residual Gas Fraction was employed to obtain cyclic dynamic measurements of CO2 concentration in the compression stroke measurement involves comparing the content in HC or CO2 between the exhaust gas and the fresh charge

  11. SOLID PHASE MICROEXTRACTION SAMPLING OF FIRE DEBRIS RESIDUES IN THE PRESENCE OF RADIONUCLIDE SURROGATE METALS

    SciTech Connect (OSTI)

    Duff, M; Keisha Martin, K; S Crump, S

    2007-03-23

    The Federal Bureau of Investigation (FBI) Laboratory currently does not have on site facilities for handling radioactive evidentiary materials and there are no established FBI methods or procedures for decontaminating highly radioactive fire debris (FD) evidence while maintaining evidentiary value. One experimental method for the isolation of FD residue from radionuclide metals involves using solid phase microextraction (SPME) fibers to remove the residues of interest. Due to their high affinity for organics, SPME fibers should have little affinity for most (radioactive) metals. The focus of this research was to develop an examination protocol that was applicable to safe work in facilities where high radiation doses are shielded from the workers (as in radioactive shielded cells or ''hot cells''). We also examined the affinity of stable radionuclide surrogate metals (Co, Ir, Re, Ni, Ba, Cs, Nb, Zr and Nd) for sorption by the SPME fibers. This was done under exposure conditions that favor the uptake of FD residues under conditions that will provide little contact between the SPME and the FD material (such as charred carpet or wood that contains commonly-used accelerants). Our results from mass spectrometric analyses indicate that SPME fibers show promise for use in the room temperature head space uptake of organic FD residue (namely, diesel fuel oil, kerosene, gasoline and paint thinner) with subsequent analysis by gas chromatography (GC) with mass spectrometric (MS) detection. No inorganic forms of ignitable fluids were included in this study.

  12. CO2 Sequestration in Chrysotile Mining ResiduesImplication of Watering and Passivation under Environmental Conditions

    E-Print Network [OSTI]

    , Canada G1V 0A6 ABSTRACT: Factors affecting carbon dioxide fixation in chrysotile mining residues (CMR of carbon dioxide as stable solid carbonates by reacting it with magnesium silicates is one among several carbonation reactors for the capture of CO2 produced at its source.5-8 In most available direct carbonation

  13. Determination of residual monomers resulting from the chemical polymerization process of dental materials

    SciTech Connect (OSTI)

    Boboia, S.; Moldovan, M.; Ardelean, I.

    2013-11-13

    The residual monomer present in post-polymerized dental materials encourages premature degradation of the reconstructed tooth. That is why the residual monomer should be quantified in a simple, fast, accurate and reproducible manner. In our work we propose such an approach for accurate determination of the residual monomer in dental materials which is based on low-field nuclear magnetic resonance (NMR) relaxometry. The results of the NMR approach are compared with those of the high performance liquid chromatography (HPLC) technique. The samples under study contain the main monomers (2,2-bis[4-(2-hydroxy-3-methacryloyloxypropoxy)phenyl]propane and triethylene glycol dimethacrylate) constituting the liquid phase of most dental materials and an initiator. Two samples were analyzed with different ratios of chemical initiation systems: N,N-dimethyl-p-toluide: benzoyl peroxide (1:2 and 0.7:1.2). The results obtained by both techniques highlight that by reducing the initiator the polymerization process slows down and the amount of residual monomer reduces. This prevents the premature degradation of the dental fillings and consequently the reduction of the biomaterial resistance.

  14. RESIDUAL PREDICTION BASED ON UNIT SELECTION David Sundermann1,2

    E-Print Network [OSTI]

    Suendermann, David

    RESIDUAL PREDICTION BASED ON UNIT SELECTION David S¨undermann1,2 , Harald H¨oge1 , Antonio tech- niques that can be applied to voice conversion based on lin- ear transformation or hidden Markov model-based speech synthesis. Our voice conversion experiments showed that none of the six compared

  15. LONG TERM RESIDUAL EFFECTS OF A NUTRIENT ADDITION ON A BARRIER ISLAND DUNE ECOSYSTEM

    E-Print Network [OSTI]

    Lawrence, Deborah

    LONG TERM RESIDUAL EFFECTS OF A NUTRIENT ADDITION ON A BARRIER ISLAND DUNE ECOSYSTEM by Susan M EFFECTS OF A NUTRIENT ADDITION ON A BARRIER ISLAND DUNE ECOSYSTEM Susan M. Heyel Old Dominion University, 2000 Director: Dr. Frank P. Day In 1991, 150 m2 were fertilized with nitrogen on three dunes on Hog

