Sample records for research topics catalysis

  1. Catalysis Research for Energy Independence

    E-Print Network [OSTI]

    yields insights into improving the industrial catalyst for oil refining, chemicals processing into chemical fuels. In addition, we conduct applied catalysis research with industrial, academic, and other collaborate with catalysis leaders in academia, industry, and national laboratories. Research in Science

  2. Topics in Catalysis ISSN 1022-5528

    E-Print Network [OSTI]

    Frenkel, Anatoly

    1 23 Topics in Catalysis ISSN 1022-5528 Top Catal DOI 10.1007/s11244-013-0053-y Characterization ubiquitous catalytic systems commonly used [1­6]. Despite significant progress made in developing catalysis, the challenge remains in the co-interpretation of their results since these methods are commonly applied

  3. INSTITUTE FOR INTEGRATED CATALYSIS Catalysis Research for

    E-Print Network [OSTI]

    . This work includes catalysis for upgrading biomass feedstocks; for chemical energy storage, retrieval

  4. Seventh BES (Basic Energy Sciences) catalysis and surface chemistry research conference

    SciTech Connect (OSTI)

    Not Available

    1990-03-01T23:59:59.000Z

    Research programs on catalysis and surface chemistry are presented. A total of fifty-seven topics are included. Areas of research include heterogeneous catalysis; catalysis in hydrogenation, desulfurization, gasification, and redox reactions; studies of surface properties and surface active sites; catalyst supports; chemical activation, deactivation; selectivity, chemical preparation; molecular structure studies; sorption and dissociation. Individual projects are processed separately for the data bases. (CBS)

  5. Basic Research Needs: Catalysis for Energy

    SciTech Connect (OSTI)

    Bell, Alexis T.; Gates, Bruce C.; Ray, Douglas; Thompson, Michael R.

    2008-03-11T23:59:59.000Z

    The report presents results of a workshop held August 6-8, 2007, by DOE SC Basic Energy Sciences to determine the basic research needs for catalysis research.

  6. asymmetric catalysis stereoelectronic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    X Lewis Acid Catalysis Brnsted Acid Catalysis X Johnson, Jeff S. 2 Multidimensional free energy relationships in asymmetric catalysis. Open Access Theses and Dissertations...

  7. DOE Laboratory Catalysis Research Symposium - Abstracts

    SciTech Connect (OSTI)

    Dunham, T.

    1999-02-01T23:59:59.000Z

    The conference consisted of two sessions with the following subtopics: (1) Heterogeneous Session: Novel Catalytic Materials; Photocatalysis; Novel Processing Conditions; Metals and Sulfides; Nuclear Magnetic Resonance; Metal Oxides and Partial Oxidation; Electrocatalysis; and Automotive Catalysis. (2) Homogeneous Catalysis: H-Transfer and Alkane Functionalization; Biocatalysis; Oxidation and Photocatalysis; and Novel Medical, Methods, and Catalyzed Reactions.

  8. aqueous phase catalysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    corroborate asymmetry of catalysis in F0F1-ATP synthase. Zarrabi, Nawid; Diez, Manuel; Graeber, Peter; Wrachtrup, Joerg; Boersch, Michael 2007-01-01 292 Magnetic catalysis in hot...

  9. asymmetric catalysis solvent-free: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    X Lewis Acid Catalysis Brnsted Acid Catalysis X Johnson, Jeff S. 2 Multidimensional free energy relationships in asymmetric catalysis. Open Access Theses and Dissertations...

  10. Opportunities in Catalysis Research Using Synchrotron Radiation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  11. acid-base catalysis ii: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    corroborate asymmetry of catalysis in F0F1-ATP synthase. Zarrabi, Nawid; Diez, Manuel; Graeber, Peter; Wrachtrup, Joerg; Boersch, Michael 2007-01-01 232 Magnetic catalysis in hot...

  12. Heterogeneous Catalysis Environmental Catalysis and Processes

    E-Print Network [OSTI]

    Vardi, Amichay

    Department of Chemical Engineering Ben ­ Gurion University of the Negev Blechner Center for Applied CatalysisHeterogeneous Catalysis Environmental Catalysis and Processes Renewable Fuels M. Herskowitz Nanotechnology and advanced methods are applied in use inspired research #12;Fundamental research of catalytic

  13. The research at the department of Biochemistry is focused on enzyme catalysis, applied enzymology and ecological plant biochemistry. There are two main activities within enzyme catalysis, one towards synthesis

    E-Print Network [OSTI]

    Lagergren, Jens

    The research at the department of Biochemistry is focused on enzyme catalysis, applied enzymology and ecological plant biochemistry. There are two main activities within enzyme catalysis, one towards synthesis of enzyme catalysis based on a broad interdisciplinary competence in enzymology, molecular biology, organic

  14. 2010 CATALYSIS GORDON RESEARCH CONFERENCE, JUNE 27 - JULY 2, 2010, NEW LONDON, NEW HAMPSHIRE

    SciTech Connect (OSTI)

    Abhaya Datye

    2010-07-02T23:59:59.000Z

    Catalysis is a key technology for improving the quality of life while simultaneously reducing the adverse impact of human activities on the environment. The discovery of new catalytic processes and the improvement of existing ones are also critically important for securing the nation's energy supply. The GRC on Catalysis is considered one the most prestigious conference for catalysis research, bringing together leading researchers from both academia, industry and national labs to discuss the latest, most exciting research in catalysis and the future directions for the field. The 2010 GRC on Catalysis will follow time-honored traditions and feature invited talks from the world's leading experts in the fundamentals and applications of catalytic science and technology. We plan to have increased participation from industry. The extended discussions in the company of outstanding thinkers will stimulate and foster new science. The conference will include talks in the following areas: Alternative feedstocks for chemicals and fuels, Imaging and spectroscopy, Design of novel catalysts, Catalyst preparation fundamentals, Molecular insights through theory, Surface Science, Catalyst stability and dynamics. In 2010, the Catalysis conference will move to a larger conference room with a new poster session area that will allow 40 posters per session. The dorm rooms provide single and double accommodations, free WiFi and the registration fee includes all meals and the famous lobster dinner on Thursday night. Afternoons are open to enjoy the New England ambiance with opportunities for hiking, sailing, golf and tennis to create an outstanding conference that will help you network with colleagues, and make long lasting connections.

  15. 337th Catalysis Research Center (CRC) Colloquium Fluorine Industry in China

    E-Print Network [OSTI]

    Ishii, Hitoshi

    337th Catalysis Research Center (CRC) Colloquium Fluorine Industry in China Lu Long (Shanghai industries in China, the second largest economy in the world. In this presentation, fluorine industry in China and the potential business opportunity will be discussed briefly, including inorganic fluorides

  16. adaptation research topics: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RoomMEMORANDUM Current Topics in Accounting Research Students January 19, 2011 The syllabus. This is a course offering primarily designed for Accounting and Accounting...

  17. catalysis | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    analysis radionuclides aerosols catalysis renewable energy subsurface geological field battery materials catalyst beds geochemistry ion microprobe high sensitivity high mass...

  18. Catalysis Center for Energy Innovation for Biomass Processing: Research Strategies and Goals

    SciTech Connect (OSTI)

    Vlachos, Dion G.; Chen, Jingguang; Gorte, R. J.; Huber, George W.; Tsapatsis, Michael

    2010-01-01T23:59:59.000Z

    Production of energy and chemicals from biomass is of critical importance in meeting some of the challenges associated with decreasing availability of fossil fuels and addressing global climate change. In the current article, we outline a perspective on key challenges of biomass processing. We also introduce the Catalysis Center for Energy Innovation (CCEI), one of the 46 Energy Frontier Research Centers established by the Department of Energy in the spring of 2009, and CCEI’s overall research strategies and goals along with its cross-cutting research thrusts that can enable potential technological breakthroughs in the utilization of biomass and its derivatives. The center focuses on developing innovative heterogeneous catalysts and processing schemes that can lead to viable biorefineries for the conversion of biomass to chemicals, fuels, and electricity. In order to achieve this goal, a group of over twenty faculty members from nine institutions has been assembled to bring together complementary expertise covering novel materials synthesis, advanced characterization, multiscale modeling, surface science, catalytic kinetics, and microreactors.

  19. Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis . Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis . Abstract: The research described in...

  20. Small Business Innovation Research (SBIR) FY 2014 Phase I topics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (SBIR) FY 2014 Phase I topics for the Funding Opportunity Announcement (FOA). Small Business Innovation Research (SBIR) FY 2014 Phase I topics for the Funding Opportunity...

  1. Neutrons for Catalysis: A Workshop on Neutron Scattering Techniques for Studies in Catalysis

    SciTech Connect (OSTI)

    Overbury, Steven {Steve} H [ORNL; Coates, Leighton [ORNL; Herwig, Kenneth W [ORNL; Kidder, Michelle [ORNL

    2011-10-01T23:59:59.000Z

    This report summarizes the Workshop on Neutron Scattering Techniques for Studies in Catalysis, held at the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory (ORNL) on September 16 and 17, 2010. The goal of the Workshop was to bring experts in heterogeneous catalysis and biocatalysis together with neutron scattering experimenters to identify ways to attack new problems, especially Grand Challenge problems in catalysis, using neutron scattering. The Workshop locale was motivated by the neutron capabilities at ORNL, including the High Flux Isotope Reactor (HFIR) and the new and developing instrumentation at the SNS. Approximately 90 researchers met for 1 1/2 days with oral presentations and breakout sessions. Oral presentations were divided into five topical sessions aimed at a discussion of Grand Challenge problems in catalysis, dynamics studies, structure characterization, biocatalysis, and computational methods. Eleven internationally known invited experts spoke in these sessions. The Workshop was intended both to educate catalyst experts about the methods and possibilities of neutron methods and to educate the neutron community about the methods and scientific challenges in catalysis. Above all, it was intended to inspire new research ideas among the attendees. All attendees were asked to participate in one or more of three breakout sessions to share ideas and propose new experiments that could be performed using the ORNL neutron facilities. The Workshop was expected to lead to proposals for beam time at either the HFIR or the SNS; therefore, it was expected that each breakout session would identify a few experiments or proof-of-principle experiments and a leader who would pursue a proposal after the Workshop. Also, a refereed review article will be submitted to a prominent journal to present research and ideas illustrating the benefits and possibilities of neutron methods for catalysis research.

  2. Research Topics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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  3. Field of Expertise RESEARCH TOPICS

    E-Print Network [OSTI]

    supply in electric vehicles Fuel cell development, monitor Doppler Laboratory for Fuel Cell Systems Research Studio Austria Flex Fuel Reformer for Fuel Cell Systems Process technology Resources, auxiliaries and utilities Alternative fuels TRAINING AND FURTHER EDUCATION

  4. 2009 SEAri Annual Research Summit Research Topic

    E-Print Network [OSTI]

    de Weck, Olivier L.

    Massachusetts Institute of Technology 6 Tradespace Exploration Paradigm: Avoiding Point Designs Cost Utility, 2009 Cambridge, MA Massachusetts Institute of Technology #12;seari.mit.edu SEAri Annual Research Summit © 2009 Massachusetts Institute of Technology 2 Tradespace Exploration (TSE) · Model-based, high

  5. Automatic detection of research interest using topic modeling

    E-Print Network [OSTI]

    Soetjipto, Rusmin

    2013-01-01T23:59:59.000Z

    We demonstrated the possibility of inferring the research interest of an MIT faculty member given the title of only a few research papers written by him or her, using a topic model learned from a corpus of research paper ...

  6. agricultural research system: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Page Last Page Topic Index 1 Food Systems Research Leopold Center for Sustainable Agriculture Environmental Sciences and Ecology Websites Summary: Systems Working Group of the...

  7. affairs national research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    24 25 Next Page Last Page Topic Index 121 Ris National Laboratory DTU Optics and Plasma Research Department Multidisciplinary Databases and Resources Websites Summary: Ris...

  8. applications national research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    23 24 25 Next Page Last Page Topic Index 81 Ris National Laboratory DTU Optics and Plasma Research Department Multidisciplinary Databases and Resources Websites Summary: Ris...

  9. alternative medicine research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    pathways to health, healing, and wellbeing. This course addresses alternative models of health practices and care. Topics Boonstra, Rudy 2 Research Article in Medicine...

  10. innovative research fa l l 2 0 0 6

    E-Print Network [OSTI]

    New Mexico, University of

    on the editorial boards of Applied Catalysis A, Catalysis Letters, Topics in Catalysis and Catalysis Communications of reactants. Catalysis playsakeyroleintheglobaleconomy,account- ing for 90% of manufacturing processes in the catalysis community. His seminal work in catalyst imaging has helped moved catalysis from an empirically

  11. How To Identify a Good Research Topic? Marek J. Druzdzel

    E-Print Network [OSTI]

    Brusilovsky, Peter

    ... But everybody who wants to succeed works hard. "Because I have a secret weapon" Much better! #12;How To Identify a Good Research Topic? Finding a research topic: Secret weapon What is a secret weapon? · A good problem are not completely on your own here ... · Listen to your advisor: He/she is (or should be) one of your secret weapons

  12. 2012 Catalysis Lectures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bert Weckhuysen, who holds the chair of Inorganic Chemistry and Catalysis at Utrecht University, will give a series of catalysis lectures during his sabbatical period at...

  13. Examples of Topics Project topics researched over the past two years

    E-Print Network [OSTI]

    Sinnamon, Gordon J.

    Examples of Topics Project topics researched over the past two years have included: · Forecasting demand for financial services in China · The impact of social media in the recording industry · How between government "green" energy programs and stock returns · Predicting media politicization around

  14. Catalysis Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  15. accepting foregin research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Swinburne University of Technology Research Funding Acceptance Form Physics Websites Summary: )...

  16. argonne researchers win: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Page Last Page Topic Index 1 Argonne is a partner in the Argonne-Northwestern Solar Energy Research Center led by Northwestern University. Argonne is a partner in the Center for...

  17. SouthWest Catalysis Society 2011 Spring Symposium

    E-Print Network [OSTI]

    Natelson, Douglas

    Award for Excellence in Applied Catalysis later in the day. On-site registration will begin at 7:30 AMSouthWest Catalysis Society 2011 Spring Symposium April 15, 2011 BioScience Research Collaborative in teaching and in the field of catalysis. Additionally, the Society is proud to present the inaugural SWCS

  18. Chemistry {ampersand} Materials Science progress report summary of selected research and development topics, FY97

    SciTech Connect (OSTI)

    Newkirk, L.

    1997-12-01T23:59:59.000Z

    This report contains summaries of research performed in the Chemistry and Materials Science division. Topics include Metals and Ceramics, High Explosives, Organic Synthesis, Instrument Development, and other topics.

  19. This research was supported as part of the Catalysis Center for Energy Innovatio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  20. archaeological inventory research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    archaeological inventory research First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 RESEARCH REQUEST FORM...

  1. accident research priorities: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    accident research priorities First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Chapter 6: Research...

  2. air pollution research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    air pollution research First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Edinburgh Research Explorer...

  3. Catalysis by Design: Bridging the Gap between Theory and Experiments...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    between Theory and Experiments Catalysis by Design: Bridging the Gap between Theory and Experiments Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research...

  4. HETEROGENEOUS CATALYSIS RESEARCH MEETING

    E-Print Network [OSTI]

    Authors, Various

    2011-01-01T23:59:59.000Z

    synthesis gas by coal gasification is very expensive andin the cost of coal gasification would have a significantas K co , to promote gasification would be beneficial s1nce

  5. HETEROGENEOUS CATALYSIS RESEARCH MEETING

    E-Print Network [OSTI]

    Authors, Various

    2011-01-01T23:59:59.000Z

    production of SNG or Fischer-Tropsch products Therefore, abe trying to obtain from Fischer-Tropsch synthesis? Answer:intermediates in Fischer-Tropsch synthesis? Answer: It was

  6. HETEROGENEOUS CATALYSIS RESEARCH MEETING

    E-Print Network [OSTI]

    Authors, Various

    2011-01-01T23:59:59.000Z

    is pointed out that coal gasification involves 70% to 80% ofof alkali metals in coal gasification is poorly under- stoodOther methods of catalyzing coal gasification also should be

  7. Topics for letter "c" | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Wing RadEMSL Virtual Tour Topics for letter "c" carbon carbon cycling carbon dioxide carbon sequestration Cascade catalysis catalytic reaction cation migration chemical...

  8. atomic energy research establishment: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    atomic energy research establishment First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Danish Atomic...

  9. alternative energy research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    energy research First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 November 2008 Alternative Energy...

  10. advanced energy research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    advanced energy research First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Department of Advanced Energy...

  11. atomic energy research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    energy research First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Danish Atomic Energy Commission...

  12. advanced process research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    process research First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Abstract--Genomic Signal Processing is...

  13. advanced nuclear research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    advanced nuclear research First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Department of Advanced Energy...

  14. advanced materials research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    materials research First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 University of New Orleans Advanced...

  15. 1 Background 1.1 Topic of research

    E-Print Network [OSTI]

    Hunt, Sebastian

    1 Background 1.1 Topic of research Mathematical quantitative tools (like probabil- ity theory analyses on the basis of these meth- ods. 1.2 Academic and industrial con- text Interference in a security section 1.3). Applications of this work can be found in large scale, mission critical, security related

  16. advanced corrosion research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    advanced corrosion research First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Systems Engineering...

  17. accident research network: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    accident research network First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Structure Evolution of...

  18. SOUTHWEST CATALYSIS 2012 SPRING SYMPOSIUM

    E-Print Network [OSTI]

    ) "Catalysis to Meet the Energy Challenge" 11:00 AM Southwest Catalysis Society Excellence in Applied CatalysisSOUTHWEST CATALYSIS SOCIETY 2012 SPRING SYMPOSIUM April 20, 2012 Duncan Hall - McMurtry Auditorium registration fee is $50, which includes North American Catalysis Society and SWCS yearly membership dues, along

  19. EMSL - In situ catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    situ-catalysis en New generation NMR bioreactor coupled with high-resolution NMR spectroscopy leads to novel discoveries in Moorella http:www.emsl.pnl.govemslwebpublications...

  20. Computational Catalysis and Electrocatalysis

    E-Print Network [OSTI]

    · Hydrogen storage · Photocatalysis #12;Fuel cell electrocatalysts Parallelism between bimetallics projects: photo-catalysis water decomposes over a catalyst producing oxygen and hydrogen From members

  1. SOUTHWEST CATALYSIS 2013 SPRING SYMPOSIUM

    E-Print Network [OSTI]

    Natelson, Douglas

    -free Substrates" 11:05 AM Southwest Catalysis Society Excellence in Applied Catalysis Award James "Jerry" SpiveySOUTHWEST CATALYSIS SOCIETY 2013 SPRING SYMPOSIUM Friday, April 26, 2013 Grand Hall of the Ley registration fee is $50, which includes North American Catalysis Society and SWCS yearly membership dues, along

  2. Materials and interfaces for catalysis, separation, storage, and environmental applications

    E-Print Network [OSTI]

    Li, Mo

    Materials and interfaces for catalysis, separation, storage, and environmental applications collaborative effort in cutting-edge fundamental and applied research to discover and develop polymeric' problems such as inexpensive CO2 capture, energy-efficient and high-performance catalysis and separations

  3. Final technical report, Symposium on New Theoretical Concepts and Directions in Catalysis

    SciTech Connect (OSTI)

    Metiu, Horia [University of California, Santa Barbara

    2014-08-22T23:59:59.000Z

    We organized in August 2013 a “Symposium on New Theoretical Concepts and Directions in Catalysis” with the participation of 20 invited distinguished quantum chemists and other researchers who use computations to study catalysis. Symposium website; http://catalysis.cnsi.ucsb.edu/

  4. Research topics related to ESI | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with form History FacebookRegenesysRenewableStrategies (EC-LEDS) |Research topics

  5. IEMS 490: Special topics: Operations Research Modeling in Humanitarian and Non-Profit Logistics

    E-Print Network [OSTI]

    Smilowitz, Karen

    IEMS 490: Special topics: Operations Research Modeling in Humanitarian and Non-Profit Logistics228) Course Description This course will cover a range of topics related to the modeling of logistics. Course material focuses on formulating complex logistics problems, teaching students to trans- late real

  6. Research on Estrogen and Behavior Is a 'Hot Topic' at the 2011 Society for Neuroscience Meeting

    ScienceCinema (OSTI)

    Anat Biegon

    2013-07-19T23:59:59.000Z

    The Society for Neuroscience has selected recent research on estrogen and its effect on behavior conducted at BNL for its "hot topics" book distributed to reporters attending the society's 2011 meeting in Washington, D.C., November 12-16.

  7. Research Worksheet 1. Your Topic prevention of workplace bullying

    E-Print Network [OSTI]

    Thompson, Michael

    : English Publication Dates: 2000-2013 Document Types: Books X Journal Articles, peer-reviewed yes/Databases and Subject Guides tabs on the library home page to identify library databases covering your topic and your

  8. agile research group: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Forest Research, Northern Research Station, Roslin, 11 Renewable Energy Websites Summary: Timber Quality Steering Group 8 th Meeting at Forest Research, Northern Research Station,...

  9. Heterogeneous Catalysis on Atomically Dispersed Supported Metals...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalysis on Atomically Dispersed Supported Metals: CO2 Reduction on Multifunctional Pd Catalysts. Heterogeneous Catalysis on Atomically Dispersed Supported Metals: CO2 Reduction...

  10. accelerator fusion research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on the Fusion Ignition Research Experiment (FIRE), a tokamak designed for burning plasma research. Engineering 17 Research Needs Workshop for Magnetic Fusion Energy Plasma Physics...

  11. association fusion research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on the Fusion Ignition Research Experiment (FIRE), a tokamak designed for burning plasma research. Engineering 18 Research Needs Workshop for Magnetic Fusion Energy Plasma Physics...

  12. aafp national research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Environmental Research 63 Ris National Laboratory DTU Optics and Plasma Research Department Multidisciplinary Databases and Resources Websites Summary: Ris...

  13. applied research accelerator: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    period including: Entrepreneurial thinking, aspirations and role models The business planning researchers from across SICSA to accelerate promising research ideas...

  14. atmospheric research community: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    University Corporation for Atmospheric Research Geosciences Websites Summary: University Corporation for Atmospheric Research CIGNA DENTAL PREFERRED PROVIDER INSURANCE EFFECTIVE...

  15. Support for U.S. Participants at the 15th International Congress on Catalysis

    SciTech Connect (OSTI)

    Wachs, Israel E.

    2013-08-05T23:59:59.000Z

    The grant was used to partially assist the travel expenses of U.S. academic scientists to attend the 15th International Congress on Catalysis. The conference was held in Munich, Germany from July 1-6, 2012. The importance of the International Congress was to bring together the international community of faculty members who participate in catalysis research, and to share information that would lead to further developments and directions in the field of study. Graduate students and Post Docs were invited to apply for travel assistance based on criteria established by the North American Catalysis Society (NACS) and the local Catalysis Clubs.

  16. astrophysics research program: Topics by E-print Network

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    Program Summer Research Program 2011 Funded Summer Research Opportunities in Germany for Students in Science, Engineering, and Health Sciences The OntarioBaden-Wrttemberg...

  17. advance science research: Topics by E-print Network

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    that one Geddes, Cameron Guy Robinson 3 Advanced Scientific Computing Research Computer Science Engineering Websites Summary: Advanced Scientific Computing Research Computer...

  18. advanced accelerator research: Topics by E-print Network

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    praxis sessions during the semester. Preference will be given to students whose Johnson Jr.,, Ray 158 * This research was supported in part by the Advanced Research Projects...

  19. annual research conference: Topics by E-print Network

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    Websites Summary: 12;12th Annual VT Undergraduate Research Conference April 18, 2014 Page 2 Welcome to Virginia Tech's Spring Undergraduate Research Conference. This event...

  20. actor research overview: Topics by E-print Network

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    chemicals Developed full three Chappell, William J. 14 Overview of BNL's Solar Energy Research Plansgy Physics Websites Summary: Overview of BNL's Solar Energy Research...

  1. arctic research station: Topics by E-print Network

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    The Rocky Mountain Research Sta- tion is one of five 19 Z .Atmospheric Research 51 1999 4575 Cloud resolving simulations of Arctic stratus Geosciences Websites Summary: Z...

  2. administration langley research: Topics by E-print Network

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    Lifecycle Bandettini, Peter A. 33 GC Policies Research Administration Policy, October 30, 2013 1 RESEARCH ADMINISTRATION POLICY Environmental Sciences and Ecology Websites...

  3. atomic research center: Topics by E-print Network

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  4. argonne research reactor: Topics by E-print Network

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  5. array research program: Topics by E-print Network

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  6. apprenticeship research program: Topics by E-print Network

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  8. asthma research program: Topics by E-print Network

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  10. Magnetic catalysis and inverse magnetic catalysis in QCD

    E-Print Network [OSTI]

    Niklas Mueller; Jan M. Pawlowski

    2015-02-27T23:59:59.000Z

    We investigate the effects of strong magnetic fields on the QCD phase structure at vanishing density by solving the gluon and quark gap equations, and by studying the dynamics of the quark scattering with the four-fermi coupling. The chiral crossover temperature as well as the chiral condensate are computed. For asymptotically large magnetic fields we find magnetic catalysis, while we find inverse magnetic catalysis for intermediate magnetic fields. Moreover, for large magnetic fields the chiral phase transition for massless quarks turns into a crossover. The underlying mechanisms are then investigated analytically within a few simplifications of the full numerical analysis. We find that a combination of gluon screening effects and the weakening of the strong coupling is responsible for the phenomenon of inverse catalysis. In turn, the magnetic catalysis at large magnetic field is already indicated by simple arguments based on dimensionality.

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  12. Hot Topics Workshop-Renewable Energy | Photosynthetic Antenna Research

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  13. asia oceania research: Topics by E-print Network

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  16. applied research field: Topics by E-print Network

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  17. atmosphere research launch: Topics by E-print Network

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    14 research staff and postdoctoral scientists More than 5M per, climate change, radar meteorology, tropical meteorology Atmospheric Chemistry - fundamental...

  18. advanced propulsion research: Topics by E-print Network

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    Sciences Websites Summary: *National Radio Astronomy Observatory 12;First European Conference on Research and Advanced Technologies of bibliographic data, abstracts,...

  19. accelerator research final: Topics by E-print Network

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  20. agriculture-agricultural research service: Topics by E-print...

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  2. Synthetic Catalysis of Amide Isomerization

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    Lectka, Thomas

    , they may play other roles in vivo, including the catalysis of protein folding, functioning as auxiliary seem to be a possible way to catalyze protein folding in vitro, and experiments along these lines

  3. advanced research workshop: Topics by E-print Network

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  4. austrian research reactor: Topics by E-print Network

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  5. advancing translational research: Topics by E-print Network

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  6. advance translational research: Topics by E-print Network

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  7. agricultural sciences research: Topics by E-print Network

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  9. agricultural research center: Topics by E-print Network

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    Leistikow, Bruce N. 4 GENERAL MEMORANDUM OF AGREEMENT Mississippi Agricultural and Forestry Experiment Station (MAFES) Forest & Wildlife Research Center (FWRC) Environmental...

