National Library of Energy BETA

Sample records for relative humidity rh

  1. ARM - Relative Humidity Calculations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CalculatorsRelative Humidity Calculations Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Relative Humidity Calculations Heat Index is an index that combines air temperature and relative humidity to estimate how hot it actually feels. The human body cools off through perspiration, which

  2. Instrument uncertainty effect on calculation of absolute humidity using dewpoint, wet-bulb, and relative humidity sensors

    SciTech Connect (OSTI)

    Slayzak, S.J.; Ryan, J.P.

    1998-04-01

    As part of the US Department of Energy`s Advanced Desiccant Technology Program, the National Renewable Energy Laboratory (NREL) is characterizing the state-of-the-art in desiccant dehumidifiers, the key component of desiccant cooling systems. The experimental data will provide industry and end users with independent performance evaluation and help researchers assess the energy savings potential of the technology. Accurate determination of humidity ratio is critical to this work and an understanding of the capabilities of the available instrumentation is central to its proper application. This paper compares the minimum theoretical random error in humidity ratio calculation for three common measurement methods to give a sense of the relative maximum accuracy possible for each method assuming systematic errors can be made negligible. A series of experiments conducted also illustrate the capabilities of relative humidity sensors as compared to dewpoint sensors in measuring the grain depression of desiccant dehumidifiers. These tests support the results of the uncertainty analysis. At generally available instrument accuracies, uncertainty in calculated humidity ratio for dewpoint sensors is determined to be constant at approximately 2%. Wet-bulb sensors range between 2% and 6% above 10 g/kg (4%--15% below), and relative humidity sensors vary between 4% above 90% rh and 15% at 20% rh. Below 20% rh, uncertainty for rh sensors increases dramatically. Highest currently attainable accuracies bring dewpoint instruments down to 1% uncertainty, wet bulb to a range of 1%--3% above 10 g/kg (1.5%--8% below), and rh sensors between 1% and 5%.

  3. Oxygen and relative humidity monitoring with films tailored for enhanced photoluminescence

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cui, Weipan; Liu, Rui; Manna, Eeshita; Park, Joong -Mok; Fungura, Fadzai; Shinar, Joseph; Shinar, Ruth

    2014-10-31

    In this study, approaches to generate porous or doped sensing films, which significantly enhance the photoluminescence (PL) of oxygen optical sensors, and thus improve the signal-to-noise (S/N) ratio, are presented. Tailored films, which enable monitoring the relative humidity (RH) as well, are also presented. Effective porous structures, in which the O2-sensitive dye Pt octaethylporphyrin (PtOEP) or the Pd analog PdOEP was embedded, were realized by first generating blend films of polyethylene glycol (PEG) with polystyrene (PS) or with ethyl cellulose (EC), and then immersing the dried films in water to remove the water-soluble PEG. This approach creates pores (voids) inmore » the sensing films. The dielectric contrast between the films’ constituents and the voids increases photon scattering, which in turn increases the optical path of the excitation light within the film, and hence light absorption by the dye, and its PL. Optimized sensing films with a PEG:PS ratio of 1:4 (PEG’s molecular weight Mw ~8000) led to ~4.4× enhancement in the PL (in comparison to PS films). Lower Mw ~200 PEG with a PEG:EC ratio of 1:1 led to a PL enhancement of ~4.7×. Film-dependent PL enhancements were observed at all oxygen concentrations. The strong PL enhancement enables (i) using lower dye (luminophore) concentrations, (ii) reducing power consumption and enhancing the sensor’s operational lifetime when using organic light emitting diodes (OLEDs) as excitation sources, (iii) improving performance when using compact photodetectors with no internal gain, and (iv) reliably extending the dynamic range.« less

  4. MHK ISDB/Sensors/12-bit Temperature/Relative Humidity (2m cable...

    Open Energy Info (EERE)

    (1) Relative Humidity (8m cable) Smart Sensor ... further results Also made by Onset Computer Corporation HOBO RX3000 Remote Monitoring SystemHOBO RX3000 Remote Monitoring...

  5. MHK ISDB/Sensors/12-bit Temperature/Relative Humidity (8m cable...

    Open Energy Info (EERE)

    (1) Relative Humidity (2m cable) Smart Sensor ... further results Also made by Onset Computer Corporation HOBO RX3000 Remote Monitoring SystemHOBO RX3000 Remote Monitoring...

  6. Humidity effects on wire insulation breakdown strength.

    SciTech Connect (OSTI)

    Appelhans, Leah

    2013-08-01

    Methods for the testing of the dielectric breakdown strength of insulation on metal wires under variable humidity conditions were developed. Two methods, an ASTM method and the twisted pair method, were compared to determine if the twisted pair method could be used for determination of breakdown strength under variable humidity conditions. It was concluded that, although there were small differences in outcomes between the two testing methods, the non-standard method (twisted pair) would be appropriate to use for further testing of the effects of humidity on breakdown performance. The dielectric breakdown strength of 34G copper wire insulated with double layer Poly-Thermaleze/Polyamide-imide insulation was measured using the twisted pair method under a variety of relative humidity (RH) conditions and exposure times. Humidity at 50% RH and below was not found to affect the dielectric breakdown strength. At 80% RH the dielectric breakdown strength was significantly diminished. No effect for exposure time up to 140 hours was observed at 50 or 80%RH.

  7. RELATIVE HUMIDITY TESTS IN SUPPORT OF THE 3013 STORAGE AND SURVEILLANCE PROGRAM

    SciTech Connect (OSTI)

    Mickalonis, J.; Duffey, J.

    2011-08-01

    Techniques to control the initial relative humidity over oxide/salt mixtures have been developed using cerium oxide as a surrogate for plutonium oxide. Such control is required to validate certain assumptions in the Department of Energy Standard DOE-STD-3013, and to provide essential information to support field surveillance at the storage sites for excess plutonium oxides. Concern over the validity of the assumption that corrosion induced degradation in 3013 containers could be controlled by assuring that the moisture content of any stored oxide/salt mixture was below 0.5 w t% arose when stress corrosion cracks were found in test samples exposed at room temperature to plutonium oxide/salt mixtures having a moisture content only marginally above 0.5 wt %. Additionally, analysis of the stress corrosion cracking observations suggests that the initial relative humidity over the oxide/salt mixture may play a major role in the cracking process. The investigations summarized in this report provide the procedures necessary to control the initial relative humidity to selected values within the range of 16 to 50% by controlling the loading relative humidity (18 to 60%) and the oxide/salt mixture water content (0.05 to 0.45 wt %). The studies also demonstrated that the initial relative humidity may be estimated by calculations using software EQ3/6. Cerium oxide/salt mixtures were used in this study because qualification tests with non-radioactive materials will reduce costs while increasing the breadth of the test programs required to support field surveillances of stored 3013 containers.

  8. Fluorescence spectra and biological activity of aerosolized bacillus spores and MS2 bacteriophage exposed to ozone at different relative humidities in a rotating drum

    SciTech Connect (OSTI)

    Ratnesar-Shumate, Shanna; Pan, Yong-Le; Hill, Steven C.; Kinahan, Sean; Corson, Elizabeth; Eshbaugh, Jonathan; Santarpia, Joshua L.

    2015-10-14

    Biological aerosols (bioaerosols) released into the environment may undergo physical and chemical transformations when exposed to atmospheric constituents such as solar irradiation, reactive oxygenated species, ozone, free radicals, water vapor and pollutants. Aging experiments were performed in a rotating drum chamber subjecting bioaerosols, Bacillus thuringiensis Al Hakam (BtAH) spores and MS2 bacteriophages to ozone at 0 and 150 ppb, and relative humidities (RH) at 10%, 50%, and 80+%. Fluorescence spectra and intensities of the aerosols as a function of time in the reaction chamber were measured with a single particle fluorescence spectrometer (SPFS) and an Ultra-Violet Aerodynamic Particle Sizer® Spectrometer (UV-APS). Losses in biological activity were measured by culture and quantitative polymerase chain reaction (q-PCR) assay. For both types of aerosols the largest change in fluorescence emission was between 280 and 400 nm when excited at 263 nm followed by fluorescence emission between 380 and 700 nm when excited at 351 nm. The fluorescence for both BtAH and MS2 were observed to decrease significantly at high ozone concentration and high RH when excited at 263 nm excitation. The decreases in 263 nm excited fluorescence are indicative of hydrolysis and oxidation of tryptophan in the aerosols. Fluorescence measured with the UV-APS (355-nm excitation) increased with time for both BtAH and MS2 aerosols. A two log loss of MS2 bacteriophage infectivity was observed in the presence of ozone at ~50% and 80% RH when measured by culture and normalized for physical losses by q-PCR. Viability of BtAH spores after exposure could not be measured due to the loss of genomic material during experiments, suggesting degradation of extracelluar DNA attributable to oxidation. The results of these studies indicate that the physical and biological properties of bioaerosols change significantly after exposure to ozone and water vapor.

  9. Fluorescence spectra and biological activity of aerosolized bacillus spores and MS2 bacteriophage exposed to ozone at different relative humidities in a rotating drum

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ratnesar-Shumate, Shanna; Pan, Yong-Le; Hill, Steven C.; Kinahan, Sean; Corson, Elizabeth; Eshbaugh, Jonathan; Santarpia, Joshua L.

    2015-10-14

    Biological aerosols (bioaerosols) released into the environment may undergo physical and chemical transformations when exposed to atmospheric constituents such as solar irradiation, reactive oxygenated species, ozone, free radicals, water vapor and pollutants. Aging experiments were performed in a rotating drum chamber subjecting bioaerosols, Bacillus thuringiensis Al Hakam (BtAH) spores and MS2 bacteriophages to ozone at 0 and 150 ppb, and relative humidities (RH) at 10%, 50%, and 80+%. Fluorescence spectra and intensities of the aerosols as a function of time in the reaction chamber were measured with a single particle fluorescence spectrometer (SPFS) and an Ultra-Violet Aerodynamic Particle Sizer® Spectrometermore » (UV-APS). Losses in biological activity were measured by culture and quantitative polymerase chain reaction (q-PCR) assay. For both types of aerosols the largest change in fluorescence emission was between 280 and 400 nm when excited at 263 nm followed by fluorescence emission between 380 and 700 nm when excited at 351 nm. The fluorescence for both BtAH and MS2 were observed to decrease significantly at high ozone concentration and high RH when excited at 263 nm excitation. The decreases in 263 nm excited fluorescence are indicative of hydrolysis and oxidation of tryptophan in the aerosols. Fluorescence measured with the UV-APS (355-nm excitation) increased with time for both BtAH and MS2 aerosols. A two log loss of MS2 bacteriophage infectivity was observed in the presence of ozone at ~50% and 80% RH when measured by culture and normalized for physical losses by q-PCR. Viability of BtAH spores after exposure could not be measured due to the loss of genomic material during experiments, suggesting degradation of extracelluar DNA attributable to oxidation. The results of these studies indicate that the physical and biological properties of bioaerosols change significantly after exposure to ozone and water vapor.« less

  10. Ferrocyanide safety program: Results of relative humidity experiments using ferrocyanide waste simulants

    SciTech Connect (OSTI)

    King, C.V.

    1994-10-01

    To be categorized as conditionally safe, ferrocyanide tanks containing {ge} 8 wt% Na{sub 2}NiFe(CN){sub 6} on an energy equivalent basis (i.e., {ge} 115 cal/g) are required to contain some amount of water. These tests were conducted to determine the equilibrium moisture content of waste simulant at the conditions of 30% relative humidity and 25{degrees}C. This test report was prepared to disseminate data collected from these tests. These data are used to model the waste tank moisture contents and transport. These models can determine if the moisture in these tanks will drop below the defined safety limits.

  11. Superconductivity versus structural phase transition in the closely related Bi2Rh3.5S2 and Bi2Rh3S2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kaluarachchi, Udhara S.; Xie, Weiwei; Lin, Qisheng; Taufour, Valentin; Bud'ko, Sergey L.; Miller, Gordon J.; Canfield, Paul C.

    2015-05-19

    Single crystals of Bi2Rh3S2 and Bi2Rh3.5S2 were synthesized by solution growth, and the crystal structures and thermodynamic and transport properties of both compounds were studied. In the case of Bi2Rh3S2, a structural first-order transition at around 165 K is identified by single-crystal diffraction experiments, with clear signatures visible in resistivity, magnetization, and specific heat data. No superconducting transition for Bi2Rh3S2 was observed down to 0.5 K. In contrast, no structural phase transition at high temperature was observed for Bi2Rh3.5S2; however, bulk superconductivity with a critical temperature, Tc ≈ 1.7 K, was observed. The Sommerfeld coefficient γ and the Debye temperaturemore » (ΘD) were found to be 9.41 mJ mol–1K–2 and 209 K, respectively, for Bi2Rh3S2, and 22 mJ mol–1K–2 and 196 K, respectively, for Bi2Rh3.5S2. As a result, the study of the specific heat in the superconducting state of Bi2Rh3.5S2 suggests that Bi2Rh3.5S2 is a weakly coupled, BCS superconductor.« less

  12. SRNL PHASE II SHELF LIFE STUDIES - SERIES 1 ROOM TEMPERATURE AND HIGH RELATIVE HUMIDITY

    SciTech Connect (OSTI)

    Mickalonis, J.; Duffey, J.

    2012-09-12

    The Savannah River National Laboratory (SRNL) Phase II, Series 1 shelf-life corrosion testing for the Department of Energy Standard 3013 container is presented and discussed in terms of the localized corrosion behavior of Type 304 stainless steel in contact with moist plutonium oxide and chloride salt mixtures and the potential impact to the 3013 inner container. This testing was designed to address the influence of temperature, salt composition, initial salt moisture, residual stress and type of oxide/salt contact on the relative humidity inside a 3013 container and the initiation and propagation of localized corrosion, especially stress corrosion cracking. The integrated plan is being conducted by Los Alamos National Laboratory and SRNL. SRNL is responsible for conducting a corrosion study in small scale vessels containing plutonium oxide and chloride salts under conditions of humidity, temperature and oxide/salt compositions both within the limits of 3013 storage conditions as well as beyond the 3013 storage requirements to identify margins for minimizing the initiation of stress corrosion cracking. These worst case conditions provide data that bound the material packaged in 3013 containers. Phase I of this testing was completed in 2010. The Phase II, Series 1 testing was performed to verify previous results from Phase I testing and extend our understanding about the initiation of stress corrosion cracking and pitting that occur in 304L under conditions of room temperature, high humidity, and a specific plutonium oxide/salt chemistry. These results will aid in bounding the safe storage conditions of plutonium oxides in 3013 containers. A substantial change in the testing was the addition of the capability to monitor relative humidity during test exposure. The results show that under conditions of high initial moisture ({approx}0.5 wt%) and room temperature stress corrosion cracking occurred in 304L teardrop coupons in contact with the oxide/salt mixture at times as short as 85 days. In all cases, the cracking appeared to be associated with pitting or localized general corrosion. Crack initiation at other sites, such as surface imperfections or inclusions, cannot be excluded. Cracks appear in most cases to initiate through an intergranular mode and transition to a transgranular mode.

  13. Lead Research and Development Activity for DOE's High Temperature, Low Relative Humidity Membrane Program (Topic 2)

    SciTech Connect (OSTI)

    James Fenton, PhD; Darlene Slattery, PhD; Nahid Mohajeri, PhD

    2012-09-05

    The Department of Energy’s High Temperature, Low Relative Humidity Membrane Program was begun in 2006 with the Florida Solar Energy Center (FSEC) as the lead organization. During the first three years of the program, FSEC was tasked with developing non-Nafion® proton exchange membranes with improved conductivity for fuel cells. Additionally, FSEC was responsible for developing protocols for the measurement of in-plane conductivity, providing conductivity measurements for the other funded teams, developing a method for through-plane conductivity and organizing and holding semiannual meetings of the High Temperature Membrane Working Group (HTMWG). The FSEC membrane research focused on the development of supported poly[perfluorosulfonic acid] (PFSA) – Teflon membranes and a hydrocarbon membrane, sulfonated poly(ether ether ketone). The fourth generation of the PFSA membrane (designated FSEC-4) came close to, but did not meet, the Go/No-Go milestone of 0.1 S/cm at 50% relative humidity at 120 °C. In-plane conductivity of membranes provided by the funded teams was measured and reported to the teams and DOE. Late in the third year of the program, DOE used this data and other factors to decide upon the teams to continue in the program. The teams that continued provided promising membranes to FSEC for development of membrane electrode assemblies (MEAs) that could be tested in an operating fuel cell. FSEC worked closely with each team to provide customized support. A logic flow chart was developed and discussed before MEA fabrication or any testing began. Of the five teams supported, by the end of the project, membranes from two of the teams were easily manufactured into MEAs and successfully characterized for performance. One of these teams exceeded performance targets, while the other requires further optimization. An additional team developed a membrane that shows great promise for significantly reducing membrane costs and increasing membrane lifetime.

  14. Temperature, Humidity, Wind and Pressure Sensors (THWAPS) Handbook

    SciTech Connect (OSTI)

    Ritsche, MT

    2011-01-17

    The temperature, humidity, wind, and pressure system (THWAPS) provide surface reference values of these measurements for balloon-borne sounding system (SONDE) launches. The THWAPS is located adjacent to the SONDE launch site at the Southern Great Plains (SGP) Central Facility. The THWAPS system is a combination of calibration-quality instruments intended to provide accurate measurements of meteorological conditions near the surface. Although the primary use of the system is to provide accurate surface reference values of temperature, pressure, relative humidity (RH), and wind velocity for comparison with radiosonde readings, the system includes a data logger to record time series of the measured variables.

  15. Radiosondes Corrected for Inaccuracy in RH Measurements

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Miloshevich, Larry

    2008-01-15

    Corrections for inaccuracy in Vaisala radiosonde RH measurements have been applied to ARM SGP radiosonde soundings. The magnitude of the corrections can vary considerably between soundings. The radiosonde measurement accuracy, and therefore the correction magnitude, is a function of atmospheric conditions, mainly T, RH, and dRH/dt (humidity gradient). The corrections are also very sensitive to the RH sensor type, and there are 3 Vaisala sensor types represented in this dataset (RS80-H, RS90, and RS92). Depending on the sensor type and the radiosonde production date, one or more of the following three corrections were applied to the RH data: Temperature-Dependence correction (TD), Contamination-Dry Bias correction (C), Time Lag correction (TL). The estimated absolute accuracy of NIGHTTIME corrected and uncorrected Vaisala RH measurements, as determined by comparison to simultaneous reference-quality measurements from Holger Voemel's (CU/CIRES) cryogenic frostpoint hygrometer (CFH), is given by Miloshevich et al. (2006).

  16. Accelerated Testing and Modeling of Potential-Induced Degradation as a Function of Temperature and Relative Humidity

    SciTech Connect (OSTI)

    Hacke, Peter; Spataru, Sergiu; Terwilliger, Kent; Perrin, Greg; Glick, Stephen; Kurtz, Sarah; Wohlgemuth, John

    2015-06-14

    An acceleration model based on the Peck equation was applied to power performance of crystalline silicon cell modules as a function of time and of temperature and humidity, the two main environmental stress factors that promote potential-induced degradation. This model was derived from module power degradation data obtained semi-continuously and statistically by in-situ dark current-voltage measurements in an environmental chamber. The modeling enables prediction of degradation rates and times as functions of temperature and humidity. Power degradation could be modeled linearly as a function of time to the second power; additionally, we found that coulombs transferred from the active cell circuit to ground during the stress test is approximately linear with time. Therefore, the power loss could be linearized as a function of coulombs squared. With this result, we observed that when the module face was completely grounded with a condensed phase conductor, leakage current exceeded the anticipated corresponding degradation rate relative to the other tests performed in damp heat.

  17. In Situ Validation of a Correction for Time-Lag and Bias Errors in Vaisala RS80-H Radiosonde Humidity Measurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In Situ Validation of a Correction for Time-Lag and Bias Errors in Vaisala RS80-H Radiosonde Humidity Measurements L. M. Miloshevich National Center for Atmospheric Research Boulder, Colorado H. Vömel and S. J. Oltmans National Oceanic and Atmospheric Administration Boulder, Colorado A. Paukkunen Vaisala Oy Helsinki, Finland Introduction Radiosonde relative humidity (RH) measurements are fundamentally important to Atmospheric Radiation Measurement (ARM) Program goals because they are used in a

  18. Measured Cooling Season Results Relating the Impact of Mechanical Ventilation on Energy, Comfort, and Indoor Air Quality in Humid Climates

    SciTech Connect (OSTI)

    Martin, Eric; Amos, Bryan; McIlvaine, Janet; Chasar, David; Widder, Sarah H.; Fonorow, Ken

    2014-08-22

    Conference Paper for ACEEE Summer Study in Buildings discussing results to date of a project evaluating the impact of ventialtion on energy use, comfort, durability, and cost in the hot humid climate.

  19. EFFECT OF TEMPERATURE AND HUMIDITY ON FORMALDEHYDE EMISSIONS IN TEMPORARY HOUSING UNITS

    SciTech Connect (OSTI)

    Parthasarathy, Srinandini; Maddalena, Randy L.; Russell, Marion L.; Apte, Michael G.

    2010-04-01

    The effect of temperature and humidity on formaldehyde emissions from samples collected from temporary housing units (THUs) was studied. The THUs were supplied by the U.S Federal Emergency Management Administration (FEMA) to families that lost their homes in Louisiana and Mississippi during the Hurricane Katrina and Rita disasters. Based on a previous study 1, 2, four of the composite wood surface materials that dominated contributions to indoor formaldehyde were selected to analyze the effects of temperature and humidity on the emission factors. Humidity equilibration experiments were carried out on two of the samples to determine how long the samples take to equilibrate with the surrounding environmental conditions. Small chamber experiments were then conducted to measure emission factors for the four surface materials at various temperature and humidity conditions. The samples were analyzed for formaldehyde via high performance liquid chromatography. The experiments showed that increases in temperature or humidity contributed to an increase in emission factors. A linear regression model was built using natural log of percentage relative humidity (RH) and inverse of temperature (in K) as predictor variables, and natural log of emission factors as the target variable. The coefficients of both inverse temperature and log relative humidity with log emission factor were found to be statistically significant for all the samples at the 95percent confidence level. This study should assist to retrospectively estimate indoor formaldehyde exposures of occupants of temporary housing units (THUs).

  20. Photooxidation of Alpha-Pinene at High Relative Humidity in the Presence of Increasing Concentrations of NOx

    SciTech Connect (OSTI)

    Yu, Yong; Ezell, Michael J.; Zelenyuk, Alla; Imre, Dan G.; Alexander, M. Lizabeth; Ortega, John V.; D'Anna, Barbara; Harmon, Chris W.; Johnson, Stan; Finlayson-Pitts, Barbara J.

    2008-06-01

    The photooxidation of ~1 ppm alpha-pinene in the presence of increasing concentrations of NO2 was studied in a Teflon chamber at relative humidities from 70 - 88% and temperatures from 296 - 304 K. The loss of alpha-pinene and formation of gas phase products were followed using proton transfer reaction mass spectrometry (PTR-MS). Gas phase reaction products measured by PTR-MS and their yields include formaldehyde (5 + 1%), formic acid (2.5 + 1.4%), methanol (0.6 + 0.3%), acetaldehyde (3.9 + 1.7%), acetic acid (10 + 2%), acetone (11.5 + 3.1%), pinonaldehyde (22 + 6%), and pinene oxide (0.9 + 0.1%). There was evidence of organic nitrates in the gas phase and small peaks were tentatively assigned to norpinonaldehyde, 4-oxopinonaldehyde, propanedial, 2,3-dioxobutanal and 3,5,6-trioxoheptanal or 3-hydroxymethyl-2,2-dimethylcyclobutylethanone. The formation and growth of new particles were followed using a scanning mobility particle sizer (SMPS), and their chemical composition was probed using single particle mass spectrometry (SPLAT II). SPLAT II analysis also provided measurements of the vacuum aerodynamic diameters of the newly formed secondary organic aerosol (SOA) particles and, in combination with the electrical mobility diameter, a particle density of 1.21 + 0.02 g cm-3 was calculated, 20% larger than often assumed in calculating SOA yields. SPLAT II showed that the suspended SOA consisted of a complex mixture of organic nitrates and organics, possibly including pinonic acid, pinic acid and trans-sobrerol. Three-wavelength light scattering measurements made using an integrating nephelometer were consistent with particles having a refractive index characteristic of organic compounds, but the data could not be well matched at all three wavelengths with a single refractive index. The effect of addition of cyclohexane or NO on particle formation showed that ozonolysis was the major mechanism of SOA formation in this system. However, unlike simple ozonolysis, organic nitrates are formed in both the gas and particle phases. Identifying and measuring specific organic nitrates in both the gas and particle phases in air may help to elucidate why SOA formation has been reported in field studies to be associated with polluted urban areas, yet the carbon in these particles is largely contemporary, i.e., non-fossil fuel carbon.

  1. RH Packaging Program Guidance

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2008-01-12

    The purpose of this program guidance document is to provide the technical requirements for use, operation, inspection, and maintenance of the RH-TRU 72-B Waste Shipping Package (also known as the "RH-TRU 72-B cask") and directly related components. This document complies with the requirements as specified in the RH-TRU 72-B Safety Analysis Report for Packaging (SARP), and Nuclear Regulatory Commission (NRC) Certificate of Compliance (C of C) 9212. If there is a conflict between this document and the SARP and/or C of C, the C of C shall govern. The C of C states: "...each package must be prepared for shipment and operated in accordance with the procedures described in Chapter 7.0, Operating Procedures, of the application." It further states: "...each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application." Chapter 9.0 of the SARP tasks the Waste Isolation Pilot Plant (WIPP) Management and Operating (M&O) Contractor with assuring the packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with Title 10 Code of Federal Regulations (CFR) 71.8, "Deliberate Misconduct." Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the U.S. Department of Energy (DOE) Carlsbad Field Office (CBFO) shall be notified immediately. The CBFO will evaluate the issue and notify the NRC if required.In accordance with 10 CFR Part 71, "Packaging and Transportation of Radioactive Material," certificate holders, packaging users, and contractors or subcontractors who use, design, fabricate, test, maintain, or modify the packaging shall post copies of (1) 10 CFR Part 21, "Reporting of Defects and Noncompliance," regulations, (2) Section 206 of the Energy Reorganization Act of 1974, and (3) NRC Form 3, Notice to Employees. These documents must be posted in a conspicuous location where the activities subject to these regulations are conducted. This document details the instructions to be followed to operate, maintain, and test the RH-TRU 72-B packaging. This Program Guidance standardizes instructions for all users. Users shall follow these instructions or equivalent approved instructions. Following these instructions assures that operations meet the requirements of the SARP.

  2. Evaluation of the response of tritium-in-air instrumentation to HT in dry and humid conditions and to HTO vapor

    SciTech Connect (OSTI)

    Phillips, H.; Dean, J.; Privas, E.

    2015-03-15

    Nuclear plant operators (power generation, decommissioning and reprocessing operations) are required to monitor releases of tritium species for regulatory compliance and radiation protection purposes. Tritium monitoring is performed using tritium-in-air gas monitoring instrumentation based either on flow-through ion chambers or proportional counting systems. Tritium-in-air monitors are typically calibrated in dry conditions but in service may operate at elevated levels of relative humidity. The NPL (National Physical Laboratory) radioactive gas-in-air calibration system has been used to study the effect of humidity on the response to tritium of two tritium-in-air ion chamber based monitors and one proportional counting system which uses a P10/air gas mixture. The response of these instruments to HTO vapour has also been evaluated. In each case, instrument responses were obtained for HT in dry conditions (relative humidity (RH) about 2%), HT in 45% RH, and finally HTO at 45% RH. Instrumentation response to HT in humid conditions has been found to slightly exceed that in dry conditions. (authors)

  3. RH Packaging Program Guidance

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2006-11-07

    The purpose of this program guidance document is to provide the technical requirements for use, operation, inspection, and maintenance of the RH-TRU 72-B Waste Shipping Package and directly related components. This document complies with the requirements as specified in the RH-TRU 72-B Safety Analysis Report for Packaging (SARP), and Nuclear Regulatory Commission (NRC) Certificate of Compliance (C of C) 9212. If there is a conflict between this document and the SARP and/or C of C, the C of C shall govern. The C of C states: "...each package must be prepared for shipment and operated in accordance with the procedures described in Chapter 7.0, Operating Procedures, of the application." It further states: "...each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application." Chapter 9.0 of the SARP tasks the Waste Isolation Pilot Plant (WIPP) Management and Operating (M&O) Contractor with assuring the packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with 10 Code of Federal Regulations (CFR) 71.8, "Deliberate Misconduct." Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the U.S. Department of Energy (DOE) Carlsbad Field Office (CBFO) shall be notified immediately. CBFO will evaluate the issue and notify the NRC if required. In accordance with 10 CFR Part 71, "Packaging and Transportation of Radioactive Material," certificate holders, packaging users, and contractors or subcontractors who use, design, fabricate, test, maintain, or modify the packaging shall post copies of (1) 10 CFR Part 21, "Reporting of Defects and Noncompliance," regulations, (2) Section 206 of the Energy Reorganization Act of 1974, and (3) NRC Form 3, Notice to Employees. These documents must be posted in a conspicuous location where the activities subject to these regulations are conducted. This document details the instructions to be followed to operate, maintain, and test the RH-TRU 72-B packaging. This Program Guidance standardizes instructions for all users. Users shall follow these instructions or equivalent approved instructions. Following these instructions assures that operations meet the requirements of the SARP.

  4. Humid-air and aqueous corrosion models for corrosion-allowance barrier material

    SciTech Connect (OSTI)

    Lee, J.H.; Atkins, J.E.; Andrews, R.W.

    1995-12-31

    Humid-air and aqueous general and pitting corrosion models (including their uncertainties) for the carbon steel outer containment barrier were developed using the corrosion data from literature for a suite of cast irons and carbon steels which have similar corrosion behaviors to the outer barrier material. The corrosion data include the potential effects of various chemical species present in the testing environments. The atmospheric corrosion data also embed any effects of cyclic wetting and drying and salts that may form on the corroding specimen surface. The humid-air and aqueous general corrosion models are consistent in that the predicted humid-air general corrosion rates at relative humidities between 85 and 100% RH are close to the predicted aqueous general corrosion rates. Using the expected values of the model parameters, the model predicts that aqueous pitting corrosion is the most likely failure mode for the carbon steel outer barrier, and an earliest failure (or initial pit penetration) of the 100-mm thick barrier may occur as early as about 500 years if it is exposed continuously to an aqueous condition at between 60 and 70{degrees}C.

  5. Improving Comfort in Hot-Humid Climates with a Whole-House Dehumidifier, Windermere, Florida (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-11-01

    Maintaining comfort in a home can be challenging in hot-humid climates. At the common summer temperature set point of 75 degrees F, the perceived air temperature can vary by 11 degrees F because higher indoor humidity reduces comfort. Often the air conditioner (AC) thermostat set point is lower than the desirable cooling level to try to increase moisture removal so that the interior air is not humid or "muggy." However, this method is not always effective in maintaining indoor relative humidity (RH) or comfort. In order to quantify the performance of a combined whole-house dehumidifier (WHD) AC system, researchers from the U.S. Department of Energy's Building America team Consortium of Advanced Residential Buildings (CARB) monitored the operation of two Lennox AC systems coupled with a Honeywell DH150 TrueDRY whole-house dehumidifier for a six-month period. By using a WHD to control moisture levels (latent cooling) and optimizing a central AC to control temperature (sensible cooling), improvements in comfort can be achieved while reducing utility costs. Indoor comfort for this study was defined as maintaining indoor conditions at below 60% RH and a humidity ratio of 0.012 lbm/lbm while at common dry bulb set point temperatures of 74 degrees -80 degrees F. In addition to enhanced comfort, controlling moisture to these levels can reduce the risk of other potential issues such as mold growth, pests, and building component degradation. Because a standard AC must also reduce dry bulb air temperature in order to remove moisture, a WHD is typically needed to support these latent loads when sensible heat removal is not desired.

  6. RH-TRU Waste Content Codes (RH-TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions LLC

    2007-08-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is 3. The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR limits based on a 10-day shipping period (rather than the standard 60-day shipping period) may be used as specified in an approved content code. Requests for new or revised content codes may be submitted to the WIPP RH-TRU Payload Engineer for review and approval, provided all RH-TRAMPAC requirements are met.

  7. Optical humidity sensor

    DOE Patents [OSTI]

    Tarvin, J.A.

    1987-02-10

    An optical dielectric humidity sensor is disclosed which includes a dielectric mirror having multiple alternating layers of two porous water-adsorbent dielectric materials with differing indices of refraction carried by a translucent substrate. A narrow-band polarized light source is positioned to direct light energy onto the mirror, and detectors are positioned to receive light energy transmitted through and reflected by the mirror. A ratiometer indicates humidity in the atmosphere which surrounds the dielectric mirror as a function of a ratio of light energies incident on the detectors. 2 figs.

  8. RH-TRU Waste Content Codes (RH TRUCON)

    SciTech Connect (OSTI)

    Washington TRU Solutions

    2007-05-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is 3. The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR limits based on a 10-day shipping period (rather than the standard 60-day shipping period) may be used as specified in an approved content code.

  9. Optical Properties of Moderately-Absorbing Organic and Mixed Organic/Inorganic Particles at Very High Humidities

    SciTech Connect (OSTI)

    Bond, Tami C; Rood, Mark J; Brem, Benjamin T; Mena-Gonzalez, Francisco C; Chen, Yanju

    2012-04-16

    Relative humidity (RH) affects the water content of an aerosol, altering its ability to scatter and absorb light, which is important for aerosol effects on climate and visibility. This project involves in situ measurement and modeling of aerosol optical properties including absorption, scattering and extinction at three visible wavelengths (467, 530, 660 nm), for organic carbon (OC) generated by pyrolysis of biomass, ammonium sulfate and sodium chloride, and their mixtures at controlled RH conditions. Novel components of this project include investigation of: (1) Changes in all three of these optical properties at scanned RH conditions; (2) Optical properties at RH values up to 95%, which are usually extrapolated instead of measured; and (3) Examination of aerosols generated by the pyrolysis of wood, which is representative of primary atmospheric organic carbon, and its mixture with inorganic aerosol. Scattering and extinction values were used to determine light absorption by difference and single scattering albedo values. Extensive instrumentation development and benchmarking with independently measured and modeled values were used to obtain and evaluate these new results. The single scattering albedo value for a dry absorbing polystyrene microsphere benchmark agreed within 0.02 (absolute value) with independently published results at 530 nm. Light absorption by a nigrosin (sample light-absorbing) benchmark increased by a factor of 1.24 +/-0.06 at all wavelengths as RH increased from 38 to 95%. Closure modeling with Mie theory was able to reproduce this increase with the linear volume average (LVA) refractive index mixing rule for this water soluble compound. Absorption by biomass OC aerosol increased by a factor of 2.1 +/- 0.7 and 2.3 +/- 1.2 between 32 and 95% RH at 467 nm and 530 nm, but there was no detectable absorption at 660 nm. Additionally, the spectral dependence of absorption by OC that was observed with filter measurements was confirmed qualitatively in situ at 467 and 530 nm. Closure modeling with the dynamic effective medium approximation (DEMA) refractive index model was able to capture the increasing absorption trend with RH indicating that the droplets were heterogeneously mixed while containing dispersed insoluble absorbing material within those droplets. Seven other refractive index mixing models including LVA did not adequately describe the measurements for OC. Mixing the biomass OC aerosol with select mass fractions of ammonium sulfate ranging from 25 to 36% and sodium chloride ranging from 21 to 30% resulted in an increase in light scattering and extinction with RH and inorganic mass fraction. However, no detectable difference in light absorption behavior in comparison to pure biomass OC was observed. The main finding of this research is a measured increase in absorption with increasing RH, which is currently not represented in radiative transfer models even though biomass burning produces most of the primary OC aerosol in the atmosphere.

  10. RH_SRS_Shipment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WIPP Trucks Delivering First Remote-Handled Transuranic Waste from the Savannah River Site CARLSBAD, N.M., June 11, 2012- Photo caption: On June 7, 2012, Waste Isolation Pilot Plant (WIPP) trucks approach the WIPP facility near Carlsbad, New Mexico, with the first shipment of defense- related remote-handled transuranic (TRU) waste from Savannah River Site (SRS), near Aiken, South Carolina. TRU waste consists of materials contaminated with radioactive elements that have atomic numbers greater

  11. Data Center Economizer Contamination and Humidity Study

    SciTech Connect (OSTI)

    Shehabi, Arman; Tschudi, William; Gadgil, Ashok

    2007-03-06

    Data centers require continuous air conditioning to address high internal heat loads (heat release from equipment) and maintain indoor temperatures within recommended operating levels for computers. Air economizer cycles, which bring in large amounts of outside air to cool internal loads when weather conditions are favorable, could save cooling energy. There is reluctance from many data center owners to use this common cooling technique, however, due to fear of introducing pollutants and potential loss of humidity control. Concerns about equipment failure from airborne pollutants lead to specifying as little outside air as permissible for human occupants. To investigate contamination levels, particle monitoring was conducted at 8 data centers in Northern California. Particle counters were placed at 3 to 4 different locations within and outside of each data center evaluated in this study. Humidity was also monitored at many of the sites to determine how economizers affect humidity control. Results from this study indicate that economizers do increase the outdoor concentration in data centers, but this concentration, when averaged annually, is still below current particle concentration limits. Study results are summarized below: (1) The average particle concentrations measured at each location, both outside and at the servers, are shown in Table 1. Measurements show low particle concentrations at all data centers without economizers, regardless of outdoor particle concentrations. Particle concentrations were typically an order of magnitude below both outside particle concentrations and recently published ASHRAE standards. (2) Economizer use caused sharp increases in particle concentrations when the economizer vents were open. The particle concentration in the data centers, however, quickly dropped back to pre-economizer levels when the vents closed. Since economizers only allow outside air part of the time, the annual average concentrations still met the ASHRAE standards. However, concentration were still above the levels measured in data centers that do not use economizers (3) Current filtration in data centers is minimal (ASHRAE 40%) since most air is typically recycled. When using economizers, modest improvements in filtration (ASHRAE 85%) can reduce particle concentrations to nearly match the level found in data centers that do not use economizers. The extra cost associated with improve filters was not determined in this study. (4) Humidity was consistent and within the ASHRAE recommended levels for all data centers without economizers. Results show that, while slightly less steady, humidity in data centers with economizers can also be controlled within the ASHRAE recommended levels. However, this control of humidity reduces energy savings by limiting the hours the economizer vents are open. (5) The potential energy savings from economizer use has been measured in one data center. When economizers were active, mechanical cooling power dropped by approximately 30%. Annual savings at this center is estimated within the range of 60-80 MWh/year, representing approximately a 5% savings off the mechanical energy load of the data center. Incoming temperatures and humidity at this data center were conservative relative to the ASHRAE acceptable temperature and humidity ranges. Greater savings may be available if higher temperature humidity levels in the data center area were permitted. The average particle concentrations measured at each of the eight data center locations are shown in Table 1. The data centers ranged in size from approximately 5,000 ft{sup 2} to 20,000 ft{sup 2}. The indoor concentrations and humidity in Table 1 represents measurements taken at the server rack. Temperature measurements at the server rack consistently fell between 65-70 F. The Findings section contains a discussion of the individual findings from each center. Data centers currently operate under very low contamination levels. Economizers can be expected to increase the particle concentration in data centers, but the increase appears to still be

  12. High Temperature, Low Relative Humidity, Polymer-type Membranes Based on Disulfonated Poly(arylene ether) Block and Random Copolymers Optionally Incorporating Protonic Conducting Layered Water insoluble Zirconium Fillers

    SciTech Connect (OSTI)

    McGrath, James E.; Baird, Donald G.

    2010-06-03

    Our research group has been engaged in the past few years in the synthesis of biphenol based partially disulfonated poly(arylene ether sulfone) random copolymers as potential PEMs. This series of polymers are named as BPSH-xx, where BP stands for biphenol, S stands for sulfonated, H stands for acidified and xx represents the degree of disulfonation. All of these sulfonated copolymers phase separate to form nano scale hydrophilic and hydrophobic morphological domains. The hydrophilic phase containing the sulfonic acid moieties causes the copolymer to absorb water. Water confined in hydrophilic pores in concert with the sulfonic acid groups serve the critical function of proton (ion) conduction and water transport in these systems. Both Nafion and BPSH show high proton conductivity at fully hydrated conditions. However proton transport is especially limited at low hydration level for the BPSH random copolymer. It has been observed that the diffusion coefficients of both water and protons change with the water content of the pore. This change in proton and water transport mechanisms with hydration level has been attributed to the solvation of the acid groups and the amount of bound and bulk-like water within a pore. At low hydration levels most of the water is tightly associated with sulfonic groups and has a low diffusion coefficient. This tends to encourage isolated domain morphology. Thus, although there may be significant concentrations of protons, the transport is limited by the discontinuous morphological structure. Hence the challenge lies in how to modify the chemistry of the polymers to obtain significant protonic conductivity at low hydration levels. This may be possible if one can alter the chemical structure to synthesize nanophase separated ion containing block copolymers. Unlike the BPSH copolymers, where the sulfonic acid groups are randomly distributed along the chain, the multiblock copolymers will feature an ordered sequence of hydrophilic and hydrophobic segments. If, like in Nafion, connectivity is established between the hydrophilic domains in these multiblock copolymers, they will not need as much water, and hence will show much better protonic conductivity than the random copolymers (with similar degree of sulfonation, or IEC) at partially hydrated conditions. The goal of this research is to develop a material suitable for use as a polymer electrolyte membrane which by the year 2010 will meet all the performance requirements associated with fuel cell operation at high temperatures and low relative humidity, and will out-perform the present standard Nafion{reg_sign}. In particular, it is our objective to extend our previous research based on the use of thermally, oxidatively, and hydrolytically, ductile, high Tg ion containing polymers based on poly(arylene ethers) to the production of polymer electrolyte membranes which will meet all the performance requirements in addition to having an areal resistance of < 0.05 ohm-cm{sup 2} at a temperature of up to 120 C, relative humidity of 25 to 50%, and up to 2.5 atm total pressure. In many instances, our materials already out performs Nafion{reg_sign}, and it is expected that with some modification by either combining with conductive inorganic fillers and/or synthesizing as a block copolymer it will meet the performance criteria at high temperatures and low relative humidity. A key component in improving the performance of the membranes (and in particular proton conductivity) and meeting the cost requirements of $40/m{sup 2} is our development of a film casting process, which shows promise for generation of void free thin films of uniform thickness with controlled polymer alignment and configuration.

  13. Measure Guideline: Supplemental Dehumidification in Warm-Humid Climates

    SciTech Connect (OSTI)

    Rudd, Armin

    2014-10-01

    This document covers a description of the need and applied solutions for supplemental dehumidification in warm-humid climates, especially for energy efficient homes where the sensible cooling load has been dramatically reduced. Cooling loads are typically high and cooling equipment runs a lot to cool the air in older homes in warm-humid climates. The cooling process also removes indoor moisture, reducing indoor relative humidity. However, at current residential code levels, and especially for above-code programs, sensible cooling loads have been so dramatically reduced that the cooling system does not run a lot to cool the air, resulting in much less moisture being removed. In these new homes, cooling equipment is off for much longer periods of time especially during spring/fall seasons, summer shoulder months, rainy periods, some summer nights, and winter days. In warm-humid climates, those long-off periods allow indoor humidity to become elevated due to internally generated moisture and ventilation air change. Elevated indoor relative humidity impacts comfort, indoor air quality, and building material durability. Industry is responding with supplemental dehumidification options, but that effort is really in its infancy regarding year-round humidity control in low-energy homes. Available supplemental humidity control options are discussed. Some options are less expensive but may not control indoor humidity as well as more expensive and comprehensive options. The best performing option is one that avoids overcooling and adding unnecessary heat to the space by using waste heat from the cooling system to reheat the cooled and dehumidified air to room-neutral temperature.

  14. Measure Guideline: Supplemental Dehumidification in Warm-Humid Climates

    SciTech Connect (OSTI)

    Rudd, A.

    2014-10-01

    This document covers a description of the need and applied solutions for supplemental dehumidification in warm-humid climates, especially for energy efficient homes where the sensible cooling load has been dramatically reduced. In older homes in warm-humid climates, cooling loads are typically high and cooling equipment runs a lot to cool the air. The cooling process also removes indoor moisture, reducing indoor relative humidity. However, at current residential code levels, and especially for above-code programs, sensible cooling loads have been so dramatically reduced that the cooling system does not run a lot to cool the air, resulting in much less moisture being removed. In these new homes, cooling equipment is off for much longer periods of time especially during spring/fall seasons, summer shoulder months, rainy periods, some summer nights, and some winter days. In warm-humid climates, those long off periods allow indoor humidity to become elevated due to internally generated moisture and ventilation air change. Elevated indoor relative humidity impacts comfort, indoor air quality, and building material durability. Industry is responding with supplemental dehumidification options, but that effort is really in its infancy regarding year-round humidity control in low-energy homes. Available supplemental humidity control options are discussed. Some options are less expensive but may not control indoor humidity as well as more expensive and comprehensive options. The best performing option is one that avoids overcooling and avoids adding unnecessary heat to the space by using waste heat from the cooling system to reheat the cooled and dehumidified air to room-neutral temperature.

  15. RH-TRU Waste Content Codes

    SciTech Connect (OSTI)

    Washington TRU Solutions

    2007-07-01

    The Remote-Handled Transuranic (RH-TRU) Content Codes (RH-TRUCON) document describes the inventory of RH-TRU waste within the transportation parameters specified by the Remote-Handled Transuranic Waste Authorized Methods for Payload Control (RH-TRAMPAC).1 The RH-TRAMPAC defines the allowable payload for the RH-TRU 72-B. This document is a catalog of RH-TRU 72-B authorized contents by site. A content code is defined by the following components: A two-letter site abbreviation that designates the physical location of the generated/stored waste (e.g., ID for Idaho National Laboratory [INL]). The site-specific letter designations for each of the sites are provided in Table 1. A three-digit code that designates the physical and chemical form of the waste (e.g., content code 317 denotes TRU Metal Waste). For RH-TRU waste to be transported in the RH-TRU 72-B, the first number of this three-digit code is 3. The second and third numbers of the three-digit code describe the physical and chemical form of the waste. Table 2 provides a brief description of each generic code. Content codes are further defined as subcodes by an alpha trailer after the three-digit code to allow segregation of wastes that differ in one or more parameter(s). For example, the alpha trailers of the subcodes ID 322A and ID 322B may be used to differentiate between waste packaging configurations. As detailed in the RH-TRAMPAC, compliance with flammable gas limits may be demonstrated through the evaluation of compliance with either a decay heat limit or flammable gas generation rate (FGGR) limit per container specified in approved content codes. As applicable, if a container meets the watt*year criteria specified by the RH-TRAMPAC, the decay heat limits based on the dose-dependent G value may be used as specified in an approved content code. If a site implements the administrative controls outlined in the RH-TRAMPAC and Appendix 2.4 of the RH-TRU Payload Appendices, the decay heat or FGGR limits based on a 10-day shipping period (rather than the standard 60-day shipping period) may be used as specified in an approved content code. Requests for new or revised content codes may be submitted to the WIPP RH-TRU Payload Engineer for review and approval, provided all RH-TRAMPAC requirements are met.

  16. Check for chirality in {sup 102}Rh

    SciTech Connect (OSTI)

    Tonev, D.; Goutev, N.; Yavahchova, M. S.; Petkov, P.; Angelis, G. de; Bhowmik, R. K.; Singh, R. P.; Muralithar, S.; Madhavan, N.; Kumar, R.; Raju, M. Kumar; Kaur, J.; Mahanto, G.; Singh, A.; Kaur, N.; Garg, R.; Sukla, A.; Marinov, Ts. K.; Brant, S.

    2012-10-20

    Excited states in {sup 102}Rh, populated by the fusion-evaporation reaction {sup 94}Zr({sup 11}B,3n){sup 102}Rh at a beam energy of 36 MeV, were studied using the INGA spectrometer at IUAC, New Delhi. The angular correlations and the electromagnetic character of some of the gamma-ray transitions observed were investigated in details. A new chiral candidate sister band was found in the level-scheme of {sup 102}Rh. Lifetimes of exited states in {sup 102}Rh were measured by means of the Doppler-shift attenuation technique. The experimental results do not support the presence of static chirality in {sup 102}Rh.

  17. Methods for providing bond activation catalysts and related catalysts, systems, and methods

    DOE Patents [OSTI]

    Goddard, III, William A.; Cheng, Mu-Jeng; Fu, Ross

    2016-04-12

    Described herein are catalysts for activation of an R--H bond in a R--H substrate and related catalytic matrices, compositions, methods and systems.

  18. Group 3: Humidity, Temperature, and Voltage (Presentation)

    SciTech Connect (OSTI)

    Wohlgemuth, J.

    2013-05-01

    Group 3 is chartered to develop accelerated stress tests that can be used as comparative predictors of module lifetime versus stresses associated with humidity, temperature and voltage.

  19. Understanding the Temperature and Humidity Environment Inside...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Environment Inside a PV Module (Presentation), NREL (National Renewable Energy Laboratory) Understanding the Temperature and Humidity Environment Inside a PV Module ...

  20. Model for the Prediction of the Hydriding Thermodynamics of Pd-Rh-Co Ternary Alloys

    SciTech Connect (OSTI)

    Teter, D.F.; Thoma, D.J.

    1999-03-01

    A dilute solution model (with respect to the substitutional alloying elements) has been developed, which accurately predicts the hydride formation and decomposition thermodynamics and the storage capacities of dilute ternary Pd-Rh-Co alloys. The effect of varying the rhodium and cobalt compositions on the thermodynamics of hydride formation and decomposition and hydrogen capacity of several palladium-rhodium-cobalt ternary alloys has been investigated using pressure-composition (PC) isotherms. Alloying in the dilute regime (<10 at.%) causes the enthalpy for hydride formation to linearly decrease with increasing alloying content. Cobalt has a stronger effect on the reduction in enthalpy than rhodium for equivalent alloying amounts. Also, cobalt reduces the hydrogen storage capacity with increasing alloying content. The plateau thermodynamics are strongly linked to the lattice parameters of the alloys. A near-linear dependence of the enthalpy of hydride formation on the lattice parameter was observed for both the binary Pd-Rh and Pd-Co alloys, as well as for the ternary Pd-Rh-Co alloys. The Pd-5Rh-3Co (at. %) alloy was found to have similar plateau thermodynamics as a Pd-10Rh alloy, however, this ternary alloy had a diminished hydrogen storage capacity relative to Pd-10Rh.

  1. Rh(I)-Catalyzed Direct Arylation of Pyridines and Quinolines

    SciTech Connect (OSTI)

    Berman, Ashley; Lewis, Jared; Bergman, Robert; Ellman, Jonathan

    2008-07-29

    The pyridine and quinoline nuclei are privileged scaffolds that occupy a central role in many medicinally relevant compounds. Consequently, methods for their expeditious functionalization are of immediate interest. However, despite the immense importance of transition-metal catalyzed cross-coupling for the functionalization of aromatic scaffolds, general solutions for coupling 2-pyridyl organometallics with aryl halides have only recently been presented. Direct arylation at the ortho position of pyridine would constitute an even more efficient approach because it eliminates the need for the stoichiometric preparation and isolation of 2-pyridyl organometallics. Progress towards this goal has been achieved by activation of the pyridine nucleus for arylation via conversion to the corresponding pyridine N-oxide or N-iminopyridinium ylide. However, this approach necessitates two additional steps: activation of the pyridine or quinoline starting material, and then unmasking the arylated product. The use of pyridines directly would clearly represent the ideal situation both in terms of cost and simplicity. We now wish to document our efforts in this vein, culminating in an operationally simple Rh(I)-catalyzed direct arylation of pyridines and quinolines. We recently developed an electron-rich Rh(I) system for catalytic alkylation at the ortho position of pyridines and quinolines with alkenes. Therefore, we initially focused our attention on the use of similarly electron-rich Rh(I) catalysts for the proposed direct arylation. After screening an array of electron-rich phosphine ligands and Rh(I) salts, only marginal yields (<20%) of the desired product were obtained. Much more efficient was an electron-poor Rh(I) system with [RhCl(CO){sub 2}]{sub 2} as precatalyst (Table 1). For the direct arylation of picoline with 3,5-dimethyl-bromobenzene, addition of P(OiPr){sub 3} afforded a promising 40% yield of the cross coupled product 1a (entry 1). The exclusion of phosphite additive proved even more effective, with the yield of 1a improving to 61% (entry 2). Further enhancement in yield was not observed upon the inclusion of other additives such as MgO (entry 3), various organic bases (entries 4, 5), or a protic acid source (entry 6). Absolute concentration proved very important, with the best results being obtained at relatively high concentrations of the aryl bromide (compare entries 7 and 8). A marginal improvement was observed upon running the reaction with 6 equivalents of 2-methyl pyridine (entry 9). The reaction temperature could also be increased to 175 or 190 C while maintaining reaction yield, to enable the reaction time to be reduced to 24 h (entries 10 and 11). In summary, we have developed a Rh(I)-catalyzed strategy for the direct arylation of pyridines and quinolines. The heterocycle is used without the need for prefunctionalization, and all reaction components are inexpensive and readily available. The strategy represents an expeditious route to an important class of bis(hetero)aryls and should be of broad utility.

  2. The Use of Humidity Sensors to Develop BIPV Packaging Solutions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Use of Humidity Sensors to Develop BIPV Packaging Solutions The Use of Humidity Sensors to Develop BIPV Packaging Solutions Presented at the PV Module Reliability Workshop, ...

  3. Building America Expert Meeting: Recommended Approaches to Humidity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Recommended Approaches to Humidity Control in High Performance Homes Building America Expert Meeting: Recommended Approaches to Humidity Control in High Performance Homes The topic ...

  4. Is It Homogeneous or Heterogeneous Catalysis Derived from [RhCp*Cl2]2? In Operando-XAFS, Kinetic and Crucial Kinetic Poisoning Evidence for Subnanometer Rh4 Cluster-Based Benzene Hydrogenation Catalysis

    SciTech Connect (OSTI)

    Bayram, Ercan; Linehan, John C.; Fulton, John L.; Roberts, John A.; Szymczak, Nathaniel; Smurthwaite, Tricia D.; Ozkar, Saim; Balasubramanian, Mahalingam; Finke, Richard G.

