Sample records for removing asphalt compounds

  1. Removal of arsenic compounds from petroliferous liquids

    DOE Patents [OSTI]

    Fish, R.H.

    1984-04-06T23:59:59.000Z

    The present invention in one aspect comprises a process for removing arsenic from petroliferous-derived liquids by contacting said liquid with a divinylbenzene-crosslinked polystyrene polymer (i.e. PS-DVB) having catechol ligands anchored to said polymer, said contacting being at an elevated temperature. In another aspect, the invention is a process for regenerating spent catecholated polystyrene polymer by removal of the arsenic bound to it from contacting petroliferous liquid in accordance with the aspect described above which regenerating process comprises: (a) treating said spent catecholated polystyrene polymer with an aqueous solution of at least one member selected from the group consisting of carbonates and bicarbonates of ammonium, alkali metals, and alkaline earth metals, said solution having a pH between about 8 and 10, and said treating being at a temperature in the range of about 20/sup 0/ to 100/sup 0/C; (b) separating the solids and liquids from each other. In a preferred embodiment the regeneration treatment is in two steps wherein step: (a) is carried out with an aqueous alcoholic carbonate solution which includes at least one lower alkyl alcohol, and, steps (c) and (d) are added. Steps (c) and (d) comprise: (c) treating the solids with an aqueous alcoholic solution of at least one ammonium, alkali or alkaline earth metal bicarbonate at a temperature in the range of about 20 to 100/sup 0/C; and (d) separating the solids from the liquids.

  2. Process for removing heavy metal compounds from heavy crude oil

    DOE Patents [OSTI]

    Cha, Chang Y. (Golden, CO); Boysen, John E. (Laramie, WY); Branthaver, Jan F. (Laramie, WY)

    1991-01-01T23:59:59.000Z

    A process is provided for removing heavy metal compounds from heavy crude oil by mixing the heavy crude oil with tar sand; preheating the mixture to a temperature of about 650.degree. F.; heating said mixture to up to 800.degree. F.; and separating tar sand from the light oils formed during said heating. The heavy metals removed from the heavy oils can be recovered from the spent sand for other uses.

  3. Aged asphalt

    E-Print Network [OSTI]

    Martin, Kenneth Lloyd

    1988-01-01T23:59:59.000Z

    Dorchester Asphalts Exxon Asphalts CONCLUSIONS RECOMMENDATIONS LITERATURE CITED APPENDIX 41 42 48 59 70 84 90 93 96 99 103 105 106 A. GEL PERMEATION CHROMATOGRAMS OF TEST ASPHALTS 108 B. FOURIER-TRANSFORM INFRARED SPECTRUMS OF TEST... Apparatus 5. Abson Method Apparatus 6. ASTM D 2171 Apparatus 7. Sample Pellet Die 8. Sample Pellet Holder 21 23 27 29 38 40 9. GPC of Lufkin Exxon AC-20 Extracted by Two Methods . . . . . . . . . . . . . . . . 46 10. GPC of Dickens Exxon AC-20 51...

  4. Process for removing an organic compound from water

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Kaschemekat, Jurgen (Palo Alto, CA); Wijmans, Johannes G. (Menlo Park, CA); Kamaruddin, Henky D. (San Francisco, CA)

    1993-12-28T23:59:59.000Z

    A process for removing organic compounds from water is disclosed. The process involves gas stripping followed by membrane separation treatment of the stripping gas. The stripping step can be carried out using one or multiple gas strippers and using air or any other gas as stripping gas. The membrane separation step can be carried out using a single-stage membrane unit or a multistage unit. Apparatus for carrying out the process is also disclosed. The process is particularly suited for treatment of contaminated groundwater or industrial wastewater.

  5. Integrated coke, asphalt and jet fuel production process and apparatus

    DOE Patents [OSTI]

    Shang, Jer Y. (McLean, VA)

    1991-01-01T23:59:59.000Z

    A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

  6. Experimental Study on Geocell-Reinforced Recycled Asphalt Pavement (RAP) Bases under Static and Cyclic Loading

    E-Print Network [OSTI]

    Thakur, Jitendra Kumar

    2011-01-13T23:59:59.000Z

    Recycled Asphalt Pavement (RAP) is a removed and reprocessed pavement material containing asphalt and aggregates which can be used as a base course material for pavement applications. Geocells are a three-dimensional interconnected honeycomb type...

  7. Method for removing chlorine compounds from hydrocarbon mixtures

    DOE Patents [OSTI]

    Janoski, E.J.; Hollstein, E.J.

    1984-09-29T23:59:59.000Z

    A process for removing halide ions from a hydrocarbon feedstream containing halogenated hydrocarbons wherein the contaminated feedstock is contacted with a solution of a suitable oxidizing acid containing a lanthanide oxide, the acid being present in a concentration of at least about 50 weight percent for a time sufficient to remove substantially all of the halide ion from the hydrocarbon feedstock.

  8. Methods of hydrotreating a liquid stream to remove clogging compounds

    DOE Patents [OSTI]

    Minderhoud, Johannes Kornelis [Amsterdam, NL; Nelson, Richard Gene [Katy, TX; Roes, Augustinus Wilhelmus Maria [Houston, TX; Ryan, Robert Charles [Houston, TX; Nair, Vijay [Katy, TX

    2009-09-22T23:59:59.000Z

    A method includes producing formation fluid from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a gas stream. At least a portion of the liquid stream is provided to a hydrotreating unit. At least a portion of selected in situ heat treatment clogging compositions in the liquid stream are removed to produce a hydrotreated liquid stream by hydrotreating at least a portion of the liquid stream at conditions sufficient to remove the selected in situ heat treatment clogging compositions.

  9. Precipitate hydrolysis process for the removal of organic compounds from nuclear waste slurries

    DOE Patents [OSTI]

    Doherty, J.P.; Marek, J.C.

    1987-02-25T23:59:59.000Z

    A process for removing organic compounds from a nuclear waste slurry comprising reacting a mixture of radioactive waste precipitate slurry and an acid in the presence of a catalytically effective amount of a copper(II) catalyst whereby the organic compounds in the precipitate slurry are hydrolyzed to form volatile organic compounds which are separated from the reacting mixture. The resulting waste slurry, containing less than 10 percent of the original organic compounds, is subsequently blended with high level radioactive sludge land transferred to a vitrification facility for processing into borosilicate glass for long-term storage. 2 figs., 3 tabs.

  10. Precipitate hydrolysis process for the removal of organic compounds from nuclear waste slurries

    DOE Patents [OSTI]

    Doherty, Joseph P. (Elkton, MD); Marek, James C. (Augusta, GA)

    1989-01-01T23:59:59.000Z

    A process for removing organic compounds from a nuclear waste slurry comprising reacting a mixture of radioactive waste precipitate slurry and an acid in the presence of a catalytically effective amount of a copper (II) catalyst whereby the organic compounds in the precipitate slurry are hydrolyzed to form volatile organic compounds which are separated from the reacting mixture. The resulting waste slurry, containing less than 10 percent of the orginal organic compounds, is subsequently blended with high level radioactive sludge and transferred to a virtrification facility for processing into borosilicate glass for long-term storage.

  11. Bibliography of work on the photocatalytic removal of hazardous compounds from water and air

    SciTech Connect (OSTI)

    Blake, D.M.

    1994-05-01T23:59:59.000Z

    This is a bibliography of information in the open literature on work that has been done to date on the photocatalytic oxidation of compounds, principally organic compounds. The goal of the listing is removing hazardous oompounds from water or air. It contains lists of substances and literature citations. The bibliography includes information obtained through the middle of 1993 and some selected references for the balance of that year.

  12. Composites for removing metals and volatile organic compounds and method thereof

    DOE Patents [OSTI]

    Coronado, Paul R. (Livermore, CA); Coleman, Sabre J. (Oakland, CA); Reynolds, John G. (San Ramon, CA)

    2006-12-12T23:59:59.000Z

    Functionalized hydrophobic aerogel/solid support structure composites have been developed to remove metals and organic compounds from aqueous and vapor media. The targeted metals and organics are removed by passing the aqueous or vapor phase through the composite which can be in molded, granular, or powder form. The composites adsorb the metals and the organics leaving a purified aqueous or vapor stream. The species-specific adsorption occurs through specific functionalization of the aerogels tailored towards specific metals and/or organics. After adsorption, the composites can be disposed of or the targeted metals and/or organics can be reclaimed or removed and the composites recycled.

  13. Process for removing halogenated aliphatic and aromatic compounds from petroleum products

    DOE Patents [OSTI]

    Googin, J.M.; Napier, J.M.; Travaglini, M.A.

    1983-09-20T23:59:59.000Z

    A process is described for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contacting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible compound, such as, water or a polyhydroxy compound, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of water or polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the water or polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds and the low polar or nonpolar solvent are separated by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered from recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 1 fig.

  14. Process for removing halogenated aliphatic and aromatic compounds from petroleum products

    DOE Patents [OSTI]

    Googin, John M. (Oak Ridge, TN); Napier, John M. (Oak Ridge, TN); Travaglini, Michael A. (Oliver Springs, TN)

    1983-01-01T23:59:59.000Z

    A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contacting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible compound, such as, water or a polyhydroxy compound, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of water or polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the water or polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds and the low polar or nonpolar solvent are separated by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered from recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced.

  15. Tertiary nitrogen heterocyclic material to reduce moisture-induced damage in asphalt-aggregate mixtures

    DOE Patents [OSTI]

    Plancher, Henry (Laramie, WY); Petersen, Joseph C. (Laramie, WY)

    1982-01-01T23:59:59.000Z

    Asphalt-aggregate roads crack when subjected to freezing and thawing cycles. Herein, the useful life of asphalts are substantially improved by a minor amount of a moisture damage inhibiting agent selected from compounds having a pyridine moiety, including acid salts of such compounds. A shale oil fraction may serve as the source of the improving agent and may simply be blended with conventional petroleum asphalts.

  16. Application of Metagenomics for Identification of Novel Petroleum Hydrocarbon Degrading Enzymes in Natural Asphalts from the Rancho La Brea Tar Pits

    E-Print Network [OSTI]

    Baquiran, Jean-Paul Mendoza

    2010-01-01T23:59:59.000Z

    and the origin of heavy oil. Nature, 426, 344-352. HEITKAMP,natural asphalts and heavy oil compounds. A major questionmainly of asphalts and heavy oils, which have saturated into

  17. Asphalt Oxidation Kinetics and Pavement Oxidation Modeling

    E-Print Network [OSTI]

    Jin, Xin

    2012-07-16T23:59:59.000Z

    Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement...

  18. Pilot scale test of a produced water-treatment system for initial removal of organic compounds

    SciTech Connect (OSTI)

    Sullivan, Enid J [Los Alamos National Laboratory; Kwon, Soondong [UT-AUSTIN; Katz, Lynn [UT-AUSTIN; Kinney, Kerry [UT-AUSTIN

    2008-01-01T23:59:59.000Z

    A pilot-scale test to remove polar and non-polar organics from produced water was performed at a disposal facility in Farmington NM. We used surfactant-modified zeolite (SMZ) adsorbent beds and a membrane bioreactor (MBR) in combination to reduce the organic carbon content of produced water prior to reverse osmosis (RO). Reduction of total influent organic carbon (TOC) to 5 mg/L or less is desirable for efficient RO system operation. Most water disposed at the facility is from coal-bed gas production, with oil production waters intermixed. Up to 20 gal/d of produced water was cycled through two SMZ adsorbent units to remove volatile organic compounds (BTEX, acetone) and semivolatile organic compounds (e.g., napthalene). Output water from the SMZ units was sent to the MBR for removal of the organic acid component of TOC. Removal of inorganic (Mn and Fe oxide) particulates by the SMZ system was observed. The SMZ columns removed up to 40% of the influent TOC (600 mg/L). BTEX concentrations were reduced from the initial input of 70 mg/L to 5 mg/L by the SMZ and to an average of 2 mg/L after the MBR. Removal rates of acetate (input 120-170 mg/L) and TOC (input up to 45 mg/L) were up to 100% and 92%, respectively. The water pH rose from 8.5 to 8.8 following organic acid removal in the MBR; this relatively high pH was likely responsible for observed scaling of the MBR internal membrane. Additional laboratory studies showed the scaling can be reduced by metered addition of acid to reduce the pH. Significantly, organic removal in the MBR was accomplished with a very low biomass concentration of 1 g/L throughout the field trial. An earlier engineering evaluation shows produced water treatment by the SMZ/MBR/RO system would cost from $0.13 to $0.20 per bbl at up to 40 gpm. Current estimated disposal costs for produced water are $1.75 to $4.91 per bbl when transportation costs are included, with even higher rates in some regions. Our results suggest that treatment by an SMZ/MBR/RO system may be a feasible alternative to current methods for produced water treatment and disposal.

  19. The use of HPGPC for determination of MWD of asphalt cement - A spectrophotometric vs. gravimetric finish

    SciTech Connect (OSTI)

    Bishara, S.W.; McReynolds, R.L. (Kansas Dept. of Transportation, Topeka (United States))

    1990-07-01T23:59:59.000Z

    A comparison between spectrophotometric and gravimetric methods to study MWD of asphalt is presented. Spectrophotometry suffers from not detecting saturated compounds, as well as from variation of molar absorptivity during analysis. To address these shortcoming, the whole asphalt sample is fractionated, and the relative molar absorptivity determined for each fraction. Using another sample weight of the whole asphalt, the saturates are separated, and injected to get their MWD using refractive index detection. This information, when used to mathematically treat the whole asphalt distribution data, can correct the latter to include saturates as well, but can only partially account for continuous variation of the molar absorptivity.

  20. Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds

    SciTech Connect (OSTI)

    Chang, Shih-Ger; Yan, Nai-Qiang; Qu, Zan; Chi, Yao; Qiao, Shao-Hua; Dod, Ray; Chang, Shih-Ger; Miller, Charles

    2008-07-02T23:59:59.000Z

    Oxidation of Hg0 with any oxidant or converting it to a particle-bound form can facilitate its removal. Two sulfur-chlorine compounds, sulfur dichloride (SCl2) and sulfur monochloride (S2Cl2), were investigated as oxidants for Hg0 by gas phase reaction and by surface-involved reactions in the presence of flyash or activated carbon. The gas phase reaction rate constants between Hg0 and the sulfur/chlorine compounds were determined, and the effects of temperature and the main components in flue gases were studied. The gas phase reaction between Hg0 and SCl2 is shown to be more rapid than the gas phase reaction with chlorine, and the second order rate constant was 9.1(+-0.5) x 10-18 mL-molecules-1cdots-1 at 373oK. Nitric oxide (NO) inhibited the gas phase reaction of Hg0 with sulfur-chlorine compounds. The presence of flyash or powdered activated carbon in flue gas can substantially accelerate the reaction. The predicted Hg0 removal is about 90percent with 5 ppm SCl2 or S2Cl2 and 40 g/m3 of flyash in flue gas. The combination of activated carbon and sulfur-chlorine compounds is an effective alternative. We estimate that co-injection of 3-5 ppm of SCl2 (or S2Cl2) with 2-3 Lb/MMacf of untreated Darco-KB is comparable in efficiency to the injection of 2-3 Lb/MMacf Darco-Hg-LH. Extrapolation of kinetic results also indicates that 90percent of Hg0 can be removed if 3 Lb/MMacf of Darco-KB pretreated with 3percent of SCl2 or S2Cl2 is used. Unlike gas phase reactions, NO exhibited little effect on Hg0 reactions with SCl2 or S2Cl2 on flyash or activated carbon. Mercuric sulfide was identified as one of the principal products of the Hg0/SCl2 or Hg0/S2Cl2 reactions. Additionally, about 8percent of SCl2 or S2Cl2 in aqueous solutions is converted to sulfide ions, which would precipitate mercuric ion from FGD solution.

  1. asphalt: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    asphalt pavements containing asphalt binder and aggregates. The use of RAP can reduce the cost of construction materials, reduce the amount of waste... Thakur, Jitendra Kumar...

  2. asphalts: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    asphalt pavements containing asphalt binder and aggregates. The use of RAP can reduce the cost of construction materials, reduce the amount of waste... Thakur, Jitendra Kumar...

  3. BBR Asphalt mixture creep test BBR Asphalt mixture creep size effect

    E-Print Network [OSTI]

    Minnesota, University of

    #12;Outline ØBBR Asphalt mixture creep test ØBBR Asphalt mixture creep size effect ØBBR Asphalt Point Bending Test Low temperature 3-point bending creep tests on specimens with three different sizes mixture strength test ØBBR Asphalt binder strength test #12;Asphalt Pavements ØRecent efforts under NCHRP

  4. Process for removing halogenated aliphatic and aromatic compounds from petroleum products. [Polychlorinated biphenyls; methylene chloride; perchloroethylene; trichlorofluoroethane; trichloroethylene; chlorobenzene

    DOE Patents [OSTI]

    Googin, J.M.; Napier, J.M.; Travaglini, M.A.

    1982-03-31T23:59:59.000Z

    A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contracting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible polyhydroxy compound, such as, water, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds in the low polar or nonpolar solvent by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered for recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 2 tables.

  5. Asphalt Roofing Shingles Into Energy Project Summary Report

    SciTech Connect (OSTI)

    Jameson, Rex, PE

    2008-04-28T23:59:59.000Z

    Based on a widely cited September, 1999 report by the Vermont Agency of Natural Resources, nearly 11 million tons of asphalt roofing shingle wastes are produced in the United States each year. Recent data suggests that the total is made up of about 9.4 million tons from roofing tear-offs and about 1.6 million tons from manufacturing scrap. Developing beneficial uses for these materials would conserve natural resources, promote protection of the environment and strengthen the economy. This project explored the feasibility of using chipped asphalt shingle materials in cement manufacturing kilns and circulating fluidized bed (CFB) boilers. A method of enhancing the value of chipped shingle materials for use as fuel by removing certain fractions for use as substitute raw materials for the manufacture of new shingles was also explored. Procedures were developed to prevent asbestos containing materials from being processed at the chipping facilities, and the frequency of the occurrence of asbestos in residential roofing tear-off materials was evaluated. The economic feasibility of each potential use was evaluated based on experience gained during the project and on a review of the well established use of shingle materials in hot mix asphalt. This project demonstrated that chipped asphalt shingle materials can be suitable for use as fuel in circulating fluidized boilers and cement kilns. More experience would be necessary to determine the full benefits that could be derived and to discover long term effects, but no technical barriers to full scale commercial use of chipped asphalt shingle materials in these applications were discovered. While the technical feasibility of various options was demonstrated, only the use of asphalt shingle materials in hot mix asphalt applications is currently viable economically.

  6. Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded ­ II ­ Asphalt Pavements ­ Effect of Aging ­ Simulations ­ Concluding Remarks #12;3 Objectives Develop) Correspondence Principle based formulation Application: Asphalt concrete pavements (Part II) #12;4 Asphalt

  7. Method and apparatus for converting and removing organosulfur and other oxidizable compounds from distillate fuels, and compositions obtained thereby

    DOE Patents [OSTI]

    D'Alessandro, Robert N. (Spanish Fort, AL); Tarabocchia, John (Parsippany, NJ); Jones, Jerald Andrew (Frankfurt am Main, DE); Bonde, Steven E. (West Richard, WA); Leininger, Stefan (Langenselbold, DE)

    2010-10-26T23:59:59.000Z

    The present disclosure is directed to a multi-stage system and a process utilizing said system with the design of reducing the sulfur-content in a liquid comprising hydrocarbons and organosulfur compounds. The process comprising at least one of the following states: (1) an oxidation stage; (2) an extraction state; (3) a raffinate washing stage; (4) a raffinate polishing stage; (5) a solvent recovery stage; (6) a solvent purification stage; and (7) a hydrocarbon recovery stage. The process for removing sulfur-containing hydrocarbons from gas oil, which comprises oxidizing gas oil comprising hydrocarbons and organosulfur compounds to obtain a product gas oil.

  8. Method for removing sulfur compounds from C/sub 6/ and lower alkanes

    SciTech Connect (OSTI)

    Keyworth, D.A.

    1989-03-28T23:59:59.000Z

    A process is described for recovering a low sulfur content hydrocarbon fraction having a boiling point of n-hexane or less from a hydrocarbon stream containing hydrocarbons boiling at or below the boiling point of hexane and organic sulfur compounds comprising monosulfides boiling at or below the boiling point of n-hexane. It consists of contacting the hydrocarbon stream with a dilute aqueous solution of sodium hypochlorite for a time sufficient to convert a selected amount of monosulfide compounds present to compounds having boiling points above the boiling point of n-hexane, separating an aqueous phase and a hydrocarbon phase and fractionally distilling the hydrocarbon phase to recover a hydrocarbon fraction having a boiling point of n-hexane or less, and having a reduced amount of the organic sulfur compounds.

  9. Life Cycle Assessment of Reclaimed Asphalt Pavement

    E-Print Network [OSTI]

    Minnesota, University of

    Life Cycle Assessment of Reclaimed Asphalt Pavement to Improve Asphalt Pavement Sustainability By Pavement (RAP) Courtesy of http://myconstructionphotos.smugmug.com/ RAP #12;Transport Back to the Plant-melt old binder on the RAP #12;Life Cycle Assessment (LCA) · #12;Asphalt Pavement Life Cycle Road

  10. A novel method of bitumen extraction from asphalt pavement

    SciTech Connect (OSTI)

    Houser, T.J. (Western Michigan Univ., Kalamazoo (United States))

    1990-07-01T23:59:59.000Z

    A new method of extracting bitumen from asphalt pavement mixtures has been developed which does not require chlorinated or aromatic compounds for solvents. The preferred solvent is cyclohexane (although cyclopentane may be used) at high temperatures and pressures. The new method requires equipment that is less costly than the centrifuge method currently used and takes less time than extractions with Bioact but more time than when chlorocompounds are used.

  11. Removal of arsenic, vanadium and/or nickel compounds from spent catecholated polymer

    DOE Patents [OSTI]

    Fish, R.H.

    1987-04-21T23:59:59.000Z

    Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20 to 100 C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

  12. Removal of arsenic, vanadium, and/or nickel compounds from petroliferous liquids

    DOE Patents [OSTI]

    Fish, R.H.

    1985-05-17T23:59:59.000Z

    Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids (shale oil, SRC, etc.) by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20/sup 0/ to 100/sup 0/C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

  13. Asphalt deposition in miscible floods

    E-Print Network [OSTI]

    Hasan, Syed Mir Ahmed

    1964-01-01T23:59:59.000Z

    : Petroleum Engineering ASPHALT DEPOSITION IN MISCIBLE FLOODS A Thesis By SYED MIR AHMED HASAN Approved as to style and content by: (Chairman of Committee) ommittee Member) Committee Member) Head of Department), (Co 'ttee Member) January, f964... Subject: Petroleum Engineering TABLE OF CONTENTS ABS TRAC T. Page 2. INTRODUCTION. 3 DESCRIPTION OF EQUIPMENT AND MATERIALS. . . . . , . 6 4. EXPERIMENTAL PROCEDURE 5. INTERPRETATION AND DISCUSSION OF RESULTS. . . . . . 13 6. CONCLUSIONS. 7...

  14. Methods for recovering a solvent from a fluid volume and methods of removing at least one compound from a nonpolar solvent

    SciTech Connect (OSTI)

    Ginosar, Daniel M.; Wendt, Daniel S.; Petkovic, Lucia M.

    2014-06-10T23:59:59.000Z

    A method of removing a nonpolar solvent from a fluid volume that includes at least one nonpolar compound, such as a fat, an oil or a triglyceride, is provided. The method comprises contacting a fluid volume with an expanding gas to expand the nonpolar solvent and form a gas-expanded solvent. The gas-expanded solvent may have a substantially reduced density in comparison to the at least one nonpolar compound and/or a substantially reduced capacity to solubilize the nonpolar compound, causing the nonpolar compounds to separate from the gas-expanded nonpolar solvent into a separate liquid phase. The liquid phase including the at least one nonpolar compound may be separated from the gas-expanded solvent using conventional techniques. After separation of the liquid phase, at least one of the temperature and pressure may be reduced to separate the nonpolar solvent from the expanding gas such that the nonpolar solvent may be recovered and reused.

  15. Winter Performance and Maintenance of Porous Asphalt Pavements

    E-Print Network [OSTI]

    Concrete (HSG-B)Porous Asphalt (HSG-C) #12;Cold Climate Performance Results #12;12 Porous Asphalt SurfaceWinter Performance and Maintenance of Porous Asphalt Pavements Robert M. Roseen, Ph.D., P.E., D impacts for new development and reverse impacts in areas with redevelopment. #12;Porous Asphalt Design

  16. Compatibilizer for crumb rubber modified asphalt

    SciTech Connect (OSTI)

    Labib, M.E. [New Jersey Institute of Technology, Newark, NJ (United States); Memon, G.M.; Chollar, B.H. [Federal Highway Administration, McLean, VA (United States)

    1996-12-31T23:59:59.000Z

    The United States of America discards more than 300 million tires each year, and out of that a large fraction of the tires is dumped into stock piles. This large quantity of tires creates an environmental problem. The use of scrap tires is limited. There is a usage potential in such fields as fuel for combustion and Crumb Rubber-Modified Asphalt binder (CRMA). The use of crumb rubber in modifying asphalt is not a new technique; it is been used since early 1960 by pavement engineers. Crumb rubber is a composite of different blends of natural and synthetic rubber (natural rubber, processing oils, polybutadiene, polystyrene butadiene, and filler). Prior research had concluded that the performance of crumb rubber modified asphalt is asphalt dependent. In some cases it improves the Theological properties and in some cases it degrades the properties of modified asphalt.

  17. Materials characterization of asphalt and polymer modified asphalt 

    E-Print Network [OSTI]

    Paramasivam, Mohan

    1992-01-01T23:59:59.000Z

    specimen mold made of aluminum ? ? ? ? ? ? ? ? ? ? - 28 5. Strain sweep of Santa Maria AC10/AR4000 at 100 rad/sec --- 33 6. Strain sweep of Conoco AC10 at 10 rad/sec ------------- 34 7. Stress relaxation modulus of AAM grade asphalt at 25'C --- 37 8.... The verification of Cox-Merz rule for Santa Maria AC6/AR2000 at 40'C- 9. The master curve of Santa Maria AC6/Muehlstein LDPE shifted to 25'C showing the errors 10. Master curve (G') of Santa Maria AC6 shifted to 25'C ? ? ? ? ? 43 11. Master curve of Santa...

  18. Materials characterization of asphalt and polymer modified asphalt

    E-Print Network [OSTI]

    Paramasivam, Mohan

    1992-01-01T23:59:59.000Z

    specimen mold made of aluminum ? ? ? ? ? ? ? ? ? ? - 28 5. Strain sweep of Santa Maria AC10/AR4000 at 100 rad/sec --- 33 6. Strain sweep of Conoco AC10 at 10 rad/sec ------------- 34 7. Stress relaxation modulus of AAM grade asphalt at 25'C --- 37 8.... The verification of Cox-Merz rule for Santa Maria AC6/AR2000 at 40'C- 9. The master curve of Santa Maria AC6/Muehlstein LDPE shifted to 25'C showing the errors 10. Master curve (G') of Santa Maria AC6 shifted to 25'C ? ? ? ? ? 43 11. Master curve of Santa...

  19. Rapid determination of actinides in asphalt samples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maxwell, Sherrod L.; Culligan, Brian K.; Hutchison, Jay B.

    2014-01-12T23:59:59.000Z

    A new rapid method for the determination of actinides in asphalt samples has been developed that can be used in emergency response situations or for routine analysis If a radiological dispersive device (RDD), Improvised Nuclear Device (IND) or a nuclear accident such as the accident at the Fukushima Nuclear Power Plant in March, 2011 occurs, there will be an urgent need for rapid analyses of many different environmental matrices, including asphalt materials, to support dose mitigation and environmental clean up. The new method for the determination of actinides in asphalt utilizes a rapid furnace step to destroy bitumen and organicsmore »present in the asphalt and sodium hydroxide fusion to digest the remaining sample. Sample preconcentration steps are used to collect the actinides and a new stacked TRU Resin + DGA Resin column method is employed to separate the actinide isotopes in the asphalt samples. The TRU Resin plus DGA Resin separation approach, which allows sequential separation of plutonium, uranium, americium and curium isotopes in asphalt samples, can be applied to soil samples as well.« less

  20. Rapid determination of actinides in asphalt samples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maxwell, Sherrod L.; Culligan, Brian K.; Hutchison, Jay B.

    2014-01-12T23:59:59.000Z

    A new rapid method for the determination of actinides in asphalt samples has been developed that can be used in emergency response situations or for routine analysis If a radiological dispersive device (RDD), Improvised Nuclear Device (IND) or a nuclear accident such as the accident at the Fukushima Nuclear Power Plant in March, 2011 occurs, there will be an urgent need for rapid analyses of many different environmental matrices, including asphalt materials, to support dose mitigation and environmental clean up. The new method for the determination of actinides in asphalt utilizes a rapid furnace step to destroy bitumen and organics present in the asphalt and sodium hydroxide fusion to digest the remaining sample. Sample preconcentration steps are used to collect the actinides and a new stacked TRU Resin + DGA Resin column method is employed to separate the actinide isotopes in the asphalt samples. The TRU Resin plus DGA Resin separation approach, which allows sequential separation of plutonium, uranium, americium and curium isotopes in asphalt samples, can be applied to soil samples as well.

  1. TECHNICAL POLLUTION PREVENTION GUIDE FOR ASPHALT PREPARATION OPERATIONS

    E-Print Network [OSTI]

    Delivery, Storage and Cold Feed . . . . . . . . . . . . . 12 2.3.2 Liquid Asphalt Delivery, Storage . . . . . . . . . . . . . . . . . . . . . . 4 2 INDUSTRY PROFILE . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 2.1 ASPHALT and Heating . . . . . . . . . . . . 12 2.3.3 Cold Feed Drying and Heating

  2. An investigation of the use of tire rubber in asphalt

    E-Print Network [OSTI]

    Koo, Heamo Lee

    1996-01-01T23:59:59.000Z

    -rubber binder. The selected variables chosen are curing time, curing temperature, rubber content (weight percent), rubber particle size, base asphalt type, and carbonyl area. Results confirmed that the addition of rubber increased the viscosity of the asphalt...

  3. asphalt composition aplicacao: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Warm mix asphalt (WMA) is not a hot mix asphalt (HMA), it's just warm mix The WMA production temperature typically ranges from 100 to 140o C, whereas for HMA it ranges Das,...

  4. Moisture Diffusion in Asphalt Binders and Fine Aggregate Mixtures

    E-Print Network [OSTI]

    Vasconcelos, Kamilla L.

    2011-08-08T23:59:59.000Z

    cost in highway maintenance and vehicle operations. One key mechanism of how moisture reaches the asphalt-aggregate interface is by its permeation or diffusion through the asphalt binder or mastic. Different techniques are available for diffusion...

  5. Controlling Thermal Properties of Asphalt Concrete and its Multifunctional Applications 

    E-Print Network [OSTI]

    Shi, Xijun

    2014-08-10T23:59:59.000Z

    ) by controlling thermal properties of the construction materials. To change thermal properties of asphalt concrete, expanded polypropylene (EPP) pellet and graphite were selected as the additives and mixed into asphalt concrete. Experimental tests are classified...

  6. Damage analysis in asphalt concrete mixtures based on parameter relationships 

    E-Print Network [OSTI]

    Song, Injun

    2004-11-15T23:59:59.000Z

    Asphalt pavements experience damage due to traffic loading under various environmental conditions. Damage can be caused by viscopl microcracks, fracture due to fatigue cracking, or fracture due to thermal cracking. Asphalt ...

  7. Evaluation of Rexene polymers in hot mixed asphalt concrete 

    E-Print Network [OSTI]

    Rodriguez, Mary Anne Reese

    1991-01-01T23:59:59.000Z

    Committee: Dr. Dallas N. Little The objective of this research was to provide a comprehensive characterization of asphalt binders and paving mixtures modified with four polymers produced by the Rexene Products Company (Odessa, Texas). The four polymers... LITERATURE REVIEW AND INTERPRETATION General Available Asphalt Additives Practical Application of Asphalt Additives Benefit-Costs for Additives Future Outlook for Additives MATERIALS AND TEST METHODS Polymers Asphalt Cements Aggregate Procedure...

  8. Disk-shaped Compact Tension Test for Asphalt Concrete Fracture

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Disk-shaped Compact Tension Test for Asphalt Concrete Fracture by M.P.Wagoner, W.G. Buttlar and G geometry is the ability to test cylindrical cores obtained from in-place asphalt concrete pavements finalizing the specimen geometry, a typical asphalt concrete surface mixture was tested at various

  9. Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded ­ Verification ­ Concluding Remarks Part ­ II (Companion presentation) ­ Asphalt Pavements ­ Effect of Aging: Asphalt concrete pavements (Part II) E1 E2 E3 Eh 1 2 3 h #12;Graded Finite Elements Graded Elements

  10. What's the future for rubberized asphalt

    SciTech Connect (OSTI)

    Not Available

    1991-04-01T23:59:59.000Z

    This article describes the debate over the use of rubberized asphalt for highway surfacing. The Department of Transportation claims that the process is too costly; that it presents potential air pollution, safety and health problems. They also claim that there is a lack of understanding between rubber and asphalt cement and of the recyclability of the product. The Legislative Commission on Solid Waste Management claims that the mixture performs as well or better than conventional asphalt at reduced thicknesses. In addition, there could be savings of local funds currently expended for regulation of tire dumps, fire-fighting and clean-up, vector control and scrap tire disposal costs ranging from $.50 to $2.00 per tire.

  11. The potential use of tar sand bitumen as paving asphalt

    SciTech Connect (OSTI)

    Petersen, J.C.

    1988-01-01T23:59:59.000Z

    In this paper several research reports describing the preparation of potential paving asphalts from tar sand bitumen are reviewed and the results of the studies compared. The tar sand asphalts described in the studies were prepared from 1) hot water-recovered bitumen from deposits near San Luis Obispo, California (Edna deposits), and deposits near Vernal and Sunnyside, Utah; and 2) bitumen recovered from the Northwest Asphalt Ridge deposits near Vernal, Utah, by both in situ steamflood and in situ combustion recovery processes. Important properties of the tar sand asphalts compare favorably with those of specification petroleum asphalts. Laboratory data suggest that some tar sand asphalts may have superior aging characteristics and produce more water-resistant paving mixtures than typical petroleum asphalts.

  12. The potential use of tar sand bitumen as paving asphalt

    SciTech Connect (OSTI)

    Petersen, J.C.

    1987-01-01T23:59:59.000Z

    The properties of several tar sand asphalts prepared in past studies by several different investigators were compared with each other and with the properties of petroleum asphalts. These results were reviewed and discussed with regard to the potential use of tar sand bitumen in pavement applications. The data show that tar sand bitumen has good potential for use in highway pavements that meet today's performance specifications. No deficiencies in the tar sand asphalts were found that would be expected to seriously affect performance. On the other hand, the data indicate that some tar sand asphalts may have superior aging characteristics, being relatively resistant to oxidative age hardening compared with typical petroleum asphalts. Asphalt-aggregate mixtures prepared using two tar sand asphalts also showed acceptable strength properties and excellent resistance to moisture-induced damage.

  13. Evaluation of polyethylene-modified asphalt blends

    E-Print Network [OSTI]

    Consuegra Granger, Fernando

    1990-01-01T23:59:59.000Z

    aggregate and asphalt modified with LDPE (binder contents of 4. 8%%u and 5. 87'). 42 Table 9. Summary of statistical parameters derived from IDT testing on crushed granite mixtures bound with AC-20 + LDPE (4. 8%, and 5. 8/ binder). 46 Table 10. Summary... of creep to rupture data for crushed granite mixtures. 71 Table 11. Summary of the results of IDT repeated load fatigue testing of river gravel mixtures bound with Texaco asphalt: AC- 10, AC-10 + LDPE and AC-20. Table 12. K, ' and n, values of river...

  14. Bibliography of work on the heterogeneous photocatalytic removal of hazardous compounds from water and air, Update Number 2 to October 1996

    SciTech Connect (OSTI)

    Blake, D.M.

    1997-01-01T23:59:59.000Z

    The Solar Industrial Program has developed processes that destroy hazardous substances in or remove them from water and air. The processes of interest in this report are based on the application of heterogeneous photocatalysts, principally titanium dioxide or modifications thereof, but work on other heterogeneous catalysts is included in this compilation. This report continues bibliographies that were published in May, 1994, and October, 1995. The previous reports included 663 and 574 citations, respectively. This update contains an additional 518 references. These were published during the period from June 1995 to October 1996, or are references from prior years that were not included in the previous reports. The work generally focuses on removing hazardous contaminants from air or water to meet environmental or health regulations. This report also references work on properties of semiconductor photocatalysts and applications of photocatalytic chemistry in organic synthesis. This report follows the same organization as the previous publications. The first part provides citations for work done in a few broad categories that are generic to the process. Three tables provide references to work on specific substances. The first table lists organic compounds that are included in various lists of hazardous substances identified by the US Environmental Protection Agency (EPA). The second table lists compounds not included in those categories, but which have been treated in a photocatalytic process. The third table covers inorganic compounds that are on EPA lists of hazardous materials or that have been treated by a photocatalytic process. A short update on companies that are active in providing products or services based on photocatalytic processes is provided.

  15. The effect of asphalt deposition on recovery of oil by a pentane slug

    E-Print Network [OSTI]

    Bhagia, Nanik S

    1965-01-01T23:59:59.000Z

    ":ty reduction increases, in general, with the increase in amount of, asphalt contained ir the oil. The increases in recovery at breakthrough due to asphalt deposition were noted for four asphaltic crude oils and were compared to those of asphalt-free refined... substantial range, the gain in recovery at breakthrough of asphaltic oils over refined oils of the same viscosity increases with increase in size of slug used. This is attributed to more favorable mobility ratios resulting from asphalt deposition during...

  16. Asphalt Pavement Aging and TemperatureAsphalt Pavement Aging and Temperature Dependent Properties using a FunctionallyDependent Properties using a Functionally

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Asphalt Pavement Aging and TemperatureAsphalt Pavement Aging and Temperature Dependent Properties Analysis Time Integration Analysis Application Examples: Asphalt Pavement Summary and Conclusions #12) ­ Large fraction produced as hot-mix asphalt (HMA) ­ Most common form of pavement surfacing material (96

  17. Investigation of Noise and Durability Performance Trends for Asphaltic Pavement Surface Types: Three-Year Results

    E-Print Network [OSTI]

    Lu, Qing; Kohler, Erwin R.; Harvey, John T; Ongel, Aybike

    2009-01-01T23:59:59.000Z

    Trends for Asphalt Pavement Surface Types: First- andResults. University of California Pavement Research Center,Trends for Asphaltic Pavement Surface Types: First- and

  18. A novel technique for the production of cool colored concrete tile and asphalt shingle roofing products

    E-Print Network [OSTI]

    Levinson, Ronnen

    2010-01-01T23:59:59.000Z

    for providing concrete tiles, and Lou Hahn of GAF-Elk forof cool colored concrete tile and asphalt shingle roofingsolar-reflective nonwhite concrete tile and asphalt shingle

  19. Predicting the fatigue life of asphalt concrete overlay systems

    E-Print Network [OSTI]

    Germann, Frederick P

    1979-01-01T23:59:59.000Z

    ON CRACK GROWTH IN VISCOELASTIC MATERIALS C'HAPTER V - STATE OF THE ART Effect of Mix Variables on Fatigue and Cracking Resistance in Asphalt Concrete Pavements . Field Performance of Asphalt Overlays with Fabric Summary CHAPTER VI ? MATERIALS... LIFE OF AN ASPHALT OVERLAY CHAPTER X - CONCLUSIONS AND RECOMMENDATIONS REFERENCES APPENDIX A. CRACK TIP STRESS ANALYSIS APPENDIX B. CONSTRUCTION OF THE MASTER RESILIENT MODULUS AND MASTER CREEP COMPLIANCE CURVES APPENDIX C. CRACK GROWTH RATES, da...

  20. Microstructural Characterization of Material Properties and Damage in Asphalt Composites

    E-Print Network [OSTI]

    Mohammad Khorasani, Sara

    2013-05-03T23:59:59.000Z

    MICROSTRUCTURAL CHARACTERIZATION OF MATERIAL PROPERTIES AND DAMAGE IN ASPHALT COMPOSITES A Thesis by SARA MOHAMMAD KHORASANI Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... Engineering Copyright 2013 Sara Mohammad Khorasani ii ABSTRACT Asphalt composites are used to construct 90% of roads in the United States. These composites consist of asphalt binder, which is a product of the refinery process of oil, aggregates...