  10. applied research units: Topics by E-print Network

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  11. annual research progress: Topics by E-print Network

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  13. aeroelasticity division research: Topics by E-print Network

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  15. applied geoscience research: Topics by E-print Network

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  16. applied thermionic research: Topics by E-print Network

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  17. applied nuclear research: Topics by E-print Network

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  18. applied research reatores: Topics by E-print Network

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  20. army research laboratory: Topics by E-print Network

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  3. airbreathing propulsion research: Topics by E-print Network

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    you for being so encouraging, for listening to and understanding the woes of RF plasma research, and for being so friendly at conferences and in the hallways. Professor...

  4. aditya tokamak research: Topics by E-print Network

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    Robert G. Kleva and Parvez N. Guzdar Materials Science Websites Summary: for Plasma Research, University of Maryland, College Park, Maryland 20770 Received 9 June 1999;...

  5. ames laboratory research: Topics by E-print Network

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  6. ames laboratory research reactor: Topics by E-print Network

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  7. ames laboratory researchers: Topics by E-print Network

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  8. advanced tokamak research: Topics by E-print Network

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    Robert G. Kleva and Parvez N. Guzdar Materials Science Websites Summary: for Plasma Research, University of Maryland, College Park, Maryland 20770 Received 9 June 1999;...

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  10. aging research laboratory: Topics by E-print Network

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    of the authors Perona, Pietro 36 Ris National Laboratory DTU Optics and Plasma Research Department Multidisciplinary Databases and Resources Websites Summary: Ris...

  11. atlantic research laboratory: Topics by E-print Network

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    of the authors Perona, Pietro 62 Ris National Laboratory DTU Optics and Plasma Research Department Multidisciplinary Databases and Resources Websites Summary: Ris...

  12. alamos national research: Topics by E-print Network

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  13. avian research program: Topics by E-print Network

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  14. annual research symposium: Topics by E-print Network

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    "Against Chase, Ph.D., Critical Studies "SolidSpace: A Device for Redesigning Perception" Bryan Jaycox, M McLeod, Dennis 29 Research Symposium January 2005...

  15. advanced reactor research: Topics by E-print Network

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    student Harish Nair and undergraduate research student John Mills, David L. 45 Friction pressure drop measurements and flow distribution analysis for LEU conversion study of MIT...

  16. aist tsukuba research: Topics by E-print Network

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    Japan. We also give brief summaries of: (1) the Joint Research Center for Atom Technology (JRCAT), (2) a special purpose computer (Molecular Orbital Engine--MOE) for...

  17. analytical tool research: Topics by E-print Network

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    ... Leong, Ming 2011-01-01 78 Researchers develop new search tool to help fight child porn, catch cyber Computer Technologies and Information Sciences Websites Summary:...

  18. agent research tool: Topics by E-print Network

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    ... Leong, Ming 2011-01-01 59 Researchers develop new search tool to help fight child porn, catch cyber Computer Technologies and Information Sciences Websites Summary:...

  19. assessment research development: Topics by E-print Network

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    and Utilization Websites Summary: Renewable Energy Center California Off-shore Wind Technology Assessment 12;California Renewable EnergyRESEARCH RESULTS FORUM FOR RENEWABLE...

  20. agricultural technology research: Topics by E-print Network

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    and Utilization Websites Summary: Renewable Energy Center California Off-shore Wind Technology Assessment 12;California Renewable EnergyRESEARCH RESULTS FORUM FOR RENEWABLE...

  1. assessing research proposals: Topics by E-print Network

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    and Utilization Websites Summary: Renewable Energy Center California Off-shore Wind Technology Assessment 12;California Renewable EnergyRESEARCH RESULTS FORUM FOR RENEWABLE...

  2. advanced technological research: Topics by E-print Network

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  3. ash resources research: Topics by E-print Network

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  4. assessment research centre: Topics by E-print Network

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  6. american manufacturing research: Topics by E-print Network

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    hardships suffered by the unemployed. unknown authors 2003-01-01 4 Manufacturing for the Hydrogen Economy Manufacturing Research & Development Energy Storage, Conversion and...

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    of particle and nuclear physics, magnetic confinement of high-temperature plasmas for thermonuclear fusion research, and gravity wave observatories based on laser...

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    2013-01-01 14 Complex workplace radiation fields at European high-energy accelerators and thermonuclear fusion facilities CERN Preprints Summary: This report outlines the research...

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    represent our observations such as "one's blood type is AB Sato, Taisuke 115 Journal of Artificial Intelligence Research 33 (2008) 3377 Submitted 0907; published 0908 ICE: An...

  10. artificial intelligence research: Topics by E-print Network

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    represent our observations such as "one's blood type is AB Sato, Taisuke 118 Journal of Artificial Intelligence Research 33 (2008) 3377 Submitted 0907; published 0908 ICE: An...

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    figures, and images are efficient; they communicate a lot Northern British Columbia, University of 36 Academic Event Funding Through the GAPSA Research Student Council Biology...

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    agency contact Minnesota, University of 38 Application for Undergraduate ResearchTravel Funding History Department, University of Michigan Multidisciplinary Databases and...

  14. advancing prevention research: Topics by E-print Network

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  15. acid research frontiers: Topics by E-print Network

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    (NSF), Department of Energy (DOE), National Institutes of Health (NIH) and NASA, are funding the necessary cyberinfrastructure to empower e-science research and allied education...

  16. area process research: Topics by E-print Network

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    research environmental January 2012 The Issue Comprehensive and reliable energy statistics are essential for good policy analysis and for future projections of energy...

  17. applied research center: Topics by E-print Network

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    Publications 39 Seminars 43 Luncheon Discussions 47 Workshops 48 Visiting Scholars 49 Funding Wang, Yuqing 13 Louisiana Transportation Research Center Environmental Sciences and...

  18. alberta flare research: Topics by E-print Network

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    O. Terry 5 FLARE: Fast Layout for Augmented Reality Applications Microsoft Research Energy Storage, Conversion and Utilization Websites Summary: FLARE: Fast Layout for Augmented...

  19. aerosol characteristic researching: Topics by E-print Network

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    as they have significant impacts both on localregional air pollution and global climate. Recent for Aerosol and Cloud Chemistry, Aerodyne Research, Incorporated, Billerica,...

  20. atmosphere research satellite: Topics by E-print Network

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    remote sensing device), and airplane and satellite observations. Airplane based sensible heat flux Research. This national observatory accommodates numerous remote sensing and...

  1. air research sst: Topics by E-print Network

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    data (one ship using bucket, one ERI 2 Improved Validation of Satellite SST for Climate Research Environmental Sciences and Ecology Websites Summary: , and resolution)...

  2. australian replacement research reactor: Topics by E-print Network

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    facilities operated by the department include the research reactor DR 3, the Isotope Laboratory 140 Compound cryopump for fusion reactors CERN Preprints Summary: We reconsider an...

  4. agricultural research centre: Topics by E-print Network

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    Water Resources Research. WASTE GUIDE ON THERMAL POLLUTION Copies of an "Industrial, Pacific Northwest Water Laboratory, Corvallis, Oregon, 97330, or Federal Water Pollution...

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    Austin, TX On-X Life Technologies Inc Brenham, TX REM Research Group Inc Dallas, TX Raytheon Co Forth Worth, TX Alcon Laboratories Inc Bell Helicopter Sovereign Pharmaceuticals...

  6. Advice on Choosing Research Topics and Writing Technical Papers

    E-Print Network [OSTI]

    ­ "Solar panels that achieve 50% conversion efficiency using low cost, nonprecious metal materials" ­ Make hypothesisdriven research · Bad title example and reasons ­ "Effects of materials on solar panel efficiency

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    Canada, following appIes (Matus domestica Barkh.) and grapes (Vizisspp.). In 1988 Biggs, Alan R. 2 National Research Council Canada Computer Technologies and Information...

  8. antarctic research station: Topics by E-print Network

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    Canada, following appIes (Matus domestica Barkh.) and grapes (Vizisspp.). In 1988 Biggs, Alan R. 18 ANNUAL REVIEW 2011 Antarctic Research Centre Environmental Sciences and...

  9. afrl research highlights: Topics by E-print Network

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    conducting researchElectric Power Group, Lawrence Berkeley National Laboratory, Oak Ridge National Laboratory, Pacific Northwest National Laboratory, the National Science...

  10. advance genetic research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    About Researchers create the world's most advanced genetic map Massachusetts Health Care Reform Increased Access Reich, David 3 Advanced Genetics PCB 5065 Fall 2013 page 1...

  11. argonne tank research and test reactor-aarr: Topics by E-print...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    argonne tank research and test reactor-aarr First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Tests using...

  12. addiction research foundation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: AND ADDICTION (K12) Funding Opportunity Number: PAR-10-177. CFDA Number(s): 93.279. AgencyDepartment: National) leading to research independence in the...

  13. act funded researchers: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FOR TEACHERS (RET) IN ENGINEERING AND COMPUTER Funding Opportunity Number: NSF 11-509. CFDA Number(s): 47.041. Engineering Websites Summary: Grant Title: RESEARCH EXPERIENCES FOR...

  14. advanced photon research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to attend EVERY class, on time, regardless Gallo, Linda C. 85 Photon Physics and Plasma Research, WILGA 2012; EuCARD Sessions CERN Preprints Summary: Wilga Sessions on HEP...

  15. agenda setting research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Break 10:35-11:00 Robert Savinell, CWRU Revisiting flow-battery R&D 11 Johnson, DOE ARPA-E Flow cell research in GRIDS 12:05-12:30 Tom Zawodzinski, ORNL and UTK Transitioning 71...

  16. advanced research project: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program. Through Dennehy, John 64 The Advanced Research Projects Agency-Energy (ARPA-E) has awarded engineers at Case Western Reserve University 1,508,000 in a second round...

  17. advanced research projects: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program. Through Dennehy, John 64 The Advanced Research Projects Agency-Energy (ARPA-E) has awarded engineers at Case Western Reserve University 1,508,000 in a second round...

  18. action research study: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on all fields of N4 vector multiplet. We also consider the derivation of leading low-enrgy effective action at two loops. I. L. Buchbinder 2004-02-12 31 European Research...

  19. application research reactor: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Yuen-Ting 2008-01-01 18 Design and optimization of a high thermal flux research reactor via Kriging-based algorithm MIT - DSpace Summary: In response to increasing demands...

  20. addiction research centres: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and other research D. C. Satjja; D. K. Sharma; Arun Gaur; S. S. Nathawat 213 The Addict in Us all MIT - DSpace Summary: In this paper, we contend that the psychology of...

  1. advanced media research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7.5 to 13 micron range, which means it is more useable Nebraska-Lincoln, University of 20 Media Contact: Gretchen Smith New Hampshire Innovation Research Center Materials Science...

  2. Enhanced Micellar Catalysis LDRD.

    SciTech Connect (OSTI)

    Betty, Rita G.; Tucker, Mark David; Taggart, Gretchen; Kinnan, Mark K.; Glen, Crystal Chanea; Rivera, Danielle; Sanchez, Andres; Alam, Todd Michael

    2012-12-01T23:59:59.000Z

    The primary goals of the Enhanced Micellar Catalysis project were to gain an understanding of the micellar environment of DF-200, or similar liquid CBW surfactant-based decontaminants, as well as characterize the aerosolized DF-200 droplet distribution and droplet chemistry under baseline ITW rotary atomization conditions. Micellar characterization of limited surfactant solutions was performed externally through the collection and measurement of Small Angle X-Ray Scattering (SAXS) images and Cryo-Transmission Electron Microscopy (cryo-TEM) images. Micellar characterization was performed externally at the University of Minnesota's Characterization Facility Center, and at the Argonne National Laboratory Advanced Photon Source facility. A micellar diffusion study was conducted internally at Sandia to measure diffusion constants of surfactants over a concentration range, to estimate the effective micelle diameter, to determine the impact of individual components to the micellar environment in solution, and the impact of combined components to surfactant phase behavior. Aerosolized DF-200 sprays were characterized for particle size and distribution and limited chemical composition. Evaporation rates of aerosolized DF-200 sprays were estimated under a set of baseline ITW nozzle test system parameters.

  3. autism research findings: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DISORDERS (R01R03R21) Funding Opportunity Number: PA-10-158, PA-10-159, PA-10-160. CFDA Number(s): 93.242, 93.865, 93.173, Engineering Websites Summary: Grant Title: RESEARCH...

  4. Fuel Synthesis Catalysis Laboratory (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-07-01T23:59:59.000Z

    This fact sheet provides information about Fuel Synthesis Catalysis Laboratory capabilities and applications at NREL's National Bioenergy Center.

  5. Fuel Synthesis Catalysis Laboratory (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-07-01T23:59:59.000Z

    This fact sheet provides information about Fuel Synthesis Catalysis Laboratory capabilities and applications at NREL's National Bioenergy Center.

  6. Transformation of Sorbitol to Biofuels by Heterogeneous Catalysis: Chemical and Industrial

    E-Print Network [OSTI]

    Boyer, Edmond

    Transformation of Sorbitol to Biofuels by Heterogeneous Catalysis: Chemical and Industrial ainsi que des exemples d'applications industrielles. Abstract -- Transformation of Sorbitol to Biofuels and biodiesel production led to first generation biofuels. Nowadays, research is focused on lignocellulosic

  7. Dendrimer-encapsulated metal nanoparticles: synthesis, characterization, and applications to catalysis 

    E-Print Network [OSTI]

    Niu, Yanhui

    2004-09-30T23:59:59.000Z

    The research in this dissertation examines the chemistry and applications of dendrimers in homogeneous catalysis. We examined interactions between dendrimers and charged probe molecules, prepared dendrimer-encapsulated metal nanoparticles...

  8. Simulations on the effects of confinement and Ni-catalysis on the formation of tubular fullerene structures from peapod precursors

    E-Print Network [OSTI]

    Goddard III, William A.

    Simulations on the effects of confinement and Ni-catalysis on the formation of tubular fullerene April 2007 We applied the recently developed reactive force field ReaxFF to study the dynamics buckyballs. This barrier is lowered by 40% with the aid of Ni-catalysis. This research can help the community

  9. Charge Transfer and Support Effects in Heterogeneous Catalysis

    E-Print Network [OSTI]

    Hervier, Antoine

    2012-01-01T23:59:59.000Z

    T. ; Haruta, M.  Applied Catalysis A:  General 1998, 169, Albert Vannice, M.  Applied Catalysis A: General 1994, 113, Viswanath, R.  P.  Applied Catalysis A: General 2001, 208, 

  10. Charge Transfer and Catalysis at the Metal-Support Interface

    E-Print Network [OSTI]

    Baker, Lawrence Robert

    2012-01-01T23:59:59.000Z

    A. ; Miko?ajska, A. Applied Catalysis A: General 2002, 233,T. ; Haruta, M. Applied Catalysis A: General 1998, 169,Albert Vannice, M. Applied Catalysis A: General 1994, 113, (

  11. Workshop: Synchrotron Applications in Chemical Catalysis | Stanford...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Applications in Chemical Catalysis Tuesday, October 25, 2011 - 8:00am 2011 SSRLLCLS Annual Users Conference This workshop, part of the 2011 SSRLLCLS Annual Users...

  12. Plasma Assisted Catalysis System for NOx Reduction

    Broader source: Energy.gov (indexed) [DOE]

    2 NOXTECH NOXTECH PLASMA ASSISTED CATALYSIS SYSTEM FOR NOx REDUCTION BY NOXTECH With the Support & Cooperation of DOE Noxtech, Inc. *Delaware Corporation registered to do business...

  13. Findings of the US research needs workshop on the topic of fusion power

    SciTech Connect (OSTI)

    W. R. Meier; A. R. Raffray; R. J. Kurtz; N. B. Morley; W. T. Reiersen; Phil Sharpe; S. Willms

    2010-12-01T23:59:59.000Z

    The US Department of Energy, Office of Fusion Energy Sciences (OFES) conducted a Research Needs Workshop, referred to as ReNeW, in June 2009. The information developed at this workshop will help OFES develop a plan for US fusion research during the ITER era, roughly the next two decades. The workshop was organized in five Themes, one of which was Harnessing Fusion Power (or Fusion Power for short). The top level goal of the Fusion Power Theme was to identify the research needed to develop the knowledge to design and build, with high confidence, robust and reliable systems that can convert fusion products to useful forms of energy in a reactor environment, including a self-sufficient supply of tritium fuel. Each Theme was subsequently subdivided into Panels to address specific topics. The Fusion Power Panel topics were: Fusion Fuel Cycle; Power Extraction; Materials Science; Safety and Environment; and Reliability, Availability, Maintainability and Inspectability (RAMI). Here we present the key findings of the Fusion Power Theme.

  14. Findings of the US research needs workshop on the topic of fusion power

    SciTech Connect (OSTI)

    Meier, Wayne R.; Raffray, R.; Kurtz, Richard J.; Morley, Neil B.; Reiersen, Wayne T.; Sharpe, Phil; Willms, Scott

    2010-12-01T23:59:59.000Z

    The US Department of Energy, Of?ce of Fusion Energy Sciences (OFES) conducted a Research Needs Workshop, referred to as ReNeW, in June 2009. The information developed at this workshop will help OFES develop a plan for US fusion research during the ITER era, roughly the next two decades. The workshop was organized in ?ve Themes, one of which was Harnessing Fusion Power (or Fusion Power for short). The top level goal of the Fusion Power Theme was to identify the research needed to develop the knowledge to design and build, with high con?dence, robust and reliable systems that can convert fusion products to useful forms of energy in a reactor environment, including a self-suf?cient supply of tritium fuel. Each Theme was subsequently subdivided into Panels to address speci?c topics. The Fusion Power Panel topics were: Fusion Fuel Cycle; Power Extraction; Materials Science; Safety and Environment; and Reliability, Availability, Maintainability and Inspectability (RAMI). Here we present the key ?ndings of the Fusion Power Theme.

  15. Findings of the US Research Needs Workshop on the Topic of Fusion Power

    SciTech Connect (OSTI)

    Meier, W R; Raffray, A R; Kurtz, R J; Morley, N B; Reiersen, W T; Sharpe, P; Willms, S

    2009-09-16T23:59:59.000Z

    The US Department of Energy, Office of Fusion Energy Sciences (OFES) conducted a Research Needs Workshop, referred to as ReNeW, in June 2009. The information developed at this workshop will help OFES develop a plan for US fusion research during the ITER era, roughly the next two decades. The workshop was organized in five Themes, one of which was Harnessing Fusion Power (or Fusion Power for short). The top level goal of the Fusion Power Theme was to identify the research needed to develop the knowledge to design and build, with high confidence, robust and reliable systems that can convert fusion products to useful forms of energy in a reactor environment, including a self-sufficient supply of tritium fuel. Each Theme was subsequently subdivided into Panels to address specific topics. The Fusion Power Panel topics were: fusion fuel cycle; power extraction; materials science; safety and environment; and reliability, availability, maintainability and inspectability (RAMI). Here we present the key findings of the Fusion Power Theme.

  16. Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conversion: Using Heat and Catalysis to Make Biofuels and Bioproducts Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels and Bioproducts The Bioenergy...

  17. CATALYSIS SCIENCE AND TECHNOLOGY

    SciTech Connect (OSTI)

    M. ABRAMS; R. BAKER; ET AL

    2000-08-01T23:59:59.000Z

    This is the final report of a three-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). Our objectives were to develop a multidisciplinary team and capabilities to develop a fundamental understanding of homogeneous, heterogeneous, and heterogenized catalysts. With the aid of theoretical chemistry approaches we explored and characterized the chemical reactivity and physical properties of a large number of catalytic systems.

  18. Low-rank coal research, Task 5.1. Topical report, April 1986--December 1992

    SciTech Connect (OSTI)

    Not Available

    1993-02-01T23:59:59.000Z

    This document is a topical progress report for Low-Rank Coal Research performed April 1986 - December 1992. Control Technology and Coal Preparation Research is described for Flue Gas Cleanup, Waste Management, Regional Energy Policy Program for the Northern Great Plains, and Hot-Gas Cleanup. Advanced Research and Technology Development was conducted on Turbine Combustion Phenomena, Combustion Inorganic Transformation (two sections), Liquefaction Reactivity of Low-Rank Coals, Gasification Ash and Slag Characterization, and Coal Science. Combustion Research is described for Atmospheric Fluidized-Bed Combustion, Beneficiation of Low-Rank Coals, Combustion Characterization of Low-Rank Fuels (completed 10/31/90), Diesel Utilization of Low-Rank Coals (completed 12/31/90), Produce and Characterize HWD (hot-water drying) Fuels for Heat Engine Applications (completed 10/31/90), Nitrous Oxide Emission, and Pressurized Fluidized-Bed Combustion. Liquefaction Research in Low-Rank Coal Direct Liquefaction is discussed. Gasification Research was conducted in Production of Hydrogen and By-Products from Coals and in Sulfur Forms in Coal.

  19. Column Asymmetric Catalysis for -Lactam Synthesis

    E-Print Network [OSTI]

    Lectka, Thomas

    Column Asymmetric Catalysis for -Lactam Synthesis Ahmed M. Hafez, Andrew E. Taggi, Harald Wack that constitute the packing of a series of "reaction columns". This process was applied to the catalytic- and diastereoselectivity. In the realm of chiral synthesis and drug discovery, asym- metric catalysis1 and solid

  20. Molecular-Level Design of Heterogeneous Chiral Catalysis

    SciTech Connect (OSTI)

    Francisco Zaera

    2012-03-21T23:59:59.000Z

    The following is a proposal to continue our multi-institutional research on heterogeneous chiral catalysis. Our team combines the use of surface-sensitive analytical techniques for the characterization of model systems with quantum and statistical mechanical calculations to interpret experimental data and guide the design of future research. Our investigation focuses on the interrelation among the three main mechanisms by which enantioselectivity can be bestowed to heterogeneous catalysts, namely: (1) by templating chirality via the adsorption of chiral supramolecular assemblies, (2) by using chiral modifiers capable of forming chiral complexes with the reactant and force enantioselective surface reactions, and (3) by forming naturally chiral surfaces using imprinting chiral agents. Individually, the members of our team are leaders in these various aspects of chiral catalysis, but the present program provides the vehicle to generate and exploit the synergies necessary to address the problem in a comprehensive manner. Our initial work has advanced the methodology needed for these studies, including an enantioselective titration procedure to identify surface chiral sites, infrared spectroscopy in situ at the interface between gases or liquids and solids to mimic realistic catalytic conditions, and DFT and Monte Carlo algorithms to simulate and understand chirality on surfaces. The next step, to be funded by the monies requested in this proposal, is to apply those methods to specific problems in chiral catalysis, including the identification of the requirements for the formation of supramolecular surface structures with enantioselective behavior, the search for better molecules to probe the chiral nature of the modified surfaces, the exploration of the transition from supramolecular to one-to-one chiral modification, the correlation of the adsorption characteristics of one-to-one chiral modifiers with their physical properties, in particular with their configuration, and the development of ways to imprint chiral centers on achiral solid surfaces. Chiral catalysis is not only a problem of great importance in its own right, but also the ultimate test of how to control selectivity in catalysis. The time is ripe for fundamental work in heterogeneous chiral catalysis to provide the U.S. with a leadership role in developing the next generation of catalytic processes for medicinal and agrochemical manufacturing. Our team provides the required expertise for a synergistic and comprehensive integration of physical and chemical experimentation with solid state and molecular reactivity theories to solve this problem.

  1. Catalysis for Mixed Alcohol Synthesis from Biomass Derived Syngas: Cooperative Research and Development Final Report, CRADA Number CRD-08-292

    SciTech Connect (OSTI)

    Hensley, J.

    2013-04-01T23:59:59.000Z

    The Dow Chemical Company (Dow) developed and tested catalysts for production of mixed alcohols from synthesis gas (syngas), under research and development (R&D) projects that were discontinued a number of years ago. Dow possesses detailed laboratory notebooks, catalyst samples, and technical expertise related to this past work. The National Renewable Energy Laboratory (NREL) is conducting R&D in support of the United States Department of Energy (DOE) to develop methods for economically producing ethanol from gasified biomass. NREL is currently conducting biomass gasification research at an existing 1/2 ton/day thermochemical test platform. Both Dow and NREL believe that the ability to economically produce ethanol from biomass-derived syngas can be enhanced through collaborative testing, refinement, and development of Dow's mixed-alcohol catalysts at NREL's and/or Dow's bench- and pilot-scale facilities. Dow and NREL further agree that collaboration on improvements in catalysts as well as gasifier operating conditions (e.g., time, temperature, upstream gas treatment) will be necessary to achieve technical and economic goals for production of ethanol and other alcohols.

  2. Research on Quality of Transaction Standards: The Maturity of a Research Topic1

    E-Print Network [OSTI]

    Boyer, Edmond

    a research gap which has been presented at the 6th International Conference on STANDARDIZATION and INNOVATION, often outside the traditional standard setting organizations (also called standard development organization). As standards are means to an end: interoperability. A general assumption is that a good standard

  3. "Nanocrystal bilayer for tandem catalysis"

    SciTech Connect (OSTI)

    Yamada, Yusuke; Tsung, Chia Kuang; Huang, Wenyu; Huo, Ziyang; E.Habas, Susan E; Soejima, Tetsuro; Aliaga, Cesar E; Samorjai, Gabor A; Yang, Peidong

    2011-01-24T23:59:59.000Z

    Supported catalysts are widely used in industry and can be optimized by tuning the composition and interface of the metal nanoparticles and oxide supports. Rational design of metal-metal oxide interfaces in nanostructured catalysts is critical to achieve better reaction activities and selectivities. We introduce here a new class of nanocrystal tandem catalysts that have multiple metal-metal oxide interfaces for the catalysis of sequential reactions. We utilized a nanocrystal bilayer structure formed by assembling platinum and cerium oxide nanocube monolayers of less than 10 nm on a silica substrate. The two distinct metal-metal oxide interfaces, CeO2-Pt and Pt-SiO2, can be used to catalyse two distinct sequential reactions. The CeO2-Pt interface catalysed methanol decomposition to produce CO and H2, which were subsequently used for ethylene hydroformylation catalysed by the nearby Pt-SiO2 interface. Consequently, propanal was produced selectively from methanol and ethylene on the nanocrystal bilayer tandem catalyst. This new concept of nanocrystal tandem catalysis represents a powerful approach towards designing high-performance, multifunctional nanostructured catalysts

  4. Nanocrystal assembly for tandem catalysis

    DOE Patents [OSTI]

    Yang, Peidong; Somorjai, Gabor; Yamada, Yusuke; Tsung, Chia-Kuang; Huang, Wenyu

    2014-10-14T23:59:59.000Z

    The present invention provides a nanocrystal tandem catalyst comprising at least two metal-metal oxide interfaces for the catalysis of sequential reactions. One embodiment utilizes a nanocrystal bilayer structure formed by assembling sub-10 nm platinum and cerium oxide nanocube monolayers on a silica substrate. The two distinct metal-metal oxide interfaces, CeO.sub.2--Pt and Pt--SiO.sub.2, can be used to catalyze two distinct sequential reactions. The CeO.sub.2--Pt interface catalyzed methanol decomposition to produce CO and H.sub.2, which were then subsequently used for ethylene hydroformylation catalyzed by the nearby Pt--SiO.sub.2 interface. Consequently, propanal was selectively produced on this nanocrystal bilayer tandem catalyst.

