National Library of Energy BETA

Sample records for research surface properties

  1. Controlling Surface Properties of Transparent Conducting Oxides | ANSER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center | Argonne-Northwestern National Laboratory Controlling Surface Properties of Transparent Conducting Oxides Home > Research > ANSER Research Highlights > Controlling Surface Properties of Transparent Conducting Oxides

  2. Enhancement of surface properties for coal beneficiation

    SciTech Connect (OSTI)

    Chander, S.; Aplan, F.F.

    1992-01-30

    This report will focus on means of pyrite removal from coal using surface-based coal cleaning technologies. The major subjects being addressed in this study are the natural and modulated surface properties of coal and pyrite and how they may best be utilized to facilitate their separation using advanced surface-based coal cleaning technology. Emphasis is based on modified flotation and oil agglomerative processes and the basic principles involved. The four areas being addressed are: (1) Collectorless flotation of pyrite; (2) Modulation of pyrite and coal hydrophobicity; (3) Emulsion processes and principles; (4) Evaluation of coal hydrophobicity.

  3. [Plasma properties research: Task 3

    SciTech Connect (OSTI)

    Not Available

    1992-01-01

    The principal research activities of the Magneto-Fluid Dynamics Division relate to magnetic fusion plasma physics. In addition, there is a modest amount of work in closely related areas, including space plasma physics, fluid dynamics, and dynamical systems. Members of the Magneto-Fluid Dynamics Division maintain close contacts with fusion researchers in the US and abroad. Some of the work of the Division is clearly directed towards ITER and TPX, while other problems relate to the broader development of fusion plasma physics and to the support of other issues arising in the many experimental programs. Topics of some note in the last year that are discussed in this report are: Application of sophisticated statistical techniques to tokamak data reduction, including time series analysis of TFTR fluctuation data and spline analysis of profile data. Continuing development of edge plasma and divertor modelling, including initial ergodic divertor studies. Analysis of energetic fusion products losses from TFTR plasmas. Examination of anomalous transport in dynamical systems induced by chaotic-like Hamiltonian motion. Numerical simulation of the development of singular MHD equilibria. Exploration of the validity of moment expansions of kinetic equations for weakly collisional systems. Studies of RF- and ripple-induced helium ash removal. Ballooning mode studies in fluids and rotating stars. Studies in dynamical systems, including explosive instabilities, development of chaos, and motion of collisionless particles in a domain with overlapping islands.

  4. [Plasma properties research: Task 3

    SciTech Connect (OSTI)

    Not Available

    1992-12-31

    The principal research activities of the Magneto-Fluid Dynamics Division relate to magnetic fusion plasma physics. In addition, there is a modest amount of work in closely related areas, including space plasma physics, fluid dynamics, and dynamical systems. Members of the Magneto-Fluid Dynamics Division maintain close contacts with fusion researchers in the US and abroad. Some of the work of the Division is clearly directed towards ITER and TPX, while other problems relate to the broader development of fusion plasma physics and to the support of other issues arising in the many experimental programs. Topics of some note in the last year that are discussed in this report are: Application of sophisticated statistical techniques to tokamak data reduction, including time series analysis of TFTR fluctuation data and spline analysis of profile data. Continuing development of edge plasma and divertor modelling, including initial ergodic divertor studies. Analysis of energetic fusion products losses from TFTR plasmas. Examination of anomalous transport in dynamical systems induced by chaotic-like Hamiltonian motion. Numerical simulation of the development of singular MHD equilibria. Exploration of the validity of moment expansions of kinetic equations for weakly collisional systems. Studies of RF- and ripple-induced helium ash removal. Ballooning mode studies in fluids and rotating stars. Studies in dynamical systems, including explosive instabilities, development of chaos, and motion of collisionless particles in a domain with overlapping islands.

  5. Seventh BES (Basic Energy Sciences) catalysis and surface chemistry research conference

    SciTech Connect (OSTI)

    Not Available

    1990-03-01

    Research programs on catalysis and surface chemistry are presented. A total of fifty-seven topics are included. Areas of research include heterogeneous catalysis; catalysis in hydrogenation, desulfurization, gasification, and redox reactions; studies of surface properties and surface active sites; catalyst supports; chemical activation, deactivation; selectivity, chemical preparation; molecular structure studies; sorption and dissociation. Individual projects are processed separately for the data bases. (CBS)

  6. Sink property of metallic glass free surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shao, Lin; Fu, Engang; Price, Lloyd; Chen, Di; Chen, Tianyi; Wang, Yongqiang; Xie, Guoqiang; Lucca, Don A.

    2015-03-16

    When heated to a temperature close to glass transition temperature, metallic glasses (MGs) begin to crystallize. Under deformation or particle irradiation, crystallization occurs at even lower temperatures. Hence, phase instability represents an application limit for MGs. Here, we report that MG membranes of a few nanometers thickness exhibit properties different from their bulk MG counterparts. The study uses in situ transmission electron microscopy with concurrent heavy ion irradiation and annealing to observe crystallization behaviors of MGs. For relatively thick membranes, ion irradiations introduce excessive free volumes and thus induce nanocrystal formation at a temperature linearly decreasing with increasing ion fluences.more » For ultra-thin membranes, however, the critical temperature to initiate crystallization is about 100 K higher than the bulk glass transition temperature. Molecular dynamics simulations indicate that this effect is due to the sink property of the surfaces which can effectively remove excessive free volumes. These findings suggest that nanostructured MGs having a higher surface to volume ratio are expected to have higher crystallization resistance, which could pave new paths for materials applications in harsh environments requiring higher stabilities.« less

  7. Sink property of metallic glass free surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shao, Lin; Fu, Engang; Price, Lloyd; Chen, Di; Chen, Tianyi; Wang, Yongqiang; Xie, Guoqiang; Lucca, Don A.

    2015-03-16

    When heated to a temperature close to glass transition temperature, metallic glasses (MGs) begin to crystallize. Under deformation or particle irradiation, crystallization occurs at even lower temperatures. Hence, phase instability represents an application limit for MGs. Here, we report that MG membranes of a few nanometers thickness exhibit properties different from their bulk MG counterparts. The study uses in situ transmission electron microscopy with concurrent heavy ion irradiation and annealing to observe crystallization behaviors of MGs. For relatively thick membranes, ion irradiations introduce excessive free volumes and thus induce nanocrystal formation at a temperature linearly decreasing with increasing ion fluences.moreFor ultra-thin membranes, however, the critical temperature to initiate crystallization is about 100 K higher than the bulk glass transition temperature. Molecular dynamics simulations indicate that this effect is due to the sink property of the surfaces which can effectively remove excessive free volumes. These findings suggest that nanostructured MGs having a higher surface to volume ratio are expected to have higher crystallization resistance, which could pave new paths for materials applications in harsh environments requiring higher stabilities.less

  8. Sink property of metallic glass free surfaces

    SciTech Connect (OSTI)

    Shao, Lin; Fu, Engang; Price, Lloyd; Chen, Di; Chen, Tianyi; Wang, Yongqiang; Xie, Guoqiang; Lucca, Don A.

    2015-03-16

    When heated to a temperature close to glass transition temperature, metallic glasses (MGs) begin to crystallize. Under deformation or particle irradiation, crystallization occurs at even lower temperatures. Hence, phase instability represents an application limit for MGs. Here, we report that MG membranes of a few nanometers thickness exhibit properties different from their bulk MG counterparts. The study uses in situ transmission electron microscopy with concurrent heavy ion irradiation and annealing to observe crystallization behaviors of MGs. For relatively thick membranes, ion irradiations introduce excessive free volumes and thus induce nanocrystal formation at a temperature linearly decreasing with increasing ion fluences. For ultra-thin membranes, however, the critical temperature to initiate crystallization is about 100 K higher than the bulk glass transition temperature. Molecular dynamics simulations indicate that this effect is due to the sink property of the surfaces which can effectively remove excessive free volumes. These findings suggest that nanostructured MGs having a higher surface to volume ratio are expected to have higher crystallization resistance, which could pave new paths for materials applications in harsh environments requiring higher stabilities.

  9. Surface property detection apparatus and method

    DOE Patents [OSTI]

    Martens, Jon S. (Albuquerque, NM); Ginley, David S. (Evergreen, CO); Hietala, Vincent M. (Placitas, NM); Sorensen, Neil R. (Albuquerque, NM)

    1995-01-01

    Apparatus and method for detecting, determining, and imaging surface resistance corrosion, thin film growth, and oxide formation on the surface of conductors or other electrical surface modification. The invention comprises a modified confocal resonator structure with the sample remote from the radiating mirror. Surface resistance is determined by analyzing and imaging reflected microwaves; imaging reveals anomalies due to surface impurities, non-stoichiometry, and the like, in the surface of the superconductor, conductor, dielectric, or semiconductor.

  10. Surface property detection apparatus and method

    DOE Patents [OSTI]

    Martens, J.S.; Ginley, D.S.; Hietala, V.M.; Sorensen, N.R.

    1995-08-08

    Apparatus and method for detecting, determining, and imaging surface resistance corrosion, thin film growth, and oxide formation on the surface of conductors or other electrical surface modification. The invention comprises a modified confocal resonator structure with the sample remote from the radiating mirror. Surface resistance is determined by analyzing and imaging reflected microwaves; imaging reveals anomalies due to surface impurities, non-stoichiometry, and the like, in the surface of the superconductor, conductor, dielectric, or semiconductor. 4 figs.

  11. Los Alamos researchers uncover new properties in nanocomposite...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New properties in nanocomposite oxide ceramics Los Alamos researchers uncover new properties in nanocomposite oxide ceramics for reactor fuel, fast-ion conductors In a...

  12. Surface Contamination Guidelines/Radiological Clearance of Property |

    Energy Savers [EERE]

    Department of Energy Surface Contamination Guidelines/Radiological Clearance of Property Surface Contamination Guidelines/Radiological Clearance of Property Authorized limits govern the control and clearance of personal and real property. They are radionuclide concentrations or activity levels approved by DOE to permit the clearance of property from DOE radiological control for either restricted or unrestricted use, consistent with DOE's radiation protection framework and standards for the

  13. Intellectual Property Provisions (GLB-115) Grant Research, Development...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GLB-115) Grant Research, Development, or Demonstration Large Business and Foreign Entity Intellectual Property Provisions (GLB-115) Grant Research, Development, or Demonstration...

  14. Intellectual Property Provisions (GSB-115) Grant Research, Development...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GSB-115) Grant Research, Development, or Demonstration Domestic Small Business Intellectual Property Provisions (GSB-115) Grant Research, Development, or Demonstration Domestic...

  15. Modification of surface properties of copper-refractory metal alloys

    DOE Patents [OSTI]

    Verhoeven, John D. (Ames, IA); Gibson, Edwin D. (Ames, IA)

    1993-10-12

    The surface properties of copper-refractory metal (CU-RF) alloy bodies are modified by heat treatments which cause the refractory metal to form a coating on the exterior surfaces of the alloy body. The alloys have a copper matrix with particles or dendrites of the refractory metal dispersed therein, which may be niobium, vanadium, tantalum, chromium, molybdenum, or tungsten. The surface properties of the bodies are changed from those of copper to that of the refractory metal.

  16. Method for determining surface properties of microparticles

    DOE Patents [OSTI]

    Eisenthal, Kenneth B. (Ridgewood, NJ)

    2000-01-01

    Second harmonic generation (SHG), sum frequency generation (SFG) and difference frequency generation (DFG) can be used for surface analysis or characterization of microparticles having a non-metallic surface feature. The microparticles can be centrosymmetric or such that non-metallic molecules of interest are centrosymmetrically distributed inside and outside the microparticles but not at the surface of the microparticles where the asymmetry aligns the molecules. The signal is quadratic in incident laser intensity or proportional to the product of two incident laser intensities for SFG, it is sharply peaked at the second harmonic wavelength, quadratic in the density of molecules adsorbed onto the microparticle surface, and linear in microparticles density. In medical or pharmacological applications, molecules of interest may be of drugs or toxins, for example.

  17. Intellectual Property Provisions (CSB-115) Cooperative Agreement Research,

    Energy Savers [EERE]

    Development, or Demonstration Domestic Small Business | Department of Energy 15) Cooperative Agreement Research, Development, or Demonstration Domestic Small Business Intellectual Property Provisions (CSB-115) Cooperative Agreement Research, Development, or Demonstration Domestic Small Business PDF icon CSB-115.pdf More Documents & Publications Intellectual Property Provisions (CSB-1003) Cooperative Agreement Research, Development, or Demonstration Domestic Small Businesses Intellectual

  18. Nanotextured Anti-Icing Surfaces | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Demonstrate Promising Anti-icing Nano Surfaces Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) Click to share on LinkedIn (Opens in new window) Click to share on Tumblr (Opens in new window) GE Scientists Demonstrate Promising Anti-icing Nano Surfaces GE Global Research today presented new research findings on its nanotextured anti-icing surfaces. In addition to dramatically reducing ice adhesion, these surfaces

  19. Intellectual Property Provisions (GSB-115) Grant Research, Development, or

    Energy Savers [EERE]

    Demonstration Domestic Small Business | Department of Energy GSB-115) Grant Research, Development, or Demonstration Domestic Small Business Intellectual Property Provisions (GSB-115) Grant Research, Development, or Demonstration Domestic Small Business PDF icon GSB-115.pdf More Documents & Publications GSB-1003.PDF� Intellectual Property Provisions (CLB-115) Cooperative Agreement Research, Development, or Demonstration Large Business and Foreign Entity Intellectual Property

  20. Nanoscale Material Properties | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanotechnology Drives New Levels of Performance Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) Click to share on LinkedIn (Opens in new window) Click to share on Tumblr (Opens in new window) Nanotechnology Drives New Levels of Performance GE scientists are discovering new material properties at the nanoscale that drive new performance levels in jet engines, gas and steam turbines, electronic devices and disease

  1. Enhancement of surface properties for coal beneficiation. Final report

    SciTech Connect (OSTI)

    Chander, S.; Aplan, F.F.

    1992-01-30

    This report will focus on means of pyrite removal from coal using surface-based coal cleaning technologies. The major subjects being addressed in this study are the natural and modulated surface properties of coal and pyrite and how they may best be utilized to facilitate their separation using advanced surface-based coal cleaning technology. Emphasis is based on modified flotation and oil agglomerative processes and the basic principles involved. The four areas being addressed are: (1) Collectorless flotation of pyrite; (2) Modulation of pyrite and coal hydrophobicity; (3) Emulsion processes and principles; (4) Evaluation of coal hydrophobicity.

  2. Intellectual Property Provisions (CLB-115) Cooperative Agreement Research,

    Energy Savers [EERE]

    Development, or Demonstration Large Business and Foreign Entity | Department of Energy CLB-115) Cooperative Agreement Research, Development, or Demonstration Large Business and Foreign Entity Intellectual Property Provisions (CLB-115) Cooperative Agreement Research, Development, or Demonstration Large Business and Foreign Entity PDF icon CLB-115.pdf More Documents & Publications CLB-1003.PDF� CDLB-1003.PDF� Intellectual Property Provisions (CDLB-115) Cooperative Agreement -

  3. Los Alamos researchers uncover new properties in nanocomposite oxide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ceramics for reactor fuel, fast-ion conductors Los Alamos researchers uncover new properties in nanocomposite oxide ceramics for reactor fuel, fast-ion conductors Alumni Link: Opportunities, News and Resources for Former Employees Latest Issue:September 2015 all issues All Issues » submit Los Alamos researchers uncover new properties in nanocomposite oxide ceramics for reactor fuel, fast-ion conductors In a nanocomposite, the size of each of these grains is on the order of nanometers,

  4. Intellectual Property Provisions (GLB-115) Grant Research, Development, or

    Energy Savers [EERE]

    Demonstration Large Business and Foreign Entity | Department of Energy GLB-115) Grant Research, Development, or Demonstration Large Business and Foreign Entity Intellectual Property Provisions (GLB-115) Grant Research, Development, or Demonstration Large Business and Foreign Entity PDF icon GLB-115.pdf More Documents & Publications GLB-1003.PDF� CLB-1003.PDF� CDLB

  5. Determining the research needs of the surface coal mining industry

    SciTech Connect (OSTI)

    Zell, L.M.

    1982-12-01

    This paper reveals avenues open to the coal industry to help gain technology and research information needed to meet the requirements of the Surface Mining Control and Reclamation Act of 1977. It discusses projects of the Department of Energy's (DOE) Office of Coal Mining and the Mining and Reclamation Council of America (MARC) to help meet the environmental needs as well as the coal industry needs.

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chinese Researchers Report Reliable Method for Monitoring Soil Moisture Submitter: Bhattacharya, A., Pacific Northwest National Laboratory Area of Research: Surface Properties...

  7. Koel applies science of surface chemistry to fusion research at PPPL |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Princeton Plasma Physics Lab Koel applies science of surface chemistry to fusion research at PPPL By Catherine Zandonella March 26, 2012 Tweet Widget Google Plus One Share on Facebook To study the interactions of lithium under conditions similar to what might be found in a fusion reactor, lithium on a sample of TZM molybdenum, which is an alloy of molybdenum, titanium, zirconium and carbon known for its high strength and temperature properties, is heated inside an ultrahigh vacuum chamber

  8. Surface chemistry and bonding configuration of ultrananocrystalline diamond surfaces and their effects on nanotribological properties

    SciTech Connect (OSTI)

    Sumant, A. V.; Grierson, D. S.; Carpick, R. W.; Gerbi, J. E.; Carlisle, J. A.; Auciello, O.

    2007-12-15

    We present a comprehensive study of surface composition and nanotribology for ultrananocrystalline diamond (UNCD) surfaces, including the influence of film nucleation on these properties. We describe a methodology to characterize the underside of the films as revealed by sacrificial etching of the underlying substrate. This enables the study of the morphology and composition resulting from the nucleation and initial growth of the films, as well as the characterization of nanotribological properties which are relevant for applications including micro-/nanoelectromechanical systems. We study the surface chemistry, bonding configuration, and nanotribological properties of both the topside and the underside of the film with synchrotron-based x-ray absorption near-edge structure spectroscopy to identify the bonding state of the carbon atoms, x-ray photoelectron spectroscopy to determine the surface chemical composition, Auger electron spectroscopy to further verify the composition and bonding configuration, and quantitative atomic force microscopy to study the nanoscale topography and nanotribological properties. The films were grown on SiO{sub 2} after mechanically polishing the surface with detonation synthesized nanodiamond powder, followed by ultrasonication in a methanol solution containing additional nanodiamond powder. The sp{sup 2} fraction, morphology, and chemistry of the as-etched underside are distinct from the topside, exhibiting a higher sp{sup 2} fraction, some oxidized carbon, and a smoother morphology. The nanoscale single-asperity work of adhesion between a diamond nanotip and the as-etched UNCD underside is far lower than for a silicon-silicon interface (59.2{+-}2 vs 826{+-}186 mJ/m{sup 2}, respectively). Exposure to atomic hydrogen dramatically reduces nanoscale adhesion to 10.2{+-}0.4 mJ/m{sup 2}, at the level of van der Waals' interactions and consistent with recent ab initio calculations. Friction is substantially reduced as well, demonstrating a direct link between the surface chemistry and nanoscale friction. The proposed mechanism, supported by the detailed surface spectroscopic analysis, is the elimination of reactive (e.g., C*-), polar (e.g., C=O), and {pi}-bonded (C=C) surface groups, which are replaced by fully saturated, hydrogen-terminated surface bonds to produce an inert surface that interacts minimally with the contacting counterface.

  9. Surface chemistry and bonding configuration of ultrananocrystalline diamond surfaces and their effects on nanotribological properties.

    SciTech Connect (OSTI)

    Sumant, A. V.; Grierson, D. S.; Gerbi, J. E.; Carlisle, J. A.; Auciello, O.; Carpick, R. W.; Univ. of Wisconsin at Madison

    2007-12-01

    We present a comprehensive study of surface composition and nanotribology for ultrananocrystalline diamond (UNCD) surfaces, including the influence of film nucleation on these properties. We describe a methodology to characterize the underside of the films as revealed by sacrificial etching of the underlying substrate. This enables the study of the morphology and composition resulting from the nucleation and initial growth of the films, as well as the characterization of nanotribological properties which are relevant for applications including micro-/nanoelectromechanical systems. We study the surface chemistry, bonding configuration, and nanotribological properties of both the topside and the underside of the film with synchrotron-based x-ray absorption near-edge structure spectroscopy to identify the bonding state of the carbon atoms, x-ray photoelectron spectroscopy to determine the surface chemical composition, Auger electron spectroscopy to further verify the composition and bonding configuration, and quantitative atomic force microscopy to study the nanoscale topography and nanotribological properties. The films were grown on SiO{sub 2} after mechanically polishing the surface with detonation synthesized nanodiamond powder, followed by ultrasonication in a methanol solution containing additional nanodiamond powder. The sp{sup 2} fraction, morphology, and chemistry of the as-etched underside are distinct from the topside, exhibiting a higher sp{sup 2} fraction, some oxidized carbon, and a smoother morphology. The nanoscale single-asperity work of adhesion between a diamond nanotip and the as-etched UNCD underside is far lower than for a silicon-silicon interface (59.2 {+-} 2 vs 826 {+-} 186 mJ/m{sup 2}, respectively). Exposure to atomic hydrogen dramatically reduces nanoscale adhesion to 10.2 {+-} 0.4 mJ/m{sup 2}, at the level of van der Waals interactions and consistent with recent ab initio calculations. Friction is substantially reduced as well, demonstrating a direct link between the surface chemistry and nanoscale friction. The proposed mechanism, supported by the detailed surface spectroscopic analysis, is the elimination of reactive (e.g., C*-), polar (e.g., C-O), and {pi}-bonded (C-C) surface groups, which are replaced by fully saturated, hydrogen-terminated surface bonds to produce an inert surface that interacts minimally with the contacting counterface.

  10. Intellectual Property Provisions (CSB-1003) Cooperative Agreement Research,

    Energy Savers [EERE]

    Development, or Demonstration Domestic Small Businesses | Department of Energy 003) Cooperative Agreement Research, Development, or Demonstration Domestic Small Businesses Intellectual Property Provisions (CSB-1003) Cooperative Agreement Research, Development, or Demonstration Domestic Small Businesses 01. FAR 52.227-1 Authorization and Consent (JUL 1995)-Alternate I (APR 1984) 02. FAR 52.227-2 Notice and Assistance Regarding Patent and Copyright Infringement (AUG 1996) This clause is not

  11. The Role of Surface Chemistry and Bulk Properties on the Cycling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Role of Surface Chemistry and Bulk Properties on the Cycling and Rate Capability of Lithium Positive Electrode Materials The Role of Surface Chemistry on the Cycling and ...

  12. Charging properties of cassiterite (alfa-SnO2) surfaces

    SciTech Connect (OSTI)

    Rosenqvist, Jorgen K; Machesky, Michael L.; Vlcek, L.; Cummings, Peter T; Wesolowski, David J

    2009-01-01

    The acid-base properties of cassiterite (alfa-SnO2) surfaces at 10 50 C were studied using potentiometric titrations of powder suspensions in aqueous NaCl and RbCl media. The proton sorption isotherms exhibited common intersection points in the pH-range 4.0 to 4.5 at all conditions and the magnitude of charging was similar but not identical in NaCl and RbCl. The hydrogen bonding configuration at the oxide-water interface, obtained from classical Molecular Dynamics (MD) simulations, was analyzed in detail and the results were explicitly incorporated in calculations of protonation constants for the reactive surface sites using the revised MUSIC model. The calculations indicated that the terminal SnOH2 group is more acidic than the bridging Sn2OH group, with protonation constants (log KH) of 3.60 and 5.13 at 25 C, respectively. This is contrary to the situation on the isostructural alfa-TiO2 (rutile), apparently due to the difference in electronegativity between Ti and Sn. MD simulations and speciation calculations indicated considerable differences in the speciation of Na+ and Rb+, despite the similarities in overall charging. Adsorbed sodium ions are almost exclusively found in bidentate surface complexes, while adsorbed rubidium ions form comparable amounts of bidentate and tetradentate complexes. Also, the distribution of adsorbed Na+ between the different complexes shows a considerable dependence on surface charge density (pH), while the distribution of adsorbed Rb+ is almost independent of pH. A Surface Complexation Model (SCM) capable of accurately describing both the measured surface charge and the MD predicted speciation of adsorbed Na+/Rb+ was formulated. According to the SCM, the deprotonated terminal group (SnOH-0.40) and the protonated bridging group (Sn2OH+0.36) dominate the surface speciation over the entire pH-range (2.7 10), illustrating the ability of positively and negatively charged surface groups to coexist. Complexation of the medium cations increases significantly with increasing negative surface charge and at pH 10 roughly 40 percent of the terminal sites are predicted to form cation complexes, while anion complexation is minor throughout the studied pH-range.

  13. Los Alamos researchers uncover new properties in nanocomposite oxide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ceramics for reactor fuel, fast-ion conductors New properties in nanocomposite oxide ceramics Los Alamos researchers uncover new properties in nanocomposite oxide ceramics for reactor fuel, fast-ion conductors In a nanocomposite, the size of each of these grains is on the order of nanometers, roughly 1000 times smaller than the width of a human hair. September 23, 2014 Schematic depicting distinct dislocation networks for SrO- and TiO2-terminated SrTiO3/MgO interface. Schematic depicting

  14. Plasma-Surface Interaction Research At The Cambridge Laboratory Of Accelerator Studies Of Surfaces

    SciTech Connect (OSTI)

    Wright, G. M.; Barnard, H. S.; Hartwig, Z. S.; Stahle, P. W.; Sullivan, R. M.; Woller, K. B.; Whyte, D. G.

    2011-06-01

    The material requirements for plasma-facing components in a nuclear fusion reactor are some of the strictest and most challenging facing us today. These materials are simultaneously exposed to extreme heat loads (20 MW/m{sup 2} steady-state, 1 GW/m{sup 2} in millisecond transients) and particle fluxes (>10{sup 24} m{sup -2} s{sup -1}) while also undergoing high neutron irradiation (10{sup 18} neutrons/m{sup 2} s). At the Cambridge Laboratory of Accelerator Studies of Surfaces (CLASS), many of the most important issues in plasma-surface interaction research, such as plasma-driven material erosion and deposition, material transport and irradiation and hydrogenic retention are investigated with the use of a 1.7 MV tandem ion accelerator. Ion-Beam Analysis (IBA) is used to investigate and quantify changes in materials due to plasma exposure and ion irradiation is used as a proxy for neutron irradiation to investigate plasma-surface interactions for irradiated materials. This report will outline the capabilities and current research activities at CLASS.

  15. Studies of the viscoelastic properties of water confined between surfaces of specified chemical nature.

    SciTech Connect (OSTI)

    Houston, Jack E.; Grest, Gary Stephen; Moore, Nathan W.; Feibelman, Peter J.

    2010-09-01

    This report summarizes the work completed under the Laboratory Directed Research and Development (LDRD) project 10-0973 of the same title. Understanding the molecular origin of the no-slip boundary condition remains vitally important for understanding molecular transport in biological, environmental and energy-related processes, with broad technological implications. Moreover, the viscoelastic properties of fluids in nanoconfinement or near surfaces are not well-understood. We have critically reviewed progress in this area, evaluated key experimental and theoretical methods, and made unique and important discoveries addressing these and related scientific questions. Thematically, the discoveries include insight into the orientation of water molecules on metal surfaces, the premelting of ice, the nucleation of water and alcohol vapors between surface asperities and the lubricity of these molecules when confined inside nanopores, the influence of water nucleation on adhesion to salts and silicates, and the growth and superplasticity of NaCl nanowires.

  16. Surface Di-directional Reflectance Properties Over the ARM SGP Area from Satellite Multi-Platform Observations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bi-Directional Reflectance Properties Over the ARM SGP Area from Satellite Multi-Platform Observations Y. Luo, A. P. Trishchenko, and R. Latifovic Canada Centre for Remote Sensing Natural Resources Canada Ottawa, Ontario, Canada Z. Li Earth System Science Interdisciplinary Center University of Maryland College Park, Maryland Introduction Surface albedo is an important parameter in atmospheric radiation research. Good knowledge of surface bi-directional reflectance distribution function (BRDF) is

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climate Change Download a printable PDF Submitter: Maseyk, K. S., Universite Pierre et Marie Curie, Paris 6 Area of Research: Surface Properties Working Group(s):...

  18. The Role of Surface Chemistry and Bulk Properties on the Cycling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications The Role of Surface Chemistry and Bulk Properties on the ... Energy Storage R&D The Role of Surface Chemistry on the Cycling and Rate Capability of ...

  19. Nanotextured Anti-Icing Surfaces | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Demonstrate Promising Anti-icing Nano Surfaces Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window)...

  20. Surface-active properties of humic and sulfochlorohumic acids

    SciTech Connect (OSTI)

    Ryabova, I.N.; Mustafina, G.A.; Akkulova, Z.G.; Satymbaeva, A.S.

    2009-10-15

    The surface tension of alkaline solutions of humic acids and their sulfochloroderivatives, which are synthesized by sulfonation of chlorohumic acids isolated from coal chlorinated by the electrochemical method, is investigated. It is established that humic compounds possess weak surface activity. Basic adsorption parameters are calculated.

  1. Manipulation of fluids in three-dimensional porous photonic structures with patterned surface properties

    DOE Patents [OSTI]

    Aizenberg, Joanna; Burgess, Ian B.; Mishchenko, Lidiya; Hatton, Benjamin; Loncar, Marko

    2016-03-08

    A three-dimensional porous photonic structure, whose internal pore surfaces can be provided with desired surface properties in a spatially selective manner with arbitrary patterns, and methods for making the same are described. When exposed to a fluid (e.g., via immersion or wicking), the fluid can selectively penetrate the regions of the structure with compatible surface properties. Broad applications, for example in security, encryption and document authentication, as well as in areas such as simple microfluidics and diagnostics, are anticipated.

  2. Cooperative Research and Development of Primary Surface Recuperator for Advanced Microturbine Systems

    SciTech Connect (OSTI)

    Escola, George

    2007-01-17

    Recuperators have been identified as key components of advanced gas turbines systems that achieve a measure of improvement in operating efficiency and lead the field in achieving very low emissions. Every gas turbine manufacturer that is studying, developing, or commercializing advanced recuperated gas turbine cycles requests that recuperators operate at higher temperature without a reduction in design life and must cost less. The Solar Cooperative Research and Development of Primary Surface Recuperator for Advanced Microturbine Systems Program is directed towards meeting the future requirements of advanced gas turbine systems by the following: (1) The development of advanced alloys that will allow recuperator inlet exhaust gas temperatures to increase without significant cost increase. (2) Further characterization of the creep and oxidation (dry and humid air) properties of nickel alloy foils (less than 0.13 mm thick) to allow the economical use of these materials. (3) Increasing the use of advanced robotic systems and advanced in-process statistical measurement systems.

  3. Influence of Elastic and Surface Strains on the Optical Properties of

    Office of Scientific and Technical Information (OSTI)

    Semiconducting Core-Shell Nanoparticles (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Influence of Elastic and Surface Strains on the Optical Properties of Semiconducting Core-Shell Nanoparticles Citation Details In-Document Search This content will become publicly available on July 6, 2016 Title: Influence of Elastic and Surface Strains on the Optical Properties of Semiconducting Core-Shell Nanoparticles Authors: Mangeri, John ; Heinonen, Olle ;

  4. Unusual adsorption properties of silver adlayers on the Pt(111) electrode surface

    SciTech Connect (OSTI)

    Marinkovic, N.S.; Wang, J.X.; Adzic, R.R.; Marinkovic, J.S.

    1999-01-07

    Adsorption properties of silver monolayer and bilayer deposited at underpotentials on a Pt(111) electrode were studied by means of linear sweep voltammetry, in situ surface X-ray scattering and infrared spectroelectrochemistry. Surface X-ray scattering measurements show a pseudomorphic Ag monolayer and an incommensurate expanded bilayer on Pt(111) formed at underpotentials. Unusual adsorption properties of the silver layers with respect to the bulk silver are observed. The two Ag adlayers were found to have intermediate adsorption/oxidation characteristics between those of metallic Ag and Pt surfaces with (111) orientation. The Ag monolayer has properties that facilitate adsorption of bisulfate anions and adsorption and oxidation of CO. These properties are closer to the adsorption properties of the Pt(111) surface than to those of Ag(111), which adsorbs sulfate anions and does not adsorb CO. The Ag bilayer on the Pt(111) surface adsorbs sulfate anions as Ag(111) does, but in contrast to the behavior of Ag(111), it adsorbs CO. These properties of the Ag adlayers appear to be a consequence of the charge-transfer process and the electron distribution in the Ag/Pt(111) surface.

  5. The influence of surface functionalisation on the electrical properties and thermal stability of nanodiamonds

    SciTech Connect (OSTI)

    Welch, Joseph O; Li, Pei; Chaudhary, Aysha; Edgington, Robert; Jackman, Richard B.

    2014-10-07

    Detonation nanodiamond (ND) has recently emerged as a useful new class of diamond material. However, to date there has been little investigation of the electrical properties of this material. Due to the nanoscale dimensions, the surface functionalisation of the individual ND is of particular importance to the characteristics of ND films. Here, hydrogen and oxygen termination of ND, verified using Fourier transform infrared spectroscopy, are shown to strongly influence the electronic properties of NDs. Hydrogen terminated ND exhibiting a far greater resilience to thermal decomposition when compared to the oxygen terminated NDs. Moreover, H-NDs also displayed so-called surface conductivity, a property displayed by hydrogen-terminated bulk diamond films, whilst O-NDs display properties high resistivity. These results indicate that under the correct conditions ND layers can display similar electrical properties to bulk diamond thin films.

  6. Effect of Surface Termination on the Electonic Properties of LaNiO₃ Films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kumah, Divine P.; Malashevich, Andrei; Disa, Ankit S.; Arena, Dario A.; Walker, Fred J.; Ismail-Beigi, Sohrab; Ahn, Charles H.

    2014-11-06

    The electronic and structural properties of thin LaNiO₃ films grown by using molecular beam epitaxy are studied as a function of the net ionic charge of the surface terminating layer. We demonstrate that electronic transport in nickelate heterostructures can be manipulated through changes in the surface termination due to a strong coupling of the surface electrostatic properties to the structural properties of the Ni—O bonds that govern electronic conduction. We observe experimentally and from first-principles theory an asymmetric response of the structural properties of the films to the sign of the surface charge, which results from a strong interplay betweenmore » electrostatic and mechanical boundary conditions governing the system. The structural response results in ionic buckling in the near-surface NiO₂ planes for films terminated with negatively charged NiO₂ and bulklike NiO₂ planes for films terminated with positively charged LaO planes. The ability to modify transport properties by the deposition of a single atomic layer can be used as a guiding principle for nanoscale device fabrication.« less

  7. Effect of Surface Termination on the Electonic Properties of LaNiO? Films

    SciTech Connect (OSTI)

    Kumah, Divine P.; Malashevich, Andrei; Disa, Ankit S.; Arena, Dario A.; Walker, Fred J.; Ismail-Beigi, Sohrab; Ahn, Charles H.

