Sample records for reported coal synfuel

  1. Refining and upgrading of synfuels from coal and oil shales by advanced catalytic processes. Quarterly report, January-March 1981

    SciTech Connect (OSTI)

    Sullivan, R. F.; O'Rear, D. J.

    1981-05-01T23:59:59.000Z

    Samples of SRC-II naphtha, middle distillate, and heavy distillate were received and analyzed. These samples are part of a planned study of the potential biological hazards of synthetic crudes. These oils will be hydrotreated when DOE provides blending instructions. Five drums of EDS syncrude made from Big Brown Texas lignite were received and analyzed. The boiling range and other properties of this syncrude are very similar to the properties of the previously studied H-Coal and SRC-II syncrudes. The hydrotreating severities, which were employed to upgrade the H-Coal and SRC-II syncrudes to transportation fuels, are expected to be close to the severities needed for the EDS syncrude.

  2. Tri-State Synfuels Project Review: Volume 12. Fluor project status. [Proposed Henderson, Kentucky coal to gasoline plant; engineering

    SciTech Connect (OSTI)

    Not Available

    1982-06-01T23:59:59.000Z

    The purpose of this report is to document and summarize activities associated with Fluor's efforts on the Tri-State Synfuels Project. The proposed facility was to be coal-to-transport fuels facility located in Henderson, Kentucky. Tri-State Synfuels Company was participating in the project as a partner of the US Department of Energy per terms of a Cooperative Agreement resulting from DOE's synfuel's program solicitation. Fluor's initial work plan called for preliminary engineering and procurement services to the point of commitment for construction for a Sasol Fischer-Tropsch plant. Work proceeded as planned until October 1981 when results of alternative coal-to-methanol studies revealed the economic disadvantage of the Synthol design for US markets. A number of alternative process studies followed to determine the best process configuration. In January 1982 Tri-State officially announced a change from Synthol to a Methanol to Gasoline (MTG) design basis. Further evaluation and cost estimates for the MTG facility eventually led to the conclusion that, given the depressed economic outlook for alternative fuels development, the project should be terminated. Official announcement of cancellation was made on April 13, 1982. At the time of project cancellation, Fluor had completed significant portions of the preliminary engineering effort. Included in this report are descriptions and summaries of Fluor's work during this project. In addition location of key project data and materials is identified and status reports for each operation are presented.

  3. Ambient monitoring of pollutants around synfuel plants : final report

    E-Print Network [OSTI]

    Golomb, D.

    1984-01-01T23:59:59.000Z

    This study was undertaken to aid in the evaluation of Environmental Monitoring Plans (EMP) submitted to the U.S. Synfuel Corporation by prospective operators of large-scale synfuel plants who are applying for financial ...

  4. Processing needs and methodology for wastewaters from the conversion of coal, oil shale, and biomass to synfuels

    SciTech Connect (OSTI)

    Not Available

    1980-05-01T23:59:59.000Z

    The workshop identifies needs to be met by processing technology for wastewaters, and evaluates the suitability, approximate costs, and problems associated with current technology. Participation was confined to DOE Environmental Control Technology contractors to pull together and integrate past wastewater-related activities, to assess the status of synfuel wastewater treatability and process options, and to abet technology transfer. Particular attention was paid to probable or possible environmental restrictions which cannot be economically met by present technology. Primary emphasis was focussed upon process-condensate waters from coal-conversion and shale-retorting processes. Due to limited data base and time, the workshop did not deal with transients, upsets, trade-offs and system optimization, or with solids disposal. The report is divided into sections that, respectively, survey the water usage and effluent situation (II); identify the probable and possible water-treatment goals anticipated at the time when large-scale plants will be constructed (III); assess the capabilities, costs and shortcomings of present technology (IV); explore particularly severe environmental-control problems (V); give overall conclusions from the Workshop and recommendations for future research and study (VI); and, finally, present Status Reports of current work from participants in the Workshop (VII).

  5. Improving process performances in coal gasification for power and synfuel production

    SciTech Connect (OSTI)

    M. Sudiro; A. Bertucco; F. Ruggeri; M. Fontana [University of Padova, Milan (Italy). Italy and Foster Wheeler Italiana Spa

    2008-11-15T23:59:59.000Z

    This paper is aimed at developing process alternatives of conventional coal gasification. A number of possibilities are presented, simulated, and discussed in order to improve the process performances, to avoid the use of pure oxygen, and to reduce the overall CO{sub 2} emissions. The different process configurations considered include both power production, by means of an integrated gasification combined cycle (IGCC) plant, and synfuel production, by means of Fischer-Tropsch (FT) synthesis. The basic idea is to thermally couple a gasifier, fed with coal and steam, and a combustor where coal is burnt with air, thus overcoming the need of expensive pure oxygen as a feedstock. As a result, no or little nitrogen is present in the syngas produced by the gasifier; the required heat is transferred by using an inert solid as the carrier, which is circulated between the two modules. First, a thermodynamic study of the dual-bed gasification is carried out. Then a dual-bed gasification process is simulated by Aspen Plus, and the efficiency and overall CO{sub 2} emissions of the process are calculated and compared with a conventional gasification with oxygen. Eventually, the scheme with two reactors (gasifier-combustor) is coupled with an IGCC process. The simulation of this plant is compared with that of a conventional IGCC, where the gasifier is fed by high purity oxygen. According to the newly proposed configuration, the global plant efficiency increases by 27.9% and the CO{sub 2} emissions decrease by 21.8%, with respect to the performances of a conventional IGCC process. 29 refs., 7 figs., 5 tabs.

  6. Procedure for matching synfuel users with potential suppliers. Final report

    SciTech Connect (OSTI)

    None

    1981-09-26T23:59:59.000Z

    A procedure has been developed for matching prospective users and producers of synthetic fuels. The matching procedure, which involves a hierarchical screening process, is designed to assist OFC in: locating a supplier for a firm that wishes to obtain synthetic fuel exemption (Fuel Use Act); determining whether the fuel supplier proposed by a petitioner is technically and economically capable of meeting the petitioner's needs; and assisting the Synthetic Fuels Corporation in evaluating potential markets for synthetic fuels. Application of the screening procedure resulted in the identification of one or more candidates for supplying synthetic fuel to each of the prospective users. In this report the development of the screening procedure is described. Chapter 1 contains a detailed description of the seven screens; Chapter 2 describes the development of the hierarchical procedure for applying the screens to each synthetic fuels project; Chapter 3 describes the modification of the screening procedure for low and medium Btu gas; Chapter 4 describes the application of the procedure. Appendix A is a list of references used in developing the procedure; Appendix B is a detailed listing of proposed and ongoing synthetic fuel projects.

  7. Refining and upgrading of synfuels from coal and oil shales by advanced catalytic processes. Sixth interim report Task 9: hydrotreating 400/sup 0/F+ SRC-II oil for biological studies

    SciTech Connect (OSTI)

    Sullivan, R.F.

    1982-04-01T23:59:59.000Z

    400/sup 0/F+ SRC-II oil derived from Pittsburgh Seam coal was hydrotreated to provide DOE samples for subsequent biological testing at the Oak Ridge National Laboratory. Samples containing about 500 ppM nitrogen, 2000 ppM nitrogen, and 5000 ppM nitrogen were prepared. These samples do not represent finished products, but conditions were selected to provide a wide range of processing severities. The feedstock was somewhat higher boiling and more difficult to hydrotreat than another 400/sup 0/F+ SRC-II oil studied previously.

  8. Tri-State Synfuels Project Review: Volume 8. Commercial status of licensed process units. [Proposed Henderson, Kentucky coal to gasoline plant; licensed commercial processes

    SciTech Connect (OSTI)

    Not Available

    1982-06-01T23:59:59.000Z

    This document demonstrates the commercial status of the process units to be used in the Tri-State Synfuels Project at Henderson, Kentucky. The basic design philosophy as established in October, 1979, was to use the commercial SASOL II/III plants as a basis. This was changed in January 1982 to a plant configuration to produce gasoline via a methanol and methanol to gasoline process. To accomplish this change the Synthol, Oil workup and Chemical Workup Units were eliminated and replaced by Methanol Synthesis and Methanol to Gasoline Units. Certain other changes to optimize the Lurgi liquids processing eliminated the Tar Distillation and Naphtha Hydrotreater Units which were replaced by the Partial Oxidation Unit. The coals to be gasified are moderately caking which necessitates the installation of stirring mechanism in the Lurgi Dry Bottom gasifier. This work is in the demonstration phase. Process licenses either have been obtained or must be obtained for a number of processes to be used in the plant. The commercial nature of these processes is discussed in detail in the tabbed sections of this document. In many cases there is a list of commercial installations at which the licensed equipment is used.

  9. Syn-fuels: general

    SciTech Connect (OSTI)

    Not Available

    1981-03-01T23:59:59.000Z

    The General Accounting Office recently published results of a study conducted for the US Congress entitled, ''Oil and Natural Gas From Alaska, Canada, and Mexico - Only Limited Help for US.'' Copies are available from the GPO as report number EMD-80-72. From this, the GAO made the following observations: (1) The gap between domestic consumption and production of conventional oil and gas can be expected to widen during the 1980's and 1990's, and our import dependency can be expected to continue. This observation is made with consideration of Alaskan production, which, regardless of how promising it may appear to be, requires long lead times for production to come on line and is subject to uncertainty. (2) Concentrated effort should be made to increase our domestic production, including the development of synthetic fuels, and unconventional oil and gas resources. (3) The decline in domestic production cannot be offset by synfuels development during the 1980's and 1990's because of lead times and other constraints, but unconventional gas appears to offer more promise because several technologies are already operational on a commercial basis.

  10. Support Requirements for Synfuels

    E-Print Network [OSTI]

    Hyland, M. J.

    1981-01-01T23:59:59.000Z

    ON aATlVE COSTS OF NH3 EFFECT OF INFLATION Fig. 6 SYN-FUEL MARKETS 250 SUBSTITUTE NATURAL GAS 240 INDUSTRIAL FUEL GAS 2~ - REGIONAL 220 - INDIVIDUAL 210 LIQUIDS 200 - HIGH VISCOSITY OIL - TAR SANDS - OIL SHALE 190 PLANT '" 2 \\ll...

  11. Low-rank coal research. Final technical report, April 1, 1988--June 30, 1989, including quarterly report, April--June 1989

    SciTech Connect (OSTI)

    Not Available

    1989-12-31T23:59:59.000Z

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  12. Quarterly coal report

    SciTech Connect (OSTI)

    Young, P.

    1996-05-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about U.S. coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for October through December 1995 and aggregated quarterly historical data for 1987 through the third quarter of 1995. Appendix A displays, from 1987 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  13. Preparation of environmental analyses for synfuel and unconventional gas technologies

    SciTech Connect (OSTI)

    Reed, R.M. (ed.)

    1982-09-01T23:59:59.000Z

    Government agencies that offer financial incentives to stimulate the commercialization of synfuel and unconventional gas technologies usually require an analysis of environmental impacts resulting from proposed projects. This report reviews potentially significant environmental issues associated with a selection of these technologies and presents guidance for developing information and preparing analyses to address these issues. The technologies considered are western oil shale, tar sand, coal liquefaction and gasification, peat, unconventional gas (western tight gas sands, eastern Devonian gas shales, methane from coal seams, and methane from geopressured aquifers), and fuel ethanol. Potentially significant issues are discussed under the general categories of land use, air quality, water use, water quality, biota, solid waste disposal, socioeconomics, and health and safety. The guidance provided in this report can be applied to preparation and/or review of proposals, environmental reports, environmental assessments, environmental impact statements, and other types of environmental analyses. The amount of detail required for any issue discussed must, by necessity, be determined on a case-by-case basis.

  14. Annual Coal Report 2013

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001)gasoline prices4 OilU.S. OffshoreOilAnnual Coal Report

  15. Low-rank coal research

    SciTech Connect (OSTI)

    Weber, G. F.; Laudal, D. L.

    1989-01-01T23:59:59.000Z

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  16. Annual Coal Distribution Report

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecade Year-0 Year-1 Year-2Cubic

  17. Quarterly coal report, January--March 1998

    SciTech Connect (OSTI)

    Young, P.

    1998-08-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for January through March 1998 and aggregated quarterly historical data for 1992 through the fourth quarter of 1997. Appendix A displays, from 1992 on, detailed quarterly historical coal imports data. To provide a complete picture of coal supply and demand in the United States, historical information has been integrated in this report. 58 tabs.

  18. Quarterly coal report, October--December 1996

    SciTech Connect (OSTI)

    NONE

    1997-05-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for October through December 1996 and aggregated quarterly historical data for 1990 through the third quarter of 1996. Appendix A displays, from 1988 on, detailed quarterly historical coal imports data. To provide a complete picture of coal supply and demand in the US, historical information has been integrated in this report. 8 figs., 72 tabs.

  19. Quarterly Coal Report, July--September 1994

    SciTech Connect (OSTI)

    Not Available

    1995-02-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1994 and aggregated quarterly historical data for 1986 through the second quarter of 1994. Appendix A displays, from 1986 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons. To provide a complete picture of coal supply and demand in the United States, historical information has been integrated in this report. Additional historical data can also be found in the following EIA publications : Annual Energy Review 1993 (DOE/EIA-0384(93)), Monthly Energy Review (DOE/EIA-0035), and Coal Data: A Reference (DOE/EIA-0064(90)). The historical data in this report are collected by the EIA in three quarterly coal surveys (coal consumption at manufacturing plants, coal distribution, and coal consumption at coke plants), one annual coal production survey, and two monthly surveys of electric utilities. All data shown for 1993 and previous years are final. Data for 1994 are preliminary.

  20. Quarterly coal report, January--March 1996

    SciTech Connect (OSTI)

    NONE

    1996-08-01T23:59:59.000Z

    This report presents detailed quarterly data for March 1996 and historical data for 1988 through 1995 on coal production, distribution, imports and exports, prices, consumption, and stocks.

  1. Proceedings of the opportunities in the synfuels industry

    SciTech Connect (OSTI)

    Not Available

    1992-12-31T23:59:59.000Z

    World interest in coal-based synthetic fuels technology is like a roller coaster ride. Interest soars when energy prices are high or world oil supplies are threatened. When energy is inexpensive and oil is plentiful, interest plummets. However, some people remain undaunted by the ups and downs of the synfuels industry. They cling tenaciously to the idea that coal-based synthetic fuels are the world`s energy future. They are the select group attending the SynOps `92 symposium in Bismarck, North Dakota. SynOps `92 participants represent an extraordinary combination of visionaries and practical thinkers. They believe the ``coal refinery`` concept will eventually provide the most efficient and productive use of our coal resources. They know that coal is a valuable resource which can be used to produce a huge variety of valuable nonfuel products. They also recognize that until technology can make alternative fuels economically feasible, the world will continue to rely heavily on fossil fuels--especially coal, the world`s most abundant energy resource. Individual papers have been entered.

  2. Quarterly coal report, April--June 1997

    SciTech Connect (OSTI)

    NONE

    1997-11-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for April through June 1997 and aggregated quarterly historical data for 1991 through the first quarter of 1997. Appendix A displays, from 1991 on, detailed quarterly historical coal imports data. Appendix B gives selected quarterly tables converted to metric tons. To provide a complete picture of coal supply and demand in the US, historical information has been integrated in this report. 8 figs., 73 tabs.

  3. Quarterly coal report, July--September 1997

    SciTech Connect (OSTI)

    NONE

    1998-02-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks. Coke production consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1997 and aggregated quarterly historical data for 1991 through the second quarter of 1997. Appendix A displays, from 1991 on, detailed quarterly historical coal imports data. 72 tabs.

  4. Quarterly coal report, July--September 1998

    SciTech Connect (OSTI)

    NONE

    1999-02-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1998 and aggregated quarterly historical data for 1992 through the second quarter of 1998. 58 tabs.

  5. Quarterly coal report, April--June, 1998

    SciTech Connect (OSTI)

    NONE

    1998-11-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for April through June 1998 and aggregated quarterly historical data for 1992 through the first quarter of 1998. Appendix A displays, from 1992 on, detailed quarterly historical coal imports data. 58 tabs.

  6. Quarterly coal report, April--June 1990

    SciTech Connect (OSTI)

    Not Available

    1990-11-02T23:59:59.000Z

    The Quarterly Coal Report provides comprehensive information about US coal production, exports, imports, receipts, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. This issue presents detailed quarterly data for April 1990 through June 1990, aggregated quarterly historical data for 1982 through the second quarter of 1990, and aggregated annual historical data for 1960 through 1989 and projected data for selected years from 1995 through 2010. To provide a complete picture of coal supply and demand in the United States, historical information and forecasts have been integrated in this report. 7 figs., 37 tabs.

  7. Heteroatom speciation in coal liquefaction via FTIR coupled with liquid chromatography. Quarterly progress report, October 1-December 31, 1983

    SciTech Connect (OSTI)

    Taylor, L.T.

    1984-05-01T23:59:59.000Z

    The objectives of the research are (1) evaluate the potential of FT-IR for qualitative functional group detection in chromatographic fractions of highly polar materials, (2) develop separation techniques with the aid of FT-IR detection for concentration of oxygen, nitrogen and sulfur functionalities in synfuels, (3) describe and quantify the various heteroatom functionalities in selected solvent refined coal fractions, (4) place speciation techniques on-line with chromatographic separations, (5) compare quantitative speciation information obtained from LC-FTIR with established fluorine tagging techniques regarding model compounds and synfuels. 23 figures, 5 tables.

  8. Quarterly coal report, April 1996--June 1996

    SciTech Connect (OSTI)

    NONE

    1996-11-01T23:59:59.000Z

    This report provides information about U.S. coal production, distribution; exports, imports, prices, consumption, and stocks. Data on coke production is also provided. This report presents data for April 1996 thru June 1996.

  9. Quarterly coal report, October--December 1997

    SciTech Connect (OSTI)

    NONE

    1998-05-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities. This report presents detailed quarterly data for october through December 1997 and aggregated quarterly historical data for 1991 through the third quarter of 1997. Appendix A displays, from 1991 on, detailed quarterly historical coal imports data, as specified in Section 202 of the energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons. To provide a complete picture of coal supply and demand in the US, historical information has been integrated in this report. 8 figs., 73 tabs.

  10. Arrowhead Center: Coal Production and Regional Economic Growth Report Title: Coal Production and Regional Economic Growth

    E-Print Network [OSTI]

    Johnson, Eric E.

    Arrowhead Center: Coal Production and Regional Economic Growth Report Title: Coal Production@nmsu.edu #12;Arrowhead Center: Coal Production and Regional Economic Growth i Disclaimer This report States Government or any agency thereof. #12;Arrowhead Center: Coal Production and Regional Economic

  11. ENCOAL mild coal gasification project. Annual report

    SciTech Connect (OSTI)

    Not Available

    1993-10-01T23:59:59.000Z

    This document is the combination of the fourth quarter report (July--September 1993) and the 1993 annual report for the ENCOAL project. The following pages include the background and process description for the project, brief summaries of the accomplishments for the first three quarters, and a detailed fourth quarter report. Its purpose is to convey the accomplishments and current progress of the project. ENCOAL Corporation, has completed the construction of a mild gasification demonstration plant at Triton Coal Company`s Buckskin Mine near Gillette, Wyoming. The process, using Liquids From Coal (LFC) technology developed by SMC and SGI International, utilizes low-sulfur Powder River Basin coal to produce two new fuels, Process Derived Fuel (PDF) and Coal Derived Liquids (CDL). ENCOAL submitted an application to the US Department of Energy (DOE) in August 1989, soliciting joint funding of the project in the third round of the Clean Coal Technology Program. The project was selected by DOE in December, 1989 and the Cooperative Agreement approved in September, 1990. Construction, commissioning, and start-up of the ENCOAL mild coal gasification facility was completed in June of 1992, and the project is currently in the operations phase. Some plant modifications have been required and are discussed in this report.

  12. Quarterly coal report, July--September 1993

    SciTech Connect (OSTI)

    Not Available

    1994-02-18T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended.

  13. Quarterly coal report, January--March 1995

    SciTech Connect (OSTI)

    NONE

    1995-08-24T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for January through March 1995 and aggregated quarterly historical data for 1987 through the fourth quarter of 1994. Appendix A displays, from 1987 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  14. Quarterly coal report, October--December 1994

    SciTech Connect (OSTI)

    NONE

    1995-05-23T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for October through December 1994 and aggregated quarterly historical data for 1986 through the third quarter of 1994. Appendix A displays, from 1986 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  15. Quarterly coal report, January--March 1997

    SciTech Connect (OSTI)

    NONE

    1997-08-01T23:59:59.000Z

    This Quarterly Coal Report (QCR) provides comprehensive information about U.S. coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience,including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for January through March 1997 and aggregated quarterly historical data for 1991 through the fourth quarter of 1996. Appendix A displays, from 1988 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  16. Quarterly coal report, January--March 1994

    SciTech Connect (OSTI)

    Not Available

    1994-08-24T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for January through March 1994 and aggregated quarterly historical data for 1986 through the fourth quarter of 1993. Appendix A displays, from 1986 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  17. Coal transformation chemistry third quarterly progress report

    SciTech Connect (OSTI)

    Stock, Leon M.; Blain, D. A.; Handy, C. I.; Huang, C. B.; King, H. H.; Landschulz, W.; Willis, R. S.

    1980-01-01T23:59:59.000Z

    A Colorado subbituminous coal was reacted with potassium and naphthalene in tetrahydrofuran. This was then alkylated with n-butyl iodide and the solubility in tetrahydrofuran was determined. The solubility was found to be less than in a corresponding reaction with Illinois No. 6 coal. The solubilization of a Colorado subbituminous coal by reacting it with potassium in liquid ammonia, followed by alkylation is discussed. The preliminary results from a reaction of Illinois No. 6 coal with tetrabutylammonium hydroxide and methyl iodide are reported. Reductive acylation of coal is being studied at the present time using trifluoroacetic anhydride as a quenching reagent. /sup 19/F is a candidate for nmr studies and chemical shifts for trifluoroacetyl derivatives of phenols, thiols, and amides indicate that fluorine may be useful as a sensitive probe for reactive species in coal. The effort on donor solvent coal chemistry was directed to the role played by pericyclic reactions in the liquefaction process. The acceptors were reduced by the deuterated donors. The isotopic distribution of the reduction product indicates that free radical processes occur preferentially. Thus, the pericyclic reactions appear to be unimportant at the threshold reaction temperatures of 350 to 425/sup 0/C. The reactions of aromatic ethers with inorganic sulfide at 400/sup 0/C produces thiophenols.

  18. Testing Kentucky Coal to Set Design Criteria for a Lurgi Gasification Plant 

    E-Print Network [OSTI]

    Roeger, A., III; Jones, J. E., Jr.

    1983-01-01T23:59:59.000Z

    Tri-State Synfuels Company, in cooperation with the Commonwealth of Kentucky, undertook a comprehensive coal testing program to support the development of an indirect coal liquefaction project. One of the major elements of the program was a...

  19. "Annual Coal Report

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001)gasoline prices4 Oil demand8) June 2010 StateAnnual Coal

  20. Coal Combustion Science quarterly progress report, April--June 1990

    SciTech Connect (OSTI)

    Hardesty, D.R. (ed.); Baxter, L.L.; Fletcher, T.H.; Mitchell, R.E.

    1990-11-01T23:59:59.000Z

    This document provides a quarterly status report of the Coal Combustion Science Program that is being conducted at the Combustion, Research Facility, Sandia National Laboratories, Livermore, California. Coal devolatilization, coal char combustion, and fate of mineral matter during coal combustion. 56 refs., 25 figs., 13 tabs.

  1. Quarterly coal report, April 1995--June 1995

    SciTech Connect (OSTI)

    NONE

    1995-11-01T23:59:59.000Z

    This document provides comprehensive information about U.S. coal production, distribution, imports, exports, prices, and consumption. Coke production, consumption, distribution, imports, and exports are also provided. This report presents compiled data for April thru June, and historical data for 1987 thru the first quarter of 1995.

  2. Coal based electric generation comparative technologies report

    SciTech Connect (OSTI)

    Not Available

    1989-10-26T23:59:59.000Z

    Ohio Clean Fuels, Inc., (OCF) has licensed technology that involves Co-Processing (Co-Pro) poor grade (high sulfur) coal and residual oil feedstocks to produce clean liquid fuels on a commercial scale. Stone Webster is requested to perform a comparative technologies report for grassroot plants utilizing coal as a base fuel. In the case of Co-Processing technology the plant considered is the nth plant in a series of applications. This report presents the results of an economic comparison of this technology with other power generation technologies that use coal. Technologies evaluated were:Co-Processing integrated with simple cycle combustion turbine generators, (CSC); Co-Processing integrated with combined cycle combustion turbine generators, (CCC); pulverized coal-fired boiler with flue gas desulfurization and steam turbine generator, (PC) and Circulating fluidized bed boiler and steam turbine generator, (CFB). Conceptual designs were developed. Designs were based on approximately equivalent net electrical output for each technology. A base case of 310 MWe net for each technology was established. Sensitivity analyses at other net electrical output sizes varying from 220 MWe's to 1770 MWe's were also performed. 4 figs., 9 tabs.

  3. Enhancement of surface properties for coal beneficiation. Final report

    SciTech Connect (OSTI)

    Chander, S.; Aplan, F.F.

    1992-01-30T23:59:59.000Z

    This report will focus on means of pyrite removal from coal using surface-based coal cleaning technologies. The major subjects being addressed in this study are the natural and modulated surface properties of coal and pyrite and how they may best be utilized to facilitate their separation using advanced surface-based coal cleaning technology. Emphasis is based on modified flotation and oil agglomerative processes and the basic principles involved. The four areas being addressed are: (1) Collectorless flotation of pyrite; (2) Modulation of pyrite and coal hydrophobicity; (3) Emulsion processes and principles; (4) Evaluation of coal hydrophobicity.

  4. Feasibility study report for the Imperial Valley Ethanol Refinery: a 14. 9-million-gallon-per-year ethanol synfuel refinery utilizing geothermal energy

    SciTech Connect (OSTI)

    Not Available

    1981-03-01T23:59:59.000Z

    The construction and operation of a 14,980,000 gallon per year fuel ethanol from grain refinery in the Imperial Valley of California is proposed. The Imperial Valley Ethanol Refinery (refinery) will use hot geothermal fluid from geothermal resources at the East Mesa area as the source of process energy. In order to evaluate the economic viability of the proposed Project, exhaustive engineering, cost analysis, and financial studies have been undertaken. This report presents the results of feasibility studies undertaken in geothermal resource, engineering, marketing financing, management, environment, and permits and approvals. The conclusion of these studies is that the Project is economically viable. US Alcohol Fuels is proceeding with its plans to construct and operate the Refinery.

  5. Elementary processes in combustion and sooting of coal-derived fuels. University coal research. Final report

    SciTech Connect (OSTI)

    McVey, J.K.

    1986-01-01T23:59:59.000Z

    In this final report, a review of the major results and accomplishments are presented. This research program examined the role of several key radical-radical, radical-molecule and ionic decomposition reactions important in the formation of soot. In light of the then predicted increased use of fossile-based synfuels, a better understanding of the combustion of aromatic-rich fuels seemed imperative as these materials are particularly prone of form soot. Objectives of this work included developing techniques for the efficient generation of gas-phase radicals and ions, probes of their reaction dynamics, and finding new procedures for stabilization of reaction intermediates in combustion. Five specific issues examined in this study are discussed and summarized in this report: (1) the reactivity of phenyl radicals, (2) chemistry of diradicals generated from laser induced decomposition of cyclic ketones, (3) reactions of butadiene radicals, (4) reactions of gas-phase methylene, and (5) selective generation and induced decomposition of phenyl-based cations. New techniques for examining the kinetics of fast, combustion-related systems were developed using free jet expansion cooling of reaction intermediates and in using ultraviolet multiphoton ionization techniques for initiation of chemical sequences.

  6. Clean coal technologies: A business report

    SciTech Connect (OSTI)

    Not Available

    1993-01-01T23:59:59.000Z

    The book contains four sections as follows: (1) Industry trends: US energy supply and demand; The clean coal industry; Opportunities in clean coal technologies; International market for clean coal technologies; and Clean Coal Technology Program, US Energy Department; (2) Environmental policy: Clean Air Act; Midwestern states' coal policy; European Community policy; and R D in the United Kingdom; (3) Clean coal technologies: Pre-combustion technologies; Combustion technologies; and Post-combustion technologies; (4) Clean coal companies. Separate abstracts have been prepared for several sections or subsections for inclusion on the data base.

  7. Data Summary Report for Hanford Site Coal Ash Characterization

    SciTech Connect (OSTI)

    Sulloway, H. M.

    2012-03-06T23:59:59.000Z

    The purpose of this report is to present data and findings from sampling and analysis of five distinct areas of coal ash within the Hanford Site River Corridor

  8. Report Title: The Economic Impact of Coal Mining in New Mexico: 2008 Update Type of Report: Technical Report

    E-Print Network [OSTI]

    Johnson, Eric E.

    Report Title: The Economic Impact of Coal Mining in New Mexico: 2008 Update Type of Report 88003-8001 At Madrid Coal Mine, New Mexico by Carl Redin 1934. * *At Madrid Coal Mine, New Mexico 1934: The economic impact of coal mining in New Mexico is examined in this report. This report is an update

  9. [Basic properties of coals and other solids]. Eighth quarterly report, [September--November 1991

    SciTech Connect (OSTI)

    Not Available

    1991-11-25T23:59:59.000Z

    This report discusses basic properties of bituminous, subbituminous, and lignite coals. Properties of coal liquids are also investigated. Heats of immersion in strong acids are found for Pittsburgh {number_sign}8, Illinois {number_sign}6, and Wyodak coals. Production of coal liquids by distillation is discussed. Heats of titration of coal liquids and coal slurries are reported. (VC)

  10. Quarterly coal report July--September 1996, February 1997

    SciTech Connect (OSTI)

    NONE

    1997-02-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. This report presents detailed quarterly data for July through September 1996 and aggregated quarterly historical data for 1990 through the second quarter of 1996. Appendix A displays, from 1988 on, detailed quarterly historical coal imports data. 8 figs., 72 tabs.

  11. Quarterly coal report, April--June 1993

    SciTech Connect (OSTI)

    Not Available

    1993-11-26T23:59:59.000Z

    In the second quarter of 1993, the United States produced 235 million short tons of coal. This brought the total for the first half of 1993 to 477 million short tons, a decrease of 4 percent (21 million short tons) from the amount produced during the first half of 1992. The decrease was due to a 26-million-short-ton decline in production east of the Mississippi River, which was partially offset by a 5-million-short-ton increase in coal production west of the Mississippi River. Compared with the first 6 months of 1992, all States east of the Mississippi River had lower coal production levels, led by West Virginia and Illinois, which produced 9 million short tons and 7 million short tons less coal, respectively. The principal reasons for the drop in coal output for the first 6 months of 1993 compared to a year earlier were: a decrease in demand for US coal in foreign markets, particularly the steam coal markets; a draw-down of electric utility coal stocks to meet the increase in demand for coal-fired electricity generation; and a lower producer/distributor stock build-up. Distribution of US coal in the first half of 1993 was 15 million short tons lower than in the first half of 1992, with 13 million short tons less distributed to overseas markets and 2 million short tons less distributed to domestic markets.

  12. Investigation of coal structure. Final report

    SciTech Connect (OSTI)

    Nishioka, Masaharu

    1994-03-01T23:59:59.000Z

    A better understanding of coal structure is the first step toward more effective utilization of the most abundant hydrocarbon resource. Detailed characterization of coal structure is very difficult, even with today`s highly developed analytical techniques. This is primarily due to the amorphous nature of these high-molecular-weight mixtures. Coal has a polymeric character and has been popularly represented as a three-dimensional cross-linked network. There is, however, little or no information which positively verifies this model. The principal objective of this research was to further investigate the physical structure of coal and to determine the extent to which coal molecules may be covalently cross-linked and/or physically associated. Two common characterization methods, swellability and extractability, were used. A technique modifying the conventional swelling procedure was established to better determine network or associated model conformation. A new method for evaluating coal swelling involving laser scattering has also been developed. The charge-transfer interaction is relatively strong in high-volatile bituminous coal. Soaking in the presence of electron donors and acceptors proved effective for solubilizing the coal, but temperatures in excess of 200 C were required. More than 70 wt% of the coal was readily extracted with pyridine after soaking. Associative/dissociative equilibria of coal molecules were observed during soaking. From these results, the associated model has gained credibility over the network model as the representative structure of coal. Significant portions of coal molecules are unquestionably physically associated, but the overall extent is not known at this time.

  13. Quarterly coal report, January--March 1993

    SciTech Connect (OSTI)

    Not Available

    1993-08-20T23:59:59.000Z

    The United States produced 242 million short tons of coal in the first quarter of 1993, a decrease of 6 percent (14 million short tons) from the amount produced during the first quarter of 1992. The decrease was due to a decline in production east of the Mississippi River. All major coal-producing States in this region had lower coal production levels led by West Virginia, which produced 5 million short tons less coal. The principal reasons for the overall drop in coal output compared to a year earlier were: A decrease in demand for US coal in foreign markets; a slower rate of producer/distributor stock build-up; and a drawn-down of electric utility coal stocks. Distribution of US coal in the first quarter of 1993 was 10 million short tons lower than in the first quarter of 1992, with 5 million short tons less distributed to both electric utilities and overseas markets. The average price of coal delivered to electric utilities during the first quarter of 1993 was $28.65 per short ton, the lowest value since the first quarter of 1980. Coal consumption in the first quarter of 1993 was 230 million short tons, 4 percent higher than in the first quarter of 1992, due primarily to a 5-percent increase in consumption at electric utility plants. Total consumer stocks, at 153 million short tons, and electric utility stocks, at 144 million short tons, were at their lowest quarterly level since the end of 1989. US. coal exports totaled 19 million short tons, 6 million short tons less than in the first quarter of 1992, and the lowest quarterly level since 1988. The decline was primarily due to a 1-million-short-ton drop in exports to each of the following destinations: Italy, France, Belgium and Luxembourg, and Canada.

  14. Economic assessment of coal-burning locomotives: Topical report

    SciTech Connect (OSTI)

    Not Available

    1986-02-01T23:59:59.000Z

    The General Electric Company embarked upon a study to evaluate various alternatives for the design and manufacture a coal fired locomotive considering various prime movers, but retaining the electric drive transmission. The initial study was supported by the Burlington-Northern and Norfolk-Southern railroads, and included the following alternatives: coal fired diesel locomotive; direct fired gas turbine locomotives; direct fired gas turbine locomotive with steam injection; raw coal gasifier gas turbine locomotive; and raw coal fluid bed steam turbine locomotive. All alternatives use the electric drive transmission and were selected for final evaluation. The first three would use a coal water slurry as a fuel, which must be produced by new processing plants. Therefore, use of a slurry would require a significant plant capital investment. The last two would use classified run-of-the-mine (ROM) coal with much less capital expenditure. Coal fueling stations would be required but are significantly lower in capital cost than a coal slurry plant. For any coal fired locomotive to be commercially viable, it must pass the following criteria: be technically feasible and environmentally acceptable; meet railroads' financial expectations; and offer an attractive return to the locomotive manufacturer. These three criteria are reviewed in the report.

  15. Comprehensive Report to Congress Clean Coal Technology Program: Clean power from integrated coal/ore reduction

    SciTech Connect (OSTI)

    NONE

    1996-10-01T23:59:59.000Z

    This report describes a clean coal program in which an iron making technology is paired with combined cycle power generation to produce 3300 tons per day of hot metal and 195 MWe of electricity. The COREX technology consists of a metal-pyrolyzer connected to a reduction shaft, in which the reducing gas comes directly from coal pyrolysis. The offgas is utilized to fuel a combined cycle power plant.

  16. Experimental results Airotech fuels and Brookville coal - CRADA 92-003. Final report

    SciTech Connect (OSTI)

    Pennline, H.W.; Freeman, M. [Dept. of Energy Pittsburgh Energy Technology Center, PA (United States)]|[Airotech, Inc., Homestead, PA (United States)

    1992-07-21T23:59:59.000Z

    This report presents combustion screening tests and emissions procedures for Brookville coal in a residential stoker.

  17. Healy Clean Coal Project: Healy coal firing at TRW Cleveland Test Facility. Final report

    SciTech Connect (OSTI)

    Koyama, T.; Petrill, E.; Sheppard, D.

    1991-08-01T23:59:59.000Z

    A test burn of two Alaskan coals was conducted at TRW`s Cleveland test facility in support of the Healy Clean Coal Project, as part of Clean Coal Technology III Program in which a new power plant will be constructed using a TRW Coal Combustion System. This system features ash slagging technology combined with NO{sub x} and SO{sub x} control. The tests, funded by the Alaska Industrial Development and Export Authority (AIDEA) and TRW, were conducted to verify that the candidate Healy station coals could be successfully fired in the TRW coal combustor, to provide data required for scale-up to the utility project size requirements, and to produce sufficient flash-calcined material (FCM) for spray dryer tests to be conducted by Joy/NIRO. The tests demonstrated that both coals are viable candidates for the project, provided the data required for scale-up, and produced the FCM material. This report describes the modifications to the test facility which were required for the test burn, the tests run, and the results of the tests.

  18. Report Title: The Economic Impact of Coal Mining in New Mexico Type of Report: Final Technical Report

    E-Print Network [OSTI]

    Johnson, Eric E.

    Report Title: The Economic Impact of Coal Mining in New Mexico Type of Report: Final Technical The economic impact of coal mining in New Mexico is examined in this report. The analysis is based on economic impacts of coal mining in New Mexico are presented in terms of output, value added, employment, and labor

  19. Quarterly coal report July--September 1995, February 1996

    SciTech Connect (OSTI)

    NONE

    1996-02-16T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about US coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for July through September 1995 and aggregated quarterly historical data for 1987 through the second quarter of 1995. Appendix A displays, from 1987 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  20. Annual Coal Distribution Report - Energy Information Administration

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecade Year-0 Year-1 Year-2Cubiccurrent Coal

  1. Assessment of underground coal gasification in bituminous coals. Volume I. Executive summary. Final report

    SciTech Connect (OSTI)

    None

    1981-01-01T23:59:59.000Z

    This report describes the bituminous coal resources of the United States, identifies those resources which are potentially amenable to Underground Coal Gasification (UCG), identifies products and markets in the vicinity of selected target areas, identifies UCG concepts, describes the state of the art of UCG in bituminous coal, and presents three R and D programs for development of the technology to the point of commercial viability. Of the 670 billion tons of bituminous coal remaining in-place as identified by the National Coal Data System, 32.2 billion tons or 4.8% of the total are potentially amenable to UCG technology. The identified amenable resource was located in ten states: Alabama, Colorado, Illinois, Kentucky, New Mexico, Ohio, Oklahoma, Utah, Virginia, and West Virginia. The principal criteria which eliminated 87.3% of the resource was the minimum thickness (42 inches). Three R and D programs were developed using three different concepts at two different sites. Open Borehole, Hydraulic Fracture, and Electrolinking concepts were developed. The total program costs for each concept were not significantly different. The study concludes that much of the historical information based on UCG in bituminous coals is not usable due to the poor siting of the early field tests and a lack of adequate diagnostic equipment. This information gap requires that much of the early work be redone in view of the much improved understanding of the role of geology and hydrology in the process and the recent development of analytical tools and methods.

  2. Underground coal gasification simulation. Final report

    SciTech Connect (OSTI)

    Gunn, R.D.

    1984-07-01T23:59:59.000Z

    The underground coal gasification (UCG) process - both forward gasification and reverse combustion linkage - was mathematically modeled. The models were validated with field and laboratory data. They were then used to explain some important UCG phenomena that had not been predictable with other methods. Some views on the UCG technology status are also presented. 3 references, 25 figures, 10 tables.

  3. Coal surface structure and thermodynamics. Final report

    SciTech Connect (OSTI)

    Larsen, J.W.; Wernett, P.C.; Glass, A.S.; Quay, D.; Roberts, J.

    1994-05-01T23:59:59.000Z

    Coals surfaces were studied using static surface adsorption measurements, low angle x-ray scattering (LAXS), inverse gas chromatography (IGC) and a new {sup 13}C NMR relaxation technique. A comparison of surface areas determined by hydrocarbon gas adsorption and LAXS led to the twin conclusions that the hydrocarbons had to diffuse through the solid to reach isolated pores and that the coal pores do not form interconnected networks, but are largely isolated. This conclusion was confirmed when IGC data for small hydrocarbons showed no discontinuities in their size dependence as usually observed with porous solids. IGC is capable of providing adsorption thermodynamics of gases on coal surfaces. The interactions of non-polar molecules and coal surfaces are directly proportioned to the gas molecular polarizability. For bases, the adsorption enthalpy is equal to the polarizability interaction plus the heat of hydrogen bond formation with phenol. Amphoteric molecules have more complex interactions. Mineral matter can have highly specific effects on surface interactions, but with most of the molecules studied is not an important factor.

  4. The Technical and Economic Feasibility of Siting Synfuels Plants in Wyoming

    SciTech Connect (OSTI)

    Anastasia M Gandrik; Rick A Wood; David Bell; William Schaffers; Thomas Foulke; Richard D Boardman

    2011-09-01T23:59:59.000Z

    A comprehensive study has been completed to determine the feasibility of constructing and operating gasification and reforming plants which convert Wyoming fossil resources (coal and natural gas) into the higher value products of power, transportation fuels, and chemical feedstocks, such as ammonia and methanol. Detailed plant designs, simulation models, economic models and well-to-wheel greenhouse gas models were developed, validated by national-level engineering firms, which were used to address the following issues that heretofore have prevented these types of projects from going forward in Wyoming, as much as elsewhere in the United States: 1. Quantification of plant capital and operating expenditures 2. Optimization of plant heat integration 3. Quantification of coal, natural gas, electricity, and water requirements 4. Access to raw materials and markets 5. Requirements for new infrastructure, such as electrical power lines and product pipelines 6. The possible cost-benefit tradeoffs of using natural gas reforming versus coal gasification 7. The extent of labor resources required for plant construction and for permanent operations 8. Options for managing associated CO2 emissions, including capture and uses in enhanced oil recovery and sequestration 9. Options for reducing water requirements such as recovery of the high moisture content in Wyoming coal and use of air coolers rather than cooling towers 10. Permitting requirements 11. Construction, and economic impacts on the local communities This paper will summarize the analysis completed for two major synfuels production pathways, methanol to gasoline and Fischer-Trosph diesel production, using either coal or natural gas as a feedstock.

  5. ENERGY & ENVIRONMENT DIVISION ANNUAL REPORT 1979

    E-Print Network [OSTI]

    Cairns, E.J.

    2010-01-01T23:59:59.000Z

    the conversion of coal, oil shale and biomass to synfuels,"waters are co produced with shale oil and separated from itmaterial in the Occidental shale oil. Oil samples of various

  6. Petrographic characterization of Kentucky coals. Annual report

    SciTech Connect (OSTI)

    Hower, J.C.; Ferm, J.C.; Cobb, J.C.; Trinkle, E.J.; Frankie, K.A.; Poe, S.H.

    1981-09-29T23:59:59.000Z

    The study of the petrography of Kentucky coals sponsored by the US Department of Energy currently involves three projects as described below: semi-inert macerals, spectral fluorescence of liptinites, and pyrite size/form/microlithotype distribution. Progress to date has varied due to requirements for training personnel and due to equipment problems. With the two-year continuation of the grant further study will apply results from the above projects to stratigraphic problems.

  7. Testing Kentucky Coal to Set Design Criteria for a Lurgi Gasification Plant

    E-Print Network [OSTI]

    Roeger, A., III; Jones, J. E., Jr.

    1983-01-01T23:59:59.000Z

    's subcontractors, the Commonwealth of Kentucky or any agency thereof, or the United States Government or any agency thereof. INTRODUCTION Tri-State Synfuels Project Tri-State Synfuels Company, a partnershi of Texas Eastern Corporation and Texas Gas Transmis...Eion Corporat ion affiliates, proposes to produce li~Uid transportation fuels and substitute natural gas rom coal using the indirect liquefaction appr ach (Reference 1). The proj ect is sited in Hende son County, Kentucky and will, if built, use COIer...

  8. Quarterly Coal Distribution Report - Energy Information Administration

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) - HouseholdshortEIA-782A andS F J9Quarterly Coal

  9. Utilization of coal-associated minerals. Final report

    SciTech Connect (OSTI)

    Slonaker, J. F.; Akers, D. J.; Alderman, J. K.

    1980-01-01T23:59:59.000Z

    Under contract number DE-AS21-77ET10533 with the US-DOE several methods of utilizing coal associated by-products were examined for potential commercial use. Such use could transform a costly waste disposal situation into new materials for further use and could provide incentive for the adoption of new coal utilization processes. Several utilization processes appear to have merit and are recommended for further study. Each process is discussed separately in the text of this report. Common coal cleaning processes were also examined to determine the effect of such processes on the composition of by-products. Data obtained in this portion of the research effort are reported in the Appendix. Information of this type is required before utilization processes can be considered. A knowledge of the mineral composition of these materials is also required before even simple disposal methods can be considered.

  10. Coal diesel combined-cycle project. Comprehensive report to Congress: Clean Coal Technology Program

    SciTech Connect (OSTI)

    Not Available

    1994-05-01T23:59:59.000Z

    One of the projects selected for funding is a project for the design, construction, and operation of a nominal 90 ton-per-day 14-megawatt electrical (MWe), diesel engine-based, combined-cycle demonstration plant using coal-water fuels (CWF). The project, named the Coal Diesel Combined-Cycle Project, is to be located at a power generation facility at Easton Utilities Commission`s Plant No. 2 in Easton, Talbot County, Maryland, and will use Cooper-Bessemer diesel engine technology. The integrated system performance to be demonstrated will involve all of the subsystems, including coal-cleaning and slurrying systems; a selective catalytic reduction (SCR) unit, a dry flue gas scrubber, and a baghouse; two modified diesel engines; a heat recovery steam generation system; a steam cycle; and the required balance of plant systems. The base feedstock for the project is bituminous coal from Ohio. The purpose of this Comprehensive Report is to comply with Public Law 102-154, which directs the DOE to prepare a full and comprehensive report to Congress on each project selected for award under the CCT-V Program.

  11. Coal demonstration plants. Quarterly report, January-March 1979. [US DOE-supported

    SciTech Connect (OSTI)

    None

    1980-01-01T23:59:59.000Z

    Progress in US DOE-supported demonstration plants for the gasification and liquefaction of coal is reported: company, contract number, process description and flowsheet, history and progress in the current quarter. Related projects involve coal feeders, lock hoppers, values, etc. for feeding coal into high pressure systems, coal grinding equipment and measuring and process control instrumentation. (LTN)

  12. Low-rank coal research. Quarterly report, January--March 1990

    SciTech Connect (OSTI)

    Not Available

    1990-08-01T23:59:59.000Z

    This document contains several quarterly progress reports for low-rank coal research that was performed from January-March 1990. Reports in Control Technology and Coal Preparation Research are in Flue Gas Cleanup, Waste Management, and Regional Energy Policy Program for the Northern Great Plains. Reports in Advanced Research and Technology Development are presented in Turbine Combustion Phenomena, Combustion Inorganic Transformation (two sections), Liquefaction Reactivity of Low-Rank Coals, Gasification Ash and Slag Characterization, and Coal Science. Reports in Combustion Research cover Fluidized-Bed Combustion, Beneficiation of Low-Rank Coals, Combustion Characterization of Low-Rank Coal Fuels, Diesel Utilization of Low-Rank Coals, and Produce and Characterize HWD (hot-water drying) Fuels for Heat Engine Applications. Liquefaction Research is reported in Low-Rank Coal Direct Liquefaction. Gasification Research progress is discussed for Production of Hydrogen and By-Products from Coal and for Chemistry of Sulfur Removal in Mild Gas.

  13. Energy Policy Act transportation rate study: Interim report on coal transportation

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    The primary purpose of this report is to examine changes in domestic coal distribution and railroad coal transportation rates since enactment of the Clean Air Act Amendments of 1990 (CAAA90). From 1988 through 1993, the demand for low-sulfur coal increased, as a the 1995 deadline for compliance with Phase 1 of CAAA90 approached. The shift toward low-sulfur coal came sooner than had been generally expected because many electric utilities switched early from high-sulfur coal to ``compliance`` (very low-sulfur) coal. They did so to accumulate emissions allowances that could be used to meet the stricter Phase 2 requirements. Thus, the demand for compliance coal increased the most. The report describes coal distribution and sulfur content, railroad coal transportation and transportation rates, and electric utility contract coal transportation trends from 1979 to 1993 including national trends, regional comparisons, distribution patterns and regional profiles. 14 figs., 76 tabs.

  14. Cooperative research program in coal liquefaction. Quarterly report, May 1, 1993--October 31, 1993

    SciTech Connect (OSTI)

    Hoffman, G.P. [ed.

    1994-07-01T23:59:59.000Z

    This report summarizes progress in four areas of research under the general heading of Coal Liquefaction. Results of studies concerning the coliquefaction of coal with waste organic polymers or chemical products of these polymers were reported. Secondly, studies of catalytic systems for the production of clean transportation fuels from coal were discussed. Thirdly, investigations of the chemical composition of coals and their dehydrogenated counterparts were presented. These studies were directed toward elucidation of coal liquefaction processes on the chemical level. Finally, analytical methodologies developed for in situ monitoring of coal liquefaction were reported. Techniques utilizing model reactions and methods based on XAFS, ESR, and GC/MS are discussed.

  15. Coal operators prepare for a prosperous new year

    SciTech Connect (OSTI)

    Fiscor, S.

    2008-01-15T23:59:59.000Z

    Results are given of the Coal Age 2008 annual Forecast Survey of 17 coal mining executives which reinforces that 2008 could be a very good year. Coal operators are planning to invest in new equipment, development and new coal mine start-ups, based on a number of demand- and supply-side fundamentals. 71% of those surveyed thought coal production in 2008 would increase from 2007 levels and US exports are expected to climb due to the weak dollar. If the tax credit on synfuels expires on 31 December 2007 production of coal synfuel will likely cease. Asked about expensive planned purchases, companies answers ranged from $80,000 for an underground scoop to $500 m for a new mine installation. However, most producers admit they will not be able to operate at full capacity. 7 figs.

  16. Impacts of the extended-weight coal haul road system (interim report). Research report

    SciTech Connect (OSTI)

    Crabtree, J.D.; Pigman, J.G.; Deacon, J.A.; Agent, K.R.

    1993-10-01T23:59:59.000Z

    The Extended-Weight Coal Haul Road System, created by Kentucky`s Legislature in 1986, consists of all roads which carry over 50,000 tons of coal in a calendar year. Trucks hauling coal on this system are authorized to exceed normal weight limits through the payment of an annual decal fee. A research study was initiated in July of 1992 to analyze the impacts of the extended-weight system. This interim report prepared after one year of a three-year study, describes the analyses performed thus far and presents preliminary findings, recommendations, and a discussion of future work. Analyses in this report are based on: historical data on coal production and transportation; data from coal decal applications; interviews of legislators, transportation officials, coal company representatives, and coal trucking representatives: newspaper articles; vehicle classification data; a pavement cost analysis; and accident data. Preliminary conclusions include: (1) The extended-weight system has apparently been somewhat successful in accomplishing the primary objectives: to enhance the competitiveness and economic viability of Kentucky`s coal industry and to eliminate the perceived need for cal haulers to violate the law in order to be competitive; (2) Overall accident rates are no higher on the extended-weight system than on other comparable routes, but the fatal accident rate is significantly higher on the extended-weight system; (3) The coal-decal fee structure results in a net annual loss in Road Fund revenue of approximately $2 million; (4) Forty percent of the revenue from decal sales is allocated to the counties, although less than ten percent of the extended-weight system in county-maintained; (5) The heavier weights of coal-decal trucks add approximately $9 million annually to pavement overlay costs and increase other highway costs. (6) Road users throughout the state are subsidizing the movement of Kentucky coal by underwriting the increased costs.

  17. Pacific Northwest Laboratory annual report for 1983 to the DOE Office of Energy Research. Part 1. Biomedical sciences

    SciTech Connect (OSTI)

    Drucker, H.

    1983-02-01T23:59:59.000Z

    Biomedical and health effects research conducted at PNL in 1982 on the evaluation of risk to man from existing and/or developing energy-related technologies are described. Most of the studies described in this report relate to activities for three major energy technologies: nuclear fuel cycle; fossil fuel cycle (oil, gas, and coal process technologies, mining, and utilization; synfuel development), and fudion (biomagnetic effects). The report is organized under these technologies. In addition, research reports are included on the application of nuclear energy to biomedical problems. Individual projects are indexed separately.

  18. ENCOAL mild coal gasification project public design and construction report

    SciTech Connect (OSTI)

    NONE

    1994-12-01T23:59:59.000Z

    This Public Design Report describes the 1000 ton per day ENCOAL mild coal gasification demonstration plant now in operation at the Buckskin Mine near Gillette, Wyoming. The objective of the project is to demonstrate that the proprietary Liquids From Coal (LFC) technology can reliably and economically convert low Btu PRB coal into a superior, high-Btu solid fuel (PDF), and an environmentally attractive low-sulfur liquid fuel (CDL). The Project`s plans also call for the production of sufficient quantities of PDF and CDL to permit utility companies to carry out full scale burn tests. While some process as well as mechanical design was done in 1988, the continuous design effort was started in July 1990. Civil construction was started in October 1990; mechanical erection began in May 1991. Virtually all of the planned design work was completed by July 1991. Most major construction was complete by April 1992 followed by plant testing and commissioning. Plant operation began in late May 1992. This report covers both the detailed design and initial construction aspects of the Project.

  19. COAL LIQUEFACTION ALLOY TEST PROGRAM ANNUAL REPORT FY 1978

    E-Print Network [OSTI]

    Levy, A.

    2014-01-01T23:59:59.000Z

    vs. Tempeature of Coal Slurries in Creosote OiL III z u wdilatant behavior of the coal slurries (Figures 2 and 3) atIt can be seen that the coal slurry produced a minor. but

  20. Hydrothermally treated coals for pulverized coal injection. Technical progress report, April 1995--June 1995

    SciTech Connect (OSTI)

    Walsh, D.E.; Rao, P.D.; Ogunsola, O.; Lin, H.K.

    1995-07-01T23:59:59.000Z

    This project is investigating the suitability of hydrothermally dried low-rank coals for pulverized fuel injection into blast furnaces in order to reduce coke consumption. Coal samples from the Beluga coal field and Usibelli Coal Mine, Alaska, are being used for the study. Crushed coal samples were hydrothermally treated at three temperatures, 275, 300 and 325{degrees}C, for residence times ranging from 10 to 120 minutes. Products have been characterized to determine their suitability for pulverized coal injection. Characterization includes proximate and ultimate analyses, vitrinite reflectance, TGA reactivity and thermochemical modeling. A literature survey has been conducted.

  1. Evaluation of technology modifications required to apply clean coal technologies in Russian utilities. Final report

    SciTech Connect (OSTI)

    NONE

    1995-12-01T23:59:59.000Z

    The report describes the following: overview of the Russian power industry; electric power equipment of Russia; power industry development forecast for Russia; clean coal technology demonstration program of the US Department of Energy; reduction of coal TPS (thermal power station) environmental impacts in Russia; and base options of advanced coal thermal power plants. Terms of the application of clean coal technology at Russian TPS are discussed in the Conclusions.

  2. Assessment of underground coal gasification in bituminous coals: catalog of bituminous coals and site selection. Appendix A. National coal resource data system: Ecoal, Wcoal, and Bmalyt. Final report, Phase I. [Bituminous coal; by state; coal seam depth and thickness; identification

    SciTech Connect (OSTI)

    None

    1982-01-31T23:59:59.000Z

    Appendix A is a catalog of the bituminous coal in 29 states of the contiguous United States which contain identified bituminous coal resources.

  3. Formation and retention of methane in coal. Final report

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15T23:59:59.000Z

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  4. Evaluation of coal minerals and metal residues as coal-liquefaction catalysts. Final report

    SciTech Connect (OSTI)

    Garg, D.; Givens, E. N.; Schweighardt, F. K.; Tarrer, A. R.; Guin, J. A.; Curtis, C. W.; Huang, W. J.; Shridharani, K.; Clinton, J. H.

    1982-02-01T23:59:59.000Z

    The catalytic activity of various minerals, metallic wastes, and transition metals was investigated in the liquefaction of various coals. The effects of coal type, process variables, coal cleaning, catalyst addition mode, solvent quality, and solvent modification on coal conversion and oil production were also studied. Coal conversion and oil production improved significantly by the addition of pyrite, reduced pyrite, speculite, red mud, flue dust, zinc sulfide, and various transition metal compounds. Impregnation and molecular dispersion of iron gave higher oil production than particulate incorporation of iron. However, the mode of molybdenum addition was inconsequential. Oil production increased considerably both by adding a stoichiometric mixture of iron oxide and pyrite and by simultaneous impregnation of coal with iron and molybdenum. Hydrogenation activity of disposable catalysts decreased sharply in the presence of nitrogen compounds. The removal of heteroatoms from process solvent improved thermal as well as catalytic coal liquefaction. The improvement in oil production was very dramatic with a catalyst.

  5. X-ray Computed Tomography of coal: Final report

    SciTech Connect (OSTI)

    Maylotte, D.H.; Spiro, C.L.; Kosky, P.G.; Lamby, E.J.

    1986-12-01T23:59:59.000Z

    X-ray Computed Tomography (CT) is a method of mapping with x-rays the internal structures of coal. The technique normally produces 2-D images of the internal structures of an object. These images can be recast to create pseudo 3-D representations. CT of coal has been explored for a variety of different applications to coal and coal processing technology. In a comparison of CT data with conventional coal analyses and petrography, CT was found to offer a good indication of the total ash content of the coal. The spatial distribution of the coal mineral matter as seen with CT has been suggested as an indicator of coal washability. Studies of gas flow through coal using xenon gas as a tracer have shown the extremely complicated nature of the modes of penetration of gas through coal, with significant differences in the rates at which the gas can pass along and across the bedding planes of coal. In a special furnace designed to allow CT images to be taken while the coal was being heated, the pyrolysis and gasification of coal have been studied. Gasification rates with steam and CO/sub 2/ for a range of coal ranks have been obtained, and the location of the gasification reactions within the piece of coal can be seen. Coal drying and the progress of the pyrolysis wave into coal have been examined when the coal was subjected to the kind of sudden temperature jump that it might experience in fixed bed gasifier applications. CT has also been used to examine stable flow structures within model fluidized beds and the accessibility of lump coal to microbial desulfurization. 53 refs., 242 figs., 26 tabs.

  6. Low severity coal liquefaction promoted by cyclic olefins. Quarterly report, October 1991--December 1991

    SciTech Connect (OSTI)

    Curtis, C.W.

    1991-12-31T23:59:59.000Z

    The objective of this project is to evaluate the efficacy of low severity coal liquefaction in the presence of highly reactive hydrogen donors, cyclic olefins. The work that was performed this quarter involved performing a literature search in which different aspects of low severity coal liquefaction were examined. In addition, two new mater`s graduate students learned the fundamental differences between high severity coal liquefaction and low severity coal liquefaction by examining the literature and reading texts on coal liquefaction. The literature review presented for the first quarter`s work is a compilation of the material which we have found to data involving low severity coal liquefaction. Additional review of low severity liquefaction literature is being conducted this quarter and will be reported in the next quarterly report. In addition, a summary of the work involving the reactivity of cyclic olefins in the absence and presence of coal will be presented next quarter.

  7. Solvent refined coal (SRC) process. Annual technical progress report, January 1979-December 1979

    SciTech Connect (OSTI)

    Not Available

    1980-11-01T23:59:59.000Z

    This report discusses the effects on SRC yields of seven process variables (reactor temperature, SRT, hydrogen partial pressure, recycle ash and coal concentrations, gas velocity and coal type) predicted by second-order regression models developed from a data base containing pilot plant data with both Kentucky and Powhatan coals. The only effect of coal type in the model is a shift in each yield by a constant factor. Although some differences were found between the models developed from the Kentucky data base (1) (which we call Kentucky models) and the pooled coal models, the general conclusions of the previous report are confirmed by the new models and the assumption of similar behavior of the two coals appears to be justified. In some respects the dependence of the yields (MAF coal basis) on variables such as pressure and temperature are clearer than in the previous models. The principal trends which emerge are discussed.

  8. Cooperative research in coal liquefaction. Final report, May 1, 1990-- April 30, 1991

    SciTech Connect (OSTI)

    Huffman, G.P. [ed.

    1992-02-15T23:59:59.000Z

    The Consortium for Fossil Fuel Liquefaction Science (CFFLS) is currently engaged in a three year contract with the US Department of Energy investigating a range of research topics dealing with direct coal liquefaction. This report summarizes the results of this program in its second year, from May 1, 1990 to April 30, 1991. Accomplishments for this period are presented for the following tasks: Iron-based catalysts for coal liquefaction, exploratory research on coal conversion, novel coal liquefaction concepts, and novel catalysts for coal liquefaction.

  9. Blast Furnace Granulated Coal Injection System Demonstration Project public design report. Topical report

    SciTech Connect (OSTI)

    NONE

    1995-03-01T23:59:59.000Z

    The public design report describes the Blast Furnace Granulated Coal Injection (BFGCI) project under construction at Bethlehem Steel Corporation`s (BSC) Burns Harbor, Indiana, plant. The project is receiving cost-sharing from the U.S. Department of Energy (DOE), and is being administrated by the Morgantown Energy Technology Center in accordance with the DOE Cooperative Agreement No. DE-FC21-91MC27362. The project is the first installation in the United States for the British Steel technology using granular coal in blast furnaces. The objective is to demonstrate that granular coal is an economic and reliable fuel which can successfully be applied to large North American blast furnaces. These include: coal grind size, coal injection rate, coal source (type) and blast furnace conversion method. To achieve the program objectives, the demonstration project is divided into the following three Phases: Phase I-Design; Phase II-Procurement & Construction; and Phase III-Operation. Preliminary design (Phase I) began in 1991 with detailed design commencing in April 1993. Construction at Burns Harbor (Phase II) began August 1993. Construction is expected to be complete in the first quarter of 1995 which will be followed by a demonstration test program (Phase III).

  10. Clean coal reference plants: Atmospheric CFB. Topical report, Task 1

    SciTech Connect (OSTI)

    Rubow, L.N.; Harvey, L.E.; Buchanan, T.L.; Carpenter, R.G.; Hyre, M.R.; Zaharchuk, R.

    1992-06-01T23:59:59.000Z

    The Clean Coal Technology Demonstration Program is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of full-scale facilities. The goal of the program is to provide the US energy marketplace with a number of advanced, more efficient and environmentally responsive coal-using technologies. The Morgantown Energy Technology Center (METC) has the responsibility for monitoring the CCT Projects within certain technology categories, which correspond to the center`s areas of technology development, including atmospheric fluidized bed combustion, pressurized fluidized bed combustion, integrated gasification combined cycle, mild gasification, and industrial applications. A measure of success in the CCT program will be the commercial acceptance of the new technologies being demonstrated. The dissemination of project information to potential users is being accomplished by producing a series of reference plant designs which will provide the users a basis for the selection of technologies applicable to their future energy requirements. As a part of DOE`s monitoring and evaluation of the CCT Projects, Gilbert/Commonwealth (G/C) has been contracted to assist in this effort by producing the design of a commercial size Reference Plant, utilizing technologies developed in the CCT Program. This report, the first in a series, describes the design of a 400 MW electric power plant, utilizing an atmospheric pressure, circulating fluidized bed combustor (ACFB) similar to the one which was demonstrated at Colorado-Ute`s Nucla station, funded in Round 1 of the CCT Program. The intent of the reference plant design effort was to portray a commercial power plant with attributes considered important to the utility industry. The logical choice for the ACFB combustor was Pyropower since they supplied the ACFB for the Nucla Project.