    2011-11-23

    Determining the true, kinetically dominant catalytically active species, in the classic benzene hydrogenation system pioneered by Maitlis and co-workers 34 years ago starting with [RhCp*Cl2]2 (Cp* = [{eta}5-C5(CH3)5]), has proven to be one of the most challenging case studies in the quest to distinguish single-metal-based 'homogeneous' from polymetallic, 'heterogeneous' catalysis. The reason, this study will show, is the previous failure to use the proper combination of (i) operando spectroscopy to determine the dominant form(s) of the precatalyst's mass under catalysis (i.e., operating) conditions, plus then and crucially also (ii) the previous lack of the necessary kinetic studies, catalysis being a 'wholly kinetic phenomenon' as J. Halpern long ago noted. An important contribution from this study will be to reveal the power of quantitiative kinetic poisoning experiments for distinguishing single-metal, or in this case subnanometer Rh4 cluster-based catalysis from larger, polymetallic Rh(0)n nanoparticle catalysis, at least under favorable conditions. The combined operando-XAFS (X-ray absorption fine structure) spectroscopy and kinetic evidences provide a compelling case for Rh4-based, with average stoichiometry 'Rh4Cp*2.4Cl4Hc', benzene hydrogenation catalysis in 2-propanol with added Et3N and at 100 C and 50 atm initial H2 pressure. The results also reveal, however, that if even ca. 1.4% of the total soluble Rh(0)n had formed nanoparticles, then those Rh(0)n nanoparticles would have been able to account for all the observed benzene hydrogenation catalytic rate (using commercial, ca. 2 nm, polyethyleneglycol-dodecylether hydrosol stabilized Rh(0)n nanoparticles as a model system). The results 'especially the poisoning methodology developed and employed' are of significant, broader interest since determining the nature of the true catalyst continues to be a central, often vexing issue in any and all catalytic reactions. The results are also of fundamental interest in that they add to a growing body of evidence indicating that certain, appropriately ligated, coordinatively unsaturated, subnanometer M4 transition-metal clusters can be relatively robust catalysts. Also demonstrated herein is that Rh4 clusters are poisoned by Hg(0), demonstrating for the first time that the classic Hg(0) poisoning test of 'homogeneous' vs 'heterogeneous'catalysts cannot distinguish Rh4-based subnanometer catalysts from Rh(0)n nanoparticle catalysts, at least for the present examples of these two specific, Rh-based catalysts.

  5. Hybridized Nature of Pseudogap in Kondo Insulators CeRhSb and CeRhAs

    SciTech Connect (OSTI)

    Kumigashira, H.; Takahashi, T.; Yoshii, S.; Kasaya, M.

    2001-08-06

    We studied the electronic structure of Kondo insulators CeRhSb and CeRhAs using high-resolution photoemission spectroscopy. We found that the 4f -derived density of states shows a depletion (pseudogap) at E{sub F} in contrast to metallic Kondo materials. It was found that the size of the f pseudogap is smaller than that of conduction electrons (c pseudogap) while both scale well with the Kondo temperature. The present results indicate that the hybridization between 4f and conduction electrons near E{sub F} is essential for the Kondo gap in the Ce-based compounds.

  6. Lanthanide-halide based humidity indicators

    DOE Patents [OSTI]

    Beitz, James V.; Williams, Clayton W.

    2008-01-01

    The present invention discloses a lanthanide-halide based humidity indicator and method of producing such indicator. The color of the present invention indicates the humidity of an atmosphere to which it is exposed. For example, impregnating an adsorbent support such as silica gel with an aqueous solution of the europium-containing reagent solution described herein, and dehydrating the support to dryness forms a substance with a yellow color. When this substance is exposed to a humid atmosphere the water vapor from the air is adsorbed into the coating on the pore surface of the silica gel. As the water content of the coating increases, the visual color of the coated silica gel changes from yellow to white. The color change is due to the water combining with the lanthanide-halide complex on the pores of the gel.

  7. Retrieval and Repackaging of RH-TRU Waste - General Presentation...

    Office of Environmental Management (EM)

    Retrieval and Repackaging of RH-TRU Waste- GENERAL PRESENTATION MODULAR HOT CELL TECHNOLOGY AREVA FEDERAL SERVICES - OAK RIDGE, TN - GENERAL PRESENTATION OF MODULAR HOT CELL ...

  8. ARM: AOS: Scanning-Mobility Particle Sizer; temperature and RH...

    Office of Scientific and Technical Information (OSTI)

    AOS: Scanning-Mobility Particle Sizer; temperature and RH output Authors: Derek Hageman ; Bill Behrens ; Janek Uin ; Robert Bullard ; Cynthia Salwen ; Cynthia Salwen ; Annette ...

  9. Chemical and Morphological Evolution of Nanoporous Pd/Rh Alloy...

    Office of Scientific and Technical Information (OSTI)

    Conference: Chemical and Morphological Evolution of Nanoporous PdRh Alloy Particles for ... Country of Publication: United States Language: English Word Cloud More Like This Full ...

  10. Group 3: Humidity, Temperature and Voltage (Presentation)

    SciTech Connect (OSTI)

    Wohlgemuth, J.

    2013-09-01

    This is a summary of the work of Group 3 of the International PV QA Task Force. Group 3 is chartered to develop accelerated stress tests that can be used as comparative predictors of module lifetime versus stresses associated with humidity, temperature and voltage.

  11. Conquering Moisture and Humidity in Your Home | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conquering Moisture and Humidity in Your Home Conquering Moisture and Humidity in Your Home September 5, 2014 - 10:54am Addthis Moisture barriers can help reduce humidity in your home. | Photo courtesy of Dennis Schroder, National Renewable Energy Laboratory Moisture barriers can help reduce humidity in your home. | Photo courtesy of Dennis Schroder, National Renewable Energy Laboratory Paige Terlip Paige Terlip Former Communicator, National Renewable Energy Laboratory What does this mean for

  12. MHK ISDB/Sensors/Relative Humidity Sensor 3445 | Open Energy...

    Open Energy Info (EERE)

    Velocity Planar Measurement (Current), 3D Velocity Volumetric Measurement (Current), Density (Ice), Direction (Ice), Speed (Ice), Thickness (Ice), Pressure (Tidal), Sea Surface...

  13. Posters A Comparison of Model-Simulated Relative Humidity with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is the treatment of cloudiness. In the real atmosphere, clouds are interactively linked to dynamical, hydrological, turbulent, and radiative processes over scales ranging...

  14. Humidity trends imply increased sensitivity to clouds in a warming Arctic

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cox, Christopher J.; Walden, Von P.; Rowe, Penny M.; Shupe, Matthew D.

    2015-12-10

    Infrared radiative processes are implicated in Arctic warming and sea-ice decline. The infrared cloud radiative effect (CRE) at the surface is modulated by cloud properties; however, CRE also depends on humidity because clouds emit at wavelengths that are semi-transparent to greenhouse gases, most notably water vapour. Here we show how temperature and humidity control CRE through competing influences between the mid- and far-infrared. At constant relative humidity, CRE does not decrease with increasing temperature/absolute humidity as expected, but rather is found to be approximately constant for temperatures characteristic of the Arctic. This stability is disrupted if relative humidity varies. Ourmore » findings explain observed seasonal and regional variability in Arctic CRE of order 10Wm 2. With the physical properties of Arctic clouds held constant, we calculate recent increases in CRE of 1–5Wm 2 in autumn and winter, which are projected to reach 5–15Wm 2 by 2050, implying increased sensitivity of the surface to clouds.« less

  15. Humidity trends imply increased sensitivity to clouds in a warming Arctic

    SciTech Connect (OSTI)

    Cox, Christopher J.; Walden, Von P.; Rowe, Penny M.; Shupe, Matthew D.

    2015-12-10

    Infrared radiative processes are implicated in Arctic warming and sea-ice decline. The infrared cloud radiative effect (CRE) at the surface is modulated by cloud properties; however, CRE also depends on humidity because clouds emit at wavelengths that are semi-transparent to greenhouse gases, most notably water vapour. Here we show how temperature and humidity control CRE through competing influences between the mid- and far-infrared. At constant relative humidity, CRE does not decrease with increasing temperature/absolute humidity as expected, but rather is found to be approximately constant for temperatures characteristic of the Arctic. This stability is disrupted if relative humidity varies. Our findings explain observed seasonal and regional variability in Arctic CRE of order 10Wm 2. With the physical properties of Arctic clouds held constant, we calculate recent increases in CRE of 1–5Wm 2 in autumn and winter, which are projected to reach 5–15Wm 2 by 2050, implying increased sensitivity of the surface to clouds.

  16. Correlating Humidity-Dependent Ionically Conductive Surface Area with Transport Phenomena in Proton-Exchange Membranes

    SciTech Connect (OSTI)

    He, Qinggang; Kusoglu, Ahmet; Lucas, Ivan T.; Clark, Kyle; Weber, Adam Z.; Kostecki, Robert

    2011-08-01

    The objective of this effort was to correlate the local surface ionic conductance of a Nafion? 212 proton-exchange membrane with its bulk and interfacial transport properties as a function of water content. Both macroscopic and microscopic proton conductivities were investigated at different relative humidity levels, using electrochemical impedance spectroscopy and current-sensing atomic force microscopy (CSAFM). We were able to identify small ion-conducting domains that grew with humidity at the surface of the membrane. Numerical analysis of the surface ionic conductance images recorded at various relative humidity levels helped determine the fractional area of ion-conducting active sites. A simple square-root relationship between the fractional conducting area and observed interfacial mass-transport resistance was established. Furthermore, the relationship between the bulk ionic conductivity and surface ionic conductance pattern of the Nafion? membrane was examined.

  17. ARM - PI Product - Radiosondes Corrected for Inaccuracy in RH...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : Radiosondes Corrected for Inaccuracy in RH Measurements Corrections for inaccuracy...

  18. Ethanol Oxidation on the Ternary PtRhSnO2/C Electrocatalysts with Varied Pt:Rh:Sn ratios

    SciTech Connect (OSTI)

    Adzic, R.R.; Li, M.; Kowal, A.; Sasaki, K.; Marinkovic, N.; Su, D.; Korach, E.; Liu, P.

    2010-05-30

    Ternary Pt-Rh-SnO{sub 2}/C electrocatalysts with the atomic ratio Pt:Rh:Sn = 3:1:x, where x varies from 2 to 6, were synthesized using the modified polyol method followed by thermal treatment. Several techniques used to characterize these electrocatalysts showed they were composed of homogeneous PtRh alloy and SnO{sub 2}, having all three constituents coexisting in single nanoparticles with the average particle size around 1.4 nm and a narrow size distribution. While all the electrocatalysts investigated exhibited high catalytic activity for ethanol oxidation, the most active one had the composition with the Pt:Rh:Sn = 3:1:4 atomic ratio. These ternary-electrocatalysts effectively split the C-C bond in ethanol at room temperature in acidic solutions, which is verified using the in situ IRRAS technique.

  19. Indoor Temperature and Humidity Data Collection and Analysis

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    use * Temperature and humidity affect comfort, health and safety, and durability ... does data get used? o Improved simulation models and inputs Current Project Scope * ...

  20. Humidity trends imply increased sensitivity to clouds in a warming...

    Office of Scientific and Technical Information (OSTI)

    is modulated by cloud properties; however, CRE also depends on humidity because clouds emit at wavelengths that are semi-transparent to greenhouse gases, most notably water vapour. ...

  1. Structural and ferromagnetic properties of an orthorhombic phase of MnBi stabilized with Rh additions

    SciTech Connect (OSTI)

    Taufour, Valentin; Thimmaiah, Srinivasa; March, Stephen; Saunders, Scott; Sun, Kewei; Lamichhane, Tej Nath; Kramer, Matthew J.; Bud’ko, Sergey L.; Canfield, Paul C.

    2015-07-28

    The article addresses the possibility of alloy elements in MnBi which may modify the thermodynamic stability of the NiAs-type structure without significantly degrading the magnetic properties. The addition of small amounts of Rh and Mn provides an improvement in the thermal stability with some degradation of the magnetic properties. The small amounts of Rh and Mn additions in MnBi stabilize an orthorhombic phase whose structural and magnetic properties are closely related to the ones of the previously reported high-temperature phase of MnBi (HT MnBi). The properties of the HT MnBi, which is stable between 613 and 719 K, have not been studied in detail because of its transformation to the stable low-temperature MnBi (LT MnBi), making measurements near and below its Curie temperature difficult. The Rh-stabilized MnBi with chemical formula Mn1.0625–xRhxBi [x=0.02(1)] adopts a new superstructure of the NiAs/Ni2In structure family. It is ferromagnetic below a Curie temperature of 416 K. The critical exponents of the ferromagnetic transition are not of the mean-field type but are closer to those associated with the Ising model in three dimensions. The magnetic anisotropy is uniaxial; the anisotropy energy is rather large, and it does not increase when raising the temperature, contrary to what happens in LT MnBi. The saturation magnetization is approximately 3μB/f.u. at low temperatures. Thus, while this exact composition may not be application ready, it does show that alloying is a viable route to modifying the stability of this class of rare-earth-free magnet alloys.

  2. Moisture performance of sealed attics in the mixed-humid climate

    SciTech Connect (OSTI)

    Boudreaux, Philip R; Pallin, Simon B; Jackson, Roderick K

    2013-12-01

    Oak Ridge National Laboratory studied 8 homes in the mixed-humid climate, 4 with vented attics and 4 with sealed attics. ORNL wanted to understand the moisture performance of the sealed attic and how it affected the interior environment. We found that the attic and interior of sealed attic homes were more humid than the attic and interior observed in vented attic homes. This is due to the lack of ventilation in the sealed attic. Historically attics have been vented to dehumidify the attic and interior of the home. A sealed attic design greatly reduces the venting potential and thus this drying pathway and can cause elevated interior moisture over a vented attic home. Despite the elevated attic and interior moisture in the sealed attic homes, so far no mold or material degradation has been found. The roof sheathing moisture content has stayed below 20%, indicating low potential for material degradation. Also the relative humidity at the roof sheathing has stayed within the ASHRAE 160 design criteria except for a short time during the 2011/2012 winter. This was due to a combination of the sealed attic design (minimal venting to the outside) and the duct work not being operated in the attic which usually provides a dehumidification pathway. It was also found that when the humidity was controlled using the HVAC system, it resulted in 7% more cooling energy consumption. In the mixed-humid climate this reduces the cost effectiveness of the sealed attic design as a solution for bringing ducts into a semi-conditioned space. Because of this we are recommending the other alternatives be used to bringing ducts into the conditioned space in both new construction and retrofit work in the mixed-humid climate.

  3. Humidity scanning quartz crystal microbalance with dissipation monitoring setup for determination of sorption-desorption isotherms and rheological changes

    SciTech Connect (OSTI)

    Bjrklund, Sebastian Kocherbitov, Vitaly

    2015-05-15

    A new method to determine water sorption-desorption isotherms with high resolution in the complete range of water activities (relative humidities) is presented. The method is based on quartz crystal microbalance with dissipation monitoring (QCM-D). The QCM-D is equipped with a humidity module in which the sample film is kept in air with controlled humidity. The experimental setup allows for continuous scanning of the relative humidity from either dry to humid conditions or vice versa. The amount of water sorbed or desorbed from the sample is determined from the resonance frequencies of the coated quartz sensor, via analysis of the overtone dependence. In addition, the method allows for characterization of hydration induced changes of the rheological properties from the dissipation data, which is closely connected to the viscoelasticity of the film. The accuracy of the humidity scanning setup is confirmed in control experiments. Sorption-desorption isotherms of pig gastric mucin and lysozyme, obtained by the new method, show good agreement with previous results. Finally, we show that the deposition technique used to coat the quartz sensor influences the QCM-D data and how this issue can be used to obtain further information on the effect of hydration. In particular, we demonstrate that spin-coating represents an attractive alternative to obtain sorption-desorption isotherms, while drop-coating provides additional information on changes of the rheological properties during hydration.

  4. Theory, electro-optical design, testing, and calibration of a prototype atmospheric supersaturation, humidity, and temperature sensor. Final report Mar 81-Jul 82

    SciTech Connect (OSTI)

    Nelson, L.D.

    1982-07-15

    A new infrared differential absorption - passive thermal emission based instrument designed to make accurate in-cloud measurements of absolute humidity, air temperature, relative humidity, and ice and water supersaturations has been developed. Absolute humidity is measured by the differential infrared absorption of a broad-band light beam between 2.45 microns wavelength and the strongly absorbing water vapor band at 2.67 microns. Air temperature is sensed by a passive radiometric measurement of the Planck's law radiance emitted by carbon dioxide molecules in their very intense emission band at 4.25 microns. Significant operational advantages over previous 14-16 micron band radiometers are achieved. These non-contact optical measurements of absolute humidity and true air temperature can then be combined to yield relative humidity values with respect to both water and ice which remain valid in condensing supersaturated conditions and in spite of hydrometeors in the sample volume.

  5. The Nature of the First Order Isostructural Transition in GdRhSn...

    Office of Scientific and Technical Information (OSTI)

    The Nature of the First Order Isostructural Transition in GdRhSn Citation Details In-Document Search Title: The Nature of the First Order Isostructural Transition in GdRhSn...

  6. BC TIPS - Hot-Humid Climate: New Orleans

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hot-Humid Climate: New Orleans Building Technologies Program The U.S. Department of Energy's Builders Challenge recognizes quality homes that also save you money. U.S. homebuilders...

  7. Tower Temperature and Humidity Sensors (TWR) Handbook (Technical Report) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Tower Temperature and Humidity Sensors (TWR) Handbook Citation Details In-Document Search Title: Tower Temperature and Humidity Sensors (TWR) Handbook Three tall towers are installed at the Atmospheric Radiation Measurement (ARM) Climate Research Facility: a 60-meter triangular tower at the Southern Great Plains (SGP) Central Facility (CF), a 21-meter walkup scaffolding tower at the SGP Okmulgee forest site (E21), and a 40-meter triangular tower at the North Slope of Alaska

  8. The Building America Indoor Temperature and Humidity Measurement Protocol

    SciTech Connect (OSTI)

    Metzger, C.; Norton, Paul

    2014-02-01

    When modeling homes using simulation tools, the heating and cooling set points can have a significant impact on home energy use. Every four years, the Energy Information Administration (EIA) Residential Energy Consumption Survey (RECS) asks homeowners about their heating and cooling set points. Unfortunately, no temperature data is measured, and most of the time, the homeowner may be guessing at this number. Even one degree Fahrenheit difference in heating set point can make a 5% difference in heating energy use! So, the survey-based RECS data cannot be used as the definitive reference for the set point for the "average occupant" in simulations. The purpose of this document is to develop a protocol for collecting consistent data for heating/cooling set points and relative humidity so that an average set point can be determined for asset energy models in residential buildings. This document covers the decision making process for researchers to determine how many sensors should be placed in each home, where to put those sensors, and what kind of asset data should be taken while they are in the home. The authors attempted to design the protocols to maximize the value of this study and minimize the resources required to achieve that value.

  9. Building America Indoor Temperature and Humidity Measurement Protocol

    SciTech Connect (OSTI)

    Engebrecht-Metzger, C.; Norton, P.

    2014-02-01

    When modeling homes using simulation tools, the heating and cooling set points can have a significant impact on home energy use. Every 4 years the Energy Information Administration (EIA) Residential Energy Consumption Survey (RECS) asks homeowners about their heating and cooling set points. Unfortunately, no temperature data is measured, and most of the time, the homeowner may be guessing at this number. Even one degree Fahrenheit difference in heating set point can make a 5% difference in heating energy use! So, the survey-based RECS data cannot be used as the definitive reference for the set point for the 'average occupant' in simulations. The purpose of this document is to develop a protocol for collecting consistent data for heating/cooling set points and relative humidity so that an average set point can be determined for asset energy models in residential buildings. This document covers the decision making process for researchers to determine how many sensors should be placed in each home, where to put those sensors, and what kind of asset data should be taken while they are in the home. The authors attempted to design the protocols to maximize the value of this study and minimize the resources required to achieve that value.

  10. Structural and ferromagnetic properties of an orthorhombic phase of MnBi stabilized with Rh additions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Taufour, Valentin; Thimmaiah, Srinivasa; March, Stephen; Saunders, Scott; Sun, Kewei; Lamichhane, Tej Nath; Kramer, Matthew J.; Bud’ko, Sergey L.; Canfield, Paul C.

    2015-07-28

    The article addresses the possibility of alloy elements in MnBi which may modify the thermodynamic stability of the NiAs-type structure without significantly degrading the magnetic properties. The addition of small amounts of Rh and Mn provides an improvement in the thermal stability with some degradation of the magnetic properties. The small amounts of Rh and Mn additions in MnBi stabilize an orthorhombic phase whose structural and magnetic properties are closely related to the ones of the previously reported high-temperature phase of MnBi (HT MnBi). The properties of the HT MnBi, which is stable between 613 and 719 K, have notmore » been studied in detail because of its transformation to the stable low-temperature MnBi (LT MnBi), making measurements near and below its Curie temperature difficult. The Rh-stabilized MnBi with chemical formula Mn1.0625–xRhxBi [x=0.02(1)] adopts a new superstructure of the NiAs/Ni2In structure family. It is ferromagnetic below a Curie temperature of 416 K. The critical exponents of the ferromagnetic transition are not of the mean-field type but are closer to those associated with the Ising model in three dimensions. The magnetic anisotropy is uniaxial; the anisotropy energy is rather large, and it does not increase when raising the temperature, contrary to what happens in LT MnBi. The saturation magnetization is approximately 3μB/f.u. at low temperatures. Thus, while this exact composition may not be application ready, it does show that alloying is a viable route to modifying the stability of this class of rare-earth-free magnet alloys.« less

  11. Humidity effects on tip-induced polarization switching in lithium niobate

    SciTech Connect (OSTI)

    Ievlev, A. V.; Morozovska, A. N.; Shur, V. Ya.; Kalinin, S. V.

    2014-03-03

    In the last several decades, ferroelectrics have attracted much attention as perspective materials for nonlinear optics and data storage devices. Scanning probe microscopy (SPM) has emerged as a powerful tool both for studies of domain structures with nanoscale spatial resolution and for writing the isolated nanodomains by local application of the electric field. Quantitative analysis of the observed behavior requires understanding the role of environmental factors on imaging and switching process. Here, we study the influence of the relative humidity in the SPM chamber on tip-induced polarization switching. The observed effects are attributed to existence of a water meniscus between the tip and the sample surface in humid atmosphere. These results are important for a deeper understanding of complex investigations of ferroelectric materials and their applications and suggest the necessity for fundamental studies of electrocapillary phenomena at the tip-surface junction and their interplay with bias-induced materials responses.

  12. Humidity effects on tip-induced polarization switching in lithium niobate

    SciTech Connect (OSTI)

    Ievlev, Anton; Morozovska, A. N.; Shur, Vladimir Ya.; Kalinin, Sergei V

    2014-01-01

    In the last several decades, ferroelectrics have attracted much attention as perspective materials for nonlinear optics and data storage devices. Scanning probe microscopy (SPM) has emerged as a powerful tool both for studies of domain structures with nanoscale spatial resolution and for writing the isolated nanodomains by local application of the electric field. Quantitative analysis of the observed behavior requires understanding the role of environmental factors on imaging and switching process. Here we study the influence of the relative humidity in the SPM chamber on tip-induced polarization switching. The observed effects are attributed to existence of a water meniscus between the tip and the sample surface in humid atmosphere. These results are important for a deeper understanding of complex investigations of ferroelectric materials and their applications, and suggest the necessity for fundamental studies of electrocapillary phenomena at the tip-surface junction and their interplay with bias-induced materials responses.

  13. Mechanisms of degradation in adhesive joint strength: Glassy polymer thermoset bond in a humid environment

    SciTech Connect (OSTI)

    Kropka, Jamie Michael; Adolf, Douglas Brian; Spangler, Scott Wilmer; Austin, Kevin N.; Chambers, Robert S.

    2015-08-06

    The degradation in the strength of napkin-ring (NR) joints bonded with an epoxy thermoset is evaluated in a humid environment. While adherend composition (stainless steel and aluminum) and surface preparation (polished, grit blasted, primed, coupling agent coated) do not affect virgin (time=0) joint strength, they can significantly affect the role of moisture on the strength of the joint. Adherend surface abrasion and corrosion processes are found to be key factors in determining the reliability of joint strength in humid environments. In cases where surface specific joint strength degradation processes are not active, decreases in joint strength can be accounted for by the glass transition temperature, Tg, depression of the adhesive associated with water sorption. Under these conditions, joint strength can be rejuvenated to virgin strength by drying. In addition, the decrease in joint strength associated with water sorption can be predicted by the Simplified Potential Energy Clock (SPEC) model by shifting the adhesive reference temperature, Tref, by the same amount as the Tg depression. When surface specific degradation mechanisms are active, they can reduce joint strength below that associated with adhesive Tg depression, and joint strength is not recoverable by drying. Furthermore, a critical relative humidity (or, potentially, critical water sorption concentration), below which the surface specific degradation does not occur, appears to exist for the polished stainless steel joints.

  14. Mechanisms of degradation in adhesive joint strength: Glassy thermoset polymer bond in a humid environment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kropka, Jamie Michael; Adolf, Douglas Brian; Spangler, Scott Wilmer; Austin, Kevin N.; Chambers, Robert S.

    2015-08-06

    The degradation in the strength of napkin-ring (NR) joints bonded with an epoxy thermoset is evaluated in a humid environment. While adherend composition (stainless steel and aluminum) and surface preparation (polished, grit blasted, primed, coupling agent coated) do not affect virgin (time=0) joint strength, they can significantly affect the role of moisture on the strength of the joint. Adherend surface abrasion and corrosion processes are found to be key factors in determining the reliability of joint strength in humid environments. In cases where surface specific joint strength degradation processes are not active, decreases in joint strength can be accounted formoreby the glass transition temperature, Tg, depression of the adhesive associated with water sorption. Under these conditions, joint strength can be rejuvenated to virgin strength by drying. In addition, the decrease in joint strength associated with water sorption can be predicted by the Simplified Potential Energy Clock (SPEC) model by shifting the adhesive reference temperature, Tref, by the same amount as the Tg depression. When surface specific degradation mechanisms are active, they can reduce joint strength below that associated with adhesive Tg depression, and joint strength is not recoverable by drying. Furthermore, a critical relative humidity (or, potentially, critical water sorption concentration), below which the surface specific degradation does not occur, appears to exist for the polished stainless steel joints.less

  15. Mechanisms of degradation in adhesive joint strength: Glassy polymer thermoset bond in a humid environment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kropka, Jamie Michael; Adolf, Douglas Brian; Spangler, Scott Wilmer; Austin, Kevin N.; Chambers, Robert S.

    2015-08-06

    The degradation in the strength of napkin-ring (NR) joints bonded with an epoxy thermoset is evaluated in a humid environment. While adherend composition (stainless steel and aluminum) and surface preparation (polished, grit blasted, primed, coupling agent coated) do not affect virgin (time=0) joint strength, they can significantly affect the role of moisture on the strength of the joint. Adherend surface abrasion and corrosion processes are found to be key factors in determining the reliability of joint strength in humid environments. In cases where surface specific joint strength degradation processes are not active, decreases in joint strength can be accounted formore » by the glass transition temperature, Tg, depression of the adhesive associated with water sorption. Under these conditions, joint strength can be rejuvenated to virgin strength by drying. In addition, the decrease in joint strength associated with water sorption can be predicted by the Simplified Potential Energy Clock (SPEC) model by shifting the adhesive reference temperature, Tref, by the same amount as the Tg depression. When surface specific degradation mechanisms are active, they can reduce joint strength below that associated with adhesive Tg depression, and joint strength is not recoverable by drying. Furthermore, a critical relative humidity (or, potentially, critical water sorption concentration), below which the surface specific degradation does not occur, appears to exist for the polished stainless steel joints.« less

  16. Electronic structure and magnetism of the Rh[l brace]001[r brace] surface

    SciTech Connect (OSTI)

    Wu, S.C. Physics Department, Peking University, Beijing 100871 ); Garrison, K. ); Begley, A.M.; Jona, F. ); Johnson, P.D. )

    1994-05-15

    Spin-polarized-photoemission experiments on clean Rh[l brace]001[r brace] show that the surface resonance at the [ital [bar M

  17. Quantitative EDS Analysis of Nanometer-Scale Core/Shell Pd/Rh...

    Office of Scientific and Technical Information (OSTI)

    of Nanometer-Scale CoreShell PdRh Structures. Authors: Sugar, Joshua Daniel ; Kotula, Paul Gabriel 1 ; Robinson, David ; Cappillino, Patrick + Show Author Affiliations (Sandia...

  18. Microwave Synthesis of Au?Rh Core?Shell Nanoparticles and Implications...

    Office of Scientific and Technical Information (OSTI)

    Microwave Synthesis of Au?Rh Core?Shell Nanoparticles and Implications of the Shell Thickness in Hydrogenation Catalysis Citation Details In-Document Search Title: Microwave ...

  19. Highly Active and Stable MgAl2O4 Supported Rh and Ir Catalysts for Methane Steam Reforming: A Combined Experimental and Theoretical Study

    SciTech Connect (OSTI)

    Mei, Donghai; Glezakou, Vassiliki Alexandra; Lebarbier, Vanessa MC; Kovarik, Libor; Wan, Haiying; Albrecht, Karl O.; Gerber, Mark A.; Rousseau, Roger J.; Dagle, Robert A.

    2014-07-01

    In this work we present a combined experimental and theoretical investigation of stable MgAl2O4 spinel-supported Rh and Ir catalysts for the steam methane reforming (SMR) reaction. Firstly, catalytic performance for a series of noble metal catalysts supported on MgAl2O4 spinel was evaluated for SMR at 600-850C. Turnover rate at 850C follows the order: Pd > Pt > Ir > Rh > Ru > Ni. However, Rh and Ir were found to have the best combination of activity and stability for methane steam reforming in the presence of simulated biomass-derived syngas. It was found that highly dispersed ~2 nm Rh and ~1 nm Ir clusters were formed on the MgAl2O4 spinel support. Scanning Transition Electron Microscopy (STEM) images show that excellent dispersion was maintained even under challenging high temperature conditions (e.g. at 850C in the presence of steam) while Ir and Rh catalysts supported on Al2O3 were observed to sinter at increased rates under the same conditions. These observations were further confirmed by ab initio molecular dynamics (AIMD) simulations which find that ~1 nm Rh and Ir particles (50-atom cluster) bind strongly to the MgAl2O4 surfaces via a redox process leading to a strong metal-support interaction, thus helping anchor the metal clusters and reduce the tendency to sinter. Density functional theory (DFT) calculations suggest that these supported smaller Rh and Ir particles have a lower work function than larger more bulk-like ones, which enables them to activate both water and methane more effectively than larger particles, yet have a minimal influence on the relative stability of coke precursors. In addition, theoretical mechanistic studies were used to probe the relationship between structure and reactivity. Consistent with the experimental observations, our theoretical modeling results also suggest that the small spinel-supported Ir particle catalyst is more active than the counterpart of Rh catalyst for SMR. This work was financially supported by the United States Department of Energy (DOE)s Bioenergy Technologies Office (BETO) and performed at the Pacific Northwest National Laboratory (PNNL). PNNL is a multi-program national laboratory operated for DOE by Battelle Memorial Institute. Computing time was granted by a user proposal at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) located at PNNL. Part of the computational time was provided by the National Energy Research Scientific Computing Center (NERSC).

  20. Ind.Audit Guide June 13_b.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - CAGI (Compressed Air & Gas Institute): - ASME 14.7 psia, 60F, 0% rh (relative humidity) 14.7 psia, 68F, 36% rh Typical dryer dew points: Refrigerated Dryers +35F to...

  1. Bimetallic Ni-Rh catalysts with low amounts of Rh for the steam and autothermal reforming of n-butane for fuel-cell applications.

    SciTech Connect (OSTI)

    Ferrandon, M.; Kropf, A. J.; Krause, T.; Chemical Sciences and Engineering Division

    2010-05-15

    Mono-metallic nickel and rhodium catalysts and bimetallic Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}, CeZrO{sub 2} and CeMgOx were prepared and evaluated for catalyzing the steam and autothermal reforming of n-butane. The binary Ni-Rh supported on La-Al{sub 2}O{sub 3} catalysts with low weight loading of rhodium exhibited higher H{sub 2} yields than Ni or Rh alone. The Ni-Rh/CeZrO{sub 2} catalyst exhibited higher performance and no coke formation, compared to the same metals on other supports. A NiAl{sub 2}O{sub 4} spinel phase was obtained on all Ni and Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}. The presence of rhodium stabilized the spinel phase as well as NiOx species upon reforming while Ni alone was mostly reduced into metallic species. Extended X-ray absorption fine-structure analysis showed evidence of Ni-Rh alloy during preparation and even further after an accelerated aging at 900C in a H{sub 2}/H{sub 2}O atmosphere.

  2. Final Design Report for the RH LLW Disposal Facility (RDF) Project

    SciTech Connect (OSTI)

    Austad, Stephanie Lee

    2015-09-01

    The RH LLW Disposal Facility (RDF) Project was designed by AREVA Federal Services (AFS) and the design process was managed by Battelle Energy Alliance (BEA) for the Department of Energy (DOE). The final design report for the RH LLW Disposal Facility Project is a compilation of the documents and deliverables included in the facility final design.

  3. Final Design Report for the RH LLW Disposal Facility (RDF) Project

    SciTech Connect (OSTI)

    Austad, S. L.

    2015-05-01

    The RH LLW Disposal Facility (RDF) Project was designed by AREVA Federal Services (AFS) and the design process was managed by Battelle Energy Alliance (BEA) for the Department of Energy (DOE). The final design report for the RH LLW Disposal Facility Project is a compilation of the documents and deliverables included in the facility final design.

  4. Energy Efficient Crawlspace Foundation Retrofit: Mixed Humid Climate

    SciTech Connect (OSTI)

    Del Bianco, M.; Wiehagen, J.

    2013-01-01

    Residential quality management systems have most often been designed for new home construction. To address quality in existing homes in the form of Scopes of Work (SOW), the NAHB Research Center began with a new construction scope of work and applied it to an existing home project. This document is intended to outline the steps of translating a new home construction SOW to SOW for retrofit and addressed crawlspace foundations in a mixed-humid climate.

  5. Performance Evaluation of a Hot-Humid Climate Community

    SciTech Connect (OSTI)

    Osser, R.; Kerrigan, P.

    2012-02-01

    Project Home Again is a development in New Orleans, LA created to provide new homes to victims of Hurricane Katrina. Building Science Corporation acted as a consultant for the project, advocating design strategies for durability, flood resistance, occupant comfort, and low energy use while maintaining cost effectiveness. These techniques include the use of high density spray foam insulation, LoE3 glazing, and supplemental dehumidification to maintain comfortable humidity levels without unnecessary cooling.

  6. Building America Case Study: Compact Buried Ducts in a Hot-Humid...

    Energy Savers [EERE]

    Compact Buried Ducts in a Hot-Humid Climate House Lady's Island, South Carolina PROJECT ... Price: 300,000 Date Completed: August 2015 Climate Zone: Hot-humid (International Energy ...

  7. Radiometer Calibration and Characterization (RCC) User's Manual...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... RH Relative humidity RLY Relay (for data logger) RS Responsivity SHD Shaded test ... SPA Solar position algorithm STD Standard (control) instrument SW Shortwave THM Thermistor ...

  8. Data Center Efficiency and IT Equipment Reliability at Wider Operating Temperature and Humidity Ranges

    Broader source: Energy.gov [DOE]

    provides an overview of how operators of data centers can increase energy efficiency at wider operating temperatures and humidity ranges

  9. Technology Solutions Case Study: Improving Comfort in Hot-Humid Climates with a Whole-House Dehumidifier

    SciTech Connect (OSTI)

    2013-11-01

    In order to quantify the performance of a combined whole-house dehumidifier (WHD) AC system, researchers from the Consortium of Advanced Residential Buildings (CARB) team monitored the operation of two Lennox AC systems coupled with a Honeywell DH150 TrueDRY whole-house dehumidifier for a six-month period. By using a WHD to control moisture levels (latent cooling) and optimizing a central AC to control temperature (sensible cooling), improvements in comfort can be achieved while reducing utility costs. Indoor comfort for this study was defined as maintaining indoor conditions at below 60% RH and a humidity ratio of 0.012 lbm/lbm while at common dry bulb set point temperatures of 74-80F. In addition to enhanced comfort, controlling moisture to these levels can reduce the risk of other potential issues such as mold growth, pests, and building component degradation. Because a standard AC must also reduce dry bulb air temperature in order to remove moisture, a WHD is typically needed to support these latent loads when sensible heat removal is not desired.

  10. Towards tailoring the magnetocaloric response in FeRh-based ternary compounds

    SciTech Connect (OSTI)

    Barua, Radhika Jiménez-Villacorta, Félix; Lewis, L. H.

    2014-05-07

    In this work, we demonstrate that the magnetocaloric response of FeRh-based compounds may be tailored for potential magnetic refrigeration applications by chemical modification of the FeRh lattice. Alloys of composition Fe(Rh{sub 1−x}A{sub x}) or (Fe{sub 1−x}B{sub x})Rh (A = Cu, Pd; B = Ni; 0 < x < 0.06) were synthesized via arc-melting and subsequent annealing in vacuum at 1000 °C for 48 h. The magnetocaloric properties of the FeRh-based systems were determined using isothermal M(H) curves measured in the vicinity of the magnetostructural temperature (T{sub t}). It is found that the FeRh working temperature range (δT{sub FWHM}) may be chemically tuned over a wide temperature range, 100 K ≤ T ≤ 400 K. While elemental substitution consistently decreases the magnetic entropy change (ΔS{sub mag}) of the FeRh-based ternary alloys from that of the parent FeRh compound (ΔS{sub mag},{sub FeRh} ∼ 17 J/kg K; ΔS{sub mag,FeRh-ternary =} 7–14 J/kg K at H{sub app} = 2 T), the net refrigeration capacity (RC), defined as the amount of heat that can be transferred during one magnetic refrigeration cycle, of the modified systems is significantly higher (RC{sub FeRh} ∼ 150 J/kg; RC{sub FeRh-ternary =} 170–210 J/kg at H{sub app} = 2 T). These results are attributed to stoichiometry-induced changes in the FeRh electronic band structure and beneficial broadening of the magnetostructural transition due to local chemical disorder.

  11. Effect of exposing two commercial manufacturers' second surface silver/glass mirrors to elevated temperature, mechanical loading, and high-humidity environments

    SciTech Connect (OSTI)

    Dake, L.S.; Lind, M.A.

    1982-04-01

    A preliminary examination of the effect of three accelerated exposure parameters on second surface silver/glass mirrors was performed. The variables studied were temperature (elevated and sub-zero), humidity and mechanical loading. One test consisted of exposing mirror coupons to dry heat (80/sup 0/C) and heat plus water vapor (80/sup 0/C, approx. 100% RH) environments. Another test consisted of subjecting mechanically loaded mirror strips to sub-zero temperature (-20/sup 0/C), dry heat (80/sup 0/C), and heat plus water vapor. Samples were evaluated qualitatively using dark field microscopy (1X and 100X). Quantitative determination of the effects of exposure testing on the mirrors was done with spectrophotometer spectral hemispherical and diffuse reflectance measurements. Degradation that was progressive with time was observed for mirrors exposed to dry heat and heat plus water vapor. The degradation did not have the same visual appearance for the two environments. Mechanical loading at -20/sup 0/C produced no degradation after three months' exposure time. Mechanical loading in dry heat and heat plus water vapor environments resulted in mirror degradation that was the same as that found in unloaded mirrors exposed to the same temperature and humidity. These preliminary tests indicate that the dry heat and heat plus water vapor accelerated tests may provide useful information about mirror degradation, while the mechanical load tests do not. The microscopy and spectrophotometer reflectance measurements were both useful techniques for determining the extent of degradation.

  12. Guides and Case Studies for Mixed-Humid Climates | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mixed-Humid Climates Guides and Case Studies for Mixed-Humid Climates Map of the Mixed-Humid Climate which reaches from the coast of Maryland through North Carolina and sprawls to cover most of Kansas and Oklahoma. The Department of Energy (DOE) has developed a series of best practices and case studies to help builders improve whole-house energy performance in buildings found in mixed-humid climates. Best Practice Guides 40% Whole-House Energy Savings in the Mixed-Humid Climates - Volume 16

  13. The effect of Fe-Rh alloying on CO hydrogenation to C2+ oxygenates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Palomino, Robert; Magee, Joseph W.; Llorca, Jordi; Senanayake, Sanjaya D.; White, Michael G.

    2015-05-20

    A combination of reactivity and structural studies using X-ray diffraction (XRD), pair distribution function (PDF), and transmission electron microscopy (TEM) was used to identify the active phases of Fe-modified Rh/TiO2 catalysts for the synthesis of ethanol and other C2+ oxygenates from CO hydrogenation. XRD and TEM confirm the existence of Fe–Rh alloys for catalyst with 1–7 wt% Fe and ~2 wt% Rh. Rietveld refinements show that FeRh alloy content increases with Fe loading up to ~4 wt%, beyond which segregation to metallic Fe becomes favored over alloy formation. Catalysts that contain Fe metal after reduction exhibit some carburization as evidencedmore »by the formation of small amounts of Fe3C during CO hydrogenation. Analysis of the total Fe content of the catalysts also suggests the presence of FeOx also increased under reaction conditions. Reactivity studies show that enhancement of ethanol selectivity with Fe loading is accompanied by a significant drop in CO conversion. Comparison of the XRD phase analyses with selectivity suggests that higher ethanol selectivity is correlated with the presence of Fe–Rh alloy phases. As a result, the interface between Fe and Rh serves to enhance the selectivity of ethanol, but suppresses the activity of the catalyst which is attributed to the blocking or modifying of Rh active sites.« less

  14. Decomposition pathways of C2 oxygenates on Rh-modified tungsten carbide surfaces

    SciTech Connect (OSTI)

    Kelly, Thomas G.; Ren, Hui; Chen, Jingguang G.

    2015-03-27

    Ethanol decomposition on tungsten monocarbide (WC) and Rh-modified WC was investigated using ultrahigh vacuum (UHV) surface science experiments and density functional theory (DFT) calculations. DFT calculations indicated that the binding energies of ethanol and its decomposition intermediates on WC(0001) were modified by Rh, with Rh/WC(0001) showing similar values to those on Rh(111). Through temperature-programmed desorption (TPD) experiments on polycrystalline WC and Rh-modified WC, it was shown that the selectivity for ethanol decomposition was different on these surfaces. On WC, the C-O bond of ethanol was preferentially broken to produce ethylene; on Rh-modified WC, the C-C bond was broken to produce carbon monoxide and methane. In addition, high-resolution electron energy loss spectroscopy (HREELS) was used to determine likely surface intermediates. On Rh-modified WC, ethanol first formed ethoxy through O-H scission, then reacted through an aldehyde intermediate to form the C1 products.

  15. The effect of Fe-Rh alloying on CO hydrogenation to C2+ oxygenates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Palomino, Robert; Magee, Joseph W.; Llorca, Jordi; Senanayake, Sanjaya D.; White, Michael G.

    2015-05-20

    A combination of reactivity and structural studies using X-ray diffraction (XRD), pair distribution function (PDF), and transmission electron microscopy (TEM) was used to identify the active phases of Fe-modified Rh/TiO2 catalysts for the synthesis of ethanol and other C2+ oxygenates from CO hydrogenation. XRD and TEM confirm the existence of Fe–Rh alloys for catalyst with 1–7 wt% Fe and ~2 wt% Rh. Rietveld refinements show that FeRh alloy content increases with Fe loading up to ~4 wt%, beyond which segregation to metallic Fe becomes favored over alloy formation. Catalysts that contain Fe metal after reduction exhibit some carburization as evidencedmore » by the formation of small amounts of Fe3C during CO hydrogenation. Analysis of the total Fe content of the catalysts also suggests the presence of FeOx also increased under reaction conditions. Reactivity studies show that enhancement of ethanol selectivity with Fe loading is accompanied by a significant drop in CO conversion. Comparison of the XRD phase analyses with selectivity suggests that higher ethanol selectivity is correlated with the presence of Fe–Rh alloy phases. As a result, the interface between Fe and Rh serves to enhance the selectivity of ethanol, but suppresses the activity of the catalyst which is attributed to the blocking or modifying of Rh active sites.« less

  16. Synthesis, characterization, and catalytic activity of Rh-based lanthanum zirconate pyrochlores for higher alcohol synthesis

    SciTech Connect (OSTI)

    Abdelsayed, Victor; Shekhawat, Dushyant; Poston, James A., Jr.; Spivey, James J.

    2013-05-01

    Two lanthanum zirconate pyrochlores (La{sub 2}Zr{sub 2}O{sub 7}; LZ) were prepared by Pechini method and tested for higher alcohols selectivity. In one, Rh was substituted into the pyrochlore lattice (LRZ, 1.7 wt%) while for the second, Rh was supported on an unsubstituted La{sub 2}Zr{sub 2}O{sub 7} (R/LZ, 1.8 wt%). X-ray photoelectron spectroscopy (XPS) and temperature programmed reduction (TPR) results show that the surface reducibility depends on whether the Rh is in (or supported on) the LZ pyrochlore. Rhodium in the LRZ is more reducible than rhodium supported on the R/LZ pyrochlore, likely due to the presence of a perovskite phase (LaRhO{sub 3}; identified by XRD), in which rhodium is more reducible. The formation of the perovskite accompanies that of the pyrochlore. CO hydrogenation results show higher ethanol selectivity for R/LZ than LRZ, possibly due to the strong interaction between Rh and LZ on the R/LZ, forming atomically close Rh{sup +}/Rh{sup 0} sites, which have been suggested to favor ethanol production.

  17. Decomposition pathways of C2 oxygenates on Rh-modified tungsten carbide surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kelly, Thomas G.; Ren, Hui; Chen, Jingguang G.

    2015-03-27

    Ethanol decomposition on tungsten monocarbide (WC) and Rh-modified WC was investigated using ultrahigh vacuum (UHV) surface science experiments and density functional theory (DFT) calculations. DFT calculations indicated that the binding energies of ethanol and its decomposition intermediates on WC(0001) were modified by Rh, with Rh/WC(0001) showing similar values to those on Rh(111). Through temperature-programmed desorption (TPD) experiments on polycrystalline WC and Rh-modified WC, it was shown that the selectivity for ethanol decomposition was different on these surfaces. On WC, the C-O bond of ethanol was preferentially broken to produce ethylene; on Rh-modified WC, the C-C bond was broken to producemore » carbon monoxide and methane. In addition, high-resolution electron energy loss spectroscopy (HREELS) was used to determine likely surface intermediates. On Rh-modified WC, ethanol first formed ethoxy through O-H scission, then reacted through an aldehyde intermediate to form the C1 products.« less

  18. The nature of the first order isostructural transition in GdRhSn (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect SciTech Connect Search Results Journal Article: The nature of the first order isostructural transition in GdRhSn Citation Details In-Document Search Title: The nature of the first order isostructural transition in GdRhSn We present structural, magnetic, thermal, magnetocaloric, and electrical transport properties of polycrystalline GdRhSn. Magnetization data show that it orders antiferromagnetically at TN = 16.2 K. The compound has the ZrNiAl type hexagonal crystal

  19. Magnitude of the magnetic exchange interaction in the heavy-fermion antiferromagnet CeRhIn?

    SciTech Connect (OSTI)

    Das, Pinaki [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Lin, S. -Z. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Ghimire, N.? J. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Huang, K. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Univ. of California, San Diego, La Jolla, CA (United States); Ronning, F. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Bauer, E.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Thompson, J.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Batista, C.? D. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Ehlers, G. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Janoschek, M. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

    2014-12-01

    We have used high-resolution neutron spectroscopy experiments to determine the complete spin wave spectrum of the heavy-fermion antiferromagnet CeRhIn?. The spin wave dispersion can be quantitatively reproduced with a simple frustrated J??J? model that also naturally explains the magnetic spin-spiral ground state of CeRhIn? and yields a dominant in-plane nearest-neighbor magnetic exchange constant J?=0.74(3)??meV. Our results pave the way to a quantitative understanding of the rich low-temperature phase diagram of the prominent CeTIn? (T = Co, Rh, Ir) class of heavy-fermion materials.

  20. Effect of residential air-to-air heat and moisture exchangers on indoor humidity

    SciTech Connect (OSTI)

    Barringer, C.G.; McGugan, C.A. )

    1989-01-01

    A project was undertaken to develop guidelines for the selection of residential heat and moisture recovery ventilation systems (HRVs) in order to maintain an acceptable indoor humidity for various climatic conditions. These guidelines were developed from reviews on ventilation requirements, HRV performance specifications, and from computer modeling. Space conditions within three house/occupancy models for several types of HRV were simulated for three climatic conditions (Lake Charles, LA; Seattle, WA; and Winnipeg, MB) in order to determine the impact of the HRVs on indoor relative humidity and space-conditioning loads. Results show that when reduction of cooling cost is the main consideration, exchangers with moisture recovery are preferable to sensible HRVs. For reduction of heating costs, moisture recovery should be done for ventilation rates greater than about 15 L/s and average winter temperatures less than about (minus) 10{degrees}C if internal moisture generation rates are low. For houses with higher ventilation rates and colder average winter temperatures, exchangers with moisture recovery should be used.

  1. W.T.; Rainey, R.H. 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS;...

    Office of Scientific and Technical Information (OSTI)

    thorium fuel reprocessing experience Brooksbank, R.E.; McDuffee, W.T.; Rainey, R.H. 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; NUCLEAR MATERIALS DIVERSION; SAFEGUARDS; SPENT FUELS;...

  2. Summary of EXAFS results on Cd-doped PuRhIn5 (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Summary of EXAFS results on Cd-doped PuRhIn5 Authors: Booth, C H ; Bauer, E D ; Tobin, J G Publication Date: 2014-06-12 OSTI Identifier: ...

  3. Electronic band structure and Kondo coupling in YbRh2Si2

    SciTech Connect (OSTI)

    Wigger, G.A.

    2010-04-15

    The electronic band structure of YbRh2Si2 is calculated in a relativistic framework including correlation corrections and magnetization of the Yb ion and compared to detailed angle-resolved photoemission spectra. The photoemission spectra for LuRh2Si2 are used as reference to identify electronic bands with no f symmetry. The calculated band structure manifests a 4f13 spin-polarized configuration leaving the unoccupied state at 1.4eV above the Fermi energy. At the band theory level, the 4f bands are located far below the Fermi level and the anisotropic Coulomb interaction within the 4f shell spreads the multilevel into broader 4f complexes below -2.5eV . The photoemission spectra obtained on YbRh2Si2 show a clear f -multilevel splitting into j=7/2 and 5/2 excitations. The interaction of the 4f7/2 levels close to the Fermi energy with two conduction bands shows visible hybridization gaps of 45 and 80meV, respectively. We discuss the origin of these excitations and provide an analysis according to Anderson's single-impurity model with parameters suggested by the band-structure calculation and the photoemission spectra. Both experiment and theory indicate nearly identical Fermi surfaces for LuRh2Si2 and YbRh2Si2 . The valency of Yb in YbRh2Si2 is estimated to be close to +3.

  4. Impact of Infiltration and Ventilation on Measured Space Conditioning Energy and Moisture Levels in the Hot-Humid Climate, Cocoa, Florida (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-04-01

    Air infiltration and ventilation in residential buildings is a very large part of the heating loads, but empirical data regarding the impact on space cooling has been lacking. Moreover, there has been little data on how building tightness might relate to building interior moisture levels in homes in a hot and humid climate. To address this need, BA-PIRC has conducted research to assess the moisture and cooling load impacts of airtightness and mechanical ventilation in two identical laboratory homes in the hot-humid climate over the cooling season. ​

  5. Technology Solutions Case Study: Impact of Infiltration and Ventilation on Measured Space Conditioning Energy and Moisture Levels in the Hot-Humid Climate

    SciTech Connect (OSTI)

    2014-04-01

    Air infiltration and ventilation in residential buildings is a very large part of the heating loads, but empirical data regarding the impact on space cooling has been lacking. Moreover, there has been little data on how building tightness might relate to building interior moisture levels in homes in a hot and humid climate. To address this need, BA-PIRC conducted research to assess the moisture and cooling load impacts of airtightness and mechanical ventilation in two identical laboratory homes in the hot-humid climate over the cooling season.

  6. Steam reforming of fast pyrolysis-derived aqueous phase oxygenates over Co, Ni, and Rh metals supported on MgAl2O4

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xing, Rong; Dagle, Vanessa Lebarbier; Flake, Matthew; Kovarik, Libor; Albrecht, Karl O.; Deshmane, Chinmay; Dagle, Robert A.

    2016-02-03

    In this paper we examine the feasibility of steam reforming the mixed oxygenate aqueous fraction derived from fast pyrolysis bio-oils. Catalysts selective towards hydrogen formation and resistant to carbon formation utilizing feeds with relatively low steam-to-carbon (S/C) ratios are desired. Rh (5 wt%), Pt (5 wt%), Ru (5 wt%), Ir (5 wt%), Ni (15 wt%), and Co (15 wt%) metals supported on MgAl2O4 were evaluated for catalytic performance at 500 °C and 1 atm using a complex feed mixture comprising acids, polyols, cycloalkanes, and phenolic compounds. The Rh catalyst was found to be the most active and resistant to carbonmore » formation. The Ni and Co catalysts were found to be more active than the other noble metal catalysts investigated (Pt, Ru, and Ir).« less

  7. Kondo lattice and antiferromagnetic behavior in quaternary CeTAl4Si2 (T = Rh, Ir) single crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maurya, Arvind; Kulkarni, Ruta; Thamizhavel, Arumugam; Paudyal, Durga; Dhar, Sudesh Kumar

    2016-02-26

    Here, we have explored in detail the anisotropic magnetic properties of CeRhAl4Si2 and CeIrAl4Si2, which undergo two antiferromagnetic transitions, at TN1 = 12.6 and 15.5 K, followed by a second transition at TN2 = 9.4 and 13.8 K, respectively, with the [001]-axis as the relatively easy axis of magnetization. The electrical resistivity at ambient and applied pressure provides evidence of Kondo interaction in both compounds, further supported by a reduced value of the entropy associated with the magnetic ordering. The Sommerfeld coefficient γ is inferred to be 195.6 and 49.4 mJ/(mol K2) for CeRhAl4Si2 and CeIrAl4Si2, respectively, classifying these materialsmore » as moderate heavy-fermion compounds. The crystal electric field energy levels are derived from the peak seen in the Schottky heat capacity. Furthermore, we have also performed electronic structure calculations by using the local spin density approximation + U [LSDA+U] approach, which provide physical insights on the observed magnetic behavior of these two compounds.« less

  8. Guides and Case Studies for Hot-Humid Climates | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hot-Humid Climates Guides and Case Studies for Hot-Humid Climates Map of the Hot and Humid Climate Zone of the United States. This zone covers eastern Texas through Florida and reaches up to mid-Georgia it also includes Puerto Rico and Hawaii. The U.S. Department of Energy (DOE) Building America program has developed a series of best practices and case studies to help builders improve whole-house energy performance in buildings found in hot-humid climates. Best Practice Guides 40% Whole-House

  9. Test Plan to Evaluate the Relationship Among IAQ, Comfort, Moisture, and Ventilation in Humid Climates

    SciTech Connect (OSTI)

    Widder, Sarah H.; Martin, Eric

    2013-03-15

    This experimental plan describes research being conducted by Pacific Northwest National Laboratory (PNNL), in coordinatation with Florida Solar Energy Center (FSEC), Florida HERO, and Lawrence Berkeley National Laboratory (LBNL) to evaluate the impact of ventilation rate on interior moisture levels, temperature distributions, and indoor air contaminant concentrations. Specifically, the research team will measure concentrations of indoor air contaminants, ventilation system flow rates, energy consumption, and temperature and relative humidity in ten homes in Gainesville, FL to characterize indoor pollutant levels and energy consumption associated with the observed ventilation rates. PNNL and FSEC have collaboratively prepared this experimental test plan, which describes background and context for the proposed study; the experimental design; specific monitoring points, including monitoring equipment, and sampling frequency; key research questions and the associated data analysis approach; experimental logistics, including schedule, milestones, and team member contact information; and clearly identifies the roles and responsibilities of each team in support of project objectives.