    2014-11-06

    The electronic and structural properties of thin LaNiO? films grown by using molecular beam epitaxy are studied as a function of the net ionic charge of the surface terminating layer. We demonstrate that electronic transport in nickelate heterostructures can be manipulated through changes in the surface termination due to a strong coupling of the surface electrostatic properties to the structural properties of the NiO bonds that govern electronic conduction. We observe experimentally and from first-principles theory an asymmetric response of the structural properties of the films to the sign of the surface charge, which results from a strong interplay between electrostatic and mechanical boundary conditions governing the system. The structural response results in ionic buckling in the near-surface NiO? planes for films terminated with negatively charged NiO? and bulklike NiO? planes for films terminated with positively charged LaO planes. The ability to modify transport properties by the deposition of a single atomic layer can be used as a guiding principle for nanoscale device fabrication.

  8. The Role of Surface Chemistry and Bulk Properties on the Cycling and Rate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Capability of Lithium Positive Electrode Materials | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es084_shaohorn_2011_o.pdf More Documents & Publications The Role of Surface Chemistry and Bulk Properties on the Cycling and Rate Capability of Lithium Positive Electrode Materials FY 2011 Annual Progress Report for Energy Storage R&D The Role of Surface Chemistry on the Cycling and Rate

  9. The Role of Surface Chemistry and Bulk Properties on the Cycling and Rate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Capability of Lithium Positive Electrode Materials | Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es084_shaohorn_2010_p.pdf More Documents & Publications The Role of Surface Chemistry and Bulk Properties on the Cycling and Rate Capability of Lithium Positive Electrode Materials The Role of Surface Chemistry on the Cycling and Rate Capability of Lithium Positive Electrode

  10. Communication: The correct interpretation of surface hopping trajectories: How to calculate electronic properties

    SciTech Connect (OSTI)

    Landry, Brian R.; Falk, Martin J.; Subotnik, Joseph E.

    2013-12-07

    In a recent paper, we presented a road map for how Tully's fewest switches surface hopping (FSSH) algorithm can be derived, under certain circumstances, from the mixed quantum-classical Liouville equation. In this communication, we now demonstrate how this new interpretation of surface hopping can yield significantly enhanced results for electronic properties in nonadiabatic calculations. Specifically, we calculate diabatic populations for the spin-boson problem using FSSH trajectories. We show that, for some Hamiltonians, without changing the FSSH algorithm at all but rather simply reinterpreting the ensemble of surface hopping trajectories, we recover excellent results and remove any and all ambiguity about the initial condition problem.

  11. Optical, electrical and surface properties of annealed CdO:Mg thin films prepared by spray pyrolysis

    SciTech Connect (OSTI)

    Karakaya, Seniye E-mail: oozbas@ogu.edu.tr; Ozbas, Omer E-mail: oozbas@ogu.edu.tr

    2013-12-16

    The use of transparent conducting oxides in optoelectronic and photovoltaic devices has encouraged research on this field in recent years. Especially, cadmium oxide is a promising material for solar cell application but also for photodiodes and gas sensors. Mg doped CdO (CdO:Mg) films have been prepared on glass substrates by the ultrasonic spray pyrolysis (USP) technique. After the production, the films have been annealed in air atmosphere at 475C and half hour. Results on surface, optical and electrical properties of the films as a function of the thermal annealing have been reported. Thicknesses of the films have been determined by the filmetrics thin film measurement system. Transmission and absorbance spectra have been taken by UV-vis spectrophotometer. Atomic Force Microscopy (AFM) analysis indicates that the roughness of the surface decreases upon increasing Mg concentration. The minimum resistivity value of the films was 210{sup ?3} ? cm.

  12. Electric double layer at metal oxide surfaces: Static properties of the cassiterite - Water Interface

    SciTech Connect (OSTI)

    Vlcek, Lukas; Zhang, Zhan; Machesky, Michael L.; Wesolowski, David J

    2007-04-01

    The structure of water at the (110) surface of cassiterite ({alpha}-SnO{sub 2}) at ambient conditions was studied by means of molecular dynamics simulations and X-ray crystal truncation rod experiments and interpreted with the help of the revised MUSIC model of surface protonation. The interactions of the metal oxide in the simulations were described by a recently developed classical force field based on the SPC/E model of water. Two extreme cases of completely hydroxylated and nonhydroxylated surfaces were considered along with a mixed surface with 50% dissociation. To study the dependence of the surface properties on pH, neutral and negatively charged variants of the surfaces were constructed. Axial and lateral density distributions of water for different types of surfaces were compared to each other and to experimental axial density distributions found by X-ray experiments. Although significant differences were found between the structures of the studied interfaces, the axial distances between Sn and O atoms are very similar and therefore could not be clearly distinguished by the diffraction technique. The explanation of structures observed in the density distributions was provided by a detailed analysis of hydrogen bonding in the interfacial region. It revealed qualitatively different hydrating patterns formed at neutral hydroxylated and nonhydroxylated surfaces and suggested a preference for the dissociative adsorption of water. At negatively charged surfaces, however, the situation can be reversed by the electric field stabilizing a hydrogen bond network similar to that found at the neutral nonhydroxylated surface. Comparison with previously studied rutile ({alpha}-TiO{sub 2}) surfaces provided insight into the differences between the hydration of these two metal oxides, and an important role was ascribed to their different lattice parameters. A link to macroscopic properties was provided by the revised MUSIC surface protonation model. Explicit use of the Sn-O bond lengths based on ab initio calculations and H-bond configurations as inputs led to the prediction of a pH of zero net-proton induced surface charge (pH{sub pzc}) that agrees very well with those determined experimentally (about 4.4 at 298 K).

  13. Electric double layer at metal oxide surfaces:static properties of the cassiterite-water interface.

    SciTech Connect (OSTI)

    Vlcek, L.; Zhang, Z.; Machesky, M .L.; Fenter, P.; Rosenqvist, J.; Wesolowski, D. J.; Anovitz, L. M.; Predota, M.; Cummings, P. T.; Vanderbilt Univ.; ORNL; Univ. of South Bohimia; Illinois State Water Survey

    2007-03-24

    The structure of water at the (110) surface of cassiterite ({alpha}-SnO{sub 2}) at ambient conditions was studied by means of molecular dynamics simulations and X-ray crystal truncation rod experiments and interpreted with the help of the revised MUSIC model of surface protonation. The interactions of the metal oxide in the simulations were described by a recently developed classical force field based on the SPC/E model of water. Two extreme cases of completely hydroxylated and nonhydroxylated surfaces were considered along with a mixed surface with 50% dissociation. To study the dependence of the surface properties on pH, neutral and negatively charged variants of the surfaces were constructed. Axial and lateral density distributions of water for different types of surfaces were compared to each other and to experimental axial density distributions found by X-ray experiments. Although significant differences were found between the structures of the studied interfaces, the axial distances between Sn and O atoms are very similar and therefore could not be clearly distinguished by the diffraction technique. The explanation of structures observed in the density distributions was provided by a detailed analysis of hydrogen bonding in the interfacial region. It revealed qualitatively different hydrating patterns formed at neutral hydroxylated and nonhydroxylated surfaces and suggested a preference for the dissociative adsorption of water. At negatively charged surfaces, however, the situation can be reversed by the electric field stabilizing a hydrogen bond network similar to that found at the neutral nonhydroxylated surface. Comparison with previously studied rutile ({alpha}-TiO{sub 2}) surfaces provided insight into the differences between the hydration of these two metal oxides, and an important role was ascribed to their different lattice parameters. A link to macroscopic properties was provided by the revised MUSIC surface protonation model. Explicit use of the Sn-O bond lengths based on ab initio calculations and H-bond configurations as inputs led to the prediction of a pH of zero net-proton induced surface charge (pH{sub pzc}) that agrees very well with those determined experimentally (about 4.4 at 298 K).

  14. Rough surface electrical contact resistance considering scale dependent properties and quantum effects

    SciTech Connect (OSTI)

    Jackson, Robert L.; Crandall, Erika R.; Bozack, Michael J.

    2015-05-21

    The objective of this work is to evaluate the effect of scale dependent mechanical and electrical properties on electrical contact resistance (ECR) between rough surfaces. This work attempts to build on existing ECR models that neglect potentially important quantum- and size-dependent contact and electrical conduction mechanisms present due to the asperity sizes on typical surfaces. The electrical conductance at small scales can quantize or show a stepping trend as the contact area is varied in the range of the free electron Fermi wavelength squared. This work then evaluates if these effects remain important for the interface between rough surfaces, which may include many small scale contacts of varying sizes. The results suggest that these effects may be significant in some cases, while insignificant for others. It depends on the load and the multiscale structure of the surface roughness.

  15. Method And Apparatus For Two Dimensional Surface Property Analysis Based On Boundary Measurement

    DOE Patents [OSTI]

    Richardson, John G. (Idaho Falls, ID)

    2005-11-15

    An apparatus and method for determining properties of a conductive film is disclosed. A plurality of probe locations selected around a periphery of the conductive film define a plurality of measurement lines between each probe location and all other probe locations. Electrical resistance may be measured along each of the measurement lines. A lumped parameter model may be developed based on the measured values of electrical resistance. The lumped parameter model may be used to estimate resistivity at one or more selected locations encompassed by the plurality of probe locations. The resistivity may be extrapolated to other physical properties if the conductive film includes a correlation between resistivity and the other physical properties. A profile of the conductive film may be developed by determining resistivity at a plurality of locations. The conductive film may be applied to a structure such that resistivity may be estimated and profiled for the structure's surface.

  16. Ash Deposit Formation and Deposit Properties. A Comprehensive Summary of Research Conducted at Sandia's Combustion Research Facility

    SciTech Connect (OSTI)

    Larry L. Baxter

    2000-08-01

    This report summarizes experimental and theoretical work performed at Sandia's Combustion Research Facility over the past eight years on the fate of inorganic material during coal combustion. This work has been done under four broad categories: coal characterization, fly ash formation, ash deposition, and deposit property development. The objective was to provide sufficient understanding of these four areas to be able to predict coal behavior in current and advanced conversion systems. This work has led to new characterization techniques for fuels that provide, for the first time, systematic and species specific information regarding the inorganic material. The transformations of inorganic material during combustion can be described in terms of the net effects of the transformations of these individual species. Deposit formation mechanisms provide a framework for predicting deposition rates for abroad range of particle sizes. Predictions based on these rates many times are quite accurate although there are important exceptions. A rigorous framework for evaluating deposit has been established. Substantial data have been obtained with which to exercise this framework, but this portion of the work is less mature than is any other. Accurate prediction of deposit properties as functions of fuel properties, boiler design, and boiler operating conditions represents the single most critical area where additional research is needed.

  17. Spectroscopic Investigation of Surface Dependent Acid-base Property of Ceria Nanoshapes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Zili; Mann, Amanda K; Li, Meijun; Overbury, Steven

    2015-01-01

    In addition to their well-known redox character, the acid-base property is another interesting aspect of ceria-based catalysts. Herein, the effect of surface structure on the acid-base property of ceria was studied in detail by utilizing ceria nanocrystals with different morphologies (cubes, octahedra and rods) that exhibit crystallographically well-defined surface facets. The nature, type, strength and amount of acid and base sites on these ceria nanoshapes were investigated via in situ IR spectroscopy combined with various probe molecules. Pyridine adsorption shows the presence of Lewis acid sites (Ce cations) on the ceria nanoshapes. These Lewis acid sites are relatively weak andmore » similar in strength among the three nanoshapes according to the probing by both pyridine and acetonitrile. Both Br nsted (hydroxyl group) and Lewis (surface lattice oxygen) base sites are present on the ceria nanoshapes as probed by CO2 adsorption. CO2 and chloroform adsorption indicate that the strength and amount of the Lewis base sites are shape dependent: rods > cubes > octahedra. The weak and strong surface dependence of the acid and base sites, respectively, are a result of interplay between the surface structure dependent coordination unsaturation status of the Ce cations and O anions and the amount of defect sites on the three ceria nanoshapes. Furthermore, it was found that the nature of the acid-base sites of ceria can be impacted by impurities, such as Na and P residues that result from their use as structure-directing reagent in the hydrothermal synthesis of the ceria nanocrystals. This observation calls for precaution in interpreting the catalytic behavior of nanoshaped ceria where trace impurities may be present.« less

  18. Spectroscopic Investigation of Surface Dependent Acid-base Property of Ceria Nanoshapes

    SciTech Connect (OSTI)

    Wu, Zili; Mann, Amanda K; Li, Meijun; Overbury, Steven {Steve} H

    2015-01-01

    In addition to their well-known redox character, the acid-base property is another interesting aspect of ceria-based catalysts. Herein, the effect of surface structure on the acid-base property of ceria was studied in detail by utilizing ceria nanocrystals with different morphologies (cubes, octahedra and rods) that exhibit crystallographically well-defined surface facets. The nature, type, strength and amount of acid and base sites on these ceria nanoshapes were investigated via in situ IR spectroscopy combined with various probe molecules. Pyridine adsorption shows the presence of Lewis acid sites (Ce cations) on the ceria nanoshapes. These Lewis acid sites are relatively weak and similar in strength among the three nanoshapes according to the probing by both pyridine and acetonitrile. Both Br nsted (hydroxyl group) and Lewis (surface lattice oxygen) base sites are present on the ceria nanoshapes as probed by CO2 adsorption. CO2 and chloroform adsorption indicate that the strength and amount of the Lewis base sites are shape dependent: rods > cubes > octahedra. The weak and strong surface dependence of the acid and base sites, respectively, are a result of interplay between the surface structure dependent coordination unsaturation status of the Ce cations and O anions and the amount of defect sites on the three ceria nanoshapes. Furthermore, it was found that the nature of the acid-base sites of ceria can be impacted by impurities, such as Na and P residues that result from their use as structure-directing reagent in the hydrothermal synthesis of the ceria nanocrystals. This observation calls for precaution in interpreting the catalytic behavior of nanoshaped ceria where trace impurities may be present.

  19. Modification of Bi:YIG film properties by substrate surface ion pre-treatment

    SciTech Connect (OSTI)

    Shaposhnikov, A.N.; Prokopov, A.R.; Karavainikov, A.V.; Berzhansky, V.N.; Mikhailova, T.V.; Kotov, V.A.; Balabanov, D.E.; Sharay, I.V.; Salyuk, O.Y.; Vasiliev, M.; Golub, V.O.

    2014-07-01

    Highlights: Effects of substrates ion beam treatment on magnetoptical properties Bi:YIG films. Substrate surface damage results in sign inversion of the magneto-optical effects. Atomically smooth films growth takes place on low energy ions treated substrates. High energy ions treatment results in selective nucleation mechanism of the growth. - Abstract: The effect of a controlled ion beam pre-treatment of (1 1 1)-oriented Gd{sub 3}Ga{sub 5}O{sub 12} substrates on the magneto-optical properties and surface morphology of the ultrathin bismuth-substituted yttriumiron garnet films with a composition Bi{sub 2.8}Y{sub 0.2}Fe{sub 5}O{sub 12} was studied. It has been shown that the observed sign inversion of magneto-optical effects (Faraday rotation and magnetic circular dichroism) observed in films that were deposited on the GGG substrate pre-treated by 1 keV and 4 keV Ar{sup +} ion beams is a result of the substrate surface amorphization caused by the ion bombardment.

  20. Investigations of the Electronic Properties and Surface Structures of Aluminium-Rich Quasicrystalline Alloys

    SciTech Connect (OSTI)

    Jason A. Barrow

    2003-08-05

    The work presented in this dissertation has investigated three distinct areas of interest in the field of quasicrystals: bulk structure, transport properties, and electronic structure. First, they have described the results of a study which explored the fundamental interactions between the atomic species of the icosahedral Al-Pd-Mn quasicrystal. The goal of this work was to determine whether the pseudo-MacKay or Bergman type clusters have a special stability or are merely a geometric coincidence. This was carried out by using laser vaporization to produce gas-phase metal clusters, which were analyzed using time-of-flight mass spectrometry. Both the kinetic and thermodynamic stabilities of the clusters were probed. The data indicated no special stability for either pseudo-MacKay or Bergman type clusters as isolated units. This, however, is not proof that these clusters are simply a geometric coincidence. It is possible that such clusters only have stability in the framework of the bulk matrix and do not exist as isolated units. Next, they have reported their investigations of the bulk thermal transport properties of a decagonal Al-Ni-Co two dimensional quasicrystal in the temperature range 373K-873K. The properties of a sample oriented along the periodic axis and another oriented along the aperiodic axis were measured. A high degree of anisotropy was observed between the aperiodic and periodic directions. Additionally, the properties were measured for a sample miscut to an orientation 45{sup o} off-axis. The properties of the miscut sample were shown to have good agreement with a theoretical model used to describe thermal transport in metallic single crystals. This model only considers thermal transport by a free-electron gas; therefore, agreement with experimental data suggests the validity of the Drude free-electron model for the decagonal Al-Ni-Co at these temperatures. Consequently, the observed anisotropy may be adequately described using classical transport equations. Transport behavior is described in terms of charge carriers and the mean-free time between carrier collisions. It is concluded that the mean-free time is much longer in the periodic direction than in the aperiodic direction. This difference produces the observed anisotropy in thermal transport. The third study presented a detailed analysis of the reversible, sputter-induced phase transformation which occurs on the 5-fold surface of an icosahedral Al-Cu-Fe quasicrystal. Reflection high-energy electron diffraction (RHEED), x-ray photoemission spectroscopy (XPS), and ultra-violet photoemission spectroscopy (UPS) data were collected as a function of annealing temperature and were used to probe surface structure, surface composition, and electronic structure, respectively. The composition and structure of the sputtered surface are consistent with a transformation to the {beta}-Al-Cu-Fe cubic structure, and shows a sharp metallic cut-off in the spectral intensity of the electronic structure at the Fermi edge. Upon annealing the surface reverts to a quasicrystalline composition and structure. This transformation has been correlated with a reduction in the spectral intensity of the electronic structure at the Fermi level. This data clearly demonstrates that the observed reduction is intrinsic to a quasicrystalline surface. It is concluded that this is due to the opening of a pseudo-gap in the electronic density of states as the surface reverts from {beta}-Al-Cu-Fe to quasicrystalline.

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Climatology of Midlatitude Continental Cloud Properties and Their Impact on the Surface Radiation Budget Submitter: Dong, X., University of North Dakota Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Dong, X., P. Minnis, and B. Xi, 2005: A climatology of midlatitude continental clouds from ARM SGP site. Part I: Low-level Cloud Macrophysical, microphysical and radiative properties. J. Climate. 18, 1391-1410. Dong, X., B. Xi, and P.

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cumuli Impact on Solar Radiation at Surface: Spectral Changes Download a printable PDF Submitter: Kassianov, E., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle, Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: Kassianov E, J Barnard, LK Berg, CN Long, and C Flynn. 2011. "Shortwave spectral radiative forcing of cumulus clouds from surface observations." Geophysical Research Letters, 38, L07801,

  3. Performance of the BL4 Beamline for Surface and Interface Research at the Siam Photon Laboratory

    SciTech Connect (OSTI)

    Nakajima, Hideki; Buddhakala, Moragote; Chumpolkulwong, Somchai; Supruangnet, Ratchadapora; Kakizaki, Akito; Songsiriritthigul, Prayoon

    2007-01-19

    The evaluations of the monochromator of the BL4 beamline at the Siam Photon Laboratory were carried out by gas-phase photoionization measurements. The beamline employs a varied-line-spacing plane grating monochromator, which delivers photons with energies between 20-240 eV. The resolving power of the monochromator depends strongly with the alignment of the exit slit. The designed resolving power of 5000 has been achieved. The experimental station of the beamline has been upgraded for surface and interface research. The new experimental station removes the disadvantage and expands the capabilities of the old one in such a way that photoemission experiments using synchrotron light can be performed in parallel with other in situ surface analysis techniques, as well as with preparation of other samples. The new system includes the old photoemission system and a multi-UHV-chamber system. The standard surface-sensitive techniques available in addition to photoemission spectroscopy using synchrotron light are UPS, XPS, AES and LEED. The new experimental station also includes a metal MBE system for preparing samples for the studies of ultra-thin magnetic films and metal-semiconductor interfaces.

  4. Optimization of the optical properties of nanostructured silicon surfaces for solar cell applications

    SciTech Connect (OSTI)

    Zhou, Di; Pennec, Y.; Djafari-Rouhani, B.; Lambert, Y.; Deblock, Y.; Stiévenard, D.; Cristini-Robbe, O.; Xu, T.; Faucher, M.

    2014-04-07

    Surface nanostructuration is an important challenge for the optimization of light trapping in solar cell. We present simulations on both the optical properties and the efficiency of micro pillars—MPs—or nanocones—NCs—silicon based solar cells together with measurements on their associated optical absorption. We address the simulation using the Finite Difference Time Domain method, well-adapted to deal with a periodic set of nanostructures. We study the effect of the period, the bottom diameter, the top diameter, and the height of the MPs or NCs on the efficiency, assuming that one absorbed photon induces one exciton. This allows us to give a kind of abacus involving all the geometrical parameters of the nanostructured surface with regard to the efficiency of the associated solar cell. We also show that for a given ratio of the diameter over the period, the best efficiency is obtained for small diameters. For small lengths, MPs are extended to NCs by changing the angle between the bottom surface and the vertical face of the MPs. The best efficiency is obtained for an angle of the order of 70°. Finally, nanostructures have been processed and allow comparing experimental results with simulations. In every case, a good agreement is found.

  5. Magnetic properties on the surface of FeAl stripes induced by nanosecond pulsed laser irradiation

    SciTech Connect (OSTI)

    Kaiju, H. Kondo, K.; Ishibashi, A.; Yoshida, Y.; Watanabe, S.; Yoshimi, K.

    2014-05-07

    We demonstrate the formation of magnetic nanostripes on the surface of Fe{sub 52}Al{sub 48} induced by nanosecond pulsed laser irradiation and investigate their magnetic properties. The magnetic stripe consists of a disordered A2 phase of Fe-Al alloys with Al-oxide along the [110] direction on the (111)-oriented plane. According to the focused magneto-optical Kerr effect measurement, the coercive force of the magnetic stripe obeys the 1/cos?? law, where ? is the field rotation angle estimated from the stripe direction. Also, the jump field can be observed in the magnetic hysteresis loop. These results indicate that the magnetization reversal in the magnetic stripe originates from the domain pinning, showing that the magnetization rotates incoherently.

  6. Surface driven effects on magnetic properties of antiferromagnetic LaFeO{sub 3} nanocrystalline ferrite

    SciTech Connect (OSTI)

    Sendil Kumar, A. E-mail: anilb42@gmail.com; Manivel Raja, M.; Bhatnagar, Anil K. E-mail: anilb42@gmail.com

    2014-09-21

    LaFeO{sub 3} nanocrystalline ferrites were synthesized through sol-gel method in different size distributions and the effect of finite size on magnetic properties is investigated. Results of magnetization and Mssbauer measurements show that superparamagnetism and weak ferromagnetic behavior in some of the size distributions. The origin of the superparamagnetism is from fine particles similar to ferromagnetic single domains and the weak ferromagnetism comes from surface spin disorder caused by Dzyaloshinskii-Moriya interaction. The magnetic ground state of LaFeO{sub 3} nanoparticles differs from that of bulk, and the ground state is dictated by the finite size effect because density of states depends on the dimensionality of the sample.

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Method for Satellite/Surface Comparisons Download a printable PDF Submitter: Long, C. N., NOAA Global Monitoring Division/CIRES Area of Research: Radiation Processes Working Group(s): Cloud Properties, Radiative Processes Journal Reference: Zhang Y, CN Long, WB Rossow, and EG Dutton. 2010. "Exploiting diurnal variations to evaluate the ISCCP-FD flux calculations and radiative-flux-analysis-processed surface observations from BSRN, ARM, and SURFRAD." Journal of Geophysical

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Broadband Albedo Observations in the Southern Great Plains Submitter: Lamb, P. J., University of Oklahoma Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: Journal of Applied Meteorology and Climatology, Vol. 45, 2006, pp. 210-235. Figure 1 Figure 2 Because surface reflection of solar radiation plays a fundamental role in the surface energy budget, knowledge of its spatial and temporal variability is important for understanding the weather and climate of a

  9. Surface and Interface Properties of 10–12 Unit Cells Thick Sputter Deposited Epitaxial CeO 2 Films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Saraf, L. V.; Wang, C. M.; Engelhard, M. H.; Nachimuthu, P.

    2008-01-01

    Ulmore » trathin and continuous epitaxial films with relaxed lattice strain can potentially maintain more of its bulk physical and chemical properties and are useful as buffer layers. We study surface, interface, and microstructural properties of ultrathin ( ∼ 10–12 unit cells thick) epitaxial ceria films grown on single crystal YSZ substrates. The out-of -plane and in-plane lattice parameters indicate relaxation in the continuous film due to misfit dislocations seen by high-resolution transmission electron microscopy (HRTEM) and substrate roughness of ∼ 1-2 unit cells, confirmed by atomic force microscopy and HRTEM. A combination of secondary sputtering, lattice mismatch, substrate roughness, and surface reduction creating secondary phase was likely the cause of surface roughness which should be reduced to a minimum level for effective use of it as buffer layers.« less

  10. Surface and Interface Properties of 1012 Unit Cells Thick Sputter Deposited Epitaxial CeO2Films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Saraf, L. V.; Wang, C. M.; Engelhard, M. H.; Nachimuthu, P.

    2008-01-01

    Ultrathin and continuous epitaxial films with relaxed lattice strain can potentially maintain more of its bulk physical and chemical properties and are useful as buffer layers. We study surface, interface, and microstructural properties of ultrathin (?1012 unit cells thick) epitaxial ceria films grown on single crystal YSZ substrates. The out-of -plane and in-plane lattice parameters indicate relaxation in the continuous film due to misfit dislocations seen by high-resolution transmission electron microscopy (HRTEM) and substrate roughness of?1-2 unit cells, confirmed by atomic force microscopy and HRTEM. A combination of secondary sputtering, lattice mismatch, substrate roughness, and surface reduction creating secondary phasemorewas likely the cause of surface roughness which should be reduced to a minimum level for effective use of it as buffer layers.less

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Observational Analysis of Land-Atmosphere Coupling for Climate Model Evaluation Download a printable PDF Submitter: Phillips, T. J., Lawrence Livermore National Laboratory Klein, S., Lawrence Livermore National Laboratory Area of Research: Surface Properties Working Group(s): Cloud Life Cycle Journal Reference: Phillips TJ and SA Klein. 2014. "Land-atmosphere coupling manifested in warm-season observations on the U.S. southern great plains." Journal of Geophysical Research -

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Revealing Look Inside Northern Australian Wet Season Precipitation Download a printable PDF Submitter: Giangrande, S., Brookhaven National Laboratory Area of Research: Surface Properties Working Group(s): Cloud Life Cycle Journal Reference: Giangrande SE, M Bartholomew, M Pope, S Collis, and MP Jensen. 2014. "A Summary of Precipitation Characteristics from the 2006-2011 Northern Australian Wet Seasons as Revealed by ARM Disdrometer Research Facilities (Darwin, Australia)." Journal of

  13. ARM Climate Research Facility Spectral Surface Albedo Value-Added Product (VAP) Report

    SciTech Connect (OSTI)

    McFarlane, S; Gaustad, K; Long, C; Mlawer, E

    2011-07-15

    This document describes the input requirements, output data products, and methodology for the Spectral Surface Albedo (SURFSPECALB) value-added product (VAP). The SURFSPECALB VAP produces a best-estimate near-continuous high spectral resolution albedo data product using measurements from multifilter radiometers (MFRs). The VAP first identifies best estimates for the MFR downwelling and upwelling shortwave irradiance values, and then calculates narrowband spectral albedo from these best-estimate irradiance values. The methodology for finding the best-estimate values is based on a simple process of screening suspect data and backfilling screened and missing data with estimated values when possible. The resulting best-estimate MFR narrowband spectral albedos are used to determine a daily surface type (snow, 100% vegetation, partial vegetation, or 0% vegetation). For non-snow surfaces, a piecewise continuous function is used to estimate a high spectral resolution albedo at 1 min temporal and 10 cm-1 spectral resolution.

  14. A Nano Surface Icephobic Coating Delays Ice Formation | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nano Surface Icephobic Coating Delays Ice Formation Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) Click to share on LinkedIn (Opens in new window) Click to share on Tumblr (Opens in new window) A Nano Surface Icephobic Coating Delays Ice Formation Azar Alizadeh 2012.03.08 Hi folks, As many of you may know ice could be a huge problem in everyday life. For many of us who live in the North East of the US, dealing

  15. Electrical properties and surface morphology of electron beam evaporated p-type silicon thin films on polyethylene terephthalate for solar cells applications

    SciTech Connect (OSTI)

    Ang, P. C.; Ibrahim, K.; Pakhuruddin, M. Z.

    2015-04-24

    One way to realize low-cost thin film silicon (Si) solar cells fabrication is by depositing the films with high-deposition rate and manufacturing-compatible electron beam (e-beam) evaporation onto inexpensive foreign substrates such as glass or plastic. Most of the ongoing research is reported on e-beam evaporation of Si films on glass substrates to make polycrystalline solar cells but works combining both e-beam evaporation and plastic substrates are still scarce in the literature. This paper studies electrical properties and surface morphology of 1 m electron beam evaporated Al-doped p-type silicon thin films on textured polyethylene terephthalate (PET) substrate for application as an absorber layer in solar cells. In this work, Si thin films with different doping concentrations (including an undoped reference) are prepared by e-beam evaporation. Energy dispersion X-ray (EDX) showed that the Si films are uniformly doped by Al dopant atoms. With increased Al/Si ratio, doping concentration increased while both resistivity and carrier mobility of the films showed opposite relationships. Root mean square (RMS) surface roughness increased. Overall, the Al-doped Si film with Al/Si ratio of 2% (doping concentration = 1.5710{sup 16} atoms/cm{sup 3}) has been found to provide the optimum properties of a p-type absorber layer for fabrication of thin film Si solar cells on PET substrate.

  16. Surface Transportation Research and Development Act of 1997. House of Representatives, One Hundred Fifth Congress, Second Session

    SciTech Connect (OSTI)

    1998-12-31

    Mr. Sensenbrenner, from the Committee on Science, submitted this report together with additional views. The Committee on Science, to whom was referred the bill (H.R. 860) to authorize appropriations to the Department of Transportation for surface transportation research and development, and for other purposes, having considered the same, report favorably thereon with an amendment and recommend that the bill as amended do pass.

  17. Structural and electrochemical properties of nanostructured nickel silicides by reduction and silicification of high-surface-area nickel oxide

    SciTech Connect (OSTI)

    Chen, Xiao [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)] [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China); Zhang, Bingsen [Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society (Germany)] [Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society (Germany); Li, Chuang; Shao, Zhengfeng [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)] [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China); Su, Dangsheng [Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society (Germany)] [Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society (Germany); Williams, Christopher T. [Department of Chemical Engineering, Swearingen Engineering Center, University of South Carolina (United States)] [Department of Chemical Engineering, Swearingen Engineering Center, University of South Carolina (United States); Liang, Changhai, E-mail: changhai@dlut.edu.cn [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)] [Laboratory of Advanced Materials and Catalytic Engineering, State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024 (China)

    2012-03-15

    Graphical abstract: Nanostructured nickel silicides have been synthesized by reduction and silification of high-surface-area nickel oxide, and exhibited remarkably like-noble metal property, lower electric resistivity, and ferromagnetism at room temperature. Highlights: Black-Right-Pointing-Pointer NiSi{sub x} have been prepared by reduction and silification of high-surface-area NiO. Black-Right-Pointing-Pointer The structure of nickel silicides changed with increasing reaction temperature. Black-Right-Pointing-Pointer Si doping into nickel changed the magnetic properties of metallic nickel. Black-Right-Pointing-Pointer NiSi{sub x} have remarkably lower electric resistivity and like-noble metal property. -- Abstract: Nanostructured nickel silicides have been prepared by reduction and silicification of high-surface-area nickel oxide (145 m{sup 2} g{sup -1}) produced via precipitation. The prepared materials were characterized by nitrogen adsorption, X-ray diffraction, thermal analysis, FT-IR spectroscopy, scanning electron microscopy, transmission electron microscopy, magnetic and electrochemical measurements. The nickel silicide formation involves the following sequence: NiO (cubic) {yields} Ni (cubic) {yields} Ni{sub 2}Si (orthorhombic) {yields} NiSi (orthorhombic) {yields} NiSi{sub 2} (cubic), with particles growing from 13.7 to 21.3 nm. The nickel silicides are ferromagnetic at room temperature, and their saturation magnetization values change drastically with the increase of Si content. Nickel silicides have remarkably low electrical resistivity and noble metal-like properties because of a constriction of the Ni d band and an increase of the electronic density of states. The results suggest that such silicides are promising candidates as inexpensive yet functional materials for applications in electrochemistry as well as catalysis.

  18. Effects of unreconstructed and reconstructed polar surface terminations on growth, structure, and magnetic properties of hematite films

    SciTech Connect (OSTI)

    Cheung, Sau Ha; Celik-Aktas, A.; Dey, P.; Pande, K.; Weinert, M.; Kabius, B.; Keavney, D.; Lazarov, Vlado; Chambers, Scott A.; Gajdardziska-Josifovska, Marija

    2012-01-05

    The effects of polar surface stabilization mechanisms on the film growth, phase composition, surface and interface structure, and magnetic properties are explored for polar oxide interfaces formed by the epitaxial growth of hematite films on magnesia and alumina single crystals. Growth of {alpha}-Fe{sub 2}O{sub 3}(0001) on the ({radical}3 x {radical}3)R30{sup o} and (2 x 2) reconstructed MgO(111) surfaces results in formation of a self-organized Fe{sub 3}O{sub 4}(111) interfacial nano buffer that persists after growth. The interfacial magnetite-like phase is absent from the hematite films formed on hydrogen-stabilized unreconstructed MgO(111)-(1 x 1) and on Al{sub 2}O{sub 3}(0001)-(1 x 1) surfaces under equivalent conditions. This study suggests that in addition to the customary strain, spin, and band-gap engineering, control of surface polarity stabilization could also be important for electronic and magnetic device engineering.

  19. Oxidation of activated carbon fibers: Effect on pore size, surface chemistry, and adsorption properties

    SciTech Connect (OSTI)

    Mangun, C.L.; Benak, K.R.; Daley, M.A.; Economy, J.

    1999-12-01

    Activated carbon fibers (ACFs) were oxidized using both aqueous and nonaqueous treatments. As much as 29 wt% oxygen can be incorporated onto the pore surface in the form of phenolic hydroxyl, quinine, and carboxylic acid groups. The effect of oxidation on the pore size, pore volume, and the pore surface chemistry was thoroughly examined. The average micropore size is typically affected very little by aqueous oxidation while the micropore volume and surface area decreases with such a treatment. In contrast, the micropore size and micropore volume both increase with oxidation in air. Oxidation of the fibers produces surface chemistries in the pore that provide for enhanced adsorption of basic (ammonia) and polar (acetone) molecules at ambient and nonambient temperatures. The adsorption capacity of the oxidized fibers for acetone is modestly better than the untreated ACFs while the adsorption capacity for ammonia can increase up to 30 times compared to untreated ACFs. The pore surface chemical makeup was analyzed using elemental analysis, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), and X-ray photoelectron spectroscopy (XPS).

