National Library of Energy BETA

Sample records for research topics catalysis

  1. Basic Research Needs: Catalysis for Energy

    SciTech Connect (OSTI)

    Bell, Alexis T.; Gates, Bruce C.; Ray, Douglas; Thompson, Michael R.

    2008-03-11

    The report presents results of a workshop held August 6-8, 2007, by DOE SC Basic Energy Sciences to determine the basic research needs for catalysis research.

  2. Seventh BES (Basic Energy Sciences) catalysis and surface chemistry research conference

    SciTech Connect (OSTI)

    Not Available

    1990-03-01

    Research programs on catalysis and surface chemistry are presented. A total of fifty-seven topics are included. Areas of research include heterogeneous catalysis; catalysis in hydrogenation, desulfurization, gasification, and redox reactions; studies of surface properties and surface active sites; catalyst supports; chemical activation, deactivation; selectivity, chemical preparation; molecular structure studies; sorption and dissociation. Individual projects are processed separately for the data bases. (CBS)

  3. Pre-Competitive Catalysis Research: Fundamental Sulfation/Desulfation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pre-Competitive Catalysis Research: Fundamental SulfationDesulfation Studies of Lean NOx Traps Pre-Competitive Catalysis Research: Fundamental SulfationDesulfation Studies of...

  4. Opportunities in Catalysis Research Using Synchrotron Radiation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Catalysis Research Using Synchrotron Radiation Tuesday 10/8/02 Chair: Lars Pettersson 1:30-1:40 Anders Nilsson Welcome 1:40-2:30 Gabor Somorjai University of California, Berkeley and LBLN Need for New Directions of Research at the Frontiers of Catalysis Science 2:30-3:00 Geoff Thornton University of Manchester Influence of defects on the reactivity of ZnO 3:00-3:30 Anders Nilsson Stanford Synchrotron Radiation Laboratory Soft X-ray Spectroscopy of Surfaces and Reactions 3:30-3:45 Break Chair:

  5. Advanced Resources for Catalysis Science; Recommendations for a National Catalysis Research Institute

    SciTech Connect (OSTI)

    Peden, Charles HF.; Ray, Douglas

    2005-10-05

    Catalysis is one of the most valuable contributors to our economy and historically an area where the United States has enjoyed, but is now losing, international leadership. While other countries are stepping up their work in this area, support for advanced catalysis research and development in the U.S. has diminished. Yet, more than ever, innovative and improved catalyst technologies are imperative for new energy production processes to ease our dependence on imported resources, for new energy-efficient and environmentally benign chemical production processes, and for new emission reduction technologies to minimize the environmental impact of an active and growing economy. Addressing growing concerns about the future direction of U.S. catalysis science, experts from the catalysis community met at a workshop to determine and recommend advanced resources needed to address the grand challenges for catalysis research and development. The workshop's primary conclusion: To recapture our position as the leader in catalysis innovation and practice, and promote crucial breakthroughs, the U.S. must establish one or more well-funded and well-equipped National Catalysis Research Institutes competitively selected, centered in the national laboratories and, by charter, networked to other national laboratories, universities, and industry. The Institute(s) will be the center of a national collaboratory that gives catalysis researchers access to the most advanced techniques available in the scientific enterprise. The importance of catalysis to our energy, economic, and environmental security cannot be overemphasized. Catalysis is a vital part of our core industrial infrastructure, as it is integral to chemical processing and petroleum refining, and is critical to proposed advances needed to secure a sustainable energy future. Advances in catalysis could reduce our need for foreign oil by making better use of domestic carbon resources, for example, allowing cost-effective and zero emission conversion of coal into transportation fuels. No matter what energy sources are being considered (oil, natural gas, coal, biomass, solar, or nuclear based), a clean, sustainable energy future will involve catalysis to improve energy efficiency and storage and use options, and to mitigate environmental impacts. Recent revolutionary advances in nanotechnology and high-performance computing are enabling the breakthroughs in catalysis science and technology essential for a secure energy future. Thus, the time is right for substantially increased investments in catalysis science and technology.

  6. DOE Laboratory Catalysis Research Symposium - Abstracts

    SciTech Connect (OSTI)

    Dunham, T.

    1999-02-01

    The conference consisted of two sessions with the following subtopics: (1) Heterogeneous Session: Novel Catalytic Materials; Photocatalysis; Novel Processing Conditions; Metals and Sulfides; Nuclear Magnetic Resonance; Metal Oxides and Partial Oxidation; Electrocatalysis; and Automotive Catalysis. (2) Homogeneous Catalysis: H-Transfer and Alkane Functionalization; Biocatalysis; Oxidation and Photocatalysis; and Novel Medical, Methods, and Catalyzed Reactions.

  7. Dedicated Beamline Facilities for Catalytic Research. Synchrotron Catalysis Consortium (SCC)

    SciTech Connect (OSTI)

    Chen, Jingguang; Frenkel, Anatoly; Rodriguez, Jose; Adzic, Radoslav; Bare, Simon R.; Hulbert, Steve L.; Karim, Ayman; Mullins, David R.; Overbury, Steve

    2015-03-04

    Synchrotron spectroscopies offer unique advantages over conventional techniques, including higher detection sensitivity and molecular specificity, faster detection rate, and more in-depth information regarding the structural, electronic and catalytic properties under in-situ reaction conditions. Despite these advantages, synchrotron techniques are often underutilized or unexplored by the catalysis community due to various perceived and real barriers, which will be addressed in the current proposal. Since its establishment in 2005, the Synchrotron Catalysis Consortium (SCC) has coordinated significant efforts to promote the utilization of cutting-edge catalytic research under in-situ conditions. The purpose of the current renewal proposal is aimed to provide assistance, and to develop new sciences/techniques, for the catalysis community through the following concerted efforts: Coordinating the implementation of a suite of beamlines for catalysis studies at the new NSLS-II synchrotron source; Providing assistance and coordination for catalysis users at an SSRL catalysis beamline during the initial period of NSLS to NSLS II transition; Designing in-situ reactors for a variety of catalytic and electrocatalytic studies; Assisting experimental set-up and data analysis by a dedicated research scientist; Offering training courses and help sessions by the PIs and co-PIs.

  8. Center for Biological Electron Transfer and Catalysis (BETCy...

    Office of Science (SC) Website

    Research Topics solar (fuels), biofuels (including algae and biomass), bio-inspired, ... 5 GrandChallenge 2 Grand Challenge 2 BES Reports Catalysis Hydrogen Solar Energy

  9. Funding Topics for Small Business Innovation Research and Small...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Topics for Small Business Innovation Research and Small Business Technology Transfer Programs Funding Topics for Small Business Innovation Research and Small Business Technology ...

  10. 2010 CATALYSIS GORDON RESEARCH CONFERENCE, JUNE 27 - JULY 2, 2010, NEW LONDON, NEW HAMPSHIRE

    SciTech Connect (OSTI)

    Abhaya Datye

    2010-07-02

    Catalysis is a key technology for improving the quality of life while simultaneously reducing the adverse impact of human activities on the environment. The discovery of new catalytic processes and the improvement of existing ones are also critically important for securing the nation's energy supply. The GRC on Catalysis is considered one the most prestigious conference for catalysis research, bringing together leading researchers from both academia, industry and national labs to discuss the latest, most exciting research in catalysis and the future directions for the field. The 2010 GRC on Catalysis will follow time-honored traditions and feature invited talks from the world's leading experts in the fundamentals and applications of catalytic science and technology. We plan to have increased participation from industry. The extended discussions in the company of outstanding thinkers will stimulate and foster new science. The conference will include talks in the following areas: Alternative feedstocks for chemicals and fuels, Imaging and spectroscopy, Design of novel catalysts, Catalyst preparation fundamentals, Molecular insights through theory, Surface Science, Catalyst stability and dynamics. In 2010, the Catalysis conference will move to a larger conference room with a new poster session area that will allow 40 posters per session. The dorm rooms provide single and double accommodations, free WiFi and the registration fee includes all meals and the famous lobster dinner on Thursday night. Afternoons are open to enjoy the New England ambiance with opportunities for hiking, sailing, golf and tennis to create an outstanding conference that will help you network with colleagues, and make long lasting connections.

  11. Catalysis Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Opportunities in Catalysis Research Using Synchrotron Radiation Stanford Synchrotron Radiation Laboratory October 8-9, 2002 Organizer: Anders Nilsson Chemical catalysis is one of the research areas of enormous importance for the industrial society. There are important challenges to be met in the near future where development of new processes and catalysts are a necessity. We need to find a way to make methanol from methane, split water into hydrogen using sunlight, find replacement of platinum

  12. This research was supported as part of the Catalysis Center for Energy Innovatio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This research was supported as part of the Catalysis Center for Energy Innovation, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Improving Efficiencies in Fuel, Chemical and Pharmaceutical Industries Repetitive branching, a novel and simple synthesis method, produces zeolite crystals with large-pore "highways" that improve transport and utilization of chemicals within the crystal This research was

  13. Funding Topics for Small Business Innovation Research and Small Business

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Transfer Programs | Department of Energy Topics for Small Business Innovation Research and Small Business Technology Transfer Programs Funding Topics for Small Business Innovation Research and Small Business Technology Transfer Programs Each year, the Office of Energy Efficiency and Renewable Energy's (EERE's) Small Business Innovation Research (SBIR) and Small Business Technology Transfer (STTR) programs issue Funding Opportunity Announcements (FOAs), which invite established or

  14. Events & Topics | Metrolink Tour | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics | Metrolink Tour Events & Topics | Metrolink Tour

  15. Virtual special issue on catalysis at the U.S. Department of Energy's National Laboratories

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pruski, Marek; Sadow, Aaron D.; Slowing, Igor I.; Marshall, Christopher L.; Stair, Peter; Rodriguez, Jose; Harris, Alex; Somorjai, Gabor A.; Biener, Juergen; Matranga, Christopher; et al

    2016-04-21

    Here the catalysis research at the U.S. Department of Energy's (DOE's) National Laboratories covers a wide range of research topics in heterogeneous catalysis, homogeneous/molecular catalysis, biocatalysis, electrocatalysis, and surface science. Since much of the work at National Laboratories is funded by DOE, the research is largely focused on addressing DOE's mission to ensure America's security and prosperity by addressing its energy, environmental, and nuclear challenges through transformative science and technology solutions.

  16. Biomimetic Chalcogels for Solar Fuel Catalysis | ANSER Center...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biomimetic Chalcogels for Solar Fuel Catalysis Home > Research > ANSER Research Highlights > Biomimetic Chalcogels for Solar Fuel Catalysis...

  17. Chemistry {ampersand} Materials Science progress report summary of selected research and development topics, FY97

    SciTech Connect (OSTI)

    Newkirk, L.

    1997-12-01

    This report contains summaries of research performed in the Chemistry and Materials Science division. Topics include Metals and Ceramics, High Explosives, Organic Synthesis, Instrument Development, and other topics.

  18. Hot Topics Workshop - February 2015 | Photosynthetic Antenna Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center - February 2015 Hot Topics Workshop - February 2015 Shots from our Hot Topics Workshop: Energy and the Environment for Secondary Science Teachers. Original Event Info found here

  19. Small Business Innovation Research Program Topics- October 28, 2013

    Broader source: Energy.gov [DOE]

    This document outlines the topics covered by the 2013-14 SBIR funding opportunity announcement and show the details of how to apply for the program.

  20. Hot Topics Workshop-Summer 2014 | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Workshop-Summer 2014 Hot Topics Workshop-Summer 2014 Teachers from St. Louis area schools were welcomed to Washington University in St. Louis to learn about new, exciting classroom activities centered around Solar, Wind, and Biomass energy.

  1. Events & Topics In Bioenergy | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics In Bioenergy Events & Topics In Bioenergy Dr. Chenyang Lu Smart Building with Wireless Sensor Networks Dr. Joseph Cullen "Measuring the Environmental Benefits of Wind Power" Dr. Pratim Biswas "Aerosol nanoparticle technology enabling solar energy applications: Biohybrid and biomimetic solar devices" Dr. Dewey Holten "Bioinspired and Biohybrid photosynthetic antenna systems for energy applications" Mark Henson "Modeling the Production of

  2. Biomimetic Chalcogels for Solar Fuel Catalysis | ANSER Center |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne-Northwestern National Laboratory Biomimetic Chalcogels for Solar Fuel Catalysis Home > Research > ANSER Research Highlights > Biomimetic Chalcogels for Solar Fuel Catalysis

  3. Catalysis Capabilities | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalysis Research Areas Facilities and Equipment Intellectual Property Publications Staff Partnerships Licensing Sponsored Research Technical Services Technologist in Residence News Press Releases Feature Stories In the News Photos Videos Ombudsman Ombudsman Argonne National Laboratory Technology Development and Commercialization About Technologies Available for Licensing Capabilities Partnerships News Capabilities Catalysis Research Areas Facilities and Equipment Intellectual Property

  4. Neutrons for Catalysis: A Workshop on Neutron Scattering Techniques for Studies in Catalysis

    SciTech Connect (OSTI)

    Overbury, Steven {Steve} H; Coates, Leighton; Herwig, Kenneth W; Kidder, Michelle

    2011-10-01

    This report summarizes the Workshop on Neutron Scattering Techniques for Studies in Catalysis, held at the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory (ORNL) on September 16 and 17, 2010. The goal of the Workshop was to bring experts in heterogeneous catalysis and biocatalysis together with neutron scattering experimenters to identify ways to attack new problems, especially Grand Challenge problems in catalysis, using neutron scattering. The Workshop locale was motivated by the neutron capabilities at ORNL, including the High Flux Isotope Reactor (HFIR) and the new and developing instrumentation at the SNS. Approximately 90 researchers met for 1 1/2 days with oral presentations and breakout sessions. Oral presentations were divided into five topical sessions aimed at a discussion of Grand Challenge problems in catalysis, dynamics studies, structure characterization, biocatalysis, and computational methods. Eleven internationally known invited experts spoke in these sessions. The Workshop was intended both to educate catalyst experts about the methods and possibilities of neutron methods and to educate the neutron community about the methods and scientific challenges in catalysis. Above all, it was intended to inspire new research ideas among the attendees. All attendees were asked to participate in one or more of three breakout sessions to share ideas and propose new experiments that could be performed using the ORNL neutron facilities. The Workshop was expected to lead to proposals for beam time at either the HFIR or the SNS; therefore, it was expected that each breakout session would identify a few experiments or proof-of-principle experiments and a leader who would pursue a proposal after the Workshop. Also, a refereed review article will be submitted to a prominent journal to present research and ideas illustrating the benefits and possibilities of neutron methods for catalysis research.

  5. Research on Estrogen and Behavior Is a 'Hot Topic' at the 2011 Society for Neuroscience Meeting

    ScienceCinema (OSTI)

    Anat Biegon

    2013-07-19

    The Society for Neuroscience has selected recent research on estrogen and its effect on behavior conducted at BNL for its "hot topics" book distributed to reporters attending the society's 2011 meeting in Washington, D.C., November 12-16.

  6. This research was supported as part of the Catalysis Center for Energy Innovatio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Direct Carbon Fuel Cell with a Molten Antimony Anode This research was conducted by the groups of Ray Gorte and John Vohs at the University of Pennsylvania and Doug Buttrey at the University of Delaware. In order to secure our energy future, researchers have been working to develop technology capable of efficiently producing energy from cheap and abundant solid carbonaceous fuel resources, like coal and renewable biomass. Much research has been devoted to developing direct carbon fuel cells

  7. This research was supported as part of the Catalysis Center for Energy Innovatio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This research was conducted by the group of Mark Davis at the California Institute of Technology. The core of catalytic chemistry research lies in understanding the role of a catalyst in a reaction. This understanding is crucial to the discovery of new materials leading to more energy efficient and benign chemical transformations. A critical reaction in utilization of the most abundant biomass ingredient, cellulose, is the conversion of glucose to fructose. Researchers at Caltech have now

  8. This research was supported as part of the Catalysis Center for Energy Innovatio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computational Methods Predict Thermochemistry and Kinetics of Biomass Derivatives on Transition Metals This research was conducted by the groups of Dion Vlachos, Jingguang Chen and Mark Barteau at the University of Delaware. First-principle simulation of biomass processing is hindered by the sheer size of biomass derivatives and the associated computational cost of quantum calculations. Researchers at the University of Delaware developed a new framework for estimating thermochemistry of

  9. This research was supported as part of the Catalysis Center for Energy Innovatio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Catalyst Converts Selectively Biomass-Derived Sugars to Chemicals This research was conducted by the group of Mark Davis at the California Institute of Technology. A novel catalyst was developed to efficiently convert biomass derived sugars. This development can have unprecedented impact on the production of renewable chemicals and fuels. Interest in carbohydrate chemistry has been revitalized by the recent push to produce chemicals from biomass. A reaction of particular importance and

  10. Dynamic nuclear polarization solid-state NMR in heterogeneous catalysis research

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kobayashi, Takeshi; Perras, Frédéric A.; Slowing, Igor I.; Sadow, Aaron D.; Pruski, Marek

    2015-10-20

    In this study, a revolution in solid-state nuclear magnetic resonance (SSNMR) spectroscopy is taking place, attributable to the rapid development of high-field dynamic nuclear polarization (DNP), a technique yielding sensitivity improvements of 2–3 orders of magnitude. This higher sensitivity in SSNMR has already impacted materials research, and the implications of new methods on catalytic sciences are expected to be profound.

  11. Low-rank coal research, Task 5.1. Topical report, April 1986--December 1992

    SciTech Connect (OSTI)

    Not Available

    1993-02-01

    This document is a topical progress report for Low-Rank Coal Research performed April 1986 - December 1992. Control Technology and Coal Preparation Research is described for Flue Gas Cleanup, Waste Management, Regional Energy Policy Program for the Northern Great Plains, and Hot-Gas Cleanup. Advanced Research and Technology Development was conducted on Turbine Combustion Phenomena, Combustion Inorganic Transformation (two sections), Liquefaction Reactivity of Low-Rank Coals, Gasification Ash and Slag Characterization, and Coal Science. Combustion Research is described for Atmospheric Fluidized-Bed Combustion, Beneficiation of Low-Rank Coals, Combustion Characterization of Low-Rank Fuels (completed 10/31/90), Diesel Utilization of Low-Rank Coals (completed 12/31/90), Produce and Characterize HWD (hot-water drying) Fuels for Heat Engine Applications (completed 10/31/90), Nitrous Oxide Emission, and Pressurized Fluidized-Bed Combustion. Liquefaction Research in Low-Rank Coal Direct Liquefaction is discussed. Gasification Research was conducted in Production of Hydrogen and By-Products from Coals and in Sulfur Forms in Coal.

  12. Catalysis by Design: Bridging the Gap between Theory and Experiments...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalysis by Design: Bridging the Gap between Theory and Experiments Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 ...

  13. 2012 Catalysis Lectures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalysis Lectures May 21-24 2012 Bert Weckhuysen Bert Weckhuysen, who holds the chair of Inorganic Chemistry and Catalysis at Utrecht University, will give a series of catalysis lectures during his sabbatical period at Stanford University and SLAC. (1) "Characterization of Heterogeneous Catalysts: Possibilities and Limitations of In-situ Spectroscopy" (Part I) Monday, May 21, 2012, 4.30-6 p.m. Location: SLAC Redwood Conference Room C&D (2) "Characterization of Heterogeneous

  14. Reaction Selectivity in Heterogeneous Catalysis

    SciTech Connect (OSTI)

    Somorjai, Gabor A.; Kliewer, Christopher J.

    2009-02-02

    The understanding of selectivity in heterogeneous catalysis is of paramount importance to our society today. In this review we outline the current state of the art in research on selectivity in heterogeneous catalysis. Current in-situ surface science techniques have revealed several important features of catalytic selectivity. Sum frequency generation vibrational spectroscopy has shown us the importance of understanding the reaction intermediates and mechanism of a heterogeneous reaction, and can readily yield information as to the effect of temperature, pressure, catalyst geometry, surface promoters, and catalyst composition on the reaction mechanism. DFT calculations are quickly approaching the ability to assist in the interpretation of observed surface spectra, thereby making surface spectroscopy an even more powerful tool. HP-STM has revealed three vitally important parameters in heterogeneous selectivity: adsorbate mobility, catalyst mobility, and selective site-blocking. The development of size controlled nanoparticles from 0.8 to 10 nm, of controlled shape, and of controlled bimetallic composition has revealed several important variables for catalytic selectivity. Lastly, DFT calculations may be paving the way to guiding the composition choice for multi-metallic heterogeneous catalysis for the intelligent design of catalysts incorporating the many factors of selectivity we have learned.

  15. Research needs in claus technology. Topical report, February 1993-May 1995

    SciTech Connect (OSTI)

    Abernathy, R.G.; Quinlan, M.P.

    1995-05-01

    A review is presented of the state-of-the-art of Claus technology and of research needs in this area. Since considerable quantities of natural gas are treated with this technology, it is very important to improve it. The study is based on literature searches and a survey of vendors, licensors, and research groups. Conclusions indicate that the design of reaction furnace and burner, and by development of selective direct oxidation catalysts for the final stage of the process. Replacing air with oxygen, minimizing the formation of carbonyl sulfide (COS) and carbon disulfide (CS2) while maximizing hydrogen (H2) production leaving the waste heat boiler will improve the efficiency of the Claus unit.

  16. Potential Collaborative Research topics with Koreas Agency for Defense Development

    SciTech Connect (OSTI)

    Farrar, Charles R.; Todd, Michael D.

    2012-08-23

    This presentation provides a high level summary of current research activities at the Los Alamos National Laboratory (LANL)-University of California Jacobs School of Engineering (UCSD) Engineering Institute that will be presented at Korea's Agency for Defense Development (ADD). These research activities are at the basic engineering science level with different level of maturity ranging from initial concepts to field proof-of-concept demonstrations. We believe that all of these activities are appropriate for collaborative research activities with ADD subject to approval by each institution. All the activities summarized herein have the common theme that they are multi-disciplinary in nature and typically involved the integration of high-fidelity predictive modeling, advanced sensing technologies and new development in information technology. These activities include: Wireless Sensor Systems, Swarming Robot sensor systems, Advanced signal processing (compressed sensing) and pattern recognition, Model Verification and Validation, Optimal/robust sensor system design, Haptic systems for large-scale data processing, Cyber-physical security for robots, Multi-source energy harvesting, Reliability-based approaches to damage prognosis, SHMTools software development, and Cyber-physical systems advanced study institute.

  17. Lead Research and Development Activity for DOE's High Temperature, Low Relative Humidity Membrane Program (Topic 2)

    SciTech Connect (OSTI)

    James Fenton, PhD; Darlene Slattery, PhD; Nahid Mohajeri, PhD

    2012-09-05

    The Department of Energy’s High Temperature, Low Relative Humidity Membrane Program was begun in 2006 with the Florida Solar Energy Center (FSEC) as the lead organization. During the first three years of the program, FSEC was tasked with developing non-Nafion® proton exchange membranes with improved conductivity for fuel cells. Additionally, FSEC was responsible for developing protocols for the measurement of in-plane conductivity, providing conductivity measurements for the other funded teams, developing a method for through-plane conductivity and organizing and holding semiannual meetings of the High Temperature Membrane Working Group (HTMWG). The FSEC membrane research focused on the development of supported poly[perfluorosulfonic acid] (PFSA) – Teflon membranes and a hydrocarbon membrane, sulfonated poly(ether ether ketone). The fourth generation of the PFSA membrane (designated FSEC-4) came close to, but did not meet, the Go/No-Go milestone of 0.1 S/cm at 50% relative humidity at 120 °C. In-plane conductivity of membranes provided by the funded teams was measured and reported to the teams and DOE. Late in the third year of the program, DOE used this data and other factors to decide upon the teams to continue in the program. The teams that continued provided promising membranes to FSEC for development of membrane electrode assemblies (MEAs) that could be tested in an operating fuel cell. FSEC worked closely with each team to provide customized support. A logic flow chart was developed and discussed before MEA fabrication or any testing began. Of the five teams supported, by the end of the project, membranes from two of the teams were easily manufactured into MEAs and successfully characterized for performance. One of these teams exceeded performance targets, while the other requires further optimization. An additional team developed a membrane that shows great promise for significantly reducing membrane costs and increasing membrane lifetime.

  18. Zeolite catalysis: technology

    SciTech Connect (OSTI)

    Heinemann, H.

    1980-07-01

    Zeolites have been used as catalysts in industry since the early nineteen sixties. The great majority of commercial applications employ one of three zeolite types: zeolite Y; Mordenite; ZSM-5. By far the largest use of zeolites is in catalytic cracking, and to a lesser extent in hydrocracking. This paper reviews the rapid development of zeolite catalysis and its application in industries such as: the production of gasoline by catalytic cracking of petroleum; isomerization of C/sub 5/ and C/sub 6/ paraffin hydrocarbons; alkylation of aromatics with olefins; xylene isomerization; and conversion of methanol to gasoline.

  19. Electron Microscopy Catalysis Projects: Success Stories from...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electron Microscopy Catalysis Projects: Success Stories from the High Temperature Materials Laboratory (HTML) User Program Electron Microscopy Catalysis Projects: Success Stories ...

  20. Catalysis and Synthesis | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalysis and Synthesis Catalysis and Synthesis Many different types of chemical reactions depend on catalysts in order to work, and the hunt for better catalysts has deep...

  1. Homogeneous and Interfacial Catalysis in 3D Controlled Environment | The

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ames Laboratory Homogeneous and Interfacial Catalysis in 3D Controlled Environment FWP/Project Description: Project Leader(s): Marek Pruski Principal Investigators: Marek Pruski, Aaron Sadow, Igor Slowing Key Scientific Personnel: Takeshi Kobayashi This collaborative research effort is geared toward bringing together the best features of homogeneous and heterogeneous catalysis for developing new catalytic principles. Novel silica-based, single-site mesoporous catalysts with controlled,

  2. Outer sphere hydrogenation catalysis (Journal Article) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Outer sphere hydrogenation catalysis Citation Details In-Document Search Title: Outer sphere hydrogenation catalysis Authors: Eisenstein, Odile ; Crabtree, Robert H Publication Date: 2013-01-01 OSTI Identifier: 1080563 DOE Contract Number: SC0001055 Resource Type: Journal Article Resource Relation: Journal Name: New J. Chem.; Journal Volume: 37; Related Information: CETM partners with General Electric Global Research (lead); Lawrence Berkeley National Laboratory; Stanford University; Yale

  3. EERE Success Story-Fundamental Studies in Catalysis Enabled the use of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficient "Lean-Burn" Engines for Vehicle Transportation | Department of Energy Fundamental Studies in Catalysis Enabled the use of Efficient "Lean-Burn" Engines for Vehicle Transportation EERE Success Story-Fundamental Studies in Catalysis Enabled the use of Efficient "Lean-Burn" Engines for Vehicle Transportation May 7, 2015 - 1:29pm Addthis Building on a catalysis research program sponsored by EERE's Vehicles Technology Office (VTO) and DOE's Office of

  4. 2013 DOE Catalysis Working Group Meeting Agenda | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Catalysis Working Group Meeting Agenda 2013 DOE Catalysis Working Group Meeting Agenda Agenda for the 2013 DOE Catalysis Working Group Meeting on May 15, 2013. PDF icon...

  5. Topic Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RAP Work Plan Topics Page 1 of 3 Topic Committee Potential FY 2016 Action/Product Context (from FY 2016 HAB Work Plan) 6-Month Status (IM, Committee, Advice, Deferred, No Action) 1. 100 Area retrieval process, K Basin RAP Project update (May not be ready until 2017 for an update; work ready in 2018 per milestone)  Attended tour in October 2015, including visit to MO-500/Sludge Annex facility 2. 100 D/H Proposed Plan RAP Project update Cleanup of soils and groundwater at D/H. Are the proposed

  6. Topic Committee

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TWC Work Plan Topics Page 1 of 2 Topic Committee Potential FY 2016 Action/Product Context (from FY 2016 HAB Work Plan) 6-Month Status (IM, Committee, Advice, Deferred, No Action) 11. AY-102 status update TWC Project update Provide updates on the planning, design, and installation of the equipment to begin pumping waste from double-shell tank AY-102 no later than March 4, 2016.  Received briefing on A/AX tank farms retrieval at committee in September 2015  Attended tour in October 2015,

  7. Enhanced Micellar Catalysis LDRD.

    SciTech Connect (OSTI)

    Betty, Rita G.; Tucker, Mark David; Taggart, Gretchen; Kinnan, Mark K.; Glen, Crystal Chanea; Rivera, Danielle; Sanchez, Andres; Alam, Todd Michael

    2012-12-01

    The primary goals of the Enhanced Micellar Catalysis project were to gain an understanding of the micellar environment of DF-200, or similar liquid CBW surfactant-based decontaminants, as well as characterize the aerosolized DF-200 droplet distribution and droplet chemistry under baseline ITW rotary atomization conditions. Micellar characterization of limited surfactant solutions was performed externally through the collection and measurement of Small Angle X-Ray Scattering (SAXS) images and Cryo-Transmission Electron Microscopy (cryo-TEM) images. Micellar characterization was performed externally at the University of Minnesota's Characterization Facility Center, and at the Argonne National Laboratory Advanced Photon Source facility. A micellar diffusion study was conducted internally at Sandia to measure diffusion constants of surfactants over a concentration range, to estimate the effective micelle diameter, to determine the impact of individual components to the micellar environment in solution, and the impact of combined components to surfactant phase behavior. Aerosolized DF-200 sprays were characterized for particle size and distribution and limited chemical composition. Evaporation rates of aerosolized DF-200 sprays were estimated under a set of baseline ITW nozzle test system parameters.

  8. Final technical report, Symposium on New Theoretical Concepts and Directions in Catalysis

    SciTech Connect (OSTI)

    Metiu, Horia

    2014-08-22

    We organized in August 2013 a “Symposium on New Theoretical Concepts and Directions in Catalysis” with the participation of 20 invited distinguished quantum chemists and other researchers who use computations to study catalysis. Symposium website; http://catalysis.cnsi.ucsb.edu/

  9. Fundamental Studies in Catalysis Enabled the use of Efficient Lean-Burn Engines for Vehicle Transportation

    Broader source: Energy.gov [DOE]

    Building on a catalysis research program sponsored by EEREs Vehicles Technology Office (VTO) and DOEs Office of Science, researchers at Cummins, Inc. and Pacific Northwest National Laboratory ...

  10. UNIRIB: Physics Topics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Topics Research Capitalizing on the strengths of nine collaborating research universities and the world-class equipment available at the Holifield Radioactive Ion Beam Facility (HRIBF) at Oak Ridge National Laboratory (ORNL), the University Radioactive Ion Beam (UNIRIB) consortium is conducting research at the forefront of nuclear physics. UNIRIB, a division of the Oak Ridge Institute for Science and Education (ORISE), brings together researchers from around the world to study the

  11. Integrated Mesoscale Architectures for Sustainable Catalysis...

    Office of Science (SC) Website

    Integrated Mesoscale Architectures for Sustainable Catalysis (IMASC) Energy Frontier ... science, molecular dynamics (MD), density functional theory (DFT), quantum ...

  12. Catalysis Working Group Meeting: June 2015

    Broader source: Energy.gov [DOE]

    Agenda and presentations from the Catalysis Working Group meeting held on June 8, 2015, in Arlington, Virginia.

  13. Physics Topics - MST - UW Plasma Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Topics UW Madison Madison Symmetric Torus Physics Topics MST HomeGraduate Student InformationLinksTourControl and Auxiliary SystemsPhysics TopicsDeviceResearch MissionMST ...

  14. Materials research at selected Japanese laboratories. Based on a 1992 visit: Overview, summary of highlights, notes on laboratories and topics

    SciTech Connect (OSTI)

    Not Available

    1994-02-01

    I visited Japan from June 29 to August 1, 1992. The purpose of this visit was to assess the status of materials science research at selected governmental, university and industrial laboratories and to established acquaintances with Japanese researchers. The areas of research covered by these visits included ceramics, oxide superconductors, intermetallics alloys, superhard materials and diamond films, high-temperature materials and properties, mechanical properties, fracture, creep, fatigue, defects, materials for nuclear reactor applications and irradiation effects, high pressure synthesis, self-propagating high temperature synthesis, microanalysis, magnetic properties and magnetic facilities, and surface science.

  15. Catalysis for Mixed Alcohol Synthesis from Biomass Derived Syngas: Cooperative Research and Development Final Report, CRADA Number CRD-08-292

    SciTech Connect (OSTI)

    Hensley, J.

    2013-04-01

    The Dow Chemical Company (Dow) developed and tested catalysts for production of mixed alcohols from synthesis gas (syngas), under research and development (R&D) projects that were discontinued a number of years ago. Dow possesses detailed laboratory notebooks, catalyst samples, and technical expertise related to this past work. The National Renewable Energy Laboratory (NREL) is conducting R&D in support of the United States Department of Energy (DOE) to develop methods for economically producing ethanol from gasified biomass. NREL is currently conducting biomass gasification research at an existing 1/2 ton/day thermochemical test platform. Both Dow and NREL believe that the ability to economically produce ethanol from biomass-derived syngas can be enhanced through collaborative testing, refinement, and development of Dow's mixed-alcohol catalysts at NREL's and/or Dow's bench- and pilot-scale facilities. Dow and NREL further agree that collaboration on improvements in catalysts as well as gasifier operating conditions (e.g., time, temperature, upstream gas treatment) will be necessary to achieve technical and economic goals for production of ethanol and other alcohols.

  16. Catalysis Center for Energy Innovation (CCEI) | U.S. DOE Office of Science

    Office of Science (SC) Website

    (SC) Catalysis Center for Energy Innovation (CCEI) Energy Frontier Research Centers (EFRCs) EFRCs Home Centers EFRC External Websites Research Science Highlights News & Events Publications History Contact BES Home Centers Catalysis Center for Energy Innovation (CCEI) Print Text Size: A A A FeedbackShare Page CCEI Header Director Dionisios Vlachos Lead Institution University of Delaware Year Established 2009 Mission To focus on developing innovative, transformational heterogeneous

  17. Workshop: Synchrotron Applications in Chemical Catalysis | Stanford...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Applications in Chemical Catalysis Tuesday, October 25, 2011 - 8:00am 2011 SSRLLCLS Annual Users Conference This workshop, part of the 2011 SSRLLCLS Annual Users...

  18. Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to Make Fuels and Chemicals BETO works with the emerging U.S. bioindustry to sustainably convert non-food ...

  19. Basic Research Needs: Catalysis for Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with heretofore unprecedented detail. Examples of new computational methods include optimization of structures determined experimentally by diffraction scattering based on...

  20. Featured Topic Pages

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Featured Topic Pages * Renowned scientists, with information about the scientists' R&D results * Significant DOE research disciplines, with R&D results * Manhattan Project, including scientists and key events Laureates * Nobel Prize winners associated with DOE and predecessor agencies * Winners of the Enrico Fermi Award, a U.S. Presidential award Database * Selected documents about noteworthy R&D results * Documents and individual pages searchable by word or phrase * Tag cloud

  1. The energy landscape of ;#8203;adenylate kinase during catalysis...

    Office of Scientific and Technical Information (OSTI)

    The energy landscape of ;8203;adenylate kinase during catalysis Citation Details In-Document Search Title: The energy landscape of ;8203;adenylate kinase during catalysis ...