  1. asphalt technology test: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and evaluated its performance when used in split mastic asphalt (SMA) mixture using Marshall Characteristic and dynamic charateristics (resilient modulus). As many as 90...

  2. anionic emulsified asphalt: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Volucm Change... Gandhi, Poduru Mohandas Karamchand 1966-01-01 15 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization Websites...

  3. asphalt rock: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Corrections to Volucm Change... Gandhi, Poduru Mohandas Karamchand 1966-01-01 17 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  4. asphaltic sand: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Corrections to Volucm Change... Gandhi, Poduru Mohandas Karamchand 1966-01-01 19 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  5. asphalt concrete overlays: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    experimental results for concrete containing virgin limestone Paulino, Glaucio H. 71 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  6. asphalt overlay design: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    these overlay networks. Routing and search in these overlay ... Cheng, Bow-Nan 69 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  7. asphalt binder extraction: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Corrections to Volucm Change... Gandhi, Poduru Mohandas Karamchand 1966-01-01 43 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  8. Full-Depth Pavement Reclamation with Foamed Asphalt: Final Report

    E-Print Network [OSTI]

    Jones, David; Fu, P.; Harvey, John T; Halles, F.

    2008-01-01T23:59:59.000Z

    University of California Pavement Research Center. (WP-2005-8 th Conference on Asphalt Pavements for Southern Africa (International Journal of Pavement Engineering, Vol 8, No

  9. asphalt concrete bases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    large amounts of PS wastes in civil engineering constructions. Key words: Asphalt surfaces Disposable dishes Polystyrene (PS) Wastes Environment A. Akbari Motlagh; A....

  10. asphalt concrete soil: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    large amounts of PS wastes in civil engineering constructions. Key words: Asphalt surfaces Disposable dishes Polystyrene (PS) Wastes Environment A. Akbari Motlagh; A....

  11. Compositional evaluation of asphalt binder recycling agents

    E-Print Network [OSTI]

    Madrid, Richard Charles

    1997-01-01T23:59:59.000Z

    from: Exxon Research and Engineering Company, The National Consortium for Graduate Degrees for Minorities in Engineering and Science, Inc. Fellowship (GEM), and the DOW Technical Fellowship is greatly appreciated. I thank Sophie and Ignacio Madrid... for Recycled Blends . . . . . Asphaltic Materials. . 54 58 63 69 V-2 V-3 V-4 V-5 V-6 V-7 Fina DMO and Exxon Tank Compositions and Viscosities. . . . Blend Compositions and Viscosities...

  12. Rheological Investigation of the Influence of Acrylate Polymers on the Modification of Asphalt

    E-Print Network [OSTI]

    Hussein, Ibnelwaleed A.

    and superior ACM properties when blended with the high asphaltenes Arabian asphalt. © 2006 Wiley Periodicals

  13. Recycled rubber, aggregate, and filler in asphalt paving mixtures. Transportation research record

    SciTech Connect (OSTI)

    NONE

    1996-12-31T23:59:59.000Z

    ;Contents(Partial): Evaluation Systems for Crumb Rubber Modified Binders and Mixtures; Hot Mix Asphalt Rubber Applications in Virginia; Evaluation of Pyrolized Carbon Black from Scrap Tires as Additive in Hot Mix Asphalt; Use of Scrap Tire Chips in Asphaltic Membrane; Effects of Mineral Fillers on Properties of Stone Matrix Asphalt Mixtures; and Quantitative Analysis of Aggregate Based on Hough Transform.

  14. Field Manual for Crack Sealing in Asphalt Pavements

    E-Print Network [OSTI]

    Texas at Austin, University of

    Field Manual for Crack Sealing in Asphalt Pavements Yetkin Yildirim, Ahmed Qatan, and Jorge Prozzi January 2006 3208RedRiver Austin,TX78705 #12;Dr. Yetkin Yildirim, P.E. Director Texas Pavement for Crack Sealing in Asphalt Pavements #12;Performing Organization: Center for Transportation Research

  15. Recycling asphalt overview of more than 25 years of use

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Recycling asphalt overview of more than 25 years of use in France Y. Brosseaud ­ LCPC hal with ring for recycling ­ Average rate with high proportion : 30 to 50% ­ Used of rejuvenators (soft oil,version1-20May2011 #12;4 Hot recycling asphalt on mixing plant Recycling in place in hot or cold

  16. Relationship Between Surface Free Energy and Total Work of Fracture of Asphalt Binder and Asphalt Binder-Aggregate Interfaces 

    E-Print Network [OSTI]

    Howson, Jonathan Embrey

    2012-10-19T23:59:59.000Z

    is the surface free energy of the asphalt binder and the aggregate. Surface free energy, which is a thermodynamic material property, is directly related to the adhesive bond energy between the asphalt binder and the aggregate as well as the cohesive bond energy...

  17. Relationship Between Surface Free Energy and Total Work of Fracture of Asphalt Binder and Asphalt Binder-Aggregate Interfaces

    E-Print Network [OSTI]

    Howson, Jonathan Embrey

    2012-10-19T23:59:59.000Z

    is the surface free energy of the asphalt binder and the aggregate. Surface free energy, which is a thermodynamic material property, is directly related to the adhesive bond energy between the asphalt binder and the aggregate as well as the cohesive bond energy...

  18. Excess Foundry Sand Characterization and Experimental Investigation in Controlled Low-Strength Material and Hot-Mixing Asphalt

    SciTech Connect (OSTI)

    Paul J. Tikalsky, Hussain U. Bahia, An Deng and Thomas Snyder

    2004-10-15T23:59:59.000Z

    This report provides technical data regarding the reuse of excess foundry sand. The report addresses three topics: a statistically sound evaluation of the characterization of foundry sand, a laboratory investigation to qualify excess foundry sand as a major component in controlled low-strength material (CLSM), and the identification of the best methods for using foundry sand as a replacement for natural aggregates for construction purposes, specifically in asphalt paving materials. The survival analysis statistical technique was used to characterize foundry sand over a full spectrum of general chemical parameters, metallic elements, and organic compounds regarding bulk analysis and leachate characterization. Not limited to characterization and environmental impact, foundry sand was evaluated by factor analyses, which contributes to proper selection of factor and maximization of the reuse marketplace for foundry sand. Regarding the integration of foundry sand into CLSM, excavatable CLSM and structural CLSM containing different types of excess foundry sands were investigated through laboratory experiments. Foundry sand was approved to constitute a major component in CLSM. Regarding the integration of foundry sand into asphalt paving materials, the optimum asphalt content was determined for each mixture, as well as the bulk density, maximum density, asphalt absorption, and air voids at Nini, Ndes, and Nmax. It was found that foundry sands can be used as an aggregate in hot-mix asphalt production, but each sand should be evaluated individually. Foundry sands tend to lower the strength of mixtures and also may make them more susceptible to moisture damage. Finally, traditional anti-stripping additives may decrease the moisture sensitivity of a mixture containing foundry sand, but not to the level allowed by most highway agencies.

  19. Excess Foundry Sand Characterization and Experimental Investigation in Controlled Low-Strength Material and Hot-Mixing Asphalt

    SciTech Connect (OSTI)

    Pauul J. Tikalsky

    2004-10-31T23:59:59.000Z

    This report provides technical data regarding the reuse of excess foundry sand. The report addresses three topics: (1) a statistically sound evaluation of the characterization of foundry sand, (2) a laboratory investigation to qualify excess foundry sand as a major component in controlled low-strength material (CLSM), and (3) the identification of the best methods for using foundry sand as a replacement for natural aggregates for construction purposes, specifically in asphalt paving materials. The survival analysis statistical technique was used to characterize foundry sand over a full spectrum of general chemical parameters, metallic elements, and organic compounds regarding bulk analysis and leachate characterization. Not limited to characterization and environmental impact, foundry sand was evaluated by factor analyses, which contributes to proper selection of factor and maximization of the reuse marketplace for foundry sand. Regarding the integration of foundry sand into CLSM, excavatable CLSM and structural CLSM containing different types of excess foundry sands were investigated through laboratory experiments. Foundry sand was approved to constitute a major component in CLSM. Regarding the integration of foundry sand into asphalt paving materials, the optimum asphalt content was determined for each mixture, as well as the bulk density, maximum density, asphalt absorption, and air voids at N{sub ini}, N{sub des}, and N{sub max}. It was found that foundry sands can be used as an aggregate in hot-mix asphalt production, but each sand should be evaluated individually. Foundry sands tend to lower the strength of mixtures and also may make them more susceptible to moisture damage. Finally, traditional anti-stripping additives may decrease the moisture sensitivity of a mixture containing foundry sand, but not to the level allowed by most highway agencies.

  20. Improvements to a Transport Model of Asphalt Binder Oxidation in Pavements: Pavement Temperature Modeling, Oxygen Diffusivity in Asphalt Binders and Mastics, and Pavement Air Void Characterization

    E-Print Network [OSTI]

    Han, Rongbin

    2012-07-16T23:59:59.000Z

    Although evidence is mounting that asphalt binder oxidizes in pavements, and that oxidation and subsequent hardening of asphalt binder has a profound effect on pavement durability, important implementation issues remain to be better understood...

  1. Nutrient Removal Mechanisms in a Cold Climate Gravel Wetland

    E-Print Network [OSTI]

    Nutrient Removal Mechanisms in a Cold Climate Gravel Wetland Alison Watts, Robert Roseen, Kim Farah and development of stormwater treatment systems Gregg Hall 35 Colovos Road Durham, New Hampshire 03824-3534 603.862.4024 http://www.unhsc.unh.edu #12;POROUS ASPHALT Watershed Boundary #12;#12;Gravel Wetland Effluent sampling

  2. Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded Viscoelastic Model, Part-II: Applications

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded simulation of functionally graded viscoelastic properties in asphalt concrete pavements. The techniques properties. A full-depth asphalt concrete pavement has been simulated to demonstrate the applicability

  3. Removing Stains from Washable Fabrics.

    E-Print Network [OSTI]

    Beard, Ann Vanderpoorten

    1988-01-01T23:59:59.000Z

    Page Numbers Stain Page Numbers Acne medicine Blueberry Special 9 Wet 8 Adhesive tape Dye 8 Special 9 Butter Alcoholic beverages Dry 8 Wet 8 Oil 8 Tannin 8 Calamine lotion Asphalt Combination 8 Combination 8 Dye 8 Dye 8 Candle wax Automotive... the most gentle to the most harsh, so always stop treatments as soon as the stain has been removed. Dry Type Stains Dissolve the stain with a grease solvent. Lubricate the stain with dry spotter, coconut oil or mineral oil (sold in health food...

  4. The curing of asphalt with rubber and its effect on the physical and chemical properties of asphalt-rubber binders

    E-Print Network [OSTI]

    Chun, Jay Sung

    1995-01-01T23:59:59.000Z

    10% TG-40 and 90% Exxon AC-5. 105 B-1 Molecular Size Distribution of Rubber in Asphalt 5% TG-40 and 95% Fina AC-10. . . 123 B-2 Molecular Size Distribution of Rubber in Asphalt 10% TG-40 and 90% Fina AC-10. . 124 xlv FIGURE B-3 Molecular Size.... 0 Frequency (rad/s) 10. 0 100. 0 Figure III-2: Effect of Frequency on Viscosity Measurements Fina AC-10 Tank Asphalt 2500 2000 0 a 1500 1000 o 0 0 0 0 o o 0 0 0 0 0 0 0 o 0 Fina AC-10 with 5% TG-40 mesh rubber Cured at 375 F and 500...

  5. asphalt emulsions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 21 Life Cycle Assessment of Reclaimed Asphalt Pavement Energy Storage, Conversion and Utilization...

  6. Characterization of Fatigue Cracking and Healing of Asphalt Mixtures

    E-Print Network [OSTI]

    Luo, Xue

    2012-07-16T23:59:59.000Z

    mixtures using an energy-based mechanistic approach. A controlled-strain repeated direct tension (RDT) test is selected to generate both fatigue cracking and permanent deformation in an asphalt mixture specimen. Fatigue cracking is separated from...

  7. Viscoelastic{Viscoplastic Damage Model for Asphalt Concrete

    E-Print Network [OSTI]

    Graham, Michael A.

    2010-10-12T23:59:59.000Z

    This thesis presents a continuum model for asphalt concrete incorporating non- linear viscoelasticity, viscoplasticity, mechanically-induced damage and moisture- induced damage. The Schapery single-integral viscoelastic model describes the nonlinear...

  8. A thermodynamic approach for compaction of asphaltic composites

    E-Print Network [OSTI]

    Koneru, Saradhi

    2009-05-15T23:59:59.000Z

    and Focus of Current Work . . . . . . . . . . . . . . 2 B. Outline of the Thesis . . . . . . . . . . . . . . . . . . . . . 3 C. Notations Used . . . . . . . . . . . . . . . . . . . . . . . . 4 II LITERATURE REVIEW... . . . . . . . . . . . . . . . . 8 b. Asphalt Binder . . . . . . . . . . . . . . . . . . . 8 C. Compaction Equipment . . . . . . . . . . . . . . . . . . . . 9 1. Field Compaction Equipment . . . . . . . . . . . . . . 9 a. Static Steel Wheel Rollers . . . . . . . . . . . . . 9 b...

  9. asphaltic pavements microsurfacing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    service have been... Lau, Chee Keung 1991-01-01 14 A utility evaluation of nondestructive testing devices used on asphalt concrete pavements Texas A&M University - TxSpace...

  10. asphalt pavement cracking: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    service have been... Lau, Chee Keung 1991-01-01 16 A utility evaluation of nondestructive testing devices used on asphalt concrete pavements Texas A&M University - TxSpace...

  11. asphalt concrete pavement: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    this thesis. It included the following tasks: investigation of a testing and grading system for grading asphalt binder residues... Hoyt, Denise 2012-07-16 8 Full-Depth Pavement...

  12. asphalt pavement rap: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    service have been... Lau, Chee Keung 1991-01-01 14 A utility evaluation of nondestructive testing devices used on asphalt concrete pavements Texas A&M University - TxSpace...

  13. asphaltic concrete pavement: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    this thesis. It included the following tasks: investigation of a testing and grading system for grading asphalt binder residues... Hoyt, Denise 2012-07-16 8 Full-Depth Pavement...

  14. asphalt concrete pavements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    this thesis. It included the following tasks: investigation of a testing and grading system for grading asphalt binder residues... Hoyt, Denise 2012-07-16 8 Full-Depth Pavement...

  15. asphaltic concrete pavements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    this thesis. It included the following tasks: investigation of a testing and grading system for grading asphalt binder residues... Hoyt, Denise 2012-07-16 8 Full-Depth Pavement...

  16. asphalt pavements: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    service have been... Lau, Chee Keung 1991-01-01 14 A utility evaluation of nondestructive testing devices used on asphalt concrete pavements Texas A&M University - TxSpace...

  17. Measurements of moisture suction in hot mix asphalt mixes 

    E-Print Network [OSTI]

    Kassem, Emad Abdel-Rahman

    2006-10-30T23:59:59.000Z

    with different bond energies and exhibited different field performance in terms of resistance to moisture damage. The suction measurements in sand asphalt specimens were used to calculate the moisture diffusion coefficient. The results revealed that water...

  18. Moisture Diffusion in Asphalt Binders and Fine Aggregate Mixtures 

    E-Print Network [OSTI]

    Vasconcelos, Kamilla L.

    2011-08-08T23:59:59.000Z

    coefficient measurement of a wide variety of polymersolvent systems. For the asphalt-water system studied, the focus is on two techniques: (i) Fourier Transform Infrared (FTIR)-Attenuated Total Reflectance (ATR) spectrometry and (ii) Gravimetric Sorption...

  19. Imparting Electrical Conductivity into Asphalt Composites Using Graphite 

    E-Print Network [OSTI]

    Baranikumar, Aishwarya

    2013-07-09T23:59:59.000Z

    publications showed the potential of graphite in mitigating the sudden transition. The study presented herein investigates possibility of precisely controlling the electrical conductivity of asphalt concrete only by adding filler size graphite powder. Nine...

  20. asphalt concrete performance: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Robert L. 2014-01-01 23 Establishing material properties for thin asphalt concrete surfaces on granular bases Texas A&M University - TxSpace Summary: of MASTER OF SCIENCE...

  1. Study of properties of sand asphalt using a torsional rheometer 

    E-Print Network [OSTI]

    Kasula, Lavan Kumar Reddy

    2004-11-15T23:59:59.000Z

    The modeling of Sand Asphalt and experiments to measure their rheological properties are of vital concern to many industrial processes especially highway and roadway pavement construction industry. A variety of hot mix ...

  2. Use of VFDs on Asphalt Plant Induced Draft Fans

    E-Print Network [OSTI]

    Anderson, G. R.; Case, P. L.; Lowery, J.

    2005-01-01T23:59:59.000Z

    Studies of 10 asphalt plants in the Intermountain Region have identified average ID fan energy savings of 68% by controlling airflow using Variable Frequency Drives (VFDs) on the fan motors in place of damper control (inlet or outlet). Average...

  3. Fiber reinforcement of asphalt concrete using cow manure

    E-Print Network [OSTI]

    Bakar, Mohammed Abu

    1976-01-01T23:59:59.000Z

    . Specimens were made according to the Marshall Method of Mixture Design and tested for 1) Marshall Stability 2) Hveem Stability and 3) Hater Susceptibil- ity. Test results indicated that 4. 4 percent cow manure by volume of rhe total aggregate when used... Voids in Mineral Aggregate 11 LIST OF FIGURES Figures Page l. 2 l. 3 1. 4 1. 5 1. 6 Determination of Optimum Asphalt Content by the Marshall Method Determination of Optimum Asphalt Content by the Marshall Method Determination of Optimum...

  4. Characterization of road asphalt using Gel Permeation Chromatography

    E-Print Network [OSTI]

    Donaldson, Guy Randal

    1987-01-01T23:59:59.000Z

    inconsistent and inconsistent. Six were consistent, three were slightly inconsist nt, and three were inconsistent. To study the relationship between GPC and performance, samples from test pavements at three locations were obtained. Both original asphalts... Columns/Toluene/100 Nicroliters/ 7X 3 ' 2. Reproducibility of the Standard Asphalt in THF . ~ . . ~ . ~ . . . 500 and 50 Angstrom Columns/Toluene/100 Nicroliters/ 7X 19 3. 3. Differences in Refractive Index Detector Response. Exxon AC-10/Dumas Tank...

  5. Fatigue Resistance of Asphalt Mixtures Affected by Water Vapor Movement

    E-Print Network [OSTI]

    Tong, Yunwei

    2013-11-08T23:59:59.000Z

    aggregate contact due to dust particles on the aggregate surface. The rupture may occur because of the construction loads and operating traffic during construction, or could be environmentally induced by freeze-thaw cycling. Once a break in the film... design, environment and traffic, can be defined as progressive degradation of asphalt mixture material due to the presence of water. The occurrence of moisture damage in asphalt material is a rather complex phenomenon, which involves chemical, physical...

  6. Downstream Processing of Recombinant Proteins from Transgenic Plant Systems: Phenolic Compounds Removal from Monoclonal Antibody Expressing Lemna minor and Purification of Recombinant Bovine Lysozyme from Sugarcane

    E-Print Network [OSTI]

    Barros, Georgia

    2012-07-16T23:59:59.000Z

    expensive. To avoid monoclonal antibody (mAb) modification or fouling of chromatography resins, removal of phenolics from plant extracts is desirable. Removal of major phenolics in Lemna extracts was evaluated by adsorption to PVPP, XAD-4, IRA-402 and Q...

  7. Investigation of Conditions for Moisture Damage in Asphalt Concrete and Appropriate Laboratory Test Methods

    E-Print Network [OSTI]

    Lu, Qing

    2005-01-01T23:59:59.000Z

    of Asphalt Concrete-Physical Testing. ” Final Report, #930-of Asphalt Concrete: Chemical Testing. ” Alabama Highwayconcrete mixes, it is preferred to use a mix that would have good moisture resistance under laboratory testing

  8. Investigation of Conditions for Moisture Damage in Asphalt Concrete and Appropriate Laboratory Test Methods

    E-Print Network [OSTI]

    Harvey, John T; Lu, Qing

    2005-01-01T23:59:59.000Z

    of Asphalt Concrete-Physical Testing. ” Final Report no.of Asphalt Concrete: Chemical Testing. ” Alabama Highwayconcrete mixes, it is preferable to use a mix that would have good moisture resistance under laboratory testing

  9. A Coupled Micromechanical Model of Moisture-Induced Damage in Asphalt Mixtures: Formulation and Applications 

    E-Print Network [OSTI]

    Caro Spinel, Silvia

    2011-02-22T23:59:59.000Z

    The deleterious effect of moisture on the structural integrity of asphalt mixtures has been recognized as one of the main causes of early deterioration of asphalt pavements. This phenomenon, usually referred to as moisture damage, is defined...

  10. Asphalt compositions containing spurted polyolefin fibers with improved dispersibility in hydrocarbons

    SciTech Connect (OSTI)

    Jabloner, H.

    1987-07-07T23:59:59.000Z

    A cutback asphalt composition is described comprising asphalt and a hydrocarbon solvent. The improvement composition comprises a water-dispersible spurted polyolefin pulp having precipitated a natural rubber or synthetic elastomer that is swellable in hydrocarbon solvents.

  11. E-Print Network 3.0 - asphalt mix design Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Environmental Engineering, Arizona State University Collection: Engineering 35 Bi Oil i A h ltBio-Oil in Asphalt ApplicationsApplications Summary: tons of hot mix asphalt...

  12. Evaluation of the filler effects on fatique cracking and permanent deformation of asphalt concrete mixtures 

    E-Print Network [OSTI]

    Izzo, Richard P

    1997-01-01T23:59:59.000Z

    The addition of hydrated lime to asphalt has shown to be beneficial with an improvement in the Theological properties of the binder, as well as resistance to permanent deformation (rutting) and fatigue cracking of asphalt concrete mixtures...

  13. Evaluation of the filler effects on fatique cracking and permanent deformation of asphalt concrete mixtures

    E-Print Network [OSTI]

    Izzo, Richard P

    1997-01-01T23:59:59.000Z

    The addition of hydrated lime to asphalt has shown to be beneficial with an improvement in the Theological properties of the binder, as well as resistance to permanent deformation (rutting) and fatigue cracking of asphalt concrete mixtures...

  14. Development of asphalts and pavements using recycled tire rubber. Phase 1: technical feasibility. Final report

    SciTech Connect (OSTI)

    Bullin, J.A.; Davison, R.R.; Glover, C.J. [and others

    1998-01-01T23:59:59.000Z

    This report documents the technical progress made on the development of asphalts and pavements using recycled tire rubber.

  15. A study of the mixing viscosity of asphalt in hot-mix production

    E-Print Network [OSTI]

    Khan, Md. Musharraf Hossain

    1961-01-01T23:59:59.000Z

    Gravity and Absorption of Aggregates. 36 Sieve Analysis of Combined Aggregates 37 Centrifuge Kerosene Equivalent Test Data for Estimated Optimum Asphalt Content . 38 Test Data on Molded Specimens for Optimum Asphalt Content 39 XIII . Test Data... there is available to be filled with asphalt. The Centrifuge Kerosene Equivalent (CKE) Test was performed to 11 determine the estimated optimum asphalt content as a percentage of the 10 The American Association of State Highway Officials, "Standard...

  16. A Pilot Study of the Effectiveness of Indoor Plants for Removal of Volatile Organic Compounds in Indoor Air in a Seven-Story Office Building

    SciTech Connect (OSTI)

    Apte, Michael G.; Apte, Joshua S.

    2010-04-27T23:59:59.000Z

    The Paharpur Business Centre and Software Technology Incubator Park (PBC) is a 7 story, 50,400 ft{sup 2} office building located near Nehru Place in New Delhi India. The occupancy of the building at full normal operations is about 500 people. The building management philosophy embodies innovation in energy efficiency while providing full service and a comfortable, safe, healthy environment to the occupants. Provision of excellent Indoor Air Quality (IAQ) is an expressed goal of the facility, and the management has gone to great lengths to achieve it. This is particularly challenging in New Delhi, where ambient urban pollution levels rank among the worst on the planet. The approach to provide good IAQ in the building includes a range of technical elements: air washing and filtration of ventilation intake air from rooftop air handler, the use of an enclosed rooftop greenhouse with a high density of potted plants as a bio-filtration system, dedicated secondary HVAC/air handling units on each floor with re-circulating high efficiency filtration and UVC treatment of the heat exchanger coils, additional potted plants for bio-filtration on each floor, and a final exhaust via the restrooms located at each floor. The conditioned building exhaust air is passed through an energy recovery wheel and chemisorbent cartridge, transferring some heat to the incoming air to increase the HVAC energy efficiency. The management uses 'green' cleaning products exclusively in the building. Flooring is a combination of stone, tile and 'zero VOC' carpeting. Wood trim and finish appears to be primarily of solid sawn materials, with very little evidence of composite wood products. Furniture is likewise in large proportion constructed from solid wood materials. The overall impression is that of a very clean and well-kept facility. Surfaces are polished to a high sheen, probably with wax products. There was an odor of urinal cake in the restrooms. Smoking is not allowed in the building. The plants used in the rooftop greenhouse and on the floors were made up of a number of species selected for the following functions: daytime metabolic carbon dioxide (CO{sub 2}) absorption, nighttime metabolic CO{sub 2} absorption, and volatile organic compound (VOC) and inorganic gas absorption/removal for air cleaning. The building contains a reported 910 indoor plants. Daytime metabolic species reported by the PBC include Areca Palm, Oxycardium, Rubber Plant, and Ficus alii totaling 188 plants (21%). The single nighttime metabolic species is the Sansevieria with a total of 28 plants (3%). The 'air cleaning' plant species reported by the PBC include the Money Plant, Aglaonema, Dracaena Warneckii, Bamboo Palm, and Raphis Palm with a total of 694 plants (76%). The plants in the greenhouse (Areca Palm, Rubber Plant, Ficus alii, Bamboo Palm, and Raphis Palm) numbering 161 (18%) of those in the building are grown hydroponically, with the room air blown by fan across the plant root zones. The plants on the building floors are grown in pots and are located on floors 1-6. We conducted a one-day monitoring session in the PBC on January 1, 2010. The date of the study was based on availability of the measurement equipment that the researchers had shipped from Lawrence Berkeley National Lab in the U.S.A. The study date was not optimal because a large proportion of the regular building occupants were not present being New Year's Day. An estimated 40 people were present in the building all day during January 1. This being said, the building systems were in normal operations, including the air handlers and other HVAC components. The study was focused primarily on measurements in the Greenhouse and 3rd and 5th floor environments as well as rooftop outdoors. Measurements included a set of volatile organic compounds (VOCs) and aldehydes, with a more limited set of observations of indoor and outdoor particulate and carbon dioxide concentrations. Continuous measurements of Temperature (T) and relative humidity (RH) were made selected indoor and outdoor locations.

  17. Recycling of plastic and rubber tire waste in asphalt pavements

    SciTech Connect (OSTI)

    Morrison, G.R.; Lee, N.K.; Hesp, S.A.M. [Queen`s Univ., Kingston, Ontario (Canada). Dept. of Chemistry

    1994-12-31T23:59:59.000Z

    This paper discusses some important issues related to the use of recycled thermoplastics and rubber tire waste in asphalt binders for hot-mix pavements. Both high temperature rheological and low temperature fracture studies are presented on recycled polyethylene, devulcanized and crumb rubber-modified asphalt binders. The results are compared to unmodified and commercially available modified binders. This research is especially timely in light of the US Intermodal Surface Transportation Efficiency Act of 1991, Section 1038 which, starting in 1995, will force state and local governments to use significant amounts of recycled rubber tire or plastic waste in federally funded highway projects. High temperature rheological measurements of the loss modulus, loss tangent and complex modulus show a significant improvement when only small quantities of crumb rubber, devulcanized crumb rubber or waste polyethylene are added to the asphalt binders. The low temperature fracture performance of the modified asphalts is greatly influenced by the interfacial strength between the dispersed and continuous phase. The fracture toughness increases dramatically, only when low molecular weight polymers are grafted in-situ onto the rubber and polymer dispersed phases in order to strength the interface. This points to a crack-pinning mechanism as being responsible for the dramatic increase in fracture toughness that is observed in this work. Single phase, devulcanized crumb rubber-asphalt systems perform quite poorly at low temperatures.

  18. Use of recycled chunk rubber asphalt concrete (CRAC) on low volume roads and use of recycled crumb rubber modifier in asphalt pavements. Final report, June 1993-June 1995

    SciTech Connect (OSTI)

    Hossain, M.; Funk, L.P.; Sadeq, M.A.; Marucci, G.

    1995-06-01T23:59:59.000Z

    The major objective of this project was to formulate a Chunk Rubber Asphalt Concrete (CRAC) mix for use on low volume roads. CRAC is a rubber modified asphalt concrete product produced by the `dry process` where rubber chunks of 1/2 inch size are used as aggregate in a cold mix with a type C fly ash. The second objective of this project was to develop guidelines concerning the use of rubber modified asphalt concrete hot mix to include: (1) Design methods for use of asphalt-rubber mix for new construction and overlay, (2) Mix design method for asphalt-rubber, and (3) Test method for determining the amount of rubber in an asphalt-rubber concrete for quality control purposes.

  19. Effect of pyrolyzed carbon black on asphalt cement. Part 2. Asphalt binder. Final report, September 1993-May 1995

    SciTech Connect (OSTI)

    Zeng, Y.; Lovell, C.W.

    1996-02-20T23:59:59.000Z

    Scrap tires derived from automobiles have become a large environmental problem in the United States. In the study, research is carried out to investigate the potential use of tire-derived pyrolyzed carbon black from scrap tires as an asphalt cement modifier. The asphlat cements used in the research were AC10 and AC20. Penetration and softening point tests were performed to obtain the consistency of the asphalt cements. The pyrolyzed carbon black, as provided by Wolf Industries, was combined with the asphalt cement in the following percentages: 5%, 10%, 15% and 20%. Penetration, softening point and ductility tests were performed to determine the temperature susceptibility of the modified binder as altered by the pyrolyzed carbon black. In order that the results are comparable to previous testing, commercial carbon black purchased from CABOT Industry was also used as a modifier in the tests. The same test procedures were applied to the asphalt cements modified by commercial carbon black. The test results contained in the report illustrate the viability of the pyrolyzed carbon black as an asphalt modifier. Recommendations are provided to facilitate further research on this particular project. A preliminary assessment of a test road using the pyrolyzed carbon is appended.

  20. A study of the effects of limestone rock asphalt screenings on the structural properties of hot-mix asphaltic concrete made with siliceous materials 

    E-Print Network [OSTI]

    Albritton, Oscar Willard

    1958-01-01T23:59:59.000Z

    LiSRagy pptt8pp py IEXAa A STUDY OF THE EFFECTS OF LIMESTONE ROCK ASPHALT SCREENINGS ON THE STRUCTURAL PROPERTIES OF HOT-MIX ASPHALTIC CONCRETE MADE WITH SILICEOUS MATERIALS A Thesis By OSCAR WILLARD. AQBRITTON Submitted to the Graduate... ON THE STRUCTURAL PROPERTIES OF HOT-MIX ASPHALTIC CONCRETE MADE WITH SILICEOUS MATERIALS A Thesis By OSCAR WILLARD ALBRITTON Approved as to Style and Content by: Chairman of Committee ead of Departme t August 1958 ACKNOWLEDGMENTS Acknowledgment is due...

  1. Recycling asphaltic concrete with sulphur as a supplemental binder

    E-Print Network [OSTI]

    Barnett, Robert William

    1976-01-01T23:59:59.000Z

    in the United States, and the use of this secondary sulphur for construction purposes could provide not only a vast savings of natural resources and reusable materials but also aid industry in recovering the cost of environ- mental protection. The waste... industry [25, 26, 27, 28]. Research has been undertaken to investigate the use of sulphur in sand-asphalt- sulphur pavement mixes [11, 25, 29, 30]. The use of sulphur in sulphur-asphalt emulsions to serve as a binder has also been studied [26, 31, 32...

  2. Asphalt roofing industry Fourier transform infrared spectroscopy modified bitumen

    SciTech Connect (OSTI)

    NONE

    1999-07-01T23:59:59.000Z

    A Request for Emissions Testing at Four Asphalt Roofing and Processing Facilities was submitted by the US EPA Emission Standards Division (ESD), Minerals and Inorganic Chemicals Group (MICG) to the Emission Measurement Center (EMC). The Emission Measurement Center directed Midwest Research Institute (MRI) to conduct emissions testing at asphalt roofing plants. This report presents results of MRI`s FTIR and Method 25A testing conducted at US Intec in Port Arthur, Texas. The field measurements were performed in September 1997 under several test conditions for both controlled and uncontrolled emissions.

  3. Automated titration method for use on blended asphalts

    DOE Patents [OSTI]

    Pauli, Adam T. (Cheyenne, WY); Robertson, Raymond E. (Laramie, WY); Branthaver, Jan F. (Chatham, IL); Schabron, John F. (Laramie, WY)

    2012-08-07T23:59:59.000Z

    A system for determining parameters and compatibility of a substance such as an asphalt or other petroleum substance uses titration to highly accurately determine one or more flocculation occurrences and is especially applicable to the determination or use of Heithaus parameters and optimal mixing of various asphalt stocks. In a preferred embodiment, automated titration in an oxygen gas exclusive system and further using spectrophotometric analysis (2-8) of solution turbidity is presented. A reversible titration technique enabling in-situ titration measurement of various solution concentrations is also presented.

  4. A Methodology of Quantifying Precipitation Exposure for Wet-Weather Collisions and Evaluating Effectiveness of Open-Grade Asphalt Concrete as a Countermeasure

    E-Print Network [OSTI]

    Chan, Ching-Yao; Jin, Eui-Jae; Oh, Soon Mi; Ragland, David R

    2010-01-01T23:59:59.000Z

    Open-graded Asphaltic Concrete Friction Courses in Arizona.for Open-Graded Asphalt Concrete (OGAC) Wearing Courses.of Open-Grade Asphalt Concrete as a Countermeasure Ching-Yao

  5. asphalt technology development: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    asphalt technology development First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Development and...

  6. asphalt based materials: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    asphalt based materials First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Establishing material...

  7. Controlling Thermal Properties of Asphalt Concrete and its Multifunctional Applications

    E-Print Network [OSTI]

    Shi, Xijun

    2014-08-10T23:59:59.000Z

    of the thermally modified asphalt mixtures on the surface temperature of pavements and bridges, a series of heat transfer analysis were conducted using the finite difference heat transfer model. In addition, a case study of a building using EPP modified cement...

  8. Measurements of moisture suction in hot mix asphalt mixes

    E-Print Network [OSTI]

    Kassem, Emad Abdel-Rahman

    2006-10-30T23:59:59.000Z

    The presence of moisture in hot mix asphalt (HMA) causes loss of strength and durability of the mix, which is referred to as moisture damage. This study deals with the development of experimental methods for measuring total suction in HMA, which can...

  9. asphalt construction premature: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    asphalt construction premature First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Moisture Diffusion in...

  10. Winter Maintenance Guidelines for Porous Asphalt Maintenance

    E-Print Network [OSTI]

    environmental impact. · Apply deicing treatments during, and after storms as necessary to control compact snow and ice not removed by plowing. · Sand application should be limited since its use will increase the need

  11. Summary of Construction Activities and Results from Six Initial Accelerated Pavement Tests Conducted on Asphalt Concrete Pavement Section for Modified-Binder Overlay

    E-Print Network [OSTI]

    Bejarano, Manuel O.; Morton, Bruce S.; Scheffy, Clark

    2005-01-01T23:59:59.000Z

    Testing on the Asphalt Concrete FWD testing was conducted onin asphalt concrete modulus after HVS testing for Sectionsconcrete pavements under accelerated pavement testing. This

  12. The use of sulfer modified bottom ash (SMBA) as an aggregate in asphaltic mixtures

    E-Print Network [OSTI]

    Chimakurthy, Harshavardhan

    1998-01-01T23:59:59.000Z

    , bottom ash is lighter in weight and generally much cheaper than conventional quality aggregates such as limestone, sand and gravel. This research was designed to up-grade the load-bearing charactcnstics of bottom ash and maximize its usc m asphaltic... and gravel. According to a study done by Hafizuddin Ahmad in 1974, sulfur was used extensively in sand-asphalt sulfur to upgrade marginal aggregates for use in asphaltic mixtures, was developed at Texas Transportation Institute (TT1) (JO). TTI's work...

  13. Experimental Study on Geocell-Reinforced Flexible Pavements with Recycled Asphalt Pavement (RAP) Bases under Cyclic Loading

    E-Print Network [OSTI]

    Acharya, B. S.

    2011-12-31T23:59:59.000Z

    ABSTRACT The reprocessed old hot mix asphalt (HMA) concrete also called "Recycled Asphalt Pavement (RAP)", if used to build new roads or to maintain existing roads, would have several benefits, such as preservation of natural resources for future...

  14. Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded Viscoelastic Model, Part-I: Development,

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Asphalt Pavement Aging and Temperature Dependent Properties through a Functionally Graded simulations, correspondence principle, finite-element method Abstract. Asphalt concrete pavements to climatic conditions are the major cause of such graded non-homogeneity. Current pavement analysis

  15. Microstructural Characterization of the Chemo-mechanical Behavior of Asphalt in Terms of Aging and Fatigue Performance Properties

    E-Print Network [OSTI]

    Allen, Robert Grover

    2013-03-27T23:59:59.000Z

    The study of asphalt chemo-mechanics requires a basic understanding of the physical properties and chemical composition of asphalt and how these properties are linked to changes in performance induced by chemical modifications. This work uniquely...

  16. ORIGINAL CONTRIBUTION Rheological characterization of asphalt

    E-Print Network [OSTI]

    Mather, Patrick T.

    compared favorably with those obtained using conventional parallel-plate torsional flow in a commercial and are aggregates of polar aromatic compounds (Maruska and Rao 1987). Maltenes are nonpolar aliphatic hydrocarbons time (Anderson and Marasteanu 1999). Because of their codification, the conventional tests

  17. Microstructural Characterization of Material Properties and Damage in Asphalt Composites 

    E-Print Network [OSTI]

    Mohammad Khorasani, Sara

    2013-05-03T23:59:59.000Z

    by NPRP grant # 08-310-2-110 from the Qatar National Research Fund (a member of Qatar Foundation). The statements made herein are solely the responsibility of the authors. vi TABLE OF CONTENTS Page ABSTRACT... ........................................................................................................................ 17 3D Experimental Investigation of the Microstructure of Cement Pastes Using Synchrotron X-Ray Microtomography (?CT) .......................................................... 18 Dynamic Modulus Simulation of the Asphalt Concrete Using the X...

  18. Evaluation of Rexene polymers in hot mixed asphalt concrete

    E-Print Network [OSTI]

    Rodriguez, Mary Anne Reese

    1991-01-01T23:59:59.000Z

    -- polyethylene, polypropylene, ethylene-vinyl acetate (EVA) and ethylene-propylene rubbers -- show increased stability and stiffness modulus, increased resistance to permanent deformation and lower temperature susceptibility. Carpenter and VanDam (14... five asphalt additives: block copolymer rubber, SBR latex, EVA, polyethylene and carbon black. Mixture stability, stiffness, tensile strength and resistance to fatigue, thermal cracking, permanent deformation and moisture damage were tested. Three...