  20. Fundamentals of Reservoir Surface Energy as Related to Surface Properties, Wettability, Capillary Action, and Oil Recovery from Fractured Reservoirs by Spontaneous Imbibition

    SciTech Connect (OSTI)

    Norman Morrow; Herbert Fischer; Yu Li; Geoffrey Mason; Douglas Ruth; Siddhartha Seth; Zhengxin Tong; Evren Unsal; Siluni Wickramathilaka; Shaochang Wo; Peigui Yin

    2008-06-30

    The objective of this project is to increase oil recovery from fractured reservoirs through improved fundamental understanding of the process of spontaneous imbibition by which oil is displaced from the rock matrix into the fractures. Spontaneous imbibition is fundamentally dependent on the reservoir surface free energy but this has never been investigated for rocks. In this project, the surface free energy of rocks will be determined by using liquids that can be solidified within the rock pore space at selected saturations. Thin sections of the rock then provide a two-dimensional view of the rock minerals and the occupant phases. Saturations and oil/rock, water/rock, and oil/water surface areas will be determined by advanced petrographic analysis and the surface free energy which drives spontaneous imbibition will be determined as a function of increase in wetting phase saturation. The inherent loss in surface free energy resulting from capillary instabilities at the microscopic (pore level) scale will be distinguished from the decrease in surface free energy that drives spontaneous imbibition. A mathematical network/numerical model will be developed and tested against experimental results of recovery versus time over broad variation of key factors such as rock properties, fluid phase viscosities, sample size, shape and boundary conditions. Two fundamentally important, but not previously considered, parameters of spontaneous imbibition, the capillary pressure acting to oppose production of oil at the outflow face and the pressure in the non-wetting phase at the no-flow boundary versus time, will also be measured and modeled. Simulation and network models will also be tested against special case solutions provided by analytic models. In the second stage of the project, application of the fundamental concepts developed in the first stage of the project will be demonstrated. The fundamental ideas, measurements, and analytic/numerical modeling will be applied to mixed-wet rocks. Imbibition measurements will include novel sensitive pressure measurements designed to elucidate the basic mechanisms that determine induction time and drive the very slow rate of spontaneous imbibition commonly observed for mixed-wet rocks. In further demonstration of concepts, three approaches to improved oil recovery from fractured reservoirs will be tested; use of surfactants to promote imbibition in oil wet rocks by wettability alteration: manipulation of injection brine composition: reduction of the capillary back pressure which opposes production of oil at the fracture face.

  1. Ion-assisted physical vapor deposition for enhanced film properties on nonflat surfaces

    SciTech Connect (OSTI)

    Alami, J.; Persson, P.O.A.; Music, D.; Gudmundsson, J. T.; Bohlmark, J.; Helmersson, U.

    2005-03-01

    We have synthesized Ta thin films on Si substrates placed along a wall of a 2-cm-deep and 1-cm-wide trench, using both a mostly neutral Ta flux by conventional dc magnetron sputtering (dcMS) and a mostly ionized Ta flux by high-power pulsed magnetron sputtering (HPPMS). Structure of the grown films was evaluated by scanning electron microscopy, transmission electron microscopy, and atomic force microscopy. The Ta thin film grown by HPPMS has a smooth surface and a dense crystalline structure with grains oriented perpendicular to the substrate surface, whereas the film grown by dcMS exhibits a rough surface, pores between the grains, and an inclined columnar structure. The improved homogeneity achieved by HPPMS is a direct consequence of the high ion fraction of sputtered species.

  2. Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Research Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. Research thorium test foil A thorium test foil target for proof-of-concept actinium-225 production In addition to our routine isotope products, the LANL Isotope Program is focused on developing the next suite of isotopes and services to meet the Nation's emerging needs. The LANL Isotope Program's R&D strategy is focused on four main areas (see

  3. 2014 CHEMICAL REACTIONS AT SURFACES GORDON RESEARCH CONFERENCE AND GORDON RESEARCH SEMINAR (APRIL 28-MAY 3, 2013 - LES DIABLERETS CONFERENCE CENTER, LES DIABLERETS, SWITZERLAND)

    SciTech Connect (OSTI)

    Stair, Peter C.

    2013-02-03

    presentations on chemistry at solid and liquid surfaces of relevance to catalysis, synthesis, photochemistry, environmental science, and tribology. Topics include: Fundamental Surface Chemistry; Catalysis; Solid Liquid and Aerosol Interfaces; Surface Photochemistry; Synthesis of Surfaces; Environmental Interfaces; Hot Topics in Surface Chemical Reactions; Tribology; Gas-Surface Scattering and Reactions; Novel Materials and Environments.

  4. First-principles study of quantum confinement and surface effects on the electronic properties of InAs nanowires

    SciTech Connect (OSTI)

    Ning, Feng; Tang, Li-Ming Zhang, Yong; Chen, Ke-Qiu

    2013-12-14

    We have used first principles methods to systematically investigate the quantum confinement effect on the electronic properties of zinc-blende (ZB) and wurtzite (WZ) InAs nanowires (NWs) with different orientations and diameters, and compared their electronic properties before and after pseudo-hydrogen passivation. The results show that the calculated carrier effective masses are dependent on the NW diameter, except for [110] ZB NWs, and the hole effective masses of [111] ZB NWs are larger than the electron effective masses when the NW diameter is ?26?. The band alignments of [111] ZB and [0001] WZ NWs reveal that the effect of quantum confinement on the conduction bands is greater than on the valence bands, and the position of the valence band maximum level changes little with increasing NW diameter. The pseudo-hydrogen passivated NWs have larger band gaps than the corresponding unpassivated NWs. The carrier effective masses and mobilities can be adjusted by passivating the surface dangling bonds.

  5. Charging Properties of Cassiterite (alpha-SnO2) surfaces in NaCl and RbCl Ionic Media.

    SciTech Connect (OSTI)

    Rosenqvist, Jorgen K; Machesky, Michael L.; Vlcek, Lukas; Wesolowski, David J

    2009-09-01

    The acid-base properties of cassiterite (alpha-SnO2) surfaces at 10-50 degrees C were studied using potentiometric titrations of powder suspensions in aqueous NaCl and RbCl media. The proton sorption isotherms exhibited common intersection points in the pH range of 4.0-4.5 under all conditions, and the magnitude of charging was similar but not identical in NaCl and RbCl. The hydrogen bonding configuration at the oxide-water interface, obtained from classical molecular dynamics (MD) simulations, was analyzed in detail, and the results were explicitly incorporated in calculations of protonation constants for the reactive surface sites using the revised MUSIC model. The calculations indicated that the terminal SnOH2 group is more acidic than the bridging Sn2OH group, with protonation constants (log KH) of 3.60 and 5.13 at 25 degrees C, respectively. This is contrary to the situation on the isostructural alpha-TiO2 (rutile), apparently because of the difference in electronegativity between Ti and Sn. MD simulations and speciation calculations indicated considerable differences in the speciation of Na+ and Rb+, despite the similarities in overall charging. Adsorbed sodium ions are almost exclusively found in bidentate surface complexes, whereas adsorbed rubidium ions form comparable numbers of bidentate and tetradentate complexes. Also, the distribution of adsorbed Na+ between the different complexes shows a considerable dependence on the surface charge density (pH), whereas the distribution of adsorbed Rb+ is almost independent of pH. A surface complexation model (SCM) capable of accurately describing both the measured surface charge and the MD-predicted speciation of adsorbed Na+/Rb+ was formulated. According to the SCM, the deprotonated terminal group (SnOH(-0.40)) and the protonated bridging group (Sn2OH+0.36) dominate the surface speciation over the entire pH range of this study (2.7-10). The complexation of medium cations increases significantly with increasing negative surface charge, and at pH 10, roughly 40% of the terminal sites are predicted to form cation complexes, whereas anion complexation is minor throughout the studied pH range.

  6. Charging Properties of Cassiterite (alpha-SnO2) Surfaces in NaCl and RbCl Ionic Media.

    SciTech Connect (OSTI)

    Rosenqvist, Jorgen K; Machesky, Michael L.; Vlcek, Lukas; Wesolowski, David J

    2009-09-01

    The acid-base properties of cassiterite ({alpha}-SnO{sub 2}) surfaces at 10-50 C were studied using potentiometric titrations of powder suspensions in aqueous NaCl and RbCl media. The proton sorption isotherms exhibited common intersection points in the pH range of 4.0-4.5 under all conditions, and the magnitude of charging was similar but not identical in NaCl and RbCl. The hydrogen bonding configuration at the oxide-water interface, obtained from classical molecular dynamics (MD) simulations, was analyzed in detail, and the results were explicitly incorporated in calculations of protonation constants for the reactive surface sites using the revised MUSIC model. The calculations indicated that the terminal SnOH{sub 2} group is more acidic than the bridging Sn{sub 2}OH group, with protonation constants (log K{sub H}) of 3.60 and 5.13 at 25 C, respectively. This is contrary to the situation on the isostructural {alpha}-TiO{sub 2} (rutile), apparently because of the difference in electronegativity between Ti and Sn. MD simulations and speciation calculations indicated considerable differences in the speciation of Na{sup +} and Rb{sup +}, despite the similarities in overall charging. Adsorbed sodium ions are almost exclusively found in bidentate surface complexes, whereas adsorbed rubidium ions form comparable numbers of bidentate and tetradentate complexes. Also, the distribution of adsorbed Na{sup +} between the different complexes shows a considerable dependence on the surface charge density (pH), whereas the distribution of adsorbed Rb{sup +} is almost independent of pH. A surface complexation model (SCM) capable of accurately describing both the measured surface charge and the MD-predicted speciation of adsorbed Na{sup +}/Rb{sup +} was formulated. According to the SCM, the deprotonated terminal group (SnOH{sup -0.40}) and the protonated bridging group (Sn{sub 2}OH{sup +0.36}) dominate the surface speciation over the entire pH range of this study (2.7-10). The complexation of medium cations increases significantly with increasing negative surface charge, and at pH 10, roughly 40% of the terminal sites are predicted to form cation complexes, whereas anion complexation is minor throughout the studied pH range.

  7. Structure and electronic properties of Cu nanoclusters supported on Mo2C(001) and MoC(001) surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Posada-Pérez, Sergio; Viñes, Francesc; Rodríguez, José A.; Illas, Francesc

    2015-09-15

    In this study, the atomic structure and electronic properties of Cun nanoclusters (n = 4, 6, 7, and 10) supported on cubic nonpolar δ-MoC(001) and orthorhombic C- or Mo-terminated polar β-Mo2C(001) surfaces have been investigated by means of periodic density functional theory based calculations. The electronic properties have been analyzed by means of the density of states, Bader charges, and electron localization function plots. The Cu nanoparticles supported on β-Mo2C(001), either Mo- or C-terminated, tend to present a two-dimensional structure whereas a three-dimensional geometry is preferred when supported on δ-MoC(001), indicating that the Mo:C ratio and the surface polarity playmore » a key role determining the structure of supported clusters. Nevertheless, calculations also reveal important differences between the C- and Mo-terminated β-Mo2C(001) supports to the point that supported Cu particles exhibit different charge states, which opens a way to control the reactivity of these potential catalysts.« less

  8. Macrostructure-dependent photocatalytic property of high-surface-area porous titania films

    SciTech Connect (OSTI)

    Kimura, T.

    2014-11-01

    Porous titania films with different macrostructures were prepared with precise control of condensation degree and density of the oxide frameworks in the presence of spherical aggregates of polystyrene-block-poly(oxyethylene) (PS-b-PEO) diblock copolymer. Following detailed explanation of the formation mechanisms of three (reticular, spherical, and large spherical) macrostructures by the colloidal PS-b-PEO templating, structural variation of the titania frameworks during calcination were investigated by X-ray diffraction and X-ray photoelectron spectroscopy. Then, photocatalytic performance of the macroporous titania films was evaluated through simple degradation experiments of methylene blue under an UV irradiation. Consequently, absolute surface area of the film and crystallinity of the titania frameworks were important for understanding the photocatalytic performance, but the catalytic performance can be improved further by the macrostructural design that controls diffusivity of the targeted molecules inside the film and their accessibility to active sites.

  9. Multicycle rapid thermal annealing optimization of Mg-implanted GaN: Evolution of surface, optical, and structural properties

    SciTech Connect (OSTI)

    Greenlee, Jordan D.; Feigelson, Boris N.; Anderson, Travis J.; Hite, Jennifer K.; Mastro, Michael A.; Eddy, Charles R.; Hobart, Karl D.; Kub, Francis J.; Tadjer, Marko J.

    2014-08-14

    The first step of a multi-cycle rapid thermal annealing process was systematically studied. The surface, structure, and optical properties of Mg implanted GaN thin films annealed at temperatures ranging from 900 to 1200?C were investigated by Raman spectroscopy, photoluminescence, UV-visible spectroscopy, atomic force microscopy, and Nomarski microscopy. The GaN thin films are capped with two layers of in-situ metal organic chemical vapor deposition -grown AlN and annealed in 24 bar of N{sub 2} overpressure to avoid GaN decomposition. The crystal quality of the GaN improves with increasing annealing temperature as confirmed by UV-visible spectroscopy and the full widths at half maximums of the E{sub 2} and A{sub 1} (LO) Raman modes. The crystal quality of films annealed above 1100?C exceeds the quality of the as-grown films. At 1200?C, Mg is optically activated, which is determined by photoluminescence measurements. However, at 1200?C, the GaN begins to decompose as evidenced by pit formation on the surface of the samples. Therefore, it was determined that the optimal temperature for the first step in a multi-cycle rapid thermal anneal process should be conducted at 1150?C due to crystal quality and surface morphology considerations.

  10. Forecasting the response of Earth's surface to future climatic and land use changes: A review of methods and research needs

    SciTech Connect (OSTI)

    Pelletier, Jon D.; Murray, A. Brad; Pierce, Jennifer L.; Bierman, Paul R.; Breshears, David D.; Crosby, Benjamin T.; Ellis, Michael; Foufoula-Georgiou, Efi; Heimsath, Arjun M.; Houser, Chris; Lancaster, Nick; Marani, Marco; Merritts, Dorothy J.; Moore, Laura J.; Pederson, Joel L.; Poulos, Michael J.; Rittenour, Tammy M.; Rowland, Joel C.; Ruggiero, Peter; Ward, Dylan J.; Wickert, Andrew D.; Yager, Elowyn M.

    2015-07-14

    In the future, Earth will be warmer, precipitation events will be more extreme, global mean sea level will rise, and many arid and semiarid regions will be drier. Human modifications of landscapes will also occur at an accelerated rate as developed areas increase in size and population density. We now have gridded global forecasts, being continually improved, of the climatic and land use changes (C&LUC) that are likely to occur in the coming decades. However, besides a few exceptions, consensus forecasts do not exist for how these C&LUC will likely impact Earth-surface processes and hazards. In some cases, we have the tools to forecast the geomorphic responses to likely future C&LUC. Fully exploiting these models and utilizing these tools will require close collaboration among Earth-surface scientists and Earth-system modelers. This paper assesses the state-of-the-art tools and data that are being used or could be used to forecast changes in the state of Earth's surface as a result of likely future C&LUC. We also propose strategies for filling key knowledge gaps, emphasizing where additional basic research and/or collaboration across disciplines are necessary. The main body of the paper addresses cross-cutting issues, including the importance of nonlinear/threshold-dominated interactions among topography, vegetation, and sediment transport, as well as the importance of alternate stable states and extreme, rare events for understanding and forecasting Earth-surface response to C&LUC. Five supplements delve into different scales or process zones (global-scale assessments and fluvial, aeolian, glacial/periglacial, and coastal process zones) in detail.

  11. Forecasting the response of Earth's surface to future climatic and land use changes: A review of methods and research needs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pelletier, Jon D.; Murray, A. Brad; Pierce, Jennifer L.; Bierman, Paul R.; Breshears, David D.; Crosby, Benjamin T.; Ellis, Michael; Foufoula-Georgiou, Efi; Heimsath, Arjun M.; Houser, Chris; et al

    2015-07-14

    In the future, Earth will be warmer, precipitation events will be more extreme, global mean sea level will rise, and many arid and semiarid regions will be drier. Human modifications of landscapes will also occur at an accelerated rate as developed areas increase in size and population density. We now have gridded global forecasts, being continually improved, of the climatic and land use changes (C&LUC) that are likely to occur in the coming decades. However, besides a few exceptions, consensus forecasts do not exist for how these C&LUC will likely impact Earth-surface processes and hazards. In some cases, we havemore » the tools to forecast the geomorphic responses to likely future C&LUC. Fully exploiting these models and utilizing these tools will require close collaboration among Earth-surface scientists and Earth-system modelers. This paper assesses the state-of-the-art tools and data that are being used or could be used to forecast changes in the state of Earth's surface as a result of likely future C&LUC. We also propose strategies for filling key knowledge gaps, emphasizing where additional basic research and/or collaboration across disciplines are necessary. The main body of the paper addresses cross-cutting issues, including the importance of nonlinear/threshold-dominated interactions among topography, vegetation, and sediment transport, as well as the importance of alternate stable states and extreme, rare events for understanding and forecasting Earth-surface response to C&LUC. Five supplements delve into different scales or process zones (global-scale assessments and fluvial, aeolian, glacial/periglacial, and coastal process zones) in detail.« less

  12. Single Dirac Cone Topological Surface State and Unusual Thermoelectric Property of Compounds from a New Topological Insulator Family

    SciTech Connect (OSTI)

    Chen, Y

    2011-08-18

    Angle resolved photoemission spectroscopy (ARPES) study on TlBiTe2 and TlBiSe2 from a Thallium-based III-V-VI2 ternary chalcogenides family revealed a single surface Dirac cone at the center of the Brillouin zone for both compounds. For TlBiSe{sub 2}, the large bulk gap ({approx} 200meV) makes it a topological insulator with better mechanical properties than the previous binary 3D topological insualtor family. For TlBiTe{sub 2}, the observed negative bulk gap indicates it as a semi-metal, rather than a narrow gap semi-conductor as conventionally believed; this semi-metality naturally explains its mysteriously small thermoelectric figure of merit comparing to other compounds in the family. Finally, the unique band structures of TlBiTe{sub 2} also suggests it as a candidate for topological superconductors.

  13. Effect of doping on growth and field emission properties of spherical carbon nanotube tip placed over cylindrical surface

    SciTech Connect (OSTI)

    Santolia, Isha; Tewari, Aarti; Sharma, Suresh C.; Sharma, Rinku

    2014-06-15

    Theoretical investigations to study the effect of doping of hetero-atoms on the growth and field emission properties of Carbon Nanotubes (CNTs) tip placed over a cylindrical surface in complex plasma have been carried out. A theoretical model incorporating kinetics of plasma species such as electron, ions, and neutral atoms including doping elements like nitrogen (N) and boron (B) and energy balance of CNTs in a complex plasma has been developed. The effect of doping elements of N and B on the growth of CNTs, namely, the tip radius has been carried out for typical glow discharge plasma parameters. It is found that N and B as doping elements affect the radius of CNTs extensively. We obtain small radii of CNT doped with N and large radius of CNT doped with B. The field emission characteristics from CNTs have therefore been suggested on the basis of results obtained. Some of theoretical results are in compliance with the existing experimental observations.

  14. Determination of elastic properties of a MnO{sub 2} coating by surface acoustic wave velocity dispersion analysis

    SciTech Connect (OSTI)

    Sermeus, J.; Glorieux, C.; Sinha, R.; Vereecken, P. M.; Vanstreels, K.

    2014-07-14

    MnO{sub 2} is a material of interest in the development of high energy-density batteries, specifically as a coating material for internal 3D structures, thus ensuring rapid energy deployment. Its electrochemical properties have been mapped extensively, but there are, to the best of the authors' knowledge, no records of the elastic properties of thin film MnO{sub 2}. Impulsive stimulated thermal scattering (ISTS), also known as the heterodyne diffraction or transient grating technique, was used to determine the Young's modulus (E) and porosity (?) of a 500?nm thick MnO{sub 2} coating on a Si(001) substrate. ISTS is an all optical method that is able to excite and detect surface acoustic waves (SAWs) on opaque samples. From the measured SAW velocity dispersion, the Young's modulus and porosity were determined to be E?=?25??1?GPa and ?=421%, respectively. These values were confirmed by independent techniques and determined by a most-squares analysis of the carefully fitted SAW velocity dispersion. This study demonstrates the ability of the presented technique to determine the elastic parameters of a thin, porous film on an anisotropic substrate.

  15. Pulsed laser-induced oxygen deficiency at TiO{sub 2} surface: Anomalous structure and electrical transport properties

    SciTech Connect (OSTI)

    Nakajima, Tomohiko; Tsuchiya, Tetsuo; Kumagai, Toshiya

    2009-09-15

    We have studied pulsed laser-induced oxygen deficiencies at rutile TiO{sub 2} surfaces. The crystal surface was successfully reduced by excimer laser irradiation, and an oxygen-deficient TiO{sub 2-{delta}} layer with 160 nm thickness was formed by means of ArF laser irradiation at 140 mJ/cm{sup 2} for 2000 pulses. The TiO{sub 2-{delta}} layer fundamentally maintained a rutile structure, though this structure was distorted by many stacking faults caused by the large oxygen deficiency. The electrical resistivity of the obtained TiO{sub 2-{delta}} layer exhibited unconventional metallic behavior with hysteresis. A metal-insulator transition occurred at 42 K, and the electrical resistivity exceeded 10{sup 4} OMEGA cm below 42 K. This metal-insulator transition could be caused by bipolaronic ordering derived from Ti-Ti pairings that formed along the stacking faults. The constant magnetization behavior observed below 42 K is consistent with the bipolaronic scenario that has been observed previously for Ti{sub 4}O{sub 7}. These peculiar electrical properties are strongly linked to the oxygen-deficient crystal structure, which contains many stacking faults formed by instantaneous heating during excimer laser irradiation. - Graphical abstract: A pulsed laser-irradiated TiO{sub 2-{delta}} substrate showed an unconventional metallic phase, with hysteresis over a wide range of temperatures and a metal-insulator transition at 42 K.

  16. Fuels for Advanced Combustion Engines Research Diesel Fuels: Analysis of Physical and Chemical Properties

    SciTech Connect (OSTI)

    Gallant, Tom; Franz, Jim; Alnajjar, Mikhail; Storey, John Morse; Lewis Sr, Samuel Arthur; Sluder, Scott; Cannella, William C; Fairbridge, Craig; Hager, Darcy; Dettman, Heather; Luecke, Jon; Ratcliff, Matthew A.; Zigler, Brad

    2009-01-01

    The CRC Fuels for Advanced Combustion Engines working group has worked to identify a matrix of research diesel fuels for use in advanced combustion research applications. Nine fuels were specified and formulated to investigate the effects of cetane number aromatic content and 90% distillation fraction. Standard ASTM analyses were performed on the fuels as well as GC/MS and /u1H//u1/u3C NMR analyses and thermodynamic characterizations. Details of the actual results of the fuel formulations compared with the design values are presented, as well as results from standard analyses, such as heating value, viscosity and density. Cetane number characterizations were accomplished by using both the engine method and the Ignition Quality Tester (IQT/sT) apparatus.

  17. The relationship between hydroxyl groups on oxide surfaces and the properties of supported metals. Progress report, June 1, 1992--January 31, 1994

    SciTech Connect (OSTI)

    Schwarz, J.A.

    1994-05-01

    Supported metal catalysts are commonly prepared by depositing catalytic precursors from aqueous solutions of electrolytes onto high surface area oxides. A general conclusion of our previous studies was that the performance of the finished catalyst depends on the characteristic properties of the hydroxyl inventory on the surface of the oxide support, both in wet and in (pseudo)-dry conditions. Hydroxyl groups serve as adsorption or exchange sites during catalyst preparation. On the other hand, the configuration of hydroxyl groups still remaining on oxides after dehydration determines the acid-base characteristics of the catalyst, which is an important catalytic property. The purpose of the investigation is to characterize the relationship between the complex inventory of hydroxyl groups at oxide surfaces, the acid-base properties of oxides (both in aqueous solution and in the pseudo-dry state) and the resultant effects on the properties of catalytic materials formed by adsorption/impregnation onto these hydroxylated supports during catalyst preparation. We use a common crystallographic model to describe the local configuration of hydroxyl groups on both the pseudo-dry surface and -the oxide/aqueous solution interface. This allows us to extend the concept of structurally determined intrinsic heterogeneity of pseudo-dry surfaces (as already known from the IR spectra of isolated surface hydroxyls) to the oxide/solution interface. We examine the consequences of that heterogeneity upon the impregnation step during catalyst preparation.

  18. Property

    Energy Savers [EERE]

    ER-B-98-07 AUDIT REPORT PERSONAL PROPERTY AT THE OAK RIDGE OPERATIONS OFFICE AND THE OFFICE OF SCIENTIFIC AND TECHNICAL INFORMATION U.S. DEPARTMENT OF ENERGY OFFICE OF INSPECTOR GENERAL OFFICE OF AUDIT SERVICES APRIL 1998 Page 10 DEPARTMENT OF ENERGY Washington, DC 20585 April 6, 1998 MEMORANDUM FOR THE MANAGER, OAK RIDGE OPERATIONS OFFICE AND THE DIRECTOR, OFFICE OF SCIENTIFIC AND TECHNICAL INFORMATION FROM: Terry L. Brendlinger Eastern Regional Audit Office Office of Inspector General SUBJECT:

  19. Research on the electronic and optical properties of polymer and other organic molecular thin films

    SciTech Connect (OSTI)

    1997-02-01

    The main goal of the work is to find materials and methods of optimization of organic layered electroluminescent cells and to study such properties of polymers and other organic materials that can be used in various opto-electronic devices. The summary of results obtained during the first year of work is presented. They are: (1) the possibility to produce electroluminescent cells using a vacuum deposition photoresist technology for commercial photoresists has been demonstrated; (2) the idea to replace the polyaryl polymers by other polymers with weaker hole conductivity for optimization of electroluminescent cells with ITO-Al electrodes has been suggested. The goal is to obtain amorphous processable thin films of radiative recombination layers in electroluminescent devices; (3) procedures of preparation of high-quality vacuum-deposited poly (p-phenylene) (PPP) films on various substrates have been developed; (4) it was found for the first time that the fluorescence intensity of PPP films depends on the degree of polymerization; (5) the role of interfaces between organic compounds, on one side, and metals or semiconductors, on the other side, has been studied and quenching of the fluorescence caused by semiconductor layer in thin sandwiches has been observed; (6) studies of the dynamics of photoexcitations revealed the exciton self-trapping in quasi-one-dimensional aggregates; and (7) conditions for preparation of highly crystalline fullerene C{sub 60} films by vacuum deposition have been found. Composites of C{sub 60} with conjugated polymers have been prepared.

  20. Current status, research needs, and opportunities in applications of surface processing to transportation and utilities technologies. Proceedings of a December 1991 workshop

    SciTech Connect (OSTI)

    Czanderna, A.W.; Landgrebe, A.R.

    1992-09-01

    Goal of surface processing is to develop innovative methods of surface modification and characterization for optimum performance and environmental protection for cost-effective operational lifetimes of systems, materials, and components used in transportation and utilities. These proceedings document the principal discussions and conclusions reached at the workshop; they document chapters about the current status of surface characterization with focus on composition, structure, bonding, and atomic-scale topography of surfaces. Also documented are chapters on the current status of surface modification techniques: electrochemical, plasma-aided, reactive and nonreactive physical vapor deposition, sol-gel coatings, high-energy ion implantation, ion-assisted deposition, organized molecular assemblies, solar energy. Brief chapters in the appendices document basic research in surface science by NSF, Air Force, and DOE. Participants at the workshop were invited to serve on 10 working groups. Separate abstracts were prepared for the data base where appropriate.

  1. Intermolecular potential energy surface and thermophysical properties of the CH{sub 4}N{sub 2} system

    SciTech Connect (OSTI)

    Hellmann, Robert Bich, Eckard; Vogel, Eckhard; Vesovic, Velisa

    2014-12-14

    A five-dimensional potential energy surface (PES) for the interaction of a rigid methane molecule with a rigid nitrogen molecule was determined from quantum-chemical ab initio calculations. The counterpoise-corrected supermolecular approach at the CCSD(T) level of theory was utilized to compute a total of 743 points on the PES. The interaction energies were calculated using basis sets of up to quadruple-zeta quality with bond functions and were extrapolated to the complete basis set limit. An analytical site-site potential function with nine sites for methane and five sites for nitrogen was fitted to the interaction energies. The PES was validated by calculating the cross second virial coefficient as well as the shear viscosity and binary diffusion coefficient in the dilute-gas limit for CH{sub 4}N{sub 2} mixtures. An improved PES was obtained by adjusting a single parameter of the analytical potential function in such a way that quantitative agreement with the most accurate experimental values of the cross second virial coefficient was achieved. The transport property values obtained with the adjusted PES are in good agreement with the best experimental data.

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosol Effects on Liquid-Water Path of Thin Stratocumulus Clouds Download a printable PDF Submitter: Penner, J. E., University of Michigan Lee, S., University of Michigan Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: n/a Thin clouds with mean liquid-water path (LWP) of ~ 50 g m-2 cover 27.5% of the globe and thus play an important role in the Earth's radiation budget. Radiative fluxes at the Earth's surface and top of atmosphere (TOA) are very sensitive to

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mixed-Phase Cloud Radiative Properties from M-PACE Microphysical Retrievals Download a printable PDF Submitter: de Boer, G., University of Colorado, Boulder/CIRES Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: de Boer G, WD Collins, S Menon, and CN Long. 2011. "Using surface remote sensors to derive radiative characteristics of mixed-phase clouds: An example from M-PACE." Atmospheric Chemistry and Physics, 11, doi: 10.5194/acp-11-11937-2011.

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Seasonal and Interannual Variability in 13C of Ecosystem Carbon Fluxes from 2002-2009 Submitter: Torn, M. S., Lawrence Berkeley National Laboratory Area of Research: Surface Properties Working Group(s): Aerosol Life Cycle Journal Reference: Torn MS, SC Biraud, CJ Still, WJ Riley, and JA Berry. 2011. "Seasonal and inter-annual variability in δ13C of net ecosystem carbon exchanges from 2002-2009 in the U.S. Southern Great Plains." Tellus, 63(2), 10.1111/j.1600-0889.2010.00519.x. Time

  5. Superhydrophobic surfaces

    DOE Patents [OSTI]

    Wang, Evelyn N; McCarthy, Matthew; Enright, Ryan; Culver, James N; Gerasopoulos, Konstantinos; Ghodssi, Reza

    2015-03-24

    Surfaces having a hierarchical structure--having features of both microscale and nanoscale dimensions--can exhibit superhydrophobic properties and advantageous condensation and heat transfer properties. The hierarchical surfaces can be fabricated using biological nanostructures, such as viruses as a self-assembled nanoscale template.

  6. Effects of surface properties on barrier height and barrier inhomogeneities of platinum contacts to n-type 4H-SiC

    SciTech Connect (OSTI)

    Huang Lingqin; Li Shijuan; Wang Dejun [School of Electronic Science and Technology, Faculty of Electronic Information and Electrical Engineering, Dalian University of Technology, Dalian 116024 (China); Qin Fuwen [State Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), Dalian University of Technology, Dalian 116024 (China)

    2013-07-15

    We investigated the Schottky barrier of Pt/4H-SiC contact as a function of 4H-SiC surface properties which effectively controlled by electronic cyclotron resonance hydrogen plasma pretreatment for different periods and annealing. It is found that the effective barrier height monotonically increases with decreasing the degree of Fermi level pinning. Electrically homogeneous contacts are observed when the Fermi level (FL) is 'pinned (Bardeen limit)' and 'free-pinned (Schottky limit).' However, a partial pinning of FL leads to Gaussian distribution of inhomogeneous barrier height. These results could be correlated with changes in the magnitude and spatial distribution of surface state density after different pretreatments.

  7. Influence of particle size and water coverage on the thermodynamic properties of water confined on the surface of SnO2 cassiterite nanoparticles

    SciTech Connect (OSTI)

    Spencer, Elinor; Ross, Dr. Nancy; Parker, Stewart F.; Kolesnikov, Alexander I; Woodfield, Brian; Woodfield, K; Rytting, M; Boerio-Goates, Juliana; Navrotsky, Alexandra

    2011-01-01

    Inelastic neutron scattering (INS) data for SnO2 nanoparticles of three different sizes and varying hydration levels are presented. Data were recorded on five nanoparticle samples that had the following compositions: 2 nm SnO2*0.82H2O, 6 nm SnO2*0.055H2O, 6 nm SnO2*0.095H2O, 20 nm SnO2*0.072H2O, and 20 nm SnO2*0.092H2O. The isochoric heat capacity and vibrational entropy values at 298 K for the water confined on the surface of these nanoparticles were calculated from the vibrational density of states that were extracted from the INS data. This study has shown that the hydration level of the SnO2 nanoparticles influences the thermodynamic properties of the water layers and, most importantly, that there appears to be a critical size limit for SnO2 between 2 and 6 nm below which the particle size also affects these properties and above which it does not. These results have been compared with those for isostructural rutile-TiO2 nanoparticles [TiO2*0.22H2O and TiO2*0.37H2O], which indicated that water on the surface of TiO2 nanoparticles is more tightly bound and experiences a greater degree of restricted motion with respect to water on the surface of SnO2 nanoparticles. This is believed to be a consequence of the difference in chemical composition, and hence surface properties, of these metal oxide nanoparticles.

  8. Uncertainty quantification for evaluating impacts of caprock and reservoir properties on pressure buildup and ground surface displacement during geological CO2 sequestration

    SciTech Connect (OSTI)

    Bao, Jie; Hou, Zhangshuan; Fang, Yilin; Ren, Huiying; Lin, Guang

    2013-08-12

    A series of numerical test cases reflecting broad and realistic ranges of geological formation properties was developed to systematically evaluate and compare the impacts of those properties on geomechanical responses to CO2 injection. A coupled hydro-geomechanical subsurface transport simulator, STOMP (Subsurface Transport over Multiple Phases), was adopted to simulate the CO2 migration process and geomechanical behaviors of the surrounding geological formations. A quasi-Monte Carlo sampling method was applied to efficiently sample a high-dimensional parameter space consisting of injection rate and 14 subsurface formation properties, including porosity, permeability, entry pressure, irreducible gas and aqueous saturation, Youngs modulus, and Poissons ratio for both reservoir and caprock. Generalized cross-validation and analysis of variance methods were used to quantitatively measure the significance of the 15 input parameters. Reservoir porosity, permeability, and injection rate were found to be among the most significant factors affecting the geomechanical responses to the CO2 injection. We used a quadrature generalized linear model to build a reduced-order model that can estimate the geomechanical response instantly instead of running computationally expensive numerical simulations. The injection pressure and ground surface displacement are often monitored for injection well safety, and are believed can partially reflect the risk of fault reactivation and seismicity. Based on the reduced order model and response surface, the input parameters can be screened for control the risk of induced seismicity. The uncertainty of the subsurface structure properties cause the numerical simulation based on a single or a few samples does not accurately estimate the geomechanical response in the actual injection site. Probability of risk can be used to evaluate and predict the risk of injection when there are great uncertainty in the subsurface properties and operation conditions.