  2. Materials Design and Discovery: Catalysis and Energy Storage...

    Office of Scientific and Technical Information (OSTI)

    Materials Design and Discovery: Catalysis and Energy Storage (Mira Early Science Program ... Citation Details In-Document Search Title: Materials Design and Discovery: Catalysis and ...

  3. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO Oxidation Catalysis in Support ...

  4. Transmural Catalysis - High Efficiency Catalyst Systems for NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Transmural Catalysis - High Efficiency Catalyst Systems for NOx Adsorbers and SCR Presentation ...

  5. Improving Catalysis by Putting the Best Face Forward | U.S. DOE Office of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science (SC) Improving Catalysis by Putting the Best Face Forward Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences Advisory Committee (BESAC) Community Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3081 F: (301) 903-6594 E: Email Us More Information » 04.01.12 Improving Catalysis by

  6. Priority Research Topics, Runtime (Granetz)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    data points ( 40.96 microseconds). 3D-Printed 625 Inconel 3D-Printed Camera Mounts * 3D-Printing can be used to very rapidly produce mounts, flanges, and other small components...

  7. Research Topics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... S-503 Solar Systems Integration Possible Disciplines: Power Systems Engineering, Electrical Engineering, ... The development of Pickering emulsions to increase the stability and ...

  8. Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2

    SciTech Connect (OSTI)

    Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B.; Dobbek, Holger; DuBois, Daniel L.; Dupuis, Michel; Ferry, James G.; Fujita, Etsuko; Hille, Russ; Kenis, Paul; Kerfeld, Cheryl A.; Morris, Robert H.; Peden, Charles HF; Portis, Archie; Ragsdale, Steve; Rauchfuss, Thomas B.; Reek, Joost; Seefeldt, Lance C.; Thauer, Rudolf K.; Waldrop, Grover L.

    2013-08-14

    Our central premise is that catalytic scientists can learn by studying how these important metabolic processes occur in nature. Complementarily, biochemists can learn by studying how catalytic scientists view these same chemical transformations promoted by synthetic catalysts. From these studies, hypotheses can be developed and tested through manipulation of enzyme structure and by synthesizing simple molecular catalysts to incorporate different structural features of the enzymes. It is hoped that these studies will lead to new and useful concepts in catalyst design for fuel production and utilization. This paper describes the results of a workshop held to explore these concepts in regard to the development of new and more efficient catalytic processes for the conversion of CO2 to a variety of carbon-based fuels. The organization of this overview/review is as follows: 1) The first section briefly explores how interactions between the catalysis and biological communities have been fruitful in developing new catalysts for the reduction of protons to hydrogen, the simplest fuel generation reaction. 2) The second section assesses the state of the art in both biological and chemical reduction of CO2 by two electrons to form either carbon monoxide (CO) or formate (HCOO-). It also attempts to identify common principles between biological and synthetic catalysts and productive areas for future research. 3) The third section explores both biological and chemical processes that result in the reduction of CO2 beyond the level of CO and formate, again seeking to identify common principles and productive areas of future research. 4) The fourth section explores the formation of carbon-carbon bonds in biological and chemical systems in the same vein as the other sections. 5) A fifth section addresses the role of non-redox reactions of CO2 in biological systems and their role in carbon metabolism, with a parallel discussion of chemical systems. 6) In section 6, the topics of electrode modification, photochemical systems, and tandem catalysis are briefly discussed. These areas may be important for developing practical systems for CO2 reduction, and they share the common theme of coupling chemical reactions. 7) Section 7 describes some of the crosscutting activities that are critical for advancing the science underpinning catalyst development. 8) The last section attempts to summarize common issues in biological and chemical catalysis and to identify challenges that must be addressed to achieve practical catalysts that are suitable for the reduction of CO2 to fuels.

  9. "Nanocrystal bilayer for tandem catalysis"

    SciTech Connect (OSTI)

    Yamada, Yusuke; Tsung, Chia Kuang; Huang, Wenyu; Huo, Ziyang; E.Habas, Susan E; Soejima, Tetsuro; Aliaga, Cesar E; Samorjai, Gabor A; Yang, Peidong

    2011-01-24

    Supported catalysts are widely used in industry and can be optimized by tuning the composition and interface of the metal nanoparticles and oxide supports. Rational design of metal-metal oxide interfaces in nanostructured catalysts is critical to achieve better reaction activities and selectivities. We introduce here a new class of nanocrystal tandem catalysts that have multiple metal-metal oxide interfaces for the catalysis of sequential reactions. We utilized a nanocrystal bilayer structure formed by assembling platinum and cerium oxide nanocube monolayers of less than 10 nm on a silica substrate. The two distinct metal-metal oxide interfaces, CeO2-Pt and Pt-SiO2, can be used to catalyse two distinct sequential reactions. The CeO2-Pt interface catalysed methanol decomposition to produce CO and H2, which were subsequently used for ethylene hydroformylation catalysed by the nearby Pt-SiO2 interface. Consequently, propanal was produced selectively from methanol and ethylene on the nanocrystal bilayer tandem catalyst. This new concept of nanocrystal tandem catalysis represents a powerful approach towards designing high-performance, multifunctional nanostructured catalysts

  10. Iron Catalysis in Oxidations by Ozone - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Iron Catalysis in Oxidations by Ozone Ames Laboratory Contact AMES About This Technology Technology Marketing Summary Ozone is used commercially for treatment of potable and non-potable water, and as an industrial oxidant. ISU and Ames Laboratory researchers have developed a method for using iron in ozone oxidation that significantly improves the speed of oxidation reactions. Description Ozone is recognized as potent and effective oxidizing agent, and has a

  11. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  12. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  13. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  14. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  15. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  16. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab researchers used x-rays at the ALS in a novel way to observe the behavior of

  17. Molecular-Level Design of Heterogeneous Chiral Catalysis

    SciTech Connect (OSTI)

    Francisco Zaera

    2012-03-21

    The following is a proposal to continue our multi-institutional research on heterogeneous chiral catalysis. Our team combines the use of surface-sensitive analytical techniques for the characterization of model systems with quantum and statistical mechanical calculations to interpret experimental data and guide the design of future research. Our investigation focuses on the interrelation among the three main mechanisms by which enantioselectivity can be bestowed to heterogeneous catalysts, namely: (1) by templating chirality via the adsorption of chiral supramolecular assemblies, (2) by using chiral modifiers capable of forming chiral complexes with the reactant and force enantioselective surface reactions, and (3) by forming naturally chiral surfaces using imprinting chiral agents. Individually, the members of our team are leaders in these various aspects of chiral catalysis, but the present program provides the vehicle to generate and exploit the synergies necessary to address the problem in a comprehensive manner. Our initial work has advanced the methodology needed for these studies, including an enantioselective titration procedure to identify surface chiral sites, infrared spectroscopy in situ at the interface between gases or liquids and solids to mimic realistic catalytic conditions, and DFT and Monte Carlo algorithms to simulate and understand chirality on surfaces. The next step, to be funded by the monies requested in this proposal, is to apply those methods to specific problems in chiral catalysis, including the identification of the requirements for the formation of supramolecular surface structures with enantioselective behavior, the search for better molecules to probe the chiral nature of the modified surfaces, the exploration of the transition from supramolecular to one-to-one chiral modification, the correlation of the adsorption characteristics of one-to-one chiral modifiers with their physical properties, in particular with their configuration, and the development of ways to imprint chiral centers on achiral solid surfaces. Chiral catalysis is not only a problem of great importance in its own right, but also the ultimate test of how to control selectivity in catalysis. The time is ripe for fundamental work in heterogeneous chiral catalysis to provide the U.S. with a leadership role in developing the next generation of catalytic processes for medicinal and agrochemical manufacturing. Our team provides the required expertise for a synergistic and comprehensive integration of physical and chemical experimentation with solid state and molecular reactivity theories to solve this problem.

  18. Nanocrystal assembly for tandem catalysis

    DOE Patents [OSTI]

    Yang, Peidong; Somorjai, Gabor; Yamada, Yusuke; Tsung, Chia-Kuang; Huang, Wenyu

    2014-10-14

    The present invention provides a nanocrystal tandem catalyst comprising at least two metal-metal oxide interfaces for the catalysis of sequential reactions. One embodiment utilizes a nanocrystal bilayer structure formed by assembling sub-10 nm platinum and cerium oxide nanocube monolayers on a silica substrate. The two distinct metal-metal oxide interfaces, CeO.sub.2--Pt and Pt--SiO.sub.2, can be used to catalyze two distinct sequential reactions. The CeO.sub.2--Pt interface catalyzed methanol decomposition to produce CO and H.sub.2, which were then subsequently used for ethylene hydroformylation catalyzed by the nearby Pt--SiO.sub.2 interface. Consequently, propanal was selectively produced on this nanocrystal bilayer tandem catalyst.

  19. Catalysis Working Group Meeting: June 2014

    Broader source: Energy.gov [DOE]

    Agenda and presentations from the Catalysis Working Group held on June 16, 2014, in Washington, D.C., in conjunction with the DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting.

  20. Catalysis Working Group Meeting: May 2013

    Broader source: Energy.gov [DOE]

    Information from the Catalysis Working Group meeting held on May 15, 2013, in Arlington, Virginia, in conjunction with the DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting.

  1. Workshop: Synchrotron Applications in Chemical Catalysis | Stanford

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synchrotron Radiation Lightsource Synchrotron Applications in Chemical Catalysis Tuesday, October 25, 2011 - 8:00am 2011 SSRL/LCLS Annual Users Conference This workshop, part of the 2011 SSRL/LCLS Annual Users Conference, will focus on understanding processes in homogeneous (both biological and small molecule) and heterogeneous catalysis, using synchrotron-based methods. The workshop will cover more traditional applications (using XANES and EXAFS), as well as applications of XES, RIXS and

  2. USD Catalysis Group for Alternative Energy - Final report

    SciTech Connect (OSTI)

    Hoefelmeyer, James

    2014-10-03

    I. Project Summary Catalytic processes are a major technological underpinning of modern society, and are essential to the energy sector in the processing of chemical fuels from natural resources, fine chemicals synthesis, and energy conversion. Advances in catalyst technology are enormously valuable since these lead to reduced chemical waste, reduced energy loss, and reduced costs. New energy technologies, which are critical to future economic growth, are also heavily reliant on catalysts, including fuel cells and photo-electrochemical cells. Currently, the state of South Dakota is underdeveloped in terms of research infrastructure related to catalysis. If South Dakota intends to participate in significant economic growth opportunities that result from advances in catalyst technology, then this area of research needs to be made a high priority for investment. To this end, a focused research effort is proposed in which investigators from The University of South Dakota (USD) and The South Dakota School of Mines and Technology (SDSMT) will contribute to form the South Dakota Catalysis Group (SDCG). The multidisciplinary team of the (SDCG) include: (USD) Dan Engebretson, James Hoefelmeyer, Ranjit Koodali, and Grigoriy Sereda; (SDSMT) Phil Scott Ahrenkiel, Hao Fong, Jan Puszynski, Rajesh Shende, and Jacek Swiatkiewicz. The group is well suited to engage in a collaborative project due to the resources available within the existing programs. Activities within the SDCG will be monitored through an external committee consisting of three distinguished professors in chemistry. The committee will provide expert advice and recommendations to the SDCG. Advisory meetings in which committee members interact with South Dakota investigators will be accompanied by individual oral and poster presentations in a materials and catalysis symposium. The symposium will attract prominent scientists, and will enhance the visibility of research in the state of South Dakota. The SDCG requests funding through the Department of Energy (DoE) to establish this multidisciplinary research cluster in the area of catalysis. This long-term approach includes synthesis, characterization, catalyst evaluation, modeling, and scale-up. The project includes plans to acquire instrumentation critical to enabling competitive research. These acquisitions will complement existing resources in the state. The effect of implementation of the proposed efforts will be to significantly enhance state infrastructure in personnel and equipment, and lead to a nationally and internationally recognized research center.

  3. Physics Topics - Plasma Couette Experiment - Cary Forest Group...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Topics UW Madison Plasma Couette Experiment Physics Topics PCX HomeResearch MissionPhysics TopicsDeviceDiagnosticsContacts LinksPCX People CPLA Home Directory Publications ...

  4. Physics Topics - Rotating Wall Machine - UW Plasma Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Topics UW Madison Line Tied Reconnection Experiment Physics Topics LTRX HomeResearch MissionLTRX DevicePhysics TopicsDiagnosticsLTRX GalleryLTRX People CPLA Home Directory ...

  5. TEC Communications Topic Group

    Office of Environmental Management (EM)

    procurement - Routing criteriaemergency preparedness Tribal Issues Topic Group * TEPP Navajo Nation (Tom Clawson) - 1404 - Needs Assessment * Identified strengths and...

  6. 2014 CHEMICAL REACTIONS AT SURFACES GORDON RESEARCH CONFERENCE AND GORDON RESEARCH SEMINAR (APRIL 28-MAY 3, 2013 - LES DIABLERETS CONFERENCE CENTER, LES DIABLERETS, SWITZERLAND)

    SciTech Connect (OSTI)

    Stair, Peter C.

    2013-02-03

    presentations on chemistry at solid and liquid surfaces of relevance to catalysis, synthesis, photochemistry, environmental science, and tribology. Topics include: Fundamental Surface Chemistry; Catalysis; Solid Liquid and Aerosol Interfaces; Surface Photochemistry; Synthesis of Surfaces; Environmental Interfaces; Hot Topics in Surface Chemical Reactions; Tribology; Gas-Surface Scattering and Reactions; Novel Materials and Environments.

  7. Shining Light on Catalysis | Stanford Synchrotron Radiation Lightsourc...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shining Light on Catalysis Tuesday, July 19, 2011 - 4:38pm SSRL Conference Room 137-322 Jeroen A. van Bokhoven, Professor for Heterogeneous Catalysis Institute for Chemical and...

  8. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis ALS X-Rays Shine a New Light on Catalysis Print Thursday, 21 May 2015 11:16 Electrocatalysts are responsible for expediting reactions in...

  9. Fuel Synthesis Catalysis Laboratory: Catalytic Testing for Thermochemical Transformations of Molecules (Fact Sheet), NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthesis Catalysis Laboratory Catalytic testing for thermochemical transformations of molecules NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. NREL's Fuel Synthesis Catalysis Laboratory (FSCL) provides a wide range of capabilities in heterogeneous catalyst testing. Current research areas of emphasis include the transformation of biomass pyrolysis and gasification products to

  10. Catalysis Science | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Catalysis Science Chemical Sciences, Geosciences, & Biosciences (CSGB) Division CSGB Home ... principles enabling rational catalyst design and chemical transformation control. ...

  11. Geek-Up[3.11.2011]: Energy Efficiency, Catalysis and Open Source Tools |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 11.2011]: Energy Efficiency, Catalysis and Open Source Tools Geek-Up[3.11.2011]: Energy Efficiency, Catalysis and Open Source Tools March 11, 2011 - 4:37pm Addthis L. Keith Woo | Photo courtesy of Ames National Laboratory L. Keith Woo | Photo courtesy of Ames National Laboratory Niketa Kumar Niketa Kumar Public Affairs Specialist, Office of Public Affairs Ames Laboratory researcher and Iowa State University professor L. Keith Woo is on the search for catalysts that lead

  12. Center for Catalysis at Iowa State University

    SciTech Connect (OSTI)

    Kraus, George A.

    2006-10-17

    The overall objective of this proposal is to enable Iowa State University to establish a Center that enjoys world-class stature and eventually enhances the economy through the transfer of innovation from the laboratory to the marketplace. The funds have been used to support experimental proposals from interdisciplinary research teams in areas related to catalysis and green chemistry. Specific focus areas included: Catalytic conversion of renewable natural resources to industrial materials Development of new catalysts for the oxidation or reduction of commodity chemicals Use of enzymes and microorganisms in biocatalysis Development of new, environmentally friendly reactions of industrial importance These focus areas intersect with barriers from the MYTP draft document. Specifically, section 2.4.3.1 Processing and Conversion has a list of bulleted items under Improved Chemical Conversions that includes new hydrogenation catalysts, milder oxidation catalysts, new catalysts for dehydration and selective bond cleavage catalysts. Specifically, the four sections are: 1. Catalyst development (7.4.12.A) 2. Conversion of glycerol (7.4.12.B) 3. Conversion of biodiesel (7.4.12.C) 4. Glucose from starch (7.4.12.D) All funded projects are part of a soybean or corn biorefinery. Two funded projects that have made significant progress toward goals of the MYTP draft document are: Catalysts to convert feedstocks with high fatty acid content to biodiesel (Kraus, Lin, Verkade) and Conversion of Glycerol into 1,3-Propanediol (Lin, Kraus). Currently, biodiesel is prepared using homogeneous base catalysis. However, as producers look for feedstocks other than soybean oil, such as waste restaurant oils and rendered animal fats, they have observed a large amount of free fatty acids contained in the feedstocks. Free fatty acids cannot be converted into biodiesel using homogeneous base-mediated processes. The CCAT catalyst system offers an integrated and cooperative catalytic system that performs both esterification (of free fatty acids) and transesterification (of soybean oil) in a one-pot fashion. This will allow the biodiesel producers to use the aforementioned cheap feedstocks without any pretreatment. In addition, the catalyst system is heterogeneous and is highly recyclable and reusable. Although markets currently exist for glycerin, concern is mounting that the price of glycerin may plummet to $.05 - $.10 per pound if future production exceeds demand. Developing a system to make high value chemicals such as 1,3-propanediol from the glycerin stream will add value for biodiesel producers who implement the new technology. Given the fact that both DuPont and Shell chemicals have announced the commercialization of two new PDO-based polymers, a rapid increase of market demand for a cheaper PDO source is very likely. 4. Comparison of actual accomplishments with goals and objectives From our progress reports, the four areas are: 1. Catalyst development (7.4.12.A) 2. Conversion of glycerol (7.4.12.B) 3. Conversion of biodiesel (7.4.12.C) 4. Glucose from starch (7.4.12.D)

  13. SBIR and STTR: Topics, FY 2015 Phase I Release 2

    Broader source: Energy.gov [DOE]

    Small Business Innovation Research (SBIR) and Small Business Technology Transfer (STTR) Programs: Topics, FY 2015, Phase I, Release 2.

  14. Heterogeneous Catalysis for Thermochemical Conversion | Bioenergy | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heterogeneous Catalysis for Thermochemical Conversion Our mission is to transform thermal biomass deconstruction products (syngas and pyrolysis oil) into the fuels and chemicals that keep society moving forward. Figure includes three panels. The first pane, labeled single-source precursors, depicts a bis(triphenylphosphine)rhodium(I) carbonyl chloride single-source precursor for producing rhodium phosphide nanoparticles, shown by a vertical line labeled PPh3 at the top, Rh in the middle, and

  15. USD Catalysis Group for Alternative Energy

    SciTech Connect (OSTI)

    Hoefelmeyer, James D.; Koodali, Ranjit; Sereda, Grigoriy; Engebretson, Dan; Fong, Hao; Puszynski, Jan; Shende, Rajesh; Ahrenkiel, Phil

    2012-03-13

    The South Dakota Catalysis Group (SDCG) is a collaborative project with mission to develop advanced catalysts for energy conversion with two primary goals: (1) develop photocatalytic systems in which polyfunctionalized TiO2 are the basis for hydrogen/oxygen synthesis from water and sunlight (solar fuels group), (2) develop new materials for hydrogen utilization in fuel cells (fuel cell group). In tandem, these technologies complete a closed chemical cycle with zero emissions.

  16. Nanoscale Advances in Catalysis and Energy Applications

    SciTech Connect (OSTI)

    Li, Yimin; Somorjai, Gabor A.

    2010-05-12

    In this perspective, we present an overview of nanoscience applications in catalysis, energy conversion, and energy conservation technologies. We discuss how novel physical and chemical properties of nanomaterials can be applied and engineered to meet the advanced material requirements in the new generation of chemical and energy conversion devices. We highlight some of the latest advances in these nanotechnologies and provide an outlook at the major challenges for further developments.

  17. ARM - Topic List

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TeachersTopic List Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Topic List Atmosphere Atmospheric Heat Budget Atmospheric Pressure Composition of the Atmosphere Evolution of the Atmosphere Mesosphere Stratosphere Thermosphere Troposphere Oceans Oceans Sea Surface and Sea Level Weather and

  18. Research | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Division of Chemical and Biological Sciences - This Division develops and applies theoretical, computational and experimental methods to the study of surface reaction phenomena, cluster science and nucleation, biological processes and catalysis. World-leading research is conducted at the interface between homogenous and heterogenous catalysis. This research has led to improved processes for biodiesel production. New characterization techniques and theoretical methods to enable improved

  19. Proceedings of the Twenty-First Water Reactor Safety Information Meeting: Volume 1, Plenary session; Advanced reactor research; advanced control system technology; advanced instrumentation and control hardware; human factors research; probabilistic risk assessment topics; thermal hydraulics; thermal hydraulic research for advanced passive LWRs

    SciTech Connect (OSTI)

    Monteleone, S.

    1994-04-01

    This three-volume report contains 90 papers out of the 102 that were presented at the Twenty-First Water Reactor Safety Information Meeting held at the Bethesda Marriott Hotel, Bethesda, Maryland, during the week of October 25--27, 1993. The papers are printed in the order of their presentation in each session and describe progress and results of programs in nuclear safety research conducted in this country and abroad. Foreign participation in the meeting included papers presented by researchers from France, Germany, Japan, Russia, Switzerland, Taiwan, and United Kingdom. The titles of the papers and the names of the authors have been updated and may differ from those that appeared in the final program of the meeting. Individual papers have been cataloged separately. This document, Volume 1 covers the following topics: Advanced Reactor Research; Advanced Instrumentation and Control Hardware; Advanced Control System Technology; Human Factors Research; Probabilistic Risk Assessment Topics; Thermal Hydraulics; and Thermal Hydraulic Research for Advanced Passive Light Water Reactors.

  20. Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bioproducts | Department of Energy Conversion: Using Heat and Catalysis to Make Biofuels and Bioproducts Thermochemical Conversion: Using Heat and Catalysis to Make Biofuels and Bioproducts The Bioenergy Technologies Office works with industry to develop pathways that use heat, pressure, and catalysis to convert domestic, non-food biomass into gasoline, jet fuel, and other products. PDF icon thermochemical_four_pager.pdf More Documents & Publications 2013 Peer Review

  1. Catalysis Working Group Meeting: January 2015 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    January 2015 Catalysis Working Group Meeting: January 2015 The Catalysis Working Group held a meeting on January 21, 2015, in Los Alamos, New Mexico. Meeting Agenda and Presentations PDF icon Catalysis Working Group January 2015 Meeting Agenda PDF icon Electrocatalysts with Ultra-Low PGM Loadings-Vojislav Stamenkovic, Argonne National Laboratory PDF icon Improving Stability and Activity of Pt Monolayer in Non-Pt Core-Shell Electrocatalysts-Radoslav Adzic, Brookhaven National Laboratory PDF icon

  2. Shining Light on Catalysis | Stanford Synchrotron Radiation Lightsource

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shining Light on Catalysis Tuesday, July 19, 2011 - 4:38pm SSRL Conference Room 137-322 Jeroen A. van Bokhoven, Professor for Heterogeneous Catalysis Institute for Chemical and Bioengineering ETH Zurich Head of Laboratory for Catalysis and Sustainable Chemistry (LSK) Swiss Light Source Paul Scherrer Institute Understanding a functioning catalyst requires understanding at the atomic scales in a time-resolved manner. X-rays can be readily used to accomplish that task, because of the large

  3. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis Print Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme...

  4. Materials Design and Discovery: Catalysis and Energy Storage...

    Office of Scientific and Technical Information (OSTI)

    Materials Design and Discovery: Catalysis and Energy Storage (Mira Early Science Program Final Technical Report): ALCF-2 Early Science Program Technical Report Citation Details ...

  5. Control Heterogeneous Catalysis at Atomic and Electronic-level...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Control Heterogeneous Catalysis at Atomic and Electronic-level Using Intermetallic Compounds Precious metals and metal alloys are important heterogeneous catalysts for renewable...

  6. Catalysis by Design - Theoretical and Experimental Studies of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design - Theoretical and Experimental Studies of Model Catalysts for Lean NOx Treatment Catalysis by Design - Theoretical and Experimental Studies of Model Catalysts for Lean NOx ...

  7. Catalysis | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Catalysis Basic Energy Sciences Advisory Committee (BESAC) BESAC Home Meetings Meeting Presentations History Logistics BESAC 2016-2017 Membership ChargesReports Charter .pdf file ...

  8. A research needs assessment for the capture, utilization and disposal of carbon dioxide from fossil fuel-fired power plants. Volume 2, Topical reports: Final report

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    This study, identifies and assesses system approaches in order to prioritize research needs for the capture and non-atmospheric sequestering of a significant portion of the carbon dioxide (CO{sub 2}) emitted from fossil fuel-fired electric power plants (US power plants presently produce about 7% of the world`s CO{sub 2} emissions). The study considers capture technologies applicable either to existing plants or to those that optimistically might be demonstrated on a commercial scale over the next twenty years. The research needs that have high priority in establishing the technical, environmental, and economic feasibility of large-scale capture and disposal of CO{sub 2} from electric power plants are:(1) survey and assess the capacity, cost, and location of potential depleted gas and oil wells that are suitable CO{sub 2} repositories (with the cooperation of the oil and gas industry); (2) conduct research on the feasibility of ocean disposal, with objectives of determining the cost, residence time, and environmental effects for different methods of CO{sub 2} injection; (3) perform an in-depth survey of knowledge concerning the feasibility of using deep, confined aquifers for disposal and, if feasible, identify potential disposal locations (with the cooperation of the oil and gas industry); (4) evaluate, on a common basis, system and design alternatives for integration of CO{sub 2} capture systems with emerging and advanced technologies for power generation; and prepare a conceptual design, an analysis of barrier issues, and a preliminary cost estimate for pipeline networks necessary to transport a significant portion of the CO{sub 2} to potentially feasible disposal locations.

  9. Topical Committee | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Topical Committee Topical Committee In the interest of optimum technology transfer, the DOE Technical Standards Program (TSP) has set up a network of topical committees. These committees provide a forum for communication across the DOE complex on technical standards related activities. If you would like information about a specific topical committee, or wish to join one of the groups, we've provided a roster of TSP Topical Committees and corresponding Topical Committee Chairpersons. Expectations

  10. Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control PDF icon ...

  11. Wilsonville Advanced Coal Liquefaction Research and Development Facility, Wilsonville, Alabama. Topical report No. 14. Catalyst activity trends in two-stage coal liquefaction

    SciTech Connect (OSTI)

    Not Available

    1984-02-01

    The Two Stage Coal Liquefaction process became operational at Wilsonville in May 1981, with the inclusion of an H-OIL ebullated-bed catalytic reactor. The two stage process was initially operated in a nonintegrated mode and has recently been reconfigurated to fully integrate the thermal and the catalytic stages. This report focuses on catalyst activity trends observed in both modes of operation. A literature review of relevant catalyst screening studies in bench-scale and PDU units is presented. Existing kinetic and deactivation models were used to analyze process data over an extensive data base. Based on the analysis, three separate, application studies have been conducted. The first study seeks to elucidate the dependence of catalyst deactivation rate on type of coal feedstock used. A second study focuses on the significance of catalyst type and integration mode on SRC hydrotreatment. The third study presents characteristic deactivation trends observed in integrated operation with different first-stage thermal severities. In-depth analytical work was conducted at different research laboratories on aged catalyst samples from Run 242. Model hydrogenation and denitrogenation activity trends are compared with process activity trends and with changes observed in catalyst porosimetric properties. The accumulation of metals and coke deposits with increasing catalyst age, as well as their distribution across a pellet cross-section, are discussed. The effect of catalyst age and reactor temperature on the chemical composition of flashed bottoms product is addressed. Results from regenerating spent catalysts are also presented. 35 references, 31 figures, 18 tables.

  12. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support of HCCI

    Broader source: Energy.gov (indexed) [DOE]

    Emission Control | Department of Energy Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_rappe.pdf More Documents & Publications Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support of HCCI Emission Control Selectlive Catalytic Reducution of NOx wilth Diesel-Based

  13. SIMPLIFIED PREDICTIVE MODELS FOR CO2 SEQUESTRATION PERFORMANCE ASSESSMENT RESEARCH TOPICAL REPORT ON TASK #4 REDUCED-ORDER METHOD (ROM) BASED MODELS

    SciTech Connect (OSTI)

    Mishra, Srikanta; Jin, Larry; He, Jincong; Durlofsky, Louis

    2015-06-30

    Reduced-order models provide a means for greatly accelerating the detailed simulations that will be required to manage CO2 storage operations. In this work, we investigate the use of one such method, POD-TPWL, which has previously been shown to be effective in oil reservoir simulation problems. This method combines trajectory piecewise linearization (TPWL), in which the solution to a new (test) problem is represented through a linearization around the solution to a previously-simulated (training) problem, with proper orthogonal decomposition (POD), which enables solution states to be expressed in terms of a relatively small number of parameters. We describe the application of POD-TPWL for CO2-water systems simulated using a compositional procedure. Stanford’s Automatic Differentiation-based General Purpose Research Simulator (AD-GPRS) performs the full-order training simulations and provides the output (derivative matrices and system states) required by the POD-TPWL method. A new POD-TPWL capability introduced in this work is the use of horizontal injection wells that operate under rate (rather than bottom-hole pressure) control. Simulation results are presented for CO2 injection into a synthetic aquifer and into a simplified model of the Mount Simon formation. Test cases involve the use of time-varying well controls that differ from those used in training runs. Results of reasonable accuracy are consistently achieved for relevant well quantities. Runtime speedups of around a factor of 370 relative to full- order AD-GPRS simulations are achieved, though the preprocessing needed for POD-TPWL model construction corresponds to the computational requirements for about 2.3 full-order simulation runs. A preliminary treatment for POD-TPWL modeling in which test cases differ from training runs in terms of geological parameters (rather than well controls) is also presented. Results in this case involve only small differences between training and test runs, though they do demonstrate that the approach is able to capture basic solution trends. The impact of some of the detailed numerical treatments within the POD-TPWL formulation is considered in an Appendix. ii

  14. Manufacturing Innovation Topics Workshop

    Broader source: Energy.gov [DOE]

    The Advanced Manufacturing Office (AMO) and the Office of the Secretary of Defense Manufacturing Technology Program (OSD ManTech) will host a workshop to discuss AMO's recent Request for Information (RFI) on Clean Energy Manufacturing Topic Areas as well as the recent areas of interest announced by OSD ManTech for a new Manufacturing Innovation Institute on October 8-9, 2014 in Fort Worth, TX.

  15. SBIR and STTR: Topics, FY 2015 Phase I Release 2 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SBIR and STTR: Topics, FY 2015 Phase I Release 2 Small Business Innovation Research (SBIR) and Small Business Technology Transfer (STTR) Programs: Topics, FY 2015, Phase I, Release ...

  16. Kokes Awards for the 22nd North American Catalysis Society Meeting, June 5-10, 2011

    SciTech Connect (OSTI)

    Fabio H. Ribeiro

    2011-06-05

    The biennial North American Catalysis Society (NACS) Meetings are the premiere conferences in the area of catalysis, surface science, and reaction engineering. The 22nd meeting will be held the week of June 5-10, 2011 in Detroit, Michigan. The objective of the Meetings is to bring together leading researchers for intensive scientific exchange and interactions. Financial support that offsets some of the associated costs (specifically, registration fee, airline tickets, and hotel accommodations) would encourage graduate students, and for the first time undergraduate students, to attend and participate meaningfully in this conference. The funds sought in this proposal will help support the Richard J. Kokes Travel Award program. Graduate students eligible for these merit-based Awards are those who study at a North American university and who will present at the Meeting. We have currently 209 applications and we expect to be able to fund about half of them. The NACS has traditionally sought to encourage graduate student, and this year for the first time undergraduate studies, participation at the National Meetings and providing financial support is the most effective means to do so. Their attendance would contribute significantly to their scientific training and communication and presentation skills. They would be exposed to the leading researchers from the US and abroad; they would meet their peers from other universities; they would learn about cutting-edge results that could benefit their research projects; and they may become interested in becoming active participants in the catalysis community. These young investigators represent the next generation of scientists and engineers, and their proper training will lead to future scientific breakthroughs and technological innovations that benefit the US economy. Advances in catalysis can come in the form of more energy-efficient and environmentally-friendly chemical processes, improved fuel cell performance, efficient hydrogen production, and a cleaner environment.

  17. Hot Topics Summer Workshops | Photosynthetic Antenna Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    workshop series, led by PARC Teacher Leaders and graduate students, focuses on bringing authentic science and engineering concepts into the classroom. Workshops focused on...

  18. Hot Topic Workshop | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This workshop is intended for secondary science teachers. PARC Teacher Leader, Traice Cain, and PARC's Education and Outreach Coordinator, Rachel Ruggirello, will facilitate this...

  19. TECHNICAL STANDARDS PROGRAM TOPICAL COMMITTEES

    Broader source: Energy.gov [DOE]

    PurposeThis procedure describes how topical committees are organized and recognized under the Technical Standards Program. 

  20. Catalysis Working Group Kick-Off Meeting Agenda

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Arlington, VA - May 14, 2012 Catalysis Working Group Kick-off Meeting Co-Chairs: Piotr Zelenay Los Alamos National Laboratory Nancy L. Garland U.S. Department of Energy 2 2...

  1. Catalysis Working Group Kick-Off Meeting Agenda

    Broader source: Energy.gov [DOE]

    Agenda for the kick-off meeting of the U.S. Department of Energy Fuel Cell Technologies Program's Catalysis Working Group, held May 14, 2012, in Arlington, Virginia.