  19. INTRODUCTION The increase in energy costs has led to a significant rise in the cost of mixtures containing asphalt cement. This resulted

    E-Print Network [OSTI]

    Harms, Kyle E.

    containing asphalt cement. This resulted in a need to search for alternatives that reduce the cost of those mixed with low percentages (1 percent below standard HMA mixtures) of paving grade asphalt cement and lower percentages of asphalt cement binder and easier compaction efforts. Asphalt treated mixtures can

  20. Effect of pavement temperature on the macrotexture of a semidense asphalt surface

    E-Print Network [OSTI]

    Boyer, Edmond

    Effect of pavement temperature on the macrotexture of a semidense asphalt surface J. Luong, M the pavement temperature could change the texture surface of the pavement. The aim of this work is to analyze the influence of the surface temperature on the macrotexture of a semidense asphalt pavement located in an urban

  1. Dynamic Effects on Moisture Transport in Asphalt Concrete M. Emin Kutay1

    E-Print Network [OSTI]

    Aydilek, Ahmet

    Dynamic Effects on Moisture Transport in Asphalt Concrete M. Emin Kutay1 and Ahmet H. Aydilek2 2007 133:7 406 CE Database subject headings: Moisture; Asphalt concrete; Dynamics; Hydraulic and Magdalena 2002 ; however, limited research has been conducted in modeling dynamic flow in porous geomedia

  2. RESEARCH REPORT 987-9 ASPHALT OVERLAY DESIGN METHODS FOR RIGID

    E-Print Network [OSTI]

    Texas at Austin, University of

    by using a fractional factorial design. An analysis of variance (ANOVA) was performed to identifyRESEARCH REPORT 987-9 ASPHALT OVERLAY DESIGN METHODS FOR RIGID PAVEMENTS CONSIDERING RUTTING's Catalog No. 5. Report Date October 1998 4. Title and Subtitle ASPHALT OVERLAY DESIGN METHODS FOR RIGID

  3. Characterization of asphalt cements modified with crumbed rubber from discarded tires. Final report

    SciTech Connect (OSTI)

    Daly, W.H.; Negulescu, I.I.

    1994-11-01T23:59:59.000Z

    The potential legislative requirement for incorporation of scrap rubber into asphalt blends mandated a thorough evaluation of the influence of scrap rubber additives on the physical properties and aging characteristics of rubber/asphalt blends. Blends with up to 20 percent ground vulcanized rubber (both crumb and 200 mesh powder particles) from recycled tires were prepared with asphalt cements of various grades (AC5 - AC30) and evaluated using DMA. Blends produced from powdered rubber particles exhibited Newtonian behavior at high temperatures; similar behavior was not observed with crumb rubber blends. The mechanical properties of asphalt-rubber blends depend upon the concentration of rubber additives, the particle dimensions, and the chemical composition of the asphalt.

  4. A study of the effects of limestone rock asphalt screenings on the structural properties of hot-mix asphaltic concrete made with siliceous materials

    E-Print Network [OSTI]

    Albritton, Oscar Willard

    1958-01-01T23:59:59.000Z

    Society for Testing Materials, Phila. , Pa. 15 PROCEDURE To limit the wide variations of aggregate grading, specifica- tions of the Texas Highway Department for a Type "D" Hot-Mix, Hot- Laid, Asphaltic Concrete were used as a guide in the design... Standards on Mineral Aggregates, Concrete, and Nonbituminous Highway Materials, American Society for Testing Materials, Phila, , Pa. Benson, Fred J, and Bh. Subbaraju, "Specific Gravity of Aggregates in Asphaltic Paving Mixtures, " Texas Engineering...

  5. High temperature performance of scrap tire rubber modified asphalt concrete

    SciTech Connect (OSTI)

    Coomarasamy, A. [Ministry of Transportation, Downsview, Ontario (Canada); Manolis, S.; Hesp, S. [Queen`s Univ., Kingston, Ontario (Canada)

    1996-12-31T23:59:59.000Z

    Wheel track rutting tests on mixes modified with 30 mesh, 80 mesh, and very fine colloidal crumb rubber particles show that a very significant improvement in performance occurs with a reduction in the rubber particle size. The SHRP binder test for rutting, which was originally developed for homogeneous systems only, does not predict the performance improvement for smaller rubber particles. If these new scrap rubber binder systems are to be used in pavements then rutting tests on the asphalt-aggregate mixture should be conducted in order to accurately predict high temperature performance.

  6. Influence of fundamental material properties and air void structure on moisture damage of asphalt mixes 

    E-Print Network [OSTI]

    Arambula Mercado, Edith

    2009-05-15T23:59:59.000Z

    parameters were obtained using mechanical tests and surface energy measurements. The microstructure of asphalt mixes prepared in the laboratory having different air void structures was captured using X-ray CT, and image analysis techniques were used...

  7. Evaluation of healing in asphalt binders using dynamic shear rheometer and molecular modeling techniques 

    E-Print Network [OSTI]

    Bommavaram, Ramamohan Reddy

    2009-05-15T23:59:59.000Z

    A self-healing material has the inherent ability to partially reverse damage such as crack formation that might have occurred during its service. Significant evidence exists in the literature to indicate that asphalt binder is a self...

  8. A Continuum Coupled Moisture-mechanical Constitutive Model for Asphalt Concrete

    E-Print Network [OSTI]

    Shakiba, Maryam

    2013-12-09T23:59:59.000Z

    procedure and give insight into the various damage inducing mechanisms in asphalt concrete. In this dissertation, thermo-hygro-mechanical constitutive relationships are developed based on the principle of virtual power and laws of thermodynamics in order...

  9. Chip Seals for Asphalt Concrete Pavements: A Proposed Emulsion Residue Specification and Existing Pavement Texture Evaluation

    E-Print Network [OSTI]

    Hoyt, Denise

    2012-07-16T23:59:59.000Z

    Chip seals are a pavement surface treatment used for maintaining asphalt concrete pavements. National Cooperative Highway Research Program (NCHRP) Project 14-17 was performed to produce a national Chip Seal Manual which would consolidate the best...

  10. Development of superior asphalt recycling agency: Phase 1, Technical feasibility. Technical progress report

    SciTech Connect (OSTI)

    Bullin, J.A.; Glover, C.J.; Davison, R.R.; Lin, Moon-Sun; Chaffin, J.; Liu, Meng; Eckhardt, C.

    1996-04-01T23:59:59.000Z

    About every 12 years, asphalt roads must be reworked, and this is usually done by placing thick layers (hot-mix overlays) of new material on top of failed material, resulting in considerable waste of material and use of new asphalt binder. A good recycling agent is needed, not only to reduce the viscosity of the aged material but also to restore compatibility. Objective is to establish the technical feasibility (Phase I) of determining the specifications and operating parameters for producing high quality recycling agents which will allow most/all the old asphalt-based road material to be recycled. It is expected that supercritical fractionation can be used. The advanced road aging simulation procedure will be used to study aging of blends of old asphalt and recycling agents.

  11. A program to design asphalt concrete overlays to mitigate reflection cracking

    E-Print Network [OSTI]

    Satyanarayana Rao, Sindhu

    2002-01-01T23:59:59.000Z

    of the research are to understand the occurrence and behavior of reflection cracking and for devising ways of mitigating them and to put together an effective and complete package of computer programs to design asphalt concrete overlays. Another primary objective...

  12. Evaluation of healing in asphalt binders using dynamic shear rheometer and molecular modeling techniques

    E-Print Network [OSTI]

    Bommavaram, Ramamohan Reddy

    2009-05-15T23:59:59.000Z

    the parameters of characteristic healing function of asphalt binders. In the second part of this study, Molecular Modeling (MM) techniques were used to determine the interrelationship between molecular structure, surface free energy, self diffusivity, and other...

  13. Laboratory evaluation of crumb rubber asphalt concrete mixtures using the concepts of SMA mixtures 

    E-Print Network [OSTI]

    Rebala, Somasekhar Reddy

    1994-01-01T23:59:59.000Z

    Eight CRM asphalt concrete mixtures were evaluated using AAMAS characterization procedures: Four wet-process mixtures and four dry-process mixtures. These mixtures were compared to a conventional dense graded mixture. It was determined that CRM has...

  14. Automated Protocol for the Analysis of Dynamic Mechanical Analyzer Date from Fine Aggregate Asphalt Mixes 

    E-Print Network [OSTI]

    Cavalcanti De Sousa, Pedro

    2010-10-12T23:59:59.000Z

    Fatigue cracking and moisture damage are two important modes of distresses in asphalt pavements. Recently, the Dynamic Mechanical Analyzer (DMA) was used to characterize fatigue cracking and evaluate the effects of moisture ...

  15. The morphology of polymer modified asphalt and its relationship to rheology and durability

    E-Print Network [OSTI]

    Kraus, Zachary Rothman

    2008-10-10T23:59:59.000Z

    % % loglog * deg6010* deg6010 ?? , where d%A is the change in asphaltene in the asphalt (19). The other theory is that only the polar aromatics and napthene aromatics fluoresce when separated from the asphalt binder (16). Therefore as polar and napthene... aromatics change to asphaltenes with oxidative aging, the brightness would decrease. This brightness decrease would correspond to the increase in asphaltene with carbonyl area leading to a graph that looks like a chart for hardening susceptibility...

  16. An investigation of three problems concerning the analysis of airborne asphalt fumes

    E-Print Network [OSTI]

    Laird, Larry Teal

    1981-01-01T23:59:59.000Z

    AN INVESTIGATION OF THREE PROBLEMS CONCERNING THE ANALYSIS OF AIRBORNE ASPHALT FUMES A Thesis by LARRY TEAL LAIRD Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement for the degree of MASTER... OF SCIENCE May 1981 Major Subject: Industrial Hygiene AN INVESTIGATION OF THREE PROBLEMS CONCERNING THE ANALYSIS OF AIRBORNE ASPHALT FUMES A Thesis by LARRY T. LAIRD Approved as to style and content by: (Chairm of Committee) (Head of Department...

  17. Evaluation of oil shale bitumen as a pavement asphalt additive to reduce moisture damage susceptibility

    SciTech Connect (OSTI)

    Robertson, R.E.; Harnsberger, P.M.; Wolf, J.M.

    1991-01-01T23:59:59.000Z

    An unrefined shale bitumen was evaluated as an agent to reduce moisture damage susceptibility of asphalt aggregate mixtures. Some activity was observed but less than might have been expected based on the molecular weight and nitrogen content of the bitumen. The counter effects of free carboxylic acids, which are known to be variable in asphalt and which are also present in the unrefined bitumen, appear to diminish the activity of the bitumen to inhibit moisture damage. 5 refs., 1 tab.

  18. Evaluation of the effects of crumb rubber and SBR on rutting resistance of asphalt concrete

    SciTech Connect (OSTI)

    Shih, Chuang-Tsair; Tia, Mang; Ruth, B.E. [Univ. of Florida, Gainesville, FL (United States)

    1996-12-31T23:59:59.000Z

    This paper presents the results of a study to evaluate the effects of addition of crumb rubber (CR) and styrene-butadiene rubber (SBR) on the rutting resistance of asphalt concrete. These two additives were blended with an AC-20 and an AC-30 grade asphalt cements at different levels of concentrations. These modified and unmodified asphalt blends were tested at intermediate and high temperatures to evaluate their rutting resistance characteristics. They were also used to make Florida type S-I structural surface mixtures. These mixtures were made into Marshall-size specimens by using Gyratory Testing Machine (GTM) equipped with air-roller to compact and density to three compaction levels which simulate three different conditions in the pavement. The FDOT`s (Florida Department of Transportation) Loaded Wheel Tester was also used to evaluate the rutting resistance of these asphalt mixtures. The test results indicate that the modified asphalt mixtures show relatively better rutting resistance and shear resistance as compared with the unmodified asphalt mixtures.

  19. State of the practice: Design and construction of asphalt paving materials with crumb-rubber modifier. Final report

    SciTech Connect (OSTI)

    Heitzman, M.A.

    1992-05-01T23:59:59.000Z

    The document is a comprehensive overview of the terminology, processes, products, and applications of crumb rubber modifier (CRM) technology. The technology includes any use of scrap tire rubber in asphalt paving materials. In general, CRM technology can be divided into two categories--the wet process and the dry process. When CRM is incorporated into an asphalt paving material, it will modify the properties of the binder (asphalt rubber) and/or act as a rubber aggregate (rubber modified hot mix asphalt). The five concepts for using CRM discussed in the report are McDonald, PlusRide, generic dry, chunk rubber asphalt concrete, and continuous blending asphalt rubber. There are two principal unresolved engineering issues related to the use of CRM in asphalt paving materials. On the national level, the ability to recycle asphalt paving mixes containing CRM has not been demonstrated. At the State and local levels, these modified asphalt mixes must be field evaluated to establish expected levels of performance. The appendices provide guidelines for material specifications, mix design, and construction specifications. An experimental work plan for monitoring performance and a stack emission testing program are also included.

  20. Process for removing sulfur from coal

    DOE Patents [OSTI]

    Aida, Tetsuo (Ames, IA); Squires, Thomas G. (Gilbert, IA); Venier, Clifford G. (Ames, IA)

    1985-02-05T23:59:59.000Z

    A process for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  1. Process for removing sulfur from coal

    DOE Patents [OSTI]

    Aida, T.; Squires, T.G.; Venier, C.G.

    1983-08-11T23:59:59.000Z

    A process is disclosed for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  2. Development of statistical wet weather model to evaluate frictional properties at the pavement-tire interface on hot mix asphalt concrete

    E-Print Network [OSTI]

    Bedi, Harpreet

    2001-01-01T23:59:59.000Z

    Skid resistance on wet pavements is influenced by friction at the tire-pavement interface as well as overall hot mix asphalt (HMA) performance. It is important to control aggregate, asphalt, and mix properties to achieve desirable frictional...

  3. Method of removal of sulfur from coal and petroleum products

    DOE Patents [OSTI]

    Verkade, John G. (Ames, IA); Mohan, Thyagarajan (Ames, IA); Angelici, Robert J. (Ames, IA)

    1995-01-01T23:59:59.000Z

    A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

  4. Department of Energy and Mineral Engineering Spring Roller Design to Increase the Lifespan of Asphalt Compactor Wiper Blades

    E-Print Network [OSTI]

    Demirel, Melik C.

    the Lifespan of Asphalt Compactor Wiper Blades By: Thomas Krupa, Eric Resch, Phillip Yesenosky, John Marshall, Asset Kusmanov Overview Volvo CE's asphalt compactors have a polymer wiper blade that is used life. o The roller was tested five times as long as the wipers and never showed any change in diameter

  5. Development of superior asphalt recycling agents. Phase 1, Technical feasibility. Final technical progress report

    SciTech Connect (OSTI)

    Bullin, J.A.; Davison, R.R.; Glover, C.J.; Chaffin, J.; Liu, M.; Madrid, R.

    1997-07-01T23:59:59.000Z

    After an introduction and a literature survey in Chap. 1, Chap. 2 describes the tasks, together with objectives and important results obtained for each task throughout the entire project. Chaps. 3 thru 7 detail work in developing a qualitative and quantitative knowledge of asphalt oxidation, composition dependence of asphalt properties, and guidelines for producing superior asphalt binders through composition control. They also detail the development of a kinetic model for asphalt oxidative aging and present an understanding of the composition dependence of asphalt oxidation as well as other performance-related properties. Chaps. 8 and 9 compare the aging performance of recycled blends produced using commercial recycling agents and industrial supercritical fractions as rejuvenating agents. Oxidative aging of the recycled blends were evaluated along with the performance of the recycled blends in terms of the strategic highway research program performance grading procedure. Chap. 10 summarizes the work completed in the areas of processing schemes development, projection updates, and scale-up and commercialization plans.

  6. Effects of carboxylic acids on the rheological properties of crumb rubber modified asphalt

    SciTech Connect (OSTI)

    Tauer, J.E.; Robertson, R.E. [Western Research Institute, Laramie, WY (United States)

    1996-12-31T23:59:59.000Z

    The Federal mandate of 1991-1995 on the use of scrap tires in Federal roadway construction sparked a major interest in gaining a fundamental understanding of the behavior of rubber in asphalt. This study is a systematic elucidation of what chemistry controls the final crumb rubber modified asphalt (CRMA) product quality. We discovered that the type and total acid content in the asphalt are the most influential chemical factors that determine the changes in the important roadway properties of shear modulus (G*) and loss angle ({delta}) of CRMA. Low acid (<0.005 m/L) asphalts were modified with three types of carboxylic acid and each made into CRMA using typical field mixing conditions of 1 hour at 175{degrees}C. Rheological measurements were then made at various storage times up to 192 hours following storage at both 156 and 200{degrees}C. We found the changes in CRMA theological properties correspond to the acid type spiked into the asphalt.

  7. Viscoroute 2.0: a tool for the simulation of moving load effects on asphalt pavement

    E-Print Network [OSTI]

    Chabot, Armelle; Deloffre, Lydie; Duhamel, Denis

    2010-01-01T23:59:59.000Z

    As shown by strains measured on full scale experimental aircraft structures, traffic of slow-moving multiple loads leads to asymmetric transverse strains that can be higher than longitudinal strains at the bottom of asphalt pavement layers. To analyze this effect, a model and a software called ViscoRoute have been developed. In these tools, the structure is represented by a multilayered half-space, the thermo-viscoelastic behaviour of asphalt layers is accounted by the Huet-Sayegh rheological law and loads are assumed to move at constant speed. First, the paper presents a comparison of results obtained with ViscoRoute to results stemming from the specialized literature. For thick asphalt pavement and several configurations of moving loads, other ViscoRoute simulations confirm that it is necessary to incorporate viscoelastic effects in the modelling to well predict the pavement behaviour and to anticipate possible damages in the structure.

  8. Asphalt emulsion radon barrier systems for uranium mill tailings: an overview of the technology

    SciTech Connect (OSTI)

    Baker, E.G.; Hartley, J.N.; Freeman, H.D.; Gates, T.E.; Nelson, D.A.; Dunning, R.L.

    1984-03-01T23:59:59.000Z

    Pacific Northwest Laboratory (PNL), under contract to the US Department of Energy (DOE) Uranium Mill Tailings Remedial Action Project (UMTRAP) office, has developed an asphalt emulsion cover system to reduce the release of radon from uranium mill tailings. The system has been field tested at Grand Junction, Colorado. Results from laboratory and field tests indicate that this system is effective in reducing radon release to near-background levels (<2.5 pCi m/sup -2/s/sup -1/) and has the properties required for long-term effectiveness and stability. Engineering specifications have been developed, and analysis indicates that asphalt emulsion covers are cost-competitive with other cover systems. This report summarizes the technology for asphalt emulsion radon barrier systems. 59 references, 45 figures, 36 tables.

  9. Application of pyrolized carbon black from scrap tires in asphalt pavement design and construction

    SciTech Connect (OSTI)

    Park, T.; Coree, B.J. [Indiana Department of Transportation, West Lafayette, IN (United States). Division of Research; Lovell, C.W. [Purdue Univ., West Lafayette, IN (United States). School of Civil Engineering

    1995-12-31T23:59:59.000Z

    According to EPA reports (1991) of the over 242 million waste generated each year in the United State, 5% are exported, 6% recycled, 11% incinerated, and 78% are landfilled, stockpiled, or illegally dumped. A variety of uses for these tires are being studied. Among these is pyrolysis which produces 5 5% of oil, 25% of carbon black, 9% of steel, 5% of fiber and 6% of gas. Pyrolized carbon black contains 9 % of ash, 4% of sulfur, 12% of butadine copolymer and 75% of carbon black. The objective of this research is to investigate the viability of using PCB as an additive in hot mix asphalt. The use of PCB in asphalt pavement is expected not only to improve the performance of conventional asphalt, but also to provide a means for the mass disposal of waste fires.

  10. Recycled tire rubber and other waste materials in asphalt mixtures. Transportation research record

    SciTech Connect (OSTI)

    NONE

    1995-12-31T23:59:59.000Z

    The papers in this volume, dealing with various facets of recycled tire rubber and other waste materials in asphalt mixtures, should be of interest to state and local construction, design, materials, and research engineers as well as contractors and material producers. In the first papers, Rebala and Estakhri, Malpass and Khosla, and Baker and Connolly describe research related to crumb rubber modified mixtures that was done for the Texas, North Carolina, and New Jersey State Departments of Transportation. Ali et al. report on their research in Canada to determine the feasibility of sing reclaimed roofing materials in hot mix asphalt pavement. Emery discusses the evaluation of 11 Ontario rubber modified demonstration projects in terms of pavement performance, environmental impacts, and recyclability. In the last paper, Fwa and Aziz report on their work in Singapore related to the use of incinerator residue in asphalt mixtures.

  11. Studies of asphalt air blowing and development of a new short-term aging technique

    E-Print Network [OSTI]

    Vassiliev, Nicolai

    2001-01-01T23:59:59.000Z

    , Table m-2. Low temperature hardening properi. ies of air blown asphalt fractions and blends. Table III-3. Parent asphalt HS, oxidation rate, and HR . Table IV-1. Estimated time required to achieve same degrcc of aging as RTFOT for Exxon AC-10 films... of varying I. hickness . 70 Table IV-2 Effect of air blowing conditions for Exxon AC- I 0, 325 'F, 70 min. 70 Table IV-3. Condensed volatiles and RTFOT mass change . 80 Table IV-4. Reproducibility analysis. LIST OF FIGURES P ige Figure I-l. Thin film...

  12. Influence of coarse aggregate size, shape and surface texture on rutting of hot mix asphalt concrete

    E-Print Network [OSTI]

    Yeggoni, Mohan

    1993-01-01T23:59:59.000Z

    increased Hveem Stability, Marshall Stability and resistance to creep of hot mix asphalt concrete. The resilient modulus of the specimens was also enhanced by the increase in the amount of crushed aggregate in the mix at high temperatures (115'F). Fractal...

  13. The State of the Practice and Common Pitfalls for Porous Asphalt for

    E-Print Network [OSTI]

    of stormwater treatment systems · To provide resources to stormwater communities currently involved in design)-131 Porous Asphalt Pavements (2008) NAPA IS-115 Open-Graded Friction Courses (2002) 3 #12;Overview 1. State of the Practice 2. Water Quality Performance 3. Hydraulic Performance 4. Cold Climate

  14. Project Information Form Project Title Evaluation of the Combined Effect of Recycled Asphalt Pavement (RAP),

    E-Print Network [OSTI]

    California at Davis, University of

    Pavement (RAP), Recycled Asphalt Shingles (RAS), and Different Virgin Binder Sources on Performance of Research Project As virgin material sources become increasingly scarce, and the volume of pavement material for pavement construction. The California Department of Transportation (Caltrans) has recently increased

  15. Mixture design and performance prediction of rubber-modified asphalt in Ohio. Final report

    SciTech Connect (OSTI)

    Liang, R.Y.

    1997-08-01T23:59:59.000Z

    Appropriate disposal of scrap tires has been a major environmental concern over the years, mainly due to potential fire and health hazards associated with uncontrolled stockpiling. Primarily driven by this environmental concern, the Intermodal Surface Transportation Efficiency Act (ISTEA) of 1991 has required each State to begin incorporating scrap tire rubber into its asphalt paving materials. Although in the revision of the original ISTEA, the mandate has been eliminated, there remains a language of encouraging the use of crumb rubbers in asphalt paving materials. Ohio Department of Transportation (ODOT) desires to develop the mix design procedure, construction practice, and performance specifications for crumb rubber modified asphalt paving materials. This research was conducted to develop the needed design and construction guidance for meeting the ODOT anticipated needs. Specifically, the objectives of this research encompass the following scope: (1) investigation of the rheological properties of asphalt-rubber binder to determine optimum content of crumb rubber, (2) development of optimum mix design for various applications, including both wet and dry mix processes, (3) characterization of mechanical properties of recommended paving mixtures, including resilient modulus, fatigue cracking behavior, low-temperature thermal cracking resistance, water sensitivity test, incremental creep test and loaded wheel track test, and (4) comparison of performance of selected paving mixes.

  16. FIELD PERFORMANCE AND LABORATORY EVALUATION OF WARM MIX ASPHALT PRODUCED WITH RUBBERIZED BITUMEN

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    FIELD PERFORMANCE AND LABORATORY EVALUATION OF WARM MIX ASPHALT PRODUCED WITH RUBBERIZED BITUMEN of rubberized bitumen has been spread out mainly due to environmental aspects, but high mixing and compaction temperatures are necessary due to the higher viscosity of this bitumen. A WMA mixture (using a surfactant

  17. Creep Compliance Analysis Technique for the Flattened Indirect Tension Test of Asphalt Concrete

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Creep Compliance Analysis Technique for the Flattened Indirect Tension Test of Asphalt Concrete: ­ Cored Sample (Cylindrical) Indirect tensile testing (IDT) (Strength/Creep) ­ AASHTO T-322 Damage under and Flattened IDT · 1000-sec creep tests on three replicates · 0, -10, and -20 deg. C · Displacement

  18. Mirzahosseini et. al. ANN-Based Prediction Model for Rutting Propensity of Asphalt Mixtures1

    E-Print Network [OSTI]

    Fernandez, Thomas

    in a repeated load permanent deformation test.21 Dynamic creep test is one of the best tools for assessing of load cycles is the most23 important output of the dynamic creep test. This curve includes primary based on volumetric proportioning of the asphalt mixture. This method does16 not include any direct test

  19. Polybenzimidazole compounds

    DOE Patents [OSTI]

    Klaehn, John R. (Idaho Falls, ID); Peterson, Eric S. (Idaho Falls, ID); Orme, Christopher J. (Shelley, ID); Jones, Michael G. (Chubbuck, ID); Wertsching, Alan K. (Idaho Falls, ID); Luther, Thomas A. (Idaho Falls, ID); Trowbridge, Tammy L. (Idaho Falls, ID)

    2011-11-22T23:59:59.000Z

    A PBI compound includes imidazole nitrogens at least a portion of which are substituted with a moiety containing a carbonyl group, the substituted imidazole nitrogens being bonded to carbon of the carbonyl group. At least 85% of the nitrogens may be substituted. The carbonyl-containing moiety may include RCO--, where R is alkoxy or haloalkyl. The PBI compound may exhibit a first temperature marking an onset of weight loss corresponding to reversion of the substituted PBI that is less than a second temperature marking an onset of decomposition of an otherwise identical PBI compound without the substituted moiety. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may use more than 5 equivalents in relation to the imidazole nitrogens to be substituted.

  20. Polybenzimidazole compounds

    DOE Patents [OSTI]

    Klaehn, John R. (Idaho Falls, ID); Peterson, Eric S. (Idaho Falls, ID); Wertsching, Alan K. (Idaho Falls, ID); Orme, Christopher J. (Shelley, ID); Luther, Thomas A. (Idaho Falls, ID); Jones, Michael G. (Pocatello, ID)

    2010-08-10T23:59:59.000Z

    A PBI compound that includes imidazole nitrogens, at least a portion of which are substituted with an organic-inorganic hybrid moiety. At least 85% of the imidazole nitrogens may be substituted. The organic-inorganic hybrid moiety may be an organosilane moiety, for example, (R)Me.sub.2SiCH.sub.2--, where R is selected from among methyl, phenyl, vinyl, and allyl. The PBI compound may exhibit similar thermal properties in comparison to the unsubstituted PBI. The PBI compound may exhibit a solubility in an organic solvent greater than the solubility of the unsubstituted PBI. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may occur at about room temperature and/or at about atmospheric pressure. Substituting may use at least five equivalents in relation to the imidazole nitrogens to be substituted or, preferably, about fifteen equivalents.

  1. Asphalt and Asphaltic Concrete

    E-Print Network [OSTI]

    Young, A. R.

    1914-05-01T23:59:59.000Z

    , and combined curb and gutter furnished and set, the rate for resetting old curbing; the rate per cubic yard for extra concrete, if any is used; the price per cubic yard for broken stone or gravel; the rate per square yard for paving and for relaying old...- tified and given access to the same at least ten days be- fore it is required for use, and any work in which re- jected cement was used will be rejected altogether. 5. The cement shall be packed in strong bags having printed on the outside the brand...

  2. A comparison of the fracture properties of conventional and polymer-modified two-layer asphalt concrete overlay systems 

    E-Print Network [OSTI]

    Reddy, Praveena Gutha

    1996-01-01T23:59:59.000Z

    The problem of reflection cracking through the conventional asphalt concrete overlays has increased the need to find new materials which could resist cracking or fracture more effectively. It is for this reason that polymers ...

  3. Comparison of fatigue analysis approaches for predicting fatigue lives of hot-mix asphalt concrete (HMAC) mixtures

    E-Print Network [OSTI]

    Walubita, Lubinda F.

    2006-08-16T23:59:59.000Z

    Hot-mix asphalt concrete (HMAC) mixture fatigue characterization constitutes a fundamental component of HMAC pavement structural design and analysis to ensure adequate field fatigue performance. HMAC is a heterogeneous complex composite material...

  4. Fatigue resistance of hot-mix asphalt concrete (HMAC) mixtures using the calibrated mechanistic with surface energy (CMSE) measurements approach

    E-Print Network [OSTI]

    Ofori-Abebresse, Edward Kwame

    2006-10-30T23:59:59.000Z

    Fatigue cracking is one of the fundamental distresses that occur in the life of a Hot Mix Asphalt Concrete (HMAC) pavement. This load induced distress leads to structural collapse of the entire pavement ultimately and can only be remedied...

  5. Fatigue resistance of hot-mix asphalt concrete (HMAC) mixtures using the calibrated mechanistic with surface energy (CMSE) measurements approach 

    E-Print Network [OSTI]

    Ofori-Abebresse, Edward Kwame

    2006-10-30T23:59:59.000Z

    Fatigue cracking is one of the fundamental distresses that occur in the life of a Hot Mix Asphalt Concrete (HMAC) pavement. This load induced distress leads to structural collapse of the entire pavement ultimately and can ...

  6. A unified method for the analysis of nonlinear viscoelasticity and fatigue cracking of asphalt mixtures using the dynamic mechanical analyzer

    E-Print Network [OSTI]

    Castelo Branco, Veronica Teixeira Franco

    2009-05-15T23:59:59.000Z

    A UNIFIED METHOD FOR THE ANALYSIS OF NONLINEAR VISCOELASTICITY AND FATIGUE CRACKING OF ASPHALT MIXTURES USING THE DYNAMIC MECHANICAL ANALYZER A Dissertation by VERONICA TEIXEIRA FRANCO CASTELO BRANCO Submitted to the Office... VISCOELASTICITY AND FATIGUE CRACKING OF ASPHALT MIXTURES USING THE DYNAMIC MECHANICAL ANALYZER A Dissertation by VERONICA TEIXEIRA FRANCO CASTELO BRANCO Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

  7. A study of substitution solvents in asphalt fume extraction and the effects of heating duration and temperature 

    E-Print Network [OSTI]

    Curry, Noel Thomas

    1981-01-01T23:59:59.000Z

    may be used as substitute solvents for the solvent extraction analytical method for asphalt furres proposed by NlnSH and currently in use by OSHA. Benzene is known to orovide IC0% effic- 1 iency in asphalt fume extraction. The results..., rather than the solvents' effic- iency loss, was responsible for the differences. The importance of the data lies in the fact that the other two test solvents exhibited a consiatency equal to that of benzene. 'Ahile the exact coefficient of any...

  8. An analysis of some properties of paving asphalts in Texas as they relate to pavement performance

    E-Print Network [OSTI]

    DuBose, Emmett Haygood

    1980-01-01T23:59:59.000Z

    51 73 93 115 115 DISTRESS AND CRACKING FACTORS THE PAVEMENT PERFORMANCE SYSTEM 5 CONCLUSIONS AND RECOMMENDATIONS CONCLUSIONS RECOMMENDATIONS REFERENCES . APPENDIX A: RAW DATA APPENDIX B: PAVEMENT PERFORMANCE VS. TIME CURVES APPENDIX C... harden1ng model. It had been shown in earlier research that excessive asphalt1c concrete binder hardening was a detrimental factor influencing certain types of pavement distress such as thermal cracking, raveling, fatigue cracking, and reflective crack...

  9. Thickness estimation of subsurface layers in asphalt pavement using monstatic ground penetrating radar

    E-Print Network [OSTI]

    Lau, Chun Lok

    1991-01-01T23:59:59.000Z

    for the degree of MASTER OF SCIENCE December 1991 Major Subject: Electrical Engineering THICKNESS ESTIMATION OF SUBSURFACE LAYERS IN ASPHALT PAVEMENT USING MONSTATIC GROUND PENETRATING RADAR A Thesis CHUN LOK LAU Approved as to style and content by... ACKNOWLEDGEMENTS. LIST OF FIGURES. . CHAPTER I INTRODUCTION. 1. 1 Importance of pavement profile data. 1. 2 Principle of Ground Penetrating Radar (GPR) . . . 1. 3 Subsurface layer thickness measurement method. . . . . . II GPR ANTENNA AND SYSTEM CALIBRATION...

  10. Oxidative reactions and their impact on the properties of asphalt as a pavement binder

    E-Print Network [OSTI]

    Lau, Chee Keung

    1991-01-01T23:59:59.000Z

    mechanical spectrometer was found to increase with aging time. Correlation was shown to exist between the limiting complex viscosity and the carbonyl area as determined by infrared analysis. The correlation was unique for each asphalt and was independent... of aging temperature. The carbonyl area growth rate was a strong function of the aging temperature and the temperature dependence of the rate constant followed the Arrhenius relation within the temperature range tested. The results led...

  11. Viscosity, relaxation time, and dynamics within a model asphalt of larger molecules

    SciTech Connect (OSTI)

    Li, Derek D.; Greenfield, Michael L., E-mail: greenfield@egr.uri.edu [Department of Chemical Engineering, University of Rhode Island, Kingston, Rhode Island 02881 (United States)

    2014-01-21T23:59:59.000Z

    The dynamics properties of a new “next generation” model asphalt system that represents SHRP AAA-1 asphalt using larger molecules than past models is studied using molecular simulation. The system contains 72 molecules distributed over 12 molecule types that range from nonpolar branched alkanes to polar resins and asphaltenes. Molecular weights range from 290 to 890 g/mol. All-atom molecular dynamics simulations conducted at six temperatures from 298.15 to 533.15 K provide a wealth of correlation data. The modified Kohlrausch-Williams-Watts equation was regressed to reorientation time correlation functions and extrapolated to calculate average rotational relaxation times for individual molecules. The rotational relaxation rate of molecules decreased significantly with increasing size and decreasing temperature. Translational self-diffusion coefficients followed an Arrhenius dependence. Similar activation energies of ?42 kJ/mol were found for all 12 molecules in the model system, while diffusion prefactors spanned an order of magnitude. Viscosities calculated directly at 533.15 K and estimated at lower temperatures using the Debye-Stokes-Einstein relationship were consistent with experimental data for asphalts. The product of diffusion coefficient and rotational relaxation time showed only small changes with temperature above 358.15 K, indicating rotation and translation that couple self-consistently with viscosity. At lower temperatures, rotation slowed more than diffusion.

  12. Materials Chemistry and Performance of Silicone-Based Replicating Compounds.

    SciTech Connect (OSTI)

    Brumbach, Michael T.; Mirabal, Alex James; Kalan, Michael; Trujillo, Ana B; Hale, Kevin

    2014-11-01T23:59:59.000Z

    Replicating compounds are used to cast reproductions of surface features on a variety of materials. Replicas allow for quantitative measurements and recordkeeping on parts that may otherwise be difficult to measure or maintain. In this study, the chemistry and replicating capability of several replicating compounds was investigated. Additionally, the residue remaining on material surfaces upon removal of replicas was quantified. Cleaning practices were tested for several different replicating compounds. For all replicating compounds investigated, a thin silicone residue was left by the replica. For some compounds, additional inorganic species could be identified in the residue. Simple solvent cleaning could remove some residue.

  13. Development of asphalts and pavements using recycled tire rubber. Phase 1, Technical feasibility. Technical progress report, September 1, 1994--August 31, 1995

    SciTech Connect (OSTI)

    Bullin, J.A.; Davison, R.R.; Glover, C.J. [and others

    1996-06-01T23:59:59.000Z

    About 285 million tires are discarded every year; less than 100 million are currently being recycled, with the rest being placed in landfills and other waste sites. A solution to reduce the littering of the environment is to use ground tire rubber in road construction. Currently, about 27 million tons of asphalt are used each year in road construction and maintenance of the country`s 2 million miles of roads. If all of the waste tire rubber could be combined with asphalt in road construction, it would displace less than 6% of the total asphalt used each year, yet could save about 60 trillion Btus annually. Purpose of this project is to provide data needed to optimize the performance of rubber-asphalt concretes. The first phase is to develop asphalts and recycling agents tailored for compatibility with ground tire rubber. Chapter 2 presents results on Laboratory Testing and Evaluation: fractionate asphalt material, reblending for aromatic asphalts, verifying optimal curing parameters, aging of blends, and measuring ductilities of asphalt-rubber binders. Chapter 3 focuses on Evaluating Mixture Characteristics (modified binders). Chapter 4 covers Adhesion Test Development (water susceptibility is also covered). The final chapter focuses on the Performance/Economic Update and Commercialization Plan.

  14. Bismaleimide compounds

    DOE Patents [OSTI]

    Adams, J.E.; Jamieson, D.R.

    1986-01-14T23:59:59.000Z

    Bismaleimides of the formula shown in the diagram wherein R[sub 1] and R[sub 2] each independently is H, C[sub 1-4]-alkyl, C[sub 1-4]-alkoxy, Cl or Br, or R[sub 1] and R[sub 2] together form a fused 6-membered hydrocarbon aromatic ring, with the proviso that R[sub 1] and R[sub 2] are not t-butyl or t-butoxy; X is O, S or Se; n is 1--3; and the alkylene bridging group, optionally, is substituted by 1--3 methyl groups or by fluorine, form polybismaleimide resins which have valuable physical properties. Uniquely, these compounds permit extended cure times, i.e., they remain fluid for a time sufficient to permit the formation of a homogeneous melt prior to curing.

  15. Bismaleimide compounds

    DOE Patents [OSTI]

    Adams, Johnnie E. (Grandview, MO); Jamieson, Donald R. (Merriam, KS)

    1986-01-14T23:59:59.000Z

    Bismaleimides of the formula ##STR1## wherein R.sub.1 and R.sub.2 each independently is H, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, C1 or Br, or R.sub.1 and R.sub.2 together form a fused 6-membered hydrocarbon aromatic ring, with the proviso that R.sub.1 and R.sub.2 are not t-butyl or t-butoxy; X is O, S or Se; n is 1-3; and the alkylene bridging group, optionally, is substituted by 1-3 methyl groups or by fluorine, form polybismaleimide resins which have valuable physical properties. Uniquely, these compounds permit extended cure times, i.e., they remain fluid for a time sufficient to permit the formation of a homogeneous melt prior to curing.

  16. Experimental Study on Shear Fatigue Behavior and Stiffness Performance of Warm Mix Asphalt by adding Synthetic Wax

    E-Print Network [OSTI]

    Petit, Christophe; Canestrari, Francesco; Pannunzio, Valter; Virgili, Amadeo

    2012-01-01T23:59:59.000Z

    Synthetic waxes produced by standard and registered processes may be used to manufacture Warm Mix Asphalt (WMA), which is a modified asphalt concrete produced, applied and compacted at temperatures below those typically required. This feature leads to environmental benefits, such as reduced energy consumption, gas and fume emissions, as well as to economic/operational advantages, such as lower production costs and greater hauling distances for extended construction seasons with tighter schedules. The present article serves to compare the mechanical performance of a WMA produced by adding synthetic wax with a traditional Hot Mix Asphalt (HMA) specimen, in terms of shear fatigue response and both complex and stiffness moduli. The experimental results and related modeling work demonstrate that adding synthetic wax into the WMA composition does not hinder either the destructive or non-destructive performance of an HMA, and this finding is corroborated by respectively measuring fatigue life and stiffness.

  17. Experimental Study on Shear Fatigue Behavior and Stiffness Performance of Warm Mix Asphalt by adding Synthetic Wax

    E-Print Network [OSTI]

    Christophe Petit; Anne Millien; Francesco Canestrari; Valter Pannunzio; Amadeo Virgili

    2012-03-13T23:59:59.000Z

    Synthetic waxes produced by standard and registered processes may be used to manufacture Warm Mix Asphalt (WMA), which is a modified asphalt concrete produced, applied and compacted at temperatures below those typically required. This feature leads to environmental benefits, such as reduced energy consumption, gas and fume emissions, as well as to economic/operational advantages, such as lower production costs and greater hauling distances for extended construction seasons with tighter schedules. The present article serves to compare the mechanical performance of a WMA produced by adding synthetic wax with a traditional Hot Mix Asphalt (HMA) specimen, in terms of shear fatigue response and both complex and stiffness moduli. The experimental results and related modeling work demonstrate that adding synthetic wax into the WMA composition does not hinder either the destructive or non-destructive performance of an HMA, and this finding is corroborated by respectively measuring fatigue life and stiffness.

