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1

Development of non-premixed porous inserted regenerative thermal oxidizer  

Science Journals Connector (OSTI)

In this study, a porous inserted regenerative thermal oxidizer (PRTO) system was developed for a... x emissions and high radiant efficiency. Zirconium dioxide (ZrO2...) ceramic ...

Jun-chun Zhang; Le-ming Cheng; Cheng-hang Zheng…

2013-09-01T23:59:59.000Z

2

Regenerative thermal oxidation and alternative technologies for VOC control  

SciTech Connect

Thermal oxidation technologies have been used successfully to control VOC`s for many years but the recent 1990 Clean Air Act Amendments have spurred improvements in the established processes and development of economic alternatives. The combination of the regulatory maze and confusion in the selection of the best technology for a particular application has created a potential nightmare for those companies facing a need to reduce their VOC EMISSIONS. The relative advantages and disadvantages of regenerative, recuperative and catalytic oxidizers will be reviewed, with an emphasis on the economic justification for regenerative thermal oxidation (RTO). Control efficiencies of more than 99% have been demonstrated for RTO`s on a multitude of industrial process exhaust streams. Lowest evaluated cost over a fifteen to twenty year effective equipment life is a key selection criteria. This paper describes the underlying principles of thermal oxidation, and discusses the applicability of these and other emerging technologies for VOC control.

Biedell, E.L. [REECQ, Somerville, NJ (United States)

1995-12-31T23:59:59.000Z

3

Modeling Process Characteristics and Performance of Fixed and Fluidized Bed Regenerative Thermal Oxidizer  

Science Journals Connector (OSTI)

Modeling Process Characteristics and Performance of Fixed and Fluidized Bed Regenerative Thermal Oxidizer ... (7)?Cheng, W.-H.; Chou, M.-S.; Lee, W.-S.; Huang, B.-J. Applications of Low-Temperature Regenerative Thermal Oxidizers to Treat Volatile Organic Compounds. ...

Pietropaolo Morrone; Francesco P. Di Maio; Alberto Di Renzo; Mario Amelio

2006-05-26T23:59:59.000Z

4

Innovative technical advances in the application of regenerative thermal oxidizers  

SciTech Connect

Regenerative Thermal Oxidizers (RTOs) have been applied in industry for over twenty (20) years to reduce the emissions of Volatile Organic compounds (VOCs) into the atmosphere from industrial process emissions. The Clean Air Act and its amendments have established a regulatory framework setting standards for allowable levels of VOC emissions. Several forces are driving the increasing use and acceptance of this technology: (1) High efficiency and increasing stringent standards require higher destruction efficiency; (2) Low operating cost and control of emission streams with less VOCs (therefore, less fuel value) causing higher use of natural gas for combustion; (3) Low NO{sub x}--the overlapping concern of NO{sub x} generation from the combustion process; (4) Low process upsets with improved productivity of industrial process require continuous integration of VOC abatement equipment; and (5) Reduced capital cost--capital cost criteria is $/ton of VOC abated. The latest development in RTO technology is the Single Can Oxidizer (SCO). This regenerative thermal oxidizer is the accumulation of developments in many subsystems of RTOs, combined with a dramatic new configuration. Several features of the system offer unique benefits to industrial end users: (1) Single can configuration gives reduced weight, material usage, and cost; (2) Rotary valve design gives smooth operation, and low pressure fluctuations; (3) Structured block heat recovery media reduces pressure drop, and lowers HP/operating cost; and (4) SMART system lowers NO{sub x} output/reduced operation cost. This paper will present a discussion of the features listed above. In addition, it will provide analytical documentation of test results for a full scale commercial unit.

Grzanka, R.; Truppi, T.

1999-07-01T23:59:59.000Z

5

Reduction of carbon monoxide emissions with regenerative thermal oxidizers  

SciTech Connect

Regenerative thermal oxidizers (RTOs) have been extensively used for the control of volatile organic compound (VOC) emissions from various sources. However, very little information is available on the ability of RTOs to control carbon monoxide (CO) emissions. This paper presents the results of extensive tests conducted on two RTOs to determine their VOC and CO control efficiencies. The inlet gas stream to the RTOs includes VOC and CO concentrations as high as 2,000 ppm and 3,600 ppm, respectfully. The testing demonstrated that both RTOs were capable of controlling greater than 98% of both inlet VOCs and CO. While the destruction efficiencies within the combustion chambers exceeded 99.9%, direct leakage past valves accounted for the lower control efficiencies. The tests indicated that the overall VOC and CO control efficiencies of the RTOs may be limited by valve leakage. The design and permitting of a RTO should include conservative control estimates which account for possible valve leakage.

Firmin, S.M.; Lipke, S.; Baturay, A.

1996-09-01T23:59:59.000Z

6

Regenerative catalytic oxidation  

SciTech Connect

Currently Regenerative Thermal Oxidizers (R.T.O.`s) are an accepted technology for the control of volatile organic compounds (VOC`s) and hazardous air pollutants (HAP`s). This control technology, when introduced, offered substantial reductions in operating costs, especially auxiliary fuel requirements when compared to existing control technologies such as recuperative thermal and recuperative catalytic oxidizers. While these savings still exist, there is a demand for control of new and/or hybrid technologies, one of which is Regenerative Catalytic Oxidizers (R.C.O.`s). This paper will explore the development of regenerative catalytic oxidation from the theoretical stage through pilot testing through a commercial installation. The operating cost of R.C.O.`s will be compared to R.T.O.`s to verify the savings that are achievable through the use of regenerative catalytic oxidation. In the development of this technology, which is a combination of two (2) existing technologies, R.T.O.`s and catalysis, a second hybrid technology was explored and pilot tested. This is a combination R.C.O. for VOC and HAP control and simultaneous SCR (Selective Catalytic Reduction) for NOx (Oxides of Nitrogen) control. Based on the pilot and full scale testing, both regenerative catalytic oxidizers and systems which combine R.C.O. with SCR for both VOC and NOx reduction are economically viable and are in fact commercially available. 6 figs., 2 tabs.

Gribbon, S.T. [Engelhard Process Emission Systems, South Lyon, MI (United States)

1996-12-31T23:59:59.000Z

7

Regenerative thermal oxidizers for VOC and NO{sub x} -- efficiency and cost  

SciTech Connect

Regenerative fume incinerators or thermal oxidizers have a combustion chamber at about 1,600 F. Heat recovery is provided by switching regenerator beds filled with ceramic. Volatile organic compounds, VOC`s, are about 99% removed along with a thermal efficiency of 90 to 95%. Improvements are discussed which reduce fuel costs, reduce investment cost and give better VOC removal. A method of preventing NO{sub x} formation is presented as well as a possible method for removing NO{sub x} from incoming feed gas. Regenerative fume incinerators or regenerative thermal oxidizers have 3 possible improvements. (1) Add the required fuel to the incoming gas to nearly eliminate NO{sub x} generation while improving thermal efficiency. (2) Remove NO{sub x} from the incoming gas by a new modification of the Exxon Thermal DeNO{sub x} process. (3) Use a new 4-way valve for 1 or 2-bed regenerators to cut investment and improve destruction efficiency.

Houston, R. [Houston Consulting, Hendersonville, NC (United States)

1995-12-31T23:59:59.000Z

8

Stripping of organic compounds from wastewater as an auxiliary fuel of regenerative thermal oxidizer  

Science Journals Connector (OSTI)

Organic solvents with different volatilities are widely used in various processes and generate air and water pollution problems. In the cleaning processes of electronics industries, most volatile organic compounds (VOCs) are vented to air pollution control devices while most non-volatile organic solvents dissolve in the cleaning water and become the major sources of COD in wastewater. Discharging a high-COD wastewater stream to wastewater treatment facility often disturbs the treatment performance. A pretreatment of the high-COD wastewater is therefore highly desirable. This study used a packed-bed stripping tower in combination with a regenerative thermal oxidizer to remove the COD in the wastewater from a printed circuit board manufacturing process and to utilize the stripped organic compounds as the auxiliary fuel of the RTO. The experimental results showed that up to 45% of the COD could be removed and 66% of the RTO fuel could be saved by the combined treatment system.

Meng-Wen Chang; Jia-Ming Chern

2009-01-01T23:59:59.000Z

9

Numerical evaluation of the energetic performances of structured and random packed beds in regenerative thermal oxidizers  

Science Journals Connector (OSTI)

Regenerative thermal oxidizers (RTO) can be conveniently used to control volatile organic components (VOC) emissions, because of their thermal efficiency and cost effectiveness. In the RTO technology, beds of inert material are used in order to heat the polluted air by cooling burnt gases, through a sequence of cyclic operations which cut the fuel requirements. A computational 1D unsteady model, able to account for both structured and random packed bed regenerators, is developed and applied to realistic plant conditions. Process thermal efficiency and gas pressure drop are calculated as functions of the system geometry and operating parameters. The code can be usefully employed in the analysis and design of RTO systems and in order to choose the more suitable type of regenerator, structured or random packed bed (even considering various particle shapes). Energetic performances of both random and structured regenerators were compared, showing that the first ones exhibit a little higher thermal efficiency but also an elevated pressure drop, at a same value of exchange surface per unit volume of the bed. Random packed bed regenerators resulted less attractive from the energetic point of view and their usage is advisable if their lower cost satisfy economical requirements.

Mario Amelio; Pietropaolo Morrone

2007-01-01T23:59:59.000Z

10

Development and testing of improved heat transfer media for regenerative thermal oxidizers in the wood products industry  

SciTech Connect

Recently regenerative thermal oxidizers (RTOs) have been used to control gaseous hydrocarbon air pollutant emissions from wood products plants. Two major problems related to the ceramic saddle heat transfer matrix in conventional RTOs have been encountered, cold face fouling and breakdown of the ceramic matrix. A structured packing heat transfer media having straight airflow passages of constant cross section was developed to remedy these problems. Results of pilot scale testing has shown that the structured packing is resistant to cold face fouling and breakdown of the ceramic matrix. In addition, in a full scale retrofit application, improvements in pollutant reduction effectiveness and operating efficiency were measured. 5 refs., 3 figs., 2 tabs.

Klobucar, J.M. [Duerr Industries, Inc., Plymouth, MI (United States)

1996-12-31T23:59:59.000Z

11

Thermal regenerative injector  

SciTech Connect

This patent describes an apparatus for injecting fuel and oxidizer into the combustion zone of an engine, comprising: a housing; means for receiving the fuel within the housing; means for preheating the fuel within the housing; a heat source external to the apparatus; means for transporting the fuel from the housing to the heat source wherein the fuel is heated; means for receiving the heated fuel within the housing; means for receiving the oxidizer within the housing; and means for injecting the oxidizer and the heated fuel from the housing into the combustion zone, the injection means being integral with the housing.

Wagner, W.R.

1987-11-24T23:59:59.000Z

12

Conversion of a regenerative oxidizer into catalytic unit  

SciTech Connect

Use of a VOC oxidation catalyst in the existing regenerative thermal oxidizers may greatly reduce fuel consumption and improve the oxidizer performance. This was demonstrated in a commercial 25,000 SCFM unit installed at a printing facility. The paper discusses the principles of the oxidizer retrofit design and test results obtained at various conditions of operation.

Matros, Y.S.; Bunimovich, G.A.; Strots, V.O. [Matros Technologies, Chesterfield, MO (United States)] [and others

1997-12-31T23:59:59.000Z

13

Low-temperature thermally regenerative electrochemical system  

DOE Patents (OSTI)

A thermally regenerative electrochemical system is described including an electrochemical cell with two water-based electrolytes separated by an ion exchange membrane, at least one of the electrolytes containing a complexing agent and a salt of a multivalent metal whose respective order of potentials for a pair of its redox couples is reversible by a change in the amount of the ocmplexing agent in the electrolyte, the complexing agent being removable by distillation to cause the reversal.

Loutfy, R.O.; Brown, A.P.; Yao, N.P.

1982-04-21T23:59:59.000Z

14

Low temperature thermally regenerative electrochemical system  

DOE Patents (OSTI)

A thermally regenerative electrochemical system including an electrochemical cell with two water-based electrolytes separated by an ion exchange membrane, at least one of the electrolytes containing a complexing agent and a salt of a multivalent metal whose respective order of potentials for a pair of its redox couples is reversible by a change in the amount of the complexing agent in the electrolyte, the complexing agent being removable by distillation to cause the reversal.

Loutfy, Raouf O. (Tucson, AZ); Brown, Alan P. (Bolingbrook, IL); Yao, Neng-Ping (Clarendon Hills, IL)

1983-01-01T23:59:59.000Z

15

Development of efficiency-enhanced cogeneration system utilizing high-temperature exhaust-gas from a regenerative thermal oxidizer for waste volatile-organic-compound gases  

Science Journals Connector (OSTI)

We have developed a gas-turbine cogeneration system that makes effective use of the calorific value of the volatile organic compound (VOC) gases exhausted during production processes at a manufacturing plant. The system utilizes the high-temperature exhaust-gas from the regenerative thermal oxidizer (RTO) which is used for incinerating VOC gases. The high-temperature exhaust gas is employed to resuperheat the steam injected into the gasturbine. The steam-injection temperature raised in this way increases the heat input, resulting in the improved efficiency of the gas-turbine. Based on the actual operation of the system, we obtained the following results: • Operation with the steam-injection temperature at 300 °C (45 °C resuperheated from 255 °C) increased the efficiency of the gasturbine by 0.7%. • The system can enhance the efficiency by 1.3% when the steam-injection temperature is elevated to 340 °C (85 °C resuperheated). In this case, up to 6.6 million yen of the total energy cost and 400 tons of carbon dioxide (CO2) emissions can be reduced annually. • A gas-turbine cogeneration and RTO system can reduce energy consumption by 23% and CO2 emission by 30.1% at the plant.

Masaaki Bannai; Akira Houkabe; Masahiko Furukawa; Takao Kashiwagi; Atsushi Akisawa; Takuya Yoshida; Hiroyuki Yamada

2006-01-01T23:59:59.000Z

16

Regenerative oxidizer recovers 85% fume control energy, saves $350,000 annually  

SciTech Connect

Expansion of production for carbofuran insecticides increased ventilation requirements for fume and odor control from 8,000 to 50,000 scfm at FMC Corporation's Middleport, NY plant. A seven-lobe, closed thermal regenerative oxidation system was installed with heat recovery of up to 90%. Performance, operation, and results of the regenerative oxidizer are described. Almost a million gallons of oil are conserved annually which is equivalent to about 90% of plant requirements for steam generation.

McElhinney, R.

1980-05-01T23:59:59.000Z

17

Energy Recovery Efficiency and Cost Analysis of VOC Thermal Oxidation Pollution Control Technology  

Science Journals Connector (OSTI)

Respective cost models were derived for recuperative thermal oxidizer (TO) and regenerative thermal oxidizer (RTO). ... In a thermal oxidation process, VOC-laden air is thermally treated (oxidized/decomposed) at temperatures about 730?850 °C. ... Choi and Yi(4) worked on the simulation and optimization of regenerative thermal oxidizers. ...

Aruna S. K. Warahena; Yew Khoy Chuah

2009-06-24T23:59:59.000Z

18

Chapter 10 - Regenerative catalytic oxidizer technology for VOC control  

Science Journals Connector (OSTI)

Publisher Summary The regenerative catalytic oxidizer (RCO) technology has evolved significantly as an efficient method to control volatile organic compounds. The RCO technology favors using oxide catalysts because it allows for easy compensation of lower activity by an increase in the catalyst amount or temperature. Heat transfer and accumulation properties of ceramic packing material strongly influence RCO performance. The rate of heat transfer affects the temperature gradients along the bed length that, in turn, determine the volume of material required to preheat the gas to the temperature of catalytic or thermal oxidation. During the catalyst operation, it gradually becomes less active and must be eventually replaced. The factors affecting the catalyst lifetime include high temperature, catalytic poisons, and masking agents. Compounds of halogens and sulfur are the most common catalyst poisons. Temperature control, poison tolerant catalysts, and gas-flow pretreatment are used to reduce the impact of catalyst deactivation. This chapter also presents the behavior of an RCO when the catalyst deactivates, and proposes strategies ensuring the required performance during the entire catalyst lifetime.

V.O. Strots; G.A. Bunimovich; C.R. Roach; Yu.Sh. Matros

2000-01-01T23:59:59.000Z

19

Treating isopropyl alcohol by a regenerative catalytic oxidizer  

Science Journals Connector (OSTI)

Regenerative catalytic oxidizer (RCO) can be conveniently used to control emissions of volatile organic compounds (VOCs), because of their thermal recovery efficiency (TRE), low fuel cost and high oxidation. In this work, catalysts with various metal weight loadings were prepared by deposition–precipitation, wet impregnation and incipient impregnation to treat isopropyl alcohol (IPA). We used the excellent catalytic performance in a pilot RCO to test IPA oxidation performance under various conditions. The best catalyst was selected and its TRE, bed temperature variations, pressure drops and selectivity of the catalyst were more widely discussed. The results demonstrate that the optimal catalyst was prepared by wet impregnation with 20 wt.% metal on ceramic honeycomb (CH). 20 wt.% Cu–Co/(CH) catalyst was the best catalyst used in a RCO because it was effective in treating IPA, with a CO2 yield of up to 95% at a heating zone temperature (Tset) = 400 °C under various conditions. It also had the largest tolerance of variations in inlet IPA concentration and gas velocity (Ug). This 20 wt.% Cu–Co/(CH) catalyst in a RCO performed well in terms of TRE, pressure drop and selectivity to CO2. The TRE range in a RCO was from 87.8 to 91.2% under various conditions, and decreased as Ug increased in a fixed Tset. The pressure drop increased with Ug and Tset. The selectivity to CO2 increased to over 95% at 300 °C, and that to propene remained at 2–5% from 200 to 400 °C. Finally, the stability test results indicated that the 20 wt.% Cu–Co/(CH) catalyst was very stable at various CO2 yields and temperatures.

Jie-Chung Lou; Shih-Wei Huang

2008-01-01T23:59:59.000Z

20

Choose the best heat-recovery method for thermal oxidizers  

SciTech Connect

Thermal oxidation is current the most economically favorable add-on method of controlling hydrocarbon air emissions of moderate to low concentration (below 10,000 ppm). This concentration range covers emissions from a wide variety of chemical process industries (CPI) sources, including dryers, reactor vents, tank vents, and coaters. Thermal oxidizer systems consist of three basic sub-systems--burner, combustion chamber, and primary heat recovery. Selecting the type of primary heat recovery is probably the most important decision in the design of a thermal oxidizer, and requires consideration of a wide range of factors. The two most widely used types of primary heat recovery--recuperative and regenerative--each have distinct advantages and disadvantages. In general, recuperative oxidizers are simpler and less costly to purchase, whereas regenerative oxidizers offer substantially lower operating costs. Selecting between recuperative and regenerative heat recovery requires balancing a number of factors, such as capital and operating costs, exhaust gas composition and temperature, and secondary heat demand. This article provides guidance on when, where, and how to use each.

Klobucar, J.M.

1995-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Enhanced Thermal Conductivity Oxide Fuels  

SciTech Connect

the purpose of this project was to investigate the feasibility of increasing the thermal conductivity of oxide fuels by adding small fractions of a high conductivity solid phase.

Alvin Solomon; Shripad Revankar; J. Kevin McCoy

2006-01-17T23:59:59.000Z

22

Thermally Oxidized Silicon  

NLE Websites -- All DOE Office Websites (Extended Search)

Anneli Munkholm (Lumileds Lighting) and Sean Brennan (SSRL) Anneli Munkholm (Lumileds Lighting) and Sean Brennan (SSRL) Illustration of the silicon positions near the Si-SiO2 interface for a 4° miscut projected onto the ( ) plane. The silicon atoms in the substrate are blue and those in the oxide are red. The small black spots represent the translated silicon positions in the absence of static disorder. The silicon atoms in the oxide have been randomly assigned a magnitude and direction based on the static disorder value at that position in the lattice. The outline of four silicon unit cells is shown in black, whereas the outline of four expanded lattice cells in the oxide is shown in blue One of the most studied devices of modern technology is the field-effect transistor, which is the basis for most integrated circuits. At its heart

23

Development and Field-Scale Optimization of a Honeycomb Zeolite Rotor Concentrator/Recuperative Oxidizer for the Abatement of Volatile Organic Carbons from Semiconductor Industry  

Science Journals Connector (OSTI)

Also the developed rotor performance’s was evaluated in the field; (2) Direct Fired Thermal Oxidizer (DFTO), Recuperative Oxidizer (RO), Regenerative Thermal Oxidizer (RTO) and Regenerative Catalytic oxidizer (RCO) are the available incinerators and the RO was selected as the oxidizer in this work; (3) The overall performance of the developed rotor/oxidizer was explored in a field scale under varying conditions; (4) The energy saving strategy was fulfilled by reducing heat loss from the oxidizer and recovering heat from the exhaust gas. ... The available types of oxidizers include Direct Fired Thermal Oxidizer (DFTO), Recuperative Oxidizer (RO), Regenerative Thermal Oxidizer (RTO) and Regenerative Catalytic oxidizer (RCO). ... cost models were derived for recuperative thermal (TO) and regenerative thermal oxidizers (RTO). ...

Ji Yang; Yufeng Chen; Limei Cao; Yuling Guo; Jinping Jia

2011-11-17T23:59:59.000Z

24

Treatment of \\{VOCs\\} with molecular sieve catalysts in regenerative catalytic oxidizer  

Science Journals Connector (OSTI)

This work prepares molecular sieve catalysts with various metal species and various metal weight loadings by impregnation, and then screens them in a catalytic combustion system. The current study further investigates the molecular sieve catalyst in an RCO system after it performed well in combustion efficiency. This work tests its performances in terms of CO2 yield, pressure drop, the difference between temperatures of the inlet and outlet gases (Td), and thermal recovery efficiency (TRE), with various operational conditions. Experimental results demonstrate that the 10 wt% Cu/(MS) catalyst was the most active because it has the greatest combustion efficiency to treat volatile organic compounds (VOCs) than Co/(MS) catalysts and Mn/(MS) catalysts. The 10 wt% Cu/(MS) catalyst used in an RCO system reaches over 95% CO2 yields under the heating zone temperature (Tset) = 400 °C, gas velocity (Ug) = 0.37 m/s, isopropyl alcohol (IPA) concentration = 200–400 ppm conditions. Moreover, the RCO system performed well in economic efficiency with the RCO with in terms of TRE, Td and pressure drop. The TRE ranged from 90.4% to 94.6% and Td ranged from 14.0 to 34.2 °C under various conditions at Tset = 300–450 °C. Finally, the results of the stability test demonstrated that the catalyst was very stable at various Ug values and various Tset values.

Shih-Wei Huang; Jie-Chung Lou; Yung-Chang Lin

2010-01-01T23:59:59.000Z

25

Flameless thermal oxidation. Innovative technology summary report  

SciTech Connect

The Flameless Thermal Oxidizer (FTO) is a commercial technology offered by Thermatrix, Inc. The FTO has been demonstrated to be an effective destructive technology for process and waste stream off-gas treatment of volatile organic compounds (VOCs), and in the treatment of VOC and chlorinated volatile organic compounds (CVOCs) off-gases generated during site remediation using either baseline or innovative in situ environmental technologies. The FTO process efficiently converts VOCs and CVOCs to carbon dioxide, water, and hydrogen chloride. When FTO is coupled with a baseline technology, such as soil vapor extraction (SVE), an efficient in situ soil remediation system is produced. The innovation is in using a simple, reliable, scalable, and robust technology for the destruction of VOC and CVOC off-gases based on a design that generates a uniform thermal reaction zone that prevents flame propagation and efficiently oxidizes off-gases without forming products of incomplete combustion (PICs).

NONE

1995-09-01T23:59:59.000Z

26

Thermal and Oxidative Degradation of Castor Oil Biodiesel  

Science Journals Connector (OSTI)

Thermal and Oxidative Degradation of Castor Oil Biodiesel ... The neat biodiesels, 20% blends, and the base fuel (No. 2 diesel) were tested at 2 different loads (100 and 20%) and 3 injection timings (3° advanced, std., 3° retarded). ...

Marta M. Conceição; Valter J. Fernandes, Jr.; Antonio S. Araújo; Mirna F. Farias; Ieda M. G. Santos; Antonio G. Souza

2007-03-23T23:59:59.000Z

27

Rapid thermal oxidation of silicon in mixtures of oxygen and nitrous oxide  

SciTech Connect

Oxidation in nitrous oxide by conventional hot wall furnace processing and by rapid thermal oxidation (RTO) has been a subject of much interest in recent years. RTO is a fundamentally different process than furnace oxidation, however, and the full effects of this type of processing on the oxidation kinetics are not well understood. Oxidation of silicon by RTO at a variety of pressures, temperatures, and oxidation gas mixtures has been studied. Although at lower temperatures (< 850 C) the atmospheric pressure oxidation rate in nitrous oxide is very close to that in oxygen, at higher temperatures the oxidation rate in nitrous oxide is much lower than that in oxygen. At lower pressures in a RTO process, the oxidation rate in nitrous oxide is higher than that in oxygen. The effect of the nitrogen incorporated in the oxide acting as a diffusion barrier has been proposed as the mechanism of temperature dependence for atmospheric pressure oxidation in nitrous oxide. This does not explain the effects seen at lower pressure,s however, The authors propose that some of the intermediate species produced in the decomposition of nitrous oxide into molecular nitrogen, molecular oxygen, and nitric oxide play a role in the initial stages of oxidation by RTO in nitrous oxide.

Grant, J.M.; Karim, Z. [Sharp Microelectronics Technology, Inc., Camas, WA (United States)

1996-12-01T23:59:59.000Z

28

Scalable enhancement of graphene oxide properties by thermally driven phase  

E-Print Network (OSTI)

Scalable enhancement of graphene oxide properties by thermally driven phase transformation Priyank,2,4 * and Jeffrey C. Grossman1 * Chemical functionalization of graphene is promising for a variety of next-generation technologies. Although graphene oxide (GO) is a versatile material in this direction, its use is limited

Wu, Junqiao

29

Clean Energy Technologies: A Preliminary Inventory of the Potential for Electricity Generation  

E-Print Network (OSTI)

generally regenerative thermal oxidizers (RTO) are used. Insystem compared to a regenerative thermal oxidizer (RTO) VOC

Bailey, Owen; Worrell, Ernst

2005-01-01T23:59:59.000Z

30

Thermal and Electrical Transport in Oxide Heterostructures  

E-Print Network (OSTI)

2.3.1 Electrical transport . . . . . . . . . . . . . . . .3.5 Controlling electrical conductivity and opticalthe variation of electrical and thermal con- ductivity and

Ravichandran, Jayakanth

2011-01-01T23:59:59.000Z

31

Regenerative switching CMOS system  

DOE Patents (OSTI)

Complementary Metal Oxide Semiconductor (CMOS) Schottky barrier Field Effect Transistor systems, which are a series combination of N and P-Channel MOSFETS, in which Source Schottky barrier junctions of the N and P-Channel Schottky barrier MOSFETS are electrically interconnected, (rather than the Drains as in conventional diffused junction CMOS), which Schottky barrier MOSFET system demonstrates Regenerative Inverting Switching Characteristics in use are disclosed. Both the N and P-Channel Schottky barrier MOSFET devices are unique in that they provide operational Drain Current vs. Drain to Source voltage as a function of Gate voltage only where the polarities of the Drain voltage and Gate voltage are opposite, referenced to the Source as a common terminal, and where the polarity of the voltage applied to the Gate is appropriate to cause Channel inversion. Experimentally derived results which demonstrate and verify the operation of N and P-Channel Schottky barrier MOSFETS actually fabricated on P and N-type Silicon respectively, by a common procedure using vacuum deposited Chromium as a Schottky barrier forming metal, are also provided. 14 figs.

Welch, J.D.

1998-06-02T23:59:59.000Z

32

Molten Oxide Glass Materials for Thermal Energy Storage  

Science Journals Connector (OSTI)

Abstract Halotechnics, Inc. is developing an energy storage system utilizing a low melting point molten glass as the heat transfer and thermal storage material. This work is supported under a grant from the Department of Energy's Advanced Research Projects Agency-Energy (ARPA-E). Advanced oxide glasses promise a potential breakthrough as a low cost, earth abundant, and stable thermal storage material. The system and new glass material will enable grid scale electricity storage at a fraction of the cost of batteries by integrating the thermal storage with a large heat pump device. Halotechnics is combining its proven expertise in combinatorial chemistry with advanced techniques for handling molten glass to design and build a two-tank thermal energy storage system. This system, operating at a high temperature of 1200 °C and a low temperature of 400 °C, will demonstrate sensible heat thermal energy storage using a uniquely formulated oxide glass. Our molten glass thermal storage material has the potential to significantly reduce thermal storage costs once developed and deployed at commercial scale. Thermal storage at the target temperature can be integrated with existing high temperature gas turbines that significantly increase efficiencies over today's steam turbine technology. This paper describes the development and selection of Halotechnics’ molten glass heat transfer fluids with some additional systems considerations.

B. Elkin; L. Finkelstein; T. Dyer; J. Raade

2014-01-01T23:59:59.000Z

33

Therapeutic potential of nanoceria in regenerative medicine.  

SciTech Connect

Tissue engineering and regenerative medicine aim to achieve functional restoration of tissue or cells damaged through disease, aging or trauma. Advancement of tissue engineering requires innovation in the field of 3D scaffolding, and functionalization with bioactive molecules. Nanotechnology offers advanced materials with patterned nano-morphologies for cell growth and different molecular substrates which can support cell survival and functions. Cerium oxide nanoparticles (nanoceria) can control intracellular as well as extracellular reactive oxygen and nitrogen species. Recent findings suggest that nanoceria can enhance long-term cell survival, enable cell migration and proliferation, and promote stem cell differentiation. Moreover, the self-regenerative property of nanoceria permits a small dose to remain catalytically active for extended time. This review summarizes the possibilities and applications of nanoceria in the field of tissue engineering and regenerative medicine.

Das, Soumen; Chigurupati, Srinivasulu; Dowding, Janet; Munusamy, Prabhakaran; Baer, Donald R.; McGinnis, James F.; Mattson, Mark P.; Self, William; Seal, Sudipta

2014-11-14T23:59:59.000Z

34

Thermal Stress Analysis of LCA-based Solid Oxide Fuel Cells.  

E-Print Network (OSTI)

??This research characterizes the thermal stress resulting from temperature gradients in hybrid solid oxide fuel cells that are processed using a novel oxide powder slurry… (more)

LeMasters, Jason Augustine

2004-01-01T23:59:59.000Z

35

Oxidation of Metals, Vol. 61, Nos. 3/4, April 2004 ( 2004) Thermal Conductivity, Phase Stability, and Oxidation  

E-Print Network (OSTI)

, and Oxidation Resistance of Y3Al5O12 (YAG)/Y2O3­ZrO2 (YSZ) Thermal-Barrier Coatings Y. J. Su, R. W. Trice,# K oxidation resistance while maintaining low thermal conductivity and good phase stability. Padture) is proposed. The objective of this work is to quantify the effect of YAG on thermal resistance, long

Trice, Rodney W.

36

Thermal stability and oxidation resistance of TiCrAlYO coatings...  

NLE Websites -- All DOE Office Websites (Extended Search)

stability and oxidation resistance of TiCrAlYO coatings on SS430 for solid oxide fuel cell interconnect applications. Thermal stability and oxidation resistance of TiCrAlYO...

37

Regenerative feedback resonant circuit  

DOE Patents (OSTI)

A regenerative feedback resonant circuit for measuring a transient response in a loop is disclosed. The circuit includes an amplifier for generating a signal in the loop. The circuit further includes a resonator having a resonant cavity and a material located within the cavity. The signal sent into the resonator produces a resonant frequency. A variation of the resonant frequency due to perturbations in electromagnetic properties of the material is measured.

Jones, A. Mark; Kelly, James F.; McCloy, John S.; McMakin, Douglas L.

2014-09-02T23:59:59.000Z

38

Energy efficiency improvement and cost saving opportunities for the Corn Wet Milling Industry: An ENERGY STAR Guide for Energy and Plant Managers  

E-Print Network (OSTI)

process control Regenerative thermal oxidizers Reduction inexhaust gases, regenerative thermal oxidizers (RTO, see RTOsWHE) and a regenerative thermal oxidizer (RTO) (see Section

Galitsky, Christina; Worrell, Ernst; Ruth, Michael

2003-01-01T23:59:59.000Z

39

Energy Efficiency Improvement and Cost Saving Opportunities for the Vehicle Assembly Industry: An ENERGY STAR Guide for Energy and Plant Managers  

E-Print Network (OSTI)

and painting RTOs (regenerative thermal oxidizers). Ford hasenergy use in its regenerative thermal oxidizers by reducinghatches on each regenerative thermal oxidizer (RTO), which

Galitsky, Christina

2008-01-01T23:59:59.000Z

40

Thermal oxidation as a simple method to increase resolution in nanoimprint lithography  

Science Journals Connector (OSTI)

We introduce a simple thermal oxidation technique for decreasing feature sizes of nanoimprint lithography (NIL) masters. During oxidation, the dimensions of negative features are reduced (e.g., gaps become narrower), and the dimensions of positive features ... Keywords: Electron beam lithography, Master fabrication, Nanoimprint lithography, Resolution, Thermal oxidation

Andrew P. Bonifas; Richard L. McCreery; Kenneth D. Harris

2011-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Regenerative nanomedicines: an emerging investment prospective?  

Science Journals Connector (OSTI)

...application of nanotechnologies to the field of regenerative medicine offers the potential...regenerative medicine products rather than nanotechnology as a platform...application of nanotechnology to regenerative medicine may offer enormous...

2010-01-01T23:59:59.000Z

42

Translation and commercialization of regenerative medicines  

Science Journals Connector (OSTI)

...issue 'Translation and commercialization of regenerative medicines...Prescott Translation and commercialization of regenerative medicines...accelerate the banking process and facilitate appropriate...Supplement Translation and commercialization of regenerative medicines...

2010-01-01T23:59:59.000Z

43

MERCURY OXIDIZATION IN NON-THERMAL PLASMA BARRIER DISCHARGE SYSTEM  

SciTech Connect

In the past decade, the emission of toxic elements from human activities has become a matter of great public concern. Hg, As, Se and Cd typically volatilize during a combustion process and are not easily caught with conventional air pollution control techniques. In addition, there is no pollution prevention technique available now or likely be available in the foreseeable future that can prevent the emission of these trace elements. These trace elements pose additional scientific challenge as they are present at only ppb levels in large gas streams. Mercury, in particular, has attracted significant attention due to its high volatility, toxicity and potential threat to human health. In the present research work, a non-thermal plasma dielectric barrier discharge technique has been used to oxidize Hg{sup 0}(g) to HgO. The basic premise of this approach is that Hg{sup 0} in vapor form cannot be easily removed in an absorption tower whereas HgO as a particulate is amiable to water scrubbing. The work presented in this report consists of three steps: (1) setting-up of an experimental apparatus to generate mercury vapors at a constant rate and modifying the existing non-thermal plasma reactor system, (2) solving the analytical challenge for measuring mercury vapor concentration at ppb level, and (3) conducting experiments on mercury oxidation under plasma conditions to establish proof of concept.

V.K. Mathur

2003-02-01T23:59:59.000Z

44

Project Profile: Regenerative Carbonate-Based Thermochemical...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Regenerative Carbonate-Based Thermochemical Energy Storage System for Concentrating Solar Power Project Profile: Regenerative Carbonate-Based Thermochemical Energy Storage System...

45

Translation and commercialization of regenerative medicines  

Science Journals Connector (OSTI)

...applying the latest nanotechnologies to enhance the regenerative...impact of regenerative medicine is not just as a new...commercialization of regenerative medicines. References Abdulrazzak...extracellular matrix through nanotechnology. J. R. Soc. Interface...2010 Regenerative medicine: the emergence of...

2010-01-01T23:59:59.000Z

46

Distributed Porosity as a Control Parameter for Oxide Thermal Barriers Made by Physical Vapor Deposition  

E-Print Network (OSTI)

Anthony G. Evans* Materials Institute, Princeton University, Princeton, New Jersey 08544 Thermal barrier and generating new thermal resistance solutions, as appropri- ate. A continuum heat flow analysis is usedDistributed Porosity as a Control Parameter for Oxide Thermal Barriers Made by Physical Vapor

Wadley, Haydn

47

Surface characterization and mechanical property evaluation of thermally oxidized Ti-6Al-4V  

SciTech Connect

The present study concerns development of a thin and adherent oxide film on the surface of Ti-6Al-4V by thermal oxidation. Thermal oxidation was carried out over a range of temperature between 400 to 600 deg. C and a time from 25 h to 60 h. A detailed characterization of the surface and cross section of the oxidized surface was carried out by optical/scanning electron microscopy and X-ray diffraction techniques. Finally, the mechanical properties of the oxidized surface in terms of microindentation hardness and wear resistance were evaluated as a function of oxidation parameters. Surface oxidation of Ti-6Al-4V at 600 deg. C for 36 h offered a defect free oxide scale with improved hardness and wear resistance.