  16. From residue matching patterns to protein folding topographies: General model and bovine

    E-Print Network [OSTI]

    Berry, R. Stephen

    From residue matching patterns to protein folding topographies: General model and bovine pancreatic-grained model for protein-folding dynamics is introduced based on a discretized representation of torsional, pattern recognition, and general characteristics of protein folding kinetics. Topology here implies

  17. Nuclear reactor with makeup water assist from residual heat removal system

    DOE Patents [OSTI]

    Corletti, Michael M. (New Kensington, PA); Schulz, Terry L. (Murrysville, PA)

    1993-01-01

    A pressurized water nuclear reactor uses its residual heat removal system to make up water in the reactor coolant circuit from an in-containment refueling water supply during staged depressurization leading up to passive emergency cooling by gravity feed from the refueling water storage tank, and flooding of the containment building. When depressurization commences due to inadvertence or a manageable leak, the residual heat removal system is activated manually and prevents flooding of the containment when such action is not necessary. Operation of the passive cooling system is not impaired. A high pressure makeup water storage tank is coupled to the reactor coolant circuit, holding makeup coolant at the operational pressure of the reactor. The staged depressurization system vents the coolant circuit to the containment, thus reducing the supply of makeup coolant. The level of makeup coolant can be sensed to trigger opening of successive depressurization conduits. The residual heat removal pumps move water from the refueling water storage tank into the coolant circuit as the coolant circuit is depressurized, preventing reaching the final depressurization stage unless the makeup coolant level continues to drop. The residual heat removal system can also be coupled in a loop with the refueling water supply tank, for an auxiliary heat removal path.

  18. Analysis of the Functional Role of Conserved Residues in the Protein Subunit of Ribonuclease P

    E-Print Network [OSTI]

    Gopalan, Venkat

    National Library of Medicine National Institutes of Health Room 8N-805, Building 38A Bethesda, MD 20894Analysis of the Functional Role of Conserved Residues in the Protein Subunit of Ribonuclease P from of Biology, Yale University, New Haven, CT 06520-8103, USA 2 National Center for Biotechnology Information

  19. The nuclear density of states and the role of the residual interaction

    E-Print Network [OSTI]

    Calvin W. Johnson; Edgar Teran

    2005-12-02

    We discuss the role of mean-field and moment methods in microscopic models for calculating the nuclear density of states (also known as the nuclear level density). Working in a shell-model framework, we use moments of the nuclear many-body Hamiltonian to illustrate the importance of the residual interaction for accurate representations.

  20. Influence of Solvent Molecules on the Stereochemical Code of Glycyl Residues in Proteins

    E-Print Network [OSTI]

    Srinivasan, N.

    Influence of Solvent Molecules on the Stereochemical Code of Glycyl Residues in Proteins Narayanan- tions are shown to have highest solvent accessibility in a system of two-linked peptide units high solvent accessibility. Analysis of a subset of nonhomologous structures with very high resolu

  1. ECOTOXICOLOGICAL IMPLICATIONS OF AQUATIC DISPOSAL OF COAL COMBUSTION RESIDUES IN THE UNITED STATES

    E-Print Network [OSTI]

    Hopkins, William A.

    environmental effects. A large number of metals and trace elements are present in CCR, some of which are rapidly known to be associated with this element. However, the complex mixture of metals and trace elementsECOTOXICOLOGICAL IMPLICATIONS OF AQUATIC DISPOSAL OF COAL COMBUSTION RESIDUES IN THE UNITED STATES

  2. Investigation of residual stresses induced during the selective laser melting process

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    jean-claude.boyer@insa-lyon.fr Keywords: Selective laser melting, layer additional method, Residual stresses. Abstract. The selective laser melting process (SLM), belonging to the family of additive manufacturing processes, can create complex geometry parts from a CAD file. Previously, only prototypes were

  3. Engineered Heart Tissue Enables Study of Residual Undifferentiated Embryonic Stem Cell Activity in a

    E-Print Network [OSTI]

    Zandstra, Peter W.

