National Library of Energy BETA

Sample records for remove inactive high

  1. Removing High Explosives from Groundwater

    Broader source: Energy.gov [DOE]

    LOS ALAMOS, N.M. – In an initiative supported by EM, Los Alamos National Laboratory’s Corrective Actions Program is addressing high explosive contamination in surface water and groundwater at a location this summer in the forests surrounding the laboratory.

  2. High SO2 Removal Efficiency Testing

    SciTech Connect (OSTI)

    Gary Blythe

    1997-02-12

    This document provides a discussion of the technical progress on DOE/PETC project number DE-AC22-92PC91338, "High Efficiency SO Removal Testing," for 2 the time period 1 October through 31 December 1996. The project involves testing at six full-scale utility flue gas desulfurization (FGD) systems, to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO removal efficiency. The upgrades being 2 evaluated mostly involve using performance additives in the FGD systems. The "base" project involved testing at the Tampa Electric Company?s Big Bend Station. All five potential options to the base program have been exercised by DOE, involving testing at Hoosier Energy?s Merom Station (Option I), Southwestern Electric Power Company?s Pirkey Station (Option II), PSI Energy?s Gibson Station (Option III), Duquesne Light?s Elrama Station (Option IV), and New York State Electric and Gas Corporation?s Kintigh Station (Option V). The originally planned testing has been completed for all six sites. However, additional testing has been planned at the Big Bend Station, and that testing commenced during the current quarter. The remainder of this document is divided into four sections. Section 2, Project Summary, provides a brief overview of the status of technical efforts on this project. Section 3, Results, summarizes the outcome from technical efforts during the quarter, or results from prior quarters that have not been previously reported. In Section 4, Plans for the Next Reporting Period, an overview is provided of the technical efforts that are anticipated for the first quarter of calendar year 1996. Section 5 contains a brief acknowledgment.

  3. High SO2 Removal Efficiency Testing

    SciTech Connect (OSTI)

    Gary Blythe

    1997-04-23

    This document provides a discussion of the technical progress on DOE/PETC project number DE-AC22-92PC91338, "High Efficiency SO2 Removal Testing", for the time period 1 January through 31 March 1997. The project involves testing at six full-scale utility flue gas desulfurization (FGD) systems, to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO2 removal efficiency. The upgrades being evaluated mostly involve using performance additives in the FGD systems. The "base" project involved testing at the Tampa Electric Company?s Big Bend Station. All five potential options to the base program have been exercised by DOE, involving testing at Hoosier Energy?s Merom Station (Option I), Southwestern Electric Power Company?s Pirkey Station (Option II), PSI Energy?s Gibson Station (Option III), Duquesne Light?s Elrama Station (Option IV), and New York State Electric and Gas Corporation?s (NYSEG) Kintigh Station (Option V). The originally planned testing has been completed for all six sites. However, additional testing is planned at the Big Bend Station. The remainder of this document is divided into four sections. Section 2, Project Summary, provides a brief overview of the status of technical efforts on this project. Section 3, Results, summarizes the outcome from technical efforts during the quarter, or results from prior quarters that have not been previously reported. In Section 4, Plans for the Next Reporting Period, an overview is provided of the technical efforts that are anticipated for the second quarter of calendar year 1997. Section 5 contains a brief acknowledgement.

  4. High SO2 Removal Efficiency Testing

    SciTech Connect (OSTI)

    Gary Blythe

    1997-07-29

    This document provides a discussion of the technical progress on DOE/PETC project number DE-AC22-92PC91338, "High Efficiency SO2 Removal Testing", for the time period 1 April through 30 June 1997. The project involves testing at six full-scale utility flue gas desulfurization (FGD) systems to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO2 removal efficiency. The upgrades being evaluated mostly involve using performance additives in the FGD systems. The "base" project involved testing at the Tampa Electric Company?s Big Bend Station. All five potential options to the base program have been exercised by DOE, involving testing at Hoosier Energy?s Merom Station (Option I), Southwestern Electric Power Company?s Pirkey Station (Option II), PSI Energy?s Gibson Station (Option III), Duquesne Light?s Elrama Station (Option IV), and New York State Electric and Gas Corporation?s Kintigh Station (Option V). The originally planned testing has been completed for all six sites. However, additional testing is being conducted at the Big Bend Station. The remainder of this document is divided into four sections. Section 2, Project Summary, provides a brief overview of the status of technical efforts on this project. Section 3, Results, summarizes the outcome from technical efforts during the quarter, or results from prior quarters that have not been previously reported. In Section 4, Plans for the Next Reporting Period, an overview is provided of the technical efforts that are anticipated for the third quarter of calendar year 1997. Section 5 contains a brief acknowledgment.

  5. HIGH SO2 REMOVAL EFFICIENCY TESTING

    SciTech Connect (OSTI)

    Gary M. Blythe; James L. Phillips

    1997-10-15

    This final report describes the results of performance tests at six full-scale wet lime- and limestone-reagent flue gas desulfurization (FGD) systems. The objective of these tests was to evaluate the effectiveness of low capital cost sulfur dioxide (SO{sub 2}) removal upgrades for existing FGD systems as an option for complying with the provisions of the Clean Air Act Amendments of 1990. The upgrade options tested at the limestone-reagent systems included the use of organic acid additives (dibasic acid (DBA) and/or sodium formate) as well as increased reagent ratio (higher excess limestone levels in the recirculating slurry solids) and absorber liquid-to-gas ratio. One system also tested operating at higher flue gas velocities to allow the existing FGD system to treat flue gas from an adjacent, unscrubbed unit. Upgrade options for the one lime-based system tested included increased absorber venturi pressure drop and increased sulfite concentration in the recirculating slurry liquor.

  6. High SO(2) Removal Efficiency Testing.

    SciTech Connect (OSTI)

    Blythe, G.

    1997-10-22

    On the base program, testing was completed at the Tampa Electric Company`s (TECo`s) Big Bend Station in November 1992. The upgrade option tested was DBA additive. Additional testing was conducted at this site during the previous quarter (April through June 1997). Results from that testing were presented in the Technical Progress Report dated July 1997. For Option I, at the Hoosier Energy Merom Station, results from another program co-funded by the Electric Power Research Institute (EPRI) and the National Rural Electric Cooperative Association have been combined with results from DOE-funded testing. Three upgrade options have been tested: DBA additive, sodium formate additive, and high pH set-point operation. All testing was completed by November 1992. There were no activities for this site during the current quarter. Option II involved testing at the Southwestern Electric Power Company Pirkey Station. Both sodium formate and DBA additives were tested as potential upgrade options. All of the testing at this site was completed by May 1993. On Option III, for testing at the PSI Energy Gibson Station, testing with sodium formate additive was completed in early October 1993, and a DBA additive performance and consumption test was completed in March of 1994. There were no efforts for this site during the current quarter. Option IV is for testing at the Duquesne Light Elrama Station. The FGD system employs magnesium-enhanced lime reagent and venturi absorber modules. An EPRI-funded model evaluation of potential upgrade options for this FGD system, along with a preliminary economic evaluation, determined that the most attractive upgrade options for this site were to increase thiosulfate ion concentrations in the FGD system liquor to lower oxidation percentages.

  7. TYPE A VERIFICATION FOR THE HIGH FLUX BEAM REACTOR UNDERGROUND UTILITIES REMOVAL PHASE 2 DF WASTE LINE REMOVAL, BNL

    SciTech Connect (OSTI)

    P.C. Weaver

    2010-07-09

    5098-SR-02-0 PROJECT-SPECIFIC TYPE A VERIFICATION FOR THE HIGH FLUX BEAM REACTOR UNDERGROUND UTILITIES REMOVAL PHASE 2 DF WASTE LINE REMOVAL, BROOKHAVEN NATIONAL LABORATORY

  8. High SO{sub 2} removal efficiency testing

    SciTech Connect (OSTI)

    NONE

    1995-03-10

    Tests were conducted on the Tampa Electric Company`s (TECo) Big Bend Station, Unit 4 flue gas desulfurization (FGD) system to evaluate an option for achieving high sulfur dioxide (SO{sub 2}) removal efficiencies. The option tested was the addition of dibasic acid (DBA) additive. In addition, the effectiveness of other potential options was simulated with the Electric Power Research Institute`s (EPRI) FGD PRocess Integration and Simulation Model (FGDPRISM) after it was calibrated to the system. An economic analysis was conducted to determine the cost effectiveness of each option considered.

  9. Regenerable hydrogen chloride removal sorbent and regenerable multi-functional hydrogen sulfide and hydrogen chloride removal sorbent for high temperature gas streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani (Morgantown, WV)

    2010-08-03

    Regenerable hydrogen chloride removal sorbent and regenerable multi-functional hydrogen sulfide and hydrogen chloride removal sorbent for high temperature gas streams

  10. High SO[sub 2] removal efficiency testing

    SciTech Connect (OSTI)

    Blythe, G.

    1993-04-22

    This document provides a discussion of the technical progress on DOE-PETC Project Number AC22-92PC91338, High Efficiency SO[sub 2] Removal Testing,'' for the time period from January 1 through March 31, 1993. The project involves testing at full-scale utility flue gas desulfurization (FGD) systems to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO[sub 2] removal efficiency. The options to be evaluated primarily involve the addition of organic acid buffers to the FGD systems. The base'' project involves testing at one site, Tampa Electric Company's Big Bend Station. Up to five optional sites may be added to the program at the discretion of DOE-PETC. By March 31, 1993, four of those five options had been exercised. The options include testing at Hoosier Energy's Merom Station (Option I), Southwestern Electric Power Company's (SWEPCo) Pirkey Station (Option II), PSI Energy's Gibson Station (Option III), and Duquesne Light's Elrama Station (Option IV). The remainder of this document is divided into three sections. Section 2, Project Summary, provides a brief overview of the technical efforts on this project during the quarter. Section 3, Results, summarizes the outcome of those technical efforts. Results for the Base Program and for Options I and II are discussed in separate subsections. There are no technical results yet for Options III and IV, which were just exercised by DOE-PETC this quarter.

  11. Polyaluminum chloride with high Al30 content as removal agent for arsenic-contaminated well water

    E-Print Network [OSTI]

    Wehrli, Bernhard

    Polyaluminum chloride with high Al30 content as removal agent for arsenic-contaminated well water-established coagulant in water treatment with high removal efficiency for arsenic. A high content of Al30 nanoclusters¨ berlandstrasse 133, 8600 Du¨bendorf, Switzerland c Water Research Institute (IRSA), National Research Council

  12. Alternatives Generation and Analysis for Heat Removal from High Level Waste Tanks

    SciTech Connect (OSTI)

    WILLIS, W.L.

    2000-06-15

    This document addresses the preferred combination of design and operational configurations to provide heat removal from high-level waste tanks during Phase 1 waste feed delivery to prevent the waste temperature from exceeding tank safety requirement limits. An interim decision for the preferred method to remove the heat from the high-level waste tanks during waste feed delivery operations is presented herein.

  13. SPRU Removes High-Risk Radioactive Waste | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterestedReplacement-2-AA-1 SECTION J APPENDIXAllegations Related to theDoeSPRU Removes

  14. High SO[sub 2] removal efficiency testing

    SciTech Connect (OSTI)

    Blythe, G.

    1992-10-20

    This project involves testing at full-scale utility flue gas desulftirization (FGD) systems to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO[sub 2] removal efficiency. The options to be evaluated primarily involve the addition of organic acid buffers to the FGD systems. The base'' project involves testing at one site, the Tampa Electric Company Big Bend Station. Up to five optional sites may be added to the program at the discretion of DOE-PETC. By 30 September, 1992, two of the five options had been exercised for testing at the Hoosier Energy Merom Station and at the Southwestern Electric Power Company Pirkey Station.

  15. High Metal Removal Rate Process for Machining Difficult Materials

    Broader source: Energy.gov (indexed) [DOE]

    in high precision manufacturing environments: Fuel injector nozzle drilling (automotive industry) Ceramic hole drilling (electronics industry) Precious metal...

  16. The ultra-high lime with aluminum process for removing chloride from recirculating cooling water 

    E-Print Network [OSTI]

    Abdel-wahab, Ahmed Ibraheem Ali

    2004-09-30

    Chloride is a deleterious ionic species in cooling water systems because it is important in promoting corrosion. Chloride can be removed from cooling water by precipitation as calcium chloroaluminate using ultra-high lime with aluminum process (UHLA...

  17. DOE to Remove 200 Metric Tons of Highly Enriched Uranium from...

    Broader source: Energy.gov (indexed) [DOE]

    Administration (NNSA) will remove up to 200 metric tons (MT) of Highly Enriched Uranium (HEU), in the coming decades, from further use as fissile material in U.S. nuclear...

  18. High SO[sub 2] removal efficiency testing

    SciTech Connect (OSTI)

    Blythe, G.

    1993-01-20

    Baseline testing at the base'' site. Tampa Electric Company's (TECo's) Big Bend Station, commenced on September 28 and was completed on October 2. Initial results from this testing were presented in the previous Technical Progress Report, but a more complete discussion is provided in this report. Parametric testing was conducted at the Big Bend site during this quarter to evaluate the effects of dibasic acid (DBA) addition on system SQ removal performance. The parametric tests were conducted from November 2 through 19. A DBA consumption rate test was also conducted, after the parametric tests were completed. The DBA consumption test was conducted from November 21 through 25. Options I and II to the base program were exercised by DOE/PETC at the end of the previous quarter. These options involve testing at Hoosier Energy Rural Electric Cooperative Inc.'s Merom Station and Southwestern Electric Power Company's Pirkey Station, respectively. Testing was conducted at Merom Station during November. Previously, Radian Corporation was the test contractor for EPRI-funded performance additive testing at this site. This EPRI-funded testing involved the equivalent of baseline testing, parametric testing with both DBA and sodium formate performance additives, and an additive consumption test with the DBA additive. The results of the prior testing will be available to support the objectives of this DOE project Consequently, the only testing required at the Merom site was to conduct consumption tests with the sodium formate additive. After a brief baseline repeat test, two sodium formate consumption tests were conducted during the time period from November 11 through 23. Results from the consumption tests are presented and discussed in this report.

  19. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1984-06-19

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  20. High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1982-07-07

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  1. High Metal Removal Rate Process for Machining Difficult Materials

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nA Guide to TappingWORK BREAKDOWNEnergy how toEM&High impactHigh

  2. High Metal Removal Rate Process for Machining Difficult Materials

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nA Guide to TappingWORK BREAKDOWNEnergy how toEM&High impactHighAndy

  3. High Metal Removal Rate Process for Machining Difficult Materials |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancing ProgramsDepartment of¡ ¢HelpHighJian

  4. Highly'efficient'and'effective'removal'of'fat'from'fried'chicken' via'centrifugation'

    E-Print Network [OSTI]

    Amir, Yair

    #12;Highly'efficient'and'effective'removal'of'fat'from'fried'chicken' via'centrifugation' Lucas!centrifugation!of!the!already!cooked!fried!chicken!as!an!alternative!method!for!fat! reduction.!We!show!that!centrifugation!already!fried!chicken,!thus!providing!the!first!method!that!can!be!used!directly! by!consumers!with!access!to!a!centrifuge

  5. Method of and apparatus for removing silicon from a high temperature sodium coolant

    DOE Patents [OSTI]

    Yunker, W.H.; Christiansen, D.W.

    1983-11-25

    This patent discloses a method of and system for removing silicon from a high temperature liquid sodium coolant system for a nuclear reactor. The sodium is cooled to a temperature below the silicon saturation temperature and retained at such reduced temperature while inducing high turbulence into the sodium flow for promoting precipitation of silicon compounds and ultimate separation of silicon compound particles from the liquid sodium.

  6. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction

    SciTech Connect (OSTI)

    Chou, M.I.M.

    1991-01-01

    A pre-combustion coal desulfurization process at 120{degree}C using perchloroethylene (PCE) to remove up to 70% of the organic sulfur has been developed by the Midwest Ore Processing Co. (MWOPC). However, this process has not yet proven to be as successful with Illinois coals as it has for Ohio and Indiana coals. The organic sulfur removal has been achieved only with highly oxidized Illinois coals containing high sulfatic sulfur. A logical explanation for this observation is vital to successful process optimization for the use of Illinois coals. In addition, the high levels of organic sulfur removals observed by the MWOPC may be due to certain errors involved in the ASTM data interpretation; this needs verification. For example, elemental sulfur extracted by the PCE may be derived from pyrite oxidation during coal pre-oxidation, but it may be interpreted as organic sulfur removed by the PCE using ASTM analysis. The goals of this research are: (1) to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process reported by the MWOPC, (2) to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation, and (3) to determine the suitability of Illinois coals for use in the PCE desulfurization process. This project involves the Illinois State Geological Survey (ISGS), Eastern Illinois University (EIU), the University of Illinois-Urbana/Champaign (UI-UC), and the University of Kentucky, Lexington (UK). This is the first year of a two-year project.

  7. Assessment of commercially available ion exchange materials for cesium removal from highly alkaline wastes

    SciTech Connect (OSTI)

    Brooks, K.P.; Kim, A.Y.; Kurath, D.E.

    1996-04-01

    Approximately 61 million gallons of nuclear waste generated in plutonium production, radionuclide removal campaigns, and research and development activities is stored on the Department of Energy`s Hanford Site, near Richland, Washington. Although the pretreatment process and disposal requirements are still being defined, most pretreatment scenarios include removal of cesium from the aqueous streams. In many cases, after cesium is removed, the dissolved salt cakes and supernates can be disposed of as LLW. Ion exchange has been a leading candidate for this separation. Ion exchange systems have the advantage of simplicity of equipment and operation and provide many theoretical stages in a small space. The organic ion exchange material Duolite{trademark} CS-100 has been selected as the baseline exchanger for conceptual design of the Initial Pretreatment Module (IPM). Use of CS-100 was chosen because it is considered a conservative, technologically feasible approach. During FY 96, final resin down-selection will occur for IPM Title 1 design. Alternate ion exchange materials for cesium exchange will be considered at that time. The purpose of this report is to conduct a search for commercially available ion exchange materials which could potentially replace CS-100. This report will provide where possible a comparison of these resin in their ability to remove low concentrations of cesium from highly alkaline solutions. Materials which show promise can be studied further, while less encouraging resins can be eliminated from consideration.

  8. Novel Sorbent-Based Process for High Temperature Trace Metal Removal

    SciTech Connect (OSTI)

    Gokhan Alptekin

    2008-09-30

    The objective of this project was to demonstrate the efficacy of a novel sorbent can effectively remove trace metal contaminants (Hg, As, Se and Cd) from actual coal-derived synthesis gas streams at high temperature (above the dew point of the gas). The performance of TDA's sorbent has been evaluated in several field demonstrations using synthesis gas generated by laboratory and pilot-scale coal gasifiers in a state-of-the-art test skid that houses the absorbent and all auxiliary equipment for monitoring and data logging of critical operating parameters. The test skid was originally designed to treat 10,000 SCFH gas at 250 psig and 350 C, however, because of the limited gas handling capabilities of the test sites, the capacity was downsized to 500 SCFH gas flow. As part of the test program, we carried out four demonstrations at two different sites using the synthesis gas generated by the gasification of various lignites and a bituminous coal. Two of these tests were conducted at the Power Systems Demonstration Facility (PSDF) in Wilsonville, Alabama; a Falkirk (North Dakota) lignite and a high sodium lignite (the PSDF operator Southern Company did not disclose the source of this lignite) were used as the feedstock. We also carried out two other demonstrations in collaboration with the University of North Dakota Energy Environmental Research Center (UNDEERC) using synthesis gas slipstreams generated by the gasification of Sufco (Utah) bituminous coal and Oak Hills (Texas) lignite. In the PSDF tests, we showed successful operation of the test system at the conditions of interest and showed the efficacy of sorbent in removing the mercury from synthesis gas. In Test Campaign No.1, TDA sorbent reduced Hg concentration of the synthesis gas to less than 5 {micro}g/m{sup 3} and achieved over 99% Hg removal efficiency for the entire test duration. Unfortunately, due to the relatively low concentration of the trace metals in the lignite feed and as a result of the intermittent operation of the PSDF gasifier (due to the difficulties in the handling of the low quality lignite), only a small fraction of the sorbent capacity was utilized (we measured a mercury capacity of 3.27 mg/kg, which is only a fraction of the 680 mg/kg Hg capacity measured for the same sorbent used at our bench-scale evaluations at TDA). Post reaction examination of the sorbent by chemical analysis also indicated some removal As and Se (we did not detect any significant amounts of Cd in the synthesis gas or over the sorbent). The tests at UNDEERC was more successful and showed clearly that the TDA sorbent can effectively remove Hg and other trace metals (As and Se) at high temperature. The on-line gas measurements carried out by TDA and UNDEERC separately showed that TDA sorbent can achieve greater than 95% Hg removal efficiency at 260 C ({approx}200g sorbent treated more than 15,000 SCF synthesis gas). Chemical analysis conducted following the tests also showed modest amounts of As and Se accumulation in the sorbent bed (the test durations were still short to show higher capacities to these contaminants). We also evaluated the stability of the sorbent and the fate of mercury (the most volatile and unstable of the trace metal compounds). The Synthetic Ground Water Leaching Procedure Test carried out by an independent environmental laboratory showed that the mercury will remain on the sorbent once the sorbent is disposed. Based on a preliminary engineering and cost analysis, TDA estimated the cost of mercury removal from coal-derived synthesis gas as $2,995/lb (this analysis assumes that this cost also includes the cost of removal of all other trace metal contaminants). The projected cost will result in a small increase (less than 1%) in the cost of energy.

  9. Sorbents for High Temperature Removal of Arsenic from Coal-Derived Synthesis Gas

    SciTech Connect (OSTI)

    Alptekin, G.O.; Copeland, R.; Dubovik, M.; Gershanovich, Y.

    2002-09-20

    Gasification technologies convert coal and other heavy feedstocks into synthesis gas feed streams that can be used in the production of a wide variety of chemicals, ranging from hydrogen through methanol, ammonia, acetic anhydride, dimethyl ether (DME), methyl tertiary butyl ether (MTBE), high molecular weight liquid hydrocarbons and waxes. Syngas can also be burned directly as a fuel in advanced power cycles to generate electricity with very high efficiency. However, the coal-derived synthesis gas contains a myriad of trace contaminants that may poison the catalysts that are used in the downstream manufacturing processes and may also be regulated in power plant emissions. Particularly, the catalysts used in the conversion of synthesis gas to methanol and other liquid fuels (Fischer-Tropsch liquids) have been found to be very sensitive to the low levels of poisons, especially arsenic, that are present in the synthesis gas from coal. TDA Research, Inc. (TDA) is developing an expendable high capacity, low-cost chemical absorbent to remove arsenic from coal-derived syngas. Unlike most of the commercially available sorbents that physically adsorb arsenic, TDA's sorbent operates at elevated temperatures and removes the arsenic through chemical reaction. The arsenic content in the coal gas stream is reduced to ppb levels with the sorbent by capturing and stabilizing the arsenic gas (As4) and arsenic hydrides (referred to as arsine, AsH3) in the solid state. To demonstrate the concept of high temperature arsenic removal from coal-derived syngas, we carried out bench-scale experiments to test the absorption capacity of a variety of sorbent formulations under representative conditions. Using on-line analysis techniques, we monitored the pre- and post-breakthrough arsine concentrations over different sorbent samples. Some of these samples exhibited pre-breakthrough arsine absorption capacity over 40% wt. (capacity is defined as lb of arsenic absorbed/lb of sorbent), while maintaining an arsine outlet concentration at less than 10 ppb.

  10. Removal of H{sub 2}S using molten carbonate at high temperature

    SciTech Connect (OSTI)

    Kawase, Makoto, E-mail: kawase@criepi.denken.or.jp; Otaka, Maromu

    2013-12-15

    Highlights: • The performance of molten carbonate for the removal of H{sub 2}S improves at higher temperatures. • The degree of H{sub 2}S removal is significantly affected by the CO{sub 2} concentration in syngas. • Addition of carbon elements, such as char and tar, decrease the negative effects of CO{sub 2}. • Continuous addition of carbon elements into molten carbonate enables continuous desulfurization. • Desulfurization using molten carbonate is suitable for gasification gas. - Abstract: Gasification is considered to be an effective process for energy conversion from various sources such as coal, biomass, and waste. Cleanup of the hot syngas produced by such a process may improve the thermal efficiency of the overall gasification system. Therefore, the cleanup of hot syngas from biomass gasification using molten carbonate is investigated in bench-scale tests. Molten carbonate acts as an absorbent during desulfurization and dechlorination and as a thermal catalyst for tar cracking. In this study, the performance of molten carbonate for removing H{sub 2}S was evaluated. The temperature of the molten carbonate was set within the range from 800 to 1000 °C. It is found that the removal of H{sub 2}S is significantly affected by the concentration of CO{sub 2} in the syngas. When only a small percentage of CO{sub 2} is present, desulfurization using molten carbonate is inadequate. However, when carbon elements, such as char and tar, are continuously supplied, H{sub 2}S removal can be maintained at a high level. To confirm the performance of the molten carbonate gas-cleaning system, purified biogas was used as a fuel in power generation tests with a molten carbonate fuel cell (MCFC). The fuel cell is a high-performance sensor for detecting gaseous impurities. When purified gas from a gas-cleaning reactor was continuously supplied to the fuel cell, the cell voltage remained stable. Thus, the molten carbonate gas-cleaning reactor was found to afford good gas-cleaning performance.

  11. In Situ Stabilization of Inactive Low Level Waste Pipelines in the Melton Valley Watershed at Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Cange, J.; Cox, J. [Bechtel Jacobs Company, LLC, Oak Ridge, TN (United States); Coye, St. [Sevenson Environmental Services, Inc., Niagara Falls, NY (United States); Skinner, R. [US DOE Oak Ridge Operations, Oak Ridge, TN (United States); Shaw, K. [Restoration Services, Inc., Oak Ridge, TN (United States); McGinley, S. [Pro2Serve, Oak Ridge, TN (United States)

    2008-07-01

    The Melton Valley watershed at Oak Ridge National Laboratory (ORNL) contained an inactive waste pipeline system consisting of approximately 12 kilometers of buried waste pipelines and over 142 m{sup 3} in surface/subsurface appurtenances (e.g., vents, valve pits, pump vaults, etc.). Historically, the system was used to transport liquid low level and process waste between generator facilities in Melton Valley, storage and disposal sites in Melton Valley, and storage/treatment facilities in Bethel Valley. The selected remedy in the Melton Valley Record of Decision (ROD) for inactive pipelines was isolation, removal, or stabilization. Pipeline remediation activities began in the summer of 2005 and were completed in the spring of 2006. The task entailed an iterative process of selecting pipeline access points, excavating and exposing pipelines, performing tapping, draining and cutting activities, either installing fittings for grouting or plugging and capping the lines. Grouting was accomplished using paired access points, with one location serving as the grout injection point and the other as vent/drain and grout confirmation point. Grouting was conducted by pumping a cement-bentonite grout into the specially installed fittings and typically proceeded from a low point to a high point to ensure complete filling of the pipeline (i.e., no void space). The project successfully grouted a total of 8,454 meters (linear distance) of pipeline; another 3,573 meters of pipeline was stabilized through isolation. (authors)

  12. REMOVAL OF SOLIDS FROM HIGHLY ENRICHED URANIUM SOLUTIONS USING THE H-CANYON CENTRIFUGE

    SciTech Connect (OSTI)

    Rudisill, T; Fernando Fondeur, F

    2009-01-15

    Prior to the dissolution of Pu-containing materials in HB-Line, highly enriched uranium (HEU) solutions stored in Tanks 11.1 and 12.2 of H-Canyon must be transferred to provide storage space. The proposed plan is to centrifuge the solutions to remove solids which may present downstream criticality concerns or cause operational problems with the 1st Cycle solvent extraction due to the formation of stable emulsions. An evaluation of the efficiency of the H-Canyon centrifuge concluded that a sufficient amount (> 90%) of the solids in the Tank 11.1 and 12.2 solutions will be removed to prevent any problems. We based this conclusion on the particle size distribution of the solids isolated from samples of the solutions and the calculation of particle settling times in the centrifuge. The particle size distributions were calculated from images generated by scanning electron microscopy (SEM). The mean particle diameters for the distributions were 1-3 {micro}m. A significant fraction (30-50%) of the particles had diameters which were < 1 {micro}m; however, the mass of these solids is insignificant (< 1% of the total solids mass) when compared to particles with larger diameters. It is also probable that the number of submicron particles was overestimated by the software used to generate the particle distribution due to the morphology of the filter paper used to isolate the solids. The settling times calculated for the H-Canyon centrifuge showed that particles with diameters less than 1 to 0.5 {micro}m will not have sufficient time to settle. For this reason, we recommend the use of a gelatin strike to coagulate the submicron particles and facilitate their removal from the solution; although we have no experimental basis to estimate the level of improvement. Incomplete removal of particles with diameters < 1 {micro}m should not cause problems during purification of the HEU in the 1st Cycle solvent extraction. Particles with diameters > 1 {micro}m account for > 99% of the solid mass and will be efficiently removed by the centrifuge; therefore, the formation of emulsions during solvent extraction operations is not an issue. Under the current processing plan, the solutions from Tanks 11.1 and 12.2 will be transferred to the enriched uranium storage (EUS) tank following centrifugation. The solution from Tanks 11.1 and 12.2 may remain in the EUS tank for an extended time prior to purification. The effects of extended storage on the solution were not evaluated as part of this study.

  13. DEVELOPMENT OF DISPOSABLE SORBENTS FOR CHLORIDE REMOVAL FROM HIGH TEMPERATURE COAL-DERIVED GASES

    SciTech Connect (OSTI)

    Gopala Krishnan; Raghubir Gupta

    1999-09-01

    Advanced integrated-gasification combined-cycle (IGCC) and integrated-gasification fuel cell (IGFC) systems require the development of high temperature sorbents for the removal of hydrogen chloride (HCl) vapor to less than 1 parts-per-million (ppm) levels. HCl is a highly reactive, corrosive, and toxic gas which must be removed to meet environmental regulations, to protect power generation equipment, and to minimize deterioration of hot gas desulfurization sorbents. The objective of this program was to develop disposable, alkali-based sorbents capable of reducing HCl vapor levels to less than 1 ppm in the temperature range from 400 to 750 C and pressures in the range from 1 to 20 atm. The primary areas of focus of this program were to investigate different methods of sorbent fabrication, testing their suitability for different reactor configurations, obtaining reaction kinetics data, and conducting a preliminary economic feasibility assessment. This program was a joint effort between SRI International (SRI), Research Triangle Institute (RTI), and General Electric Corporate Research and Development (GE-CRD). SRI, the prime contractor and RTI, a major subcontractor, performed most of the work in this program. Thermochemical calculations indicated that sodium-based sorbents were capable of reducing HCl vapor levels to less than 1 ppm at temperatures up to 650 C, but the regeneration of spent sorbents would require complex process steps. Nahcolite (NaHCO{sub 3}), a naturally-occurring mineral, could be used as an inexpensive sorbent to remove HCl vapor in hot coal gas streams. In the current program, nahcolite powder was used to fabricate pellets suitable for fixed-bed reactors and granules suitable for fluidized-bed reactors. Pilot-scale equipment were used to prepare sorbents in large batches: pellets by disk pelletization and extrusion techniques, and granules by granulation and spray-drying techniques. Bench-scale fixed- and fluidized-bed reactors were assembled at SRI and RTI to conduct tests at high-temperature, high-pressure conditions (HTHP). The HTHP tests confirmed the ability of nahcolite pellets and granules to reduce the HCl vapor levels to less than 1 ppm levels with a very high sorbent utilization for chloride capture. The effect of several operating variables such as temperature, pressure, presence of hydrogen sulfide, and sorbent preparation methods was studied on the efficacy of HCl removal by the sorbent. Pilot-scale tests were performed in the fluidized-bed mode at the gasifier facility at the GE-CRD. Sorbent exposure tests were also conducted using a hot coal gas stream from the DOE/FETC's fluidized-bed gasifier at Morgantown, WV. These tests confirmed the results obtained at SRI and RTI. A preliminary economic assessment showed that the cost of HCl removal in a commercial IGCC system will be about $0.001/kWh (1 mills/kWh).

  14. Mercury Reduction and Removal from High Level Waste at the Defense Waste Processing Facility - 12511

    SciTech Connect (OSTI)

    Behrouzi, Aria [Savannah River Remediation, LLC (United States); Zamecnik, Jack [Savannah River National Laboratory, Aiken, South Carolina, 29808 (United States)

    2012-07-01

    The Defense Waste Processing Facility processes legacy nuclear waste generated at the Savannah River Site during production of enriched uranium and plutonium required by the Cold War. The nuclear waste is first treated via a complex sequence of controlled chemical reactions and then vitrified into a borosilicate glass form and poured into stainless steel canisters. Converting the nuclear waste into borosilicate glass is a safe, effective way to reduce the volume of the waste and stabilize the radionuclides. One of the constituents in the nuclear waste is mercury, which is present because it served as a catalyst in the dissolution of uranium-aluminum alloy fuel rods. At high temperatures mercury is corrosive to off-gas equipment, this poses a major challenge to the overall vitrification process in separating mercury from the waste stream prior to feeding the high temperature melter. Mercury is currently removed during the chemical process via formic acid reduction followed by steam stripping, which allows elemental mercury to be evaporated with the water vapor generated during boiling. The vapors are then condensed and sent to a hold tank where mercury coalesces and is recovered in the tank's sump via gravity settling. Next, mercury is transferred from the tank sump to a purification cell where it is washed with water and nitric acid and removed from the facility. Throughout the chemical processing cell, compounds of mercury exist in the sludge, condensate, and off-gas; all of which present unique challenges. Mercury removal from sludge waste being fed to the DWPF melter is required to avoid exhausting it to the environment or any negative impacts to the Melter Off-Gas system. The mercury concentration must be reduced to a level of 0.8 wt% or less before being introduced to the melter. Even though this is being successfully accomplished, the material balances accounting for incoming and collected mercury are not equal. In addition, mercury has not been effectively purified and collected in the Mercury Purification Cell (MPC) since 2008. A significant cleaning campaign aims to bring the MPC back up to facility housekeeping standards. Two significant investigations are being undertaken to restore mercury collection. The SMECT mercury pump has been removed from the tank and will be functionally tested. Also, research is being conducted by the Savannah River National Laboratory to determine the effects of antifoam addition on the behavior of mercury. These path forward items will help us better understand what is occurring in the mercury collection system and ultimately lead to an improved DWPF production rate and mercury recovery rate. (authors)

  15. ARM - TWP Manus Site-Inactive

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow, AlaskaManus Site-Inactive TWP Related Links Facilities and Instruments Manus

  16. ARM - TWP Nauru Site-Inactive

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow, AlaskaManus Site-Inactive TWP Related Links Facilities and Instruments

  17. High SO{sub 2} removal efficiency testing. Quarterly report, July - September 1996

    SciTech Connect (OSTI)

    Blythe, G.

    1996-07-01

    This document provides a discussion of the technical progress on DOE/PETC project number DE-AC22-92PC91338, ``High Efficiency SO{sub 2} Removal Testing,`` for the time period 1 July through 30 September 1996. The project involves testing at six full-scale utility flue gas desulfurization (FGD) systems, to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO{sub 2} removal efficiency. The upgrades being evaluated mostly involve using performance additives in the FGD systems. The ``base`` project involved testing at the Tampa Electric Company`s Big Bend Station. All five potential options to the base program have been exercised by DOE, involving testing at Hoosier Energy`s Merom Station (Option I), Southwestern Electric Power Company`s Pirkey Station (Option II), PSI Energy`s Gibson Station (Option III), Duquesne Light`s Elrama Station (Option IV), and New York State Electric and Gas Corporation`s Kintigh Station (Option V). The originally planned testing has been completed for all six sites. The remainder of this document provides a brief overview of the status of technical efforts on this project, including those efforts anticipated for the first quarter of calendar year 1996, summarizes results from prior quarters, and contains a brief acknowledgment. 13 refs.

  18. High SO{sub 2} removal efficiency testing. Technical progress report, [January 1--March 31, 1993

    SciTech Connect (OSTI)

    Blythe, G.

    1993-04-22

    This document provides a discussion of the technical progress on DOE-PETC Project Number AC22-92PC91338, ``High Efficiency SO{sub 2} Removal Testing,`` for the time period from January 1 through March 31, 1993. The project involves testing at full-scale utility flue gas desulfurization (FGD) systems to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO{sub 2} removal efficiency. The options to be evaluated primarily involve the addition of organic acid buffers to the FGD systems. The ``base`` project involves testing at one site, Tampa Electric Company`s Big Bend Station. Up to five optional sites may be added to the program at the discretion of DOE-PETC. By March 31, 1993, four of those five options had been exercised. The options include testing at Hoosier Energy`s Merom Station (Option I), Southwestern Electric Power Company`s (SWEPCo) Pirkey Station (Option II), PSI Energy`s Gibson Station (Option III), and Duquesne Light`s Elrama Station (Option IV). The remainder of this document is divided into three sections. Section 2, Project Summary, provides a brief overview of the technical efforts on this project during the quarter. Section 3, Results, summarizes the outcome of those technical efforts. Results for the Base Program and for Options I and II are discussed in separate subsections. There are no technical results yet for Options III and IV, which were just exercised by DOE-PETC this quarter.

  19. High SO{sub 2} removal efficiency testing. Technical progress report, July--September 1995

    SciTech Connect (OSTI)

    Blythe, G.

    1995-10-18

    This document provides a discussion of the technical progress on DOE/PETC project number DE-AC22-92PC91338, {open_quotes}High Efficiency SO{sub 2} Removal Testing{close_quotes}, for the time period 1 July through 30 September 1995. The project involves testing at six full-scale utility flue gas desulfurization (FGD) systems, to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO{sub 2} removal efficiency. The upgrades being evaluated mostly involve using performance additives in the FGD systems. The {open_quotes}base{close_quotes} project involved testing at the Tampa Electric Company Big Bend station. All five potential options to the base program have been exercised by DOE, involving testing at Hoosier Energy`s Merom Station (Option I), Southwestern Electric Power Company`s Pirkey Station (Option II), PSI Energy`s Gibson Station (Option III), Duquesne Light`s Elrama Station (Option IV), and New York State Electric and Gas Corporation`s Kintigh Station (Option V). The originally planned testing has been completed for all six sites. The remainder of this document is divided into four sections. Section 2, Project Summary, provides a brief overview of the status of technical efforts on this project. Section 3, Results, summarizes the outcome from technical efforts during the quarter or results from prior quarters that have not been previously reported. In Section 4, Plans for the Next Reporting Period, an overview is provided of the technical efforts that are anticipated for the fourth quarter of calendar year 1995. Section 5 contains a brief acknowledgement.

  20. High SO{sub 2} removal efficiency testing. Quarterly status report, October 1994--December 1994

    SciTech Connect (OSTI)

    Blythe, G.

    1995-02-03

    This document provides a discussion of the technical progress on DOE/PETC project number DE-AC22-92PC91338, {open_quotes}High Efficiency SO{sub 2} Removal Testing{close_quotes}, for the time period 1 October through 31 December 1994. The project involves testing at six full-scale utility flue gas desulfurization (FGD) systems, to evaluate low-capital cost upgrades that may allow these systems to achieve up to 98% SO{sub 2} removal efficiency. The upgrades to be evaluated primAllily involve using additives in the FGD systems. The {open_quotes}base{close_quotes} project involved testing at the Tampa Electric Company Big Bend station. AR five potential options to the base program have been exercised by DOE, involving testing at the Hoosier Energy Merom Station (Option I), the Southwestern Electric Power Company Pirkey Station (Option II), the PSI Energy Gibson Station (Option III), the Duquesne Light Elrama Station (Option IV), and the New York State Electric and Gas Corporation (NYSEG) Kintigh Station (Option V). By the beginning of the fourth quarter of 1994, testing had been completed for the base project and for all options. The remainder of this document is divided into four sections. Section 2, Project Summary, provides a brief overview of the status of technical efforts on this project. Section 3, Results, summarizes the outcome from these technical efforts during the quarter. In Section 4, Plans for the Next Reporting Period, an overview is provided of the technical efforts that are anticipated for the first quarter of calendar year 1995. Section 5 contains a brief acknowledgement.

  1. A microfluidics approach towards high-throughput pathogen removal from blood using margination

    E-Print Network [OSTI]

    Hou, Han Wei

    Sepsis is an adverse systemic inflammatory response caused by microbial infection in blood. This paper reports a simple microfluidic approach for intrinsic, non-specific removal of both microbes and inflammatory cellular ...

  2. High SO{sub 2} removal efficiency testing. Technical progress report

    SciTech Connect (OSTI)

    Blythe, G.

    1994-04-28

    The project involves testing at six full-scale utility flue gas desulfurization (FGD) systems, to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO{sub 2} removal efficiency. The upgrades to be evaluated mostly involve using additives in the FGD systems. On the base program, testing was completed at the Tampa Electric Big Bend Station in November 1992. The upgrade option tested was DBA additive. For Option 1, at the Hoosier Energy Merom Station, three upgrade options have been tested: DBA additive, sodium formate additive, and high pH set point operation. Option 2 has involved testing at the Southwestern Electric Power Company Pirkey Station. Both sodium formate and DBA additives were tested as potential upgrade options at Pirkey. On Option 3, for testing at the PSI Energy Gibson Station, a DBA additive performance and consumption test was conducted in late February through mid-March 1994. Preliminary results from these tests are discussed in Section 3 of this progress report. Option 4 is for testing at the Duquesne Light Elrama Station. The FGD system employs magnesium-enhanced lime reagent and venturi absorber modules. An EPRI-funded model evaluation of potential upgrade options for this FGD system, along with a preliminary economic evaluation, determined that the most attractive upgrade options for this site were to increase thiosulfate ion concentrations in the FGD system liquor to lower oxidation percentages and increase liquid-phase sulfite alkalinity, and to increase the venturi absorber pressure drop to improve gas/liquid contacting. Parametric testing of these upgrade options was conducted in late March 1994. Preliminary results from these tests are also discussed in Section 3 of this progress report.

  3. PROJECT-SPECIFIC TYPE A VERIFICATION FOR THE HIGH FLUX BEAM REACTOR UNDERGROUND UTILITIES REMOVAL PHASE 3 TRENCH 1, BROOKHAVEN NATIONAL LABORATORY UPTON, NEW YORK

    SciTech Connect (OSTI)

    E.M. Harpenau

    2010-12-15

    5098-SR-05-0 PROJECT-SPECIFIC TYPE A VERIFICATION FOR THE HIGH FLUX BEAM REACTOR UNDERGROUND UTILITIES REMOVAL PHASE 3 TRENCH 1 BROOKHAVEN NATIONAL LABORATORY

  4. PROJECT-SPECIFIC TYPE A VERIFICATION FOR THE HIGH FLUX BEAM REACTOR UNDERGROUND UTILITIES REMOVAL PHASE 3 TRENCH 5, BROOKHAVEN NATIONAL LABORATORY UPTON, NEW YORK

    SciTech Connect (OSTI)

    P.C. Weaver

    2010-11-03

    5098-SR-04-0 PROJECT-SPECIFIC TYPE A VERIFICATION FOR THE HIGH FLUX BEAM REACTOR UNDERGROUND UTILITIES REMOVAL PHASE 3 TRENCH 5, BROOKHAVEN NATIONAL LABORATORY

  5. A Low Cost and High Efficient Facility for Removal of $\\SO_{2}$ and $\\NO_{x}$ in the Flue Gas from Coal Fire Power Plant

    E-Print Network [OSTI]

    Pei, Y J; Dong, X; Feng, G Y; Fu, S; Gao, H; Hong, Y; Li, G; Li, Y X; Shang, L; Sheng, L S; Tian, Y C; Wang, X Q; Wang, Y; Wei, W; Zhang, Y W; Zhou, H J

    2001-01-01

    A Low Cost and High Efficient Facility for Removal of $\\SO_{2}$ and $\\NO_{x}$ in the Flue Gas from Coal Fire Power Plant

  6. HIGH LEVEL WASTE MECHANCIAL SLUDGE REMOVAL AT THE SAVANNAH RIVER SITE F TANK FARM CLOSURE PROJECT

    SciTech Connect (OSTI)

    Jolly, R; Bruce Martin, B

    2008-01-15

    The Savannah River Site F-Tank Farm Closure project has successfully performed Mechanical Sludge Removal (MSR) using the Waste on Wheels (WOW) system for the first time within one of its storage tanks. The WOW system is designed to be relatively mobile with the ability for many components to be redeployed to multiple waste tanks. It is primarily comprised of Submersible Mixer Pumps (SMPs), Submersible Transfer Pumps (STPs), and a mobile control room with a control panel and variable speed drives. In addition, the project is currently preparing another waste tank for MSR utilizing lessons learned from this previous operational activity. These tanks, designated as Tank 6 and Tank 5 respectively, are Type I waste tanks located in F-Tank Farm (FTF) with a capacity of 2,840 cubic meters (750,000 gallons) each. The construction of these tanks was completed in 1953, and they were placed into waste storage service in 1959. The tank's primary shell is 23 meters (75 feet) in diameter, and 7.5 meters (24.5 feet) in height. Type I tanks have 34 vertically oriented cooling coils and two horizontal cooling coil circuits along the tank floor. Both Tank 5 and Tank 6 received and stored F-PUREX waste during their operating service time before sludge removal was performed. DOE intends to remove from service and operationally close (fill with grout) Tank 5 and Tank 6 and other HLW tanks that do not meet current containment standards. Mechanical Sludge Removal, the first step in the tank closure process, will be followed by chemical cleaning. After obtaining regulatory approval, the tanks will be isolated and filled with grout for long-term stabilization. Mechanical Sludge Removal operations within Tank 6 removed approximately 75% of the original 95,000 liters (25,000 gallons). This sludge material was transferred in batches to an interim storage tank to prepare for vitrification. This operation consisted of eleven (11) Submersible Mixer Pump(s) mixing campaigns and multiple intraarea transfers utilizing STPs from July 2006 to August 2007. This operation and successful removal of sludge material meets requirement of approximately 19,000 to 28,000 liters (5,000 to 7,500 gallons) remaining prior to the Chemical Cleaning process. Removal of the last 35% of sludge was exponentially more difficult, as less and less sludge was available to mobilize and the lighter sludge particles were likely removed during the early mixing campaigns. The removal of the 72,000 liters (19,000 gallons) of sludge was challenging due to a number factors. One primary factor was the complex internal cooling coil array within Tank 6 that obstructed mixer discharge jets and impacted the Effective Cleaning Radius (ECR) of the Submersible Mixer Pumps. Minimal access locations into the tank through tank openings (risers) presented a challenge because the available options for equipment locations were very limited. Mechanical Sludge Removal activities using SMPs caused the sludge to migrate to areas of the tank that were outside of the SMP ECR. Various SMP operational strategies were used to address the challenge of moving sludge from remote areas of the tank to the transfer pump. This paper describes in detail the Mechanical Sludge Removal activities and mitigative solutions to cooling coil obstructions and other challenges. The performance of the WOW system and SMP operational strategies were evaluated and the resulting lessons learned are described for application to future Mechanical Sludge Removal operations.

  7. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  8. Nanopore reactive adsorbents for the high-efficiency removal of waste species

    DOE Patents [OSTI]

    Yang, Arthur Jing-Min; Zhang, Yuehua

    2005-01-04

    A nanoporous reactive adsorbent incorporates a relatively small number of relatively larger reactant, e.g., metal, enzyme, etc., particles (10) forming a discontinuous or continuous phase interspersed among and surrounded by a continuous phase of smaller adsorbent particles (12) and connected interstitial pores (14) therebetween. The reactive adsorbent can effectively remove inorganic or organic impurities in a liquid by causing the liquid to flow through the adsorbent. For example, silver ions may be adsorbed by the adsorbent particles (12) and reduced to metallic silver by reducing metal, such as ions, as the reactant particles (10). The column can be regenerated by backwashing with the liquid effluent containing, for example, acetic acid.

  9. Microstructure evolution of Li uptake/removal in MoO{sub 2}@C nanoparticles with high lithium storage performance

    SciTech Connect (OSTI)

    Liu, Yulong; Zhang, Hong; Ouyang, Pan; Chen, Wenhao [School of Materials Science and Engineering, Central South University, Changsha 410083 (China); Li, Zhicheng, E-mail: zhchli@mail.csu.edu.cn [School of Materials Science and Engineering, Central South University, Changsha 410083 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083 (China)

    2014-02-01

    Highlights: • The carbon-coated MoO{sub 2} (MoO{sub 2}@C) ultra fine nanoparticles are synthesized by one-pot hydrothermal method. • MoO{sub 2}@C nanoparticles have high specific capacity, excellent cycling performance and rate performance. • Phase transformations for lithium ion uptake/removal are examined carefully by TEM. • Phase transformations are highly reversible during the redox process. - Abstract: A facile one pot strategy of a hydrothermal methodology was applied to synthesize the carbon coated MoO{sub 2} (MoO{sub 2}@C) nanostructured particles, which are composed of ultra fine nanoparticles with homogeneous carbon coating about several nanometers. As an electrode in lithium ion batteries, the MoO{sub 2}@C shows a high specific capacity and reversible capacity (730 mA h g{sup ?1} after 60 cycles). Microstructure investigations, by using a high resolution transmission electron microscopy, of the MoO{sub 2}@C based electrodes employed at various states during the first discharge/charge cycle were conducted to elucidate the lithium ion uptake/removal mechanism and cycling behavior. In the lithium uptake process, the original MoO{sub 2} phase transfers into Li{sub 0.98}MoO{sub 2} through an addition type reaction, and then nanosized metallic Mo emerges as a result of a conversion reaction. In turn, Mo could be oxidized to the intermediate Li{sub 0.98}MoO{sub 2} before converting to hyperfine MoO{sub 2} phase on upcoming lithium removal process.

  10. CO.sub.2 removal sorbent composition with high chemical stability during multiple cycles

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.; Rosencwaig, Shira

    2015-09-22

    Disclosed herein is a clay-alkali-amine CO.sub.2 sorbent composition prepared by integrating a clay substrate, basic alkali salt, and amine liquid. The basic alkali salt is present relative to the clay substrate in a weight ratio of from about 1 part to about 50 parts per 100 parts of the clay substrate. The amine liquid is present relative to a clay-alkali combination in a weight ratio of from about 1 part to about 10 parts per 10 parts of the clay-alkali combination. The clay-alkali-amine C02 sorbent is particularly advantageous for low temperature CO.sub.2 removal cycles in a gas stream having a C02 concentration less than around 2000 ppm and an oxygen concentration around 21%, such as air.