  2. CABS | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Research Topics: catalysis (homogeneous), catalysis (heterogeneous), solar (fuels), ... GC5 Non-equilibrium BRN Addressed CombustionTransportation Fuels Solar Energy Utilization

  3. Materials Design and Discovery: Catalysis and Energy Storage (Mira Early

    Office of Scientific and Technical Information (OSTI)

    Science Program Final Technical Report): ALCF-2 Early Science Program Technical Report (Technical Report) | SciTech Connect Materials Design and Discovery: Catalysis and Energy Storage (Mira Early Science Program Final Technical Report): ALCF-2 Early Science Program Technical Report Citation Details In-Document Search Title: Materials Design and Discovery: Catalysis and Energy Storage (Mira Early Science Program Final Technical Report): ALCF-2 Early Science Program Technical Report Authors:

  4. Theoretical Study on Catalysis by Protein Enzymes and Ribozyme

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Theoretical Study on Catalysis by Protein Enzymes and Ribozyme Theoretical Study on Catalysis by Protein Enzymes and Ribozyme 2000 NERSC Annual Report 17shkarplus.jpg The energetics were determined for three mechanisms proposed for TIM catalyzed reactions. Results from reaction path calculations suggest that the two mechanisms that involve an enediol intermediate are likely to occur, while the direct intra-substrate proton transfer mechanism (in green) is energetically unfavorable due to the

  5. Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Make Fuels and Chemicals | Department of Energy Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to Make Fuels and Chemicals Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to Make Fuels and Chemicals BETO works with the emerging U.S. bioindustry to sustainably convert non-food biomass resources into cost-competitive biofuels, biopower, and bioproducts. PDF icon biochemical_four_pager.pdf More Documents & Publications Replacing the Whole

  6. Visualizing Group II Intron Catalysis through the Stages of Splicing

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Visualizing Group II Intron Catalysis through the Stages of Splicing Citation Details In-Document Search Title: Visualizing Group II Intron Catalysis through the Stages of Splicing Authors: Marcia, Marco ; Pyle, Anna Marie [1] ; HHMI) [2] + Show Author Affiliations (Yale) ( Publication Date: 2013-01-10 OSTI Identifier: 1054354 Resource Type: Journal Article Resource Relation: Journal Name: Cell; Journal

  7. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS X-Rays Shine a New Light on Catalysis ALS X-Rays Shine a New Light on Catalysis Print Thursday, 21 May 2015 11:16 Electrocatalysts are responsible for expediting reactions in many promising renewable energy technologies. However, the extreme sensitivity of their surface redox states to temperatures, to gas pressures, and to electrochemical reaction conditions renders them difficult to investigate by conventional surface-science techniques. Recently a team of Stanford and Berkeley Lab

  8. Lean NOx Catalysis Research and Development | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    3 DEER Conference Presentation: Caterpillar, Inc. PDF icon 2003_deer_park.pdf More Documents & Publications Lean-NOx Catalyst Development for Diesel Engine Applications Fuel Effects on Emissions Control Technologies

  9. Support for Speakers and Attendees at 2008 GRC Conference Catalysis (to be held at Colby Sawyer College, New London, New Hampshire on June 22-27, 2008)

    SciTech Connect (OSTI)

    Stuart L. Soled and Nancy Ryan Gray

    2009-01-01

    The GRC on Catalysis is one of the most prestigious catalysis conferences as it brings together leading researchers from around the world to discuss their latest, most exciting work in catalysis. The 2008 conference will continue this tradition. The conference will cover a variety of themes including new catalytic materials, theoretical and experimental approaches to improve understanding of kinetics and transport phenomena, and state of the art nanoscale characterization probes to monitor active sites. The conference promotes interactions among established researchers and young scientists. It provides a venue for students to meet, talk to and learn from some of the world leading researchers in the area. It also gives them a platform for displaying their own work during the poster sessions. The informal nature of the meeting, excellent quality of the presentations and posters, and ability to meet many outstanding colleagues makes this an excellent conference.

  10. Some General Themes in Catalysis at LANL

    SciTech Connect (OSTI)

    Gordon, John C.

    2012-07-19

    Some general themes in catalysis at LANL are: (1) Storage and release of energy within chemical bonds (e.g. H{sub 2} storage in and release from covalent bonds, N{sub 2} functionalization, CO{sub 2} functionalization, H{sub 2} oxidation/evolution, O{sub 2} reduction/evolution); (2) Can we control the chemistry of reactive substrates to effect energy relevant transformations in non-traditional media (e.g. can we promote C-C couplings, dehydrations, or hydrogenations in water under relatively mild conditions)? (3) Can we supplant precious metal or rare earth catalysts to effect these transformations, by using earth abundant metals/elements instead? Can we use organocatalysis and circumvent the use of metals completely? (4) Can we improve upon existing rare earth catalyst systems (e.g. in rare earth oxides pertinent to fluid cracking or polymerization) and reduce amounts required for catalytic efficacy? Carbohydrates can be accessed from non-food based biomass sources such as woody residues and switchgrass. After extracted from the plant source, our goal is to upgrade these classes of molecules into useful fuels.

  11. The 2013 Clusters, Nanocrystals & Nanostructures Gordon Research Conference/Gordon Research Seminar

    SciTech Connect (OSTI)

    Krauss, Todd D.

    2014-11-25

    The fundamental properties of small particles and their potential for groundbreaking applications are among the most exciting areas of study in modern physics, chemistry, and materials science. The Clusters, Nanocrystals & Nanostructures Gordon ResearchConference and Gordon Research Seminar synthesize contributions from these inter-related fields that reflect the pivotal role of nano-particles at the interface between these disciplines. Size-dependent optical, electronic, magnetic and catalytic properties offer prospects for applications in many fields, and possible solutions for many of the grand challenges facing energy generation, consumption, delivery, and storage in the 21st century. The goal of the 2013 Clusters, Nanocrystals & Nanostructures Gordon Research Conference and Gordon Research Seminar is to continue the historical interdisciplinary tradition of this series and discuss the most recent advances, basic scientific questions, and emerging applications of clusters, nanocrystals, and nanostructures. The Clusters, Nanocrystals & Nanostructures GRC/GRS traditionally brings together the leading scientific groups that have made significant recent advances in one or more fundamental nanoscience or nanotechnology areas. Broad interests of the DOE BES and Solar Photochemistry Program addressed by this meeting include the areas of solar energy to fuels conversion, new photovoltaic systems, fundamental characterization of nanomaterials, magnetism, catalysis, and quantum physics. The vast majority of speakers and attendees will address either directly the topic of nanotechnology for photoinduced charge transfer, charge transport, and catalysis, or will have made significant contributions to related areas that will impact these fields indirectly. These topics have direct relevance to the mission of the DOE BES since it is this cutting-edge basic science that underpins our energy future.

  12. Special Topics and Data Reports

    U.S. Energy Information Administration (EIA) Indexed Site

    (HTML format) Yellow Arrow Energy Consumption and Expenditures (HTML format) adobe logo Download Acrobat Reader for viewing PDF files. Special Topics and Data Reports...

  13. Photos | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photos Photos EFRC Graduate Student Postdoctoral Researcher Competition Missouri Botanical Gardens Tour | Events & Topics Hot Topics Summer Workshops All Hands 2015 Tyson Research...

  14. Study of catalysis of coal gasification at elevated pressures. [Evaluation

    Office of Scientific and Technical Information (OSTI)

    of 20 compounds at 850/sup 0/C] (Journal Article) | SciTech Connect Study of catalysis of coal gasification at elevated pressures. [Evaluation of 20 compounds at 850/sup 0/C] Citation Details In-Document Search Title: Study of catalysis of coal gasification at elevated pressures. [Evaluation of 20 compounds at 850/sup 0/C] Authors: Haynes, W.P. ; Neilson, H. [1] ; Field, J.H. + Show Author Affiliations (US Bur. Mines, Pittsburgh, PA) Publication Date: 1971-01-01 OSTI Identifier: 5238924

  15. Shape-selective catalysis in dimethyl ether conversion

    SciTech Connect (OSTI)

    Sardesai, A.; Lee, S.

    1999-07-01

    Coal-derived syngas can be effectively converted to dimethyl ether (DME) in a single-stage, liquid-phase process. This Liquid Phase Dimethyl Ether (LPDME) process utilizes a dual catalytic system, which comprises of a physical blend between the methanol synthesis and the methanol dehydration catalyst slurried in an inert mineral oil. Such produced DME has vast potential as a building block chemical in the petrochemical industry to produce value-added specialty chemicals. The current research efforts are made to exploit the utilization of shape-selective catalysis using zeolites to produce targeted petrochemicals, including lower olefinic hydrocarbons. The catalysts probed in this investigation include zeolites of different physical, morphological, and chemical configurations. The effect of acidity of ZSM-5 type zeolites as well as the effect of the different channel size and orientation of the zeolites on product selectivity and catalyst deactivation are examined. Results obtained from experimentation of this study show that ZSM-5 type zeolite with low acidity (high SiO{sub 2}/Al{sub 2}O{sub 3} ratio, in this case 150) exhibits the highest selectivity towards lower (C{sub 2}-C{sub 4}) olefins in general. Controlled selectivity toward targeted olefinic species can be accomplished via devising catalytic reaction systems in such a way that the structural property of the catalyst and reactive interaction between molecules in the pores are geared toward formation of targeted molecular species which also at the same time prevent the formation of less desirable products. The internal morphology of the catalyst also has a pronounced effect on the deactivation phenomenon, where it is observed that zeolites possessing high acidity and a unidimensional channel structure are prone towards catalyst deactivation by coking and pore blockage.

  16. FY16 SBIR Phase II Release 1 Awards Announced: Includes Hydrogen Contaminants Detection, Fuel Cell and Hydrogen Catalysis, and Alkaline Membrane Electrolysis

    Broader source: Energy.gov [DOE]

    The Energy Department has announced the 2016 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase II Release 1 awards, including three projects focused on catalysis for fuel cell and hydrogen production as well as hydrogen contaminants detection.

  17. Lean NOx Trap Catalysis for Lean Natural Gas Engine Applications

    SciTech Connect (OSTI)

    Parks, II, James E; Storey, John Morse; Theiss, Timothy J; Ponnusamy, Senthil; Ferguson, Harley Douglas; Williams, Aaron M; Tassitano, James B

    2007-09-01

    Distributed energy is an approach for meeting energy needs that has several advantages. Distributed energy improves energy security during natural disasters or terrorist actions, improves transmission grid reliability by reducing grid load, and enhances power quality through voltage support and reactive power. In addition, distributed energy can be efficient since transmission losses are minimized. One prime mover for distributed energy is the natural gas reciprocating engine generator set. Natural gas reciprocating engines are flexible and scalable solutions for many distributed energy needs. The engines can be run continuously or occasionally as peak demand requires, and their operation and maintenance is straightforward. Furthermore, system efficiencies can be maximized when natural gas reciprocating engines are combined with thermal energy recovery for cooling, heating, and power applications. Expansion of natural gas reciprocating engines for distributed energy is dependent on several factors, but two prominent factors are efficiency and emissions. Efficiencies must be high enough to enable low operating costs, and emissions must be low enough to permit significant operation hours, especially in non-attainment areas where emissions are stringently regulated. To address these issues the U.S. Department of Energy and the California Energy Commission launched research and development programs called Advanced Reciprocating Engine Systems (ARES) and Advanced Reciprocating Internal Combustion Engines (ARICE), respectively. Fuel efficiency and low emissions are two primary goals of these programs. The work presented here was funded by the ARES program and, thus, addresses the ARES 2010 goals of 50% thermal efficiency (fuel efficiency) and <0.1 g/bhp-hr emissions of oxides of nitrogen (NOx). A summary of the goals for the ARES program is given in Table 1-1. ARICE 2007 goals are 45% thermal efficiency and <0.015 g/bhp-hr NOx. Several approaches for improving the efficiency and emissions of natural gas reciprocating engines are being pursued. Approaches include: stoichiometric engine operation with exhaust gas recirculation and three-way catalysis, advanced combustion modes such as homogeneous charge compression ignition, and extension of the lean combustion limit with advanced ignition concepts and/or hydrogen mixing. The research presented here addresses the technical approach of combining efficient lean spark-ignited natural gas combustion with low emissions obtained from a lean NOx trap catalyst aftertreatment system. This approach can be applied to current lean engine technology or advanced lean engines that may result from related efforts in lean limit extension. Furthermore, the lean NOx trap technology has synergy with hydrogen-assisted lean limit extension since hydrogen is produced from natural gas during the lean NOx trap catalyst system process. The approach is also applicable to other lean engines such as diesel engines, natural gas turbines, and lean gasoline engines; other research activities have focused on those applications. Some commercialization of the technology has occurred for automotive applications (both diesel and lean gasoline engine vehicles) and natural gas turbines for stationary power. The research here specifically addresses barriers to commercialization of the technology for large lean natural gas reciprocating engines for stationary power. The report presented here is a comprehensive collection of research conducted by Oak Ridge National Laboratory (ORNL) on lean NOx trap catalysis for lean natural gas reciprocating engines. The research was performed in the Department of Energy's ARES program from 2003 to 2007 and covers several aspects of the technology. All studies were conducted at ORNL on a Cummins C8.3G+ natural gas engine chosen based on industry input to simulate large lean natural gas engines. Specific technical areas addressed by the research include: NOx reduction efficiency, partial oxidation and reforming chemistry, and the effects of sulfur poisons on the partial oxidation, reformer, and lean NOx trap catalysts. The initial work on NOx reduction efficiency demonstrated that NOx emissions <0.1 g/bhp-hr (the ARES goal) can be achieved with the lean NOx trap catalyst technology. Subsequent work focused on cost and size optimization and durability issues which addressed two specific ARES areas of interest to industry ('Cost of Power' and 'Availability, Reliability, and Maintainability', respectively). Thus, the research addressed the approach of the lean NOx trap catalyst technology toward the ARES goals as shown in Table 1-1.

  18. Topics: Determining the Beta Limit - MST - UW Plasma Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Determining the Beta Limit UW Madison Madison Symmetric Torus Topics: Determining the Beta Limit MST HomeGraduate Student InformationLinksTourControl and Auxiliary SystemsPhysics TopicsDeviceResearch MissionMST People mst logo CPLA Home Directory Publications Links Internal University of Wisconsin Physics Department Research funding includes support from: Department of Energy National Science Foundation One of the reasons improved confinement in MST can be described as "tokamak-like"

  19. Center for Molecular Electrocatalysis (CME) | U.S. DOE Office...

    Office of Science (SC) Website

    To understand and design molecular electrocatalysts for conversions between electrical energy and chemical energy. Research Topics catalysis (homogeneous), solar (fuels), ...

  20. HeteroFoaM | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    as fuel cells, batteries, supercapacitors, electrolyzers, and solid membranes. Research Topics: catalysis (heterogeneous), energy storage (including batteries and capacitors), ...

  1. Fluid Interface Reactions, Structures and Transport Center (FIRST...

    Office of Science (SC) Website

    Research Topics catalysis (heterogeneous), energy storage (including batteries and capacitors), charge transport, mesostructured materials, materials and chemistry by design, ...

  2. TEC Working Group Topic Groups Archives Consolidated Grant Topic Group

    Broader source: Energy.gov [DOE]

    The Consolidated Grant Topic Group arose from recommendations provided by the TEC and other external parties to the DOE Senior Executive Transportation Forum in July 1998. It was proposed that the consolidation of multiple funding streams from numerous DOE sources into a single grant would provide a more equitable and efficient means of assistance to States and Tribes affected by DOE nuclear material shipments.

  3. More About "Topic A" and "Topic B" Awards | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of major new long-distance transmission facilities and networks. Topic A, Interconnection-Level Analysis and Planning Learn more about "Topic A" requirements Topic B, ...

  4. Recent advances of lanthanum-based perovskite oxides for catalysis

    SciTech Connect (OSTI)

    Zhu, Huiyuan; Zhang, Pengfei; Dai, Sheng

    2015-09-21

    There is a need to reduce the use of noble metal elements especially in the field of catalysis, where noble metals are ubiquitously applied. To this end, perovskite oxides, an important class of mixed oxide, have been attracting increasing attention for decades as potential replacements. Benefiting from the extraordinary tunability of their compositions and structures, perovskite oxides can be rationally tailored and equipped with targeted physical and chemical properties e.g. redox behavior, oxygen mobility, and ion conductivity for enhanced catalysis. Recently, the development of highly efficient perovskite oxide catalysts has been extensively studied. This review article summarizes the recent development of lanthanum-based perovskite oxides as advanced catalysts for both energy conversion applications and traditional heterogeneous reactions.

  5. Recent advances of lanthanum-based perovskite oxides for catalysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, Huiyuan; Zhang, Pengfei; Dai, Sheng

    2015-09-21

    There is a need to reduce the use of noble metal elements especially in the field of catalysis, where noble metals are ubiquitously applied. To this end, perovskite oxides, an important class of mixed oxide, have been attracting increasing attention for decades as potential replacements. Benefiting from the extraordinary tunability of their compositions and structures, perovskite oxides can be rationally tailored and equipped with targeted physical and chemical properties e.g. redox behavior, oxygen mobility, and ion conductivity for enhanced catalysis. Recently, the development of highly efficient perovskite oxide catalysts has been extensively studied. This review article summarizes the recent developmentmore » of lanthanum-based perovskite oxides as advanced catalysts for both energy conversion applications and traditional heterogeneous reactions.« less

  6. Missouri Botanical Gardens Tour | Events & Topics | Photosynthetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Events & Topics Missouri Botanical Gardens Tour | Events & Topics PARC welcomed community members for our guided tour of the Missouri Botanical Garden. http:...

  7. TEC Working Group Topic Groups Archives

    Broader source: Energy.gov [DOE]

    The following Topic Groups are no longer active; however, related documents and notes for these archived Topic Groups are available through the following links:

  8. ECIS and Compass Metals: Platinum Nanostructures for Enhanced Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ECIS and Compass Metals: Platinum Nanostructures for Enhanced Catalysis - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel

  9. University of Delaware | Catalysis Center for Energy Innovation | Modeling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Modeling Activity map produced from the new high-throughput computational engine. Example for ethylene glycol catalysis. Reforming, hydrodeoxygenation, dehydrogenation, and catalyst poisoning (e.g., coking) occur at different regions of the map. Major developments have taken place in first-principles-based prediction of reforming and hydrodeoxygenation catalysts for key biomass derivatives. These developments can eventually assist in catalyst and process design for bio-oil upgrade and conversion

  10. Catalysis by Design - Theoretical and Experimental Studies of Model

    Broader source: Energy.gov (indexed) [DOE]

    Catalysis Working Group (CWG) meets twice per year to exchange information, create synergies, and collaboratively develop both an understanding of and tools for studying electrocatalysis for polymer electrolyte fuel cells (PEFCs) and other low- and intermediate-temperature fuel cell systems, including direct methanol fuel cells (DMFCs), alkaline fuel cells (AFCs), alkaline membrane fuel cells (AMFCs), and phosphoric acid fuel cells (PAFCs). The CWG members include principal and co-principal

  11. 2012 LANSCE Topical User Meeting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 LANSCE Topical User Meeting January 9-10, 2012 The Office of Defense Programs is developing a long-term strategy for the construction of new experimental science facilities supporting NNSA missions. The new facilities will provide the critical science and technology capabilities necessary to execute the 21 st century responsibilities of NNSA in executing its mission and in supporting the broader national security agenda. The call focuses on large facilities with costs exceeding $100M. The NNSA

  12. Events & Topics in Renewable Energy & the Environment | Photosynthetic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Antenna Research Center Events & Topics in Renewable Energy & the Environment Events & Topics in Renewable Energy & the Environment Missouri Botanical Garden- EarthWays Center October 6, 2015 - 4:00pm How "green" are you? Join us as we experience a sustainability-themed visit to the Missouri Botanical Garden led by a representative from the EarthWays Center, including an interpretive tour that illustrates the importance of waste minimization, energy, energy

  13. Topical Collaboration "Neutrinos and Nucleosynthesis in Hot and Dense Matter"

    SciTech Connect (OSTI)

    Allahverdi, Rouzbeh

    2015-09-18

    This is the final technical report describing contributions from the University of New Mexico to Topical Collaboration on "Neutrinos and Nucleosynthesis in Hot and Dense Matter" in the period June 2010 through May 2015. During the funding period, the University of New Mexico successfully hired Huaiyu Duan as a new faculty member with the support from DOE, who has contributed to the Topical Collaboration through his research and collaborations.

  14. Manufacturing Innovation Multi-Topic Workshop | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Innovation Multi-Topic Workshop Manufacturing Innovation Multi-Topic Workshop DOE's Advanced Manufacturing Office (AMO) and the Office of Secretary of Defense Manufacturing Technology Program (OSD ManTech) held a joint workshop October 8 and 9, 2014 in Fort Worth, TX. This workshop identified mid-Technology Readiness Level (TRL) research and development (R&D) needs, market and supply chain challenges, and shared facility needs for advanced manufacturing. The workshop complemented a recently

  15. WTP Communications Strategy Discussion Topics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Discussion Topics For discussion at the April 7, 2015 PIC meeting Issue Managers: Bob Suyama, Dave Bernhard, Melanie Myers-Magnuson, Dirk Dunning, Liz Mattson, Pam Larsen, Ken Niles Some potential questions and areas that the TWC/PIC need to discuss in order to develop a Communica- tions Strategy for the Waste Treatment Plant. These questions represent the data that the TWC/PIC might need in order to provide a plan that will be of value to the Tri-Party Agencies and the Public and Stakeholders.

  16. Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. Research thorium test foil A thorium test foil ...

  17. Hydrogen catalysis and scavenging action of Pd-POSS nanoparticles

    SciTech Connect (OSTI)

    Maiti, A; Gee, R H; Maxwell, R; Saab, A

    2007-02-01

    Prompted by the need for a self-supported, chemically stable, and functionally flexible catalytic nanoparticle system, we explore a system involving Pd clusters coated with a monolayer of polyhedral oligomeric silsesquioxane (POSS) cages. With an initial theoretical focus on hydrogen catalysis and sequestration in the Pd-POSS system, we report Density Functional Theory (DFT) results on POSS binding energies to the Pd(110) surface, hydrogen storing ability of POSS, and possible pathways of hydrogen radicals from the catalyst surface to unsaturated bonds away from the surface.

  18. Fuels and energy for the future: The role of catalysis

    SciTech Connect (OSTI)

    Rostrup-Nielsen, J.R.; Nielsen, R.

    2004-07-01

    There are many reasons to decrease the dependency on oil and to increase the use of other energy sources than fossil fuels. The wish for energy security is balanced by a wish for sustainable growth. Catalysis plays an important role in creating new routes and flexibility in the network of energy sources, energy carriers, and energy conversion. The process technologies resemble those applied in the large scale manufacture of commodities. This is illustrated by examples from refinery fuels, synfuels, and hydrogen and the future role of fossil fuels is discussed.

  19. Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control

    Broader source: Energy.gov (indexed) [DOE]

    | Department of Energy PDF icon 2002_deer_aardahl.pdf More Documents & Publications Heavy-Duty NOx Emissions Control: Reformer-Assisted vs. Plasma-Facilitated Lean NOx Catalysis Selective reduction of NOx in oxygen rich environments with plasma-assisted catalysis: Catalyst development and mechanistic studies

  20. Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Research Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. Research thorium test foil A thorium test foil target for proof-of-concept actinium-225 production In addition to our routine isotope products, the LANL Isotope Program is focused on developing the next suite of isotopes and services to meet the Nation's emerging needs. The LANL Isotope Program's R&D strategy is focused on four main areas (see

  1. TEC Working Group Topic Groups Routing

    Broader source: Energy.gov [DOE]

    The Routing Topic Group has been established to examine topics of interest and relevance concerning routing of shipments of spent nuclear fuel (SNF) and high-level radioactive waste (HLW) to a...

  2. Energy & Manufacturing Workforce Training Topics List - Version...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Manufacturing Workforce Training Topics List - Version 1.7 (02.11.14) Energy & Manufacturing Workforce Training Topics List - Version 1.7 (02.11.14) View this searchable list of ...

  3. Research News December 2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ORD's Catalysis Expertise is Key to a Cleaner Energy Future page 3 the ENERGY lab NATIONAL ENERGY TECHNOLOGY LABORATORY From NETL's Office of Research & Development Researchnews December 2014, Issue 3 2 Contents D id you know that catalysts can be used to convert carbon dioxide (CO 2 ) into a useable fuel? Or that catalysts can use clean, free sunlight to drive CO 2 conversion to useful chemicals? The Office of Research and Development (ORD) is harnessing the power of catalysts to make

  4. Surface Catalysis of Water Oxidation by the Blue Ruthenium Dimer

    SciTech Connect (OSTI)

    Jurss, Jonah W.; Concepcion, Javier C.; Norris, Michael R.; Templeton, Joseph L.; Meyer, Thomas J.

    2010-04-08

    Single-electron activation of multielectron catalysis has been shown to be viable in catalytic water oxidation with stepwise proton-coupled electron transfer, leading to high-energy catalytic precursors. For the blue dimer, cis,cis-[(bpy)2(H2O)RuIIIORuIII(H2O)(bpy)2]4+, the first well-defined molecular catalyst for water oxidation, stepwise 4e-/4H+ oxidation occurs to give the reactive precursor [(O)RuVORuV(O)]4+. This key intermediate is kinetically inaccessible at an unmodified metal oxide surface, where the only available redox pathway is electron transfer. We report here a remarkable surface activation of indium-tin oxide (In2O3:Sn) electrodes toward catalytic water oxidation by the blue dimer at electrodes derivatized by surface phosphonate binding of [Ru(4,4'-((HO)2P(O)CH2)2bpy)2(bpy)]2+. Surface binding dramatically improves the rate of surface oxidation of the blue dimer and induces water oxidation catalysis.

  5. Presentation: QER Energy Topics | Department of Energy

    Energy Savers [EERE]

    QER Energy Topics Presentation: QER Energy Topics A briefing to the Secretary's Energy Advisory Board on QER Energy Topics (Energy Flows, Water Flows, and Program for Climate Model Diagnosis and Intercomparison) prepared by: A.J. Simon, Lawrence Livermore National Laboratory PDF icon QER Energy Topics More Documents & Publications Presentation: High Performance Computing Applications Computational Advances in Applied Energy December 3, 2013 SEAB Meeting Minutes

  6. Technical Assistance Topics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electricity Policy Coordination and Implementation » Electricity Policy Technical Assistance Program » Technical Assistance Topics Technical Assistance Topics Topics addressed are those of greatest interest to states, regions, and Tribes, including: Reliability, resiliency, and cyber security of electric power systems Electric resource planning, integrated resource planning, regional transmission planning, and resource acquisition strategies Ratepayer-funded energy efficiency, demand response,

  7. Research

    SciTech Connect (OSTI)

    1999-10-01

    Subjects covered in this section are: (1) PCAST panel promotes energy research cooperation; (2) Letter issued by ANS urges funding balance in FFTF restart consideration and (3) FESAC panel releases report on priorities and balance.

  8. 2013 INORGANIC REACTION MECHANISMS GORDON RESEARCH CONFERENCE (MARCH 3-8, 2013 - HOTEL GALVEZ, GALVESTON TX)

    SciTech Connect (OSTI)

    Abu-Omar, Mahdi M.

    2012-12-08

    The 2013 Gordon Conference on Inorganic Reaction Mechanisms will present cutting-edge research on the molecular aspects of inorganic reactions involving elements from throughout the periodic table and state-of-the art techniques that are used in the elucidation of reaction mechanisms. The Conference will feature a wide range of topics, such as homogeneous and heterogeneous catalysis, metallobiochemistry, electron-transfer in energy reactions, polymerization, nitrogen fixation, green chemistry, oxidation, solar conversion, alkane functionalization, organotransition metal chemistry, and computational chemistry. The talks will cover themes of current interest including energy, materials, and bioinorganic chemistry. Sections cover: Electron-Transfer in Energy Reactions; Catalytic Polymerization and Oxidation Chemistry; Kinetics and Spectroscopy of Heterogeneous Catalysts; Metal-Organic Chemistry and its Application in Synthesis; Green Energy Conversion;Organometallic Chemistry and Activation of Small Molecules; Advances in Kinetics Modeling and Green Chemistry; Metals in Biology and Disease; Frontiers in Catalytic Bond Activation and Cleavage.

  9. Decision Point 1 Topical Report

    SciTech Connect (OSTI)

    Yablonsky, Al; Barsoumian, Shant; Legere, David

    2013-05-01

    This Topical Report addresses accomplishments achieved during Phase 2a of the SkyMine® Carbon Mineralization Pilot Project. The primary objectives of this project are to design, construct, and operate a system to capture CO2 from a slipstream of flue gas from a commercial coal-fired cement kiln, convert that CO2 to products having commercial value (i.e., beneficial use), show the economic viability of the CO2 capture and conversion process, and thereby advance the technology to the point of readiness for commercial scale demonstration and proliferation. The overall process is carbon negative, resulting in mineralization of CO2 that would otherwise be released into the atmosphere. The project will also substantiate market opportunities for the technology by sales of chemicals into existing markets, and identify opportunities to improve technology performance and reduce costs at the commercial scale. The project is being conducted in two phases. The primary objectives of Phase 1 were to elaborate proven SkyMine® process chemistry to commercial pilot-scale operation and complete the preliminary design for the pilot plant to be built and operated in Phase 2, complete a NEPA evaluation, and develop a comprehensive carbon life cycle analysis. The objective of the current Phase (2a) is to complete the detailed design of the pilot plant to be built in Phase 2b.

  10. Preface: Special Topic on Interfacial and Confined Water

    SciTech Connect (OSTI)

    Molinero, Valeria; Kay, Bruce D.

    2014-11-14

    This Special Topic on the Chemical Physics of Interfacial and Confined Water contains a collection of original research papers that showcase recent theoretical and experimental advances in the field. These papers provide a timely discussion of fundamental aspects of interfacial and confined water that are important in both natural environments and engineered applications.

  11. Cooperative research in coal liquefaction

    SciTech Connect (OSTI)

    Huffman, G.P.; Sendlein, L.V.A. (eds.)

    1991-05-28

    Significant progress was made in the May 1990--May 1991 contract period in three primary coal liquefaction research areas: catalysis, structure-reactivity studies, and novel liquefaction processes. A brief summary of the accomplishments in the past year in each of these areas is given.

  12. SBIR/STTR FY16 Phase 1 Release 1 Topics Announced—Includes Hydrogen Production and Fuel Cell Membrane Topics

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy has announced the 2016 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase I Release 1 Topics, including hydrogen production from organic waste streams and fuel cell membranes, through the Office of Basic Energy Sciences.

  13. Events & Topics in Renewable Energy & the Environment | Photosynthetic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Antenna Research Center Events & Topics in Renewable Energy & the Environment Events & Topics in Renewable Energy & the Environment Missouri MetroLink Facility April 12, 2016 - 4:00pm 700 S. Ewing, St. Louis, MO 63103 Event flyer RSVP here Free bus will depart from the front of Brookings Hall at 3:30 pm sharp and will return to the same location following the tour. If you plan to drive yourself, please contact Erin Plut (eplut@wustl.edu) for parking information and meet up

  14. UNC EFRC: Fuels from Sunlight (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    SciTech Connect (OSTI)

    Meyer, Thomas J.; UNC EFRC Staff

    2011-05-01

    'Fuels from Sunlight' was submitted by the University of North Carolina (UNC) EFRC: Solar Fuels and Next Generation Photovoltaics to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. The UNC EFRC directed by Thomas J. Meyer is a partnership of scientists from six institutions: UNC (lead), Duke University, University of Florida, North Caroline Central University, North Carolina State University, and the Research Triangle Institute. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of Solar Fuels and Next Generation Photovoltaics is 'to combine the best features of academic and translational research to study light/matter interactions and chemical processes for the efficient collection, transfer, and conversion of solar energy into chemical fuels and electricity.' Research topics are: catalysis (CO{sub 2}, hydrocarbons, water), electrocatalysis, photocatalysis, photoelectrocatalysis, solar photovoltaic, solar fuels, photonic, solar electrodes, photosynthesis, fuel cells, CO{sub 2} (convert), greenhosue gas, hydrogen (fuel), interfacial characterization, novel materials synthesis, charge transport, and self-assembly.

  15. UNC EFRC: Fuels from Sunlight (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    ScienceCinema (OSTI)

    Meyer, Thomas J. (Director, UNC EFRC: Solar Fuels and Next Generation Photovoltaics); UNC EFRC Staff

    2011-11-02

    'Fuels from Sunlight' was submitted by the University of North Carolina (UNC) EFRC: Solar Fuels and Next Generation Photovoltaics to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. The UNC EFRC directed by Thomas J. Meyer is a partnership of scientists from six institutions: UNC (lead), Duke University, University of Florida, North Caroline Central University, North Carolina State University, and the Research Triangle Institute. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of Solar Fuels and Next Generation Photovoltaics is 'to combine the best features of academic and translational research to study light/matter interactions and chemical processes for the efficient collection, transfer, and conversion of solar energy into chemical fuels and electricity.' Research topics are: catalysis (CO{sub 2}, hydrocarbons, water), electrocatalysis, photocatalysis, photoelectrocatalysis, solar photovoltaic, solar fuels, photonic, solar electrodes, photosynthesis, fuel cells, CO{sub 2} (convert), greenhosue gas, hydrogen (fuel), interfacial characterization, novel materials synthesis, charge transport, and self-assembly.

  16. Tracking topic birth and death in LDA.

    SciTech Connect (OSTI)

    Wilson, Andrew T.; Robinson, David Gerald

    2011-09-01

    Most topic modeling algorithms that address the evolution of documents over time use the same number of topics at all times. This obscures the common occurrence in the data where new subjects arise and old ones diminish or disappear entirely. We propose an algorithm to model the birth and death of topics within an LDA-like framework. The user selects an initial number of topics, after which new topics are created and retired without further supervision. Our approach also accommodates many of the acceleration and parallelization schemes developed in recent years for standard LDA. In recent years, topic modeling algorithms such as latent semantic analysis (LSA)[17], latent Dirichlet allocation (LDA)[10] and their descendants have offered a powerful way to explore and interrogate corpora far too large for any human to grasp without assistance. Using such algorithms we are able to search for similar documents, model and track the volume of topics over time, search for correlated topics or model them with a hierarchy. Most of these algorithms are intended for use with static corpora where the number of documents and the size of the vocabulary are known in advance. Moreover, almost all current topic modeling algorithms fix the number of topics as one of the input parameters and keep it fixed across the entire corpus. While this is appropriate for static corpora, it becomes a serious handicap when analyzing time-varying data sets where topics come and go as a matter of course. This is doubly true for online algorithms that may not have the option of revising earlier results in light of new data. To be sure, these algorithms will account for changing data one way or another, but without the ability to adapt to structural changes such as entirely new topics they may do so in counterintuitive ways.

  17. LANSCE | Users | LUG | Topical User Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 LANSCE Topical User Meeting | January 9-10 2012 LANSCE Topical User Workshop LANSCE will host the 2012 Topical User Workshop, January 9-10, 2012. We hope to see you there! Registration | Accommodations | Agenda (some presentations are included on the agenda) LANL foreign nationals may register at anytime. | Poster Dimensions: 32 in x 40 in This workshop will solicit user input for the scientific opportunities offered by the pulse stacker and superconducting accelerator that LANSCE has proposed

  18. TEC Working Group Topic Groups Archives Communications

    Broader source: Energy.gov [DOE]

    The Communications Topic Group was convened in April 1998 to improve internal and external strategic level communications regarding DOE shipments of radioactive and other hazardous materials.

  19. TEC Working Group Topic Groups Security

    Broader source: Energy.gov [DOE]

    The Security Topic group is comprised of regulators, law enforcement officials, labor and industry representatives and other subject matter experts concerned with secure transport of spent nuclear...

  20. Collaboration Topics - Visualization | National Nuclear Security...

    National Nuclear Security Administration (NNSA)

    NNSACEA Cooperation in Computer Science Collaboration Topics - Visualization ... to visualize large data sets on small computational resources. 3) In situ visualization ...

  1. Interconnection-Wide Transmission Planning Initiative: Topic...

    Energy Savers [EERE]

    the Texas Interconnection Interconnection-Wide Transmission Planning Initiative: Topic B, State Agency Input Regarding Electric Resource and Transmission Planning in the Texas ...

  2. Interconnection-Wide Transmission Planning Initiative: Topic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Western Interconnection on Electric Resource Planning and Priorities Interconnection-Wide Transmission Planning Initiative: Topic B, Cooperation Among States in the Western ...

  3. Interconnection-Wide Transmission Planning Initiative: Topic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Eastern Interconnection on Electric Resource Planning and Priorities Interconnection-Wide Transmission Planning Initiative: Topic B, Cooperation Among States in the Eastern ...

  4. Interconnection-Wide Transmission Planning Initiative: Topic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A, Interconnection-Level Analysis and Planning Interconnection-Wide Transmission Planning Initiative: Topic A, Interconnection-Level Analysis and Planning A description of the ...