  5. Magnetic Catalysis vs Magnetic Inhibition

    E-Print Network [OSTI]

    Kenji Fukushima; Yoshimasa Hidaka

    2012-09-06T23:59:59.000Z

    We discuss the fate of chiral symmetry in an extremely strong magnetic field B. We investigate not only quark fluctuations but also neutral meson effects. The former would enhance the chiral-symmetry breaking at finite B according to the Magnetic Catalysis, while the latter would suppress the chiral condensate once B exceeds the scale of the hadron structure. Using a chiral model we demonstrate how neutral mesons are subject to the dimensional reduction and the low dimensionality favors the chiral-symmetric phase. We point out that this effect, the Magnetic Inhibition, can be a feasible explanation for recent lattice-QCD data indicating the decreasing behavior of the chiral-restoration temperature with increasing B.

  6. Lean NOx Catalysis Research and Development

    Broader source: Energy.gov (indexed) [DOE]

    temperature range, poorly selective (N 2 O) Zeolites (ex. Cu-ZSM-5) active, selective hydro-thermally unstable Metal oxides (ex. AgAl 2 O 3 ) highly selective, stable,...

  7. Basic Research Needs: Catalysis for Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    solar energy to electrical energy at acceptable low costs. Many of these third- generation solar conversion strategies require the fabrication of interdigitated...

  8. 2014 CHEMICAL REACTIONS AT SURFACES GORDON RESEARCH CONFERENCE AND GORDON RESEARCH SEMINAR (APRIL 28-MAY 3, 2013 - LES DIABLERETS CONFERENCE CENTER, LES DIABLERETS, SWITZERLAND)

    SciTech Connect (OSTI)

    Stair, Peter C.

    2013-02-03T23:59:59.000Z

    presentations on chemistry at solid and liquid surfaces of relevance to catalysis, synthesis, photochemistry, environmental science, and tribology. Topics include: Fundamental Surface Chemistry; Catalysis; Solid Liquid and Aerosol Interfaces; Surface Photochemistry; Synthesis of Surfaces; Environmental Interfaces; Hot Topics in Surface Chemical Reactions; Tribology; Gas-Surface Scattering and Reactions; Novel Materials and Environments.

  9. Catalysis-by-design impacts assessment

    SciTech Connect (OSTI)

    Fassbender, L L; Young, J K [Pacific Northwest Lab., Richland, WA (USA); Sen, R K [Sen (R.K.) and Associates, Washington, DC (USA)

    1991-05-01T23:59:59.000Z

    Catalyst researchers have always recognized the need to develop a detailed understanding of the mechanisms of catalytic processes, and have hoped that it would lead to developing a theoretical predictive base to guide the search for new catalysts. This understanding allows one to develop a set of hierarchical models, from fundamental atomic-level ab-initio models to detailed engineering simulations of reactor systems, to direct the search for optimized, efficient catalyst systems. During the last two decades, the explosions of advanced surface analysis techniques have helped considerably to develop the building blocks for understanding various catalytic reactions. An effort to couple these theoretical and experimental advances to develop a set of hierarchical models to predict the nature of catalytic materials is a program entitled Catalysis-by-Design (CRD).'' In assessing the potential impacts of CBD on US industry, the key point to remember is that the value of the program lies in developing a novel methodology to search for new catalyst systems. Industrial researchers can then use this methodology to develop proprietary catalysts. Most companies involved in catalyst R D have two types of ongoing projects. The first type, what we call market-driven R D,'' are projects that support and improve upon a company's existing product lines. Project of the second type, technology-driven R D,'' are longer term, involve the development of totally new catalysts, and are initiated through scientists' research ideas. The CBD approach will impact both types of projects. However, this analysis indicates that the near-term impacts will be on market-driven'' projects. The conclusions and recommendations presented in this report were obtained by the authors through personal interviews with individuals involved in a variety of industrial catalyst development programs and through the three CBD workshops held in the summer of 1989. 34 refs., 7 figs., 7 tabs.

  10. ISOTOPE METHODS IN HOMOGENEOUS CATALYSIS.

    SciTech Connect (OSTI)

    BULLOCK,R.M.; BENDER,B.R.

    2000-12-01T23:59:59.000Z

    The use of isotope labels has had a fundamentally important role in the determination of mechanisms of homogeneously catalyzed reactions. Mechanistic data is valuable since it can assist in the design and rational improvement of homogeneous catalysts. There are several ways to use isotopes in mechanistic chemistry. Isotopes can be introduced into controlled experiments and followed where they go or don't go; in this way, Libby, Calvin, Taube and others used isotopes to elucidate mechanistic pathways for very different, yet important chemistries. Another important isotope method is the study of kinetic isotope effects (KIEs) and equilibrium isotope effect (EIEs). Here the mere observation of where a label winds up is no longer enough - what matters is how much slower (or faster) a labeled molecule reacts than the unlabeled material. The most careti studies essentially involve the measurement of isotope fractionation between a reference ground state and the transition state. Thus kinetic isotope effects provide unique data unavailable from other methods, since information about the transition state of a reaction is obtained. Because getting an experimental glimpse of transition states is really tantamount to understanding catalysis, kinetic isotope effects are very powerful.

  11. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Broader source: Energy.gov (indexed) [DOE]

    rappe.pdf More Documents & Publications Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO Oxidation Catalysis in...

  12. UNCORRECTEDPROOF Applied Catalysis B: Environmental 793 (2000) 19

    E-Print Network [OSTI]

    Jardim, Wilson de Figueiredo

    2000-01-01T23:59:59.000Z

    UNCORRECTEDPROOF Applied Catalysis B: Environmental 793 (2000) 1­9 Catalyst deactivation in the gas;UNCORRECTEDPROOF 2 R.M. Alberici et al. / Applied Catalysis B: Environmental 793 (2000) 1­9 when photo-oxidizing 1

  13. Shining Light on Catalysis | Stanford Synchrotron Radiation Lightsourc...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shining Light on Catalysis Tuesday, July 19, 2011 - 4:38pm SSRL Conference Room 137-322 Jeroen A. van Bokhoven, Professor for Heterogeneous Catalysis Institute for Chemical and...

  14. Challenges for the application of quantum chemical calculations to problems in catalysis

    E-Print Network [OSTI]

    Bell, Alexis T.

    2004) A long-standing goal of researchers in the field of catalysis is to develop first-principles of a catalysed reaction occurring in a reactor given knowledge only of reactor configuration, catalyst accurate determinations of reactor performance given a set of rate parameters describing catalyst

  15. Catalysis by Supported Gold Nanoclusters D. Wayne Goodman

    E-Print Network [OSTI]

    Goodman, Wayne

    by the selective oxidation of propylene to propylene oxide by gold,[4] alkene and arene hydrogenation catalysis,[5

  16. Home Video Blog Research Topics Politics World Markets Policy Energy Tech History Religion Books Sports TweetTweet 5 Email | Print | 0 Comments | Share

    E-Print Network [OSTI]

    de Bivort, Benjamin

    Home Video Blog Research Topics Politics World Markets Policy Energy Tech History Religion Books. This is aberrant behavior, but the authors were not able to identify a genetic explanation for this

  17. Geometrically induced magnetic catalysis and critical dimensions

    E-Print Network [OSTI]

    Antonino Flachi; Kenji Fukushima; Vincenzo Vitagliano

    2015-02-21T23:59:59.000Z

    We discuss the combined effect of magnetic fields and geometry in interacting fermionic systems. At leading order in the heat-kernel expansion, the infrared singularity (that in flat space leads to the magnetic catalysis) is regulated by the chiral gap effect and the catalysis is deactivated by effect of the curvature. We discover that an infrared singularity may reappear from higher-order terms in the heat kernel expansion leading to a novel form of geometrically induced magnetic catalysis (absent in flat space). The dynamical mass squared is then modified not only due to the chiral gap effect by an amount proportional to the curvature, but also by a magnetic shift $\\propto (4-D)eB$ where $D$ represents the number of space-time dimensions. We argue that $D=4$ is a critical dimension across which the behaviour of the magnetic shift changes qualitatively.

  18. Geometrically induced magnetic catalysis and critical dimensions

    E-Print Network [OSTI]

    Flachi, Antonino; Vitagliano, Vincenzo

    2015-01-01T23:59:59.000Z

    We discuss the combined effect of magnetic fields and geometry in interacting fermionic systems. At leading order in the heat-kernel expansion, the infrared singularity (that in flat space leads to the magnetic catalysis) is regulated by the chiral gap effect and the catalysis is deactivated by effect of the curvature. We discover that an infrared singularity may reappear from higher-order terms in the heat kernel expansion leading to a novel form of geometrically induced magnetic catalysis (absent in flat space). The dynamical mass squared is then modified not only due to the chiral gap effect by an amount proportional to the curvature, but also by a magnetic shift $\\propto (4-D)eB$ where $D$ represents the number of space-time dimensions. We argue that $D=4$ is a critical dimension across which the behaviour of the magnetic shift changes qualitatively.

  19. Geometrically induced magnetic catalysis and critical dimensions

    E-Print Network [OSTI]

    Antonino Flachi; Kenji Fukushima; Vincenzo Vitagliano

    2015-04-27T23:59:59.000Z

    We discuss the combined effect of magnetic fields and geometry in interacting fermionic systems. At leading order in the heat-kernel expansion, the infrared singularity (that in flat space leads to the magnetic catalysis) is regulated by the chiral gap effect, and the catalysis is deactivated by the effect of the scalar curvature. We discover that an infrared singularity is found in higher-order terms that mix the magnetic field with curvature, and these lead to a novel form of geometrically induced magnetic catalysis. The dynamical mass squared is then modified not only due to the chiral gap effect by an amount proportional to the curvature, but also by a magnetic shift $\\propto (4-D)eB$, where $D$ represents the number of space-time dimensions. We argue that $D=4$ is a critical dimension across which the behavior of the magnetic shift changes qualitatively.

  20. Center for Catalysis at Iowa State University

    SciTech Connect (OSTI)

    Kraus, George A.

    2006-10-17T23:59:59.000Z

    The overall objective of this proposal is to enable Iowa State University to establish a Center that enjoys world-class stature and eventually enhances the economy through the transfer of innovation from the laboratory to the marketplace. The funds have been used to support experimental proposals from interdisciplinary research teams in areas related to catalysis and green chemistry. Specific focus areas included: • Catalytic conversion of renewable natural resources to industrial materials • Development of new catalysts for the oxidation or reduction of commodity chemicals • Use of enzymes and microorganisms in biocatalysis • Development of new, environmentally friendly reactions of industrial importance These focus areas intersect with barriers from the MYTP draft document. Specifically, section 2.4.3.1 Processing and Conversion has a list of bulleted items under Improved Chemical Conversions that includes new hydrogenation catalysts, milder oxidation catalysts, new catalysts for dehydration and selective bond cleavage catalysts. Specifically, the four sections are: 1. Catalyst development (7.4.12.A) 2. Conversion of glycerol (7.4.12.B) 3. Conversion of biodiesel (7.4.12.C) 4. Glucose from starch (7.4.12.D) All funded projects are part of a soybean or corn biorefinery. Two funded projects that have made significant progress toward goals of the MYTP draft document are: Catalysts to convert feedstocks with high fatty acid content to biodiesel (Kraus, Lin, Verkade) and Conversion of Glycerol into 1,3-Propanediol (Lin, Kraus). Currently, biodiesel is prepared using homogeneous base catalysis. However, as producers look for feedstocks other than soybean oil, such as waste restaurant oils and rendered animal fats, they have observed a large amount of free fatty acids contained in the feedstocks. Free fatty acids cannot be converted into biodiesel using homogeneous base-mediated processes. The CCAT catalyst system offers an integrated and cooperative catalytic system that performs both esterification (of free fatty acids) and transesterification (of soybean oil) in a one-pot fashion. This will allow the biodiesel producers to use the aforementioned cheap feedstocks without any pretreatment. In addition, the catalyst system is heterogeneous and is highly recyclable and reusable. Although markets currently exist for glycerin, concern is mounting that the price of glycerin may plummet to $.05 - $.10 per pound if future production exceeds demand. Developing a system to make high value chemicals such as 1,3-propanediol from the glycerin stream will add value for biodiesel producers who implement the new technology. Given the fact that both DuPont and Shell chemicals have announced the commercialization of two new PDO-based polymers, a rapid increase of market demand for a cheaper PDO source is very likely. 4. Comparison of actual accomplishments with goals and objectives From our progress reports, the four areas are: 1. Catalyst development (7.4.12.A) 2. Conversion of glycerol (7.4.12.B) 3. Conversion of biodiesel (7.4.12.C) 4. Glucose from starch (7.4.12.D)

  1. Preliminary draft research topics subject to revision prior to a solicitation being issued May 18, 2007

    E-Print Network [OSTI]

    (500,000 units). In addition, six sigma standards must be reached for fuel cell subsystems to achieve six sigma quality standards. Topic 1 Alternative Electrode Deposition Processes The current high volume cost targets for MEA manufacturing while achieving a six sigma standard. Applicant cost

  2. applied research sub-section: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Applied Science Graduate Research Ambassador Award Materials Science Websites Summary: of Engineering & Applied Science Graduate Research Ambassador Award Spring 2014 Application...

  3. anti-counterfeiting research program: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    offers world-class research Biology and Medicine Websites Summary: 12;The Michigan State University Neuroscience Ph.D. Program offers world-class research. In the...

  4. ISHHC XIII International Symposium on the Relations between Homogeneous and Heterogeneous Catalysis

    E-Print Network [OSTI]

    Somorjai Ed., G.A.

    2007-01-01T23:59:59.000Z

    Catalytic Processes Applied Catalysis A: General 221 (2001)Kamp, J.J.F. Scholten Applied Catalysis A. : General 89 (77. S. Xie, M. Qiao Applied Catalysis A: General 176 (1999)

  5. Nanoscale Advances in Catalysis and Energy Applications

    SciTech Connect (OSTI)

    Li, Yimin; Somorjai, Gabor A.

    2010-05-12T23:59:59.000Z

    In this perspective, we present an overview of nanoscience applications in catalysis, energy conversion, and energy conservation technologies. We discuss how novel physical and chemical properties of nanomaterials can be applied and engineered to meet the advanced material requirements in the new generation of chemical and energy conversion devices. We highlight some of the latest advances in these nanotechnologies and provide an outlook at the major challenges for further developments.

  6. USD Catalysis Group for Alternative Energy

    SciTech Connect (OSTI)

    James D. Hoefelmeyer, Ranjit Koodali, Grigoriy Sereda, Dan Engebretson, Hao Fong, Jan Puszynski, Rajesh Shende, Phil Ahrenkiel

    2012-03-13T23:59:59.000Z

    The South Dakota Catalysis Group (SDCG) is a collaborative project with mission to develop advanced catalysts for energy conversion with two primary goals: (1) develop photocatalytic systems in which polyfunctionalized TiO2 are the basis for hydrogen/oxygen synthesis from water and sunlight (solar fuels group), (2) develop new materials for hydrogen utilization in fuel cells (fuel cell group). In tandem, these technologies complete a closed chemical cycle with zero emissions.

  7. Blue Ruthenium Dimer Catalysis for Hydrogen Generation | Advanced...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed Blue Ruthenium Dimer Catalysis for Hydrogen Generation APRIL 15, 2013 Bookmark and Share Key...

  8. "Seeing" hydrogen atoms to unveil enzyme catalysis | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    "Seeing" hydrogen atoms to unveil enzyme catalysis Image shows nuclear density maps in the active site of DHFR where the catalytic group Asp27 and substrate folate have...

  9. Catalysis by Design - Theoretical and Experimental Studies of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lean NOx Traps - Microstructural Studies of Real World and Model Catalysts Catalysts via First Principles Catalysis by Design: Bridging the Gap between Theory and Experiments...

  10. Catalysis by Design: Bridging the Gap Between Theory and Experiments...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Between Theory and Experiments at Nanoscale Level Catalysis by Design: Bridging the Gap Between Theory and Experiments at Nanoscale Level Studies on a simple platinum-alumina...

  11. anglo-american research alliance: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Behavioral research, evaluations and behavior change initiatives. The Northwest Energy Efficiency Alliance (NEEA interest groups and energy efficiency industry...

  12. [Studies of supported hydrodesulfurization catalysis

    SciTech Connect (OSTI)

    Not Available

    1992-01-01T23:59:59.000Z

    Research progress is in three areas. First, correlation of the distribution of molybdenum oxidation states in reduced Mo/Al[sub 2]O[sub 3] catalysts with benzene hydrogenation activity. Second, the use of factor analysis curve-fitting to determine the distribution of molybdenum oxidation states educed Mo/TiO[sub 2] catalysts. Third, quantitative Raman and ESCA characterization of W/TiO[sub 2] catalysts.

  13. Neutrons for Catalysis: A Workshop on Neutron Scattering Techniques for Studies in Catalysis

    E-Print Network [OSTI]

    Pennycook, Steve

    -EM Fischer Tropsch Catalysis on Fe- or Co-catalysts, ,,CTL" Coal to Liquids ­ ,a rough (?) analogy #12;Peter Albers, AQ-EM Carbonaceous Deposits on Catalysts #12;Peter Albers, AQ-EM IINS on Coked Catalysts from Industrial Plants High-temperature and low-temperature cokes deposited on catalysts during

  14. australia trans-disciplinary research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: a Antarctic Climate and Ecosystems Cooperative Research Centre (ACE CRC), Hobart, Tasmania 7001, Australia b, Tasmania 7001, Australia c University of...

  15. all-russian scientific research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MPI programming in Python NumPy (SciPy) arrays Plotting in Python: - bar-charts, pie and processing (interpolation) 2 12;Advanced Research Computing About me ...

  16. Frontiers in Catalysis Science and Engineering Seminar Series

    E-Print Network [OSTI]

    Frontiers in Catalysis Science and Engineering Seminar Series "Frustrated Lewis Pairs": Metal and applied to develop metal-free hydrogenations for C=N bonds in a variety of organic substrates. In addition, alkynes, cyclopropanes, CO2 and N2O. The implications of the discovery of such systems to catalysis

  17. Periodic Solutions of a Nonlinear Evolution Problem from Heterogeneous Catalysis

    E-Print Network [OSTI]

    Bothe, Dieter

    Periodic Solutions of a Nonlinear Evolution Problem from Heterogeneous Catalysis Dieter Bothe for heterogeneous catalysis in a stirred multi-phase chemical reactor. Since the appearance of T-periodic feeds for this evolution problem are provided and applied to the class of reaction-diffusion systems mentioned above. AMS

  18. Frontiers in Catalysis Science and Engineering Seminar Series

    E-Print Network [OSTI]

    Frontiers in Catalysis Science and Engineering Seminar Series Heterogenized M-Salen Catalysts complexes are widely applied as catalysts for numerous important enantioselective reactions. The reactions catalysis (e.g. Co-salen for epoxide ring-opening or Al-salen conjugate additions of cyanide). The design

  19. Heterogeneous Catalysis DOI: 10.1002/anie.201209476

    E-Print Network [OSTI]

    Kik, Pieter

    Heterogeneous Catalysis DOI: 10.1002/anie.201209476 Trends in the Binding Strength of Surface? These questions are at the heart of many fundamental and practical problems, ranging from heterogeneous catalysis to important applied processes con- nected to materials science. In particular the interaction of oxygen

  20. Lithium Diisopropylamide-Mediated Enolization: Catalysis by Hemilabile Ligands

    E-Print Network [OSTI]

    Collum, David B.

    Lithium Diisopropylamide-Mediated Enolization: Catalysis by Hemilabile Ligands Antonio Ramirez of a lithium diisopropylamide (LDA)-mediated ester enolization. Hemilabile amino ether MeOCH2CH2NMe2, binding-based catalysis are thwarted by the occlusion of the catalyst on the lithium salt products and byproducts (eq 1

  1. Kokes Awards for the 22nd North American Catalysis Society Meeting, June 5-10, 2011

    SciTech Connect (OSTI)

    Fabio H. Ribeiro

    2011-06-05T23:59:59.000Z

    The biennial North American Catalysis Society (NACS) Meetings are the premiere conferences in the area of catalysis, surface science, and reaction engineering. The 22nd meeting will be held the week of June 5-10, 2011 in Detroit, Michigan. The objective of the Meetings is to bring together leading researchers for intensive scientific exchange and interactions. Financial support that offsets some of the associated costs (specifically, registration fee, airline tickets, and hotel accommodations) would encourage graduate students, and for the first time undergraduate students, to attend and participate meaningfully in this conference. The funds sought in this proposal will help support the Richard J. Kokes Travel Award program. Graduate students eligible for these merit-based Awards are those who study at a North American university and who will present at the Meeting. We have currently 209 applications and we expect to be able to fund about half of them. The NACS has traditionally sought to encourage graduate student, and this year for the first time undergraduate studies, participation at the National Meetings and providing financial support is the most effective means to do so. Their attendance would contribute significantly to their scientific training and communication and presentation skills. They would be exposed to the leading researchers from the US and abroad; they would meet their peers from other universities; they would learn about cutting-edge results that could benefit their research projects; and they may become interested in becoming active participants in the catalysis community. These young investigators represent the next generation of scientists and engineers, and their proper training will lead to future scientific breakthroughs and technological innovations that benefit the US economy. Advances in catalysis can come in the form of more energy-efficient and environmentally-friendly chemical processes, improved fuel cell performance, efficient hydrogen production, and a cleaner environment.

  2. Dynamic control of catalysis within biological cells

    E-Print Network [OSTI]

    Biman Jana; Biman Bagchi

    2011-05-26T23:59:59.000Z

    We develop a theory of enzyme catalysis within biological cells where the substrate concentration [S](t) is time dependent, in contrast to the Michaelis-Menten theory that assumes a steady state. We find that the time varying concentration can combine, in a non-linear way, with the ruggedness of the free energy landscape of enzymes (discovered both in single molecule studies and in simulations) to provide a highly efficient switch (or, bifurcation) between two catalytically active states, at a critical substrate concentration. This allows a dynamic control of product synthesis in cell.

  3. asia-oceania research organisation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    collected with the OPAL detector at LEP have been used to exclude a Standard Model Higgs boson (H 0EUROPEAN ORGANISATION FOR NUCLEAR RESEARCH CERN-PPE90-116 14 August 1990...

  4. FCH 495 Library Research Topics (for possible continuation as FCH 498)

    E-Print Network [OSTI]

    Chatterjee, Avik P.

    of research in the Abrams' group focuses on the synthesis and templating of inorganic materials using low 498 students: 1-2 students 1. Solvothermal Routes to Metastable Inorganic Template Materials One area synthetic strategy for low-temperature solvothermal synthesis of oxynitride compounds. 2. Novel Inorganic

  5. Special topic JPFR article "Prospects of Research on Innovative Concepts in ITER Era"

    E-Print Network [OSTI]

    Brown, Michael R.

    by M. Brown Section 5.2.2 5.2.2 Dynamo and Reconnection Research: Overview: Spheromaks undergo the relaxation process, dynamo activity can be studied in the spheromak configuration. A fully relaxed spheromak play in spheromaks. Reconnection: Magnetic reconnection [Priest and Forbes, 2007] is the process

  6. E.ON International Research Initiative 2012 topic: Smart Home a new customer relationship with energy

    E-Print Network [OSTI]

    Weyde, Tillman

    involving demand- side participation and dynamic pricing mechanisms. The research, modeling in creative workshops to help build a vision of their future energy supply and future energy services will manage the work. His academic colleagues at City University London are Professor Neil Maiden, Head

  7. Cooperative research in coal liquefaction infratechnology and generic technology development: Final report, October 1, 1985 to December 31, 1986

    SciTech Connect (OSTI)

    Sendlein, L.V.A.

    1987-06-29T23:59:59.000Z

    During the first year of its research program, the Consortium for Fossil Fuel Liquefaction Science has made significant progress in many areas of coal liquefaction and coal structure research. Research topics for which substantial progress has been made include integrated coal structure and liquefaction studies, investigation of differential liquefaction processes, development and application of sophisticated techniques for structural analysis, computer analysis of multivariate data, biodesulfurization of coal, catalysis studies, co-processing of coal and crude oil, coal dissolution and extraction processes, coal depolymerization, determination of the liquefaction characteristics of many US coals for use in a liquefaction database, and completion of a retrospective technology assessment for direct coal liquefaction. These and related topics are discussed in considerably more detail in the remainder of this report. Individual projects are processed separately for the data base.

  8. Sampling, preservation, and analytical methods research plan - liquid redox sulfur recovery technologies: Stretford process. Topical report

    SciTech Connect (OSTI)

    Trofe, T.W.

    1986-11-01T23:59:59.000Z

    GRI has developed a sampling, preservation, and analytical (SPandA) methods research plan for developing and validating analytical methodologies for liquid redox sulfur recovery processes (e.g., Stretford process). The document describes the technical approach which will be used to direct research activities to develop SPandA methodologies to analyze gaseous, aqueous, and solid process streams from the Stretford sulfur recovery process. The primary emphasis is on developing and validating methodologies for analyzing vanadium (IV) and vanadium (V), anthraquinone disulphonic acids (ADA), polysulfide-sulfur, sulfide-sulfur, thiosulfate, sulfate, thiocyanate, total soluble sulfur, alkalinity, pH, total dissolved solids, total suspended solids, and dissolved oxygen in aqueous process streams. The document includes descriptions of the process streams and chemical species, selection of candidate analytical methods, and technical approach for methods development and validation.

  9. Potential Collaborative Research topics with Korea’s Agency for Defense Development

    SciTech Connect (OSTI)

    Farrar, Charles R. [Los Alamos National Laboratory; Todd, Michael D. [Univ. of California, San Diego

    2012-08-23T23:59:59.000Z

    This presentation provides a high level summary of current research activities at the Los Alamos National Laboratory (LANL)-University of California Jacobs School of Engineering (UCSD) Engineering Institute that will be presented at Korea's Agency for Defense Development (ADD). These research activities are at the basic engineering science level with different level of maturity ranging from initial concepts to field proof-of-concept demonstrations. We believe that all of these activities are appropriate for collaborative research activities with ADD subject to approval by each institution. All the activities summarized herein have the common theme that they are multi-disciplinary in nature and typically involved the integration of high-fidelity predictive modeling, advanced sensing technologies and new development in information technology. These activities include: Wireless Sensor Systems, Swarming Robot sensor systems, Advanced signal processing (compressed sensing) and pattern recognition, Model Verification and Validation, Optimal/robust sensor system design, Haptic systems for large-scale data processing, Cyber-physical security for robots, Multi-source energy harvesting, Reliability-based approaches to damage prognosis, SHMTools software development, and Cyber-physical systems advanced study institute.

  10. Research Focus WorkatFEERCiscenteredonthreeinterrelated

    E-Print Network [OSTI]

    , and Emissions Research Center (FEERC) is a comprehensive laboratory for internal combustion engine technology synthetic and renewable sources. The FEERCconductsresearchoninnovativeinternal combustion engine-linear dynamics and controls · Engine controls · Combustion · Catalysis · Fuels · Emission control modeling

  11. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Laboratory U.S. Department of Energy Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Ken Rapp, Liyu Li, Jonathan Male, Dave King...

  12. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    D.C. acep03rappe.pdf More Documents & Publications Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO...

  13. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (OFCVT). deer07rappe.pdf More Documents & Publications Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO...

  14. Redox, haem and CO in enzymatic catalysis and regulation

    E-Print Network [OSTI]

    Ragsdale, Stephen W.

    The present paper describes general principles of redox catalysis and redox regulation in two diverse systems. The first is microbial metabolism of CO by the Wood–Ljungdahl pathway, which involves the conversion of CO or ...

  15. Theoretical investigation of solar energy conversion and water oxidation catalysis

    E-Print Network [OSTI]

    Wang, Lee-Ping

    2011-01-01T23:59:59.000Z

    Solar energy conversion and water oxidation catalysis are two great scientific and engineering challenges that will play pivotal roles in a future sustainable energy economy. In this work, I apply electronic structure ...