  11. High SO{sub 2} removal efficiency testing. Technical progress report, January--March 1996

    SciTech Connect (OSTI)

    Blythe, G.

    1996-04-19

    This project involves testing at six full-scale utility flue gas desulfurization (FGD) systems, to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO{sub 2} removal efficiency. The upgrades being evaluated primarily involve using performance additives in the FGD systems. The base project involved testing at the Tampa Electric Company Big Bend station. All five potential options to the base program have been exercised by DOE, involving testing at Hooiser Energy`s Merom Station (Option I), Southwestern Electric Power Company`s Pirkey Station (Option II), PSI Energy`s Gibson Station (Option III), Duquesne Light`s Elrama Station (Option IV), and New York State Electric and Gas Corporation`s Kintigh Station (Option V). The originally planned testing has been completed for all six sites.

  12. Process for removing sulfur from sulfur-containing gases: high calcium fly-ash

    DOE Patents [OSTI]

    Rochelle, Gary T. (Austin, TX); Chang, John C. S. (Cary, NC)

    1991-01-01

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accordance with the present invention include preparing an aqueous slurry composed of a calcium alkali source and a source of reactive silica and/or alumina, heating the slurry to above-ambient temperatures for a period of time in order to facilitate the formation of sulfur-absorbing calcium silicates or aluminates, and treating the gas with the heat-treated slurry components. Examples disclosed herein demonstrate the utility of these processes in achieving improved sulfur-absorbing capabilities. Additionally, disclosure is provided which illustrates preferred configurations for employing the present processes both as a dry sorbent injection and for use in conjunction with a spray dryer and/or bagfilter. Retrofit application to existing systems is also addressed.

  13. High SO{sub 2} removal efficiency testing. Technical progress report

    SciTech Connect (OSTI)

    Blythe, G.

    1992-10-20

    This project involves testing at full-scale utility flue gas desulftirization (FGD) systems to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO{sub 2} removal efficiency. The options to be evaluated primarily involve the addition of organic acid buffers to the FGD systems. The ``base`` project involves testing at one site, the Tampa Electric Company Big Bend Station. Up to five optional sites may be added to the program at the discretion of DOE-PETC. By 30 September, 1992, two of the five options had been exercised for testing at the Hoosier Energy Merom Station and at the Southwestern Electric Power Company Pirkey Station.

  14. Engineering assessment of inactive uranium mill tailings

    SciTech Connect (OSTI)

    Not Available

    1981-07-01

    The Grand Junction site has been reevaluated in order to revise the October 1977 engineering assessment of the problems resulting from the existence of radioactive uranium mill tailings at Grand Junction, Colorado. This engineering assessment has included the preparation of topographic maps, the performance of core drillings and radiometric measurements sufficient to determine areas and volumes of tailings and radiation exposures of individuals and nearby populations, the investigations of site hydrology and meteorology, and the evaluation and costing of alternative corrective actions. Radon gas released from the 1.9 million tons of tailings at the Grand Junction site constitutes the most significant environmental impact, although windblown tailings and external gamma radiation are also factors. The eight alternative actions presented herein range from millsite and off-site decontamination with the addition of 3 m of stabilization cover material (Option I), to removal of the tailings to remote disposal sites and decontamination of the tailings site (Options II through VIII). Cost estimates for the eight options range from about $10,200,000 for stabilization in-place to about $39,500,000 for disposal in the DeBeque area, at a distance of about 35 mi, using transportation by rail. If transportation to DeBeque were by truck, the cost estimated to be about $41,900,000. Three principal alternatives for the reprocessing of the Grand Junction tailings were examined: (a) heap leaching; (b) treatment at an existing mill; and (c) reprocessing at a new conventional mill constructed for tailings reprocessing. The cost of the uranium recovered would be about $200/lb by heap leach and $150/lb by conventional plant processes. The spot market price for uranium was $25/lb early in 1981. Therefore, reprocessing the tailings for uranium recovery appears not to be economically attractive.

  15. High SO{sub 2} removal efficiency testing. Quarterly status report, April-June 1995

    SciTech Connect (OSTI)

    Blythe, G.

    1995-07-14

    This project involves testing at six full-scale utility flue gas desulfurization (FGD) systems to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO{sub 2} removal efficiency. The upgrades being evaluated mostly involve using performance additives in the FGD systems. The {open_quotes}base{close_quotes} project involved testing at the Tampa Electric Company Big Bend station. All five potential options to the base program have been exercised by DOE, involving testing at Hoosier Energy`s Merom Station (Option I), Southwestern Electric Power Company`s Pirkey Station (Option II), PSI Energy`s Gibson Station (Option III), Duquesne Light`s Elrama Station (Option IV), and New York State Electric and Gas Corporation`s Kintigh Station (Option V). The originally planned testing has been completed for all six sites. The remainder of this document is divided into four sections. Section 2, Project Summary, provides a brief overview of the status of technical efforts on this project. Section 3, Results, summarizes the outcome from technical efforts during the quarter, or results from prior quarters that have not been previously reported. In Section 4, Plans for the Next Reporting Period, an overview is provided of the technical efforts that are anticipated for the third quarter of calendar year 1995. Section 5 contains a brief acknowledgment.

  16. High SO(2) removal efficiency testing. Technical progress report, March - May 1996

    SciTech Connect (OSTI)

    Murphy, J. [USDOE Pittsburgh Energy Technology Center, PA (United States); Blythe, G. [Radian Corp., Austin, TX (United States)

    1996-12-31

    This project involves testing at six full-scale utility flue gas desulfurization (FGD) systems, to evaluate low capital cost upgrades may allow these systems to achieve up to 98% SO{sub 2} removal efficiency. The upgrades being evaluated mostly involve using performance additives in the FGD systems. The ``base`` project involved testing at the Tampa Electric Company`s Big Bend Station. All five potential options to the base program have been exercised by DOE, involving testing at Hoosier Energy`s Merom Station (Option I), Southwestern Electric Power Company`s Pirkey Station (Option II), PSI Energy`s Gibson Station (Option III), Duquesne Light`s Elrama Station (Option IV), and New York State Electric and Gas Corporation`s Kintigh Station (Option V). The originally planned testing has been completed for all six sites. The remainder of this document is divided into four sections. Section 2, project summary, provides a brief overview of the status of technical efforts on this project. Section 3, results, summarizes the outcome from technical efforts during the quarter or results from prior quarters that have not been previously reported. In Section 4, plans for the next reporting period, an overview is provided of the technical efforts anticipated for the first quarter of calendar year 1996. Section 5 contains a brief acknowledgment.

  17. High SO{sub 2} removal efficiency testing. Technical progress report, October--December 1995

    SciTech Connect (OSTI)

    Blythe, G.

    1995-10-18

    This project involves testing at six full-scale utility flue gas desulfurization (FGD) systems, to evaluate low capital cost upgrades that may allow these systems to achieve up to 98% SO{sub 2} removal efficiency. The upgrades being evaluated mostly involve using performance additives in the FGD systems. The ``base`` project involved testing at the Tampa Electric Company Big Bend station. All five potential options to the base program have been exercised by DOE, involving testing at Hoosier Energy`s Merom Station (Option I), Southwestern Electric Power Company`s Pirkey Station (Option II), PSI Energy`s Gibson Station (Option III), Duquesne Light`s Elrama Station (Option IV), and New York State Electric and Gas Corporation`s Kintigh Station (Option V). The originally planned testing has been completed for all six sites. Following the introduction, this report is divided into four sections. Section 2, Project Summary, provides a brief overview of the status of technical efforts on this project. Section 3, Results, summarizes the outcome from technical efforts during the quarter, or results from prior quarter that have not been previously reported. In Section 4, Plans for the Next Reporting Period, an overview is provided of the technical efforts anticipated for the first quarter of calendar year 1996. Section 5 contains a brief acknowledgment.

  18. Apparatus and method for removing particulate deposits from high temperature filters

    DOE Patents [OSTI]

    Nakaishi, Curtis V. (Morgantown, WV); Holcombe, Norman T. (McMurray, PA); Micheli, Paul L. (Morgantown, WV)

    1992-01-01

    A combustion of a fuel-air mixture is used to provide a high-temperature and high-pressure pulse of gaseous combustion products for the back-flush cleaning of ceramic filter elements contained in a barrier filter system and utilized to separate particulates from particulate-laden process gases at high temperature and high pressure. The volume of gaseous combustion products provided by the combustion of the fuel-air mixture is preferably divided into a plurality of streams each passing through a sonic orifice and conveyed to the open end of each filter element as a high pressure pulse which passes through the filter elements and dislodges dust cake supported on a surface of the filter element.

  19. High-Performance, Superparamagnetic, Nanoparticle-Based Heavy Metal Sorbents for Removal of Contaminants from Natural Waters

    SciTech Connect (OSTI)

    Warner, Cynthia L.; Addleman, Shane; Cinson, Anthony D.; Droubay, Timothy C.; Engelhard, Mark H.; Nash, Michael A.; Yantasee, Wassana; Warner, Marvin G.

    2010-06-01

    We describe the synthesis and characterization of superparamagnetic iron oxide nanoparticle based heavy metal sorbents with various surface chemistries that demonstrate an excellent affinity for the separation of heavy metals in contaminated water systems (i.e. spiked Columbia river water). The magnetic nanoparticle sorbents are prepared from an easy to synthesize iron oxide precursor, followed by a simple, one-step ligand exchange technique to introduce the organic surface functionality of interest chosen to target either specific or broader classes of heavy metals. Functionalized superparamagnetic nanoparticles are excellent sorbent materials for the extraction of heavy metal contaminants from environmental and clinical samples since they are easily removed from the media once bound to the contaminant by simply applying a magnetic field. These engineered magnetic nanoparticle sorbents have an inherently high active surface area (often > 100 m2/g), allowing for increased binding capacity. To demonstrate the potential sorbent performance of each of the surface modified magnetic nanoparticles, river water was spiked with Hg, Pb, Cd, Ag, Co, Cu, and Tl and exposed to low concentrations of the functionalized nanoparticles. The samples were analyzed to determine the metal content before and after exposure to the magnetic nanoparticle sorbents. In almost all cases reported here the nanoparticles were found to be superior to commercially available sorbents binding a wide range of different heavy metals with extremely high affinity. Detailed characterization of the functionalized magnetic nanoparticle sorbents including FT-IR, BET surface analysis, TGA, XPS and VSM as well as the heavy metal removal experiments are presented.

  20. High SO{sub 2} removal efficiency testing. Technical progress report, [October 1--December 31, 1992

    SciTech Connect (OSTI)

    Blythe, G.

    1993-01-20

    Baseline testing at the ``base`` site. Tampa Electric Company`s (TECo`s) Big Bend Station, commenced on September 28 and was completed on October 2. Initial results from this testing were presented in the previous Technical Progress Report, but a more complete discussion is provided in this report. Parametric testing was conducted at the Big Bend site during this quarter to evaluate the effects of dibasic acid (DBA) addition on system SO{sub 2} removal performance. The parametric tests were conducted from November 2 through 19. A DBA consumption rate test was also conducted, after the parametric tests were completed. The DBA consumption test was conducted from November 21 through 25. Options I and II to the base program were exercised by DOE/PETC at the end of the previous quarter. These options involve testing at Hoosier Energy Rural Electric Cooperative Inc.`s Merom Station and Southwestern Electric Power Company`s Pirkey Station, respectively. Testing was conducted at Merom Station during November. Previously, Radian Corporation was the test contractor for EPRI-funded performance additive testing at this site. This EPRI-funded testing involved the equivalent of baseline testing, parametric testing with both DBA and sodium formate performance additives, and an additive consumption test with the DBA additive. The results of the prior testing will be available to support the objectives of this DOE project Consequently, the only testing required at the Merom site was to conduct consumption tests with the sodium formate additive. After a brief baseline repeat test, two sodium formate consumption tests were conducted during the time period from November 11 through 23. Results from the consumption tests are presented and discussed in this report.

  1. Environmental Patterns Associated with Active and Inactive Caribbean Hurricane Seasons

    E-Print Network [OSTI]

    Environmental Patterns Associated with Active and Inactive Caribbean Hurricane Seasons MARK R. JURY of hurricanes passing through the Caribbean in the 1950­2005 period reveals that seasons with more intense hurricanes occur with the onset of Pacific La Nin~a events and when Atlantic SSTs west of Africa are above

  2. High-Risk Components Removed from K-25's Tc-99 Area | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancingR Walls - Building America Top Innovation High-R Walls

  3. Radiological survey of the inactive uranium-mill tailings at Naturita, Colorado

    SciTech Connect (OSTI)

    Haywood, F.F.; Jacobs, D.J.; Hubbard, H.M. Jr.; Ellis, B.S.; Shinpaugh, W.H.

    1980-03-01

    Results of a radiological survey of the inactive uranium-mill site a Naturita, Colorado, conducted in May 1976, are presented. The spread of tailings was detected in the area surrounding the site by means of direct above ground gamma measurements and analysis of surface and subsurface soil samples. Radiochemical analyses of water samples in the vicinity of the tailings pile indicate local surface water contamination immediately downstream from the pile, although the /sup 226/Ra concentration in the water at that point as well below the concentration guide for drinking water. The calculated subsoil distribution of /sup 226/Ra in onsite holes is presented graphically. The tailings at this site were removed and reprocessed at another location. This operation was completed and reclamation of the site was conducted in 1978. Consequently the information in this report documents radiological conditions that no longer exist.

  4. Institute for High Heat Flux Removal (IHHFR). Phases I, II, and III

    SciTech Connect (OSTI)

    Boyd, Ronald D.

    2014-08-31

    The IHHFR focused on interdisciplinary applications as it relates to high heat flux engineering issues and problems which arise due to engineering systems being miniaturized, optimized, or requiring increased high heat flux performance. The work in the IHHFR focused on water as a coolant and includes: (1) the development, design, and construction of the high heat flux flow loop and facility; (2) test section development, design, and fabrication; and, (3) single-side heat flux experiments to produce 2-D boiling curves and 3-D conjugate heat transfer measurements for single-side heated test sections. This work provides data for comparisons with previously developed and new single-side heated correlations and approaches that address the single-side heated effect on heat transfer. In addition, this work includes the addition of single-side heated circular TS and a monoblock test section with a helical wire insert. Finally, the present work includes: (1) data base expansion for the monoblock with a helical wire insert (only for the latter geometry), (2) prediction and verification using finite element, (3) monoblock model and methodology development analyses, and (4) an alternate model development for a hypervapotron and related conjugate heat transfer controlling parameters.

  5. material removal

    National Nuclear Security Administration (NNSA)

    %2A en Nuclear Material Removal http:www.nnsa.energy.govaboutusourprogramsdnnm3remove

    Pag...

  6. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Chou, M.I.M; Lytle, J.M.; Ruch, R.R.; Kruse, C.W.; Chaven, C.; Hackley, K.C.; Hughes, R.E.; Harvey, R.D.; Frost, J.K. [Illinois State Geological Survey, Champaign, IL (United States); Buchanan, D.H. [Eastern Illinois Univ., Charleston, IL (United States); Stucki, J.W. [Illinois Univ., Urbana, IL (United States); Huffman, G.; Huggins, F.E. [Kentucky Univ., Lexington, KY (United States)

    1992-09-01

    A pre-combustion coal desulfurization process at 120{degree}C using perchloroethylene (PCE) to remove up to 70% of the organic sulfur has been developed by the Midwest Ore Processing Co. (MWOPC). However, this process has not yet proven to be as successful with Illinois coals as it has for Ohio and Indiana coals. In addition, the high levels of organic sulfur removals observed by the MWOPC may be due to certain errors involved in the ASTM data interpretation; this needs verification. For example, elemental sulfur extracted by the PCE may be derived from pyrite oxidation during coal preoxidation, but it may be interpreted as organic sulfur removed by the PCE using ASTM analysis. The purposes of this research are to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process reported by the MWOPC and to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation.

  7. Waste management plan for inactive LLLW tanks 3001-B, 3004-B, 3013, and T-30 at Oak Ridge National Laboratory, Oak Ridge, Tennessee. Environmental Restoration Program

    SciTech Connect (OSTI)

    1995-07-01

    This Project Waste Management Plan identifies the waste that is expected to be generated in connection with the removal and disposition of inactive liquid low-level radioactive waste tanks 3001-B, 3004-B, and T-30, and grouting of tank 3013 at the Oak Ridge National Laboratory and the isolation of these tanks` associated piping systems. The plan also identifies the organization, responsibilities, and administrative controls that will be followed to ensure proper handling of the waste.

  8. Manganese and Ceria Sorbents for High Temperature Sulfur Removal from Biomass-Derived Syngas -- The Impact of Steam on Capacity and Sorption Mode

    SciTech Connect (OSTI)

    Cheah, S.; Parent, Y. O.; Jablonski, W. S.; Vinzant, T.; Olstad, J. L.

    2012-07-01

    Syngas derived from biomass and coal gasification for fuel synthesis or electricity generation contains sulfur species that are detrimental to downstream catalysts or turbine operation. Sulfur removal in high temperature, high steam conditions has been known to be challenging, but experimental reports on methods to tackle the problem are not often reported. We have developed sorbents that can remove hydrogen sulfide from syngas at high temperature (700 C), both in dry and high steam conditions. The syngas composition chosen for our experiments is derived from statistical analysis of the gasification products of wood under a large variety of conditions. The two sorbents, Cu-ceria and manganese-based, were tested in a variety of conditions. In syngas containing steam, the capacity of the sorbents is much lower, and the impact of the sorbent in lowering H{sub 2}S levels is only evident in low space velocities. Spectroscopic characterization and thermodynamic consideration of the experimental results suggest that in syngas containing 45% steam, the removal of H{sub 2}S is primarily via surface chemisorptions. For the Cu-ceria sorbent, analysis of the amount of H{sub 2}S retained by the sorbent in dry syngas suggests both copper and ceria play a role in H{sub 2}S removal. For the manganese-based sorbent, in dry conditions, there is a solid state transformation of the sorbent, primarily into the sulfide form.

  9. High-Level Waste Mechanical Sludge Removal at the Savannah River Site - F Tank Farm Closure Project

    SciTech Connect (OSTI)

    Jolly, R.C.Jr. [Washington Savannah River Company (United States); Martin, B. [Washington Savannah River Company, A Washington Group International Company (United States)

    2008-07-01

    The Savannah River Site F-Tank Farm Closure project has successfully performed Mechanical Sludge Removal (MSR) using the Waste on Wheels (WOW) system for the first time within one of its storage tanks. The WOW system is designed to be relatively mobile with the ability for many components to be redeployed to multiple waste tanks. It is primarily comprised of Submersible Mixer Pumps (SMPs), Submersible Transfer Pumps (STPs), and a mobile control room with a control panel and variable speed drives. In addition, the project is currently preparing another waste tank for MSR utilizing lessons learned from this previous operational activity. These tanks, designated as Tank 6 and Tank 5 respectively, are Type I waste tanks located in F-Tank Farm (FTF) with a capacity of 2,840 cubic meters (750,000 gallons) each. The construction of these tanks was completed in 1953, and they were placed into waste storage service in 1959. The tank's primary shell is 23 meters (75 feet) in diameter, and 7.5 meters (24.5 feet) in height. Type I tanks have 34 vertically oriented cooling coils and two horizontal cooling coil circuits along the tank floor. Both Tank 5 and Tank 6 received and stored F-PUREX waste during their operating service time before sludge removal was performed. DOE intends to remove from service and operationally close (fill with grout) Tank 5 and Tank 6 and other HLW tanks that do not meet current containment standards. Mechanical Sludge Removal, the first step in the tank closure process, will be followed by chemical cleaning. After obtaining regulatory approval, the tanks will be isolated and filled with grout for long-term stabilization. Mechanical Sludge Removal operations within Tank 6 removed approximately 75% of the original 95,000 liters (25,000 gallons). This sludge material was transferred in batches to an interim storage tank to prepare for vitrification. This operation consisted of eleven (11) Submersible Mixer Pump(s) mixing campaigns and multiple intra-area transfers utilizing STPs from July 2006 to August 2007. This operation and successful removal of sludge material meets requirement of approximately 19,000 to 28,000 liters (5,000 to 7,500 gallons) remaining prior to the Chemical Cleaning process. Removal of the last 35% of sludge was exponentially more difficult, as less and less sludge was available to mobilize and the lighter sludge particles were likely removed during the early mixing campaigns. The removal of the 72,000 liters (19,000 gallons) of sludge was challenging due to a number factors. One primary factor was the complex internal cooling coil array within Tank 6 that obstructed mixer discharge jets and impacted the Effective Cleaning Radius (ECR) of the Submersible Mixer Pumps. Minimal access locations into the tank through tank openings (risers) presented a challenge because the available options for equipment locations were very limited. Mechanical Sludge Removal activities using SMPs caused the sludge to migrate to areas of the tank that were outside of the SMP ECR. Various SMP operational strategies were used to address the challenge of moving sludge from remote areas of the tank to the transfer pump. This paper describes in detail the Mechanical Sludge Removal activities and mitigative solutions to cooling coil obstructions and other challenges. The performance of the WOW system and SMP operational strategies were evaluated and the resulting lessons learned are described for application to future Mechanical Sludge Removal operations. (authors)

  10. Calculating a checksum with inactive networking components in a computing system

    DOE Patents [OSTI]

    Aho, Michael E; Chen, Dong; Eisley, Noel A; Gooding, Thomas M; Heidelberger, Philip; Tauferner, Andrew T

    2014-12-16

    Calculating a checksum utilizing inactive networking components in a computing system, including: identifying, by a checksum distribution manager, an inactive networking component, wherein the inactive networking component includes a checksum calculation engine for computing a checksum; sending, to the inactive networking component by the checksum distribution manager, metadata describing a block of data to be transmitted by an active networking component; calculating, by the inactive networking component, a checksum for the block of data; transmitting, to the checksum distribution manager from the inactive networking component, the checksum for the block of data; and sending, by the active networking component, a data communications message that includes the block of data and the checksum for the block of data.

  11. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal

    SciTech Connect (OSTI)

    Nick Degenstein; Minish Shah; Doughlas Louie

    2012-05-01

    The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

  12. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. Technical report, September 1, 1991--November 30, 1991

    SciTech Connect (OSTI)

    Chou, M.I.M.

    1991-12-31

    A pre-combustion coal desulfurization process at 120{degree}C using perchloroethylene (PCE) to remove up to 70% of the organic sulfur has been developed by the Midwest Ore Processing Co. (MWOPC). However, this process has not yet proven to be as successful with Illinois coals as it has for Ohio and Indiana coals. The organic sulfur removal has been achieved only with highly oxidized Illinois coals containing high sulfatic sulfur. A logical explanation for this observation is vital to successful process optimization for the use of Illinois coals. In addition, the high levels of organic sulfur removals observed by the MWOPC may be due to certain errors involved in the ASTM data interpretation; this needs verification. For example, elemental sulfur extracted by the PCE may be derived from pyrite oxidation during coal pre-oxidation, but it may be interpreted as organic sulfur removed by the PCE using ASTM analysis. The goals of this research are: (1) to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process reported by the MWOPC, (2) to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation, and (3) to determine the suitability of Illinois coals for use in the PCE desulfurization process. This project involves the Illinois State Geological Survey (ISGS), Eastern Illinois University (EIU), the University of Illinois-Urbana/Champaign (UI-UC), and the University of Kentucky, Lexington (UK). This is the first year of a two-year project.

  13. Radiological survey of the inactive uranium-mill tailings at Durango, Colorado

    SciTech Connect (OSTI)

    Haywood, F.F.; Perdue, P.T.; Shinpaugh, W.H.; Ellis, B.S.; Chou, K.D.

    1980-03-01

    Results of a radiological survey of the inactive uranium-mill site at Durango, Colorado, conducted in April 1976, in cooperation with a team from Ford, Bacon and Davis Utah Inc., are presented together with descriptions of the instruments and techniques used to obtain the data. Direct above-ground gamma measurements and analysis of surface soil and sediment samples indicate movement of tailings from the piles toward Lightner Creek on the north and the Animas River on the east side of the piles. The concentration of /sup 226/Ra in the former raffinate pond area is only slightly above the background level. Two structures in Durango were found to contain high concentrations of airborne radon daughters, where tailings are known to have been utilized in construction. Near-background concentrations of radon daughters were found in a well-ventilated building close to the tailings.

  14. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. Final technical report, September 1, 1991--August 31, 1992

    SciTech Connect (OSTI)

    Chou, M.I.M.; Lytle, J.M. [Illinois State Geological Survey, Champaign, IL (United States); Buchanan, D.H. [Eastern Illinois Univ., Charleston, IL (United States)] [and others

    1992-12-31

    The purposes of this Testing and Materials (ASTM) forms of sulfur analysis. The purposes of this research are to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE desulfurization process and to verify the forms-of-sulfur determination using the ASTM method for the PCE process evaluation. Problem that limits commercial application of the PCE process is the high chlorine content in the PCE-treated coals. Hence, to develop a dechlorination procedure to remove excess PCE from the PCE-treated coal is an additional goal of this investigation. MWOPC`s results have been repeated on fresh IBC-104 coal. Oxidation of coals was found to affect subsequent PCE desulfurization. Elemental sulfur is more amenable to removal by PCE. Ohio 5/6 coal appears to produce elemental sulfur more readily than Illinois coal during oxidation. Data from X-Ray Diffraction spectroscopy indicate that sulfate in the oxidized Illinois IBC-104 coal is mainly in gypsum form, whereas, sulfate in oxidized Ohio 5/6 sample is mainly in szomolnokite form. These data suggest that the oxidation reaction for Ohio 5/6 coal might occur under catalytic conditions which readily convert pyrite to produce FeSO{sub 4} and elemental sulfur. The higher elemental sulfur content in that coal results in higher ASTM organic sulfur removal by PCE extraction. From mass balance calculation, 96% of the total sulfur and greater than 95% of total iron were accounted for during our PCE tests with both long-term ambient-oxidized IBC-104 coal and ambient-oxidized Ohio 516 coal.

  15. ROBUSTNESS OF THE CSSX PROCESS TO FEED VARIATION: EFFICIENT CESIUM REMOVAL FROM THE HIGH POTASSIUM WASTES AT HANFORD

    SciTech Connect (OSTI)

    Delmau, Laetitia Helene; Birdwell Jr, Joseph F; McFarlane, Joanna; Moyer, Bruce A

    2010-01-01

    This contribution finds the Caustic-Side Solvent Extraction (CSSX) process to be effective for the removal of cesium from the Hanford tank-waste supernatant solutions. The Hanford waste types are more challenging than those at the Savannah River Site (SRS) in that they contain significantly higher levels of potassium, the chief competing ion in the extraction of cesium. By use of a computerized CSSX thermodynamic model, it was calculated that the higher levels of potassium depress the cesium distribution ratio (D{sub Cs}), as validated to within {+-}11% by the measurement of D{sub Cs} values on various Hanford waste-simulant compositions. A simple analog model equation that can be readily applied in a spreadsheet for estimating the D{sub Cs} values for the varying waste compositions was developed and shown to yield nearly identical estimates as the computerized CSSX model. It is concluded from the batch distribution experiments, the physical-property measurements, the equilibrium modeling, the flowsheet calculations, and the contactor sizing that the CSSX process as currently formulated for cesium removal from alkaline salt waste at the SRS is capable of treating similar Hanford tank feeds, albeit with more stages. For the most challenging Hanford waste composition tested, 31 stages would be required to provide a cesium decontamination factor (DF) of 5000 and a concentration factor (CF) of 2. Commercial contacting equipment with rotor diameters of 10 in. for extraction and 5 in. for stripping should have the capacity to meet throughput requirements, but testing will be required to confirm that the needed efficiency and hydraulic performance are actually obtainable. Markedly improved flowsheet performance was calculated based on experimental distribution ratios determined for an improved solvent formulation employing the more soluble cesium extractant BEHBCalixC6 used with alternative scrub and strip solutions, respectively 0.1 M NaOH and 0.010 M boric acid. The improved solvent and flowsheet can meet minimum requirements (DF = 5000 and CF = 2) with 15 stages or more ambitious goals (DF = 40,000 and CF = 15) with 19 stages. Thus, a modular CSSX application for the Hanford waste seems readily obtainable with further short-term development.

  16. Method of preparation of a CO.sub.2 removal sorbent with high chemical stability during multiple cycles

    SciTech Connect (OSTI)

    Siriwardane, Ranjani V.; Rosencwaig, Shira

    2015-07-14

    Method for the production of a clay-alkali-amine CO.sub.2 sorbent prepared by integrating a clay substrate, basic alkali salt, and amine liquid. The basic alkali salt is present relative to the clay substrate in a weight ratio of from about 1 part to about 50 parts per 100 parts of the clay substrate. The amine liquid is present relative to a clay-alkali combination in a weight ratio of from about 1 part to about 10 parts per 10 parts of the clay-alkali combination. The clay substrate and basic alkali salt may be combined in a solid-solid heterogeneous mixture and followed by introduction of the amine liquid. Alternatively, an alkaline solution may be blended with the amine solution prior to contacting the clay substrate. The clay-alkali-amine CO.sub.2 sorbent is particularly advantageous for low temperature CO.sub.2 removal cycles in a gas stream having a CO.sub.2 concentration less than around 2000 ppm and an oxygen concentration around 21%, such as air. Results are presented illustrating the performance of the clay-alkali-amine CO.sub.2 sorbent compared to a clay-amine sorbent lacking the alkali inclusion.

  17. Summary of the engineering assessment of inactive uranium mill tailings

    SciTech Connect (OSTI)

    none,

    1981-07-01

    The Grand Junction site has been reevaluated in order to revise the october 1977 engineering assessment of the problems resulting from the existence of radioactive uranium mill tailings at Grand Junction, Colorado. This engineering assessment has included the preparation of topographic maps, the performance of core drillings and radiometric measurements sufficient to determine areas and volumes of tailings and radiation exposures of individuals and nearby populations, the investigations of site hydrology and meteorology, and the evaluation and costing of alternative corrective actions. Radon gas released from the 1.9 million tons of tailings at the Grand Junction site constitutes the most significant environmental impact, although windblown tailings and external gamma radiation are also factors. The eight alternative actions presented herein range from millsite and off-site decontamination with the addition of 3 m of stabilization cover material (Option I), to removal of the tailings to remote disposal sites and decontamination of the tailings site (Option II through VIII). Cost estimates for the eight options range from about $10,200,000 for stabilization in-place to about $39,500,000 for disposal in the DeBeque area, at a distance of about 35 mi, using transportation by rail. If transportation to DeBeque were by truck, the cost is estimated to be about $41,900,000. Three prinicpal alternatives for the reprocessing of the Grand Junction tailings were examined: (a) heap leaching; (b) treatment at an existing mill; and (c) reprocessing at a new conventional mill constructed for tailings reprocessing. The cost of the uranium recovered would be about $200/lb by heap leach and $150/lb by conventional plant processes. The spot market price for uranium was $25/lb early in 1981. Therefore, reprocessing the tailings for uranium recovery appears not to be economically attractive.

  18. A solution to the subdiffusion-efficiency paradox: Inactive states enhance reaction efficiency at subdiffusion conditions in living cells

    E-Print Network [OSTI]

    Leila Esmaeili Sereshki; Michael A. Lomholt; Ralf Metzler

    2012-03-08

    Macromolecular crowding in living biological cells effects subdiffusion of larger biomolecules such as proteins and enzymes. Mimicking this subdiffusion in terms of random walks on a critical percolation cluster, we here present a case study of EcoRV restriction enzymes involved in vital cellular defence. We show that due to its so far elusive propensity to an inactive state the enzyme avoids non-specific binding and remains well-distributed in the bulk cytoplasm of the cell. Despite the reduced volume exploration capability of subdiffusion processes, this mechanism guarantees a high efficiency of the enzyme. By variation of the non-specific binding constant and the bond occupation probability on the percolation network, we demonstrate that reduced non-specific binding are beneficial for efficient subdiffusive enzyme activity even in relatively small bacteria cells. Our results corroborate a more local picture of cellular regulation.

  19. Conceptual Design of a Simplified Skid-Mounted Caustic-Side Solvent Extraction Process for Removal of Cesium from Savannah Rive Site High-Level Waste

    SciTech Connect (OSTI)

    Birdwell, JR.J.F.

    2004-05-12

    This report presents the results of a conceptual design of a solvent extraction process for the selective removal of {sup 137}Cs from high-level radioactive waste currently stored in underground tanks at the U.S. Department of Energy's Savannah River Site (SRS). This study establishes the need for and feasibility of deploying a simplified version of the Caustic-Side Solvent Extraction (CSSX) process; cost/benefit ratios ranging from 33 to 55 strongly support the considered deployment. Based on projected compositions, 18 million gallons of dissolved salt cake waste has been identified as having {sup 137}Cs concentrations that are substantially lower than the worst-case design basis for the CSSX system that is to be deployed as part of the Salt Waste Processing Facility (SWPF) but that does not meet the waste acceptance criteria for immobilization as grout in the Saltstone Manufacturing and Disposal Facility at SRS. Absent deployment of an alternative cesium removal process, this material will require treatment in the SWPF CSSX system, even though the cesium decontamination factor required is far less than that provided by that system. A conceptual design of a CSSX processing system designed for rapid deployment and having reduced cesium decontamination factor capability has been performed. The proposed accelerated-deployment CSSX system (CSSX-A) has been designed to have a processing rate of 3 million gallons per year, assuming 90% availability. At a more conservative availability of 75% (reflecting the novelty of the process), the annual processing capacity is 2.5 million gallons. The primary component of the process is a 20-stage cascade of centrifugal solvent extraction contactors. The decontamination and concentration factors are 40 and 15, respectively. The solvent, scrub, strip, and wash solutions are to have the same compositions as those planned for the SWPF CSSX system. As in the SWPF CSSX system, the solvent and scrub flow rates are equal. The system is designed to facilitate remote operation and direct maintenance. Two general deployment concepts were considered: (1) deployment in an existing but unused SRS facility and (2) deployment in transportable containers. Deployment in three transportable containers was selected as the preferred option, based on concerns regarding facility availability (due to competition from other processing alternatives) and decontamination and renovation costs. A risk assessment identified environmental, safety, and health issues that exist. These concerns have been addressed in the conceptual design by inclusion of mitigating system features. Due to the highly developed state of CSSX technology, only a few technical issues remain unresolved; however, none of these issues have the potential to make the technology unviable. Recommended development tasks that need to be performed to address technical uncertainties are discussed in this report. Deployment of the proposed CSSX-A system provides significant qualitative and quantitative benefits. The qualitative benefits include (1) verification of full-scale contactor performance under CSSX conditions that will support SWPF CSSX design and deployment; (2) development of design, fabrication, and installation experience bases that will be at least partially applicable to the SWPF CSSX system; and (3) availability of the CSSX-A system as a means of providing contactor-based solvent extraction system operating experience to SWPF CSSX operating personnel. Estimates of fixed capital investment, development costs, and annual operating cost for SRS deployment of the CSSX-A system (in mid-2003 dollars) are $9,165,199, $2,734,801, and $2,108,820, respectively. When the economics of the CSSX-A system are compared with those of the baseline SWPF CSSX system, benefit-to-cost ratios ranging from 20 to 47 are obtained. The benefits in the cost/benefit comparison arise from expedited tank closure and reduced engineering, construction, and operating costs for the SWPF CSSX system. No significant impediments to deployment were determined in the reported a

  20. Development of the Next-Generation Caustic-Side Solvent Extraction (NG-CSSX) Process for Cesium Removal from High-Level Tank Waste

    SciTech Connect (OSTI)

    Moyer, Bruce A; Bonnesen, Peter V; Delmau, Laetitia Helene; Sloop Jr, Frederick {Fred} V; Williams, Neil J; Birdwell Jr, Joseph F; Lee, Denise L; Leonard, Ralph; Fink, Samuel D; Peters, Thomas B.; Geeting, Mark W

    2011-01-01

    This paper describes the chemical performance of the Next-Generation Caustic-Side Solvent Extraction (NG-CSSX) process in its current state of development for removal of cesium from the alkaline high-level tank wastes at the Savannah River Site (SRS) in the US Department of Energy (USDOE) complex. Overall, motivation for seeking a major enhancement in performance for the currently deployed CSSX process stems from needs for accelerating the cleanup schedule and reducing the cost of salt-waste disposition. The primary target of the NG-CSSX development campaign in the past year has been to formulate a solvent system and to design a corresponding flowsheet that boosts the performance of the SRS Modular CSSX Unit (MCU) from a current minimum decontamination factor of 12 to 40,000. The chemical approach entails use of a more soluble calixarene-crown ether, called MaxCalix, allowing the attainment of much higher cesium distribution ratios (DCs) on extraction. Concurrently decreasing the Cs-7SB modifier concentration is anticipated to promote better hydraulics. A new stripping chemistry has been devised using a vitrification-friendly aqueous boric acid strip solution and a guanidine suppressor in the solvent, resulting in sharply decreased DCs on stripping. Results are reported herein on solvent phase behavior and batch Cs distribution for waste simulants and real waste together with a preliminary flowsheet applicable for implementation in the MCU. The new solvent will enable MCU to process a much wider range of salt feeds and thereby extend its service lifetime beyond its design life of three years. Other potential benefits of NG-CSSX include increased throughput of the SRS Salt Waste Processing Facility (SWPF), currently under construction, and an alternative modular near-tank application at Hanford.

  1. Revegetation and rock cover for stabilization of inactive uranium mill tailings disposal sites. Final report

    SciTech Connect (OSTI)

    Beedlow, P.A.

    1984-05-01

    Guidelines for using vegetation and rock to protect inactive uranium mill tailings from erosion were developed by Pacific Northwest Laboratory as part of the Department of Energy's Uranium Mill Tailings Remedial Action Project (UMTRAP) Technology Development program. Information on soils, climate, and vegetation were collected for 20 inactive tailings sites in the western United States. Sites were grouped according to similarities in climate and vegetation. Soil loss for those sites was characterized using the Universal Soil Loss Equation. Test plots were used to evaluate (1) the interaction between vegetation and sealant barrier systems and (2) the effects of surface rock on soil water and vegetation. Lysimeter and simulation studies were used to direct and support field experiments. 49 references, 17 figures, 16 tables.

  2. Inactive end cell assembly for fuel cells for improved electrolyte management and electrical contact

    DOE Patents [OSTI]

    Yuh, Chao-Yi (New Milford, CT); Farooque, Mohammad (Danbury, CT); Johnsen, Richard (New Fairfield, CT)

    2007-04-10

    An assembly for storing electrolyte in a carbonate fuel cell is provided. The combination of a soft, compliant and resilient cathode current collector and an inactive anode part including a foam anode in each assembly mitigates electrical contact loss during operation of the fuel cell stack. In addition, an electrode reservoir in the positive end assembly and an electrode sink in the negative end assembly are provided, by which ribbed and flat cathode members inhibit electrolyte migration in the fuel cell stack.

  3. Sulfur removal from high-sulfur Illinois coal by low-temperature perchloroethylene (PCE) extraction. [Quarterly] technical report, March 1, 1993--May 31, 1993

    SciTech Connect (OSTI)

    Chou, M.I.M. [Illinois State Geological Survey, Champaign, IL (United States); Buchanan, D.H. [Eastern Illinois Univ., Charleston, IL (United States); Stucki, J.W. [Illinois Univ., Urbana, IL (United States)

    1993-09-01

    The purposes of this project are: to independently confirm and possibly to improve the organic sulfur removal from Illinois coals with the PCE process developed by the Midwest Ore Processing Co. (MWOPC), to verify the forms-of-sulfur determination using the ASTM method for evaluation of the PCE process, and to develop a dechlorination procedure to remove excess PCE from the PCE-treated coal. The objectives for the second year are: to verify the possible effects of PCE treatment on coal-derived FeS{sub 2}, FeSO{sub 4}, and Fe{sub 2}(SO{sub 4}){sub 3} on ASTM coal analysis, to investigate the behavior of sulfur during oxidation and PCE desulfurization using the isotopically signatured coal sample, to investigate the effects of conditions and/or reagents on the oxidation of the organic-sulfur-model compounds, to evaluate the extended oxidation condition on the organic sulfur removal by PCE desulfurization, and to study other innovative pretreatment processes for the removal of organic sulfur from coal under mild conditions.

  4. Graphitic packing removal tool

    DOE Patents [OSTI]

    Meyers, Kurt Edward (Avella, PA); Kolsun, George J. (Pittsburgh, PA)

    1997-01-01

    Graphitic packing removal tools for removal of the seal rings in one piece. he packing removal tool has a cylindrical base ring the same size as the packing ring with a surface finish, perforations, knurling or threads for adhesion to the seal ring. Elongated leg shanks are mounted axially along the circumferential center. A slit or slits permit insertion around shafts. A removal tool follower stabilizes the upper portion of the legs to allow a spanner wrench to be used for insertion and removal.

  5. Graphitic packing removal tool

    DOE Patents [OSTI]

    Meyers, K.E.; Kolsun, G.J.

    1997-11-11

    Graphitic packing removal tools for removal of the seal rings in one piece are disclosed. The packing removal tool has a cylindrical base ring the same size as the packing ring with a surface finish, perforations, knurling or threads for adhesion to the seal ring. Elongated leg shanks are mounted axially along the circumferential center. A slit or slits permit insertion around shafts. A removal tool follower stabilizes the upper portion of the legs to allow a spanner wrench to be used for insertion and removal. 5 figs.

  6. Continuous sulfur removal process

    DOE Patents [OSTI]

    Jalan, deceased, Vinod (late of Concord, MA); Ryu, Jae (Cambridge, MA)

    1994-01-01

    A continuous process for the removal of hydrogen sulfide from a gas stream using a membrane comprising a metal oxide deposited on a porous support is disclosed.

  7. Reactor for removing ammonia

    DOE Patents [OSTI]

    Luo, Weifang (Livermore, CA); Stewart, Kenneth D. (Valley Springs, CA)

    2009-11-17

    Disclosed is a device for removing trace amounts of ammonia from a stream of gas, particularly hydrogen gas, prepared by a reformation apparatus. The apparatus is used to prevent PEM "poisoning" in a fuel cell receiving the incoming hydrogen stream.

  8. Continuous sulfur removal process

    DOE Patents [OSTI]

    Jalan, V.; Ryu, J.

    1994-04-26

    A continuous process for the removal of hydrogen sulfide from a gas stream using a membrane comprising a metal oxide deposited on a porous support is disclosed. 4 figures.

  9. Emission assessment at the Burj Hammoud inactive municipal landfill: Viability of landfill gas recovery under the clean development mechanism

    SciTech Connect (OSTI)

    El-Fadel, Mutasem; Abi-Esber, Layale; Salhab, Samer

    2012-11-15

    Highlights: Black-Right-Pointing-Pointer LFG emissions are measured at an abandoned landfill with highly organic waste. Black-Right-Pointing-Pointer Mean headspace and vent emissions are 0.240 and 0.074 l CH{sub 4}/m{sup 2} hr, respectively. Black-Right-Pointing-Pointer At sites with high food waste content, LFG generation drops rapidly after site closure. Black-Right-Pointing-Pointer The viability of LFG recovery for CDMs in developing countries is doubtful. - Abstract: This paper examines landfill gas (LFG) emissions at a large inactive waste disposal site to evaluate the viability of investment in LFG recovery through the clean development mechanism (CDM) initiative. For this purpose, field measurements of LFG emissions were conducted and the data were processed by geospatial interpolation to estimate an equivalent site emission rate which was used to calibrate and apply two LFG prediction models to forecast LFG emissions at the site. The mean CH{sub 4} flux values calculated through tessellation, inverse distance weighing and kriging were 0.188 {+-} 0.014, 0.224 {+-} 0.012 and 0.237 {+-} 0.008 l CH{sub 4}/m{sup 2} hr, respectively, compared to an arithmetic mean of 0.24 l/m{sup 2} hr. The flux values are within the reported range for closed landfills (0.06-0.89 l/m{sup 2} hr), and lower than the reported range for active landfills (0.42-2.46 l/m{sup 2} hr). Simulation results matched field measurements for low methane generation potential (L{sub 0}) values in the range of 19.8-102.6 m{sup 3}/ton of waste. LFG generation dropped rapidly to half its peak level only 4 yrs after landfill closure limiting the sustainability of LFG recovery systems in similar contexts and raising into doubt promoted CDM initiatives for similar waste.

  10. Cleanup of inactive Uranium Mill Tailings Sites in the Navajo Nation

    SciTech Connect (OSTI)

    Martin, B.

    1994-12-31

    The U.S. Congress passed the Uranium Mill Tailings Radiation Control Act (UMTRCA) in 1978 to address potential and significant radiation health hazards to the public from active and inactive mill operations. Title I to the UMTRCA identified sites to be designated for remedial action. These include four uranium mill tailings remedial action (UMTRA) sites in the Navajo Nation. These sites are located in Shiprock, New Mexico; Tuba City, Arizona; Cane Valley, Arizona; and Halchita, Utah. The U.S. Department of Energy (DOE) was directed to select and execute a plan of remedial action that provides long-term stabilization and control of radioactive materials and satisfies the U.S. Environmental Protection Agency standards and other applicable laws and regulations.

  11. Radiological survey of the inactive uranium-mill tailings at Rifle, Colorado

    SciTech Connect (OSTI)

    Haywood, F.F.; Jacobs, D.J.; Ellis, B.S.; Hubbard, H.M. Jr.; Shinpaugh, W.H.

    1980-06-01

    Results of radiological surveys of two inactive uranium-mill sites near Rifle, Colorado, in May 1976 are presented. These sites are referred to as Old Rifle and New Rifle. The calculated /sup 226/Ra inventory of the latter site is much higher than at the older mill location. Data on above-ground measurements of gamma exposure rates, surface and near-surface concentration of /sup 226/Ra in soil and sediment samples, concentration of /sup 226/Ra in water, calculated subsurface distribution of /sup 226/Ra, and particulate radionuclide concentrations in air samples are given. The data serve to define the extent of contamination in the vicinity of the mill sites and their immediate surrounding areas with tailings particles. Results of these measurements were utilized as technical input for an engineering assessment of these two sites.

  12. Revegetation/rock cover for stabilization of inactive uranium mill tailings disposal sites

    SciTech Connect (OSTI)

    Beedlow, P.A.; McShane, M.C.; Cadwell, L.L.

    1982-07-01

    Pacific Northwest Laboratory is developing design and performance guidelines for surface stabilization of inactive uranium mill tailings. In this work, vegetation and rock covers are being evaluated for maintaining long-term integrity of impoundment systems. Methods are being developed to estimate erosion rates associated with rock and/or vegetation covers, and to determine the effects of surface treatments on soil moisture. Interactions between surface treatments and barriers (radon and biological) are being studied as well. The product will be a set of guidelines to aid in designing surface covers. This report presents the status of this program and a discussion of considerations pertinent to the application of surface covers to tailings. Test plots located in Grand Junction, Colorado and Waterflow, New Mexico are being used to study: (1) the interactions between vegetation and radon and biological barriers, (2) the effects of surface covers on soil moisture, and (3) the effects of rock covers on vegetation.

  13. Industrial lead paint removal specifications

    SciTech Connect (OSTI)

    Stone, R.C.

    1997-06-01

    The purpose of this paper is to inform the reader as to some of the pertinent rules and regulations promulgated by the Environmental Protection Agency (EPA) and the Occupational Safety and Health Administration (OSHA) that may effect an industrial lead paint removal project. The paper discusses a recommended schedule of procedures and preparations to be followed by the lead paint removal specification writer when analyzing the possible impact of the project on the environment, the public and workers. Implications of the Clean Air Act, the Clean Water Act and the Resource Conservation and Recovery Act (RCRA) along with hazardous waste handling, manifesting, transporting and disposal procedures are discussed with special emphasis placed as to their impact on the writer and the facility owner. As the rules and regulations are highly complex, the writer has attempted to explain the methodology currently being used in state-of-the-art industrial lead abatement specifications.

  14. Arsenic removal from water

    DOE Patents [OSTI]

    Moore, Robert C. (Edgewood, NM); Anderson, D. Richard (Albuquerque, NM)

    2007-07-24

    Methods for removing arsenic from water by addition of inexpensive and commonly available magnesium oxide, magnesium hydroxide, calcium oxide, or calcium hydroxide to the water. The hydroxide has a strong chemical affinity for arsenic and rapidly adsorbs arsenic, even in the presence of carbonate in the water. Simple and commercially available mechanical methods for removal of magnesium hydroxide particles with adsorbed arsenic from drinking water can be used, including filtration, dissolved air flotation, vortex separation, or centrifugal separation. A method for continuous removal of arsenic from water is provided. Also provided is a method for concentrating arsenic in a water sample to facilitate quantification of arsenic, by means of magnesium or calcium hydroxide adsorption.

  15. Removable feedwater sparger assembly

    DOE Patents [OSTI]

    Challberg, R.C.

    1994-10-04

    A removable feedwater sparger assembly includes a sparger having an inlet pipe disposed in flow communication with the outlet end of a supply pipe. A tubular coupling includes an annular band fixedly joined to the sparger inlet pipe and a plurality of fingers extending from the band which are removably joined to a retention flange extending from the supply pipe for maintaining the sparger inlet pipe in flow communication with the supply pipe. The fingers are elastically deflectable for allowing engagement of the sparger inlet pipe with the supply pipe and for disengagement therewith. 8 figs.

  16. Drum lid removal tool

    DOE Patents [OSTI]

    Pella, Bernard M. (Martinez, GA); Smith, Philip D. (North Augusta, SC)

    2010-08-24

    A tool for removing the lid of a metal drum wherein the lid is clamped over the drum rim without protruding edges, the tool having an elongated handle with a blade carried by an angularly positioned holder affixed to the midsection of the handle, the blade being of selected width to slice between lid lip and the drum rim and, when the blade is so positioned, upward motion of the blade handle will cause the blade to pry the lip from the rim and allow the lid to be removed.

  17. Section 46: Removal of Waste

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust, High-ThroughputUpcomingmagnetoresistanceand Governmentm D m r e DFigureEffects ofRemoval

  18. Condensate removal device

    DOE Patents [OSTI]

    Maddox, James W. (Newport News, VA); Berger, David D. (Alexandria, VA)

    1984-01-01

    A condensate removal device is disclosed which incorporates a strainer in unit with an orifice. The strainer is cylindrical with its longitudinal axis transverse to that of the vapor conduit in which it is mounted. The orifice is positioned inside the strainer proximate the end which is remoter from the vapor conduit.