  10. Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts

    SciTech Connect (OSTI)

    Mei, Donghai; Lebarbier, Vanessa MC; Rousseau, Roger J.; Glezakou, Vassiliki Alexandra; Albrecht, Karl O.; Kovarik, Libor; Flake, Matthew D.; Dagle, Robert A.

    2013-06-01

    In a combined experimental and first-principles density functional theory (DFT) study, benzene steam reforming (BSR) over MgAl2O4 supported Rh and Ir catalysts was investigated. Experimentally, it has been found that both highly dispersed Rh and Ir clusters (1-2 nm) on the MgAl2O4 spinel support are stable during the BSR in the temperature range of 700-850?C. Compared to the Ir/MgAl2O4 catalyst, the Rh/MgAl2O4 catalyst is more active with higher benzene turnover frequency and conversion. At typical steam conditions with the steam-to-carbon ratio > 12, the benzene conversion is only a weak function of the H2O concentration in the feed. This suggests that the initial benzene decomposition step rather than the benzene adsorption is most likely the rate-determined step in BSR over supported Rh and Ir catalysts. In order to understand the differences between the two catalysts, we followed with a comparative DFT study of initial benzene decomposition pathways over two representative model systems for each supported metal (Rh and Ir) catalysts. A periodic terrace (111) surface and an amorphous 50-atom metal cluster with a diameter of 1.0 nm were used to represent the two supported model catalysts under low and high dispersion conditions. Our DFT results show that the decreasing catalyst particle size enhances the benzene decomposition on supported Rh catalysts by lowering both C-C and C-H bond scission. The activation barriers of the C-C and the C-H bond scission decrease from 1.60 and 1.61 eV on the Rh(111) surface to 1.34 and 1.26 eV on the Rh50 cluster. For supported Ir catalysts, the decreasing particle size only affects the C-C scission. The activation barrier of the C-C scission of benzene decreases from 1.60 eV on the Ir(111) surface to 1.35 eV on the Ir50 cluster while the barriers of the C-H scission are practically the same. The experimentally measured higher BSR activity on the supported highly dispersed Rh catalyst can be rationalized by the thermodynamic limitation for the very first C-C bond scission of benzene on the small Ir50 catalyst. The C-C bond scission of benzene on the small Ir50 catalyst is highly endothermic although the barrier is competitive with the barriers of both the C-C and the C-H bond-breakings on the small Rh50 catalyst. The calculations also imply that, for the supported Rh catalysts the C-C and C-H bond scissions are competitive, independently of the Rh cluster sizes. After the initial dissociation step via either the C-C or the C-H bond scission, the C-H bond breaking seems to be more favorable rather than the C-C bond breaking on the larger Rh terrace surface. This work was financially supported by the United States Department of Energys Office of Biomass Programs. Computing time was granted by a user project at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  11. Quality Controlled Radiosonde Profile from MC3E (Dataset) | Data Explorer

    Office of Scientific and Technical Information (OSTI)

    Quality Controlled Radiosonde Profile from MC3E Title: Quality Controlled Radiosonde Profile from MC3E The sonde-adjust VAP produces data that corrects documented biases in radiosonde humidity measurements. Unique fields contained within this datastream include smoothed original relative humidity, dry bias corrected relative humidity, and final corrected relative humidity. The smoothed RH field refines the relative humidity from integers - the resolution of the instrument - to fractions of a

  12. Understanding the Temperature and Humidity Environment Inside a PV Module (Presentation), NREL (National Renewable Energy Laboratory)

    Broader source: Energy.gov [DOE]

    This PowerPoint presentation was originally given by Michael Kempe of NREL in February 2013 detailing a project funded by the SunShot Initiative. Understanding the Temperature and Humidity Environment Inside a PV Module aims to show that by choosing humidity conditions that more closely match the use environment, one can minimize the uncertainty associated with moisture induced degradation modes.

  13. Behavior of trace and companion elements of ULC-IF steel grades during RH-treatment

    SciTech Connect (OSTI)

    Jungreithmeier, A.; Viertauer, A.; Presslinger, H.

    1996-12-31

    A large number of metallurgical reactions are caused by lowering the partial pressure during vacuum treatment. One of these reactions is the volatilization of elements with high vapor pressure. The concentration of trace and companion elements during RH-treatment mostly changes because of cooling scrap, deoxidation agents and ferro-alloy additions, slag/metal reactions, vaporization and also because of reactions with the RH-vessel lining. These changes in the concentration of trace and companion elements during RH-treatment are exemplified for ULC-IF (ultra low carbon--interstitial free) steel grades. The elements which are considered are chromium, nickel, molybdenum, copper, vanadium, tin, zinc, lead, phosphorus, sulfur and nitrogen. Calculations of the theoretical equilibrium solubility using thermodynamic data--in dependence of pressure and temperature--correspond well with the values obtained during steel production operations. 67 refs.

  14. Origin of the smaller conductances of Rh, Pb, and Co atomic junctions in hydrogen environment

    SciTech Connect (OSTI)

    Li, Xue; Chen, Mingyan; Ye, Xiang; Xie, Yi-qun; Ke, San-huang

    2015-02-14

    We study theoretically the structural and electronic origins of the smaller conductances (one conductance quantum, G{sub 0}, and smaller) of Rh, Pb, and Co metal atomic junctions (MAJs) in a hydrogen environment, as were measured in recent experiments. For the Rh MAJs, the 1G{sub 0} conductance is attributed to a stable contact bridged by a single hydrogen molecule whose antibonding state provides a single transport channel. For the Pb and Co MAJs the 1G{sub 0} conductance is, however, ascribed to a linear atomic chain adsorbing two dissociated H atoms, which largely reduces the density of states at the Fermi energy with respect to the pure ones. On the other hand, the small conductances of 0.3G{sub 0} (Rh) and 0.2G{sub 0} (Co) are due to H-decorated atomic chains connected to electrodes by a H atom.

  15. Electronic Band Structure And Kondo Coupling in YbRh(2)Si(2)

    SciTech Connect (OSTI)

    Wigger, G.A.; Baumberger, F.; Shen, Z.X.; Yin, Z.P.; Pickett, W.E.; Maquilon, S.; Fisk, Z.; /UC, Davis

    2007-09-26

    The electronic band structure of YbRh{sub 2}Si{sub 2} is calculated in a relativistic framework including correlation corrections and magnetization of the Yb ion and compared to detailed angle-resolved photoemission spectra. The photoemission spectra for LuRh{sub 2}Si{sub 2} are used as reference to identify electronic bands with no f symmetry. The calculated band structure manifests a 4f{sup 13} spin-polarized configuration leaving the unoccupied state at 1.4 eV above the Fermi energy. At the band theory level, the 4f bands are located far below the Fermi level and the anisotropic Coulomb interaction within the 4f shell spreads the multilevel into broader 4f complexes below -2.5 eV. The photoemission spectra obtained on YbRh2Si2 show a clear f-multilevel splitting into j=7/2 and 5/2 excitations. The interaction of the 4f{sub 7/2} levels close to the Fermi energy with two conduction bands shows visible hybridization gaps of 45 and 80 meV, respectively. We discuss the origin of these excitations and provide an analysis according to Anderson's single-impurity model with parameters suggested by the band-structure calculation and the photoemission spectra. Both experiment and theory indicate nearly identical Fermi surfaces for LuRh{sub 2}Si{sub 2} and YbRh{sub 2}Si{sub 2}. The valency of Yb in YbRh{sub 2}Si{sub 2} is estimated to be close to +3.

  16. Corrosion problems in Ti/KC1O/sub 4/ loaded devices when subjected to humid environments

    SciTech Connect (OSTI)

    Massis, T.M.; Healey, J.T.; Huskisson, D.H.; Perkins, W.G.

    1980-01-01

    A piston motor/igniter loaded with a Ti/KClO/sub 4/ pyrotechnic and sealed with a silicone adhesive exhibited serious corrosion problems during aging. Five 24-hour thermal cycles between room temperature and 71/sup 0/C at 90% relative humidity resulted in extensive surface corrosion of the Kovar pins and severe stress corrosion cracking of the Kovar pins in the vicinity of the bridgewire weld. No corrosion or cracking of the Nichrome bridgewire was observed. Similar results were observed after 60 days at 50% and 90% relative humidity at room temperature. Tests at ambient relative humidity and room temperature caused limited surface corrosion and no observable cracking. It was determined that these problems resulted from the combined presence of chlorine containing contaminants and atmospheric moisture. Chlorine was detected in both the surface corrosion product and the corrosion product in the subsurface cracks. The absence of reaction and/or morphological alteration of the Ti/KClO/sub 4/ at the pyrotechnic interface with the Kovar indicated the pyrotechnic was not involved in the corrosion reaction, and, hence, the chlorine was present in the surface contamination on the Kovar pins. The aging tests indicate that external moisture was involved in the corrosion reaction. Calculation and experimentation have shown the silicone adhesive used to seal these devices to be permeable to water vapor, and the moisture conditions inside the devices equilibrated with external conditions within a few hours. Corrosion and cracking could be solved by eliminating the source of moisture by hermetically sealing the devices. Tests of hermetically sealed units have confirmed this conclusion.

  17. Rh-Based Mixed Alcohol Synthesis Catalysts: Characterization and Computational Report

    SciTech Connect (OSTI)

    Albrecht, Karl O.; Glezakou, Vassiliki Alexandra; Rousseau, Roger J.; Engelhard, Mark H.; Varga, Tamas; Colby, Robert J.; Jaffe, John E.; Li, Xiaohong S.; Mei, Donghai; Windisch, Charles F.; Kathmann, Shawn M.; Lemmon, Teresa L.; Gray, Michel J.; Hart, Todd R.; Thompson, Becky L.; Gerber, Mark A.

    2013-08-01

    The U.S. Department of Energy is conducting a program focused on developing a process for the conversion of biomass to bio-based fuels and co-products. Biomass-derived syngas is converted thermochemically within a temperature range of 240 to 330C and at elevated pressure (e.g., 1200 psig) over a catalyst. Ethanol is the desired reaction product, although other side compounds are produced, including C3 to C5 alcohols; higher (i.e., greater than C1) oxygenates such as methyl acetate, ethyl acetate, acetic acid and acetaldehyde; and higher hydrocarbon gases such as methane, ethane/ethene, propane/propene, etc. Saturated hydrocarbon gases (especially methane) are undesirable because they represent a diminished yield of carbon to the desired ethanol product and represent compounds that must be steam reformed at high energy cost to reproduce CO and H2. Ethanol produced by the thermochemical reaction of syngas could be separated and blended directly with gasoline to produce a liquid transportation fuel. Additionally, higher oxygenates and unsaturated hydrocarbon side products such as olefins also could be further processed to liquid fuels. The goal of the current project is the development of a Rh-based catalyst with high activity and selectivity to C2+ oxygenates. This report chronicles an effort to characterize numerous supports and catalysts to identify particular traits that could be correlated with the most active and/or selective catalysts. Carbon and silica supports and catalysts were analyzed. Generally, analyses provided guidance in the selection of acceptable catalyst supports. For example, supports with high surface areas due to a high number of micropores were generally found to be poor at producing oxygenates, possibly because of mass transfer limitations of the products formed out of the micropores. To probe fundamental aspects of the complicated reaction network of CO with H2, a computational/ theoretical investigation using quantum mechanical and ab initio molecular dynamics calculations was initiated in 2009. Computational investigations were performed first to elucidate understanding of the nature of the catalytically active site. Thermodynamic calculations revealed that Mn likely exists as a metallic alloy with Rh in Rh-rich environments under reducing conditions at the temperatures of interest. After determining that reduced Rh-Mn alloy metal clusters were in a reduced state, the activation energy barriers of numerous transition state species on the catalytically active metal particles were calculated to compute the activation barriers of several reaction pathways that are possible on the catalyst surface. Comparison of calculations with a Rh nanoparticle versus a Rh-Mn nanoparticle revealed that the presence of Mn enabled the reaction pathway of CH with CO to form an adsorbed CHCO species, which was a precursor to C2+ oxygenates. The presence of Mn did not have a significant effect on the rate of CH4 production. Ir was observed during empirical catalyst screening experiments to improve the activity and selectivity of Rh-Mn catalysts. Thus, the addition of Ir to the Rh-Mn nanoparticles also was probed computationally. Simulations of Rh-Mn-Ir nanoparticles revealed that, with sufficient Ir concentrations, the Rh, Mn and Ir presumably would be well mixed within a nanoparticle. Activation barriers were calculated for Rh-Mn-Ir nanoparticles for several C-, H-, and O-containing transitional species on the nanoparticle surface. It was found that the presence of Ir opened yet another reactive pathway whereby HCO is formed and may undergo insertion with CHx surface moieties. The reaction pathway opened by the presence of Ir is in addition to the CO + CH pathway opened by the presence of Mn. Similar to Mn, the presence of Ir was not found to not affect the rate of CH4 production.

  18. CVEN 6960 master's project, investigation of a cooling coil in high humidity conditions. Master's thesis

    SciTech Connect (OSTI)

    Sloop, R.E.

    1993-12-10

    The primary purpose of this project is to validate the HVAC*2 Toolkit calculations for a cooling coil in high humidity conditions. A total of 19 experimental runs at different entering air temperature and humidity conditions were performed at the Joint Center for Energy Management HVAC Laboratory that exposed a cooling coil to temperature and humidity conditions that are typically found in the southern United States. The inlet conditions and manufacturer's coil rating data was used as input to the HVAC*2 Toolkit simple cooling coil subroutine (CCSIM). The predicted results from the toolkit were then compared to the experimental results.

  19. Impact of Materials Processing on Microstructural Evolution and Hydrogen Isotope Storage Properties of Pd-Rh Alloy Powders.

    SciTech Connect (OSTI)

    Yee, Joshua K

    2015-02-01

    Cryomilled Pd - 10Rh was investiga ted as potential solid - state storage material of hydrogen. Pd - 10Rh was first atomized, and then subsequently cryomilled. The cryomilled Pd - 10Rh was then examined using microstructural characterization techniques including op tical microscopy, electron microscopy, and X - ray diffraction. Pd - 10Rh particles were significantly flattened, increasing the apparent surface area. Microstructural refinement was observed in the cryomilled Pd - 10Rh, generating grains at the nanom etric scale through dislocation - based activity. Hydrogen sorption properties were also characterized, generating both capacity as well as kinetics measurements. It was found that the microstructural refinement due to cryomilling did not play a significant role on hyd rogen sorption properties until the smallest grain size (on the order of %7E25 nm) was achieved. Additionally, the increased surface area and other changes in particle morphology were associated with cryomilling changed the kinetics of hydrogen absorption.

  20. Thermodynamics and superconductivity of Th7(Fe, Ru, Os, Co, Rh, Ir)3 system

    SciTech Connect (OSTI)

    Smith, James L; Lashley, Jason C; Volz, Heather M; Fisher, Robert A

    2008-01-01

    Expanding the temperature range of previous specific-heat measurements on the Th7(Fe, Ru, Os, Co, Rh, Ir)3 system, we measure the effect of transition-metal substitution on total entropy (S{sub 298 k}), electronic specific heat ({gamma}), and Debye temperature ({Theta}D). In addition we measure the pressure dependence, up to 10 kbar, of the superconducting transition.

  1. Stable room-temperature ferromagnetic phase at the FeRh(100) surface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pressacco, Federico; Uhlir, Vojtech; Gatti, Matteo; Bendounan, Azzedine; Fullerton, Eric E.; Sirotti, Fausto

    2016-03-03

    Interfaces and low dimensionality are sources of strong modifications of electronic, structural, and magnetic properties of materials. FeRh alloys are an excellent example because of the first-order phase transition taking place at ~400 K from an antiferromagnetic phase at room temperature to a high temperature ferromagnetic one. It is accompanied by a resistance change and volume expansion of about 1%. We have investigated the electronic and magnetic properties of FeRh(100) epitaxially grown on MgO by combining spectroscopies characterized by different probing depths, namely X-ray magnetic circular dichroism and photoelectron spectroscopy. Furthermore, we find that the symmetry breaking induced at themore » Rh-terminated surface stabilizes a surface ferromagnetic layer involving five planes of Fe and Rh atoms in the nominally antiferromagnetic phase at room temperature. First-principles calculations provide a microscopic description of the structural relaxation and the electron spin-density distribution that support the experimental findings.« less

  2. Antiferromagnetic ordering in the doped Kondo insulator CeRhSb

    SciTech Connect (OSTI)

    Menon, L.; Malik, S.K.

    1997-06-01

    CeRhSb, the so-called {open_quotes}Kondo insulator,{close_quotes} is a mixed-valent compound showing a gap formation in the electronic density of states. On the other hand, CePdSb is ferromagnetically ordered with a Curie temperature of {approximately}17 K. We have carried out magnetic susceptibility and electrical resistivity measurements on CeRh{sub 1{minus}x}Pd{sub x}Sb (0{le}x{le}1.0), to study the ground-state properties of this system. For small Pd doping in CeRhSb, up to 20{percent}, the gap continually diminishes and no magnetic ordering is observed down to 2 K. In the region 0.3{le}x{le}0.4, as soon as the gap is suppressed, an antiferromagnetic ground state is observed. In the region 0.5{le}x{lt}0.7, the compounds are not single phase. At the CePdSb end, in the region 0.7{le}x{le}1, the ground state is ferromagnetic. The observation of an antiferromagnetic phase in the phase diagram of CeRh{sub 1{minus}x}Pd{sub x}Sb, where neither end is antiferromagnetic, is interesting and is discussed in the light of some recent theoretical models. {copyright} {ital 1997} {ital The American Physical Society}

  3. Waste Isolation Pilot Plant simulated RH TRU waste experiments: Data and interpretation pilot

    SciTech Connect (OSTI)

    Molecke, M.A.; Argueello, G.J.; Beraun, R.

    1993-04-01

    The simulated, i.e., nonradioactive remote-handled transuranic waste (RH TRU) experiments being conducted underground in the Waste Isolation Pilot Plant (WIPP) were emplaced in mid-1986 and have been in heated test operation since 9/23/86. These experiments involve the in situ, waste package performance testing of eight full-size, reference RH TRU containers emplaced in horizontal, unlined test holes in the rock salt ribs (walls) of WIPP Room T. All of the test containers have internal electrical heaters; four of the test emplacements were filled with bentonite and silica sand backfill materials. We designed test conditions to be ``near-reference`` with respect to anticipated thermal outputs of RH TRU canisters and their geometrical spacing or layout in WIPP repository rooms, with RH TRU waste reference conditions current as of the start date of this test program. We also conducted some thermal overtest evaluations. This paper provides a: detailed test overview; comprehensive data update for the first 5 years of test operations; summary of experiment observations; initial data interpretations; and, several status; experimental objectives -- how these tests support WIPP TRU waste acceptance, performance assessment studies, underground operations, and the overall WIPP mission; and, in situ performance evaluations of RH TRU waste package materials plus design details and options. We provide instrument data and results for in situ waste container and borehole temperatures, pressures exerted on test containers through the backfill materials, and vertical and horizontal borehole-closure measurements and rates. The effects of heat on borehole closure, fracturing, and near-field materials (metals, backfills, rock salt, and intruding brine) interactions were closely monitored and are summarized, as are assorted test observations. Predictive 3-dimensional thermal and structural modeling studies of borehole and room closures and temperature fields were also performed.

  4. High Temperature/Low Humidity Polymer Electrolytes Derived from Ionic Liquids

    Broader source: Energy.gov [DOE]

    Presentation on High Temperature/Low Humidity Polymer Electrolytes Derived from Ionic Liquids to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

  5. Study on the Humidity Susceptibility of Thin-Film CIGS Absorber

    SciTech Connect (OSTI)

    Pern, F. J.; Egaas, B.; To, B.; Jiang, C. S.; Li, J. V.; Glynn, S.; DeHart, C.

    2010-01-01

    The report summarizes the research on the susceptibility of a thermally co-evaporated CuInGaSe2 (CIGS) thin-film absorber to humidity and its consequence on composition, morphology, electrical and electronic properties, and device efficiency.

  6. Mechanisms of Oriented Attachment of TiO2 Nanocrystals in Vacuum and Humid

    Office of Scientific and Technical Information (OSTI)

    Environments: Reactive Molecular Dynamics (Journal Article) | SciTech Connect Journal Article: Mechanisms of Oriented Attachment of TiO2 Nanocrystals in Vacuum and Humid Environments: Reactive Molecular Dynamics Citation Details In-Document Search Title: Mechanisms of Oriented Attachment of TiO2 Nanocrystals in Vacuum and Humid Environments: Reactive Molecular Dynamics Authors: Raju, Muralikrishna [1] ; Van Duin, Adri C. T. [2] ; Fichthorn, Kristen [1] + Show Author Affiliations Pennsylvania

  7. Expert Meeting: Recommended Approaches to Humidity Control in High Performance Homes

    SciTech Connect (OSTI)

    Rudd, A.

    2013-07-01

    The topic of this Building America expert meeting was 'Recommended Approaches to Humidity Control in High Performance Homes,' which was held on October 16, 2012, in Westford, MA, and brought together experts in the field of residential humidity control to address modeling issues for dehumidification. The presentations and discussions centered on computer simulation and field experience with these systems, with the goal of developing foundational information to support the development of a Building America Measure Guideline on this topic.

  8. Building America Expert Meeting: Recommended Approaches to Humidity Control in High Performance Homes

    Broader source: Energy.gov [DOE]

    The topic of this Building America expert meeting was Recommended Approaches to Humidity Control in High Performance Homes,Ž which was held on October 16, 2012, in Westford, MA, and brought together experts in the field of residential humidity control to address modeling issues for dehumidification. The presentations and discussions centered on computer simulation and field experience with these systems, with the goal of developing foundational information to support the development of a Building America Measure Guideline on this topic.

  9. 15.10.5 RH ECS Atwater - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    JCAP's Harry Atwater on Critical Energy Issues (ECS Podcast) JCAP Director Harry Atwater in conversation with the Electrochemical Society's Executive Director Roque Calvo on the eve of the fifth international ECS Electrochemical Energy Summit. Related Link: ECS Blog (http://www.ecsblog.org/harry-atwater-on-critical-energy-issues/)

  10. The effect of Fe-Rh alloying on CO hydrogenation to C2+ oxygenates

    SciTech Connect (OSTI)

    Palomino, Robert; Magee, Joseph W.; Llorca, Jordi; Senanayake, Sanjaya D.; White, Michael G.

    2015-05-20

    A combination of reactivity and structural studies using X-ray diffraction (XRD), pair distribution function (PDF), and transmission electron microscopy (TEM) was used to identify the active phases of Fe-modified Rh/TiO2 catalysts for the synthesis of ethanol and other C2+ oxygenates from CO hydrogenation. XRD and TEM confirm the existence of Fe–Rh alloys for catalyst with 1–7 wt% Fe and ~2 wt% Rh. Rietveld refinements show that FeRh alloy content increases with Fe loading up to ~4 wt%, beyond which segregation to metallic Fe becomes favored over alloy formation. Catalysts that contain Fe metal after reduction exhibit some carburization as evidenced by the formation of small amounts of Fe3C during CO hydrogenation. Analysis of the total Fe content of the catalysts also suggests the presence of FeOx also increased under reaction conditions. Reactivity studies show that enhancement of ethanol selectivity with Fe loading is accompanied by a significant drop in CO conversion. Comparison of the XRD phase analyses with selectivity suggests that higher ethanol selectivity is correlated with the presence of Fe–Rh alloy phases. As a result, the interface between Fe and Rh serves to enhance the selectivity of ethanol, but suppresses the activity of the catalyst which is attributed to the blocking or modifying of Rh active sites.

  11. Humidity-resistant ambient-temperature solid-electrolyte amperometric sensing apparatus

    DOE Patents [OSTI]

    Zaromb, Solomon

    1994-01-01

    Apparatus and methods for detecting selected chemical compounds in air or other gas streams at room or ambient temperature includes a liquid-free humidity-resistant amperometric sensor comprising a sensing electrode and a counter and reference electrode separated by a solid electrolyte. The sensing electrode preferably contains a noble metal, such as Pt black. The electrolyte is water-free, non-hygroscopic, and substantially water-insoluble, and has a room temperature ionic conductivity .gtoreq.10.sup.-4 (ohm-cm).sup.-1, and preferably .gtoreq.0.01 (ohm-cm).sup.-1. The conductivity may be due predominantly to Ag+ ions, as in Ag.sub.2 WO.sub.4.4AgI, or to F- ions, as in Ce.sub.0.95 Ca.sub.0.05 F.sub.2.95. Electrical contacts serve to connect the electrodes to potentiostating and detecting circuitry which controls the potential of the sensing electrode relative to the reference electrode, detects the signal generated by the sensor, and indicates the detected signal.

  12. Humidity-resistant ambient-temperature solid-electrolyte amperometric sensing apparatus and methods

    DOE Patents [OSTI]

    Zaromb, Solomon

    2001-01-01

    Apparatus and methods for detecting selected chemical compounds in air or other gas streams at room or ambient temperature includes a liquid-free humidity-resistant amperometric sensor comprising a sensing electrode and a counter and reference electrode separated by a solid electrolyte. The sensing electrode preferably contains a noble metal, such as Pt black. The electrolyte is water-free, non-hygroscopic, and substantially water-insoluble, and has a room temperature ionic conductivity .gtoreq.10.sup.-4 (ohm-cm).sup.-1, and preferably .gtoreq.0.01 (ohm-cm).sup.-1. The conductivity may be due predominantly to Ag+ ions, as in Ag.sub.2 WO.sub.4.4AgI, or to F- ions, as in Ce.sub.0.95 Ca.sub.0.05 F.sub.2.95. Electrical contacts serve to connect the electrodes to potentiostating and detecting circuitry which controls the potential of the sensing electrode relative to the reference electrode, detects the signal generated by the sensor, and indicates the detected signal.

  13. Synthesis of few-walled carbon nanotube-Rh nanoparticles by arc discharge: Effect of selective oxidation

    SciTech Connect (OSTI)

    Zhang Yanfeng

    2012-06-15

    Highly crystalline rhodium (Rh) nanoparticles supported on carbon nanotubes were prepared by selective oxidation method. Carbon nanotubes and FeRh nanoparticles were simultaneously generated in hydrogen arc plasma. The as-grown nanomaterials can be purified by heat treatment in open air and by soaking in HCl. X-ray diffraction and selected area electron diffraction results reveal that as-grown FeRh nanoparticles have a typical chemical CsCl-type structure which can be transformed into a face-centered cubic structure by thermal annealing in the purification process. The purification process is selective toward the removal of the amorphous carbon coating the nanoparticles, and transforms Fe to Fe{sub 2}O{sub 3}. Fe{sub 2}O{sub 3} can be easily dissolved in hydrochloric acid, leaving carbon nanotubes-Rh nanoparticles. Rh nanoparticles with diameters of 2-60 nm are deposited uniformly on the surface of the carbon nanotube bundles. This simple and selective chemistry offers a new process for synthesizing and controlling Fe content in carbon nanotube-FeRh nanoparticles. Highlights: Black-Right-Pointing-Pointer High-crystallinity CNTs and FeRh nanoparticles were simultaneously generated in arc plasma. Black-Right-Pointing-Pointer The diameter distribution of CNTs depends on different gases. Black-Right-Pointing-Pointer Heat treatment in open air and soaking in HCl can convert CNTs-FeRh to CNTs-Rh. Black-Right-Pointing-Pointer The selective oxidation mechanisms of metal nanoparticles and carbon materials differ.

  14. Effects of Humidity During Formation of Zinc Oxide Electron Contact...

    Office of Scientific and Technical Information (OSTI)

    Additional Journal Information: Journal Volume: 31; Related Information: Organic Electronics; Journal ID: ISSN 1566-1199 Publisher: Elsevier Research Org: NREL (National Renewable ...

  15. Magnitude of the magnetic exchange interaction in the heavy-fermion antiferromagnet CeRhIn5

    SciTech Connect (OSTI)

    Das, Pinaki; Lin, S. -Z.; Ghimire, N. J.; Huang, K.; Ronning, F.; Bauer, E. D.; Thompson, J. D.; Batista, C. D.; Ehlers, G.; Janoschek, M.

    2014-12-08

    We have used high-resolution neutron spectroscopy experiments to determine the complete spin wave spectrum of the heavy-fermion antiferromagnet CeRhIn?. The spin wave dispersion can be quantitatively reproduced with a simple frustrated J?-J? model that also naturally explains the magnetic spin-spiral ground state of CeRhIn? and yields a dominant in-plane nearest-neighbor magnetic exchange constant J?=0.74(3) meV. Our results lead the way to a quantitative understanding of the rich low-temperature phase diagram of the prominent CeTIn? (T = Co, Rh, Ir) class of heavy-fermion materials.

  16. Magnitude of the magnetic exchange interaction in the heavy-fermion antiferromagnet CeRhIn5

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Das, Pinaki; Lin, S. -Z.; Ghimire, N. J.; Huang, K.; Ronning, F.; Bauer, E. D.; Thompson, J. D.; Batista, C. D.; Ehlers, G.; Janoschek, M.

    2014-12-08

    We have used high-resolution neutron spectroscopy experiments to determine the complete spin wave spectrum of the heavy-fermion antiferromagnet CeRhIn₅. The spin wave dispersion can be quantitatively reproduced with a simple frustrated J₁-J₂ model that also naturally explains the magnetic spin-spiral ground state of CeRhIn₅ and yields a dominant in-plane nearest-neighbor magnetic exchange constant J₀=0.74(3) meV. Our results lead the way to a quantitative understanding of the rich low-temperature phase diagram of the prominent CeTIn₅ (T = Co, Rh, Ir) class of heavy-fermion materials.

  17. Magnetism and superconductivity in U2PtxRh1?xC2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-09

    We report the phase diagram of the doping series U?PtxRh(1x)C?, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Nel temperature of U?Rh?C? of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. Additionally, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ? 0.9, with Tc increasing with increasing x. Themorereduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.less

  18. Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C-H Bond Activation

    SciTech Connect (OSTI)

    Lewis, Jared; Bergman, Robert; Ellman, Jonathan

    2008-02-04

    Nitrogen heterocycles are present in many compounds of enormous practical importance, ranging from pharmaceutical agents and biological probes to electroactive materials. Direct funtionalization of nitrogen heterocycles through C-H bond activation constitutes a powerful means of regioselectively introducing a variety of substituents with diverse functional groups onto the heterocycle scaffold. Working together, our two groups have developed a family of Rh-catalyzed heterocycle alkylation and arylation reactions that are notable for their high level of functional-group compatibility. This Account describes their work in this area, emphasizing the relevant mechanistic insights that enabled synthetic advances and distinguished the resulting transformations from other methods. They initially discovered an intramolecular Rh-catalyzed C-2-alkylation of azoles by alkenyl groups. That reaction provided access to a number of di-, tri-, and tetracyclic azole derivatives. They then developed conditions that exploited microwave heating to expedite these reactions. While investigating the mechanism of this transformation, they discovered that a novel substrate-derived Rh-N-heterocyclic carbene (NHC) complex was involved as an intermediate. They then synthesized analogous Rh-NHC complexes directly by treating precursors to the intermediate [RhCl(PCy{sub 3}){sub 2}] with N-methylbenzimidazole, 3-methyl-3,4-dihydroquinazolein, and 1-methyl-1,4-benzodiazepine-2-one. Extensive kinetic analysis and DFT calculations supported a mechanism for carbene formation in which the catalytically active RhCl(PCy{sub 3}){sub 2} fragment coordinates to the heterocycle before intramolecular activation of the C-H bond occurs. The resulting Rh-H intermediate ultimately tautomerizes to the observed carbene complex. With this mechanistic information and the discovery that acid co-catalysts accelerate the alkylation, they developed conditions that efficiently and intermolecularly alkylate a variety of heterocycles, including azoles, azolines, dihydroquinazolines, pyridines, and quinolines, with a wide range of functionalized olefins. They demonstrated the utility of this methodology in the synthesis of natural products, drug candidates, and other biologically active molecules. In addition, they developed conditions to directly arylate these heterocycles with aryl halides. The initial conditions that used PCy{sub 3} as a ligand were successful only for aryl iodides. However, efforts designed to avoid catalyst decomposition led to the development of ligands based on 9-phosphabicyclo[4.2.1]nonane (Phoban) that also facilitated the coupling of aryl bromides. They then replicated the unique coordination environment, stability, and catalytic activity of this complex using the much simpler tetrahydrophosphepine ligands and developed conditions that coupled aryl bromides bearing diverse functional groups without the use of a glovebox or purified reagents. With further mechanistic inquiry, they anticipate that researchers will better understand the details of the aforementioned Rh-catalyzed C-H bond functionalization reactions, resulting in the design of more efficient and robust catalysts, expanded substrate scope, and new transformations.

  19. Magnetism and superconductivity in U?PtxRh(1x)C?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-01

    We report the phase diagram of the doping series U?PtxRh(1x)C?, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Nel temperature of U?Rh?C? of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. In addition, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ? 0.9, with Tc increasing with increasing x.moreThe reduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.less

  20. Syntheses and characterization of the cubic uranium chalcogenides Rh2U6S15,

    Office of Scientific and Technical Information (OSTI)

    Cs2Ti2U6Se15, Cs2Cr2U6Se15, and Cs2Ti2U6Te15 (Journal Article) | DOE PAGES DOE PAGES Search Results Publisher's Accepted Manuscript: Syntheses and characterization of the cubic uranium chalcogenides Rh2U6S15, Cs2Ti2U6Se15, Cs2Cr2U6Se15, and Cs2Ti2U6Te15 This content will become publicly available on July 11, 2017 « Prev Next » Title: Syntheses and characterization of the cubic uranium chalcogenides Rh2U6S15, Cs2Ti2U6Se15, Cs2Cr2U6Se15, and Cs2Ti2U6Te15 Authors: Ward, Matthew D. ; Oh,

  1. Electronic structure of U2PtC2 and U2RhC2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ronning, F.; Zhu, J. -X.

    2015-03-18

    In this study, we present density functional theory calculations within the generalized gradient approximation of U2RhC2 and U2PtC2. We find the calculated density of states are significantly less than that measured by specific heat indicating the need for electronic correlations. The mass enhancement found for U2PtC2 is m*/mband ≈ 4.

  2. Moisture and Ventilation Solutions in Hot, Humid Climates: Florida...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    team to diagnose the cause of moisture problems in manufactured housing in Florida and ... One manufacturer reported zero moisture-related issues in 35,000 homes built after ...

  3. Hydrogen sorption characteristics of nanostructured Pd–10Rh processed by cryomilling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Nancy; Yee, Joshua K.; Zhang, Zhihui; Kurmanaeva, Lilia; Cappillino, Patrick; Stavila, Vitalie; Lavernia, Enrique J.; San Marchi, Chris

    2014-10-03

    Palladium and its alloys are model systems for studying solid-state storage of hydrogen. Mechanical milling is commonly used to process complex powder systems for solid-state hydrogen storage; however, milling can also be used to evolve nanostructured powder to modify hydrogen sorption characteristics. In the present study, cryomilling (mechanical attrition milling in a cryogenic liquid) is used to produce nanostructured palladium-rhodium alloy powder. Characterization of the cryomilled Pd-10Rh using electron microscopy, X-ray diffraction, and surface area analysis reveals that (i) particle morphology evolves from spherical to flattened disk-like particles; while the (ii) crystallite size decreases from several microns to less thanmore » 100 nm and (iii) dislocation density increases with increased cryomilling time. Hydrogen absorption and desorption isotherms as well as the time scales for absorption were measured for cryomilled Pd-10Rh, and correlated with observed microstructural changes induced by the cryomilling process. In short, as the microstructure of the Pd-10Rh alloy is refined by cryomilling: (i) the maximum hydrogen concentration in the α-phase increases, (ii) the pressure plateau becomes flatter, and (iii) the equilibrium hydrogen capacity at 760 Torr increases. In addition, the rate of hydrogen absorption was reduced by an order of magnitude compared to non-cryomilled (atomized) powder.« less

  4. Hydrogen sorption characteristics of nanostructured Pd10Rh processed by cryomilling

    SciTech Connect (OSTI)

    Yang, Nancy; Yee, Joshua K.; Zhang, Zhihui; Kurmanaeva, Lilia; Cappillino, Patrick; Stavila, Vitalie; Lavernia, Enrique J.; San Marchi, Chris

    2014-10-03

    Palladium and its alloys are model systems for studying solid-state storage of hydrogen. Mechanical milling is commonly used to process complex powder systems for solid-state hydrogen storage; however, milling can also be used to evolve nanostructured powder to modify hydrogen sorption characteristics. In the present study, cryomilling (mechanical attrition milling in a cryogenic liquid) is used to produce nanostructured palladium-rhodium alloy powder. Characterization of the cryomilled Pd-10Rh using electron microscopy, X-ray diffraction, and surface area analysis reveals that (i) particle morphology evolves from spherical to flattened disk-like particles; while the (ii) crystallite size decreases from several microns to less than 100 nm and (iii) dislocation density increases with increased cryomilling time. Hydrogen absorption and desorption isotherms as well as the time scales for absorption were measured for cryomilled Pd-10Rh, and correlated with observed microstructural changes induced by the cryomilling process. In short, as the microstructure of the Pd-10Rh alloy is refined by cryomilling: (i) the maximum hydrogen concentration in the ?-phase increases, (ii) the pressure plateau becomes flatter, and (iii) the equilibrium hydrogen capacity at 760 Torr increases. In addition, the rate of hydrogen absorption was reduced by an order of magnitude compared to non-cryomilled (atomized) powder.

  5. The valence band structure of Ag{sub x}Rh{sub 1–x} alloy nanoparticles

    SciTech Connect (OSTI)

    Yang, Anli; Sakata, Osami; Kusada, Kohei; Kobayashi, Hirokazu; Yayama, Tomoe; Ishimoto, Takayoshi; Yoshikawa, Hideki; Koyama, Michihisa; and others

    2014-10-13

    The valence band (VB) structures of face-centered-cubic Ag-Rh alloy nanoparticles (NPs), which are known to have excellent hydrogen-storage properties, were investigated using bulk-sensitive hard x-ray photoelectron spectroscopy. The observed VB spectra profiles of the Ag-Rh alloy NPs do not resemble simple linear combinations of the VB spectra of Ag and Rh NPs. The observed VB hybridization was qualitatively reproduced via a first-principles calculation. The electronic structure of the Ag{sub 0.5}Rh{sub 0.5} alloy NPs near the Fermi edge was strikingly similar to that of Pd NPs, whose superior hydrogen-storage properties are well known.

  6. Colloidally Synthesized Monodisperse Rh Nanoparticles Supported on SBA-15 for Size- and Pretreatment-Dependent Studies of CO Oxidation

    SciTech Connect (OSTI)

    Grass, Michael E.; Joo, Sang Hoon; Somorjai, Gabor A.

    2009-02-12

    A particle size dependence for CO oxidation over rhodium nanoparticles of 1.9-11.3 nm has been investigated and determined to be modified by the existence of the capping agent poly(vinylpyrrolidone) (PVP). The particles were prepared using a polyol reduction procedure with PVP as the capping agent. The Rh nanoparticles were subsequently supported on SBA-15 during hydrothermal synthesis to produce Rh/SBA-15 supported catalysts for size-dependent catalytic studies. CO oxidation by O{sub 2} at 40 Torr CO and 100 Torr O{sub 2} was investigated over two series of Rh/SBA-15 catalysts: as-synthesized Rh/SBA-15 covering the full range of Rh sizes and the same set of catalysts after high temperature calcination and reduction. The turnover frequency at 443 K increases from 0.4 to 1.7 s{sup -1} as the particle size decreases from 11.3 to 1.9 nm for the as-synthesized catalysts. After calcination and reduction, the turnover frequency is between 0.1 and 0.4 s{sup -1} with no particle size dependence. The apparent activation energy for all catalysts is {approx}30 kcal mol{sup -1} and is independent of particle size and thermal treatment. Infrared spectroscopy of CO on the Rh nanoparticles indicates that the heat treatments used influence the mode of CO adsorption. As a result, the particle size dependence for CO oxidation is altered after calcination and reduction of the catalysts. CO adsorbs at two distinct bridge sites on as-synthesized Rh/SBA-15, attributable to metallic Rh(0) and oxidized Rh(I) bridge sites. After calcination and reduction, however, CO adsorbs only at Rh(0) atop sites. The change in adsorption geometry and oxidation activity may be attributable to the interaction between PVP and the Rh surface. This capping agent affect may open new possibilities for the tailoring of metal catalysts using solution nanoparticle synthesis methods.

  7. Quality Controlled Radiosonde Profile from MC3E (Dataset) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Dataset: Quality Controlled Radiosonde Profile from MC3E Citation Details In-Document Search Title: Quality Controlled Radiosonde Profile from MC3E The sonde-adjust VAP produces data that corrects documented biases in radiosonde humidity measurements. Unique fields contained within this datastream include smoothed original relative humidity, dry bias corrected relative humidity, and final corrected relative humidity. The smoothed RH field refines the relative

  8. Fundamental Bulk/Surface Structure Photoactivity Relationships of Supported (Rh2-yCryO3)/GaN Photocatalysts

    SciTech Connect (OSTI)

    Phivilay, Somphonh; Roberts, Charles; Puretzky, Alexander A; Domen, Kazunari Domen; Wachs, Israel

    2013-01-01

    ABSTRACT. The supported (Rh2-yCryO3)/GaN photocatalyst was examined as a model nitride photocatalyst system to assist in the development of fundamental structure photoactivity relationships for UV activated water splitting. Surface characterization of the outermost surface layers by High Sensitivity-LEIS and High Resolution-XPS revealed for the first time that the GaN support consists of a GaOx outermost surface layer and a thin film of GaOxNy in the surface region. HR-XPS also demonstrates that the supported (Rh2-yCryO3) mixed oxide nanoparticles (NPs) exclusively consist of Cr+3 and Rh+3 cations and are surface enriched for the supported (Rh2-yCryO3)/GaN photocatalyst. Bulk analysis by Raman and UV-vis spectroscopy show that the bulk molecular and electronic structures, respectively, of the GaN support are not perturbed by the deposition of the (Rh2-yCryO3) mixed oxide NPs. The function of the GaN bulk lattice is to generate photoexcited electrons/holes, with the electrons harnessed by the surface Rh+3 sites for evolution of H2 and the holes trapped at the Ga oxide/oxynitride surface sites for splitting of water and evolving O2. These new structure-photoactivity relationships for supported (Rh2-yCryO3)/GaN also extend to the best performing visible light activated supported (Rh2-yCryO3)/(Ga1-xZnx)(N1-xOx) photocatalyst.

  9. X:\ARM_19~1\P273-281.WPD

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RH c ) RH c RH c RH c Session Papers 273 Evaluation of Cloud Prediction and Determination of Critical Relative Humidity for a Mesoscale Numerical Weather Prediction Model N. L. Seaman, Z. Guo, and T. P. Ackerman Pennsylvania State University, Department of Meteorology University Park, Pennsylvania Predictions of cloud occurrence and vertical location from the Pennsylvania State University/National Center for Atmospheric Research nonhydrostatic mesoscale model (MM5) were evaluated statistically

  10. Expert Meeting. Recommended Approaches to Humidity Control in High Performance Homes

    SciTech Connect (OSTI)

    Rudd, Armin

    2013-07-01

    This meeting was held on October 16, 2012, in Westford, MA, and brought together experts in the field of residential humidity control to address modeling issues for dehumidification. The presentations and discussions centered on computer simulation and field experience with these systems, with the goal of developing foundational information to support the development of a Building America Measure Guideline on this topic.

  11. Understanding the Temperature and Humidity Environment Inside a PV Module (Presentation)

    SciTech Connect (OSTI)

    Kempe, M.

    2013-06-01

    This presentation addresses moisture-driven degradation processes in PV modules and the conditions to use for accelerated stress testing. Here we show that by choosing humidity conditions that more closely match the use environment, one can minimize the uncertainty associated with moisture induced degradation modes.

  12. The influence of nano-architectured CeOx supports in RhPd/CeO₂ for the catalytic ethanol steam reforming reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Divins, N. J.; Senanayake, S. D.; Casanovas, A.; Xu, W.; Trovarelli, A.; Llorca, J.

    2015-01-19

    The ethanol steam reforming (ESR) reaction has been tested over RhPd supported on polycrystalline ceria in comparison to structured supports composed of nanoshaped CeO₂ cubes and CeO₂ rods tailored towards the production of hydrogen. At 650-700 K the hydrogen yield follows the trend RhPd/CeO₂-cubes > RhPd/CeO₂ -rods > RhPd/CeO₂- polycrystalline, whereas at temperatures higher than 800 K the catalytic performance of all samples is similar and close to the thermodynamic equilibrium. The improved performance of RhPd/CeO₂-cubes and RhPd/CeO₂ -rods for ESR at low temperature is mainly ascribed to higher water-gas shift activity and a strong interaction between the bimetallic -more » oxide support interaction. STEM analysis shows the existence of RhPd alloyed nanoparticles in all samples, with no apparent relationship between ESR performance and RhPd particle size. X-ray diffraction under operating conditions shows metal reorganization on {100} and {110} ceria crystallographic planes during catalyst activation and ESR, but not on {111} ceria crystallographic planes. The RhPd reconstructing and tuned activation over ceria nanocubes and nanorods is considered the main reason for better catalytic activity with respect to conventional catalysts based on polycrystalline ceria« less

  13. The influence of nano-architectured CeOx supports in RhPd/CeO₂ for the catalytic ethanol steam reforming reaction

    SciTech Connect (OSTI)

    Divins, N. J.; Senanayake, S. D.; Casanovas, A.; Xu, W.; Trovarelli, A.; Llorca, J.

    2015-01-19

    The ethanol steam reforming (ESR) reaction has been tested over RhPd supported on polycrystalline ceria in comparison to structured supports composed of nanoshaped CeO₂ cubes and CeO₂ rods tailored towards the production of hydrogen. At 650-700 K the hydrogen yield follows the trend RhPd/CeO₂-cubes > RhPd/CeO₂ -rods > RhPd/CeO₂- polycrystalline, whereas at temperatures higher than 800 K the catalytic performance of all samples is similar and close to the thermodynamic equilibrium. The improved performance of RhPd/CeO₂-cubes and RhPd/CeO₂ -rods for ESR at low temperature is mainly ascribed to higher water-gas shift activity and a strong interaction between the bimetallic - oxide support interaction. STEM analysis shows the existence of RhPd alloyed nanoparticles in all samples, with no apparent relationship between ESR performance and RhPd particle size. X-ray diffraction under operating conditions shows metal reorganization on {100} and {110} ceria crystallographic planes during catalyst activation and ESR, but not on {111} ceria crystallographic planes. The RhPd reconstructing and tuned activation over ceria nanocubes and nanorods is considered the main reason for better catalytic activity with respect to conventional catalysts based on polycrystalline ceria

  14. The structure and reactivity of adsorbates on stepped Rh and Pt surfaces investigated by LEED, HREELS, TPD, XPS and STM

    SciTech Connect (OSTI)

    Batteas, J.D. |

    1995-06-01

    Defects on surfaces such as steps play an important role in surface chemistry. In order to obtain an understanding of the influence of steps in surface chemical reactions, the structure and reactivity of small molecules (O{sub 2}, CO, H{sub 2}S, and C{sub 2}H{sub 4}) on atomically stepped surfaces of RH and Pt have been investigated. The detailed structures of CO and oxygen bonded to the Rh(110) surface were determined. The CO molecules bond near the short bridge sites with the CO molecular axis tilted approximately 24{degree} from the surface normal. Oxygen atoms are bound asymmetrically in the 3-fold fcc hollow-sites to the (111) facets of the steps. The interactions of CO and oxygen on the Rh(311) surface were examined. The reaction of CO with the ordered phases of O shows two distinct reaction channels, a low temperature reaction limited channel (200 K) and a high temperature diffusion limited channel (350 K). Models of the reaction geometry and dynamics are proposed. The thermal decomposition of ethylene was examined on the Rh(311) surface. The stable decomposition species (C{sub 2}H, CH and C{sub 2}) are formed near 300 K, approximately 100 K lower on the stepped Rh(311) than on the flatter Rh(111) surface. The formation of these species at lower temperatures is attributed to the stepped nature of the surface. Finally, in situ STM was used to examine surface structural changes of a stepped Pt(111) crystal under coadsorption of sulfur and CO. This is the first direct evidence for a new mechanism by which a surface covered with an unreactive, strongly chemisorbed overlayer can form new sites, for bonding and reactions to occur, by massive surface restructuring at the step edges. This new surface phenomenon answers some of the puzzles of metal surface catalysis and its implications are described. 278 refs.

  15. Heating, Ventilation, and Air Conditioning Design Strategy for a Hot-Humid Production Builder

    SciTech Connect (OSTI)

    Kerrigan, P.

    2014-03-01

    Building Science Corporation (BSC) worked directly with the David Weekley Homes - Houston division to develop a cost-effective design for moving the HVAC system into conditioned space. In addition, BSC conducted energy analysis to calculate the most economical strategy for increasing the energy performance of future production houses in preparation for the upcoming code changes in 2015. This research project addressed the following questions: 1. What is the most cost effective, best performing and most easily replicable method of locating ducts inside conditioned space for a hot-humid production home builder that constructs one and two story single family detached residences? 2. What is a cost effective and practical method of achieving 50% source energy savings vs. the 2006 International Energy Conservation Code for a hot-humid production builder? 3. How accurate are the pre-construction whole house cost estimates compared to confirmed post construction actual cost?

  16. Comfort in High-Performance Homes in a Hot-Humid Climate

    SciTech Connect (OSTI)

    Poerschke, A.; Beach, R.

    2016-01-01

    IBACOS monitored 37 homes during the late summer and early fall of 2014 in a hot and humid climate to better understand indoor comfort conditions. These homes were constructed in the last several years by four home builders that offered a comfort and performance guarantee for the homes. The homes were located in one of four cities: Tampa, Florida; Orlando, Florida; Houston, Texas; and San Antonio, Texas. Temperature and humidity data were collected from the thermostat and each room of the house using small, battery-powered data loggers. To understand system runtime and its impact on comfort, supply air temperature also was measured on a 1-minute interval. Overall, the group of homes only exceeded a room-to-room temperature difference of 6 degrees Fahrenheit for 5% of the time.

  17. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    optical characteristics on variations of the relative humidity Rh of air. The particle growth factor, which can be found as the ratio of radii corresponding to the same value of...

  18. Improved Humidity Profiling by Combining Passive and Active Remote Sensors at the Southern Great Plains

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Improved Humidity Profiling by Combining Passive and Active Remote Sensors at the Southern Great Plains L. Bianco, D. Cimini, and F. Marzano Center of Excellence CETEMPS University of L'Aquila L'Aquila, Italy L. Bianco and E. R. Westwater Cooperative Institute for Research in Environmental Sciences University of Colorado National Oceanic and Atmospheric Administration Environmental Technology Laboratory Boulder, Colorado R. Ware Radiometrics Co. and University Consortium for Atmospheric Research

  19. 40% Whole-House Energy Savings in the Hot-Humid Climate

    SciTech Connect (OSTI)

    none,

    2011-09-01

    This guide book is a resource to help builders design and construct highly energy-efficient homes, while addressing building durability, indoor air quality, and occupant health, safety, and comfort. With the measures described in this guide, builders in the hot-humid climate can build homes that achieve whole house energy savings of 40% over the Building America benchmark (the 1993 Model Energy Code) with no added overall costs for consumers.

  20. 40% Whole-House Energy Savings in the Mixed-Humid Climate

    SciTech Connect (OSTI)

    Baechler, Michael C.; Gilbride, T. L.; Hefty, M. G.; Cole, P. C.; Adams, K.; Butner, R. S.; Ortiz, S. J.; Love, Pat M.

    2011-09-01

    This guide book is a resource to help builders design and construct highly energy-efficient homes, while addressing building durability, indoor air quality, and occupant health, safety, and comfort. With the measures described in this guide, builders in the mixed-humid climate can build homes that achieve whole house energy savings of 40% over the Building America benchmark (the 1993 Model Energy Code) with no added overall costs for consumers.

  1. IEC Quality Assurance Task Group 5: UV, Temperature, and Humidity (Presentation)

    SciTech Connect (OSTI)

    Miller, D.; Bath, J.; Kohl, M.; Shioda, T.

    2014-03-01

    Taskgroup 5 (TG5) is concerned with a comparative aging standard incorporating factors including ultraviolet radiation, temperature, and humidity. Separate experiments are being conducted in support of a test standard via the regional sub-groups in Asia, Europe, and the United States. The authors will describe the objectives and timeline for TG5 as well as providing an update on the experiments in progress.

  2. Synthesis, NMR spectra, and structure of rhodium hydride complexes with Rh-Sn bonds

    SciTech Connect (OSTI)

    Krut'ko, B.P.; Permin, A.B.; Petrosyan, V.S.; Reutov, O.A.

    1985-06-20

    The authors study the hydride complexes using Sn 119 and H 1 NMR spectroscopy. The spectra were taken in a pulse mode on a Varian FT-80A spectrometer equipped with a wideband system at 29.66 and 79.54 MHz. The Sn 119 and H 1 NMR spectral parameters for a solution of the complex (Bu/sub 4/N)/sub 3/ (HRh(SnCl/sub 3/)/sub 5/) in CD/sub 3/CN are shown, the spectra show that the (HRh(SnCl/sub 3/)/sub 5/)/sup 3 -/ anion has octahedral structure with four equatorial and one axial Rh-Sn bonds. New rhodium hydride complexes with general formula (R/sub 4/N)/sub 3/(HRh(SnCl/sub 3/)/sub 5/) were synthesized.

  3. Magnetism and superconductivity in U2PtxRh1-xC2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-09

    We report the phase diagram of the doping series U₂PtxRh(1–x)C₂, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Néel temperature of U₂Rh₂C₂ of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. Additionally, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ≥ 0.9, with Tc increasing with increasing x. Themore » reduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.« less

  4. Single to Multiquasiparticle Excitations in the Itinerant Helical Magnet CeRhIn5

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stock, C.; Rodriguez-Rivera, J. A.; Schmalzl, K.; Rodriguez, E. E.; Stunault, A.; Petrovic, C.

    2015-06-19

    Neutron scattering is used to measure the quantum spin fluctuations in CeRhIn5 - the parent material of the eXIn5 superconducting series. Out-of-plane spin fluctuations are gapped and localized in momentum, similar to the spin excitons in CeCoIn5. The in-plane fluctuations consist of sharp spin-wave excitations parameterized by a nearest neighbor exchange JRKKY =0.88 ± 0.05 meV that crossover to a temporally and spatially broad multiparticle spectrum with energies of ~ 2 × JRKKY . This continuum represents composite fluctuations that illustrate the breakdown of single magnons originating from the delicate energy balance between localized 4f and itinerant behavior in amore » heavy metal. The experiment therefore shows how quasiparticle behavior is changed by the close proximity of quantum criticality.« less

  5. Single to Multiquasiparticle Excitations in the Itinerant Helical Magnet CeRhIn5

    SciTech Connect (OSTI)

    Stock, C.; Rodriguez-Rivera, J. A.; Schmalzl, K.; Rodriguez, E. E.; Stunault, A.; Petrovic, C.