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Submitter: Westwater, E. R., University of Colorado Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Properties Journal Reference:...

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liljegren, J. C., Argonne National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Properties, Radiative Processes...

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Influence of Dust Composition on Cloud Droplet Formation Download a printable PDF Submitter: Chuang, C., Lawrence Livermore National Laboratory Area of Research: Aerosol Properties...

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lovejoy, S., McGill University Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Properties Journal Reference: Lovejoy, S., D....

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of MBL Cloud Properties over the Azores Download a printable PDF Submitter: Dong, X., University of North Dakota Area of Research: Radiation Processes Working Group(s): Cloud...

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Production Flux of Sea-Spray Aerosol Download a printable PDF Submitter: Schwartz, S. E., Brookhaven National Laboratory Area of Research: Aerosol Properties Working Group(s):...

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosols Help Heat Up the Yangtze River Delta in China Download a printable PDF Submitter: Flynn, C. J., Pacific Northwest National Laboratory Area of Research: Aerosol Properties...

  16. ARM - Measurement - Sea surface temperature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sea surface temperature The temperature of sea water near the surface. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the...

  17. Tailoring surface properties and structure of layered double hydroxides using silanes with different number of functional groups

    SciTech Connect (OSTI)

    Tao, Qi; He, Hongping; Li, Tian; Frost, Ray L.; Zhang, Dan; He, Zisen

    2014-05-01

    Four silanes, trimethylchlorosilane (TMCS), dimethyldiethoxylsilane (DMDES), 3-aminopropyltriethoxysilane (APTES) and tetraethoxysilane (TEOS), were adopted to graft layered double hydroxides (LDH) via an induced hydrolysis silylation method (IHS). Fourier transform infrared spectra (FTIR) and {sup 29}Si MAS nuclear magnetic resonance spectra ({sup 29}Si MAS NMR) indicated that APTES and TEOS can be grafted onto LDH surfaces via condensation with hydroxyl groups of LDH, while TMCS and DMDES could only be adsorbed on the LDH surface with a small quantity. A combination of X-ray diffraction patterns (XRD) and {sup 29}Si MAS NMR spectra showed that silanes were exclusively present in the external surface and had little influence on the long range order of LDH. The surfactant intercalation experiment indicated that the adsorbed and/or grafted silane could not fix the interlamellar spacing of the LDH. However, they will form crosslink between the particles and affect the further surfactant intercalation in the silylated samples. The replacement of water by ethanol in the tactoids and/or aggregations and the polysiloxane oligomers formed during silylation procedure can dramatically increase the value of BET surface area (S{sub BET}) and total pore volumes (V{sub p}) of the products. - Graphical abstract: The replacement of water by ethanol in the tactoids and aggregations of LDHs, and the polysiloxane oligomers formed during silylation process can dramatically increase the BET surface area (S{sub BET}) and the total pore volume (V{sub p}) of the silylated products. - Highlights: Silanes with multifunctional groups were grafted onto LDH surface in C{sub 2}H{sub 5}OH medium. The number of hydrolysable groups in silanes affects the structure of grafted LDH. Replacement of H{sub 2}O by C{sub 2}H{sub 5}OH in aggregations increases S{sub BET} and V{sub p} of grafted LDH. Polysiloxane oligomers contribute to the increase of S{sub BET} and V{sub p} of grafted LDH.

  18. PROCESSING, MICROSTRUCTURE AND MECHANICAL PROPERTY CORRELATION IN Al-B4C SURFACE COMPOSITE PRODUCED VIA FRICTION STIR PROCESSING

    SciTech Connect (OSTI)

    Komarasamy, Mageshwari; Mishra, Rajiv S.; Baumann, John A.; Grant, Glenn J.; Hovanski, Yuri

    2013-01-29

    Friction stir processing (FSP) was employed to prepare surface composites (SC) composed of B4C particles in 5024 Al matrix. The processing parameters, such as hole pattern and geometry,and the number of FSP passes, were optimized to obtain uniform powder distribution. The micrographs revealed a homogeneous distribution of the particles with good interfacial bonding. The hardness of the composite was uniform across the processed region which again indicates the uniformity of powder distribution. The modulus of the surface composite was measured using strain gage and showed a significant improvement. This improvement in modulus lies in the load sharing capability from the soft matrix to the hard particles.

  19. The role of precipitation size distributions in km-scale NWP simulations of intense precipitation: Evaluation of cloud properties and surface precipitation

    SciTech Connect (OSTI)

    VanWeverberg K.; Vogelmann A.; vanLipzig, N. P. M.; Delobbec, L.

    2012-04-01

    We investigate the sensitivity of simulated cloud properties and surface precipitation to assumptions regarding the size distributions of the precipitating hydrometeors in a one-moment bulk microphysics scheme. Three sensitivity experiments were applied to two composites of 15 convective and 15 frontal stratiform intense precipitation events observed in a coastal midlatitude region (Belgium), which were evaluated against satellite-retrieved cloud properties and radar-rain-gauge derived surface precipitation. It is found that the cloud optical thickness distribution was well captured by all experiments, although a significant underestimation of cloudiness occurred in the convective composite. The cloud-top-pressure distribution was improved most by more realistic snow size distributions (including a temperature-dependent intercept parameter and non-spherical snow for the calculation of the slope parameter), due to increased snow depositional growth at high altitudes. Surface precipitation was far less sensitive to whether graupel or hail was chosen as the rimed ice species, as compared to previous idealized experiments. This smaller difference in sensitivity could be explained by the stronger updraught velocities and higher freezing levels in the idealized experiments compared to typical coastal midlatitude environmental conditions.

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SGP Observations Help Validate Soil Temperature Simulations Download a printable PDF Submitter: Huang, M., Pacific Northwest National Laboratory Area of Research: Surface...

  1. U.S. Department of Energy (DOE)--Surface Biogeochemical Research (SBR) 6th Annual PI Meeting: Abstracts

    SciTech Connect (OSTI)

    Hazen Ed., T.C.

    2011-04-11

    On behalf of the Subsurface Biogeochemical Research (SBR) program managers in the Climate and Environmental Sciences Division (CESD), Office of Biological and Environmental Research (BER), welcome to the 2011 SBR Principal Investigators meeting. Thank you in advance for your attendance and your presentations at this year's meeting. As the events in Japan continue to unfold, we are all reminded that the research we perform on radionuclide behavior in the environment has implications beyond legacy waste cleanup and in fact has its place in the discussion on the expanded use of nuclear power. As in the past, there are three broad objectives to the Principal Investigators meeting: (1) to provide opportunities to share research results and promote interactions among the SBR scientists and other invited guests; (2) to evaluate the progress of each project within the program; and (3) to showcase the scientific expertise and research progress over the past year to senior managers within the DOE Office of Science, the technology offices within DOE, and other invited attendees from other Federal Agencies. This past year has seen a few significant changes within BER and within the SBR program. In November, our Associate Director for BER, Anna Palmisano, retired from Federal service. Just this month, Dr. Sharlene Weatherwax (Division Director for Biological Systems Sciences) has been named as the new Associate Director for BER. In August, BER welcomed Dr. Gary Geernaert as the new Division Director for CESD. Gary joins the division from Los Alamos National Laboratory with a background in atmospheric science. Within the SBR program, a new Strategic Plan was completed last June (currently posted on the SBR and the Office of Science website). The new strategic plan is intended to foster integration within the Environmental Systems Science portion of the BER budget that includes both SBR and Terrestrial Ecosystem Sciences (TES). Both these programs share a goal of advancing a predictive understanding of environmental processes and utilizing iterative, multidisciplinary approaches to understand complex environmental systems of relevance to DOE. CESD in general is undergoing continued discussions on integration among its programs in an effort to develop a new strategic plan for the division. This effort also includes identifying opportunities for integration with BER's Biological Systems Science Division (BSSD). The program this year includes three poster presentation sessions, six plenary sessions, and three breakout sessions. The plenary session on Tuesday morning will feature introductory presentations by BER program staff and three keynote addresses from Dr. Ken Bencala (USGS), Dr. Michael (Mick) Follows (MIT) and Dr. Sue Brantley (PSU) that will lead into three breakout sessions Tuesday afternoon. The breakout sessions are intended to highlight key developments in SBR research and foster a dialog among session participants on scientific paths forward in each particular area. The SBR program managers are asking for input from the SBR community at these sessions to help guide future efforts and/or identify areas of integration within BER programs. On Wednesday, plenary sessions will continue in the morning, followed by an early afternoon poster session. After an extended break for lunch, plenary sessions will continue in the afternoon, followed by an evening poster session. Thursday's plenary session will focus on selected highlights of research efforts at the IFRC sites and on a new potential TES field effort in the Arctic. This new field site is an obvious point of integration between the SBR and TES programs.

  2. Surface and Interfacial Properties of Nonaqueous-Phase Liquid Mixtures Released to the Subsurface at the Hanford Site

    SciTech Connect (OSTI)

    Nellis, Scott; Yoon, Hongkyu; Werth, Charlie; Oostrom, Martinus; Valocchi, Albert J.

    2009-05-01

    Surface and interfacial tensions that arise at the interface between different phases are key parameters affecting Nonaqueous Phase Liquid (NAPL) movement and redistribution in the vadose zone after spill events. In this study, the impact of major additive components on surface and interfacial tensions for organic mixtures and wastewater was investigated. Organic mixture and wastewater compositions are based upon carbon tetrachloride (CT) mixtures released at the Hanford site, where CT was discharged simultaneously with dibutyl butyl phosphonate (DBBP), tributyl phosphate (TBP), dibutyl phosphate (DBP), and a machining lard oil (LO). A considerable amount of wastewater consisting primarily of nitrates and metal salts was also discharged. The tension values measured in this study revealed that the addition of these additive components caused a significant lowering of the interfacial tension with water or wastewater and the surface tension of the wastewater phase in equilibrium with the organic mixtures, compared to pure CT, but had minimal effect on the surface tension of the NAPL itself. These results lead to large differences in spreading coefficients for several mixtures, where the additives caused both a higher (more spreading) initial spreading coefficient and a lower (less spreading) equilibrium spreading coefficient. This indicates that if these mixtures migrate into uncontaminated areas, they will tend to spread quickly, but form a higher residual NAPL saturation after equilibrium, as compared to pure CT. Over time, CT likely volatilizes more rapidly than other components in the originally disposed mixtures and the lard oil and phosphates would become more concentrated in the remaining NAPL, resulting in a lower interfacial tension for the mixture. Spreading coefficients are expected to increase and perhaps change the equilibrated organic mixtures from nonspreading to spreading in water-wetting porous media. These results show that the behavior of organic chemical mixtures should be accounted for in numerical flow and transport models.

  3. Early Career. Harnessing nanotechnology for fusion plasma-material interface research in an in-situ particle-surface interaction facility

    SciTech Connect (OSTI)

    Allain, Jean Paul

    2014-08-08

    This project consisted of fundamental and applied research of advanced in-situ particle-beam interactions with surfaces/interfaces to discover novel materials able to tolerate intense conditions at the plasma-material interface (PMI) in future fusion burning plasma devices. The project established a novel facility that is capable of not only characterizing new fusion nanomaterials but, more importantly probing and manipulating materials at the nanoscale while performing subsequent single-effect in-situ testing of their performance under simulated environments in fusion PMI.

  4. Water adsorption onto Y and V sites at the surface of the YVO{sub 4} photocatalyst and related electronic properties

    SciTech Connect (OSTI)

    Oshikiri, Mitsutake; Matsushita, Akiyuki; Ye, Jinhua; Boero, Mauro

    2009-07-21

    The dynamics of water molecules and the adsorption properties at the V and Y sites on the surface of the photocatalyst YVO{sub 4} have been investigated by first principles molecular dynamics. This system has shown an excellent performance in the production of both hydrogen and oxygen in the ultraviolet region. Yet, its catalytic properties, related to the electronic structure, are poorly understood. Here we show that imperfectly oxygen coordinated V sites (i.e., not fourfold oxygen coordinated vanadium but threefold oxygen coordinated vanadium) exposed on the catalyst surface play a central role in the dissociation of water molecules. By simulating the H{sub 2}O adsorption process and by performing an analysis of the electronic structure of the unoccupied orbitals corresponding to the lowest unoccupied energy level of the system, we can infer that the dissociation of water at these imperfectly oxygen coordinated V sites can promote the proton reduction and is expected to trigger the H{sub 2} generation.

  5. New Analysis Methods Estimate a Critical Property of Ethanol Fuel Blends (Fact Sheet), Highlights in Research & Development, NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methods developed at NREL disclose the impact of ethanol on gasoline blend heat of vaporization with potential for improved efficiency of spark-ignition engines. More stringent standards for fuel economy, regulation of greenhouse gas emissions, and the mandated increase in the use of renew- able fuel are driving research to improve the efficiency of spark ignition engines. When fuel properties such as octane number and evaporative cooling (heat of vaporization or HOV) are insufficient, they

  6. Research on thermophoretic and inertial aspects of ash particle deposition on heat exchanger surfaces in coal-fired equipment

    SciTech Connect (OSTI)

    Rosner, D.E.

    1988-12-01

    A real-time laser light-reflectivity technique is being used to study simultaneous thermophoretic and inertial influences on the deposition behavior of MgO particles produced via ultrasonic nebulization (submicrometer range). The deposition surface (a concave platinum ribbon) is exposed to a high velocity/temperature jet of alkali sulfate-free combustion products exiting from a seeded (C3[sub 3]H[sub 8]/air) microcombustor (110 cm[sup 3]). The reflectivity data were calibrated against deposition rates obtained from SEM pictures of the target, and were normalized with the nominal particle feed rate, in order to obtain the mass transfer Stanton number, St[sub m], trends depicted in Figure 1. For the submicron (ca. 0.7[mu]m) particles inertial effects appear to set in at Stokes (Stk) numbers of O(10[sup [minus]2]) (an order of magnitude lower than the ones needed for pure'' inertial impaction), affecting significantly the dominant thermophoretic deposition mechanism. A first order (in Stk) theoretical analysis of the problem in which particle inertia is treated as equivalent to pressure diffusion,'' cannot explain the observed dependence of the deposition rate on Stk. We are presently formulating a Lagrangian approach, valid for all values of Stk, in order to interpret these data. In addition, a Single Particle Counter (SPC) and Transit Time Velocimeter (TTV), are being developed, to allow more precise measurements of particle feed rates and velocities.

  7. Investigation of Cathode Electrocatalytic Activity using Surface Engineered Thin Film Samples and High Temperature Physical Property Measurements

    SciTech Connect (OSTI)

    Salvador, Paul

    2014-02-23

    In this Final Technical Report, a summary of the technical output from the award DE-NT0004105 is given. First, the major goals and observations from the project are reviewed and then specific example results are presented as highlights. The surprising importance of microstructure on the surface chemical exchange coefficient in La0.7Sr0.3MnO3 (LSM) was uncovered in this work and is re-emphasized in this report. Significant orientation and thickness dependencies of the surface exchange coefficient are correlated with microstructural effects, especially to the nature of the strain, dislocation content, and grain boundary population. We also illustrate similar microstructural effects are present in other SOFC cathode systems, including LSCF (La1-xSrxCo1-yFeyO3) and La2NiO4 (LNO). Throughout the report, the relation to SOFC cathode performance is discussed.

  8. Effect of deuterium substitution for hydrogen in surface functionalisation of hydrophilic nanosilicon particles on their spectral and dynamic properties

    SciTech Connect (OSTI)

    Kompanets, V O; Chekalin, S V; Dorofeev, S G; Kononov, N N; Barzilovich, P Yu; Ishchenko, A A

    2014-06-30

    Broadband femtosecond spectroscopy has been used to study two types of hydrophilic silicon nanoparticles: (1) photoluminescent, passivated with deuterium and oxidised in fully deuterated dimethyl sulphoxide, and (2) nonluminescent (control samples having a similar crystalline core), passivated with hydrogen and oxidised in dimethyl sulphoxide. We have found significant differences in ultrafast spectral temporal induced absorption dynamics between the two types of nanoparticles in the energy range corresponding to their calculated band gap. The observed distinction is due to the considerably higher oxidation rate of silicon on the surface of the deuterated samples in comparison with the undeuterated ones and with the associated increase in the number of photoluminescence centres on the surface of the nanoparticles. In the samples containing self-trapped exciton (STE) energy states responsible for the photoluminescence in the red spectral region, carrier capture at these levels and carrier relaxation to the ground state have characteristic times in the femtosecond range. In the samples free of STE states, excited carriers relax to the conduction band bottom in a characteristic time of several picoseconds. (extreme light fields and their applications)

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From Fire to Ice Download a printable PDF Submitter: Kulkarni, G., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Kulkarni GR, M Nandasiri, A Zelenyuk, J Beranek, N Madaan, A Devaraj, V Shutthanandan, S Thevuthasan, and T Varga. 2015. "Effects of crystallographic properties on the ice nucleation properties of volcanic ash particles." Geophysical Research Letters, 42(8), doi:10.1002/2015GL063270. Tons of

  10. Adsorption and switching properties of a N-benzylideneaniline based molecular switch on a Au(111) surface

    SciTech Connect (OSTI)

    Ovari, Laszlo; Luo, Ying; Haag, Rainer; Leyssner, Felix; Tegeder, Petra; Wolf, Martin

    2010-07-28

    High resolution electron energy loss spectroscopy has been employed to analyze the adsorption geometry and the photoisomerization ability of the molecular switch carboxy-benzylideneaniline (CBA) adsorbed on Au(111). CBA on Au(111) adopts a planar (trans) configuration in the first monolayer (ML) as well as for higher coverages (up to 6 ML), in contrast to the strongly nonplanar geometry of the molecule in solution. Illumination with UV light of CBA in direct contact with the Au(111) surface ({<=}1 ML) caused no changes in the vibrational structure, whereas at higher coverages (>1 ML) pronounced modifications of vibrational features were observed, which we assign to a trans{yields}cis isomerization. Thermal activation induced the back reaction to trans-CBA. We propose that the photoisomerization is driven by a direct (intramolecular) electronic excitation of the adsorbed CBA molecules in the second ML (and above) analogous to CBA in the liquid phase.

  11. Effects of charge and surface ligand properties of nanoparticles on oxidative stress and gene expression within the gut of Daphnia magna

    SciTech Connect (OSTI)

    Dominguez, Gustavo A.; Lohse, Samuel E.; Torelli, Marco; Murphy, Catherine; Hamers, Robert J.; Orr, Galya; Klaper, Rebecca D.

    2015-05-01

    Concern has been raised regarding the current and future release of engineered nanomaterials into aquatic environments from industry and other sources. However, not all nanomaterials may cause an environ-mental impact and identifying which nanomaterials may be of greatest concern has been difficult. It is thought that the surface groups of a functionalized nanoparticles (NPs) may play a significant role in determining their interactions with aquatic organisms, but the way in which surface properties of NPs impact their toxicity in whole organisms has been minimally explored. A major point of interaction of NPs with aquatic organisms is in the gastrointestinal tract as they ingest particulates from the water column or from the sediment. The main goal of this study was to use model gold NP (AuNPs) to evaluate the potential effects of the different surfaces groups on NPs on the gut of an aquatic model organism, Daphnia magna. In this study, we exposed daphnids to a range of AuNPs concentrations and assessed the impact of AuNP exposure in the daphnid gut by measuring reactive oxygen species (ROS) production and expression of genes associated with oxidative stress and general cellular stress: glutathione S-transferase(gst), catalase (cat), heat shock protein 70 (hsp70), and metallothionein1 (mt1). We found ROS formation and gene expression were impacted by both charge and the specific surface ligand used. We detected some degree of ROS production in all NP exposures, but positively charged AuNPs induced a greater ROS response. Similarly, we observed that, compared to controls, both positively charged AuNPs and only one negatively AuNP impacted expression of genes associated with cellular stress. Finally, ligand-AuNP exposures showed a different toxicity and gene expression profile than the ligand alone, indicating a NP specific effect.

  12. Collider Detector at Fermilab (CDF): Data from the QCD Group's Research into Properties of the Strong Interaction

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    ,

    The Collider Detector at Fermilab (CDF) is a Tevatron experiment at Fermilab. The Tevatron, a powerful particle accelerator, accelerates protons and antiprotons close to the speed of light, and then makes them collide head-on inside the CDF detector. The CDF detector is used to study the products of such collisions. The CDF Physics Group at Fermilab is organized into six working groups, each with a specific focus. The QCD group studies the properties of the strong interaction. Their public web page makes data and numerous figures available from both CDF Runs I and II.

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Area of Research: Cloud DistributionsCharacterizations Working Group(s): Cloud Properties Journal Reference: Wang X, KN Liou, SS Ou, GG Mace, and M Deng. 2009. "Remote sensing of ...

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Detection and Retrieval of Cirrus Clouds in the Tropics from AIRS: Validation from ARM Data Submitter: Yue, Q., Jet Propulsion Laboratory/California Institute of Technology Liou, K., University of California, Los Angeles Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Yue Q and KN Liou. 2009. "Cirrus cloud optical and microphysical properties determined from AIRS infrared spectra." Geophysical Research Letters, 36, L05810,

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluation of Cloud Properties in Major Reanalyses Download a printable PDF Submitter: Liu, Y., Brookhaven National Laboratory Wu, W., Brookhaven National Laboratory Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle Journal Reference: Wu W, YG Liu, and AK Betts. 2012. "Observationally based evaluation of NWP reanalyses in modeling cloud properties over the Southern Great Plains." Journal of Geophysical Research - Atmospheres, 117, D12202,

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MBL Cloud and CCN Properties Under Coupled and Decoupled Conditions Submitter: Dong, X., University of North Dakota Area of Research: Cloud-Aerosol-Precipitation Interactions Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Dong X, A Schwantes, B Xi, and P Wu. 2015. "Investigation of the marine boundary layer cloud and CCN properties under coupled and decoupled conditions over the Azores." Journal of Geophysical Research - Atmospheres, , 1-13. ONLINE. A

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Retrieving Cloud and Aerosol Properties from the ARM Raman Lidar Download a printable PDF Submitter: Thorsen, T., NASA - Langley Research Center Fu, Q., University of Washington Area of Research: Cloud Distributions/Characterizations Working Group(s): Aerosol Life Cycle, Cloud Life Cycle Journal Reference: Thorsen TJ, Q Fu, RK Newsom, DD Turner, and JM Comstock. 2015. "Automated retrieval of cloud and aerosol properties from the ARM Raman lidar, Part I: Feature detection." Journal of

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Roles of Wind Shear at Different Vertical Levels in Cloud System Organization and Properties Download a printable PDF Submitter: Fan, J., Pacific Northwest National Laboratory Area of Research: Cloud Processes Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Chen Q, J Fan, S Hagos, W Gustafson, and L Berg. 2015. "Roles of wind shear at different vertical levels, Part I: Cloud system organization and properties." Journal of Geophysical Research -

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase State and Physical Properties of Ambient and Lab Generated Aerosols: X-ray Microscopy Download a printable PDF Submitter: OBrien, R. E., Lawrence Berkeley National Laboratory Gilles, M., Lawrence Berkeley National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: O'Brien RE, A Neu, SA Epstein, AC MacMillan, B Wang, ST Kelly, SA Nizkorodov, A Laskin, RC Moffet, and MK Gilles. 2014. "Physical properties of ambient and

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Summertime Radiative Forcing by Shallow Cumuli at the ARM SGP Download a printable PDF Submitter: Berg, L., Pacific Northwest National Laboratory Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: Berg LK, EI Kassianov, CN Long, and DL Mills. 2011. "Surface summertime radiative forcing by shallow cumuli at the ARM SGP." Journal of Geophysical Research - Atmospheres, 116, D01202, 10.1029/2010JD014593. Histogram of hourly average shortwave

  1. Evidence of incomplete annealing at 800 °C and the effects of 120 °C baking on the crystal orientation and the surface superconducting properties of cold-worked and chemically polished Nb

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sung, Z. -H.; Dzyuba, A.; Lee, P. J.; Larbalestier, D C; Cooley, L. D.

    2015-07-01

    High-purity niobium rods were cold-worked by wire-drawing, followed by various combinations of chemical polishing and high-vacuum baking at 120 °C or annealing at 800 °C in order to better understand changes to the surface superconducting properties resulting from typical superconducting radio-frequency cavity processing. AC susceptibility measurements revealed an enhanced upper transition Tc at ~ 9.3–9.4 K in all samples that was stable through all annealing steps, a value significantly above the accepted Tc of 9.23 K for pure annealed niobium. Corresponding elevations were seen in the critical fields, the ratio of the surface critical field Hc3 to the bulk uppermore » critical field Hc2 rising to 2.3, well above the Ginzburg–Landau value of 1.695. Orientation imaging revealed an extensive dislocation rich sub-grain structure in the as-drawn rods, a small reduction of the surface strain after baking at 120 °C, and a substantial but incomplete recrystallization near the surface after annealing at 800 °C. We interpret these changes in surface superconducting and structural properties to extensive changes in the near-surface interstitial contamination produced by baking and annealing and to synergistic interactions between H and surface O introduced during electropolishing and buffered chemical polishing.« less

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Significance of Multilayer Cloud Systems in Tropical Convection Download a printable PDF Submitter: Stephens, G. L., Colorado State University Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Stephens, GL, and NB Wood. 2007. "Properties of tropical convection observed by millimeter-wave radar systems." Monthly Weather Review 135: 821-842. Storm classifications (derived from k-means clustering analysis) applied to MWR

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turn Trash Into Treasure: Continental Warm Cloud Properties Derived from Unexploited Solar Background Signals Download a printable PDF Submitter: Chiu, J., University of Reading Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: Chiu JC, JA Holmes, RJ Hogan, and EJ O'Connor. 2014. "The interdependence of continental warm cloud properties derived from unexploited solar background signals in

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Validation of Climate Model Ice Cloud Properties Download a printable PDF Submitter: Eidhammer, T., NCAR Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Eidhammer T, H Morrison, A Bansemer, A Gettelman, and AJ Heymsfield. 2014. "Comparison of ice cloud properties simulated by the Community Atmosphere Model (CAM5) with in situ observations." Atmospheric Chemistry and Physics, 14(18), doi:10.5194/acp-14-10103-2014. Mass weighted terminal fall

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DCS Ice Cloud Microphysical Properties Derived from Aircraft Data During MC3E Submitter: Dong, X., University of North Dakota Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Wang J, X Dong, and B Xi. 2015. "Investigation of ice cloud microphysical properties of DCSs using aircraft in situ measurements during MC3E over the ARM SGP site." Journal of Geophysical Research - Atmospheres, 120(8), 3533-3552. Figure 1. The observed PSDs at different

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Observations of Microphysical Properties of Single Layer Stratocumulus During the Mixed-Phase Arctic Cloud Experiment Submitter: McFarquhar, G., University of Illinois, Urbana Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Fridlind, A.M., A.S. Ackerman, G.M. McFarquhar, G. Zhang, M.R. Poellot, P.J. DeMott, A.J. Prenni and A.J. Heymsfield, 2007: Ice properties of single-layer stratocumulus during the Mixed-Phase Arctic Cloud

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Continuous Clear-Sky Longwave from Surface Measurements Download a printable PDF Submitter: Long, C. N., NOAA Global Monitoring Division/CIRES Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: Long, CN, and DD Turner. 2008. "A method for continuous estimation of clear-sky downwelling longwave radiative flux developed using ARM surface measurements." Journal of Geophysical

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Diurnal Cycle of Monsoon Clouds, Precipitation, and Surface Radiation Download a printable PDF Submitter: Long, C. N., NOAA Global Monitoring Division/CIRES May, P. T., Bureau of Meteorology Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: May PT, CN Long, and A Protat. 2012. "The diurnal cycle of the boundary layer, convection, clouds, and surface radiation in a coastal monsoon environment (Darwin

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Regime Analysis to Identify the Contribution of Clouds to Surface Temperature Errors in GCMs Submitter: Van Weverberg, K., Met Office Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Life Cycle Journal Reference: Van Weverberg K, CJ Morcrette, H Ma, SA Klein, and JC Petch. 2015. "Using regime analysis to identify the contribution of clouds to surface temperature errors in weather and climate models." Quarterly Journal Royal

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Earth Lightens Up Submitter: Long, C. N., NOAA Global Monitoring Division/CIRES Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: Wild, M., H. Gilgen, A. Roesch, A. Ohmura, C. N. Long, E. G. Dutton, B. Forgan, A. Kallis, V. Russak, and A. Tsvetkov, (2005): From dimming to brightening: Decadal changes in solar radiation at the Earth's surface, Science, 308, Issue 5723, 847-850, [DOI:10.1126/science.1103215] Global distribution of surface observation

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Threshold Radar Reflectivity Separating Precipitating from Non-Precipitating Clouds Download a printable PDF Submitter: Liu, Y., Brookhaven National Laboratory Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Liu, Y, B Geerts, PH Daum, R McGraw, and M Miller. 2008. "Threshold radar reflectivity for drizzling clouds." Geophysical Research Letters 35, L03807, doi:10.1029/2007GL031201. Figure 1 shows the comparison of the

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Small Ice Crystals on Ice Sedimentation Rates in Cirrus Clouds and GCM Simulations Download a printable PDF Submitter: Mitchell, D. L., Desert Research Institute Rasch, P., Pacific Northwest National Laboratory Ivanova, D., Embry-Riddle Aeronautical University McFarquhar, G., University of Illinois, Urbana Nousiainen, T. P., University of Helsinki Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Properties Journal Reference: Mitchell, DL, P

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Arctic Aerosol Study Flies By Download a printable PDF Submitter: Schmid, B., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: ARM Climate Research Facility Operations Update, April 30, 2008, Edition Preliminary screening and analysis of images from the time-resolved aerosol collector indicate particles laden with carbon and sulfur. These data were obtained on April 8, 2008. Image courtesy of Alexander Laskin, PNNL. Images

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Surprisingly Large Contribution of Small Marine Clouds to Cloud Fraction and Reflectance Download a printable PDF Submitter: Oreopoulos, L., NASA Feingold, G., NOAA - Earth System Research Laboratory Koren, I., Weizmann Institute of Science Remer, L., NASA - GSFC, Laboratory for Atmospheres Area of Research: Clouds with Low Optical [Water] Depths (CLOWD) Working Group(s): Cloud Properties Journal Reference: Koren, I, L Oreopoulos, G Feingold, LA Remer, and O Altaratz. 2008. "How small

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Aerosol Measurements on Cloudy Days: a New Method Download a printable PDF Submitter: Kassianov, E., Pacific Northwest National Laboratory Ovchinnikov, M., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: Kassianov, EI, and M Ovtchinnikov. 2008. "On reflectance ratios and aerosol optical depth retrieval in the presence of cumulus clouds." Geophysical Research Letters doi:10.1029/2008GL033231.

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thin Is In Download a printable PDF Submitter: Tomlinson, J., Pacific Northwest National Laboratory Long, C. N., NOAA Global Monitoring Division/CIRES Comstock, J. M., Pacific Northwest National Laboratory Ronfeld, D., Pacific Northwest National Laboratory Area of Research: Radiation Processes Working Group(s): Cloud Properties Journal Reference: N/A The Twin Otter takes off to test the onboard instruments for the RACORO field campaign that began in January 2009. Researchers are gathering data

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Method for Retrieving Cloud Heights from Satellite Data Download a printable PDF Submitter: Chang, F., Science Systems and Applications, Inc. Minnis, P., NASA - Langley Research Center Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Chang F, P Minnis, B Lin, MM Khaiyer, R Palikonda, and DA Spangenberg. 2010. "A modified method for inferring cloud top height using GOES-12 imager 10.7- and 13.3-µm data." Journal of

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Higher Clouds Retain Less Energy Download a printable PDF Submitter: Bhattacharya, A., Pacific Northwest National Laboratory Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle Journal Reference: Qiu Y, Q Wang, and F Hu. 2012. "Shouxian aerosol radiative properties measured by DOE AMF and compared with CERES-MODIS." Advanced Materials Research, 518-523(2), doi:10.4028/www.scientific.net/AMR.518-523.1973. Clouds with bases at different altitudes.

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Micropulse Lidar-Derived Aerosol Optical Depth Climatology at ARM Sites Worldwide Download a printable PDF Submitter: Kafle, D. N., NASA GSFC /ADNET Systems Coulter, R. L., Argonne National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Kafle DN and RL Coulter. 2013. "Micropulse lidar-derived aerosol optical depth climatology at ARM sites worldwide." Journal of Geophysical Research - Atmospheres, 118(13), 10.1002/jgrd.50536.

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hemispherical Simulations Show Impact of Aerosols on Cloud Reflectivity Submitter: Rotstayn, L., Commonwealth Scientific and Industrial Research Organization Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: Rotstayn, L., and Y. Liu, Sensitivity of the First Indirect Aerosol Effect to an Increase in Cloud Droplet Spectral Dispersion with Droplet Number Concentration, Journal of Climate: Vol. 16, No. 21, pp.3476-3481, May 2003. Figure 1. Measurements of the

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Overambitious Other Carbon Submitter: Church, J., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Song C, M Gyawali, RA Zaveri, JE Shilling, and WP Arnott. 2013. "Light absorption by secondary organic aerosol from α-pinene: Effects of oxidants, seed aerosol acidity, and relative humidity." Journal of Geophysical Research - Atmospheres, 118, doi:10.1002/jgrd.50767. Time-dependent Mass Absorption

  2. Measuring Complementary Electronic Structure Properties of both Deposited and Gas Phase Clusters using STM, UPS, and PES: Size-Selected Clusters on Surfaces

    SciTech Connect (OSTI)

    Bowen, Kit H.

    2014-03-05

    In this project, we studied size-selected cluster interactions with surfaces, with other clusters on surfaces, and with external stimuli. These studies focused on mobility as a function of cluster size, surface morphologies as a function of composition and coverage, ion-induced modification and reactivity of clusters as a function of composition, the structural evolution of cluster cuboids culminating in the characterization of theoretically-predicted baby crystal clusters, and unusual fractal pattern formation due to deposition.

  3. ARM - Measurement - Surface condition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Weather Forecasts Model Data LANDCOVER-SAT : Landcover Derived From Satellite Data RSP : Research Scanning Polarimeter MET : Surface Meteorological Instrumentation VEGWATER-SAT :...

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Checking Up on Tropical Sunlight Download a printable PDF Submitter: Riihimaki, L., Pacific Northwest National Laboratory Long, C. N., NOAA Global Monitoring Division/CIRES Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: Riihimaki LD and CN Long. 2014. "Spatial variability of surface irradiance measurements at the Manus ARM site." Journal of Geophysical Research - Atmospheres, 119(9), 5475-5491. ACCEPTED. The radiometer system used at the

  5. Temperature sensitive surfaces and methods of making same

    DOE Patents [OSTI]

    Liang, Liang [Richland, WA; Rieke, Peter C [Pasco, WA; Alford, Kentin L [Pasco, WA

    2002-09-10

    Poly-n-isopropylacrylamide surface coatings demonstrate the useful property of being able to switch charateristics depending upon temperature. More specifically, these coatings switch from being hydrophilic at low temperature to hydrophobic at high temperature. Research has been conducted for many years to better characterize and control the properties of temperature sensitive coatings. The present invention provides novel temperature sensitive coatings on articles and novel methods of making temperature sensitive coatings that are disposed on the surfaces of various articles. These novel coatings contain the reaction products of n-isopropylacrylamide and are characterized by their properties such as advancing contact angles. Numerous other characteristics such as coating thickness, surface roughness, and hydrophilic-to-hydrophobic transition temperatures are also described. The present invention includes articles having temperature-sensitve coatings with improved properties as well as improved methods for forming temperature sensitive coatings.