Biswas, Amit [Department of Metal. and Maters. Engg., I. I. T. Kharagpur, W. B. - 721302 (India); Dutta Majumdar, Jyotsna, E-mail: jyotsna@metal.iitkgp.ernet.in [Department of Metal. and Maters. Engg., I. I. T. Kharagpur, W. B. - 721302 (India)

2009-06-15T23:59:59.000Z

48

Regenerative Energie Systeme RegEnSys | Open Energy Information  

Open Energy Info (EERE)

Regenerative Energie Systeme RegEnSys Regenerative Energie Systeme RegEnSys Jump to: navigation, search Name Regenerative Energie Systeme (RegEnSys) Place Frankenthal, Rhineland-Palatinate, Germany Zip 67227 Sector Solar Product Sale and installation of solar (thermal and PV) and ventilation systems. Coordinates 51.131202°, 14.106809° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":51.131202,"lon":14.106809,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

49

Direct Non-oxidative Methane Conversion by Non-thermal Plasma: Experimental Study  

Science Journals Connector (OSTI)

The direct non-oxidative conversion of methane to higher hydrocarbons in non-thermal plasma, namely dielectric barrier discharge and corona discharge, has been investigated experimentally at atmospheric pressure....

Yun Yang

2003-06-01T23:59:59.000Z

50

Laser system using regenerative amplifier  

DOE Patents (OSTI)

High energy laser system using a regenerative amplifier, which relaxes all constraints on laser components other than the intrinsic damage level of matter, so as to enable use of available laser system components. This can be accomplished by use of segmented components, spatial filters, at least one amplifier using solid state or gaseous media, and separated reflector members providing a long round trip time through the regenerative cavity, thereby allowing slower switching and adequate time to clear the spatial filters, etc. The laser system simplifies component requirements and reduces component cost while providing high energy output.

Emmett, John L. [Pleasanton, CA

1980-03-04T23:59:59.000Z

51

Regenerative Medicine: Learning from Past Examples  

E-Print Network (OSTI)

Regenerative medicine products have characteristically shown great therapeutic potential, but limited market success. Learning from the past attempts at capturing value is critical for new and emerging regenerative medicine ...

Couto, Daniela S.

52

Synthesis of monodisperse iron oxide nanocrystals by thermal decomposition of iron carboxylate salts{  

E-Print Network (OSTI)

's group12 recently published a study of c-Fe2O3 nanocrystals with different shapes. Iron acetylacetonateSynthesis of monodisperse iron oxide nanocrystals by thermal decomposition of iron carboxylate September 2004 Iron oxide (Fe3O4, magnetite) nanocrystals of 6 to 30 nm with narrow size distributions (s

Richards-Kortum, Rebecca

53

Anode supported single chamber solid oxide fuel cells operating in exhaust gases of thermal engine  

E-Print Network (OSTI)

Anode supported single chamber solid oxide fuel cells operating in exhaust gases of thermal engine fuel cells are usually described as devices able to convert chemical energy into electrical energy. Conventional solid oxide fuel cells are separated into two compartments containing each electrode split

Boyer, Edmond

54

Composition of a thermal plasma formed from PTFE with copper in non-oxidant atmosphere.  

E-Print Network (OSTI)

1 Composition of a thermal plasma formed from PTFE with copper in non-oxidant atmosphere. Part I the minimization of given thermodynamic functions or mass action laws even with plasmas out of thermal equilibrium- . Key Words: circuit breakers, SF6, PTFE, carbon formation, copper, dielectric gas, plasma composition

Paris-Sud XI, Université de

55

Thermal resistance of contact with oxidized metal surfaces  

Science Journals Connector (OSTI)

A model of an elementary heat channel is analyzed which simulates the ... is derived which describes the increment of contact resistance due to the presence of an oxide...

V. M. Popov; A. I. Krasnoborod'ko

1973-10-01T23:59:59.000Z

56

Iodine doping effects on the lattice thermal conductivity of oxidized polyacetylene nanofibers  

SciTech Connect

Thermal transport in oxidized polyacetylene (PA) nanofibers with diameters in the range between 74 and 126?nm is measured with the use of a suspended micro heater device. With the error due to both radiation and contact thermal resistance corrected via a differential measurement procedure, the obtained thermal conductivity of oxidized PA nanofibers varies in the range between 0.84 and 1.24?W?m{sup ?1}?K{sup ?1} near room temperature, and decreases by 40%–70% after iodine doping. It is also found that the thermal conductivity of oxidized PA nanofibers increases with temperature between 100 and 350?K. Because of exposure to oxygen during sample preparation, the PA nanofibers are oxidized to be electrically insulating before and after iodine doping. The measurement results reveal that iodine doping can result in enhanced lattice disorder and reduced lattice thermal conductivity of PA nanofibers. If the oxidation issue can be addressed via further research to increase the electrical conductivity via doping, the observed suppressed lattice thermal conductivity in doped polymer nanofibers can be useful for the development of such conducting polymer nanostructures for thermoelectric energy conversion.

Bi, Kedong, E-mail: lishi@mail.utexas.edu, E-mail: kedongbi@seu.edu.cn [Jiangsu Key Laboratory for Design and Manufacture of Micro-Nano Biomedical Instruments, School of Mechanical Engineering, Southeast University, Nanjing 211189 (China); Department of Mechanical Engineering, University of Texas at Austin, Austin, Texas 78712 (United States); Weathers, Annie; Pettes, Michael T.; Shi, Li, E-mail: lishi@mail.utexas.edu, E-mail: kedongbi@seu.edu.cn [Department of Mechanical Engineering, University of Texas at Austin, Austin, Texas 78712 (United States); Matsushita, Satoshi; Akagi, Kazuo [Department of Polymer Chemistry, Kyoto University, Kyoto 615-8510 (Japan); Goh, Munju [Department of Polymer Chemistry, Kyoto University, Kyoto 615-8510 (Japan); Institute of Advanced Composite Materials, Korea Institute of Science and Technology (KIST), Eunha-ri san 101, Bondong-eup, Wanju-gun, Jeolabuk-do 565-905 (Korea, Republic of)

2013-11-21T23:59:59.000Z

57

Regenerative Boiler Feedwater Heater Economics  

E-Print Network (OSTI)

REGENERATIVE BOILER FEEDWATER HEATER ECONOMICS William L. Viar, PE waterland, Viar & Associates, Inc. Wilmington, Delaware ABSTRACT The basic Rankine Vapor Cycle has been r,~peatedly modified to improve efficiency. Always, the objective....g., first and second laws of thermodynamics) have improved and contributed to the evolution. The demands for larger systems with higher performance have been persistent. Progress i ve changes in the app1icat ion of the fundamental Rankine cycle have...

Viar, W. L.

58

Exfoliation of Graphite Oxide in Propylene Carbonate and Thermal  

E-Print Network (OSTI)

disper- sions in organic solvents is also highly desir- able and may further broaden the scope organic solvents by diluting the colloidal suspension of RG-O platelets in DMF/H2O (9:1) with solvents as a "green" route to suspensions of RG-O.23 Direct thermal treatment at elevated tem- peratures provides

59

Regenerative Architecture: A Pathway Beyond Sustainability.  

E-Print Network (OSTI)

??The current paradigm in the field of architecture today is one of degeneration and obsolete building technologies. Regenerative architecture is the practice of engaging the… (more)

Littman, Jacob A

2009-01-01T23:59:59.000Z

60

Advanced regenerative absorption refrigeration cycles  

DOE Patents (OSTI)

Multi-effect regenerative absorption cycles which provide a high coefficient of performance (COP) at relatively high input temperatures. An absorber-coupled double-effect regenerative cycle (ADR cycle) (10) is provided having a single-effect absorption cycle (SEA cycle) (11) as a topping subcycle and a single-effect regenerative absorption cycle (1R cycle) (12) as a bottoming subcycle. The SEA cycle (11) includes a boiler (13), a condenser (21), an expansion device (28), an evaporator (31), and an absorber (40), all operatively connected together. The 1R cycle (12) includes a multistage boiler (48), a multi-stage resorber (51), a multisection regenerator (49) and also uses the condenser (21), expansion device (28) and evaporator (31) of the SEA topping subcycle (11), all operatively connected together. External heat is applied to the SEA boiler (13) for operation up to about 500 degrees F., with most of the high pressure vapor going to the condenser (21) and evaporator (31) being generated by the regenerator (49). The substantially adiabatic and isothermal functioning of the SER subcycle (12) provides a high COP. For higher input temperatures of up to 700 degrees F., another SEA cycle (111) is used as a topping subcycle, with the absorber (140) of the topping subcycle being heat coupled to the boiler (13) of an ADR cycle (10). The 1R cycle (12) itself is an improvement in that all resorber stages (50b-f) have a portion of their output pumped to boiling conduits (71a-f) through the regenerator (49), which conduits are connected to and at the same pressure as the highest pressure stage (48a) of the 1R multistage boiler (48).

Dao, Kim (14 Nace Ave., Piedmont, CA 94611)

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Carbon Diffusion and Clustering in SiGeC Layers Under Thermal Oxidation D. De Salvador1  

E-Print Network (OSTI)

in order to distinguish the pure thermal effects from those produced by the I injection under oxidationCarbon Diffusion and Clustering in SiGeC Layers Under Thermal Oxidation D. De Salvador1 , E to the formation and growth of C containing precipitates which are promoted by the I injection and act as a sink

62

Evidence of Nanocrystalline Semiconducting Graphene Monoxide during Thermal Reduction of Graphene Oxide in Vacuum  

Science Journals Connector (OSTI)

Our results indicate that the resulting thermally reduced G-O (TRG-O) consists of a two-dimensional nanocrystalline phase segregation: unoxidized graphitic regions are separated from highly oxidized regions of GMO. ... Two different systems are used as a platform to explore these interactions, namely, epitaxial graphene/SiC(0001) functionalized with atomic oxygen (graphene ... ...

Eric C. Mattson; Haihui Pu; Shumao Cui; Marvin A. Schofield; Sonny Rhim; Ganhua Lu; Michael J. Nasse; Rodney S. Ruoff; Michael Weinert; Marija Gajdardziska-Josifovska; Junhong Chen; Carol J. Hirschmugl

2011-11-21T23:59:59.000Z

63

Thermal oxidation of polycrystalline and single crystalline aluminum nitride wafers (Prop 2003-054)  

SciTech Connect

Two types of aluminum nitride (AlN) samples were oxidized in flowing oxygen between 900 C and 1150 C for up to 6 h - highly (0001) textured polycrystalline AlN wafers and low defect density AlN single crystals. The N-face consistently oxidized at a faster rate than the Al-face. At 900 C and 1000 C after 6 h, the oxide was 15% thicker on the N-face than on the Al-face of polycrystalline AlN. At 1100 C and 1150 C, the oxide was only 5% thicker on the N-face, as the rate-limiting step changed from kinetically-controlled to diffusion-controlled with the oxide thickness. A linear parabolic model was established for the thermal oxidation of polycrystalline AlN on both the Al- and N-face. Transmission electron microscopy (TEM) confirmed the formation of a thicker crystalline oxide film on the N-face than on the Al-face, and established the crystallographic relationship between the oxide film and substrate. The oxidation of high-quality AlN single crystals resulted in a more uniform colored oxide layer compared to polycrystalline AlN. The aluminum oxide layer was crystalline with a rough AlN/oxide interface. The orientation relationship between AlN and Al{sub 2}O{sub 3} was (0001) AlN//(10{bar 1}0) Al{sub 2}O{sub 3} and (1{bar 1}00) AlN//(01{bar 1}2) Al{sub 2}O{sub 3}.

Speakman, Scott A [ORNL; Gu, Z [Kansas State University; Edgar, J H [Kansas State University; Blom, Douglas Allen [ORNL; Perrin, J [Kansas State University; Chaudhuri, J [Kansas State University

2006-10-01T23:59:59.000Z

64

Effect of Thermal Neutron Irradiation on Oxide Catalysts for the Decomposition of Nitrous Oxide  

Science Journals Connector (OSTI)

... alpha-particles which are produced by an (n, a) reaction with lithium-6 or boron-10 atoms. Nickel oxide contains excess oxygen ions as a £-type semiconductor and probably ...

YASUKAZU SAITO; YUKIO YONEDA; SHOJI MAKISHIMA

1959-02-07T23:59:59.000Z

65

Standard Test Method for Thermal Oxidative Resistance of Carbon Fibers  

E-Print Network (OSTI)

1.1 This test method covers the apparatus and procedure for the determination of the weight loss of carbon fibers, exposed to ambient hot air, as a means of characterizing their oxidative resistance. 1.2 The values stated in SI units are to be regarded as standard. The values given in parentheses are mathematical conversions to inch-pound units which are provided for information only and are not considered standard. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard information, see Section 8.

American Society for Testing and Materials. Philadelphia

1982-01-01T23:59:59.000Z

66

Regenerative Fuel Cells for Energy Storage | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Regenerative Fuel Cells for Energy Storage Regenerative Fuel Cells for Energy Storage Presentation by Corky Mittelsteadt, Giner Electrochemical Systems, at the NREL Reversible Fuel...

67

I n s i t u thermal oxidation for surface cleaning and mask generation prior to selective area epitaxy  

Science Journals Connector (OSTI)

Dry thermal oxidation of GaAs and AlAs has been carried out in an organometallic chemical vapor deposition system. This i n s i t u process performed either before or after an epitaxialgrowth serves the purposes of surface cleaning and mask generation for selective area epitaxy of various III?V semiconductors.AlAsoxidized immediately after growth and patterned for the next regrowth provides better oxide?semiconductor interfaces and minimizes wafer handling. Pre?epitaxy oxidation at 435?°C on a patterned wafer with AlAs/GaAs areas resulted in a selective oxide mask. Since thermal oxides of GaAssublime at temperatures >600?°C a 700?°C pregrowth annealing thus thermally cleans the oxidizedGaAs areas while the oxides of AlAs remain as a mask for the following regrowth. Photoluminescence results indicate that high quality regrown interfaces have been obtained.

Stephen H. Jones; Kei May Lau

1988-01-01T23:59:59.000Z

68

Iron(III) Oxides from Thermal ProcessesSynthesis, Structural and Magnetic Properties, Mössbauer Spectroscopy Characterization, and Applications  

Science Journals Connector (OSTI)

Structural and magnetic properties, methods of synthesis, and applications of seven iron(III) oxide polymorphs, including rare beta, epsilon, amorphous, and high-pressure forms, are reviewed. ... Their discoveries as well as the majority of formation processes are connected with thermal transformations of iron-bearing materials in an oxidizing atmosphere. ... Iron(III) oxide in all its forms is one of the most used metal oxides with various applications in many scientific and industrial fields. ...

Radek Zboril; Miroslav Mashlan; Dimitris Petridis

2002-02-28T23:59:59.000Z

69

The steady-state thermal-hydraulic performance of 3500 MWth metal and oxide fueled LMRs  

SciTech Connect

The thermal-hydraulic performance of a 3500 MWth metal and oxide fueled LMR is reported. Orifice zones are defined and coolant flowrates are given for use in safety analyses. The flux calculations were carried out in three-dimensional hexagonal-Z geometry using a finite differenced diffusion theory code. The heating calculations included the transport and deposition of gamma energy. The assembly temperature calculations were performed using a subchannel code.

Vilim, R.B.; Hill, R.N.

1989-03-01T23:59:59.000Z

70

Regenerative medicine: the emergence of an industry  

Science Journals Connector (OSTI)

...orthopaedic area followed by neural repair, the cardiovascular area, inflammatory...products in the regenerative medicine pipeline. This is in addition to 28 products...ECMs as scaffolds for musculoskeletal repair. Clin. Ortho. Relat. Res. 3675...

2010-01-01T23:59:59.000Z

71

TiO2/graphene composite from thermal reaction of graphene oxide and its photocatalytic activity in visible light  

Science Journals Connector (OSTI)

In this study, the P25 TiO2 nanoparticles and graphene sheets (GSs) composite were prepared from a facile thermal reaction of graphene oxide. Its microstructures and photocatalytic properties were ... nm in the a...

Yupeng Zhang; Chunxu Pan

2011-04-01T23:59:59.000Z

72

Regenerative fuel cell engineering - FY99  

SciTech Connect

The authors report the work conducted by the ESA-EPE Fuel Cell Engineering Team at Los Alamos National Laboratory during FY99 on regenerative fuel cell system engineering. The work was focused on the evaluation of regenerative fuel cell system components obtained through the RAFCO program. These components included a 5 kW PEM electrolyzer, a two-cell regenerative fuel cell stack, and samples of the electrolyzer membrane, anode, and cathode. The samples of the electrolyzer membrane, anode, and cathode were analyzed to determine their structure and operating characteristics. Tests were conducted on the two-cell regenerative fuel cell stack to characterize its operation as an electrolyzer and as a fuel cell. The 5 kW PEM electrolyzer was tested in the Regenerative Fuel Cell System Test Facility. These tests served to characterize the operation of the electrolyzer and, also, to verify the operation of the newly completed test facility. Future directions for this work in regenerative fuel cell systems are discussed.

Michael A. Inbody; Rodney L. Borup; James C. Hedstrom; Jose Tafoya; Byron Morton; Lois Zook; Nicholas E. Vanderborgh

2000-01-01T23:59:59.000Z

73

Regenerative rotary displacer Stirling engine  

SciTech Connect

A few rotary displacer Stirling engines in which the displacer has one gas pocket space at one side and rotates in a main enclosed cylinder, which is heated from one side and cooled from opposite side without any regenerator, have been studied for some time by the authors. The authors tried to improve this engine by equipping it with a regenerator, because without a regenerator, pressure oscillation and efficiency are too small. Here, several types of regenerative rotary displacer piston Stirling engines are proposed. One is the contra-rotating tandem two disc type displacer engine using axial heat conduction through side walls or by heat pipes and another is a single disc type with circulating fluid regenerator or heat pipes. Stirling engines of this new rotary displacer type are thought to attain high speed. Here, experimental results of the original rotary displacer Stirling engine without a regenerator, and one contra-rotating tandem displacer engine with side wall regenerator by axial heat conduction are reported accompanied with a discussion of the results.

Isshiki, Naotsugu; Watanabe, Hiroichi [Nihon Univ. Tokyo (Japan); Raggi, L. [Waseda Univ., Tokyo (Japan); Isshiki, Seita; Hirata, Koichi

1996-12-31T23:59:59.000Z

74

Batch Coffee Roasting; Roasting Energy Use; Reducing That Use  

Science Journals Connector (OSTI)

Regenerative thermal oxidizers (RTOs) use regenerative heat exchange to heat afterburner feeds from T GO to appropriate T ...

Henry Schwartzberg

2013-01-01T23:59:59.000Z

75

Iron(III) Oxide Nanoparticles in the Thermally Induced Oxidative Decomposition of Prussian Blue, Fe4[Fe(CN)6]3  

Science Journals Connector (OSTI)

Iron(III) Oxide Nanoparticles in the Thermally Induced Oxidative Decomposition of Prussian Blue, Fe4[Fe(CN)6]3 ... Iron(III) oxides, particularly in the form of nanoparticles, are being used as catalysts, pigments, gas sensors, contrast agents in the magnetic resonance imaging, magnetic storage media, and furthermore, as basic components in the ferrofluid technologies or in biomagnetic separation processes. ... Structural and magnetic properties, methods of synthesis, and applications of seven Fe(III) oxide polymorphs, including rare beta, epsilon, amorphous, and high-pressure forms, are reviewed. ...

Radek Zboril; Libor Machala; Miroslav Mashlan; Virender Sharma

2004-10-05T23:59:59.000Z

76

Thermal Cyclability of Reactive Air Braze Seals in Anode Supported Solid Oxide Fuel Cells  

SciTech Connect

The popularity of anode-supported solid oxide fuel cells (SOFC) has increased in tandem with the ability to fabricate thinner gas-tight yttrium-stabilized zirconia (YSZ) electrolyte layers, which can now be routinely produced on the order of 7 to 10 ?m thick. While this has significantly improved power output and decreased the required fuel cell operating temperatures, the ability to reliably seal fuel cells remains a concern. The seals must be hermetic and be robust enough to retain their hermeticity even under the extreme operating conditions of SOFCs. Perhaps the largest contributor to stresses experienced by the seal is the fact that the SOFC is an assembly of many different materials with different thermal expansion properties. Although every effort is made to minimize thermal expansion mismatches across the seals, the stresses developed during thermal cycling still jeopardize seal integrity. Reactive air brazing (RAB), a method of joining that employs a metallic, and therefore non-brittle, seal material has been used to seal electrolyte/anode bilayers, such as those in anode-supported SOFCs, to Crofer-22 alloy. The results of rupture strength testing will be reported for as-brazed and thermally cycled samples and the effect of thermal cycling on the RAB seal microstructure will be shown

Hardy, John S.; Darsell, Jens T.; Coyle, Christopher A.; Birnbaum, Jerome C.; Weil, K. Scott

2004-12-31T23:59:59.000Z

77

Isothermal and thermal cycling oxidation of hot-dip aluminide coating on flake/spheroidal graphite cast iron  

E-Print Network (OSTI)

as engineering materials in high temperature applications, such as furnace parts, turbocharger housings and exhaust manifolds that require high-temperature oxidation resistance and mechanical strength [1 been aluminized by hot-dipping, and then their oxidation and thermal fatigue resistance were evaluated

Volinsky, Alex A.

78

Diesel Oxidation Catalyst Combined to Non-Thermal Plasma: Effect on Activation Catalyst Temperature and by-products formation  

E-Print Network (OSTI)

Diesel Oxidation Catalyst Combined to Non-Thermal Plasma: Effect on Activation Catalyst Temperature efficiency together with the catalyst activation temperature when a Diesel Oxidation Catalyst (DOC) is placed the advantageous plasma catalyst coupling effect on the lowering of the catalyst activation temperature

Paris-Sud XI, Université de

79

Transient thermal behaviour of a solid oxide fuel cell Moussa Chnani, Marie-Ccile Pra, Raynal Glises, Jean Marie Kauffmann and  

E-Print Network (OSTI)

Transient thermal behaviour of a solid oxide fuel cell Moussa Chnani, Marie-Cécile Péra, Raynal provided by HTceramix. Keywords: Solid oxide fuel cell; Transient thermal modelling; Fluidic and Electrochemical modelling. 1- Introduction The solid oxide fuel cell (SOFC) is a promising technology

Paris-Sud XI, Université de

80

A thermally self-sustained micro-power plant with integrated micro-solid oxide fuel cells, micro-reformer and functional  

E-Print Network (OSTI)

A thermally self-sustained micro-power plant with integrated micro-solid oxide fuel cells, micro Micro-solid oxide fuel cell Thin films Butane reformation Chemical micro-reactors Thermally independent 2014 Accepted 8 February 2014 Available online xxx a b s t r a c t Low temperature micro-solid oxide

Daraio, Chiara

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Thermal stability and oxidation of layer-structured rhombohedral In{sub 3}Se{sub 4} nanostructures  

SciTech Connect

The thermal stability and oxidation of layer-structured rhombohedral In{sub 3}Se{sub 4} nanostructures have been investigated. In-situ synchrotron X-ray diffraction in a sealed system reveals that In{sub 3}Se{sub 4} has good thermal stability up to 900?°C. In contrast, In{sub 3}Se{sub 4} has lower thermal stability up to 550 or 200?°C when heated in an atmosphere flushed with Ar or in air, respectively. The degradation mechanism was determined to be the oxidation of In{sub 3}Se{sub 4} by O{sub 2} in the heating environment. This research demonstrates how thermal processing conditions can influence the thermal stability of In{sub 3}Se{sub 4}, suggesting that appropriate heating environment for preserving its structural integrity is required.

Han, Guang; Chen, Zhi-Gang, E-mail: j.zou@uq.edu.au, E-mail: z.chen1@uq.edu.au; Yang, Lei; Cheng, Lina [Materials Engineering, The University of Queensland, Brisbane QLD 4072 (Australia)] [Materials Engineering, The University of Queensland, Brisbane QLD 4072 (Australia); Jack, Kevin; Drennan, John [Centre for Microscopy and Microanalysis, The University of Queensland, Brisbane QLD 4072 (Australia)] [Centre for Microscopy and Microanalysis, The University of Queensland, Brisbane QLD 4072 (Australia); Zou, Jin, E-mail: j.zou@uq.edu.au, E-mail: z.chen1@uq.edu.au [Materials Engineering, The University of Queensland, Brisbane QLD 4072 (Australia) [Materials Engineering, The University of Queensland, Brisbane QLD 4072 (Australia); Centre for Microscopy and Microanalysis, The University of Queensland, Brisbane QLD 4072 (Australia)

2013-12-23T23:59:59.000Z

82

Regenerative medicine. Opportunities and challenges: a brief overview  

Science Journals Connector (OSTI)

...components of regenerative medicine is intense worldwide...man-made materials using nanotechnology to improve their surface...opportunities for regenerative medicines are immense especially...researched; the advent of nanotechnology has allowed the development...commercialization of regenerative medicines. References Appelbaum...

2010-01-01T23:59:59.000Z

83

An improved theory for regenerative pump performance  

E-Print Network (OSTI)

, impeller angles, CFD 1 INTRODUCTION Regenerative flow pumps and compressors have found many applications of publications existing in the literature is comparatively less than papers dealing with centrifugal and axial flow pump/compressor (RFP and RFC) is applied as a gas compressor there is a further advantage

Kim, Yong Jung

84

Resumption of thermal stabilization of plutonium oxide in Building 707, Rocky Flats Plant, Golden, Colorado. Environmental Assessment  

SciTech Connect

The Department of Energy is proposing thermal stabilization to enhance the safe storage of plutonium at Rocky Flats Plant until decisions are made on long-term storage and disposition of the material. The proposed action is to resume thermal stabilization of pyrophoric plutonium in Building 707 at Rocky Flats Plant. Thermal stabilization would heat the pyrophoric plutonium under controlled conditions in a glovebox furnace to promote full oxidation and convert the material into stable plutonium oxide in the form of PuO{sub 2}. Other activities associated with thermal stabilization would include post-stabilization characterization of non-pyrophoric plutonium and on-site movement of pyrophoric and non-pyrophoric plutonium. This report covers; purpose and need; proposed action; alternatives to the proposed action; affected environment; environmental effects of proposed action and no action alternative; agencies and person consulted; and public participation.

Not Available

1994-02-01T23:59:59.000Z

85

Atomistic Simulations of Mass and Thermal Transport in Oxide Nuclear Fuels  

SciTech Connect

In this talk we discuss simulations of the mass and thermal transport in oxide nuclear fuels. Redistribution of fission gases such as Xe is closely coupled to nuclear fuel performance. Most fission gases have low solubility in the fuel matrix, specifically the insolubility is most pronounced for large fission gas atoms such as Xe, and as a result there is a significant driving force for segregation of gas atoms to grain boundaries or dislocations and subsequently for nucleation of gas bubbles at these sinks. The first step of the fission gas redistribution is diffusion of individual gas atoms through the fuel matrix to existing sinks, which is governed by the activation energy for bulk diffusion. Fission gas bubbles are then formed by either separate nucleation events or by filling voids that were nucleated at a prior stage; in both cases their formation and latter growth is coupled to vacancy dynamics and thus linked to the production of vacancies via irradiation or thermal events. In order to better understand bulk Xe behavior (diffusion mechanisms) in UO{sub 2{+-}x} we first calculate the relevant activation energies using density functional theory (DFT) techniques. By analyzing a combination of Xe solution thermodynamics, migration barriers and the interaction of dissolved Xe atoms with U, we demonstrate that Xe diffusion predominantly occurs via a vacancy-mediated mechanism, though other alternatives may exist in high irradiation fields. Since Xe transport is closely related to diffusion of U vacancies, we have also studied the activation energy for this process. In order to explain the low value of 2.4 eV found for U migration from independent damage experiments (not thermal equilibrium) the presence of vacancy clusters must be included in the analysis. Next a continuum transport model for Xe and U is formulated based on the diffusion mechanisms established from DFT. After combining this model with descriptions of the interaction between Xe and grain boundaries derived from separate atomistic calculations, we simulate Xe redistribution for a few simple microstructures using finite element methods (FEM), as implemented in the MOOSE framework from Idaho National Laboratory. Thermal transport together with the power distribution determines the temperature distribution in the fuel rod and it is thus one of the most influential properties on nuclear fuel performance. The fuel thermal conductivity changes as function of time due to microstructure evolution (e.g. fission gas redistribution) and compositional changes. Using molecular dynamics simulations we have studied the impact of different types of grain boundaries and fission gas bubbles on UO{sub 2} thermal conductivity.

Andersson, Anders D. [Los Alamos National Laboratory; Uberuaga, Blas P. [Los Alamos National Laboratory; Du, Shiyu [Los Alamos National Laboratory; Liu, Xiang-Yang [Los Alamos National Laboratory; Nerikar, Pankaj [IBM; Stanek, Christopher R. [Los Alamos National Laboratory; Tonks, Michael [Idaho National Laboratory; Millet, Paul [Idaho National Laboratory; Biner, Bulent [Idaho National Laboratory

2012-06-04T23:59:59.000Z

86

Synthesis and structural, magnetic, thermal, and transport properties of several transition metal oxides and aresnides  

SciTech Connect

Oxide compounds containing the transition metal vanadium (V) have attracted a lot of attention in the field of condensed matter physics owing to their exhibition of interesting properties including metal-insulator transitons, structural transitions, ferromagnetic and antiferromagnetic orderings, and heavy fermion behavior. Binary vanadium oxides V{sub n}O{sub 2n-1} where 2 {le} n {le} 9 have triclinic structures and exhibit metal-insulator and antiferromagnetic transitions. The only exception is V{sub 7}O{sub 13} which remains metallic down to 4 K. The ternary vanadium oxide LiV{sub 2}O{sub 4} has the normal spinel structure, is metallic, does not undergo magnetic ordering and exhibits heavy fermion behavior below 10 K. CaV{sub 2}O{sub 4} has an orthorhombic structure with the vanadium spins forming zigzag chains and has been suggested to be a model system to study the gapless chiral phase. These provide great motivation for further investigation of some known vanadium compounds as well as to explore new vanadium compounds in search of new physics. This thesis consists, in part, of experimental studies involving sample preparation and magnetic, transport, thermal, and x-ray measurements on some strongly correlated eletron systems containing the transition metal vanadium. The compounds studied are LiV{sub 2}O{sub 4}, YV{sub 4}O{sub 8}, and YbV{sub 4}O{sub 8}. The recent discovery of superconductivity in RFeAsO{sub 1-x}F{sub x} (R = La, Ce, Pr, Gd, Tb, Dy, Sm, and Nd), and AFe{sub 2}As{sub 2} (A = Ba, Sr, Ca, and Eu) doped with K, Na, or Cs at the A site with relatively high T{sub c} has sparked tremendous activities in the condensed matter physics community and a renewed interest in the area of superconductivity as occurred following the discovery of the layered cuprate high T{sub c} superconductors in 1986. To discover more superconductors with hopefully higher T{sub c}'s, it is extremely important to investigate compounds having crystal structures related to the compounds showing high T{sub c} superconductivity. Along with the vanadium oxide compounds described before, this thesis describes our investigations of magnetic, structural, thermal and transport properties of EuPd{sub 2}Sb{sub 2} single crystals which have a crystal structure closely related to the AFe{sub 2}As{sub 2} compounds and also a study of the reaction kinetics of the formation of LaFeAsO{sub 1-x}F{sub x}.

Das, Supriyo

2010-05-16T23:59:59.000Z

87

Structure Evolution of Graphene Oxide during Thermally Driven Phase Transformation: Is the Oxygen Content Really Preserved?  

E-Print Network (OSTI)

A mild annealing procedure was recently proposed for the scalable enhancement of graphene oxide (GO) properties with the oxygen content preserved, which was demonstrated to be attributed to the thermally driven phase separation. In this work, the structure evolution of GO with mild annealing is closely investigated. It reveals that in addition to phase separation, the transformation of oxygen functionalities also occurs, which leads to the slight reduction of GO membranes and further the enhancement of GO properties. These results are further supported by the density functional theory based calculations. The results also show that the amount of chemically bonded oxygen atoms on graphene decreases gradually and we propose that the strongly physisorbed oxygen species constrained in the holes and vacancies on GO lattice might be responsible for the preserved oxygen content during the mild annealing procedure. The present experimental results and calculations indicate that both the diffusion and transformation of...

Sun, Pengzhan; Liu, He; Wang, Kunlin; Wu, Dehai; Xu, Zhiping; Zhu, Hongwei

2014-01-01T23:59:59.000Z

88

Maass Regenerative Energien GmbH founders | Open Energy Information  

Open Energy Info (EERE)

Maass Regenerative Energien GmbH founders Maass Regenerative Energien GmbH founders Jump to: navigation, search Name Maass Regenerative Energien GmbH founders Place Wesel, Germany Sector Solar Product Founders of the Wesel-based solar project company. References Maass Regenerative Energien GmbH founders[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Maass Regenerative Energien GmbH founders is a company located in Wesel, Germany . References ↑ "[ Maass Regenerative Energien GmbH founders]" Retrieved from "http://en.openei.org/w/index.php?title=Maass_Regenerative_Energien_GmbH_founders&oldid=348555" Categories: Clean Energy Organizations Companies Organizations Stubs What links here

89

Performance analysis of reciprocating regenerative magnetic heat pumping. Final report  

SciTech Connect

Transient flow phenomena in the regenerator tube of reciprocating magnetic heat pumps have been studied numerically and experimentally. In the numerical study, two approaches were taken: (1) solving the energy balance equations for fluid through a porous bed directly and (2) solving the Navier-Stokes equations with a buoyancy force term in the momentum equation. A flow thermal mixing problem was found in both approaches because of the piston-like motion of the regenerator tube that hinders the development of the temperature. The numerical study results show that a 45 K temperature span can be reached in 10 minutes of charge time through the use of a 7-Tesla magnetic field. Using the second numerical approach, temperature stratification in the regenerator fluid column was clearly indicated through temperature rasters. The study also calculates regenerator efficiency and energy delivery rates when heating load and cooling load are applied. Piecewise variation of the regenerator tube moving speed has been used in the present numerical study to control the mass flow rate, reduce thermal mixing of the flow and thus the regenerative losses. The gadolinium`s adiabatic temperature has been measured under 6.5 Tesla of magnet field and different of operating temperatures ranging from 285 K to 320 K. Three regenerative heat pumping tests have also been conducted based on the Reynolds number of the regenerator tube flow, namely Re=300, Re=450, and Re=750 without loads. Maximum temperature span are 12 & 11 K and 9 K for the case of Re=300, Re=450 and Re=750, respectively. Experimental data are in good agreement with the numerical calculation results, and have been used to calibrate the numerical results and to develop a design database for reciprocating-type room-temperature magnetic heat pumps.

Chen, D.T. [Oak Ridge Associated Universities, Inc., TN (United States); Murphy, R.W.; Mei, V.C.; Chen, F.C.; Lue, J.W.; Lubell, M.S. [Oak Ridge National Lab., TN (United States)

1994-02-01T23:59:59.000Z

90

Investigation of a regenerative damping concept  

E-Print Network (OSTI)

including stationary equipment, turbine engines, and automotive systems. Perhaps one of the most common uses for the damper is in the automobile suspension, where the damper controls passenger comfort and vehicle handling. The power dissipated... by automotive shock absorbers has been studied previously, and these studies begin to provide motivation for the investigation of regenerative damping. The power dissipated in an automotive shock absorber has been studied through both computer simulation...

Fodor, Michael Glenn

2012-06-07T23:59:59.000Z

91

Gas-Phase Advanced Oxidation for Effective, Efficient in Situ Control of Pollution  

Science Journals Connector (OSTI)

The process uses ozone and UV-C light to produce in situ radicals to oxidize pollution, generating particles that are removed by a filter; ozone is removed using a MnO2 honeycomb catalyst. ... (22, 23) Catalytic and thermal oxidizers can be used effectively for treating high VOC levels (>1 g/m3) but require additional fuel when pollution is below the threshold needed to maintain operating temperature; these methods have relatively high costs for installation, operation, and maintenance. ... (24) Regenerative adsorption and cryotrapping remove VOCs but consume energy and are not suitable for wet gas streams. ...

Matthew S. Johnson; Elna J. K. Nilsson; Erik A. Svensson; Sarka Langer

2014-06-23T23:59:59.000Z

92

Rapid thermal cycling of metal-supported solid oxide fuel cell membranes  

E-Print Network (OSTI)

effect of pressure on solid oxide fuel cell performance," inand flat plate solid oxide fuel cells," in Proceedings ofSymposium on Solid Oxide Fuel Cells. Electrochem. Soc. 1993,

Matus, Yuriy B.; De Jonghe, Lutgard C.; Jacobson, Craig P.; Visco, Steven J.

2004-01-01T23:59:59.000Z

93

Powering MEMS portable devices—a review of non-regenerative and regenerative  

Science Journals Connector (OSTI)

Power consumption is forecast by the International Technology Roadmap of Semiconductors (ITRS) to pose long-term technical challenges for the semiconductor industry. The purpose of this paper is threefold: (1) to provide an overview of strategies for powering MEMS via non-regenerative and regenerative power supplies; (2) to review the fundamentals of piezoelectric energy harvesting, along with recent advancements, and (3) to discuss future trends and applications for piezoelectric energy harvesting technology. The paper concludes with a discussion of research needs that are critical for the enhancement of piezoelectric energy harvesting devices.