    2015-06-19

    Neutron scattering is used to measure the quantum spin fluctuations in CeRhIn5 - the parent material of the eXIn5 superconducting series. Out-of-plane spin fluctuations are gapped and localized in momentum, similar to the spin excitons in CeCoIn5. The in-plane fluctuations consist of sharp spin-wave excitations parameterized by a nearest neighbor exchange JRKKY =0.88 ± 0.05 meV that crossover to a temporally and spatially broad multiparticle spectrum with energies of ~ 2 × JRKKY . This continuum represents composite fluctuations that illustrate the breakdown of single magnons originating from the delicate energy balance between localized 4f and itinerant behavior in a heavy metal. The experiment therefore shows how quasiparticle behavior is changed by the close proximity of quantum criticality.

  6. Superconducting properties of Rh9In4S4 single crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kaluarachchi, Udhara S.; Lin, Qisheng; Xie, Weiwei; Taufour, Valentin; Bud'ko, Sergey L.; Miller, Gordon J.; Canfield, Paul C.

    2016-03-28

    The synthesis and crystallographic, thermodynamic, and transport properties of single crystalline Rh9In4S4 were studied. The resistivity, magnetization, and specific heat measurements all clearly indicate bulk superconductivity with a critical temperature, Tc~2.25 K. The Sommerfeld coefficient γ and the Debye temperature (ΘD) were found to be 34 mJ mol–1 K–2 and 217 K, respectively. The observed specific heat jump, ΔC/γTc=1.66, is larger than the expected BCS weak coupling value of 1.43. Ginzburg-Landau (GL) ratio of the low-temperature GL-penetration depth, λGL≈5750 Å, to the GL-coherence length, ξGL≈94 Å, is large: κ ~60. However, we observed a peak effect in the resistivity measurementmore » as a function of both temperature and magnetic field.« less

  7. ?ot8rh QI ahnloal Corporation In Hart IUnover, Ma86rohusett8,

    Office of Legacy Management (LM)

    GE 1 ;" qr)-1 s?llq ' p raspy.. c" ifa K. mris I talked with Hr. Wllllm cIF(Iy, Metrllurgist, Wnlon CarbId@ Nuclear cOrp8ny, 08k B&t&$@, Tenne66ee, on April 26, 1961. He informed me th&t the #rtioMl Northern birislon, Ame~ic6.n ?ot8rh QI ahnloal Corporation In Hart IUnover, Ma86rohusett8, la pePfopn1~ lo8lve forming studier for the. ilnion olo)w Wuolem Conpmy "p l7?JHa). The work at National Northern l#rirc.- alon ir under the 6upenl6lon of Ehsll Phillpohuc4~, v of

  8. National Weatherization Assistance Program Impact Evaluation: Impact of Exhaust-Only Ventilation on Radon and Indoor Humidity - A Field Investigation

    SciTech Connect (OSTI)

    Pigg, Scott

    2014-09-01

    The study described here sought to assess the impact of exhaust-only ventilation on indoor radon and humidity in single-family homes that had been treated by the Weatherization Assistance Program (WAP).

  9. Evaluation of the Performance of Houses With and Without Supplemental Dehumidification in a Hot-Humid Climate

    SciTech Connect (OSTI)

    Kerrigan, P.; Norton, P.

    2014-10-01

    This report, Evaluation of the Performance of Houses with and without Supplemental Dehumidification in a Hot-Humid Climate, describes a research study that that was conducted by the Building Science Corporation (BSC) Building America Research Team. BSC seeks to research and report on the field monitoring of the performance of in-situ supplemental dehumidification systems in low energy, high performance, homes in a Hot-Humid climate. The purpose of this research project was to observe and compare the humidity control performance of new, single family, low energy, and high performance, homes. Specifically, the study sought to compare the interior conditions and mechanical systems operation between two distinct groups of houses, homes with a supplemental dehumidifier installed in addition to HVAC system, and homes without any supplemental dehumidification. The subjects of the study were ten single-family new construction homes in New Orleans, LA.Data logging equipment was installed at each home in 2012. Interior conditions and various end-use loads were monitored for one year. In terms of averages, the homes with dehumidifiers are limiting elevated levels of humidity in the living space. However, there was significant variation in humidity control between individual houses. An analysis of the equipment operation did not show a clear correlation between energy use and humidity levels. In general, no single explanatory variable appears to provide a consistent understanding of the humidity control in each house. Indoor humidity is likely due to all of the factors we have examined, and the specifics of how they are used by each occupant.

  10. Energy Retrofit Field Study and Best Practices in a Hot-Humid Climate

    SciTech Connect (OSTI)

    McIvaine, J.; Sutherland, K.; Martin, E.

    2013-03-01

    Energy efficiency improvement as a component of comprehensive renovation was investigated under U.S. Department of Energy (DOE) funding of the Building America Partnership for Improved Residential Construction (BA-PIRC). Researchers at the Florida Solar Energy Center (FSEC) worked with affordable housing partners renovating foreclosed homes built from the 1950's through the 2000's in the hot-humid climate (within the Southern census region), primarily in Florida. Researchers targeted a 30% improvement in whole-house energy efficiency along with the health and safety, durability, and comfort guidelines outlined in DOE's Builders Challenge Program (Version 1) Quality Criteria.

  11. Field Testing Unvented Roofs with Asphalt Shingles in Cold and Hot-Humid Climates

    SciTech Connect (OSTI)

    Ueno, Kohta; Lstiburek, Joseph W.

    2015-09-01

    Test houses with unvented roof assemblies were built to measure long-term moisture performance, in the Chicago area (5A) and the Houston area (2A). The Chicago-area test bed had seven experimental rafter bays, including a control vented compact roof, and six unvented roof variants with cellulose or fiberglass insulation. The interior was run at 50% RH. The Houston-area roof was an unvented attic insulated with spray-applied fiberglass. Most ridges and hips were built with a diffusion vent detail, capped with vapor permeable roof membrane. In contrast, the diffusion vent roofs had drier conditions at the roof peak in wintertime, but during the summer, RHs and MCs were higher than the unvented roof (albeit in the safe range).

  12. Field Testing Unvented Roofs with Asphalt Shingles in Cold and Hot-Humid Climates

    SciTech Connect (OSTI)

    Ueno, Kohta; Lstiburek, Joseph W.

    2015-09-01

    Insulating roofs with dense-pack cellulose (instead of spray foam) has moisture risks, but is a lower cost approach. If moisture risks could be addressed, buildings could benefit from retrofit options, and the ability to bring HVAC systems within the conditioned space. Test houses with unvented roof assemblies were built to measure long-term moisture performance, in the Chicago area (5A) and the Houston area (2A). The Chicago-area test bed had seven experimental rafter bays, including a control vented compact roof, and six unvented roof variants with cellulose or fiberglass insulation. The interior was run at 50% RH. All roofs except the vented cathedral assembly experienced wood moisture contents and RH levels high enough to constitute failure. Disassembly at the end of the experiment showed that the unvented fiberglass roofs had wet sheathing and mold growth. In contrast, the cellulose roofs only had slight issues, such as rusted fasteners and sheathing grain raise. The Houston-area roof was an unvented attic insulated with spray-applied fiberglass. Most ridges and hips were built with a diffusion vent detail, capped with vapor permeable roof membrane. Some ridge sections were built as a conventional unvented roof, as a control. In the control unvented roofs, roof peak RHs reached high levels in the first winter; as exterior conditions warmed, RHs quickly fell. In contrast, the diffusion vent roofs had drier conditions at the roof peak in wintertime, but during the summer, RHs and MCs were higher than the unvented roof (albeit in the safe range).

  13. Heating, Ventilation, and Air Conditioning Design Strategy for a Hot-Humid Production Builder

    SciTech Connect (OSTI)

    Kerrigan, P.

    2014-03-01

    BSC worked directly with the David Weekley Homes - Houston division to redesign three floor plans in order to locate the HVAC system in conditioned space. The purpose of this project is to develop a cost effective design for moving the HVAC system into conditioned space. In addition, BSC conducted energy analysis to calculate the most economical strategy for increasing the energy performance of future production houses. This is in preparation for the upcoming code changes in 2015. The builder wishes to develop an upgrade package that will allow for a seamless transition to the new code mandate. The following research questions were addressed by this research project: 1. What is the most cost effective, best performing and most easily replicable method of locating ducts inside conditioned space for a hot-humid production home builder that constructs one and two story single family detached residences? 2. What is a cost effective and practical method of achieving 50% source energy savings vs. the 2006 International Energy Conservation Code for a hot-humid production builder? 3. How accurate are the pre-construction whole house cost estimates compared to confirmed post construction actual cost? BSC and the builder developed a duct design strategy that employs a system of dropped ceilings and attic coffers for moving the ductwork from the vented attic to conditioned space. The furnace has been moved to either a mechanical closet in the conditioned living space or a coffered space in the attic.

  14. Building for the Pacific Rim Countries. Energy-efficient building strategies for hot, humid climates

    SciTech Connect (OSTI)

    Sheinkopf, K.

    1991-09-01

    This book has been published by the Solar Energy Industries Association (SEIA), the US trade association of the solar thermal, photovoltaic, and passive solar manufacturers, distributors, and component suppliers. Its purpose is to help architects, builders, and developers construct energy-efficient homes in hot humid climates like the Pacific Rim Countries, and to allow occupants of these homes to enjoy enhanced comfort without reliance on mechanical air-conditioning systems. Two important factors are addressed in this book. First, the past few years have seen a tremendous increase in practical applications of new research. The current popularity of ceiling paddle fans, attic radiant barriers and natural daylighting attest to the importance of keeping up with the latest concepts in energy-reduction and comfort-awareness. Professionals who have been in the field for the past few years may be unaware of the latest research findings--some of which dramatically alter prior thinking on such subjects as natural ventilation or mechanical air conditioning. The second factor is the importance of site-specific characteristics, which greatly affect building strategies and designs. A thorough understanding of the climate is a prerequisite to good building design. Such factors as temperature, humidity, wind speed and direction, and solar radiation must be understood and properly integrated into the design for the home to be truly energy-efficient.

  15. HVAC Design Strategy for a Hot-Humid Production Builder, Houston, Texas (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-03-01

    BSC worked directly with the David Weekley Homes - Houston division to redesign three floor plans in order to locate the HVAC system in conditioned space. The purpose of this project is to develop a cost effective design for moving the HVAC system into conditioned space. In addition, BSC conducted energy analysis to calculate the most economical strategy for increasing the energy performance of future production houses. This is in preparation for the upcoming code changes in 2015. The builder wishes to develop an upgrade package that will allow for a seamless transition to the new code mandate. The following research questions were addressed by this research project: 1. What is the most cost effective, best performing and most easily replicable method of locating ducts inside conditioned space for a hot-humid production home builder that constructs one and two story single family detached residences? 2. What is a cost effective and practical method of achieving 50% source energy savings vs. the 2006 International Energy Conservation Code for a hot-humid production builder? 3. How accurate are the pre-construction whole house cost estimates compared to confirmed post construction actual cost? BSC and the builder developed a duct design strategy that employs a system of dropped ceilings and attic coffers for moving the ductwork from the vented attic to conditioned space. The furnace has been moved to either a mechanical closet in the conditioned living space or a coffered space in the attic.

  16. Approaches to 30% Energy Savings at the Community Scale in the Hot-Humid Climate

    SciTech Connect (OSTI)

    Thomas-Rees, S.; Beal, D.; Martin, E.; Fonorow, K.

    2013-03-01

    BA-PIRC has worked with several community-scale builders within the hot humid climate zone to improve performance of production, or community scale, housing. Tommy Williams Homes (Gainesville, FL), Lifestyle Homes (Melbourne, FL), and Habitat for Humanity (various locations, FL) have all been continuous partners of the BA Program and are the subjects of this report to document achievement of the Building America goal of 30% whole house energy savings packages adopted at the community scale. The scope of this report is to demonstrate achievement of these goals though the documentation of production-scale homes built cost-effectively at the community scale, and modeled to reduce whole-house energy use by 30% in the Hot Humid climate region. Key aspects of this research include determining how to evolve existing energy efficiency packages to produce replicable target savings, identifying what builders' technical assistance needs are for implementation and working with them to create sustainable quality assurance mechanisms, and documenting the commercial viability through neutral cost analysis and market acceptance. This report documents certain barriers builders overcame and the approaches they implemented in order to accomplish Building America (BA) Program goals that have not already been documented in previous reports.

  17. Relative Hazard and Risk Measure Calculation Methodology

    SciTech Connect (OSTI)

    Stenner, Robert D.; Strenge, Dennis L.; Elder, Matthew S.

    2004-03-20

    The relative hazard (RH) and risk measure (RM) methodology and computer code is a health risk-based tool designed to allow managers and environmental decision makers the opportunity to readily consider human health risks (i.e., public and worker risks) in their screening-level analysis of alternative cleanup strategies. Environmental management decisions involve consideration of costs, schedules, regulatory requirements, health hazards, and risks. The RH-RM tool is a risk-based environmental management decision tool that allows managers the ability to predict and track health hazards and risks over time as they change in relation to mitigation and cleanup actions. Analysis of the hazards and risks associated with planned mitigation and cleanup actions provides a baseline against which alternative strategies can be compared. This new tool allows managers to explore “what if scenarios,” to better understand the impact of alternative mitigation and cleanup actions (i.e., alternatives to the planned actions) on health hazards and risks. This new tool allows managers to screen alternatives on the basis of human health risk and compare the results with cost and other factors pertinent to the decision. Once an alternative or a narrow set of alternatives are selected, it will then be more cost-effective to perform the detailed risk analysis necessary for programmatic and regulatory acceptance of the selected alternative. The RH-RM code has been integrated into the PNNL developed Framework for Risk Analysis In Multimedia Environmental Systems (FRAMES) to allow the input and output data of the RH-RM code to be readily shared with the more comprehensive risk analysis models, such as the PNNL developed Multimedia Environmental Pollutant Assessment System (MEPAS) model.

  18. Mechanistic aspects of [Rh(nbd)CI][sub 2]initiated oligomerization of new acetylenic monomers

    SciTech Connect (OSTI)

    Densmore, C.G. (Crystal G); Rasmussen, P.G. (Paul G.)

    2004-01-01

    Although a number of papers report the use of rhodium-based initiators, very little has been said about the mechanism of acetylene polymerizations. Kishimoto and coworkers recently proposed an insertion mechanism for the rhodium-initiated polymerization of phenylacetylenes. The initiator consisted of the tetracoordinate rhodium complex, Rh(C{triple_bond}CC{sub 6}H{sub 5})(nbd)(PPh{sub 3}) with 4-(dimethylamino)-pyidine. The product was found to be stereoregular poly(phenylacety1ene) with a cis-transoidal backbone microstructure. Gorman and coworkers found palladium and nickel-based catalysts to be successful in the polymerization of cyanoacetylene. Zhan and Yang addressed the polymerization mechanism of acetylenes using palladium and nickel acetylide catalysts. They propose that the initial activation step, and also the rate-determining step, involve coordination of a nickel or palladium acetylide catalyst with an acetylene. Based on NMR and elemental analysis, we propose a more complete mechanistic picture of acetylene polymerizations, especially those with electron-withdrawing substituents.

  19. Ternary Pt/Rh/SnO2 Electrocatalysts for Oxidizing Ethanol to CO2

    SciTech Connect (OSTI)

    Kowal, A.; Li, M; Shao, M; Sasaki, K; Vukmirovic, M; Zhang, J; Marinkovic, N; Liu, P; Frenkel, A; Adzic, R

    2009-01-01

    Ethanol, with its high energy density, likely production from renewable sources and ease of storage and transportation, is almost the ideal combustible for fuel cells wherein its chemical energy can be converted directly into electrical energy. However, commercialization of direct ethanol fuel cells has been impeded by ethanol's slow, inefficient oxidation even at the best electrocatalysts1, 2. We synthesized a ternary PtRhSnO2/C electrocatalyst by depositing platinum and rhodium atoms on carbon-supported tin dioxide nanoparticles that is capable of oxidizing ethanol with high efficiency and holds great promise for resolving the impediments to developing practical direct ethanol fuel cells. This electrocatalyst effectively splits the C-C bond in ethanol at room temperature in acid solutions, facilitating its oxidation at low potentials to CO2, which has not been achieved with existing catalysts. Our experiments and density functional theory calculations indicate that the electrocatalyst's activity is due to the specific property of each of its constituents, induced by their interactions. These findings help explain the high activity of Pt-Ru for methanol oxidation and the lack of it for ethanol oxidation, and point to the way to accomplishing the C-C bond splitting in other catalytic processes.

  20. Ternary Pt/Rh/SnO2 Electrocatalysts for Oxidizing Ethanol to CO2

    SciTech Connect (OSTI)

    Adzic, R.R.; Kowal, A.; Li, M.; Shao, M.; Sasaki, K.; Vukmirovic, M.B.; Zhang, J.; Marinkovic, N.S. Liu, P.; Frenkel, A.I.

    2009-04-01

    Ethanol, with its high energy density, likely production from renewable sources and ease of storage and transportation, is almost the ideal combustible for fuel cells wherein its chemical energy can be converted directly into electrical energy. However, commercialization of direct ethanol fuel cells has been impeded by ethanol's slow, inefficient oxidation even at the best electrocatalysts. We synthesized a ternary PtRhSnO{sub 2}/C electrocatalyst by depositing platinum and rhodium atoms on carbon-supported tin dioxide nanoparticles that is capable of oxidizing ethanol with high efficiency and holds great promise for resolving the impediments to developing practical direct ethanol fuel cells. This electrocatalyst effectively splits the C-C bond in ethanol at room temperature in acid solutions, facilitating its oxidation at low potentials to CO{sub 2}, which has not been achieved with existing catalysts. Our experiments and density functional theory calculations indicate that the electrocatalyst's activity is due to the specific property of each of its constituents, induced by their interactions. These findings help explain the high activity of Pt-Ru for methanol oxidation and the lack of it for ethanol oxidation, and point to the way to accomplishing the C-C bond splitting in other catalytic processes.

  1. Magnetism and superconductivity in U?PtxRh(1x)C?

    SciTech Connect (OSTI)

    Wakeham, N.; Ni, Ni; Bauer, E. D.; Thompson, J. D.; Tegtmeier, E.; Ronning, F.

    2015-01-01

    We report the phase diagram of the doping series U?PtxRh(1x)C?, studied through measurements of resistivity, specific heat, and magnetic susceptibility. The Nel temperature of U?Rh?C? of ~ 22 K is suppressed with increasing Pt content, reaching zero temperature close to x = 0.7, where we observed signatures of increased quantum fluctuations. In addition, evidence is presented that the antiferromagnetic state undergoes a spin-reorientation transition upon application of an applied magnetic field. This transition shows non-monotonic behavior as a function of x, peaking at around x = 0.3. Superconductivity is observed for x ? 0.9, with Tc increasing with increasing x. The reduction in Tc and increase in residual resistivity with decreasing Pt content is inconsistent with the extension of the Abrikosov-Gor'kov theory to unconventional superconductivity.

  2. Synthesis and crystal structure of two new cerium rhodium oxides: Ce{sub 2/3-x}Rh{sup 3+}{sub 2}O{sub 4} (x{approx}0.12) with Ce mixed valency and Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5}

    SciTech Connect (OSTI)

    Mizoguchi, Hiroshi; Zakharov, L.N.; Bhuvanesh, N.S.P.; Sleight, A.W.; Subramanian, M.A.

    2011-06-15

    The new compounds Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) and CeRh{sub 2}O{sub 5} have been prepared. Their structures were determined from single crystal X-ray diffraction data. Electrical and magnetic properties were also evaluated. Based on the structural analysis and physical properties, oxidation states for CeRh{sub 2}O{sub 5} can be assigned as Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5}. A small variation in x was detected for Ce{sub 2/3-x}Rh{sub 2}O{sub 4} indicating a formula ranging from Ce{sup 3.64+}{sub 0.55}Rh{sup 3+}{sub 2}O{sub 4} to Ce{sup 3.81+}{sub 0.525}Rh{sup 3+}{sub 2}O{sub 4}. - Graphical abstract: The new compounds Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) and CeRh{sub 2}O{sub 5} have been prepared and their structures were determined from single crystal X-ray diffraction data. Electrical and magnetic properties were also evaluated. Highlights: > The new compounds CeRh{sub 2}O{sub 5} and Ce{sub 2/3-x}Rh{sub 2}O{sub 4} (x{approx}0.11-0.14) have been prepared. > Their structures were determined from single crystal X-ray diffraction data. > Valence picture is Ce{sup 4+}Rh{sup 3+}{sub 2}O{sub 5} and Ce{sup 3.64+}{sub 0.55}Rh{sup 3+}{sub 2}O{sub 4} to Ce{sup 3.81+}{sub 0.525}Rh{sup 3+}{sub 2}O{sub 4}.

  3. Safety evaluation for packaging (onsite) for the concrete-shielded RH TRU drum for the 327 Postirradiation Testing Laboratory

    SciTech Connect (OSTI)

    Smith, R.J.

    1998-03-31

    This safety evaluation for packaging authorizes onsite transport of Type B quantities of radioactive material in the Concrete Shielded Remote-Handled Transuranic Waste (RH TRU) Drum per HNF-PRO-154, Responsibilities and Procedures for all Hazardous Material Shipments. The drum will be used for transport of 327 Building legacy waste from the 300 Area to a solid waste storage facility on the Hanford Site.

  4. Excited states in {sup 115}Pd populated in the {beta}{sup -} decay of {sup 115}Rh

    SciTech Connect (OSTI)

    Kurpeta, J.; Plochocki, A. [Faculty of Physics, University of Warsaw, ul. Hoza 69, PL-00-681 Warsaw (Poland); Urban, W. [Faculty of Physics, University of Warsaw, ul. Hoza 69, PL-00-681 Warsaw (Poland); Institut Laue-Langevin, 6 rue J. Horowitz, F-38042 Grenoble (France); Rissanen, J.; Eronen, T.; Hakala, J.; Jokinen, A.; Kankainen, A.; Karvonen, P.; Moore, I. D.; Penttilae, H.; Saastamoinen, A.; Weber, C.; Aeystoe, J. [Department of Physics, University of Jyvaeskylae, P.O. Box 35, FIN-40351, Jyvaeskylae (Finland); Elomaa, V.-V. [Turku PET Centre, Accelerator Laboratory, Abo Akademi University, FIN-20500 Turku (Finland); Rahaman, S. [Physics Division, P-23, Mail Stop H803, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Sonoda, T. [Nishina Center for Accelerator Based Science, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198 (Japan); Szerypo, J. [Fakultaet fuer Physik, Ludwig-Maximilians-Universitaet Muenchen, Am Coulombwall 1, D-85748 Garching (Germany)

    2010-08-15

    Excited states in {sup 115}Pd, populated following the {beta}{sup -} decay of {sup 115}Rh have been studied by means of {gamma} spectroscopy after the Penning-trap station at the IGISOL facility, University of Jyvaeskylae. The 1/2{sup +} spin and parity assignment of the ground state of {sup 115}Pd, confirmed in this work, may indicate a transition to an oblate shape in Pd isotopes at high neutron number.

  5. Investigation of the physical properties of the tetragonal CeMAl4Si2 (M = Rh, Ir, Pt) compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ghimire, N. J.; Ronning, F.; Williams, D. J.; Scott, B. L.; Luo, Yongkang; Thompson, J. D.; Bauer, E. D.

    2014-12-15

    The synthesis, crystal structure and physical properties studied by means of x-ray diffraction, magnetic, thermal and transport measurements of CeMAl4Si2 (M = Rh, Ir, Pt) are reported, along with the electronic structure calculations for LaMAl4Si2 (M = Rh, Ir, Pt). These materials adopt a tetragonal crystal structure (space group P4/mmm) comprised of BaAl4 blocks, separated by MAl2 units, stacked along the c-axis. Both CeRhAl4Si2 and CeIrAl4Si2 order antiferromagnetically below TN1 = 14 and 16 K, respectively, and undergo a second antiferromagnetic transitition at lower temperature (TN2 = 9 and 14 K, respectively). CePtAl4Si2 orders ferromagnetically below TC = 3 Kmore » with an ordered moment of μsat = 0.8 μB for a magnetic field applied perpendicular to the c-axis. Electronic structure calculations reveal quasi-2D character of the Fermi surface.« less

  6. Features of conduction mechanisms in n-HfNiSn semiconductor heavily doped with a Rh acceptor impurity

    SciTech Connect (OSTI)

    Romaka, V. A.; Rogl, P.; Stadnyk, Yu. V.; Romaka, V. V.; Hlil, E. K.; Krajovskii, V. Ya.; Horyn, A. M.

    2013-09-15

    The crystal structure and electron-density distribution, as well as the energy, kinetic, and magnetic characteristics of n-HfNiSn intermetallic semiconductor heavily doped with a Rh acceptor impurity in the temperature range T = 80-400 K, in the acceptor-concentration range N{sub A}{sup Rh} Almost-Equal-To 9.5 Multiplication-Sign 10{sup 19}-1.9 Multiplication-Sign 10{sup 21} cm{sup -3} (x = 0.005-0.10), and in magnetic fields H {<=} 10 kG are investigated. It is established that doping is accompanied by a simultaneous decrease in concentration, the elimination of donor-type structural defects (to x Almost-Equal-To 0.02), and an increase in the concentration of acceptor-type structural defects (0 < x {<=} 0.10). The dependence of the degree of semiconductor compensation on temperature is revealed. A model of the spatial arrangement of atoms in HfNi{sub 1-x}Rh{sub x}Sn is proposed, and the results of calculating the electron structure based on this model agree with the results of investigations of the kinetic and magnetic characteristics of the semiconductor. The results are discussed within the context of the Shklovskii-Efros model for a heavily doped and compensated semiconductor.

  7. Effects of PV Module Soiling on Glass Surface Resistance and Potential-Induced Degradation: Preprint

    SciTech Connect (OSTI)

    Hacke, Peter; Burton, Patrick; Hendrickson, Alex; Spartaru, Sergiu; Glick, Stephen; Terwilliger, Kent

    2015-12-03

    The sheet resistance of three soil types (Arizona road dust, soot, and sea salt) on glass were measured by the transmission line method as a function of relative humidity (RH) between 39% and 95% at 60 degrees C. Sea salt yielded a 3.5 order of magnitude decrease in resistance on the glass surface when the RH was increased over this RH range. Arizona road dust showed reduced sheet resistance at lower RH, but with less humidity sensitivity over the range tested. The soot sample did not show significant resistivity change compared to the unsoiled control. Photovoltaic modules with sea salt on their faces were step-stressed between 25% and 95% RH at 60 degrees C applying -1000 V bias to the active cell circuit. Leakage current from the cell circuit to ground ranged between two and ten times higher than that of the unsoiled controls. Degradation rate of modules with salt on the surface increased with increasing RH and time.

  8. Spin-orbit tuned metal-insulator transitions in single-crystal Sr?Ir1xRhxO? (0?x?1)

    SciTech Connect (OSTI)

    Qi, T. F.; Korneta, O. B.; Li, L.; Butrouna, K.; Cao, V. S.; Wan, Xiangang; Schlottmann, P.; Kaul, R. K.; Cao, G.

    2012-09-06

    Sr?IrO? is a magnetic insulator driven by spin-orbit interaction (SOI) whereas the isoelectronic and isostructural Sr?RhO? is a paramagnetic metal. The contrasting ground states have been shown to result from the critical role of the strong SOI in the iridate. Our investigation of structural, transport, magnetic, and thermal properties reveals that substituting 4d Rh?? (4d?) ions for 5d Ir?? (5d?) ions in Sr?IrO? directly reduces the SOI and rebalances the competing energies so profoundly that it generates a rich phase diagram for Sr?Ir1xRhxO? featuring two major effects: (1) Light Rh doping (0 ? x ? 0.16) prompts a simultaneous and precipitous drop in both the electrical resistivity and the magnetic ordering temperature TC, which is suppressed to zero at x = 0.16 from 240 K at x = 0. (2) However, with heavier Rh doping [0.24 < x < 0.85 (0.05)] disorder scattering leads to localized states and a return to an insulating state with spin frustration and exotic magnetic behavior that only disappears near x = 1. The intricacy of Sr?Ir1xRhxO? is further highlighted by comparison with Sr?Ir1xRuxO? where Ru?? (4d?) drives a direct crossover from the insulating to metallic states.

  9. Influence of humidity on the scattering of {gamma}-rays in soil

    SciTech Connect (OSTI)

    Cortes, M. L.; Melo, L. M.; Cristancho, F.

    2010-08-04

    Transmission and backscattering of {gamma}-rays have been used to study soil properties such as its porosity, hydraulic conductivity and also for the detection of organic material buried in soil. These applications require a deeper understanding of the interaction of {gamma}-rays with soil. In the present work a study of the interaction of 511 keV {gamma}-rays with layers of sand varying both its humidity and thickness is presented. The experimental set-up uses the positron decay of a {sup 22}Na source, and two gamma detectors connected in fast time-coincidence. Both transmitted and backscattered spectra are obtained. For transmission, the photopeak and the low angle scattered photons are studied, and for backscattering we analyze the number of single and multiple backscattered photons as a function of thickness. Finally, a theoretical model for the derivative of the number of backscattered photons as a function of depth is presented.

  10. PARAMETRIC STUDY OF GROUND SOURCE HEAT PUMP SYSTEM FOR HOT AND HUMID CLMATE

    SciTech Connect (OSTI)

    Jiang Zhu; Yong X. Tao

    2011-11-01

    The U-tube sizes and varied thermal conductivity with different grout materials are studied based on the benchmark residential building in Hot-humid Pensacola, Florida. In this study, the benchmark building is metered and the data is used to validate the simulation model. And a list of comparative simulation cases with varied parameter value are simulated to study the importance of pipe size and grout to the ground source heat pump energy consumption. The simulation software TRNSYS [1] is employed to fulfill this task. The results show the preliminary energy saving based on varied parameters. Future work needs to be conducted for the cost analysis, include the installation cost from contractor and materials cost.

  11. Approaches to 30 Percent Energy Savings at the Community Scale in the Hot-Humid Climate

    SciTech Connect (OSTI)

    Thomas-Rees, S.; Beal, D.; Martin, E.

    2013-03-01

    BA-PIRC has worked with several community-scale builders within the hot humid climate zone to improve performance of production, or community scale, housing. Tommy Williams Homes (Gainesville, FL), Lifestyle Homes (Melbourne, FL), and Habitat for Humanity (various locations, FL) have all been continuous partners of the Building America program and are the subjects of this report to document achievement of the Building America goal of 30% whole house energy savings packages adopted at the community scale. Key aspects of this research include determining how to evolve existing energy efficiency packages to produce replicable target savings, identifying what builders' technical assistance needs are for implementation and working with them to create sustainable quality assurance mechanisms, and documenting the commercial viability through neutral cost analysis and market acceptance. This report documents certain barriers builders overcame and the approaches they implemented in order to accomplish Building America (BA) Program goals that have not already been documented in previous reports.

  12. Variable Speed Heat Pump Sizing Guide for Mixed-Humid Climates

    SciTech Connect (OSTI)

    Munk, Jeffrey D; Odukomaiya, Adewale; Jackson, Roderick K; Boudreaux, Philip R

    2015-03-01

    The similarities and differences between different capacity units in a model family will vary depending on the manufacturer. These unit specific details are critical to choosing the VSHP capacity that will yield the highest energy savings without compromising comfort. In addition, the house construction, climate, and occupant behavior will influence the balance of the heating and cooling load on the house as well as the sensible and latent cooling demand. All of these factors need to be considered when trying to select the proper unit for the highest energy savings. Based on the simulations performed in this study, it is likely that VSHPs with an enhanced dehumidification mode can be sized up to two times the cooling load of the house without any reduction in comfort when compared to a single speed heat pump assuming a typical home and occupant behavior in the mixed-humid and cold climates.

  13. Evaluation and performance of the special wasteform lysimeters at a humid site

    SciTech Connect (OSTI)

    Oblath, S B; Hoeffner, S L

    1985-09-01

    The Savannah River Laboratory has been evaluating the leaching/migration behavior of commercial power reactor wasteforms by the use of lysimeters operated under field conditions at a humid site. These lysimeters model the conditions in actual burial trenches. Wasteforms comprising Portland cement, masonry cement, and vinyl ester-styrene polymer wasteforms were emplaced in the lysimeters in March 1982. Effluent water has been analyzed on a regular basis since that time. Cs-137, Sr-90, and/or Co-60 have observed in the effluent water from the lysimeters, as well as in soil moisture samples collected from the unsaturated zone beneath the wasteforms. In March of 1984, horizontal cores were taken from one of the lysimeters containing a Portland cement wasteform to determine the vertical and radial profiles of radionuclides which might not have reached the lysimeter sump. Results from all of these sampling methods are discussed and interpreted. 6 refs., 3 figs., 3 tabs.

  14. Efficient Multifamily Homes in a Hot-Humid Climate by Atlantic Housing Partners

    SciTech Connect (OSTI)

    Chasar, D.; Martin, E.

    2013-04-01

    With assistance from the Florida Solar Energy Center (FSEC) and its Building America Partnership for Improved Residential Construction (BA-PIRC), Atlantic Housing Partners (AHP) has implemented a high performance, systems engineered package of measures. This report demonstrates how the initiative achieves Building America (BA) goals of 30%-50% energy savings. Specifically, the goals are documented as being achieved in the new construction multifamily housing sector in the hot humid climate. Results from energy modeling of the high performance package are presented. The role of utility allowance calculations, used as part of the low-income housing tax credit process, to value those energy savings is discussed, as is customer satisfaction with heat pump water heaters.

  15. Efficient Multifamily Homes in a Hot Humid Climate by Atlantic Housing Partners

    SciTech Connect (OSTI)

    Chaser, Dave; Martin, Eric

    2013-04-01

    With assistance from the Florida Solar Energy Center (FSEC) and its Building America Partnership for Improved Residential Construction (BA-PIRC), Atlantic Housing Partners (AHP) has implemented a high performance, systems engineered package of measures. This report demonstrates how the initiative achieves Building America (BA) goals of 30%-50% energy savings. Specifically, the goals are documented as being achieved in the new construction multifamily housing sector in the hot humid climate. Results from energy modeling of the high performance package are presented. The role of utility allowance calculations, used as part of the low-income housing tax credit process, to value those energy savings is discussed, as is customer satisfaction with heat pump water heaters.

  16. Reducing Thermal Losses and Gains With Buried and Encapsulated Ducts in Hot-Humid Climates

    SciTech Connect (OSTI)

    Shapiro, C.; Magee, A.; Zoeller, W.

    2013-02-01

    The Consortium for Advanced Residential Buildings (CARB) monitored three houses in Jacksonville, FL, to investigate the effectiveness of encapsulated and encapsulated/buried ducts in reducing thermal losses and gains from ductwork in unconditioned attics. Burying ductwork beneath loose-fill insulation has been identified as an effective method of reducing thermal losses and gains from ductwork in dry climates, but it is not applicable in humid climates where condensation may occur on the outside of the duct jacket. By encapsulating the ductwork in closed cell polyurethane foam (ccSPF) before burial beneath loose-fill mineral fiber insulation, the condensation potential may be reduced while increasing the R-value of the ductwork.

  17. Impact of Residential Mechanical Ventilation on Energy Cost and Humidity Control

    SciTech Connect (OSTI)

    Martin, E.

    2014-01-01

    The DOE Building America program has been conducting research leading to cost effective high performance homes since the early 1990's. Optimizing whole house mechanical ventilation as part of the program's systems engineered approach to constructing housing has been an important subject of the program's research. Ventilation in residential buildings is one component of an effective, comprehensive strategy for creation and maintenance of a comfortable and healthy indoor air environment. The study described in this white paper is based on building energy modeling with an important focus on the indoor humidity impacts of ventilation. The modeling tools used were EnergyPlus version 7.1 (E+) and EnergyGauge USA (EGUSA). Twelve U.S. cities and five climate zones were represented. A total of 864 simulations (2*2*3*3*12= 864) were run using two building archetypes, two building leakage rates, two building orientations, three ventilation systems, three ventilation rates, and twelve climates.

  18. Impact of Residential Mechanical Ventilation on Energy Cost and Humidity Control

    SciTech Connect (OSTI)

    Martin, Eric

    2014-01-01

    Optimizing whole house mechanical ventilation as part of the Building Ameerica program's systems engineered approach to constructing housing has been an important subject of the program's research. Ventilation in residential buildings is one component of an effective, comprehensive strategy for creation and maintenance of a comfortable and healthy indoor air environment. The study described in this report is based on building energy modeling with an important focus on the indoor humidity impacts of ventilation. The modeling tools used were EnergyPlus version 7.1 (E+) and EnergyGauge USA (EGUSA). Twelve U.S. cities and five climate zones were represented. A total of 864 simulations (2*2*3*3*12= 864) were run using two building archetypes, two building leakage rates, two building orientations, three ventilation systems, three ventilation rates, and twelve climates.

  19. Humidity-resistant ambient-temperature solid-electrolyte amperometric sensing apparatus

    DOE Patents [OSTI]

    Zaromb, S.

    1994-06-21

    Apparatus and methods for detecting selected chemical compounds in air or other gas streams at room or ambient temperature includes a liquid-free humidity-resistant amperometric sensor comprising a sensing electrode and a counter and reference electrode separated by a solid electrolyte. The sensing electrode preferably contains a noble metal, such as Pt black. The electrolyte is water-free, non-hygroscopic, and substantially water-insoluble, and has a room temperature ionic conductivity [>=]10[sup [minus]4] (ohm-cm)[sup [minus]1], and preferably [>=]0.01 (ohm-cm)[sup [minus]1]. The conductivity may be due predominantly to Ag[sup +] ions, as in Ag[sub 2]WO[sub 4], or to F[sup [minus

  20. Performance of Variable Capacity Heat Pumps in a Mixed Humid Climate

    SciTech Connect (OSTI)

    Munk, Jeffrey D; Gehl, Anthony C; Jackson, Roderick K

    2012-04-01

    Variable capacity heat pumps represent the next wave of technology for heat pumps. In this report, the performance of two variable capacity heat pumps (HPs) is compared to that of a single or two stage baseline system. The units were installed in two existing research houses located in Knoxville, TN. These houses were instrumented to collect energy use and temperature data while both the baseline systems and variable capacity systems were installed. The homes had computer controlled simulated occupancy, which provided consistent schedules for hot water use and lighting. The temperature control and energy use of the systems were compared during both the heating and cooling seasons. Multiple linear regression models were used along with TMY3 data for Knoxville, TN in order to normalize the effect that the outdoor air temperature has on energy use. This enables a prediction of each system's energy use over a year with the same weather. The first system was a multi-split system consisting of 8 indoor units and a single outdoor unit. This system replaced a 16 SEER single stage HP with a zoning system, which served as the baseline. Data was collected on the baseline system from August 2009 to December 2010 and on the multi-split system from January 2011 to January 2012. Soon after the installation of the multi-split system, some of the smaller rooms began over-conditioning. This was determined to be caused by a small amount of continuous refrigerant flow to all of the indoor units when the outdoor unit was running regardless of whether they were calling for heat. This, coupled with the fact that the indoor fans run continuously, was providing enough heat in some rooms to exceed the set point. In order to address this, the indoor fans were disabled when not actively heating per the manufacturer's recommendation. Based on the measured data, the multi-split system was predicted to use 40% more energy in the heating season and 16% more energy in the cooling season than the baseline system, for the typical meteorological year weather data. The AHRI ratings indicated that the baseline system would perform slightly better than the multi-split system, but not by as large of a margin as seen in this study. The multi-split system was able to maintain more consistent temperature throughout the house than the baseline system, but it did allow relative humidity levels to increase above 60% in the summer. The second system was a split system with an inverter driven compressor and a single ducted air handler. This unit replaced a 16 SEER two stage HP with a zoning system. Data was collected on the baseline system from July 2009 to November 2010 and on the ducted inverter system from December 2010 to January 2012. The ducted inverter system did not offer a zone controller, so it functioned as a single zone system. Due to this fact, the registers had to be manually adjusted in order to better maintain consistent temperatures between the two levels of the house. The predicted heating season energy use for the ducted inverter system, based on the measured energy use, was 30% less than that of the baseline system for the typical meteorological year. However, the baseline system was unable to operate in its high stage due to a wiring issue with the zone controller. This resulted in additional resistance heat use during the winter and therefore higher energy use than would be expected in a properly performing unit. The AHRI ratings would indicate that the baseline system would use less energy than the ducted inverter system, which is opposite to the results of this study. During the cooling season, the ducted inverter system was predicted to use 23% more energy than the baseline system during the typical meteorological year. This is also opposite of the results expected by comparing the AHRI ratings. After a detailed comparison of the ducted inverter system's power use compared to that of a recently installed identical system at a retro-fit study house, there is concern that the unit is not operating as intended. The power use and cycles indicate t

  1. Pyrrole Hydrogenation over Rh(111) and Pt(111) Single-Crystal Surfaces and Hydrogenation Promotion Mediated by 1-Methylpyrrole: A Kinetic and Sum-Frequency Generation Vibrational Spectroscopy Study

    SciTech Connect (OSTI)

    Kliewer, Christopher J.; Bieri, Marco; Somorjai, Gabor A.

    2008-03-04

    Sum-frequency generation (SFG) surface vibrational spectroscopy and kinetic measurements using gas chromatography have been used to study the adsorption and hydrogenation of pyrrole over both Pt(111) and Rh(111) single-crystal surfaces at Torr pressures (3 Torr pyrrole, 30 Torr H{sub 2}) to form pyrrolidine and the minor product butylamine. Over Pt(111) at 298 K it was found that pyrrole adsorbs in an upright geometry cleaving the N-H bond to bind through the nitrogen evidenced by SFG data. Over Rh(111) at 298 K pyrrole adsorbs in a tilted geometry relative to the surface through the p-aromatic system. A pyrroline surface reaction intermediate, which was not detected in the gas phase, was seen by SFG during the hydrogenation over both surfaces. Significant enhancement of the reaction rate was achieved over both metal surfaces by adsorbing 1-methylpyrrole before reaction. SFG vibrational spectroscopic results indicate that reaction promotion is achieved by weakening the bonding between the N-containing products and the metal surface because of lateral interactions on the surface between 1-methylpyrrole and the reaction species, reducing the desorption energy of the products. It was found that the ring-opening product butylamine was a reaction poison over both surfaces, but this effect can be minimized by treating the catalyst surfaces with 1-methylpyrrole before reaction. The reaction rate was not enhanced with elevated temperatures, and SFG suggests desorption of pyrrole at elevated temperatures.

  2. Solar-Powered, Liquid-Desiccant Air Conditioner for Low-Electricity Humidity Control: Report and Summary Report

    SciTech Connect (OSTI)

    Dean, J.; Kozubal, E.; Herrmann, L.; Miller, J.; Lowenstein, A.; Barker, G.; Slayzak, S.

    2012-11-01

    The primary objective of this project was to demonstrate the capabilities of a new high-performance, liquid-desiccant dedicated outdoor air system (DOAS) to enhance cooling efficiency and comfort in humid climates while substantially reducing electric peak demand at Tyndall Air Force Base (AFB), which is 12 miles east of Panama City, Florida.

  3. Measurements of structural and chemical order in Zr80Pt20 and Zr77Rh23 liquids

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Johnson, M. L.; Blodgett, M. E.; Lokshin, K. A.; Mauro, N. A.; Neuefeind, J.; Pueblo, C.; Quirinale, D. G.; Vogt, A. J.; Egami, T.; Goldman, A. I.; et al

    2016-02-03

    In this study, the short-range order (SRO) and medium-range order of electrostatically levitated Zr80Pt20 and Zr77Rh23 liquids are presented founded on a combination of high-energy x-ray diffraction and time-of-flight neutron diffraction studies. The atomic structures of the Zr80Pt20 liquids were determined as a function of temperature from constrained reverse Monte Carlo simulations using x-ray and elastic neutron scattering measurements and two partial pair-distribution functions obtained from molecular dynamics (MD) simulations.

  4. Energy-Efficient Supermarket Heating, Ventilation, and Air Conditioning in Humid Climates in the United States

    SciTech Connect (OSTI)

    Clark, J.

    2015-03-01

    Supermarkets are energy-intensive buildings that consume the greatest amount of electricity per square foot of building of any building type in the United States and represent 5% of total U.S. commercial building primary energy use (EIA 2005). Refrigeration and heating, ventilation, and air-conditioning (HVAC) systems are responsible for a large proportion of supermarkets’ total energy use. These two systems sometimes work together and sometimes compete, but the performance of one system always affects the performance of the other. To better understand these challenges and opportunities, the Commercial Buildings team at the National Renewable Energy Laboratory investigated several of the most promising strategies for providing energy-efficient HVAC for supermarkets and quantified the resulting energy use and costs using detailed simulations. This research effort was conducted on behalf of the U.S. Department of Energy (DOE) Commercial Building Partnerships (CBP) (Baechler et al. 2012; Parrish et al. 2013; Antonopoulos et al. 2014; Hirsch et al. 2014). The goal of CBP was to reduce energy use in the commercial building sector by creating, testing, and validating design concepts on the pathway to net zero energy commercial buildings. Several CBP partners owned or operated buildings containing supermarkets and were interested in optimizing the energy efficiency of supermarket HVAC systems in hot-humid climates. These partners included Walmart, Target, Whole Foods Market, SUPERVALU, and the Defense Commissary Agency.

  5. Short-Term Test Results: Transitional Housing Energy Efficiency Retrofit in the Hot-Humid Climate

    SciTech Connect (OSTI)

    Sutherland, K.; Martin, E.

    2013-02-01

    This project evaluates the renovation of a 5,800 ft2, multi-use facility located in St. Petersburg, on the west coast of central Florida, in the hot humid climate. An optimal package of retrofit measures was designed to deliver 30-40% annual energy cost savings for this building with annual utility bills exceeding $16,000 and high base load consumption. Researchers projected energy cost savings for potential retrofit measures based on pre-retrofit findings and disaggregated, weather normalized utility bills as a basis for simulation true-up. A cost-benefit analysis was conducted for the seven retrofit measures implemented; adding attic insulation and sealing soffits, tinting windows, improving whole building air-tightness, upgrading heating and cooling systems and retrofitting the air distribution system, replacing water heating systems, retrofitting lighting, and replacing laundry equipment. The projected energy cost savings for the full retrofit package based on a post-retrofit audit is 35%. The building's architectural characteristics, vintage, and residential and commercial uses presented challenges for both economic projections and retrofit measure construction.

  6. Short-Term Test Results. Transitional Housing Energy Efficiency Retrofit in the Hot Humid Climate

    SciTech Connect (OSTI)

    Sutherland, K.

    2013-02-01

    This project evaluates the renovation of a 5,800 ft2, multi-use facility located in St. Petersburg, on the west coast of central Florida, in the hot humid climate. An optimal package of retrofit measures was designed to deliver 30%-40% annual energy cost savings for this building with annual utility bills exceeding $16,000 and high base load consumption. Researchers projected energy cost savings for potential retrofit measures based on pre-retrofit findings and disaggregated, weather normalized utility bills as a basis for simulation true-up. A cost-benefit analysis was conducted for the seven retrofit measures implemented; adding attic insulation and sealing soffits, tinting windows, improving whole building air-tightness, upgrading heating and cooling systems and retrofitting the air distribution system, replacing water heating systems, retrofitting lighting, and replacing laundry equipment. The projected energy cost savings for the full retrofit package based on a post-retrofit audit is 35%. The building's architectural characteristics, vintage, and residential and commercial uses presented challenges for both economic projections and retrofit measure construction.

  7. Perovskite LaRhO{sub 3} as a p-type active layer in oxide photovoltaics

    SciTech Connect (OSTI)

    Nakamura, Masao Krockenberger, Yoshiharu; Fujioka, Jun; Kawasaki, Masashi; Tokura, Yoshinori

    2015-02-16

    Perovskite-type transition-metal oxides have a wide variety of physical properties and triggered intensive research on functional devices in the form of heteroepitaxial junctions. However, there is a missing component that is a p-type conventional band semiconductor. LaRhO{sub 3} (LRO) is one of very few promising candidates having its bandgap between filled t{sub 2g} and empty e{sub g} of Rh in low-spin state, but there has been no report on the synthesis of large-size single crystals or thin films. Here, we report on the junction properties of single-crystalline thin films of LRO grown on (110) oriented Nb-doped SrTiO{sub 3} substrates. The external quantum efficiency of the photo-electron conversion exceeds 1% in the visible-light region due to the wide depletion layer and long diffusion length of minority carriers in LRO. Clear indication of p-type band semiconducting character in a perovskite oxide of LRO will pave a way to explore oxide electronics of perovskite heterostructures.

  8. A RhxSy/C Catalyst for the Hydrogen Oxidation and Hydrogen Evolution Reactions in HBr

    SciTech Connect (OSTI)

    Masud, Jahangir; Nguyena, Trung V.; Singh, Nirala; McFarland, Eric; Ikenberry, Myles; Hohn, Keith; Pan, Chun-Jern; Hwang, Bing-Joe

    2015-01-01

    Rhodium sulfide (Rh2S3) on carbon support was synthesized by refluxing rhodium chloride with ammonium thiosulfate. Thermal treatment of Rh2S3 at high temperatures (600C to 850C) in presence of argon resulted in the transformation of Rh2S3 into Rh3S4, Rh17S15 and Rh which were characterized by TGA/DTA, XRD, EDX, and deconvolved XPS analyses. The catalyst particle size distribution ranged from 3 to 12 nm. Cyclic voltammetry and rotating disk electrode measurements were used to evaluate the catalytic activity for hydrogen oxidation and evolution reactions in H2SO4 and HBr solutions. The thermally treated catalysts show high activity for the hydrogen reactions. The exchange current densities (io) of the synthesized RhxSy catalysts in H2-saturated 1M H2SO4 and 1M HBr for HER and HOR were 0.9 mA/cm2 to 1.0 mA/cm2 and 0.8 to 0.9 mA/cm2, respectively. The lower io values obtained in 1M HBr solution compared to in H2SO4 might be due to the adsorption of Br- on the active surface. Stable electrochemical active surface area (ECSA) of RhxSy catalyst was obtained for CV scan limits between 0 V and 0.65 V vs. RHE. Scans with upper voltage limit beyond 0.65 V led to decreased and unreproducible ECSA measurements.

  9. Temperature, humidity and air flow in the emplacement drifts using convection and dispersion transport models

    SciTech Connect (OSTI)

    Danko, G.; Birkholzer, J.T.; Bahrami, D.; Halecky, N.

    2009-10-01

    A coupled thermal-hydrologic-airflow model is developed, solving for the transport processes within a waste emplacement drift and the surrounding rockmass together at the proposed nuclear waste repository at Yucca Mountain. Natural, convective air flow as well as heat and mass transport in a representative emplacement drift during post-closure are explicitly simulated, using the MULTIFLUX model. The conjugate, thermal-hydrologic transport processes in the rockmass are solved with the TOUGH2 porous-media simulator in a coupled way to the in-drift processes. The new simulation results show that large-eddy turbulent flow, as opposed to small-eddy flow, dominate the drift air space for at least 5000 years following waste emplacement. The size of the largest, longitudinal eddy is equal to half of the drift length, providing a strong axial heat and moisture transport mechanism from the hot to the cold drift sections. The in-drift results are compared to those from simplified models using a surrogate, dispersive model with an equivalent dispersion coefficient for heat and moisture transport. Results from the explicit, convective velocity simulation model provide higher axial heat and moisture fluxes than those estimated from the previously published, simpler, equivalent-dispersion models, in addition to showing differences in temperature, humidity and condensation rate distributions along the drift length. A new dispersive model is also formulated, giving a time- and location-variable function that runs generally about ten times higher in value than the highest dispersion coefficient currently used in the Yucca Mountain Project as an estimate for the equivalent dispersion coefficient in the emplacement drift. The new dispersion coefficient variation, back-calculated from the convective model, can adequately describe the heat and mass transport processes in the emplacement drift example.

  10. Leucaena and tall grasses as energy crops in humid lower south USA

    SciTech Connect (OSTI)

    Prine, G.M.; Woodard, K.R.; Cunilio, T.V.

    1994-12-31

    The tropical leguminous shrub/tree, leucaena (Leucaena spp. mainly leucocephala), and perennial tropical tall grasses such as elephantgrass (Pennisetum purpureum), sugarcane, and energycane (Saccharum spp.) are well adapted to the long growing seasons and high rainfall of the humid lower South. In much of the area the topgrowth is killed by frost during winter and plants regenerate from underground parts in spring. Selected accessions from a duplicated 373 accession leucaena nursery had an average annual woody stem dry matter production of 31.4 Mg ha{sup -1}. Average oven dry stem wood yields from selected accessions adjusted for environmental enrichment over the 4 growth seasons were 78.9 Mg ha{sup -1} total and average annual yield of 19.7 Mg ha{sup -1}. The tall perennial grasses have linear growth rates of 18 to 27 g m{sup 2}d{sup -1} for long periods (140 to 196 d and sometimes longer) each season. Oven dry biomass yields of tall grasses have varied from 20 to 45 Mg ha{sup -1} in mild temperature locations to over 60 Mg ha{sup -1} yr{sup -1} in warm subtropics of the lower Florida peninsula. Tall grasses and leucaena, once established, may persist for many seasons. A map showing the possible range of the crops in lower South is shown. Highest biomass yields of tall grasses have been produced when irrigated with sewage effluent or when grown on phosphatic clay and muck soils of south Florida. Several companies are considering using leucaena and/or tall grasses for bioenergy in the phosphatic mining area of Polk County, Florida.

  11. Evaluation of the Performance of Houses With and Without Supplemental Dehumidification in a Hot-Humid Climate

    SciTech Connect (OSTI)

    Kerrigan, P.

    2014-10-01

    This report describes a research study that was conducted by the Building Science Corporation (BSC) Building America Research Team. BSC seeks to research and report on the field monitoring of the performance of in-situ supplemental dehumidification systems in low energy, high performance homes in a hot-humid climate. The purpose of this research project was to observe and compare the humidity control performance. Specifically, the study sought to compare the interior conditions and mechanical systems operation between two distinct groups of houses; homes with a supplemental dehumidifier installed in addition to HVAC system, and homes without any supplemental dehumidification. The subjects of the study were 10 single-family, new construction homes in New Orleans, LA.

  12. Microwave-assisted synthesis and humidity sensing of nanostructured {alpha}-Fe{sub 2}O{sub 3}

    SciTech Connect (OSTI)

    Deshmukh, Rupali G.; Badadhe, Satish S.; Mulla, Imtiaz S.

