National Library of Energy BETA

Sample records for research surface properties

  1. Controlling Surface Properties of Transparent Conducting Oxides | ANSER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center | Argonne-Northwestern National Laboratory Controlling Surface Properties of Transparent Conducting Oxides Home > Research > ANSER Research Highlights > Controlling Surface Properties of Transparent Conducting Oxides

  2. Wetting properties of molecularly rough surfaces

    SciTech Connect (OSTI)

    Svoboda, Martin; Lísal, Martin; Malijevský, Alexandr

    2015-09-14

    We employ molecular dynamics simulations to study the wettability of nanoscale rough surfaces in systems governed by Lennard-Jones (LJ) interactions. We consider both smooth and molecularly rough planar surfaces. Solid substrates are modeled as a static collection of LJ particles arranged in a face-centered cubic lattice with the (100) surface exposed to the LJ fluid. Molecularly rough solid surfaces are prepared by removing several strips of LJ atoms from the external layers of the substrate, i.e., forming parallel nanogrooves on the surface. We vary the solid-fluid interactions to investigate strongly and weakly wettable surfaces. We determine the wetting properties by measuring the equilibrium droplet profiles that are in turn used to evaluate the contact angles. Macroscopic arguments, such as those leading to Wenzel’s law, suggest that surface roughness always amplifies the wetting properties of a lyophilic surface. However, our results indicate the opposite effect from roughness for microscopically corrugated surfaces, i.e., surface roughness deteriorates the substrate wettability. Adding the roughness to a strongly wettable surface shrinks the surface area wet with the liquid, and it either increases or only marginally affects the contact angle, depending on the degree of liquid adsorption into the nanogrooves. For a weakly wettable surface, the roughness changes the surface character from lyophilic to lyophobic due to a weakening of the solid-fluid interactions by the presence of the nanogrooves and the weaker adsorption of the liquid into the nanogrooves.

  3. Enhancement of surface properties for coal beneficiation

    SciTech Connect (OSTI)

    Chander, S.; Aplan, F.F.

    1992-01-30

    This report will focus on means of pyrite removal from coal using surface-based coal cleaning technologies. The major subjects being addressed in this study are the natural and modulated surface properties of coal and pyrite and how they may best be utilized to facilitate their separation using advanced surface-based coal cleaning technology. Emphasis is based on modified flotation and oil agglomerative processes and the basic principles involved. The four areas being addressed are: (1) Collectorless flotation of pyrite; (2) Modulation of pyrite and coal hydrophobicity; (3) Emulsion processes and principles; (4) Evaluation of coal hydrophobicity.

  4. [Plasma properties research: Task 3

    SciTech Connect (OSTI)

    Not Available

    1992-01-01

    The principal research activities of the Magneto-Fluid Dynamics Division relate to magnetic fusion plasma physics. In addition, there is a modest amount of work in closely related areas, including space plasma physics, fluid dynamics, and dynamical systems. Members of the Magneto-Fluid Dynamics Division maintain close contacts with fusion researchers in the US and abroad. Some of the work of the Division is clearly directed towards ITER and TPX, while other problems relate to the broader development of fusion plasma physics and to the support of other issues arising in the many experimental programs. Topics of some note in the last year that are discussed in this report are: Application of sophisticated statistical techniques to tokamak data reduction, including time series analysis of TFTR fluctuation data and spline analysis of profile data. Continuing development of edge plasma and divertor modelling, including initial ergodic divertor studies. Analysis of energetic fusion products losses from TFTR plasmas. Examination of anomalous transport in dynamical systems induced by chaotic-like Hamiltonian motion. Numerical simulation of the development of singular MHD equilibria. Exploration of the validity of moment expansions of kinetic equations for weakly collisional systems. Studies of RF- and ripple-induced helium ash removal. Ballooning mode studies in fluids and rotating stars. Studies in dynamical systems, including explosive instabilities, development of chaos, and motion of collisionless particles in a domain with overlapping islands.

  5. [Plasma properties research: Task 3

    SciTech Connect (OSTI)

    Not Available

    1992-12-31

    The principal research activities of the Magneto-Fluid Dynamics Division relate to magnetic fusion plasma physics. In addition, there is a modest amount of work in closely related areas, including space plasma physics, fluid dynamics, and dynamical systems. Members of the Magneto-Fluid Dynamics Division maintain close contacts with fusion researchers in the US and abroad. Some of the work of the Division is clearly directed towards ITER and TPX, while other problems relate to the broader development of fusion plasma physics and to the support of other issues arising in the many experimental programs. Topics of some note in the last year that are discussed in this report are: Application of sophisticated statistical techniques to tokamak data reduction, including time series analysis of TFTR fluctuation data and spline analysis of profile data. Continuing development of edge plasma and divertor modelling, including initial ergodic divertor studies. Analysis of energetic fusion products losses from TFTR plasmas. Examination of anomalous transport in dynamical systems induced by chaotic-like Hamiltonian motion. Numerical simulation of the development of singular MHD equilibria. Exploration of the validity of moment expansions of kinetic equations for weakly collisional systems. Studies of RF- and ripple-induced helium ash removal. Ballooning mode studies in fluids and rotating stars. Studies in dynamical systems, including explosive instabilities, development of chaos, and motion of collisionless particles in a domain with overlapping islands.

  6. Sink property of metallic glass free surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shao, Lin; Fu, Engang; Price, Lloyd; Chen, Di; Chen, Tianyi; Wang, Yongqiang; Xie, Guoqiang; Lucca, Don A.

    2015-03-16

    When heated to a temperature close to glass transition temperature, metallic glasses (MGs) begin to crystallize. Under deformation or particle irradiation, crystallization occurs at even lower temperatures. Hence, phase instability represents an application limit for MGs. Here, we report that MG membranes of a few nanometers thickness exhibit properties different from their bulk MG counterparts. The study uses in situ transmission electron microscopy with concurrent heavy ion irradiation and annealing to observe crystallization behaviors of MGs. For relatively thick membranes, ion irradiations introduce excessive free volumes and thus induce nanocrystal formation at a temperature linearly decreasing with increasing ion fluences.moreFor ultra-thin membranes, however, the critical temperature to initiate crystallization is about 100 K higher than the bulk glass transition temperature. Molecular dynamics simulations indicate that this effect is due to the sink property of the surfaces which can effectively remove excessive free volumes. These findings suggest that nanostructured MGs having a higher surface to volume ratio are expected to have higher crystallization resistance, which could pave new paths for materials applications in harsh environments requiring higher stabilities.less

  7. Sink property of metallic glass free surfaces

    SciTech Connect (OSTI)

    Shao, Lin; Fu, Engang; Price, Lloyd; Chen, Di; Chen, Tianyi; Wang, Yongqiang; Xie, Guoqiang; Lucca, Don A.

    2015-03-16

    When heated to a temperature close to glass transition temperature, metallic glasses (MGs) begin to crystallize. Under deformation or particle irradiation, crystallization occurs at even lower temperatures. Hence, phase instability represents an application limit for MGs. Here, we report that MG membranes of a few nanometers thickness exhibit properties different from their bulk MG counterparts. The study uses in situ transmission electron microscopy with concurrent heavy ion irradiation and annealing to observe crystallization behaviors of MGs. For relatively thick membranes, ion irradiations introduce excessive free volumes and thus induce nanocrystal formation at a temperature linearly decreasing with increasing ion fluences. For ultra-thin membranes, however, the critical temperature to initiate crystallization is about 100 K higher than the bulk glass transition temperature. Molecular dynamics simulations indicate that this effect is due to the sink property of the surfaces which can effectively remove excessive free volumes. These findings suggest that nanostructured MGs having a higher surface to volume ratio are expected to have higher crystallization resistance, which could pave new paths for materials applications in harsh environments requiring higher stabilities.

  8. Sink property of metallic glass free surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shao, Lin; Fu, Engang; Price, Lloyd; Chen, Di; Chen, Tianyi; Wang, Yongqiang; Xie, Guoqiang; Lucca, Don A.

    2015-03-16

    When heated to a temperature close to glass transition temperature, metallic glasses (MGs) begin to crystallize. Under deformation or particle irradiation, crystallization occurs at even lower temperatures. Hence, phase instability represents an application limit for MGs. Here, we report that MG membranes of a few nanometers thickness exhibit properties different from their bulk MG counterparts. The study uses in situ transmission electron microscopy with concurrent heavy ion irradiation and annealing to observe crystallization behaviors of MGs. For relatively thick membranes, ion irradiations introduce excessive free volumes and thus induce nanocrystal formation at a temperature linearly decreasing with increasing ion fluences.more » For ultra-thin membranes, however, the critical temperature to initiate crystallization is about 100 K higher than the bulk glass transition temperature. Molecular dynamics simulations indicate that this effect is due to the sink property of the surfaces which can effectively remove excessive free volumes. These findings suggest that nanostructured MGs having a higher surface to volume ratio are expected to have higher crystallization resistance, which could pave new paths for materials applications in harsh environments requiring higher stabilities.« less

  9. Seventh BES (Basic Energy Sciences) catalysis and surface chemistry research conference

    SciTech Connect (OSTI)

    Not Available

    1990-03-01

    Research programs on catalysis and surface chemistry are presented. A total of fifty-seven topics are included. Areas of research include heterogeneous catalysis; catalysis in hydrogenation, desulfurization, gasification, and redox reactions; studies of surface properties and surface active sites; catalyst supports; chemical activation, deactivation; selectivity, chemical preparation; molecular structure studies; sorption and dissociation. Individual projects are processed separately for the data bases. (CBS)

  10. Surface property detection apparatus and method

    DOE Patents [OSTI]

    Martens, Jon S.; Ginley, David S.; Hietala, Vincent M.; Sorensen, Neil R.

    1995-01-01

    Apparatus and method for detecting, determining, and imaging surface resistance corrosion, thin film growth, and oxide formation on the surface of conductors or other electrical surface modification. The invention comprises a modified confocal resonator structure with the sample remote from the radiating mirror. Surface resistance is determined by analyzing and imaging reflected microwaves; imaging reveals anomalies due to surface impurities, non-stoichiometry, and the like, in the surface of the superconductor, conductor, dielectric, or semiconductor.

  11. Surface property detection apparatus and method

    DOE Patents [OSTI]

    Martens, J.S.; Ginley, D.S.; Hietala, V.M.; Sorensen, N.R.

    1995-08-08

    Apparatus and method for detecting, determining, and imaging surface resistance corrosion, thin film growth, and oxide formation on the surface of conductors or other electrical surface modification. The invention comprises a modified confocal resonator structure with the sample remote from the radiating mirror. Surface resistance is determined by analyzing and imaging reflected microwaves; imaging reveals anomalies due to surface impurities, non-stoichiometry, and the like, in the surface of the superconductor, conductor, dielectric, or semiconductor. 4 figs.

  12. Surface Contamination Guidelines/Radiological Clearance of Property |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Surface Contamination Guidelines/Radiological Clearance of Property Surface Contamination Guidelines/Radiological Clearance of Property Authorized limits govern the control and clearance of personal and real property. They are radionuclide concentrations or activity levels approved by DOE to permit the clearance of property from DOE radiological control for either restricted or unrestricted use, consistent with DOE's radiation protection framework and standards for the

  13. Modification of surface properties of copper-refractory metal alloys

    DOE Patents [OSTI]

    Verhoeven, John D.; Gibson, Edwin D.

    1993-10-12

    The surface properties of copper-refractory metal (CU-RF) alloy bodies are modified by heat treatments which cause the refractory metal to form a coating on the exterior surfaces of the alloy body. The alloys have a copper matrix with particles or dendrites of the refractory metal dispersed therein, which may be niobium, vanadium, tantalum, chromium, molybdenum, or tungsten. The surface properties of the bodies are changed from those of copper to that of the refractory metal.

  14. Method for determining surface properties of microparticles

    DOE Patents [OSTI]

    Eisenthal, Kenneth B.

    2000-01-01

    Second harmonic generation (SHG), sum frequency generation (SFG) and difference frequency generation (DFG) can be used for surface analysis or characterization of microparticles having a non-metallic surface feature. The microparticles can be centrosymmetric or such that non-metallic molecules of interest are centrosymmetrically distributed inside and outside the microparticles but not at the surface of the microparticles where the asymmetry aligns the molecules. The signal is quadratic in incident laser intensity or proportional to the product of two incident laser intensities for SFG, it is sharply peaked at the second harmonic wavelength, quadratic in the density of molecules adsorbed onto the microparticle surface, and linear in microparticles density. In medical or pharmacological applications, molecules of interest may be of drugs or toxins, for example.

  15. Intellectual Property Provisions (GLB-115) Grant Research, Development...

    Energy Savers [EERE]

    GLB-115) Grant Research, Development, or Demonstration Large Business and Foreign Entity Intellectual Property Provisions (GLB-115) Grant Research, Development, or Demonstration ...

  16. Intellectual Property Provisions (GSB-115) Grant Research, Development...

    Energy Savers [EERE]

    GSB-115) Grant Research, Development, or Demonstration Domestic Small Business Intellectual Property Provisions (GSB-115) Grant Research, Development, or Demonstration Domestic ...

  17. Nanotextured Anti-Icing Surfaces | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Demonstrate Promising Anti-icing Nano Surfaces Click to email this to a friend (Opens in ... GE Scientists Demonstrate Promising Anti-icing Nano Surfaces GE Global Research today ...

  18. Surface barrier research at the Hanford Site

    SciTech Connect (OSTI)

    Gee, G.W.; Ward, A.L.; Fayer, M.J.

    1997-12-31

    At the DOE Hanford Site, a field-scale prototype surface barrier was constructed in 1994 over an existing waste site as a part of a CERCLA treatability test. The above-grade barrier consists of a fine-soil layer overlying coarse layers of sands, gravels, basalt rock (riprap), and a low permeability asphalt layer. Two sideslope configurations, clean-fill gravel on a 10:1 slope and basalt riprap on a 2:1 slope, were built and are being tested. Design considerations included: constructability; drainage and water balance monitoring, wind and water erosion control and monitoring; surface revegetation and biotic intrusion; subsidence and sideslope stability, and durability of the asphalt layer. The barrier is currently in the final year of a three-year test designed to answer specific questions related to stability and long-term performance. One half of the barrier is irrigated such that the total water applied, including precipitation, is 480 mm/yr (three times the long-term annual average). Each year for the past two years, an extreme precipitation event (71 mm in 8 hr) representing a 1,000-yr return storm was applied in late March, when soil water storage was at a maximum. While the protective sideslopes have drained significant amounts of water, the soil cover (2-m of silt-loam soil overlying coarse sand and rock) has never drained. During the past year there was no measurable surface runoff or wind erosion. This is attributed to extensive revegetation of the surface. In addition, the barrier elevation has shown a small increase of 2 to 3 cm that is attributed to a combination of root proliferation and freeze/thaw activity. Testing will continue through September 1997. Performance data from the prototype barrier will be used by DOE in site-closure decisions at Hanford.

  19. Intellectual Property Provisions (CSB-115) Cooperative Agreement Research,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development, or Demonstration Domestic Small Business | Department of Energy 15) Cooperative Agreement Research, Development, or Demonstration Domestic Small Business Intellectual Property Provisions (CSB-115) Cooperative Agreement Research, Development, or Demonstration Domestic Small Business CSB-115.pdf (56.83 KB) More Documents & Publications Intellectual Property Provisions (CSB-1003) Cooperative Agreement Research, Development, or Demonstration Domestic Small Businesses

  20. Properties of water surface discharge at different pulse repetition rates

    SciTech Connect (OSTI)

    Ruma,; Yoshihara, K.; Hosseini, S. H. R. Sakugawa, T.; Akiyama, H.; Akiyama, M.; Lukeš, P.

    2014-09-28

    The properties of water surface discharge plasma for variety of pulse repetition rates are investigated. A magnetic pulse compression (MPC) pulsed power modulator able to deliver pulse repetition rates up to 1000 Hz, with 0.5 J per pulse energy output at 25 kV, was used as the pulsed power source. Positive pulse with a point-to-plane electrode configuration was used for the experiments. The concentration and production yield of hydrogen peroxide (H₂O₂) were quantitatively measured and orange II organic dye was treated, to evaluate the chemical properties of the discharge reactor. Experimental results show that the physical and chemical properties of water surface discharge are not influenced by pulse repetition rate, very different from those observed for under water discharge. The production yield of H₂O₂ and degradation rate per pulse of the dye did not significantly vary at different pulse repetition rates under a constant discharge mode on water surface. In addition, the solution temperature, pH, and conductivity for both water surface and underwater discharge reactors were measured to compare their plasma properties for different pulse repetition rates. The results confirm that surface discharge can be employed at high pulse repetition rates as a reliable and advantageous method for industrial and environmental decontamination applications.

  1. Nanotextured Anti-Icing Surfaces | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Demonstrate Promising Anti-icing Nano Surfaces Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) Click to share on LinkedIn (Opens in new window) Click to share on Tumblr (Opens in new window) GE Scientists Demonstrate Promising Anti-icing Nano Surfaces GE Global Research today presented new research findings on its nanotextured anti-icing surfaces. In addition to dramatically reducing ice adhesion, these surfaces

  2. Intellectual Property Provisions (GSB-115) Grant Research, Development, or

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Demonstration Domestic Small Business | Department of Energy GSB-115) Grant Research, Development, or Demonstration Domestic Small Business Intellectual Property Provisions (GSB-115) Grant Research, Development, or Demonstration Domestic Small Business GSB-115.pdf (46.58 KB) More Documents & Publications GSB-1003.PDF� Intellectual Property Provisions (CSB-1003) Cooperative Agreement Research, Development, or Demonstration Domestic Small Businesses Intellectual Property Provisions

  3. Nanoscale Material Properties | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Symposium and Exhibition Focuses on Materials, Surfaces and Interfaces IMG0475 Innovation 247: We're Always Open a57-v-zero-liquid-discharge Reverse Osmosis (RO)...

  4. Los Alamos researchers uncover new properties in nanocomposite...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Los Alamos researchers uncover new properties in nanocomposite oxide ceramics for reactor fuel, fast-ion conductors Alumni Link: Opportunities, News and Resources for Former ...

  5. Enhancement of surface properties for coal beneficiation. Final report

    SciTech Connect (OSTI)

    Chander, S.; Aplan, F.F.

    1992-01-30

    This report will focus on means of pyrite removal from coal using surface-based coal cleaning technologies. The major subjects being addressed in this study are the natural and modulated surface properties of coal and pyrite and how they may best be utilized to facilitate their separation using advanced surface-based coal cleaning technology. Emphasis is based on modified flotation and oil agglomerative processes and the basic principles involved. The four areas being addressed are: (1) Collectorless flotation of pyrite; (2) Modulation of pyrite and coal hydrophobicity; (3) Emulsion processes and principles; (4) Evaluation of coal hydrophobicity.

  6. Research Portfolio Report Ultra-Deepwater: Surface Systems and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Systems and Umbilicals (Wellbore Stability) Research Portfolio Report Ultra-Deepwater: Surface Systems and Umbilicals (Wellbore Stability) DOE/NETL-2015/1696 Prepared by: Mari Nichols-Haining, Jennifer Funk, John Oelfke, and Christine Rueter KeyLogic Systems, Inc. National Energy Technology Laboratory (NETL) Contact: James Ammer james.ammer@netl.doe.gov Contract DE-FE0004003 Activity 4003.200.03 DISCLAIMER This report was prepared as an account of work sponsored by an agency of the

  7. Surface chemistry and bonding configuration of ultrananocrystalline diamond surfaces and their effects on nanotribological properties

    SciTech Connect (OSTI)

    Sumant, A. V.; Grierson, D. S.; Carpick, R. W.; Gerbi, J. E.; Carlisle, J. A.; Auciello, O.

    2007-12-15

    We present a comprehensive study of surface composition and nanotribology for ultrananocrystalline diamond (UNCD) surfaces, including the influence of film nucleation on these properties. We describe a methodology to characterize the underside of the films as revealed by sacrificial etching of the underlying substrate. This enables the study of the morphology and composition resulting from the nucleation and initial growth of the films, as well as the characterization of nanotribological properties which are relevant for applications including micro-/nanoelectromechanical systems. We study the surface chemistry, bonding configuration, and nanotribological properties of both the topside and the underside of the film with synchrotron-based x-ray absorption near-edge structure spectroscopy to identify the bonding state of the carbon atoms, x-ray photoelectron spectroscopy to determine the surface chemical composition, Auger electron spectroscopy to further verify the composition and bonding configuration, and quantitative atomic force microscopy to study the nanoscale topography and nanotribological properties. The films were grown on SiO{sub 2} after mechanically polishing the surface with detonation synthesized nanodiamond powder, followed by ultrasonication in a methanol solution containing additional nanodiamond powder. The sp{sup 2} fraction, morphology, and chemistry of the as-etched underside are distinct from the topside, exhibiting a higher sp{sup 2} fraction, some oxidized carbon, and a smoother morphology. The nanoscale single-asperity work of adhesion between a diamond nanotip and the as-etched UNCD underside is far lower than for a silicon-silicon interface (59.2{+-}2 vs 826{+-}186 mJ/m{sup 2}, respectively). Exposure to atomic hydrogen dramatically reduces nanoscale adhesion to 10.2{+-}0.4 mJ/m{sup 2}, at the level of van der Waals' interactions and consistent with recent ab initio calculations. Friction is substantially reduced as well, demonstrating a

  8. Surface chemistry and bonding configuration of ultrananocrystalline diamond surfaces and their effects on nanotribological properties.

    SciTech Connect (OSTI)

    Sumant, A. V.; Grierson, D. S.; Gerbi, J. E.; Carlisle, J. A.; Auciello, O.; Carpick, R. W.; Univ. of Wisconsin at Madison

    2007-12-01

    We present a comprehensive study of surface composition and nanotribology for ultrananocrystalline diamond (UNCD) surfaces, including the influence of film nucleation on these properties. We describe a methodology to characterize the underside of the films as revealed by sacrificial etching of the underlying substrate. This enables the study of the morphology and composition resulting from the nucleation and initial growth of the films, as well as the characterization of nanotribological properties which are relevant for applications including micro-/nanoelectromechanical systems. We study the surface chemistry, bonding configuration, and nanotribological properties of both the topside and the underside of the film with synchrotron-based x-ray absorption near-edge structure spectroscopy to identify the bonding state of the carbon atoms, x-ray photoelectron spectroscopy to determine the surface chemical composition, Auger electron spectroscopy to further verify the composition and bonding configuration, and quantitative atomic force microscopy to study the nanoscale topography and nanotribological properties. The films were grown on SiO{sub 2} after mechanically polishing the surface with detonation synthesized nanodiamond powder, followed by ultrasonication in a methanol solution containing additional nanodiamond powder. The sp{sup 2} fraction, morphology, and chemistry of the as-etched underside are distinct from the topside, exhibiting a higher sp{sup 2} fraction, some oxidized carbon, and a smoother morphology. The nanoscale single-asperity work of adhesion between a diamond nanotip and the as-etched UNCD underside is far lower than for a silicon-silicon interface (59.2 {+-} 2 vs 826 {+-} 186 mJ/m{sup 2}, respectively). Exposure to atomic hydrogen dramatically reduces nanoscale adhesion to 10.2 {+-} 0.4 mJ/m{sup 2}, at the level of van der Waals interactions and consistent with recent ab initio calculations. Friction is substantially reduced as well

  9. Enhancing the Properties of Carbon and Gold Substrates by Surface Modification

    SciTech Connect (OSTI)

    Jennifer Anne Harnisch

    2002-06-27

    The properties of both carbon and gold substrates are easily affected by the judicious choice of a surface modification protocol. Several such processes for altering surface composition have been published in literature. The research presented in this thesis primarily focuses on the development of on-column methods to modify carbon stationary phases used in electrochemically modulated liquid chromatography (EMLC). To this end, both porous graphitic carbon (PGC) and glassy carbon (GC) particles have been modified on-column by the electroreduction of arenediazonium salts and the oxidation of arylacetate anions (the Kolbe reaction). Once modified, the carbon stationary phases show enhanced chromatographic performance both in conventional liquid chromatographic columns and EMLC columns. Additionally, one may also exploit the creation of aryl films to by electroreduction of arenediazonium salts in the creation of nanostructured materials. The formation of mercaptobenzene film on the surface of a GC electrode provides a linking platform for the chemisorption of gold nanoparticles. After deposition of nanoparticles, the surface chemistry of the gold can be further altered by self-assembled monolayer (SAM) formation via the chemisorption of a second thiol species. Finally, the properties of gold films can be altered such that they display carbon-like behavior through the formation of benzenehexathiol (BHT) SAMs. BHT chemisorbs to the gold surface in a previously unprecedented planar fashion. Carbon and gold substrates can be chemically altered by several methodologies resulting in new surface properties. The development of modification protocols and their application in the analytical arena is considered herein.

  10. Los Alamos researchers uncover new properties in nanocomposite...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Los Alamos researchers uncover new properties in nanocomposite oxide ceramics for reactor fuel, fast-ion conductors In a nanocomposite, the size of each of these grains is on the ...

  11. Intellectual Property Provisions (CLB-115) Cooperative Agreement Research,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development, or Demonstration Large Business and Foreign Entity | Department of Energy CLB-115) Cooperative Agreement Research, Development, or Demonstration Large Business and Foreign Entity Intellectual Property Provisions (CLB-115) Cooperative Agreement Research, Development, or Demonstration Large Business and Foreign Entity CLB-115.pdf (46.18 KB) More Documents & Publications CLB-1003.PDF� CDLB-1003.PDF� Intellectual Property Provisions (CDLB-115) Cooperative Agreement

  12. The Role of Surface Chemistry and Bulk Properties on the Cycling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Role of Surface Chemistry and Bulk Properties on the Cycling and Rate Capability of Lithium Positive Electrode Materials The Role of Surface Chemistry on the Cycling and ...