  18. Removal of Estrogenic Pollutants from Contaminated Water Using

    E-Print Network [OSTI]

    Chen, Wilfred

    Removal of Estrogenic Pollutants from Contaminated Water Using Molecularly Imprinted Polymers Z I H that this material may be appropriate for treating a complex mixture of estrogenic pollutants. The feasibility of removing estrogenic compounds from environmental water by the MIP was demonstrated using lake water spiked

  19. Establishing material properties for thin asphalt concrete surfaces on granular bases

    E-Print Network [OSTI]

    Rosson, Barry Thomas

    1985-01-01T23:59:59.000Z

    cross-section of a Goodyear Hi -Miler 10. 00-20 14-ply bias truck tire carcass was obtained; the input data for the Tielking tire model was developed by measuring cord locations, angles, and plies on a section of the tire; and the tire pressure.... Since little work in the past has been done in the area of thin asphalt concrete surface analysis, re-evaluation of several assumptions concerning the tire load were necessary. The truck tire pressures on Texas highways have dramatically increased...

  20. The Effects of Using Alkali-Silica Reaction Affected Recycled Concrete Aggregate in Hot Mix Asphalt

    E-Print Network [OSTI]

    Geiger, Brian James

    2011-10-21T23:59:59.000Z

    mix asphalt (HMA) were investigated in this study. Dilatometer and modified beam tests were performed to determine the possibility of new ASR occurring in reactive aggregates within the HMA or re-expansion of existing gel. The Lottman test... (XRD) was used to check for the potential presence of gel in the filler fraction of the ASR-RCAs. Micro-deval and freeze-thaw tests were evaluated for their potential to indicate the presence of excess micro-cracks or ASR gel. Expansion testing...

  1. Whole House Thermal Performance of Asphalt Shingles Exploiting Special Infrared Reflective Pigments

    E-Print Network [OSTI]

    Hahn, L.; Miller, W.; Desjarlais, A.; Jacobs, J.; Youngquist, A.

    2006-01-01T23:59:59.000Z

    -04 using cycle 4 as described in Table X2.1, Common Exposure Conditions, of the G 154 standard (ASTM 2002b). A UVB-340 lamp was used for simulating direct solar UV radiation; this lamp has no UV output below 300 nm, which is the cutoff wavelength... for this behavior is unknown; overall, however, the data clearly show that the IRR shingles perform just as well when subjected to direct solar UV radiation as standard products accepted on the open market. The IRR asphalt shingles do not lose solar reflectance...

  2. INTRODUCTION Asphalt is a mixture of a wide variety of chemical compounds that include aliphatic hydrocarbons and highly fused

    E-Print Network [OSTI]

    Harms, Kyle E.

    hydrocarbons and highly fused aromatic ring systems.They are classified as asphaltenes (medium molecular weight

  3. Particulate Matter Sampling and Volatile Organic Compound Removal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    being proposed to mitigate adverse human health and environmental impacts of internal combustion engines. With that in mind, it has been proposed that vehicular...

  4. Energy Saving System to Remove Volatile Organic Compounds (VOCs) from

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8, 2000Consumption Survey (CBECS) Data 210EnergyEnergy SaverSavingP

  5. Method for combined removal of mercury and nitrogen oxides from off-gas streams

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Downers Grove, IL); Livengood, C. David (Lockport, IL)

    2006-10-10T23:59:59.000Z

    A method for removing elemental Hg and nitric oxide simultaneously from a gas stream is provided whereby the gas stream is reacted with gaseous chlorinated compound to convert the elemental mercury to soluble mercury compounds and the nitric oxide to nitrogen dioxide. The method works to remove either mercury or nitrogen oxide in the absence or presence of each other.

  6. Method for the removal of elemental mercury from a gas stream

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Downers Grove, IL); Huang, Hann-Sheng (Darien, IL)

    1999-01-01T23:59:59.000Z

    A method is provided to remove elemental mercury from a gas stream by reacting the gas stream with an oxidizing solution to convert the elemental mercury to soluble mercury compounds. Other constituents are also oxidized. The gas stream is then passed through a wet scrubber to remove the mercuric compounds and oxidized constituents.

  7. Method for the removal of elemental mercury from a gas stream

    DOE Patents [OSTI]

    Mendelsohn, M.H.; Huang, H.S.

    1999-05-04T23:59:59.000Z

    A method is provided to remove elemental mercury from a gas stream by reacting the gas stream with an oxidizing solution to convert the elemental mercury to soluble mercury compounds. Other constituents are also oxidized. The gas stream is then passed through a wet scrubber to remove the mercuric compounds and oxidized constituents. 7 figs.

  8. Porous Asphalt Pavement for Stormwater Management The UNH Stormwater Center Web: www.unh.edu/erg/cstev/

    E-Print Network [OSTI]

    Porous Asphalt Pavement for Stormwater Management The UNH Stormwater Center Web: www. Extended Pavement Life Due to Well Drained Base and Reduced Freeze-Thaw Disadvantages · Requires Routine. Standard Pavement Applications where Stormwater Infrastructure is Required · Materials Cost is ~20-25% More

  9. SOURCE: UNIVERSITY OF CALIFORNIA PAVEMENT RESEARCH CENTER FIGURE 1 Moisture-induced stripping in asphalt treated base layer

    E-Print Network [OSTI]

    California at Berkeley, University of

    SOURCE: UNIVERSITY OF CALIFORNIA PAVEMENT RESEARCH CENTER FIGURE 1 Moisture-induced stripping in asphalt treated base layer PAVEMENT TECHNOLOGY UPDATE This Technology Transfer Program publication is provided by the University of California Pavement Research Center. The University of California Pavement

  10. Recycling spent sandblasting grit and similar wastes as aggregate in asphaltic concrete. Technical data sheet

    SciTech Connect (OSTI)

    Heath, J.C.; Nelson, B.

    1998-12-01T23:59:59.000Z

    The Naval Facilities Engineering Service Center (NFESC), Port Hueneme, California, and Naval Facilities Engineering Command Engineering Field Activity, West, San Bruno, California, took overall leadership in identifying and testing methods to manage waste generated from a machine shop located at Hunters Point Annex, at Naval Station, Treasure Island, California. Ship cleaning and equipment maintenance resulted in the accumulation of 4,665 tons of spent sandblasting grit at the site. The spent grit, consisting of silica sand plus a small amount of slag-derived grit, had the physical characteristics of coarse-grained beach sand and also contained fragments of coatings. The spent grit had the potential for exhibiting hazardous characteristics since the coatings included lead-based primers, copper, and butyltin-containing antifouling topcoats. The most beneficial application of reusing the spent grit was to use it as a replacement for some of the fine aggregate in asphaltic concrete. A test program was established that included characterization, bench-scale testing, long-term pilot scale testing, and a full-scale demonstration. Full-scale asphalt production provided samples which proved both the chemical leaching resistance and physical performance characteristics were acceptable.

  11. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

    1993-01-01T23:59:59.000Z

    Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70.degree. C. and 500.degree. C. and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

  12. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1993-01-05T23:59:59.000Z

    Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70 C and 500 C and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

  13. Silica Scaling Removal Process

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sidestreams of cooling tower water by providing a substrate for the deposition and adsorption of silica. The removal of the silica prevents scaling deposition on heat transfer...

  14. Two- and Three-Dimensional Microstructural Modeling of Asphalt Particulate Composite Materials using a Unified Viscoelastic-Viscoplastic-Viscodamage Constitutive Model

    E-Print Network [OSTI]

    You, Taesun

    2013-08-13T23:59:59.000Z

    The main objective of this study is to develop and validate a framework for microstructural modeling of asphalt composite materials using a coupled thermo-viscoelastic, thermo-viscoplastic, and thermo-viscodamage constitutive model. In addition...

  15. Molecular characterization of vanadyl and nickel non-porphyrin compounds in heavy crude petroleums and residua

    SciTech Connect (OSTI)

    Reynolds, J.G.; Biggs, W.R.; Fetzer, J.C.; Gallegos, E.J.; Fish, R.H.; Komlenic, J.J.; Wines, B.K.

    1984-01-01T23:59:59.000Z

    The molecular characterization of vanadium and nickel compounds in heavy crude petroleums has been the subject of current research. Arabian Heavy, Maya, Boscan, Cerro Negro, Prudhoe Bay, Wilmington Beta, Kern River, and Morichal crude petroleums have been examined. Fractions from D 2007 separations, porphyrin extractions, and solvent selective extraction with reversed phase column separations of these petroleums have been studied thoroughly by EPR. Important structural aspects are emerging from the presented data: (1) There are non-porphyrin metal complexes in the crude petroleums. (2) They appear to be smaller molecules with MW < 400 which are liberated when the tertiary structure of the large asphaltics is denatured. (3) The first coordination spheres of this class of compounds are possibly 4N, N O 2S, and 4S. 10 references, 3 figures, 1 table.

  16. Use of shredded tires in the subbase layer of asphalt pavements

    SciTech Connect (OSTI)

    Papp, W.J. Jr.; Maher, M.H. [Rutgers Univ., Piscataway, NJ (United States). Dept. of Civil and Environmental Engineering; Baker, R.F. [New Jersey Dept. of Transportation, Trenton, NJ (United States)

    1997-12-31T23:59:59.000Z

    Research was conducted on the use of shredded scrap tires for use in the subbase layer of asphalt pavements. Mixtures of shredded scrap tires with virgin soil provide a means of recycling unwanted tires and conserving a finite supply of virgin soil. The mechanistic procedure for the design of pavement systems requires resilient modulus values. Plastic and elastic strains were measured using external LVDT`s and internal proximity sensors. Resilient modulus measurements were conducted on cohesionless soils mixed with various amounts of shredded tire chips. The performance f the shredded tire mixture is compared to that of the naturally occurring virgin soil used in subbase applications in New Jersey. A number of experimental issues are discussed such as: method of compaction, optimum ratio of shredded tire chips to soil, optimum size and gradation of shredded tire chips, and strength testing using California Bearing Ratio.

  17. Reactor for removing ammonia

    DOE Patents [OSTI]

    Luo, Weifang (Livermore, CA); Stewart, Kenneth D. (Valley Springs, CA)

    2009-11-17T23:59:59.000Z

    Disclosed is a device for removing trace amounts of ammonia from a stream of gas, particularly hydrogen gas, prepared by a reformation apparatus. The apparatus is used to prevent PEM "poisoning" in a fuel cell receiving the incoming hydrogen stream.

  18. Continuous sulfur removal process

    DOE Patents [OSTI]

    Jalan, V.; Ryu, J.

    1994-04-26T23:59:59.000Z

    A continuous process for the removal of hydrogen sulfide from a gas stream using a membrane comprising a metal oxide deposited on a porous support is disclosed. 4 figures.

  19. Recycled brake linings as partial aggregate substitute in asphalt paving. Construction and final report. Report for July 1992-August 1996

    SciTech Connect (OSTI)

    Miller, P.A.; Sukley, R.

    1996-09-01T23:59:59.000Z

    The purpose of this project was to evaluate the performance of asphalt containing various percentages of brake lining as an aggregate, and compare its performance to that of normal asphalt containing natural aggregate. This project is an effort to explore alternate ways to use waste product. Four test section of FB-2 Modified mix containing brake lining materials were placed in July 1992 along with one control section on SR 3022 in Mercer county. To date all sections are performing satisfactory, and Brake linings should be recommended as a viable partial replacement of aggregate in bituminous materials. This study only considered the performance of only off-spec brake linings, therefore, any performance data or enviromental effects of placement of used brake material should be addressed.

  20. Solid materials for removing arsenic and method thereof

    SciTech Connect (OSTI)

    Coronado, Paul R. (Livermore, CA); Coleman, Sabre J. (Oakland, CA); Sanner, Robert D. (Livermore, CA); Dias, Victoria L. (Livermore, CA); Reynolds, John G. (San Ramon, CA)

    2010-09-28T23:59:59.000Z

    Solid materials have been developed to remove arsenic compounds from aqueous media. The arsenic is removed by passing the aqueous phase through the solid materials which can be in molded, granular, or powder form. The solid materials adsorb the arsenic leaving a purified aqueous stream. The materials are aerogels or xerogels and aerogels or xerogels and solid support structure, e.g., granulated activated carbon (GAC), mixtures. The species-specific adsorption occurs through specific chemical modifications of the solids tailored towards arsenic.

  1. Solid materials for removing arsenic and method thereof

    DOE Patents [OSTI]

    Coronado, Paul R. (Livermore, CA); Coleman, Sabre J. (Oakland, CA); Sanner, Robert D. (Livermore, CA); Dias, Victoria L. (Livermore, CA); Reynolds, John G. (San Ramon, CA)

    2008-07-01T23:59:59.000Z

    Solid materials have been developed to remove arsenic compounds from aqueous media. The arsenic is removed by passing the aqueous phase through the solid materials which can be in molded, granular, or powder form. The solid materials adsorb the arsenic leaving a purified aqueous stream. The materials are aerogels or xerogels and aerogels or xerogels and solid support structure, e.g., granulated activated carbon (GAC), mixtures. The species-specific adsorption occurs through specific chemical modifications of the solids tailored towards arsenic.

  2. Electrochemical assessment and service-life prediction of mechanically stabilized earth walls backfilled with crushed concrete and recycled asphalt pavement

    E-Print Network [OSTI]

    Esfeller, Michael Watts, Jr.

    2009-06-02T23:59:59.000Z

    Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August 2006 Major Subject: Civil Engineering ELECTROCHEMICAL ASSESSMENT AND SERVICE-LIFE PREDICTION... OF MECHANICALLY STABILIZED EARTH WALLS BACKFILLED WITH CRUSHED CONCRETE AND RECYCLED ASPHALT PAVEMENT A Thesis by MICHAEL WATTS ESFELLER, JR. Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

  3. Elements & Compounds Atoms (Elements)

    E-Print Network [OSTI]

    Frey, Terry

    #12;Elements & Compounds #12;Atoms (Elements) Molecules (Compounds) Cells Elements & Compounds #12 #12;First shell Second shell Third shell Hydrogen 1H Lithium 3Li Sodium 11Na Beryllium 4Be Magnesium energy Higher energy (a) A ball bouncing down a flight of stairs provides an analogy for energy levels

  4. Solid materials for removing metals and fabrication method

    DOE Patents [OSTI]

    Coronado, Paul R.; Reynolds, John G.; Coleman, Sabre J.

    2004-10-19T23:59:59.000Z

    Solid materials have been developed to remove contaminating metals and organic compounds from aqueous media. The contaminants are removed by passing the aqueous phase through the solid materials which can be in molded, granular, or powder form. The solid materials adsorb the metals and the organics leaving a purified aqueous stream. The materials are sol-gel and or sol-gel and granulated activated carbon (GAC) mixtures. The species-specific adsorption occurs through specific chemical modifications of the solids tailored towards the contaminant(s). The contaminated solid materials can then be disposed of or the contaminant can be removed and the solids recycled.

  5. Arsenic removal from water

    DOE Patents [OSTI]

    Moore, Robert C. (Edgewood, NM); Anderson, D. Richard (Albuquerque, NM)

    2007-07-24T23:59:59.000Z

    Methods for removing arsenic from water by addition of inexpensive and commonly available magnesium oxide, magnesium hydroxide, calcium oxide, or calcium hydroxide to the water. The hydroxide has a strong chemical affinity for arsenic and rapidly adsorbs arsenic, even in the presence of carbonate in the water. Simple and commercially available mechanical methods for removal of magnesium hydroxide particles with adsorbed arsenic from drinking water can be used, including filtration, dissolved air flotation, vortex separation, or centrifugal separation. A method for continuous removal of arsenic from water is provided. Also provided is a method for concentrating arsenic in a water sample to facilitate quantification of arsenic, by means of magnesium or calcium hydroxide adsorption.

  6. Drum lid removal tool

    DOE Patents [OSTI]

    Pella, Bernard M. (Martinez, GA); Smith, Philip D. (North Augusta, SC)

    2010-08-24T23:59:59.000Z

    A tool for removing the lid of a metal drum wherein the lid is clamped over the drum rim without protruding edges, the tool having an elongated handle with a blade carried by an angularly positioned holder affixed to the midsection of the handle, the blade being of selected width to slice between lid lip and the drum rim and, when the blade is so positioned, upward motion of the blade handle will cause the blade to pry the lip from the rim and allow the lid to be removed.

  7. Removable feedwater sparger assembly

    DOE Patents [OSTI]

    Challberg, R.C.

    1994-10-04T23:59:59.000Z

    A removable feedwater sparger assembly includes a sparger having an inlet pipe disposed in flow communication with the outlet end of a supply pipe. A tubular coupling includes an annular band fixedly joined to the sparger inlet pipe and a plurality of fingers extending from the band which are removably joined to a retention flange extending from the supply pipe for maintaining the sparger inlet pipe in flow communication with the supply pipe. The fingers are elastically deflectable for allowing engagement of the sparger inlet pipe with the supply pipe and for disengagement therewith. 8 figs.

  8. Electric Turbo Compounding Technology Update

    Broader source: Energy.gov (indexed) [DOE]

    Turbo Compounding Technology Update Electric Turbo Compounding Technology Update 15 August, 2007 Carl Vuk 15 August, 2007 Carl Vuk Electric Turbo Compounding Highlights Electric...

  9. Process for preparing a chemical compound enriched in isotope content

    DOE Patents [OSTI]

    Michaels, Edward D. (Spring Valley, OH)

    1982-01-01T23:59:59.000Z

    A process to prepare a chemical enriched in isotope content which includes: (a) A chemical exchange reaction between a first and second compound which yields an isotopically enriched first compound and an isotopically depleted second compound; (b) the removal of a portion of the first compound as product and the removal of a portion of the second compound as spent material; (c) the conversion of the remainder of the first compound to the second compound for reflux at the product end of the chemical exchange reaction region; (d) the conversion of the remainder of the second compound to the first compound for reflux at the spent material end of the chemical exchange region; and the cycling of the additional chemicals produced by one conversion reaction to the other conversion reaction, for consumption therein. One of the conversion reactions is an oxidation reaction, and the energy that it yields is used to drive the other conversion reaction, a reduction. The reduction reaction is carried out in a solid polymer electrolyte electrolytic reactor. The overall process is energy efficient and yields no waste by-products.

  10. Adsorption -capacity data for 283 organic compounds

    SciTech Connect (OSTI)

    Yaws, C.L.; Bu, L.; Nijhawan, S. [Lamar Univ., Beaumont, TX (United States)

    1995-05-01T23:59:59.000Z

    Adsorption on activated carbon is a widely used method for removing volatile organic compounds (VOCs) from gases and other exhaust streams. This article presents a compilation of adsorption-capacity data as a function of the VOC concentration in the gas. The results are useful in engineering and environmental studies, and in the design of carbon-based adsorption systems to remove unwanted organic pollutants from gases. For vapor control, carbon-based systems typically combine a carbon-adsorption unit with a secondary control method to reclaim or destroy the vapors desorbed during carbon-bed regeneration. To remove organics dissolved in wastewater, air stripping is typically used to transfer the organics to a vapor stream. Carbon adsorption is then used to separate the organics from the stripper exhaust. Collected vapors can be recovered for reuse or destroyed, depending on their value.

  11. Condensate removal device

    DOE Patents [OSTI]

    Maddox, James W. (Newport News, VA); Berger, David D. (Alexandria, VA)

    1984-01-01T23:59:59.000Z

    A condensate removal device is disclosed which incorporates a strainer in unit with an orifice. The strainer is cylindrical with its longitudinal axis transverse to that of the vapor conduit in which it is mounted. The orifice is positioned inside the strainer proximate the end which is remoter from the vapor conduit.

  12. IMPROVED PROCESSES TO REMOVE NAPHTHENIC ACIDS

    SciTech Connect (OSTI)

    Aihua Zhang; Qisheng Ma; William A. Goddard; Yongchun Tang

    2004-04-28T23:59:59.000Z

    In the first year of this project, we have established our experimental and theoretical methodologies for studies of the catalytic decarboxylation process. We have developed both glass and stainless steel micro batch type reactors for the fast screening of various catalysts with reaction substrates of model carboxylic acid compounds and crude oil samples. We also developed novel product analysis methods such as GC analyses for organic acids and gaseous products; and TAN measurements for crude oil. Our research revealed the effectiveness of several solid catalysts such as NA-Cat-1 and NA-Cat-2 for the catalytic decarboxylation of model compounds; and NA-Cat-5{approx}NA-Cat-9 for the acid removal from crude oil. Our theoretical calculations propose a three-step concerted oxidative decarboxylation mechanism for the NA-Cat-1 catalyst.

  13. Value-added utilisation of recycled concrete in hot-mix asphalt

    SciTech Connect (OSTI)

    Wong, Yiik Diew [School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore); Sun, Darren Delai [School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)]. E-mail: ddsun@ntu.edu.sg; Lai, Dickson [School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798 (Singapore)

    2007-07-01T23:59:59.000Z

    The feasibility of partial substitution of granite aggregate in hot-mix asphalt (HMA) with waste concrete aggregate was investigated. Three hybrid HMA mixes incorporating substitutions of granite fillers/fines with 6%, 45% untreated, and 45% heat-treated concrete were evaluated by the Marshall mix design method; the optimum binder contents were found to be 5.3%, 6.5% and 7.0% of grade Pen 60/70 bitumen, respectively. All three hybrid mixes satisfied the Marshall criteria of the Singapore Land Transport Authority (LTA) W3B wearing course specification. The hybrid mix with 6% concrete fillers gave comparable resilient modulus and creep resistance as the conventional W3B mix, while hybrid mixes with higher concrete substitutions achieved better performance. X-ray diffraction (XRD) showed the distinct presence of free lime in the heat-treated concrete, while the scanning electron microscope (SEM) provided an in-depth perspective of the concrete grains in the HMA matrix. The results suggest feasible use of waste concrete as partial aggregate substitution in HMA.

  14. XAFS Model Compound Library

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Newville, Matthew

    The XAFS Model Compound Library contains XAFS data on model compounds. The term "model" compounds refers to compounds of homogeneous and well-known crystallographic or molecular structure. Each data file in this library has an associated atoms.inp file that can be converted to a feff.inp file using the program ATOMS. (See the related Searchable Atoms.inp Archive at http://cars9.uchicago.edu/~newville/adb/) This Library exists because XAFS data on model compounds is useful for several reasons, including comparing to unknown data for "fingerprinting" and testing calculations and analysis methods. The collection here is currently limited, but is growing. The focus to date has been on inorganic compounds and minerals of interest to the geochemical community. [Copied, with editing, from http://cars9.uchicago.edu/~newville/ModelLib/

  15. Metal chelate process to remove pollutants from fluids

    DOE Patents [OSTI]

    Chang, S.G.T.

    1994-12-06T23:59:59.000Z

    The present invention relates to improved methods using an organic iron chelate to remove pollutants from fluids, such as flue gas. Specifically, the present invention relates to a process to remove NO[sub x] and optionally SO[sub 2] from a fluid using a metal ion (Fe[sup 2+]) chelate wherein the ligand is a dimercapto compound wherein the --SH groups are attached to adjacent carbon atoms (HS--C--C--SH) or (SH--C--CCSH) and contain a polar functional group so that the ligand of DMC chelate is water soluble. Alternatively, the DMC is covalently attached to a water insoluble substrate such as a polymer or resin, e.g., polystyrene. The chelate is regenerated using electroreduction or a chemical additive. The dimercapto compound bonded to a water insoluble substrate is also useful to lower the concentration or remove hazardous metal ions from an aqueous solution. 26 figures.

  16. Preparation of uranium compounds

    DOE Patents [OSTI]

    Kiplinger, Jaqueline L; Montreal, Marisa J; Thomson, Robert K; Cantat, Thibault; Travia, Nicholas E

    2013-02-19T23:59:59.000Z

    UI.sub.3(1,4-dioxane).sub.1.5 and UI.sub.4(1,4-dioxane).sub.2, were synthesized in high yield by reacting turnings of elemental uranium with iodine dissolved in 1,4-dioxane under mild conditions. These molecular compounds of uranium are thermally stable and excellent precursor materials for synthesizing other molecular compounds of uranium including alkoxide, amide, organometallic, and halide compounds.

  17. Partially fluorinated ionic compounds

    DOE Patents [OSTI]

    Han, legal representative, Amy Qi (Hockessin, DE); Yang, Zhen-Yu (Hockessin, DE)

    2008-11-25T23:59:59.000Z

    Partially fluorinated ionic compounds are prepared. They are useful in the preparation of partially fluorinated dienes, in which the repeat units are cycloaliphatic.

  18. Astatinated organic compounds

    DOE Patents [OSTI]

    Milius, R.A.; Lambrecht, R.M.; Bloomer, W.D.

    1989-05-02T23:59:59.000Z

    Methods and kits for incorporating a radioactive astatine isotope (particularly [sup 211]At) into an organic compound by electrophilic astatodestannylation of organostannanes. 3 figs.

  19. Pneumatic soil removal tool

    DOE Patents [OSTI]

    Neuhaus, J.E.

    1992-10-13T23:59:59.000Z

    A soil removal tool is provided for removing radioactive soil, rock and other debris from the bottom of an excavation, while permitting the operator to be located outside of a containment for that excavation. The tool includes a fixed jaw, secured to one end of an elongate pipe, which cooperates with a movable jaw pivotably mounted on the pipe. Movement of the movable jaw is controlled by a pneumatic cylinder mounted on the pipe. The actuator rod of the pneumatic cylinder is connected to a collar which is slidably mounted on the pipe and forms part of the pivotable mounting assembly for the movable jaw. Air is supplied to the pneumatic cylinder through a handle connected to the pipe, under the control of an actuator valve mounted on the handle, to provide movement of the movable jaw. 3 figs.

  20. Pneumatic soil removal tool

    DOE Patents [OSTI]

    Neuhaus, John E. (Newport News, VA)

    1992-01-01T23:59:59.000Z

    A soil removal tool is provided for removing radioactive soil, rock and other debris from the bottom of an excavation, while permitting the operator to be located outside of a containment for that excavation. The tool includes a fixed jaw, secured to one end of an elongate pipe, which cooperates with a movable jaw pivotably mounted on the pipe. Movement of the movable jaw is controlled by a pneumatic cylinder mounted on the pipe. The actuator rod of the pneumatic cylinder is connected to a collar which is slidably mounted on the pipe and forms part of the pivotable mounting assembly for the movable jaw. Air is supplied to the pneumatic cylinder through a handle connected to the pipe, under the control of an actuator valve mounted on the handle, to provide movement of the movable jaw.

  1. KKG Group Paraffin Removal

    SciTech Connect (OSTI)

    Schulte, Ralph

    2001-12-01T23:59:59.000Z

    The Rocky Mountain Oilfield Testing Center (RMOTC) has recently completed a test of a paraffin removal system developed by the KKG Group utilizing the technology of two Russian scientists, Gennady Katzyn and Boris Koggi. The system consisting of chemical ''sticks'' that generate heat in-situ to melt the paraffin deposits in oilfield tubing. The melted paraffin is then brought to the surface utilizing the naturally flowing energy of the well.

  2. A study of substitution solvents in asphalt fume extraction and the effects of heating duration and temperature

    E-Print Network [OSTI]

    Curry, Noel Thomas

    1981-01-01T23:59:59.000Z

    (denoted Dl). Duration two ( D2) ran from time 60 minutes to time 90 minutes, Dl and DZ were separated by a 30 minute period in wh i ch no sampling occurred. The total time of heati ng at this temperature range was 90 minutes, which was near the limit... of the filter to hold it in position, and the cassette cap was placed on top of this. 3oth ends were then plugged. (Figure 2) After a warming period of approximately 30 minutes, the temperature of the liquid asphalt was raised to 250 C. iihen it reached...

  3. A novel technique for the production of cool colored concrete tile and asphalt shingle roofing products

    SciTech Connect (OSTI)

    Levinson, Ronnen; Akbari, Hashem; Berdahl, Paul; Wood, Kurt; Skilton, Wayne; Petersheim, Jerry

    2009-11-20T23:59:59.000Z

    The widespread use of solar-reflective roofing materials can save energy, mitigate urban heat islands and slow global warming by cooling the roughly 20% of the urban surface that is roofed. In this study we created prototype solar-reflective nonwhite concrete tile and asphalt shingle roofing materials using a two-layer spray coating process intended to maximize both solar reflectance and factory-line throughput. Each layer is a thin, quick-drying, pigmented latex paint based on either acrylic or a poly(vinylidene fluoride)/acrylic blend. The first layer is a titanium dioxide rutile white basecoat that increases the solar reflectance of a gray-cement concrete tile from 0.18 to 0.79, and that of a shingle surfaced with bare granules from 0.06 to 0.62. The second layer is a 'cool' color topcoat with weak near-infrared (NIR) absorption and/or strong NIR backscattering. Each layer dries within seconds, potentially allowing a factory line to pass first under the white spray, then under the color spray. We combined a white basecoat with monocolor topcoats in various shades of red, brown, green and blue to prepare 24 cool color prototype tiles and 24 cool color prototypes shingles. The solar reflectances of the tiles ranged from 0.26 (dark brown; CIELAB lightness value L* = 29) to 0.57 (light green; L* = 76); those of the shingles ranged from 0.18 (dark brown; L* = 26) to 0.34 (light green; L* = 68). Over half of the tiles had a solar reflectance of at least 0.40, and over half of the shingles had a solar reflectance of at least 0.25.

  4. Asphaltenes and Asphalts, 2. Developments in Petroleum Science, 40 B edited by T.F. Yen and G.V. Chilingarian

    E-Print Network [OSTI]

    Ã?agin, Tahir

    Asphaltenes and Asphalts, 2. Developments in Petroleum Science, 40 B edited by T.F. Yen and G OF ASPHALTENES: A PREDICTIVE APPROACH BASED ON COMPUTER ASSISTED STRUCTURE ELUCIDATION AND ATOMISTIC SIMULATIONS, asphaltenes and resins [1­4]. Asphaltenes are operationally defined as the non-volatile and polar fraction

  5. Heart testing compound

    DOE Patents [OSTI]

    Knapp, F.F. Jr.; Goodman, M.M.

    1983-06-29T23:59:59.000Z

    The compound 15-(p-(/sup 125/I)-iodophenyl)-6-tellurapentadecanoic acid is disclosed as a myocardial imaging agent having rapid and pronounced uptake, prolonged myocardial retention, and low in vivo deiodination.

  6. Heart testing compound

    DOE Patents [OSTI]

    Knapp, Jr., Furn F. (Oak Ridge, TN); Goodman, Mark M. (Knoxville, TN)

    1985-01-01T23:59:59.000Z

    The compound 15-(p-[.sup.125 I]-iodophenyl)-6-tellurapentadecanoic acid is disclosed as a myocardial imaging agent having rapid and pronounced uptake, prolonged myocardial retention, and low in vivo deiodination.

  7. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOE Patents [OSTI]

    Baker, E.G.; Elliott, D.C.

    1993-01-19T23:59:59.000Z

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compounds as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  8. Health and safety plan for the removal action at the former YS-860 Firing Ranges, Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    NONE

    1998-04-28T23:59:59.000Z

    This health and safety plan sets forth the requirements and procedures to protect the personnel involved in the Lead Source Removal Project at the Former YS-86O Firing Ranges. This project will be conducted in a manner that ensures the protection of the safety and health of workers, the public, and the environment. The purpose of this removal action is to address lead contaminated soil and reduce a potential risk to human health and the environment. This site is an operable unit within the Upper East Fork Poplar Creek watershed. The removal action will contribute to early source actions within the watershed. The project will accomplish this through the removal of lead-contaminated soil in the target areas of the two small arms firing ranges. This plan covers the removal actions at the Former YS-86O Firing Ranges. These actions involve the excavation of lead-contaminated soils, the removal of the concrete trench and macadam (asphalt) paths, verification/confirmation sampling, grading and revegetation. The primary hazards include temperature extremes, equipment operation, noise, potential lead exposure, uneven and slippery working surfaces, and insects.

  9. Geothermal hydrogen sulfide removal

    SciTech Connect (OSTI)

    Urban, P.

    1981-04-01T23:59:59.000Z

    UOP Sulfox technology successfully removed 500 ppM hydrogen sulfide from simulated mixed phase geothermal waters. The Sulfox process involves air oxidation of hydrogen sulfide using a fixed catalyst bed. The catalyst activity remained stable throughout the life of the program. The product stream composition was selected by controlling pH; low pH favored elemental sulfur, while high pH favored water soluble sulfate and thiosulfate. Operation with liquid water present assured full catalytic activity. Dissolved salts reduced catalyst activity somewhat. Application of Sulfox technology to geothermal waters resulted in a straightforward process. There were no requirements for auxiliary processes such as a chemical plant. Application of the process to various types of geothermal waters is discussed and plans for a field test pilot plant and a schedule for commercialization are outlined.

  10. Rubber stopper remover

    DOE Patents [OSTI]

    Stitt, Robert R. (Arvada, CO)

    1994-01-01T23:59:59.000Z

    A device for removing a rubber stopper from a test tube is mountable to an upright wall, has a generally horizontal splash guard, and a lower plate spaced parallel to and below the splash guard. A slot in the lower plate has spaced-apart opposing edges that converge towards each other from the plate outer edge to a narrowed portion, the opposing edges shaped to make engagement between the bottom of the stopper flange and the top edge of the test tube to wedge therebetween and to grasp the stopper in the slot narrowed portion to hold the stopper as the test tube is manipulated downwardly and pulled from the stopper. The opposing edges extend inwardly to adjoin an opening having a diameter significantly larger than that of the stopper flange.

  11. Structural Characterization of Micromechanical Properties in Asphalt Using Atomic Force Microscopy

    E-Print Network [OSTI]

    Allen, Robert Grover

    2012-02-14T23:59:59.000Z

    -nuclear aromatics and hetero-aromatic molecules (asphaltenes), viscous naphtheno-aromatic hydrocarbons (heavy oils) and heterocyclic and polar compounds (resins). The initial relative amount and arrangement of 9 asphaltenes, resins and oils are highly... between the PDM morphology and the colloidal system where the asphaltenes are stabilized by polar aromatics in a sea of naphthene aromatics and saturated compounds. This does not necessarily invalidate the model but suggests that it is possibly too...

  12. Stable surface passivation process for compound semiconductors

    DOE Patents [OSTI]

    Ashby, Carol I. H. (Edgewood, NM)

    2001-01-01T23:59:59.000Z

    A passivation process for a previously sulfided, selenided or tellurated III-V compound semiconductor surface. The concentration of undesired mid-gap surface states on a compound semiconductor surface is reduced by the formation of a near-monolayer of metal-(sulfur and/or selenium and/or tellurium)-semiconductor that is effective for long term passivation of the underlying semiconductor surface. Starting with the III-V compound semiconductor surface, any oxidation present thereon is substantially removed and the surface is then treated with sulfur, selenium or tellurium to form a near-monolayer of chalcogen-semiconductor of the surface in an oxygen-free atmosphere. This chalcogenated surface is then contacted with a solution of a metal that will form a low solubility chalcogenide to form a near-monolayer of metal-chalcogen-semiconductor. The resulting passivating layer provides long term protection for the underlying surface at or above the level achieved by a freshly chalcogenated compound semiconductor surface in an oxygen free atmosphere.

  13. Removing Arsenic from Drinking Water

    ScienceCinema (OSTI)

    None

    2013-05-28T23:59:59.000Z

    See how INL scientists are using nanotechnology to remove arsenic from drinking water. For more INL research, visit http://www.facebook.com/idahonationallaboratory

  14. Microoptical compound lens

    DOE Patents [OSTI]

    Sweatt, William C. (Albuquerque, NM); Gill, David D. (Albuquerque, NM)

    2007-10-23T23:59:59.000Z

    An apposition microoptical compound lens comprises a plurality of lenslets arrayed around a segment of a hollow, three-dimensional optical shell. The lenslets collect light from an object and focus the light rays onto the concentric, curved front surface of a coherent fiber bundle. The fiber bundle transports the light rays to a planar detector, forming a plurality of sub-images that can be reconstructed as a full image. The microoptical compound lens can have a small size (millimeters), wide field of view (up to 180.degree.), and adequate resolution for object recognition and tracking.

  15. Aminopropyl thiophene compounds

    DOE Patents [OSTI]

    Goodman, Mark M. (Knoxville, TN); Knapp, Jr., Furn F. (Oak Ridge, TN)

    1990-01-01T23:59:59.000Z

    Radiopharmaceuticals useful in brain imaging comprising radiohalogenated thienylethylamine derivatives. The compounds are 5-halo-thiophene-2-isopropyl amines able to cross the blood-brain barrier and be retained for a sufficient length of time to allow the evaluation of regional blood flow by radioimaging of the brain.

  16. Tailoring hydrocarbon streams for asphaltene removal

    SciTech Connect (OSTI)

    Del Bianco, A.; Stroppa, F.; Bertero, L.

    1995-11-01T23:59:59.000Z

    Oilfield production is often hindered by asphaltene precipitation which tends to fill the pores of the reservoir rocks and plug the wellbore tubing as well as the other auxiliary equipment used during crude oil recovery. Several remedies to remove these deposits have been proposed and patented but the injection of aromatic solvents such as toluene and light petroleum distillates is normally preferred. Previous studies with a number of pure aromatic hydrocarbons have shown that the solvent capacity of these molecules may be very different and that the degree of condensation plays an important role. In this regard, tetralins and naphthalenes are superior to alkylbenzenes. However, because the use of pure compounds is not economically feasible, the authors examined various industrial streams and the authors correlated their chemical composition to the solvent capacity. This work allowed the identification of the pseudo-components whose relative concentration is crucial for evaluating the solvent performances. Based on these data, the authors were able to find new products with ideal characteristics. The efficiency of one of these products was confirmed by the analysis of the data obtained when using this new solvent to remove asphaltene in damaged wells of an Italian field.

  17. Utilize Cementitious High Carbon Fly Ash (CHCFA) to Stabilize Cold In-Place Recycled (CIR) Asphalt Pavement as Base Coarse

    SciTech Connect (OSTI)

    Wen, Haifang; Li, Xiaojun; Edil, Tuncer; O'Donnell, Jonathan; Danda, Swapna

    2011-02-05T23:59:59.000Z

    The purpose of this study was to evaluate the performance of cementitious high carbon fly ash (CHCFA) stabilized recycled asphalt pavement as a base course material in a real world setting. Three test road cells were built at MnROAD facility in Minnesota. These cells have the same asphalt surface layers, subbases, and subgrades, but three different base courses: conventional crushed aggregates, untreated recycled pavement materials (RPM), and CHCFA stabilized RPM materials. During and after the construction of the three cells, laboratory and field tests were carried out to characterize the material properties. The test results were used in the mechanistic-empirical pavement design guide (MEPDG) to predict the pavement performance. Based on the performance prediction, the life cycle analyses of cost, energy consumption, and greenhouse gasses were performed. The leaching impacts of these three types of base materials were compared. The laboratory and field tests showed that fly ash stabilized RPM had higher modulus than crushed aggregate and RPM did. Based on the MEPDG performance prediction, the service life of the Cell 79 containing fly ash stabilized RPM, is 23.5 years, which is about twice the service life (11 years) of the Cell 77 with RPM base, and about three times the service life (7.5 years) of the Cell 78 with crushed aggregate base. The life cycle analysis indicated that the usage of the fly ash stabilized RPM as the base of the flexible pavement can significantly reduce the life cycle cost, the energy consumption, the greenhouse gases emission. Concentrations of many trace elements, particularly those with relatively low water quality standards, diminish over time as water flows through the pavement profile. For many elements, concentrations below US water drinking water quality standards are attained at the bottom of the pavement profile within 2-4 pore volumes of flow.

  18. Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline

    DOE Patents [OSTI]

    Baker, Eddie G. (Richland, WA); Elliott, Douglas C. (Richland, WA)

    1993-01-01T23:59:59.000Z

    The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compouns as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

  19. Rutting Performance of Airport Hot-Mix Asphalt Characterized by Laboratory Performance Testing, Full-Scale Accelerated Pavement Testing, and Finite Element Modeling

    E-Print Network [OSTI]

    Rushing, John Ford

    2014-04-25T23:59:59.000Z

    California Bearing Ratio DoD Department of Defense DSR Dynamic Shear Rheometer ERDC U.S. Army Engineer Research and Development Center FAA Federal Aviation Administration FN flow number FT flow time HMA Hot Mix Asphalt HVS heavy vehicle simulator... aircraft continue to necessitate modifications in the procedures by which HMA mixtures are designed so that rutting does not become a prevalent distress on airport pavements. The Federal Aviation Administration (FAA) has predominantly required use...

  20. Multipollutant Removal with WOWClean® System 

    E-Print Network [OSTI]

    Romero, M.