  11. Underground Coal Thermal Treatment Task 6 Topical Report, Utah Clean Coal Program

    SciTech Connect (OSTI)

    Smith, P.J.; Deo, M.; Edding, E.G.; Hradisky, M.; Kelly, K.E.; Krumm, R.; Sarofim, Adel; Wang, D.

    2014-08-15T23:59:59.000Z

    The long-term objective of this task is to develop a transformational energy production technology by in- situ thermal treatment of a coal seam for the production of substitute natural gas and/or liquid transportation fuels while leaving much of the coal’s carbon in the ground. This process converts coal to a high-efficiency, low-greenhouse gas (GHG) emitting fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This task focused on three areas: • Experimental. The Underground Coal Thermal Treatment (UCTT) team focused on experiments at two scales, bench-top and slightly larger, to develop data to understand the feasibility of a UCTT process as well as to develop validation/uncertainty quantification (V/UQ) data for the simulation team. • Simulation. The investigators completed development of High Performance Computing (HPC) simulations of UCTT. This built on our simulation developments over the course of the task and included the application of Computational Fluid Dynamics (CFD)- based tools to perform HPC simulations of a realistically sized domain representative of an actual coal field located in Utah. • CO2 storage. In order to help determine the amount of CO2 that can be sequestered in a coal formation that has undergone UCTT, adsorption isotherms were performed on coals treated to 325, 450, and 600°C with slow heating rates. Raw material was sourced from the Sufco (Utah), Carlinville (Illinois), and North Antelope (Wyoming) mines. The study indicated that adsorptive capacity for the coals increased with treatment temperature and that coals treated to 325°C showed less or similar capacity to the untreated coals.

  12. Coal log pipeline research at University of Missouri. 1. quarterly report for 1996, January 1--March 31, 1996

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    This project consists of the following nine tasks: Machine design for coal log fabrication; Very rapid compaction of coal logs; Rapid compaction of coal logs; Fast-track experiments on coal log compaction; Coal log fabrication using hydrophobic binders; Drag reduction in large diameter hydraulic capsule pipeline; Automatic control of coal log pipeline system; Hydraulics of CLP (Coal Log Pipeline); and Coal heating system research. The purpose of the task, the work accomplished during this report period, and work proposed for the next quarter are described for each task.

  13. Coal surface control for advanced fine coal flotation. Final report, October 1, 1988--March 31, 1992

    SciTech Connect (OSTI)

    Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. [California Univ., Berkeley, CA (United States); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. [Columbia Univ., New York, NY (United States); Hu, W.; Zou, Y.; Chen, W. [Utah Univ., Salt Lake City, UT (United States); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. [Praxis Engineers, Inc., Milpitas, CA (United States)

    1992-03-01T23:59:59.000Z

    The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal`s emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

  14. Low-rank coal research semiannual report, January 1992--June 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-31T23:59:59.000Z

    This semiannual report is a compilation of seventeen reports on ongoing coal research at the University of North Dakota. The following research areas are covered: control technology and coal preparation; advanced research and technology development; combustion; liquefaction and gasification. Individual papers have been processed separately for inclusion in the Energy Science and Technology Database.

  15. Petrographic characterization of Kentucky coals. Final report. Part VI. The nature of pseudovitrinites in Kentucky coals

    SciTech Connect (OSTI)

    Trinkle, E.J.; Hower, J.C.

    1984-02-01T23:59:59.000Z

    Overall average pseudovitrinite content for 1055 eastern Kentucky coal samples is nearly 9% while average percentage of pseudovitrinite for 551 western Kentucky coals is approximately 4%. Examination of variation in pseudovitrinite content relative to rank changes shows uniformity in pseudovitrinite percentages within the 4 to 7 V-type interval for eastern Kentucky coals but a gradual increase in pseudovitrinite content for western Kentucky coals over the same rank interval. Coals from both coal fields show similar, distinct increases in pseudovitrinite percentage in the highest V-type categories. However, it is suggested here that these supposed increases in pseudovitrinite percentages are not real but rather, indicate distinct increase in the brightness of nitrinite resulting from increased alteration of vitrinite beginning at this stage of coalification and continuing into the higher rank stages. This conclusion is reached when it is found that differences between pseudovitrinite and vitrinite reflectance are least in coals at these high rank intervals of Kentucky and, also, when vitrinite particles are often visually observed having brightness equal to that of pseudovitrinite particles. Relation of pseudovitrinite to other sulfur forms and total sulfur in general shows no significant trends, although the relatively high pyritic sulfur content in western Kentucky coals, coupled with relatively low inert percentages suggest the existence of predominantly reducing, or at least non-oxidizing conditions in the Pennsylvanian peat swamps of western Kentucky. Initial work involving Vicker's microhardness testing of coals indicates that microhardness values for pseudovitrinite are higher than those for vitrinite within the same sample regardless of coal rank or coal field from which the sample was collected. 15 references, 9 figures, 9 tables.

  16. Gasifier feed - Tailor-made from Illinois coals. [Quarterly] report, March 1, 1992--May 31, 1992

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III [Illinois State Geological Survey, Champaign, IL (United States); Lytle, J.; Frost, R.R.; Lizzio, A.; Kohlenberger, L.; Brewer, K. [Illinois State Geological Survey, Champaign, IL (United States)]|[DESTEC Energy (United States)]|[Williams Technology (United States)]|[Illinois Coal Association (United States)

    1992-10-01T23:59:59.000Z

    The main purpose of this project is to produce a feedstock from preparation plant fines from an Illinois coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high sulfur content and high Btu value of Illinois coals are particularly advantageous in such a gasifier; preliminary calculations indicate that the increased cost of removing sulfur from the gas from a high sulfur coal is more than offset by the increased revenue from the sale of the elemental sulfur; additionally the high Btu Illinois coal concentrates more energy into the slurry of a given coal to water ratio. This project will bring the expertise of four organizations together to perform the various tasks. The Illinois Coal Association will help direct the project to be the most beneficial to the Illinois coal industry. DESTEC Energy, a wholly-owned subsidiary of Dow Chemical Company, will provide guidelines and test compatibility of the slurries developed for gasification feedstock. Williams Technology will provide their expertise in long distance slurry pumping, and test selected products for viscosity, pumpability, and handlability. The Illinois State Geological Survey will study methods for producing clean coal/water slurries from preparation plant wastes including the concentration of pyritic sulfur into the coal slurry to increase the revenue from elemental sulfur produced during gasification operations, and decrease the pyritic sulfur content of the waste streams. ISGS will also test the gasification reactivity of the coals. As reported earlier, a variety of possible samples of coal have been analyzed and the gasification performance evaluation reported. Additionally, commercial sized samples of -28 mesh {times} 100 mesh coal -100 {times} 0 coal were subjected to pumpability testing. Neither the coarse product nor the fine product by themselves proved to be good candidates for trouble free pumping, but the mix of the two proved to be a very acceptable product

  17. Coal industry annual 1994

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    This report presents data on coal consumption, distribution, coal stocks, quality, prices, coal production information, and emissions for a wide audience.

  18. Energy Information Administration quarterly coal report, October--December 1992

    SciTech Connect (OSTI)

    Not Available

    1993-05-21T23:59:59.000Z

    The United States produced just over 1 billion short tons of coal in 1992, 0.4 percent more than in 1991. Most of the 4-million-short-ton increase in coal production occurred west of the Mississippi River, where a record level of 408 million short tons of coal was produced. The amount of coal received by domestic consumers in 1992 totaled 887 million short tons. This was 7 million short tons more than in 1991, primarily due to increased coal demand from electric utilities. The average price of delivered coal to each sector declined by about 2 percent. Coal consumption in 1992 was 893 million short tons, only 1 percent higher than in 1991, due primarily to a 1-percent increase in consumption at electric utility plants. Consumer coal stocks at the end of 1992 were 163 million short tons, a decrease of 3 percent from the level at the end of 1991, and the lowest year-end level since 1989. US coal exports fell 6 percent from the 1991 level to 103 million short tons in 1992. Less coal was exported to markets in Europe, Asia, and South America, but coal exports to Canada increased 4 million short tons.

  19. Coal-transformation chemistry. Fourth quarterly progress report

    SciTech Connect (OSTI)

    Stock, Leon M.; Blain, D. A.; Handy, C. I.; Heimann, P.; Huang, C. B.; King, H. -H.; Landschulz, W.; Willis, R. S.

    1980-01-01T23:59:59.000Z

    Pyrene, perylene, anthracene, 9,10-diphenylanthracene, naphthalene and biphenyl have been employed as electron transfer agents in the reduction of Illinois No. 6 coal with potassium in tetrahydrofuran. These electron transfer agents are about equally effective for the reduction of this coal at short reaction times (3 hours). We conclude that the anions of biphenyl and naphthalene achieve a greater degree of electron transfer to the coal molecules and that the use of these anions enhances the fragmentation reactions of the coal. Illinois No. 6 bituminous coal and Colorado subbituminous coal were reacted with potassium dissolved in a mixture of monoglyme and triglyme at -50/sup 0/C. The reduction reaction proceeded via solvated electrons rather than by an electron transfer reaction. The coals were then alkylated with methyl iodide and their solubilities in tetrahydrofuran were determined. The Illinois coal reductively alkylated via solvated electrons was considerably less soluble in tetrahydrofuran than the same coal reductively alkylated with potassium and naphthalene in tetrahydrofuran. A sample of Illinois No. 6 coal which had been reductively butylated with n-butyl-1-/sup 13/C iodide was hydrolyzed. Carbon nmr spectroscopy of the hydrolyzed coal revealed that the resonances previously assigned either to the presence of n-butyl carboxylates or to n-butyl tertiary ethers were removed. This observation provides definite evidence that only carboxylates were present in the original alkylated product. Selective alkylation of the acidic hydroxyl groups in Illinois No. 6 coal was carried out using tetrabutylammonium hydroxide as a phase transfer catalyst and iodomethane or 1-iodobutane as alkylating agent as described by Liotta. The tetrahydrofuran solubility of the product was significantly improved in a reaction where reductively butylated coal was subsequently coal was subsequently methylated using Liotta's procedure.

  20. Wabash River coal gasification repowering project: Public design report

    SciTech Connect (OSTI)

    NONE

    1995-07-01T23:59:59.000Z

    The Wabash River Coal Gasification Repowering Project (the Project), conceived in October of 1990 and selected by the US Department of Energy as a Clean Coal IV demonstration project in September 1991, is expected to begin commercial operations in August of 1995. The Participants, Destec Energy, Inc., (Destec) of Houston, Texas and PSI Energy, Inc., (PSI) of Plainfield, Indiana, formed the Wabash River Coal Gasification Repowering Project Joint Venture (the JV) to participate in the DOE`s Clean Coal Technology (CCT) program by demonstrating the coal gasification repowering of an existing 1950`s vintage generating unit affected by the Clean Air Act Amendments (CAAA). The Participants, acting through the JV, signed the Cooperative Agreement with the DOE in July 1992. The Participants jointly developed, and separately designed, constructed, own, and will operate an integrated coal gasification combined cycle (CGCC) power plant using Destec`s coal gasification technology to repower Unit {number_sign}1 at PSI`s Wabash River Generating Station located in Terre Haute, Indiana. PSI is responsible for the new power generation facilities and modification of the existing unit, while Destec is responsible for the coal gasification plant. The Project demonstrates integration of the pre-existing steam turbine generator, auxiliaries, and coal handling facilities with a new combustion turbine generator/heat recovery steam generator tandem and the coal gasification facilities.

  1. Characterization and evaluation of washability of Alaskan coals: Fifty selected seams from various coal fields: Final technical report, September 30, 1976-February 28, 1986. [50 coal seams

    SciTech Connect (OSTI)

    Rao, P.D.

    1986-09-01T23:59:59.000Z

    This final report is the result of a study initiated in 1976 to obtain washability data for Alaskan coals, to supplement the efforts of the US Department of Energy in their ongoing studies on washability of US coals. Washability characteristics were determined for fifty coal samples from the Northern Alaska, Chicago Creek, Unalakleet, Nenana, Matanuska, Beluga, Yentna and Herendeen Bay coal fields. The raw coal was crushed to 1-1/2 inches, 3/8 inch, 14 mesh and 65 mesh top sizes, and float-sink separations were made at 1.30, 1.40 and 1.60 specific gravities. A limited number of samples were also crushed to 200 and 325 mesh sizes prior to float-sink testing. Samples crushed to 65 mesh top size were also separated at 1.60 specific gravity and the float and sink products were characterized for proximate and ultimate analyses, ash composition and ash fusibility. 72 refs., 79 figs., 57 tabs.

  2. Predictors of plasticity in bituminous coals. Technical progress report No. 5. [Gieseler plastometer

    SciTech Connect (OSTI)

    Lloyd, W.G.; Reasoner, J.W.; Hower, J.C.; Yates, L.P.; Bowling, C.C.; Davis, E.; Whitt, J.M.

    1982-12-01T23:59:59.000Z

    The forty fresh coal samples have been obtained, and the proximate, ultimate and petrographic characterization on all samples is now completed. ASTM Gieseler plastometry analyses have been completed on all 40 coals, in quadruplicate, and the melting and coking slopes and intersection maximum fluidities have been estimated. Significant progress has been made in completing the nonstandard analyses which will provide an important part of the project database. Fifteen coals have been subjected to the 20-run sets of isothermal Gieseler analyses; the balance of this group is expected to be completed by mid-1983. Pyrolysis gas chromatogrpahy has been completed for 36 of the 40 coals. Quantitative extractions have now been completed for 32 of the 40 coals, both with tegrahydrofuran and with dimethylformamide. FTIR spectra have been obtained in sets of three (whole coal, residue from THF extraction, residue from DMF extraction) for 31 of the 40 coals. This report also includes a descriptive study by optical microscopy of selected coals and semi-cokes derived from these coals. Future work will include correlation analysis of the completed datasets, and an intensive study of the characteristics of six or seven coals selected from the present set.

  3. Petrographic characterization of Kentucky coals. Quarterly progress report, December 1982 to February 1983

    SciTech Connect (OSTI)

    Hower, J.C.; Ferm, J.C.; Cobb, J.C.; Trinkle, E.J.; Frankie, K.A.; Poe, S.H.; Baynard, D.N.; Graese, A.M.; Raione, R.P.

    1983-01-01T23:59:59.000Z

    The project Petrographic characterization of Kentucky coals consists of three specific areas of coal petrology: spectral fluorescence of liptinite macerals, properties of semi-inert macerals, and size/form/microlithotype association of pyrite/marcasite. Additional research on the Mannington and Dunbar coals in western Kentucky and the Alma coal zone in eastern Kentucky will apply techniques developed in the first three areas. Suites of coals from other states will also be studied to expand the variability in the sample set. Due to the discrete nature of the projects, the final reports will be submitted in several parts. The first report on spectral fluorescence is in development and should be submitted prior to the end of the project. The other reports will be submitted shortly after the end of the project.

  4. Petrographic characterization of Kentucky coals. Quarterly progress report, September-November 1981

    SciTech Connect (OSTI)

    Hower, J.C.; Ferm, J.C.; Cobb, J.C.; Trinkle, E.J.; Frankie, K.A.; Poe, S.H.; Baynard, D.N.

    1981-01-01T23:59:59.000Z

    The project Petrographic Characterization of Kentucky Coals consists of research in three specific areas of coal petrology: spectral fluorescence of liptinite macerals, properties of semi-inert macerals, and size/form/microlithotype association of pyrite/marcasite. Additional research on the Mannington (No. 4, also known as Mining City and Lewisport) coal will apply techniques developed in the first three areas. Certain suits of coals from other states will also be studied to expand the variability in the samples. Preliminary results are reported.

  5. Coal demonstration plants. Quarterly report, July-September 1979

    SciTech Connect (OSTI)

    None

    1980-07-01T23:59:59.000Z

    The status of two coal liquefaction demonstration plants and of four coal gasification demonstration plants is reviewed under the following headings: company involved, contract number, funding, process name, process description, flowsheet, schedule, history and progress during the July-September quarter, 1979. Supporting projects in coal feeding systems, valves, grinding equipment, instrumentation, process control and water treatment are discussed in a similar way. Conceptual design work on commercial plants for coal to methanol and for a HYGAS high BTU gas plant were continued. (LTN)

  6. Coal anion structure and chemistry of coal alkylation. Final report, March 1, 1979-February 29, 1980

    SciTech Connect (OSTI)

    Stock, L.M.

    1980-01-01T23:59:59.000Z

    In accord with Task 1, some ether cleavage reactions were carried out in two different media - potassium/naphthalene/tetrahydrofuran and potassium/ ammonia - so that the merits and demerits of the two methods could be compared. Preliminary results suggest that both systems yield the same products, and that the ammonia medium is more convenient to work with, because of the absence of by-products such as reduced naphthalenes and tetralin. Dialkyl ethers were found to be least reactive compounds while the benzyl and phenyl ethers were found to be most reactive, as would be expected. The reductive alkylation of coal was carried out in ammonia at 25/sup 0/C. The tetrahydrofuran solubility of the reaction product was surprisingly low. We have obtained additional /sup 13/C)/sup 1/H) nmr data for tetrahydrofuran-soluble butylated coal and some model compounds; obtained additional Styragel(R) chromatography data of tetrahydrofuran-soluble coal labelled with 98%-enriched butyl-1,1-d/sub 2/ iodide; and obtained /sup 2/D nmr spectra of all the deuterium-labelled, tetrahydrofuran-soluble coal products. In accord with Task 4, we have undertaken a review of the information now available concerning the nature of Illinois No. 6 coal. Also, the effects of organic additives on the exchange reactions between tetralin-d/sub 12/ and diphenyl-methane and on the thermal cleavage reactions of several model compounds in tetralin were investigated to probe the relationship between structure and reactivity. The exchange reaction can be accelerated by coal, asphaltene-preasphaltene fractions derived from coal, compounds with labile bonds, or compounds which can be reduced readily. The pyridine-insoluble coal product, acids, and bases are inactive toward the exchange reaction.

  7. Predictors of plasticity in bituminous coals. Technical progress report No. 2, March 1, 1982

    SciTech Connect (OSTI)

    Lloyd, W. G.; Reasoner, J. W.; Hower, J. C.; Yates, L. P.; Clark, C. P.; Jones, T. M.; Sturgeon, L. P.; Whitt, J. M.

    1982-03-01T23:59:59.000Z

    The approach of this study is to secure three dozen (or more) coals of varying rank, composition and plasticity, and to analyze these coals carefully by standard chemical and petrographic techniques. The bitumen fractions will be determined, both by THF (asphaltenes but not preasphaltenes) and DMF (everything). Pyrolysis gas chromatography on both whole coals and extracted residues will compare capacities to generate metaplast. Extracts from coals with plasticities differing by at least four orders of magnitude will be examined for identifiable differences; extraction residues will be subjected to differential FTIR analysis. All of the data will be combined and subjected to systematic statistical analysis with the objective of identifying predictors of coal plasticity. This report describes the work in the first six months of the study. During this period equipment and instrumentation has been obtained, 24 coal samples have been obtained, the nonclassical methods have been developed and checked out, and an appreciable amount of experimentl data has been obtained.

  8. Advanced coal conversion process demonstration. Progress report, January 1, 1992--December 31, 1992

    SciTech Connect (OSTI)

    NONE

    1993-12-01T23:59:59.000Z

    This report contains a description of the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1992, through December 31, 1992. This project demonstrates an advanced thermal coal drying process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After drying, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. The SynCoal{reg_sign} process enhances low-rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,500 to 9,000 British thermal units per pound (Btu/lb), by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. The 45-ton-per-hour unit is located adjacent to a unit train loadout facility at Western Energy Company`s Rosebud coal mine near Colstrip, Montana. The demonstration plant is sized at about one-tenth the projected throughput of a multiple processing train commercial facility. The demonstration drying and cooling equipment is currently near commercial size. Rosebud SynCoal Partnership`s ACCP Demonstration Facility entered Phase III, Demonstration Operation, in April 1992 and has been operating in an extended startup mode since that time. As with any new developing technology, a number of unforeseen obstacles have been encountered; however, Rosebud SynCoal Partnership has instituted an aggressive program to overcome these obstacles.

  9. Impacts of the extended-weight coal haul road system. Final research report, December 1995

    SciTech Connect (OSTI)

    Pigman, J.; Crabtree, J.; Agent, K.; Graves, C.; Deacon, J.

    1995-12-01T23:59:59.000Z

    The Extended-Weight Coal Haul Road System, created by the Kentucky Legislature in 1986, consists of all roads which carry over 50,000 tons of coal in a calendar year. Trucks hauling coal on this system are authorized to exceed normal weight limits through the payment of an annual decal fee. A research study was initiated in July of 1992 to analyze the impacts of the extended-weight system. Analyses in this report are based on the following: historical data on coal production and transportation: data from coal decal applications; interviews of legislators, transportation officials, coal company representatives, and coal trucking representatives; newspaper articles; vehicle classification data; analyses of pavement costs; pavement rideability data; and accident data. Primary conclusions include; (1) The extended-weight system has apparently been somewhat successful in accomplishing the objective of enhancing the competitiveness and economic viability of the Kentucky coal industry; (2) Overall accident rates did not increase as a result of implementation of the extended-weight system, but the fatal accident injury rates were significantly higher on the extended-weight system and for trucks operating with the coal decal; (3) Advance-warning flashers have been evaluated and recommended as a means of reducing intersection accidents involving heavy/coal trucks; (4) The coal-decal fee structure results in a net annual loss in Road Fund revenue of approximately $2 million; (5) Forty percent of revenue from decal fees are allocated to counties even though county-maintained roads comprise only eight percent of the extended-weight system; (6) Heavier weights of coal-decal trucks add approximately $9 million annually to the pavement overlay costs; (7) Road users throughout the state are subsidizing the movement of Kentucky coal by participating in the cost of maintaining and improving the highway system; and (8) Possibly reflecting the increased funding of extended-weight roads.

  10. Predictors of plasticity in bituminous coals. Final technical report

    SciTech Connect (OSTI)

    Lloyd, W. G.; Reasoner, J. W.; Hower, J. C.; Yates, L. P.; Clark, C. P.; Davis, E.; Fitzpatrick, A.; Irefin, A.; Jiminez, A.; Jones, T. M.

    1984-02-01T23:59:59.000Z

    A group of 40 hvb coals, mostly from western Kentucky fields, has been examined with regard to ASTM Gieseler plastometric properties. Twenty-nine of these coals have also been studied over a range of temperatures by isothermal Gieseler plastometry. Raw Gieseler data provide melting and coking slopes and readily calculable fluidity spans. Maximum fluidity by slope intersection is a more consistent measure than observed maximum fluidity. Isothermal slopes and maximum fluidities follow Arrhenius temperature dependencies, with activation energies related systematically to fluid properties. These freshly sampled coals are also characterized by chemical, physical and petrographic criteria, by quantitative solvent extractions, by pyrolysis gas chromatography, by Fourier Transform infrared analysis of coals and extraction residues, by the HPLC analysis of coal extracts, and by optical microscopy of coals and Gieseler semi-coke residues. Multiple linear regression analysis yields three-term expressions which estimate maximum fluidities (both ASTM and isothermal) with R values of .90 to .92. Slopes and critical temperatures are similarly predictable. Plastometer experiments with selected coals under superatmospheric pressures show both melting slopes and maximum fluidities to be sharply increased, the latter by one to three orders of magnitude. Some suggestions are offered to accommodate this new information into the general body of knowledge concerning the phenomenon of plasticity in mid-ranked coals. 81 references, 28 figures, 40 tables.

  11. Liquid Tin Anode Direct Coal Fuel Cell Final Program Report

    SciTech Connect (OSTI)

    Tao, Thomas

    2012-01-26T23:59:59.000Z

    This SBIR program will result in improved LTA cell technology which is the fundamental building block of the Direct Coal ECL concept. As described below, ECL can make enormous efficiency and cost contributions to utility scale coal power. This program will improve LTA cells for small scale power generation. As described in the Commercialization section, there are important intermediate military and commercial markets for LTA generators that will provide an important bridge to the coal power application. The specific technical information from this program relating to YSZ electrolyte durability will be broadly applicable SOFC developers working on coal based SOFC generally. This is an area about which very little is currently known and will be critical for successfully applying fuel cells to coal power generation.

  12. Status Report: USGS coal assessment of the Powder River Basin, Wyoming

    SciTech Connect (OSTI)

    James A. Luppens; Timothy J. Rohrbacher; Jon E. Haacke; David C. Scott; Lee M. Osmonson [USGS, Reston, VA (United States)

    2006-07-01T23:59:59.000Z

    This publication reports on the status of the current coal assessment of the Powder River Basin (PRB) in Wyoming and Montana. This slide program was presented at the Energy Information Agency's 2006 EIA Energy Outlook and Modeling Conference in Washington, DC, on March 27, 2006. The PRB coal assessment will be the first USGS coal assessment to include estimates of both regional coal resources and reserves for an entire coal basin. Extensive CBM and additional oil and gas development, especially in the Gillette coal field, have provided an unprecedented amount of down-hole geological data. Approximately 10,000 new data points have been added to the PRB database since the last assessment (2002) which will provide a more robust evaluation of the single most productive U.S. coal basin. The Gillette coal field assessment, including the mining economic evaluation, is planned for completion by the end of 2006. The geologic portion of the coal assessment work will shift to the northern and northwestern portions of the PRB before the end of 2006 while the Gillette engineering studies are finalized. 7 refs.

  13. Low-rank coal research, Task 5.1. Topical report, April 1986--December 1992

    SciTech Connect (OSTI)

    Not Available

    1993-02-01T23:59:59.000Z

    This document is a topical progress report for Low-Rank Coal Research performed April 1986 - December 1992. Control Technology and Coal Preparation Research is described for Flue Gas Cleanup, Waste Management, Regional Energy Policy Program for the Northern Great Plains, and Hot-Gas Cleanup. Advanced Research and Technology Development was conducted on Turbine Combustion Phenomena, Combustion Inorganic Transformation (two sections), Liquefaction Reactivity of Low-Rank Coals, Gasification Ash and Slag Characterization, and Coal Science. Combustion Research is described for Atmospheric Fluidized-Bed Combustion, Beneficiation of Low-Rank Coals, Combustion Characterization of Low-Rank Fuels (completed 10/31/90), Diesel Utilization of Low-Rank Coals (completed 12/31/90), Produce and Characterize HWD (hot-water drying) Fuels for Heat Engine Applications (completed 10/31/90), Nitrous Oxide Emission, and Pressurized Fluidized-Bed Combustion. Liquefaction Research in Low-Rank Coal Direct Liquefaction is discussed. Gasification Research was conducted in Production of Hydrogen and By-Products from Coals and in Sulfur Forms in Coal.

  14. Ultrafine coal single stage dewatering and briquetting process. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Wilson, J.W. [Univ. of Missouri, Rolla, MO (United States). Dept. of Mining Engineering; Honaker, R.Q. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mining Engineering

    1994-12-31T23:59:59.000Z

    It is well known that a large portion of the pyrite particles in the coal seams of the Illinois Basin, are finely disseminated within the coal matrix. In order to liberate these micron size pyrite particles, one must use a fine grinding operation. The ultrafine coal particles that are produced are difficult to dewater and they create problems in coal transportation as well as in its storage and handling at utility plants. The objective of this research project is to combine ultrafine coal dewatering and briquetting processes into a single stage operation. This will be accomplished by the use of bitumen based emulsions for dewatering and a compaction device for briquetting. During this reporting period, two types of coal samples have been tested for use in the dewatering and briquetting processes. These tests were carried out in conjunction with a selected hydrophobic binder as the dewatering reagent and an uniaxial hydraulic press. The influence of compaction pressure and binder concentration (2 to 5%) on the performance of coal pellets have been evaluated in terms of their water and wear resistance. A laboratory scale ultrafine coal dewatering and briquetting extruder that can be operated continuously for coal pellets fabrication, has been designed and built, and will be available for testing in the next quarter.

  15. Fundamental aspects of coal-water fuel droplet combustion and secondary atomization of coal-water mixtures. Volume I, final report

    E-Print Network [OSTI]

    Sarofim, Adel F.

    1987-01-01T23:59:59.000Z

    This Final Report is issued in two volumes, covering research into the combustion of coal-water fuels (CWF). Two separate but related tasks are discussed; the present report, Volume I, contains results obtained under Task ...

  16. Report to the United States Congress clean coal technology export markets and financing mechanisms

    SciTech Connect (OSTI)

    Not Available

    1994-05-01T23:59:59.000Z

    This report responds to a Congressional Conference Report that requests that $625,000 in funding provided will be used by the Department to identify potential markets for clean coal technologies in developing countries and countries with economies in transition from nonmarket economies and to identify existing, or new, financial mechanisms or financial support to be provided by the Federal government that will enhance the ability of US industry to participate in these markets. The Energy Information Administration (EIA) expects world coal consumption to increase by 30 percent between 1990 and 2010, from 5.1 to 6.5 billion short tons. Five regions stand out as major foreign markets for the export of US clean coal technologies: China; The Pacific Rim (other than China); South Asia (primarily India); Transitional Economies (Central Europe and the Newly Independent States); and Other Markets (the Americas and Southern Africa). Nearly two-thirds of the expected worldwide growth in coal utilization will occur in China, one quarter in the United States. EIA forecasts nearly a billion tons per year of additional coal consumption in China between 1990 and 2010, a virtual doubling of that country`s coal consumption. A 30-percent increase in coal consumption is projected in other developing countries over that same period. This increase in coal consumption will be accompanied by an increase in demand for technologies for burning coal cost-effectively, efficiently and cleanly. In the Pacific Rim and South Asia, rapid economic growth coupled with substantial indigenous coal supplies combine to create a large potential market for CCTS. In Central Europe and the Newly Independent States, the challenge will be to correct the damage of decades of environmental neglect without adding to already-considerable economic disruption. Though the situation varies, all these countries share the basic need to use indigenous low-quality coal cleanly and efficiently.

  17. MHD coal-fired flow facility. Annual technical progress report, October 1979-September 1980

    SciTech Connect (OSTI)

    Alstatt, M.C.; Attig, R.C.; Brosnan, D.A.

    1981-03-01T23:59:59.000Z

    The University of Tennessee Space Institute (UTSI) reports on significant activity, task status, planned research, testing, development, and conclusions for the Magnetohydrodynamics (MHD) Coal-Fired Flow Faclity (CFFF) and the Energy Conversion Facility (ECF).

  18. Low-rank coal research. Quarterly technical progress report, April-June 1984

    SciTech Connect (OSTI)

    Not Available

    1984-08-01T23:59:59.000Z

    Papers in the quarterly technical progress report for the period April-June, 1984, of the Low-Rank Coal Research project have been entered individually into EDB and ERA (17 items). (LTN)

  19. Advanced Coal Conversion Process Demonstration Project. Technical progress report, January 1, 1995--March 31, 1995

    SciTech Connect (OSTI)

    NONE

    1996-06-01T23:59:59.000Z

    This detailed report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project. This U.S. Department of Energy (DOE) Clean Coal Technology Project demonstrates an advanced thermal coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to high-quality, low-sulfur fuel. During this reporting period, the primary focus for the project was to expand market awareness and acceptability for the products and the technology. The use of covered hopper cars has been successful and marketing efforts have focused on this technique. Operational improvements are currently aimed at developing fines marketing systems, increasing throughput capacity, decreasing operation costs, and developing standardized continuous operator training. Testburns at industrial user sites were also conducted. A detailed process description; technical progress report including facility operations/plant production, facility testing, product testing, and testburn product; and process stability report are included. 3 figs., 8 tabs.

  20. U.S. Energy Information Administration | Annual Coal Report 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSSCoal Production and Number of MinesCoalCoal Coal

  1. The development of coal-based technologies for Department of Defense facilities: Phase 1 final report. Volume 1: Technical report

    SciTech Connect (OSTI)

    Miller, B.G.; Morrison, J.L.; Pisupati, S.V. [Pennsylvania State Univ., University Park, PA (United States). Energy and Fuels Research Center] [and others

    1997-01-31T23:59:59.000Z

    The first phase of a three-phase project investigating the development of coal-based technologies for Department of Defense facilities has been completed. The objectives of the project are to: decrease DOD`s dependence on foreign oil and increase its use of coal; promote public and private sector deployment of technologies for utilizing coal-based fuels in oil-designed combustion equipment; and provide a continuing environment for research and development of coal-based fuel technologies for small-scale applications at a time when market conditions in the US are not favorable for the introduction of coal-fired equipment in the commercial and industrial capacity ranges. The Phase 1 activities were focused on developing clean, coal-based combustion technologies for the utilization of both micronized coal-water mixtures (MCWMs) and dry, micronized coal (DMC) in fuel oil-designed industrial boilers. The specific objective in Phase 1 was to deliver fully engineered retrofit options for a fuel oil-designed watertube boiler located on a DOD installation to fire either MCWM or DMC. This was achieved through a project consisting of fundamental, pilot-sale, and demonstration-scale activities investigating coal beneficiation and preparation, and MCWM and DMC combustion performance. In addition, detailed engineering designs and an economic analysis were conducted for a boiler located at the Naval Surface Warfare Center, near Crane, Indiana. Results are reported on MCWM and DMC combustion performance evaluation; engineering design; and cost/economic analysis.

  2. Molecular accessibility in oxidized and dried coals. Quarterly report

    SciTech Connect (OSTI)

    Kispert, L.D.

    1995-06-01T23:59:59.000Z

    The objective of this research project is to determine the molecular and structural changes that occur in swelled coal as a result of oxidation and moisture loss both in the presence and absence of light using the newly developed EPR spin probe method. The proposed study will make it possible to deduce the molecular accessibility distribution in swelled, oxidized APCS coal for each rank as a function of (1) size (up to 6 nm) and shape, (2) the relative acidic/basic reactive site distributions, and (3) the role of hydrogen bonding as a function of swelling solvents. The advantage of the EPR method is that it permits molecules of selected shape, size and chemical reactivity to be used as probes of molecular accessible regions of swelled coal. From such data an optimum catalyst can be designed to convert oxidized coal into a more convenient form and methods can be devised to lessen the detrimental weathering processes.

  3. Encoal mild coal gasification project: Final design modifications report

    SciTech Connect (OSTI)

    NONE

    1997-07-01T23:59:59.000Z

    The design, construction and operation Phases of the Encoal Mild Coal Gasification Project have been completed. The plant, designed to process 1,000 ton/day of subbituminous Power River Basin (PRB) low-sulfur coal feed and to produce two environmentally friendly products, a solid fuel and a liquid fuel, has been operational for nearly five years. The solid product, Process Derived Fuel (PDF), is a stable, low-sulfur, high-Btu fuel similar in composition and handling properties to bituminous coal. The liquid product, Coal Derived Liquid (CDL), is a heavy, low-sulfur, liquid fuel similar in properties to heavy industrial fuel oil. Opportunities for upgrading the CDL to higher value chemicals and fuels have been identified. Significant quantities of both PDF and CDL have been delivered and successfully burned in utility and industrial boilers. A summary of the Project is given.

  4. Illinois coal reserve assessment and database development. Final report

    SciTech Connect (OSTI)

    Treworgy, C.G.; Prussen, E.I.; Justice, M.A.; Chenoweth, C.A. [and others

    1997-11-01T23:59:59.000Z

    The new demonstrated reserve base estimate of coal of Illinois is 105 billion short tons. This estimate is an increase from the 78 billion tons in the Energy Information Administration`s demonstrated reserve base of coal, as of January 1, 1994. The new estimate arises from revised resource calculations based on recent mapping in a number of countries, as well as significant adjustments for depletion due to past mining. The new estimate for identified resources is 199 billion tons, a revision of the previous estimate of 181 billion tons. The new estimates incorporate the available analyses of sulfur, heat content, and rank group appropriate for characterizing the remaining coal resources in Illinois. Coal-quality data were examined in conjunction with coal resource mapping. Analyses of samples from exploration drill holes, channel samples from mines and outcrops, and geologic trends were compiled and mapped to allocate coal resource quantities to ranges of sulfur, heat content, and rank group. The new allocations place almost 1% of the demonstrated reserve base of Illinois in the two lowest sulfur categories, in contrast to none in the previous allocation used by the Energy Information Administration (EIA). The new allocations also place 89% of the demonstrated reserve base in the highest sulfur category, in contrast to the previous allocation of 69% in the highest category.

  5. Research on chemical factors in underground coal gasification. Final technical report

    SciTech Connect (OSTI)

    Edgar, T.F.

    1985-09-01T23:59:59.000Z

    The goal of this research has been to acquire experimental data and develop mathematical models in order to analyze results from laboratory-scale and field-scale experiments on underground coal gasification (UCG), especially for low-rank coals such as Texas lignite. Experimental data for water injection in a combustion tube, coal core combustion, and coal block gasification are reported; in parallel, a mathematical model for the combustion tube temperature profile and gas composition was developed which compared favorably with experimental data. A mathematical model for predicting gas composition and coal recovery in the Hoe Creek field experiment has been completed and verified with field data. Two experiments have been constructed to obtain data on reactions of interest to UCG; these include an apparatus for determining the kinetics of tar cracking and a microreactor for analyzing the process dynamics of the water gas shift reaction carried out in a fixed bed catalytic system. 44 refs., 60 figs., 22 tabs.

  6. Cooperative research in coal liquefaction infratechnology and generic technology development: Final report, October 1, 1985 to December 31, 1986

    SciTech Connect (OSTI)

    Sendlein, L.V.A.

    1987-06-29T23:59:59.000Z

    During the first year of its research program, the Consortium for Fossil Fuel Liquefaction Science has made significant progress in many areas of coal liquefaction and coal structure research. Research topics for which substantial progress has been made include integrated coal structure and liquefaction studies, investigation of differential liquefaction processes, development and application of sophisticated techniques for structural analysis, computer analysis of multivariate data, biodesulfurization of coal, catalysis studies, co-processing of coal and crude oil, coal dissolution and extraction processes, coal depolymerization, determination of the liquefaction characteristics of many US coals for use in a liquefaction database, and completion of a retrospective technology assessment for direct coal liquefaction. These and related topics are discussed in considerably more detail in the remainder of this report. Individual projects are processed separately for the data base.

  7. Secondary economic impact of acid deposition control legislation in six coal producing states: Final report

    SciTech Connect (OSTI)

    Scott, M.J.; Guthrie, S.J.

    1988-12-01T23:59:59.000Z

    Among the difficult policy questions on the US environmental agenda is what to do about emissions to the earth's atmosphere of pollutants that may result in ''acid rain''. The Congress has considered several pieces of legislation spelling out potential approaches to the problem and setting goals for emission reduction, mostly emphasizing the control of oxides of sulfur and nitrogen. Significant policy concern is the dollar costs to the nation's economy of achieving the intended effects of the legislation and the potential impacts on economic activity---in particular, losses of both coal mining and secondary service sector employment in states and regions dependent on the mining of high sulfur coal. There are several direct economic effects of regulations such as the acid rain control legislation. One of the more obvious effects was the switching from high sulfur coal to low sulfur coal. This would result in increases in employment and coal business procurements in low sulfur coal mining regions, but also would result in lower employment and lower coal business procurements in high sulfur coal mining areas. The potential negative effects are the immediate policy concern and are the focus of this report. 15 refs., 1 fig., 17 tabs.

  8. Impact of hydrodynamics on coal liquefaction. Final technical report

    SciTech Connect (OSTI)

    Kang, D.; Ying, D.H.S.; Givens, E.N.

    1983-09-01T23:59:59.000Z

    We have attempted to determine the hydrodynamic effects of various reactor configurations on coal liquefaction, to help select the optimal reactor configuration and to provide additional understanding of coal liquefaction reaction kinetics, which cannot be definitively determined by a CSTR alone. Only a qualitative understanding of the fluid dynamic effects on product yields has been perceived by operating various sizes of open-column tubular reactors, because the fluid-dynamic characteristics of these reactors were not clearly understood and could not be varied significantly. Indirect studies, by cold-flow simulation, have been of little help in defining the fluid dynamic impact on coal liquefaction. Comparison of actual coal liquefaction data from both the plug-flow reactor and the CSTR showed that the plug-flow configuration had various advantages. Reactor yields improved significantly, especially the primary product conversions. At 840/sup 0/F and residence times of 29 and 40 min, coal and preasphaltene conversions were enhanced approximately 6 and 10%, respectively. At these conditions, the plug-flow reactor also yielded about 10% more oils than the CSTR with significant increase in hydrogen utilization. Also, this study provided an opportunity to examine the soundness of APCI/ICRC's sequential kinetic model, by interfacing the plug-flow and CSTR yield data. Transforming CSTR yields to plug-flow data showed that product yields deviated considerably from the measured plug-flow data, suggesting the need to improve the existing reaction model. Having both CSTR and plug-flow reactor data bases is important for developing a sound coal reaction model and for determining hydrodynamic effects on coal liquefaction in a direct way. The results will lead to an optimized reactor configuration as well as optimized operation. 5 references, 23 figures, 20 tables.

  9. Oxidation of coal and coal pyrite mechanisms and influence on surface characteristics. Technical progress report, December 31, 1992

    SciTech Connect (OSTI)

    Doyle, F.M.

    1992-12-31T23:59:59.000Z

    During the ninth quarter, electrochemical experiments were done on electrodes prepared from Upper Freeport coal pyrite and Pittsburgh coal pyrite samples provided by the US Bureau of Mines, Pittsburgh Research Center, Pennsylvania. Scanning electron microscopy and energy dispersive X-ray analysis were done to characterize the morphology and composition of the surface of as-received coal, oxidized coal and coal pyrite. In addition, electrokinetic tests were done on Upper Freeport coal pyrite.

  10. Rawlins UCG (underground coal gasification) Demonstration Project site characterization report

    SciTech Connect (OSTI)

    Not Available

    1989-04-01T23:59:59.000Z

    The US Department of Energy and Energy International, Inc. have entered into a Cooperative Agreement to conduct a cost-shared UCG field test demonstrating the operation of commercial scale underground coal gasification (UCG) on steeply dipping bed modules to provide synthesis gas for a small scale commercial ammonia plant. The field test and the commercial ammonia plant will be located at the North Knobs site near Rawlins, Wyoming. During this demonstration test, two or more UCG modules will be operated simultaneously until one module is completely consumed and an additional module is brought on line. During this period, the average coal gasification rate will be between 500 and 1200 tons per day. A portion of the raw UCG product gas will be cleaned and converted into a synthesis gas, which will be used as feedstock to a 400--500 ton per day ammonia plant. The UCG facility will continue to operate subsequent to the test demonstration to provide feedstock for the commercial plant. The objective of the geologic site characterization program is to provide a descriptive model that accurately represents the geologic environment of the coal resource that is to be gasified. This model is to be used as an aid in understanding the hydrology of the coal bearing sequence, as a framework for installation of the process wells and the subsequent exploitation of the coal resources. 3 figs., 3 tabs.

  11. Analysis of chemical coal cleaning processes. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-06-01T23:59:59.000Z

    Six chemical coal cleaning processes were examined. Conceptual designs and costs were prepared for these processes and coal preparation facilities, including physical cleaning and size reduction. Transportation of fine coal in agglomerated and unagglomerated forms was also discussed. Chemical cleaning processes were: Pittsburgh Energy Technology Center, Ledgemont, Ames Laboratory, Jet Propulsion Laboratory (two versions), and Guth Process (KVB). Three of the chemical cleaning processes are similar in concept: PETC, Ledgemont, and Ames. Each of these is based on the reaction of sulfur with pressurized oxygen, with the controlling factor being the partial pressure of oxygen in the reactor. All of the processes appear technically feasible. Economic feasibility is less certain. The recovery of process chemicals is vital to the JPL and Guth processes. All of the processes consume significant amounts of energy in the form of electric power and coal. Energy recovery and increased efficiency are potential areas for study in future more detailed designs. The Guth process (formally designed KVB) appears to be the simplest of the systems evaluated. All of the processes require future engineering to better determine methods for scaling laboratory designs/results to commercial-scale operations. A major area for future engineering is to resolve problems related to handling, feeding, and flow control of the fine and often hot coal.

  12. Documentation of the demonstrated reserve base of coal in the United States. Volume 2. Final report

    SciTech Connect (OSTI)

    Herhal, A J; Britton, S G; Minnucci, C A

    1982-03-01T23:59:59.000Z

    The purpose of this report is to document the methodologies used to develop the 1979 Demonstrated Reserve Base (DRB) of coal. The main body of this report summarizes the methodological procedures used to develop each state reserve estimate. The appendices to the report provide a detailed description of the entire DRB process for each state.

  13. Chlorine in coal and its relationship with boiler corrosion. [Quarterly] technical report, December 1, 1993--February 28, 1994

    SciTech Connect (OSTI)

    Chou, M.I.M.; Lytle, J.M.; Ruch, R.R.; Chou, C.L. [Illinois State Geological Survey, Champaign, IL (United States)] [and others

    1994-06-01T23:59:59.000Z

    Limited literature and use history data have suggested that some high-chlorine Illinois coals do not cause boiler corrosion while extensive data developed by the British correlate corrosion with chlorine content and other parameters related to the coal and boiler. The differences in corrosivity in coals may be due to the coal properties, to blending of coals, or to the boiler parameters in which they were burned. The goals of this study focus on coal properties and are: (1) to characterize chlorine and other constituents in coals which have been reported to behave differently with respect to corrosion problems during combustion; (2) to determine the evolution profiles of chlorine-containing compounds in coals during pyrolysis and oxidation; and (3) to examine the behavior of Cl-, S-, N-, O-containing compounds in coal during pyrolysis. Proximate, ultimate, and ash composition analyses for all of the British and Illinois coal samples were completed in this quarter. Analysis of the acid-soluble sodium and potassium in coals is in progress. These data, along with ash composition data, will be used to assess a coal`s relative corrosion potential. The HCl evolution profiles obtained from oxidation of the five Illinois coal samples were examined. The results indicate that temperatures of maximum HCl evolution range were 430{degree}C to 450{degree}C.

  14. High performance materials in coal conversion utilization. Technical progress report, October 1, 1994--December 31, 1994

    SciTech Connect (OSTI)

    NONE

    1995-01-01T23:59:59.000Z

    This is the fifth quarterly report on a three year grant regarding {open_quotes}High Performance Materials in Coal Conversion Utilization.{close_quotes} The grant is for a joint university/industry effort under the US Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. UTSI has completed the planned laboratory exposure tests involving pulverized coal slag on the production Lanxide DIMOX{trademark} ceramic composite material. In addition, the strength testing (at temperature) of C-ring sections of the production composite is complete.

  15. Fundamental investigations of underground coal gasification. Final report, March 1982-December 1986

    SciTech Connect (OSTI)

    Gunn, R.D.

    1987-08-01T23:59:59.000Z

    The report presents several mathematical models of underground coal-gasification processes. Through these models, a much better theoretical understanding of underground coal gasification becomes possible. Specific phenomena studied were the effects of high-amplitude pressure oscillation, reverse combustion, spontaneous ignition at high pressures, an analytical model of reverse-combustion channeling, an exploratory study of electrolinking, cavity-growth behavior, and a technical evaluation of the Forestburg underground coal-gasification field test at Forestburg, Alberta. This test is especially interesting because the site was escavated after completion of the experiment.

  16. Testing of Western Kentucky No. 9 coal in an atmospheric fluidized-bed combustor. Technical report

    SciTech Connect (OSTI)

    Pettit, R.

    1984-05-01T23:59:59.000Z

    This report deals with the characterization of a western Kentucky No. 9 coal as an atmospheric fluidized-bed combustor (AFBC) feedstock. It is the first of a series of four reports, each dealing with a different Kentucky coal. All of the coal tests were conducted using an Oregon dolomite from the central Kentucky region. The tests were conducted in a 2 ft. 8 in. x 2 ft. 5 in. atmospheric fluidized bed combustor. The Western Kentucky No. 9 coal tested had a heating value of 12200 Btu/lb. The Oregon dolomite used contained 61% CaCO3 and 31% MgCO3. Detailed feedstock analyses are presented in Appendix E. Seven steady-state test runs were conducted over a two-week period. The runs were at one of 100%, 85%, or 70% loads. The air flowrate, bed temperature, and stack sulfur dioxide emissions rate were kept approximately constant during these tests to facilitate comparison.

  17. Combustion of calcium-exchanged coal. First quarterly report

    SciTech Connect (OSTI)

    Gavalas, G.R.; Flagan, R.C.

    1984-02-10T23:59:59.000Z

    The work performed during this first period includes equipment modification, development of analytical methods, oxidative pretreatment runs and combustion runs. The coal feeding section of an existing furnace was modified for uninterrupted feeding and better control of residence time. Analytical methods for sulfur and calcium in the coal and ash and for gaseous SO/sub 2/ were standardized. Oxidative pretreatment experiments were conducted in a fluidized bed at temperatures about 200/sup 0/C to evaluate the potential of this method for increasing the ion exchange capacity of coals and determine the accompanying loss of heating value. Combustion experiments were carried out at very high particle temperatures (2000/sup 0/K) at which a large fraction of the calcium additive was vaporized while 50 to 80% of the sulfur evolved as sulfur oxide. Continuing combustion experiments will be conducted at lower particle temperatures.

  18. U.S. Energy Information Administration | Annual Coal Report 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSSCoal Production and Number of MinesCoalCoal

  19. U.S. Energy Information Administration | Annual Coal Report 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSSCoal Production and Number of MinesCoalCoal

  20. Preliminary report on LLNL mine seismicity deployment at the Twentymile Coal Mine

    SciTech Connect (OSTI)

    Walter, W.R.; Hunter, S.L.; Glenn, L.A.

    1996-01-01T23:59:59.000Z

    This report summarizes the preliminary results of a just completed experiment at the Twentymile Coal Mine, operated by the Cyprus Amax Coal Company near Oak Creek, CO. The purpose of the experiment was to obtain local and regional seismic data from roof caves associated with long-wall mining activities and to use this data to help determine the effectiveness with which these events can be discriminated from underground nuclear explosions under a future Comprehensive Test Ban Treaty.

  1. Development of a retrofit coal combustor for industrial applications. Technical progress report, January--March 1987

    SciTech Connect (OSTI)

    Not Available

    1987-12-31T23:59:59.000Z

    In this first quarterly technical report for DOE Contract No. DE-AC22-87PC79654, a description of the background, technology, and application is provided. The design and fabrication of advanced combustion chambers were completed during this period. Initial testing on both the bare metal and refractory lined advanced chambers were initiated. The units were tested initially with gas but primarily with coal. A Pittsburgh No. 8 pulverized coal was used for these test activities. Both advanced chambers pulsed well.

  2. Fundamental aspects of coal-water fuel droplet combustion and secondary atomization of coal-water mixtures. Volume II, final report

    E-Print Network [OSTI]

    Ber?, J. M.

    1987-01-01T23:59:59.000Z

    This Final Report is issued in two volumes, covering research into the combustion of Coal Water Fuels (CWF). Two separate but related tasks are discussed; Volume I contains results obtained under Task 1 - Fundamental aspects ...

  3. Evaluation of hyperbaric filtration for fine coal dewatering. Final report

    SciTech Connect (OSTI)

    Parekh, B.K. [Univ. of Kentucky, Lexington, KY (United States); Hogg, R. [Pennsylvania State Univ., University Park, PA (United States); Fonseca, A. [CONSOL Inc. (United States)

    1996-08-15T23:59:59.000Z

    The main objectives of the project were to investigate the fundamental aspects of particle-liquid interaction in fine coal dewatering, to conduct laboratory and pilot plant studies on the applicability of hyperbaric filter systems and to develop process conditions for dewatering of fine clean coal to less than 20% moisture. The program consisted of three phases, namely Phase 1 -- Model Development, Phase 2 -- Laboratory Studies, Phase 3 -- Pilot Plant Testing. The Pennsylvania State University led efforts in Phase 1, the University of Kentucky in Phase 2, and CONSOL Inc. in Phase 3 of the program. All three organizations were involved in all the three phases of the program. The Pennsylvania State University developed a theoretical model for hyperbaric filtration systems, whereas the University of Kentucky conducted experimental studies to investigate fundamental aspects of particle-liquid interaction and application of high pressure filter in fine coal dewatering. The optimum filtration conditions identified in Phase 1 and 2 were tested in two of the CONSOL Inc. coal preparation plants using an Andritz Ruthner portable hyperbaric filtration unit.

  4. Biological production of ethanol from coal. Final report

    SciTech Connect (OSTI)

    Not Available

    1992-12-01T23:59:59.000Z

    Due to the abundant supply of coal in the United States, significant research efforts have occurred over the past 15 years concerning the conversion of coal to liquid fuels. Researchers at the University of Arkansas have concentrated on a biological approach to coal liquefaction, starting with coal-derived synthesis gas as the raw material. Synthesis gas, a mixture of CO, H{sub 2}, CO{sub 2}, CH{sub 4} and sulfur gases, is first produced using traditional gasification techniques. The CO, CO{sub 2} and H{sub 2} are then converted to ethanol using a bacterial culture of Clostridium 1jungdahlii. Ethanol is the desired product if the resultant product stream is to be used as a liquid fuel. However, under normal operating conditions, the ``wild strain`` produces acetate in favor of ethanol in conjunction with growth in a 20:1 molar ratio. Research was performed to determine the conditions necessary to maximize not only the ratio of ethanol to acetate, but also to maximize the concentration of ethanol resulting in the product stream.

  5. Fine particle clay catalysts for coal liquefaction. Final technical report

    SciTech Connect (OSTI)

    Olson, E.S.

    1995-08-01T23:59:59.000Z

    In an effort to develop new disposable catalysts for direct coal liquefaction, several types of clay-supported pyrrhotite catalysts were prepared and tested. These included iron-pillared montmorillonite, mixed iron/alumina-pillared montmorillonite, iron-impregnated montmorillonite, and iron oxometallate-impregnated montmorillonite.

  6. Pricetown I underground coal gasification field test: operations report

    SciTech Connect (OSTI)

    Agarwal, A.K.; Seabaugh, P.W.; Zielinski, R.E.

    1981-01-01T23:59:59.000Z

    An Underground Coal Gasification (UCG) field test in bituminous coal was successfully completed near Pricetown, West Virginia. The primary objective of this field test was to determine the viability of the linked vertical well (LVV) technology to recover the 900 foot deep, 6 foot thick coal seam. A methane rich product gas with an average heating value of approximately 250 Btu/SCF was produced at low air injection flow rates during the reverse combustion linkage phase. Heating value of the gas produced during the linkage enhancement phase was 221 Btu/SCF with air injection. The high methane formation has been attributed to the thermal and hydrocracking of tars and oils along with hydropyrolysis and hydrogasification of coal char. The high heating value of the gas was the combined effect of residence time, flow pattern, injection flow rate, injection pressure, and back pressure. During the gasification phase, a gas with an average heating value of 125 Btu/SCF was produced with only air injection, which resulted in an average energy production of 362 MMBtu/day.

  7. Petrographic characterization of Kentucky coals. Quarterly progress report, December 1981-February 1982

    SciTech Connect (OSTI)

    Hower, J.C.; Ferm, J.C.; Cobb, J.C.; Trinkle, E.J.; Frankie, K.A.; Poe, S.H.; Baynard, D.N.

    1982-01-01T23:59:59.000Z

    The project involves three specific areas of coal petrology: spectral fluorescence of liptinite macerals; properties of semi-inert macerals; and size/form/microlithotype association of pyrite/marcasite. Additional research on the Mannington and Dunbar coals in western Kentucky will apply techniques developed in the first three areas. Suites of coals from other states will also be studied to expand the variability for the project which involves the determination of coal rank through the use of fluorescence measurements on sporinite, all samples have been studied and data analysis is still incomplete. Interpretation of results will be presented in future reports. The actual developments of pseudovitrinites are being investigated. Two possible mechanisms for the origin of pseudovitrinites have been suggested. The first mechanism is differential coalification of similar materials. The second factor for influencing the development of pseudovitrinite is an actual difference in original plant composition. Pyrite analysis of western Kentucky coals has been completed, however data reduction is still incomplete. Changes in the petrography of western coals may be related to depositional environments of the coal.

  8. Solvent Refined Coal (SRC) process. Quarterly technical progress report, January 1979-March 1979

    SciTech Connect (OSTI)

    Not Available

    1980-02-01T23:59:59.000Z

    This report summarizes the progress of the Solvent Refined Coal (SRC) Project by the Pittsburg and Midway Coal Mining Co. for the Department of Energy for the period January 1, 1979 to March 31, 1979. Activities included the operation and modification of the Solvent Refined Coal Pilot Plant at Fort Lewis, Washington; the Process Development Unit P-99 at Harmarville, Pennsylvania; and research at Merriam Laboratory in Merriam, Kansas. The Pilot Plant processed Powhatan No. 5 Coal in the SRC-II mode of operation studying the effect of coal particle size and system temperature on coal slurry blending and the effect of carbon monoxide concentration in the reaction feed gas on process yields. January and February were spent completing installation of a fourth High Pressure Separator on Process Development Unit P-99 to better simulate operating conditions for the proposed Demonstration Plant. During March, one run was completed at P-99 feeding Pittsburgh Seam Coal from the Powhatan No. 5 Mine. Merriam investigations included a study of the effect of iron containing additives on SRC-I operation, the addition of carbon monoxide to the feed gas, utilization of a hydrogenated solvent (Cresap process solvent) in the SRC-I mode under both normal and short residence time operating conditions, and development of a simulated distillation technique to determine the entire boiling range distribution of product oils.

  9. The development of coal-based technologies for Department of Defense facilities. Technical progress report, September 1995 - March 1996

    SciTech Connect (OSTI)

    Miller, B.G.; Pisupati, S.V.; Scaroni, A.W. [and others

    1996-10-01T23:59:59.000Z

    The U.S. Department of Defense (DOD), through an Interagency Agreement with the U.S. Department of Energy (DOE), has initiated a three-phase program with the Consortium for Coal-Water Slurry Fuel Technology, with the aim of decreasing DOD`s reliance on imported oil by increasing its use of coal. The program is being conducted as a cooperative agreement between the Consortium and DOE. Activities this reporting period are summarized by phase. During this reporting period, the Phase I final report was completed. Work in Phase II focused on emissions reductions, coal beneficiation/preparation studies, and economic analyses of coal use. Emissions reductions investigations included completing a study to identify appropriate SO{sub 2} and NO{sub x} control technologies for coal-fired industrial boilers. In addition, work continued on the design of a ceramic filtering device for installation on the demonstration boiler. The ceramic filtering device will be used to demonstrate a smaller and more efficient filtering device for retrofit applications. Work related to coal preparation and utilization, and the economic analysis was primarily focused on preparing the final report. Work in Phase III focused on coal preparation studies and economic analyses of coal use. Coal preparation studies were focused on continuing activities on particle size control, physical separations, surface-based separation processes, and dry processing. The economic study focused on community sensitivity to coal usage, regional economic impacts of new coal utilization technologies, and constructing a national energy portfolio.

  10. ENCOAL mild coal gasification demonstration project. Annual report, October 1994--September 1995

    SciTech Connect (OSTI)

    NONE

    1996-01-01T23:59:59.000Z

    This document is the combination of the fourth quarter report (July - September 1995) and the 1995 annual report for the ENCOAL project. The following pages include the background and process description for the project, brief summaries of the accomplishments for the first three quarters, and a detailed fourth quarter report. Its purpose is to convey the accomplishments and current progress of the project. ENCOAL Corporation, a wholly-owned subsidiary of SMC Mining Company (formerly Shell Mining company, now owned by Zeigler Coal Holding Company), has completed the construction and start-up of a mild gasification demonstration plant at Triton Coal Company`s Buckskin Mine near Gillette, Wyoming. The process, using Liquids From Coal (LFC) technology developed by SMC and SGI International, utilizes low-sulfur Powder River Basis coal to produce two new fuels, Process Derived Fuel (PDF) and Coal Derived Liquids (CDL). The products, as alternative fuels sources, are expected to significantly lower current sulfur emissions at industrial and utility boiler sites throughout the nation, thereby reducing pollutants causing acid rain. In the LFC technology, coal is first deeply dried to remove water physically. The temperature is further raised in a second stage which results in decomposition reactions that form the new products. This chemical decomposition (mild gasification) creates gases by cracking reactions from the feed coal. The chemically altered solids are cooled and further processed to make PDF. The gases are cooled, condensing liquids as CDL, and the residual gases are burned in the process for heat. The process release for the ENCOAL plant predicted that one ton of feed coal would yield roughly {1/2} ton of PDF and {1/2} barrel of CDL. By varying plant running conditions, however, it has since been learned that the actual CDL recovery rate may be as much as 15% to 20% above the projections.

  11. High-pressure coal fuel processor development. Final report

    SciTech Connect (OSTI)

    Greenhalgh, M.L. [Caterpillar, Inc., Peoria, IL (United States)

    1992-12-01T23:59:59.000Z

    Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. Two overall conclusions resulted from Task 1. First direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risk associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept. The significant conclusions from Task 2 were: An engine concept, derived from a Caterpillar 3600 series engine, and a fuel processor concept, based on scaling up a removable-canister configuration from the test rig, appear feasible; and although the results of this concept study are encouraging, further, full-scale component research and development are required before attempting a full-scale integrated system demonstration effort.

  12. Coal-fired high performance power generating system. Final report

    SciTech Connect (OSTI)

    NONE

    1995-08-31T23:59:59.000Z

    As a result of the investigations carried out during Phase 1 of the Engineering Development of Coal-Fired High-Performance Power Generation Systems (Combustion 2000), the UTRC-led Combustion 2000 Team is recommending the development of an advanced high performance power generation system (HIPPS) whose high efficiency and minimal pollutant emissions will enable the US to use its abundant coal resources to satisfy current and future demand for electric power. The high efficiency of the power plant, which is the key to minimizing the environmental impact of coal, can only be achieved using a modern gas turbine system. Minimization of emissions can be achieved by combustor design, and advanced air pollution control devices. The commercial plant design described herein is a combined cycle using either a frame-type gas turbine or an intercooled aeroderivative with clean air as the working fluid. The air is heated by a coal-fired high temperature advanced furnace (HITAF). The best performance from the cycle is achieved by using a modern aeroderivative gas turbine, such as the intercooled FT4000. A simplified schematic is shown. In the UTRC HIPPS, the conversion efficiency for the heavy frame gas turbine version will be 47.4% (HHV) compared to the approximately 35% that is achieved in conventional coal-fired plants. This cycle is based on a gas turbine operating at turbine inlet temperatures approaching 2,500 F. Using an aeroderivative type gas turbine, efficiencies of over 49% could be realized in advanced cycle configuration (Humid Air Turbine, or HAT). Performance of these power plants is given in a table.

  13. LLNL Underground Coal Gasification Project annual report - fiscal year 1984

    SciTech Connect (OSTI)

    Stephens, D.R.; O'Neal, E.M. (eds.)