  13. Charging properties of cassiterite (alfa-SnO2) surfaces

    SciTech Connect (OSTI)

    Rosenqvist, Jorgen K; Machesky, Michael L.; Vlcek, L.; Cummings, Peter T; Wesolowski, David J

    2009-01-01

    The acid-base properties of cassiterite (alfa-SnO2) surfaces at 10 50 C were studied using potentiometric titrations of powder suspensions in aqueous NaCl and RbCl media. The proton sorption isotherms exhibited common intersection points in the pH-range 4.0 to 4.5 at all conditions and the magnitude of charging was similar but not identical in NaCl and RbCl. The hydrogen bonding configuration at the oxide-water interface, obtained from classical Molecular Dynamics (MD) simulations, was analyzed in detail and the results were explicitly incorporated in calculations of protonation constants for the reactive surface sites using the revised MUSIC model. The calculations indicated that the terminal SnOH2 group is more acidic than the bridging Sn2OH group, with protonation constants (log KH) of 3.60 and 5.13 at 25 C, respectively. This is contrary to the situation on the isostructural alfa-TiO2 (rutile), apparently due to the difference in electronegativity between Ti and Sn. MD simulations and speciation calculations indicated considerable differences in the speciation of Na+ and Rb+, despite the similarities in overall charging. Adsorbed sodium ions are almost exclusively found in bidentate surface complexes, while adsorbed rubidium ions form comparable amounts of bidentate and tetradentate complexes. Also, the distribution of adsorbed Na+ between the different complexes shows a considerable dependence on surface charge density (pH), while the distribution of adsorbed Rb+ is almost independent of pH. A Surface Complexation Model (SCM) capable of accurately describing both the measured surface charge and the MD predicted speciation of adsorbed Na+/Rb+ was formulated. According to the SCM, the deprotonated terminal group (SnOH-0.40) and the protonated bridging group (Sn2OH+0.36) dominate the surface speciation over the entire pH-range (2.7 10), illustrating the ability of positively and negatively charged surface groups to coexist. Complexation of the medium cations

  14. Intellectual Property Provisions (GLB-115) Grant Research, Development, or

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Demonstration Large Business and Foreign Entity | Department of Energy GLB-115) Grant Research, Development, or Demonstration Large Business and Foreign Entity Intellectual Property Provisions (GLB-115) Grant Research, Development, or Demonstration Large Business and Foreign Entity GLB-115.pdf (42.57 KB) More Documents & Publications GLB-1003.PDF� CLB-1003.PDF� CDLB

  15. Koel applies science of surface chemistry to fusion research at PPPL |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Princeton Plasma Physics Lab Koel applies science of surface chemistry to fusion research at PPPL By Catherine Zandonella March 26, 2012 Tweet Widget Google Plus One Share on Facebook To study the interactions of lithium under conditions similar to what might be found in a fusion reactor, lithium on a sample of TZM molybdenum, which is an alloy of molybdenum, titanium, zirconium and carbon known for its high strength and temperature properties, is heated inside an ultrahigh vacuum chamber

  16. Determining the research needs of the surface coal mining industry

    SciTech Connect (OSTI)

    Zell, L.M.

    1982-12-01

    This paper reveals avenues open to the coal industry to help gain technology and research information needed to meet the requirements of the Surface Mining Control and Reclamation Act of 1977. It discusses projects of the Department of Energy's (DOE) Office of Coal Mining and the Mining and Reclamation Council of America (MARC) to help meet the environmental needs as well as the coal industry needs.

  17. Intellectual Property Provisions (CSB-1003) Cooperative Agreement Research,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development, or Demonstration Domestic Small Businesses | Department of Energy 003) Cooperative Agreement Research, Development, or Demonstration Domestic Small Businesses Intellectual Property Provisions (CSB-1003) Cooperative Agreement Research, Development, or Demonstration Domestic Small Businesses 01. FAR 52.227-1 Authorization and Consent (JUL 1995)-Alternate I (APR 1984) 02. FAR 52.227-2 Notice and Assistance Regarding Patent and Copyright Infringement (AUG 1996) This clause is not

  18. Studies of the viscoelastic properties of water confined between surfaces of specified chemical nature.

    SciTech Connect (OSTI)

    Houston, Jack E.; Grest, Gary Stephen; Moore, Nathan W.; Feibelman, Peter J.

    2010-09-01

    This report summarizes the work completed under the Laboratory Directed Research and Development (LDRD) project 10-0973 of the same title. Understanding the molecular origin of the no-slip boundary condition remains vitally important for understanding molecular transport in biological, environmental and energy-related processes, with broad technological implications. Moreover, the viscoelastic properties of fluids in nanoconfinement or near surfaces are not well-understood. We have critically reviewed progress in this area, evaluated key experimental and theoretical methods, and made unique and important discoveries addressing these and related scientific questions. Thematically, the discoveries include insight into the orientation of water molecules on metal surfaces, the premelting of ice, the nucleation of water and alcohol vapors between surface asperities and the lubricity of these molecules when confined inside nanopores, the influence of water nucleation on adhesion to salts and silicates, and the growth and superplasticity of NaCl nanowires.

  19. Los Alamos researchers uncover new properties in nanocomposite oxide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ceramics for reactor fuel, fast-ion conductors New properties in nanocomposite oxide ceramics Los Alamos researchers uncover new properties in nanocomposite oxide ceramics for reactor fuel, fast-ion conductors In a nanocomposite, the size of each of these grains is on the order of nanometers, roughly 1000 times smaller than the width of a human hair. September 23, 2014 Schematic depicting distinct dislocation networks for SrO- and TiO2-terminated SrTiO3/MgO interface. Schematic depicting

  20. Plasma-Surface Interaction Research At The Cambridge Laboratory Of Accelerator Studies Of Surfaces

    SciTech Connect (OSTI)

    Wright, G. M.; Barnard, H. S.; Hartwig, Z. S.; Stahle, P. W.; Sullivan, R. M.; Woller, K. B.; Whyte, D. G.

    2011-06-01

    The material requirements for plasma-facing components in a nuclear fusion reactor are some of the strictest and most challenging facing us today. These materials are simultaneously exposed to extreme heat loads (20 MW/m{sup 2} steady-state, 1 GW/m{sup 2} in millisecond transients) and particle fluxes (>10{sup 24} m{sup -2} s{sup -1}) while also undergoing high neutron irradiation (10{sup 18} neutrons/m{sup 2} s). At the Cambridge Laboratory of Accelerator Studies of Surfaces (CLASS), many of the most important issues in plasma-surface interaction research, such as plasma-driven material erosion and deposition, material transport and irradiation and hydrogenic retention are investigated with the use of a 1.7 MV tandem ion accelerator. Ion-Beam Analysis (IBA) is used to investigate and quantify changes in materials due to plasma exposure and ion irradiation is used as a proxy for neutron irradiation to investigate plasma-surface interactions for irradiated materials. This report will outline the capabilities and current research activities at CLASS.

  1. The Role of Surface Chemistry and Bulk Properties on the Cycling...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications The Role of Surface Chemistry and Bulk Properties on the ... Energy Storage R&D The Role of Surface Chemistry on the Cycling and Rate Capability of ...

  2. Further studies of the effects of oxidation on the surface properties of coal and coal pyrite

    SciTech Connect (OSTI)

    Herrera, M.N.

    1994-12-31

    The objective of this research was to investigate the oxidation behavior of coal and coal pyrite and to correlate the changes in the surface properties induced by oxidation, along with the intrinsic physical and chemical properties of these organic and inorganic materials, with the behavior in physical coal cleaning processes. This provide more fundamental knowledge for understanding the way in which different factors interact in a medium as heterogeneous as coal. Fourteen coal samples of different ranks ranging from high to medium sulfur content were studied by dry oxidation tests at different temperatures and humidities, and by wet oxidation tests using different oxidizing agents. The concentration of surface oxygen functional groups was determined by ion-exchange methods. The changes in the coal composition with oxidation were analyzed by spectroscopic techniques. The wettability of as-received and oxidized coal and coal pyrite samples was assessed by film flotation tests. The electrokinetic behavior of different coals and coal pyrite samples was studied by electrokinetic tests using electrophoresis. Possible oxidation mechanisms have been proposed to explain the changes on the coal surface induced by different oxidation treatments.

  3. Tassilo Heeg > Researcher - SURFACE systems+technology GmbH > Center Alumni

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    > The Energy Materials Center at Cornell Tassilo Heeg Researcher - SURFACE systems+technology GmbH info@surface-tec.com Formerly a Postdoctoral Associate with the Schlom Group, Tassilo now works with SURFACE Systems & Technology.

  4. Surface Di-directional Reflectance Properties Over the ARM SGP...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Z. Li Earth System Science Interdisciplinary Center University of Maryland College Park, Maryland Introduction Surface albedo is an important parameter in atmospheric...

  5. Surface-active properties of humic and sulfochlorohumic acids

    SciTech Connect (OSTI)

    Ryabova, I.N.; Mustafina, G.A.; Akkulova, Z.G.; Satymbaeva, A.S.

    2009-10-15

    The surface tension of alkaline solutions of humic acids and their sulfochloroderivatives, which are synthesized by sulfonation of chlorohumic acids isolated from coal chlorinated by the electrochemical method, is investigated. It is established that humic compounds possess weak surface activity. Basic adsorption parameters are calculated.

  6. Manipulation of fluids in three-dimensional porous photonic structures with patterned surface properties

    DOE Patents [OSTI]

    Aizenberg, Joanna; Burgess, Ian B.; Mishchenko, Lidiya; Hatton, Benjamin; Loncar, Marko

    2016-03-08

    A three-dimensional porous photonic structure, whose internal pore surfaces can be provided with desired surface properties in a spatially selective manner with arbitrary patterns, and methods for making the same are described. When exposed to a fluid (e.g., via immersion or wicking), the fluid can selectively penetrate the regions of the structure with compatible surface properties. Broad applications, for example in security, encryption and document authentication, as well as in areas such as simple microfluidics and diagnostics, are anticipated.

  7. Satellite and Surface Data Synergy for Developing a 3D Cloud Structure and Properties Characterization Over the ARM SGP. S...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Satellite and Surface Data Synergy for Developing a 3D Cloud Structure and Properties Characterization Over the ARM SGP Site Stage 1: Cloud Amounts, Optical Depths, and Cloud Heights Reconciliation I. Genkova and C. N. Long Pacific Northwest National Laboratory Richland, Washington P. W. Heck Analytical Services & Materials, Inc. Hampton, Virginia P. Minnis National Aeronautics and Space Administration Langley Research Center Hampton, Virginia Introduction One of the primary Atmospheric

  8. Intermolecular potential energy surface and thermophysical properties of ethylene oxide

    SciTech Connect (OSTI)

    Crusius, Johann-Philipp Hassel, Egon; Hellmann, Robert; Bich, Eckard

    2014-10-28

    A six-dimensional potential energy hypersurface (PES) for two interacting rigid ethylene oxide (C{sub 2}H{sub 4}O) molecules was determined from high-level quantum-chemical ab initio calculations. The counterpoise-corrected supermolecular approach at the MP2 and CCSD(T) levels of theory was utilized to determine interaction energies for 10178 configurations of two molecules. An analytical site-site potential function with 19 sites per ethylene oxide molecule was fitted to the interaction energies and fine tuned to agree with data for the second acoustic virial coefficient from accurate speed of sound measurements. The PES was validated by computing the second virial coefficient, shear viscosity, and thermal conductivity. The values of these properties are substantiated by the best experimental data as they tend to fall within the uncertainty intervals and also obey the experimental temperature functions, except for viscosity, where experimental data are insufficient. Due to the lack of reliable data, especially for the transport properties, our calculated values are currently the most accurate estimates for these properties of ethylene oxide.

  9. Unusual adsorption properties of silver adlayers on the Pt(111) electrode surface

    SciTech Connect (OSTI)

    Marinkovic, N.S.; Wang, J.X.; Adzic, R.R.; Marinkovic, J.S.

    1999-01-07

    Adsorption properties of silver monolayer and bilayer deposited at underpotentials on a Pt(111) electrode were studied by means of linear sweep voltammetry, in situ surface X-ray scattering and infrared spectroelectrochemistry. Surface X-ray scattering measurements show a pseudomorphic Ag monolayer and an incommensurate expanded bilayer on Pt(111) formed at underpotentials. Unusual adsorption properties of the silver layers with respect to the bulk silver are observed. The two Ag adlayers were found to have intermediate adsorption/oxidation characteristics between those of metallic Ag and Pt surfaces with (111) orientation. The Ag monolayer has properties that facilitate adsorption of bisulfate anions and adsorption and oxidation of CO. These properties are closer to the adsorption properties of the Pt(111) surface than to those of Ag(111), which adsorbs sulfate anions and does not adsorb CO. The Ag bilayer on the Pt(111) surface adsorbs sulfate anions as Ag(111) does, but in contrast to the behavior of Ag(111), it adsorbs CO. These properties of the Ag adlayers appear to be a consequence of the charge-transfer process and the electron distribution in the Ag/Pt(111) surface.

  10. Cooperative Research and Development of Primary Surface Recuperator for Advanced Microturbine Systems

    SciTech Connect (OSTI)

    Escola, George

    2007-01-17

    Recuperators have been identified as key components of advanced gas turbines systems that achieve a measure of improvement in operating efficiency and lead the field in achieving very low emissions. Every gas turbine manufacturer that is studying, developing, or commercializing advanced recuperated gas turbine cycles requests that recuperators operate at higher temperature without a reduction in design life and must cost less. The Solar Cooperative Research and Development of Primary Surface Recuperator for Advanced Microturbine Systems Program is directed towards meeting the future requirements of advanced gas turbine systems by the following: (1) The development of advanced alloys that will allow recuperator inlet exhaust gas temperatures to increase without significant cost increase. (2) Further characterization of the creep and oxidation (dry and humid air) properties of nickel alloy foils (less than 0.13 mm thick) to allow the economical use of these materials. (3) Increasing the use of advanced robotic systems and advanced in-process statistical measurement systems.

  11. Characterization of the surface properties of Illinois Basin coals. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Demir, I.; Harvey, R.D.; Lizzio, A.A.

    1992-08-01

    Understanding the surface properties of coal is important for predicting the physical-chemical behavior of coal during coal cleaning combustion and conversion. Data on surface properties help coal scientists and engineers in the design of effective coal desulfurization processes, and thereby aid in the marketability of Illinois Basin coals. The main objective of this project is to characterize the surface properties (surface area, porosity, pore size distribution, surface charge, and surface chemical structure) of eight coals in the Illinois Basin Coal Sample Program (IBCSP), and explore statistical relationships between surface properties and other coal characteristics.

  12. Chemical, electronic, and magnetic structure of LaFeCoSi alloy: Surface and bulk properties

    SciTech Connect (OSTI)

    Lollobrigida, V.; Basso, V.; Kuepferling, M.; Coïsson, M.; Olivetti, E. S.; Celegato, F.; Borgatti, F.; Torelli, P.; Panaccione, G.; Tortora, L.; Stefani, G.; Offi, F.

    2014-05-28

    We investigate the chemical, electronic, and magnetic structure of the magnetocaloric LaFeCoSi compound with bulk and surface sensitive techniques. We put in evidence that the surface retains a soft ferromagnetic behavior at temperatures higher than the Curie temperature of the bulk due to the presence of Fe clusters at the surface only. This peculiar magnetic surface effect is attributed to the exchange interaction between the ferromagnetic Fe clusters located at the surface and the bulk magnetocaloric alloy, and it is used here to monitor the magnetic properties of the alloy itself.

  13. Modifying zirconia solid electrolyte surface property to enhance oxide transport

    SciTech Connect (OSTI)

    Liaw, B.Y.; Song, S.Y.

    1996-12-31

    Bismuth-strontium-calcium-copper oxide (Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8}, BSCCO) is known for its high T{sub c} superconducting behavior and mixed conducting property. The applicability of similar high T{sub c} cuprates for intermediate-temperature solid oxide fuel cell (SOFC) application has been studied recently. We investigated the electrochemical behavior of several Ag{vert_bar}BSCCO{vert_bar}10 mol% yttria-stabilized zirconia (YSZ){vert_bar}Ag and Ag{vert_bar}YSZ{vert_bar}Ag cells using complex impedance spectroscopy. A highly uniform and porous microstructure was observed at the interface of the YSZ and BSCCO. The ionic conductivity determined from the Nyquest plots in the temperature range of 200-700{degrees}C agrees with the values reported in the literature. The specific resistance of the BSCCO{vert_bar}YSZ interface was also determined to be lower than those of the conventional manganite electrode, suggesting that BSCCO seems attractive for cathode applications in SOFC.

  14. The influence of surface functionalisation on the electrical properties and thermal stability of nanodiamonds

    SciTech Connect (OSTI)

    Welch, Joseph O; Li, Pei; Chaudhary, Aysha; Edgington, Robert; Jackman, Richard B.

    2014-10-07

    Detonation nanodiamond (ND) has recently emerged as a useful new class of diamond material. However, to date there has been little investigation of the electrical properties of this material. Due to the nanoscale dimensions, the surface functionalisation of the individual ND is of particular importance to the characteristics of ND films. Here, hydrogen and oxygen termination of ND, verified using Fourier transform infrared spectroscopy, are shown to strongly influence the electronic properties of NDs. Hydrogen terminated ND exhibiting a far greater resilience to thermal decomposition when compared to the oxygen terminated NDs. Moreover, H-NDs also displayed so-called “surface conductivity,” a property displayed by hydrogen-terminated bulk diamond films, whilst O-NDs display properties high resistivity. These results indicate that under the correct conditions ND layers can display similar electrical properties to “bulk” diamond thin films.

  15. Effect of Surface Termination on the Electonic Properties of LaNiO₃ Films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kumah, Divine P.; Malashevich, Andrei; Disa, Ankit S.; Arena, Dario A.; Walker, Fred J.; Ismail-Beigi, Sohrab; Ahn, Charles H.

    2014-11-06

    The electronic and structural properties of thin LaNiO₃ films grown by using molecular beam epitaxy are studied as a function of the net ionic charge of the surface terminating layer. We demonstrate that electronic transport in nickelate heterostructures can be manipulated through changes in the surface termination due to a strong coupling of the surface electrostatic properties to the structural properties of the Ni—O bonds that govern electronic conduction. We observe experimentally and from first-principles theory an asymmetric response of the structural properties of the films to the sign of the surface charge, which results from a strong interplay betweenmore » electrostatic and mechanical boundary conditions governing the system. The structural response results in ionic buckling in the near-surface NiO₂ planes for films terminated with negatively charged NiO₂ and bulklike NiO₂ planes for films terminated with positively charged LaO planes. The ability to modify transport properties by the deposition of a single atomic layer can be used as a guiding principle for nanoscale device fabrication.« less

  16. Effect of Surface Termination on the Electonic Properties of LaNiO? Films

    SciTech Connect (OSTI)

    Kumah, Divine P.; Malashevich, Andrei; Disa, Ankit S.; Arena, Dario A.; Walker, Fred J.; Ismail-Beigi, Sohrab; Ahn, Charles H.

    2014-11-06

    The electronic and structural properties of thin LaNiO? films grown by using molecular beam epitaxy are studied as a function of the net ionic charge of the surface terminating layer. We demonstrate that electronic transport in nickelate heterostructures can be manipulated through changes in the surface termination due to a strong coupling of the surface electrostatic properties to the structural properties of the NiO bonds that govern electronic conduction. We observe experimentally and from first-principles theory an asymmetric response of the structural properties of the films to the sign of the surface charge, which results from a strong interplay between electrostatic and mechanical boundary conditions governing the system. The structural response results in ionic buckling in the near-surface NiO? planes for films terminated with negatively charged NiO? and bulklike NiO? planes for films terminated with positively charged LaO planes. The ability to modify transport properties by the deposition of a single atomic layer can be used as a guiding principle for nanoscale device fabrication.

  17. Fe and Co nanostructures embedded into the Cu(100) surface: Self-Organization and magnetic properties

    SciTech Connect (OSTI)

    Kolesnikov, S. V. Klavsyuk, A. L.; Saletsky, A. M.

    2015-10-15

    The self-organization and magnetic properties of small iron and cobalt nanostructures embedded into the first layer of a Cu(100) surface are investigated using the self-learning kinetic Monte Carlo method and density functional theory. The similarities and differences between the Fe/Cu(100) and the Co/Cu(100) are underlined. The time evolution of magnetic properties of a copper monolayer with embedded magnetic atoms at 380 K is discussed.

  18. Communication: The correct interpretation of surface hopping trajectories: How to calculate electronic properties

    SciTech Connect (OSTI)

    Landry, Brian R.; Falk, Martin J.; Subotnik, Joseph E.

    2013-12-07

    In a recent paper, we presented a road map for how Tully's fewest switches surface hopping (FSSH) algorithm can be derived, under certain circumstances, from the mixed quantum-classical Liouville equation. In this communication, we now demonstrate how this new interpretation of surface hopping can yield significantly enhanced results for electronic properties in nonadiabatic calculations. Specifically, we calculate diabatic populations for the spin-boson problem using FSSH trajectories. We show that, for some Hamiltonians, without changing the FSSH algorithm at all but rather simply reinterpreting the ensemble of surface hopping trajectories, we recover excellent results and remove any and all ambiguity about the initial condition problem.

  19. Optical, electrical and surface properties of annealed CdO:Mg thin films prepared by spray pyrolysis

    SciTech Connect (OSTI)

    Karakaya, Seniye E-mail: oozbas@ogu.edu.tr; Ozbas, Omer E-mail: oozbas@ogu.edu.tr

    2013-12-16

    The use of transparent conducting oxides in optoelectronic and photovoltaic devices has encouraged research on this field in recent years. Especially, cadmium oxide is a promising material for solar cell application but also for photodiodes and gas sensors. Mg doped CdO (CdO:Mg) films have been prepared on glass substrates by the ultrasonic spray pyrolysis (USP) technique. After the production, the films have been annealed in air atmosphere at 475C and half hour. Results on surface, optical and electrical properties of the films as a function of the thermal annealing have been reported. Thicknesses of the films have been determined by the filmetrics thin film measurement system. Transmission and absorbance spectra have been taken by UV-vis spectrophotometer. Atomic Force Microscopy (AFM) analysis indicates that the roughness of the surface decreases upon increasing Mg concentration. The minimum resistivity value of the films was 210{sup ?3} ? cm.

  20. Electric double layer at metal oxide surfaces: Static properties of the cassiterite - Water Interface

    SciTech Connect (OSTI)

    Vlcek, Lukas; Zhang, Zhan; Machesky, Michael L.; Wesolowski, David J

    2007-04-01

    The structure of water at the (110) surface of cassiterite ({alpha}-SnO{sub 2}) at ambient conditions was studied by means of molecular dynamics simulations and X-ray crystal truncation rod experiments and interpreted with the help of the revised MUSIC model of surface protonation. The interactions of the metal oxide in the simulations were described by a recently developed classical force field based on the SPC/E model of water. Two extreme cases of completely hydroxylated and nonhydroxylated surfaces were considered along with a mixed surface with 50% dissociation. To study the dependence of the surface properties on pH, neutral and negatively charged variants of the surfaces were constructed. Axial and lateral density distributions of water for different types of surfaces were compared to each other and to experimental axial density distributions found by X-ray experiments. Although significant differences were found between the structures of the studied interfaces, the axial distances between Sn and O atoms are very similar and therefore could not be clearly distinguished by the diffraction technique. The explanation of structures observed in the density distributions was provided by a detailed analysis of hydrogen bonding in the interfacial region. It revealed qualitatively different hydrating patterns formed at neutral hydroxylated and nonhydroxylated surfaces and suggested a preference for the dissociative adsorption of water. At negatively charged surfaces, however, the situation can be reversed by the electric field stabilizing a hydrogen bond network similar to that found at the neutral nonhydroxylated surface. Comparison with previously studied rutile ({alpha}-TiO{sub 2}) surfaces provided insight into the differences between the hydration of these two metal oxides, and an important role was ascribed to their different lattice parameters. A link to macroscopic properties was provided by the revised MUSIC surface protonation model. Explicit use of the Sn

  1. Electric double layer at metal oxide surfaces:static properties of the cassiterite-water interface.

    SciTech Connect (OSTI)

    Vlcek, L.; Zhang, Z.; Machesky, M .L.; Fenter, P.; Rosenqvist, J.; Wesolowski, D. J.; Anovitz, L. M.; Predota, M.; Cummings, P. T.; Vanderbilt Univ.; ORNL; Univ. of South Bohimia; Illinois State Water Survey

    2007-03-24

    The structure of water at the (110) surface of cassiterite ({alpha}-SnO{sub 2}) at ambient conditions was studied by means of molecular dynamics simulations and X-ray crystal truncation rod experiments and interpreted with the help of the revised MUSIC model of surface protonation. The interactions of the metal oxide in the simulations were described by a recently developed classical force field based on the SPC/E model of water. Two extreme cases of completely hydroxylated and nonhydroxylated surfaces were considered along with a mixed surface with 50% dissociation. To study the dependence of the surface properties on pH, neutral and negatively charged variants of the surfaces were constructed. Axial and lateral density distributions of water for different types of surfaces were compared to each other and to experimental axial density distributions found by X-ray experiments. Although significant differences were found between the structures of the studied interfaces, the axial distances between Sn and O atoms are very similar and therefore could not be clearly distinguished by the diffraction technique. The explanation of structures observed in the density distributions was provided by a detailed analysis of hydrogen bonding in the interfacial region. It revealed qualitatively different hydrating patterns formed at neutral hydroxylated and nonhydroxylated surfaces and suggested a preference for the dissociative adsorption of water. At negatively charged surfaces, however, the situation can be reversed by the electric field stabilizing a hydrogen bond network similar to that found at the neutral nonhydroxylated surface. Comparison with previously studied rutile ({alpha}-TiO{sub 2}) surfaces provided insight into the differences between the hydration of these two metal oxides, and an important role was ascribed to their different lattice parameters. A link to macroscopic properties was provided by the revised MUSIC surface protonation model. Explicit use of the Sn

  2. Rough surface electrical contact resistance considering scale dependent properties and quantum effects

    SciTech Connect (OSTI)

    Jackson, Robert L.; Crandall, Erika R.; Bozack, Michael J.

    2015-05-21

    The objective of this work is to evaluate the effect of scale dependent mechanical and electrical properties on electrical contact resistance (ECR) between rough surfaces. This work attempts to build on existing ECR models that neglect potentially important quantum- and size-dependent contact and electrical conduction mechanisms present due to the asperity sizes on typical surfaces. The electrical conductance at small scales can quantize or show a stepping trend as the contact area is varied in the range of the free electron Fermi wavelength squared. This work then evaluates if these effects remain important for the interface between rough surfaces, which may include many small scale contacts of varying sizes. The results suggest that these effects may be significant in some cases, while insignificant for others. It depends on the load and the multiscale structure of the surface roughness.