    2009-05-06

    Nanocrystalline {alpha}-Fe{sub 2}O{sub 3} has been prepared on a large-scale by a facile microwave-assisted hydrothermal route from a solution of Fe(NO{sub 3}){sub 3}.9H{sub 2}O and pentaerythritol. A systematic study of the morphology, crystallinity and oxidation state of Fe using different characterization techniques, such as transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy was performed. It reveals that nanostructured {alpha}-Fe{sub 2}O{sub 3} comprises bundles of nanorods with a rhombohedral crystalline structure. The individual nanorod has 8-10 nm diameter and {approx}50 nm length. The as-prepared nanostructured {alpha}-Fe{sub 2}O{sub 3} (sensor) gives selective response towards humidity. The sensor shows high sensitivity, fast linear response to change in the humidity with almost 100% reproducibility. The sensor works at room temperature and rejuvenates without heat treatment. The as-prepared nanostructured {alpha}-Fe{sub 2}O{sub 3} appears to be a promising humidity sensing material with the potential for commercialization.

  13. Effect of magnetic fields on the Kondo insulator CeRhSb: Magnetoresistance and high-field heat capacity measurements

    SciTech Connect (OSTI)

    Malik, S.K.; Menon, L.; Pecharsky, V.K.; Gschneidner, K.A. Jr.

    1997-05-01

    The compound CeRhSb is a mixed valent Ce-based compound which shows a gap in the electronic density of states at low temperatures. The gap manifests by a rise in electrical resistivity{emdash}below about 8 K from which the gap energy is estimated to be about 4 K. We have carried out heat capacity measurements on this compound in various applied fields up to 9.85 T. The magnetic contribution to the heat capacity, {Delta}C, is found to have a maximum in {Delta}C/T vs T at 10 K, below which {Delta}C/T is linear with T. This is attributed to the fact that below this temperature, in the gapped state, the electronic density of states decreases linearly with decreasing temperature. On application of a magnetic field, the electronic specific heat coefficient {gamma} in the gapped state increases by {approximately}4mJ/molK{sup 2}. The maximum in {Delta}C/T vs T is observed in all fields, which shifts to lower temperatures {approximately}1K at 5.32 T and raises again at 9.85 T to about the same values as at H=0T. This suggests that the gap exists for all fields up to 9.85 T. Above 10 K, in the mixed-valent state, {Delta}C/T vs T decreases with increasing temperature in zero field. There is hardly any effect of application of field in the mixed-valent state. We have also carried out magnetoresistance measurements on CeRhSb up to fields of 5.5 T at 2, 4.5, 10, 20, and 30 K. The magnetoresistance in CeRhSb is positive at temperatures of 4.5 K and above, in applied fields up to 5.5 T. At 5.5 T, the magnetoresistance is maximum at 4.5 K (6{percent}) and decreases with increasing temperature. The observation of the maximum is consistent with the observation of a maximum in {Delta}C/T vs T and is due to a change in the density of states. At a temperature of 2 K, a negative magnetoresistance is observed for magnetic fields greater than {approximately}3.5T which suggests reduction in the gap. {copyright} {ital 1997} {ital The American Physical Society}

  14. Systematics of the temperature-dependent interplane resistivity in Ba(Fe1-xMx)₂As₂ (M=Co, Rh, Ni, and Pd)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tanatar, M. A.; Ni, N.; Thaler, A.; Bud’ko, S. L.; Canfield, P. C.; Prozorov, R.

    2011-07-27

    Temperature-dependent interplane resistivity ρc(T) was measured systematically as a function of transition-metal substitution in the iron-arsenide superconductors Ba(Fe1-xMx)₂As₂, M=Ni, Pd, Rh. The data are compared with the behavior found in Ba(Fe1-xCox)₂As₂, revealing resistive signatures of pseudogap. In all compounds we find resistivity crossover at a characteristic pseudogap temperature T* from nonmetallic to metallic temperature dependence on cooling. Suppression of T* proceeds very similarly in cases of Ni and Pd doping and much faster than in similar cases of Co and Rh doping. In cases of Co and Rh doping an additional minimum in the temperature-dependent ρc emerges for high dopings,more » when superconductivity is completely suppressed. These features are consistent with the existence of a charge gap covering part of the Fermi surface. The part of the Fermi surface affected by this gap is notably larger for Ni- and Pd-doped compositions than in Co- and Rh-doped compounds.« less

  15. Tuning the Curie temperature of L1{sub 0} ordered FePt thin films through site-specific substitution of Rh

    SciTech Connect (OSTI)

    Xu, Dongbin; Sun, Cheng-Jun E-mail: msecgm@nus.edu.sg; Heald, Steve M.; Chen, Jing-Sheng; Chow, Gan Moog E-mail: msecgm@nus.edu.sg; Zhou, Tie-Jun; Bergman, Anders; Sanyal, Biplab

    2014-10-14

    In structurally ordered magnetic thin films, the Curie temperature (T{sub C}) of ferromagnetic films depends on the exchange integral of the short range ordered neighboring atoms. The exchange integral may be adjusted by controlling the elemental substitutional concentration at the lattice site of interest. We show how to control the T{sub C} in high anisotropy L1{sub 0} Fe{sub 50}Pt{sub 50} magnetic thin films by substituting Rh into the Pt site. Rh substitution in L1{sub 0} FePt modified the local atomic environment and the corresponding electronic properties, while retaining the ordered L1{sub 0} phase. The analysis of extended x-ray Absorption Fine Structure spectra shows that Rh uniformly substitutes for Pt in L1{sub 0} FePt. A model of antiferromagnetic defects caused by controlled Rh substitution of the Pt site, reducing the T{sub C,} is proposed to interpret this phenomenon and its validity is further examined by ab initio density functional calculations.

  16. Building America Residential System Research Results: Achieving 30% Whole House Energy Savings Level in Mixed-Humid Climates; January 2006 - December 2006

    SciTech Connect (OSTI)

    Anderson, R.; Hendron, R.; Eastment, M.; Jalalzadeh-Azar, A.

    2006-12-01

    This report summarizes research results for the 30% energy savings level and demonstrates that lead builders can successfully provide 30% homes in the Mixed-Humid Climate Region on a cost-neutral basis.

  17. Building America Best Practices Series: Volume 4; Builders and Buyers Handbook for Improving New Home Efficiency, Comfort, and Durability in the Mixed-Humid Climate

    SciTech Connect (OSTI)

    2005-09-01

    This guide book is a resource to help builders large and small build high-quality, energy-efficient homes that achieve 30% energy savings in space conditioning and water heating in the mixed-humid climate region.

  18. Building America Case Study: Evaluation of the Performance of Houses With and Without Supplemental Dehumidification in a Hot-Humid Climate, New Orleans, Louisiana (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-11-01

    This report, Evaluation of the Performance of Houses with and without Supplemental Dehumidification in a Hot-Humid Climate, describes a research study that that was conducted by the Building Science Corporation (BSC) Building America Research Team. BSC seeks to research and report on the field monitoring of the performance of in-situ supplemental dehumidification systems in low energy, high performance, homes in a Hot-Humid climate. The purpose of this research project was to observe and compare the humidity control performance of new, single family, low energy, and high performance, homes. Specifically, the study sought to compare the interior conditions and mechanical systems operation between two distinct groups of houses, homes with a supplemental dehumidifier installed in addition to HVAC system, and homes without any supplemental dehumidification. The subjects of the study were ten single-family new construction homes in New Orleans, LA. Data logging equipment was installed at each home in 2012. Interior conditions and various end-use loads were monitored for one year. In terms of averages, the homes with dehumidifiers are limiting elevated levels of humidity in the living space. However, there was significant variation in humidity control between individual houses. An analysis of the equipment operation did not show a clear correlation between energy use and humidity levels. In general, no single explanatory variable appears to provide a consistent understanding of the humidity control in each house. Indoor humidity is likely due to all of the factors we have examined, and the specifics of how they are used by each occupant.

  19. Cell death mechanisms in GT1-7 GnRH cells exposed to polychlorinated biphenyls PCB74, PCB118, and PCB153

    SciTech Connect (OSTI)

    Dickerson, Sarah M.; Guevara, Esperanza; Woller, Michael J.; Gore, Andrea C.

    2009-06-01

    Exposure to endocrine disrupting chemicals (EDCs) such as polychlorinated biphenyls (PCBs) causes functional deficits in neuroendocrine systems. We used an immortalized hypothalamic GT1-7 cell line, which synthesizes the neuroendocrine peptide gonadotropin-releasing hormone (GnRH), to examine the neurotoxic and endocrine disrupting effects of PCBs and their mechanisms of action. Cells were treated for 1, 4, 8, or 24 h with a range of doses of a representative PCB from each of three classes: coplanar (2,4,4',5-tetrachlorobiphenyl: PCB74), dioxin-like coplanar (2',3,4,4',5' pentachlorobiphenyl: PCB118), non-coplanar (2,2',4,4',5,5'-hexachlorobiphenyl: PCB153), or their combination. GnRH peptide concentrations, cell viability, apoptotic and necrotic cell death, and caspase activation were quantified. In general, GnRH peptide levels were suppressed by high doses and longer durations of PCBs, and elevated at low doses and shorter timepoints. The suppression of GnRH peptide levels was partially reversed in cultures co-treated with the estrogen receptor antagonist ICI 182,780. All PCBs reduced viability and increased both apoptotic and necrotic cell death. Although the effects for the three classes of PCBs were often similar, subtle differences in responses, together with evidence that the combination of PCBs acted slightly different from individual PCBs, suggest that the three tested PCB compounds may act via slightly different or more than one mechanism. These results provide evidence that PCB congeners have endocrine disrupting and/or neurotoxic effects on the hypothalamic GnRH cell line, a finding that has implications for environmental endocrine disruption in animals.

  20. Technology Solutions Case Study: Evaluation of the Performance of Houses With and Without Supplemental Dehumidification in a Hot-Humid Climate, New Orleans, Louisiana

    SciTech Connect (OSTI)

    2014-11-01

    The purpose of this project by Building Science Corporation was to evaluate the humidity control performance of new single family high performance homes, and compare the interior conditions and mechanical systems operation between two distinct groups of houses: homes with a supplemental dehumidifier installed in addition to HVAC system, and homes without any supplemental dehumidification. The subjects of the study were 10 single-family new construction homes in New Orleans, LA. Data logging equipment was installed at each home in 2012, and interior conditions and various end-use loads were monitored for one year. In terms of averages, the homes with dehumidifiers are limiting elevated levels of humidity in the living space; however, there was significant variation in humidity control between individual houses. An analysis of the equipment operation did not show a clear correlation between energy use and humidity levels. In general, no single explanatory variable appears to provide a consistent understanding of the humidity control in each house. Indoor humidity is likely due to all of the factors we have examined, and the specifics of how they are used by each occupant.

  1. Synthesis, structural and magnetic studies of the CuCr{sub 1-x}Rh{sub x}O{sub 2} delafossite solid solution with 0 {<=} x {<=} 0.2

    SciTech Connect (OSTI)

    Amami, M.; Jlaiel, F.; Strobel, P.; Ben Salah, A.

    2011-10-15

    Highlights: {yields} Rh non-magnetic replacement of the Cr in the magnetic frustrated delafossite CuCrO{sub 2}. {yields} Delafossite solid solution is maintained up to 0.2 in this system. {yields} Strain generated by Rh substitution is strongly anisotropic. {yields} M{sup 3+}-O bond strength is affected. {yields} High temperature paramagnetic behavior and weak ferromagnetism at low temperature. -- Abstract: The CuCr{sub 1-x}Rh{sub x}O{sub 2} series is investigated by X-ray diffraction, magnetization measurements and Raman spectroscopy on ceramic samples. It is found that a delafossite solid solution is maintained up to x = 0.2 in CuCr{sub 1-x}Rh{sub x}O{sub 2}. The small observed variation in cell parameters is consistent with the small difference between the ionic radii of Cr{sup 3+} and Rh{sup 3+}. A significant broadening of X-ray reflections is observed and when analyzed using the Williamson-Hall relationship showed that the strain generated by Rh substitution is strongly anisotropic, affecting mainly (Cr,Rh)-O bonds in the ab plane. Room temperature Raman spectra displayed three main Raman active modes. All modes shift to lower frequency and undergo significant changes in intensity with increasing Rh content, showing the effect of Rh atoms on the M{sup 3+}-O bond strength. The magnetic behavior of CuCr{sub 1-x}Rh{sub x}O{sub 2} samples was investigated as a function of temperature and applied field. At high temperature paramagnetic behavior, and at low temperature, evidence for weak ferromagnetism, reinforced by a hysteresis loop at 4 K is observed. The magnetic behavior of CuCr{sub 1-x}Rh{sub x}O{sub 2} is attributed to the disorder of Cr and Rh in octahedral sites resulting in short-range Cr-O-Cr and Cr-O-Rh interactions, which give rise to short-range weak ferromagnetism.

  2. Large fluxes and rapid turnover of mineral-associated carbon across topographic gradients in a humid tropical forest: insights from paired 14C analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hall, S. J.; McNicol, G.; Natake, T.; Silver, W. L.

    2015-04-29

    It has been proposed that the large soil carbon (C) stocks of humid tropical forests result predominantly from C stabilization by reactive minerals, whereas oxygen (O2) limitation of decomposition has received much less attention. We examined the importance of these factors in explaining patterns of C stocks and turnover in the Luquillo Experimental Forest, Puerto Rico, using radiocarbon (14C) measurements of contemporary and archived samples. Samples from ridge, slope, and valley positions spanned three soil orders (Ultisol, Oxisol, Inceptisol) representative of humid tropical forests, and differed in texture, reactive metal content, O2 availability, and root biomass. Mineral-associated C comprised themore » large majority (87 ± 2%, n = 30) of total soil C. Turnover of most mineral-associated C (66 ± 2%) was rapid (11 to 26 years; mean and SE: 18 ± 3 years) in 25 of 30 soil samples across surface horizons (0–10 and 10–20 cm depths) and all topographic positions, independent of variation in reactive metal concentrations and clay content. Passive C with centennial–millennial turnover was typically much less abundant (34 ± 3%), even at 10–20 cm depths. Carbon turnover times and concentrations significantly increased with concentrations of reduced iron (Fe(II)) across all samples, suggesting that O2 availability may have limited the decomposition of mineral-associated C over decadal scales. Steady-state inputs of mineral-associated C were statistically similar among the three topographic positions, and could represent 10–25% of annual litter production. Observed trends in mineral-associated Δ14C over time could not be fit using the single-pool model used in many other studies, which generated contradictory relationships between turnover and Δ14C as compared with a more realistic two-pool model. The large C fluxes in surface and near-surface soils documented here are supported by findings from paired 14C studies in other types of ecosystems, and suggest that most mineral-associated C cycles relatively rapidly (decadal scales) across ecosystems that span a broad range of state factors.« less

  3. Building a 40% Energy Saving House in the Mixed-Humid Climate

    SciTech Connect (OSTI)

    Christian, Jeffrey E; Bonar, Jacob

    2011-10-01

    This report describes a home that uses 40% less energy than the energy-efficient Building America standard - a giant step in the pursuit of affordable near-zero-energy housing through the evolution of five near-zero-energy research houses. This four-bedroom, two-bath, 1232-ft2 house has a Home Energy Rating System (HERS) index of 35 (a HERS rating of 0 is a zero-energy house, a conventional new house would have a HERS rating of 100), which qualifies it for federal energy efficiency and solar incentives. The house is leading to the planned construction of a similar home in Greensburg, Kansas, and 21 staff houses in the Walden Reserve, a 7000-unit "deep green" community in Cookville, Tennessee. Discussions are underway for construction of similar houses in Charleston, South Carolina, Seattle, Washington, Knoxville and Oak Ridge, Tennessee, and upstate New York. This house should lead to a 40% and 50% Gate-3, Mixed-Humid-Climate Joule for the DOE Building America Program. The house is constructed with structurally-insulated-panel walls and roof, raised metal-seam roof with infrared reflective coating, airtight envelope (1.65 air changes per hour at 50 Pascal), supply mechanical ventilation, ducts inside the conditioned space, extensive moisture control package, foundation geothermal space heating and cooling system, ZEHcor wall, solar water heater, and a 2.2 kWp grid-connected photovoltaic (PV) system. The detailed specifications for the envelope and the equipment used in ZEH5 compared to all the houses in this series are shown in Tables 1 and 2. Based on a validated computer simulation of ZEH5 with typical occupancy patterns and energy services for four occupants, energy for this all-electric house is predicted to cost only $0.66/day ($0.86/day counting the hookup charges). By contrast, the benchmark house would require $3.56/day, including hookup charges (these costs are based on a 2006 residential rates of $0.07/kWh and solar buyback at $0.15/kWh). The solar fraction for this home located in Lenoir City, Tennessee, is predicted to be as high as 41%(accounting for both solar PV and the solar water heater). This all-electric home is predicted to use 25 kWh/day based on the one year of measured data used to calibrate a whole-building simulation model. Based on two years of measured data, the roof-mounted 2.2 kWp PV system is predicted to generate 7.5 kWh/day. The 2005 cost to commercially construct ZEH5, including builder profit and overhead, is estimated at about $150,000. This cost - for ZEH5's panelized construction, premanufactured utility wall (ZEHcor), foundation geothermal system, and the addition of the walkout lower level, and considering the falling cost for PV - suggests that the construction cost per ft2 for a ZEH5 two-story will be even more cost-competitive. The 2005 construction cost estimate for a finished-out ZEH5 with 2632 ft2 is $222,000 or $85/ft2. The intention of this report is to help builders and homeowners make the decision to build zero-energy-ready homes. Detailed drawings, specifications, and lessons learned in the construction and analysis of data from about 100 sensors monitoring thermal performance for a one-year period are presented. This information should be specifically useful to those considering structural insulated panel walls and roof, foundation geothermal space heating and cooling, solar water heater and roof-mounted, photovoltaic, grid-tied systems.

  4. Apparatus for adjusting and maintaining the humidity of gas at a constant value within a closed system

    DOE Patents [OSTI]

    Abernathy, B.R.; Walters, R.R.

    1985-08-05

    The humidity of a gas within a closed system is maintained at constant level by providing a saturated salt solution within a lower chamber in communication with an upper chamber conjointly defined by upper and lower container sections in sealing contact with each other to establish a closed container. A partition wall separates the salt solution from the test region in the upper chamber. A tube extending through the partition plate allows humidified gas to pass from the lower to the upper chamber. A glass wool plug or membranous material within the tube prevents migration of salt into the test region.

  5. Apparatus for adjusting and maintaining the humidity of gas at a constant value within a closed system

    DOE Patents [OSTI]

    Abernathy, Bethel R.; Walters, Ronald R.

    1986-01-01

    The humidity of a gas within a closed system is maintained at constant level by providing a saturated salt solution within a lower chamber in communication with an upper chamber conjointly defined by upper and lower container sections in sealing contact with each other to establish a closed container. A partition wall separates the salt solution from the test region in the upper chamber. A tube extending through the partition plate allows humidified gas to pass from the lower to the upper chamber. A glass wool plug or membranous material within the tube prevents migration of salt into the test region.

  6. Optimization of preparation of Rh-105 labeled (B72.3) MOAB using an amine oxime ligand and comparison of its biodistribution with I-131 labeled B72.3 MOAB

    SciTech Connect (OSTI)

    Venkatesh, M.; Kilcoin, T.T.; Schlemper, E.O.

    1994-05-01

    Propyleneamineoxime ligands with the four N donor atoms form stable complexes with Rh(III). The p-aminobenzylpropyleneamineoxime ligand (L) was made to act as a bifunctional chelating agent to label proteins with Rh-105. This study encompasses the optimization of formation of the Rh-105 complex of L, its purification, activation with thiophosgene, conjugation the B72.3 MOAB, purification by gel filtration, determination of its stability in physiological buffers and in human serum and comparison of the biodistribution Rh-105 labeled antibody with I-131 labeled antibody in normal healthy mice. Rh-105 was complexed with the ligand L by refluxing at pH 5-6 for 45 min. CuCl, was added to form a charged complex and the neutral activated Rh-105 complex extracted into chloroform. Following evaporation of CHC1{sub 3}, the complex was dissolved in 20 {mu}1 of DMF and reconstituted with 0.5 ml of saline. This was then reacted with the B72.3 MOAB in 0.05 M bicarbonate buffer at pH 9 and incubated for 3 h at 37{degrees}C. The complexation yields were generally 95% and the conjugation yields {approximately}60%. The Rh-105 conjugate was stable at room temperature in phosphate buffer saline (pH 7.4), bicarbonate buffer saline (pH 8.5) and human serum at 37{degrees}C for 4 days. >95% of the conjugate remained immunoreactive using mucin-bound to sepharose as the antigen. I-131 labeled antibody was prepared by using iodogen as the oxidizing agent. The two labeled antibodies were co-injected into healthy mice and the biodistribution studied at different time intervals. The biodistribution studies show good correlation between I-131 and Rh-105 labeled B72.3 MOAB preparations over 20 h demonstrating good in vivo stability. This ligand may be useful as a bifunctional chelating agent for Rh-105 labeled antibody.

  7. Kinetic and Performance Studies of the Regeneration Phase of Model Pt/Ba/Rh NOx Traps for Design and Optimization

    SciTech Connect (OSTI)

    Michael Harold; Vemuri Balakotaiah

    2010-05-31

    In this project a combined experimental and theoretical approach was taken to advance our understanding of lean NOx trap (LNT) technology. Fundamental kinetics studies were carried out of model LNT catalysts containing variable loadings of precious metals (Pt, Rh), and storage components (BaO, CeO{sub 2}). The Temporal Analysis of Products (TAP) reactor provided transient data under well-characterized conditions for both powder and monolith catalysts, enabling the identification of key reaction pathways and estimation of the corresponding kinetic parameters. The performance of model NOx storage and reduction (NSR) monolith catalysts were evaluated in a bench scale NOx trap using synthetic exhaust, with attention placed on the effect of the pulse timing and composition on the instantaneous and cycle-averaged product distributions. From these experiments we formulated a global model that predicts the main spatio-temporal features of the LNT and a mechanistic-based microkinetic models that incorporates a detailed understanding of the chemistry and predicts more detailed selectivity features of the LNT. The NOx trap models were used to determine its ability to simulate bench-scale data and ultimately to evaluate alternative LNT designs and operating strategies. The four-year project led to the training of several doctoral students and the dissemination of the findings as 47 presentations in conferences, catalysis societies, and academic departments as well 23 manuscripts in peer-reviewed journals. A condensed review of NOx storage and reduction was published in an encyclopedia of technology.

  8. Quality Controlled Radiosonde Profile from MC3E

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Toto, Tami; Jensen, Michael

    2014-11-13

    The sonde-adjust VAP produces data that corrects documented biases in radiosonde humidity measurements. Unique fields contained within this datastream include smoothed original relative humidity, dry bias corrected relative humidity, and final corrected relative humidity. The smoothed RH field refines the relative humidity from integers - the resolution of the instrument - to fractions of a percent. This profile is then used to calculate the dry bias corrected field. The final correction fixes a time-lag problem and uses the dry-bias field as input into the algorithm. In addition to dry bias, solar heating is another correction that is encompassed in the final corrected relative humidity field. Additional corrections were made to soundings at the extended facility sites (S0*) as necessary: Corrected erroneous surface elevation (and up through rest of height of sounding), for S03, S04 and S05. Corrected erroneous surface pressure at Chanute (S02).

  9. Magnetic structure of the antiferromagnetic Kondo lattice compounds CeRhAl4Si2 and CeIrAl4Si2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ghimire, N. J.; Calder, S.; Janoschek, M.; Bauer, E. D.

    2015-06-01

    In this article, we have investigated the magnetic ground state of the antiferromagnetic Kondo-lattice compounds CeMAl4Si2(M = Rh, Ir) using neutron powder diffraction. Although both of these compounds show two magnetic transitions TN1 and TN2 in the bulk properties measurements, evidence for magnetic long-range order was only found below the lower transition TN2. Analysis of the diffraction profiles reveals a commensurate antiferromagnetic structure with a propagation vector k = (0, 0, 1/2). The magnetic moment in the ordered state of CeRhAl4Si2 and CeIrAl4Si2 were determined to be 1.14(2) and 1.41(3) μB/Ce, respectively, and are parallel to the crystallographic c-axis inmore » agreement with magnetic susceptibility measurements.« less

  10. Structure symmetry determination and magnetic evolution in Sr2Ir1–xRhxO4

    SciTech Connect (OSTI)

    Ye, Feng; Wang, Xiaoping; Hoffmann, Christina; Wang, Jinchen; Chi, Songxue; Matsuda, Masaaki; Chakoumakos, Bryan C.; Fernandez-Baca, Jaime A.; Cao, Gang

    2015-11-23

    We use single-crystal neutron diffraction to determine the crystal structure symmetry and to study the magnetic evolution in the rhodium doped iridates Sr2Ir1–xRhxO4 (0 ≤ x ≤ 0.16). Throughout this doping range, the crystal structure retains a tetragonal symmetry (space group I41/a) with two distinct magnetic Ir sites in the unit cell forming staggered IrO6 rotation. Upon Rh doping, the magnetic order is suppressed and the magnetic moment of Ir4+ is reduced from 0.21 μB/Ir for x = 0 to 0.18 μB/Ir for x = 0.12. As a result, the magnetic structure at x = 0.12 is different from that of the parent compound while the moments remain in the basal plane.

  11. Asymmetric “melting” and “freezing” kinetics of the magnetostructural phase transition in B2-ordered FeRh epilayers

    SciTech Connect (OSTI)

    Vries, M. A. de; Loving, M.; Lewis, L. H.; McLaren, M.; Brydson, R. M. D.; Liu, X.; Langridge, S.; Marrows, C. H.

    2014-06-09

    Synchrotron X-ray diffraction was used to study the phase transformation processes during the magnetostructural transition in a B2-ordered FeRh (001)-oriented epilayer grown on MgO by sputtering. Out-of-plane lattice constant measurements within the hysteretic regime of the transition reveal a microstructure consistent with the coexistence of lattice-expanded and contracted phases in spatially distinct regions. It was found that the phase separation is more pronounced during cooling than heating. Furthermore, whilst lattice-expanded domains that span the height of the film can be undercooled by several kelvins, there is no equivalent superheating. This asymmetry between the cooling and heating processes in FeRh is consistent with the difference in the kinetics of generic freezing and melting transitions.

  12. Influence of the hydration by the environmental humidity on the metallic speciation and the photocatalytic activity of Cr/MCM-41

    SciTech Connect (OSTI)

    Elías, Verónica R.; Sabre, Ema V.; Winkler, Elin L.; Andrini, Leandro; Requejo, Félix G.; Casuscelli, Sandra G.; Eimer, Griselda A.

    2014-05-01

    The influence of the environmental humidity on the Cr species deposited on inorganic supports like MCM-41 silicates was analyzed by UV–vis Diffuse Reflectance (UV–vis RD), Electronic Spin Resonance (ESR) and X-ray near-edge (XANES) spectroscopy. Metal speciation could be inferred, finding that prolonged exposure periods under environmental humidity provoked the reduction of the active Cr{sup 6+} species and thus, the decrease of the Cr/MCM-41 photoactivity. After the Ti loading over the Cr modified samples, Cr species and the photoactivity were not notably influenced by the humidity exposure. Thus, it could be concluded that the presence of Ti is important because the TiO{sub 2} cover protects the oxidized Cr species, stabilizing them. - Graphical abstract: The load of Ti on the Cr modified MCM-41 produces a TiO{sub 2} cover that protects the active Cr species from their reduction by the environmental humidity. - Highlights: • Spectroscopic analysis shows presence of Cr{sup 6+}/Cr{sup 5+} in calcined/re-calcined samples. • Cr{sup 3+} species increase for hydrated samples causing their photoactivity decrease. • Samples with high Cr loadings are more sensitive to environmental humidity presence. • TiO{sub 2} cover protects oxidized Cr species from their reduction by the water. • Ti is important to allow a synergistic effect and to stabilize active Cr{sup 6+}/Cr{sup 5+}.

  13. Wiedemann-Franz law and nonvanishing temperature scale across the field-tuned quantum critical point of YbRh2Si2

    SciTech Connect (OSTI)

    Reid, J.-Ph.; Tanatar, Makariy; Daou, R.; Hu, Rongwei; Petrovic, C.; Taillefer, Louis

    2014-01-23

    The in-plane thermal conductivity kappa and electrical resistivity rho of the heavy-fermion metal YbRh2Si2 were measured down to 50 mK for magnetic fields H parallel and perpendicular to the tetragonal c axis, through the field-tuned quantum critical point H-c, at which antiferromagnetic order ends. The thermal and electrical resistivities, w L0T/kappa and rho, show a linear temperature dependence below 1 K, typical of the non-Fermi-liquid behavior found near antiferromagnetic quantum critical points, but this dependence does not persist down to T = 0. Below a characteristic temperature T-star similar or equal to 0.35 K, which depends weakly on H, w(T) and rho(T) both deviate downward and converge as T -> 0. We propose that T-star marks the onset of short-range magnetic correlations, persisting beyond H-c. By comparing samples of different purity, we conclude that the Wiedemann-Franz law holds in YbRh2Si2, even at H-c, implying that no fundamental breakdown of quasiparticle behavior occurs in this material. The overall phenomenology of heat and charge transport in YbRh2Si2 is similar to that observed in the heavy-fermion metal CeCoIn5, near its own field-tuned quantum critical point.

  14. Dendrimer Templated Synthesis of One Nanometer Rh and Pt Particles Supported on Mesoporous Silica: Catalytic Activity for Ethylene and Pyrrole Hydrogenation.

    SciTech Connect (OSTI)

    Huang, Wenyu; Kuhn, John N.; Tsung, Chia-Kuang; Zhang, Yawen; Habas, Susan E.; Yang, Peidong; Somorjai, Gabor A.

    2008-05-09

    Monodisperse rhodium (Rh) and platinum (Pt) nanoparticles as small as {approx}1 nm were synthesized within a fourth generation polyaminoamide (PAMAM) dendrimer, a hyperbranched polymer, in aqueous solution and immobilized by depositing onto a high-surface-area SBA-15 mesoporous support. X-ray photoelectron spectroscopy indicated that the as-synthesized Rh and Pt nanoparticles were mostly oxidized. Catalytic activity of the SBA-15 supported Rh and Pt nanoparticles was studied with ethylene hydrogenation at 273 and 293 K in 10 torr of ethylene and 100 torr of H{sub 2} after reduction (76 torr of H{sub 2} mixed with 690 torr of He) at different temperatures. Catalysts were active without removing the dendrimer capping but reached their highest activity after hydrogen reduction at a moderate temperature (423 K). When treated at a higher temperature (473, 573, and 673 K) in hydrogen, catalytic activity decreased. By using the same treatment that led to maximum ethylene hydrogenation activity, catalytic activity was also evaluated for pyrrole hydrogenation.

  15. Water adsorption, solvation and deliquescence of alkali halide thin films on SiO2 studied by ambient pressure X-ray photoelectron spectroscopy

    SciTech Connect (OSTI)

    Arima, Kenta; Jiang, Peng; Deng, Xingyi; Bluhm, Henrik; Salmeron, Miquel

    2010-03-31

    The adsorption of water on KBr thin films evaporated onto SiO2 was investigated as a function of relative humidity (RH) by ambient pressure X-ray photoelectron spectroscopy. At 30percent RH adsorbed water reaches a coverage of approximately one monolayer. As the humidity continues to increase, the coverage of water remains constant or increases very slowly until 60percent RH, followed by a rapid increase up to 100percent RH. At low RH a significant number of the Br atoms are lost due to irradiation damage. With increasing humidity solvation increases ion mobility and gives rise to a partial recovery of the Br/K ratio. Above 60percent RH the increase of the Br/K ratio accelerates. Above the deliquescence point (85percent RH), the thickness of the water layer continues to increase and reaches more than three layers near saturation. The enhancement of the Br/K ratio at this stage is roughly a factor 2.3 on a 0.5 nm KBr film, indicating a strong preferential segregation of Br ions to the surface of the thin saline solution on SiO2.

  16. Indoor climate and moisture durability performances of houses with unvented attic roof constructions in a mixed-humid climate.

    SciTech Connect (OSTI)

    Pallin, Simon B.; Boudreaux, Philip R.; Jackson, Roderick K.

    2014-10-01

    A sealed or unvented attic is an energy-efficient envelope component that can reduce the amount of energy a house consumes for space conditioning if the air handler and/or ducts are located in the attic. The attic is typically sealed by using spray foam on the underside of the roof deck and covering the soffit, ridge and gable vents to minimize air leakage from the attic to the outside. This approach can save up to 10% in space-conditioning energy when ducts are located in the attic (DOE 2013). Past research done by ORNL and Florida Solar Energy Center suggests that in more hot, humid climates, an unvented attic could potentially create a more humid, uncomfortable living environment than a vented attic (Colon 2011, Boudreaux, Pallin et al. 2013). Research showed that controlling the higher indoor humidity could reduce the energy savings from the sealed, unvented attic, which in turn would decrease the energy savings payback. Research also showed that the roof assembly (5.5 inches of open-cell foam, 1inch of closed-cell foam, OSB, felt paper, and asphalt shingles) stored moisture, thus acting as a moisture buffer. During the fall and winter, the roof assembly stored moisture and during the spring and summer it released moisture. This phenomenon is not seen in a vented attic, in which the air exchange rate to the outside is greater and, in the winter, helps to dehumidify the attic air. It was also seen that in a vented attic, the direction of water vapor diffusion is on average from the attic to the interior of the house. Air leakage from the attic to the interior also occurs during more of the year in a house with an unvented attic than in one with a vented attic. These discoveries show that the moisture dynamics in a house with an unvented attic are much different from those in a house with a vented attic. This study reports on a series of computer model investigations completed to determine the key variables impacting indoor comfort and the durability of roof assemblies against moisture. The key variables investigated were the leakage area from the attic to the outside, leakage area from the attic to the interior, leakage area from the interior to the outside, supply duct leakage in the attic, and interior moisture generation. These investigations are described in this report.

  17. Moisture and Ventilation Solutions in Hot, Humid Climates: Florida Manufactured Housing- Building America Top Innovation

    Broader source: Energy.gov [DOE]

    This Building America Innovations profile describes work by Building America researchers who visited 24 manufactured home factories between 1996 and 2003 to investigate moisture problems while improving energy efficiency and identified insufficient air sealing and poor HVAC installation as the biggest culprits. One manufacturer reported zero moisture-related issues in 35,000 homes built after implementing Building America recommendations.

  18. Building America Top Innovations 2012: Moisture and Ventilation Solutions in Hot, Humid Climates: Florida Manufactured Housing

    SciTech Connect (OSTI)

    none,

    2013-01-01

    This Building America Top Innovations profile describes work by Building America researchers who visited 24 manufactured home factories between 1996 and 2003 to investigate moisture problems while improving energy efficiency and identified insufficient air sealing and poor HVAC installation as the biggest culprits. One manufacturer reported zero moisture-related issues in 35,000 homes built after implementing Building America recommendations.

  19. Integrated and Optimized Energy-Efficient Construction Package for a Community of Production Homes in the Mixed-Humid Climate

    SciTech Connect (OSTI)

    Mallay, D.; Wiehagen, J.; Del Bianco, M.

    2014-10-01

    This research high performance home analyzes how a set of advanced technologies can be integrated into a durable and energy-efficient house in the mixed-humid climate while remaining affordable to homeowners. The technical solutions documented in this report are the cornerstone of the builder's entire business model based on delivering high-performance homes on a production basis as a standard product offering to all price segments of the residential market. Home Innovation Research Labs partnered with production builder Nexus EnergyHomes (CZ 4) and they plan to adopt the successful components of the energy solution package for all 55 homes in the community. The research objective was to optimize the builder's energy solution package based on energy performance and construction costs. All of the major construction features, including envelope upgrades, space conditioning system, hot water system, and solar electric system were analyzed.

  20. Magnetization studies of oxides related to the high temperature cuprate superconductors

    SciTech Connect (OSTI)

    Wang, Z.

    1995-06-19

    The magnetic properties related to the following high temperature superconductors were measured utilizing a Faraday magnetometer: BaCuO{sub 2+x}, La{sub 2} CuO{sub 4}, Sr{sub 2} RhO{sub 4}, Sr{sub 2} VO{sub 4}, and Sr{sub 2} CuO{sub 3}. Neutron diffraction, magnetic susceptibility, and heat capacity measurements are discussed.

  1. Bay Ridge Gardens - Mixed-Humid Affordable Multifamily Housing Deep Energy Retrofit

    SciTech Connect (OSTI)

    Lyons, J.; Moore, M.; Thompson, M.

    2013-08-01

    Under this project, Newport Partners (as part of the BA-PIRC research team) evaluated the installation, measured performance, and cost-effectiveness of efficiency upgrade measures for a tenant-in-place DER at the Bay Ridge multifamily (MF) development in Annapolis, Maryland. The design and construction phase of the Bay Ridge project was completed in August 2012. This report summarizes system commissioning, short-term test results, utility bill data analysis, and analysis of real-time data collected over a one-year period after the retrofit was complete. The Bay Ridge project is comprised of a 'base scope' retrofit which was estimated to achieve a 30%+ savings (relative to pre-retrofit) on 186 apartments, and a 'DER scope' which was estimated to achieve 50% savings (relative to pre-retrofit) on a 12-unit building. The base scope was applied to the entire apartment complex, except for one 12-unit building which underwent the DER scope. A wide range of efficiency measures was applied to pursue this savings target for the DER building, including improvements/replacements of mechanical equipment and distribution systems, appliances, lighting and lighting controls, the building envelope, hot water conservation measures, and resident education. The results of this research build upon the current body of knowledge of multifamily retrofits. Towards this end, the research team has collected and generated data on the selection of measures, their estimated performance, their measured performance, and risk factors and their impact on potential measures.

  2. Bay Ridge Gardens - Mixed Humid Affordable Multifamily Housing Deep Energy Retrofit

    SciTech Connect (OSTI)

    Lyons, James; Moore, Mike; Thompson, Margo

    2013-08-01

    Under this project, Newport Partners (as part of the BA-PIRC research team) evaluated the installation, measured performance, and cost effectiveness of efficiency upgrade measures for a tenant-in-place deep energy retrofit (DER) at the Bay Ridge multifamily development in Annapolis, Maryland. This report summarizes system commissioning, short-term test results, utility bill data analysis, and analysis of real-time data collected over a one-year period after the retrofit was complete. The Bay Ridge project is comprised of a "base scope" retrofit which was estimated to achieve a 30%+ savings (relative to pre-retrofit) on 186 apartments, and a "DER scope" which was estimated to achieve 50% savings (relative to pre-retrofit) on a 12-unit building. A wide range of efficiency measures was applied to pursue this savings target for the DER building, including improvements/replacements of mechanical equipment and distribution systems, appliances, lighting and lighting controls, the building envelope, hot water conservation measures, and resident education. The results of this research build upon the current body of knowledge of multifamily retrofits. Towards this end, the research team has collected and generated data on the selection of measures, their estimated performance, their measured performance, and risk factors and their impact on potential measures.

  3. Achieving Challenge Home in Affordable Housing in the Hot-Humid Climate

    SciTech Connect (OSTI)

    Beal, D.; McIlvaine, J.; Winter, B.; Allnutt, R.

    2014-08-01

    The Building America Partnership for Improved Residential Construction (BA-PIRC), one of the Building America research team leads, has partnered with two builders as they work through the Challenge Home certification process (now Zero Energy Ready Home) in one test home each. The builder partners participating in this cost-shared research are Southeast Volusia County Habitat for Humanity near Daytona, Florida and Manatee County Habitat for Humanity near Tampa, Florida. Both are affiliates of Habitat for Humanity International, a non-profit affordable housing organization. This research serves to identify viable technical pathways to meeting the CH criteria for other builders in the region. A further objective of this research is to identify gaps and barriers in the marketplace related to product availability, labor force capability, code issues, cost effectiveness, and business case issues that hinder or prevent broader adoption on a production scale.

  4. Achieving Challenge Home in Affordable Housing in the Hot-Humid Climate

    SciTech Connect (OSTI)

    Beal, D.; McIlvaine, J.; Winter, B.; Allnutt, R.

    2014-08-01

    The Building America Partnership for Improved Residential Construction (BA-PIRC), one of the Building America research team leads, has partnered with two builders as they work through the Challenge Home certification process in one test home each. The builder partners participating in this cost-shared research are Southeast Volusia County Habitat for Humanity near Daytona, Florida and Manatee County Habitat for Humanity near Tampa, Florida. Both are affiliates of Habitat for Humanity International, a non-profit affordable housing organization. This research serves to identify viable technical pathways to meeting the CH criteria for other builders in the region. A further objective of this research is to identify gaps and barriers in the marketplace related to product availability, labor force capability, code issues, cost effectiveness, and business case issues that hinder or prevent broader adoption on a production scale.

  5. RH TRU Waste Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    as addressed in WIPP's first environmental impact statement in 1980 and the 1992 federal WIPP ... and NMED must approve the site's procedures for characterization, determining ...

  6. Temperature and RH Targets

    Broader source: Energy.gov [DOE]

    Presented by Vishal O Mittal of the Florida Solar Energy Center at the High Temperature Membrane Working Group Meeting, San Francisco, September 14, 2006.

  7. Microsoft Word - ORNL RH

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NEWS MEDIA CONTACT: March 2, 2009 Roger Nelson, Carlsbad Field Office (575) 234-7213 Walter Perry, Oak Ridge Office (865) 576-0885 FIRST OAK RIDGE REMOTE-HANDLED TRANSURANIC WASTE SHIPMENT ARRIVES SAFELY AT WASTE ISOLATION PILOT PLANT IN NEW MEXICO Energy Department meets regulatory milestone OAK RIDGE, Tenn. - The U.S. Department of Energy (DOE) achieved a major environmental cleanup milestone this week with the first shipment of Remote-Handled Transuranic (TRU) Waste leaving DOE's Oak Ridge

  8. Microsoft Word - SRS RH

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FOR IMMEDIATE RELEASE Roger Nelson, (575) 234-7213 April 24, 2009 For Immediate Release REMOTE-HANDLED TRU WASTE SHIPMENTS FROM SAVANNAH RIVER SITE ARRIVE SAFELY AT WIPP CARLSBAD, N.M. - The U.S. Department of Energy's (DOE) Carlsbad Field Office announced that the first two shipments of remote-handled transuranic (TRU) waste from the Savannah River Site (SRS) in South Carolina have arrived safely at the Waste Isolation Pilot Plant (WIPP). In addition to the initial remote-handled TRU waste

  9. Building America Best Practices Series: Volume 1; Builders and Buyers Handbook for Improving New Home Efficiency, Comfort, and Durability in the Hot and Humid Climate

    SciTech Connect (OSTI)

    2004-12-01

    This Building America Best Practices guide book is a resource to help builders large and small build high-quality, energy-efficient homes that achieve 30% energy savings in space conditioning and water heating in the hot and humid climate.

  10. Analysis of Energy, Environmental and Life Cycle Cost Reduction Potential of Ground Source Heat Pump (GSHP) in Hot and Humid Climate

    Broader source: Energy.gov [DOE]

    Project objectives: Gather and analyze independently the available technical, cost, financial incentive data on installed GSHP/HGSHP applications in residential, commercial and schools in hot and humid climate regions, and develop a calibrated baseline and performance period model of new construction and retrofitted buildings in conjunction with the energy simulation program.

  11. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Preliminary Correction of Vaisala Radiosonde Humidity Measurements for Slow Sensor Time-Response at Cold Temperatures L. M. Miloshevich and A. J. Heymsfield National Center for Atmospheric Research Boulder, Colorado A. Paukkunen Vaisala Oy Helsinki, Finland Introduction The goal of this study is to improve the accuracy of relative humidity (RH) measurements from Vaisala radiosondes, especially in the upper troposphere (UT), by correcting measurement error that results from slow time-response of

  12. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM Radiosonde Humidity Measurements and Proposed Corrections Based On AWEX Radiosonde Intercomparisons Miloshevich, L.M.(a), Lesht, B.M.(b), and Voemel, H.(c), National Center for Atmospheric Research (a), Argonne National Laboratory (b), NOAA/CMDL (c) Fourteenth Atmospheric Radiation Measurement (ARM) Science Team Meeting ARM radiosonde relative humidity (RH) measurements are widely used in numerical modeling, remote sensor validation, and radiative transfer calculations, yet their accuracy as

  13. Glossary of Energy-Related Terms | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Glossary of Energy-Related Terms Glossary of Energy-Related Terms August 20, 2013 - 9:20am Addthis Here you'll find a glossary of energy-related terms. A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z A Absolute Humidity The ratio of the mass of water vapor to the volume occupied by a mixture of water vapor and dry air. Absorbent A material that extracts one or more substances from a fluid (gas or liquid) medium on contact, and which changes

  14. Bioorganometallic chemistry: biocatalytic oxidation reactions with biomimetic nad+/nadh co-factors and [cp*rh(bpy)h]+ for selective organic synthesis

    SciTech Connect (OSTI)

    Lutz, Jochen; Hollman, Frank; Ho, The Vinh; Schnyder, Adrian; Fish, Richard H.; Schmid, Andreas

    2004-03-09

    The biocatalytic, regioselective hydroxylation of 2-hydroxybiphenyl to the corresponding catechol was accomplished utilizing the monooxygenase 2-hydroxybiphenyl 3-monooxygenase (HbpA). The necessary natural nicotinamide adenine dinucleotide (NAD{sup +}) co-factor for this biocatalytic process was replaced by a biomimetic co-factor, N-benzylnicotinamide bromide, 1a. The interaction between the flavin (FAD) containing HbpA enzyme and the corresponding biomimetic NADH compound, N-benzyl-1,4-dihdronicotinamide, 1b, for hydride transfers, was shown to readily occur. The in situ recycling of the reduced NADH biomimic 1b from 1a was accomplished with [Cp*Rh(bpy)H](Cl); however, productive coupling of this regeneration reaction to the enzymatic hydroxylation reaction was not totally successful, due to a deactivation process concerning the HbpA enzyme peripheral groups; i.e., -SH or -NH{sub 2} possibly reacting with the precatalyst, [Cp*Rh(bpy)(H{sub 2}O)](Cl){sub 2}, and thus inhibiting the co-factor regeneration process. The deactivation mechanism was studied, and a promising strategy of derivatizing these peripheral -SH or -NH{sub 2} groups with a polymer containing epoxide was successful in circumventing the undesired interaction between HbpA and the precatalyst. This latter strategy allowed tandem co-factor regeneration using 1a or 2a, [Cp*Rh(bpy)(H2O)](Cl){sub 2}, and formate ion, in conjunction with the polymer bound, FAD containing HbpA enzyme to provide the catechol product.

  15. Integrated and Optimized Energy-Efficient Construction Package for a Community of Production Homes in the Mixed-Humid Climate

    SciTech Connect (OSTI)

    Mallay, D.; Wiehagen, J.; Del Bianco, M.

    2014-10-01

    Selection and integration of high performance home features are two sides of the same coin in energy efficient sustainable construction. Many advanced technologies are available for selection, but it is in the integration of these technologies into an affordable set of features that can be used on a production basis by builders, that ensures whole-house performance meets expectations. This research high performance home analyzes how a set of advanced technologies can be integrated into a durable and energy efficient house in the mixed-humid climate while remaining affordable to homeowners. The technical solutions documented in this report are the cornerstone of the builder's entire business model based on delivering high-performance homes on a production basis as a standard product offering to all price segments of the residential market. Home Innovation Research Labs partnered with production builder Nexus EnergyHomes (CZ 4). The builder plans to adopt the successful components of the energy solution package for all 55 homes in the community. The research objective was to optimize the builder's energy solution package based on energy performance and construction costs. All of the major construction features, including envelope upgrades, space conditioning system, hot water system, and solar electric system were analyzed. The information in this report can be used by builders and designers to evaluate options, and the integration of options, for increasing the efficiency of home designs in climate zone 4. The data also provide a point of reference for evaluating estimates of energy savings and costs for specific features.

  16. Performance Verification of Production-Scalable Energy-Efficient Solutions: Winchester/Camberley Homes Mixed-Humid Climate

    SciTech Connect (OSTI)

    Mallay, D.; Wiehagen, J.

    2014-07-01

    Winchester/Camberley Homes collaborated with the Building America team Partnership for Home Innovation to develop a new set of high performance home designs that could be applicable on a production scale. The new home designs are to be constructed in the mixed humid climate zone and could eventually apply to all of the builder's home designs to meet or exceed future energy codes or performance-based programs. However, the builder recognized that the combination of new wall framing designs and materials, higher levels of insulation in the wall cavity, and more detailed air sealing to achieve lower infiltration rates changes the moisture characteristics of the wall system. In order to ensure long term durability and repeatable successful implementation with few call-backs, the project team demonstrated through measured data that the wall system functions as a dynamic system, responding to changing interior and outdoor environmental conditions within recognized limits of the materials that make up the wall system. A similar investigation was made with respect to the complete redesign of the HVAC systems to significantly improve efficiency while maintaining indoor comfort. Recognizing the need to demonstrate the benefits of these efficiency features, the builder offered a new house model to serve as a test case to develop framing designs, evaluate material selections and installation requirements, changes to work scopes and contractor learning curves, as well as to compare theoretical performance characteristics with measured results.

  17. Assessing health impacts in complex eco-epidemiological settings in the humid tropics: Modular baseline health surveys

    SciTech Connect (OSTI)

    Winkler, Mirko S.; Divall, Mark J.; Krieger, Gary R.; Schmidlin, Sandro; Magassouba, Mohamed L.; Knoblauch, Astrid M.; Singer, Burton H.; Utzinger, Juerg

    2012-02-15

    The quantitative assessment of health impacts has been identified as a crucial feature for realising the full potential of health impact assessment (HIA). In settings where demographic and health data are notoriously scarce, but there is a broad range of ascertainable ecological, environmental, epidemiological and socioeconomic information, a diverse toolkit of data collection strategies becomes relevant for the mainly small-area impacts of interest. We present a modular, cross-sectional baseline health survey study design, which has been developed for HIA of industrial development projects in the humid tropics. The modular nature of our toolkit allows our methodology to be readily adapted to the prevailing eco-epidemiological characteristics of a given project setting. Central to our design is a broad set of key performance indicators, covering a multiplicity of health outcomes and determinants at different levels and scales. We present experience and key findings from our modular baseline health survey methodology employed in 14 selected sentinel sites within an iron ore mining project in the Republic of Guinea. We argue that our methodology is a generic example of rapid evidence assembly in difficult-to-reach localities, where improvement of the predictive validity of the assessment and establishment of a benchmark for longitudinal monitoring of project impacts and mitigation efforts is needed.

  18. Performance Verification of Production-Scalable Energy-Efficient Solutions: Winchester/Camberley Homes Mixed-Humid Climate

    SciTech Connect (OSTI)

    Mallay, D.; Wiehagen, J.

    2014-07-01

    Winchester/Camberley Homes with the Building America program and its NAHB Research Center Industry Partnership collaborated to develop a new set of high performance home designs that could be applicable on a production scale. The new home designs are to be constructed in the mixed humid climate zone four and could eventually apply to all of the builder's home designs to meet or exceed future energy codes or performance-based programs. However, the builder recognized that the combination of new wall framing designs and materials, higher levels of insulation in the wall cavity, and more detailed air sealing to achieve lower infiltration rates changes the moisture characteristics of the wall system. In order to ensure long term durability and repeatable successful implementation with few call-backs, this report demonstrates through measured data that the wall system functions as a dynamic system, responding to changing interior and outdoor environmental conditions within recognized limits of the materials that make up the wall system. A similar investigation was made with respect to the complete redesign of the heating, cooling, air distribution, and ventilation systems intended to optimize the equipment size and configuration to significantly improve efficiency while maintaining indoor comfort. Recognizing the need to demonstrate the benefits of these efficiency features, the builder offered a new house model to serve as a test case to develop framing designs, evaluate material selections and installation requirements, changes to work scopes and contractor learning curves, as well as to compare theoretical performance characteristics with measured results.

  19. 20th Century Reanalysis Project Ensemble Gateway: 56 Estimates of World Temperature, Pressure, Humidity, and Wind, 1871-2010

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    This site provides data from the 20th Century Reanalysis Project, offering temperature, pressure, humidity, and wind predictions in 200 km sections all around the earth from 1871 to 2010, every 6 hours, based on historical data. The ensemble mean and standard deviation for each value were calculated over a set of 56 simulations. Data for each of the 56 ensemble members are included here. The dataset consists of files in netCDF 4 format that are available for download from the National Energy Research. The goal of the 20th Century Reanalysis Project is to use a Kalman filter-based technique to produce a global trophospheric circulation dataset at four-times-daily resolution back to 1871. The only dataset available for the early 20th century consists of error-ridden hand-drawn analyses of the mean sea level pressure field over the Northern Hemisphere. Modern data assimilation systems have the potential to improve upon these maps, but prior to 1948, few digitized upper-air sounding observations are available for such a reanalysis. The global tropospheric circulation dataset will provide an important validation check on the climate models used to make 21st century climate projections....[copied from http://portal.nersc.gov/project/20C_Reanalysis/

  20. Labor Relations

    Broader source: Energy.gov [DOE]

    The National Labor Relations Act prohibits unfair labor practices, including discrimination in employment to discourage (or encourage) membership in a union, and engaging in bad faith collective bargaining.

  1. Related Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Skip navigation links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases BP-18 Rate Case Related Publications Meetings...

  2. Investor Relations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and related services at cost. BPA Overview for Investors - as of September 24, 2015 Credit Ratings Latest Rating Agency Reports Full Reports: Fitch Full Report, March 2014...

  3. Labor Relations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Relations also provides technical assistance to, and coordination of, the Partnership Council and other labor-management forums. Collective Bargaining Agreements BPA AFGE...

  4. Energy and economic assessment of desiccant cooling systems coupled with single glazed air and hybrid PV/thermal solar collectors for applications in hot and humid climate

    SciTech Connect (OSTI)

    Beccali, Marco; Finocchiaro, Pietro; Nocke, Bettina

    2009-10-15

    This paper presents a detailed analysis of the energy and economic performance of desiccant cooling systems (DEC) equipped with both single glazed standard air and hybrid photovoltaic/thermal (PV/t) collectors for applications in hot and humid climates. The use of 'solar cogeneration' by means of PV/t hybrid collectors enables the simultaneous production of electricity and heat, which can be directly used by desiccant air handling units, thereby making it possible to achieve very energy savings. The present work shows the results of detailed simulations conducted for a set of desiccant cooling systems operating without any heat storage. System performance was investigated through hourly simulations for different systems and load combinations. Three configurations of DEC systems were considered: standard DEC, DEC with an integrated heat pump and DEC with an enthalpy wheel. Two kinds of building occupations were considered: office and lecture room. Moreover, three configurations of solar-assisted air handling units (AHU) equipped with desiccant wheels were considered and compared with standard AHUs, focusing on achievable primary energy savings. The relationship between the solar collector's area and the specific primary energy consumption for different system configurations and building occupation patterns is described. For both occupation patterns, sensitivity analysis on system performance was performed for different solar collector areas. Also, this work presents an economic assessment of the systems. The cost of conserved energy and the payback time were calculated, with and without public incentives for solar cooling systems. It is worth noting that the use of photovoltaics, and thus the exploitation of related available incentives in many European countries, could positively influence the spread of solar air cooling technologies (SAC). An outcome of this work is that SAC systems equipped with PV/t collectors are shown to have better performance in terms of primary energy saving than conventional systems fed by vapour compression chillers and coupled with PV cells. All SAC systems present good figures for primary energy consumption. The best performances are seen in systems with integrated heat pumps and small solar collector areas. The economics of these SAC systems at current equipment costs and energy prices are acceptable. They become more interesting in the case of public incentives of up to 30% of the investment cost (Simple Payback Time from 5 to 10 years) and doubled energy prices. (author)

  5. Building America Best Practices Series Volume 15: 40% Whole-House Energy Savings in the Hot-Humid Climate

    SciTech Connect (OSTI)

    Baechler, Michael C.; Gilbride, Theresa L.; Hefty, Marye G.; Cole, Pamala C.; Adams, Karen; Noonan, Christine F.