    1985-06-15T23:59:59.000Z

    The Laboratory has been conducting an interdisciplinary underground coal gasification program since 1974 under the sponsorship of DOE and its predecessors. We completed three UCG tests at the Hoe Creek site near Gillette, Wyoming, during the period 1975 to 1979. Five small field experiments, the large-block tests, were completed from 1981 to 1982 at the exposed coal face in the WIDCO coal mine near Centralia, Washington. A larger test at the same location, the partial-seam CRIP test, was completed during fiscal year 1984. In conjunction with the DOE and an industrial group lead by the Gas Research Institute, we have prepared a preliminary design for a large-scale test at the WIDCO site. The planned test features dual injection and production wells, module interaction, and consumption of 20,000 tons of coal during a hundred-day steam-oxygen gasification. During fiscal year 1984, we documented the large-block excavations. The cavities were elongated, the cavity cross sections were elliptical, and the cavities contained ash and slag at the bottom, char and dried coal above that, and a void at the top. The results from the large-block tests provided enough data to allow us to construct a composite model, CAVSM. Preliminary results from the model agree well with the product-gas chemistry and cavity shape observed in the large-block tests. Other models and techniques developed during the year include a transient, moving-front code, a two-dimensional, reactive-flow code using the method of lines, and a wall-recession-rate model. In addition, we measured the rate of methane decomposition in the hot char bed and developed an engineering rate expression to estimate the magnitude of the methane-decomposition reaction. 16 refs., 30 figs., 1 tab.

  14. Low-rank coal research under the UND/DOE cooperative agreement. Quarterly technical progress report, April 1983-June 1983

    SciTech Connect (OSTI)

    Wiltsee, Jr., G. A.

    1983-01-01T23:59:59.000Z

    Progress reports are presented for the following tasks: (1) gasification wastewater treatment and reuse; (2) fine coal cleaning; (3) coal-water slurry preparation; (4) low-rank coal liquefaction; (5) combined flue gas cleanup/simultaneous SO/sub x/-NO/sub x/ control; (6) particulate control and hydrocarbons and trace element emissions from low-rank coals; (7) waste characterization; (8) combustion research and ash fowling; (9) fluidized-bed combustion of low-rank coals; (10) ash and slag characterization; (11) organic structure of coal; (12) distribution of inorganics in low-rank coals; (13) physical properties and moisture of low-rank coals; (14) supercritical solvent extraction; and (15) pyrolysis and devolatilization.

  15. Coal-firing sulfur coal with refuse derived fuels. Technical progress report {number_sign}7, [April--June 1996

    SciTech Connect (OSTI)

    Pan, Wei-Ping, Riley, J.T.; Lloyd, W.G.

    1996-05-31T23:59:59.000Z

    The objectives for this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the organic compounds tentatively identified as combustion products in the previous report were confirmed by comparing retention times with pure samples. Secondly, a reduced amount of unburned carbon in the fly ash and an oxygen concentration at about 3--6% in the flue gases were achieved by the addition of removable heat exchange tubes in the AFBC system.

  16. Synfuels from fusion: using the tandem mirror reactor and a thermochemical cycle to produce hydrogen

    SciTech Connect (OSTI)

    Werner, R.W. (ed.)

    1982-11-01T23:59:59.000Z

    This study is concerned with the following area: (1) the tandem mirror reactor and its physics; (2) energy balance; (3) the lithium oxide canister blanket system; (4) high-temperature blanket; (5) energy transport system-reactor to process; (6) thermochemical hydrogen processes; (7) interfacing the GA cycle; (8) matching power and temperature demands; (9) preliminary cost estimates; (10) synfuels beyond hydrogen; and (11) thermodynamics of the H/sub 2/SO/sub 4/-H/sub 2/O system. (MOW)

  17. Surface Properties of Photo-Oxidized Bituminous Coals: Final report

    SciTech Connect (OSTI)

    NONE

    1998-09-01T23:59:59.000Z

    Natural weathering has a detrimental effect on the hydrophobic nature of coal, which in turn can influence clean-coal recovery during flotation. Few techniques are available that can establish the quality of coal surfaces and that have a short analysis time to provide input for process control. Luminescence emissions which can be quantified with an optical microscope and photometer system, are measurably influenced by degree of weathering as well as by mild storage deterioration. In addition, it has been shown that when vitrinite is irradiated with a relatively high intensity flux of violet- or ultraviolet- light in the presence of air, photo-oxidation of the surface occurs. The combination of measuring the change in luminescence emission intensity with degree of surface oxidation provided the impetus for the current investigation. The principal aim of this research was to determine whether clear correlations could be established among surface oxygen functionality, hydrophobicity induced by photo-oxidation, and measurements of luminescence intensity and alteration. If successful, the project would result in quantitative luminescence techniques based on optical microscopy that would provide a measure of the changes in surface properties as a function of oxidation and relate them to coal cleanability. Two analytical techniques were designed to achieve these goals. Polished surfaces of vitrain bands or a narrow size fraction of powdered vitrain concentrates were photo-oxidized using violet or ultraviolet light fluxes and then changes in surface properties and chemistry were measured using a variety of near-surface analytical techniques. Results from this investigation demonstrate that quantitative luminescence intensity measurements can be performed on fracture surfaces of bituminous rank coals (vitrains) and that the data obtained do reveal significant variations depending upon the level of surface oxidation. Photo-oxidation induced by violet or ultraviolet light fluxes does result in a progressive and significant increase in the amount of near-surface oxygen concentration at about the same level regardless of bituminous coal rank. These incremental changes in oxygen concentration appear to lower the hydrophobicity as shown by contact angle measurements on polished surfaces. Although this influence diminished as coal rank increased, the level of oxygen uptake was about the same, suggesting that the type of oxygen functionality formed during oxidation may be of great importance in modifying surface hydrophobicity. Changes in functional-group chemistry, measured by a variety of near-surface techniques, showed a general increase in the concentration of carbonyl-containing groups while those of CH{sub 2} groups decreased. All of these observations follow the trends observed in previous investigations of naturally weathered coals. The photo-oxidation technique also resulted in the development of phenolic, ester and anhydride moieties instead of the expected emplacement of carboxylic acid groups which are normally associated with naturally weathered coals. The importance of this observation is that esters and anhydrides would result in a more hydrophobic surface in comparison to the more hydrophilic surface resulting from acid functionality. This observation is consistent with the results of film flotation of UV-irradiated powdered vitrain in which floatability was generally observed to increase with increasing photo- oxidation.

  18. Geochemistry of a reclaimed coal slurry impoundment. Technical report, 1 March--31 May 1994

    SciTech Connect (OSTI)

    Dreher, G.B.; Roy, W.R.; Steele, J.D.; Heidari, M. [Illinois State Geological Survey, Champaign, IL (United States)

    1994-09-01T23:59:59.000Z

    The highly alkaline residue from the fluidized-bed combustion (FBC) of coal may be an environmentally acceptable material for use in neutralizing acid produced by the oxidation of pyrite in coal slurry solids (CSS). Previous research indicated that FBC residues in mixtures with pyrite-rich CSS neutralized the acid produced by or attenuated the oxidation of pyrite in CSS. The intent in this research was to collect cores of unconsolidated material and sample pore gases from a reclaimed coal slurry impoundment. The gas composition data would provide background data for the development of a predictive computer model of the generation and migration of acid in a reclaimed coal slurry impoundment. Cores of coal slurry were collected on May 16--18, 1994 from four holes in a reclaimed coal slurry impoundment. There was no unsaturated zone in the coal, so no gas samples can be collected from that zone. The authors installed three samplers in one hole. Two of the samplers are in the saturated zone (in the coal) and the third one might be in the unsaturated zone, but in the soil cover above the coal particles. They plan to collect samples in about mid-June. The water and solids from the cores are being separated for chemical analysis. The computer model for the oxidation of pyrite at near-neutral conditions is being developed. The first portion of code, the calculation of thermodynamic equilibrium without consideration of ionic strength, has been written. The methods of Morel and Hering (1993) and Westall (1986) are the basis for the model, however, the model does not follow the matrix solution used by them. Rather, an algebraic solution is used. A matrix similar to the one reported last quarter was used to formulate mass balance and material balance equations.

  19. Encoal mild coal gasification project: Encoal project final report, July 1, 1997--July 31, 1997

    SciTech Connect (OSTI)

    NONE

    1997-07-01T23:59:59.000Z

    This document is the summative report on the ENCOAL Mild Coal Gasification Project. It covers the time period from September 17, 1990, the approval date of the Cooperative Agreement between ENCOAL and the US Department of Energy (DOE), to July 17, 1997, the formal end of DOE participation in the Project. The Cooperative Agreement was the result of an application by ENCOAL to the DOE soliciting joint funding under Round III of the Clean Coal Technology Program. By June 1992, the ENCOAL Plant had been built, commissioned and started up, and in October 1994, ENCOAL was granted a two-year extension, carrying the project through to September 17, 1996. No-cost extensions have moved the Cooperative Agreement end date to July 17, 1997 to allow for completion of final reporting requirements. At its inception, ENCOAL was a subsidiary of Shell Mining Company. In November 1992, Shell Mining Company changed ownership, becoming a subsidiary of Zeigler Coal Holding Company (Zeigler) of Fairview Heights, Illinois. Renamed successively as SMC Mining Company and then Bluegrass Coal Development Company, it remained the parent entity for ENCOAL, which has operated a 1,000-ton/day mild coal gasification demonstration plant near Gillette, Wyoming for nearly 5 years. ENCOAL operates at the Buckskin Mine owned by Triton Coal Company (Triton), another Zeigler subsidiary.

  20. Geochemistry of a reclaimed coal slurry impoundment. [Quarterly] technical report, September 1, 1993--November 30, 1993

    SciTech Connect (OSTI)

    Dreher, G.B.; Roy, W.R.; Steele, J.D.; Heidari, M.

    1993-12-31T23:59:59.000Z

    The highly alkaline residue from the fluidized-bed combustion (FBC) of coal may be an environmentally acceptable material for use in neutralizing acid produced by the oxidation of pyrite in coal slurry solids (CSS). Previous research indicated that FBC residues in mixtures with pyrite-rich CSS neutralized the acid produced by or attenuated the oxidation of pyrite in CSS. In the present research we intend to collect cores of unconsolidated material and sample pore gases from a reclaimed coal slurry impoundment. The data gathered will provide background information necessary for the development of a predictive computer model of the generation and migration of acid in a reclaimed coal slurry impoundment. A conceptual model for the oxidation of pyrite at near-neutral conditions is being developed. This report includes our first approximation of the model. The model is subject to change.

  1. Water assessment report: Section 13 (c); Great Plains gasification project, Mercer County, ND

    SciTech Connect (OSTI)

    None

    1980-12-01T23:59:59.000Z

    The Water Resources Council is completing a water assessment of synfuels development in the Upper Missouri River Basin. This is being done under Section 13(a) of the Federal Nonnuclear Energy Research and Development Act. The assessment area includes the coal deposits in the Mercer County project site. Levels of North Dakota coal gasification development that are several times the production level of the Great Plains gasification project are being examined. This report assesses: (1) the availability of adequate water supplies to meet the water requirements of the project, supporting activities, and other development induced by the project; and (2) the changes in the water resources that will result from the project. Findings of the 13(a) assessment show that water supplies are physically available within the mainstem of the Missouri River in North Dakota to supply the requirements of the gasification facilities and the supporting activities - mining and reclamation, electricity, and project-induced population increases.

  2. MHD coal combustor technology. Final report, phase II

    SciTech Connect (OSTI)

    Not Available

    1980-09-01T23:59:59.000Z

    The design, performance, and testing of a 20-MW coal combustor for scaleup to 50 MW for use in an MHD generator are described. The design incorporates the following key features: (1) a two-stage combustor with an intermediate slag separator to remove slag at a low temperture, thus minimizing enthalpy losses required for heating and vaporizing the slag; (2) a first-stage pentad (four air streams impinging on one coal stream) injector design with demonstrated efficient mixing, promoting high carbon burnout; (3) a two-section first-stage combustion chamber; the first stage using a thin slag-protected refractory layer and the second section using a thick refractory layer, both to minimize heat losses; (4) a refractory lining in the slag separator to minimize heat losses; (5) a second-stage combustor, which provided both de-swirl of the combustion products exiting from the slag separator and simple mixing of the vitiated secondary air and seed; (6) a dense-phase coal feed system to minimize cold carrier gas entering the first-stage combustors; (7) a dry seed injection system using pulverized K/sub 2/CO/sub 3/ with a 1% amorphous, fumed silicon dioxide additive to enhance flowability, resulting in rapid vaporization and ionization and ensuring maximum performance; and (8) a performance evaluation module (PEM) of rugged design based on an existing, successfully-fired unit. (WHK)

  3. Coal Industry Annual 1995

    SciTech Connect (OSTI)

    NONE

    1996-10-01T23:59:59.000Z

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  4. Coal industry annual 1996

    SciTech Connect (OSTI)

    NONE

    1997-11-01T23:59:59.000Z

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  5. Computed tomography of coals. Quarterly technical progress report No. 1, August 16, 1982-November 28, 1982

    SciTech Connect (OSTI)

    Maylotte, D. H.; Kosky, P. G.; Spiro, C. L.; Lamby, E. J.

    1982-01-01T23:59:59.000Z

    The purpose of this contract is to examine the utility and advantages of x-ray computed tomography (CT) for investigating the structure within coal and the changes that occur in these structures during such processes as combustion and gasification. The CT technique is noninvasive and nondestructive. It can produce interior views of the coal and, with a data acquisition time of ca 9 seconds, can be used for following many coal processes in real time. This is the first in-depth study of the application of the x-ray tomography technique to the problems in coal utilization, and consequently, considerable time will be spent in the early stages of this contract in examining CT pictures of coal and relating them to more conventional petrographic and mineral analyses. This phase of the work is being undertaken in Task 1 of the contract and is reported for this period. Building on this foundation, the succeeding tasks will follow changes in the coal structure during reaction. The first series of CT experiments is scheduled to take place on December 11-13, 1982, at the General Electric Company, Medical Systems Operation, Milwaukee, Wisconsin. 4 figures, 1 table.

  6. Exploratory research on solvent refined coal liquefaction. Annual technical progress report, January 1-December 31, 1979

    SciTech Connect (OSTI)

    None

    1980-09-01T23:59:59.000Z

    This report summarizes the progress of the Exploratory Research on Solvent Refined Coal Liquefaction project by The Pittsburg and Midway Coal Mining Co.'s Merriam Laboratory during 1979. In a series of experiments with varying feed gas composition, low levels (5 to 10 mole %) of carbon monoxide had little effect on the SRC II processing of Pittsburgh Seam coal (Powhatan No. 5 Mine) while higher levels (20 to 40 mole %) resulted in a general degradation of operability and reduced oil yields. Addition of finely divided (approx. 1 ..mu..m) pyrite to the reactive Powhatan coal had little effect on oil yields although the molecular weight of the distillation residue was apparently decreased. When finely divided pyrite and magnetite were added to the less reactive coals from the Loveridge and Blacksville No. 1 Mines (also Pittsburgh Seam), however, substantial increases in oil yields and product quality were obtained. In a comparison of upflow and downflow dissolver configurations with Powhatan coal in the SRC II mode, there was no difference in yields or product quality. A study characterizing specific reactors revealed a significantly higher conversion in the SRC I mode with a reactor approximating plug flow conditions compared to a completely backmixed reactor. In the SRC II mode there was only a slightly higher oil yield with the plug flow reactor.

  7. LLNL Underground-Coal-Gasification Project. Quarterly progress report, July-September 1981

    SciTech Connect (OSTI)

    Stephens, D.R.; Clements, W. (eds.) [eds.

    1981-11-09T23:59:59.000Z

    We have continued our laboratory studies of forward gasification in small blocks of coal mounted in 55-gal drums. A steam/oxygen mixture is fed into a small hole drilled longitudinally through the center of the block, the coal is ignited near the inlet and burns toward the outlet, and the product gases come off at the outlet. Various diagnostic measurements are made during the course of the burn, and afterward the coal block is split open so that the cavity can be examined. Development work continues on our mathematical model for the small coal block experiments. Preparations for the large block experiments at a coal outcrop in the Tono Basin of Washington State have required steadily increasing effort with the approach of the scheduled starting time for the experiments (Fall 1981). Also in preparation is the deep gasification experiment, Tono 1, planned for another site in the Tono Basin after the large block experiments have been completed. Wrap-up work continues on our previous gasification experiments in Wyoming. Results of the postburn core-drilling program Hoe Creek 3 are presented here. Since 1976 the Soviets have been granted four US patents on various aspects of the underground coal gasification process. These patents are described here, and techniques of special interest are noted. Finally, we include ten abstracts of pertinent LLNL reports and papers completed during the quarter.

  8. Study of the properties of mine waste in the midwestern coal fields. Phase I report

    SciTech Connect (OSTI)

    None

    1980-07-04T23:59:59.000Z

    In an effort to assist the coal industry in complying with the applicable regulations, to design safe and environmentally acceptable disposal systems, and to encourage secondary use of coal mine waste, the US Department of Energy has initiated research programs to develop coal mine waste disposal and use technology. This study of the properties of mine wastes in the Midwestern coal fields has been limited to the waste materials obtained from underground coal mines and preparation plants attached to both underground and surface mines. The program has been divided into two phases. In Phase I, the 20 most important properties relevant to safe disposal, reclamation, underground disposal, and secondary uses have been identified. An inventory of the significant waste disposal sites in the Midwestern coal fields has been prepared. The site locations have been plotted on USGS maps. Estimates of coal production and coal mine waste production during the next 2 decades have been prepared and are presented in this report. Also, all available information obtained from a search of existing literature on physical and chemical properties, including analysis results of the general runoff from the refuse disposal areas, has been collected and is presented. In order to fill the gaps in information, 20 sites have been identified for drilling and sampling to determine the various physical and chemical properties. They have been selected on the basis of the distribution and quantity of waste at the existing locations (both abandoned and active), the future trends in production and likely locations of waste disposal areas, their geographical and geological distribution, and ease of accessibility for drilling and sampling.

  9. Coal combustion science: Task 1, Coal char combustion: Task 2, Fate of mineral matter. Quarterly progress report, July--September 1993

    SciTech Connect (OSTI)

    Hardesty, D.R. [ed.; Hurt, R.H.; Davis, K.A.; Baxter, L.L.

    1994-07-01T23:59:59.000Z

    Progress reports are presented for the following tasks: (1) kinetics and mechanisms of pulverized coal char combustion and (2) fate of inorganic material during coal combustion. The objective of Task 1 is to characterize the combustion behavior of selected US coals under conditions relevant to industrial pulverized coal-fired furnaces. In Sandia`s Coal Combustion Laboratory (CCL), optical techniques are used to obtain high-resolution images of individual burning coal char particles and to measure, in situ, their temperatures, sizes, and velocities. Detailed models of combustion transport processes are then used to determine kinetic parameters describing the combustion behavior as a function of coal type and combustion environment. Partially reacted char particles are also sampled and characterized with advanced materials diagnostics to understand the critical physical and chemical transformations that influence reaction rates and burnout times. The ultimate goal of the task is the establishment of a data base of the high temperature reactivities of chars from strategic US coals, from which important trends may be identified and predictive capabilities developed. The overall objectives for task 2 are: (1) to complete experimental and theoretical investigation of ash release mechanisms; (2) to complete experimental work on char fragmentation; (3) to establish the extent of coal (as opposed to char) fragmentation as a function of coal type and particle size; (4) to develop diagnostic capabilities for in situ, real-time, qualitative indications of surface species composition during ash deposition, with work continuing into FY94; (5) to develop diagnostic capabilities for in situ, real-time qualitative detection of inorganic vapor concentrations; and (6) to conduct a literature survey on the current state of understanding of ash deposition, with work continuing into FY94.

  10. U.S. Energy Information Administration | Annual Coal Report 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSSCoal Production and Number of Mines byCoal

  11. U.S. Energy Information Administration | Annual Coal Report 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSSCoal Production and Number of Mines Coal Mining

  12. U.S. Energy Information Administration | Annual Coal Report 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSSCoal Production and Number of Mines Coal Mining

  13. U.S. Energy Information Administration | Annual Coal Report 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSSCoal Production and Number of Mines Coal Mining

  14. U.S. Energy Information Administration | Annual Coal Report 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSSCoal Production and Number of Mines Coal Mining

  15. U.S. Energy Information Administration | Annual Coal Report 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSSCoal Production and Number of Mines Coal

  16. U.S. Energy Information Administration | Annual Coal Report 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSSCoal Production and Number of Mines Coal0.

  17. U.S. Energy Information Administration | Annual Coal Report 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSSCoal Production and Number of Mines Coal0.1.

  18. U.S. Energy Information Administration | Annual Coal Report 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2,EHSSCoal Production and Number of MinesCoal

  19. High performance materials in coal conversion utilization. Technical progress report, April 1, 1995--June 30, 1995

    SciTech Connect (OSTI)

    NONE

    1995-07-01T23:59:59.000Z

    This is the seventh quarterly report on a three year grant regarding {open_quotes}High Performance Materials in Coal Conversion Utilization.{close_quotes} The grant is for a joint university/industry effort under the US Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. UTSI has completed the planned laboratory exposure tests involving pulverized coal slag on the production of Lanxide DIMOX{trademark} ceramic composite material. In addition, the strength testing (at temperature) of C-ring sections of the production composite is complete and the analysis of the data is reported in a thesis which was submitted toward a M.S. degree.

  20. Advanced coal-fueled gas turbine systems, Volume 1: Annual technical progress report

    SciTech Connect (OSTI)

    Not Available

    1988-07-01T23:59:59.000Z

    This is the first annual technical progress report for The Advanced Coal-Fueled Gas Turbine Systems Program. Two semi-annual technical progress reports were previously issued. This program was initially by the Department of Energy as an R D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular three-stage slagging combustor concept. Fuel-rich conditions inhibit NO/sub x/ formation from fuel nitrogen in the first stage; coal ash and sulfur is subsequently removed from the combustion gases by an impact separator in the second stage. Final oxidation of the fuel-rich gases and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage. 27 figs., 15 tabs.

  1. Coal industry annual 1997

    SciTech Connect (OSTI)

    NONE

    1998-12-01T23:59:59.000Z

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  2. Rawlins UCG (underground coal gasification) Demonstration Project site characterization report

    SciTech Connect (OSTI)

    Not Available

    1989-04-01T23:59:59.000Z

    The United States Department of Energy and Energy International, Inc. have entered into a Cooperative Agreement to conduct a cost-shared UCG field test demonstrating the operation of commercial scale Underground Coal Gasification (UCG) on steeply dipping bed modules to provide synthesis gas for a small scale commercial ammonia plant. The field test and the commercial ammonia plant will be located at the North Knobs site near Rawlins, Wyoming. During this demonstration test, two or more UCG modules will be operated simultaneously until one module is completely consumed and an additional module is brought on line. During this period, the average coal gasification rate will be between 500 and 1200 tons per day. A portion of the raw UCG product gas will be cleaned and converted into a synthesis gas, which will be used as feedstock to a 400--500 ton per day ammonia plant. The UCG facility will continue to operate subsequent to the test demonstration to provide feedstock for the commercial plant. The objective of the hydrologic site characterization program is to provide an accurate representation of the hydrologic environment within the area to be gasified. This information will aid in the placement and operation of the process wells in relation to the ground water source. 21 refs., 14 figs., 6 tabs.

  3. Advanced Coal-Fueled Gas Turbine Program. Final report

    SciTech Connect (OSTI)

    Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

    1989-02-01T23:59:59.000Z

    The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

  4. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly report, April 1--June 30, 1997

    SciTech Connect (OSTI)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1997-12-31T23:59:59.000Z

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2 t/hr process development unit (PDU). Accomplishments during the quarter are described on the following tasks and subtasks: Development of near-term applications (engineering development and dewatering studies); Engineering development of selective agglomeration (bench-scale testing and process scale-up); PDU and advanced column flotation module (coal selection and procurement and advanced flotation topical report); Selective agglomeration module (module operation and clean coal production with Hiawatha, Taggart, and Indiana 7 coals); Disposition of the PDU; and Project final report. Plans for next quarter are discussed and agglomeration results of the three tested coals are presented.

  5. ANNUAL REPORT OCTOBER 1, 1979-SEPTEMBER 30, 1980 CHEMISTRY AND MORPHOLOGY OF COAL LIQUEFACTION

    E-Print Network [OSTI]

    Heinemann, Heinz

    2013-01-01T23:59:59.000Z

    AND MORPHOLOGY OF COAL LIQUEFACTION LA , . . ,:;. ~~Microscope Studies of Coal during Hydrogenation Taskspread evenly over the coal grains of this particular area.

  6. Estimating Externalities of Coal Fuel Cycles, Report 3

    SciTech Connect (OSTI)

    Barnthouse, L.W.; Cada, G.F.; Cheng, M.-D.; Easterly, C.E.; Kroodsma, R.L.; Lee, R.; Shriner, D.S.; Tolbert, V.R.; Turner, R.S.

    1994-09-01T23:59:59.000Z

    The agreement between the US DOE and the EC established the specific objectives of the study: (a) to develop a methodological framework that uses existing data and models to quantify the external costs and benefits of energy; (b) to demonstrate the application of the framework to estimate the externalities of the coal, biomass, oil, natural gas, hydro, nuclear, photovoltaic, and wind fuel cycles (by agreement with the EC, the US addressed the first six of these); and (c) to identify major gaps in the availability of information to quantify impacts, damages, benefits, and externalities of fuel cycles; and to suggest priorities for future research. The main consideration in defining these objectives was a desire to have more information about externalities, and a better method for estimating them.

  7. Performance of low-rank coal in atmospheric fluidized bed combustion. Technology transfer report

    SciTech Connect (OSTI)

    Hajicek, D.R.; Zobeck, B.J.; Mann, M.D.; Miller, B.G.; Ellman, R.C.; Benson, S.A.; Goblirsch, G.M.; Cooper, J.L.; Guillory, J.L.; Eklund, A.G.

    1985-10-01T23:59:59.000Z

    This report presents test data generated at GFETC and discusses the implications of this data in regard to the technical and economic feasibility of using low-rank coals in the AFBC. Atmospheric fluidized bed combustion offers a number of potential advantages over conventional pulverized coal combustion due to the intense turbulence in the fluidized bed and long residence times of solids in the bed without a long linear flow path. Advantages of the AFBC include flexibility to handle varying fuels, sulfur capture by limestone, high combustion efficiency, compact combustor size, lower NO/sub x/ emissions, and reduced slagging and fouling problems. Low-rank coals with high alkali-to-sulfur ratios offer a significant additional advantage: the ability to absorb significant sulfur on the alkaline ash. Results verify that AFBC is particularly well suited for the direct combustion of low-rank coals. With combustion temperatures above 1450/sup 0/F at 20% excess air or higher, the combustion efficiencies while burning low-rank coal were found to be above 98%, with efficiencies above 99% for most tests. The CO emissions were very low, typically below 0.05 lb/MMBtu or 50 ppMv. Overall heat transfer coefficients to water-cooled tubes while burning low-rank coals were comparable to those obtained with other fuels in AFBC, or 20 to 60 Btu/h-ft/sup 2/-/sup 0/F. These are considerably higher than those obtained in conventional coal-fired systems which are typically 5 to 15 Btu/h-ft/sup 2/-/sup 0/F. Factors influencing heat transfer included mass velocity, bed particle size, bed temperature, and ash recycle.

  8. Innovative process for concentration of fine particle coal slurries. Technical report, September 1--November 30, 1995

    SciTech Connect (OSTI)

    Rajchel, M. [Williams Technologies, Inc. (United States)]|[Clarke Rajchel Engineering, Arvada, CO (United States); Harnett, D. [Williams Technologies, Inc. (United States); Fonseca, A. [CONSOL, Pittsburgh, PA (United States); Maurer, R. [Destec (United States); Ehrlinger, H.P.

    1995-12-31T23:59:59.000Z

    Williams Technologies, Inc. and Clarke Rajchel Engineering are developing a technology (patent pending) to produce high quality coal water slurries from preparation plant fine coal streams. The WTI/CRE technology uses the novel implementation of high-shear cross-flow separation which replaces and enhances conventional thickening processes by surpassing normally achievable solids loadings. Dilute ultra-fine (minus 100 mesh) solids slurries can be concentrated to greater than 60 weight percent and re-mixed, as required, with de-watered coarser fractions to produce pumpable, heavily loaded coal slurries. The permeate (filtrate) resulting from this process has been demonstrated to be crystal clear and totally free of suspended solids. The primary objective of this project is to demonstrate the WTI/CRE coal slurry production process technology at the pilot scale. The technology will enable Illinois coal producers and users to realize significant coast and environmental benefits both by eliminating fine coal waste disposal problems and producing an IGCC fuel to produce power which meets all foreseeable clean air standards. In addition, testing is also directed at concentrating mine tailings material to produce a tailings paste which can be mine-back-, filled and thus eliminate the need for tailings ponds. This reporting period, September 1, 1995 through November 30, 1995, marked the inception of this project. During this period Task No. 1, Procurement and Set-Up, was completed. The pilot plant apparatus was constructed at the SIU Coal Research Center in Carterville, Illinois. All equipment and feedstock were received at the site.

  9. Hydrogen separation by ceramic membranes in coal gasification. Final report

    SciTech Connect (OSTI)

    Gavalas, G.R.

    1993-08-01T23:59:59.000Z

    The general objective of this project was to develop hydrogen permselective membranes for hydrogen production from coal gas. The project consisted of the following tasks: (i) membrane preparation and characterization, (ii) membrane stability testing, and (iii) analysis and economic evaluation of a membrane-assisted ammonia from coal process. Several oxides (SiO{sub 2}, TiO{sub 2}, Al{sub 2}O{sub 3}, B{sub 2}O{sub 3}) in dense (or nonporous) form were identified to be permselective to hydrogen at elevated temperatures. To obtain reasonable permeance it is necessary that the membrane consists of a thin selective layer of the dense oxide supported on or within the pores of a porous support tube (or plate). Early in the project we chose porous Vycor tubes (5mm ID, 7 mm OD, 40 {Angstrom} mean pore diameter) supplied by Corning Inc. as the membrane support. To form the permselective layer (SiO{sub 2}, TiO{sub 2}, Al{sub 2}O{sub 3}, B{sub 2}O{sub 3}) we employed chemical vapor deposition using the reaction of the chloride (SiCl{sub 4}, etc.) vapor and water vapor at high temperatures. Deposition of the selective layer was carried out in a simple concentric tube reactor comprising the porous support tube surrounded by a wider concentric quartz tube and placed in an electrically heated split tube furnace. In one deposition geometry (the opposing reactants or two-sided geometry) the chloride vapor in nitrogen carrier was passed through the inner tube while the water vapor also in nitrogen carrier was passed in the same direction through the annulus between the two tubes. In the other (two-sided) geometry the chloride-containing stream and the water-containing stream were both passed through the inner tube or both through the annulus.

  10. High performance materials in coal conversion utilization. Technical progress report, October 1, 1995--December 31, 1995

    SciTech Connect (OSTI)

    NONE

    1996-01-01T23:59:59.000Z

    This is the ninth quarterly report on a three year grant regarding {open_quotes}High Performance Materials in Coal Conversion Utilization.{close_quotes} The grant is for a joint university/industry effort under the U.S. Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. UTSI has completed all the initially planned laboratory exposure tests involving pulverized coal slag on the production Lanxide DIMOX{trademark} ceramic composite material. In addition, the strength testing (at temperature) and analysis of C-ring sections of the exposed production composite is complete. The development of a technique to laser coat the material has been the major activity while awaiting an innovatively produced new test sample. This sample will be tested and compared to the production tubes tested at UTSI.

  11. High performance materials in coal conversion utilization. Technical progress report, April 1, 1994--June 30, 1994

    SciTech Connect (OSTI)

    Not Available

    1994-10-01T23:59:59.000Z

    This is the third quarterly report concerning this three year grant on {open_quotes}High Performance Materials in Coal Conversion Utilization.{close_quotes} The grant is for a joint university/industry effort under the US Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. UTSI has completed one third of the planned laboratory exposure tests involving pulverized coal slag on the production of Lanxide DIMOS{sup TM} ceramic composite material. The upgrade of the MTS testing machine is underway and the strength testing (at temperature) of C-ring sections of the composite will begin next quarter.

  12. Predictors of plasticity in bituminous coals. Technical progress report No. 8

    SciTech Connect (OSTI)

    Lloyd, W.G.; Reasoner, J.W.; Hower, J.C.; Yates, L.P.; Clark, C.P.; Davis, E.; Fitzpatrick, A.; Reagles, C.L.; Whitt, J.M.

    1983-09-01T23:59:59.000Z

    The greater part of the present study on predictors of coal fluidity has now been completed, with most of the developed database presented in the preceding Technical Progress Report. The one critical area in which we have fallen behind schedule is that of isothermal fluidity measurements at superatmospheric pressures. During the past quarter we have made several modifications to the experimental high-pressure Gieseler plastometer, and have been able to complete over 60 superatmospheric runs. This work will be completed and analyzed within the period of the 90-day no-cost extension which has been granted. The extra time has permitted completion of additional experiments in solvent extraction. During this period we have also completed characterization of THF extracts by HPLC, and characterization of coals, coal extraction residues and selected extracts by FTIR. 13 references, 25 tables.

  13. TRW Advanced Slagging Coal Combustor Utility Demonstration. Fourth Quarterly progress report, August 1989--October 1989

    SciTech Connect (OSTI)

    Not Available

    1989-12-31T23:59:59.000Z

    The TRW Advanced Slagging Coal Combustor Demonstration Project consists of retrofitting Orange and Rockland (O&R) Utility Corporation`s Lovett Plant Unit No. 3 with four (4) slagging combustors which will allow the gas/ou desip unit to fire 2.5 sulfur coal. The slogging combustor process will provide NO{sub x} and SO{sub x} emissions that meet NSPS and New York State Envirommental Standards. TRW-CBU scope of work includes the engineering, design and supply of the slogging combustors, coal and limestone feed systems and a control system for these components. During this report period, the design activities for all systems progressed to permit the release of specifications and requests for proposals. Award of contracts for long-delivery items and major equipment are being placed to meet the revised program schedule.

  14. High performance materials in coal conversion utilization. Technical progress report, January 1, 1996--March 31, 1996

    SciTech Connect (OSTI)

    NONE

    1996-04-01T23:59:59.000Z

    This is the tenth quarterly report on a three year grant regarding ``High Performance Materials in Coal Conversion Utilization.`` The grant is for a joint university/industry effort under the US Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. The object of this grant is to test, analyze, and improve the heat and coal-slag corrosion resistance of a SiC{sub (p)}/Al{sub 2}O{sub 3} ceramic composite tubular material. The material will be evaluated for its ability to withstand the pressures, temperatures and corrosion attack which would be encountered within a coal-fired high-temperature, high pressure air heater. The evaluation includes strength testing at elevated temperatures of production tubes as well as one tube manufactured with an innovative new technology. The feasibility of several joining and coating techniques will also be investigated. UTSI has completed all the initially planned laboratory exposure tests involving pulverized coal slag on the production Lanxide DIMOX{trademark} ceramic composite material. In addition, the strength testing (at temperature) and analysis of C-ring sections of the exposed production composite is complete. The evaluation of a laser-induced coating to laser coat the material has been the major activity this quarter while awaiting an innovatively produced new DIMOX{trademark} test sample.

  15. High performance materials in coal conversion utilization. Technical progress report, July 1, 1995--September 30, 1995

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    This is the eighth quarterly report on a three year grant regarding ``High Performance Materials in Coal Conversion Utilization.`` The grant is for a joint university/industry effort under the US Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and the University of Pennsylvania and Lanxide Corporation are subcontractors. The object of this grant is to test, analyze, and improve the heat and coal-slag corrosion resistance of a SiC{sub (p)}/Al{sub 2}O{sub 3} ceramic composite tubular material. The material will be evaluated for its ability to withstand the pressures, temperatures and corrosion attack which would be encountered within a coal-fired high-temperature, high pressure air heater. The evaluation includes strength testing at elevated temperatures of production tubes as well as one manufactured with an innovative new technology. The feasibility of several joining and coating techniques are also being investigated. UTSI has completed all the initially planned laboratory exposure tests involving pulverized coal slag on the production Lanxide DIMOX{trademark} ceramic composite material. In addition, the strength testing (at temperature) and analysis of C- ring sections of the exposed production composite are complete.

  16. Advanced coal-fueled gas turbine systems: Subscale combustion testing. Topical report, Task 3.1

    SciTech Connect (OSTI)

    Not Available

    1993-05-01T23:59:59.000Z

    This is the final report on the Subscale Combustor Testing performed at Textron Defense Systems` (TDS) Haverhill Combustion Laboratories for the Advanced Coal-Fueled Gas Turbine System Program of the Westinghouse Electric Corp. This program was initiated by the Department of Energy in 1986 as an R&D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular staged, rich-lean-quench, Toroidal Vortex Slogging Combustor (TVC) concept. Fuel-rich conditions in the first stage inhibit NO{sub x} formation from fuel-bound nitrogen; molten coal ash and sulfated sorbent are removed, tapped and quenched from the combustion gases by inertial separation in the second stage. Final oxidation of the fuel-rich gases, and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage, which is maintained sufficiently lean so that here, too, NO{sub x} formation is inhibited. The primary objective of this work was to verify the feasibility of a direct coal-fueled combustion system for combustion turbine applications. This has been accomplished by the design, fabrication, testing and operation of a subscale development-type coal-fired combustor. Because this was a complete departure from present-day turbine combustors and fuels, it was considered necessary to make a thorough evaluation of this design, and its operation in subscale, before applying it in commercial combustion turbine power systems.

  17. Coal precursors for production of carbon and graphite products. Final report

    SciTech Connect (OSTI)

    Lewis, I.C.; Lewis, R.T.; Mayer, H.K. [Ucar Carbon Co., Inc., Parma, OH (United States)

    1996-04-08T23:59:59.000Z

    The main goal of this program was to demonstrate the utility of coal extracts from the West Virginia University (WVU) extraction process as suitable base raw materials for the carbon products encompassed by the Carbon Products Consortium (CPC) team. These include binder and impregnation pitches, Coke for graphite electrodes, Cokes for anodes and specialty graphite, matrices for C/C composites and raw material for mesophase pitch fibers. Previous work in this program has shown that the WVU coal extraction process coupled with hydrotreatment, does have the potential for achieving this objective. The current effort involved screening and evaluation of extracts produced by the WVU Group and recommending appropriate materials for scaleup for subsequent evaluation by Consortium Team members. The program involved an initial characterization of small-scale extracts using standard analytical methods and mesophase formation studies. This was followed by feedback to the WVU Group and to the CPC partners with recommendation of material for scaleup. Similar analytical and mesophase studies on some of the scaled-up extracts was performed. The activation of the coal extraction residues for the purpose of producing a useful active carbon was investigated. A further task was to fabricate a small graphite artifact using Coke derived from coal extract as the filler and the coal extract itself as a binder. The results of the studies are summarized in this report.

  18. Coal industry annual 1993

    SciTech Connect (OSTI)

    Not Available

    1994-12-06T23:59:59.000Z

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

  19. Combustion characterization of the blend of plant coal and recovered coal fines. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Singh, S. [SS Energy Environmental International, Inc., Rockford, IL (United States); Scaroni, A.; Miller, B. [Pennsylvania State Univ., University Park, PA (United States). Combustion Lab.; Choudhry, V. [Praxis Engineers, Inc., Milpitas, CA (United States)

    1992-08-01T23:59:59.000Z

    The overall objective of this proposed research program is to determine the combustion characteristics of the blend derived from mixing a plant coal and recovered and clean coal fines from the pond. During this study, one plant coal and three blend samples will be prepared and utilized. The blend samples will be of a mixture of 90% plant coal + 10% fines, 85% plant coal + 15% fines, 80% plant coal + 20% fines having particle size distribution of 70% passing through -200 mesh size. These samples` combustion behavior will be examined in two different furnaces at Penn State University, i.e., a down-fired furnace and a drop-tube furnace. The down-fired furnace will be used mainly to measure the emissions and ash deposition study, while the drop tube furnace will be used to determine burning profile, combustion efficiency, etc.

  20. Fossil Energy Program. Progress report for November 1979. [35 Wt % Illinois No. 6 coal with Wilsonville recycle solvent

    SciTech Connect (OSTI)

    Not Available

    1980-01-01T23:59:59.000Z

    This report - the sixty-fourth of a series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion development, materials engineering, a coal equipment test program, an atmospheric fluid bed combustor for cogeneration, engineering studies and technical support, process and program analysis, environmental assessment studies, magnetic beneficiation of dry pulverized coal, technical support to the TVA fluid bed combustion program, coal cogeneration/district heating plant assessment, chemical research and development, and technical support to major liquefaction projects.

  1. Novel nanodispersed coal liquefaction catalysts: Molecular design via microemulsion-based synthesis. Final technical report, October 1990--December 1994

    SciTech Connect (OSTI)

    Osseo-Asare, K.; Boakye, E.; Vittal, M. [and others

    1995-04-01T23:59:59.000Z

    This report described the synthesis of Molybdenum Sulfides in microemulsions by acidification of ammonium tetrathiomolybdate. Molybdenum Sulfides have been shown to be potential coal liquefaction catalysts. The importance of particle size, temperature effects, and coal surface chemistry to impregnation are discussed.

  2. Kinetics of coal conversion to soluble products. Final technical report

    SciTech Connect (OSTI)

    Larsen, J.W.

    1994-04-12T23:59:59.000Z

    The objectives of this work are (1) to measure the kinetics of the conversion of coals to soluble products under model liquefaction conditions using GPS techniques to count the number of bonds broken; (2) to analyze these data using kinetic schemes based on the behavior of crosslinked macromolecular networks. The product was Soxhlet extracted with pyridine until the pyridine solution was clear. A gel permeation chromatogram of the pyridine soluble is shown in Figure 2A. The improved mass sensitive detector system requires only about 500 ng to acquire a chromatogram having fairly good S/N ratio. Apparently, no disturbance is caused by the remaining tetralin and naphthalene formed by dehydrogenation of tetralin. These seriously affect the lower molecular weight region when IR or UV detectors are used. It is a notable advantage of the mass sensitive detector that suitable adjustment of the nebulizer and of the evaporator completely suppressed the contribution of solvent to the chromatogram. The molecular weight distribution of liquefaction product appears to be almost unimodal if the small shoulder at the lower elution volume side is neglected.

  3. The chemical enhancement of the triboelectric separation of coal from pyrite and ash: A novel approach for electrostatic separation of mineral matter from coal. Final report

    SciTech Connect (OSTI)

    Gustafson, R.M.; DiMare, S.; Sabatini, J.

    1992-02-01T23:59:59.000Z

    Arthur D. Little, Inc., under contract to the US DOE Pittsburgh Energy Technology Center, has developed a triboelectric separation device for coal beneficiation, that employs an entrained-flow, rotating-cylinder concept. The described apparatus has been used to test the efficacy of chemical pretreatment and in-situ treatment of coal on separation efficiency. Coal particle entrainment is achieved with gaseous carbon dioxide and particle collection is accomplished by an electrostatic plate separator. The triboelectric separation device incorporates instrumentation for the direct measurement of charge in the dilute-phase particle stream. Some of the pretreatment materials investigated under this project to modify the surface charging characteristics of the coal included oleic acid, sodium oleate, quinoline and dicyclohexylamine. Ammonia and sulfur dioxide at a concentration up to 1000 ppM was used for in-situ treatment of the coal, with carbon dioxide as the carrier/inerting gas. Nitrogen was used earlier in the test program as the carrier/inerting gas for the coal, but a severe arcing problem was encountered in the electrostatic collector with nitrogen as the carrier gas. This problem did not occur when carbon dioxide was used. The report covers the chemical treatment employed, and summarizes and interprets the results achieved. In addition, an economic analysis of a full scale system based on this concept is presented.

  4. KVB coal desulfurization process development. Quarterly technical progress report, October-December 1980

    SciTech Connect (OSTI)

    Not Available

    1980-01-01T23:59:59.000Z

    This is the second technical progress report for the KVB Coal Desulfurization Process Development. The project is a joint venture between Research-Cottrell, Inc. and the College of Engineering of Rutgers University. The process involves oxidation of the sulfur in coal (both organic and pyritic) to soluble forms using nitrogen oxide gas mixtures and subsequent extractive removal. Key features of the process are mild reaction conditions and the use of a regenerable oxidant. Construction of a bench scale oxidation reactor system was completed and a short experimental program was carried out using Illinois No. 6 coal. An investigation of extraction reagents was also conducted. The emphasis to date has been on development and demonstration of procedures rather than on data generation. However preliminary data do indicate reaction of both organic and pyritic sulfur. Preliminary coal characterization work using x-ray fluorescence is also reported. A brief discussion of project plans in the areas of process modelling and commercial evaluation is also given.

  5. Oxidation of coal and coal pyrite mechanisms and influence on surface characteristics. Technical progress report, September 30, 1992

    SciTech Connect (OSTI)

    Doyle, F.M.

    1992-12-31T23:59:59.000Z

    The objective of this research is to develop a mechanistic understanding of the oxidation of coal and coal pyrite, and to correlate the intrinsic physical and chemical properties of these minerals, along with changes resulting from oxidation, with those surface properties that influence the behavior in physical cleaning processes. The results will provide fundamental insight into oxidation, in terms of the bulk and surface chemistry, the microstructure, and the semiconductor properties of the pyrite. During the eighth quarter, wet chemical and dry oxidation tests were done on Upper Freeport coal from the Troutville {number_sign}2 Mine, Clearfield County, Pennsylvania. In addition electrochemical experiments were done on electrodes prepared from Upper Freeport coal pyrite and Pittsburgh coal pyrite samples provided by the US Bureau of Mines, Pittsburgh Research Center, Pennsylvania.

  6. International perspectives on coal preparation

    SciTech Connect (OSTI)

    NONE

    1997-12-31T23:59:59.000Z

    The report consists of the vugraphs from the presentations which covered the following topics: Summaries of the US Department of Energy`s coal preparation research programs; Preparation trends in Russia; South African coal preparation developments; Trends in hard coal preparation in Germany; Application of coal preparation technology to oil sands extraction; Developments in coal preparation in China; and Coal preparation in Australia.

  7. The development of coal-based technologies for Department of Defense facilities. Volume 1, Technical report. Semiannual technical progress report, September 28, 1994--March 27, 1995

    SciTech Connect (OSTI)

    Miller, B.G.; Bartley, D.A.; Hatcher, P. [Pennsylvania State Univ., University Park, PA (United States). Energy and Fuels Research Center] [and others

    1996-10-15T23:59:59.000Z

    This program is being conducted as a cooperative agreement between the Consortium for Coal Water Mixture Technology and the U.S. Department of Energy. Activities this reporting period are summarized by phase. Phase I is nearly completed. During this reporting period, coal beneficiation/preparation studies, engineering designs and economics for retrofitting the Crane, Indiana boiler to fire coal-based fuels, and a 1,000-hour demonstration of dry, micronized coal were completed. In addition, a demonstration-scale micronized-coal water mixture (MCWM) preparation circuit was constructed and a 1,000-hour demonstration firing MCWM began. Work in Phase II focused on emissions reductions, coal beneficiation/preparation studies, and economic analyses of coal use. Emissions reductions investigations involved literature surveys of NO{sub x}, SO{sub 2}, trace metals, volatile organic compounds, and fine particulate matter capture. In addition, vendors and engineering firms were contacted to identify the appropriate emissions technologies for the installation of commercial NO{sub x} and SO{sub 2} removal systems on the demonstration boiler. Information from the literature surveys and engineering firms will be used to identify, design, and install a control system(s). Work continued on the refinement and optimization of coal grinding and MCWM preparation procedures, and on the development of advanced processes for beneficiating high ash, high sulfur coals. Work also continued on determining the basic cost estimation of boiler retrofits, and evaluating environmental, regulatory, and regional economic impacts. In addition, the feasibility of technology adoption, and the public`s perception of the benefits and costs of coal usage was studied. A coal market analysis was completed. Work in Phase III focused on coal preparation studies, emissions reductions and economic analyses of coal use.

  8. Characteristics of American coals in relation to their conversion into clean-energy fuels. Final report. [1150 samples of US coals

    SciTech Connect (OSTI)

    Spackman, W.; Davis, A.; Walker, P.L.; Lovell, H.L.; Vastola, F.J.; Given, P.H.; Suhr, N.H.; Jenkins, R.G.

    1982-06-01T23:59:59.000Z

    To further characterize the Nation's coals, the Penn State Coal Sample Bank and Data Base were expanded to include a total of 1150 coal samples. The Sample Bank includes full-seam channel samples as well as samples of lithotypes, seam benches, and sub-seam sections. To the extent feasible and appropriate basic compositional data were generated for each sample and validated and computerized. These data include: proximate analysis, ultimate analysis, sulfur forms analysis, calorific value, maceral analysis, vitrinite reflectance analysis, ash fusion analysis, free-swelling index determination, Gray-King coke type determination, Hardgrove grindability determination, Vicker's microhardness determination, major and minor element analysis, trace element analysis, and mineral species analysis. During the contract period more than 5000 samples were prepared and distributed. A theoretical and experimental study of the pyrolysis of coal has been completed. The reactivity of chars, produced from all ranks of American coals, has been studied with regard to reactivity to air, CO/sub 2/, H/sub 2/ and steam. Another area research has concerned the catalytic effect of minerals and various cations on the gasification processes. Combustion of chars, low volatile fuels, coal-oil-water-air emulsions and other subjects of research are reported here. The products of this research can be found in 23 DOE Technical Research Reports and 49 published papers. As another mechanism of technology transfer, the results have been conveyed via more than 70 papers presented at a variety of scientific meetings. References to all of these are contained in this report.

  9. High performance materials in coal conversion utilization. Technical progress report, October 1, 1993--December 31, 1993

    SciTech Connect (OSTI)

    Not Available

    1994-02-01T23:59:59.000Z

    This is the first quarterly report for this three year grant on {open_quotes}High Performance Materials in Coal Conversion Utilization.{close_quotes} The grant is a joint university/industry effort under the Department of Energy (DOE) University Coal Research program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. It was initially planned to field test ceramic composite tubes furnished by Lanxide Corporation in conjunction with an on-going DOE magnetohydrodynamic (MHD) test series at UTSI. The MHD test program was curtailed due to funding limitations near the beginning of the grant so that the field test portion is now greatly reduced. Bench scale testing will replace most of the field testing. This development should have minimal effect on this research since there is now little interest in the affects of the potassium seeded MHD coal ash on heat exchanger surfaces. The objective is to test and analyze the heat and corrosion resistance of a SiC(p)/Al{sub 2}O{sub 3} ceramic composite tubular material. The material will be evaluated for its ability to withstand the pressures, temperatures and corrosion attack which will be encountered within a coal-fired high-temperature, high-pressure air heater. The evaluation will include strength testing at elevated temperatures.

  10. Coal-fired high performance power generating system. Quarterly progress report, January 1--March 31, 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-31T23:59:59.000Z

    This report covers work carried out under Task 2, Concept Definition and Analysis, and Task 3, Preliminary R and D, under contract DE-AC22-92PC91155, ``Engineering Development of a Coal Fired High Performance Power Generation System`` between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of: > 47% thermal efficiency; NO{sub x}, SO{sub x} and Particulates {le} 25% NSPS; cost {ge} 65% of heat input; and all solid wastes benign. In order to achieve these goals our team has outlined a research plan based on an optimized analysis of a 250 MW{sub e} combined cycle system applicable to both frame type and aeroderivative gas turbines. Under the constraints of the cycle analysis we have designed a high temperature advanced furnace (FHTAF) which integrates several combustor and air heater designs with appropriate ash management procedures. The cycle optimization effort has brought about several revisions to the system configuration resulting from: (1) the use of Illinois No. 6 coal instead of Utah Blind Canyon; (2) the use of coal rather than methane as a reburn fuel; (3) reducing radiant section outlet temperatures to 1700F (down from 1800F); and (4) the need to use higher performance (higher cost) steam cycles to offset losses introduced as more realistic operating and construction constraints are identified.

  11. Molecular catalytic coal liquid conversion. Quarterly status report, April 1995--June 1995

    SciTech Connect (OSTI)

    Stock, L.M.

    1995-06-30T23:59:59.000Z

    In this Quarter, the research was focused continually on the two general tasks: Task 1, molecular organometallic catalysts for hydrogenation and Task 2, organic base catalysts for arene hydrogenation and the hydrotreating of the coal liquids. With regards to Task 1, the [1,5-HDRhCl]{sub 2}/buffer catalyst system was investigated to improve its performance, especially catalyst`s stability. Although the addition of a phase transfer agent will usually reduce the catalyst`s activity as described in the last report, a small amount of some surfactant molecules can improve the catalyst`s stability without apparently affecting the catalytic activity. Task 2 was continually focused on the hydrotreating of coal liquid (VSOH) catalyzed by Catalyst 2 and Catalyst 5. The dependence of temperature and hydrogenation pressure on the hydrotreating of VSOH was investigated systematically. The coal liquid hydrotreated at 300{degrees}C has an H/C ratio of 1.53 while that treated at 100{degrees}C has an H/C ratio of only 1.43. We found that 1000 psig of hydrogen pressure was needed for the reaction to proceed completely. Other catalytic alkali metal bis(trimethylsilyl)amides were also investigated to hydrotreat the same coal liquid. Potassium bis(trimethylsilyl)amide was more active than lithium bis(trimethylsilyl)amide and sodium bis(trimethylsilyl)amide.

  12. Simulated coal gas MCFC power plant system verification. Final report

    SciTech Connect (OSTI)

    NONE

    1998-07-30T23:59:59.000Z

    The objective of the main project is to identify the current developmental status of MCFC systems and address those technical issues that need to be resolved to move the technology from its current status to the demonstration stage in the shortest possible time. The specific objectives are separated into five major tasks as follows: Stack research; Power plant development; Test facilities development; Manufacturing facilities development; and Commercialization. This Final Report discusses the M-C power Corporation effort which is part of a general program for the development of commercial MCFC systems. This final report covers the entire subject of the Unocal 250-cell stack. Certain project activities have been funded by organizations other than DOE and are included in this report to provide a comprehensive overview of the work accomplished.

  13. Solvent refined coal (SRC) process. Annual technical progress report, January 1979-December 1979

    SciTech Connect (OSTI)

    Not Available

    1980-11-01T23:59:59.000Z

    A set of statistically designed experiments was used to study the effects of several important operating variables on coal liquefaction product yield structures. These studies used a Continuous Stirred-Tank Reactor to provide a hydrodynamically well-defined system from which kinetic data could be extracted. An analysis of the data shows that product yield structures can be adequately represented by a correlative model. It was shown that second-order effects (interaction and squared terms) are necessary to provide a good model fit of the data throughout the range studied. Three reports were issued covering the SRC-II database and yields as functions of operating variables. The results agree well with the generally-held concepts of the SRC reaction process, i.e., liquid phase hydrogenolysis of liquid coal which is time-dependent, thermally activated, catalyzed by recycle ash, and reaction rate-controlled. Four reports were issued summarizing the comprehensive SRC reactor thermal response models and reporting the results of several studies made with the models. Analytical equipment for measuring SRC off-gas composition and simulated distillation of coal liquids and appropriate procedures have been established.

  14. Solvent refined coal (SRC) process. Quarterly technical progress report, January 1980-March 1980. [In process streams

    SciTech Connect (OSTI)

    Not Available

    1981-01-01T23:59:59.000Z

    This report summarizes the progress of the Solvent Refined Coal (SRC) project at the SRC Pilot Plant in Fort Lewis, Wahsington, and the Process Development Unit (P-99) in Harmarville, Pennsylvania. After the remaining runs of the slurry preheater survey test program were completed January 14, the Fort Lewis Pilot Plant was shut down to inspect Slurry Preheater B and to insulate the coil for future testing at higher rates of heat flux. Radiographic inspection of the coil showed that the welds at the pressure taps and the immersion thermowells did not meet design specifications. Slurry Preheater A was used during the first 12 days of February while weld repairs and modifications to Slurry Preheater B were completed. Two attempts to complete a material balance run on Powhatan No. 6 Mine coal were attempted but neither was successful. Slurry Preheater B was in service the remainder of the quarter. The start of a series of runs at higher heat flux was delayed because of plugging in both the slurry and the hydrogen flow metering systems. Three baseline runs and three slurry runs of the high heat flux program were completed before the plant was shut down March 12 for repair of the Inert Gas Unit. Attempts to complete a fourth slurry run at high heat flux were unsuccessful because of problems with the coal feed handling and the vortex mix systems. Process Development Unit (P-99) completed three of the four runs designed to study the effect of dissolver L/D ratio. The fourth was under way at the end of the period. SRC yield correlations have been developed that include coal properties as independent variables. A preliminary ranking of coals according to their reactivity in PDU P-99 has been made. Techniques for studying coking phenomenona are now in place.

  15. Novel carbons from Illinois coal for natural gas storage. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Rostam-Abadi, M.; Sun, J.; Lizzio, A.A. [Illinois State Geological Survey, Champaign, IL (United States); Fatemi, M. [Amoco Research Center, Naperville, IL (United States)

    1994-12-31T23:59:59.000Z

    The goal of this project is to develop a technology for producing microengineered adsorbent carbons from Illinois coal and to evaluate the potential application of these novel materials for storing natural gas for use in emerging low pressure, natural gas vehicles (NGV). Potentially, about two million tons of adsorbent could be consumed in natural gas vehicles by year 2000. If successful, the results obtained in this project could lead to the use of Illinois coal in a growing and profitable market that could exceed 6 million tons per year. During this reporting period, a pyrolysis-gasification reactor system was designed and assembled. Four carbon samples were produced from a {minus}20+100 mesh size fraction of an Illinois Basin Coal (IBC-106) using a three-step process. The three steps were: coal oxidation in air at 250 C, oxicoal (oxidized coal) devolatilization in nitrogen at 425 C and char gasification in 50% steam-50% nitrogen at 860 C. These initial tests were designed to evaluate the effects of pre-oxidation on the surface properties of carbon products, and to determine optimum reaction time and process conditions to produce an activated carbon with high surface area. Nitrogen-BET surface areas of the carbon products ranged from 700--800 m{sup 2}/g. Work is in progress to further optimize reaction conditions in order to produce carbons with higher surface areas. A few screening tests were made with a pressurized thermogravimetric (PTGA) to evaluate the suitability of this instrument for obtaining methane adsorption isotherms at ambient temperature and pressures ranging from one to 30 atmospheres. The preliminary results indicate that PTGA can be used for both the adsorption kinetic and equilibrium studies.

  16. Rocky mountain 1: Underground coal-gasification test, Hanna, Wyoming. Summary report, Volume 1. Appendix. Final report

    SciTech Connect (OSTI)

    Vardaman, M.H.

    1989-02-01T23:59:59.000Z

    The Rocky Mountain 1 underground coal gasification test was conducted near Hanna, Wyoming during the period January 1986 through March 1988. These appendixes include information supporting Volume I as well as complete data for certain aspects of the gasification phase. These aspects include daily operations reports, raw and corrected process data, thermocouple and Time Domain Reflectometer results, and monitoring well pressure and level data obtained during the gasification phase. Piping and instrumentation diagrams and supplemental informations on the data acquisition system are included.

  17. Petrographic characterization of Kentucky coals: relationship between sporinite spectral fluorescence and coal rank of selected western Kentucky coals. Final report, Part I. [Vitrinite

    SciTech Connect (OSTI)

    Poe, S.H.; Hower, J.C.

    1983-01-01T23:59:59.000Z

    A total of 43 coal samples were analyzed - the majority from western Kentucky, with a few from Pennsylvania for comparative purposes - using quantitative fluorescence microscopy of sporinite to determine if coal rank as determined by vitrinite maximum reflectance could be predicted by data gathered from selected fluorescence parameters. All eight parameters (wavelength of highest intensity, area under curve to the left of the peak, area in the blue wavelengths (400 to 500 nm), green (500 to 570 nm), yellow (570 to 630 nm), blue-red ratio, and red-green ratio were found to statistically predict coal rank. The general research hypothesis, which included all the variables, had a R/sup 2/ = 0.354. The results of the step-wise regression yielded red and yellow (collective R/sup 2/ = 0.341) as the best predictor variables of coal rank. The individual parameters of area of red wavelength and blue-red ratio accounted for the greatest variance in predicting coal rank, while the parameter yellow area was the least predictive of coal rank. 31 references, 7 figures, 5 tables.

  18. Potential for thermal coal and Clean Coal Technology (CCT) in the Asia-Pacific. Final technical report

    SciTech Connect (OSTI)

    Johnson, C.J.; Long, S.

    1991-11-22T23:59:59.000Z

    The Coal Project was able to make considerable progress in understanding the evolving energy situation in Asia and the future role of coal and Clean Coal Technologies. It is clear that there will be major growth in consumption of coal in Asia over the next two decades -- we estimate an increase of 1.2 billion metric tons. Second, all governments are concerned about the environmental impacts of increased coal use, however enforcement of regulations appears to be quite variable among Asian countries. There is general caution of the part of Asian utilities with respect to the introduction of CCT`s. However, there appears to be potential for introduction of CCT`s in a few countries by the turn of the century. It is important to emphasize that it will be a long term effort to succeed in getting CCT`s introduced to Asia. The Coal Project recommends that the US CCT program be expanded to allow the early introduction of CCT`s in a number of countries.

  19. Assessment of underground coal gasification in bituminous coals: potential UCG products and markets. Final report, Phase I

    SciTech Connect (OSTI)

    None

    1982-01-31T23:59:59.000Z

    The following conclusions were drawn from the study: (1) The US will continue to require new sources of energy fuels and substitutes for petrochemical feedstocks into the foreseeable future. Most of this requirement will be met using coal. However, the cost of mining, transporting, cleaning, and preparing coal, disposing of ash or slag and scrubbing stack gases continues to rise; particularly, in the Eastern US where the need is greatest. UCG avoids these pitfalls and, as such, should be considered a viable alternative to the mining of deeper coals. (2) Of the two possible product gases LBG and MBG, MBG is the most versatile. (3) The most logical use for UCG product in the Eastern US is to generate power on-site using a combined-cycle or co-generation system. Either low or medium Btu gas (LBG or MBG) can be used. (4) UCG should be an option whenever surface gasification is considered; particularly, in areas where deeper, higher sulfur coal is located. (5) There are environmental and social benefits to use of UCG over surface gasification in the Eastern US. (6) A site could be chosen almost anywhere in the Illinois and Ohio area where amenable UCG coal has been determined due to the existence of existing transportation or transmission systems. (7) The technology needs to be demonstrated and the potential economic viability determined at a site in the East-North-Central US which has commercial quantities of amenable bituminous coal before utilities will show significant interest.

  20. Liquid chromatographic analysis of coal surface properties. Quarterly progress report, September--December 1991

    SciTech Connect (OSTI)

    Kwon, K.C.