  16. Frontiers in Catalysis Science and Engineering Materials Science

    E-Print Network [OSTI]

    Frontiers in Catalysis Science and Engineering Materials Science Chemical Imaging Date: May 13 the quality of human life but also critical to our survival. To power the planet for a better future

  17. Catalysis Working Group Kick-Off Meeting Agenda

    Broader source: Energy.gov [DOE]

    Agenda for the kick-off meeting of the U.S. Department of Energy Fuel Cell Technologies Program's Catalysis Working Group, held May 14, 2012, in Arlington, Virginia.

  18. The 2013 Clusters, Nanocrystals & Nanostructures Gordon Research Conference/Gordon Research Seminar

    SciTech Connect (OSTI)

    Krauss, Todd D. [University of Rochester

    2014-11-25T23:59:59.000Z

    The fundamental properties of small particles and their potential for groundbreaking applications are among the most exciting areas of study in modern physics, chemistry, and materials science. The Clusters, Nanocrystals & Nanostructures Gordon ResearchConference and Gordon Research Seminar synthesize contributions from these inter-related fields that reflect the pivotal role of nano-particles at the interface between these disciplines. Size-dependent optical, electronic, magnetic and catalytic properties offer prospects for applications in many fields, and possible solutions for many of the grand challenges facing energy generation, consumption, delivery, and storage in the 21st century. The goal of the 2013 Clusters, Nanocrystals & Nanostructures Gordon Research Conference and Gordon Research Seminar is to continue the historical interdisciplinary tradition of this series and discuss the most recent advances, basic scientific questions, and emerging applications of clusters, nanocrystals, and nanostructures. The Clusters, Nanocrystals & Nanostructures GRC/GRS traditionally brings together the leading scientific groups that have made significant recent advances in one or more fundamental nanoscience or nanotechnology areas. Broad interests of the DOE BES and Solar Photochemistry Program addressed by this meeting include the areas of solar energy to fuels conversion, new photovoltaic systems, fundamental characterization of nanomaterials, magnetism, catalysis, and quantum physics. The vast majority of speakers and attendees will address either directly the topic of nanotechnology for photoinduced charge transfer, charge transport, and catalysis, or will have made significant contributions to related areas that will impact these fields indirectly. These topics have direct relevance to the mission of the DOE BES since it is this cutting-edge basic science that underpins our energy future.

  19. Basic research opportunities to support LNG technology. Topical report, July 1989-December 1990

    SciTech Connect (OSTI)

    Groten, B.

    1991-03-01T23:59:59.000Z

    As additional gas reserves come on production during the next decade in areas with limited local markets, worldwide LNG trade is expected to expand. The availability of dedicated LNG tankers may well determine the rate at which this growth occurs. Plans are being made now to bring the four U.S. import terminals up to capacity during this period. As LNG becomes a more significant factor in the domestic natural gas market, consideration should be given to applications other than simply regassifying and comingling it with other supplies entering the pipeline grid. The higher energy density and the low temperature of LNG offer opportunities for expanding the use of natural gas into the industrial and transportation sectors. Greater use of LNG in peak shaving and intermediate storage may also provide benefits in increased reliability and performance of the gas transmission and distribution grid. In order to provide new and more cost-effective technologies to respond to these opportunities, it is recommended that GRI broaden the range of research it is currently performing on LNG.

  20. Lead Research and Development Activity for DOE's High Temperature, Low Relative Humidity Membrane Program (Topic 2)

    SciTech Connect (OSTI)

    James Fenton, PhD; Darlene Slattery, PhD; Nahid Mohajeri, PhD

    2012-09-05T23:59:59.000Z

    The Department of Energy’s High Temperature, Low Relative Humidity Membrane Program was begun in 2006 with the Florida Solar Energy Center (FSEC) as the lead organization. During the first three years of the program, FSEC was tasked with developing non-Nafion® proton exchange membranes with improved conductivity for fuel cells. Additionally, FSEC was responsible for developing protocols for the measurement of in-plane conductivity, providing conductivity measurements for the other funded teams, developing a method for through-plane conductivity and organizing and holding semiannual meetings of the High Temperature Membrane Working Group (HTMWG). The FSEC membrane research focused on the development of supported poly[perfluorosulfonic acid] (PFSA) – Teflon membranes and a hydrocarbon membrane, sulfonated poly(ether ether ketone). The fourth generation of the PFSA membrane (designated FSEC-4) came close to, but did not meet, the Go/No-Go milestone of 0.1 S/cm at 50% relative humidity at 120 °C. In-plane conductivity of membranes provided by the funded teams was measured and reported to the teams and DOE. Late in the third year of the program, DOE used this data and other factors to decide upon the teams to continue in the program. The teams that continued provided promising membranes to FSEC for development of membrane electrode assemblies (MEAs) that could be tested in an operating fuel cell. FSEC worked closely with each team to provide customized support. A logic flow chart was developed and discussed before MEA fabrication or any testing began. Of the five teams supported, by the end of the project, membranes from two of the teams were easily manufactured into MEAs and successfully characterized for performance. One of these teams exceeded performance targets, while the other requires further optimization. An additional team developed a membrane that shows great promise for significantly reducing membrane costs and increasing membrane lifetime.

  1. Lean NOx Trap Catalysis for Lean Natural Gas Engine Applications

    SciTech Connect (OSTI)

    Parks, II, James E [ORNL; Storey, John Morse [ORNL; Theiss, Timothy J [ORNL; Ponnusamy, Senthil [ORNL; Ferguson, Harley Douglas [ORNL; Williams, Aaron M [ORNL; Tassitano, James B [ORNL

    2007-09-01T23:59:59.000Z

    Distributed energy is an approach for meeting energy needs that has several advantages. Distributed energy improves energy security during natural disasters or terrorist actions, improves transmission grid reliability by reducing grid load, and enhances power quality through voltage support and reactive power. In addition, distributed energy can be efficient since transmission losses are minimized. One prime mover for distributed energy is the natural gas reciprocating engine generator set. Natural gas reciprocating engines are flexible and scalable solutions for many distributed energy needs. The engines can be run continuously or occasionally as peak demand requires, and their operation and maintenance is straightforward. Furthermore, system efficiencies can be maximized when natural gas reciprocating engines are combined with thermal energy recovery for cooling, heating, and power applications. Expansion of natural gas reciprocating engines for distributed energy is dependent on several factors, but two prominent factors are efficiency and emissions. Efficiencies must be high enough to enable low operating costs, and emissions must be low enough to permit significant operation hours, especially in non-attainment areas where emissions are stringently regulated. To address these issues the U.S. Department of Energy and the California Energy Commission launched research and development programs called Advanced Reciprocating Engine Systems (ARES) and Advanced Reciprocating Internal Combustion Engines (ARICE), respectively. Fuel efficiency and low emissions are two primary goals of these programs. The work presented here was funded by the ARES program and, thus, addresses the ARES 2010 goals of 50% thermal efficiency (fuel efficiency) and <0.1 g/bhp-hr emissions of oxides of nitrogen (NOx). A summary of the goals for the ARES program is given in Table 1-1. ARICE 2007 goals are 45% thermal efficiency and <0.015 g/bhp-hr NOx. Several approaches for improving the efficiency and emissions of natural gas reciprocating engines are being pursued. Approaches include: stoichiometric engine operation with exhaust gas recirculation and three-way catalysis, advanced combustion modes such as homogeneous charge compression ignition, and extension of the lean combustion limit with advanced ignition concepts and/or hydrogen mixing. The research presented here addresses the technical approach of combining efficient lean spark-ignited natural gas combustion with low emissions obtained from a lean NOx trap catalyst aftertreatment system. This approach can be applied to current lean engine technology or advanced lean engines that may result from related efforts in lean limit extension. Furthermore, the lean NOx trap technology has synergy with hydrogen-assisted lean limit extension since hydrogen is produced from natural gas during the lean NOx trap catalyst system process. The approach is also applicable to other lean engines such as diesel engines, natural gas turbines, and lean gasoline engines; other research activities have focused on those applications. Some commercialization of the technology has occurred for automotive applications (both diesel and lean gasoline engine vehicles) and natural gas turbines for stationary power. The research here specifically addresses barriers to commercialization of the technology for large lean natural gas reciprocating engines for stationary power. The report presented here is a comprehensive collection of research conducted by Oak Ridge National Laboratory (ORNL) on lean NOx trap catalysis for lean natural gas reciprocating engines. The research was performed in the Department of Energy's ARES program from 2003 to 2007 and covers several aspects of the technology. All studies were conducted at ORNL on a Cummins C8.3G+ natural gas engine chosen based on industry input to simulate large lean natural gas engines. Specific technical areas addressed by the research include: NOx reduction efficiency, partial oxidation and reforming chemistry, and the effects of sulfur poisons on the partial oxidation

  2. Applied Catalysis B: Environmental 140141 (2013) 468477 Contents lists available at SciVerse ScienceDirect

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    2013-01-01T23:59:59.000Z

    Applied Catalysis B: Environmental 140­141 (2013) 468­477 Contents lists available at SciVerse ScienceDirect Applied Catalysis B: Environmental journal homepage: www

  3. Some General Themes in Catalysis at LANL

    SciTech Connect (OSTI)

    Gordon, John C. [Los Alamos National Laboratory

    2012-07-19T23:59:59.000Z

    Some general themes in catalysis at LANL are: (1) Storage and release of energy within chemical bonds (e.g. H{sub 2} storage in and release from covalent bonds, N{sub 2} functionalization, CO{sub 2} functionalization, H{sub 2} oxidation/evolution, O{sub 2} reduction/evolution); (2) Can we control the chemistry of reactive substrates to effect energy relevant transformations in non-traditional media (e.g. can we promote C-C couplings, dehydrations, or hydrogenations in water under relatively mild conditions)? (3) Can we supplant precious metal or rare earth catalysts to effect these transformations, by using earth abundant metals/elements instead? Can we use organocatalysis and circumvent the use of metals completely? (4) Can we improve upon existing rare earth catalyst systems (e.g. in rare earth oxides pertinent to fluid cracking or polymerization) and reduce amounts required for catalytic efficacy? Carbohydrates can be accessed from non-food based biomass sources such as woody residues and switchgrass. After extracted from the plant source, our goal is to upgrade these classes of molecules into useful fuels.

  4. E-Print Network 3.0 - alkane oxidation catalysis Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hydrogen... Reforming of Methane 10 Gas Phase Incorporation of Pd onto Iron-Ceria Aerogels for Water Gas Shift Catalysis... at the 20 North American Meeting of the Catalysis...

  5. Applied Catalysis A: General 243 (2003) 1524 On the potential role of hydroxyl groups in

    E-Print Network [OSTI]

    Marks, Laurence D.

    2003-01-01T23:59:59.000Z

    Applied Catalysis A: General 243 (2003) 15­24 On the potential role of hydroxyl groups in CO.K. Costello et al. / Applied Catalysis A: General 243 (2003) 15­24 sensitivity may also account, in part

  6. Applied Catalysis A: General 392 (2011) 5768 Contents lists available at ScienceDirect

    E-Print Network [OSTI]

    Auerbach, Scott M.

    2011-01-01T23:59:59.000Z

    Applied Catalysis A: General 392 (2011) 57­68 Contents lists available at ScienceDirect Applied Catalysis A: General journal homepage: www.elsevier.com/locate/apcata Liquid phase aldol condensation

  7. GTPase Catalysis by Ras and Other G-proteins: Insights from Substrate Directed SuperImposition

    E-Print Network [OSTI]

    Kosloff, Mickey

    GTPase Catalysis by Ras and Other G-proteins: Insights from Substrate Directed Super usage of similar approaches to comparison of enzyme catalytic machineries. We applied SDSI to various G catalysis; GTPase; guanine nucleotides; conformational rearrangement; structure comparison

  8. Applied Catalysis B: Environmental 105 (2011) 5060 Contents lists available at ScienceDirect

    E-Print Network [OSTI]

    Frenkel, Anatoly

    2011-01-01T23:59:59.000Z

    Applied Catalysis B: Environmental 105 (2011) 50­60 Contents lists available at ScienceDirect Applied Catalysis B: Environmental journal homepage: www.elsevier.com/locate/apcatb Cobalt

  9. This issue of Topics in Catalysis is devoted to ``Nanotechnology in Catalysis'' and covers some of the

    E-Print Network [OSTI]

    Resasco, Daniel

    silica, catalyst supports and catalytic membranes. Nanosized hollow spheres (silica or carbon) have been crystal structures, electronic configurations, or surface compositions that can only be obtained with nano of Nanotechnology. A well-known advan- tage of reducing particle size is the increase in surface area per unit

  10. Gold(I)-Mediated Nucleophilic Additions to Allenes: from Enantioselective Catalysis to Supramolecular Chemistry

    E-Print Network [OSTI]

    Wang, Zhan

    2012-01-01T23:59:59.000Z

    supramolecular catalysis where the capsule itself serves as a molecular reaction vessel, product can bind competitively with the starting material.

  11. ISHHC XIII International Symposium on the Relations between Homogeneous and Heterogeneous Catalysis

    E-Print Network [OSTI]

    Somorjai Ed., G.A.

    2007-01-01T23:59:59.000Z

    K. Lee Semiconductor Photocatalysis in Advanced Oxidationthermal) catalysis or photocatalysis on nanoporous supportswith Heterogeneous Photocatalysis using Nanostructured

  12. Applied Catalysis A: General 391 (2011) 342349 Contents lists available at ScienceDirect

    E-Print Network [OSTI]

    Goodman, Wayne

    2011-01-01T23:59:59.000Z

    Applied Catalysis A: General 391 (2011) 342­349 Contents lists available at ScienceDirect Applied Catalysis A: General journal homepage: www.elsevier.com/locate/apcata Preparation and characterization of Co in the last several decades due to their practical applications in many industrial areas such as catalysis

  13. Applied Catalysis B: Environmental 29 (2001) 327336 Gas-phase photo-oxidation of toluene using

    E-Print Network [OSTI]

    2001-01-01T23:59:59.000Z

    Applied Catalysis B: Environmental 29 (2001) 327­336 Gas-phase photo-oxidation of toluene using reserved. PII: S0926-3373(00)00211-3 #12;328 A.J. Maira et al. / Applied Catalysis B: Environmental 29.V. All rights reserved. Keywords: Photo-catalysis; Titanium dioxide; Nanoparticles; Volatile organic

  14. Heterodimerization of Olefins. 1. Hydrovinylation Reactions of Olefins That Are Amenable to Asymmetric Catalysis

    E-Print Network [OSTI]

    RajanBabu, T. V. "Babu"

    , 151. (b) Chauvin, Y.; Olivier, H. Dimerization and Codimerization. In Applied Homogeneous Catalysis) Jolly, P. W.; Wilke, G. Hydrovinylation. In Applied Homoge- neous Catalysis with Organometallic to Asymmetric Catalysis T. V. RajanBabu,* Nobuyoshi Nomura, Jian Jin, Malay Nandi, Haengsoon Park, and Xiufeng

  15. Applied Catalysis A: General 477 (2014) 102108 Contents lists available at ScienceDirect

    E-Print Network [OSTI]

    Cao, Guozhong

    2014-01-01T23:59:59.000Z

    Applied Catalysis A: General 477 (2014) 102­108 Contents lists available at ScienceDirect Applied Catalysis A: General journal homepage: www.elsevier.com/locate/apcata Ordered mesoporous tungsten carbide, in particular, catalysis [21­24]. A key issue for improving this class of meso- porous structure

  16. DOI: 10.1002/ijch.201100102 Single-Molecule Studies of HIV-1 Protease Catalysis

    E-Print Network [OSTI]

    Myong, Sua

    DOI: 10.1002/ijch.201100102 Single-Molecule Studies of HIV-1 Protease Catalysis Enabled by Chemical. Introduction Understanding the chemistry of enzyme catalysis has been an important objective of chemical of the chemistry occurring in the enzyme­substrate complex. The physical organic chemistry of enzyme catalysis

  17. Exhaust aftertreatment using plasma-assisted catalysis

    SciTech Connect (OSTI)

    Penetrante, B

    2000-01-20T23:59:59.000Z

    In the field of catalysis, one application that has been classified as a breakthrough technology is the catalytic reduction of NO{sub x} in oxygen-rich environments using hydrocarbons. This breakthrough will require dramatic improvements in both catalyst and engine technology, but the benefits will be substantial for energy efficiency and a cleaner environment. Engine and automobile companies are placing greater emphasis on the diesel engine because of its potential for saving fuel resources and reducing CO{sub 2} emissions. The modern direct-injection diesel engine offers demonstrated fuel economy advantages unmatched by any other commercially-viable engine. The main drawback of diesel engines is exhaust emissions. A modification of existing oxidation catalyst/engine technology is being used to address the CO, hydrocarbon and particulates. However, no satisfactory solution currently exists for NO{sub x}. Diesel engines operate under net oxidizing conditions, thus rendering conventional three-way catalytic converters ineffective for the controlling the NO{sub x} emission. NO{sub x} reduction catalysts, using ammonia as a reductant, do exist for oxygen-rich exhausts; however, for transportation applications, the use of on-board hydrocarbon fuels is a more feasible, cost-effective, and environmentally-sound approach. Selective catalytic reduction (SCR) by hydrocarbons is one of the leading catalytic aftertreatment technologies for the reduction of NO{sub x} in lean-burn engine exhaust (often referred to as lean-NO{sub x}). The objective is to chemically reduce the pollutant molecules of NO{sub x} to benign molecules such as N{sub 2}. Aftertreatment schemes have focused a great deal on the reduction of NO because the NO{sub x} in engine exhaust is composed primarily of NO. Recent studies, however, have shown that the oxidation of NO to NO{sub 2} serves an important role in enhancing the efficiency for reduction of NO{sub x} to N{sub 2}. It has become apparent that preconverting NO to NO{sub 2} could improve both the efficiency and durability of lean-NO{sub x} catalysts. A non-thermal plasma is an efficient means for selective partial oxidation of NO to NO{sub 2}. The use of a non-thermal plasma in combination with a lean-NO{sub x} catalyst opens the opportunity for catalysts that are more efficient and more durable compared to conventional catalysts. In the absence of hydrocarbons, the O radicals will oxidize NO to NO{sub 2}, and the OH radicals will further oxidize NO{sub 2} to nitric acid. In plasma-assisted catalysis it is important that the plasma oxidize NO to NO{sub 2} without further producing acids.

  18. High-Spin Cobalt Hydrides for Catalysis

    SciTech Connect (OSTI)

    Holland, Patrick L. [Yale University] [Yale University

    2013-08-29T23:59:59.000Z

    Organometallic chemists have traditionally used catalysts with strong-field ligands that give low-spin complexes. However, complexes with a weak ligand field have weaker bonds and lower barriers to geometric changes, suggesting that they may lead to more rapid catalytic reactions. Developing our understanding of high-spin complexes requires the use of a broader range of spectroscopic techniques, but has the promise of changing the mechanism and/or selectivity of known catalytic reactions. These changes may enable the more efficient utilization of chemical resources. A special advantage of cobalt and iron catalysts is that the metals are more abundant and cheaper than those currently used for major industrial processes that convert unsaturated organic molecules and biofeedstocks into useful chemicals. This project specifically evaluated the potential of high-spin cobalt complexes for small-molecule reactions for bond rearrangement and cleavage reactions relevant to hydrocarbon transformations. We have learned that many of these reactions proceed through crossing to different spin states: for example, high-spin complexes can flip one electron spin to access a lower-energy reaction pathway for beta-hydride elimination. This reaction enables new, selective olefin isomerization catalysis. The high-spin cobalt complexes also cleave the C-O bond of CO2 and the C-F bonds of fluoroarenes. In each case, the detailed mechanism of the reaction has been determined. Importantly, we have discovered that the cobalt catalysts described here give distinctive selectivities that are better than known catalysts. These selectivities come from a synergy between supporting ligand design and electronic control of the spin-state crossing in the reactions.

  19. Enantioselective Alkenylation of Aldehydes with Boronic Acids via the Synergistic Combination of Copper(II) and Amine Catalysis

    E-Print Network [OSTI]

    MacMillan, David W. C.

    recently applied the synergistic catalysis paradigm to the development of several new asymmetric bond of Copper(II) and Amine Catalysis Jason M. Stevens and David W. C. MacMillan* Merck Center for Catalysis combination of copper and chiral amine catalysis. The merger of two highly utilized and robust catalytic

  20. Pre-Competitive Catalysis Research: Fundamental Sulfation/Desulfation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    D.C. ace033toops2010o.pdf More Documents & Publications Emissions Control for Lean Gasoline Engines Functionality of Commercial NOx Storage-Reduction Catalysts and the...

  1. Lean NOx Catalysis Research and Development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment ofLetter Report:40PMDepartment ofs o u t h e a s t e rtheNOx

  2. Pre-Competitive Catalysis Research: Fundamental Sulfation/Desulfation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of Contamination in235-1Department of60Powersubsidiary

  3. Allylation of acetanilides with allyl acetate under conditions of metal-complex catalysis combined with phase-transfer catalysis

    SciTech Connect (OSTI)

    Lebedev, S.A.; Leonova, Yu.P.; Berestova, S.S.; Petrov, E.S.

    1988-10-20T23:59:59.000Z

    Acetanilides are alkylated at the nitrogen atom under the conditions of phase-transfer catalysis. For the case of the reaction of acetanilides with allyl acetate the authors showed that 2-alkenyl esters can be used for the alkylation of acetanilides under the conditions of phase-transfer catalysis in the presence of the complexes of zero valent palladium. N-Acetylskatole was obtained with a yield of 50% from N-allyl-2-bromoacetanilide by intramolecular cyclization in the presence of Od(OAc)/sub 2/ as catalyst.

  4. Frontiers in Catalysis Science and Engineering Seminar Series

    E-Print Network [OSTI]

    in internal combustion engines and power plants. Copper-exchanged promising as selective catalytic reduction ) are a major atmospheric pollutant produced through the combustion of fossil fuels in internal combustionFrontiers in Catalysis Science and Engineering Seminar Series Small Pore Zeolites: Effective

  5. Homogeneous Catalysis Selective Oxidation of Methane to Methanol

    E-Print Network [OSTI]

    Goddard III, William A.

    Homogeneous Catalysis Selective Oxidation of Methane to Methanol Catalyzed, with CÀH Activation (generated by dissolution[6] of Au2O3) react with methane at 1808C to selectively generate methanol (as a mixture of the ester and methanol) in high yield (Table 1, entries 1 and 2). As expected, the irreversible

  6. Frontiers in Catalysis Science and Engineering Seminar Series

    E-Print Network [OSTI]

    Frontiers in Catalysis Science and Engineering Seminar Series On the role of hydrogen of Chemical & Biological Engineering ·University of Wisconsin - Madison Abstract Hydrogen is a frequent principles governing the role of hydrogen in a wide range of catalytic transformations begin to emerge

  7. Overview of surface science and catalysis by Qifei Wu

    E-Print Network [OSTI]

    of hydrodesulfurization catalysis Crude oil contains S-impurity (R-S; environmental hazard) H2 + R-S RH + H2S catalyst P. Hydrodesulfurization (HDS) on metcar nanoparticles C4H4S(g) +3H2(g) C4H8(g) +H2S(g) According to our DFT calculations

  8. Lithium Diisopropylamide-Mediated Ortholithiations: Lithium Chloride Catalysis

    E-Print Network [OSTI]

    Collum, David B.

    Lithium Diisopropylamide-Mediated Ortholithiations: Lithium Chloride Catalysis Lekha Gupta, 2008 Ortholithiations of a range of arenes mediated by lithium diisopropylamide (LDA) in THF at -78 °C protocols with unpurified commercial samples of n-butyl- lithium to prepare LDA or commercially available

  9. JOURNAL OF CATALYSIS 177, 343351 (1998) ARTICLE NO. CA982143

    E-Print Network [OSTI]

    Iglesia, Enrique

    1998-01-01T23:59:59.000Z

    - modynamically favorable at high temperatures, but often leads to high yields of coke and smaller hydrocarbons, but it requires a selective catalyst in order to avoid complete oxidation to CO and CO2. A number of recentJOURNAL OF CATALYSIS 177, 343­351 (1998) ARTICLE NO. CA982143 Structure and Properties of Vanadium

  10. paper topics

    E-Print Network [OSTI]

    2013-03-10T23:59:59.000Z

    The final paper must be about 10 pages long, written in Latex, and on a topic ... The topic must be chosen by March 21st, a first draft (which must be complete) is.

  11. Nanomaterials Engineering and Applications in Catalysis

    E-Print Network [OSTI]

    Zhang, Qiao

    2012-01-01T23:59:59.000Z

    75 Although direct photocatalysis utilizing such plasmoniclittle investigated. In photocatalysis research, anatase TiOthe perspective of photocatalysis, there are also several

  12. SOUTHWEST CATALYSIS SOCIETY 2006 SPRING SYMPOSIUM

    E-Print Network [OSTI]

    Natelson, Douglas

    XIAO TOTAL PETROCHEMICALS USA, INC. RESEARCH & TECHNOLOGY CENTER Deer Park, TX 77536 (281) 884 in Methane Reactions Catalyzed by Supported Metal Clusters" 8:50 AM Dr. Jon G. McCarty, Catalytica Energy

  13. Selective catalysis utilizing bifunctionalized MCM-41 mesoporous materials

    SciTech Connect (OSTI)

    Strosahl, Kasey Jean

    2005-05-01T23:59:59.000Z

    Selective catalysis is a field that has been under intense investigation for the last 100 years. The most widely used method involves catalysts with stereochemical selectivity. In this type of catalysis, the catalyst controls which reactants will be transformed into the desired product. The secret to employing this type of catalysis, though, is to design the proper catalyst, which can be difficult. One may spend as much time developing the catalyst as spent separating the various products achieved. Another method of selective catalysis is now being explored. The method involves utilizing a multifunctional mesoporous silica catalyst with a gate-keeping capability. Properly functionalized mesoporous materials with well-defined pore morphology and surface properties can provide an ideal three-dimensional environment for anchoring various homogeneous catalysts. These materials can circumvent the multi-sited two-dimensional nature most heterogeneous systems have without adversely impacting the reactant diffusivity. These single-site nanostructured catalysts with ordered geometrical structure are advantageous in achieving high selectivity and reactivity. Mesoporous materials can be prepared to include pores lined homogeneously with tethered catalysts via co-condensation. Additionally, these materials can be reacted with another (RO){sub 3}Si{approx}Z group by using the traditional grafting method; this group is anchored predominantly at the entrances to the pores rather than inside the pores. Thus, if these {approx}Z groups are chosen properly, they can select certain molecules to enter the pores and be converted to products (Scheme 1). In such multifunctional catalysts, the selectivity depends on the discrimination of the gatekeeper. Gate-keeping MCM-41 materials are at the forefront of catalytic substances.

  14. Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2002deeraardahl.pdf More Documents & Publications Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated Lean NOx Catalysis Selective reduction of NOx in...

  15. Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    Lean NOx Catalysis l Chemistry l Reducing Agent Effects l Collaboration with LEP CRADA l Aging Studies Plasma Initiation - + Electron Avalanche e - e - e - e - e - e - e -...