K A Cook-Chennault; N Thambi; A M Sastry

2008-01-01T23:59:59.000Z

94

2013-2014 Handbook Stem Cell Biology and Regenerative  

E-Print Network (OSTI)

2013-2014 Handbook Stem Cell Biology and Regenerative Medicine Interdisciplinary Graduate Program and yet focus specifically on fundamentals of biology and medicine necessary for a successful career

Puglisi, Joseph

95

On the Use of Thermal NF3 as the Fluorination and Oxidation Agent in Treatment of Used Nuclear Fuels  

SciTech Connect

This paper presents results of our investigation on the use of nitrogen trifluoride as the fluorination or fluorination/oxidation agent for use in a process for separating valuable constituents from used nuclear fuels by employing the volatility of many transition metal and actinide fluorides. Nitrogen trifluoride is less chemically and reactively hazardous than the hazardous and aggressive fluorinating agents used to prepare uranium hexafluoride and considered for fluoride volatility based nuclear fuels reprocessing. In addition, nitrogen trifluoride’s less aggressive character may be used to separate the volatile fluorides from used fuel and from themselves based on the fluorination reaction’s temperature sensitivity (thermal tunability) rather than relying on differences in sublimation/boiling temperature and sorbents. Our thermodynamic calculations found that nitrogen trifluoride has the potential to produce volatile fission product and actinide fluorides from candidate oxides and metals. Our simultaneous thermogravimetric and differential thermal analyses found that the oxides of lanthanum, cerium, rhodium, and plutonium fluorinated but did not form volatile fluorides and that depending on temperature volatile fluorides formed from the oxides of niobium, molybdenum, ruthenium, tellurium, uranium, and neptunium. We also demonstrated near-quantitative removal of uranium from plutonium in a mixed oxide.

Scheele, Randall D.; McNamara, Bruce K.; Casella, Andrew M.; Kozelisky, Anne E.

2012-05-01T23:59:59.000Z

96

Basic properties of the mixed oxides obtained by thermal decomposition of hydrotalcites containing different metallic compositions  

SciTech Connect

Carbonated layered double hydroxides (LDHs) containing Al, Fe, or Cr in a Mg(OH){sub 2} matrix or Al dissolved in hydroxides of Mg, Cu, Ni, Co, or Zn are used as precursors of basic catalysts. Decarbonation is studied by thermal analysis. The average basic strength, evaluated by the decarbonation temperature, is related to the partial charge of oxygen in the LDHs obtained from the Sanderson theory of electronegativity. The enthalpy of adsorption of CO{sub 2} on the resulting mixed oxides is measured by calorimetry. A homogeneous surface is generally observed for CO{sub 2} adsorption, with initial heats of adsorption close to those reported for MgO. The number of sites determined by this method is proportional to the rate constants for {beta}-isophorone isomerization, suggesting that both techniques measure surface properties. The layered structure in which OH{sup {minus}} is the compensating anion can be re-formed by hydration. This process does not appreciably change the adsorption of CO{sub 2}; thus, oxygens and hydroxyls show similar basic strengths in this case.

Valente, J.S.; Figueras, F.; Gravelle, M.; Kumbhar, P.; Lopez, J.; Besse, J.P.

2000-01-25T23:59:59.000Z

97

Regenerative nanotechnology in oral and maxillofacial surgery  

Science Journals Connector (OSTI)

Abstract Regenerative nanotechnology is at the forefront of medical research, and translational medicine is a challenge to both scientists and clinicians. Although there has been an exponential rise in the volume of research generated about it for both medical and surgical uses, key questions remain about its actual benefits. Nevertheless, some people think that therapeutics based on its principles may form the core of applied research for the future. Here we give an account of its current use in oral and maxillofacial surgery, and implications and challenges for the future.

Kaveh Shakib; Aaron Tan; Vukic Soskic; Alexander M. Seifalian

2014-01-01T23:59:59.000Z

98

Multilayered thermal insulation formed of zirconia bonded layers of zirconia fibers and metal oxide fibers and method for making same  

DOE Patents (OSTI)

A multilayered thermal insulating composite is formed of a first layer of zirconia-bonded zirconia fibers for utilization near the hot phase or surface of a furnace or the like. A second layer of zirconia-bonded metal oxide fibers is attached to the zirconia fiber layer by a transition layer formed of intermingled zirconia fibers and metal oxide fibers. The thermal insulation is fabricated by vacuum molding with the layers being sequentially applied from aqueous solutions containing the fibers to a configured mandrel. A portion of the solution containing the fibers forming the first layer is intermixed with the solution containing the fibers of the second layer for forming the layer of mixed fibers. The two layers of fibers joined together by the transition layer are saturated with a solution of zirconium oxynitrate which provides a zirconia matrix for the composite when the fibers are sintered together at their nexi.

Wrenn, Jr., George E. (Clinton, TN); Holcombe, Jr., Cressie E. (Farragut, TN)

1988-01-01T23:59:59.000Z

99

Current concepts: tissue engineering and regenerative medicine applications in the ankle joint  

Science Journals Connector (OSTI)

...hand, regenerative medicine (RM) is a broader...strategies [18], nanotechnologies and several medical...engineering and regenerative medicine strategies to skin...technologies such as nanotechnology [17,20,33...engineering and regenerative medicine strategies to tendon...

2014-01-01T23:59:59.000Z

100

Multiple excitation regenerative amplifier inertial confinement system  

DOE Patents (OSTI)

The invention relates to apparatus and methods for producing high intensity laser radiation generation which is achieved through an optical amplifier-storage ring design. One or two synchronized, counterpropagating laser pulses are injected into a regenerative amplifier cavity and amplified by gain media which are pumped repetitively by electrical or optical means. The gain media excitation pulses are tailored to efficiently amplify the laser pulses during each transit. After the laser pulses have been amplified to the desired intensity level, they are either switched out of the cavity by some switch means, as for example an electro-optical device, for any well known laser end uses, or a target means may be injected into the regenerative amplifier cavity in such a way as to intercept simultaneously the counterpropagating laser pulses. One such well known end uses to which this invention is intended is for production of high density and temperature plasmas suitable for generating neutrons, ions and x-rays and for studying matter heated by high intensity laser radiation. 11 figs.

George, V.E.; Haas, R.A.; Krupke, W.F.; Schlitt, L.G.

1980-05-27T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Multiple excitation regenerative amplifier inertial confinement system  

DOE Patents (OSTI)

The invention relates to apparatus and methods for producing high intensity laser radiation generation which is achieved through an optical amplifier-storage ring design. One or two synchronized, counterpropagating laser pulses are injected into a regenerative amplifier cavity and amplified by gain media which are pumped repetitively by electrical or optical means. The gain media excitation pulses are tailored to efficiently amplify the laser pulses during each transit. After the laser pulses have been amplified to the desired intensity level, they are either switched out of the cavity by some switch means, as for example an electro-optical device, for any well known laser end uses, or a target means may be injected into the regenerative amplifier cavity in such a way as to intercept simultaneously the counterpropagating laser pulses. One such well known end uses to which this invention is intended is for production of high density and temperature plasmas suitable for generating neutrons, ions and x-rays and for studying matter heated by high intensity laser radiation.

George, Victor E. [Livermore, CA; Haas, Roger A. [Pleasanton, CA; Krupke, William F. [Pleasanton, CA; Schlitt, Leland G. [Livermore, CA

1980-05-27T23:59:59.000Z

102

Thermal-Hydraulic Analysis of Advanced Mixed-Oxide Fuel Assemblies with VIPRE-01  

E-Print Network (OSTI)

depletion and core reshuffling, and fuel material thermal-physical properties. Additionally, a text-based coupling method is developed to facilitate the exchange of information between the neutronic code DRAGON and thermal-hydraulic code VIPRE-01. The new...

Bingham, Adam R.

2010-07-14T23:59:59.000Z

103

New Regenerative Cycle for Vapor Compression Refrigeration  

Office of Scientific and Technical Information (OSTI)

SCIENTIFIC REPORT SCIENTIFIC REPORT Title Page Project Title: New Regenerative Cycle for Vapor Compression Refrigeration DOE Award Number: DE-FG36-04GO14327 Document Title: Final Scientific Report Period Covered by Report: September 30, 2004 to September 30, 2005 Name and Address of Recipient Organization: Magnetic Development, Inc., 68 Winterhill Road, Madison, CT 06443, phone: 203-214-7247, fax: 203-421-7948, e-mail: mjb1000@aol.com Contact Information: Mark J. Bergander, Ph.D., P.E., Principal Investigator, phone: 203-214-7247, fax: 203-421-7948, e-mail: mjb1000@aol.com Project Objective (as stated in the proposal): The main objective of this project is to confirm on a well-instrumented prototype the theoretically derived claims of higher efficiency and coefficient

104

Mechanisms Underpinning Degradation of Protective Oxides and Thermal Barrier Coatings in High Hydrogen Content (HHC) - Fueled Turbines  

SciTech Connect

The overarching goal of this research program has been to evaluate the potential impacts of coal-derived syngas and high-hydrogen content fuels on the degradation of turbine hot-section components through attack of protective oxides and thermal barrier coatings. The primary focus of this research program has been to explore mechanisms underpinning the observed degradation processes, and connections to the combustion environments and characteristic non-combustible constituents. Based on the mechanistic understanding of how these emerging fuel streams affect materials degradation, the ultimate goal of the program is to advance the goals of the Advanced Turbine Program by developing materials design protocols leading to turbine hot-section components with improved resistance to service lifetime degradation under advanced fuels exposures. This research program has been focused on studying how: (1) differing combustion environments – relative to traditional natural gas fired systems – affect both the growth rate of thermally grown oxide (TGO) layers and the stability of these oxides and of protective thermal barrier coatings (TBCs); and (2) how low levels of fuel impurities and characteristic non-combustibles interact with surface oxides, for instance through the development of molten deposits that lead to hot corrosion of protective TBC coatings. The overall program has been comprised of six inter-related themes, each comprising a research thrust over the program period, including: (i) evaluating the role of syngas and high hydrogen content (HHC) combustion environments in modifying component surface temperatures, heat transfer to the TBC coatings, and thermal gradients within these coatings; (ii) understanding the instability of TBC coatings in the syngas and high hydrogen environment with regards to decomposition, phase changes and sintering; (iii) characterizing ash deposition, molten phase development and infiltration, and associated corrosive/thermo-chemical attack mechanisms; (iv) developing a mechanics-based analysis of the driving forces for crack growth and delamination, based on molten phase infiltration, misfit upon cooling, and loss of compliance; (v) understanding changes in TGO growth mechanisms associated with these emerging combustion product streams; and (vi) identifying degradation resistant alternative materials (including new compositions or bi-layer concepts) for use in mitigating the observed degradation modes. To address the materials stability concerns, this program integrated research thrusts aimed at: (1) Conducting tests in simulated syngas and HHC environments to evaluate materials evolution and degradation mechanisms; assessing thermally grown oxide development unique to HHC environmental exposures; carrying out high-resolution imaging and microanalysis to elucidate the evolution of surface deposits (molten phase formation and infiltration); exploring thermo-chemical instabilities; assessing thermo-mechanical drivers and thermal gradient effects on degradation; and quantitatively measuring stress evolution due to enhanced sintering and thermo-chemical instabilities induced in the coating. (2) Executing experiments to study the melting and infiltration of simulated ash deposits, and identifying reaction products and evolving phases associated with molten phase corrosion mechanisms; utilizing thermal spray techniques to fabricate test coupons with controlled microstructures to study mechanisms of instability and degradation; facilitating thermal gradient testing; and developing new materials systems for laboratory testing; (3) Correlating information on the resulting combustion environments to properly assess materials exposure conditions and guide the development of lab-scale simulations of material exposures; specification of representative syngas and high-hydrogen fuels with realistic levels of impurities and contaminants, to explore differences in heat transfer, surface degradation, and deposit formation; and facilitating combustion rig testing of materials test coupons.

Mumm, Daniel

2013-08-31T23:59:59.000Z

105

Adaptive controller for regenerative and friction braking system  

DOE Patents (OSTI)

A regenerative and friction braking system for a vehicle having one or more roadwheels driven by an electric traction motor includes a driver responsive device for producing a brake demand signal having a magnitude corresponding to the level of braking force selected by the driver and friction and regenerative brakes operatively connected with the roadwheels of the vehicle. A system according to this invention further includes control means for operating the friction and regenerative braking subsystems so that maximum brake torques sustainable by the roadwheels of the vehicle without skidding or slipping will not be exceeded.

Davis, Roy I. (Ypsilanti, MI)

1990-01-01T23:59:59.000Z

106

Thermal oxidation of single crystal aluminum antimonide and materials having the same  

DOE Patents (OSTI)

In one embodiment, a method for forming a non-conductive crystalline oxide layer on an AlSb crystal includes heat treating an AlSb crystal in a partial vacuum atmosphere at a temperature conducive for air adsorbed molecules to desorb, surface molecule groups to decompose, and elemental Sb to evaporate from a surface of the AlSb crystal and exposing the AlSb crystal to an atmosphere comprising oxygen to form a crystalline oxide layer on the surface of the AlSb crystal. In another embodiment, a method for forming a non-conductive crystalline oxide layer on an AlSb crystal includes heat treating an AlSb crystal in a non-oxidizing atmosphere at a temperature conducive for decomposition of an amorphous oxidized surface layer and evaporation of elemental Sb from the AlSb crystal surface and forming stable oxides of Al and Sb from residual surface oxygen to form a crystalline oxide layer on the surface of the AlSb crystal.

Sherohman, John William; Yee, Jick Hong; Coombs, III, Arthur William; Wu, Kuang Jen J.

2012-12-25T23:59:59.000Z

107

Direct Non-oxidative Methane Conversion by Non-thermal Plasma: Modeling Study  

Science Journals Connector (OSTI)

The direct non-oxidative conversion of methane to higher hydrocarbons ... dielectric barrier discharges has been investigated theoretically at atmospheric pressure. Preliminary modeling of the results is...2...hy...

Yun Yang

2003-06-01T23:59:59.000Z

108

Methods of reducing emissions of nitrogen oxides at thermal power plants burning solid domestic waste  

Science Journals Connector (OSTI)

Essentially all the major methods of reducing the emissions of nitrogen oxides from flue gases employed in power generation have been tested on plants in Moscow which burn solid domestic waste for production of h...

A. N. Tugov; V. F. Moskvichev

2009-01-01T23:59:59.000Z

109

Thermal stability of synthetic aurichalcite implications for making mixed metal oxides for use as catalysts  

Science Journals Connector (OSTI)

TG combined with MS has been used to study the thermal decomposition of a synthetic aurichalcite with varying copper-zinc ratios from 0....3 and CuCO3.... A higher temperature decomposition at around 805°C, based...

R. L. Frost; A. J. Locke; M. C. Hales…

2008-10-01T23:59:59.000Z

110

Speciation and oxidation kinetics of arsenic in the thermal springs of Wiesbaden spa, Germany  

Science Journals Connector (OSTI)

Since 1886 arsenic has been known to be present as a trace component in the Wiesbaden thermal waters at concentrations of over 100 µg L–1. In this study for the first time molecular level speciation of arsenic w...

Susanne P. Schwenzer; Caterina E. Tommaseo…

2001-12-01T23:59:59.000Z

111

Vehicle Technologies Office Merit Review 2014: Thermally Stable Ultra-Low Temperature Oxidation Catalysts  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by [company name] at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about thermally stable ultra-low...

112

A novel integrated thermally double coupled configuration for methane steam reforming, methane oxidation and dehydrogenation of propane  

Science Journals Connector (OSTI)

Abstract The goal of this study is the simultaneous production of synthesis gas, hydrogen and propylene in a thermally double coupled steam reformer reactor. This reactor has three concentric tubes where the exothermic reaction of methane oxidation is supposed to occur in the middle tube and the inner and outer tubes are considered to be endothermic sides of steam reforming and propane dehydrogenation, respectively. The motivation is to combine the energy efficient concept of coupling one exothermic reaction with two endothermic reactions, enhancement of synthesis gas production, propylene and hydrogen production and also producing two different H2/CO ratio streams of syngas. A steady state homogeneous model of fixed bed for three sides predicts the performance of this new configuration. The simulation results are compared with corresponding predictions of the conventional steam reformer. The results prove that synthesis gas production is increased in a thermally double coupled reactor in comparison with conventional steam reforming. In addition, the thermally double coupled reactor reduces the capital and operating costs by reducing the reactor size and consumption of energy.

D. Karimipourfard; S. Kabiri; M.R. Rahimpour

2014-01-01T23:59:59.000Z

113

Compliant alkali silicate sealing glass for solid oxide fuel cell applications: thermal cycle stability and chemical compatibility  

SciTech Connect

An alkali silicate glass (SCN-1) is currently being evaluated as a candidate sealing glass for solid oxide fuel (SOFC) applications. The glass containing ~17 mole% alkalis (K2O and Na2O) remains vitreous and compliant during SOFC operation, unlike conventional SOFC sealing glasses, which experience substantial devitrification after the sealing process. The non-crystallizing compliant sealing glass has lower glass transition and softening temperatures since the microstructure remains glassy without significant crystallite formation, and hence can relieve or reduce residual stresses and also has the potential for crack healing. Sealing approaches based on compliant glass will also need to satisfy all the mechanical, thermal, chemical, physical, and electrical requirements for SOFC applications, not only in bulk properties but also at sealing interfaces. In this first of a series of papers we will report the thermal cycle stability of the glass when sealed between two SOFC components, i.e., a NiO/YSZ anode supported YSZ bilayer and a coated ferritic stainless steel interconnect material. High temperature leak rates were monitored versus thermal cycles between 700-850oC using back pressures ranging from 0.2 psi to 1.0 psi. Isothermal stability was also evaluated in a dual environment consisting of flowing dilute H2 fuel versus ambient air. In addition, chemical compatibility at the alumina and YSZ interfaces was examined with scanning electron microscopy and energy dispersive spectroscopy. The results shed new light on the topic of SOFC glass seal development.

Chou, Y. S.; Thomsen, Edwin C.; Williams, Riley T.; Choi, Jung-Pyung; Canfield, Nathan L.; Bonnett, Jeff F.; Stevenson, Jeffry W.; Shyam, Amit; Lara-Curzio, E.

2011-03-01T23:59:59.000Z

114

Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite  

E-Print Network (OSTI)

,X,O Margarita Herrera-Alonso, David L. Milius, Roberto Car,,§ Robert K. Prud'homme, and Ilhan A. Aksay, the functionalized and defective graphene sheets do not collapse back to graphite oxide but are highly agglomerated and Roberto Car (Princeton University) showed that the stress-strain behaviors of graphene sheets and SWCNTs

Aksay, Ilhan A.

115

Thermal battery cells utilizing molten nitrates as the electrolyte and oxidizer  

Science Journals Connector (OSTI)

The Ca/LiNO3...-LiCl-KCl (50-25-25 mol%) thermal battery cell can be activated at 160° C...?2.... At operating temperatures between 250 and 350° C, this system shows promise for applications requiring a sixty-min...

M. H. Miles; A. N. Fletcher

1980-03-01T23:59:59.000Z

116

Mechanisms Underpinning Degradation of Protective Oxides and Thermal Barrier Coatings in High Hydrogen Content-Fueled Turbines - University of California, Irvine  

NLE Websites -- All DOE Office Websites (Extended Search)

Mechanisms Underpinning Degradation Mechanisms Underpinning Degradation of Protective Oxides and Thermal Barrier Coatings in High Hydrogen Content-Fueled Turbines-University of California, Irvine Background Thermal barrier coatings (TBCs) and components in the hot section of gas turbines are degraded by coal-derived high hydrogen content (HHC) synthesis gas (syngas). In this project the University of California, Irvine (UCI) will provide an improved mechanistic understanding of the degradation of critical turbine system materials in HHC-fueled

117

THERMAL DESTRUCTION OF HIGHLY CHLORINATED MIXED WASTES WITHOUT GENERATING CORROSIVE OFF-GASES USING MOLTEN SALT OXIDATION (1,2)  

SciTech Connect

A pilot-scale MSO (Molten Salt Oxidation) system was used to process 45-gallons of a halogenated mixed waste that is difficult to treat with other thermal systems. The mixed waste was a halogenated solvent that consisted mostly of methylchloroform. The 80 weight percent of waste consisting of highly corrosive chlorine was captured in the first process vessel as sodium chloride. The sodium chloride leached chrome from that process vessel and the solidified salt exhibited the toxicity characteristic for chrome as measured by TCLP (Toxicity Characteristic Leaching Procedure) testing. The operating ranges for parameters such as salt bed temperature, off-gas temperature, and feed rate that enable sustained operation were identified. At feed rates below the sustainable limit, both processing capacity and maintenance requirements increased with feed rate. Design and operational modifications to increase the sustainable feed rate limit and reduce maintenance requirements reduced both salt carryover and volumetric gas flows.

Smith, W.; Feizollahi, F.

2002-02-25T23:59:59.000Z

118

Experimental study and kinetic model of monoethanolamine oxidative and thermal degradation for post-combustion CO2 capture  

Science Journals Connector (OSTI)

Abstract In the present work, a kinetic model is proposed for the prediction of amine solvent degradation in the post-combustion CO2 capture process. Solvent degradation combined to the emission of degradation products represents one of the main operational drawbacks of this process. It induces additional costs and it impacts the process efficiency and its environmental balance. In the present work, degradation is studied under accelerated conditions for the case of monoethanolamine solvent (MEA). The influence of the temperature and of the O2 and CO2 concentrations in the gas feed are studied, and their effect on the MEA loss and the emission of degradation products is quantified. Based on the experimental results, a kinetic model for both oxidative and thermal degradation of MEA is proposed and compared to previous attempts to model MEA degradation. The present kinetic model may be further used to develop a practical tool assessing solvent degradation in large-scale capture plants.

Grégoire Léonard; Dominique Toye; Georges Heyen

2014-01-01T23:59:59.000Z

119

Modeling of the Effective Elastic and Thermal Properties of Glass-Ceramic Solid Oxide Fuel Cell Seal Materials  

SciTech Connect

In this study, the effective elastic properties and coefficients of thermal expansion (CTE) of a glass-ceramic were predicted using homogenization techniques. Using G18, a glass-ceramic solid oxide fuel cell (SOFC) sealant as an initial reference material, the effectiveness of different homogenization models was investigated for a two-phase glass-ceramic. The elastic properties and CTEs of the G18 amorphous phase are currently unknown. Thus, estimated values were used as an input to the models. The predictive model offers accurate macroscopic values on both the elastic modulus and the CTE of glass-ceramic materials, providing the estimated amorphous values are reasonable. This model can be used in designing glass-ceramic SOFC seal materials for its specific operation conditions.

Milhans, Jacqueline; Ahzi, Said; Garmestani, Hamid; Khaleel, Mohammad A.; Sun, Xin; Koeppel, Brian J.

2009-05-01T23:59:59.000Z

120

The development of a preliminary correlation of data on oxide growth on 6061 aluminum under ANS thermal-hydraulic conditions  

SciTech Connect

The corrosion of aluminum alloy 6061 is being studied in a special test loop facility under the range of thermal-hydraulic conditions appropriate for fuel plate operation in the Advanced Neutron Source (ANS) reactor core. Experimental measurements describing the growth of the boehmite (Al{sub 2}O{sub 3}H{sub 2}O) films on the exposed aluminum surfaces are now available for a range of coolant conditions and heat fluxes, and these results have been analyzed to demonstrate the influence of several important experimental variables. A subset of our data base particularly appropriate to the ANS conditions presently anticipated was used to develop a preliminary correlation based on an empirical oxidation model.

Pawel, R.E.; Yoder, G.L.; West, C.D.; Montgomery, B.H.

1990-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Photoelectron spectroscopic study of the cleaned, thermally treated and oxidized Zr??Ni?? amorphaus alloy  

E-Print Network (OSTI)

microscopy have also been used. The results show that in this alloy system, nickel is unrea, ctive and remains in its metallic form; zirconium, however, interacts with oxygen through different channels at different oxygen activities during the thermal... the changes of the va- lence band spectra have been reported (e, g. Hauert et al 1985). Chemically, the activity of binary transition metal alloys for hydrogenation and isomerization reac- tions has been demonstrated by Lunin and Khan (1984). The dif...

Liang, Guiping

2012-06-07T23:59:59.000Z

122

Electric vehicle regenerative antiskid braking and traction control system  

DOE Patents (OSTI)

An antiskid braking and traction control system for an electric or hybrid vehicle having a regenerative braking system operatively connected to an electric traction motor, and a separate hydraulic braking system includes one or more sensors for monitoring present vehicle parameters and a processor, responsive to the sensors, for calculating vehicle parameters defining the vehicle behavior not directly measurable by the sensors and determining if regenerative antiskid braking control, requiring hydrualic braking control, or requiring traction control are required. The processor then employs a control strategy based on the determined vehicle state and provides command signals to a motor controller to control the operation of the electric traction motor and to a brake controller to control fluid pressure applied at each vehicle wheel to provide the appropriate regenerative antiskid braking control, hydraulic braking control, and traction control.

Cikanek, Susan R. (Wixom, MI)

1995-01-01T23:59:59.000Z

123

Lightweight pressure vessels and unitized regenerative fuel cells  

SciTech Connect

Energy storage systems have been designed using lightweight pressure vessels with unitized regenerative fuel cells (URFCs). The vessels provide a means of storing reactant gases required for URFCs; they use lightweight bladder liners that act as inflatable mandrels for composite overwrap and provide a permeation barrier. URFC systems have been designed for zero emission vehicles (ZEVs); they are cost competitive with primary FC powered vehicles that operate on H/air with capacitors or batteries for power peaking and regenerative braking. URFCs are capable of regenerative braking via electrolysis and power peaking using low volume/low pressure accumulated oxygen for supercharging the power stack. URFC ZEVs can be safely and rapidly (<5 min.) refueled using home electrolysis units. Reversible operation of cell membrane catalyst is feasible without significant degradation. Such systems would have a rechargeable specific energy > 400 Wh/kg.

Mitlitsky, F.; Myers, B.; Weisberg, A.H.

1996-09-06T23:59:59.000Z

124

Growth strains and creep in thermally grown alumina : oxide growth mechanisms.  

SciTech Connect

In situ measurements of growth strains and creep relaxation in {alpha}-Al{sub 2}O{sub 3} films, isothermally grown on {beta}-NiAl alloys at 1100 C, are reported and analyzed. Samples containing the reactive element Zr, and Zr-free samples, are examined. For Zr-free samples, steady state growth strains are compressive, whereas the growth strains are tensile when the reactive element (RE) is added to the alloy. This behavior is attributed to the counterflow of oxygen and aluminum interstitials, and to simultaneous counterflow of oxygen and aluminum vacancies, all moving through the grain boundaries. Cross diffusing oxygen and aluminum interstitials may merge and combine within the film, forming new oxide along grain boundary walls, a mechanism that leads to an in-plane compressive stress. Cross diffusing oxygen and aluminum vacancies will also merge and combine within the film; in this case material is removed from grain boundary walls, a mechanism that leads to an in-plane tensile stress. When no RE is present, the interstitial mechanism dominates and the resultant stress is compressive. Consistent with the 'dynamic segregation model', the RE slows the outdiffusion of Al interstitials permitting the tensile mechanism to dominate. This interpretation invokes the unconventional view that oxygen and aluminum interstitials and vacancies, created in and driven by the strong chemical gradient, all participate meaningfully in the scale growth process. Grain boundary diffusion measurements were obtained from low stress creep data, interpreted using the Coble model of grain boundary diffusion. Reported diffusion measurements of oxygen through grain boundaries of {alpha}-Al{sub 2}O{sub 3}, which are known to be inconsistent with oxide scale growth, are critically examined. A simple picture, a 'balanced defect model', emerges that is consistent with the dynamic segregation model, observed growth stresses and their dependence on the presence of a reactive element, sequential oxidation experiments, and our best knowledge about grain boundary diffusion coefficients.

Veal, B. W.; Paulikas, A. P.; Materials Science Division

2008-01-01T23:59:59.000Z

125

Increasing subterranean mobilization of organic contaminants and petroleum by aqueous thermal oxidation  

DOE Patents (OSTI)

In situ hydrous pyrolysis/partial oxidation of organics at the site of the organics constrained in an subsurface reservoir produces surfactants that can form an oil/water emulsion that is effectively removed from an underground formation. The removal of the oil/water emulsions is particularly useful in several applications, e.g., soil contaminant remediation and enhanced oil recovery operations. A portion of the constrained organics react in heated reservoir water with injected steam containing dissolved oxygen gas at ambient reservoir conditions to produce such surfactants.

Leif, Roald N. (San Francisco, CA); Knauss, Kevin G. (Livermore, CA); Newmark, Robin L. (Livermore, CA); Aines, Roger D. (Livermore, CA); Eaker, Craig (Alta Loma, CA)

2002-01-01T23:59:59.000Z

126

Dispersion engineering of high-Q silicon microresonators via thermal oxidation  

E-Print Network (OSTI)

We propose and demonstrate a convenient and sensitive technique for precise engineering of group-velocity dispersion in high-Q silicon microresonators. By accurately controlling the surface-oxidation thickness of silicon microdisk resonators, we are able to precisely manage the zero-dispersion wavelength while simultaneously further improving the high optical quality of our devices, with the optical Q close to a million. The demonstrated dispersion management allows us to achieve parametric generation with precisely engineerable emission wavelengths, which shows great potential for application in integrated silicon nonlinear and quantum photonics.

Jiang, Wei C; Usechak, Nicholas G; Lin, Qiang

2014-01-01T23:59:59.000Z

127

A Model of Transient Thermal Transport Phenomena Applied to the Carbonation and Calcination of a Sorbent Particle for Calcium Oxide Looping CO2 Capture  

E-Print Network (OSTI)

looping is selected as the model cycle because of its suitability for solar-driven carbon dioxide captureA Model of Transient Thermal Transport Phenomena Applied to the Carbonation and Calcination of a Sorbent Particle for Calcium Oxide Looping CO2 Capture Lindsey Yue and Wojciech Lipi´nski, The Australian

128

Ignition feedback regenerative free electron laser (FEL) amplifier  

DOE Patents (OSTI)

An ignition feedback regenerative amplifier consists of an injector, a linear accelerator with energy recovery, and a high-gain free electron laser amplifier. A fraction of the free electron laser output is coupled to the input to operate the free electron laser in the regenerative mode. A mode filter in this loop prevents run away instability. Another fraction of the output, after suitable frequency up conversion, is used to drive the photocathode. An external laser is provided to start up both the amplifier and the injector, thus igniting the system.

Kim, Kwang-Je (Burr Ridge, IL); Zholents, Alexander (Walnut Creek, CA); Zolotorev, Max (Oakland, CA)

2001-01-01T23:59:59.000Z

129

Thermal Controls for the On-Site Transfer of Mixed Oxide Scrap  

SciTech Connect

Mixed oxide scrap consisting primarily of PuO{sub 2} and UO{sub 2} is stored in crimp-sealed product cans at Savannah River Site (SRS). The product cans are to be transported onsite to a processing facility for dissolution using an earlier version of the 9975 (prior to the redesigned drum closure) package called DDF-1. This paper compares the maximum plutonium temperatures inside the DDF-1 and the maximum temperatures when the product can is in a storage vault. The comparison shows that the maximum Pu temperature for low wattage cans are marginally higher during transport provided the drum packages are kept out of sunlight. At higher wattage the differences become significant. The application of this work is to provide guidance and an estimate of temperature sensitive chemical reactions during transport compared with storage.

Gupta, N.K.

2001-05-08T23:59:59.000Z

130

Regenerative oscillation and four-wave mixing in graphene optoelectronics  

E-Print Network (OSTI)

Regenerative oscillation and four-wave mixing in graphene optoelectronics T. Gu1 *, N. Petrone2 , J consecutive first observations in graphene­ silicon hybrid optoelectronic devices--ultralow-power resonant optoelectronics and all-optical signal processing. S ubwavelength nanostructures in monolithic material platforms

Hone, James

131

Alkaline regenerative fuel cell systems for energy storage  

SciTech Connect

This paper presents the results of a preliminary design study of a Regenerative Fuel Cell Energy Storage system for application to future low-earth orbit space missions. This high energy density storage system is based on state-of-the-art alkaline electrolyte cell technology and incorporates dedicated fuel cell and electrolysis cell modules. 11 refs.

Schubert, F.H.; Reid, M.A.; Martin, R.E.

1981-01-01T23:59:59.000Z

132

Oxidation, graphitization and thermal resistance of PCD materials with the various bonding phases of up to 800 °C  

Science Journals Connector (OSTI)

Abstract Three types of polycrystalline diamond composites (PCDs) were studied. The first material was sintered using the mixture containing 80 wt.% diamond, 15 wt.% of Ti–Si–C powder (mixture of 47.1 wt.% Ti3SiC2 and TiSi2, TiC and SiC, from self-propagating high-temperature synthesis) and 5 wt.% nanometric Ti(CN) powders. The second material was prepared using diamond powder and 10 wt.% of titanium diboride. Materials were sintered using a Bridgman-type high-pressure apparatus at 8 GPa and at the temperature of 2000 °C. The third material was a commercial PCD containing 88 wt.% of diamond, 10 wt.% of Co and 2 wt.% of WC. The coefficients of friction for diamond composites in a sliding contact with an Al2O3 ceramic ball were determined from room temperature of up to 800 °C, in air. X-ray diffraction patterns of diamond composites after HP–HT sintering and wear tests are presented. In the studies, due to the use of Raman spectroscopy the strong influence of the bonding phase on the oxidation of diamond composites was confirmed. The most thermally stable material is the diamond composite with TiB2. High temperature bonding phase for diamond composites guarantees higher hardness and low coefficient of friction at elevated temperatures.

Lucyna Jaworska; Magdalena Szutkowska; Piotr Klimczyk; Maciej Sitarz; Miroslaw Bucko; Pawel Rutkowski; Pawel Figiel; Joanna Lojewska

2014-01-01T23:59:59.000Z

133

Identification of volatile butyl rubber thermal-oxidative degradation products by cryofocusing gas chromatography/mass spectrometry (cryo-GC/MS).  

SciTech Connect

Chemical structure and physical properties of materials, such as polymers, can be altered as aging progresses, which may result in a material that is ineffective for its envisioned intent. Butyl rubber formulations, starting material, and additives were aged under thermal-oxidative conditions for up to 413 total days at up to 124 %C2%B0C. Samples included: two formulations developed at Kansas City Plant (KCP) (%236 and %2310), one commercially available formulation (%2321), Laxness bromobutyl 2030 starting material, and two additives (polyethylene AC-617 and Vanax MBM). The low-molecular weight volatile thermal-oxidative degradation products that collected in the headspace over the samples were preconcentrated, separated, and detected using cryofocusing gas chromatography mass spectrometry (cryo-GC/MS). The majority of identified degradation species were alkanes, alkenes, alcohols, ketones, and aldehydes. Observations for Butyl %2310 aged in an oxygen-18 enriched atmosphere (18O2) were used to verify when the source of oxygen in the applicable degradation products was from the gaseous environment rather than the polymeric mixture. For comparison purposes, Butyl %2310 was also aged under non-oxidative thermal conditions using an argon atmosphere.

Smith, Jonell Nicole; White, Michael Irvin; Bernstein, Robert; Hochrein, James Michael

2013-02-01T23:59:59.000Z

134

Chapter 71 - Ethics in Regenerative Medicine and Transplantation  

Science Journals Connector (OSTI)

The relationship between regenerative medicine and organ transplantation is characterized by a high degree of complexity and variety, an extraordinary combination of disciplines and technologies, and a broad range of translational development. Research in regenerative medicine and organ transplantation therefore raises an unprecedented mix of ethical issues, both familiar and constantly changing as science advances and societal priorities change. Despite its enormous promise, organ regeneration research remains in the early stages, sharing many features of first-in-human trials, but also expanding and updating the ethical considerations relevant to translational research. These include balancing harms and benefits; ensuring that research is well designed and therefore likely to yield useful data; equitable selection of research subjects; informed consent and the therapeutic misconception; long-term follow-up; and cost, access, and distributive justice.

Nancy M.P. King

2014-01-01T23:59:59.000Z

135

Chapter 30 - Applications of Nanotechnology for Regenerative Medicine  

Science Journals Connector (OSTI)

Publisher Summary This chapter examines the impact of nanotechnology on regenerative medicine related to cellular therapies and biomaterial control, which play an important role for implant design and tissue engineering. Cellular therapies for regenerative medicine would benefit from nanotechnology since tracking of implanted cells would provide the means to better evaluate the viability of engineered tissues and help in understanding the biodistribution and migration pathways of transplanted cells. Nanotechnology would also allow better and more intelligent control of the bioactive factors, which can influence cellular therapies. Biomaterials play an important role in regenerative medicine because they make up a large component of implants and tissue scaffolds. Biocompatible scaffolds could provide temporary structural support guiding cell growth, assist the transportation of essential nutrients, and facilitate the formation of functional tissues and organs. Increasing evidence shows that the nature of the biomaterial greatly affects long-term success of biomedical implants and short-term wound healing response. Substrate features such as the chemical composition and surface morphology affect the viability, adhesion, morphology, and motility of cells. Therefore, controlling the three-dimensional structure and surface composition of a biomaterial is important to promoting normal tissue growth or minimizing foreign body response. The unique properties of nanomaterials and nanostructures could be particularly useful in controlling intrinsic stem cell signals and in dissecting the mechanisms underlying embryonic and adult stem cell behavior.