    1991-12-31T23:59:59.000Z

    The main objectives of this proposed research are to refine further the inverse liquid chromatography technique for the study of surface properties of raw coals, treated coals and coal minerals in water, to evaluate relatively surface properties of raw coals, treated coals and coal minerals by inverse liquid chromatography, and to evaluate floatability of various treated coals in conjunction with surface properties of coals. Alcohols such as methanol, ethanol, isopropanol, isobutanol, tert-butanol, heptanol, 1-hexadecanol, 2-methyl-pentanol, 4-methyl-2-penthanol (methylisobutyl carbinol), n-octanol, s-octanol, and cyclohexanol as probe compounds are utilized to evaluate hydrophilicity of coals and coal minerals. N-alkanes such as hexane, heptane and octane, and stearic acid are employed as probe compounds to evaluate hydrophobicity of coals and coal minerals. Aromatic compounds such as benzene and toluene as probe compounds are used to examine aromaticity of coal surface. Aromatic acids such as o-cresol, m-cresol, p-cresol, phenol and B-naphthol are used to detect aromatic acidic sites of coal surface. Hydrophilicity, hydrophobicity and aromaticity of surfaces for either raw coals or treated coals in water are relatively determined by evaluating both equilibrium physical/chemical adsorption and dynamic adsorption of probe compounds on various raw coals and treated coals to compare affinities of coals for water.

  1. Hanna, Wyoming underground coal gasification data base. Volume 5. Hanna III field test research report

    SciTech Connect (OSTI)

    Bartke, T.C.; Fischer, D.D.; King, S.B.; Boyd, R.M.; Humphrey, A.E.

    1985-08-01T23:59:59.000Z

    This report is part of a seven-volume series on the Hanna, Wyoming, underground coal gasification field tests. Volume 1 is a summary of the project and each of Volumes 2 through 6 describes a particular test. Volume 7 is a compilation of all the data for the tests in Volumes 2 through 6. Hanna III was conducted during the spring and summer of 1977. The test involved only two process wells but also had twelve water monitoring wells, eight in the Hanna No. 1 coal seam and four in an aquifer above the coal seam. The test was designed to obtain information regarding the effects of the process on groundwater within the target seam and the overlying aquifer. The site for Hanna III had a low productivity aquifer above the Hanna No. 1 seam. The wells within the seam and the overlying aquifer were placed in such a manner that maximum information on groundwater flow and quality could be obtained. This report covers: (1) site selection and characterization; (2) test objectives; (3) facilities description; (4) pre-operation tests; (5) test operations summary; and (6) post-test activity. 4 refs., 11 figs., 5 tabs.

  2. High performance materials in coal conversion utilization. Technical progress report, January 1, 1994--March 31, 1994

    SciTech Connect (OSTI)

    Not Available

    1994-04-01T23:59:59.000Z

    This is the second quarterly report concerning this three year grant on {open_quotes}High Performance Materials in Coal Conversion Utilization.{close_quotes} The grant is for a joint university/industry effort under the US Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. The administrative details involved in the finalizing of the subcontracts and the acquisition of the cost shared equipment by UTSI and the U of Pa has slowed progress somewhat, however, the project should go smoothly from this point on. Most of the efforts of this quarter have gone toward preparing the equipment and plans for the laboratory tests. Research into the identification of a suitable protective coating based on thermodynamic considerations and the development of techniques for their application as well as joining ceramic materials has been initiated.

  3. KVB coal desulfurization process development. Quarterly technical progress report for May-September 1980

    SciTech Connect (OSTI)

    Not Available

    1980-01-01T23:59:59.000Z

    This is the initial technical progress report for the KVB Coal Desulfurization Process Development. The project is a joint effort between Research-Cottrell, Inc. and the College of Engineering of Rutgers University. The process involves oxidation of the sulfur in coal (both organic and pyritic) to soluble forms using nitrogen oxide gas mixtures and subsequent extractive removal. Key features of the process are mild reaction conditions and the use of regenerable reagents. A description of the process chemistry is given, as well as a brief summary of previous experimental studies. The experimental and analytical procedures being used in the current investigation, which is just getting underway, are described in detail. A brief outline of process modelling and commercial evaluation studies which will be a part of the project is also given.

  4. Utilization of coal associated minerals. Quarterly report No. 11, April 1-June 30, 1980

    SciTech Connect (OSTI)

    Slonaker, J. F.; Akers, D. J.; Alderman, J. K.

    1980-08-29T23:59:59.000Z

    The purpose of this research program is to examine the effects of coal mineral materials on coal waste by-product utilization and to investigate new and improved methods for the utilization of waste by-products from cleaning, combustion and conversion processing of coal. The intermediate objectives include: (1) the examination of the effects of cleaning, gasification and combustion on coal mineral materials; and (2) the changes which occur in the coal wastes as a result of both form and distribution of mineral materials in feed coals in conjunction with the coal treatment effects resulting from coal cleaning or either gasification or combustion.

  5. Char crystalline transformations during coal combustion and their implications for carbon burnout. Semiannual technical progress report, July 1, 1996--January 1, 1997

    SciTech Connect (OSTI)

    Hurt, R.H.

    1997-06-01T23:59:59.000Z

    This paper reports on research concerned with coal combustion and the crystal transformations of coal chars. Goals were to: determine transient high-temperature deactivation kinetics as a function of parent coal; and to characterize the effect of thermal treatments on the carbon crystal structure.

  6. Autothermal coal gasification

    SciTech Connect (OSTI)

    Konkol. W.; Ruprecht, P.; Cornils, B.; Duerrfeld, R.; Langhoff, J.

    1982-03-01T23:59:59.000Z

    Test data from the Ruhrchemie/Ruhrkohle Texaco coal gasification demonstration plant at Oberhausen are reported. (5 refs.)

  7. Comprehensive report to Congress: Proposals received in response to the Clean Coal Technology V Program Opportunity Notice

    SciTech Connect (OSTI)

    Not Available

    1993-06-01T23:59:59.000Z

    This report is a comprehensive overview of all proposals received and the projects that were selected in response to the Program Opportunity Notice (PON) for the Clean Coal Technology V (CCT-V) Demonstration Projects (solicitation number DE-PS01-92FE62647). The Department of Energy (DOE) issued the solicitation on July 6, 1992. Through this PON, DOE solicited proposals to conduct cost-shared Clean Coal Technology (CCT) projects that advance significantly the efficiency and environmental performance of coal-using technologies and that are applicable to either new or existing facilities.

  8. Technical support for the Ohio Coal Technology Program. Volume 1, Baseline of knowledge concerning by-product characteristics: Final report

    SciTech Connect (OSTI)

    Olfenbuttel, R.; Clark, S.; Helper, E.; Hinchee, R.; Kuntz, C.; Means, J.; Oxley, J.; Paisley, M.; Rogers, C.; Sheppard, W.; Smolak, L. [Battelle, Columbus, OH (United States)

    1989-08-28T23:59:59.000Z

    This report was prepared for the Ohio Coal Development Office (OCDO) under Grant Agreement No. CDO/R-88-LRl and comprises two volumes. Volume I presents data on the chemical, physical, and leaching characteristics of by-products from a wide variety of clean coal combustion processes. Volume II consists of a discussion of (a) process modification waste minimization opportunities and stabilization considerations; (b) research and development needs and issues relating to clean coal combustion technologies and by-products; (c) the market potential for reusing or recycling by-product materials; and (d) regulatory considerations relating to by-product disposal or reuse.

  9. Coal data: A reference

    SciTech Connect (OSTI)

    Not Available

    1995-02-01T23:59:59.000Z

    This report, Coal Data: A Reference, summarizes basic information on the mining and use of coal, an important source of energy in the US. This report is written for a general audience. The goal is to cover basic material and strike a reasonable compromise between overly generalized statements and detailed analyses. The section ``Supplemental Figures and Tables`` contains statistics, graphs, maps, and other illustrations that show trends, patterns, geographic locations, and similar coal-related information. The section ``Coal Terminology and Related Information`` provides additional information about terms mentioned in the text and introduces some new terms. The last edition of Coal Data: A Reference was published in 1991. The present edition contains updated data as well as expanded reviews and additional information. Added to the text are discussions of coal quality, coal prices, unions, and strikes. The appendix has been expanded to provide statistics on a variety of additional topics, such as: trends in coal production and royalties from Federal and Indian coal leases, hours worked and earnings for coal mine employment, railroad coal shipments and revenues, waterborne coal traffic, coal export loading terminals, utility coal combustion byproducts, and trace elements in coal. The information in this report has been gleaned mainly from the sources in the bibliography. The reader interested in going beyond the scope of this report should consult these sources. The statistics are largely from reports published by the Energy Information Administration.

  10. Gasifier feed - Tailor-made from Illinois coals. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III [Illinois State Geological Survey, Champaign, IL (United States); Lytle, J.; Frost, R.R.; Lizzio, A.; Kohlenberger, L.; Brewer, K. [Illinois State Geological Survey, Champaign, IL (United States)]|[DESTEC Energy (United States)]|[Williams Technology, (United States)]|[Illinois Coal Association (United States)

    1992-08-01T23:59:59.000Z

    The main purpose of this project is to produce a feedstock from preparation plant fines from an illinois coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high sulfur content and high Btu value of Illinois coals are particularly advantageous in such a gasifier; preliminary calculations indicate that the increased cost of removing sulfur from the gas from a high sulfur coal is more than offset by the increased revenue from the sale of the elemental sulfur; additionally the high Btu Illinois coal concentrates more energy into the slurry of a given coal to water ratio. The Btu is higher not only because of the higher Btu value of the coal but also because Illinois coal requires less water to produce a pumpable slurry than western coal, i.e., as little as 30--35% water may be used for Illinois coal as compared to approximately 45% for most western coals.

  11. Permeability changes in coal resulting from gas desorption. Second quarterly report, November 15, 1989--February 15, 1990

    SciTech Connect (OSTI)

    Levine, J.R.; Tsay, F.

    1990-12-31T23:59:59.000Z

    Measurement of sorption capacity of coals by microbalance in a high pressure environment requires that corrections be made for the buoyancy of the gas that is displaced by the solid coal. As the pressure increases, the gas density increases, requiring that a correction factor be applied to the weight of the sample as measured by microbalance. A brief report summarizing this correction is attached as Appendix A.

  12. An SAIC Report Prepared for The Indiana Center for Coal Technology

    E-Print Network [OSTI]

    Fernández-Juricic, Esteban

    ....................................................................................................................... 15 1.6.2 Implement advanced clean coal technologies for production of energy products ........ 15

  13. Rocky Mountain 1: Underground coal gasification test, Hanna, Wyoming. Volume 1. Operations. Summary report

    SciTech Connect (OSTI)

    Not Available

    1989-03-01T23:59:59.000Z

    The Rocky Mountain 1 underground coal gasification (UCG) test was conducted near Hanna, Wyoming during the period January 1986 through March 1988. The report focuses on operations phases that included site selection, facility design, facility construction, well drilling, gasification and environmental monitoring. Two technologies were evaluated as separate modules: the Extended Linked Well (ELW) and the Controlled Retracting Injection Point (CRIP) processes. The test results, along with a discussion of the key test parameters and conclusions of the gasification phase, are provided. A bibliography and schematics are included.

  14. Transformations of inorganic coal constituents in combustion systems. Volume 3, Appendices: Final report

    SciTech Connect (OSTI)

    Helble, J.J. [ed.; Srinivasachar, S.; Wilemski, G.; Boni, A.A. [PSI Technology Co., Andover, MA (United States); Kang, Shim-Gyoo; Sarofim, A.F.; Graham, K.A.; Beer, J.M. [Massachusetts Inst. of Tech., Cambridge, MA (United States); Peterson, T.W.; Wendt, O.L.; Gallagher, N.B.; Bool, L. [Arizona Univ., Tucson, AZ (United States); Huggins, F.E.; Huffman, G.P.; Shah, N.; Shah, A. [Kentucky Univ., Lexington, KY (United States)

    1992-11-01T23:59:59.000Z

    This report contains the computer codes developed for the coal combustion project. In Subsection B.1 the FORTRAN code developed for the percolative fragmentation model (or the discrete model, since a char is expressed as a collection of discrete elements in a discrete space) is presented. In Subsection B.2 the code for the continuum model (thus named because mineral inclusions are distributed in a continuum space) is presented. A stereological model code developed to obtain the pore size distribution from a two-dimensional data is presented in Subsection B.3.

  15. Petrographic characterization of Kentucky coals. Quarterly progress report, March 1982-May 1982

    SciTech Connect (OSTI)

    Hower, J.C.; Ferm, J.C.; Cobb, J.C.; Trinkle, E.J.; Frankie, K.A.; Poe, S.H.; Baynard, D.N.; Graese, A.M.; Raione, R.P.

    1982-01-01T23:59:59.000Z

    The project Petrographic characterization of Kentucky coals consists of three specific areas of coal petrology: spectral fluorescence of liptinite macerals, properties of semi-inert macerals, and size/form/microlithotype association of pyrite/marcasite. Additional research on the Mannington and Dunbar coals in western Kentucky and the Alma coal zone in eastern Kentucky will apply techniques developed in the first three areas. Suites of coals from other states will also be studied to expand the variability in the sample set.

  16. Petrographic characterization of Kentucky coals. Quarterly progress report, June 1982-August 1982

    SciTech Connect (OSTI)

    Hower, J.C.; Ferm, J.C.; Cobb, J.C.; Trinkle, E.J.; Frankie, K.A.; Poe, S.H.; Baynard, D.N.; Graese, A.M.; Raione, R.P.

    1982-01-01T23:59:59.000Z

    The project Petrographic Characterization of Kentucky Coals consists of three specific areas of coal petrology: spectral fluorescence of liptinite macerals, properties of semi-inert macerals, and size/form/microlithotype association of pyrite/marcasite. Additional research on the Mannington and Dunbar coals in western Kentucky and the Alma coal zone in eastern Kentucky will apply techniques developed in the first three areas. Suites of coals from other states will also be studied to expand the variability in the sample set.

  17. (Basic properties of coals and other solids)

    SciTech Connect (OSTI)

    Not Available

    1991-11-25T23:59:59.000Z

    This report discusses basic properties of bituminous, subbituminous, and lignite coals. Properties of coal liquids are also investigated. Heats of immersion in strong acids are found for Pittsburgh {number sign}8, Illinois {number sign}6, and Wyodak coals. Production of coal liquids by distillation is discussed. Heats of titration of coal liquids and coal slurries are reported. (VC)

  18. Coal plasticity at high heating rates and temperatures. Final technical progress report

    SciTech Connect (OSTI)

    Gerjarusak, S.; Peters, W.A.; Howard, J.B.

    1995-05-01T23:59:59.000Z

    Plastic coals are important feedstocks in coke manufacture, coal liquefaction, gasification, and combustion. During these processes, the thermoplastic behavior of these coals is also important since it may contribute to desirable or undesirable characteristics. For example, during liquefaction, the plastic behavior is desired since it leads to liquid-liquid reactions which are faster than solid-liquid reactions. During gasification, the elastic behavior is undesired since it leads to caking and agglomeration of coal particles which result in bed bogging in fixed or fluidized bed gasifiers. The plastic behavior of different coals was studied using a fast-response plastometer. A modified plastometer was used to measure the torque required to turn at constant angular speed a cone-shaped disk embedded in a thin layer of coal. The coal particles were packed between two metal plates which are heated electrically. Heating rates, final temperatures, pressures, and durations of experiment ranged from 200--800 K/s, 700--1300 K, vacuum-50 atm helium, and 0--40 s, respectively. The apparent viscosity of the molten coal was calculated from the measured torque using the governing equation of the cone-and-plate viscometer. Using a concentrated suspension model, the molten coal`s apparent viscosity was related to the quantity of the liquid metaplast present during pyrolysis. Seven coals from Argonne National Laboratory Premium Coal Sample Bank were studied. Five bituminous coals, from high-volatile to low-volatile bituminous, were found to have very good plastic behavior. Coal type strongly affects the magnitude and duration of plasticity. Hvb coals were most plastic. Mvb and lvb coals, though the maximum plasticity and plastic period were less. Low rank coals such as subbituminous and lignite did not exhibit any plasticity in the present studies. Coal plasticity is moderately well correlated with simple indices of coal type such as the elemental C,O, and H contents.

  19. Production and screening of carbon products precursors from coal. Quarterly technical progress report and key personnel staffing report No. 6, April 1, 1996--June 30, 1996

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    The main goal of this program is to demonstrate the utility of coal extracts from the West Virginia University (WVU) extraction process as suitable base raw materials for the carbon products encompassed by the Carbon Products Consortium (CPC) team. This quarterly report covers activities during the period from April 1, 1996 through June 30, 1996. The first year of the project ended in February, 1996; however, the WVU research effort has continued on a no-cost extension of the original contract. Samples have been supplied to CPC participants so they could conduct their portions of the project as contracted through ORNL. Progress reports are presented for the following tasks: project planning and administration; consortium administration and reporting; coal extraction; technical/economic evaluation of WVU extraction process; and technology transfer. Previous work has shown that the WVU coal extraction process coupled with hydrotreatment, does have the potential for producing suitable base raw materials for carbon products. Current effort, therefore, involved the screening and evaluation of extracts produced by the WVU Group and recommending appropriate materials for scaleup for subsequent evaluation by Consortium Team members. As part of this program, the activation of the coal extraction residues was investigated for the purpose of producing a useful active carbon. A further task, which was started towards the end of the program, was to fabricate a small graphite artifact using Coke derived from coal extract as the filler and the coal extract itself as a binder. The results of these studies are summarized in this report.

  20. Chlorine in coal and its relationship with boiler corrosion. Technical report, 1 March--31 May 1994

    SciTech Connect (OSTI)

    Chou, M.I.M.; Lytle, J.M.; Ruch, R.R. [Illinois State Geological Survey, Champaign, IL (United States)] [and others

    1994-09-01T23:59:59.000Z

    Limited literature and use history data have suggested that some high-chlorine Illinois coals do not cause boiler corrosion while extensive data developed by the British correlate corrosion with chlorine content and other parameters related to the coal and boiler. The differences in corrosivity in coals may be due to the coal properties, to blending of coals, or to the boiler parameters in which they were burned. The goals of this study focus on coal properties. In this quarter, both destructive temperature-programmed Thermogravimetry with Fourier transform infrared (TGA-FTIR) and non-destructive X-ray absorption near-edge structure (XANES) techniques were used to examine the forms and the evolution characteristics of chlorine in coals. The TGA-FTIR results indicate that under oxidation condition, both British and Illinois coals release hydrogen chloride gas. Illinois coals release the gas at high temperature with maximum evolution temperature ranged between 210 and 280 C. The XANES results indicate that chlorine in coal exists in ionic forms including a solid salt form. The solid NaCl salt form, however, is observed only in some of the British coals and none of the Illinois coals. These results combined with TGA-FTIR results suggest that the chlorine ions in Illinois coals are different from the chlorine ions in British coals.

  1. Petrographic characterization of Kentucky coal. Final report. Part III. Petrographic characterization of the Upper Elkhorn No. 2 coal zone of eastern Kentucky

    SciTech Connect (OSTI)

    Raione, R.P.; Hower, J.C.

    1984-01-01T23:59:59.000Z

    This report presents the study of the Upper Elkhorn No. 2 coal zone in the Big Sandy Reserve District and the surrounding area of eastern Kentucky. The seams were analyzed using megascopic and microscopic petrography and chemical methods. The Upper Elkhorn No. 2 consists predominantly of clarain. A fair degree of correlation of fusain bands and clay partings between data sites is apparent. Microscopically, the vitrinite group of macerals are dominant. A rank increase from high volatile B to high volatile A bituminous to the southwest was noted. Pseudovitrinite is associated negatively with vitrinite and has a higher reflectance and microhardness than vitrinite. Both factors may indicate source material and/or environmental differences in the respective origins of the maceral. High inertinite and lipinite areas, low ash and sulfur contents, and the distribution of thin coals may be indicative of paleotopographic highs. 62 references, 26 figures, 8 tables.

  2. Hindered diffusion of coal liquids. Quarterly report No. 5, September 18, 1993--December 17, 1993

    SciTech Connect (OSTI)

    Tsotsis, T.T.; Sahimi, M. [Univ. of Southern California, Los Angeles, CA (United States). Dept. of Chemical Engineering; Webster, I.A. [UNOCAL Corp., Los Angeles, CA (United States)

    1994-05-01T23:59:59.000Z

    The design of industrial catalysts requires that the diffusivity of the reacting species within the catalyst be accurately known. Nowhere is this more important than in the area of coal liquefaction and upgrading of coal liquids. In this area one is faced with the task of processing a number of heavy oils, containing metals and other contaminants, in a variety of process dependent solvents. It is important, therefore, on the basis of predicting catalyst activity, selectivity, and optimizing reactor performance, that the diffusivities of these oil species be accurately known. In this report, the authors report the publication of model studies of the diffusivity of Lennard-Jones particles in porous systems with dimensionality between two and three. Such a modeled system includes pillared clays. They also published a paper which addresses the sorption and aggregation of asphaltene particles with porous media such as catalysts. The paper presents new experimental data for the amount of asphalt precipitation formed with various solvents. The experimental results are compared to model calculations.

  3. Upgraded coal interest group. Quarterly report, July 1, 1995--September 30, 1995

    SciTech Connect (OSTI)

    Weber, W. [Electric Power Research Inst., Chattanooga, TN (United States); Lebowitz, H.E. [Fossil Fuel Sciences, Palo Alto, CA (United States)

    1995-12-31T23:59:59.000Z

    The objectives of the Upgraded Coal Interest Group (UCIG) are as follows: Review and update the status of various coal upgrading technologies and developments and critically assess the results. Perform engineering screening analyses on various coal upgrading approaches. Perform commercialization analyses that will promote the availability and use of upgraded coal products by quantifying the benefits of using them. Identify market opportunities for introduction of upgraded coals. Perform critical analyses on a variety of coals and technologies in areas important to users but not readily available. Perform critical experiments which will show the differences between technologies.

  4. Development of an advanced high efficiency coal combustor for boiler retrofit. Summary report

    SciTech Connect (OSTI)

    LaFlesh, R.C.; Rini, M.J.; McGowan, J.G.; Beer, J.M.; Toqan, M.A.

    1990-04-01T23:59:59.000Z

    The objective of the program was to develop an advanced coal combustion system for firing beneficiated coal fuels (BCFs) capable of being retrofitted to industrial boilers originally designed for firing natural gas. The High Efficiency Advanced Coal Combustor system is capable of firing microfine coal-water fuel (MCWF), MCWF with alkali sorbent (for SO{sub 2} reduction), and dry microfine coal. Design priorities for the system were that it be simple to operate and offer significant reductions in NO{sub x}, SO{sub x}, and particulate emissions as compared with current coal-fired combustor technology. (VC)

  5. Illinois Clean Coal Institute 2005 annual report. Final technical report for the period September 1st, 2004, through August 31, 2005 on projects funded by the Illinois Department of Commerce and Economic Opportunity

    SciTech Connect (OSTI)

    NONE

    2005-11-08T23:59:59.000Z

    This final technical report contains the abstracts and executive summaries of projects funded through the Illinois Clean Coal Institute solicitation entitled 'Request for proposals No. 04-1(ICCI/RFP04-1)'. Support of these projects is by the Office of Coal Development and Department of Commerce and Economic Opportunity. The projects fall into the following categories: advanced coal mining technologies; coal preparation and coal production business practice; management of coal combustion byproducts; commercialization and technology transfer. Final project extensions are also recorded.

  6. Low-rank coal research: Volume 3, Combustion research: Final report. [Great Plains

    SciTech Connect (OSTI)

    Mann, M. D.; Hajicek, D. R.; Zobeck, B. J.; Kalmanovitch, D. P.; Potas, T. A.; Maas, D. J.; Malterer, T. J.; DeWall, R. A.; Miller, B. G.; Johnson, M. D.

    1987-04-01T23:59:59.000Z

    Volume III, Combustion Research, contains articles on fluidized bed combustion, advanced processes for low-rank coal slurry production, low-rank coal slurry combustion, heat engine utilization of low-rank coals, and Great Plains Gasification Plant. These articles have been entered individually into EDB and ERA. (LTN)

  7. Characterization and supply of coal based fuels. Quarterly report, August 1, 1987--October 31, 1987

    SciTech Connect (OSTI)

    Not Available

    1988-01-01T23:59:59.000Z

    Contract objectives are as follows: Develop fuel specifications to serve combustor requirements; Select coals having appropriate compositional and quality characteristics as well as an economically attractive reserve base; Provide quality assurance for both the parent coals and the fuel forms; and deliver premium coal-based fuels to combustor developers as needed for their contract work. Progress is discussed.

  8. Quarterly review of methane from coal seams technology. Volume 10, Number 2, October 1992. Report for April-June 1992

    SciTech Connect (OSTI)

    McBane, R.A.; Scgwichow, S.D.; Lombardi, T.E.; Thompson, D.A.

    1992-10-01T23:59:59.000Z

    Research in the area of methane from coal seams is directed toward adapting and improving techniques for producing natural gas from coal and associated strata. Verification field experiments are being conducted at various sites to validate concepts for geology, geophysical diagnostics, completion techniques, fracturing, operations, and reservoir modeling. The reports summarize the results of recent exploration, testing, and production in the coal basins. In part because of the unprecedented drilling and development activity in the San Juan and Black Warrior basins, new wells have become too numerous to track individually. Consequently, the detailed well activity tables and basin index maps are no longer presented; only condensed statistical tables accompany selected basin narratives. For details of individual wells, readers are referred to publications of the commercial reporting services and to the respective state oil and gas regulatory agencies.

  9. High performance materials in coal conversion utilization. Final report, October 1, 1993--September 30, 1996

    SciTech Connect (OSTI)

    McCay, T.D.; Boss, W.H. [ed.; Dahotre, N. [and others

    1996-12-01T23:59:59.000Z

    This report describes the research conducted at the University of Tennessee Space Institute on high performance materials for use in corrosive environments. The work was supported by a US Department of Energy University Coal Research grant. Particular attention was given to the silicon carbide particulate reinforced alumina matrix ceramic composite manufactured by Lanxide Corporation as a potential tubular component in a coal-fired recuperative high-temperature air heater. Extensive testing was performed to determine the high temperature corrosion effects on the strength of the material. A computer modeling of the corrosion process was attempted but the problem proved to be too complex and was not successful. To simplify the situation, a computer model was successfully produced showing the corrosion thermodynamics involved on a monolithic ceramic under the High Performance Power System (HIPPS) conditions (see Appendix A). To seal the material surface and thus protect the silicon carbide particulate from corrosive attack, a dense non porous alumina coating was applied to the material surface. The coating was induced by a defocused carbon dioxide laser beam. High temperature corrosion and strength tests proved the effectiveness of the coating. The carbon dioxide laser was also used to successfully join two pieces of the Lanxide material, however, resources did not allow for the testing of the resulting joint.

  10. Coal-fired high performance power generating system. Quarterly progress report, April 1--June 30, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-11-01T23:59:59.000Z

    This report covers work carried out under Task 2, Concept Definition and Analysis, Task 3, Preliminary R&D and Task 4, Commercial Generating Plant Design, under Contract AC22-92PC91155, ``Engineering Development of a Coal Fired High Performance Power Generation System`` between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of: >47% thermal efficiency; NO{sub x}, SO{sub x} and Particulates {le}25% NSPS; cost {ge}65% of heat input; all solid wastes benign. In order to achieve these goals our team has outlined a research plan based on an optimized analysis of a 250 MW{sub e} combined cycle system applicable to both frame type and aeroderivative gas turbines. Under the constraints of the cycle analysis we have designed a high temperature advanced furnace (HITAF) which integrates several combustor and air heater designs with appropriate ash management procedures. A survey of currently available high temperature alloys has been completed and some of their high temperature properties are shown for comparison. Several of the most promising candidates will be selected for testing to determine corrosion resistance and high temperature strength. The corrosion resistance testing of candidate refractory coatings is continuing and some of the recent results are presented. This effort will provide important design information that will ultimately establish the operating ranges of the HITAF.

  11. Healy Clean Coal Project. Quarterly technical progress report number 27, July 1--September 30, 1997

    SciTech Connect (OSTI)

    NONE

    1998-02-01T23:59:59.000Z

    The Healy Clean Coal Project, selected by the US Department of Energy under Round 3 of the Clean Coal Technology Program is currently in construction. The project is owned and financed by the Alaska Industrial Development and Export Authority (AIDEA), and is cofunded by the US Department of Energy. Construction is 99.8% complete and scheduled for physical completion on November 15, 1997, with startup activity concluding in early 1998. Demonstration testing and reporting of the results will take place in 1998, followed by commercial operation of the facility. The emission levels of nitrogen oxides, sulfur dioxide, and particulates from this 50 megawatt plant are expected to be significantly lower than current standards. The primary objective of the project is to demonstrate a new power plant design which features the innovative integration of an advanced combustor and heat recovery system coupled with both high- and low-temperature emission control processes. Equipment includes entrained combustion slagging systems coupled with a boiler which will produce low NOx levels, and function as a limestone calciner and first-stage SO{sub 2} remover in addition to its heat recovery function; a single spray dryer absorber vessel for second-stage SO{sub 2} removal; a baghouse for third-stage SO{sub 2} and particulate removal; and a lime activation system which recovers unused reagent from particulate collected in the baghouse.

  12. Development of Biological Coal Gasification (MicGAS Process). Topical report, July 1991--February 1993

    SciTech Connect (OSTI)

    Srivastava, K.C.

    1993-06-01T23:59:59.000Z

    Laboratory and bench scale reactor research carried out during the report period confirms the feasibility of biomethanation of Texas lignite (TxL) and some other low-rank coals to methane by specifically developed unique anaerobic microbial consortia. The data obtained demonstrates specificity of a particular microbial consortium to a given lignite. Development of a suitable microbial consortium is the key to the success of the process. The Mic-1 consortium was developed to tolerate higher coal loadings of 1 and 5% TxL in comparison to initial loadings of 0.01% and 0.1% TxL. Moreover, the reaction period was reduced from 60 days to 14 to 21 days. The cost of the culture medium for bioconversion was reduced by studying the effect of different growth factors on the biomethanation capability of Mic-1 consortium. Four different bench scale bioreactor configurations, namely Rotating Biological Contactor (RBC), Upflow Fluidized Bed Reactor (UFBR), Trickle Bed Reactor (TBR), and Continuously Stirred Tank Reactor (CSTR) were evaluated for scale up studies. Preliminary results indicated highest biomethanation of TxL by the Mic-1 consortium in the CSTR, and lowest in the trickle bed reactor. However, highest methane production and process efficiency were obtained in the RBC.

  13. Synthesis of methyl methacrylate from coal-derived syngas: Quarterly report,, October 1-December 31, 1997

    SciTech Connect (OSTI)

    NONE

    1998-09-01T23:59:59.000Z

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas that consists of three steps of synthesis of a propionate, its condensation with formaldehyde, and esterification of resulting methacrylic acid (MAA) with methanol to produce MMA. Over the last quarter, Eastman developed two new processes which have resulted in two new invention reports. One process deals with carbonylation of benzyl ether which represents a model for coal liquefaction and the second focuses on the acceleration of carbonylation rates for propionic acid synthesis, via use of polar aprotic solvents. These two inventions are major improvements in the novel Mo-catalyzed homogeneous process for propionic acid synthesis technology, developed by Eastman. Over the last quarter, RTI completed three reaction cycles and two regeneration cycles as a part of long-term reaction regeneration cycle study on a 10% Nb{sub 2}O{sub 5}/Si0{sub 2} catalyst, for vapor phase condensation reaction of formaldehyde with propionic acid.

  14. Table 10. Major U.S. Coal Producers, 2013 U.S. Energy Information Administration | Annual Coal Report 2013

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocks Nov-14 Dec-14TableConference |6:Welcome toU.S.Major U.S. Coal

  15. Wyoming coal-conversion project. Final technical report, November 1980-February 1982. [Proposed WyCoalGas project, Converse County, Wyoming; contains list of appendices with title and identification

    SciTech Connect (OSTI)

    None

    1982-01-01T23:59:59.000Z

    This final technical report describes what WyCoalGas, Inc. and its subcontractors accomplished in resolving issues related to the resource, technology, economic, environmental, socioeconomic, and governmental requirements affecting a project located near Douglas, Wyoming for producing 150 Billion Btu per day by gasifying sub-bituminous coal. The report summarizes the results of the work on each task and includes the deliverables that WyCoalGas, Inc. and the subcontractors prepared. The co-venturers withdrew from the project for two reasons: federal financial assistance to the project was seen to be highly uncertain; and funds were being expended at an unacceptably high rate.

  16. CFBC evaluation of fuels processed from Illinois coals. Technical report, March 1, 1992--May 31, 1992

    SciTech Connect (OSTI)

    Rajan, S. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mechanical Engineering and Energy Processes

    1992-10-01T23:59:59.000Z

    The combustion and emissions properties of (a) flotation slurry fuel beneficiated from coal fines at various stages of the cleaning process and (b) coal-sorbent pellets made from the flotation concentrate of the same beneficiation process using corn starch as binder is being investigated in a 4-inch internal diameter circulating fluidized bed combustor (CFBC). Combustion data such as SO{sub 2}, NO{sub x} emissions, combustion efficiency and ash mineral matter analyses from these fuels are compared with similar parameters from a reference coal burnt in the same fluidized bed combustor. In the last quarter, the CFBC was brought on line and tests were performed on standard coal No. 3 from the Illinois Basin Coal Sample Program (IBCSP). During this quarter, it was decided, that a more meaningful comparison could be obtained if, instead of using the IBCSP No. 3 coal as a standard, the run-of-mine Illinois No. 5 coal from the Kerr-McGee Galatia plant could be used as the reference coal for purposes of comparing the combustion and emissions performance, since the slurry and pellet fuels mentioned in (a) and (b) above were processed from fines recovered form this same Illinois No. 5 seam coal. Accordingly, run-of-the mine Illinois No. 5 coal from the Galatia plant were obtained, riffled and sieved to {minus}14+18 size for the combustion tests. Preliminary combustion tests have been made in the CFBC with this new coal. In preparation for the slurry tests, the moisture content of the beneficiated slurry samples was determined. Proximate and ultimate analyses of all the coal samples were performed. Using a Leeds and Northrup Model 7995-10 Microtrek particle size analyzer, the size distributions of the coal in the three slurry samples were determined. The mineral matter content of the coal in the three slurry samples and the Illinois No. 5 seam coal were investigated using energy dispersive x-ray analysis.

  17. ENCOAL Mild Coal Gasification Demonstration Project. Annual report, October 1993--September 1994

    SciTech Connect (OSTI)

    NONE

    1995-03-01T23:59:59.000Z

    ENCOAL Corporation, a wholly-owned subsidiary of SMC Mining Company (formerly Shell Mining Company, now owned by Zeigler Coal Holding Company), has completed the construction and start-up of a mild gasification demonstration plant at Triton Coal Company`s Buckskin Mine near Gillette, Wyoming. The process, using Liquids From Coal (LFC) technology developed by SMC and SGI International, utilizes low-sulfur Powder River Basin coal to produce two new fuels, Process Derived Fuel (PDF) and Coal Derived Liquids (CDL). The LFC technology uses a mild pyrolysis or mild gasification process which involves heating the coal under carefully controlled conditions. The process causes chemical changes in the feed coal in contrast to conventional drying, which leads only to physical changes. Wet subbituminous coal contains considerable water, and conventional drying processes physically remove some of this moisture, causing the heating value to increase. The deeper the coal is physically dried, the higher the heating value and the more the pore structure permanently collapses, preventing resorption of moisture. However, deeply dried Powder River Basin coals exhibit significant stability problems when dried by conventional thermal processes. The LFC process overcomes these stability problems by thermally altering the solid to create PDF and CDL. Several of the major objectives of the ENCOAL Project have now been achieved. The LFC Technology has been essentially demonstrated. Significant quantities of specification CDL have been produced from Buckskin coal. Plant operation in a production mode with respectable availability (approaching 90%) has been demonstrated.

  18. Fundamental investigations of underground coal gasification. Annual report Mar 82-Mar 83

    SciTech Connect (OSTI)

    Dunn, R.D.

    1983-03-01T23:59:59.000Z

    Coal deposits in the Appalachian and Midwest Coal Regions consist primarily of thin relatively deep seams of swelling bituminous coal, but little scientific effort in the United States has been directed toward underground coal gasification in these important industrial areas. In Europe, however, major work is under way on underground coal gasification in thin, deep seams of swelling coal. The principal investigator and a graduate student are participating in field tests in Belgium and supporting laboratory experiments in Germany. Mathematical models are being developed to interpret these experimental data, and a better understanding of the underground coal gasification process is emerging. This understanding is essential for evaluating potential problems, for devising solutions to such problems and for designing field tests.

  19. Petrographic characterization of Kentucky coals. Quarterly progress report, March-May 1983

    SciTech Connect (OSTI)

    Hower, J.C.; Ferm, J.C.; Cobb, J.C.; Trinkle, E.J.; Frankie, K.A.; Poe, S.H.; Baynard, D.N.; Graese, A.M.; Raione, R.P.

    1983-01-01T23:59:59.000Z

    This project consists of three specific areas of coal petrology: spectral fluorescence of liptinite macerals; properties of semi-inert macerals; and size/form/microlithotype association of pyrite/marcasite. Techniques developed in the first three areas were used in additional research on Mannington and Dunbar coals in western Kentucky and the Alma coal zone in eastern Kentucky. Some of the findings are: percent variations (pseudovitrinite-vitrinite/vitrinite X100) indicate greater dispersions in Vicker's microhardness values, MH(v), of vitrinite and pseudovitrinite from eastern Kentucky coals than those of western Kentucky coals; reflectance data confirm a previously suspected rank increase from eastern Knott and Magoffin Counties to eastern Pike County; microhardness investigation of Upper Elkhorn 2 coal in eastern Kentucky indicates that pseudovitrinite is consistently harder than vitrinite; and of the western coals studied, Dunbar and Lead Creek, there appears to be some correlations between vitrinite, ash, sulfur, and thickness. 6 tables.

  20. Cooperative research in coal liquefaction. Technical progress report, May 1, 1993--April 30, 1994

    SciTech Connect (OSTI)

    Huffman, G.P. [ed.

    1994-10-01T23:59:59.000Z

    Accomplishments for the past year are presented for the following tasks: coliquefaction of coal with waste materials; catalysts for coal liquefaction to clean transportation fuels; fundamental research in coal liquefaction; and in situ analytical techniques for coal liquefaction and coal liquefaction catalysts some of the highlights are: very promising results have been obtained from the liquefaction of plastics, rubber tires, paper and other wastes, and the coliquefaction of wastes with coal; a number of water soluble coal liquefaction catalysts, iron, cobalt, nickel and molybdenum, have been comparatively tested; mossbauer spectroscopy, XAFS spectroscopy, TEM and XPS have been used to characterize a variety of catalysts and other samples from numerous consortium and DOE liquefaction projects and in situ ESR measurements of the free radical density have been conducted at temperatures from 100 to 600{degrees}C and H{sub 2} pressures up to 600 psi.

  1. IGCC repowering project clean coal II project public design report. Annual report, October 1992--September 1993

    SciTech Connect (OSTI)

    NONE

    1993-10-01T23:59:59.000Z

    Combustion Engineering, Inc. (CE) is participating in a $270 million coal gasification combined cycle repowering project that was designed to provide a nominal 60 MW of electricity to City, Water, Light and Power (CWL&P) in Springfield, Illinois. The Integrated Gasification Combined Cycle (IGCC) system consists of CE`s air-blown entrained flow two-stage gasifier; an advanced hot gas cleanup system; a combustion turbine adapted to use low-BTU gas; and all necessary coal handling equipment, The project is currently completing the second budget period of five. The major activities to date are: (1) Establishment of a design, cost, and schedule for the project; (2) Establishment of financial commitments; (3) Acquire design and modeling data; (4) Establishment of an approved for design (AFD) engineering package; (5) Development of a detailed cost estimate; (6) Resolution of project business issues; (7) CWL&P renewal and replacement activities; and (8) Application for environmental air permits. A Project Management Plan was generated, The conceptual design of the plant was completed and a cost and schedule baseline for the project was established in Budget Period One. This information was used to establish AFD Process Flow Diagrams, Piping and Instrument Diagrams, Equipment Data Sheets, material take offs, site modification plans and other information necessary to develop a plus or minus 20% cost estimate. Environmental permitting activities were accomplished, including the Air Permit Application, completion of the National Environmental Policy Act process, and the draft Environmental Monitoring Plan. At the end of 1992 the DOE requested that Duke Engineering and Services Inc., (DESI) be used to complete the balance of plant cost estimate. DESI was retained to do this work, DESI completed the material take off estimate and included operations, maintenance, and startup in the estimate.

  2. Coal conversion and biomass conversion: Volume 1: Final report on USAID (Agency for International Development)/GOI (Government of India) Alternate Energy Resources and Development Program

    SciTech Connect (OSTI)

    Kulkarni, A.; Saluja, J.

    1987-06-30T23:59:59.000Z

    The United States Agency for International Development (AID), in joint collaboration with the Government of India (GOI), supported a research and development program in Alternate Energy Resources during the period March 1983 to June 1987. The primary emphasis of this program was to develop new and advanced coal and biomass conversion technologies for the efficient utilization of coal and biomass feedstocks in India. This final ''summary'' report is divided into two volumes. This Report, Volume I, covers the program overview and coal projects and Volume II summarizes the accomplishments of the biomass projects. The six projects selected in the area of coal were: Evaluation of the Freeboard Performance in a Fluidized-Bed Combustor; Scale-up of AFBC boilers; Rheology, Stability and Combustion of Coal-Water Slurries; Beneficiation of Fine Coal in Dense Medium Cyclones; Hot Gas Cleanup and Separation; and Cold Gas Cleanup and Separation.

  3. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 3

    SciTech Connect (OSTI)

    Miller, Bruce; Shea, Winton

    2010-12-31T23:59:59.000Z

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or ~28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to the research, technology transfer/outreach was a large component of CPCPC's activities. Efficient technology transfer was critical for the deployment of new technologies into the field. CPCPC organized and hosted technology transfer meetings, tours, and tutorials, attended outreach conferences and workshops to represent CPCPC and attract new members, prepared and distributed reports and publications, and developed and maintained a Web site. The second contract ended December 31, 2010, and it is apparent that CPCPC positively impacted the carbon industry and coal research. Statistics and information were compiled to provide a comprehensive account of the impact the consortium had and the beneficial outcomes of many of the individual projects. Project fact sheet, success stories, and other project information were prepared. Two topical reports, a Synthesis report and a Web report, were prepared detailing this information.

  4. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 4

    SciTech Connect (OSTI)

    Miller, Bruce; Shea, Winton

    2010-12-31T23:59:59.000Z

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or {approx}28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to the research, technology transfer/outreach was a large component of CPCPC's activities. Efficient technology transfer was critical for the deployment of new technologies into the field. CPCPC organized and hosted technology transfer meetings, tours, and tutorials, attended outreach conferences and workshops to represent CPCPC and attract new members, prepared and distributed reports and publications, and developed and maintained a Web site. The second contract ended December 31, 2010, and it is apparent that CPCPC positively impacted the carbon industry and coal research. Statistics and information were compiled to provide a comprehensive account of the impact the consortium had and the beneficial outcomes of many of the individual projects. Project fact sheet, success stories, and other project information were prepared. Two topical reports, a Synthesis report and a Web report, were prepared detailing this information.

  5. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 2

    SciTech Connect (OSTI)

    Miller, Bruce; Winton, Shea

    2010-12-31T23:59:59.000Z

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or ~28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to the research, technology transfer/outreach was a large component of CPCPC's activities. Efficient technology transfer was critical for the deployment of new technologies into the field. CPCPC organized and hosted technology transfer meetings, tours, and tutorials, attended outreach conferences and workshops to represent CPCPC and attract new members, prepared and distributed reports and publications, and developed and maintained a Web site. The second contract ended December 31, 2010, and it is apparent that CPCPC positively impacted the carbon industry and coal research. Statistics and information were compiled to provide a comprehensive account of the impact the consortium had and the beneficial outcomes of many of the individual projects. Project fact sheet, success stories, and other project information were prepared. Two topical reports, a Synthesis report and a Web report, were prepared detailing this information.

  6. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 5

    SciTech Connect (OSTI)

    Miller, Bruce; Shea, Winton

    2010-12-31T23:59:59.000Z

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or {approx}28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to the research, technology transfer/outreach was a large component of CPCPC's activities. Efficient technology transfer was critical for the deployment of new technologies into the field. CPCPC organized and hosted technology transfer meetings, tours, and tutorials, attended outreach conferences and workshops to represent CPCPC and attract new members, prepared and distributed reports and publications, and developed and maintained a Web site. The second contract ended December 31, 2010, and it is apparent that CPCPC positively impacted the carbon industry and coal research. Statistics and information were compiled to provide a comprehensive account of the impact the consortium had and the beneficial outcomes of many of the individual projects. Project fact sheet, success stories, and other project information were prepared. Two topical reports, a Synthesis report and a Web report, were prepared detailing this information.

  7. Rock creek multiple coal streams project. Final report, July 1984-November 1994

    SciTech Connect (OSTI)

    Saulsberry, J.L.; Lambert, S.W.; Wallace, J.A.; Spafford, S.D.; Steidl, P.F.

    1995-12-01T23:59:59.000Z

    The report summarizes the research conducted at the Rock Creek Project from 1984 to 1994. The Rock Creek Project was a field laboratory with the purpose of determining the best methods to produce methane from multiple coal seams. The site is located in the Oak Grove field of the Black Warrior Basin approximately 15 miles west of Birmingham, Alabama. The research performed under the Rock Creek Project involved: resource evaluation, reservoir testing, completion techniques, stimulation design and evaluation, operational methods, production forecasting, and remedial stimulations. Offsite cooperative research with other operators was also performed as part of the project. In addition to developing new technology, the work at Rock Creek demonstrated how existing technology from mining, groundwater hydrology, and the petroleum industry could be applied to coalbed methane production. The work also highlighted the pitfalls associated with some of the technology that was being used by certain operators.

  8. An Industrial-Based Consortium to Develop Premium Carbon Products from Coal Final Report - Part 1

    SciTech Connect (OSTI)

    Miller, Bruce; Winton, Shea

    2010-12-31T23:59:59.000Z

    Since 1998, The Pennsylvania State University successfully managed the Consortium for Premium Carbon Products from Coal (CPCPC), which was a vehicle for industry-driven research on the promotion, development, and transfer of innovative technologies on premium carbon products from coal to the U.S. industry. The CPCPC was an initiative led by Penn State, its cocharter member West Virginia University (WVU), and the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL), who also provided the base funding for the program, with Penn State responsible for consortium management. CPCPC began in 1998 under DOE Cooperative Agreement No. DE-FC26-98FT40350. This agreement ended November 2004 but the CPCPC activity continued under cooperative agreement No. DE-FC26-03NT41874, which started October 1, 2003 and ended December 31, 2010. The objective of the second agreement was to continue the successful operation of the CPCPC. The CPCPC enjoyed tremendous success with its organizational structure, which included Penn State and WVU as charter members, numerous industrial affiliate members, and strategic university affiliate members together with NETL, forming a vibrant and creative team for innovative research in the area of transforming coal to carbon products. The key aspect of CPCPC was its industry-led council that selected proposals submitted by CPCPC members to ensure CPCPC target areas had strong industrial support. CPCPC had 58 member companies and universities engaged over the 7-year period of this contract. Members were from 17 states and five countries outside of the U.S. During this period, the CPCPC Executive Council selected 46 projects for funding. DOE/CPCPC provided $3.9 million in funding or an average of $564,000 per year. The total project costs were $5.45 million with $1.5 million, or ~28% of the total, provided by the members as cost share. Total average project size was $118,000 with $85,900 provided by DOE/CPCPC. In addition to the research, technology transfer/outreach was a large component of CPCPC's activities. Efficient technology transfer was critical for the deployment of new technologies into the field. CPCPC organized and hosted technology transfer meetings, tours, and tutorials, attended outreach conferences and workshops to represent CPCPC and attract new members, prepared and distributed reports and publications, and developed and maintained a Web site. The second contract ended December 31, 2010, and it is apparent that CPCPC positively impacted the carbon industry and coal research. Statistics and information were compiled to provide a comprehensive account of the impact the consortium had and the beneficial outcomes of many of the individual projects. Project fact sheet, success stories, and other project information were prepared. Two topical reports, a Synthesis report and a Web report, were prepared detailing this information.

  9. Coal liquefaction: A research and development needs assessment: Final report, Volume II

    SciTech Connect (OSTI)

    Schindler, H.D.; Burke, F.P.; Chao, K.C.; Davis, B.H.; Gorbaty, M.L.; Klier, K.; Kruse, C.W.; Larsen, J.W.; Lumpkin, R.E.; McIlwain, M.E.; Wender, I.; Stewart, N.

    1989-03-01T23:59:59.000Z

    Volume II of this report on an assessment of research needs for coal liquefaction contains reviews of the five liquefaction technologies---direct, indirect, pyrolysis, coprocessing, and bioconversion. These reviews are not meant to be encyclopedic; several outstanding reviews of liquefaction have appeared in recent years and the reader is referred to these whenever applicable. Instead, these chapters contain reviews of selected topics that serve to support the panel's recommendations or to illustrate recent accomplishments, work in progress, or areas of major research interest. At the beginning of each of these chapters is a brief introduction and a summary of the most important research recommendations brought out during the panel discussions and supported by the material presented in the review. A review of liquefaction developments outside the US is included. 594 refs., 100 figs., 60 tabs.

  10. AFBC co-firing of coal and hospital waste. Quarterly report, February - April, 1996

    SciTech Connect (OSTI)

    Stuart, J.M.

    1996-12-31T23:59:59.000Z

    The project objective is to design, construct, install provide operator training and start-up a circulating fluidized bed combustion system at the Lebanon Pennsylvania Veteran`s Affairs Medical Center. This unit will co-fire coal and hospital waste providing lower cost steam for heating and possibly cooling (absorption chiller) and operation of a steam turbine-generator for limited power generation while providing efficient destruction of both general and infectious hospital waste. The steam generated is as follows: steam = 20,000 lb/hr; temperature = 353 F (saturated); pressure = 125 psig; and steam quality = {approximately}98.5%. During this reporting period: structural corrections have been made to make the facility meet the required building costs; and refractory bakeout was successfully completed during April 23-25, 1996 over a 54 -hour period. Operating permits will be obtained after construction has been completed.

  11. The Hanna and Hoe Creek underground coal gasification test sites: Status report, (June 1986-June 1987)

    SciTech Connect (OSTI)

    Berdan, G.L.; Nolan, B.T.; Barteaux, W.L.; Barrash, W.

    1987-06-01T23:59:59.000Z

    To comply with a cooperative agreement with the U.S. Department of Energy (DOE), the Western Research Institute (WRI) is required to submit an annual report summarizing the status of environmentally related work performed by WRI at the Hanna and Hoe Creek underground coal gasification (UCG) sites. The following is a summary of work performed at these two sites from June 1986 to June 1987. Several tasks for restoring the water quailty at Hoe Creek were: (1) groundwater treatment demonstration (1986); (2) bench-scale carbon adsorption experiments (1987); (3) design of the scaled-up treatment system (1987); (4) well-pumping test (1987). A summary of the results of each task is presented. 6 refs., 8 figs., 4 tabs.

  12. Investigation of coal structure. Quarterly report No. 7, October 1, 1993--December 31, 1993

    SciTech Connect (OSTI)

    Not Available

    1994-01-01T23:59:59.000Z

    The objective of this project is to investigate the physical structure of coal illustrated. Coal structure should be well understood to guarantee effective utilization. A better understanding of this physical structure is the first step for effective development of coal utilization processes. Solvent swelling and extraction are the two main investigative probes in this project. No single solvent tested to date can disrupt all of the relatively strong secondary interactions in coal. Various relatively strong secondary interactions must be solvated step by step using appropriate procedures. If physical association is considerable, coal should be readily extracted. Physical association will be evaluated by coal swelling using conventional and new methods. To investigate the effects of low coal concentration and continuous mixing, a new method will be developed. The focus of the work was directed toward a specific bituminous coal low in sulfur and iron. Blind Canyon (DECS-16) coal obtained from the Penn State Coal Bank has been used in this project. Contract activities for this period are: (1) The swelling kinetics were evaluated by conventional procedures using glass tubes. Diffusion of solvent into the coal was small, and solvation of intra- and intermolecular interactions was the rate determining step for swelling. (2) A newly established technique using laser scattering has been used to evaluate interparticle aggregation and swelling. It was observed that particles from certain fractions of specific coals were selectively aggregated in particular solvents. (3) Pyridine extractability after soaking in phenol at 200--250{degrees}C was studied. Approximately 70 wt % of Blind Canyon (DECS-16) coal was extracted under the optimum condition. A significant amount of phenol, however, was physically retained. (4) The associated molecular structure of coal proposed has been supported by associative equilibria during soaking in poor and good solvents.

  13. Production and screening of carbon products precursors from coal. Quarterly progress report, July 1, 1996--September 30, 1996

    SciTech Connect (OSTI)

    Zondlo, J.; Stiller, A.

    1996-10-25T23:59:59.000Z

    This quarterly report covers activities during the period from July 1, 1996 through September 30, 1996 on the development of carbon products precursor materials from coal. The first year of the project ended in February, 1996; however, the WVU research effort continued through August 14, 1997 on a no-cost extension of the original contract. PETC chose to exercise the option for continuation of the projects and $100,000 became available on August 9, 1996. The objective for year two is to focus on development of those carbon products from coal-based solvent extract precursors which have the greatest possibility for commercial success.

  14. Study of catalytic diffusion in coal. Final report, 1983-1984

    SciTech Connect (OSTI)

    Kispert, L.D.

    1984-09-01T23:59:59.000Z

    The purpose of these studies is to determine the pore (hole) size and pore shape distribution in standard bituminous coal samples from various Alabama coal seams such as that of the Mary Lee, Black Creek and Pratt during and after swelling of the coal with different solvents at various temperatures. These samples come from the Penn State Coal Sample Bank at Pennsylvania State University Coal Research Section and from Alabama's Mineral Industries. Methods were developed in the laboratory whereby free-radical probes of varying sizes can be diffused into the coal under various conditions. These probes can be detected and the environment surrounding the probes can be deduced by electron paramagnetic resonance (EPR) methods. To date, it has been found that not only can the shape and size of the pores be determined, but that the size distribution varies from one bituminous coal seam to another, even for coal of the same rank, suggesting a different optimal catalyst should be used for each seam. The effect of oxygen on the coal samples during grinding has been studied; however, the free radical technique appears to be insensitive to the presence of oxygen effects. The goal is to determine the structural differences between various bituminous coals.

  15. Wabash River Coal Gasification Repowering Project. Topical report, July 1992--December 1993

    SciTech Connect (OSTI)

    Not Available

    1994-01-01T23:59:59.000Z

    The Wabash River Coal Gasification Repowering Project (WRCGRP, or Wabash Project) is a joint venture of Destec Energy, Inc. of Houston, Texas and PSI Energy, Inc. of Plainfield, Indiana, who will jointly repower an existing 1950 vintage coal-fired steam generating plant with coal gasification combined cycle technology. The Project is located in West Terre Haute, Indiana at PSI`s existing Wabash River Generating Station. The Project will process locally-mined Indiana high-sulfur coal to produce 262 megawatts of electricity. PSI and Destec are participating in the Department of Energy Clean Coal Technology Program to demonstrate coal gasification repowering of an existing generating unit affected by the Clean Air Act Amendments. As a Clean Coal Round IV selection, the project will demonstrate integration of an existing PSI steam turbine generator and auxiliaries, a new combustion turbine generator, heat recovery steam generator tandem, and a coal gasification facility to achieve improved efficiency, reduced emissions, and reduced installation costs. Upon completion in 1995, the Project will not only represent the largest coal gasification combined cycle power plant in the United States, but will also emit lower emissions than other high sulfur coal-fired power plants and will result in a heat rate improvement of approximately 20% over the existing plant configuration. As of the end of December 1993, construction work is approximately 20% complete for the gasification portion of the Project and 25% complete for the power generation portion.

  16. Studies of in-situ calcium based sorbents in advanced pressurized coal conversion systems. Final report, June 1991--October 1994

    SciTech Connect (OSTI)

    Katta, S.; Shires, P.J.; Campbell, W.M.; Henningsen, G.

    1994-10-01T23:59:59.000Z

    The overall objective of this project was to obtain experimental data on the reactions of calcium-based sorbents in both air-blown coal gasification systems and second generation fluid bed coal combustion systems (partial gasification) as well as stabilization of the spent sorbent produced. The project consisted of six tasks: Tasks 1 and 2 dealt mostly with project-related activities and preparation of test equipment, Task 3 -- study on sulfidation of calcium-based sorbents, Task 4 -- kinetic studies on calcium-catalyzed carbon gasification reactions, and Task 5 -- oxidation of CaS present in LASHs and DASHs (mixtures of coal ash and limestone or dolomite respectively) to CaSO{sub 4} and absorption of SO{sub 2} on various solids, and Task 6 -- economic evaluation of the most promising CaS oxidation method developed under this program. Experimental studies were conducted primarily to address Task 5 issues, and are discussed in this report.

  17. Two dimensional NMR and NMR relaxation studies of coal structure. Progress report, October 1, 1992--December 31, 1992

    SciTech Connect (OSTI)

    Zilm, K.W.

    1992-12-31T23:59:59.000Z

    This report covers the progress made on the title project for the project period. Four major areas of inquiry are being pursued. Advanced solid state NMR methods are being developed to assay the distribution of the various important functional groups that determine the reactivity of coals. Special attention is being paid to methods that are compatible with the very high magic angle sample spinning rates needed for operation at the high magnetic field strengths available today. Polarization inversion methods utilizing the difference in heat capacities of small groups of spins are particularly promising. Methods combining proton-proton spin diffusion with {sup 13}C CPMAS readout are being developed to determine the connectivity of functional groups in coals in a high sensitivity relay type of experiment. Additional work is aimed at delineating the role of methyl group rotation in the proton NMR relaxation behavior of coals.

  18. Status and future opportunities for conversion of synthesis gas to liquid energy fuels: Final report

    SciTech Connect (OSTI)

    Mills, G. (Delaware Univ., Newark, DE (United States). Center for Catalytic Science and Technology)

    1993-05-01T23:59:59.000Z

    The manufacture of liquid energy fuels from syngas (a mixture of H[sub 2] and CO, usually containing CO[sub 2]) is of growing importance and enormous potential because: (1) Abundant US supplies of coal, gas, and biomass can be used to provide the needed syngas. (2) The liquid fuels produced, oxygenates or hydrocarbons, can help lessen environmental pollution. Indeed, oxygenates are required to a significant extent by the Clean Air Act Amendments (CAAA) of 1990. (3) Such liquid synfuels make possible high engine efficiencies because they have high octane or cetane ratings. (4) There is new, significantly improved technology for converting syngas to liquid fuels and promising opportunities for further improvements. This is the subject of this report. The purpose of this report is to provide an account and evaluative assessment of advances in the technology for producing liquid energy fuels from syngas and to suggest opportunities for future research deemed promising for practical processes. Much of the improved technology for selective synthesis of desired fuels from syngas has resulted from advances in catalytic chemistry. However, novel process engineering has been particularly important recently, utilizing known catalysts in new configurations to create new catalytic processes. This report is an update of the 1988 study Catalysts for Fuels from Syngas: New Directions for Research (Mills 1988), which is included as Appendix A. Technology for manufacture of syngas is not part of this study. The manufacture of liquid synfuels is capital intensive. Thus, in evaluating advances in fuels technology, focus is on the potential for improved economics, particularly on lowering plant investment costs. A second important criteria is the potential for environmental benefits. The discussion is concerned with two types of hydrocarbon fuels and three types of oxygenate fuels that can be synthesized from syngas. Seven alternative reaction pathways are involved.

  19. Status and future opportunities for conversion of synthesis gas to liquid energy fuels: Final report

    SciTech Connect (OSTI)

    Mills, G. [Delaware Univ., Newark, DE (United States). Center for Catalytic Science and Technology

    1993-05-01T23:59:59.000Z

    The manufacture of liquid energy fuels from syngas (a mixture of H{sub 2} and CO, usually containing CO{sub 2}) is of growing importance and enormous potential because: (1) Abundant US supplies of coal, gas, and biomass can be used to provide the needed syngas. (2) The liquid fuels produced, oxygenates or hydrocarbons, can help lessen environmental pollution. Indeed, oxygenates are required to a significant extent by the Clean Air Act Amendments (CAAA) of 1990. (3) Such liquid synfuels make possible high engine efficiencies because they have high octane or cetane ratings. (4) There is new, significantly improved technology for converting syngas to liquid fuels and promising opportunities for further improvements. This is the subject of this report. The purpose of this report is to provide an account and evaluative assessment of advances in the technology for producing liquid energy fuels from syngas and to suggest opportunities for future research deemed promising for practical processes. Much of the improved technology for selective synthesis of desired fuels from syngas has resulted from advances in catalytic chemistry. However, novel process engineering has been particularly important recently, utilizing known catalysts in new configurations to create new catalytic processes. This report is an update of the 1988 study Catalysts for Fuels from Syngas: New Directions for Research (Mills 1988), which is included as Appendix A. Technology for manufacture of syngas is not part of this study. The manufacture of liquid synfuels is capital intensive. Thus, in evaluating advances in fuels technology, focus is on the potential for improved economics, particularly on lowering plant investment costs. A second important criteria is the potential for environmental benefits. The discussion is concerned with two types of hydrocarbon fuels and three types of oxygenate fuels that can be synthesized from syngas. Seven alternative reaction pathways are involved.

  20. Stabilization of coal cleaning wastes. Fossil Energy Program. Technical progress report, 1 April 1985-30 June 1985

    SciTech Connect (OSTI)

    Burnet, G.; Gokhale, A.

    1985-07-01T23:59:59.000Z

    This report describes research work in progress on the stabilization of waste from the mining and cleaning of coal. A survey of the literature in the area of coal refuse processing has been conducted using computerized searches of the Energy Data Base and Chemical Abstracts as well as manual scanning of the Chemical Abstracts, NTIS and Energy Research Abstracts. Relevant data from these sources are being assimilated to augment the present research efforts. The coal refuse material to be studied has been analyzed for major elements, Si, Al, Fe and Ca, using atomic absorption. Qualitative information on the mineralogy of the refuse has been obtained using x-ray diffraction. Small scale pelletization and sintering tests have been conducted on the coal refuse which had been ground to different levels of fineness. Water was used as a binding agent and, in the case of coarse refuse, fly ash was added in order to form pellets. The coal refuse had to be ground to about minus 30 mesh particle size to obtain intact pellets after sintering. A laboratory fixed bed reactor system has been designed and built for processing green pellets to simulate the treatment occurring in a traveling grate furnace. The reactor is heated electrically and sequentially exposes samples to drying, ignition, combustion, tempering and cooling. 12 refs., 4 figs., 6 tabs.