  19. Radiological survey of the inactive uranium-mill tailings at Ambrosia Lake, New Mexico

    SciTech Connect (OSTI)

    Haywood, F.F.; Christian, D.J.; Ellis, B.S.; Hubbard, H.M. Jr.; Lorenzo, D.; Shinpaugh, W.H.

    1980-06-01

    The inactive uranium-mill tailings pile at Ambrosia Lake, New Mexico, contains approximately 1520 Ci of /sup 226/Ra in 2.4 million metric tons of tailings covering an area of 43 hectares. All of the former mill buildings were intact and, at the time of this survey, several were in use. The tailings have not been stabilized, but the crusty surface is reported to be resistant to wind erosion. The average gamma-ray exposure rate 1 m above the tailings is 720 ..mu..R/h while the average rate in the former mill area is 150 ..mu..R/h. The adjacent area, between the mill site, ponds, and tailings pile, has an average exposure rate of 230 ..mu..R/h. Gamma radiation measurements outside these areas, as well as the results of analyses of surface or near-surface sediment and soil samples, show fairly wide dispersion of contamination around the site. The subsurface distribution of /sup 226/Ra in 18 holes drilled at the site, calculated from gamma-ray monitoring data, is presented graphically and compared with measured concentrations in two holes.

  20. Radiological survey of the inactive uranium-mill tailings at Lakeview, Oregon

    SciTech Connect (OSTI)

    Haywood, F.F.; Burden, J.E.; Ellis, B.S.; Loy, E.T.; Shinpaugh, W.H.

    1980-06-01

    The results of the radiological survey of the inactive uranium-mill site at Lakeview, Oregon, show that the average gamma-ray exposure rate 1 m above the tailings pile and the evaporation pond area (now dry) is close to the average background level for the area (11 ..mu..R/hr). The /sup 226/Ra concentration in most of the surface soil and sediment samples is also at or below the average background value for surface soil samples in the area (0.8 pCi/g). Calculated /sup 226/Ra concentrations, based on gamma radiation measurements in shallow (1-m-deep) holes, are in agreement with the results of surface soil and sediment analyses and with gamma-ray exposure rate measurements. The tailings at this site have been stabilized by the addition of 46 to 60 cm (18 to 24 in.) of soil that supports vigorous growth of vegetation. This treatment, coupled with a low-level inventory of /sup 226/Ra in the tailings (50 Ci), has resulted in limited spread of tailings by wind and water.

  1. Pneumatic soil removal tool

    DOE Patents [OSTI]

    Neuhaus, John E. (Newport News, VA)

    1992-01-01

    A soil removal tool is provided for removing radioactive soil, rock and other debris from the bottom of an excavation, while permitting the operator to be located outside of a containment for that excavation. The tool includes a fixed jaw, secured to one end of an elongate pipe, which cooperates with a movable jaw pivotably mounted on the pipe. Movement of the movable jaw is controlled by a pneumatic cylinder mounted on the pipe. The actuator rod of the pneumatic cylinder is connected to a collar which is slidably mounted on the pipe and forms part of the pivotable mounting assembly for the movable jaw. Air is supplied to the pneumatic cylinder through a handle connected to the pipe, under the control of an actuator valve mounted on the handle, to provide movement of the movable jaw.

  2. Pneumatic soil removal tool

    DOE Patents [OSTI]

    Neuhaus, J.E.

    1992-10-13

    A soil removal tool is provided for removing radioactive soil, rock and other debris from the bottom of an excavation, while permitting the operator to be located outside of a containment for that excavation. The tool includes a fixed jaw, secured to one end of an elongate pipe, which cooperates with a movable jaw pivotably mounted on the pipe. Movement of the movable jaw is controlled by a pneumatic cylinder mounted on the pipe. The actuator rod of the pneumatic cylinder is connected to a collar which is slidably mounted on the pipe and forms part of the pivotable mounting assembly for the movable jaw. Air is supplied to the pneumatic cylinder through a handle connected to the pipe, under the control of an actuator valve mounted on the handle, to provide movement of the movable jaw. 3 figs.

  3. Quick Stain Removal Guide 

    E-Print Network [OSTI]

    Brown, Pamela J.

    1998-07-29

    and dryer. ? Use the hottest wash temperature recommended on the garment care label. ? Use the right wash and dry cycle for the fabric. ? Avoid using chlorine bleach on silk, wool or spandex or on non-colorfast garments. ? Remove clothes... color-safe bleach or fabric softener. Bleaches are strong cleaning agents. Follow the in- structions on the containers. Use chlorine bleach on colorfast fabrics; it is most effective if added 5 to 6 minutes into the wash cycle. It is best...

  4. Alternatives to Nitric Acid Stripping in the Caustic-Side Solvent Extraction (CSSX) Process for Cesium Removal from Alkaline High-Level Waste

    SciTech Connect (OSTI)

    Delmau, Laetitia Helene; Haverlock, Tamara; Bazelaire, Eve; Bonnesen, Peter V; Ditto, Mary E; Moyer, Bruce A

    2009-01-01

    Effective alternatives to nitric acid stripping in the Caustic-Side Solvent Extraction (CSSX) solvent have been demonstrated in this work. The CSSX solvent employs calix[4]arene-bis(tert-octylbenzo-18-crown-6) (BOBCalixC6) as the cesium extractant in a modified alkane diluent for decontamination of alkaline high-level wastes. Results reported in this paper support the idea that replacement of the nitrate anion by a much more hydrophilic anion like borate can substantially lower cesium distribution ratios on stripping. Without any other change in the CSSX flowsheet, however, the use of a boric acid stripping solution in place of the 1 mM nitric acid solution used in the CSSX process marginally, though perhaps still usefully, improves stripping. The less-than-expected improvement was explained by the carryover of nitrate from scrubbing into stripping. Accordingly, more effective stripping is obtained after a scrub of the solvent with 0.1 M sodium hydroxide. Functional alternatives to boric acid include sodium bicarbonate or cesium hydroxide as strip solutions. Profound stripping improvement is achieved when trioctylamine, one of the components of the CSSX solvent, is replaced with a commercial guanidine reagent (LIX 79). The more basic guanidine affords greater latitude in selection of aqueous conditions in that it protonates even at mildly alkaline pH values. Under process-relevant conditions, cesium distributions on stripping are decreased on the order of 100-fold compared with current CSSX performance. The extraction properties of the solvent were preserved unchanged over three successive extract-scrub-strip cycles. From the point of view of compatibility with downstream processing, boric acid represents an attractive stripping agent, as it is also a potentially ideal feed for borosilicate vitrification of the separated 137Cs product stream. Possibilities for use of these results toward a dramatically better next-generation CSSX process, possibly one employing the more soluble cesium extractant calix[4]arene-bis(2 ethylhexylbenzo-18-crown-6) (BEHBCalixC6) are discussed.

  5. Remedial action plan and site design for stabilization of the inactive uranium mill tailings sites at Rifle, Colorado

    SciTech Connect (OSTI)

    Not Available

    1992-02-01

    This appendix assesses the present conditions and data gathered about the two inactive uranium mill tailings sites near Rifle, Colorado, and the designated disposal site six miles north of Rifle in the area of Estes Gulch. It consolidates available engineering, radiological, geotechnical, hydrological, meteorological, and other information pertinent to the design of the Remedial Action Plan (RAP). The data characterize conditions at the mill, tailings, and disposal site so that the Remedial Action Contractor (RAC) may complete final designs for the remedial actions.

  6. Melter Glass Removal and Dismantlement

    SciTech Connect (OSTI)

    Richardson, BS

    2000-10-31

    The U.S. Department of Energy (DOE) has been using vitrification processes to convert high-level radioactive waste forms into a stable glass for disposal in waste repositories. Vitrification facilities at the Savannah River Site (SRS) and at the West Valley Demonstration Project (WVDP) are converting liquid high-level waste (HLW) by combining it with a glass-forming media to form a borosilicate glass, which will ensure safe long-term storage. Large, slurry fed melters, which are used for this process, were anticipated to have a finite life (on the order of two to three years) at which time they would have to be replaced using remote methods because of the high radiation fields. In actuality the melters useable life spans have, to date, exceeded original life-span estimates. Initial plans called for the removal of failed melters by placing the melter assembly into a container and storing the assembly in a concrete vault on the vitrification plant site pending size-reduction, segregation, containerization, and shipment to appropriate storage facilities. Separate facilities for the processing of the failed melters currently do not exist. Options for handling these melters include (1) locating a facility to conduct the size-reduction, characterization, and containerization as originally planned; (2) long-term storing or disposing of the complete melter assembly; and (3) attempting to refurbish the melter and to reuse the melter assembly. The focus of this report is to look at methods and issues pertinent to size-reduction and/or melter refurbishment in particular, removing the glass as a part of a refurbishment or to reduce contamination levels (thus allowing for disposal of a greater proportion of the melter as low level waste).

  7. Electrochemically assisted paint removal

    SciTech Connect (OSTI)

    Keller, R.; Hydock, D.M.; Burleigh, T.D.

    1995-12-31

    A method to remove paint coatings from metal and other electronically conductive substrates is being studied. In particular, the remediation of objects coated with lead based paints is the focus of research. The approach also works very well with automotive coatings and may be competitive with sandblasting. To achieve debonding of the coating, the deteriorated or artifically damaged surface of the object is cathodically polarized. The object can be immersed in a benign aqueous electrolyte for treatment, or the electrolyte can be retained in an absorbent pad covering the surface to be treated.

  8. Highly Radioactive Sludge Removal Complete: Historic Cleanup...

    Broader source: Energy.gov (indexed) [DOE]

    water, transferring it into copper inserts and scrap baskets that were then loaded into stainless steel structures called multi-canister overpack containers. The containers were...

  9. Method of removing cesium from steam

    DOE Patents [OSTI]

    Carson, Jr., Neill J. (Clarendon Hills, IL); Noland, Robert A. (Oak Park, IL); Ruther, Westly E. (Skokie, IL)

    1991-01-01

    Method for removal of radioactive cesium from a hot vapor, such as high temperature steam, including the steps of passing input hot vapor containing radioactive cesium into a bed of silicate glass particles and chemically incorporating radioactive cesium in the silicate glass particles at a temperature of at least about 700.degree. F.

  10. Summary of the engineering assessment of inactive uranium mill tailings: Lakeview Site, Lakeview, Oregon

    SciTech Connect (OSTI)

    none,

    1981-10-01

    Radon gas released from the 130,000 tons of tailings at the Lakeview site constitutes the most significant environmental impact, although windblown tailings and external gamma radiation also are factors. The three alternative actions include millsite decontamination with the addition of 3 m of stabilization cover material (Option I) and removal of the tailings to remote disposal sites and decontamination of the tailings site (Options II and III). Cost estimates range from $6,000,000 for stabilization in-place, to $7,500,000 for disposal at a distance of about 10 miles. Three alternatives for reprocessing the Lakeview tailings were examined. Results show that uranium recovery is not economical.

  11. Continuous cryopump with a method for removal of solidified gases

    DOE Patents [OSTI]

    Carlson, L.W.; Herman, H.

    1988-05-05

    An improved cryopump for the removal of gases from a high vacuum, comprising a cryopanel incorporating honeycomb structure, refrigerant means thermally connected to the cryopanel, and a rotatable channel moving azimuthally around an axis located near the center of the cryopanel, removing gases adsorbed within the honeycomb structure by subliming them and conducting them outside the vacuum vessel. 4 figs.

  12. Removing Arsenic from Drinking Water

    ScienceCinema (OSTI)

    None

    2013-05-28

    See how INL scientists are using nanotechnology to remove arsenic from drinking water. For more INL research, visit http://www.facebook.com/idahonationallaboratory

  13. Removing Arsenic from Drinking Water

    SciTech Connect (OSTI)

    2011-01-01

    See how INL scientists are using nanotechnology to remove arsenic from drinking water. For more INL research, visit http://www.facebook.com/idahonationallaboratory

  14. Summary of the engineering assessment of inactive uranium mill tailings, Green River site, Green River, Utah

    SciTech Connect (OSTI)

    none,

    1981-08-01

    Radon gas released from the 123,000 tons of tailings at the Green River site constitutes the most significant environmental impact, although windblown tailings and external gamma radiation also are factors. The five alternative actions range from millsite decontamination with the addition of 3 m of stabilization cover material, to removal of the tailings to remote disposal sites and decontamination of the tailings site. Cost estimates for the five options range from about $4,300,000 for stabilization in-place, to about $9,600,000 for disposal at a distance of about 30 miles. Three principal alternatives for the reprocessing of the Green River tailings were examined: heap leaching, treatment at an existing mill, and reprocessing at a new conventional mill constructed for tailings reprocessing. The cost of the uranium recovered would be about $1,800/lb by heap leach and $1,600/lb by conventional plant processes.

  15. Summary of the engineering assessment of inactive uranium mill tailings, Naturita site, Naturita, Colorado

    SciTech Connect (OSTI)

    Not Available

    1981-07-01

    Ford, Bacon and Davis Utah Inc. has reevaluated the Naturita site in order to revise the November 1977 engineering assessment of the problems resulting from the existence of radioactive contamination at the former uranium mill tailings site at Naturita, Colorado. This evaluation has included the preparation of topographic maps, the drilling of boreholes and radiometric measurements sufficient to determine areas and volumes of contaminated materials and radiation exposures of individuals and nearby populations, and the evaluation and costing of alternative remedial actions. Radon gas released from the estimated 344,000 tons of contaminated materials that remain at the Naturita site constitutes the most significant environmental impact, although external gamma radiation also is a factor. The two alternative actions presented in this engineering assessment are stabilization of the site in its present location with the addition of 3 m of stabilization cover material (Option I), and removal of residual radioactive materials to a disposal site and decontamination of the Naturita site (Option II). Cost estimates for the two options are about $7,200,000 for stabilization in-place, and about $8,200,000 for disposal at the Ranchers Exploration and Development Corporation's reprocessing site. Truck haulage would be used to transport the contaminated materials from the Naturita site to the selected disposal site.Ranchers Exploration and Development Corporation removed the tailings from the site, reprocessed them, and disposed of them from 1977 to 1979. There is no noteworthy mineral resource remaining at the former tailings site; therefore, recovery of residual mineral values was not considered in this assessment.

  16. Engineering assessment of inactive uranium mill tailings, Naturita Site, Naturita, Colorado

    SciTech Connect (OSTI)

    Not Available

    1981-07-01

    Ford, Bacon and Davis Utah Inc. has reevaluated the Naturita site in order to revise the November 1977 engineering assessment of the problems resulting from the existence of radioactive contamination at the former uranium mill tailings site at Naturita, Colorado. This evaluation has included the preparation of topographic maps, the drilling of boreholes and radiometric measurements sufficient to determine areas and volumes of contaminated materials and radiation exposures of individuals and nearby populations, and the evaluation and costing of alternative remedial actions. Radon gas released from the estimated 344,000 tons of contaminated materials that remain at the Naturita site constitutes the most significant environmental impact, although external gamma radiation also is a factor. The two alternative actions presented in this engineering assessment are stabilization of the site in its present location with the addition of 3 m of stabilization cover material (Option I), and removal of residual radioactive materials to a disposal site and decontamination of the Naturita site (Option II). Cost estimates for the two options are about $7,200,000 for stabilization in-place, and about $8,200,000 for disposal at the Ranchers Exploration and Development Corporations's reprocessing site. Truck haulage would be used to transport the contaminated materials from the Naturita site to the selected disposal site.Ranchers Exploration and Development Corporation removed the tailings from the site, reprocessed them, and disposed of them from 1977 to 1979. There is no noteworthy mineral resource remaining at the former tailings site; therefore, recovery of residual mineral values was not considered in this assessment.

  17. BOA: Pipe asbestos insulation removal robot system

    SciTech Connect (OSTI)

    Schempf, H.; Bares, J.; Schnorr, W. [and others

    1995-12-31

    The BOA system is a mobile pipe-external robotic crawler used to remotely strip and bag asbestos-containing lagging and insulation materials (ACLIM) from various diameter pipes in (primarily) industrial installations. Steam and process lines within the DOE weapons complex warrant the use of a remote device due to the high labor costs and high level of radioactive contamination, making manual removal extremely costly and highly inefficient. Currently targeted facilities for demonstration and remediation are Fernald in Ohio and Oak Ridge in Tennessee.

  18. Engineering assessment of inactive uranium mill tailings: Monument Valley Site, Monument Valley, Arizona

    SciTech Connect (OSTI)

    Not Available

    1981-10-01

    Ford, Bacon and Davis Utah Inc. has reevalated the Monument Valley site in order to revise the March 1977 engineering assessment of the problems resulting from the existence of radioactive uranium mill tailings at Monument Valley, Arizona. This engineering assessment has included the preparation of topographic maps, the performance of core drillings and radiometric measurements sufficient to determine areas and volumes of tailings and radiation exposure of individuals and nearby populations, the investigations of site hydrology and meteorology, and the evaluation and costing of alternative corrective actions. Radon gas released from the 1.1 million tons of tailings at the Monument Valley site constitutes the most significant environmental impact, although windblown tailings and external gamma radiation also are factors. The four alternative actions presented in this engineering assessment range from millsite decontamination with the addition of 3 m of stabilization cover material (Option I), to removal of the tailings to remote disposal sites and decontamination of the tailings site (Options II through IV). Cost estimates for the four options range from about $6,600,000 for stabilization in-place, to about $15,900,000 for disposal at a distance of about 15 mi. Three principal alternatives for reprocessing the Monument Valley tailings were examined: heap leaching; Treatment at an existing mill; and reprocessing at a new conventional mill constructed for tailings reprocessing. The cost of the uranium recovery is economically unattractive.

  19. Engineering assessment of inactive uranium mill tailings, Gunnison Site, Gunnison, Colorado: summary

    SciTech Connect (OSTI)

    none,

    1981-09-01

    Ford, Bacon and Davis Utah Inc. has reevaluated the Gunnison site in order to revise the November 1977 engineering assessment of the problems resulting from the existence of radioactive uranium mill tailings at Gunnison, Colorado. This evaluation has included the preparation of topographic maps, the performance of core drillings and radiometric measurements sufficient to determine areas and volumes of tailings and radiation exposures of individuals and nearby populations, the ivnvestigations of site hydrology and meteorology, and the evaluation and costing of alternative remedial actions. Radon gas released from the combined 540,000 dry tons of tailings and the 435,400 tons of contaminated waste at the Gunnison site constitutes the most significant environmental impact, although windblown tailings and external gamma radiation also are factors. The 10 alternative actions presented in this engineering assessment range from stabilization of the site in its present location with the addition of 3 m of stabilization cover material (Option I), to removal of the tailings to disposal sites along with decontamination of the Gunnison site (Options II through X). Cost estimates for the 10 options range from about $8,900,000 for stabilization in-place, to about $14,000,000 for disposal in the North Alkali Creek area at a distance of about 18 mi. Truck haulage would be used to transport the tailings and contaminated materials from the Gunnison site to the selected disposal site. Three principal alternatives for the reprocessing of the Gunnison tailings were examined: heap leaching; treatment at an existing mill; and reprocessing at a new conventional mill constructed for tailings reprocesssing. The cost of the uranium recovered would be about $250 and $230/lb of U/sub 3/O/sub 8/ by heap leach and conventional plant processes, respectively. The spot market price for uranium was $25/lb early in 1981.

  20. Engineering assessment of inactive uranium mill tailings: Slick Rock sites, Slick Rock, Colorado

    SciTech Connect (OSTI)

    none,

    1981-09-01

    Ford, Bacon and Davis Utah, Inc., has reevaluated the Slick Rock sites in order to revise the October 1977 engineering radioactive uranium mill tailings at Slick Rock, Colorado. This engineering assessment has included the preparation of topographic maps, the performance of core drillings and radiometric measurements sufficient to determine areas and volumes of tailings and radiation exposures of individuals and nearby populations, the investigations of site hydrology and meteorology, and the evaluation and costing of alternative corrective actions. Radon gas released from the 387,000 tons of tailings at the Slick Rock sites constitutes the most significant environmental impact, although windblown tailings and external gamma radiation also are factors. The five alternative actions presented in this engineering assessment include millsite decontamination with the addition of 3 m of stabilization cover material, consolidation of the piles, and removal of the tailings to remote disposal sites and decontamination of the tailings sites. Cost estimates for the five options range from about $6,800,000 for stabilization in-place, to about $11,000,000 for disposal at a distance of about 6.5 mi. Three principal alternatives for the reprocessing of the Slick Rock tailings were examined: heap leaching; treatment at an existing mill; and reprocessing at a new conventional mill constructed for tailings reprocessing. The cost of the uranium recovered would be over $800/lb of U/sub 3/O/sub 8/ whether by conventional or heap leach plant processes. The spot market price for uranium was $25/lb early in 1981. Therefore, reprocessing the tailings for uranium recovery is not economically attractive at present, nor for the foreseeable future.

  1. Summary of the engineering assessment of inactive uranium mill tailings: Falls City site, Falls City, Texas

    SciTech Connect (OSTI)

    none,

    1981-10-01

    Ford, Bacon and Davis Utah Inc. has reevaluated the Falls City site in order to update the December 1977 engineering assessment of the problems resulting from the existence of radioactive uranum mill tailings at Falls City, Texas. This engineering assessment has included the preparation of topographic maps, the performance of core drillings and radiometric measurements sufficient to determine areas and volumes of tailings and radiation exposures of individuals and nearby populations, the investigations of site hydrolgy and meteorology, and the evaluation and costing of alternative corrective actions. Radon gas released from the 2.5 million tons of tailings at the Falls City site constitutes the most significant environmental impact, although windblown tailings and external gamma radiation also are factors. The four alternative actions presented in this engineering assessment range from millsite decontamination with the addition of 3 m of stabilization cover material, to removal of the tailings to remote disposal sites and decontamination of the tailings site. Cost estimates for the four options range from about $21,700,000 for stabilization in place, to about $35,100,000 for disposal at a distance of about 15 mi. Three principal alternatives for the reprocessing of the Falls City tailings were examined: heap leaching; treatment at an existing mill; reprocessing at a new conventional mill constructed for tailings reprocessing. The tailings piles are presently being rewashed for uranium recovery by Solution Engineering, Inc. The cost for further reprocessing would be about $250/lb of U/sub 3/O/sub 8/. The spot market price for uranium was $25/lb early in 1981. Therefore, reprocessing the tailings for uranium recovery does not appear to be economically attractive for the foreseeable future.

  2. Summary of the engineering assessment of inactive uranium mill tailings: Monument Valley site, Monument Valley, Arizona

    SciTech Connect (OSTI)

    none,

    1981-10-01

    Ford, Bacon and Davis Utah Inc. has reevaluated the Monument Valley site in order to revise the March 1977 engineering assessment of the problems resulting from the existence of radioactive uranium mill tailings at Monument Valley, Arizona. This engineering assessment has included the preparation of topographic maps, the performance of core drillings and radiometric measurements sufficient to determine areas and volumes of tailings and radiation exposures of individuals and nearby populations, the investigations of site hydrology and meteorology, and the evaluation and costing of alternative corrective actions. Radon gas released from the 1.1 million tons of tailings at the Monument Valley site constitutes the most significant environmental impact, although windblown tailings and external gamma radiation also are factors. The four alternative actions presented in this engineering assessment range from millsite decontamination with the addition of 3 m of stabilization cover material to removal of the tailings to remote disposal sites and decontamination of the tailings site. Cost estimates for the four options range from about $6,600,000 for stabilization in-place, to about $15,900,000 for disposal at a distance of about 15 mi. Three principal alternatives for reprocessing the Monument Valley tailings were examined: heap leaching, treatment at an existing mill; and reprocessing at a new conventional mill constructed for tailings reprocessing. The cost of the uranium recovered would be more than $500/lb of U/sub 3/O/sub 8/ by heap leach or conventional plant processes. The spot market price for uranium was $25/lb early in 1981. Therefore, reprocessing the tailings for uranium recovery is economically unattractive.

  3. Engineering assessment of inactive uranium mill tailings: Mexican Hat site, Mexican Hat, Utah. Summary

    SciTech Connect (OSTI)

    none,

    1981-09-01

    Ford, Bacon and Davis Utah Inc. has reevaluated the Mexican Hat site in order to revise the March 1977 engineering assessment of the problems resulting from the existence of radioactive uranium mill tailings at Mexican Hat, Utah. This engineering assessment has included the preparation of topographic maps, the performance of core drillings and radiometric measurements sufficient to determine areas and volumes of tailings and radiation exposures of individuals and nearby populations, the investigations of site hydrology and meteorology, and the investigations of site hydrology and meteorology, and the evaluation and costing of alternative corrective actions. Radon gas released from the 2.2 million tons of tailings at the Mexican Hat site constitutes the most significant environmental impact, although windblown tailings and external gamma radiation also are factors. The four alternative actions presented in this engineering assessment range from millsite decontamination with the addition of 3 m of stabilization cover material to removal of the tailings to remote disposal sites and decontamination of the tailings site. Cost estimates for the four options range from about $15,200,000 for stabilization in place, to about $45,500,000 for disposal at a distance of about 16 mi. Three principal alternatives for the reprocessing of the Mexican Hat tailings were examined: (a) heap leaching; treatment at an existing mill; and reprocessing at a new conventional mill constructed for tailings reprocessing. The cost of the uranium recovered would be about $115/lb of U/sub 3/O/sub 8/ whether by heap leach or conventional plant processes. The spot market price for uranium was $25/lb early in 1981. Reprocessing the Mexican Hat tailings for uranium recovery is not economically attractive under present conditions.

  4. Summary of the engineering assessment of inactive uranium mill tailings: Slick Rock sites, Slick Rock, Colorado

    SciTech Connect (OSTI)

    none,

    1981-09-01

    Ford, Bacon and Davis Utah, Inc., has reevaluated the Slick Rock sites in order to revise the October 1977 engineering assessment of the problems resulting from the existence of radioactive uranium mill tailings at Slick Rock, Colorado. This engineering assessment has included the preparation of topographic maps, the performance of core drillings and volumes of tailings and radiation exposures of individuals and nearby populations, the investigations of site hydrology and meteorology, and the evaluation and costing of alternative corrective actions. Radon gas released from the 387,000 tons of tailings at the Slick Rock sites constitutes the most significant environmental impact, although windblown tailings and external gamma radiation also are factors. The five alternative actions presented in this engineering assessment include millsite decontamination with the addition of 3 m of stabilization cover material, consolidation of the piles, and removal of the tailings to remote disposal sites and decontamination of the tailings sites. Cost estimates for the five options range from about $6,800,000 for stabilization in-place, to about $11,000,000 for disposal at a distance of about 6.5 mi. Three principal alternatives for the reprocessing of the Slick Rock tailings were examined: heap leaching; treatment at an existing mill; and reprocessing at a new conventional mill constructed for tailings reprocessing. The cost of the uranium recovered would be over $800/lb of U/sub 3/O/sub 8/ whether by conventional or heap leach plant processes. The spot market price for uranium was $25/lb early in 1981. Therefore, reprocessing the tailings for uranium recovery is not economically attractive at present, nor for the foreseeable future.

  5. Summary of the engineering assessment of inactive uranium mill tailings, Shiprock Site, Shiprock, New Mexico

    SciTech Connect (OSTI)

    none,

    1981-07-01

    Ford, Bacon and Davis Utah Inc. has reevaluated the Shiprock site in order to revise the March 1977 engineering assessment of the problems resulting from the existence of radioactive uranium mill tailings at Shiprock, New Mexico. This engineering assessment has included the preparation of topographic maps, the performance of core drillings and radiometric measurements sufficient to determine areas and volumes of tailings and radiation exposures of individuals and nearby populations, the investigations of site hydrology and meteorology, and the evaluation and costing of alternative corrective actions. Radon gas released from the 1.5 million dry tons of tailings at the Shiprock site constitutes the most significant environmental impact, although windblown tailings and external gamma radiation also are factors. The eight alternative actions presented in this engineering assessment range from millsite decontamination with the addition of 3 m of the stabilization cover material (Option I), to removal of the tailings to remote disposal sites and decontamination of the tailings site (Options II through VIII). Cost estimates for the eight options range from about $13,400,000 for stabilization in place to about $37,900,000 for disposal at a distance of about 16 miles. Three principal alternatives for the reprocessing of the Shiprock tailings were examined: (a) heap leaching; (b) treatment at an existing mill; and(c) reprocessing at a new conventional mill constructed for tailings reprocessing. The cost of the uranium recovered would be about $230/lb by heap leach and $250/lb by conventional plant processes. The spot market price for uranium was $25/lb early in 1981. Therefore, reprocessing the tailings for uranium recovery is not economically attractive.

  6. Summary of the engineering assessment of inactive uranium mill tailings, Riverton Site, Riverton, Wyoming

    SciTech Connect (OSTI)

    none,

    1981-08-01

    Ford, Bacon, and Davis Utah Inc. has reevaluated the Riverton site in order to revise the December 1977 engineering assessment of the problems resulting from the existence of radioactive uranium mill tailings at Riverton, Wyoming. This engineering assessment has included the preparation of topographic maps, the performance of core drillings and radiometric measurements sufficient to determine areas and volumes of tailings and radiation exposures of individuals and nearby populations, the investigations of site hydrology and meteorology, and the evaluation and costing of alternative corrective actions. Radon gas released from the 900,000 tons of tailings materials at the Riverton site constitutes the most significant environmental impact, although windblown tailings and external gamma radiation also are factors. The nine alternative actions presented in this engineering assessment range from millsite decontamination with the addition of 3 m of stabilization cover material (Option I), to removal of the tailings to remote disposal sites and decontaminations of the tailings site (Options II through IX). Cost estimates for the nine options range from about $16,600,000 for stabilization in-place, to about $23,200,000 for disposal at a distance of 18 to 25 mi. Three principal alternatives for the reprocessing of the Riverton tailings were examined: (a) heap leaching; (b) treatment at an existing mill; and (c) reprocessing at a new conventional mill constructed for tailings reprocessing. The cost of the uranium recovered would be about $260 and $230/lb of U/sub 3/O/sub 8/ by heap leach and conventional plant processes respectively. The spot market price for uranium was $25/lb early in 1981. Therefore, reprocessing the tailings for uranium recovery does not appear to be economically attractive.

  7. Multipollutant Removal with WOWClean® System 

    E-Print Network [OSTI]

    Romero, M.

    2010-01-01

    from the flue gas of a power plant and demonstrate the technology. The system integrates proven emission reduction techniques into a single, multi-pollutant reduction system and is designed to remove Mercury, SOx, NOx, particulates, heavy metals...

  8. Method of arsenic removal from water

    DOE Patents [OSTI]

    Gadgil, Ashok (El Cerrito, CA)

    2010-10-26

    A method for low-cost arsenic removal from drinking water using chemically prepared bottom ash pre-treated with ferrous sulfate and then sodium hydroxide. Deposits on the surface of particles of bottom ash form of activated iron adsorbent with a high affinity for arsenic. In laboratory tests, a miniscule 5 grams of pre-treated bottom ash was sufficient to remove the arsenic from 2 liters of 2400 ppb (parts per billion) arsenic-laden water to a level below 50 ppb (the present United States Environmental Protection Agency limit). By increasing the amount of pre-treated bottom ash, even lower levels of post-treatment arsenic are expected. It is further expected that this invention supplies a very low-cost solution to arsenic poisoning for large population segments.

  9. Salt-and-Pepper Noise Removal by Median-type Noise Detectors and

    E-Print Network [OSTI]

    Chan, Raymond

    1 Salt-and-Pepper Noise Removal by Median-type Noise Detectors and Detail-preserving Regularization for removing salt-and-pepper impulse noise. In the first phase, an adaptive median filter is used to identify remove salt-and-pepper-noise with noise level as high as 90%. Index Terms Impulse noise, adaptive median

  10. Tank 241-CX-70 waste removal and packaging

    SciTech Connect (OSTI)

    DuVon, D.K.

    1993-06-01

    Tank 241-CX-70, located on the Hanford Site in Washington State, is a 30,000 gal single-shell storage tank built in 1952 to hold high-level process waste from pilot tests of the reduction-oxidation process. In 1979 decommissioning operations were begun by pumping liquid waste from the tank to the double-shell tank (DST) 101-AY. Not all the waste was removed at that time. Approximately 10,300 gal of sludge remained. On September 25, 1987, operations were resumed to remove the remaining waste using a sluicing and pumping method. This report documents the final removal of waste from Tank 241-CX-70.

  11. Tank 241-CX-70 waste removal and packaging

    SciTech Connect (OSTI)

    DuVon, D.K.

    1993-01-01

    Tank 241-CX-70, located on the Hanford Site in Washington State, is a 30,000 gal single-shell storage tank built in 1952 to hold high-level process waste from pilot tests of the reduction-oxidation process. In 1979 decommissioning operations were begun by pumping liquid waste from the tank to the double-shell tank (DST) 101-AY. Not all the waste was removed at that time. Approximately 10,300 gal of sludge remained. On September 25, 1987, operations were resumed to remove the remaining waste using a sluicing and pumping method. This report documents the final removal of waste from Tank 241-CX-70.

  12. Protection #2: Trap and Remove Sediment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trap and Remove Sediment Protection 2: Trap and Remove Sediment The 3 Protections Defense in Depth August 1, 2013 Sediment behind LA Canyon weir is sampled and excavated...

  13. Removal - An alternative to clearance

    SciTech Connect (OSTI)

    Feinhals, J.; Kelch, A.; Kunze, V.

    2007-07-01

    This presentation shows the differences between the application of clearance and removal, both being procedures for materials leaving radiation protection areas permanently. The differentiation will be done on the basis of the German legislation but may be also applicable for other national legislation. For clearance in Germany two basic requirements must be given, i.e. that the materials are activated or contaminated and that they result from the licensed use or can be assigned to the scope of the license. Clearance needs not to be applied to objects in Germany which are to be removed only temporarily from controlled areas with the purpose of repair or reuse in other controlled areas. In these cases only the requirements of contamination control apply. In the case of removal it must either be proved by measurements that the relevant materials are neither activated nor contaminated or that the materials result from areas where activation or contamination is impossible due to the operational history considering operational procedures and events. If the material is considered neither activated nor contaminated there is no need for a clearance procedure. Therefore, these materials can be removed from radiation protection areas and the removal is in the responsibility of the licensee. Nevertheless, the removal procedure and the measuring techniques to be applied for the different types of materials need an agreement from the competent authority. In Germany a maximum value of 10% of the clearance values has been established in different licenses as a criterion for the application of removal. As approximately 2/3 of the total mass of a nuclear power plant is not expected to be contaminated or activated there is a need for such a procedure of removal for this non contaminated material without any regulatory control especially in the case of decommissioning. A remarkable example is NPP Stade where in the last three years more than 8600 Mg were disposed of by removal and only 315 Mg were released by clearance, even before the decommissioning licensing procedure was finished. (authors)

  14. Large Component Removal/Disposal

    SciTech Connect (OSTI)

    Wheeler, D. M.

    2002-02-27

    This paper describes the removal and disposal of the large components from Maine Yankee Atomic Power Plant. The large components discussed include the three steam generators, pressurizer, and reactor pressure vessel. Two separate Exemption Requests, which included radiological characterizations, shielding evaluations, structural evaluations and transportation plans, were prepared and issued to the DOT for approval to ship these components; the first was for the three steam generators and one pressurizer, the second was for the reactor pressure vessel. Both Exemption Requests were submitted to the DOT in November 1999. The DOT approved the Exemption Requests in May and July of 2000, respectively. The steam generators and pressurizer have been removed from Maine Yankee and shipped to the processing facility. They were removed from Maine Yankee's Containment Building, loaded onto specially designed skid assemblies, transported onto two separate barges, tied down to the barges, th en shipped 2750 miles to Memphis, Tennessee for processing. The Reactor Pressure Vessel Removal Project is currently under way and scheduled to be completed by Fall of 2002. The planning, preparation and removal of these large components has required extensive efforts in planning and implementation on the part of all parties involved.

  15. Actinide removal from spent salts

    DOE Patents [OSTI]

    Hsu, Peter C. (Pleasanton, CA); von Holtz, Erica H. (Livermore, CA); Hipple, David L. (Livermore, CA); Summers, Leslie J. (Livermore, CA); Adamson, Martyn G. (Danville, CA)

    2002-01-01

    A method for removing actinide contaminants (uranium and thorium) from the spent salt of a molten salt oxidation (MSO) reactor is described. Spent salt is removed from the reactor and analyzed to determine the contaminants present and the carbonate concentration. The salt is dissolved in water, and one or more reagents are added to precipitate the thorium as thorium oxide and/or the uranium as either uranium oxide or as a diuranate salt. The precipitated materials are filtered, dried and packaged for disposal as radioactive waste. About 90% of the thorium and/or uranium present is removed by filtration. After filtration, salt solutions having a carbonate concentration >20% can be dried and returned to the reactor for re-use. Salt solutions containing a carbonate concentration <20% require further clean-up using an ion exchange column, which yields salt solutions that contain less than 0.1 ppm of thorium or uranium.

  16. UNIVERSITY OF SUSSEX Removal expenses

    E-Print Network [OSTI]

    Sussex, University of

    scale: first year of employment: 100% second year of employment: 50% third year of employment: 25 be payable to staff whose contract is for one year or more. However, new staff employed on a contract of less than one year who contract is subsequently extended beyond one year will then be eligible for removal

  17. Baseline risk assessment of ground water contamination at the inactive uraniferous lignite ashing site near Bowman, North Dakota

    SciTech Connect (OSTI)

    Not Available

    1994-11-01

    This baseline risk assessment of ground water contamination at the inactive uraniferous lignite ashing site near Bowman, North Dakota, evaluates the potential impacts to public health or the environment from contaminated ground water at this site. This contamination is a result of the uraniferous lignite ashing process, when coal containing uranium was burned to produce uranium. Potential risk is quantified only for constituents introduced by the processing activities and not for the constituents naturally occurring in background ground water in the site vicinity. Background ground water, separate from any site-related contamination, imposes a percentage of the overall risk from ground water ingestion in the Bowman site vicinity. The US Department of Energy (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project is developing plans to address soil and ground water contamination at the site. The UMTRA Surface Project involves the determination of the extent of soil contamination and design of an engineered disposal cell for long-term storage of contaminated materials. The UMTRA Ground Water Project evaluates ground water contamination. Based on results from future site monitoring activities as defined in the site observational work plan and results from this risk assessment, the DOE will propose an approach for managing contaminated ground water at the Bowman site.

  18. US Department of Energy response to standards for remedial actions at inactive uranium processing sites: Proposed rule

    SciTech Connect (OSTI)

    Not Available

    1988-01-29

    The Title I groundwater standards for inactive uranium mill tailings sites, which were promulgated on January 5, 1983, by the US Environmental Protection Agency (EPA) for the Uranium Mill Tailings Remedial Action (UMTRA) Project, were remanded to the EPA on September 3, 1985, by the US Tenth Circuit Court of Appeals. The Court instructed the EPA to compile general groundwater standards for all Title I sites. On September 24, 1987, the EPA published proposed standards (52FR36000-36008) in response to the remand. This report includes an evaluation of the potential effects of the proposed EPA groundwater standards on the UMTRA Project, as well as a discussion of the DOE's position on the proposed standards. The report also contains and appendix which provides supporting information and cost analyses. In order to assess the impacts of the proposed EPA standards, this report summarizes the proposed EPA standards in Section 2.0. The next three sections assess the impacts of the three parts of the EPA standards: Subpart A considers disposal sites; Subpart B is concerned with restoration at processing sites; and Subpart C addresses supplemental standards. Section 6.0 integrates previous sections into a recommendations section. Section 7.0 contains the DOE response to questions posed by the EPA in the preamble to the proposed standards. 6 refs., 5 figs., 3 tabs.

  19. Removing Stains from Washable Fabrics. 

    E-Print Network [OSTI]

    Beard, Ann Vanderpoorten

    1988-01-01

    unique treatment be cause of chemical make-up or physical characteristics. (Examples: chewing gum, iodine, lead pencil) Stain Removal Products Bleaches Chlorine bleaches contain a hypochlorite com pound. Do not use them on wool, silk, polyurethane... foam, spandex or blends of these fibers; on finishes which are embossed or flame retardant; or on fabrics labeled no chlorine bleach. Avoid contact with metal. Always follow package instructions for dilu tion. Liquid chlorine bleaches lose strength...

  20. Remedial action plan for the inactive Uranium Processing Site at Naturita, Colorado. Remedial action plan: Attachment 2, Geology report, Attachment 3, Ground water hydrology report: Working draft

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    The uranium processing site near Naturita, Colorado, is one of 24 inactive uranium mill sites designated to be cleaned up by the US Department of Energy (DOE) under the Uranium Mill Tailings Radiation Control Act of 1978 (UMTRCA), 42 USC {section}7901 et seq. Part of the UMTRCA requires that the US Nuclear Regulatory Commission (NRC) concur with the DOE`s remedial action plan (RAP) and certify that the remedial action conducted at the site complies with the standards promulgated by the US Environmental Protection Agency (EPA). This RAP serves two purposes. First, it describes the activities that are proposed by the DOE to accomplish remediation and long-term stabilization and control of the radioactive materials at the inactive uranium processing site near Naturita, Colorado. Second, this RAP, upon concurrence and execution by the DOE, the state of Colorado, and the NRC, become Appendix B of the cooperative agreement between the DOE and the state of Colorado.

  1. Status of activities on the inactive uranium mill tailings sites remedial action program. Office of the Assistant Secretary for Environment

    SciTech Connect (OSTI)

    Not Available

    1981-04-01

    This report on the status of the Office of Environment's program for inactive uranium mill tailings sites is an analysis of the current status and a forecast of future activities of the Office of Environment. The termination date for receipt of information was September 30, 1980. Aerial radiological surveys and detailed ground radiological assessments of properties within the communities in the vicinity of the designated processing sites in Canonsburg, Pennsylvania, Salt Lake City, Utah, and Boise, Idaho led to the designation of an initial group of vicinity properties for remedial action. The potential health effects of the residual radioactive materials on or near these properties were estimated, and the Assistant Secretary for Environment recommended priorities for performing remedial action to the Department's Assistant Secretary for Nuclear Energy. In designating these properties and establishing recommended priorities for performing remedial action, the Office of Environment consulted with the Environmental Protection Agency, the Nuclear Regulatory Commission, representatives from the affected State and local governments, and individual property owners. After notifying the Governors of each of the affected States and the Navajo Nation of the Secretary of Energy's designation of processing sites within their areas of jurisdiction and establishment of remedial action priorities, a Sample Cooperative Agreement was developed by the Department in consultation with the Nuclear Regulatory Commission and provided to the affected States and the Navajo Nation for comments. During September 1980, a Cooperative Agreement with the Commonwealth of Pennsylvania for the designated Canonsburg processing site was executed by the Department. It is anticipated that a Cooperative Agreement between the State of Utah and the Department to perform remedial actions at the designated Salt Lake City site will be executed in the near future.

  2. Remedial action plan and site design for stabilization of the inactive uranium mill tailings sites at Rifle, Colorado. Volume 2, Appendices D and E: Final report

    SciTech Connect (OSTI)

    Not Available

    1992-02-01

    This appendix assesses the present conditions and data gathered about the two inactive uranium mill tailings sites near Rifle, Colorado, and the designated disposal site six miles north of Rifle in the area of Estes Gulch. It consolidates available engineering, radiological, geotechnical, hydrological, meteorological, and other information pertinent to the design of the Remedial Action Plan (RAP). The data characterize conditions at the mill, tailings, and disposal site so that the Remedial Action Contractor (RAC) may complete final designs for the remedial actions.

  3. Remedial Action Plan and site design for stabilization of the inactive uranium mill tailings site at Mexican Hat, Utah: Appendix D. Final report

    SciTech Connect (OSTI)

    NONE

    1988-07-01

    This appendix is an assessment of the present conditions of the inactive uranium mill site near Mexican Hat, Utah. It consolidates available engineering, radiological, geotechnical, hydrological, meteorological, and other information pertinent to the design of the Remedial Action Plan. Plan is to characterize the conditions at the mill and tailings site so that the Remedial Action Contractor may complete final designs of the remedial action.

  4. Savannah River Site Waste Removal Program - Past, Present and Future

    SciTech Connect (OSTI)

    Saldivar, E.

    2002-02-25

    The Savannah River Site has fifty-one high level waste tanks in various phases of operation and closure. These tanks were originally constructed to receive, store, and treat the high level waste (HLW) created in support of the missions assigned by the Department of Energy (DOE). The Federal Facilities Agreement (FFA) requires the high level waste to be removed from the tanks and stabilized into a final waste form. Additionally, closure of the tanks following waste removal must be completed. The SRS HLW System Plan identifies the interfaces of safe storage, waste removal, and stabilization of the high level waste and the schedule for the closure of each tank. HLW results from the dissolution of irradiated fuel components. Desired nuclear materials are recovered and the byproducts are neutralized with NaOH and sent to the High Level Waste Tank Farms at the SRS. The HLW process waste clarifies in the tanks as the sludge settles, resulting in a layer of dense sludge with salt supernate settling above the sludge. Salt supernate is concentrated via evaporation into saltcake and NaOH liquor. This paper discusses the history of SRS waste removal systems, recent waste removal experiences, and the challenges facing future removal operations to enhance efficiency and cost effectiveness. Specifically, topics will include the evolution and efficiency of systems used in the 1960's which required large volumes of water to current systems of large centrifugal slurry pumps, with significant supporting infrastructure and safety measures. Interactions of this equipment with the waste tank farm operations requirements will also be discussed. The cost and time improvements associated with these present-day systems is a primary focus for the HLW Program.

  5. Video requirements plan for the HMT equipment removal system

    SciTech Connect (OSTI)

    Vargo, G.F. Jr.

    1995-02-01

    This document is the plan defining the video coverage requirements for the equipment removal event of the Hydrogen Mitigation Test (HMT) mixer pump currently installed in high level nuclear waste storage Tank 241-SY-101. When the mixer pump fails the removal and installation of a spare pump will be a time critical event. Since the success of the HMT mixer pump has resolved the DOE safety issue it is absolutely essential that mixing be restored to the tank in a short as time possible. Therefore, the removal of the failed pump and the installation of the spare pump must be anticipated and planned well in advance. The removal, containment, transporting, and storage of the failed pump is a very complex and hazardous task. The successful completion of this task will require careful planning and monitoring. Certain events, during the removal and subsequent installation of the new pump, will require video observation and storage for safety, documenting, training, and promotional use. Furthermore, certain events will require close monitoring and observation by the event directors and key supervisory personnel for the execution of specific tasks during the equipment removal event.

  6. IDENTIFYING CANDIDATE PROTEIN FOR REMOVAL OF ENVIRONMENTALLY

    E-Print Network [OSTI]

    Uppsala Universitet

    IDENTIFYING CANDIDATE PROTEIN FOR REMOVAL OF ENVIRONMENTALLY HAZARDOUS SUBSTANCES Pharem Biotech products and technologies for removing environmental hazardous substances in our everyday life. The products can be applied in areas from the private customer up to the global corporate perspective

  7. Mexico HEU Removal | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Apply for Our Jobs Our Jobs Working at NNSA Blog Home content Four-Year Plan Mexico HEU Removal Mexico HEU Removal Location Mexico United States 24 24' 35.298" N, 102...

  8. Nuclear & Radiological Material Removal | National Nuclear Security...

    National Nuclear Security Administration (NNSA)

    & Radiological Material Removal | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation...

  9. Quick Stain Removal Guide (Spanish) 

    E-Print Network [OSTI]

    Brown, Pamela J.

    2001-08-22

    -5191S de la Oficina de Extensi?n, Etiquetas de Instrucciones y su Ropa). Lleve las prendas de vestir de lavado en seco a tintorer?as profe- sionales. Siga estas pautas para las prendas de vestir lavables: Sepa de qu? es la mancha. Si no sabe, intente...). The Soap and Detergent Association, Marzo/Abril. NY: New York. Laundering Facts. (1991). The Soap and Detergent Association. NY: New York. Beard, A.V. (1989). Removing stains from washable fabrics. Servicio de Extensi?n Agr?cola de Texas. TX: College...

  10. Method of making thermally removable epoxies

    SciTech Connect (OSTI)

    Loy, Douglas A. (Albuquerque, NM); Wheeler, David R. (Albuquerque, NM); Russick, Edward M. (Rio Rancho, NM); McElhanon, James R. (Albuquerque, NM); Saunders, Randall S. (late of Albuquerque, NM)

    2002-01-01

    A method of making a thermally-removable epoxy by mixing a bis(maleimide) compound to a monomeric furan compound containing an oxirane group to form a di-epoxy mixture and then adding a curing agent at temperatures from approximately room temperature to less than approximately 90.degree. C. to form a thermally-removable epoxy. The thermally-removable epoxy can be easily removed within approximately an hour by heating to temperatures greater than approximately 90.degree. C. in a polar solvent. The epoxy material can be used in protecting electronic components that may require subsequent removal of the solid material for component repair, modification or quality control.

  11. The HMDS Coating Flaw Removal Tool

    SciTech Connect (OSTI)

    Monticelli, M V; Nostrand, M C; Mehta, N; Kegelmeyer, L; Johnson, M A; Fair, J; Widmayer, C

    2008-10-24

    In many high energy laser systems, optics with HMDS sol gel antireflective coatings are placed in close proximity to each other making them particularly susceptible to certain types of strong optical interactions. During the coating process, halo shaped coating flaws develop around surface digs and particles. Depending on the shape and size of the flaw, the extent of laser light intensity modulation and consequent probability of damaging downstream optics may increase significantly. To prevent these defects from causing damage, a coating flaw removal tool was developed that deploys a spot of decane with a syringe and dissolves away the coating flaw. The residual liquid is evacuated leaving an uncoated circular spot approximately 1mm in diameter. The resulting uncoated region causes little light intensity modulation and thus has a low probability of causing damage in optics downstream from the mitigated flaw site.

  12. Sorbents for the oxidation and removal of mercury

    DOE Patents [OSTI]

    Olson, Edwin S.; Holmes, Michael J.; Pavlish, John Henry

    2014-09-02

    A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

  13. Sorbents for the oxidation and removal of mercury

    DOE Patents [OSTI]

    Olson, Edwin S. (Grand Forks, ND); Holmes, Michael J. (Thompson, ND); Pavlish, John H. (East Grand Forks, MN)

    2012-05-01

    A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

  14. Sorbents for the oxidation and removal of mercury

    DOE Patents [OSTI]

    Olson, Edwin S. (Grand Forks, ND); Holmes, Michael J. (Thompson, ND); Pavlish, John H. (East Grand Forks, MN)

    2008-10-14

    A promoted activated carbon sorbent is described that is highly effective for the removal of mercury from flue gas streams. The sorbent comprises a new modified carbon form containing reactive forms of halogen and halides. Optional components may be added to increase reactivity and mercury capacity. These may be added directly with the sorbent, or to the flue gas to enhance sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The sorbent can be regenerated and reused. Sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active sorbent into the mercury contaminated gas stream are described.