    2010-01-01T23:59:59.000Z

    from the flue gas of a power plant and demonstrate the technology. The system integrates proven emission reduction techniques into a single, multi-pollutant reduction system and is designed to remove Mercury, SOx, NOx, particulates, heavy metals...

  1. Complex Compound Chemical Heat Pumps 

    E-Print Network [OSTI]

    Rockenfeller, U.; Langeliers, J.; Horn, G.

    1987-01-01T23:59:59.000Z

    Complex-compound solid-vapor fluid pairs can be used in heat of reaction heat pumps for temperature amplifier (TA) as well as heat amplifier (HA) cycle configurations. This report describes the conceptual hardware design for complex compound...

  2. Complex Compound Chemical Heat Pumps

    E-Print Network [OSTI]

    Rockenfeller, U.; Langeliers, J.; Horn, G.

    Complex-compound solid-vapor fluid pairs can be used in heat of reaction heat pumps for temperature amplifier (TA) as well as heat amplifier (HA) cycle configurations. This report describes the conceptual hardware design for complex compound...

  3. Method of and apparatus for removing silicon from a high temperature sodium coolant

    DOE Patents [OSTI]

    Yunker, W.H.; Christiansen, D.W.

    1983-11-25T23:59:59.000Z

    This patent discloses a method of and system for removing silicon from a high temperature liquid sodium coolant system for a nuclear reactor. The sodium is cooled to a temperature below the silicon saturation temperature and retained at such reduced temperature while inducing high turbulence into the sodium flow for promoting precipitation of silicon compounds and ultimate separation of silicon compound particles from the liquid sodium.

  4. Titanium alkoxide compound

    DOE Patents [OSTI]

    Boyle, Timothy J. (Albuquerque, NM)

    2007-08-14T23:59:59.000Z

    A titanium alkoxide composition is provided, as represented by the chemical formula (OC.sub.6H.sub.5N).sub.2Ti(OC.sub.6H.sub.5NH.sub.2).sub.2. As prepared, the compound is a crystalline substance with a hexavalent titanium atom bonded to two OC.sub.6H.sub.5NH.sub.2 groups and two OC.sub.6H.sub.5N groups with a theoretical molecular weight of 480.38, comprising 60.01% C, 5.04% H and 11.66% N.

  5. Boronated porphyrin compounds

    DOE Patents [OSTI]

    Kahl, Stephen B. (Portola Valley, CA); Koo, Myoung-Seo (San Francisco, CA)

    1992-01-01T23:59:59.000Z

    A compound is described having the structure ##STR1## where R preferably is ##STR2## and most preferably R.sup.3 is a closo-carborane and R.sup.2 is --H, an alkyl or aryl having 1 to about 7 carbon atoms, This invention was made with Government support under NIH Grant No. CA-37961 awarded by the Department of Health and Human Services and under the Associated Universities Inc. Contract No. De-AC02-76CH00016 with the U.S. Department of Energy. The Government has rights in this invention.

  6. Boronated porphyrin compounds

    DOE Patents [OSTI]

    Kahl, S.B.; Koo, M.S.

    1992-09-22T23:59:59.000Z

    A compound is described having the structure ##STR1## where R preferably is ##STR2## and most preferably R.sup.3 is a closo-carborane and R.sup.2 is --H, an alkyl or aryl having 1 to about 7 carbon atoms, This invention was made with Government support under NIH Grant No. CA-37961 awarded by the Department of Health and Human Services and under the Associated Universities Inc. Contract No. De-AC02-76CH00016 with the U.S. Department of Energy. The Government has rights in this invention.

  7. Large Component Removal/Disposal

    SciTech Connect (OSTI)

    Wheeler, D. M.

    2002-02-27T23:59:59.000Z

    This paper describes the removal and disposal of the large components from Maine Yankee Atomic Power Plant. The large components discussed include the three steam generators, pressurizer, and reactor pressure vessel. Two separate Exemption Requests, which included radiological characterizations, shielding evaluations, structural evaluations and transportation plans, were prepared and issued to the DOT for approval to ship these components; the first was for the three steam generators and one pressurizer, the second was for the reactor pressure vessel. Both Exemption Requests were submitted to the DOT in November 1999. The DOT approved the Exemption Requests in May and July of 2000, respectively. The steam generators and pressurizer have been removed from Maine Yankee and shipped to the processing facility. They were removed from Maine Yankee's Containment Building, loaded onto specially designed skid assemblies, transported onto two separate barges, tied down to the barges, th en shipped 2750 miles to Memphis, Tennessee for processing. The Reactor Pressure Vessel Removal Project is currently under way and scheduled to be completed by Fall of 2002. The planning, preparation and removal of these large components has required extensive efforts in planning and implementation on the part of all parties involved.

  8. Scanning Probe AFM Compound Microscope | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Probe AFM Compound Microscope Scanning Probe AFM Compound Microscope The atomic force microscope (AFM) compound microscope is designed primarily for fluorescence imaging in the...

  9. Polymer formulation for removing hydrogen and liquid water from an enclosed space

    DOE Patents [OSTI]

    Shepodd, Timothy J. (Livermore, CA)

    2006-02-21T23:59:59.000Z

    This invention describes a solution to the particular problem of liquid water formation in hydrogen getters exposed to quantities of oxygen. Water formation is usually desired because the recombination reaction removes hydrogen without affecting gettering capacity and the oxygen removal reduces the chances for a hydrogen explosion once free oxygen is essentially removed. The present invention describes a getter incorporating a polyacrylate compound that can absorb up to 500% of its own weight in liquid water without significantly affecting its hydrogen gettering/recombination properties, but that also is insensitive to water vapor.

  10. Process for preparing a chemical compound enriched in isotope content. [nitrogen 15-enriched nitric acid

    DOE Patents [OSTI]

    Michaels, E.D.

    1981-02-25T23:59:59.000Z

    A process to prepare a chemical enriched in isotope content includes: a chemical exchange reaction between a first and second compound which yields an isotopically enriched first compound and an isotopically depleted second compound; the removal of a portion of the first compound as product and the removal of a portion of the second compound as spent material; the conversion of the remainder of the first compound to the second compound for reflux at the product end of the chemical exchange reaction region; the conversion of the remainder of the second compound to the first compound for reflux at the spent material end of the chemical exchange region; and the cycling of the additional chemicals produced by one conversion reaction to the other conversion reaction, for consumption therein. One of the conversion reactions is an oxidation reaction, and the energy that it yields is used to drive the other conversion reaction, a reduction. The reduction reaction is carried out in a solid polymer electrolyte electrolytic reactor. The overall process is energy efficient and yields no waste by-products. A particular embodiment of the process in the production of nitrogen-15-enriched nitric acid.

  11. Removal of phosphorus from mud

    SciTech Connect (OSTI)

    Nield, M.A.; Robbins, B.N.

    1988-08-09T23:59:59.000Z

    This patent describes a method of processing an aqueous phosphorous-containing solids-containing waste material containing about 5 to about 75 wt.% of elemental phosphorus and which is phosphorus mud obtained as a by-product in the electrothermal production of elemental phosphorus by removing the water and phosphorus substantially completely therefrom, the improvement in the processing which consists essentially of the steps of: first boiling off the water from the waste material to effect the substantially-complete removal of water therefrom, next boiling-off yellow phosphorus from the waste material, and finally burning off residual phosphorus remaining from the boiling-off of yellow phosphorus from the waste material, whereby the boiling-off of yellow phosphorus and the burning-off of the residual phosphorus effects substantially complete removal of phosphorus from the waste material to produce a substantially phosphorus-free solid residue.

  12. Actinide removal from spent salts

    DOE Patents [OSTI]

    Hsu, Peter C. (Pleasanton, CA); von Holtz, Erica H. (Livermore, CA); Hipple, David L. (Livermore, CA); Summers, Leslie J. (Livermore, CA); Adamson, Martyn G. (Danville, CA)

    2002-01-01T23:59:59.000Z

    A method for removing actinide contaminants (uranium and thorium) from the spent salt of a molten salt oxidation (MSO) reactor is described. Spent salt is removed from the reactor and analyzed to determine the contaminants present and the carbonate concentration. The salt is dissolved in water, and one or more reagents are added to precipitate the thorium as thorium oxide and/or the uranium as either uranium oxide or as a diuranate salt. The precipitated materials are filtered, dried and packaged for disposal as radioactive waste. About 90% of the thorium and/or uranium present is removed by filtration. After filtration, salt solutions having a carbonate concentration >20% can be dried and returned to the reactor for re-use. Salt solutions containing a carbonate concentration <20% require further clean-up using an ion exchange column, which yields salt solutions that contain less than 0.1 ppm of thorium or uranium.

  13. Metals removal from spent salts

    DOE Patents [OSTI]

    Hsu, Peter C. (Pleasanton, CA); Von Holtz, Erica H. (Livermore, CA); Hipple, David L. (Livermore, CA); Summers, Leslie J. (Livermore, CA); Brummond, William A. (Livermore, CA); Adamson, Martyn G. (Danville, CA)

    2002-01-01T23:59:59.000Z

    A method and apparatus for removing metal contaminants from the spent salt of a molten salt oxidation (MSO) reactor is described. Spent salt is removed from the reactor and analyzed to determine the contaminants present and the carbonate concentration. The salt is dissolved in water, and one or more reagents may be added to precipitate the metal oxide and/or the metal as either metal oxide, metal hydroxide, or as a salt. The precipitated materials are filtered, dried and packaged for disposal as waste or can be immobilized as ceramic pellets. More than about 90% of the metals and mineral residues (ashes) present are removed by filtration. After filtration, salt solutions having a carbonate concentration >20% can be spray-dried and returned to the reactor for re-use. Salt solutions containing a carbonate concentration <20% require further clean-up using an ion exchange column, which yields salt solutions that contain less than 1.0 ppm of contaminants.

  14. Removal of pollutants from solid matrices using supercritical fluids

    SciTech Connect (OSTI)

    Tomasko, D.L. [Ohio State Univ., Columbus, OH (United States); Macnaughton, S.J.; Foster, N.R. [Univ. of South Wales, Kensington (Australia)] [and others

    1995-04-01T23:59:59.000Z

    Several supercritical fluid extraction (SCFE) processes have been proposed for removing toxic and intractable organic compounds from a range of contaminated solids. These include soil remediation and the regeneration of absorbents used to treat wastewater streams such as granular activated carbon (GAC). As a separation technique for environmental control, SCFR has several distinct advantages over conventional liquid extraction methods and incineration. Most notably, the contaminant is removed from the solvent in a concentrated form via a change in pressure or temperature and can be completely separated upon expansion to atmospheric pressure. The viability of SCFE hinges on process conditions such as solvent-feed ratio and solvent recycle ratio. The necessity of recycling solvent complicates the contaminant separation step since a complete reduction to atmospheric pressure would create large recompression costs. Because of this, the pressure and temperature dependence of contaminant solubility must be understood so that operating conditions for the separation step can be defined. Fortunately, this is the most developed aspect of SCF technology. However, the mass transfer limitations to removing contaminants from solids change with solvent flow rate. This paper discusses the use of SCFE for environmental control and presents results for the removal of DDT and 2-chlorophenol from GAC. 2-chlorophenol is almost completely removed with pure CO{sub 2} at 40{degrees}C and 101 bar while only 55% of the DDT is removed at 40{degrees}C and 200 bar. These differences in regeneration efficiency cannot be understood solely in terms of solubility but point to a need for detailed studies of adsorption equilibrium and mass transfer resistances in supercritical fluid systems.

  15. Mercury removal in utility wet scrubber using a chelating agent

    DOE Patents [OSTI]

    Amrhein, Gerald T. (Louisville, OH)

    2001-01-01T23:59:59.000Z

    A method for capturing and reducing the mercury content of an industrial flue gas such as that produced in the combustion of a fossil fuel or solid waste adds a chelating agent, such as ethylenediaminetetraacetic acid (EDTA) or other similar compounds like HEDTA, DTPA and/or NTA, to the flue gas being scrubbed in a wet scrubber used in the industrial process. The chelating agent prevents the reduction of oxidized mercury to elemental mercury, thereby increasing the mercury removal efficiency of the wet scrubber. Exemplary tests on inlet and outlet mercury concentration in an industrial flue gas were performed without and with EDTA addition. Without EDTA, mercury removal totaled 42%. With EDTA, mercury removal increased to 71%. The invention may be readily adapted to known wet scrubber systems and it specifically provides for the removal of unwanted mercury both by supplying S.sup.2- ions to convert Hg.sup.2+ ions into mercuric sulfide (HgS) and by supplying a chelating agent to sequester other ions, including but not limited to Fe.sup.2+ ions, which could otherwise induce the unwanted reduction of Hg.sup.2+ to the form, Hg.sup.0.

  16. Multipollutant Removal with WOWClean® System

    E-Print Network [OSTI]

    Romero, M.

    2010-01-01T23:59:59.000Z

    such as petcoke, coal, wood, diesel and natural gas. In addition to significant removal of CO2, test results demonstrate the capability to reduce 99.5% SOx (from levels as high as 2200 ppm), 90% reduction of NOx, and > 90% heavy metals. The paper will include...

  17. Methods for fabricating thin film III-V compound solar cell

    DOE Patents [OSTI]

    Pan, Noren; Hillier, Glen; Vu, Duy Phach; Tatavarti, Rao; Youtsey, Christopher; McCallum, David; Martin, Genevieve

    2011-08-09T23:59:59.000Z

    The present invention utilizes epitaxial lift-off in which a sacrificial layer is included in the epitaxial growth between the substrate and a thin film III-V compound solar cell. To provide support for the thin film III-V compound solar cell in absence of the substrate, a backing layer is applied to a surface of the thin film III-V compound solar cell before it is separated from the substrate. To separate the thin film III-V compound solar cell from the substrate, the sacrificial layer is removed as part of the epitaxial lift-off. Once the substrate is separated from the thin film III-V compound solar cell, the substrate may then be reused in the formation of another thin film III-V compound solar cell.

  18. ORIGINAL RESEARCH PAPER Enhanced nitrogen removal in bio-electrochemical systems

    E-Print Network [OSTI]

    Nerenberg, Robert

    .V. 2009 Abstract Microbial fuel cells can be designed to remove nitrogenous compounds out of wastewater systems. Keywords Bio-catalyzed cathode Á Energy recovery Á Microbial electrolysis cell Á Microbial fuel, the term microbial fuel cell (MFC) is used, whereas the term microbial electrolysis cell (MEC) is used when

  19. How to run PATSEE 1.) In the INS file remove all commands save

    E-Print Network [OSTI]

    Meagher, Mary

    How to run PATSEE 1.) In the INS file remove all commands save TITL compound SAVE as *.RES ii. Start XP, read the *.res file iii. Use the PICK command to trim the molecule to the desired fragment iv. Save the fragment with the ORTH command b. Second method : Use a modelling program

  20. Feed gas contaminant removal in ion transport membrane systems

    DOE Patents [OSTI]

    Underwood, Richard Paul (Allentown, PA); Makitka, III, Alexander (Hatfield, PA); Carolan, Michael Francis (Allentown, PA)

    2012-04-03T23:59:59.000Z

    An oxygen ion transport membrane process wherein a heated oxygen-containing gas having one or more contaminants is contacted with a reactive solid material to remove the one or more contaminants. The reactive solid material is provided as a deposit on a support. The one or more contaminant compounds in the heated oxygen-containing gas react with the reactive solid material. The contaminant-depleted oxygen-containing gas is contacted with a membrane, and oxygen is transported through the membrane to provide transported oxygen.

  1. Improved Processes to Remove Naphthenic Acids

    SciTech Connect (OSTI)

    Aihua Zhang; Qisheng Ma; Kangshi Wang; Yongchun Tang; William A. Goddard

    2005-12-09T23:59:59.000Z

    In the past three years, we followed the work plan as we suggested in the proposal and made every efforts to fulfill the project objectives. Based on our large amount of creative and productive work, including both of experimental and theoretic aspects, we received important technical breakthrough on naphthenic acid removal process and obtained deep insight on catalytic decarboxylation chemistry. In detail, we established an integrated methodology to serve for all of the experimental and theoretical work. Our experimental investigation results in discovery of four type effective catalysts to the reaction of decarboxylation of model carboxylic acid compounds. The adsorption experiment revealed the effectiveness of several solid materials to naphthenic acid adsorption and acidity reduction of crude oil, which can be either natural minerals or synthesized materials. The test with crude oil also received promising results, which can be potentially developed into a practical process for oil industry. The theoretical work predicted several possible catalytic decarboxylation mechanisms that would govern the decarboxylation pathways depending on the type of catalysts being used. The calculation for reaction activation energy was in good agreement with our experimental measurements.

  2. Sandia National Laboratories: compound semiconductor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    compound semiconductor Sandia and EMCORE: Solar Photovoltaics, Fiber Optics, MODE, and Energy Efficiency On March 29, 2013, in Concentrating Solar Power, Energy, Partnership,...

  3. Characterization of nickel and vanadium compounds in tar sand bitumen by UV-VIS spectroscopy and size exclusion chromatography coupled with element specific detection

    SciTech Connect (OSTI)

    Reynolds, J.G.; Jones, E.L.; Bennett, J.A. (Lawrence Livermore National Lab., CA (USA)); Biggs, W.R. (Chevron Research Co., Richmond, CA (USA))

    1989-01-01T23:59:59.000Z

    Previously, the authors examined the Ni and V in heavy crude oils, residua, and processed products by several metal speciation techniques to ascertain molecular structure and processing behavior. Two classes of metal compounds were found - metallopetroporphyrins and metallo-nonprophyrins - each having unique reactivity during processing. In efforts to better understand the binding of metals in the oil medium, they now examine NI and V in tar sand bitumens. The bitumen was solvent extracted from the sand matrix and was separated by column chromatography and the petroporphyrin content was quantitated by UV-vis spectroscopy. The petroporphyrin contents ranged from virtually none to over 36% of the total metals. Asphalt Ridge (Utah) has primarily Ni petroporphyrins; Big Clifty (Kentucky) and Athabasca (Canada) have primarily V petroporphyrins; Arroyo Grande and McKittrick (California) have roughly equal amounts of both types; and Sunnyside (Utah) has virtually none of either.

  4. Devices for collecting chemical compounds

    DOE Patents [OSTI]

    Scott, Jill R; Groenewold, Gary S

    2013-12-24T23:59:59.000Z

    A device for sampling chemical compounds from fixed surfaces and related methods are disclosed. The device may include a vacuum source, a chamber and a sorbent material. The device may utilize vacuum extraction to volatilize the chemical compounds from a fixed surface so that they may be sorbed by the sorbent material. The sorbent material may then be analyzed using conventional thermal desorption/gas chromatography/mass spectrometry (TD/GC/MS) instrumentation to determine presence of the chemical compounds. The methods may include detecting release and presence of one or more chemical compounds and determining the efficacy of decontamination. The device may be useful in collection and analysis of a variety of chemical compounds, such as residual chemical warfare agents, chemical attribution signatures and toxic industrial chemicals.

  5. IDENTIFYING CANDIDATE PROTEIN FOR REMOVAL OF ENVIRONMENTALLY

    E-Print Network [OSTI]

    Uppsala Universitet

    IDENTIFYING CANDIDATE PROTEIN FOR REMOVAL OF ENVIRONMENTALLY HAZARDOUS SUBSTANCES Pharem Biotech products and technologies for removing environmental hazardous substances in our everyday life. The products can be applied in areas from the private customer up to the global corporate perspective

  6. Arsenic removal and stabilization by synthesized pyrite

    E-Print Network [OSTI]

    Song, Jin Kun

    2009-05-15T23:59:59.000Z

    hydride generation atomic absorption spectrometry method for measuring arsenic species (As(III), As(V)). The synthesized pyrite was applied to remove arsenic and its maximum capacity for arsenic removal was measured in batch adsorption experiments to be 3...

  7. Polishing compound for plastic surfaces

    DOE Patents [OSTI]

    Stowell, M.S.

    1995-08-22T23:59:59.000Z

    A polishing compound for plastic surfaces is disclosed. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains fine particles silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS{trademark}, LEXAN{trademark}, LUCITE{trademark}, polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired. 5 figs.

  8. Polishing compound for plastic surfaces

    DOE Patents [OSTI]

    Stowell, Michael S. (New Ellenton, SC)

    1995-01-01T23:59:59.000Z

    A polishing compound for plastic surfaces. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains fine particles silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS.TM., LEXAN.TM., LUCITE.TM., polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired.

  9. Polishing compound for plastic surfaces

    DOE Patents [OSTI]

    Stowell, M.S.

    1993-01-01T23:59:59.000Z

    A polishing compound for plastic surfaces is disclosed. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains colloidal silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS{sup TM}, LEXAN{sup TM}, LUCITE{sup TM}, polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired.

  10. Cleaning method for removing sulfur containing deposits from coke oven gas lines

    SciTech Connect (OSTI)

    Sumansky, L.W.

    1985-04-09T23:59:59.000Z

    Process for removing hard to remove deposits containing elemental sulfur and multivalent compounds from a surface comprising contacting the deposits with a cleaning composition comprising (a) a major portion of aliphatic amine, (b) water, and (c) an oxidizing or reducing agent, allowing the cleaning composition to remain in contact with the deposits for sufficient time to allow sufficient dissolution of said solid to take place to allow removal of the deposits to take place, and applying such force as is necessary to remove these partially dissolved deposits from the surface. A preferred cleaning composition comprises from about 60 to about 90 volume percent aliphatic amine, from about 10 to about 40 volume percent water, and from about 1 to about 3 weight percent of a moderate oxidizing or reducing agent, such percentages based on the total composition.

  11. SOLAR HEATING OF TANK BOTTOMS Application of Solar Heating to Asphaltic and Parrafinic Oils Reducing Fuel Costs and Greenhouse Gases Due to Use of Natural Gas and Propane

    SciTech Connect (OSTI)

    Eugene A. Fritzler

    2005-09-01T23:59:59.000Z

    The sale of crude oil requires that the crude meet product specifications for BS&W, temperature, pour point and API gravity. The physical characteristics of the crude such as pour point and viscosity effect the efficient loading, transport, and unloading of the crude oil. In many cases, the crude oil has either a very high paraffin content or asphalt content which will require either hot oiling or the addition of diluents to the crude oil to reduce the viscosity and the pour point of the oil allowing the crude oil to be readily loaded on to the transport. Marginal wells are significantly impacted by the cost of preheating the oil to an appropriate temperature to allow for ease of transport. Highly paraffinic and asphaltic oils exist throughout the D-J basin and generally require pretreatment during cold months prior to sales. The current study addresses the use of solar energy to heat tank bottoms and improves the overall efficiency and operational reliability of stripper wells.

  12. Automatic Eyeglasses Removal from Face Images

    E-Print Network [OSTI]

    Narasayya, Vivek

    Automatic Eyeglasses Removal from Face Images Chenyu Wu, Ce Liu, Heung-Yueng Shum, Member, IEEE an intelligent image editing and face synthesis system that automatically removes eyeglasses from an input frontal face image. Although conventional image editing tools can be used to remove eyeglasses by pixel

  13. Laser-based coatings removal

    SciTech Connect (OSTI)

    Freiwald, J.G.; Freiwald, D.

    1995-12-01T23:59:59.000Z

    Over the years as building and equipment surfaces became contaminated with low levels of uranium or plutonium dust, coats of paint were applied to stabilize the contaminants in place. Most of the earlier paint used was lead-based paint. More recently, various non-lead-based paints, such as two-part epoxy, are used. For D & D (decontamination and decommissioning), it is desirable to remove the paints or other coatings rather than having to tear down and dispose of the entire building.

  14. COMBUSTION SOURCES OF NITROGEN COMPOUNDS

    E-Print Network [OSTI]

    Brown, Nancy J.

    2011-01-01T23:59:59.000Z

    Rasmussen, R.A. (1976). Combustion as a source of nitrousx control for stationary combustion sources. Prog. Energy,CA, March 3-4, 1977 COMBUSTION SOURCES OF NITROGEN COMPOUNDS

  15. Detection of chlorinated aromatic compounds

    DOE Patents [OSTI]

    Ekechukwu, A.A.

    1996-02-06T23:59:59.000Z

    A method for making a composition for measuring the concentration of chlorinated aromatic compounds in aqueous fluids, and an optical probe for use with the method are disclosed. The composition comprises a hydrophobic polymer matrix, preferably polyamide, with a fluorescent indicator uniformly dispersed therein. The indicator fluoresces in the presence of the chlorinated aromatic compounds with an intensity dependent on the concentration of these compounds in the fluid of interest, such as 8-amino-2-naphthalene sulfonate. The probe includes a hollow cylindrical housing that contains the composition in its distal end. The probe admits an aqueous fluid to the probe interior for exposure to the composition. An optical fiber transmits excitation light from a remote source to the composition while the indicator reacts with chlorinated aromatic compounds present in the fluid. The resulting fluorescence light signal is reflected to a second optical fiber that transmits the light to a spectrophotometer for analysis. 5 figs.

  16. Polishing compound for plastic surfaces

    DOE Patents [OSTI]

    Stowell, M.S.

    1991-01-01T23:59:59.000Z

    This invention is comprised of a polishing compound for plastic materials. The compound includes approximately by approximately by weight 25 to 80 parts at least one petroleum distillate lubricant, 1 to 12 parts mineral spirits, 50 to 155 parts abrasive paste, and 15 to 60 parts water. Preferably, the compound includes approximately 37 to 42 parts at least one petroleum distillate lubricant, up to 8 parts mineral spirits, 95 to 110 parts abrasive paste, and 50 to 55 parts water. The proportions of the ingredients are varied in accordance with the particular application. The compound is used on PLEXIGLAS{trademark}, LEXAN{trademark}, LUCITE{trademark}, polyvinyl chloride (PVC), and similar plastic materials whenever a smooth, clear polished surface is desired.

  17. Method for removing oxide contamination from silicon carbide powders

    DOE Patents [OSTI]

    Brynestad, J.; Bamberger, C.E.

    1984-08-01T23:59:59.000Z

    The described invention is directed to a method for removing oxide contamination in the form of oxygen-containing compounds such as SiO/sub 2/ and B/sub 2/O/sub 3/ from a charge of finely divided silicon carbide. The silicon carbide charge is contacted with a stream of hydrogen fluoride mixed with an inert gas carrier such as argon at a temperature in the range of about 200/sup 0/ to 650/sup 0/C. The oxides in the charge react with the heated hydrogen fluoride to form volatile gaseous fluorides such as SiF/sub 4/ and BF/sub 3/ which pass through the charge along with unreacted hydrogen fluoride and the carrier gas. Any residual gaseous reaction products and hydrogen fluoride remaining in the charge are removed by contacting the charge with the stream of inert gas which also cools the powder to room temperature. The removal of the oxygen contamination by practicing the present method provides silicon carbide powders with desirable pressing and sintering characteristics. 1 tab.

  18. Aza compounds as anion receptors

    DOE Patents [OSTI]

    Lee, H.S.; Yang, X.Q.; McBreen, J.

    1998-01-06T23:59:59.000Z

    A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of Li{sup +} ion in alkali metal batteries. 3 figs.

  19. Rejection and fate of trace organic compounds (TrOCs) during membrane distillation

    E-Print Network [OSTI]

    Rejection and fate of trace organic compounds (TrOCs) during membrane distillation Kaushalya COCs) Direct contact membrane distillation (DCMD) Volatility Fate and transport Hydrophobicity/hydrophilicity a b s t r a c t In this study, we examined the feasibility of membrane distillation (MD) for removing

  20. Contamination levels of human pharmaceutical compounds in French surface and drinking water

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    -west France. 98 samples were analysed from 63 stations (surface water and drinking water produced from surface. The removal rate of human pharmaceutical compounds at 11 water treatment units was also determined. Only caffeine proved to be resistant to drinking water treatment processes (with a minimum rate of 5%). Other

  1. Low Temperature Sorbents for removal of Sulfur Compounds from fluid feed Streams

    SciTech Connect (OSTI)

    Siriwardane, Ranjan

    1999-09-30T23:59:59.000Z

    A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

  2. Removal of pharmaceuticals and endocrine disrupting compounds in water recycling process using reverse osmosis systems 

    E-Print Network [OSTI]

    Al-Rifai, Jawad H.; Khabbazb, Hadi; Schäfer, Andrea

    2011-01-01T23:59:59.000Z

    A detailed investigation was carried out to evaluate the occurrence, persistence and fate of a range of micropollutants at different processing points at a full-scale water recycling plant (WRP) in Queensland, Australia. ...

  3. The removal kinetics of industrial organic compounds in natural and synthetic systems

    E-Print Network [OSTI]

    Petrasek, Albert Charles

    1970-01-01T23:59:59.000Z

    on the value of the 1ndependent variable, and those data in which the dependent variable 1s a function of the 1ndependent variable. This program has wide appl1cation whenever data analysis is necessary, and the volume dictates more rapid', processing.... Lineprinter 'listing of dissolved oxygen unit rate curve parameters. 131 xii LI. ST OF TABLES (CONTINUED) Table Ul-10. Computer listing of NLSS values computed from the approximation function. UI-ll. List of computed total organic carbon concentrations...

  4. Removal of hydrophobic Volatile Organic Compounds1 in an integrated process coupling Absorption and2

    E-Print Network [OSTI]

    Boyer, Edmond

    is an interesting method, owing to the low pressure drop generated and68 the low maintenance needed, contrarily to membrane processes that require high working pressures to69 treat low gas flow rates (Fig. 1). An emerging of the process, hydrophobic VOC27 absorption in a gas-liquid contactor, and biodegradation in the TPPB. VOC

  5. Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds

    E-Print Network [OSTI]

    Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

    2008-01-01T23:59:59.000Z

    Coal-fired power generating plants contribute approximatelynumber of coal-fired generating plants (1-3). The mercury is

  6. Removing oestrogenic compounds from sewage effluent Andrew Johnson and Richard Darton

    E-Print Network [OSTI]

    Darton, Richard

    of intersex roach, with oocytes in the testes, downstream of many domestic sewage effluents in the UK (figure 2). #12;3 Figures 2(a) Roach fish. 2(b) Testis of intersex roach showing presence of ova within chemicals, suggesting that these roach had been exposed to similar chemicals in the wild. Initially

  7. Removal of volatile organic compounds from polluted air in a reverse flow reactor: An experimental study

    SciTech Connect (OSTI)

    Beld, B. van de; Borman, R.A.; Derkx, O.R.; Woezik, B.A.A. van; Westerterp, K.R. (Univ. of Twente, Enschede (Netherlands). Dept. of Chemical Engineering)

    1994-12-01T23:59:59.000Z

    An experimental study of the reverse flow reactor for the purification of contaminated air has been carried out. An experimental reactor with an inner diameter of 0.145 m has been constructed. It almost completely reached the goal of an adiabatically operating system. The influence of several operating parameters such as gas velocity, cycle period, chemical character, and concentration of the pollutants and reactor pressure are discussed. The reactor could be operated autothermally provided that the inlet concentrations were sufficiently high. If a mixture of contaminants is fed to the reactor, it might be necessary to increase the total hydrocarbon concentration to assure an autothermal process. Increasing the reactor pressure will hardly change the axial temperature profiles, if the mass flux is kept constant. Increasing the mass flow rate will lead to a higher plateau temperature. Not only the reactor behavior at fixed operating conditions, but also the response of the reactor toward variations in inlet conditions is reported.

  8. Low Temperature Sorbents for Removal of Sulfur Compounds from Fluid Feed Streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani

    2004-06-01T23:59:59.000Z

    A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

  9. Compound cast product and method for producing a compound cast product

    DOE Patents [OSTI]

    Meyer, Thomas N. (3987 Murray Highlands Cir., Murrysville, PA 15668-1747); Viswanathan, Srinath (1104 Albermarle La., Knoxville, TN 37923)

    2002-09-17T23:59:59.000Z

    A compound cast product is formed in a casting mold (14) having a mold cavity (16) sized and shaped to form the cast product. A plurality of injectors (24) is supported from a bottom side (26) of the casting mold (14). The injectors (24) are in fluid communication with the mold cavity (16) through the bottom side (26) of the casting mold (14). A molten material holder furnace (12) is located beneath the casting mold (14). The holder furnace (12) defines molten material receiving chambers (36) configured to separately contain supplies of two different molten materials (37, 38). The holder furnace (12) is positioned such that the injectors (24) extend downward into the receiving chamber (36). The receiving chamber (36) is separated into at least two different flow circuits (51, 52). A first molten material (37) is received in a first flow circuit (51), and a second molten material (38) is received into a second flow circuit (52). The first and second molten materials (37, 38) are injected into the mold cavity (16) by the injectors (24) acting against the force of gravity. The injectors (24) are positioned such that the first and second molten materials (37, 38) are injected into different areas of the mold cavity (16). The molten materials (37, 38) are allowed to solidify and the resulting compound cast product is removed from the mold cavity (16).

  10. Radioactive air emissions notice of construction fuel removal for 105-KW Basin

    SciTech Connect (OSTI)

    Hays, C.B.

    1997-05-29T23:59:59.000Z

    This document serves as a Notice of Construction (NOC), pursuant to the requirements of Washington Administrative Code (WAC) 246-247-060, and as a request for approval to construct, pursuant to 40 Code of Federal Regulations (CFR) 61.96, for the modifications, installation of new equipment, and fuel removal and sludge relocation activities at 105-KW Basin. The purpose of the activities described in this NOC is to enable the eventual retrieval and transport of the fuel for processing. The fuel retrieval and transport will require an integrated water treatment system for which performance specifications have been developed. These specifications are currently in the procurement process. Following procurement (and before installation of this system and the handling of fuel) design details will be provided to Washington State Department of Health (WDOH). The 105-K West Reactor (105-KW) and its associated spent nuclear fuel (SNF) storage basin were constructed in the early 1950s and are located on the Hanford Site in the 100-K Area about 1,400 feet from the Columbia River. The 105-KW Basin contains 964 Metric Tons of SNF stored under water in approximately 3,800 closed canisters. This SNF has been stored for varying periods of time ranging from 8 to 17 years. The 105-KW Basin is constructed of concrete with an epoxy coating and contains approximately 1.3 million gallons of water with an asphaltic membrane beneath the pool. Although the 105-KW Basin has not been known to leak, the discharge chute and associated construction joint have been isolated from the rest of the basin by metal isolation barriers. This was a precautionary measure, to mitigate the consequences of a seismic event. The proposed modifications described are scheduled to begin in calendar year 1997.

  11. Molecular Characterization of Nitrogen Containing Organic Compounds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nitrogen Containing Organic Compounds in Biomass Burning Aerosols Using High Resolution Mass Molecular Characterization of Nitrogen Containing Organic Compounds in Biomass Burning...

  12. Process for production of a borohydride compound

    DOE Patents [OSTI]

    Chin, Arthur Achhing; Jain, Puja; Linehan, Suzanne; Lipiecki, Francis Joseph; Maroldo, Stephen Gerard; November, Samuel J; Yamamoto, John Hiroshi

    2013-02-19T23:59:59.000Z

    A process for production of a borohydride compound. The process comprises combining a compound comprising boron and oxygen with an adduct of alane.

  13. Melter Glass Removal and Dismantlement

    SciTech Connect (OSTI)

    Richardson, BS

    2000-10-31T23:59:59.000Z

    The U.S. Department of Energy (DOE) has been using vitrification processes to convert high-level radioactive waste forms into a stable glass for disposal in waste repositories. Vitrification facilities at the Savannah River Site (SRS) and at the West Valley Demonstration Project (WVDP) are converting liquid high-level waste (HLW) by combining it with a glass-forming media to form a borosilicate glass, which will ensure safe long-term storage. Large, slurry fed melters, which are used for this process, were anticipated to have a finite life (on the order of two to three years) at which time they would have to be replaced using remote methods because of the high radiation fields. In actuality the melters useable life spans have, to date, exceeded original life-span estimates. Initial plans called for the removal of failed melters by placing the melter assembly into a container and storing the assembly in a concrete vault on the vitrification plant site pending size-reduction, segregation, containerization, and shipment to appropriate storage facilities. Separate facilities for the processing of the failed melters currently do not exist. Options for handling these melters include (1) locating a facility to conduct the size-reduction, characterization, and containerization as originally planned; (2) long-term storing or disposing of the complete melter assembly; and (3) attempting to refurbish the melter and to reuse the melter assembly. The focus of this report is to look at methods and issues pertinent to size-reduction and/or melter refurbishment in particular, removing the glass as a part of a refurbishment or to reduce contamination levels (thus allowing for disposal of a greater proportion of the melter as low level waste).

  14. Removal of metal ions from aqueous solution

    DOE Patents [OSTI]

    Jackson, Paul J. (both Los Alamos, NM); Delhaize, Emmanuel (both Los Alamos, NM); Robinson, Nigel J. (Durham, GB2); Unkefer, Clifford J. (Los Alamos, NM); Furlong, Clement (Seattle, WA)

    1990-11-13T23:59:59.000Z

    A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat unit for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heayv metals from solution. This also results in the removal of the metals from the column in a concentrated form.

  15. Removal of metal ions from aqueous solution

    DOE Patents [OSTI]

    Jackson, Paul J. (Los Alamos, NM); Delhaize, Emmanuel (Los Alamos, NM); Robinson, Nigel J. (Durham, GB2); Unkefer, Clifford J. (Los Alamos, NM); Furlong, Clement (Seattle, WA)

    1990-01-01T23:59:59.000Z

    A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat units for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heavy metals from solution. This also results in the removal of the metals from the column in a concentrated form.

  16. Method for removing contaminants from plastic resin

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2008-12-09T23:59:59.000Z

    A resin recycling method that produces essentially contaminant-free synthetic resin material in an environmentally safe and economical manner. The method includes receiving the resin in container form. The containers are then ground into resin particles. The particles are exposed to a solvent, the solvent contacting the resin particles and substantially removing contaminants on the resin particles. After separating the particles and the resin, a solvent removing agent is used to remove any residual solvent remaining on the resin particles after separation.

  17. PRTR ion exchange vault water removal

    SciTech Connect (OSTI)

    Ham, J.E.

    1995-11-01T23:59:59.000Z

    This report documents the removal of radiologically contaminated water from the Plutonium Recycle Test Reactor (PRTR) ion exchange vault. Approximately 57,000 liters (15,000 gallons) of water had accumulated in the vault due to the absence of a rain cover. The water was removed and the vault inspected for signs of leakage. No evidence of leakage was found. The removal and disposal of the radiologically contaminated water decreased the risk of environmental contamination.

  18. General Counsel Legal Interpretation Regarding Medical Removal...

    Energy Savers [EERE]

    Regarding Medical Removal Protection Benefits Pursuant to 10 CFR Part 850, Chronic Beryllium Disease Prevention Program General Counsel Legal Interpretation Regarding Medical...

  19. System for removing contaminants from plastic resin

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2010-11-23T23:59:59.000Z

    A resin recycling system that produces essentially contaminant-free synthetic resin material in an environmentally safe and economical manner. The system includes receiving the resin in container form. A grinder grinds the containers into resin particles. The particles are exposed to a solvent in one or more solvent wash vessels, the solvent contacting the resin particles and substantially removing contaminants on the resin particles. A separator is used to separate the resin particles and the solvent. The resin particles are then placed in solvent removing element where they are exposed to a solvent removing agent which removes any residual solvent remaining on the resin particles after separation.

  20. Slag capture and removal during laser cutting

    DOE Patents [OSTI]

    Brown, Clyde O. (Newington, CT)

    1984-05-08T23:59:59.000Z

    Molten metal removed from a workpiece in a laser cutting operation is blown away from the cutting point by a gas jet and collected on an electromagnet.

  1. Possible explosive compounds in the Savannah River Site Tank Farm facilities. Revision 1

    SciTech Connect (OSTI)

    Hobbs, D.T.

    1995-04-27T23:59:59.000Z

    Since 1970, many studies have been conducted concerning the potential for explosive compounds in tank farm operations including ammonium nitrate, metal oxalates, and silver and mercury compounds. The study currently in progress is the most comprehensive to date, encompassing all previous studies and extending the scope to include all compounds that could be formed from the known species in SRS wastes. In addition to waste storage, the study also considers waste removal and waste processing operations. The total number of possible explosive compounds is so large that it would not be useful to list them all here. Instead, only those compounds are listed that are known to be present or could conceivably be formed from material that is known to be present in the waste. The general approach to the problem is: identify all of the constituents that are known to be present in the waste together with those that might be present from possible chemical and radiolytic reactions, determine the compounds that could be formed from these constituents, compare these compounds with those listed in the literature, and assess the formation and stability of these compounds against the conditions existing in the tank farm facilities.