  1. A fine coal circuitry study using column flotation and gravity separation. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Honaker, R.Q. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mining Engineering; Reed, S. [Kerr-McGee Coal Corp., Oklahoma City, OK (United States)

    1994-12-31T23:59:59.000Z

    Column flotation provides excellent recovery of ultrafine coal while producing low ash content concentrates. However, column flotation is not efficient for treating fine coal containing significant amounts of mixed-phase particles. Fortunately, enhanced gravity separation has proved to have the ability to treat the mixed-phased particles more effectively. A disadvantage of gravity separation is that ultrafine clay particles are not easily rejected. Thus, a combination of these two technologies may provide a circuit that maximizes both the ash and sulfur rejection that can be achieved by physical coal cleaning while maintaining a high energy recovery. This project is studying the potential of using different combinations of gravity separators, i.e., a Floatex hydrosizer and a Falcon Concentrator, and a proven flotation column, which will be selected based on previous studies by the principle investigator. The gravity/flotation circuits will be compared based on their optimum separation performance which will consider ash and total sulfur rejection and energy recovery as well as the probable error (E{sub p}) value obtained from washability analyses. During this reporting period, multi-stage treatment using the Falcon concentrator was conducted on a refuse pond ({minus}100 mesh) coal sample and a {minus}28 mesh run-of-mine coal sample. The results suggest that the Falcon concentrator can make an ideal separation for either sample in a single process. Recleaning was found to improve product grade, however, recovery was reduced sharply. In addition, the groups involved with the in-plant testing of the Floatex Hydrosizer met and organized the test plan which will be conducted at Kerr-McGee`s Galatia preparation plant during the next reporting period. Coal samples for the circuitry tests will be collected during, this time period.

  2. Radiation-turbulence interactions in pulverized-coal flames. Quarterly reports I and II, September 15, 1993--March 15, 1994

    SciTech Connect (OSTI)

    Menguec, M.P.; McDonough, J.M.

    1994-05-01T23:59:59.000Z

    This is the First Report of the project titled {open_quotes}Radiation-Turbulence Interactions in Pulverized-Coal Flames{close_quotes}. The report covers the period of 6 months from September 15, 1993 to March 15, 1994. During the period covered, the authors have started to modify the experimental facilities for this research and worked on the formulation. This period has been more like a planning time. They expect to have more accomplishments within the next three months.

  3. Electrostatic beneficiation of coal. Quarterly technical progress report, January 1, 1994--March 31, 1994

    SciTech Connect (OSTI)

    Mazumder, M.K.

    1994-04-28T23:59:59.000Z

    Electrostatic beneficiation of dry coal has received significant attention in the last decade. In this process the coal is ground and then charged, either by corona charging or by triboelectrification (friction charging). Coal and minerals receive different levels of charge -- often opposite polarities in the case of triboelectrification -- and can then be separated based on differences in electrical mobility. Problems associated with the techniques include rapid deposition of particles on the electrodes, thus, effecting further separation. The goal of this project is to optimize the electrostatic coal cleaning process to remove pyrites and inorganic materials through studies of the electrostatic properties of powdered coal, in-situ measurements of the electrodynamics of coal and mineral particles inside the separator, and development of self-cleaning collector plates for continuous separation.

  4. Studies of coupled chemical and catalytic coal conversion methods. Ninth quarterly report, October, November, December 1989

    SciTech Connect (OSTI)

    Stock, L.M.

    1989-12-31T23:59:59.000Z

    A new base catalyzed C-alkylation reaction that employs a mixture of n-butyllithium and potassium t-butoxide in refluxing heptane to produce coal anions that are subsequently treated with n-alkyl halides at 0{degree}C has been developed. Almost quantitative pyridine solubilization was achieved by C-octylation of a Lower Kittanning coal, PSOC 1197. C-Octylation was less successful for the solubilization of bituminous Illinois No. 6 coal, APCSP 3, and subbituminous Wyodak coal, APCSP 2, which gave 35 and 33% soluble material, respectively. Their O-methyl derivatives yielded 43 and 20% soluble material in the same reaction. The observations are in accord with the concept of Ouchi and his associates that higher rank coals, although more aromatic in character, have a lower degree of polymerization than low rank coals. Relatively mild chemical reactions, such as Calkylation, that lead to modest changes in molecular dimensions, can disrupt intermolecular forces and accomplish solubilization.

  5. Multi-parameter on-line coal bulk analysis. Quarterly report, March 16--June 15, 1997

    SciTech Connect (OSTI)

    Vourvopoulos, G.

    1997-12-31T23:59:59.000Z

    An on-line coal analyzer is being developed as a joint venture between the French company SODERN which specializes in the manufacturing of neutron generators and associated electronics and the John B. Long Company which specializes in coal sampling equipment. Progress this quarter is summarized under the following topical headings: Measurement layout; Detector temperature stabilization; Raw coal library; and Determination of Btu content from elemental concentrations.

  6. Biodesulfurization techniques: Application of selected microorganisms for organic sulfur removal from coals. Final report

    SciTech Connect (OSTI)

    Elmore, B.B.

    1993-08-01T23:59:59.000Z

    As an alternative to post-combustion desulfurization of coal and pre-combustion desulfurization using physicochemical techniques, the microbial desulfurization of coal may be accomplished through the use of microbial cultures that, in an application of various microbial species, may remove both the pyritic and organic fractions of sulfur found in coal. Organisms have been isolated that readily depyritize coal but often at prohibitively low rates of desulfurization. Microbes have also been isolated that may potentially remove the organic-sulfur fraction present in coal (showing promise when acting on organic sulfur model compounds such as dibenzothiophene). The isolation and study of microorganisms demonstrating a potential for removing organic sulfur from coal has been undertaken in this project. Additionally, the organisms and mechanisms by which coal is microbially depyritized has been investigated. Three cultures were isolated that grew on dibenzothiophene (DBT), a model organic-sulfur compound, as the sole sulfur source. These cultures (UMX3, UMX9, and IGTS8) also grew on coal samples as the sole sulfur source. Numerous techniques for pretreating and ``cotreating`` coal for depyritization were also evaluated for the ability to improve the rate or extent of microbial depyritization. These include prewashing the coal with various solvents and adding surfactants to the culture broth. Using a bituminous coal containing 0.61% (w/w) pyrite washed with organic solvents at low slurry concentrations (2% w/v), the extent of depyritization was increased approximately 25% in two weeks as compared to controls. At slurry concentrations of 20% w/v, a tetrachloroethylene treatment of the coal followed by depyritization with Thiobacillus ferrooxidans increased both the rate and extent of depyritization by approximately 10%.

  7. Coal gasification power generation, and product market study. Topical report, March 1, 1995--March 31, 1996

    SciTech Connect (OSTI)

    Sheesley, D.; King, S.B.

    1998-12-31T23:59:59.000Z

    This Western Research Institute (WRI) project was part of a WRI Energy Resource Utilization Program to stimulate pilot-scale improved technologies projects to add value to coal resources in the Rocky Mountain region. The intent of this program is to assess the application potential of emerging technologies to western resources. The focus of this project is on a coal resource near the Wyoming/Colorado border, in Colorado. Energy Fuels Corporation/Kerr Coal Company operates a coal mine in Jackson County, Colorado. The coal produces 10,500 Btu/lb and has very low sulfur and ash contents. Kerr Coal Company is seeking advanced technology for alternate uses for this coal. This project was to have included a significant cost-share from the Kerr Coal Company ownership for a market survey of potential products and technical alternatives to be studied in the Rocky Mountain Region. The Energy Fuels Corporation/Kerr Coal Company and WRI originally proposed this work on a cost reimbursable basis. The total cost of the project was priced at $117,035. The Kerr Coal Company had scheduled at least $60,000.00 to be spent on market research for the project that never developed because of product market changes for the company. WRI and Kerr explored potential markets and new technologies for this resource. The first phase of this project as a preliminary study had studied fuel and nonfuel technical alternatives. Through related projects conducted at WRI, resource utilization was studied to find high-value materials that can be targeted for fuel and nonfuel use and eventually include other low-sulfur coals in the Rocky Mountain region. The six-month project work was spread over about a three-year period to observe, measure, and confirm over time-any trends in technology development that would lead to economic benefits in northern Colorado and southern Wyoming from coal gasification and power generation.

  8. Improvement of storage, handling, and transportability of fine coal. Quarterly technical progress report No. 5, January 1, 1995--March 31, 1995

    SciTech Connect (OSTI)

    NONE

    1996-08-21T23:59:59.000Z

    The Mulled Coal process was developed as a means of overcoming the adverse handling characteristics of wet fine coal without thermal drying. The process involves the addition of a low cost, harmless reagent to wet fine coal using off-the-shelf mixing equipment. Based on laboratory- and bench-scale testing, Mulled Coal can be stored, shipped, and burned without causing any of the plugging, pasting, carryback and freezing problems normally associated with wet coal. The objectives of this project are to demonstrate that: the Mulled Coal process, which has been proven to work on a wide range of wet fine coals at bench scale, will work equally well on a continuous basis, producing consistent quality at a convincing rate of production in a commercial coal preparation plant; the wet product from a fine coal cleaning circuit can be converted to a solid fuel form for ease of handling and cost savings in storage and rail car transportation; and a wet fine coal product thus converted to a solid fuel form, can be stored, shipped, and burned with conventional fuel handling, transportation, and combustion systems. During this reporting period, virtually all of the technical activities and progress was made in the areas of circuit installation and startup operations. Work in these activity areas are described.

  9. The development of coal-based technologies for Department of Defense facilities. Semiannual technical progress report, March 28, 1994--September 27, 1994

    SciTech Connect (OSTI)

    Miller, B.G.; Bartley, D.A.; Morrison, J.L. [and others

    1995-04-14T23:59:59.000Z

    The US Department of Defense (DOD), through an Interagency Agreement with the US Department of Energy (DOE), has initiated a three-phase program with the Consortium for Coal Water Slurry Fuel Technology, with the aim of decreasing DOD`s reliance on imported oil by increasing its use of coal. The program is being conducted as a cooperative agreement between the Consortium and DOE and the first two phases of the program are underway. Activities this reporting period included performing coal beneficiation/preparation studies, conducting combustion performance evaluations, preparing retrofit engineering designs, determining retrofit economics, and installing a micronized coal-water mixture (MCWM) circuit.

  10. ENCOAL Mild Coal Gasification Project. Annual report, October 1990--September 1991

    SciTech Connect (OSTI)

    Not Available

    1992-02-01T23:59:59.000Z

    ENCOAL Corporation, a wholly-owned subsidiary of Shell Mining Company, is constructing a mild gasification demonstration plant at Triton Coal Company`s Buckskin Mine near Gillette, Wyoming. The process, using Liquids From Coal (LFC) technology developed by Shell and SGI International, utilizes low-sulfur Powder River Basin Coal to produce two new fuels, Process Derived Fuel (PDF) and Coal Derived Liquids (CDL). The products, as alternative fuels sources, are expected to significantly reduce current sulfur emissions at industrial and utility boiler sites throughout the nation, thereby reducing pollutants causing acid rain.

  11. Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Final report

    SciTech Connect (OSTI)

    Chunshan Song; Schobert, H.H.; Parfitt, D.P. [and others

    1997-11-01T23:59:59.000Z

    Development of new catalysts is a promising approach to more efficient coal liquefaction. It has been recognized that dispersed catalysts are superior to supported catalysts for primary liquefaction of coals, because the control of initial coal dissolution or depolymerization requires intimate contact between the catalyst and coal. This research is a fundamental and exploratory study on catalytic coal liquefaction, with the emphasis on exploring novel bimetallic dispersed catalysts for coal liquefaction and the effectiveness of temperature-programmed liquefaction using dispersed catalysts. The primary objective of this research was to explore novel bimetallic dispersed catalysts from organometallic molecular precursors, that could be used in low concentrations but exhibit relatively high activity for efficient hydroliquefaction of coals under temperature-programmed conditions. We have synthesized and tested various catalyst precursors in liquefaction of subbituminous and bituminous coals and in model compound studies to examine how do the composition and structure of the catalytic precursors affect their effectiveness for coal liquefaction under different reaction conditions, and how do these factors affect their catalytic functions for hydrogenation of polyaromatic hydrocarbons, for cleavage of C-C bonds in polycyclic systems such as 4-(1-naphthylmethyl)bibenzyl, for hydrogenolysis of C-O bond such as that in dinaphthylether, for hydrodeoxygenation of phenolic compounds and other oxygen-containing compounds such as xanthene, and for hydrodesulfurization of polycyclic sulfur compounds such as dibenzothiophene. The novel bimetallic and monometallic precursors synthesized and tested in this project include various Mo- and Fe-based compounds.

  12. Oxidative derivatization and solubilization of coal. Final report. Period: October 1, 1986 - April 30, 1988

    SciTech Connect (OSTI)

    Schulz, J.G.; Porowski, E.N.; Straub, A.M.

    1988-05-01T23:59:59.000Z

    We investigated the solubilization of coal by oxidative means to produce motor fuels. Nitric acid was used in the first of two approaches taken to cleave aliphatic linkages in coal and reduce the size of its macrostructure. Mild conditions, with temperatures up to a maximum of 75 C, and nitric acid concentrations below 20% by weight, characterize this process. The solid product, obtained in high yields, is soluble in polar organic solvents. Lower alcohols, methanol in particular, are of interest as carrier solvents in diesel fuel applications. Coals investigated were New York State peat, Wyodak subbituminous coal, North Dakota lignite, and Illinois No. 6 bituminous coal. The lower tank coals were easily converted and appear well suited to the process, while the bituminous Illinois No. 6 and Pitt Seam coals were unreactive. We concentrated our efforts on Wyodak coal and North Dakota lignite. Reaction conditions with regards to temperature, acid concentration, and time were optimized to obtain high product selectivity at maximum conversion. A continuous process scheme was developed for single pass coal conversions of about 50% to methanol-soluble product.

  13. ANNUAL REPORT OCTOBER 1, 1979-SEPTEMBER 30, 1980 CHEMISTRY AND MORPHOLOGY OF COAL LIQUEFACTION

    E-Print Network [OSTI]

    Heinemann, Heinz

    2013-01-01T23:59:59.000Z

    effect on its behavior during gasification and liquefactionand observation of the gasification reactions in-situ in anfrom coal instead of gasification to CO and H 2 • Since

  14. Joint United States and People`s Republic of China clean coal activities. Annual report, April 1994--December 1995

    SciTech Connect (OSTI)

    NONE

    1996-06-01T23:59:59.000Z

    The United States Department of Energy (U.S. DOE) and the Ministry of Coal Industry of the People`s Republic of China (China) signed a protocol in the field of fossil energy research and development in April 1985. An annex to this agreement, Annex IX, was signed in April 1994 for cooperation between the U.S. DOE and China`s State Science and Technology Commission (SSTC) in the area of clean coal utilization. Article III of Annex IX requires the United States and China jointly to prepare an annual report i describing the work performed and results achieved. This report, in compliance with Article III, is a description of the activities conducted under Annex IX during the period from April 1994 through December 1995. The report also contains the plans for future activities for the next 12 months, or through December 1996.

  15. Report to Congress: Expressions of interest in commercial clean coal technology projects in foreign countries

    SciTech Connect (OSTI)

    NONE

    1995-06-01T23:59:59.000Z

    This report was prepared in response to the guidance provided by the Congress in the course of the Fiscal Year 1995 appropriations process for the Department of Energy`s (DOE) Office of Fossil Energy (FE). As described in detail below, DOE was directed to make the international dissemination of Clean Coal Technologies (CCTs) an integral part of its policy to reduce greenhouse gas emissions in developing countries. Congress directed DOE to solicit ``Statements of Interest`` in commercial projects employing CCTs in countries projected to have significant growth in greenhouse gas emissions. Additionally, DOE was asked to submit to the Congress a report that analyzes the information contained in the Statements of Interest, and that identifies the extent to which various types of Federal incentives would accelerate the commercial availability of these technologies in an international context. In response to DOE`s solicitation of 18 November 1994, 77 Statements of Interest were received from 33 companies, as well as five additional materials. The contents of these submittals, including the requested Federal incentives, the CCTs proposed, the possible host countries, and the environmental aspects of the Statements of Interest, are described and analyzed in the chapters that follow.

  16. Clean Coal Technology Program: Completing the mission. Comprehensive report to Congress

    SciTech Connect (OSTI)

    Not Available

    1994-05-01T23:59:59.000Z

    With its roots in the acid rain debate of the 1980`s, the Clean Coal Technology Demonstration Program initially emphasized acid rain abatement technologies in its early phases. With the subsequent passage of the Clean Air Act Amendments and growing concern with global climate change, the emphasis of the Program shifted in the later rounds to highly efficient technologies. This report is divided into six chapters. Chapter 1 introduces the report. Chapter 2 provides a background of the CCT Program including the legislative history, the projects currently in the program, and the lessons that have been learned from the five rounds to date. Chapter 3 discusses the commercial potential of the technologies represented in the program and is based on a continuing series of interviews that have been conducted by the Department of Energy to solicit the views of senior management in those companies and organizations that will be making or affecting commercial decisions on the use of these technologies. Chapter 4 provides an accounting of the funds that have been appropriated for the CCT Program. Chapter 5 presents the options available for the Government to further assist in the commercial implementation of these technologies. Chapter 6 presents a discussion of these options with recommendations.

  17. Suppression of fine ash formation in pulverized coal flames. Final technical report, September 30, 1992--January 31, 1996

    SciTech Connect (OSTI)

    Kramlich, J.C.; Chenevert, B.; Park, Jungsung; Hoffman, D.A.; Butcher, E.K.

    1996-07-19T23:59:59.000Z

    Coal ash, and particularly fine fly ash, remain one of the principal practical and environmental problems in coal-based power generation. In particular, submicron aerosols are identified with direct inhalation risk. Submicron ash is thought to arise from mineral vaporization during char combustion, followed by nucleation, condensation and coagulation to yield an aerosol. While aerosols are predominantly made out of volatile alkali minerals, they also can include refractory oxides that are chemically reduced to more volatile forms within the char particle and vaporized. Most of the ash of size greater than 1 {mu}m is generated by agglomeration of mineral as the char particle bums out. These two principal mechanisms are thought to account for most of the ash generated in coal combustion. Previous research has shown that various forms of coal treatment can influence the yields of fine ash from combustion. The research reported here investigates various forms of treatment, including physical coal cleaning, aerodynamic sizing, degree of grinding, and combinations of these on both aerosol yields and on yields of fine residual ash (1-4 {mu}m). The work also includes results from the combustion of artificial chars that include individual mineral elements. This research shows that these various forms of coal treatment can significantly change ash characteristics. While none of the treatments affected the bulk of the residual ash size distribution significantly, the yield of the ash aerosol mode (d<0.5 {mu}m) and fine residual ash mode (1-4 {mu}m) are changed by the treatments.

  18. Analysis quality report on the EIA Annual Report to Congress 1978, volume III : coal supply

    E-Print Network [OSTI]

    Wood, David O.

    1981-01-01T23:59:59.000Z

    The Energy Information Administration (EIA) is charged by Congress to prepare an Annual Report to Congress (ARC) which includes projections of energy supplies, consumption and prices, as well as the relation of energy to ...

  19. Permeability changes in coal resulting from gas desorption. Quarterly report, August 16, 1989--November 15, 1989

    SciTech Connect (OSTI)

    Not Available

    1989-12-31T23:59:59.000Z

    The goal of this task is to accurately measure the elongation and shrinkage exhibited by coal as it sorbs and desorbs methane gas at elevated pressure. Our research group has discussed several possible methods to measure this strain, including: optical microscopy, laser interferometry, conventional strain gauges, and LVDT strain gauges. There are advantages and disadvantages of each method. We had planned to use optical microscopy but, on further investigation, this approach will be less satisfactory than the strain gauge method. Accordingly, we have switched our focws to the use of strain gauges. Conventional strain gauges also involve potential problems which must be overcome, including: (1) Contrast in strength between the coal and the strain gauge must be minimized, (2) The proper glue that is neither too strong or too weak must be used to affix the strain gauge to the coal or the strain in the coal will not be accurately transmitted to the gauge, and (3) We must be aware that the total strain in the coal may not be homogeneously distributed through the specimen (due either either to boundary effects or contrast in composition of the coal layers). A high pressure chamber for sorption-strain experiments is currently being tested an modified and tested. The chamber will accommodate several small blocks of coal simultaneously. This will optimize efficiency, owing to the long times required to reequilibrate the coal blocks to changes in methane pressure.

  20. Low-rank coal research: Volume 2, Advanced research and technology development: Final report

    SciTech Connect (OSTI)

    Mann, M.D.; Swanson, M.L.; Benson, S.A.; Radonovich, L.; Steadman, E.N.; Sweeny, P.G.; McCollor, D.P.; Kleesattel, D.; Grow, D.; Falcone, S.K.

    1987-04-01T23:59:59.000Z

    Volume II contains articles on advanced combustion phenomena, combustion inorganic transformation; coal/char reactivity; liquefaction reactivity of low-rank coals, gasification ash and slag characterization, and fine particulate emissions. These articles have been entered individually into EDB and ERA. (LTN)

  1. Preliminary evaluation of resinite recovery from Illinois coal. Technical report, March 1--May 31, 1995

    SciTech Connect (OSTI)

    Crelling, J.C.

    1995-12-31T23:59:59.000Z

    Resinite is a naturally occurring substance found in coal and derived from original plant resins. It has been commercially exploited in the western USA for use in adhesives, varnishes and thermal setting inks. The overall objective of this project is to compare the properties of the resinite contained in Illinois Basin coals to resinite being commercially exploited in the western US, and to recover the resinite from Illinois coals by microbubble column floatation techniques. The significance of this study is that it has the potential to show the way to recover a valuable chemical, resinite, from coal using only physical processing techniques. The value of the resinite at $1.00/kg or $0.50/lb makes it about fifty times more valuable than steam coal. The removal of resinite from coal does not decrease the value of the remaining coal in any way. During this quarter pure concentrates of resinite from Herrin No. 6 Seam were produced by the density gradient centrifugation technique. This material is also now being characterized by petrographic and chemical methods. Another accomplishment this quarter was the completion of a series of microbubble column flotation tests under eight different conditions. The tests were successful in producing concentrates that are now being evaluated. The significance of the work done during this quarter is the confirmation that the resinite in an Illinois coal can be successfully separated in quantities useful for testing and analysis.

  2. Characterization of the surface properties of Illinois Basin Coals. Technical report, September 1--November 30, 1991

    SciTech Connect (OSTI)

    Demir, I.

    1991-12-31T23:59:59.000Z

    The overall objective of this research project is to provide fundamental data on the physical and chemical surface properties of Illinois coals, specifically those of the Illinois Basin Coal Sample Program (IBCSP). This will help coal researchers achieve an optimal match between Illinois Basin coals and potential coal cleaning and conversion processes (or at least reduce the number of coals suitable for a particular process) and may lead to improved desulfurization and increased utilization of Illinois Basin coals. The specific tasks scheduled to meet our objective are: (1) Physical Characterization: Determine total surface area, porosity, pore size and volume distributions of IBCSP coals crushed to two particle sizes, {minus}100 and {minus}400 mesh (exclusive of IBC-108 which is available only in {minus}400 mesh form), in both an unoxidized and oxidized state. (2) Chemical Characterization: Determine the surface charge (electrokinetic mobility) as a function of pH by electrophoresis and analyze the surface chemical structure of the above samples using Diffuse Reflectance Infrared Spectroscopy (DRIS). (3) Multivariate Statistical Analyses: Explore possible relationships among the newly determined surface properties and other available characterization data, including chemical and petrographic compositions, vitrinite reflectance, free swelling index, ash yield, sulfur forms, and other relevant properties.

  3. Predictors of plasticity in bituminous coals. Technical progress report No. 4, Part I of II

    SciTech Connect (OSTI)

    Lloyd, W.G.; Reasoner, J.W.; Hower, J.C.; Yates, L.P.; Bowling, C.C.; Davis, E.; Jones, T.M.; Whitt, J.M.

    1982-09-01T23:59:59.000Z

    We have substantially enlarged the analytical database developed from the first 37 coals obtained for this study. Pyrolysis/GC has now been completed for 30 coals, and THF and DMF quantitative extractions for 23 coals. FT-IR spectra have been obtained and disc-stored for all coals; differential analysis of these data is now commencing. The first statistical trial runs have been made. ASTM maximum fluidity can be predicted by a simple two-variable regression equation with R = 0.95. This initial success encourages us to undertake a more sophisticated examination of the interdependencies which are becoming evident as the database is built. Under the original work plan we are to enter an intensive Phase 2 study of six selected coals by January 1983.

  4. Exploratory research on novel coal liquefaction concept. Progress report, April 1, 1996--June 30, 1996

    SciTech Connect (OSTI)

    Burke, F.P.; Brandes, S.D.; Winschel, R.A.

    1996-08-12T23:59:59.000Z

    Activities this quarter were conducted under Tasks 2, 3, and 5. Task 2 work concentrated on evaluating the effects of low-severity, first-stage reaction conditions on coal conversions of lignite, subbituminous, and bituminous coals. The impact of artificially weathering bituminous coal was investigated. Large quantities of first-stage product were made using the one-liter reactor for subsequent filtration and catalytic upgrading tests. Test conditions and coal conversions for all microautoclave and one-liter tests made this quarter are presented. Filtration tests examined lignite, subbituminous, and bituminous coal products. The effects on resid conversion of second-stage reaction conditions and catalyst recycle were studied. Task 3 work included the successful transfer of first-stage reactor products to a receiver and the design of an interstage filter. Task 5 work included an ongoing review of the technical and patent literature and expansion of the annotated bibliography. Mass and elemental balances were obtained for selected tests.

  5. Basic properties of coals and other solids. Final report, September 1, 1989--August 30, 1992

    SciTech Connect (OSTI)

    Arnett, E.M.

    1992-12-31T23:59:59.000Z

    The previous project dissected the heats of interactions of a series of coals into components that represented Bronsted acidity, hydrogen-bonding acidity and dispersion force interactions through comparison with the simple prototype solid acids: sulfonic acid resin, silica, and graphitized carbon black respectively. The present grant has emphasized the interaction of basic components in the coal with strong Bronsted acids and boron trichloride, a very strong Lewis acid, with a brief examination of the interactions of the coals with phenols as weaker hydrogen-bonding acids. We have also compared several coals with liquids derived from them at Wilsonville and Exxon. Finally, we have examined the effect of citric acid washing on several coals.

  6. Clean coal technologies market potential

    SciTech Connect (OSTI)

    Drazga, B. (ed.)

    2007-01-30T23:59:59.000Z

    Looking at the growing popularity of these technologies and of this industry, the report presents an in-depth analysis of all the various technologies involved in cleaning coal and protecting the environment. It analyzes upcoming and present day technologies such as gasification, combustion, and others. It looks at the various technological aspects, economic aspects, and the various programs involved in promoting these emerging green technologies. Contents: Industry background; What is coal?; Historical background of coal; Composition of coal; Types of coal; Environmental effects of coal; Managing wastes from coal; Introduction to clean coal; What is clean coal?; Byproducts of clean coal; Uses of clean coal; Support and opposition; Price of clean coal; Examining clean coal technologies; Coal washing; Advanced pollution control systems; Advanced power generating systems; Pulverized coal combustion (PCC); Carbon capture and storage; Capture and separation of carbon dioxide; Storage and sequestration of carbon dioxide; Economics and research and development; Industry initiatives; Clean Coal Power Initiative; Clean Coal Technology Program; Coal21; Outlook; Case Studies.

  7. Temperature effects on chemical structure and motion in coal. Final report

    SciTech Connect (OSTI)

    Maciel, G.E.

    1996-09-30T23:59:59.000Z

    The objective of this project was to apply recently developed, state-of-the-art nuclear magnetic resonance (NMR) techniques to examine in situ changes in the chemical structure and molecular/macromolecular motion in coal as the temperature is increased above room temperature. Although alterations in the chemical structure of coal have been studied previously by {sup 13}C NMR, using quenched samples, the goal of this project was to examine these chemical structural changes, and changes in molecular/macromolecular mobility that may precede or accompany the chemical changes, at elevated temperatures, using modern {sup 13}C and {sup 1}H NMR techniques, especially {sup 1}H dipolar-dephasing techniques and related experiments pioneered in the laboratory for examining pyridine-saturated coals. This project consisted of the following four primary segments and related efforts on matters relevant to the first four tasks. (1) {sup 1}H NMR characterization of coal structure and mobility as a function of temperature variation over a temperature range (30--240 C) for which substantial chemical transformations were not anticipated. (2) {sup 1}H NMR characterization of coal structure, mobility and conversion as a function of temperature variation over a temperature range (240--500 C) for which chemical transformations of coal are known to occur. (3) {sup 13}C NMR investigation of coal structure/mobility as a function of temperature over a temperature range (30--240 C) for which substantial chemical transformations were not anticipated. (4) {sup 13}C NMR investigation of coal structure, dynamics and conversion as a function of temperature variation over a range (240--500 C) for which chemical transformations of coal are known to occur. (5) Related matters relevant to the first four tasks: (a) {sup 1}H CRAMPS NMR characterization of oil shales and their kerogen concentrates; and (b) improved quantitation in {sup 13}C MAS characterization of coals.

  8. Preliminary evaluation of resinite recovery from Illinois coal. Technical report, December 1, 1994--February 28, 1995

    SciTech Connect (OSTI)

    Crelling, J.C.

    1995-12-31T23:59:59.000Z

    Resinite is a naturally occurring substance found in coal and derived from original plant resins. It is ubiquitous in North American coals. It makes up one to four percent by volume of most Illinois coals. It has been commercially exploited in the western USA for use in adhesives, varnishes and thermal setting inks. The overall objective of this project is to compare the properties of the resinite contained in Illinois Basin coals to resinite being commercially exploited in the western United States, and to recover the resinite from Illinois coals by microbubble column floatation techniques. This project is relevant to priority 1.4A identified in ICCI/RFP93-1. The significance of this study is that it has the potential to show the way to recover a valuable chemical, resinite, from coal using only physical processing techniques. The value of the resinite at $1.00/kg or $0.50/lb makes it about fifty times more valuable than steam coal. The removal of resinite from coal does not decrease the value of the remaining coal in any way. The unique aspects are that: (1) it is the first examination of the resinite recovery potential of Illinois coal, (2) it integrates the latest characterization techniques such as density gradient centrifugation, microspectrofluorometry, and gas chromatography-mass spectrometry, and (3) it uses microbubble column flotation to determine the resinite recovery potential. During this quarter samples were obtained, information from both the databases of both the Illinois State Geological Survey (ISGS) and the Pennsylvania State University (PSU) was obtained and evaluated, and IBCSP samples from the Herrin No. 6, the Springfield No. 5 and the Colchester No. 2 seams were analyzed petrographically and the resinites in these samples were characterized by fluorescence spectral analysis.

  9. Preliminary evaluation of resinite recovery from Illinois coal. [Quarterly] technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Crelling, J.C. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Geology

    1994-12-31T23:59:59.000Z

    Resinite is a naturally occurring substance found in coal and derived from original plant resins. It is ubiquitous in North American coals. It makes up one to four percent by volume of most Illinois coals. It has been commercially exploited in the western USA for use in adhesives, varnishes and thermal setting inks. The overall objective of this project is to compare the properties of the resinite contained in Illinois Basin coals to resinite being commercially exploited in the western United States, and to recover the resinite from Illinois coals by microbubble column floatation techniques. The significance of this study is that it has the potential to show the way to recover a valuable chemical, resinite, from coal using only physical processing techniques. The value of the resinite at $1.00/kg or $0.50/lb makes it about fifty times more valuable than steam coal. The removal of resinite from coal does not decrease the value of the remaining coal in any way. The unique aspects are that: (1) it is the first examination of the resinite recovery potential of Illinois coal, (2) it integrates the latest characterization techniques such as density Gradient centrifugation, microspectrofluorometry, and gas chromatography- mass spectrometry, and (3) it uses microbubble column flotation to determine the resinite recovery potential. During this quarter samples were obtained, information from both the databases of both the Illinois State Geological Survey (ISGS) and the Pennsylvania State University (PSU) was obtained and evaluated, and EBCSP samples from the Herrin No. 6, the Springfield No. 5 and the Colchester No. 2 seams were analyzed petrographically and the resinites in these samples were characterized by fluorescence spectral analysis.

  10. The use of NMR techniques for the analysis of water in coal and the effect of different coal drying techniques on the structure and reactivity of coal. Final report

    SciTech Connect (OSTI)

    Netzel, D.A.; Miknis, F.P.; Wallace, J.C. Jr.; Butcher, C.H.; Mitzel, J.M.; Turner, T.F.; Hurtubise, R.J.

    1995-02-01T23:59:59.000Z

    Western Research Institute has conducted a study of different methods of coal drying as pretreatment steps before liquefaction. The objectives of this study were to develop a combined chemical dehydration/nuclear magnetic resonance (NMR) method for measuring the moisture content of coal, to measure the changes in coal structure that occur during drying, and to determine the effects of different drying methods on liquefaction reactivity of coals. Different methods of drying were investigated to determine whether coal drying can be accomplished without reducing the reactivity of coals toward liquefaction. Drying methods included thermal, microwave, and chemical dehydration. Coals of rank lignite to high volatile bituminous were studied. Coals that were dried or partially dried thermally and with microwaves had lower liquefaction conversions than coals containing equilibrium moisture contents. However, chemically dried coals had conversions equal to or greater than the premoisturized coals. The conversion behavior is consistent with changes in the physical structure and cross linking reactions because of drying. Thermal and microwave drying appear to cause a collapse in the pore structure, thus preventing donor solvents such as tetralin from contacting reactive sites inside the coals. Chemical dehydration does not appear to collapse the pore structure. These results are supported by the solvent swelling measurements in which the swelling ratios of thermally dried and microwave-dried coals were lower than those of premoisturized coals, indicating a greater degree of cross linking in the dried coals. The swelling ratios of the chemically dried coals were greater than those of the premoisturized coals because the pore structure remaining unchanged or increased when water was removed. These results are consistent with the NMR results, which did not show significant changes in coal chemical structure.

  11. Suppression of fine ash formation in pulverized coal flames. Quarterly technical progress report No. 4, July 1, 1993--September 30, 1993

    SciTech Connect (OSTI)

    Kramlich, J.C.; Hoffman, D.A.; Butcher, E.K.

    1993-10-29T23:59:59.000Z

    Laboratory work and studies of full-scale coal-fired boilers have identified two general mechanisms for ash production. The vast majority of the ash is formed from mineral matter that coalesces as the char burns, yielding particles that are normally larger than 0.5 {mu}m. The second major mechanism is the generation of a submicron aerosol through a vaporization/condensation mechanism. Previous work has shown that pulverized bituminous coals that were treated by coal cleaning (via froth flotation) or aerodynamic sizing exhibited altered aerosol emission characteristics. Specifically, the emissions of aerosol for the cleaned and sized coals increased by as much as one order of magnitude. The goals of the present progress are to: (1) perform measurements on carefully characterized coals to identify the means by which the coal treatment increases aerosol yields; (2) investigate means by which coal cleaning can be done in a way that will not increase aerosol yields; (3) identify whether this mechanism can be used to reduce aerosol yields from systems burning straight coal. This paper discusses model description and model formulation, and reports on the progress of furnace design and construction, and coal selection.

  12. VHF EPR quantitation and speciation of organic sulfur in coal. Technical report, September 1, 1993--November 30, 1993

    SciTech Connect (OSTI)

    Clarkson, R.B.; Belford, R.L. [Illinois Univ., Urbana, IL (United States)

    1993-12-31T23:59:59.000Z

    Over the last few years, we have developed a non-destructive technique called Very High Frequency Electron Paramagnetic Resonance (VHF-EPR) that is proving to be a practical and very sensitive analytical method for the organic sulfur in coal. Already, although still under development, the technique rapidly can quantify organic sulfur, and perhaps provide information on organic oxygen and nitrogen, in typical Illinois coals. At this stage, the precision is not well enough calibrated, and specificity for particular species needs more development. This year`s proposal outlined a 12 month work plan designed to improve and extend the utility of VHF-EPR. Two main goals of the work are: (1) refinement and calibration of organic sulfur analysis, in coals of differing rank, over a concentration range from 0.1% to 5%, and (2) better utilization of VHF-EPR coal spectral data for sulfur speciation. This quarter, goal (1) is being pursued; results will be ready to describe in a future report. Meanwhile, work toward goal (2) has produced detailed information about the VHF-EPR spectral behavior of several comparison compounds -- sulfur -- containing thiophenic fused-ring molecules.

  13. Coal Reburning for Cyclone Boiler NO{sub x} Control Demonstration. Quarterly report No. 11, October--December 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-31T23:59:59.000Z

    The project involves retrofitting/testing the reburning technology at Wisconsin Power & Light`s 100 MWe Nelson Dewey unit No. 2 in Cassville, Wisconsin to determine the commercial applicability of this technology to reduce NO{sub x} emission levels. The final set of performance tests on Lamar coal were carried out from September 27 through October 9, 1992. Hazardous air pollutant (HAP) testing was performed on Lamar coal from November 2 through November 9, 1992. Also, parametric optimization testing on western sub-bituminous coal was performed from November 16 through December 11, 1992. Both the HAP and western fuel testing were additions to the original project testing scope of Phase III. As of the end of this quarterly report period, project Phase III testing is complete. Preliminary results with western sub-bituminous coal indicate NO{sub 4} reductions in excess of 50% down to the 50% load range. In general, similar reductions are experienced but at a less aggressive stoichiometry in the reburn zone. Accordingly, an additional few percent of NO{sub 4} reduction at the same stoichiometry are noted with the western fuel compared to Lamar results.

  14. Graphic values for some organic constitutents of beneficiated coal samples. [Quarterly] report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Kohlenberger, L.B. [Illinois State Geological Survey, Champaign, IL (United States)

    1992-08-01T23:59:59.000Z

    Graphic techniques exist which can accurately predict values for calorific value, organic sulfur, and possibly other constituents of the organic portion of beneficiated coal sample fractions. These techniques also permit a determination of coal rank to be made without the use of the approximations required in the standard procedure. Fractions of IBC-101 with varying ash contents were produced by froth flotation. The various fractions were analyzed by the coal analysis laboratory and the particular data type was plotted in each case vs. the individual ash content of each fraction, using Lotus 123 and Freelace software packages. Such plots for calorific value and organic sulfur have, so far, been made. These curves and the information they contain are discussed in this report. A comparison of the graphic mineral matter value with the usual one calculated from the Parr approximation has been made. Eventually, the data may lead to an effective way to estimate inorganic carbon, hydrogen, nitrogen, and other organic constitents of coal. All data will be made available to researchers.

  15. Characterization of available coals from Illinois mines. Technical report, December 1, 1992--February 28, 1993

    SciTech Connect (OSTI)

    Demir, I.; Harvey, R.D.; Ruch, R.R.; Chaven, C.; Damberger, H.H.; Dreher, G.B.; Frankie, W.T. [Illinois Dept. of Energy and Natural Resources, Springfield, IL (United States). Geological Survey; Ho, K.K. [Illinois Clean Coal Inst., Carterville, IL (United States)

    1993-05-01T23:59:59.000Z

    The goal of this project is to characterize marketed coals from Illinois mines. The results generated by this project will promote Illinois coals for prospective new markets as feed materials for advanced gasification processes, for synthetic organic chemicals, and help asses future environmental requirements for abatement of noxious trace elements. The properties that are being determined include the concentration of all trace elements that are of environmental concern, the pyrite size distribution and maceral association, preliminary froth flotation cleanability, slagging and fouling characteristics relevant to the coal`s behavior in utility boilers, chlorine forms and distribution, and certain gasification and rheology parameters. We completed collection and processing of samples of 34 marketed coals that represent the products from a total of 40 mines. All the samples were submitted for standard coal and trace element analyses, and some of the analytical tasks were completed. There was a considerable amount of trace element data on face channel samples scattered in various files at the ISGS. In order to establish useful correlations between the marketed coal and face channel samples, the existing files were integrated and edited for accuracy and completeness.

  16. Demonstration of coal reburning for cyclone boiler NO{sub x} control. Final project report

    SciTech Connect (OSTI)

    Not Available

    1994-02-01T23:59:59.000Z

    As part of the US Department of Energy`s (DOE`s) Innovative Clean Coal Technology Program, under Round 2, a project for Full Scale Demonstration of Coal Reburning for Cyclone Boiler Nitrogen Oxide (NO{sub x},) Control was selected. DOE sponsored The Babcock & Wilcox (B&W) Company, with Wisconsin Power & Light (WP&L) as the host utility, to demonstrate coal reburning technology at WP&L`s 110 MW{sub c}, cyclone-fired Unit No.2 at the Nelson Dewey Generating Station in Cassville, Wisconsin. The coal reburning demonstration was justified based on two prior studies. An Electric Power Research Institute (EPRI) and B&W sponsored engineering feasibility study indicated that the majority of cyclone-equipped boilers could successfully apply reburning technology to reduce NO{sub x}, emissions by 50 to 70%. An EPRI/Gas Research Institute (GRI)/B&W pilot-scale evaluation substantiated this conclusion through pilot-scale testing in B&W`s 6 million Btu/hr Small Boiler Simulator. Three different reburning fuels, natural gas, No. 6 oil, and pulverized coal were tested. This work showed that coal as a reburning fuel performs nearly as well as gas/oil without deleterious effects of combustion efficiency. Coal was selected for a full scale demonstration since it is available to all cyclone units and represents the highest level of technical difficulty-in demonstrating the technology.

  17. Development of high energy density fuels from mild gasification of coal. Final report

    SciTech Connect (OSTI)

    Not Available

    1991-12-01T23:59:59.000Z

    METC has concluded that MCG technology has the potential to simultaneously satisfy the transportation and power generation fuel needs in the most cost-effective manner. MCG is based on low temperature pyrolysis, a technique known to the coal community for over a century. Most past pyrolysis developments were aimed at maximizing the liquids yield which results in a low quality tarry product requiring significant and capital intensive upgrading. By properly tailoring the pyrolysis severity to control the liquid yield-liquid quality relationship, it has been found that a higher quality distillate-boiling liquid can be readily ``skimmed`` from the coal. The resultant liquids have a much higher H/C ratio than conventional pyrolytic tars and therefore can be hydroprocessed at lower cost. These liquids are also extremely enriched in l-, 2-, and 3-ring aromatics. The co-product char material can be used in place of coal as a pulverized fuel (pf) for power generation in a coal combustor. In this situation where the original coal has a high sulfur content, the MCG process can be practiced with a coal-lime mixture and the calcium values retained on the char can tie up the unconverted coal sulfur upon pf combustion of the char. Lime has also been shown to improve the yield and quality of the MCG liquids.

  18. Resumption of SPR US Strategic Petroleum Reserve fill attached to synfuels bill

    SciTech Connect (OSTI)

    Not Available

    1980-06-23T23:59:59.000Z

    House-Senate conferees approved a bill which would establish a $20 billion US Synthetic Fuels Corp., a $3.1 billion bank to fund energy conservation and solar energy projects, a $1.4 billion biomass-to-energy program, and other energy conservation and production measures. An order requiring the filling of the SPR at a minimum average rate of 100,000 bbl/day beginning 10/1/80 was attached to the bill. If that rate is not achieved, the SPR measure requires that Elk Hills, Calif., field crude be sold or exchanged to acquire other crude for the SPR. Some OPEC members have threatened to reduce their output if the US buys oil for storage. The SPR measure will increase US refiners' crude-acquisition costs by $0.04/gal, which will be passed along to purchasers. The SPR goal is 750 million bbl of crude; current capacity is 250 million bbl, with only 91.7 million bbl in place. A House subcommittee issued a report recommending that the 118,000 bbl/day oil production from US National Petroleum Reserves (NPR) be reserved for the US Department of Defense (DOD) and stored in the SPR, but criticizing DOD for inefficiencies in its energy office, inadequate conversion to coal, and inadequate storage facilities.

  19. Mild coal pretreatment to improve liquefaction reactivity. Final technical report, September 1990--February 1994

    SciTech Connect (OSTI)

    Miller, R.L.; Shams, K.G.

    1994-07-01T23:59:59.000Z

    Recent research efforts in direct coal liquefaction are focused on lowering the level of reaction severity, identification and determination of the causes of retrogressive reactions, and improving the economics of the process. Ambient pretreatment of coals using methanol and a trace amount of hydrochloric acid was extensively studied in connection with low severity coal liquefaction. Ambient pretreatment of eight Argonne coals using methanol/HCl improved THF-soluble conversions 24.5 wt % (maf basis) for Wyodak subbituminous coal and 28.4 wt % for Beulah-Zap lignite with an average increase of 14.9 wt % for the eight Argonne coals at 623 K (350{degrees}C) reaction temperature and 30 minutes reaction time. Optimal pretreatment conditions were determined using Wyodak and Illinois No. 6 coals. Acid concentration was the most important pretreatment variable studied; liquefaction reactivity increased with increasing acid concentration up to 2 vol %. The FTIR spectra of treated and untreated Wyodak coal samples demonstrated formation of carboxylic functional groups during pretreatment, a result of divalent (Ca, Mg) cationic bridge destruction. The extent of liquefaction reactivity directly correlated with the amount of calcium removed during pretreatment, and results from calcium ``addback`` experiments supported the observation that calcium adversely affected coal reactivity at low severity reaction conditions. Model compound studies using benzyl phenyl ether demonstrated that calcium cations catalyzed retrogressive reactions, inhibited hydrogenation reactions at low severity reaction conditions, and were more active at higher reaction temperatures. Based on kinetic data, mechanisms for hydrogenation-based inhibition and base-catalyzed retrogressive reactions are proposed. The base-catalyzed retrogressive reactions are shown to occur via a hydrogen abstraction mechanism where hydrogenation inhibition reactions are shown to take place via a surface quenching mechanism.

  20. The use of ethanol to remove sulfur from coal. Final report, September 1991--December 1992; Revision

    SciTech Connect (OSTI)

    Savage, R.L.; Lazarov, L.K.; Prudich, M.E.; Lange, C.A.; Kumar, N.

    1994-03-10T23:59:59.000Z

    The initial technical goal in the project was to develop a chemical method for the cost effective removal of both inorganic and organic sulfur from Ohio coals. Verifying and using a process of reacting ethanol vapors with coal under conditions disclosed in U.S. Patent 4,888,029, the immediate technical objectives were to convert a small scale laborative batch process to a larger scale continuous process which can serve as the basis for commercial development of the technology. This involved getting as much information as possible from small scale batch autoclave or fluid bed laboratory reactors for use in pilot plant studies. The laboratory data included material balances on the coal and sulfur, temperature and pressure ranges for the reaction, minimum reaction times at different conditions, the effectiveness of different activators such as oxygen and nitric oxide, the amount and nature of by-products such as sulfur dioxide, hydrogen sulfide and acetaldehyde, the effect of coal particle size on the speed and completeness of the reaction, and the effectiveness of the reaction on different Ohio coals. Because the laboratory experiments using the method disclosed in U.S. 4,888,029 were not successful, the objective for the project was changed to develop a new laboratory process to use ethanol to remove sulfur from coal. Using copper as a catalyst and as an H{sub 2}S scavenger, a new laboratory procedure to use ethanol to remove sulfur from coal has been developed at Ohio University and a patent application covering this process was filed in March, 1993. The process is based on the use of copper as a catalyst for the dehydrogenation of ethanol to produce nascent hydrogen to remove sulfur from the coal and the use of copper as a scavenger to capture the hydrogen sulfide formed from the sulfur removed from coal.

  1. Characterization of available coals from Illinois mines. Final technical report, September 1, 1992--August 31, 1993

    SciTech Connect (OSTI)

    Demir, I.; Harvey, R.D.; Ruch, R.R.; Chaven, C.; Damberger, H.H.; Steele, J.D.; Frankie, W.T. [Illinois State Geological Survey, Champaign, IL (United States)

    1993-12-31T23:59:59.000Z

    The goal of this project was to characterize available product coals from Illinois mines. The characterization parameters that were determined include the concentration of all trace and minor elements that are of environmental concern, the pyrite size distribution and maceral association, preliminary froth flotation cleanability, slagging and fouling characteristics, chlorine forms and distribution, and certain gasification and rheology parameters. The available trace element data on Illinois coals, mainly on channel samples, was edited and updated with new records. The determinations of the trace and minor elements in 34 collected cleaned coal samples, as well as the proximate and ultimate compositions of 34 samples, were completed. In comparison with the previous channel sample data, the results indicated that the cleaning at existing preparation plants reduced the average concentrations of most of the trace elements in the coals. The data also indicated that the trace element concentrations in the product coals could be reduced further by advanced physical cleaning techniques. A sequential (hot water, dilute ammonia, and dilute sodium hydroxide) extraction procedure on three samples indicated variable chloride reductions. The pyrite cleanability index was determined microscopically for each sample. This index is a relative measure of the ease of pyrite removal from the tested sample. The froth flotation test data on 15 of the samples provided a measure of further cleanability of the product coals by physical fine coal cleaning. Viscosities of the 50% solid and <60 mesh particle size slurries of the same 15 samples revealed that these coals can be pumped in slurry form through a pipeline. Slagging and fouling indices, calculated for all 34 samples, indicated that most of the samples are of low to medium slagging and fouling types. Calculation of the gasification parameters indicated that the Illinois coals are in general amenable to gasification.

  2. The development of coal-based technologies for Department of Defense facilities. Volume 2, Appendices. Semiannual technical progress report, September 28, 1994--March 27, 1995

    SciTech Connect (OSTI)

    Miller, B.G.; Bartley, D.A.; Hatcher, P. [Pennsylvania State Univ., University Park, PA (United States). Energy and Fuels Research Center] [and others

    1996-10-15T23:59:59.000Z

    This semiannual progress report contains the following appendices: description of the 1,000 lb steam/h watertube research boiler; the Pennsylvania CGE model; Phase II, subtask 3.9 coal market analysis; the CGE model; and sector definition.

  3. Separation and structure elucidation of coal molecule fragments. Final report, February 1, 1976-August 31, 1979

    SciTech Connect (OSTI)

    Schultz, R V; Jorgenson, J W; Maskarinec, M P; Kump, R L; Marli, F; Novotny, M; Todd, L J

    1980-01-01T23:59:59.000Z

    Separation and identification of the polynuclear aromatic and aliphatic fractions of solvent-refined coal and its recycle oil were performed using a combination of solvent partition and chromatographic fractionation procedures with glass-capillary gas chromatography/mass spectrometry. Chromatographic profiles were generated for each fraction and some semiquantitative data were also obtained. In total, 146 polynuclear aromatic components of SRC were tentatively identified by their molecular weights, as indicated by the mass spectra of the gas chromatography peaks. In addition, wherever possible, specific isomers have been indicated, based on comparison of spectral characteristics and retention data. Separation and identification of nitrogen-containing aromatics of the recycle oil of SRC was accomplished with a combination solvent partition and capillary gas chromatography with deactivated glass columns. High-precision retention measurements of known pyridine and quinoline derivatives are reported, utilizing parent aza-arenes as retention standards. Both precisely measured retention data and mass spectral information combined lead to positive identification of some compounds in SRC samples. A total of 48 two-membered or three-membered aza-arenes have been tentatively identified in the recycle oil.

  4. AFBC co-firing of coal and hospital waste. Quarterly report, November 1995--January 1996

    SciTech Connect (OSTI)

    Stuart, J.M.

    1996-03-01T23:59:59.000Z

    The project objective is to design, construct, install provide operator training and start-up a circulating fluidized bed combustion system at the Lebanon Pennsylvania Veteran`s Affairs Medical Center. This unit will co-fire coal and hospital waste providing lower cost steam for heating and possibly cooling (absorption chiller) and operation of a steam turbine-generator for limited power generation while providing efficient destruction of both general and infectious hospital waste. Operating permits will be obtained after construction has been completed. The stack sampler has been selected. This vendor is currently developing the testing protocol. Severe weather in December and January caused work delays to the project, especially to outside work The fabrication and installation of the stack are complete. Only the insulation of the stack remains to be done. Budget problems began to occur in late January. Correction of this situation should occur shortly in February or March. A current schedule for the project is included with this report.

  5. Coal-fired furnace for testing of thermionic converters. Topical report

    SciTech Connect (OSTI)

    Not Available

    1980-10-01T23:59:59.000Z

    The development of thermionic converter technology has progressed to make near-term applications interesting. One of these applications is the thermionic topping of a pulverized coal-fired central station powerplant. Up to now, thermionic converters have been flame tested using natural gas as fuel. A new test furnace is required for evaluation of thermionic converters in a coal-fired environment. The design and costs of a facility which adapts a coal-fired furnace built by Foster Wheeler Development Corporation (FWDC) for thermionic converter testing are discussed. Such a facility would be exempt from air pollution regulations because of its low firing rate.

  6. Gasifier feed: Tailor-made from Illinois coals. Technical report, September 1, 1991--November 30, 1991

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III

    1991-12-31T23:59:59.000Z

    The purpose of this research is to develop a coal slurry from waste streams using Illinois coal that is ideally suited for a gasification feed. The principle items to be studied are (1) methods of concentrating pyrite and decreasing other ash forming minerals into a high grade gasification feed using froth flotation and gravity separation techniques; (2) chemical and particle size analyses of coal slurries; (3) determination of how that slurry can be densified and to what degree of densification is optimum from the pumpability and combustibility analyses; and (4) reactivity studies.

  7. Engineering support services for the DOE/GRI coal gasification research program. Final technical progress report, October 1978-November 1982

    SciTech Connect (OSTI)

    Bostwick, L.E.

    1982-01-01T23:59:59.000Z

    The agreement between the United States Government Department of Energy and the Gas Research Institute for the Joint Coal Gasification Research Program provided for one or more technical evaluation contractors. Pullman Kellogg (now the M.W. Kellogg Company) was selected as evaluation contractor to assess, and report to the DOE/GRI Operating Committee on, the relative merits of the active programs covered by the agreement. This report includes the period from 1 October 1978 to 30 November 1982. The objective was to provide engineering support for the DOE/GRI high Btu coal gasification program. This support generally consisted of assistance in developing or advancing each process to its maximum potential. Kellogg monitored and evaluated the startup and operational activities of all pilot plant projects within the combined DOE/GRI program. Kellogg evaluated proposals to determine their technical feasibility as potential processes or as viable processing operations for commercial-scale gasification of coal. Kellogg also recorded observations on the reliability, maintainability, and availability of the equipment used in the pilot plant or PDU facilities. Kellogg performed design reviews, data analyses, and engineering evaluations of proposals, cost estimates and monthly progress reports to provide information considered essential to the overall objectives of the combined DOE/GRI program.

  8. Industrial application fluidized bed combustion. Category III: indirect fired heaters. Quarterly technical report No. 16, April 1-June 30, 1980

    SciTech Connect (OSTI)

    Not Available

    1980-01-01T23:59:59.000Z

    The High Temperature Heat Flux Test Unit was put into operation during July 1979. Tests using both propane and coal fuels have been completed. Test results are summarized in this report. The object of the Economic and Applications Task of the Program is to evaluate the economic and logistic factors that might influence the schedule and circumstances under which coal fired Atmospheric Fluidized Bed Combustion (AFBC) technology might be applied to petroleum and petrochemical plant process heaters. The results of these studies indicate that the potential for near term application of AFBC technology to refinery crude heaters is relatively low. A possible alternative application of FBC heaters in the Exxon Donor Solvent Process for the liquefaction of coal has been identified. In this alternative an FBC heater would be used to burn the heavy vacuum tower bottoms. A preliminary design of such a heater has been completed and released to the Exxon Synfuels Division for further evaluation. The final task of the program will be to prepare a design specification for a hypothetical commercial sized process heater from which all interested parties can make a definitive evaluation of the technical and commercial prospects of the technology. This design work is now underway.

  9. State coal profiles, January 1994

    SciTech Connect (OSTI)

    Not Available

    1994-02-02T23:59:59.000Z

    The purpose of State Coal Profiles is to provide basic information about the deposits, production, and use of coal in each of the 27 States with coal production in 1992. Although considerable information on coal has been published on a national level, there is a lack of a uniform overview for the individual States. This report is intended to help fill that gap and also to serve as a framework for more detailed studies. While focusing on coal output, State Coal Profiles shows that the coal-producing States are major users of coal, together accounting for about three-fourths of total US coal consumption in 1992. Each coal-producing State is profiled with a description of its coal deposits and a discussion of the development of its coal industry. Estimates of coal reserves in 1992 are categorized by mining method and sulfur content. Trends, patterns, and other information concerning production, number of mines, miners, productivity, mine price of coal, disposition, and consumption of coal are detailed in statistical tables for selected years from 1980 through 1992. In addition, coal`s contribution to the State`s estimated total energy consumption is given for 1991, the latest year for which data are available. A US summary of all data is provided for comparing individual States with the Nation as a whole. Sources of information are given at the end of the tables.

  10. Characterization of the surface properties of Illinois Basin coals. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Demir, I.; Harvey, R.D.; Lizzio, A.A.

    1992-08-01T23:59:59.000Z

    Understanding the surface properties of coal is important for predicting the physical-chemical behavior of coal during coal cleaning combustion and conversion. Data on surface properties help coal scientists and engineers in the design of effective coal desulfurization processes, and thereby aid in the marketability of Illinois Basin coals. The main objective of this project is to characterize the surface properties (surface area, porosity, pore size distribution, surface charge, and surface chemical structure) of eight coals in the Illinois Basin Coal Sample Program (IBCSP), and explore statistical relationships between surface properties and other coal characteristics.

  11. Mechanisms of syncrude/synfuel degradation: Fourth and final report, October 1, 1984-December 31, 1986

    SciTech Connect (OSTI)

    Beal, E.J.; Cooney, J.V.; Hazlett, R.N.; Morris, R.E.; Mushrush, G.W.; Beaver, B..; Hardy, D.R.

    1987-04-01T23:59:59.000Z

    Much of the effort during the final period of this project dealt with interactions between co-dopants added to a stable shale derived diesel fuel. Five classes of nitrogen compounds have been examined in detail. A substituted pyridine and a substituted quinoline behave similarly, exhibiting only minor interactions with t-butylhydroperoxide (TBHP), organic bases and weak organic acids, but forming large amounts of insolubles with a sulfonic acid. Dimethylpyrrole (DMP) interacted strongly with TBHP, weak and strong organic acids to produce increased amounts of sediments but interacted only weakly with organic bases. 3-Methylindole exhibited interaction behavior similar to DMP but the positive interaction was significantly enhanced by venting of sample flasks. Dodecahydrocarbazole showed a distinctive pattern of behavior, a strong positive increase in insolubles with TBHP or tributylamine but a substantial decrease with acids, both carboxylic and sulfonic. Widely used fuel stabilizers were ineffective in reducing sediment formation by 2,5-DMP. An intermediate stream from a shale refining process was moderately stable although it was high in nitrogen content, (2290 ppM w/v). Consecutive treatments with dilute HCl and silica gel significantly improved the stability of this liquid. The extracts contained substantial amounts of pyridines and tetrahydroquinolines with smaller amounts of hydrocarbons and other nitrogen compounds. The most polar of the extracts, that stripped from the silicagel by methanol, was a potent sediment producer, on par with DMP on an equivalent nitrogen basis. Light scattering easily detected formation of larger molecules for stressed shale derived diesel fuel containing DMP. However, formation of copious amounts of insolubles prevented the use of this technique as a useful quantitative tool for evaluating fuel instability. 42 refs., 5 figs., 54 tabs.

  12. Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1990--June 1991

    SciTech Connect (OSTI)

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01T23:59:59.000Z

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  13. Cooperative research in coal liquefaction. Final report, May 1, 1992--April 30, 1993

    SciTech Connect (OSTI)

    Huffman, G.P. [ed.

    1996-03-01T23:59:59.000Z

    Research on sulfate and metal (Mo, Sn) promoted Fe{sub 2}O{sub 3} catalysts in the current year focused on optimization of conditions. Parameters varied included temperature, solvent, solvent-to-coal ratio, and the effect of presulfiding versus in situ sulfiding. Oil yields were found to increase approximately proportionately with both temperature and solvent-to-coal ratio. The donor solvent, tetralin, proved to give better total conversion and oil yields than either 1-methylnaphthalene or Wilsonville recycle oil. A significant enhancement of both total liquefaction yields and oil yields from lignites and subbituminous coals has been achieved by incorporating iron into the coal matrix by cation exchange. A study has been conducted on the synthesis of iron, molybdenum, and tungsten catalysts using a laser pyrolysis technique.

  14. Coal-log pipeline system development. Fifth quarterly report, August 25, 1991--November 25, 1991

    SciTech Connect (OSTI)

    Liu, H.

    1991-12-01T23:59:59.000Z

    Project tasks include: (1) Perform the necessary testing and development to demonstrate that the amount of binder in coal logs can be reduced to 8% or lower to produce logs with adequate strength to eliminate breakage during pipeline transportation, under conditions experienced in long distance pipeline systems. Prior to conducting any testing and demonstration, grantee shall perform an information search and make full determination of all previous attempts to extrude or briquette coal, upon which the testing and demonstration shall be based. (2) Perform the necessary development to demonstrate a small model of the most promising injection system for coal-logs, and tests the logs produced. (3) Conduct economic analysis of coal-log pipeline, based upon the work to date. Refine and complete the economic model. (VC)

  15. Stress evaluation of welded steel bridges on coal-haul routes. Interim research report

    SciTech Connect (OSTI)

    Hopwood, T.; Hogan, K.J.; Oberst, C.M.

    1993-05-01T23:59:59.000Z

    Certain roads in Kentucky are designated as `extended-weight coal haul routes.` On those roads, coal transporters are allowed to employ coal trucks loaded far in excess of legal limits in force on normal roads throughout the state. The objective of this study is to measure live-load stresses on welded steel bridges on extended-weight coal haul routes. Fatigue analyses are performed on strain (stress) data derived from field stress measurements. Those are performed to determine whether the magnitude of those stresses and frequency of their occurrence are sufficient to pose fatigue problems presently or over the anticipated service lives of those bridges (i.e., 75 years). Live-load stress data obtained from bridges not possessing fatigue-prone weld details may be of benefit to bridge designers.

  16. Geochemistry of a reclaimed coal slurry impoundment. [Quarterly] technical report, December 1, 1993--February 28, 1994

    SciTech Connect (OSTI)

    Dreher, G.B.; Roy, W.R.; Steele, J.D.; Heidari, M. [Illinois State Geological Survey, Champaign, IL (United States)

    1994-06-01T23:59:59.000Z

    The highly alkaline residue from the fluidized-bed combustion (FBC) of coal may be an environmentally acceptable material for use in neutralizing acid produced by the oxidation of pyrite in coal slurry solids (CSS). Previous research indicated that FBC residues in mixtures with pyrite-rich CSS neutralized the acid produced by or attenuated the oxidation of pyrite in CSS. In the present research we intend to collect cores of unconsolidation material and sample pore gases from a reclaimed coal slurry impoundment. The data gathered will provide background information necessary for the development of a predictive computer model of the generation and migration of acid in a reclaimed coal slurry impoundment. The conceptual model for the oxidation of pyrite at near-neutral conditions has been revised. The model is being built around the method of Morel and Hering (1993) and Westall (1986).

  17. High performance materials in coal conversion utilization. Technical progress report, April 1, 1996--June 30, 1996

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    Object is to test, analyze, and improve the heat and coal-slag corrosion resistance of a SiC(p)/Al{sub 2}O{sub 3} ceramic composite tubular material. The material will be evaluated for resistance to pressures, temperatures, and corrosion within a coal-fired high- temperature, high-pressure air heater. Microstructures and some mechanical properties of composite tubes were studied. Other studies include corrosion thermodynamic analysis of Al oxide coated composite.

  18. Combustion characterization of beneficiated coal-based fuels. Quarterly report No. 18, July--September 1993

    SciTech Connect (OSTI)

    Chow, O.K.; Hargrove, M.J.