  6. Fluorinated silica microchannel surfaces

    DOE Patents [OSTI]

    Kirby, Brian J.; Shepodd, Timothy Jon

    2005-03-15

    A method for surface modification of microchannels and capillaries. The method produces a chemically inert surface having a lowered surface free energy and improved frictional properties by attaching a fluorinated alkane group to the surface. The coating is produced by hydrolysis of a silane agent that is functionalized with either alkoxy or chloro ligands and an uncharged C.sub.3 -C.sub.10 fluorinated alkane chain. It has been found that the extent of surface coverage can be controlled by controlling the contact time from a minimum of about 2 minutes to a maximum of 120 minutes for complete surface coverage.

  7. Research Techniques

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Techniques Research Techniques Print Coming Soon

  8. Using Radar, Lidar and Radiometer Data from NSA and SHEBA to Quantify Cloud Property Effects on the Surface Heat Budget in the Arctic

    SciTech Connect (OSTI)

    Janet Intrieri; Mathhew Shupe

    2005-01-01

    Cloud and radiation data from two distinctly different Arctic areas are analyzed to study the differences between coastal Alaskan and open Arctic Ocean region clouds and their respective influence on the surface radiation budget. The cloud and radiation datasets were obtained from (1) the DOE North Slope of Alaska (NSA) facility in the coastal town of Barrow, Alaska, and (2) the SHEBA field program, which was conducted from an icebreaker frozen in, and drifting with, the sea-ice for one year in the Western Arctic Ocean. Radar, lidar, radiometer, and sounding measurements from both locations were used to produce annual cycles of cloud occurrence and height, atmospheric temperature and humidity, surface longwave and shortwave broadband fluxes, surface albedo, and cloud radiative forcing. In general, both regions revealed a similar annual trend of cloud occurrence fraction with minimum values in winter (60-75%) and maximum values during spring, summer and fall (80-90%). However, the annual average cloud occurrence fraction for SHEBA (76%) was lower than the 6-year average cloud occurrence at NSA (92%). Both Arctic areas also showed similar annual cycle trends of cloud forcing with clouds warming the surface through most of the year and a period of surface cooling during the summer, when cloud shading effects overwhelm cloud greenhouse effects. The greatest difference between the two regions was observed in the magnitude of the cloud cooling effect (i.e., shortwave cloud forcing), which was significantly stronger at NSA and lasted for a longer period of time than at SHEBA. This is predominantly due to the longer and stronger melt season at NSA (i.e., albedo values that are much lower coupled with Sun angles that are somewhat higher) than the melt season observed over the ice pack at SHEBA. Longwave cloud forcing values were comparable between the two sites indicating a general similarity in cloudiness and atmospheric temperature and humidity structure between the two regions.

  9. Sandia National Laboratories: Research: Research Foundations: Geoscience

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geoscience Bioscience Computing and Information Science Electromagnetics Engineering Science Geoscience Materials Science Nanodevices and Microsystems Radiation Effects and High Energy Density Science Research Geoscience Geoscience photo The Geoscience Research Foundation performs recognized world-class earth and atmospheric sciences research and development to support Sandia's national security missions. Why our work matters Knowledge of the Earth's subsurface properties, structure and

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM Measurements Validate New Satellite Multilayer Cloud Remote Sensing Method Submitter: Minnis, P., NASA - Langley Research Center Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Huang, J., P. Minnis, B. Lin, Y. Yi, T.-F. Fan, S. Sun-Mack, and J. K. Ayers, 2006: Determination of ice water path in ice-over-water cloud systems using combined MODIS and AMSR-E measurements. Geophys. Res. Lett., 33, L21801, 10.1029/2006GL027038. Minnis,

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climate Warming Due to Soot and Smoke? Maybe Not. Submitter: Penner, J. E., University of Michigan Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: Penner, J.E., S.Y. Zhang, and C.C. Chuang, Soot and smoke aerosol may not warm climate, J. Geophys. Res., 108(D21), 4657, doi:10.1029/2003JD003409, 2003. New research results from the Department of Energy's Atmospheric Radiation Measurement (ARM) Program suggest that fossil fuel soot emissions and biomass smoke may

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM Program Achieves Milestone in Global Cloud Properties Research Submitter: Revercomb, H. E., University of Wisconsin, Madison Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: Knuteson, R.O., Best, F.A., Dedecker, R.G., Feltz, W.F., Revercomb, H.E., and Tobin, D.C., 2004: "10 Years of AERI Data from the DOE ARM Southern Great Plains Site," In Proceedings from the Fourteenth ARM Science Team Meeting, U.S. Department of Energy,Washington,

  13. Research Highlight

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    Dust Takes Detour on Ice-Cloud Journey Download a printable PDF Submitter: Kulkarni, G., Pacific Northwest National Laboratory Area of Research: Aerosol Processes Working Group(s): Aerosol Life Cycle Journal Reference: Kulkarni G, C Sanders, K Zhang, X Liu, and C Zhao. 2014. "Ice nucleation of bare and sulfuric acid-coated mineral dust particles and implication for cloud properties." Journal of Geophysical Research - Atmospheres, 119(16), doi:10.1002/2014JD021567. Cirrus clouds are

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Vertical Structure of Cloud Radiative Forcing at the ACRF SGP Revealed by 8 Years of Continuous Measurements Submitter: Mace, G., University of Utah Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Modeling, Cloud Properties Journal Reference: Accepted to Journal of Climate, 2007. Figure 1. Cloud occurrence, coverage, radiative forcing, and radiation effects over a composite annual cycle that is derived by averaging all observations collected during a

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Raman Lidar Observations of Aerosol Humidification Near Clouds Submitter: Ferrare, R. A., NASA LaRC Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: Ferrare, R., et al., Evaluation of Daytime Measurements of Aerosols and Water Vapor Made by an Operational Raman Lidar over the Southern Great Plains, J. Geophys. Res., 111, D05S08, doi:10.1029/2005JD005836, 2006. Relative humidity profiles derived from the Raman lidar during the ALIVE 2005 field experiment. Aerosol

  16. Research Highlight

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    Can Ice-Nucleating Aerosols Affect Arctic Seasonal Climate? Submitter: Prenni, A. J., Colorado State University Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Prenni, A. J., J. Y. Harrington, M. Tjernstrom, P. J. DeMott, A. Avramov, C. N. Long, S. M. Kreidenweis, P. Q. Olsson, and J. Verlinde, (2006): Can Ice-Nucleating Aerosols Affect Arctic Seasonal Climate?, BAMS, Vol.88, Iss. 4; pg. 541-550. ACIA, 2004: Impacts of a Warming

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mixed-Phase Cloud Vertical Velocities and Dynamical-Microphysical Interactions Download a printable PDF Submitter: Shupe, M., University of Colorado Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Shupe, MD, P Kollias, M Poellot, and E Eloranta. 2008. "On deriving vertical air motions from cloud radar Doppler spectra." Journal of Atmospheric and Oceanic Technology 25: 547-557. Shupe, MD, P Kollias, POG Persson, and GM

  18. Research Highlight

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    Characterizing Mixed-Phase Clouds from the Ground: a Status Report Download a printable PDF Submitter: Shupe, M., University of Colorado Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Shupe, MD, JS Daniel, G De Boer, EW Eloranta, P Kollias, E Luke, CN Long, DD Turner, and J Verlinde. 2008. "A focus on mixed-phase clouds: The status of ground-ba sed observational methods." Bulletin of the American Meteorological Society,

  19. Research Highlight

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    Assessment of CloudSat Using ARM, AMF, and CloudNet Observations Download a printable PDF Submitter: Protat, A., Australian Bureau of Meterology May, P. T., Bureau of Meteorology O'Connor, E. J., University of Reading Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Submitted. PDF of cloud reflectivity (upper-left), cloud top height (upper-right), thickness (lower-left), and cloud base height (lower right) as measured by the Darwin

  20. Research Highlight

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    Vertical Variation of Cloud Droplet Size Using Ship and Space-borne R/S Data Download a printable PDF Submitter: Li, Z., University of Maryland Chen, R., University of Maryland Wood, R., University of Washington Chang, F., Science Systems and Applications, Inc. Ferraro, R., NOAA/NESDIS, WWBG Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Chen, R, R Wood, Z Li, R Ferraro, and F Chang. 2008. "Studying the vertical variation of

  1. Research Highlight

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    CCN Activity and Mixing Rules of Isoprene Secondary Organic Aerosol (SOA) and Sulfate Download a printable PDF Submitter: Martin, S. T., Harvard University Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: King SM, T Rosenoern, JH Shilling, Q Chen, Z Wang, G Biskos, KA McKinney, U Poeschl, and ST Martin. 2010. "Cloud droplet activation of mixed organic-sulfate particles produced by the photooxidation of

  2. Research Highlight

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    Increased Accuracy for Sky Imager Retrievals Download a printable PDF Submitter: Long, C. N., NOAA Global Monitoring Division/CIRES Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Long CN. 2010. "Correcting for circumsolar and near-horizon errors in sky cover retrievals from sky images." The Open Atmospheric Science Journal, 4, doi:10.2174/1874282301004010045. Long CN, JM Sabburg, J Calbo, and D Pages. 2006. "Retrieving

  3. Research Highlight

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    Characterizing Clouds at Arctic Atmospheric Observatories Download a printable PDF Submitter: Shupe, M., University of Colorado Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle Journal Reference: Shupe MD, VP Walden, E Eloranta, T Uttal, JR Campbell, SM Starkweather, and M Shiobara. 2011. "Clouds at Arctic atmospheric observatories, part I: occurrence and macrophysical properties." Journal of Applied Meteorology and Climatology, 50(3), 626-644.

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How Aerosols Affect Cloud Properties in Arctic Mixed-Phase Stratocumulus Download a printable PDF Submitter: McFarquhar, G., University of Illinois, Urbana Area of Research: Cloud-Aerosol-Precipitation Interactions Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Jackson RC, GM McFarquhar, AV Korolev, ME Earle, PS Liu, RP Lawson, S Brooks, M Wolde, A Laskin, and M Freer. 2012. "The dependence of ice microphysics on aerosol concentration in arctic mixed-phase

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pollution Hitches Ride to Arctic Download a printable PDF Submitter: Zelenyuk-Imre, A., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Zelenyuk A, D Imre, J Beranek, E Abramson, J Wilson, and M Shrivastava. 2012. "Synergy between secondary organic aerosols and long-range transport of polycyclic aromatic hydrocarbons." Environmental Science & Technology, 46(22), doi:10.1021/es302743z. When airborne

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Modeling from a Tropical State of Mind Download a printable PDF Submitter: Del Genio, A. D., National Aeronautics and Space Administration Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Mrowiec AA, C Rio, AM Fridlind, AS Ackerman, AD Del Genio, OM Pauluis, AC Varble, and J Fan. 2012. "Analysis of cloud-resolving simulations of a tropical mesoscale convective system observed during TWP-ICE: Vertical fluxes and draft properties in convective and

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High and Dry - Probing Greenland's Atmosphere and Clouds Download a printable PDF Submitter: Shupe, M., University of Colorado Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Shupe MD, DD Turner, VP Walden, R Bennartz, M Cadeddu, B Castellani, C Cox, D Hudak, M Kulie, N Miller, RR Neely, III, W Neff, and PM Rowe. 2013. "High and Dry: New observations of tropospheric and cloud properties

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    When Pollution Gets a Whiff of Trees Download a printable PDF Submitter: Shilling, J., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Shilling JE, RA Zaveri, JD Fast, L Kleinman, M Alexander, MR Canagaratna, E Fortner, JM Hubbe, JT Jayne, A Sedlacek, A Setyan, S Springston, DR Worsnop, and Q Zhang. 2013. "Enhanced SOA formation from mixed anthropogenic and biogenic emissions during the CARES campaign."

  9. Research Highlight

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    Wildfires Lead to More Warming Than Climate Models Predict, a New Mexico Fire Study Reports Download a printable PDF Submitter: Bhattacharya, A., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: China S, C Mazzoleni, K Gorkowski, AC Aiken, and MK Dubey. 2013. "Morphology and mixing state of individual freshly emitted wildfire carbonaceous particles." Nature Communications, 4, 2122, doi:10.1038/ncomms3122.

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Initial Aerosol Concentration Is Key Contributor to Low-Level Cloud Reflectivity Submitter: Penner, J. E., University of Michigan Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: Penner, J., Dong, X., Chen. Y., Observational evidence of a change in radiative forcing due to the indirect aerosol effect, Nature, Vol. 427, 15 January 2004. Cloud optical depth, as determined from the parcel model, is indicated by the dots. Red lines show best fit data of cloud liquid

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reality Check: Estimates for Human-Caused Methane Emissions in the U.S. Appear Off by 50% Download a printable PDF Submitter: Biraud, S. C., Lawrence Berkeley National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Miller SM, SC Wofsy, AM Michalak, EA Kort, AE Andrews, SC Biraud, EJ Dlugokencky, J Elszkeiwicz, ML Fischer, G Janssens-Maenhout, BR Miller, JB Miller, SA Montzka, T Nehrkorn, and C Sweeney. 2013. "Anthropogenic emissions

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Observing Warm Clouds in 3D Using ARM Scanning Cloud Radars and a Novel Ensemble Method Download a printable PDF Submitter: Fielding, M. D., University of Reading Area of Research: Cloud-Aerosol-Precipitation Interactions Working Group(s): Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: Fielding MD, J Chiu, RJ Hogan, and G Feingold. 2014. "A novel ensemble method for retrieving properties of warm cloud in 3-D using ground-based scanning radar and zenith

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effects of Relative Humidity on Aerosols-Implications for Climate Submitter: Lacis, A. A., NASA - Goddard Institute for Space Studies Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: "Refractive Indices of Three Hygroscopic Aerosols and their Dependence on Relative Humidity," October 2001. Sponsored by the DOE Atmospheric Radiation Measurement (ARM) Program, science collaborators at the National Aeronautics and Space Administration (NASA) Goddard

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Even at High Humidity, Aerosols Stick Around: Slowly Evaporating Particles Refute Assumption Download a printable PDF Submitter: Zelenyuk-Imre, A., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Wilson J, D Imre, J Beránek, M Shrivastava, and A Zelenyuk. 2014. "Evaporation kinetics of laboratory-generated secondary organic aerosols at elevated relative humidity." Environmental Science & Technology,

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Arctic Haze: Effect of Anthropogenic and Biomass Burning Aerosols Transported from Europe to the Arctic Download a printable PDF Submitter: Fast, J. ., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Marelle L, J Raut, JL Thomas, KS Law, B Quennehen, G Ancellet, J Pelon, A Schwarzenboeck, and JD Fast. 2015. "Transport of anthropogenic and biomass burning aerosols from Europe to the

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    For Estimates of Cloud Optical Thickness, Simple Equation Is Good Enough Submitter: Barnard, J., University of Nevada Reno Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Barnard, J. C., and C. N. Long, (2004): A Simple Empirical Equation to Calculate Cloud Optical Thickness Using Shortwave Broadband Measurement, JAM, 43, 1057-1066. Distributions of cloud optical thickness reveal that the empirical method (dashed line) closely

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Self-Regulation Strikes a Balance Between Hydrological Cycle, Radiation Processes, and Intraseasonal Dynamic Variations Submitter: Stephens, G. L., Colorado State University Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Properties Journal Reference: Stephens, Graeme L., Webster, Peter J., Johnson, Richard H., Engelen, Richard, L'Ecuyer, Tristan. 2004: Observational Evidence for the Mutual Regulation of the Tropical Hydrological Cycle and Tropical

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosol Experiment Results Featured in Technical Journal Submitter: Sheridan, P., U.S. Department of Commerce/NOAA Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: Sheridan, P, W Arnott, J Ogren, E Andrews, D Atkinson, D Covert, H Moosmuller, A Petzold, B Schmid, A Strawa, R Varma, and A Virkkula. 2005. "The Reno Aerosol Optics Study: An evaluation of aerosol absorption measurement methods." Aerosol Science and Technology 39(1):1-16. This magnification

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Radiative and Thermodynamic Responses to Uncertainty in Aerosol Extinction Profiles Download a printable PDF Submitter: Feng, Y., Argonne National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Feng Y, R Kotamarthi, R Coulter, C Zhao, and M Cadeddu. 2016. "Radiative and Thermodynamic Responses to Aerosol Extinction Profiles during the Pre-monsoon Month over South Asia." Atmospheric Chemistry and Physics, 16(1), 247-264. WRF-Chem

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Dark Side of Cold Clouds Download a printable PDF Submitter: Kulkarni, G., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: China S, G Kulkarni, BV Scarnato, N Sharma, M Pekour, JE Shilling, J Wilson, A Zelenyuk, D Chand, S Liu, AC Aiken, MK Dubey, A Laskin, RA Zaveri, and C Mazzoleni. 2015. "Morphology of diesel soot residuals from supercooled water droplets and ice crystals: implications for optical

  1. Intellectual Property Provisions (CSB-115) Cooperative Agreement...

    Energy Savers [EERE]

    15) Cooperative Agreement Research, Development, or Demonstration Domestic Small Business Intellectual Property Provisions (CSB-115) Cooperative Agreement Research, Development, or...

  2. Intellectual Property Provisions (CLB-115) Cooperative Agreement...

    Office of Environmental Management (EM)

    Agreement Research, Development, or Demonstration Large Business and Foreign Entity Intellectual Property Provisions (CLB-115) Cooperative Agreement Research, Development, or...

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM QCRad Goes Global Download a printable PDF Submitter: Long, C. N., NOAA Global Monitoring Division/CIRES Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: Long, CN, and Y Shi. 2008. "An automated quality assessment and control algorithm for surface radiation measurements." The Open Atmospheric Science Journal 2: 23-37, doi: 10.2174/1874282300802010023. Figure: QCRad downwelling (top) and upwelling (bottom) longwave (LW) comparison

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Clouds Get in the Way: How Climate Models Calculate the Effects of Clouds on Earth's Warming Download a printable PDF Submitter: Qian, Y., Pacific Northwest National Laboratory Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle Journal Reference: Qian Y, CN Long, H Wang, JM Comstock, SA McFarlane, and S Xie. 2012. "Evaluation of cloud fraction and its radiative effect simulated by IPCC AR4 global models against ARM surface observations."

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2007 Floods Not a Complete Washout in U.S. Great Plains Submitter: Bhattacharya, A., Pacific Northwest National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Lamb PJ, DH Portis, and A Zangvil. 2012. "Investigation of Large-Scale Atmospheric Moisture Budget and Land Surface Interactions over U.S. Southern Great Plains including for CLASIC (June 2007)." Journal of

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Arctic Mixed-phase Clouds Persist with Little Help from the Local Surface Download a printable PDF Submitter: Shupe, M., University of Colorado Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: Shupe MD, OG Persson, IM Brooks, M Tjernstrom, J Sedlar, T Mauritsen, S Sjogren, and C Leck. 2013. "Cloud and boundary layer interactions over the Arctic sea ice in late summer." Atmospheric Chemistry and Physics,

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Satellite Inference of Thermals and Cloud Base Updraft Speeds Download a printable PDF Submitter: Zheng, Y., University of Maryland Area of Research: Vertical Velocity Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Zheng Y, D Rosenfeld, and Z Li. 2015. "Satellite inference of thermals and cloud base updraft speeds based on retrieved surface and cloud base temperatures." Journal of the Atmospheric Sciences, , . ONLINE. Validation of satellite-estimated

  8. Intellectual Property Provisions

    Office of Environmental Management (EM)

    GNP-115 1 Intellectual Property Provisions (GNP-115) Grant and Cooperative Agreement Research, Development, or Demonstration Non-Federal Entity (State, Local government, Indian tribe, Institution of higher education, or Nonprofit organization) A Non-Federal Entity is subject to the intellectual property requirements at 2 CFR 200.315. 2 CFR 200.315 Intangible Property (a) Title to intangible property (see §200.59 Intangible property) acquired under a Federal award vests upon acquisition in the

  9. ARM - Measurement - Surface albedo

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    albedo ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Surface albedo The fraction of incoming solar radiation at a surface (i.e. land, cloud top) that is effectively reflected by that surface. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of

  10. Solid Electrolyte/Electrode Interfaces: Atomistic Behavior Analyzed Via UHV-AFM, Surface Spectroscopies, and Computer Simulations Computational and Experimental Studies of the Cathode/Electrolyte Interface in Oxide Thin Film Batteries

    SciTech Connect (OSTI)

    Garofalini, Stephen H

    2012-03-21

    The goals of the research were to understand the structural, dynamic, and chemical properties of solid electrolyte surfaces and the cathode/electrolyte interface at an atomistic and nanometer level using both computational and experimental techniques.

  11. ARM - Research Highlights: Notable Findings

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HighlightsNotable Research Findings Form Submit a New Research Highlight Sort Highlights Submitter Title Research Area Working Group Submission Date DOE Progress Reports Notable Research Findings for 2001-2006 Office of Science Abstracts Database Research Highlights Summaries Notable Research Findings for the Past Five Years Aerosols Cloud Parameterization and Modeling (Currently Cloud Modeling) Cloud Properties Instantaneous Radiative Flux (Currently Radiative Processes)

  12. Research Needs: Glass Solar Reflectance and Vinyl Siding

    SciTech Connect (OSTI)

    Hart, Robert; Curcija, Charlie; Arasteh, Dariush; Goudey, Howdy; Kohler, Christian; Selkowitz, Stephen

    2011-07-07

    The subject of glass solar reflectance and its contribution to permanent vinyl siding distortion has not been extensively studied, and some phenomena are not yet well understood. This white paper presents what is known regarding the issue and identifies where more research is needed. Three primary topics are discussed: environmental factors that control the transfer of heat to and from the siding surface; vinyl siding properties that may affect heat build-up and permanent distortion; and factors that determine the properties of reflected solar radiation from glass surfaces, including insulating window glass. Further research is needed to fully characterize the conditions associated with siding distortion, the scope of the problem, physical properties of vinyl siding, insulating window glass reflection characteristics, and possible mitigation or prevention strategies.

  13. CARMA SURVEY TOWARD INFRARED-BRIGHT NEARBY GALAXIES (STING). III. THE DEPENDENCE OF ATOMIC AND MOLECULAR GAS SURFACE DENSITIES ON GALAXY PROPERTIES

    SciTech Connect (OSTI)

    Wong, Tony; Xue, Rui; Bolatto, Alberto D.; Fisher, David B.; Vogel, Stuart N.; Leroy, Adam K.; Blitz, Leo; Rosolowsky, Erik; Bigiel, Frank; Ott, Jrgen; Rahman, Nurur; Walter, Fabian

    2013-11-01

    We investigate the correlation between CO and H I emission in 18 nearby galaxies from the CARMA Survey Toward IR-Bright Nearby Galaxies (STING) at sub-kpc and kpc scales. Our sample, spanning a wide range in stellar mass and metallicity, reveals evidence for a metallicity dependence of the H I column density measured in regions exhibiting CO emission. Such a dependence is predicted by the equilibrium model of McKee and Krumholz, which balances H{sub 2} formation and dissociation. The observed H I column density is often smaller than predicted by the model, an effect we attribute to unresolved clumping, although values close to the model prediction are also seen. We do not observe H I column densities much larger than predicted, as might be expected were there a diffuse H I component that did not contribute to H{sub 2} shielding. We also find that the H{sub 2} column density inferred from CO correlates strongly with the stellar surface density, suggesting that the local supply of molecular gas is tightly regulated by the stellar disk.

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Retrieving Cloud Characteristics from Ground-Based Daytime Color All-Sky Images Submitter: Long, C. N., NOAA Global Monitoring Division/CIRES Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Long, C. N., J. M. Sabburg, J. Calbo, and D. Pages, (2006): Retrieving Cloud Characteristics from Ground-based Daytime Color All-sky Images, JTech, 23, No. 5, 633–652. Long, C. N., J. M. Sabburg, J. Calbo, and D. Pages, (2006): Papers of Note:

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Memo from Real World to Cumulus Parameterizations: Get Organized! Download a printable PDF Submitter: Del Genio, A. D., National Aeronautics and Space Administration Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Del Genio AD, J Wu, and Y Chen. 2012. "Characteristics of mesoscale organization in WRF simulations of convection during TWP-ICE." Journal of Climate, 25(17), 5666, doi:10.1175/JCLI-D-11-00422.1. Properties of cold pool air (solid

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    More Like Shades of Gray: the Effects of Black Carbon in Aerosols Submitter: McComiskey, A. C., National Oceanic and Atmospheric Administration Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Cappa CD, TB Onasch, P Massoli, DR Worsnop, TS Bates, ES Cross, P Davidovits, J Hakala, KL Hayden, BT Jobson, KR Kolesar, DA Lack, BM Lerner, SM Li, D Mellon, I Nuaaman, JS Olfert, T Petaja, PK Quinn, C Song, R Subramanian, EJ Williams, and RA Zaveri. 2012.

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Unique Properties of the Arctic Stratiform Cloud-Top Region Submitter: Shupe, M., University of Colorado Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Sedlar J, MD Shupe, and M Tjernström. 2011. "On the relationship between thermodynamic structure and cloud top, and its climate significance in the Arctic." Journal of Climate, 25(7), doi:10.1175/JCLI-D-11-00186.1. Occurrence frequency of low-level, stratiform cloud cases used in the analysis

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dust in the Wind... and the Clouds... and the Atmosphere Submitter: Sassen, K., University of Alaska, Fairbanks Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: Sassen, K., P.J. DeMott, J.M. Propsero, and M.R. Poellot, Saharan Dust Storms and Indirect Aerosol Effects on Clouds: CRYSTAL-FACE Results, Geophys. Res. Ltt., 30(12), 1633, doi:10/1029/2003GL017371, 2003. PDL linear depolarization ratio (color scale on top) and relative returned power (in gray scale) of

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Comparison of Mixed-layer Heights from Airborne HSRL and WRF-Chem During CARES Download a printable PDF Submitter: Scarino, A. J., Science Systems and Applications, Inc. Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Scarino AJ, MD Obland, JD Fast, SP Burton, RA Ferrare, CA Hostetler, LK Berg, B Lefer, C Haman, JW Hair, RR Rogers, C Butler, AL Cook, and DB Harper. 2014. "Comparison of mixed layer heights from airborne high spectral resolution

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Technique Successful for Measuring Thickness of Broken Clouds Submitter: Marshak, A., NASA - Goddard Space Flight Center Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Properties Journal Reference: Marshak, A, Y Knyazikhin, K.D. Evans, and W.J. Wiscomb, (2004): The "RED versus NIR" Plane to Retrieve Broken-Cloud Optical Depth from Ground-Based Measurements, Journal of Atmospheric Sciences , 61, 1911-1925. In the "lookup table," vertical

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Using ARM Cloud Data to Evaluate the Effect of a Land Surface on Clouds Download a printable PDF Submitter: GSFC, N., NASA GSFC Area of Research: Cloud Distributions/Characterizations Working Group(s): Aerosol, Cloud Modeling Journal Reference: Zeng, X., W.-K. Tao, M. Zhang, C. Peters-Lidard, S. Lang, J. Simpson, S. Kumar, S. Xie, J. L. Eastman, C.-L. Shie, and J. V. Geiger, 2007: Evaluating clouds in long-term cloud-resolving model simulations with observational data. J. Atmos. Sci. (in press).

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM Data Used to Evaluate Reanalysis Results Download a printable PDF Submitter: Dong, X., University of North Dakota Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: Dolinar E, X Dong, and B Xi. 2015. "Evaluation and intercomparison of clouds, precipitation, and radiation budgets in recent reanalyses using satellite-surface observations." Climate Dynamics, , DOI 10.1007/s00382-0, 10.1007/s00382-0. Figure 1. Monthly means of CF (a), SWDNsfc

  3. Mechanical properties and tribological behavior of contaminate...

    Office of Scientific and Technical Information (OSTI)

    behavior of contaminate nanoparticles on micromachined surfaces. Citation Details In-Document Search Title: Mechanical properties and tribological behavior of ...

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    layer drizzle properties and their impact on cloud property retrieval." Atmospheric Measurement Techniques, 8, doi:10.5194amt-8-3555-2015. Figure 1. Drizzle properties...

  5. Materials research at selected Japanese laboratories. Based on a 1992 visit: Overview, summary of highlights, notes on laboratories and topics

    SciTech Connect (OSTI)

    Not Available

    1994-02-01

    I visited Japan from June 29 to August 1, 1992. The purpose of this visit was to assess the status of materials science research at selected governmental, university and industrial laboratories and to established acquaintances with Japanese researchers. The areas of research covered by these visits included ceramics, oxide superconductors, intermetallics alloys, superhard materials and diamond films, high-temperature materials and properties, mechanical properties, fracture, creep, fatigue, defects, materials for nuclear reactor applications and irradiation effects, high pressure synthesis, self-propagating high temperature synthesis, microanalysis, magnetic properties and magnetic facilities, and surface science.

  6. DNA ELECTROPHORESIS AT SURFACES

    SciTech Connect (OSTI)

    RAFAILOVICH, MIRIAM; SOKOLOV, JONATHAN; GERSAPPE, DILIP

    2003-09-01

    During this year we performed two major projects: I. We developed a detailed theoretical model which complements our experiments on surface DNA electrophoresis. We found that it was possible to enhance the separation of DNA chains by imposing a chemical nanoscale pattern on the surface. This approach utilized the surface interaction effect of the DNA chains with the substrate and is a refinement to our previous method in which DNA chains were separated on homogeneous flat surfaces. By introducing the nano-patterns on the surface, the conformational changes of DNA chains of different lengths can be amplified, which results in the different friction strengths with the substrate surface. Our results also show that, when compared to the DNA electrophoresis performed on homogeneous flat surfaces, nanopatterned surfaces offer a larger window in choosing different surface interactions to achieve separation. II. In collaboration with a large international manufacturer of skin care products we also embarked on a project involving photo toxicity of titanium dioxide nanoparticles, which are a key ingredient in sunscreen and cosmetic lotions. The results clearly implicated the nanoparticles in catalyzing damage to chromosomal DNA. We then used this knowledge to develop a polymer/anti-oxidant coating which prevented the photocatalytic reaction on DNA while still retaining the UV absorptive properties of the nanoparticles. The standard gel electrophoresis was not sufficient in determining the extent of the DNA damage. The conclusions of this study were based predominantly on analysis obtained with the surface electrophoresis method.

  7. ARM - Measurement - Soil surface temperature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    surface temperature ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Soil surface temperature The temperature of the soil measured near the surface. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those

  8. ARM - Measurement - Surface skin temperature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    skin temperature ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Surface skin temperature The radiative surface skin temperature, from an IR thermometer measuring the narrowband radiating temperature of the ground surface in its field of view. Categories Radiometric, Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the

  9. Characterization of fundamental catalytic properties of MoS2/WS2 nanotubes and nanoclusters for desulfurization catalysis - a surface temperature study

    SciTech Connect (OSTI)

    U. Burghaus

    2012-07-05

    The prior project consisted of two main project lines. First, characterization of novel nanomaterials for hydrodesulfurization (HDS) applications. Second, studying more traditional model systems for HDS such as vapor-deposited silica-supported Mo and MoSx clusters. In the first subproject, we studied WS2 and MoS2 fullerene-like nanoparticles as well as WS2 nanotubes. Thiophene (C4H4S) was used as the probe molecule. Interestingly, metallic and sulfur-like adsorption sites could be identified on the silica-supported fullerene-particles system. Similar structures are seen for the traditional system (vapor-deposited clusters). Thus, this may be a kinetics fingerprint feature of modern HDS model systems. In addition, kinetics data allowed characterization of the different adsorption sites for thiophene on and inside WS2 nanotube bundles. The latter is a unique feature of nanotubes that has not been reported before for any inorganic nanotube system; however, examples are known for carbon nanotubes, including prior work of the PI. Although HDS has been studied for decades, utilizing nanotubes as nanosized HDS reactors has never been tried before, as far as we know. This is of interest from a fundamental perspective. Unfortunately, the HDS activity of the nanocatalysts at ultra-high vacuum (UHV) conditions was close to the detection limit of our techniques. Therefore, we propose to run experiments at ambient pressure on related nanopowder samples as part of the renewal application utilizing a now-available GC (gas chromatograph) setup. In addition, Ni and Co doped nanocatalyts are proposed for study. These dopants will boost the catalytic activity. In the second subproject of the prior grant, we studied HDS-related chemistry on more traditional supported cluster catalysts. Mo clusters supported by physical vapor deposition (PVD) on silica have been characterized. Two reaction pathways are evident when adsorbing thiophene on Mo and MoSx clusters: molecular adsorption and dissociation. PVD Mo clusters turned out to be very reactive toward thiophene bond activation. Sulfur and carbon residuals form, which poison the catalyst and sulfide the Mo clusters. Sulfided silica-supported MoSx samples are not reactive toward thiophene bond activation. In addition to S and C deposits, H2, H2S, and small organic molecules were detected in the gas phase. Catalyst reactivation procedures, including O2 and atomic hydrogen treatments, have been tested. Cluster size effects have been seen: thiophene adsorbs molecularly with larger binding energies on smaller clusters. However, larger clusters have smaller activation energy for C4H4S bond activation than smaller clusters. The latter is consistent with early catalysis studies. Kinetics and dynamics parameters have been determined quantitatively. We spent a significant amount of time on upgrades of our equipment. A 2nd-hand refurbished X-ray photoelectron spectrometer (XPS) has been integrated into the existing molecular beam scattering system and is already operational (supported by the DoE supplemental grant available in October 2009). We also added a time of flight (TOF) system to the beam scattering apparatus and improved on the accessible impact energy range (new nozzle heater and gas mixing manifold) for the beam scattering experiments. In addition, a GC-based powder atmospheric flow reactor for studies on powder samples is now operational. Furthermore, a 2nd UHV kinetics system has been upgraded as well. In summary, mostly single crystal systems have so far been considered in basic science studies about HDS. Industrial catalysts, however, can be better approximated with the supported cluster systems that we studied in this project. Furthermore, an entirely new class of HDS systems, namely fullerene-like particles and inorganic nanotubes, has been included. Studying new materials and systems has the potential to impact science and technology. The systems investigated are closely related to energy and environmental-related surface science/catalysis. This prior project, conducted at NDSU by a sma

  10. LANL, LLNL researchers among Early Career Research Program award...

    National Nuclear Security Administration (NNSA)

    Program awards for 2013. LLNL physicist Yuan Ping's project, selected by the Office of Fusion Research, aims to provide high quality data on critical energy transport properties of...

  11. Property:SurfaceManager | Open Energy Information

    Open Energy Info (EERE)

    + COCONINO NF + AZA-009169 + COCONINO NF + AZA-009170 + COCONINO NF + AZA-009171 + FOREST SERVICE + AZA-009172 + FOREST SERVICE + AZA-009173 + FOREST SERVICE + AZA-009174 +...