  2. Method for removal and stabilization of mercury in mercury-containing gas streams

    DOE Patents [OSTI]

    Broderick, Thomas E.

    2005-09-13T23:59:59.000Z

    The present invention is directed to a process and apparatus for removing and stabilizing mercury from mercury-containing gas streams. A gas stream containing vapor phase elemental and/or speciated mercury is contacted with reagent, such as an oxygen-containing oxidant, in a liquid environment to form a mercury-containing precipitate. The mercury-containing precipitate is kept or placed in solution and reacts with one or more additional reagents to form a solid, stable mercury-containing compound.

  3. Methods and compositions for removing carbon dioxide from a gaseous mixture

    DOE Patents [OSTI]

    Li, Jing; Wu, Haohan

    2014-06-24T23:59:59.000Z

    Provided is a method for adsorbing or separating carbon dioxide from a mixture of gases by passing the gas mixture through a porous three-dimensional polymeric coordination compound having a plurality of layers of two-dimensional arrays of repeating structural units, which results in a lower carbon dioxide content in the gas mixture. Thus, this invention provides useful compositions and methods for removal of greenhouse gases, in particular CO.sub.2, from industrial flue gases or from the atmosphere.

  4. Method for removal of plutonium impurity from americium oxides and fluorides

    DOE Patents [OSTI]

    FitzPatrick, J.R.; Dunn, J.G.; Avens, L.R.

    1987-02-13T23:59:59.000Z

    Method for removal of plutonium impurity from americium oxides and fluorides. AmF/sub 4/ is not further oxidized to AmF/sub 6/ by the application of O/sub 2/F at room temperature thereto, while plutonium compounds present in the americium sample are fluorinated to volatile PuF/sub 6/, which can readily be separated therefrom, leaving the purified americium oxides and/or fluorides as the solid tetrafluoride thereof.

  5. Method for removal of plutonium impurity from americium oxides and fluorides

    DOE Patents [OSTI]

    FitzPatrick, John R. (Los Alamos, NM); Dunn, Jerry G. (Los Alamos, NM); Avens, Larry R. (Los Alamos, NM)

    1987-01-01T23:59:59.000Z

    Method for removal of plutonium impurity from americium oxides and fluorides. AmF.sub.4 is not further oxidized to AmF.sub.6 by the application of O.sub.2 F at room temperature, while plutonium compounds present in the americium sample are fluorinated to volatile PuF.sub.6, which can readily be separated therefrom, leaving the purified americium oxides and/or fluorides as the solid tetrafluoride.

  6. Selection of an acid-gas removal process for an LNG plant

    SciTech Connect (OSTI)

    Stone, J.B.; Jones, G.N. [Exxon Production Research, Houston, TX (United States); Denton, R.D. [Exxon Production Malaysia, Inc., Kuala Lumpur (Malaysia)

    1996-12-31T23:59:59.000Z

    Acid gas contaminants, such as, CO{sub 2}, H{sub 2}S and mercaptans, must be removed to a very low level from a feed natural gas before it is liquefied. CO{sub 2} is typically removed to a level of about 100 ppm to prevent freezing during LNG processing. Sulfur compounds are removed to levels required by the eventual consumer of the gas. Acid-gas removal processes can be broadly classified as: solvent-based, adsorption, cryogenic or physical separation. The advantages and disadvantages of these processes will be discussed along with design and operating considerations. This paper will also discuss the important considerations affecting the choice of the best acid-gas removal process for LNG plants. Some of these considerations are: the remoteness of the LNG plant from the resource; the cost of the feed gas and the economics of minimizing capital expenditures; the ultimate disposition of the acid gas; potential for energy integration; and the composition, including LPG and conditions of the feed gas. The example of the selection of the acid-gas removal process for an LNG plant.

  7. Development Of Chemical Reduction And Air Stripping Processes To Remove Mercury From Wastewater

    SciTech Connect (OSTI)

    Jackson, Dennis G.; Looney, Brian B.; Craig, Robert R.; Thompson, Martha C.; Kmetz, Thomas F.

    2013-07-10T23:59:59.000Z

    This study evaluates the removal of mercury from wastewater using chemical reduction and air stripping using a full-scale treatment system at the Savannah River Site. The existing water treatment system utilizes air stripping as the unit operation to remove organic compounds from groundwater that also contains mercury (C ~ 250 ng/L). The baseline air stripping process was ineffective in removing mercury and the water exceeded a proposed limit of 51 ng/L. To test an enhancement to the existing treatment modality a continuous dose of reducing agent was injected for 6-hours at the inlet of the air stripper. This action resulted in the chemical reduction of mercury to Hg(0), a species that is removable with the existing unit operation. During the injection period a 94% decrease in concentration was observed and the effluent satisfied proposed limits. The process was optimized over a 2-day period by sequentially evaluating dose rates ranging from 0.64X to 297X stoichiometry. A minimum dose of 16X stoichiometry was necessary to initiate the reduction reaction that facilitated the mercury removal. Competing electron acceptors likely inhibited the reaction at the lower 1 doses, which prevented removal by air stripping. These results indicate that chemical reduction coupled with air stripping can effectively treat large-volumes of water to emerging part per trillion regulatory standards for mercury.

  8. Method of removing contaminants from plastic resins

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2008-11-18T23:59:59.000Z

    A method for removing contaminants from synthetic resin material containers using a first organic solvent system and a second carbon dioxide system. The organic solvent is utilized for removing the contaminants from the synthetic resin material and the carbon dioxide is used to separate any residual organic solvent from the synthetic resin material.

  9. Method for removing contaminants from plastic resin

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2008-12-30T23:59:59.000Z

    A method for removing contaminants from synthetic resin material containers using a first organic solvent system and a second carbon dioxide system. The organic solvent is utilized for removing the contaminants from the synthetic resin material and the carbon dioxide is used to separate any residual organic solvent from the synthetic resin material.

  10. Method of removing contaminants from plastic resins

    DOE Patents [OSTI]

    Bohnert,George W. (Harrisonville, MO); Hand,Thomas E. (Lee's Summit, MO); Delaurentiis,Gary M. (Jamestown, CA)

    2007-08-07T23:59:59.000Z

    A method for removing contaminants from synthetic resin material containers using a first organic solvent system and a second carbon dioxide system. The organic solvent is utilized for removing the contaminants from the synthetic resin material and the carbon dioxide is used to separate any residual organic solvent from the synthetic resin material.

  11. Methods of removing a constituent from a feed stream using adsorption media

    DOE Patents [OSTI]

    Tranter, Troy J. (Idaho Falls, ID); Mann, Nicholas R. (Rigby, ID); Todd, Terry A. (Aberdeen, ID); Herbst, Ronald S. (Idaho Falls, ID)

    2011-05-24T23:59:59.000Z

    A method of producing an adsorption medium to remove at least one constituent from a feed stream. The method comprises dissolving and/or suspending at least one metal compound in a solvent to form a metal solution, dissolving polyacrylonitrile into the metal solution to form a PAN-metal solution, and depositing the PAN-metal solution into a quenching bath to produce the adsorption medium. The at least one constituent, such as arsenic, selenium, or antimony, is removed from the feed stream by passing the feed stream through the adsorption medium. An adsorption medium having an increased metal loading and increased capacity for arresting the at least one constituent to be removed is also disclosed. The adsorption medium includes a polyacrylonitrile matrix and at least one metal hydroxide incorporated into the polyacrylonitrile matrix.

  12. Removal Action Plan for the Accelerated Retrieval Project for a Described Area within Pit 4

    SciTech Connect (OSTI)

    A. M. Tyson

    2006-08-01T23:59:59.000Z

    This Removal Action Plan documents the plan for implementation of the Comprehensive Environmental Response, Compenstion, and Liability Act non-time-critical removal action to be performed by the Accelerated Retrieval Project. The focus of the action is the limited excavation and retrieval of selected waste streams from a designated portion of the Radioactive Waste Management Complex Subsurface Disposal Area that are contaminated with volatile organic compounds, isotopes of uranium, or transuranic radionuclides. The selected retrieval area is approximately 0.2 ha (1/2 acre) and is located in the eastern portion of Pit 4. The proposed project is referred to as the Accelerated Retrieval Project. This Removal Action Plan details the major work elements, operations approach, and schedule, and summarizes the environmental, safety and health, and waste management considerations associated with the project.

  13. Multi-component removal in flue gas by aqua ammonia

    DOE Patents [OSTI]

    Yeh, James T. (Bethel Park, PA); Pennline, Henry W. (Bethel Park, PA)

    2007-08-14T23:59:59.000Z

    A new method for the removal of environmental compounds from gaseous streams, in particular, flue gas streams. The new method involves first oxidizing some or all of the acid anhydrides contained in the gas stream such as sulfur dioxide (SO.sub.2) and nitric oxide (NO) and nitrous oxide (N.sub.2O) to sulfur trioxide (SO.sub.3) and nitrogen dioxide (NO.sub.2). The gas stream is subsequently treated with aqua ammonia or ammonium hydroxide which captures the compounds via chemical absorption through acid-base or neutralization reactions. The products of the reactions can be collected as slurries, dewatered, and dried for use as fertilizers, or once the slurries have been dewatered, used directly as fertilizers. The ammonium hydroxide can be regenerated and recycled for use via thermal decomposition of ammonium bicarbonate, one of the products formed. There are alternative embodiments which entail stoichiometric scrubbing of nitrogen oxides and sulfur oxides with subsequent separate scrubbing of carbon dioxide.

  14. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1993-09-07T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 figures.

  15. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

    1994-06-14T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

  16. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Houston, TX)

    1989-01-01T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  17. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

    1993-01-01T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  18. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

    1994-01-01T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

  19. Alkylation of organic aromatic compounds

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1989-07-18T23:59:59.000Z

    Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

  20. Superconductivity in graphite intercalation compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Robert P. [Univ. of Cambridge (United Kingdom); Dean, Mark P. M. [Brookhaven National Lab. (BNL), Upton, NY (United States); Weller, Thomas E. [Univ. College of London (United Kingdom); Howard, Christopher A. [Univ. College of London (United Kingdom); Rahnejat, Kaveh C. [Univ. College of London (United Kingdom); Saxena, Siddharth S. [Univ. of Cambridge (United Kingdom); Ellerby, Mark [Univ. College of London (United Kingdom)

    2015-07-01T23:59:59.000Z

    The field of superconductivity in the class of materials known as graphite intercalation compounds has a history dating back to the 1960s This paper recontextualizes the field in light of the discovery of superconductivity in CaC? and YbC? in 2005. In what follows, we outline the crystal structure and electronic structure of these and related compounds. We go on to experiments addressing the superconducting energy gap, lattice dynamics, pressure dependence, and how this relates to theoretical studies. The bulk of the evidence strongly supports a BCS superconducting state. However, important questions remain regarding which electronic states and phonon modes are most important for superconductivity and whether current theoretical techniques can fully describe the dependence of the superconducting transition temperature on pressure and chemical composition.

  1. Superconductivity in graphite intercalation compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Robert P.; Dean, Mark P. M.; Weller, Thomas E.; Howard, Christopher A.; Rahnejat, Kaveh C.; Saxena, Siddharth S.; Ellerby, Mark

    2015-07-01T23:59:59.000Z

    The field of superconductivity in the class of materials known as graphite intercalation compounds has a history dating back to the 1960s This paper recontextualizes the field in light of the discovery of superconductivity in CaC? and YbC? in 2005. In what follows, we outline the crystal structure and electronic structure of these and related compounds. We go on to experiments addressing the superconducting energy gap, lattice dynamics, pressure dependence, and how this relates to theoretical studies. The bulk of the evidence strongly supports a BCS superconducting state. However, important questions remain regarding which electronic states and phonon modes aremore »most important for superconductivity and whether current theoretical techniques can fully describe the dependence of the superconducting transition temperature on pressure and chemical composition.« less

  2. Compound semiconductor optical waveguide switch

    DOE Patents [OSTI]

    Spahn, Olga B.; Sullivan, Charles T.; Garcia, Ernest J.

    2003-06-10T23:59:59.000Z

    An optical waveguide switch is disclosed which is formed from III-V compound semiconductors and which has a moveable optical waveguide with a cantilevered portion that can be bent laterally by an integral electrostatic actuator to route an optical signal (i.e. light) between the moveable optical waveguide and one of a plurality of fixed optical waveguides. A plurality of optical waveguide switches can be formed on a common substrate and interconnected to form an optical switching network.

  3. Method for changing removable bearing for a wind turbine generator

    DOE Patents [OSTI]

    Bagepalli, Bharat Sampathkumaran (Niskayuna, NY); Jansen, Patrick Lee (Scotia, NY); Gadre, Aniruddha Dattatraya (Rexford, NY)

    2008-04-22T23:59:59.000Z

    A wind generator having removable change-out bearings includes a rotor and a stator, locking bolts configured to lock the rotor and stator, a removable bearing sub-assembly having at least one shrunk-on bearing installed, and removable mounting bolts configured to engage the bearing sub-assembly and to allow the removable bearing sub-assembly to be removed when the removable mounting bolts are removed.

  4. Removable bearing arrangement for a wind turbine generator

    DOE Patents [OSTI]

    Bagepalli, Bharat Sampathkumaran; Jansen, Patrick Lee; Gadre, Aniruddha Dattatraya

    2010-06-15T23:59:59.000Z

    A wind generator having removable change-out bearings includes a rotor and a stator, locking bolts configured to lock the rotor and stator, a removable bearing sub-assembly having at least one shrunk-on bearing installed, and removable mounting bolts configured to engage the bearing sub-assembly and to allow the removable bearing sub-assembly to be removed when the removable mounting bolts are removed.

  5. In situ removal of contamination from soil

    DOE Patents [OSTI]

    Lindgren, Eric R. (Albuquerque, NM); Brady, Patrick V. (Albuquerque, NM)

    1997-01-01T23:59:59.000Z

    A process of remediation of cationic heavy metal contamination from soil utilizes gas phase manipulation to inhibit biodegradation of a chelating agent that is used in an electrokinesis process to remove the contamination, and further gas phase manipulation to stimulate biodegradation of the chelating agent after the contamination has been removed. The process ensures that the chelating agent is not attacked by bioorganisms in the soil prior to removal of the contamination, and that the chelating agent does not remain as a new contaminant after the process is completed.

  6. In situ removal of contamination from soil

    DOE Patents [OSTI]

    Lindgren, E.R.; Brady, P.V.

    1997-10-14T23:59:59.000Z

    A process of remediation of cationic heavy metal contamination from soil utilizes gas phase manipulation to inhibit biodegradation of a chelating agent that is used in an electrokinesis process to remove the contamination. The process also uses further gas phase manipulation to stimulate biodegradation of the chelating agent after the contamination has been removed. The process ensures that the chelating agent is not attacked by bioorganisms in the soil prior to removal of the contamination, and that the chelating agent does not remain as a new contaminant after the process is completed. 5 figs.

  7. Feedback Capacity of the Compound Channel

    E-Print Network [OSTI]

    Shrader, Brooke E.

    In this work, we find the capacity of a compound finite-state channel (FSC) with time-invariant deterministic feedback. We consider the use of fixed length block codes over the compound channel. Our achievability result ...

  8. Semiconducting compounds and devices incorporating same

    SciTech Connect (OSTI)

    Marks, Tobin J; Facchetti, Antonio; Boudreault, Pierre-Luc; Miyauchi, Hiroyuki

    2014-06-17T23:59:59.000Z

    Disclosed are molecular and polymeric compounds having desirable properties as semiconducting materials. Such compounds can exhibit desirable electronic properties and possess processing advantages including solution-processability and/or good stability. Organic transistor and photovoltaic devices incorporating the present compounds as the active layer exhibit good device performance.

  9. Method of removing polychlorinated biphenyl from oil

    DOE Patents [OSTI]

    Cook, G.T.; Holshouser, S.K.; Coleman, R.M.; Harless, C.E.; Whinnery, W.N. III

    1982-03-17T23:59:59.000Z

    Polychlorinated biphenyls are removed from oil by extracting the biphenyls into methanol. The mixture of methanol and extracted biphenyls is distilled to separate methanol therefrom, and the methanol is recycled for further use in extraction of biphenyls from oil.

  10. Install Removable Insulation on Valves and Fittings

    SciTech Connect (OSTI)

    Not Available

    2006-01-01T23:59:59.000Z

    This revised ITP tip sheet on installing removable insulation on valves and fittings provides how-to advice for improving the system using low-cost, proven practices and technologies.

  11. Part removal of 3D printed parts

    E-Print Network [OSTI]

    Peña Doll, Mateo

    2014-01-01T23:59:59.000Z

    An experimental study was performed to understand the correlation between printing parameters in the FDM 3D printing process, and the force required to remove a part from the build platform of a 3D printing using a patent ...

  12. Method of removing polychlorinated biphenyl from oil

    DOE Patents [OSTI]

    Cook, Gus T. (Paducah, KY); Holshouser, Stephen K. (Boaz, KY); Coleman, Richard M. (Paducah, KY); Harless, Charles E. (Smithland, KY); Whinnery, III, Walter N. (Paducah, KY)

    1983-01-01T23:59:59.000Z

    Polychlorinated biphenyls are removed from oil by extracting the biphenyls into methanol. The mixture of methanol and extracted biphenyls is distilled to separate methanol therefrom, and the methanol is recycled for further use in extraction of biphenyls from oil.

  13. Laser removal of sludge from steam generators

    DOE Patents [OSTI]

    Nachbar, Henry D. (Ballston Lake, NY)

    1990-01-01T23:59:59.000Z

    A method of removing unwanted chemical deposits known as sludge from the metal surfaces of steam generators with laser energy is provided. Laser energy of a certain power density, of a critical wavelength and frequency, is intermittently focused on the sludge deposits to vaporize them so that the surfaces are cleaned without affecting the metal surface (sludge substrate). Fiberoptic tubes are utilized for laser beam transmission and beam direction. Fiberoptics are also utilized to monitor laser operation and sludge removal.

  14. Oil removal from water via adsorption 

    E-Print Network [OSTI]

    Jacobs, William Edward

    1973-01-01T23:59:59.000Z

    . TABLE OF CONTENTS CHAPTER I. INTRODUCTION I I. LITERATURE REVIEW Significance of Oil Spill Proble. ". . s Growth of Marine Commerce Superport Oil Spills Oil Spills and the Law Oil Spill Control Methods Physical Removal of Oil III. MATERIALS... IV Table V Table VI Significant Facts about Major Oil Spills Viscosity of Test Oils Determined by Capillary Viscometer Percent of Oil Remaining in Water After Removal of Oil-Carrier Combination Maximum Oil Adsorption Capacity for Light Crude...

  15. Volatile organic compound sensor system

    DOE Patents [OSTI]

    Schabron, John F. (Laramie, WY); Rovani, Jr., Joseph F. (Laramie, WY); Bomstad, Theresa M. (Laramie, WY); Sorini-Wong, Susan S. (Laramie, WY)

    2009-02-10T23:59:59.000Z

    Generally, this invention relates to the development of field monitoring methodology for new substances and sensing chemical warfare agents (CWAs) and terrorist substances. It also relates to a portable test kit which may be utilized to measure concentrations of halogenated volatile organic compounds (VOCs) in the field. Specifically it relates to systems for reliably field sensing the potential presence of such items while also distinguishing them from other elements potentially present. It also relates to overall systems and processes for sensing, reacting, and responding to an indicated presence of such substance, including modifications of existing halogenated sensors and arrayed sensing systems and methods.

  16. Volatile organic compound sensor system

    DOE Patents [OSTI]

    Schabron, John F. (Laramie, WY); Rovani, Jr., Joseph F. (Laramie, WY); Bomstad, Theresa M. (Waxahachie, TX); Sorini-Wong, Susan S. (Laramie, WY); Wong, Gregory K. (Laramie, WY)

    2011-03-01T23:59:59.000Z

    Generally, this invention relates to the development of field monitoring methodology for new substances and sensing chemical warfare agents (CWAs) and terrorist substances. It also relates to a portable test kit which may be utilized to measure concentrations of halogenated volatile organic compounds (VOCs) in the field. Specifically it relates to systems for reliably field sensing the potential presence of such items while also distinguishing them from other elements potentially present. It also relates to overall systems and processes for sensing, reacting, and responding to an indicated presence of such substance, including modifications of existing halogenated sensors and arrayed sensing systems and methods.

  17. Thin films of mixed metal compounds

    DOE Patents [OSTI]

    Mickelsen, R.A.; Chen, W.S.

    1985-06-11T23:59:59.000Z

    Disclosed is a thin film heterojunction solar cell, said heterojunction comprising a p-type I-III-IV[sub 2] chalcopyrite substrate and an overlying layer of an n-type ternary mixed metal compound wherein said ternary mixed metal compound is applied to said substrate by introducing the vapor of a first metal compound to a vessel containing said substrate from a first vapor source while simultaneously introducing a vapor of a second metal compound from a second vapor source of said vessel, said first and second metals comprising the metal components of said mixed metal compound; independently controlling the vaporization rate of said first and second vapor sources; reducing the mean free path between vapor particles in said vessel, said gas being present in an amount sufficient to induce homogeneity of said vapor mixture; and depositing said mixed metal compound on said substrate in the form of a uniform composition polycrystalline mixed metal compound. 5 figs.

  18. Use of sonication for in-well softening of semivolatile organic compounds. 1997 annual progress report

    SciTech Connect (OSTI)

    Peters, R.W.; Manning, J. [Argonne National Lab., IL (US); Hoffman, M.R. [California Inst. of Tech., Pasadena, CA (US); Gorelick, S. [Stanford Univ., CA (US)

    1997-01-01T23:59:59.000Z

    'This project investigates the in-situ degradation of semivolatile organic compounds (SVOCs) and volatile organic compounds (VOCs) using in-well sonication, in-well vapor stripping, and bioremediation. Pretreating groundwaters with sonication techniques in-situ would form VOCs that can be effectively removed by in-well vapor stripping and bioremediation. The mechanistic studies focus on the coupling of megasonics and ultrasonics to soften (i.e., partially degrade) the SVOCs; oxidative reaction mechanism studies; surface corrosion studies (on the reactor walls/well); enhancement due to addition of oxidants, quantification of the hydroxyl radical formation; identification/quantification of degradation products; volatility/degradability of the treated waters; development of a computer simulation model to describe combined in-well sonication/in-well vapor stripping/bioremediation; systems analysis/economic analysis; large laboratory-scale experiment verification; and field demonstration of the integrated technology. Benefits of this approach include: (1) Remediation is performed in-situ; (2) The treatment systems complement each other; their combination can drastically reduce or remove SVOCs and VOCs; (3) Ability to convert hard-to-degrade organics into more volatile organic compounds; (4) Ability to remove residual VOCs and softened SVOCs through the combined action of in-well vapor stripping and biodegradation; (5) Does not require handling or disposing of water at the ground surface; and (6) Cost-effective and improved efficiency, resulting in shortened clean-up times to remediate a site.'

  19. Workers Remove Glove Boxes from Ventilation at Hanford's Plutonium...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Remove Glove Boxes from Ventilation at Hanford's Plutonium Finishing Plant Workers Remove Glove Boxes from Ventilation at Hanford's Plutonium Finishing Plant January 28, 2015 -...

  20. Functionalized Nanoporous Silica for Removal of Heavy Metals...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoporous Silica for Removal of Heavy Metals from Biological Systems; Adsorption and Application. Functionalized Nanoporous Silica for Removal of Heavy Metals from Biological...

  1. Removing Barriers to Innovations: Related Codes and Standards...

    Energy Savers [EERE]

    Removing Barriers to Innovations: Related Codes and Standards CSI Team Removing Barriers to Innovations: Related Codes and Standards CSI Team This presentation was delivered at the...

  2. Y-12 Removes Nuclear Materials from Two Facilities to Reduce...

    National Nuclear Security Administration (NNSA)

    Home Field Offices Welcome to the NNSA Production Office NPO News Releases Y-12 Removes Nuclear Materials from Two Facilities ... Y-12 Removes Nuclear Materials from...

  3. Field Demonstration Of Permeable Reactive Barriers To Remove

    E-Print Network [OSTI]

    Field Demonstration Of Permeable Reactive Barriers To Remove Dissolved Uranium From Groundwater-001 November 2000 FIELD DEMONSTRATION OF PERMEABLE REACTIVE BARRIERS TO REMOVE DISSOLVED URANIUM FROM

  4. New Research Facility to Remove Hurdles to Offshore Wind and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research Facility to Remove Hurdles to Offshore Wind and Water Power Development New Research Facility to Remove Hurdles to Offshore Wind and Water Power Development January 10,...

  5. Selective Removal of Lanthanides from Natural Waters, Acidic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Removal of Lanthanides from Natural Waters, Acidic Streams and Dialysate. Selective Removal of Lanthanides from Natural Waters, Acidic Streams and Dialysate. Abstract: The...

  6. Oak Ridge Removes Laboratory's Greatest Source of Groundwater...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Removes Laboratory's Greatest Source of Groundwater Contamination Oak Ridge Removes Laboratory's Greatest Source of Groundwater Contamination May 1, 2012 - 12:00pm Addthis Workers...

  7. United States, International Partners Remove Last Remaining Weapons...

    Broader source: Energy.gov (indexed) [DOE]

    removed HEU under this effort are Austria, Chile, Czech Republic, Libya, Mexico, Romania, Serbia, Taiwan, Turkey, Ukraine, and Vietnam. To date, the Department has removed or...

  8. 241-AZ-101 pump removal trough analysis

    SciTech Connect (OSTI)

    Coverdell, B.L.

    1995-10-17T23:59:59.000Z

    As part of the current Hanford mission of environmental cleanup, various long length equipment must be removed from highly radioactive waste tanks. The removal of equipment will utilize portions of the Equipment Removal System for Project W320 (ERS-W320), specifically the 50 ton hydraulic trailer system. Because the ERS-W320 system was designed to accommodate much heavier equipment it is adequate to support the dead weight of the trough, carriage and related equipment for 241AZ101 pump removal project. However, the ERS-W320 components when combined with the trough and its` related components must also be analyzed for overturning due to wind loads. Two troughs were designed, one for the 20 in. diameter carriage and one for the 36 in. diameter carriage. A proposed 52 in. trough was not designed and, therefore is not included in this document. In order to fit in the ERS-W320 strongback the troughs were design with the same widths. Structurally, the only difference between the two troughs is that more material was removed from the stiffener plates on the 36 in trough. The reduction in stiffener plate material reduces the allowable load. Therefore, only the 36 in. trough was analyzed.

  9. Planning study, resin and debris removal system. Three Mile Island nuclear station unit 2 make-up and purification demineralizers

    SciTech Connect (OSTI)

    Renkey, E.J.; Jenkins, W.W.

    1983-06-01T23:59:59.000Z

    Various methods were evaluated to remove the resin and debris from the makeup and purification demineralizers. There are two preferred concepts. The existing waste disposal system should be utilized if some contamination of currently clean lines is acceptable. A skid mounted, temporary, upflow/downflow system should be utilized if the demineralizers and associated piping are to be cleaned to the maximum extent practicable with minimum contamination of the existing system. Both methods provide for removal of complex organic compounds from the effluent and elution of cesium from the resin. The resin and debris will be diluted with concrete to be disposed of in accordance with 10CFR61 burial limits.

  10. Method for etching thin films of niobium and niobium-containing compounds for preparing superconductive circuits

    DOE Patents [OSTI]

    Kampwirth, Robert T. (Darien, IL); Schuller, Ivan K. (Woodridge, IL); Falco, Charles M. (Woodridge, IL)

    1981-01-01T23:59:59.000Z

    An improved method of preparing thin film superconducting electrical circuits of niobium or niobium compounds in which a thin film of the niobium or niobium compound is applied to a nonconductive substrate, and covered with a layer of photosensitive material. The sensitive material is in turn covered with a circuit pattern exposed and developed to form a mask of the circuit in photoresistive material on the surface of the film. The unmasked excess niobium film is removed by contacting the substrate with an aqueous etching solution of nitric acid, sulfuric acid and hydrogen fluoride, which will rapidly etch the niobium compound without undercutting the photoresist. A modification of the etching solution will permit thin films to be lifted from the substrate without further etching.

  11. System for removal of arsenic from water

    DOE Patents [OSTI]

    Moore, Robert C.; Anderson, D. Richard

    2004-11-23T23:59:59.000Z

    Systems for removing arsenic from water by addition of inexpensive and commonly available magnesium oxide, magnesium hydroxide, calcium oxide, or calcium hydroxide to the water. The hydroxide has a strong chemical affinity for arsenic and rapidly adsorbs arsenic, even in the presence of carbonate in the water. Simple and commercially available mechanical systems for removal of magnesium hydroxide particles with adsorbed arsenic from drinking water can be used, including filtration, dissolved air flotation, vortex separation, or centrifugal separation. A system for continuous removal of arsenic from water is provided. Also provided is a system for concentrating arsenic in a water sample to facilitate quantification of arsenic, by means of magnesium or calcium hydroxide adsorption.

  12. Organic electronic devices using phthalimide compounds

    DOE Patents [OSTI]

    Hassan, Azad M.; Thompson, Mark E.

    2012-10-23T23:59:59.000Z

    Organic electronic devices comprising a phthalimide compound. The phthalimide compounds disclosed herein are electron transporters with large HOMO-LUMO gaps, high triplet energies, large reduction potentials, and/or thermal and chemical stability. As such, these phthalimide compounds are suitable for use in any of various organic electronic devices, such as OLEDs and solar cells. In an OLED, the phthalimide compounds may serve various functions, such as a host in the emissive layer, as a hole blocking material, or as an electron transport material. In a solar cell, the phthalimide compounds may serve various functions, such as an exciton blocking material. Various examples of phthalimide compounds which may be suitable for use in the present invention are disclosed.

  13. Organic electronic devices using phthalimide compounds

    DOE Patents [OSTI]

    Hassan, Azad M.; Thompson, Mark E.

    2010-09-07T23:59:59.000Z

    Organic electronic devices comprising a phthalimide compound. The phthalimide compounds disclosed herein are electron transporters with large HOMO-LUMO gaps, high triplet energies, large reduction potentials, and/or thermal and chemical stability. As such, these phthalimide compounds are suitable for use in any of various organic electronic devices, such as OLEDs and solar cells. In an OLED, the phthalimide compounds may serve various functions, such as a host in the emissive layer, as a hole blocking material, or as an electron transport material. In a solar cell, the phthalimide compounds may serve various functions, such as an exciton blocking material. Various examples of phthalimide compounds which may be suitable for use in the present invention are disclosed.

  14. Organic electronic devices using phthalimide compounds

    DOE Patents [OSTI]

    Hassan, Azad M.; Thompson, Mark E.

    2013-03-19T23:59:59.000Z

    Organic electronic devices comprising a phthalimide compound. The phthalimide compounds disclosed herein are electron transporters with large HOMO-LUMO gaps, high triplet energies, large reduction potentials, and/or thermal and chemical stability. As such, these phthalimide compounds are suitable for use in any of various organic electronic devices, such as OLEDs and solar cells. In an OLED, the phthalimide compounds may serve various functions, such as a host in the emissive layer, as a hole blocking material, or as an electron transport material. In a solar cell, the phthalimide compounds may serve various functions, such as an exciton blocking material. Various examples of phthalimide compounds which may be suitable for use in the present invention are disclosed.

  15. Process for removing metals from water

    DOE Patents [OSTI]

    Napier, J.M.; Hancher, C.M.; Hackett, G.D.

    1987-06-29T23:59:59.000Z

    A process for removing metals from water including the steps of prefiltering solids from the water, adjusting the pH to between about 2 and 3, reducing the amount of dissolved oxygen in the water, increasing the pH to between about 6 and 8, adding water-soluble sulfide to precipitate insoluble sulfide- and hydroxide-forming metals, adding a containing floc, and postfiltering the resultant solution. The postfiltered solution may optionally be eluted through an ion exchange resin to remove residual metal ions. 2 tabs.

  16. Process for removing metals from water

    DOE Patents [OSTI]

    Napier, John M. (Oak Ridge, TN); Hancher, Charles M. (Oak Ridge, TN); Hackett, Gail D. (Knoxville, TN)

    1989-01-01T23:59:59.000Z

    A process for removing metals from water including the steps of prefiltering solids from the water, adjusting the pH to between about 2 and 3, reducing the amount of dissolved oxygen in the water, increasing the pH to between about 6 and 8, adding water-soluble sulfide to precipitate insoluble sulfide- and hydroxide-forming metals, adding a flocculating agent, separating precipitate-containing floc, and postfiltering the resultant solution. The postfiltered solution may optionally be eluted through an ion exchange resin to remove residual metal ions.

  17. Removal of uranium from aqueous HF solutions

    DOE Patents [OSTI]

    Pulley, Howard (West Paducah, KY); Seltzer, Steven F. (Paducah, KY)

    1980-01-01T23:59:59.000Z

    This invention is a simple and effective method for removing uranium from aqueous HF solutions containing trace quantities of the same. The method comprises contacting the solution with particulate calcium fluoride to form uranium-bearing particulates, permitting the particulates to settle, and separting the solution from the settled particulates. The CaF.sub.2 is selected to have a nitrogen surface area in a selected range and is employed in an amount providing a calcium fluoride/uranium weight ratio in a selected range. As applied to dilute HF solutions containing 120 ppm uranium, the method removes at least 92% of the uranium, without introducing contaminants to the product solution.

  18. Sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, Evan J.; Hargis, Richard A.; Pennline, Henry W.

    1998-01-01T23:59:59.000Z

    A review of the various promoters and sorbents examined for the removal of mercury from flue gas is presented. Commercial sorbent processes are described along with the chemistry of the various sorbent-mercury interactions. Novel sorbents for removing mercury from flue gas are suggested. Since activated carbons are expensive, alternate sorbents and/or improved activated carbons are needed. Because of their lower cost, sorbent development work can focus on base metal oxides and halides. Additionally, the long-term sequestration of the mercury on the sorbent needs to be addressed. Contacting methods between the flue gas and the sorbent also merit investigation.

  19. Heat treatment of exchangers to remove coke

    SciTech Connect (OSTI)

    Turner, J.D.

    1990-02-20T23:59:59.000Z

    This patent describes a process for preparing furfural coke for removal from metallic surfaces. It comprises: heating the furfural coke without causing an evolution of heat capable of undesirably altering metallurgical properties of the surfaces in the presence of a gas containing molecular oxygen at a sufficient temperature below 800{degrees}F (427{degrees}C) for a sufficient time to change the crush strength of the coke so as to permit removal with a water jet at a pressure of five thousand pounds per square inch.

  20. Oxygen stabilized zirconium vanadium intermetallic compound

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Woodridge, IL); Gruen, Dieter M. (Downers Grove, IL)

    1982-01-01T23:59:59.000Z

    An oxygen stabilized intermetallic compound having the formula Zr.sub.x OV.sub.y where x=0.7 to 2.0 and y=0.18 to 0.33. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 450.degree. C. at pressures down to 10.sup.-6 Torr. The compound is also capable of selectively sorbing hydrogen from gaseous mixtures in the presence of CO and CO.sub.2.

  1. Recommendation 183: Preferred Alternative for the Removal of Hexavalent Chromium

    Broader source: Energy.gov [DOE]

    The ORSSAB Recommendation to DOE on the Preferred Alternative for the Removal of Hexavalent Chromium.

  2. Removal of hydrogen sulfide from waste treatment plant biogas using the apollo scrubber

    SciTech Connect (OSTI)

    Smith, J.W.; Burrowes, P.A.; Gupta, A.; Walton, P.S.; Meffe, S.

    1996-12-31T23:59:59.000Z

    The removal of hydrogen sulfide and other sulphur compounds from anaerobic digester gas streams prior to their use as fuel for boilers, stationary engines, and cogeneration units minimizes corrosion problems and reduces sulfur emission loadings. A research program at the Department of Chemical Engineering and Applied Chemistry, University of Toronto in the 1980`s demonstrated the use of a modified flotation cell for the absorption of hydrogen sulfide from a gas stream and its catalytic oxidation to sulfur. The essence of the technology was a proprietary gas liquid contactor which provided very high mass transfer rates at the interface. A bench scale contactor developed at the university achieved hydrogen sulfide removal efficiencies of over 99.9% at atmospheric pressure. A demonstration unit for digester gas scrubbing applications was designed, fabricated, and then installed and evaluated at the Metropolitan Toronto Works Department - Main Treatment Plant (MTP).

  3. ASBESTOS PIPE-INSULATION REMOVAL ROBOT SYSTEM

    SciTech Connect (OSTI)

    Unknown

    2000-09-15T23:59:59.000Z

    This final topical report details the development, experimentation and field-testing activities for a robotic asbestos pipe-insulation removal robot system developed for use within the DOE's weapon complex as part of their ER and WM program, as well as in industrial abatement. The engineering development, regulatory compliance, cost-benefit and field-trial experiences gathered through this program are summarized.

  4. Removed Barriers: 3.32 Knowledge

    E-Print Network [OSTI]

    Fabrikant, Sara Irina

    Students Average Values from Entry and Exit Surveys for Participants in 2006 Workshops ENTRY 1 BarriersResults EXIT 2 Removed Barriers: 3.32 Knowledge 3.67 GIS 3.46 Data Access 3.68 Software Use 3

  5. Method of preparation of removable syntactic foam

    DOE Patents [OSTI]

    Arnold, Jr., Charles (Albuquerque, NM); Derzon, Dora K. (Albuquerque, NM); Nelson, Jill S. (Albuquerque, NM); Rand, Peter B. (Albuquerque, NM)

    1995-01-01T23:59:59.000Z

    Easily removable, environmentally safe, low-density, syntactic foams are disclosed which are prepared by mixing insoluble microballoons with a solution of water and/or alcohol-soluble polymer to produce a pourable slurry, optionally vacuum filtering the slurry in varying degrees to remove unwanted solvent and solute polymer, and drying to remove residual solvent. The properties of the foams can be controlled by the concentration and physical properties of the polymer, and by the size and properties of the microballoons. The suggested solute polymers are non-toxic and soluble in environmentally safe solvents such as water or low-molecular weight alcohols. The syntactic foams produced by this process are particularly useful in those applications where ease of removability is beneficial, and could find use in packaging recoverable electronic components, in drilling and mining applications, in building trades, in art works, in the entertainment industry for special effects, in manufacturing as temporary fixtures, in agriculture as temporary supports and containers and for delivery of fertilizer, in medicine as casts and splints, as temporary thermal barriers, as temporary protective covers for fragile objects, as filters for particulate matter, which matter may be easily recovered upon exposure to a solvent, as in-situ valves (for one-time use) which go from maximum to minimum impedance when solvent flows through, and for the automatic opening or closing of spring-loaded, mechanical switches upon exposure to a solvent, among other applications.

  6. Method of preparation of removable syntactic foam

    DOE Patents [OSTI]

    Arnold, C. Jr.; Derzon, D.K.; Nelson, J.S.; Rand, P.B.

    1995-07-11T23:59:59.000Z

    Easily removable, environmentally safe, low-density, syntactic foams are disclosed which are prepared by mixing insoluble microballoons with a solution of water and/or alcohol-soluble polymer to produce a pourable slurry, optionally vacuum filtering the slurry in varying degrees to remove unwanted solvent and solute polymer, and drying to remove residual solvent. The properties of the foams can be controlled by the concentration and physical properties of the polymer, and by the size and properties of the microballoons. The suggested solute polymers are non-toxic and soluble in environmentally safe solvents such as water or low-molecular weight alcohols. The syntactic foams produced by this process are particularly useful in those applications where ease of removability is beneficial, and could find use in packaging recoverable electronic components, in drilling and mining applications, in building trades, in art works, in the entertainment industry for special effects, in manufacturing as temporary fixtures, in agriculture as temporary supports and containers and for delivery of fertilizer, in medicine as casts and splints, as temporary thermal barriers, as temporary protective covers for fragile objects, as filters for particulate matter, which matter may be easily recovered upon exposure to a solvent, as in-situ valves (for one-time use) which go from maximum to minimum impedance when solvent flows through, and for the automatic opening or closing of spring-loaded, mechanical switches upon exposure to a solvent, among other applications. 1 fig.