    ARTICLE Engineered Heart Tissue Enables Study of Residual Undifferentiated Embryonic Stem Cell, Canada, M5S 3G9 6 Heart and Stroke/Richard Lewar Centre of Excellence, Toronto, Ontario, Canada, M5S 3G9 cell survival. As an alternative, we have used an engineered heart tissue (EHT) based on neonatal rat

  4. Abundant and Stable Char Residues in Soils: Implications for Soil Fertility and Carbon Sequestration

    E-Print Network [OSTI]

    Lehmann, Johannes

    Abundant and Stable Char Residues in Soils: Implications for Soil Fertility and Carbon Department of Chemistry, Iowa State University, Ames, Iowa 50011, United States § Department of Crop and Soil, Ames, Iowa 50011, United States *S Supporting Information ABSTRACT: Large-scale soil application

  5. Residue Number System Operands to Decimal Conversion for 3-Moduli Sets

    E-Print Network [OSTI]

    Cotofana, Sorin

    Number System (RNS) operands to decimal. First we assume a general {mi}i=1,3 moduli set with the dynamic with a Common factor, RNS-Decimal Converter, Chinese Remainder Theorem. I. INTRODUCTION Carry propagation systems, e.g., (redundant) signed digit systems, Residue Number Systems (RNS) have been proposed. RNS has

  6. Development of source functions for modeling dissolution of residual DNAPL fingers in the saturated zone 

    E-Print Network [OSTI]

    Johnson, Brian Scott

    1993-01-01

    fmger in the saturated zone. Modeling dissolution from a residual fmger can be approached in one of two ways: as an equilibrium process or as a rate dependent kinetic process. Development of a source term for modeling the dissolution from remediation...

  7. PROTEIN FOLD RECOGNITION USING RESIDUE-BASED ALIGNMENTS OF SEQUENCE AND SECONDARY STRUCTURE

    E-Print Network [OSTI]

    Erdogan, Hakan

    PROTEIN FOLD RECOGNITION USING RESIDUE-BASED ALIGNMENTS OF SEQUENCE AND SECONDARY STRUCTURE Zafer methods [3,4]. Index Terms- protein fold recognition, secondary structure alignment, amino acid alignment- ture. Protein threading or fold recognition refers to a class of compu- tational methods for predicting

  8. Ito-Wiener chaos expansion with exact residual and correlation, variance inequalities

    E-Print Network [OSTI]

    Hu, Yaozhong

    1997-10-01

    We give a formula of expanding the solution of a stochastic differential equation (abbreviated as SDE) into a finite Ito-Wiener chaos with explicit residual. And then we apply this formula to obtain several inequalities for diffusions such as FKG...

  9. Identification of Residual Stress State in an RF-MEMS Device

    E-Print Network [OSTI]

    Espinosa, Horacio D.

    Identification of Residual Stress State in an RF-MEMS Device l Horacio D. Espinosa, M. Fischer Dept Microelectromechanical Systems (MEMS) are among the most significant technological advances of this decade. The objective is of a few nanometers. The study of "thin films" and "ultra thin films" employed in MEMS devices is being

  10. Energy distribution and flux of fast neutrals and residual ions extracted from a neutral beam source

    E-Print Network [OSTI]

    Economou, Demetre J.

    Energy distribution and flux of fast neutrals and residual ions extracted from a neutral beam-4004 Received 21 April 2006; accepted 6 July 2006; published 7 August 2006 The energy distribution and flux into fast neutrals. The neutral energy distribution was always shifted to lower energies compared

  11. Nuclear reactor with makeup water assist from residual heat removal system

    DOE Patents [OSTI]

    Corletti, M.M.; Schulz, T.L.

    1993-12-07

    A pressurized water nuclear reactor uses its residual heat removal system to make up water in the reactor coolant circuit from an in-containment refueling water supply during staged depressurization leading up to passive emergency cooling by gravity feed from the refueling water storage tank, and flooding of the containment building. When depressurization commences due to inadvertence or a manageable leak, the residual heat removal system is activated manually and prevents flooding of the containment when such action is not necessary. Operation of the passive cooling system is not impaired. A high pressure makeup water storage tank is coupled to the reactor coolant circuit, holding makeup coolant at the operational pressure of the reactor. The staged depressurization system vents the coolant circuit to the containment, thus reducing the supply of makeup coolant. The level of makeup coolant can be sensed to trigger opening of successive depressurization conduits. The residual heat removal pumps move water from the refueling water storage tank into the coolant circuit as the coolant circuit is depressurized, preventing reaching the final depressurization stage unless the makeup coolant level continues to drop. The residual heat removal system can also be coupled in a loop with the refueling water supply tank, for an auxiliary heat removal path. 2 figures.