  12. The High Temperature Materials Laboratory: A research and user facility at the Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Not Available

    1992-01-01

    HTML is a modern facility for high-temperature ceramic research; it is also a major user facility, providing industry and university communities access to special research equipment for studying microstructure and microchemistry of materials. User research equipment is divided among six User Centers: Materials Analysis, X-ray Diffraction, Physical Properties, Mechanical Properties, Ceramic Specimen Preparation, and Residual Stress. This brochure provides brief descriptions of each of the major research instruments in the User Centers: scanning Auger microprobe, field emission SEMs, electron microprobe, multitechnique surface analyzer, analytical electron microscope, HRTEM, optical microscopy image analysis, goniometer, scanning calorimetry, simultaneous thermal analysis, thermal properties (expansion, diffusivity, conductivity), high-temperature tensile test facilities, flexure, electromechanical test facilities (flexure, compression creep, environmental), microhardness microprobe, ceramic machining. Hands-on operation by qualified users is encouraged; staff is available. Both proprietary and nonproprietary research may be performed; the former on full cost recovery basis.

  13. The High Temperature Materials Laboratory: A research and user facility at the Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Not Available

    1992-12-01

    HTML is a modern facility for high-temperature ceramic research; it is also a major user facility, providing industry and university communities access to special research equipment for studying microstructure and microchemistry of materials. User research equipment is divided among six User Centers: Materials Analysis, X-ray Diffraction, Physical Properties, Mechanical Properties, Ceramic Specimen Preparation, and Residual Stress. This brochure provides brief descriptions of each of the major research instruments in the User Centers: scanning Auger microprobe, field emission SEMs, electron microprobe, multitechnique surface analyzer, analytical electron microscope, HRTEM, optical microscopy & image analysis, goniometer, scanning calorimetry, simultaneous thermal analysis, thermal properties (expansion, diffusivity, conductivity), high-temperature tensile test facilities, flexure, electromechanical test facilities (flexure, compression creep, environmental), microhardness microprobe, ceramic machining. Hands-on operation by qualified users is encouraged; staff is available. Both proprietary and nonproprietary research may be performed; the former on full cost recovery basis.

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    scatter sunlight, with other particle properties. These properties include particle size, chemical composition, and ability to soak up atmospheric water. By linking these...

  15. Intellectual Property Provisions (GDSB-115) Grant - Special Data...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - Special Data Statute Research, Development, or Demonstration Domestic Small Business Intellectual Property Provisions (GDSB-115) Grant - Special Data Statute Research,...

  16. Superhydrophobic surfaces (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Patent: Superhydrophobic surfaces Citation Details In-Document Search Title: Superhydrophobic surfaces Surfaces having a hierarchical structure--having features of both microscale and nanoscale dimensions--can exhibit superhydrophobic properties and advantageous condensation and heat transfer properties. The hierarchical surfaces can be fabricated using biological nanostructures, such as viruses as a self-assembled nanoscale template. Authors: Wang, Evelyn N ; McCarthy, Matthew ; Enright, Ryan ;

  17. Transportation Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    transportation-research TRACC RESEARCH Computational Fluid Dynamics Computational Structural Mechanics Transportation Systems Modeling Transportation Research Current Research Overview The U.S. Department of Transportation (USDOT) has established its only high-performance computing and engineering analysis research facility at Argonne National Laboratory to provide applications support in key areas of applied research and development for the USDOT community. The Transportation Research and

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hourly temperatures at the atmospheric temperature inversion altitude (magenta), surface (black), snow-sea ice interface (green), and ocean surface (cyan). The climate of the...

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    process-related fields like surface precipitation, clouds, and radiation are examined. Errors in the surface temperature and sea level pressure are also discussed. Both...

  20. Surface Radiation from GOES: A Physical Approach; Preprint

    SciTech Connect (OSTI)

    Habte, A.; Sengupta, M.; Wilcox, S.

    2012-09-01

    Models to compute Global Horizontal Irradiance (GHI) and Direct Normal Irradiance (DNI) have been in development over the last 3 decades. These models can be classified as empirical or physical, based on the approach. Empirical models relate ground based observations with satellite measurements and use these relations to compute surface radiation. Physical models consider the radiation received from the earth at the satellite and create retrievals to estimate surface radiation. While empirical methods have been traditionally used for computing surface radiation for the solar energy industry the advent of faster computing has made operational physical models viable. The Global Solar Insolation Project (GSIP) is an operational physical model from NOAA that computes GHI using the visible and infrared channel measurements from the GOES satellites. GSIP uses a two-stage scheme that first retrieves cloud properties and uses those properties in a radiative transfer model to calculate surface radiation. NREL, University of Wisconsin and NOAA have recently collaborated to adapt GSIP to create a 4 km GHI and DNI product every 30 minutes. This paper presents an outline of the methodology and a comprehensive validation using high quality ground based solar data from the National Oceanic and Atmospheric Administration (NOAA) Surface Radiation (SURFRAD) (http://www.srrb.noaa.gov/surfrad/sitepage.html) and Integrated Surface Insolation Study (ISIS) http://www.srrb.noaa.gov/isis/isissites.html), the Solar Radiation Research Laboratory (SRRL) at National Renewable Energy Laboratory (NREL), and Sun Spot One (SS1) stations.

  1. ARM - Measurement - Surface energy balance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    energy balance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Surface energy balance The energy balance at the earth's surface between the net radiation and the sensible and latent heat fluxes and ground heat flux. Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each

  2. Research | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Division of Chemical and Biological Sciences - This Division develops and applies theoretical, computational and experimental methods to the study of surface reaction phenomena, cluster science and nucleation, biological processes and catalysis. World-leading research is conducted at the interface between homogenous and heterogenous catalysis. This research has led to improved processes for biodiesel production. New characterization techniques and theoretical methods to enable improved

  3. 2010 Atmospheric System Research (ASR) Science Team Meeting Summary

    SciTech Connect (OSTI)

    Dupont, DL

    2011-05-04

    This document contains the summaries of papers presented in poster format at the March 2010 Atmospheric System Research Science Team Meeting held in Bethesda, Maryland. More than 260 posters were presented during the Science Team Meeting. Posters were sorted into the following subject areas: aerosol-cloud-radiation interactions, aerosol properties, atmospheric state and surface, cloud properties, field campaigns, infrastructure and outreach, instruments, modeling, and radiation. To put these posters in context, the status of ASR at the time of the meeting is provided here.

  4. Oxidation of coal and coal pyrite mechanisms and influence on surface characteristics. [Coal pyrite electrodes

    SciTech Connect (OSTI)

    Doyle, F.M.

    1992-01-01

    The objective of this research is to develop a mechanistic understanding of the oxidation of coal and coal pyrite, and to correlate the intrinsic physical and chemical properties of these minerals, along with changes resulting from oxidation, with those surface properties that influence the behavior in physical cleaning processes. The results will provide fundamental insight into oxidation, in terms of the bulk and surface chemistry, the microstructure, and the semiconductor properties of the pyrite. During the eighth quarter, wet chemical and dry oxidation tests were done on Upper Freeport coal from the Troutville [number sign]2 Mine, Clearfield County, Pennsylvania. In addition electrochemical experiments were done on electrodes prepared from Upper Freeport coal pyrite and Pittsburgh coal pyrite samples provided by the US Bureau of Mines, Pittsburgh Research Center, Pennsylvania.

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Submitter: Area of Research: Journal Reference: N/A

  6. Chemistry and Materials Science progress report, first half FY 1992. Weapons-Supporting Research and Laboratory Directed Research and Development

    SciTech Connect (OSTI)

    Not Available

    1992-07-01

    This report contains sections on: Fundamentals of the physics and processing of metals; interfaces, adhesion, and bonding; energetic materials; plutonium research; synchrotron radiation-based materials science; atomistic approach to the interaction of surfaces with the environment: actinide studies; properties of carbon fibers; buried layer formation using ion implantation; active coherent control of chemical reaction dynamics; inorganic and organic aerogels; synthesis and characterization of melamine-formaldehyde aerogels; structural transformation and precursor phenomena in advanced materials; magnetic ultrathin films, surfaces, and overlayers; ductile-phase toughening of refractory-metal intermetallics; particle-solid interactions; electronic structure evolution of metal clusters; and nanoscale lithography induced chemically or physically by modified scanned probe microscopy.

  7. Tailoring the surface properties of LiNi0.4Mn0.4Co0.2O₂ by titanium substitution for improved high voltage cycling performance

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wolff-Goodrich, Silas; Xin, Huolin L.; Lin, Feng; Markus, Isaac M.; Nordlund, Dennis; Asta, Mark; Doeff, Marca M.

    2015-07-30

    The present research aims to provide insights into the behavior of LiNi0.4Mn0.4Co0.2O2 (NMC442) and LiNi0.4Mn0.4Co0.2O₂ (NMC442-Ti02) cathode materials under galvanostatic cycling to high potentials, in the context of previous work which predicted that Ti-substituted variants should deliver higher capacities and exhibit better cycling stability than the unsubstituted compounds. It is found that NMC cathodes containing Ti show equivalent capacity fading but greater specific capacity than those without Ti in the same potential range. When repeatedly charged to the same degree of delithiation, NMC cathodes containing Ti showed better capacity retention. Soft x-ray absorption spectroscopy (XAS) spectra for Mn and Comore » indicated increased reduction in these elements for NMC cathodes without Ti, indicating that the substitution of Ti for Co acts to suppress the formation of a high impedance rock salt phase at the surface of NMC cathode particles. The results of this study validate the adoption of a facile change to existing NMC chemistries to improve cathode capacity retention under high voltage cycling conditions.« less

  8. Tailoring the surface properties of LiNi0.4Mn0.4Co0.2O? by titanium substitution for improved high voltage cycling performance

    SciTech Connect (OSTI)

    Wolff-Goodrich, Silas; Xin, Huolin L.; Lin, Feng; Markus, Isaac M.; Nordlund, Dennis; Asta, Mark; Doeff, Marca M.

    2015-07-30

    The present research aims to provide insights into the behavior of LiNi0.4Mn0.4Co0.2O2 (NMC442) and LiNi0.4Mn0.4Co0.2O? (NMC442-Ti02) cathode materials under galvanostatic cycling to high potentials, in the context of previous work which predicted that Ti-substituted variants should deliver higher capacities and exhibit better cycling stability than the unsubstituted compounds. It is found that NMC cathodes containing Ti show equivalent capacity fading but greater specific capacity than those without Ti in the same potential range. When repeatedly charged to the same degree of delithiation, NMC cathodes containing Ti showed better capacity retention. Soft x-ray absorption spectroscopy (XAS) spectra for Mn and Co indicated increased reduction in these elements for NMC cathodes without Ti, indicating that the substitution of Ti for Co acts to suppress the formation of a high impedance rock salt phase at the surface of NMC cathode particles. The results of this study validate the adoption of a facile change to existing NMC chemistries to improve cathode capacity retention under high voltage cycling conditions.

  9. Investigation of the texture surface silicon solar cell

    SciTech Connect (OSTI)

    Rongqiang, C.; Huilan, Q.

    1983-10-01

    The optical and electrical properties of the texture surface silicon solar cell are analyzed and discussed. A new method of etching a texture surface by LiOH is presented and the mechanism of etching a texture surface is investigated.

  10. Historic Properties

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of its historic properties. The National Park Service would provide interpretation, education, and technical preservation assistance for properties at LANL. Potential Los...

  11. Structure-Property Relationship in Metal Carbides and Bimetallic Alloys

    SciTech Connect (OSTI)

    Chen, Jingguan

    2014-03-04

    The primary objective of our DOE/BES sponsored research is to use carbide and bimetallic catalysts as model systems to demonstrate the feasibility of tuning the catalytic activity, selectivity and stability. Our efforts involve three parallel approaches, with the aim at studying single crystal model surfaces and bridging the materials gap and pressure gap between fundamental surface science studies and real world catalysis. The utilization of the three parallel approaches has led to the discovery of many intriguing catalytic properties of carbide and bimetallic surfaces and catalysts. During the past funding period we have utilized these combined research approaches to explore the possibility of predicting and verifying bimetallic and carbide combinations with enhanced catalytic activity, selectivity and stability.

  12. Breakthrough Research on Platinum-Nickel Alloys

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    surfaces. The next step is to engineer nanoparticle catalysts with electronic and morphological properties that mimic the surfaces of pure single crystals of Pt3Ni(111). In this...

  13. Surface Soil

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Soil Surface Soil We compare local soil samples with samples collected from northern New Mexico locations that are beyond the range of potential influence from normal Laboratory operations. April 12, 2012 Farm soil sampling Two LANL environmental field team members take soil samples from a farm. Contact Environmental Communication & Public Involvement P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email Measurements are compared to samples from the regional sites and

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Working Group(s): Cloud Properties Journal Reference: Greg M. McFarquhar and Stewart G. Cober. 2004: Single-Scattering Properties of Mixed-Phase Arctic Clouds at Solar...

  15. Superhydrophobic Surface Coatings for Microfluidics and MEMs.

    SciTech Connect (OSTI)

    Branson, Eric D.; Singh, Seema [Sandia National Laboratories, Livermore, CA] [Sandia National Laboratories, Livermore, CA; Houston, Jack E.; van Swol, Frank B.; Brinker, C. Jeffrey

    2006-11-01

    Low solid interfacial energy and fractally rough surface topography confer to Lotus plants superhydrophobic (SH) properties like high contact angles, rolling and bouncing of liquid droplets, and self-cleaning of particle contaminants. This project exploits the porous fractal structure of a novel, synthetic SH surface for aerosol collection, its self-cleaning properties for particle concentration, and its slippery nature 3 to enhance the performance of fluidic and MEMS devices. We propose to understand fundamentally the conditions needed to cause liquid droplets to roll rather than flow/slide on a surface and how this %22rolling transition%22 influences the boundary condition describing fluid flow in a pipe or micro-channel. Rolling of droplets is important for aerosol collection strategies because it allows trapped particles to be concentrated and transported in liquid droplets with no need for a pre-defined/micromachined fluidic architecture. The fluid/solid boundary condition is important because it governs flow resistance and rheology and establishes the fluid velocity profile. Although many research groups are exploring SH surfaces, our team is the first to unambiguously determine their effects on fluid flow and rheology. SH surfaces could impact all future SNL designs of collectors, fluidic devices, MEMS, and NEMS. Interfaced with inertial focusing aerosol collectors, SH surfaces would allow size-specific particle populations to be collected, concentrated, and transported to a fluidic interface without loss. In microfluidic systems, we expect to reduce the energy/power required to pump fluids and actuate MEMS. Plug-like (rather than parabolic) velocity profiles can greatly improve resolution of chip-based separations and enable unprecedented control of concentration profiles and residence times in fluidic-based micro-reactors. Patterned SH/hydrophilic channels could induce mixing in microchannels and enable development of microflow control elements. Acknowledgements This work was funded by Sandia National Laboratory's Laboratory Directed Research & Development program (LDRD). Some coating processes were conducted in the cleanroom facility located at the University of New Mexico's Center for High Technology Materials (CHTM). SEM images were performed at UNM's Center for Micro-Engineering on equipment funded by a NSF New Mexico EPSCoR grant. 4

  16. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Now, researchers are using x-ray spectroscopy at ALS Beamline 4.0.2 to study the magnetism of proton-irradiated graphite surfaces in order to understand the effects of...

  17. Research Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Gallery Research Gallery Exhibits in this gallery capture Laboratory's leading-edge research in many areas of science and technology to help solve national problems related to energy, the environment, infrastructure, and health. August 18, 2014 Museum floor plan showing the Research Gallery Basic research conducted here enhances our national defense and global security missions. Science serving society The Laboratory conducts leading-edge research in many areas of science and technology

  18. Research Highlights

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Highlights Form Submit a New Research Highlight Sort Highlights Submitter Title Research Area Working Group Submission Date DOE Progress Reports Notable Research Findings for 2001-2006 Office of Science Abstracts Database Research Highlights Summaries Research Highlights Members of ARM's science team are major contributors to radiation and cloud research. ARM investigators publish about 150 refereed journal articles per year, and ARM data are used in many studies published by other scientific

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Terrestrial Radiation Download a printable PDF Submitter: Mitchell, D. L., Desert Research Institute Area of Research: General Circulation and Single Column Models...

  20. Research Projects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Current Research Projects Joint Los Alamos National LaboratoryUCSD Research Projects Collaborations between Los Alamos National Laboratory and the University of California at San...

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Testing and Comparing the Modified Anomalous Diffraction Approximation Submitter: Mitchell, D. L., Desert Research Institute Area of Research: Cloud DistributionsCharacterizations...

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM Program Research Improves Longwave Radiative Transfer Models Submitter: Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: General Circulation and...

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fog and Rain in the Amazon For original submission and image(s), see ARM Research Highlights http:www.arm.govsciencehighlights Research Highlight The diurnal and seasonal...

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Masters the Misunderstood Mixed-Phase Cloud Download a printable PDF Submitter: Ovchinnikov, M., Pacific Northwest National Laboratory Area of Research:...

  5. MST Research Programs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ADEPS » MST » MST Research Programs MST Research Programs Providing world-leading, innovative, and agile materials science and technology solutions for national security missions. Contact Us Division Leader David Teter Email Emphasizing the synergy among materials synthesis, processing, properties, and performance, the Materials Science and Technology Division applies fundamental materials science and technology expertise to a broad range of programs in support of national security needs,

  6. Polymer surface treatment with particle beams

    DOE Patents [OSTI]

    Stinnett, Regan W. (1033 Tramway La. NE., Albuquerque, NM 87122); VanDevender, J. Pace (7604 Lamplighter NE., Albuquerque, NM 87109)

    1999-01-01

    A polymer surface and near surface treatment process produced by irradiation with high energy particle beams. The process is preferably implemented with pulsed ion beams. The process alters the chemical and mechanical properties of the polymer surface in a manner useful for a wide range of commercial applications.

  7. Polymer surface treatment with particle beams

    DOE Patents [OSTI]

    Stinnett, R.W.; VanDevender, J.P.

    1999-05-04

    A polymer surface and near surface treatment process produced by irradiation with high energy particle beams is disclosed. The process is preferably implemented with pulsed ion beams. The process alters the chemical and mechanical properties of the polymer surface in a manner useful for a wide range of commercial applications. 16 figs.

  8. Measurement and image processing evaluation of surface modifications of dental implants G4 pure titanium created by different techniques

    SciTech Connect (OSTI)

    Bulutsuz, A. G.; Demircioglu, P. Bogrekci, I.; Durakbasa, M. N.

    2015-03-30

    Foreign substances and organic tissue interaction placed into the jaw in order to eliminate tooth loss involves a highly complex process. Many biological reactions take place as well as the biomechanical forces that influence this formation. Osseointegration denotes to the direct structural and functional association between the living bone and the load-bearing artificial implant's surface. Taking into consideration of the requirements in the manufacturing processes of the implants, surface characterizations with high precise measurement techniques are investigated and thus long-term success of dental implant is emphasized on the importance of these processes in this study. In this research, the detailed surface characterization was performed to identify the dependence of the manufacturing techniques on the surface properties by using the image processing methods and using the scanning electron microscope (SEM) for morphological properties in 3D and Taylor Hobson stylus profilometer for roughness properties in 2D. Three implant surfaces fabricated by different manufacturing techniques were inspected, and a machined surface was included into the study as a reference specimen. The results indicated that different surface treatments were strongly influenced surface morphology. Thus 2D and 3D precise inspection techniques were highlighted on the importance for surface characterization. Different image analyses techniques such as Dark-light technique were used to verify the surface measurement results. The computational phase was performed using image processing toolbox in Matlab with precise evaluation of the roughness for the implant surfaces. The relationship between the number of black and white pixels and surface roughness is presented. FFT image processing and analyses results explicitly imply that the technique is useful in the determination of surface roughness. The results showed that the number of black pixels in the image increases with increase in surface roughness.

  9. Method of modifying a surface

    DOE Patents [OSTI]

    Renk, Timothy J. (Albuquerque, NM); Sorensen, Neil R. (Albuquerque, NM); Senft, Donna Cowell (Albuquerque, NM); Buchheit, Jr., Rudolph G. (Columbus, OH); Thompson, Michael O. (Ithaca, NY); Grabowski, Kenneth S. (Alexandria, VA)

    2000-01-01

    The present invention provides a surface modification method that provides beneficial changes in surface properties, can modify a surface to a greater depth than previous methods, and that is suitable for industrial application. The present method comprises applying a thin-film coating to a surface of a substrate, then subjecting the coated surface to an ion beam. The ion beam power pulse heats the coated surface, leading to alloying between the material in the coating and the material of the substrate. Rapid cooling of the alloyed layer after an ion beam pulse can lead to formation of metastable alloys and microstructures not accessible by conventional alloying methods or intense ion beam treatment of the substrate alone.

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Improved Daytime Precipitable Water Vapor from Vaisala Radiosonde Humidity Sensors Download a printable PDF Submitter: Cady-Pereira, K. E., Atmospheric and Environmental Research, Inc. Mlawer, E. J., Atmospheric & Environmental Research, Inc. Turner, D. D., National Oceanic and Atmospheric Administration Shephard, M. W., Atmospheric and Environmental Research, Inc. Clough, S. A., Atmospheric and Environmental Research, Inc. Area of Research: Atmospheric Thermodynamics and Vertical Structures

  11. Research Highlight

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    Optimal Method to Determine Orientation Average of Scattering Properties of Ice Crystals Download a printable PDF Submitter: Um, J., University of Illinois, Urbana McFarquhar, G.,...

  12. Research Highlight

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    small ice crystals to cirrus properties: Observations from the Tropical Warm Pool International Cloud Experiment (TWP-ICE). Geophys. Res. Lett., 34, L13803, doi:10.1029...

  13. Research Highlight

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    2014. "Evaluation of cloud-resolving and limited area model simulations using TWP-ICE observations. Part 1: Deep convective updraft properties." Journal of Geophysical...

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Single-Scattering Properties of Aggregates of Plates Download a printable PDF Submitter: Um, J., University of Illinois, Urbana McFarquhar, G., University of Illinois, Urbana Area...

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Life Cycle Journal Reference: Giangrande SE, S Collis, J Straka, A Protat, C Williams, and S Krueger. 2013. "A summary of convective core vertical velocity properties...

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of microphysics based on the prediction of bulk ice particle properties. Part II: Case study comparisons with observations and other schemes." Journal of the Atmospheric...

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fridlind, and AS Ackerman. 2015. "Properties of a mesoscale convective system in the context of an isentropic analysis." Journal of the Atmospheric Sciences, , doi:10.1175...

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    radiation and absorb more infrared radiation than water clouds, in essence enhancing the "greenhouse effect." Members of the ARM Cloud Properties Working Group who specialize in...

  19. Research Highlight

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    energy balance due to aerosol-radiation interactions, but the effect depends on the dust optical properties assumed in the simulations without mineralogy. More importantly, the...

  20. International Conference on Surface Transportation System Resilience...

    Broader source: Energy.gov (indexed) [DOE]

    practices and state of the art research results on how to adapt surface transportation networks to the potential impacts of climate change and extreme weather events. Learn More......

  1. Recovery Act: Geologic Sequestration Training and Research (Technical...

    Office of Scientific and Technical Information (OSTI)

    of a laboratory for measurement of rock properties, (2) evaluation of the sealing ... students through independent research on rock properties and reservoir simulation, and ...

  2. Research Highlight

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    evaporative fraction from a combination of day and night land surface temperature and NDVI: A new method to determine the Priestley-Taylor parameter. Remote Sensing of...

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    derive surface fluxes from measurements of wind speed, air temperature, humidity, and ground temperature. However, observations are simply not available at every grid point. As...

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud-Aerosol-Precipitation Interactions Journal Reference: Qian Y, MY Huang, B Yang, and LK Berg. 2013. "A modeling study of irrigation effects on surface fluxes and...

  5. Research Highlight

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    the ocean surface. The behavior of the GCCN parameterization in a large-eddy simulation (LES) framework is consistent with simulations employing explicit, size-resolving...

  6. Research Highlight

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    g, respectively. Climate models indicate that the reduction of surface albedo caused by black carbon contamination of snow contributes to global warming and near-worldwide...

  7. Research Highlight

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    surface albedo product for the ARM Southern Great Plains central facility." Atmospheric Measurement Techniques, 4, 1713-1733. Time series of daily percent vegetation derived from...

  8. Research Highlight

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    Albee. 2012. "Evaluation of Arctic broadband surface radiation measurements." Atmospheric Measurement Techniques, 5, doi:10.5194amt-5-429-2012. The Arctic is showing increased...

  9. Research Highlight

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    humidity (UTH) based on Geostationary satellite data; (middle) PI, CLD, and UTH from the IR simulator applied to the MMF; (bottom) the MMF actual surface precipitation rate, CLD,...

  10. Research Highlight

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    upward motion of the large-scale circulation. It allows convective available potential energy, or CAPE, to accumulate from surface processes before convection occurs and links...

  11. Research Highlight

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    Data from DOE Atmospheric Radiation Measurement Program Allows Evaluation of Surface ... DOE's AtmosphericRadiation Measurement (ARM) Program is contributing to this project-part ...

  12. Oxidation of coal and coal pyrite mechanisms and influence on surface characteristics. Technical progress report, September 30, 1992

    SciTech Connect (OSTI)

    Doyle, F.M.

    1992-12-31

    The objective of this research is to develop a mechanistic understanding of the oxidation of coal and coal pyrite, and to correlate the intrinsic physical and chemical properties of these minerals, along with changes resulting from oxidation, with those surface properties that influence the behavior in physical cleaning processes. The results will provide fundamental insight into oxidation, in terms of the bulk and surface chemistry, the microstructure, and the semiconductor properties of the pyrite. During the eighth quarter, wet chemical and dry oxidation tests were done on Upper Freeport coal from the Troutville {number_sign}2 Mine, Clearfield County, Pennsylvania. In addition electrochemical experiments were done on electrodes prepared from Upper Freeport coal pyrite and Pittsburgh coal pyrite samples provided by the US Bureau of Mines, Pittsburgh Research Center, Pennsylvania.

  13. Surface coatings. Science and technology

    SciTech Connect (OSTI)

    Paul, S.

    1985-01-01

    This book covers the coating field from the latest industry developments to current energy and pollution regulations. It explains the composition of coatings, how they are prepared and applied and the factors that control their ultimate performance. The author discusses the synthesis of polymeric binders, industrial resins, pigments, paints and paint properties, types of coatings, and new technologies. CONTENTS: Binders: Synthesis of Polymeric Binders; Industrial Resins; Pigments; Paints and Paint Properties: Pigment Dispersion; Surface Preparation and Paint Application; Paint Properties and Their Evaluation; Types of Coatings; New Technolgies.

  14. Research Highlight

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    SPartICus Submitter: Mishra, S., DOE - SunShot Initiative, AAAS S&T Policy Fellow Mitchell, D. L., Desert Research Institute Area of Research: General Circulation and Single...

  15. Research Highlight

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    Environmental Thermodynamics Affect Radiative Impact of Deep Convective Cloud Systems Submitter: Jensen, M., Brookhaven National Laboratory Area of Research: Atmospheric...

  16. Research Projects

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    LaboratoryNational Security Education Center Menu NSEC Educational Programs Los Alamos Dynamics Summer School Science of Signatures Advanced Studies Institute Judicial Science School SHM Data Sets and Software Research Projects Current Projects Past Projects Publications NSEC » Engineering Institute » Research Projects » Joint Los Alamos National Laboratory/UCSD research projects Past Research Projects Previous collaborations between Los Alamos National Laboratory and the University of

  17. Current Research

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    Current Research The U.S. Department of Transportation (USDOT) has established its only high-performance computing and engineering analysis research facility at Argonne National Laboratory to provide applications support in key areas of applied research and development for the USDOT community. The Transportation Research and Analysis Computing Center (TRACC) features a state-of-the-art massively parallel computer system, advanced scientific visualization capability, high-speed network

  18. Rheological Properties of Aqueous Nanometric Alumina Suspensions

    SciTech Connect (OSTI)

    Chuanping Li

    2004-12-19

    Colloidal processing is an effective and reliable approach in the fabrication of the advanced ceramic products. Successful colloidal processing of fine ceramic powders requires accurate control of the rheological properties. The accurate control relies on the understanding the influences of various colloidal parameters on the rheological properties. Almost all research done on the rheology paid less attention to the interactions of particle and solvent. However, the interactions of the particles are usually built up through the media in which the particles are suspended. Therefore, interactions of the particle with the media, the adsorbed layers on the particle surface, and chemical and physical properties of media themselves must influence the rheology of the suspension, especially for the dense suspensions containing nanosized particles. Relatively little research work has been reported in this area. This thesis addresses the rheological properties of nanometric alumina aqueous suspensions, and paying more attention to the interactions between particle and solvent, which in turn influence the particle-particle interactions. Dense nanometric alumina aqueous suspensions with low viscosity were achieved by environmentally-benign fructose additives. The rheology of nanometric alumina aqueous suspensions and its variation with the particle volume fraction and concentration of fructose were explored by rheometry. The adsorptions of solute (fructose) and solvent (water) on the nanometric alumina particle surfaces were measured and analyzed by TG/DSC, TOC, and NMR techniques. The mobility of water molecules in the suspensions and its variation with particle volume fractions and fructose additive were determined by the {sup 17}O NMR relaxation method. The interactions between the nanometric alumina particles in water and fructose solutions were investigated by AFM. The results indicated that a large number of water layers were physically bound on the particles' surfaces in the aqueous suspension. The viscosity of the suspension increases dramatically when the solid volume fraction exceeds 30 vol.%. The overlap of physically adsorbed water layers at this level causes the sharp increase in viscosity. Fructose molecules can weaken the interactions between the particle surfaces and water molecules, as a consequence, they release some bound water layers from the surfaces to the bulk medium. It is believed that fraction of the water that is bound by the solid surface is reduced hence becoming available for flow. The oxygen-17 relaxation time decreased with the increase of particle volume fractions in the suspension. Fructose addition increased the overall water mobility in the suspension. Only part of the alumina particle surfaces was covered with fructose molecules. This adsorption of fructose molecules on the particle surfaces increased the pH of the suspension with a concomitant decrease in {zeta}-potential of the alumina nanoparticles. The interactions between the nanometric alumina particles in water to a large extent can be explained by the DLVO theory. However, the interactions between particles in fructose solutions cannot be well described by the DLVO theory. The interaction forces (magnitude and range) as well as adhesive force and surface tension between nanometric alumina particles were decreased with the fructose concentration.

  19. Research Library

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    LANL Research Library: delivering essential knowledge services for national security sciences since 1947 About the Research Library Mission We deliver agile, responsive knowledge services, connecting people with information, technology and resources. Vision Essential knowledge services for national security sciences. The Research Library provides extensive collections of books, journals, databases, patents and technical reports and offers literature searching, training and outreach services. The

  20. Research Staff | Materials Science | NREL

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    Research Staff Research staff members in NREL's Materials Science Center are aligned within four groups: Materials Physics, Analytical Microscopy and Imaging Science, Interfacial and Surface Science, and Thin-Film Materials Science and Processing. For lead researcher contacts, see our research areas. For our business contact, see Work with Us. Photo of Nancy Haegel Nancy Haegel Center Director, Materials Science Center Email | 303-384-6548 Materials Physics Photo of Angelo Mascarenhas Angelo

  1. Surface mining

    SciTech Connect (OSTI)

    Not Available

    1989-06-01

    This paper reports on a GAO study of attorney and expert witness fees awarded as a result of litigation brought under the Surface Mining Control and Reclamation Act. As of March 24, 1989, a total of about $1.4 million had been awarded in attorney fees and expenses - about $1.3 subject to the provisions of the Employee Retirement Income Security Act, a comparison of its features with provisions of ERISA showed that the plan differed from ERISA provisions in areas such as eligibility, funding, and contribution limits.

  2. Method of sputter etching a surface

    DOE Patents [OSTI]

    Henager, Jr., Charles H.

    1984-01-01

    The surface of a target is textured by co-sputter etching the target surface with a seed material adjacent thereto, while the target surface is maintained at a pre-selected temperature. By pre-selecting the temperature of the surface while sputter etching, it is possible to predetermine the reflectance properties of the etched surface. The surface may be textured to absorb sunlight efficiently and have minimal emittance in the infrared region so as to be well-suited for use as a solar absorber for photothermal energy conversion.

  3. Method of sputter etching a surface

    DOE Patents [OSTI]

    Henager, C.H. Jr.

    1984-02-14

    The surface of a target is textured by co-sputter etching the target surface with a seed material adjacent thereto, while the target surface is maintained at a pre-selected temperature. By pre-selecting the temperature of the surface while sputter etching, it is possible to predetermine the reflectance properties of the etched surface. The surface may be textured to absorb sunlight efficiently and have minimal emittance in the infrared region so as to be well-suited for use as a solar absorber for photothermal energy conversion. 4 figs.

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Modeling, Cloud Properties Journal Reference: Liu, Y., P. H. Daum, R. McGraw, M. Miller, and S. Niu, 2007: Theoretical formulation for autoconversion rate of cloud droplet...

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Working Group(s): Cloud Properties Journal Reference: Fu, Q., W.B. Sun, and P. Yang, 1999: "Modeling of Scattering and Absorption by Nonspherical Cirrus Ice Particles at...

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Properties Journal Reference: Ou SS, KN Liou, XJ Wang, A Dybdahl, M Mussetto, LD Carey, J Niu, JA Kankiewicz, S Kidder, and TH Von der Haar. 2009. "Retrievals of mixed-phase...

  7. Intellectual Property

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    Property Intellectual Property The innovation assets we make available to our industry partners include the ideas, knowledge, skills and experience of our people. Contact thumbnail of Kathleen McDonald Head of Intellectual Property, Business Development Executive Kathleen McDonald Richard P. Feynman Center for Innovation (505) 667-5844 Email The primary mission of Los Alamos National Laboratory is to develop and deploy the technology required to protect and preserve our national security.

  8. Research Highlight

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    varying impacts on Earth's energy budget. Clouds with bases between five and seven kilometers above the Earth's surface, also known as mid-level clouds, occur over West Africa...

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cloud base. Radar and satellite observations show that clouds with tops from 1-11 kilometers contribute more or less equally to surface-measured precipitation at Graciosa. A...

  10. Research Highlight

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    scheme." Monthly Weather Review, 141(8), doi:10.1175MWR-D-13-00036.1. Figure 1: Spatial Distribution of the 5-hr accumulated surface precipitation for simulations that...

  11. Research Highlight

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    flux in summer partly due to model biases in simulating near-surface humidity. The model errors of humidity and latent heat flux further influence simulation of low-level clouds....

  12. Research Highlight

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    140(6), doi:10.1175MWR-D-11-00120.1. Sensitivity of surface precipitation to drop breakup parameterization. The spatial distribution over a two-dimensional domain of...

  13. Research Highlight

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    at the TOA (left panel) and at the surface (right panel) as a function of CN concentration. Figure 2. Cloud frequency of occurrence for three ranges of CN concentration: (a)...

  14. Research Highlight

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    of annual mean surface solar radiation from 1990 to 2005 as measured at sites in India showing continued significant dimming. The updated focal period 2000-2005 is visually...

  15. The Role of Surface Chemistry on the Cycling and Rate Capability...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Role of Surface Chemistry on the Cycling and Rate Capability of Lithium Positive ... More Documents & Publications The Role of Surface Chemistry and Bulk Properties on the ...