  3. Topography and Mechanical Property Mapping of International Simple Glass Surfaces with Atomic Force Microscopy

    SciTech Connect (OSTI)

    Pierce, Eric M

    2014-01-01

    Quantitative Nanomechanical Peak Force (PF-QNM) TappingModeTM atomic force microscopy measurements are presented for the first time on polished glass surfaces. The PF-QNM technique allows for topography and mechanical property information to be measured simultaneously at each pixel. Results for the international simple glass which represents a simplified version of SON68 glass suggests an average Young s modulus of 78.8 15.1 GPa is within the experimental error of the modulus measured for SON68 glass (83.6 2 GPa) with conventional approaches. Application of the PF-QNM technique will be extended to in situ glass corrosion experiments with the goal of gaining atomic-scale insights into altered layer development by exploiting the mechanical property differences that exist between silica gel (e.g., altered layer) and pristine glass surface.

  4. Method And Apparatus For Two Dimensional Surface Property Analysis Based On Boundary Measurement

    DOE Patents [OSTI]

    Richardson, John G.

    2005-11-15

    An apparatus and method for determining properties of a conductive film is disclosed. A plurality of probe locations selected around a periphery of the conductive film define a plurality of measurement lines between each probe location and all other probe locations. Electrical resistance may be measured along each of the measurement lines. A lumped parameter model may be developed based on the measured values of electrical resistance. The lumped parameter model may be used to estimate resistivity at one or more selected locations encompassed by the plurality of probe locations. The resistivity may be extrapolated to other physical properties if the conductive film includes a correlation between resistivity and the other physical properties. A profile of the conductive film may be developed by determining resistivity at a plurality of locations. The conductive film may be applied to a structure such that resistivity may be estimated and profiled for the structure's surface.

  5. The effect of alkali metal on the surface properties of potassium doped Au-Beta zeolites

    SciTech Connect (OSTI)

    Sobczak, Izabela; Rydz, Michal; Ziolek, Maria

    2013-02-15

    Graphical abstract: Display Omitted Highlights: ► Interaction of gold with K leads to the change of electronic state and redox properties of gold. ► The amount of potassium incorporated into Au-zeolites determines the size of gold particles. ► K(0.2 wt.%)/Au-Beta exhibits the best performance in decomposition of N{sub 2}O and removal of Bu{sub 2}S. -- Abstract: Beta zeolite was applied as support for gold introduced by gold-precipitation method and potassium added by impregnation or adsorption. The effect of zeolite composition and the amount of potassium introduced on the surface properties of the final materials was considered. Moreover, the interaction of gold and potassium species was found to be related to the adsorptive and catalytic behaviour of zeolites in NO reduction with propene and deodorization. K/Au-Beta(Impregnated) exhibits the best performance in the above mentioned processes because of the small gold particles (between 2 and 5 nm) and interaction of gold with potassium species leading to the change of electronic properties of the surface (the appearance of cationic gold species). Potassium added as a promoter improves the catalytic properties of Au-zeolite in N{sub 2}O decomposition and also in deodorization (increase of the ability to dibutyl sulphide oxidation). The catalysts prepared were characterized by XRD, XPS, UV–vis, TEM, pyridine adsorption combined with FTIR and test reaction (2-propanol transformation).

  6. Enhanced visible light photocatalytic property of red phosphorus via surface roughening

    SciTech Connect (OSTI)

    Li, Weibing; Yue, Jiguang; Hua, Fangxia; Feng, Chang; Bu, Yuyu; Chen, Zhuoyuan

    2015-10-15

    Highlights: • Photocatalytic RhB degradation of red phosphorus was studied for the first time. • Surface rough can increase the photocatalysis reaction active sites. • Surface rough red phosphorus possesses high photocatalytic performance. • Surface rough red phosphorus has high industrial application value. - Abstract: Red phosphorus with rough surface (SRP) was prepared by catalyst-assisted hydrothermal synthesis using Co{sup 2+} catalyst. The photocatalytic Rhodamine B (RhB) degradation of red phosphorus (RP) and SRP was studied for the first time in this work. Rough surface can enhance the dye adsorption ability of RP. About 75% RhB was absorbed by SRP after 30-min adsorption in 100 ml RhB solution with concentration of 10 mg l{sup −1} in dark. After only 10 min of illumination by visible light, more than 95% RhB was degraded, indicating that SRP has a great application potential in the area of photocatalysis. The photocatalytic RhB degradation properties of RP are much weaker than those of SRP. The increase of the number of the active sites for the photocatalytic reactions, the electron mobility and the lifetime of the photogenerated electrons cause the significant improvement of the photocatalytic performance of SRP based on the experimental results obtained.

  7. Spectroscopic Investigation of Surface Dependent Acid-base Property of Ceria Nanoshapes

    SciTech Connect (OSTI)

    Wu, Zili; Mann, Amanda K; Li, Meijun; Overbury, Steven {Steve} H

    2015-01-01

    In addition to their well-known redox character, the acid-base property is another interesting aspect of ceria-based catalysts. Herein, the effect of surface structure on the acid-base property of ceria was studied in detail by utilizing ceria nanocrystals with different morphologies (cubes, octahedra and rods) that exhibit crystallographically well-defined surface facets. The nature, type, strength and amount of acid and base sites on these ceria nanoshapes were investigated via in situ IR spectroscopy combined with various probe molecules. Pyridine adsorption shows the presence of Lewis acid sites (Ce cations) on the ceria nanoshapes. These Lewis acid sites are relatively weak and similar in strength among the three nanoshapes according to the probing by both pyridine and acetonitrile. Both Br nsted (hydroxyl group) and Lewis (surface lattice oxygen) base sites are present on the ceria nanoshapes as probed by CO2 adsorption. CO2 and chloroform adsorption indicate that the strength and amount of the Lewis base sites are shape dependent: rods > cubes > octahedra. The weak and strong surface dependence of the acid and base sites, respectively, are a result of interplay between the surface structure dependent coordination unsaturation status of the Ce cations and O anions and the amount of defect sites on the three ceria nanoshapes. Furthermore, it was found that the nature of the acid-base sites of ceria can be impacted by impurities, such as Na and P residues that result from their use as structure-directing reagent in the hydrothermal synthesis of the ceria nanocrystals. This observation calls for precaution in interpreting the catalytic behavior of nanoshaped ceria where trace impurities may be present.

  8. Spectroscopic Investigation of Surface-Dependent Acid–Base Property of Ceria Nanoshapes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Zili; Mann, Amanda K. P.; Li, Meijun; Overbury, Steven H.

    2015-03-12

    In addition to their well-known redox character, the acid-base property is another interesting aspect of ceria-based catalysts. Thus, the effect of surface structure on the acid-base property of ceria was studied in detail by utilizing ceria nanocrystals with different morphologies (cubes, octahedra and rods) that exhibit crystallographically well-defined surface facets. The nature, type, strength and amount of acid and base sites on these ceria nanoshapes were investigated via in situ IR spectroscopy combined with various probe molecules. Pyridine adsorption shows the presence of Lewis acid sites (Ce cations) on the ceria nanoshapes. These Lewis acid sites are relatively weak andmore » similar in strength among the three nanoshapes according to the probing by both pyridine and acetonitrile. Both Br nsted (hydroxyl group) and Lewis (surface lattice oxygen) base sites are present on the ceria nanoshapes as probed by CO2 adsorption. CO2 and chloroform adsorption indicate that the strength and amount of the Lewis base sites are shape dependent: rods > cubes > octahedra. Moreover, the weak and strong surface dependence of the acid and base sites, respectively, are a result of interplay between the surface structure dependent coordination unsaturation status of the Ce cations and O anions and the amount of defect sites on the three ceria nanoshapes. Furthermore, it was found that the nature of the acid-base sites of ceria can be impacted by impurities, such as Na and P residues that result from their use as structure-directing reagent in the hydrothermal synthesis of the ceria nanocrystals. Finally, our observation calls for precaution in interpreting the catalytic behavior of nanoshaped ceria where trace impurities may be present.« less

  9. Spectroscopic Investigation of Surface Dependent Acid-base Property of Ceria Nanoshapes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Zili; Mann, Amanda K; Li, Meijun; Overbury, Steven

    2015-01-01

    In addition to their well-known redox character, the acid-base property is another interesting aspect of ceria-based catalysts. Herein, the effect of surface structure on the acid-base property of ceria was studied in detail by utilizing ceria nanocrystals with different morphologies (cubes, octahedra and rods) that exhibit crystallographically well-defined surface facets. The nature, type, strength and amount of acid and base sites on these ceria nanoshapes were investigated via in situ IR spectroscopy combined with various probe molecules. Pyridine adsorption shows the presence of Lewis acid sites (Ce cations) on the ceria nanoshapes. These Lewis acid sites are relatively weak andmore » similar in strength among the three nanoshapes according to the probing by both pyridine and acetonitrile. Both Br nsted (hydroxyl group) and Lewis (surface lattice oxygen) base sites are present on the ceria nanoshapes as probed by CO2 adsorption. CO2 and chloroform adsorption indicate that the strength and amount of the Lewis base sites are shape dependent: rods > cubes > octahedra. The weak and strong surface dependence of the acid and base sites, respectively, are a result of interplay between the surface structure dependent coordination unsaturation status of the Ce cations and O anions and the amount of defect sites on the three ceria nanoshapes. Furthermore, it was found that the nature of the acid-base sites of ceria can be impacted by impurities, such as Na and P residues that result from their use as structure-directing reagent in the hydrothermal synthesis of the ceria nanocrystals. This observation calls for precaution in interpreting the catalytic behavior of nanoshaped ceria where trace impurities may be present.« less

  10. Modification of Bi:YIG film properties by substrate surface ion pre-treatment

    SciTech Connect (OSTI)

    Shaposhnikov, A.N.; Prokopov, A.R.; Karavainikov, A.V.; Berzhansky, V.N.; Mikhailova, T.V.; Kotov, V.A.; Balabanov, D.E.; Sharay, I.V.; Salyuk, O.Y.; Vasiliev, M.; Golub, V.O.

    2014-07-01

    Highlights: Effects of substrates ion beam treatment on magnetoptical properties Bi:YIG films. Substrate surface damage results in sign inversion of the magneto-optical effects. Atomically smooth films growth takes place on low energy ions treated substrates. High energy ions treatment results in selective nucleation mechanism of the growth. - Abstract: The effect of a controlled ion beam pre-treatment of (1 1 1)-oriented Gd{sub 3}Ga{sub 5}O{sub 12} substrates on the magneto-optical properties and surface morphology of the ultrathin bismuth-substituted yttriumiron garnet films with a composition Bi{sub 2.8}Y{sub 0.2}Fe{sub 5}O{sub 12} was studied. It has been shown that the observed sign inversion of magneto-optical effects (Faraday rotation and magnetic circular dichroism) observed in films that were deposited on the GGG substrate pre-treated by 1 keV and 4 keV Ar{sup +} ion beams is a result of the substrate surface amorphization caused by the ion bombardment.

  11. Investigations of the Electronic Properties and Surface Structures of Aluminium-Rich Quasicrystalline Alloys

    SciTech Connect (OSTI)

    Jason A. Barrow

    2003-08-05

    The work presented in this dissertation has investigated three distinct areas of interest in the field of quasicrystals: bulk structure, transport properties, and electronic structure. First, they have described the results of a study which explored the fundamental interactions between the atomic species of the icosahedral Al-Pd-Mn quasicrystal. The goal of this work was to determine whether the pseudo-MacKay or Bergman type clusters have a special stability or are merely a geometric coincidence. This was carried out by using laser vaporization to produce gas-phase metal clusters, which were analyzed using time-of-flight mass spectrometry. Both the kinetic and thermodynamic stabilities of the clusters were probed. The data indicated no special stability for either pseudo-MacKay or Bergman type clusters as isolated units. This, however, is not proof that these clusters are simply a geometric coincidence. It is possible that such clusters only have stability in the framework of the bulk matrix and do not exist as isolated units. Next, they have reported their investigations of the bulk thermal transport properties of a decagonal Al-Ni-Co two dimensional quasicrystal in the temperature range 373K-873K. The properties of a sample oriented along the periodic axis and another oriented along the aperiodic axis were measured. A high degree of anisotropy was observed between the aperiodic and periodic directions. Additionally, the properties were measured for a sample miscut to an orientation 45{sup o} off-axis. The properties of the miscut sample were shown to have good agreement with a theoretical model used to describe thermal transport in metallic single crystals. This model only considers thermal transport by a free-electron gas; therefore, agreement with experimental data suggests the validity of the Drude free-electron model for the decagonal Al-Ni-Co at these temperatures. Consequently, the observed anisotropy may be adequately described using classical transport

  12. Characterization of the surface properties of Illinois basin coals. Technical report, March 1, 1992--May 31, 1992

    SciTech Connect (OSTI)

    Demir, I.; Harvey, R.D.; Lizzio, A.A.

    1992-10-01

    The main objective of this project is to characterize the surface properties (surface area, pore size distribution, surface charge, and surface chemical structure) of eight coals in the Illinois Basin Coal Sample Program (IBCSP), and explore statistical relationships between surface properties and other coal characteristics. We completed analyses of -100 and -400 mesh, unoxidized IBCSP coals for surface area and pore volume distribution. Two thirds or more of the measured surface area of the samples are derived from the micropores (3.5-20 {Angstrom}). The mesopore surface areas of IBC-101, IBC-102, and IBC-107 coals are higher than the other coals, and the mesopore surface area of the IBC-103 coal is the smallest among all the coals tested. The pore volume in pores less than about 1800 {Angstrom} in diameter varies about five-fold among the samples. The differences between the samples suggest that these coals may show different physical-chemical behavior during various processes involving preparation and utilization of coal. Statistical analyses of the measured and other available coal properties indicate that the micropore surface area correlates positively with carbon content and vitrinite reflectance and negatively with volatile matter. and hydrogen content of the coal. The mesopore surface area correlates negatively with carbon content but positively with oxygen and hydrogen contents of the coal. The statistical correlations can be used to predict one parameter from another one.

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chinese Researchers Report Reliable Method for Monitoring Soil Moisture Submitter: Bhattacharya, A., Pacific Northwest National Laboratory Area of Research: Surface Properties Working Group(s): Cloud Life Cycle Journal Reference: Sun L, R Sun, XW Li, SL Liang, and RH Zhang. 2012. "Monitoring surface soil moisture status based on remotely sensed surface temperature and vegetation index information." Agricultural and Forest Meteorology, 166, doi:10.1016/j.agrformet.2012.07.015. Shown

  14. ''Green'' Biopolymers for Improved Decontamination of Metals from Surfaces: Sorptive Characterization and Coating Properties

    SciTech Connect (OSTI)

    Davison, Brian H.; Kuritz, Tanya

    2000-06-01

    The proposed research aims to develop a fundamental understanding of important biological and physical chemical parameters for effective decontamination of metal surfaces using environmentally benign aqueous-based biopolymer solutions. Understanding how heavy metal-chelating biopolymers coat and interact with contaminated surfaces will benefit the development of novel, safe, easy-to-apply decontamination methodologies for removal of radionuclides and heavy metals. The benefits of these methodologies will include the following: (1) decreased exposure hazards for workers; (2) decreased secondary waste generation; (3) increased efficiency of decontamination; (4) positive public appeal and development of novel, nature-friendly business opportunities; and (5) lower cost of cleanup to the government. We propose to use aqueous biopolymer solutions to coat a contaminated metal surface (i.e., steel), solubilize the heavy metals (e.g., uranium) from the surface, and bind the heavy metals into the biopolymer. The biopolymer coating (containing the immobilized hazardous metal contaminants) will then be removed as a viscous film, as a dry powder, or by washing. This ''apply, wait, and remove'' procedure will reduce the amount of worker time spent in decontamination activities.

  15. ''Green'' Biopolymers for Improved Decontamination of Metals from Surfaces: Sorptive Characterization and Coating Properties

    SciTech Connect (OSTI)

    Davison, Brian H.

    2002-04-30

    The proposed research aimed to develop a fundamental understanding of important biological and physical chemical parameters for effective decontamination of metal surfaces using environmentally benign aqueous-based biopolymer solutions. Understanding how heavy metal-chelating biopolymers coat and interact with contaminated surfaces will benefit the development of novel, safe, easy-to-apply decontamination methodologies for removal of radionuclides and heavy metals. The benefits of these methodologies include the following: decreased exposure hazards for workers; decreased secondary waste generation; increased efficiency of decontamination; positive public appeal and development of novel, nature-friendly business opportunities; and lower cost of cleanup to the government. We proposed to use aqueous biopolymer solutions to coat a contaminated metal surface (i.e., steel), solubilize the heavy metals (e.g., uranium) from the surface, and bind the heavy metals into the biopolymer. The biopolymer coating (containing the immobilized hazardous metal contaminants) was to be removed as a viscous film, as a dry powder, or by washing. This ''apply, wait, and remove'' procedure will reduce the amount of worker time spent in decontamination activities.

  16. ''Green'' Biopolymers for Improved Decontamination of Metals from Surfaces: Sorptive Characterization and Coating Properties

    SciTech Connect (OSTI)

    Davison, Brian H.; Kurtiz,Tanya

    1999-06-01

    The proposed research aims to develop a fundamental understanding of important biological and physical chemical parameters for effective decontamination of metal surfaces using environmentally benign aqueous-based biopolymer solutions. Understanding how heavy metal-chelating biopolymers coat and interact with contaminated surfaces will benefit the development of novel, safe, easy-to-apply decontamination methodologies for removal of radionuclides and heavy metals. The benefits of these methodologies will include the following: (1) decreased exposure hazards for workers; (2) decreased secondary waste generation; (3) increased efficiency of decontamination; (4) positive public appeal and development of novel, nature-friendly business opportunities; and (5) lower cost of cleanup to the government. We propose to use aqueous biopolymer solutions to coat a contaminated metal surface (i.e., steel), solubilize the heavy metals (e.g., uranium) from the surface, and bind the heavy metals into the biopolymer. The biopolymer coating (containing the immobilized hazardous metal contaminants) will then be removed as a viscous film, as a dry powder, or by washing. This ''apply, wait, and remove'' procedure will reduce the amount of worker time spent in decontamination activities.

  17. Optimization of the optical properties of nanostructured silicon surfaces for solar cell applications

    SciTech Connect (OSTI)

    Zhou, Di; Pennec, Y.; Djafari-Rouhani, B.; Lambert, Y.; Deblock, Y.; Stiévenard, D.; Cristini-Robbe, O.; Xu, T.; Faucher, M.

    2014-04-07

    Surface nanostructuration is an important challenge for the optimization of light trapping in solar cell. We present simulations on both the optical properties and the efficiency of micro pillars—MPs—or nanocones—NCs—silicon based solar cells together with measurements on their associated optical absorption. We address the simulation using the Finite Difference Time Domain method, well-adapted to deal with a periodic set of nanostructures. We study the effect of the period, the bottom diameter, the top diameter, and the height of the MPs or NCs on the efficiency, assuming that one absorbed photon induces one exciton. This allows us to give a kind of abacus involving all the geometrical parameters of the nanostructured surface with regard to the efficiency of the associated solar cell. We also show that for a given ratio of the diameter over the period, the best efficiency is obtained for small diameters. For small lengths, MPs are extended to NCs by changing the angle between the bottom surface and the vertical face of the MPs. The best efficiency is obtained for an angle of the order of 70°. Finally, nanostructures have been processed and allow comparing experimental results with simulations. In every case, a good agreement is found.

  18. Ash Deposit Formation and Deposit Properties. A Comprehensive Summary of Research Conducted at Sandia's Combustion Research Facility

    SciTech Connect (OSTI)

    Larry L. Baxter

    2000-08-01

    This report summarizes experimental and theoretical work performed at Sandia's Combustion Research Facility over the past eight years on the fate of inorganic material during coal combustion. This work has been done under four broad categories: coal characterization, fly ash formation, ash deposition, and deposit property development. The objective was to provide sufficient understanding of these four areas to be able to predict coal behavior in current and advanced conversion systems. This work has led to new characterization techniques for fuels that provide, for the first time, systematic and species specific information regarding the inorganic material. The transformations of inorganic material during combustion can be described in terms of the net effects of the transformations of these individual species. Deposit formation mechanisms provide a framework for predicting deposition rates for abroad range of particle sizes. Predictions based on these rates many times are quite accurate although there are important exceptions. A rigorous framework for evaluating deposit has been established. Substantial data have been obtained with which to exercise this framework, but this portion of the work is less mature than is any other. Accurate prediction of deposit properties as functions of fuel properties, boiler design, and boiler operating conditions represents the single most critical area where additional research is needed.

  19. Magnetic properties on the surface of FeAl stripes induced by nanosecond pulsed laser irradiation

    SciTech Connect (OSTI)

    Kaiju, H. Kondo, K.; Ishibashi, A.; Yoshida, Y.; Watanabe, S.; Yoshimi, K.

    2014-05-07

    We demonstrate the formation of magnetic nanostripes on the surface of Fe{sub 52}Al{sub 48} induced by nanosecond pulsed laser irradiation and investigate their magnetic properties. The magnetic stripe consists of a disordered A2 phase of Fe-Al alloys with Al-oxide along the [110] direction on the (111)-oriented plane. According to the focused magneto-optical Kerr effect measurement, the coercive force of the magnetic stripe obeys the 1/cos?? law, where ? is the field rotation angle estimated from the stripe direction. Also, the jump field can be observed in the magnetic hysteresis loop. These results indicate that the magnetization reversal in the magnetic stripe originates from the domain pinning, showing that the magnetization rotates incoherently.

  20. Surface driven effects on magnetic properties of antiferromagnetic LaFeO{sub 3} nanocrystalline ferrite

    SciTech Connect (OSTI)

    Sendil Kumar, A. E-mail: anilb42@gmail.com; Manivel Raja, M.; Bhatnagar, Anil K. E-mail: anilb42@gmail.com

    2014-09-21

    LaFeO{sub 3} nanocrystalline ferrites were synthesized through sol-gel method in different size distributions and the effect of finite size on magnetic properties is investigated. Results of magnetization and Mössbauer measurements show that superparamagnetism and weak ferromagnetic behavior in some of the size distributions. The origin of the superparamagnetism is from fine particles similar to ferromagnetic single domains and the weak ferromagnetism comes from surface spin disorder caused by Dzyaloshinskii-Moriya interaction. The magnetic ground state of LaFeO{sub 3} nanoparticles differs from that of bulk, and the ground state is dictated by the finite size effect because density of states depends on the dimensionality of the sample.

  1. Surface properties of carbided molybdena-alumina and its activity for CO{sub 2} hydrogenation

    SciTech Connect (OSTI)

    Nagai, M.; Oshikawa, K.; Kurakami, T.; Miyao, T.; Omi, S.

    1998-11-15

    The surface properties of carbided molybdena-alumina were investigated through O{sub 2}-TPD and TPSR along with the catalytic activities of the supported catalysts for CO{sub 2} hydrogenation. The 1173 K-carbided catalyst exhibited the highest activity for the reaction on the CO adsorption basis. H{sub 2} pretreatment of the passivated 973 K-carbided catalyst at 773 K did not affect the activity for CO{sub 2} hydrogenation but a change was visible for the unpassivated catalyst. Through O{sub 2}-TPD, it was found that the adsorbed oxygen oxidizes the surface carbon of the molybdenum carbide to form CO{sub 2} and CO. A possible reaction scheme for the hydrogenation of CO{sub 2} is given, along with an explanation for the lowered activity of the passivated catalysts. {eta}-Mo{sub 3}C{sub 2} serves as an active site for CO{sub 2} hydrogenation. TPSR results were correlated with the activity to reveal that the number of Mo carbides depends on the activity for CO{sub 2} hydrogenation.

  2. Implementation of the Research Performance Progress Report (RPPR) and the SF-428 Tangible Personal Property Report Forms Family

    Broader source: Energy.gov [DOE]

    The new Research Performance Progress Report (RPPR) and SF-428 Tangible Personal Property Report Forms Family are now available for use.

  3. Performance of the BL4 Beamline for Surface and Interface Research at the Siam Photon Laboratory

    SciTech Connect (OSTI)

    Nakajima, Hideki; Buddhakala, Moragote; Chumpolkulwong, Somchai; Supruangnet, Ratchadapora; Kakizaki, Akito; Songsiriritthigul, Prayoon

    2007-01-19

    The evaluations of the monochromator of the BL4 beamline at the Siam Photon Laboratory were carried out by gas-phase photoionization measurements. The beamline employs a varied-line-spacing plane grating monochromator, which delivers photons with energies between 20-240 eV. The resolving power of the monochromator depends strongly with the alignment of the exit slit. The designed resolving power of 5000 has been achieved. The experimental station of the beamline has been upgraded for surface and interface research. The new experimental station removes the disadvantage and expands the capabilities of the old one in such a way that photoemission experiments using synchrotron light can be performed in parallel with other in situ surface analysis techniques, as well as with preparation of other samples. The new system includes the old photoemission system and a multi-UHV-chamber system. The standard surface-sensitive techniques available in addition to photoemission spectroscopy using synchrotron light are UPS, XPS, AES and LEED. The new experimental station also includes a metal MBE system for preparing samples for the studies of ultra-thin magnetic films and metal-semiconductor interfaces.

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Climatology of Midlatitude Continental Cloud Properties and Their Impact on the Surface Radiation Budget Submitter: Dong, X., University of Arizona Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Dong, X., P. Minnis, and B. Xi, 2005: A climatology of midlatitude continental clouds from ARM SGP site. Part I: Low-level Cloud Macrophysical, microphysical and radiative properties. J. Climate. 18, 1391-1410. Dong, X., B. Xi, and P.

  5. System and method for generating 3D images of non-linear properties of rock formation using surface seismic or surface to borehole seismic or both

    DOE Patents [OSTI]

    Vu, Cung Khac; Nihei, Kurt Toshimi; Johnson, Paul A.; Guyer, Robert A.; Ten Cate, James A.; Le Bas, Pierre-Yves; Larmat, Carene S.