  5. Topic Index to the DOE Administrative Records Disposition Schedules...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Topic Index to the DOE Administrative Records Disposition Schedules Topic Index to the DOE Administrative Records Disposition Schedules Topic Index to the DOE Administrative...

  6. Preface: Special Topic on Interfacial and Confined Water (Journal...

    Office of Scientific and Technical Information (OSTI)

    Preface: Special Topic on Interfacial and Confined Water Citation Details In-Document Search Title: Preface: Special Topic on Interfacial and Confined Water This Special Topic on...

  7. Webtrends Archives by Fiscal Year - Topic Landing Pages | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Topic Landing Pages Webtrends Archives by Fiscal Year - Topic Landing Pages From the EERE Web Statistics Archive: Corporate sites, Webtrends archives for the topic landing pages by ...

  8. Search for the ANSER (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum

    SciTech Connect (OSTI)

    Wasielewski, Michael R.; ANSER Staff

    2011-05-01

    'Search for the ANSER' was submitted by the Argonne-Northwestern Solar Energy Research Center (ANSER) to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. ANSER, an EFRC directed by Michael Wasielewski at Argonne National Laboratory is a partnership of scientists from five institutions: Argonne National Laboratory, Northwestern University, University of Chicago, University of Illinois at Urbana-Champaign, and Yale. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. At ANSER, the mission is 'to revolutionize our understanding of molecules, materials and methods necessary to create dramatically more efficient technologies for solar fuels and electricity production.' Research topics are: catalysis (water), electrocatalysis, photocatalysis, photoelectrocatalysis, solar photovoltaic, solar fuels, solar electrodes, photosynthesis, transportation fuels, bio-inspired, spin dynamics, hydrogen (fuel), ultrafast physics, interfacial characterization, matter by design, novel materials synthesis, charge transport, and self-assembly.

  9. Search for the ANSER (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum

    ScienceCinema (OSTI)

    Wasielewski, Michael R. (Director, Argonne-Northwestern Solar Energy Research Center); ANSER Staff

    2011-11-02

    'Search for the ANSER' was submitted by the Argonne-Northwestern Solar Energy Research Center (ANSER) to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. ANSER, an EFRC directed by Michael Wasielewski at Argonne National Laboratory is a partnership of scientists from five institutions: Argonne National Laboratory, Northwestern University, University of Chicago, University of Illinois at Urbana-Champaign, and Yale. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. At ANSER, the mission is 'to revolutionize our understanding of molecules, materials and methods necessary to create dramatically more efficient technologies for solar fuels and electricity production.' Research topics are: catalysis (water), electrocatalysis, photocatalysis, photoelectrocatalysis, solar photovoltaic, solar fuels, solar electrodes, photosynthesis, transportation fuels, bio-inspired, spin dynamics, hydrogen (fuel), ultrafast physics, interfacial characterization, matter by design, novel materials synthesis, charge transport, and self-assembly.

  10. Energy Department Announces Topics and New Approaches for Grants to Small

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Businesses in Clean Energy Technologies | Department of Energy Topics and New Approaches for Grants to Small Businesses in Clean Energy Technologies Energy Department Announces Topics and New Approaches for Grants to Small Businesses in Clean Energy Technologies October 31, 2013 - 1:10pm Addthis The Energy Department's Office of Energy Efficiency and Renewable Energy (EERE) today announced new topics under its Small Business Innovation Research (SBIR) and Technology Transfer (STTR) program

  11. TEC Working Group Topic Groups Archives Protocols

    Broader source: Energy.gov [DOE]

    The Transportation Protocols Topic Group serves as an important vehicle for DOE senior managers to assess and incorporate stakeholder input into the protocols process. The Topic Group was formed to review a series of transportation protocols developed in response to a request for DOE to be more consistent in its approach to transportation.

  12. Hot Topics Summer Workshops | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hot Showers, Fresh Laundry, Clean Dishes Hot Showers, Fresh Laundry, Clean Dishes March 5, 2013 - 11:17am Addthis The GE GeoSpring™ Electric Heat Pump Water Heater is readily integrated into new and existing home designs. Taking up the same footprint as a traditional 50-gallon tank water heater, the Electric Heat Pump Water Heater uses the existing water heater's plumbing and electrical connections. Credit: GE The GE GeoSpring(tm) Electric Heat Pump Water Heater is readily integrated into

  13. Hot Topics Workshop 2016 | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Participants explored how to use Makey Makey to teach electric circuits. Using Makey Makey is a great way to combine science, technology, engineering and math. Participants ...

  14. Hot Topics Fall Workshop | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    edge science to your students? This workshop series, led by PARC Teacher Leaders Tracie Cain and Karen Thompson, focuses on bringing authentic science and engineering concepts into...

  15. Research topics related to ESI | OpenEI Community

    Open Energy Info (EERE)

    A. C. Z. de Souza, "Short-Term Operation Planning of Integrated Hydrothermal and Natural Gas Systems," in Power Tech, 2007 IEEE Lausanne, 2007, pp. 1410-1416. 6 M. Chaudry, N....

  16. Small Business Innovation Research Program Topics - October 28...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... of sales and system design aspects; (ii) expediting of ... transmission and dynamic distribution engineering analysis software combined with innovative hardware systems for data ...

  17. Small Business Innovative Research Topics for grant proposals

    Broader source: Energy.gov [DOE]

    Advanced energy storage and power electronic systems, High temperature superconductivity, Advanced technologies and materials for fusion energy systems

  18. TEC Working Group Topic Groups Rail Conference Call Summaries...

    Office of Environmental Management (EM)

    Summaries Rail Topic Group TEC Working Group Topic Groups Rail Conference Call Summaries Rail Topic Group Rail Topic Group PDF icon May 17, 2007 PDF icon January 16, 2007 PDF icon...

  19. The Fluid Interface Reactions Structures and Transport (FIRST) EFRC (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    SciTech Connect (OSTI)

    Wesolowski, David J.; FIRST Staff

    2011-05-01

    'The Fluid Interface Reactions Structures and Transport (FIRST) EFRC' was submitted by FIRST to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. FIRST, an EFRC directed by David J. Wesolowski at the Oak Ridge National Laboratory is a partnership of scientists from nine institutions: Oak Ridge National Laboratory (lead), Argonne National Laboratory, Drexel University, Georgia State University, Northwestern University, Pennsylvania State University, Suffolk University, Vanderbilt University, and University of Virginia. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of Fluid Interface Reactions, Structures and Transport Center is 'to develop quantitative and predictive models of the unique nanoscale environment at fluid-solid interfaces that will enable transformational advances in electrical energy storage and heterogeneous catalysis for solar fuels.' Research topics are: catalysis (biomass, CO{sub 2}, water), electrocatalysis, photocatalysis, photoelectrocatalysis, solar fuels, solar electrodes, electrical energy storage, batteries, capacitors, battery electrodes, electrolytes, extreme environment, CO{sub 2} (convert), greenhouse gas, microelectromechanical systems (MEMS), interfacial characterization, matter by design, novel materials synthesis, and charge transport.

  20. The Fluid Interface Reactions Structures and Transport (FIRST) EFRC (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    ScienceCinema (OSTI)

    Wesolowski, David J. (Director, FIRST - Fluid Interface Reactions, Structures, and Transport Center); FIRST Staff

    2011-11-02

    'The Fluid Interface Reactions Structures and Transport (FIRST) EFRC' was submitted by FIRST to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. FIRST, an EFRC directed by David J. Wesolowski at the Oak Ridge National Laboratory is a partnership of scientists from nine institutions: Oak Ridge National Laboratory (lead), Argonne National Laboratory, Drexel University, Georgia State University, Northwestern University, Pennsylvania State University, Suffolk University, Vanderbilt University, and University of Virginia. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of Fluid Interface Reactions, Structures and Transport Center is 'to develop quantitative and predictive models of the unique nanoscale environment at fluid-solid interfaces that will enable transformational advances in electrical energy storage and heterogeneous catalysis for solar fuels.' Research topics are: catalysis (biomass, CO{sub 2}, water), electrocatalysis, photocatalysis, photoelectrocatalysis, solar fuels, solar electrodes, electrical energy storage, batteries, capacitors, battery electrodes, electrolytes, extreme environment, CO{sub 2} (convert), greenhouse gas, microelectromechanical systems (MEMS), interfacial characterization, matter by design, novel materials synthesis, and charge transport.

  1. Application of solid ash based catalysts in heterogeneous catalysis

    SciTech Connect (OSTI)

    Shaobin Wang

    2008-10-01

    Solid wastes, fly ash, and bottom ash are generated from coal and biomass combustion. Fly ash is mainly composed of various metal oxides and possesses higher thermal stability. Utilization of fly ash for other industrial applications provides a cost-effective and environmentally friendly way of recycling this solid waste, significantly reducing its environmental effects. On the one hand, due to the higher stability of its major component, aluminosilicates, fly ash could be employed as catalyst support by impregnation of other active components for various reactions. On the other hand, other chemical compounds in fly ash such as Fe{sub 2}O{sub 3} could also provide an active component making fly ash a catalyst for some reactions. In this paper, physicochemical properties of fly ash and its applications for heterogeneous catalysis as a catalyst support or catalyst in a variety of catalytic reactions were reviewed. Fly-ash-supported catalysts have shown good catalytic activities for H{sub 2} production, deSOx, deNOx, hydrocarbon oxidation, and hydrocracking, which are comparable to commercially used catalysts. As a catalyst itself, fly ash can also be effective for gas-phase oxidation of volatile organic compounds, aqueous-phase oxidation of organics, solid plastic pyrolysis, and solvent-free organic synthesis. 107 refs., 4 figs., 2 tabs.

  2. Saving the Sun for a Rainy Day (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    SciTech Connect (OSTI)

    Bullock, R. Morris; CME Staff

    2011-05-01

    'Saving the Sun for a Rainy Day' was submitted by the Center for Molecular Electrocatalysis (CME) to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. CME, an EFRC directed by R. Morris Bullock at Pacific Northwest National Laboratory is a partnership of scientists from four institutions: PNNL (lead), Pensylvania State University, University of Washington, and the University of Wyoming. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of the Center for Molecular Electrocatalysis is 'to understand, design and develop molecular electrocatalysts for solar fuel production and use.' Research topics are: catalysis (water), electrocatalysis, bio-inspired, electrical energy storage, fuel cells, hydrogen (fuel), matter by design, novel materials synthesis, and charge transport.

  3. Saving the Sun for a Rainy Day (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    ScienceCinema (OSTI)

    Bullock, R. Morris (Director, Center for Molecular Electrocatalysis); CME Staff

    2011-11-02

    'Saving the Sun for a Rainy Day' was submitted by the Center for Molecular Electrocatalysis (CME) to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. CME, an EFRC directed by R. Morris Bullock at Pacific Northwest National Laboratory is a partnership of scientists from four institutions: PNNL (lead), Pensylvania State University, University of Washington, and the University of Wyoming. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of the Center for Molecular Electrocatalysis is 'to understand, design and develop molecular electrocatalysts for solar fuel production and use.' Research topics are: catalysis (water), electrocatalysis, bio-inspired, electrical energy storage, fuel cells, hydrogen (fuel), matter by design, novel materials synthesis, and charge transport.

  4. Jonathan Link, Columbia KEK Topical Conference

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    -22, 2001 Jonathan Link, Columbia KEK Topical Conference Short Baseline Neutrino Oscillations and MiniBooNE Jonathan Link Columbia University The 5 th KEK Topical Conference - Frontiers in Flavor Physics November 20-22, 2001 November 20-22, 2001 Jonathan Link, Columbia KEK Topical Conference Outline 1. Background on Short Baseline Neutrino Oscillations * A little neutrino physics * The LSND oscillation result 2. About MiniBooNE 3. Status of MiniBooNE. Some of you may have noticed that I'll be

  5. Preface: Special Topic on Advances in Density Functional Theory

    SciTech Connect (OSTI)

    Yang, Weitao

    2014-05-14

    This Special Topic Issue on the Advances in Density Functional Theory, published as a celebration of the fifty years of density functional theory, contains a retrospective article, a perspective article, and a collection of original research articles that showcase recent theoretical advances in the field. It provides a timely discussion reflecting a cross section of our understanding, and the theoretical and computational developments, which have significant implications in broad areas of sciences and engineering.

  6. TEC Working Group Topic Groups Rail

    Broader source: Energy.gov [DOE]

    The Rail Topic Group has the responsibility to identify and discuss current issues and concerns regarding rail transportation of radioactive materials by the Department of Energy (DOE). The group’s...

  7. TEC Working Group Topic Groups Tribal

    Broader source: Energy.gov [DOE]

    The Tribal Topic Group was established in January 1998 to address government-to-government consultation between DOE and Indian Tribes affected by its transportation activities. The group focuses on...

  8. Structural Insights into the Mechanism of PEPCK Catalysis

    SciTech Connect (OSTI)

    Holyoak,T.; Sullivan, S.; Nowak, T.

    2006-01-01

    Phosphoenolpyruvate carboxykinase catalyzes the reversible decarboxylation of oxaloacetic acid with the concomitant transfer of the {gamma}-phosphate of GTP to form PEP and GDP as the first committed step of gluconeogenesis and glyceroneogenesis. The three structures of the mitochondrial isoform of PEPCK reported are complexed with Mn{sup 2+}, Mn{sup 2+}-PEP, or Mn{sup 2+}-malonate-Mn{sup 2+}GDP and provide the first observations of the structure of the mitochondrial isoform and insight into the mechanism of catalysis mediated by this enzyme. The structures show the involvement of the hyper-reactive cysteine (C307) in the coordination of the active site Mn{sup 2+}. Upon formation of the PEPCK-Mn{sup 2+}-PEP or PEPCK-Mn{sup 2+}-malonate-Mn{sup 2+}GDP complexes, C307 coordination is lost as the P-loop in which it resides adopts a different conformation. The structures suggest that stabilization of the cysteine-coordinated metal geometry holds the enzyme as a catalytically incompetent metal complex and may represent a previously unappreciated mechanism of regulation. A third conformation of the mobile P-loop in the PEPCK-Mn{sup 2+}-malonate-Mn{sup 2+}GDP complex demonstrates the participation of a previously unrecognized, conserved serine residue (S305) in mediating phosphoryl transfer. The ordering of the mobile active site lid in the PEPCK-Mn{sup 2+}-malonate-Mn{sup 2+}GDP complex yields the first observation of this structural feature and provides additional insight into the mechanism of phosphoryl transfer.

  9. The Behavior of Hydrogen Under Extreme Conditions on Ultrafast Timescales (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    SciTech Connect (OSTI)

    Mao, Ho-kwang; EFree Staff

    2011-05-01

    'The Behavior of Hydrogen Under Extreme Conditions on Ultrafast Timescales ' was submitted by the Center for Energy Frontier Research in Extreme Environments (EFree) to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. EFree is directed by Ho-kwang Mao at the Carnegie Institute of Washington and is a partnership of scientists from thirteen institutions.The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of Energy Frontier Research in Extreme Environments is 'to accelerate the discovery and creation of energy-relevant materials using extreme pressures and temperatures.' Research topics are: catalysis (CO{sub 2}, water), photocatalysis, solid state lighting, optics, thermelectric, phonons, thermal conductivity, solar electrodes, fuel cells, superconductivity, extreme environment, radiation effects, defects, spin dynamics, CO{sub 2} (capture, convert, store), greenhouse gas, hydrogen (fuel, storage), ultrafast physics, novel materials synthesis, and defect tolerant materials.

  10. The Behavior of Hydrogen Under Extreme Conditions on Ultrafast Timescales (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    ScienceCinema (OSTI)

    Mao, Ho-kwang (Director, Center for Energy Frontier Research in Extreme Environments); EFree Staff

    2011-11-02

    'The Behavior of Hydrogen Under Extreme Conditions on Ultrafast Timescales ' was submitted by the Center for Energy Frontier Research in Extreme Environments (EFree) to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. EFree is directed by Ho-kwang Mao at the Carnegie Institute of Washington and is a partnership of scientists from thirteen institutions.The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of Energy Frontier Research in Extreme Environments is 'to accelerate the discovery and creation of energy-relevant materials using extreme pressures and temperatures.' Research topics are: catalysis (CO{sub 2}, water), photocatalysis, solid state lighting, optics, thermelectric, phonons, thermal conductivity, solar electrodes, fuel cells, superconductivity, extreme environment, radiation effects, defects, spin dynamics, CO{sub 2} (capture, convert, store), greenhouse gas, hydrogen (fuel, storage), ultrafast physics, novel materials synthesis, and defect tolerant materials.

  11. Energy Efficiency and Renewable Energy Postdoctoral Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development Postdoctoral Research Awards Award Information Benefits Research Topics How to Apply For Research Mentors Annual Meetings Frequently Asked Questions Contact Us

  12. Topics: Discovering the lower limit to magnetic transport - MST - UW Plasma

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Discovering the lower limit to magnetic transport UW Madison Madison Symmetric Torus Topics: Discovering the lower limit to magnetic transport MST HomeGraduate Student InformationLinksTourControl and Auxiliary SystemsPhysics TopicsDeviceResearch MissionMST People mst logo CPLA Home Directory Publications Links Internal University of Wisconsin Physics Department Research funding includes support from: Department of Energy National Science Foundation Energy transport in conventional

  13. Topics: Uncovering the physics of magnetic self-organization and links to

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    astrophysics - MST - UW Plasma Physics Uncovering the physics of magnetic self-organization and links to astrophysics UW Madison Madison Symmetric Torus Topics: Uncovering the physics of magnetic self-organization and links to astrophysics MST HomeGraduate Student InformationLinksTourControl and Auxiliary SystemsPhysics TopicsDeviceResearch MissionMST People mst logo CPLA Home Directory Publications Links Internal University of Wisconsin Physics Department Research funding includes support

  14. Converting Homogeneous to Heterogeneous in Electrophilic Catalysis using Monodisperse Metal Nanoparticles

    SciTech Connect (OSTI)

    Witham, Cole A.; Huang, Wenyu; Tsung, Chia-Kuang; Kuhn, John N.; Somorjai, Gabor A.; Toste, F. Dean

    2009-10-15

    A continuing goal in catalysis is the transformation of processes from homogeneous to heterogeneous. To this end, nanoparticles represent a new frontier in heterogeneous catalysis, where this conversion is supplemented by the ability to obtain new or divergent reactivity and selectivity. We report a novel method for applying heterogeneous catalysts to known homogeneous catalytic reactions through the design and synthesis of electrophilic platinum nanoparticles. These nanoparticles are selectively oxidized by the hypervalent iodine species PhICl{sub 2}, and catalyze a range of {pi}-bond activation reactions previously only homogeneously catalyzed. Multiple experimental methods are utilized to unambiguously verify the heterogeneity of the catalytic process. The discovery of treatments for nanoparticles that induce the desired homogeneous catalytic activity should lead to the further development of reactions previously inaccessible in heterogeneous catalysis. Furthermore, our size and capping agent study revealed that Pt PAMAM dendrimer-capped nanoparticles demonstrate superior activity and recyclability compared to larger, polymer-capped analogues.

  15. TEC Working Group Topic Groups Rail Conference Call Summaries Rail Topic

    Office of Environmental Management (EM)

    Group | Department of Energy Summaries Rail Topic Group TEC Working Group Topic Groups Rail Conference Call Summaries Rail Topic Group Rail Topic Group PDF icon May 17, 2007 PDF icon January 16, 2007 PDF icon August 31, 2006 PDF icon July 27, 2006 PDF icon June 8, 2006 PDF icon April 20, 2006 PDF icon March 9, 2006 PDF icon January 26, 2006 PDF icon November 9, 2005 PDF icon September 15, 2005 PDF icon April 28, 2005 PDF icon March 24, 2005 PDF icon February 24, 2005 PDF icon January 27,

  16. Growth mechanism of graphene on platinum: Surface catalysis and carbon segregation

    SciTech Connect (OSTI)

    Sun, Jie Lindvall, Niclas; Yurgens, August; Nam, Youngwoo; Cole, Matthew T.; Teo, Kenneth B. K.; Woo Park, Yung

    2014-04-14

    A model of the graphene growth mechanism of chemical vapor deposition on platinum is proposed and verified by experiments. Surface catalysis and carbon segregation occur, respectively, at high and low temperatures in the process, representing the so-called balance and segregation regimes. Catalysis leads to self-limiting formation of large area monolayer graphene, whereas segregation results in multilayers, which evidently grow from below. By controlling kinetic factors, dominantly monolayer graphene whose high quality has been confirmed by quantum Hall measurement can be deposited on platinum with hydrogen-rich environment, quench cooling, tiny but continuous methane flow and about 1000?C growth temperature.

  17. Smart Grid Investment Grant Topic Areas | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Topic Areas Smart Grid Investment Grant Topic Areas A description of the topic areas for projects selected for award under the Smart Grid Investment Grant project of the American ...

  18. Webtrends Archives by Fiscal Year - Topic Landing Pages | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Topic Landing Pages Webtrends Archives by Fiscal Year - Topic Landing Pages From the EERE Web Statistics Archive: Corporate sites, Webtrends archives for the topic landing pages by fiscal year. Microsoft Office document icon Topic Landing Pages FY10 Microsoft Office document icon Topic Landing Pages FY11 PDF icon Topic Landing Pages FY12-FY13 More Documents & Publications Webtrends Archives by Fiscal Year - Commercialization Webtrends Archives by Fiscal Year - Social Media Site

  19. Quark-gluon plasma (Selected Topics)

    SciTech Connect (OSTI)

    Zakharov, V. I.

    2012-09-15

    Introductory lectures to the theory of (strongly interacting) quark-gluon plasma given at the Winter School of Physics of ITEP (Moscow, February 2010). We emphasize theoretical issues highlighted by the discovery of the low viscosity of the plasma. The topics include relativistic hydrodynamics, manifestations of chiral anomaly in hydrodynamics, superfluidity, relativistic superfluid hydrodynamics, effective stringy scalars, holographic models of Yang-Mills theories.

  20. Manufacturing Innovation Multi-Topic Workshop Report

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy (DOE) and Department of Defense (DoD) held a Manufacturing Innovation Topics Workshop on October 8 and 9, 2014. Representatives from industry, academia, DOE national laboratories, and DoD centers gathered in Fort Worth TX to hear keynote addresses and participate in workshop breakout sessions.

  1. Events & Topics in Renewable Energy & the Environment | Photosynthetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics in Renewable Energy & the Environment Events & Topics in Renewable Energy & the Environment Donald Danforth Plant Science Center April 9, 2015 - 3:15pm Donald...

  2. Events & Topics in Renewable Energy & the Environment | Photosynthetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics in Renewable Energy & the Environment Events & Topics in Renewable Energy & the Environment MIssouri Botanical Garden | Earthways Center - October 6th, 3:15 -...

  3. Events & Topics in Renewable Energy & the Environment | Photosynthetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Events & Topics in Renewable Energy & the Environment Events & Topics in Renewable Energy & the Environment Tyson Living Learning Center tour November 18, 2014 - 4:00pm Tyson...

  4. List of Topics for Interagency Performance & Risk Assessment...

    Energy Savers [EERE]

    List of Topics for Interagency Performance & Risk Assessment Community of Practice (P&RA CoP) Discussion List of Topics for Interagency Performance & Risk Assessment Community of ...

  5. Public Perception of 13 Different Energy Topics analyzed in new...

    Open Energy Info (EERE)

    and unfavorability energy topics such as transportation, renewable technology, nuclear, clean coal, and smart grid topics. Some of the highlights of the study are as...

  6. Microsoft Word - 20111012_RAP Dec_Mtg_Topics.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    12 Potential December RAP Committee Meeting Agenda Topics TopicPurpose (incl. any framing questions) 2012 Priority? Issue Managers (* denotes lead) Agency Lead (s) Time...

  7. TEC Working Group Topic Groups Routing Key Documents | Department...

    Office of Environmental Management (EM)

    Key Documents TEC Working Group Topic Groups Routing Key Documents KEY DOCUMENTS PDF icon Proposed Task Plan - Routing Topic Group More Documents & Publications TEC Working Group...

  8. TEC Working Group Topic Groups Routing Meeting Summaries | Department...

    Office of Environmental Management (EM)

    Routing Meeting Summaries TEC Working Group Topic Groups Routing Meeting Summaries MEETING SUMMARIES PDF icon Atlanta TEC Meeting, Routing Topic Group Summary More Documents &...

  9. TEC Working Group Topic Groups Rail Conference Call Summaries...

    Office of Environmental Management (EM)

    Rail Conference Call Summaries TEC Working Group Topic Groups Rail Conference Call Summaries CONFERENCE CALL SUMMARIES Rail Topic Group Inspections Subgroup Planning Subgroup...

  10. TEC Working Group Topic Groups Archives Protocols Meeting Summaries...

    Office of Environmental Management (EM)

    Protocols Meeting Summaries TEC Working Group Topic Groups Archives Protocols Meeting Summaries Meeting Summaries PDF icon Philadelphia TEC Meeting, Protocols Topic Group Summary -...

  11. TEC Working Group Topic Groups Rail Meeting Summaries | Department...

    Office of Environmental Management (EM)

    TEC Working Group Topic Groups Rail Meeting Summaries MEETING SUMMARIES PDF icon Kansas City TEC Meeting, Rail Topic Group Summary - July 25, 2007 PDF icon Atlanta TEC...

  12. Regulatory cross-cutting topics for fuel cycle facilities.

    SciTech Connect (OSTI)

    Denman, Matthew R.; Brown, Jason; Goldmann, Andrew Scott; Louie, David

    2013-10-01

    This report overviews crosscutting regulatory topics for nuclear fuel cycle facilities for use in the Fuel Cycle Research&Development Nuclear Fuel Cycle Evaluation and Screening study. In particular, the regulatory infrastructure and analysis capability is assessed for the following topical areas:Fire Regulations (i.e., how applicable are current Nuclear Regulatory Commission (NRC) and/or International Atomic Energy Agency (IAEA) fire regulations to advance fuel cycle facilities)Consequence Assessment (i.e., how applicable are current radionuclide transportation tools to support risk-informed regulations and Level 2 and/or 3 PRA) While not addressed in detail, the following regulatory topic is also discussed:Integrated Security, Safeguard and Safety Requirement (i.e., how applicable are current Nuclear Regulatory Commission (NRC) regulations to future fuel cycle facilities which will likely be required to balance the sometimes conflicting Material Accountability, Security, and Safety requirements.)

  13. VFP Research Projects | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Projects Ames Lab provides hands-on research opportunities in materials science in the following research areas: Mathematical modeling of the aptamers and its effect on small molecule transport into the cell (Marit Nilsen-Hamilton) Synthesis and Characterization of a Hafnium Derivative of the MOF UiO-66-NH2 and its use in Biomass Related Catalysis (Wenyu Huang) Reliable Nanomanufacturing of Ge-Sn Alloys for Solar Energy Conversion (Javier Vela) Past Programs

  14. ISHHC XIII International Symposium on the Relations betweenHomogeneous and Heterogeneous Catalysis

    SciTech Connect (OSTI)

    Somorjai , G.A.

    2007-06-11

    The International Symposium on Relations between Homogeneous and Heterogeneous Catalysis (ISHHC) has a long and distinguished history. Since 1974, in Brussels, this event has been held in Lyon, France (1977), Groeningen, The Netherlands (1981); Asilomar, California (1983); Novosibirsk, Russia (1986); Pisa, Italy (1989); Tokyo, Japan (1992); Balatonfuered, Hungary (1995); Southampton, United Kingdom (1999); Lyon, France (2001); Evanston, Illinois (2001) and Florence, Italy (2005). The aim of this international conference in Berkeley is to bring together practitioners in the three fields of catalysis, heterogeneous, homogeneous and enzyme, which utilize mostly nanosize particles. Recent advances in instrumentation, synthesis and reaction studies permit the nanoscale characterization of the catalyst systems, often for the same reaction, under similar experimental conditions. It is hoped that this circumstance will permit the development of correlations of these three different fields of catalysis on the molecular level. To further this goal we aim to uncover and focus on common concepts that emerge from nanoscale studies of structures and dynamics of the three types of catalysts. Another area of focus that will be addressed is the impact on and correlation of nanosciences with catalysis. There is information on the electronic and atomic structures of nanoparticles and their dynamics that should have importance in catalyst design and catalytic activity and selectivity.

  15. Solvation and Acid Strength Effects on Catalysis by Faujasite Zeolites

    SciTech Connect (OSTI)

    Gounder, Rajamani P.; Jones, Andrew J.; Carr, Robert T.; Iglesia, Enrique

    2012-02-01

    Kinetic, spectroscopic, and chemical titration data indicate that differences in monomolecular isobutane cracking and dehydrogenation and methanol dehydration turnover rates (per H+) among FAU zeolites treated thermally with steam (H-USY) and then chemically with ammonium hexafluorosilicate (CDHUSY) predominantly reflect differences in the size and solvating properties of their supercage voids rather than differences in acid strength. The number of protons on a given sample was measured consistently by titrations with Na+, with CH3 groups via reactions of dimethyl ether, and with 2,6-di-tert-butylpyridine during methanol dehydration catalysis; these titration values were also supported by commensurate changes in acidic OH infrared band areas upon exposure to titrant molecules. The number of protons, taken as the average of the three titration methods, was significantly smaller than the number of framework Al atoms (Alf) obtained from X-ray diffraction and 27Al magic angle spinning nuclear magnetic resonance spectroscopy on H-USY (0.35 H+/Alf) and CD-HUSY (0.69 H+/Alf). These data demonstrate that the ubiquitous use of Alf sites as structural proxies for active H+ sites in zeolites can be imprecise, apparently because distorted Al structures that are not associated with acidic protons are sometimes detected as Alf sites. Monomolecular isobutane cracking and dehydrogenation rate constants, normalized non-rigorously by the number of Alf species, decreased with increasing Na+ content on both H-USY and CD-HUSY samples and became undetectable at sub-stoichiometric exchange levels (0.32 and 0.72 Na+/Alf ratios, respectively), an unexpected finding attributed incorrectly in previous studies to the presence of minority ‘‘super-acidic’’ sites. These rate constants, when normalized rigorously by the number of residual H+ sites were independent of Na+ content on both H-USY and CD-HUSY samples, reflecting the stoichiometric replacement of protons that are uniform in reactivity by Na+ cations. Monomolecular isobutane cracking and dehydrogenation rate constants (per H+; 763 K), however, were higher on H-USY than CD-HUSY (by a factor of 1.4). Equilibrium constants for the formation of protonated methanol dimers via adsorption of gaseous methanol onto adsorbed methanol monomers, determined from kinetic studies of methanol dehydration to dimethyl ether (433 K), were also higher on H-USY than CD-HUSY (by a factor of 2.1). These larger constants predominantly reflect stronger dispersive interactions in H-USY, consistent with its smaller supercage voids that result from the occlusion of void space by extraframework Al (Alex) residues. These findings appear to clarify enduring controversies about the mechanistic interpretation of the effects of Na+ and Alex species on the catalytic reactivity of FAU zeolites. They also illustrate the need to normalize rates by the number of active sites instead of more convenient but less accurate structural proxies for such sites.

  16. More About "Topic A" and "Topic B" Awards | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More About "Topic A" and "Topic B" Awards More About "Topic A" and "Topic B" Awards The awards pursuant to the Department of Energy's Interconnection-wide Transmission Planning Initiative cover two broad topics. "Topic A" covers Interconnection-Level Analysis and Planning. "Topic B" covers Cooperation Among States on Electric Resource Planning and Priorities, where the states will develop input to the Topic A analyses and perform other

  17. Topic A Awardee: Eastern Interconnection Planning Collaborative |

    Energy Savers [EERE]

    Department of Energy Eastern Interconnection Planning Collaborative Topic A Awardee: Eastern Interconnection Planning Collaborative Eastern Interconnection Planning Collaborative The Eastern Interconnection Planning Collaborative (EIPC) was initiated by a coalition of regional Planning Authorities. These Planning Authorities are entities listed on the NERC compliance registry as Planning Authorities and represent the entire Eastern Interconnection. The EIPC was founded to be a broad-based,

  18. Renewable Energy Project Development: Advanced Concept Topics

    Energy Savers [EERE]

    Concept Topics An Introduction to Risk, Tribal Roles, and Support Policies in the Renewable Energy Project Development Process Course Outline What we will cover...  About the DOE Office of Indian Energy Education Initiative  Concepts and Policies for Understanding Renewable Energy Projects on Tribal Lands - Risk and Uncertainty - Tribal Project Roles - Policies and Incentives  Additional Information and Resources 2 Introduction The U.S. Department of Energy (DOE) Office of Indian Energy

  19. Renewable Energy Project Development: Advanced Process Topics

    Energy Savers [EERE]

    Process Topics Understanding Energy Markets, Project Scale Decision Factors, Procurement Options, and the Role of the Project Team Course Outline What we will cover...  About the DOE Office of Indian Energy Education Initiative  Processes for Developing Renewable Energy Projects on Tribal Lands - Understanding the Energy Market and Project Scale - Project Scale and Ownership Options - Procurement Process - Project Team  Additional Information and Resources 2 Introduction The U.S.

  20. TEC/WG Tribal Topic Group

    Office of Environmental Management (EM)

    Meeting September 22, 2005 - Pueblo, CO Group Chair: Jay Jones (DOE/OCRWM) Tribal Topic Group Members Present: Richard Arnold (Southern Paiute/CGTO), Vicki Best (Bechtel SAIC-YMP), Kevin Blackwell (DOT/FRA), Sandra Covi (UPRR), Barbara Durham (Timbisha Shoshone Tribe), Greg Fasano (Bechtel SAIC-YMP), Elizabeth Helvey (BSC), Angela Hill (DOE/OCRWM), Judith Holm (DOE/OCRWM), Marsha Keister (INL), Dan King (Oneida Nation), Gary Lanthrum (DOE/OCRWM), Corinne Macaluso (DOE/OCRWM), Calvin Meyers

  1. Pre-Competitive Catalysis Research: Fundamental Sulfation/Desulfation Studies of Lean NOx Traps

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  2. The Catalysis Center for Energy Innovation is an Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    February 17, 2016 12:30 PM  322 ISE Lab Susannah Scott Mellichamp Professor of Sustainable Catalytic Processing Department of Chemical Engineering Department of Chemistry & Biochemistry University of California, Santa Barbara Biography: Scott received her B.Sc. in Chemistry from the University of Alberta (Canada) in 1987, and her Ph.D. in Inorganic Chemistry from Iowa State University in 1991, where she worked with J. Espenson and A. Bakac on the activation of O2 and organic oxidation

  3. This research was supported as part of the Catalysis Center for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of new materials leading to more energy efficient and benign chemical transformations. A critical reaction in utilization of the most abundant biomass ingredient, cellulose,...

  4. This research was supported as part of the Catalysis Center for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    wood, agricultural wastes, and energy crops) directly into aromatics and olefins with zeolite catalysts in a fluidized bed reactor in a process called catalytic fast pyrolysis. ...