  15. Environmental Impacts of Stover Removal in the Corn Belt

    SciTech Connect (OSTI)

    Alicia English; Wallace E. Tyner; Juan Sesmero; Phillip Owens; David Muth

    2012-08-01

    When considering the market for biomass from corn stover resources erosion and soil quality issues are important to consider. Removal of stover can be beneficial in some areas, especially when coordinated with other conservation practices, such as vegetative barrier strips and cover crops. However, benefits are highly dependent on several factors, namely if farmers see costs and benefits associated with erosion and the tradeoffs with the removal of biomass. This paper uses results from an integrated RUSLE2/WEPS model to incorporate six different regime choices, covering management, harvest and conservation, into simple profit maximization model to show these tradeoffs.

  16. Fuel removal, transport, and storage

    SciTech Connect (OSTI)

    Reno, H.W.

    1986-01-01

    The March 1979 accident at Unit 2 of the Three Mile Island Nuclear Power Station (TMI-2) which damaged the core of the reactor resulted in numerous scientific and technical challenges. Some of those challenges involve removing the core debris from the reactor, packaging it into canisters, loading canisters into a rail cask, and transporting the debris to the Idaho National Engineering Laboratory (INEL) for storage, examination, and preparation for final disposal. This paper highlights how some challenges were resolved, including lessons learned and benefits derived therefrom. Key to some success at TMI was designing, testing, fabricating, and licensing two rail casks, which each provide double containment of the damaged fuel. 10 refs., 12 figs.

  17. BOA II: pipe-asbestos insulation removal system

    SciTech Connect (OSTI)

    Schempf, H.; Mutschler; Boehmke, S.; Chemel, B.; Piepgras, C.

    1996-12-31

    BOA system is a mobile pipe-external robotic crawler used to remotely strip and bag asbestos-containing lagging and insulation materials from various diameter pipes in (primarily) industrial installations. Steam and process lines within the DOE weapons complex warrant the use of a remote device due to high labor costs and high level of radioactive contamination, making manual removal costly and inefficient. Currently targeted facilities for demonstration and remediation are Fernald in Ohio and Oak Ridge in Tennessee.

  18. Remedial Action Plan and final design for stabilization of the inactive uranium mill tailings at Green River, Utah. Volume 1, Text, Appendices A, B, and C: Final report

    SciTech Connect (OSTI)

    Matthews, M.L. [USDOE Albuquerque Operations Office, NM (United States). Uranium Mill Tailings Remedial Action Project Office; Alkema, K. [Utah Dept. of Health, Salt Lake City, UT (United States). Environmental Health Div.

    1991-03-01

    This Remedial Action Plan (RAP) has been developed to serve a threefold purpose. It presents the series of activities that are proposed by the US Department of Energy (DOE) to accomplish long-term stabilization and control of radioactive materials at the inactive uranium processing site located near Green River, Utah. It provides a characterization of the present conditions of the site. It also serves to document the concurrence of the state of Utah and the US Nuclear Regulatory Commission (NRC) in the remedial action. This agreement, upon execution by the DOE and the state of Utah, and concurrence by the NRC, becomes Appendix 8 of the Cooperative Agreement.

  19. Using Magnetically Responsive Tea Waste to Remove Lead in Waters under Environmentally Relevant

    E-Print Network [OSTI]

    Doyle, Patrick S.

    on the initial Pb concentration. Our prepared magnetite-waste tea composites show promise as a green, inexpensiveUsing Magnetically Responsive Tea Waste to Remove Lead in Waters under Environmentally Relevant report the use of a simple yet highly effective magnetite-waste tea composite to remove lead(II) (Pb2

  20. Methods and apparatus for removal and control of material in laser drilling of a borehole

    DOE Patents [OSTI]

    Rinzler, Charles C; Zediker, Mark S; Faircloth, Brian O; Moxley, Joel F

    2014-01-28

    The removal of material from the path of a high power laser beam during down hole laser operations including drilling of a borehole and removal of displaced laser effected borehole material from the borehole during laser operations. In particular, paths, dynamics and parameters of fluid flows for use in conjunction with a laser bottom hole assembly.

  1. Method for removing contaminants from plastic resin

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2008-12-09

    A resin recycling method that produces essentially contaminant-free synthetic resin material in an environmentally safe and economical manner. The method includes receiving the resin in container form. The containers are then ground into resin particles. The particles are exposed to a solvent, the solvent contacting the resin particles and substantially removing contaminants on the resin particles. After separating the particles and the resin, a solvent removing agent is used to remove any residual solvent remaining on the resin particles after separation.

  2. PRTR ion exchange vault water removal

    SciTech Connect (OSTI)

    Ham, J.E.

    1995-11-01

    This report documents the removal of radiologically contaminated water from the Plutonium Recycle Test Reactor (PRTR) ion exchange vault. Approximately 57,000 liters (15,000 gallons) of water had accumulated in the vault due to the absence of a rain cover. The water was removed and the vault inspected for signs of leakage. No evidence of leakage was found. The removal and disposal of the radiologically contaminated water decreased the risk of environmental contamination.

  3. Process for particulate removal from coal liquids

    DOE Patents [OSTI]

    Rappe, Gerald C. (Macungie, PA)

    1983-01-01

    Suspended solid particulates are removed from liquefied coal products by first subjecting such products to hydroclone action for removal in the underflow of the larger size particulates, and then subjecting the overflow from said hydroclone action, comprising the residual finer particulates, to an electrostatic field in an electrofilter wherein such finer particulates are deposited in the bed of beads of dielectric material on said filter. The beads are periodically cleaned by backwashing to remove the accumulated solids.

  4. System for removing contaminants from plastic resin

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2010-11-23

    A resin recycling system that produces essentially contaminant-free synthetic resin material in an environmentally safe and economical manner. The system includes receiving the resin in container form. A grinder grinds the containers into resin particles. The particles are exposed to a solvent in one or more solvent wash vessels, the solvent contacting the resin particles and substantially removing contaminants on the resin particles. A separator is used to separate the resin particles and the solvent. The resin particles are then placed in solvent removing element where they are exposed to a solvent removing agent which removes any residual solvent remaining on the resin particles after separation.

  5. Turkey HEU Removal | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Turkey HEU Removal | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the...

  6. General Counsel Legal Interpretation Regarding Medical Removal...

    Energy Savers [EERE]

    Regarding Medical Removal Protection Benefits Pursuant to 10 CFR Part 850, Chronic Beryllium Disease Prevention Program General Counsel Legal Interpretation Regarding Medical...

  7. Slag capture and removal during laser cutting

    DOE Patents [OSTI]

    Brown, Clyde O. (Newington, CT)

    1984-05-08

    Molten metal removed from a workpiece in a laser cutting operation is blown away from the cutting point by a gas jet and collected on an electromagnet.

  8. Method of making thermally removable polymeric encapsulants

    SciTech Connect (OSTI)

    Small, James H. (Santa Fe, NM); Loy, Douglas A. (Albuquerque, NM); Wheeler, David R. (Albuquerque, NM); McElhanon, James R. (Albuquerque, NM); Saunders, Randall S. (late of Albuquerque, NM)

    2001-01-01

    A method of making a thermally-removable encapsulant by heating a mixture of at least one bis(maleimide) compound and at least one monomeric tris(furan) or tetrakis(furan) compound at temperatures from above room temperature to less than approximately 90.degree. C. to form a gel and cooling the gel to form the thermally-removable encapsulant. The encapsulant can be easily removed within approximately an hour by heating to temperatures greater than approximately 90.degree. C., preferably in a polar solvent. The encapsulant can be used in protecting electronic components that may require subsequent removal of the encapsulant for component repair, modification or quality control.

  9. Remedial action plan and site design for stabilization of the inactive uranium processing site at Naturita, Colorado. Remedial action selection report, Attachment 2, Geology report: Preliminary final

    SciTech Connect (OSTI)

    Not Available

    1993-08-01

    The uranium processing site near Naturita, Colorado, is one of 24 inactive uranium mill sites designated to be cleaned up by the US Department of Energy (DOE) under the Uranium Mill Tailings Radiation Control Act of 1978 (UMTRCA), Public Law 95-604. Part of the UMTRCA requires that the US Nuclear Regulatory Commission (NRC) concur with the DOE`s remedial action plan (RAP) and certify that the remedial action conducted at the site complies with the standards promulgated by the US Environmental Protection Agency (EPA). Included in the RAP is this Remedial Action Selection Report (RAS), which serves two purposes. First, it describes the activities that are proposed by the DOE to accomplish remediation and long-term stabilization and control of the radioactive materials at the inactive uranium processing site near Naturita, Colorado. Second, this document and the rest of the RAP, upon concurrence and execution by the DOE, the state of Colorado, and the NRC, become Appendix B of the cooperative agreement between the DOE and the State of Colorado.

  10. Chloride removal from vitrification offgas

    SciTech Connect (OSTI)

    Slaathaug, E.J. [Westinghouse Hanford Co., Richland, WA (United States)

    1995-06-01

    This study identified and investigated techniques of selectively purging chlorides from the low-level waste (LLW) vitrification process with the purge stream acceptable for burial on the Hanford Site. Chlorides will be present in high concentration in several individual feeds to the LLW Vitrification Plant. The chlorides are highly volatile in combustion type melters and are readily absorbed by wet scrubbing of the melter offgas. The Tank Waste Remediation System (TWRS) process flow sheets show that the resulting chloride rich scrub solution is recycled back to the melter. The chlorides must be purged from the recycle loop to prevent the buildup of excessively high chloride concentrations.

  11. Method of removing contaminants from plastic resins

    DOE Patents [OSTI]

    Bohnert,George W. (Harrisonville, MO); Hand,Thomas E. (Lee's Summit, MO); Delaurentiis,Gary M. (Jamestown, CA)

    2007-08-07

    A method for removing contaminants from synthetic resin material containers using a first organic solvent system and a second carbon dioxide system. The organic solvent is utilized for removing the contaminants from the synthetic resin material and the carbon dioxide is used to separate any residual organic solvent from the synthetic resin material.

  12. Method for removing contaminants from plastic resin

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2008-12-30

    A method for removing contaminants from synthetic resin material containers using a first organic solvent system and a second carbon dioxide system. The organic solvent is utilized for removing the contaminants from the synthetic resin material and the carbon dioxide is used to separate any residual organic solvent from the synthetic resin material.

  13. Method of removing contaminants from plastic resins

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2008-11-18

    A method for removing contaminants from synthetic resin material containers using a first organic solvent system and a second carbon dioxide system. The organic solvent is utilized for removing the contaminants from the synthetic resin material and the carbon dioxide is used to separate any residual organic solvent from the synthetic resin material.

  14. TABLE OF CONTENTS Tree Maintenance and Removal

    E-Print Network [OSTI]

    US Army Corps of Engineers

    protection should be worn for all tree maintenance and removal operations. b. Training shall be providedEM 385-1-1 30 Nov 14 31-i Section 31 TABLE OF CONTENTS Tree Maintenance and Removal Section: Page ....................................................................... 31-10 31.E Other Operations and Equipment

  15. Test Plan for the overburden removal demonstration

    SciTech Connect (OSTI)

    Rice, P.; Thompson, D.; Winberg, M.; Skaggs, J.

    1993-06-01

    The removal of soil overburdens from contaminated pits and trenches involves using equipment that will remove a small layer of soil from 3 to 6 in. at any time. As a layer of soil is removed, overburden characterization techniques perform surveys to a depth that exceeds each overburden removal layer to ensure that the removed soil will be free of contamination. It is generally expected that no contamination will be found in the soil overburden, which was brought in after the waste was put in place. It is anticipated that some containers in the waste zone have lost their integrity, and the waste leakage from those containers has migrated by gravity downward into the waste zone. To maintain a safe work environment, this method of overburden removal should allow safe preparation of a pit or trench for final remediation. To demonstrate the soil overburden techniques, the Buried Waste Integrated Demonstration Program has contracted vendor services to provide equipment and techniques demonstrating soil overburden removal technology. The demonstration will include tests that will evaluate equipment performance and techniques for removal of overburden soil, control of contamination spread, and dust control. To evaluate the performance of these techniques, air particulate samples, physical measurements of the excavation soil cuts, maneuverability measurements, and time versus volume (rate) of soil removal data will be collected during removal operations. To provide a medium for sample evaluation, the overburden will be spiked at specific locations and depths with rare earth tracers. This test plan will be describe the objectives of the demonstration, data quality objectives, methods to be used to operate the equipment and use the techniques in the test area, and methods to be used in collecting data during the demonstration.

  16. The washability of lignites for clay removal

    SciTech Connect (OSTI)

    Oteyaka, B.; Yamik, A.; Ucar, A.; Sahbaz, O.; Demir, U. [Dumlupinar University, Kutahya (Turkey). Dept. of Mining Engineering

    2008-07-01

    In the washability research of the Seyitomer Lignites (Kutahya-Turkey), with lower calorific value (1,863 kcal/kg) and high ash content (51.91%), by heavy medium separation, it was found out that middling clay in the coal had an effect to change the medium density. To prevent this problem, a trommel sieve with 18 and 5 mm aperture diameter was designed, and the clay in the coal was tried to be removed using it before the coal was released to heavy medium. Following that, the obtained coal in -100 + 18 mm and -18 + 5 mm fractions was subjected to sink and float test having 1.4 gcm{sup -3} and 1.7 gcm{sup -3} medium densities (-5 mm fraction will be evaluated in a separate work). Depending on the raw coal, with the floating of -100 + 18 mm and -18 + 5 mm size fraction in 1.4 gcm{sup -3} medium density, clean coal with 60.10% combustible matter recovery, 19.12% ash, and 3,150 kcal/kg was obtained. Also floating of the samples sinking in 1.4 gcm{sup -3} in the medium density (1.7 gcm{sup -3}), middling with 18.70% combustible matter recovery, 41.93% ash, 2,150 kcal/kg, and tailing having 78.31% ash were obtained.

  17. Removable bearing arrangement for a wind turbine generator

    DOE Patents [OSTI]

    Bagepalli, Bharat Sampathkumaran; Jansen, Patrick Lee; Gadre, Aniruddha Dattatraya

    2010-06-15

    A wind generator having removable change-out bearings includes a rotor and a stator, locking bolts configured to lock the rotor and stator, a removable bearing sub-assembly having at least one shrunk-on bearing installed, and removable mounting bolts configured to engage the bearing sub-assembly and to allow the removable bearing sub-assembly to be removed when the removable mounting bolts are removed.

  18. Method for changing removable bearing for a wind turbine generator

    DOE Patents [OSTI]

    Bagepalli, Bharat Sampathkumaran (Niskayuna, NY); Jansen, Patrick Lee (Scotia, NY), Gadre; Aniruddha Dattatraya (Rexford, NY)

    2008-04-22

    A wind generator having removable change-out bearings includes a rotor and a stator, locking bolts configured to lock the rotor and stator, a removable bearing sub-assembly having at least one shrunk-on bearing installed, and removable mounting bolts configured to engage the bearing sub-assembly and to allow the removable bearing sub-assembly to be removed when the removable mounting bolts are removed.

  19. Condensate Removal by Drain Orifice 

    E-Print Network [OSTI]

    Guzick, L. L.

    1979-01-01

    psig and 1200 psig. Based on the initial test results, a program was adopted by the U.S. Navy to replace all conventional steam traps with the Drain Orifice in all high pressure drain systems on ships in the U.S. Fleet....

  20. Summary of the engineering assessment of inactive uranium mill tailings: Phillips/United Nuclear site, Ambrosia Lake, New Mexico

    SciTech Connect (OSTI)

    none,

    1981-10-01

    Ford, Bacon and Davis Utah, Inc., has reevaluated the Phillips/United Nuclear site in order to revise the December 1977 engineering assessment of the problems resulting from the existence of radioactive uranium mill tailings at Ambrosia Lake, New Mexico. This engineering assessment has included the preparation of topographic maps, the performance of core drillings and radiometric maps, the performance of core drillings and radiometric measurements sufficient to determine areas and volumes of tailings and radiation exposures of individuals and nearby populations, the investigations of site hydrology and meteorology, and the evaluation and costing of alternative corrective actions. Radon gas released from the 2.6 million dry tons of tailings at the Phillips/United Nuclear site constitutes the most significant environmental impact, although windblown tailings and external gamma radiation also are factors. The four alternative actions presented in this engineering assessment range from millsite decontamination with the addition of 3 m of stabilization cover material, to removal of the tailings to remote disposal sites and decontamination of the tailings site. Cost estimates for the four options range from about $21,500,000 for stabilization in-place, to about $45,200,000 for disposal at a distance of about 15 mi. Three principal alternatives for the reprocessing of the Phillips/United Nuclear tailings were examined: heap leaching; treatment at an existing mill; reprocessing at a new conventional mill constructed for tailings reprocessing. The cost of the uranium recovered would be about $87/lb of U/sub 3/O/sub 8/ by either heap leach or conventional plant process. The spot market price for uranium was $25/lb early in 1981. Reprocessing the Phillips/United Nuclear tailings for uranium recovery does not appear to be economically attractive under present or foreseeable market conditions.

  1. In situ removal of contamination from soil

    DOE Patents [OSTI]

    Lindgren, Eric R. (Albuquerque, NM); Brady, Patrick V. (Albuquerque, NM)

    1997-01-01

    A process of remediation of cationic heavy metal contamination from soil utilizes gas phase manipulation to inhibit biodegradation of a chelating agent that is used in an electrokinesis process to remove the contamination, and further gas phase manipulation to stimulate biodegradation of the chelating agent after the contamination has been removed. The process ensures that the chelating agent is not attacked by bioorganisms in the soil prior to removal of the contamination, and that the chelating agent does not remain as a new contaminant after the process is completed.

  2. In situ removal of contamination from soil

    DOE Patents [OSTI]

    Lindgren, E.R.; Brady, P.V.

    1997-10-14

    A process of remediation of cationic heavy metal contamination from soil utilizes gas phase manipulation to inhibit biodegradation of a chelating agent that is used in an electrokinesis process to remove the contamination. The process also uses further gas phase manipulation to stimulate biodegradation of the chelating agent after the contamination has been removed. The process ensures that the chelating agent is not attacked by bioorganisms in the soil prior to removal of the contamination, and that the chelating agent does not remain as a new contaminant after the process is completed. 5 figs.

  3. Remedial Action Plan and site design for stabilization of the inactive uranium mill tailings site at Mexican Hat, Utah: Appendix E. Final report

    SciTech Connect (OSTI)

    NONE

    1988-07-01

    This document provides Appendix E of the Remedial Action Plan (RAP) presented in 1988 for the stabilization of the inactive uranium mill tailings at the Mexican Hat, Utah site. The RAP was developed to serve a two- fold purpose. It presents the activities proposed by the Department of Energy (DOE) to accomplish long-term stabilization and control of the residual radioactive materials (RRM) from Monument Valley, Arizona, and Mexican Hat, Utah, at the Mexican Hat disposal site. It also serves to document the concurrence of both the Navajo Nation and the Nuclear Regulatory Commission (NRC) in the remedial action. This agreement, upon execution by the DOE and the Navajo Nation and concurrence by the NRC, becomes Appendix B of the Cooperative Agreement. The RAP has been structured to provide a comprehensive understanding of the remedial action proposed for the Monument Valley and Mexican Hat sites. It includes specific design and construction requirements for the remedial action.

  4. Parametric Analyses of Heat Removal from High Level Waste Tanks

    SciTech Connect (OSTI)

    TRUITT, J.B.

    2000-06-05

    The general thermal hydraulics program GOTH-SNF was used to predict the thermal response of the waste in tanks 241-AY-102 and 241-AZ-102 when mixed by two 300 horsepower mixer pumps. This mixing was defined in terms of a specific waste retrieval scenario. Both dome and annulus ventilation system flow are necessary to maintain the waste within temperature control limits during the mixing operation and later during the sludge-settling portion of the scenario are defined.

  5. High Metal Removal Rate Process for Machining Difficult Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PolyPlus Battery Company has developed the protected lithium electrode (PLE), an invention that enables the use of lithium metal as an electrode in a secondary battery....

  6. High Metal Removal Rate Process for Machining Difficult Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for treating wastewater exist in a number of industries, including petroleum refining, pulp and paper, and chemical manufacturing. The sustainable low- energy approach to water...

  7. High Metal Removal Rate Process for Machining Difficult Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    technology (HSPT) (Completed). * Demonstrate targeted mechanical properties, including static tensile (yield strength: 950MPa and elongation of 13.1%), fracture toughness of K Ic...

  8. High Metal Removal Rate Process for Machining Difficult Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    tool, milling operations where the cutting tool rotates against the workpiece, and drilling operations where holes are produced or refined. However, traditional machining...

  9. Belgium Highly Enriched Uranium and Plutonium Removals | National...

    National Nuclear Security Administration (NNSA)

    This Site Budget IG Web Policy Privacy No Fear Act Accessibility FOIA Sitemap Federal Government The White House DOE.gov USA.gov Jobs Apply for Our Jobs Our Jobs Working at NNSA...

  10. Italy Highly Enriched Uranium and Plutonium Removals | National...

    National Nuclear Security Administration (NNSA)

    This Site Budget IG Web Policy Privacy No Fear Act Accessibility FOIA Sitemap Federal Government The White House DOE.gov USA.gov Jobs Apply for Our Jobs Our Jobs Working at NNSA...

  11. Belgium Highly Enriched Uranium and Plutonium Removals | National Nuclear

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouthReport for the t-) S/,,5 'a C | National NuclearLibrary

  12. Highly Radioactive Sludge Removal Complete: Historic Cleanup Effort Reduces

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancingR Walls - Building America Topathe Risk along the Columbia

  13. Italy Highly Enriched Uranium and Plutonium Removals | National Nuclear

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation CurrentHenryInhibitingInteractivePGAS andUniversityCancerFuelIt's

  14. Part removal of 3D printed parts

    E-Print Network [OSTI]

    Peña Doll, Mateo

    2014-01-01

    An experimental study was performed to understand the correlation between printing parameters in the FDM 3D printing process, and the force required to remove a part from the build platform of a 3D printing using a patent ...

  15. Method of removing polychlorinated biphenyl from oil

    DOE Patents [OSTI]

    Cook, Gus T. (Paducah, KY); Holshouser, Stephen K. (Boaz, KY); Coleman, Richard M. (Paducah, KY); Harless, Charles E. (Smithland, KY); Whinnery, III, Walter N. (Paducah, KY)

    1983-01-01

    Polychlorinated biphenyls are removed from oil by extracting the biphenyls into methanol. The mixture of methanol and extracted biphenyls is distilled to separate methanol therefrom, and the methanol is recycled for further use in extraction of biphenyls from oil.

  16. Method of removing polychlorinated biphenyl from oil

    DOE Patents [OSTI]

    Cook, G.T.; Holshouser, S.K.; Coleman, R.M.; Harless, C.E.; Whinnery, W.N. III

    1982-03-17

    Polychlorinated biphenyls are removed from oil by extracting the biphenyls into methanol. The mixture of methanol and extracted biphenyls is distilled to separate methanol therefrom, and the methanol is recycled for further use in extraction of biphenyls from oil.

  17. Ultrasound : an alternative solution for removing tattoos

    E-Print Network [OSTI]

    Teng, Jennifer

    2005-01-01

    The recent influx of tattoos has been accompanied by a rise in demand for tattoo removals. Due to the recent success of ultrasound as a noninvasive alternative for multiple medical therapies, the feasibility of ultrasound-mediated ...

  18. Advanced Water Removal via Membrane Solvent Extraction

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Water Removal via Membrane Solvent Extraction Reduction in energy and water use for the ethanol industry Ethanol is the leading biofuel in the U.S. with 13 Billion gallons produced...

  19. Method for removing RFI from SAR images

    DOE Patents [OSTI]

    Doerry, Armin W.

    2003-08-19

    A method of removing RFI from a SAR by comparing two SAR images on a pixel by pixel basis and selecting the pixel with the lower magnitude to form a composite image. One SAR image is the conventional image produced by the SAR. The other image is created from phase-history data which has been filtered to have the frequency bands containing the RFI removed.

  20. Laser removal of sludge from steam generators

    DOE Patents [OSTI]

    Nachbar, Henry D. (Ballston Lake, NY)

    1990-01-01

    A method of removing unwanted chemical deposits known as sludge from the metal surfaces of steam generators with laser energy is provided. Laser energy of a certain power density, of a critical wavelength and frequency, is intermittently focused on the sludge deposits to vaporize them so that the surfaces are cleaned without affecting the metal surface (sludge substrate). Fiberoptic tubes are utilized for laser beam transmission and beam direction. Fiberoptics are also utilized to monitor laser operation and sludge removal.

  1. Oil removal from water via adsorption 

    E-Print Network [OSTI]

    Jacobs, William Edward

    1973-01-01

    WILLIAM EDWARD JACOBS 1974 OIL REMOVAL FROM WATER VIA ADSORPTION A Thesis by WILLIAM EDWARD JACOBS Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE... December 1973 Major Subject: Civil Engineering OIL REMOVAL FROM WATER VIA ADSORPTION A Thesis by WILLIAM EDWARD JACOBS Approved as to style and content by: C airman of Committee ea o Department m er Member Memb December 1973 ABSTRACT Oil...

  2. Acid rain control strategists overlook dust removal benefits

    SciTech Connect (OSTI)

    Not Available

    1989-09-01

    Various strategies for controlling acid rain by reducing SO{sub 2} from existing utilities have failed to take into account the incidental particulate removal abilities of SO{sub 2} scrubbers. This has resulted in over-estimating the costs of acid rain control by 25% or more. This oversight has also caused utilities to invest in preliminary engineering of precipitator upgrades which will never have to be made if scrubbers are installed. While it seems inexplicable that a factor of this importance could have been overlooked by the industry, it is because of the unique situation in old U.S. utility power plants. These plants have relatively inefficient particulate control equipment which is not subject to new source performance standards. New power plants incorporate highly efficient particulate control devices so the ability of the downstream scrubbers to remove dust is irrelevant. The very small amount of particulate entering the scrubber from a highly efficient precipitator could be offset by escaping sulfate particles from a poorly operated scrubber. So an informal guideline was established to indicate that the scrubber had no overall effect on particulate emissions. The industry has generalized upon this guideline when, in fact, it only applies to new plants. The McIlvaine Company in its FGD Knowledge Network has thoroughly documented evidence that SO{sub 2} scrubbers will remove as much as 95% of the particulate being emitted from the relatively low efficiency precipitators operating on the nations existing coal-fired power plants.

  3. The CNG process: Acid gas removal with liquid carbon dioxide

    SciTech Connect (OSTI)

    Liu, Y.C.; Auyang, L.; Brown, W.R.

    1987-01-01

    The CNG acid gas removal process has two unique features: the absorption of sulfur-containing compounds and other trace contaminants with liquid carbon dioxide, and the regeneration of pure liquid carbon dioxide by triple-point crystallization. The process is especially suitable for treating gases which contain large amounts of carbon dioxide and much smaller amounts (relative to carbon dioxide) of hydrogen sulfide. Capital and energy costs are lower than conventional solvent processes. Further, products of the CNG process meet stringent purity specifications without undue cost penalties. A process demonstration unit has been constructed and operated to demonstrate the two key steps of the CNG process. Hydrogen sulfide and carbonyl sulfide removal from gas streams with liquid carbon dioxide absorbent to sub-ppm concentrations has been demonstrated. The production of highly purified liquid carbon dioxide (less than 0.1 ppm total contaminant) by triple-point crystallization also has been demonstrated.

  4. Development of Remove Sensing Instrumentation for NOx and PM...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of Remove Sensing Instrumentation for NOx and PM Emissions from Heavy Duty Trucks Development of Remove Sensing Instrumentation for NOx and PM Emissions from Heavy Duty...

  5. Oak Ridge Removes Laboratory's Greatest Source of Groundwater...

    Energy Savers [EERE]

    Removes Laboratory's Greatest Source of Groundwater Contamination Oak Ridge Removes Laboratory's Greatest Source of Groundwater Contamination May 1, 2012 - 12:00pm Addthis Workers...

  6. New Research Facility to Remove Hurdles to Offshore Wind and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research Facility to Remove Hurdles to Offshore Wind and Water Power Development New Research Facility to Remove Hurdles to Offshore Wind and Water Power Development January 10,...

  7. Evaluation of Passive and Active Soot Filters for Removal of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Passive and Active Soot Filters for Removal of Particulate Emissions from Diesel Engines Evaluation of Passive and Active Soot Filters for Removal of Particulate Emissions from...

  8. Self-propelled sweeping removal of dropwise condensate (Journal...

    Office of Scientific and Technical Information (OSTI)

    Self-propelled sweeping removal of dropwise condensate Citation Details In-Document Search Title: Self-propelled sweeping removal of dropwise condensate Authors: Qu, Xiaopeng 1 ;...

  9. Remedial action plan for the inactive uranium processing site at Naturita, Colorado. DOE responses to comments from U.S. Nuclear Regulatory Commission and Colorado Department of Public Health and Environment

    SciTech Connect (OSTI)

    NONE

    1998-11-16

    This report contains responses by the US Department of Energy to comments from the US Nuclear Regulatory Commission and the Colorado Department of Public Health and Environment on the Naturita remedial action plan. This was done in an attempt to clarify information. The site is an inactive uranium processing site at Naturita, Colorado.

  10. Perchlorate ion (C104) removal using an electrochemically induced catalytic reaction on modified activated carbon 

    E-Print Network [OSTI]

    Langille, Meredith Caitlyn

    2009-05-15

    to remove perchlorate ion. Bioremediation has been used to remove perchlorate, generally with the addition of acetate and hydrogen as electron donors. Phytoremediation with plants like smartweed, watercress and the trees chinaberry, elm, willow, mulberry... treatment processes to chemically reduce (a transfer of electrons) perchlorate ion cannot do so effectively due to a high activation energy barrier. This unique energy barrier and electron transfer process is called the bridged electron transfer (6, 7, 8...

  11. Sodium removal process development for LMFBR fuel subassemblies

    SciTech Connect (OSTI)

    Simmons, C.R.; Taylor, G.R.

    1981-10-01

    Two 37-pin scale models of Clinch River Breeder Reactor Plant fuel subassemblies were designed, fabricated and used at Westinghouse Advanced Reactors Division in the development and proof-testing of a rapid water-based sodium removal process for the ORNL Hot Experimental Facility, Liquid Metal Fast Breeder Reactor Fuel Reprocessing Cycle. Through a series of development tests on one of the models, including five (5) sodium wettings and three (3) high temperature sodium removal operations, optimum process parameters for a rapid water vapor-argon-water rinse process were identified and successfully proof-tested on a second model containing argon-pressurized, sodium-corroded model fuel pins simulating the gas plenum and cladding conditions expected for spent fuel pins in full scale subassemblies. Based on extrapolations of model proof test data, preliminary process parameters for a water vapor-nitrogen-water rinse process were calculated and recommended for use in processing full scale fuel subassemblies in the Sodium Removal Facility of the Fuel Receiving Cell, ORNL HEF.

  12. BOA: Pipe-asbestos insulation removal robot system

    SciTech Connect (OSTI)

    Schempf, H.; Bares, J.; Mutschler, E. [and others

    1995-12-31

    This paper describes the BOA system, a mobile pipe-external crawler used to remotely strip and bag (possibly contaminated) asbestos-containing lagging and insulation materials (ACLIM) from various diameter pipes in (primarily) industrial installations across the DOE weapons complex. The mechanical removal of ACLIM is very cost-effective due to the relatively low productivity and high cost involved in human removal scenarios. BOA, a mechanical system capable of removing most forms of lagging (paper, plaster, aluminum sheet, clamps, screws and chicken-wire), and insulation (paper, tar, asbestos fiber, mag-block) uses a circular cutter and compression paddles to cut and strip the insulation off the pipe through compression, while a HEPA-filter and encapsulant system maintain a certifiable vacuum and moisture content inside the system and on the pipe, respectively. The crawler system has been built and is currently undergoing testing. Key design parameters and performance parameters are developed and used in performance testing. Since the current system is a testbed, we also discuss future enhancements and outline two deployment scenarios (robotic and manual) for the final system to be designed and completed by the end of FY `95. An on-site demonstration is currently planned for Fernald in Ohio and Oak Ridge in Tennessee.

  13. Sulfur removal from diesel fuel-contaminated methanol.

    SciTech Connect (OSTI)

    Lee, S. H. D.; Kumar, R.; Krumpelt, M.; Chemical Engineering

    2002-03-01

    Methanol is considered to be a potential on-board fuel for fuel cell-powered vehicles. In current distribution systems for liquid fuels used in the transportation sector, commodity methanol can occasionally become contaminated with the sulfur in diesel fuel or gasoline. This sulfur would poison the catalytic materials used in fuel reformers for fuel cells. We tested the removal of this sulfur by means of ten activated carbons (AC) that are commercially available. Tests were conducted with methanol doped with 1 vol.% grade D-2 diesel fuel containing 0.29% sulfur, which was present essentially as 33-35 wt.% benzothiophenes (BTs) and 65-67 wt.% dibenzothiophenes (DBT). In general, coconut shell-based carbons activated by high-temperature steam were more effective at sulfur removal than coal-based carbons. Equilibrium sorption data showed linear increase in sulfur capture with the increase of sulfur concentration in methanol. Both types of carbons had similar breakthrough characteristics, with the dynamic sorption capacity of each being about one-third of its equilibrium sorption capacity. Results of this study suggest that a fixed-bed sorber of granular AC can be used, such as in refueling stations, for the removal of sulfur in diesel fuel-contaminated methanol.

  14. Preliminary Evaluation of Removing Used Nuclear Fuel from Shutdown Sites

    SciTech Connect (OSTI)

    Maheras, Steven J.; Best, Ralph E.; Ross, Steven B.; Buxton, Kenneth A.; England, Jeffery L.; McConnell, Paul E.

    2013-09-30

    This report fulfills the M2 milestone M2FT-13PN0912022, “Stranded Sites De-Inventorying Report.” In January 2013, the U.S. Department of Energy (DOE) issued the Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level Radioactive Waste (DOE 2013). Among the elements contained in this strategy is an initial focus on accepting used nuclear fuel from shutdown reactor sites. This focus is consistent with the recommendations of the Blue Ribbon Commission on America’s Nuclear Future, which identified removal of stranded used nuclear fuel at shutdown sites as a priority so that these sites may be completely decommissioned and put to other beneficial uses (BRC 2012). Shutdown sites are defined as those commercial nuclear power reactor sites where the nuclear power reactors have been shut down and the site has been decommissioned or is undergoing decommissioning. In this report, a preliminary evaluation of removing used nuclear fuel from 12 shutdown sites was conducted. The shutdown sites were Maine Yankee, Yankee Rowe, Connecticut Yankee, Humboldt Bay, Big Rock Point, Rancho Seco, Trojan, La Crosse, Zion, Crystal River, Kewaunee, and San Onofre. These sites have no other operating nuclear power reactors at their sites and have also notified the U.S. Nuclear Regulatory Commission that their reactors have permanently ceased power operations and that nuclear fuel has been permanently removed from their reactor vessels. Shutdown reactors at sites having other operating reactors are not included in this evaluation.

  15. System for removal of arsenic from water

    DOE Patents [OSTI]

    Moore, Robert C.; Anderson, D. Richard

    2004-11-23

    Systems for removing arsenic from water by addition of inexpensive and commonly available magnesium oxide, magnesium hydroxide, calcium oxide, or calcium hydroxide to the water. The hydroxide has a strong chemical affinity for arsenic and rapidly adsorbs arsenic, even in the presence of carbonate in the water. Simple and commercially available mechanical systems for removal of magnesium hydroxide particles with adsorbed arsenic from drinking water can be used, including filtration, dissolved air flotation, vortex separation, or centrifugal separation. A system for continuous removal of arsenic from water is provided. Also provided is a system for concentrating arsenic in a water sample to facilitate quantification of arsenic, by means of magnesium or calcium hydroxide adsorption.

  16. Technetium Removal Using Tc-Goethite Coprecipitation

    SciTech Connect (OSTI)

    Um, Wooyong; Wang, Guohui; Jung, Hun Bok; Peterson, Reid A.

    2013-11-18

    This report describes the results from laboratory tests performed at Pacific Northwest National Laboratory for the U.S. Department of Energy (DOE) EM-31 Support Program (EMSP) subtask, “Low temperature waste forms coupled with technetium removal using an alternative immobilization process such as Fe(II) treated-goethite precipitation” to increase our understanding of 99Tc long-term stability in goethite mineral form and the process that controls the 99Tc(VII) reduction and removal by the final Fe (oxy)hydroxide forms. The overall objectives of this task were to 1) evaluate the transformation process of Fe (oxy)hydroxide solids to the more crystalline goethite (?-FeOOH) mineral for 99Tc removal and 2) determine the mechanism that limits 99Tc(IV) reoxidation in Fe(II)-treated 99Tc-goethite mineral and 3) evaluate whether there is a long-term 99Tcoxidation state change for Tc sequestered in the iron solids.

  17. Properly engineer lead paint removal projects

    SciTech Connect (OSTI)

    Kaelin, A.B.

    1996-01-01

    Deciding how to mitigate the hazards during lead paint removal is complex and requires consideration of many variables. Assessment of public health risk, environmental impact, and emissions potential of the operations must be considered. Additionally, the removal technique, containment system, and monitoring criteria must be developed. This article presents an integrated approach to identifying lead hazards, assessing risks to workers, the environment, and the public, developing the appropriate maintenance strategy, and selecting paint removal and containment systems. Also considered are guidelines for selecting a third party to design the overall project. This approach is based on a decision path that provides criteria for project assessment in an orderly fashion. The design of lead paint management projects in industrial applications requires consideration of the variables shown in the decision path.

  18. Method of making thermally removable polyurethanes

    SciTech Connect (OSTI)

    Loy, Douglas A. (Albuquerque, NM); Wheeler, David R. (Albuquerque, NM); McElhanon, James R. (Livermore, CA); Saunders, Randall S. (late of Albuquerque, NM); Durbin-Voss, Marvie Lou (Albuquerque, NM)

    2002-01-01

    A method of making a thermally-removable polyurethane material by heating a mixture of a maleimide compound and a furan compound, and introducing alcohol and isocyanate functional groups, where the alcohol group and the isocyanate group reacts to form the urethane linkages and the furan compound and the maleimide compound react to form the thermally weak Diels-Alder adducts that are incorporated into the backbone of the urethane linkages during the formation of the polyurethane material at temperatures from above room temperature to less than approximately 90.degree. C. The polyurethane material can be easily removed within approximately an hour by heating to temperatures greater than approximately 90.degree. C. in a polar solvent. The polyurethane material can be used in protecting electronic components that may require subsequent removal of the solid material for component repair, modification or quality control.

  19. Arsenic removal in conjunction with lime softening

    DOE Patents [OSTI]

    Khandaker, Nadim R.; Brady, Patrick V.; Teter, David M.; Krumhansl, James L.

    2004-10-12

    A method for removing dissolved arsenic from an aqueous medium comprising adding lime to the aqueous medium, and adding one or more sources of divalent metal ions other than calcium and magnesium to the aqueous medium, whereby dissolved arsenic in the aqueous medium is reduced to a lower level than possible if only the step of adding lime were performed. Also a composition of matter for removing dissolved arsenic from an aqueous medium comprising lime and one or more sources of divalent copper and/or zinc metal ions.

  20. Sorbents for mercury removal from flue gas

    SciTech Connect (OSTI)

    Granite, Evan J.; Hargis, Richard A.; Pennline, Henry W.

    1998-01-01

    A review of the various promoters and sorbents examined for the removal of mercury from flue gas is presented. Commercial sorbent processes are described along with the chemistry of the various sorbent-mercury interactions. Novel sorbents for removing mercury from flue gas are suggested. Since activated carbons are expensive, alternate sorbents and/or improved activated carbons are needed. Because of their lower cost, sorbent development work can focus on base metal oxides and halides. Additionally, the long-term sequestration of the mercury on the sorbent needs to be addressed. Contacting methods between the flue gas and the sorbent also merit investigation.

  1. Process for removing metals from water

    DOE Patents [OSTI]

    Napier, J.M.; Hancher, C.M.; Hackett, G.D.

    1987-06-29

    A process for removing metals from water including the steps of prefiltering solids from the water, adjusting the pH to between about 2 and 3, reducing the amount of dissolved oxygen in the water, increasing the pH to between about 6 and 8, adding water-soluble sulfide to precipitate insoluble sulfide- and hydroxide-forming metals, adding a containing floc, and postfiltering the resultant solution. The postfiltered solution may optionally be eluted through an ion exchange resin to remove residual metal ions. 2 tabs.

  2. Method of making thermally removable adhesives

    DOE Patents [OSTI]

    Aubert, James H.

    2004-11-30

    A method of making a thermally-removable adhesive is provided where a bismaleimide compound, a monomeric furan compound, containing an oxirane group an amine curative are mixed together at an elevated temperature of greater than approximately 90.degree. C. to form a homogeneous solution, which, when cooled to less than approximately 70.degree. C., simultaneously initiates a Diels-Alder reaction between the furan and the bismaleimide and a epoxy curing reaction between the amine curative and the oxirane group to form a thermally-removable adhesive. Subsequent heating to a temperature greater than approximately 100.degree. C. causes the adhesive to melt and allows separation of adhered pieces.

  3. Greener Solvent Selection and Solvent Recycling for CO2 Capture Economically removing CO2 from the flue gases of coal-fired power plants would alleviate concerns

    E-Print Network [OSTI]

    Ben-Arie, Jezekiel

    to remove CO2 from dilute gas streams because they have very high affinity for CO2. Unfortunately high solvents that balance high affinity for CO2 with ease of solvent recovery and reuse. Because the numberGreener Solvent Selection and Solvent Recycling for CO2 Capture Economically removing CO2 from

  4. Method of dye removal for the textile industry

    DOE Patents [OSTI]

    Stone, Mark L. (Idaho Falls, ID)

    2000-01-01

    The invention comprises a method of processing a waste stream containing dyes, such as a dye bath used in the textile industry. The invention comprises using an inorganic-based polymer, such as polyphosphazene, to separate dyes and/or other chemicals from the waste stream. Membranes comprising polyphosphazene have the chemical and thermal stability to survive the harsh, high temperature environment of dye waste streams, and have been shown to completely separate dyes from the waste stream. Several polyphosplhazene membranes having a variety of organic substituent have been shown effective in removing color from waste streams.

  5. Butyl acetate replaces toluene to remove phenol from water

    SciTech Connect (OSTI)

    Hodel, A.E.

    1993-03-01

    Plastics Engineering Co. manufactures phenol formaldehyde resins and molding compounds at a plant in Sheboygan, WI. Process water from the plant, containing 7% phenol and 1% methanol, requires treatment prior to discharge to the sewer. Toluene was used as a solvent in a countercurrent liquid-liquid extraction column. A vacuum distillation of the extract separated the phenol and toluene. The raffinate (1% methanol, 98% water and 1% toluene) was stripped to recover the toluene and remove methanol from the bottoms prior to discharge. Methanol was not recovered. Disposal costs for the waste methanol (with about 10% toluene as an azeotrope) were high.

  6. Removal of sulfur and nitrogen containing pollutants from discharge gases

    DOE Patents [OSTI]

    Joubert, James I. (Pittsburgh, PA)

    1986-01-01

    Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

  7. THE STRUCTURAL CHEMISTRY OF MOLYBDENUM IN MODEL HIGH LEVEL NUCLEAR WASTE GLASSES, INVESTIGATED BY MO K-EDGE X-RAY ABSORPTION

    E-Print Network [OSTI]

    Sheffield, University of

    THE STRUCTURAL CHEMISTRY OF MOLYBDENUM IN MODEL HIGH LEVEL NUCLEAR WASTE GLASSES, INVESTIGATED of molybdenum in model UK high level nuclear waste glasses was investigated by X-ray Absorption Spectroscopy (XAS). Molybdenum K-edge XAS data were acquired from several inactive simulant high level nuclear waste

  8. Recommendation 183: Preferred Alternative for the Removal of Hexavalent Chromium

    Broader source: Energy.gov [DOE]

    The ORSSAB Recommendation to DOE on the Preferred Alternative for the Removal of Hexavalent Chromium.

  9. Pentek metal coating removal system: Baseline report

    SciTech Connect (OSTI)

    1997-07-31

    The Pentek coating removal technology was tested and is being evaluated at Florida International University (FIU) as a baseline technology. In conjunction with FIU`s evaluation of efficiency and cost, this report covers evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The Pentek coating removal system consisted of the ROTO-PEEN Scaler, CORNER-CUTTER{reg_sign}, and VAC-PAC{reg_sign}. They are designed to remove coatings from steel, concrete, brick, and wood. The Scaler uses 3M Roto Peen tungsten carbide cutters while the CORNER-CUTTER{reg_sign} uses solid needles for descaling activities. These hand tools are used with the VAC-PAC{reg_sign} vacuum system to capture dust and debris as removal of the coating takes place. The safety and health evaluation during the testing demonstration focused on two main areas of exposure: dust and noise. Dust exposure minimal, but noise exposure was significant. Further testing for each exposure is recommended because of the environment where the testing demonstration took place. It is feasible that the dust and noise levels will be higher in an enclosed operating environment of different construction. In addition, other areas of concern found were arm-hand vibration, whole-body, ergonomics, heat stress, tripping hazards, electrical hazards, machine guarding, and lockout/tagout.

  10. Tank waste remediation system compensatory measure removal

    SciTech Connect (OSTI)

    MILLIKEN, N.J.

    1999-05-18

    In support of Fiscal Year 1998 Performance Agreement TWR1.4.3, ''Replace Compensatory Measures,'' the Tank Waste Remediation System is documenting the completion of field modifications supporting the removal of the temporary exemptions from the approved Tank Waste Remediation System Technical Safety Requirements (TSRs), HNF-SD-WM-TSR-006. These temporary exemptions or compensatory measures expire September 30, 1998.

  11. The Scottish Government's Policy on Woodland Removal

    E-Print Network [OSTI]

    significant woodland removal associated with landscape design, restoration of priority habitats, wind farms associated with the internal re-design of woodlands to meet the UK Forestry Standard. #12;4 | Control comprises 18% of the world's greenhouse gas emissions (compared to 25% from electricity and heat generation

  12. Forecast Technical Document Felling and Removals

    E-Print Network [OSTI]

    of local investment and business planning. Timber volume production will be estimated at sub. Planning of operations. Control of the growing stock. Wider reporting (under UKWAS). The calculation fellings and removals are handled in the 2011 Production Forecast system. Tom Jenkins Robert Matthews Ewan

  13. Method of preparation of removable syntactic foam

    DOE Patents [OSTI]

    Arnold, Jr., Charles (Albuquerque, NM); Derzon, Dora K. (Albuquerque, NM); Nelson, Jill S. (Albuquerque, NM); Rand, Peter B. (Albuquerque, NM)

    1995-01-01

    Easily removable, environmentally safe, low-density, syntactic foams are disclosed which are prepared by mixing insoluble microballoons with a solution of water and/or alcohol-soluble polymer to produce a pourable slurry, optionally vacuum filtering the slurry in varying degrees to remove unwanted solvent and solute polymer, and drying to remove residual solvent. The properties of the foams can be controlled by the concentration and physical properties of the polymer, and by the size and properties of the microballoons. The suggested solute polymers are non-toxic and soluble in environmentally safe solvents such as water or low-molecular weight alcohols. The syntactic foams produced by this process are particularly useful in those applications where ease of removability is beneficial, and could find use in packaging recoverable electronic components, in drilling and mining applications, in building trades, in art works, in the entertainment industry for special effects, in manufacturing as temporary fixtures, in agriculture as temporary supports and containers and for delivery of fertilizer, in medicine as casts and splints, as temporary thermal barriers, as temporary protective covers for fragile objects, as filters for particulate matter, which matter may be easily recovered upon exposure to a solvent, as in-situ valves (for one-time use) which go from maximum to minimum impedance when solvent flows through, and for the automatic opening or closing of spring-loaded, mechanical switches upon exposure to a solvent, among other applications.

  14. Method of preparation of removable syntactic foam

    DOE Patents [OSTI]

    Arnold, C. Jr.; Derzon, D.K.; Nelson, J.S.; Rand, P.B.

    1995-07-11

    Easily removable, environmentally safe, low-density, syntactic foams are disclosed which are prepared by mixing insoluble microballoons with a solution of water and/or alcohol-soluble polymer to produce a pourable slurry, optionally vacuum filtering the slurry in varying degrees to remove unwanted solvent and solute polymer, and drying to remove residual solvent. The properties of the foams can be controlled by the concentration and physical properties of the polymer, and by the size and properties of the microballoons. The suggested solute polymers are non-toxic and soluble in environmentally safe solvents such as water or low-molecular weight alcohols. The syntactic foams produced by this process are particularly useful in those applications where ease of removability is beneficial, and could find use in packaging recoverable electronic components, in drilling and mining applications, in building trades, in art works, in the entertainment industry for special effects, in manufacturing as temporary fixtures, in agriculture as temporary supports and containers and for delivery of fertilizer, in medicine as casts and splints, as temporary thermal barriers, as temporary protective covers for fragile objects, as filters for particulate matter, which matter may be easily recovered upon exposure to a solvent, as in-situ valves (for one-time use) which go from maximum to minimum impedance when solvent flows through, and for the automatic opening or closing of spring-loaded, mechanical switches upon exposure to a solvent, among other applications. 1 fig.

  15. Commercial Submersible Mixing Pump For SRS Tank Waste Removal - 15223

    SciTech Connect (OSTI)

    Hubbard, M.