    2011-09-01

    This best practices guide is the 15th in a series of guides for builders produced by PNNL for the U.S. Department of Energy’s Building America program. This guide book is a resource to help builders design and construct homes that are among the most energy-efficient available, while addressing issues such as building durability, indoor air quality, and occupant health, safety, and comfort. With the measures described in this guide, builders in the hot-humid climate can build homes that have whole-house energy savings of 40% over the Building America benchmark with no added overall costs for consumers. The best practices described in this document are based on the results of research and demonstration projects conducted by Building America’s research teams. Building America brings together the nation’s leading building scientists with over 300 production builders to develop, test, and apply innovative, energy-efficient construction practices. Building America builders have found they can build homes that meet these aggressive energy-efficiency goals at no net increased costs to the homeowners. Currently, Building America homes achieve energy savings of 40% greater than the Building America benchmark home (a home built to mid-1990s building practices roughly equivalent to the 1993 Model Energy Code). The recommendations in this document meet or exceed the requirements of the 2009 IECC and 2009 IRC and those requirements are highlighted in the text. Requirements of the 2012 IECC and 2012 IRC are also noted in text and tables throughout the guide. This document will be distributed via the DOE Building America website: www.buildingamerica.gov.

  6. Building America Best Practices Series Volume 16: 40% Whole-House Energy Savings in the Mixed-Humid Climate

    SciTech Connect (OSTI)

    Baechler, Michael C.; Gilbride, Theresa L.; Hefty, Marye G.; Cole, Pamala C.; Adams, Karen; Butner, Ryan S.; Ortiz, Sallie J.

    2011-09-01

    This best practices guide is the 16th in a series of guides for builders produced by PNNL for the U.S. Department of Energy’s Building America program. This guide book is a resource to help builders design and construct homes that are among the most energy-efficient available, while addressing issues such as building durability, indoor air quality, and occupant health, safety, and comfort. With the measures described in this guide, builders in the mixed-humid climate can build homes that have whole-house energy savings of 40% over the Building America benchmark with no added overall costs for consumers. The best practices described in this document are based on the results of research and demonstration projects conducted by Building America’s research teams. Building America brings together the nation’s leading building scientists with over 300 production builders to develop, test, and apply innovative, energy-efficient construction practices. Building America builders have found they can build homes that meet these aggressive energy-efficiency goals at no net increased costs to the homeowners. Currently, Building America homes achieve energy savings of 40% greater than the Building America benchmark home (a home built to mid-1990s building practices roughly equivalent to the 1993 Model Energy Code). The recommendations in this document meet or exceed the requirements of the 2009 IECC and 2009 IRC and those requirements are highlighted in the text. Requirements of the 2012 IECC and 2012 IRC are also noted in text and tables throughout the guide. This document will be distributed via the DOE Building America website: www.buildingamerica.gov.

  7. Relational Blackboard

    Energy Science and Technology Software Center (OSTI)

    2012-09-11

    The Relational Blackboard (RBB) is an extension of the H2 Relational Database to support discrete events and timeseries data. The original motivation for RBB is as a knowledge base for cognitive systems and simulations. It is useful wherever there is a need for persistent storage of timeseries (i.e. samples of a continuous process generating numerical data) and semantic labels for the data. The RBB is an extension to the H2 Relational Database, which is open-source.more » RBB is a set of stored procedures for H2 allowing data to be labeled, queried, and resampled.« less

  8. Electronic structure of Ce?RhIn?: A two-dimensional heavy-fermion system studied by angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Rui; Petrovic, C.; Mou, Daixing; Liu, Chang; Zhao, Xin; Yao, Yongxin; Ryu, Hyejin; Ho, Kai -Ming; Kaminski, Adam

    2015-04-01

    We use angle-resolved photoemission spectroscopy (ARPES) to study the 2D heavy fermion superconductor, Ce?RhIn?. The Fermi surface is rather complicated and consists of several hole and electron pockets with one of the sheets displaying strong nesting properties with a q-vector of (0.32, 0.32) ?/a. We do not observe kz dispersion of the Fermi sheets, which is consistent with the expected 2D character of the electronic structure. Comparison of the ARPES data to band structure calculations suggests that a localized picture of the f-electrons works best. While there is some agreement in the overall band dispersion and location of the Fermimoresheets, the model does not reproduce all observed bands and is not completely accurate for those it does. Our data paves the way for improving the band structure calculations and the general understanding of the transport and thermodynamical properties of this material.less

  9. Analysis of Energy, Environmental and Life Cycle Cost Reduction Potential of Ground Source Heat Pump (GSHP) in Hot and Humid Climate

    SciTech Connect (OSTI)

    Yong X. Tao; Yimin Zhu

    2012-04-26

    It has been widely recognized that the energy saving benefits of GSHP systems are best realized in the northern and central regions where heating needs are dominant or both heating and cooling loads are comparable. For hot and humid climate such as in the states of FL, LA, TX, southern AL, MS, GA, NC and SC, buildings have much larger cooling needs than heating needs. The Hybrid GSHP (HGSHP) systems therefore have been developed and installed in some locations of those states, which use additional heat sinks (such as cooling tower, domestic water heating systems) to reject excess heat. Despite the development of HGSHP the comprehensive analysis of their benefits and barriers for wide application has been limited and often yields non-conclusive results. In general, GSHP/HGSHP systems often have higher initial costs than conventional systems making short-term economics unattractive. Addressing these technical and financial barriers call for additional evaluation of innovative utility programs, incentives and delivery approaches. From scientific and technical point of view, the potential for wide applications of GSHP especially HGSHP in hot and humid climate is significant, especially towards building zero energy homes where the combined energy efficient GSHP and abundant solar energy production in hot climate can be an optimal solution. To address these challenges, this report presents gathering and analyzing data on the costs and benefits of GSHP/HGSHP systems utilized in southern states using a representative sample of building applications. The report outlines the detailed analysis to conclude that the application of GSHP in Florida (and hot and humid climate in general) shows a good potential.

  10. Winchester/Camberley Homes New Construction Test House Design, Construction, and Short-Term Testing in a Mixed-Humid Climate

    SciTech Connect (OSTI)

    Mallay, D.; Wiehagen, J.; Wood, A.

    2012-10-01

    The NAHB Research Center partnered with production builder Winchester/Camberley Homes to build a new construction test house in the mixed-humid climate zone of Silver Spring, MD in June 2011. The goal for this house was to improve energy efficiency by 30% over the Building America B10 benchmark through an optimized energy solutions package design that could be constructed on a production basis. This report outlines the features of this house, discusses the energy efficient design, and reports on short-term testing results.

  11. Building America Best Practices Series: Volume 4; Builders and Buyers Handbook for Improving New Home Efficiency, Comfort, and Durability in the Mixed-Humid Climate

    SciTech Connect (OSTI)

    Baechler, M. C.; Taylor, Z. T.; Bartlett, R.; Gilbride, T.; Hefty, M.; Steward, H.; Love, P. M.; Palmer, J. A.

    2005-09-01

    This best practices guide is part of a series produced by Building America. The guide book is a resource to help builders large and small build high-quality, energy-efficient homes that achieve 30% energy savings in space conditioning and water heating in the mixed-humid climate region. The savings are in comparison with the 1993 Model Energy Code. The guide contains chapters for every member of the builders team-from the manager to the site planner to the designers, site supervisors, the trades, and marketers. There is also a chapter for homeowners on how to use the book to provide help in selecting a new home or builder.

  12. Winchester/Camberley Homes New Construction Test House Design, Construction, and Short-Term Testing in a Mixed-Humid Climate

    SciTech Connect (OSTI)

    Mallav, D.; Wiehagen, J.; Wood, A.

    2012-10-01

    The NAHB Research Center partnered with production builder Winchester/Camberley Homes to build a DOE Building America New Construction Test House (NCTH). This single family, detached house, located in the mixed-humid climate zone of Silver Spring, MD, was completed in June 2011. The primary goal for this house was to improve energy efficiency by 30% over the Building America B10 benchmark by developing and implementing an optimized energy solutions package design that could be cost effectively and reliably constructed on a production basis using quality management practices. The intent of this report is to outline the features of this house, discuss the implementation of the energy efficient design, and report on short-term testing results. During the interactive design process of this project, numerous iterations of the framing, air sealing, insulation, and space conditioning systems were evaluated for energy performance, cost, and practical implementation. The final design featured numerous advanced framing techniques, high levels of insulation, and the HVAC system entirely within conditioned space. Short-term testing confirmed a very tight thermal envelope and efficient and effective heating and cooling. In addition, relevant heating, cooling, humidity, energy, and wall cavity moisture data will be collected and presented in a future long-term report.

  13. Labor Relations

    Broader source: Energy.gov [DOE]

    Addressing Poor Performance What Happens if an Employee’s Performance is Below the Meets Expectations (ME) level? Any time during the appraisal period an employee demonstrates that he/she is performing below the ME level in at least one critical element, the Rating Official should contact his/her Human Resources Office for guidance and: •If performance is at the Needs Improvement (NI) level; issue the employee a Performance Assistance Plan (PAP); or •If performance is at the Fails to Meet Expectations (FME) level; issue the employee a Performance Improvement Plan (PIP). Department of Energy Headquarters and The National Treasury Employees Union (NTEU) Collective Bargaining Agreement The National Treasury Employees Union (NTEU) is the exclusive representative of bargaining unit employees at the Department of Energy Headquarters offices in the Washington DC metropolitan area. The terms and conditions of this agreement have been negotiated by DOE and NTEU, and prescribe their respective rights and obligations in matters related to conditions of employment. Headquarters 1187 Request For Payroll Deductions For Labor Organization Dues The Request for Payroll Deduction for Labor Organization Dues (SF-1187) permits eligible employees, who are members of the National Treasury Employees Union (NTEU), to authorize voluntary allotments from their compensation. Headquarters 1188 Cancellation Of Payroll Deductions For Labor Organization Dues The Cancellation of Payroll Deductions for Labor Organizations Dues (SF-1188) permits eligible employees, who are members of the National Treasury Employees Union (NTEU), to cancel dues allotments. The National Treasury Employees Union, Collective Bargaining Agreement, Article 9 – Dues Withholding This article is for the purpose of permitting eligible employees, who are members of the National Treasury Employees Union (NTEU), to authorize voluntary allotments from their compensation.

  14. Tuned sensitivity towards H{sub 2}S and NH{sub 3} with Cu doped barium strontium titanate materials

    SciTech Connect (OSTI)

    Simion, C. E. Teodorescu, V. S.; Stănoiu, A.; Sackmann, A.; Ruşti, C. F.; Piticescu, R. M.

    2014-11-05

    The different amount of Cu-doped Barium Strontium Titanate (BST) thick film materials have been tested for their gas-sensing performances towards NH{sub 3} and H{sub 2}S under dry and 50% relative humidity (RH) background conditions. The optimum NH{sub 3} sensitivity was attained with 0.1mol% Cu-doped BST whereas the selective detection of H{sub 2}S was highlighted using 5mol% Cu-doped BST material. No cross-sensitivity effects to CO, NO{sub 2}, CH{sub 4} and SO{sub 2} were observed for all tested materials operated at their optimum temperature (200°C) under humid conditions (50% RH). The presence of humidity clearly enhances the gas sensitivity to NH{sub 3} and H{sub 2}S detection.

  15. Electronic structure of Ce2 RhIn8: A two-dimensional heavy-fermion system studied by angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Rui; Mou, Daixing; Liu, Chang; Zhao, Xin; Yao, Yongxin; Ryu, Hyejin; Petrovic, C.; Ho, Kai -Ming; Kaminski, Adam

    2015-04-01

    In this study, we use angle-resolved photoemission spectroscopy (ARPES) to study the two-dimensional (2D) heavy-fermion superconductor, Ce2 RhIn8. The Fermi surface is rather complicated and consists of several hole and electron pockets with one of the sheets displaying strong nesting properties with a q vector of (0.32, 0.32) π/a. We do not observe kz dispersion of the Fermi sheets, which is consistent with the expected 2D character of the electronic structure. Comparison of the ARPES data to band-structure calculations suggests that a localized picture of the f electrons works best. While there is some agreement in the overall band dispersionmore » and location of the Fermi sheets, the model does not reproduce all observed bands and is not completely accurate for those it does. Our data paves the way for improving the band-structure calculations and the general understanding of the transport and thermodynamical properties of this material.« less

  16. Electronic structure of Ce2RhIn8: A two-dimensional heavy-fermion system studied by angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jiang, Rui; Mou, Daixing; Liu, Chang; Zhao, Xin; Yao, Yongxin; Ryu, Hyejin; Petrovic, C.; Ho, Kai -Ming; Kaminski, Adam

    2015-04-01

    We use angle-resolved photoemission spectroscopy (ARPES) to study the 2D heavy fermion superconductor, Ce₂RhIn₈. The Fermi surface is rather complicated and consists of several hole and electron pockets with one of the sheets displaying strong nesting properties with a q-vector of (0.32, 0.32) π/a. We do not observe kz dispersion of the Fermi sheets, which is consistent with the expected 2D character of the electronic structure. Comparison of the ARPES data to band structure calculations suggests that a localized picture of the f-electrons works best. While there is some agreement in the overall band dispersion and location of the Fermimore » sheets, the model does not reproduce all observed bands and is not completely accurate for those it does. As a result, our data paves the way for improving the band structure calculations and the general understanding of the transport and thermodynamical properties of this material.« less

  17. Intermediate valence in single crystals of (Lu{sub 1?x}Y b{sub x}){sub 3}Rh{sub 4}Ge{sub 13} (0 ? x ? 1)

    SciTech Connect (OSTI)

    Rai, Binod K.; Morosan, E.

    2015-04-01

    Single crystals of (Lu{sub 1?x}Y b{sub x}){sub 3}Rh{sub 4}Ge{sub 13} were characterized by magnetization, specific heat, and electrical resistivity measurements. Doping Yb into the non-magnetic Lu{sub 3}Rh{sub 4}Ge{sub 13} compound tunes this cubic systems properties from a superconductor with disordered metal normal state (x < 0.05) to a Kondo for 0.05 ? x ?0.2 and intermediate valence at the highest Yb concentrations. The evidence for intermediate Yb valence comes from a broad maximum in the magnetic susceptibility and X-ray photoelectron spectroscopy. Furthermore, the resistivity displays a local maximum at finite temperatures at intermediate compositions x, followed by apparent metallic behavior closest to the Yb end compound in the series.

  18. Change in magnetic and structural properties of FeRh thin films by gold cluster ion beam irradiation with the energy of 1.67?MeV/atom

    SciTech Connect (OSTI)

    Koide, T.; Iwase, A. [Department of Materials Science, Osaka Prefecture University, Sakai, Osaka 599-8531 (Japan); Saitoh, Y. [Japan Atomic Energy Agency, Takasaki, Gunma 370-1292 (Japan); Sakamaki, M.; Amemiya, K. [High Energy Accelerator Research Organization, Tsukuba, Ibaraki 305-0801 (Japan); Matsui, T., E-mail: t-matsui@21c.osakafu-u.ac.jp [Research Organization for the 21st Century, Osaka Prefecture University Sakai, Osaka 599-8531 (Japan)

    2014-05-07

    The effect of energetic cluster ion beam irradiation on magnetic and structural properties of FeRh thin films have been investigated. The cluster ions used in the present studies consist of a few gold atoms with the energy of 1.67?MeV/gold atom. Saturation magnetization of the sample irradiated with Au3 cluster ion beam (280?emu/cc) is larger than that for the irradiated sample with Au1 ion beam (240?emu/cc) for the same irradiation ion fluence. These results can also be confirmed by the X-ray magnetic circular dichroism (XMCD) measurement; the XMCD signal for Au3 cluster ion irradiation is larger than that for Au1 ion irradiation. Since the ion beam irradiation induced magnetization of FeRh is significantly correlated with the amount of the lattice defects in the samples, cluster ion beam irradiation can be considered to effectively introduce the lattice defects in B2-type FeRh rather than the single ion beam. Consequently, cluster ion irradiation is better than single ion irradiation for the viewpoint of saturation magnetization, even if the same irradiation energy is deposited in the samples.

  19. Building America Residential System Research Results: Achieving 30% Whole House Energy Savings Level in Mixed-Humid Climates; January 2006 - December 2006

    SciTech Connect (OSTI)

    Building America Industrialized Housing Partnership; Building Industry Research Alliance; Building Science Consortium; Consortium for Advanced Residential Buildings; Davis Energy Group; IBACOS; National Association of Home Builders Research Center; National Renewable Energy Laboratory

    2006-12-01

    The Building America program conducts the system research required to reduce risks associated with the design and construction of homes that use an average of 30% to 90% less total energy for all residential energy uses than the Building America Research Benchmark, including research on homes that will use zero net energy on annual basis. To measure the program's progress, annual research milestones have been established for five major climate regions in the United States. The system research activities required to reach each milestone take from 3 to 5 years to complete and include research in individual test houses, studies in pre-production prototypes, and research studies with lead builders that provide early examples that the specified energy savings level can be successfully achieved on a production basis. This report summarizes research results for the 30% energy savings level and demonstrates that lead builders can successfully provide 30% homes in the Mixed-Humid Climate Region on a cost-neutral basis.

  20. HVAC Design Strategy for a Hot-Humid Production Builder, Houston, Texas (Fact Sheet), Building America Case Study: Whole-House Solutions for New Homes, Building Technologies Office (BTO)

    Energy Savers [EERE]

    HVAC Design Strategy for a Hot-Humid Production Builder Houston, Texas PROJECT INFORMATION Construction: New Home Type: Single-family, production builder Builder: David Weekley Homes - Houston www.davidweekleyhomes.com/ new-homes/tx/houston Size: 1,757 ft 2 to 4,169 ft 2 Price Range: about $260,000 to $450,000 Date Completed: 2013 Climate Zone: Hot-humid PERFORMANCE DATA HERS index: Builder standard practice = 66; case study 1,757-ft 2 house = 54 Projected annual energy cost savings: $375

  1. High Hydrogen Concentrations Detected In The Underground Vaults For RH-TRU Waste At INEEL Compared With Calculated Values Using The INEEL-Developed Computer Code

    SciTech Connect (OSTI)

    Rajiv Bhatt; Soli Khericha

    2005-02-01

    About 700 remote-handled transuranic (RH-TRU) waste drums are stored in about 144 underground vaults at the Intermediate-Level Transuranic Storage Facility at the Idaho National Environmental and Engineering Laboratorys (INEELs) Radioactive Waste Management Complex (RWMC). These drums were shipped to the INEEL from 1976 through 1996. During recent monitoring, concentrations of hydrogen were found to be in excess of lower explosive limits. The hydrogen concentration in one vault was detected to be as high as 18% (by volume). This condition required evaluation of the safety basis for the facility. The INEEL has developed a computer program to estimate the hydrogen gas generation as a function of time and diffusion through a series of layers (volumes), with a maximum five layers plus a sink/environment. The program solves the first-order diffusion equations as a function of time. The current version of the code is more flexible in terms of user input. The program allows the user to estimate hydrogen concentrations in the different layers of a configuration and then change the configuration after a given time; e.g.; installation of a filter on an unvented drum or placed in a vault or in a shipping cask. The code has been used to predict vault concentrations and to identify potential problems during retrieval and aboveground storage. The code has generally predicted higher hydrogen concentrations than the measured values, particularly for the drums older than 20 year, which could be due to uncertainty and conservative assumptions in drum age, heat generation rate, hydrogen generation rate, Geff, and diffusion rates through the layers.

  2. Synthesis, structure and chemical bonding of CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x=0, 1.32, and 2) and SrCo{sub 2}Si{sub 2}

    SciTech Connect (OSTI)

    Hlukhyy, Viktor Hoffmann, Andrea V.; Fssler, Thomas F.

    2013-07-15

    The finding of superconductivity in Ba{sub 0.6}K{sub 0.4}Fe{sub 2}As{sub 2} put the attention on the investigation of compounds that crystallize with ThCr{sub 2}Si{sub 2} structure type such as AT{sub 2}X{sub 2} (A=alkali/alkaline earth/rare earth element; T=transition metal and X=element of the 1315th group). In this context the silicides CaFe{sub 2}Si{sub 2}, CaFe{sub 0.68(6)}Rh{sub 1.32(6)}Si{sub 2}, CaRh{sub 2}Si{sub 2} and SrCo{sub 2}Si{sub 2} have been synthesized by reaction of the elements under an argon atmosphere. Single crystals were obtained by special heat treatment in welded niobium/tantalum ampoules. The compounds were investigated by means of powder and single crystal X-ray diffraction. All compounds crystallize in the ThCr{sub 2}Si{sub 2}-type structure with space group I4/mmm (No. 139): a=3.939(1) , c=10.185(1) , R{sub 1}=0.045, 85 F{sup 2} values, 8 variable parameters for CaFe{sub 2}Si{sub 2}; a=4.0590(2) , c=9.9390(8) , R{sub 1}=0.030, 90 F{sup 2} values, 10 variable parameters for CaFe{sub 0.68(6)}Rh{sub 1.32(6)}Si{sub 2}; a=4.0695(1) , c=9.9841(3) , R{sub 1}=0.031, 114 F{sup 2} values, 9 variable parameters for CaRh{sub 2}Si{sub 2}; and a=3.974(1) , c=10.395(1) , R{sub 1}=0.036, 95 F{sup 2} values, 8 variable parameters for SrCo{sub 2}Si{sub 2}. The structure of SrCo{sub 2}Si{sub 2} contains isolated [Co{sub 2}Si{sub 2}]{sup 2?} 2D-layers in the ab-plane whereas in CaFe{sub 2?x}Rh{sub x}Si{sub 2} the [T{sub 2}Si{sub 2}] layers (T=Fe and Rh) are interconnected along the c-axis via Si3Si bonds resulting in a three-dimentional (3D) [T{sub 2}Si{sub 2}]{sup 2?} polyanions and therefore belong to the so-called collapsed form of the ThCr{sub 2}Si{sub 2}-type structure. The SrCo{sub 2}Si{sub 2} and CaRh{sub 2}Si{sub 2} are isoelectronic to the parent 122 ironpnictide superconductors AeFe{sub 2}As{sub 2} (Ae=alkaline earth elements), whereas CaFe{sub 2}Si{sub 2} is a full substituted variant (As/Si) of CaFe{sub 2}As{sub 2}. The crystal chemistry and chemical bonding in the title compounds are discussed in terms of LMTO band structure calculations and a topological analysis using the Electron Localization Function (ELF). - Graphical abstract: The SrCo{sub 2}Si{sub 2} and CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x==0, 1.32, and 2) crystallize in the ThCr{sub 2}Si{sub 2}-type. The structure of SrCo{sub 2}Si{sub 2} contains isolated [Co{sub 2}Si{sub 2}]{sup 2?} layers in the ab-plane, whereas the [T{sub 2}Si{sub 2}] layers in CaFe{sub 2?x}Rh{sub x}Si{sub 2} are interconnected along the c-axis via Si3Si bonds resulting in a [T{sub 2}Si{sub 2}]{sup 2?} network. - Highlights: Synthesis and structure of ternary silicides SrCo{sub 2}Si{sub 2} and CaFe{sub 2?x}Rh{sub x}Si{sub 2} (x=0, 1.32, and 2). The SrCo{sub 2}Si{sub 2} and CaRh{sub 2}Si{sub 2} are isoelectronic to the parent 122 ironpnictide superconductors AeFe{sub 2}As{sub 2}. CaFe{sub 2}Si{sub 2} is a full substituted variant (As/Si) of superconductor CaFe{sub 2}As{sub 2}. The title compounds demonstrate the tunable Si3Si distances.

  3. Large fluxes and rapid turnover of mineral-associated carbon across topographic gradients in a humid tropical forest: insights from paired 14C analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hall, S. J.; McNicol, G.; Natake, T.; Silver, W. L.

    2015-01-16

    It has been proposed that the large soil carbon (C) stocks of humid tropical forests result predominantly from C stabilization by reactive minerals, whereas oxygen (O2) limitation of decomposition has received much less attention. We examined the importance of these factors in explaining patterns of C stocks and turnover in the Luquillo Experimental Forest, Puerto Rico, using radiocarbon (14C) measurements of contemporary and archived samples. Samples from ridge, slope, and valley positions spanned three soil orders (Ultisol, Oxisol, Inceptisol) representative of humid tropical forests, and differed in texture, reactive metal content, O2 availability, and root biomass. Mineral-associated C comprised themore » large majority (87 ± 2%, n = 30) of total soil C. Turnover of most mineral-associated C (74 ± 4%) was rapid (9 to 29 years, mean and SE 20 ± 2 years) in 25 of 30 soil samples across surface horizons (0–10 and 10–20 cm depths) and all topographic positions, independent of variation in reactive metal concentrations and clay content. Passive C with centennial – millennial turnover was much less abundant (26%), even at 10–20 cm depths. Carbon turnover times and concentrations significantly increased with concentrations of reduced iron (Fe(II)) across all samples, suggesting that O2 availability may have limited the decomposition of mineral associated C over decadal scales. Steady-state inputs of mineral-associated C were similar among the three topographic positions, and could represent 10–30% of annual litterfall production (estimated by doubling aboveground litterfall). Observed trends in mineral-associated Δ14C over time could not be fit using the single pool model used in many other studies, which generated contradictory relationships between turnover and Δ14C as compared with a more realistic constrained two-pool model. The large C fluxes in surface and near-surface soils implied by our data suggest that other studies using single-pool Δ14C models of mineral-associated C dynamics, unconstrained by multiple time points, may have systematically underestimated C turnover.« less

  4. Photoredox degradation of different water pollutants (MO, RhB, MB, and Cr(VI)) using Fe–N–S-tri-doped TiO{sub 2} nanophotocatalyst prepared by novel chemical method

    SciTech Connect (OSTI)

    Xu, Xuyao; Zhou, Xiaosong Zhang, Lingling; Xu, Limei; Ma, Lin; Luo, Jin; Li, Mengjia; Zeng, Lihua

    2015-10-15

    Highlights: • TiO{sub 2} was synthesized through simple one-step hydrothermal method. • Photocatalytic activity for degradation of organic dyes and Cr(VI) are investigated. • The synergistic effect is shown in coexistence of MB and Cr(VI). - Abstract: Fe–N–S-tri-doped TiO{sub 2} (FeNS-TiO{sub 2}) was synthesized by a simple one-step hydrothermal method. The as-synthesized samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS). The photocatalytic activities of as-synthesized samples were tested by the oxidation of methyl orange (MO), rhodamine B (RhB), methylene blue (MB) and the reduction of aqueous Cr(VI) under visible-light (λ > 420 nm) irradiation, and compared with N-dope P25 (N-P25) and the undoped TiO{sub 2}. Besides, the effects of the coexistence of MO, RhB, and MB on FeNS-TiO{sub 2}-mediated photocatalytic reduction of aqueous Cr(VI) were also studied. The results indicated FeNS-TiO{sub 2} displayed higher visible-light-activated photocatalytic activity than N-P25 and the undoped TiO{sub 2}. Otherwise, FeNS-TiO{sub 2} showed the coexistence of MB enhanced the photocatalytic reduction of Cr(VI), whereas the coexistence of MO and RhB retarded the photocatalytic reduction of Cr(VI) over FeNS-TiO{sub 2}. Moreover, a possible photocatalytic mechanism is discussed.

  5. Community Relations Plan

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environmental Stewardship Environmental Protection Community Relations Plan Community Relations Plan Consultations, communications, agreements, and disagreements...

  6. Relevance of biotic pathways to the long-term regulation of nuclear waste disposal. Topical report on reference eastern humid low-level sites

    SciTech Connect (OSTI)

    McKenzie, D.H.; Cadwell, L.L.; Eberhardt, L.E.; Kennedy, W.E. Jr.; Peloquin, R.A.; Simmons, M.A.

    1983-01-01

    The purpose of the work reported here was to develop an order-of-magnitude estimate for the potential dose to man resulting from biotic transport mechanisms at a humid reference low-level waste site in the eastern US. A description of the reference site is presented that includes the waste inventories, site characteristics and biological communites. Parameter values for biotic transport processes are based on data reported in current literature. Transport and exposure scenarios are developed for assessing biotic transport during 500 years following site closure. Calculations of radionuclide decay and waste container decomposition are made to estimate the quantities available for biotic transport. Doses to man are calculated for the biological transport of radionucludes at the reference site after loss of institutional control. These dose estimates are compared to dose estimates we calculated for the intruder-agricultural scenarios reported in the DEIS for 10 CFR 61 (NRC). Dose to man estimates as a result of cumulative biotic transport are calculated to be of the same order-of-magnitude as the dose resulting from the more commonly evaluated human intrusion scenario. The reported lack of potential importance of biotic transport at low-level waste sites in earlier assessment studies is not confirmed by findings presented in this report. Through biotic transport, radionuclides can be moved to locations where they can enter exposure pathways to man.

  7. Ion Segregation and Deliquescence of Alkali Halide Nanocrystals on SiO2

    SciTech Connect (OSTI)

    Arima, Kenta; Jiang, Peng; Lin, Deng-Sung; Verdaguer, Albert; Salmeron, Miquel

    2009-08-11

    The adsorption of water on alkali halide (KBr, KCl, KF, NaCl) nanocrystals on SiO{sub 2} and their deliquescence was investigated as a function of relative humidity (RH) from 8% to near saturation by scanning polarization force microscopy. At low humidity, water adsorption solvates ions at the surface of the crystals and increases their mobility. This results in a large increase in the dielectric constant, which is manifested in an increase in the electrostatic force and in an increase in the apparent height of the nanocrystals. Above 58% RH, the diffusion of ions leads to Ostwald ripening, where larger nanocrystals grow at the expense of the smaller ones. At the deliquescence point, droplets were formed. For KBr, KCl, and NaCl, the droplets exhibit a negative surface potential relative to the surrounding region, which is indicative of the preferential segregation of anions to the air/solution interface.

  8. Issues related to venting of attics and cathedral ceilings

    SciTech Connect (OSTI)

    TenWolde, A.; Rose, W.B.

    1999-07-01

    Current model building codes require attic ventilation in all US climates. Originally, these requirements were strictly based on concerns for condensation in attics during winter in cold climates, and they were based on limited technical information. Nevertheless, attic ventilation has become the uncontested strategy to minimize condensation and ice dams during winter and extreme attic temperatures during summer. However, other strategies exist that address each of these problems as well as or better than attic ventilation. This paper examines issues such as summer attic temperatures, ice dams, and shingle durability and discusses the relative merits of attic ventilation compared to alternative design approaches in various climates. The authors support current recommendations for attic ventilation in cold and mixed climates but recommend that attic ventilation be treated as a design option in warm, humid climates. The authors review the new information on attic and roof ventilation in the 1997 ASHRAE Handbook--Fundamentals and discuss the reasons for the changes.

  9. Magnetic structure of the antiferromagnetic Kondo lattice compounds CeRhAl4Si2 and CeIrAl4Si2

    SciTech Connect (OSTI)

    Ghimire, N. J.; Calder, S.; Janoschek, M.; Bauer, E. D.

    2015-06-01

    In this article, we have investigated the magnetic ground state of the antiferromagnetic Kondo-lattice compounds CeMAl4Si2(M = Rh, Ir) using neutron powder diffraction. Although both of these compounds show two magnetic transitions TN1 and TN2 in the bulk properties measurements, evidence for magnetic long-range order was only found below the lower transition TN2. Analysis of the diffraction profiles reveals a commensurate antiferromagnetic structure with a propagation vector k = (0, 0, 1/2). The magnetic moment in the ordered state of CeRhAl4Si2 and CeIrAl4Si2 were determined to be 1.14(2) and 1.41(3) ?B/Ce, respectively, and are parallel to the crystallographic c-axis in agreement with magnetic susceptibility measurements.

  10. Ellipsometry characterization of polycrystalline ZnO layers with the modeling of carrier concentration gradient: Effects of grain boundary, humidity, and surface texture

    SciTech Connect (OSTI)

    Sago, Keisuke; Fujiwara, Hiroyuki; Kuramochi, Hideto; Iigusa, Hitoshi; Utsumi, Kentaro

    2014-04-07

    Spectroscopic ellipsometry (SE) has been applied to study the effects of grain boundary, humidity, and surface texture on the carrier transport properties of Al-doped ZnO layers fabricated by dc and rf magnetron sputtering. In the SE analysis, the variation in the free carrier absorption toward the growth direction, induced by the ZnO grain growth on foreign substrates, has been modeled explicitly by adopting a multilayer model in which the optical carrier concentration (N{sub opt}) varies continuously with a constant optical mobility (?{sub opt}). The effect of the grain boundary has been studied by comparing ?{sub opt} with Hall mobility (?{sub Hall}). The change in ?{sub Hall}/?{sub opt} indicates a sharp structural transition of the ZnO polycrystalline layer at a thickness of d???500?nm, which correlates very well with the structure confirmed by transmission electron microscopy. In particular, below the transition thickness, the formation of the high density grain boundary leads to the reduction in the ?{sub Hall}/?{sub opt} ratio as well as N{sub opt}. As a result, we find that the thickness dependence of the carrier transport properties is almost completely governed by the grain boundary formation. On the other hand, when the ZnO layer is exposed to wet air at 85?C, ?{sub Hall} reduces drastically with a minor variation of ?{sub opt} due to the enhanced grain boundary scattering. We have also characterized textured ZnO:Al layers prepared by HCl wet etching by SE. The analysis revealed that the near-surface carrier concentration increases slightly after the etching. We demonstrate that the SE technique can be applied to distinguish various rough textured structures (size???1??m) of the ZnO layers prepared by the HCl etching.

  11. Energy Balance Bowen Ratio (EBBR) Handbook (Technical Report) | SciTech

    Office of Scientific and Technical Information (OSTI)

    Connect Energy Balance Bowen Ratio (EBBR) Handbook Citation Details In-Document Search Title: Energy Balance Bowen Ratio (EBBR) Handbook The Energy Balance Bowen Ratio (EBBR) system produces 30-minute estimates of the vertical fluxes of sensible and latent heat at the local surface. Flux estimates are calculated from observations of net radiation, soil surface heat flux, and the vertical gradients of temperature and relative humidity (RH). Meteorological data collected by the EBBR are used

  12. Managing the Drivers of Air Flow and Water Vapor Transport in Existing Single Family Homes (Revised)

    SciTech Connect (OSTI)

    Cummings, J.; Withers, C.; Martin, E.; Moyer, N.

    2012-10-01

    This document focuses on managing the driving forces which move air and moisture across the building envelope. While other previously published Measure Guidelines focus on elimination of air pathways, the ultimate goal of this Measure Guideline is to manage drivers which cause air flow and water vapor transport across the building envelope (and also within the home), control air infiltration, keep relative humidity (RH) within acceptable limits, avoid combustion safety problems, improve occupant comfort, and reduce house energy use.

  13. Analysis of Selected Radiosonde Data from the ARM/NSA Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analysis of Selected Radiosonde Data from the ARM/NSA Site B. Petracca, H. W. Church, and B. D. Zak Sandia National Laboratories Albuquerque, New Mexico R. Storvold and C. Marty Geophysical Institute University of Alaska Fairbanks, Alaska B. M. Lesht Argonne National Laboratories Argonne, Illinois Introduction The purpose of this study was to analyze differences in temperature and relative humidity (RH) profiles obtained from near-simultaneous radiosonde soundings made from different locations

  14. Building America Case Study: Evaluation of the Performance of Houses With and Without Supplemental Dehumidification in a Hot-Humid Climate, New Orleans, Louisiana (Fact Sheet), Technology Solutions for New and Existing Homes, Energy Efficiency & Renewable Energy (EERE)

    Energy Savers [EERE]

    the Performance of Houses With and Without Supplemental Dehumidification in a Hot-Humid Climate New Orleans, Louisiana PROJECT INFORMATION Project Name: New Orleans Dehumidification Study Location: New Orleans, LA Partners: Project Home Again Building Science Corporation, buildingscience.com National Renewable Energy Laboratory, nrel.gov Mountain Energy Partnership Building Component: Supplemental dehumidification Application: New; single- and multifamily homes Year Tested: 2012-2013 Applicable

  15. Synthesis, crystal structure investigation and magnetism of the complex metal-rich boride series Cr{sub x}(Rh{sub 1-y}Ru{sub y}){sub 7-x}B{sub 3} (x=0.88-1; y=0-1) with Th{sub 7}Fe{sub 3}-type structure

    SciTech Connect (OSTI)

    Misse, Patrick R.N.; Mbarki, Mohammed; Fokwa, Boniface P.T.

    2012-08-15

    Powder samples and single crystals of the new complex boride series Cr{sub x}(Rh{sub 1-y}Ru{sub y}){sub 7-x}B{sub 3} (x=0.88-1; y=0-1) have been synthesized by arc-melting the elements under purified argon atmosphere on a water-cooled copper crucible. The products, which have metallic luster, were structurally characterized by single-crystal and powder X-ray diffraction as well as EDX measurements. Within the whole solid solution range the hexagonal Th{sub 7}Fe{sub 3} structure type (space group P6{sub 3}mc, no. 186, Z=2) was identified. Single-crystal structure refinement results indicate the presence of chromium at two sites (6c and 2b) of the available three metal Wyckoff sites, with a pronounced preference for the 6c site. An unexpected Rh/Ru site preference was found in the Ru-rich region only, leading to two different magnetic behaviors in the solid solution: The Rh-rich region shows a temperature-independent (Pauli) paramagnetism whereas an additional temperature-dependent paramagnetic component is found in the Ru-rich region. - Graphical abstract: The new complex boride series Cr{sub x}(Rh{sub 1-y}Ru{sub y}){sub 7-x}B{sub 3} (x=0.88-1; y=0-1) has been synthesized by arc melting the elements under purified argon atmosphere. Beside the 3d/4d site preference within the whole solid solution, an unexpected Rh/Ru site preference was found in the Ru-rich region only, leading to two different magnetic behaviors: The Rh-rich region shows a temperature-independent (Pauli) paramagnetism whereas an additional temperature-dependent paramagnetic component is found in the Ru-rich region. Highlights: Black-Right-Pointing-Pointer Synthesis of a new boride series fulfilling Vegard Acute-Accent s rule. Black-Right-Pointing-Pointer 3d/4d site preference. Black-Right-Pointing-Pointer Unexpected Ru/Rh site preference. Black-Right-Pointing-Pointer Rh-rich region is Pauli paramagnetic. Black-Right-Pointing-Pointer Ru-rich region is Pauli and temperature-dependent paramagnetic.

  16. First-principles studies of structural stabilities and enthalpies of formation of refractory intermetallics: TM and TM3 (T = Ti, Zr, Hf; M = Ru, Rh, Pd, Os, Ir, Pt)

    SciTech Connect (OSTI)

    Xing, Weiwei; Chen, X.; Li, Dianzhong; Li, Y. Y.; Fu, Chong Long; Meschel, S.

    2012-01-01

    Using first-principles local density functional approach, we have calculated the ground-state structural phase stabilities and enthalpies of formation of thirty-six binary transition-metal refractory TM and TM3 compounds formed by Group IV elements T (T = Ti, Zr, Hf) and platinum group elements M (M = Ru, Rh, Pd, Os, Ir, Pt) . We compared our results with the available experimental data and found good agreement between theory and experiment in both the trends of structural stabilities and the magnitudes of formation enthalpies. Moreover, based on our calculated results, an empirical relationship between cohesive energies ( E) and melting temperatures (Tm) was derived as Tm = 0.0292 E/kB (where kB is the Boltzmann constant) for both TM and TM3 compounds.

  17. Role of the reaction intermediates in determining PHIP (parahydrogen induced polarization) effect in the hydrogenation of acetylene dicarboxylic acid with the complex [Rh (dppb)]{sup +} (dppb: 1,4-bis(diphenylphosphino)butane)

    SciTech Connect (OSTI)

    Reineri, F.; Aime, S.; Gobetto, R.; Nervi, C.

    2014-03-07

    This study deals with the parahydrogenation of the symmetric substrate acetylene dicarboxylic acid catalyzed by a Rh(I) complex bearing the chelating diphosphine dppb (1,4-bis(diphenylphosphino)butane). The two magnetically equivalent protons of the product yield a hyperpolarized emission signal in the {sup 1}H-NMR spectrum. Their polarization intensity varies upon changing the reaction solvent from methanol to acetone. A detailed analysis of the hydrogenation pathway is carried out by means of density functional theory calculations to assess the structure of hydrogenation intermediates and their stability in the two solvents. The observed polarization effects have been accounted on the basis of the obtained structures. Insights into the lifetime of a short-lived reaction intermediate are also obtained.

  18. S-H bond activation in H{sub 2}S and thiols by [RhMn(CO){sub 4}(Ph{sub 2}PCH{sub 2}PPh{sub 2}){sub 2}]. Compounds containing terminal or bridging sulfhydryl and thiolato groups

    SciTech Connect (OSTI)

    Li-Sheng Wang; McDonald, R.; Cowie, M. [Univ. of Alberta, Edmonton (Canada)

    1994-08-17

    A rhodium-magnesium carbonyl-phosphines reacted with thiols to yield the products of S-H addition. Further reactions result in bridging sulfide can be alkylated or protonated at the sulfur. The compound, [RhMn(CO){sub 4}({mu}-S)(dppm){sub 2}], was structurally characterized by X-ray crystallography.

  19. EMPLOYMENT OF RELATIVES (NEPOTISM)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EMPLOYMENT OF RELATIVES (NEPOTISM) An applicant who is a relative of an employee of Oak Ridge Associated Universities (ORAU) will be considered for employment on the same basis as other candidates. However, applicants are obligated to inform the Employment Department of relatives who are ORAU employees. ORAU's nepotism policy places the following restrictions on employment of relatives: * An employee may not have a managerial or administrative relationship over a relative (this prohibition

  20. Performance of a Heat Pump Water Heater in the Hot-Humid Climate, Windermere, Florida (Fact Sheet), Building America Case Study: Technology Solutions for New and Existing Homes, Building Technologies Office (BTO)

    Energy Savers [EERE]

    Performance of a Heat Pump Water Heater in the Hot-Humid Climate Windermere, Florida Over recent years, heat pump water heaters (HPWHs) have become more read- ily available and more widely adopted in the marketplace. A key feature of an HPWH unit is that it is a hybrid system. When conditions are favorable, the unit will operate in heat pump mode (using a vapor compression system that extracts heat from the surrounding air) to effciently provide domestic hot water (DHW). Homeowners need not

  1. Related Links - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Related Links Hanford Advisory Board Convening Report SSAB Guidance Memorandum of Understanding Membership Nomination and Appointment Process Operating Ground Rules Calendars Advice and Responses Full Board Meeting Information Committee Meeting Information Outgoing Board Correspondence Key Board Products and Special Reports HAB Annual Report HAB and Committee Lists Points of Contact Related Links Related Links Email Email Page | Print Print Page |Text Increase Font Size Decrease Font Size

  2. Community Relations Plan

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Community, Environment » Environmental Stewardship » Environmental Protection » Community Relations Plan Community Relations Plan Consultations, communications, agreements, and disagreements between the Permittees and the public are documented during the Hazardous Waste Facility Permit Community Relations Plan development. Contact Environmental Communication & Public Involvement PO Box 1663, MS M996 Los Alamos, NM 87544 (505) 667-0216 Email We welcome your comments and suggestions on how

  3. ARM - Related Links

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Releases TWP-ICE Images ARM flickr site <"" li"" height"14" width"16"> Related Links Planning Science Plan November 2004 Planning Meeting BOM Experiment Webpage BOM Northern...

  4. Fermilab Today - Related Content

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Related Content Subscribe | Contact Fermilab Today | Archive | Classifieds Search GO Classifieds Director's Corner Physics in a Nutshell Frontier Science Result Tip of the Week...

  5. WIPP - Related Links

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Related Links Categories Project Participants TRU Waste Sites Oversight Other Related Links Project Participants US Department of Energy - Albuquerque Operations Office US Department of Energy - Headquarters Nuclear Waste Partnership LLC Los Alamos National Laboratory Sandia National Laboratories Portage - Carlsbad Field Office Technical Assistance Contractor Skylla Engineering SM Stoller Corporation L&M Technologies, Inc. Transuranic Back to top Waste Sites Argonne National Laboratory

  6. Insights into accelerated aging of SSL luminaires

    SciTech Connect (OSTI)

    Davis, J. Lynn; Lamvik, Michael; Bittle, James; Shepherd, Sarah; Yaga, Robert; Baldasaro, Nick; Solano, Eric; Bobashev, Georgiy

    2013-09-30

    Although solid-state lighting (SSL) products are often intended to have product lifetimes of 15 years or more, the rapid change in technology has created a need for accelerated life tests (ALTs) that can be performed in the span of several months. A critical element of interpreting results from any systems-level ALT is understanding of the impact of the test environment on each component. Because of its ubiquity in electronics, the use of temperature-humidity environments as potential ALTs for SSL luminaires was investigated. Results from testing of populations of three commercial 6 downlights in environments of 85oC and 85% relative humidity (RH) and 75oC and 75% RH are reported. These test environments were found to accelerate lumen depreciation of the entire luminaire optical system, including LEDs, lenses, and reflectors. The effects of aging were found to depend strongly on both the optical materials that were used and the design of the luminaire; this shows that the lumen maintenance behavior of SSL luminaires must be addressed at the optical systems level. Temperature-Humidity ALTs can be a useful test in understand lumainaire depreciation provided that proper consideration is given to the different aging rates of various materials. Since the impact of the temperature-humidity environment varies among components of the optical system, uniform aging of all system components in a single test is difficult to achieve.

  7. Dimethyl sulfide substituted mixed-metal clusters: Synthesis, structure, and characterization of HRuCo sub 3 (CO) sub 11 (SMe sub 2 ) and (HRuRh sub 3 (CO) sub 9 ) sub 2 (SMe sub 2 ) sub 3

    SciTech Connect (OSTI)

    Rossi, S.; Pursianinen, J.; Ahlgren, M.; Pakkanen, T.A. (Univ. of Joensuu (Finland))

    1990-02-01

    Ligand substitution reactions of dimethyl sulfide with mixed-metal clusters are described. The clusters HRuCo{sub 3}(CO){sub 11}(SMe{sub 2}) (1) and (HRuRh{sub 3}(CO){sub 9}){sub 2}(SMe{sub 2}){sub 3} (2) have been prepared by reactions of SMe{sub 2} with the neutral parent clusters. Their crystal structures have been established: 1, monoclinic, space group P2{sub 1}/n, a = 11.459 (5) {angstrom}, b = 12.484 (4) {angstrom}, c = 14.384 (4) {angstrom}, {beta} = 96.40 (3){degree}, Z = 4; 2, trigonal, space group R3c, a = 13.181 (7) {angstrom}, {alpha} = 75.54 (5){degree}, Z = 2. Dimethyl sulfide coordinates terminally as a two-electron donor on basal cobalt in 1 and as a bridging four-electron donor causing unusual dimerization of clusters in 2. The carbonyl arrangement of the parent clusters was not changed during the ligand substitution, and hydride ligands bridge the three basal metals in both compounds.

  8. Assignment of the luminescing states of [Au{sup 1}Rh{sup 1}({sup t}BuNC){sub 2}({mu}-dppm){sub 2}][PF{sub 6}]{sub 2}

    SciTech Connect (OSTI)

    Striplin, D.R.; Crosby, G.A.

    1995-07-13

    Fluorescence, phosphorescence, and excitation spectra were measured on the title compound. These results were augmented with polarization ratios obtained at 77 K and detailed studies of the temperature dependence of the phosphorescence in the 77-4 K range. The phosphorescence decay rate at K was also recorded as a function of an applied magnetic field. All the results are consistent with a 4d{sub z}Rh{sup 1} {yields} 6p{sub 2}Au{sup 1} orbital promotion leading to emitting {sup 1}A, {sup 3}A{sub 1} terms in pseudo-C{sub 2v} symmetry. The {sup 3}A{sub 1} term is split by spin-orbit coupling into a forbidden A{sub 2} state lying lowest followed by a quasi-degenerate pair, [B{sub 1}(x), B{sub 2}(y)] lying approximately 16 cm{sup -1} higher that decays >500 times faster than the lowest one. 28 refs., 6 figs.

  9. Paducah Community Relations Plan

    Broader source: Energy.gov [DOE]

    The Paducah Community Relations Plan is a primary document of the FFA that directs the comprehensive remediation of the PGDP site. The Paducah CRP describes how DOE will provide opportunities for...

  10. Measurement uncertainty relations

    SciTech Connect (OSTI)

    Busch, Paul; Lahti, Pekka; Werner, Reinhard F.

    2014-04-15

    Measurement uncertainty relations are quantitative bounds on the errors in an approximate joint measurement of two observables. They can be seen as a generalization of the error/disturbance tradeoff first discussed heuristically by Heisenberg. Here we prove such relations for the case of two canonically conjugate observables like position and momentum, and establish a close connection with the more familiar preparation uncertainty relations constraining the sharpness of the distributions of the two observables in the same state. Both sets of relations are generalized to means of order ? rather than the usual quadratic means, and we show that the optimal constants are the same for preparation and for measurement uncertainty. The constants are determined numerically and compared with some bounds in the literature. In both cases, the near-saturation of the inequalities entails that the state (resp. observable) is uniformly close to a minimizing one.

  11. Community Relations Plan

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Community Relations Plan Community Relations Plan The Laboratory maintains an open working relationship with communities and interested members of the public. August 1, 2013 Guests listen to Lab historian Ellen McGhee on tour of historical sites Guests listen to Laboratory historian Ellen McGhee on a tour of historical sites. What the plan does Establishes a productive government-to-government relationship with local tribes and pueblos Keeps communities and interested members of the public

  12. WIPP - Related FOIA Sites

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FOIA Reading Room DOE Headquarters FOIA Program Department of Justice (DOJ) Office of Information and Privacy Records that have been released in response to multiple written requests for information under the FOIA or are likely to be requested again: Current Contracts Expired Contracts Other Documents Final opinions made in the adjudication of cases DOE Directives, Regulations, and Standards Other WIPP Related Documents

  13. Bay Ridge Gardens - Mixed Humid Affordable Multifamily Housing Deep Energy Retrofit: Annapolis, Maryland. Building America Case Study: Whole-House Solutions for Existing Homes (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-10-01

    Under this project, Newport Partners (as part of the BA-PIRC research team) evaluated the installation, measured performance, and cost-effectiveness of efficiency upgrade measures for a tenant-in-place DER at the Bay Ridge multifamily (MF) development in Annapolis, Maryland. The design and construction phase of the Bay Ridge project was completed in August 2012. This report summarizes system commissioning, short-term test results, utility bill data analysis, and analysis of real-time data collected over a one-year period after the retrofit was complete. The Bay Ridge project is comprised of a "base scope" retrofit which was estimated to achieve a 30%+ savings (relative to pre-retrofit) on 186 apartments, and a "DER scope" which was estimated to achieve 50% savings (relative to pre-retrofit) on a 12-unit building. The base scope was applied to the entire apartment complex, except for one 12-unit building which underwent the DER scope. A wide range of efficiency measures was applied to pursue this savings target for the DER building, including improvements/replacements of mechanical equipment and distribution systems, appliances, lighting and lighting controls, the building envelope, hot water conservation measures, and resident education. The results of this research build upon the current body of knowledge of multifamily retrofits. Towards this end, the research team has collected and generated data on the selection of measures, their estimated performance, their measured performance, and risk factors and their impact on potential measures.

  14. SNL Community Relations Plan

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RESOURCE CONSERVATION AND RECOVERY ACT FACILITY OPERATING PERMIT COMMUNITY RELATIONS PLAN SANDIA NATIONAL LABORATORIES, NEW MEXICO AUGUST 2015 United States Department of Energy National Nuclear Security Administration Sandia Field Office Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract

  15. The dynamic shape factor of sodium chloride nanoparticles as regulated by drying rate

    SciTech Connect (OSTI)

    Wang, Z.; Lewis, E.; King, S. M.; Freney, E.; Rosenoern, T.; Smith, M.; Chen, Q.; Kuwata, M.; Poschl, U.; Wang, W.; Buseck, P. R.; Martin, S. T.

    2010-09-01

    The influence of drying rate on the dynamic shape factor {chi} of NaCl particles was investigated. The drying rate at the efflorescence relative humidity (ERH) of 45% was controlled in a laminar flow tube and varied from 5.5 {+-} 0.9 to 101 {+-} 3 RH s{sup -1} at ERH, where RH represents one percent unit of relative humidity. Dry particles having mobility diameters of 23-84 nm were studied, corresponding to aqueous particles of 37-129 nm at the RH (57%) prior to drying. At each mobility diameter and drying rate, the critical supersaturation of cloud-condensation activation was also measured. The mobility diameter and the critical supersaturation were combined in an analysis to determine the value of {chi}. The measured values varied from 1.02 to 1.26. For fixed particle diameter the {chi} value decreased with increasing drying rate. For fixed drying rate, a maximum occurred in {chi} between 35- and 40-nm dry mobility diameter, with a lower {chi} for both smaller and larger particles. The results of this study, in conjunction with the introduced apparatus for obtaining quantified drying rates, can allow the continued development of a more detailed understanding of the morphology of submicron salt particles, with the potential for the follow-on development of quantitative modeling of evaporation and crystal growth at these dimensions.

  16. Community Relations Plan Update

    Office of Legacy Management (LM)

    8-TAR MAC-MRAP 1.9.1 Monticello Mill Tailings Superfund Site and Monticello Vicinity Properties Superfund Site Monticello, Utah Community Relations Plan Update FY 2001 Prepared for U.S. Department of Energy Albuquerque Operations Office Grand Junction Office Prepared by MACTEC Environmental Restoration Services, LLC Grand Junction, Colorado Work performed under DOE Contract No. DE-AC13-96GJ87335 for the U.S. Department of Energy For more information or to request additional copies of this

  17. 2.01.16 RH Plasmonics - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... DE-SC0004993). Calculations in this work used the National Energy Research Scientific Computing Center, a DOE Office of Science User Facility supported by the Office of Science of ...