  5. Preface: Thin Solid Films Topical Special Issue on ZnO Related Transparent

    Office of Scientific and Technical Information (OSTI)

    Conductive Oxides (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Preface: Thin Solid Films Topical Special Issue on ZnO Related Transparent Conductive Oxides Citation Details In-Document Search Title: Preface: Thin Solid Films Topical Special Issue on ZnO Related Transparent Conductive Oxides World-wide research activities on ZnO and related transparent conductive oxides (TCO) in thin film, nanostructured, and multilayered forms are driven by the vast

  6. Thomas Jaramillo - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    thomas jaramillo Principal Investigator and Research Thrust Coordinator Email: jaramillo@stanford.edu Dr. Jaramillo's research interests center around: energy and catalysis, engineering surface and bulk materials chemistry in relation to energy conversion reactions-production, utilization, and storage. General themes include nano-scale effects in heterogeneous catalysis and electro-catalysis. Topics include water electrolysis, fuel cell electrocatalysis (oxygen reduction, fuel oxidation,

  7. TEC Working Group Topic Groups | Department of Energy

    Energy Savers [EERE]

    Topic Groups TEC Working Group Topic Groups TEC Topic Groups were formed in 1991 following an evaluation of the TEC program. Interested members, DOE and other federal agency staff meet to examine specific issues related to radioactive materials transportation. TEC Topic Groups enable a small number of participants to focus intensively on key issues at a level of detail that is unattainable during the TEC semiannual meetings due to time and group size constraints. Topic Groups meet individually

  8. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Broader source: Energy.gov (indexed) [DOE]

    Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER ... PDF icon deer07rappe.pdf More Documents & Publications Low-Temperature HydrocarbonCO ...

  9. ALS X-Rays Shine a New Light on Catalysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    vice versa. At the ALS, researchers were able to directly observe redox processes in thin-film iron and cobalt perovskite oxide electrocatalysts using surface-sensitive, x-ray...

  10. The Catalysis Center for Energy Innovation is an Energy Frontier...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    State faculty, he has received a number of awards, including a DARPA Young Faculty Award, ... Research in his laboratory is currently sponsored by NSF, DOE-BES, DARPA, AFOSR, AFRL, ...

  11. High-Potential Electrocatalytic O2 Reduction with Nitroxyl / NOx Mediators: Implications for Fuel Cells and Aerobic Oxidation Catalysis

    SciTech Connect (OSTI)

    Gerken, James B.; Stahl, Shannon S.

    2015-07-15

    Efficient reduction of O2 to water is a central challenge in energy conversion and aerobic oxidation catalysis. In the present study, we investigate the electrochemical reduction of O2 with soluble organic nitroxyl and nitrogen oxide (NOx) mediators. When used alone, neither organic nitroxyls, such as TEMPO (2,2,6,6-tetramethyl-1-piperidinyl-N-oxyl), nor NOx species, such as sodium nitrite, are effective mediators of electrochemical O2 reduction. The combination of nitroxyl/NOx species, however, mediates sustained O2 reduction at electrochemical potentials of 0.19–0.33 V (vs. Fc/Fc+) in acetonitrile containing trifluoroacetic acid. Mechanistic analysis of the coupled redox reactions supports a process in which the nitrogen oxide catalyst drives aerobic oxidation of a nitroxyl mediator to an oxoammonium species, which then is reduced back to the nitroxyl at the cathode. The electrolysis potential is dictated by the oxoammonium/nitroxyl reduction potential. The high potentials observed with this ORR system benefit from the mechanism-based specificity for four-electron reduction of oxygen to water mediated by NOx species, together with kinetically efficient reduction of oxidized NOx species by TEMPO and other organic nitroxyls. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center, funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences.

  12. University of Delaware | Catalysis Center for Energy Innovation | Furans

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Thrust Sugars to Furans Converting sugars to high-value intermediates. CCEI introduced an iconic technology for the isomerization of aldoses to ketoses production via Sn-beta zeolite and other related heterogeneous and homogeneous Lewis acid catalysts in water and demonstrated that this technology is broadly applicable to the conversion of C6 and C5 sugars. Researchers discovered the first single-pot process that combines heterogeneous Lewis acidity with Bronsted acidity to carry

  13. Preface to Special Topic: Marine Renewable Energy

    SciTech Connect (OSTI)

    Pinto, F. T.; Iglesias, G.; Santos, P. R.; Deng, Zhiqun

    2015-12-30

    Marine renewable energy (MRE) is generates from waves, currents, tides, and thermal resources in the ocean. MRE has been identified as a potential commercial-scale source of renewable energy. This special topic presents a compilation of works selected from the 3rd IAHR Europe Congress, held in Porto, Portugal, in 2014. It covers different subjects relevant to MRE, including resource assessment, marine energy sector policies, energy source comparisons based on levelized cost, proof-of-concept and new-technology development for wave and tidal energy exploitation, and assessment of possible inference between wave energy converters (WEC).

  14. TEC/WG Tribal Topic Group

    Office of Environmental Management (EM)

    April 4, 2005 - Phoenix, AZ Group Chair: Jay Jones (DOE/OCRWM) Tribal Topic Group Members Present: Nancy Bennett (UNM/ATRI), Kevin Blackwell (DOT/FRA), Kristen Ellis (DOE/CI), Ed Gonzales (ELG), Elizabeth Helvey (BSC), Jeff Hepting (Pueblo of Acoma), Robert Holden (NCAI), Judith Holm (DOE/OCRWM), Dan King (Oneida Nation), Gary Lanthrum (DOE/OCRWM), Bob Lupton (DOE/ORD/IR), Corinne Macaluso (DOE/OCRWM), Ellen Ott (DOE/GC), Jennifer Patric (BAH), Stanley Paytiamo (Pueblo of Acoma), Wilda Portner

  15. Theoretical/Computational Tools for Energy-Relevant Catalysis | The Ames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Theoretical/Computational Tools for Energy-Relevant Catalysis FWP/Project Description: Project Leader(s): James Evans, Mark Gordon Principal Investigators: James Evans, Mark Gordon This project will develop new strategies for and integrated combinations of electronic structure analysis and statistical mechanical, coarse-grained, and multi-scale modeling approaches to treat energy-relevant heterogeneous catalytic systems. Currently, there is a lack of effective molecular-level

  16. Kokes Awards for the 23rd North American Catalysis Society Meeting

    SciTech Connect (OSTI)

    Jacobs, Gary

    2014-01-31

    The Tri-State Catalysis Society awarded 107 Kokes Travel Awards. The program was very successful and to date this was the most Kokes Travel Awards ever awarded at a North American Catalysis Society Meeting. It provided students who merited an award the opportunity to attend the meeting, present a paper in the form of either an oral presentation or a poster presentation, and to serve the North American Catalysis Society by participating in the organization of the meeting. Students worked very hard during the week of the meeting to make it a success. Financial support for the Kokes awards was provided by DOE, NSF, NACS, as well as the Tri-State Catalysis Society, the latter through fund raising activities, and other donations. AT the meeting, each student received over $1050 in kind to offset the costs of registration fees ($260), hotel accommodations ($295.7), transportation ($400 travel allowance), as well as T-shirts ($20), and banquet tickets ($95 provided by donations from society members). In addition, for the first time, students received certificates that were signed by the President of NACS, Professor Enrique Iglesia, and by the Kokes Awards Chair, Gary Jacobs (see last page). A list of meeting co-chairs (i.e., Uschi M. Graham, Umit S. Ozkan, and Madan Bhassin) and the honorary chair (Burtron H. Davis) was also included on the certificate, along with the name of the recipient. The awardees were chosen on a merit-based guideline which also included the requirements of having a presentation accepted at the meeting and being a student at a North American University. The Richard J. Kokes Student Travel Award Committee (Gary Jacobs, Rodney Andrews, and Peter Smirniotis) with help from the Organizing Committee were able to secure money from four sources as detailed in Table 1. As detailed by our Treasurer, Dr. Helge Toufar of Clariant, the total amount spent was $105,000.

  17. Catalysis by Design: Bridging the Gap Between Theory and Experiments at

    Broader source: Energy.gov (indexed) [DOE]

    Nanoscale Level | Department of Energy Studies on a simple platinum-alumina system constitute a first step toward a "catalyst by design" approach. PDF icon deer08_narula.pdf More Documents & Publications Catalysis by Design: Bridging the Gap between Theory and Experiments Catalyst by Design - Theoretical, Nanostructural, and Experimental Studies of Oxidation Catalyst for Diesel Engine Emission Treatment

  18. Research Mission - Plasma Couette Experiment - Cary Forest Group...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Mission UW Madison Plasma Couette Experiment Research Mission PCX HomeResearch MissionPhysics TopicsDeviceDiagnosticsContacts LinksPCX People CPLA Home Directory...

  19. UNLV Center for Energy Research CER | Open Energy Information

    Open Energy Info (EERE)

    Center for Energy Research is a focus area for research, information exchange, and education in energy topics. References: UNLV Center for Energy Research (CER)1 This article...

  20. NMR Computational Studies of Solid Acidity/Fundamental Studies of Catalysis by Solid Acids

    SciTech Connect (OSTI)

    James F. Haw

    2008-06-28

    This project focused on catalysis by zeolites and the synergy of spectroscopic characterization and theoretical modeling. In collaboration with the Waroquier group in Belgium we used state-of-the-art quantum chemical simulations on a supramolecular model of both the HZSM-5 zeolite and the co-catalytic hydrocarbon pool species and calculated a full catalytic cycle (including all rate constants) for methanol-to-olefin (MTO) catalysis involving a hydrocarbon pool species. This work not only represents the most robust computational analysis of a successful MTO route to date, but it also succeeds in tying together the many experimental clues. That work was featured on the cover of Angewandte Chemie. More recently we elucidated several unsuspected roles for formaldehyde in methanol to olefin catalysis. Formaldehyde proves to be a key species responsible for both the growth of the catalytically active hydrocarbon pool and its inevitable aging into deactivated polycyclic aromatic species. The apparent inevitability of formaldehyde formation at high temperatures, in particular in contact with active metal or metal oxide surfaces, may put some fundamental limitations on the economic potential of conversion of methanol to olefins.

  1. Meet CMI Researcher Theresa Windus | Critical Materials Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Theresa Windus Image of Theresa Windus, researcher at Critical Materials Institute CMI researcher Theresa Windus joined Iowa State University as a full professor and an associate researcher with DOE's Ames Laboratory in August of 2006. She develops new methods and algorithms for high performance computational chemistry as well as applying those techniques to both basic and applied research. Her current interests are rare earth and heavy element chemistry, catalysis, aerosol formation, cellulose

  2. University of Delaware | Catalysis Center for Energy Innovation | Pyrolysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Thrust Pyrolysis Thin-film pyrolysis sample. The next generation of biofuels will be produced by high-temperature (>1000 °F) pyrolysis or gasification of lignocellulosic biomass. At these temperatures, large biopolymers (such as cellulose) thermally fracture to smaller fragments, which can evaporate and be collected as bio-oil. Subsequent upgrading of bio-oil then produces gasoline, diesel and jet fuel. Thus, the future of biofuels depends on the production of high-quality,

  3. Catalysis by Design: Bridging the Gap between Theory and Experiments |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_narula.pdf More Documents & Publications Catalysts via First Principles Catalysts via First Principles

  4. Electron Microscopy Catalysis Projects: Success Stories from the High

    Broader source: Energy.gov (indexed) [DOE]

    The U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) Fuel Cell Technologies Office (FCTO) held the Electrolytic Hydrogen Production Workshop on February 27-28, 2014, at The National Renewable Energy Laboratory (NREL) in Golden, Colorado, to discuss and share information on the research, development, and demonstration (RD&D) needs for enabling low-cost, effective hydrogen production from all types of water electrolysis systems, both centralized and

  5. TEC Working Group Topic Groups Archives Communications Meeting Summaries |

    Office of Environmental Management (EM)

    Department of Energy Archives Communications Meeting Summaries TEC Working Group Topic Groups Archives Communications Meeting Summaries Meeting Summaries PDF icon Milwaukee TEC Meeting, Communications Topic Group Summary - July 1998 PDF icon Inaugural Group Meeting - April 1998 More Documents & Publications TEC Working Group Topic Groups Archives Communications Conference Call Summaries TEC Meeting Summaries - January 1997 TEC Working Group Topic Groups Tribal Conference Call

  6. TEC Working Group Topic Groups Rail Conference Call Summaries Inspections

    Office of Environmental Management (EM)

    Subgroup | Department of Energy Summaries Inspections Subgroup TEC Working Group Topic Groups Rail Conference Call Summaries Inspections Subgroup Inspections Subgroup PDF icon April 6, 2006 PDF icon February 23, 2006 Draft PDF icon January 24, 2006 More Documents & Publications TEC Working Group Topic Groups Rail Conference Call Summaries Planning Subgroup TEC Working Group Topic Groups Rail Conference Call Summaries Tracking Subgroup TEC Working Group Topic Groups Rail Conference Call

  7. TEC Working Group Topic Groups Rail Key Documents Radiation Monitoring

    Office of Environmental Management (EM)

    Subgroup | Department of Energy Radiation Monitoring Subgroup TEC Working Group Topic Groups Rail Key Documents Radiation Monitoring Subgroup Radiation Monitoring Subgroup PDF icon Draft Work Plan - February 4, 2008 More Documents & Publications TEC Working Group Topic Groups Rail Meeting Summaries TEC Working Group Topic Groups Rail Conference Call Summaries Radiation Monitoring Subgroup TEC Working Group Topic Groups Rail Key Documents Intermodal Subgroup

  8. SBIR/STTR FY16 Phase I Release 2 Topics Announced—Includes Hydrogen Delivery and Two Technology Transfer Opportunities

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy has announced the 2016 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase I Release 2 Topics, including magnetocaloric materials development for hydrogen delivery and two technology transfer opportunities.

  9. SBIR/STTR FY16 Phase 1 Release 2 Topics AnnouncedIncludes Hydrogen Delivery and Two Technology Transfer Opportunities

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy has announced the 2016 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase I Release 2 Topics, including magnetocaloric materials development for hydrogen delivery and two technology transfer opportunities.

  10. TEC Working Group Topic Groups Archives Protocols Conference Call Summaries

    Office of Environmental Management (EM)

    | Department of Energy Conference Call Summaries TEC Working Group Topic Groups Archives Protocols Conference Call Summaries Conference Call Summaries PDF icon May 13, 1999 PDF icon April 8, 1999 PDF icon March 1, 1999 More Documents & Publications TEC Working Group Topic Groups Archives Protocols Meeting Summaries TEC Working Group Topic Groups Archives Communications Conference Call Summaries

  11. University of Delaware | Catalysis Center for Energy Innovation | Aromatics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Thrust Green Aromatics Transition state for the Diels-Alder reaction of 2,5-dimethylfuran and ethylene in zeolite LiY Most polymers and plastics require six-carbon ring structures. Sugars (such as glucose and xylose) derived from cellulose and hemicellulose are converted into five-atom ring structures called furans, which consist of four carbons and one oxygen. In order to make the right carbon atom ring, CCEI has introduced technology for the production of aromatics from furans by

  12. University of Delaware | Catalysis Center for Energy Innovation | Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cells Research Thrust Fuel Cells Schematic for a large-scale DCFC system based on molten Sb anodes. CCEI's technology is based on electrolytes that are ceramic oxygen-ion conductors, such as cubic zirconia. It uses molten antimony (Sb) as the fuel electrode. Inside the fuel cell, Sb is oxidized at the electrolyte interface to Sb2O3, producing electrical power. The Sb2O3 is in turn reduced by carbon-based fuels to regenerate the Sb, allowing the cycle to start again

  13. Tyson Research Center Tour | Fall 2014 | Photosynthetic Antenna Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center | Fall 2014 Tyson Research Center Tour | Fall 2014 Our Events & Topics in Bioenergy & the Environment tours takes us to the Tyson Research Center. Visit their website here: http://www.tyson.wustl.edu/

  14. Light Matters (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    ScienceCinema (OSTI)

    Atwater, Harry (Director, Light-Material Interactions in Energy Conversion (LMI), California Institute of Technology); LMI Staff

    2011-11-02

    'Light Matters' was submitted by the Center for Light-Material Interactions in Energy Conversion (LMI) to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. This video was selected as one of five winners by a distinguished panel of judges for its 'striking photography and visual impact'. LMI, an EFRC directed by Harry Atwater at the California Institute of Technology is a partnership of scientists from three institutions: CalTech (lead), University of California, Berkeley, and the University of Illinois at Urbana-Champaign. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of Light-Material Interactions in Energy Conversion is 'to tailor the morphology, complex dielectric structure, and electronic properties of matter to sculpt the flow of sunlight, enabling light conversion to electrical and chemical energy with unprecedented efficiency.' Research topics are: catalysis (imines hydrocarbons), solar photovoltaic, solar fuels, photonic, solid state lighting, metamaterial, optics, phonons, thermal conductivity, solar electrodes, photsynthesis, CO{sub 2} (convert), greenhouse gas, and matter by design.

  15. Light Matters (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    SciTech Connect (OSTI)

    Atwater, Harry , California Institute of Technology); LMI Staff

    2011-05-01

    'Light Matters' was submitted by the Center for Light-Material Interactions in Energy Conversion (LMI) to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. This video was selected as one of five winners by a distinguished panel of judges for its 'striking photography and visual impact'. LMI, an EFRC directed by Harry Atwater at the California Institute of Technology is a partnership of scientists from three institutions: CalTech (lead), University of California, Berkeley, and the University of Illinois at Urbana-Champaign. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of Light-Material Interactions in Energy Conversion is 'to tailor the morphology, complex dielectric structure, and electronic properties of matter to sculpt the flow of sunlight, enabling light conversion to electrical and chemical energy with unprecedented efficiency.' Research topics are: catalysis (imines hydrocarbons), solar photovoltaic, solar fuels, photonic, solid state lighting, metamaterial, optics, phonons, thermal conductivity, solar electrodes, photsynthesis, CO{sub 2} (convert), greenhouse gas, and matter by design.

  16. Search tool plug-in: imploements latent topic feedback

    Energy Science and Technology Software Center (OSTI)

    2011-09-23

    IRIS is a search tool plug-in that is used to implement latent topic feedback for enhancing text navigation. It accepts a list of returned documents from an information retrieval wywtem that is generated from keyword search queries. Data is pulled directly from a topic information database and processed by IRIS to determine the most prominent and relevant topics, along with topic-ngrams, associated with the list of returned documents. User selected topics are then used tomore » expand the query and presumabley refine the search results.« less

  17. Application of lidar to current atmospheric topics

    SciTech Connect (OSTI)

    Sedlacek, A.J. III

    1996-12-31

    The goal of the conference was to address the various applications of lidar to topics of interest in the atmospheric community. Specifically, with the development of frequency-agile, all solid state laser systems, high-quantum-efficiency detectors, increased computational power along with new and more powerful algorithms, and novel detection schemes, the application of lidar to both old and new problems has expanded. This expansion is evidenced by the contributions to the proceedings, which demonstrate the progress made on a variety of atmospheric remote sensing problems, both theoretically and experimentally. The first session focused on aerosol, ozone, and temperature profile measurements from ground-based units. The second session, Chemical Detection, provided applications of lidar to the detection of atmospheric pollutants. Papers in the third session, Wind and Turbulence Measurements, described the Multi-center Airborne Coherent Atmospheric Wind Sensor (MACAWS) experiments, Doppler techniques for ground-based wind profiling and mesopause radial wind and temperature measurements utilizing a frequency-agile lidar system. The papers in the last two sessions, Recent Advanced in Lidar Technology and Techniques and Advanced Operational Lidars, provided insights into novel approaches, materials, and techniques that would be of value to the lidar community. Papers have been processed separately for inclusion on the data base.

  18. SBIR/STTR Release 2 Topics Announced—Includes Hydrogen and Fuel Cells

    Broader source: Energy.gov [DOE]

    The 2015 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase I Release 2 topics include fuel cell-battery electric hybrid trucks and in-line quality control devices for polymer electrolyte membrane (PEM) fuel cells.

  19. Energy Department Announces New Grant Topics to Help Small Businesses Develop Clean Energy Technologies

    Broader source: Energy.gov [DOE]

    The Energy Department's Office of Energy Efficiency and Renewable Energy (EERE) today announced nine topics and 26 new subtopics under its Small Business Innovation Research (SBIR) and Technology Transfer (STTR) programs that will help small businesses develop and deliver market-driven clean energy technologies.

  20. Thomas Moore | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thomas Moore Thomas Moore Thomas Moore Thomas Moore Scientific Advisory Committee Chair E-mail: tom.moore@asu.edu Phone: 480.965.3308 Fax: 480.965.2747 Website: Arizona State University Chair - Scientific Advisory Committee Dr. Moore's research interests are the design and assembly of bio-designed constructs for solar energy conversion, catalysis and signal transduction. His work includes the incorporation of artificial antennas and reaction centers into model biological membranes to make solar

  1. Electric-field enhanced performance in catalysis and solid-state devices involving gases

    DOE Patents [OSTI]

    Blackburn, Bryan M.; Wachsman, Eric D.; Van Assche, IV, Frederick Martin

    2015-05-19

    Electrode configurations for electric-field enhanced performance in catalysis and solid-state devices involving gases are provided. According to an embodiment, electric-field electrodes can be incorporated in devices such as gas sensors and fuel cells to shape an electric field provided with respect to sensing electrodes for the gas sensors and surfaces of the fuel cells. The shaped electric fields can alter surface dynamics, system thermodynamics, reaction kinetics, and adsorption/desorption processes. In one embodiment, ring-shaped electric-field electrodes can be provided around sensing electrodes of a planar gas sensor.

  2. Topic 5: Time-Dependent Behavior

    SciTech Connect (OSTI)

    Pfeiffer, P.A. [Argonne National Lab., IL (United States); Tanabe, Tada-aki [Nagoya Univ. (Japan). Dept. of Civil Engineering

    1991-12-31

    This chapter is a report of the material presented at the International Workshop on Finite Element Analysis of Reinforced Concrete, Session 4 -- Time Dependent Behavior, held at Columbia University, New York on June 3--6, 1991. Dr. P.A. Pfeiffer presented recent developments in time-dependent behavior of concrete and Professor T. Tanabe presented a review of research in Japan on time-dependent behavior of concrete. The chapter discusses the recent research of time-dependent behavior of concrete in the past few years in both the USA-European and Japanese communities. The author appreciates the valuable information provided by Zdenek P. Bazant in preparing the USA-European Research section.

  3. Interconnection-Wide Transmission Planning Initiative: Topic A,

    Energy Savers [EERE]

    Interconnection-Level Analysis and Planning | Department of Energy A, Interconnection-Level Analysis and Planning Interconnection-Wide Transmission Planning Initiative: Topic A, Interconnection-Level Analysis and Planning A description of the requirements for Topic A for all Interconnections under the Interconnection-Wide Transmission Planning Initiative, part of the American Recovery and Reinvestment Act. PDF icon Interconnection-Wide Transmission Planning Initiative: Topic A,

  4. 2013 February POTENTIAL COMMITTEE MEETING TOPICS HAB Committee: RAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Page 1 of 3 2013 February POTENTIAL COMMITTEE MEETING TOPICS HAB Committee: RAP Committee meeting: Tuesday, February 12 from 9 a.m. - 4 p.m. Agenda Topic When is HAB input needed? Issue Managers (* = lead) Agency Lead(s) Time to Allocate (minutes) Title: Framing Discussion: Central Plateau Groundwater and Vadose Zone Modeling (JOINT TOPIC W/ TWC) 2013 Priority: Groundwater Modeling Purpose: To hear a report-out from issue managers on their work regarding Central Plateau groundwater and vadose

  5. TEC Working Group Topic Groups Archives Communications Conference Call

    Office of Environmental Management (EM)

    Summaries | Department of Energy Communications Conference Call Summaries TEC Working Group Topic Groups Archives Communications Conference Call Summaries Conference Call Summaries PDF icon Conference Call Summary April 2000 PDF icon Conference Call Summary February 1999 PDF icon Conference Call Summary November 1998 More Documents & Publications TEC Working Group Topic Groups Archives Communications Meeting Summaries TEC Working Group Topic Groups Tribal Conference Call Summaries TEC

  6. TEC Working Group Topic Groups Archives Training - Medical Training |

    Office of Environmental Management (EM)

    Department of Energy Training - Medical Training TEC Working Group Topic Groups Archives Training - Medical Training The TEC Training and Medical Training Issues Topic Group was formed to address the training issues for emergency responders in the event of a radioactive material transportation incident. The Topic Group first met in 1996 to assist DOE in developing an approach to address radiological emergency response training needs and to avoid redundancy of existing training materials. The

  7. TRIBAL ISSUES TOPIC GROUP MEETING SUMMARY Milwaukee, WI July 1998

    Office of Environmental Management (EM)

    Milwaukee, WI July 1998 The Topic Group is developing a process to identify appropriate Topic Group membership, and will be working on a protocol for identifying and inviting individual tribes to participate he group identified five actions: (1) catalogue tribal transportation issues; (2) identify a level of tribal awareness of DOE transportation issues; (3) examine funding and tribal support; (4) develop a process for Tribal Topic Group membership; and (5) review the best channels to

  8. Focus Group Meeting (Topical Wrap-Up) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wrap-Up) Focus Group Meeting (Topical Wrap-Up) Meeting Date: December 4, 2008 Meeting ... More Documents & Publications Focus Group Meeting (Activities Status) Focus Group Meeting ...

  9. Focus Group Meeting (Topical Meeting) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Enforcement Inspection Schedule More Documents & Publications Focus Group Meeting (Activities Status) Focus Group Meeting (Activities Status) Focus Group Meeting (Topical Wrap-Up)

  10. TEC Working Group Topic Groups Rail Key Documents Radiation Monitoring...

    Office of Environmental Management (EM)

    Radiation Monitoring Subgroup TEC Working Group Topic Groups Rail Key Documents Radiation Monitoring Subgroup Radiation Monitoring Subgroup PDF icon Draft Work Plan - February 4,...

  11. Topic A and B Awardee: Electric Reliability Council of Texas...

    Office of Environmental Management (EM)

    and B Awardee: Electric Reliability Council of Texas Topic A and B Awardee: Electric Reliability Council of Texas The Electric Reliability Council of Texas (ERCOT) manages the flow ...

  12. TEC Working Group Topic Groups Section 180(c) Meeting Summaries...

    Office of Environmental Management (EM)

    Meeting Summaries TEC Working Group Topic Groups Section 180(c) Meeting Summaries Meeting Summaries PDF icon Washington, DC TEC Meeting - 180(c) Group Summary - March 15, 2006 More...

  13. TEC Working Group Topic Groups Rail Conference Call Summaries...

    Office of Environmental Management (EM)

    Summaries Inspections Subgroup TEC Working Group Topic Groups Rail Conference Call Summaries Inspections Subgroup Inspections Subgroup PDF icon April 6, 2006 PDF icon February 23,...

  14. TEC Working Group Topic Groups Routing Conference Call Summaries...

    Office of Environmental Management (EM)

    Routing Conference Call Summaries TEC Working Group Topic Groups Routing Conference Call Summaries CONFERENCE CALL SUMMARIES PDF icon January 31, 2008 PDF icon December 6, 2007 PDF...

  15. TEC Working Group Topic Groups Security Meeting Summaries | Department...

    Office of Environmental Management (EM)

    Meeting Summaries TEC Working Group Topic Groups Security Meeting Summaries Meeting Summaries PDF icon Green Bay STG Meeting Summary- September 14, 2006 PDF icon Washington STG...

  16. TEC Working Group Topic Groups Archives Mechanics of Funding...

    Office of Environmental Management (EM)

    Mechanics of Funding and Techical Assistance TEC Working Group Topic Groups Archives Mechanics of Funding and Techical Assistance Mechanics of Funding and Techical Assistance Items...

  17. TEC Working Group Topic Groups Rail Archived Documents | Department...

    Office of Environmental Management (EM)

    Archived Documents TEC Working Group Topic Groups Rail Archived Documents ARCHIVED DOCUMENTS PDF icon Inspections Summary Matrix PDF icon TEC Transportation Safety WIPP-PIG Rail...

  18. TEC Working Group Topic Groups Tribal Conference Call Summaries...

    Office of Environmental Management (EM)

    Conference Call Summaries TEC Working Group Topic Groups Tribal Conference Call Summaries Conference Call Summaries PDF icon March 12, 2008 PDF icon October 3, 2007 PDF icon...

  19. TEC Working Group Topic Groups Archives Communications Conference...

    Office of Environmental Management (EM)

    Communications Conference Call Summaries TEC Working Group Topic Groups Archives Communications Conference Call Summaries Conference Call Summaries PDF icon Conference Call Summary...

  20. TEC Working Group Topic Groups Archives Communications Meeting...

    Office of Environmental Management (EM)

    Archives Communications Meeting Summaries TEC Working Group Topic Groups Archives Communications Meeting Summaries Meeting Summaries PDF icon Milwaukee TEC Meeting, Communications...

  1. TEC Working Group Topic Groups Section 180(c) Key Documents ...

    Office of Environmental Management (EM)

    Key Documents TEC Working Group Topic Groups Section 180(c) Key Documents Key Documents Briefing Package for Section 180(c) Implementation - July 2005 PDF icon Executive Summary...

  2. TEC Working Group Topic Groups Security Conference Call Summaries...

    Office of Environmental Management (EM)

    Security Conference Call Summaries TEC Working Group Topic Groups Security Conference Call Summaries Conference Call Summaries PDF icon August 17, 2006 (Draft) PDF icon July 18,...

  3. TEC Working Group Topic Groups Rail Key Documents | Department...

    Office of Environmental Management (EM)

    Rail Key Documents TEC Working Group Topic Groups Rail Key Documents KEY DOCUMENTS Radiation Monitoring Subgroup Intermodal Subgroup Planning Subgroup PDF icon Current FRA State...

  4. TEC Working Group Topic Groups Rail Key Documents Intermodal...

    Office of Environmental Management (EM)

    Intermodal Subgroup TEC Working Group Topic Groups Rail Key Documents Intermodal Subgroup Intermodal Subgroup PDF icon Draft Work Plan More Documents & Publications TEC Working...

  5. AMO Requests Technical Topics Suitable for a Manufacturing Innovation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Innovation Institute AMO Requests Technical Topics Suitable for a Manufacturing Innovation Institute April 17, 2014 - 12:23pm Addthis The Advanced Manufacturing Office...

  6. Microsoft PowerPoint - Chairs Round Robin Presentation- Topics...

    Energy Savers [EERE]

    April 22, 2015 www.energy.govEM 2 Savannah River Citizens' Advisory Board Topic: * Liquid ... Board Issues: * Waste Isolation Pilot Plant (WIPP): The status of recovery efforts ...

  7. Microsoft Word - Tribal Topic Group Summary March 06 final _3...

    Office of Environmental Management (EM)

    TEC Tribal Topic Group Meeting Tuesday, March 14, 2006 Washington, DC Participants: Jay Jones, Department of Energy (DOE)Office of Civilian Radioactive Waste Management (OCRWM),...

  8. Topic B Awardee: Eastern Interconnection States' Planning Council...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Eastern Interconnection States' Planning Council Topic B Awardee: Eastern Interconnection States' Planning Council The Eastern Interconnection States' Planning Council (EISPC) is ...

  9. Events & Topics in Renewable Energy & the Environment | Photosynthetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technologies campus, followed by a brief presentation. Topics will include home automation, the internet of things, wireless sensor networks and other smart technologies. The...

  10. TEC Working Group Topic Groups Tribal Meeting Summaries | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tribal Meeting Summaries TEC Working Group Topic Groups Tribal Meeting Summaries Meeting Summaries PDF icon Kansas City TEC Meeting - Tribal Group Summary - July 25, 2007 PDF icon ...

  11. Collaboration Topics - System Software | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration System Software This collaboration focuses on research and development of parallel file system interfaces and tools, system resource management capabilities, operating system evaluation, and software for high-performance interconnects. Current activities include the test and evaluation of technologies and tools associated with the Lustre parallel file system, the development and analysis of middleware to encapsulate application I/O requirements and abstract the capabilities of

  12. Framework Topic Briefing: Direct Feed LAW

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fission (Technical Report) | SciTech Connect Fragment Yields Calculated in a Time-Dependent Microscopic Theory of Fission Citation Details In-Document Search Title: Fragment Yields Calculated in a Time-Dependent Microscopic Theory of Fission Authors: Younes, W ; Gogny, D Publication Date: 2012-09-28 OSTI Identifier: 1053671 Report Number(s): LLNL-TR-586678 DOE Contract Number: W-7405-ENG-48 Resource Type: Technical Report Research Org: Lawrence Livermore National Laboratory (LLNL),

  13. Understanding catalysis in a multiphasic two-dimensional transition metal dichalcogenide.

    SciTech Connect (OSTI)

    Chou, Stanley Shihyao; Sai, Na; Lu, Ping; Coker, Eric Nicholas; Liu, Sheng; Artyushkova, Kateryna; Luk, Ting S.; Kaehr, Bryan James; Brinker, C. Jeffrey

    2015-10-07

    Establishing processing–structure–property relationships for monolayer materials is crucial for a range of applications spanning optics, catalysis, electronics and energy. Presently, for molybdenum disulfide, a promising catalyst for artificial photosynthesis, considerable debate surrounds the structure/property relationships of its various allotropes. Here we unambiguously solve the structure of molybdenum disulfide monolayers using high-resolution transmission electron microscopy supported by density functional theory and show lithium intercalation to direct a preferential transformation of the basal plane from 2H (trigonal prismatic) to 1T' (clustered Mo). These changes alter the energetics of molybdenum disulfide interactions with hydrogen (ΔGH), and, with respect to catalysis, the 1T' transformation renders the normally inert basal plane amenable towards hydrogen adsorption and hydrogen evolution. Furthermore, we show basal plane activation of 1T' molybdenum disulfide and a lowering of ΔGH from +1.6 eV for 2H to +0.18 eV for 1T', comparable to 2H molybdenum disulfide edges on Au(111), one of the most active hydrogen evolution catalysts known.

  14. Understanding catalysis in a multiphasic two-dimensional transition metal dichalcogenide.

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chou, Stanley Shihyao; Sai, Na; Lu, Ping; Coker, Eric Nicholas; Liu, Sheng; Artyushkova, Kateryna; Luk, Ting S.; Kaehr, Bryan James; Brinker, C. Jeffrey

    2015-10-07

    Establishing processing–structure–property relationships for monolayer materials is crucial for a range of applications spanning optics, catalysis, electronics and energy. Presently, for molybdenum disulfide, a promising catalyst for artificial photosynthesis, considerable debate surrounds the structure/property relationships of its various allotropes. Here we unambiguously solve the structure of molybdenum disulfide monolayers using high-resolution transmission electron microscopy supported by density functional theory and show lithium intercalation to direct a preferential transformation of the basal plane from 2H (trigonal prismatic) to 1T' (clustered Mo). These changes alter the energetics of molybdenum disulfide interactions with hydrogen (ΔGH), and, with respect to catalysis, the 1T' transformationmore » renders the normally inert basal plane amenable towards hydrogen adsorption and hydrogen evolution. Furthermore, we show basal plane activation of 1T' molybdenum disulfide and a lowering of ΔGH from +1.6 eV for 2H to +0.18 eV for 1T', comparable to 2H molybdenum disulfide edges on Au(111), one of the most active hydrogen evolution catalysts known.« less

  15. Applying Innovation System Concept in Agricultural Research for...

    Open Energy Info (EERE)

    in Agricultural Research for Development: A learning module AgencyCompany Organization: International Livestock Research Institute Sector: Land Focus Area: Agriculture Topics:...

  16. Superacid catalysis of light hydrocarbon conversion. DOE PETC third quarterly report, February 25, 1994--May 24, 1994

    SciTech Connect (OSTI)

    Gates, B.C.