    2015-01-12

    The Savannah River Site Tank Farms have 45 active underground waste tanks used to store and process nuclear waste materials. There are 4 different tank types, ranging in capacity from 2839 m3 to 4921 m3 (750,000 to 1,300,000 gallons). Eighteen of the tanks are older style and do not meet all current federal standards for secondary containment. The older style tanks are the initial focus of waste removal efforts for tank closure and are referred to as closure tanks. Of the original 51 underground waste tanks, six of the original 24 older style tanks have completed waste removal and are filled with grout. The insoluble waste fraction that resides within most waste tanks at SRS requires vigorous agitation to suspend the solids within the waste liquid in order to transfer this material for eventual processing into glass filled canisters at the Defense Waste Processing Facility (DWPF). SRS suspends the solid waste by use of recirculating mixing pumps. Older style tanks generally have limited riser openings which will not support larger mixing pumps, since the riser access is typically 58.4 cm (23 inches) in diameter. Agitation for these tanks has been provided by four long shafted standard slurry pumps (SLP) powered by an above tank 112KW (150 HP) electric motor. The pump shaft is lubricated and cooled in a pressurized water column that is sealed from the surrounding waste in the tank. Closure of four waste tanks has been accomplished utilizing long shafted pump technology combined with heel removal using multiple technologies. Newer style waste tanks at SRS have larger riser openings, allowing the processing of waste solids to be accomplished with four large diameter SLPs equipped with 224KW (300 HP) motors. These tanks are used to process the waste from closure tanks for DWPF. In addition to the SLPs, a 224KW (300 HP) submersible mixer pump (SMP) has also been developed and deployed within older style tanks. The SMPs are product cooled and product lubricated canned motor pumps designed to fit within available risers and have significant agitation capabilities to suspend waste solids. Waste removal and closure of two tanks has been accomplished with agitation provided by 3 SMPs installed within the tanks. In 2012, a team was assembled to investigate alternative solids removal technologies to support waste removal for closing tanks. The goal of the team was to find a more cost effective approach that could be used to replace the current mixing pump technology. This team was unable to identify an alternative technology outside of mixing pumps to support waste agitation and removal from SRS waste tanks. However, the team did identify a potentially lower cost mixing pump compared to the baseline SLPs and SMPs. Rather than using the traditional procurement using an engineering specification, the team proposed to seek commercially available submersible mixer pumps (CSMP) as alternatives to SLPs and SMPs. SLPs and SMPs have a high procurement cost and the actual cost of moving pumps between tanks has shown to be significantly higher than the original estimates that justified the reuse of SMPs and SLPs. The team recommended procurement of “off-the-shelf” industry pumps which may be available for significant savings, but at an increased risk of failure and reduced operating life in the waste tank. The goal of the CSMP program is to obtain mixing pumps that could mix from bulk waste removal through tank closure and then be abandoned in place as part of tank closure. This paper will present the development, progress and relative advantages of the CSMP.

  16. Removal of Pertechnetate from Simulated Nuclear Waste Streams Using Supported Zerovalent Iron

    E-Print Network [OSTI]

    -stable, nanocrystalline zirconia was used as a support for nanoiron for tests with highly alkaline solutions, while of contact time, the high surface area zirconia supported nanoiron sorbent removed about 50% (Kd ) 370 L, it was demonstrated that a mixture of 20 mass % of the solid reaction products obtained from contacting zirconia

  17. Removal of Mercury from Wastewater by Nanoparticle Pyrite (FeS2) and Ultrafiltration (UF) Membrane System 

    E-Print Network [OSTI]

    Kawsher, Md Solayman

    2015-07-27

    This research investigated the removal of mercury by Reactive Adsorbent Membrane (RAM) hybrid filtration process to attain high quality water from wastewater or water resources contaminated with Hg(II), while producing stable final residuals. Pyrite...

  18. Low-quality natural gas sulfur removal/recovery

    SciTech Connect (OSTI)

    K. Amo; R.W. Baker; V.D. Helm; T. Hofmann; K.A. Lokhandwala; I. Pinnau; M.B. Ringer; T.T. Su; L. Toy; J.G. Wijmans

    1998-01-29

    A significant fraction of U.S. natural gas reserves are subquality due to the presence of acid gases and nitrogen; 13% of existing reserves (19 trillion cubic feed) may be contaminated with hydrogen sulfide. For natural gas to be useful as fuel and feedstock, this hydrogen sulfide has to be removed to the pipeline specification of 4 ppm. The technology used to achieve these specifications has been amine, or similar chemical or physical solvent, absorption. Although mature and widely used in the gas industry, absorption processes are capital and energy-intensive and require constant supervision for proper operation. This makes these processes unsuitable for treating gas at low throughput, in remote locations, or with a high concentration of acid gases. The U.S. Department of Energy, recognizes that exploitation of smaller, more sub-quality resources will be necessary to meet demand as the large gas fields in the U.S. are depleted. In response to this need, Membrane Technology and Research, Inc. (MTR) has developed membranes and a membrane process for removing hydrogen sulfide from natural gas. During this project, high-performance polymeric thin-film composite membranes were brought from the research stage to field testing. The membranes have hydrogen sulfide/methane selectivities in the range 35 to 60, depending on the feed conditions, and have been scaled up to commercial-scale production. A large number of spiral-wound modules were manufactured, tested and optimized during this project, which culminated in a field test at a Shell facility in East Texas. The short field test showed that membrane module performance on an actual natural gas stream was close to that observed in the laboratory tests with cleaner streams. An extensive technical and economic analysis was performed to determine the best applications for the membrane process. Two areas were identified: the low-flow-rate, high-hydrogen-sulfide-content region and the high-flow-rate, high-hydrogen-sulfide-content region. In both regions the MTR membrane process will be combined with another process to provide the necessary hydrogen sulfide removal from the natural gas. In the first region the membrane process will be combined with the SulfaTreat fixed-bed absorption process, and in the second region the membrane process will be combined with a conventional absorption process. Economic analyses indicate that these hybrid processes provide 20-40% cost savings over stand-alone absorption technologies.

  19. Photoacoustic removal of occlusions from blood vessels

    DOE Patents [OSTI]

    Visuri, Steven R. (Livermore, CA); Da Silva, Luiz B. (Danville, CA); Celliers, Peter M. (Berkeley, CA); London, Richard A. (Orinda, CA); Maitland, IV, Duncan J. (Lafayette, CA); Esch, Victor C. (San Francisco, CA)

    2002-01-01

    Partial or total occlusions of fluid passages within the human body are removed by positioning an array of optical fibers in the passage and directing treatment radiation pulses along the fibers, one at a time, to generate a shock wave and hydrodynamics flows that strike and emulsify the occlusions. A preferred application is the removal of blood clots (thrombin and embolic) from small cerebral vessels to reverse the effects of an ischemic stroke. The operating parameters and techniques are chosen to minimize the amount of heating of the fragile cerebral vessel walls occurring during this photo acoustic treatment. One such technique is the optical monitoring of the existence of hydrodynamics flow generating vapor bubbles when they are expected to occur and stopping the heat generating pulses propagated along an optical fiber that is not generating such bubbles.

  20. IMPROVED PROCESSES TO REMOVE NAPHTHENIC ACIDS

    SciTech Connect (OSTI)

    Aihua Zhang; Qisheng Ma; Kangshi Wang, William A. Goddard, Yongchun Tang

    2005-05-05

    In the second year of this project, we continued our effort to develop low temperature decarboxylation catalysts and investigate the behavior of these catalysts at different reaction conditions. We conducted a large number of dynamic measurements with crude oil and model compounds to obtain the information at different reaction stages, which was scheduled as the Task2 in our work plan. We developed a novel adsorption method to remove naphthenic acid from crude oil using naturally occurring materials such as clays. Our results show promise as an industrial application. The theoretical modeling proposed several possible reaction pathways and predicted the reactivity depending on the catalysts employed. From all of these studies, we obtained more comprehensive understanding about catalytic decarboxylation and oil upgrading based on the naphthenic acid removal concept.

  1. Removal of mercury from waste gases

    SciTech Connect (OSTI)

    Muster, U.; Marr, R.; Pichler, G.; Kremshofer, S.; Wilferl, R.; Draxler, J.

    1996-12-31

    Waste and process gases from thermal power, incineration and metallurgical plants or those from cement and alkali chloride industries contain metallic, inorganic and organic mercury. Widespread processes to remove the major amount of mercury are absorption and adsorption. Caused by the lowering of the emission limit from 200 to 50 {mu}g/m{sup 3} [STP] by national and European legislators, considerable efforts were made to enhance the efficiency of the main separation units of flue gas cleaning plants. Specially impregnated ceramic carriers can be used for the selective separation of metallic, inorganic and organic mercury. Using the ceramic reactor removal rates lower than 5 {mu}g/m{sup 3} [STP] of gaseous mercury and its compounds can be achieved. The ceramic reactor is active, regenerable and stable for a long term operation. 4 refs., 7 figs.

  2. Metathesis depolymerization for removable surfactant templates.

    SciTech Connect (OSTI)

    Zifer, Thomas (Sandia National Laboratories, Livermore, CA); Wheeler, David Roger; Rahimian, Kamayar; McElhanon, James Ross (Sandia National Laboratories, Livermore, CA); Long, Timothy Michael; Jamison, Gregory Marks; Loy, Douglas Anson (Los Alamos National Laboratories, Los Alamos, NM); Kline, Steven R. (National Institute of Standards and Technology, Gaithersburg, MD); Simmons, Blake Alexander (Sandia National Laboratories, Livermore, CA)

    2005-03-01

    Current methodologies for the production of meso- and nanoporous materials include the use of a surfactant to produce a self-assembled template around which the material is formed. However, post-production surfactant removal often requires centrifugation, calcination, and/or solvent washing which can damage the initially formed material architecture(s). Surfactants that can be disassembled into easily removable fragments following material preparation would minimize processing damage to the material structure, facilitating formation of templated hybrid architectures. Herein, we describe the design and synthesis of novel cationic and anionic surfactants with regularly spaced unsaturation in their hydrophobic hydrocarbon tails and the first application of ring closing metathesis depolymerization to surfactant degradation resulting in the mild, facile decomposition of these new compounds to produce relatively volatile nonsurface active remnants.

  3. Removal of copper from ferrous scrap

    DOE Patents [OSTI]

    Blander, M.; Sinha, S.N.

    1987-07-30

    A process for removing copper from ferrous or other metal scrap in which the scrap is contacted with a polyvalent metal sulfide slag in the presence of an excess of copper-sulfide forming additive to convert the copper to copper sulfide which is extracted into the slag to provide a ratio of copper in the slag to copper in the metal scrap of at least about 10.

  4. REMOVAL OF LEGACY PLUTONIUM MATERIALS FROM SWEDEN

    SciTech Connect (OSTI)

    Dunn, Kerry A.; Bellamy, J. Steve; Chandler, Greg T.; Iyer, Natraj C.; Koenig, Rich E.; Leduc, D.; Hackney, B.; Leduc, Dan R.

    2013-08-18

    U.S. Department of Energy’s National Nuclear Security Administration (NNSA) Office of Global Threat Reduction (GTRI) recently removed legacy plutonium materials from Sweden in collaboration with AB SVAFO, Sweden. This paper details the activities undertaken through the U.S. receiving site (Savannah River Site (SRS)) to support the characterization, stabilization, packaging and removal of legacy plutonium materials from Sweden in 2012. This effort was undertaken as part of GTRI’s Gap Materials Program and culminated with the successful removal of plutonium from Sweden as announced at the 2012 Nuclear Security Summit. The removal and shipment of plutonium materials to the United States was the first of its kind under NNSA’s Global Threat Reduction Initiative. The Environmental Assessment for the U.S. receipt of gap plutonium material was approved in May 2010. Since then, the multi-year process yielded many first time accomplishments associated with plutonium packaging and transport activities including the application of the of DOE-STD-3013 stabilization requirements to treat plutonium materials outside the U.S., the development of an acceptance criteria for receipt of plutonium from a foreign country, the development and application of a versatile process flow sheet for the packaging of legacy plutonium materials, the identification of a plutonium container configuration, the first international certificate validation of the 9975 shipping package and the first intercontinental shipment using the 9975 shipping package. This paper will detail the technical considerations in developing the packaging process flow sheet, defining the key elements of the flow sheet and its implementation, determining the criteria used in the selection of the transport package, developing the technical basis for the package certificate amendment and the reviews with multiple licensing authorities and most importantly integrating the technical activities with the Swedish partners.

  5. Removal of copper from ferrous scrap

    DOE Patents [OSTI]

    Blander, Milton (12833 S. 82nd Ct., Palos Park, IL 60464); Sinha, Shome N. (5748 Drexel, 2A, Chicago, IL 60637)

    1990-01-01

    A process for removing copper from ferrous or other metal scrap in which the scrap is contacted with a polyvalent metal sulfide slag in the presence of an excess of copper-sulfide forming additive to convert the copper to copper sulfide which is extracted into the slag to provide a ratio of copper in the slag to copper in the metal scrap of at least about 10.

  6. Process for removing mercury from aqueous solutions

    DOE Patents [OSTI]

    Googin, J.M.; Napier, J.M.; Makarewicz, M.A.; Meredith, P.F.

    1985-03-04

    A process for removing mercury from water to a level not greater than two parts per billion wherein an anion exchange material that is insoluble in water is contacted first with a sulfide containing compound and second with a compound containing a bivalent metal ion forming an insoluble metal sulfide. To this treated exchange material is contacted water containing mercury. The water containing not more than two parts per billion of mercury is separated from the exchange material.

  7. Process for removing sulfur from coal

    DOE Patents [OSTI]

    Aida, T.; Squires, T.G.; Venier, C.G.

    1983-08-11

    A process is disclosed for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

  8. Removal of copper from ferrous scrap

    DOE Patents [OSTI]

    Blander, M.; Sinha, S.N.

    1990-05-15

    A process for removing copper from ferrous or other metal scrap in which the scrap is contacted with a polyvalent metal sulfide slag in the presence of an excess of copper-sulfide forming additive to convert the copper to copper sulfide which is extracted into the slag to provide a ratio of copper in the slag to copper in the metal scrap of at least about 10.

  9. Flattening filter removal for improved image quality of megavoltage fluoroscopy

    SciTech Connect (OSTI)

    Christensen, James D.; Kirichenko, Alexander; Gayou, Olivier

    2013-08-15

    Purpose: Removal of the linear accelerator (linac) flattening filter enables a high rate of dose deposition with reduced treatment time. When used for megavoltage imaging, an unflat beam has reduced primary beam scatter resulting in sharper images. In fluoroscopic imaging mode, the unflat beam has higher photon count per image frame yielding higher contrast-to-noise ratio. The authors’ goal was to quantify the effects of an unflat beam on the image quality of megavoltage portal and fluoroscopic images.Methods: 6 MV projection images were acquired in fluoroscopic and portal modes using an electronic flat-panel imager. The effects of the flattening filter on the relative modulation transfer function (MTF) and contrast-to-noise ratio were quantified using the QC3 phantom. The impact of FF removal on the contrast-to-noise ratio of gold fiducial markers also was studied under various scatter conditions.Results: The unflat beam had improved contrast resolution, up to 40% increase in MTF contrast at the highest frequency measured (0.75 line pairs/mm). The contrast-to-noise ratio was increased as expected from the increased photon flux. The visualization of fiducial markers was markedly better using the unflat beam under all scatter conditions, enabling visualization of thin gold fiducial markers, the thinnest of which was not visible using the unflat beam.Conclusions: The removal of the flattening filter from a clinical linac leads to quantifiable improvements in the image quality of megavoltage projection images. These gains enable observers to more easily visualize thin fiducial markers and track their motion on fluoroscopic images.

  10. Removing nuclear waste, one shipment at a time

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Removing nuclear waste, one shipment at a time Removing nuclear waste, one shipment at a time The Lab's 1,000th shipment of transuranic waste recently left Los Alamos, on its way...

  11. Identifying and removing sources of imprecision in polynomial regression

    E-Print Network [OSTI]

    Brauner, Neima

    Identifying and removing sources of imprecision in polynomial regression Neima Braunera and removal of imprecision in polynomial regression, originating from random errors (noise) in the independent.V. Keywords: Regression; Polynomial; Precision; Noise; Collinearity 1. Introduction Mathematical modeling

  12. Process for removing technetium from iron and other metals

    DOE Patents [OSTI]

    Leitnaker, J.M.; Trowbridge, L.D.

    1999-03-23

    A process for removing technetium from iron and other metals comprises the steps of converting the molten, alloyed technetium to a sulfide dissolved in manganese sulfide, and removing the sulfide from the molten metal as a slag. 4 figs.

  13. Modeling and simulation of material removal with particulate flows

    E-Print Network [OSTI]

    Arbelaez, D; Zohdi, T I; Dornfeld, David

    2008-01-01

    optimization In material removal processes there are a large number of input parameters which control the quality of the process.

  14. Method for removing fluoride contamination from nitric acid

    DOE Patents [OSTI]

    Pruett, David J. (Knoxville, TN); Howerton, William B. (Kingston, TN)

    1982-01-01

    Fluoride ions are removed from nitric acid solution by contacting the vaporized solution with alumina or zirconium.

  15. Slang characterization and removal using pulse detonation technology during coal gasification

    SciTech Connect (OSTI)

    Huque, Z.; Mei, D.; Biney, P.O.; Zhou, J.

    1997-03-25

    Boiler slagging and fouling as a result of inorganic impurities in combustion gases being deposited on heat transfer tubes have caused severe problems in coal-fired power plant operation. These problems are fuel, system design, and operating condition dependent. Pulse detonation technology for the purpose of removing slag and fouling deposits in coal-fired utility power plant boilers offers great potential. The detonation wave technique based on high impact velocity with sufficient energy and thermal shock on the slag deposited on gas contact surfaces offers a convenient, inexpensive, yet efficient and effective way to supplement existing slag removal methods. These detonation waves have been demonstrated experimentally to have exceptionally high shearing capability important to the task of removing slag and fouling deposits. The experimental results show that the single shot detonation wave is capable of removing the entire slag (types of slag deposited on economizer) even at a distance of 8 in. from the exit of a detonation engine tube. Wave strength and slag orientation also have different effects on the chipping off of the slag. This paper discusses about the results obtained in effectively removing the economizer slag.

  16. Factors affecting the removal of geosmin and MIB in drinking water biofilters

    SciTech Connect (OSTI)

    Elhadi, S.L.N.; Huck, P.M.; Slawson, R.M. [Wilfrid Laurier University, Waterloo, ON (Canada). Dept. for Biology

    2006-08-15

    Bench-scale experiments were conducted using four parallel dual-media filter columns containing biologically active anthracite or granular activated carbon media and sand. The factors under investigation were low-(8{sup o}C) and high-(20{sup o}C) temperature operations, geosmin and 2-methylisoborneol (MIB) concentration, media type, and biodegradable organic matter (BOM) level. Source water consisted of dechlorinated tap water to which geosmin and MIB were added, as well as a cocktail of easily biodegradable organic matter (i.e., typical ozonation by-products). Phase 1 experiments used a high BOM level (280 {mu} g/L carbon) to simulate water that had been subjected to ozonation before filtration. Phase 2 experiments used a low BOM level (28 {mu} g/L C) to simulate nonozonated water. Factorial design experiments showed that all four main factors (temperature, concentration, media, and BOM level) were important to both geosmin and MIB removal. Temperature and media interaction and concentration and BOM level interaction were significant for geosmin removal only. Temperature and BOM level interaction as well as media and BOM level interaction were significant for the removal of both geosmin and MIB. Overall, removals of geosmin and MIB were lower in phase 2 (low BOM level), in particular in the anthracite media filters. Biomass levels in the filters appeared to have a significant effect upon the removal efficiencies of both odor compounds.

  17. Method for the removal of carbonyl sulfide from liquid propane

    SciTech Connect (OSTI)

    McClure, G.

    1980-06-17

    A method for the removal of carbonyl sulfide from liquid propane under liquid-liquid contact conditions by mixing liquid propane containing carbonyl sulfide as an impurity with 2-(2-aminoethoxy) ethanol as the principal agent for the carbonyl sulfide removal. The 2(2-aminoethoxy) ethanol is reclaimed and reused for further carbonyl sulfide removal. 5 claims.

  18. INVESTIGATION OF IONIC CONTAMINATION REMOVAL FROM SILICON DIOXIDE SURFACES

    E-Print Network [OSTI]

    Suni, Ian Ivar

    INVESTIGATION OF IONIC CONTAMINATION REMOVAL FROM SILICON DIOXIDE SURFACES H. Lin, A. A. Busnaina, and I. I. Suni T he removal of ionic contaminants from silicon surfaces surface contamination level canM Communications L td. INTRODUCTION with increasing frequency and power, and decreases Contamination removal is one

  19. Ultracapacitor having residual water removed under vacuum

    DOE Patents [OSTI]

    Wei, Chang (Niskayuna, NY); Jerabek, Elihu Calvin (Glenmont, NY); Day, James (Scotia, NY)

    2002-10-15

    A multilayer cell is provided that comprises two solid, nonporous current collectors, two porous electrodes separating the current collectors, a porous separator between the electrodes and an electrolyte occupying pores in the electrodes and separator. The mutilayer cell is electrolyzed to disassociate water within the cell to oxygen gas and hydrogen gas. A vacuum is applied to the cell substantially at the same time as the electrolyzing step, to remove the oxygen gas and hydrogen gas. The cell is then sealed to form a ultracapacitor substantially free from water.

  20. Mechanism of paint removing by organic solvents

    SciTech Connect (OSTI)

    Del Nero, V.; Siat, C.; Marti, M.J.; Aubry, J.M.; Lallier, J.P.; Dupuy, N.; Huvenne, J.P.

    1996-01-01

    The mechanism of paint removing has been studied by comparing the stripping efficiency of a given solvent with its ability to swell the film. The most effective solvents have a Hildebrand{close_quote}s parameter, {delta}{sub H}, ranging from 10.5 to 12 and a Dimroth parameter, ET{sub (30)}, ranging from 0.25 to 0.4. The synergy observed with the mixtures DMSO/non polar solvent is explained by a dissociation of the DMSO clusters into individual molecules which diffuse more easily. {copyright} {ital 1996 American Institute of Physics.}

  1. Protection #2: Trap and Remove Sediment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeedingProgramExemptions |(Conference)ProjectProposedAmerica'sTrap and Remove

  2. Keeler-Pennwalt Wood Pole Removal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACTThousand Cubic Feet) Sold toKeeler-Pennwalt-Wood-Pole-Removal Sign

  3. Saeltzer Dam Removal on Clear Creek 11 years later: An assessment of upstream channel changes since the dam's removal

    E-Print Network [OSTI]

    Simons, Crystal; Walker, Katelyn; Zimring, Mark

    2011-01-01

    Boulder BLDR Bedrock BDRK Dam Rubble DMRB Table B1. 2011pages. Brown, M. (n.d. ). Clear Creek—McCormick-Saeltzer DamRemoval: Dam removal re-opens spring run salmon habitat. US

  4. Removing oestrogenic compounds from sewage effluent Andrew Johnson and Richard Darton

    E-Print Network [OSTI]

    Darton, Richard

    through a water treatment plant (and Londoners can be reassured that treating is done to an extremely high material in the feed. Widespread use of activated sludge plants has enabled fish to return to many previously grossly polluted rivers. However, such treatment plants were never tasked with removing all

  5. Removal of SO2 from gas streams using a dielectric barrier discharge and combined plasma photolysis

    E-Print Network [OSTI]

    Kushner, Mark

    is obtained with a series of short, high E/N current pulses rather than a single, low E/N current pulse studies into alternate plasma-based removal technologies such as pulsed corona discharges by the combustion of fossil fuels containing sulphur relies on tivo mechanisms. The first, which we call direct

  6. Principal Component Analysis of Tsunami Buoy Record: Tide Prediction and Removal

    E-Print Network [OSTI]

    Tolkova, Elena

    Principal Component Analysis of Tsunami Buoy Record: Tide Prediction and Removal Elena Tolkova a, a for short- term tidal predictions at tsunami buoy locations with precision of more advanced methods on a network of tsunameters (Deep-ocean Assessment and Reporting of Tsunamis (DART) buoys) to obtain high qual

  7. Process for removal of hydrogen halides or halogens from incinerator gas

    DOE Patents [OSTI]

    Huang, H.S.; Sather, N.F.

    1987-08-21

    A process for reducing the amount of halogens and halogen acids in high temperature combustion gas and through their removal, the formation of halogenated organics at lower temperatures, with the reduction being carried out electrochemically by contacting the combustion gas with the negative electrode of an electrochemical cell and with the halogen and/or halogen acid being recovered at the positive electrode.

  8. Bower paint removal leads to reduced female visits, suggesting bower paint functions as a chemical signal

    E-Print Network [OSTI]

    Borgia, Gerald

    Bower paint removal leads to reduced female visits, suggesting bower paint functions as a chemical unique display elements, bower painting, has received relatively little attention despite males' large of masticated vegetation and male saliva or `bower paint' to a chest-high band inside their bower walls

  9. Using Magnetically Responsive Tea Waste to Remove Lead in Waters under Environmentally Relevant Conditions

    E-Print Network [OSTI]

    Yeo, Siang Yee

    We report the use of a simple yet highly effective magnetite-waste tea composite to remove lead(II) (Pb[superscript 2+]) ions from water. Magnetite-waste tea composites were dispersed in four different types of water–deionized ...

  10. Precipitation process for the removal of technetium values from nuclear waste solutions

    DOE Patents [OSTI]

    Walker, D.D.; Ebra, M.A.

    1985-11-21

    High efficiency removal of techetium values from a nuclear waste stream is achieved by addition to the waste stream of a precipitant contributing tetraphenylphosphonium cation, such that a substantial portion of the technetium values are precipitated as an insoluble pertechnetate salt.

  11. Removal of arsenic compounds from petroliferous liquids

    DOE Patents [OSTI]

    Fish, R.H.

    1984-04-06

    The present invention in one aspect comprises a process for removing arsenic from petroliferous-derived liquids by contacting said liquid with a divinylbenzene-crosslinked polystyrene polymer (i.e. PS-DVB) having catechol ligands anchored to said polymer, said contacting being at an elevated temperature. In another aspect, the invention is a process for regenerating spent catecholated polystyrene polymer by removal of the arsenic bound to it from contacting petroliferous liquid in accordance with the aspect described above which regenerating process comprises: (a) treating said spent catecholated polystyrene polymer with an aqueous solution of at least one member selected from the group consisting of carbonates and bicarbonates of ammonium, alkali metals, and alkaline earth metals, said solution having a pH between about 8 and 10, and said treating being at a temperature in the range of about 20/sup 0/ to 100/sup 0/C; (b) separating the solids and liquids from each other. In a preferred embodiment the regeneration treatment is in two steps wherein step: (a) is carried out with an aqueous alcoholic carbonate solution which includes at least one lower alkyl alcohol, and, steps (c) and (d) are added. Steps (c) and (d) comprise: (c) treating the solids with an aqueous alcoholic solution of at least one ammonium, alkali or alkaline earth metal bicarbonate at a temperature in the range of about 20 to 100/sup 0/C; and (d) separating the solids from the liquids.

  12. Drum ring removal/installation tool

    DOE Patents [OSTI]

    Andrade, William Andrew (Livermore, CA)

    2006-11-14

    A handheld tool, or a pair of such tools, such as for use in removing/installing a bolt-type clamping ring on a container barrel/drum, where the clamping ring has a pair of clamping ends each with a throughbore. Each tool has an elongated handle and an elongated lever arm transversely connected to one end of the handle. The lever arm is capable of being inserted into the throughbore of a selected clamping end and leveraged with the handle to exert a first moment on the selected clamping end. Each tool also has a second lever arm, such as a socket with an open-ended slot, which is suspended alongside the first lever arm. The second lever arm is capable of engaging the selected clamping end and being leveraged with the handle to exert a second moment which is orthogonal to the first moment. In this manner, the first and second moments operate to hold the selected clamping end fixed relative to the tool so that the selected clamping end may be controlled with the handle. The pair of clamping ends may also be simultaneously and independently controlled with the use of two handles/tools so as to contort the geometry of the drum clamping ring and enable its removal/installation.

  13. Process for removing polychlorinated biphenyls from soil

    DOE Patents [OSTI]

    Hancher, C.W.; Saunders, M.B.; Googin, J.M.

    1984-11-16

    The present invention relates to a method of removing polychlorinated biphenyls from soil. The polychlorinated biphenyls are extracted from the soil by employing a liquid organic solvent dispersed in water in the ratio of about 1:3 to 3:1. The organic solvent includes such materials as short-chain hydrocarbons including kerosene or gasoline which are immiscible with water and are nonpolar. The organic solvent has a greater affinity for the PCB's than the soil so as to extract the PCB's from the soil upon contact. The organic solvent phase is separated from the suspended soil and water phase and distilled for permitting the recycle of the organic solvent phase and the concentration of the PCB's in the remaining organic phase. The present process can be satisfactorily practiced with soil containing 10 to 20% petroleum-based oils and organic fluids such as used in transformers and cutting fluids, coolants and the like which contain PCB's. The subject method provides for the removal of a sufficient concentration of PCB's from the soil to provide the soil with a level of PCB's within the guidelines of the Environmental Protection Agency.

  14. EVOLVING EXPECTATIONS OF DAM REMOVAL OUTCOMES: DOWNSTREAM GEOMORPHIC EFFECTS FOLLOWING REMOVAL OF A SMALL, GRAVEL-FILLED DAM1

    E-Print Network [OSTI]

    Tullos, Desiree

    EVOLVING EXPECTATIONS OF DAM REMOVAL OUTCOMES: DOWNSTREAM GEOMORPHIC EFFECTS FOLLOWING REMOVAL OF A SMALL, GRAVEL-FILLED DAM1 Kelly Kibler, Desiree Tullos, and Mathias Kondolf 2 ABSTRACT: Dam removal is a promising river restoration technique, particularly for the vast number of rivers impounded by small dams

  15. Pretreatment of neutralized cladding removal waste sludge: Status Report

    SciTech Connect (OSTI)

    Lumetta, G J; Swanson, J L

    1993-03-01

    This report describes the status of process development for pretreating Hanford neutralized cladding removal waste (NCRW) sludge, of which [approximately] 3.3 [times] 10[sup 6] L is stored in Tanks 103-AW and 105-AW at the Hanford Site. The initial baseline process chosen for pretreating NCRW sludge is to dissolve the sludge in nitric acid and extract the -transuranic (MU) elements from the dissolved sludge solution with octyl(phenyl)-N,N-diisobutylcarbamoyl methyl phosphine oxide (CNWO). This process converts the NCRW sludge into a relatively large volume of low-level waste (LLW) to be disposed of as grout, leaving only a small volume of high-level waste (HLW) requiring vitrification in the Hanford Waste Vitrification Plant (HWVP).

  16. Removal of Sarin Aerosol and Vapor by Water Sprays

    SciTech Connect (OSTI)

    Brockmann, John E.

    1998-09-01

    Falling water drops can collect particles and soluble or reactive vapor from the gas through which they fall. Rain is known to remove particles and vapors by the process of rainout. Water sprays can be used to remove radioactive aerosol from the atmosphere of a nuclear reactor containment building. There is a potential for water sprays to be used as a mitigation technique to remove chemical or bio- logical agents from the air. This paper is a quick-look at water spray removal. It is not definitive but rather provides a reasonable basic model for particle and gas removal and presents an example calcu- lation of sarin removal from a BART station. This work ~ a starting point and the results indicate that further modeling and exploration of additional mechanisms for particle and vapor removal may prove beneficial.

  17. Tank 37H Salt Removal Batch Process and Salt Dissolution Mixing Study

    SciTech Connect (OSTI)

    Kwon, K.C.

    2001-09-18

    Tank 30H is the receipt tank for concentrate from the 3H Evaporator. Tank 30H has had problems, such as cooling coil failure, which limit its ability to receive concentrate from the 3H Evaporator. SRS High Level Waste wishes to use Tank 37H as the receipt tank for the 3H Evaporator concentrate. Prior to using Tank 37H as the 3H Evaporator concentrate receipt tank, HLW must remove 50 inches of salt cake from the tank. They requested SRTC to evaluate various salt removal methods for Tank 37H. These methods include slurry pumps, Flygt mixers, the modified density gradient method, and molecular diffusion.

  18. Improving proton-induced one-nucleon removal in intranuclear cascade

    E-Print Network [OSTI]

    Davide Mancusi; Alain Boudard; Jaume Carbonell; Joseph Cugnon; Jean-Christophe David; Sylvie Leray

    2015-01-27

    It is a well-established fact that intranuclear-cascade models generally fail to consistently reproduce the cross sections for one-proton and one-neutron removal from stable nuclei by a high-energy proton beam. We use simple shell-model calculations to investigate the reasons of this deficiency. We find that a refined description of the neutron skin and of the energy density in the nuclear surface is crucial for the aforementioned observables, and that neither ingredient is sufficient if taken separately. As a by-product, the predictions for removal of several nucleons are also improved by the refined treatment.

  19. Apparatus and method for removing particle species from fusion-plasma-confinement devices

    DOE Patents [OSTI]

    Hamilton, G.W.

    1981-10-26

    In a mirror fusion plasma confinement apparatus, method and apparatus are provided for selectively removing (pumping) trapped low energy (thermal) particle species from the end cell region, without removing the still useful high energy particle species, and without requiring large power input to accomplish the pumping. Perturbation magnets are placed in the thermal barrier region of the end cell region at the turning point characteristic of trapped thermal particles, thus deflecting the thermal particles from their closed trajectory, causing them to drift sufficiently to exit the thermal barrier.

  20. Preliminary Evaluation of Removing Used Nuclear Fuel from Shutdown Sites

    SciTech Connect (OSTI)

    Maheras, Steven J.; Best, Ralph E.; Ross, Steven B.; Buxton, Kenneth A.; England, Jeffery L.; McConnell, Paul E.; Massaro, Lawrence M.; Jensen, Philip J.

    2014-10-01

    This report presents a preliminary evaluation of removing used nuclear fuel (UNF) from 12 shutdown nuclear power plant sites. At these shutdown sites the nuclear power reactors have been permanently shut down and the sites have been decommissioned or are undergoing decommissioning. The shutdown sites are Maine Yankee, Yankee Rowe, Connecticut Yankee, Humboldt Bay, Big Rock Point, Rancho Seco, Trojan, La Crosse, Zion, Crystal River, Kewaunee, and San Onofre. The evaluation was divided into four components: characterization of the UNF and greater-than-Class C low-level radioactive waste (GTCC waste) inventory; a description of the on-site infrastructure and conditions relevant to transportation of UNF and GTCC waste; an evaluation of the near-site transportation infrastructure and experience relevant to shipping transportation casks containing UNF and GTCC waste, including identification of gaps in information; and, an evaluation of the actions necessary to prepare for and remove UNF and GTCC waste. The primary sources for the inventory of UNF and GTCC waste are the U.S. Department of Energy (DOE) RW-859 used nuclear fuel inventory database, industry sources such as StoreFUEL and SpentFUEL, and government sources such as the U.S. Nuclear Regulatory Commission. The primary sources for information on the conditions of site and near-site transportation infrastructure and experience included observations and information collected during visits to the Maine Yankee, Yankee Rowe, Connecticut Yankee, Humboldt Bay, Big Rock Point, Rancho Seco, Trojan, La Crosse, and Zion sites; information provided by managers at the shutdown sites; Facility Interface Data Sheets compiled for DOE in 2005; Services Planning Documents prepared for DOE in 1993 and 1994; industry publications such as Radwaste Solutions; and Google Earth. State and Regional Group representatives, a Tribal representative, and a Federal Railroad Administration representative participated in six of the shutdown site visits. Every site was found to have at least one off-site transportation mode option for removing its UNF and GTCC waste; some have multiple options. Experience removing large components during reactor decommissioning provided an important source of information used to identify the transportation mode options for the sites. Especially important in conducting the evaluation were site visits, through which information was obtained that would not have been available otherwise. Extensive photographs taken during the site visits proved to be particularly useful in documenting the current conditions at or near the sites. Additional conclusions from this evaluation include: The 12 shutdown sites use designs from 4 different suppliers involving 9 different (horizontal and vertical) dry storage systems that would require the use of 8 different transportation cask designs to remove the UNF and GTCC waste from the shutdown sites; Although there are common aspects, each site has some unique features and/or conditions; Although some regulatory actions will be required, all UNF at the initial 9 shutdown sites (Maine Yankee, Yankee Rowe, Connecticut Yankee, Humboldt Bay, Big Rock Point, Rancho Seco, Trojan, La Crosse, and Zion) is in licensed systems that can be transported, including a small amount of high-burnup fuel; Each site indicated that 2-3 years of advance time would be required for its preparations before shipments could begin; Most sites have more than one transportation option, e.g., rail, barge, or heavy haul truck, as well as constraints and preferences. It is expected that additional site visits will be conducted to add to the information presented in the evaluation.

  1. Three dimensional electrode for the electrolytic removal of contaminants from aqueous waste streams

    DOE Patents [OSTI]

    Spiegel, Ella F. (Louisville, CO); Sammells, Anthony F. (Boulder, CO)

    2001-01-01

    Efficient and cost-effective electrochemical devices and processes for the remediation of aqueous waste streams. The invention provides electrolytic cells having a high surface area spouted electrode for removal of heavy metals and oxidation of organics from aqueous environments. Heavy metal ions are reduced, deposited on cathode particles of a spouted bed cathode and removed from solution. Organics are efficiently oxidized at anode particles of a spouted bed anode and removed from solution. The method of this inventions employs an electrochemical cell having an anolyte compartment and a catholyte compartment, separated by a microporous membrane, in and through which compartments anolyte and catholyte, respectively, are circulated. A spouted-bed electrode is employed as the cathode for metal deposition from contaminated aqueous media introduced as catholyte and as the anode for oxidation of organics from contaminated aqueous media introduced as anolyte.

  2. Removal of lead paint from old housing: the need for a new approach

    SciTech Connect (OSTI)

    Chisolm, J.J. Jr.

    1986-03-01

    Considerations for the development of criteria for safe and effective methods for removal of lead-based paints and dusts from exposed residential surfaces include the following: residential buildings should be classified according to the degree of deterioration, taking into account not only the presence of scaling paint but also structural soundness, present and potential water damage, and the condition of the flooring. A wet chemical process which removes all paint from both flat and irregular surfaces and does not create or leave behind fine lead-bearing particulates is recommended. A high efficiency particle accumulator vacumming system will be needed to remove the particulates that have accumulated over the years. Splintered flooring should be sealed, covered or replaced.

  3. IMPROVED PROCESSES TO REMOVE NAPHTHENIC ACIDS

    SciTech Connect (OSTI)

    Aihua Zhang; Qisheng Ma; William A. Goddard; Yongchun Tang

    2004-04-28

    In the first year of this project, we have established our experimental and theoretical methodologies for studies of the catalytic decarboxylation process. We have developed both glass and stainless steel micro batch type reactors for the fast screening of various catalysts with reaction substrates of model carboxylic acid compounds and crude oil samples. We also developed novel product analysis methods such as GC analyses for organic acids and gaseous products; and TAN measurements for crude oil. Our research revealed the effectiveness of several solid catalysts such as NA-Cat-1 and NA-Cat-2 for the catalytic decarboxylation of model compounds; and NA-Cat-5{approx}NA-Cat-9 for the acid removal from crude oil. Our theoretical calculations propose a three-step concerted oxidative decarboxylation mechanism for the NA-Cat-1 catalyst.

  4. Removing sulphur oxides from a fluid stream

    DOE Patents [OSTI]

    Katz, Torsten; Riemann, Christian; Bartling, Karsten; Rigby, Sean Taylor; Coleman, Luke James Ivor; Lail, Marty Alan

    2014-04-08

    A process for removing sulphur oxides from a fluid stream, such as flue gas, comprising: providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the liquid being incompletely miscible with water; treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

  5. AX Tank Farm tank removal study

    SciTech Connect (OSTI)

    SKELLY, W.A.

    1999-02-24

    This report examines the feasibility of remediating ancillary equipment associated with the 241-AX Tank Farm at the Hanford Site. Ancillary equipment includes surface structures and equipment, process waste piping, ventilation components, wells, and pits, boxes, sumps, and tanks used to make waste transfers to/from the AX tanks and adjoining tank farms. Two remedial alternatives are considered: (1) excavation and removal of all ancillary equipment items, and (2) in-situ stabilization by grout filling, the 241-AX Tank Farm is being employed as a strawman in engineering studies evaluating clean and landfill closure options for Hanford single-shell tanks. This is one of several reports being prepared for use by the Hanford Tanks Initiative Project to explore potential closure options and to develop retrieval performance evaluation criteria for tank farms.

  6. AX Tank Farm tank removal study

    SciTech Connect (OSTI)

    SKELLY, W.A.

    1998-10-14

    This report considers the feasibility of exposing, demolishing, and removing underground storage tanks from the 241-AX Tank Farm at the Hanford Site. For the study, it was assumed that the tanks would each contain 360 ft{sup 3} of residual waste (corresponding to the one percent residual Inventory target cited in the Tri-Party Agreement) at the time of demolition. The 241-AX Tank Farm is being employed as a ''strawman'' in engineering studies evaluating clean and landfill closure options for Hanford single-shell tank farms. The report is one of several reports being prepared for use by the Hanford Tanks Initiative Project to explore potential closure options and to develop retrieval performance evaluation criteria for tank farms.

  7. Successful removal of zinc sulfide scale restriction from a hot, deep, sour gas well

    SciTech Connect (OSTI)

    Kenrick, A.J.; Ali, S.A.

    1997-07-01

    Removal of zinc sulfide scale with hydrochloric acid from a hot, deep, Norphlet Sandstone gas well in the Gulf of Mexico resulted in a 29% increase in the production rates. The zinc sulfide scale was determined to be in the near-wellbore area. The presence of zinc sulfide is explained by the production of 25 ppm H{sub 2}S gas, and the loss of 50--100 bbl of zinc bromide fluid to the formation. Although zinc sulfide scale has been successfully removed with hydrochloric acid in low-to-moderate temperature wells, no analogous treatment data were available for high temperature, high pressure (HTHP) Norphlet wells. Therefore laboratory testing was initiated to identify suitable acid systems for scale removal, and select a high quality corrosion inhibitor that would mitigate detrimental effects of the selected acid on downhole tubulars and surface equipment. This case history presents the first successful use of hydrochloric acid in removing zinc sulfide scale from a HTHP Norphlet sour gas well.

  8. Nuclear reactor with makeup water assist from residual heat removal system

    DOE Patents [OSTI]

    Corletti, Michael M. (New Kensington, PA); Schulz, Terry L. (Murrysville, PA)

    1993-01-01

    A pressurized water nuclear reactor uses its residual heat removal system to make up water in the reactor coolant circuit from an in-containment refueling water supply during staged depressurization leading up to passive emergency cooling by gravity feed from the refueling water storage tank, and flooding of the containment building. When depressurization commences due to inadvertence or a manageable leak, the residual heat removal system is activated manually and prevents flooding of the containment when such action is not necessary. Operation of the passive cooling system is not impaired. A high pressure makeup water storage tank is coupled to the reactor coolant circuit, holding makeup coolant at the operational pressure of the reactor. The staged depressurization system vents the coolant circuit to the containment, thus reducing the supply of makeup coolant. The level of makeup coolant can be sensed to trigger opening of successive depressurization conduits. The residual heat removal pumps move water from the refueling water storage tank into the coolant circuit as the coolant circuit is depressurized, preventing reaching the final depressurization stage unless the makeup coolant level continues to drop. The residual heat removal system can also be coupled in a loop with the refueling water supply tank, for an auxiliary heat removal path.

  9. Nuclear reactor with makeup water assist from residual heat removal system

    DOE Patents [OSTI]

    Corletti, M.M.; Schulz, T.L.

    1993-12-07

    A pressurized water nuclear reactor uses its residual heat removal system to make up water in the reactor coolant circuit from an in-containment refueling water supply during staged depressurization leading up to passive emergency cooling by gravity feed from the refueling water storage tank, and flooding of the containment building. When depressurization commences due to inadvertence or a manageable leak, the residual heat removal system is activated manually and prevents flooding of the containment when such action is not necessary. Operation of the passive cooling system is not impaired. A high pressure makeup water storage tank is coupled to the reactor coolant circuit, holding makeup coolant at the operational pressure of the reactor. The staged depressurization system vents the coolant circuit to the containment, thus reducing the supply of makeup coolant. The level of makeup coolant can be sensed to trigger opening of successive depressurization conduits. The residual heat removal pumps move water from the refueling water storage tank into the coolant circuit as the coolant circuit is depressurized, preventing reaching the final depressurization stage unless the makeup coolant level continues to drop. The residual heat removal system can also be coupled in a loop with the refueling water supply tank, for an auxiliary heat removal path. 2 figures.

  10. FLOWSHEET FOR ALUMINUM REMOVAL FROM SLUDGE BATCH 6

    SciTech Connect (OSTI)

    Pike, J; Jeffrey Gillam, J

    2008-12-17

    Samples of Tank 12 sludge slurry show a substantially larger fraction of aluminum than originally identified in sludge batch planning. The Liquid Waste Organization (LWO) plans to formulate Sludge Batch 6 (SB6) with about one half of the sludge slurry in Tank 12 and one half of the sludge slurry in Tank 4. LWO identified aluminum dissolution as a method to mitigate the effect of having about 50% more solids in High Level Waste (HLW) sludge than previously planned. Previous aluminum dissolution performed in a HLW tank in 1982 was performed at approximately 85 C for 5 days and dissolved nearly 80% of the aluminum in the sludge slurry. In 2008, LWO successfully dissolved 64% of the aluminum at approximately 60 C in 46 days with minimal tank modifications and using only slurry pumps as a heat source. This report establishes the technical basis and flowsheet for performing an aluminum removal process in Tank 51 for SB6 that incorporates the lessons learned from previous aluminum dissolution evolutions. For SB6, aluminum dissolution process temperature will be held at a minimum of 65 C for at least 24 days, but as long as practical or until as much as 80% of the aluminum is dissolved. As planned, an aluminum removal process can reduce the aluminum in SB6 from about 84,500 kg to as little as 17,900 kg with a corresponding reduction of total insoluble solids in the batch from 246,000 kg to 131,000 kg. The extent of the reduction may be limited by the time available to maintain Tank 51 at dissolution temperature. The range of dissolution in four weeks based on the known variability in dissolution kinetics can range from 44 to more than 80%. At 44% of the aluminum dissolved, the mass reduction is approximately 1/2 of the mass noted above, i.e., 33,300 kg of aluminum instead of 66,600 kg. Planning to reach 80% of the aluminum dissolved should allow a maximum of 81 days for dissolution and reduce the allowance if test data shows faster kinetics. 47,800 kg of the dissolved aluminum will be stored in Tank 8 and 21,000 kg will be stored in saltcake via evaporation. Up to 77% of the total aluminum planned for SB6 may be removed via aluminum dissolution. Storage of the aluminum-laden supernate in Tank 8 will require routine evaluation of the free hydroxide concentration in order to maintain aluminum in solution. Periodic evaluation will be established on concurrent frequency with corrosion program samples as previously established for aluminum-laden supernate from SB5 that is stored in Tank 11.

  11. ACTINIDE REMOVAL PROCESS SAMPLE ANALYSIS, CHEMICAL MODELING, AND FILTRATION EVALUATION

    SciTech Connect (OSTI)

    Martino, C.; Herman, D.; Pike, J.; Peters, T.

    2014-06-05

    Filtration within the Actinide Removal Process (ARP) currently limits the throughput in interim salt processing at the Savannah River Site. In this process, batches of salt solution with Monosodium Titanate (MST) sorbent are concentrated by crossflow filtration. The filtrate is subsequently processed to remove cesium in the Modular Caustic Side Solvent Extraction Unit (MCU) followed by disposal in saltstone grout. The concentrated MST slurry is washed and sent to the Defense Waste Processing Facility (DWPF) for vitrification. During recent ARP processing, there has been a degradation of filter performance manifested as the inability to maintain high filtrate flux throughout a multi-batch cycle. The objectives of this effort were to characterize the feed streams, to determine if solids (in addition to MST) are precipitating and causing the degraded performance of the filters, and to assess the particle size and rheological data to address potential filtration impacts. Equilibrium modelling with OLI Analyzer{sup TM} and OLI ESP{sup TM} was performed to determine chemical components at risk of precipitation and to simulate the ARP process. The performance of ARP filtration was evaluated to review potential causes of the observed filter behavior. Task activities for this study included extensive physical and chemical analysis of samples from the Late Wash Pump Tank (LWPT) and the Late Wash Hold Tank (LWHT) within ARP as well as samples of the tank farm feed from Tank 49H. The samples from the LWPT and LWHT were obtained from several stages of processing of Salt Batch 6D, Cycle 6, Batch 16.

  12. Metal Cutting for Large Component Removal

    SciTech Connect (OSTI)

    Hulick, Robert M.

    2008-01-15

    Decommissioning of commercial nuclear power plants presents technological challenges. One major challenge is the removal of large components mainly consisting of the reactor vessel, steam generators and pressurizer. In order to remove and package these large components nozzles must be cut from the reactor vessel to precise tolerances. In some cases steam generators must be segmented for size and weight reduction. One innovative technology that has been used successfully at several commercial nuclear plant decommissioning is diamond wire sawing. Diamond wire sawing is performed by rotating a cable with diamond segments attached using a flywheel approximately 24 inches in diameter driven remotely by a hydraulic pump. Tension is provided using a gear rack drive which also takes up the slack in the wire. The wire is guided through the use of pulleys keeps the wire in a precise location. The diamond wire consists of 1/4 inch aircraft cable with diamond beads strung over the cable separated by springs and brass crimps. Standard wire contains 40 diamond beads per meter and can be made to any length. Cooling the wire and controlling the spread of contamination presents significant challenges. Under normal circumstances the wire is cooled and the cutting kerf cleaned by using water. In some cases of reactor nozzle cuts the use of water is prohibited because it cannot be controlled. This challenge was solved by using liquid Carbon Dioxide as the cooling agent. The liquid CO{sub 2} is passed through a special nozzle which atomizes the liquid into snowflakes which is introduced under pressure to the wire. The snowflakes attach to the wire keeping it cool and to the metal shavings. As the CO{sub 2} and metal shavings are released from the wire due to its fast rotation, the snowflakes evaporate leaving only the fine metal shavings as waste. Secondary waste produced is simply the small volume of fine metal shavings removed from the cut surface. Diamond wire sawing using CO{sub 2} cooling has been employed for cutting the reactor nozzles at San Onofre Unit 1 and at Connecticut Yankee. These carbon steel nozzles ranged up to 54 inch diameter with a 15 inch thick wall and an interior stainless cladding. Diamond wire sawing using traditional water cooling has been used to segment the reactor head at Rancho Seco and for cutting reactor nozzles and control rod drive tubes at Dairyland Power's Lacrosse BWR project. Advantages: - ALARA: All cutting is preformed remotely significantly reducing dose. Stringing of wires is accomplished using long handle tools. - Secondary waste is reduced to just the volume of material cut with the diamond wire. - The potential for airborne contamination is eliminated. Due to the flexibility of the wire, any access restrictions and interferences can be accommodated using pulleys and long handle tools. - The operation is quiet. Disadvantages: - With Liquid Carbon Dioxide cooling and cleaning, delivery of the material must be carefully planned. The longer the distance from the source to the cut area, the greater the chance for pressure drop and subsequent problems with line freezing. - Proper shrouding and ventilation are required for environmental reasons. In each case, the metal structures were cut at a precise location. Radiation dose was reduced significantly by operating the equipment from a remote location. The cuts were very smooth and completed on schedule. Each project must be analyzed individually and take into account many factors including access, radiological conditions, environmental conditions, schedule requirements, packaging requirements and size of cuts.