  18. IPP RH-TRU Waste Study - Summary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary This study was prepared by the Department in fulfillment of a congressional mandate specified in Public Law 102-579, referred to as the Waste Isolation Pilot Plant Land Withdrawal Act. In addition, the Department considers the preparation of the study to be a prudent element in the compliance certification process for the Waste Isolation Pilot Plant (WIPP). The study includes an analysis of the impact of remote-handled Transuranic waste on the performance assessment of the WIPP and a

  19. 15.11.21 RH Methanol - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    an electrochemical reduction of carbon dioxide exclusively to methanol Javier, A. et al. Overlayer Au-on-W Near-Surface Alloy for the Selective Electrochemical Reduction of CO2 to Methanol: Empirical (DEMS) Corroboration of a Computational (DFT) Prediction. Electrocatalysis, DOI: 10.1007/s12678-015-0276-8 (2015). With kind permission from Springer Science+Business Media: Javier, A. et al. Overlayer Au-on-W Near-Surface Alloy for the Selective Electrochemical Reduction of carbon dioxide to

  20. 15.12.03 RH Assembly - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Assembly and Photocarrier Dynamics of Heterostructured Nanocomposite Photoanodes from Multicomponent Colloidal Nanocrystals Loiudice, A. et al. Assembly and Photocarrier Dynamics of Heterostructured Nanocomposite Photoanodes from Multicomponent Colloidal Nanocrystals. Nano Letters (2015), DOI: 10.1021/acs.nanolett.5b03871 (2015). Scientific Achievement Multicomponent oxides and their heterostructures were assembled with broad synthetic tunability. A combination of transient absorption

  1. 15.12.04 RH Motifs - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Detailed investigation of the role of surface motifs on the behavior of p-wse2 photocathodes Velazquez, J. M. et al. A Scanning Probe Investigation of the Role of Surface Motifs in the Behavior of p-WSe2Photocathodes. Energy & Environmental Science, DOI: 10.1039/C5EE02530C (2015). Scientific Achievement Detailed investigation of microscopic terraces in p-WSe2 single-crystal photocathode revealed these to be major sites of performance losses, challenging the traditionally accepted paradigm

  2. 15.12.04 RH Screening - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How can theory help with rapid screening of promising photocatalysts in solvent? JCAP scientists are developing novel theoretical methods to predict the effect that solvents have on material properties - and consequently the photoelectrochemical performance - inside solar-fuels generators. Inside a working integrated device that uses solar energy to convert carbon dioxide and water into fuels, chemical reactions occur on solid-liquid interfaces, where the solid is a photocatalyst and the liquid

  3. Labor-Management Relations (LMR)

    Broader source: Energy.gov [DOE]

    Department of Energy (DOE) Labor Management Relations (LMR), provides direction and oversight of the Departments labor-management relations programs and appraises the effectiveness of DOE labor...

  4. Documents Related to the ICP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Financial Assistance & Solicitations > ICP Contract > Documents Related ICP Blue Line Free Acrobat Reader Link The documents listed below are related to the Idaho Cleanup...

  5. wang-98.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    October 1993 include humidity reports at RH<20% and at temperatures lower than -40 C (Wade 1994). Another purpose of this study is to investigate the relationship between water...

  6. Insights into accelerated aging of SSL luminaires

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Davis, J. Lynn; Lamvik, Michael; Bittle, James; Shepherd, Sarah; Yaga, Robert; Baldasaro, Nick; Solano, Eric; Bobashev, Georgiy

    2013-09-30

    Although solid-state lighting (SSL) products are often intended to have product lifetimes of 15 years or more, the rapid change in technology has created a need for accelerated life tests (ALTs) that can be performed in the span of several months. A critical element of interpreting results from any systems-level ALT is understanding of the impact of the test environment on each component. Because of its ubiquity in electronics, the use of temperature-humidity environments as potential ALTs for SSL luminaires was investigated. Results from testing of populations of three commercial 6” downlights in environments of 85oC and 85% relative humiditymore » (RH) and 75oC and 75% RH are reported. These test environments were found to accelerate lumen depreciation of the entire luminaire optical system, including LEDs, lenses, and reflectors. The effects of aging were found to depend strongly on both the optical materials that were used and the design of the luminaire; this shows that the lumen maintenance behavior of SSL luminaires must be addressed at the optical systems level. Temperature-Humidity ALTs can be a useful test in understand lumainaire depreciation provided that proper consideration is given to the different aging rates of various materials. Since the impact of the temperature-humidity environment varies among components of the optical system, uniform aging of all system components in a single test is difficult to achieve.« less

  7. Tower Temperature and Humidity Sensors (TWR) Handbook

    SciTech Connect (OSTI)

    Cook, DR

    2010-02-01

    Three tall towers are installed at the Atmospheric Radiation Measurement (ARM) Climate Research Facility: a 60-meter triangular tower at the Southern Great Plains (SGP) Central Facility (CF), a 21-meter walkup scaffolding tower at the SGP Okmulgee forest site (E21), and a 40-meter triangular tower at the North Slope of Alaska (NSA) Barrow site. The towers are used for meteorological, radiological, and other measurements.

  8. Comparing Wind, Temperature, Pressure, and Humidity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is of the highest resolution for a ground based weather station. This activity is for classes to compare data from three very different places in the world, and may be used in...

  9. Harvard Bounce Apparatus GoAmazon 2014/15 Field Campaign Report (Technical

    Office of Scientific and Technical Information (OSTI)

    Report) | SciTech Connect SciTech Connect Search Results Technical Report: Harvard Bounce Apparatus GoAmazon 2014/15 Field Campaign Report Citation Details In-Document Search Title: Harvard Bounce Apparatus GoAmazon 2014/15 Field Campaign Report The effect of relative humidity (RH) on the physical state of particulate matter during the GoAmazon 2014/15 campaign was investigated through the use of particle rebound (or lack thereof) during impaction. The physics governing particle rebound have

  10. Transparent hydrogel with enhanced water retention capacity by introducing highly hydratable salt

    SciTech Connect (OSTI)

    Bai, Yuanyuan; Xiang, Feng; Wang, Hong E-mail: suo@seas.harvard.edu; Chen, Baohong; Zhou, Jinxiong; Suo, Zhigang E-mail: suo@seas.harvard.edu

    2014-10-13

    Polyacrylamide hydrogels containing salt as electrolyte have been used as highly stretchable transparent electrodes in flexible electronics, but those hydrogels are easy to dry out due to water evaporation. Targeted, we try to enhance water retention capacity of polyacrylamide hydrogel by introducing highly hydratable salts into the hydrogel. These hydrogels show enhanced water retention capacity in different level. Specially, polyacrylamide hydrogel containing high content of lithium chloride can retain over 70% of its initial water even in environment with relative humidity of only 10% RH. The excellent water retention capacities of these hydrogels will make more applications of hydrogels become possible.

  11. Liquid-liquid phase separation in aerosol particles: Imaging at the Nanometer Scale

    SciTech Connect (OSTI)

    O'Brien, Rachel; Wang, Bingbing; Kelly, Stephen T.; Lundt, Nils; You, Yuan; Bertram, Allan K.; Leone, Stephen R.; Laskin, Alexander; Gilles, Mary K.

    2015-04-21

    Atmospheric aerosols can undergo phase transitions including liquid-liquid phase separation (LLPS) while responding to changes in the ambient relative humidity (RH). Here, we report results of chemical imaging experiments using environmental scanning electron microscopy (ESEM) and scanning transmission x-ray microscopy (STXM) to investigate the LLPS of micron sized particles undergoing a full hydration-dehydration cycle. Internally mixed particles composed of ammonium sulfate (AS) and either: limonene secondary organic carbon (LSOC), a, 4-dihydroxy-3-methoxybenzeneaceticacid (HMMA), or polyethylene glycol (PEG-400) were studied. Events of LLPS with apparent core-shell particle morphology were observed for all samples with both techniques. Chemical imaging with STXM showed that both LSOC/AS and HMMA/AS particles were never homogeneously mixed for all measured RHs above the deliquescence point and that the majority of the organic component was located in the shell. The shell composition was estimated as 65:35 organic: inorganic in LSOC/AS and as 50:50 organic: inorganic for HMMA/AS. PEG-400/AS particles showed fully homogeneous mixtures at high RH and phase separated below 89-92% RH with an estimated 50:50% organic to inorganic mix in the shell. These two chemical imaging techniques are well suited for in-situ analysis of the hygroscopic behavior, phase separation, and surface composition of collected ambient aerosol particles.

  12. JLF Facility-related Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Facility-related Publications Europa Janus Titan Title Author Source Date Title Author Source Date Title Author Source Date...

  13. Entropic uncertainty relations and entanglement

    SciTech Connect (OSTI)

    Guehne, Otfried; Lewenstein, Maciej

    2004-08-01

    We discuss the relationship between entropic uncertainty relations and entanglement. We present two methods for deriving separability criteria in terms of entropic uncertainty relations. In particular, we show how any entropic uncertainty relation on one part of the system results in a separability condition on the composite system. We investigate the resulting criteria using the Tsallis entropy for two and three qubits.

  14. Microbial Gas Generation Under Expected Waste Isolation Pilot Plant Repository Conditions: Final Report

    SciTech Connect (OSTI)

    Gillow, J.B.; Francis, A.

    2011-07-01

    Gas generation from the microbial degradation of the organic constituents of transuranic (TRU) waste under conditions expected in the Waste Isolation Pilot Plant (WIPP) was investigated. The biodegradation of mixed cellulosic materials and electron-beam irradiated plastic and rubber materials (polyethylene, polyvinylchloride, hypalon, leaded hypalon, and neoprene) was examined. We evaluated the effects of environmental variables such as initial atmosphere (air or nitrogen), water content (humid ({approx}70% relative humidity, RH) and brine inundated), and nutrient amendments (nitogen phosphate, yeast extract, and excess nitrate) on microbial gas generation. Total gas production was determined by pressure measurement and carbon dioxide (CO{sub 2}) and methane (CH{sub 4}) were analyzed by gas chromatography; cellulose degradation products in solution were analyzed by high-performance liquid chromatography. Microbial populations in the samples were determined by direct microscopy and molecular analysis. The results of this work are summarized.

  15. Related Links | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Related Links Related Links Private, public, and nonprofit organizations around the country offer a wide range of courses and other services to help you either improve your current skills or learn new ones. The sites featured here can help you find courses of specific interest as well as other information about training requirements for certain energy jobs. DOE Related Advanced Manufacturing Office: Training Find training sessions in your area and learn how to save energy in your manufacturing

  16. Related Links | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Development WINDExchange Financial Opportunities Information Resources Publications Wind Vision Energy Basics Wind Energy FAQs Small Wind Systems FAQs Multimedia Related Links News

  17. Documents Related to the INL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Financial Assistance & Solicitations > INL Contract > Documents Related INL Blue Line Free Acrobat Reader Link The documents listed below represent an electronic copy of...

  18. Stability of CIGS Solar Cells and Component Materials Evaluated by a Step-Stress Accelerated Degradation Test Method: Preprint

    SciTech Connect (OSTI)

    Pern, F. J.; Noufi, R.

    2012-10-01

    A step-stress accelerated degradation testing (SSADT) method was employed for the first time to evaluate the stability of CuInGaSe2 (CIGS) solar cells and device component materials in four Al-framed test structures encapsulated with an edge sealant and three kinds of backsheet or moisture barrier film for moisture ingress control. The SSADT exposure used a 15oC and then a 15% relative humidity (RH) increment step, beginning from 40oC/40%RH (T/RH = 40/40) to 85oC/70%RH (85/70) as of the moment. The voluminous data acquired and processed as of total DH = 3956 h with 85/70 = 704 h produced the following results. The best CIGS solar cells in sample Set-1 with a moisture-permeable TPT backsheet showed essentially identical I-V degradation trend regardless of the Al-doped ZnO (AZO) layer thickness ranging from standard 0.12 ?m to 0.50 ?m on the cells. No clear 'stepwise' feature in the I-V parameter degradation curves corresponding to the SSADT T/RH/time profile was observed. Irregularity in I-V performance degradation pattern was observed with some cells showing early degradation at low T/RH < 55/55 and some showing large Voc, FF, and efficiency degradation due to increased series Rs (ohm-cm2) at T/RH ? 70/70. Results of (electrochemical) impedance spectroscopy (ECIS) analysis indicate degradation of the CIGS solar cells corresponded to increased series resistance Rs (ohm) and degraded parallel (minority carrier diffusion/recombination) resistance Rp, capacitance C, overall time constant Rp*C, and 'capacitor quality' factor (CPE-P), which were related to the cells? p-n junction properties. Heating at 85/70 appeared to benefit the CIGS solar cells as indicated by the largely recovered CPE-P factor. Device component materials, Mo on soda lime glass (Mo/SLG), bilayer ZnO (BZO), AlNi grid contact, and CdS/CIGS/Mo/SLG in test structures with TPT showed notable to significant degradation at T/RH ? 70/70. At T/RH = 85/70, substantial blistering of BZO layers on CIGS cell pieces was observed that was not seen on BZO/glass, and a CdS/CIGS sample displayed a small darkening and then flaking feature. Additionally, standard AlNi grid contact was less stable than thin Ni grid contact at T/RH ? 70/70. The edge sealant and moisture-blocking films were effective to block moisture ingress, as evidenced by the good stability of most CIGS solar cells and device components at T/RH = 85/70 for 704 h, and by preservation of the initial blue color on the RH indicator strips. The SSADT experiment is ongoing to be completed at T/RH = 85/85.

  19. LTS Related Links - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Related Links About Us LTS Home Page LTS Project Management LTS Transition and Timeline LTS Execution LTS Background LTS Information Management LTS Fact Sheets / Briefings LTS In The News LTS Related Links LTS Contact Us LTS Related Links Email Email Page | Print Print Page |Text Increase Font Size Decrease Font Size Hanford Site Cleanup Completion Framework (DOE/RL 2009-10) (PDF) Hanford Long-Term Stewardship Program Plan (DOE/RL 2010-35) (PDF) DOE-EM LTS Site Legacy Management CERCLA 5 Year

  20. NREL: Energy Analysis - Related Links

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Related Links Here you'll find links to other programs, organizations, and information resources concerning other analysis capabilities, energy-modeling, and technology expertise related to renewable energy. International Applications NREL's International Program in its effort to promote the use of renewable energy as a tool for sustainable development, applies world-class expertise in technology development and deployment, economic analysis, resource assessment, project design and

  1. Communications and Media Relations Group

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Communications and Media Relations Group Public Affairs Communications Community Public Affairs Org Chart Education Creative Services ⇒ Navigate Section Public Affairs Communications Community Public Affairs Org Chart Education Creative Services Berkeley Lab's Communications and Media Relations Group is responsible for gathering, reporting, and disseminating news about the Lab to both internal and external audiences, including employees, the media, and the community. The latest news can be

  2. Energy-related manpower, 1985

    SciTech Connect (OSTI)

    Not Available

    1986-01-01

    This report provides information about current and potential employment requirements and the relative adequacy of labor supplies for energy R and D and commercial energy activities, with special attention to scientific and engineering personnel. Since the oil embargo of 1973, major domestic and international changes have occurred in economies, political relationships, and energy production, markets, and prices. These changes, with concurrent modification in federal policy emphasis and programs, have altered energy production, conservation, and R and D activities sufficiently to affect employment requirements and educational needs. This is the fourth annual energy-related manpower report. It provides basic information for both public and private policymakers, educators, legislators, program managers, and others concerned with the labor market for scientists and engineers. It also provides information about future job opportunities for those interested in energy-related careers.

  3. Documents Related to the ICP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Idaho Cleanup Project (ICP) Core Contract No. DE-EM0004083 You are here: DOE-ID Home > Contracts, Financial Assistance & Solicitations > ICP-Core Contract > Documents Related ICP-Core Contract Blue Line Free Acrobat Reader Link The documents listed below are related to the Idaho Cleanup Project (ICP) Core contract. These documents are in PDF format. The Adobe� Reader is required to access them. If you do not currently have the Acrobat Reader, you may download the Reader FREE by

  4. Documents Related to the ICP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SPECTRA TECH, INC. Contract No. DE-EM0003976 You are here: DOE-ID Home > Contracts, Financial Assistance & Solicitations > STI Contract > Documents Related STI Blue Line Free Acrobat Reader Link The documents listed below are related to the Spectra Tech, Inc. (STI) contract. These documents are in PDF format. The Adobe� Reader is required to access them. If you do not currently have the Acrobat Reader, you may download the Reader FREE by clicking on the icon at left. Blue Line

  5. Radiation Exposure Monitoring Systems - Other Related Sites ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Radiation Exposure Monitoring Systems - Other Related Sites Radiation Exposure Monitoring Systems - Other Related Sites Other Related Sites DOE - Main Home Page - the home page for ...

  6. COGR Council on Governmental Relations

    Energy Savers [EERE]

    COGR COUNCIL ON GOVERNMENTAL RELATIONS an organization of research universities 1200 New York Avenue, N.W., Suite 750, Washington, D.C. 20005 (202) 289-6655/(202) 289-6698 (FAX) BOARD OF DIRECTORS CHAIR DAVID WYNES Emory University MICHAEL AMEY The Johns Hopkins University JAMES BARBRET Wayne State University ELAINE BROCK University of Michigan SUSAN CAMBER University of Washington MICHELLE CHRISTY Massachusetts Institute of Technology KELVIN DROEGEMEIER University of Oklahoma CHARLES LOUIS

  7. Epistemology and Rosen's Modeling Relation

    SciTech Connect (OSTI)

    Dress, W.B.

    1999-11-07

    Rosen's modeling relation is embedded in Popper's three worlds to provide an heuristic tool for model building and a guide for thinking about complex systems. The utility of this construct is demonstrated by suggesting a solution to the problem of pseudo science and a resolution of the famous Bohr-Einstein debates. A theory of bizarre systems is presented by an analogy with entangled particles of quantum mechanics. This theory underscores the poverty of present-day computational systems (e.g., computers) for creating complex and bizarre entities by distinguishing between mechanism and organism.

  8. Statistically significant relational data mining :

    SciTech Connect (OSTI)

    Berry, Jonathan W.; Leung, Vitus Joseph; Phillips, Cynthia Ann; Pinar, Ali; Robinson, David Gerald; Berger-Wolf, Tanya; Bhowmick, Sanjukta; Casleton, Emily; Kaiser, Mark; Nordman, Daniel J.; Wilson, Alyson G.

    2014-02-01

    This report summarizes the work performed under the project (3z(BStatitically significant relational data mining.(3y (BThe goal of the project was to add more statistical rigor to the fairly ad hoc area of data mining on graphs. Our goal was to develop better algorithms and better ways to evaluate algorithm quality. We concetrated on algorithms for community detection, approximate pattern matching, and graph similarity measures. Approximate pattern matching involves finding an instance of a relatively small pattern, expressed with tolerance, in a large graph of data observed with uncertainty. This report gathers the abstracts and references for the eight refereed publications that have appeared as part of this work. We then archive three pieces of research that have not yet been published. The first is theoretical and experimental evidence that a popular statistical measure for comparison of community assignments favors over-resolved communities over approximations to a ground truth. The second are statistically motivated methods for measuring the quality of an approximate match of a small pattern in a large graph. The third is a new probabilistic random graph model. Statisticians favor these models for graph analysis. The new local structure graph model overcomes some of the issues with popular models such as exponential random graph models and latent variable models.

  9. Associations of indoor carbon dioxide concentrations and environmental susceptibilities with mucous membrane and lower respiratory building related symptoms in the BASE study: Analyses of the 100 building dataset

    SciTech Connect (OSTI)

    Erdmann, Christine A.; Apte, Michael G.

    2003-09-01

    Using the US EPA 100 office-building BASE Study dataset, they conducted multivariate logistic regression analyses to quantify the relationship between indoor CO{sub 2} concentrations (dCO{sub 2}) and mucous membrane (MM) and lower respiratory system (LResp) building related symptoms, adjusting for age, sex, smoking status, presence of carpet in workspace, thermal exposure, relative humidity, and a marker for entrained automobile exhaust. In addition, they tested the hypothesis that certain environmentally-mediated health conditions (e.g., allergies and asthma) confer increased susceptibility to building related symptoms within office buildings. Adjusted odds ratios (ORs) for statistically significant, dose-dependent associations (p < 0.05) for dry eyes, sore throat, nose/sinus congestion, and wheeze symptoms with 100 ppm increases in dCO{sub 2} ranged from 1.1 to 1.2. These results suggest that increases in the ventilation rates per person among typical office buildings will, on average, reduce the prevalence of several building related symptoms by up to 70%, even when these buildings meet the existing ASHRAE ventilation standards for office buildings. Building occupants with certain environmentally-mediated health conditions are more likely to experience building related symptoms than those without these conditions (statistically significant ORs ranged from 2 to 11).

  10. Experimental Tests of Special Relativity

    ScienceCinema (OSTI)

    Roberts, Tom [Illinois Institute of Technology, Chicago, Illinois, United States

    2009-09-01

    Over the past century Special Relativity has become a cornerstone of modern physics, and its Lorentz invariance is a foundation of every current fundamental theory of physics. So it is crucial that it be thoroughly tested experimentally. The many tests of SR will be discussed, including several modern high-precision measurements. Several experiments that appear to be in conflict with SR will also be discussed, such as claims that the famous measurements of Michelson and Morley actually have a non-null result, and the similar but far more extensive measurements of Dayton Miller that 'determined the absolute motion of the earth'. But the errorbars for these old experiments are huge, and are larger than their purported signals. In short, SR has been tested extremely well and stands un-refuted today, but current thoughts about quantum gravity suggest that it might not truly be a symmetry of nature.

  11. Environment on the Surfaces of the Drip Shield and Waste Package Outer Barrier

    SciTech Connect (OSTI)

    T. Wolery

    2005-02-22

    This report provides supporting analysis of the conditions at which an aqueous solution can exist on the drip shield or waste package surfaces, including theoretical underpinning for the evolution of concentrated brines that could form by deliquescence or evaporation, and evaluation of the effects of acid-gas generation on brine composition. This analysis does not directly feed the total system performance assessment for the license application (TSPA-LA), but supports modeling and abstraction of the in-drift chemical environment (BSC 2004 [DIRS 169863]; BSC 2004 [DIRS 169860]). It also provides analyses that may support screening of features, events, and processes, and input for response to regulatory inquiries. This report emphasizes conditions of low relative humidity (RH) that, depending on temperature and chemical conditions, may be dry or may be associated with an aqueous phase containing concentrated electrolytes. Concentrated solutions at low RH may evolve by evaporative concentration of water that seeps into emplacement drifts, or by deliquescence of dust on the waste package or drip shield surfaces. The minimum RH for occurrence of aqueous conditions is calculated for various chemical systems based on current understanding of site geochemistry and equilibrium thermodynamics. The analysis makes use of known characteristics of Yucca Mountain waters and dust from existing tunnels, laboratory data, and relevant information from the technical literature and handbooks.

  12. Performance of a Cross-Flow Humidifier with a High Flux Water Vapor Transport Membrane

    SciTech Connect (OSTI)

    Ahluwalia, R. K.; Wang, X.; Johnson, W. B.; Berg, F.; Kadylak, D.

    2015-09-30

    Water vapor transport (WVT) flux across a composite membrane that consists of a very thin perfluorosulfonic acid (PFSA) ionomer layer sandwiched between two expanded polytetrafluoroethylene (PTFE) microporous layers is investigated. Static and dynamic tests are conducted to measure WVT flux for different composite structures; a transport model shows that the underlying individual resistances for water diffusion in the gas phase and microporous and ionomer layers and for interfacial kinetics of water uptake at the ionomer surface are equally important under different conditions. A finite-difference model is formulated to determine water transport in a full-scale (2-m2 active membrane area) planar cross-flow humidifier module assembled using pleats of the optimized composite membrane. In agreement with the experimental data, the modeled WVT flux in the module increases at higher inlet relative humidity (RH) of the wet stream and at lower pressures, but the mass transfer effectiveness is higher at higher pressures. The model indicates that the WVT flux is highest under conditions that maintain the wet stream at close to 100% RH while preventing the dry stream from becoming saturated. The overall water transport is determined by the gradient in RH of the wet and dry streams but is also affected by vapor diffusion in the gas layer and the microporous layer.

  13. Sub-micrometre Particulate Matter is Primarily in Liquid Form over Amazon Rainforests

    SciTech Connect (OSTI)

    Bateman, Adam P.; Gong, Z. H.; Liu, Pengfei; Sato, Bruno; Cirino, Glauber; Zhang, Yue; Artaxo, Paulo; Bertram, Allan K.; Manzi, A.; Rizzo, L. V.; Souza, Rodrigo A.; Zaveri, Rahul A.; Martin, Scot T.

    2016-01-01

    Particulate matter (PM) occurs in the Earth’s atmosphere both in liquid and non-liquid forms. The physical state affects the available physical and chemical mechanisms of growth and reactivity, ultimately affecting the number, size, and composition of the atmospheric particle population. Herein, the physical state, including the response to relative humidity (RH), was investigated on-line and in real time for PM (< 1 μm) over the tropical rain forest of central Amazonia during both the wet and dry seasons of 2013. The results show that the PM was liquid for RH > 80% across 296 to 300 K. These results, in conjunction with the distributions of RH and temperature in Amazonia, imply that near-surface submicron PM in Amazonia is liquid most of the time. The observations are consistent with laboratory experiments showing that PM produced by isoprene photo-oxidation is liquid across these meteorological conditions. The findings have implications for the mechanisms of new particle production in Amazonia, the growth of submicron particles and hence dynamics of the cloud life cycle, and the sensitivity of these processes to anthropogenic activities. An approach for inclusion of particle physical state in chemical transport models is presented.

  14. Alternative Fuels Data Center: Biodiesel Related Links

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biodiesel Printable Version Share this resource Send a link to Alternative Fuels Data Center: Biodiesel Related Links to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Related Links on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Related Links on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Related Links on Google Bookmark Alternative Fuels Data Center: Biodiesel Related Links on Delicious Rank Alternative Fuels Data Center: Biodiesel Related Links

  15. Alternative Fuels Data Center: Ethanol Related Links

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Printable Version Share this resource Send a link to Alternative Fuels Data Center: Ethanol Related Links to someone by E-mail Share Alternative Fuels Data Center: Ethanol Related Links on Facebook Tweet about Alternative Fuels Data Center: Ethanol Related Links on Twitter Bookmark Alternative Fuels Data Center: Ethanol Related Links on Google Bookmark Alternative Fuels Data Center: Ethanol Related Links on Delicious Rank Alternative Fuels Data Center: Ethanol Related Links on Digg Find

  16. Alternative Fuels Data Center: Hydrogen Related Links

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Hydrogen Printable Version Share this resource Send a link to Alternative Fuels Data Center: Hydrogen Related Links to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Related Links on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Related Links on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Related Links on Google Bookmark Alternative Fuels Data Center: Hydrogen Related Links on Delicious Rank Alternative Fuels Data Center: Hydrogen Related Links on

  17. Alternative Fuels Data Center: Propane Related Links

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Propane Printable Version Share this resource Send a link to Alternative Fuels Data Center: Propane Related Links to someone by E-mail Share Alternative Fuels Data Center: Propane Related Links on Facebook Tweet about Alternative Fuels Data Center: Propane Related Links on Twitter Bookmark Alternative Fuels Data Center: Propane Related Links on Google Bookmark Alternative Fuels Data Center: Propane Related Links on Delicious Rank Alternative Fuels Data Center: Propane Related Links on Digg Find

  18. Alternative Fuels Data Center: Related Links

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Tools Printable Version Share this resource Send a link to Alternative Fuels Data Center: Related Links to someone by E-mail Share Alternative Fuels Data Center: Related Links on Facebook Tweet about Alternative Fuels Data Center: Related Links on Twitter Bookmark Alternative Fuels Data Center: Related Links on Google Bookmark Alternative Fuels Data Center: Related Links on Delicious Rank Alternative Fuels Data Center: Related Links on Digg Find More places to share Alternative Fuels Data

  19. Energy-Related Carbon Emissions in Manufacturing

    Reports and Publications (EIA)

    2000-01-01

    Energy-related carbon emissions in manufacturing analysis and issues related to the energy use, energy efficiency, and carbon emission indicators.

  20. International Relations Specialist | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    International Relations Specialist International Relations Specialist Submitted by admin on Tue, 2016-05-10 18:01 Job Summary Organization Name Department Of Energy Agency ...

  1. Energy-Related Carbon Emissions in Manufacturing

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Energy-Related Carbon Emissions Detailed Energy-Related Carbon Emissions All Industry Groups 1994 emissions Selected Industries Petroleum refining Chemicals Iron & Steel...

  2. US NRC-Sponsored Research on Stress Corrosion Cracking Susceptibility of Dry Storage Canister Materials in Marine Environments - 13344

    SciTech Connect (OSTI)

    Oberson, Greg; Dunn, Darrell; Mintz, Todd; He, Xihua; Pabalan, Roberto; Miller, Larry

    2013-07-01

    At a number of locations in the U.S., spent nuclear fuel (SNF) is maintained at independent spent fuel storage installations (ISFSIs). These ISFSIs, which include operating and decommissioned reactor sites, Department of Energy facilities in Idaho, and others, are licensed by the U.S. Nuclear Regulatory Commission (NRC) under Title 10 of the Code of Federal Regulations, Part 72. The SNF is stored in dry cask storage systems, which most commonly consist of a welded austenitic stainless steel canister within a larger concrete vault or overpack vented to the external atmosphere to allow airflow for cooling. Some ISFSIs are located in marine environments where there may be high concentrations of airborne chloride salts. If salts were to deposit on the canisters via the external vents, a chloride-rich brine could form by deliquescence. Austenitic stainless steels are susceptible to chloride-induced stress corrosion cracking (SCC), particularly in the presence of residual tensile stresses from welding or other fabrication processes. SCC could allow helium to leak out of a canister if the wall is breached or otherwise compromise its structural integrity. There is currently limited understanding of the conditions that will affect the SCC susceptibility of austenitic stainless steel exposed to marine salts. NRC previously conducted a scoping study of this phenomenon, reported in NUREG/CR-7030 in 2010. Given apparent conservatisms and limitations in this study, NRC has sponsored a follow-on research program to more systematically investigate various factors that may affect SCC including temperature, humidity, salt concentration, and stress level. The activities within this research program include: (1) measurement of relative humidity (RH) for deliquescence of sea salt, (2) SCC testing within the range of natural absolute humidity, (3) SCC testing at elevated temperatures, (4) SCC testing at high humidity conditions, and (5) SCC testing with various applied stresses. Results to date indicate that the deliquescence RH for sea salt is close to that of MgCl{sub 2} pure salt. SCC is observed between 35 and 80 deg. C when the ambient (RH) is close to or higher than this level, even for a low surface salt concentration. (authors)

  3. Method for early detection of cooling-loss events

    SciTech Connect (OSTI)

    Bermudez, Sergio A.; Hamann, Hendrik; Marianno, Fernando J.

    2015-06-30

    A method of detecting cooling-loss event early is provided. The method includes defining a relative humidity limit and change threshold for a given space, measuring relative humidity in the given space, determining, with a processing unit, whether the measured relative humidity is within the defined relative humidity limit, generating a warning in an event the measured relative humidity is outside the defined relative humidity limit and determining whether a change in the measured relative humidity is less than the defined change threshold for the given space and generating an alarm in an event the change is greater than the defined change threshold.

  4. Method for early detection of cooling-loss events

    SciTech Connect (OSTI)

    Bermudez, Sergio A.; Hamann, Hendrik F.; Marianno, Fernando J.

    2015-12-22

    A method of detecting cooling-loss event early is provided. The method includes defining a relative humidity limit and change threshold for a given space, measuring relative humidity in the given space, determining, with a processing unit, whether the measured relative humidity is within the defined relative humidity limit, generating a warning in an event the measured relative humidity is outside the defined relative humidity limit and determining whether a change in the measured relative humidity is less than the defined change threshold for the given space and generating an alarm in an event the change is greater than the defined change threshold.

  5. Public Health-Related Impacts of Climate Change inCalifornia

    SciTech Connect (OSTI)

    Drechsler, D.M.; Motallebi, N.; Kleeman, M.; Cayan, D.; Hayhoe,K.; Kalkstein, L.S.; Miller, N.L.; Jin, J.; VanCuren, R.A.

    2005-12-01

    In June 2005 Governor Arnold Schwarzenegger issued Executive Order S-3-05 that set greenhouse gas emission reduction targets for California, and directed the Secretary of the California Environmental Protection Agency to report to the governor and the State legislature by January 2006 and biannually thereafter on the impacts to California of global warming, including impacts to water supply, public health, agriculture, the coastline, and forestry, and to prepare and report on mitigation and adaptation plans to combat these impacts. This report is a part of the report to the governor and legislature, and focuses on public health impacts that have been associated with climate change. Considerable evidence suggests that average ambient temperature is increasing worldwide, that temperatures will continue to increase into the future, and that global warming will result in changes to many aspects of climate, including temperature, humidity, and precipitation (McMichael and Githeko, 2001). It is expected that California will experience changes in both temperature and precipitation under current trends. Many of the changes in climate projected for California could have ramifications for public health (McMichael and Githeko, 2001), and this document summarizes the impacts judged most likely to occur in California, based on a review of available peer-reviewed scientific literature and new modeling and statistical analyses. The impacts identified as most significant to public health in California include mortality and morbidity related to temperature, air pollution, vector and water-borne diseases, and wildfires. There is considerable complexity underlying the health of a population with many contributing factors including biological, ecological, social, political, and geographical. In addition, the relationship between climate change and changes in public health is difficult to predict for the most part, although more detailed information is available on temperature-related mortality and air pollution effects than the other endpoints discussed in this document. Consequently, these two topics are discussed in greater detail. Where possible, estimates of the magnitude and significance of these impacts are also discussed, along with possible adaptations that could reduce climate-related health impacts. In the context of this review, weather refers to meteorological conditions at a specific place and time over a relatively short time frame, such as up to a year or two. Climate, on the other hand, refers to the same meteorological conditions, but over a longer time frame, such as decades or centuries.

  6. Fire Protection Related Sites | Department of Energy

    Energy Savers [EERE]

    Related Sites Fire Protection Related Sites DOE-Related Fire Safety Web Sites EFCOG - Fire Protection Working Group Headquarter's Office of Science Brookhaven National Laboratory Hanford Fire Department Non-DOE Government-Related Web Sites Consumer Product Safety Commission (CPSC) Occupational Safety & Health Administration (OSHA) U.S. Nuclear Regulatory Commission (NRC) U.S. Environmental Protection Agency EPA Federal Emergency Management Agency (FEMA) National Fire Academy Other Related

  7. Alternative Fuels Data Center: Electricity Related Links

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Electricity Printable Version Share this resource Send a link to Alternative Fuels Data Center: Electricity Related Links to someone by E-mail Share Alternative Fuels Data Center: Electricity Related Links on Facebook Tweet about Alternative Fuels Data Center: Electricity Related Links on Twitter Bookmark Alternative Fuels Data Center: Electricity Related Links on Google Bookmark Alternative Fuels Data Center: Electricity Related Links on Delicious Rank Alternative Fuels Data Center: Electricity

  8. RPP Environmental Permits and Related Documentation

    SciTech Connect (OSTI)

    DEXTER, M.L.

    1999-10-04

    This document contains the current list of environmental permits and related documentation for TWRS facilities and activities.

  9. RPP Environmental Permits and Related Documentation

    SciTech Connect (OSTI)

    DEXTER, M.L.

    2000-11-29

    This document contains the current list of environmental permits and related documentation for TWRS facilities and activities.

  10. RPP Environmental Permits and Related Documentation

    SciTech Connect (OSTI)

    DEXTER, M.L.

    2000-01-17

    This document contains the current list of environmental permits and related documentation for TWRS facilities and activities.

  11. RPP Environmental Permits and Related Documentation

    SciTech Connect (OSTI)

    DEXTER, M.L.

    1999-08-04

    This document contains the current list of environmental permits and related documentation for TWRS facilities and activities.

  12. Related Financial Opportunities | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Related Financial Opportunities Related Financial Opportunities The U.S. Department of Energy's (DOE's) Hydrogen and Fuel Cells Program is a partnership among four DOE program offices: Energy Efficiency and Renewable Energy, Fossil Energy, Nuclear Energy, and Science. These DOE offices provide useful hydrogen-related financial opportunity information. Other federal organizations, including the Department of Defense, also offer funding opportunities for hydrogen-related technologies. The Hydrogen

  13. 15.08.28 RH Novel Photoanodes - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... DE-SC0004993). Computational work is supported by the Materials Project Predictive Modeling Center (EDCBEE) through the U.S. Department of Energy, Office of Basic Energy Sciences, ...

  14. WIPP RH-TRU Waste Study - Notice To Users

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Notice To Users The NTP World Wide Web (WWW) server is provided as a service of the Department of Energy for distribution of publicly available information and is maintained by the Waste Isolation Pilot Plant (WIPP). NTP is an agency of the Federal Government of the United States of America. Use of NTP WWW server is intended only for the retrieval of information available through NTP WWW documents. Only authorized WIPP administrators may make changes to the information. This document could not

  15. 16.02.11 RH 10 Device - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Introduction Why Solar Fuels? Goals & Objectives Thrusts Thrust 1 Thrust 2 Thrust 3 Thrust 4 Library Publications Research Highlights Videos Resources User Facilities Expert Team Benchmarking Database Device Simulation Tool XPS Spectral Database Efficient Solar-Driven Hydrogen-generating Device Featuring Protected Photoelectrochemical Assembly with Earth-abundant Catalysts Verlage, E. et al. A Monolithically Integrated, Intrinsically Safe, 10% Efficient, Solar-Driven Water-Splitting

  16. 15.07.10 RH P-type Transparent - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Efficient and Stable Solar Water Oxidation Chen, L. et al. p -Type Transparent Conducting Oxide n-Type Semiconductor Heterojunctions for Efficient and Stable ...

  17. 14.05.14 RH Synchrotron X-ray - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High-Throughput Synchrotron X-Ray Experimentation for Combinatorial Phase Matching Gregoire, J. M. et al. High-throughput synchrotron X-ray diffraction for combinatorial phase mapping. Journal of Synchrotron Radiation 21, 1262-1268, DOI: 10.1107/s1600577514016488 (2014). Scientific Achievement Development of new synchrotron X-ray diffraction and fluorescence methods for rapid characterization of material libraries. Significance & impact First demonstration of prototype facility capable of

  18. 14.11.05 RH Stabilized Si Microwire - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stabilized Si Microwire Arrays for Solar-Driven H2O Oxidation Shaner, M. R., Hu, S., Sun, K. & Lewis, N. S. Stabilization of Si microwire arrays for solar-driven H2O oxidation to O2(g) in 1.0 M KOH(aq) using conformal coatings of amorphous TiO2. Energy & Environmental Science 8, 203-207, DOI: 10.1039/c4ee03012e (2015). Scientific Achievement Atomic-layer deposition of TiO2combined with sputtering of NiCrOxoxygen-evolution catalyst on Si microwires yields robust microwire-array

  19. 14.12.16 RH Hot Carrier - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hot-Carrier Generation from Plasmon Decay in Energy Conversion Sundararaman , R., Narang, P., Jermyn, A. S., Goddard, W. A. & Atwater, H. A. Theoretical predictions for hot-carrier generation from surface plasmo decay. Nature Communications 5, 8, DOI: 10.1038/ncomms6788 (2014). Scientific Achievement First theoretical study combining plasmon modes with density functional theory to predict initial energy distribution of hot carriers in real metals. Significance & impact Understanding the

  20. 15.01.05 RH High OER - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Origin of High OER Activity in Ni/Fe Oxyhydroxides Friebel , D. et al. Identification of highly active Fe sites in (Ni,Fe)OOH for electrocatalytic water splitting. Journal of the American Chemical Society 137, 1305-1313, DOI: 10.1021/ja511559d (2015). Scientific Achievement Operando X-ray techniques and density-functional theory (DFT) are used to understand the effect of Fe on the performance of the oxygen-evolving reaction (OER) Ni1-xFexOOH catalysts. Significance & impact With excellent

  1. 15.01.16 RH Perovskite Solar Cells - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fabrication of High Efficiency Perovskite Solar Cells Li, Y., Cooper, J. K., Buonsanti, R., Giannini, G., Liu, Y., Toma, F. M. & Sharp, I. D. Fabrication of Planar Heterojunction Perovskite Solar Cells by Controlled Low-Pressure Vapor Annealing. J. Phys. Chem. Lett ., 6, 493-499, DOI: 10.1021/jz502720a (2015). Scientific Achievement A new synthetic method based on low-pressure and reduced-temperature vapor annealing was developed and demonstrated to yield efficient hybrid halide perovskites

  2. 15.01.21 RH Computational and Experimental ID - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computational and Experimental Identification of an Earth-Abundant Light Absorber for Solar Water Splitting Yan, Q. et al. Mn2V2O7: An Earth Abundant Light Absorber for Solar Water Splitting. Advanced Energy Materials, DOI: 10.1002/aenm.201401840 (2015). Scientific Achievement Computation, synthesis, and spectroscopy are used to first identify and then study the earth-abundant Mn2V2O7 as a highly promising light absorber for photocatalytic water splitting. Significance & impact The detailed

  3. 15.02.10 RH Transparent Catalytic - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transparent Catalytic Nickel Oxide Protecting Films for Photoanodes Sun, K. et al. Stable solar-driven oxidation of water by semiconducting photoanodes protected by transparent catalytic nickel oxide films. PNAS 112 ( 12), 3612-3617, DOI: 10.1073/ pnas . 1423034112 (2015). Scientific Achievement Reactively sputtered NiOx layer provides a transparent, anti-reflective, conductive, chemically stable, inherently catalytic coating that stabilizes many efficient and technologically important

  4. 15.02.27 RH Unique Nanostructure - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Unique Nanostructure Revealed in New OER Electrocatalyst Haber, J. A., Anzenburg, E., Yano, J., Kisielowski, C. & Gregoire, J. M. Multiphase Nanostructure of a Quinary Metal Oxide Electrocatalyst Reveals a New Direction for OER Electrocatalyst Design. Advanced Energy Materials, DOI: 10.1002/aenm.201402307 (2015). Scientific Achievement JCAP discovered a new electrocatalyst for the oxygen evolution reaction (OER) containing 5 elements: Ni, Fe, Co, Ce, and O. Further detailed investigation

  5. 15.03.03 RH Fe Elecrolyte - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effects of Fe Electrolyte Composition on Ni ( OH ) 2/NiOOH Structure and Oxygen Evolution Activity Klaus, S., Cai, Y., Louie, M. W., Trotochaud, L. & Bell, A. T. Effects of Fe Electrolyte Impurities on Ni ( OH ) 2/NiOOH Structure and Oxygen Evolution Activity. The Journal of Physical Chemistry C, 119 ( 13), 7243-7254, DOI: 10.1021/ acs . jpcc . 5b00105 (2015). Scientific Achievement Electrochemical characterization, in situ Raman spectroscopy, and quartz crystal microbalance measurements

  6. 15.05.29 RH Operando X-ray - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Observation of a Semiconductor/Liquid Junction by Operando X-Ray Photoelectron Spectroscopy (XPS) Lichterman , M. F. et al. Direct Observation of the Energetics at a Semiconductor/Liquid Junction by Operando X-Ray Photoelectron Spectroscopy. Energy Environ. Sci ., 2015, DOI: 10.1039/C5EE01014D (2015). Scientific Achievement We demonstrated that the operando XPS technique, applied to a semiconductor/liquid junction, can directly measure the positions of the electronic states of the

  7. 15.07.15 RH Interface Engineering - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Interface Engineering for Stable, High-Performance Photoanodes Zhou, X. et al. Interface Engineering of the Photoelectrochemical Performance of Ni-Oxide-Coated n-Si Photoanodes by Atomic-Layer Deposition of Ultrathin Films of Cobalt Oxide. Energy & Environmental Science, DOI: 10.1039/C5EE01687H (2015). Scientific Achievement We demonstrated that interfacial transition-metal oxide layers provide a route to stable, high-performance photoanodes for oxygen evolution in contact with aqueous 1 M

  8. 15.08.07 RH Si Microwire Photoanode - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A High-Performance Si Microwire Photocathode Coupled with Ni-Mo Catalyst Shaner, M. R., McKone, J. R., Gray, H. B. & Lewis, N. S. Functional integration of Ni-Mo electrocatalysts with i microwire array photocathodes to simultaneously achieve high fill factors and light-limited photocurrent densities for solar-driven hydrogen evolution. Energy & Environmental Science, DOI: 10.1039/C5EE01076D (2015). Scientific Achievement We have designed and demonstrated a H2-evolving Si microwire

  9. 15.09.28 RH Bandgap Tunability - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Band Gap Tunability in Sb-Alloyed BiVO4 Quaternary Oxides as Visible-Light Absorbers for Solar Fuel Applications Loiudice, A. et al. Bandgap Tunability in Sb-Alloyed BiVO4 Quaternary Oxides as Visible Light Absorbers for Solar Fuel Applications. Advanced Materials, DOI: 10.1002/adma.201502361 (2015). Scientific Achievement A novel hotoanode material was discovered using a colloidal nanocrystal (NC ) -seeded growth, that is of general applicability for other complex oxides and thus may aid in

  10. 03.01.16 RH Nickel-Gallium - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Introduction Why Solar Fuels? Goals & Objectives Thrusts Thrust 1 Thrust 2 Thrust 3 Thrust 4 Library Publications Research Highlights Videos Resources User Facilities Expert Team Benchmarking Database Device Simulation Tool XPS Spectral Database CO2 electrochemical reduction catalyzed by bimetallic materials at low overpotential Torelli, D. A., Francis, S.A. et al. Nickel-Gallium-Catalyzed Electrochemical Reduction of CO2 to Highly Reduced Products at Low Overpotentials. ACS

  11. Microsoft Word - MPUR_Feb2011_final_rh.docx

    Gasoline and Diesel Fuel Update (EIA)

    11 1 February 2011 Short-Term Energy Outlook Market Prices and Uncertainty Report 1 February 8, 2011 Release Crude Oil Prices. WTI crude oil spot prices averaged $89 per barrel in January, about the same as the December average, while over the same time period the estimated average cost of all crude oil to U.S. refineries increased by about $1 per barrel. Growing volumes of Canadian crude oil imported into the United States contributed to record-high storage levels at Cushing, Oklahoma, and a

  12. Fuel Cells Related Links | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cells » Fuel Cells Related Links Fuel Cells Related Links The following resources provide details about U.S. Department of Energy (DOE)-funded fuel cell activities, research plans and roadmaps, partnerships, and additional related links. DOE-Funded Fuel Cell Activities Each year, hydrogen and fuel cell projects funded by DOE's Hydrogen and Fuel Cells Program are reviewed for their merit during an Annual Merit Review and Peer Evaluation Meeting. View posters and presentations from the

  13. Hydrogen Delivery Related Links | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Delivery Related Links Hydrogen Delivery Related Links The following resources provide details about U.S. Department of Energy (DOE)-funded hydrogen delivery activities, research plans and roadmaps, models and tools, and additional related links. DOE-Funded Hydrogen Delivery Activities Each year, hydrogen and fuel cell projects funded by DOE's Hydrogen and Fuel Cells Program are reviewed for their merit during an Annual Merit Review and Peer Evaluation Meeting. View posters and

  14. Hydrogen Production Related Links | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production Related Links Hydrogen Production Related Links The following resources provide details about U.S. Department of Energy (DOE)-funded hydrogen production activities, research plans and roadmaps, models and tools, and additional related links. DOE-Funded Hydrogen Production Activities Each year, hydrogen and fuel cell projects funded by DOE's Hydrogen and Fuel Cells Program are reviewed for their merit during an Annual Merit Review and Peer Evaluation Meeting. View posters and

  15. Hydrogen Storage Related Links | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Related Links Hydrogen Storage Related Links The following resources provide details about U.S. Department of Energy (DOE)-funded hydrogen storage activities, research plans and roadmaps, models and tools, and additional related links. DOE-Funded Hydrogen Storage Activities Each year, hydrogen and fuel cell projects funded by DOE's Hydrogen and Fuel Cells Program are reviewed for their merit during an Annual Merit Review and Peer Evaluation Meeting. View posters and presentations from the latest

  16. The endotopism semigroups of an equivalence relation

    SciTech Connect (OSTI)

    Zhuchok, Yu V; Toichkina, E A

    2014-05-31

    In this work we investigate six types of endotopism semigroups for a given equivalence relation. Necessary and sufficient conditions for the existence of all such endotopisms are presented. Conditions for the regularity and coregularity of each of the endotopism semigroups of agiven type are established. The notion of the endotype of abinary relation with respect to its endotopisms is introduced and the endotype of an arbitrary equivalence relation is calculated. Bibliography: 26 titles.

  17. The General Theory of Relativity - F

    Office of Scientific and Technical Information (OSTI)

    ... The Evolution of Physics by Albert Einstein and Leopold Infeld Traces the main ideas of physics from Galileo to modern quantum theory in four chapters. Relativity theory, including ...

  18. The General Theory of Relativity - A

    Office of Scientific and Technical Information (OSTI)

    Einstein's special theory of relativity addressed the problem of the invariant speed of light in vacuum by showing the interrelationship of space and time. The general theory of ...

  19. Supercapacitor compositions, devices and related methods

    DOE Patents [OSTI]

    Gogotsi, Yury; Simon, Patrice; Largeot, Celine; Portet, Cristelle; Chmiola, John; Taberna, Pierre-Louis

    2013-07-30

    Disclosed are supercapacitor materials comprising compositions having pores that are optimally sized to maximize capacitance. Also disclosed are related methods for fabricating such supercapacitors.

  20. BC TIPS- Hot-Humid Climate: New Orleans

    Broader source: Energy.gov [DOE]

    Homes that provide substantial reductions in energy use and home-owner utility bills and recognizes the best practices for quality, comfort, health, and safety in the market.

  1. Expert Meeting: Recommended Approaches to Humidity Control in...

    Energy Savers [EERE]

    ... ASHRAE Transactions (17, Dallas 2007). American Society of Heating Refrigeration and Air-Conditioning Engineers, Atlanta, GA. Shirey, D.B.; Henderson, H.I.; and Raustad, R. (2006). ...

  2. Guides and Case Studies for Mixed-Humid Climates | Department...

    Broader source: Energy.gov (indexed) [DOE]

    homes features SIP walls, geothermal heat pumps, solar PV, and a proprietary energy management system. Project: Winchester Homes and Camberly Homes - Silver Spring...

  3. Impact of Vaisala Radiosonde Humidity Corrections on ARM IOP Data

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Impact of Teaming Arrangements on Small Business Status Impact of Teaming Arrangements on Small Business Status Impact of Teaming Arrangements on Small Business Status The Department of Energy is planning to set aside for small businesses a number of acquisitions of a very complex nature, requiring a myriad of capabilities on the part of offerors, which might result in teaming arrangements or joint ventures being formed. Given this, the Department believes that potential offerors

  4. J. Cherry & Sons: Hot, Humid climate Region 40+% Energy Savings

    SciTech Connect (OSTI)

    2009-08-13

    This case study describes highly efficient features of homes built by Cherry & Sons Home Builders in Port Saint Lucie, Florida.

  5. QA TG5 UV, temperature and humidity | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wednesday, Feb. 27, 2013, presented by David Miller, NREL PDF icon pvmrw13uvthnrelfraunhofermiller.pdf More Documents & Publications Hail Impact Testing on Crystalline Si ...

  6. Energy Efficient Crawlspace Foundation Retrofit: Mixed Humid Climate

    SciTech Connect (OSTI)

    Del Bianco, M.; Wiehagen, J.; Wood, A.

    2013-01-01

    Residential quality management systems have most often been designed for new home construction. To address quality in existing homes in the form of Scopes of Work (SOW), the NAHB Research Center began with a new construction scope of work and applied it to an existing home project. This document is intended to outline the steps of translating a new home construction SOW to SOW for retrofit.

  7. Compact Buried Ducts in a Hot-Humid Climate House

    SciTech Connect (OSTI)

    Mallay, D.

    2016-01-01

    A system of compact, buried ducts provides a high-performance and cost-effective solution for delivering conditioned air throughout the building. This report outlines research activities that are expected to facilitate adoption of compact buried duct systems by builders. The results of this research would be scalable to many new house designs in most climates and markets, leading to wider industry acceptance and building code and energy program approval.

  8. Performance Evaluation of a Hot-Humid Climate Community

    SciTech Connect (OSTI)

    Osser, R.; Kerrigan, P.

    2012-02-01

    This report describes the Project Home Again community in New Orleans, a new development for high-performance, affordable homes for residents who lost their homes to Hurricane Katrina. Building Science Corporation acted as a consultant for the project, advocating design strategies for durability, flood resistance, occupant comfort, and low energy use while maintaining cost effectiveness.

  9. Bay Ridge Gardens - Mixed Humid Affordable Multifamily Housing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pre-retrofit annual energy use (normalized): 28.4 kilowatt-hour per square foot (kWhft 2 ... efficiency * Solar thermal rooftop system; flat panel collector * Energy dashboard for ...

  10. Group 3: Humidity, Temperature, and Voltage | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Emerging Technologies Project for the 2013 Building Technologies Office's Program Peer Review PDF icon emrgtech16_liu_040313.pdf More Documents & Publications Three new/under-utilized ground loop designs being evaluated for their ground loop cost reduction potential<br /> Credit: Oak Ridge National Lab Advanced Ground Source Heat Pump Technology for Very-Low-Energy Buildings Oak Ridge City Center Technology Demonstration Project 4th U.S.-China Energy Efficiency Forum Documents

  11. Moisture and Ventilation Solutions in Hot, Humid Climates: Florida...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Photo of workers on the roof of a home. This Top Innovation profile describes research by ... Find more case studies of Building America projects across the country that demonstrate ...

  12. Humidity trends imply increased sensitivity to clouds in a warming...

    Office of Scientific and Technical Information (OSTI)

    at wavelengths that are semi-transparent to greenhouse gases, most notably water vapour. ... and variability in clouds14, water vapour15,16 and surface emission16,17 all ...

  13. Mercedes Homes: Hot, Humid Climate Region 40+% Energy Savings

    SciTech Connect (OSTI)

    2009-08-13

    This case study describes construction of a hurricane-resistant, energy efficient home that achieved 48% whole-house source energy savings over the Building America benchmark.

  14. Precise Relative Earthquake Magnitudes from Cross Correlation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cleveland, K. Michael; Ammon, Charles J.

    2015-04-21

    We present a method to estimate precise relative magnitudes using cross correlation of seismic waveforms. Our method incorporates the intercorrelation of all events in a group of earthquakes, as opposed to individual event pairings relative to a reference event. This method works well when a reliable reference event does not exist. We illustrate the method using vertical strike-slip earthquakes located in the northeast Pacific and Panama fracture zone regions. Our results are generally consistent with the Global Centroid Moment Tensor catalog, which we use to establish a baseline for the relative event sizes.

  15. Mechanical Models of Fault-Related Folding

    SciTech Connect (OSTI)

    Johnson, A. M.

    2003-01-09

    The subject of the proposed research is fault-related folding and ground deformation. The results are relevant to oil-producing structures throughout the world, to understanding of damage that has been observed along and near earthquake ruptures, and to earthquake-producing structures in California and other tectonically-active areas. The objectives of the proposed research were to provide both a unified, mechanical infrastructure for studies of fault-related foldings and to present the results in computer programs that have graphical users interfaces (GUIs) so that structural geologists and geophysicists can model a wide variety of fault-related folds (FaRFs).