    1995-12-31

    Environmental concerns are leading to the replacement of aromatic hydrocarbons in gasoline by high-octane-number branched paraffins and oxygenated compounds such as methyl t-butyl ether. The ether is produced from methanol and isobutylene, and the latter can be formed from n-butane by isomerization followed by dehydrogenation. Paraffin isomerization reactions are catalyzed by very strong acids such as aluminum chloride supported on alumina. The aluminum chloride-containing catalysts are corrosive, and their disposal is expensive. Alternatively, hydroisomerization is catalyzed by zeolite-supported metals at high temperatures, but high temperatures do not favor branched products at equilibrium. Thus there is a need for improved catalysts and processes for the isomerization of n-butane and other straight-chain paraffins. Consequently, researchers have sought for solid acids that are noncorrosive and active enough to catalyze isomerization of paraffins at low temperatures. For example, sulfated zirconia catalyzes isomerization of n-butane at temperatures as low as 25{degrees}C. The addition of iron and manganese promoters has been reported to increase the activity of sulfated zirconia for n-butane isomerization by three orders of magnitude. Although the high activity of this catalyst is now established, the reaction network is not known, and the mechanism has not been investigated. The goal of this work is to investigate low-temperature reactions of light paraffins catalyzed by solid superacids of the sulfated zirconia type. The present report is concerned with catalysis of n-butane conversion catalyzed by the Fe- and Mn- promoted sulfated zirconia described in the previous report in this series.

  17. Northwestern University Facility for Clean Catalytic Process Research

    SciTech Connect (OSTI)

    Marks, Tobin Jay

    2013-05-08

    Northwestern University with DOE support created a Facility for Clean Catalytic Process Research. This facility is designed to further strengthen our already strong catalysis research capabilities and thus to address these National challenges. Thus, state-of-the art instrumentation and experimentation facility was commissioned to add far greater breadth, depth, and throughput to our ability to invent, test, and understand catalysts and catalytic processes, hence to improve them via knowledge-based design and evaluation approaches.

  18. SERS internship Fall 1992--Spring 1993: Abstract and research papers

    SciTech Connect (OSTI)

    Not Available

    1993-08-05

    This report contains the abstracts and research papers by students on a variety of topics in engineering, genetics, solid state physics, thermonuclear energy, astrophysics, and other science related topics.

  19. Wavelet-based surrogate time series for multiscale simulation of heterogeneous catalysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Savara, Aditya Ashi; Daw, C. Stuart; Xiong, Qingang; Gur, Sourav; Danielson, Thomas L.; Hin, Celine N.; Pannala, Sreekanth; Frantziskonis, George N.

    2016-01-28

    We propose a wavelet-based scheme that encodes the essential dynamics of discrete microscale surface reactions in a form that can be coupled with continuum macroscale flow simulations with high computational efficiency. This makes it possible to simulate the dynamic behavior of reactor-scale heterogeneous catalysis without requiring detailed concurrent simulations at both the surface and continuum scales using different models. Our scheme is based on the application of wavelet-based surrogate time series that encodes the essential temporal and/or spatial fine-scale dynamics at the catalyst surface. The encoded dynamics are then used to generate statistically equivalent, randomized surrogate time series, which canmore » be linked to the continuum scale simulation. As a result, we illustrate an application of this approach using two different kinetic Monte Carlo simulations with different characteristic behaviors typical for heterogeneous chemical reactions.« less

  20. SILICON CARBIDE JOINING. FINAL TOPICAL REPORT

    SciTech Connect (OSTI)

    1998-10-01

    Future energy systems will be required to fire lower-grade fuels and meet higher energy conversion efficiencies than today's systems. The steam cycle used at present is limited to a maximum temperature of 550 C because above that, the stainless steel tubes deform and corrode excessively. To boost efficiency significantly, much higher working fluid temperatures are required. Although high-temperature alloys will suffice for the construction of these components in the near term, the greatest efficiency increases can be reached only with the use of advanced structural ceramics such as silicon carbide (SiC). However, SiC does not melt, but instead sublimes at temperatures over 2000 C. Therefore, it is not possible to join pieces of it through welding, and most brazing compounds have much lower melting points, so the joints lose strength at temperatures much lower than the maximum use temperature of the SiC. Since larger objects such as heat exchangers cannot be easily created from smaller ceramic pieces, the size of the SiC structures that can presently be manufactured are limited by the size of the sintering furnaces (approximately 10 feet for sintered alpha SiC). In addition, repair of the objects will require the use of field-joining techniques. Some success has been had by causing silicon and carbon to react at 1400--1500 C to form SiC in a joint (Rabin, 1995), but these joints contain continuous channels of unreacted silicon, which cause the joints to corrode and creep excessively at temperatures below 1260 C (Breder and Parten, 1996). The objective of this work conducted at the Energy & Environmental Research Center (EERC) is to develop a patentable technique for joining large SiC structures in the field. The key to developing a successful technique will be the use of reactive joining compounds to lower the joining temperature without leaving continuous channels of unreacted compounds that can weaken the joint at temperatures below 1260 C or serve as conduits for transport of corrodents. In addition, the method of heating the joint to cause the reaction bonding must be applicable to structures that are large in two dimensions, which precludes the use of furnaces for heating the samples. Special efforts will be made in this project to transfer the developed technologies to the materials industry via licensing agreements through the EERC Foundation.

  1. Homesteading on the Pajarito Plateau topic of inaugural lecture at Los

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alamos National Laboratory Homesteading On The Pajarito Plateau Homesteading on the Pajarito Plateau topic of inaugural lecture at Los Alamos National Laboratory The lecture is based on a book by local writers Dorothy Hoard, Judy Machen and Ellen McGehee about the area's settlement between 1887 and 1942. January 4, 2013 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering

  2. Matter, antimatter and surviving the big bang is topic of Lab's next

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Frontiers in Science lecture Frontiers in Science lectures Matter, antimatter and surviving the big bang is topic of Lab's next Frontiers in Science lecture LANL scientist Vincenzo Cirigliano asks the question, How did we survive the big bang? in a series of Frontiers in Science lectures. October 31, 2013 Frontiers in Science lecture series is intended to increase local public awareness of the diversity of science and engineering research at the Laboratory. Frontiers in Science lecture

  3. CANCELED - Events & Topics in Renewable Energy & the Environment...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environment CANCELED - Events & Topics in Renewable Energy & the Environment Midwest Biodiesel Products LLC November 3, 2015 - 4:00pm Please join us for a tour of the Midwest...

  4. EAC Presentation (March 10, 2011): Potential Study Topics | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    or whether it should limit itself to providing recommendations to DOE about how the topic should be framed and analyzed by the national laboratories or other parties. PDF icon...

  5. TEC Working Group Topic Groups Security Key Documents | Department...

    Office of Environmental Management (EM)

    Key Documents TEC Working Group Topic Groups Security Key Documents Key Documents PDF icon Security TG Work Plan August 7, 2006 PDF icon Security Lessons Learned Document August 2,...

  6. Proposed Work Scope for the Rail Topic Group

    Office of Environmental Management (EM)

    (TEC) Working Group's Rail Topic Group (RTG) is to provide stakeholder perspectives and ... or as necessary, reporting back to the full RTG on the bimonthly calls and at meetings. ...

  7. Is It Homogeneous or Heterogeneous Catalysis Derived from [RhCp*Cl2]2? In Operando-XAFS, Kinetic and Crucial Kinetic Poisoning Evidence for Subnanometer Rh4 Cluster-Based Benzene Hydrogenation Catalysis

    SciTech Connect (OSTI)

    Bayram, Ercan; Linehan, John C.; Fulton, John L.; Roberts, John A.; Szymczak, Nathaniel; Smurthwaite, Tricia D.; Ozkar, Saim; Balasubramanian, Mahalingam; Finke, Richard G.

    2011-11-23

    Determining the true, kinetically dominant catalytically active species, in the classic benzene hydrogenation system pioneered by Maitlis and co-workers 34 years ago starting with [RhCp*Cl2]2 (Cp* = [{eta}5-C5(CH3)5]), has proven to be one of the most challenging case studies in the quest to distinguish single-metal-based 'homogeneous' from polymetallic, 'heterogeneous' catalysis. The reason, this study will show, is the previous failure to use the proper combination of (i) operando spectroscopy to determine the dominant form(s) of the precatalyst's mass under catalysis (i.e., operating) conditions, plus then and crucially also (ii) the previous lack of the necessary kinetic studies, catalysis being a 'wholly kinetic phenomenon' as J. Halpern long ago noted. An important contribution from this study will be to reveal the power of quantitiative kinetic poisoning experiments for distinguishing single-metal, or in this case subnanometer Rh4 cluster-based catalysis from larger, polymetallic Rh(0)n nanoparticle catalysis, at least under favorable conditions. The combined operando-XAFS (X-ray absorption fine structure) spectroscopy and kinetic evidences provide a compelling case for Rh4-based, with average stoichiometry 'Rh4Cp*2.4Cl4Hc', benzene hydrogenation catalysis in 2-propanol with added Et3N and at 100 C and 50 atm initial H2 pressure. The results also reveal, however, that if even ca. 1.4% of the total soluble Rh(0)n had formed nanoparticles, then those Rh(0)n nanoparticles would have been able to account for all the observed benzene hydrogenation catalytic rate (using commercial, ca. 2 nm, polyethyleneglycol-dodecylether hydrosol stabilized Rh(0)n nanoparticles as a model system). The results 'especially the poisoning methodology developed and employed' are of significant, broader interest since determining the nature of the true catalyst continues to be a central, often vexing issue in any and all catalytic reactions. The results are also of fundamental interest in that they add to a growing body of evidence indicating that certain, appropriately ligated, coordinatively unsaturated, subnanometer M4 transition-metal clusters can be relatively robust catalysts. Also demonstrated herein is that Rh4 clusters are poisoned by Hg(0), demonstrating for the first time that the classic Hg(0) poisoning test of 'homogeneous' vs 'heterogeneous'catalysts cannot distinguish Rh4-based subnanometer catalysts from Rh(0)n nanoparticle catalysts, at least for the present examples of these two specific, Rh-based catalysts.

  8. Interconnection-Wide Transmission Planning Initiative: Topic B, Cooperation

    Energy Savers [EERE]

    Among States in the Eastern Interconnection on Electric Resource Planning and Priorities | Department of Energy Eastern Interconnection on Electric Resource Planning and Priorities Interconnection-Wide Transmission Planning Initiative: Topic B, Cooperation Among States in the Eastern Interconnection on Electric Resource Planning and Priorities A description of the requirements for Topic B for the Eastern Interconnection under the Interconnection-Wide Transmission Planning Initiative, part of

  9. Interconnection-Wide Transmission Planning Initiative: Topic B, Cooperation

    Energy Savers [EERE]

    Among States in the Western Interconnection on Electric Resource Planning and Priorities | Department of Energy Western Interconnection on Electric Resource Planning and Priorities Interconnection-Wide Transmission Planning Initiative: Topic B, Cooperation Among States in the Western Interconnection on Electric Resource Planning and Priorities A description of the requirements for Topic B for the Western Interconnection under the Interconnection-Wide Transmission Planning Initiative, part of

  10. Interconnection-Wide Transmission Planning Initiative: Topic B, State

    Energy Savers [EERE]

    Agency Input Regarding Electric Resource and Transmission Planning in the Texas Interconnection | Department of Energy State Agency Input Regarding Electric Resource and Transmission Planning in the Texas Interconnection Interconnection-Wide Transmission Planning Initiative: Topic B, State Agency Input Regarding Electric Resource and Transmission Planning in the Texas Interconnection A description of the requirements for Topic B for the Texas Interconnect under the Interconnection-Wide

  11. Topic B Awardee: Western Governors' Association | Department of Energy

    Energy Savers [EERE]

    Western Governors' Association Topic B Awardee: Western Governors' Association For the Topic A input requirements of the award, the states and provinces in the Western Interconnection have formed a new committee -- the State and Provincial Steering Committee -- to provide input in regional transmission planning and analysis in the interconnection. The Committee will consist of representatives from each state and province in the Western Interconnection. Pending formal announcement, the Committee

  12. Request for Information (RFI): Clean Energy Manufacturing Topics Suitable

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for a Manufacturing Innovation Institute | Department of Energy Clean Energy Manufacturing Topics Suitable for a Manufacturing Innovation Institute Request for Information (RFI): Clean Energy Manufacturing Topics Suitable for a Manufacturing Innovation Institute April 17, 2014 - 11:04am Addthis Funding: This RFI is not a Funding Opportunity Announcement (FOA); therefore, EERE is not accepting applications at this time. Open Date: 04/17/2014 Close Date: 05/20/2014 Funding Organization: The

  13. 18th Topical Conference High-Temperature Plasma Diagnostics (HTPD) |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Princeton Plasma Physics Lab May 16, 2010, 9:00am to May 20, 2010, 5:00pm Conference Wildwood, New Jersey 18th Topical Conference High-Temperature Plasma Diagnostics (HTPD) The 18th Topical Conference on High-Temperature Plasma Diagnostics will be held May 16-20, 2010 in Wildwood, New Jersey. This biennial conference brings together plasma physicists from a variety of fields including magnetic confinement fusion, inertial confinement fusion, space plasmas, astrophysics, and industrial

  14. Nuclear Physics: Experiment Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    search Nuclear Physics Program Please upgrade your browser. This site's design is only visible in a graphical browser that supports web standards, but its content is accessible to any browser. Concerns? Nuclear Physics Program Physics Home Seminars & Colloquia Experiment Research User/Researcher Information print version Research Highlights Public Interest Nuclear Physics Accelerator Free Electron Laser (FEL) Medical Imaging Physics Topics Campaigns Meetings Recent Talks Archived Talks

  15. Nuclear Physics: Experiment Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Colloquium Experiment Research User/Researcher Information print version Research Highlights Public Interest Nuclear Physics Accelerator Free Electron Laser (FEL) Medical Imaging Physics Topics Campaigns Meetings Recent Talks Archived Talks Additional Information Computing at JLab Operations Logbook Accelerator and Experimental Schedule Memos & Information Short Term Schedule (MCC Whiteboard) Nominal Dates for Bi-annual Beam Time Requests Forms for Beam Time Requests and Experiment

  16. Nuclear Physics: Experiment Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physics Privacy and Security Notice Skip over navigation Search the JLab Site Nuclear Physics Program Please upgrade your browser. This site's design is only visible in a graphical browser that supports web standards, but its content is accessible to any browser. Concerns? Nuclear Physics Program Physics Home Events Experiment Research User/Researcher Information print version Research Highlights Public Interest Nuclear Physics Accelerator Free Electron Laser (FEL) Medical Imaging Physics Topics

  17. SBIR/STTR Phase I Release 2 Technical Topics Announced for FY14 Fuel Cell Topics Included

    Broader source: Energy.gov [DOE]

    Phase I Release 2 technical topics include prototype fuel cell-battery electric hybrid trucks for waste transportation and novel membranes and non-platinum group metal catalysts for direct methanol as well as hydrogen fuel cells.

  18. SBIR/STTR Phase I Technical Topics for FY15 Announced – Webinar July 22 at 1:00 p.m. EDT

    Broader source: Energy.gov [DOE]

    The Fiscal Year 2015 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase I Release 1 technical topics include non-platinum catalysts for fuel cells and detection of contaminants in hydrogen.

  19. Sandia Combustion Research: Technical review

    SciTech Connect (OSTI)

    1995-07-01

    This report contains reports from research programs conducted at the Sandia Combustion Research Facility. Research is presented under the following topics: laser based diagnostics; combustion chemistry; reacting flow; combustion in engines and commercial burners; coal combustion; and industrial processing. Individual projects were processed separately for entry onto the DOE databases.

  20. Topic Index to the DOE Administrative Records Disposition Schedules

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5/21/07 TOPICINDEXTODOEADMINSCHEDULES Topic Index to the DOE Administrative Records Disposition Schedules (excluding the GRS Schedules) Topic Schedule Item [A] [B] [C] [D] [E] [F] [G] [H] [I] [J] [K] [L] [M] [N] [O] [P] [Q] [R] [S] [T] [U] [V] [W] [X] [Y] [Z] A Academic/Outreach Program 1 44 Access Request Files 18 6 Accountable Officers' Files 6 1 Accounting Administrative Files 6 5 Administrative Claims Files 6 10 Administrative Training Records 1 29.2 Administrative Issuances 16 1

  1. Acoustics topic of upcoming Frontiers in Science series

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acoustics topic of upcoming Frontiers in Science Acoustics topic of upcoming Frontiers in Science series Dipen Sinha will discuss acoustics and its applications, including how it is possible to use sound to solve problems in health, national security and for industry. July 24, 2014 Whenever an object vibrates, it creates sound, vibrations can 0:19 be detected. Besides just listening to it, we can detect it with various sensors. We 0:25 can tell what's inside a single container from the sound or

  2. Molecular beam mass spectrometer equipped with a catalytic wall reactor for in situ studies in high temperature catalysis research

    SciTech Connect (OSTI)

    Horn, R.; Ihmann, K.; Ihmann, J.; Jentoft, F.C.; Geske, M.; Taha, A.; Pelzer, K.; Schloegl, R.

    2006-05-15

    A newly developed apparatus combining a molecular beam mass spectrometer and a catalytic wall reactor is described. The setup has been developed for in situ studies of high temperature catalytic reactions (>1000 deg. C), which involve besides surface reactions also gas phase reactions in their mechanism. The goal is to identify gas phase radicals by threshold ionization. A tubular reactor, made from the catalytic material, is positioned in a vacuum chamber. Expansion of the gas through a 100 {mu}m sampling orifice in the reactor wall into differentially pumped nozzle, skimmer, and collimator chambers leads to the formation of a molecular beam. A quadrupole mass spectrometer with electron impact ion source designed for molecular beam inlet and threshold ionization measurements is used as the analyzer. The sampling time from nozzle to detector is estimated to be less than 10 ms. A detection time resolution of up to 20 ms can be reached. The temperature of the reactor is measured by pyrometry. Besides a detailed description of the setup components and the physical background of the method, this article presents measurements showing the performance of the apparatus. After deriving the shape and width of the energy spread of the ionizing electrons from measurements on N{sub 2} and He we estimated the detection limit in threshold ionization measurements using binary mixtures of CO in N{sub 2} to be in the range of several hundreds of ppm. Mass spectra and threshold ionization measurements recorded during catalytic partial oxidation of methane at 1250 deg. C on a Pt catalyst are presented. The detection of CH{sub 3}{center_dot} radicals is successfully demonstrated.

  3. Sulfation of metal-organic framework: Opportunities for acid catalysis and proton conductivity

    SciTech Connect (OSTI)

    Goesten, M.G.; Stavitski, E.; Juan-Alcaniz, J.; Ramos-Fernandez, E.V.; Sai Sankar Gupta, K.B.; van Bekkum, H.; Gascon, J. and Kapteijn, F.

    2011-05-24

    A new post-functionalization method for metal-organic frameworks (MOFs) has been developed to introduce acidity for catalysis. Upon treatment with a mixture of triflic anhydride and sulfuric acid, chemically stable MOF structures MIL-101(Cr) and MIL-53(Al) can be sulfated, resulting in a Broensted sulfoxy acid group attached to up to 50% of the aromatic terephthalate linkers of the structure. The sulfated samples have been extensively characterized by solid-state NMR, XANES, and FTIR spectroscopy. The functionalized acidic frameworks show catalytic activity similar to that of acidic polymers like Nafion{reg_sign} display in the esterification of n-butanol with acetic acid (TOF {approx} 1 min{sup -1} {at} 343 K). Water adsorbs strongly up to 4 molecules per sulfoxy acid group, and an additional 2 molecules are taken up at lower temperatures in the 1-D pore channels of S-MIL-53(Al). The high water content and Broensted acidity provide the structure S-MIL-53(Al) a high proton conductivity up to moderate temperatures.

  4. Catalytic conversion of light alkanes-proof-of-concept stage - Phase IV. Topical report, February 1, 1994--January 31, 1995

    SciTech Connect (OSTI)

    1998-12-31

    This report details the research performed on Phase IV of the extended Cooperative Agreement. This Phase, entitled C{sub 1}-C{sub 4} Research, provides the research support which accompanies the C{sub 4} Proof-of-Concept Phase (Phase V) as the two major activities of the Cooperative Agreement during calendar 1993. It is the objective of this phase to understand the nature of the catalysts and catalytic activity of perhaloporphyrin complexes uncovered during Phases I-III in order that superior catalytic materials can be made and tested which meet commercial criteria for the oxidation of the C{sub 1}-C{sub 4} light alkane gases found in natural gas and other available hydrocarbon streams. During Phase IV, we have examined the physical and electronic structures of the very active perhaloporphyrin catalysts which we have developed, and have gained an understanding of the properties which make them active. This has led us to design and synthesize materials which are cheaper, more active, more robust and, in general superior for carrying out practical catalysis. Our early generation perhaloporphyrin catalysts, while exhibiting unprecedented catalytic activity, were far too expensive for use in converting natural gas or its C{sub 1}-C{sub 4} components.

  5. DOE Research and Development Accomplishments Menu Synopsis

    Office of Scientific and Technical Information (OSTI)

    Menu Synopsis Featured Scientists/Topics The Basics * Laureates * Explore * Database * Finding Aids * New Media Featured Scientists/Topics The Featured Scientists/Topics drop-down provides links to feature pages that contain compilations that spotlight an individual scientist or an area of research Top The Basics Home is the Welcome page for DOE R&D Accomplishments About provides information about the content of DOE R&D Accomplishments and provides a brief history of DOE and predecessors

  6. Accelerators, Beams And Physical Review Special Topics - Accelerators And Beams

    SciTech Connect (OSTI)

    Siemann, R.H.; /SLAC

    2011-10-24

    Accelerator science and technology have evolved as accelerators became larger and important to a broad range of science. Physical Review Special Topics - Accelerators and Beams was established to serve the accelerator community as a timely, widely circulated, international journal covering the full breadth of accelerators and beams. The history of the journal and the innovations associated with it are reviewed.

  7. TEC Working Group Topic Groups Archives Route Identification Process |

    Office of Environmental Management (EM)

    Department of Energy Route Identification Process TEC Working Group Topic Groups Archives Route Identification Process Route Identification Process Items Available for Download PDF icon Routing Discussion Paper (April 1998) More Documents & Publications TEC Meeting Summaries - January 1997 TEC Meeting Summaries - July 1997 TEC Meeting Summaries - January 1998

  8. Tritium R&D at AECL Selected Topics

    Office of Environmental Management (EM)

    Tritium R&D at AECL Selected Topics Tritium Focus Group Meeting, Savannah River Site 2014 April 22-24 Hugh Boniface Chalk River Laboratories, Ontario, CANADA Outline of Presentation * Introduction & Background * Tritium Facilities: Laboratories, old and new * Tritium Separations: CECE process * Tritium Properties: Materials * Tritium Exploitation: Batteries, Helium-3 * Other work: Education, environment, biology, fusion, hydrogen UNRESTRICTED / ILLIMITÉ 2 Background UNRESTRICTED /

  9. 2015 DOE SSL R&D Workshop LED Topic Table Questions to Consider

    Broader source: Energy.gov [DOE]

    This document was distributed during the LED Topic Table portion of the DOE SSL R&D Workshop and aimed to prompt discussion on the following topics:

  10. A Research Agenda on Assessing and Remediating Home Dampness...

    Office of Scientific and Technical Information (OSTI)

    research reports, current scientific knowledge on two topics: assessing unhealthy ... Based on a comparison of current scientific knowledge to that required to support ...

  11. Photosynthetic Antenna Research Center (PARC) | U.S. DOE Office...

    Office of Science (SC) Website

    and bioinspired architectures for next-generation systems for solar-energy conversion. Research Topics solar (fuels), photosynthesis (natural and artificial), biofuels ...

  12. SERS internship spring 1996 abstracts and research papers

    SciTech Connect (OSTI)

    Williams, B.

    1996-07-01

    This is the student symposium for the Science & Engineering Research Semester, May 2-3, 1996. A variety of topics are covered.

  13. Research Techniques

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Techniques Research Techniques Print Coming Soon

  14. Structures of trihydroxynaphthalene reductase-fungicide complexes: implications for structure-based design and catalysis

    SciTech Connect (OSTI)

    Liao, D.-I.; Basarab, G.S.; Gatenby, A.A.; Valent, B.; Jordan, D.B.

    2010-03-08

    Trihydroxynaphthalene reductase catalyzes two intermediate steps in the fungal melanin biosynthetic pathway. The enzyme, a typical short-chain dehydrogenase, is the biochemical target of three commercial fungicides. The fungicides bind preferentially to the NADPH form of the enzyme. Three X-ray structures of the Magnaporthe grisea enzyme complexed with NADPH and two commercial and one experimental fungicide were determined at 1.7 {angstrom} (pyroquilon), 2.0 {angstrom} (2,3-dihydro-4-nitro-1H-inden-1-one, 1), and 2.1 {angstrom} (phthalide) resolutions. The chemically distinct inhibitors occupy similar space within the enzyme's active site. The three inhibitors share hydrogen bonds with the side chain hydroxyls of Ser-164 and Tyr-178 via a carbonyl oxygen (pyroquilon and 1) or via a carbonyl oxygen and a ring oxygen (phthalide). Active site residues occupy similar positions among the three structures. A buried water molecule that is hydrogen bonded to the NZ nitrogen of Lys-182 in each of the three structures likely serves to stabilize the cationic form of the residue for participation in catalysis. The pro S hydrogen of NADPH (which is transferred as a hydride to the enzyme's naphthol substrates) is directed toward the carbonyl carbon of the inhibitors that mimic an intermediate along the reaction coordinate. Modeling tetrahydroxynaphthalene and trihydroxynaphthalene in the active site shows steric and electrostatic repulsion between the extra hydroxyl oxygen of the former substrate and the sulfur atom of Met-283 (the C-terminal residue), which accounts, in part, for the 4-fold greater substrate specificity for trihydroxynaphthalene over tetrahydroxynaphthalene.

  15. Argonne Researchers | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Researchers Name Topic - Any - General Argonne Information -Awards -Honors Energy -Energy efficiency --Vehicles ---Alternative fuels ---Automotive engineering ---Biofuels ---Diesel ---Electric drive technology ---Fuel economy ---Fuel injection ---Heavy-duty vehicles ---Hybrid & electric vehicles ---Hydrogen & fuel cells ---Internal combustion ---Maglev systems ---Powertrain research ---Vehicle testing --Building design ---Construction ---Industrial heating & cooling

  16. Topic A Awardee: Western Electricity Coordinating Council | Department of

    Energy Savers [EERE]

    Energy Western Electricity Coordinating Council Topic A Awardee: Western Electricity Coordinating Council Regional Transmission Expansion Planning (RTEP) The America Recovery and Reinvestment Act (ARRA) directs the Department of Energy (DOE) to provide assistance for the development of interconnection-based transmission plans for the Eastern and Western Interconnections, and for ERCOT. WECC received notification from the U.S. Department of Energy (DOE) on December 18, 2009 that it has been

  17. Topic B Awardee: Eastern Interconnection States' Planning Council |

    Energy Savers [EERE]

    Department of Energy Eastern Interconnection States' Planning Council Topic B Awardee: Eastern Interconnection States' Planning Council The Eastern Interconnection States' Planning Council (EISPC) is an historic endeavor initially funded by an award from the United States Department of Energy (DOE) pursuant to a provision of the American Recovery and Reinvestment Act (ARRA). The goal is to create an unprecedented collaborative among the states in the Eastern Interconnection. Comprised of

  18. Focus Group Meeting (Topical Meeting) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Training Meeting Date: April 30, 2008 Documents Available for Download PDF icon Meeting Agenda PDF icon Meeting Summary PDF icon Meeting Participants PDF icon Executive Summary/Actions PDF icon Information Package - Part I PDF icon Information Package - Part II More Documents & Publications Focus Group Meeting (Topical Wrap-Up) Training Work Group Charter 2012 National Trainers' Exchange for Department of Energy Safety and Health Trainers

  19. Mat. Sci. Training More Advanced Topics Jack Deslippe

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mat. Sci. Training More Advanced Topics Jack Deslippe Part 1: Building Applications at NERSC Jack Deslippe Applications Already Available Did you know that NERSC offers precompiled executables for more than 100 applications? Applications Already Available Did you know that NERSC offers precompiled executables for more than 100 applications? Example, Materials Science: VASP, NAMD, LAMMPS, NWCHEM, Quantum ESPRESSO, BerkeleyGW, SIESTA, Abinit, Gamess, GROMACS, GPAW MEEP, cpmd, libxc, etsf_io,

  20. Topic Group Reports  DOE Program Summaries

    Broader source: Energy.gov (indexed) [DOE]

    Philadelphia 1999 Meeting  Topic Group Reports  DOE Program Summaries  Discussion of SNF Storage Initiatives & Transportations Issues  Discussion of WIPP Opening  Summary of Breakout Sessions The Transportation External Coordination (TEC) Working Group held its 15th semi-annual meeting July 14-15, 1999 in Philadelphia, Pennsylvania. Over 150 members, participants, and observers representing state, tribal, and local governments, regional groups, industry and professional

  1. Discussion series on PURPA related topics: load management

    SciTech Connect (OSTI)

    Sturgeon, J I

    1980-08-01

    The Discussion Series on PURPA Related Topics is composed of five volumes: Metering, Billing, Information to Customers, Load Management Techniques and Master Metering. These reports are based on twenty-five Demonstration and Implementation projects sponsored and directed during the past five years by the US Department of Energy, Office of Utility Systems. Each of the topics bears directly on one or more of the federal standards contained in the Public Utilities Regulatory Policies Act of 1978 (PURPA). This volume, Load Management Techniques, relates primarily to the Time-of-Day rates standard, PURPA IB(d)3. The experiences related in this report deal, in part, with the procedures and equipment which are affected when time-of-day rates are implemented. One goal of this report is to describe how people in a variety of settings have dealt with the many practical issues in load management. Another is to highlight the lessons and summarize the experiences of the Project participants. This report does not stand as a manual nor provide prescriptive guidelines on how to deal with the topic. Rather it offers an account for those charged with the responsibility of implementing PURPA requirements to learn from the insights and problems which occurred during the Rate Demonstration projects.

  2. Opportunities for Catalysis in The 21st Century. A report from the Basic Energy Sciences Advisory Committee

    SciTech Connect (OSTI)

    White, J. M.; Bercaw, J.

    2002-05-16

    Chemical catalysis affects our lives in myriad ways. Catalysis provides a means of changing the rates at which chemical bonds are formed and broken and of controlling the yields of chemical reactions to increase the amounts of desirable products from these reactions and reduce the amounts of undesirable ones. Thus, it lies at the heart of our quality of life: The reduced emissions of modern cars, the abundance of fresh food at our stores, and the new pharmaceuticals that improve our health are made possible by chemical reactions controlled by catalysts. Catalysis is also essential to a healthy economy: The petroleum, chemical, and pharmaceutical industries, contributors of $500 billion to the gross national product of the United States, rely on catalysts to produce everything from fuels to ''wonder drugs'' to paints to cosmetics. Today, our Nation faces a variety of challenges in creating alternative fuels, reducing harmful by-products in manufacturing, cleaning up the environment and preventing future pollution, dealing with the causes of global warming, protecting citizens from the release of toxic substances and infectious agents, and creating safe pharmaceuticals. Catalysts are needed to meet these challenges, but their complexity and diversity demand a revolution in the way catalysts are designed and used. This revolution can become reality through the application of new methods for synthesizing and characterizing molecular and material systems. Opportunities to understand and predict how catalysts work at the atomic scale and the nanoscale are now appearing, made possible by breakthroughs in the last decade in computation, measurement techniques, and imaging and by new developments in catalyst design, synthesis, and evaluation.

  3. 11th Topical conference high-temperature plasma diagnostics. Book of abstracts

    SciTech Connect (OSTI)

    1996-06-01

    This report contains abstracts from the 11th topical conference on high-temperature plasma diagnostics.

  4. Topic: Cesium Management and Disposition Alternatives for the Low Activity Waste Pre-Treatment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Department of Energy Topic Index to the DOE Administrative Records Disposition Schedules Topic Index to the DOE Administrative Records Disposition Schedules Topic Index to the DOE Administrative Records Disposition Schedules PDF icon Topic Index to the DOE Administrative Records Disposition Schedules More Documents & Publications ADMINISTRATIVE RECORDS SCHEDULE 20: ELECTRONIC RECORDS ADMINISTRATIVE RECORDS SCHEDULE 20: ELECTRONIC RECORDS ADMINISTRATIVE RECORDS SCHEDULE 12: COMMUNICATIONS

  5. DOE-TSPP-11, Technical Standards Program Topical Committees- July 1, 2009

    Broader source: Energy.gov [DOE]

    This procedure describes how topical committees are organized and recognized under the Technical Standards Program.

  6. DOE-TSPP-9-2013, DOE Technical Standards Program Topical Committees

    Broader source: Energy.gov [DOE]

    This procedure describes how topical committees are organized and recognized under the Technical Standards Program (TSP).

  7. DOE-TSPP-11, Technical Standards Program Topical Committees- August 1, 2000

    Broader source: Energy.gov [DOE]

    This procedure describes how topical committees are organized and recognized under the Technical Standards Program.

  8. Contact: Paul Dauenhauer (hauer@umn.edu) UD's Catalysis Center for Energy Innovation Invents New Chemical Detector

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Information Contact (If you're a human, don't change the following field) Enter your name: 8c7f598568c7f Your first name. Please enable Javascript to use this form. Your name: * Your e-mail address: * Subject: * Category: * - Please choose - STIP Website Subscribe to the OSTI.gov Newsletter Message: * Send message

    immediate release Contact: Paul Dauenhauer (hauer@umn.edu) UD's Catalysis Center for Energy Innovation Invents New Chemical Detector (NEWARK, DE) January 12, 2015 -- A team of

  9. Technology development for iron Fischer-Tropsch catalysis. Quarterly technical progress report No. 5, October 1, 1995--December 31, 1995

    SciTech Connect (OSTI)

    Davis, B.H.

    1996-01-19

    The objective of this research project is to develop the technology for the production of physically robust iron-based Fischer-Tropsch catalysts that have suitable activity, selectivity and stability to be used in the slurry phase synthesis reactor development. The catalysts that are developed shall be suitable for testing in the Advanced Fuels Development Facility at LaPorte, Texas, to produce either low- or high-alpha product distributions. Previous work by the offeror has produced a catalyst formulation that is 1.5 times as active as the ``standard-catalyst`` developed by German workers for slurry phase synthesis. The proposed work will optimize the catalyst composition and pretreatment operation for this low-alpha catalyst. In parallel, work will be conducted to design a high-alpha iron catalyst this is suitable for slurry phase synthesis. Studies will be conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors will be studied at the laboratory scale. Catalyst performance will be determined for catalysts synthesized in this program for activity, selectivity and aging characteristics. The research is divided into four major topical areas: (a) catalyst preparation and characterization, (b) product characterization, (c) reactor operations, and (d) data assessment. Accomplishments to date are described.

  10. Technology development for iron Fischer-Tropsch catalysis. Quarterly technical progress report No. 6, January 1, 1996--March 31, 1996

    SciTech Connect (OSTI)

    Davis, B.H.