  13. Thiacrown polymers for removal of mercury from waste streams

    DOE Patents [OSTI]

    Baumann, Theodore F.; Reynolds, John G.; Fox, Glenn A.

    2004-02-24

    Thiacrown polymers immobilized to a polystyrene-divinylbenzene matrix react with Hg.sup.2+ under a variety of conditions to efficiently and selectively remove Hg.sup.2+ ions from acidic aqueous solutions, even in the presence of a variety of other metal ions. The mercury can be recovered and the polymer regenerated. This mercury removal method has utility in the treatment of industrial wastewater, where a selective and cost-effective removal process is required.

  14. Thiacrown polymers for removal of mercury from waste streams

    DOE Patents [OSTI]

    Baumann, Theodore F. (Tracy, CA); Reynolds, John G. (San Ramon, CA); Fox, Glenn A. (Livermore, CA)

    2002-01-01

    Thiacrown polymers immobilized to a polystyrene-divinylbenzene matrix react with Hg.sup.2+ under a variety of conditions to efficiently and selectively remove Hg.sup.2+ ions from acidic aqueous solutions, even in the presence of a variety of other metal ions. The mercury can be recovered and the polymer regenerated. This mercury removal method has utility in the treatment of industrial wastewater, where a selective and cost-effective removal process is required.

  15. Heat recirculating cooler for fluid stream pollutant removal

    DOE Patents [OSTI]

    Richards, George A. (Morgantown, WV); Berry, David A. (Morgantown, WV)

    2008-10-28

    A process by which heat is removed from a reactant fluid to reach the operating temperature of a known pollutant removal method and said heat is recirculated to raise the temperature of the product fluid. The process can be utilized whenever an intermediate step reaction requires a lower reaction temperature than the prior and next steps. The benefits of a heat-recirculating cooler include the ability to use known pollutant removal methods and increased thermal efficiency of the system.

  16. Removal of radioactive and other hazardous material from fluid waste

    DOE Patents [OSTI]

    Tranter, Troy J. (Idaho Falls, ID); Knecht, Dieter A. (Idaho Falls, ID); Todd, Terry A. (Aberdeen, ID); Burchfield, Larry A. (W. Richland, WA); Anshits, Alexander G. (Krasnoyarsk, RU); Vereshchagina, Tatiana (Krasnoyarsk, RU); Tretyakov, Alexander A. (Zheleznogorsk, RU); Aloy, Albert S. (St. Petersburg, RU); Sapozhnikova, Natalia V. (St. Petersburg, RU)

    2006-10-03

    Hollow glass microspheres obtained from fly ash (cenospheres) are impregnated with extractants/ion-exchangers and used to remove hazardous material from fluid waste. In a preferred embodiment the microsphere material is loaded with ammonium molybdophosphonate (AMP) and used to remove radioactive ions, such as cesium-137, from acidic liquid wastes. In another preferred embodiment, the microsphere material is loaded with octyl(phenyl)-N-N-diisobutyl-carbamoylmethylphosphine oxide (CMPO) and used to remove americium and plutonium from acidic liquid wastes.

  17. Y-12 Removes Nuclear Materials from Two Facilities to Reduce...

    National Nuclear Security Administration (NNSA)

    Removes Nuclear Materials from Two Facilities to Reduce Site's Nuclear Footprint (Alpha 5 and 9720-38 No Longer Designated as Nuclear Facilities) | National Nuclear Security...

  18. Treatment of Difficult Waters: Arsenic Removal Silica Control...

    Office of Scientific and Technical Information (OSTI)

    of Difficult Waters: Arsenic Removal Silica Control Carbon Capture and Enhanced Oil Recovery. Citation Details In-Document Search Title: Treatment of Difficult Waters:...

  19. Study of Alternative Approaches for Transite Panel Removal

    Broader source: Energy.gov [DOE]

    Bechtel Jacobs Company LLC (BJC) assembled an experienced team from both sites to evaluate both the manual and mechanical methods of transite panel removal.

  20. RADTRAD: A simplified model for RADionuclide Transport and Removal...

    Office of Scientific and Technical Information (OSTI)

    RADTRAD: A simplified model for RADionuclide Transport and Removal And Dose estimation Citation Details In-Document Search Title: RADTRAD: A simplified model for RADionuclide...

  1. Preliminary Evaluation of Removing Used Nuclear Fuel from Shutdown...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Preliminary Evaluation of Removing Used Nuclear Fuel from Shutdown Sites Prepared for U.S. Department of Energy Nuclear Fuels Storage and Transportation Planning Project Steven J....

  2. United States, International Partners Remove Last Remaining Weapons...

    Broader source: Energy.gov (indexed) [DOE]

    are Austria, Chile, Czech Republic, Libya, Mexico, Romania, Serbia, Taiwan, Turkey, Ukraine, and Vietnam. To date, the Department has removed or dispositioned more than 5,000...

  3. Oregon Section 401 Removal/Fill Certification Webpage | Open...

    Open Energy Info (EERE)

    Certification Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Oregon Section 401 RemovalFill Certification Webpage Abstract Provides overview...

  4. EGR Cooler Fouling- Visualization of Deposition and Removal Mechanis

    Broader source: Energy.gov [DOE]

    Presents experimental data on exhaust gas recirculation(EGR) cooler fouling using new test apparatus that allows for in-situ observation of deposition and removal processes

  5. Process to remove rare earth from IFR electrolyte

    DOE Patents [OSTI]

    Ackerman, J.P.; Johnson, T.R.

    1992-01-01

    The invention is a process for the removal of rare earths from molten chloride electrolyte salts used in the reprocessing of integrated fast reactor fuel (IFR). The process can be used either continuously during normal operation of the electrorefiner or as a batch process. The process consists of first separating the actinide values from the salt before purification by removal of the rare earths. After replacement of the actinides removed in the first step, the now-purified salt electrolyte has the same uranium and plutonium concentration and ratio as when the salt was removed from the electrorefiner.

  6. EM Removes Radioactive Components from Former Reactor at Oak...

    Office of Environmental Management (EM)

    contractor employees who worked on the project to remove irradiated components from a reactor pool gather to watch the transport of the shipment offsite for disposition. Employees...

  7. Removal of Animal Antibiotics for Potable Water Reclamation: A Review

    E-Print Network [OSTI]

    Chang, Rita

    2015-01-01

    Treatment Primary treatment of wastewater usually involveswastewater. Removals of antibiotics in primary treatmentprimary clarifier effluents were taken from the Amherst, NY wastewater treatment

  8. Remove Condensate with Minimal Air Loss; Industrial Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 * August 2004 Industrial Technologies Program Suggested Actions * Inspect the condensate traps and determine if they are operating properly. * Review your condensate removal...

  9. NNSA's Global Threat Reduction Initiative Removes More Than One...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Global Threat Reduction Initiative Removes More Than One Ton of Food | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the...

  10. Treatment of Difficult Waters: Arsenic Removal Silica Control...

    Office of Scientific and Technical Information (OSTI)

    of Difficult Waters: Arsenic Removal Silica Control Carbon Capture and Enhanced Oil Recovery. Brady, Patrick Vane Abstract not provided. Sandia National Laboratories...

  11. Method of removal of sulfur from coal and petroleum products

    DOE Patents [OSTI]

    Verkade, John G. (Ames, IA); Mohan, Thyagarajan (Ames, IA); Angelici, Robert J. (Ames, IA)

    1995-01-01

    A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

  12. More Economical Sulfur Removal for Fuel Processing Plants

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    crude oil it is present in sulfur-containing organic compounds which are converted into hydrocarbons and H 2 S during the removal process (hydrodesulfurization). In both cases,...

  13. Oregon Guidelines for Stormwater Management Plans for Removal...

    Open Energy Info (EERE)

    Oregon Guidelines for Stormwater Management Plans for RemovalFill Permit Applications Jump to: navigation, search OpenEI Reference LibraryAdd to library PermittingRegulatory...

  14. Development of a removable conformal coating through the synthetic...

    Office of Scientific and Technical Information (OSTI)

    Conference: Development of a removable conformal coating through the synthetic incorporation of Diels-Adler thermally reversible adducts into an epoxy resin. Citation Details...

  15. Removal of Animal Antibiotics for Potable Water Reclamation: A Review

    E-Print Network [OSTI]

    Chang, Rita

    2015-01-01

    Pharmaceuticals and personal care products in effluent matrices: A survey of transformation and removal during wastewater treatment and implications for wastewater management.

  16. Process to remove rare earth from IFR electrolyte

    DOE Patents [OSTI]

    Ackerman, John P. (Downers Grove, IL); Johnson, Terry R. (Wheaton, IL)

    1994-01-01

    The invention is a process for the removal of rare earths from molten chloride electrolyte salts used in the reprocessing of integrated fast reactor fuel (IFR). The process can be used either continuously during normal operation of the electrorefiner or as a batch process. The process consists of first separating the actinide values from the salt before purification by removal of the rare earths. After replacement of the actinides removed in the first step, the now-purified salt electrolyte has the same uranium and plutonium concentration and ratio as when the salt was removed from the electrorefiner.

  17. Process to remove rare earth from IFR electrolyte

    DOE Patents [OSTI]

    Ackerman, J.P.; Johnson, T.R.

    1994-08-09

    The invention is a process for the removal of rare earths from molten chloride electrolyte salts used in the reprocessing of integrated fast reactor fuel (IFR). The process can be used either continuously during normal operation of the electrorefiner or as a batch process. The process consists of first separating the actinide values from the salt before purification by removal of the rare earths. After replacement of the actinides removed in the first step, the now-purified salt electrolyte has the same uranium and plutonium concentration and ratio as when the salt was removed from the electrorefiner. 1 fig.

  18. Study on removal of organic sulfur compound by modified activated carbon

    SciTech Connect (OSTI)

    Fan Huiling; Li Chunhu; Guo Hanxian [Taiyuan Univ. of Technology (China). Research Inst. for Chemical Engineering of Coal

    1997-12-31

    With the price of coal increasing in China, more and more small and medium scale chemical plants are turning to high sulfur coal as the raw material in order to cut cost. However, the major drawback is that the lifetime of the ammonia synthesis catalyst is then reduced greatly because of the high concentration of the sulfur compounds in the synthesis gas, especially organic sulfur, usually CS{sub 2} and COS. The effects of water vapor and experimental temperature on removal of organic sulfur compounds by using a modified activated carbon were studied in this paper. It was found that water vapor had a negative effect on removal of carbon disulfide by activated carbon impregnated with organic amine. The use of activated carbon impregnated with K{sub 2}CO{sub 3} for removal of carbonyl sulfide was also investigated over the temperature range 30--60, the results show a favorable temperature (40) existing for carbonyl sulfide removal. Fixed-bed breakthrough curves for the adsorbent bed were also offered in this paper.

  19. Preliminary study of iron removal from hydrochloric pickling liquor by ion exchange

    SciTech Connect (OSTI)

    Maranon, E.; Suarez, F.; Alonso, F.; Fernandez, Y.; Sastre, H. [Univ. of Oviedo, Asturias (Spain). Dept. of Chemical and Environmental Engineering] [Univ. of Oviedo, Asturias (Spain). Dept. of Chemical and Environmental Engineering

    1999-07-01

    Hydrochloric acid from exhausted pickling baths is a residue that has to be managed adequately because of its high pollutant potential. In this work, an ion exchange treatment for removing iron from the spent acid was studied in an attempt to make the re-utilization of said acid viable for industry while reducing the amount of waste generated. Several cationic, anionic, and chelating resins were tested. Cationic and chelating resins are able to remove Fe(II) that is present as a cation in the acid, whereas anionic resins are able to remove Fe(III) that forms anionic complexes with the chloride anion. The capacity of the cationic and chelating resins, although not high, does improve as the iron concentration in the hydrochloric acid increases and when the acid concentration decreases, because there is less competition between the ferrous cation and the protons. The anionic resins showed higher capacity for removing iron, especially the Lewatit MP-500, and this capacity also increased with iron concentration.

  20. Method of removing oxidized contaminants from water

    DOE Patents [OSTI]

    Amonette, J.E.; Fruchter, J.S.; Gorby, Y.A.; Cole, C.R.; Cantrell, K.J.; Kaplan, D.I.

    1998-07-21

    The present invention is a method for removing oxidized contaminant(s) from water. More specifically, the invention has the steps of contacting water containing the oxidized contaminant(s) with a layered aluminosilicate having Fe(II). The aluminosilicate may contain naturally occurring Fe(II), or the Fe(II) may be produced by reducing Fe(III) that is initially present. Reduction may be either by exposure to a chemical or biological reductant. Contacting the water containing oxidized contaminant(s) may be by (1) injection of Fe(II)-containing layered aluminosilicate, via a well, into a saturated zone where it is likely to intercept the contaminated water; (2) injection of contaminated water into a vessel containing the Fe(II)-bearing layered aluminosilicate; and (3) first reducing Fe(III) in the layered aluminosilicate to Fe(II) by injection of a biological or chemical reductant, into an aquifer or vessel having sufficient Fe(III)-bearing aluminosilicate to produce the necessary Fe(II). 8 figs.

  1. Method of removing oxidized contaminants from water

    DOE Patents [OSTI]

    Amonette, James E. (Richland, WA); Fruchter, Jonathan S. (Richland, WA); Gorby, Yuri A. (Richland, WA); Cole, Charles R. (West Richmond, WA); Cantrell, Kirk J. (West Richmond, WA); Kaplan, Daniel I. (Richland, WA)

    1998-01-01

    The present invention is a method for removing oxidized contaminant(s) from water. More specifically, the invention has the steps of contacting water containing the oxidized contaminant(s) with a layered aluminosilicate having Fe(II). The aluminosilicate may contain naturally occurring Fe(II), or the Fe(II) may be produced by reducing Fe(III) that is initially present. Reduction may be either by exposure to a chemical or biological reductant. Contacting the water containing oxidized contaminant(s) may be by (1) injection of Fe(II)-containing layered aluminosilicate, via a well, into a saturated zone where it is likely to intercept the contaminated water; (2) injection of contaminated water into a vessel containing the Fe(II)-bearing layered aluminosilicate; and (3) first reducing Fe(III) in the layered aluminosilicate to Fe(II) by injection of a biological or chemical reductant, into an aquifer or vessel having sufficient Fe(III)-bearing aluminosilicate to produce the necessary Fe(II).

  2. Improved Processes to Remove Naphthenic Acids

    SciTech Connect (OSTI)

    Aihua Zhang; Qisheng Ma; Kangshi Wang; Yongchun Tang; William A. Goddard

    2005-12-09

    In the past three years, we followed the work plan as we suggested in the proposal and made every efforts to fulfill the project objectives. Based on our large amount of creative and productive work, including both of experimental and theoretic aspects, we received important technical breakthrough on naphthenic acid removal process and obtained deep insight on catalytic decarboxylation chemistry. In detail, we established an integrated methodology to serve for all of the experimental and theoretical work. Our experimental investigation results in discovery of four type effective catalysts to the reaction of decarboxylation of model carboxylic acid compounds. The adsorption experiment revealed the effectiveness of several solid materials to naphthenic acid adsorption and acidity reduction of crude oil, which can be either natural minerals or synthesized materials. The test with crude oil also received promising results, which can be potentially developed into a practical process for oil industry. The theoretical work predicted several possible catalytic decarboxylation mechanisms that would govern the decarboxylation pathways depending on the type of catalysts being used. The calculation for reaction activation energy was in good agreement with our experimental measurements.

  3. Debris Engine: A Potential Thruster for Space Debris Removal

    E-Print Network [OSTI]

    Lan, Lei; Baoyin, Hexi

    2015-01-01

    We present a design concept for a space engine that can continuously remove the orbit debris by using the debris as a propellant. Space robotic cleaner is adopted to capture the targeting debris and to transfer them into the engine. Debris with larger size is first disintegrated into small pieces by using a mechanical method. The planetary ball mill is then adopted to grind the pieces into micrometer or smaller powder. The energy needed in this process is get from the nuclear and solar power. By the effect of gamma-ray photoelectric or the behavior of tangently rub of tungsten needles, the debris powered is charged. This behavior can be used to speed up the movement of powder in a tandem electrostatic particle accelerator. By ejecting the high-temperture and high-pressure charged powered from the nozzle of the engine,the continuously thrust is obtained. This thrust can be used to perform orbital maneuver and debris rendezvous for the spacecraft and robotic cleaner. The ejected charged particle will be blown a...

  4. Remedial action plan and site design for stabilization of the inactive uranium processing site at Naturita, Colorado. Attachment 3, Groundwater hydrology report, Attachment 4, Water resources protection strategy: Preliminary final

    SciTech Connect (OSTI)

    Not Available

    1993-08-01

    The US Environmental Protection Agency (EPA) has established health and environmental protection regulations to correct and prevent groundwater contamination resulting from processing activities at inactive uranium milling sites (40 CFR 192). The Uranium Mill Tailings Radiation Control Act (UMTRCA) of 1978 designated responsibility to the US Department of Energy (DOE) for assessing the inactive uranium milling sites. The DOE has determined that each assessment shall include information on site characterization, a description of the proposed action, and a summary of the water resources protection strategy that describes how the proposed action will comply with the EPA groundwater protection standards. To achieve compliance with the proposed US Environmental Protection Agency (EPA) groundwater protection standards, the US Department of Energy (DOE) proposes that supplemental standards be applied at the Dry Flats disposal site because of Class III (limited use) groundwater in the uppermost aquifer (the basal sandstone of the Cretaceous Burro Canyon Formation) based on low yield. The proposed remedial action will ensure protection of human health and the environment.

  5. Remedial action plan for the inactive uranium processing site at Naturita, Colorado. Remedial action selection report: Attachment 2, geology report; Attachment 3, ground water hydrology report; Attachment 4, supplemental information

    SciTech Connect (OSTI)

    1998-03-01

    The uranium processing site near Naturita, Colorado, is one of 24 inactive uranium mill sites designated to be cleaned up by the U.S. Department of Energy (DOE) under the Uranium Mill Tailings Radiation Control Act of 1978 (UMTRCA), 42 USC {section} 7901 et seq. Part of the UMTRCA requires that the U.S. Nuclear Regulatory Commission (NRC) concur with the DOE`s remedial action plan (RAP) and certify that the remedial action conducted at the site complies with the standards promulgated by the U.S. Environmental Protection Agency (EPA). This RAP serves two purposes. First, it describes the activities that are proposed by the DOE to accomplish remediation and long-term stabilization and control of the radioactive materials at the inactive uranium processing site near Naturita, Colorado. Second, this RAP, upon concurrence and execution by the DOE, the state of Colorado, and the NRC, becomes Appendix B of the cooperative agreement between the DOE and the state of Colorado.

  6. Passive shut-down heat removal system

    DOE Patents [OSTI]

    Hundal, Rolv (Greensburg, PA); Sharbaugh, John E. (Bullskin Township, Fayette County, PA)

    1988-01-01

    An improved shut-down heat removal system for a liquid metal nuclear reactor of the type having a vessel for holding hot and cold pools of liquid sodium is disclosed herein. Generally, the improved system comprises a redan or barrier within the reactor vessel which allows an auxiliary heat exchanger to become immersed in liquid sodium from the hot pool whenever the reactor pump fails to generate a metal-circulating pressure differential between the hot and cold pools of sodium. This redan also defines an alternative circulation path between the hot and cold pools of sodium in order to equilibrate the distribution of the decay heat from the reactor core. The invention may take the form of a redan or barrier that circumscribes the inner wall of the reactor vessel, thereby defining an annular space therebetween. In this embodiment, the bottom of the annular space communicates with the cold pool of sodium, and the auxiliary heat exchanger is placed in this annular space just above the drawn-down level that the liquid sodium assumes during normal operating conditions. Alternatively, the redan of the invention may include a pair of vertically oriented, concentrically disposed standpipes having a piston member disposed between them that operates somewhat like a pressure-sensitive valve. In both embodiments, the cessation of the pressure differential that is normally created by the reactor pump causes the auxiliary heat exchanger to be immersed in liquid sodium from the hot pool. Additionally, the redan in both embodiments forms a circulation flow path between the hot and cold pools so that the decay heat from the nuclear core is uniformly distributed within the vessel.

  7. Process for removing metal carbonyls from gaseous streams

    SciTech Connect (OSTI)

    Heyd, R.L.; Pignet, T.P.

    1988-04-26

    A process for removing metal carbonyl contaminates from a gaseous stream is described containing such contaminates and which is free from sulfur contaminates, which process comprises contacting the gaseous stream with a zinc sulfide absorbent to thereby remove metal carbonyl contaminates from the gaseous stream, and separating the gaseous stream from the zinc sulfide absorbent.

  8. EBeam Irradiation for Water Reuse: Removal of Bromate 

    E-Print Network [OSTI]

    Wang, Li

    2015-07-28

    Beam) irradiation has been investigated in areas including both bacterial/viral disinfection and chemical contaminant removal. However, eBeam research on BrO3- removal is limited. Particularly, the application of eBeam to water reuse has not been investigated...

  9. Removal of Estrogenic Pollutants from Contaminated Water Using

    E-Print Network [OSTI]

    Chen, Wilfred

    Removal of Estrogenic Pollutants from Contaminated Water Using Molecularly Imprinted Polymers Z I H that this material may be appropriate for treating a complex mixture of estrogenic pollutants. The feasibility of removing estrogenic compounds from environmental water by the MIP was demonstrated using lake water spiked

  10. Method for removing chlorine compounds from hydrocarbon mixtures

    DOE Patents [OSTI]

    Janoski, E.J.; Hollstein, E.J.

    1984-09-29

    A process for removing halide ions from a hydrocarbon feedstream containing halogenated hydrocarbons wherein the contaminated feedstock is contacted with a solution of a suitable oxidizing acid containing a lanthanide oxide, the acid being present in a concentration of at least about 50 weight percent for a time sufficient to remove substantially all of the halide ion from the hydrocarbon feedstock.

  11. Process for removing pyritic sulfur from bituminous coals

    DOE Patents [OSTI]

    Pawlak, Wanda (Edmonton, CA); Janiak, Jerzy S. (Edmonton, CA); Turak, Ali A. (Edmonton, CA); Ignasiak, Boleslaw L. (Edmonton, CA)

    1990-01-01

    A process is provided for removing pyritic sulfur and lowering ash content of bituminous coals by grinding the feed coal, subjecting it to micro-agglomeration with a bridging liquid containing heavy oil, separating the microagglomerates and separating them to a water wash to remove suspended pyritic sulfur. In one embodiment the coal is subjected to a second micro-agglomeration step.

  12. Process for selected gas oxide removal by radiofrequency catalysts

    DOE Patents [OSTI]

    Cha, C.Y.

    1993-09-21

    This process to remove gas oxides from flue gas utilizes adsorption on a char bed subsequently followed by radiofrequency catalysis enhancing such removal through selected reactions. Common gas oxides include SO[sub 2] and NO[sub x]. 1 figure.

  13. Water supplier copes with lead paint removal regs

    SciTech Connect (OSTI)

    Becker, C.E. ); Lovejoy, D.R.; Bryck, J.L.; Rockensies, W.H.

    1993-12-01

    This article examines new paint removal methods that minimize releasing of paints containing lead to the environment and lead free coating systems for tank corrosion protection used in the Village of Freeport in Long Island, New York. The topics of the article include coating failures, removal tools and methods, paint and application methods.

  14. Removal of residual particulate matter from filter media

    DOE Patents [OSTI]

    Almlie, Jay C; Miller, Stanley J

    2014-11-11

    A method for removing residual filter cakes that remain adhered to a filter after typical particulate removal methodologies have been employed, such as pulse-jet filter element cleaning, for all cleanable filters used for air pollution control, dust control, or powder control.

  15. UNL/OSU Researchers Try Promising Technique to Remove Groundwater

    E-Print Network [OSTI]

    Nebraska-Lincoln, University of

    UNL/OSU Researchers Try Promising Technique to Remove Groundwater Contamination Under Former Oklahoma State University have joined to test promising new methods of removing longstanding groundwater into specially drilled injection wells, where it mixes with contaminants in the groundwater under the former

  16. ITER HEAT REMOVAL SYSTEM SYSTEM & PROCESS CONTROL DESIGN

    E-Print Network [OSTI]

    Raffray, A. René

    in-vessel component cooling systems malfunction. Therefore, special design criteria are requestedITER HEAT REMOVAL SYSTEM SYSTEM & PROCESS CONTROL DESIGN Y. Hoshi 1 , Y. Kataoka 2 , V. Tanchuk 1 the vacuum vessel cooling system has a safety role of providing the ultimate decay heat removal system ,when

  17. Removal of radium from acidic solutions containing same by adsorption on coal fly ash

    DOE Patents [OSTI]

    Scheitlin, Frank M. (Oak Ridge, TN)

    1984-01-01

    The invention is a process for the removal of radium from acidic aqueous solutions. In one aspect, the invention is a process for removing radium from an inorganic-acid solution. The process comprises contacting the solution with coal fly ash to effect adsorption of the radium on the ash. The radium-containing ash then is separated from the solution. The process is simple, comparatively inexpensive, and efficient. High radium-distribution coefficients are obtained even at room temperature. Coal fly ash is an inexpensive, acid-resistant, high-surface-area material which is available in large quantities throughout the United States. The invention is applicable, for example, to the recovery of .sup.226 Ra from nitric acid solutions which have been used to leach radium from uranium-mill tailings.

  18. REMOVAL OF ORGANIC POLLUTANTS FROM SUBCRITICAL WATER WITH ACTIVATED CARBON

    SciTech Connect (OSTI)

    Steven B. Hawthorne; Arnaud J. Lagadec

    1999-08-01

    The Energy & Environmental Research Center (EERC) has demonstrated that controlling the temperature (and to a lesser extent, the pressure) of water can dramatically change its ability to extract organics and inorganics from matrices ranging from soils and sediments to waste sludges and coal. The dielectric constant of water can be changed from about 80 (a very polar solvent) to <5 (similar to a nonpolar organic solvent) by controlling the temperature (from ambient to about 400 C) and pressure (from about 5 to 350 bar). The EERC has shown that hazardous organic pollutants such as pesticides, PACS (polycyclic aromatic hydrocarbons), and PCBs (polychlorinated biphenyls) can be completely removed from soils, sludges, and sediments at temperatures (250 C) and pressures (<50 atm) that are much milder than typically used for supercritical water processes (temperature >374 C, pressure >221 atm). In addition, the process has been demonstrated to be particularly effective for samples containing very high levels of contaminants (e.g., part per thousand). Current projects include demonstrating the subcritical water remediation process at the pilot scale using an 8-liter system constructed under separate funding during 1997. To date, subcritical water has been shown to be an effective extraction fluid for removing a variety of organic pollutants from soils and sludges contaminated with fossil fuel products and waste products, including PACS from soil (e.g., town gas sites), refining catalysts, and petroleum tank bottom sludges; PCBs from soil and sediments; toxic gasoline components (e.g., benzene) from soil and waste sludge; and phenols from petroleum refinery sludges. The obvious need to clean the wastewater from subcritical water processes led to preliminary experiments with activated carbon placed in line after the extractor. Initial experiments were performed before and after cooling the extractant water (e.g., with water at 200 C and with water cooled to 25 C). Surprisingly, the ability of activated carbon to remove organics from the water is better at a high temperature than at room temperature. These initial results are opposite to those expected from chromatographic theory, since the solubility of the organics is about 100,000-fold higher in the hot water than in ambient water. At present, the physicochemical mechanism accounting for these results is unknown; however, it is possible that the lower surface tension and lower viscosity of subcritical water (compared to water at ambient conditions) greatly increases the available area of the carbon by several orders of magnitude. Regardless of the mechanism involved, the optimal use of activated carbon to clean the wastewater generated from subcritical water remediation will depend on obtaining a better understanding of the controlling parameters. While these investigations focused on the cleanup of wastewater generated from subcritical water remediation, the results also apply to cleanup of any wastewater contaminated with nonpolar and moderately polar organics such as wastewaters from coal and petroleum processing.

  19. Enhanced Organic Precursor Removals Using "Aged" Filter Media Page 1 Enhanced Organic Precursor Removals Using "Aged" Filter Media

    E-Print Network [OSTI]

    OH. Fresh buffered water and influent solution were prepared prior to each filter challenge. C. CoagulatedEnhanced Organic Precursor Removals Using "Aged" Filter Media Page 1 Enhanced Organic Precursor Removals Using "Aged" Filter Media O b j e c t i v e s The main goals of this project was to evaluate

  20. Arsenic Removal Using AgedArsenic Removal Using Aged Rapid Sand Filter MediaRapid Sand Filter Media

    E-Print Network [OSTI]

    Arsenic Removal Using AgedArsenic Removal Using Aged Rapid Sand Filter MediaRapid Sand Filter Media byby C. Menard, D. Burt, M.R. CollinsC. Menard, D. Burt, M.R. Collins Water Treatment Technology Assistance CenterWater Treatment Technology Assistance Center Department of Civil Engineering

  1. Silica coated magnetite nanoparticles for removal of heavy metal ions from polluted waters

    E-Print Network [OSTI]

    Dash, Monika

    2013-01-01

    Magnetic removal of Hg2+ and other heavy metal ions like Cd2+, Pb2+ etc. using silica coated magnetite particles from polluted waters is a current topic of active research to provide efficient water recycling and long term high quality water. The technique used to study the bonding characteristics of such kind of nanoparticles with the heavy metal ions is a very sensitive hyperfine specroscopy technique called the perturbed angular correlation technique (PAC).

  2. INVESTIGATION OF MIXED METAL SORBENT/CATALYSTS FOR THE SIMULTANEOUS REMOVAL OF SULFUR AND NITROGEN OXIDES

    SciTech Connect (OSTI)

    Ates Akyurtlu; Jale F. Akyurtle

    2001-08-01

    Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}.

  3. Selective ammonia slip catalyst enabling highly efficient NOx...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    enabling highly efficient NOx removal requirements of the future A low precious metal loading ammonia-slip catalyst was developed that is able to oxidize the ammonia that...

  4. Controlled epitaxial graphene growth within removable amorphous carbon corrals

    SciTech Connect (OSTI)

    Palmer, James; Hu, Yike; Hankinson, John; Guo, Zelei; Heer, Walt A. de; Kunc, Jan; Berger, Claire

    2014-07-14

    We address the question of control of the silicon carbide (SiC) steps and terraces under epitaxial graphene on SiC and demonstrate amorphous carbon (aC) corrals as an ideal method to pin SiC surface steps. aC is compatible with graphene growth, structurally stable at high temperatures, and can be removed after graphene growth. For this, aC is first evaporated and patterned on SiC, then annealed in the graphene growth furnace. There at temperatures above 1200?°C, mobile SiC steps accumulate at the aC corral that provide effective step flow barriers. Aligned step free regions are thereby formed for subsequent graphene growth at temperatures above 1330?°C. Atomic force microscopy imaging supports the formation of step-free terraces on SiC with the step morphology aligned to the aC corrals. Raman spectroscopy indicates the presence of good graphene sheets on the step-free terraces.

  5. Passive removal of manganese from acid mine drainage

    SciTech Connect (OSTI)

    Brant, D.L.; Ziemkiewicz, P.F. [West Virginia Univ., Morgantown, WV (United States)

    1997-12-31

    Removal of manganese (Mn) from mine drainage is difficult due to the abnormal chemistry of the element. The removal requires the oxidation of Mn(II) (the form found in mine drainage) to the more oxidized forms (Mn(III) or Mn(IV)). The more oxidized forms exist only as solids and will not return to Mn(II) spontaneously. Chemical treatment of Mn often requires a pH near 10 to initiate the oxidation quickly. A stabilized pH of 10 normally causes more harm to aquatic organisms than the Mn and is not desirable, making additional steps in the treatment necessary. Biological removal of Mn can be achieved at near neutral pH levels. The Shade Mining site in Somerset County, PA has been treating Mn to discharge limits since the early 1990`s (reducing Mn concentrations from 12 - 25 mg/L in the influent to <2 mg/L in the effluent). The treatment system consists of an anoxic limestone drain discharging into a wetland to remove iron, aluminum, and acidity, while increasing pH and alkalinity. The wetland effluent flows into two limestone beds (Mn removal). The limestone beds developed a black slime coating as the Mn removal increased. This system continues to remove Mn in all weather conditions and has not required chemical treatment since the black coating appeared on the limestone. A laboratory study was conducted using limestone collected from the Shade site to use the same naturally occurring Mn oxidizing microbes. The lab study compared W removal rates of microbial oxidation, MnO{sub 2} catalyzed limestone, and fresh uncoated limestone. The microbial removal performed the best (25 mg/L Mn reduced to <2 mg/L in 72 hours).

  6. Duct Remediation Program: Material characterization and removal/handling

    SciTech Connect (OSTI)

    Beckman, T.d.; Davis, M.M.; Karas, T.M.

    1992-11-01

    Remediation efforts were successfully performed at Rocky Flats to locate, characterize, and remove plutonium holdup from process exhaust ducts. Non-Destructive Assay (NDA) techniques were used to determine holdup locations and quantities. Visual characterization using video probes helped determine the physical properties of the material, which were used for remediation planning. Assorted equipment types, such as vacuum systems, scoops, brushes, and a rotating removal system, were developed to remove specific material types. Personnel safety and material handling requirements were addressed throughout the project.

  7. Northwest Plume Groundwater System Green-sand Media Removal and Waste Packaging Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    Troutman, M.T.; Richards, C.J.; Tarantino, J.J. [CDM Federal Programs Corporation, 325 Kentucky Avenue, Kevil, KY 42053 (United States)

    2006-07-01

    The Northwest Plume Groundwater System (NWPGS) was temporarily shut down due to high differential pressures across the green-sand filters. Increased levels of suspended solids were introduced into the system from monitoring well development water, equipment decontamination water, and secondary containment water. These waters were treated for suspended solids through a groundwater pretreatment system but were suspected of causing the high differential pressures in the green-sand filters. Prior to the system being shutdown, the NWPGS had been experiencing increasingly shorter run times between filter backwashes indicating that the normal backwash cycle was not adequately removing the fines. This condition led to the removal and replacement of green-sand media from two filter vessels. Discussions include problems with the removal process, waste packaging specifications, requirements for the disposition of green-sand media, and lessons learned. (authors)

  8. Removal of Radioactive Nuclides from Mo-99 Acidic Liquid Waste - 13027

    SciTech Connect (OSTI)

    Hsiao, Hsien-Ming; Pen, Ben-Li

    2013-07-01

    About 200 liters highly radioactive acidic liquid waste originating from Mo-99 production was stored at INER (Institute of Nuclear Energy Research). A study regarding the treatment of the radioactive acidic liquid waste was conducted to solve storage-related issues and allow discharge of the waste while avoiding environmental pollution. Before discharging the liquid waste, the acidity, NO{sub 3}{sup -} and Hg ions in high concentrations, and radionuclides must comply with environmental regulations. Therefore, the treatment plan was to neutralize the acidic liquid waste, remove key radionuclides to reduce the dose rate, and then remove the nitrate and mercury ions. Bench tests revealed that NaOH is the preferred solution to neutralize the high acidic waste solution and the pH of solution must be adjusted to 9?11 prior to the removal of nuclides. Significant precipitation was produced when the pH of solution reached 9. NaNO{sub 3} was the major content in the precipitate and part of NaNO{sub 3} was too fine to be completely collected by filter paper with a pore size of approximately 3 ?m. The residual fine particles remaining in solution therefore blocked the adsorption column during operation. Two kinds of adsorbents were employed for Cs-137 and a third for Sr-90 removal to minimize cost. For personnel radiation protection, significant lead shielding was required at a number of points in the process. The final process design and treatment facilities successfully treated the waste solutions and allowed for environmentally compliant discharge. (authors)

  9. The Gas-Cooled Fast Reactor: Report on Safety System Design for Decay Heat Removal

    SciTech Connect (OSTI)

    K. D. Weaver; T. Marshall; T. Y. C. Wei; E. E. Feldman; M. J. Driscoll; H. Ludewig

    2003-09-01

    The gas-cooled fast reactor (GFR) was chosen as one of the Generation IV nuclear reactor systems to be developed based on its excellent potential for sustainability through reduction of the volume and radiotoxicity of both its own fuel and other spent nuclear fuel, and for extending/utilizing uranium resources orders of magnitude beyond what the current open fuel cycle can realize. In addition, energy conversion at high thermal efficiency is possible with the current designs being considered, thus increasing the economic benefit of the GFR. However, research and development challenges include the ability to use passive decay heat removal systems during accident conditions, survivability of fuels and in-core materials under extreme temperatures and radiation, and economical and efficient fuel cycle processes. This report addresses/discusses the decay heat removal options available to the GFR, and the current solutions. While it is possible to design a GFR with complete passive safety (i.e., reliance solely on conductive and radiative heat transfer for decay heat removal), it has been shown that the low power density results in unacceptable fuel cycle costs for the GFR. However, increasing power density results in higher decay heat rates, and the attendant temperature increase in the fuel and core. Use of active movers, or blowers/fans, is possible during accident conditions, which only requires 3% of nominal flow to remove the decay heat. Unfortunately, this requires reliance on active systems. In order to incorporate passive systems, innovative designs have been studied, and a mix of passive and active systems appears to meet the requirements for decay heat removal during accident conditions.

  10. Investigation of mixed metal sorbent/catalysts for the simultaneous removal of sulfur and nitrogen oxides

    SciTech Connect (OSTI)

    Akyurtlu, A.; Akyurtlu, J.F.

    1999-03-31

    Simultaneous removal of SO{sub 2} and NO{sub x} using a regenerable solid sorbent will constitute an important improvement over the use of separate processes for the removal of these two pollutants from stack gases and possibly eliminate several shortcomings of the individual SO{sub 2} and NO{sub x} removal operations. The work done at PETC and the DOE-funded investigation of the investigators on the sulfation and regeneration of alumina-supported cerium oxide sorbents have shown that they can perform well at relatively high temperatures (823-900 K) as regenerable desulfurization sorbents. Survey of the recent literature shows that addition of copper oxide to ceria lowers the sulfation temperature of ceria down to 773 K, sulfated ceria-based sorbents can function as selective SCR catalysts even at elevated temperatures, SO{sub 2} can be directly reduced to sulfur by CO on CuO-ceria catalysts, and ceria-based catalysts may have a potential for selective catalytic reduction of NO{sub x} by methane. These observations indicate a possibility of developing a ceria-based sorbent/catalyst which can remove both SO{sub 2} and NO{sub x} from flue gases within a relatively wide temperature window, produce significant amounts of elemental sulfur during regeneration, and use methane for the selective catalytic reduction of NO{sub x}. The objective of this research is to conduct kinetic and parametric studies of the selective catalytic reduction of NO{sub x} with NH{sub 3} and CH{sub 4} over alumina-supported cerium oxide and copper oxide-cerium oxide sorbent/catalysts; investigate SO{sub 2} removal at lower temperatures by supported copper oxide-cerium oxide sorbents; and investigate the possibility of elemental sulfur production during regeneration with CO or with CH{sub 4}-air mixtures.

  11. Removal of carbonyl sulfide from liquid hydrocarbon streams

    SciTech Connect (OSTI)

    Damron, E.; Mick, M.B.; Woodall, R.M.

    1981-09-22

    Carbonyl sulfide is removed from propane and other similar liquefied petroleum gas products by mixing liquid methanol with the untreated liquefied gas and then contacting the liquid mixture with solid potassium hydroxide.

  12. Method to remove uranium/vanadium contamination from groundwater

    DOE Patents [OSTI]

    Metzler, Donald R. (DeBeque, CO); Morrison, Stanley (Grand Junction, CO)

    2004-07-27

    A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

  13. Removal Rate Model for Magnetorheological Finishing of Glass

    SciTech Connect (OSTI)

    DeGroote, J.E.; Marino, A.E.; WIlson, J.P.; Bishop, A.L.; Lambropoulos, J.C.; Jacobs, S.D.

    2007-11-14

    Magnetorheological finishing (MRF) is a deterministic subaperture polishing process. The process uses a magntorheological (MR) fluid that consists of micrometer-sized, spherical, magnetic carbonyl iron (CI) particles, nonmagnetic polishing abrasives, water, and stabilizers. Material removal occurs when the CI and nonmagnetic polishing abrasives shear material off the surface being polished. We introduce a new MRF material removal rate model for glass. This model contains terms for the near surface mechanical properties of glass, drag force, polishing abrasive size and concentration, chemical durability of the glass, MR fluid pH, and the glass composition. We introduce quantitative chemical predictors for the first time, to the best of our knowledge, into an MRF removal rate model. We validate individual terms in our model separately and then combine all of the terms to show the whole MRF material removal model compared with experimental data. All of our experimental data were obtained using nanodiamond MR fluids and a set of six optical glasses.

  14. Massive Hanford Test Reactor Removed - Plutonium Recycle Test...

    Energy Savers [EERE]

    challenge on the U.S. Department of Energy's (DOE) Hanford Site by removing a 1,082-ton nuclear test reactor from the 300 Area. The River Corridor is a 220-square-mile section of...

  15. Lab sets new record for waste volume removed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the waste were removed, and 220 shipments were sent to WIPP. The data represents the fourth year in a row that the Lab has set new LANL records for TRU waste shipments. Next...

  16. BOD5 removal in subsurface flow constructed wetlands 

    E-Print Network [OSTI]

    Melton, Rebecca Hobbs

    2005-08-29

    advanced or secondary treatment of domestic wastewater. The pollutant removal efficiency in SFCW depends on design parameters. Many of these factors have been investigated while others such as aspect ratio, design of water inlet structure and method...

  17. Ozone Removal by Filters Containing Activated Carbon: A Pilot Study

    E-Print Network [OSTI]

    Fisk, William

    2012-01-01

    removing particulate matter. ANSI/ASHRAE standard 52.1-1992efficiency by particle size. ANSI/ASHRAE Standard 52.2-1999.GA, ASHRAE. ASHRAE (2007). ANSI/ASHRAE Standard 62.1.

  18. Method to Remove Uranium/Vanadium Contamination from Groundwater

    DOE Patents [OSTI]

    Metzler, Donald R.; Morrison Stanley

    2004-07-27

    A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

  19. Process for the removal of acid gases from gaseous streams

    SciTech Connect (OSTI)

    Blytas, G.C.; Diaz, Z.

    1982-11-16

    Hydrogen sulfide, carbon dioxide, and carbonyl sulfide are removed from a gas stream in a staged procedure by: absorption of the CO/sub 2/ and COS; conversion of the hydrogen sulfide to produce sulfur in an absorbent mixture; hydrolysis of the carbonyl sulfide to produce a gas stream of hydrogen sulfide and carbon dioxide; and removal of the hydrogen sulfide from the gas stream.

  20. Radiator debris removing apparatus and work machine using same

    DOE Patents [OSTI]

    Martin, Kevin L. (Washburn, IL); Elliott, Dwight E. (Chillicothe, IL)

    2008-09-02

    A radiator assembly includes a finned radiator core and a debris removing apparatus having a compressed air inlet and at least one compressed air outlet configured to direct compressed air through the radiator core. A work machine such as a wheel loader includes a radiator and a debris removing apparatus coupled with on-board compressed air and having at least one pressurized gas outlet configured to direct a gas toward the face of the radiator.

  1. Process for removing heavy metal compounds from heavy crude oil

    DOE Patents [OSTI]

    Cha, Chang Y. (Golden, CO); Boysen, John E. (Laramie, WY); Branthaver, Jan F. (Laramie, WY)

    1991-01-01

    A process is provided for removing heavy metal compounds from heavy crude oil by mixing the heavy crude oil with tar sand; preheating the mixture to a temperature of about 650.degree. F.; heating said mixture to up to 800.degree. F.; and separating tar sand from the light oils formed during said heating. The heavy metals removed from the heavy oils can be recovered from the spent sand for other uses.

  2. Method for removing oxide contamination from titanium diboride powder

    DOE Patents [OSTI]

    Brynestad, Jorulf (Oak Ridge, TN); Bamberger, Carlos E. (Oak Ridge, TN)

    1984-01-01

    A method for removing oxide contamination from titanium diboride powder involves the direct chemical treatment of TiB.sub.2 powders with a gaseous boron halide, such as BCl.sub.3, at temperatures in the range of 500.degree.-800.degree. C. The BCl.sub.3 reacts with the oxides to form volatile species which are removed by the BCl.sub.3 exit stream.

  3. Fluidized bed gasification ash reduction and removal system

    DOE Patents [OSTI]

    Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

    1984-02-28

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  4. Fluidized bed gasification ash reduction and removal process

    DOE Patents [OSTI]

    Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

    1984-12-04

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  5. Solid materials for removing arsenic and method thereof

    SciTech Connect (OSTI)

    Coronado, Paul R. (Livermore, CA); Coleman, Sabre J. (Oakland, CA); Sanner, Robert D. (Livermore, CA); Dias, Victoria L. (Livermore, CA); Reynolds, John G. (San Ramon, CA)

    2008-07-01

    Solid materials have been developed to remove arsenic compounds from aqueous media. The arsenic is removed by passing the aqueous phase through the solid materials which can be in molded, granular, or powder form. The solid materials adsorb the arsenic leaving a purified aqueous stream. The materials are aerogels or xerogels and aerogels or xerogels and solid support structure, e.g., granulated activated carbon (GAC), mixtures. The species-specific adsorption occurs through specific chemical modifications of the solids tailored towards arsenic.

  6. Solid materials for removing arsenic and method thereof

    DOE Patents [OSTI]

    Coronado, Paul R. (Livermore, CA); Coleman, Sabre J. (Oakland, CA); Sanner, Robert D. (Livermore, CA); Dias, Victoria L. (Livermore, CA); Reynolds, John G. (San Ramon, CA)

    2010-09-28

    Solid materials have been developed to remove arsenic compounds from aqueous media. The arsenic is removed by passing the aqueous phase through the solid materials which can be in molded, granular, or powder form. The solid materials adsorb the arsenic leaving a purified aqueous stream. The materials are aerogels or xerogels and aerogels or xerogels and solid support structure, e.g., granulated activated carbon (GAC), mixtures. The species-specific adsorption occurs through specific chemical modifications of the solids tailored towards arsenic.

  7. Method and apparatus for the removal or bioconversion of constituents of organic liquids

    DOE Patents [OSTI]

    Scott, T.; Scott, C.D.

    1994-10-25

    A method and apparatus are disclosed for the removal or conversion of constituents from bulk organic liquids. A countercurrent biphasic bioreactor system is utilized to disperse and recoalesce a biocatalyst contained in the aqueous liquid phase into the organic liquid phase containing the constituent. Two transient, high-intensity electrical fields rupture the aqueous drops into a plurality of microdroplets and induce continuous coalescence and redispersion as the microdroplets travel through the organic phase, thus increasing surface area. As the aqueous microdroplets progress through the organic phase, the biocatalyst then reacts with the constituent to produce a product which is then removed from the bioreactor in the aqueous phase or retained in the organic phase. The organic liquid, now free of the original constituents, is ready for immediate use or further processing. 1 fig.

  8. Development of Acetic Acid Removal Technology for the UREX+Process

    SciTech Connect (OSTI)

    Robert M. Counce; Jack S. Watson

    2009-06-30

    It is imperative that acetic acid is removed from a waste stream in the UREX+process so that nitric acid can be recycled and possible interference with downstreatm steps can be avoidec. Acetic acid arises from acetohydrozamic acid (AHA), and is used to suppress plutonium in the first step of the UREX+process. Later, it is hydrolyzed into hydroxyl amine nitrate and acetic acid. Many common separation technologies were examined, and solvent extraction was determined to be the best choice under process conditions. Solvents already used in the UREX+ process were then tested to determine if they would be sufficient for the removal of acetic acid. The tributyl phosphage (TBP)-dodecane diluent, used in both UREX and NPEX, was determined to be a solvent system that gave sufficient distribution coefficients for acetic acid in addition to a high separation factor from nitric acid.

  9. Design Strategies and Preliminary Prototype for a Low-Cost Arsenic Removal System for Rural Bangladesh

    SciTech Connect (OSTI)

    Mathieu, Johanna L.; Gadgil, Ashok J.; Kowolik, Kristin; Qazi, Shefah; Agogino, Alice M.

    2009-09-14

    Researchers have invented a material called ARUBA -- Arsenic Removal Using Bottom Ash -- that effectively and affordably removes arsenic from Bangladesh groundwater. Through analysis of studies across a range of disciplines, observations, and informal interviews conducted over three trips to Bangladesh, we have applied mechanical engineering design methodology to develop eight key design strategies, which were used in the development of a low-cost, community-scale water treatment system that uses ARUBA to removearsenic from drinking water. We have constructed, tested, and analysed a scale version of the system. Experiments have shown that the system is capable of reducing high levels of arsenic (nearly 600 ppb) to below the Bangladesh standard of 50 ppb, while remaining affordable to people living on less than US$2/day. The system could be sustainably implemented as a public-private partnership in rural Bangladesh.

  10. Treated bottom ash medium and method of arsenic removal from drinking water

    DOE Patents [OSTI]

    Gadgil, Ashok (El Cerrito, CA)

    2009-06-09

    A method for low-cost arsenic removal from drinking water using chemically prepared bottom ash pre-treated with ferrous sulfate and then sodium hydroxide. Deposits on the surface of particles of bottom ash form of activated iron adsorbent with a high affinity for arsenic. In laboratory tests, a miniscule 5 grams of pre-treated bottom ash was sufficient to remove the arsenic from 2 liters of 2400 ppb (parts per billion) arsenic-laden water to a level below 50 ppb (the present United States Environmental Protection Agency limit). By increasing the amount of pre-treated bottom ash, even lower levels of post-treatment arsenic are expected. It is further expected that this invention supplies a very low-cost solution to arsenic poisoning for large population segments.

  11. Decay Heat Removal in GEN IV Gas-Cooled Fast Reactors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cheng, Lap-Yan; Wei, Thomas Y. C.