Benjamin S. Harrison; Sirinrath Sirivisoot

2011-01-01T23:59:59.000Z

136

Steady state thermal stress analyses of two-dimensional and three-dimensional solid oxide fuel cells.  

E-Print Network (OSTI)

??Fuel cells are electrochemical devices which convert fuels directly into electrical energy without combustion. The Solid Oxide Fuel Cell (SOFC) is the most promising energy… (more)

Valluru, Srividya.

2005-01-01T23:59:59.000Z

137

Theoretical and experimental study on regenerative rotary displacer Stirling engine  

SciTech Connect

Recently a quite new type of hot air engine called rotary displacer engine, in which the displacer is a rotating disk enclosed in a cylinder, has been conceived and developed. The working gas, contained in a notch excavated in the disk, is heated and cooled alternately, on account of the heat transferred through the enclosing cylinder that is heated at one side and cooled at the opposite one. The gas temperature oscillations cause the pressure fluctuations that get out mechanical power acting on a power piston. In order to attempt to increase the performances for this kind of engine, the authors propose three different regeneration methods. The first one comprises two coaxial disks that, revolving in opposite ways, cause a temperature gradient on the cylinder wall and a regenerative axial heat conduction through fins shaped on the cylinder inner wall. The other two methods are based on the heat transferred by a proper closed circuit that in one case has a circulating liquid inside and in the other one is formed by several heat pipes working each one for different temperatures. An engine based on the first principle, the Regenerative Tandem Contra-Rotary Displacer Stirling Engine, has been realized and experimented. In this paper experimental results with and without regeneration are reported comparatively with a detailed description of the unity. A basic explanation of the working principle of this engine and a theoretical analysis investigating the main influential parameters for the regenerative effect are done. This new rotating displacer Stirling engines, for their simplicity, are expected to attain high rotational speed especially for applications as demonstration and hobby unities.

Raggi, L.; Katsuta, Masafumi [Waseda Univ., Tokyo (Japan); Isshiki, Naotsugu [Nihon Univ., Tokyo (Japan); Isshiki, Seita [Isshiki R and D Lab., Tokyo (Japan)

1997-12-31T23:59:59.000Z

138

Propellant feed system of a regeneratively cooled scramjet  

SciTech Connect

An expander cycle for an airframe-integrated hydrogen-fueled scramjet is analyzed to study regenerative cooling characteristics and overall specific impulse. Below Mach 10, the specific impulse and thrust coincide with the reference values. At Mach numbers above 10, a reduction of the specific impulse occurs due to the coolant flow rate requirement, which is accompanied by an increase of thrust. It is shown that the thrust may be increased by injecting excess fuel into the combustor to compensate for the decrease of the specific impulse. 9 refs.

Kanda, Takeshi; Masuya, Goro; Wakamatsu, Yoshio (National Aerospace Laboratory, Kakuda (Japan))

1991-04-01T23:59:59.000Z

139

Improvements of vehicle fuel economy using mechanical regenerative braking  

Science Journals Connector (OSTI)

The paper presents a mixed theoretical and experimental evaluation of the improvements in fuel economy that follow the introduction of a mechanical Kinetic Energy Recovery System (KERS) on a full size passenger car. This system, made up of a high speed storage flywheel and a Constant Variable Transmission (CVT), has a full regenerative cycle overall efficiency about twice the efficiency of battery-based hybrids. With reference to the baseline configuration having a 4L gasoline engine, adoption of a KERS may reduce the fuel consumption covering the NEDC by 25% without downsizing, and by 33% downsizing the engine to 3.3L.

Alberto A. Boretti

2011-01-01T23:59:59.000Z

140

Asphalt Oxidation Kinetics and Pavement Oxidation Modeling  

E-Print Network (OSTI)

Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement...

Jin, Xin

2012-07-16T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Electrical characteristics and thermal stability of HfO{sub 2} metal-oxide-semiconductor capacitors fabricated on clean reconstructed GaSb surfaces  

SciTech Connect

HfO{sub 2}/GaSb interfaces fabricated by high-vacuum HfO{sub 2} deposition on clean reconstructed GaSb surfaces were examined to explore a thermally stable GaSb metal-oxide-semiconductor structure with low interface-state density (D{sub it}). Interface Sb-O bonds were electrically and thermally unstable, and post-metallization annealing at temperatures higher than 200?°C was required to stabilize the HfO{sub 2}/GaSb interfaces. However, the annealing led to large D{sub it} in the upper-half band gap. We propose that the decomposition products that are associated with elemental Sb atoms act as interface states, since a clear correlation between the D{sub it} and the Sb coverage on the initial GaSb surfaces was observed.

Miyata, Noriyuki, E-mail: nori.miyata@aist.go.jp; Mori, Takahiro; Yasuda, Tetsuji [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8568 (Japan); Ohtake, Akihiro [National Institute for Materials Science (NIMS), Tsukuba, Ibaraki 305-0044 (Japan); Ichikawa, Masakazu [The University of Tokyo, Tokyo 113-8656 (Japan)

2014-06-09T23:59:59.000Z

142

Could Gaussian regenerative stations act as quantum repeaters?  

E-Print Network (OSTI)

Higher transmission loss diminishes the performance of optical communication|be it the rate at which classical or quantum data can be sent reliably, or the secure key generation rate of quantum key distribution (QKD). Loss compounds with distance|exponentially in an optical fiber, and inverse-square with distance for a free-space channel. In order to boost classical communication rates over long distances, it is customary to introduce regenerative relays at intermediate points along the channel. It is therefore natural to speculate whether untended regenerative stations, such as phase-insensitive or phase-sensitive optical amplifiers, could serve as repeaters for long-distance QKD. The primary result of this paper rules out all bosonic Gaussian channels to be useful as QKD repeaters, which include phase-insensitive and phase-sensitive amplifiers as special cases, for any QKD protocol. We also delineate the conditions under which a Gaussian relay renders a lossy channel entanglement breaking, which in turn makes the channel useless for QKD.

Ryo Namiki; Oleg Gittsovich; Saikat Guha; Norbert Lütkenhaus

2014-10-02T23:59:59.000Z

143

Fast Threat Detection and Localization Using Super-Regenerative Transceiver in  

E-Print Network (OSTI)

Fast Threat Detection and Localization Using Super-Regenerative Transceiver in Random Noise Radar-Regenerative (SRG) transceiver as a type of ultra-fast electronics platform for threat detection and localization the Angle-of-Arrival (AOA) information of the inbound threats. Simulations and detailed laboratory

Zhang, Yan

144

A New Absorption Cycle: The Single-Effect Regenerative Absoprtion Refrigeration Cycle  

E-Print Network (OSTI)

I r;,.foO REGENERATIVE ABSORPTION Y- Wz Z .lW U t- o 0:I:I I I /f I I I ~~-/5f=- - - - ABSORPTION .c:::. ." ." ,,,"l e lR (regene r ative absorption) using NH3/H20 mixture s .

Dao, K.

2011-01-01T23:59:59.000Z

145

Integration and Dynamics of a Renewable Regenerative Hydrogen Fuel Cell System  

E-Print Network (OSTI)

Integration and Dynamics of a Renewable Regenerative Hydrogen Fuel Cell System by Alvin Peter, hydrogen and electricity storage, and fuel cells. A special design feature of this test bed is the ability of the author. #12;ii Supervisory Committee Integration and Dynamics of a Renewable Regenerative Hydrogen Fuel

Victoria, University of

146

Heat transfer and combustion characteristics of a burner with a rotary regenerative heat exchanger  

SciTech Connect

The authors have developed a Rotary Regenerative Combustion (RRX) System, which is coupled with a compact high efficiency regenerative air heat exchanger and a combustion burner. This system contributes to saving energy of fuel firing industrial furnaces and decreases NO{sub x} emission. This technology can be considered as a solution of greenhouse problem. This paper, discusses a compact high efficiency regenerative air heat exchanger in comparison with the existing types of regenerative burners and reverse firing with high momentum fuel jet (with motive fluid) in the furnace. This burner is compact in size, with high fuel efficiency, low NOx emission, easy to operate, and reliable, based on the results of field tests and commercial operations. The authors can say that the RRX system is a regenerative burner of the second generation.

Hirose, Yasuo; Kaji, Hitoshi; Arai, Norio

1998-07-01T23:59:59.000Z

147

Improving the efficiency and availability analysis of a modified reheat regenerative Rankine cycle  

SciTech Connect

Reheating in a reheat regenerative steam power cycle increases efficiency by increasing the average temperature of heat reception, but also increases the irreversibility of feed water heaters by raising the temperature of the superheated steam used for the regenerative process. This paper introduces some modifications to the regular reheat regenerative steam power cycle that reduce the irreversibility of the regenerative process. An availability analysis of the modified cycle and the regular reheat regenerative cycle as well as a comparison study between both cycles is done. The results indicate that a gain in energy efficiency of up to 2.5% as the steam generator pressure varies is obtained when applying such modifications at the same conditions of pressure, temperature's number of reheating stages, and feed water heaters. The availability analysis showed that such increase in efficiency is due to the reduction of the irreversibility of the regeneration process of the modified cycle.

Bassily, A.M.

1999-07-01T23:59:59.000Z

148

High Temperature Thermal Stability and Oxidation Resistance of Magnetron-sputtered Homogeneous CrAlON Coatings on 430 Steel  

SciTech Connect

The requirements of low cost and high-temperature corrosion resistance for bipolar interconnect plates in solid oxide fuel cell stacks has directed attention to the use of metal plates with oxidation resistant coatings. We have investigated the performance of steel plates with homogenous coatings of CrAlON (oxynitrides). The coatings were deposited using RF magnetron sputtering, with Ar as a sputtering gas. Oxygen in these coatings was not intentionally added. Oxygen might have come through contaminated nitrogen gas bottle, leak in the chamber or from the partial pressure of water vapors. Nitrogen was added during the growth process to get oxynitride coating. The Cr/Al composition ratio in the coatings was varied in a combinatorial approach. The coatings were subsequently annealed in air for up to 25 hours at 800 deg. C. The composition of the coated plates and the rate of oxidation were characterized using Rutherford backscattering (RBS) and nuclear reaction analysis (NRA). From our results, we conclude that Al rich coatings are more susceptible to oxidation than Cr rich coatings.

Kayani, A.; Wickey, K. J.; Nandasiri, M. I.; Moore, A.; Garratt, E.; AlFaify, S.; Gao, X. [Western Michigan University-Kalamazoo, MI 49008 (United States); Smith, R. J.; Buchanan, T. L.; Priyantha, W.; Kopczyk, M.; Gannon, P. E. [Montana State University-Bozeman, MT 59717 (United States); Gorokhovsky, V. I. [Arcomac Surface Engineering, LLC-Bozeman, MT 59715 (United States)

2009-03-10T23:59:59.000Z

149

Regenerative fuel cells for High Altitude Long Endurance Solar Powered Aircraft  

SciTech Connect

High Altitude Long Endurance (HALE) unmanned missions appear to be feasible using a lightweight, high efficiency, span-loaded, Solar Powered Aircraft (SPA) which includes a Regenerative Fuel Cell (RFC) system and novel tankage for energy storage. An existing flightworthy electric powered flying wing design was modified to incorporate present and near-term technologies in energy storage, power electronics, aerodynamics, and guidance and control in order to design philosophy was to work with vendors to identify affordable near-term technological opportunities that could be applied to existing designs in order to reduce weight, increase reliability, and maintain adequate efficiency of components for delivery within 18 months. The energy storage subsystem for a HALE SPA is a key driver for the entire vehicle because it can represent up to half of the vehicle weight and most missions of interest require the specific energy to be considerably higher than 200 W-hr/kg for many cycles. This stringent specific energy requirement precludes the use of rechargeable batteries or flywheels and suggests examination of various RFC designs. An RFC system using lightweight tankage, a single fuel cell (FC) stack, and a single electrolyzer (EC) stack separated by the length of a spar segment (up to 39 ft), has specific energy of {approximately}300 W-hr/kg with 45% efficiency, which is adequate for HALE SPA requirements. However, this design has complexity and weight penalties associated with thermal management, electrical wiring, plumbing, and structural weight. A more elegant solution is to use unitized RFC stacks (reversible stacks that act as both FCs and ECs) because these systems have superior specific energy, scale to smaller systems more favorably, and have intrinsically simpler thermal management.

Mitlitsky, F.; Colella, N.J.; Myers, B. [Lawrence Livermore National Lab., CA (United States); Anderson, C.J. [Aero Vironment, Inc., Monrovia, CA (United States)

1993-06-02T23:59:59.000Z

150

Thermally oxidized formation of new Ge dots over as-grown Ge dots in the Si capping layer  

SciTech Connect

A Si-capped Ge quantum dot sample was self-assembly grown via Stranski-Krastanov mode in a molecular beam epitaxy system with the Si capping layer deposited at 300 deg. C. After annealing the sample in an oxygen atmosphere at 1000 deg. C, a structure, namely two layers of quantum dots, was formed with the newly formed Ge-rich quantum dots embedded in the oxidized matrix with the position accurately located upon the as-grown quantum dots. It has been found that the formation of such nanostructures strongly depends upon the growth temperature and oxygen atmosphere. A growth mechanism was proposed to explain the formation of the nanostructure based on the Ge diffusion from the as-grown quantum dots, Ge segregation from the growing oxide, and subsequent migration/agglomeration.

Nie Tianxiao [State Key Laboratory of Surface Physics, Fudan University, Shanghai 200433 (China); Materials Engineering, University of Queensland, Brisbane, Queensland QLD 4072 (Australia); Lin Jinhui; Shao Yuanmin; Wu Yueqin; Yang Xinju; Fan Yongliang; Jiang Zuimin [State Key Laboratory of Surface Physics, Fudan University, Shanghai 200433 (China); Chen Zhigang [Materials Engineering, University of Queensland, Brisbane, Queensland QLD 4072 (Australia); Zou Jin [Materials Engineering, University of Queensland, Brisbane, Queensland QLD 4072 (Australia); Centre for Microscopy and Microanalysis, University of Queensland, Brisbane, Queensland QLD 4072 (Australia)

2011-12-01T23:59:59.000Z

151

Fuzzy logic electric vehicle regenerative antiskid braking and traction control system  

DOE Patents (OSTI)

An regenerative antiskid braking and traction control system using fuzzy logic for an electric or hybrid vehicle having a regenerative braking system operatively connected to an electric traction motor, and a separate hydraulic braking system includes sensors for monitoring present vehicle parameters and a processor, responsive to the sensors, for calculating vehicle parameters defining the vehicle behavior not directly measurable by the sensor and determining if regenerative antiskid braking control, requiring hydraulic braking control, and requiring traction control are required. The processor then employs fuzzy logic based on the determined vehicle state and provides command signals to a motor controller to control operation of the electric traction motor and to the brake controller to control fluid pressure applied at each vehicle wheel to provide the appropriate regenerative braking control, hydraulic braking control, and traction control.

Cikanek, Susan R. (Wixom, MI)

1994-01-01T23:59:59.000Z

152

Compliant alkali silicate sealing glass for solid oxide fuel cell applications: Combined stability in isothermal ageing and thermal cycling with YSZ coated ferritic stainless steels  

SciTech Connect

An alkali-containing silicate glass (SCN-1) is currently being evaluated as a candidate sealing glass for solid oxide fuel cell (SOFC) applications. The glass contains about 17 mole% alkalis (K+Na) and has low glass transition and softening temperatures. It remains vitreous and compliant around 750-800oC after sealing without substantial crystallization, as contrary to conventional glass-ceramic sealants, which experience rapid crystallization after the sealing process. The glassy nature and low characteristic temperatures can reduce residual stresses and result in the potential for crack healing. In a previous study, the glass was found to have good thermal cycle stability and was chemically compatible with YSZ coating during short term testing. In the current study, the compliant glass was further evaluated in a more realistic way in that the sealed glass couples were first isothermally aged for 1000h followed by thermal cycling. High temperature leakage was measured. The chemical compatibility was also investigated with powder mixtures at 700 and 800oC to enhance potential interfacial reaction. In addition, interfacial microstructure was examined with scanning electron microscopy and evaluated with regard to the leakage and chemical compatibility results.

Chou, Y. S.; Thomsen, Edwin C.; Choi, Jung-Pyung; Stevenson, Jeffry W.

2012-01-01T23:59:59.000Z

153

Power production from a moderate temperature geothermal resource with regenerative Organic Rankine Cycles  

Science Journals Connector (OSTI)

Much remains to be done in binary geothermal power plant technology, especially for exploiting low-enthalpy resources. Due to the great variability of available resources (temperature, pressure, chemical composition), it is really difficult to “standardize the technology”.The problem involves many different variables: working fluid selection, heat recovery system definition, heat transfer surfaces sizing and auxiliary systems consumption. Electricity generation from geothermal resources is convenient if temperature of geothermal resources is higher than 130 °C. Extension of binary power technology to use low-temperature geothermal resources has received much attention in the last years. This paper analyzes and discusses the exploitation of low temperature, water-dominated geothermal fields with a specific attention to regenerative Organic Rankine Cycles (ORC). The geothermal fluid inlet temperatures considered are in the 100–130 °C range, while the return temperature of the brine is assumed to be between 70 and 100 °C. The performances of different configurations, two basic cycle configurations and two recuperated cycles are analyzed and compared using dry organic fluids as the working fluids. The dry organic fluids for this study are R134a, isobutane, n-pentane and R245fa. Effects of the operating parameters such as turbine inlet temperature and pressure on the thermal efficiency, exergy destruction rate and Second Law efficiency are evaluated. The possible advantages of recuperated configurations in comparison with basic configurations are analyzed, showing that in a lot of cases the advantage in terms of performance increase is minimal but significant reductions in cooling systems surface area can be obtained (up to 20%).

Alessandro Franco

2011-01-01T23:59:59.000Z

154

The feasibility of a unitised regenerative fuel cell with a reversible carbon-based hydrogen storage electrode.  

E-Print Network (OSTI)

??This thesis seeks to experimentally demonstrate the possibility of reversible storage of hydrogen directly into a carbon-based electrode of a PEM unitised regenerative fuel cell.… (more)

Jazaeri, M

2013-01-01T23:59:59.000Z

155

Adaptive scapula bone remodeling computational simulation: Relevance to regenerative medicine  

SciTech Connect

Shoulder arthroplasty success has been attributed to many factors including, bone quality, soft tissue balancing, surgeon experience, and implant design. Improved long-term success is primarily limited by glenoid implant loosening. Prosthesis design examines materials and shape and determines whether the design should withstand a lifetime of use. Finite element (FE) analyses have been extensively used to study stresses and strains produced in implants and bone. However, these static analyses only measure a moment in time and not the adaptive response to the altered environment produced by the therapeutic intervention. Computational analyses that integrate remodeling rules predict how bone will respond over time. Recent work has shown that subject-specific two- and three dimensional adaptive bone remodeling models are feasible and valid. Feasibility and validation were achieved computationally, simulating bone remodeling using an intact human scapula, initially resetting the scapular bone material properties to be uniform, numerically simulating sequential loading, and comparing the bone remodeling simulation results to the actual scapula’s material properties. Three-dimensional scapula FE bone model was created using volumetric computed tomography images. Muscle and joint load and boundary conditions were applied based on values reported in the literature. Internal bone remodeling was based on element strain-energy density. Initially, all bone elements were assigned a homogeneous density. All loads were applied for 10 iterations. After every iteration, each bone element’s remodeling stimulus was compared to its corresponding reference stimulus and its material properties modified. The simulation achieved convergence. At the end of the simulation the predicted and actual specimen bone apparent density were plotted and compared. Location of high and low predicted bone density was comparable to the actual specimen. High predicted bone density was greater than actual specimen. Low predicted bone density was lower than actual specimen. Differences were probably due to applied muscle and joint reaction loads, boundary conditions, and values of constants used. Work is underway to study this. Nonetheless, the results demonstrate three dimensional bone remodeling simulation validity and potential. Such adaptive predictions take physiological bone remodeling simulations one step closer to reality. Computational analyses are needed that integrate biological remodeling rules and predict how bone will respond over time. We expect the combination of computational static stress analyses together with adaptive bone remodeling simulations to become effective tools for regenerative medicine research.

Sharma, Gulshan B., E-mail: gbsharma@ucalgary.ca [Emory University, Department of Radiology and Imaging Sciences, Spine and Orthopaedic Center, Atlanta, Georgia 30329 (United States); University of Pittsburgh, Swanson School of Engineering, Department of Bioengineering, Pittsburgh, Pennsylvania 15213 (United States); University of Calgary, Schulich School of Engineering, Department of Mechanical and Manufacturing Engineering, Calgary, Alberta T2N 1N4 (Canada); Robertson, Douglas D., E-mail: douglas.d.robertson@emory.edu [Emory University, Department of Radiology and Imaging Sciences, Spine and Orthopaedic Center, Atlanta, Georgia 30329 (United States); University of Pittsburgh, Swanson School of Engineering, Department of Bioengineering, Pittsburgh, Pennsylvania 15213 (United States)

2013-07-01T23:59:59.000Z

156

Investigation of the part-load performance of two 1. 12 MW regenerative marine gas turbines  

SciTech Connect

Regenerative and intercooled-regenerative gas turbine engines with low pressure ratio have significant efficiency advantages over traditional aero-derivative engines of higher pressure ratios, and can compete with modern diesel engines for marine propulsion. Their performance is extremely sensitive to thermodynamic-cycle parameter choices and the type of components. The performance of two 1.12 MW (1,500 hp) regenerative gas turbines are predicted with computer simulations. One engine has a single-shaft configuration, and the other has a gas-generator/power-turbine combination. The latter arrangement is essential for wide off-design operating regime. The performance of each engine driving fixed-pitch and controllable-pitch propellers, or an AC electric bus (for electric-motor-driven propellers) is investigated. For commercial applications the controllable-pitch propeller may have efficiency advantages (depending on engine type and shaft arrangements). For military applications the electric drive provides better operational flexibility.

Korakianitis, T.; Beier, K.J. (Washington Univ., St. Louis, MO (United States). Dept. of Mechanical Engineering)

1994-04-01T23:59:59.000Z

157

Thermal-fluid and electrochemical modeling and performance study of a planar solid oxide electrolysis cell : analysis on SOEC resistances, size, and inlet flow conditions.  

SciTech Connect

Argonne National Laboratory and Idaho National Laboratory researchers are analyzing the electrochemical and thermal-fluid behavior of solid oxide electrolysis cells (SOECs) for high temperature steam electrolysis using computational fluid dynamics (CFD) techniques. The major challenges facing commercialization of steam electrolysis technology are related to efficiency, cost, and durability of the SOECs. The goal of this effort is to guide the design and optimization of performance for high temperature electrolysis (HTE) systems. An SOEC module developed by FLUENT Inc. as part of their general CFD code was used for the SOEC analysis by INL. ANL has developed an independent SOEC model that combines the governing electrochemical mechanisms based on first principals to the heat transfer and fluid dynamics in the operation of SOECs. The ANL model was embedded into the commercial STAR-CD CFD software, and is being used for the analysis of SOECs by ANL. The FY06 analysis performed by ANL and reported here covered the influence of electrochemical properties, SOEC component resistances and their contributing factors, SOEC size and inlet flow conditions, and SOEC flow configurations on the efficiency and expected durability of these systems. Some of the important findings from the ANL analysis are: (1) Increasing the inlet mass flux while going to larger cells can be a compromise to overcome increasing thermal and current density gradients while increasing the cell size. This approach could be beneficial for the economics of the SOECs; (2) The presence of excess hydrogen at the SOEC inlet to avoid Ni degradation can result in a sizeable decrease in the process efficiency; (3) A parallel-flow geometry for SOEC operation (if such a thing be achieved without sealing problems) yields smaller temperature gradients and current density gradients across the cell, which is favorable for the durability of the cells; (4) Contact resistances can significantly influence the total cell resistance and cell temperatures over a large range of operating potentials. Thus it is important to identify and avoid SOEC stack conditions leading to such high resistances due to poor contacts.

Yildiz, B.; Smith, J.; Sofu, T.; Nuclear Engineering Division

2008-06-25T23:59:59.000Z

158

Response to comments received from the State of Colorado and the public on the Environmental Assessment for resumption of thermal stabilization of plutonium oxide in Building 707  

SciTech Connect

The Department of Energy (DOE) prepared this document to respond to comments from the State of Colorado and the public on the draft Environmental Assessment (EA) for the Resumption of Thermal Stabilization of Plutonium Oxide in Building 707 at the Rocky Flats Plant (RFP) in Golden, Colorado. The draft EA was provided to the State of Colorado and the public on September 8, 1993, for a comment period of 60 days. The Department`s National Environmental Policy Act (NEPA) Implementing Procedures (10 Code of Federal Regulations [CFR] 1021.301) requires that prior to approval of the EA, DOE is to allow the host State and Indian Tribe a period of from 14 to 30 days to review and comment on the EA. The Department established a comment period of 60 days for this EA in response to requests by the public during the first public meeting on July 7, 1993, before preparation of the EA. Other issues raised at the July 7 meeting included the range of alternatives to be considered, the time period for preparation of the EA, and the amount of material to be thermally stabilized. These and other comments made by the public at that meeting were carefully considered in preparation of the EA. In addition to providing the preapproval draft EA to the State of Colorado, DOE distributed the EA to all persons and groups on the RFP public information mailing list and placed the EA and reference documents in the DOE Public Reading Rooms in the RFP area. A public meeting was held on October 6, 1993, to hear public comments on the draft EA. All comments on the draft EA, those received both at the October 6 public meeting and through correspondence, have been reproduced in their entirety in this Response to Comments document. Responses to the commenters` questions and concerns are provided, and changes made to the body of the EA are indicated in the responses. All comments received have been considered in the revision of the EA.

Not Available

1994-02-01T23:59:59.000Z

159

ENERGY HARVESTING, RIDE COMFORT, AND ROAD HANDLING OF REGENERATIVE VEHICLE SUSPENSIONS  

E-Print Network (OSTI)

, wheel and chasses masses to the vehicle performances and harvestable power are studied. Experiments power on a typical highway. Kawaoto et al [10] modeled a ball-screw type electromagnetic damper a regenerative suspension with a ball screw and three-phase motor of a real car on vibration test rig

Zuo, Lei

160

Corrosion Control Using Regenerative Biofilms on Aluminum 2024 and Brass in Different Media  

E-Print Network (OSTI)

Corrosion Control Using Regenerative Biofilms on Aluminum 2024 and Brass in Different Media F. Mansfeld,a, *,z H. Hsu,a D. O¨ rnek,b T. K. Wood,b and B. C. Syrettc a Corrosion and Environmental Effects Institute, Palo Alto, California 94303, USA The corrosion behavior of Al 2024-T3 and C26000 brass exposed

Wood, Thomas K.

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Corrosion control using regenerative biofilms (CCURB) on brass in different media  

E-Print Network (OSTI)

Corrosion control using regenerative biofilms (CCURB) on brass in different media D. OOrnek a , T of Chemical Engineering, University of Connecticut, Storrs, CT 06269-3222, USA b Corrosion and Environmental The corrosion behavior of cartridge brass (UNS C26000) exposed to artificial seawater (AS) and Luria Bertani (LB

Wood, Thomas K.

162

Pitting corrosion control using regenerative biolms on aluminium 2024 in articial seawater  

E-Print Network (OSTI)

Pitting corrosion control using regenerative bio®lms on aluminium 2024 in arti®cial seawater D, CT 06269-3222, USA b Corrosion and Environment Eects Laboratory (CEEL), Department of Materials polyglutamate or polyaspartate, an additional small increase in corrosion inhibition occurred. Corrosion control

Wood, Thomas K.

163

High-energy kHz Yb:KYW dual-crystal regenerative amplifier  

Science Journals Connector (OSTI)

A highly stable Yb:KYW based dual crystal regenerative amplifier is demonstrated, which generates at 1 kHz 6.5-mJ pulses before and up to 4.7-mJ sub-ps pulses after compression with...

Calendron, Anne-Laure; Çankaya, Hüseyin; Kärtner, Franz X

2014-01-01T23:59:59.000Z

164

of Stem Cell Biology and Regenerative Medicine Forum" DateNov 27th  

E-Print Network (OSTI)

-Together ------------------------------------------------------------------------------------------------------------------------------------- Hosted by Center for Stem Cell Biology and Regenerative Medicine ---Information--- Please register with their cell doses having failed to meet the minimum standard. Overall, these facts boosted us to look by utilizing mouse transplantation models a proof of concept that combined multiple units of allogeneic

Miyashita, Yasushi

165

Thermal treatment for VOC control  

SciTech Connect

Catalytic and thermal oxidation are well-established technologies for controlling volatile organic compounds (VOCs). Oxidation destroys pollutants, rather than capturing them. Oxidation units can destroy nearly 100% of VOC and toxic emissions targeted by the Clean Air Act Amendments of 1990--some systems attain destruction efficiencies over 99.99%. To assist in the design of these systems, an engineer will often look a/t the heat of combustion of the gas stream, along with the type of pollutant, to best determine the correct type of oxidation device to use. The paper discusses catalytic and thermal oxidation, energy recovery, and equipment for these processes.

Cloud, R.A. [Huntington Environmental Systems, Schaumburg, IL (United States)

1998-07-01T23:59:59.000Z

166

CX-001922: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

22: Categorical Exclusion Determination CX-001922: Categorical Exclusion Determination Biogas to Regenerative Thermal Oxidizer CX(s) Applied: B2.5, B5.1 Date: 03312010...

167

Regenerative Feedback Resonant Circuit to Detect Transient Changes in Electromagnetic Properties of Semi-Insulating Materials  

SciTech Connect

A prototype regenerative feedback resonant circuit has been developed for measuring the transient spectral response due to perturbations in properties of various electromagnetic materials. The circuit can accommodate a variety of cavity resonators, shown here in the 8 GHz range, with passive quality factors (Qstat) as high as 7,000 depending upon material loading. The positive feedback enhanced dynamic quality factors (Qdyn) of resonator/material combinations in the regenerative circuit are on the order of 107 - 108. The theory, design, and implementation of the circuit is discussed along with real-time monitored example measurements of effects due to photon-induced charge carriers in high-resistivity silicon wafers and magnetic-field induced perturbations of yttrium-iron garnet.

Jones, Anthony M.; Kelly, James F.; Severtsen, Ronald H.; McCloy, John S.

2013-08-08T23:59:59.000Z

168

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A process is described for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. 19 figs.

Frei, H.; Blatter, F.; Sun, H.

1999-06-22T23:59:59.000Z

169

Evaluation of thermal stresses in planar solid oxide fuel cells as a function of thermo-mechanical properties of component materials  

E-Print Network (OSTI)

, cathode and anode materials for SOFC and their effect on thermally induced stresses in SOFC stacks. Since a mismatch in Coefficient of Thermal Expansion (CTE) and Elastic moduli between the materials causes the development of detrimental thermal stresses... the development of the advanced flat plate (Planar) SOFC. Along with the SOFC design as a whole, advance materials were being developed for the various components. In the early 1970s, Nickel/YSZ, doped In 2 O 3 , and CoCr 2 O 3 were used as anode, cathode...

Manisha,

2008-10-10T23:59:59.000Z

170

Processing and characterization of multi-cellular monolithic bioceramics for bone regenerative scaffolds  

Science Journals Connector (OSTI)

Multicellular monolithic ceramic body is a ceramic material which has many gas or liquid passages partitioned by thin walls throughout the bulk material. There are many currently known advanced industrial applications of multicellular ceramics structures i.e. as supports for various catalysts electrode support structure for solid oxide fuel cells refractories electric/electronic materials aerospace vehicle re-entry heat shields and biomaterials for dental as well as orthopaedic implants by naming only a few. Multicellular ceramic bodies are usually made of ceramic phases such as mullite cordierite aluminum titanate or pure oxides such as silica zirconia and alumina. What make alumina ceramics is excellent for the above functions are the intrinsic properties of alumina which are hard wear resistant excellent dielectric properties resists strong acid and alkali attacks at elevated temperatures good thermal conductivities high strength and stiffness as well as biocompatible. In this work the processing technology leading to truly multicellular monolithic alumina ceramic bodies and their characterization are reported. Ceramic slip with 66 wt.% solid loading was found to be optimum as impregnant to the polyurethane foam template. Mullitic ceramic composite of alumina-sodium alumino disilicate-Leucite-like phases with bulk and true densities of 0.852 and 1.241 g cm?3 respectively pore linear density of ±35 cm?1 linear and bulk volume shrinkages of 7-16% and 32 vol.% were obtained. The compressive strength and elastic modulus of the bioceramics are ?0.5-1.0 and ?20 MPa respectively.

2014-01-01T23:59:59.000Z

171

Novel Bioreactors for Waste Gas Treatment  

Science Journals Connector (OSTI)

Modern thermal oxidizers can achieve a RE of 90–98% ... irrespective of the VOCs. In general, for thermal oxidizers to be economically acceptable, some form of ... recuperative or shell and tube type and the regenerative

Eldon R. Rene; María Montes; María C. Veiga…

2012-01-01T23:59:59.000Z

172

Thermal expansion of SOFC materials  

Science Journals Connector (OSTI)

A short overview is given for the thermal expansion of solid oxide fuel cell materials. The thermomechanical compatibility of state-of-the-art materials is compared with alternative, new materials. With these ...

F. Tietz

1999-01-01T23:59:59.000Z

173

High Temperature Oxidation Resistance and Surface Electrical...  

NLE Websites -- All DOE Office Websites (Extended Search)

plates with oxidation resistant coatings. Candidate coatings must exhibit chemical and thermal-mechanical stability and high electrical conductivity during long-term...

174

Thermally deposited Ag-doped CdS thin film transistors with high-k rare-earth oxide Nd2O3 as gate dielectric  

Science Journals Connector (OSTI)

The performance of thermally deposited CdS thin film transistors doped with Ag has been reported. Ag-doped CdS thin films have been prepared using chemical...2O3 has been used as gate insulator. The thin film tra...

P. Gogoi

2013-03-01T23:59:59.000Z

175

Integrated Modular Propulsion and Regenerative Electro-energy Storage System (IMPRESS) for small satellites  

SciTech Connect

The IMPRESS is a significant advancement in space system technology as it is able to operate alternately as a fuel cell to produce electrical power from stored hydrogen and oxygen and as a water electrolyzer using electrical power to produce hydrogen and oxygen from stored water. The electrolysis of a controllable fraction of stored water can provide high Isp rocket propellants on demand. The heart of the IMPRESS is the Unitized Regenerative Fuel Cell (URFC), which produces power and electrolytically regenerates its reactants using a single stack of reversible cells. This integrated approach has several significant advantages over separate (battery) power and propulsion systems.

Mitlitsky, F. [Lawrence Livermore National Lab., CA (United States); de Groot, W. [Nyma, Inc., Brook Park, OH (United States); Butler, L.; McElroy, J. [United Technologies Corp., Windsor Locks, CT (United States). Hamilton Standard Div.

1996-09-01T23:59:59.000Z

176

Thermal Recovery Methods  

SciTech Connect

Thermal Recovery Methods describes the basic concepts of thermal recovery and explains the injection patterns used to exploit reservoir conditions. Basic reservoir engineering is reviewed with an emphasis on changes in flow characteristics caused by temperature. The authors discuss an energy balance for steam and combustion drive, and they explain in situ reactions. Heat loss, combustion drive, and steam displacement also are examined in detail, as well as cyclic steam injection, downhole ignition, well heating, and low-temperature oxidation. Contents: Thermal processes; Formation and reservoir evaluations; Well patterns and spacing; Flow and process equations; Laboratory simulation of thermal recovery; Heat loss and transmission; Displacement and production; Equipment; Basic data for field selection; Laboratory evaluation of combustion characteristics; Thermal properties of reservoirs and fluids.

White, P.D.; Moss, J.T.

1983-01-01T23:59:59.000Z

177

ESS 2012 Peer Review - Novel Regenerative Fuel Cells based on Anion Exchange Membranes - Katherine Ayers, Proton Onsite  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

l l R ti F l C ll b d A i E h M b f Novel Regenerative Fuel Cells based on Anion Exchange Membranes for Novel Regenerative Fuel Cells based on Anion Exchange Membranes for g g Affordable Renewable Energy Storage Affordable Renewable Energy Storage Affordable Renewable Energy Storage PI: Dr Katherine Ayers Proton Energy Systems kayers@protononsite com PI: Dr. Katherine Ayers, Proton Energy Systems, kayers@protononsite.com y , gy y , y @p A h Key Challenges and Progress Approach Key Challenges and Progress Approach Key Challenges and Progress pp N PGM t l t ( l t l ) Fuel Cell Durability: Non-PGM catalysts (electrolyzer) * Leverage Proton experience in large scale Fuel Cell Durability: o G cata ysts (e ect o y e ) * Leverage Proton experience in large scale Anode flooding and cathode * Translation from RDE to cell results electrolysis and regenerative fuel

178

Study on The Effect of Regenerative System on Power Type Relative Internal Efficiency of Nuclear Steam Turbine  

Science Journals Connector (OSTI)

Nuclear steam turbine use wet steam as working medium, which is unable to determine the enthalpy drop type relative internal efficiency through exhaust enthalpy of steam, but the power type relative internal efficiency avoids this question. This paper introduced the calculate method of power type relative internal efficience, and then took a 900MW nuclear steam turbine for example, calculated the power type relative internal efficiency when the factors of regenerative system are changed. The result shows that when the factors of regenerative system are changed in a large range, the power type relative internal efficiency is nearly changeless, so the effect of regenerative system on relative internal efficiency can be neglected. At last, the independence between relative internal efficiency and ideal cycle heat efficiency is calculated and analyzed.