    1993-11-01T23:59:59.000Z

    The Pittsburgh Energy Technology Center of the US Department of Energy has contracted with Combustion Engineering, Inc. (CE) to perform a five-year project on ``Combustion Characterization of Beneficiated Coal-Based Fuels.`` The beneficiated coals are produced by other contractors under the DOE Coal Preparation Program. Several contractor-developed advanced coal cleaning processes are run at pilot-scale cleaning facilities to produce 20-ton batches of fuels for shipment to CE`s laboratory in Windsor, Connecticut. CE then processes the products into either a coal-water fuel (CWF) or a dry microfine pulverized coal (DMPC) form for combustion testing. The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of BCFs influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs. The technical approach used to develop the technical data includes: bench-scale fuel property, combustion, and ash deposition tests; pilot-scale combustion and ash effects tests; and full-scale combustion tests. During the third quarter of 1993, the following technical progress was made: Continued with data and sample analysis from the pilot-scale tests of Upper Freeport feed coal, air-dried and mulled microagglomerate products; air-dried Pittsburgh No. 8 as-is and mulled products for upcoming Task 3 combustion testing; and prepared two abstracts for presentation for the March 1 994 Coal Utilization and Fuel Systems Conference.

  19. Demonstration of coal mine illumination systems. Open file report (final) October 1977-June 1980

    SciTech Connect (OSTI)

    Szpak, A.D.; Hahn, W.F.; Skinner, C.S.

    1981-01-01T23:59:59.000Z

    The purpose of this program was to demonstrate the feasibility of illuminating various types of underground coal mining machinery as required by the Federal Coal Mine Illumination Standards Part 75.1719 to 75.1719-4 Code of Federal Regulations Title 30. Nine various machines were illuminated and the illumination systems were evaluated for a 3-month period. Factors evaluted were ease of implementation, reliability, ease of maintenance, acceptance by mine workers and operations, illumination degradation, and durability.

  20. Coal-fueled diesel technology development. Final report, March 3, 1988--January 31, 1994

    SciTech Connect (OSTI)

    none,

    1994-01-31T23:59:59.000Z

    Since 1979, the US Department of Energy has been sponsoring Research and Development programs to use coal as a fuel for diesel engines. In 1984, under the partial sponsorship of the Burlington Northern and Norfolk Southern Railroads, GE completed a 30-month study on the economic viability of a coal-fueled locomotive. In response to a GE proposal to continue researching the economic and technical feasibility of a coal-fueled diesel engine for locomotives, DOE awarded a contract to GE Corporate Research and Development for a three-year program that began in March 1985 and was completed in 1988. That program was divided into two parts: an Economic Assessment Study and a Technical Feasibility Study. The Economic Assessment Study evaluated the benefits to be derived from development of a coal-fueled diesel engine. Seven areas and their economic impact on the use of coal-fueled diesels were examined; impact on railroad infrastructure, expected maintenance cost, environmental considerations, impact of higher capital costs, railroad training and crew costs, beneficiated coal costs for viable economics, and future cost of money. The Technical Feasibility Study used laboratory- and bench-scale experiments to investigate the combustion of coal. The major accomplishments of this study were the development of injection hardware for coal water slurry (CWS) fuel, successful testing of CWS fuel in a full-size, single-cylinder, medium-speed diesel engine, evaluation of full-scale engine wear rates with metal and ceramic components, and the characterization of gaseous and particulate emissions. Full combustion of CWS fuel was accomplished at full and part load with reasonable manifold conditions.

  1. Catalytic Two-Stage Liquefaction (CTSL{trademark}) process bench studies and PDU scale-up with sub-bituminous coal. Final report

    SciTech Connect (OSTI)

    Comolli, A.G.; Johanson, E.S.; Karolkiewicz, W.F.; Lee, L.K.T.; Stalzer, R.H.; Smith, T.O.

    1993-03-01T23:59:59.000Z

    Reported are the details and results of Laboratory and Bench-Scale experiments using sub-bituminous coal conducted at Hydrocarbon Research, Inc., under DOE Contract No. DE-AC22-88PC88818 during the period October 1, 1988 to December 31, 1992. The work described is primarily concerned with testing of the baseline Catalytic Two-Stage Liquefaction (CTSL{trademark}) process with comparisons with other two stage process configurations, catalyst evaluations and unit operations such as solid separation, pretreatments, on-line hydrotreating, and an examination of new concepts. In the overall program, three coals were evaluated, bituminous Illinois No. 6, Burning Star and sub-bituminous Wyoming Black Thunder and New Mexico McKinley Mine seams. The results from a total of 16 bench-scale runs are reported and analyzed in detail. The runs (experiments) concern process variables, variable reactor volumes, catalysts (both supported, dispersed and rejuvenated), coal cleaned by agglomeration, hot slurry treatments, reactor sequence, on-line hydrotreating, dispersed catalyst with pretreatment reactors and CO{sub 2}/coal effects. The tests involving the Wyoming and New Mexico Coals are reported herein, and the tests involving the Illinois coal are described in Topical Report No. 2. On a laboratory scale, microautoclave tests evaluating coal, start-up oils, catalysts, thermal treatment, CO{sub 2} addition and sulfur compound effects were conducted and reported in Topical Report No. 3. Other microautoclave tests are described in the Bench Run sections to which they refer such as: rejuvenated catalyst, coker liquids and cleaned coals. The microautoclave tests conducted for modelling the CTSL{trademark} process are described in the CTSL{trademark} Modelling section of Topical Report No. 3 under this contract.

  2. Mineralogy of Alabama coals. Annual report for the 1983-84 Project Year

    SciTech Connect (OSTI)

    Fang, J.H.; Donahoe, J.L.; Grow, A.G.

    1985-08-01T23:59:59.000Z

    Forty-one coal samples collected from the Pennsylvanian Pottsville Formation in the Black Warrior basin of Alabama were (low-temperature) plasma ashed to yield minerals. These lta ashes were qualitatively and quantitatively analyzed by x-ray diffraction techniques. The major minerals are kaolinite, illite, mixed-layer clays, pyrite, quartz, and gypsum. Trace amounts of feldspars, siderite, marcasite, calcite, and dolomite were also found. Chlorite, in variable amounts, is found in most samples. Quantitative analysis was carried out by the internal standard method for nonclay minerals. For clay minerals, a modified Schultz's method was employed. The relative abundances of the major minerals are variable - total clays range from 63 to 91%; quartz, from 1 to 21%; pyrite, from trace amount to as much as 64%, due to pyrite nodules. Among clay minerals, kaolinite ranges from 29 to 70% (of the total clay); illite from 14 to 57%; mixed-layer clays from 10 to 34%. Smectite is found only in three samples, and chlorite is quite common, ranging from trace amount to 11%. Coal minerals are genetically classified into: syngenetic (detrital) and epigenetic (diagenetic). Syngenetic minerals, especially pyrite and clays, are not only important geologically, but also technologically in terms of coal preparation. Mineral analysis of coal ash helps identify some of the problems associated with sulphur and ash removal from coal. Some further studies are suggested in order to better understand the Alabama coal from the geological and technological points of view. 14 refs., 8 figs., 5 tabs.

  3. Fundamental research on novel process alternatives for coal gasification: Final report

    SciTech Connect (OSTI)

    Hill, A H; Knight, R A; Anderson, G L; Feldkirchner, H L; Babu, S P

    1986-10-01T23:59:59.000Z

    The Institute of Gas Technology has conducted a fundamental research program to determine the technical feasibility of and to prepare preliminary process evaluations for two new approaches to coal gasification. These two concepts were assessed under two major project tasks: Task 1. CO/sub 2/-Coal Gasification Process Concept; Task 2. Internal Recirculation Catalysts Coal Gasification Process Concept. The first process concept involves CO/sub 2/-O/sub 2/ gasification of coal followed by CO/sub 2/ removal from the hot product gas by a solid MgO-containing sorbent. The sorbent is regenerated by either a thermal- or a pressure-swing step and the CO/sub 2/ released is recycled back to the gasifier. The product is a medium-Btu gas. The second process concept involves the use of novel ''semivolatile'' materials as internal recirculating catalysts for coal gasification. These materials remain in the gasifier because their vapor pressure-temperature behavior is such that they will be in the vapor state at the hotter, char exit part of the reactor and will condense in the colder, coal-inlet part of the reactor. 21 refs., 43 figs., 43 tabs.

  4. Characterization of available coals from Illinois mines. [Quarterly] technical report, March 1, 1993--May 31, 1993

    SciTech Connect (OSTI)

    Demir, I.; Harvey, R.D.; Ruch, R.R.; Chaven, C.; Damberger, H.H.; Steele, J.D.; Frankie, W.T. [Illinois State Geological Survey, Champaign, IL (United States)

    1993-09-01T23:59:59.000Z

    The goal of this project is to characterize marketed coals from Illinois mines. The characterization parameters that are being determined include the concentration of all trace and minor elements that are of environmental concern, proximate and ultimate compositions, the pyrite size distribution and maceral association, preliminary froth flotation cleanability, slagging and fouling characteristics relevant to the coal`s behavior in utility boilers, chlorine forms and distribution, and certain gasification and rheology parameters. During the third quarter, the trace element data base on Illinois coals was fully checked and edited. The determinations of the trace and minor element contents and proximate and ultimate compositions of the 34 project samples were largely completed. The pyritic S content, still high in some of the marketed samples, could be reduced further in the samples by advanced physical cleaning techniques. Results from the analysis of all 34 samples for Ba, Hg, Mn, and Zr indicate that these elements are primarily or partly associated with mineral matter and, therefore, their concentrations could also be reduced further in the product coals by advanced physical cleaning techniques. A sequential extraction of Cl from two of the samples revealed that regardless of the initial chlorine concentration of the two coals, the total combined amount of chlorine extracted by water, ammonia, and sodium hydroxide is about the same.

  5. Coal combustion products: trash or treasure?

    SciTech Connect (OSTI)

    Hansen, T.

    2006-07-15T23:59:59.000Z

    Coal combustion by-products can be a valuable resource to various industries. The American Coal Ash Association (ACAA) collects data on production and uses of coal combustion products (CCPs). 122.5 million tons of CCPs were produced in 2004. The article discusses the results of the ACCA's 2004 survey. Fly ash is predominantly used as a substitute for Portland cement; bottom ash for structural fill, embankments and paved road cases. Synthetic gypsum from the FGD process is commonly used in wallboard. Plant owners are only likely to have a buyer for a portion of their CCPs. Although sale of hot water (from Antelope Valley Station) from condensers for use in a fish farm to raise tilapia proved unviable, the Great Plains Synfuels Plant which manufactures natural gas from lignite produces a wide range of products including anhydrous ammonia, phenol, krypton, carbon dioxide (for enhanced oil recovery), tar oils and liquid nitrogen. ACCA's goal is to educate people about CCPs and how to make them into useful products, and market them, in order to reduce waste disposal and enhance revenue. The article lists members of the ACCA. 2 photos., 1 tab.

  6. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Chou, M.I.M; Lytle, J.M.; Ruch, R.R.; Kruse, C.W.; Chaven, C.; Hackley, K.C.; Hughes, R.E.; Harvey, R.D.; Frost, J.K. [Illinois State Geological Survey, Champaign, IL (United States); Buchanan, D.H. [Eastern Illinois Univ., Charleston, IL (United States); Stucki, J.W. [Illinois Univ., Urbana, IL (United States); Huffman, G.; Huggins, F.E. [Kentucky Univ., Lexington, KY (United States)

    1992-09-01T23:59:59.000Z

    A pre-combustion coal desulfurization process at 120{degree}C using perchloroethylene (PCE) to remove up to 70% of the organic sulfur has been developed by the Midwest Ore Processing Co. (MWOPC). However, this process has not yet proven to be as successful with Illinois coals as it has for Ohio and Indiana coals. In addition, the high levels of organic sulfur removals observed by the MWOPC may be due to certain errors involved in the ASTM data interpretation; this needs verification. For example, elemental sulfur extracted by the PCE may be derived from pyrite oxidation during coal preoxidation, but it may be interpreted as organic sulfur removed by the PCE using ASTM analysis. The purposes of this research are to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process reported by the MWOPC and to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation.

  7. Coal: the new black

    SciTech Connect (OSTI)

    Tullo, A.H.; Tremblay, J.-F.

    2008-03-15T23:59:59.000Z

    Long eclipsed by oil and natural gas as a raw material for high-volume chemicals, coal is making a comeback, with oil priced at more than $100 per barrel. It is relatively cheap feedstock for chemicals such as methanol and China is building plants to convert coal to polyolefins on a large scale and interest is spreading worldwide. Over the years several companies in the US and China have made fertilizers via the gasification of coal. Eastman in Tennessee gasifies coal to make methanol which is then converted to acetic acid, acetic anhydride and acetate fiber. The future vision is to convert methanol to olefins. UOP and Lurgi are the major vendors of this technology. These companies are the respective chemical engineering arms of Honeywell and Air Liquide. The article reports developments in China, USA and India on coal-to-chemicals via coal gasification or coal liquefaction. 2 figs., 2 photo.

  8. Development of a coal fired pulse combustor for residential space heating. Technical progress report, July--September 1987

    SciTech Connect (OSTI)

    NONE

    1987-12-31T23:59:59.000Z

    The systematic development of the residential combustion system is divided into three phases. Only Phase I is detailed here. Phase I constitutes the design, fabrication, testing, and evaluation of a pulse combustor sized for residential space heating. Phase II is an optional phase to develop an integrated system including a heat exchanger. Phase III is projected as a field test of the integrated coal-fired residential space heater. The Phase I effort was nearing completion during this reporting period and a final report is in preparation. The configuration testing was completed early in the period and based upon results of the configuration tests, an optimized configuration for the experimental development testing was chosen. The refractory-lined chambers were fabricated and tested from mid-September through early October. The tandem unit was operated on dry micromized coal without support gas or excitation air for periods lasting from one to three hours. Performance was stable and turndown ratios of 3:1 were achieved during the first three-hour test. A early commercial residential heating system configuration has been identified on the basis of the development testing conducted throughout the first phase of this effort. The development effort indicates that the residential unit goals are achievable with some additional product improvement effort to increase carbon burn-out efficiency, reduce CO emissions and develop a reliable and compact dry, ultrafine coal feed system (not included in the present effort).

  9. The development of coal-based technologies for Department of Defense facilities. Semiannual technical progress report, September 28, 1992--March 27, 1993

    SciTech Connect (OSTI)

    Miller, B.G.; Scaroni, A.W.; Hogg, R. [and others

    1993-05-13T23:59:59.000Z

    The US Department of Defense (DOD), through an Interagency Agreement with the US Department of Energy (DOE), has initiated a three-phase program with the Consortium for Coal-Water Slurry Fuel Technology, with the aim of decreasing DOD`s reliance on imported oil by increasing its use of coal. The program is being conducted as a cooperative agreement between the Consortium and DOE and the first phase of the program is underway. Phase I activities are focused on developing clean, coal-based combustion technologies for the utilization of both micronized coal-water mixtures (MCWMs) and dry, micronized coal (MC) in fuel oil-designed industrial boilers. Phase II research and development activities will continue to focus on industrial boiler retrofit technologies by addressing emissions control and pre-combustion (i.e., slagging combustion and/or gasification) strategies for the utilization of high ash and high sulfur coals. Phase III activities will examine coal-based fuel combustion systems that cofire wastes. Each phase includes an engineering cost analysis and technology assessment. The activities and status of Phase I are described below. The objective in Phase I is to deliver fully engineered retrofit options for a fuel oil- designed watertube boiler located on a DOD installation to fire either MCWM or MC. This will be achieved through a program consisting of the following five tasks: (1) Coal Beneficiation and Preparation; (2) Combustion Performance Evaluation; (3) Engineering Design; (4) Engineering and Economic Analysis; (5) Final Report/Submission of Design Package.

  10. Char particle fragmentation and its effects on unburned carbon during pulverized coal combustion. Quarterly report, January 1, 1995--March 31, 1995

    SciTech Connect (OSTI)

    Mitchell, R.E.

    1995-08-01T23:59:59.000Z

    This document is the tenth quarterly status report of work on a project concerned with the fragmentation of char particles during pulverized coal combustion that is being conducted at the High Temperature Gasdynamics Laboratory at Stanford University. The project is intended to satisfy, in part, PETC`s research efforts to understand the chemical and physical processes that govern coal combustion. The work is pertinent to the char oxidation phase of coal combustion and focuses on how the fragmentation of coal char particles affects overall mass loss rates and how char fragmentation phenomena influence coal conversion efficiency. The knowledge and information obtained will allow the development of engineering models that can be used to predict accurately char particle temperatures and total mass loss rates during pulverized coal combustion. The overall objectives of the project are: (1) to characterize fragmentation events as a function of combustion environment, (2) to characterize fragmentation with respect to particle porosity and mineral loadings, (3) to assess overall mass loss rates with respect to particle fragmentation, and (4) to quantify the impact of fragmentation on unburned carbon in ash. The knowledge obtained during the course of this project will be used to predict accurately the overall mass loss rates of coals based on the mineral content and porosity of their chars. The work will provide a means of assessing reasons for unburned carbon in the ash of coal fired boilers and furnaces. Accomplishments for this period are presented for Task 3, char fragmentation studies and Task 4, fragmentation modelling.

  11. Coal-fired high performance power generating system. Draft quarterly progress report, January 1--March 31, 1995

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    This report covers work carried out under Task 3, Preliminary R and D, under contract DE-AC22-92PC91155, ``Engineering Development of a Coal-Fired High Performance Power Generation System`` between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of >47% thermal efficiency; NO{sub x}, SO{sub x} and particulates {le} 25% NSPS; cost {ge}65% of heat input; all solid wastes benign. A crucial aspect of the authors design is the integration of the gas turbine requirements with the HITAF output and steam cycle requirements. In order to take full advantage of modern highly efficient aeroderivative gas turbines they have carried out a large number of cycle calculations to optimize their commercial plant designs for both greenfield and repowering applications.

  12. Innovative process for concentration of fine particle coal slurries. Technical report, March 1- May 31, 1996

    SciTech Connect (OSTI)

    Rajchel, M.; Ehrlinger, H.P.; Fonseca, A.; Mauer, R.

    1996-12-31T23:59:59.000Z

    Williams Technologies, Inc. And Clarke Rajchel Engineering are developing a technology (patent pending) to produce high quality coal water slurries from preparation plant fine coal streams. The WTI/CRE technology uses the novel implementation of high-shear cross-flow separation which replaces and enhances conventional thickening processes by surpassing normally achievable solids loadings. Dilute ultra-fine (minus 100 mesh) solids slurries can be, concentrated to greater than 60 weight percent and re-mixed, as required, with de-watered coarser fractions to produce pumpable, heavily loaded coal slurries. The permeate (filtrate) resulting from this process has been demonstrated to be crystal clear and totally free of suspended solids. The primary objective of this project was to demonstrate the WTI/CRE coal slurry production process technology at the pilot scale. The technology can enable Illinois coal producers and users to realize significant cost and environmental benefits both by eliminating fine coal waste disposal problems and producing an IGCC fuel to produce power which meets all foreseeable clean air standards. Testing was also directed at concentrating mine tailings material to produce a tailings paste which can be mine-back-filled, eliminating the need for tailings ponds. During the grant period, a laboratory-scale test apparatus (up to 3 GPM feed rate) was assembled and operated to demonstrate process performance over a range of feed temperatures and pressures. A dilute coal/water slurry from Consol, Inc.`s Rend Lake Preparation Plant was concentrated using the process to a maximum recorded solids loading of 61.9% solids by weight. Analytical results from the concentrate were evaluated by Destec Energy for suitability as an IGCC fuel.

  13. The use of ethanol to remove sulfur from coal. Final report, September 1991--December 1992

    SciTech Connect (OSTI)

    Not Available

    1993-04-15T23:59:59.000Z

    In developing the new Ohio University procedure the thermodynamic limitations of the reactions for removal of both pyritic and organic sulfur from coal at 400--600{degrees}C were studied using copper as a very strong H{sub 2}S-acceptor. Copper serves as a catalyst for ethanol dehydrogenation to form nascent hydrogen. Copper also serves as a scavenger to form copper sulfide from the hydrogen sulfide evolved during the reaction. Copper sulfide in turn serves as a catalyst for organic sulfur hydrodesulfurization reactions. If the coal to be desulfurized contains pyrite (FeS{sub 2}) or FeS, the copper scavenger effect reduces any back reaction of hydrogen sulfide with the iron and increases the removal of sulfur from the carbonaceous material. The desired effect of using copper can be achieved by using copper or copper containing alloys as materials of construction or as liners for a regenerable reactor. During the time period that Ohio Coal Development Office supported this work, small scale (560 grams) laboratory experiments with coals containing about 3.5% sulfur have achieved up to 90% desulfurization at temperatures of 500{degrees}C when using a copper reactor. Results from the autoclave experiments have identified the nature of the chemical reactions taking place. Because the process removes both pyritic and organic sulfur in coal, the successful scale up of the process would have important economic significance to the coal industry. Even though this and other chemical processes may be relatively expensive and far from being commercial, the reason for further development is that this process may hold the promise of achieving much greater sulfur reduction and of producing a cleaner coal than other methods. This would be especially important for small or older power plants and industrial boilers.

  14. Dewatering studies of fine clean coal. Technical report, March 1, 1992--May 31, 1992

    SciTech Connect (OSTI)

    Parekh, B.K. [Kentucky Univ., Lexington, KY (United States). Center for Applied Energy Research

    1992-10-01T23:59:59.000Z

    Physical cleaning of ultra-fine coal using an advanced froth flotation technique provides a low ash product, however, due to high surface area of particles the amount of water associated with clean coal is high. Economic removal of water to 20 percent or lower moisture level from the clean coal froth will be important for commercial applicability of advanced froth flotation processes. The main objective of the present research program is to study and understand the dewatering characteristics of ultra-fine clean coal and to develop process parameters to effectively reduce the moisture to less than 20 percent in the clean coal product. The research approach under investigation utilizes synergistic effect of metal ions and surfactant to lower the moisture of clean coal using a conventional vacuum dewatering technique. The studies have identified a combination of metal ions and surfactant found to be effective in providing a 22 percent moisture filter cake. During the third quarter, efforts were made to understand reagent adsorption mechanism. Adsorption studies indicated that the presence of metal ions enhanced adsorption of surfactant. It appears that metal ions induced floc formation at pH {approximately}7.0, which are hydrophilic in nature, however addition of surfactant restores the hydrophobicity. Organic polymers along with metal ions were found to be effective in dewatering of fine coal. Continuous filtration tests conducted using a drum filter provided a filter cake containing 24 percent moisture. Additional studies on mechanism of adsorption and continuous filtration using AC Electro-Coagulation will be conducted in the next quarter.

  15. Coal transformation chemistry. Second quarterly progress report, June 1, 1980-August 31, 1980

    SciTech Connect (OSTI)

    Stock, Leon M.; Alemany, L. B.; Handy, C. I.; King, H. -H.

    1980-01-01T23:59:59.000Z

    A review of the information concerning the structure of Illinois No. 6 coal obtained in this laboratory and elsewhere provides the basis for a proposed structure for this bituminous coal. All the available facts concerning reduction, reductive alkylation, hydrogen atom exchange, oxidation, functional group analysis and so forth have been used to define a structural segment consisting of about 1000 atoms with a molecular weight in excess of 6000. This work is discussed in Part A. The study of the reductive alkylation reaction of Illinois No. 6 coal in liquid ammonia has been directed toward the optimization of the reaction conditions for the achievement of maximum solubility. The latest results indicate that about 55% of the original Illinois No. 6 coal can be converted to products which are soluble in tetrahydrofuran using potassium in liquid ammonia as the reducing agent and n-butyl iodide in tetrahydrofuran as the reducing alkylating agent. These observations are treated in Part B. The effort on donor solvent coal chemistry was directed to the role played by pericyclic reactions in the liquefaction process. The reactivity of a number of donors has been examined including 1,2- and 1,4-dihydronaphthalene. Although the research is not yet complete, the preliminary results indicate that free radical processes occur preferentially. Thus, the pericyclic reactions appear to be unimportant at the threshold reaction temperatures of 350 to 425/sup 0/C. This work is described in Part C.

  16. Impact of hydrogen partial pressure on coal liquefaction. Final technical report

    SciTech Connect (OSTI)

    Kang, D.; Hoover, D.S.; Schweighardt, F.K.

    1984-06-01T23:59:59.000Z

    This program was conducted to determine the effects of hydrogen partial pressure on the SRC-I direct coal liquefaction process and SRC-I Demonstration Plant design. A native solvent was produced in quantity and slurried with Kentucky number 9 Mulford coal in a series of coal liquefaction runs under varying hydrogen gas rates, temperatures, residence times, and hydrogen partial pressures. The results showed that hydrogen partial pressure significantly affected product distribution; the magnitude of the effect was comparable to changes in temperature and residence time. Also, the impact of hydrogen partial pressure was enhanced by increases in both temperature and residence time. Operating at low hydrogen partial pressure did not show any apparent advantage; it reduced coal conversion, reduced oil yield, and had a detrimental effect on the yield distribution of other products. An increase in hydrogen partial pressure had the following effects: increased coal conversion; increased conversion of asphaltenes and preasphaltenes to lighter products; significantly increased the oil yield; increased light gas yields; decreased sulfur content in the SRC; increased hydrogen content of the recycle solvent; and increased hydrogen consumption. This study strongly suggests that further studies should be conducted to optimize the effects of hydrogen partial pressure on the process, both within and, preferably, beyond the constraints of the current basic SRC-I design, considering the major impact of this variable on the process. 10 references, 37 figures, 10 tables.

  17. Development and evaluation of coal/water mixture combustion technology. Final report

    SciTech Connect (OSTI)

    Scheffee, R.S.; Rossmeissl, N.P.; Skolnik, E.G.; McHale, E.T.

    1981-08-01T23:59:59.000Z

    The objective was to advance the technology for the preparation, storage, handling and combustion of highly-loaded coal/water mixtures. A systematic program to prepare and experimentally evaluate coal/water mixtures was conducted to develop mixtures which (1) burn efficiently using combustion chambers and burners designed for oil, (2) can be provided at a cost less than that of No. 6 oil, and (3) can be easily transported and stored. The program consisted of three principal tasks. The first was a literature survey relevant to coal/water mixture technology. The second involved slurry preparation and evaluation of rheological and stability properties, and processing techniques. The third consisted of combustion tests to characterize equipment and slurry parameters. The first task comprised a complete search of the literature, results of which are tabulated in Appendix A. Task 2 was involved with the evaluation of composition and process variables on slurry rheology and stability. Three bituminous coals, representing a range of values of volatile content, ash content, and hardness were used in the slurries. Task 3 was concerned with the combustion behavior of coal/water slurry. The studies involved first upgrading of an experimental furnace facility, which was used to burn slurry fuels, with emphasis on studying the effect on combustion of slurry properties such as viscosity and particle size, and the effect of equipment parameters such as secondary air preheat and atomization.

  18. Preconversion processing of bituminous coals: New directions to improved direct catalytic coal liquefaction. Final report, September 20, 1991--September 19, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-09-01T23:59:59.000Z

    One of the main goals for competitive coal liquefaction is to decrease gas yields to reduce hydrogen consumption. Complexing this element as methane and ethane decreases process efficiently and is less cost effective. To decrease the gas yield and increase the liquid yield, an effective preconversion process has been explored on the basis of the physically associated molecular nature of coal. Activities have been focused on two issues: (1) maximizing the dissolution of associated coal and (2) defining the different reactivity associated with a wide molecular weight distribution. Two-step soaking at 350{degrees}C and 400{degrees}C in a recycle oil was found to be very effective for coal solubilization. No additional chemicals, catalysts, and hydrogen are required for this preconversion process. High-volatile bituminous coals tested before liquefaction showed 80--90% conversion with 50--55% oil yields. New preconversion steps suggested are as follows: (1) dissolution of coal with two-step high-temperature soaking, (2) separation into oil and heavy fractions of dissolved coal with vacuum distillation, and (3) selective liquefaction of the separated heavy fractions under relatively mild conditions. Laboratory scale tests of the proposed procedure mode using a small autoclave showed a 30% increase in the oil yield with a 15--20% decrease in the gas yield. This batch operation projects a substantial reduction in the ultimate cost of coal liquefaction.

  19. Influence of continuous-miner bit sharpness and coal-lithotype composition on coal breakage: examples from Kentucky mines. Technical report

    SciTech Connect (OSTI)

    Lineberry, G.T.; Rogers, F.D.; Leonard, J.W.; Hower, J.C.; Graese, A.M.

    1985-01-01T23:59:59.000Z

    This pilot study addresses the influence of coal lithotype, continuous miner bit sharpness, and coal hardness on particle sizing and liberation characteristics. The interface of the job end of the traditional continuous mining machine and the given geologic conditions at the job site; and their combined influence on particle sizing and liberation is investigated.

  20. Supercritical fluid thermodynamics for coal processing: Quarterly progress report, September 15, 1988--December 31, 1988

    SciTech Connect (OSTI)

    Eckert, C.A.

    1988-01-01T23:59:59.000Z

    Because of their unusual solvating and mass transfer properties, supercritical fluids show potential for a variety of coal processing applications. To establish a database of coal model compound equilibria, this quarter we have measured the solubility of 5,6-dimethyl-benzimidazole and anthraquinone in supercritical butane. In addition, we have used fluorescence spectroscopy to study the nature of the intermolecular interactions in the systems of pyrene and naphthalene in supercritical CO/sub 2/, C/sub 2/H/sub 4/, and CF/sub 3/H. The spectroscopy measurements are being used to guide the development of an equation of state that can be used to predict the solubility behavior so systems can be designed for the processing of coal with supercritical fluids. 4 figs.

  1. Oil shale, tar sands, and underground coal gasification. Quarterly progress report, July-September, 1983

    SciTech Connect (OSTI)

    Not Available

    1983-10-28T23:59:59.000Z

    Technical progress made for the second quarter, July 1, 1983 through September 30, 1983 are described for three areas, oil shale, tar sand and underground gasification of coal. The oil shale program is divided into the following tasks: chemistry and physics; retort bed analysis; novel processing methods; and environmental impact mitigation. The tar sand investigation covers: recovery processes; preparation; novel processing methods; and environmental impact mitigation. Underground coal gasification covers: recovery processes; field project evaluation; novel processing methods; and environmental impact mitigation. An executive summary is provided for the three programs. 19 figures, 23 tables.

  2. Technical and economic assessment of particle control technology for direct coal fueled turbines: Final report

    SciTech Connect (OSTI)

    DiBella, C.A.W.; Thomas, R.L.; Rubow, L.N.; Zaharchuk, R.

    1987-02-01T23:59:59.000Z

    Gilbert/Commomwealth (1984) analyzed ten different concepts for high-temperature, high-pressure control of gas stream particulate matter in coal-fueled pressurized fluidized-bed combustion (PFBC) systems. This paper analyzes the five higher ranking concepts of the Gilbert study at direct coal fueled turbine conditions which are even more severe than PFBC conditions. The five concepts are ceramic crossflow filter, ceramic bag filter, granular bed filter, and advanced cyclones. Five ranking factors were used: economic, design, operations complexity, materials/mechanical, and development status. (DLC)

  3. A computational model for coal transport and combustion. Quarterly technical progress report, June 1, 1993--August 31, 1993

    SciTech Connect (OSTI)

    Ahmadi, G.

    1993-12-31T23:59:59.000Z

    The objective of this project is to develop an accurate model describing turbulent flows of coal slurries, rapid flows of granular coal-air mixtures, and turbulent coal combustion processes. The other main objective is to develop a computer code incorporating the new model. Experimental verification of the foundation of the model is also included in the study. In this report the thermodynamically consistent, rate dependent model for turbulent two-phase flows analysis was used and the phasic fluctuation energy dissipation rates are evaluated. Further progress on the application of the kinetic model for rapid flows of granular materials including the frictional energy losses were made. The velocity, the fluctuation energy and the solid volume fraction profiles for granular flows down a vertical channel were obtained. The results were compared with the molecular dynamic simulations of Savage and good agreement was obtained. The computational model was used and the rapid granular flows around a rectangular block in a channel were analyzed. The effect of bumpy wall on flow of granular materials was analyzed. The special case of Couette flow was studied. The preliminary results obtained is quite encouraging. Further progress was made in the experimental study of mono-layer simple shear flow device. Preliminary data concerning the shearing of 12 mm multi-color glass particles are obtained.

  4. Coal Reburning for Cyclone Boiler NO{sub x} Control Demonstration. Quarterly report No. 10, July--September 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-18T23:59:59.000Z

    The Coal Reburning for Cyclone Boiler NO{sub x}, Control Demonstration project progress for July, August, and September 1992 is identified in this tenth quarterly report and pertains to the on-going activities of Phase III Operation and Disposition. The project involves retrofitting/testing the reburning technology at Wisconsin Power & Light`s 100 MWe Nelson Dewey Unit {number_sign}2 in Cassville, Wisconsin to determine the commercial applicability of this technology to reduce NO{sub x} emission levels. Phase III activities emphasized continuation of long-term testing. WP&L is operating the reburn system in full automatic in a load following mode, using Lamar coal, which is an Indiana bituminous medium sulfur content fuel. Reductions in NO{sub x} emissions continue at the 50%+ level with no apparent significant adverse impacts to boiler operation. As of the end of September, a second set of performance tests were initiated to determine if any performance impacts as a result of long-term operation have occurred. Data evaluation continued in an effort to design a testing sequence to more precisely evaluate reburn impact on unburned carbon. These tests will be carried out during the second set of performance tests in early October. Performance and mathematical modeling are being carried out to understand the cause of the reduction in furnace exit gas temperature observed during reburn testing on Lamar coal and to predict whether the same phenomenon will occur on future units where reburn technology is being considered.

  5. Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Technical progress report, October 1995--December 1995

    SciTech Connect (OSTI)

    Song, C.; Cooke, W.S.; Schmidt, E.; Schobert, H.H.

    1996-02-01T23:59:59.000Z

    Coal liquefaction involves cleavage of methylene, dimethylene and ether bridges connecting polycyclic aromatic units and the reactions of various oxygen functional groups. Here in this quarterly, we report on the catalytic effects of several molybdenum-, cobalt-, and iron-containing compounds in the reactions of dibenzothiophene (DBT) with hydrogen under conditions related to coal liquefaction. The catalytic effects of several molybdenum-, cobalt-, and iron-containing compounds have been examined in the hydrogenation and hydrodesulfurization reactions of dibenzothiophene (DBT) under conditions related to coal liquefaction. The metal compounds are candidate catalyst precursors for direct coal liquefaction. The reactions were carried out in batch microautoclave reactors at 400{degrees}C for 30 minutes with 6.9 MPa (cold) hydrogen pressure, and tridecane solvent. A metal loading of 0.5 mol% resulted in low conversion and only hydrogenation. Addition of sulfur in 4:1 molar ratio led only to a minor increase in conversion and hydrodesulfurization. The use of a higher boiling solvent (octadecane vs. tridecane) was beneficial in providing increased conversion, hydrodesulfurization, and hydrogenation. An increase in metal compound loading to 36.2 mol% led to a dramatic increase in conversion, hydrodesulfurization, and hydrocracking. Molybdenum hexacarbonyl at 36 mol% loading, with added sulfur at 6:1 ratio and octadecane solvent, gave 100% conversion of dibenzothiophene to other products with 100% hydrodesulfurization. Ammonium tetrathiomolybdate and molybdenum(III) chloride are less active under similar conditions. A cobalt-molybdenum thiocubane complex gave unexpectedly low conversions. Iron and cobalt carbonyls also provided very low conversions, even with added sulfur.

  6. Coal liquefaction process streams characterization and evaluation. Topical report: Analytical methods for application to coal-derived resids, A literature survey

    SciTech Connect (OSTI)

    Brandes, S.D.

    1993-06-01T23:59:59.000Z

    This literature survey was conducted to address an important question: What are the methods available in the realm of analytical chemistry that may have potential usefulness to the development of coal liquefaction technology? In an attempt to answer to that question, the emphasis of this survey was directed at analytical techniques which would be applicable to the high molecular weight, non-distillable residue of coal-derived liquids. It is this material which is most problematic to the analytical investigator and the developer of direct coal liquefaction processes. A number of comprehensive analytical reviews of literature dealing with coal and other fossil fuels are available. This literature survey will (1) be limited to articles published between 1980--1991, with some exceptions; (2) be limited to the use of analytical methods for high molecular weight, primarily nondistillable, fossil fuel-derived materials, except where the application of an analytical method to coals or distillates may show promise for application to non-distillable coal-derived materials; and (3) demonstrate the potential usefulness of an analytical method by showing how the method has been applied to high molecular weight, non-distillable materials, if not specifically to coal liquids. The text is divided by type of methodology, i.e. spectroscopy, microscopy, etc. Each section will be essentially free-standing. An historical background is provided.

  7. Oil shale, tar sands, and underground coal gasification. Quarterly progress report, April-June 1984

    SciTech Connect (OSTI)

    Not Available

    1984-08-15T23:59:59.000Z

    Highlights of progress achieved during the quarter ending June 30, 1984 are summarized. This research involves three resource areas: oil shale, tar sands, and underground gasification of coal. Separate abstracts have been prepared for each section for inclusion in the Energy Database. (DMC)

  8. Predictors of plasticity in bituminous coals. Technical progress report No. 7

    SciTech Connect (OSTI)

    Lloyd, W.G.; Reasoner, J.W.; Hower, J.C.; Yates, L.P.; Clark, C.P.; Davis, E.; Fitzpatrick, A.; Reagles, C.L.; Whitt, J.M.

    1983-06-13T23:59:59.000Z

    The 40-coal database for the prediction of the plastic properties of hvb coals has been completed. Statistical analysis has been commenced. Most of the 37 ostensibly independent experimental variables and the 22 derived variables are shown to have little or no predictive power. Approximately a dozen independent variables appear to be systematically related to plasticity. Maximum fluidity can be determined in several ways from Gieseler plastometer data. Under both ASTM and isothermal conditions, maximum fluidity can be predicted using just two independent variables with a standard linear regression model of the form ln(maximum fluidity) = ..beta../sub 0/ + ..beta../sub 1/*V/sub 1/ + ..beta../sub 2/*V/sub 2/ with correlation coefficients greater than .85. The use of three or four independent variables permits predictions with R greater than .90. Pyrolysis gas chromatography has emerged as a powerful and relatively inexpensive new tool for the characterization of coals. In conjunction with studies of extraction, extract characteristics, and residue swelling, pyrolysis/GC affords insights into the basic factors determining the plastic behavior of coals.

  9. Predictors of plasticity in bituminous coals. Technical progress report No. 3, June 1, 1982

    SciTech Connect (OSTI)

    Lloyd, W.G.; Reasoner, J.W.; Hower, J.C.; Yates, L.P.; Bowling, C.C.; Jones, T.M.; Sturgeon, L.P.; Whitt, J.M.

    1982-06-01T23:59:59.000Z

    An additional 13 coals have been obtained, bringing the total to 37. Classical chemical and petrographic characterizations have been completed for most of the coals now in hand. The database for analytical pyrolysis/gas chromatography and for quantitative extraction (THF and DMF) has been more than doubled. The procedures for Fourier Transform infrared analysis have been further modified, making use of a new micropulverizer and drying system, and a procedure for the production of uniform and reproducible KBr pellets has been developed and is now in use. The first analytical isothermal plastometry (AIP) data have been obtained, on two highly plastic coals, and additional data are now being generated. Additional work will be carried out with the pyrolysis/GC system and the THF and DMF extraction work. With the progress made in FTIR spectra acquisition, it is expected to complete acquisition and storage of raw coal spectra and to commence application of techniques to provide differential spectrometric information. HPLC analysis of extracts now appears ready for standardization of procedure. Finally, with the data available, statistical analytical work will be initiated.

  10. Predictors of plasticity in bituminous coals. Technical progress report No. 6

    SciTech Connect (OSTI)

    Lloyd, W.G.; Reasoner, J.W.; Hower, J.C.; Yates, L.P.; Bowling, C.C.; Davis, E.; Fitzpatrick, A.; Whitt, J.M.

    1983-03-01T23:59:59.000Z

    We have completed the pyrolysis/gas chromatographic analysis of all 40 coals in the present study, at two temperatures, 450/sup 0/ and 650/sup 0/C. We have also completed triplicate quantitative extraction analyses of all 40 coals, using tetrahydrofuran as the extractant solvent, and have completed a parallel set of extractions using N,N-dimethylformamide as the extractant solvent. In addition, we have completed analysis of over 100 additional isothermal Gieseler plastometer runs, and have made the first series of quantitative estimates of H(aromatic)/H(aliphatic) ratios from Fourier Transform Infrared Spectroscopy data. Exploratory work has begun on the petrographic characterization of the semi-coke residues from Gieseler plastometer runs, and also in characterizing THF extracts by thin layer chromatography and by column chromatography (quantitative group separations). Proximate, ultimate and petrographic characterization of the 40 coals has been completed previously. We are now prepared to start a study, using freshly re-sampled coals, of the effects of varying pressure upon the several parameters of fluidity.

  11. Configurational diffusion of coal macromolecules. Final technical report, September 15, 1986--September 14, 1991

    SciTech Connect (OSTI)

    Guin, J.A.; Curtis, C.W.; Tarrer, A.R.; Kim, S.; Hwang, D.; Chen, C.C.; Chiou, Z.

    1991-12-31T23:59:59.000Z

    The objective of our research was to obtain fundamental information regarding the functional dependence of the diffusion coefficient of coal molecules on the ratio of molecule to pore diameter. That is, the objective of our study was to examine the effect of molecule size and configuration on hindered diffusion of coal macromolecules through as porous medium. To best accomplish this task, we circumvented the complexities of an actual porous catalyst by using a well defined porous matrix with uniform capillaric pores, i.e., a track-etched membrane. In this way, useful information was obtained regarding the relationship of molecular size and configuration on the diffusion rate of coal derived macromolecules through a pore structure with known geometry. Similar studies were performed using a pellet formed of porous alumina, to provide a link between the idealized membranes and the actual complex pore structure of real catalyst extrudates. The fundamental information from our study will be useful toward the tailoring of catalysts to minimize diffusional influences and thereby increase coal conversion and selectivity for desirable products. (VC)

  12. Production of a pellet fuel from Illinois coal fines. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Rapp, D.; Lytle, J.; Berger, R.

    1994-12-31T23:59:59.000Z

    The primary goal of this research is to produce a pellet fuel from low-sulfur Illinois coal fines which could burn with emissions of less than 1.8 lbs SO{sub 2}/10{sup 6} Btu in stoker-fired boilers. The significance of 1.8 lbs SO{sub 2}/10{sup 6} Btu is that in the Chicago (9 counties) and St. Louis (2 counties) metropolitan areas, industrial users of coal currently must comply with this level of emissions. Stokers are an attractive market for pellets because pellets are well-suited for this application and because western coal is not a competitor in the stoker market. Compliance stoker fuels come from locations such as Kentucky and West Virginia and the price for fuels from these locations is high relative to the current price of Illinois coal. This market offers the most attractive near-term economic environment for commercialization of pelletization technology. For this effort, the authors will be investigating the use of fines from two Illinois mines which currently mine relatively low-sulfur reserves and that discard their fines fraction (minus 100 mesh). The research will involve investigation of multiple unit operations including column flotation, filtration and pellet production. The end result of the effort will allow for an evaluation of the commercial viability of the approach. This quarter pellet production work commenced and planning for collection and processing of a preparation plant fines fraction is underway.

  13. Geochemistry of a reclaimed coal slurry impoundment. Final technical report, September 1, 1993--November 30, 1994

    SciTech Connect (OSTI)

    Dreher, G.B.; Roy, W.R.; Steele, J.D.; Heidari, M.

    1994-12-31T23:59:59.000Z

    The highly alkaline residue from the fluidized-bed combustion (FBC) of coal may be an environmentally acceptable material for use in neutralizing acid produced by the oxidation of pyrite in coal. slurry solids (CSS). Previous research indicated that FBC residues in mixtures with pyrite-rich CSS neutralized the acid produced by or attenuated the oxidation of pyrite in CSS. In the present research project we retrieved five drill cores from a reclaimed coal slurry impoundment, and installed three samplers in one of the core holes. The solids were chemically and mineralogically analyzed. Display of the mineralogical data on a cross section showed that pyrite was randomly distributed through much of the length of the coal slurry impoundment. Trace concentrations of heavy metals were correlated with pyrite in the core solids. Water samples were collected and analyzed. The water analyses showed that nutrients are insufficient to support plant growth without supplemental fertilization. The analytical data will provide background information necessary for the development of a predictive computer model of the kinetics of pyrite oxidation at near-neutral pH conditions. Programming of a computerized model to simulate pyrite oxidation under near-neutral pH conditions was begun. The program includes ideas from Morel and Hering (1993) and species are calculated in terms of 7 components of known concentrations. The ionic strength of the solution, the species activity coefficients, and the activities are calculated iteratively.

  14. Advanced coal liquefaction research. Quarterly technical progress report, July 1, 1983-September 30, 1983

    SciTech Connect (OSTI)

    None

    1984-04-01T23:59:59.000Z

    Work this quarter focused on staged liquefaction. The effect of residence time on conversion in single pass experiments was found to be quite different for the subbituminous Belle Ayr Mine and bituminous Illinois No. 6 coals studied. With bituminous coal, conversion to soluble material is quite high and the limit of conversion is approached in only a few minutes. With a subbituminous coal, however, conversion is much lower and the limit of conversion is approached much more slowly. Short contact time (SCT) dissolution of Belle Ayr coal was studied as a possible first stage in a two-stage process. Conversion, hydrocarbon gas yield and hydrogen consumption were increased as residence time or temperature were increased. Conversion was also significantly increased by partial slurry recycle. Pyrite was found to be the most effective slurry catalyst for increasing conversion, followed by ammonium molybdate emulsion and finally nickel-molybdenum on alumina. Illinois No. 6 coal was liquefied in two stages. Conditions in the first stage dissolution were varied to determine the effect on upgradability in the second stage. An SCT (6 minute) coal dissolution stage is preferred over one at 30 minutes because hydrocarbon gas yield was much lower while overall oil yields for the combined dissolution and upgrading stages were nearly the same. Use of a NiMo/Al/sub 2/O/sub 3/ catalyst in a trickle-bed second stage resulted in a higher oil yield and lower product heteroatom content than use of the same catalyst in the slurry phase. The total oil yield was lower with a pyrite slurry catalyst than with a NiMo/Al/sub 2/O/sub 3/ slurry catalyst. With Belle Ayr coal and added pyrite, there was no change in total oil yield, conversion or product quality brought about by adding an 8-minute first stage at 450/sup 0/C (842/sup 0/F) to a 2-hour second stage operated at 420/sup 0/C (788/sup 0/F). 39 figures, 12 tables.

  15. Development and testing of industrial scale, coal fired combustion system, Phase 3. Fifth quarterly technical progress report, January 1, 1993--March 31, 1993

    SciTech Connect (OSTI)

    Zauderer, B.

    1993-05-17T23:59:59.000Z

    In the present reporting period, the first quarter of calendar year 1993, the effort was divided between Task 2. ``Pre Systems Tests`` and Task 4 ``Economics and Commercialization Plan.`` A major part of the task 2 effort was devoted converting the nozzle from adiabatic to air cooted operation. This conversion will allow immediate implementation of the longer duration task 3.2 tests after the completion of the task 2 tests. Therefore, a significant pan of the exit nozzle conversion effort is also part of task 3.1, ``Combustor Refurbishment.`` In task 1 the only activity remaining is to receive the results of the BYU combustion modeling. The results are anticipated this Spring. One of the three remaining tests in task 2 was implemented in late January under freezing weather and snow conditions. Ice plugged the coal feed lines and stack scrubber water outlet and ice jammed and damaged the coal metering auger. While these lines were thawed, the combustor was fired with oil. The coal used in this test contained fine fibrous tramp material which passed through the two tramp material retaining screens and eventually plugged several of the coal feed lines to the combustor. This cut the planned coal feed rate in half. As a result it was decided for the next test to increase the number of coal injection ports by 50% in order to provide excess capacity in the pneumatic feed feed. This will allow continued operation even in the presence of fine tramp material in the coal.

  16. AFBC co-firing of coal and hospital waste: Quarterly report, 1 May 1996-31 July, 1996

    SciTech Connect (OSTI)

    Stuart, J.M.

    1996-12-31T23:59:59.000Z

    The project objective is to design, construct, install, provide operator training and start-up a circulating fluidized bed combustion system at the Lebanon Pennsylvania Veteran`s Affairs Medical Center. This unit will co-fire coal and hospital waste providing lower cost steam for heating and possibly cooling (absorption chiller) and operation of a steam turbine-generator for limited power generation while providing efficient destruction of both general and infectious hospital waste. This quarterly report describes activities completed in the design, procure, install and start-up phase.

  17. Validation testing of the EERC pilot-scale circulating fluidized-bed combustor using Salt Creek coal. Final report

    SciTech Connect (OSTI)

    Mann, M.D.; Hajicek, D.R.; Moe, T.A.; Henderson, A.K.

    1991-09-01T23:59:59.000Z

    The overall goal of the project was to provide a technical basis for assessing the economic and environmental feasibility of circulating fluidized-bed combustion (CFBC) technology, focusing on the effect of system configuration and coal properties on performance. Other underlying goals of the program were to (1) design and construct a CFBC test facility, thereby providing a test facility at an independent laboratory; (2) demonstrate that the test unit is capable of meeting the original design objectives; and (3) assess the ability of the unit to provide scalable data. The purpose of this interim report is to present data from validation testing to establish the scalability of data generated from this unit.

  18. Demonstration program for coal-oil mixture combustion in an electric utility boiler - Category III A. 1978 annual report

    SciTech Connect (OSTI)

    Not Available

    1980-04-01T23:59:59.000Z

    The 1978 annual report covers New England Power Service Company's participation in the Department of Energy coal-oil mixture (COM) program. Continued world-wide unrest resulting in an unstable fuel oil supply coupled with rapidly inflating costs have caused continued interest in a demonstrable viable solution. NEPSCO's program, while not attaining all the milestones forecast, has made considerable progress. As of January 31, 1979, ninety-five (95% percent of engineering and design has been completed. Construction of facilities and installation of required equipment was approximately 75% complete and the six-week Feasibility Testing program was expected to commence during April 1979.

  19. Coal desulfurization in a rotary kiln combustor. Final report, March 15, 1990--July 31, 1991

    SciTech Connect (OSTI)

    Cobb, J.T. Jr.

    1992-09-11T23:59:59.000Z

    The purpose of this project was to demonstrate the combustion of coal and coal wastes in a rotary kiln reactor with limestone addition for sulfur control. The rationale for the project was the perception that rotary systems could bring several advantages to combustion of these fuels, and may thus offer an alternative to fluid-bed boilers. Towards this end, an existing wood pyrolysis kiln (the Humphrey Charcoal kiln) was to be suitably refurbished and retrofitted with a specially designed version of a patented air distributor provided by Universal Energy, Inc. (UEI). As the project progressed beyond the initial stages, a number of issues were raised regarding the feasibility and the possible advantages of burning coals in a rotary kiln combustor and, in particular, the suitability of the Humphrey Charcoal kiln as a combustor. Instead, an opportunity arose to conduct combustion tests in the PEDCO Rotary Cascading-Bed Boiler (RCBB) commercial demonstration unit at the North American Rayon CO. (NARCO) in Elizabethton, TN. The tests focused on anthracite culm and had two objectives: (a) determine the feasibility of burning anthracite culms in a rotary kiln boiler and (b) obtain input for any further work involving the Humphrey Charcoal kiln combustor. A number of tests were conducted at the PEDCO unit. The last one was conducted on anthracite culm procured directly from the feed bin of a commercial circulating fluid-bed boiler. The results were disappointing; it was difficult to maintain sustained combustion even when large quantities of supplemental fuel were used. Combustion efficiency was poor, around 60 percent. The results suggest that the rotary kiln boiler, as designed, is ill-suited with respect to low-grade, hard to burn solid fuels, such as anthracite culm. Indeed, data from combustion of bituminous coal in the PEDCO unit suggest that with respect to coal in general, the rotary kiln boiler appears inferior to the circulating fluid bed boiler.

  20. LLNL underground coal gasification project. Quarterly progress report, October-December 1980

    SciTech Connect (OSTI)

    Olness, D.U. (ed.)

    1981-01-26T23:59:59.000Z

    We have continued laboratory studies of forward gasification through drilled holes in small blocks of coal (approx. 30 cm on a side). Such studies give insight into cavity growth mechanisms and particulate production. In addition, we have been developing a mathematical model for these experiments in order to further our understanding of the physical and chemical processes governing the burning of the coal and the growth of the cavity within the block. This model will be adapted, later, to larger-scale coal-block experiments, and finally to full-scale field exoperiments. We hope to obtain scaling laws and other insights from the model. The small-block experiments are beginning to provide information relevant to the early-time cavity growth. The natural extension of these experiments to larger blocks, perhaps 10ft or more on a side, is presently being planned. The large-block tests will be conducted at a mine, where blocks of coal will be isolated by the experimenter; the objective will be to quantify early-time cavity growth. We completed planning for the directionally drilled injection well for DOE Experiment No. 1. Assessment of the data obtained during the various underground coal gasification tests is continuing. Results from the four different diagnostic systems have been combined to produce a description of the shape of the burn cavity as a function of time during the Hoe Creek No. 3 experiment. Groundwater samples from wells located at distances of a few feet to several hundred feet from the gasification cavities have been collected before, during, and after each of the Hoe Creek tests. The analysis of the groundwater contamination data pertinent to the Hoe Creek No. 2 test was completed.

  1. LLNL underground coal gasification project. Quarterly progress report, January-March 1981

    SciTech Connect (OSTI)

    Olness, D.U.; Clements, W. (eds.)

    1981-04-27T23:59:59.000Z

    We have continued our laboratory studies of forward gasification through drilled holes in small blocks of coal, approximately 1 foot on a side. Such studies give insight into cavity growth mechanisms and particulate production. However, because of the small dimensions involved, the information these tests provide is necessarily limited to aspects of cavity growth at very early times. The preliminary process design of the Tono No. 1 field experiment in Washington has been completed. The experimental plan and operational strategy have been developed to ensure that the injection point remains near the bottom of the coal seam and that the experiment continues at least until a period of stable operation has been reached and sustained for a time. We have continued to develop a mathematical model for the small coal block experiments in order to further our understanding of the physical and chemical processes governing the burning of the coal and the growth of the cavity within the block. This model will be adapted, later, to larger-scale coal block experiments, and finally to full-scale field experiments. We hope to obtain scaling laws and other insights from the model. Groundwater samples from wells located at distances of a few feet to several hundred feet from the gasification cavities were collected before, during, and after each of the Hoe Creek tests. The analysis of the groundwater contamination data pertinent to the Hoe Creek No. 3 test was completed. This is an ongoing project, and we will continue to obtain and analyze groundwater samples from these test sites.

  2. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 15, April 1, 1992--June 30, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-02-12T23:59:59.000Z

    The Department of Energy (DOE) awarded a contract entitled ``Engineering Development of Advanced Physical Fine Coal Cleaning Technology - Froth Flotation``, to ICF Kaiser Engineers with the following team members, Ohio Coal Development Office, Babcock and Wilcox, Consolidation Coal Company, Eimco Process Equipment Company, Illinois State Geological Survey, Virginia Polytechnic Institute and State University, Process Technology, Inc. This document a quarterly report prepared in accordance with the project reporting requirements covering the period from July 1, 1992 to September 30, 1992. This report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings.

  3. Hanna, Wyoming underground coal gasification data base. Volume 6. Hanna IVA and IVB field test research report

    SciTech Connect (OSTI)

    Bartke, T.C.; Fischer, D.D.; King, S.B.; Boyd, R.M.; Humphrey, A.E.

    1985-08-01T23:59:59.000Z

    This report is part of a seven-volume series on the Hanna, Wyoming, underground coal gasification field tests. Volume 1 is a summary of the project and each of Volumes 2 through 6 describes a particular test. Volume 7 is a compilation of all the data for the tests in Volumes 2 through 6. The reports in this series include: The Hanna IV test was designed as the first underground coal gasification test using commercial well spacings of 100 and 150 feet between well pairs in a linear 3-well pattern. The test was initiated in late 1977 and completed in late 1979. This long duration was due to unfavorable geologic conditions (faulting) which could not be successfully overcome resulting in the test being split into Hanna IVA and Hanna IVB with about one year between the conduct of each. This report covers: (1) specific site selection and characteristics; (2) test objectives; (3) facility description; (4) pre-operation tests; (5) test operations summary; and (6) post-test activity. 5 refs., 19 figs., 13 tabs.

  4. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01T23:59:59.000Z

    Synthetic Fuel from Coal," Federal Energy Administration,Chemical Refining of Coal," Battelle Energy Program Report,reserves coal characteristics energy content sulfur ash ni

  5. Energy Program annual report

    SciTech Connect (OSTI)

    Borg, I.Y. (ed.)

    1988-02-01T23:59:59.000Z

    The national economy is particularly dependent on efficient electrical generation and transportation. Electrical demand continues to grow and will increasingly rely on coal and nuclear fuels. The nuclear power industry still has not found a solution to the problem of disposing of the waste produced by nuclear reactors. Although coal is in ample supply and the infrastructure is in place for its utilization, environmental problems and improved conversion processes remain technical challenges. In the case of transportation, the nation depends almost exclusively on liquid fuels with attendant reliance on imported oil. Economic alternates---synfuels from coal, natural gas, and oil shale, or fuel cells and batteries---have yet to be developed or perfected so as to impact the marketplace. Inefficiencies in energy conversion in almost all phases of resource utilization remain. These collective problems are the focus of the Energy Program.

  6. Application of the SELECS methodology to evaluate socioeconomic and environmental impacts of commercial-scale coal liquefaction plants at six potential sites in Kentucky. Final report from the study on development of environmental guidelines for the selection of sites for fossil energy conversion facilities

    SciTech Connect (OSTI)

    Northrop, G. M.; D'Ambra, C. A.

    1980-11-01T23:59:59.000Z

    Environmental and socioeconomic impacts likely to occur during the operational phase of two coal liquefaction processes have been evaluated with SELECS (Site Evaluation for Energy Conversion Systems) for each of six potential sites in Kentucky for commercial scale facilities capable of processing about 26,000 tons of coal per stream day. The processes considered in this evaluation are SRC-I, a direct liquefaction route with solid boiler fuel as the principal product, and Coal-to-Methanol-to-Gasoline, an indirect liquefaction route with transportation fuel as the primary product. For comparative purposes, the impacts of a 2-gigawatt coal-fired steam-electric power plant (with coal requirements comparable to the liquefaction facilities) and an automobile parts manufacturing plant (with employment requirements of 849, comparable to the liquefaction facilities) have also been evaluated at each site. At each site, impacts have been evaluated for one or two nearby cities or towns and four to six counties where significant impacts might be expected. The SELECS methodology affords a well-organized and efficient approach to collecting and assessing a large volume of data needed to comprehensively determine the potential socioeconomic and environmental impacts resulting from the implementation of commercial scale synfuel and other energy conversion facilities. This study has also shown that SELECS is equally applicable to determine the impacts of other facilities, such as automobile parts manufacturing. In brief, the SELECS methodology serves the purpose of objectively screening sites in order to choose one at which adverse impacts will be least, and/or to determine what aspect of a proposed facility might be modified to lessen impacts at a specific site.

  7. Petrographic characterization of Kentucky coals. Final report. Part IV. A petrographic and chemical model for the evolution of the Tradewater Formation coals in Western Kentucky

    SciTech Connect (OSTI)

    Graese, A.M.; Hower, J.C.; Ferm, J.C.

    1984-01-01T23:59:59.000Z

    A depositional model for the coals of the Tradewater Formation and associated rock units was constructed as a predictive device for the occurrence of economically important low sulfur coal. Twenty-one cores were examined and ninety-eight coal samples were analyzed for maceral, ash, and sulfur contents. These data were then analyzed to determine regional variation as well as vertical variation in single coal columns. Core data indicate that the majority of the Tradewater rocks consist of irregularly distributed, coarsening-upward, fine-grained detrital material which was deposited in shallow bodies of water. Minor fossiliferous shales and limestones suggest a marine influence. Less common coarse-grained, fining-upward sequences appear to be deposits of meandering channels. Like the detrital rocks, the coal seams are also irregularly distributed and exhibit variable petrographic and chemical properties reflecting changes in the Eh and pH of the coal swamp waters as well as detrital influx into the swamps. These swamps were relatively limited in extent and probably occupied the upper reaches of the tidal zone. The lack of significant stratigraphic and geographic trends in the regional data suggests that this mode of deposition was widespread and continued for a long period of time. 42 references, 19 figures, 9 tables.

  8. Use of fluidized bed coal combustion techniques to study efficiency, emission reduction, boiler effects, and waste utilization. Annual report, January 1-June 30, 1985

    SciTech Connect (OSTI)

    Hesketh, H.E.; Rajan, S.

    1985-09-01T23:59:59.000Z

    The acquisition of thermodynamic and operating data on a wide variety of waste coals in a laboratory-scale atmospheric fluidized bed combustor (AFBC) unit is reported. The coals tested include: (1) low and medium heating value gob pile wastes, with ash content as high as 60%; (2) pelletized gob waste fines; (3) various cuts taken from beneficiation plant rejects with low heating values and high ash content; and (4) a partially devolatilized char produced from a caking Illinois coal. These waste coals could be successfully burned in the bench-scale unit with the exception of the high ash content beneficiation plant reject with a low heating value of 1700 Btu/lb. Some of the waste coals exhibited better combustion characteristics than others. The results obtained and the recommendations for improving the combustion and emission characteristics of the waste coals are discussed. Shakedown tests have been completed with the 1-ft diameter, 1 MBtu/h pilot-scale AFBC unit, and the results are reported. 1 ref., 15 figs., 8 tabs.

  9. Low-rank coal research annual report, July 1, 1989--June 30, 1990 including quarterly report, April--June 1990

    SciTech Connect (OSTI)

    Not Available

    1990-11-01T23:59:59.000Z

    Research programs in the following areas are presented: control technology and coal preparation; advance research and technology development; combustion; liquefaction; and gasification. Sixteen projects are included. Selected items have been processed separately for inclusion in the Energy Science and Technology Database.

  10. Liquid fossil-fuel technology. Quarterly technical progress report, April-June 1982

    SciTech Connect (OSTI)

    Linville, B. (ed.)