  7. Bioreactors for Removing Methyl Bromide following Contained

    E-Print Network [OSTI]

    Bioreactors for Removing Methyl Bromide following Contained Fumigations L A U R E N C E G . M I L L contributes to the depletion of stratospheric ozone. A closed-system bioreactor consisting of 0.5 L recirculating air. Strain IMB-1 grew slowly to high cell densities in the bioreactor using MeBr as its sole

  8. Plastic bottles > Remove lids (not recyclable)

    E-Print Network [OSTI]

    Brierley, Andrew

    Plastic bottles Please: > Remove lids (not recyclable) > Empty bottles > Rinse milk bottles, & other bottles if possible > Squash bottles www.st-andrews.ac.uk/estates/environment All types of plastic bottle accepted Clear, opaque and coloured bottles Labels can remain on X No plastic bags X No plastics

  9. MODELING OF PARTICULATE REMOVAL IN MIXED MEDIA

    E-Print Network [OSTI]

    Clark, Shirley E.

    versus Downflow Modes DATA COLLECTION #12;4 UPFLOW CONTRUCTION #12;5 UPFLOW FILTRATION RESULTS · Drawback to downflow filtration is the need for pretreatment. Upflow filtration may remove need for pretreatment-specific, and transfer of data from lab-scale to field is not applicable. ACKNOWLEDGMENTS Anitha Balakrishnan, UAB Renee

  10. Pentek metal coating removal system: Baseline report

    SciTech Connect (OSTI)

    NONE

    1997-07-31T23:59:59.000Z

    The Pentek coating removal technology was tested and is being evaluated at Florida International University (FIU) as a baseline technology. In conjunction with FIU`s evaluation of efficiency and cost, this report covers evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The Pentek coating removal system consisted of the ROTO-PEEN Scaler, CORNER-CUTTER{reg_sign}, and VAC-PAC{reg_sign}. They are designed to remove coatings from steel, concrete, brick, and wood. The Scaler uses 3M Roto Peen tungsten carbide cutters while the CORNER-CUTTER{reg_sign} uses solid needles for descaling activities. These hand tools are used with the VAC-PAC{reg_sign} vacuum system to capture dust and debris as removal of the coating takes place. The safety and health evaluation during the testing demonstration focused on two main areas of exposure: dust and noise. Dust exposure minimal, but noise exposure was significant. Further testing for each exposure is recommended because of the environment where the testing demonstration took place. It is feasible that the dust and noise levels will be higher in an enclosed operating environment of different construction. In addition, other areas of concern found were arm-hand vibration, whole-body, ergonomics, heat stress, tripping hazards, electrical hazards, machine guarding, and lockout/tagout.

  11. NNSA B-Roll: Fuel Removals

    SciTech Connect (OSTI)

    2010-05-21T23:59:59.000Z

    The National Nuclear Security Administration established the Global Threat Reduction Initiative (GTRI) to identify, secure, remove and/or facilitate the disposition of high risk vulnerable nuclear and radiological materials around the world, as quickly as possible, that pose a threat to the United States and the international community.

  12. ADVANCED OXIDATION PROCESSES FOR THE REMOVAL OF

    E-Print Network [OSTI]

    Boyer, Edmond

    ADVANCED OXIDATION PROCESSES FOR THE REMOVAL OF RESIDUAL NON-STEROIDAL ANTI- INFLAMMATORY. G. Esposito, PhD, MSc Associate Professor of Sanitary and Environmental Engineering University in Biogeochemistry University of Paris-Est Paris, France Prof. dr. ir P.N.L. Lens Professor of Biotechnology UNESCO

  13. Method of removing cesium from steam

    DOE Patents [OSTI]

    Carson, Jr., Neill J. (Clarendon Hills, IL); Noland, Robert A. (Oak Park, IL); Ruther, Westly E. (Skokie, IL)

    1991-01-01T23:59:59.000Z

    Method for removal of radioactive cesium from a hot vapor, such as high temperature steam, including the steps of passing input hot vapor containing radioactive cesium into a bed of silicate glass particles and chemically incorporating radioactive cesium in the silicate glass particles at a temperature of at least about 700.degree. F.

  14. Decontaminating Human Judgments by Removing Sequential Dependencies

    E-Print Network [OSTI]

    Mozer, Michael C.

    Decontaminating Human Judgments by Removing Sequential Dependencies Michael C. Mozer, Harold, and thereby decontaminate a series of ratings to obtain more meaningful human judgments. In our formulation, decontamination is fun- damentally a problem of inferring latent states (internal sensations) which, be- cause

  15. Forecast Technical Document Felling and Removals

    E-Print Network [OSTI]

    of local investment and business planning. Timber volume production will be estimated at sub. Planning of operations. Control of the growing stock. Wider reporting (under UKWAS). The calculation fellings and removals are handled in the 2011 Production Forecast system. Tom Jenkins Robert Matthews Ewan

  16. Removal of a Permanent IVC Filter

    SciTech Connect (OSTI)

    Kumar, Bangalore C. Anil [Queen's Medical Centre, Department of Radiology (United Kingdom)], E-mail: anil.kumar@doctors.org.uk; Chakraverty, Sam; Zealley, Ian [Ninewells Hospital, Department of Radiology (United Kingdom)

    2006-02-15T23:59:59.000Z

    Inferior vena cava (IVC) filters are increasingly used for prevention of life-threatening pulmonary emboli in patients who have contraindications to anticoagulation therapy. We report a case of the removal of a permanent IVC filter, which was inadvertently inserted due to an incorrect ultrasound report.

  17. Catalytic two-stage coal liquefaction process having improved nitrogen removal

    DOE Patents [OSTI]

    Comolli, Alfred G. (Yardley, PA)

    1991-01-01T23:59:59.000Z

    A process for catalytic multi-stage hydrogenation and liquefaction of coal to produce high yields of low-boiling hydrocarbon liquids containing low concentrations of nitogen compounds. First stage catalytic reaction conditions are 700.degree.-800.degree. F. temperature, 1500-3500 psig hydrogen partial pressure, with the space velocity maintained in a critical range of 10-40 lb coal/hr ft.sup.3 catalyst settled volume. The first stage catalyst has 0.3-1.2 cc/gm total pore volume with at least 25% of the pore volume in pores having diameters of 200-2000 Angstroms. Second stage reaction conditions are 760.degree.-870.degree. F. temperature with space velocity exceeding that in the first stage reactor, so as to achieve increased hydrogenation yield of low-boiling hydrocarbon liquid products having at least 75% removal of nitrogen compounds from the coal-derived liquid products.

  18. Characterization of nickel and vanadium compounds in tar sand bitumen by petroporphyrin quantitation and size exclusion chromatography coupled with element specific detection

    SciTech Connect (OSTI)

    Reynolds, J.G.; Jones, E.L.; Bennett, J.A.; Biggs, W.R.

    1988-02-01T23:59:59.000Z

    Previously, we have examined the Ni and V in heavy crude oils, residua, and processed products by several metal speciation techniques to ascertain molecular structure and processing behavior. Two classes of metal compounds were found/--/metallopetroporphyrins and metallo-nonporphyrins/--/each having unique reactivity during processing. In efforts to better understand the binding of metals in the oil medium, we have now examined Ni and V in tar sand bitumens. The bitumen was solvent extracted from the sand matrix and was separated by column chromatography to quantitate petroporphyrin content. The petroporphyrin contents ranged from virtually none to over 36% of the total metals. Asphalt Ridge (Utah) has primarily Ni petroporphyrins; Big Clifty (Kentucky) and Athabasca (Canada) have primarily V petroporphyrins; Arroyo Grande and McKittrick (California) have roughly equal amounts of both types; and Sunnyside (Utah) has virtually none of either. Size characteristic profiles (SEC-HPLC-ICP) were generated for the extracted bitumens. The profiles are generally bimodal in shape and resemble several different specific heavy crude oils and residua. For examples, Arroyo Grande and McKittrick appear to be similar to Kern River (California) 650/degree/F+ residuum, while Athabasca resembles Morichal (Venezuela) 650/degree/F+ residuum. These results will be discussed in terms of generalized profile and petroporphyrin behavior. 23 refs., 3 figs., 3 tabs.

  19. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, David K. (San Pablo, CA); Chang, Shih-Ger (El Cerrito, CA)

    1989-01-01T23:59:59.000Z

    A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

  20. Hydraulic dredging, a sediment removal technique

    SciTech Connect (OSTI)

    Spotts, J.W.

    1980-12-01T23:59:59.000Z

    Sediment was successfully removed from a Peabody Coal Company pond near Macon, Missouri, by a Mud Cat Model SP-810 hydraulic dredge. Previous attempts using land-based equipment had been unsatisfactory. The hydraulic-powered auger and submerged pump easily removed 882 m/sup 3/ (1154 yd/sup 3/) and pumped the slurry a distance of 305 m (1000 ft) to a disposal area. The hydraulic dredge was more effective and cheaper to operate than land-based equipment. The dredge cost was $1.31/m/sup 3/ ($1.00/yd/sup 3/), the dragline cost was $6.54/m/sup 3/ ($5.00/yd/sup 3/) and the front-end loader cost was $15.70/m/sup 3/ ($12.00/yd/sup 3/), under optimum conditions.

  1. Method of arsenic removal from water

    DOE Patents [OSTI]

    Gadgil, Ashok (El Cerrito, CA)

    2010-10-26T23:59:59.000Z

    A method for low-cost arsenic removal from drinking water using chemically prepared bottom ash pre-treated with ferrous sulfate and then sodium hydroxide. Deposits on the surface of particles of bottom ash form of activated iron adsorbent with a high affinity for arsenic. In laboratory tests, a miniscule 5 grams of pre-treated bottom ash was sufficient to remove the arsenic from 2 liters of 2400 ppb (parts per billion) arsenic-laden water to a level below 50 ppb (the present United States Environmental Protection Agency limit). By increasing the amount of pre-treated bottom ash, even lower levels of post-treatment arsenic are expected. It is further expected that this invention supplies a very low-cost solution to arsenic poisoning for large population segments.

  2. Removal of fluoride from aqueous nitric acid

    SciTech Connect (OSTI)

    Pruett, D.J.; Howerton, W.B.; Mailen, J.C.

    1981-06-01T23:59:59.000Z

    Several methods for removing fluoride from aqueous nitric acid were investigated and compared with the frequently used aluminum nitrate-calcium nitrate (Ca/sup 2 +/-Al/sup 3 +/) chemical trap-distillation system. Zirconium oxynitrate solutions were found to be superior in preventing volatilization of fluoride during distillation of the nitric acid, producing decontamination factors (DFs) on the order of 2 x 10/sup 3/ (vs approx. 500 for the Ca/sup 2 +/-Al/sup 3 +/ system). Several other metal nitrate systems were tested, but they were less effective. Alumina and zirconia columns proved highly effective in removing HF from HF-HNO/sub 3/ vapors distilled through the columns; fluoride DFs on the order of 10/sup 6/ and 10/sup 4/, respectively, were obtained. A silica gel column was very effective in adsorbing HF from HF-HNO/sub 3/ solutions, producing a fluoride DF of approx. 10/sup 4/.

  3. Fly ash enhanced metal removal process

    SciTech Connect (OSTI)

    Nonavinakere, S. [Plexus Scientific Corp., Annapolis, MD (United States); Reed, B.E. [West Virginia Univ., Morgantown, WV (United States). Dept. of Civil Engineering

    1995-12-31T23:59:59.000Z

    The primary objective of the study was to evaluate the effectiveness of fly ashes from local thermal power plants in the removal of cadmium, nickel, chromium, lead, and copper from aqueous waste streams. Physical and chemical characteristics of fly ashes were determined, batch isotherm studies were conducted. A practical application of using fly ash in treating spent electroless nickel (EN) plating baths by modified conventional precipitation or solid enhanced metal removal process (SEMR) was investigated. In addition to nickel the EN baths also contains completing agents such as ammonium citrate and succinic acid reducing agents such as phosphate and hypophosphite. SEMR experiments were conducted at different pHs, fly ash type and concentrations, and settling times.

  4. Acid treatment removes zinc sulfide scale restriction

    SciTech Connect (OSTI)

    Biggs, K. (Kerr McGee Corp., Lafayette, LA (US)); Allison, D. (Otis Engineering Corp., Lafayette, LA (US)); Ford, W.G.F. (Halliburton Co., Duncan, OK (United States))

    1992-08-31T23:59:59.000Z

    This paper reports that removal of zinc sulfide (ZnS) scale with acid restored an offshore Louisiana well's production to original rates. The zinc sulfide scale was determined to be in the near well bore area. The selected acid had been proven to control iron sulfide (FeS) scales in sour wells without causing harm to surface production equipment, tubing, and other downhole hardware. The successful removal of the blockage re-established previous production rates with a 105% increase in flowing tubing pressure. On production for a number of months, a high rate, high-pressure offshore well was experiencing unusually rapid pressure and rate declines. A small sample of the restrictive material was obtained during the wire line operations. The well was subsequently shut in while a laboratory analysis determined that zinc sulfide was the major component of the obstruction.

  5. Photoacoustic removal of occlusions from blood vessels

    DOE Patents [OSTI]

    Visuri, Steven R. (Livermore, CA); Da Silva, Luiz B. (Danville, CA); Celliers, Peter M. (Berkeley, CA); London, Richard A. (Orinda, CA); Maitland, IV, Duncan J. (Lafayette, CA); Esch, Victor C. (San Francisco, CA)

    2002-01-01T23:59:59.000Z

    Partial or total occlusions of fluid passages within the human body are removed by positioning an array of optical fibers in the passage and directing treatment radiation pulses along the fibers, one at a time, to generate a shock wave and hydrodynamics flows that strike and emulsify the occlusions. A preferred application is the removal of blood clots (thrombin and embolic) from small cerebral vessels to reverse the effects of an ischemic stroke. The operating parameters and techniques are chosen to minimize the amount of heating of the fragile cerebral vessel walls occurring during this photo acoustic treatment. One such technique is the optical monitoring of the existence of hydrodynamics flow generating vapor bubbles when they are expected to occur and stopping the heat generating pulses propagated along an optical fiber that is not generating such bubbles.

  6. Oil removal from water via adsorption

    E-Print Network [OSTI]

    Jacobs, William Edward

    1973-01-01T23:59:59.000Z

    . Inorganic adsorbents, such as perlite and glass wool, do not have high oil adsorption capacities compared to organ- ics and the capacities are dependent on the viscosity of the oils. The inorganic adsorbents have higher oil adsorption capacities in more... IV Table V Table VI Significant Facts about Major Oil Spills Viscosity of Test Oils Determined by Capillary Viscometer Percent of Oil Remaining in Water After Removal of Oil-Carrier Combination Maximum Oil Adsorption Capacity for Light Crude...

  7. REMOVAL OF LEGACY PLUTONIUM MATERIALS FROM SWEDEN

    SciTech Connect (OSTI)

    Dunn, Kerry A. [Savannah River National Laboratory; Bellamy, J. Steve [Savannah River National Laboratory; Chandler, Greg T. [Savannah River National Laboratory; Iyer, Natraj C. [U.S. Department of Energy, National Nuclear Security Administration, Office of; Koenig, Rich E.; Leduc, D. [Savannah River National Laboratory; Hackney, B. [Savannah River National Laboratory; Leduc, Dan R. [Savannah River National Laboratory

    2013-08-18T23:59:59.000Z

    U.S. Department of Energy’s National Nuclear Security Administration (NNSA) Office of Global Threat Reduction (GTRI) recently removed legacy plutonium materials from Sweden in collaboration with AB SVAFO, Sweden. This paper details the activities undertaken through the U.S. receiving site (Savannah River Site (SRS)) to support the characterization, stabilization, packaging and removal of legacy plutonium materials from Sweden in 2012. This effort was undertaken as part of GTRI’s Gap Materials Program and culminated with the successful removal of plutonium from Sweden as announced at the 2012 Nuclear Security Summit. The removal and shipment of plutonium materials to the United States was the first of its kind under NNSA’s Global Threat Reduction Initiative. The Environmental Assessment for the U.S. receipt of gap plutonium material was approved in May 2010. Since then, the multi-year process yielded many first time accomplishments associated with plutonium packaging and transport activities including the application of the of DOE-STD-3013 stabilization requirements to treat plutonium materials outside the U.S., the development of an acceptance criteria for receipt of plutonium from a foreign country, the development and application of a versatile process flow sheet for the packaging of legacy plutonium materials, the identification of a plutonium container configuration, the first international certificate validation of the 9975 shipping package and the first intercontinental shipment using the 9975 shipping package. This paper will detail the technical considerations in developing the packaging process flow sheet, defining the key elements of the flow sheet and its implementation, determining the criteria used in the selection of the transport package, developing the technical basis for the package certificate amendment and the reviews with multiple licensing authorities and most importantly integrating the technical activities with the Swedish partners.

  8. Removal of copper from ferrous scrap

    DOE Patents [OSTI]

    Blander, M.; Sinha, S.N.

    1987-07-30T23:59:59.000Z

    A process for removing copper from ferrous or other metal scrap in which the scrap is contacted with a polyvalent metal sulfide slag in the presence of an excess of copper-sulfide forming additive to convert the copper to copper sulfide which is extracted into the slag to provide a ratio of copper in the slag to copper in the metal scrap of at least about 10.

  9. Removal of copper from ferrous scrap

    DOE Patents [OSTI]

    Blander, M.; Sinha, S.N.

    1990-05-15T23:59:59.000Z

    A process for removing copper from ferrous or other metal scrap in which the scrap is contacted with a polyvalent metal sulfide slag in the presence of an excess of copper-sulfide forming additive to convert the copper to copper sulfide which is extracted into the slag to provide a ratio of copper in the slag to copper in the metal scrap of at least about 10.

  10. Removal of copper from ferrous scrap

    DOE Patents [OSTI]

    Blander, Milton (12833 S. 82nd Ct., Palos Park, IL 60464); Sinha, Shome N. (5748 Drexel, 2A, Chicago, IL 60637)

    1990-01-01T23:59:59.000Z

    A process for removing copper from ferrous or other metal scrap in which the scrap is contacted with a polyvalent metal sulfide slag in the presence of an excess of copper-sulfide forming additive to convert the copper to copper sulfide which is extracted into the slag to provide a ratio of copper in the slag to copper in the metal scrap of at least about 10.

  11. Purificaiton of Lanthanides for Large Neutrino Detectors: Thorium Removal from Gadolinium Chloride

    SciTech Connect (OSTI)

    Yeh, M.; Cumming, J.B.; Hans, S.; Hahn, R.L.

    2010-06-01T23:59:59.000Z

    Metal-loaded liquid scintillators are the detectors of choice for various neutrino experiments. Procedures have been developed to transfer metals into organic liquids by solvent extraction or direct dissolution of a metallic compound. Traces of natural radioactivity introduced into the scintillator with the metal may produce undesirable backgrounds. Measurements using a {sup 229}Th tracer indicate that the inclusion of a pH-controlled partial hydrolysis and filtration prior to the preparation of a gadolinium-loading compound can reduce thorium by a factor of {approx}100. This 'self-scavenging' procedure has the advantage that it uses only reagents encountered in the production process. Addition of non-elemental scavengers such as iron, or the use of solvent extraction or ion exchange procedures can be avoided. It also improves the optical transmission in the blue region by removing traces of iron. This purification method has potential applications to the large-scale production of other metal-loaded liquid scintillators and for the removal of traces of thorium in the industrial production of lanthanides.

  12. Digital Construction Platform: A Compound Arm Approach

    E-Print Network [OSTI]

    Spielberg, Nathan A.

    2014-01-01T23:59:59.000Z

    We introduce a novel large-scale Digital Construction Platform (DCP) for on-site sensing, analysis, and fabrication. The DCP is an in-progress research project consisting of a compound robotic arm system comprised of a ...

  13. Production method for making rare earth compounds

    DOE Patents [OSTI]

    McCallum, R. William (Ames, IA); Ellis, Timothy W. (Ames, IA); Dennis, Kevin W. (Ames, IA); Hofer, Robert J. (Ames, IA); Branagan, Daniel J. (Ames, IA)

    1997-11-25T23:59:59.000Z

    A method of making a rare earth compound, such as a earth-transition metal permanent magnet compound, without the need for producing rare earth metal as a process step, comprises carbothermically reacting a rare earth oxide to form a rare earth carbide and heating the rare earth carbide, a compound-forming reactant (e.g. a transition metal and optional boron), and a carbide-forming element (e.g. a refractory metal) that forms a carbide that is more thermodynamically favorable than the rare earth carbide whereby the rare earth compound (e.g. Nd.sub.2 Fe.sub.14 B or LaNi.sub.5) and a carbide of the carbide-forming element are formed.

  14. Production method for making rare earth compounds

    DOE Patents [OSTI]

    McCallum, R.W.; Ellis, T.W.; Dennis, K.W.; Hofer, R.J.; Branagan, D.J.

    1997-11-25T23:59:59.000Z

    A method of making a rare earth compound, such as a earth-transition metal permanent magnet compound, without the need for producing rare earth metal as a process step, comprises carbothermically reacting a rare earth oxide to form a rare earth carbide and heating the rare earth carbide, a compound-forming reactant (e.g., a transition metal and optional boron), and a carbide-forming element (e.g., a refractory metal) that forms a carbide that is more thermodynamically favorable than the rare earth carbide whereby the rare earth compound (e.g., Nd{sub 2}Fe{sub 14}B or LaNi{sub 5}) and a carbide of the carbide-forming element are formed.

  15. Moab Mill Tailings Removal Project Celebrates 5 Years of Success...

    Office of Environmental Management (EM)

    Moab Mill Tailings Removal Project Celebrates 5 Years of Success Moab Mill Tailings Removal Project Celebrates 5 Years of Success October 3, 2012 - 12:00pm Addthis Pictured here is...

  16. Removing nuclear waste, one shipment at a time

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stories Removing nuclear waste, one shipment at a time Removing nuclear waste, one shipment at a time The Lab's 1,000th shipment of transuranic waste recently left Los Alamos,...

  17. Process for selected gas oxide removal by radiofrequency catalysts

    DOE Patents [OSTI]

    Cha, Chang Y. (3807 Reynolds St., Laramie, WY 82070)

    1993-01-01T23:59:59.000Z

    This process to remove gas oxides from flue gas utilizes adsorption on a char bed subsequently followed by radiofrequency catalysis enhancing such removal through selected reactions. Common gas oxides include SO.sub.2 and NO.sub.x.

  18. Process for removing technetium from iron and other metals

    DOE Patents [OSTI]

    Leitnaker, James M. (Kingston, TN); Trowbridge, Lee D. (Oak Ridge, TN)

    1999-01-01T23:59:59.000Z

    A process for removing technetium from iron and other metals comprises the steps of converting the molten, alloyed technetium to a sulfide dissolved in manganese sulfide, and removing the sulfide from the molten metal as a slag.

  19. Process for removing technetium from iron and other metals

    DOE Patents [OSTI]

    Leitnaker, J.M.; Trowbridge, L.D.

    1999-03-23T23:59:59.000Z

    A process for removing technetium from iron and other metals comprises the steps of converting the molten, alloyed technetium to a sulfide dissolved in manganese sulfide, and removing the sulfide from the molten metal as a slag. 4 figs.

  20. Aza crown ether compounds as anion receptors

    DOE Patents [OSTI]

    Lee, H.S.; Yang, X.O.; McBreen, J.

    1998-08-04T23:59:59.000Z

    A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the new family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of LI{sup +} ion in alkali metal batteries. 3 figs.

  1. Removal of Heavy Metals from Aqueous Systems with Thiol Functionalized...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heavy Metals from Aqueous Systems with Thiol Functionalized Superparamagnetic Nanoparticles. Removal of Heavy Metals from Aqueous Systems with Thiol Functionalized...

  2. Method for removing fluoride contamination from nitric acid

    SciTech Connect (OSTI)

    Howerton, W.B.; Pruett, D.J.

    1982-07-13T23:59:59.000Z

    Fluoride ions are removed from nitric acid solution by contacting the vaporized solution with alumina or zirconium.

  3. Electrostatic Dust Detection and Removal for ITER

    SciTech Connect (OSTI)

    C.H. Skinner; A. Campos; H. Kugel; J. Leisure; A.L. Roquemore; S. Wagner

    2008-09-01T23:59:59.000Z

    We present some recent results on two innovative applications of microelectronics technology to dust inventory measurement and dust removal in ITER. A novel device to detect the settling of dust particles on a remote surface has been developed in the laboratory. A circuit board with a grid of two interlocking conductive traces with 25 ?m spacing is biased to 30 – 50 V. Carbon particles landing on the energized grid create a transient short circuit. The current flowing through the short circuit creates a voltage pulse that is recorded by standard nuclear counting electronics and the total number of counts is related to the mass of dust impinging on the grid. The particles typically vaporize in a few seconds restoring the previous voltage standoff. Experience on NSTX however, showed that in a tokamak environment it was still possible for large particles or fibers to remain on the grid causing a long term short circuit. We report on the development of a gas puff system that uses helium to clear such particles. Experiments with varying nozzle designs, backing pressures, puff durations, and exit flow orientations have given an optimal configuration that effectively removes particles from an area up to 25 cm² with a single nozzle. In a separate experiment we are developing an advanced circuit grid of three interlocking traces that can generate a miniature electrostatic traveling wave for transporting dust to a suitable exit port. We have fabricated such a 3-pole circuit board with 25 micron insulated traces that operates with voltages up to 200 V. Recent results showed motion of dust particles with the application of only 50 V bias voltage. Such a device could potentially remove dust continuously without dedicated interventions and without loss of machine availability for plasma operations.

  4. 9. Analysis a. Analysis tools for dam removal

    E-Print Network [OSTI]

    Tullos, Desiree

    (Randle 2003). Mechanical removal, or dredging, involves removing some or all of the reservoir sediment infrastructure and landowners, downstream confinement, presence of threatened and endangered species, and cost in stages) and type (fine or contaminated sediment can be removed through dredging prior to sediment release

  5. INVESTIGATION OF IONIC CONTAMINATION REMOVAL FROM SILICON DIOXIDE SURFACES

    E-Print Network [OSTI]

    Suni, Ian Ivar

    INVESTIGATION OF IONIC CONTAMINATION REMOVAL FROM SILICON DIOXIDE SURFACES H. Lin, A. A. Busnaina, and I. I. Suni T he removal of ionic contaminants from silicon surfaces surface contamination level canM Communications L td. INTRODUCTION with increasing frequency and power, and decreases Contamination removal is one

  6. Ultracapacitor having residual water removed under vacuum

    DOE Patents [OSTI]

    Wei, Chang (Niskayuna, NY); Jerabek, Elihu Calvin (Glenmont, NY); Day, James (Scotia, NY)

    2002-10-15T23:59:59.000Z

    A multilayer cell is provided that comprises two solid, nonporous current collectors, two porous electrodes separating the current collectors, a porous separator between the electrodes and an electrolyte occupying pores in the electrodes and separator. The mutilayer cell is electrolyzed to disassociate water within the cell to oxygen gas and hydrogen gas. A vacuum is applied to the cell substantially at the same time as the electrolyzing step, to remove the oxygen gas and hydrogen gas. The cell is then sealed to form a ultracapacitor substantially free from water.

  7. Specific energy for laser removal of rocks.

    SciTech Connect (OSTI)

    Xu, Z.; Kornecki, G.; Reed, C. B.; Gahan, B. C.; Parker, R. A.; Batarseh, S.; Graves, R. M.

    2001-08-16T23:59:59.000Z

    Application of advanced high power laser technology into oil and gas well drilling has been attracting significant research interests recently among research institutes, petroleum industries, and universities. Potential laser or laser-aided oil and gas well drilling has many advantages over the conventional rotary drilling, such as high penetration rate, reduction or elimination of tripping, casing, and bit costs, and enhanced well control, perforating and side-tracking capabilities. The energy required to remove a unit volume of rock, namely the specific energy (SE), is a critical rock property data that can be used to determine both the technical and economic feasibility of laser oil and gas well drilling.

  8. The influence of Streptococcus spp., Lactobacillus spp. and Pediococcus spp. on production of volatile sulfhydryl compounds in Cheddar cheese slurries

    E-Print Network [OSTI]

    Dagerath, Michael Lynn

    1989-01-01T23:59:59.000Z

    resulted from the failure of the direct acidified cheese to reach and maintain the low oxidation- reduction potential needed for volatile compound existence (21, 22). With the exception of hydrogen sulfide (51, 24), it does not appear that lactobacilli... 19 dimethyl sulfide (Aldrich Chemicals, Milwaukee, Wisconsin) into a plastic pouch with 500 ml of previously added nitrogen. The pouch was incubated at 30 ~C. One ml of the gas mixture was removed and injected into a second pouch which contained...

  9. Reduced weight decontamination formulation utilizing a solid peracid compound for neutralization of chemical and biological warfare agents

    DOE Patents [OSTI]

    Tucker, Mark D. (Albuquerque, NM)

    2011-09-20T23:59:59.000Z

    A reduced weight decontamination formulation that utilizes a solid peracid compound (sodium borate peracetate) and a cationic surfactant (dodecyltrimethylammonium chloride) that can be packaged with all water removed. This reduces the packaged weight of the decontamination formulation by .about.80% (as compared to the "all-liquid" DF-200 formulation) and significantly lowers the logistics burden on the warfighter. Water (freshwater or saltwater) is added to the new decontamination formulation at the time of use from a local source.

  10. Photochemical removal of NpF sub 6 and PuF sub 6 from UF sub 6 gas streams

    SciTech Connect (OSTI)

    Beitz, J.V.; Williams, C.W.

    1990-01-01T23:59:59.000Z

    A novel photochemical method of removing reactive fluorides from UF{sub 6} gas has been discovered. This method reduces generated waste to little more than the volume of the removed impurities, minimizes loss of UF{sub 6}, and can produce a recyclable by-product, fluorine gas. In our new method, impure UF{sub 6}, is exposed to ultraviolet light which dissociates the UF{sub 6} to UF{sub 5} and fluorine atom. Impurities which chemically react with UF{sub 5} are reduced and form solid compounds easily removed from the gas while UF{sub 5} is converted back to UF{sub 6}. Proof-of-concept testing involved UF{sub 6} containing NpF{sub 6} and PuF{sub 6} with CO added as a fluorine atom scavenger. In a single photolysis step, greater than 5000-fold reduction of PuF{sub 6} was demonstrated while reducing NpF{sub 6} by more than 40-fold. This process is likely to remove corrosion and fission product fluorides that are more reactive than UF{sub 6} and has been demonstrated without an added fluorine atom scavenger by periodically removing photogenerated fluorine gas. 44 refs., 3 figs., 2 tabs.

  11. Biodesulfurization techniques: Application of selected microorganisms for organic sulfur removal from coals. Final report

    SciTech Connect (OSTI)

    Elmore, B.B.

    1993-08-01T23:59:59.000Z

    As an alternative to post-combustion desulfurization of coal and pre-combustion desulfurization using physicochemical techniques, the microbial desulfurization of coal may be accomplished through the use of microbial cultures that, in an application of various microbial species, may remove both the pyritic and organic fractions of sulfur found in coal. Organisms have been isolated that readily depyritize coal but often at prohibitively low rates of desulfurization. Microbes have also been isolated that may potentially remove the organic-sulfur fraction present in coal (showing promise when acting on organic sulfur model compounds such as dibenzothiophene). The isolation and study of microorganisms demonstrating a potential for removing organic sulfur from coal has been undertaken in this project. Additionally, the organisms and mechanisms by which coal is microbially depyritized has been investigated. Three cultures were isolated that grew on dibenzothiophene (DBT), a model organic-sulfur compound, as the sole sulfur source. These cultures (UMX3, UMX9, and IGTS8) also grew on coal samples as the sole sulfur source. Numerous techniques for pretreating and ``cotreating`` coal for depyritization were also evaluated for the ability to improve the rate or extent of microbial depyritization. These include prewashing the coal with various solvents and adding surfactants to the culture broth. Using a bituminous coal containing 0.61% (w/w) pyrite washed with organic solvents at low slurry concentrations (2% w/v), the extent of depyritization was increased approximately 25% in two weeks as compared to controls. At slurry concentrations of 20% w/v, a tetrachloroethylene treatment of the coal followed by depyritization with Thiobacillus ferrooxidans increased both the rate and extent of depyritization by approximately 10%.

  12. TYPE A VERIFICATION FOR THE HIGH FLUX BEAM REACTOR UNDERGROUND UTILITIES REMOVAL PHASE 2 DF WASTE LINE REMOVAL, BNL

    SciTech Connect (OSTI)

    P.C. Weaver

    2010-07-09T23:59:59.000Z

    5098-SR-02-0 PROJECT-SPECIFIC TYPE A VERIFICATION FOR THE HIGH FLUX BEAM REACTOR UNDERGROUND UTILITIES REMOVAL PHASE 2 DF WASTE LINE REMOVAL, BROOKHAVEN NATIONAL LABORATORY

  13. Saeltzer Dam Removal on Clear Creek 11 years later: An assessment of upstream channel changes since the dam's removal

    E-Print Network [OSTI]

    Simons, Crystal; Walker, Katelyn; Zimring, Mark

    2011-01-01T23:59:59.000Z

    Boulder BLDR Bedrock BDRK Dam Rubble DMRB Table B1. 2011pages. Brown, M. (n.d. ). Clear Creek—McCormick-Saeltzer DamRemoval: Dam removal re-opens spring run salmon habitat. US

  14. Polymers containing borane or carborane cage compounds and related applications

    SciTech Connect (OSTI)

    Bowen, III, Daniel E; Eastwood, Eric A

    2013-04-23T23:59:59.000Z

    Polymers comprising residues of cage compound monomers having at least one polyalkoxy silyl substituent are provided. The cage compound monomers are selected from borane cage compound monomers comprising at least 7 cage atoms and/or carborane cage compound monomers comprising 7 to 11 cage compound monomers. Such polymers can further comprise one or more reactive matrices and/or co-monomers covalently bound with the cage compound monomer residues. Articles of manufacture comprising such polymers are also disclosed.

  15. Compound and Elemental Analysis At Clear Lake Area (Thompson...

    Open Energy Info (EERE)

    Compound and Elemental Analysis At Clear Lake Area (Thompson, Et Al., 1992) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and...

  16. Novel Compounds for Enhancing Electrolyte Stability and Safety...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Compounds for Enhancing Electrolyte Stability and Safety of Lithium-ion Cells Novel Compounds for Enhancing Electrolyte Stability and Safety of Lithium-ion Cells 2010 DOE Vehicle...

  17. Compound and Elemental Analysis At Newberry Caldera Area (Goles...

    Open Energy Info (EERE)

    Compound and Elemental Analysis At Newberry Caldera Area (Goles & Lambert, 1990) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and...

  18. Process for removing polychlorinated biphenyls from soil

    DOE Patents [OSTI]

    Hancher, C.W.; Saunders, M.B.; Googin, J.M.

    1984-11-16T23:59:59.000Z

    The present invention relates to a method of removing polychlorinated biphenyls from soil. The polychlorinated biphenyls are extracted from the soil by employing a liquid organic solvent dispersed in water in the ratio of about 1:3 to 3:1. The organic solvent includes such materials as short-chain hydrocarbons including kerosene or gasoline which are immiscible with water and are nonpolar. The organic solvent has a greater affinity for the PCB's than the soil so as to extract the PCB's from the soil upon contact. The organic solvent phase is separated from the suspended soil and water phase and distilled for permitting the recycle of the organic solvent phase and the concentration of the PCB's in the remaining organic phase. The present process can be satisfactorily practiced with soil containing 10 to 20% petroleum-based oils and organic fluids such as used in transformers and cutting fluids, coolants and the like which contain PCB's. The subject method provides for the removal of a sufficient concentration of PCB's from the soil to provide the soil with a level of PCB's within the guidelines of the Environmental Protection Agency.

  19. EVOLVING EXPECTATIONS OF DAM REMOVAL OUTCOMES: DOWNSTREAM GEOMORPHIC EFFECTS FOLLOWING REMOVAL OF A SMALL, GRAVEL-FILLED DAM1

    E-Print Network [OSTI]

    Tullos, Desiree

    EVOLVING EXPECTATIONS OF DAM REMOVAL OUTCOMES: DOWNSTREAM GEOMORPHIC EFFECTS FOLLOWING REMOVAL OF A SMALL, GRAVEL-FILLED DAM1 Kelly Kibler, Desiree Tullos, and Mathias Kondolf 2 ABSTRACT: Dam removal is a promising river restoration technique, particularly for the vast number of rivers impounded by small dams

  20. Evaluation of sustained release polylactate electron donors for removal of hexavalent chromium from contaminated groundwater

    SciTech Connect (OSTI)

    Brodie, E.L.; Joyner, D. C.; Faybishenko, B.; Conrad, M. E.; Rios-Velazquez, C.; Mork, B.; Willet, A.; Koenigsberg, S.; Herman, D.; Firestone, M. K.; Hazen, T. C.; Malave, Josue; Martinez, Ramon

    2011-02-15T23:59:59.000Z

    To evaluate the efficacy of bioimmobilization of Cr(VI) in groundwater at the Department of Energy Hanford site, we conducted a series of microcosm experiments using a range of commercial electron donors with varying degrees of lactate polymerization (polylactate). These experiments were conducted using Hanford Formation sediments (coarse sand and gravel) immersed in Hanford groundwater, which were amended with Cr(VI) and several types of lactate-based electron donors (Hydrogen Release Compound, HRC; primer-HRC, pHRC; extended release HRC) and the polylactate-cysteine form (Metal Remediation Compound, MRC). The results showed that polylactate compounds stimulated an increase in bacterial biomass and activity to a greater extent than sodium lactate when applied at equivalent carbon concentrations. At the same time, concentrations of headspace hydrogen and methane increased and correlated with changes in the microbial community structure. Enrichment of Pseudomonas spp. occurred with all lactate additions, and enrichment of sulfate-reducing Desulfosporosinus spp. occurred with almost complete sulfate reduction. The results of these experiments demonstrate that amendment with the pHRC and MRC forms result in effective removal of Cr(VI) from solution most likely by both direct (enzymatic) and indirect (microbially generated reductant) mechanisms.

  1. Process for production of a borohydride compound

    DOE Patents [OSTI]

    Allen, Nathan Tait; Butterick, III, Robert; Chin, Arthur Achhing; Millar, Dean Michael; Molzahn, David Craig

    2014-08-19T23:59:59.000Z

    A process for production of a borohydride compound M(BH.sub.4).sub.y. The process has three steps. The first step combines a compound of formula (R.sup.1O).sub.yM with aluminum, hydrogen and a metallic catalyst containing at least one metal selected from the group consisting of titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula M(AlH.sub.3OR.sup.1).sub.y, wherein R.sup.1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group; M is an alkali metal, Be or Mg; and y is one or two; wherein the catalyst is present at a level of at least 200 ppm based on weight of aluminum. The second step combines the compound of formula M(AlH.sub.3OR.sup.1).sub.y with a borate, boroxine or borazine compound to produce M(BH.sub.4).sub.y and a byproduct mixture containing alkali metal and aluminum aryloxides. The third step separates M(BH.sub.4).sub.y from the byproduct mixture.

  2. Conversion of depleted uranium hexafluoride to a solid uranium compound

    DOE Patents [OSTI]

    Rothman, Alan B. (Willowbrook, IL); Graczyk, Donald G. (Lemont, IL); Essling, Alice M. (Elmhurst, IL); Horwitz, E. Philip (Naperville, IL)

    2001-01-01T23:59:59.000Z

    A process for converting UF.sub.6 to a solid uranium compound such as UO.sub.2 and CaF. The UF.sub.6 vapor form is contacted with an aqueous solution of NH.sub.4 OH at a pH greater than 7 to precipitate at least some solid uranium values as a solid leaving an aqueous solution containing NH.sub.4 OH and NH.sub.4 F and remaining uranium values. The solid uranium values are separated from the aqueous solution of NH.sub.4 OH and NH.sub.4 F and remaining uranium values which is then diluted with additional water precipitating more uranium values as a solid leaving trace quantities of uranium in a dilute aqueous solution. The dilute aqueous solution is contacted with an ion-exchange resin to remove substantially all the uranium values from the dilute aqueous solution. The dilute solution being contacted with Ca(OH).sub.2 to precipitate CaF.sub.2 leaving dilute NH.sub.4 OH.

  3. Apparatus for removing micronized coal from steam

    SciTech Connect (OSTI)

    Vlnaty, J.