  12. The fate of residual treatment water in gas shale Terry Engelder a,

    E-Print Network [OSTI]

    Engelder, Terry

    The fate of residual treatment water in gas shale Terry Engelder a, , Lawrence M. Cathles b , L Marcellus Gas shale Osmosis-diffusion a b s t r a c t More than 2 Â 104 m3 of water containing additives is commonly injected into a typical horizontal well in gas shale to open fractures and allow gas recovery

  13. A three-phase cylinder model for residual and transformational stresses in SMA composites

    SciTech Connect (OSTI)

    Berman, J.B.; White, S.R. [Univ. of Illinois, Urbana, IL (United States). Dept. of Aeronautical and Astronautical Engineering

    1994-12-31

    SMA composites are a class of smart materials in which shape memory alloy (SMA) actuators are embedded in a polymer matrix composite. The difference in thermal expansion between the SMA and the host material leads to residual stresses during processing. Similarly, the SMA transformations from martensite to austenite, or the reverse, also generate stresses. These stresses acting in combination can lead to SMA/epoxy interfacial debonding. In this study the residual and transformational stresses are investigated for an SMA wire embedded in a graphite/epoxy composite. A three phase micromechanical model is developed. The SMA wire is assumed to behave as a thermoelastic material. Nitinol{trademark} SMA austenitic and martensitic transformations are modeled using linear piecewise interpolation of the experimental data. The interphase is modeled as a thermoelastic polymer. A transversely isotropic thermoelastic composite is used for the outer phase. Stress-free conditions are assumed immediately before cool down from the cure temperature. The effect of SMA and coating properties on residual and transformational stresses are evaluated. A decrease in stresses at the composite/coating interface is predicted through the use of thick, compliant coatings. Reducing the recovery strain and moving the transformation to higher temperatures are also effective in reducing residual stresses.

  14. Incineration of residue from paint stripping operations using plastic media blasting

    SciTech Connect (OSTI)

    Helt, J.E.; Mallya, N.

    1988-01-01

    A preliminary investigation has been performed on the environmental consequences of incinerating plastic-media-blasting (PMB) wastes from plant removal operations. PMB is similar to sandblasting although blasting taken place at a much lower pressure. The blasted media can be recovered and recycled several times, but ultimately a residue of paint dust/chips and attrited media dust are left for disposal. This residue is a dry solid that may potentially be classified as a hazardous waste. One possible alternative to depositing the waste residue directly into a hazardous waste landfill is incineration. Incineration would provide desirable volume reduction. However, the fate of heavy metals from the entrained paint waste is not known. Samples of PMB residue were combusted at temperatures between 690/degree/C and 815/degree/C with approximately 125% of the stoichiometric air. The ash remaining after combustion was then analyzed for heavy metal content and tested for leachability using the EPA toxicity characteristics leaching procedures (TCLP). 6 refs., 7 tabs.

  15. A model for aging under deformation field, residual stresses and strains in soft glassy materials

    E-Print Network [OSTI]

    Joshi, Yogesh Moreshwar

    A model for aging under deformation field, residual stresses and strains in soft glassy materials Yogesh M. Joshi* A model is proposed that considers aging and rejuvenation in a soft glassy material as, respectively, a decrease and an increase in free energy. The aging term is weighted by an inverse

  16. End-of-life vehicle recycling : state of the art of resource recovery from shredder residue.

    SciTech Connect (OSTI)

    Jody, B. J.; Daniels, E. J.; Energy Systems

    2007-03-21

    Each year, more than 50 million vehicles reach the end of their service life throughout the world. More than 95% of these vehicles enter a comprehensive recycling infrastructure that includes auto parts recyclers/dismantlers, remanufacturers, and material recyclers (shredders). Today, about 75% of automotive materials are profitably recycled via (1) parts reuse and parts and components remanufacturing and (2) ultimately by the scrap processing (shredding) industry. The process by which the scrap processors recover metal scrap from automobiles involves shredding the obsolete automobiles, along with other obsolete metal-containing products (such as white goods, industrial scrap, and demolition debris), and recovering the metals from the shredded material. The single largest source of recycled ferrous scrap for the iron and steel industry is obsolete automobiles. The non-metallic fraction that remains after the metals are recovered from the shredded materials (about 25% of the weight of the vehicle)--commonly called shredder residue--is disposed of in landfills. Over the past 10 to 15 years, a significant amount of research and development has been undertaken to enhance the recycle rate of end-of-life vehicles (ELVs), including enhancing dismantling techniques and improving remanufacturing operations. However, most of the effort has focused on developing technology to recover materials, such as polymers, from shredder residue. To make future vehicles more energy efficient, more lighter-weight materials--primarily polymers and polymer composites--will be used in manufacturing these vehicles. These materials increase the percentage of shredder residue that must be disposed of, compared with the percentage of metals. Therefore, as the complexity of automotive materials and systems increases, new technologies will be required to sustain and maximize the ultimate recycling of these materials and systems at end-of-life. Argonne National Laboratory (Argonne), in cooperation with the Vehicle Recycling Partnership (VRP) and the American Plastics Council (APC), is working to develop technology for recycling materials from shredder residue. Several other organizations worldwide are also working on developing technology for recycling shredder residue. Without a commercially viable shredder industry, our nation may face greater environmental challenges and a decreased supply of quality scrap and be forced to turn to primary ores for the production of finished metals. This document presents a review of the state of the art in shredder residue recycling. Available technologies and emerging technologies for the recycling of materials from shredder residue are discussed.