    2016-06-07

    A system and method of characterizing properties of a medium from a non-linear interaction are include generating, by first and second acoustic sources disposed on a surface of the medium on a first line, first and second acoustic waves. The first and second acoustic sources are controllable such that trajectories of the first and second acoustic waves intersect in a mixing zone within the medium. The method further includes receiving, by a receiver positioned in a plane containing the first and second acoustic sources, a third acoustic wave generated by a non-linear mixing process from the first and second acoustic waves in the mixing zone; and creating a first two-dimensional image of non-linear properties or a first ratio of compressional velocity and shear velocity, or both, of the medium in a first plane generally perpendicular to the surface and containing the first line, based on the received third acoustic wave.

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cumuli Impact on Solar Radiation at Surface: Spectral Changes Download a printable PDF Submitter: Kassianov, E., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle, Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: Kassianov E, J Barnard, LK Berg, CN Long, and C Flynn. 2011. "Shortwave spectral radiative forcing of cumulus clouds from surface observations." Geophysical Research Letters, 38, L07801,

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Surface Albedo Data Set Enables Improved Radiative Transfer Calculations Download a printable PDF Submitter: McFarlane, S. A., U.S. Department of Energy Area of Research: Surface Properties Working Group(s): Cloud Life Cycle Journal Reference: McFarlane SA, K Gaustad, E Mlawer, C Long, and J Delamere. 2011. "Development of a high spectral resolution surface albedo product for the ARM Southern Great Plains central facility." Atmospheric Measurement Techniques, 4, 1713-1733. Time

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Characterization Data for the ARM SGP CART Site Submitter: Cialella, A. T., Brookhaven National Laboratory Area of Research: Surface Properties Journal Reference: N/A Figure 1 Figure 2 Figure 3 Figure 4 Figure 5 The ARM External Data Center (XDC) is continually searching for surface characterization data for the ARM CART sites. These data can provide a better understanding of geophysical parameters, allowing for more accurate parameterization within General Circulation Models (GCMs),

  9. Surface and Interface Properties of 1012 Unit Cells Thick Sputter Deposited Epitaxial CeO2Films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Saraf, L. V.; Wang, C. M.; Engelhard, M. H.; Nachimuthu, P.

    2008-01-01

    Ultrathin and continuous epitaxial films with relaxed lattice strain can potentially maintain more of its bulk physical and chemical properties and are useful as buffer layers. We study surface, interface, and microstructural properties of ultrathin (?1012 unit cells thick) epitaxial ceria films grown on single crystal YSZ substrates. The out-of -plane and in-plane lattice parameters indicate relaxation in the continuous film due to misfit dislocations seen by high-resolution transmission electron microscopy (HRTEM) and substrate roughness of?1-2 unit cells, confirmed by atomic force microscopy and HRTEM. A combination of secondary sputtering, lattice mismatch, substrate roughness, and surface reduction creating secondary phasemorewas likely the cause of surface roughness which should be reduced to a minimum level for effective use of it as buffer layers.less

  10. Surface and Interface Properties of 10–12 Unit Cells Thick Sputter Deposited Epitaxial CeO 2 Films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Saraf, L. V.; Wang, C. M.; Engelhard, M. H.; Nachimuthu, P.

    2008-01-01

    Ulmore » trathin and continuous epitaxial films with relaxed lattice strain can potentially maintain more of its bulk physical and chemical properties and are useful as buffer layers. We study surface, interface, and microstructural properties of ultrathin ( ∼ 10–12 unit cells thick) epitaxial ceria films grown on single crystal YSZ substrates. The out-of -plane and in-plane lattice parameters indicate relaxation in the continuous film due to misfit dislocations seen by high-resolution transmission electron microscopy (HRTEM) and substrate roughness of ∼ 1-2 unit cells, confirmed by atomic force microscopy and HRTEM. A combination of secondary sputtering, lattice mismatch, substrate roughness, and surface reduction creating secondary phase was likely the cause of surface roughness which should be reduced to a minimum level for effective use of it as buffer layers.« less

  11. Investigations of surface structural, dynamical, and magnetic properties of systems exhibiting multiferroicity, and topological phases by helium scattering spectroscopies

    SciTech Connect (OSTI)

    El-Batanouny, Maged

    2015-08-03

    We propose to investigate the surface structural, dynamics and magnetic properties of the novel class of topological insulator crystals, as well as crystals that exhibit multiferroicity, magnetoelectricity and thermoelectricity. Topological insulators (TIs) are a new class of insulators in which a bulk gap for electronic excitations is generated because of the strong spin-orbit coupling inherent to these systems. These materials are distinguished from ordinary insulators by the presence of gapless metallic surface states, resembling chiral edge modes in quantum Hall systems, but with unconventional spin textures. These exotic metallic states are formed by topological conditions that also render the electrons travelling on such surfaces insensitive to scattering by impurities. The electronic quasi-particles populating the topological surface state are Dirac fermions; they have a linear dispersion and thus are massless just like photons. We propose to investigate the interaction of these massless Dirac fermions with the massive lattice in the newly discovered crystals, Bi2Se3, Bi2Te3 and Sb2Te3. We shall use inelastic helium beam scattering from surfaces to search for related signatures in surface phonon dispersions mappings that cover the entire surface Brillouin zone of these materials. Our recent investigations of the (001) surface of the multiferroic crystals (Li/Na)Cu2O2 revealed an anomalous surface structural behavior where surface Cu$^{2+}$ row rise above the surface plane as the crystal was cooled. Subsequent worming revealed the onset of a thermally activated incommensurate surface phase, driven by the elevated rows. We are currently investigating the structure of the magnetic phases in these quasi-one-dimensional magnetic rows. Multiferroics are excellent candidates for large magnetoelectric response. We propose to extend this investigation to the class of delafossites which are also multiferroics and have been investigated as good candidates for

  12. Improvement in Clouds and the Earth's Radiant Energy System/Surface and Atmosphere Radiation Budget Dust Aerosol Properties, Effects on Surface Validation of Clouds and Radiative Swath

    SciTech Connect (OSTI)

    Rutan, D.; Rose, F.; Charlock, T.P.

    2005-03-18

    Within the Clouds and the Earth's Radiant Energy System (CERES) science team (Wielicki et al. 1996), the Surface and Atmospheric Radiation Budget (SARB) group is tasked with calculating vertical profiles of heating rates, globally, and continuously, beneath CERES footprint observations of Top of Atmosphere (TOA) fluxes. This is accomplished using a fast radiative transfer code originally developed by Qiang Fu and Kuo-Nan Liou (Fu and Liou 1993) and subsequently highly modified by the SARB team. Details on the code and its inputs can be found in Kato et al. (2005) and Rose and Charlock (2002). Among the many required inputs is characterization of the vertical column profile of aerosols beneath each footprint. To do this SARB combines aerosol optical depth information from the moderate-resolution imaging spectroradiometer (MODIS) instrument along with aerosol constituents specified by the Model for Atmosphere and Chemical Transport (MATCH) of Collins et al. (2001), and aerosol properties (e.g. single scatter albedo and asymmetry parameter) from Tegen and Lacis (1996) and OPAC (Hess et al. 1998). The publicly available files that include these flux profiles, called the Clouds and Radiative Swath (CRS) data product, available from the Langley Atmospheric Sciences Data Center (http://eosweb.larc.nasa.gov/). As various versions of the code are completed, publishable results are named ''Editions.'' After CRS Edition 2A was finalized it was found that dust aerosols were too absorptive. Dust aerosols have subsequently been modified using a new set of properties developed by Andy Lacis and results have been released in CRS Edition 2B. This paper discusses the effects of changing desert dust aerosol properties, which can be significant for the radiation budget in mid ocean, a few thousand kilometers from the source regions. Resulting changes are validated via comparison of surface observed fluxes from the Saudi Solar Village surface site (Myers et al. 1999), and the E13 site

  13. Theory of ground- and excited state-properties of solids, surfaces, and interfaces: Beyond density functional formalsim

    SciTech Connect (OSTI)

    Louie, S.G.

    1988-10-01

    Two recently developed approaches for calculating properties of materials going beyond the density functional formalism are discussed. For excited-state properties, a first-principles quasiparticle theory has been developed. The electron self-energy operator is calculated using the full dielectric matrix and the dressed Green's function. Electron excitation spectra are interpreted as transitions between quasiparticle states of an interacting many-electron system. For ground-state properties, a new method using nonlocal pseudopotentials in conjunction with the variational quantum Monte Carlo approach is introduced. Electron correlations are treated using the exact interaction with a correlated wavefunction of the Jastrow-Slater form. Selected examples from bulk, surface, and interface calculations are presented to illustrate the capabilities of these two approaches. 47 refs., 6 figs., 5 tabs.

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Preferred States of the Winter Arctic Atmosphere, Surface, and Sub-Surface Download a printable PDF Submitter: Del Genio, A. D., National Aeronautics and Space Administration Area of Research: Surface Properties Working Group(s): Cloud Life Cycle Journal Reference: Stramler K, AD Del Genio, and WB Rossow. 2011. "Synoptically driven Arctic winter states." Journal of Climate, 24(6), doi:10.1175/2010JCLI3817.1. SHEBA winter hourly surface net (down - up) longwave radiation flux versus

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM Program Surface Measurements for Aerosol Profiles Shown to Represent Integrated Column Measurements Submitter: Andrews, E., University of Colorado Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: Andrews, E., P. J. Sheridan, J. A. Ogren, and R. Ferrare (2004), In situ aerosol profiles over the Southern Great Plains cloud and radiation test bed site: 1. Aerosol optical properties, J. Geophys. Res., 109, D06208, doi:10.1029/2003JD004025. Delle Monache, L., K.

  16. Electrical properties and surface morphology of electron beam evaporated p-type silicon thin films on polyethylene terephthalate for solar cells applications

    SciTech Connect (OSTI)

    Ang, P. C.; Ibrahim, K.; Pakhuruddin, M. Z.

    2015-04-24

    One way to realize low-cost thin film silicon (Si) solar cells fabrication is by depositing the films with high-deposition rate and manufacturing-compatible electron beam (e-beam) evaporation onto inexpensive foreign substrates such as glass or plastic. Most of the ongoing research is reported on e-beam evaporation of Si films on glass substrates to make polycrystalline solar cells but works combining both e-beam evaporation and plastic substrates are still scarce in the literature. This paper studies electrical properties and surface morphology of 1 µm electron beam evaporated Al-doped p-type silicon thin films on textured polyethylene terephthalate (PET) substrate for application as an absorber layer in solar cells. In this work, Si thin films with different doping concentrations (including an undoped reference) are prepared by e-beam evaporation. Energy dispersion X-ray (EDX) showed that the Si films are uniformly doped by Al dopant atoms. With increased Al/Si ratio, doping concentration increased while both resistivity and carrier mobility of the films showed opposite relationships. Root mean square (RMS) surface roughness increased. Overall, the Al-doped Si film with Al/Si ratio of 2% (doping concentration = 1.57×10{sup 16} atoms/cm{sup 3}) has been found to provide the optimum properties of a p-type absorber layer for fabrication of thin film Si solar cells on PET substrate.

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capturing Biogenic Volatile Organic Compounds in a Coupled-Model System Compared to Observation PI Contact: Zhao, C., Pacific Northwest National Laboratory Area of Research: Surface Properties Working Group(s): Aerosol Life Cycle Journal Reference: Zhao C, M Huang, JD Fast, LK Berg, Y Qian, A Guenther, D Gu, M Shrivastava, Y Liu, S Walters, G Pfister, J Jin, JE Shilling, and C Warneke. 2016. "Sensitivity of biogenic volatile organic compounds to land surface parameterizations and vegetation

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Method for Satellite/Surface Comparisons Download a printable PDF Submitter: Long, C. N., NOAA Global Monitoring Division/CIRES Area of Research: Radiation Processes Working Group(s): Cloud Properties, Radiative Processes Journal Reference: Zhang Y, CN Long, WB Rossow, and EG Dutton. 2010. "Exploiting diurnal variations to evaluate the ISCCP-FD flux calculations and radiative-flux-analysis-processed surface observations from BSRN, ARM, and SURFRAD." Journal of Geophysical

  19. Structural and electrochemical properties of nanostructured nickel silicides by reduction and silicification of high-surface-area nickel oxide

    SciTech Connect (OSTI)

    Chen, Xiao [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)] [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China); Zhang, Bingsen [Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society (Germany)] [Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society (Germany); Li, Chuang; Shao, Zhengfeng [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)] [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China); Su, Dangsheng [Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society (Germany)] [Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society (Germany); Williams, Christopher T. [Department of Chemical Engineering, Swearingen Engineering Center, University of South Carolina (United States)] [Department of Chemical Engineering, Swearingen Engineering Center, University of South Carolina (United States); Liang, Changhai, E-mail: changhai@dlut.edu.cn [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)] [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)

    2012-03-15

    Graphical abstract: Nanostructured nickel silicides have been synthesized by reduction and silification of high-surface-area nickel oxide, and exhibited remarkably like-noble metal property, lower electric resistivity, and ferromagnetism at room temperature. Highlights: Black-Right-Pointing-Pointer NiSi{sub x} have been prepared by reduction and silification of high-surface-area NiO. Black-Right-Pointing-Pointer The structure of nickel silicides changed with increasing reaction temperature. Black-Right-Pointing-Pointer Si doping into nickel changed the magnetic properties of metallic nickel. Black-Right-Pointing-Pointer NiSi{sub x} have remarkably lower electric resistivity and like-noble metal property. -- Abstract: Nanostructured nickel silicides have been prepared by reduction and silicification of high-surface-area nickel oxide (145 m{sup 2} g{sup -1}) produced via precipitation. The prepared materials were characterized by nitrogen adsorption, X-ray diffraction, thermal analysis, FT-IR spectroscopy, scanning electron microscopy, transmission electron microscopy, magnetic and electrochemical measurements. The nickel silicide formation involves the following sequence: NiO (cubic) {yields} Ni (cubic) {yields} Ni{sub 2}Si (orthorhombic) {yields} NiSi (orthorhombic) {yields} NiSi{sub 2} (cubic), with particles growing from 13.7 to 21.3 nm. The nickel silicides are ferromagnetic at room temperature, and their saturation magnetization values change drastically with the increase of Si content. Nickel silicides have remarkably low electrical resistivity and noble metal-like properties because of a constriction of the Ni d band and an increase of the electronic density of states. The results suggest that such silicides are promising candidates as inexpensive yet functional materials for applications in electrochemistry as well as catalysis.

  20. Optical properties and defect levels in a surface layer found on CuInSe{sub 2} thin films

    SciTech Connect (OSTI)

    Abulfotuh, F.; Wangensteen, T.; Ahrenkiel, R.; Kazmerski, L.L.

    1996-05-01

    In this paper the authors have used photoluminescence (PL) and wavelength scanning ellipsometry (WSE) to clarify the relationship among the electro-optical properties of copper indium diselenide (CIS) thin films, the type and origin of dominant defect states, and device performance. The PL study has revealed several shallow acceptor and donor levels dominating the semiconductor. PL emission from points at different depths from the surface of the CIS sample has been obtained by changing the angle of incidence of the excitation laser beam. The resulting data were used to determine the dominant defect states as a function of composition gradient at the surface of the chalcopyrite compound. The significance of this type of measurement is that it allowed the detection of a very thin layer with a larger bandgap (1.15-1.26 eV) than the CIS present on the surface of the CIS thin films. The presence of this layer has been correlated by several groups to improvement of the CIS cell performance. An important need that results from detecting this layer on the surface of the CIS semiconductor is the determination of its thickness and optical constants (n, k) as a function of wavelength. The thickness of this surface layer is about 500 {Angstrom}.

  1. Effects of unreconstructed and reconstructed polar surface terminations on growth, structure, and magnetic properties of hematite films

    SciTech Connect (OSTI)

    Cheung, Sau Ha; Celik-Aktas, A.; Dey, P.; Pande, K.; Weinert, M.; Kabius, B.; Keavney, D.; Lazarov, Vlado; Chambers, Scott A.; Gajdardziska-Josifovska, Marija

    2012-01-05

    The effects of polar surface stabilization mechanisms on the film growth, phase composition, surface and interface structure, and magnetic properties are explored for polar oxide interfaces formed by the epitaxial growth of hematite films on magnesia and alumina single crystals. Growth of {alpha}-Fe{sub 2}O{sub 3}(0001) on the ({radical}3 x {radical}3)R30{sup o} and (2 x 2) reconstructed MgO(111) surfaces results in formation of a self-organized Fe{sub 3}O{sub 4}(111) interfacial nano buffer that persists after growth. The interfacial magnetite-like phase is absent from the hematite films formed on hydrogen-stabilized unreconstructed MgO(111)-(1 x 1) and on Al{sub 2}O{sub 3}(0001)-(1 x 1) surfaces under equivalent conditions. This study suggests that in addition to the customary strain, spin, and band-gap engineering, control of surface polarity stabilization could also be important for electronic and magnetic device engineering.

  2. Oxidation of activated carbon fibers: Effect on pore size, surface chemistry, and adsorption properties

    SciTech Connect (OSTI)

    Mangun, C.L.; Benak, K.R.; Daley, M.A.; Economy, J.

    1999-12-01

    Activated carbon fibers (ACFs) were oxidized using both aqueous and nonaqueous treatments. As much as 29 wt% oxygen can be incorporated onto the pore surface in the form of phenolic hydroxyl, quinine, and carboxylic acid groups. The effect of oxidation on the pore size, pore volume, and the pore surface chemistry was thoroughly examined. The average micropore size is typically affected very little by aqueous oxidation while the micropore volume and surface area decreases with such a treatment. In contrast, the micropore size and micropore volume both increase with oxidation in air. Oxidation of the fibers produces surface chemistries in the pore that provide for enhanced adsorption of basic (ammonia) and polar (acetone) molecules at ambient and nonambient temperatures. The adsorption capacity of the oxidized fibers for acetone is modestly better than the untreated ACFs while the adsorption capacity for ammonia can increase up to 30 times compared to untreated ACFs. The pore surface chemical makeup was analyzed using elemental analysis, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), and X-ray photoelectron spectroscopy (XPS).

  3. Fundamentals of Reservoir Surface Energy as Related to Surface Properties, Wettability, Capillary Action, and Oil Recovery from Fractured Reservoirs by Spontaneous Imbibition

    SciTech Connect (OSTI)

    Norman Morrow; Herbert Fischer; Yu Li; Geoffrey Mason; Douglas Ruth; Siddhartha Seth; Zhengxin Tong; Evren Unsal; Siluni Wickramathilaka; Shaochang Wo; Peigui Yin

    2008-06-30

    The objective of this project is to increase oil recovery from fractured reservoirs through improved fundamental understanding of the process of spontaneous imbibition by which oil is displaced from the rock matrix into the fractures. Spontaneous imbibition is fundamentally dependent on the reservoir surface free energy but this has never been investigated for rocks. In this project, the surface free energy of rocks will be determined by using liquids that can be solidified within the rock pore space at selected saturations. Thin sections of the rock then provide a two-dimensional view of the rock minerals and the occupant phases. Saturations and oil/rock, water/rock, and oil/water surface areas will be determined by advanced petrographic analysis and the surface free energy which drives spontaneous imbibition will be determined as a function of increase in wetting phase saturation. The inherent loss in surface free energy resulting from capillary instabilities at the microscopic (pore level) scale will be distinguished from the decrease in surface free energy that drives spontaneous imbibition. A mathematical network/numerical model will be developed and tested against experimental results of recovery versus time over broad variation of key factors such as rock properties, fluid phase viscosities, sample size, shape and boundary conditions. Two fundamentally important, but not previously considered, parameters of spontaneous imbibition, the capillary pressure acting to oppose production of oil at the outflow face and the pressure in the non-wetting phase at the no-flow boundary versus time, will also be measured and modeled. Simulation and network models will also be tested against special case solutions provided by analytic models. In the second stage of the project, application of the fundamental concepts developed in the first stage of the project will be demonstrated. The fundamental ideas, measurements, and analytic/numerical modeling will be applied to mixed

  4. Ion-assisted physical vapor deposition for enhanced film properties on nonflat surfaces

    SciTech Connect (OSTI)

    Alami, J.; Persson, P.O.A.; Music, D.; Gudmundsson, J. T.; Bohlmark, J.; Helmersson, U.

    2005-03-01

    We have synthesized Ta thin films on Si substrates placed along a wall of a 2-cm-deep and 1-cm-wide trench, using both a mostly neutral Ta flux by conventional dc magnetron sputtering (dcMS) and a mostly ionized Ta flux by high-power pulsed magnetron sputtering (HPPMS). Structure of the grown films was evaluated by scanning electron microscopy, transmission electron microscopy, and atomic force microscopy. The Ta thin film grown by HPPMS has a smooth surface and a dense crystalline structure with grains oriented perpendicular to the substrate surface, whereas the film grown by dcMS exhibits a rough surface, pores between the grains, and an inclined columnar structure. The improved homogeneity achieved by HPPMS is a direct consequence of the high ion fraction of sputtered species.

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Observational Analysis of Land-Atmosphere Coupling for Climate Model Evaluation Download a printable PDF Submitter: Phillips, T. J., Lawrence Livermore National Laboratory Klein, S., Lawrence Livermore National Laboratory Area of Research: Surface Properties Working Group(s): Cloud Life Cycle Journal Reference: Phillips TJ and SA Klein. 2014. "Land-atmosphere coupling manifested in warm-season observations on the U.S. southern great plains." Journal of Geophysical Research -

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Revealing Look Inside Northern Australian Wet Season Precipitation Download a printable PDF Submitter: Giangrande, S., Brookhaven National Laboratory Area of Research: Surface Properties Working Group(s): Cloud Life Cycle Journal Reference: Giangrande SE, M Bartholomew, M Pope, S Collis, and MP Jensen. 2014. "A Summary of Precipitation Characteristics from the 2006-2011 Northern Australian Wet Seasons as Revealed by ARM Disdrometer Research Facilities (Darwin, Australia)." Journal of

  7. First-principles study of quantum confinement and surface effects on the electronic properties of InAs nanowires

    SciTech Connect (OSTI)

    Ning, Feng; Tang, Li-Ming Zhang, Yong; Chen, Ke-Qiu

    2013-12-14

    We have used first principles methods to systematically investigate the quantum confinement effect on the electronic properties of zinc-blende (ZB) and wurtzite (WZ) InAs nanowires (NWs) with different orientations and diameters, and compared their electronic properties before and after pseudo-hydrogen passivation. The results show that the calculated carrier effective masses are dependent on the NW diameter, except for [110] ZB NWs, and the hole effective masses of [111] ZB NWs are larger than the electron effective masses when the NW diameter is ?26?. The band alignments of [111] ZB and [0001] WZ NWs reveal that the effect of quantum confinement on the conduction bands is greater than on the valence bands, and the position of the valence band maximum level changes little with increasing NW diameter. The pseudo-hydrogen passivated NWs have larger band gaps than the corresponding unpassivated NWs. The carrier effective masses and mobilities can be adjusted by passivating the surface dangling bonds.

  8. The Role of Surface Chemistry and Bulk Properties on the Cycling and Rate

    Broader source: Energy.gov (indexed) [DOE]

    The Return of Residential PACE - the Sequel (201), call slides and discussion summary. Call Slides and Discussion Summary (2.38 MB) More Documents & Publications Residential PACE Webinar: Dig Deeper into the Recent DOE and HUD Residential PACE Best Practice Guidelines for Residential PACE Financing Programs Property-Assessed Clean Energy (PACE) Financing Resources

    Right Idea ... at the Right Time 2004 DOE Tribal Energy Program Review Meeting 2004 DOE Tribal Energy Program Review Meeting *

  9. Magnetic properties and Fermi surface of antiferromagnetic SmCu/sub 6/

    SciTech Connect (OSTI)

    Onuki, Y.; Umezawa, A.; Kwok, W.K.; Crabtree, G.W.; Nishihara, M.; Ina, K.; Yamazaki, T.; Omi, T.; Komatsubara, T.; Maezawa, K.

    1987-08-01

    We report measurements of the magnetic susceptibility, specific heat, magnetoresistance, Hall effect, and Fermi surface in SmCu/sup 6/. The susceptibility follows the Van Vleck form for Sm/sup 3 +/ near room temperature and shows two antiferromagnetic phase transitions at 9.6 K and 5.2 K. The specific heat implies a quartet ground state for the crystal field split J = 5/2 angular momentum state. Magnetoresistance indicates two conduction carriers of uncompensated electrons and holes. de Haas-van Alphen measurements show that the Fermi surface in the antiferromagnetic state consists of a network of cylinders oriented 30/degree/ from the b and c axes. 14 refs., 10 figs.

  10. Magnetic properties and Fermi surface of antiferromagnetic SmCu sub 6

    SciTech Connect (OSTI)

    Onuki, Y.; Umezawa, A.; Kwok, W.K.; Crabtree, G.W. ); Nishihara, M.; Ina, K.; Yamazaki, T.; Omi, T.; Komatsubara, T. ); Maezawa, K.; Wakabayashi, S. ); Takayanagi, S. ); Wada, N. )

    1990-01-01

    We report measurements of the magnetic susceptibility, specific heat, magnetoresistance, Hall effect, and Fermi surface in SmCu{sub 6}. The susceptibility follows the Van Vleck form for Sm{sup 3+} near room temperature and shows two antiferromagnetic phase transitions at 9.6 and 5.2 K. The specific heat implies a quartet ground state for the crystal-field-split {ital J}=5/2 angular momentum state. Magnetoresistance indicates that SmCu{sub 6} contains both electron and hole carriers but is uncompensated. de Haas--van Alphen measurements show that the Fermi surface in the antiferromagnetic state consists of a network of cylinders oriented 30{degree} from the {ital b} and {ital c} axes.