  16. Photocatalysis Currently, the research

    E-Print Network [OSTI]

    Vollmer, Heribert

    Photocatalysis Currently, the research activit in the area ofies Photocatalysis focus on the topics Photocatalysis and Prof. Dr. Detlef Bahnemann Nanotechnology Research Topics Bioprocess Engineering Bioprocess Modeling and Control Photocatalysis and Nanotechnology Institute of Technical Chemistry Contact Person

  17. Materials research at selected Japanese laboratories. Based on a 1992 visit: Overview, summary of highlights, notes on laboratories and topics

    SciTech Connect (OSTI)

    Not Available

    1994-02-01T23:59:59.000Z

    I visited Japan from June 29 to August 1, 1992. The purpose of this visit was to assess the status of materials science research at selected governmental, university and industrial laboratories and to established acquaintances with Japanese researchers. The areas of research covered by these visits included ceramics, oxide superconductors, intermetallics alloys, superhard materials and diamond films, high-temperature materials and properties, mechanical properties, fracture, creep, fatigue, defects, materials for nuclear reactor applications and irradiation effects, high pressure synthesis, self-propagating high temperature synthesis, microanalysis, magnetic properties and magnetic facilities, and surface science.

  18. Summary of selected topics from G. J. Babu's Research G. J. Babu has diverse research interests in both statistics and probability, and their applications to

    E-Print Network [OSTI]

    Babu, G. Jogesh

    in both statistics and probability, and their applications to problems in biomedical research, Population Engineering's (SPIE) Symposium on Optical Science and Technology) in San Diego, in August 2001 on Statistical Inference is under preparation. Inter-disciplinary research and activities: Since late 1980's, G

  19. Applied Catalysis A: General 232 (2002) 219235 An EXAFS study of the co-ordination chemistry of hydrogen

    E-Print Network [OSTI]

    Regalbuto, John R.

    2002-01-01T23:59:59.000Z

    Applied Catalysis A: General 232 (2002) 219­235 An EXAFS study of the co-ordination chemistry)00116-3 #12;220 W.A. Spieker et al. / Applied Catalysis A: General 232 (2002) 219­235 dissociation

  20. [Studies of supported hydrodesulfurization catalysis]. Progress report

    SciTech Connect (OSTI)

    Not Available

    1991-12-31T23:59:59.000Z

    Research progress to be reviewed here will be in three areas. First, correlation of the distribution of molybdenum oxidation states in reduced Mo/Al{sub 2}O{sub 3} catalysts with benzene hydrogenation activity. Second, the use of factor analysis curve-fitting to determine the distribution of molybdenum oxidation states in reduced Mo/TiO{sub 2} catalysts. Third, quantitative Raman and ESCA characterization of W/TiO{sub 2} catalysts.

  1. [Studies of supported hydrodesulfurization catalysis]. Progress report

    SciTech Connect (OSTI)

    Not Available

    1992-12-01T23:59:59.000Z

    Research progress is in three areas. First, correlation of the distribution of molybdenum oxidation states in reduced Mo/Al{sub 2}O{sub 3} catalysts with benzene hydrogenation activity. Second, the use of factor analysis curve-fitting to determine the distribution of molybdenum oxidation states educed Mo/TiO{sub 2} catalysts. Third, quantitative Raman and ESCA characterization of W/TiO{sub 2} catalysts.

  2. Removal of Toluene in Air by Non Thermal Plasma-Catalysis Hybrid , H. T. Pham

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Removal of Toluene in Air by Non Thermal Plasma-Catalysis Hybrid System A. Khacef , H. T. Pham , A Orléans Cedex 02, France * Institute of Applied Material Science, VAST, 1 Mac Dinh Chi, HCMC, Vietnam with heterogeneous catalysts. This combination can be either single-stage (in-plasma catalysis, IPC) or two

  3. Probing the chemistry of thioredoxin catalysis Arun P. Wiita1,2

    E-Print Network [OSTI]

    Fernandez, Julio M.

    LETTERS Probing the chemistry of thioredoxin catalysis with force Arun P. Wiita1,2 , Raul Perez organisms1 . Although catalysis is thought to proceed through a substitution nucleophilic bimolecular (SN2 (Trx). We applied mechanical force in the range of 25­600 pN to a disulphide bond substrate

  4. Advanced Synthesis & Catalysis Terminal alkyne metathesis: a further step towards selectivity.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Advanced Synthesis & Catalysis Terminal alkyne metathesis: a further step towards selectivity 320436585 E-mail: andre.mortreux@ensc-lille.fr , Received alkyne / metathesis / catalysis / carbyne,[2] the latter giving rise to much more active catalysts, allowing the reaction to be applied

  5. Amine a-heteroarylation via photoredox catalysis: a homolytic aromatic substitution pathway

    E-Print Network [OSTI]

    MacMillan, David W. C.

    Amine a-heteroarylation via photoredox catalysis: a homolytic aromatic substitution pathway accomplished via photoredox catalysis to generate valuable benzylic amine pharmacophores. A variety of five substitution (SNAr)3 or transi- tion metal-catalyzed approaches,4 have been extensively studied and applied

  6. Applied Catalysis A: General 226 (2002) 183192 NO reduction by urea under lean conditions

    E-Print Network [OSTI]

    Gulari, Erdogan

    2002-01-01T23:59:59.000Z

    Applied Catalysis A: General 226 (2002) 183­192 NO reduction by urea under lean conditions over.V. All rights reserved. PII: S0926-860X(01)00901-2 #12;184 E. Seker et al. / Applied Catalysis A: General

  7. Journal of Catalysis 260 (2008) 342350 Contents lists available at ScienceDirect

    E-Print Network [OSTI]

    Regalbuto, John R.

    2008-01-01T23:59:59.000Z

    Journal of Catalysis 260 (2008) 342­350 Contents lists available at ScienceDirect Journal of Catalysis www.elsevier.com/locate/jcat The synthesis of highly dispersed noble and base metals on silica via The catalyst synthesis method of strong electrostatic adsorption (SEA) was applied to mesoporous silica SBA-15

  8. Journal of Catalysis 260 (2008) 329341 Contents lists available at ScienceDirect

    E-Print Network [OSTI]

    Regalbuto, John R.

    2008-01-01T23:59:59.000Z

    Journal of Catalysis 260 (2008) 329­341 Contents lists available at ScienceDirect Journal of Catalysis www.elsevier.com/locate/jcat The synthesis of highly dispersed noble and base metals on silica via and after reduction. The results showed that the SEA method can be applied for many ammine complexes

  9. Z .Journal of Molecular Catalysis A: Chemical 153 2000 155163 www.elsevier.comrlocatermolcata

    E-Print Network [OSTI]

    Truong, Thanh N.

    Z .Journal of Molecular Catalysis A: Chemical 153 2000 155­163 www and Applied Chemistry, Chemistry Department, Faculty of Science, Kasetsart UniÕersity, Bangkok 10900, Thailand. q 2000 Elsevier Science B.V. All rights reserved. 1. Introduction Zeolite catalysis is of prime

  10. Bifunctional Lewis Acid-Nucleophile-Based Asymmetric Catalysis: Mechanistic Evidence for Imine Activation Working

    E-Print Network [OSTI]

    Lectka, Thomas

    Bifunctional Lewis Acid-Nucleophile-Based Asymmetric Catalysis: Mechanistic Evidence for Imine that substantial progress has been made in the use of well- defined bifunctional systems as applied to asymmetric catalysis.4 Several of these systems combine a metal ion (usually as part of a chiral Lewis acid complex

  11. Tandem Catalysis A Highly Efficient and Rapid Approach to Synthetic Elaboration

    E-Print Network [OSTI]

    Stoltz, Brian M.

    diiodide catalyzed Mukaiyama Michael-aldol reactions C.) Zirconium catalyzed synthesis of !-cyanohydrins D and rhodium catalyzed annulation. B.) Cobalt catalyzed annulation and cycloaddition C.) Rapid synthesis of pyrroles and furans D.) Organocatalytic / Lewis acid tandem catalysis 5.) Conclusions Tandem catalysis

  12. Single-molecule enzymology of RNA: Essential functional groups impact catalysis from a distance

    E-Print Network [OSTI]

    Walter, Nils G.

    Single-molecule enzymology of RNA: Essential functional groups impact catalysis from a distance the site of catalysis have on the individual rate constants. We find that all ribozyme variants show rate constants. This leads to heterogeneous cleavage activity as com- monly observed for RNA enzymes

  13. Physica A 249 (1998) 558564 Mutual catalysis in sets of prebiotic

    E-Print Network [OSTI]

    Pilpel, Yitzhak

    1998-01-01T23:59:59.000Z

    Physica A 249 (1998) 558­564 Mutual catalysis in sets of prebiotic organic molecules : Evolution on the origin of life needs to delineate a chemically rigorous, self-consistent path from highly heterogeneous Replication Domain (GARD) model for explicit kinetic analysis of mutual catalysis in sets of random oligomers

  14. 2013 INORGANIC REACTION MECHANISMS GORDON RESEARCH CONFERENCE (MARCH 3-8, 2013 - HOTEL GALVEZ, GALVESTON TX)

    SciTech Connect (OSTI)

    Abu-Omar, Mahdi M.

    2012-12-08T23:59:59.000Z

    The 2013 Gordon Conference on Inorganic Reaction Mechanisms will present cutting-edge research on the molecular aspects of inorganic reactions involving elements from throughout the periodic table and state-of-the art techniques that are used in the elucidation of reaction mechanisms. The Conference will feature a wide range of topics, such as homogeneous and heterogeneous catalysis, metallobiochemistry, electron-transfer in energy reactions, polymerization, nitrogen fixation, green chemistry, oxidation, solar conversion, alkane functionalization, organotransition metal chemistry, and computational chemistry. The talks will cover themes of current interest including energy, materials, and bioinorganic chemistry. Sections cover: Electron-Transfer in Energy Reactions; Catalytic Polymerization and Oxidation Chemistry; Kinetics and Spectroscopy of Heterogeneous Catalysts; Metal-Organic Chemistry and its Application in Synthesis; Green Energy Conversion;Organometallic Chemistry and Activation of Small Molecules; Advances in Kinetics Modeling and Green Chemistry; Metals in Biology and Disease; Frontiers in Catalytic Bond Activation and Cleavage.

  15. Inorganic Chemistry in Hydrogen Storage and Biomass Catalysis

    SciTech Connect (OSTI)

    Thorn, David [Los Alamos National Laboratory

    2012-06-13T23:59:59.000Z

    Making or breaking C-H, B-H, C-C bonds has been at the core of catalysis for many years. Making or breaking these bonds to store or recover energy presents us with fresh challenges, including how to catalyze these transformations in molecular systems that are 'tuned' to minimize energy loss and in molecular and material systems present in biomass. This talk will discuss some challenging transformations in chemical hydrogen storage, and some aspects of the inorganic chemistry we are studying in the development of catalysts for biomass utilization.

  16. Catalysis Science | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C o . C lKieling ,Catalysis Science Chemical

  17. Theoretical Study on Catalysis by Protein Enzymes and Ribozyme

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in theTheoretical Study on Catalysis by Protein Enzymes

  18. Catalysis Working Group Meeting: June 2014 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof Energy Change RequestFirstchampions, checklists,CaseyCatalysis Working

  19. Catalysis Working Group Meeting: May 2013 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof Energy Change RequestFirstchampions, checklists,CaseyCatalysis

  20. Catalysis by Design - Theoretical and Experimental Studies of Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof Energy Change RequestFirstchampions, checklists,CaseyCatalysisCatalysts

  1. Catalysis | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurTheBrookhaven National Laboratory Laboratory Policy (LP) LPCMSNFScienceCatalysis

  2. UNC EFRC: Fuels from Sunlight (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    ScienceCinema (OSTI)

    Meyer, Thomas J. (Director, UNC EFRC: Solar Fuels and Next Generation Photovoltaics); UNC EFRC Staff

    2011-11-02T23:59:59.000Z

    'Fuels from Sunlight' was submitted by the University of North Carolina (UNC) EFRC: Solar Fuels and Next Generation Photovoltaics to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. The UNC EFRC directed by Thomas J. Meyer is a partnership of scientists from six institutions: UNC (lead), Duke University, University of Florida, North Caroline Central University, North Carolina State University, and the Research Triangle Institute. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of Solar Fuels and Next Generation Photovoltaics is 'to combine the best features of academic and translational research to study light/matter interactions and chemical processes for the efficient collection, transfer, and conversion of solar energy into chemical fuels and electricity.' Research topics are: catalysis (CO{sub 2}, hydrocarbons, water), electrocatalysis, photocatalysis, photoelectrocatalysis, solar photovoltaic, solar fuels, photonic, solar electrodes, photosynthesis, fuel cells, CO{sub 2} (convert), greenhosue gas, hydrogen (fuel), interfacial characterization, novel materials synthesis, charge transport, and self-assembly.

  3. Scaleup tests and supporting research for the development of duct injection technology. Topical report No. 1, Literature review

    SciTech Connect (OSTI)

    Gooch, J.P.; Dismukes, E.B.; Dahlin, R.S.; Faulkner, M.G. [Southern Research Inst., Birmingham, AL (United States); Klett, M.G.; Buchanan, T.L.; Hunt, J.E. [Gilbert/Commonwealth, Inc., Reading, PA (United States)

    1989-05-01T23:59:59.000Z

    Gilbert Commonwealth, Southern Research Institute and the American Electric Power Service Corporation have embarked on a program to convert DOE`s Duct Injection Test Facility located at the Muskingum River Power Plant of Ohio Power Company to test alternate duct injection technologies. The technologies to be tested include slurry sorbent injection of hydrated lime using dual fluid nozzles, or a rotary atomizer and pneumatic injection of hydrated lime, with flue gas humidification before or after sorbent injection. The literature review and analysis contained in this report is a part of the preparatory effort for the test program.

  4. Nuclear Physics: Experiment Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    UserResearcher Information print version Research Highlights Public Interest Nuclear Physics Accelerator Free Electron Laser (FEL) Medical Imaging Physics Topics Campaigns...

  5. accessing integrated genomic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Last Page Topic Index 1 RESEARCH ARTICLE Open Access Integrating cytogenetics and genomics in Environmental Sciences and Ecology Websites Summary: RESEARCH ARTICLE Open Access...

  6. acid-assisted phosphine catalysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Washington University School of Medicine, 660 S. Euclid Avenue, St. Louis, MO 63110 Marshall, Garland R. 37 Catalytic Hydrogenolysis of Biphenylene with Platinum, Palladium,...

  7. Proceedings of the Twenty-First Water Reactor Safety Information Meeting: Volume 1, Plenary session; Advanced reactor research; advanced control system technology; advanced instrumentation and control hardware; human factors research; probabilistic risk assessment topics; thermal hydraulics; thermal hydraulic research for advanced passive LWRs

    SciTech Connect (OSTI)

    Monteleone, S. [Brookhaven National Lab., Upton, NY (United States)] [comp.

    1994-04-01T23:59:59.000Z

    This three-volume report contains 90 papers out of the 102 that were presented at the Twenty-First Water Reactor Safety Information Meeting held at the Bethesda Marriott Hotel, Bethesda, Maryland, during the week of October 25--27, 1993. The papers are printed in the order of their presentation in each session and describe progress and results of programs in nuclear safety research conducted in this country and abroad. Foreign participation in the meeting included papers presented by researchers from France, Germany, Japan, Russia, Switzerland, Taiwan, and United Kingdom. The titles of the papers and the names of the authors have been updated and may differ from those that appeared in the final program of the meeting. Individual papers have been cataloged separately. This document, Volume 1 covers the following topics: Advanced Reactor Research; Advanced Instrumentation and Control Hardware; Advanced Control System Technology; Human Factors Research; Probabilistic Risk Assessment Topics; Thermal Hydraulics; and Thermal Hydraulic Research for Advanced Passive Light Water Reactors.

  8. Search for the ANSER (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum

    ScienceCinema (OSTI)

    Wasielewski, Michael R. (Director, Argonne-Northwestern Solar Energy Research Center); ANSER Staff

    2011-11-02T23:59:59.000Z

    'Search for the ANSER' was submitted by the Argonne-Northwestern Solar Energy Research Center (ANSER) to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. ANSER, an EFRC directed by Michael Wasielewski at Argonne National Laboratory is a partnership of scientists from five institutions: Argonne National Laboratory, Northwestern University, University of Chicago, University of Illinois at Urbana-Champaign, and Yale. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. At ANSER, the mission is 'to revolutionize our understanding of molecules, materials and methods necessary to create dramatically more efficient technologies for solar fuels and electricity production.' Research topics are: catalysis (water), electrocatalysis, photocatalysis, photoelectrocatalysis, solar photovoltaic, solar fuels, solar electrodes, photosynthesis, transportation fuels, bio-inspired, spin dynamics, hydrogen (fuel), ultrafast physics, interfacial characterization, matter by design, novel materials synthesis, charge transport, and self-assembly.

  9. Cooperative research in coal liquefaction

    SciTech Connect (OSTI)

    Huffman, G.P.; Sendlein, L.V.A. (eds.)

    1991-05-28T23:59:59.000Z

    Significant progress was made in the May 1990--May 1991 contract period in three primary coal liquefaction research areas: catalysis, structure-reactivity studies, and novel liquefaction processes. A brief summary of the accomplishments in the past year in each of these areas is given.

  10. a-007 topical gel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Description Engineering Websites Summary: , separations science, chemical catalysis and coatings science. By definition the sol-gel process starts materials. The resulting films,...

  11. The Fluid Interface Reactions Structures and Transport (FIRST) EFRC (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    SciTech Connect (OSTI)

    Wesolowski, David J. (Director, FIRST - Fluid Interface Reactions, Structures, and Transport Center) [Director, FIRST - Fluid Interface Reactions, Structures, and Transport Center; FIRST Staff

    2011-05-01T23:59:59.000Z

    'The Fluid Interface Reactions Structures and Transport (FIRST) EFRC' was submitted by FIRST to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. FIRST, an EFRC directed by David J. Wesolowski at the Oak Ridge National Laboratory is a partnership of scientists from nine institutions: Oak Ridge National Laboratory (lead), Argonne National Laboratory, Drexel University, Georgia State University, Northwestern University, Pennsylvania State University, Suffolk University, Vanderbilt University, and University of Virginia. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of Fluid Interface Reactions, Structures and Transport Center is 'to develop quantitative and predictive models of the unique nanoscale environment at fluid-solid interfaces that will enable transformational advances in electrical energy storage and heterogeneous catalysis for solar fuels.' Research topics are: catalysis (biomass, CO{sub 2}, water), electrocatalysis, photocatalysis, photoelectrocatalysis, solar fuels, solar electrodes, electrical energy storage, batteries, capacitors, battery electrodes, electrolytes, extreme environment, CO{sub 2} (convert), greenhouse gas, microelectromechanical systems (MEMS), interfacial characterization, matter by design, novel materials synthesis, and charge transport.

  12. The Fluid Interface Reactions Structures and Transport (FIRST) EFRC (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    ScienceCinema (OSTI)

    Wesolowski, David J. (Director, FIRST - Fluid Interface Reactions, Structures, and Transport Center); FIRST Staff

    2011-11-02T23:59:59.000Z

    'The Fluid Interface Reactions Structures and Transport (FIRST) EFRC' was submitted by FIRST to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. FIRST, an EFRC directed by David J. Wesolowski at the Oak Ridge National Laboratory is a partnership of scientists from nine institutions: Oak Ridge National Laboratory (lead), Argonne National Laboratory, Drexel University, Georgia State University, Northwestern University, Pennsylvania State University, Suffolk University, Vanderbilt University, and University of Virginia. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of Fluid Interface Reactions, Structures and Transport Center is 'to develop quantitative and predictive models of the unique nanoscale environment at fluid-solid interfaces that will enable transformational advances in electrical energy storage and heterogeneous catalysis for solar fuels.' Research topics are: catalysis (biomass, CO{sub 2}, water), electrocatalysis, photocatalysis, photoelectrocatalysis, solar fuels, solar electrodes, electrical energy storage, batteries, capacitors, battery electrodes, electrolytes, extreme environment, CO{sub 2} (convert), greenhouse gas, microelectromechanical systems (MEMS), interfacial characterization, matter by design, novel materials synthesis, and charge transport.

  13. Spontaneous generation of local CP violation and inverse magnetic catalysis

    E-Print Network [OSTI]

    Lang Yu; Hao Liu; Mei Huang

    2014-09-14T23:59:59.000Z

    In the chiral symmetric phase, the polarized instanton--anti-instanton molecule pairing induces a nontrivial repulsive interaction in the iso-scalar axial-vector channel. As a consequence, one unusual property is observed that in the chiral restoration phase, there is a first order phase transition for the spontaneous generation of local CP violation and chiral imbalance. Furthermore, it is found that external magnetic fields will lower the critical temperature for the local CP-odd phase transition and catalyze the chiral imbalance, which destroys the chiral condensate with pairing quarks between different chiralities. A reasonable strength of the repulsive interaction in the iso-scalar axial-vector channel can naturally explain the inverse magnetic catalysis around the critical temperature under external magnetic fields.

  14. Metal Carbonyl-Hydrosilane Reactions and Hydrosilation Catalysis

    SciTech Connect (OSTI)

    Cutler, A. R.

    2001-04-14T23:59:59.000Z

    Manganese carbonyl complexes serve as hydrosilation precatalysts for selectively transforming a carbonyl group into a siloxy methylene or a fully reduced methylene group. Substrates of interest include (1) aldehydes, ketones, carboxylic acids, silyl esters, and esters, and (2) their organometallic acyl counterparts. Three relevant catalytic reactions are shown. Two types of manganese precatalysts have been reported: (a) alkyl and acyl complexes (L)(C0){sub 4}MnR [L = CO, PPh{sub 3}; R = COCH{sub 3}, COPh, CH{sub 3}] and (b) halides (CO){sub 5}MnX and [(CO){sub 4}MnX]{sub 2} (X = Br, I). The former promote hydrosilation and deoxygenation catalysis; the latter promote dehydrogenative silation of alcohols and carboxylic acids as well as hydrosilation and deoxygenation of some metallocarboxylic acid derivatives. In every case studied, these Mn precatalysts are far more reactive or selective than traditional Rh(I) precatalysts.

  15. Saving the Sun for a Rainy Day (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    ScienceCinema (OSTI)

    Bullock, R. Morris (Director, Center for Molecular Electrocatalysis); CME Staff

    2011-11-02T23:59:59.000Z

    'Saving the Sun for a Rainy Day' was submitted by the Center for Molecular Electrocatalysis (CME) to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. CME, an EFRC directed by R. Morris Bullock at Pacific Northwest National Laboratory is a partnership of scientists from four institutions: PNNL (lead), Pensylvania State University, University of Washington, and the University of Wyoming. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of the Center for Molecular Electrocatalysis is 'to understand, design and develop molecular electrocatalysts for solar fuel production and use.' Research topics are: catalysis (water), electrocatalysis, bio-inspired, electrical energy storage, fuel cells, hydrogen (fuel), matter by design, novel materials synthesis, and charge transport.

  16. Studies toward biomimetic claisen condensation using nucleic acid templates and ribozyme catalysis

    E-Print Network [OSTI]

    Ryu, Youngha

    2005-08-29T23:59:59.000Z

    Many different experimental approaches were attempted to achieve carbon-carbon bond formation by nucleic acid template-directed reactions and ribozyme catalysis as potential lipid synthesizing machineries in the RNA world. A novel biomimetic...

  17. Two-Stage Plasma-Catalysis for Diesel NOx Emission Control. ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    producing nitrogen. Citation: Hoard J, and RG Tonkyn.2003."Two-Stage Plasma-Catalysis for Diesel NOx Emission Control."Journal of Advanced Oxidation Technologies 6(2):158-165....

  18. Molecular computations for reactions and phase transitions: applications to protein stabilization, hydrates and catalysis

    E-Print Network [OSTI]

    Anderson, Brian J.

    In this work we have made significant contributions in three different areas of interest: therapeutic protein stabilization, thermodynamics of natural gas clathrate-hydrates, and zeolite catalysis. In all three fields, ...

  19. Argonne Researchers | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Researchers Name Topic - Any - General Argonne Information -Awards -Honors Energy -Energy efficiency --Vehicles ---Alternative fuels ---Automotive engineering ---Biofuels...

  20. Analytical modeling of the interaction of enzyme catalysis and diffusion processes at the intracellular level

    E-Print Network [OSTI]

    Faith, Duane Willbern

    1977-01-01T23:59:59.000Z

    ANALYTICAL MODELING OF THE INTERACTION OF ENZYME CATALYSIS AND DIFFUSION PROCESSES AT THE INTRACELLULAR LEVEL A Thesis by Duane Nillbern Faith Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE May 1977 Major Subject: Bioengineering ANALYTICAL MODELING OF THE INTERACTION OF ENZYME CATALYSIS AND DIFFUSION PROCESSES AT THE INTRACELLULAR LEVEL A Thesis by Duane Willbern Faith Approved as to style and content by...

  1. Studies of the relationship of protein structure to regulation and catalysis in tyrosine hydroxylase

    E-Print Network [OSTI]

    Sura, Giri Raju

    2007-09-17T23:59:59.000Z

    STUDIES OF THE RELATIONSHIP OF PROTEIN STRUCTURE TO REGULATION AND CATALYSIS IN TYROSINE HYDROXYLASE A Dissertation by GIRI RAJU SURA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of DOCTOR OF PHILOSOPHY May 2006 Major Subject: Biochemistry STUDIES OF THE RELATIONSHIP OF PROTEIN STRUCTURE TO REGULATION AND CATALYSIS IN TYROSINE HYDROXYLASE A Dissertation by GIRI RAJU...

  2. Final Report on Kokes Awards for the 20th North American Catalysis Society Meeting

    SciTech Connect (OSTI)

    Wong, Michael S

    2008-12-31T23:59:59.000Z

    This Final Report describes how the Kokes Awards program was carried out for the 2007 meeting with regard to selection of students and disbursement of funds received from DOE and other sources. The objective of the Richard J. Kokes Travel Award program of the American Catalysis Society is to encourage graduate students to attend and participate meaningfully in the biennial North American Catalysis Society Meeting.

  3. The Behavior of Hydrogen Under Extreme Conditions on Ultrafast Timescales (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    ScienceCinema (OSTI)

    Mao, Ho-kwang (Director, Center for Energy Frontier Research in Extreme Environments); EFree Staff

    2011-11-02T23:59:59.000Z

    'The Behavior of Hydrogen Under Extreme Conditions on Ultrafast Timescales ' was submitted by the Center for Energy Frontier Research in Extreme Environments (EFree) to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. EFree is directed by Ho-kwang Mao at the Carnegie Institute of Washington and is a partnership of scientists from thirteen institutions.The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of Energy Frontier Research in Extreme Environments is 'to accelerate the discovery and creation of energy-relevant materials using extreme pressures and temperatures.' Research topics are: catalysis (CO{sub 2}, water), photocatalysis, solid state lighting, optics, thermelectric, phonons, thermal conductivity, solar electrodes, fuel cells, superconductivity, extreme environment, radiation effects, defects, spin dynamics, CO{sub 2} (capture, convert, store), greenhouse gas, hydrogen (fuel, storage), ultrafast physics, novel materials synthesis, and defect tolerant materials.