Yong Li; Chao Wang

2012-01-01T23:59:59.000Z

179

E-Print Network 3.0 - activity oxidative stress Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

due to growth of the oxide film or thermal... within the oxide, not through to the bare metal. ... Source: Ecole Polytechnique, Centre de mathmatiques Collection: Mathematics...

180

Study of Power Grid Connection with an Unstable Source from Elevator Energy Regenerative Unit (EERU)  

Science Journals Connector (OSTI)

Abstract This paper presents a study of power grid connection with an unstable source from elevator energy regenerative unit (EERU). The investigated system used a Permanent Magnet Synchronous Motor (PMSM). The EERU is installed for this system to generate electricity according to the generative mode of the elevator which delivers power to the grid as an unstable power source. To meet standard specifications in term of power quality and safety for grid connection, the phase angle and the amplitude as well as the frequency of the grid voltage are considered for grid connection. Phase lock loop (PLL) algorithm is therefore very important and selected for grid synchronization. The study is done by simulation using Matlab/Simulink program. The simulation used phase lock loop to synchronize between two systems. The results of this simulation will lead to a proper design of the grid connection with EERU as an unstable power source.

A. Noppakant; B. Plangklang; Y. Paraken

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Performance analysis of regenerative organic Rankine cycle (RORC) using the pure working fluid and the zeotropic mixture over the whole operating range of a diesel engine  

Science Journals Connector (OSTI)

Abstract A regenerative organic Rankine cycle (RORC) system is designed to recover the exhaust heat of a diesel engine, and the influence of the intermediate pressure (the pressures at which the steam is extracted from the expander) on performance parameters such as net power output, thermal efficiency and mass flow rate of the working fluid are analyzed. The organic working fluids under investigation are \\{R245fa\\} and the zeotropic mixture isopentane/R245fa (in a 0.7/0.3 mol fraction). Based on initial calculations of RORC system performance, the intermediate pressure is set to 1.15 MPa for the RORC system when using isopentane/R245fa (in a 0.7/0.3 mol fraction) as the working fluid, and 1.2 MPa when using \\{R245fa\\} as the working fluid. A performance analysis of the RORC system using the two different working fluids is then conducted over the whole operating range of a diesel engine. The results show that the zeotropic mixture isopentane/R245fa (in a 0.7/0.3 mol fraction) performs better. Finally, a combined diesel engine and RORC system is defined to evaluate the performance improvement of such a combined system over the whole operating range. Results show that, for the combined system, a 10.54% improvement in power output and a 9.55% improvement in fuel economy can be achieved at the engine’s rated condition.

Jian Zhang; Hongguang Zhang; Kai Yang; Fubin Yang; Zhen Wang; Guangyao Zhao; Hao Liu; Enhua Wang; Baofeng Yao

2014-01-01T23:59:59.000Z

182

Development of an Alternate Synthesis for a Key JAK2 Inhibitor Intermediate via Sequential C–H Bond Functionalization  

Science Journals Connector (OSTI)

(6, 7) Silicon dioxide which results from triethylsilane incineration leads to particulate agglomeration on the heat transfer media of regenerative thermal oxidizers. ... In Proceedings of the International Conference on Thermal Treatment Technologies and Hazardous Waste Combustors (IT3/HWC); University of Maryland, Air and Waste Management Association: College Park, 2004. ... Plugging/fouling of thermal media in regenerative thermal oxidizers due to particulate SiO2 formation can lead to additional manufacturing costs associated with incineration shutdown and thermal media replacement. ...

Alison N. Campbell; Kevin P. Cole; Joseph R. Martinelli; Scott A. May; David Mitchell; Patrick M. Pollock; Kevin A. Sullivan

2013-01-12T23:59:59.000Z

183

Thermal barrier coatings  

DOE Patents (OSTI)

This disclosure addresses the issue of providing a metallic-ceramic overlay coating that potentially serves as an interface or bond coat layer to provide enhanced oxidation resistance to the underlying superalloy substrate via the formation of a diffusion barrier regime within the supporting base material. Furthermore, the metallic-ceramic coating is expected to limit the growth of a continuous thermally grown oxide (TGO) layer that has been primarily considered to be the principal cause for failure of existing TBC systems. Compositional compatibility of the metallic-ceramic with traditional yttria-stabilized zirconia (YSZ) top coats is provided to further limit debond or spallation of the coating during operational use. A metallic-ceramic architecture is disclosed wherein enhanced oxidation resistance is imparted to the surface of nickel-based superalloy or single crystal metal substrate, with simultaneous integration of the yttria stabilized zirconia (YSZ) within the metallic-ceramic overlayer.

Alvin, Mary Anne (Pittsburg, PA)

2010-06-22T23:59:59.000Z

184

Post-combustion Air Emission Control  

Science Journals Connector (OSTI)

Typical destruction and removal efficiency of a thermal oxidizer is above 99 % at typical capacities...3.../s. There are two options for heat recovery, a regenerative and a recuperative recovery system with the thermal

Zhongchao Tan

2014-01-01T23:59:59.000Z

185

Structural and electrochemical characterization of two proton conducting oxide thin films for a microfabricated solid oxide fuel cell  

E-Print Network (OSTI)

The use of proton conducting oxide materials as an electrolyte offers the potential to reduce the operating temperature of a solid oxide fuel cell (SOFC), leading to improved thermal management and material compatibility. ...

Capozzoli, Peter M

2006-01-01T23:59:59.000Z

186

An electromagnetic and thermodynamic lumped parameter model of an explosively driven regenerative magnetohydrodynamic generator  

SciTech Connect

The objective of this research is to develop a simple, yet accurate, lumped parameter mathematical model for an explosively driven magnetohydrodynamic generator that can predict the pulse power variables of voltage and current from startup through regenerative operation. The inputs to the model will be the plasma properties entering the generator as predicted by the explosive shock model of Reference [1]. The strategy used was to simplify electromagnetic and thermodynamic three dimensional effects into a zero dimensional model. The model will provide a convenient tool for researchers to optimize designs to be used in pulse power applications. The model is validated using experimental data of Reference [1]. An overview of the operation of the explosively driven generator is first presented. Then a simplified electrical circuit model that describes basic performance of the device is developed. Then a lumped parameter model that incorporates the coupled electromagnetic and thermodynamic effects that govern generator performance is described and developed. The model is based on fundamental physical principles and parameters that were either obtained directly from design data or estimated from experimental data. The model was used to obtain parameter sensitivities and predict beyond the limits observed in the experiments to the levels desired by the potential Department of Defense sponsors. The model identifies process limitations that provide direction for future research.

Morrison, J.L.

1992-12-01T23:59:59.000Z

187

Regeneratively cooled coal combustor/gasifier with integral dry ash removal  

DOE Patents (OSTI)

A coal combustor/gasifier is disclosed which produces a low or medium combustion gas for further combustion in modified oil or gas fired furnaces or boilers. Two concentric shells define a combustion volume within the inner shell and a plenum between them through which combustion air flows to provide regenerative cooling of the inner shell for dry ash operation. A fuel flow and a combustion air flow having opposed swirls are mixed and burned in a mixing-combustion portion of the combustion volume and the ash laden combustion products flow with a residual swirl into an ash separation region. The ash is cooled below the fusion temperature and is moved to the wall by centrifugal force where it is entrained in the cool wall boundary layer. The boundary layer is stabilized against ash re-entrainment as it is moved to an ash removal annulus by a flow of air from the plenum through slots in the inner shell, and by suction on an ash removal skimmer slot.

Beaufrere, Albert H. (Huntington, NY)

1983-10-04T23:59:59.000Z

188

Radio frequency regenerative oscillations in monolithic high-Q/V heterostructured photonic crystal cavities  

E-Print Network (OSTI)

of the radio frequency tones by laser-cavity detuning and laser power levels, confirmed by the CMT simulations crystal cavity is removed by buffered oxide wet etching. Inverse tapered couplers with an oxide over-cladding the CW coherent transverse-electric light from a tunable laser onto chip through polarization control

Hone, James

189

Regenerative air energy storage for remote wind–diesel micro-grid communities  

Science Journals Connector (OSTI)

Abstract Remote communities beyond the reach of conventional electricity grids primarily rely on diesel generators (DG) to supply electricity. The systems in these communities are costly to operate because of the high price of transporting diesel to remote areas, and the low overall efficiencies caused by part-load operation of the DG. There is increasing interest to use wind energy converters (WEC) to supplement DG, thereby lowering the fuel consumption and operating costs. In order to use WEC to reduce the economic and environmental burden that DG have on remote communities, an energy storage system can be incorporated to buffer both generation and demand. This can avoid curtailment of the WEC, operate the DG at optimal efficiency, and reduce the necessary maximum installed generator capacities. Regenerative air energy storage (RAES) is a form of compressed air storage that is suitable for deployment in remote communities due to its ability to utilize waste heat from DG to boost the roundtrip efficiency of energy storage. This article presents a numerical model for a RAES system operating in a wind-diesel micro-grid. Simulations are run for varying WEC penetration levels and RAES energy capacities. The results show that in systems with WEC penetration less than 75%, increasing WEC capacity is more economic than adding a RAES system. Above penetration rates of 75%, the use of RAES achieves increased diesel savings with only slightly longer payback than simple wind-diesel systems. In the remote Canadian community case study, the optimal RAES system is 0.5 MW and 1 MW h with a WEC penetration rate of approximately 75%. A larger RAES results in further fuel savings, and thus environmental benefit, with only marginal increase in simple payback period.

Sebastian C. Manchester; Lukas G. Swan; Dominic Groulx

2014-01-01T23:59:59.000Z

190

Thermal and Electrical Transport in Oxide Heterostructures  

E-Print Network (OSTI)

such as Seebeck e?ect, Peltier e?ect and Thomson e?ect. Ameasure temperature over a wide temperature ranges. Peltiereffect Peltier e?ect was discovered by Jean-Charles Peltier

Ravichandran, Jayakanth

2011-01-01T23:59:59.000Z

191

Carbon Capture by a Continuous, Regenerative Ammonia-Based Scrubbing Process  

SciTech Connect

Overview: To develop a knowledge/data base to determine whether an ammonia-based scrubbing process is a viable regenerable-capture technique that can simultaneously remove carbon dioxide, sulfur dioxide, nitric oxides, and trace pollutants from flue gas.

Resnik, K.P.; Yeh, J.T.; Pennline, H.W.

2006-10-01T23:59:59.000Z

192

Metal Oxides  

Science Journals Connector (OSTI)

Metal oxides are the class of materials having the widest application in gas sensors. This chapter presents information related to the application of various metal oxides in gas sensors designed on different p...

Ghenadii Korotcenkov

2013-01-01T23:59:59.000Z

193

Hydrocarbons Heterogeneous Pyrolysis: Experiments and Modeling for Scramjet Thermal Management  

E-Print Network (OSTI)

The last years saw a renewal of interest for hypersonic research in general and regenerative cooling specifically, with a large increase of the number of dedicated facilities and technical studies. In order to quantify the heat transfer in the cooled structures and the composition of the cracked fuel entering the combustor, an accurate model of the thermal decomposition of the fuel is required. This model should be able to predict the fuel chemical composition and physical properties for a broad range of pressures, temperatures and cooling geometries. For this purpose, an experimental and modeling study of the thermal decomposition of generic molecules (long-chain or polycyclic alkanes) that could be good surrogates of real fuels, has been started at the DCPR laboratory located in Nancy (France). This successful effort leads to several versions of a complete kinetic model. These models do not assume any effect from the material that constitutes the cooling channel. A specific experimental study was performed ...

Bouchez, Marc; Visez, Nicolas; Herbinet, Olivier; Fournet, René; Marquaire, Paul-Marie

2009-01-01T23:59:59.000Z

194

Thermal treatment  

Science Journals Connector (OSTI)

Thermal treatment can be regarded as either a pre-treatment of waste prior to final disposal, or as a means of valorising waste by recovering energy. It includes both the burning of mixed MSW in municipal inciner...

Dr. P. White; Dr. M. Franke; P. Hindle

1995-01-01T23:59:59.000Z

195

Thermal Processes  

Energy.gov (U.S. Department of Energy (DOE))

Some thermal processes use the energy in various resources, such as natural gas, coal, or biomass, to release hydrogen, which is part of their molecular structure. In other processes, heat, in...

196

Applications of direct chemical oxidation to demilitarization  

SciTech Connect

Research is reported concerning an aqueous process for oxidative destruction of solid- and liquid organic wastes, including ongoing work relevant to demilitarization This process uses acidified ammonium- or sodium peroxydisulfate and operates at ambient pressure and at temperatures of 80- 100 C The oxidant may be regenerated by electrolysis of the sulfate by- product at Pt anodes at roughly 80% coulombic efficiency, even in the presence of inorganic contaminants (e g , nitrate, phosphate or chloride) found in the original waste and entrained in the recycle stream Integral rate constants have been determined for the oxidation of diverse organic compounds at low concentrations (50 ppm, C), with rate constants (based on equivalents) of 0 004-O 02 miri Higher concentrations generally react at a 2-4X higher rate. The process has been carried through full- scale laboratory tests and initial pilot plant tests on chlorinated solvents, using a hydrolysis pretreatment Integral rate data indicate throughput rates of about 200 kg- C/m3-day The process may benefit the demilitarization efforts in various specialized applications destruction of solvents; destruction of trace propellants and explosives in shell casings remaining after bulk removal, destruction of red and pink waters, in situ remediation of soils at open pit burning/detonation sites; and as a regenerative filter for offgas carrying toxic or explosive substances.

Cooper, J.F., LLNL

1998-06-01T23:59:59.000Z

197

News & Views ISSN 1746-075110.2217/RME.13.31 2013 Future Medicine Ltd Regen. Med. (2013) 8(4), 409412 409  

E-Print Network (OSTI)

News & Views ISSN 1746-075110.2217/RME.13.31 © 2013 Future Medicine Ltd Regen. Med. (2013) 8(4), 409­412 409 News & ViewsNews & ViewsNews & Views What first brought you from the engineering

Zandstra, Peter W.

198

Hydraulic Drivetrain and Regenerative Braking Team 13: Andrew Brown, Karan Desai, Andrew McGrath, Hurst Nuckols, Grant Wilson Adviser: Dr. Andrew Jackson  

E-Print Network (OSTI)

. The main components of the model include an electric motor, hydraulic pump, hydraulic motor and two 1 flow during regenerative braking Electric Motor: Provides rotational energy to the hydraulic drivetrain (% kinetic energy recovered) 24.73% Drivetrain Efficiency 67.02% Overall Efficiency 53.47% Current Electric

Carpick, Robert W.

199

Lifetime Assessment for Thermal Barrier Coatings: Tests for Measuring Mixed Mode Delamination Toughness  

E-Print Network (OSTI)

the thermally grown oxide (TGO), and a porous ceramic topcoat which serves as the thermal insulation. DetailsLifetime Assessment for Thermal Barrier Coatings: Tests for Measuring Mixed Mode Delamination Mechanisms leading to degradation of the adherence of thermal barrier coatings (TBC) used in aircraft

Hutchinson, John W.

200

Oxygen enriched combustion system performance study. Phase 2: 100 percent oxygen enriched combustion in regenerative glass melters, Final report  

SciTech Connect

The field test project described in this report was conducted to evaluate the energy and environmental performance of 100% oxygen enriched combustion (100% OEC) in regenerative glass melters. Additional objectives were to determine other impacts of 100% OEC on melter operation and glass quality, and to verify on a commercial scale that an on-site Pressure Swing Adsorption oxygen plant can reliably supply oxygen for glass melting with low electrical power consumption. The tests constituted Phase 2 of a cooperative project between the United States Department of Energy, and Praxair, Inc. Phase 1 of the project involved market and technical feasibility assessments of oxygen enriched combustion for a range of high temperature industrial heating applications. An assessment of oxygen supply options for these applications was also performed during Phase 1, which included performance evaluation of a pilot scale 1 ton per day PSA oxygen plant. Two regenerative container glass melters were converted to 100% OEC operation and served as host sites for Phase 2. A 75 ton per day end-fired melter at Carr-Lowrey Glass Company in Baltimore, Maryland, was temporarily converted to 100% OEC in mid- 1990. A 350 tpd cross-fired melter at Gallo Glass Company in Modesto, California was rebuilt for permanent commercial operation with 100% OEC in mid-1991. Initially, both of these melters were supplied with oxygen from liquid storage. Subsequently, in late 1992, a Pressure Swing Adsorption oxygen plant was installed at Gallo to supply oxygen for 100% OEC glass melting. The particular PSA plant design used at Gallo achieves maximum efficiency by cycling the adsorbent beds between pressurized and evacuated states, and is therefore referred to as a Vacuum/Pressure Swing Adsorption (VPSA) plant.

Tuson, G.B.; Kobayashi, H.; Campbell, M.J.

1994-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

AQUIFER THERMAL ENERGY STORAGE  

E-Print Network (OSTI)

using aquifers for thermal energy storage. Problems outlinedmatical Modeling of Thermal Energy Storage in Aquifers,"ings of Aquifer Thermal Energy Storage Workshop, Lawrence

Tsang, C.-F.

2011-01-01T23:59:59.000Z

202

Project Profile: Thermochemical Heat Storage for CSP Based on Multivalent Metal Oxides  

Energy.gov (U.S. Department of Energy (DOE))

General Atomics (GA), under the Thermal Storage FOA, is developing a high-density thermochemical heat storage system based on solid metal oxides.

203

Effect of Substrate Thickness on Oxide Scale Spallation for Solid Oxide Fuel Cells  

SciTech Connect

In this paper, the effect of the ferritic substrate's thickness on the delamination/spallation of the oxide scale was investigated experimentally and numerically. At the high-temperature oxidation environment of solid oxide fuel cells (SOFCs), a combination of growth stress with thermal stresses may lead to scale delamination/buckling and eventual spallation during SOFC stack cooling, even leading to serious degradation of cell performance. The growth stress is induced by the growth of the oxide scale on the scale/substrate interface, and thermal stress is induced by a mismatch of the coefficient of thermal expansion between the oxide scale and the substrate. The numerical results show that the interfacial shear stresses, which are the driving force of scale delamination between the oxide scale and the ferritic substrate, increase with the growth of the oxide scale and also with the thickness of the ferritic substrate; i.e., the thick ferritic substrate can easily lead to scale delamination and spallation. Experimental observation confirmed the predicted results of the delamination and spallation of the oxide scale on the ferritic substrate.

Liu, Wenning N.; Sun, Xin; Stephens, Elizabeth V.; Khaleel, Mohammad A.

2011-07-01T23:59:59.000Z

204

Growth of SiC thin films on graphite for oxidation-protective coating J.-H. Boo,a)  

E-Print Network (OSTI)

, it is necessary to improve its resistance to oxidation. SiC is used as a semiconductor material for high of the SiC layers compared to those grown by thermal MOCVD. The mechanical and oxidation-resistant-2101 00 18204-1 I. INTRODUCTION Graphite, with its advantages of high thermal conductiv- ity, low-thermal

Boo, Jin-Hyo

205

Micromechanics applied to the thermal shock behavior of refractory ceramics  

E-Print Network (OSTI)

Micromechanics applied to the thermal shock behavior of refractory ceramics N. Schmitt a,*, A. Burr-phase ceramics subjected to thermal shock. A macroscopic fracture criterion is proposed that accounts for local, F-59 381 Dunkerque, France Received 3 May 2002 Abstract Oxides­carbon refractories are ceramics

206

Optical properties of Zircaloy and Zircaloy oxide by ellipsometry  

Science Journals Connector (OSTI)

The optical constants of Zircaloy 2 and 4, which are alloys of zirconium and their thermal oxides, are determined by ellipsometry over a 0.3131–3.39-?m wavelength range. Both the...

Bashara, N M; Peng, Y -K

1980-01-01T23:59:59.000Z

207

Predictive kinetic modeling of low-temperature hydrocarbon oxidation  

E-Print Network (OSTI)

Low temperature oxidation in the gas and condensed phases has been the subject of experimental investigations for many decades owing to applications in many areas of practical significance like thermal stability, combustion, ...

Jalan, Amrit

2014-01-01T23:59:59.000Z

208

Design Principles of a flywheel Regenerative Braking System (f-RBS) for Formula SAE type racecar and system testing on a Virtual Test Rig modeled on MSC ADAMS  

E-Print Network (OSTI)

momentum in the industry [4]. These vehicles (BEVs and HEVS) use electric motor/generator pairs to propel themselves and to recapture braking energy (electric RBS) and the power source is the battery. The regenerative braking system uses a generator..., aerodynamic and road losses. 4. Improvised Transmission design to reduce losses. 5. Hybrid and Alternative Energy Propulsion systems e.g. the Hybrid Electric Vehicle (HEV), the Fuel Cell Vehicle (FCV). 6. Recycling Braking energy – Storage and reuse...

Pochiraju, Anirudh

2012-08-31T23:59:59.000Z

209

Theoretical model for predicting thermodynamic behavior of thermal-lag Stirling engine  

Science Journals Connector (OSTI)

A theoretical model for predicting thermodynamic behavior of thermal-lag Stirling engine is presented in this study. Without a displacer and its link, the thermal-lag engine contains only a moving part (piston) and a static part (regenerative heater) in engine's cylinder and hence, is regarded as a unique type of Stirling engines that featuring rather simple mechanical structure. In this study, a numerical simulation of thermodynamic behavior of the thermal-lag Stirling engine is performed based on the theoretical model developed. Transient variations of temperatures, pressures, pressure difference, and working fluid masses in the individual working spaces of the engine are predicted. Dependence of indicated power and thermal efficiency on engine speed has been investigated. Then, optimal engine speeds at which the engine may reach its maximum power output and/or maximum thermal efficiency is determined. Furthermore, effects of geometrical and operating parameters, such as heating and cooling temperatures, volumes of the chambers, thermal resistances, stroke of piston, and bore size on indicated power output and thermal efficiency are also evaluated.

Chin-Hsiang Cheng; Hang-Suin Yang

2013-01-01T23:59:59.000Z

210

Theoretical research on working fluid selection for a high-temperature regenerative transcritical dual-loop engine organic Rankine cycle  

Science Journals Connector (OSTI)

Abstract In this paper, a regenerative transcritical dual-loop organic Rankine cycle is proposed to recover the waste heat of the exhaust, engine coolant and all the residual heat of the HT loop. Double regenerators are adopted in this system. Transcritical cycles are used in both loops. Hexamethyldisiloxane (MM), octamethyl cyclotetrasiloxane (D4), octamethyltrisiloxane (MDM), cyclohexane, toluene and n-decane are chosen as the candidate working fluids of the HT loop and \\{R143a\\} is chosen as the working fluid of the LT loop. Influences of inlet temperature of turbine THT (T3) on mass flow rates (mf,HT and mf,LT), net output power (Wnet), energy conversion efficiency (?ec), volumetric expansion ratio (VER), ratio of power consumed to power output (COR) and component irreversibility are analyzed and performance comparison of these working fluids is also evaluated. Results show that toluene possesses the maximum Wnet (42.46 kW), highest ?e (51.92%) and ?ec (12.77%). The increase of T3 worsens system performance, decreasing Wnet, ?e and ?ec. Condenser CLT and turbine TLT possess the least system irreversibility. In addition, turbines and exhaust evaporators are optimized components.

Hua Tian; Lina Liu; Gequn Shu; Haiqiao Wei; Xingyu Liang

2014-01-01T23:59:59.000Z

211

Oxidation of Propane by Doped Nickel Oxides  

Science Journals Connector (OSTI)

... present study, however, indicate that in the absence of excess oxygen, direct oxidation of propane by the oxide lattice can occur.

D. W. McKEE

1964-04-11T23:59:59.000Z

212

Solar Thermal Reactor Materials Characterization  

SciTech Connect

Current research into hydrogen production through high temperature metal oxide water splitting cycles has created a need for robust high temperature materials. Such cycles are further enhanced by the use of concentrated solar energy as a power source. However, samples subjected to concentrated solar radiation exhibited lifetimes much shorter than expected. Characterization of the power and flux distributions representative of the High Flux Solar Furnace(HFSF) at the National Renewable Energy Laboratory(NREL) were compared to ray trace modeling of the facility. In addition, samples of candidate reactor materials were thermally cycled at the HFSF and tensile failure testing was performed to quantify material degradation. Thermal cycling tests have been completed on super alloy Haynes 214 samples and results indicate that maximum temperature plays a significant role in reduction of strength. The number of cycles was too small to establish long term failure trends for this material due to the high ductility of the material.

Lichty, P. R.; Scott, A. M.; Perkins, C. M.; Bingham, C.; Weimer, A. W.

2008-03-01T23:59:59.000Z

213

Experimental Study of Electron Transport through Nanometer-Scale Metal-Oxide Junctions  

E-Print Network (OSTI)

-annealing. The resistive bistability effect has been observed for all these materials, with particularly high switching, crested barrier, rapid thermal annealing, endurance, resistive bistability, reproducibility. #12;v List properties of Nb/Al/Nb junctions fabricated using thermal oxidation or rf-plasma oxidation at various

214

Magnetosome-like ferrimagnetic iron oxide nanocubes for highly sensitive MRI of single cells and transplanted pancreatic islets  

Science Journals Connector (OSTI)

...Contrast Agent. Ferrimagnetic iron oxide nanocubes were synthesized via thermal decomposition of iron (III) acetylacetonate in a mixture composed of oleic...PEG-phospholipid-encapsulated ferrimagnetic iron oxide nanocubes, designated as...

Nohyun Lee; Hyoungsu Kim; Seung Hong Choi; Mihyun Park; Dokyoon Kim; Hyo-Cheol Kim; Yoonseok Choi; Shunmei Lin; Byung Hyo Kim; Hye Seung Jung; Hyeonjin Kim; Kyong Soo Park; Woo Kyung Moon; Taeghwan Hyeon

2011-01-01T23:59:59.000Z

215

Seasonal thermal energy storage  

SciTech Connect

This report describes the following: (1) the US Department of Energy Seasonal Thermal Energy Storage Program, (2) aquifer thermal energy storage technology, (3) alternative STES technology, (4) foreign studies in seasonal thermal energy storage, and (5) economic assessment.

Allen, R.D.; Kannberg, L.D.; Raymond, J.R.

1984-05-01T23:59:59.000Z

216

Thermal unobtainiums? The perfect thermal conductor and  

E-Print Network (OSTI)

contribute to thermal resistance · Isotopically pure diamond has highest thermal conductivity of any material materials: disordered layered crystals Conclude with some thoughts on promising, high-risk, research even in a computer model. #12;Thermal resistance is created by Umklapp scattering (U

Braun, Paul

217

Excitation mechanism and thermal emission quenching of Tb ions in silicon rich silicon oxide thin films grown by plasma-enhanced chemical vapour deposition—Do we need silicon nanoclusters?  

SciTech Connect

In this work, we will discuss the excitation and emission properties of Tb ions in a Silicon Rich Silicon Oxide (SRSO) matrix obtained at different technological conditions. By means of electron cyclotron resonance plasma-enhanced chemical vapour deposition, undoped and doped SRSO films have been obtained with different Si content (33, 35, 39, 50 at. %) and were annealed at different temperatures (600, 900, 1100?°C). The samples were characterized optically and structurally using photoluminescence (PL), PL excitation, time resolved PL, absorption, cathodoluminescence, temperature dependent PL, Rutherford backscattering spectrometry, Fourier transform infrared spectroscopy and positron annihilation lifetime spectroscopy. Based on the obtained results, we discuss how the matrix modifications influence excitation and emission properties of Tb ions.

Podhorodecki, A., E-mail: artur.p.podhorodecki@pwr.wroc.pl; Golacki, L. W.; Zatryb, G.; Misiewicz, J. [Institute of Physics, Wroclaw University of Technology, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw (Poland); Wang, J.; Jadwisienczak, W. [School of EECS, Ohio University, Stocker Center 363, Athens, Ohio 45701 (United States); Fedus, K. [Institute of Physics, Nicholas Copernicus University, Grudziadzka 5/7, 87-100 Torun (Poland); Wojcik, J.; Wilson, P. R. J.; Mascher, P. [Department of Engineering Physics and Centre for Emerging Device Technologies, McMaster University, 1280 Main St. W, Hamilton, Ontario L8S4L7 (Canada)

2014-04-14T23:59:59.000Z

218

Thermal Control & System Integration  

Energy.gov (U.S. Department of Energy (DOE))

The thermal control and system integration activity focuses on issues such as the integration of motor and power control technologies and the development of advanced thermal control technologies....

219

Smoldering combustion hazards of thermal insulation materials  

SciTech Connect

Work on the smolder ignitability in cellulosic insulation and on thermal analytical characterization of the oxidation of this material is presented. Thermal analysis (TGA and DSC) shows that both retarded and unretarded cellulosic insulation oxidizes in two overall stages, both of which are exothermic. The second stage (oxidation of the char left as a residue of the first stage) is much more energetic on a unit mass basis than the first. However, kinetics and a sufficient exothermicity make the first stage responsible for ignition in most realistic circumstances. Existing smolder retardants such as boric acid have their major effect on the kinetics of the second oxidation stage and thus produce only a rather small (20/sup 0/C) increase in smolder ignition temperature. Several simplified analogs of attic insulations have been tested to determine the variability of minimum smolder ignition temperature. These employed planar or tubular constant temperature heat sources in a thermal environment quite similar to a realistic attic application. Go/no-go tests provided the borderline (minimum) ignition temperature for each configuration. The wide range (150/sup 0/C) of minimum ignition temperatures confirmed the predominant dependence of smolder ignition on heat flow geometry. Other factors (bulk density, retardants) produced much less effect on ignitability.

Ohlemiller, T.J.; Rogers, F.E.

1980-07-01T23:59:59.000Z

220

Inhibition of Oxidation in Nuclear Graphite  

SciTech Connect

Graphite is a fundamental material of high temperature gas cooled nuclear reactors, providing both structure and neutron moderation. Its high thermal conductivity, chemical inertness, thermal heat capacity, and high thermal structural stability under normal and off normal conditions contribute to the inherent safety of these reactor designs. One of the primary safety issues for a high temperature graphite reactor core is the possibility of rapid oxidation of the carbon structure during an off normal design basis event where an oxidizing atmosphere (air ingress) can be introduced to the hot core. Although the current Generation IV high temperature reactor designs attempt to mitigate any damage caused by a postualed air ingress event, the use of graphite components that inhibit oxidation is a logical step to increase the safety of these reactors. Recent experimental studies of graphite containing between 5.5 and 7 wt% boron carbide (B4C) indicate that oxidation is dramatically reduced even at prolonged exposures at temperatures up to 900°C. The proposed addition of B4C to graphite components in the nuclear core would necessarily be enriched in B-11 isotope in order to minimize B-10 neutron absorption and graphite swelling. The enriched boron can be added to the graphite during billet fabrication. Experimental oxidation rate results and potential applications for borated graphite in nuclear reactor components will be discussed.

Phil Winston; James W. Sterbentz; William E. Windes

2013-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Thermal Management of Solar Cells  

E-Print Network (OSTI)

a better thermal conductance and when ceramic particles areor ceramic fillers that enhances thermal conductivity. Solid

Saadah, Mohammed Ahmed

2013-01-01T23:59:59.000Z

222

The Vapor Deposition and Oxidation of Platinum-and Yttria-Stabilized Zirconia Multilayers  

E-Print Network (OSTI)

rates by disrupting thermal transport processes. Novel metal­ceramic multilayer's combining thin metal layers with low thermal conductivity oxide ceramics offer a potential approach for impeding both­200-mm-thick low thermal conductivity ceramic outer layer (the top coat), a 10­20-mm-thick, aluminum

Wadley, Haydn

223

FARADAYIC ElectroPhoretic Deposition of YSZ for Use in Thermal Barrier Coatings - Faraday Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

FARADAYIC ElectroPhoretic Deposition FARADAYIC ElectroPhoretic Deposition of YSZ for Use in Thermal Barrier Coatings-Faraday Technology Background Thermal barrier coatings (TBCs) are employed to protect gas turbine engine components. These coating systems provide thermal, oxidation, and mechanical protection; reduce thermal gradients; and lower the metal substrate surface temperature, extending the life of the engine components. Faraday Technology, Inc. (Faraday) is developing a new manufacturing process, the

224

Synthesis and characterizations of graphene oxide and reduced graphene oxide nanosheets  

SciTech Connect

Interest in graphene on its excellent mechanical, electrical, thermal and optical properties, it’s very high specific surface area, and our ability to influence these properties through chemical functionalization. Chemical reduction of graphene oxide is one of the main routes of preparation for large quantities of graphenes. Hydrazine hydrate used as reducing agent to prepare for the reduced graphene oxide (RGO). There are a number of methods for generating graphene and chemically modified graphene from natural graphite flakes, graphite derivative (such as graphite oxide) and graphite interaction compounds (i.e. expandable graphite). Here we review the use of colloidal suspensions of reduced graphene oxide (RGO) with large scalable, and is adaptable to a wide variety of applications. The graphene oxide (GO) and the reduced material (RGO) were characterized by XRD, UV-Vis spectroscopy, Thermo-gravimetric analysis (TGA), Raman spectroscopy and Field emission Scanning electron microscopy (FESEM) etc.

Venkanna, M., E-mail: venkanna.pcu@gmail.com; Chakraborty, Amit K., E-mail: venkanna.pcu@gmail.com [Carbon Nanotechnology Laboratory, Department of Physics, National Institute of Technology Durgapur, M.G. Avenue, Durgapur - 713209 (India)

2014-04-24T23:59:59.000Z

225

INFLUENCE OF OXIDE GROWTH AND METAL CREEP ON STRAIN DEVELOPMENT IN THE STEAM-SIDE OXIDE IN BOILER TUBES  

SciTech Connect

This effort is concerned with developing a quantitative description of the exfoliation behavior of oxide scales grown inside steam tubes in a pressure boiler. Consideration of the development of stress/strain in growing oxides has included expansion mismatch-induced strains during thermal cycling as well as inelastic mechanical effects from oxide/alloy creep phenomena and volume change from oxide growth. The magnitude of the parameters used has been closely matched to actual boiler operating practice. The creep model used was validated against published data. Representation of oxide growth-induced strain was found to be a difficult challenge because the processes involved are not fully understood. In addition to the traditional uniaxial (radial) and dilatational models, lateral growth models are discussed in the context of experimentally-derived criteria, such as the level of elastic strains involved in oxide exfoliation. It was found that strain variation in the oxide cannot be neglected.

Sabau, Adrian S [ORNL; Wright, Ian G [ORNL

2010-01-01T23:59:59.000Z

226

Fabrication of thermal microphotonic sensors and sensor arrays  

DOE Patents (OSTI)

A thermal microphotonic sensor is fabricated on a silicon substrate by etching an opening and a trench into the substrate, and then filling in the opening and trench with silicon oxide which can be deposited or formed by thermally oxidizing a portion of the silicon substrate surrounding the opening and trench. The silicon oxide forms a support post for an optical resonator which is subsequently formed from a layer of silicon nitride, and also forms a base for an optical waveguide formed from the silicon nitride layer. Part of the silicon substrate can be selectively etched away to elevate the waveguide and resonator. The thermal microphotonic sensor, which is useful to detect infrared radiation via a change in the evanescent coupling of light between the waveguide and resonator, can be formed as a single device or as an array.

Shaw, Michael J. (Tijeras, NM); Watts, Michael R. (Albuquerque, NM); Nielson, Gregory N. (Albuquerque, NM)

2010-10-26T23:59:59.000Z

227

HEATS: Thermal Energy Storage  

SciTech Connect

HEATS Project: The 15 projects that make up ARPA-E’s HEATS program, short for “High Energy Advanced Thermal Storage,” seek to develop revolutionary, cost-effective ways to store thermal energy. HEATS focuses on 3 specific areas: 1) developing high-temperature solar thermal energy storage capable of cost-effectively delivering electricity around the clock and thermal energy storage for nuclear power plants capable of cost-effectively meeting peak demand, 2) creating synthetic fuel efficiently from sunlight by converting sunlight into heat, and 3) using thermal energy storage to improve the driving range of electric vehicles (EVs) and also enable thermal management of internal combustion engine vehicles.

None

2012-01-01T23:59:59.000Z

228

Holographic thermalization patterns  

E-Print Network (OSTI)

We investigate the behaviour of various correlators in N=4 super Yang Mills theory, taking finite coupling corrections into account. In the thermal limit we investigate the flow of the quasinormal modes as a function of the 't Hooft coupling. Then by using a specific model of holographic thermalization we investigate the deviation of the spectral densities from their thermal limit in an out-of-equilibrium situation. The main focus lies on the thermalization pattern with which the various plasma constituents of different energies approach their final thermal distribution as the coupling constant decreases from the infinite coupling limit. All results point towards the weakening of the usual top down thermalization pattern.