  11. Charging Properties of Cassiterite (alpha-SnO2) surfaces in NaCl and RbCl Ionic Media.

    SciTech Connect (OSTI)

    Rosenqvist, Jorgen K; Machesky, Michael L.; Vlcek, Lukas; Wesolowski, David J

    2009-09-01

    The acid-base properties of cassiterite (alpha-SnO2) surfaces at 10-50 degrees C were studied using potentiometric titrations of powder suspensions in aqueous NaCl and RbCl media. The proton sorption isotherms exhibited common intersection points in the pH range of 4.0-4.5 under all conditions, and the magnitude of charging was similar but not identical in NaCl and RbCl. The hydrogen bonding configuration at the oxide-water interface, obtained from classical molecular dynamics (MD) simulations, was analyzed in detail, and the results were explicitly incorporated in calculations of protonation constants for the reactive surface sites using the revised MUSIC model. The calculations indicated that the terminal SnOH2 group is more acidic than the bridging Sn2OH group, with protonation constants (log KH) of 3.60 and 5.13 at 25 degrees C, respectively. This is contrary to the situation on the isostructural alpha-TiO2 (rutile), apparently because of the difference in electronegativity between Ti and Sn. MD simulations and speciation calculations indicated considerable differences in the speciation of Na+ and Rb+, despite the similarities in overall charging. Adsorbed sodium ions are almost exclusively found in bidentate surface complexes, whereas adsorbed rubidium ions form comparable numbers of bidentate and tetradentate complexes. Also, the distribution of adsorbed Na+ between the different complexes shows a considerable dependence on the surface charge density (pH), whereas the distribution of adsorbed Rb+ is almost independent of pH. A surface complexation model (SCM) capable of accurately describing both the measured surface charge and the MD-predicted speciation of adsorbed Na+/Rb+ was formulated. According to the SCM, the deprotonated terminal group (SnOH(-0.40)) and the protonated bridging group (Sn2OH+0.36) dominate the surface speciation over the entire pH range of this study (2.7-10). The complexation of medium cations increases significantly with increasing

  12. Charging Properties of Cassiterite (alpha-SnO2) Surfaces in NaCl and RbCl Ionic Media.

    SciTech Connect (OSTI)

    Rosenqvist, Jorgen K; Machesky, Michael L.; Vlcek, Lukas; Wesolowski, David J

    2009-09-01

    The acid-base properties of cassiterite ({alpha}-SnO{sub 2}) surfaces at 10-50 C were studied using potentiometric titrations of powder suspensions in aqueous NaCl and RbCl media. The proton sorption isotherms exhibited common intersection points in the pH range of 4.0-4.5 under all conditions, and the magnitude of charging was similar but not identical in NaCl and RbCl. The hydrogen bonding configuration at the oxide-water interface, obtained from classical molecular dynamics (MD) simulations, was analyzed in detail, and the results were explicitly incorporated in calculations of protonation constants for the reactive surface sites using the revised MUSIC model. The calculations indicated that the terminal SnOH{sub 2} group is more acidic than the bridging Sn{sub 2}OH group, with protonation constants (log K{sub H}) of 3.60 and 5.13 at 25 C, respectively. This is contrary to the situation on the isostructural {alpha}-TiO{sub 2} (rutile), apparently because of the difference in electronegativity between Ti and Sn. MD simulations and speciation calculations indicated considerable differences in the speciation of Na{sup +} and Rb{sup +}, despite the similarities in overall charging. Adsorbed sodium ions are almost exclusively found in bidentate surface complexes, whereas adsorbed rubidium ions form comparable numbers of bidentate and tetradentate complexes. Also, the distribution of adsorbed Na{sup +} between the different complexes shows a considerable dependence on the surface charge density (pH), whereas the distribution of adsorbed Rb{sup +} is almost independent of pH. A surface complexation model (SCM) capable of accurately describing both the measured surface charge and the MD-predicted speciation of adsorbed Na{sup +}/Rb{sup +} was formulated. According to the SCM, the deprotonated terminal group (SnOH{sup -0.40}) and the protonated bridging group (Sn{sub 2}OH{sup +0.36}) dominate the surface speciation over the entire pH range of this study (2.7-10). The

  13. ARM Climate Research Facility Spectral Surface Albedo Value-Added Product (VAP) Report

    SciTech Connect (OSTI)

    McFarlane, S; Gaustad, K; Long, C; Mlawer, E

    2011-07-15

    This document describes the input requirements, output data products, and methodology for the Spectral Surface Albedo (SURFSPECALB) value-added product (VAP). The SURFSPECALB VAP produces a best-estimate near-continuous high spectral resolution albedo data product using measurements from multifilter radiometers (MFRs). The VAP first identifies best estimates for the MFR downwelling and upwelling shortwave irradiance values, and then calculates narrowband spectral albedo from these best-estimate irradiance values. The methodology for finding the best-estimate values is based on a simple process of screening suspect data and backfilling screened and missing data with estimated values when possible. The resulting best-estimate MFR narrowband spectral albedos are used to determine a daily surface type (snow, 100% vegetation, partial vegetation, or 0% vegetation). For non-snow surfaces, a piecewise continuous function is used to estimate a high spectral resolution albedo at 1 min temporal and 10 cm-1 spectral resolution.

  14. Structure and electronic properties of Cu nanoclusters supported on Mo2C(001) and MoC(001) surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Posada-Pérez, Sergio; Viñes, Francesc; Rodríguez, José A.; Illas, Francesc

    2015-09-15

    In this study, the atomic structure and electronic properties of Cun nanoclusters (n = 4, 6, 7, and 10) supported on cubic nonpolar δ-MoC(001) and orthorhombic C- or Mo-terminated polar β-Mo2C(001) surfaces have been investigated by means of periodic density functional theory based calculations. The electronic properties have been analyzed by means of the density of states, Bader charges, and electron localization function plots. The Cu nanoparticles supported on β-Mo2C(001), either Mo- or C-terminated, tend to present a two-dimensional structure whereas a three-dimensional geometry is preferred when supported on δ-MoC(001), indicating that the Mo:C ratio and the surface polarity playmore » a key role determining the structure of supported clusters. Nevertheless, calculations also reveal important differences between the C- and Mo-terminated β-Mo2C(001) supports to the point that supported Cu particles exhibit different charge states, which opens a way to control the reactivity of these potential catalysts.« less

  15. Surface Transportation Research and Development Act of 1997. House of Representatives, One Hundred Fifth Congress, Second Session

    SciTech Connect (OSTI)

    1998-12-31

    Mr. Sensenbrenner, from the Committee on Science, submitted this report together with additional views. The Committee on Science, to whom was referred the bill (H.R. 860) to authorize appropriations to the Department of Transportation for surface transportation research and development, and for other purposes, having considered the same, report favorably thereon with an amendment and recommend that the bill as amended do pass.

  16. Macrostructure-dependent photocatalytic property of high-surface-area porous titania films

    SciTech Connect (OSTI)

    Kimura, T.

    2014-11-01

    Porous titania films with different macrostructures were prepared with precise control of condensation degree and density of the oxide frameworks in the presence of spherical aggregates of polystyrene-block-poly(oxyethylene) (PS-b-PEO) diblock copolymer. Following detailed explanation of the formation mechanisms of three (reticular, spherical, and large spherical) macrostructures by the colloidal PS-b-PEO templating, structural variation of the titania frameworks during calcination were investigated by X-ray diffraction and X-ray photoelectron spectroscopy. Then, photocatalytic performance of the macroporous titania films was evaluated through simple degradation experiments of methylene blue under an UV irradiation. Consequently, absolute surface area of the film and crystallinity of the titania frameworks were important for understanding the photocatalytic performance, but the catalytic performance can be improved further by the macrostructural design that controls diffusivity of the targeted molecules inside the film and their accessibility to active sites.

  17. Multicycle rapid thermal annealing optimization of Mg-implanted GaN: Evolution of surface, optical, and structural properties

    SciTech Connect (OSTI)

    Greenlee, Jordan D.; Feigelson, Boris N.; Anderson, Travis J.; Hite, Jennifer K.; Mastro, Michael A.; Eddy, Charles R.; Hobart, Karl D.; Kub, Francis J.; Tadjer, Marko J.

    2014-08-14

    The first step of a multi-cycle rapid thermal annealing process was systematically studied. The surface, structure, and optical properties of Mg implanted GaN thin films annealed at temperatures ranging from 900 to 1200?C were investigated by Raman spectroscopy, photoluminescence, UV-visible spectroscopy, atomic force microscopy, and Nomarski microscopy. The GaN thin films are capped with two layers of in-situ metal organic chemical vapor deposition -grown AlN and annealed in 24 bar of N{sub 2} overpressure to avoid GaN decomposition. The crystal quality of the GaN improves with increasing annealing temperature as confirmed by UV-visible spectroscopy and the full widths at half maximums of the E{sub 2} and A{sub 1} (LO) Raman modes. The crystal quality of films annealed above 1100?C exceeds the quality of the as-grown films. At 1200?C, Mg is optically activated, which is determined by photoluminescence measurements. However, at 1200?C, the GaN begins to decompose as evidenced by pit formation on the surface of the samples. Therefore, it was determined that the optimal temperature for the first step in a multi-cycle rapid thermal anneal process should be conducted at 1150?C due to crystal quality and surface morphology considerations.

  18. Improvement of bonding properties of laser transmission welded, dissimilar thermoplastics by plasma surface treatment

    SciTech Connect (OSTI)

    Hopmann, Ch.; Weber, M.; Schöngart, M.; Sooriyapiragasam, S.; Behm, H.; Dahlmann, R.

    2015-05-22

    Compared to different welding methods such as ultrasonic welding, laser transmission welding is a relatively new technology to join thermoplastic parts. The most significant advantages over other methods are the contactless energy input which can be controlled very precisely and the low mechanical loads on the welded parts. Therefore, laser transmission welding is used in various areas of application, for example in medical technology or for assembling headlights in the automotive sector. However, there are several challenges in welding dissimilar thermoplastics. This may be due to different melting points on the one hand and different polarities on the other hand. So far these problems are faced with the intermediate layer technique. In this process a layer bonding together the two components is placed between the components. This means that an additional step in the production is needed to apply the extra layer. To avoid this additional step, different ways of joining dissimilar thermoplastics are investigated. In this regard, the improvement in the weldability of the dissimilar thermoplastics polyamide 6 (PA 6) and polypropylene (PP) by means of plasma surface modification and contour welding is examined. To evaluate the influence of the plasma surface modification process on the subsequent welding process of the two dissimilar materials, the treatment time as well as the storage time between treatment and welding are varied. The treatment time in pulsed micro wave excited oxygen plasmas with an electron density of about 1x10{sup 17} m{sup −3} is varied from 0.5 s to 120 s and the time between treatment and welding is varied from a few minutes up to a week. As reference, parts being made of the same polymer (PP and PA 6) are welded and tested. For the evaluation of the results of the welding experiments, short-time tensile tests are used to determine the bond strength. Without plasma treatment the described combination of PA 6/PP cannot be welded with

  19. Effect of doping on growth and field emission properties of spherical carbon nanotube tip placed over cylindrical surface

    SciTech Connect (OSTI)

    Santolia, Isha; Tewari, Aarti; Sharma, Suresh C.; Sharma, Rinku

    2014-06-15

    Theoretical investigations to study the effect of doping of hetero-atoms on the growth and field emission properties of Carbon Nanotubes (CNTs) tip placed over a cylindrical surface in complex plasma have been carried out. A theoretical model incorporating kinetics of plasma species such as electron, ions, and neutral atoms including doping elements like nitrogen (N) and boron (B) and energy balance of CNTs in a complex plasma has been developed. The effect of doping elements of N and B on the growth of CNTs, namely, the tip radius has been carried out for typical glow discharge plasma parameters. It is found that N and B as doping elements affect the radius of CNTs extensively. We obtain small radii of CNT doped with N and large radius of CNT doped with B. The field emission characteristics from CNTs have therefore been suggested on the basis of results obtained. Some of theoretical results are in compliance with the existing experimental observations.

  20. Single Dirac Cone Topological Surface State and Unusual Thermoelectric Property of Compounds from a New Topological Insulator Family

    SciTech Connect (OSTI)

    Chen, Y

    2011-08-18

    Angle resolved photoemission spectroscopy (ARPES) study on TlBiTe2 and TlBiSe2 from a Thallium-based III-V-VI2 ternary chalcogenides family revealed a single surface Dirac cone at the center of the Brillouin zone for both compounds. For TlBiSe{sub 2}, the large bulk gap ({approx} 200meV) makes it a topological insulator with better mechanical properties than the previous binary 3D topological insualtor family. For TlBiTe{sub 2}, the observed negative bulk gap indicates it as a semi-metal, rather than a narrow gap semi-conductor as conventionally believed; this semi-metality naturally explains its mysteriously small thermoelectric figure of merit comparing to other compounds in the family. Finally, the unique band structures of TlBiTe{sub 2} also suggests it as a candidate for topological superconductors.

  1. Graphene oxide/carbon nanoparticle thin film based IR detector: Surface properties and device characterization

    SciTech Connect (OSTI)

    Chowdhury, Farzana Aktar; Hossain, Mohammad Abul; Uchida, Koji; Tamura, Takahiro; Sugawa, Kosuke; Mochida, Tomoaki; Otsuki, Joe; Mohiuddin, Tariq; Boby, Monny Akter; Alam, Mohammad Sahabul

    2015-10-15

    This work deals with the synthesis, characterization, and application of carbon nanoparticles (CNP) adorned graphene oxide (GO) nanocomposite materials. Here we mainly focus on an emerging topic in modern research field presenting GO-CNP nanocomposite as a infrared (IR) radiation detector device. GO-CNP thin film devices were fabricated from liquid phase at ambient condition where no modifying treatments were necessary. It works with no cooling treatment and also for stationary objects. A sharp response of human body IR radiation was detected with time constants of 3 and 36 sec and radiation responsivity was 3 mAW{sup −1}. The current also rises for quite a long time before saturation. This work discusses state-of-the-art material developing technique based on near-infrared photon absorption and their use in field deployable instrument for real-world applications. GO-CNP-based thin solid composite films also offer its potentiality to be utilized as p-type absorber material in thin film solar cell, as well.

  2. 2014 CHEMICAL REACTIONS AT SURFACES GORDON RESEARCH CONFERENCE AND GORDON RESEARCH SEMINAR (APRIL 28-MAY 3, 2013 - LES DIABLERETS CONFERENCE CENTER, LES DIABLERETS, SWITZERLAND)

    SciTech Connect (OSTI)

    Stair, Peter C.

    2013-02-03

    presentations on chemistry at solid and liquid surfaces of relevance to catalysis, synthesis, photochemistry, environmental science, and tribology. Topics include: Fundamental Surface Chemistry; Catalysis; Solid Liquid and Aerosol Interfaces; Surface Photochemistry; Synthesis of Surfaces; Environmental Interfaces; Hot Topics in Surface Chemical Reactions; Tribology; Gas-Surface Scattering and Reactions; Novel Materials and Environments.

  3. Determination of elastic properties of a MnO{sub 2} coating by surface acoustic wave velocity dispersion analysis

    SciTech Connect (OSTI)

    Sermeus, J.; Glorieux, C.; Sinha, R.; Vereecken, P. M.; Vanstreels, K.

    2014-07-14

    MnO{sub 2} is a material of interest in the development of high energy-density batteries, specifically as a coating material for internal 3D structures, thus ensuring rapid energy deployment. Its electrochemical properties have been mapped extensively, but there are, to the best of the authors' knowledge, no records of the elastic properties of thin film MnO{sub 2}. Impulsive stimulated thermal scattering (ISTS), also known as the heterodyne diffraction or transient grating technique, was used to determine the Young's modulus (E) and porosity (?) of a 500?nm thick MnO{sub 2} coating on a Si(001) substrate. ISTS is an all optical method that is able to excite and detect surface acoustic waves (SAWs) on opaque samples. From the measured SAW velocity dispersion, the Young's modulus and porosity were determined to be E?=?25??1?GPa and ?=421%, respectively. These values were confirmed by independent techniques and determined by a most-squares analysis of the carefully fitted SAW velocity dispersion. This study demonstrates the ability of the presented technique to determine the elastic parameters of a thin, porous film on an anisotropic substrate.

  4. Pulsed laser-induced oxygen deficiency at TiO{sub 2} surface: Anomalous structure and electrical transport properties

    SciTech Connect (OSTI)

    Nakajima, Tomohiko; Tsuchiya, Tetsuo; Kumagai, Toshiya

    2009-09-15

    We have studied pulsed laser-induced oxygen deficiencies at rutile TiO{sub 2} surfaces. The crystal surface was successfully reduced by excimer laser irradiation, and an oxygen-deficient TiO{sub 2-{delta}} layer with 160 nm thickness was formed by means of ArF laser irradiation at 140 mJ/cm{sup 2} for 2000 pulses. The TiO{sub 2-{delta}} layer fundamentally maintained a rutile structure, though this structure was distorted by many stacking faults caused by the large oxygen deficiency. The electrical resistivity of the obtained TiO{sub 2-{delta}} layer exhibited unconventional metallic behavior with hysteresis. A metal-insulator transition occurred at 42 K, and the electrical resistivity exceeded 10{sup 4} OMEGA cm below 42 K. This metal-insulator transition could be caused by bipolaronic ordering derived from Ti-Ti pairings that formed along the stacking faults. The constant magnetization behavior observed below 42 K is consistent with the bipolaronic scenario that has been observed previously for Ti{sub 4}O{sub 7}. These peculiar electrical properties are strongly linked to the oxygen-deficient crystal structure, which contains many stacking faults formed by instantaneous heating during excimer laser irradiation. - Graphical abstract: A pulsed laser-irradiated TiO{sub 2-{delta}} substrate showed an unconventional metallic phase, with hysteresis over a wide range of temperatures and a metal-insulator transition at 42 K.

  5. Robust surface electronic properties of topological insulators: Bi{sub 2}Te{sub 3} films grown by molecular beam epitaxy

    SciTech Connect (OSTI)

    Plucinski, L.; Herdt, A.; Mussler, G.; Krumrain, J.; Gruetzmacher, D.; Suga, S.; Schneider, C. M.

    2011-05-30

    The surface electronic properties of the important topological insulator Bi{sub 2}Te{sub 3} are shown to be robust under an extended surface preparation procedure, which includes exposure to atmosphere and subsequent cleaning and recrystallization by an optimized in situ sputter-anneal procedure under ultrahigh vacuum conditions. Clear Dirac-cone features are displayed in high-resolution angle-resolved photoemission spectra from the resulting samples, indicating remarkable insensitivity of the topological surface state to cleaning-induced surface roughness.

  6. The relationship between hydroxyl groups on oxide surfaces and the properties of supported metals. Progress report, June 1, 1992--January 31, 1994

    SciTech Connect (OSTI)

    Schwarz, J.A.

    1994-05-01

    Supported metal catalysts are commonly prepared by depositing catalytic precursors from aqueous solutions of electrolytes onto high surface area oxides. A general conclusion of our previous studies was that the performance of the finished catalyst depends on the characteristic properties of the hydroxyl inventory on the surface of the oxide support, both in wet and in (pseudo)-dry conditions. Hydroxyl groups serve as adsorption or exchange sites during catalyst preparation. On the other hand, the configuration of hydroxyl groups still remaining on oxides after dehydration determines the acid-base characteristics of the catalyst, which is an important catalytic property. The purpose of the investigation is to characterize the relationship between the complex inventory of hydroxyl groups at oxide surfaces, the acid-base properties of oxides (both in aqueous solution and in the pseudo-dry state) and the resultant effects on the properties of catalytic materials formed by adsorption/impregnation onto these hydroxylated supports during catalyst preparation. We use a common crystallographic model to describe the local configuration of hydroxyl groups on both the pseudo-dry surface and -the oxide/aqueous solution interface. This allows us to extend the concept of structurally determined intrinsic heterogeneity of pseudo-dry surfaces (as already known from the IR spectra of isolated surface hydroxyls) to the oxide/solution interface. We examine the consequences of that heterogeneity upon the impregnation step during catalyst preparation.

  7. Property

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ER-B-98-07 AUDIT REPORT PERSONAL PROPERTY AT THE OAK RIDGE OPERATIONS OFFICE AND THE OFFICE OF SCIENTIFIC AND TECHNICAL INFORMATION U.S. DEPARTMENT OF ENERGY OFFICE OF INSPECTOR GENERAL OFFICE OF AUDIT SERVICES APRIL 1998 Page 10 DEPARTMENT OF ENERGY Washington, DC 20585 April 6, 1998 MEMORANDUM FOR THE MANAGER, OAK RIDGE OPERATIONS OFFICE AND THE DIRECTOR, OFFICE OF SCIENTIFIC AND TECHNICAL INFORMATION FROM: Terry L. Brendlinger Eastern Regional Audit Office Office of Inspector General SUBJECT:

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Development of a New Method for Estimating Evapotranspiration Using ARM Measurements Submitter: Li, Z., University of Maryland Area of Research: Surface Properties Working Group(s): Radiative Processes Journal Reference: Wang, K., P. Wang, Z. Li, M. Cribb, and M. Sparrow (2007). A simple method to estimate actual evapotranspiration from a combination of net radiation, vegetation index, and temperature, J. Geophys. Res., 112, D15107, doi:10.1029/2006JD008351. Wang, K., Z. Li, and M. Cribb (2006).

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SGP Observations Help Validate Soil Temperature Simulations Download a printable PDF Submitter: Huang, M., Pacific Northwest National Laboratory Area of Research: Surface Properties Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Xia Y, M Ek, J Sheffield, B Livneh, M Huang, H Wei, S Feng, L Luo, J Meng, and E Wood. 2012. "Validation of Noah-simulated soil temperature in the North American Land Data Assimilation System Phase 2." Journal of Applied

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ground Stations Likely Get a Boost from Satellites to Estimate Carbon Dioxide Emissions Download a printable PDF Submitter: Roeder, L. R., Pacific Northwest National Laboratory Area of Research: Surface Properties Working Group(s): Aerosol Life Cycle Journal Reference: Basu S, S Guerlet, A Butz, S Houweling, OP Hasekamp, I Aben, PB Krummel, LP Steele, RL Langenfelds, MS Torn, SC Biraud, B Stephens, A Andrews, and D Worthy. 2013. "Global CO2 fluxes estimated from GOSAT retrievals of total

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Growing More Effective Ways to Measure Climate Change Download a printable PDF Submitter: Maseyk, K. S., Universite Pierre et Marie Curie, Paris 6 Area of Research: Surface Properties Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Maseyk K, JA Berry, D Billesbach, JE Campbell, MS Torn, M Zahniser, and U Seibt. 2014. "Sources and sinks of carbonyl sulfide in an agricultural field in the Southern Great Plains." Proceedings of the National Academy of

  12. Forecasting the response of Earth's surface to future climatic and land use changes: A review of methods and research needs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pelletier, Jon D.; Murray, A. Brad; Pierce, Jennifer L.; Bierman, Paul R.; Breshears, David D.; Crosby, Benjamin T.; Ellis, Michael; Foufoula-Georgiou, Efi; Heimsath, Arjun M.; Houser, Chris; et al

    2015-07-14

    In the future, Earth will be warmer, precipitation events will be more extreme, global mean sea level will rise, and many arid and semiarid regions will be drier. Human modifications of landscapes will also occur at an accelerated rate as developed areas increase in size and population density. We now have gridded global forecasts, being continually improved, of the climatic and land use changes (C&LUC) that are likely to occur in the coming decades. However, besides a few exceptions, consensus forecasts do not exist for how these C&LUC will likely impact Earth-surface processes and hazards. In some cases, we havemore » the tools to forecast the geomorphic responses to likely future C&LUC. Fully exploiting these models and utilizing these tools will require close collaboration among Earth-surface scientists and Earth-system modelers. This paper assesses the state-of-the-art tools and data that are being used or could be used to forecast changes in the state of Earth's surface as a result of likely future C&LUC. We also propose strategies for filling key knowledge gaps, emphasizing where additional basic research and/or collaboration across disciplines are necessary. The main body of the paper addresses cross-cutting issues, including the importance of nonlinear/threshold-dominated interactions among topography, vegetation, and sediment transport, as well as the importance of alternate stable states and extreme, rare events for understanding and forecasting Earth-surface response to C&LUC. Five supplements delve into different scales or process zones (global-scale assessments and fluvial, aeolian, glacial/periglacial, and coastal process zones) in detail.« less

  13. Forecasting the response of Earth's surface to future climatic and land use changes: A review of methods and research needs

    SciTech Connect (OSTI)

    Pelletier, Jon D.; Murray, A. Brad; Pierce, Jennifer L.; Bierman, Paul R.; Breshears, David D.; Crosby, Benjamin T.; Ellis, Michael; Foufoula-Georgiou, Efi; Heimsath, Arjun M.; Houser, Chris; Lancaster, Nick; Marani, Marco; Merritts, Dorothy J.; Moore, Laura J.; Pederson, Joel L.; Poulos, Michael J.; Rittenour, Tammy M.; Rowland, Joel C.; Ruggiero, Peter; Ward, Dylan J.; Wickert, Andrew D.; Yager, Elowyn M.

    2015-07-14

    In the future, Earth will be warmer, precipitation events will be more extreme, global mean sea level will rise, and many arid and semiarid regions will be drier. Human modifications of landscapes will also occur at an accelerated rate as developed areas increase in size and population density. We now have gridded global forecasts, being continually improved, of the climatic and land use changes (C&LUC) that are likely to occur in the coming decades. However, besides a few exceptions, consensus forecasts do not exist for how these C&LUC will likely impact Earth-surface processes and hazards. In some cases, we have the tools to forecast the geomorphic responses to likely future C&LUC. Fully exploiting these models and utilizing these tools will require close collaboration among Earth-surface scientists and Earth-system modelers. This paper assesses the state-of-the-art tools and data that are being used or could be used to forecast changes in the state of Earth's surface as a result of likely future C&LUC. We also propose strategies for filling key knowledge gaps, emphasizing where additional basic research and/or collaboration across disciplines are necessary. The main body of the paper addresses cross-cutting issues, including the importance of nonlinear/threshold-dominated interactions among topography, vegetation, and sediment transport, as well as the importance of alternate stable states and extreme, rare events for understanding and forecasting Earth-surface response to C&LUC. Five supplements delve into different scales or process zones (global-scale assessments and fluvial, aeolian, glacial/periglacial, and coastal process zones) in detail.