  16. BEDES Related Projects | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Related Projects BEDES Related Projects The long-term vision is for a BEDES organization to review, support, and promote BEDES-compliant products. A key part of this effort will be to facilitate two different paths for compliance: through Mapping and Exchange, as shown in Table 1. Mapping compliance documents the relationships between the terms and definitions used in a product and the associated BEDES terms. Exchange compliance takes Mapping compliance one step further by establishing a schema

  17. Biochemical Conversion Related Links | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conversion » Biochemical Conversion Related Links Biochemical Conversion Related Links Further reading about current Bioenergy Technologies Office R&D in the Biochemical Platform can be found in this website's Information Resources section. Key publications will also be provided on this page. Using Fermentation and Catalysis to Make Fuels and Products: Biochemical Conversion (January 2011) Biochemical Conversion 2009 Peer Review Biochemical Production of Ethanol from Corn Stover: 2007 State

  18. Earl Salazar named LANL tribal relations liaison

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Earl Salazar LANL's new tribal relations liaison Earl Salazar named LANL tribal relations liaison Previously a budget analyst for LANL's Chief Financial Officer Division, Salazar began working in his new capacity on August 22. August 25, 2011 Earl Salazar Earl Salazar Contact Communications Office Email Longtime employee is former tribal pueblo governor LOS ALAMOS, New Mexico, August 25, 2011-Earl Salazar is Los Alamos National Laboratory's new tribal liaison in the Government Affairs Office.

  19. Feedstock Related Links | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research & Development » Feedstocks » Feedstock Related Links Feedstock Related Links There are a variety of other resources available for information on biomass feedstocks. We have organized some of those resources into the following categories: Other DOE Offices and Federal Agencies Department of Energy (DOE) Office of Science Biological and Environmental Research (BER) Biofuels Mission Focus DOE Office of Science BER Bioenergy Research Centers U.S. Department of Agriculture (USDA) 2007

  20. Related Sites | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Related Sites Related Sites Links to the following sources of information are provided as resources. Listings are obtained from government, industry and trade organizations and from other resources. Government System for Award Management The System for Award Management (SAM) (formerly Central Contractor Registration-CCR) is the main database used by the U.S. Government for collection, validation, storage and dissemination of data in support of agency acquisition missions. DOE Small Business Site

  1. Related Financial Opportunities | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Related Financial Opportunities Related Financial Opportunities The sites below provide access to energy efficiency and renewable energy financial incentives and solicitations offered by the U.S. Department of Energy (DOE) and other federal, state, local, and non-government agencies. Office of Energy Efficiency and Renewable Energy The Office of Energy Efficiency and Renewable Energy (EERE) provides information on financial opportunities for energy efficiency and renewable energy projects for

  2. Field Derived Emission Factors For Formaldehyde and other Volatile Organic Compounds in FEMA Temporary Housing Units

    SciTech Connect (OSTI)

    Parthasarathy, Srinandini; Maddalena, Randy L.; Russell, Marion L.; Apte, Michael G.

    2010-10-01

    Sixteen previously occupied temporary housing units (THUs) were studied to assess emissions of volatile organic compounds. The whole trailer emission factors wereevaluated for 36 VOCs including formaldehyde. Indoor sampling was carried out in the THUs located in Purvis staging yard in Mississippi, USA. Indoor temperature andrelative humidity (RH) were also measured in all the trailers during sampling. Indoor temperatures were varied (increased or decreased) in a selection of THUs using theheating, ventilation and air conditioning (HVAC) systems. Indoor temperatures during sampling ranged from 14o C to 33o C, and relative humidity (RH) varied between 35percentand 74percent. Ventilation rates were increased in some trailers using bathroom fans and vents during some of the sampling events. Ventilation rates measured during some aselection of sampling events varied from 0.14 to 4.3 h-1. Steady state indoor formaldehyde concentrations ranged from 10 mu g-m-3 to 1000 mu g-m-3. The formaldehyde concentrations in the trailers were of toxicological significance. The effects of temperature, humidity and ventilation rates were also studied. A linearregression model was built using log of percentage relative humidity, inverse of temperature (in K-1), and inverse log ACH as continuous independent variables, trailermanufacturer as a categorical independent variable, and log of the chemical emission factors as the dependent variable. The coefficients of inverse temperature, log relativehumidity, log inverse ACH with log emission factor were found to be statistically significant for all the samples at the 95percent confidence level. The regression model wasfound to explain about 84percent of the variation in the dependent variable. Most VOC concentrations measured indoors in the Purvis THUs were mostly found to be belowvalues reported in earlier studies by Maddalena et al.,1,2 Hodgson et al.,3 and Hippelein4. Emissions of TMPB-DIB (a plasticizer found in vinyl products) were found to be higher than values reported in comparable housing by Hodgson et al.,3. Emissions of phenol were also found to be slightly higher than values reported in earlier studies1,2,3. This study can assist in retrospective formaldehyde exposure assessments of THUs where estimates of the occupants indoor formaldehyde exposures are needed.

  3. Determination of the Relative Amount of Fluorine in Uranium Oxyfluoride Particles using Secondary Ion Mass Spectrometry and Optical Spectroscopy

    SciTech Connect (OSTI)

    Kips, R; Kristo, M J; Hutcheon, I D; Amonette, J; Wang, Z; Johnson, T; Gerlach, D; Olsen, K B

    2009-05-29

    Both nuclear forensics and environmental sampling depend upon laboratory analysis of nuclear material that has often been exposed to the environment after it has been produced. It is therefore important to understand how those environmental conditions might have changed the chemical composition of the material over time, particularly for chemically sensitive compounds. In the specific case of uranium enrichment facilities, uranium-bearing particles stem from small releases of uranium hexafluoride, a highly reactive gas that hydrolyzes upon contact with moisture from the air to form uranium oxyfluoride (UO{sub 2}F{sub 2}) particles. The uranium isotopic composition of those particles is used by the International Atomic Energy Agency (IAEA) to verify whether a facility is compliant with its declarations. The present study, however, aims to demonstrate how knowledge of time-dependent changes in chemical composition, particle morphology and molecular structure can contribute to an even more reliable interpretation of the analytical results. We prepared a set of uranium oxyfluoride particles at the Institute for Reference Materials and Measurements (IRMM, European Commission, Belgium) and followed changes in their composition, morphology and structure with time to see if we could use these properties to place boundaries on the particle exposure time in the environment. Because the rate of change is affected by exposure to UV-light, humidity levels and elevated temperatures, the samples were subjected to varying conditions of those three parameters. The NanoSIMS at LLNL was found to be the optimal tool to measure the relative amount of fluorine in individual uranium oxyfluoride particles. At PNNL, cryogenic laser-induced time-resolved U(VI) fluorescence microspectroscopy (CLIFS) was used to monitor changes in the molecular structure.

  4. Using EnergyPlus to Perform Dehumidification Analysis on Building America Homes

    SciTech Connect (OSTI)

    Fang, Xia; Winkler, Jon; Christensen, Dane

    2011-03-01

    This study used EnergyPlus to investigate humidity issues on a typical mid-1990s reference home, a 2006 International Energy Conservation Code home, and a high-performance home in a hot-humid climate; the study confirmed that supplemental dehumidification should be provided to maintain space relative humidity below 60% in a hot-humid climate.

  5. On the initial state and consistency relations

    SciTech Connect (OSTI)

    Berezhiani, Lasha; Khoury, Justin E-mail: jkhoury@sas.upenn.edu

    2014-09-01

    We study the effect of the initial state on the consistency conditions for adiabatic perturbations. In order to be consistent with the constraints of General Relativity, the initial state must be diffeomorphism invariant. As a result, we show that initial wavefunctional/density matrix has to satisfy a Slavnov-Taylor identity similar to that of the action. We then investigate the precise ways in which modified initial states can lead to violations of the consistency relations. We find two independent sources of violations: i) the state can include initial non-Gaussianities; ii) even if the initial state is Gaussian, such as a Bogoliubov state, the modified 2-point function can modify the q-vector ?0 analyticity properties of the vertex functional and result in violations of the consistency relations.

  6. Department of Energy Labor Relations and Standards

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2014-02-06

    The change would be to remove Chapter I, Labor Relations, and Chapter II Labor Standards from DOE O 350.1 and develop DOE O DOE O 350.3, which will cancel and supersede Chapters I and II in DOE O 350.1. Content of the two chapters will be updated to reflect the Secretarial determination transferring functions for contractor labor relations and labor standards from the Office of Legacy Management to the Office of General Counsel. CRDs for those chapters will also be removed.

  7. Quantum theory and Einstein's general relativity

    SciTech Connect (OSTI)

    v. Borzeszkowski, H.; Treder, H.

    1982-11-01

    We dicusss the meaning and prove the accordance of general relativity, wave mechanics, and the quantization of Einstein's gravitation equations themselves. Firstly, we have the problem of the influence of gravitational fields on the de Broglie waves, which influence is in accordance with Einstein's weak principle of equivalence and the limitation of measurements given by Heisenberg's uncertainty relations. Secondly, the quantization of the gravitational fields is a ''quantization of geometry.'' However, classical and quantum gravitation have the same physical meaning according to limitations of measurements given by Einstein's strong principle of equivalence and the Heisenberg uncertainties for the mechanics of test bodies.

  8. Council on Foreign Relations | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Council on Foreign Relations Council on Foreign Relations January 13, 2005 - 9:47am Addthis Remarks Prepared for Energy Secretary Abraham Thank you. It's an honor to be here with you today. For over 80 years the Council has played a leading role in guiding American foreign policy. As Leslie Gelb once said, "If the Council as a body has stood for anything ... it has been for American internationalism based on American interests." This body has not just stood for American

  9. Wireless, relative-motion computer input device

    DOE Patents [OSTI]

    Holzrichter, John F.; Rosenbury, Erwin T.

    2004-05-18

    The present invention provides a system for controlling a computer display in a workspace using an input unit/output unit. A train of EM waves are sent out to flood the workspace. EM waves are reflected from the input unit/output unit. A relative distance moved information signal is created using the EM waves that are reflected from the input unit/output unit. Algorithms are used to convert the relative distance moved information signal to a display signal. The computer display is controlled in response to the display signal.

  10. Centrifugal separator devices, systems and related methods

    DOE Patents [OSTI]

    Meikrantz, David H.; Law, Jack D.; Garn, Troy G.; Todd, Terry A.; Macaluso, Lawrence L.

    2012-03-20

    Centrifugal separator devices, systems and related methods are described. More particularly, fluid transfer connections for a centrifugal separator system having support assemblies with a movable member coupled to a connection tube and coupled to a fixed member, such that the movable member is constrained to movement along a fixed path relative to the fixed member are described. Also, centrifugal separator systems including such fluid transfer connections are described. Additionally, methods of installing, removing and/or replacing centrifugal separators from centrifugal separator systems are described.

  11. Clark Atlanta Universities (CAU) Energy Related Research Capabilities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Clark Atlanta Universities (CAU) Energy Related Research Capabilities Clark Atlanta Universities (CAU) Energy Related Research Capabilities How energy related research has helped ...

  12. Evaluation of two Vaisala RS92 radiosonde solar radiative dry bias correction algorithms

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dzambo, A. M.; Turner, D. D.; Mlawer, E. J.

    2015-10-20

    Solar heating of the relative humidity (RH) probe on Vaisala RS92 radiosondes results in a large dry bias in the upper troposphere. Two different algorithms (Miloshevich et al., 2009, MILO hereafter; and Wang et al., 2013, WANG hereafter) have been designed to account for this solar radiative dry bias (SRDB). These corrections are markedly different with MILO adding up to 40 % more moisture to the original radiosonde profile than WANG; however, the impact of the two algorithms varies with height. The accuracy of these two algorithms is evaluated using three different approaches: a comparison of precipitable water vapor (PWV),moredownwelling radiative closure with a surface-based microwave radiometer at a high-altitude site (5.3 km MSL), and upwelling radiative closure with the space-based Atmospheric Infrared Sounder (AIRS). The PWV computed from the uncorrected and corrected RH data is compared against PWV retrieved from ground-based microwave radiometers at tropical, mid-latitude, and arctic sites. Although MILO generally adds more moisture to the original radiosonde profile in the upper troposphere compared to WANG, both corrections yield similar changes to the PWV, and the corrected data agree well with the ground-based retrievals. The two closure activities done for clear-sky scenes use the radiative transfer models MonoRTM and LBLRTM to compute radiance from the radiosonde profiles to compare against spectral observations. Both WANG- and MILO-corrected RH are statistically better than original RH in all cases except for the driest 30 % of cases in the downwelling experiment, where both algorithms add too much water vapor to the original profile. In the upwelling experiment, the RH correction applied by the WANG vs. MILO algorithm is statistically different above 10 km for the driest 30 % of cases and above 8 km for the moistest 30 % of cases, suggesting that the MILO correction performs better than the WANG in clear-sky scenes. The cause of this statistical significance is likely explained by the fact the WANG correction also accounts for cloud cover a condition not accounted for in the radiance closure experiments.less

  13. Effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events

    SciTech Connect (OSTI)

    Quan, Jiannong; Liu, Yangang; Liu, Quan; Li, Xia; Gao, Yang; Jia, Xingcan; Sheng, Jiujiang

    2015-09-30

    In this study, the effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events was investigated by analysis of comprehensive measurements of aerosol composition and concentrations [e.g., particular matters (PM2.5), nitrate (NO3), sulfate (SO4), ammonium (NH4)], gas-phase precursors [e.g., nitrogen oxides (NOx), sulfur dioxide (SO2), and ozone (O3)], and relevant meteorological parameters [e.g., visibility and relative humidity (RH)]. The measurements were conducted in Beijing, China from Sep. 07, 2012 to Jan. 16, 2013. The results show that the conversion ratios of N from NOx to nitrate (Nratio) and S from SO2 to sulfate (Sratio) both significantly increased in haze events, suggesting enhanced conversions from NOx and SO2 to their corresponding particle phases in the late haze period. Further analysis shows that Nratio and Sratio increased with increasing RH, with Nratio and Sratio being only 0.04 and 0.03, respectively, when RH < 40%, and increasing up to 0.16 and 0.12 when RH reached 60–80%, respectively. The enhanced conversion ratios of N and S in the late haze period is likely due to heterogeneous aqueous reactions, because solar radiation and thus the photochemical capacity are reduced by the increases in aerosols and RH. This point was further affirmed by the relationships of Nratio and Sratio to O3: the conversion ratios increase with decreasing O3 concentration when O3 concentration is lower than <15 ppb but increased with increasing O3 when O3 concentration is higher than 15 ppb. The results suggest that heterogeneous aqueous reactions likely changed aerosols and their precursors during the haze events: in the beginning of haze events, the precursor gases accumulated quickly due to high emission and low reaction rate; the occurrence of heterogeneous aqueous reactions in the late haze period, together with the accumulated high concentrations of precursor gases such as SO2 and NOx, accelerated the formation of secondary inorganic aerosols, and led to rapid increase of the PM2.5 concentration.

  14. Effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Quan, Jiannong; Liu, Yangang; Liu, Quan; Li, Xia; Gao, Yang; Jia, Xingcan; Sheng, Jiujiang

    2015-09-30

    In this study, the effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events was investigated by analysis of comprehensive measurements of aerosol composition and concentrations [e.g., particular matters (PM2.5), nitrate (NO3), sulfate (SO4), ammonium (NH4)], gas-phase precursors [e.g., nitrogen oxides (NOx), sulfur dioxide (SO2), and ozone (O3)], and relevant meteorological parameters [e.g., visibility and relative humidity (RH)]. The measurements were conducted in Beijing, China from Sep. 07, 2012 to Jan. 16, 2013. The results show that the conversion ratios of N from NOx to nitrate (Nratio) and S from SO2 to sulfate (Sratio) bothmore » significantly increased in haze events, suggesting enhanced conversions from NOx and SO2 to their corresponding particle phases in the late haze period. Further analysis shows that Nratio and Sratio increased with increasing RH, with Nratio and Sratio being only 0.04 and 0.03, respectively, when RH < 40%, and increasing up to 0.16 and 0.12 when RH reached 60–80%, respectively. The enhanced conversion ratios of N and S in the late haze period is likely due to heterogeneous aqueous reactions, because solar radiation and thus the photochemical capacity are reduced by the increases in aerosols and RH. This point was further affirmed by the relationships of Nratio and Sratio to O3: the conversion ratios increase with decreasing O3 concentration when O3 concentration is lower than <15 ppb but increased with increasing O3 when O3 concentration is higher than 15 ppb. The results suggest that heterogeneous aqueous reactions likely changed aerosols and their precursors during the haze events: in the beginning of haze events, the precursor gases accumulated quickly due to high emission and low reaction rate; the occurrence of heterogeneous aqueous reactions in the late haze period, together with the accumulated high concentrations of precursor gases such as SO2 and NOx, accelerated the formation of secondary inorganic aerosols, and led to rapid increase of the PM2.5 concentration.« less

  15. The effect of plutonium dioxide water surface coverage on the generation of hydrogen and oxygen

    SciTech Connect (OSTI)

    Veirs, Douglas K.; Berg, John M.; Crowder, Mark L.

    2012-06-20

    The conditions for the production of oxygen during radiolysis of water adsorbed onto plutonium dioxide powder are discussed. Studies in the literature investigating the radiolysis of water show that both oxygen and hydrogen can be generated from water adsorbed on high-purity plutonium dioxide powder. These studies indicate that there is a threshold in the amount of water below which oxygen is not generated. The threshold is associated with the number of monolayers of adsorbed water and is shown to occur at approximately two monolayers of molecularly adsorbed water. Material in equilibrium with 50% relative humidity (RH) will be at the threshold for oxygen generation. Using two monolayers of molecularly adsorbed water as the threshold for oxygen production, the total pressure under various conditions is calculated assuming stoichiometric production of hydrogen and oxygen. The specific surface area of the oxide has a strong effect on the final partial pressure. The specific surface areas resulting in the highest pressures within a 3013 container are evaluated. The potential for oxygen generation is mitigated by reduced relative humidity, and hence moisture adsorption, at the oxide surface which occurs if the oxide is warmer than the ambient air. The potential for oxygen generation approaches zero as the temperature difference between the ambient air and the material approaches 6 C.

  16. Removal of carbonyl sulfide using activated carbon adsorption

    SciTech Connect (OSTI)

    Sattler, M.L.; Rosenberk, R.S. [University of Texas, Arlington, TX (United States). Dept. for Civil & Environmental Engineering

    2006-02-15

    Wastewater treatment plant odors are caused by compounds such as hydrogen sulfide (H{sub 2}S), methyl mercaptans, and carbonyl sulfide (COS). One of the most efficient odor control processes is activated carbon adsorption; however, very few studies have been conducted on COS adsorption. COS is not only an odor causing compound but is also listed in the Clean Air Act as a hazardous air pollutant. Objectives of this study were to determine the following: (1) the adsorption capacity of 3 different carbons for COS removal; (2) the impact of relative humidity (RH) on COS adsorption; (3) the extent of competitive adsorption of COS in the presence of H{sub 2}S; and (4) whether ammonia injection would increase COS adsorption capacity. Vapor phase react (VPR; reactivated), BPL (bituminous coal-based), and Centaur (physically modified to enhance H{sub 2}S adsorption) carbons manufactured by Calgon Carbon Corp. were tested in three laboratory-scale columns. It was found that the adsorption capacity of Centaur carbon for COS was higher than the other two carbons, regardless of RH. As humidity increased, the percentage of decrease in adsorption capacity of Centaur carbon, however, was greater than the other two carbons. The carbon adsorption capacity for COS decreased in proportion to the percentage of H{sub 2}S in the gas stream. More adsorption sites appear to be available to H{sub 2}S, a smaller molecule. Ammonia, which has been found to increase H{sub 2}S adsorption capacity, did not increase the capacity for COS.

  17. Absolute and relative dosimetry for ELIMED

    SciTech Connect (OSTI)

    Cirrone, G. A. P.; Schillaci, F.; Scuderi, V.; Cuttone, G.; Candiano, G.; Musumarra, A.; Pisciotta, P.; Romano, F.; Carpinelli, M.; Presti, D. Lo; Raffaele, L.; Tramontana, A.; Cirio, R.; Sacchi, R.; Monaco, V.; Marchetto, F.; Giordanengo, S.

    2013-07-26

    The definition of detectors, methods and procedures for the absolute and relative dosimetry of laser-driven proton beams is a crucial step toward the clinical use of this new kind of beams. Hence, one of the ELIMED task, will be the definition of procedures aiming to obtain an absolute dose measure at the end of the transport beamline with an accuracy as close as possible to the one required for clinical applications (i.e. of the order of 5% or less). Relative dosimetry procedures must be established, as well: they are necessary in order to determine and verify the beam dose distributions and to monitor the beam fluence and the energetic spectra during irradiations. Radiochromic films, CR39, Faraday Cup, Secondary Emission Monitor (SEM) and transmission ionization chamber will be considered, designed and studied in order to perform a fully dosimetric characterization of the ELIMED proton beam.

  18. Cybersecurity Related Blogs | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Blogs Cybersecurity Related Blogs November 3, 2015 Power lines like these make up our nation's power grid -- a critical component of our national critical infrastructure. National Critical Infrastructure Security and Resilience Month: Improving the Security and Resilience of the Nation's Grid November is National Critical Infrastructure Security and Resilience Month, and our Office of Electricity (OE) is hard at work safeguarding the power grid. March 31, 2015 Encouraging Innovation for New

  19. Cybersecurity Related News | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    News Cybersecurity Related News October 6, 2014 New Article on Cybersecurity Discusses DOE's Partnership with the Energy Sector to Keep the Grid Reliable and Secure An article by OE's Carol Hawk and Akhlesh Kaushiva in The Electricity Journal discusses cybersecurity for the power grid and how DOE and the energy sector are partnering to keep the smart grid reliable and secure. April 28, 2014 Energy Department Releases New Guidance for Strengthening Cybersecurity of the Grid's Supply Chain

  20. Related Articles: 2009 Archive | Department of Energy

    Energy Savers [EERE]

    9 Archive Related Articles: 2009 Archive This page provides links to 2009 articles describing the latest developments in the area of solid-state lighting. Some of the following documents are available as Adobe Acrobat PDFs. December 2009 The Status of Solid-State Lighting Today James Brodrick, U.S. Department of Energy Electrical Construction & Maintenance Magazine http://www.ecmweb.com Lifetime Concerns James Brodrick, U.S. Department of Energy LD+A Magazine

  1. Related Links | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Related Links NNSA Lab Directed Research and Development (LDRD) Lab Directed Research and Development Collaborations DOE Adanced Scientific Computing Research DTRA (Defense Threat Reduction Agency) NAS (National Academy of Sciences) NSF (National Science Foundation) DOD (Department of Defense) NASA Exascale Activities NNSA Exascale Environment Planning Workshop ASCR Co-Design Centers Supercomputing Top 500 List ASC at Supercomputing Conference General Information ASC at the Labs How ASC Supports

  2. Tandem Differential Mobility Analyzer/Aerodynamic Particle Sizer (APS) Handbook

    SciTech Connect (OSTI)

    Collins, D

    2010-06-18

    The tandem differential mobility analyzer (TDMA) is a single instrument that cycles through a series of complementary measurements of the physical properties of size-resolved submicron particles. In 2008, the TDMA was augmented through the addition of an aerodynamic particle sizer (APS), which extends the upper limit of the measured size distribution into the supermicron range. These two instruments are operated in parallel, but because they are controlled by a common computer and because the size distributions measured by the two are integrated in the produced datastreams, they are described together here. Throughout the day, the TDMA sequentially measures submicron aerosol size distributions and size-resolved hygroscopic growth distributions. More specifically, the instrument is operated as a scanning DMA to measure size distributions and as a TDMA to measure size-resolved hygroscopicity. A typical measurement sequence requires roughly 45 minutes. Each morning additional measurements are made of the relative humidity (RH) dependent hygroscopicity and temperature-dependent volatility of size-resolved particles. When the outside temperature and RH are within acceptable ranges, the hydration state of size-resolved particles is also characterized. The measured aerosol distributions complement the array of aerosol instruments in the Aerosol Observing System (AOS) and provide additional details of the light-scattering and cloud-nucleating characteristics of the aerosol.

  3. Refueling machine with relative positioning capability

    DOE Patents [OSTI]

    Challberg, Roy Clifford; Jones, Cecil Roy

    1998-01-01

    A refueling machine having relative positioning capability for refueling a nuclear reactor. The refueling machine includes a pair of articulated arms mounted on a refueling bridge. Each arm supports a respective telescoping mast. Each telescoping mast is designed to flex laterally in response to application of a lateral thrust on the end of the mast. A pendant mounted on the end of the mast carries an air-actuated grapple, television cameras, ultrasonic transducers and waterjet thrusters. The ultrasonic transducers are used to detect the gross position of the grapple relative to the bail of a nuclear fuel assembly in the fuel core. The television cameras acquire an image of the bail which is compared to a pre-stored image in computer memory. The pendant can be rotated until the television image and the pre-stored image match within a predetermined tolerance. Similarly, the waterjet thrusters can be used to apply lateral thrust to the end of the flexible mast to place the grapple in a fine position relative to the bail as a function of the discrepancy between the television and pre-stored images.

  4. Refueling machine with relative positioning capability

    DOE Patents [OSTI]

    Challberg, R.C.; Jones, C.R.

    1998-12-15

    A refueling machine is disclosed having relative positioning capability for refueling a nuclear reactor. The refueling machine includes a pair of articulated arms mounted on a refueling bridge. Each arm supports a respective telescoping mast. Each telescoping mast is designed to flex laterally in response to application of a lateral thrust on the end of the mast. A pendant mounted on the end of the mast carries an air-actuated grapple, television cameras, ultrasonic transducers and waterjet thrusters. The ultrasonic transducers are used to detect the gross position of the grapple relative to the bail of a nuclear fuel assembly in the fuel core. The television cameras acquire an image of the bail which is compared to a pre-stored image in computer memory. The pendant can be rotated until the television image and the pre-stored image match within a predetermined tolerance. Similarly, the waterjet thrusters can be used to apply lateral thrust to the end of the flexible mast to place the grapple in a fine position relative to the bail as a function of the discrepancy between the television and pre-stored images. 11 figs.

  5. Star formation relations in nearby molecular clouds

    SciTech Connect (OSTI)

    Evans, Neal J. II; Heiderman, Amanda; Vutisalchavakul, Nalin

    2014-02-20

    We test some ideas for star formation relations against data on local molecular clouds. On a cloud by cloud basis, the relation between the surface density of star formation rate and surface density of gas divided by a free-fall time, calculated from the mean cloud density, shows no significant correlation. If a crossing time is substituted for the free-fall time, there is even less correlation. Within a cloud, the star formation rate volume and surface densities increase rapidly with the corresponding gas densities, faster than predicted by models using the free-fall time defined from the local density. A model in which the star formation rate depends linearly on the mass of gas above a visual extinction of 8 mag describes the data on these clouds, with very low dispersion. The data on regions of very massive star formation, with improved star formation rates based on free-free emission from ionized gas, also agree with this linear relation.

  6. Development of an Integrated Residential Heating, Ventilation, Cooling, and Dehumidification System for Residences

    SciTech Connect (OSTI)

    Hoeschele, M.A.; D.A. Springer

    2008-06-18

    The Need and the Opportunity Codes such as ASHRAE 90.2 and IECC, and programs such as Energy Star and Builders Challenge, are causing new homes to be built to higher performance standards. As a result sensible cooling loads in new homes are going down, but indoor air quality prerogatives are causing ventilation rates and moisture loads to increase in humid climates. Conventional air conditioners are unable to provide the low sensible heat ratios that are needed to efficiently cool and dehumidify homes since dehumidification potential is strongly correlated with cooling system operating hours. The project team saw an opportunity to develop a system that is at least as effective as a conventional air conditioner plus dehumidifier, removes moisture without increasing the sensible load, reduces equipment cost by integrating components, and simplifies installation. Project Overview Prime contractor Davis Energy Group led a team in developing an Integrated Heating, Ventilation, Cooling, and Dehumidification (I-HVCD) system under the DOE SBIR program. Phase I and II SBIR project activities ran from July 2003 through December 2007. Tasks included: (1) Mechanical Design and Prototyping; (2) Controls Development; (3) Laboratory and Field Testing; and (4) Commercialization Activities Technology Description. Key components of the prototype I-HVCD system include an evaporator coil assembly, return and outdoor air damper, and controls. These are used in conjunction with conventional components that include a variable speed air handler or furnace, and a two-stage condensing unit. I-HVCD controls enable the system to operate in three distinct cooling modes to respond to indoor temperature and relative humidity (RH) levels. When sensible cooling loads are high, the system operates similar to a conventional system but varies supply airflow in response to indoor RH. In the second mode airflow is further reduced, and the reheat coil adds heat to the supply air. In the third mode, the reheat coil adds additional heat to maintain the supply air temperature close to the return air temperature (100% latent cooling). Project Outcomes Key Phase II objectives were to develop a pre-production version of the system and to demonstrate its performance in an actual house. The system was first tested in the laboratory and subsequently underwent field-testing at a new house in Gainesville, Florida. Field testing began in 2006 with monitoring of a 'conventional best practices' system that included a two stage air conditioner and Energy Star dehumidifier. In September 2007, the I-HVCD components were installed for testing. Both systems maintained uniform indoor temperatures, but indoor RH control was considerably better with the I-HVCD system. The daily variation from average indoor humidity conditions was less than 2% for the I-HVCD vs. 5-7% for the base case system. Data showed that the energy use of the two systems was comparable. Preliminary installed cost estimates suggest that production costs for the current I-HVCD integrated design would likely be lower than for competing systems that include a high efficiency air conditioner, dehumidifier, and fresh air ventilation system. Project Benefits This project verified that the I-HVCD refrigeration compacts are compact (for easy installation and retrofit) and can be installed with air conditioning equipment from a variety of manufacturers. Project results confirmed that the system can provide precise indoor temperature and RH control under a variety of climate conditions. The I-HVCD integrated approach offers numerous benefits including integrated control, easier installation, and reduced equipment maintenance needs. Work completed under this project represents a significant step towards product commercialization. Improved indoor RH control and fresh air ventilation are system attributes that will become increasingly important in the years ahead as building envelopes improve and sensible cooling loads continue to fall. Technologies like I-HVCD will be instrumental in meeting goals set by Building America

  7. Space nuclear power, propulsion, and related technologies.

    SciTech Connect (OSTI)

    Berman, Marshall

    1992-01-01

    Sandia National Laboratories (Sandia) is one of the nation's largest research and development (R&D) facilities, with headquarters at Albuquerque, New Mexico; a laboratory at Livermore, California; and a test range near Tonopah, Nevada. Smaller testing facilities are also operated at other locations. Established in 1945, Sandia was operated by the University of California until 1949, when, at the request of President Truman, Sandia Corporation was formed as a subsidiary of Bell Lab's Western Electric Company to operate Sandia as a service to the U.S. Government without profit or fee. Sandia is currently operated for the U.S. Department of Energy (DOE) by AT&T Technologies, Inc., a wholly-owned subsidiary of AT&T. Sandia's responsibility is national security programs in defense and energy with primary emphasis on nuclear weapon research and development (R&D). However, Sandia also supports a wide variety of projects ranging from basic materials research to the design of specialized parachutes. Assets, owned by DOE and valued at more than $1.2 billion, include about 600 major buildings containing about 372,000 square meters (m2) (4 million square feet [ft2]) of floor space, located on land totalling approximately 1460 square kilometers (km2) (562 square miles [mi]). Sandia employs about 8500 people, the majority in Albuquerque, with about 1000 in Livermore. Approximately 60% of Sandia's employees are in technical and scientific positions, and the remainder are in crafts, skilled labor, and administrative positions. As a multiprogram national laboratory, Sandia has much to offer both industrial and government customers in pursuing space nuclear technologies. The purpose of this brochure is to provide the reader with a brief summary of Sandia's technical capabilities, test facilities, and example programs that relate to military and civilian objectives in space. Sandia is interested in forming partnerships with industry and government organizations, and has already formed several cooperative alliances and agreements. Because of the synergism of multiple governmental and industrial sponsors of many programs, Sandia is frequently able to provide complex technical solutions in a relatively short time, and often at lower cost to a particular customer. They have listed a few ongoing programs at Sandia related to space nuclear technology as examples of the possible synergisms that could result from forming teams and partnerships with related technologies and objectives.

  8. Related Articles: 2010 Archive | Department of Energy

    Energy Savers [EERE]

    0 Archive Related Articles: 2010 Archive This page provides links to 2010 articles describing the latest developments in the area of solid-state lighting. Some of the following documents are available as Adobe Acrobat PDFs. December 2010 LED Watch: The Standards Wave Rolls On James Brodrick, U.S. Department of Energy LD+A Magazine http://www.ies.org/lda/members_contact.cfm October 2010 LED Replacement Lamps: Getting Ready for a Game-Changing Decade James Brodrick, U.S. Department of Energy NEMA

  9. Related Articles: 2011 Archive | Department of Energy

    Energy Savers [EERE]

    1 Archive Related Articles: 2011 Archive This page provides links to 2011 articles describing the latest developments in the area of solid-state lighting. December 2011 LED Watch: A Rising Tide Lifts All Boats James Brodrick, U.S. Department of Energy LD+A Magazine http://www.ies.org/lda/members_contact.cfm October 2011 LED Watch: Standards Update: The Question of Lifetime James Brodrick, U.S. Department of Energy LD+A Magazine http://www.ies.org/lda/members_contact.cfm August 2011 LED Watch: A

  10. Related Articles: 2012 Archive | Department of Energy

    Energy Savers [EERE]

    2 Archive Related Articles: 2012 Archive This page provides links to 2012 articles describing the latest developments in the area of solid-state lighting. December 2012 LED Watch: Making Progress Is Standard Procedure for SSL James Brodrick, U.S. Department of Energy LD+A Magazine http://www.ies.org/lda/members_contact.cfm October 2012 LED Watch: A Small Footprint-and Getting Smaller James Brodrick, U.S. Department of Energy LD+A Magazine http://www.ies.org/lda/members_contact.cfm August 2012 A

  11. Ootw Tool Requirements in Relation to JWARS

    SciTech Connect (OSTI)

    Hartley III, D.S.; Packard, S.L.

    1998-01-01

    This document reports the results of the CMke of the Secretary of Defense/Program Analysis & Evaluation (OSD/PA&E) sponsored project to identify how Operations Other Than War (OOTW) tool requirements relate to the Joint Warfare Simulation (JWARS) and, more generally, to joint analytical modeling and simulation (M&S) requirements. It includes recommendations about which OOTW tools (and functionality within tools) should be included in JWARS, which should be managed as joint analytical modeling and simulation (M&S) tools, and which should be left for independent development.

  12. Centrifugal separators and related devices and methods

    DOE Patents [OSTI]

    Meikrantz, David H.; Law, Jack D.; Garn, Troy G.; Macaluso, Lawrence L.; Todd, Terry A.

    2012-03-06

    Centrifugal separators and related methods and devices are described. More particularly, centrifugal separators comprising a first fluid supply fitting configured to deliver fluid into a longitudinal fluid passage of a rotor shaft and a second fluid supply fitting sized and configured to sealingly couple with the first fluid supply fitting are described. Also, centrifugal separator systems comprising a manifold having a drain fitting and a cleaning fluid supply fitting are described, wherein the manifold is coupled to a movable member of a support assembly. Additionally, methods of cleaning centrifugal separators are described.

  13. The universal relation of galactic chemical evolution: the origin of the mass-metallicity relation

    SciTech Connect (OSTI)

    Zahid, H. Jabran; Dima, Gabriel I.; Kudritzki, Rolf-Peter; Kewley, Lisa J.; Geller, Margaret J.; Hwang, Ho Seong; Silverman, John D.; Kashino, Daichi

    2014-08-20

    We examine the mass-metallicity relation for z ≲ 1.6. The mass-metallicity relation follows a steep slope with a turnover, or 'knee', at stellar masses around 10{sup 10} M {sub ☉}. At stellar masses higher than the characteristic turnover mass, the mass-metallicity relation flattens as metallicities begin to saturate. We show that the redshift evolution of the mass-metallicity relation depends only on the evolution of the characteristic turnover mass. The relationship between metallicity and the stellar mass normalized to the characteristic turnover mass is independent of redshift. We find that the redshift-independent slope of the mass-metallicity relation is set by the slope of the relationship between gas mass and stellar mass. The turnover in the mass-metallicity relation occurs when the gas-phase oxygen abundance is high enough that the amount of oxygen locked up in low-mass stars is an appreciable fraction of the amount of oxygen produced by massive stars. The characteristic turnover mass is the stellar mass, where the stellar-to-gas mass ratio is unity. Numerical modeling suggests that the relationship between metallicity and the stellar-to-gas mass ratio is a redshift-independent, universal relationship followed by all galaxies as they evolve. The mass-metallicity relation originates from this more fundamental universal relationship between metallicity and the stellar-to-gas mass ratio. We test the validity of this universal metallicity relation in local galaxies where stellar mass, metallicity, and gas mass measurements are available. The data are consistent with a universal metallicity relation. We derive an equation for estimating the hydrogen gas mass from measurements of stellar mass and metallicity valid for z ≲ 1.6 and predict the cosmological evolution of galactic gas masses.

  14. Building-related risk factors and work-related lower respiratory symptoms in 80 office buildings

    SciTech Connect (OSTI)

    Mendell, M.J.; Naco, G.M.; Wilcox, T.G.; Sieber, W.K.

    2002-01-01

    We assessed building-related risk factors for lower respiratory symptoms in office workers. The National Institute for Occupational Safety and Health in 1993 collected data during indoor environmental health investigations of workplaces. We used multivariate logistic regression analyses to assess relationships between lower respiratory symptoms in office workers and risk factors plausibly related to microbiologic contamination. Among 2,435 occupants in 80 office buildings, frequent, work-related multiple lower respiratory symptoms were strongly associated, in multivariate models, with two risk factors for microbiologic contamination: poor pan drainage under cooling coils and debris in outside air intake. Associations tended to be stronger among those with a history of physician-diagnosed asthma. These findings suggest that adverse lower respiratory health effects from indoor work environments, although unusual, may occur in relation to poorly designed or maintained ventilation systems, particularly among previously diagnosed asthmatics. These findings require confirmation in more representative buildings.

  15. Neuroimaging for drug addiction and related behaviors

    SciTech Connect (OSTI)

    Parvaz M. A.; Parvaz, M.A.; Alia-Klein, N.; Woicik,P.A.; Volkow, N.D.; Goldstein, R.Z.

    2011-10-01

    In this review, we highlight the role of neuroimaging techniques in studying the emotional and cognitive-behavioral components of the addiction syndrome by focusing on the neural substrates subserving them. The phenomenology of drug addiction can be characterized by a recurrent pattern of subjective experiences that includes drug intoxication, craving, bingeing, and withdrawal with the cycle culminating in a persistent preoccupation with obtaining, consuming, and recovering from the drug. In the past two decades, imaging studies of drug addiction have demonstrated deficits in brain circuits related to reward and impulsivity. The current review focuses on studies employing positron emission tomography (PET), functional magnetic resonance imaging (fMRI), and electroencephalography (EEG) to investigate these behaviors in drug-addicted human populations. We begin with a brief account of drug addiction followed by a technical account of each of these imaging modalities. We then discuss how these techniques have uniquely contributed to a deeper understanding of addictive behaviors.

  16. Vlasov multi-dimensional model dispersion relation

    SciTech Connect (OSTI)

    Lushnikov, Pavel M.; Rose, Harvey A.; Silantyev, Denis A.; Vladimirova, Natalia

    2014-07-15

    A hybrid model of the Vlasov equation in multiple spatial dimension D?>?1 [H. A. Rose and W. Daughton, Phys. Plasmas 18, 122109 (2011)], the Vlasov multi dimensional model (VMD), consists of standard Vlasov dynamics along a preferred direction, the z direction, and N flows. At each z, these flows are in the plane perpendicular to the z axis. They satisfy Eulerian-type hydrodynamics with coupling by self-consistent electric and magnetic fields. Every solution of the VMD is an exact solution of the original Vlasov equation. We show approximate convergence of the VMD Langmuir wave dispersion relation in thermal plasma to that of Vlasov-Landau as N increases. Departure from strict rotational invariance about the z axis for small perpendicular wavenumber Langmuir fluctuations in 3D goes to zero like ?{sup N}, where ? is the polar angle and flows are arranged uniformly over the azimuthal angle.

  17. Energy related environmental policies in Turkey

    SciTech Connect (OSTI)

    Kaygusuz, K.; Bilgen, S.

    2008-07-01

    There is increasing consensus in both the scientific and political communities that significant reductions in greenhouse gas (GHG) emissions are necessary to limit the magnitude and extent of climate change. Renewable energy systems already reduce GHG emissions from the energy sector, although on a modest scale. Turkey is heavily dependent on expensive imported energy resources (oil, gas, and coal) that place a big burden on the economy, and air pollution is becoming a great environmental concern in the country. In this regard, renewable energy resources appear to be one of the most efficient and effective solutions for clean and sustainable energy development in Turkey. Turkey's geographical location has several advantages for extensive use of most of these renewable energy sources. This article presents a review of the energy related environmental policies in Turkey.

  18. Plasma generators, reactor systems and related methods

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Pink, Robert J. (Pocatello, ID); Lee, James E. (Idaho Falls, ID)

    2007-06-19

    A plasma generator, reactor and associated systems and methods are provided in accordance with the present invention. A plasma reactor may include multiple sections or modules which are removably coupled together to form a chamber. Associated with each section is an electrode set including three electrodes with each electrode being coupled to a single phase of a three-phase alternating current (AC) power supply. The electrodes are disposed about a longitudinal centerline of the chamber and are arranged to provide and extended arc and generate an extended body of plasma. The electrodes are displaceable relative to the longitudinal centerline of the chamber. A control system may be utilized so as to automatically displace the electrodes and define an electrode gap responsive to measure voltage or current levels of the associated power supply.

  19. Oil shale, tar sands, and related materials

    SciTech Connect (OSTI)

    Stauffer, H.C.

    1981-01-01

    This sixteen-chapter book focuses on the many problems and the new methodology associated with the commercialization of the oil shale and tar sand industry. Topics discussed include: an overview of the Department of Energy's oil shale R, D, and D program; computer simulation of explosive fracture of oil shale; fracturing of oil shale by treatment with liquid sulfur dioxide; chemistry of shale oil cracking; hydrogen sulfide evolution from Colorado oil shale; a possible mechanism of alkene/alkane production in oil shale retorting; oil shale retorting kinetics; kinetics of oil shale char gasification; a comparison of asphaltenes from naturally occurring shale bitumen and retorted shale oils: the influence of temperature on asphaltene structure; beneficiation of Green River oil shale by density methods; beneficiation of Green River oil shale pelletization; shell pellet heat exchange retorting: the SPHER energy-efficient process for retorting oil shale; retorted oil shale disposal research; an investigation into the potential economics of large-scale shale oil production; commercial scale refining of Paraho crude shale oil into military specification fuels; relation between fuel properties and chemical composition; chemical characterization/physical properties of US Navy shale-II fuels; relation between fuel properties and chemical composition: stability of oil shale-derived jet fuel; pyrolysis of shale oil residual fractions; synfuel stability: degradation mechanisms and actual findings; the chemistry of shale oil and its refined products; the reactivity of Cold Lake asphaltenes; influence of thermal processing on the properties of Cold Lake asphaltenes: the effect of distillation; thermal recovery of oil from tar sands by an energy-efficient process; and hydropyrolysis: the potential for primary upgrading of tar sand bitumen.

  20. Jointly Sponsored Research Program Energy Related Research

    SciTech Connect (OSTI)

    Western Research Institute

    2009-03-31

    Cooperative Agreement, DE-FC26-98FT40323, Jointly Sponsored Research (JSR) Program at Western Research Institute (WRI) began in 1998. Over the course of the Program, a total of seventy-seven tasks were proposed utilizing a total of $23,202,579 in USDOE funds. Against this funding, cosponsors committed $26,557,649 in private funds to produce a program valued at $49,760,228. The goal of the Jointly Sponsored Research Program was to develop or assist in the development of innovative technology solutions that will: (1) Increase the production of United States energy resources - coal, natural gas, oil, and renewable energy resources; (2) Enhance the competitiveness of United States energy technologies in international markets and assist in technology transfer; (3) Reduce the nation's dependence on foreign energy supplies and strengthen both the United States and regional economies; and (4) Minimize environmental impacts of energy production and utilization. Under the JSR Program, energy-related tasks emphasized enhanced oil recovery, heavy oil upgrading and characterization, coal beneficiation and upgrading, coal combustion systems development including oxy-combustion, emissions monitoring and abatement, coal gasification technologies including gas clean-up and conditioning, hydrogen and liquid fuels production, coal-bed methane recovery, and the development of technologies for the utilization of renewable energy resources. Environmental-related activities emphasized cleaning contaminated soils and waters, processing of oily wastes, mitigating acid mine drainage, and demonstrating uses for solid waste from clean coal technologies, and other advanced coal-based systems. Technology enhancement activities included resource characterization studies, development of improved methods, monitors and sensors. In general the goals of the tasks proposed were to enhance competitiveness of U.S. technology, increase production of domestic resources, and reduce environmental impacts associated with energy production and utilization. This report summarizes the accomplishments of the JSR Program.

  1. ARM - Datastreams - mwr3c

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    kPa surfacepressure ( time ) Ambient surface relative humidity % surfacerelativehumidity ( time ) Ambient surface absolute temperature degC surfacetemperature ( time )...

  2. ARM - Datastreams - mwrhf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    flag None surfacerainflag ( time ) Ambient surface relative humidity % surfacerelativehumidity ( time ) Ambient surface temperature degC surfacetemperature ( time ) Microwave...

  3. ARM - Publications: Science Team Meeting Documents: Radius and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aerosol particles: Accurate approximations for dependence on relative humidity Lewis, Ernie Brookhaven National Laboratory Schwartz, Stephen Brookhaven National Laboratory...

  4. Relative sensitivity of formability to anisotropy

    SciTech Connect (OSTI)

    Logan, R.W.; Maker, B.N.

    1997-01-01

    This work compares the relative importance of material anisotropy in sheet forming as compared to other material and process variables. The comparison is made quantitative by the use of normalized dependencies of depth to failure (forming limit is reached) on various measures of anisotropy, as well as strain and rate sensitivity, friction, and tooling. Comparisons are made for a variety of forming processes examined previously in the literature as well as two examples of complex stampings in this work. 7 The examples rover a range from nearly pure draw to nearly pure stretch situations, and show that for materials following a quadratic yield criterion, anisotropy is among the most sensitive parameters influencing formability. For materials following higher-exponent yield criteria, the dependency is milder but is still of the order of most other process parameters. However, depending on the particular forming operation, it is shown that in some cases anisotropy may be ignored, whereas in others its consideration is crucial to a good quality analysis.

  5. Asbestos-related pulmonary disease in boilermakers

    SciTech Connect (OSTI)

    Demers, R.Y.; Neale, A.V.; Robins, T.; Herman, S.C. )

    1990-01-01

    Boilermakers are skilled building tradesmen who construct, repair, and dismantle boilers. The present study reports on the evaluation of members of a Michigan boilermaker's union for the presence of signs and symptoms of chronic pulmonary disease. Study variables included standardized evaluations of chest x-ray findings, pulmonary function testing, physical examination, and respiratory symptoms. An overall participation rate of 69% was achieved. A non-participant survey identified no significant differences between participants and non-participants in dyspnea, cough, age, or smoking history. Among participants with greater than 20 years experience in the trade, the mean FVC was 91% of predicted; the FEV1 was 86% of predicted; 25% showed at least a 1/0 profusion of interstitial markings on chest x-ray; 30% had bilateral pleural abnormalities; and 52% had audible inspiratory rales on physical examination. Forced vital capacity and forced expiratory volume at one second both decreased with years in the trade. Chest x-ray findings of interstitial fibrosis and pleural plaques were related to ten or more years in the trade, as were respiratory symptoms of pulmonary rales, wheeze, and dyspnea.

  6. Agriculture-related radiation dose calculations

    SciTech Connect (OSTI)

    Furr, J.M.; Mayberry, J.J.; Waite, D.A.

    1987-10-01

    Estimates of radiation dose to the public must be made at each stage in the identification and qualification process leading to siting a high-level nuclear waste repository. Specifically considering the ingestion pathway, this paper examines questions of reliability and adequacy of dose calculations in relation to five stages of data availability (geologic province, region, area, location, and mass balance) and three methods of calculation (population, population/food production, and food production driven). Calculations were done using the model PABLM with data for the Permian and Palo Duro Basins and the Deaf Smith County area. Extra effort expended in gathering agricultural data at succeeding environmental characterization levels does not appear justified, since dose estimates do not differ greatly; that effort would be better spent determining usage of food types that contribute most to the total dose; and that consumption rate and the air dispersion factor are critical to assessment of radiation dose via the ingestion pathway. 17 refs., 9 figs., 32 tabs.

  7. EIA Energy Efficiency-Energy Related Greenhouse Gas Emissions...

    U.S. Energy Information Administration (EIA) Indexed Site

    Related Greenhouse Gas Emissions Links Energy Related Greenhouse Gas Emissions Links Posted Date: May 2007 Page Last Modified: September 2010 EIA Links Disclaimer: These pages...

  8. AN EVALUATION OF PYROLYSIS OIL PROPERTIES AND CHEMISTRY AS RELATED...

    Office of Scientific and Technical Information (OSTI)

    AN EVALUATION OF PYROLYSIS OIL PROPERTIES AND CHEMISTRY AS RELATED TO PROCESS AND UPGRADE ... Title: AN EVALUATION OF PYROLYSIS OIL PROPERTIES AND CHEMISTRY AS RELATED TO PROCESS AND ...

  9. Table 1b. Relative Standard Errors for Effective, Occupied, and...

    U.S. Energy Information Administration (EIA) Indexed Site

    b.Relative Standard Errors Table 1b. Relative Standard Errors for Effective Occupied, and Vacant Square Footage, 1992 Building Characteristics All Buildings (thousand) Total...

  10. Tritium Related Material Research -Irradiation Effect on Isotropic...

    Office of Environmental Management (EM)

    Related Material Research -Irradiation Effect on Isotropic Graphite Utilizing Heavy Ion-Irradiation- Tritium Related Material Research -Irradiation Effect on Isotropic Graphite...

  11. Natural Gas Regulation - Other Gas-Related Information Sources...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Gas Regulation - Other Gas-Related Information Sources Natural Gas Regulation - Other Gas-Related Information Sources The single largest source of energy information...

  12. Table 2b. Relative Standard Errors for Electricity Consumption...

    U.S. Energy Information Administration (EIA) Indexed Site

    2b. Relative Standard Errors for Electricity Table 2b. Relative Standard Errors for Electricity Consumption and Electricity Intensities, per Square Foot, Specific to Occupied and...

  13. Initiatives Related to Climate Change in Ghana | Open Energy...

    Open Energy Info (EERE)

    Initiatives Related to Climate Change in Ghana Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Initiatives Related to Climate Change in Ghana AgencyCompany...

  14. Research on Factors Relating to Density and Climate Change |...

    Open Energy Info (EERE)

    on Factors Relating to Density and Climate Change Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Research on Factors Relating to Density and Climate Change Agency...

  15. Exploring high temperature phenomena related to post-detonation...

    Office of Scientific and Technical Information (OSTI)

    Exploring high temperature phenomena related to post-detonation by an electric arc Citation Details In-Document Search Title: Exploring high temperature phenomena related to ...

  16. Department of Energy Data Access and Privacy Issues Related To...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Data Access and Privacy Issues Related To Smart Grid Technologies Department of Energy Data Access and Privacy Issues Related To Smart Grid Technologies This report by the ...

  17. Public Roundtable- Data Access and Privacy Issues Related to...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Roundtable- Data Access and Privacy Issues Related to Smart Grid Technologies Public Roundtable- Data Access and Privacy Issues Related to Smart Grid Technologies Transcript of ...

  18. Energy-Related Carbon Emissions, by Industry, 1994

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Efficiency Page > Energy Energy-Related Carbon Emissions > Total Table Total Energy-Related Carbon Emissions for Manufacturing Industries, 1994 Carbon Emissions (million...

  19. FY 2014 Real Property Data Related to Operations and Maintenance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Real Property Data Related to Operations and Maintenance Guidance FY 2014 Real Property Data Related to Operations and Maintenance Guidance PDF icon FY2014DataRelatedtoOperati...

  20. Laboratory for Energy-Related Health Research, California, Site...

    Office of Legacy Management (LM)

    Fact Sheet Laboratory for Energy-Related Health Research, California, Site This fact sheet provides information about the Laboratory for Energy-Related Health Research, California, ...

  1. 2006 National Electric Transmission Congestion Study and Related...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6 National Electric Transmission Congestion Study and Related Materials 2006 National Electric Transmission Congestion Study and Related Materials The 2006 National Congestion...

  2. NDAA Section 3116 Waste Determinations with Related Disposal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NDAA Section 3116 Waste Determinations with Related Disposal Performance Assessments NDAA Section 3116 Waste Determinations with Related Disposal Performance Assessments Section ...

  3. Understanding Collection-Related Losses in Organic Solar Cells...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Understanding Collection-Related Losses in Organic Solar Cells Home > Research > ANSER Research Highlights > Understanding Collection-Related Losses in Organic Solar Cells...

  4. (Energy related studies utilizing microline thermochronology)

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    In our first year of the current funding cycle, we have investigated three interrelated aspects of K-feldspar thermochronology; (1) the Ar diffusion properties and microstructures of K-feldspars, (2) the thermal evolution of the Valles Caldera and (3) the continued development of microanalysis. Results of TEM and light microscopy on heated and unheated samples of MH-10 K-feldspar reveal three classes of substructure are present: (1) cross hatched extinction is common and there is almost no albite/pericline twinning, only tweed microstructure; (2) 5--10 vol. % of this K-feldspar are turbid zones with complex twin and tweed structures at the sub-micron scale and numerous dislocation and strain features; (3) about 20% of the K-feldspar is comprised of 0.01 {times} 0.2-1{mu}m albite exsolution lamellae. The network of fractured/turbid zones divides the sample into blocks of approximately 50 {mu}m and the separation between albite exsolution lamellae produce K-feldspar domains of the order 0.1 {mu}m. Independent crushing and diffusion experiments suggest the scale of the largest domain is order ten's of micron whereas the smallest domain size is inferred to be {approximately}0.1 {mu}m. Many, and perhaps most, alkali feldspars contain diffusion domains with activation energies that may vary by as much as 8 kcal/mol. An extraordinary consequence of even relatively small variations in activation energy between domains is that the shape of an age spectrum can change dramatically by varying the laboratory heating schedule. We have performed {sup 40}Ar/{sup 39}Ar age spectrum experiments on K-feldspar separated from Proterozoic quartz monzonite taken from a depth of 1.76 km down the VC-2B drill hole, Valles Caldera, north-central New Mexcio.

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    2014-11-18

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    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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    Open Energy Info (EERE)

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    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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