    2009-01-01

    The safety goal of the current designs of advanced high-temperature thermal gas-cooled reactors (HTRs) is that no core meltdown would occur in a depressurization event with a combination of concurrent safety system failures. This study focused on the analysis of passive decay heat removal (DHR) in a GEN IV direct-cycle gas-cooled fast reactor (GFR) which is based on the technology developments of the HTRs. Given the different criteria and design characteristics of the GFR, an approach different from that taken for the HTRs for passive DHR would have to be explored. Different design options based on maintaining core flow weremore »evaluated by performing transient analysis of a depressurization accident using the system code RELAP5-3D. The study also reviewed the conceptual design of autonomous systems for shutdown decay heat removal and recommends that future work in this area should be focused on the potential for Brayton cycle DHRs.« less

  12. Removal of gadolinium nitrate from heavy water

    SciTech Connect (OSTI)

    Wilde, E.W.

    2000-03-22

    Work was conducted to develop a cost-effective process to purify 181 55-gallon drums containing spent heavy water moderator (D2O) contaminated with high concentrations of gadolinium nitrate, a chemical used as a neutron poison during former nuclear reactor operations at the Savannah River Site (SRS). These drums also contain low level radioactive contamination, including tritium, which complicates treatment options. Presently, the drums of degraded moderator are being stored on site. It was suggested that a process utilizing biological mechanisms could potentially lower the total cost of heavy water purification by allowing the use of smaller equipment with less product loss and a reduction in the quantity of secondary waste materials produced by the current baseline process (ion exchange).

  13. Cesium Removal at Fukushima Nuclear Plant - 13215

    SciTech Connect (OSTI)

    Braun, James L.; Barker, Tracy A. [Avantech Incorporated, 95A Sunbelt Blvd Columbia, SC 29203 (United States)] [Avantech Incorporated, 95A Sunbelt Blvd Columbia, SC 29203 (United States)

    2013-07-01

    The Great East Japan Earthquake that took place on March 11, 2011 created a number of technical challenges at the Fukushima Daiichi Nuclear Plant. One of the primary challenges involved the treatment of highly contaminated radioactive wastewater. Avantech Inc. developed a unique patent pending treatment system that addressed the numerous technical issues in an efficient and safe manner. Our paper will address the development of the process from concept through detailed design, identify the lessons learned, and provide the updated results of the project. Specific design and operational parameters/benefits discussed in the paper include: - Selection of equipment to address radionuclide issues; - Unique method of solving the additional technical issues associated with Hydrogen Generation and Residual Heat; - Operational results, including chemistry, offsite discharges and waste generation. Results show that the customized process has enabled the utility to recycle the wastewater for cooling and reuse. This technology had a direct benefit to nuclear facilities worldwide. (authors)

  14. SLUDGE HEEL REMOVAL BY ALUMINUM DISSOLUTION AT SAVANNAH RIVER SITE 12390

    SciTech Connect (OSTI)

    Keefer, M.

    2012-01-12

    High Level Waste (HLW) at the Savannah River Site (SRS) is currently stored in aging underground storage tanks. This waste is a complex mixture of insoluble solids, referred to as sludge, and soluble salts. Continued long-term storage of these radioactive wastes poses an environmental risk. Operations are underway to remove and disposition the waste, clean the tanks and fill with grout for permanent closure. Heel removal is the intermediate phase of the waste retrieval and tank cleaning process at SRS, which is intended to reduce the volume of waste prior to treatment with oxalic acid. The goal of heel removal is to reduce the residual amount of radioactive sludge wastes to less than 37,900 liters (10,000 gallons) of wet solids. Reducing the quantity of residual waste solids in the tank prior to acid cleaning reduces the amount of acid required and reduces the amount of excess acid that could impact ongoing waste management processes. Mechanical heel removal campaigns in Tank 12 have relied solely on the use of mixing pumps that have not been effective at reducing the volume of remaining solids. The remaining waste in Tank 12 is known to have a high aluminum concentration. Aluminum dissolution by caustic leaching was identified as a treatment step to reduce the volume of remaining solids and prepare the tank for acid cleaning. Dissolution was performed in Tank 12 over a two month period in July and August, 2011. Sample results indicated that 16,440 kg of aluminum oxide (boehmite) had been dissolved representing 60% of the starting inventory. The evolution resulted in reducing the sludge solids volume by 22,300 liters (5900 gallons), preparing the tank for chemical cleaning with oxalic acid.

  15. Multiple pollutant removal using the condensing heat exchanger: Phase 1 final report, October 1995--July 1997

    SciTech Connect (OSTI)

    Bailey, R.T.; Jankura, B.J.; Kudlac, G.A.

    1998-06-01

    The Integrated Flue Gas Treatment (IFGT) system is a new concept whereby a Teflon{reg_sign} covered condensing heat exchanger is adapted to remove certain flue gas constitutents, both particulate and gaseous, while recovering low level heat. Phase 1 includes two experimental tasks. One task dealt principally with the pollutant removal capabilities of the IFGT at a scale of about 1.2MW{sub t}. The other task studied the durability of the Teflon{reg_sign} covering to withstand the rigors of abrasive wear by fly ash emitted as a result of coal combustion. The pollutant removal characteristics of the IFGT system were measured over a wide range of operating conditions. The coals tested included high, medium and low-sulfur coals. The flue gas pollutants studied included ammonia, hydrogen chloride, hydrogen fluoride, particulate, sulfur dioxide, gas phase and particle phase mercury and gas phase and particle phase trace elements. The particulate removal efficiency and size distribution was investigated. These test results demonstrated that the IFGT system is an effective device for both acid gas absorption and fine particulate collection. The durability of the Teflon{reg_sign} covered heat exchanger tubes was studied on a pilot-scale single-stage condensing heat exchanger (CHX{reg_sign}). Data from the test indicate that virtually no decrease in Teflon{reg_sign} thickness was observed for the coating on the first two rows of heat exchanger tubes, even at high inlet particulate loadings. Evidence of wear was present only at the microscopic level, and even then was very minor in severity.

  16. A method for removing arm backscatter from EPID images

    SciTech Connect (OSTI)

    King, Brian W. [School of Mathematical and Physics Sciences, University of Newcastle, Newcastle, New South Wales 2308 (Australia); Greer, Peter B. [Department of Radiation Oncology, Calvary Mater Newcastle Hospital, Newcastle, New South Wales 2310 (Australia); School of Mathematical and Physical Sciences, University of Newcastle, Newcastle, New South Wales 2308 (Australia)

    2013-07-15

    Purpose: To develop a method for removing the support arm backscatter from images acquired using current Varian electronic portal imaging devices (EPIDs).Methods: The effect of arm backscatter on EPID images was modeled using a kernel convolution method. The parameters of the model were optimized by comparing on-arm images to off-arm images. The model was used to develop a method to remove the effect of backscatter from measured EPID images. The performance of the backscatter removal method was tested by comparing backscatter corrected on-arm images to measured off-arm images for 17 rectangular fields of different sizes and locations on the imager. The method was also tested using on- and off-arm images from 42 intensity modulated radiotherapy (IMRT) fields.Results: Images generated by the backscatter removal method gave consistently better agreement with off-arm images than images without backscatter correction. For the 17 rectangular fields studied, the root mean square difference of in-plane profiles compared to off-arm profiles was reduced from 1.19% (standard deviation 0.59%) on average without backscatter removal to 0.38% (standard deviation 0.18%) when using the backscatter removal method. When comparing to the off-arm images from the 42 IMRT fields, the mean {gamma} and percentage of pixels with {gamma} < 1 were improved by the backscatter removal method in all but one of the images studied. The mean {gamma} value (1%, 1 mm) for the IMRT fields studied was reduced from 0.80 to 0.57 by using the backscatter removal method, while the mean {gamma} pass rate was increased from 72.2% to 84.6%.Conclusions: A backscatter removal method has been developed to estimate the image acquired by the EPID without any arm backscatter from an image acquired in the presence of arm backscatter. The method has been shown to produce consistently reliable results for a wide range of field sizes and jaw configurations.

  17. Horizontal Heat Exchanger Design and Analysis for Passive Heat Removal Systems

    SciTech Connect (OSTI)

    Vierow, Karen

    2005-08-29

    This report describes a three-year project to investigate the major factors of horizontal heat exchanger performance in passive containment heat removal from a light water reactor following a design basis accident LOCA (Loss of Coolant Accident). The heat exchanger studied in this work may be used in advanced and innovative reactors, in which passive heat removal systems are adopted to improve safety and reliability The application of horizontal tube-bundle condensers to passive containment heat removal is new. In order to show the feasibility of horizontal heat exchangers for passive containment cooling, the following aspects were investigated: 1. the condensation heat transfer characteristics when the incoming fluid contains noncondensable gases 2. the effectiveness of condensate draining in the horizontal orientation 3. the conditions that may lead to unstable condenser operation or highly degraded performance 4. multi-tube behavior with the associated secondary-side effects This project consisted of two experimental investigations and analytical model development for incorporation into industry safety codes such as TRAC and RELAP. A physical understanding of the flow and heat transfer phenomena was obtained and reflected in the analysis models. Two gradute students (one funded by the program) and seven undergraduate students obtained research experience as a part of this program.

  18. Development of NF3 Deposit Removal Technology for the Portsmouth Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Scheele, R.D.; McNamara, B.K.; Rapko, B.M.; Edwards, M.K.; Kozelisky, A.E.; Daniel, R.C. [Battelle Pacific Northwest Division, PO Box 999, Battelle Blvd, Richland, Washington 99352 (United States); McSweeney, T.I.; Maharas, S.J.; Weaver, P.J.; Iwamasa, K.J. [Battelle Columbus Operations, 505 King Avenue, Columbus, Ohio 43201 (United States); Kefgen, R.B. [WASTREN, Inc., 1864 Shyville Road, Piketon, Ohio 45661 (United States)

    2006-07-01

    This paper summarizes the Battelle, Stoller, and WASTREN (BSW) team's efforts, to date, in support of the United States Department of Energy's plans to remove uranium and technetium deposits before decommissioning the Portsmouth Gaseous Diffusion Plant. The BSW team investigated nitrogen trifluoride (NF{sub 3}) as a safer yet effective alternative gaseous treatment to the chlorine trifluoride (ClF{sub 3})-elemental fluorine (F{sub 2}) treatment currently used to remove uranium and technetium deposits from the uranium enrichment cascade. Both ClF{sub 3} and F{sub 2} are highly reactive, toxic, and hazardous gases, while NF{sub 3}, although toxic [1], is no more harmful than moth balls [2]. BSW's laboratory thermo-analytical and laboratory-scale prototype studies with NF{sub 3} established that thermal NF{sub 3} can effectively remove likely and potential uranium (UO{sub 2}F{sub 2} and UF{sub 4}) and technetium deposits (a surrogate deposit material, TcO{sub 2}, and pertechnetates) by conversion to volatile compounds. Our engineering evaluations suggest that NF{sub 3}'s effectiveness could be enhanced by combining with a lesser concentration of ClF{sub 3}. BSW's and other's studies indicate compatibility with Portsmouth materials of construction (aluminum, copper, and nickel). (authors)

  19. FULL-SCALE TREATMENT WETLANDS FOR METAL REMOVAL FROM INDUSTRIAL WASTEWATER

    SciTech Connect (OSTI)

    Nelson, E; John Gladden, J

    2007-03-22

    The A-01 NPDES outfall at the Savannah River Site receives process wastewater discharges and stormwater runoff from the Savannah River National Laboratory. Routine monitoring indicated that copper concentrations were regularly higher than discharge permit limit, and water routinely failed toxicity tests. These conditions necessitated treatment of nearly one million gallons of water per day plus storm runoff. Washington Savannah River Company personnel explored options to bring process and runoff waters into compliance with the permit conditions, including source reduction, engineering solutions, and biological solutions. A conceptual design for a constructed wetland treatment system (WTS) was developed and the full-scale system was constructed and began operation in 2000. The overall objective of our research is to better understand the mechanisms of operation of the A-01 WTS in order to provide better input to design of future systems. The system is a vegetated surface flow wetland with a hydraulic retention time of approximately 48 hours. Copper, mercury, and lead removal efficiencies are very high, all in excess of 80% removal from water passing through the wetland system. Zinc removal is 60%, and nickel is generally unaffected. Dissolved organic carbon in the water column is increased by the system and reduces toxicity of the effluent. Concentrations of metals in the A-01 WTS sediments generally decrease with depth and along the flow path through the wetland. Sequential extraction results indicate that most metals are tightly bound to wetland sediments.

  20. Mobile system for microwave removal of concrete surfaces

    DOE Patents [OSTI]

    White, Terry L. (Oak Ridge, TN); Bigelow, Timothy S. (Knoxville, TN); Schaich, Charles R. (Lenoir City, TN); Foster, Jr., Don (Knoxville, TN)

    1997-01-01

    A method and apparatus for the microwave removal of contaminated concrete surfaces. The apparatus comprises a housing adapted to pass over a support surface. The housing includes a waveguide for directing microwave energy to the surface at an angle maximizing absorption of microwave energy by the surface. The apparatus is further provided with a source of microwave energy operably associated with the waveguide, wherein the microwave energy has a frequency of between about 10.6 GHz and about 24 GHz and acts to remove the uppermost layer from the surface. The apparatus further includes a debris containment assembly comprising a vacuum assembly operably associated with the housing. The vacuum assembly is adapted to remove debris from the area adjacent the surface.

  1. Metal chelate process to remove pollutants from fluids

    DOE Patents [OSTI]

    Chang, S.G.T.

    1994-12-06

    The present invention relates to improved methods using an organic iron chelate to remove pollutants from fluids, such as flue gas. Specifically, the present invention relates to a process to remove NO[sub x] and optionally SO[sub 2] from a fluid using a metal ion (Fe[sup 2+]) chelate wherein the ligand is a dimercapto compound wherein the --SH groups are attached to adjacent carbon atoms (HS--C--C--SH) or (SH--C--CCSH) and contain a polar functional group so that the ligand of DMC chelate is water soluble. Alternatively, the DMC is covalently attached to a water insoluble substrate such as a polymer or resin, e.g., polystyrene. The chelate is regenerated using electroreduction or a chemical additive. The dimercapto compound bonded to a water insoluble substrate is also useful to lower the concentration or remove hazardous metal ions from an aqueous solution. 26 figures.

  2. Evaluation of Alternatives for Hanford 327 Building Hot Cell Removal and Transport

    SciTech Connect (OSTI)

    Stevens, Ray W.; Jasen, William G.

    2003-02-27

    The Department of Energy (DOE) Hanford site 327 Building, built in 1953, played a key role in reactor material and fuel research programs. The facility includes nine shielded hot cells, a fuel storage basin, dry sample storage, and a large inerted hot (SERF) cell. In 1996, the 327 Building was transferred from Pacific Northwest National Laboratory (PNNL) to Fluor Hanford, Inc., to begin the transition from the mission of irradiated fuel examination to stabilization and deactivation. In 2001, a multi-contractor team conducted a review of the concept of intact (one piece) removal, packaging, and disposal of the 327 hot cells. This paper focuses on challenges related to preparing the 327 Building hot cells for intact one-piece disposal as Low Level Waste (LLW) at the Hanford Site. These challenges, described in this paper, are threefold and include: Sampling and characterization of the cells for low level waste designation; Packaging of the cells for transportation and waste disposal; Transportation from the facility to the disposal site. The primary technical challenges in one-piece removal, packaging, and disposal of the hot cells involve the techniques required to characterize, remove, handle, package and transport a large (approximately up to 12-feet long and 8-feet high) contaminated object that weighs 35 to 160 tons. Specific characterization results associated with two hot cells, G and H cells will be reported. A review of the activities and plans to stabilize and deactivate the 327 Building provides insight into the technical challenges faced by this project and identifies a potential opportunity to modify the baseline strategy by removing the hot cells in one piece instead of decontaminating and dismantling the cells.

  3. Compositions and methods for removing arsenic in water

    DOE Patents [OSTI]

    Gadgil, Ashok Jagannth (El Cerrito, CA)

    2011-02-22

    Compositions and methods and for contaminants from water are provided. The compositions comprise ferric hydroxide and ferric oxyhydride coated substrates for use in removing the contaminant from the water. Contacting water bearing the contaminant with the substrates can substantially reduce contaminant levels therein. Methods of oxidizing the contaminants in water to facilitate their removal by the ferric hydroxide and ferric oxyhydride coated substrates are also provided. The contaminants include, but are not limited to, arsenic, selenium, uranium, lead, cadmium, nickel, copper, zinc, chromium and vanadium, their oxides and soluble salts thereof.

  4. Method for removal of beryllium contamination from an article

    SciTech Connect (OSTI)

    Simandl, Ronald F.; Hollenbeck, Scott M.

    2012-12-25

    A method of removal of beryllium contamination from an article is disclosed. The method typically involves dissolving polyisobutylene in a solvent such as hexane to form a tackifier solution, soaking the substrate in the tackifier to produce a preform, and then drying the preform to produce the cleaning medium. The cleaning media are typically used dry, without any liquid cleaning agent to rub the surface of the article and remove the beryllium contamination below a non-detect level. In some embodiments no detectible residue is transferred from the cleaning wipe to the article as a result of the cleaning process.

  5. Methods of hydrotreating a liquid stream to remove clogging compounds

    DOE Patents [OSTI]

    Minderhoud, Johannes Kornelis [Amsterdam, NL; Nelson, Richard Gene [Katy, TX; Roes, Augustinus Wilhelmus Maria [Houston, TX; Ryan, Robert Charles [Houston, TX; Nair, Vijay [Katy, TX

    2009-09-22

    A method includes producing formation fluid from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a gas stream. At least a portion of the liquid stream is provided to a hydrotreating unit. At least a portion of selected in situ heat treatment clogging compositions in the liquid stream are removed to produce a hydrotreated liquid stream by hydrotreating at least a portion of the liquid stream at conditions sufficient to remove the selected in situ heat treatment clogging compositions.

  6. Method for the removal and recovery of mercury

    DOE Patents [OSTI]

    Easterly, C.E.; Vass, A.A.; Tyndall, R.L.

    1997-01-28

    The present invention is an enhanced method for the removal and recovery of mercury from mercury-contaminated matrices. The method involves contacting a mercury-contaminated matrix with an aqueous dispersant solution derived from specific intra-amoebic isolates to release the mercury from the mercury-contaminated matrix and emulsify the mercury; then, contacting the matrix with an amalgamating metal from a metal source to amalgamate the mercury to the amalgamating metal; removing the metallic source from the mercury-contaminated matrix; and heating the metallic source to vaporize the mercury in a closed system to capture the mercury vapors.

  7. Method for removing undesired particles from gas streams

    DOE Patents [OSTI]

    Durham, Michael Dean (Castle Rock, CO); Schlager, Richard John (Aurora, CO); Ebner, Timothy George (Westminster, CO); Stewart, Robin Michele (Arvada, CO); Hyatt, David E. (Denver, CO); Bustard, Cynthia Jean (Littleton, CO); Sjostrom, Sharon (Denver, CO)

    1998-01-01

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

  8. Method for removing semiconductor layers from salt substrates

    DOE Patents [OSTI]

    Shuskus, Alexander J. (West Hartford, CT); Cowher, Melvyn E. (East Brookfield, MA)

    1985-08-27

    A method is described for removing a CVD semiconductor layer from an alkali halide salt substrate following the deposition of the semiconductor layer. The semiconductor-substrate combination is supported on a material such as tungsten which is readily wet by the molten alkali halide. The temperature of the semiconductor-substrate combination is raised to a temperature greater than the melting temperature of the substrate but less than the temperature of the semiconductor and the substrate is melted and removed from the semiconductor by capillary action of the wettable support.

  9. Simultaneous SO2, SO3 and NOx removal by the EBA Process

    SciTech Connect (OSTI)

    Hirano, S.; Aoki, S.; Izutsu, M.; Yuki, Y.

    1999-07-01

    The system for electron beam flue gas treatment, the EBA (Electron Beam with Ammonia) Process is an innovative, dry, air pollution control technology that, by ammonia injection and electron beam irradiation, can efficiently remove sulfur oxides, (SOx, i.e., SO2 and SO3), from partially humidified flue gas. This is accompanied by simultaneous nitrogen oxides, (NOx), emission reduction in an amount that is determined, optionally, by site-specific system design. The process operation converts these pollutants as well as gasborne hydrogen chloride into a dry by-product solids consisting principally of ammonium sulfate, ammonium nitrate and ammonium chloride that can be used, worldwide, as a plant nutrient stock in large-scale agriculture. Commercial application of the Process has now been achieved, utilizing engineering data gained over many years of experience in operation of pilot plant facilities (including a process development unit that was field installed in the 1980s under sponsorship by US DOE at a coal-fired powerplant of Indianapolis Power and Light Company). With the co-operation of the Chinese government, EBARA Corporation has in 1997 completed the first commercial EBA Process installation, which is sited at the coal-fired Chengdu Power Station in China. This retrofit facility as a whole in addition to its performance in this high-sulfur bituminous coal service, including the targeted SOx removal efficiency, incidental NOx abatement and the usability of the by-product, were assessed and fully accepted contractually by a diversely structured, Examination Committee established by Chinese government authorities and assisted by an Expert Group. Criteria and considerations of the Chinese officials, in evaluating adequacy of the technology for further commercial application in China, all assessed positively, encompassed design, installation, operation, performance, reliability, environmental impact, cost effectiveness and by-product utilization/marketing. To illustrate attractive process economics for SOx removal in high-sulfur service with only incidental NOx removal, i.e. FGD (flue gas desulfurization) only, evaluation of cost-effectiveness of the Chengdu facility (at its moderate design SO2 removal efficiency) is presented.

  10. Subtask 1.23 - Mercury Removal from Barite the Oil Industry

    SciTech Connect (OSTI)

    Michael Holmes; Carolyn Nyberg; Katie Brandt; Kurt Eylands; Nathan Fiala; Grant Dunham

    2008-09-01

    Drilling muds are used by the oil and gas industry to provide a seal and to float rock chips to the surface during the drilling process. Barite (naturally occurring barium sulfate ore) is commonly used as a weighting agent additive in drilling muds because it is chemically nonreactive and has a high specific gravity (between 4.2 and 4.25 at 20 C). Because of environmental concerns, barite used by the oil and gas industry in the Gulf of Mexico must be certified to contain less than 1 mg/kg of mercury. Faced with these regulations, the U.S. Gulf Coast oil industry has looked to foreign sources of low-mercury barite, primarily India and China. These sources tend to have high-grade barite deposits and relatively inexpensive domestic transportation costs; as of late, however, U.S. purchasers have been forced to pay increasing costs for shipping to U.S. grinding plants. The objective of this project was to demonstrate two mercury removal techniques for high-mercury barite sources. Two barite samples of unique origins underwent processing to reduce mercury to required levels. The chemical treatment with dilute acid removed a portion of the mercury in both barite samples. The desired concentration of 1 mg/kg was achieved in both barite samples. An economic analysis indicates that thermal removal of mercury would not significantly add to the cost of barite processing, making higher-mercury barite a viable alternative to more expensive barite sources that contain lower concentrations of mercury.

  11. Precipitate hydrolysis process for the removal of organic compounds from nuclear waste slurries

    DOE Patents [OSTI]

    Doherty, Joseph P. (Elkton, MD); Marek, James C. (Augusta, GA)

    1989-01-01

    A process for removing organic compounds from a nuclear waste slurry comprising reacting a mixture of radioactive waste precipitate slurry and an acid in the presence of a catalytically effective amount of a copper (II) catalyst whereby the organic compounds in the precipitate slurry are hydrolyzed to form volatile organic compounds which are separated from the reacting mixture. The resulting waste slurry, containing less than 10 percent of the orginal organic compounds, is subsequently blended with high level radioactive sludge and transferred to a virtrification facility for processing into borosilicate glass for long-term storage.

  12. Precipitate hydrolysis process for the removal of organic compounds from nuclear waste slurries

    DOE Patents [OSTI]

    Doherty, J.P.; Marek, J.C.

    1987-02-25

    A process for removing organic compounds from a nuclear waste slurry comprising reacting a mixture of radioactive waste precipitate slurry and an acid in the presence of a catalytically effective amount of a copper(II) catalyst whereby the organic compounds in the precipitate slurry are hydrolyzed to form volatile organic compounds which are separated from the reacting mixture. The resulting waste slurry, containing less than 10 percent of the original organic compounds, is subsequently blended with high level radioactive sludge land transferred to a vitrification facility for processing into borosilicate glass for long-term storage. 2 figs., 3 tabs.

  13. The effect of removal of Sigmodon hispidus on microhabitat utilization by Baiomys taylori and Reithrodontomys fulvescens 

    E-Print Network [OSTI]

    Turner, Clarence LaVerne

    1982-01-01

    flay 1981, except duri ng November. All cotton rats were removed from 2 grids beginning January 1981. Grid points were classified using cluster analysis into 1 of 8 microhabi tats during winter (January ? February) and 1 of 7 mi crohabi tats during... spring (March ? Bh(ay) based on plant speci es cover in 3 vertical stats within a 2 m radius of each grid point. During winter& cotCon raCs and pigmy mice pre fered microhabi Cats in which brownseed paspalum cover was high. During winter, Fulvous...

  14. Reconditioning of semiconductor substrates to remove photoresist during semiconductor device fabrication

    DOE Patents [OSTI]

    Farino, Anthony J.

    2004-01-27

    A method for reconditioning the surface of a semiconductor substrate to remove an unwanted (i.e. defective) layer of photoresist is disclosed. The method adapts a conventional automated spinner which is used to rotate the substrate at high speed while a stream of a first solvent (e.g. acetone) is used to dissolve the photoresist. A stream of a second solvent (e.g. methanol) is then used to clean the substrate at a lower speed, with the substrate being allowed to dry with continued rotation. The method of the present invention can be used within a photolithography track so that the substrates need never leave the track for reconditioning.

  15. Removal of pertechnetate from simulated nuclear waste streams using supported zerovalent iron

    SciTech Connect (OSTI)

    Darab, John; Amonette, Alexandra; Burke, Deborah; Orr, Robert; Ponder, Sherman; Schrick, Bettina; Mallouk, Thomas; Lukens, Wayne; Caulder, Dana; Shuh, David

    2007-07-11

    The application of nanoparticles of predominantly zerovalent iron (nanoiron), either unsupported or supported, to the separation and reduction of pertechnetate anions (TcO4-) from complex waste mixtures was investigated as an alternative approach to current waste-processing schemes. Although applicable to pertechnetate-containing waste streams in general, the research discussed here was directed at two specific potential applications at the U.S. Department of Energy's Hanford Site: (1) the direct removal of pertechnetate from highly alkaline solutions, typical of those found in Hanford tank waste, and (2) the removal of dilute pertechnetate from near-neutral solutions, typical of the eluate streams from commercial organic ion-exchange resins that may be used to remediate Hanford tank wastes. It was envisioned that both applications would involve the subsequent encapsulation of the loaded sorbent material into a separate waste form. A high surface area (>200 M2/g) base-stable, nanocrystalline zirconia was used as a support for nanoiron for tests with highly alkaline solutions, while a silica gel support was used for tests with near-neutral solutions. It was shown that after 24 h of contact time, the high surface area zirconia supported nanoiron sorbent removed about 50percent (K-d = 370 L/kg) of the pertechnetate from a pH 14 tank waste simulant containing 0.51 mM TCO4- and large concentrations of Na+, OH-, NO3-, and CO32- for a phase ratio of 360 L simulant per kg of sorbent. It was also shown that after 18 h of contact time, the silica-supported nanoiron removed>95percent pertechnetate from a neutral pH eluate simulant containing 0.076 mM TcO4_ for a phase ratio of 290 L/kg. It was determined that in all cases, nanoiron reduced the Tc(VII) to Tc(IV), or possibly to Tc(V), through a redox reaction. Finally, it was demonstrated that a mixture of 20 mass percent of the solid reaction products obtained from contacting zirconia- supported nanoiron with an alkaline waste solution containing Re(VII), a surrogate for Tc(VII), with 80 mass percent alkali borosilicate based frit heat-treated at 700 degrees C for 4 h sintered into an easily handled glass composite waste form.

  16. Simultaneous Removal of Particulates and NOx Using Catalyst Impregnated Fibrous Ceramic Filters

    SciTech Connect (OSTI)

    Choi, J.I.; Mun, S.H.; Kim, S.T.; Hong, M.S.; Lee, J.C.

    2002-09-19

    The research is focused on the development and commercialization of high efficiency, cost effective air pollution control system, which can replace in part air pollution control devices currently in use. In many industrial processes, hot exhaust gases are cooled down to recover heat and to remove air pollutants in exhaust gases. Conventional air pollution control devices such as bag filters, E.P. and adsorption towers withstand operating temperatures up to 300 C. Also, reheating is sometimes necessary to meet temperature windows for S.C.R. Since Oxidation reactions of acid gases such as SO{sub 2}, and HCl with lime are enhanced at high temperatures, catalyst impregnated ceramic filters can be candidate for efficient and cost effective air pollution control devices. As shown on Fig. 1., catalytic ceramic filters remove particulates on exterior surface of filters and acid gases are oxidized to salts reacting with limes injected in upstream ducts. Oxidation reactions are enhanced in the cake formed on exterior of filters. Finally, injected reducing gas such as NH{sub 3} react with NOx to form N{sub 2} and H{sub 2}O interior of filters in particulate-free environment. Operation and maintenance technology is similar to conventional bag filters except that systems are exposed to relatively high temperatures ranging 300-500 C.

  17. Remedial action plan and site design for stabilization of the inactive uranium processing site at Naturita, Colorado. Remedial Action Selection Report, Appendix B of Attachment 2: Geology report, Final

    SciTech Connect (OSTI)

    Not Available

    1994-03-01

    The uranium processing site near Naturita, Colorado, is one of 24 inactive uranium mill sites designated to be cleaned up by the US Department of Energy (DOE) under the Uranium Mill Tailings Radiation Control Act of 1978 (UMTRCA), 42 USC {section} 7901 et seq. Part of the UMTRCA requires that the US Nuclear Regulatory Commission (NRC) concur with the DOE`s remedial action plan (RAP) and certify that the remedial action conducted at the site complies with the standards promulgated by the US Environmental Protection Agency (EPA). Included in the RAP is this Remedial Action Selection Report (RAS), which describes the proposed remedial action for the Naturita site. An extensive amount of data and supporting information has been generated and evaluated for this remedial action. These data and supporting information are not incorporated into this single document but are included or referenced in the supporting documents. The RAP consists of this RAS and four supporting documents or attachments. This Attachment 2, Geology Report describes the details of geologic, geomorphic, and seismic conditions at the Dry Flats disposal site.

  18. Technical note Barriers and opportunities for passive removal of indoor ozone

    E-Print Network [OSTI]

    Siegel, Jeffrey

    Technical note Barriers and opportunities for passive removal of indoor ozone Elliott T. Gall presents a Monte Carlo simulation to assess passive removal materials (PRMs) that remove ozone of homes in Houston, Texas, were taken from the literature and combined with back- ground ozone removal

  19. Pentek metal coating removal system: Baseline report; Greenbook (chapter)

    SciTech Connect (OSTI)

    1997-07-31

    The Pentek coating removal technology was tested and is being evaluated at Florida International University (FIU) as a baseline technology. In conjunction with FIU`s evaluation of efficiency and cost, this report covers evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The Pentek coating removal system consisted of the ROTO-PEEN Scaler, CORNER-CUTTER{reg_sign}, and VAC-PAC{reg_sign}. They are designed to remove coatings from steel, concrete, brick, and wood. The Scaler uses 3M Roto Peen tungsten carbide cutters while the CORNER-CUTTER{reg_sign} uses solid needles for descaling activities. These hand tools are used with the VAC-PAC{reg_sign} vacuum system to capture dust and debris as removal of the coating takes place. The safety and health evaluation during the testing demonstration focused on two main areas of exposure: dust and noise. Dust exposure minimal, but noise exposure was significant. Further testing for each exposure is recommended because of the environment where the testing demonstration took place. It is feasible that the dust and noise levels will be higher in an enclosed operating environment of different construction. In addition, other areas of concern found were arm-hand vibration, whole-body, ergonomics, heat stress, tripping hazards, electrical hazards, machine guarding, and lockout/tagout.

  20. Thief process for the removal of mercury from flue gas

    DOE Patents [OSTI]

    Pennline, Henry W. (Bethel Park, PA); Granite, Evan J. (Wexford, PA); Freeman, Mark C. (South Park Township, PA); Hargis, Richard A. (Canonsburg, PA); O'Dowd, William J. (Charleroi, PA)

    2003-02-18

    A system and method for removing mercury from the flue gas of a coal-fired power plant is described. Mercury removal is by adsorption onto a thermally activated sorbent produced in-situ at the power plant. To obtain the thermally activated sorbent, a lance (thief) is inserted into a location within the combustion zone of the combustion chamber and extracts a mixture of semi-combusted coal and gas. The semi-combusted coal has adsorptive properties suitable for the removal of elemental and oxidized mercury. The mixture of semi-combusted coal and gas is separated into a stream of gas and semi-combusted coal that has been converted to a stream of thermally activated sorbent. The separated stream of gas is recycled to the combustion chamber. The thermally activated sorbent is injected into the duct work of the power plant at a location downstream from the exit port of the combustion chamber. Mercury within the flue gas contacts and adsorbs onto the thermally activated sorbent. The sorbent-mercury combination is removed from the plant by a particulate collection system.

  1. Particulate contamination removal from wafers using plasmas and mechanical agitation

    DOE Patents [OSTI]

    Selwyn, Gary S. (Los Alamos, NM)

    1998-01-01

    Particulate contamination removal from wafers using plasmas and mechanical agitation. The present invention includes the use of plasmas with mechanical agitation for removing particulate matter from the surface of a wafer. The apparatus hereof comprises a mechanical activator, at least one conducting contact pin for transferring the vibration from the activator to the wafer, clamp fingers that maintain the wafer's position, and means for generating a plasma in the vicinity of the surface of the wafer, all parts of the cleaning apparatus except the mechanical activator and part of the contact pin being contained inside the processing chamber. By exposing a wafer to a plasma and providing motion thereto in a direction perpendicular to its surface, the bonding between the particulate matter and the surface may be overcome. Once free of the wafer surface, the particulates become charged by electrons from the plasma and are drawn into the plasma by attractive forces which keep them from redepositing. The introduction of a flowing gas through the plasma sweeps the particulates away from the wafer and out of the plasma. The entire surface is cleaned during one cleaning step. The use of an rf plasma to accomplish the particulate removal was found to remove more than 90% of the particulates.

  2. Particulate contamination removal from wafers using plasmas and mechanical agitation

    DOE Patents [OSTI]

    Selwyn, G.S.

    1998-12-15

    Particulate contamination removal from wafers is disclosed using plasmas and mechanical agitation. The present invention includes the use of plasmas with mechanical agitation for removing particulate matter from the surface of a wafer. The apparatus hereof comprises a mechanical activator, at least one conducting contact pin for transferring the vibration from the activator to the wafer, clamp fingers that maintain the wafer`s position, and means for generating a plasma in the vicinity of the surface of the wafer, all parts of the cleaning apparatus except the mechanical activator and part of the contact pin being contained inside the processing chamber. By exposing a wafer to a plasma and providing motion thereto in a direction perpendicular to its surface, the bonding between the particulate matter and the surface may be overcome. Once free of the wafer surface, the particulates become charged by electrons from the plasma and are drawn into the plasma by attractive forces which keep them from redepositing. The introduction of a flowing gas through the plasma sweeps the particulates away from the wafer and out of the plasma. The entire surface is cleaned during one cleaning step. The use of an rf plasma to accomplish the particulate removal was found to remove more than 90% of the particulates. 4 figs.

  3. Removal of Pollutants by Atmospheric Non Thermal Plasmas

    E-Print Network [OSTI]

    Khacef, Ahmed; Pouvesle, Jean Michel; Van, Tiep Le

    2008-01-01

    Results on the application of non thermal plasmas in two environmentally important fields: oxidative removal of VOC and NOx in excess of oxygen were presented. The synergetic application of a plasma-catalytic treatment of NOx in excess of oxygen is also described.

  4. On automated prepared statement generation to remove SQL injection vulnerabilities

    E-Print Network [OSTI]

    Xie, Tao

    On automated prepared statement generation to remove SQL injection vulnerabilities Stephen Thomas in revised form 5 August 2008 Accepted 8 August 2008 Available online 27 September 2008 Keywords: SQL vulnerabilities were SQL injection vulnerabilities (SQLIVs). This paper presents an algorithm of prepared

  5. Magnetic process for removing heavy metals from water employing magnetites

    DOE Patents [OSTI]

    Prenger, F. Coyne; Hill, Dallas D.; Padilla, Dennis D.; Wingo, Robert M.; Worl, Laura A.; Johnson, Michael D.

    2003-07-22

    A process for removing heavy metals from water is provided. The process includes the steps of introducing magnetite to a quantity of water containing heavy metal. The magnetite is mixed with the water such that at least a portion of, and preferably the majority of, the heavy metal in the water is bound to the magnetite. Once this occurs the magnetite and absorbed metal is removed from the water by application of a magnetic field. In most applications the process is achieved by flowing the water through a solid magnetized matrix, such as steel wool, such that the magnetite magnetically binds to the solid matrix. The magnetized matrix preferably has remnant magnetism, but may also be subject to an externally applied magnetic field. Once the magnetite and associated heavy metal is bound to the matrix, it can be removed and disposed of, such as by reverse water or air and water flow through the matrix. The magnetite may be formed in-situ by the addition of the necessary quantities of Fe(II) and Fe(III) ions, or pre-formed magnetite may be added, or a combination of seed and in-situ formation may be used. The invention also relates to an apparatus for performing the removal of heavy metals from water using the process outlined above.

  6. Magnetic process for removing heavy metals from water employing magnetites

    DOE Patents [OSTI]

    Prenger, F. Coyne; Hill, Dallas D.

    2006-12-26

    A process for removing heavy metals from water is provided. The process includes the steps of introducing magnetite to a quantity of water containing heavy metal. The magnetite is mixed with the water such that at least a portion of, and preferably the majority of, the heavy metal in the water is bound to the magnetite. Once this occurs the magnetite and absorbed metal is removed from the water by application of a magnetic field. In most applications the process is achieved by flowing the water through a solid magnetized matrix, such as steel wool, such that the magnetite magnetically binds to the solid matrix. The magnetized matrix preferably has remnant magnetism, but may also be subject to an externally applied magnetic field. Once the magnetite and associated heavy metal is bound to the matrix, it can be removed and disposed of, such as by reverse water or air and water flow through the matrix. The magnetite may be formed in-situ by the addition of the necessary quantities of Fe(II) and Fe(III) ions, or pre-formed magnetite may be added, or a combination of seed and in-situ formation may be used. The invention also relates to an apparatus for performing the removal of heavy metals from water using the process outlined above.

  7. Process for removing polymer-forming impurities from naphtha fraction

    DOE Patents [OSTI]

    Kowalczyk, D.C.; Bricklemyer, B.A.; Svoboda, J.J.

    1983-12-27

    Polymer precursor materials are vaporized without polymerization or are removed from a raw naphtha fraction by passing the raw naphtha to a vaporization zone and vaporizing the naphtha in the presence of a wash oil while stripping with hot hydrogen to prevent polymer deposits in the equipment. 2 figs.

  8. Process for removing polymer-forming impurities from naphtha fraction

    DOE Patents [OSTI]

    Kowalczyk, Dennis C. (Pittsburgh, PA); Bricklemyer, Bruce A. (Avonmore, PA); Svoboda, Joseph J. (Pittsburgh, PA)

    1983-01-01

    Polymer precursor materials are vaporized without polymerization or are removed from a raw naphtha fraction by passing the raw naphtha to a vaporization zone (24) and vaporizing the naphtha in the presence of a wash oil while stripping with hot hydrogen to prevent polymer deposits in the equipment.

  9. Apparatus for removably holding a plurality of microballoons

    DOE Patents [OSTI]

    Jorgensen, B.S.

    1984-06-05

    The present invention relates generally to the manipulation of microballoons and more particularly to an apparatus for removably holding a plurality of microballoons in order to more efficiently carry out the filling of the microballoons with a known quantity of gas.

  10. Calf Removal: A Way to Stimulate Reproduction in Cows 

    E-Print Network [OSTI]

    Sprott, L. R.

    2003-10-08

    Cows that are slow to breed or fail to breed are costly to producers. One of the factors that delays the resumption of estrous activity in a cow--and subsequent breeding--is nursing stress. Removing a calf from a dam, either short...

  11. GROUNDWATER NITRATE REMOVAL CAPACITY OF RIPARIAN ZONES IN

    E-Print Network [OSTI]

    Gold, Art

    GROUNDWATER NITRATE REMOVAL CAPACITY OF RIPARIAN ZONES IN URBANIZING WATERSHEDS BY TARA KIMBERLY the watershed, however, is not well understood. Nitrate in groundwater moving through the "biologically active and geomorphology of riparian zones, potentially changing riparian groundwater denitrification capacity. Little work

  12. Quantifying the Effects of Removing Permissions from Android Applications

    E-Print Network [OSTI]

    Chen, Hao

    Quantifying the Effects of Removing Permissions from Android Applications Kristen Kennedy, Eric Gustafson, Hao Chen University of California, Davis Abstract With the growing popularity of Android smart study found that approximately 26% of Android applications in Google Play can access personal data

  13. Apparatuses and methods for removal of ink buildup

    DOE Patents [OSTI]

    Cudzinovic, Michael; Pass, Thomas; Rogers, Rob; Sun, Ray-Hon; Sun, Sheng; Wahlstrom, Ben; Fuhrman, Dennis Jason; Altendorf, Kyle David

    2013-03-12

    A substrate patterning method including the steps of spraying ink on a surface of a substrate, the spraying of the ink resulting in an overspray of excess ink past an edge of the substrate; changing a temperature of the excess ink to cause a change in a viscosity of the excess ink; and removing the excess ink having the changed viscosity.

  14. Mercury removal in utility wet scrubber using a chelating agent

    DOE Patents [OSTI]

    Amrhein, Gerald T. (Louisville, OH)

    2001-01-01

    A method for capturing and reducing the mercury content of an industrial flue gas such as that produced in the combustion of a fossil fuel or solid waste adds a chelating agent, such as ethylenediaminetetraacetic acid (EDTA) or other similar compounds like HEDTA, DTPA and/or NTA, to the flue gas being scrubbed in a wet scrubber used in the industrial process. The chelating agent prevents the reduction of oxidized mercury to elemental mercury, thereby increasing the mercury removal efficiency of the wet scrubber. Exemplary tests on inlet and outlet mercury concentration in an industrial flue gas were performed without and with EDTA addition. Without EDTA, mercury removal totaled 42%. With EDTA, mercury removal increased to 71%. The invention may be readily adapted to known wet scrubber systems and it specifically provides for the removal of unwanted mercury both by supplying S.sup.2- ions to convert Hg.sup.2+ ions into mercuric sulfide (HgS) and by supplying a chelating agent to sequester other ions, including but not limited to Fe.sup.2+ ions, which could otherwise induce the unwanted reduction of Hg.sup.2+ to the form, Hg.sup.0.

  15. Finding mold removal directions using graphics hardware Rahul Khardekar

    E-Print Network [OSTI]

    McMains, Sara

    Finding mold removal directions using graphics hardware Rahul Khardekar University of California, Berkeley Sara McMains University of California, Berkeley 1 Introduction In molding and casting manufacturing processes, molten raw ma- terial is shaped in molds from which the resulting part must be re

  16. Energy Savings for CO2 Removal in Ammonia Plants 

    E-Print Network [OSTI]

    Pouilliart, R.; Van Hecke, F. C.

    1981-01-01

    An exergy analysis of carbonate solution C02 removal systems which use solution flashing shows that there is no energy saving by using a mechanical thermocompressor instead of a steam-jet ejector. In a 1000 ShT/D ammonia plant an energy saving...

  17. Process for removing sulfur from sulfur-containing gases

    DOE Patents [OSTI]

    Rochelle, Gary T. (Austin, TX); Jozewicz, Wojciech (Chapel Hill, NC)

    1989-01-01

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accorda The government may own certain rights in the present invention pursuant to EPA Cooperative Agreement CR 81-1531.

  18. User-guided Pedestrian and Object Removal Antonio Haro

    E-Print Network [OSTI]

    Haro, Antonio

    User-guided Pedestrian and Object Removal Antonio Haro Nokia 425 West Randolph Street Chicago, IL of locations around the world. While the focus is on capturing streets and buildings, pedestrians are commonly captured. Pedestrian faces are identified and blurred in different sys- tems to address privacy concerns

  19. Investigating the Use of Biosorbents to Remove Arsenic from Water 

    E-Print Network [OSTI]

    Erapalli, Shreyas

    2011-02-22

    , As (III), and arsenate, As (V), from water. Batch reactors were employed to assess the percent removal, reaction kinetics, adsorption capacity, and desorption of each arsenic species onto/from biosorbents under pH buffered and non?buffered conditions...

  20. Method for removal of mercury from various gas streams

    DOE Patents [OSTI]

    Granite, E.J.; Pennline, H.W.

    2003-06-10

    The invention provides for a method for removing elemental mercury from a fluid, the method comprising irradiating the mercury with light having a wavelength of approximately 254 nm. The method is implemented in situ at various fuel combustion locations such as power plants and municipal incinerators.

  1. Guide wire extension for shape memory polymer occlusion removal devices

    SciTech Connect (OSTI)

    Maitland, Duncan J.; Small, IV, Ward; Hartman, Jonathan

    2009-11-03

    A flexible extension for a shape memory polymer occlusion removal device. A shape memory polymer instrument is transported through a vessel via a catheter. A flexible elongated unit is operatively connected to the distal end of the shape memory polymer instrument to enhance maneuverability through tortuous paths en route to the occlusion.

  2. Potential Supply Impacts of Removal of 1-Pound RVP Waiver

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    trends, and current laws and regulations. The EIA's Annual Energy Outlook 2002 (AEO2002) is usedPotential Supply Impacts of Removal of 1-Pound RVP Waiver September 2002 #12;ii Energy Information by the Office of Oil and Gas of the Energy Information Administration. General questions concerning the report

  3. Columbia River Channel Improvement Project Rock Removal Blasting: Monitoring Plan

    SciTech Connect (OSTI)

    Carlson, Thomas J.; Johnson, Gary E.

    2010-01-29

    This document provides a monitoring plan to evaluate take as outlined in the National Marine Fisheries Service 2002 Biological Opinion for underwater blasting to remove rock from the navigation channel for the Columbia River Channel Improvement Project. The plan was prepared by the Pacific Northwest National Laboratory (PNNL) for the U.S. Army Corps of Engineers (USACE), Portland District.

  4. Detroit Edison's Fermi 1 - Preparation for Reactor Removal

    SciTech Connect (OSTI)

    Swindle, Danny [Sargent and Lundy Engineers, LLC, 55 E. Monroe Street, Chicago, IL 60603 (United States)

    2008-01-15

    This paper is intended to provide information about the ongoing decommissioning tasks at Detroit Edison's Fermi 1 plant, and in particular, the work being performed to prepare the reactor for removal and disposal. In 1972 Fermi 1 was shutdown and the fuel returned to the Atomic Energy Commission. By the end of 1975, a retirement plan was prepared, the bulk sodium removed, and the plant placed in a safe store condition. The plant systems were left isolated with the sodium containing systems inert with carbon dioxide in an attempt to form a carbonate layer, thus passivating the underlying reactive sodium. In 1996, Detroit Edison determined to evaluate the condition of the plant and to make recommendations in relation to the Fermi 1 future plans. At the end of 1997 approval was obtained to remove the bulk asbestos and residual alkali-metals (i.e., sodium and sodium potassium (NaK)). In 2000, full nuclear decommissioning of the plant was approved. To date, the bulk asbestos insulation has been removed, and the only NaK remaining is located in six capillary instrument tubes. The remaining sodium is contained within the reactor, two of the three primary loops, and miscellaneous removed pipes and equipment to be processed. The preferred method for removing or reacting sodium at Fermi 1 is by injecting superheated steam into a heated, nitrogen inert system. The byproducts of this reaction are caustic sodium hydroxide, hydrogen gas, and heat. The decision was made to separate the three primary loops from the reactor for better control prior to processing each loop and the reactor separately. The first loop has already been processed. The main focus is now to process the reactor to allow removal and disposal of the Class C waste prior to the anticipated June 2008 closure of the Barnwell radioactive waste disposal facility located in South Carolina. Lessons learnt are summarized and concern: the realistic schedule and adherence to the schedule, time estimates, personnel accountability, back up or fill in work, work packages, condensation control, radiological contamination control, and organization of the waste stream.

  5. Simulating dam removal with a 1D hydraulic model: Accuracy and techniques for reservoir erosion and downstream deposition at the Chiloquin Dam removal

    E-Print Network [OSTI]

    Tullos, Desiree

    Simulating dam removal with a 1D hydraulic model: Accuracy and techniques for reservoir erosion and downstream deposition at the Chiloquin Dam removal Desiree Tullos1 , Matt Cox1 , Cara Walter1 1 Department are often used to reduce uncertainty regarding the outcomes of dam removal, though the accuracy

  6. Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development

    SciTech Connect (OSTI)

    Stephenson, M.

    1994-03-01

    Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because of the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.

  7. Designing Fusion Machines for High Availability

    E-Print Network [OSTI]

    Designing Fusion Machines for High Availability Tom Brown, Hutch Neilson Princeton Plasma Physics is proportional to (Availability)-1 Rapid removal/replacement of limited-life in-vessel components is a necessary condition for high availability. DEMO will need to show that a fusion plant can operate with high

  8. Laser patterning of laminated structures for electroplating

    DOE Patents [OSTI]

    Mayer, Steven T. (San Leandro, CA); Evans, Leland B. (Antioch, CA)

    1993-01-01

    A process for laser patterning of a substrate so that it can be subsequently electroplated or electrolessly plated. The process utilizes a laser to treat an inactive (inert) layer formed over an active layer to either combine or remove the inactive layer to produce a patterned active layer on which electrodeposition can occur. The process is carried out by utilizing laser alloying and laser etching, and involves only a few relatively high yield steps and can be performed on a very small scale.