  4. E-Mobility Research Network Prof. Dr.-Ing. Dietmar Ghlich

    E-Print Network [OSTI]

    Berlin,Technische Universität

    E-Mobility Research Network Prof. Dr.- Ing. Dietmar Göhlich #12;Research Area Energy Storage and Conversion E-Mobility Research Network | TU Berlin Page 2 #12;E-Mobility Research Network | TU Berlin Page 3 Chemical Engineering, Electrochemical Catalysis E-Mobility Research Interests and Competencies 1. Hydrogen

  5. ENVS 340: Topics in Pollution: Gulf Oil Spill Spring 2011

    E-Print Network [OSTI]

    ENVS 340: Topics in Pollution: Gulf Oil Spill Spring 2011 ENVS 340 Topics in Pollution: Gulf Oil Oil Spill based on scientific research. Our report is due ~May 8. Our first goal is to determine with their instructors as soon as possible to discuss their needs. #12;ENVS 340/BIOL 378: Topics in Pollution Spring 2011

  6. Applied Catalysis A: General 192 (2000) 227234 Hydrogen production via the direct cracking of methane over Ni/SiO2

    E-Print Network [OSTI]

    zur Loye, Hans-Conrad

    2000-01-01T23:59:59.000Z

    Applied Catalysis A: General 192 (2000) 227­234 Hydrogen production via the direct cracking al. / Applied Catalysis A: General 192 (2000) 227­234 to be the diffusion of carbon through the metal

  7. Journal of Catalysis 191, 4654 (2000) doi:10.1006/jcat.1999.2798, available online at http://www.idealibrary.com on

    E-Print Network [OSTI]

    Androulakis, Ioannis (Yannis)

    2000-01-01T23:59:59.000Z

    high-temperature processes based on heterogeneous catalysis may involve homogeneous gas-phase reactionsJournal of Catalysis 191, 46­54 (2000) doi:10.1006/jcat.1999.2798, available online at http

  8. SELECTIVE REDUCTION OF NOX IN OXYGEN RICH ENVIRONMENTS WITH PLASMA-ASSISTED CATALYSIS: CATALYST DEVELOPMENT AND MECHANISTIC STUDIES

    SciTech Connect (OSTI)

    Peden, C; Barlow, S; Hoard, J; Kwak, J; *Balmer-Millar, M; *Panov, A; Schmieg, S; Szanyi, J; Tonkyn, R

    2003-08-24T23:59:59.000Z

    The control of NOx (NO and NO2) emissions from so-called ''lean-burn'' vehicle engines remains a challenge. In recent years, there have been a number of reports that show that a plasma device combined with a catalyst can reduce as high as 90% or more of NOx in simulated diesel and other ''lean-burn'' exhaust. In the case of propylene containing simulated diesel exhaust, the beneficial role of a plasma treatment is now thought to be due to oxidation of NO to NO2, and the formation of partially oxidized hydrocarbons that are more active for the catalytic reduction of NO2 than propylene. Thus, the overall system can be most usefully described as hydrocarbon selective catalytic reduction (SCR) enhanced by 'reforming' the exhaust with a non-thermal plasma (NTP) device. For plasma-enhanced catalysis, both zeolite- and alumina-based materials have shown high activity, albeit in somewhat different temperature ranges, when preceded by an NTP reactor. This paper will briefly describe our research efforts aimed at optimizing the catalyst materials for NTP-catalysis devices based, in part, on our continuing studies of the NTP- and catalytic-reaction mechanisms. Various alkali- and alkaline earth-cation-exchanged Y zeolites have been prepared, their material properties characterized, and they have been tested as catalytic materials for NOx reduction in laboratory NTP-catalysis reactors. Interestingly, NO2 formed in the plasma and not subsequently removed over these catalysts, will back-convert to NO, albeit to varying extents depending upon the nature of the cation. Besides this comparative reactivity, we will also discuss selected synthesis strategies for enhancing the performance of these zeolite-based catalyst materials. A particularly important result from our mechanistic studies is the observation that aldehydes, formed during the plasma treatment of simulated diesel exhaust, are the important species for the reduction of NOx to N2. Indeed, acetaldehyde has been found to be especially effective in the thermal reduction of both NO and NO2 over Ba- and Na-Y zeolite catalysts.

  9. animal breeding chemical: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    approach (Vygotsky, 1978) to teaching. This type of example can also be used in other courses involving topics such as genetic and animal improvement. If the research is...

  10. advanced digestive endoscopy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sets are topics of research. Virtual endoscopy is a promising new technique to explore hollow organs and anatomical cavities. The fields of application are manifold... Anna...

  11. accelerator facility complex: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topic Index 1 Complex workplace radiation fields at European high-energy accelerators and thermonuclear fusion facilities CERN Preprints Summary: This report outlines the research...

  12. acid gaba deficits: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    21 22 23 24 25 Next Page Last Page Topic Index 41 Investigating Binding Deficits in Dyslexia Edinburgh, University of - Research Archive Summary: Working Memory deficits have...

  13. acinetobacter baumannii infection: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    25 Next Page Last Page Topic Index 1 Diversity of acinetobacter baumannii isolates from Egypt Edinburgh, University of - Research Archive Summary: Acinetobacter baumannii is an...

  14. acinetobacter baumannii infections: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    25 Next Page Last Page Topic Index 1 Diversity of acinetobacter baumannii isolates from Egypt Edinburgh, University of - Research Archive Summary: Acinetobacter baumannii is an...

  15. acute subtentorial hematoma: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    vessel rupture is the major diagnosis have become popular research topics. For traumatic brain injury (TBI), head computed tomography Tan, Chew Lim 8 Open Access Airway Compromise...

  16. atrial septal hematoma: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    vessel rupture is the major diagnosis have become popular research topics. For traumatic brain injury (TBI), head computed tomography Tan, Chew Lim 14 Fast block flow tracking of...

  17. advanced scientific computing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    22 23 24 25 Next Page Last Page Topic Index 1 Advanced Scientific Computing Research Computer Science Plasma Physics and Fusion Websites Summary: Advanced Scientific Computing...

  18. asthmatic childrens health: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2008-01-01 7 Economics 845: New Research in Health and Mental Health Economics: Children, Health Care Policy towards Children and Related Topics Multidisciplinary Databases and...

  19. Overview of GRI research at the Rock Creek Site, Black Warrior Basin. Overview of GRI research at Rock Creek: Eight years of cooperative research, coalbed methane shortcourse. Held in Birmingham, Alabama on October 21, 1992. Topical report

    SciTech Connect (OSTI)

    Schraufnagel, R.

    1992-10-01T23:59:59.000Z

    The presentation slides from the October 21, 1992 workshop on coalbed methane exploration and production are assembled in this volume. They illustrate the following discussions Overview of GRI Research at Rock Creek: Eight Years of Cooperative Research, Drilling and Completing Coalbed to the Formation: Perforations vs. Slotting, Coalbed Methane Well Testing in the Warrior Basin, Reservoir Engineering: A Case Study at Rock Creek, Fraccing of Multiple Thin Seams: Considerations and Constraints, Implementing Coal Seam Stimulations: Requirements for Successful Treatments, Coal-Fluid Interactions, Mine-Through Observations of Coal Seam Stimulations: Reality vs. Theory, and Improving Gas Production: Techniques of Operations.

  20. Overview of GRI research at the Rock Creek Site, Black Warrior Basin. Overview of GRI research at Rock Creek: Eight years of cooperative research, coalbed methane shortcourse. Held in Abingdon, Virginia on October 23, 1992. Topical report

    SciTech Connect (OSTI)

    Schraufnagel, R.

    1992-10-01T23:59:59.000Z

    The presentation slides from the October 23, 1992 workshop on coalbed methane exploration and production are assembled in this volume. They illustrate the following discussions: Overview of GRI Research at Rock Creek: Eight Years of Cooperative Research, Drilling and Completing Coalbed Methane Wells: Techniques for Fragile Formations, Connecting the Wellborne to the Formation: Perforations vs. Slotting, Coalbed Methane Well Testing in the Warrior Basin, Reservoir Engineering: A Case Study at Rock Creek, Fraccing of Multiple Thin Seams: Considerations and Constraints, Implementing Coal Seam Stimulations: Requirements for Successful Treatments, Coal-Fluid Interactions, Mine-Through Observations of Coal Seam Stimulations: Reality vs. Theory, and Recompleting Coalbed Methane Wells: The Second Try at Success.

  1. Interactive Topic Modeling

    E-Print Network [OSTI]

    Pleple, Quentin

    26 Interactive LDA . . . . . . . . . . . . . . . .and B. Satinoff (2011). Interactive topic modeling. InOF CALIFORNIA, SAN DIEGO Interactive Topic Modeling A thesis

  2. Asymmetric Catalysis on Sequentially-Linked Columns Ahmed M. Hafez, Andrew E. Taggi, Travis Dudding, and Thomas Lectka*

    E-Print Network [OSTI]

    Lectka, Thomas

    Asymmetric Catalysis on Sequentially-Linked Columns Ahmed M. Hafez, Andrew E. Taggi, Travis Dudding of a series of "reaction columns". This process was applied to the catalytic asymmetric synthesis of -lactams that they conduct chemical reactions. In regard to chiral synthesis and drug discovery, asymmetric catalysis1

  3. Catalysis of Protein Disulfide Bond Isomerization in a Homogeneous Substrate Elizabeth A. Kersteen,, Seth R. Barrows, and Ronald T. Raines*,,|

    E-Print Network [OSTI]

    Raines, Ronald T.

    Catalysis of Protein Disulfide Bond Isomerization in a Homogeneous Substrate Elizabeth A. Kersteen in these assays are, however, heterogeneous, which complicates mechanistic analyses. Here, we report the first use this continuous assay to analyze catalysis by wild-type human PDI and a variant in which the C

  4. Converting Homogeneous to Heterogeneous in Electrophilic Catalysis using Monodisperse Metal Nanoparticles

    SciTech Connect (OSTI)

    Witham, Cole A.; Huang, Wenyu; Tsung, Chia-Kuang; Kuhn, John N.; Somorjai, Gabor A.; Toste, F. Dean

    2009-10-15T23:59:59.000Z

    A continuing goal in catalysis is the transformation of processes from homogeneous to heterogeneous. To this end, nanoparticles represent a new frontier in heterogeneous catalysis, where this conversion is supplemented by the ability to obtain new or divergent reactivity and selectivity. We report a novel method for applying heterogeneous catalysts to known homogeneous catalytic reactions through the design and synthesis of electrophilic platinum nanoparticles. These nanoparticles are selectively oxidized by the hypervalent iodine species PhICl{sub 2}, and catalyze a range of {pi}-bond activation reactions previously only homogeneously catalyzed. Multiple experimental methods are utilized to unambiguously verify the heterogeneity of the catalytic process. The discovery of treatments for nanoparticles that induce the desired homogeneous catalytic activity should lead to the further development of reactions previously inaccessible in heterogeneous catalysis. Furthermore, our size and capping agent study revealed that Pt PAMAM dendrimer-capped nanoparticles demonstrate superior activity and recyclability compared to larger, polymer-capped analogues.

  5. Topic Distillation with Query-Dependent Link Connections and Page Characteristics

    E-Print Network [OSTI]

    Wu, Mingfang

    6 Topic Distillation with Query-Dependent Link Connections and Page Characteristics MINGFANG WU about a topic. Finding such results is called topic distillation. Previous research has shown statistics. This article presents a new approach to improve topic distillation by exploring the use

  6. Growth mechanism of graphene on platinum: Surface catalysis and carbon segregation

    SciTech Connect (OSTI)

    Sun, Jie, E-mail: jie.sun@chalmers.se; Lindvall, Niclas; Yurgens, August [Quantum Device Physics Laboratory, Department of Microtechnology and Nanoscience, Chalmers University of Technology, SE-41296 Gothenburg (Sweden); Nam, Youngwoo [Quantum Device Physics Laboratory, Department of Microtechnology and Nanoscience, Chalmers University of Technology, SE-41296 Gothenburg (Sweden); Department of Physics and Astronomy, Seoul National University, Seoul 151-747 (Korea, Republic of); Cole, Matthew T. [Electrical Engineering Division, Department of Engineering, University of Cambridge, 9 JJ Thomson Avenue, CB3 0FA Cambridge (United Kingdom); Teo, Kenneth B. K. [AIXTRON Nanoinstruments Ltd., Swavesey, CB24 4FQ Cambridge (United Kingdom); Woo Park, Yung [Department of Physics and Astronomy, Seoul National University, Seoul 151-747 (Korea, Republic of)

    2014-04-14T23:59:59.000Z

    A model of the graphene growth mechanism of chemical vapor deposition on platinum is proposed and verified by experiments. Surface catalysis and carbon segregation occur, respectively, at high and low temperatures in the process, representing the so-called balance and segregation regimes. Catalysis leads to self-limiting formation of large area monolayer graphene, whereas segregation results in multilayers, which evidently “grow from below.” By controlling kinetic factors, dominantly monolayer graphene whose high quality has been confirmed by quantum Hall measurement can be deposited on platinum with hydrogen-rich environment, quench cooling, tiny but continuous methane flow and about 1000?°C growth temperature.

  7. Improved Modeling of Transition Metals, Applications to Catalysis and Technetium Chemistry

    SciTech Connect (OSTI)

    Cundari, T. R.

    2004-03-05T23:59:59.000Z

    There is considerable impetus for identification of aqueous OM catalysts as water is the ultimate ''green'' solvent. In collaboration with researchers at Ames Lab, we investigated effective fragment and Monte Carlo techniques for aqueous-phase hydroformylation (HyF). The Rh of the HyF catalyst is weakly aquated, in contrast to the hydride of the Rh-H bond. As the insertion of the olefin C=C into Rh-H determines the linear-to-branched aldehyde ratio, it is reasonable to infer that solvent plays an important role in regiochemistry. Studies on aqueous-phase organometallic catalysis were complemented in studies of the gas-phase reaction. A Rh-carbonyl-phosphine catalyst was investigated. Two of the most important implications of this research include (a) pseudorotation among five-coordinate intermediates is significant in HyF, and (b) CO insertion is the rate-determining step. The latter is in contrast to experimental deductions, highlighting the need for more accurate modeling. To this end, we undertook studies of (a) experimentally relevant PR{sub 3} co-ligands (PMe{sub 3}, PPh{sub 3}, P(p-PhSO{sub 3{sup -}}){sub 3}, etc.), and (b) HyF of propene. For the propylene research, simulations indicated that the linear: branched aldehyde ratio (linear is more desirable) is determined by thermodynamic discrimination of two distinct pathways. Other projects include a theory-experiment study of C-H activation by early transition metal systems, which establishes that weakly-bound adducts play a key role in activity selectivity. By extension, more selective catalysts for functionalization of methane (major component of natural gas) will require better understanding of these adducts, which are greatly affected by steric interactions with the ligands. In the de novo design of Tc complexes, we constructed (and are now testing) a coupled quantum mechanics-molecular mechanics protocol. Initial research shows it to be capable of accurately predicting structure ''from scratch.'' Challenges include conformational, geometric, coordination, spin, and particularly linkage (e.g., Tc-SCN versus Tc-NCS) isomerism. In general, our protocol can rapidly (<1 day with desktop software/hardware) predict the structure of diverse Tc complexes with an accuracy commensurate to organics. Our de novo strategy is also being used to investigate tris-pyrazolyl borate (Tp) complexes. Data suggests a fundamental difference in methane activation between TpRe and related CpRe complexes. Furthermore, Tp is a more electronically ''flexible'' platform for catalysts modification than Cp.

  8. Current Postdoctoral Researchers | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Postdoctoral Researchers Name Topic - Any - General Argonne Information -Awards -Honors Energy -Energy efficiency --Vehicles ---Alternative fuels ---Automotive engineering...

  9. Enzyme-Like Catalysis of the Nazarov Cyclization by Supramolecular Encapsulation

    SciTech Connect (OSTI)

    Hastings, Courtney; Pluth, Michael; Bergman, Robert; Raymond, Kenneth

    2010-03-29T23:59:59.000Z

    A primary goal in the design and synthesis of molecular hosts has been the selective recognition and binding of a variety of guests using non-covalent interactions. Supramolecular catalysis, which is the application of such hosts towards catalysis, has much in common with many enzymatic reactions, chiefly the use of both spatially appropriate binding pockets and precisely oriented functional groups to recognize and activate specific substrate molecules. Although there are now many examples which demonstrate how selective encapsulation in a host cavity can enhance the reactivity of a bound guest, all have failed to reach the degree of increased reactivity typical of enzymes. We now report the catalysis of the Nazarov cyclization by a self-assembled coordination cage, a carbon-carbon bond-forming reaction which proceeds under mild, aqueous conditions. The acceleration in this system is over a million-fold, and represents the first example of supramolecular catalysis that achieves the level of rate enhancement comparable to that observed in several enzymes. We explain the unprecedented degree of rate increase as due to the combination of (a) preorganization of the encapsulated substrate molecule, (b) stabilization of the transition state of the cyclization by constrictive binding, and (c) increase in the basicity of the complexed alcohol functionality.

  10. Enantioselective Organocatalytic Indole Alkylations. Design of a New and Highly Effective Chiral Amine for Iminium Catalysis

    E-Print Network [OSTI]

    MacMillan, David W. C.

    structural motifs of established value in medicinal chemistry or complex target synthesis. In this regard the capacity of iminium catalysis to mediate the enantioselective coupling of pyrroles and R, -unsaturated alde nucleophiles. Despite struc- tural similarities, it has long been established7 that the pyrrole -system

  11. Applied Catalysis A: General 254 (2003) 97106 Photoionization detection (PID) as a high throughput

    E-Print Network [OSTI]

    Senkan, Selim M.

    Applied Catalysis A: General 254 (2003) 97­106 Photoionization detection (PID) as a high throughput 2002 Abstract A versatile photoionization detection (PID) system has been developed to rapidly screen libraries of catalytic materials. The PID approach involves the use of an appropriately selected dc

  12. High surface area crystalline titanium dioxide: potential and limits in electrochemical energy storage and catalysis

    E-Print Network [OSTI]

    Pfeifer, Holger

    High surface area crystalline titanium dioxide: potential and limits in electrochemical energy-Planck-Institut für Polymerforschung, Ackermannweg 10, D-55128 Mainz, Germany Abstract Titanium dioxide is one, as support in catalysis etc. Common synthesis methods of titanium dioxide typically require a high

  13. Argonne National Laboratory Chemical Engineering Division Water-gas shift catalysis

    E-Print Network [OSTI]

    Argonne National Laboratory Chemical Engineering Division Water-gas shift catalysis Sara Yu Choung Engineering Division Argonne National Laboratory Hydrogen, Fuel Cells, and Infrastructure Technologies 2003 Merit Review Berkeley, CA May 19-22, 2003 #12;Argonne National Laboratory Chemical Engineering Division

  14. Catalysis Today 77 (2002) 6578 CO-free fuel processing for fuel cell applications

    E-Print Network [OSTI]

    Goodman, Wayne

    2002-01-01T23:59:59.000Z

    Catalysis Today 77 (2002) 65­78 CO-free fuel processing for fuel cell applications T.V. Choudhary In view of the stringent CO intolerance of the state-of-the-art proton exchange membrane (PEM) fuel cells of hydrocarbons has been proposed for production of CO-free hydrogen for fuel cell applications. The decomposition

  15. Author's personal copy Catalysis of imido group hydrolysis in a maleimide conjugate

    E-Print Network [OSTI]

    Raines, Ronald T.

    Author's personal copy Catalysis of imido group hydrolysis in a maleimide conjugate Jeet Kaliaa, resulting in undesirable heterogeneity. Here, a chromophoric maleimide is used to demonstrate that both for molybdate and chromate, and provides a strategy for decreasing the heterogeneity of bioconjugates derived

  16. ISHHC XIII International Symposium on the Relations betweenHomogeneous and Heterogeneous Catalysis

    SciTech Connect (OSTI)

    Somorjai (Ed.), G.A.

    2007-06-11T23:59:59.000Z

    The International Symposium on Relations between Homogeneous and Heterogeneous Catalysis (ISHHC) has a long and distinguished history. Since 1974, in Brussels, this event has been held in Lyon, France (1977), Groeningen, The Netherlands (1981); Asilomar, California (1983); Novosibirsk, Russia (1986); Pisa, Italy (1989); Tokyo, Japan (1992); Balatonfuered, Hungary (1995); Southampton, United Kingdom (1999); Lyon, France (2001); Evanston, Illinois (2001) and Florence, Italy (2005). The aim of this international conference in Berkeley is to bring together practitioners in the three fields of catalysis, heterogeneous, homogeneous and enzyme, which utilize mostly nanosize particles. Recent advances in instrumentation, synthesis and reaction studies permit the nanoscale characterization of the catalyst systems, often for the same reaction, under similar experimental conditions. It is hoped that this circumstance will permit the development of correlations of these three different fields of catalysis on the molecular level. To further this goal we aim to uncover and focus on common concepts that emerge from nanoscale studies of structures and dynamics of the three types of catalysts. Another area of focus that will be addressed is the impact on and correlation of nanosciences with catalysis. There is information on the electronic and atomic structures of nanoparticles and their dynamics that should have importance in catalyst design and catalytic activity and selectivity.

  17. Asymmetric Catalysis at the Mesoscale: Gold Nanoclusters Embedded in Chiral Self-Assembled Monolayer as Heterogeneous

    E-Print Network [OSTI]

    Asymmetric Catalysis at the Mesoscale: Gold Nanoclusters Embedded in Chiral Self of the catalytically active metallic sites and the surrounding chiral SAM for the formation of a mesoscale the catalytically active site from the nanoscale to the mesoscale, which implies a principle of operating systems

  18. Enhancing quantum entanglement and quantum teleportation for two-mode squeezed vacuum state by local quantum-optical catalysis

    E-Print Network [OSTI]

    Xue-xiang Xu

    2015-03-17T23:59:59.000Z

    I investigate how the entanglement properties of a two-mode squeezed vacuum state (TMSVS) can be enhanced by operating quantum-optical catalysis, proposed by Lovvky and Mlynek [Phys. Rev. Lett. 88, 250404 (2002)], on each mode. I show that the degree of entanglement, the Eistein-Podolsky-Rosen-type correlation, and the performance of quantum teleportation can be all enhanced for the output state when the appropriate quantum-optical catalysis is applied to a TMSVS. It is found that all the enhancements are happened in the small-squeezing and small-catalysis parameter regime.

  19. alaska linking wildlife: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Alaska Cooperative Fish and Wildlife Research Unit Annual Research Report--2011 Environmental Sciences and...

  20. [Research at the Notre Dame Radiation Laboratory]. Quarterly report, April 1--June 30, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-08-02T23:59:59.000Z

    Forty-four abstracts are presented of research projects in radiation chemistry, photochemistry, and related topics.

  1. Solvation and Acid Strength Effects on Catalysis by Faujasite Zeolites

    SciTech Connect (OSTI)

    Gounder, Rajamani P.; Jones, Andrew J.; Carr, Robert T.; Iglesia, Enrique

    2012-02-01T23:59:59.000Z

    Kinetic, spectroscopic, and chemical titration data indicate that differences in monomolecular isobutane cracking and dehydrogenation and methanol dehydration turnover rates (per H+) among FAU zeolites treated thermally with steam (H-USY) and then chemically with ammonium hexafluorosilicate (CDHUSY) predominantly reflect differences in the size and solvating properties of their supercage voids rather than differences in acid strength. The number of protons on a given sample was measured consistently by titrations with Na+, with CH3 groups via reactions of dimethyl ether, and with 2,6-di-tert-butylpyridine during methanol dehydration catalysis; these titration values were also supported by commensurate changes in acidic OH infrared band areas upon exposure to titrant molecules. The number of protons, taken as the average of the three titration methods, was significantly smaller than the number of framework Al atoms (Alf) obtained from X-ray diffraction and 27Al magic angle spinning nuclear magnetic resonance spectroscopy on H-USY (0.35 H+/Alf) and CD-HUSY (0.69 H+/Alf). These data demonstrate that the ubiquitous use of Alf sites as structural proxies for active H+ sites in zeolites can be imprecise, apparently because distorted Al structures that are not associated with acidic protons are sometimes detected as Alf sites. Monomolecular isobutane cracking and dehydrogenation rate constants, normalized non-rigorously by the number of Alf species, decreased with increasing Na+ content on both H-USY and CD-HUSY samples and became undetectable at sub-stoichiometric exchange levels (0.32 and 0.72 Na+/Alf ratios, respectively), an unexpected finding attributed incorrectly in previous studies to the presence of minority ‘‘super-acidic’’ sites. These rate constants, when normalized rigorously by the number of residual H+ sites were independent of Na+ content on both H-USY and CD-HUSY samples, reflecting the stoichiometric replacement of protons that are uniform in reactivity by Na+ cations. Monomolecular isobutane cracking and dehydrogenation rate constants (per H+; 763 K), however, were higher on H-USY than CD-HUSY (by a factor of 1.4). Equilibrium constants for the formation of protonated methanol dimers via adsorption of gaseous methanol onto adsorbed methanol monomers, determined from kinetic studies of methanol dehydration to dimethyl ether (433 K), were also higher on H-USY than CD-HUSY (by a factor of 2.1). These larger constants predominantly reflect stronger dispersive interactions in H-USY, consistent with its smaller supercage voids that result from the occlusion of void space by extraframework Al (Alex) residues. These findings appear to clarify enduring controversies about the mechanistic interpretation of the effects of Na+ and Alex species on the catalytic reactivity of FAU zeolites. They also illustrate the need to normalize rates by the number of active sites instead of more convenient but less accurate structural proxies for such sites.

  2. Scenes from Argonne's Materials Engineering Research Facility...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scenes from Argonne's Materials Engineering Research Facility Share Description B-roll for the Materials Engineering Research Facility Topic Energy Energy usage Energy storage...

  3. The roles of redox active cofactors in catalysis : structural studies of iron sulfur cluster and flavin dependent enzymes

    E-Print Network [OSTI]

    Goldman, Peter John

    2013-01-01T23:59:59.000Z

    Cofactors are highly prevalent in biological systems and have evolved to take on many functions in enzyme catalysis. Two cofactors, flavin adenine dinucleotide (FAD) and [4Fe-4S] clusters, were originally determined to aid ...

  4. HOMOGENEOUS CATALYSIS AND MASS TRANSFER IN BIPHASIC IONIC LIQUID SYSTEMS WITH COMPRESSED CO2 AND ORGANIC COMPOUNDS

    E-Print Network [OSTI]

    Ahosseini, Azita

    ABSTRACT Homogeneous catalysis in which the catalyst, solvents and reactants are all in the same phase can yield high activity and selectivity and efficiently produce chemical products. However, the main problem with these ...

  5. Fundamental Studies in Catalysis Enabled the use of Efficient...

    Office of Environmental Management (EM)

    that has significantly reduced harmful emissions from many of today's fuel-efficient diesel engines. The same research program also advanced the foundational understanding of...

  6. Tandem Catalysis in Nanocrystal Interfaces | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Recently, researchers at the Department's Lawrence Berkeley National Laboratory (LBNL) created bilayered nanocrystals of metal-oxide metal that are first to feature multiple...

  7. Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements Recently ApprovedReliabilityPrincipal Investigators PostdoctoralResearch

  8. Research results from the Ashland Exploration, Inc. Ford Motor Company 78 (ed) well, Pike County, Kentucky. Topical report, April 1992-December 1993

    SciTech Connect (OSTI)

    Hopkins, C.W.; Frantz, J.H.; Lancaster, D.E.