    1982-10-01T23:59:59.000Z

    This report primarily covers in-house oil, gas, and synfuel research and lists the contracted research. The report is broken into the following areas: liquid fossil fuel cycle, extraction, processing, utilization, and project integration and technology transfer. BETC publications are listed. (DLC)

  11. Combustion properties of coal-char blends: NO{sub x} emission characteristics. Interim final technical report, September 1, 1992--August 31, 1993

    SciTech Connect (OSTI)

    Rostam-Abadi, M.; Khan, L.; Khan, S. [Illinois State Geological Survey, Champaign, IL (United States); Smoot, L.D.; Germane, G.J.; Eatough, C.N. [Brigham Young Univ., Provo, UT (United States). Advanced Combustion Engineering Research Center

    1993-12-31T23:59:59.000Z

    Under pulverized coal combustion conditions, NO{sub x} formed during the release of volatile matter far exceed NO{sub x} formed from combustion of the resulting char. It is believed that interactions of NO{sub x} with char is responsible for the reduced NO{sub x} formation from the combustion of char. The goal of this research is to assess the potential technical and economical benefits of co-firing coal-char blends in pulverized coal boilers to reduce NO{sub x}. The rationale for the proposed research is that the presence of char in the flame during the initial stages of combustion may provide catalytic activity for reduction of NO{sub x} produced from volatile nitrogen. This project is a cooperative effort between the Illinois State Geological Survey (ISGS) and BYU/ACERC. Seven hundred and fifty pounds of three coal-char blends containing 12.5%, 25%, and 50% char and 125 pounds of a coal-activated carbon blend containing 12.5% activated carbon were prepared. The volatile matter contents of the blends ranged from 27.3 to 35.6% (dry basis). Char (16.2 wt% volatile matter) was made from an Illinois No. 6 coal (Peabody Coal Company) in a continuous feed charring oven under mild gasification conditions. Nine combustion tests will be performed with the coal and blends in a 0.5--1.0 MBtu/hr combustor located at BYU. Combustion data will be analyzed to determine the effect of blend type, stoichiometry, and flame temperature on NO{sub x} formation, ignition characteristics, flame stability, and combustion efficiency. A four month no-cost extension has been requested for the project. The results of the combustion tests will be reported in the final technical report in December 1993.

  12. High resolution seismic survey (of the) Rawlins, Wyoming underground coal gasification area. Final report

    SciTech Connect (OSTI)

    Youngberg, A.D.; Berkman, E.; Orange, A.S.

    1983-01-01T23:59:59.000Z

    In October 1982, a high resolution seismic survey was conducted at the Gulf Research and Development Company's underground coal gasification test site near Rawlins, Wyoming. The objectives of the survey were to utilize high resolution seismic technology to locate and characterize two underground coal burn zones. Seismic data acquisition and processing parameters were specifically designed to emphasize reflections at the shallow depths of interest. A three-dimensional grid of data was obtained over the Rawlins burn zones. Processing included time varying filters, trace composition, and two-dimensional areal stacking of the data in order to identify burn zone anomalies. An anomaly was discernable resulting from the rubble-collapse cavity associated with the burn zone which was studied in detail at the Rawlins 1 and 2 test sites. 21 refs., 20 figs.

  13. Supercritical fluid thermodynamics for coal processing. Final report, September 15, 1988--September 14, 1991

    SciTech Connect (OSTI)

    van Swol, F. [Illinois Univ., Urbana, IL (United States). Dept. of Chemical Engineering; Eckert, C.A. [Georgia Inst. of Tech., Atlanta, GA (United States). School of Chemical Engineering

    1988-09-15T23:59:59.000Z

    The main objective of this research is to develop an equation of state that can be used to predict solubilities and tailor supercritical fluid solvents for the extraction and processing of coal. To meet this objective we have implemented a two-sided. approach. First, we expanded the database of model coal compound solubilities in higher temperature fluids, polar fluids, and fluid mixtures systems. Second, the unique solute/solute, solute/cosolvent and solute/solvent intermolecular interactions in supercritical fluid solutions were investigated using spectroscopic techniques. These results increased our understanding of the molecular phenomena that affect solubility in supercritical fluids and were significant in the development of an equation of state that accurately reflects the true molecular makeup of the solution. (VC)

  14. Predictors of plasticity in bituminous coals. Technical progress report No. 1

    SciTech Connect (OSTI)

    Lloyd, W.G.; Reasoner, J.W.; Jiminez, A.; Hower, J.C.; Yates, L.P.; Jones, T.M.

    1981-12-01T23:59:59.000Z

    The first dozen coals - high volatile B and C from western Kentucky - have been identified and samples obtained. Classical analyses are nearly completed on this first group. Method development work has been undertaken and is substantially completed for pyrolysis gas chromatography, quantitative extraction of bitumen fraction, and isothermal plastometry. The principal item of new equipment, a Fourier transform infrared spectrometer, has been purchased and has been delivered. It is planned to acquire and to commence classical (ASTM and petrographic) characterization of the second dozen coals to be used, and to commence the systematic acquisition of isothermal plastometric data, GC pyrograms, and quantitative extractions. Development work will be initiated on the statistical analytical approaches to be used, with the expectation of commencing the first statistical analysis in May 1982.

  15. Co-firing high sulfur coal with refuse derived fuels. Quarterly report, October - December 1996

    SciTech Connect (OSTI)

    Pan, W.-P.; Riley, J.T.; Lloyd, W.G.

    1996-12-01T23:59:59.000Z

    The objectives of this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the effect of S0{sub 2} on the formation of chlorine during combustion processes was examined. To simulate the conditions used in the AFBC system, experiments were conducted in a quartz tube in an electrically heated furnace. The principle analytical technique used for identification of the products from this study was GC/MS. The evolved gas was trapped by an absorbent and analyzed with a GC/MS system. The preliminary results indicate an inhibiting effect of S0{sub 2} on the Deacon Reaction. Secondly, information on the evolution of chlorine, sulfur and organic compounds from coals 95031 and 95011 were studied with the AFBC system. 2 figs., 1 tab.

  16. BLAST FURNACE GRANULAR COAL INJECTION SYSTEM. Final Report Volume 2: Project Performance and Economics

    SciTech Connect (OSTI)

    Unknown

    1999-10-01T23:59:59.000Z

    Bethlehem Steel Corporation (BSC) requested financial assistance from the Department of Energy (DOE), for the design, construction and operation of a 2,800-ton-per-day blast furnace granulated coal injection (BFGCI) system for two existing iron-making blast furnaces. The blast furnaces are located at BSC's facilities in Burns Harbor, Indiana. The demonstration project proposal was selected by the DOE and awarded to Bethlehem in November 1990. The design of the project was completed in December 1993 and construction was completed in January 1995. The equipment startup period continued to November 1995 at which time the operating and testing program began. The blast furnace test program with different injected coals was completed in December 1998.

  17. Performance of a high efficiency advanced coal combustor. Task 2, Pilot scale combustion tests: Final report

    SciTech Connect (OSTI)

    Toqan, M.A.; Paloposki, T.; Yu, T.; Teare, J.D.; Beer, J.M. [Massachusetts Inst. of Tech., Cambridge, MA (United States)

    1989-12-01T23:59:59.000Z

    Under contract from DOE-PETC, Combustion Engineering, Inc. undertook the lead-role in a multi-task R&D program aimed at development of a new burner system for coal-based fuels; the goal was that this burner system should be capable of being retrofitted in oil- or gas-fired industrial boilers, or usable in new units. In the first phase of this program a high efficiency advanced coal combustor was designed jointly by CE and MIT. Its burner is of the multiannular design with a fixed shrouded swirler in the center immediately surrounding the atomizer gun to provide the ``primary act,`` and three further annuli for the supply of the ``secondary air.`` The degree of rotation (swirl) in the secondary air is variable. The split of the combustion air into primary and secondary air flows serves the purpose of flame stabilization and combustion staging, the latter to reduce NO{sub x} formation.

  18. Cyclone reburn using coal-water fuel: Pilot-scale development and testing. Final report

    SciTech Connect (OSTI)

    Eckhart, C.F.; DeVault, R.F.

    1991-10-01T23:59:59.000Z

    There is an ongoing effort to develop retrofit technologies capable of converting oil- and/or gas-fired boilers to coal combustion. The objective of this project is to demonstrate the technical feasibility of an improved portion of a previously developed retrofit system designed for the purpose of converting oil/gas boilers. This improvement would almost entirely eliminate the use of premium fuels, thereby significantly increasing the economical attractiveness of the system. Specifically, the goals in this program were to replace natural gas as a reburning fuel with coal-water fuel (CWF). The advantages of such a system include: (1) increased return on investment (ROI) for conversions; (2) nearly complete elimination of premium oil or gas fuel; (3) a more integrated approach to the conversion of oil- or gas-designed boilers to CWF.

  19. Summary report: Trace substance emissions from a coal-fired gasification plant

    SciTech Connect (OSTI)

    Williams, A.; Wetherold, B.; Maxwell, D.

    1996-10-16T23:59:59.000Z

    The U.S. Department of Energy (DOE), the Electric Power Research Institute (EPRI), and Louisiana Gasification Technology Inc. (LGTI) sponsored field sampling and analyses to characterize emissions of trace substances from LGTI`s integrated gasification combined cycle (IGCC) power plant at Plaquemine, Louisiana. The results indicate that emissions from the LGTI facility were quite low, often in the ppb levels, and comparable to a well-controlled pulverized coal-fired power plant.

  20. Measurements of POM emissions from coal-fired utility boilers. Final report

    SciTech Connect (OSTI)

    Sonnichsen, T.W.

    1983-02-01T23:59:59.000Z

    Emissions of polycyclic organic matter (POM) from fossil-fuel combustion systems are of concern due to the potential carcinogenic activity of specific POM species. The initial objectives of this research program were to (1) conduct a limited laboratory verification of state-of-the-art POM sampling and analysis techniques for pulverized coal-fired combustion exhausts and (2) measure the POM emissions of up to four coal-fired utility boilers. Initial laboratory tests, involving the injection of synthetic POM tracers into the sampling and analytical procedures were capable of accurate POM measurements. However, subsequent tracer recovery results and measurements of combustion generated POM from a coal-fired laboratory test furnace and a utility boiler were highly erratic. The program was consequently redirected to include a comprehensive evaluation of the analytical techniques and interfering factors in the flue gas or sampling train that may have impacted the POM measurements. State-of-the-art GC/MS analytical technical techniques were shown to be generally adequate, but some questions remain concerning sample preparation and adaptability for routine measurements. Review of the literature identified the potential for interaction of POM with the fly ash in either the flue-gas stream or the sampling system. The results of these evaluations were incorporated into a final field-test program on a coal-fired utility boiler. While some improvement in tracer recoveries and combustion-generated POM were obtained, several inconsistencies in the data were still apparent. Recommendations for future POM-measurement programs on utility boilers are presented.

  1. LLNL in situ coal gasification project. Quarterly progress report, April-June 1980

    SciTech Connect (OSTI)

    Olness, D.U. (ed.)

    1980-07-25T23:59:59.000Z

    We have continued our laboratory work on forward gasification through drilled holes in blocks of coal. These tests have produced some insight into cavity growth mechanisms and particulate production in Wyodak coal. The results will be presented at the Sixth Underground Coal Conversion Symposium in July. The data from the Hanna 4B experiment have been incorporated into the UCC Data Base and have been analyzed in the same way as the Hoe Creek data. Eventually, all of the Department of Energy (DOE) test data will be included in this continuing program. Site-restoration work has been started at the Hoe Creek site. This work includes the sealing of abandoned wells, some grading and reseeding of the ground surface, and general cleanup. A search for a site for underground coal-gasification (UCG) testing and possible commercial development has been carried out in Washington. The Tono basin was chosen as a tentative UCG test site, and a preliminary investigation of the site has been accomplished. Although the Tono basin appears suitable for UCG testing, additional geohydrologic investigation is needed. Our effort to survey the Soviet literature is continuing; in particular, experiments that yielded results similar to those obtained at Hoe Creek have been analyzed carefully. The Soviets conducted a series of directed-flow experiments in 1955 and 1956. In each experiment, both those in which the roof subsided and those in which it did not, the product-gas heating value was quite stable throughout the gasification period and there was no general decline in heating value, as is customarily observed.

  2. Estimated groundwater restoration costs associated with commercial underground coal gasification operations. Topical report

    SciTech Connect (OSTI)

    Fischer, D.D.

    1985-12-17T23:59:59.000Z

    The objective of this program was to complete a preliminary cost estimate for groundwater restoration for the Hoe Creek commercial underground coal gasification (UCG) facility under a set of ground rules based on field data measurements and specific compound removal requirements. Of the three approaches evaluated for disposal of the contaminated groundwater, deep well injection is the least expensive, followed by the alternate treatment approach.

  3. Life assessment and emissions monitoring of Indian coal-fired power plants. Final report

    SciTech Connect (OSTI)

    Not Available

    1992-07-01T23:59:59.000Z

    At the request of the Pittsburgh Energy Technology Center (PETC) of the United States Department of Energy (USDOE), the traveler, along with Dr. R. P. Krishnan, Oak Ridge National Laboratory (ORNL), Oak Ridge, Tennessee spent three weeks in India planning and performing emissions monitoring at the coal-fired Vijayawada Thermal Power Station (VTPS). The coordination for the Indian participants was provided by BHEL, Trichy and CPRI, Bangalore. The trip was sponsored by the PETC under the United States Agency for International Development (USAID)/Government of India (GOI)P Alternate Energy Resources Development (AERD) Project. The AERD Project is managed by PETC, and ORNL is providing the technical coordination and support for four coal projects that are being implemented with BHEL, Trichy. The traveler, after briefing the USAID mission in New Delhi visited BHEL, Trichy and CPRI, Bangalore to coordinate and plan the emissions test program. The site selection was made by BHEL, CPRI, TVA, and PETC. Monitoring was performed for 4 days on one of the 4 existing 210 MW coal-fired boilers at the VTPS, 400 km north of Madras, India.

  4. Co-production of electricity and alternate fuels from coal. Final report, August 1995

    SciTech Connect (OSTI)

    NONE

    1995-12-31T23:59:59.000Z

    The Calderon process and its process development unit, PDU, were originally conceived to produce two useful products from a bituminous coal: a desulfurized medium BTU gas containing primarily CO, H{sub 2}, CH{sub 4}, CO{sub 2}, and H{sub 2}O; and a desulfurized low BTU gas containing these same constituents plus N{sub 2} from the air used to provide heat for the process through the combustion of a portion of the fuel. The process was viewed as a means for providing both a synthesis gas for liquid fuel production (perhaps CH{sub 3}OH, alternatively CH{sub 4} or NH{sub 3}) and a pressurized, low BTU fuel gas, for gas turbine based power generation. The Calderon coal process comprises three principle sections which perform the following functions: coal pyrolysis in a continuous, steady flow unit based on coke oven technology; air blown, slagging, coke gasification in a moving bed unit based on a blast furnace technology; and a novel, lime pebble based, product gas processing in which a variety of functions are accomplished including the cracking of hydrocarbons and the removal of sulfur, H{sub 2}S, and of particulates from both the medium and low BTU gases. The product gas processing unit, based on multiple moving beds, has also been conceived to regenerate the lime pebbles and recover sulfur as elemental S.

  5. Co-firing high sulfur coal with refuse derived fuels. Final report

    SciTech Connect (OSTI)

    Pan, W.P.; Riley, J.T.; Lloyd, W.G.

    1997-11-30T23:59:59.000Z

    This project was designed to evaluate the combustion performance of and emissions from a fluidized bed combustor during the combustion of mixtures of high sulfur and/or high chlorine coals and municipal solid waste (MSW). The project included four major tasks, which were as follows: (1) Selection, acquisition, and characterization of raw materials for fuels and the determination of combustion profiles of combination fuels using thermal analytical techniques; (2) Studies of the mechanisms for the formation of chlorinated organics during the combustion of MSW using a tube furnace; (3) Investigation of the effect of sulfur species on the formation of chlorinated organics; and (4) Examination of the combustion performance of combination fuels in a laboratory scale fluidized bed combustor. Several kinds of coals and the major combustible components of the MSW, including PVC, newspaper, and cellulose were tested in this project. Coals with a wide range of sulfur and chlorine contents were used. TGA/MS/FTIR analyses were performed on the raw materials and their blends. The possible mechanism for the formation of chlorinated organics during combustion was investigated by conducting a series of experiments in a tube furnace. The effect of sulfur dioxide on the formation of molecular chlorine during combustion processes was examined in this study.

  6. Hot coal gas desulfurization with manganese-based sorbents. Final report, September 1992--December 1994

    SciTech Connect (OSTI)

    Hepworth, M.T.; Slimane, R.B.

    1994-11-01T23:59:59.000Z

    The focus of much current work being performed by the Morgantown Energy Technology Center (METC) of the Department of Energy on hot coal-derived fuel gas desulfurization is in the use of zinc-based sorbents. METC has shown interest in formulating and testing manganese-based pellets as alternative effective sulfur sorbents in the 700 to 1200{degree}C temperature range. To substantiate the potential superiority of Mn-based pellets, a systematic approach toward the evaluation of the desulfurizing power of single-metal sorbents is developed based on thermodynamic considerations. This novel procedure considered several metal-based sorbents and singled out manganese oxide as a prime candidate sorbent capable of being utilized under a wide temperature range, irrespective of the reducing power (determined by CO{sub 2}/CO ratio) of the fuel gas. Then, the thermodynamic feasibility of using Mn-based pellets for the removal of H{sub 2}S from hot-coal derived fuel gases, and the subsequent oxidative regeneration of loaded (sulfided) pellets was established. It was concluded that MnO is the stable form of manganese for virtually all commercially available coal-derived fuel gases. In addition, the objective of reducing the H{sub 2}S concentration below 150 ppMv to satisfy the integrated gasification combined cycle system requirement was shown to be thermodynamically feasible. A novel process is developed for the manufacture of Mn-based spherical pellets which have the desired physical and chemical characteristics required.

  7. LLNL underground-coal-gasification project. Quarterly progress report, April-June 1982

    SciTech Connect (OSTI)

    Not Available

    1982-08-06T23:59:59.000Z

    Cavity mapping has been completed for the large block experiments, which were done near Centralia, Washington, in the winter of 1981-1982. Postburn excavations into the experimental sites show all the cavities to be largely filled with rubble consisting of dried coal, char, ash, and slag. None of the five injection holes remained completely open through its associated cavity. Temperature histories for all the in situ thermocouples in the large block experiments have been analyzed. The interpretation of most of this temperature data is straightforward and consistent with other observations. As a further refinement in our underground coal gasification (UCG) modeling effort, transient temperature profiles have been calculated for open borehole gasification in wet coal by the isotherm migration method, using the LSODE computer code developed at LLNL. The next logical step in this calculation would be to make the rate of combustion surface movement a function of the rate of steam generation at the vaporization interface. Follow-up observations have continued at the Hoe Creek UCG experiment sites in Wyoming. Phenols have been detected at very low but significant levels in groundwater 400 ft from the Hoe Creek 2 experiment, which was done in 1977. It appears important to continue this investigation of phenol transport at Hoe Creek, and to extend it by drilling and sampling additional wells. The controlled retracting injection point (CRIP) technique, which was devised for UCG application, may also have applications in enhanced recovery of crude oil.

  8. The use of FBC wastes in the reclamation of coal slurry solids. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Dreher, G.B.; Roy, W.R.; Steele, J.D.

    1992-08-01T23:59:59.000Z

    The present research project is designed to provide initial data on one possible use of FBC waste. FBC wastes from five different locations in Illinois are mixed with coal slurry solids (CSS) from two different coal preparation plants at Illinois coal mines. In mixtures of FBC waste and coal slurry solids, the alkaline components of the FBC waste are expected to react with acid produced by the oxidation of pyrite in the coal slurry solid. An objective of this research is to determine the chemical composition of aqueous leachates from mixtures of FBC wastes, generated under various operating conditions, and the coal slurry solids.

  9. Production and screening of carbon products precursors from coal. Quarterly technical progress report and key personnel staffing report No. 3, July 1, 1995--Sepember 30, 1995

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    Tasks 1 and 2 involve preparation of a Project Management Plan and establishment of a Participants Agreement/Proprietary Information Agreement for members of the Carbon Products Consortium (CPC). These tasks are now complete. Task 3 is to provide a series of samples of solvent extracted coal to the CPC participants and to incorporate their feedback and suggestions into subsequent samples. As of September 30, 1995, UCAR has received two rounds of samples; Koppers has received one round of samples; ALCOA and AMOCO have not yet specified the types of samples they wish to receive; FMI has received one round of samples and has requested a rather large, five kilogram, sample of coal extracts to do multiple impregnation on a large carbon fiber preform. There are extensive communications between the WVU research team and the five industrial partners. Task 4, cooperation with MITRE on their preparation of an economic analysis of the solvent extraction, is complete. Task 5, Technology Transfer, is an on going endeavor with research team meetings, general CPC meetings, presentations of conference papers, and submission of required reports. The CPC is finally functioning as it has been envisioned, i.e., with the WVU solvent extracted coal materials being evaluated by several companies as precursor for their individual product lines. The companies are comparing the WVU materials with commercially available pitches and cokes.

  10. Energy Conversion and Storage Program: 1992 Annual report

    SciTech Connect (OSTI)

    Cairns, E.J.

    1993-06-01T23:59:59.000Z

    This report is the 1992 annual progress report for the Energy Conversion and Storage Program, a part of the Energy and Environment Division of the Lawrence Berkeley Laboratory. Work described falls into three broad areas: electrochemistry; chemical applications; and materials applications. The Energy Conversion and Storage Program applies principles of chemistry and materials science to solve problems in several areas: (1) production of new synthetic fuels, (2) development of high-performance rechargeable batteries and fuel cells, (3) development of advanced thermochemical processes for energy conversion, (4) characterization of complex chemical processes and chemical species, and (5) study and application of novel materials for energy conversion and transmission. Projects focus on transport-process principles, chemical kinetics, thermodynamics, separation processes, organic and physical chemistry, novel materials, and advanced methods of analysis. Electrochemistry research aims to develop advanced power systems for electric vehicle and stationary energy storage applications. Chemical applications research includes topics such as separations, catalysis, fuels, and chemical analyses. Included in this program area are projects to develop improved, energy-efficient methods for processing product and waste streams from synfuel plants, coal gasifiers, and biomass conversion processes. Materials applications research includes evaluation of the properties of advanced materials, as well as development of novel preparation techniques. For example, techniques such as sputtering, laser ablation, and poised laser deposition are being used to produce high-temperature superconducting films.

  11. Characterization of the surface properties of Illinois basin coals. Technical report, March 1, 1992--May 31, 1992

    SciTech Connect (OSTI)

    Demir, I.; Harvey, R.D.; Lizzio, A.A. [Illinois State Geological Survey, Champaign, IL (United States)

    1992-10-01T23:59:59.000Z

    The main objective of this project is to characterize the surface properties (surface area, pore size distribution, surface charge, and surface chemical structure) of eight coals in the Illinois Basin Coal Sample Program (IBCSP), and explore statistical relationships between surface properties and other coal characteristics. We completed analyses of -100 and -400 mesh, unoxidized IBCSP coals for surface area and pore volume distribution. Two thirds or more of the measured surface area of the samples are derived from the micropores (3.5-20 {Angstrom}). The mesopore surface areas of IBC-101, IBC-102, and IBC-107 coals are higher than the other coals, and the mesopore surface area of the IBC-103 coal is the smallest among all the coals tested. The pore volume in pores less than about 1800 {Angstrom} in diameter varies about five-fold among the samples. The differences between the samples suggest that these coals may show different physical-chemical behavior during various processes involving preparation and utilization of coal. Statistical analyses of the measured and other available coal properties indicate that the micropore surface area correlates positively with carbon content and vitrinite reflectance and negatively with volatile matter. and hydrogen content of the coal. The mesopore surface area correlates negatively with carbon content but positively with oxygen and hydrogen contents of the coal. The statistical correlations can be used to predict one parameter from another one.

  12. Gasifier feed: Tailor-made from Illinois coals. Final technical report, September 1, 1991--December 31, 1992

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III [Illinois State Geological Survey, Champaign, IL (United States); Lytle, J.M.; Frost, R.R.; Lizzio, A.A.; Kohlenberger, L.B.; Brewer, K.K. [Illinois State Geological Survey, Champaign, IL (United States)]|[DESTEC Energy (United States)]|[Williams Technologies, Inc. (United States)]|[Illinois Coal Association (United States)

    1992-12-31T23:59:59.000Z

    The main purpose of this project was to produce a feedstock from preparation plant fines from an Illinois (IL) coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high-sulfur content and high-Btu value of IL coals are Particularly advantageous in such a gasifier; preliminary-calculations indicate that the increased cost of removing sulfur from the gas from a high-sulfur coal is more than offset b the increased revenue from the sale of the elemental sulfur; additionally the high-Btu IL coal concentrates more energy into the slurry of a given coal to water ratio. The Btu is--higher not only because of the hither Btu value of the coal but also because IL coal requires less water to produce a pumpable slurry than western coal, i.e., as little as 30--35% water may be used for IL coal as compared to approximately 45% for most western coals. During the contract extension, additional coal testing was completed confirming the fact that coal concentrates can be made from plant waste under a variety of flotation conditions 33 tests were conducted, yielding an average of 13326 Btu with 9.6% ash while recovering 86.0%-Of the energy value.

  13. Characterization of open-cycle coal-fired MHD generators. 16th quarterly technical progress report, December 16, 1980-March 31, 1981

    SciTech Connect (OSTI)

    Wormhoudt, J.; Yousefian, V.; Weinberg, M.; Kolb, C.; Martinez-Sanchez, M.; Cheng, W.; Dvore, D.; Freedman, A.; Stanton, A.; Stewart, G.

    1981-05-01T23:59:59.000Z

    The successful design of full-scale, open-cycle, coal-fired MHD generators for baseload electrical production requires a detailed understanding of the plasma chemical and plasma dynamic characteristics of anticipated combustor and channel fluids. Progress in efforts to model the efficiency of an open-cycle, coal-fired MHD channel based on the characterization of the channel flow as well as laboratory experiments to validate the modeling effort is reported. In addition, studies related to understanding arcing and corrosion phenomena in the vicinity of an anode are reported.

  14. Coal transfer: can an environmentally safe coal transfer operation be undertaken in the lower Delaware Bay. Delaware Estuary situation report. [Dusts from transport of coal from barges to colliers

    SciTech Connect (OSTI)

    Biggs, R.B.; Sharp, J.H.; Manus, A.T.; Wypyszinski, A.W.

    1983-01-01T23:59:59.000Z

    Effective August 1983, the U.S. Coast Guard authorized coal transfer between vessels moored in Anchorage Area A, off Big Stone Beach in lower Delaware Bay. Two general methods may be used to transfer coal from shallow-draft barges to deep-draft colliers: auger or conveyor-belt operation and clamshell operation. Although dust emission is inherent in coal transfer, best available data from similar situations indicate dust emission can vary from 0.168 pounds per ton for clamshell to 0.0024 pounds per ton for auger/conveyor transfer. Air quality and bottom water deterioration are the major potential environmental impacts.

  15. Coal resources of Kyrgyzstan

    SciTech Connect (OSTI)

    Landis, E.R.; Bostick, N.H.; Gluskoter, H.J.; Johnson, E.A. [Geological Survey, Denver, CO (United States); Harrison, C.D. [CQ Inc., Homer City, PA (United States); Huber, D.W.

    1995-12-31T23:59:59.000Z

    The rugged, mountainous country of Kyrgyzstan contains about one-half of the known coal resources of central Asia (a geographic and economic region that also includes Uzbekistan, Tadjikistan and Turkmenistan). Coal of Jurassic age is present in eight regions in Kyrgyzstan in at least 64 different named localities. Significant coal occurrences of about the same age are present in the central Asian countries of Kazakhstan, China, and Russia. Separation of the coal-bearing rocks into individual deposits results more than earth movements before and during formation of the present-day mountains and basins of the country than from deposition in separate basins.Separation was further abetted by deep erosion and removal of the coal-bearing rocks from many areas, followed by covering of the remaining coal-bearing rocks by sands and gravels of Cenozoic age. The total resources of coal in Kyrgyzstan have been reported as about 30 billion tons. In some of the reported localities, the coal resources are known and adequately explored. In other parts of the republic, the coal resources are inadequately understood or largely unexplored. The resource and reserve inventory of Kyrgyzstan is at best incomplete; for some purposes, such as short-term local and long-range national planning, it may be inadequate. Less than 8% of the total estimated resources are categorized as recoverable reserves, and the amount that is economically recoverable is unknown. The coal is largely of subbituminous and high-volatile C bituminous rank, most has low and medium ash and sulfur contents, and coals of higher rank (some with coking qualities) are present in one region. It is recommended that appropriate analyses and tests be made during planning for utilization.

  16. Carbon Dioxide Capture from Coal-Fired

    E-Print Network [OSTI]

    Carbon Dioxide Capture from Coal-Fired Power Plants: A Real Options Analysis May 2005 MIT LFEE 2005. LFEE 2005-002 Report #12;#12;i ABSTRACT Investments in three coal-fired power generation technologies environment. The technologies evaluated are pulverized coal (PC), integrated coal gasification combined cycle

  17. Radiation-turbulence interactions in pulverized-coal flames. Quarterly report No. III, March 15, 1994--June 15, 1994

    SciTech Connect (OSTI)

    Menguec, M.P.; McDonough, J.M.

    1994-09-01T23:59:59.000Z

    The work concerns the development of computer codes for the simulation of radiation turbulence interactions in coal flames. Experimental studies in tandem with the turbulence calculations are based on optical observation of scattered light from coal particles under combustion conditions.

  18. Innovative Clean Coal Technology (ICCT): 180 MW demonstration of advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from coal-fired boilers. Topical report, LNCFS Levels 1 and 3 test results

    SciTech Connect (OSTI)

    Not Available

    1993-08-17T23:59:59.000Z

    This report presents results from the third phase of an Innovative Clean Coal Technology (ICC-1) project demonstrating advanced tangentially-fired combustion techniques for the reduction of nitrogen oxide (NO{sub x}) emissions from a coal-fired boiler. The purpose of this project was to study the NO{sub x} emissions characteristics of ABB Combustion Engineering`s (ABB CE) Low NO{sub x} Concentric Firing System (LNCFS) Levels I, II, and III. These technologies were installed and tested in a stepwise fashion at Gulf Power Company`s Plant Lansing Smith Unit 2. The objective of this report is to provide the results from Phase III. During that phase, Levels I and III of the ABB C-E Services Low NO{sub x} Concentric Firing System were tested. The LNCFS Level III technology includes separated overfire air, close coupled overfire air, clustered coal nozzles, flame attachment coal nozzle tips, and concentric firing. The LNCFS Level I was simulated by closing the separated overfire air nozzles of the LNCFS Level III system. Based upon long-term data, LNCFS Level HI reduced NO{sub x} emissions by 45 percent at full load. LOI levels with LNCFS Level III increased slightly, however, tests showed that LOI levels with LNCFS Level III were highly dependent upon coal fineness. After correcting for leakage air through the separated overfire air system, the simulated LNCFS Level I reduced NO{sub x} emissions by 37 percent. There was no increase in LOI with LNCFS Level I.

  19. The development of coal-based technologies for Department of Defense facilities. Semiannual technical progress report, September 28, 1993--March 27, 1994

    SciTech Connect (OSTI)

    Miller, B.G.; Morrison, J.L.; Sharifi, R.; Shepard, J.F.; Scaroni, A.W.; Hogg, R.; Chander, S.; Cho, H.; Ityokumbul, M.T.; Klima, M.S. [and others

    1994-11-30T23:59:59.000Z

    The U.S. Department of Defense (DOD), through an Interagency Agreement with the U.S. Department of Energy (DOE), has initiated a three-phase program with the Consortium for Coal-Water Slurry Fuel Technology, with the aim of decreasing DOD`s reliance on imported oil by increasing its use of coal. The program is being conducted as a cooperative agreement between the Consortium and DOE and the first two phases of the program are underway. To achieve the objectives of the program, a team of researchers was assembled. Phase I activities are focused on developing clean, coal-based combustion technologies for the utilization of both micronized coal-water slurry fuels (MCWSFS) and dry, micronized coal (DMC) in fuel oil-designed industrial boilers. Phase II research and development activities will continue to focus on industrial boiler retrofit technologies by addressing emissions control and precombustion (i.e., slagging combustion and/or gasification) strategies for the utilization of high ash, high sulfur coals. Phase III activities will examine coal-based fuel combustion systems that cofire wastes. Each phase includes an engineering cost analysis and technology assessment. The activities and status of Phases I and II are described below. The objective in Phase I is to deliver fully engineered retrofit options for a fuel oil-designed watertube boiler located on a DOD installation to fire either MCWSF or DMC. This will be achieved through a program consisting of the following five tasks: (1) Coal Beneficiation and Preparation; (2) Combustion Performance Evaluation; (3) Engineering Design; (4) Engineering and Economic Analysis; and (5) Final Report/Submission of Design Package.

  20. Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high temperature furnace (HITAF). Volume 1, Final report

    SciTech Connect (OSTI)

    NONE

    1996-02-01T23:59:59.000Z

    A major objective of the coal-fired high performance power systems (HIPPS) program is to achieve significant increases in the thermodynamic efficiency of coal use for electric power generation. Through increased efficiency, all airborne emissions can be decreased, including emissions of carbon dioxide. High Performance power systems as defined for this program are coal-fired, high efficiency systems where the combustion products from coal do not contact the gas turbine. Typically, this type of a system will involve some indirect heating of gas turbine inlet air and then topping combustion with a cleaner fuel. The topping combustion fuel can be natural gas or another relatively clean fuel. Fuel gas derived from coal is an acceptable fuel for the topping combustion. The ultimate goal for HIPPS is to, have a system that has 95 percent of its heat input from coal. Interim systems that have at least 65 percent heat input from coal are acceptable, but these systems are required to have a clear development path to a system that is 95 percent coal-fired. A three phase program has been planned for the development of HIPPS. Phase 1, reported herein, includes the development of a conceptual design for a commercial plant. Technical and economic feasibility have been analysed for this plant. Preliminary R&D on some aspects of the system were also done in Phase 1, and a Research, Development and Test plan was developed for Phase 2. Work in Phase 2 include s the testing and analysis that is required to develop the technology base for a prototype plant. This work includes pilot plant testing at a scale of around 50 MMBtu/hr heat input. The culmination of the Phase 2 effort will be a site-specific design and test plan for a prototype plant. Phase 3 is the construction and testing of this plant.

  1. Engineering development of advanced physical fine coal cleaning for premium fuel applications. Quarterly technical progress report 14, January--March 1996

    SciTech Connect (OSTI)

    Moro, N.; Shields, G.L.; Smit, F.J.; Jha, M.C.

    1996-04-30T23:59:59.000Z

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope includes laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction, and operation of a 2-t/hr process development unit (PDU). The project began in October, 1992, and is scheduled for completion by June 1997. During Quarter 14 (January--March 1996), parametric testing of the 30-inch Microcel{trademark} flotation column at the Lady Dunn Plant continued under Subtask 3.2. Subtask 3. 3 testing, investigating a novel Hydrophobic Dewatering process (HD), continued this quarter with parametric testing of the batch dewatering unit. Coal product moistures of 3 to 12 percent were achieved, with higher percent solids slurry feeds resulting in lower product moistures. For a given percent solids feed, the product moisture decreased with increasing butane to dry coal ratios. Stirring time, stirring rate, and settling time were all found to have little effect on the final moisture content. Continuing Subtask 6.4 work, investigating coal-water-fuel slurry formulation for coals cleaned by selective agglomeration, indicated that pH adjustment to 10 resulted in marginally better (lower viscosity) slurries for one of the two coals tested. Subtask 6.5 agglomeration bench-scale testing results indicate that the new Taggart coal requires a grind with a d{sub 80} of approximately 33 microns to achieve the 1 lb ash/MBtu product quality specification. Also under Subtask 6.5, reductions in the various trace element concentrations accomplished during selective agglomeration were determined. Work was essentially completed on the detailed design of the PDU selective agglomeration module under Task 7 with the issuing of a draft report.

  2. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. Technical report, September 1, 1991--November 30, 1991

    SciTech Connect (OSTI)

    Chou, M.I.M.

    1991-12-31T23:59:59.000Z

    A pre-combustion coal desulfurization process at 120{degree}C using perchloroethylene (PCE) to remove up to 70% of the organic sulfur has been developed by the Midwest Ore Processing Co. (MWOPC). However, this process has not yet proven to be as successful with Illinois coals as it has for Ohio and Indiana coals. The organic sulfur removal has been achieved only with highly oxidized Illinois coals containing high sulfatic sulfur. A logical explanation for this observation is vital to successful process optimization for the use of Illinois coals. In addition, the high levels of organic sulfur removals observed by the MWOPC may be due to certain errors involved in the ASTM data interpretation; this needs verification. For example, elemental sulfur extracted by the PCE may be derived from pyrite oxidation during coal pre-oxidation, but it may be interpreted as organic sulfur removed by the PCE using ASTM analysis. The goals of this research are: (1) to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process reported by the MWOPC, (2) to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation, and (3) to determine the suitability of Illinois coals for use in the PCE desulfurization process. This project involves the Illinois State Geological Survey (ISGS), Eastern Illinois University (EIU), the University of Illinois-Urbana/Champaign (UI-UC), and the University of Kentucky, Lexington (UK). This is the first year of a two-year project.

  3. Clean Coal Power Initiative

    SciTech Connect (OSTI)

    Doug Bartlett; Rob James; John McDermott; Neel Parikh; Sanjay Patnaik; Camilla Podowski

    2006-03-31T23:59:59.000Z

    This report is the fifth quarterly Technical Progress Report submitted by NeuCo, Incorporated, under Award Identification Number, DE-FC26-04NT41768. This award is part of the Clean Coal Power Initiative (''CCPI''), the ten-year, $2B initiative to demonstrate new clean coal technologies in the field. This report is one of the required reports listed in Attachment B Federal Assistance Reporting Checklist, part of the Cooperative Agreement. The report covers the award period January 1, 2006 - March 31, 2006 and NeuCo's efforts within design, development, and deployment of on-line optimization systems during that period.

  4. PFB coal fired combined cycle development program. Annual report, July 1978-June 1979

    SciTech Connect (OSTI)

    Not Available

    1980-05-01T23:59:59.000Z

    The Coal Fired Combined Cycle (CFCC) is the unique powerplant concept developed under the leadership of the General Electric Company to provide a direct coal-burning gas turbine and steam turbine combined cycle powerplant. On the basis of previous studies and confirming work under this contract, General Electric continues to believe that the CFCC approach offers important advantages over alternate approaches: higher powerplant efficiency in the combustor temperature range of interest; reduced combustor/steam generator corrosion potential, due to low fluid-bed tube temperature (as contrasted to the air in tube cycle); and increased gas turbine bucket life from improved material protection systems. The objective of this program is to evaluate the coal fired combined cycle powerplant conceptual design, and to conduct a supporting development program. The supporting development is required for evaluating the pressurized fluidized bed combustion concept, for developing engineering correlations to be used in optimizing the commercial plant concept, and for evaluating the combustor/steam generator, the hot-gas cleanup, and the advanced gas turbine materials approach for this application. Work to date has identified the need to protect the gas turbine from corrosion caused by substantial amounts of alkali in the submicron aerosol and vapor phase and to protect the turbine from erosion caused by multi-micron-sized particulates. We believe that a solution to the corrosion protection challenge can more confidently and quickly be found by extending turbine materials work in dirty liquid fuels to the PFB environmental levels. Particulate removal for erosion protection has as its objective a better quantification of the erosion tolerance level coupled with work to improve the performance of inertial separators, including electrostatic augmentation, in the less-than-10-..mu..m-particle-size region. A few other testing programs are described briefly.

  5. Refining and end use study of coal liquids. Quarterly report, January--March 1996

    SciTech Connect (OSTI)

    NONE

    1996-09-01T23:59:59.000Z

    Bechtel, with Southwest Research Institute, Amoco Oil R&D, and the M. W. Kellogg Co. as subcontractors, initiated a study on November 1, 1993, for the US Department of Energy`s (DOE`s) Pittsburgh Energy Technology Center (PETC) to determine the most cost effective and suitable combination of existing petroleum refinery processes needed to make specification transportation fuels or blending stocks, from direct and indirect coal liquefaction product liquids. A key objective is to determine the most desirable ways of integrating coal liquefaction liquids into existing petroleum refineries to produce transportation fuels meeting current and future, e.g. year 2000, Clean Air Act Amendment (CAAA) standards. An integral part of the above objectives is to test the fuels or blends produced and compare them with established ASTM fuels. The comparison will include engine tests to ascertain compliance of the fuels produced with CAAA and other applicable fuel quality and performance standards. The final part of the project includes a detailed economic evaluation of the cost of processing the coal liquids to their optimum products. The cost analyses is for the incremental processing cost; in other words, the feed is priced at zero dollars. The study reflects costs for operations using state of the art refinery technology; no capital costs for building new refineries is considered. Some modifications to the existing refinery may be required. Economy of scale dictates the minimum amount of feedstock that should be processed. The major efforts conducted during the first quarter of 1996 were in the areas of: DL2 light distillate hydrotreating; and DL2 heave distillate catalytic cracking.

  6. Assessment of ether and alcohol fuels from coal. Volume 2. Technical report

    SciTech Connect (OSTI)

    Not Available

    1983-03-01T23:59:59.000Z

    A unique route for the indirect liquefaction of coal to produce transportation fuel has been evaluated. The resultant fuel includes alkyl tertiary alkyl ethers and higher alcohols, all in the gasoline boiling range. When blended into gasoline, the ether fuel provides several advantages over the lower alcohols: (1) lower chemical oxygen content, (2) less-severe water-separation problems, and (3) reduced front-end volatility effects. The ether fuel also has high-octane quality. Further, it can be utilized as a gasoline substitute in all proportions. Production of ether fuel combines several steps, all of which are or have been practiced on an industrial scale: (1) coal gasification, (2) gas cleanup and shift to desired H/sub 2/:CO ratio, (3) conversion of synthesis gas to isobutanol, methanol, and higher alcohols, (4) separation of alcohols, (5) chemical dehydration of isobutanol to isobutylene, and (6) etherification of isobutylene with methanol. A pilot-plant investigation of the isobutanol synthesis step was performed. Estimates of ether-fuel manufacturing costs indicate this process route is significantly more costly than synthesis of methanol. However, the fuel performance features provide incentive for developing the necessary process and catalyst improvements. Co-production of higher-molecular-weight co-solvent alcohols represents a less-drastic form of methanol modification to achieve improvement in the performance of methanol-gasoline blends. Costs were estimated for producing several proportions of methanol plus higher alcohols from coal. Estimated fuel selling price increases regularly but modestly with higher alcohol content.

  7. Hindered diffusion of coal liquids. Quarterly report No. 1, September 18, 1992--December 17, 1992

    SciTech Connect (OSTI)

    Tsotsis, T.T.; Sahimi, M. [University of Southern California, Los Angeles, CA (United States). Dept. of Chemical Engineering; Webster, I.A. [Unocal Corp., Los Angeles, CA (United States)

    1992-12-31T23:59:59.000Z

    The molecules comprising coal liquids can range from less than 10 to several hundred {angstrom} in diameter. Their size is, therefore, comparable to the average pore size of most hydroprocessing catalysts. Thus, during processing, transport of these molecules into the catalyst occurs mainly by ``configurational`` or ``hindered diffusion,`` which is the result of two phenomena occurring in the pores; the distribution of solute molecules in the pores is affected by the pores and the solute molecules experience an increased hydrodynamic drag. The field of hindered diffusion has been reviewed by Deen [16]. The earliest studies in the filed were by Renkin et al. [17].

  8. The fate of alkali species in advanced coal conversion systems. Final report

    SciTech Connect (OSTI)

    Krishnan, G.N.; Wood, B.J.

    1991-11-01T23:59:59.000Z

    The fate of species during coal combustion and gasification was determined experimentally in a fluidized bed reactor. A molecular-beam sampling mags spectrometer was used to identify and measure the concentration of vapor phase sodium species in the high temperature environment. Concurrent collection and analysis of the ash established the distribution of sodium species between gas-entrained and residual ash fractions. Two coals, Beulah Zap lignite and Illinois No. 6 bituminous, were used under combustion and gasification conditions at atmospheric pressure. Steady-state bed temperatures were in the range 800--950{degree}C. An extensive calibration procedure ensured that the mass spectrometer was capable of detecting sodium-containing vapor species at concentrations as low as 50 ppb. In the temperature range 800{degree} to 950{degree}C, the concentrations of vapor phase sodium species (Na, Na{sub 2}O, NaCl, and Na{sub 2}SO{sub 4}) are less than 0.05 ppm under combustion conditions with excess air. However, under gasification conditions with Beulah Zap lignite, sodium vapor species are present at about 14 ppm at a temperature of 820{degree}. Of this amount, NaCl vapor constitutes about 5 ppm and the rest is very likely NAOH. Sodium in the form of NaCl in coal enhances the vaporization of sodium species during combustion. Vapor phase concentration of both NaCl and Na{sub 2}SO{sub 4} increased when NaCl was added to the Beulah Zap lignite. Ash particles account for nearly 100% of the sodium in the coal during combustion in the investigated temperature range. The fine fly-ash particles (<10 {mu}m) are enriched in sodium, mainly in the form of sodium sulfate. The amount of sodium species in this ash fraction may be as high as 30 wt % of the total sodium. Sodium in the coarse ash particle phase retained in the bed is mainly in amorphous forms.

  9. Instrumentation and process control development for in situ coal gasification. Quarterly report, December 1979-March 1980

    SciTech Connect (OSTI)

    Glass, R.E. (ed.)

    1980-06-01T23:59:59.000Z

    The analysis of data for the Hanna IV and Hoe Creek in situ coal gasification tests raised questions concerning the fundamental controlling mechanisms of the process. The two main areas of concern are: (1) the air flow patterns; and (2) the initial cavity growth. Sandia National Laboratories is addressing these concerns by developing models of these processes. Results to date are in qualitative agreement with known phenomena. There have also been developments in data handling capability. These include improved data presentation ability and development of routine storage, access and back up methods.

  10. U.S. Energy Information Administration | Quarterly Coal Report (Abbreviated), Ja

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heatingintensity Energy intensity4. U.S. Coal Exports

  11. U.S. Energy Information Administration | Quarterly Coal Report (Abbreviated), Ja

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heatingintensity Energy intensity4. U.S. Coal

  12. U.S. Energy Information Administration | Quarterly Coal Report (Abbreviated), Ja

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heatingintensity Energy intensity4. U.S. Coal6.

  13. Integrated High Temperature Coal to Hydrogen System with CO2 Separation: Semi-Annual Progress Report 1

    SciTech Connect (OSTI)

    Ruud, J A; Ku, A; Ramaswamy, V; Wei, W

    2005-12-21T23:59:59.000Z

    This is the first semi-annual progress report for the program "Integrated High Temperature Coal to Hydrogen System with CO2 Separation." The objective of the program is to develop a detailed design for a single high-temperature syngas-cleanup module to produce a pure stream of H2 from a coal-based system and to develop the new high-temperature membrane materials at the core of that design. The novel one-box process combines a shift reactor with a high-temperature CO2-selective membrane to convert CO to CO2, remove sulfur compounds, and remove CO2 in a simple, compact, fully integrated system. In the first six months of the program, a conceptual design for the one-box system was developed in Task 1 and the performance targets for the system and the membrane were evaluated. In Task 2.1 processes were developed for creating pore architectures in ceramics that are applicable to membrane structures. In Task 2.2, candidate materials were identified that have the potential for separation of CO2 and H2S at high temperatures.

  14. Petrographic characterization of Kentucky coals. Final report. Part II. Depositional settings of the coal bearing, upper Tradewater Formation in western Kentucky with emphasis on the Mannington (No. 4) coal zone

    SciTech Connect (OSTI)

    Baynard, D.N.; Hower, J.C.

    1983-01-01T23:59:59.000Z

    Depositional settings were determined in the coal bearing, Middle Pennsylvanian, upper Tradewater Formation in western Kentucky with emphasis on the Mannington (No. 4) coal zone. The coals have been analyzed for maceral contents, lithotypes, dry sulfur/ash percentages, vitrinite reflectance values, pyrite/marcasite contents, and associated lithologies at different vertical and lateral scales. This study concludes that: (1) the thin coarsening - or fining upward sequences, under the Mannington (No. 4) coal zone are possibly shallow bayfill and channel-fill deposits that provided an environment that has slight differences in topography, (2) rapid vertical and lateral change in total vitrinite, dry sulfur/ash percentages and lithotypes at different scales in the Mannington (No. 4) coal zone are indicative of wideranging Eh and pH values and possibly result from slight changes in paleotopography, and (3) the Davis (No. 6) coal was deposited after a period of thick coarsening - or fining upward sequences, possibly providing a relatively flat-stable surface for peat development. The consistent total vitrinite, dry sulfur/ash values, and thickness trends indicate a more restricted environment (pH and Eh) in the Davis (No. 6) swamp. 41 references, 25 figures, 3 tables.

  15. Results of the groundwater restoration project, Hanna Underground Coal Gasification Test Site, Wyoming: Topical report

    SciTech Connect (OSTI)

    Oliver, R.L.

    1988-01-01T23:59:59.000Z

    Underground coal gasification (UCG) experiments conducted during the 1970s at the Department of Energy (DOE) site near Hanna, Wyoming, formed six underground cavities in the Hanna No. 1 coal seam, an aquifer of low permeability. When the first Hanna UCG experiment began in March 1973, researchers had little information about what effects the geologic or hydrologic characteristics of the area might have on the UCG process; likewise, the effects of UCG on the environment were unknown. Since the UCG experiments were completed, dilute concentrations of pyrolysis products and leachates have been detected in groundwater monitoring wells in and near some of the six cavities. Three primary UCG indicator constituents have been measured at elevated concentrations: phenols, TDS, and sulfate. The Hanna III cavity water exceeded the DOE target level for TDS and sulfate, and the Hanna I cavity water exceeded the DOE target level for phenols. The indicated phenols contamination, however, was in groundwater sampled from a well which was previously used as a production well during the experiment. Water pumped during the restoration project and a new well located approximately 10 ft from the old production well was sampled and no elevated phenols concentration was detected. Therefore, the restoration performed on the Hanna I cavity water was not necessary. The restoration was performed, however, because these indications were not available until during the restoration. Locally, various other constituents exceed DOE target levels, but concentrations are very near target levels and are well within livestock use limits. 2 refs., 7 figs., 5 tabs.

  16. Co-firing high sulfur coal with refuse derived fuels. Technical report {number_sign}4

    SciTech Connect (OSTI)

    Pan, W.P.; Riley, J.T.; Lloyd, W.G.

    1995-08-03T23:59:59.000Z

    In order to study combustion performance under conditions similar to that in the AFBC system, the authors conducted a series of experiments at a heating rate of 100 C/min using the TGA/FTIR/MS system. Results indicate that more hydrocarbons are evolved at the faster heating rate, owing to incomplete combustion of the fuel. Chlorinated organic compounds can be formed at high heating rates. Certain oxidation products such as organic acids and alcohols are obtained at the slow heating rate. To simulate the conditions used in the atmospheric fluidized bed combustor (AFBC) at Western Kentucky University, studies were also conducted using a quartz tube in a tube furnace. The temperature conditions were kept identical to those of the combustor. The products evolved from the combustion of coal, PVC, and mixtures of the two were trapped in suitable solvents at different temperatures, and analyzed using the Shimadzu GC/MS system. The detection limits and the GC/MS analytical parameters were also established. The experiments were conducted keeping in mind the broader perspective; that of studying conditions conducive to the formation of chlorinated organic compounds from the combustion of coal/MSW blends. 32 figs., 16 tabs.

  17. A study of toxic emissions from a coal-fired gasification plant. Final report

    SciTech Connect (OSTI)

    NONE

    1995-12-01T23:59:59.000Z

    Under the Fine Particulate Control/Air Toxics Program, the US Department of Energy (DOE) has been performing comprehensive assessments of toxic substance emissions from coal-fired electric utility units. An objective of this program is to provide information to the US Environmental Protection Agency (EPA) for use in evaluating hazardous air pollutant emissions as required by the Clean Air Act Amendments (CAAA) of 1990. The Electric Power Research Institute (EPRI) has also performed comprehensive assessments of emissions from many power plants and provided the information to the EPA. The DOE program was implemented in two. Phase 1 involved the characterization of eight utility units, with options to sample additional units in Phase 2. Radian was one of five contractors selected to perform these toxic emission assessments.Radian`s Phase 1 test site was at southern Company Service`s Plant Yates, Unit 1, which, as part of the DOE`s Clean Coal Technology Program, was demonstrating the CT-121 flue gas desulfurization technology. A commercial-scale prototype integrated gasification-combined cycle (IGCC) power plant was selected by DOE for Phase 2 testing. Funding for the Phase 2 effort was provided by DOE, with assistance from EPRI and the host site, the Louisiana Gasification Technology, Inc. (LGTI) project This document presents the results of that effort.

  18. Combustion of ultrafine coal/water mixtures and their application in gas turbines: Final report

    SciTech Connect (OSTI)

    Toqan, M.A.; Srinivasachar, S.; Staudt, J.; Varela, F.; Beer, J.M.

    1987-10-01T23:59:59.000Z

    The feasibility of using coal-water fuels (CWF) in gas turbine combustors has been demonstrated in recent pilot plant experiments. The demands of burning coal-water fuels with high flame stability, complete combustion, low NO/sub x/ emission and a resulting fly ash particle size that will not erode turbine blades represent a significant challenge to combustion scientists and engineers. The satisfactory solution of these problems requires that the variation of the structure of CWF flames, i.e., the fields of flow, temperature and chemical species concentration in the flame, with operating conditions is known. Detailed in-flame measurements are difficult at elevated pressures and it has been proposed to carry out such experiments at atmospheric pressure and interpret the data by means of models for gas turbine combustor conditions. The research was carried out in five sequential tasks: cold flow studies; studies of conventional fine-grind CWF; combustion studies with ultrafine CWF fuel; reduction of NO/sub x/ emission by staged combustion; and data interpretation-ignition and radiation aspects. 37 refs., 61 figs., 9 tabs.

  19. Coal upgrading program for Usti nad Labem, Czech Republic: Task 8.3. Topical report, October 1994--August 1995

    SciTech Connect (OSTI)

    Young, B.C.; Musich, M.A.

    1995-10-01T23:59:59.000Z

    Coal has been a major energy source in the Czech Republic given its large coal reserves, especially brown coal and lignite (almost 4000 million metric tons) and smaller reserves of hard, mainly bituminous, coal (over 800 million tons). Political changes since 1989 have led to the reassessment of the role of coal in the future economy as increasing environmental regulations affect the use of the high-sulfur and high-ash brown coal and lignite as well as the high-ash hard coal. Already, the production of brown coal has declined from 87 million metric tons per year in 1989 to 67 million metric tons in 1993 and is projected to decrease further to 50 million metric tons per year of brown coal by the year 2000. As a means of effectively utilizing its indigenous coal resources, the Czech Republic is upgrading various technologies, and these are available at different stages of development, demonstration, and commercialization. The purpose of this review is to provide a database of information on applicable technologies that reduce the impact of gaseous (SO{sub 2}, NO{sub x}, volatile organic compounds) and particulate emissions from the combustion of coal in district and residential heating systems.

  20. Desulfurization of hot fuel gas produced from high-chlorine Illinois coals. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    O`Brien, W.S. [Southern Illinois Univ., Carbondale, IL (United States); Gupta, R.P. [Research Triangle Inst., Durham, NC (United States)

    1992-09-01T23:59:59.000Z

    There is a primary need to increase the utilization of Illinois coal resources by developing new methods of converting the coal into electricity by highly efficient and environmentally acceptable systems. New coal gasification processes are now being developed that can generate electricity with high thermal efficiency in either an integrated gasification combined cycle (IGCC) system or a molten carbonate fuel cell (MCFC). Both of-these new coal-to-electricity pathways require that the coal-derived fuel gas be at a high temperature and be free of potential pollutants, such as-sulfur compounds. Unfortunately, some high-sulfur Illinois coals also contain significant chlorine which converts into hydrogen chloride (HCI) in the coal gas. This project investigates the effect of HCI, in concentrations typical of a gasifier fed by high-chlorine Illinois coals, on zinc-titanate sorbents that are currently being developed for H{sub 2}S and COS removal from hot coal gas. This study is designed to identify any deleterious changes in the sorbent caused by HCI, both in adsorptive operation and in the regeneration cycle, and will pave the way to modify the sorbent formulation or the process operating procedure to remove HCl along with the H{sub 2}S and COS from hot coal gas. This will negate any harmful consequences Of utilizing high-chlorine Illinois coal in these processes.

  1. Engineering development of coal-fired high performance power systems, Phase II and Phase III. Quarter progress report, April 1, 1996--June 30, 1996

    SciTech Connect (OSTI)

    NONE

    1996-11-01T23:59:59.000Z

    Work is presented on the development of a coal-fired high performance power generation system by the year 2000. This report describes the design of the air heater, duct heater, system controls, slag viscosity, and design of a quench zone.

  2. The use of FBC wastes in the reclamation of coal slurry solids. Technical report, March 1, 1992--May 31, 1992

    SciTech Connect (OSTI)

    Dreher, G.B.; Roy, W.R.; Steele, J.D. [Illinois State Geological Survey, Champaign, IL (United States)

    1992-10-01T23:59:59.000Z

    Fluidized bed combustion (FBC) is a relatively new technology that is used commercially for the combustion of coal. In Illinois, this technology is valuable because it allows the combustion of Illinois high sulfur coal without pollution of the atmosphere with vast quantities of sulfur oxides. In FBC, coal is mixed with limestone or dolomite either before injection into the combustion chamber or in the combustion chamber. As the coal burns, sulfur in the coal is oxidized to S0{sub 2} and this is trapped by reaction with the limestone or dolomite to form gypsum (CaSO{sub 4} {center_dot} 2H{sub 2}O). Solid by-products from FBC are generally a mixture of calcium oxide, gypsum, coal ash, and unburned coal. The present research project is designed to provide initial data on one possible use of FBC waste. FBC wastes from five different locations in Illinois are mixed with coal slurry solids (CSS) from two different coal preparation plants at Illinois coal mines. In mixtures of FBC waste and coal slurry solids, the alkaline components of the FBC waste are expected to react with acid produced by the oxidation of pyrite in the coal slurry solid. An objective of this research is to determine the chemical composition of aqueous leachates from mixtures of FBC wastes, generated under various operating conditions, and the coal slurry solids. These data will be used in future research into the ability of such mixtures to support seed germination and plant growth. The final goal of this and future research is to determine whether mixed FBC waste and coal slurry solids can be used as a satisfactory growing medium in slurry pond reclamation. The chemical analyses of the 8 starting solids (5 FBC wastes, 2 Css samples, and 1 agricultural limestone sample) were completed.

  3. The use of FBC wastes in the reclamation of coal slurry solids. Technical report, September 1--November 30, 1991

    SciTech Connect (OSTI)

    Dreher, G.B.

    1991-12-31T23:59:59.000Z

    Fluidized bed combustion (FBC) is a relatively new technology that is used commercially for the combustion of coal. In Illinois, this technology is valuable because it allows the combustion of Illinois high sulfur coal without pollution of the atmosphere with vast quantities of sulfur oxides. In FBC, coal is mixed with limestone or dolomite either before injection into the combustion chamber or in the combustion chamber. As the coal burns, sulfur in the coal is oxidized to SO{sub 2} and this is trapped by reaction with the limestone or dolomite to form gypsum (CaSO{sub 4}{center_dot}2H{sub 2}O). Solid by-products from FBC are generally a mixture of calcium oxide, gypsum, coal ash, and unburned coal. The present research project is designed to provide initial data on one possible use of FBC waste. FBC wastes from five different locations in the Illinois are mixed with coal slurry solids from two different coal preparation plants at Illinois coal mines. In mixtures of FBC waste and coal slurry solids, the alkaline components of the FBC waste are expected to react with acid produced by the oxidation of pyrite in the coal slurry solid. An objective of this research is to determine the chemical composition of aqueous leachates from mixtures of FBC wastes, generated under various operating conditions, and the coal slurry solids. These data will be used in future research into the ability of such mixtures to support seed germination and plant growth. The ultimate of this and future research is to determine whether mixed FBC waste and coal slurry solids can be slurry pond reclamation.

  4. Gasifier feed: Tailor-made from Illinois coals. Interim final technical report, September 1, 1991--August 31, 1992

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III; Lytle, J.; Frost, R.R.; Lizzio, A.; Kohlenberger, L.; Brewer, K. [Illinois State Geological Survey, Champaign, IL (United States)

    1992-12-31T23:59:59.000Z

    The main purpose of this project is to produce a feedstock from preparation plant fines from an Illinois coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high sulfur content and high Btu value of Illinois coals are particularly advantageous in such a gasifier; preliminary calculations indicate that the increased cost of removing sulfur from the gas from a high sulfur coal is more than offset by the increased revenue from the sale of the elemental sulfur; additionally the high Btu Illinois coal concentrates more energy into the slurry of a given coal to water ratio. The Btu is higher not only because of the higher Btu value of the coal but also because Illinois coal requires less water to produce a pumpable slurry than western coal, i.e., as little as 30--35% water may be used for Illinois coal as compared to approximately 45% for most western coals. Destec Energy, a wholly-owned subsidiary of Dow Chemical Company, will provide guidelines and test compatibility of the slurries developed for gasification feedstock. Williams Technologies, Inc., will provide their expertise in long distance slurry pumping, and test selected products for viscosity, pumpability, and handleability. The Illinois State Geological Survey will study methods for producing clean coal/water slurries from preparation plant wastes including the concentration of pyritic sulfur into the coal slurry to increase the revenue from elemental sulfur produced during gasification operations, and decrease the pyritic sulfur content of the waste streams. ISGS will also test the gasification reactivity of the coals.

  5. Development and testing of a high efficiency advanced coal combustor: Phase 3, Industrial boiler retrofit. Quarterly technical progress report No. 13, October 1, 1994--December 31, 1994

    SciTech Connect (OSTI)

    Patel, R.L.; Borio, R. [ABB Combustion Engineering, Inc., Windsor, CT (United States); Scaroni, A.W.; Miller, B.G. [Pennsylvania State, PA (United States); McGowan, J.G. [Massachusetts Univ. (United States)

    1995-03-07T23:59:59.000Z

    The objective of this project is to retrofit the previously developed High Efficiency Advanced Coal Combustor (HEACC) to a standard gas/oil designed industrial boiler to assess the technical and economic viability of displacing premium fuels with microfine coal. During this reporting period, activities included completing the ``Task 3 Topical Report.`` The report is being reviewed internally by the ABB CE project team. Overall, all the program goals were met except carbon conversion efficiency. Based on all the results obtained to date the ABB CE/Penn State team believes that conducting the 1000 hr demonstration (Task 5) is warranted. Since, Penn State has planned to conduct long term combustion tests on micronized coal and coal-water fuels for other DOE-funded Projects during the first quarter of 1995, the demonstration phase (Task 5) of the subject program is tentatively scheduled to begin in June 1995, pending DOE approval. Work continued under Task 4.0 to complete the ``Commercialization Plan`` with ABB CE`s cognizant Business Unit. To address the lower combustion efficiency than the original project goal (95% vs 98%) during Task 3, the data were evaluated in-detail to understand which of the key parameters might be adjusted to achieve the desired burnout. To identify reasons for this lower combustion efficiency, and to evaluate which of the key parameters (i.e, coal fineness, residence time, coal reactivities etc.) are important for maximizing the combustion efficiency, ABB CE`s proprietary mathematical model known as the Lower Furnace Program-Slice Kinetic Model (LFP-SKM) was used for simulating the combustion process in the Penn State boiler (at full load firing rate). Fuel kinetic information for this study was selected on a surrogate basis from ABB CE`s extensive in-house data base.