  14. Determination of bulk and surface superconducting properties of N2-doped cold worked, heat treated and electro-polished SRF grade niobium

    SciTech Connect (OSTI)

    Chetri, Santosh; Larbalestier, David C.; Lee, Peter J.; Dhakal, Pashupati; Sung, Zu -Hawn

    2015-12-01

    In this study, nitrogen-doped cavities show significant performance improvement in the medium accelerating field regime due to a lowered RF surface resistivity. However, the mechanism of enhancement has not been clearly explained. Our experiments explore how N2-doping influences Nb bulk and surface superconducting properties, and compare the N2-doped properties with those obtained previously with conventionally treated samples. High purity Nb-rod was mechanically deformed and post treated based on a typical SRF cavity treatment recipe. The onset of flux penetration at Hc1, and the upper and the surface critical fields, Hc2 and Hc3, were characterized by magnetic hysteresis and AC susceptibility techniques. The surface depth profile responsible for superconductivity was examined by changing AC amplitude in AC susceptibility, and the microstructure was directly observed with EBSD-OIM. We are also investigating surface chemistry for detailed composition using XPS. We have found that N2-doping at 800 °C significantly reduces the Hc3/Hc2 ratio towards the ideal value of ~1.7, and conclude that AC susceptibility is capable of following changes to the surface properties induced by N2-doping.

  15. Determination of bulk and surface superconducting properties of N2-doped cold worked, heat treated and electro-polished SRF grade niobium

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chetri, Santosh; Larbalestier, David C.; Lee, Peter J.; Dhakal, Pashupati; Sung, Zu -Hawn

    2015-12-01

    In this study, nitrogen-doped cavities show significant performance improvement in the medium accelerating field regime due to a lowered RF surface resistivity. However, the mechanism of enhancement has not been clearly explained. Our experiments explore how N2-doping influences Nb bulk and surface superconducting properties, and compare the N2-doped properties with those obtained previously with conventionally treated samples. High purity Nb-rod was mechanically deformed and post treated based on a typical SRF cavity treatment recipe. The onset of flux penetration at Hc1, and the upper and the surface critical fields, Hc2 and Hc3, were characterized by magnetic hysteresis and AC susceptibilitymore » techniques. The surface depth profile responsible for superconductivity was examined by changing AC amplitude in AC susceptibility, and the microstructure was directly observed with EBSD-OIM. We are also investigating surface chemistry for detailed composition using XPS. We have found that N2-doping at 800 °C significantly reduces the Hc3/Hc2 ratio towards the ideal value of ~1.7, and conclude that AC susceptibility is capable of following changes to the surface properties induced by N2-doping.« less

  16. Intermolecular potential energy surface and thermophysical properties of the CH{sub 4}N{sub 2} system

    SciTech Connect (OSTI)

    Hellmann, Robert Bich, Eckard; Vogel, Eckhard; Vesovic, Velisa

    2014-12-14

    A five-dimensional potential energy surface (PES) for the interaction of a rigid methane molecule with a rigid nitrogen molecule was determined from quantum-chemical ab initio calculations. The counterpoise-corrected supermolecular approach at the CCSD(T) level of theory was utilized to compute a total of 743 points on the PES. The interaction energies were calculated using basis sets of up to quadruple-zeta quality with bond functions and were extrapolated to the complete basis set limit. An analytical site-site potential function with nine sites for methane and five sites for nitrogen was fitted to the interaction energies. The PES was validated by calculating the cross second virial coefficient as well as the shear viscosity and binary diffusion coefficient in the dilute-gas limit for CH{sub 4}N{sub 2} mixtures. An improved PES was obtained by adjusting a single parameter of the analytical potential function in such a way that quantitative agreement with the most accurate experimental values of the cross second virial coefficient was achieved. The transport property values obtained with the adjusted PES are in good agreement with the best experimental data.

  17. Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Research Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. Research thorium test foil A thorium test foil target for proof-of-concept actinium-225 production In addition to our routine isotope products, the LANL Isotope Program is focused on developing the next suite of isotopes and services to meet the Nation's emerging needs. The LANL Isotope Program's R&D strategy is focused on four main areas (see

  18. Superhydrophobic surfaces

    DOE Patents [OSTI]

    Wang, Evelyn N; McCarthy, Matthew; Enright, Ryan; Culver, James N; Gerasopoulos, Konstantinos; Ghodssi, Reza

    2015-03-24

    Surfaces having a hierarchical structure--having features of both microscale and nanoscale dimensions--can exhibit superhydrophobic properties and advantageous condensation and heat transfer properties. The hierarchical surfaces can be fabricated using biological nanostructures, such as viruses as a self-assembled nanoscale template.

  19. Fuels for Advanced Combustion Engines Research Diesel Fuels: Analysis of Physical and Chemical Properties

    SciTech Connect (OSTI)

    Gallant, Tom; Franz, Jim; Alnajjar, Mikhail; Storey, John Morse; Lewis Sr, Samuel Arthur; Sluder, Scott; Cannella, William C; Fairbridge, Craig; Hager, Darcy; Dettman, Heather; Luecke, Jon; Ratcliff, Matthew A.; Zigler, Brad

    2009-01-01

    The CRC Fuels for Advanced Combustion Engines working group has worked to identify a matrix of research diesel fuels for use in advanced combustion research applications. Nine fuels were specified and formulated to investigate the effects of cetane number aromatic content and 90% distillation fraction. Standard ASTM analyses were performed on the fuels as well as GC/MS and /u1H//u1/u3C NMR analyses and thermodynamic characterizations. Details of the actual results of the fuel formulations compared with the design values are presented, as well as results from standard analyses, such as heating value, viscosity and density. Cetane number characterizations were accomplished by using both the engine method and the Ignition Quality Tester (IQT/sT) apparatus.

  20. First-principles investigation of the electronic and Li-ion diffusion properties of LiFePO{sub 4} by sulfur surface modification

    SciTech Connect (OSTI)

    Xu, Guigui E-mail: zghuang@fjnu.edu.cn; Zhong, Kehua; Zhang, Jian-Min; Huang, Zhigao E-mail: zghuang@fjnu.edu.cn

    2014-08-14

    We present a first-principles calculation for the electronic and Li-ion diffusion properties of the LiFePO{sub 4} (010) surface modified by sulfur. The calculated formation energy indicates that the sulfur adsorption on the (010) surface of the LiFePO{sub 4} is energetically favored. Sulfur is found to form Fe-S bond with iron. A much narrower band gap (0.67 eV) of the sulfur surface-modified LiFePO{sub 4} [S-LiFePO{sub 4} (010)] is obtained, indicating the better electronic conductive properties. By the nudged elastic band method, our calculations show that the activation energy of Li ions diffusion along the one-dimensional channel on the surface can be effectively reduced by sulfur surface modification. In addition, the surface diffusion coefficient of S-LiFePO{sub 4} (010) is estimated to be about 10{sup −11} (cm{sup 2}/s) at room temperature, which implies that sulfur modification will give rise to a higher Li ion carrier mobility and enhanced electrochemical performance.

  1. Research

    SciTech Connect (OSTI)

    1999-10-01

    Subjects covered in this section are: (1) PCAST panel promotes energy research cooperation; (2) Letter issued by ANS urges funding balance in FFTF restart consideration and (3) FESAC panel releases report on priorities and balance.

  2. Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The LANL Isotope Program's R&D strategy is focused on four main areas (see article list below for recent efforts in these areas): Medical Applications are a key focus for research ...

  3. Current status, research needs, and opportunities in applications of surface processing to transportation and utilities technologies. Proceedings of a December 1991 workshop

    SciTech Connect (OSTI)

    Czanderna, A.W.; Landgrebe, A.R.

    1992-09-01

    Goal of surface processing is to develop innovative methods of surface modification and characterization for optimum performance and environmental protection for cost-effective operational lifetimes of systems, materials, and components used in transportation and utilities. These proceedings document the principal discussions and conclusions reached at the workshop; they document chapters about the current status of surface characterization with focus on composition, structure, bonding, and atomic-scale topography of surfaces. Also documented are chapters on the current status of surface modification techniques: electrochemical, plasma-aided, reactive and nonreactive physical vapor deposition, sol-gel coatings, high-energy ion implantation, ion-assisted deposition, organized molecular assemblies, solar energy. Brief chapters in the appendices document basic research in surface science by NSF, Air Force, and DOE. Participants at the workshop were invited to serve on 10 working groups. Separate abstracts were prepared for the data base where appropriate.

  4. Research on the electronic and optical properties of polymer and other organic molecular thin films

    SciTech Connect (OSTI)

    1997-02-01

    The main goal of the work is to find materials and methods of optimization of organic layered electroluminescent cells and to study such properties of polymers and other organic materials that can be used in various opto-electronic devices. The summary of results obtained during the first year of work is presented. They are: (1) the possibility to produce electroluminescent cells using a vacuum deposition photoresist technology for commercial photoresists has been demonstrated; (2) the idea to replace the polyaryl polymers by other polymers with weaker hole conductivity for optimization of electroluminescent cells with ITO-Al electrodes has been suggested. The goal is to obtain amorphous processable thin films of radiative recombination layers in electroluminescent devices; (3) procedures of preparation of high-quality vacuum-deposited poly (p-phenylene) (PPP) films on various substrates have been developed; (4) it was found for the first time that the fluorescence intensity of PPP films depends on the degree of polymerization; (5) the role of interfaces between organic compounds, on one side, and metals or semiconductors, on the other side, has been studied and quenching of the fluorescence caused by semiconductor layer in thin sandwiches has been observed; (6) studies of the dynamics of photoexcitations revealed the exciton self-trapping in quasi-one-dimensional aggregates; and (7) conditions for preparation of highly crystalline fullerene C{sub 60} films by vacuum deposition have been found. Composites of C{sub 60} with conjugated polymers have been prepared.

  5. Effects of surface properties on barrier height and barrier inhomogeneities of platinum contacts to n-type 4H-SiC

    SciTech Connect (OSTI)

    Huang Lingqin; Li Shijuan; Wang Dejun [School of Electronic Science and Technology, Faculty of Electronic Information and Electrical Engineering, Dalian University of Technology, Dalian 116024 (China); Qin Fuwen [State Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), Dalian University of Technology, Dalian 116024 (China)

    2013-07-15

    We investigated the Schottky barrier of Pt/4H-SiC contact as a function of 4H-SiC surface properties which effectively controlled by electronic cyclotron resonance hydrogen plasma pretreatment for different periods and annealing. It is found that the effective barrier height monotonically increases with decreasing the degree of Fermi level pinning. Electrically homogeneous contacts are observed when the Fermi level (FL) is 'pinned (Bardeen limit)' and 'free-pinned (Schottky limit).' However, a partial pinning of FL leads to Gaussian distribution of inhomogeneous barrier height. These results could be correlated with changes in the magnitude and spatial distribution of surface state density after different pretreatments.

  6. Characterization of the surface properties of Illinois basin coals. Final technical report, September 1, 1991--August 31, 1992

    SciTech Connect (OSTI)

    Demir, I.; Harvey, R.D.; Lizzio, A.A.

    1992-12-31

    Surface area and pore volume distributions, surface charge, and surface chemical structure of the eight coals in the Illinois Basin Coal Sample Program (IBCSP) were determined. The IBC-101 coal has the lowest total and micropore (3.5-20.0 {Angstrom}) surface areas. The IBC-103 coal has the lowest mesopore (20-500 {Angstrom}) surface area. The mesopore surface areas of IBC-101, IBC-102, and IBC-107 coals are higher than the other four coals. Pore volume in pores <1800 {Angstrom} in diameter varies almost five-fold with IBC-103 coal having the lowest value. These differences may affect the reactivity of these coals during cleaning, conversion, and combustion processes. Surface charge and isoelectric points vary among the samples. The isoelectric point, where processes such as agglomeration and dewatering is most efficient, shifted to higher pH values for some of the samples upon exposure to air oxidation at room temperature. Diffuse reflectance infrared spectroscopy (DRIS) data indicate that the surfaces of the IBCSP coals contain aromatic hydrocarbon components, aliphatic hydrocarbons, and an aldehyde group. Ball-mill grinding reduced the organic hydroxyls and thus enriched relative concentrations of nonpolar aliphatic functional groups in the samples. The room temperature air oxidation did not cause any significant change on the surface chemical structure of the coals.

  7. Structural properties of Ge on SrTiO{sub 3} (001) surface and Ge/SrTiO{sub 3} interface

    SciTech Connect (OSTI)

    Pu, Long; Wang, Jianli Tang, Gang; Zhang, Junting

    2015-03-14

    Germanium−perovskite oxide heterostructures have a strong potential for next-generation low-voltage and low-leakage metal-oxide semiconductor field-effect transistors. We investigated the atomic structure and electronic properties of Ge on perfect and defective (001) SrTiO{sub 3} by first-principle calculations. The specific adsorption sites at the initial growth stage and the atomic structure of Ge on the SrTiO{sub 3} (001) substrate have been systematically investigated. The surface grand potential was calculated and compared as a function of the relative chemical potential. The complete surface phase diagram was presented. The energetically favorable interfaces were pointed out among the atomic arrangements of the Ge/SrTiO{sub 3} (001) interfaces. The atomic structure and electronic properties of the intrinsic point defects were calculated and analyzed for the Ge/SrTiO{sub 3} (001) interfaces.

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosol Effects on Liquid-Water Path of Thin Stratocumulus Clouds Download a printable PDF Submitter: Penner, J. E., University of Michigan Lee, S., University of Michigan Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: n/a Thin clouds with mean liquid-water path (LWP) of ~ 50 g m-2 cover 27.5% of the globe and thus play an important role in the Earth's radiation budget. Radiative fluxes at the Earth's surface and top of atmosphere (TOA) are very sensitive to

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mixed-Phase Cloud Radiative Properties from M-PACE Microphysical Retrievals Download a printable PDF Submitter: de Boer, G., University of Colorado, Boulder/CIRES Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: de Boer G, WD Collins, S Menon, and CN Long. 2011. "Using surface remote sensors to derive radiative characteristics of mixed-phase clouds: An example from M-PACE." Atmospheric Chemistry and Physics, 11, doi: 10.5194/acp-11-11937-2011.

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Seasonal and Interannual Variability in 13C of Ecosystem Carbon Fluxes from 2002-2009 Submitter: Torn, M. S., Lawrence Berkeley National Laboratory Area of Research: Surface Properties Working Group(s): Aerosol Life Cycle Journal Reference: Torn MS, SC Biraud, CJ Still, WJ Riley, and JA Berry. 2011. "Seasonal and inter-annual variability in δ13C of net ecosystem carbon exchanges from 2002-2009 in the U.S. Southern Great Plains." Tellus, 63(2), 10.1111/j.1600-0889.2010.00519.x. Time

  11. Influence of particle size and water coverage on the thermodynamic properties of water confined on the surface of SnO2 cassiterite nanoparticles

    SciTech Connect (OSTI)

    Spencer, Elinor; Ross, Dr. Nancy; Parker, Stewart F.; Kolesnikov, Alexander I; Woodfield, Brian; Woodfield, K; Rytting, M; Boerio-Goates, Juliana; Navrotsky, Alexandra

    2011-01-01

    Inelastic neutron scattering (INS) data for SnO2 nanoparticles of three different sizes and varying hydration levels are presented. Data were recorded on five nanoparticle samples that had the following compositions: 2 nm SnO2*0.82H2O, 6 nm SnO2*0.055H2O, 6 nm SnO2*0.095H2O, 20 nm SnO2*0.072H2O, and 20 nm SnO2*0.092H2O. The isochoric heat capacity and vibrational entropy values at 298 K for the water confined on the surface of these nanoparticles were calculated from the vibrational density of states that were extracted from the INS data. This study has shown that the hydration level of the SnO2 nanoparticles influences the thermodynamic properties of the water layers and, most importantly, that there appears to be a critical size limit for SnO2 between 2 and 6 nm below which the particle size also affects these properties and above which it does not. These results have been compared with those for isostructural rutile-TiO2 nanoparticles [TiO2*0.22H2O and TiO2*0.37H2O], which indicated that water on the surface of TiO2 nanoparticles is more tightly bound and experiences a greater degree of restricted motion with respect to water on the surface of SnO2 nanoparticles. This is believed to be a consequence of the difference in chemical composition, and hence surface properties, of these metal oxide nanoparticles.

  12. ''Green'' Biopolymers for Improved Decontamination of Metals from Surfaces: Sorptive Characterization and Coating Properties.. Annual report to be submitted to DOE Program Managers for posting on web page.

    SciTech Connect (OSTI)

    Davison, BH

    2001-06-15

    The proposed research aims to develop a fundamental understanding of important biological and physical chemical parameters for effective decontamination of metal surfaces using environmentally benign aqueous-based biopolymer solutions. Understanding how heavy metal-chelating biopolymers coat and interact with contaminated surfaces will benefit the development of novel, safe, easy-to-apply decontamination methodologies for removal of radionuclides and heavy metals. The benefits of these methodologies will include the following: decreased exposure hazards for workers; decreased secondary waste generation; increased efficiency of decontamination; positive public appeal and development of novel, nature-friendly business opportunities; and lower cost of cleanup to the government.

  13. Uncertainty quantification for evaluating impacts of caprock and reservoir properties on pressure buildup and ground surface displacement during geological CO2 sequestration

    SciTech Connect (OSTI)

    Bao, Jie; Hou, Zhangshuan; Fang, Yilin; Ren, Huiying; Lin, Guang

    2013-08-12

    A series of numerical test cases reflecting broad and realistic ranges of geological formation properties was developed to systematically evaluate and compare the impacts of those properties on geomechanical responses to CO2 injection. A coupled hydro-geomechanical subsurface transport simulator, STOMP (Subsurface Transport over Multiple Phases), was adopted to simulate the CO2 migration process and geomechanical behaviors of the surrounding geological formations. A quasi-Monte Carlo sampling method was applied to efficiently sample a high-dimensional parameter space consisting of injection rate and 14 subsurface formation properties, including porosity, permeability, entry pressure, irreducible gas and aqueous saturation, Young’s modulus, and Poisson’s ratio for both reservoir and caprock. Generalized cross-validation and analysis of variance methods were used to quantitatively measure the significance of the 15 input parameters. Reservoir porosity, permeability, and injection rate were found to be among the most significant factors affecting the geomechanical responses to the CO2 injection. We used a quadrature generalized linear model to build a reduced-order model that can estimate the geomechanical response instantly instead of running computationally expensive numerical simulations. The injection pressure and ground surface displacement are often monitored for injection well safety, and are believed can partially reflect the risk of fault reactivation and seismicity. Based on the reduced order model and response surface, the input parameters can be screened for control the risk of induced seismicity. The uncertainty of the subsurface structure properties cause the numerical simulation based on a single or a few samples does not accurately estimate the geomechanical response in the actual injection site. Probability of risk can be used to evaluate and predict the risk of injection when there are great uncertainty in the subsurface properties and operation

  14. ARM - Measurement - Sea surface temperature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sea surface temperature The temperature of sea water near the surface. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the...

  15. Tailoring surface properties and structure of layered double hydroxides using silanes with different number of functional groups

    SciTech Connect (OSTI)

    Tao, Qi; He, Hongping; Li, Tian; Frost, Ray L.; Zhang, Dan; He, Zisen

    2014-05-01

    Four silanes, trimethylchlorosilane (TMCS), dimethyldiethoxylsilane (DMDES), 3-aminopropyltriethoxysilane (APTES) and tetraethoxysilane (TEOS), were adopted to graft layered double hydroxides (LDH) via an induced hydrolysis silylation method (IHS). Fourier transform infrared spectra (FTIR) and {sup 29}Si MAS nuclear magnetic resonance spectra ({sup 29}Si MAS NMR) indicated that APTES and TEOS can be grafted onto LDH surfaces via condensation with hydroxyl groups of LDH, while TMCS and DMDES could only be adsorbed on the LDH surface with a small quantity. A combination of X-ray diffraction patterns (XRD) and {sup 29}Si MAS NMR spectra showed that silanes were exclusively present in the external surface and had little influence on the long range order of LDH. The surfactant intercalation experiment indicated that the adsorbed and/or grafted silane could not fix the interlamellar spacing of the LDH. However, they will form crosslink between the particles and affect the further surfactant intercalation in the silylated samples. The replacement of water by ethanol in the tactoids and/or aggregations and the polysiloxane oligomers formed during silylation procedure can dramatically increase the value of BET surface area (S{sub BET}) and total pore volumes (V{sub p}) of the products. - Graphical abstract: The replacement of water by ethanol in the tactoids and aggregations of LDHs, and the polysiloxane oligomers formed during silylation process can dramatically increase the BET surface area (S{sub BET}) and the total pore volume (V{sub p}) of the silylated products. - Highlights: Silanes with multifunctional groups were grafted onto LDH surface in C{sub 2}H{sub 5}OH medium. The number of hydrolysable groups in silanes affects the structure of grafted LDH. Replacement of H{sub 2}O by C{sub 2}H{sub 5}OH in aggregations increases S{sub BET} and V{sub p} of grafted LDH. Polysiloxane oligomers contribute to the increase of S{sub BET} and V{sub p} of grafted LDH.

  16. PROCESSING, MICROSTRUCTURE AND MECHANICAL PROPERTY CORRELATION IN Al-B4C SURFACE COMPOSITE PRODUCED VIA FRICTION STIR PROCESSING

    SciTech Connect (OSTI)

    Komarasamy, Mageshwari; Mishra, Rajiv S.; Baumann, John A.; Grant, Glenn J.; Hovanski, Yuri

    2013-01-29

    Friction stir processing (FSP) was employed to prepare surface composites (SC) composed of B4C particles in 5024 Al matrix. The processing parameters, such as hole pattern and geometry,and the number of FSP passes, were optimized to obtain uniform powder distribution. The micrographs revealed a homogeneous distribution of the particles with good interfacial bonding. The hardness of the composite was uniform across the processed region which again indicates the uniformity of powder distribution. The modulus of the surface composite was measured using strain gage and showed a significant improvement. This improvement in modulus lies in the load sharing capability from the soft matrix to the hard particles.

  17. The role of precipitation size distributions in km-scale NWP simulations of intense precipitation: Evaluation of cloud properties and surface precipitation

    SciTech Connect (OSTI)

    VanWeverberg K.; Vogelmann A.; vanLipzig, N. P. M.; Delobbec, L.

    2012-04-01

    We investigate the sensitivity of simulated cloud properties and surface precipitation to assumptions regarding the size distributions of the precipitating hydrometeors in a one-moment bulk microphysics scheme. Three sensitivity experiments were applied to two composites of 15 convective and 15 frontal stratiform intense precipitation events observed in a coastal midlatitude region (Belgium), which were evaluated against satellite-retrieved cloud properties and radar-rain-gauge derived surface precipitation. It is found that the cloud optical thickness distribution was well captured by all experiments, although a significant underestimation of cloudiness occurred in the convective composite. The cloud-top-pressure distribution was improved most by more realistic snow size distributions (including a temperature-dependent intercept parameter and non-spherical snow for the calculation of the slope parameter), due to increased snow depositional growth at high altitudes. Surface precipitation was far less sensitive to whether graupel or hail was chosen as the rimed ice species, as compared to previous idealized experiments. This smaller difference in sensitivity could be explained by the stronger updraught velocities and higher freezing levels in the idealized experiments compared to typical coastal midlatitude environmental conditions.

  18. Amphiphilic Surface Active Triblock Copolymers with Mixed Hydrophobic and Hydrophilic Side Chains for Tuned Marine Fouling-Release Properties

    SciTech Connect (OSTI)

    Park, D.; Weinman, C; Finlay, J; Fletcher, B; Paik, M; Sundaram, H; Dimitriou, M; Sohn, K; Callow, M; et al.

    2010-01-01

    Two series of amphiphilic triblock surface active block copolymers (SABCs) were prepared through chemical modification of two polystyrene-block-poly(ethylene-ran-butylene)-block-polyisoprene ABC triblock copolymer precursors. The methyl ether of poly(ethylene glycol) [M{sub n} {approx} 550 g/mol (PEG550)] and a semifluorinated alcohol (CF{sub 3}(CF{sub 2}){sub 9}(CH{sub 2}){sub 10}OH) [F10H10] were attached at different molar ratios to impart both hydrophobic and hydrophilic groups to the isoprene segment. Coatings on glass slides consisting of a thin layer of the amphiphilic SABC deposited on a thicker layer of an ABA polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene thermoplastic elastomer were prepared for biofouling assays with algae. Dynamic water contact angle analysis, X-ray photoelectron spectroscopy (XPS) and near-edge X-ray absorption fine structure (NEXAFS) measurements were utilized to characterize the surfaces. Clear differences in surface structure were realized as the composition of attached side chains was varied. In biofouling assays, the settlement (attachment) of zoospores of the green alga Ulva was higher for surfaces incorporating a large proportion of the hydrophobic F10H10 side chains, while surfaces with a large proportion of the PEG550 side chains inhibited settlement. The trend in attachment strength of sporelings (young plants) of Ulva did not show such an obvious pattern. However, amphiphilic SABCs incorporating a mixture of PEG550 and F10H10 side chains performed the best. The number of cells of the diatom Navicula attached after exposure to flow decreased as the content of PEG550 to F10H10 side chains increased.

  19. Surface oxygen exchange properties of Sr doped La2NiO4+δ as SOFC cathode: Thin-film electrical conductivity relaxation investigation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guan, Bo; Li, Wenyuan; Zhang, Xinxin; Liu, Xingbo

    2015-06-02

    La2-xSrxNiO4+δ dense films are prepared by a novel spray-modified pressing method. The surface reaction kinetics is investigated via electrical conductivity relaxation (ECR). The layer thickness, 5~10 μm, is much less than the characteristic length of lanthanum nickelates, resulting in surface-controlled situation and allowing more accurate fitting than the traditional pellets ECR on the surface exchange coefficient (k). k for LNO is 1.6×10-5 cm/s in 0.2 atm at 700°C. Sr doping impairs the exchange kinetics, and k of Sr40 is about one order of magnitude smaller than undoped one. Interstitial oxygen and Ni oxidation state are suggested the predominant roles inmore » determining surface kinetics. In conclusion, given the properties of the thin-film herein developed by spray-modified pressing is closer to those in practical porous electrode compared to pulsed laser deposited film in terms of preferential orientation and strain, it warrants the use of such a method in a variety of pertinent investigations.« less

  20. Surface and Interfacial Properties of Nonaqueous-Phase Liquid Mixtures Released to the Subsurface at the Hanford Site

    SciTech Connect (OSTI)

    Nellis, Scott; Yoon, Hongkyu; Werth, Charlie; Oostrom, Martinus; Valocchi, Albert J.