    1995-06-01T23:59:59.000Z

    This report summarizes the work performed on the Ashland Exploration, Inc. Ford Motor Company 78 (Experimental Development (ED)) Well, in Pike County, KY. The ED well was the third well drilled in a research project conducted by GRI in eastern Kentucky targeting both the Devonian Shales and Berea Sandstone. Both the Shales and Berea were completed and tested in the ED well. The primary objective of the ED well was to apply what was learned from studying the Shalers in COOP 1 (first well drilled) and the Berea in COOP 2 (second well drilled) to both the Shales and the Berea in the ED well. Additionally, the ED well was used to evaluate the impact of different stimulation treatments on Shales production. Research in the ED well brings to a close GRI`s extensive field-based research program in the Appalachian Basin over the last ten years.

  9. Research results from the Ashland Exploration, Inc., Ford Motor Company 80 (COOP 2) well, Pike County, KY. Topical report, October 1991-November 1992

    SciTech Connect (OSTI)

    Frantz, J.H.; Lancaster, D.E.

    1993-04-01T23:59:59.000Z

    The report summarizes the work performed on the Ashland Exploration, Inc. (AEI) Ford Motor Company 80 (COOP 2) well in Pike County, KY. The COOP 2 was the second well in a three-well research project being conducted by GRI in eastern Kentucky targeting both the Devonian Shales and the Berea Sand; the FMC 80 focused on the Berea. The primary objective of the research was to use and transfer technologies developed in GRI`s Tight Gas Sands and Gas Shales programs to evaluate the Berea in Pike Co., KY.

  10. University of Delaware | Catalysis Center for Energy Innovation | Pyrolysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >Internship Program TheSite Map SiteResearch ThrustMaterialsResearch

  11. Charge Transfer and Support Effects in Heterogeneous Catalysis

    SciTech Connect (OSTI)

    Hervier, Antoine

    2011-12-21T23:59:59.000Z

    The kinetic, electronic and spectroscopic properties of two?dimensional oxide?supported catalysts were investigated in order to understand the role of charge transfer in catalysis. Pt/TiO{sub 2} nanodiodes were fabricated and used as catalysts for hydrogen oxidation. During the reaction, the current through the diode, as well as its I?V curve, were monitored, while gas chromatography was used to measure the reaction rate. The current and the turnover rate were found to have the same temperature dependence, indicating that hydrogen oxidation leads to the non?adiabatic excitation of electrons in Pt. A fraction of these electrons have enough energy to ballistically transport through Pt and overcome the Schottky barrier at the interface with TiO{sub 2}. The yield for this phenomenon is on the order of 10{sup ?4} electrons per product molecule formed, similar to what has been observed for CO oxidation and for the adsorption of many different molecules. The same Pt/TiO{sub 2} system was used to compare currents in hydrogen oxidation and deuterium oxidation. The current through the diode under deuterium oxidation was found to be greater than under hydrogen oxidation by a factor of three. Weighted by the difference in turnover frequencies for the two isotopes, this would imply a chemicurrent yield 5 times greater for D{sub 2} compared to H{sub 2}, contrary to what is expected given the higher mass of D{sub 2}. Reversible changes in the rectification factor of the diode are observed when switching between D{sub 2} and H{sub 2}. These changes are a likely cause for the differences in current between the two isotopes. In the nanodiode experiments, surface chemistry leads to charge flow, suggesting the possibility of creating charge flow to tune surface chemistry. This was done first by exposing a Pt/Si diode to visible light while using it as a catalyst for H{sub 2} oxidation. Absorption of the light in the Si, combined with the band bending at the interface, gives rise to a steady?state flow of hot holes to the surface. This leads to a decrease in turnover on the surface, an effect which is enhanced when a reverse bias is applied to the diode. Similar experiments were carried out for CO oxidation. On Pt/Si diodes, the reaction rate was found to increase when a forward bias was applied. When the diode was exposed to visible light and a reverse bias was applied, the rate was instead decreased. This implies that a flow of negative charges to the surface increases turnover, while positive charges decrease it. Charge flow in an oxide supported metal catalyst can be modified even without designing the catalyst as a solid state electronic device. This was done by doping stoichiometric and nonstoichiometric TiO{sub 2} films with F, and using the resulting oxides as supports for Pt films. In the case of stoichiometric TiO{sub 2}, F was found to act as an n?type dopant, creating a population of filled electronic states just below the conduction band, and dramatically increasing the conductivity of the oxide film. The electrons in those states can transfer to surface O, activating it for reaction with CO, and leading to increased turnover for CO oxidation. This reinforces the hypothesis that CO oxidation is activated by a flow of negative charges to the surface. The same set of catalysts was used for methanol oxidation. The electronic properties of the TiO{sub 2} films again correlated with the turnover rates, but also with selectivity. With stoichiometric TiO{sub 2} as the support, F?doping caused an increase in selectivity toward the formation of partial oxidation products, formaldehyde and methyl formate, versus the total oxidation product, CO{sub 2}. With non?stoichiometric TiO{sub 2}, F?doping had the reverse effect. Ambient Pressure X?Ray Photoelectron Spectroscopy was used to investigate this F?doping effect in reaction conditions. In O2 alone, and in CO oxidation conditions, the O1s spectrum showed a high binding energy peak that correlated in intensity with the activity of the different films: for stoichiomet

  12. On the role of interfacial hydrogen bonds in "on-water" catalysis

    E-Print Network [OSTI]

    Kristof Karhan; Rustam Z. Khaliullin; Thomas D. Kühne

    2014-08-21T23:59:59.000Z

    Numerous experiments have demonstrated that many classes of organic reactions exhibit increased reaction rates when performed in heterogeneous water emulsions. Despite enormous practical importance of the observed "on-water" catalytic effect and several mechanistic studies, its microscopic origins remains unclear. In this work, the second generation Car-Parrinello molecular dynamics method is extended to self-consistent charge density-functional based tight-binding in order to study "on-water" catalysis of the Diels-Alder reaction between dimethyl azodicarboxylate and quadricyclane. We find that the stabilization of the transition state by dangling hydrogen bonds exposed at the aqueous interfaces plays a significantly smaller role in "on-water" catalysis than has been suggested previously.

  13. YuTung Tsai Postdoctoral Research Associate

    E-Print Network [OSTI]

    Pennycook, Steve

    . Spivey, "Hydrotalcite Supported Co Catalysts for CO Hydrogenation," Applied Catalysis A: General 396 Catalysis Society Meeting, Asheville, North Carolina 2008­2011 Ph.D. Full Scholarship, Department Catalysts for CO Hydrogenation," Southeastern Catalysis Society Meeting, Asheville, North Carolina

  14. University of Delaware | Catalysis Center for Energy Innovation | Aromatics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >Internship Program TheSite Map SiteResearch Thrust Green Aromatics

  15. University of Delaware | Catalysis Center for Energy Innovation | Biomass

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >Internship Program TheSite Map SiteResearch Thrust Green

  16. University of Delaware | Catalysis Center for Energy Innovation | Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >Internship Program TheSite Map SiteResearch Thrust GreenCells

  17. University of Delaware | Catalysis Center for Energy Innovation | Furans

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >Internship Program TheSite Map SiteResearch Thrust

  18. University of Delaware | Catalysis Center for Energy Innovation | Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >Internship Program TheSite Map SiteResearch ThrustMaterials Bi-modal

  19. University of Delaware | Catalysis Center for Energy Innovation | Modeling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >Internship Program TheSite Map SiteResearch ThrustMaterials

  20. A research needs assessment for the capture, utilization and disposal of carbon dioxide from fossil fuel-fired power plants. Volume 2, Topical reports: Final report

    SciTech Connect (OSTI)

    Not Available

    1993-07-01T23:59:59.000Z

    This study, identifies and assesses system approaches in order to prioritize research needs for the capture and non-atmospheric sequestering of a significant portion of the carbon dioxide (CO{sub 2}) emitted from fossil fuel-fired electric power plants (US power plants presently produce about 7% of the world`s CO{sub 2} emissions). The study considers capture technologies applicable either to existing plants or to those that optimistically might be demonstrated on a commercial scale over the next twenty years. The research needs that have high priority in establishing the technical, environmental, and economic feasibility of large-scale capture and disposal of CO{sub 2} from electric power plants are:(1) survey and assess the capacity, cost, and location of potential depleted gas and oil wells that are suitable CO{sub 2} repositories (with the cooperation of the oil and gas industry); (2) conduct research on the feasibility of ocean disposal, with objectives of determining the cost, residence time, and environmental effects for different methods of CO{sub 2} injection; (3) perform an in-depth survey of knowledge concerning the feasibility of using deep, confined aquifers for disposal and, if feasible, identify potential disposal locations (with the cooperation of the oil and gas industry); (4) evaluate, on a common basis, system and design alternatives for integration of CO{sub 2} capture systems with emerging and advanced technologies for power generation; and prepare a conceptual design, an analysis of barrier issues, and a preliminary cost estimate for pipeline networks necessary to transport a significant portion of the CO{sub 2} to potentially feasible disposal locations.

  1. 328th Catalysis Research Center (CRC) Colloquium Preparation of nanocrystalline materials for selective

    E-Print Network [OSTI]

    Tachizawa, Kazuya

    the selective oxidation of methane to methanol, benzene to phenol, propylene to propylene oxide using molecular active for selective oxidation of propylene to propylene oxide and a propylene conversion of about ~ 36% with >99% propylene epoxide selectivity was achieved in the vapour phase using solely molecular oxygen

  2. 340th Catalysis Research Center (CRC) Colloquium NOx Storage Mechanism on NSR Catalysts

    E-Print Network [OSTI]

    Ishii, Hitoshi

    brought about the lean-burn engine technology with high air/fuel ratio for motor vehicles. However of the leading strategies to tackle this issue. The catalyst works with alternatively lean and rich conditions 1996 to 2003. He was a visiting professor at Kyoto University, Japan, Ecole Normale Superieure de Lyon

  3. This research was supported as part of the Catalysis Center for Energy Innovatio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengthening a solidSynthesis ofwas published inFebruary 25,902 (2010) ANNUALA

  4. This research was supported as part of the Catalysis Center for Energy Innovatio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengthening a solidSynthesis ofwas published inFebruary 25,902 (2010)

  5. This research was supported as part of the Catalysis Center for Energy Innovatio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengthening a solidSynthesis ofwas published inFebruary 25,902 (2010)Renewable

  6. This research was supported as part of the Catalysis Center for Energy Innovatio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengthening a solidSynthesis ofwas published inFebruary 25,902 (2010)Renewable

  7. This research was supported as part of the Catalysis Center for Energy Innovatio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengthening a solidSynthesis ofwas published inFebruary 25,902

  8. Energy and environmental research emphasizing low-rank coal: Task 3.4 -- Hot-gas cleaning. Topical report (includes semiannual report for January--June 1995)

    SciTech Connect (OSTI)

    Weber, G.F.; Swanson, M.L.

    1995-06-01T23:59:59.000Z

    This report summarizes the accomplishments of three subtasks completed in support of the current and future hot-gas cleanup activities at the Energy and Environmental Research Center (EERC). The overall objective of the EERC hot-gas cleanup task is to develop reliable methods to remove particulate matter from high-temperature, high-pressure gas streams produced from coal combustion and/or gasification. Near-term task objectives include (1) design, fabrication, and assembly of a high-temperature, high-pressure bench-scale filter vessel; (2) design, fabrication, and assembly of a high-temperature, high-pressure sampling train; and (3) the preliminary design of a pilot-scale high-temperature, high-pressure filter vessel and support systems. Bench-scale hot-gas filter research will be performed with the pressurized fluid-bed reactor (PFBR) or the continuous fluid-bed reactor (CFBR) and a hot-gas filter vessel. The objectives of future work with the bench-scale system will be to determine particulate and vapor-phase alkali degradation of candidate ceramic filter structures as well as filter performance relative to particulate collection efficiency, differential pressure, and filter cleanability. Construction of the high-temperature, high-pressure sampling system was intended to support bench- and pilot-scale activities with respect to conventional particulate sampling (total mass and particle-size distribution) and hazardous air pollutant (HAP) sampling. Finally, pilot-scale tests will be performed to evaluate filter performance and determine alkali corrosion of ceramic materials with a hot-gas filter vessel attached to the EERC Transport Reactor Development Unit (TRDU).

  9. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced1ALSALS RevealsALS WorkshopALS

  10. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced1ALSALS RevealsALS WorkshopALSALS

  11. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced1ALSALS RevealsALS WorkshopALSALSALS

  12. activated human neutrophils: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    22 23 24 25 Next Page Last Page Topic Index 21 EDITORIAL How to regulate neutrophils in gout CiteSeer Summary: Most research in gout has concentrated on the proinflammatory...

  13. antagonistically regulate neutrophil: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    22 23 24 25 Next Page Last Page Topic Index 1 EDITORIAL How to regulate neutrophils in gout CiteSeer Summary: Most research in gout has concentrated on the proinflammatory...

  14. ambulatory pulse pressure: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ultrashort laser pulses is one of the most attractive topics in relativistic laser-plasma research. We report protonion acceleration in the intensity range of 5x1019 Wcm2 to...

  15. aflatoxinby aspergillus sp: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 101 Solar Physics & Space Plasma Research Center (SP2RC) Geosciences Websites Summary: Solar Physics & Space Plasma...

  16. army pulse radiation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ultrashort laser pulses is one of the most attractive topics in relativistic laser-plasma research. We report protonion acceleration in the intensity range of 5x1019 Wcm2 to...

  17. aspergillus sp nr4617: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 101 Solar Physics & Space Plasma Research Center (SP2RC) Geosciences Websites Summary: Solar Physics & Space Plasma...

  18. aspergillus uvarum sp: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 101 Solar Physics & Space Plasma Research Center (SP2RC) Geosciences Websites Summary: Solar Physics & Space Plasma...

  19. arterial pulse pressure: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ultrashort laser pulses is one of the most attractive topics in relativistic laser-plasma research. We report protonion acceleration in the intensity range of 5x1019 Wcm2 to...

  20. aspergillus sp positiivne: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 101 Solar Physics & Space Plasma Research Center (SP2RC) Geosciences Websites Summary: Solar Physics & Space Plasma...

  1. air force pilots: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 21 The Air Force Research Laboratory (AFRL) Scholars Program is currently Computer Technologies and Information...

  2. air force pilot: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 21 The Air Force Research Laboratory (AFRL) Scholars Program is currently Computer Technologies and Information...

  3. attending public primary: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    20 21 22 23 24 25 Next Page Last Page Topic Index 1 3.3 Schools for Primary Care, Social Care and Public Health Research Version 8 (January 2014) Mathematics Websites Summary: 3.3...

  4. adult health study: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    22 23 24 25 Next Page Last Page Topic Index 1 RESEARCH ARTICLE Open Access Association of Health Literacy with Complementary and Alternative Medicine Use: A Cross-Sectional Study...

  5. air particulate exposure: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    25 Next Page Last Page Topic Index 1 Research Commuters Exposure to Particulate Matter Air Pollution Is Affected by Mode of Transport, Fuel Type, and Route CiteSeer Summary: Ba...

  6. DIII-D research operations

    SciTech Connect (OSTI)

    Baker, D. (ed.)

    1993-05-01T23:59:59.000Z

    This report discusses the research on the following topics: DIII-D program overview; divertor and boundary research program; advanced tokamak studies; tokamak physics; operations; program development; support services; contribution to ITER physics R D; and collaborative efforts.

  7. Selected Topics in Column Generation

    E-Print Network [OSTI]

    2002-12-02T23:59:59.000Z

    Dec 2, 2002 ... Page 1. Selected Topics in Column Generation. Marco E. Lübbecke ... is an ever recurring concept in our “selected topics.” OR/MS Subject ...

  8. Theoretical/Computational Tools for Energy-Relevant Catalysis | The Ames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in theTheoretical Study on Catalysis by

  9. High Throughput Sample Preparation and Analysis for DNA Sequencing, PCR and Combinatorial Screening of Catalysis Based on Capillary Array Technique

    SciTech Connect (OSTI)

    Yonghua Zhang

    2002-05-27T23:59:59.000Z

    Sample preparation has been one of the major bottlenecks for many high throughput analyses. The purpose of this research was to develop new sample preparation and integration approach for DNA sequencing, PCR based DNA analysis and combinatorial screening of homogeneous catalysis based on multiplexed capillary electrophoresis with laser induced fluorescence or imaging UV absorption detection. The author first introduced a method to integrate the front-end tasks to DNA capillary-array sequencers. protocols for directly sequencing the plasmids from a single bacterial colony in fused-silica capillaries were developed. After the colony was picked, lysis was accomplished in situ in the plastic sample tube using either a thermocycler or heating block. Upon heating, the plasmids were released while chromsomal DNA and membrane proteins were denatured and precipitated to the bottom of the tube. After adding enzyme and Sanger reagents, the resulting solution was aspirated into the reaction capillaries by a syringe pump, and cycle sequencing was initiated. No deleterious effect upon the reaction efficiency, the on-line purification system, or the capillary electrophoresis separation was observed, even though the crude lysate was used as the template. Multiplexed on-line DNA sequencing data from 8 parallel channels allowed base calling up to 620 bp with an accuracy of 98%. The entire system can be automatically regenerated for repeated operation. For PCR based DNA analysis, they demonstrated that capillary electrophoresis with UV detection can be used for DNA analysis starting from clinical sample without purification. After PCR reaction using cheek cell, blood or HIV-1 gag DNA, the reaction mixtures was injected into the capillary either on-line or off-line by base stacking. The protocol was also applied to capillary array electrophoresis. The use of cheaper detection, and the elimination of purification of DNA sample before or after PCR reaction, will make this approach an attractive alternative to current methods for genetic analysis and disease diagnosis.

  10. Northwestern University Facility for Clean Catalytic Process Research

    SciTech Connect (OSTI)

    Marks, Tobin Jay [Northwestern University

    2013-05-08T23:59:59.000Z

    Northwestern University with DOE support created a Facility for Clean Catalytic Process Research. This facility is designed to further strengthen our already strong catalysis research capabilities and thus to address these National challenges. Thus, state-of-the art instrumentation and experimentation facility was commissioned to add far greater breadth, depth, and throughput to our ability to invent, test, and understand catalysts and catalytic processes, hence to improve them via knowledge-based design and evaluation approaches.

  11. Continuous Isosorbide Production From Sorbitol Using Solid Acid Catalysis

    SciTech Connect (OSTI)

    Williamson, R.; Holladay,J.; Jaffe, M.; Brunelle, D.

    2006-09-29T23:59:59.000Z

    This is a final report for a project funded by the US Department of Agriculture and managed by the US Department of Energy. The Iowa Corn Promotion Board was the principal contracting entity for the grant. The Iowa Corn Promotion Board subcontracted with General Electric, Pacific Northwest National Lab and New Jersey Institute of Technology to conduct research in this project. The Iowa Corn Promotion Board and General Electric provided cost share for the project. The purpose of this diverse collaboration was to integrate both the conversion and the polymer applications into one project and increase the likelihood of success. This project has led to additional collaborations among other polymer companies. The goals of the project were to develop a renewable route to isosorbide for commercialization that is economically competitive with all existing production technologies and to develop new applications for isosorbide in various products such as polymers and materials. Under this program a novel process for the production of isosorbide was developed and evaluated. The novel process converts corn based sorbitol into isosorbide using a solid catalyst with integrated water removal and product recovery. In addition the work under this program has identified several novel products based on isosorbide chemistries. These market applications include: epoxy resins, UV stabilizers, plasticizers and polyesters. These market applications have commercial interest within the current polymer industry. This report contains an overview summary of the accomplishments. Six inventions and four patent applications have been written as a result of this project. Additional data will be published in the patent applications. The data developed at New Jersey Institute of Technology was presented at two technical conferences held in June of 2006. Several companies have made inquiries about using this material in their products.

  12. Proton Mediated Chemistry and Catalysis in a Self-Assembled Supramolecular Host

    SciTech Connect (OSTI)

    Pluth, Michael; Bergman, Robert; Raymond, Kenneth

    2009-04-10T23:59:59.000Z

    Synthetic supramolecular host assemblies can impart unique reactivity to encapsulated guest molecules. Synthetic host molecules have been developed to carry out complex reactions within their cavities, despite the fact that they lack the type of specifically tailored functional groups normally located in the analogous active sites of enzymes. Over the past decade, the Raymond group has developed a series of self-assembled supramolecules and the Bergman group has developed and studied a number of catalytic transformations. In this Account, we detail recent collaborative work between these two groups, focusing on chemical catalysis stemming from the encapsulation of protonated guests and expanding to acid catalysis in basic solution. We initially investigated the ability of a water-soluble, self-assembled supramolecular host molecule to encapsulate protonated guests in its hydrophobic core. Our study of encapsulated protonated amines revealed rich host-guest chemistry. We established that self-exchange (that is, in-out guest movement) rates of protonated amines were dependent on the steric bulk of the amine rather than its basicity. The host molecule has purely rotational tetrahedral (T) symmetry, so guests with geminal N-methyl groups (and their attendant mirror plane) were effectively desymmetrized; this allowed for the observation and quantification of the barriers for nitrogen inversion followed by bond rotation. Furthermore, small nitrogen heterocycles, such as N-alkylaziridines, N-alkylazetidines, and N-alkylpyrrolidines, were found to be encapsulated as proton-bound homodimers or homotrimers. We further investigated the thermodynamic stabilization of protonated amines, showing that encapsulation makes the amines more basic in the cavity. Encapsulation raises the effective basicity of protonated amines by up to 4.5 pK{sub a} units, a difference almost as large as that between the moderate and strong bases carbonate and hydroxide. The thermodynamic stabilization of protonated guests was translated into chemical catalysis by taking advantage of the potential for accelerating reactions that take place via positively charged transition states, which could be potentially stabilized by encapsulation. Orthoformates, generally stable in neutral or basic solution, were found to be suitable substrates for catalytic hydrolysis by the assembly. Orthoformates small enough to undergo encapsulation were readily hydrolyzed by the assembly in basic solution, with rate acceleration factors up to 3900 compared with those of the corresponding uncatalyzed reactions. Furthering the analogy to enzymes that obey Michaelis-Menten kinetics, we observed competitive inhibition with the inhibitor NPr{sub 4}{sup +}, thereby confirming that the interior cavity of the assembly was the active site for catalysis. Mechanistic studies revealed that the assembly is required for catalysis and that the rate-limiting step of the reaction involves proton transfer from hydronium to the encapsulated substrate. Encapsulation in the assembly changes the orthoformate hydrolysis from an A-1 mechanism (in which decomposition of the protonated substrate is the rate-limiting step) to an A-S{sub E}2 mechanism (in which proton transfer is the rate-limiting step). The study of hydrolysis in the assembly was next extended to acetals, which were also catalytically hydrolyzed by the assembly in basic solution. Acetal hydrolysis changed from the A-1 mechanism in solution to an A-2 mechanism inside the assembly, where attack of water on the protonated substrate is rate limiting. This work provides rare examples of assembly-catalyzed reactions that proceed with substantial rate accelerations despite the absence of functional groups in the cavity and with mechanisms fully elucidated by quantitative kinetic studies.

  13. Exam # 2 Topics 9.

    E-Print Network [OSTI]

    1910-61-10T23:59:59.000Z

    Page 1. MA 341 - Fall 2006. Exam # 2 Topics. 1. Convergence of a sequence; Squeeze Theorem (Exercise 2.3.3.); Zipper Theorem (Exercise. 2.3.5.); Algebraic

  14. Research topics will include Faculty Leader

    E-Print Network [OSTI]

    Scannell, Kevin Patrick

    Engineering on-site, while participating in computer-related service learning projects. The software Study Abroad Coordinator johnsonl13@xavier.edu Colombia: Service Learning and Software Engineering {credit in software engineering and Spanish language} Study Abroad with Xavier University Pre

  15. MC-CAM Research Topics Organic LEDs

    E-Print Network [OSTI]

    Bigelow, Stephen

    materials with highly- controlled microstructures Next generation optical storage media Products based applications Novel conjugated polymers and high-conductivity organics Nanostructured materials with unique electronic, magnetic, and optical properties Chemically modified fullerenes and fullerene devices Materials

  16. Hot Topic Workshop | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School football Highdefault Sign InData inmaxHorizontalHot

  17. General basic and coordination catalysis in reactions of haloaromatic compounds with ammonia in the presence of copper(I) compounds

    SciTech Connect (OSTI)

    Chumak, V.T.; Shein, S.M.

    1985-11-01T23:59:59.000Z

    This paper presents a study made to detect general basic catalysis by ammonia (reagent) in reactions of ammonolysis of haloaromatic compounds in the presence of Cu/sup +/ ions, as well as to determine the generality of the mechanisms of the catalytic replacement of a halogen atom by an amino group in the anthraquinone and benzene series.

  18. Effects of catalysis on particle motion in plane-parallel and cylindrical channels in a catalytic reactor

    SciTech Connect (OSTI)

    Kabanov, A.N.; Murashkevich, F.I.; Shulimanova, Z.L.; Shukin, E.R.

    1987-09-01T23:59:59.000Z

    A theoretical study is made on aerosol behavior in a catalysis zone for a plane-parallel or cylindrical channel in a catalytic reactor. It is found that the thermophoretic trapping coefficient may attain 10-15% in a laminar flow having longitudinal Pe and Re >> 1 even for small relative temperature differences.

  19. Decarboxylative Arylation of Amino Acids via Photoredox Catalysis: A One-Step Conversion of Biomass to Drug

    E-Print Network [OSTI]

    MacMillan, David W. C.

    Decarboxylative Arylation of Amino Acids via Photoredox Catalysis: A One-Step Conversion of Biomass. This method offers rapid entry to prevalent benzylic amine architectures from an abundant biomass the worldwide abundance of biomass6 that incorporates carboxylate functionality (e.g., amino acids, -hydroxy

  20. Approved Module Information for CH3010, 2014/5 Module Title/Name: Catalysis Module Code: CH3010

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    Approved Module Information for CH3010, 2014/5 Module Title/Name: Catalysis Module Code: CH3010 School: Engineering and Applied Science Module Type: Standard Module New Module? No Module Credits: 10 in which available: BSc/MChem Applied Chemistry. BSc/MChem Chemistry. BEng/MEng Chemical Engineering. MEng

  1. Structure of Human Epoxide Hydrolase Reveals Mechanistic Inferences on Bifunctional Catalysis in Epoxide and Phosphate Ester Hydrolysis,

    E-Print Network [OSTI]

    Hammock, Bruce D.

    is unclear. Recent experiments demonstrate that the N-terminal domain of human sEH catalyzes the metalStructure of Human Epoxide Hydrolase Reveals Mechanistic Inferences on Bifunctional Catalysis ReceiVed February 4, 2004 ABSTRACT: The X-ray crystal structure of human soluble epoxide hydrolase (s

  2. Applied Catalysis A: General 219 (2001) 215222 Structural analysis of unpromoted Fe-based FischerTropsch

    E-Print Network [OSTI]

    Iglesia, Enrique

    2001-01-01T23:59:59.000Z

    Applied Catalysis A: General 219 (2001) 215­222 Structural analysis of unpromoted Fe-based Fischer­Tropsch by Mössbauer emission and X-ray absorption spectroscopies after use in the Fischer­Tropsch synthesis (FTS reactant mixture. © 2001 Elsevier Science B.V. All rights reserved. Keywords: Fischer­Tropsch synthesis; X

  3. SERS internship Fall 1992--Spring 1993: Abstract and research papers

    SciTech Connect (OSTI)

    Not Available

    1993-08-05T23:59:59.000Z

    This report contains the abstracts and research papers by students on a variety of topics in engineering, genetics, solid state physics, thermonuclear energy, astrophysics, and other science related topics.