  16. Research Highlight

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    Radiative Forcing by Long-Lived Greenhouse Gases: Calculations with the AER Models Download a printable PDF Submitter: Iacono, M. J., Atmospheric & Environmental Research, Inc. Delamere, J. S., Tech-X Corporation Mlawer, E. J., Atmospheric & Environmental Research, Inc. Collins, W. D., Lawrence Berkeley National Laboratory Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Radiative Processes Journal Reference: Iacono, MJ, JS Delamere, EJ

  17. Researchers - JCAP

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    Our-Peopple-Hero_v2.jpg Researchers Who We Are JCAP Mission JCAP At A Glance Fact Sheets Organizational Chart Recent Science Technology Transfer Awards & Honors Senior Management Scientific Leadership Researchers Governance & Advisory Boards Operations & Administration Who we are Overview JCAP Mission JCAP At A Glance Fact Sheets Organizational Chart Our Achievements Recent Science Technology Transfer Awards & Honors Our People Senior Management Scientific Leadership Researchers

  18. Environmental Research

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    Dist. Category UC-l 1, 13 DE@ 010764 Health & Environmental Research Summary of Accomplishments Prepared by Office of Energy Research /U.S. Department of Energy Washington, D.C. 20585 Reprinted April 1984 Published by Technical Information Center/U.S. Department of Energy The purpose of this brief narrative is to foster an awareness of a publicly funded health and environmental research program chartered nearly forty years ago, of its contributions toward the national goal of safe and

  19. NETL Research

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    NETL Research Research One of the U.S. Department of Energy's (DOE) three strategic goals contained in the DOE's 2014-2018 Strategic Plan is to advance foundational science, innovate energy technologies, and inform data driven policies that enhance US economic growth and job creation, energy security, and environmental quality. DOE's National Energy Technology Laboratory contributes to this strategic goal through cutting-edge research and development focused on efficient energy use and clean

  20. PNNL: Research

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    Research at PNNL Research is our business With an unwavering focus on our missions, scientists and engineers at PNNL deliver science and technology. We conduct basic research that advances the frontiers of science. We translate discoveries into tools and technologies in science, energy, the environment and national security. For more than four decades, our experts have teamed with government, industry and academia to tackle some of the toughest problems facing our nation. The result: We're

  1. Research | NREL

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    Research Researching energy systems and technologies-and the science behind them-for a future powered by clean energy. Subscribe Stay connected with the latest news and research breakthroughs from NREL. Sign up now Photo of the U.S. Department of Energy's Energy Systems Integration Facility at NREL. Energy Systems Integration Facility The only facility in the nation focused on utility-scale clean energy grid integration. Learn More National Bioenergy Center National Center for Photovoltaics

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Size Distributions with Help from Satellites Download a printable PDF Submitter: Mitchell, D. L., Desert Research Institute d'Entremont, R. P., Atmospheric and Environmental...

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hagos, S. M., Pacific Northwest National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Life Cycle Journal Reference: NA...

  4. Research Highlight

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    Xie, S., Lawrence Livermore National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Modeling Journal Reference: Xie S,...

  5. Research Highlight

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    Xie, S., Lawrence Livermore National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Life Cycle Journal Reference: Xie...

  6. Research Highlight

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    Effects of Sea Spray on the Thermodynamics of the Hurricane Boundary Layer Download a printable PDF Submitter: Khain, A., The Hebrew University of Jerusalem Area of Research:...

  7. Research Highlight

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    Differences Between Tropical and Trade-Wind Shallow Cumuli Download a printable PDF Submitter: Ghate, V. P., Argonne National Laboratory Area of Research: Vertical Velocity Working...

  8. Research Highlight

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    Climate Research Facility located near Lamont, Oklahoma. Measurements from ARM Raman lidar and Doppler radar instruments were used to both initialize and evaluate the model. A...

  9. Research Highlight

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    in the Doppler spectra. Over the North Slope of Alaska, researchers used cloud radar Doppler velocity spectra, lidar backscattering coefficients and depolarization ratios, and...

  10. Research Highlight

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    Shallow Clouds Make the Case for Remote Sensing Instrumentation Submitter: McFarlane, S. A., U.S. Department of Energy Area of Research: Cloud DistributionsCharacterizations...

  11. Research Highlight

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    Quantifying Error in the Radiative Forcing of the First Aerosol Indirect Effect Submitter: McComiskey, A. C., National Oceanic and Atmospheric Administration Area of Research:...

  12. Research Highlight

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    Burning on the Prairies Submitter: Bhattacharya, A., Pacific Northwest National Laboratory Area of Research: Radiation Processes Working Group(s): Cloud-Aerosol-Precipitation...

  13. Research Highlight

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    energy budget of the atmospheric column. Researchers used measurements of atmospheric temperature and humidity profiles and ground-based retrievals of aerosol optical...

  14. Research Highlight

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    percent confidence intervals calculated from instrument uptime are given by the grey boundaries. The Atmospheric Radiation Measurement (ARM) Climate Research Facility has...

  15. Research Highlight

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    New Method for Three-Dimensional Imaging of Cirrus Clouds Submitter: Liou, K., University of California, Los Angeles Area of Research: Cloud DistributionsCharacterizations Working...

  16. Research Highlight

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    Cotton-Ball Clouds Contained Download a printable PDF Submitter: Berg, L., Pacific Northwest National Laboratory Area of Research: Cloud Processes Working Group(s): Cloud Life...

  17. Research Highlight

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    and climate change. The study, funded in large part by DOE's Atmospheric System Research program and recently discussed in the Quarterly Journal of the Royal Meteorological...

  18. Research Highlight

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    a printable PDF Submitter: Marshak, A., NASA - Goddard Space Flight Center Area of Research: Radiation Processes Working Group(s): Cloud-Aerosol-Precipitation Interactions...

  19. Research Highlight

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    Fog and Rain in the Amazon Download a printable PDF Submitter: Gentine, P., Columbia University Sobel, A., Columbia University Area of Research: Cloud-Aerosol-Precipitation...

  20. Research Highlight

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    2012. "Lateral entrainment rate in shallow cumuli: Dependence on dry air sources and probability density functions." Geophysical Research Letters, 39, L20812, doi:10.1029...

  1. Research Highlight

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    Modeling Cloud Forcing in the Tropical West Pacific Submitter: Kiehl, J., NCAR Area of Research: General Circulation and Single Column ModelsParameterizations Working Group(s):...

  2. Research Highlight

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    Validation of CERES-MODIS Cloud Retrievals Using the Azores Data Download a printable PDF Submitter: Dong, X., University of North Dakota Area of Research: Cloud Processes Working...

  3. Research Highlight

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    Kishcha, P., Tel-Aviv University Starobinets, B., Tel-Aviv University Kalashnikova, O., Jet Propulsion Laboratory Alpert, P., Tel-Aviv University Area of Research: Radiation...

  4. Research Highlight

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    Zhang, Q., University of California, Davis Fast, J. ., Pacific Northwest National Laboratory Area of Research: Aerosol Processes Working Group(s): Aerosol Life Cycle Journal...

  5. Research Highlight

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    to Lose Download a printable PDF Submitter: Laskin, A., Pacific Northwest National Laboratory Fast, J. ., Pacific Northwest National Laboratory Area of Research: Aerosol...

  6. Research Highlight

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    Probing the Birth of New Particles Download a printable PDF Submitter: Wang, J., Brookhaven National Laboratory Area of Research: Aerosol Processes Working Group(s): Aerosol Life...

  7. Research Highlight

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    ARM Sites Enable Assessment of Cluster Analysis for Identifying Cloud Regimes Submitter: Jakob, C., Monash University Area of Research: Cloud DistributionsCharacterizations...

  8. Research Highlight

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    Field Campaign Resource Allocation Using Statistical Decision Analysis Download a printable PDF Submitter: Hanlon, C., Pennsylvania State University Area of Research: Cloud...

  9. Research Highlight

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    Rosettes in Cirrus Download a printable PDF Submitter: Um, J., University of Illinois, Urbana McFarquhar, G., University of Illinois, Urbana Area of Research: Radiation Processes...

  10. UNIRIB: Research

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    of the University Radioactive Ion Beam (UNIRIB) consortium is to perform nuclear physics research, and provide training and education. UNIRIB member universities have gained...

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Black Carbon Aerosols and the Third Polar Ice Cap Submitter: Menon, S., Lawrence Berkeley National Laboratory Area of Research: General Circulation and Single Column Models...

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rain and Cloud Resistance Download a printable PDF Submitter: Flaherty, J., Pacific Northwest National Laboratory Area of Research: Cloud DistributionsCharacterizations Working...

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quantifying the Magnitude of Anomalous Solar Absorption Submitter: Ackerman, T. P., University of Washington Area of Research: General Circulation and Single Column Models...

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Development and Recent Evaluation of the MTCKD Model of Continuum Absorption Download a printable PDF Submitter: Mlawer, E. J., Atmospheric & Environmental Research, Inc. Area of...

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Area of Research: Cloud DistributionsCharacterizations Working Group(s): Cloud Life Cycle Journal Reference: Zhao Y, GG Mace, and JM Comstock. 2011. "The occurrence of particle ...

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Research: Cloud DistributionsCharacterizations Working Group(s): Cloud Life Cycle Journal Reference: NA Distributions of cloud optical depth from Aqua in four regions. The...

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Geophysical Research - Atmospheres, 118(16), doi:10.1002jgrd.50711. SPADE's methodology complements a traditional workflow for identifying resolution dependence by...

  18. Research Areas

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    in diverse research areas such as cell biology, lithography, infrared microscopy, radiology, and x-ray tomography. Time-Resolved These techniques exploit the pulsed nature of...

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Northwest National Laboratory, researchers found that a significant increase in the amount of light scattered by the clouds was caused by the amount of pollution in the air. ...

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CMBE - a New ACRF Data Product for Climate Studies Download a printable PDF Submitter: Xie, S., Lawrence Livermore National Laboratory Area of Research: Cloud Distributions...

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Lidar View of Clouds in Southeastern China Download a printable PDF Submitter: Li, Z., University of Maryland Cribb, M. C., University of Maryland Area of Research: Cloud...

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Small Processes Make a Big Difference in Model Outcomes Submitter: Cole, J. N., Canadian Centre for Climate Modelling and Analysis Area of Research: General Circulation and Single...

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liquid Water the Key to Arctic Cloud Radiative Closure Download a printable PDF Submitter: Shupe, M., University of Colorado Area of Research: Cloud DistributionsCharacterizations...

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Observational Evidence of Changes in Water Vapor, Clouds, and Radiation Submitter: Dong, X., University of North Dakota Area of Research: Cloud DistributionsCharacterizations...

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Comparison of Integrated Water Vapor Sensors: WVIOP-96 Submitter: Liljegren, J. C., Argonne National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical...

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Improved Accuracy in Liquid Water Path Retrievals Submitter: Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Clouds with Low Optical Water Depths...

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Integrated Water Vapor and Cloud Liquid Water at MCTEX Submitter: Liljegren, J. C., Argonne National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical Structures...

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Looking at the Full Spectrum for Water Vapor Download a printable PDF Submitter: Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Radiation...

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Progress in Understanding Water Vapor's Role in Models Submitter: Ackerman, T. P., University of Washington Area of Research: General Circulation and Single Column Models...

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    First Observation-Based Estimates of Cloud-Free Aerosol Radiative Forcing Across China Download a printable PDF Submitter: Li, Z., University of Maryland Area of Research: Aerosol...

  11. Research Areas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    environment and health issues; and to advance the engineering of biological systems for sustainable manufacturing. Biosciences Area research is coordinated through three...

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pollution + Storm Clouds Warmer Atmosphere Download a printable PDF Submitter: Fan, J., Pacific Northwest National Laboratory Area of Research: Cloud-Aerosol-Precipitation...

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud-Radiation Effects on Sea Ice Loss Download a printable PDF Submitter: Stephens, G. L., Colorado State University Area of Research: Cloud DistributionsCharacterizations...

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mid-Level Cloud Formation at the ARM Darwin Site Download a printable PDF Submitter: Riihimaki, L., Pacific Northwest National Laboratory Area of Research: Cloud Distributions...

  15. Deposition temperature dependence of material and Si surface passivation properties of O{sub 3}-based atomic layer deposited Al{sub 2}O{sub 3}-based films and stacks

    SciTech Connect (OSTI)

    Bordihn, Stefan; Mertens, Verena; Mller, Jrg W.; Kessels, W. M. M.

    2014-01-15

    The material composition and the Si surface passivation of aluminum oxide (Al{sub 2}O{sub 3}) films prepared by atomic layer deposition using Al(CH{sub 3}){sub 3} and O{sub 3} as precursors were investigated for deposition temperatures (T{sub Dep}) between 200?C and 500?C. The growth per cycle decreased with increasing deposition temperature due to a lower Al deposition rate. In contrast the material composition was hardly affected except for the hydrogen concentration, which decreased from [H]?=?3 at. % at 200?C to [H]?surface passivation performance was investigated after annealing at 300?C450?C and also after firing steps in the typical temperature range of 800?C925?C. A similar high level of the surface passivation performance, i.e., surface recombination velocity values <10?cm/s, was obtained after annealing and firing. Investigations of Al{sub 2}O{sub 3}/SiN{sub x} stacks complemented the work and revealed similar levels of surface passivation as single-layer Al{sub 2}O{sub 3} films, both for the chemical and field-effect passivation. The fixed charge density in the Al{sub 2}O{sub 3}/SiN{sub x} stacks, reflecting the field-effect passivation, was reduced by one order of magnitude from 310{sup 12}?cm{sup ?2} to 310{sup 11}?cm{sup ?2} when T{sub Dep} was increased from 300?C to 500?C. The level of the chemical passivation changed as well, but the total level of the surface passivation was hardly affected by the value of T{sub Dep}. When firing films prepared at of low T{sub Dep}, blistering of the films occurred and this strongly reduced the surface passivation. These results presented in this work demonstrate that a high level of surface passivation can be achieved for Al{sub 2}O{sub 3}-based films and stacks over a wide range of conditions when the combination of deposition temperature and annealing or firing temperature is carefully chosen.

  16. Mechanical properties and tribological behavior of contaminate

    Office of Scientific and Technical Information (OSTI)

    nanoparticles on micromachined surfaces. (Conference) | SciTech Connect Mechanical properties and tribological behavior of contaminate nanoparticles on micromachined surfaces. Citation Details In-Document Search Title: Mechanical properties and tribological behavior of contaminate nanoparticles on micromachined surfaces. No abstract prepared. Authors: DelRio, Frank W. [1] ; Dunn, Martin L. [1] ; de Boer, Maarten Pieter ; Boyce, Brad Lee + Show Author Affiliations (University of Colorado,

  17. Personal Property

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2014-10-16

    This Guide provides non-regulatory guidance and information to assist DOE organizations and contractors in implementing the DOE-wide and site-specific personal property management programs. It supplements the policy, requirements, and responsibilities information contained in the DOE Order cited above and clarifies the regulatory requirements contained in the Federal Property Management Regulation (FMR) and specific contracts.

  18. Intellectual Property Provisions (CDLB-115) Cooperative Agreement...

    Broader source: Energy.gov (indexed) [DOE]

    15.pdf More Documents & Publications CDLB-1003.PDF&0; Intellectual Property Provisions (CLB-115) Cooperative Agreement Research, Development, or Demonstration Large Business and...

  19. Intellectual Property Provisions (CDSB-115) Cooperative Agreement...

    Broader source: Energy.gov (indexed) [DOE]

    15.pdf More Documents & Publications CDSB-1003.PDF&0; Intellectual Property Provisions (CDLB-115) Cooperative Agreement - Special Data Statute Research, Development, or...

  20. Research | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Research Mission Statement The objective of PARC is to understand the basic scientific principles that underpin the efficient functioning of natural photosynthetic antenna systems as a basis for design of biohybrid and bioinspired architectures for next-generation systems for solar-energy conversion. Scientific Themes Through basic scientific research, PARC seeks to understand the principles of light harvesting and energy funneling as applied to The PARC Vision Graphic three

  1. Research - Cyclotron Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Overview Viewing gamma ray spectra. The Institute research program focuses on the atomic nucleus, a many-body system of strongly interacting constituents bound together by the strongest forces known in nature. The properties investigated often can be described in terms of the motions of single nucleons (neutrons and protons), the correlated motions of several nucleons, and the collective motions of many nucleons. On a finer scale, they can be understood in terms of the degrees of freedom of

  2. Energy Frontier Research Centers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Welcome US DOE Energy Frontier Research Center The Center for Revolutionary Materials for Solid State Energy Conversion will focus on solid state conversion of thermal energy to useful electrical power, both to increase the efficiency of traditional industrial energy processes and to tap new unused sources of energy such as solar thermal. Additionally materials with enhanced thermoelectric properties will find application in high efficiency, environmentally benign climate control systems. Our

  3. Task 6 - Subtask 1: PNNL Visit by JAEA Researchers to Evaluate the Feasibility of the FLESCOT Code for the Future JAEA Use for the Fukushima Surface Water Environmental Assessment

    SciTech Connect (OSTI)

    Onishi, Yasuo

    2014-01-01

    Four Japan Atomic Energy Agency (JAEA) researchers visited Pacific Northwest National Laboratory (PNNL) for seven working days and have evaluated the suitability and adaptability of FLESCOT to a JAEA’s supercomputer system to effectively simulate cesium behavior in dam reservoirs, river mouths, and coastal areas in Fukushima contaminated by the Fukushima Daiichi nuclear accident. PNNL showed the following to JAEA visitors during the seven-working day period: • FLESCOT source code • User’s manual • FLESCOT description – Program structure – Algorism – Solver – Boundary condition handling – Data definition – Input and output methods – How to run. During the visit, JAEA had access to FLESCOT to run with an input data set to evaluate the capacity and feasibility of adapting it to a JAEA super computer with massive parallel processors. As a part of this evaluation, PNNL ran FLESCOT for sample cases of the contaminant migration simulation to further describe FLESCOT in action. JAEA and PNNL researchers also evaluated time spent for each subroutine of FLESCOT, and the JAEA researcher implemented some initial parallelization schemes to FLESCOT. Based on this code evaluation, JAEA and PNNL determined that FLESCOT is • applicable to Fukushima lakes/dam reservoirs, river mouth areas, and coastal water • feasible to implement parallelization for the JAEA supercomputer. In addition, PNNL and JAEA researchers discussed molecular modeling approaches on cesium adsorption mechanisms to enhance the JAEA molecular modeling activities. PNNL and JAEA also discussed specific collaboration of molecular and computational modeling activities.

  4. INVESTIGATION OF BREAKDOWN INDUCED SURFACE DAMAGE ON 805 MHZ PILLBOX CAVITY INTERIOR SURFACES

    SciTech Connect (OSTI)

    Jana, M.R.; Chung, M.; Leonova, M.; Moretti, A.; Tollestrup,A.; Yonehara, K.; Freemire, B.; Torun, Y.; Bowring, D.; Flanagan, G.

    2013-09-25

    The MuCool Test Area (MTA) at Fermilab is a facility to develop the technology required for ionization cooling for a future Muon Collider and/or Neutrino Factory. As part of this research program, we have tested two 805 MHz vacuum RF cavities in a multi-Tesla magnetic field to study the effects of the static magnetic field on the cavity operation. This study gives useful information on field emitters in the cavity, dark current, surface conditioning, breakdown mechanisms and material properties of the cavity. All these factors determine the maximum accelerating gradient in the cavity. This paper discusses the image processing technique for quantitative estimation of spark damage spot distribution on cavity interior surfaces. The distribution is compared with the electric field distribution predicted by a computer code calculation. The local spark density is proportional to probability of surface breakdown and shows a power law dependence on the maximum electric field (E). This E dependence is consistent with the dark current calculated from the Fowler-Nordheim equation.

  5. Intellectual Property Provisions (GDLB-115) Grant - Special Data...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Data Statute Research, Development, or Demonstration Large Business and Foreign Entity Intellectual Property Provisions (GDLB-115) Grant - Special Data Statute Research,...

  6. Surface treatment of ceramic articles

    DOE Patents [OSTI]

    Komvopoulos, K.; Brown, I.G.; Wei, B.; Anders, S.; Anders, A.; Bhatia, C.S.

    1998-12-22

    A process is disclosed for producing an article with improved ceramic surface properties including providing an article having a ceramic surface, and placing the article onto a conductive substrate holder in a hermetic enclosure. Thereafter a low pressure ambient is provided in the hermetic enclosure. A plasma including ions of solid materials is produced the ceramic surface of the article being at least partially immersed in a macroparticle free region of the plasma. While the article is immersed in the macroparticle free region, a bias of the substrate holder is biased between a low voltage at which material from the plasma condenses on the surface of the article and a high negative voltage at which ions from the plasma are implanted into the article. 15 figs.

  7. Surface treatment of ceramic articles

    DOE Patents [OSTI]

    Komvopoulos, Kyriakos (Orinda, CA); Brown, Ian G. (Berkeley, CA); Wei, Bo (Daly City, CA); Anders, Simone (Albany, CA); Anders, Andre (Albany, CA); Bhatia, C. Singh (Morgan Hill, CA)

    1998-01-01

    A process for producing an article with improved ceramic surface properties including providing an article having a ceramic surface, and placing the article onto a conductive substrate holder in a hermetic enclosure. Thereafter a low pressure ambient is provided in the hermetic enclosure. A plasma including ions of solid materials is produced the ceramic surface of the article being at least partially immersed in a macroparticle free region of the plasma. While the article is immersed in the macroparticle free region, a bias of the substrate holder is biased between a low voltage at which material from the plasma condenses on the surface of the article and a high negative voltage at which ions from the plasma are implanted into the article.

  8. Heterogeneous Catalysis and Surface Science - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heterogeneous Catalysis and Surface Science / Part I: Surface Science in JCAP Laboratories Heterogeneous Catalysis and Surface Science research in JCAP focuses on the basic understanding of the relationships among the structure, composition, and reactivity of electrocatalysts. Knowledge gained from surface science experimentation can be implemented toward the discovery of better heterogeneous catalysts for solar-fuel production from carbon dioxide and water. REFERENCE Soriaga, M. P. et al.

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Climate Models: Results from TC4 and ISDAC Download a printable PDF Submitter: Mitchell, D. L., Desert Research Institute Mishra, S., DOE - SunShot Initiative, AAAS S&T...

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Wong M, M Ovchinnikov, and M Wang. 2015. "Evaluation of subgrid-scale hydrometeor transport...

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    using Tropical Warm Pool-International Cloud Experiment data." Journal of Geophysical Research - Atmospheres, 114, D14107, doi:10.10292008JD011220. Wang W and X Liu. 2009....

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    C., Texas A&M University Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Lappen C and C Schumacher. 2014. "The role of tilted heating in the...

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Feng Z, X Dong, B Xi, S McFarlane, A Kennedy, B Lin, and P Minnis....

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Area of Research: General Circulation and Single Column ModelsParameterizations Working Group(s): Cloud Modeling Journal Reference: Ghan, S.J. and Leung, L.R., 1999: "A...

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Adoption of RRTMG in the NCAR CAM5 and CESM1 Global Climate Models Download a printable PDF Submitter: Iacono, M. J., Atmospheric & Environmental Research, Inc. Collins, W. D.,...

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research - Atmospheres, 119(23), 10.10022014JD022038. a) Dependence of inversion cap on mean SSTs and b) dependence of low-level relative humidities on inversion cap based...

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Area of Research: Cloud DistributionsCharacterizations Working Group(s): Cloud Modeling Journal Reference: Naud, C, A Del Genio, GG Mace, S Benson, EE Clothiaux, and P Kollias. ...

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Journal Reference: Long CN, SA McFarlane, A Del Genio, P Minnis, TP Ackerman, J Mather, J Comstock, GG Mace, M Jensen, and C Jakob. 2013. "ARM research in the equatorial western ...

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Area of Research: General Circulation and Single Column ModelsParameterizations Working Group(s): Cloud Life Cycle Journal Reference: Mace GG, S Houser, S Benson, SA Klein, and QL ...

  20. Research Facility,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Delivering the Data As a general condition for use of the ARM Climate Research Facility, users are required to include their data in the ARM Data Archive. All data acquired...

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    McFarlane, S. A., U.S. Department of Energy Khain, A., The Hebrew University of Jerusalem Area of Research: Cloud DistributionsCharacterizations Working Group(s): Cloud...

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geophysical Research Letters, , doi:10.10022015GL064009. ONLINE. A 14-minute sequence of cloud growth as observed by a camera located at the MAST Academy in Miami,...

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Retrieving Dust Optical Depth and Mineral Composition from Infrared Spectra Download a printable PDF Submitter: Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: Turner DD. 2008. "Ground-based retrievals of optical depth, effective radius, and composition of airborne mineral dust above the Sahel." Journal of Geophysical Research - Atmospheres, 113, D00E03,

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Clouds Brighten Up the Sky Near Them Download a printable PDF Submitter: Varnai, T., University of Maryland, Baltimore County/JCEST Marshak, A., NASA - Goddard Space Flight Center Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: Varnai T and A Marshak. 2009. "MODIS observations of enhanced clear sky reflectance near clouds." Geophysical Research Letters, 36, L06807, doi:10.1029/2008GL037089. Figure 1. Illustration of clouds enhancing the

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Field Experiments to Improve the Treatment of Radiation in the Mid-to-Upper Troposphere Download a printable PDF Submitter: Turner, D. D., National Oceanic and Atmospheric Administration Mlawer, E. J., Atmospheric & Environmental Research, Inc. Area of Research: Radiation Processes Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Turner DD and EJ Mlawer. 2010. "The Radiative Heating in Underexplored Bands Campaigns (RHUBC)." Bulletin of the American

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ice Heating Up Cold Clouds Download a printable PDF Submitter: Ovchinnikov, M., Pacific Northwest National Laboratory Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Ovchinnikov M, A Korolev, and J Fan. 2011. "Effects of ice number concentration on dynamics of a shallow mixed-phase stratiform cloud." Journal of Geophysical Research - Atmospheres, 116, D00T06, doi:10.1029/2011JD015888. The mighty cloud

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    First Ground-Based Spectral Observations of the Entire Infrared Band Download a printable PDF Submitter: Turner, D. D., National Oceanic and Atmospheric Administration Mlawer, E. J., Atmospheric & Environmental Research, Inc. Area of Research: Radiation Processes Working Group(s): Aerosol Life Cycle, Cloud Life Cycle Journal Reference: Turner DD, EJ Mlawer, G Bianchini, MP Cadeddu, S Crewell, JS Delamere, RO Knuteson, G Maschwitz, M Mlynzcak, S Paine, L Palchetti, and DC Tobin. 2012.

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    "Invisible" Giants in the Sky Download a printable PDF Submitter: Kassianov, E., Pacific Northwest National Laboratory Area of Research: Radiation Processes Working Group(s): Aerosol Life Cycle Journal Reference: Kassianov E, M Pekour, and J Barnard. 2012. "Aerosols in central California: Unexpectedly large contribution of coarse mode to aerosol radiative forcing." Geophysical Research Letters, 39, L20806, doi:10.1029/2012GL053469. Daily averaged values of (a, b) the direct

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lord of the Wings: Elevated Particles a Rising Star Download a printable PDF Submitter: Kassianov, E., Pacific Northwest National Laboratory Area of Research: Radiation Processes Working Group(s): Aerosol Life Cycle Journal Reference: Kassianov E, C Flynn, J Redemann, B Schmid, PB Russell, and A Sinyuk. 2012. "Initial assessment of the Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR)-based aerosol retrieval: Sensitivity study." Atmosphere, 3,

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Brass Ring of Climate Modeling Download a printable PDF Submitter: Ghan, S. J., Pacific Northwest National Laboratory Area of Research: Aerosol Processes Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Ghan SJ, SJ Smith, M Wang, K Zhang, K Pringle, K Carslaw, J Pierce, S Bauer, and P Adams. 2013. "A simple model of global aerosol indirect effects." Journal of Geophysical Research - Atmospheres, 118, 1-20. The simple model of aerosol effects on clouds

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Twenty Years Serving Climate Science Download a printable PDF Submitter: Mather, J. H., Pacific Northwest National Laboratory Area of Research: Cloud Processes Working Group(s): Aerosol Life Cycle, Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: Mather JH and JW Voyles. 2013. "The ARM Climate Research Facility: a review of structure and capabilities." Bulletin of the American Meteorological Society, 94(3), doi:10.1175/BAMS-D-11-00218.1. A scanning ARM

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluation of WRF Microphysics Schemes in Squall Line Simulations Download a printable PDF Submitter: Dong, X., University of North Dakota Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Wu D, B Xi, Z Feng, A Kennedy, M Grenchen, G Matt, and T W-K. 2013. "The impact of various WRF single-moment microphysics parameterizations on squall line precipitation events." Journal of Geophysical Research - Atmospheres, 118, doi:10.1002/jgrd.50798.

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Invisible Giants in the Sky Download a printable PDF Submitter: Kassianov, E., Pacific Northwest National Laboratory Area of Research: Cloud-Aerosol-Precipitation Interactions Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Kassianov E, M Pekour, and J Barnard. 2012. "Aerosols in central California: Unexpectedly large contribution of coarse mode to aerosol radiative forcing." Geophysical Research Letters, 39, L20806, doi:10.1029/2012GL053469. Photo

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Accuracy of GFS and ECMWF Hurricane Sandy Track Forecasts Dependent on Cumulus Parameterization Download a printable PDF Submitter: Bassill, N. P., University of Utah Zipser, E., University of Utah Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle Journal Reference: Bassill NP. 2014. "Accuracy of early GFS and ECMWF Sandy (2012) track forecasts: Evidence for a dependence on cumulus parameterization." Geophysical Research Letters, ,

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Vapor Turbulence Statistics in the Convective Boundary Layer Download a printable PDF Submitter: Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Life Cycle Journal Reference: Turner DD, V Wulfmeyer, LK Berg, and JH Schween. 2014. "Water vapor turbulence profiles in stationary continental convective mixed layers." Journal of Geophysical Research - Atmospheres, 119,

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Novel Approach for Introducing 3D Cloud Spatial Structure Into 1D Radiative Transfer Download a printable PDF Submitter: Huang, D., Brookhaven National Laboratory Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: Huang D and Y Liu. 2015. "A novel approach for introducing cloud spatial structure into cloud radiative transfer parameterizations." Environmental Research Letters, 9(12), 124022. An example of a 3D cloud liquid water content field

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Comparison of Vertical Velocities in Cirrus Derived from Aircraft and Ground-based Radar Download a printable PDF Submitter: Muhlbauer, A., University of Washington Kalesse, H., Leibniz Institute for Tropospheric Research Area of Research: Vertical Velocity Working Group(s): Cloud Life Cycle Journal Reference: Muhlbauer A, H Kalesse, and P Kollias. 2014. "Vertical velocities and turbulence in midlatitude anvil cirrus: A comparison between in situ aircraft measurements and ground-based

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Assessing Impact of Shattered Artifacts on Measured Size Distributions Download a printable PDF Submitter: McFarquhar, G., University of Illinois, Urbana Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle Journal Reference: N/A Figure 1. (a) Photograph of 2DC with standard tips; and (b) with modified tips installed on the left pod of the National Research Council of Canada Convair 580 during ISDAC. Figure 2. (a) Ratio of number concentration of particles

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Role of Ice Nuclei Recycling in the Maintenance of Cloud Ice in Arctic Mixed-phase Stratocumulus Download a printable PDF Submitter: Solomon, A., NOAA/ESRL/Physical Sciences Division Feingold, G., NOAA - Earth System Research Laboratory Area of Research: Cloud-Aerosol-Precipitation Interactions Working Group(s): Cloud Life Cycle Journal Reference: Solomon A, G Feingold, and MD Shupe. 2015. "The role of ice nuclei recycling in the maintenance of cloud ice in Arctic mixed-phase

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pollution Changes Clouds' Ice Crystal Genesis Download a printable PDF Submitter: Kulkarni, G., Pacific Northwest National Laboratory Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Kulkarni GR, K Zhang, C Zhao, M Nandasiri, V Shutthanandan, X Liu, L Berg, and J Fast. 2015. "Ice formation on nitric acid-coated dust particles: Laboratory and modeling studies." Journal of Geophysical Research - Atmospheres, 120(15), doi:10.1002/2014JD022637.

  1. Research Projects

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    Research Projects Joint Los Alamos National Laboratory/UCSD Research Projects Collaborations between Los Alamos National Laboratory and the University of California at San Diego (UCSD) Jacobs School of Engineering Contact Institute Director Charles Farrar (505) 663-5330 Email UCSD EI Director Michael Todd (858) 534-5951 Professional Staff Assistant Jutta Kayser (505) 663-5649 Email Administrative Assistant Stacy Baker (505) 663-5233 Email "Since 2003, LANL has funded numerous collaborative

  2. Research Capabilities

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Capabilities Research Capabilities These capabilities are our science and engineering at work for the national security interest in areas from global climate to cyber security, from nonproliferation to new materials, from clean energy, to supercomputing. thumbnail of Bioscience At Los Alamos, scientists and engineers are working to unlock many of the mechanisms found in nature to improve humanity's ability to battle diseases, create new forms of environmentally friendly and abundant

  3. Personal Property

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2015-06-09

    This Guide provides non-regulatory guidance and information to assist DOE organizations and contractors in implementing the DOE-wide and site-specific personal property management programs. Supersedes DOE G 580.1-1.

  4. Historic Properties

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Historic Properties Historic Properties Our environmental stewardship commitment: we will cleanup the past, minimize impacts for current environmental operations, and create a sustainable future. April 12, 2012 TA-18-0001, site of the 1946 Louis Slotin criticality accident TA-18-0001, site of the 1946 Louis Slotin criticality accident, which significantly influenced future criticality safety programs. Contact Environmental Communication & Public Involvement P.O. Box 1663 MS M996 Los Alamos,

  5. Intellectual Property

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intellectual Property Intellectual Property Los Alamos protects the innovations of its scientists and engineers by filing patent applications and copyrights. Patents and Patent Applications Publication Number Title US20120001631A1 Ultra-Low Field Nuclear Magnetic Resonance Method to Discriminate and Identify Materials US20120055264A1 Apparatus and Method for Noninvasive Particle Detection Using Doppler Spectroscopy US20120227473A1 Apparatus and Method for Visualization of Particles Suspended in

  6. Thermal Properties Measurement Report

    SciTech Connect (OSTI)

    Carmack, Jon; Braase, Lori; Papesch, Cynthia; Hurley, David; Tonks, Michael; Zhang, Yongfeng; Gofryk, Krzysztof; Harp, Jason; Fielding, Randy; Knight, Collin; Meyer, Mitch

    2015-08-01

    The Thermal Properties Measurement Report summarizes the research, development, installation, and initial use of significant experimental thermal property characterization capabilities at the INL in FY 2015. These new capabilities were used to characterize a U3Si2 (candidate Accident Tolerant) fuel sample fabricated at the INL. The ability to perform measurements at various length scales are important and provide additional data that is not currently in the literature. However, the real value of the data will be in accomplishing a phenomenological understanding of the thermal conductivity in fuels and the ties to predictive modeling. Thus, the MARMOT advanced modeling and simulation capability was utilized to illustrate how the microstructural data can be modeled and compared with bulk characterization data. A scientific method was established for thermal property measurement capability on irradiated nuclear fuel samples, which will be installed in the Irradiated Material Characterization Laboratory (IMCL).