    2009-05-01

    Surface and interfacial tensions that arise at the interface between different phases are key parameters affecting Nonaqueous Phase Liquid (NAPL) movement and redistribution in the vadose zone after spill events. In this study, the impact of major additive components on surface and interfacial tensions for organic mixtures and wastewater was investigated. Organic mixture and wastewater compositions are based upon carbon tetrachloride (CT) mixtures released at the Hanford site, where CT was discharged simultaneously with dibutyl butyl phosphonate (DBBP), tributyl phosphate (TBP), dibutyl phosphate (DBP), and a machining lard oil (LO). A considerable amount of wastewater consisting primarily of nitrates and metal salts was also discharged. The tension values measured in this study revealed that the addition of these additive components caused a significant lowering of the interfacial tension with water or wastewater and the surface tension of the wastewater phase in equilibrium with the organic mixtures, compared to pure CT, but had minimal effect on the surface tension of the NAPL itself. These results lead to large differences in spreading coefficients for several mixtures, where the additives caused both a higher (more spreading) initial spreading coefficient and a lower (less spreading) equilibrium spreading coefficient. This indicates that if these mixtures migrate into uncontaminated areas, they will tend to spread quickly, but form a higher residual NAPL saturation after equilibrium, as compared to pure CT. Over time, CT likely volatilizes more rapidly than other components in the originally disposed mixtures and the lard oil and phosphates would become more concentrated in the remaining NAPL, resulting in a lower interfacial tension for the mixture. Spreading coefficients are expected to increase and perhaps change the equilibrated organic mixtures from nonspreading to spreading in water-wetting porous media. These results show that the behavior of organic

  1. Basic research in crystalline and noncrystalline ceramic systems. Annual report, November 1, 1981-November 30, 1982

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    Research activities are described concerning the electrical and optical properties of ceramics; kinetic studies; defect structures; defect interactions, grain boundaries and surfaces; sintering studies; and technological research needs in ceramic science.

  2. Structure and electronic properties of Cu nanoclusters supported on Mo{sub 2}C(001) and MoC(001) surfaces

    SciTech Connect (OSTI)

    Posada-Pérez, Sergio; Viñes, Francesc; Illas, Francesc

    2015-09-21

    The atomic structure and electronic properties of Cu{sub n} nanoclusters (n = 4, 6, 7, and 10) supported on cubic nonpolar δ-MoC(001) and orthorhombic C- or Mo-terminated polar β-Mo{sub 2} C(001) surfaces have been investigated by means of periodic density functional theory based calculations. The electronic properties have been analyzed by means of the density of states, Bader charges, and electron localization function plots. The Cu nanoparticles supported on β-Mo{sub 2} C(001), either Mo- or C-terminated, tend to present a two-dimensional structure whereas a three-dimensional geometry is preferred when supported on δ-MoC(001), indicating that the Mo:C ratio and the surface polarity play a key role determining the structure of supported clusters. Nevertheless, calculations also reveal important differences between the C- and Mo-terminated β-Mo{sub 2} C(001) supports to the point that supported Cu particles exhibit different charge states, which opens a way to control the reactivity of these potential catalysts.

  3. Structure and electronic properties of Cu nanoclusters supported on Mo2C(001) and MoC(001) surfaces

    SciTech Connect (OSTI)

    Posada-Pérez, Sergio; Viñes, Francesc; Rodríguez, José A.; Illas, Francesc

    2015-09-15

    In this study, the atomic structure and electronic properties of Cun nanoclusters (n = 4, 6, 7, and 10) supported on cubic nonpolar δ-MoC(001) and orthorhombic C- or Mo-terminated polar β-Mo2C(001) surfaces have been investigated by means of periodic density functional theory based calculations. The electronic properties have been analyzed by means of the density of states, Bader charges, and electron localization function plots. The Cu nanoparticles supported on β-Mo2C(001), either Mo- or C-terminated, tend to present a two-dimensional structure whereas a three-dimensional geometry is preferred when supported on δ-MoC(001), indicating that the Mo:C ratio and the surface polarity play a key role determining the structure of supported clusters. Nevertheless, calculations also reveal important differences between the C- and Mo-terminated β-Mo2C(001) supports to the point that supported Cu particles exhibit different charge states, which opens a way to control the reactivity of these potential catalysts.

  4. Water adsorption onto Y and V sites at the surface of the YVO{sub 4} photocatalyst and related electronic properties

    SciTech Connect (OSTI)

    Oshikiri, Mitsutake; Matsushita, Akiyuki; Ye, Jinhua; Boero, Mauro

    2009-07-21

    The dynamics of water molecules and the adsorption properties at the V and Y sites on the surface of the photocatalyst YVO{sub 4} have been investigated by first principles molecular dynamics. This system has shown an excellent performance in the production of both hydrogen and oxygen in the ultraviolet region. Yet, its catalytic properties, related to the electronic structure, are poorly understood. Here we show that imperfectly oxygen coordinated V sites (i.e., not fourfold oxygen coordinated vanadium but threefold oxygen coordinated vanadium) exposed on the catalyst surface play a central role in the dissociation of water molecules. By simulating the H{sub 2}O adsorption process and by performing an analysis of the electronic structure of the unoccupied orbitals corresponding to the lowest unoccupied energy level of the system, we can infer that the dissociation of water at these imperfectly oxygen coordinated V sites can promote the proton reduction and is expected to trigger the H{sub 2} generation.

  5. Investigation of Cathode Electrocatalytic Activity using Surface Engineered Thin Film Samples and High Temperature Physical Property Measurements

    SciTech Connect (OSTI)

    Salvador, Paul

    2014-02-23

    In this Final Technical Report, a summary of the technical output from the award DE-NT0004105 is given. First, the major goals and observations from the project are reviewed and then specific example results are presented as highlights. The surprising importance of microstructure on the surface chemical exchange coefficient in La0.7Sr0.3MnO3 (LSM) was uncovered in this work and is re-emphasized in this report. Significant orientation and thickness dependencies of the surface exchange coefficient are correlated with microstructural effects, especially to the nature of the strain, dislocation content, and grain boundary population. We also illustrate similar microstructural effects are present in other SOFC cathode systems, including LSCF (La1-xSrxCo1-yFeyO3) and La2NiO4 (LNO). Throughout the report, the relation to SOFC cathode performance is discussed.

  6. Effect of deuterium substitution for hydrogen in surface functionalisation of hydrophilic nanosilicon particles on their spectral and dynamic properties

    SciTech Connect (OSTI)

    Kompanets, V O; Chekalin, S V; Dorofeev, S G; Kononov, N N; Barzilovich, P Yu; Ishchenko, A A

    2014-06-30

    Broadband femtosecond spectroscopy has been used to study two types of hydrophilic silicon nanoparticles: (1) photoluminescent, passivated with deuterium and oxidised in fully deuterated dimethyl sulphoxide, and (2) nonluminescent (control samples having a similar crystalline core), passivated with hydrogen and oxidised in dimethyl sulphoxide. We have found significant differences in ultrafast spectral temporal induced absorption dynamics between the two types of nanoparticles in the energy range corresponding to their calculated band gap. The observed distinction is due to the considerably higher oxidation rate of silicon on the surface of the deuterated samples in comparison with the undeuterated ones and with the associated increase in the number of photoluminescence centres on the surface of the nanoparticles. In the samples containing self-trapped exciton (STE) energy states responsible for the photoluminescence in the red spectral region, carrier capture at these levels and carrier relaxation to the ground state have characteristic times in the femtosecond range. In the samples free of STE states, excited carriers relax to the conduction band bottom in a characteristic time of several picoseconds. (extreme light fields and their applications)

  7. Adsorption and switching properties of a N-benzylideneaniline based molecular switch on a Au(111) surface

    SciTech Connect (OSTI)

    Ovari, Laszlo; Luo, Ying; Haag, Rainer; Leyssner, Felix; Tegeder, Petra; Wolf, Martin

    2010-07-28

    High resolution electron energy loss spectroscopy has been employed to analyze the adsorption geometry and the photoisomerization ability of the molecular switch carboxy-benzylideneaniline (CBA) adsorbed on Au(111). CBA on Au(111) adopts a planar (trans) configuration in the first monolayer (ML) as well as for higher coverages (up to 6 ML), in contrast to the strongly nonplanar geometry of the molecule in solution. Illumination with UV light of CBA in direct contact with the Au(111) surface ({<=}1 ML) caused no changes in the vibrational structure, whereas at higher coverages (>1 ML) pronounced modifications of vibrational features were observed, which we assign to a trans{yields}cis isomerization. Thermal activation induced the back reaction to trans-CBA. We propose that the photoisomerization is driven by a direct (intramolecular) electronic excitation of the adsorbed CBA molecules in the second ML (and above) analogous to CBA in the liquid phase.

  8. Effects of charge and surface ligand properties of nanoparticles on oxidative stress and gene expression within the gut of Daphnia magna

    SciTech Connect (OSTI)

    Dominguez, Gustavo A.; Lohse, Samuel E.; Torelli, Marco; Murphy, Catherine; Hamers, Robert J.; Orr, Galya; Klaper, Rebecca D.

    2015-05-01

    Concern has been raised regarding the current and future release of engineered nanomaterials into aquatic environments from industry and other sources. However, not all nanomaterials may cause an environ-mental impact and identifying which nanomaterials may be of greatest concern has been difficult. It is thought that the surface groups of a functionalized nanoparticles (NPs) may play a significant role in determining their interactions with aquatic organisms, but the way in which surface properties of NPs impact their toxicity in whole organisms has been minimally explored. A major point of interaction of NPs with aquatic organisms is in the gastrointestinal tract as they ingest particulates from the water column or from the sediment. The main goal of this study was to use model gold NP (AuNPs) to evaluate the potential effects of the different surfaces groups on NPs on the gut of an aquatic model organism, Daphnia magna. In this study, we exposed daphnids to a range of AuNPs concentrations and assessed the impact of AuNP exposure in the daphnid gut by measuring reactive oxygen species (ROS) production and expression of genes associated with oxidative stress and general cellular stress: glutathione S-transferase(gst), catalase (cat), heat shock protein 70 (hsp70), and metallothionein1 (mt1). We found ROS formation and gene expression were impacted by both charge and the specific surface ligand used. We detected some degree of ROS production in all NP exposures, but positively charged AuNPs induced a greater ROS response. Similarly, we observed that, compared to controls, both positively charged AuNPs and only one negatively AuNP impacted expression of genes associated with cellular stress. Finally, ligand-AuNP exposures showed a different toxicity and gene expression profile than the ligand alone, indicating a NP specific effect.

  9. Moving | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Read More GE Scientists Demonstrate Promising Anti-icing Nano Surfaces GE Global Research today presented new research findings on its nanotextured anti-icing surfaces. In ...

  10. U.S. Department of Energy (DOE)--Surface Biogeochemical Research (SBR) 6th Annual PI Meeting: Abstracts

    SciTech Connect (OSTI)

    Hazen Ed., T.C.

    2011-04-11

    On behalf of the Subsurface Biogeochemical Research (SBR) program managers in the Climate and Environmental Sciences Division (CESD), Office of Biological and Environmental Research (BER), welcome to the 2011 SBR Principal Investigators meeting. Thank you in advance for your attendance and your presentations at this year's meeting. As the events in Japan continue to unfold, we are all reminded that the research we perform on radionuclide behavior in the environment has implications beyond legacy waste cleanup and in fact has its place in the discussion on the expanded use of nuclear power. As in the past, there are three broad objectives to the Principal Investigators meeting: (1) to provide opportunities to share research results and promote interactions among the SBR scientists and other invited guests; (2) to evaluate the progress of each project within the program; and (3) to showcase the scientific expertise and research progress over the past year to senior managers within the DOE Office of Science, the technology offices within DOE, and other invited attendees from other Federal Agencies. This past year has seen a few significant changes within BER and within the SBR program. In November, our Associate Director for BER, Anna Palmisano, retired from Federal service. Just this month, Dr. Sharlene Weatherwax (Division Director for Biological Systems Sciences) has been named as the new Associate Director for BER. In August, BER welcomed Dr. Gary Geernaert as the new Division Director for CESD. Gary joins the division from Los Alamos National Laboratory with a background in atmospheric science. Within the SBR program, a new Strategic Plan was completed last June (currently posted on the SBR and the Office of Science website). The new strategic plan is intended to foster integration within the Environmental Systems Science portion of the BER budget that includes both SBR and Terrestrial Ecosystem Sciences (TES). Both these programs share a goal of advancing a

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Submitter: Westwater, E. R., University of Colorado Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Properties Journal Reference:...

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liljegren, J. C., Argonne National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Properties, Radiative Processes...

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Influence of Dust Composition on Cloud Droplet Formation Download a printable PDF Submitter: Chuang, C., Lawrence Livermore National Laboratory Area of Research: Aerosol Properties...

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Broadband Albedo Observations in the Southern Great Plains Submitter: Lamb, P. J., University of Oklahoma Area of Research: Aerosol Properties Working Group(s): Aerosol Journal...

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nucleation Events Download a printable PDF Submitter: McMurry, P. ., University of Minnesota Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal ...

  16. Early Career. Harnessing nanotechnology for fusion plasma-material interface research in an in-situ particle-surface interaction facility

    SciTech Connect (OSTI)

    Allain, Jean Paul

    2014-08-08

    This project consisted of fundamental and applied research of advanced in-situ particle-beam interactions with surfaces/interfaces to discover novel materials able to tolerate intense conditions at the plasma-material interface (PMI) in future fusion burning plasma devices. The project established a novel facility that is capable of not only characterizing new fusion nanomaterials but, more importantly probing and manipulating materials at the nanoscale while performing subsequent single-effect in-situ testing of their performance under simulated environments in fusion PMI.

  17. New Analysis Methods Estimate a Critical Property of Ethanol Fuel Blends (Fact Sheet), Highlights in Research & Development, NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methods developed at NREL disclose the impact of ethanol on gasoline blend heat of vaporization with potential for improved efficiency of spark-ignition engines. More stringent standards for fuel economy, regulation of greenhouse gas emissions, and the mandated increase in the use of renew- able fuel are driving research to improve the efficiency of spark ignition engines. When fuel properties such as octane number and evaporative cooling (heat of vaporization or HOV) are insufficient, they

  18. Research on thermophoretic and inertial aspects of ash particle deposition on heat exchanger surfaces in coal-fired equipment

    SciTech Connect (OSTI)

    Rosner, D.E.

    1988-12-01

    A real-time laser light-reflectivity technique is being used to study simultaneous thermophoretic and inertial influences on the deposition behavior of MgO particles produced via ultrasonic nebulization (submicrometer range). The deposition surface (a concave platinum ribbon) is exposed to a high velocity/temperature jet of alkali sulfate-free combustion products exiting from a seeded (C3[sub 3]H[sub 8]/air) microcombustor (110 cm[sup 3]). The reflectivity data were calibrated against deposition rates obtained from SEM pictures of the target, and were normalized with the nominal particle feed rate, in order to obtain the mass transfer Stanton number, St[sub m], trends depicted in Figure 1. For the submicron (ca. 0.7[mu]m) particles inertial effects appear to set in at Stokes (Stk) numbers of O(10[sup [minus]2]) (an order of magnitude lower than the ones needed for pure'' inertial impaction), affecting significantly the dominant thermophoretic deposition mechanism. A first order (in Stk) theoretical analysis of the problem in which particle inertia is treated as equivalent to pressure diffusion,'' cannot explain the observed dependence of the deposition rate on Stk. We are presently formulating a Lagrangian approach, valid for all values of Stk, in order to interpret these data. In addition, a Single Particle Counter (SPC) and Transit Time Velocimeter (TTV), are being developed, to allow more precise measurements of particle feed rates and velocities.

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MBL Aerosol Properties and Their Impact on CCN at the Azores-AMF Site Download a printable PDF Submitter: Dong, X., University of Arizona Area of Research: Aerosol Properties Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Logan T, B Xi, and X Dong. 2014. "Aerosol properties and their influences on marine boundary layer cloud condensation nuclei at the ARM mobile facility over the Azores." Journal of Geophysical Research - Atmospheres, 119(8),

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From Fire to Ice Download a printable PDF Submitter: Kulkarni, G., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Kulkarni GR, M Nandasiri, A Zelenyuk, J Beranek, N Madaan, A Devaraj, V Shutthanandan, S Thevuthasan, and T Varga. 2015. "Effects of crystallographic properties on the ice nucleation properties of volcanic ash particles." Geophysical Research Letters, 42(8), doi:10.1002/2015GL063270. Tons of

  1. Collider Detector at Fermilab (CDF): Data from the QCD Group's Research into Properties of the Strong Interaction

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    ,

    The Collider Detector at Fermilab (CDF) is a Tevatron experiment at Fermilab. The Tevatron, a powerful particle accelerator, accelerates protons and antiprotons close to the speed of light, and then makes them collide head-on inside the CDF detector. The CDF detector is used to study the products of such collisions. The CDF Physics Group at Fermilab is organized into six working groups, each with a specific focus. The QCD group studies the properties of the strong interaction. Their public web page makes data and numerous figures available from both CDF Runs I and II.

  2. Evidence of incomplete annealing at 800 °C and the effects of 120 °C baking on the crystal orientation and the surface superconducting properties of cold-worked and chemically polished Nb

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sung, Z. -H.; Dzyuba, A.; Lee, P. J.; Larbalestier, D C; Cooley, L. D.

    2015-07-01

    High-purity niobium rods were cold-worked by wire-drawing, followed by various combinations of chemical polishing and high-vacuum baking at 120 °C or annealing at 800 °C in order to better understand changes to the surface superconducting properties resulting from typical superconducting radio-frequency cavity processing. AC susceptibility measurements revealed an enhanced upper transition Tc at ~ 9.3–9.4 K in all samples that was stable through all annealing steps, a value significantly above the accepted Tc of 9.23 K for pure annealed niobium. Corresponding elevations were seen in the critical fields, the ratio of the surface critical field Hc3 to the bulk uppermore » critical field Hc2 rising to 2.3, well above the Ginzburg–Landau value of 1.695. Orientation imaging revealed an extensive dislocation rich sub-grain structure in the as-drawn rods, a small reduction of the surface strain after baking at 120 °C, and a substantial but incomplete recrystallization near the surface after annealing at 800 °C. We interpret these changes in surface superconducting and structural properties to extensive changes in the near-surface interstitial contamination produced by baking and annealing and to synergistic interactions between H and surface O introduced during electropolishing and buffered chemical polishing.« less

  3. Evidence of incomplete annealing at 800 °C and the effects of 120 °C baking on the crystal orientation and the surface superconducting properties of cold-worked and chemically polished Nb

    SciTech Connect (OSTI)

    Sung, Z. -H.; Dzyuba, A.; Lee, P. J.; Larbalestier, D C; Cooley, L. D.

    2015-07-01

    High-purity niobium rods were cold-worked by wire-drawing, followed by various combinations of chemical polishing and high-vacuum baking at 120 °C or annealing at 800 °C in order to better understand changes to the surface superconducting properties resulting from typical superconducting radio-frequency cavity processing. AC susceptibility measurements revealed an enhanced upper transition Tc at ~ 9.3–9.4 K in all samples that was stable through all annealing steps, a value significantly above the accepted Tc of 9.23 K for pure annealed niobium. Corresponding elevations were seen in the critical fields, the ratio of the surface critical field Hc3 to the bulk upper critical field Hc2 rising to 2.3, well above the Ginzburg–Landau value of 1.695. Orientation imaging revealed an extensive dislocation rich sub-grain structure in the as-drawn rods, a small reduction of the surface strain after baking at 120 °C, and a substantial but incomplete recrystallization near the surface after annealing at 800 °C. We interpret these changes in surface superconducting and structural properties to extensive changes in the near-surface interstitial contamination produced by baking and annealing and to synergistic interactions between H and surface O introduced during electropolishing and buffered chemical polishing.

  4. Final Technical Report for Interagency Agreement No. DE-SC0005453 “Characterizing Aerosol Distributions, Types, and Optical and Microphysical Properties using the NASA Airborne High Spectral Resolution Lidar (HSRL) and the Research Scanning Polarimeter (RSP)”

    SciTech Connect (OSTI)

    Hostetler, Chris; Ferrare, Richard

    2015-01-13

    Measurements of the vertical profile of atmospheric aerosols and aerosol optical and microphysical characteristics are required to: 1) determine aerosol direct and indirect radiative forcing, 2) compute radiative flux and heating rate profiles, 3) assess model simulations of aerosol distributions and types, and 4) establish the ability of surface and space-based remote sensors to measure the indirect effect. Consequently the ASR program calls for a combination of remote sensing and in situ measurements to determine aerosol properties and aerosol influences on clouds and radiation. As part of our previous DOE ASP project, we deployed the NASA Langley airborne High Spectral Resolution Lidar (HSRL) on the NASA B200 King Air aircraft during major field experiments in 2006 (MILAGRO and MaxTEX), 2007 (CHAPS), 2009 (RACORO), and 2010 (CalNex and CARES). The HSRL provided measurements of aerosol extinction (532 nm), backscatter (532 and 1064 nm), and depolarization (532 and 1064 nm). These measurements were typically made in close temporal and spatial coincidence with measurements made from DOE-funded and other participating aircraft and ground sites. On the RACORO, CARES, and CalNEX missions, we also deployed the NASA Goddard Institute for Space Studies (GISS) Research Scanning Polarimeter (RSP). RSP provided intensity and degree of linear polarization over a broad spectral and angular range enabling column-average retrievals of aerosol optical and microphysical properties. Under this project, we analyzed observations and model results from RACORO, CARES, and CalNex and accomplished the following objectives. 1. Identified aerosol types, characterize the vertical distribution of the aerosol types, and partition aerosol optical depth by type, for CARES and CalNex using HSRL data as we have done for previous missions. 2. Investigated aerosol microphysical and macrophysical properties using the RSP. 3. Used the aerosol backscatter and extinction profiles measured by the HSRL

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Area of Research: Cloud DistributionsCharacterizations Working Group(s): Cloud Properties Journal Reference: Wang X, KN Liou, SS Ou, GG Mace, and M Deng. 2009. "Remote sensing of ...

  6. Measuring Complementary Electronic Structure Properties of both Deposited and Gas Phase Clusters using STM, UPS, and PES: Size-Selected Clusters on Surfaces

    SciTech Connect (OSTI)

    Bowen, Kit H.

    2014-03-05

    In this project, we studied size-selected cluster interactions with surfaces, with other clusters on surfaces, and with external stimuli. These studies focused on mobility as a function of cluster size, surface morphologies as a function of composition and coverage, ion-induced modification and reactivity of clusters as a function of composition, the structural evolution of cluster cuboids culminating in the characterization of theoretically-predicted baby crystal clusters, and unusual fractal pattern formation due to deposition.

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Importance of Small Ice Crystals to Cirrus Properties: Observations from TWP-ICE Download a printable PDF Submitter: McFarquhar, G., University of Illinois, Urbana Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: McFarquhar, G.M., J. Um, M. Freer, D. Baumgardner, G.L. Kok and G. Mace, 2007: Importance of small ice crystals to cirrus properties: Observations from the Tropical Warm Pool International Cloud Experiment (TWP-ICE). Geophys.

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Seasonal Variation of the Physical Properties of Marine Boundary Clouds Download a printable PDF Submitter: Zhang, M., Stony Brook University Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Modeling, Cloud Properties Journal Reference: Lin W, M Zhang, and NG Loeb. 2009. "Seasonal variation of the physical properties of marine boundary layer clouds off the California coast." Journal of Climate, 22(10), doi:10.1175/2008JCLI2478.1. Image (a). Seasonal

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Satellite Retrievals of Mixed-phase Cloud Properties Download a printable PDF Submitter: Ou, S., University of California, Los Angeles Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Ou SS, KN Liou, XJ Wang, A Dybdahl, M Mussetto, LD Carey, J Niu, JA Kankiewicz, S Kidder, and TH Von der Haar. 2009. "Retrievals of mixed-phase cloud properties during the National Polar-Orbiting Operational Environmental Satellite System."