  4. Zeolite catalysis

    SciTech Connect (OSTI)

    Chu, P.; Garwood, W.E.; Schwartz, A.B.

    1988-11-29T23:59:59.000Z

    This patent describes a process for preparing hydrocarbons boiling in the gasoline and/or distillate range by contacting a feedstock comprising lower molecular weight olefins in a reaction zone under conditions of elevated temperature and pressure with a shape selective crystalline aluminosilicate catalyst, comprising: reducing the non-shape selective surface-cracking and/or surface isomerization activity of the aluminosilicate catalyst by a process comprising: preparing an aqueous solution comprising colloidal silica, optionally an organic directing agent, and a source of hydroxide ions; mixing the aqueous solution with an aqueous dispersion of shape-selective crystalline aluminosilicate to form a homogeneous mixture which is subsequently heated; adding an aqueous solution comprising a source of fluoride ions to the homogeneous mixture to form a reactive composition; heating the reactive composition at a temperature to effectively form a surface-deactivated catalyst comprising a crystalline fluoride-containing silica outer shell on an aluminosilicate; withdrawing the surface-deactivated catalyst from the reactive composition for washing, drying, and calcining of the catalyst; and removing the catalyst to the reaction zone for contact with the olefin feedstock.

  5. Asymmetry of rotational catalysis of single membrane-bound F0F1-ATP synthase

    E-Print Network [OSTI]

    Zarrabi, Nawid; Diez, Manuel; Graeber, Peter; Wrachtrup, Joerg; Boersch, Michael

    2007-01-01T23:59:59.000Z

    Synthesis of the cellular 'energy currency' ATP is catalyzed by membrane-bound F0F1-ATP synthases. The chemical reaction at three binding sites in the F1 part is coupled to proton translocation through the membrane-integrated F0 part by an internal rotation of subunits. We examined the rotary movements of the epsilon-subunit of the 'rotor' with respect to the b-subunits of the 'stator' by single-molecule fluorescence resonance energy transfer (FRET). Rotation of epsilon during ATP hydrolysis is divided into three major steps with constant FRET level corresponding to three binding sites. Different catalytic activities of the individual binding sites were observed depending on the relative orientation of the 'rotor'. Computer simulations of the FRET signals and non-equally distributed orientations of epsilon strongly corroborate asymmetry of catalysis in F0F1-ATP synthase.

  6. Methane Oxidation to Methanol without CO2 Emission: Catalysis by Atomic Negative Ions

    E-Print Network [OSTI]

    Tesfamichael, Aron; Felfli, Zineb; Msezane, Alfred Z

    2014-01-01T23:59:59.000Z

    The catalytic activities of the atomic Y-, Ru-, At-, In-, Pd-, Ag-, Pt-, and Os- ions have been investigated theoretically using the atomic Au- ion as the benchmark for the selective partial oxidation of methane to methanol without CO2 emission. Dispersion-corrected density-functional theory has been used for the investigation. From the energy barrier calculations and the thermodynamics of the reactions, we conclude that the catalytic effect of the atomic Ag-, At-, Ru-, and Os- ions is higher than that of the atomic Au- ion catalysis of CH4 conversion to methanol. By controlling the temperature around 290K (Os-), 300K (Ag-), 310K (At-), 320K (Ru-) and 325K (Au-) methane can be completely oxidized to methanol without the emission of CO2. We conclude by recommending the investigation of the catalytic activities of combinations of the above negative ions for significant enhancement of the selective partial oxidation of methane to methanol.

  7. Is It Homogeneous or Heterogeneous Catalysis Derived from [RhCp*Cl2]2? In Operando-XAFS, Kinetic and Crucial Kinetic Poisoning Evidence for Subnanometer Rh4 Cluster-Based Benzene Hydrogenation Catalysis

    SciTech Connect (OSTI)

    Bayram, Ercan; Linehan, John C.; Fulton, John L.; Roberts, John A.; Szymczak, Nathaniel; Smurthwaite, Tricia D.; Ozkar, Saim; Balasubramanian, Mahalingam; Finke, Richard G.

    2011-11-23T23:59:59.000Z

    Determining the true, kinetically dominant catalytically active species, in the classic benzene hydrogenation system pioneered by Maitlis and co-workers 34 years ago starting with [RhCp*Cl2]2 (Cp* = [{eta}5-C5(CH3)5]), has proven to be one of the most challenging case studies in the quest to distinguish single-metal-based 'homogeneous' from polymetallic, 'heterogeneous' catalysis. The reason, this study will show, is the previous failure to use the proper combination of (i) operando spectroscopy to determine the dominant form(s) of the precatalyst's mass under catalysis (i.e., operating) conditions, plus then and crucially also (ii) the previous lack of the necessary kinetic studies, catalysis being a 'wholly kinetic phenomenon' as J. Halpern long ago noted. An important contribution from this study will be to reveal the power of quantitiative kinetic poisoning experiments for distinguishing single-metal, or in this case subnanometer Rh4 cluster-based catalysis from larger, polymetallic Rh(0)n nanoparticle catalysis, at least under favorable conditions. The combined operando-XAFS (X-ray absorption fine structure) spectroscopy and kinetic evidences provide a compelling case for Rh4-based, with average stoichiometry 'Rh4Cp*2.4Cl4Hc', benzene hydrogenation catalysis in 2-propanol with added Et3N and at 100 C and 50 atm initial H2 pressure. The results also reveal, however, that if even ca. 1.4% of the total soluble Rh(0)n had formed nanoparticles, then those Rh(0)n nanoparticles would have been able to account for all the observed benzene hydrogenation catalytic rate (using commercial, ca. 2 nm, polyethyleneglycol-dodecylether hydrosol stabilized Rh(0)n nanoparticles as a model system). The results 'especially the poisoning methodology developed and employed' are of significant, broader interest since determining the nature of the true catalyst continues to be a central, often vexing issue in any and all catalytic reactions. The results are also of fundamental interest in that they add to a growing body of evidence indicating that certain, appropriately ligated, coordinatively unsaturated, subnanometer M4 transition-metal clusters can be relatively robust catalysts. Also demonstrated herein is that Rh4 clusters are poisoned by Hg(0), demonstrating for the first time that the classic Hg(0) poisoning test of 'homogeneous' vs 'heterogeneous'catalysts cannot distinguish Rh4-based subnanometer catalysts from Rh(0)n nanoparticle catalysts, at least for the present examples of these two specific, Rh-based catalysts.

  8. Journal of Machine Learning Research 13 (2012) 2237-2278 Submitted 6/10; Revised 9/11; Published 8/12 MedLDA: Maximum Margin Supervised Topic Models

    E-Print Network [OSTI]

    Xing, Eric P.

    2012-01-01T23:59:59.000Z

    15213, USA Editor: David Blei Abstract A supervised topic model can use side information such as ratings latent aspect models such as the latent Dirichlet allocation (LDA) model (Blei et al., 2003) have be text documents (Blei et al., 2003), images (Fei-Fei and Perona, 2005), or even network entities

  9. Journal of Machine Learning Research 13 (2012) 2233-2236 Submitted 10/11; Revised 1/12; Published 8/12 A Topic Modeling Toolbox Using Belief Propagation

    E-Print Network [OSTI]

    Kaski, Samuel

    2012-01-01T23:59:59.000Z

    decade has seen rapid development of latent Dirichlet allocation (LDA) (Blei et al., 2003) for solving efficient approximate inference methods such as Variational Bayes (VB) (Blei et al., 2003) and collapsed (ATM) (Rosen-Zvi et al., 2004), relational topic models (RTM) (Chang and Blei, 2010), and labeled LDA

  10. Journal of Machine Learning Research 13 (2012) xx-xx Submitted 6/10; Revised 9/11; Published xx/12 MedLDA: Maximum Margin Supervised Topic Models

    E-Print Network [OSTI]

    Tomkins, Andrew

    2012-01-01T23:59:59.000Z

    15213, USA Editor: David Blei Abstract A supervised topic model can utilize side information. Introduction Probabilistic latent aspect models such as the latent Dirichlet allocation (LDA) model (Blei et al be text documents (Blei et al., 2003), images (Fei-Fei and Perona, 2005), or even network entities

  11. Superacid catalysis of light hydrocarbon conversion. Sixth quarterly report, January 1, 1995--March 31, 1995

    SciTech Connect (OSTI)

    Gates, B.C. [California Univ., Davis, CA (United States). Dept. of Chemical Engineering and Materials Science

    1995-08-01T23:59:59.000Z

    Iron- and Manganese-promoted sulfated zirconia is a catalyst for the conversion of propane, but the rate of conversion of propane is much less than the rate of conversion of butane. Whereas this catalyst appears to be a good candidate for practical, industrial conversion of butane, it appears to lack sufficient activity for practical conversion of propane. Perhaps more active catalysts will be useful for propane conversion. The propane conversion data reported here provide excellent insights into the chemistry of the catalytic conversions; they are consistent with the inference that the catalyst is a superacid and that the chemistry is analogous to. that determined in superacid solutions by G.A. Olah, who was awarded the most recent Nobel Prize in chemistry for his work. The catalyst was tested for conversion of propane at 1 bar, 200--300{degrees}C and propane partial pressures in the range of 0.01--0.05 bar. At 250{degrees}C, catalysis was demonstrated, as the number of propane molecules converted was at least 1 per sulfate group after 16 days of operation in a continues flow reactor. Propane was converted in high yield to butanes, but the conversions were low, for example being only a fraction of a percent at a space velocity of 9.1 {times} 10{sup {minus}7} mol(g of catalysis {center_dot} s) and 250{degrees}C. Coke formation was rapid. The observation of butanes, pentanes, and methane as products is consistent with Olah superacid chemistry, whereby propane is first protonated by a very strong acid to form a carbonium ion. The carbonium ion then decomposes into methane and an ethyl cation which undergoes oligocondensation reactions with propane to form higher molecular weight alkanes. The results are consistent with the identification of iron- and manganese-promoted sulfated zirconia as a superacid.

  12. architecture as topic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    architecture as topic First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Topic 1: Internet Architecture &...

  13. Collaboration Topics - Visualization | National Nuclear Security...

    National Nuclear Security Administration (NNSA)

    Simulation and Computing and Institutional R&D Programs NNSACEA Cooperation in Computer Science Collaboration Topics - Visualization Collaboration Topics - Visualization...

  14. active stabilizer tyloxapol: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    screened for compounds containing the pharmacophore. Forty-seven compounds resulted from Marshall, Garland R. 48 Nano-Catalysis: Fibrous morphology makes the difference in...

  15. activation monitoring solution: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of catalysis (Vmax). The protocol used to measure viscosity by means of a falling ball type viscometer is described, together with the determination of enzyme kinetics and the...

  16. allopurinol gel mitigates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Description Engineering Websites Summary: , separations science, chemical catalysis and coatings science. By definition the sol-gel process starts materials. The resulting films,...

  17. aloe vera gel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Description Engineering Websites Summary: , separations science, chemical catalysis and coatings science. By definition the sol-gel process starts materials. The resulting films,...

  18. active du sol: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Description Engineering Websites Summary: , separations science, chemical catalysis and coatings science. By definition the sol-gel process starts materials. The resulting films,...

  19. aluminum hydroxide gel: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Description Engineering Websites Summary: , separations science, chemical catalysis and coatings science. By definition the sol-gel process starts materials. The resulting films,...

  20. alginate gel beads: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Description Engineering Websites Summary: , separations science, chemical catalysis and coatings science. By definition the sol-gel process starts materials. The resulting films,...

  1. active polar gels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Description Engineering Websites Summary: , separations science, chemical catalysis and coatings science. By definition the sol-gel process starts materials. The resulting films,...

  2. aux sols pollues: Topics by E-print Network

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    Description Engineering Websites Summary: , separations science, chemical catalysis and coatings science. By definition the sol-gel process starts materials. The resulting films,...

  3. agarose gel electrophoresis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Description Engineering Websites Summary: , separations science, chemical catalysis and coatings science. By definition the sol-gel process starts materials. The resulting films,...

  4. agarose gel electrophoretic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Description Engineering Websites Summary: , separations science, chemical catalysis and coatings science. By definition the sol-gel process starts materials. The resulting films,...

  5. agar gel immunodiffusion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Description Engineering Websites Summary: , separations science, chemical catalysis and coatings science. By definition the sol-gel process starts materials. The resulting films,...

  6. al sol sobre: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Description Engineering Websites Summary: , separations science, chemical catalysis and coatings science. By definition the sol-gel process starts materials. The resulting films,...

  7. acetate isobutyrate gels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Description Engineering Websites Summary: , separations science, chemical catalysis and coatings science. By definition the sol-gel process starts materials. The resulting films,...

  8. acc synthase expression: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    corroborate asymmetry of catalysis in F0F1-ATP synthase. Zarrabi, Nawid; Diez, Manuel; Graeber, Peter; Wrachtrup, Joerg; Boersch, Michael 2007-01-01 202 expression? Environments...

  9. acetolactate synthase activity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    corroborate asymmetry of catalysis in F0F1-ATP synthase. Zarrabi, Nawid; Diez, Manuel; Graeber, Peter; Wrachtrup, Joerg; Boersch, Michael 2007-01-01 33 Pharmacological inhibitors...

  10. atp dependent chromatin: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    corroborate asymmetry of catalysis in F0F1-ATP synthase. Zarrabi, Nawid; Diez, Manuel; Graeber, Peter; Wrachtrup, Joerg; Boersch, Michael 2007-01-01 64 Regulation of...

  11. acid anew insights: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is the sequence of amino acids produced, and because amino acids average about Texas at San Antonio, University of 290 Combined Acid Catalysis for Asymmetric Synthesis Chemistry...

  12. airfoil characteristics synthesization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    an amino acid representation ... de la Maza, Michael 1993-05-01 166 Mechanochemistry for Solid-State Syntheses and Catalysis. Open Access Theses and Dissertations Summary:...

  13. asia pacific rim: Topics by E-print Network

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    8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Forestry Research in Asia and Pacific1 CiteSeer Summary: Abstract: Much research has been done...

  14. TECHNICAL STANDARDS PROGRAM TOPICAL COMMITTEES

    Broader source: Energy.gov [DOE]

    PurposeThis procedure describes how topical committees are organized and recognized under the Technical Standards Program. 

  15. Andrew Salway Uni Research, Bergen

    E-Print Network [OSTI]

    Bradstock, Burton

    , people, government, nations, policy, china, issues, sustainable Other topics: "energy", "wildlife blog corpus English-language blogs that mention broad climate change issues across science, politics, year, ocean, time, temperatures, scientific, research "climate change politics": climate, change

  16. Mesoporous Silica Nanomaterials for Applications in Catalysis, Sensing, Drug Delivery and Gene Transfection

    SciTech Connect (OSTI)

    Daniela Rodica Radu

    2005-12-19T23:59:59.000Z

    The central theme of this dissertation is represented by the versatility of mesoporous silica nanomaterials in various applications such as catalysis and bio-applications, with main focus on biological applications of Mesoporous Silica Nanospheres (MSN). The metamorphosis that we impose to these materials from catalysis to sensing and to drug and gene delivery is detailed in this dissertation. First, we developed a synthetic method that can fine tune the amount of chemically accessible organic functional groups on the pores surface of MSN by exploiting electrostatic and size matching between the cationic alkylammonium head group of the cetyltrimethylammonium bromide (CTAB) surfactant and various anionic organoalkoxysilane precursors at the micelle-water interface in a base-catalyzed condensation reaction of silicate. Aiming nature imitation, we demonstrated the catalytic abilities of the MSNs, We utilized an ethylenediamine functional group for chelating Cu{sup 2+} as a catalytic functional group anchored inside the mesopores. Thus, a polyalkynylene-based conducting polymer (molecular wire) was synthesized within the Cu-functionalized MSNs silica catalyst. For sensing applications, we have synthesized a poly(lactic acid) coated mesoporous silica nanosphere (PLA-MSN) material that serves as a fluorescence sensor system for detection of amino-containing neurotransmitters in neutral aqueous buffer. We exploited the mesoporosity of MSNs for encapsulating pharmaceutical drugs. We examined bio-friendly capping molecules such as polyamidoamine dendrimers of generations G2 to G4, to prevent the drug leaching. Next, the drug delivery system employed MSNs loaded with Doxorubicin, an anticancer drug. The results demonstrated that these nano-Trojan horses have ability to deliver Doxorubicin to cancer cells and induce their death. Finally, to demonstrate the potential of MSN as an universal cellular transmembrane nanovehicle, we anchored positively charged dendrimers on the surface of MSN and utilize them to complex cationic DNA. The p-EGFP-CI gene-coated MSN nanocomposite was able to transfect cancer cell lines, such as human HeLa and CHO cancer cell lines. The gene carrier ability of MSNs was further proved by transfecting primary cells and cotransfecting of two different genes in cancer cell lines. In sum, MSN are versatile partners in several types of applications.

  17. Probing the Impact of the EchinT C-Terminal Domain on Structure and Catalysis

    SciTech Connect (OSTI)

    S Bardaweel; J Pace; T Chou; V Cody; C Wagner

    2011-12-31T23:59:59.000Z

    Histidine triad nucleotide binding protein (Hint) is considered as the ancestor of the histidine triad protein superfamily and is highly conserved from bacteria to humans. Prokaryote genomes, including a wide array of both Gram-negative bacteria and Gram-positive bacteria, typically encode one Hint gene. The cellular function of Hint and the rationale for its evolutionary conservation in bacteria have remained a mystery. Despite its ubiquity and high sequence similarity to eukaryote Hint1 [Escherichia coli Hint (echinT) is 48% identical with human Hint1], prokaryote Hint has been reported in only a few studies. Here we report the first conformational information on the full-length N-terminal and C-terminal residues of Hint from the E. coli complex with GMP. Structural analysis of the echinT-GMP complex reveals that it crystallizes in the monoclinic space group P2{sub 1} with four homodimers in the asymmetric unit. Analysis of electron density for both the N-terminal residues and the C-terminal residues of the echinT-GMP complex indicates that the loops in some monomers can adopt more than one conformation. The observation of conformational flexibility in terminal loop regions could explain the presence of multiple homodimers in the asymmetric unit of this structure. To explore the impact of the echinT C-terminus on protein structure and catalysis, we conducted a series of catalytic radiolabeling and kinetic experiments on the C-terminal deletion mutants of echinT. In this study, we show that sequential deletion of the C-terminus likely has no effect on homodimerization and a modest effect on the secondary structure of echinT. However, we observed a significant impact on the folding structure, as reflected by a significant lowering of the T{sub m} value. Kinetic analysis reveals that the C-terminal deletion mutants are within an order of magnitude less efficient in catalysis compared to wild type, while the overall kinetic mechanism that proceeds through a fast step, followed by a rate-limiting hydrolysis step, was conserved. Nevertheless, the ability of the C-terminal deletion mutants to hydrolyze lysyl-AMP generated by LysU was greatly impaired. Taken together, our results highlight the emerging role of the C-terminus in governing the catalytic function of Hints.

  18. Sandia Combustion Research: Technical review

    SciTech Connect (OSTI)

    NONE

    1995-07-01T23:59:59.000Z

    This report contains reports from research programs conducted at the Sandia Combustion Research Facility. Research is presented under the following topics: laser based diagnostics; combustion chemistry; reacting flow; combustion in engines and commercial burners; coal combustion; and industrial processing. Individual projects were processed separately for entry onto the DOE databases.

  19. assessment topics thermal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    they are meaningful. We Pratt, Vaughan 2 ENVE 569 ENVIRONMENTAL RISK ASSESSMENT TOPIC SYLLABUS Environmental Sciences and Ecology Websites Summary: ENVE 569 - ENVIRONMENTAL RISK...

  20. ans topical meeting: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    automated (comput... Sandip Sen 1996-01-01 12 International Topical Meeting on Nuclear Reactor Thermal Hydraulics (NURETH-13) N13P1395 Kanazawa City, Ishikawa Prefecture, Japan,...

  1. administration topical: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    presented on topics as diverse as materials degredation in low Earth orbit, the Martian environment and several aspects of the still commercially dominant geostationary orbit. A...

  2. automatic topic indexing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    subject headings in libraries, as keywords in academic publications and as tags on the web. Knowing a documents topics helps people judge its relevance quickly. However,...

  3. Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenation of m-Cresol

    SciTech Connect (OSTI)

    Hong, Yongchun; Zhang, He; Sun, Junming; Karim, Ayman M.; Hensley, Alyssa; Gu, Meng; Engelhard, Mark H.; McEwen, Jean-Sabin; Wang, Yong

    2014-10-31T23:59:59.000Z

    In this work, a series of Pd/Fe2O3 catalysts were synthesized, characterized, and evaluated for the hydrodeoxygenation (HDO) of m-cresol. It was found that the addition of Pd remarkably promotes the catalytic activity of Fe while the product distributions resemble that of monometallic Fe catalyst, showing high selectivity towards the production of toluene (C-O cleavage without saturation of aromatic ring and C-C cleavage). Reduced catalysts featured with Pd patches on the top of reduced Fe nanoparticle surface, and the interaction between Pd and Fe was further confirmed using X-ray photoelectron spectroscopy (XPS), scanning transmission electron microscopy (STEM) and X-ray absorption near edge fine structure (XANES). A possible mechanism, including Pd assisted H2 dissociation and Pd facilitated stabilization of metallic Fe surface as well as Pd enhanced product desorption, is proposed to be responsible for the high activity and HDO selectivity in Pd-Fe catalysts. The synergic catalysis derived from Pd-Fe interaction found in this work was proved to be applicable to other precious metal promoted Fe catalysts, providing a promising strategy for future design of highly active and selective HDO catalysts.

  4. Steam catalysis in CaO carbonation under low steam partial pressure

    SciTech Connect (OSTI)

    Yang, S.J.; Xiao, Y.H. [Chinese Academy of Science, Beijing (China)

    2008-06-15T23:59:59.000Z

    CaO was widely used to capture CO{sub 2} in direct hydrogen production process, where steam always existed simultaneously. The effect of steam on CaO carbonation performance under low steam partial pressure was investigated using a pressurized thermogravimetric apparatus. The experimental results revealed that steam improved CaO carbonation performance significantly no matter whether Ca(OH){sub 2} was produced or not. At 823 K and 0.5 MPa of steam partial pressure, effect of steam on CaO carbonation performance could not be attributed mainly to production of Ca(OH){sub 2} because the hydration rate of CaO was very slow. The main reason was steam catalysis in CaO carbonation. Enhancement of steam on CaO carbonation performance without Ca(OH){sub 2} production could not be attributed to improvement of steam on the physical property, but to catalytic effect of steam. Effects of CaO precursors, CO{sub 2} partial pressure, steam partial pressure, and temperature with steam addition on CaO carbonation performance were also investigated.

  5. Molecular Insights into Substrate Recognition and Catalysis by Tryptophan 2,3-dioxygenase

    SciTech Connect (OSTI)

    Forouhar,F.; Ross Anderson, J.; Mowat, C.; Vorobiev, S.; Hussain, A.; Abashidze, M.; Bruckmann, C.; Thackray, S.; Seetharaman, J.; et al.

    2007-01-01T23:59:59.000Z

    Tryptophan 2,3-dioxygenase (TDO) and indoleamine 2,3-dioxygenase (IDO) constitute an important, yet relatively poorly understood, family of heme-containing enzymes. Here, we report extensive structural and biochemical studies of the Xanthomonas campestris TDO and a related protein SO4414 from Shewanella oneidensis, including the structure at 1.6-{angstrom} resolution of the catalytically active, ferrous form of TDO in a binary complex with the substrate l-Trp. The carboxylate and ammonium moieties of tryptophan are recognized by electrostatic and hydrogen-bonding interactions with the enzyme and a propionate group of the heme, thus defining the l-stereospecificity. A second, possibly allosteric, l-Trp-binding site is present at the tetramer interface. The sixth coordination site of the heme-iron is vacant, providing a dioxygen-binding site that would also involve interactions with the ammonium moiety of l-Trp and the amide nitrogen of a glycine residue. The indole ring is positioned correctly for oxygenation at the C2 and C3 atoms. The active site is fully formed only in the binary complex, and biochemical experiments confirm this induced-fit behavior of the enzyme. The active site is completely devoid of water during catalysis, which is supported by our electrochemical studies showing significant stabilization of the enzyme upon substrate binding.

  6. SERS internship spring 1996 abstracts and research papers

    SciTech Connect (OSTI)

    Williams, B.

    1996-07-01T23:59:59.000Z

    This is the student symposium for the Science & Engineering Research Semester, May 2-3, 1996. A variety of topics are covered.

  7. Nanoscale Synthesis and Functional Assembly Center for Nanophase Materials Science and

    E-Print Network [OSTI]

    Pennycook, Steve

    Society 2001­p Journal Reviewer: Applied Catalysis, Catalysis Communications, Chemical Communications catalysis, nanomaterials for catalysis and photocatalysis, and applied spectroscopy. Specific techniques­2003 Research Associate, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, China

  8. Topics for letter "s" | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Development Lab Quiet Wing RadEMSL Virtual Tour Topics for letter "s" samples scale scanning scanning electron microscope scanning probe scanning tunneling microscopy...

  9. Topics for letter "W" | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Virtual Tour Topics for letter "W" W-band pulsed EPR spectrometer Washington State Academy of Sciences Washington State University waste storage water water cycling Wiley Wiley...

  10. Topics for letter "p" | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Wing RadEMSL Virtual Tour Topics for letter "p" particles patents physics plants pollution polymers pore scale postdoc postdocs postdoctoral Postdoctoral Opportunities...

  11. absorption system topical: Topics by E-print Network

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    absorption system topical First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 INFORMATION SYSTEMS UNIT...

  12. UNIRIB: Physics Topics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengthening aTurbulence may bedieselsummer gasoline price0 -Physics Topics

  13. Collaboration Topics - Acceleration Hardware and APIs | National...

    National Nuclear Security Administration (NNSA)

    Simulation and Computing and Institutional R&D Programs NNSACEA Cooperation in Computer Science Collaboration Topics - Acceleration Hardware and APIs Collaboration Topics...

  14. Collaboration Topics - Meshing | National Nuclear Security Administrat...

    National Nuclear Security Administration (NNSA)

    Simulation and Computing and Institutional R&D Programs NNSACEA Cooperation in Computer Science Collaboration Topics - Meshing Collaboration Topics - Meshing This work...

  15. advanced technology proposal: Topics by E-print Network

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    technology proposal First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Proposed Research Center Biomedical...

  16. aviles giga energy: Topics by E-print Network

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    aviles giga energy First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Evolutionary Ecology Research, 1999,...

  17. akt1 nuclear localization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    akt1 nuclear localization First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Edinburgh Research Explorer...

  18. air force materials: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    air force materials First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Air Force Research Laboratory...

  19. Preface: Special Topic on Interfacial and Confined Water

    SciTech Connect (OSTI)

    Molinero, Valeria; Kay, Bruce D.

    2014-11-14T23:59:59.000Z

    This Special Topic on the Chemical Physics of Interfacial and Confined Water contains a collection of original research papers that showcase recent theoretical and experimental advances in the field. These papers provide a timely discussion of fundamental aspects of interfacial and confined water that are important in both natural environments and engineered applications.

  20. adult salivary glands: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    adult salivary glands First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 RESEARCH ARTICLE Open Access...