  7. Intellectual Property Provisions

    Office of Environmental Management (EM)

    15 Intellectual Property Provisions (CDLB-115) Cooperative Agreement - Special Data Statute Research, Development, or Demonstration Large Business and Foreign Entity 01. FAR 52.227-1 Authorization and Consent (DEC 2007) Alternate I (APR 1984) 02. FAR 52.227-2 Notice and Assistance Regarding Patent and Copyright Infringement (DEC 2007) 03. 2 CFR 910 Appendix A of Subpart D Rights in Data - Programs Covered under Special Data Statutes 04. 2 CFR 910 Appendix A of Subpart D Patent Rights (Large

  8. Intellectual Property Provisions

    Office of Environmental Management (EM)

    15 Intellectual Property Provisions (CLB-115) Cooperative Agreement Research, Development, or Demonstration Large Business and Foreign Entity 01. FAR 52.227-1 Authorization and Consent (DEC 2007) Alternate I (APR 1984) 02. FAR 52.227-2 Notice and Assistance Regarding Patent and Copyright Infringement (DEC 2007) 03. 2 CFR 910 Appendix A of Subpart D Rights in Data - General 04. 2 CFR 910 Appendix A of Subpart D Patent Rights (Large Business Firms - No Waiver) NOTE: In reading these provisions,

  9. Intellectual Property Provisions

    Office of Environmental Management (EM)

    15 Intellectual Property Provisions (GDLB-115) Grant - Special Data Statute Research, Development, or Demonstration Large Business and Foreign Entity 01. 2 CFR 910 Appendix A of Subpart D Rights in Data - Programs Covered under Special Data Statutes 02. 2 CFR 910 Appendix A of Subpart D Patent Rights (Large Business Firms - No Waiver) GDLB-115 1 01. 2 CFR 910, Appendix A of Subpart D, Rights in Data - Programs Covered Under Special Data Statutes (a) Definitions Computer Data Bases, as used in

  10. Intellectual Property Provisions - Assistance

    Office of Environmental Management (EM)

    15 Intellectual Property Provisions (CDSB-115) Cooperative Agreement - Special Data Statute Research, Development, or Demonstration Domestic Small Business 01. FAR 52.227-1 Authorization and Consent (DEC 2007) Alternate I (APR 1984) 02. FAR 52.227-2 Notice and Assistance Regarding Patent and Copyright Infringement (DEC 2007) 03. 2 CFR 910 Appendix A of Subpart D Rights in Data - Programs Covered under Special Data Statutes 04. 2 CFR 910 Appendix A of Subpart D Patent Rights (Small Business Firms

  11. RESEARCH QUARTERLY

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RESEARCH QUARTERLY First Quarter 2015 Th 90 Ac 89 Pa 91 U 92 Np 93 Pu 94 Am 95 Cm 96 Bk 97 Cf 98 Es 99 Fm 100 Md 101 No 102 Lr 103 Glenn T. Seaborg Institute for Transactinium Science/Los Alamos National Laboratory Actinide Research Quarterly About the cover The crystalline structure of plutonium in its elemental form, and in molecules and compounds with other elements, is the basis for understanding the intriguing chemistry, physics, and engineering of plutonium molecules and compounds. Colored

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM M-PACE Data Used to Evaluate and Improve Arctic Mixed-Phase Clouds Simulated in Climate Models Download a printable PDF Submitter: Xie, S., Lawrence Livermore National Laboratory Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Modeling Journal Reference: Xie, S, J Boyle, SA Klein, X Liu, and S Ghan. 2008. "Simulations of Arctic mixed-phase clouds in forecasts with CAM3 and AM2 for M-PACE." Journal of Geophysical Research 113,

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Long-Term Observations of Convective Boundary Layer Using Insect Returns at SGP Download a printable PDF Submitter: Chandra, A. S., McGill University Area of Research: Vertical Velocity Working Group(s): Cloud Life Cycle Journal Reference: Chandra AS, P Kollias, SE Giangrande, and SA Klein. 2010. "Long-term observations of the convective boundary layer using insect radar returns at the SGP ARM Climate Research Facility." Journal of Climate, 23, 5699-5714. Example of time-height mapping

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Improving the Treatment of Radiation in Climate Models Download a printable PDF Submitter: Delamere, J. S., Tech-X Corporation Area of Research: Radiation Processes Working Group(s): Aerosol Life Cycle, Cloud Life Cycle Journal Reference: Delamere JS, SA Clough, VH Payne, EJ Mlawer, DD Turner, and RR Gamache. 2010. "A far-infrared radiative closure study in the Arctic: Application to water vapor." Journal of Geophysical Research - Atmospheres, 115, D17106, 10.1029/2009JD012968. The

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Predicting Arctic Sea Ice Loss Download a printable PDF Submitter: Liu, X., University of Wyoming Area of Research: Cloud-Aerosol-Precipitation Interactions Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Liu X, S Xie, J Boyle, SA Klein, X Shi, Z Wang, W Lin, SJ Ghan, M Earle, PS Liu, and A Zelenyuk. 2011. "Testing cloud microphysics parameterizations in NCAR CAM5 with ISDAC and M-PACE observations." Journal of Geophysical Research, 116, D00T11,

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effect of Dry Deposition of Condensable Organic Vapors on SOA Formation in the Urban Plume Download a printable PDF Submitter: Hodzic, A., NCAR Area of Research: Aerosol Processes Working Group(s): Aerosol Life Cycle Journal Reference: Hodzic A, S Madronich, B Aumont, J Lee-Taylor, T Karl, M Camredon, and C Mouchel-Vallon. 2014. "Limited influence of dry deposition of semi-volatile organic vapors on secondary organic aerosol formation in the urban plume." Geophysical Research Letters,

  17. Errvironmentaf Research

    Office of Legacy Management (LM)

    online at www.sciencedirect.com Environmental Research 10 1 (2006) 3 4 4 1 Errvironmentaf Research Do scientists and fishermen collect the same size fish? Possible implications for exposure assessment Joanna urger^^^^', Michael ~ o c h f e l d ~ ~ ~ , Sean Christian W. ~ e i t n e r ~ . ~ , Stephen ~ e w e t t ~ , Daniel SnigarofP, Ronald snigarofff, Tim Starnrng, Shawn ~ a r ~ e f , Max ~ o b e r ~ * , Heloise chenelotd, Robert patrickh, Conrad D. volzi, James ~ e s t o d 'Division of Life

  18. Postdoctoral Research Awards Annual Research Meeting: Joseph...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Joseph Mondloch Postdoctoral Research Awards Annual Research Meeting: Joseph Mondloch Postdoctoral Research Awards Annual Research Meeting: Joseph Mondloch poster presentation. PDF ...

  19. Postdoctoral Research Awards Annual Research Meeting: Padmaja...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Padmaja Gunda Postdoctoral Research Awards Annual Research Meeting: Padmaja Gunda Poster Presentation at 2012 EERE Annual Research Meeting, Postdoctoral Research Awards, from the ...

  20. Postdoctoral Research Awards Annual Research Meeting: Brandon...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Brandon Mercado Postdoctoral Research Awards Annual Research Meeting: Brandon Mercado Poster Presentation at 2012 EERE Annual Research Meeting, Postdoctoral Research Awards, from ...

  1. Research on thermophoretic and inertial aspects of ash particle deposition on heat exchanger surfaces in coal-fired equipment. Quarterly report No. 9, September 1, 1988--November 30, 1988

    SciTech Connect (OSTI)

    Rosner, D.E.

    1988-12-01

    A real-time laser light-reflectivity technique is being used to study simultaneous thermophoretic and inertial influences on the deposition behavior of MgO particles produced via ultrasonic nebulization (submicrometer range). The deposition surface (a concave platinum ribbon) is exposed to a high velocity/temperature jet of alkali sulfate-free combustion products exiting from a seeded (C3{sub 3}H{sub 8}/air) microcombustor (110 cm{sup 3}). The reflectivity data were calibrated against deposition rates obtained from SEM pictures of the target, and were normalized with the nominal particle feed rate, in order to obtain the mass transfer Stanton number, St{sub m}, trends depicted in Figure 1. For the submicron (ca. 0.7{mu}m) particles inertial effects appear to set in at Stokes (Stk) numbers of O(10{sup {minus}2}) (an order of magnitude lower than the ones needed for ``pure`` inertial impaction), affecting significantly the dominant thermophoretic deposition mechanism. A first order (in Stk) theoretical analysis of the problem in which particle inertia is treated as equivalent to ``pressure diffusion,`` cannot explain the observed dependence of the deposition rate on Stk. We are presently formulating a Lagrangian approach, valid for all values of Stk, in order to interpret these data. In addition, a Single Particle Counter (SPC) and Transit Time Velocimeter (TTV), are being developed, to allow more precise measurements of particle feed rates and velocities.

  2. Research Areas | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Stewardship Science Academic Alliances / Research Areas Research Areas Properties of Materials under Extreme Conditions and Hydrodynamics During open solicitations research proposals are solicited for grants and Centers of Excellence in the area of fundamental properties and response of materials under extreme conditions (condensed matter physics and materials science, hydrodynamics and fluid dynamics). Extreme conditions include material response when subjected to one or more of the following:

  3. Thermophysical properties of uranium dioxide - Version 0 for peer review

    SciTech Connect (OSTI)

    Fink, J.K.; Petri, M.C.

    1997-02-01

    Data on thermophysical properties of solid and liquid UO{sub 2} have been reviewed and critically assessed to obtain consistent thermophysical property recommendations for inclusion in the International Nuclear Safety Center Database on the World Wide Web (http://www.insc.anl.gov.). Thermodynamic properties that have been assessed are enthalpy, heat capacity, melting point, enthalpy of fusion, thermal expansion, density, surface tension, and vapor pressure. Transport properties that have been assessed are thermal conductivity, thermal diffusivity, viscosity, and emissivity. Summaries of the recommendations with uncertainties and detailed assessments for each property are included in this report and in the International Nuclear Safety Center Database for peer review. The assessments includes a review of the experiments and data, an examination of previous recommendations, the basis for selecting recommendations, a determination of uncertainties, and a comparison of recommendations with data and with previous recommendations. New data and research that have led to new recommendations include thermal expansion and density measurements of solid and liquid UO{sub 2}, derivation of physically-based equations for the thermal conductivity of solid UO{sub 2}, measurements of the heat capacity of liquid UO{sub 2}, and measurements and analysis of the thermal conductivity of liquid UO{sub 2}.

  4. ARM - Funded Research Proposals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Proposals Science Research Themes Research Highlights Journal Articles Collaborations Atmospheric System Research (ASR) Earth System Modeling Regional &...

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Modification of the Atmospheric Boundary Layer by a Small Island: Observations from Nauru Submitter: Long, C. N., NOAA Global Monitoring Division/CIRES Area of Research: Cloud Distributions/Characterizations Working Group(s): Radiative Processes Journal Reference: Matthews, S., J. M. Hacker, J. Cole, J. Hare, C. N. Long, and R. M. Reynolds, (2007): Modification of the atmospheric boundary layer by a small island: observations from Nauru, MWR, Vol. 135, No. 3, pages 891–905. Figure 1.

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Study Aerosol Humidity Effects Using the ARM Measurements Submitter: Li, Z., University of Maryland Area of Research: Radiation Processes Working Group(s): Aerosol Journal Reference: Jeong, M.-J., Z. Li, E. Andrews, and S.-C. Tsay (2007). Effect of aerosol humidification on the column aerosol optical thickness over the Atmospheric Radiation Measurement Southern Great Plains site, J. Geophys. Res., 112, D10202, doi:10.1029/2006JD007176. (a)-(j) Column-mean aerosol humidification factor as

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Using Doppler Radar to Characterize Cloud Parameters Download a printable PDF Submitter: Kogan, Y., University of Oklahoma - CIMMS Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Modeling Journal Reference: Kogan, Y.L., Z. N. Kogan, and D. B. Mechem, 2007: Assessing the errors of microphysical retrievals in Marine Stratocumulus based on Doppler radar parameters, J. Hydrometeorol., GEWEX special issue, 8, 665-677. Figure 1. The errors of drizzle flux R retrieval

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluation of a New Mixed-Phase Cloud Microphysics Parameterization with SCAM, CAPT Forecasts and M-PACE Observations Download a printable PDF Submitter: Liu, X., University of Wyoming Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Modeling Journal Reference: Liu, X, S Xie, and SJ Ghan. 2007. "Evaluation of a new mixed-Phase cloud microphysics parameterization with the NCAR single column climate model (SCAM) and ARM M-PACE

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optical Depth Measurements by Shadowband Radiometers and Their Uncertainties Download a printable PDF Submitter: Alexandrov, M. D., Columbia University Area of Research: Radiation Processes Working Group(s): Aerosol Journal Reference: Applied Optics, accepted Sept. 2007. Effective offset to measured optical depths due to tilt of 1-degree in different directions. Offset observed in C1 MFRSR AOD relative to Cimel and representative offset due to tilt. Appearance of shading failure and effect on

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Five-Year Statistics of Shallow Clouds at the ACRF SGP Site Download a printable PDF Submitter: Berg, L., Pacific Northwest National Laboratory Kassianov, E., Pacific Northwest National Laboratory Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Modeling Journal Reference: Berg, LK, and EI Kassianov. 2008. "Temporal variability of fair-weather cumulus statistics at the ARM SGP site." Journal of Climate 21, 3344-3358. Figure 1. Five-year mean ARSCL VAP

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Susceptibility Measures Potential Cloud Sensitivity to First Aerosol Indirect Effect Download a printable PDF Submitter: Oreopoulos, L., NASA Platnick, S., NASA - Goddard Space Flight Center Area of Research: Cloud Distributions/Characterizations Working Group(s): Radiative Processes Journal Reference: Platnick, S, and L Oreopoulos. 2008. "Radiative susceptibility of cloudy atmospheres to droplet number perturbations: 1. Theoretical analysis and examples from MODIS." Journal of

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Simple Algorithm to Find Cloud Optical Depth Applied to Thin Ice Clouds Download a printable PDF Submitter: Barnard, J., University of Nevada Reno Long, C. N., NOAA Global Monitoring Division/CIRES Kassianov, E., Pacific Northwest National Laboratory McFarlane, S. A., U.S. Department of Energy Comstock, J. M., Pacific Northwest National Laboratory Freer, M., University of Illinois, Urbana McFarquhar, G., University of Illinois, Urbana Area of Research: Cloud Distributions/Characterizations

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Forcing Boundary Layer Cloud Systems with Multi-Dimensional Radiation Download a printable PDF Submitter: Mechem, D. B., University of Kansas Kogan, Y., University of Oklahoma - CIMMS Ovchinnikov, M., Pacific Northwest National Laboratory Davis, A. B., Jet Propulsion Laboratory Evans, F., University of Colorado Ellingson, R. G., Florida State University Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Modeling, Radiative Processes Journal Reference: Mechem, DB, YL

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Significant Decadal Brightening over the Continental United States Download a printable PDF Submitter: Long, C. N., NOAA Global Monitoring Division/CIRES Dutton, E. G., NOAA/OAR/ESRL Augustine, J., National Oceanic and Atmospheric Administration Wiscombe, W. J., Brookhaven National Laboratory Wild, M., Institute for Atmospheric and Climate Science - ETH Zurich McFarlane, S. A., U.S. Department of Energy Flynn, C. J., Pacific Northwest National Laboratory Area of Research: Radiation Processes

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Microwave and Millimeter-Wave Radiometric and Radiosonde Observations in an Arctic Environment Download a printable PDF Submitter: Westwater, E. R., University of Colorado Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: Mattioli V, ER Westwater, D Cimini, AJ Gasiewski, M Klein, and V Leuski. 2008. "Microwave and millimeter-wave radiometric and radiosonde observations in an arctic environment." Journal of Atmospheric and Oceanic Technology,

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ice Nuclei and Global Warming Download a printable PDF Submitter: Zeng, X., Morgan State University GSFC, N., NASA GSFC Zhang, M., Stony Brook University Hou, A., NASA - Goddard Space Flight Center Xie, S., Lawrence Livermore National Laboratory Lang, S. E., NASA - Goddard Space Flight Center Li, X., University of Maryland, Baltimore County Starr, D. O., NASA - Goddard Space Flight Center Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Improving the Numerical Simulation of Squall Lines Download a printable PDF Submitter: Morrison, H. C., NCAR Thompson, G., NCAR Tatarskii, V., Georgia Institute of Technology Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Modeling Journal Reference: Morrison HC, G Thompson, and V Tatarskii. 2009. "Impact of cloud microphysics on the development of trailing stratiform precipitation in a simulated squall line: Comparison of one- and two-moment schemes."

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mechanisms Affecting the Transition from Shallow to Deep Convection over Land Download a printable PDF Submitter: Zhang, Y., Lawrence Livermore National Laboratory Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Life Cycle Journal Reference: Zhang Y and SA Klein. 2010. "Mechanisms affecting the transition from shallow to deep convection over land: Inferences from observations of the diurnal cycle collected at the ARM Southern Great

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Impact of Horizontal Resolution on Climate Model Simulations of Tropical Moist Processes Download a printable PDF Submitter: Boyle, J., Lawrence Livermore National Laboratory Klein, S., Lawrence Livermore National Laboratory Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Life Cycle Journal Reference: Boyle JS and SA Klein. 2010. "Impact of horizontal resolution on climate model forecasts of tropical precipitation and diabatic heating

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Bulk Microphysical Scheme That Includes Riming Intensity and Temperature Dependent Ice Ch Download a printable PDF Submitter: Lin, Y., Geophysical Fluid Dynamics Laboratory Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Life Cycle Journal Reference: Lin Y and BA Colle. 2011. "A new bulk microphysical scheme that includes riming intensity and temperature dependent ice characteristics." Monthly Weather Review, 139(3),

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Downwelling Infrared Radiance Climatology for the ARM Southern Great Plains Site Download a printable PDF Submitter: Turner, D. D., National Oceanic and Atmospheric Administration Gero, J., University of Wisconsin Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: Turner DD and PJ Gero. 2011. "Downwelling infrared radiance temperature climatology for the Atmospheric Radiation Measurement Southern Great Plains site." Journal of Geophysical

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluation of CRM Intercomparison Simulations Using TWP-ICE Observations, Part 1 Download a printable PDF Submitter: Varble, A., University of Utah Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle Journal Reference: Varble AC, AM Fridlind, EJ Zipser, AS Ackerman, J Chaboureau, J Fan, A Hill, SA McFarlane, J Pinty, and B Shipway. 2011. "Evaluation of cloud-resolving model intercomparison simulations using TWP-ICE observations: Precipitation and cloud

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Estimating the Ice Crystal Enhancement Factor in the Tropics Download a printable PDF Submitter: Zeng, X., Morgan State University GSFC, N., NASA GSFC Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: Zeng X, W Tao, T Matsui, S Xie, S Lang, M Zhang, DO Starr, and X Li. 2011. "Estimating the ice crystal enhancement factor in the tropics." Journal of the

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Consistency Analysis of ARESE Aircraft Measurements Submitter: Li, Z., University of Maryland Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: Li, Z., A.P. Trishchenko, H.W. Barker, G.L. Stephens, and P. Partain, 1999: "Analyses of Atmospheric Radiation Measurement (ARM) program's Enhanced Shortwave Experiment (ARESE) multiple data sets for studying cloud absorption," J. of Geophys. Res. 104(D16):19127-19134 Figure 1. Comparisons of TOA

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Indirect Impact of Atmospheric Aerosols on an Ensemble of Deep Convective Clouds Download a printable PDF Submitter: Grabowski, W., NCAR Morrison, H. C., NCAR Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Grabowski WW and H Morrison. 2011. "Indirect impact of atmospheric aerosols in idealized simulations of convective-radiative quasi-equilibrium. Part II: Double-moment microphysics." Journal of

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Snow Particle Observations in Arctic Clouds Download a printable PDF Submitter: Morrison, H. C., NCAR Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle Journal Reference: Morrison H, P Zuidema, GM McFarquhar, A Bansemer, and AJ Heymsfield. 2011. "Microphysical observations in shallow mixed-phase and deep frontal Arctic cloud systems." Quarterly Journal Royal Meteorological Society, 137(659), doi:10.1002/qj.840. Fitted size distribution intercept

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Understanding Ice Formation in Arctic Mixed-Phase Boundary-Layer Clouds During ISDAC Download a printable PDF Submitter: Ackerman, A., NASA - Goddard Institute for Space Studies Fridlind, A. M., NASA - Goddard Institute for Space Studies Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Avramov A, AS Ackerman, AM Fridlind, B van Diedenhoven, G Botta, K Aydin, J Verlinde, KV Alexei, W Strapp, GM McFarquhar, R

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Dance of Aerosols Download a printable PDF Submitter: Song, C., Pacific Northwest National Laboratory Area of Research: Aerosol Processes Working Group(s): Aerosol Life Cycle Journal Reference: Song C, RA Zaveri, JE Shilling, ML Alexander, and M Newburn. 2011. "Effect of hydrophilic organic seed aerosols on secondary organic aerosol formation from ozonolysis of α-pinene." Environmental Science & Technology, 45(17), doi:10.1021/es201225c. The injection of alpha-pinene, a

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Modeling the Sensitivity of Convection to Tropospheric Humidity Download a printable PDF Submitter: Del Genio, A. D., National Aeronautics and Space Administration Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Life Cycle Journal Reference: Del Genio AD. 2011. "Representing the sensitivity of convective cloud systems to tropospheric humidity in general circulation models." Surveys in Geophysics, , doi:10.1007/s10712-011-9148-9.

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    What Exactly Do Metrics for Aerosol-Cloud Interactions Represent? Download a printable PDF Submitter: McComiskey, A. C., National Oceanic and Atmospheric Administration Area of Research: Cloud-Aerosol-Precipitation Interactions Working Group(s): Aerosol Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: McComiskey A and G Feingold. 2012. "The scale problem in quantifying aerosol indirect effects." Atmospheric Chemistry and Physics, 12, doi:10.5194/acp-12-1031-2012.

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TOA Radiation Budget of Convective Core/Stratiform Rain/Anvil Clouds from Deep Convection Download a printable PDF Submitter: Feng, Z., Pacific Northwest National Laboratory Dong, X., University of North Dakota Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle Journal Reference: Feng Z, XQ Dong, BK Xi, C Schumacher, P Minnis, and M Khaiyer. 2011. "Top-of-atmosphere radiation budget of convective core/stratiform rain and anvil clouds from deep

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Simulating the Impact of Aerosols on Tropical Deep Convection Download a printable PDF Submitter: Morrison, H. C., NCAR Area of Research: Cloud-Aerosol-Precipitation Interactions Working Group(s): Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: Morrison H and WW Grabowski. 2011. "Cloud-system resolving model simulations of aerosol indirect effects on tropical deep convection and its thermodynamic environment." Atmospheric Chemistry and Physics, 11(20),

  13. Research Highlight

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    Unraveling the Complexity of Arctic Mixed-Phase Clouds Download a printable PDF Submitter: Morrison, H. C., NCAR Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: Morrison H, G de Boer, G Feingold, J Harrington, M Shupe, and K Sulia. 2011. "Resilience of persistent Arctic mixed-phase clouds." Nature Geoscience, 5, doi:10.1038/ngeo1332. A conceptual model that illustrates the primary processes and basic physical structure of persistent Arctic

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trends in Downwelling Longwave Radiation over SGP Download a printable PDF Submitter: Gero, J., University of Wisconsin Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: Gero P and DD Turner. 2011. "Long-term trends in downwelling spectral infrared radiance over the U.S. Southern Great Plains." Journal of Climate, 24(18),

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spectrally Invariant Approximation Within Atmospheric Radiative Transfer Download a printable PDF Submitter: Marshak, A., NASA - Goddard Space Flight Center Area of Research: Radiation Processes Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Marshak A, Y Knyazikhin, JC Chiu, and WJ Wiscombe. 2011. "Spectrally-invariant approximation within atmospheric radiative transfer." Journal of the Atmospheric Sciences, 68(12), doi:10.1175/JAS-D-11-060.1. Ratio of

  16. Research Highlight

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    Tropical Rain Clouds Still a Challenge to Cloud-Resolving Models Download a printable PDF Submitter: Fridlind, A. M., NASA - Goddard Institute for Space Studies Ackerman, A., NASA - Goddard Institute for Space Studies Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: Fridlind AM, AS Ackerman, J Chaboureau, J Fan, WW Grabowski, AA Hill, TR Jones, MM Khaiyer, G Liu, P Minnis, H Morrison, L Nguyen,

  17. Research Highlight

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    Comparing Global Atmospheric Model Simulations of Tropical Convection Download a printable PDF Submitter: Lin, Y., Geophysical Fluid Dynamics Laboratory Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Life Cycle Journal Reference: N/A Mean profiles of (first column) total precipitation normalized Q1, (second column) convective precipitation normalized convective heating, (third column) stratiform heating, and (fourth column) convective

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mexico City Carbon-Containing Particle Composition Simulated Download a printable PDF Submitter: Zaveri, R., Pacific Northwest National Laboratory Area of Research: Radiation Processes Working Group(s): Aerosol Life Cycle Journal Reference: Lee-Taylor J, S Madronich, B Aumont, M Camredon, A Hodzic, GS Tyndall, E Aperl, and RA Zaveri. 2012. "Explicit modeling of organic chemistry and secondary organic aerosol partitioning for Mexico City and its outflow plume." Atmospheric Chemistry and

  19. Research Highlight

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    The Influence of Regional Anthropogenic Emission Reductions on Aerosol Direct Radiative Forcing Download a printable PDF Submitter: Bergmann, D., Lawrence Livermore National Laboratory Area of Research: Radiation Processes Working Group(s): Aerosol Life Cycle Journal Reference: Yu H, M Chin, J West, C Atherton, N Bellouin, D Bergmann, I Bey, H Bian, T Diehl, G Forberth, P Hess, M Schulz, D Shindell, T Takemura, and Q Tan. 2012. "An HTAP multi-model assessment of the influence of regional

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measured Radiative Cooling from Reflective Roofs in India Download a printable PDF Submitter: Fischer, M. L., Lawrence Berkeley National Laboratory Area of Research: Radiation Processes Working Group(s): Aerosol Life Cycle, Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: Salamanca F, S Tonse, S Menon, V Garg, KP Singh, M Naja, and ML Fischer. 2012. "Top-of-atmosphere radiative cooling with white roofs: Experimental verification and model-based evaluation."

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tropical Clouds: from Jekyll to Hyde Submitter: Hagos, S. M., Pacific Northwest National Laboratory Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle Journal Reference: Hagos SM and R Leung. 2012. "Large-scale environmental variables and transition to deep convection in cloud resolving model simulations: A vector representation." Journal of Advances in Modeling Earth Systems, 4(M11001), 2012MS000155, doi:10.1029/2012MS000155. The relationship

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Development and Validation of a Black Carbon Mixing State Resolved Three-Dimensional Model Download a printable PDF Submitter: Fast, J. ., Pacific Northwest National Laboratory Area of Research: Aerosol Processes Working Group(s): Aerosol Life Cycle Journal Reference: Matsui H, M Koike, Y Kondo, N Moteki, JD Fast, and RA Zaveri. 2013. "Development and validation of a black carbon mixing state resolved three-dimensional model: Aging processes and radiative impact." Journal of

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Mixing State of Carbonaceous Aerosol Particles in Northern and Southern California Measured During CARES and CalNex Download a printable PDF Submitter: Zaveri, R., Pacific Northwest National Laboratory Area of Research: Aerosol Processes Working Group(s): Aerosol Life Cycle Journal Reference: Cahill JF, K Suski, JH Seinfeld, RA Zaveri, and KA Prather. 2012. "The mixing state of carbonaceous aerosol particles in Northern and Southern California measured during CARES and CalNex

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    What Controls the Vertical Extent of Continental Shallow Cumulus? Download a printable PDF Submitter: Zhang, Y., Lawrence Livermore National Laboratory Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Zhang Y and SA Klein. 2013. "Factors controlling the vertical extent of fair-weather shallow cumulus clouds over land: investigation of diurnal-cycle observations collected at the ARM Southern Great Plains site." Journal of the Atmospheric Sciences,

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tropical Ice Cloud Simulations Using Scripps Single Column Model (SCM) Reveal Range of Model Uncertainties Submitter: McFarquhar, G., University of Illinois, Urbana Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Modeling Journal Reference: McFarquhar, G.M., S. Iacobellis, R.C.J. Somerville. SCM Simualtions of Tropical Ice Clouds Using Observationally Based Parameterizations of Microphysics, Journal of Climate: Vol 15, No. 11, pp.

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    An Application of Linear Programming Techniques to ARM Polarimetric Radar Processing Download a printable PDF Submitter: Giangrande, S., Brookhaven National Laboratory Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Giangrande SE, R McGraw, and L Lei. 2013. "An application of linear programming to polarimetric radar differential phase processing." Journal of Atmospheric and Oceanic Technology, , . ACCEPTED. C-band scanning ARM precipitation radar

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Linking Ice Nucleation to Aerosols and Its Impact on CAM5 Simulated Arctic Clouds and Radiation Download a printable PDF Submitter: Xie, S., Lawrence Livermore National Laboratory Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Life Cycle Journal Reference: Xie S, X Liu, C Zhao, and Y Zhang. 2013. "Sensitivity of CAM5 simulated arctic clouds and radiation to ice nucleation parameterization." Journal of Climate, 26(16),

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Forecast Calls for Better Models: Examining the Core Components of Arctic Clouds to Clear Their Influence on Climate Download a printable PDF Submitter: Laskin, A., Pacific Northwest National Laboratory Area of Research: Cloud-Aerosol-Precipitation Interactions Working Group(s): Aerosol Life Cycle Journal Reference: Hiranuma N, SD Brooks, RC Moffet, A Glen, A Laskin, MK Gilles, P Liu, AM Macdonald, JW Strapp, and GM McFarquhar. 2013. "Chemical characterization of individual particles and

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Is Cumulus Drag a Rayleigh Drag? Download a printable PDF Submitter: Romps, D., Lawrence Berkeley National Laboratory Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Romps DM. 2013. "Rayleigh damping in the free troposphere." Journal of the Atmospheric Sciences, , . ACCEPTED. Hovmoller diagrams of wind profiles in a large-eddy simulation of deep convection. Note the different damping rates and descent speeds for different wavelengths. In toy

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluation of Gridded SACR Reflectivity Observations and Vertical Doppler Velocity Retrievals Download a printable PDF Submitter: Lamer, K., Pennsylvania State University Kollias, P., Stony Brook University Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle Journal Reference: Lamer K, A Taterevic, I Jo, and P Kollias. 2013. "Evaluation of gridded Scanning ARM Cloud Radar reflectivity observations and vertical Doppler velocity retrievals."

  11. Research Highlight

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    Improving Estimates of Cloud Condensation Nuclei Concentration Download a printable PDF Submitter: Li, Z., University of Maryland Area of Research: Cloud-Aerosol-Precipitation Interactions Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Liu J and Z Li. 2014. "Estimation of cloud condensation nuclei concentration from aerosol optical quantities: influential factors and uncertainties." Atmospheric Chemistry and Physics, 14(1), doi:10.5194/acp-14-1-2014.

  12. Research Highlight

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    Multi-scale Variations of Decade-long Cloud Fractions from Six Different Platforms over the SGP Download a printable PDF Submitter: Wu, W., Brookhaven National Laboratory Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle Journal Reference: Wu W, Y Liu, MP Jensen, T Toto, MJ Foster, and CN Long. 2014. "A comparison of multiscale variations of decade-long cloud fractions from six different platforms over the Southern Great Plains in the United

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turbulent Entrainment-Mixing Processes in Cumuli Download a printable PDF Submitter: Liu, Y., Brookhaven National Laboratory Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Lu C, Y Liu, and S Niu. 2014. "Entrainment mixing parameterization in shallow cumuli and effects of secondary mixing events." Chinese Science Bulletin, 59(9), doi:10.1007/s11434-013-0097-1. Relationships between homogeneous mixing degree (ψ3) and two transition scale numbers

  14. Research Highlight

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    Scientists Uncover Combustion Mechanism to Better Predict Warming by Wildfires Download a printable PDF Submitter: Dubey, M. K., Los Alamos National Laboratory Donahue, N., Carnegie Mellon University Area of Research: Radiation Processes Working Group(s): Aerosol Life Cycle Journal Reference: Saleh R, E Robinson, D Tkacik, A Ahern, S Liu, A Aiken, R Sullivan, A Presto, M Dubey, R Yokelson, N Donahue, and A Robinson. 2014. "Brownness of organics in aerosols from biomass burning linked to

  15. Research Highlight

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    Parameterization of Vertical Velocity in Shallow Convections Download a printable PDF Submitter: Zhang, M., Stony Brook University Area of Research: Vertical Velocity Working Group(s): Cloud Life Cycle Journal Reference: Wang X and M Zhang. 2014. "Vertical velocity in shallow convection for different plume types." Journal of Advances in Modeling Earth Systems, 6(2), doi:10.1002/2014MS000318. Mean profiles of vertical velocity in convective cores (red); convective updrafts (blue); and

  16. Research Highlight

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    A New Theory of Time-dependent Freezing and Its Application to Investigation of Formation of Hail Download a printable PDF Submitter: Khain, A., The Hebrew University of Jerusalem Phillips, V., University of Leeds Area of Research: Cloud Processes Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Phillips VT, A Khain, N Benmoshe, E Ilotoviz, and A Ryzhkov. 2014. "Theory of time-dependent freezing. II: Scheme for freezing raindrops and simulations by a cloud model

  17. Research Highlight

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    On the Right Track for Tropical Clouds Download a printable PDF Submitter: Hagos, S. M., Pacific Northwest National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Hagos SM, Z Feng, K Landu, and C Long. 2014. "Advection, moistening, and shallow-to-deep convection transitions during the initiation and propagation of Madden-Julian Oscillation." Journal of Advances in Earth System

  18. Research Highlight

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    Tall Clouds from Tiny Raindrops Grow Download a printable PDF Submitter: Hagos, S. M., Pacific Northwest National Laboratory Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Hagos S, Z Feng, CD Burleyson, KS Lim, CN Long, D Wu, and T Greg. 2014. "Evaluation of convection-permitting model simulations of cloud populations associated with the Madden-Julian Oscillation using data collected during the AMIE/DYNAMO field campaign." Journal of Geophysical

  19. Research Highlight

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    Finding the Causes for Consistently Low Biased Stratiform Rainfall in Models Submitter: Varble, A., University of Utah Zipser, E., University of Utah Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Varble A, EJ Zipser, AM Fridlind, P Zhu, AS Ackerman, J Chaboureau, J Fan, A Hill, B Shipway, and C Williams. 2014. "Evaluation of cloud-resolving and limited area model simulations using TWP-ICE observations. 2. Precipitation microphysics." Journal of

  20. Research Highlight

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    Modeling Precipitating Cumulus Congestus Observed by the ARM Radar Suite During the MC3E Field Campaign Download a printable PDF Submitter: Mechem, D. B., University of Kansas Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: Mechem DB, SE Giangrande, CS Wittman, P Borque, T Toto, and P Kollias. 2015. "Insights from modeling and observational evaluation of a precipitating continental cumulus event observed