  9. Controlled removal of ceramic surfaces with combination of ions implantation and ultrasonic energy

    DOE Patents [OSTI]

    Boatner, Lynn A. (Oak Ridge, TN); Rankin, Janet (Providence, RI); Thevenard, Paul (Caluire, FR); Romana, Laurence J. (Gaudeloupe Antilles, FR)

    1995-01-01

    A method for tailoring or patterning the surface of ceramic articles is provided by implanting ions to predetermined depth into the ceramic material at a selected surface location with the ions being implanted at a fluence and energy adequate to damage the lattice structure of the ceramic material for bi-axially straining near-surface regions of the ceramic material to the predetermined depth. The resulting metastable near-surface regions of the ceramic material are then contacted with energy pulses from collapsing, ultrasonically-generated cavitation bubbles in a liquid medium for removing to a selected depth the ion-damaged near-surface regions containing the bi-axially strained lattice structure from the ceramic body. Additional patterning of the selected surface location on the ceramic body is provided by implanting a high fluence of high-energy, relatively-light ions at selected surface sites for relaxing the bi-axial strain in the near-surface regions defined by these sites and thereby preventing the removal of such ion-implanted sites by the energy pulses from the collapsing ultrasonic cavitation bubbles.

  10. Action and Inaction Levels in Pest Management. 

    E-Print Network [OSTI]

    Sterling, Winfield

    1984-01-01

    to this problem be to use the term "action level" as a replacement term "economic threshold" and the term "inac level" for the critical natural enemy densities (134). terms are more fitting because economic and factors are both important in pest manage dec... component of level model. If the plant has reserves of n sufficient time remaining during the growing replace damaged fruit , then a higher action level be set. The effect of leaf damage as related phenological stage of cotton plant growth is ill...

  11. ARM - TWP Darwin Site-Inactive

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow, Alaska

  12. ARM - NSA Atqasuk Facility-Inactive

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow, Alaska Outreach HomepolarizationMeasurementsWarmingMethaneMissionAtqasuk

  13. Removal of arsenic compounds from spent catecholated polymer

    DOE Patents [OSTI]

    Fish, Richard H. (Berkeley, CA)

    1985-01-01

    Described is a process for removing arsenic from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic bound to it from contacting petroliferous liquid as described above and involves: a. treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10 and, b. separating the solids and liquids from each other. Preferably the regeneration treatment is in two steps wherein step (a) is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, steps (a) and (b) are repeated using a bicarbonate.

  14. Negative kinetic energy term of general relativity and its removing

    E-Print Network [OSTI]

    T. Mei

    2009-03-30

    We first present a new Lagrangian of general relativity, which can be divided into kinetic energy term and potential energy term. Taking advantage of vierbein formalism, we reduce the kinetic energy term to a sum of five positive terms and one negative term. Some gauge conditions removing the negative kinetic energy term are discussed. Finally, we present a Lagrangian that only include positive kinetic energy terms. To remove the negative kinetic energy term leads to a new field equation of general relativity in which there are at least five equations of constraint and at most five dynamical equations, this characteristic is different from the normal Einstein field equation in which there are four equations of constraint and six dynamical equations.

  15. Apparatus for removing hydrocarbon contaminants from solid materials

    DOE Patents [OSTI]

    Bala, G.A.; Thomas, C.P.

    1996-02-13

    A system is described for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste). 4 figs.

  16. Method for removing hydrocarbon contaminants from solid materials

    DOE Patents [OSTI]

    Bala, Gregory A. (Idaho Falls, ID); Thomas, Charles P. (Idaho Falls, ID)

    1995-01-01

    A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

  17. Apparatus for removing hydrocarbon contaminants from solid materials

    DOE Patents [OSTI]

    Bala, Gregory A. (Idaho Falls, ID); Thomas, Charles P. (Idaho Falls, ID)

    1996-01-01

    A system for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste).

  18. Methods of using adsorption media for separating or removing constituents

    DOE Patents [OSTI]

    Tranter, Troy J. (Idaho Falls, ID); Herbst, R. Scott (Idaho Falls, ID); Mann, Nicholas R. (Blackfoot, ID); Todd, Terry A. (Aberdeen, ID)

    2011-10-25

    Methods of using an adsorption medium to remove at least one constituent from a feed stream. The method comprises contacting an adsorption medium with a feed stream comprising at least one constituent and removing the at least one constituent from the feed stream. The adsorption medium comprises a polyacrylonitrile (PAN) matrix and at least one metal hydroxide homogenously dispersed therein. The adsorption medium may comprise from approximately 15 wt % to approximately 90 wt % of the PAN and from approximately 10 wt % to approximately 85 wt % of the at least one metal hydroxide. The at least one metal hydroxide may be selected from the group consisting of ferric hydroxide, zirconium hydroxide, lanthanum hydroxide, cerium hydroxide, titanium hydroxide, copper hydroxide, antimony hydroxide, and molybdenum hydroxide.

  19. Removal of field and embedded metal by spin spray etching

    DOE Patents [OSTI]

    Contolini, R.J.; Mayer, S.T.; Tarte, L.A.

    1996-01-23

    A process of removing both the field metal, such as copper, and a metal, such as copper, embedded into a dielectric or substrate at substantially the same rate by dripping or spraying a suitable metal etchant onto a spinning wafer to etch the metal evenly on the entire surface of the wafer. By this process the field metal is etched away completely while etching of the metal inside patterned features in the dielectric at the same or a lesser rate. This process is dependent on the type of chemical etchant used, the concentration and the temperature of the solution, and also the rate of spin speed of the wafer during the etching. The process substantially reduces the metal removal time compared to mechanical polishing, for example, and can be carried out using significantly less expensive equipment. 6 figs.

  20. Criticality safety aspects of K-25 Building uranium deposit removal

    SciTech Connect (OSTI)

    Haire, M.J.; Jordan, W.C. [Oak Ridge National Lab., TN (United States); Ingram, J.C. III; Stinnet, E.C. Jr. [Oak Ridge K-25 Site, TN (United States)

    1995-12-31

    The K-25 Building of the Oak Ridge Gaseous Diffusion Plant (now the K-25 Site) went into operation during World War II as the first large scale production plant to separate {sup 235}U from uranium by the gaseous diffusion process. It operated successfully until 1964, when it was placed in a stand-by mode. The Department of Energy has initiated a decontamination and decommissioning program. The primary objective of the Deposit Removal (DR) Project is to improve the nuclear criticality safety of the K-25 Building by removing enriched uranium deposits from unfavorable-geometry process equipment to below minimum critical mass. The method utilized to accomplish this are detailed in this report.

  1. Methods for removing contaminant matter from a porous material

    DOE Patents [OSTI]

    Fox, Robert V. (Idaho Falls, ID) [Idaho Falls, ID; Avci, Recep (Bozeman, MT) [Bozeman, MT; Groenewold, Gary S. (Idaho Falls, ID) [Idaho Falls, ID

    2010-11-16

    Methods of removing contaminant matter from porous materials include applying a polymer material to a contaminated surface, irradiating the contaminated surface to cause redistribution of contaminant matter, and removing at least a portion of the polymer material from the surface. Systems for decontaminating a contaminated structure comprising porous material include a radiation device configured to emit electromagnetic radiation toward a surface of a structure, and at least one spray device configured to apply a capture material onto the surface of the structure. Polymer materials that can be used in such methods and systems include polyphosphazine-based polymer materials having polyphosphazine backbone segments and side chain groups that include selected functional groups. The selected functional groups may include iminos, oximes, carboxylates, sulfonates, .beta.-diketones, phosphine sulfides, phosphates, phosphites, phosphonates, phosphinates, phosphine oxides, monothio phosphinic acids, and dithio phosphinic acids.

  2. Use of microalgae to remove pollutants from power plant discharges

    DOE Patents [OSTI]

    Wilde, Edward W. (1833 Pisgah Rd., North Augusta, SC 29841); Benemann, John R. (2741 O'Harte, San Pablo, CA 94806); Weissman, Joseph C. (2086 N. Porpoise Pt. La., Vero Beach, FL 32963); Tillett, David M. (911-3 Coquina La., Vero Beach, FL 32963)

    1991-01-01

    A method and system for removing pollutants dissolved in the aqueous discharge of a plant, such as a power plant, from a body of water having known hydraulogy and physicochemical characteristics, the method comprising (a) modifying the hydraulic system of the body of water including use of physical barriers to define a zone in a portion of the body of water which zone includes the discharge point and where the water has a range of physicochemical characteristics; (b) selecting a large and preferably filamentous, planktonically growing strain of algae adapted to absorb the particular pollutants and genetically dominating algae at the physicochemical characteristics of the zone; (c) establishing a colony of the selected algal strain in the zone; (d) harvesting a portion of the colony; and (e) reinnoculating the zone near the discharge point with a fraction of the harvested portion. The fraction used for reinnoculation can be adjusted to balance the rate of pollutant removal to the rate of pollutant discharge.

  3. Method for removing undesired particles from gas streams

    DOE Patents [OSTI]

    Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Hyatt, D.E.; Bustard, C.J.; Sjostrom, S.

    1998-11-10

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 11 figs.

  4. An alternative to removing lead-based paint: Overcoating

    SciTech Connect (OSTI)

    Vernon, L.S.

    1996-02-01

    The case of repairing a municipal water tank coated with lead-based paint (LBP) is used to illustrate some of the benefits of overcoating, a possible alternative to removing failing paint. The paper discusses data regarding performance of the waterborne acrylic used in the case study, briefly reviews revisions to specifications for the coating`s use, and offers some costs by which to compare use of a waterborne encapsulant such as that used in the case study with either removal and recoating or use of a solvent-borne encapsulant. A surface-tolerant, water-based, corrosion-resistant acrylic was selected to overcoat the LBP. By cleaning and overcoating the existing adherent LBP using the acrylic coating, chances of lead exposure to workers and the public were reduced. Eliminating abrasive blasting and the need for full containment saved about $80,000 to $100,000.

  5. Method for removing hydrocarbon contaminants from solid materials

    DOE Patents [OSTI]

    Bala, G.A.; Thomas, C.P.

    1995-10-03

    A system is described for removing hydrocarbons from solid materials. Contaminated solids are combined with a solvent (preferably terpene based) to produce a mixture. The mixture is washed with water to generate a purified solid product (which is removed from the system) and a drainage product. The drainage product is separated into a first fraction (consisting mostly of contaminated solvent) and a second fraction (containing solids and water). The first fraction is separated into a third fraction (consisting mostly of contaminated solvent) and a fourth fraction (containing residual solids and water). The fourth fraction is combined with the second fraction to produce a sludge which is separated into a fifth fraction (containing water which is ultimately reused) and a sixth fraction (containing solids). The third fraction is then separated into a seventh fraction (consisting of recovered solvent which is ultimately reused) and an eighth fraction (containing hydrocarbon waste). 4 figs.

  6. Process for removing sulfate anions from waste water

    DOE Patents [OSTI]

    Nilsen, David N. (Lebanon, OR); Galvan, Gloria J. (Albany, OR); Hundley, Gary L. (Corvallis, OR); Wright, John B. (Albany, OR)

    1997-01-01

    A liquid emulsion membrane process for removing sulfate anions from waste water is disclosed. The liquid emulsion membrane process includes the steps of: (a) providing a liquid emulsion formed from an aqueous strip solution and an organic phase that contains an extractant capable of removing sulfate anions from waste water; (b) dispersing the liquid emulsion in globule form into a quantity of waste water containing sulfate anions to allow the organic phase in each globule of the emulsion to extract and absorb sulfate anions from the waste water and (c) separating the emulsion including its organic phase and absorbed sulfate anions from the waste water to provide waste water containing substantially no sulfate anions.

  7. Process for removing carbonyl-sulfide from liquid hydrocarbon feedstocks

    SciTech Connect (OSTI)

    Debras, G.L.G.; DeClippeleir, G.E.M.J.; Cahen, R.M.

    1986-09-23

    A process is described for removing carbonyl sulfide from a liquid olefinic hydrocarbon feedstock comprising: (a) passing the hydrocarbon feedstock over an absorbent material comprising zinc oxide and a promoter selected from the group consisting of alumina, silico-aluminas and any combination thereof wherein the promoter is present in amounts from about 3 to about 15 percent by weight of the absorbent material; and (b) recovering a liquid olefinic hydrocarbon stream having a substantially reduced carbonyl sulfide content.

  8. Microbial removal of no.sub.x from gases

    DOE Patents [OSTI]

    Sublette, Kerry L. (Tulsa, OK)

    1991-01-01

    Disclosed is a process by which a gas containing nitric oxide is contacted with an anaerobic microbial culture of denitrifying bacteria to effect the chemical reduction of the nitric oxide to elemental nitrogen. The process is particularly suited to the removal of nitric oxide from flue gas streams and gas streams from nitric acid plants. Thiobacillus dentrificians as well as other bacteria are disclosed for use in the process.

  9. Inflatable containment diaphragm for sealing and removing stacks

    DOE Patents [OSTI]

    Meskanick, G.R.; Rosso, D.T.

    1993-04-13

    A diaphragm with an inflatable torus-shaped perimeter is used to seal at least one end of a stack so that debris that might be hazardous will not be released during removal of the stack. A diaphragm is inserted and inflated in the lower portion of a stack just above where the stack is to be cut such that the perimeter of the diaphragm expands and forms a seal against the interior surface of the stack.

  10. System for the removal of contaminant soil-gas vapors

    DOE Patents [OSTI]

    Weidner, Jerry R. (Iona, ID); Downs, Wayne C. (Sugar City, ID); Kaser, Timothy G. (Ammon, ID); Hall, H. James (Idaho Falls, ID)

    1997-01-01

    A system extracts contaminated vapors from soil or other subsurface regions by using changes in barometric pressure to operate sensitive check valves that control air entry and removal from wells in the ground. The system creates an efficient subterranean flow of air through a contaminated soil plume and causes final extraction of the contaminants from the soil to ambient air above ground without any external energy sources.

  11. System for the removal of contaminant soil-gas vapors

    DOE Patents [OSTI]

    Weidner, J.R.; Downs, W.C.; Kaser, T.G.; Hall, H.J.

    1997-12-16

    A system extracts contaminated vapors from soil or other subsurface regions by using changes in barometric pressure to operate sensitive check valves that control air entry and removal from wells in the ground. The system creates an efficient subterranean flow of air through a contaminated soil plume and causes final extraction of the contaminants from the soil to ambient air above ground without any external energy sources. 4 figs.

  12. Nitrogen removal from natural gas using two types of membranes

    DOE Patents [OSTI]

    Baker, Richard W.; Lokhandwala, Kaaeid A.; Wijmans, Johannes G.; Da Costa, Andre R.

    2003-10-07

    A process for treating natural gas or other methane-rich gas to remove excess nitrogen. The invention relies on two-stage membrane separation, using methane-selective membranes for the first stage and nitrogen-selective membranes for the second stage. The process enables the nitrogen content of the gas to be substantially reduced, without requiring the membranes to be operated at very low temperatures.

  13. Fairer Trade, Removing Gender Bias in US Import Taxes 

    E-Print Network [OSTI]

    Taylor, Lori L.; Dar, Jawad

    2015-01-01

    Fairer Trade Removing Gender Bias in US Import Taxes LORI L. TAYLOR AND JAWAD DAR Mosbacher Institute VOLUME 6 | ISSUE 3 | 2015 There are many inequalities in US tariff policy. Products imported from certain countries enter duty free, while... in 2009 to honor Robert A. Mosbacher, Secretary of Commerce from 1989- 1992 and key architect of the North American Free Trade Agreement. Through our three core programs–Integration of Global Markets, Energy in a Global Economy, and Governance and Public...

  14. Low temperature SO{sub 2} removal with solid sorbents in a circulating fluidized bed absorber. Final report

    SciTech Connect (OSTI)

    Lee, S.K.; Keener, T.C.

    1994-10-10

    A novel flue gas desulfurization technology has been developed at the University of Cincinnati incorporating a circulating fluidized bed absorber (CFBA) reactor with dry sorbent. The main features of CFBA are high sorbent/gas mixing ratios, excellent heat and mass transfer characteristics, and the ability to recycle partially utilized sorbent. Subsequently, higher SO{sub 2} removal efficiencies with higher overall sorbent utilization can be realized compared with other dry sorbent injection scrubber systems.

  15. Ammonia removal process upgrade to the Acme Steel Coke Plant

    SciTech Connect (OSTI)

    Harris, J.L. [Acme Steel Co., Chicago, IL (United States). Chicago Coke Plant

    1995-12-01

    The need to upgrade the ammonia removal process at the Acme Steel Coke Plant developed with the installation of the benzene NESHAP (National Emission Standard for Hazardous Air Pollutants) equipment, specifically the replacement of the final cooler. At Acme Steel it was decided to replace the existing open cooling tower type final cooler with a closed loop direct spray tar/water final cooler. This new cooler has greatly reduced the emissions of benzene, ammonia, hydrogen sulfide and hydrogen cyanide to the atmosphere, bringing them into environmental compliance. At the time of its installation it was not fully recognized as to the effect this would have on the coke oven gas composition. In the late seventies the decision had been made at Acme Steel to stop the production of ammonia sulfate salt crystals. The direction chosen was to make a liquid ammonia sulfate solution. This product was used as a pickle liquor at first and then as a liquid fertilizer as more markets were developed. In the fall of 1986 the ammonia still was brought on line. The vapors generated from the operation of the stripping still are directed to the inlet of the ammonia absorber. At that point in time it was decided that an improvement to the cyclical ammonia removal process was needed. The improvements made were minimal yet allowed the circulation of solution through the ammonia absorber on a continuous basis. The paper describes the original batch process and the modifications made which allowed continuous removal.

  16. Pentek metal coating removal system: Baseline report; Summary

    SciTech Connect (OSTI)

    1997-07-31

    The Pentek metal coating removal system consists of the ROTO-PEEN Scaler, CORNER-CUTTER(R), and VAC-PAC(R). The system is designed to remove coatings from steel, concrete, brick, and wood. The Scaler uses 3M ROTO-PEEN tungsten carbide cutters, while the CORNER-CUTTER(R) uses solid needles for descaling activities. These are used with the VAC-PAC(R) vacuum system to capture dust and debris as removal of the coating takes place. The safety and health evaluation during the testing demonstration focused on two main areas of exposure: dust and noise. Dust exposure was minimal, but noise exposure was significant. Further testing for each exposure is recommended, since the outdoor environment where the testing demonstration took place may skew the results. It is feasible that dust and noise levels will be higher in an enclosed operating environment. Other areas of concern found were arm-hand vibration, whole-body vibration, ergonomics, heat stress, tripping hazards, electrical hazards, machine guarding, and lockout/tagout.

  17. Process for removal of sulfur compounds from fuel gases

    DOE Patents [OSTI]

    Moore, Raymond H. (Richland, WA); Stegen, Gary E. (Richland, WA)

    1978-01-01

    Fuel gases such as those produced in the gasification of coal are stripped of sulfur compounds and particulate matter by contact with molten metal salt. The fuel gas and salt are intimately mixed by passage through a venturi or other constriction in which the fuel gas entrains the molten salt as dispersed droplets to a gas-liquid separator. The separated molten salt is divided into a major and a minor flow portion with the minor flow portion passing on to a regenerator in which it is contacted with steam and carbon dioxide as strip gas to remove sulfur compounds. The strip gas is further processed to recover sulfur. The depleted, minor flow portion of salt is passed again into contact with the fuel gas for further sulfur removal from the gas. The sulfur depleted, fuel gas then flows through a solid absorbent for removal of salt droplets. The minor flow portion of the molten salt is then recombined with the major flow portion for feed to the venturi.

  18. Process for the removal of impurities from combustion fullerenes

    DOE Patents [OSTI]

    Alford, J. Michael; Bolskar, Robert

    2005-08-02

    The invention generally relates to purification of carbon nanomaterials, particularly fullerenes, by removal of PAHs and other hydrocarbon impurities. The inventive process involves extracting a sample containing carbon nanomaterials with a solvent in which the PAHs are substantially soluble but in which the carbon nanomaterials are not substantially soluble. The sample can be repeatedly or continuously extracted with one or more solvents to remove a greater amount of impurities. Preferred solvents include ethanol, diethyl ether, and acetone. The invention also provides a process for efficiently separating solvent extractable fullerenes from samples containing fullerenes and PAHs wherein the sample is extracted with a solvent in which both fullerenes and PAHs are substantially soluble and the sample extract then undergoes selective extraction to remove PAHs. Suitable solvents in which both fullerenes and PAHs are soluble include o-xylene, toluene, and o-dichlorobenzene. The purification process is capable of treating quantities of combustion soot in excess of one kilogram and can produce fullerenes or fullerenic soot of suitable purity for many applications.

  19. Process for off-gas particulate removal and apparatus therefor

    DOE Patents [OSTI]

    Carl, D.E.

    1997-10-21

    In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector`s centerline in proceeding toward the downstream side of the collector. Gas flow in the outer channel maintains the fluid on the channel`s wall in the form of a ``wavy film,`` while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator. 4 figs.

  20. Process for off-gas particulate removal and apparatus therefor

    DOE Patents [OSTI]

    Carl, Daniel E. (Orchard Park, NY)

    1997-01-01

    In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector's centerline in proceeding toward the downstream side of the collector. Gasflow in the outer channel maintains the fluid on the channel's wall in the form of a "wavy film," while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator.

  1. Method for removing oxide contamination from silicon carbide powders

    DOE Patents [OSTI]

    Brynestad, J.; Bamberger, C.E.

    1984-08-01

    The described invention is directed to a method for removing oxide contamination in the form of oxygen-containing compounds such as SiO/sub 2/ and B/sub 2/O/sub 3/ from a charge of finely divided silicon carbide. The silicon carbide charge is contacted with a stream of hydrogen fluoride mixed with an inert gas carrier such as argon at a temperature in the range of about 200/sup 0/ to 650/sup 0/C. The oxides in the charge react with the heated hydrogen fluoride to form volatile gaseous fluorides such as SiF/sub 4/ and BF/sub 3/ which pass through the charge along with unreacted hydrogen fluoride and the carrier gas. Any residual gaseous reaction products and hydrogen fluoride remaining in the charge are removed by contacting the charge with the stream of inert gas which also cools the powder to room temperature. The removal of the oxygen contamination by practicing the present method provides silicon carbide powders with desirable pressing and sintering characteristics. 1 tab.

  2. Particle count monitoring of reverse osmosis water treatment for removal of low-level radionuclides

    SciTech Connect (OSTI)

    Moritz, E.J.; Hoffman, C.R.; Hergert, T.R.

    1995-03-01

    Laser diode particle counting technology and analytical measurements were used to evaluate a pilot-scale reverse osmosis (RO) water treatment system for removal of particulate matter and sub-picocurie low-level radionuclides. Stormwater mixed with Waste Water Treatment Plant (WWTP) effluent from the Rocky Flats Environmental Technology Site (RFETS), formerly a Department of Energy (DOE) nuclear weapons production facility, were treated. No chemical pretreatment of the water was utilized during this study. The treatment system was staged as follows: multimedia filtration, granular activated carbon adsorption, hollow tube ultrafiltration, and reverse osmosis membrane filtration. Various recovery rates and two RO membrane models were tested. Analytical measurements included total suspended solids (TSS), total dissolved solids (TDS), gross alpha ({alpha}) and gross beta ({beta}) activity, uranium isotopes {sup 233/234}U and {sup 238}U, plutonium {sup 239/240}Pu, and americium {sup 241}Am. Particle measurement between 1--150 microns ({mu}) included differential particle counts (DPC), and total particle counts (TPC) before and after treatment at various sampling points throughout the test. Performance testing showed this treatment system produced a high quality effluent in clarity and purity. Compared to raw water levels, TSS was reduced to below detection of 5 milligrams per liter (mg/L) and TDS reduced by 98%. Gross {alpha} was essentially removed 100%, and gross {beta} was reduced an average of 94%. Uranium activity was reduced by 99%. TPC between 1-150{mu} were reduced by an average 99.8% to less than 1,000 counts per milliliter (mL), similar in purity to a good drinking water treatment plant. Raw water levels of {sup 239/240}Pu and {sup 241}Am were below reliable quantitation limits and thus no removal efficiencies could be determined for these species.

  3. Removal of Elemental Mercury from a Gas Stream Facilitated by a Non-Thermal Plasma Device

    SciTech Connect (OSTI)

    Charles Mones

    2006-12-01

    Mercury generated from anthropogenic sources presents a difficult environmental problem. In comparison to other toxic metals, mercury has a low vaporization temperature. Mercury and mercury compounds are highly toxic, and organic forms such as methyl mercury can be bio-accumulated. Exposure pathways include inhalation and transport to surface waters. Mercury poisoning can result in both acute and chronic effects. Most commonly, chronic exposure to mercury vapor affects the central nervous system and brain, resulting in neurological damage. The CRE technology employs a series of non-thermal, plasma-jet devices to provide a method for elemental mercury removal from a gas phase by targeting relevant chemical reactions. The technology couples the known chemistry of converting elemental mercury to ionic compounds by mercury-chlorine-oxygen reactions with the generation of highly reactive species in a non-thermal, atmospheric, plasma device. The generation of highly reactive metastable species in a non-thermal plasma device is well known. The introduction of plasma using a jet-injection device provides a means to contact highly reactive species with elemental mercury in a manner to overcome the kinetic and mass-transfer limitations encountered by previous researchers. To demonstrate this technology, WRI has constructed a plasma test facility that includes plasma reactors capable of using up to four plasma jets, flow control instrumentation, an integrated control panel to operate the facility, a mercury generation system that employs a temperature controlled oven and permeation tube, combustible and mercury gas analyzers, and a ductless fume hood designed to capture fugitive mercury emissions. Continental Research and Engineering (CR&E) and Western Research Institute (WRI) successfully demonstrated that non-thermal plasma containing oxygen and chlorine-oxygen reagents could completely convert elemental mercury to an ionic form. These results demonstrate potential the application of this technology for removing elemental mercury from flue gas streams generated by utility boilers. On an absolute basis, the quantity of reagent required to accomplish the oxidation was small. For example, complete oxidation of mercury was accomplished using a 1% volume fraction of oxygen in a nitrogen stream. Overall, the tests with mercury validated the most useful aspect of the CR&E technology: Providing a method for elemental mercury removal from a gas phase by employing a specific plasma reagent to either increase reaction kinetics or promote reactions that would not have occurred under normal circumstances.

  4. Selective ammonia slip catalyst enabling highly efficient NOx removal requirements of the future

    Broader source: Energy.gov [DOE]

    A low precious metal loading ammonia-slip catalyst was developed that is able to oxidize the ammonia that slips past the SCR catalyst to nitrogen.

  5. NNSA Highly Enriched Uranium Removal Featured on The Rachel Maddow Show |

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested Parties -Department of EnergyNEW1 NEPAOctoberofNNMCABDepartment

  6. DOE to Remove 200 Metric Tons of Highly Enriched Uranium from U.S. Nuclear

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-in electricLaboratory | DepartmentDOE ZeroofBatteriesHybridNational

  7. 1,153-ton Waste Vault Removed from 300 Area - Vault held waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1,153-ton Waste Vault Removed from 300 Area - Vault held waste tanks with contamination from Hanford's former laboratory facilities 1,153-ton Waste Vault Removed from 300 Area -...

  8. Removal of Chloride from Wastewater by Advanced Softening Process Using Electrochemically Generated Aluminum Hydroxide 

    E-Print Network [OSTI]

    Mustafa, Syed Faisal

    2014-07-23

    solubility. Chloride can be removed from water and wastewater by precipitation as calcium chloroaluminate using advanced softening process. This research was conducted to evaluate chloride removal using electrochemically generated aluminum hydroxide and lime...

  9. Java support on genepool: java6 (jdk1.6) will be removed on 08...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Java support on genepool: java6 (jdk1.6) will be removed on 08302013; firefox security updates Java support on genepool: java6 (jdk1.6) will be removed on 08302013; firefox...

  10. Department of Energy to Take Steps to Remove ENERGY STAR Label...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to Take Steps to Remove ENERGY STAR Label on Certain LG Refrigerator-Freezer Models Department of Energy to Take Steps to Remove ENERGY STAR Label on Certain LG...

  11. Chemical Addition prior to Membrane Processes for Natural Organic Matter (NOM) Removal 

    E-Print Network [OSTI]

    Schäfer, Andrea; Fane, Anthony G.; Waite, T. D.

    1998-01-01

    Membrane processes for surface water treatment include microfiltration (MF), ultrafiltration (UF) and nanofiltration (NF), depending on the target material to be removed and the limiting process economics. MF will remove ...

  12. Oxy-Combustion Burner and Integrated Pollutant Removal Research and Development Test Facility

    SciTech Connect (OSTI)

    Mark Schoenfield; Manny Menendez; Thomas Ochs; Rigel Woodside; Danylo Oryshchyn

    2012-09-30

    A high flame temperature oxy-combustion test facility consisting of a 5 MWe equivalent test boiler facility and 20 KWe equivalent IPR® was constructed at the Hammond, Indiana manufacturing site. The test facility was operated natural gas and coal fuels and parametric studies were performed to determine the optimal performance conditions and generated the necessary technical data required to demonstrate the technologies are viable for technical and economic scale-up. Flame temperatures between 4930-6120F were achieved with high flame temperature oxy-natural gas combustion depending on whether additional recirculated flue gases are added to balance the heat transfer. For high flame temperature oxy-coal combustion, flame temperatures in excess of 4500F were achieved and demonstrated to be consistent with computational fluid dynamic modeling of the burner system. The project demonstrated feasibility and effectiveness of the Jupiter Oxygen high flame temperature oxy-combustion process with Integrated Pollutant Removal process for CCS and CCUS. With these technologies total parasitic power requirements for both oxygen production and carbon capture currently are in the range of 20% of the gross power output. The Jupiter Oxygen high flame temperature oxy-combustion process has been demonstrated at a Technology Readiness Level of 6 and is ready for commencement of a demonstration project.

  13. Treatability Test for Removing Technetium-99 from 200-ZP-1 Groundwater, Hanford Site

    SciTech Connect (OSTI)

    Byrnes, M.E.; Petersen, S.W. [Fluor Hanford, Inc., Soil and Groundwater Remediation Project, Richland, WA (United States); Tortoso, A. [U.S. Department of Energy, Richland Operations Office, Richland, WA (United States); Elliott, W.S. [Environmental Quality Management, Inc., Richland, WA (United States)

    2008-07-01

    The 200-ZP-1 Groundwater Operable Unit (OU) is one of two groundwater OUs located within the 200 West groundwater aggregate area of the Hanford Site. The primary risk-driving contaminants within the 200-ZP-1 OU include carbon tetrachloride and technetium-99 (Tc-99). A pump-and-treat system for this OU was initially installed in 1995 to control the 0.002 kg /m{sup 3} (2000 {mu}g/L) contour of the carbon tetrachloride plume. Carbon tetrachloride is removed from groundwater with the assistance of an air-stripping tower. Ten extraction wells and three injection wells operate at a combined rate of approximately 0.017m{sup 3}/s (17.03 L/s). In 2005, groundwater from two of the extraction wells (299-W15-765 and 299-W15-44) began to show concentrations greater than twice the maximum contaminant level (MCL) of Tc-99 (33,309 beq/m{sup 3} or 900 pCi/L). The Tc-99 groundwater concentrations from all ten of the extraction wells when mixed were more than one-half of the MCL and were slowly increasing. If concentrations continued to rise and the water remained untreated for Tc-99, there was concern that the water re-injected into the aquifer could exceed the MCL standard. Multiple treatment technologies were reviewed for selectively removing Tc-99 from the groundwater. Of the treatment technologies, only ion exchange was determined to be highly selective, commercially available, and relatively low in cost. Through research funded by the U.S. Department of Energy, the ion-exchange resin Purolite{sup R} A-530E1 was found to successfully remove Tc-99 from groundwater, even in the presence of competing anions. For this and other reasons, Purolite{sup R} A-530E ion exchange resin was selected for treatability testing. The treatability test required installing resin columns on the discharge lines from extraction wells 299-W15-765 and 299-W15-44. Preliminary test results have concluded that the Purolite{sup R} A-530E1 resin is effective at removing Tc-99 from groundwater to below detection limits even in the presence of competing anions (e.g., nitrate and sulfate) at concentrations five to six magnitudes higher than Tc-99. (authors)

  14. Centrifugal accelerator, system and method for removing unwanted layers from a surface

    DOE Patents [OSTI]

    Foster, Christopher A. (Clinton, TN); Fisher, Paul W. (Heiskell, TN)

    1995-01-01

    A cryoblasting process having a centrifugal accelerator for accelerating frozen pellets of argon or carbon dioxide toward a target area utilizes an accelerator throw wheel designed to induce, during operation, the creation of a low-friction gas bearing within internal passages of the wheel which would otherwise retard acceleration of the pellets as they move through the passages. An associated system and method for removing paint from a surface with cryoblasting techniques involves the treating, such as a preheating, of the painted surface to soften the paint prior to the impacting of frozen pellets thereagainst to increase the rate of paint removal. A system and method for producing large quantities of frozen pellets from a liquid material, such as liquid argon or carbon dioxide, for use in a cryoblasting process utilizes a chamber into which the liquid material is introduced in the form of a jet which disintegrates into droplets. A non-condensible gas, such as inert helium or air, is injected into the chamber at a controlled rate so that the droplets freeze into bodies of relatively high density.

  15. Channel adjustments following two dam removals in Wisconsin Martin W. Doyle

    E-Print Network [OSTI]

    Stanley, Emily

    the removal of low-head dams on two low- gradient, fine- to coarse-grained rivers in southern Wisconsin

  16. Coupled effects of flow field geometry and diffusion media material structure on evaporative water removal from

    E-Print Network [OSTI]

    Mench, Matthew M.

    (PEFC) is responsible for many degradation and durability issues [1e4]. To remove water from the stack

  17. SULFURIC ACID REMOVAL PROCESS EVALUATION: LONG-TERM RESULTS

    SciTech Connect (OSTI)

    Gary M. Blythe; Richard McMillan

    2002-07-03

    The objective of this project is to demonstrate the use of alkaline reagents injected into the furnace of coal-fired boilers as a means of controlling sulfuric acid emissions. The project is being co-funded by the U.S. DOE National Energy Technology Laboratory, under Cooperative Agreement DE-FC26-99FT40718, along with EPRI, the American Electric Power Company (AEP), FirstEnergy Corp., the Tennessee Valley Authority, and Dravo Lime, Inc. Sulfuric acid controls are becoming of increasing interest to power generators with coal-fired units for a number of reasons. Sulfuric acid is a Toxic Release Inventory species and can cause a variety of plant operation problems such as air heater plugging and fouling, back-end corrosion, and plume opacity. These issues will likely be exacerbated with the retrofit of selective catalytic reduction (SCR) for NO{sub x} control on many coal-fired plants, as SCR catalysts are known to further oxidize a portion of the flue gas SO{sub 2} to SO{sub 3}. The project previously tested the effectiveness of furnace injection of four different calcium-and/or magnesium-based alkaline sorbents on full-scale utility boilers. These reagents were tested during four one- to two-week tests conducted on two FirstEnergy Bruce Mansfield Plant (BMP) units. One of the sorbents tested was a magnesium hydroxide byproduct slurry produced from a modified Thiosorbic{reg_sign} Lime wet flue gas desulfurization system. The other three sorbents are available commercially and include dolomite, pressure-hydrated dolomitic lime, and commercial magnesium hydroxide. The dolomite reagent was injected as a dry powder through out-of-service burners, while the other three reagents were injected as slurries through air-atomizing nozzles inserted through the front wall of the upper furnace, either across from the nose of the furnace or across from the pendant superheater tubes. After completing the four one- to two-week tests, the most promising sorbents were selected for longer-term (approximately 25-day) full-scale tests on two different units. The longer-term tests were conducted to confirm the effectiveness of the sorbents tested over extended operation on two different boilers, and to determine balance-of-plant impacts. The first long-term test was conducted on FirstEnergy's BMP, Unit 3, and the second test was conducted on AEP's Gavin Plant, Unit 1. The Gavin Plant testing provided an opportunity to evaluate the effects of sorbent injected into the furnace on SO{sub 3} formed across an operating SCR reactor. This report presents the results from those long-term tests. The tests determined the effectiveness of injecting commercially available magnesium hydroxide slurry (Gavin Plant) and byproduct magnesium hydroxide slurry (both Gavin Plant and BMP) for sulfuric acid control. The results show that injecting either slurry could achieve up to 70 to 75% overall sulfuric acid removal. At BMP, this overall removal was limited by the need to maintain acceptable electrostatic precipitator (ESP) particulate control performance. At Gavin Plant, the overall sulfuric acid removal was limited because the furnace injected sorbent was less effective at removing SO{sub 3} formed across the SCR system installed on the unit for NOX control than at removing SO{sub 3} formed in the furnace. The long-term tests also determined balance-of-plant impacts from slurry injection during the two tests. These include impacts on boiler back-end temperatures and pressure drops, SCR catalyst properties, ESP performance, removal of other flue gas species, and flue gas opacity. For the most part the balance-of-plant impacts were neutral to positive, although adverse effects on ESP performance became an issue during the BMP test.

  18. BOA: Asbestos pipe insulation removal robot system. Phase 1

    SciTech Connect (OSTI)

    Schempf, H.; Bares, J.E.

    1995-02-01

    The project described in this report targets the development of a mechanized system for safe, cost-efficient and automated abatement of asbestos containing materials used as pipe insulation. Based on several key design criteria and site visits, a proof-of-concept prototype robot system, dubbed BOA, was designed and built, which automatically strips the lagging and insulation from the pipes, and encapsulates them under complete vacuum operation. The system can operate on straight runs of piping in horizontal or vertical orientations. Currently we are limited to four-inch diameter piping without obstacles as well as a somewhat laborious emplacement and removal procedure -- restrictions to be alleviated through continued development. BOA removed asbestos at a rate of 4-5 ft./h compared to 3 ft./h for manual removal of asbestos with a 3-person crew. The containment and vacuum system on BOA was able to achieve the regulatory requirement for airborne fiber emissions of 0.01 fibers/ccm/ 8-hr. shift. This program consists of two phases. The first phase was completed and a demonstration was given to a review panel, consisting of DOE headquarters and site representatives as well as commercial abatement industry representatives. Based on the technical and programmatic recommendations drafted, presented and discussed during the review meeting, a new plan for the Phase II effort of this project was developed. Phase 11 will consist of a 26-month effort, with an up-front 4-month site-, market-, cost/benefit and regulatory study before the next BOA robot (14 months) is built, and then deployed and demonstrated (3 months) at a DOE site (such as Fernald or Oak Ridge) by the beginning of FY`97.

  19. Nitrate removal from irrigation run-off using packed-bed bioreactors 

    E-Print Network [OSTI]

    Abrameit, Bradley Kyle

    1996-01-01

    of the columns with the majority (21.12%) being removed in the final region. Intermediate regions reduced 5.2-16.5%. Ammonium concentrations remained steady with slight removal (6.3-1 1. I%) occurring in the first two regions. Efficiency of N03- and N02-removal...

  20. Efficient salt removal in a continuously operated upflow microbial desalination cell with an air cathode

    E-Print Network [OSTI]

    Efficient salt removal in a continuously operated upflow microbial desalination cell with an air of salt removal. During the 4-month operation, the UMDC constantly removed salts and generated bio-electricity. At a hydraulic retention time (HRT) of 4 days (salt solution) and current production of $62 mA, the UMDC was able

  1. DOWNSTREAM CHANNEL CHANGES AFTER A SMALL DAM REMOVAL: USING AERIAL PHOTOS AND MEASUREMENT ERROR FOR CONTEXT;

    E-Print Network [OSTI]

    Tullos, Desiree

    DOWNSTREAM CHANNEL CHANGES AFTER A SMALL DAM REMOVAL: USING AERIAL PHOTOS AND MEASUREMENT ERROR and Ecological Engineering, Oregon State University, Corvallis, OR, USA ABSTRACT Dam removal is often implemented to assess downstream channel changes associated with a small dam removal. The Brownsville Dam, a 2.1 m tall

  2. Virus removal by soil passage at field scale and ground-water protection of sandy aquifers

    E-Print Network [OSTI]

    Hassanizadeh, S. Majid

    Virus removal by soil passage at field scale and ground- water protection of sandy aquifers J; The Netherlands (E-mail: Majid@ct.tudelft.nl) Abstract Virus removal from groundwater by soil passage often for attachment than thereafter. A model is presented which interprets virus removal as a function of collision

  3. Removal of floating organic in Hanford Waste Tank 241-C-103 restart plan

    SciTech Connect (OSTI)

    Wilson, T.R.; Hanson, C.

    1994-10-03

    The decision whether or not to remove the organic layer from Waste Tank 241-C-103 was deferred until May, 1995. The following restart plan was prepared for removal of the organic if the decision is to remove the organic from the waste tank 241-C-103.

  4. Does Small Dam Removal Affect Local Property Values? An Empirical Analysis Bill Provencher

    E-Print Network [OSTI]

    Provencher, R. William

    Does Small Dam Removal Affect Local Property Values? An Empirical Analysis Bill Provencher of small dam removal on property values in south-central Wisconsin. Data on residential property sales were obtained for three categories of sites: those where a dam is intact, those where a dam was recently removed

  5. Total nitrogen removal in a hybrid, membrane-aerated activated sludge process

    E-Print Network [OSTI]

    Nerenberg, Robert

    Total nitrogen removal in a hybrid, membrane-aerated activated sludge process Leon S. Downing wastewater. Air-filled hollow-fiber membranes are incorporated into an activated sludge tank removal in activated sludge. ª 2008 Elsevier Ltd. All rights reserved. 1. Introduction The removal

  6. Widget:RemovePDFImageDimensions | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-EnhancingEtGeorgia: EnergyMaryland:Meadow Lake,Maine:RemovePDFImageDimensions Jump to:

  7. A solvent system to provide selective removal of sulfur compounds

    SciTech Connect (OSTI)

    Pearce, R.L.; Bacon, T.R.

    1986-01-01

    Energy costs and SRU inefficiencies resulting from utilization of low strength MEA technology induced a large refinery to convert to MDEA. One of the seven product streams being treated required extremely low carbonyl sulfide in the treated product. This required careful consideration in making the decision to convert. However, the conclusions were that the advantages outweighed the disadvantages. When the initial converted operations verified a need to improve the carbonyl sulfide removal, GAS/SPEC Tech Service produced an innovative solution which allowed for efficient operation at acceptable COS specification, lower energy utilization, reduced solvent losses, and improved sulfur recovery unit operation.

  8. Process for removing carbonyl sulfide from gaseous streams

    SciTech Connect (OSTI)

    Tellis, C.

    1981-11-10

    This invention relates to a process for reducing the carbonyl sulfide content of a gaseous stream which has a concentration of carbonyl sulfide of from at least 1 to about 100 parts per million, by volume, which comprises providing an absorbent bed wherein the absorbent comprises zinc oxide and contains no more than 5%, by weight, of an oxide of an alkli or alkaline earth metal, and contacting said process stream with said adsorbent bed at a temperature of from about ambient to 250/sup 0/ C. For a period of time sufficient to remove at least 90% of the carbonyl sulfide content of said gaseous stream.

  9. Reactor Vessel Removal: Improving Performance Big Rock Point Lessons Learned

    SciTech Connect (OSTI)

    Daly, P.T. [BNG America, D and D Operations, 804 South Illinois Avenue, Oak Ridge, TN 37830 (United States)

    2006-07-01

    The Big Rock Point (BRP) reactor vessel was successfully removed, packaged in a Type B shipping container, transported, and buried. The process took almost 4 years of work by many people and a variety of companies. This paper will discuss several areas that can reduce schedule time, resulting in reduced cost and employee dose exposure. For maximum cost effectiveness, these lessons should be applied during the planning stages when developing baseline cost and schedule, As Low As Reasonably Achievable (ALARA) budgets, and work processes. (authors)

  10. Feed gas contaminant removal in ion transport membrane systems

    DOE Patents [OSTI]

    Underwood, Richard Paul (Allentown, PA); Makitka, III, Alexander (Hatfield, PA); Carolan, Michael Francis (Allentown, PA)

    2012-04-03

    An oxygen ion transport membrane process wherein a heated oxygen-containing gas having one or more contaminants is contacted with a reactive solid material to remove the one or more contaminants. The reactive solid material is provided as a deposit on a support. The one or more contaminant compounds in the heated oxygen-containing gas react with the reactive solid material. The contaminant-depleted oxygen-containing gas is contacted with a membrane, and oxygen is transported through the membrane to provide transported oxygen.

  11. System and method for removal of buried objects

    DOE Patents [OSTI]

    Alexander, Robert G. (Richland, WA); Crass, Dennis (Kennewick, WA); Grams, William (Kennewick, WA); Phillips, Steven J. (Sunnyside, WA); Riess, Mark (Kennewick, WA)

    2008-06-03

    The present invention is a system and method for removal of buried objects. According to one embodiment of the invention, a crane with a vibrator casing driver is used to lift and suspend a large diameter steel casing over the buried object. Then the casing is driven into the ground by the vibratory driver until the casing surrounds the buried object. Then the open bottom of the casing is sealed shut by injecting grout into the ground within the casing near its bottom. When the seal has cured and hardened, the top of the casing is lifted to retrieve the casing, with the buried object inside, from the ground.

  12. Analytical methods for removing radiological constituents prior to organic analysis

    SciTech Connect (OSTI)

    Hakonson, K.; Monagle, M.; Cournoyer, M.

    1997-12-31

    Within the Department of Energy (DOE), there is a need to analyze mixed waste materials (i.e. materials that are contaminated with both radiological and hazardous components). As part of the technical support the Organic Analysis Group provides for programs within Los Alamos National Laboratory, methods are under development for radiologically contaminated oil samples being tested for polychlorinated biphenyls and other semivolatile constituents. Radionuclides are removed from oil samples by filtering the samples through a commercials available solid phase extraction cartridge. An aliquot of the eluent is then analyzed to quantitate the residual radioactivity.

  13. Process for removal of hazardous air pollutants from coal

    DOE Patents [OSTI]

    Akers, David J. (Indiana, PA); Ekechukwu, Kenneth N. (Silver Spring, MD); Aluko, Mobolaji E. (Burtonsville, MD); Lebowitz, Howard E. (Mountain View, CA)

    2000-01-01

    An improved process for removing mercury and other trace elements from coal containing pyrite by forming a slurry of finely divided coal in a liquid solvent capable of forming ions or radicals having a tendency to react with constituents of pyrite or to attack the bond between pyrite and coal and/or to react with mercury to form mercury vapors, and heating the slurry in a closed container to a temperature of at least about 50.degree. C. to produce vapors of the solvent and withdrawing vapors including solvent and mercury-containing vapors from the closed container, then separating mercury from the vapors withdrawn.

  14. Method for removing cesium from a nuclear reactor coolant

    DOE Patents [OSTI]

    Colburn, Richard P. (Pasco, WA)

    1986-01-01

    A method of and system for removing cesium from a liquid metal reactor coolant including a carbon packing trap in the primary coolant system for absorbing a major portion of the radioactive cesium from the coolant flowing therethrough at a reduced temperature. A regeneration subloop system having a secondary carbon packing trap is selectively connected to the primary system for isolating the main trap therefrom and connecting it to the regeneration system. Increasing the temperature of the sodium flowing through the primary trap diffuses a portion of the cesium

  15. System for fuel rod removal from a reactor module

    DOE Patents [OSTI]

    Matchett, Richard L. (Bethel Park, PA); Roof, David R. (North Huntingdon, PA); Kikta, Thomas J. (Pittsburgh, PA); Wilczynski, Rosemarie (McKees Rocks, PA); Nilsen, Roy J. (Pittsburgh, PA); Bacvinskas, William S. (Bethel Park, PA); Fodor, George (Pittsburgh, PA)

    1990-01-01

    A robotic system for remote underwater withdrawal of the fuel rods from fuel modules of a light water breeder reactor includes a collet/grapple assembly for gripping and removing fuel rods in each module, which is positioned by use of a winch and a radial support means attached to a vertical support tube which is mounted over the fuel module. A programmable logic controller in conjunction with a microcomputer, provides control for the accurate positioning and pulling force of the rod grapple assembly. Closed circuit television cameras are provided which aid in operator interface with the robotic system.

  16. Method of removing and detoxifying a phosphorus-based substance

    DOE Patents [OSTI]

    Vandegrift, G.F.; Steindler, M.J.

    1985-05-21

    A method of removing a phosphorus-based poisonous substance from water contaminated is presented. In addition, the toxicity of the phosphorus-based substance is also subsequently destroyed. A water-immiscible organic solvent is first immobilized on a supported liquid membrane before the contaminated water is contacted with one side of the supported liquid membrane to absorb the phosphorus-based substance in the organic solvent. The other side of the supported liquid membrane is contacted with a hydroxy-affording strong base to react with phosphorus-based solvated species to form a non-toxic product.

  17. Process for removing an organic compound from water

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Kaschemekat, Jurgen (Palo Alto, CA); Wijmans, Johannes G. (Menlo Park, CA); Kamaruddin, Henky D. (San Francisco, CA)

    1993-12-28

    A process for removing organic compounds from water is disclosed. The process involves gas stripping followed by membrane separation treatment of the stripping gas. The stripping step can be carried out using one or multiple gas strippers and using air or any other gas as stripping gas. The membrane separation step can be carried out using a single-stage membrane unit or a multistage unit. Apparatus for carrying out the process is also disclosed. The process is particularly suited for treatment of contaminated groundwater or industrial wastewater.

  18. System for fuel rod removal from a reactor module

    DOE Patents [OSTI]

    Matchett, R.L.; Fodor, G.; Kikta, T.J.; Bacvinsicas, W.S.; Roof, D.R.; Nilsen, R.J.; Wilczynski, R.

    1988-07-28

    A robotic system for remote underwater withdrawal of the fuel rods from fuel modules of a light water breeder reactor includes a collet/grapple assembly for gripping and removing fuel rods in each module, which is positioned by use of a winch and a radial support means attached to a vertical support tube which is mounted over the fuel module. A programmable logic controller in conjunction with a microcomputer, provides control for the accurate positioning and pulling force of the rod grapple assembly. Closed circuit television cameras are provided which aid in operator interface with the robotic system. 7 figs.

  19. Method for removing organic liquids from aqueous solutions and mixtures

    DOE Patents [OSTI]

    Hrubesh, Lawrence W.; Coronado, Paul R.; Dow, Jerome P.

    2004-03-23

    A method for removing organic liquids from aqueous solutions and mixtures. The method employs any porous material preferably in granular form and having small pores and a large specific surface area, that is hydrophobic so that liquid water does not readily wet its surface. In this method, organics, especially organic solvents that mix with and are more volatile than water, are separated from aqueous solution by preferentially evaporating across the liquid/solid boundary formed at the surfaces of the hydrophobic porous materials. Also, organic solvents that are immiscible with water, preferentially wet the surfaces of the hydrophobic material and are drawn within the porous materials by capillary action.

  20. Extraction process for removing metallic impurities from alkalide metals

    DOE Patents [OSTI]

    Royer, L.T.

    1987-03-20

    A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.