  6. Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report No. 23, April 1--June 30, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-07-15T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x} and sulfur (SO{sub x}), on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. Work on a third unit, wall fired, has been stopped because of funding limitations. Specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. This project is conducted in three phases at each site: (1) Design and Permitting, (2) Construction and Startup, and (3) Operation, Data Collection, Reporting and Disposition. In phase AIII at Hennepin - Testing, Data Collection, Reporting and Disposition - Gas Reburning runs were made that indicate as high as 77% reduction in NO{sub x} emission using about 18% gas. Gas Reburning - Sorbent Injection test results indicated as high as 62% reduction in S0{sub 2}. A year of long term testing was completed in October, 1992.

  7. Coal-fired high performance power generating system. Quarterly progress report, October 1, 1994--December 31, 1994

    SciTech Connect (OSTI)

    NONE

    1995-08-01T23:59:59.000Z

    This report covers work carried out under Task 3, Preliminary R and D, under contract DE-AC22-92PC91155, {open_quotes}Engineering Development of a Coal-Fired High Performance Power Generation System{close_quotes} between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of (1) > 47% thermal efficiency; (2) NO{sub x}, SO{sub x} and particulates {<=}25% NSPS; (3) cost {>=}65% of heat input; (4) all solid wastes benign. In our design consideration, we have tried to render all waste streams benign and if possible convert them to a commercial product. It appears that vitrified slag has commercial values. If the flyash is reinjected through the furnace, along with the dry bottom ash, then the amount of the less valuable solid waste stream (ash) can be minimized. A limitation on this procedure arises if it results in the buildup of toxic metal concentrations in either the slag, the flyash or other APCD components. We have assembled analytical tools to describe the progress of specific toxic metals in our system. The outline of the analytical procedure is presented in the first section of this report. The strengths and corrosion resistance of five candidate refractories have been studied in this quarter. Some of the results are presented and compared for selected preparation conditions (mixing, drying time and drying temperatures). A 100 hour pilot-scale stagging combustor test of the prototype radiant panel is being planned. Several potential refractory brick materials are under review and five will be selected for the first 100 hour test. The design of the prototype panel is presented along with some of the test requirements.

  8. Analysis of Rocky Mountain I Underground Coal Gasification test. Topical report, March 1989-December 1989

    SciTech Connect (OSTI)

    Lan, S.S.; Floyd, F.M.

    1989-12-01T23:59:59.000Z

    In the Rocky Mountain I Underground Coal Gasification (UCG) Project, the Extended Linked Well (ELW) module and the Controlled Retracting Injection Point (CRIP) module were operated and demonstrated side-by-side. This engineering analysis of the process data was conducted to establish the viability of these technologies for commercial use. The data indicate that an optimum oxygen rate (700 SCFM) exists for the CRIP module and that the optimum steam/oxygen rate is comparable to that for moving bed gasifiers (1.3:1). Data from the post oxygen injection period indicate that 6-10% of carbon in the product gas from the ELW module was a result of pyrolysis. The gas produced by devolatilization was essentially free of carbon dioxide.

  9. Coal transformation chemistry. First quarterly progress report, March 1, 1980-May 31, 1980

    SciTech Connect (OSTI)

    Stock, Leon M.; Alemany, L. B.; Handy, C. I.; King, H. -H.

    1980-01-01T23:59:59.000Z

    Considerable progress has been made on the development of a convenient procedure for the alkylation of Illinois No. 6 coal in liquid ammonia. The results are presented in summary in Section IIIB, Task 1 and in more detail in Section IVB. Work on the chemistry of the liquefaction reaction has led to the conclusion that phenolic compounds participate in free radical reactions in hydrogen donor solvents. Phenolic compounds and benzoic acid derivatives do not function as acid catalysts in their reactions with tetralin and other representative compounds. In addition, the reaction of styrene with tetralin at 400/sup 0/C has been shown to be a complex process involving rather deepseated chemical transformations. The results are presented in summary in Section IIIB, Task 3 and in more detail in Section IVC.

  10. Healy clean coal project. Technical quarterly progress report no. 6, April--June 1992

    SciTech Connect (OSTI)

    Not Available

    1992-08-01T23:59:59.000Z

    The objective of the Healy Clean Coal Project is to demonstrate the integration of an advanced combustor and a heat recovery system with both high and low temperature emission control processes. Resulting emission levels of SO{sub 2}, NO{sub x}, and particulates are expected to be significantly better than the federal New source Performance standards. During this past quarter, engineering and design continued on the boiler, combustion flue gas desulfurization (FGD), and turbine/generator systems. Balance of plant equipment procurement specifications continue to be prepared. Construction activities commenced as the access road construction got under way. Temporary ash pond construction and drilling of the supply well will be completed during the next quarter.

  11. Mechanism of surface enrichment and adhesion of coal combustion particulates. Second quarterly report, September 1987

    SciTech Connect (OSTI)

    Shadman, F.; Peterson, T.W.; Wendt, J.O.L.; Punjak, W.A.; Rizeq, G.

    1987-12-31T23:59:59.000Z

    Following is an updated list of accomplishments: Design of an experimental set up and development of experimental techniques for study of the adsorption and desorption of alkali on coal ash and potential additive particles. Development of techniques for quantitative and qualitative characterization of alkali distribution in small additive particles using Scanning Auger Spectroscopy. Completion of a set of adsorption experiments for measuring the rate, capacity and adsorption characteristics of alkali adsorption on bauxite, silica, lime and kaolin. Design and set up of a micro-fluidized bed for study of the agglomeration kinetics and characteristics of ash and additive particles. Completion of the first set of experiments on dependence of agglomeration characteristics on the alkali content of typical ash and potential additive particle.

  12. Coal competition: prospects for the 1980s

    SciTech Connect (OSTI)

    Not Available

    1981-03-01T23:59:59.000Z

    This report consists of 10 chapters which present an historical overview of coal and the part it has played as an energy source in the economic growth of the United States from prior to World War II through 1978. Chapter titles are: definition of coals, coal mining; types of coal mines; mining methods; mining work force; development of coal; mine ownership; production; consumption; prices; exports; and imports. (DMC)

  13. Coal pump

    DOE Patents [OSTI]

    Bonin, John H. (Sunnyvale, CA); Meyer, John W. (Palo Alto, CA); Daniel, Jr., Arnold D. (Alameda County, CA)

    1983-01-01T23:59:59.000Z

    A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

  14. CONDENSING ECONOMIZERS FOR SMALL COAL-FIRED BOILERS AND FURNACES PROJECT REPORT - JANUARY 1994

    SciTech Connect (OSTI)

    BUTCHER,T.A.

    1994-01-04T23:59:59.000Z

    Condensing economizers increase the thermal efficiency of boilers by recovering sensible and latent heat from exhaust gas. These economizers are currently being used commercially for this purpose in a wide range of applications. Performance is dependent upon application-specific factors affecting the utility of recovered heat. With the addition of a condensing economizer boiler efficiency improvements up to 10% are possible. Condensing economizers can also capture flue gas particulates. In this work, the potential use of condensing economizers for both efficiency improvement and control of particulate emissions from small, coal water slurry-fired boilers was evaluated. Analysis was done to predict heat transfer and particulate capture by mechanisms including: inertial impaction, interception, diffusion, thermophoretic forces, and condensation growth. Shell-and-tube geometries were considered with flue gas on the outside of Teflon-covered tubes. Experimental studies were done with both air- and water-cooled economizers refit to a small boiler. Two experimental arrangements were used including oil-firing with injection of flyash upstream of the economizer and direct coal water slurry firing. Firing rates ranged from 27 to 82 kW (92,000 to 280,000 Btu/hr). Inertial impaction was found to be the most important particulate capture mechanism and removal efficiencies to 95% were achieved. With the addition of water sprays directly on the first row of tubes, removal efficiencies increased to 98%. Use of these sprays adversely affects heat recovery. Primary benefits of the sprays are seen to be the addition of small impaction sites and future design improvements are suggested in which such small impacts are permanently added to the highest velocity regions of the economizer. Predicted effects of these added impactors on particulate removal and pressure drop are presented.

  15. Selenium transformation in coal mine spoils: Its environmental impact assessment. Final report

    SciTech Connect (OSTI)

    Harness, J.; Atalay, A.; Koll, K.J.; Zhang, H.; Maggon, D.

    1991-12-31T23:59:59.000Z

    The objective of this program was to conduct an environmental impact assessment study for selenium from coal mine spoils. The use of in-situ lysimetry to predict selenium speciation, transformation, and mobility under natural conditions was evaluated. The scope of the study was to construct and test field-scale lysimeter and laboratory mini-column to assess mobility and speciation of selenium in coal mine overburden and soil systems; to conduct soil and groundwater sampling throughout the state of Oklahoma for an overall environmental impact assessment of selenium; and to conduct an in-depth literature review on the solubility, speciation, mobility, and toxicity of selenium from various sources. Groundwater and surface soil samples were also collected from each county in Oklahoma. Data collected from the lysimeter study indicated that selenium in the overburden of the abandoned mine site was mainly found in the selenite form. The amount of selenite found was too low and immobile to be of concern to the environment. The spoil had equilibrated long enough (over 50 years) that most of the soluble forms of selenium have already been lost. Examination of the overburden indicated the presence of pyrite crystals that precipitated over time. The laboratory mini-column study indicated that selenite is quite immobile and remained on the overburden material even after leaching with dilute acid. Data from groundwater samples indicated that based on the current permissible level for selenium in groundwater (0.01 mg Se/L), Oklahoma groundwater is widely contaminated with the element. However, according to the new regulation (0.05 mg Se/L), which is to be promulgated in 1992, only 9 of the 77 counties in the state exceed the limit.

  16. LLL in situ Coal Gasification Project. Quarterly progress report, January-March 1980

    SciTech Connect (OSTI)

    Olness, D.U. (ed.)

    1980-05-30T23:59:59.000Z

    We have performed three small-scale, coal-block reactor experiments in order to gain some insight into the performance of the proposed injection well design for the next field test, and to better understand some of the observed in situ phenomena which occurred during the Hoe Creek No. 3 field test. The modeling group has begun to consolidate into a single data base the data from Hoe Creek No. 1, No. 2, and No. 3, permitting some comparisons which are presented and discussed. During and after the Hoe Creek experiments, groundwater samples were collected from wells located at a distance of a few feet to several hundred feet from the gasification cavities. Analysis of the water was performed and work is continuing to understand and to explain the observed increased concentration of several cations. Several sources of information, including two recent papers by Zvyaghintsev covering Soviet UCG stations, have been analyzed. The Soviets developed an effective method for UCG in the 1950's. Plans were developed to increase UCG production from 0.7 billion m/sup 3/ in 1958 to over 40 billion m/sup 3//yr. These plans were not implemented; production peaked in 1966 at 2 billion m/sup 3//yr and declined to 0.7 billion m/sup 3//yr by 1977. The reasons for this decline are presumed to be the poorer heating values, closer wellbore spacings, and higher product gas losses at Angren than expected. Comparable results would produce unfavorable economics in the US. Also, UCG technology in the USSR faced stiff competition from natural gas production and efficient open-pit coal mining.

  17. COMBUSTION OF COAL IN AN OPPOSED FLOW DIFFUSION BURNER

    E-Print Network [OSTI]

    Chin, W.K.

    2010-01-01T23:59:59.000Z

    November 1976. Wilson, P.J. and Wells, J.H. , Coal, Cokeand Coal Chemicals, 108, (1950). This report was done withliThe F1uidised Combustion of Coal," Sixteenth S m osium {

  18. Geologic assessment of natural gas from coal seams in the Warrior Basin, Alabama. Topical report, September 1985-September 1986

    SciTech Connect (OSTI)

    McFall, K.S.; Wicks, D.E.; Kuuskraa, V.A.

    1986-11-01T23:59:59.000Z

    This study provides a detailed geologic assessment of the coal deposits in the Warrior Basin area that have high potential for natural gas from coal seams. The estimate of the natural gas in place in the four major coal groups is 19.8 trillion cubic feet. Although the bulk of the gas in place is in the deeper areally extensive Black Creek and Mary Lee coal groups, the more shallow Pratt coal group also shows good potential for coal seam gas. The most concentrated areas of methane in place are in the eastern portion of the Warrior Basin. These areas coincide with thick accumulations of high rank coals and their associated higher gas contents. These areas also appear to have been structurally altered, leading to enhanced permeability to gas and water. Thus, the eastern portions of the basin appear more favorable for coalbed methane production due to high gas contents, attractive coal thicknesses, closely-spaced coal cleats and joints, and moderate depths to the coal horizons.

  19. Characterization of the surface properties of Illinois basin coals. Final technical report, September 1, 1991--August 31, 1992

    SciTech Connect (OSTI)

    Demir, I.; Harvey, R.D.; Lizzio, A.A. [Illinois State Geological Survey, Champaign, IL (United States)

    1992-12-31T23:59:59.000Z

    Surface area and pore volume distributions, surface charge, and surface chemical structure of the eight coals in the Illinois Basin Coal Sample Program (IBCSP) were determined. The IBC-101 coal has the lowest total and micropore (3.5-20.0 {Angstrom}) surface areas. The IBC-103 coal has the lowest mesopore (20-500 {Angstrom}) surface area. The mesopore surface areas of IBC-101, IBC-102, and IBC-107 coals are higher than the other four coals. Pore volume in pores <1800 {Angstrom} in diameter varies almost five-fold with IBC-103 coal having the lowest value. These differences may affect the reactivity of these coals during cleaning, conversion, and combustion processes. Surface charge and isoelectric points vary among the samples. The isoelectric point, where processes such as agglomeration and dewatering is most efficient, shifted to higher pH values for some of the samples upon exposure to air oxidation at room temperature. Diffuse reflectance infrared spectroscopy (DRIS) data indicate that the surfaces of the IBCSP coals contain aromatic hydrocarbon components, aliphatic hydrocarbons, and an aldehyde group. Ball-mill grinding reduced the organic hydroxyls and thus enriched relative concentrations of nonpolar aliphatic functional groups in the samples. The room temperature air oxidation did not cause any significant change on the surface chemical structure of the coals.

  20. Agenda of critical issues: coal price and availability. Final report. [Includes effect of legislation, sulfur content and rail transport costs

    SciTech Connect (OSTI)

    Tennican, M.L.; Wayland, R.E.; Weinstein, D.M.

    1984-10-01T23:59:59.000Z

    Temple, Barker, and Sloane, Inc. developed an agenda of critical issues regarding future coal prices and coal availability for EPRI. TBS interviewed nearly 50 utility, coal company, and railroad officials, academic experts, and coal consultants; held a one-day participatory workshop; and conducted a literature review and follow-up interviews with selected utilities. TBS found four causes of uncertainty in the utility industry over future coal prices. First, the acid deposition proposals in Congress vary in terms of the structure of the legislation, the costs of compliance, and the impact on coal prices; in turn these uncertainties impede utility fuel planning and decision making. Second, powerplant-specific factors will have a major impact on whether utilities switch or scrub in response to acid deposition legislation; existing analyses do not capture these factors. The most important powerplant-specific factors are matching unit characteristics with coal specifications, retrofit scrubber costs, and differing state regulatory environments. Third, TBS found that utility fuel managers have great uncertainty over the availability and future cost of compliance coal. TBS estimated that the existing production capacity of eastern compliance coal is at least twice as high as current production. Fourth, TBS concluded that uncertainty over future coal transportation rates was a major reason for utilities' uncertainty over future delivered prices of coal. Critical transportation-related issues are the strategic and tactical response of eastern coal producers to the Staggers Act; the impact on rail rates of the sale of Conrail, of possible transcontinental mergers, and of multi-modal mergers; and the future pricing policies that eastern railroads will adopt in response to imports of Colombian coal. 21 references.

  1. POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report, No. 4, July 1995--September 1995

    SciTech Connect (OSTI)

    Groppo, J.G.; Parekh, B.K.

    1995-11-06T23:59:59.000Z

    Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. The cost-sharing contract effort is for 36 months beginning September 30, 1994. This report discusses technical progress made during the quarter from July 1 - September 29, 1995.

  2. Non-intrusive measurement of particle charge: Electrostatic dry coal cleaning. Technical progress report No. 11, January 1, 1994--March 31, 1994

    SciTech Connect (OSTI)

    Not Available

    1994-06-01T23:59:59.000Z

    As has been previously reported, the charge measurement portion of this project has been broadened to include direct measurement techniques which yield an average particle charge per unit mass. These methods, which now include current measurements from the charging loop, an electrolytic collection solution and a Faraday cage have been employed to expand the charge measurement capabilities over those that were originally developed using the PDPA. The effects of gas velocity, humidity and temperature as well as particle size on charge was evaluated for different coals and silica. The charge accumulated on silica particles was linearly dependent on their velocity in the tribocharger for the velocities and mass loadings which were investigated. For coals, a linear increase in charge occurred over a more limited velocity range. Transport gas humidity had a much stronger effect on the charge established on silica particles than on coal particles.

  3. Clean coal today

    SciTech Connect (OSTI)

    none,

    1990-01-01T23:59:59.000Z

    This is the first issue of the Clean Coal Today publication. Each issue will provide project status reports, feature articles about certain projects and highlight key events concerning the US Clean Coal Technology Demonstration Program. Projects described in this publication include: Colorado-Ute Electric Association Circulating Fluidized Bed Combustor Project at Nucla, Colorado; Babcock and Wilcox coolside and limestone injection multistage burner process (dry sorbent injection); Coal Tech's Advanced Cyclone Combustor Project; and the TIDD pressurized fluidized bed combustor combined cycle facility in Brilliant, Ohio. The status of other projects is included.

  4. Energy and environmental research emphasizing low-rank coal. Semi-annual report, January--June 1994

    SciTech Connect (OSTI)

    NONE

    1994-09-01T23:59:59.000Z

    Summaries of progress on the following tasks are presented: Mixed waste treatment; Hot water extraction of nonpolar organic pollutant from soils; Aqueous phase thermal oxidation wastewater treatment; Review of results from comprehensive characterization of air toxic emissions from coal-fired power plants; Air toxic fine particulate control; Effectiveness of sorbents for trace elements; Catalyst for utilization of methane in selective catalytic reduction of NOx; Fuel utilization properties; Hot gas cleaning; PFBC; catalytic tar cracking; sulfur forms in coal; resid and bitumen desulfurization; biodesulfurization; diesel fuel desulfurization; stability issues; Sorbent carbon development; Evaluation of carbon products; Stable and supercritical chars; Briquette binders; Carbon molecular sieves; Coal char fuel evaporation canister sorbent; Development of a coal by-product classification protocol for utilization; Use of coal ash in recycled plastics and composite materials; Corrosion of advanced structural materials; Joining of advanced structural materials; Resource data evaluation; and the Usti and Labem (Czech Republic) coal-upgrading program.

  5. Large scale solubilization of coal and bioconversion to utilizable energy. Quarterly report, October 1--December 31, 1996

    SciTech Connect (OSTI)

    Mishra, N.C.

    1996-12-22T23:59:59.000Z

    In order to develop a system for a large scale coal solubilization and its bioconversion to utilizable fuel, the author plans to clone the genes encoding Neurospora protein that facilitate depolymerization of coal. He also plans to use desulfurizing bacteria to remove the sulfur in situ and use other microorganisms to convert biosolubilized coal into utilizable energy following an approach utilizing several microorganisms. In addition the product of coal solubilized by fungus will be characterized to determine their chemical nature and the mechanism of reaction catalyzed by fungal product during in vivo and in vitro solubilization by the fungus or purified fungal protein.

  6. Large scale solubilization of coal and bioconversion to utilizable energy. Fifth quarterly technical report, January 1, 1995--March 31, 1995

    SciTech Connect (OSTI)

    Mishra, N.C.

    1995-12-01T23:59:59.000Z

    In order to develop a system for a large scale coal solubilization and its bioconversion to utilizable fuel, we plan to clone the genes encoding Neurospora protein that facilitate depolymerization of coal. We also plan to use desulfurizing bacteria to remove the sulfur in situ and use other microorganisms to convert biosolubilized coal into utilizable energy following an approach utilizing several microorganisms. In addition the product of coal solubilized by fungus will be characterized to determine their chemical nature and the mechanism of reaction catalyzed by fungal product during in vivo and in vitro solubilization by the fungus or purified fungal protein.

  7. Multi-parameter on-line coal bulk analysis. Technical progress report, March 16, 1995--June 15, 1995

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    Research continued on multi-parameter on-line coal bulk analysis. The thermal neutron flux distribution in coal and free air for two types of neutron sources was performed. The MCNP code was used to calculate the gamma ray response function and to determine the thermal neutron flux in coal when a lead collimator was used and when paraffin blocks were placed in front of the sample. The identification of chlorine in coal is discussed along with the analysis of the gamma spectra.

  8. Application of the SULF-X process to coal conversion and utilization. Phase II final report

    SciTech Connect (OSTI)

    Shapiro, E.; Bramer, H.C.; New, R.A.

    1984-01-01T23:59:59.000Z

    Pittsburgh Environmental and Energy Systems, Inc. contracted with the Department of Energy to demonstrate the efficacy of an iron sulfide flue gas treatment system (FGT) for removing sulfur dioxide (SO/sub 2/) and nitrogen oxides (NO/sub x/) and to correlate process variables to system performance. Laboratory and bench-scale testing was conducted with the SULF-X process, using both synthesized gas and actual flue gas from a coal-fired furnace. Laboratory tests resulted in 95% SO/sub 2/ removal and up to 95% NO/sub x/ removal. The bench-scale system demonstrated similar SO/sub 2/ removal efficiencies, but achieved only 39% NO/sub x/ removal due to relatively high oxygen concentrations in the flue gas and insufficient liquid-gas interfacial area within the absorber. Elemental sulfur was recovered during the regeneration steps. Total capital investment for the SULF-X system was estimated to be $91 to $103 per kilowatt (electric), compared to $90/kw for sodium solution scrubbing, $78 to $83/kw for magnesia slurry scrubbing and $74/kw for limestone slurry scrubbing. Annual operating costs for the SULF-X system were estimated to be 5.44 to 6.90 mills per kilowatt-hour, compared to 4.96 to 5.22 for sodium, 3.68 to 3.99 for magnesia and 3.73 to 4.25 for limestone. 6 references, 6 figures, 9 tables.

  9. Assessment of instrumentation needs for advanced coal power plant applications: Final report

    SciTech Connect (OSTI)

    Nelson, E.T.; Fischer, W.H.; Lipka, J.V.; Rutkowski, M.D.; Zaharchuk, R.

    1987-10-01T23:59:59.000Z

    The purpose of this study was to identify contaminants, identify instrumentation needs, assess available instrumentation and identify instruments that should be developed for controlling and monitoring gas streams encountered in the following power plants: Integrated Gasification Combined Cycle, Pressurized Fluidized Bed Combustion, and Gasification Molten Carbonate Fuel Cell. Emphasis was placed on hot gas cleanup system gas stream analysis, and included process control, research and environmental monitoring needs. Commercial process analyzers, typical of those currently used for process control purposes, were reviewed for the purpose of indicating commercial status. No instrument selection guidelines were found which were capable of replacing user interaction with the process analyzer vendors. This study leads to the following conclusions: available process analyzers for coal-derived gas cleanup applications satisfy current power system process control and regulatory requirements, but they are troublesome to maintain; commercial gas conditioning systems and in situ analyzers continue to be unavailable for hot gas cleanup applications; many research-oriented gas stream characterization and toxicity assessment needs can not be met by commercially available process analyzers; and greater emphasis should be placed on instrumentation and control system planning for future power plant applications. Analyzers for specific compounds are not recommended other than those needed for current process control purposes. Instead, some generally useful on-line laser-based and inductively coupled plasma methods are recommended for further development because of their potential for use in present hot gas cleanup research and future optimization, component protection and regulation compliance activities. 48 refs., 21 figs., 26 tabs.

  10. AFBC co-firing of coal and hospital waste. Quarterly report, August--October 1995

    SciTech Connect (OSTI)

    Stuart, J.M.

    1996-03-01T23:59:59.000Z

    The project objective is to design, construct, install provide operator training and start-up a circulating fluidized bed combustion system at the Lebanon Pennsylvania Veteran`s Affairs Medical Center. This unit will co-fire coal and hospital waste providing lower cost steam for heating and possibly cooling (absorption chiller) and operation of a steam turbine-generator for limited power generation. This would permit full capacity operation of the FBC year round in spite of the VA laundry that was shut down as well as efficient destruction of both general and infectious hospital waste and steam generation. The State permitting process required for construction will be completed in early November to allow installation and construction to be completed. Operating permits will be obtained after construction has been completed. A request for proposal for stack sampling and biospore tests was released to four (4) vendors in mid-October. The proposals shall be reviewed during November and the stack sampler will be selected. Funding was approved as of August 1, 1995. Construction and installation resumed on August 21, 1995 at the LVAMC. Construction and installation continues and will be completed by late December 1995.

  11. Secondary atomization of coal-water fuels for gas turbine applications: Final report

    SciTech Connect (OSTI)

    Yu, T.U.; Kang, S.W.; Beer, J.M.

    1988-12-01T23:59:59.000Z

    The main research objective was to determine the effectiveness of the CWF treatments on atomization quality when applied to an ultrafine coal-water fuel (solids loading reduced to 50%) and to gas turbine operating conditions (atomization at elevated pressures). Three fuel treatment techniques were studied: (1) heating of CWF under pressure to produce steam as the pressure drops during passage of the CWF through the atomizer nozzle, (2) absorption of CO/sub 2/ gas in the CWF to produce a similar effect, and (3) a combination of the two treatments above. These techniques were expected to produce secondary atomization, that is, disruptive shattering of CWF droplets subsequent to their leaving the atomizing nozzle, and to lead to better burnout and finer fly ash size distribution. A parallel objective was to present quantitative information on the spray characteristics (mean droplet size, radial distribution of droplet size, and spray shape) of CWF with and without fuel treatment, applicable to the design of CWF-burning gas turbine combustors. The experiments included laser diffraction droplet size measurements and high-speed photographic studies in the MIT Spray Test Facility to determine mean droplet size (mass median diameter), droplet size distribution, and spray shape and angle. Three systems of atomized sprays were studied: (1) water sprays heated to a range of temperatures at atmospheric pressure; (2) CWF sprays heated at atmospheric pressure to different temperatures; and (3) sprays at elevated pressure. 31 refs., 47 figs., 1 tab.

  12. MHD Coal Fired Flow Facility. Quarterly technical progress report, July-September 1980

    SciTech Connect (OSTI)

    Altstatt, M. C.; Attig, R. C.; Brosnan, D. A.

    1980-11-01T23:59:59.000Z

    Significant activity, task status, planned research, testing, development, and conclusions for the Magnetohydrodynamics (MHD) Coal-Fired Flow Facility (CFFF) and the Energy Conversion Facility (ECF) are described. On Task 1, the first phase of the downstream quench system was completed. On Task 2, all three combustor sections were completed, hydrotested, ASME code stamped, and delivered to UTSI. The nozzle was also delivered. Fabrication of support stands and cooling water manifolds for the combustor and vitiation heater were completed, heat transfer and thermal stress analysis, along with design development, were conducted on the generator and radiant furnace and secondary combustor installation progressed as planned. Under Task 3 an Elemental Analyzer and Atomic Absorption Spectrophotometer/Graphite Furnace were received and installed, sites were prepared for two air monitoring stations, phytoplankton analysis began, and foliage and soil sampling was conducted using all study plots. Some 288 soil samples were combined to make 72 samples which were analyzed. Also, approval was granted to dispose of MHD flyash and slag at the Franklin County landfill. Task 4 effort consisted of completing all component test plans, and establishing the capability of displaying experimental data in graphical format. Under Task 7, a preliminary testing program for critical monitoring of the local current and voltage non-uniformities in the generator electrodes was outlined, electrode metal wear characteristics were documented, boron nitride/refrasil composite interelectrode sealing was improved, and several refractories for downstream MHD applications were evaluated with promising results.

  13. Milliken Clean Coal Technology Demonstration Project. Environmental monitoring report, July--September 1996

    SciTech Connect (OSTI)

    NONE

    1998-05-01T23:59:59.000Z

    New York State Electric and Gas Corporation (NYSEG) has installed and is presently operating a high-efficiency flue gas desulfurization (FGD) system to demonstrate innovative emissions control technology and comply with the Clean Air Act Amendments of 1990. The host facility for this demonstration project is NYSEG`s Milliken Station, in the Town of Lansing, New York. The primary objective of this project is to demonstrate a retrofit of energy-efficient SO{sub 2} and NO{sub x} control systems with minimal impact on overall plant efficiency. The demonstration project has added a forced oxidation, formic acid-enhanced wet limestone FGD system, which is expected to reduce SO{sub 2} emissions by at least 90 percent. NYSEG also made combustion modifications to each boiler and plans to demonstrate selective non-catalytic reduction (SNCR) technology on unit 1, which will reduce NO{sub x} emissions. Goals of the proposed demonstration include up to 98 percent SO{sub 2} removal efficiency while burning high-sulfur coal, 30 percent NO{sub x} reductions through combustion modifications, additional NO{sub x} reductions using SNCR technology, production of marketable commercial-grade gypsum and calcium chloride by-products to minimize solid waste disposal, and zero wastewater discharge.

  14. Environmental evaluation and restoration plan of the Hoe Creek Underground Coal Gasification Site, Wyoming: Topical report

    SciTech Connect (OSTI)

    Barteaux, W.L.; Berdan, G.L.; Lawrence, J.

    1986-09-01T23:59:59.000Z

    Three underground coal gasification (UCG) experiments were conducted by Lawrence Livermore National Laboratory (LLNL) at the Hoe Creek Site, Wyoming; the Hoe Creek I experiment was conducted in 1976, the Hoe Creek II experiment in 1977, and the Hoe Creek III experiment in 1979. These experiments have had an impact on the land and groundwater quality at the site, and the Department of Energy (DOE) has requested that Western Research Institute (WRI) develop and implement a site restoration plan. The purpose of the plan is to restore the site to conditions being negotiated with the Wyoming Department of Environmental Quality (WDEQ). To prepare for developing a plan, WRI compiled background information on the site. The geologic and hydrologic characteristics of the site were determined, and the water quality data were analyzed. Modelling the site was considered and possible restoration methods were examined. Samples were collected and laboratory tests were conducted. WRI then developed and began implementing a field-scale restoration test. 41 refs, 46 figs., 13 tabs.

  15. Development and testing of a high efficiency advanced coal combustor, Phase III industrial boiler retrofit. Quarterly technical progress report No. 15, April 1, 1995--June 30, 1995

    SciTech Connect (OSTI)

    Scaroni, A.W.; Miller, B.G.; McGowan, J.G.

    1995-08-29T23:59:59.000Z

    The objective of this project is to retrofit a burner capable of firing microfine coal to a standard gas/oil designed industrial boiler to assess the technical and economic viability of displacing premium fuels with microfine coal. This report documents the technical aspects of this project during the fifteenth quarter (April `95 through June `95) of the program. The overall program has consisted of five major tasks: (1.0) A review of current state-of-the-art coal firing system components. (2.0) Design and experimental testing of a prototype HEACC (High Efficiency Advanced Coal Combustor) burner. (3.0) Installation and testing of a prototype HEACC system in a commercial retrofit application. (4.0) Economics evaluation of the HEACC concept for retrofit applications. (5.0) Long term demonstration under commercial user demand conditions. Task 1 through Task 4 were previously completed. Based on all the results obtained to date the ABB/Penn State team and DOE/PETC have decided to conduct a 1000 hr demonstration test (Task 5). Importantly, a decision was made to employ a new burner for the demonstration. The new burner is based on the concept called {open_quotes}Radially Stratified Flame Core (RSFC){close_quotes}, developed by MIT and licensed by ABB. Work under Task 5 of this program was started during this reporting period.

  16. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 1 -- Base program. Final report, October 1986--September 1993

    SciTech Connect (OSTI)

    Smith, V.E.

    1994-05-01T23:59:59.000Z

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  17. Hanna, Wyoming underground coal gasification data base. Volume 4. Hanna II, Phases II and III field test research report

    SciTech Connect (OSTI)

    Bartke, T.C.; Fischer, D.D.; King, S.B.; Boyd, R.M.; Humphrey, A.E.

    1985-08-01T23:59:59.000Z

    This report is part of a seven-volume series on the Hanna, Wyoming, underground coal gasification field tests. Volume 1 is a summary of the project and each of Volumes 2 through 6 describes a particular test. Volume 7 is a compilation of all the data for the tests in Volumes 2 through 6. Hanna II, Phases II and III, were conducted during the winter of 1975 and the summer of 1976. The two phases refer to linking and gasification operations conducted between two adjacent well pairs as shown in Figure 1 with Phase II denoting operations between Wells 5 and 6 and Phase III operations between Wells 7 and 8. All of the other wells shown were instrumentation wells. Wells 7 and 8 were linked in November and December 1975. This report covers: (1) specific site selection and characteristics; (2) test objectives; (3) facilities description; (4) pre-operation tests; (5) test operations summary; and (6) post-test activity. 16 refs., 21 figs., 17 tabs.

  18. AFBC co-firing of coal and hospital waste. Quarterly progress report, May 1--July 31, 1995

    SciTech Connect (OSTI)

    Stuart, J.M.

    1995-12-31T23:59:59.000Z

    The project objective is to design, construct, install, provide operator training and start-up a circulating fluidized bed combustion system at the Lebanon, Pennsylvania Veteran`s Affairs Medical Center. This unit will co-fire coal and hospital waste providing lower cost steam for heating and possibly cooling (absorption chiller) and operation of a steam turbine-generator for limited power generation. This would permit full capacity operation of the FBC year round in spite of the VA laundry that was shut down as well as efficient destruction of both general and infectious hospital waste and steam generation. On February 3, 1995 Donlee notified Lebanon VA and DOE-METC that additional funding would be required to complete the project. This funding, in the amount of $1,140,127, is needed to complete the facility, start-up and shakedown the facility, perform the test program and write the final report. After review DOE-METC approved funding in the amount of $1,246,019 to be available August 1, 1995. This report describes each task of the project and its status.

  19. High conversion of coal to transportation fuels for the future with low HC gas production. Progress report No. 14, January 1--March 31, 1996

    SciTech Connect (OSTI)

    Wiser, W.H.; Oblad, A.G.

    1996-04-01T23:59:59.000Z

    The objective of this project is to produce a synthetic crude from coal at a cost lower than $30.00 per barrel (Task A). A second objective, reflecting a recent change in direction in the synthetic fuels effort of DOE, is to produce a fuel which is low in aromatics, yet of sufficiently high octane number for use in the gasoline- burning transportation vehicles of today. To meet this second objective, research was proposed, and funding awarded, for conversion of the highly-aromatic liquid product from coal conversion to a product high in isoparaffins, which compounds in the gasoline range exhibit a high octane number (Task B). Experimental coal liquefaction studies conducted in a batch microreactor in our laboratory have demonstrated potential for high conversions of coal to liquids with low yields of hydrocarbon (HC) gases, hence small consumption of hydrogen in the primary liquefaction step. Ratios of liquids/HC gases as high as 30/1, at liquid yields as high as 82% of the coal by weight, have been achieved. The principal objective of this work is to examine how nearly we may approach these results in a continuous- flow system, at a size sufficient to evaluate the process concept for production of transportation fuels from coal. A continuous system has been constructed and operated, with a one-half inch inside diameter (ID) tube as the reaction vessel. As the work in this project proceeded toward its conclusion, an unexpected benefit was discovered. As the residence times were decreased to values of 10 seconds or less, ratios of liquids/HC gases of 20/1 or higher were achieved. But very importantly, it was discovered that the chemical reactions which produce the primary liquids can be carried to high conversions at pressures much lower than reported, and indeed required, in the processes at longer times.

  20. Clean Coal Technology III: 10 MW Demonstration of Gas Suspension Absorption final project performance and economics report

    SciTech Connect (OSTI)

    Hsu, F.E.

    1995-08-01T23:59:59.000Z

    The 10 MW Demonstration of the Gas Suspension Absorption (GSA) program is a government and industry co-funded technology development. The objective of the project is to demonstrate the performance of the GSA system in treating a 10 MW slipstream of flue gas resulting from the combustion of a high sulfur coal. This project involves design, fabrication, construction and testing of the GSA system. The Project Performance and Economics Report provides the nonproprietary information for the ``10 MW Demonstration of the Gas Suspension Absorption (GSA) Project`` installed at Tennessee Valley Authority`s (TVA) Shawnee Power Station, Center for Emissions Research (CER) at Paducah, Kentucky. The program demonstrated that the GSA flue-gas-desulfurization (FGD) technology is capable of achieving high SO{sub 2} removal efficiencies (greater than 90%), while maintaining particulate emissions below the New Source Performance Standards (NSPS), without any negative environmental impact (section 6). A 28-day test demonstrated the reliability and operability of the GSA system during continuous operation. The test results and detailed discussions of the test data can be obtained from TVA`s Final Report (Appendix A). The Air Toxics Report (Appendix B), prepared by Energy and Environmental Research Corporation (EERC) characterizes air toxic emissions of selected hazardous air pollutants (HAP) from the GSA process. The results of this testing show that the GSA system can substantially reduce the emission of these HAP. With its lower capital costs and maintenance costs (section 7), as compared to conventional semi-dry scrubbers, the GSA technology commands a high potential for further commercialization in the United States. For detailed information refer to The Economic Evaluation Report (Appendix C) prepared by Raytheon Engineers and Constructors.

  1. A study of toxic emissions from a coal-fired power plant utilizing the SNOX innovative clean coal technology demonstration. Volume 1, Sampling/results/special topics: Final report

    SciTech Connect (OSTI)

    Not Available

    1994-07-01T23:59:59.000Z

    This study was one of a group of assessments of toxic emissions from coal-fired power plants, conducted for DOE during 1993. The motivation for those assessments was the mandate in the 1990 Clean Air Act Amendments that a study be made of emissions of hazardous air pollutants (HAPs) from electric utilities. The report is organized in two volumes. Volume 1: Sampling describes the sampling effort conducted as the basis for this study; Results presents the concentration data on HAPs in the several power plant streams, and reports the results of evaluations and calculations conducted with those data; and Special Topics report on issues such as comparison of sampling methods and vapor/solid distributions of HAPs. Volume 2: Appendices include quality assurance/quality control results, uncertainty analysis for emission factors, and data sheets. This study involved measurements of a variety of substances in solid, liquid, and gaseous samples from input, output, and process streams at the Innovative Clean Coal Technology Demonstration (ICCT) of the Wet Sulfuric Acid-Selective Catalytic Reduction (SNOX) process. The SNOX demonstration is being conducted at Ohio Edison`s Niles Boiler No. 2 which uses cyclone burners to burn bituminous coal. A 35 megawatt slipstream of flue gas from the boiler is used to demonstrate SNOX. The substances measured at the SNOX process were the following: 1. Five major and 16 trace elements, including mercury, chromium, cadmium, lead, selenium, arsenic, beryllium, and nickel; 2. Acids and corresponding anions (HCl, HF, chloride, fluoride, phosphate, sulfate); 3. Ammonia and cyanide; 4. Elemental carbon; 5. Radionuclides; 6. Volatile organic compounds (VOC); 7. Semi-volatile compounds (SVOC) including polynuclear aromatic hydrocarbons (PAH); and 8. Aldehydes.

  2. Behavior of sulfur and chlorine in coal during combustion and boiler corrosion. Technical report, September 1--November 31, 1991

    SciTech Connect (OSTI)

    Chou, C.L.

    1991-12-31T23:59:59.000Z

    The purpose of this project is to conduct laboratory experiments to clarify the mechanism of boiler corrosion, which may lead to solving the corrosion problem associated with the utilization of Illinois` high-sulfur and high-chlorine coal. The kinetics of the release of sulfur and chlorine species during coal combustion is being determined in the laboratories using temperature-programmed pyrolysis coupled with quadrupole gas analysis (QGA) and thermogravimetric analysis in conjunction with Fourier transform infrared spectroscopy (FTIR). Samples of boiler deposits and ashes from different locations in boilers using Illinois coal will be analyzed for mineralogical and chemical compositions to understand the relations among deposit compositions, coal compositions, and the gaseous species in combustion gases. The relationship between the level of chlorine in Illinois coal and boiler corrosion will be studied by experiments with simulated combustion gases under combustion conditions. Reduction of sulfur and chloride concentrations in the flue gas using additives will also be evaluated.

  3. Vhf EPR quantitation and speciation of organic sulfur in coal. [Quarterly] technical report, December 1, 1993--February 28, 1994

    SciTech Connect (OSTI)

    Clarkson, R.B.; Belford, R.I. [Illinois Univ., Urbana, IL (United States)

    1994-06-01T23:59:59.000Z

    The existence of free electrons in coals` natural site offers a great attraction for Electron Paramagnetic Resonance (EPR) analysis to aid in the study of the structure and composition of coal. This direct and non-destructive approach to coal analysis has been hindered by the problem of resolution using the conventional 9.5 GHz EPR spectrometers. In the past few years, we have developed techniques including W-band Very High Frequency EPR spectroscopy as a means of determining the quantity and structure of organic sulfur in native and desulfurized coals. The state of the art 95 GHz (W-band) EPR spectrometer which we have constructed shows a well resolved spectrum including the interaction between unpaired electrons and the heteroatom like sulfur. The spectra also provide quantitative as well as qualitative information regarding different sulfur species. In collaboration with researchers at the University of Kentucky, we are also analyzing the result of desulfurization techniques on the presence of various sulfur species in coal. In the past, we have tried to synthesize various model compounds comparing their W-band spectra with other models, the predictions of theoretical models, and with the W-band spectra of coal specimens. In this quarter, we have been concentrating our efforts on developing a new standard protocol in handling and preparing the coal samples for EPR measurements to provide a quantitative comparison between the EPR spectra of coal in the natural state and desulfurized. Ten coal samples, both native and desulfurized, have been provided to us. These samples have been run in both laboratories. The simulation of coal EPR spectra has been carried out using several mathematical models. EPR results now are being compared with XANES data.

  4. A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, July 1--September 30, 1995

    SciTech Connect (OSTI)

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1995-12-01T23:59:59.000Z

    The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank will be established and maintained for use in this project and will be available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) will be examined. From the literature and data experimentally obtained, a mathematical kinetic model of resid conversion will be constructed. It is anticipated that such a model will provide insights useful for improving process performance and thus the economics of direct coal liquefaction. Some of the contract activities for this quarter are: We completed many of the analyses on the 81 samples received from HTI bench-scale run CMSL-9, in which coal, coal/mixed plastics, and coal/high density polyethylene were fed; Liquid chromatographic separations of the 15 samples in the University of Delaware sample set were completed; and WRI completed CP/MAS {sup 13}C-NMR analyses on the Delaware sample set.

  5. Engineering development of advanced physical fine coal cleaning technologies: Froth flotation. Quarterly technical progress report No. 11, April 1, 1991--June 30, 1991

    SciTech Connect (OSTI)

    Not Available

    1991-12-31T23:59:59.000Z

    This document a quarterly report prepared in accordance with the project reporting requirements covering the period from July 1, 1992 to September 30, 1992. This report provides a summary of the technical work undertaken during this period, highlighting the major results. A brief description of the work done prior to this quarter is provided in this report under the task headings. The overall project scope of the engineering development project is to conceptually develop a commercial flowsheet to maximize pyritic sulfur reduction at practical energy recovery values. This is being accomplished by utilizing the basic research data on the surface properties of coal, mineral matter and pyrite obtained from the Coal Surface Control for Advanced Fine Coal Flotation Project, to develop this conceptual flowsheet. The conceptual flowsheet must be examined to identify critical areas that need additional design data. This data will then be developed using batch and semi-continuous bench scale testing. In addition to actual bench scale testing, other unit operations from other industries processing fine material will be reviewed for potential application and incorporated into the design if appropriate. The conceptual flowsheet will be revised based on the results of the bench scale testing and areas will be identified that need further larger scale design data verification, to prove out the design.

  6. NETL: Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Major Demonstrations Major Demonstrations Since 1985, we have helped fund commercial-scale clean coal technology demonstration projects. ICCS | CCPI | PPII | CCTDP | FutureGen...

  7. Char crystalline transformations during coal combustion and their implications for carbon burnout. Semiannual technical progress report, July 1, 1995--January 1, 1996

    SciTech Connect (OSTI)

    Hurt, R.H.

    1996-05-01T23:59:59.000Z

    Recent work at Sandia National Laboratories, Imperial College, and the U.K. utility PowerGen, has identified an important mechanism believed to have a large influence on unburned carbon levels from pulverized coal fired boilers. That mechanism is char carbon crystalline rearrangements on subsecond times scales at temperatures of 1,800--2,500 K, which lead to char deactivation in the flame zones of furnaces. The so-called thermal annealing of carbons is a well known phenomenon, but its key role in carbon burnout has only recently been appreciated, and there is a lack of quantitative data in this time/temperature range. In addition, a new fundamental tool has recently become available to study crystalline transformations, namely high resolution transmission electron microscopy (HRTEM) fringe imaging, which provides a wealth of information on the nature and degree of crystallinity in carbon materials such as coal chars. Motivated by these new developments, this University Coal Research project has been initiated with the following three goals: to determine transient, high-temperature, thermal deactivation kinetics as a function of parent coal and temperature history; and to characterize the effect of this thermal treatment on carbon crystalline structure through high-resolution transmission electron microscopy and specialized, quantitative image analysis. Work is currently underway on the following three tasks: experimental technique development; thermal deactivation kinetics; and crystal structure characterization. This report discusses the development of the transient heat treatment apparatus, and new algorithms for HRTEM image analysis.

  8. Engineering development of coal-fired high performance power systems, Phase 2 and 3. Quarterly progress report, October 1--December 31, 1995

    SciTech Connect (OSTI)

    NONE

    1995-12-31T23:59:59.000Z

    The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of: >47% thermal efficiency (HHV); NO{sub x}, SO{sub x} and particulates {ge} 10% NSPS; coal {ge} 65% of heat input; all solid wastes benign; and cost of electricity 90% of present plant. The HIPPS generating plant integrates a combustion gas turbine/HRSG combined cycle arrangement with an advanced coal-fired boiler. The unique feature of the HIPPS plant is the partial heating of gas turbine (GT) compressor outlet air using energy released by firing coal in the high temperature advanced furnace (HITAF). The compressed air is additionally heated prior to entering the GT expander section by burning natural gas. Energy available, in the gas turbine exhaust and in the HITAF flue gas are used in a steam cycle to maximize energy production. The HIPPS plant arrangement is thus a combination of existing technologies (gas turbine, heat recovery boilers, conventional steam cycle) and new technologies (the HITAF design especially the heater located in the radiant section). Work reported herein is from Task 1.3, HIPPS Commercial Design and Task 2.2, HITAF Air Heaters.

  9. Development and testing of a high efficiency advanced coal combustor: Phase III, Industrial boiler retrofit. Quarterly technical progress report No. 14, January 1, 1995--March 31, 1995

    SciTech Connect (OSTI)

    Patel, R.L.; Borio, R. [ABB Combustion Engineering Systems, Windsor, CT (United States). U.S. Power Plant Labs.; Scaroni, A.W.; Miller, B.G. [Pennsylvania State Univ., PA (United States); McGowan, J.G. [Massachusetts Univ., MA (United States)

    1995-04-28T23:59:59.000Z

    The objective of this project is to retrofit the previously developed High Efficiency Advanced Coal Combustor (HEACC) to a standard gas/oil designed industrial boiler to assess the technical and economic viability of displacing premium fuels with microfine coal. This report documents the technical aspects of this project during the fourteenth quarter (January `95 through March `95) of the program. The ABB project team met with cognizant DOE-PETC and Penn State personnel on February 15, 1995 at Penn State to discuss our ideas for a new burner (RSFC-based) to replace the HEACC burner prior to the long term ({approximately}1000 hrs) demonstration phase of this project. The main reasons for the proposed new burner were to improve combustion efficiencies and NO{sub x} reduction. Recent, experience at MIT with 5 million Btu/hr coal firing experiments on RSFC burner have shown remarkable performance. Results indicate that RSFC-based burner has the potential to produce lower NO{sub x} and higher carbon conversion efficiencies than the HEACC burner. M.I.T. developed the RSFC burner and obtained a patent for the concept. A decision was made to go with the new, RSFC-based burner during 1000 hr demonstration. ABB-CE will fund the costs ({approximately}$50K) for design/fabrication of the proposed new burner. Penn State plans to improve coal handling by installation of a gravimetric feeder and redesign/installation of a mass flow bottom on the surge bin.

  10. Combustion properties of coal-char blends: NO{sub x} emission characteristics. [Quarterly] technical report, March 1, 1993--May 31, 1993

    SciTech Connect (OSTI)

    Rostam-Abadi, M.; Khan, L.; Khan, S. [Illinois State Geological Survey, Champaign, IL (United States); Smoot, L.D.; Germane, G.J.; Eatough, C.N. [Brigham Young Univ., Provo, UT (United States). Advanced Combustion Engineering Research Center

    1993-09-01T23:59:59.000Z

    Tests under pulverized coal combustion conditions suggest that NO{sub x} formed during release of volatile matter far exceed NO{sub x} formed during combustion of the resulting char. This is attributed to char/NO{sub x} interactions by both direct reduction of NO{sub x} by carbon and char-catalyzed reduction by CO. This implies combustion of char not only produces substantially lower NO{sub x} but the presence of char in the flame during initial stages of combustion may potentially provide catalytic activity for reduction of NO{sub x} produced from volatile nitrogen. The goal of the project is to determine if the concept of NO{sub x} reduction by char/NO{sub x} interactions, while maintaining a high combustion efficiency by co-firing coal with char, is a technically feasible way to reduce NO{sub x}, emissions. The project will provide important combustion data required to establish the feasibility of utilizing chars in industrial combustion applications and the advantages of burning coal-char blends in reducing NO{sub x} and SO{sub 2} emissions. During the reporting period, 19 runs were made with a continuous feed charring oven (CFCO) to produce 237 pounds of char(about 16%vm) required for preparing coal-char blends.

  11. Analyzing organic sulfur in coal/char: Integrated mild gasification/XANES methods. Technical report, 1 March--31 May 1994

    SciTech Connect (OSTI)

    Palmer, S.R. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mechanical Engineering and Energy Processes; Huffman, G.P. [Kentucky Univ., Lexington, KY (United States)

    1994-09-01T23:59:59.000Z

    The overall goal of this study is to improve the understanding of sulfur in coals/chars via the use of combined advanced non-destructive and advanced destructive methods of sulfur analysis. This study combines selective oxidation, analytical pyrolysis, and sulfur X-ray Absorption Near Edge Structure Spectroscopy (XANES) analysis. Samples with a wide variety of sulfur contents, (0.63% to 4.40%) have been prepared for use in this study. This includes steam gasification chars, oxidized coals and desulfurized coals as well of the original unaltered coals. Mild pyrolysis and preliminary XANES data shows that the sulfur chemistry of gasification chars is significantly different from that of the original coals. Mild pyrolysis of the samples that were oxidized with peroxyacetic acid showed that the level of simple thiophene structures observed in the pyrolysis products declines with increasing levels of oxidation. Sulfur XANES spectra of treated samples showed various effects depending on the treatment severity. For the less severely treated samples (demineralization and solvent extraction), the XANES spectra were similar, although not identical, to the untreated coal spectra, whereas the more severe treatments (steam at 450 C; peroxyacetic acid at 25 C) showed preferential oxidation of one or more sulfur-bearing phases in the original coal. Additional samples have recently been examined by XANES and W-band EPR and the data is currently being processed and evaluated.

  12. A characterization and evaluation of coal liquefaction process streams. Quarterly technical progress report, April 1--June 30, 1995

    SciTech Connect (OSTI)

    Robbins, G.A.; Brandes, S.D.; Winschel, R.A.; Burke, F.P.

    1995-09-01T23:59:59.000Z

    The objectives of this project are to support the DOE direct coal liquefaction process development program and to improve the useful application of analytical chemistry to direct coal liquefaction process development. Independent analyses by well-established methods will be obtained of samples produced in direct coal liquefaction processes under evaluation by DOE. Additionally, analytical instruments and techniques which are currently underutilized for the purpose of examining coal-derived samples will be evaluated. The data obtained from this study will be used to help guide current process development and to develop an improved data base on coal and coal liquids properties. A sample bank will be established and maintained for use in this project and will be available for use by other researchers. The reactivity of the non-distillable resids toward hydrocracking at liquefaction conditions (i.e., resid reactivity) will be examined. From the literature and data experimentally obtained, a mathematical kinetic model of resid conversion will be constructed. It is anticipated that such a model will provide insights useful for improving process performance and thus the economics of direct coal liquefaction. The paper describes activities carried out this quarter. 11 refs., 21 figs., 17 tabs.

  13. Coal-fueled diesel system for stationary power applications -- Technology development. Final report, March 1988--June 1994

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    Morgantown Energy Technology Center, Cooper-Bessemer and Arthur D. Little have developed the technology to enable coal-water slurry to be utilized in large-bore, medium-speed diesel engines. The target application is modular power generation in the 10 to 100 MW size, with each plant using between two and eight engines. Such systems are expected to be economically attractive in the non-utility generation market after 2000, when oil and natural gas prices are expected to escalate rapidly compared to the price of coal. During this development program, over 1,000 hours of prototype engine operation have been achieved on coal-water slurry (CWS), including over 100 hours operation of a six-cylinder, 1.8 MW engine with an integrated emissions control system. Arthur D. Little, Inc., managed the coal-fueled diesel development, with Cooper-Bessemer as the principal subcontractor responsible for the engine design and testing. Several key technical advances which enable the viability of the coal-fueled diesel engine were made under this program. Principal among them are the development and demonstration of (1) durable injection nozzles; (2) an integrated emissions control system; ad (3) low-cost clean coal slurry formulations optimized for the engine. Significant advances in all subsystem designs were made to develop the full-scale Cooper-Bessemer coal engine components in preparation for a 100-hour proof-of-concept test of an integrated system, including emissions controls. The Clean Coal Diesel power plant of the future will provide a cost-competitive, low-emissions, modular, coal-based power generation option to the non-utility generation, small utility, independent power producer, and cogeneration markets. Combined cycle efficiencies will be approximately 48% (lower heating value basis) and installed cost will be approximately $1,300/kW (1992 dollars).

  14. Washability of trace elements in product coals from Illinois mines. Technical report, 1 March--31 May 1994

    SciTech Connect (OSTI)

    Demir, I.; Ruch, R.R.; Harvey, R.D.; Steele, J.D.; Khan, S.

    1994-09-01T23:59:59.000Z

    Existing washability data on trace elements in Illinois coals were generated using float-sink methods, which are not applicable to modern froth flotation or column flotation processes. Particularly, there is a lack of washability data on product (as-shipped) coals from modern preparation plants. The goal of this project is to provide the needed trace element washability (release analysis) data on as-shipped Illinois coals using a froth flotation/release analysis (FF/RA) procedure. The results generated by this project will promote industrial utilization of Illinois coals and help assess the effect of new environmental requirements on the use of these coals in utility steam generation. During the third quarter, preparation and submission of all samples for chemical analysis were completed. Analyses of the samples produced by cleaning 34 as-shipped coals using FF/RA were completed for ash, moisture, S, heating value (BTU), and F, and some for Mn and oxide composition. The rest of the analytical work is in progress. The analytical data are being used to evaluate removal of ash, S, and trace elements from the as-shipped coals at the chosen flotation conditions and particles sizes. Available data on the FF/RA of five as-shipped coals at {minus}100, {minus}200, {minus}400 mesh sizes indicate that ash and F rejections increase with decreasing particle size. For the {minus}400 mesh tests, 70--90% of the ash and 35--74% of F were rejected at a BTU or combustibles recovery of 80%. One of the as-shipped coals was previously subjected to FF/RA tests at {minus}100 and {minus}400 mesh sizes to investigate mass balances achievable for the procedure. Preliminary results on ash and F contents of complete set of flotation products from the two tests indicate a mass balance of 95 to 100%.

  15. Pilot plant testing of Illinois coal for blast furnace injection. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Crelling, J.C. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Geology

    1994-12-31T23:59:59.000Z

    The purpose of this study is to evaluate the combustion of Illinois coal in the blast furnace injection process in a new and unique pilot plant test facility. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. This study is unique in that it is the first North American effort to directly determine the nature of the combustion of coal injected into a blast furnace. It is intended to complete the study already underway with the Armco and Inland steel companies and to demonstrate quantitatively the suitability of both the Herrin No. 6 and Springfield No. 5 coals for blast furnace injection. The main feature of the current work is the testing of Illinois coals at CANMET`s (Canadian Centre for Mineral and Energy Technology) pilot plant coal combustion facility. This facility simulates blowpipe-tuyere conditions in an operating blast furnace, including blast temperature (900 C), flow pattern (hot velocity 200 m/s), geometry, gas composition, coal injection velocity (34 m/s) and residence time (20 ms). The facility is fully instrumented to measure air flow rate, air temperature, temperature in the reactor, wall temperature, preheater coil temperature and flue gas analysis. During this quarter a sample of the Herrin No. 6 coal (IBCSP 112) was delivered to the CANMET facility and testing is scheduled for the week of 11 December 1994. Also at this time, all of the IBCSP samples are being evaluated for blast furnace injection using the CANMET computer model.

  16. Health-hazard evaluation report MHETA 89-009-1990, Consolidation Coal Company, Humphrey No. 7 Mine, Pentress, West Virginia

    SciTech Connect (OSTI)

    Kullman, G.J.

    1989-09-01T23:59:59.000Z

    An evaluation was made of worker exposure to hydraulic fluid used on the longwall-mining operations at Consolidated Coal Company's Humphrey Number 7 Mine, Pentress, West Virginia. Employees were complaining of headache, eye and throat irritation, congestion, and cough. A particular emulsion oil, Solcenic-3A, was used with water in the mine's hydraulic roof-support system. An analysis of the oil indicated the presence of methyl-isobutyl-carbinol (MIBC), dipropylene glycol, and paraffin hydrocarbons. Personal breathing-zone samples for MIBC were collected from all workers on the longwall mining operation during the two days of the visit. All the analysis indicated concentrations of MIBC below the limit of quantification, which was 0.6 parts per million for an 8 hour sample. These levels were well below the exposure recommendations of the Mine Safety and Health Administration. Exposure to MIBC may be occurring through skin contact with oil through hydraulic line leaks, accidents, and maintenance activity on the hydraulic machines. The report concludes that Solcenic-3A oil constituents in air did not pose a health hazard at the time of the survey.

  17. AFBC co-firing of coal and hospital waste. Quarterly progress report, February 1, 1995--April 30, 1995

    SciTech Connect (OSTI)

    Stuart, J.M.

    1996-01-01T23:59:59.000Z

    The project objective is to design, construct, install, provide operator training and start-up a circulating fluidized bed combustion system at the Lebanon Pennsylvania Veteran`s Affairs Medical Center. This unit will co-fire coal and hospital waste providing inexpensive and efficient destruction of both general and infectious hospital waste and steam generation. The steam generated is as follows: (1) Steam = 20,000 lb/hr, (2) Temperature = 353 F (saturated), (3) Pressure = 125 psig, and (4) Steam quality ={approximately}98.5%. On February 3, 1995 DONLEE notified Lebanon VA and DOE-METC that additional funding would be required to complete the project. This funding, in the amount of $1,140,127, is needed to complete the facility, start-up and shakedown the facility, perform the test program and write the final report. On March 7, 1995 the vendors were notified that the Lebanon VA Steam Plant Project was shut down and that all work outside DONLEE was stopped pending obtaining additional funding.

  18. Carbonation as a binding mechanism for coal/calcium hydroxide pellets. Technical report, December 1, 1992--February 28, 1993

    SciTech Connect (OSTI)

    Rapp, D.; Lytle, J.; Hackley, K.; Dagamac, M. [Illinois State Geological Survey, Champaign, IL (United States); Berger, R. [Illinois Univ., Urbana, IL (United States); Schanche, G. [Army Construction Engineering Research Lab., Champaign, IL (United States)

    1993-05-01T23:59:59.000Z

    Pelletization of fine coal with calcium hydroxide, a sulfur capturing sorbent, represents a method to produce a fuel which will burn in compliance with the recently passed Clean Air Act Amendments (CAAA`s). To harden the pellets, the reaction of carbon dioxide with calcium hydroxide, referred to as carbonation, is being studied. Carbonation forms a bonding matrix of calcium carbonate. This is a two-year research program. This report covers the second quarter of the second year. Research is indicating that 5 to 10 wt% calcium hydroxide pellets can be produced via a roller-and-die pellet mill and air cured to achieve sufficient quality for handling and transportation. This quarter, 1/2 inch-diameter pellets containing 10% calcium hydroxide were demonstrated to gradually react with atmospheric carbon dioxide (3 days) while air drying to achieve compressive strengths equivalent to those attained for fully dried pellets which had been carbonated for one-hour with 100% commercial grade carbon dioxide. It was also demonstrated that an organic, adhesive binder, corn starch, can be very effective at producing strong pellets but drying is required before appreciable pellet strength is attained. For pellets containing 2 wt% corn starch, it was determined that less than 50% of the ultimate strength was achieved as the pellets were dried from 20 wt% to 5 wt% moisture. Strength improved considerably as the pellet moisture content was reduced below 5 wt%.

  19. Underground coal gasification: Development of theory, laboratory experimentation, interpretation, and correlation with the Hanna field tests: Final report

    SciTech Connect (OSTI)

    Gunn, R.D.; Krantz, W.B.

    1987-03-01T23:59:59.000Z

    The following report is a description of a 7 year effort to develop a theoretical understanding of the underground coal gasification process. The approach used is one of the mathematical model development from known chemical and principles, simplification of the models to isolate important effects, and through validation of models to isolate important effects, and through validation of models with laboratory experiments and field test data. Chapter I contains only introductory material. Chapter II describes the development of two models for reverse combustion: a combustion model and a linearized model for combustion front instability. Both models are required for realistic field predictions. Chapter III contains a discussion of a successful forward gasification model. Chapter IV discusses the spalling-enhanced-drying model is applicable to prediction of cavity growth and subsidence. Chapter VI decribes the correct use of energy and material balances for the analysis of UCG field test data. Chapter VII shows how laboratory experiments were used to validate the models for reverse combustion and forward gasification. It is also shown that laboratory combustion tube experiments can be used to simulate gas compositions expected from field tests. Finally, Chapter VII presents results from a comprehensive economic analysis of UCG involving 1296 separate cases. 37 refs., 49 figs., 12 tabs.

  20. Carbonation as a binding mechanism for coal/calcium hydroxide pellets. Technical report, September 1, 1991--November 30, 1991

    SciTech Connect (OSTI)

    Rapp, D.M.

    1991-12-31T23:59:59.000Z

    Current coal mining and processing procedures produce a significant quanity of fine coal that is difficult to handle and transport. The objective of this work is to determine if these fines can be economically pelletized with calcium hydroxide, a sulfur capturing sorbent, to produce a clean-burning fuel for fluidized-bed combustors or stoker boilers. To harden these pellets, carbonation, which is the reaction of calcium hydroxide with carbon dioxide to produce a cementitious matrix of calcium carbonate, is being investigated. Previous research indicated that carbonation significantly improved compressive strength, impact and attrition resistance and ``weatherproofed`` pellets formed with sufficient calcium hydroxide (5 to 10% for minus 28 mesh coal fines).