    1981-12-15T23:59:59.000Z

    Micronized coal is removed from coal-bearing steam by spraying stabilized petroleum oil into the steam and directing the resultant stream at a separation surface on which a coal-oil slurry is deposited and collected. Apparatus includes conduits which direct the resultant stream downward into a housing and normal to a surface on which the slurry is deposited by impact forces. In additional apparatus disclosed, the resultant stream is directed from a horizontal conduit circumferentially along the interior wall of a horizontally disposed cylindrical chamber at the top of the chamber and the coal-oil slurry deposited on the wall by centrifugal force is collected in a trough situated below a longitudinal slot at the bottom of the chamber. In both types of apparatus, after separation of the slurry the velocity of the steam is reduced to settle out remaining oil droplets and is then discharged to the atmosphere.

  4. Fluoride removal from water with spent catalyst

    SciTech Connect (OSTI)

    Lai, Y.D.; Liu, J.C. [National Taiwan Institute of Technology, Taipei (Taiwan, Province of China)

    1996-12-01T23:59:59.000Z

    The adsorption of fluoride from water with spent catalyst was studied. Adsorption density of fluoride decreased with increasing pH. Linear adsorption isotherm was utilized to describe the adsorption reaction. The adsorption was a first-order reaction, and the rate constant increased with decreasing surface loading. Adsorption reaction of fluoride onto spent catalyst was endothermic, and the reaction rate increased slightly with increasing temperature. Fluoro-alumino complex and free fluoride ion were involved in the adsorption reaction. It is proposed that both the silica and alumina fractions of spent catalyst contribute to the removal of fluoride from aqueous solution. Coulombic interaction is proposed as the major driving force of the adsorption reaction of fluoride onto spent catalyst.

  5. AX Tank Farm tank removal study

    SciTech Connect (OSTI)

    SKELLY, W.A.

    1999-02-24T23:59:59.000Z

    This report examines the feasibility of remediating ancillary equipment associated with the 241-AX Tank Farm at the Hanford Site. Ancillary equipment includes surface structures and equipment, process waste piping, ventilation components, wells, and pits, boxes, sumps, and tanks used to make waste transfers to/from the AX tanks and adjoining tank farms. Two remedial alternatives are considered: (1) excavation and removal of all ancillary equipment items, and (2) in-situ stabilization by grout filling, the 241-AX Tank Farm is being employed as a strawman in engineering studies evaluating clean and landfill closure options for Hanford single-shell tanks. This is one of several reports being prepared for use by the Hanford Tanks Initiative Project to explore potential closure options and to develop retrieval performance evaluation criteria for tank farms.

  6. AX Tank Farm tank removal study

    SciTech Connect (OSTI)

    SKELLY, W.A.

    1998-10-14T23:59:59.000Z

    This report considers the feasibility of exposing, demolishing, and removing underground storage tanks from the 241-AX Tank Farm at the Hanford Site. For the study, it was assumed that the tanks would each contain 360 ft{sup 3} of residual waste (corresponding to the one percent residual Inventory target cited in the Tri-Party Agreement) at the time of demolition. The 241-AX Tank Farm is being employed as a ''strawman'' in engineering studies evaluating clean and landfill closure options for Hanford single-shell tank farms. The report is one of several reports being prepared for use by the Hanford Tanks Initiative Project to explore potential closure options and to develop retrieval performance evaluation criteria for tank farms.

  7. Removing sulphur oxides from a fluid stream

    DOE Patents [OSTI]

    Katz, Torsten; Riemann, Christian; Bartling, Karsten; Rigby, Sean Taylor; Coleman, Luke James Ivor; Lail, Marty Alan

    2014-04-08T23:59:59.000Z

    A process for removing sulphur oxides from a fluid stream, such as flue gas, comprising: providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the liquid being incompletely miscible with water; treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

  8. Process for producing phenolic compounds from lignins

    DOE Patents [OSTI]

    Agblevor, F.A.

    1998-09-15T23:59:59.000Z

    A process is described for the production of low molecular weight phenolic compounds from lignins through the pyrolysis of the lignins in the presence of a strong base. In a preferred embodiment, potassium hydroxide is present in an amount of from about 0.1% to about 5% by weight, the pyrolysis temperature is from about 400 C to about 600 C at atmospheric pressure, and the time period for substantial completion of the reaction is from about 1--3 minutes. Examples of low molecular weight phenolic compounds produced include methoxyphenols, non-methoxylated phenols, and mixtures thereof. 16 figs.

  9. Dry etching method for compound semiconductors

    DOE Patents [OSTI]

    Shul, R.J.; Constantine, C.

    1997-04-29T23:59:59.000Z

    A dry etching method is disclosed. According to the present invention, a gaseous plasma comprising, at least in part, boron trichloride, methane, and hydrogen may be used for dry etching of a compound semiconductor material containing layers including aluminum, or indium, or both. Material layers of a compound semiconductor alloy such as AlGaInP or the like may be anisotropically etched for forming electronic devices including field-effect transistors and heterojunction bipolar transistors and for forming photonic devices including vertical-cavity surface-emitting lasers, edge-emitting lasers, and reflectance modulators. 1 fig.

  10. Organic photosensitive devices using subphthalocyanine compounds

    DOE Patents [OSTI]

    Rand, Barry (Princeton, NJ); Forrest, Stephen R. (Ann Arbor, MI); Mutolo, Kristin L. (Hollywood, CA); Mayo, Elizabeth (Alhambra, CA); Thompson, Mark E. (Anaheim Hills, CA)

    2011-07-05T23:59:59.000Z

    An organic photosensitive optoelectronic device, having a donor-acceptor heterojunction of a donor-like material and an acceptor-like material and methods of making such devices is provided. At least one of the donor-like material and the acceptor-like material includes a subphthalocyanine, a subporphyrin, and/or a subporphyrazine compound; and/or the device optionally has at least one of a blocking layer or a charge transport layer, where the blocking layer and/or the charge transport layer includes a subphthalocyanine, a subporphyrin, and/or a subporphyrazine compound.

  11. Inelastic neutron scattering in valence fluctuation compounds

    SciTech Connect (OSTI)

    Jon M Lawrence

    2011-02-15T23:59:59.000Z

    The valence fluctuation compounds are rare earth intermetallics where hybridization of the nearly-localized 4f electrons with the conduction electrons leads to incorporation of the 4f's into the itinerant states. This hybridization slows down the conduction electrons and hence gives them a heavy effective mass, justifying application of the term 'heavy Fermion' (HF) to these materials. During the project period, we grew large single crystals of several such compounds and measured their properties using both standard thermodynamic probes and state-of-the-art inelastic neutron scattering. We obtained three main results. For the intermediate valence compounds CePd{sub 3} and YbAl{sub 3}, we showed that the scattering of neutrons by the fluctuations of the 4f magnetic moment does not have the momentum dependence expected for the itinerant heavy mass state; rather, the scattering is more typical of a localized spin fluctuation. We believe that incoherent scattering localizes the excitation. For the heavy Fermion compound Ce(Ni{sub 0.935}Pd{sub 0.065}){sub 2}Ge{sub 2}, which sits at a T = 0 critical point for transformation into an antiferromagnetic (AF) phase, we showed that the scattering from the AF fluctuations does not exhibit any of the divergences that are expected at a phase transition. We speculate that alloy disorder profoundly suppresses the growth of the fluctuating AF regions, leading to short range clusters rather than regions of infinite size. Finally, we explored the applicability of key concepts used to describe the behavior of rare earth heavy Fermions to uranium based HF compounds where the 5f electrons are itinerant as opposed to localized. We found that scaling laws relating the spin fluctuation energy measured in neutron scattering to the low temperature specific heat and susceptibility are valid for the uranium compounds, once corrections are made for AF fluctuations; however, the degeneracy of the high temperature moment is smaller than expected for rare-earth-like Hund's rule behavior, essentially because the orbital moment is suppressed for itinerant 5f electrons. We also found that the standard local-moment-based theory of the temperature dependence of the specific heat, susceptibility and neutron scattering fails badly for URu{sub 2}Zn{sub 20} and UCo{sub 2}Zn{sub 20}, even though the theory is phenomenally successful for the closely related rare earth compound YbFe{sub 2}Zn{sub 20}. Both these results highlight the distinction between the itineracy of the 5f's and the localization of the 4f's. It is our hope that these results are sufficiently significant as to stimulate deeper investigation of these compounds.

  12. Dry etching method for compound semiconductors

    DOE Patents [OSTI]

    Shul, Randy J. (Albuquerque, NM); Constantine, Christopher (Safety Harbor, FL)

    1997-01-01T23:59:59.000Z

    A dry etching method. According to the present invention, a gaseous plasma comprising, at least in part, boron trichloride, methane, and hydrogen may be used for dry etching of a compound semiconductor material containing layers including aluminum, or indium, or both. Material layers of a compound semiconductor alloy such as AlGaInP or the like may be anisotropically etched for forming electronic devices including field-effect transistors and heterojunction bipolar transistors and for forming photonic devices including vertical-cavity surface-emitting lasers, edge-emitting lasers, and reflectance modulators.

  13. Beta cell device using icosahedral boride compounds

    DOE Patents [OSTI]

    Aselage, Terrence L. (62 Avenida Del Sol, Cedar Crest, NM 87008); Emin, David (1502 Harvard Ct., NE., Albuquerque, NM 87106-3712)

    2002-01-01T23:59:59.000Z

    A beta cell for converting beta-particle energies into electrical energy having a semiconductor junction that incorporates an icosahedral boride compound selected from B.sub.12 As.sub.2, B.sub.12 P.sub.2, elemental boron having an .alpha.-rhombohedral structure, elemental boron having a .beta.-rhombohedral structure, and boron carbides of the chemical formula B.sub.12-x C.sub.3-x, where 0.15compound self-heals, resisting degradation from radiation damage.

  14. PRECOMBUSTION REMOVAL OF HAZARDOUS AIR POLLUTANT PRECURSORS

    SciTech Connect (OSTI)

    Unknown

    2000-10-09T23:59:59.000Z

    In response to growing environmental concerns reflected in the 1990 Clean Air Act Amendment (CAAA), the United States Department of Energy (DOE) sponsored several research and development projects in late 1995 as part of an initiative entitled Advanced Environmental Control Technologies for Coal-Based Power Systems. The program provided cost-shared support for research and development projects that could accelerate the commercialization of affordable, high-efficiency, low-emission, coal-fueled electric generating technologies. Clean coal technologies developed under this program would serve as prototypes for later generations of technologies to be implemented in the industrial sector. In order to identify technologies with the greatest potential for commercial implementation, projects funded under Phase I of this program were subject to competitive review by DOE before being considered for continuation funding under Phase II. One of the primary topical areas identified under the DOE initiative relates to the development of improved technologies for reducing the emissions of air toxics. Previous studies have suggested that many of the potentially hazardous air pollutant precursors (HAPPs) occur as trace elements in the mineral matter of run-of-mine coals. As a result, these elements have the potential to be removed prior to combustion at the mine site by physical coal cleaning processes (i.e., coal preparation). Unfortunately, existing coal preparation plants are generally limited in their ability to remove HAPPs due to incomplete liberation of the mineral matter and high organic associations of some trace elements. In addition, existing physical coal cleaning plants are not specifically designed or optimized to ensure that high trace element rejections may be achieved.

  15. High SO2 Removal Efficiency Testing

    SciTech Connect (OSTI)

    Gary Blythe

    1997-02-12T23:59:59.000Z

    This document provides a discussion of the technical progress on DOE/PETC project number DE-AC22-92PC91338, "High Efficiency SO Removal Testing," for 2 the time period 1 October through 31 December 1996. The project involves testing at six full-scale utility flue gas desulfurization (FGD) systems, to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO removal efficiency. The upgrades being 2 evaluated mostly involve using performance additives in the FGD systems. The "base" project involved testing at the Tampa Electric Company?s Big Bend Station. All five potential options to the base program have been exercised by DOE, involving testing at Hoosier Energy?s Merom Station (Option I), Southwestern Electric Power Company?s Pirkey Station (Option II), PSI Energy?s Gibson Station (Option III), Duquesne Light?s Elrama Station (Option IV), and New York State Electric and Gas Corporation?s Kintigh Station (Option V). The originally planned testing has been completed for all six sites. However, additional testing has been planned at the Big Bend Station, and that testing commenced during the current quarter. The remainder of this document is divided into four sections. Section 2, Project Summary, provides a brief overview of the status of technical efforts on this project. Section 3, Results, summarizes the outcome from technical efforts during the quarter, or results from prior quarters that have not been previously reported. In Section 4, Plans for the Next Reporting Period, an overview is provided of the technical efforts that are anticipated for the first quarter of calendar year 1996. Section 5 contains a brief acknowledgment.

  16. High SO2 Removal Efficiency Testing

    SciTech Connect (OSTI)

    Gary Blythe

    1997-04-23T23:59:59.000Z

    This document provides a discussion of the technical progress on DOE/PETC project number DE-AC22-92PC91338, "High Efficiency SO2 Removal Testing", for the time period 1 January through 31 March 1997. The project involves testing at six full-scale utility flue gas desulfurization (FGD) systems, to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO2 removal efficiency. The upgrades being evaluated mostly involve using performance additives in the FGD systems. The "base" project involved testing at the Tampa Electric Company?s Big Bend Station. All five potential options to the base program have been exercised by DOE, involving testing at Hoosier Energy?s Merom Station (Option I), Southwestern Electric Power Company?s Pirkey Station (Option II), PSI Energy?s Gibson Station (Option III), Duquesne Light?s Elrama Station (Option IV), and New York State Electric and Gas Corporation?s (NYSEG) Kintigh Station (Option V). The originally planned testing has been completed for all six sites. However, additional testing is planned at the Big Bend Station. The remainder of this document is divided into four sections. Section 2, Project Summary, provides a brief overview of the status of technical efforts on this project. Section 3, Results, summarizes the outcome from technical efforts during the quarter, or results from prior quarters that have not been previously reported. In Section 4, Plans for the Next Reporting Period, an overview is provided of the technical efforts that are anticipated for the second quarter of calendar year 1997. Section 5 contains a brief acknowledgement.

  17. High SO2 Removal Efficiency Testing

    SciTech Connect (OSTI)

    Gary Blythe

    1997-07-29T23:59:59.000Z

    This document provides a discussion of the technical progress on DOE/PETC project number DE-AC22-92PC91338, "High Efficiency SO2 Removal Testing", for the time period 1 April through 30 June 1997. The project involves testing at six full-scale utility flue gas desulfurization (FGD) systems to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO2 removal efficiency. The upgrades being evaluated mostly involve using performance additives in the FGD systems. The "base" project involved testing at the Tampa Electric Company?s Big Bend Station. All five potential options to the base program have been exercised by DOE, involving testing at Hoosier Energy?s Merom Station (Option I), Southwestern Electric Power Company?s Pirkey Station (Option II), PSI Energy?s Gibson Station (Option III), Duquesne Light?s Elrama Station (Option IV), and New York State Electric and Gas Corporation?s Kintigh Station (Option V). The originally planned testing has been completed for all six sites. However, additional testing is being conducted at the Big Bend Station. The remainder of this document is divided into four sections. Section 2, Project Summary, provides a brief overview of the status of technical efforts on this project. Section 3, Results, summarizes the outcome from technical efforts during the quarter, or results from prior quarters that have not been previously reported. In Section 4, Plans for the Next Reporting Period, an overview is provided of the technical efforts that are anticipated for the third quarter of calendar year 1997. Section 5 contains a brief acknowledgment.

  18. Experimental investigation of single carbon compounds under hydrothermal conditions

    E-Print Network [OSTI]

    Rhoads, James

    reactant during the abiotic synthesis of reduced carbon compounds via Fischer­Tropsch-type processes

  19. Compositions containing borane or carborane cage compounds and related applications

    DOE Patents [OSTI]

    Bowen, III, Daniel E; Eastwood, Eric A

    2014-11-11T23:59:59.000Z

    Compositions comprising a polymer-containing matrix and a filler comprising a cage compound selected from borane cage compounds, carborane cage compounds, metal complexes thereof, residues thereof, mixtures thereof, and/or agglomerations thereof, where the cage compound is not covalently bound to the matrix polymer. Methods of making and applications for using such compositions are also disclosed.

  20. Compositions containing borane or carborane cage compounds and related applications

    DOE Patents [OSTI]

    Bowen, III, Daniel E; Eastwood, Eric A

    2013-05-28T23:59:59.000Z

    Compositions comprising a polymer-containing matrix and a filler comprising a cage compound selected from borane cage compounds, carborane cage compounds, metal complexes thereof, residues thereof, mixtures thereof, and/or agglomerations thereof, where the cage compound is not covalently bound to the matrix polymer. Methods of making and applications for using such compositions are also disclosed.

  1. Process for preparing a deuterated or tritiated compound

    DOE Patents [OSTI]

    Klei, Steven R.; Bergman, Robert C.

    2006-06-06T23:59:59.000Z

    A process for labeling organic compounds with deuterium and tritium is described using specific catalysts.

  2. Process for preparing a deuterated or tritiated compound

    DOE Patents [OSTI]

    Bergman, Robert C.; Klei, Steven R.

    2006-05-16T23:59:59.000Z

    A process for labeling organic compounds with deuterium and tritium is described using specific catalysts.

  3. Process for preparing a deuterated or tritiated compound

    DOE Patents [OSTI]

    Bergman, Robert C.; Klei, Steven R.

    2004-09-21T23:59:59.000Z

    A process for labeling organic compounds with deuterium and tritium is described using specific catalysts.

  4. HYDROGEN LOCAL VIBRATIONAL MODES IN COMPOUND SEMICONDUCTORS

    E-Print Network [OSTI]

    McCluskey, Matthew

    HYDROGEN LOCAL VIBRATIONAL MODES IN COMPOUND SEMICONDUCTORS M.D. MCCLUSKEY* University) spectroscopy of hydrogen and deuterium in GaP, AlSb, ZnSe, and GaN has provided important information about the structures of dopant- hydrogen complexes and their interaction with the host lattice. In GaN:Mg, for example

  5. Quaternary Ammonium Compounds as Water Channel Blockers

    E-Print Network [OSTI]

    de Groot, Bert

    /AQP2/AQP4, whereas the water permeability of AQP3 and AQP5, which lack a corresponding TyrQuaternary Ammonium Compounds as Water Channel Blockers SPECIFICITY, POTENCY, AND SITE OF ACTION, West Mains Road, EH9 3JJ Scotland, United Kingdom Excessive water uptake through Aquaporins (AQP) can

  6. Superconductivity in iron compounds G. R. Stewart

    E-Print Network [OSTI]

    Wu, Zhigang

    of the superconductivity in this new class of compounds. These iron pnictide and chalcogenide (FePn/Ch) superconductors-phonon coupled ``conventional'' superconductors. Clearly, superconductivity and magnetism or magnetic of magnetism and superconductivity in FePn/Ch superconductors 1606 D. Tc and TS=TSDW versus pressure 1607 1

  7. Surface Smoothing of Compound Semiconductor Substrates with Gas Cluster Ion Beams

    SciTech Connect (OSTI)

    Houzumi, S.; Toyoda, N.; Yamada, I. [Laboratory of Advanced Science and Technology for Industry, Himeji Institute of Technology, 3-1-2 Kouto, Kamigori, Ako-gun, Hyogo, 678-1205 (Japan)

    2003-08-26T23:59:59.000Z

    Surface smoothing by gas cluster ion beams (GCIB) was studied for compound semiconductor such as GaN and SiC. Average cluster size of Ar cluster ions was 2000atoms/cluster measured by time of flight (TOF). Since the total acceleration energy was 20keV, the energy per atom was 10eV/atom. This low-energy characteristic of gas cluster ion beams is desirable for compound semiconductors. GCIB irradiation was employed to remove the scratches of the mechanically polished SiC surface. After irradiation at acceleration energy of 15keV, the scratches was completry removed. The GaN film with initial average roughness of 4nm was also smoothed to that of 1.4nm by Ar cluster ion beams. Furthermore SiC substrates were irradiated with SF6 cluster ions. The sputtering yield of SiC with SF6 cluster ions was enhanced almost 3 times than that with Ar cluster ions.

  8. Heat recirculating cooler for fluid stream pollutant removal

    DOE Patents [OSTI]

    Richards, George A. (Morgantown, WV); Berry, David A. (Morgantown, WV)

    2008-10-28T23:59:59.000Z

    A process by which heat is removed from a reactant fluid to reach the operating temperature of a known pollutant removal method and said heat is recirculated to raise the temperature of the product fluid. The process can be utilized whenever an intermediate step reaction requires a lower reaction temperature than the prior and next steps. The benefits of a heat-recirculating cooler include the ability to use known pollutant removal methods and increased thermal efficiency of the system.

  9. Removal of radioactive and other hazardous material from fluid waste

    DOE Patents [OSTI]

    Tranter, Troy J. (Idaho Falls, ID); Knecht, Dieter A. (Idaho Falls, ID); Todd, Terry A. (Aberdeen, ID); Burchfield, Larry A. (W. Richland, WA); Anshits, Alexander G. (Krasnoyarsk, RU); Vereshchagina, Tatiana (Krasnoyarsk, RU); Tretyakov, Alexander A. (Zheleznogorsk, RU); Aloy, Albert S. (St. Petersburg, RU); Sapozhnikova, Natalia V. (St. Petersburg, RU)

    2006-10-03T23:59:59.000Z

    Hollow glass microspheres obtained from fly ash (cenospheres) are impregnated with extractants/ion-exchangers and used to remove hazardous material from fluid waste. In a preferred embodiment the microsphere material is loaded with ammonium molybdophosphonate (AMP) and used to remove radioactive ions, such as cesium-137, from acidic liquid wastes. In another preferred embodiment, the microsphere material is loaded with octyl(phenyl)-N-N-diisobutyl-carbamoylmethylphosphine oxide (CMPO) and used to remove americium and plutonium from acidic liquid wastes.

  10. Thiacrown polymers for removal of mercury from waste streams

    DOE Patents [OSTI]

    Baumann, Theodore F.; Reynolds, John G.; Fox, Glenn A.

    2004-02-24T23:59:59.000Z

    Thiacrown polymers immobilized to a polystyrene-divinylbenzene matrix react with Hg.sup.2+ under a variety of conditions to efficiently and selectively remove Hg.sup.2+ ions from acidic aqueous solutions, even in the presence of a variety of other metal ions. The mercury can be recovered and the polymer regenerated. This mercury removal method has utility in the treatment of industrial wastewater, where a selective and cost-effective removal process is required.

  11. Thiacrown polymers for removal of mercury from waste streams

    DOE Patents [OSTI]

    Baumann, Theodore F. (Tracy, CA); Reynolds, John G. (San Ramon, CA); Fox, Glenn A. (Livermore, CA)

    2002-01-01T23:59:59.000Z

    Thiacrown polymers immobilized to a polystyrene-divinylbenzene matrix react with Hg.sup.2+ under a variety of conditions to efficiently and selectively remove Hg.sup.2+ ions from acidic aqueous solutions, even in the presence of a variety of other metal ions. The mercury can be recovered and the polymer regenerated. This mercury removal method has utility in the treatment of industrial wastewater, where a selective and cost-effective removal process is required.

  12. Organic removal from domestic wastewater by activated alumina adsorption

    E-Print Network [OSTI]

    Yang, Pe-Der

    1982-01-01T23:59:59.000Z

    of the major groups of pollutants in wastewaters. Adsorption by granular activated carbon, a non-polar adsorbent, is now the primary treatment process for removal of residual organics from biologically treated wastewater. The ability of activated alumina... to human health if they exist in the water supply at relatively high concentrations. A wide variety of treatment processes are available to remove organic matter from wastewater. Biological treatment is the most cost effective method for removing oxygen...

  13. Use, Maintenance, Removal, Inspections, and Safety of Dams (Iowa)

    Broader source: Energy.gov [DOE]

    This section describes operating plans for dams with movable structures, as well as procedures for raising or lowering of impoundment levels, dam removal, and dam safety inspections.

  14. actinide removal process: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    plants (WWTPs) with biological nitrogen removal processes, using a life cycle assessment (LCA) approach. Literature ... Xu, Xin, S.M. Massachusetts Institute of Technology...

  15. ammonium nitrogen removal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    plants (WWTPs) with biological nitrogen removal processes, using a life cycle assessment (LCA) approach. Literature ... Xu, Xin, S.M. Massachusetts Institute of Technology...

  16. autotrophic nitrogen removal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treatment plants (WWTPs) with biological nitrogen removal processes, using a life cycle assessment (LCA) approach. Literature ... Xu, Xin, S.M. Massachusetts Institute of...

  17. Annex IV Environmental Webinar: Effects of Energy Removal on...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    tidal energy from estuaries; and Jesse Roberts, Sandia National Laboratory - Modeling energy removal by wave energy extraction. Participant Instructions: Webinar Login: You may...

  18. Safety evaluation for packaging (onsite) product removal can containers

    SciTech Connect (OSTI)

    Boettger, J.S.

    1997-04-29T23:59:59.000Z

    This safety evaluation for packaging allows the transport of nine Product Removal (PR) Cans with their Containers from the PUREX Facility to the Plutonium Finishing Plant.

  19. active debris removal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rebecca Bendick a , Kevin D. Hyde b March 2013 Keywords: Debris flow Frequency Magnitude Fire Forecasting debris flow hazard is challenging Montana, University of 110 Removing...

  20. REMOVAL OF THE CALIFORNIUM SOURCES FROM THE 222-S LABORATORY

    SciTech Connect (OSTI)

    LINSTRUM D; BAUNE HL

    2009-07-23T23:59:59.000Z

    This document develops a proposal for removal of 2-Californium sources from the 222-S Laboratory. Included in this document are assessments of shipping packages and decay calculations.

  1. Process to remove rare earth from IFR electrolyte

    DOE Patents [OSTI]

    Ackerman, John P. (Downers Grove, IL); Johnson, Terry R. (Wheaton, IL)

    1994-01-01T23:59:59.000Z

    The invention is a process for the removal of rare earths from molten chloride electrolyte salts used in the reprocessing of integrated fast reactor fuel (IFR). The process can be used either continuously during normal operation of the electrorefiner or as a batch process. The process consists of first separating the actinide values from the salt before purification by removal of the rare earths. After replacement of the actinides removed in the first step, the now-purified salt electrolyte has the same uranium and plutonium concentration and ratio as when the salt was removed from the electrorefiner.

  2. Process to remove rare earth from IFR electrolyte

    DOE Patents [OSTI]

    Ackerman, J.P.; Johnson, T.R.

    1994-08-09T23:59:59.000Z

    The invention is a process for the removal of rare earths from molten chloride electrolyte salts used in the reprocessing of integrated fast reactor fuel (IFR). The process can be used either continuously during normal operation of the electrorefiner or as a batch process. The process consists of first separating the actinide values from the salt before purification by removal of the rare earths. After replacement of the actinides removed in the first step, the now-purified salt electrolyte has the same uranium and plutonium concentration and ratio as when the salt was removed from the electrorefiner. 1 fig.

  3. NNSA's Global Threat Reduction Initiative Removes More Than One...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Press Releases Video Gallery Photo Gallery Jobs Apply for Our Jobs Our Jobs Working at NNSA Blog Home NNSA Blog NNSA's Global Threat Reduction Initiative Removes More ......

  4. Performance evaluation of organic emulsion liquid membrane on phenol removal

    E-Print Network [OSTI]

    Ng, Y S; Hashim, M A

    2014-01-01T23:59:59.000Z

    The percentage removal of phenol from aqueous solution by emulsion liquid membrane and emulsion leakage was investigated experimentally for various parameters such as membrane:internal phase ratio, membrane:external phase ratio, emulsification speed, emulsification time, carrier concentration, surfactant concentration and internal agent concentration. These parameters strongly influence the percentage removal of phenol and emulsion leakage. Under optimum membrane properties, the percentage removal of phenol was as high as 98.33%, with emulsion leakage of 1.25%. It was also found that the necessity of carrier for enhancing phenol removal was strongly dependent on the internal agent concentration.

  5. Process to remove rare earth from IFR electrolyte

    DOE Patents [OSTI]

    Ackerman, J.P.; Johnson, T.R.

    1992-01-01T23:59:59.000Z

    The invention is a process for the removal of rare earths from molten chloride electrolyte salts used in the reprocessing of integrated fast reactor fuel (IFR). The process can be used either continuously during normal operation of the electrorefiner or as a batch process. The process consists of first separating the actinide values from the salt before purification by removal of the rare earths. After replacement of the actinides removed in the first step, the now-purified salt electrolyte has the same uranium and plutonium concentration and ratio as when the salt was removed from the electrorefiner.

  6. Removal of carbon tetrachloride from a layered porous medium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon tetrachloride from a layered porous medium by means of soil vapor extraction enhanced by desiccation and water Removal of carbon tetrachloride from a layered porous medium...

  7. Removal of Carbon Tetrachloride from a Layered Porous Medium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Tetrachloride from a Layered Porous Medium by Means of Soil Vapor Extraction Enhanced by Desiccation and Water Removal of Carbon Tetrachloride from a Layered Porous Medium...

  8. Study of Alternative Approaches for Transite Panel Removal

    Broader source: Energy.gov [DOE]

    Bechtel Jacobs Company LLC (BJC) assembled an experienced team from both sites to evaluate both the manual and mechanical methods of transite panel removal.

  9. anesthesia optimizing removal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    de 7 Multiplicative Noise Removal Using Variable Splitting and Constrained Optimization CERN Preprints Summary: Multiplicative noise (also known as speckle noise) models...

  10. Diatomaceous earth and activated bauxite used as granular sorbents for the removal of sodium chloride vapor from hot flue gas

    SciTech Connect (OSTI)

    Lee, S.H.D.; Swift, W.M.; Johnson, I.

    1980-01-01T23:59:59.000Z

    Diatomaceous earth and activated bauxite were tested as granular sorbents for use as filter media in granular-bed filters for the removal of gaseous alkali metal compounds from the hot (800/sup 0/C) flue gas of PFBC. Tests were performed at atmospheric pressure, using NaCl vapor transported in relatively dry simulated flue gas of PFBC. Either a fixed-bed combustor or a high-temperature sorption test rig was used. The effects of sorbent bed temperature, superficial gas velocity, gas hourly space velocity, and NaCl-vapor concentration in flue gas on the sorption behavior of these two sorbents and their ultimate sorption capacities were determined. Both diatomaceous earth and activated bauxite were found to be very effective in removing NaCl vapor from flue gas. Preliminary cost evaluations showed that they are economically attractive as granular sorbents for cleaning alkali vapor from simulated flue gas.

  11. Variability of hot mix asphalt produced with reclaimed asphalt pavement

    E-Print Network [OSTI]

    Yang, Guiqin

    1999-01-01T23:59:59.000Z

    percent does not significantly influence the mix variability; it is desirable to use a large percentage of RAP in the Type S-I mix, i.e., more than 40% RAP; iii) On the average, the aggregate variability increases after transportation and stockpiling...

  12. Metagenomic analysis of phosphorus removing sludgecommunities

    SciTech Connect (OSTI)

    Garcia Martin, Hector; Ivanova, Natalia; Kunin, Victor; Warnecke,Falk; Barry, Kerrie; McHardy, Alice C.; Yeates, Christine; He, Shaomei; Salamov, Asaf; Szeto, Ernest; Dalin, Eileen; Putnam, Nik; Shapiro, HarrisJ.; Pangilinan, Jasmyn L.; Rigoutsos, Isidore; Kyrpides, Nikos C.; Blackall, Linda Louise; McMahon, Katherine D.; Hugenholtz, Philip

    2006-02-01T23:59:59.000Z

    Enhanced Biological Phosphorus Removal (EBPR) is not wellunderstood at the metabolic level despite being one of the best-studiedmicrobially-mediated industrial processes due to its ecological andeconomic relevance. Here we present a metagenomic analysis of twolab-scale EBPR sludges dominated by the uncultured bacterium, "CandidatusAccumulibacter phosphatis." This analysis resolves several controversiesin EBPR metabolic models and provides hypotheses explaining the dominanceof A. phosphatis in this habitat, its lifestyle outside EBPR and probablecultivation requirements. Comparison of the same species from differentEBPR sludges highlights recent evolutionary dynamics in the A. phosphatisgenome that could be linked to mechanisms for environmental adaptation.In spite of an apparent lack of phylogenetic overlap in the flankingcommunities of the two sludges studied, common functional themes werefound, at least one of them complementary to the inferred metabolism ofthe dominant organism. The present study provides a much-needed blueprintfor a systems-level understanding of EBPR and illustrates thatmetagenomics enables detailed, often novel, insights into evenwell-studied biological systems.

  13. Method of removing oxidized contaminants from water

    DOE Patents [OSTI]

    Amonette, J.E.; Fruchter, J.S.; Gorby, Y.A.; Cole, C.R.; Cantrell, K.J.; Kaplan, D.I.

    1998-07-21T23:59:59.000Z

    The present invention is a method for removing oxidized contaminant(s) from water. More specifically, the invention has the steps of contacting water containing the oxidized contaminant(s) with a layered aluminosilicate having Fe(II). The aluminosilicate may contain naturally occurring Fe(II), or the Fe(II) may be produced by reducing Fe(III) that is initially present. Reduction may be either by exposure to a chemical or biological reductant. Contacting the water containing oxidized contaminant(s) may be by (1) injection of Fe(II)-containing layered aluminosilicate, via a well, into a saturated zone where it is likely to intercept the contaminated water; (2) injection of contaminated water into a vessel containing the Fe(II)-bearing layered aluminosilicate; and (3) first reducing Fe(III) in the layered aluminosilicate to Fe(II) by injection of a biological or chemical reductant, into an aquifer or vessel having sufficient Fe(III)-bearing aluminosilicate to produce the necessary Fe(II). 8 figs.

  14. The washability of lignites for clay removal

    SciTech Connect (OSTI)

    Oteyaka, B.; Yamik, A.; Ucar, A.; Sahbaz, O.; Demir, U. [Dumlupinar University, Kutahya (Turkey). Dept. of Mining Engineering

    2008-07-01T23:59:59.000Z

    In the washability research of the Seyitomer Lignites (Kutahya-Turkey), with lower calorific value (1,863 kcal/kg) and high ash content (51.91%), by heavy medium separation, it was found out that middling clay in the coal had an effect to change the medium density. To prevent this problem, a trommel sieve with 18 and 5 mm aperture diameter was designed, and the clay in the coal was tried to be removed using it before the coal was released to heavy medium. Following that, the obtained coal in -100 + 18 mm and -18 + 5 mm fractions was subjected to sink and float test having 1.4 gcm{sup -3} and 1.7 gcm{sup -3} medium densities (-5 mm fraction will be evaluated in a separate work). Depending on the raw coal, with the floating of -100 + 18 mm and -18 + 5 mm size fraction in 1.4 gcm{sup -3} medium density, clean coal with 60.10% combustible matter recovery, 19.12% ash, and 3,150 kcal/kg was obtained. Also floating of the samples sinking in 1.4 gcm{sup -3} in the medium density (1.7 gcm{sup -3}), middling with 18.70% combustible matter recovery, 41.93% ash, 2,150 kcal/kg, and tailing having 78.31% ash were obtained.

  15. HIGH SO2 REMOVAL EFFICIENCY TESTING

    SciTech Connect (OSTI)

    Gary M. Blythe; James L. Phillips

    1997-10-15T23:59:59.000Z

    This final report describes the results of performance tests at six full-scale wet lime- and limestone-reagent flue gas desulfurization (FGD) systems. The objective of these tests was to evaluate the effectiveness of low capital cost sulfur dioxide (SO{sub 2}) removal upgrades for existing FGD systems as an option for complying with the provisions of the Clean Air Act Amendments of 1990. The upgrade options tested at the limestone-reagent systems included the use of organic acid additives (dibasic acid (DBA) and/or sodium formate) as well as increased reagent ratio (higher excess limestone levels in the recirculating slurry solids) and absorber liquid-to-gas ratio. One system also tested operating at higher flue gas velocities to allow the existing FGD system to treat flue gas from an adjacent, unscrubbed unit. Upgrade options for the one lime-based system tested included increased absorber venturi pressure drop and increased sulfite concentration in the recirculating slurry liquor.

  16. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, D. Kwok-Keung; Chang, Shih-Ger

    1987-08-25T23:59:59.000Z

    The present invention relates to a method of removing of nitrogen monoxide from a nitrogen monoxide-containing gas which method comprises contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate complex. The NO absorption efficiency of ferrous urea-dithiocarbamate and ferrous diethanolamine-xanthate as a function of time, oxygen content and solution ph is presented. 3 figs., 1 tab.

  17. APPLICATIONS OF LAYERED DOUBLE HYDROXIDES IN REMOVING OXYANIONS FROM OIL REFINING AND COAL MINING WASTEWATER

    SciTech Connect (OSTI)

    Song Jin; Paul Fallgren

    2006-03-01T23:59:59.000Z

    Western Research Institute (WRI), in conjunction with the U.S. Department of Energy (DOE), conducted a study of using the layered double hydroxides (LDH) as filter material to remove microorganisms, large biological molecules, certain anions and toxic oxyanions from various waste streams, including wastewater from refineries. Results demonstrate that LDH has a high adsorbing capability to those compounds with negative surface charge. Constituents studied include model bacteria, viruses, arsenic, selenium, vanadium, diesel range hydrocarbons, methyl tert-butyl ether (MTBE), mixed petroleum constituents, humic materials and anions. This project also attempted to modify the physical structure of LDH for the application as a filtration material. Flow characterizations of the modified LDH materials were also investigated. Results to date indicate that LDH is a cost-effective new material to be used for wastewater treatment, especially for the treatment of anions and oxyanions.

  18. Direct synthesis of catalyzed hydride compounds

    DOE Patents [OSTI]

    Gross, Karl J.; Majzoub, Eric

    2004-09-21T23:59:59.000Z

    A method is disclosed for directly preparing alkali metal aluminum hydrides such as NaAlH.sub.4 and Na.sub.3 AlH.sub.6 from either the alkali metal or its hydride, and aluminum. The hydride thus prepared is doped with a small portion of a transition metal catalyst compound, such as TiCl.sub.3, TiF.sub.3, or a mixture of these materials, in order to render them reversibly hydridable. The process provides for mechanically mixing the dry reagents under an inert atmosphere followed by charging the mixed materials with high pressure hydrogen while heating the mixture to about 125.degree. C. The method is relatively simple and inexpensive and provides reversible hydride compounds which are free of the usual contamination introduced by prior art wet chemical methods.

  19. Chemical characterization of beach asphalts

    E-Print Network [OSTI]

    May, Lloyd Alexander

    1973-01-01T23:59:59.000Z

    and flameless atomic absorption spectroscopy for vanadium, nickel, and iron. The neutron activation procedure was shown to be superior for vanadium, but no significant difference in methods was noted for nickel and iron. Other trace metals were done... by activation analysis. These include: mercury, gold, chromium, bromine, zinc, scandium, cobalt, and antimony. Use of the vanadium to nickel ratio, and of other trace element data, was discussed. As a key to understanding the nature of vanadium in crude...

  20. Chemical oxidation of volatile and semi-volatile organic compounds in soil

    SciTech Connect (OSTI)

    Gates, D.D.; Siegrist, R.L.; Cline, S.R.

    1995-06-01T23:59:59.000Z

    Subsurface contamination with fuel hydrocarbons or chlorinated hydrocarbons is prevalent throughout the Department of Energy (DOE) complex and in many sites managed by the Environmental Protection Agency (EPA) Superfund program. The most commonly reported chlorinated hydrocarbons (occurring > 50% of DOE contaminated sites) were trichloroethylene (TCE), 1, 1, 1,-trichloroethane (TCA), and tetrachloroethylene (PCE) with concentrations in the range of 0.2 {mu}g/kg to 12,000 mg/kg. The fuel hydrocarbons most frequently reported as being present at DOE sites include aromatic compounds and polyaromatic compounds such as phenanthrene, pyrene, and naphthalene. The primary sources of these semi-volatile organic compounds (SVOCs) are coal waste from coal fired electric power plants used at many of these facilities in the past and gasoline spills and leaks. Dense non-aqueous phase liquids (DNAPLs) can migrate within the subsurface for long periods of time along a variety of pathways including fractures, macropores, and micropores. Diffusion of contaminants in the non-aqueous, aqueous, and vapor phase can occur from the fractures and macropores into the matrix of fine-textured media. As a result of these contamination processes, removal of contaminants from the subsurface and the delivery of treatment agents into and throughout contaminated regions are often hindered, making rapid and extensive remediation difficult.