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase State and Physical Properties of Ambient and Lab Generated Aerosols: X-ray Microscopy Download a printable PDF Submitter: OBrien, R. E., Lawrence Berkeley National Laboratory Gilles, M., Lawrence Berkeley National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: O'Brien RE, A Neu, SA Epstein, AC MacMillan, B Wang, ST Kelly, SA Nizkorodov, A Laskin, RC Moffet, and MK Gilles. 2014. "Physical properties of ambient and

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Three Dimensions Are Better Than Two, When It Comes to Representing Aerosols PI Contact: Ching, J., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Ching J, RA Zaveri, RC Easter, N Riemer, and JD Fast. 2016. "A three-dimensional sectional representation of aerosol mixing state for simulating optical properties and cloud condensation nuclei." Journal of Geophysical Research - Atmospheres, 121(10),

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Detection and Retrieval of Cirrus Clouds in the Tropics from AIRS: Validation from ARM Data Submitter: Yue, Q., Jet Propulsion Laboratory/California Institute of Technology Liou, K., University of California, Los Angeles Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Yue Q and KN Liou. 2009. "Cirrus cloud optical and microphysical properties determined from AIRS infrared spectra." Geophysical Research Letters, 36, L05810,

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosols Help Heat Up the Yangtze River Delta in China Download a printable PDF Submitter: Flynn, C. J., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Liu J, Z Li, Y Zheng, C Flynn, and M Cribb. 2012. "Seasonal variations of aerosol optical properties, vertical distribution and associated radiative effects in the Yangtze Delta region of China." Journal of Geophysical Research, 117, D00K38,

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluation of Cloud Properties in Major Reanalyses Download a printable PDF Submitter: Liu, Y., Brookhaven National Laboratory Wu, W., Brookhaven National Laboratory Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle Journal Reference: Wu W, YG Liu, and AK Betts. 2012. "Observationally based evaluation of NWP reanalyses in modeling cloud properties over the Southern Great Plains." Journal of Geophysical Research - Atmospheres, 117, D12202,

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Retrieving Cloud and Aerosol Properties from the ARM Raman Lidar Download a printable PDF Submitter: Thorsen, T., NASA - Langley Research Center Fu, Q., University of Washington Area of Research: Cloud Distributions/Characterizations Working Group(s): Aerosol Life Cycle, Cloud Life Cycle Journal Reference: Thorsen TJ, Q Fu, RK Newsom, DD Turner, and JM Comstock. 2015. "Automated retrieval of cloud and aerosol properties from the ARM Raman lidar, Part I: Feature detection." Journal of

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Roles of Wind Shear at Different Vertical Levels in Cloud System Organization and Properties Download a printable PDF Submitter: Fan, J., Pacific Northwest National Laboratory Area of Research: Cloud Processes Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Chen Q, J Fan, S Hagos, W Gustafson, and L Berg. 2015. "Roles of wind shear at different vertical levels, Part I: Cloud system organization and properties." Journal of Geophysical Research -

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Summertime Radiative Forcing by Shallow Cumuli at the ARM SGP Download a printable PDF Submitter: Berg, L., Pacific Northwest National Laboratory Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: Berg LK, EI Kassianov, CN Long, and DL Mills. 2011. "Surface summertime radiative forcing by shallow cumuli at the ARM SGP." Journal of Geophysical Research - Atmospheres, 116, D01202, 10.1029/2010JD014593. Histogram of hourly average shortwave

  18. ARM - Measurement - Surface condition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    condition ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Surface condition State of the surface, including vegetation, land use, surface type, roughness, and such; often provided in model output. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list

  19. Temperature sensitive surfaces and methods of making same

    DOE Patents [OSTI]

    Liang, Liang [Richland, WA; Rieke, Peter C [Pasco, WA; Alford, Kentin L [Pasco, WA

    2002-09-10

    Poly-n-isopropylacrylamide surface coatings demonstrate the useful property of being able to switch charateristics depending upon temperature. More specifically, these coatings switch from being hydrophilic at low temperature to hydrophobic at high temperature. Research has been conducted for many years to better characterize and control the properties of temperature sensitive coatings. The present invention provides novel temperature sensitive coatings on articles and novel methods of making temperature sensitive coatings that are disposed on the surfaces of various articles. These novel coatings contain the reaction products of n-isopropylacrylamide and are characterized by their properties such as advancing contact angles. Numerous other characteristics such as coating thickness, surface roughness, and hydrophilic-to-hydrophobic transition temperatures are also described. The present invention includes articles having temperature-sensitve coatings with improved properties as well as improved methods for forming temperature sensitive coatings.

  20. Preface: Special Topic Section on Advanced Electronic Structure Methods for Solids and Surfaces

    SciTech Connect (OSTI)

    Michaelides, Angelos; Martinez, Todd J.; Alavi, Ali; Kresse, Georg

    2015-09-14

    This Special Topic section on Advanced Electronic Structure Methods for Solids and Surfaces contains a collection of research papers that showcase recent advances in the high accuracy prediction of materials and surface properties. It provides a timely snapshot of a growing field that is of broad importance to chemistry, physics, and materials science.

  1. Fluorinated silica microchannel surfaces

    DOE Patents [OSTI]

    Kirby, Brian J.; Shepodd, Timothy Jon

    2005-03-15

    A method for surface modification of microchannels and capillaries. The method produces a chemically inert surface having a lowered surface free energy and improved frictional properties by attaching a fluorinated alkane group to the surface. The coating is produced by hydrolysis of a silane agent that is functionalized with either alkoxy or chloro ligands and an uncharged C.sub.3 -C.sub.10 fluorinated alkane chain. It has been found that the extent of surface coverage can be controlled by controlling the contact time from a minimum of about 2 minutes to a maximum of 120 minutes for complete surface coverage.

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climatology of Aerosol Optical Depth in North-Central Oklahoma: 1992-2008 Download a printable PDF Submitter: Michalsky, J. J., Cooperative Institute for Research in Environmental Sciences Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Michalsky J, F Denn, C Flynn, G Hodges, P Kiedron, A Koontz, J Schlemmer, and SE Schwartz. 2010. "Climatology of aerosol optical depth in north-central Oklahoma: 1992-2008." Journal of Geophysical Research -

  3. Research Approach

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Approach Research Approach NETL's onsite research approach is based on integrating simulation tools with targeted experimental validation at real-life conditions in the lab and in the field. Simulation tools increase confidence in designs, thereby reducing the risk associated with incorporating multiple innovative technologies, realizing scale-up, and predicting the behavior and properties of real materials. The scientific underpinnings encoded into these models also ensure that

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Back to Basics: Theoretical Studies on Storm Clouds and Implications for Modeling For original submission and image(s), see ARM Research Highlights http://www.arm.gov/science/highlights/ Research Highlight Storms associated with deep convection are a key component of weather and climate. For example, they produce a large share of precipitation that falls to the Earth's surface, and their anvil shields act as a thermal blanket on the planet. To understand the behavior of these storms, researchers

  5. Using Radar, Lidar and Radiometer Data from NSA and SHEBA to Quantify Cloud Property Effects on the Surface Heat Budget in the Arctic

    SciTech Connect (OSTI)

    Janet Intrieri; Mathhew Shupe

    2005-01-01

    Cloud and radiation data from two distinctly different Arctic areas are analyzed to study the differences between coastal Alaskan and open Arctic Ocean region clouds and their respective influence on the surface radiation budget. The cloud and radiation datasets were obtained from (1) the DOE North Slope of Alaska (NSA) facility in the coastal town of Barrow, Alaska, and (2) the SHEBA field program, which was conducted from an icebreaker frozen in, and drifting with, the sea-ice for one year in the Western Arctic Ocean. Radar, lidar, radiometer, and sounding measurements from both locations were used to produce annual cycles of cloud occurrence and height, atmospheric temperature and humidity, surface longwave and shortwave broadband fluxes, surface albedo, and cloud radiative forcing. In general, both regions revealed a similar annual trend of cloud occurrence fraction with minimum values in winter (60-75%) and maximum values during spring, summer and fall (80-90%). However, the annual average cloud occurrence fraction for SHEBA (76%) was lower than the 6-year average cloud occurrence at NSA (92%). Both Arctic areas also showed similar annual cycle trends of cloud forcing with clouds warming the surface through most of the year and a period of surface cooling during the summer, when cloud shading effects overwhelm cloud greenhouse effects. The greatest difference between the two regions was observed in the magnitude of the cloud cooling effect (i.e., shortwave cloud forcing), which was significantly stronger at NSA and lasted for a longer period of time than at SHEBA. This is predominantly due to the longer and stronger melt season at NSA (i.e., albedo values that are much lower coupled with Sun angles that are somewhat higher) than the melt season observed over the ice pack at SHEBA. Longwave cloud forcing values were comparable between the two sites indicating a general similarity in cloudiness and atmospheric temperature and humidity structure between the two

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Significance of Multilayer Cloud Systems in Tropical Convection Download a printable PDF Submitter: Stephens, G. L., Colorado State University Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Stephens, GL, and NB Wood. 2007. "Properties of tropical convection observed by millimeter-wave radar systems." Monthly Weather Review 135: 821-842. Storm classifications (derived from k-means clustering analysis) applied to MWR

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Single-Scattering Properties of Aggregates of Bullet Rosettes in Cirrus Download a printable PDF Submitter: Um, J., University of Illinois, Urbana McFarquhar, G., University of Illinois, Urbana Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: Um, J, and GM McFarquhar. 2007. "Single-scattering properties of aggregates of bullet rosettes in cirrus." Journal of Applied Meteorology and Climatology 46, 757-775. Two images of idealized geometry

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structure of Cirrus Properties and Its Coupling with the State of the Large-Scale Atmosphere Download a printable PDF Submitter: Ivanova, K., Pennsylvania State University Ackerman, T. P., University of Washington Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Properties Journal Reference: Ivanova K and TP Ackerman. 2009. "Tracking nucleation-growth-sublimation in cirrus clouds using ARM millimeter wavelength radar observations." Journal of

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Single-Scattering Properties of Aggregates of Plates Download a printable PDF Submitter: Um, J., University of Illinois, Urbana McFarquhar, G., University of Illinois, Urbana Area of Research: Cloud Distributions/Characterizations Working Group(s): Radiative Processes Journal Reference: Um J and GM McFarquhar. 2009. "Single-scattering properties of aggregates of plates." Quarterly Journal Royal Meteorological Society, 135(639), 10.1002/qj.378. Aggregates of plates imaged by Cloud

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dependence of the Single-Scattering Properties of Small Ice Crystals on Idealized Shape Models Download a printable PDF Submitter: Um, J., University of Illinois, Urbana McFarquhar, G., University of Illinois, Urbana Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: Um J and GM McFarquhar. 2011. "Dependence of the single-scattering properties of small ice crystals on idealized shape

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Factors Influencing the Microphysics and Radiative Properties of Liquid-Dominated Arctic Clouds Download a printable PDF Submitter: Earle, M., Environment Canada Liu, P., Environment Canada Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Earle ME, PS Liu, JW Strapp, A Zelenyuk, D Imre, GM McFarquhar, NC Shantz, and WR Leaitch. 2011. "Factors influencing the microphysics and radiative properties of

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Influence of Observed Cirrus Microphysical Properties on Shortwave Radiation: a Case Study Download a printable PDF Submitter: McFarquhar, G., University of Illinois, Urbana Nousiainen, T. P., University of Helsinki Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: Mauno P, GM McFarquhar, T Nousiainen, M Timlin, M Kahnert, and P Raisanen. 2011. "The influence of cloud microphysical properties on shortwave radiation: A case study over Oklahoma."

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turn Trash Into Treasure: Continental Warm Cloud Properties Derived from Unexploited Solar Background Signals Download a printable PDF Submitter: Chiu, J., University of Reading Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: Chiu JC, JA Holmes, RJ Hogan, and EJ O'Connor. 2014. "The interdependence of continental warm cloud properties derived from unexploited solar background signals in

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Validation of Climate Model Ice Cloud Properties Download a printable PDF Submitter: Eidhammer, T., NCAR Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Eidhammer T, H Morrison, A Bansemer, A Gettelman, and AJ Heymsfield. 2014. "Comparison of ice cloud properties simulated by the Community Atmosphere Model (CAM5) with in situ observations." Atmospheric Chemistry and Physics, 14(18), doi:10.5194/acp-14-10103-2014. Mass weighted terminal fall

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Light Absorption of Primary Organic Aerosol Paper Named ACS Editors' Choice Download a printable PDF Submitter: Lu, Z., Argonne National Laboratory Streets, D. ., Argonne National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Lu Z, DG Streets, E Winijkul, F Yan, Y Chen, TC Bond, Y Feng, MK Dubey, S Liu, JP Pinto, and GR Carmichael. 2015. "Light absorption properties and radiative effects of primary organic aerosol emissions."

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterizing the Co-Existence of Water and Ice in Arctic Clouds Submitter: McFarquhar, G., University of Illinois, Urbana Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Greg M. McFarquhar and Stewart G. Cober. 2004: Single-Scattering Properties of Mixed-Phase Arctic Clouds at Solar Wavelengths: Impacts on Radiative Transfer. Journal of Climate: Vol. 17, No. 19, pp. 3799-3813. Analyses of in-cloud observations obtained during

  17. Surface oxygen exchange properties of Sr doped La2NiO4+δ as SOFC cathode: Thin-film electrical conductivity relaxation investigation

    SciTech Connect (OSTI)

    Guan, Bo; Li, Wenyuan; Zhang, Xinxin; Liu, Xingbo

    2015-06-02

    La2-xSrxNiO4+δ dense films are prepared by a novel spray-modified pressing method. The surface reaction kinetics is investigated via electrical conductivity relaxation (ECR). The layer thickness, 5~10 μm, is much less than the characteristic length of lanthanum nickelates, resulting in surface-controlled situation and allowing more accurate fitting than the traditional pellets ECR on the surface exchange coefficient (k). k for LNO is 1.6×10-5 cm/s in 0.2 atm at 700°C. Sr doping impairs the exchange kinetics, and k of Sr40 is about one order of magnitude smaller than undoped one. Interstitial oxygen and Ni oxidation state are suggested the predominant roles in determining surface kinetics. In conclusion, given the properties of the thin-film herein developed by spray-modified pressing is closer to those in practical porous electrode compared to pulsed laser deposited film in terms of preferential orientation and strain, it warrants the use of such a method in a variety of pertinent investigations.

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Validation of CERES-MODIS Cloud Properties Using ARM Data Submitter: Dong, X., University of Arizona Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Dong, X., P. Minnis, B. Xi, S. Sun-Mack, and Y. Chen, 2007: Validation of CERES-MODIS stratus cloud properties using ground-based measurements at the DOE ARM SGP site. Accepted by J. Geophys. Res. Wielicki, B. A. and Co-authors (2000), CERES Validation Plan Overview, Release 4, 10/20/00,

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MBL Cloud Properties Derived from the Azores-AMF Observations Submitter: Dong, X., University of Arizona Area of Research: Cloud Processes Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Dong X, B Xi, A Kennedy, P Minnis, and R Wood. 2014. "A 19-month record of marine aerosol-cloud-radiation properties derived from DOE ARM AMF deployment at the Azores: Part I: Cloud fraction and single-layered MBL cloud properties." Journal of Climate, 27(10),

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DCS Ice Cloud Microphysical Properties Derived from Aircraft Data During MC3E Submitter: Dong, X., University of Arizona Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Wang J, X Dong, and B Xi. 2015. "Investigation of ice cloud microphysical properties of DCSs using aircraft in situ measurements during MC3E over the ARM SGP site." Journal of Geophysical Research - Atmospheres, 120(8), 3533-3552. Figure 1. The observed PSDs at different aircraft

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Continuous Clear-Sky Longwave from Surface Measurements Download a printable PDF Submitter: Long, C. N., NOAA Global Monitoring Division/CIRES Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: Long, CN, and DD Turner. 2008. "A method for continuous estimation of clear-sky downwelling longwave radiative flux developed using ARM surface measurements." Journal of Geophysical

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Diurnal Cycle of Monsoon Clouds, Precipitation, and Surface Radiation Download a printable PDF Submitter: Long, C. N., NOAA Global Monitoring Division/CIRES May, P. T., Bureau of Meteorology Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: May PT, CN Long, and A Protat. 2012. "The diurnal cycle of the boundary layer, convection, clouds, and surface radiation in a coastal monsoon environment (Darwin

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Regime Analysis to Identify the Contribution of Clouds to Surface Temperature Errors in GCMs Submitter: Van Weverberg, K., Met Office Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Life Cycle Journal Reference: Van Weverberg K, CJ Morcrette, H Ma, SA Klein, and JC Petch. 2015. "Using regime analysis to identify the contribution of clouds to surface temperature errors in weather and climate models." Quarterly Journal Royal

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Earth Lightens Up Submitter: Long, C. N., NOAA Global Monitoring Division/CIRES Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: Wild, M., H. Gilgen, A. Roesch, A. Ohmura, C. N. Long, E. G. Dutton, B. Forgan, A. Kallis, V. Russak, and A. Tsvetkov, (2005): From dimming to brightening: Decadal changes in solar radiation at the Earth's surface, Science, 308, Issue 5723, 847-850, [DOI:10.1126/science.1103215] Global distribution of surface observation

  5. Intellectual Property Provisions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GNP-115 1 Intellectual Property Provisions (GNP-115) Grant and Cooperative Agreement Research, Development, or Demonstration Non-Federal Entity (State, Local government, Indian tribe, Institution of higher education, or Nonprofit organization) A Non-Federal Entity is subject to the intellectual property requirements at 2 CFR 200.315. 2 CFR 200.315 Intangible Property (a) Title to intangible property (see §200.59 Intangible property) acquired under a Federal award vests upon acquisition in the

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quantifying Error in the Radiative Forcing of the First Aerosol Indirect Effect Submitter: McComiskey, A. C., National Oceanic and Atmospheric Administration Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: Submitted to Geophysical Research Letters, 06-27-2007. Radiative forcing of aerosol indirect as function of CCN number density and LWP in units of W/m2 per 5% IE error. A survey of recently published works shows that values used to represent the magnitude of

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization of Atmospheric Aerosols Using MFRSR Measurements Download a printable PDF Submitter: Alexandrov, M. D., Columbia University Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: Alexandrov, MD, AA Lacis, BE Carlson, and B Cairns. 2007. "Characterization of atmospheric aerosols using MFRSR measurements." (Journal of Geophysical Research 113, DO8204. Sample spectral optical depths of atmospheric constituents in 300 - 900 nm spectral range:

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Wide Angle Imaging Lidar: Active Optical Sensor Technology for Ground-Based Probing of Dense Clouds Download a printable PDF Submitter: Davis, A. B., Jet Propulsion Laboratory Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Davis, AB. 2008. "Multiple-scattering lidar from both sides of the clouds: Addressing internal structure." Journal of Geophysical Research 113, D14S10, doi:10.1029/2007JD009666. Figure 1. Lidar

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Threshold Radar Reflectivity Separating Precipitating from Non-Precipitating Clouds Download a printable PDF Submitter: Liu, Y., Brookhaven National Laboratory Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Liu, Y, B Geerts, PH Daum, R McGraw, and M Miller. 2008. "Threshold radar reflectivity for drizzling clouds." Geophysical Research Letters 35, L03807, doi:10.1029/2007GL031201. Figure 1 shows the comparison of the

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud-Radiation Effects on Sea Ice Loss Download a printable PDF Submitter: Stephens, G. L., Colorado State University Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Kay, JE, T L'Ecuyer, A Gettelman, G Stephens, and C O'Dell. "The contribution of cloud and radiation anomalies to the 2007 Arctic sea ice extent minimum." To appear in Geophysical Research Letters. Clouds and downwelling radiation 2007-2006 differences (June

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Small Ice Crystals on Ice Sedimentation Rates in Cirrus Clouds and GCM Simulations Download a printable PDF Submitter: Mitchell, D. L., Desert Research Institute Rasch, P., Pacific Northwest National Laboratory Ivanova, D., Embry-Riddle Aeronautical University McFarquhar, G., University of Illinois, Urbana Nousiainen, T. P., University of Helsinki Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Properties Journal Reference: Mitchell, DL, P

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Arctic Aerosol Study Flies By Download a printable PDF Submitter: Schmid, B., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: ARM Climate Research Facility Operations Update, April 30, 2008, Edition Preliminary screening and analysis of images from the time-resolved aerosol collector indicate particles laden with carbon and sulfur. These data were obtained on April 8, 2008. Image courtesy of Alexander Laskin, PNNL. Images

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Surprisingly Large Contribution of Small Marine Clouds to Cloud Fraction and Reflectance Download a printable PDF Submitter: Oreopoulos, L., NASA Feingold, G., NOAA - Earth System Research Laboratory Koren, I., Weizmann Institute of Science Remer, L., NASA - GSFC, Laboratory for Atmospheres Area of Research: Clouds with Low Optical [Water] Depths (CLOWD) Working Group(s): Cloud Properties Journal Reference: Koren, I, L Oreopoulos, G Feingold, LA Remer, and O Altaratz. 2008. "How small

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Aerosol Measurements on Cloudy Days: a New Method Download a printable PDF Submitter: Kassianov, E., Pacific Northwest National Laboratory Ovchinnikov, M., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: Kassianov, EI, and M Ovtchinnikov. 2008. "On reflectance ratios and aerosol optical depth retrieval in the presence of cumulus clouds." Geophysical Research Letters doi:10.1029/2008GL033231.

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thin Is In Download a printable PDF Submitter: Tomlinson, J., Pacific Northwest National Laboratory Long, C. N., NOAA Global Monitoring Division/CIRES Comstock, J. M., Pacific Northwest National Laboratory Ronfeld, D., Pacific Northwest National Laboratory Area of Research: Radiation Processes Working Group(s): Cloud Properties Journal Reference: N/A The Twin Otter takes off to test the onboard instruments for the RACORO field campaign that began in January 2009. Researchers are gathering data

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Method for Retrieving Cloud Heights from Satellite Data Download a printable PDF Submitter: Chang, F., Science Systems and Applications, Inc. Minnis, P., NASA - Langley Research Center Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Chang F, P Minnis, B Lin, MM Khaiyer, R Palikonda, and DA Spangenberg. 2010. "A modified method for inferring cloud top height using GOES-12 imager 10.7- and 13.3-µm data." Journal of

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hemispherical Simulations Show Impact of Aerosols on Cloud Reflectivity Submitter: Rotstayn, L., Commonwealth Scientific and Industrial Research Organization Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: Rotstayn, L., and Y. Liu, Sensitivity of the First Indirect Aerosol Effect to an Increase in Cloud Droplet Spectral Dispersion with Droplet Number Concentration, Journal of Climate: Vol. 16, No. 21, pp.3476-3481, May 2003. Figure 1. Measurements of the

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Overambitious Other Carbon Submitter: Church, J., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Song C, M Gyawali, RA Zaveri, JE Shilling, and WP Arnott. 2013. "Light absorption by secondary organic aerosol from α-pinene: Effects of oxidants, seed aerosol acidity, and relative humidity." Journal of Geophysical Research - Atmospheres, 118, doi:10.1002/jgrd.50767. Time-dependent Mass Absorption

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gas-Phase Dry Deposition as a Major Removal Mechanism for Secondary Organic Aerosols (SOA) Download a printable PDF Submitter: Hodzic, A., NCAR Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Hodzic A, B Aumont, C Knote, J Lee-Taylor, S Madronich, and G Tyndall. 2014. "Volatility dependence of Henry's law constants of condensable organics: Application to estimate depositional loss of secondary organic aerosols." Geophysical Research Letters,

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bell-Shaped Curve Captures Cloud System Variability Submitter: Lamb, P. J., University of Oklahoma Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Journal of Geophysical Research, 110, D18205, doi:10.1029/2005JD006158. Figure 1. Reflectivity standard deviation PDFs, resampled as a function of timescale and contoured by equal values of probability, show an increase in variability with scale. The PDF modes lie mostly along the mean

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Checking Up on Tropical Sunlight Download a printable PDF Submitter: Riihimaki, L., Pacific Northwest National Laboratory Long, C. N., NOAA Global Monitoring Division/CIRES Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: Riihimaki LD and CN Long. 2014. "Spatial variability of surface irradiance measurements at the Manus ARM site." Journal of Geophysical Research - Atmospheres, 119(9), 5475-5491. ACCEPTED. The radiometer system used at the

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quantifying the Importance of Cold Pool Mechanisms for Convection Triggering Download a printable PDF Submitter: Kuang, Z., Harvard University Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Torri G, Z Kuang, and Y Tian. 2015. "Mechanisms for convection triggering by cold pools." Geophysical Research Letters, , . ACCEPTED. Horizontal sections of (left) potential temperature and (right) water vapor specific humidity at 25 m from the model surface.

  3. New Energy Technologies | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Read More GE Scientists Demonstrate Promising Anti-icing Nano Surfaces GE Global Research today presented new research findings on its nanotextured anti-icing surfaces. In ...

  4. ARM - Measurement - Surface albedo

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    albedo ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Surface albedo The fraction of incoming solar radiation at a surface (i.e. land, cloud top) that is effectively reflected by that surface. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of

  5. Solid Electrolyte/Electrode Interfaces: Atomistic Behavior Analyzed Via UHV-AFM, Surface Spectroscopies, and Computer Simulations Computational and Experimental Studies of the Cathode/Electrolyte Interface in Oxide Thin Film Batteries

    SciTech Connect (OSTI)

    Garofalini, Stephen H

    2012-03-21

    The goals of the research were to understand the structural, dynamic, and chemical properties of solid electrolyte surfaces and the cathode/electrolyte interface at an atomistic and nanometer level using both computational and experimental techniques.

  6. CARMA SURVEY TOWARD INFRARED-BRIGHT NEARBY GALAXIES (STING). III. THE DEPENDENCE OF ATOMIC AND MOLECULAR GAS SURFACE DENSITIES ON GALAXY PROPERTIES

    SciTech Connect (OSTI)

    Wong, Tony; Xue, Rui; Bolatto, Alberto D.; Fisher, David B.; Vogel, Stuart N.; Leroy, Adam K.; Blitz, Leo; Rosolowsky, Erik; Bigiel, Frank; Ott, Jrgen; Rahman, Nurur; Walter, Fabian

    2013-11-01

    We investigate the correlation between CO and H I emission in 18 nearby galaxies from the CARMA Survey Toward IR-Bright Nearby Galaxies (STING) at sub-kpc and kpc scales. Our sample, spanning a wide range in stellar mass and metallicity, reveals evidence for a metallicity dependence of the H I column density measured in regions exhibiting CO emission. Such a dependence is predicted by the equilibrium model of McKee and Krumholz, which balances H{sub 2} formation and dissociation. The observed H I column density is often smaller than predicted by the model, an effect we attribute to unresolved clumping, although values close to the model prediction are also seen. We do not observe H I column densities much larger than predicted, as might be expected were there a diffuse H I component that did not contribute to H{sub 2} shielding. We also find that the H{sub 2} column density inferred from CO correlates strongly with the stellar surface density, suggesting that the local supply of molecular gas is tightly regulated by the stellar disk.

  7. NREL: Solar Radiation Research - Solar Radiation Research Laboratory...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Radiation Research Laboratory Photographs The Solar Radiation Research Laboratory (SRRL) houses more than 70 instruments to analyze and record solar radiation and surface ...

  8. Mechanical properties and tribological behavior of contaminate...

    Office of Scientific and Technical Information (OSTI)

    nanoparticles on micromachined surfaces. Citation Details In-Document Search Title: Mechanical properties and tribological behavior of contaminate nanoparticles on ...

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Observations of Microphysical Properties of Single-Layer Stratocumulus During the Mixed-Phase Arctic Cloud Experiment Submitter: McFarquhar, G., University of Illinois, Urbana Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Fridlind, A.M., A.S. Ackerman, G.M. McFarquhar, G. Zhang, M.R. Poellot, P.J. DeMott, A.J. Prenni and A.J. Heymsfield, 2007: Ice properties of single-layer stratocumulus during the

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Encountering a Longstanding Cloud Physics Question in the Arctic: How Is Ice Formed in Moderately Supercooled Clouds? Submitter: Fridlind, A. M., NASA - Goddard Institute for Space Studies Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Modeling, Cloud Properties Journal Reference: Fridlind, A.M., A.S. Ackerman, G.M. McFarquhar, G. Zhang, M.R. Poellot, P.J. DeMott, A.J. Prenni and A.J. Heymsfield, 2007: Ice properties of single-layer stratocumulus during the