  17. The Effect of Weld Residual Stress on Life of Used Nuclear Fuel Dry Storage Canisters

    SciTech Connect (OSTI)

    Ronald G. Ballinger; Sara E. Ferry; Bradley P. Black; Sebastien P. Teysseyre

    2013-08-01

    With the elimination of Yucca Mountain as the long-term storage facility for spent nuclear fuel in the United States, a number of other storage options are being explored. Currently, used fuel is stored in dry-storage cask systems constructed of steel and concrete. It is likely that used fuel will continue to be stored at existing open-air storage sites for up to 100 years. This raises the possibility that the storage casks will be exposed to a salt-containing environment for the duration of their time in interim storage. Austenitic stainless steels, which are used to construct the canisters, are susceptible to stress corrosion cracking (SCC) in chloride-containing environments if a continuous aqueous film can be maintained on the surface and the material is under stress. Because steel sensitization in the canister welds is typically avoided by avoiding post-weld heat treatments, high residual stresses are present in the welds. While the environment history will play a key role in establishing the chemical conditions for cracking, weld residual stresses will have a strong influence on both crack initiation and propagation. It is often assumed for modeling purposes that weld residual stresses are tensile, high and constant through the weld. However, due to the strong dependence of crack growth rate on stress, this assumption may be overly conservative. In particular, the residual stresses become negative (compressive) at certain points in the weld. The ultimate goal of this research project is to develop a probabilistic model with quantified uncertainties for SCC failure in the dry storage casks. In this paper, the results of a study of the residual stresses, and their postulated effects on SCC behavior, in actual canister welds are presented. Progress on the development of the model is reported.

  18. Levelized life-cycle costs for four residue-collection systems and four gas-production systems

    SciTech Connect (OSTI)

    Thayer, G.R.; Rood, P.L.; Williamson, K.D. Jr.; Rollett, H.

    1983-01-01

    Technology characterizations and life-cycle costs were obtained for four residue-collection systems and four gas-production systems. All costs are in constant 1981 dollars. The residue-collection systems were cornstover collection, wheat-straw collection, soybean-residue collection, and wood chips from forest residue. The life-cycle costs ranged from $19/ton for cornstover collection to $56/ton for wood chips from forest residues. The gas-production systems were low-Btu gas from a farm-size gasifier, solar flash pyrolysis of biomass, methane from seaweed farms, and hydrogen production from bacteria. Life-cycle costs ranged from $3.3/10/sup 6/ Btu for solar flash pyrolysis of biomass to $9.6/10/sup 6/ Btu for hydrogen from bacteria. Sensitivity studies were also performed for each system. The sensitivity studies indicated that fertilizer replacement costs were the dominate costs for the farm-residue collection, while residue yield was most important for the wood residue. Feedstock costs were most important for the flash pyrolysis. Yields and capital costs are most important for the seaweed farm and the hydrogen from bacteria system.

  19. Plant foliar disease suppression mediated by composted forms of paper mill residuals exhibits molecular features of induced resistance

    E-Print Network [OSTI]

    Goodman, Robert M.

    Plant foliar disease suppression mediated by composted forms of paper mill residuals exhibits Arabidopsis thaliana grown in soil from field plots amended with composted forms of paper mill residuals (PMR with plants grown in soil from field plots amended with a non-composted PMR or non-amended soils. Similar

  20. Microbial community response to a release of neat ethanol onto residual hydrocarbons in a pilot-scale

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Microbial community response to a release of neat ethanol onto residual hydrocarbons in a pilot ethanol release (E100, 76 l) onto residual hydrocarbons in sandy soil was evaluated in a continuous-flow 8 hydrocarbons mobilized by ethanol. Growth of hydrocarbon degrad- ers was corroborated by denaturing gradient