    1996-05-01

    The objective of this research project is to develop the technology for the production of physically robust iron-based Fischer-Tropsch catalysts that have suitable activity, selectivity and stability to be used in the slurry phase synthesis reactor development. The catalysts that are developed shall be suitable for testing in the Advanced Fuels Development Facility at LaPorte, Texas, to produce either low- or high-alpha product distributions. Previous work by the offeror has produced a catalyst formulation that is 1.5 times as active as the ``standard-catalyst`` developed by German workers for slurry phase synthesis. The proposed work will optimize the catalyst composition and pretreatment operation for this low-alpha catalyst. In parallel, work will be conducted to design a high-alpha iron catalyst that is suitable for slurry phase synthesis. Studies will be conducted to define the chemical phases present at various stages of the pretreatment and synthesis stages and to define the course of these changes. The oxidation/reduction cycles that are anticipated to occur in large, commercial reactors will be studied at the laboratory scale. Catalyst performance will be determined for catalysts synthesized in this program for activity, selectivity and aging characteristics. The research is divided into four major topical areas: (a) catalyst preparation and characterization, (b) product characterization, (c) reactor operations, and (d) data assessment. Accomplishments for this period are discussed.

  11. Theoretical Studies in Heterogenous Catalysis: Towards a Rational Design of Novel Catalysts for Hydrodesulfurization and Hydrogen Production

    SciTech Connect (OSTI)

    Rodriguez,J.A.; Liu, P.

    2008-10-01

    Traditionally, knowledge in heterogeneous catalysis has come through empirical research. Nowadays, there is a clear interest to change this since millions of dollars in products are generated every year in the chemical and petrochemical industries through catalytic processes. To obtain a fundamental knowledge of the factors that determine the activity of heterogeneous catalysts is a challenge for modern science since many of these systems are very complex in nature. In principle, when a molecule adsorbs on the surface of a heterogeneous catalyst, it can interact with a large number of bonding sites. It is known that the chemical properties of these bonding sites depend strongly on the chemical environment around them. Thus, there can be big variations in chemical reactivity when going from one region to another in the surface of a heterogeneous catalyst. A main objective is to understand how the structural and electronic properties of a surface affect the energetics for adsorption processes and the paths for dissociation and chemical reactions. In recent years, advances in instrumentation and experimental procedures have allowed a large series of detailed works on the surface chemistry of heterogeneous catalysts. In many cases, these experimental studies have shown interesting and unique phenomena. Theory is needed to unravel the basic interactions behind these phenomena and to provide a general framework for the interpretation of experimental results. Ideally, theoretical calculations based on density-functional theory have evolved to the point that one should be able to predict patterns in the activity of catalytic surfaces. As in the case of experimental techniques, no single theoretical approach is able to address the large diversity of phenomena occurring on a catalyst. Catalytic surfaces are usually modeled using either a finite cluster or a two-dimensionally periodic slab. Many articles have been published comparing the results of these two approaches. An important advantage of the cluster approach is that one can use the whole spectrum of quantum-chemical methods developed for small molecules with relatively minor modifications. On the other hand, the numerical effort involved in cluster calculations increases rather quickly with the size of the cluster. This problem does not exist when using slab models. Due to the explicit incorporation of the periodicity of the crystal lattice through the Bloch theorem, the actual dimension of a slab calculation depends only on the size of the unit cell. In practical terms, the slab approach is mainly useful for investigating the behavior of adsorbates at medium and high coverages. Very large unit cells are required at the limit of low to zero coverage, or when examining the properties and chemical behavior of isolated defect sites in a surface. In these cases, from a computational viewpoint, the cluster approach can be much more cost effective than the slab approach. Slab and cluster calculations can be performed at different levels of sophistication: semi-empirical methods, simple ab initio Hartree-Fock, ab initio post-Hartree-Fock (CI, MP2, etc), and density functional theory. Density-functional (DF) based calculations frequently give adsorption geometries with a high degree of accuracy and predict reliable trends for the energetics of adsorption reactions. This article provides a review of recent theoretical studies that deal with the behavior of novel catalysts used for hydrodesulfurization (HDS) reactions and the production of hydrogen (i.e. catalytic processes employed in the generation of clean fuels). These studies involve a strong coupling of theory and experiment. A significant fraction of the review is focused on the importance of size-effects and correlations between the electronic and chemical properties of catalytic materials. The article begins with a discussion of results for the desulfurization of thiophene on metal carbides and phosphides, systems which have the potential to become the next generation of industrial HDS catalysts. Then, systematic studies con

  12. Recent advances in automotive catalysis for NOx emission control by small-pore microporous materials

    SciTech Connect (OSTI)

    Beale, Andrew M.; Gao, Feng; Lezcano-Gonzalez, Ines; Peden, Charles HF; Szanyi, Janos

    2015-10-05

    The ever increasing demand to develop highly fuel efficient engines coincides with the need to minimize air pollution originating from the exhaust gases of internal combustion engines. Dramatically improved fuel efficiency can be achieved at air-to-fuel ratios much higher than stoichiometric. In the presence of oxygen in large excess, however, traditional three-way catalysts are unable to reduce NOx. Among the number of lean-NOx reduction technologies, selective catalytic reduction (SCR) of NOx by NH3 over Cu- and Fe-ion exchanged zeolite catalysts has been extensively studied over the past 30+ years. Despite the significant advances in developing a viable practical zeolite-based catalyst for lean NOx reduction, the insufficient hydrothermal stabilities of the zeolite structures considered cast doubts about their real-world applicability. During the past decade a renewed interest in zeolite-based lean NOx reduction was spurred by the discovery of the very high activity of Cu-SSZ-13 (and the isostructural Cu-SAPO-34) in the NH3 SCR of NOx. These new, small-pore zeolite-based catalysts not only exhibited very high NOx conversion and N2 selectivity, but also exhibited exceptional high hydrothermal stability at high temperatures. In this review we summarize the key discoveries of the past ~5 years that lead to the introduction of these catalysts into practical application. The review first briefly discusses the structure and preparation of the CHA structure-based zeolite catalysts, and then summarizes the key learnings of the rather extensive (but not complete) characterisation work. Then we summarize the key findings of reaction kinetics studies, and provide some mechanistic details emerging from these investigations. At the end of the review we highlight some of the issues that are still need to be addressed in automotive exhaust control catalysis. Funding A.M.B. and I.L.G. would like to thank EPSRC for funding. F.G., C.H.F.P. and J.Sz. gratefully acknowledge financial support from the US Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Program.

  13. WTP Safety Culture Advice Joint Topic (HSEP/TWC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    January 2012 v1 Page 1 of 2 Note: The views expressed in committee meetings should not be considered a substitute for full HAB consensus on any particular issue. WTP Safety Culture Advice Joint Topic (HSEP/TWC) Framing questions for discussion regarding DOE's recently released Implementation Plan: Re: Secretary Chu's response to the DNFSB with the Implementation Plan for Recommendation 2011-1 (December 27, 2011) Note: The ORP coordinator for the DOE Response to DNFSB 2011-1 is Steve Pfaff. o

  14. TRIBAL ISSUES TOPIC GROUP MEETING SUMMARY JACKSONVILLE, FL

    Office of Environmental Management (EM)

    JACKSONVILLE, FL JANUARY 20, 1999 Mr. Kevin Blackwell (USDOT/FRA) updated the group on the status of the DOT response to DOE's inquiry about the tribal right to inspect rail shipments. The response was in the final stages of review in the General Counsel's office and is expected by July 1999. The Group has added a representative from the NRC General Counsel's office, as a topic group member, to help keep abreast of developments in the NRC's upcoming draft rulemaking regarding tribes and advanced

  15. TRIBAL ISSUES TOPIC GROUP MEETING SUMMARY JULY 13, 1999 Crowne

    Office of Environmental Management (EM)

    JULY 13, 1999 Crowne Plaza Center City Hotel, Philadelphia, PA Kevin Blackwell (U.S. Department of Transportation/Federal Rail Administration) (DOT/FRA) presented an overview of the topic group's discussion. The status of the DOT/FRA's response to DOE's inquiry about the tribal right to inspect rail shipments is still an open issue. At the time of the July meeting, the response was in the final stages of review in the Secretary of Transportation's Legal Division. The response will be forwarded

  16. Quarterly Progress Report for the Chemical and Energy Research Section of the Chemical Technology Division: July-September 1999

    SciTech Connect (OSTI)

    Jubin, R.T.

    2001-04-16

    This report summarizes the major activities conducted in the Chemical and Energy Research Section of the Chemical Technology Division at Oak Ridge National Laboratory (ORNL) during the period July-September 1999. The section conducts basic and applied research and development in chemical engineering, applied chemistry, and bioprocessing, with an emphasis on energy-driven technologies and advanced chemical separations for nuclear and waste applications. The report describes the various tasks performed within ten major areas of research: Hot Cell Operations, Process Chemistry, Molten Salt Reactor Experiment (MSRE) Remediation Studies, Chemistry Research, Physical Properties Research, Biochemical Engineering, Separations and Materials Synthesis, Fluid Structures and Properties, Biotechnology Research, and Molecular Studies. The name of a technical contact is included with each task described, and readers are encouraged to contact these individuals if they need additional information. Activities conducted within the area of the Cell Operations involved the testing of two continuously stirred tank reactors in series to evaluate the Savannah River-developed process of small-tank tetraphenylborate precipitation to remove cesium, strontium and transuranics from supernatant. Within the area of Process Chemistry, various topics related to solids formation in process solutions from caustic treatment of Hanford sludge were addressed. Saltcake dissolution efforts continued, including the development of a predictive algorithm. New initiatives for the section included modeling activities centered on detection of hydrogen in {sup 233}U storage wells and wax formation in petroleum mixtures, as well as support for the Spallation Neutron Source (investigation of transmutation products formed during operation). Other activities involved in situ grouting and evaluation of options for use (i.e., as castable shapes) of depleted uranium. In a continuation of activities of the preceding quarter, MSRE Remediation Studies focused on recovery of {sup 233}U and its conversion to a stable oxide and radiolysis experiments to permit remediation of MSRE fuel salt. Investigation of options for final disposition of the {sup 233}U inventory represents a new initiative within this area. In the area of Chemistry Research, activities included studies relative to molecular imprinting for use in areas such as selective sorption, chemical sensing, and catalysis, as well as spectroscopic investigation into the fundamental interaction between ionic solvents and solutes in both low- and high-temperature ionic liquids.

  17. Tansmutation Research program

    SciTech Connect (OSTI)

    Seidler, Paul

    2011-07-31

    Six years of research was conducted for the United States Department of Energy, Office of Nuclear Energy between the years of 2006 through 2011 at the University of Nevada, Las Vegas (UNLV). The results of this research are detailed in the narratives for tasks 1-45. The work performed spanned the range of experimental and modeling efforts. Radiochemistry (separations, waste separation, nuclear fuel, remote sensing, and waste forms) , material fabrication, material characterization, corrosion studies, nuclear criticality, sensors, and modeling comprise the major topics of study during these six years.

  18. Additional EIPC Study Analysis: Interim Report on High Priority Topics

    SciTech Connect (OSTI)

    Hadley, Stanton W

    2013-11-01

    Between 2010 and 2012 the Eastern Interconnection Planning Collaborative (EIPC) conducted a major long-term resource and transmission study of the Eastern Interconnection (EI). With guidance from a Stakeholder Steering Committee (SSC) that included representatives from the Eastern Interconnection States Planning Council (EISPC) among others, the project was conducted in two phases. Phase 1 involved a long-term capacity expansion analysis that involved creation of eight major futures plus 72 sensitivities. Three scenarios were selected for more extensive transmission- focused evaluation in Phase 2. Five power flow analyses, nine production cost model runs (including six sensitivities), and three capital cost estimations were developed during this second phase. The results from Phase 1 and 2 provided a wealth of data that could be examined further to address energy-related questions. A list of 13 topics was developed for further analysis; this paper discusses the first five.

  19. TEC Working Group Topic Groups Manual Review Key Documents | Department of

    Energy Savers [EERE]

    Energy Manual Review Key Documents TEC Working Group Topic Groups Manual Review Key Documents Key Documents PDF icon Transportation Practices Manual (DOE M 460) - March 8, 2006 More Documents & Publications DOE Shipment Activities: What We Accomplished and a Look Forward TEC Working Group Topic Groups Section 180(c) Key Documents TEC Working Group Topic Groups Rail Key Documents

  20. Operando X-ray absorption and EPR evidence for a single electron redox process in copper catalysis

    SciTech Connect (OSTI)

    Lu, Qingquan; Zhang, Jian; Peng, Pan; Zhang, Guanghui; Huang, Zhiliang; Yi, Hong; Miller, Jeffrey T.; Lei, Aiwen

    2015-05-26

    An unprecedented single electron redox process in copper catalysis is confirmed using operando X-ray absorption and EPR spectroscopies. The oxidation state of the copper species in the interaction between Cu(II) and a sulfinic acid at room temperature, and the accurate characterization of the formed Cu(I) are clearly shown using operando X-ray absorption and EPR evidence. Further investigation of anion effects on Cu(II) discloses that bromine ions can dramatically increase the rate of the redox process. Moreover, it is proven that the sulfinic acids are converted into sulfonyl radicals, which can be trapped by 2-arylacrylic acids and various valuable β-keto sulfones are synthesized with good to excellent yields under mild conditions.

  1. Operando X-ray absorption and EPR evidence for a single electron redox process in copper catalysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lu, Qingquan; Zhang, Jian; Peng, Pan; Zhang, Guanghui; Huang, Zhiliang; Yi, Hong; Miller, Jeffrey T.; Lei, Aiwen

    2015-05-26

    An unprecedented single electron redox process in copper catalysis is confirmed using operando X-ray absorption and EPR spectroscopies. The oxidation state of the copper species in the interaction between Cu(II) and a sulfinic acid at room temperature, and the accurate characterization of the formed Cu(I) are clearly shown using operando X-ray absorption and EPR evidence. Further investigation of anion effects on Cu(II) discloses that bromine ions can dramatically increase the rate of the redox process. Moreover, it is proven that the sulfinic acids are converted into sulfonyl radicals, which can be trapped by 2-arylacrylic acids and various valuable β-keto sulfonesmore » are synthesized with good to excellent yields under mild conditions.« less

  2. Crystal Structure of 12-Lipoxygenase Catalytic-Domain-Inhibitor Complex Identifies a Substrate-Binding Channel for Catalysis

    SciTech Connect (OSTI)

    Xu, Shu; Mueser, Timothy C.; Marnett, Lawrence J.; Funk, Jr., Max O.

    2014-10-02

    Lipoxygenases are critical enzymes in the biosynthesis of families of bioactive lipids including compounds with important roles in the initiation and resolution of inflammation and in associated diseases such as diabetes, cardiovascular disease, and cancer. Crystals diffracting to high resolution (1.9 {angstrom}) were obtained for a complex between the catalytic domain of leukocyte 12-lipoxygenase and the isoform-specific inhibitor, 4-(2-oxapentadeca-4-yne)phenylpropanoic acid (OPP). In the three-dimensional structure of the complex, the inhibitor occupied a new U-shaped channel open at one end to the surface of the protein and extending past the redox-active iron site that is essential for catalysis. In models, the channel accommodated arachidonic acid, defining the binding site for the substrate of the catalyzed reaction. There was a void adjacent to the OPP binding site connecting to the surface of the enzyme and providing a plausible access channel for the other substrate, oxygen.

  3. Methanol Synthesis over Cu/ZnO/Al2O3: The Active Site in Industrial Catalysis

    SciTech Connect (OSTI)

    Behrens, Malte

    2012-03-28

    Unlike homogeneous catalysts, heterogeneous catalysts that have been optimized through decades are typically so complex and hard to characterize that the nature of the catalytically active site is not known. This is one of the main stumbling blocks in developing rational catalyst design strategies in heterogeneous catalysis. We show here how to identify the crucial atomic structure motif for the industrial Cu/ZnO/Al{sub 2}O{sub 3} methanol synthesis catalyst. Using a combination of experimental evidence from bulk-, surface-sensitive and imaging methods collected on real high-performance catalytic systems in combination with DFT calculations. We show that the active site consists of Cu steps peppered with Zn atoms, all stabilized by a series of well defined bulk defects and surface species that need jointly to be present for the system to work.

  4. Request for Information (RFI): Clean Energy Manufacturing Topics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The purpose of this RFI is to solicit feedback from industry, academia, research ... addressed could provide the underlying motivation for the formation of a manufacturing ...

  5. Homesteading on the Pajarito Plateau topic of inaugural lecture...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to...

  6. SSLS Coffee/Dessert Hour Calendar of Topics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Energy Wind Energy Water Power Supercritical CO2 ... Applications National Solar Thermal Test Facility Nuclear ... 10, 2009 Jeff Tsao What's Hot in SSL Research September ...

  7. TRIBAL ISSUES TOPIC GROUP MEETING SUMMARY JACKSONVILLE, FL

    Office of Environmental Management (EM)

    also discussed the research that has been conducted on the issue of developing a "umbrella grant" from DOE to states and tribes. Tribes concerns differ from State concerns...

  8. Biochemical Conversion: Using Enzymes, Microbes, and Catalysis to Make Fuels and Chemicals

    SciTech Connect (OSTI)

    2013-07-26

    This fact sheet describes the Bioenergy Technologies Office's biochemical conversion work and processes. BETO conducts collaborative research, development, and demonstration projects to improve several processing routes for the conversion of cellulosic biomass.

  9. AMO Requests Technical Topics Suitable for a Manufacturing Innovation Institute

    Broader source: Energy.gov [DOE]

    The Advanced Manufacturing Office (AMO) seeks information on mid-Technology Readiness Level (TRL) research and development (R&D) needs, market challenges, supply chain challenges, and shared facility needs to address challenges associated with clean energy manufacturing.

  10. Events & Topics in Renewable Energy & the Environment | Photosynthetic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & the Environment Tyson Research Center tour April 14, 2015 - 3:15pm Tyson Living Learning Center - April 14th, 3:15 - 5:00pm Attendees will tour the Living Learning Center,...

  11. Research Mentors

    Broader source: Energy.gov [DOE]

    Research mentors are scientists and engineers committed to support and guide the applicant's research activities during the Research Award. Research mentors must be currently conducting or...

  12. DOE Research and Development Accomplishments What's New

    Office of Scientific and Technical Information (OSTI)

    What's New The What's New page contains information about recent developments on Department of Energy (DOE) Research and Development (R&D) Accomplishments, including additions of Database reports, Snapshots, Featured Topics, and other related topics of interest. It is divided into general categories: Recently Added Features , Recently Added Database Reports, and Recently Added Laureates. RSS News Feed - brief announcements about additions to the DOE R&D Accomplishments Recently Added

  13. Research Mission - Rotating Wall Machine - UW Plasma Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Mission UW Madison Line Tied Reconnection Experiment Research Mission LTRX HomeResearch MissionLTRX DevicePhysics TopicsDiagnosticsLTRX GalleryLTRX People CPLA Home Directory Publications Links University of Wisconsin Physics Department Department of Energy National Science Foundation Background Magnetohydrodynamic (MHD) instability of current carrying plasmas is a topic of importance to astrophysical and laboratory plasmas. In the Sun, current driven MHD instability is believed

  14. Research Mission - MST - UW Plasma Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Mission UW Madison Madison Symmetric Torus Research Mission MST HomeGraduate Student InformationLinksTourControl and Auxiliary SystemsPhysics TopicsDeviceResearch MissionMST People mst logo CPLA Home Directory Publications Links Internal University of Wisconsin Physics Department Research funding includes support from: Department of Energy National Science Foundation Additional Information: Information for Prospective Graduate Students With the MST facility, physicists study hot plasmas

  15. Current Postdoctoral Researchers | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Current Postdocs Current Postdoctoral Researchers Name Topic - Any - General Argonne Information -Awards -Honors Energy -Energy efficiency --Vehicles ---Alternative fuels ---Automotive engineering ---Biofuels ---Diesel ---Electric drive technology ---Fuel economy ---Fuel injection ---Heavy-duty vehicles ---Hybrid & electric vehicles ---Hydrogen & fuel cells ---Internal combustion ---Maglev systems ---Powertrain research ---Vehicle testing --Building design ---Construction ---Industrial

  16. Multiferroicity of Carbon-Based Charge-Transfer Magnets (Journal...

    Office of Scientific and Technical Information (OSTI)

    Research Org: Energy Frontier Research Centers (EFRC); Argonne-Northwestern Solar Energy ... Subject: catalysis (homogeneous), catalysis (heterogeneous), solar (photovoltaic), solar ...

  17. Vehicle Technologies Office Issues Notice of Intent for Multi-Topic Funding

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Opportunity Announcement | Department of Energy Multi-Topic Funding Opportunity Announcement Vehicle Technologies Office Issues Notice of Intent for Multi-Topic Funding Opportunity Announcement April 26, 2016 - 10:16am Addthis The Vehicle Technologies Office has issued a Notice of Intent (No. DE-FOA-0001534) to make interested parties aware of its plan to issue a Funding Opportunity Announcement (FOA) entitled "FY 2016 Vehicle Technologies Multi-Topic Funding Opportunity

  18. Classification of Distributed Data Using Topic Modeling and Maximum Variation Sampling

    SciTech Connect (OSTI)

    Patton, Robert M; Beaver, Justin M; Potok, Thomas E

    2011-01-01

    From a management perspective, understanding the information that exists on a network and how it is distributed provides a critical advantage. This work explores the use of topic modeling as an approach to automatically determine the classes of information that exist on an organization's network, and then use the resultant topics as centroid vectors for the classification of individual documents in order to understand the distribution of information topics across the enterprise network. The approach is tested using the 20 Newsgroups dataset.

  19. TEC Working Group Topic Groups Archives Mechanics of Funding and Techical

    Office of Environmental Management (EM)

    Assistance | Department of Energy Mechanics of Funding and Techical Assistance TEC Working Group Topic Groups Archives Mechanics of Funding and Techical Assistance Mechanics of Funding and Techical Assistance Items Available for Download PDF icon Funding Mechanisms Comparison Matrix More Documents & Publications TEC Working Group Topic Groups Section 180(c) Key Documents Implementation of Section 180(c) of the Nuclear Waste Policy Act TEC Working Group Topic Groups Tribal Conference Call

  20. List of Topics for Interagency Performance & Risk Assessment Community of

    Energy Savers [EERE]

    Practice (P&RA CoP) Discussion | Department of Energy List of Topics for Interagency Performance & Risk Assessment Community of Practice (P&RA CoP) Discussion List of Topics for Interagency Performance & Risk Assessment Community of Practice (P&RA CoP) Discussion List of Topics for Interagency Performance & Risk Assessment Community of Practice (P&RA CoP) Discussion PDF icon List of Topics - February 24, 2016 More Documents & Publications Status Updates on the

  1. Transportation Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    transportation-research TRACC RESEARCH Computational Fluid Dynamics Computational Structural Mechanics Transportation Systems Modeling Transportation Research Current Research Overview The U.S. Department of Transportation (USDOT) has established its only high-performance computing and engineering analysis research facility at Argonne National Laboratory to provide applications support in key areas of applied research and development for the USDOT community. The Transportation Research and

  2. Investigations on detonation shock dynamics and related topics. Final report

    SciTech Connect (OSTI)

    Stewart, D.S.

    1993-11-01

    This document is a final report that summarizes the research findings and research activities supported by the subcontract DOE-LANL-9-XG8-3931P-1 between the University of Illinois (D. S. Stewart Principal Investigator) and the University of California (Los Alamos National Laboratory, M-Division). The main focus of the work has been on investigations of Detonation Shock Dynamics. A second emphasis has been on modeling compaction of energetic materials and deflagration to detonation in those materials. The work has led to a number of extensions of the theory of Detonation Shock Dynamics (DSD) and its application as an engineering design method for high explosive systems. The work also enhanced the hydrocode capabilities of researchers in M-Division by modifications to CAVEAT, an existing Los Alamos hydrocode. Linear stability studies of detonation flows were carried out for the purpose of code verification. This work also broadened the existing theory for detonation. The work in this contract has led to the development of one-phase models for dynamic compaction of porous energetic materials and laid the groundwork for subsequent studies. Some work that modeled the discrete heterogeneous behavior of propellant beds was also performed. The contract supported the efforts of D. S. Stewart and a Postdoctoral student H. I. Lee at the University of Illinois.

  3. Research Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Gallery Research Gallery Exhibits in this gallery capture Laboratory's leading-edge research in many areas of science and technology to help solve national problems...

  4. Microsoft PowerPoint - TranspTopics_Sullivan

    Office of Environmental Management (EM)

    West Valley Demonstration Project Low-Level Waste Shipment Daniel Sullivan Federal Project Director Department of Energy/West Valley Demonstration Project May, 2014 www.energy.gov/EM 2 * U.S. Department of Energy Project * ~35 miles south of Buffalo, New York * New York State Energy Research and Development Authority (NYSERDA) holds title to the 3,345 acre site West Valley Demonstration Project (WVDP) Location of the West Valley Site United States 5/16/2014 2 www.energy.gov/EM 3 History 1962

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Submitter: Area of Research: Journal Reference: N/A

  6. Center for Nanophase Materials Sciences (CNMS) - CNMS User Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Achievement: The material of choice for spintronics device today is FeMgOFe tunnel ... by modi?cation of the interface is an important topic in spintronics research. ...

  7. Low-rank coal research

    SciTech Connect (OSTI)

    Weber, G. F.; Laudal, D. L.

    1989-01-01

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  8. Catalytic conversion of light alkanes, Phase 3. Topical report, January 1990--December 1992

    SciTech Connect (OSTI)

    1992-12-31

    The mission of this work is to devise a new catalyst which can be used in the first simple, economic process to convert the light alkanes in natural gas to an alcohol-rich oxygenated product which can either be used as an environmentally friendly, high-performance liquid fuel, or a precursor to a liquid hydrocarbon transportation fuel. The authors have entered the proof-of-concept stage for converting isobutane to tert butyl alcohol in a practical process and are preparing to enter proof-of-concept of a propane to isopropyl alcohol process in the near future. Methane and ethane are more refractory and thus more difficult to oxidize than the C{sub 3} and C{sub 4} hydrocarbons. Nonetheless, advances made in this area indicate that further research progress could achieve the goal of their direct conversion to alcohols. Progress in Phase 3 catalytic vapor phase methane and ethane oxidation over metals in regular oxidic lattices are the subject of this topical report.

  9. NREL, German Solar Energy Researchers to Work Together - News Releases |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL NREL, German Solar Energy Researchers to Work Together Scientists from the two nations to collaborate on next-generation PV and fuels June 23, 2011 German and American researchers will work together more closely on solar energy topics as a result of today's signing of a Memo of Understanding (MOU) between the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) and the German Helmholtz Association. The MOU identifies several key solar energy topics to explore for

  10. Laboratory Directed Research & Development Page National Energy Research Scientific Computing Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Directed Research & Development Page National Energy Research Scientific Computing Center T3E Individual Node Optimization Michael Stewart, SGI/Cray, 4/9/98 * Introduction * T3E Processor * T3E Local Memory * Cache Structure * Optimizing Codes for Cache Usage * Loop Unrolling * Other Useful Optimization Options * References 1 Laboratory Directed Research & Development Page National Energy Research Scientific Computing Center Introduction * Primary topic will be single processor

  11. Plasma Catalysis for NOx Reduction from Light-Duty Diesel Vehicles

    SciTech Connect (OSTI)

    2005-12-15

    On behalf of the Department of Energy's Office of FreedomCAR and Vehicle Technologies, we are pleased to introduce the Fiscal Year (FY) 2004 Annual Progress Report for the Advanced Combustion Engine R&D Sub-Program. The mission of the FreedomCAR and Vehicle Technologies Program is to develop more energy efficient and environmentally friendly highway transportation technologies that enable Americans to use less petroleum for their vehicles. The Advanced Combustion Engine R&D Sub-Program supports this mission by removing the critical technical barriers to commercialization of advanced internal combustion engines for light-, medium-, and heavy-duty highway vehicles that meet future Federal and state emissions regulations. The primary objective of the Advanced Combustion Engine R&D Sub-Program is to improve the brake thermal efficiency of internal combustion engines from 30 to 45 percent for light-duty applications by 2010; and 40 to 55 percent for heavy-duty applications by 2012; while meeting cost, durability, and emissions constraints. R&D activities include work on combustion technologies that increase efficiency and minimize in-cylinder formation of emissions, as well as aftertreatment technologies that further reduce exhaust emissions. Work is also being conducted on ways to reduce parasitic and heat transfer losses through the development and application of thermoelectrics and turbochargers that include electricity generating capability, and conversion of mechanically driven engine components to be driven via electric motors. This introduction serves to outline the nature, current progress, and future directions of the Advanced Combustion Engine R&D Sub-Program. The research activities of this Sub-Program are planned in conjunction with the FreedomCAR Partnership and the 21st Century Truck Partnership and are carried out in collaboration with industry, national laboratories, and universities. Because of the importance of clean fuels in achieving low emissions, R&D activities are closely coordinated with the relevant activities of the Fuel Technologies Sub-Program, also within the Office of FreedomCAR and Vehicle Technologies. Research is also being undertaken on hydrogen-fueled internal combustion engines to provide an interim hydrogen-based powertrain technology that promotes the longer-range FreedomCAR Partnership goal of transitioning to a hydrogen-fueled transportation system. Hydrogen engine technologies being developed have the potential to provide diesel-like engine efficiencies with near-zero emissions.

  12. Organusulfur Catalysis With Reduced Molybdenum Sulfides Containing the Mo6S8 Cluster

    SciTech Connect (OSTI)

    Thomas Jay Paskach

    2002-08-27

    Industrial synthesis of sulfur-containing organic chemicals basically focuses on the broad categories of mercaptans (thiols), alkylsulfides (thioethers), polysulfides, and thiophenes. Of the organo-sulfur compounds produced, by far the most important in terms of quantities produced is methyl mercaptan (methanethiol or MeSH), which is produced mainly for the downstream production of methionine and methanesulfonyl chloride. Higher thiols are also used in the manufacture of rubber and plastics as polymerization regulators, chain transfer agents, or initiators. Other important organosulfur chemicals are dimethyl sulfide (DMS) and dimethyl disulfide (DMDS), both of which are used extensively for presulfiding of industrial hydroprocessing catalysts, and substituted thiophenes which are used as intermediates for production of agrochemicals, dyes, and pharmaceuticals. Thiols are produced commercially at the rate of about 10{sup 4} ton/yr from hydrogen sulfide (H{sub 2}S) and alcohols or olefins, using homogeneous free-radical synthesis, or heterogeneous catalysts based on solid acids or supported metal oxides and/or sulfides. Despite this large production rate, and the industrial importance of the organosulfur compounds, only limited research has been devoted to the development of new catalytic materials for their synthesis. Additionally, for most organosulfur catalytic reactions, only limited information exists about reaction mechanisms, active sites, adsorbed surface species, and especially the nature of the catalysts under reaction conditions.

  13. Superacid catalysis of light hydrocarbon conversion. Final report, August 26, 1993--August 26, 1996

    SciTech Connect (OSTI)

    Gates, B.C.

    1996-12-31

    Motivated by the goal of finding improved catalysts for low- temperature conversion of light alkanes into fuel components or precursors of fuel components, the researchers have investigated sulfated zirconia and promoted sulfated zirconia for conversion of butane, propane, and ethane. Catalyst performance data for sulfated zirconia promoted with iron and manganese show that it is the most active noncorrosive, nonhalide catalyst known for n-butane isomerization, and it is an excellent candidate catalyst for new low- temperature n-butane isomerization processes to make isobutane, which can be converted by established technology into methyl t-butyl ether (MTBE). Various transition metals have been found to work as promoters of sulfated zirconia for n-butane isomerization. The combination of iron and manganese is the best known combination of promoters yet discovered. The iron- and manganese-promoted sulfated zirconia is also a catalyst for conversion of propane and of ethane. Ethane is converted into ethylene and butanes in the presence of the iron- and manganese-promoted sulfated zirconia; propane is also converted into butane, among other products. However, the activities of the catalyst for these reactions are orders of magnitude less than the activity for n-butane conversion, and there is no evidence that the catalyst would be of practical value for conversion of alkanes lighter than butane. The product distribution data for ethane and propane conversion provide new insights into the nature of the catalyst and its acidity. These data suggest the involvement of Olah superacid chemistry, whereby the catalyst protonates the alkane itself, giving carbonium ions (as transition states). The mechanism of protonation of the alkane may also pertain to the conversion of butane, but there is good evidence that the butane conversion also proceeds via alkene intermediates by conventional mechanisms of carbenium ion formation and rearrangement.

  14. Chemical Engineering Division research highlights, 1979

    SciTech Connect (OSTI)

    Burris, L.; Webster, D. S.; Barney, D. L.; Cafasso, F. A.; Steindler, M. J.

    1980-06-01

    In 1979, CEN conducted research and development in the following areas: (1) high-temperature, rechargeable lithium/iron sulfide batteries for electric vehicles and electric utility load leveling; (2) ambient-temperature batteries - improved lead-acid, nickel/zinc, and nickel/iron - for electric vehicles; (3) molten carbonate fuel cells for use by electric utilities; (4) coal technology - mainly fluidized-bed combustion of coal in the presence of SO/sub 2/ sorbent of limestone; (5) heat- and seed- recovery technology for open-cycle magnetohydrodynamic systems; (6) solar energy collectors and thermal energy storage; (7) fast breeder reactor chemistry research - chemical support of reactor safety studies, chemistry of irradiated fuels, and sodium technology; (8) fuel cycle technology - reprocessing of nuclear fuels, management of nuclear wastes, geologic migration studies, and proof-of-breeding studies for the Light Water Breeder Reactor; (9) magnetic fusion research - lithium processing technology and materials research; and (10) basic energy sciences - homogeneous catalysis, thermodynamics of inorganic and organic materials, environmental chemistry, electrochemistry, and physical properties of salt vapors. Separate abstracts were prepared for each of these areas.

  15. Research Highlights

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Highlights Form Submit a New Research Highlight Sort Highlights Submitter Title Research Area Working Group Submission Date DOE Progress Reports Notable Research Findings for 2001-2006 Office of Science Abstracts Database Research Highlights Summaries Research Highlights Members of ARM's science team are major contributors to radiation and cloud research. ARM investigators publish about 150 refereed journal articles per year, and ARM data are used in many studies published by other scientific

  16. Accelerator and Fusion Research Division 1989 summary of activities

    SciTech Connect (OSTI)

    Not Available

    1990-06-01

    This report discusses the research being conducted at Lawrence Berkeley Laboratory's Accelerator and Fusion Research Division. The main topics covered are: heavy-ion fusion accelerator research; magnetic fusion energy; advanced light source; center for x-ray optics; exploratory studies; high-energy physics technology; and bevalac operations.

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rotstayn, L., Commonwealth Scientific and Industrial Research Organization Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: Rotstayn, L.,...

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chinese Researchers Report Reliable Method for Monitoring Soil Moisture Submitter: Bhattacharya, A., Pacific Northwest National Laboratory Area of Research: Surface Properties...

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Testing and Comparing the Modified Anomalous Diffraction Approximation Submitter: Mitchell, D. L., Desert Research Institute Area of Research: Cloud DistributionsCharacterizations...

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a printable PDF Submitter: Schmid, B., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: ARM Climate Research...

  1. Research Projects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Current Research Projects Joint Los Alamos National LaboratoryUCSD Research Projects Collaborations between Los Alamos National Laboratory and the University of California at San...

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Ensemble Simulation with the ARM IOP Data Submitter: Xu, K., NASA - Langley Research Center Area of Research: General Circulation and Single Column ModelsParameterizations ...