Stefan Stricker

2014-03-11T23:59:59.000Z

229

Holographic thermalization patterns  

E-Print Network (OSTI)

We investigate the behaviour of various correlators in N=4 super Yang Mills theory, taking finite coupling corrections into account. In the thermal limit we investigate the flow of the quasinormal modes as a function of the 't Hooft coupling. Then by using a specific model of holographic thermalization we investigate the deviation of the spectral densities from their thermal limit in an out-of-equilibrium situation. The main focus lies on the thermalization pattern with which the various plasma constituents of different energies approach their final thermal distribution as the coupling constant decreases from the infinite coupling limit. All results point towards the weakening of the usual top down thermalization pattern.

Stricker, Stefan

2014-01-01T23:59:59.000Z

230

Nanotechnology for regenerative medicine  

Science Journals Connector (OSTI)

Future biomaterials must simultaneously enhance tissue regeneration while minimizing immune responses and inhibiting infection. While the field of tissue engineering has promised to develop materials that can pro...

Dongwoo Khang; Joseph Carpenter; Young Wook Chun; Rajesh Pareta…

2010-08-01T23:59:59.000Z

231

Non-thermal Plasma Chemistry Non-thermal Thermal  

E-Print Network (OSTI)

automotive industry optics biomedical technology environmental technology Plasma Technology Quote from: Pla-thermal Plasma Chemical Flow Reactor #12;Werner von Siemens ,, ... construction of an apparatus generation (1857) pollution control volatile organic components, NOx reforming, ... radiation sources excimer

Greifswald, Ernst-Moritz-Arndt-Universität

232

Thermal contact resistance  

E-Print Network (OSTI)

This work deals with phenomena of thermal resistance for metallic surfaces in contact. The main concern of the work is to develop reliable and practical methods for prediction of the thermal contact resistance for various ...

Mikic, B. B.

1966-01-01T23:59:59.000Z

233

Solar Thermal Processes  

Science Journals Connector (OSTI)

The use of solar energy for desalination purposes was one of ... The process is based on the use of solar thermal energy to evaporate water, thus separating pure ... brine. In this chapter an overview of solar thermal

M.T. Chaibi; Ali M. El-Nashar

2009-01-01T23:59:59.000Z

234

Thermal Neutron Scattering  

Science Journals Connector (OSTI)

... of its title. It is not for the nuclear physicist, nor even for the neutron physicist, but for the student of solids and liquids. "Thermal ... physicist, but for the student of solids and liquids. "Thermal neutron ...

G. E. BACON

1968-11-09T23:59:59.000Z

235

Controlling Formaldehyde Emissions with Boiler Ash  

Science Journals Connector (OSTI)

Regenerative thermal (2) or catalytic (3) oxidizers are presently used to control HAPs and other VOCs. ... In another, methanol and other VOCs released from the manufacture of printed circuit boards were trapped and concentrated in activated carbon beds before being oxidized (11). ... The capital cost of a fluidized bed is much lower than that of a thermal oxidizer, and the cost of natural gas required to operate the oxidizer is removed. ...

Jennifer Cowan; Malyuba Abu-Daabes; Sujit Banerjee

2005-06-02T23:59:59.000Z

236

Thermal neutron detection system  

DOE Patents (OSTI)

According to the present invention, a system for measuring a thermal neutron emission from a neutron source, has a reflector/moderator proximate the neutron source that reflects and moderates neutrons from the neutron source. The reflector/moderator further directs thermal neutrons toward an unmoderated thermal neutron detector.

Peurrung, Anthony J. (Richland, WA); Stromswold, David C. (West Richland, WA)

2000-01-01T23:59:59.000Z

237

Thermal Performance Benchmarking (Presentation)  

SciTech Connect

This project will benchmark the thermal characteristics of automotive power electronics and electric motor thermal management systems. Recent vehicle systems will be benchmarked to establish baseline metrics, evaluate advantages and disadvantages of different thermal management systems, and identify areas of improvement to advance the state-of-the-art.

Moreno, G.

2014-11-01T23:59:59.000Z

238

Multiwavelength Thermal Emission  

E-Print Network (OSTI)

Multiwavelength Astronomy NASA #12;Thermal Emission #12;Thermal Emission Non-thermal p-p collisions Optical IR Radio/ Microwave sources of emission massive stars, WHIM, Ly many dust, cool objects-ray ~GeV Gamma-ray ~TeV sources of emission AGN, clusters, SNR, binaries, stars AGN (obscured), shocks

California at Santa Cruz, University of

239

Thermal Insulation in Solar Thermal Devices  

Science Journals Connector (OSTI)

Thermal Insulation is a device or a practice which is used in a system for minimising heat losses caused due to transfer of heat from hotter to colder regions. It is one of the cheapest methods of energy conse...

B. C. Raychaudhuri

1986-01-01T23:59:59.000Z

240

Polyoxometalate water oxidation catalysts and methods of use thereof  

DOE Patents (OSTI)

Homogeneous water oxidation catalysts (WOCs) for the oxidation of water to produce hydrogen ions and oxygen, and methods of making and using thereof are described herein. In a preferred embodiment, the WOC is a polyoxometalate WOC which is hydrolytically stable, oxidatively stable, and thermally stable. The WOC oxidized waters in the presence of an oxidant. The oxidant can be generated photochemically, using light, such as sunlight, or electrochemically using a positively biased electrode. The hydrogen ions are subsequently reduced to form hydrogen gas, for example, using a hydrogen evolution catalyst (HEC). The hydrogen gas can be used as a fuel in combustion reactions and/or in hydrogen fuel cells. The catalysts described herein exhibit higher turn over numbers, faster turn over frequencies, and/or higher oxygen yields than prior art catalysts.

Hill, Craig L.; Gueletii, Yurii V.; Musaev, Djamaladdin G.; Yin, Qiushi; Botar, Bogdan

2014-09-02T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Oxidation of propylene over copper oxide catalysts  

E-Print Network (OSTI)

to the study of propylene oxidation. Dunlop (17) reported that small quantities of iron compounds substantially enhanced the catalytic activity of chromia-alumina catalysts with respect to propylene oxidation, Woodharn (72) has suggested that under... between 360 C and 430oC the rate of propane oxidation decreases as the teznperature is increased, and the rate of conversion to olefins, especially propylene, becomes progressively greater. Above 430 C the proportion of propane converted to ethylene in...

Billingsley, David Stuart

2012-06-07T23:59:59.000Z

242

Nitric oxide inhibition of soot oxidation by oxygen atoms at 298/sup 0/Ktiation  

SciTech Connect

Nitric oxide is observed to inhibit the rate of soot oxidation by oxygen atoms at 298 K. Small amounts of added NO reduce the rates of production of CO/sub 2/ and CO by up to 35%. The authors show experimentally that NO is not reducing the gas phase O atom concentration. Thermal description mass spectrometry is used to measure the small adsorption of NO on the soot; this NO adsorption corresponds to 1.5% of the carbon atoms on the surface of the individual soot spheres. This inhibition is interpreted in terms of a relatively small number of reactive sites on the soot at which soot gasification occurs and which are effectively blocked by NO. When considered together with our previously reported work on oxidation of soot by oxygen atoms at 298 K, these results allow a partial mechanism to be formulated for this soot oxidation process.

Wicke, B.G.; Grady, K.A.

1987-01-01T23:59:59.000Z

243

Thermo Physical Properties of Materials for Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

Solid oxide fuel cells (SOFCs) are energy conversion devices that convert chemical energy to electrical energy with high efficiency and have the added advantage of least production of pollutants during their operation. SOFCs comprise of a number of components such as the anode the electrolyte the cathode and the interconnect. Each of these components is made of a different material with different thermophysical and electrical properties. Thermal expansion coefficient is one of the most important properties of these compounds. Various components should have matching thermal expansion behaviour to avoid cracking during thermal cycling and for long term operation of SOFCs. In this article the thermophysical properties of materials for solid oxide fuel cells will be discussed with special emphasize on their thermal expansion behaviour.

S. R. Bharadwaj

2010-01-01T23:59:59.000Z

244

E-Print Network 3.0 - al oxide films Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

in semiconductors produced by thermally oxidizing AlN thin films... O2 flow at 800 to 1100C for 1- 4 ... Source: Kolodzey, James - Department of Electrical and Computer...

245

Pd oxidation under UHV in a model Pd/ceria–zirconia catalyst  

Science Journals Connector (OSTI)

A model planar catalyst was prepared by depositing Pd onto a thick (few ?m) film of ceria–zirconia in ultrahigh vacuum (UHV), and the oxidation state of Pd ... -ray photoelectron spectroscopy, following thermal t...

M.Yu. Smirnov; G.W. Graham

2001-03-01T23:59:59.000Z

246

Autothermal oxidative pyrolysis of biomass feedstocks over noble metal catalysts to liquid products.  

E-Print Network (OSTI)

??Two thermal processing technologies have emerged for processing biomass into renewable liquid products: pyrolysis and gasification/Fischer-Tropsch processing. The work presented here will demonstrate oxidative pyrolysis… (more)

Balonek, Christine Marie

2011-01-01T23:59:59.000Z

247

Commercialization of cryptomelane-type manganese oxide (OMS-2) nanowire paper oil sorbent  

E-Print Network (OSTI)

Cryptomelane-type Manganese oxide (OMS-2, a group of Octahedral Molecular Sieves) nanowire paper exhibits interesting properties: reversible wettability, oleophilic while being hydrophobic, and high thermal stability. These ...

Soo, Haw Yun

2007-01-01T23:59:59.000Z

248

Oxidation kinetics of aluminum diboride  

SciTech Connect

The oxidation characteristics of aluminum diboride (AlB{sub 2}) and a physical mixture of its constituent elements (Al+2B) were studied in dry air and pure oxygen using thermal gravimetric analysis to obtain non-mechanistic kinetic parameters. Heating in air at a constant linear heating rate of 10 °C/min showed a marked difference between Al+2B and AlB{sub 2} in the onset of oxidation and final conversion fraction, with AlB{sub 2} beginning to oxidize at higher temperatures but reaching nearly complete conversion by 1500 °C. Kinetic parameters were obtained in both air and oxygen using a model-free isothermal method at temperatures between 500 and 1000 °C. Activation energies were found to decrease, in general, with increasing conversion for AlB{sub 2} and Al+2B in both air and oxygen. AlB{sub 2} exhibited O{sub 2}-pressure-independent oxidation behavior at low conversions, while the activation energies of Al+2B were higher in O{sub 2} than in air. Differences in the composition and morphology between oxidized Al+2B and AlB{sub 2} suggested that Al{sub 2}O{sub 3}–B{sub 2}O{sub 3} interactions slowed Al+2B oxidation by converting Al{sub 2}O{sub 3} on aluminum particles into a Al{sub 4}B{sub 2}O{sub 9} shell, while the same Al{sub 4}B{sub 2}O{sub 9} developed a needle-like morphology in AlB{sub 2} that reduced oxygen diffusion distances and increased conversion. The model-free kinetic analysis was critical for interpreting the complex, multistep oxidation behavior for which a single mechanism could not be assigned. At low temperatures, moisture increased the oxidation rate of Al+2B and AlB{sub 2}, but both appear to be resistant to oxidation in cool, dry environments. - Graphical abstract: Isothermal kinetic data for AlB{sub 2} in air, showing a constantly decreasing activation energy with increasing conversion. Model-free analysis allowed for the calculation of global kinetic parameters despite many simultaneous mechanisms occurring concurrently. (a) Time–temperature plots, (b) conversion as a function of time, (c) Arrhenius plots used to calculate activation energies, and (d) activation energy as a function of conversion. Display Omitted - Highlights: • First reported kinetic parameters for AlB{sub 2} and Al+2B oxidation in air and O{sub 2}. • Possible mechanism of enhanced boron combustion presented. • Moisture sensitivity shown to be problematic for AlB{sub 2}, less for Al+2B.

Whittaker, Michael L., E-mail: michaelwhittaker2016@u.northwestern.edu [Department of Materials Science and Engineering, University of Utah, 122S. Central Campus Drive, Salt Lake City, UT 84112 (United States); Sohn, H.Y. [Department of Metallurgical Engineering, University of Utah, 135S 1460 E, Rm 00412, Salt Lake City, UT 84112 (United States); Cutler, Raymond A. [Ceramatec, Inc., 2425S. 900W., Salt Lake City, UT 84119 (United States)

2013-11-15T23:59:59.000Z

249

Thermal comfort during surgery  

E-Print Network (OSTI)

THERMAL COMFORT DURING SURGERY A Thesis by DAVID HAROLD MANNING Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE December 1978 Major Subject: Industrial... Engineering THERMAL COMFORT DURING SURGERY A Thesis by DAVID HAROLD MANNING Approved as to style and content by: airman of C it ee Head of Department Member Me er December 1978 ABSTRACT Thermal Comfort During Surgery (December 1978) David Harold...

Manning, David Harold

1978-01-01T23:59:59.000Z

250

Copper(I) Cyanide Networks: Synthesis, Luminescence Behavior and Thermal Analysis. Part 1. Diimine Ligands  

E-Print Network (OSTI)

materials derived from copper(I) halides.3 However, the resistance of copper(I) halides toward oxidationCopper(I) Cyanide Networks: Synthesis, Luminescence Behavior and Thermal Analysis. Part 1. Diimine are noted for the novel 4- and 5-coordinate Cu2- (CN)2 dimers. Thermal analyses show that most

Pike, Robert D.

251

An Improved Thermal Oxidation Method for the Quantification of  

E-Print Network (OSTI)

of Washington, Seattle, Washington 98195-7940, USA, and CSIRO Land and Water, PMB #2, Glen Osmond, SA 5064. Detection limit and GBC recovery in spiked samples were 10 mg kg-1 and 85%, respectively. Typical GBC of condensation products that could account for as much as 4-6% of total OC. Combined to stable and radioisotope

Long, Bernard

252

Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

A Solid Oxide Fuel Cell (SOFC) is typically composed of two porous electrodes, interposed between an electrolyte made of a particular solid oxide ceramic material. The system originates from the work of Nernst...

Nigel M. Sammes; Roberto Bove; Jakub Pusz

2006-01-01T23:59:59.000Z

253

Variable pressure thermal insulating jacket  

DOE Patents (OSTI)

A device for controlled insulation of a thermal device is disclosed. The device includes a thermal jacket with a closed volume able to be evacuated to form an insulating jacket around the thermal source. A getter material is in communication with the closed volume of the thermal jacket. The getter material can absorb and desorb a control gas to control gas pressure in the volume of the thermal jacket to control thermal conductivity in the thermal jacket. 10 figs.

Nelson, P.A.; Malecha, R.F.; Chilenskas, A.A.

1994-09-20T23:59:59.000Z

254

Refractory oxides for high?temperature coal?fired MHD air heaters  

Science Journals Connector (OSTI)

In a coal?burning MHD (Magnetohydrodynamic) power plant the use of a regenerative air heater is one option for producing the required high plasma temperatures. However thermal mechanical and chemical stresses which the MHD environment places on materials are enormous and candidate materials must be carefully tested. We report on the results of such testing for a variety of materials studied in heater test facilities at both FluiDyne Engineering Corporation and at Montana State University. We describe the experimental program and test facilities for MHD heater development the rationale for the choice of materials and their performance (success or failure) under various envirnoments (slagging and nonslagging). Future materials needs are discussed in light of the observed effects.

Richard J. Pollina; Ronald R. Smyth

1981-01-01T23:59:59.000Z

255

NANO REVIEW Open Access Thermal conductivity and thermal boundary  

E-Print Network (OSTI)

NANO REVIEW Open Access Thermal conductivity and thermal boundary resistance of nanostructures and the thermal transport prop- erties is a key point to design materials with preferred thermal properties with the heat dissipation on them. The influence of the interfacial roughness on the thermal conductivity

Boyer, Edmond

256

VARIOUS DEVICES. THE CHARACTERISATION OF METAL-THIN INSULATOR-n-p+  

E-Print Network (OSTI)

oxide layer thermally grown on the n-type Si FIG. 1. - a) Schematic illustration of the device structure incorporat- ing a thin ( 50 Ã?) oxide layer, including the influence of a modulating base current, the effect of temperature and the dynamic performance. A quantitative analysis of a regenerative model of switching

Paris-Sud XI, Université de

257

Steady and Transient Characteristics of Catalytic Flow Reverse Reactor Integrated with Central Heat Exchanger  

Science Journals Connector (OSTI)

Most projects among them employ thermal flow-reversal oxidizers. ... Methane is oxidized into CO2 and water, and its global warming potential is reduced by 87%. ... The regenerative combustion can achieve theoretically an autothermal run of system, even if methane in air is 0.2% v/v. ...

Sheng Wang; Diannan Gao; Shudong Wang

2014-07-28T23:59:59.000Z

258

Thermal Insulation of Houses  

Science Journals Connector (OSTI)

... THE Thermal Insulation (Dwellings) Bill which Mr. G. Nabarro introduced into the House of Commons on ... , sponsored by members of both major political parties, extends the principle of the Thermal Insulation (Industrial Buildings) Act of July 1957 to all new dwelling houses built in the ...

1958-02-22T23:59:59.000Z

259

Mechanical Engineering & Thermal Group  

E-Print Network (OSTI)

Mechanical Engineering & Thermal Group The Mechanical Engineering (ME) & Thermal Group at LASP has, and ground- based mechanical systems. Instrument Design Building on decades of design experience that has evolved with the complexity of instrument design demands, LASP mechanical engineers develop advanced

Mojzsis, Stephen J.

260

Tunable thermal link  

DOE Patents (OSTI)

Disclosed is a device whereby the thermal conductance of a multiwalled nanostructure such as a multiwalled carbon nanotube (MWCNT) can be controllably and reversibly tuned by sliding one or more outer shells with respect to the inner core. As one example, the thermal conductance of an MWCNT dropped to 15% of the original value after extending the length of the MWCNT by 190 nm. The thermal conductivity returned when the tube was contracted. The device may comprise numbers of multiwalled nanotubes or other graphitic layers connected to a heat source and a heat drain and various means for tuning the overall thermal conductance for applications in structure heat management, heat flow in nanoscale or microscale devices and thermal logic devices.

Chang, Chih-Wei; Majumdar, Arunava; Zettl, Alexander K.

2014-07-15T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Solar thermal aircraft  

DOE Patents (OSTI)

A solar thermal powered aircraft powered by heat energy from the sun. A heat engine, such as a Stirling engine, is carried by the aircraft body for producing power for a propulsion mechanism, such as a propeller. The heat engine has a thermal battery in thermal contact with it so that heat is supplied from the thermal battery. A solar concentrator, such as reflective parabolic trough, is movably connected to an optically transparent section of the aircraft body for receiving and concentrating solar energy from within the aircraft. Concentrated solar energy is collected by a heat collection and transport conduit, and heat transported to the thermal battery. A solar tracker includes a heliostat for determining optimal alignment with the sun, and a drive motor actuating the solar concentrator into optimal alignment with the sun based on a determination by the heliostat.

Bennett, Charles L. (Livermore, CA)

2007-09-18T23:59:59.000Z

262

nitrogen oxides | OpenEI  

Open Energy Info (EERE)

20 20 Varnish cache server Browse Upload data GDR 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 2142279720 Varnish cache server nitrogen oxides Dataset Summary Description Emissions from energy use in buildings are usually estimated on an annual basis using annual average multipliers. Using annual numbers provides a reasonable estimation of emissions, but it provides no indication of the temporal nature of the emissions. Therefore, there is no way of understanding the impact on emissions from load shifting and peak shaving technologies such as thermal energy storage, on-site renewable energy, and demand control. Source NREL Date Released April 11th, 2011 (3 years ago) Date Updated April 11th, 2011 (3 years ago)

263

Excellent oxidation endurance of boron nitride nanotube field electron emitters  

SciTech Connect

Boron nitride nanotubes (BNNTs) are considered as a promising cold electron emission material owing to their negative electron affinity. BNNT field emitters show excellent oxidation endurance after high temperature thermal annealing of 600?°C in air ambient. There is no damage to the BNNTs after thermal annealing at a temperature of 600?°C and also no degradation of field emission properties. The thermally annealed BNNTs exhibit a high maximum emission current density of 8.39?mA/cm{sup 2} and show very robust emission stability. The BNNTs can be a promising emitter material for field emission devices under harsh oxygen environments.

Song, Yenan [Department of Micro/Nano Systems, Korea University, Seoul 136-713 (Korea, Republic of); Sun, Yuning; Hoon Shin, Dong; Nam Yun, Ki [School of Electrical Engineering, Korea University, Seoul 136-713 (Korea, Republic of); Song, Yoon-Ho [Nano Electron-Source Creative Research Center, Creative and Challenging Research Division, ETRI, Daejeon 305-700 (Korea, Republic of); Milne, William I. [Electrical Engineering Division, Engineering Department, Cambridge University, Cambridge CB3 0FA (United Kingdom); Jin Lee, Cheol, E-mail: cjlee@korea.ac.kr [Department of Micro/Nano Systems, Korea University, Seoul 136-713 (Korea, Republic of); School of Electrical Engineering, Korea University, Seoul 136-713 (Korea, Republic of)

2014-04-21T23:59:59.000Z

264

Interfacial Shear Strength of Oxide Scale and SS 441 Substrate  

SciTech Connect

Recent developments on decreasing the operating temperature for Solid Oxide Fuel Cells (SOFCs) have enabled the use of high temperature ferritic alloys as interconnect materials. Oxide scale will inevitably grow on the ferritic interconnects in a high temperature oxidation environment of SOFCs. The growth of the oxide scale induces growth stresses in the scale layer and on the scale/substrate interface. These growth stresses combined with the thermal stresses induced upon stacking cooling by the thermal expansion coefficient mismatch between the oxide scale and the substrate may lead to scale delamination/buckling and eventual spallation, which may lead to serious cell performance degradation. Hence the interfacial adhesion strength between the oxide scale and the substrate is crucial to the reliability and durability of the metallic interconnect in SOFC operating environments. In this paper, we applied an integrated experimental/modeling methodology to quantify the interfacial adhesion strength between the oxide scale and the SS 441 metallic interconnect. The predicted interfacial strength is discussed in details.

Liu, Wenning N.; Sun, Xin; Stephens, Elizabeth V.; Khaleel, Mohammad A.

2011-05-01T23:59:59.000Z

265

Preparation and oxidation resistance of mullite/SiC coating for carbon materials at 1150 °C  

Science Journals Connector (OSTI)

To protect carbon materials from oxidation, mullite/SiC coatings were prepared on graphite by chemical vapor reaction (CVR) and slurry sintering. The XRD analyses show that the phase of the outer-layer coating is composed of SiO2 and mullite, and the inner-layer coating is mainly composed of ?-SiC. The anti-oxidation behavior of the coating and the Rockwell hardness (HRB) of the coating after oxidation were investigated. The oxidation test shows that the as-prepared multi-layer coating exhibits excellent anti-oxidation and thermal shock resistance at high temperature. After oxidation at 1150 °C for 109 h and thermal shock cycling between 1150 °C and room temperature for 12 times, the mass gain of the coated sample is 0.085%. Meanwhile, the indentation tests also demonstrate that the as-prepared coating has good bonding ability between the layers.

Xin YANG; Zhe-an SU; Qi-zhong HUANG; Li-yuan CHAI

2012-01-01T23:59:59.000Z

266

Author's personal copy Crystal structure and compressibility of a high-pressure Ti-rich oxide,  

E-Print Network (OSTI)

promising candidate for the development of electrolytes in solid oxide fuel cells. & 2009 Elsevier Ltd. All for solid-oxide-fuel-cell electrolytes, owing to its excellent stability at high temperature, good, solid electrolytes in high-temperature fuel cells, thermal barrier coatings in engines, and high

Downs, Robert T.

267

Growth of magnesium oxide thin lms using single molecular precursors by metalorganic chemical vapor deposition  

E-Print Network (OSTI)

Growth of magnesium oxide thin ®lms using single molecular precursors by metal±organic chemical precursors; Silicon; Sapphire 1. Introduction Magnesium oxide (MgO) thin ®lms have attracted much attention MgO ®lms on Si(100) above 6508C by thermal CVD. Murayama and Shionoya [12] used magnesium 2

Boo, Jin-Hyo

268

SOFC seal and cell thermal management  

SciTech Connect

The solid oxide fuel cell module includes a manifold, a plate, a cathode electrode, a fuel cell and an anode electrode. The manifold includes an air or oxygen inlet in communication with divergent passages above the periphery of the cell which combine to flow the air or oxygen radially or inwardly for reception in the center of the cathode flow field. The latter has interconnects providing circuitous cooling passages in a generally radial outward direction cooling the fuel cell and which interconnects are formed of different thermal conductivity materials for a preferential cooling.

Potnis, Shailesh Vijay (Neenah, WI); Rehg, Timothy Joseph (Huntington Beach, CA)

2011-05-17T23:59:59.000Z

269

Thermal Decomposition of Radiation-Damaged Polystyrene  

SciTech Connect

The radiation-damaged polystyrene material (''polycube'') used in this study was synthesized by mixing a high-density polystyrene (''Dylene Fines No. 100'') with plutonium and uranium oxides. The polycubes were used on the Hanford Site in the 1960s for criticality studies to determine the hydrogen-to-fissile atom ratios for neutron moderation during processing of spent nuclear fuel. Upon completion of the studies, two methods were developed to reclaim the transuranic (TRU) oxides from the polymer matrix: (1) burning the polycubes in air at 873 K; and (2) heating the polycubes in the absence of oxygen and scrubbing the released monomer and other volatile organics using carbon tetrachloride. Neither of these methods was satisfactory in separating the TRU oxides from the polystyrene. Consequently, the remaining polycubes were sent to the Hanford Plutonium Finishing Plant (PFP) for storage. Over time, the high dose of alpha and gamma radiation has resulted in a polystyrene matrix that is highly cross-linked and hydrogen deficient and a stabilization process is being developed in support of Defense Nuclear Facility Safety Board Recommendation 94-1. Baseline processes involve thermal treatment to pyrolyze the polycubes in a furnace to decompose the polystyrene and separate out the TRU oxides. Thermal decomposition products from this degraded polystyrene matrix were characterized by Pacific Northwest National Laboratory to provide information for determining the environmental impact of the process and for optimizing the process parameters. A gas chromatography/mass spectrometry (GC/MS) system coupled to a horizontal tube furnace was used for the characterization studies. The decomposition studies were performed both in air and helium atmospheres at 773 K, the planned processing temperature. The volatile and semi-volatile organic products identified for the radiation-damaged polystyrene were different from those observed for virgin polystyrene. The differences were in the n umber of organic species generated and their concentrations.

J Abrefah GS Klinger

2000-09-26T23:59:59.000Z

270

High-Temperature Thermal Array for Next Generation Solar Thermal...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Thermal Array for Next Generation Solar Thermal Power Production Award Number: DE-EE00025828 Report Date: March 15, 2013 PI: Stephen Obrey * Technical approach is focused on...

271

Integrated thermal treatment system study -- Phase 2 results. Revision 1  

SciTech Connect

This report presents the second phase of a study on thermal treatment technologies. The study consists of a systematic assessment of nineteen thermal treatment alternatives for the contact-handled mixed low-level waste (MLLW) currently stored in the US Department of Energy complex. The treatment alternatives consist of widely varying technologies for safely destroying the hazardous organic components, reducing the volume, and preparing for final disposal of the MLLW. The alternatives considered in Phase 2 were innovative thermal treatments with nine types of primary processing units. Other variations in the study examined the effect of combustion gas, air pollution control system design, and stabilization technology for the treatment residues. The Phase 1 study examined ten initial thermal treatment alternatives. The Phase 2 systems were evaluated in essentially the same manner as the Phase 1 systems. The alternatives evaluated were: rotary kiln, slagging kiln, plasma furnace, plasma gasification, molten salt oxidation, molten metal waste destruction, steam gasification, Joule-heated vitrification, thermal desorption and mediated electrochemical oxidation, and thermal desorption and supercritical water oxidation. The quantities, and physical and chemical compositions, of the input waste used in the Phase 2 systems differ from those in the Phase 1 systems, which were based on a preliminary waste input database developed at the onset of the Integrated Thermal Treatment System study. The inventory database used in the Phase 2 study incorporates the latest US Department of Energy information. All systems, both primary treatment systems and subsystem inputs, have now been evaluated using the same waste input (2,927 lb/hr). 28 refs., 88 figs., 41 tabs.

Feizollahi, F.; Quapp, W.J.

1996-02-01T23:59:59.000Z

272

Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide  

E-Print Network (OSTI)

Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide Laboratory (PAL), Pohang 790-784, Republic of Korea ABSTRACT: The capacities of graphene oxide (GO) and reduced graphene oxide (rGO) films grown on silicon substrate to cause the aniline to azobenzene oxidation

Kim, Sehun

273

Oxidation Resistant Graphite Studies  

SciTech Connect

The Very High Temperature Reactor (VHTR) Graphite Research and Development Program is investigating doped nuclear graphite grades exhibiting oxidation resistance. During a oxygen ingress accident the oxidation rates of the high temperature graphite core region would be extremely high resulting in significant structural damage to the core. Reducing the oxidation rate of the graphite core material would reduce the structural effects and keep the core integrity intact during any air-ingress accident. Oxidation testing of graphite doped with oxidation resistant material is being conducted to determine the extent of oxidation rate reduction. Nuclear grade graphite doped with varying levels of Boron-Carbide (B4C) was oxidized in air at nominal 740°C at 10/90% (air/He) and 100% air. The oxidation rates of the boronated and unboronated graphite grade were compared. With increasing boron-carbide content (up to 6 vol%) the oxidation rate was observed to have a 20 fold reduction from unboronated graphite. Visual inspection and uniformity of oxidation across the surface of the specimens were conducted. Future work to determine the remaining mechanical strength as well as graphite grades with SiC doped material are discussed.

W. Windes; R. Smith

2014-07-01T23:59:59.000Z

274

Theory of delayed thermal fluorescence  

Science Journals Connector (OSTI)

A theory of nonradiative thermal activation involved in delayed thermal fluorescence has been developed from the viewpoint of the breakdown of the Born-Oppenheimer adiabatic approximation.

S. H. Lin

1971-01-01T23:59:59.000Z

275

Thermal insulations using vacuum panels  

DOE Patents (OSTI)

Thermal insulation vacuum panels are formed of an inner core of compressed low thermal conductivity powders enclosed by a ceramic/glass envelope evaluated to a low pressure.

Glicksman, Leon R. (Lynnfield, MA); Burke, Melissa S. (Pittsburgh, PA)

1991-07-16T23:59:59.000Z

276

Fabrication of Cerium Oxide and Uranium Oxide Microspheres for Space Nuclear Power Applications  

SciTech Connect

Cerium oxide and uranium oxide microspheres are being produced via an internal gelation sol-gel method to investigate alternative fabrication routes for space nuclear fuels. Depleted uranium and non-radioactive cerium are being utilized as surrogates for plutonium-238 (Pu-238) used in radioisotope thermoelectric generators and for enriched uranium required by nuclear thermal rockets. While current methods used to produce Pu-238 fuels at Los Alamos National Laboratory (LANL) involve the generation of fine powders that pose a respiratory hazard and have a propensity to contaminate glove boxes, the sol-gel route allows for the generation of oxide microsphere fuels through an aqueous route. The sol-gel method does not generate fine powders and may require fewer processing steps than the LANL method with less operator handling. High-quality cerium dioxide microspheres have been fabricated in the desired size range and equipment is being prepared to establish a uranium dioxide microsphere production capability.

Jeffrey A. Katalenich; Michael R. Hartman; Robert C. O'Brien

2013-02-01T23:59:59.000Z

277

Thermally driven circulation  

E-Print Network (OSTI)

Several problems connected by the theme of thermal forcing are addressed herein. The main topic is the stratification and flow field resulting from imposing a specified heat flux on a fluid that is otherwise confined to a ...

Nelken, Haim

1987-01-01T23:59:59.000Z

278

Manipulation of Thermal Phonons  

E-Print Network (OSTI)

to manipulate the behavior of phonons is crucial for both energy applications and the cooling of integrated circuits. A novel class of artificially periodic structured materials — phononic crystals — might make manipulation of thermal phonons possible. In many...

Hsu, Chung-Hao

2013-03-28T23:59:59.000Z

279

Solar Thermal Energy Storage  

Science Journals Connector (OSTI)

Various types of thermal energy storage systems are introduced and their importance and desired characteristics are outlined. Sensible heat storage, which is one of the most commonly used storage systems in pract...

E. Paykoç; S. Kakaç

1987-01-01T23:59:59.000Z

280

Contact thermal lithography  

E-Print Network (OSTI)

Contact thermal lithography is a method for fabricating microscale patterns using heat transfer. In contrast to photolithography, where the minimum achievable feature size is proportional to the wavelength of light used ...

Schmidt, Aaron Jerome, 1979-

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Neutron stars - thermal emitters  

E-Print Network (OSTI)

Confronting theoretical models with observations of thermal radiation emitted by neutron stars is one of the most important ways to understand the properties of both, superdense matter in the interiors of the neutron stars and dense magnetized plasmas in their outer layers. Here we review the theory of thermal emission from the surface layers of strongly magnetized neutron stars, and the main properties of the observational data. In particular, we focus on the nearby sources for which a clear thermal component has been detected, without being contaminated by other emission processes (magnetosphere, accretion, nebulae). We also discuss the applications of the modern theoretical models of the formation of spectra of strongly magnetized neutron stars to the observed thermally emitting objects.

Potekhin, A Y; Pons, J A

2014-01-01T23:59:59.000Z

282

Texas Thermal Comfort Report  

NLE Websites -- All DOE Office Websites (Extended Search)

thermal comfort thermal comfort Too often, the systems in our houses are both physically and intellectually inaccessible. In the SNAP House, HVAC components are integrated into the overall structure, and act as an experiential threshold between public and private spaces. They are located in a central, structural chase that supports the clerestory and gives the systems a functional presence within the interior. Each individual component is contained within a single chase

283

Photovoltaic-thermal collectors  

DOE Patents (OSTI)

A photovoltaic-thermal solar cell including a semiconductor body having antireflective top and bottom surfaces and coated on each said surface with a patterned electrode covering less than 10% of the surface area. A thermal-absorbing surface is spaced apart from the bottom surface of the semiconductor and a heat-exchange fluid is passed between the bottom surface and the heat-absorbing surface.

Cox, III, Charles H. (Carlisle, MA)

1984-04-24T23:59:59.000Z

284

Modifications of the surface properties of metals by oxide overlayers: 1, Oxidized zirconium deposited on the Pt(100) single crystal surface  

SciTech Connect

Metallic zirconium was deposited on a single crystal Pt(100) surface by thermal evaporation in UHV conditions. The deposit was oxidized by exposure to oxygen immediately after deposition. Oxidized zirconium was found to grow on the platinum ace by the layer-by-layer mechanism. The adsorption of carbon monoxide on the surface was studied as a function of the zirconium coverage. The results show that oxidized zirconium forms a chemically inert layer which blocks the adsorptive sites of the underlying platinum substrate. The properties of the free Pt surface were unaffected by the presence of the oxidized zirconium layer.

Bardi, U.; Ross, P.N.

1986-06-01T23:59:59.000Z

285

METAL OXIDE NANOPARTICLES  

SciTech Connect

This chapter covers the fundamental science, synthesis, characterization, physicochemical properties and applications of oxide nanomaterials. Explains fundamental aspects that determine the growth and behavior of these systems, briefly examines synthetic procedures using bottom-up and top-down fabrication technologies, discusses the sophisticated experimental techniques and state of the art theory results used to characterize the physico-chemical properties of oxide solids and describe the current knowledge concerning key oxide materials with important technological applications.

FERNANDEZ-GARCIA,M.; RODGRIGUEZ, J.A.

2007-10-01T23:59:59.000Z

286

Dynamic modelling for thermal micro-actuators using thermal networks  

E-Print Network (OSTI)

Dynamic modelling for thermal micro-actuators using thermal networks Beatriz L´opez-Wallea,1 and analytical calculations. Key words: Micro-actuators, Thermal modelling, Electrical analogy, Thermal network 1 and MicroMechatronic Systems Department (AS2M), 24 rue Alain Savary, 25000 Besan¸con, France Abstract

Paris-Sud XI, Université de

287

Enhanced performance of high temperature aluminate cementitious materials incorporated with Cu powders for thermal energy storage  

Science Journals Connector (OSTI)

Abstract Cementitious materials have been extensively developed in thermal energy storage system of solar thermal power. This paper deals with the volume heat capacity, thermal conductivity, thermal expansion coefficient, and compressive strength of aluminate cementitious thermal energy storage materials with the addition of metal Cu powders. The specimens were subjected to heat-treatment at 105, 350, and 900 °C, respectively. In the heating process, Cu powders gradually oxidized to Cu2O and CuO, providing a so-called mass compensation mechanism for the composite paste. Meanwhile, it indicates that volume heat capacity and thermal conductivity both increase with increasing Cu powders content and decrease with the rising temperature. The optimum thermal properties were obtained at 15 wt% Cu powders loading. In addition, Calorimetric Test, XRD, TG–DSC, and MIP are performed for characterizing the hydration rates, the phases, the mass/heat evolution, and the pore distribution, respectively.