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM Measurements Validate New Satellite Multilayer Cloud Remote Sensing Method Submitter: Minnis, P., NASA - Langley Research Center Area of Research: Cloud Distributions...

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Terrestrial Radiation Download a printable PDF Submitter: Mitchell, D. L., Desert Research Institute Area of Research: General Circulation and Single Column Models...

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fog and Rain in the Amazon For original submission and image(s), see ARM Research Highlights http:www.arm.govsciencehighlights Research Highlight The diurnal and seasonal...

  6. Bioinspired design of redox-active ligands for multielectron catalysis: Effects of positioning pyrazine reservoirs on cobalt for electro- and photocatalytic generation of hydrogen from water

    SciTech Connect (OSTI)

    Jurss, Jonah W.; Khnayzer, Rony S.; Panetier, Julien A.; El Roz, Karim A.; Nichols, Eva M.; Head-Gordon, Martin; Long, Jeffrey R.; Castellano, Felix N.; Chang, Christopher J.

    2015-06-09

    Mononuclear metalloenzymes in nature can function in cooperation with precisely positioned redox-active organic cofactors in order to carry out multielectron catalysis. Inspired by the finely tuned redox management of these bioinorganic systems, we present the design, synthesis, and experimental and theoretical characterization of a homologous series of cobalt complexes bearing redox-active pyrazines. These donor moieties are locked into key positions within a pentadentate ligand scaffold in order to evaluate the effects of positioning redox non-innocent ligands on hydrogen evolution catalysis. Both metal- and ligand-centered redox features are observed in organic as well as aqueous solutions over a range of pH values, and comparison with analogs bearing redox-inactive zinc(II) allows for assignments of ligand-based redox events. Varying the geometric placement of redox non-innocent pyrazine donors on isostructural pentadentate ligand platforms results in marked effects on observed cobalt-catalyzed proton reduction activity. Electrocatalytic hydrogen evolution from weak acids in acetonitrile solution, under diffusion-limited conditions, reveals that the pyrazine donor of axial isomer 1-Co behaves as an unproductive electron sink, resulting in high overpotentials for proton reduction, whereas the equatorial pyrazine isomer complex 2-Co is significantly more active for hydrogen generation at lower voltages. Addition of a second equatorial pyrazine in complex 3-Co further minimizes overpotentials required for catalysis. The equatorial derivative 2-Co is also superior to its axial 1-Co congener for electrocatalytic and visible-light photocatalytic hydrogen generation in biologically relevant, neutral pH aqueous media. Density functional theory calculations (B3LYP-D2) indicate that the first reduction of catalyst isomers 1-Co, 2-Co, and 3-Co is largely metal-centered while the second reduction occurs at pyrazine. Taken together, the data establish that proper positioning of non-innocent pyrazine ligands on a single cobalt center is indeed critical for promoting efficient hydrogen catalysis in aqueous media, akin to optimally positioned redox-active cofactors in metalloenzymes. In a broader sense, these findings highlight the significance of electronic structure considerations in the design of effective electron–hole reservoirs for multielectron transformations.

  7. Bioinspired design of redox-active ligands for multielectron catalysis: Effects of positioning pyrazine reservoirs on cobalt for electro- and photocatalytic generation of hydrogen from water

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jurss, Jonah W.; Khnayzer, Rony S.; Panetier, Julien A.; El Roz, Karim A.; Nichols, Eva M.; Head-Gordon, Martin; Long, Jeffrey R.; Castellano, Felix N.; Chang, Christopher J.

    2015-06-09

    Mononuclear metalloenzymes in nature can function in cooperation with precisely positioned redox-active organic cofactors in order to carry out multielectron catalysis. Inspired by the finely tuned redox management of these bioinorganic systems, we present the design, synthesis, and experimental and theoretical characterization of a homologous series of cobalt complexes bearing redox-active pyrazines. These donor moieties are locked into key positions within a pentadentate ligand scaffold in order to evaluate the effects of positioning redox non-innocent ligands on hydrogen evolution catalysis. Both metal- and ligand-centered redox features are observed in organic as well as aqueous solutions over a range of pHmore » values, and comparison with analogs bearing redox-inactive zinc(II) allows for assignments of ligand-based redox events. Varying the geometric placement of redox non-innocent pyrazine donors on isostructural pentadentate ligand platforms results in marked effects on observed cobalt-catalyzed proton reduction activity. Electrocatalytic hydrogen evolution from weak acids in acetonitrile solution, under diffusion-limited conditions, reveals that the pyrazine donor of axial isomer 1-Co behaves as an unproductive electron sink, resulting in high overpotentials for proton reduction, whereas the equatorial pyrazine isomer complex 2-Co is significantly more active for hydrogen generation at lower voltages. Addition of a second equatorial pyrazine in complex 3-Co further minimizes overpotentials required for catalysis. The equatorial derivative 2-Co is also superior to its axial 1-Co congener for electrocatalytic and visible-light photocatalytic hydrogen generation in biologically relevant, neutral pH aqueous media. Density functional theory calculations (B3LYP-D2) indicate that the first reduction of catalyst isomers 1-Co, 2-Co, and 3-Co is largely metal-centered while the second reduction occurs at pyrazine. Taken together, the data establish that proper positioning of non-innocent pyrazine ligands on a single cobalt center is indeed critical for promoting efficient hydrogen catalysis in aqueous media, akin to optimally positioned redox-active cofactors in metalloenzymes. In a broader sense, these findings highlight the significance of electronic structure considerations in the design of effective electron–hole reservoirs for multielectron transformations.« less

  8. Medical Applications of Non-Medical Research: Applications Derived from BES-Supported Research and Research at BES Facilities

    DOE R&D Accomplishments [OSTI]

    1998-07-01

    This publication contains stories that illustrate how the Office of Basic Energy Sciences (BES) research and major user facilities have impacted the medical sciences in the selected topical areas of disease diagnosis, treatment (including drug development, radiation therapy, and surgery), understanding, and prevention.

  9. SBIR/STTR Phase I Release 2 Technical Topics Announced for FY14...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Addthis On October 31, the U.S. Department of Energy announced the Fiscal Year 2014 Small ... These topics include prototype fuel cell-battery electric hybrid trucks for waste ...

  10. AMO Issues Request for Information on Clean Energy Manufacturing Topics, Including Fuel Cell and Hydrogen Applications

    Broader source: Energy.gov [DOE]

    The AMO seeks information on mid-Technology Readiness Level R&D needs, market challenges, supply chain challenges, and shared facility needs addressing clean energy manufacturing topics, including the fuel cell and hydrogen sectors.

  11. Groundwater Strategy Document Is Topic of Discussion at November Advisory Board Meeting

    Broader source: Energy.gov [DOE]

    A strategy document developed to address problems with contaminated groundwater on the Department of Energys (DOE) Oak Ridge Reservation (ORR) will be the primary topic of discussion during the November 13 meeting.

  12. Final Report (2010-2015) for the Topical Collaboration on Quantitative Jet

    Office of Scientific and Technical Information (OSTI)

    and Electromagnetic Tomography (JET) of Extreme Phases of Matter in Heavy-ion Collisions (Technical Report) | SciTech Connect Technical Report: Final Report (2010-2015) for the Topical Collaboration on Quantitative Jet and Electromagnetic Tomography (JET) of Extreme Phases of Matter in Heavy-ion Collisions Citation Details In-Document Search Title: Final Report (2010-2015) for the Topical Collaboration on Quantitative Jet and Electromagnetic Tomography (JET) of Extreme Phases of Matter in

  13. JLab announces two Spring Science Series events - topics include 'scale of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    universe' and 'how things work' | Jefferson Lab announces two Spring Science Series events - topics include 'scale of universe' and 'how things work' Jefferson Lab announces two Spring Science Series events - topics include 'scale of universe' and 'how things work' January 19, 2006 Jefferson Lab's 2006 Spring Science Series kicks off at 7 p.m. on Tuesday, Feb. 21, in the CEBAF Center auditorium with astronomer, teacher and author Jeffrey Bennett from the University of Colorado (Boulder)

  14. 19th Topical Conference on Radio Frequency Power in Plasmas | Princeton

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plasma Physics Lab June 1, 2011, 9:00am to June 3, 2011, 5:00pm Conference Newport, Rhode Island 19th Topical Conference on Radio Frequency Power in Plasmas Target audience Fusion scientists and engineers, plasma physicists, RF engineers, theoretical physicists and specialists of plasma-wave interaction, students. Topics of the conference Wave interaction with plasmas, such as heating, current generation, diagnostics, and confinement and profile control. RF applications in fusion devices,

  15. TEC Working Group Topic Groups Tribal Key Documents | Department of Energy

    Office of Environmental Management (EM)

    Key Documents TEC Working Group Topic Groups Tribal Key Documents Key Documents PDF icon Tribal Discussions on Grant Program PDF icon Native American Map PDF icon Task Plan 1 - Tribal Topic Group (Rev. 07-12-00) PDF icon May 1, 2000 Department of Transportation, Federal Railroad Administration Memorandum PDF icon NRC Advanced Notice of Proposed Rulemaking PDF icon DOE Final Indian Policy PDF icon Department of Transportation (DOT) Tribal Policy Order More Documents & Publications TEC Working

  16. Microsoft Word - Tribal Topic Group Summary March 06 final _3_.doc

    Office of Environmental Management (EM)

    Formatted: Position: Horizontal: Right, Relative to: Margin, Vertical: 0", Relative to: Paragraph, Wrap Around Summary TEC Tribal Topic Group Meeting Tuesday, March 14, 2006 Washington, DC Participants: Jay Jones, Department of Energy (DOE)/Office of Civilian Radioactive Waste Management (OCRWM), chaired the session. Other Topic Group members included Richard Arnold (Pahrump Paiute Tribe/Consolidated Group of Tribes and Organizations), James Baranski (NY State Emergency Management Office),

  17. Proceedings of the 1992 topical meeting on advances in reactor physics. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1992-04-01

    This document, Volume 2, presents proceedings of the 1992 Topical Meeting on Advances in Reactor Physics on March 8--11, 1992 at Charleston, SC. Session topics were as follows: Transport Theory; Fast Reactors; Plant Analyzers; Integral Experiments/Measurements & Analysis; Core Computational Systems; Reactor Physics; Monte Carlo; Safety Aspects of Heavy Water Reactors; and Space-Time Core Kinetics. The individual reports have been cataloged separately. (FI)

  18. Research Mission

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Mission Research Mission NETL's Office of Research & Development is a national resource for fossil energy research and development, with a mission to create and expand the knowledge base that enables the safe, sustainable utilization of our abundant, domestic energy resources. In support of that mission, the onsite research effort: Develops solutions to key barriers to the implementation of emerging energy technologies. Explores transformational new concepts for next generation

  19. Fluidized-bed retorting of Colorado oil shale: Topical report. [None

    SciTech Connect (OSTI)

    Albulescu, P.; Mazzella, G.

    1987-06-01

    In support of the research program in converting oil shale into useful forms of energy, the US Department of Energy is developing systems models of oil shale processing plants. These models will be used to project the most attractive combination of process alternatives and identify future direction for R and D efforts. With the objective of providing technical and economic input for such systems models, Foster Wheeler was contracted to develop conceptual designs and cost estimates for commercial scale processing plants to produce syncrude from oil shales via various routes. This topical report summarizes the conceptual design of an integrated oil shale processing plant based on fluidized bed retorting of Colorado oil shale. The plant has a nominal capacity of 50,000 barrels per operating day of syncrude product, derived from oil shale feed having a Fischer Assay of 30 gallons per ton. The scope of the plant encompasses a grassroots facility which receives run of the mine oil shale, delivers product oil to storage, and disposes of the processed spent shale. In addition to oil shale feed, the battery limits input includes raw water, electric power, and natural gas to support plant operations. Design of the individual processing units was based on non-confidential information derived from published literature sources and supplemented by input from selected process licensors. The integrated plant design is described in terms of the individual process units and plant support systems. The estimated total plant investment is similarly detailed by plant section and an estimate of the annual operating requirements and costs is provided. In addition, the process design assumptions and uncertainties are documented and recommendations for process alternatives, which could improve the overall plant economics, are discussed.

  20. DESIGN, SYNTHESIS, AND MECHANISTIC EVALUATION OF IRON-BASED CATALYSIS FOR SYNTHESIS GAS CONVERSION TO FUELS AND CHEMICALS

    SciTech Connect (OSTI)

    Akio Ishikawa; Manuel Ojeda; Enrique Iglesia

    2005-03-31

    This project explores the extension of previously discovered Fe-based catalysts to hydrogen-poor synthesis gas streams derived from coal and biomass sources. These catalysts have previously shown unprecedented Fischer-Tropsch synthesis rate, selectivity with synthesis gas derived from methane. During the first reporting period, we certified a microreactor, installed required analytical equipment, and reproduced synthetic protocols and catalytic performance previously reported. During the second reporting period, we prepared several Fe-based compositions for Fischer-Tropsch synthesis and tested the effects of product recycle under both subcritical and supercritical conditions. During this third reporting period, we have prepared a large number of Fe-based catalyst compositions using precipitation and impregnations methods with both supercritical and subcritical drying and with the systematic use of surface active agents to prevent pore collapse during drying steps required in synthetic protocols. These samples were characterized during this period using X-ray diffraction, surface area, and temperature-programmed reduction measurements. These studies have shown that these synthesis methods lead to even higher surface areas than in our previous studies and confirm the crystalline structures of these materials and their reactivity in both oxide-carbide interconversions and in Fischer-Tropsch synthesis catalysis. Fischer-Tropsch synthesis reaction rates and selectivities with low H{sub 2}/CO ratio feeds (H{sub 2}/CO = 1) were the highest reported in the literature at the low-temperature and relatively low pressure in our measurements. Current studies are exploring the optimization of the sequence of impregnation of Cu, K, and Ru promoters, of the activation and reaction conditions, and of the co-addition of light hydrocarbons to increase diffusion rates of primary olefin products so as to increase the selectivity to unsaturated products. Finally, we are also addressing the detailed kinetic response of optimized catalysts to reaction conditions (temperature, partial pressures of H{sub 2}, CO, H{sub 2}O, CO{sub 2}, olefins) in an effort to further increase rates and olefin and C{sub 5+} selectivities.

  1. Superacid catalysis of light hydrocarbon conversion. DOE PETC seventh quarterly progress report, April 1, 1995--July 31, 1995

    SciTech Connect (OSTI)

    Gates, B.C.

    1996-02-01

    Iron- and manganese-promoted sulfated zirconia is a catalyst for the conversion of propane, but the rate of conversion of propane is much less than the rate of conversion of butane. Whereas this catalyst appears to be a good candidate for practical, industrial conversion of butane, it appears to lack sufficient activity for practical conversion of propane. The propane conversion data reported here provide excellent insights into the chemistry of the catalytic conversion. Solid and catalysts, namely, sulfated zirconia, iron- and manganese-promoted sulfated zirconia, and USY zeolite, were tested for conversion of propane at 1 atm, 200-450{degrees}C, and propane partial pressures in the range of 0.01-0.05 atm. Both promoted and unpromoted sulfated zirconia were found to be active for conversion of propane into butanes, pentanes, methane, ethane, ethylene, and propylene in the temperature range of 200-350{degrees}C, but catalyst deactivation was rapid. At the higher temperatures, only cracking and dehydrogenation products were observed. In contrast to the zirconia-supported catalysts, USY zeolite was observed to convert propane (into propylene, methane, and ethylene) only at temperatures {ge}400{degrees}C. The initial (5 min on stream) rates of propane conversion in the presence of iron- and manganese-promoted sulfated zirconia, sulfated zirconia, and USY zeolite at 450{degrees}C and 0.01 atm propane partial pressure were 3.3 x 10{sup -8}, 0.3 x 10{sup -8}, and 0.06 x 10{sup -8} mol/(s{center_dot}g), respectively. The product distributions in the temperature range 200-450{degrees}C are those of acid-base catalysis, being similar to what has been observed in superacid solution chemistry at temperatures <0{degrees}C. If propane conversion at 450{degrees}C can be considered as a probe of acid strength of the catalyst, the activity comparison suggests that the promoted sulfated zirconia is a stronger acid than sulfated zirconia, which is a stronger acid than USY zeolite.

  2. SIMPLIFIED PREDICTIVE MODELS FOR CO₂ SEQUESTRATION PERFORMANCE ASSESSMENT RESEARCH TOPICAL REPORT ON TASK #3 STATISTICAL LEARNING BASED MODELS

    SciTech Connect (OSTI)

    Mishra, Srikanta; Schuetter, Jared

    2014-11-01

    We compare two approaches for building a statistical proxy model (metamodel) for CO₂ geologic sequestration from the results of full-physics compositional simulations. The first approach involves a classical Box-Behnken or Augmented Pairs experimental design with a quadratic polynomial response surface. The second approach used a space-filling maxmin Latin Hypercube sampling or maximum entropy design with the choice of five different meta-modeling techniques: quadratic polynomial, kriging with constant and quadratic trend terms, multivariate adaptive regression spline (MARS) and additivity and variance stabilization (AVAS). Simulations results for CO₂ injection into a reservoir-caprock system with 9 design variables (and 97 samples) were used to generate the data for developing the proxy models. The fitted models were validated with using an independent data set and a cross-validation approach for three different performance metrics: total storage efficiency, CO₂ plume radius and average reservoir pressure. The Box-Behnken–quadratic polynomial metamodel performed the best, followed closely by the maximin LHS–kriging metamodel.

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SPartICus Submitter: Mishra, S., DOE - SunShot Initiative, AAAS S&T Policy Fellow Mitchell, D. L., Desert Research Institute Area of Research: General Circulation and Single...

  4. 2012 Catalysis Lectures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    his sabbatical period at Stanford University and SLAC. (1) "Characterization of Heterogeneous Catalysts: Possibilities and Limitations of In-situ Spectroscopy" (Part I) Monday,...

  5. Topical Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    INL/EXT-12-25347 March 2012 CIPS Validation Data Plan Nam Dinh CASL-U-2012-0044-000 CASL-U-2012-0044-000 INL/EXT-12-25347 CIPS Validation Data Plan Nam Dinh Published March 2012 Idaho National Laboratory Nuclear Science & Engineering Division Idaho Falls, Idaho 83415 Prepared for the U.S. Department of Energy Office of Nuclear Energy Under U.S. Department of Energy-Idaho Operations Office Contract DE-AC07-99ID13727 CASL-U-2012-0044-000 CASL-U-2012-0044-000 ABSTRACT The Consortium for

  6. Other Topics

    Broader source: Energy.gov [DOE]

    1.  As we continue our preparations for the State Energy Efficient Appliance Rebate Program (SEEARP), we have heard that there is a possibility that IRS regulations require States to provide a 1099...

  7. Research Areas

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    Research Areas Our Vision National User Facilities Research Areas In Focus Global Solutions ⇒ Navigate Section Our Vision National User Facilities Research Areas In Focus Global Solutions Biosciences The Biosciences Area forges multidisciplinary teams to solve national challenges in energy, environment and health issues; and to advance the engineering of biological systems for sustainable manufacturing. Biosciences Area research is coordinated through three divisions and is enabled by Berkeley

  8. Research Highlight

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    Environmental Thermodynamics Affect Radiative Impact of Deep Convective Cloud Systems Submitter: Jensen, M., Brookhaven National Laboratory Area of Research: Atmospheric...

  9. Research Projects

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    LaboratoryNational Security Education Center Menu NSEC Educational Programs Los Alamos Dynamics Summer School Science of Signatures Advanced Studies Institute Judicial Science School SHM Data Sets and Software Research Projects Current Projects Past Projects Publications NSEC » Engineering Institute » Research Projects » Joint Los Alamos National Laboratory/UCSD research projects Past Research Projects Previous collaborations between Los Alamos National Laboratory and the University of

  10. Research Facility,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Department of Energy Research Experience in Carbon Sequestration 2013 Now Accepting Applications Research Experience in Carbon Sequestration 2013 Now Accepting Applications March 12, 2013 - 1:43pm Addthis Washington, DC - Graduate students and early career professionals can gain hands-on field research experience in areas related to carbon capture and storage (CCS) by participating in the Research Experience in Carbon Sequestration (RECS) program. The initiative, supported by DOE's Office

  11. Current Research

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    Current Research The U.S. Department of Transportation (USDOT) has established its only high-performance computing and engineering analysis research facility at Argonne National Laboratory to provide applications support in key areas of applied research and development for the USDOT community. The Transportation Research and Analysis Computing Center (TRACC) features a state-of-the-art massively parallel computer system, advanced scientific visualization capability, high-speed network

  12. Research Library

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    LANL Research Library: delivering essential knowledge services for national security sciences since 1947 About the Research Library Mission We deliver agile, responsive knowledge services, connecting people with information, technology and resources. Vision Essential knowledge services for national security sciences. The Research Library provides extensive collections of books, journals, databases, patents and technical reports and offers literature searching, training and outreach services. The

  13. 2011 GASEOUS IONS GORDON RESEARCH CONFERENCE

    SciTech Connect (OSTI)

    Scott Anderson

    2011-03-04

    The Gaseous Ions: Structures, Energetics and Reactions Gordon Research Conference will focus on ions and their interactions with molecules, surfaces, electrons, and light. The conference will cover theory and experiments, and systems ranging from molecular to biological to clusters to materials. The meeting goal continues to be bringing together scientists interested in fundamentals, with those applying fundamental phenomena to a wide range of practical problems. Each of the ten conference sessions will focus on a topic within this spectrum, and there will also be poster sessions for contributed papers, with sufficient space and time to allow all participants to present their latest results. To encourage active participation by young investigators, about ten of the poster abstracts will be selected for 15 minute 'hot topic' talks during the conference sessions. Hot topic selection will be done about a month before the meeting. Funds should be available to offset the participation cost for young investigators.

  14. Design, Synthesis and Mechanistic Evaluation of Iron-Based Catalysis for Synthesis Gas Conversion to Fuels and Chemicals

    SciTech Connect (OSTI)

    Akio Ishikawa; Manuel Ojeda; Nan Yao; Enrique Iglesia

    2007-03-31

    This project extends previously discovered Fe-based catalysts to hydrogen-poor synthesis gas streams derived from coal and biomass sources. These catalysts have shown unprecedented Fischer-Tropsch synthesis rates and selectivities for synthesis gas derived from methane. During the first reporting period, we certified a microreactor, installed required analytical equipment, and reproduced synthetic protocols and catalytic results previously reported. During the second reporting period, we prepared several Fe-based compositions for Fischer-Tropsch Synthesis and tested the effects of product recycle under both subcritical and supercritical conditions. During the third and fourth reporting periods, we improved the catalysts preparation method, which led to Fe-based materials with the highest FTS reaction rates and selectivities so far reported, a finding that allowed their operation at lower temperatures and pressures with high selectivity to desired products (C{sub 5+}, olefins). During the fifth and sixth reporting period, we studied the effects of different promoters on catalytic performance, specifically how their sequence of addition dramatically influenced the performance of these materials in the Fischer-Tropsch synthesis. We also continued our studies of the kinetic behavior of these materials during the sixth reporting period. Specifically, the effects of H{sub 2}, CO, and CO{sub 2} on the rates and selectivities of Fischer-Tropsch Synthesis reactions led us to propose a new sequence of elementary steps on Fe and Co Fischer-Tropsch catalysts. Finally, we also started a study of the use of colloidal precipitation methods for the synthesis small Co clusters using recently developed methods to explore possible further improvements in FTS rates and selectivities. We found that colloidal synthesis makes possible the preparation of small cobalt particles, although large amount of cobalt silicate species, which are difficult to reduce, were formed. During this seventh reporting period, we have explored several methods to modify the silanol groups on SiO{sub 2} by using either a homogeneous deposition-precipitation method or surface titration of Si-OH on SiO{sub 2} with zirconium (IV) ethoxide to prevent the formation of unreducible and unreactive CoO{sub x} species during synthesis and FTS catalysis. We have synthesized monometallic Co/ZrO{sub 2}/SiO{sub 2} catalysts with different Co loadings (11-20 wt%) by incipient wetness impregnation methods and characterized the prepared Co supported catalysts by H{sub 2} temperature-programmed reduction (H{sub 2}-TPR) and H{sub 2}-chemisorption. We have measured the catalytic performance in FTS reactions and shown that although the hydroxyl groups on the SiO{sub 2} surface are difficult to be fully titrated by ZrO{sub 2}, modification of ZrO{sub 2} on SiO{sub 2} surface can improve the Co clusters dispersion and lead to a larger number of exposed Co surface atoms after reduction and during FTS reactions. During this seventh reporting period, we have also advanced our development of the reaction mechanism proposed in the previous reporting period. Specifically, we have shown that our novel proposal for the pathways involved in CO activation on Fe and Co catalysts is consistent with state-of-the-art theoretical calculations carried out in collaboration with Prof. Manos Mavrikakis (University of Wisconsin-Madison). Finally, we have also worked on the preparation of several manuscripts describing our findings about the preparation, activation and mechanism of the FTS with Fe-based catalysts and we have started redacting the final report for this project.

  15. Rui Peng Postdoctoral Research Associate Center for Nanophase...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (ACS) 2009-present Reviewer: Energy & Environment Science (RSC), Materials Letters (Elsevier), Catalysis Science & Technology (RSC) Honors and Awards 2014 Winner of Graduate...

  16. Energy & Manufacturing Workforce Training Topics List - Version 1.7

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (02.11.14) | Department of Energy & Manufacturing Workforce Training Topics List - Version 1.7 (02.11.14) Energy & Manufacturing Workforce Training Topics List - Version 1.7 (02.11.14) View this searchable list of the training programs in the areas of energy and/or manufacturing. Information provided in this list includes: the subjects being taught, grantee, project title, and state. In some cases the list also shows the certificates provided by the courses. File Energy and

  17. UNIRIB: Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Mission Focus Photo Courtesy of Oak Ridge National Laboratory The central mission focus of the University Radioactive Ion Beam (UNIRIB) consortium is to perform nuclear physics research, and provide training and education. UNIRIB member universities have gained decades of frontline research experience through the use of the world-class facilities at Oak Ridge National Laboratory (ORNL) and other national laboratories across the United States. The UNIRIB consortium is tasked by the U.S.

  18. Environmental Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dist. Category UC-l 1, 13 DE@ 010764 Health & Environmental Research Summary of Accomplishments Prepared by Office of Energy Research /U.S. Department of Energy Washington, D.C. 20585 Reprinted April 1984 Published by Technical Information Center/U.S. Department of Energy The purpose of this brief narrative is to foster an awareness of a publicly funded health and environmental research program chartered nearly forty years ago, of its contributions toward the national goal of safe and

  19. PNNL: Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research at PNNL Research is our business With an unwavering focus on our missions, scientists and engineers at PNNL deliver science and technology. We conduct basic research that advances the frontiers of science. We translate discoveries into tools and technologies in science, energy, the environment and national security. For more than four decades, our experts have teamed with government, industry and academia to tackle some of the toughest problems facing our nation. The result: We're

  20. Research | NREL

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    Research Researching energy systems and technologies-and the science behind them-for a future powered by clean energy. Subscribe Stay connected with the latest news and research breakthroughs from NREL. Sign up now Photo of the U.S. Department of Energy's Energy Systems Integration Facility at NREL. Energy Systems Integration Facility The only facility in the nation focused on utility-scale clean energy grid integration. Learn More National Bioenergy Center National Center for Photovoltaics

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Partial Mechanistic Understanding of the North American Monsoon Download a printable PDF Submitter: Erfani, E., Desert Research Institute Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Erfani E and DL Mitchell. 2014. "A partial mechanistic understanding of the North American monsoon." Journal of Geophysical Research - Atmospheres, 119(23), 10.1002/2014JD022038. a) Dependence of

  2. Research Highlights

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Highlights Research Highlights Highlighting some of the extraordinary work in Chemistry Division Contact Us Division Leader David Morris Deputy Division Leader Mark McCleskey (505) 667-4457 Deputy Division Leader (acting) George Havrilla Division Office (505) 667-4457 Email 2016 Physicist wins early-career award for isotope work 5/12 LANL researchers shine more light on the mechanism of one of the most efficient artificial catalytic reactions developed to date 4/20 3D-printing

  3. Researchers - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Administration Programs Research, Development, Test, and Evaluation Forty-eight final optic assemblies are symmetrically distributed around the upper and lower hemispheres of the target chamber of the National Ignition Facility at Lawrence Livermore National Laboratory The Office of Research, Development, Test, and Evaluation directs research, development, computer simulation, and inertial confinement fusion activities to maintain the safety, security and effectiveness of the nuclear weapons

  4. Research Approach

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Approach Research Approach NETL's onsite research approach is based on integrating simulation tools with targeted experimental validation at real-life conditions in the lab and in the field. Simulation tools increase confidence in designs, thereby reducing the risk associated with incorporating multiple innovative technologies, realizing scale-up, and predicting the behavior and properties of real materials. The scientific underpinnings encoded into these models also ensure that

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Back to Basics: Theoretical Studies on Storm Clouds and Implications for Modeling For original submission and image(s), see ARM Research Highlights http://www.arm.gov/science/highlights/ Research Highlight Storms associated with deep convection are a key component of weather and climate. For example, they produce a large share of precipitation that falls to the Earth's surface, and their anvil shields act as a thermal blanket on the planet. To understand the behavior of these storms, researchers

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Radiative Forcing by Long-Lived Greenhouse Gases: Calculations with the AER Models Download a printable PDF Submitter: Iacono, M. J., Atmospheric & Environmental Research, Inc. Delamere, J. S., Tech-X Corporation Mlawer, E. J., Atmospheric & Environmental Research, Inc. Collins, W. D., Lawrence Berkeley National Laboratory Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Radiative Processes Journal Reference: Iacono, MJ, JS Delamere, EJ

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climatology of Aerosol Optical Depth in North-Central Oklahoma: 1992-2008 Download a printable PDF Submitter: Michalsky, J. J., Cooperative Institute for Research in Environmental Sciences Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Michalsky J, F Denn, C Flynn, G Hodges, P Kiedron, A Koontz, J Schlemmer, and SE Schwartz. 2010. "Climatology of aerosol optical depth in north-central Oklahoma: 1992-2008." Journal of Geophysical Research -

  8. January and February PSERC Webinars on CERTS Research | Department of

    Energy Savers [EERE]

    Energy January and February PSERC Webinars on CERTS Research January and February PSERC Webinars on CERTS Research January 13, 2014 - 12:15pm Addthis The Power System Engineering Research Center (PSERC) is offering a free, public webinar series based on past and ongoing research coordinated by the Consortium for Electric Reliability Technology Solutions (CERTS) with funding provided by the Department of Energy. The webinars will run through April 2014. The topics for January and February are

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Differences Between Tropical and Trade-Wind Shallow Cumuli Download a printable PDF Submitter: Ghate, V. P., Argonne National Laboratory Area of Research: Vertical Velocity Working...

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nucleation Events Download a printable PDF Submitter: McMurry, P. ., University of Minnesota Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal ...

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Australian Wet Seasons as Revealed by ARM Disdrometer Research Facilities (Darwin, Australia)." Journal of Applied Meteorology and Climatology, , http:dx.doi.org10.1175...

  12. Research Highlight

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    Climate Research Facility located near Lamont, Oklahoma. Measurements from ARM Raman lidar and Doppler radar instruments were used to both initialize and evaluate the model. A...

  13. Research Highlight

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    in the Doppler spectra. Over the North Slope of Alaska, researchers used cloud radar Doppler velocity spectra, lidar backscattering coefficients and depolarization ratios, and...

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Zhang, Q., University of California, Davis Fast, J. ., Pacific Northwest National Laboratory Area of Research: Aerosol Processes Working Group(s): Aerosol Life Cycle Journal...

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Lose Download a printable PDF Submitter: Laskin, A., Pacific Northwest National Laboratory Fast, J. ., Pacific Northwest National Laboratory Area of Research: Aerosol...

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hagos, S. M., Pacific Northwest National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Life Cycle Journal Reference: NA...

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Submitter: Westwater, E. R., University of Colorado Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Properties Journal Reference:...

  18. Research Highlight

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    Liljegren, J. C., Argonne National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Properties, Radiative Processes...

  19. Research Highlight

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    Xie, S., Lawrence Livermore National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Life Cycle Journal Reference: Xie...

  20. Research Highlight

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    Effects of Sea Spray on the Thermodynamics of the Hurricane Boundary Layer Download a printable PDF Submitter: Khain, A., The Hebrew University of Jerusalem Area of Research:...

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of MBL Cloud Properties over the Azores Download a printable PDF Submitter: Dong, X., University of North Dakota Area of Research: Radiation Processes Working Group(s): Cloud...

  2. Research Highlight

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    ... data collected from 18 flights during FIRE-ACE, the researchers analyzed measurements of drop and ice crystal particle size distribution, water content, and icing rate. ...

  3. Research Highlight

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    a printable PDF Submitter: de Boer, G., University of Colorado, BoulderCIRES Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: de...

  4. Research Highlight

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    to improve the representation of the autoconversion process in atmospheric models. This research also reveals major deficiencies of existing empirical schemes (see the figure)....

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Simple Equation Is Good Enough Submitter: Barnard, J., University of Nevada Reno Area of Research: Cloud DistributionsCharacterizations Working Group(s): Cloud Properties Journal...

  6. Research Highlight

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    Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: Paine SN, DD Turner, ...

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    "Roobik" Is Part of the Answer, Not a Puzzle Submitter: Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Radiation Processes Working Group(s): ...

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Submitter: Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: Turner DD. ...

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Shupe MD, DD Turner, VP ...

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mlawer, E. J., Atmospheric & Environmental Research, Inc. Turner, D. D., National Oceanic ... Journal Reference: Cady-Pereira, K, M Shephard, E Mlawer, D Turner, S Clough, and T ...

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Size Distributions with Help from Satellites Download a printable PDF Submitter: Mitchell, D. L., Desert Research Institute d'Entremont, R. P., Atmospheric and Environmental...

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud-Radiation Effects on Sea Ice Loss Download a printable PDF Submitter: Stephens, G. L., Colorado State University Area of Research: Cloud DistributionsCharacterizations...

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a printable PDF Submitter: Marshak, A., NASA - Goddard Space Flight Center Area of Research: Radiation Processes Working Group(s): Cloud-Aerosol-Precipitation Interactions...

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Influence of Dust Composition on Cloud Droplet Formation Download a printable PDF Submitter: Chuang, C., Lawrence Livermore National Laboratory Area of Research: Aerosol Properties...

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Burning on the Prairies Submitter: Bhattacharya, A., Pacific Northwest National Laboratory Area of Research: Radiation Processes Working Group(s): Cloud-Aerosol-Precipitation...

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Long-Term Impacts of Aerosols on the Vertical Development of Clouds and Precipitation Download a printable PDF Submitter: Li, Z., University of Maryland Area of Research:...

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Complexity of Arctic Clouds Download a printable PDF Submitter: Shupe, M., University of Colorado Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal...

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Broadband Albedo Observations in the Southern Great Plains Submitter: Lamb, P. J., University of Oklahoma Area of Research: Aerosol Properties Working Group(s): Aerosol Journal...

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    over the MJO Download a printable PDF Submitter: Del Genio, A. D., National Aeronautics and Space Administration Area of Research: Cloud DistributionsCharacterizations...

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Get Organized Download a printable PDF Submitter: Del Genio, A. D., National Aeronautics and Space Administration Area of Research: Cloud Processes Working Group(s): Cloud...