Huiwen Yuan; Yu Shi; Chunhua Lu; Zhongzi Xu; Yaru Ni; Xianghui Lan

2015-01-01T23:59:59.000Z

288

Subchannel Thermal-Hydraulic Experimental Program (STEP). Volume 1. Mixing in a pressurized water reactor (PWR) rod bundle. Final report  

SciTech Connect

This volume describes an experiment that was performed to determine the mixing characteristics of a pressurized water reactor (PWR) rod bundle. The objective of this project was to improve the subchannel computer code models of the reactor core. The experimental technique was isokinetic subchannel withdrawal of the entire flow from two sample subchannels. Once withdrawn, the sample fluid was condensed and its enthalpy was measured by regenerative heat exchange calorimetry. The test bundle was a 4 x 6 electrically heated array with a 50% power upset. The COBRA IIIC code was used to model the experiment and to determine the value of the thermal mixing coefficient, ..beta.., that was necessary to predict the measured results. Both single- and two-phase data were obtained over a range of PWR operating conditions. The results indicate that both single- and two-phase mixing is small. The COBRA model predicts the enthalpy data using a turbulent mixing coefficient, ..beta.. approx. = 0.002.

Barber, A.R.; Zielke, L.A.

1980-08-01T23:59:59.000Z

289

Development of a He{sup 3}?He{sup 4} sub Kelvin active magnetic regenerative refrigerator (AMRR) with no moving parts  

SciTech Connect

Current state of the art particle and photon detectors such as Transition Edge Sensors (TES) and Microwave Kinetic Inductance Detectors (MKID) use large arrays of sensors or detectors for space science missions. As the size of these space science detectors increases, future astrophysics missions will require sub-Kelvin cooling over larger areas. This leads to not only increased cooling power requirements, but also a requirement for distributed sub-Kelvin cooling. We propose an active Magnetic Regenerative Refrigerator (AMRR) that uses a Superfluid Magnetic Pump (SMP) to circulate liquid He{sup 3}?He{sup 4} through a magnetic regenerator to provide the necessary cooling at sub-Kelvin temperatures. Such system will be capable of distributing the cooling load to a relatively large array of objects. One advantage of using a fluid for heat transfer in such systems is to isolate components such as the superconducting magnets from detectors that are sensitive to magnetic fields. Another advantage of the proposed tandem AMRR is that it does not need Gas Gap Heat Switches (GGHS) to transfer heat during various stages of the magnetic cooling. Our proposed system consists of four superconducting magnets, one superleak, and three heat exchangers. It will operate continuously with no moving parts and it will be capable of providing the necessary cooling at sub-Kelvin temperatures for future space science applications.

Jahromi, A. E. [Ph.D. student, University of Wisconsin -1500 Engineering Drive, 1335 ERB, Madison, WI, 53706 (United States); Miller, F. K. [Assistant Professor of Mechanical Engineering, University of Wisconsin - 1500 Engineering Drive, 1341 ERB Madison, WI 53706 (United States)

2014-01-29T23:59:59.000Z

290

Improved Initial Performance of Si Nanoparticles by Surface Oxide Reduction  

NLE Websites -- All DOE Office Websites (Extended Search)

Improved Initial Performance of Si Nanoparticles by Surface Oxide Reduction Improved Initial Performance of Si Nanoparticles by Surface Oxide Reduction for Lithium-Ion Battery Application Title Improved Initial Performance of Si Nanoparticles by Surface Oxide Reduction for Lithium-Ion Battery Application Publication Type Journal Article Year of Publication 2011 Authors Xun, Shidi, Xiangyun Song, Michael E. Grass, Daniel K. Roseguo, Z. Liu, Vincent S. Battaglia, and Gao Li Journal Electrochemical Solid-State Letters Volume 14 Start Page A61 Issue 5 Pagination A61-A63 Date Published 02/2001 Keywords Electrochemistry, elemental semiconductors, etching, lithium, nanoparticles, secondary cells, silicon, thermal analysis, transmission electron microscopy, X-ray photoelectron spectra Abstract This study characterizes the native oxide layer of Si nanoparticles and evaluates its effect on their performance for Li-ion batteries. x-ray photoelectron spectroscopy and transmission electron microscopy were applied to identify the chemical state and morphology of the native oxide layer. Elemental and thermogravimetric analysis were used to estimate the oxide content for the Si samples. Hydrofluoric acid was used to reduce the oxide layer. A correlation between etching time and oxide content was established. The initial electrochemical performances indicate that the reversible capacity of etched Si nanoparticles was enhanced significantly compared with that of the as-received Si sample.

291

Reactor process using metal oxide ceramic membranes  

DOE Patents (OSTI)

A reaction vessel for use in photoelectrochemical reactions includes as its reactive surface a metal oxide porous ceramic membrane of a catalytic metal such as titanium. The reaction vessel includes a light source and a counter electrode. A provision for applying an electrical bias between the membrane and the counter electrode permits the Fermi levels of potential reaction to be favored so that certain reactions may be favored in the vessel. The electrical biasing is also useful for the cleaning of the catalytic membrane. Also disclosed is a method regenerating a porous metal oxide ceramic membrane used in a photoelectrochemical catalytic process by periodically removing the reactants and regenerating the membrane using a variety of chemical, thermal, and electrical techniques. 2 figures.

Anderson, M.A.

1994-05-03T23:59:59.000Z

292

Stabilized chromium oxide film  

DOE Patents (OSTI)

Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150.ANG. are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

Garwin, Edward L. (Los Altos, CA); Nyaiesh, Ali R. (Palo Alto, CA)

1988-01-01T23:59:59.000Z

293

Stabilized chromium oxide film  

DOE Patents (OSTI)

Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150A are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

Nyaiesh, A.R.; Garwin, E.L.

1986-08-04T23:59:59.000Z

294

Ethylene Oxide Explosions  

Science Journals Connector (OSTI)

... THE occasional occurrence of ethylene oxide explosions during the fumigation of dried fruit has led us to undertake a detailed ... yielded results somewhat like those for acetaldehyde1,2.. Cool flames can be initiated in ethylene oxide – air mixtures in the neighbourhood of 330° C. at atmospheric pressure. ...

J. H. BURGOYNE; F. A. BURDEN

1948-07-31T23:59:59.000Z

295

Growth of CrO[subscript 2] coated single crystalline (SnO[subscript 2]) tin oxide nanowires  

E-Print Network (OSTI)

Single crystalline tin oxide (SnO[subscript 2]) nanowires have been synthesized by carbothermal reduction of SnO[subscript 2] nanopowder followed by thermal evaporation of the reduced precursor and growth via the ...

Miao, Guo-Xing

296

Wear Behavior of Plasma-Sprayed Carbon Nanotube-Reinforced Aluminum Oxide Coating in Marine and High-Temperature Environments  

Science Journals Connector (OSTI)

Plasma-sprayed aluminum oxide (Al2O3) coatings offer excellent wear resistance, corrosion resistance, heat, and thermal...1-6...). These coatings have to operate under severe conditions, such as high load, high s...

Anup Kumar Keshri; Arvind Agarwal

2011-12-01T23:59:59.000Z

297

Thermal Decomposition of Radiation-Damaged Polystyrene  

SciTech Connect

The radiation-damaged polystyrene (given the identification name of 'polycube') was fabricated by mixing high-density polystyrene material ("Dylene Fines # 100") with plutonium and uranium oxides. The polycubes were used in the 1960s for criticality studies during processing of spent nuclear fuel. The polycubes have since been stored for almost 40 years at the Hanford Plutonium Finishing Plant (PFP) after failure of two processes to reclaim the plutonium and uranium oxides from the polystyrene matrix. Thermal decomposition products from this highly cross-linked polystyrene matrix were characterized using Gas Chromatograph/Mass Spectroscopy (GC/MS) system coupled to a horizontal furnace. The decomposition studies were performed in air and helium atmospheres at about 773 K. The volatile and semi-volatile organic products for the radiation-damaged polystyrene were different compared to virgin polystyrene. The differences were in the number of organic species generated and their concentrations. In the inert (i.e., helium) atmosphere, the major volatile organic products identified (in order of decreasing concentrations) were styrene, benzene, toluene, ethylbenzene, xylene, nathphalene, propane, .alpha.-methylbenzene, indene and 1,2,3-trimethylbenzene. But in air, the major volatile organic species identified changed slightly. Concentrations of the organic species in the inert atmosphere were significantly higher than those for the air atmosphere processing. Overall, 38 volatile organic species were identified in the inert atmosphere compared to 49 species in air. Twenty of the 38 species in the inert conditions were also products in the air atmosphere. Twenty-two oxidized organic products were identified during thermal processing in air.

Abrefah, John; Klinger, George S.

2000-09-26T23:59:59.000Z

298

Oxidative Degradation of Monoethanolamine  

NLE Websites -- All DOE Office Websites (Extended Search)

Oxidative Degradation of Monoethanolamine Oxidative Degradation of Monoethanolamine Susan Chi Gary T. Rochelle* (gtr@che.utexas.edu, 512-471-7230) The University of Texas at Austin Department of Chemical Engineering Austin, Texas 78712 Prepared for presentation at the First National Conference on Carbon Sequestration, Washington, DC, May 14-17, 2001 Abstract Oxidative degradation of monoethanolamine (MEA) was studied under typical absorber condition of 55°C. The rate of evolution of NH 3 , which was indicative of the overall rate of degradation, was measured continuously in a batch system sparged with air. Dissolved iron from 0.0001 mM to 1 mM yields oxidation rates from 0.37 to 2 mM/hr in MEA solutions loaded with 0.4 mole CO 2 / mole MEA. Ethylenediaminetetraacetic acid (EDTA) and N,N-bis(2- hydroxyethyl)glycine effectively decrease the rate of oxidation in the presence of iron by 40 to

299

THERMAL NEUTRON BACKSCATTER IMAGING.  

SciTech Connect

Objects of various shapes, with some appreciable hydrogen content, were exposed to fast neutrons from a pulsed D-T generator, resulting in a partially-moderated spectrum of backscattered neutrons. The thermal component of the backscatter was used to form images of the objects by means of a coded aperture thermal neutron imaging system. Timing signals from the neutron generator were used to gate the detection system so as to record only events consistent with thermal neutrons traveling the distance between the target and the detector. It was shown that this time-of-flight method provided a significant improvement in image contrast compared to counting all events detected by the position-sensitive {sup 3}He proportional chamber used in the imager. The technique may have application in the detection and shape-determination of land mines, particularly non-metallic types.

VANIER,P.; FORMAN,L.; HUNTER,S.; HARRIS,E.; SMITH,G.

2004-10-16T23:59:59.000Z

300

Microwave Drilling of Ceramic Thermal-Barrier Coatings Faculty of Engineering, Tel Aviv University, Ramat Aviv 69978, Israel  

E-Print Network (OSTI)

oxidation-resistant bond coat and a thermally insulating layer of yttria-stabilized zirconia (YSZMicrowave Drilling of Ceramic Thermal-Barrier Coatings Eli Jerby Faculty of Engineering, Tel Aviv materials. Its inherent material selec- tivity makes the microwave drill ideally suited for the con- trolled

Jerby, Eli

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Thermal ignition combustion system  

DOE Patents (OSTI)

The thermal ignition combustion system comprises means for providing walls defining an ignition chamber, the walls being made of a material having a thermal conductivity greater than 20 W/m C and a specific heat greater than 480 J/kg C with the ignition chamber being in constant communication with the main combustion chamber, means for maintaining the temperature of the walls above a threshold temperature capable of causing ignition of a fuel, and means for conducting fuel to the ignition chamber. 8 figs.

Kamo, R.; Kakwani, R.M.; Valdmanis, E.; Woods, M.E.

1988-04-19T23:59:59.000Z

302

Scattering Solar Thermal Concentrators  

Energy.gov (U.S. Department of Energy (DOE))

"This fact sheet describes a scattering solar thermal concentrators project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The team, led by the Pennsylvania State University, is working to demonstrate a new, scattering-based approach to concentrating sunlight that aims to improve the overall performance and reliability of the collector field. The research team aims to show that scattering solar thermal collectors are capable of achieving optical performance equal to state-of-the-art parabolic trough systems, but with the added benefits of immunity to wind-load tracking error, more efficient land use, and utilization of stationary receivers."

303

Thermal ignition combustion system  

SciTech Connect

The thermal ignition combustion system comprises means for providing walls defining an ignition chamber, the walls being made of a material having a thermal conductivity greater than 20 W/m.degree. C. and a specific heat greater than 480 J/kg.degree. C. with the ignition chamber being in constant communication with the main combustion chamber, means for maintaining the temperature of the walls above a threshold temperature capable of causing ignition of a fuel, and means for conducting fuel to the ignition chamber.

Kamo, Roy (Columbus, IN); Kakwani, Ramesh M. (Columbus, IN); Valdmanis, Edgars (Columbus, IN); Woods, Melvins E. (Columbus, IN)

1988-01-01T23:59:59.000Z

304

Thermal ignition combustion system  

SciTech Connect

A thermal ignition combustion system adapted for use with an internal combustion engine is described comprising: (a) means for providing ignition chamber walls defining an ignition chamber, the chamber walls being made of a material having a thermal conductivity greater than 20 W/m/sup 0/C. and a specific heat greater than 480J/kg/sup 0/C., the ignition chamber being in constant communication with the main combustion chamber; (b) means for maintaining the temperature of the chamber walls above a threshold temperature capable of causing ignition of a fuel; and (c) means for conducting fuel to the ignition chamber.

Kamo, R.; Kakwani, R.M.; Valdmanis, E.; Woods, M.E.

1988-04-19T23:59:59.000Z

305

Thermal test options  

SciTech Connect

Shipping containers for radioactive materials must be qualified to meet a thermal accident environment specified in regulations, such at Title 10, Code of Federal Regulations, Part 71. Aimed primarily at the shipping container design, this report discusses the thermal testing options available for meeting the regulatory requirements, and states the advantages and disadvantages of each approach. The principal options considered are testing with radiant heat, furnaces, and open pool fires. The report also identifies some of the facilities available and current contacts. Finally, the report makes some recommendations on the appropriate use of these different testing methods.

Koski, J.A.; Keltner, N.R.; Sobolik, K.B.

1993-02-01T23:59:59.000Z

306

Full-field characterization of thermal diffusivity in continuous- fiber ceramic composite materials and components  

SciTech Connect

Continuous-fiber ceramic matrix composites (CFCCs) are currently being developed for various high-temperature applications, including use in advanced heat engines. Among the material classes of interest for such applications are silicon carbide (SiC)-fiber-reinforced SiC (SiC{sub (f)}/SiC), SiC-fiber-reinforced silicon nitride (SiC {sub (f)}/Si{sub 3}N{sub 4}), aluminum oxide (Al{sub 2}O{sub 3})-fiber-reinforced Al{sub 2}O{sub 3} (Al{sub 2}O{sub 3}{sub (f)}/Al{sub 2}O{sub 3}), and others. In such composites, the condition of the interfaces (between the fibers and matrix) are critical to the mechanical and thermal behavior of the component (as are conventional mechanical defects such as cracks, porosity, etc.). For example, oxidation of this interface (especially on carbon coated fibers) can seriously degrade both mechanical and thermal properties. Furthermore, thermal shock damage can degrade the matrix through extensive crack generation. A nondestructive evaluation method that could be used to assess interface condition, thermal shock damage, and to detect other ``defects`` would thus be very beneficial, especially if applicable to full-scale components. One method under development uses infrared thermal imaging to provide ``single-shot`` full-field assessment of the distribution of thermal properties in large components by measuring thermal diffusivity. By applying digital image filtering, interpolation, and least-squares-estimation techniques for noise reduction, we can achieve acquisition and analysis times of minutes or less with submillimeter spatial resolution. The system developed at Argonne has been used to examine the effects of thermal shock, oxidation treatment, density variations, and variations in oxidation resistant coatings in a full array of test specimens. Subscale CFCC components with nonplanar geometries have also been studied for manufacturing-induced variations in thermal properties.

Steckenrider, J.S.; Ellingson, W.A. [Argonne National Lab., IL (United States); Rothermel, S.A. [South Dakota State Univ., Brookings, SD (United States)

1995-05-01T23:59:59.000Z

307

Phase-Transfer-Catalyzed Oxidations  

Science Journals Connector (OSTI)

Phase-transfer catalysis (PTC) offers many excellent opportunities for conducting oxidation reactions using inexpensive primary oxidants such as oxygen, sodium hypochlorite, hydrogen peroxide, electrooxidation...

Charles M. Starks; Charles L. Liotta; Marc E. Halpern

1994-01-01T23:59:59.000Z

308

High Thermal Conductivity UO2-BeO Nulcear Fuel: Neutronic Performance Assessments and Overview of Fabrication  

E-Print Network (OSTI)

for the continuous (a) and dispersed (b) types [16]. 2.3 Silicon Carbide as a High Conductivity Additive Solomon et al. explored the feasibility of increasing the thermal conductivity of oxide fuels by the addition of a second, higher thermal conductivity solid... methodology used to restrict the CO or SiO gases. All processing, therefore, must take place below this temperature. Because of ! "# Table 2.3. Samples used in the thermal conductivity measurements $%&'()&*! $(+!%,-.&/! 0...

Naramore, Michael J

2010-08-03T23:59:59.000Z

309

Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants  

E-Print Network (OSTI)

ENERGY STORAGE FOR CONCENTRATING SOLAR POWER PLANTS,”Thermal Energy Storage in Concentrated Solar Thermal PowerThermal Energy Storage in Concentrated Solar Thermal Power

Hardin, Corey Lee

2011-01-01T23:59:59.000Z

310

Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants  

E-Print Network (OSTI)

CHANGE THERMAL ENERGY STORAGE FOR CONCENTRATING SOLAR POWERfor Thermal Energy Storage in Concentrated Solar Thermalfor Thermal Energy Storage in Concentrated Solar Thermal

Hardin, Corey Lee

2011-01-01T23:59:59.000Z

311

Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants  

E-Print Network (OSTI)

and Background Solar thermal energy collection is anCHANGE THERMAL ENERGY STORAGE FOR CONCENTRATING SOLAR POWERfor Thermal Energy Storage in Concentrated Solar Thermal

Hardin, Corey Lee

2011-01-01T23:59:59.000Z

312

Effect of Thermal Hydrolysis on Rheological Behavior of Municipal Sludge  

Science Journals Connector (OSTI)

Effect of Thermal Hydrolysis on Rheological Behavior of Municipal Sludge ... Fenton oxidation facilitated sludge filterability resulting in capillary suction time values which were approximately 50% of the raw sludges, whereas ultrasonication with high input energy deteriorated the filterability. ... Bingham's parameters seem to be able to detect the evolution in sludges quality and in floc strength even at low total suspended solid as the one's usually found in activated sludge processes (less than 10 g l-1). ...

Guohong Feng; Liyan Liu; Wei Tan

2014-06-12T23:59:59.000Z

313

Evaporative oxidation treatability test report  

SciTech Connect

In 1992, Congress passed the Federal Facilities Compliance Act that requires the U.S. Department of Energy (DOE) to treat and dispose of its mixed waste in accordance with the Resource Conservation and Recovery Act (RCRA) land disposal restrictions (LDRs). In response to the need for mixed-waste treatment capacity where available off-site commercial treatment facilities do not exist or cannot be used, the DOE Albuquerque Operations Office (DOE-AL) organized a Treatment Selection Team to match mixed wastes with treatment options and develop a strategy for treatment of its mixed wastes. DOE-AL manages operations at nine sites with mixed-waste inventories. The Treatment Selection Team determined a need to develop mobile treatment capacity to treat wastes at the sites where the wastes are generated. Treatment processes used for mixed waste not only must address the hazardous component (i.e., meet LDRs) but also must contain the radioactive component in a form that allows final disposal while protecting workers, the public, and the environment. On the basis of recommendations of the Treatment Selection Team, DOE-AL assigned projects to the sites to bring mixed-waste treatment capacity on-line. The three technologies assigned to the DOE Grand Junction Projects Office (GJPO) are evaporative oxidation, thermal desorption, and treated wastewater evaporation. Rust Geotech, the DOE-GJPO prime contractor, was assigned to design and fabricate mobile treatment units (MTUs) for these three technologies and to deliver the MTUs to selected DOE-AL sites. To conduct treatability tests at the GJPO, Rust leased a pilot-scale evaporative oxidation unit from the Clemson Technical Center (CTC), Anderson, South Carolina. The purpose of this report is to document the findings and results of tests performed using this equipment.

NONE

1995-04-01T23:59:59.000Z

314

Thermal barrier coating  

DOE Patents (OSTI)

A thermal barrier coating for hot gas path components of a combustion turbine based on a zirconia-scandia system. A layer of zirconium scandate having the hexagonal Zr.sub.3 Sc.sub.4 O.sub.12 structure is formed directly on a superalloy substrate or on a bond coat formed on the substrate.

Bowker, Jeffrey Charles (Gibsonia, PA); Sabol, Stephen M. (Orlando, FL); Goedjen, John G. (Oviedo, FL)

2001-01-01T23:59:59.000Z

315

Thermal management of nanoelectronics  

E-Print Network (OSTI)

-state thermoelectric on- spot cooling, requiring efficient thermoelectric materials that can be integrated with the IC are further complicated by the fact that the material's ability to conduct heat deteriorates when at the packaging level but also at the nanoscale materials and device levels. THERMAL CHALLENGES AT NANOSCALE One

316

Thermal Reactor Safety  

SciTech Connect

Information is presented concerning fire risk and protection; transient thermal-hydraulic analysis and experiments; class 9 accidents and containment; diagnostics and in-service inspection; risk and cost comparison of alternative electric energy sources; fuel behavior and experiments on core cooling in LOCAs; reactor event reporting analysis; equipment qualification; post facts analysis of the TMI-2 accident; and computational methods.

Not Available

1980-06-01T23:59:59.000Z

317

High-Temperature Thermal Array for Next Generation Solar Thermal...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

3 Q1 High-Temperature Thermal Array for Next Generation Solar Thermal Power Production - FY13 Q1 This document summarizes the progress of this Los Alamos National Laboratory...

318

Impact of Ageing on Thermal Efficiency of Solar Thermal Collectors  

Science Journals Connector (OSTI)

Today it is common practice to calculate the performance of solar thermal systems or solar collectors based on the results of a thermal performance test carried out with a new solar collector. However, for an int...

Elke Streicher; Stephan Fischer…

2009-01-01T23:59:59.000Z

319

SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL  

E-Print Network (OSTI)

SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL CELLS Dynamic Simulation Approach Modular Approach · Parallel planes: PSOFC · Other: combustor, reformer Solid Oxide Fuel Cell Electrochemistry Cell Reactions · Slow pressure transients #12;Fuel Cell Assumptions · H2 electrochemically oxidized only · CO consumed

Mease, Kenneth D.

320

Oxidation Protection of Uranium Nitride Fuel using Liquid Phase Sintering  

SciTech Connect

Two methods are proposed to increase the oxidation resistance of uranium nitride (UN) nuclear fuel. These paths are: (1) Addition of USi{sub x} (e.g. U3Si2) to UN nitride powder, followed by liquid phase sintering, and (2) 'alloying' UN nitride with various compounds (followed by densification via Spark Plasma Sintering or Liquid Phase Sintering) that will greatly increase oxidation resistance. The advantages (high thermal conductivity, very high melting point, and high density) of nitride fuel have long been recognized. The sodium cooled BR-10 reactor in Russia operated for 18 years on uranium nitride fuel (UN was used as the driver fuel for two core loads). However, the potential advantages (large power up-grade, increased cycle lengths, possible high burn-ups) as a Light Water Reactor (LWR) fuel are offset by uranium nitride's extremely low oxidation resistance (UN powders oxidize in air and UN pellets decompose in hot water). Innovative research is proposed to solve this problem and thereby provide an accident tolerant LWR fuel that would resist water leaks and high temperature steam oxidation/spalling during an accident. It is proposed that we investigate two methods to increase the oxidation resistance of UN: (1) Addition of USi{sub x} (e.g. U{sub 3}Si{sub 2}) to UN nitride powder, followed by liquid phase sintering, and (2) 'alloying' UN nitride with compounds (followed by densification via Spark Plasma Sintering) that will greatly increase oxidation resistance.

Dr. Paul A. Lessing

2012-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Preliminary requirements for thermal storage subsystems in solar thermal applications  

SciTech Connect

Methodologies for the analysis of value and comparing thermal storage concepts are presented. Value is a measure of worth and is determined by the cost of conventional fuel systems. Value data for thermal storage in large solar thermal electric power applications are presented. Thermal storage concepts must be compared when all are performing the same mission. A method for doing that analysis, called the ranking index, is derived. Necessary data to use the methodology are included.

Copeland, R.J.

1980-04-01T23:59:59.000Z

322

Carbonate-salt-based composite materials for medium- and high-temperature thermal energy storage  

Science Journals Connector (OSTI)

Abstract This paper discusses composite materials based on inorganic salts for medium- and high-temperature thermal energy storage application. The composites consist of a phase change material (PCM), a ceramic material, and a high thermal conductivity material. The ceramic material forms a microstructural skeleton for encapsulation of the PCM and structural stability of the composites; the high thermal conductivity material enhances the overall thermal conductivity of the composites. Using a eutectic salt of lithium and sodium carbonates as the PCM, magnesium oxide as the ceramic skeleton, and either graphite flakes or carbon nanotubes as the thermal conductivity enhancer, we produced composites with good physical and chemical stability and high thermal conductivity. We found that the wettability of the molten salt on the ceramic and carbon materials significantly affects the microstructure of the composites.

Zhiwei Ge; Feng Ye; Hui Cao; Guanghui Leng; Yue Qin; Yulong Ding

2014-01-01T23:59:59.000Z

323

Syngas Oxidation Mechanism  

Science Journals Connector (OSTI)

A comprehensive analysis of synthesis gas (syngas) oxidation kinetics in wide ranges of temperature ... on the basis of the reaction mechanism of syngas ignition and combustion in air. A vast set of experimental ...

A. M. Starik; N. S. Titova; A. S. Sharipov…

2010-09-01T23:59:59.000Z

324

Effect of Natural Gas Fuel Addition on the Oxidation of Fuel Cell Anode Gas  

SciTech Connect

The anode exhaust gas from a fuel cell commonly has a fuel energy density between 15 and 25% that of the fuel supply, due to the incomplete oxidation of the input fuel. This exhaust gas is subsequently oxidized (catalytically or non-catalytically), and the resultant thermal energy is often used elsewhere in the fuel cell process. Alternatively, additional fuel can be added to this stream to enhance the oxidation of the stream, for improved thermal control of the power plant, or to adjust the temperature of the exhaust gas as may be required in other specialty co-generation applications. Regardless of the application, the cost of a fuel cell system can be reduced if the exhaust gas oxidation can be accomplished through direct gas phase oxidation, rather than the usual catalytic oxidation approach. Before gas phase oxidation can be relied upon however, combustor design requirements need to be understood. The work reported here examines the issue of fuel addition, primarily as related to molten-carbonate fuel cell technology. It is shown experimentally that without proper combustor design, the addition of natural gas can readily quench the anode gas oxidation. The Chemkin software routines were used to resolve the mechanisms controlling the chemical quenching. It is found that addition of natural gas to the anode exhaust increases the amount of CH3 radicals, which reduces the concentration of H and O radicals and results in decreased rates of overall fuel oxidation.

Randall S. Gemmen; Edward H. Robey, Jr.

1999-11-01T23:59:59.000Z

325

Graphite Oxidation Simulation in HTR Accident Conditions  

SciTech Connect

Massive air and water ingress, following a pipe break or leak in steam-generator tubes, is a design-basis accident for high-temperature reactors (HTRs). Analysis of these accidents in both prismatic and pebble bed HTRs requires state-of-the-art capability for predictions of: 1) oxidation kinetics, 2) air ?helium gas mixture stratification and diffusion into the core following the depressurization, 3) transport of multi-species gas mixture, and 4) graphite corrosion. This project will develop a multi-dimensional, comprehensive oxidation kinetics model of graphite in HTRs, with diverse capabilities for handling different flow regimes. The chemical kinetics/multi-species transport model for graphite burning and oxidation will account for temperature-related changes in the properties of graphite, oxidants (O2, H2O, CO), reaction products (CO, CO2, H2, CH4) and other gases in the mixture (He and N2). The model will treat the oxidation and corrosion of graphite in geometries representative of HTR core component at temperatures of 900°C or higher. The developed chemical reaction kinetics model will be user-friendly for coupling to full core analysis codes such as MELCOR and RELAP, as well as computational fluid dynamics (CFD) codes such as CD-adapco. The research team will solve governing equations for the multi-dimensional flow and the chemical reactions and kinetics using Simulink, an extension of the MATLAB solver, and will validate and benchmark the model's predictions using reported experimental data. Researchers will develop an interface to couple the validated model to a commercially available CFD fluid flow and thermal-hydraulic model of the reactor , and will perform a simulation of a pipe break in a prismatic core HTR, with the potential for future application to a pebble-bed type HTR.

Mohamed El-Genk

2012-10-19T23:59:59.000Z

326

Strains in Thermally Growing Alumina Films Measured in-situ usingSynchrotron X-rays  

SciTech Connect

Strains in thermally grown oxides have been measured in-situ, as the oxides develop and evolve. Extensive data have been acquired from oxides grown in air at elevated temperatures on different model alloys that form Al{sub 2}O{sub 3}. Using synchrotron x-rays at the Advanced Photon Source (Beamline 12BM, Argonne National Laboratory), Debye-Scherrer diffraction patterns from the oxidizing specimen were recorded every 5 minutes during oxidation and subsequent cooling. The diffraction patterns were analyzed to determine strains in the oxides, as well as phase changes and the degree of texture. To study a specimen's response to stress perturbation, the oxidizing temperature was quickly cooled from 1100 to 950 C to impose a compressive thermal stress in the scale. This paper describes this new experimental approach and gives examples from oxidized {beta}-NiAl, Fe-20Cr-10Al, Fe-28Al-5Cr and H{sub 2}-annealed Fe-28Al-5Cr (all at. %) alloys to illustrate some current understanding of the development and relaxation of growth stresses in Al{sub 2}O{sub 3}.

Hou, P.Y.; Paulikas, A.P.; Veal, B.W.

2006-01-02T23:59:59.000Z

327

Controlled CO preferential oxidation  

DOE Patents (OSTI)

Method is described for controlling the supply of air to a PROX (PReferential OXidation for CO cleanup) reactor for the preferential oxidation in the presence of hydrogen wherein the concentration of the hydrogen entering and exiting the PROX reactor is monitored, the difference there between correlated to the amount of air needed to minimize such difference, and based thereon the air supply to the PROX reactor adjusted to provide such amount and minimize such difference. 2 figs.

Meltser, M.A.; Hoch, M.M.

1997-06-10T23:59:59.000Z

328

Mechanism for decomposition of aurichalcite—A controlled rate thermal analysis study  

Science Journals Connector (OSTI)

Controlled rate thermal analysis (CRTA) of a series of synthetic aurichalcite (Zn,Cu2+)5(CO3)2(OH)6 with the ratio of Cu/Zn varying from 0.1 to 0.5 proves that the dehydroxylation and carbonate loss occur as non-isothermal and isothermal decompositions. The temperature of the thermal decomposition increases as the Cu/Zn ratio increases. Thermal decomposition of aurichalcite provides a method for preparing mixed oxide catalysts at the molecular level as opposed to the particle level. CRTA technology enables separation of the processes of dehydration, dehydroxylation and decarbonation. X-ray diffraction of the products of the thermal decomposition proved to be a mixture of the oxides ZnO and Cu2O.

Veronika Vágvölgyi; Ashley Locke; Matthew Hales; János Kristóf; Ray L. Frost; Erzsébet Horváth; Wayde N. Martens

2008-01-01T23:59:59.000Z

329

Thermal Storage of Solar Energy  

Science Journals Connector (OSTI)

Thermal storage is needed to improve the efficiency and usefulness of solar thermal systems. The paper indicates the main storage ... which would greatly increase the practical use of solar energy — is more diffi...

H. Tabor

1984-01-01T23:59:59.000Z

330

Thermally conductive cementitious grout for geothermal heat pump systems  

DOE Patents (OSTI)

A thermally conductive cement-sand grout for use with a geothermal heat pump system. The cement sand grout contains cement, silica sand, a superplasticizer, water and optionally bentonite. The present invention also includes a method of filling boreholes used for geothermal heat pump systems with the thermally conductive cement-sand grout. The cement-sand grout has improved thermal conductivity over neat cement and bentonite grouts, which allows shallower bore holes to be used to provide an equivalent heat transfer capacity. In addition, the cement-sand grouts of the present invention also provide improved bond strengths and decreased permeabilities. The cement-sand grouts can also contain blast furnace slag, fly ash, a thermoplastic air entraining agent, latex, a shrinkage reducing admixture, calcium oxide and combinations thereof.

Allan, Marita (Old Field, NY)

2001-01-01T23:59:59.000Z

331

THERMAL ENERGY STORAGE IN AQUIFERS WORKSHOP  

E-Print Network (OSTI)

Survey of Thermal Energy Storage in Aquifers Coupled withLow Temperature Thermal Energy Storage Program of Oak Ridgefor Seasonal Thermal Energy Storage: An Overview of the DOE-

Authors, Various

2011-01-01T23:59:59.000Z

332

Electric Motor Thermal Management | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Merit Review and Peer Evaluation ape030bennion2011o.pdf More Documents & Publications Motor Thermal Control Electric Motor Thermal Management Electric Motor Thermal Management...

333

Power Electronic Thermal System Performance and Integration ...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Motor Thermal Control Thermal Stress and Reliability for Advanced Power Electronics and Electric Machines Integrated Vehicle Thermal Management...

334

THERMAL ENERGY STORAGE IN AQUIFERS WORKSHOP  

E-Print Network (OSTI)

Scale Thermal Energy Storage for Cogeneration and Solarsolar captors, thermal effluents, low cost energy duringSeale Thermal Energy Storage for Cogeneration and Solar

Authors, Various

2011-01-01T23:59:59.000Z

335

Ocean Thermal Extractable Energy Visualization: Final Technical...  

Office of Environmental Management (EM)

Ocean Thermal Extractable Energy Visualization: Final Technical Report Ocean Thermal Extractable Energy Visualization: Final Technical Report Report about the Ocean Thermal...

336

THERMAL ENERGY STORAGE IN AQUIFERS WORKSHOP  

E-Print Network (OSTI)

Survey of Thermal Energy Storage in Aquifers Coupled withconcept of thermal energy storage in aquifers was suggestedAnnual Thermal Energy Storage Contractors' Information

Authors, Various

2011-01-01T23:59:59.000Z

337

Liquid metal thermal electric converter  

DOE Patents (OSTI)

A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

1989-01-01T23:59:59.000Z

338

Low Conductivity Thermal Barrier Coatings  

E-Print Network (OSTI)

Low Conductivity Thermal Barrier Coatings A Dissertation Presented to The Faculty of the School conductivity of the coatings. The minimum thermal conductivity occurs at a low rotation rate and is 0.8 W intrinsic thermal conductivity, good phase stability and greater resistance to sintering and CMAS attack

Wadley, Haydn

339

LSPE Interim Stowage Thermal Constraints  

E-Print Network (OSTI)

-arm and thermal battery timers require operating temperatures at or above +40°F for reliable starting when·, ' LSPE Interim Stowage Thermal Constraints· Nl,;. ATM1080 PAGE 1 OF 13 DATE 15 December l97l constraints required for thermal integrity are defined. Prepared by:.:Z4·:..=..-~31!::..--.::..·~-:·::....-c

Rathbun, Julie A.

340

Reactor Thermal-Hydraulics  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermal-Hydraulics Thermal-Hydraulics Dr. Tanju Sofu, Argonne National Laboratory In a power reactor, the energy produced in fission reaction manifests itself as heat to be removed by a coolant and utilized in a thermodynamic energy conversion cycle to produce electricity. A simplified schematic of a typical nuclear power plant is shown in the diagram below. Primary coolant loop Steam Reactor Heat exchanger Primary pump Secondary pump Condenser Turbine Water Although this process is essentially the same as in any other steam plant configuration, the power density in a nuclear reactor core is typically four orders of magnitude higher than a fossil fueled plant and therefore it poses significant heat transfer challenges. Maximum power that can be obtained from a nuclear reactor is often limited by the

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Thermalization through parton transport  

E-Print Network (OSTI)

A radiative transport model is used to study kinetic equilibration during the early stage of a relativistic heavy ion collision. The parton system is found to be able to overcome expansion and move toward thermalization via parton collisions. Scaling behaviors show up in both the pressure anisotropy and the energy density evolutions. In particular, the pressure anisotropy evolution shows an approximate alpha_s scaling when radiative processes are included. It approaches an asymptotic time evolution on a time scale of 1 to 2 fm/c. The energy density evolution shows an asymptotic time evolution that decreases slower than the ideal hydro evolution. These observations indicate that partial thermalization can be achieved and viscosity is important for the evolution during the early longitudinal expansion stage of a relativistic heavy ion collision.

Bin Zhang

2009-09-03T23:59:59.000Z

342

Thermal energy storage  

Science Journals Connector (OSTI)

Various types of thermal stares for solar systems are surveyed which include: long-term water stores for solar systems; ground storage using soil as an interseasonal energy store; ground-water aquifers; pebble or rock bed storage; phase change storage; solar ponds; high temperature storage; and cold stores for solar air conditioning system. The use of mathematical models for analysis of the storage systems is considered

W.E.J. Neal

1981-01-01T23:59:59.000Z

343

Cylindrical thermal contact conductance  

E-Print Network (OSTI)

of the Mahr-Federal, Inc. respectively facilitated and provided the necessary surface metrology data of the test pieces. Mr. Claude Davis of Corning, Inc. obtained the thermophysical properties of the Ultra Low Expansion Titanium Silicate glass used... as thermal expansion standard. The engineers at National Instruments provided some much-needed advice and software for programming the data acquisition system. The TAMU Physics Machine Shop provided design advice and a couple of last...

Ayers, George Harold

2004-09-30T23:59:59.000Z

344

Thermally actuated thermionic switch  

DOE Patents (OSTI)

A thermally actuated thermionic switch which responds to an increase of temperature by changing from a high impedance to a low impedance at a predictable temperature set point. The switch has a bistable operation mode switching only on temperature increases. The thermionic material may be a metal which is liquid at the desired operation temperature and held in matrix in a graphite block reservoir, and which changes state (ionizes, for example) so as to be electrically conductive at a desired temperature.

Barrus, D.M.; Shires, C.D.

1982-09-30T23:59:59.000Z

345

Modeling of Diesel Oxidation Catalyst  

Science Journals Connector (OSTI)

Modeling of Diesel Oxidation Catalyst ... Optimization of hydrocarbon (HC) oxidation over a diesel oxidation catalyst (DOC) requires consideration of (i) HC gas diffusion into the catalyst layer, (ii) HC gas adsorption and desorption from catalyst sites, and (iii) kinetics of the oxidation reaction. ... Mutagenicity of Diesel Engine Exhaust Is Eliminated in the Gas Phase by an Oxidation Catalyst but Only Slightly Reduced in the Particle Phase ...

Yasushi Tanaka; Takashi Hihara; Makoto Nagata; Naoto Azuma; Akifumi Ueno

2005-09-30T23:59:59.000Z

346

978-1-4244-2128-2/08/$25.00 C 2008 IEEE 9th. Int. Conf. on Thermal, Mechanical and Multiphysics Simulation and Experiments in Micro-Electronics and Micro-Systems, EuroSimE 2008  

E-Print Network (OSTI)

of the thermal resistance is obtained through the integration of AlN layers. This is a material that is fully Aluminum nitride heatspreaders are demonstrated to provide a large reduction of the thermal resistance, silicon oxide and glass, leads also to very high thermal resistances. We have shown that a large decrease

Technische Universiteit Delft

347

Mobile Window Thermal Test  

NLE Websites -- All DOE Office Websites (Extended Search)

Mobile Window Thermal Test (MoWiTT) Facility Mobile Window Thermal Test (MoWiTT) Facility winter.jpg (469135 bytes) The window has come a long way since the days when it was a single pane of glass in a wood frame. Low-emissivity windows were designed to help buildings retain some of the energy that would have leaked out of less efficient windows. Designing efficient window-and-frame systems is one strategy for reducing the energy use of buildings. But the net energy flowing through a window is a combination of temperature- driven thermal flows and transmission of incident solar energy, both of which vary with time. U-factor and solar heat gain coefficient (SHGC), the window properties that control these flows, depend partly on ambient conditions. Window energy flows can affect how much energy a building uses, depending on when the window flows are available to help meet other energy demands within the building, and when they are adverse, adding to building energy use. This leads to a second strategy for reducing building energy use: using the beneficial solar gain available through a window, either for winter heating or for daylighting, while minimizing adverse flows.

348

Nitric oxide inhibition of soot oxidation by oxygen atoms at 298K  

SciTech Connect

Nitric oxide is observed to inhibit the rate of soot oxidation by oxygen atoms at 298K. Small amounts of added NO reduce the rates of production of CO/sub 2/ and CO by up to 35%. The authors show experimentally that NO is not reducing the gas phase O atom concentration. Thermal desorption mass spectrometry shows a small adsorption of NO on the soot; this NO adsorption corresponds to 1.5% of the carbon atoms on the surface of the individual soot spheres. This inhibition is interpreted in terms of a relatively small number of reactive sites on the soot at which soot gasification occurs and which are effectively blocked by NO.

Wicke, B.G.; Grady, K.A.

1987-08-01T23:59:59.000Z

349

Bionics in textiles: flexible and translucent thermal insulations for solar thermal applications  

Science Journals Connector (OSTI)

...translucent thermal insulations for solar thermal applications Thomas Stegmaier...Denkendorf73770 Denkendorf, Germany Solar thermal collectors used at present consist...transparent thermal insulation|solar thermal collector| 1. Introduction...

2009-01-01T23:59:59.000Z

350

CALIFORNIA SOLAR INITIATIVE-THERMAL PROGRAMHANDBOOK  

E-Print Network (OSTI)

CALIFORNIA SOLAR INITIATIVE-THERMAL PROGRAMHANDBOOK CALIFORNIA PUBLIC UTILITIES California Solar Initiative Thermal Program Handbook i 1. Introduction to CSI-Thermal Program ..........................................................................3 2.1 Participants in the CSI-Thermal Program

351

Thermomechanical measurements on thermal microactuators.  

SciTech Connect

Due to the coupling of thermal and mechanical behaviors at small scales, a Campaign 6 project was created to investigate thermomechanical phenomena in microsystems. This report documents experimental measurements conducted under the auspices of this project. Since thermal and mechanical measurements for thermal microactuators were not available for a single microactuator design, a comprehensive suite of thermal and mechanical experimental data was taken and compiled for model validation purposes. Three thermal microactuator designs were selected and fabricated using the SUMMiT V{sup TM} process at Sandia National Laboratories. Thermal and mechanical measurements for the bent-beam polycrystalline silicon thermal microactuators are reported, including displacement, overall actuator electrical resistance, force, temperature profiles along microactuator legs in standard laboratory air pressures and reduced pressures down to 50 mTorr, resonant frequency, out-of-plane displacement, and dynamic displacement response to applied voltages.

Baker, Michael Sean; Epp, David S.; Serrano, Justin Raymond; Gorby, Allen D.; Phinney, Leslie Mary

2009-01-01T23:59:59.000Z

352

Thermal and non-thermal energies in solar flares  

E-Print Network (OSTI)

The energy of the thermal flare plasma and the kinetic energy of the non-thermal electrons in 14 hard X-ray peaks from 9 medium-sized solar flares have been determined from RHESSI observations. The emissions have been carefully separated in the spectrum. The turnover or cutoff in the low-energy distribution of electrons has been studied by simulation and fitting, yielding a reliable lower limit to the non-thermal energy. It remains the largest contribution to the error budget. Other effects, such as albedo, non-uniform target ionization, hot target, and cross-sections on the spectrum have been studied. The errors of the thermal energy are about equally as large. They are due to the estimate of the flare volume, the assumption of the filling factor, and energy losses. Within a flare, the non-thermal/thermal ratio increases with accumulation time, as expected from loss of thermal energy due to radiative cooling or heat conduction. Our analysis suggests that the thermal and non-thermal energies are of the same magnitude. This surprising result may be interpreted by an efficient conversion of non-thermal energy to hot flare plasma.

Pascal Saint-Hilaire; Arnold O. Benz

2005-03-03T23:59:59.000Z

353

Integrated Vehicle Thermal Management Systems (VTMS) Analysis...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Integrated Vehicle Thermal Management Power Electronic Thermal System Performance and Integration Characterization and Development of Advanced Heat Transfer Technologies...

354

Ultratough, Thermally Stable Polycrystalline Diamond/Silicon...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Ultratough, Thermally Stable Polycrystalline DiamondSilicon Carbide Nanocomposites for Drill Bits Ultratough, Thermally Stable Polycrystalline DiamondSilicon Carbide...

355

Report on workshop on thermal property measurements  

SciTech Connect

Results of thermogravimetric analysis of basalt is discussed. Heat capacity, thermal conductivity and thermal expansion are specifically addressed. (CBS)

Robertson, E.C.

1987-01-01T23:59:59.000Z

356

Non-thermal Aftertreatment of Particulates  

SciTech Connect

Modern diesel passenger vehicles employing common rail, high speed direct injection engines are capable of matching the drivability of gasoline powered vehicles with the additional benefit of providing high torque at low engine speed [1]. The diesel engine also offers considerable fuel economy and CO2 emissions advantages. However, future emissions standards [2,3] present a significant challenge for the diesel engine, as its lean exhaust precludes the use of aftertreatment strategies employing 3- way catalytic converters, which operate under stoichiometric conditions. In recent years significant developments by diesel engine manufacturers have greatly reduced emissions of both particulates (PM) and oxides of nitrogen (NOx) [4,5]. However to achieve compliance with future legislative limits it has been suggested that an integrated approach involving a combination of engine modifications and aftertreatment technology [1] will be required. A relatively new approach to exhaust aftertreatment is the application of non-thermal plasma (NTP) or plasma catalyst hybrid systems. These have the potential for treatment of both NOx and PM emissions [6- 8]. The primary focus of recent plasma aftertreatment studies [9-12] has concentrated on the removal of NOx. It has been shown that by combining plasmas with catalysts it is possible to chemically reduce NOx. The most common approach is to use a 2- stage system relying upon the plasma oxidation of hydrocarbons to promote NO to NO2 conversion as a precursor to NO2 reduction over a catalyst. However, relatively little work has yet been published on the oxidation of PM by plasma [ 8,13]. Previous investigations [8] have reported that a suitably designed NTP reactor containing a packing material designed to filter and retain PM can effect the oxidation of PM in diesel exhausts at low temperatures. It has been suggested that the retained PM competes with hydrocarbons for O, and possibly OH, radicals. This is an important consideration in plasma - catalyst hybrid schemes for the removal of NOx employing an NO2 selective catalyst, as the oxidation of PM may deplete the key radicals necessary for NO to NO2 conversion. It was also suggested that where simultaneous NOx and PM removal are required, alternative catalyst formulations may be needed which may be selective to NO rather than NO2.

Thomas, S.E.

2000-08-20T23:59:59.000Z

357

Oxidative Tritium Decontamination System  

SciTech Connect

The Princeton Plasma Physics Laboratory, Tritium Systems Group has developed and fabricated an Oxidative Tritium Decontamination System (OTDS), which is designed to reduce tritium surface contamination on various components and items. The system is configured to introduce gaseous ozone into a reaction chamber containing tritiated items that require a reduction in tritium surface contamination. Tritium surface contamination (on components and items in the reaction chamber) is removed by chemically reacting elemental tritium to tritium oxide via oxidation, while purging the reaction chamber effluent to a gas holding tank or negative pressure HVAC system. Implementing specific concentrations of ozone along with catalytic parameters, the system is able to significantly reduce surface tritium contamination on an assortment of expendable and non-expendable items. This paper will present the results of various experimentation involving employment of this system.

Charles A. Gentile; John J. Parker; Gregory L. Guttadora; Lloyd P. Ciebiera

2002-02-11T23:59:59.000Z

358

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

1999-01-01T23:59:59.000Z

359

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

2001-01-01T23:59:59.000Z

360

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-17T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-24T23:59:59.000Z

362

Oxidation resistant coatings for CoSb3  

Science Journals Connector (OSTI)

Doped cobalt antimonides are used as components of thermoelectric devices at temperatures not exceeding 450 °C because of poor thermal and chemical stability. In absence of oxygen they degrade by sublimation of antimony while in air they easily oxidize to form volatile antimony oxides and non-volatile thick double oxide scales [1]. In both cases protective coatings are indispensable to ensure safe performance of thermoelectric devices over extended times. The most promising solution reported so far is a thick aerogel coating which practically stops antimony loss by sublimation. The assessment of coating effectiveness is generally based on thermogravimetric tests in vacuum so permeability of oxygen and protection from oxidation cannot be evaluated. The paper presents investigations on the development of protective coatings which would prevent oxidation of CoSb3. Two types of coatings were applied: magnetron sputtered Cr-Si thin layers [2] and thick enamel layers. Testing involved interrupted oxidation in air for 20-80 h at 500 °C and 600 °C. The Cr-Si thin layers appeared oxygen-tight at 500 °C while the enamel layers - even at 600 °C.

2012-01-01T23:59:59.000Z

363

Tetraalklylammonium polyoxoanionic oxidation catalysts  

DOE Patents (OSTI)

Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H{sub e{minus}z}[(n-C{sub 4}H{sub 9}){sub 4}N]{sub z}(XM{sub 11}M{prime}O{sub 39}){sup {minus}e}. The M{prime} (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

Ellis, P.E.; Lyons, J.E.; Myers, H.K. Jr.; Shaikh, S.N.

1998-10-06T23:59:59.000Z

364

Tetraalykylammonium polyoxoanionic oxidation catalysts  

DOE Patents (OSTI)

Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H.sub.e-z ›(n-C.sub.4 H.sub.9).sub.4 N!.sub.z (XM.sub.11 M'O.sub.39).sup.-e The M' (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

Ellis, Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA); Myers, Jr., Harry K. (Cochranville, PA); Shaikh, Shahid N. (Media, PA)

1998-01-01T23:59:59.000Z

365

Thermally switchable dielectrics  

DOE Patents (OSTI)

Precursor polymers to conjugated polymers, such as poly(phenylene vinylene), poly(poly(thiophene vinylene), poly(aniline vinylene), and poly(pyrrole vinylene), can be used as thermally switchable capacitor dielectrics that fail at a specific temperature due to the non-conjugated precursor polymer irreversibly switching from an insulator to the conjugated polymer, which serves as a bleed resistor. The precursor polymer is a good dielectric until it reaches a specific temperature determined by the stability of the leaving groups. Conjugation of the polymer backbone at high temperature effectively disables the capacitor, providing a `built-in` safety mechanism for electronic devices.

Dirk, Shawn M.; Johnson, Ross S.

2013-04-30T23:59:59.000Z

366

A Porphyrin-Stabilized Iridium Oxide Water Oxidation Catalyst  

NLE Websites -- All DOE Office Websites (Extended Search)

A Porphyrin-Stabilized Iridium Oxide Water Oxidation Catalyst Authors: Sherman, B. D., Pillai, S., Kodis, G., Bergkamp, J., Mallouk, T. E., Gust, D., Moore, T. A., and Moore, A. L....

367

In vitro magnetic hyperthermia response of iron oxide MNP’s incorporated in DA3, MCF-7 and HeLa cancer cell lines  

Science Journals Connector (OSTI)

In the current work, iron oxide magnetic nanoparticles (MNP’s) were...3-(iron acetylacetonate) compounds in high-boiling organic solvents containing...in vitro hyperthermia results, very fast thermal response was...

Evangelos I. Gkanas

2013-07-01T23:59:59.000Z

368

Thermal and non-thermal energies in solar flares  

E-Print Network (OSTI)

The energy of the thermal flare plasma and the kinetic energy of the non-thermal electrons in 14 hard X-ray peaks from 9 medium-sized solar flares have been determined from RHESSI observations. The emissions have been carefully separated in the spectrum. The turnover or cutoff in the low-energy distribution of electrons has been studied by simulation and fitting, yielding a reliable lower limit to the non-thermal energy. It remains the largest contribution to the error budget. Other effects, such as albedo, non-uniform target ionization, hot target, and cross-sections on the spectrum have been studied. The errors of the thermal energy are about equally as large. They are due to the estimate of the flare volume, the assumption of the filling factor, and energy losses. Within a flare, the non-thermal/thermal ratio increases with accumulation time, as expected from loss of thermal energy due to radiative cooling or heat conduction. Our analysis suggests that the thermal and non-thermal energies are of the same m...

Saint-Hilaire, P; Saint-Hilaire, Pascal; Benz, Arnold O.

2005-01-01T23:59:59.000Z

369

High Temperature Thermal Array for Next Generation Solar Thermal...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

A 10% increase in shaft work is directly attributable to modified thermal heat capacity Engineering HTF Specific heat yields modified power output. 27 127 227 327 427 527...

370

Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide  

E-Print Network (OSTI)

as potential feedstock in solid oxide fuel cells. Petroleum based fuels become scarcer daily, and biodiesel for use in solid oxide fuel cells. This cutting edge area of research continues to be important as energy prove useful for solid oxide fuel cells. METHODS Commercial molybdenum dioxide was used for all tests

Collins, Gary S.

371

Advanced thermally stable jet fuels. Technical progress report, April 1995--June 1995  

SciTech Connect

Research continued on thermally stable jet fuel from coal liquids and petroleum distillates. The oxidative and thermal stabilities of ten fuels have been studied by differential scanning calorimetry and in microautoclave reactors. The compositions of the stressed fuels (as well as the unreacted fuels) were characterized by gas chromatography and gas chromatography/mass spectrometry. In addition, simulated distillation curves were determined by thermogravimetric analysis. The product distributions and reaction mechanisms for the thermal decomposition of n-alkanes in near-critical and supercritical regions were studied. The emphasis of the work in this reporting period has been placed on reaction mechanisms and product distributions. Work is continuing on obtaining additional {sup 13}C-labeled jet fuel components for future thermal stressing studies. Compounds of current interest include 6-{sup 13}C-dodecane and 1-cyclohexyl-1-{sup 13}C-hexane. Further analysis of the formation of solids from the thermal stressing of decane and decalin has been performed.

Schobert, H.H.; Eser, S.; Boehman, A.; Song, C. [and others

1995-08-01T23:59:59.000Z

372

The thermal conductivity of silicon nitride with molybdenum disilicide additions  

SciTech Connect

Room-temperature thermal conductivity has been measured for a series of silicon nitride (Si{sub 3}N{sub 4}) matrix composites with molybdenum disilicide (MoSi{sub 2}) additions of 2, 5 10, 25 and 50 wt. %. Included in these measurements were a pure MoSi{sub 2} sample and a Si{sub 3}N{sub 4} sample containing only sintering aids. Aluminum oxide (Al{sub 2}O{sub 3}) and yttrium oxide (Y{sub 2}O{sub 3}) were added as the sintering aids, at approximately 6 and 2 respectively. When the amount of MoSi{sub 2} was increased to greater than 10 wt. %, the amount of the sintering aids necessary to densify the composite was decreased. No sintering aids were added to the pure MoSi{sub 2} sample. Thermal conductivities of the Si{sub 3}N{sub 4} sample without MoSi{sub 2} and the pure MoSi{sub 2} sample wee 36 W/m.K and 52 W/m.K respectively, which agree very well with the literature values for similar materials. No statistically significant changes were observed in the thermal conductivity for those samples containing up to 10 wt. % MoSi{sub 2}. However, between 10 and 25 wt. % MoSi{sub 2} there was a dramatic decrease in the thermal conductivity from 37 to 20.9 W/m.K. The thermal conductivity then increased steadily with further additions of MoSi{sub 2} up to 52 W/m.K for the pure MoSi{sub 2} specimen.

Beecher, S.C.; Dinwiddie, R.B.; Abeel, A.M.; Lowden, R.A.

1993-12-31T23:59:59.000Z

373

Highly oxidized superconductors  

DOE Patents (OSTI)

Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known synthesis in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed. 16 figs.

Morris, D.E.

1994-09-20T23:59:59.000Z

374

Thermal plasmonic interconnects in graphene  

Science Journals Connector (OSTI)

As one emerging plasmonic material, graphene can support surface plasmons at infrared and terahertz frequencies with unprecedented properties due to the strong interactions between graphene and low-frequency photons. Since graphene surface plasmons exist in the infrared and terahertz regime, they can be thermally pumped (excited) by the infrared evanescent waves emitted from an object. Here we show that thermal graphene plasmons can be efficiently excited and have monochromatic and tunable spectra, thus paving a way to harness thermal energy for graphene plasmonic devices. We further demonstrate that “thermal information communication” via graphene surface plasmons can be potentially realized by effectively harnessing thermal energy from various heat sources, e.g., the waste heat dissipated from nanoelectronic devices. These findings open up an avenue of thermal plasmonics based on graphene for different applications ranging from infrared emission control, to information processing and communication, to energy harvesting.

Baoan Liu; Yongmin Liu; Sheng Shen

2014-11-10T23:59:59.000Z

375

Staged membrane oxidation reactor system  

DOE Patents (OSTI)

Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

2012-09-11T23:59:59.000Z

376

Staged membrane oxidation reactor system  

DOE Patents (OSTI)

Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

2014-05-20T23:59:59.000Z

377

Staged membrane oxidation reactor system  

DOE Patents (OSTI)

Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

2013-04-16T23:59:59.000Z

378

Effects of Thermal Aging on the Mechanical Properties of a Porous-Matrix Ceramic Composite  

E-Print Network (OSTI)

Effects of Thermal Aging on the Mechanical Properties of a Porous-Matrix Ceramic Composite Eric A properties of an all-oxide fiber-reinforced composite following long-term exposure (1000 h) at temperatures of 1000­1200°C in air. The composite of interest derives its damage tolerance from a highly porous matrix

Zok, Frank

379

Impact of thermal strain on the dielectric constant of sputtered barium strontium titanate thin films  

E-Print Network (OSTI)

Impact of thermal strain on the dielectric constant of sputtered barium strontium titanate thin, California 93106 Received 6 November 2001; accepted for publication 10 January 2002 Barium strontium titanate: magnesium oxide, strontium titanate, sapphire, silicon, and vycor glass. These substrates were chosen

York, Robert A.

380

Influence of additives on the thermal behavior of nickel/metal hydride battery  

Science Journals Connector (OSTI)

This study discusses the thermal behavior of the 6.5 Ah cylinder Ni/MH hydride battery with 0.5 wt% ytterbium oxide (...2O3...) in nickel electrode and 1.0 wt% super absorbent polymer (SAP) in hydrogen-storage al...

Kai Yang; Jin Jing An; Shi Chen

2010-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Applications of the thermal DeNO{sub x} process to FBC boilers  

SciTech Connect

This paper presents graphical and tabular information on Exxon Research and Engineering Company`s proprietary NH{sub 3} based selective non-catalytic nitrogen oxides reduction process. The process is applicable to boilers, incinerators, and fired heaters. Process operating parameters, technology, and equipment are outlined. Thermal performance data and simplified flow diagrams are also presented.

McIntyre, A.D. [Exxon Research & Engineering Company, Florham Park, NJ (United States)

1997-12-31T23:59:59.000Z

382

Thermal Decomposition Mechanism of Disilane  

Science Journals Connector (OSTI)

Thermal Decomposition Mechanism of Disilane ... Thermal decomposition of disilane was investigated using time-of-flight (TOF) mass spectrometry coupled with vacuum ultraviolet single-photon ionization (VUV-SPI) at a temperature range of 675?740 K and total pressure of 20?40 Torr. ... Concentrations of disilane and trisilane during thermal decomposition of disilane were quantitatively measured using the VUV-SPI method. ...

Kazumasa Yoshida; Keiji Matsumoto; Tatsuo Oguchi; Kenichi Tonokura; Mitsuo Koshi

2006-03-18T23:59:59.000Z

383

Thermal desorption for passive dosimeter  

E-Print Network (OSTI)

~ ~ ~ \\ ~ ~ ~ ~ Flare Tubes for Thermal Desorber . . . . . ~. . . . . . ~ ~ . 27 4. 5 ~ Thermal Desorber Manufactured by Century System Sample Flow from Thermal Desorber to Gas Chromatograph 29 6. Direct Injection Port for Therma1 Desorber . . . . . $2... the gas badges and. providing additional guidance in conducting the study. DEDICATZOil This thesis is cedicated to my parents and my wife, Unice, for their support during the last t', o years AHSTHACT ACKI;ODL DG~~. 'ITS D' DICATICI'. LIST OF TABL...

Liu, Wen-Chen

1981-01-01T23:59:59.000Z

384

Actively driven thermal radiation shield  

DOE Patents (OSTI)

A thermal radiation shield for cooled portable gamma-ray spectrometers. The thermal radiation shield is located intermediate the vacuum enclosure and detector enclosure, is actively driven, and is useful in reducing the heat load to mechanical cooler and additionally extends the lifetime of the mechanical cooler. The thermal shield is electrically-powered and is particularly useful for portable solid-state gamma-ray detectors or spectrometers that dramatically reduces the cooling power requirements. For example, the operating shield at 260K (40K below room temperature) will decrease the thermal radiation load to the detector by 50%, which makes possible portable battery operation for a mechanically cooled Ge spectrometer.

Madden, Norman W. (Livermore, CA); Cork, Christopher P. (Pleasant Hill, CA); Becker, John A. (Alameda, CA); Knapp, David A. (Livermore, CA)

2002-01-01T23:59:59.000Z

385

Enhanced regeneration of degraded polymer solar cells by thermal annealing  

SciTech Connect

The degradation and thermal regeneration of poly(3-hexylethiophene) (P3HT):[6,6]-phenyl-C{sub 61}-butyric acid methyl ester (PCBM) and P3HT:indene-C{sub 60} bisadduct (ICBA) polymer solar cells, with Ca/Al and Ca/Ag cathodes and indium tin oxide/poly(ethylene-dioxythiophene):polystyrene sulfonate anode have been investigated. Degradation occurs via a combination of three primary pathways: (1) cathodic oxidation, (2) active layer phase segregation, and (3) anodic diffusion. Fully degraded devices were subjected to thermal annealing under inert atmosphere. Degraded solar cells possessing Ca/Ag electrodes were observed to regenerate their performance, whereas solar cells having Ca/Al electrodes exhibited no significant regeneration of device characteristics after thermal annealing. Moreover, the solar cells with a P3HT:ICBA active layer exhibited enhanced regeneration compared to P3HT:PCBM active layer devices as a result of reduced changes to the active layer morphology. Devices combining a Ca/Ag cathode and P3HT:ICBA active layer demonstrated ?50% performance restoration over several degradation/regeneration cycles.

Kumar, Pankaj, E-mail: pankaj@mail.nplindia.ernet.in [CSIR-National Physical Laboratory, Dr. K. S. Krishnan Marg, New Delhi 110012 (India); Centre for Organic Electronics, Physics, University of Newcastle, Callaghan NSW-2308 (Australia); Bilen, Chhinder; Zhou, Xiaojing; Belcher, Warwick J.; Dastoor, Paul C., E-mail: Paul.Dastoor@newcastle.edu.au [Centre for Organic Electronics, Physics, University of Newcastle, Callaghan NSW-2308 (Australia); Feron, Krishna [Centre for Organic Electronics, Physics, University of Newcastle, Callaghan NSW-2308 (Australia); CSIRO Energy Technology, P. O. Box 330, Newcastle NSW 2300 (Australia)

2014-05-12T23:59:59.000Z

386

Ultrafast Graphene Oxide Humidity Sensors  

Science Journals Connector (OSTI)

Ultrafast Graphene Oxide Humidity Sensors ... Graphene oxide can be exploited in humidity and temperature sensors with a number of convenient features such as flexibility, transparency and suitability for large-scale manufacturing. ... Here we show that the two-dimensional nature of graphene oxide and its superpermeability to water combine to enable humidity sensors with unprecedented response speed (?30 ms response and recovery times). ...

Stefano Borini; Richard White; Di Wei; Michael Astley; Samiul Haque; Elisabetta Spigone; Nadine Harris; Jani Kivioja; Tapani Ryhänen

2013-11-09T23:59:59.000Z

387

Doped palladium containing oxidation catalysts  

DOE Patents (OSTI)

A supported oxidation catalyst includes a support having a metal oxide or metal salt, and mixed metal particles thereon. The mixed metal particles include first particles including a palladium compound, and second particles including a precious metal group (PMG) metal or PMG metal compound, wherein the PMG metal is not palladium. The oxidation catalyst may also be used as a gas sensor.

Mohajeri, Nahid

2014-02-18T23:59:59.000Z

388

Underground Coal Thermal Treatment  

SciTech Connect

The long-term objective of this work is to develop a transformational energy production technology by insitu thermal treatment of a coal seam for the production of substitute natural gas (SNG) while leaving much of the coalâ??s carbon in the ground. This process converts coal to a high-efficiency, low-GHG emitting gas fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This topical report discusses the development of experimental capabilities, the collection of available data, and the development of simulation tools to obtain process thermo-chemical and geo-thermal parameters in preparation for the eventual demonstration in a coal seam. It also includes experimental and modeling studies of CO{sub 2} sequestration. Efforts focused on: â?¢ Constructing a suite of three different coal pyrolysis reactors. These reactors offer the ability to gather heat transfer, mass transfer and kinetic data during coal pyrolysis under conditions that mimic in situ conditions (Subtask 6.1). â?¢ Studying the operational parameters for various underground thermal treatment processes for oil shale and coal and completing a design matrix analysis for the underground coal thermal treatment (UCTT). This analysis yielded recommendations for terms of targeted coal rank, well orientation, rubblization, presence of oxygen, temperature, pressure, and heating sources (Subtask 6.2). â?¢ Developing capabilities for simulating UCTT, including modifying the geometry as well as the solution algorithm to achieve long simulation times in a rubblized coal bed by resolving the convective channels occurring in the representative domain (Subtask 6.3). â?¢ Studying the reactive behavior of carbon dioxide (CO{sub 2}) with limestone, sandstone, arkose (a more complex sandstone) and peridotite, including mineralogical changes and brine chemistry for the different initial rock compositions (Subtask 6.4). Arkose exhibited the highest tendency of participating in mineral reactions, which can be attributed to the geochemical complexity of its initial mineral assemblage. In experiments with limestone, continuous dissolution was observed with the release of CO{sub 2} gas, indicated by the increasing pressure in the reactor (formation of a gas chamber). This occurred due to the lack of any source of alkali to buffer the solution. Arkose has the geochemical complexity for permanent sequestration of CO{sub 2} as carbonates and is also relatively abundant. The effect of including NH{sub 3} in the injected gas stream was also investigated in this study. Precipitation of calcite and trace amounts of ammonium zeolites was observed. A batch geochemical model was developed using Geochemists Workbench (GWB). Degassing effect in the experiments was corrected using the sliding fugacity model in GWB. Experimental and simulation results were compared and a reasonable agreement between the two was observed.

P. Smith; M. Deo; E. Eddings; A. Sarofim; K. Gueishen; M. Hradisky; K. Kelly; P. Mandalaparty; H. Zhang

2011-10-30T23:59:59.000Z

389

Thermally induced photon splitting  

E-Print Network (OSTI)

We calculate thermal corrections to the non-linear QED effective action for low-energy photon interactions in a background electromagnetic field. The high-temperature expansion shows that at $T \\gg m$ the vacuum contribution is exactly cancelled to all orders in the external field except for a non-trivial two-point function contribution. The high-temperature expansion derived reveals a remarkable cancellation of infrared sensitive contributions. As a result photon-splitting in the presence of a magnetic field is suppressed in the presence of an electron-positron QED-plasma at very high temperatures. In a cold and dense plasma a similar suppression takes place. At the same time Compton scattering dominates for weak fields and the suppression is rarely important in physical situations.

Per Elmfors; Bo-Sture Skagerstam

1998-02-23T23:59:59.000Z

390

Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants  

E-Print Network (OSTI)

OF CALIFORNIA RIVERSIDE Phase Change Materials for ThermalOF THE THESIS Phase Change Materials for Thermal Energyto utilize phase change materials (PCM’s) to enhance thermal

Hardin, Corey Lee

2011-01-01T23:59:59.000Z

391

Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants  

E-Print Network (OSTI)

PHASE CHANGE THERMAL ENERGY STORAGE FOR CONCENTRATING SOLARChange Materials for Thermal Energy Storage in ConcentratedChange Materials for Thermal Energy Storage in Concentrated

Hardin, Corey Lee

2011-01-01T23:59:59.000Z

392

Graphene and Graphene Oxide: Biofunctionalization and Applications...  

NLE Websites -- All DOE Office Websites (Extended Search)

and Graphene Oxide: Biofunctionalization and Applications in Biotechnology. Graphene and Graphene Oxide: Biofunctionalization and Applications in Biotechnology. Abstract: Graphene...

393

Emergent Phenomena at Oxide Interfaces  

SciTech Connect

Transition metal oxides (TMOs) are an ideal arena for the study of electronic correlations because the s-electrons of the transition metal ions are removed and transferred to oxygen ions, and hence the strongly correlated d-electrons determine their physical properties such as electrical transport, magnetism, optical response, thermal conductivity, and superconductivity. These electron correlations prohibit the double occupancy of metal sites and induce a local entanglement of charge, spin, and orbital degrees of freedom. This gives rise to a variety of phenomena, e.g., Mott insulators, various charge/spin/orbital orderings, metal-insulator transitions, multiferroics, and superconductivity. In recent years, there has been a burst of activity to manipulate these phenomena, as well as create new ones, using oxide heterostructures. Most fundamental to understanding the physical properties of TMOs is the concept of symmetry of the order parameter. As Landau recognized, the essence of phase transitions is the change of the symmetry. For example, ferromagnetic ordering breaks the rotational symmetry in spin space, i.e., the ordered phase has lower symmetry than the Hamiltonian of the system. There are three most important symmetries to be considered here. (i) Spatial inversion (I), defined as r {yields} -r. In the case of an insulator, breaking this symmetry can lead to spontaneous electric polarization, i.e. ferroelectricity, or pyroelectricity once the point group belongs to polar group symmetry. (ii) Time-reversal symmetry (T) defined as t {yields} -t. In quantum mechanics, the time-evolution of the wave-function {Psi} is given by the phase factor e{sup -iEt/{h_bar}} with E being the energy, and hence time-reversal basically corresponds to taking the complex conjugate of the wave-function. Also the spin, which is induced by the 'spinning' of the particle, is reversed by time-reversal. Broken T-symmetry is most naturally associated with magnetism, since the spin operator changes sign with T-operation. (iii) Gauge symmetry (G), which is associated with a change in the phase of the wave-function as {Psi} {yields} e{sup i{theta}}{Psi}. Gauge symmetry is connected to the law of charge conservation, and broken G-symmetry corresponds to superconductivity/superfluidity. To summarize, the interplay among these electronic degrees of freedom produces various forms of symmetry breaking patterns of I, T, and G, leading to novel emergent phenomena, which can appear only by the collective behavior of electrons and cannot be expected from individual electrons. Figure 1 shows this schematically by means of several representative phenomena. From this viewpoint, the interfaces of TMOs offer a unique and important laboratory because I is already broken by the structure itself, and the detailed form of broken I-symmetry can often be designed. Also, two-dimensionality usually enhances the effects of electron correlations by reducing their kinetic energy. These two features of oxide interfaces produce many novel effects and functions that cannot be attained in bulk form. Given that the electromagnetic responses are a major source of the physical properties of solids, and new gauge structures often appear in correlated electronic systems, we put 'emergent electromagnetism' at the center of Fig. 1.

Hwang, H.Y.

2012-02-16T23:59:59.000Z

394

Microsoft PowerPoint - Baker_IPRC_2012-Oxide_Reduction_v2 [Compatibility Mode]  

NLE Websites -- All DOE Office Websites (Extended Search)

a a kg-Scale Oxide Reduction Module for Spent Light Water Reactor Fuel 2012 International Pyroprocessing Research Conference Fontana, Wisconsin, USA August 26 - 29, 2012 Clint Baker, Tom M Pfeiffer, Steven D Herrmann - Idaho National Laboratory Sung B Park, Si-Hyung Kim - Korea Atomic Energy Research Institute Overview  Background / Motivation  Challenges Faced - Design - Operating Environment  Major System Features  Design Details of Subassemblies  Thermal Analysis Results 2 International Pyroprocessing Research Conference August 26-29, 2012 Background / Motivation  Evaluate the recycling of used LWR oxide fuels via electrochemical technologies  Produce metallic fuel from used oxide fuel (to enable subsequent electrorefining) 3 International Pyroprocessing Research Conference August 26-29, 2012 Electrolytic Oxide Reduction  Oxide

395

Transformation of carbon monoxide dimer surface structures on yttrium oxide modified by silver  

SciTech Connect

It has been established that introducing ions of silver(II) in yttrium(III) oxide leads to the formation of a significant concentration of a paramagnetic dimer species (CO)/sub 2/-in the course of the adsorption of carbon monoxide, and that these dimers exhibit high thermal stability and reactivity. Reactions are proposed for the formation of the dimer species (CO)/sub 2//sup 2 -/ and (CO)/sub 2//sup -/ on the surface of the Ag/Y/sub 2/O/sub 3/ catalyst that involve the reduction of the anion vacancies and a change in the oxidation state of the silver ions. Modifying the yttrium oxide with ionic silver leads to a marked decrease in the strength of the oxidative ability of the surface of the catalyst for CO, while the nature of the active sites of the yttrium oxide, which adsorbs CO in three forms, remains unchanged.

Vydrin, S.N.; Bobolev, A.V.; Loginov, A.Yu.

1987-09-10T23:59:59.000Z

396

Innovative Powder Processing of Oxide Dispersion Strengthened ODS Ferritic Stainless Steels  

SciTech Connect

An innovative gas atomization reaction synthesis technique was employed as a viable method to dramatically lower the processing cost for precursor oxide dispersion forming ferritic stainless steel powders (i.e., Fe-Cr-(Hf,Ti)-Y). During this rapid solidification process the atomized powders were enveloped by a nano-metric Cr-enriched metastable oxide film. Elevated temperature heat treatment was used to dissociate this metastable oxide phase through oxygen exchange reactions with Y-(Hf,Ti) enriched intermetallic compound precipitates. These solid state reactions resulted in the formation of highly stable nano-metric mixed oxide dispersoids (i.e., Y-Ti-O or Y-Hf-O) throughout the alloy microstructure. Subsequent high temperature (1200 C) heat treatments were used to elucidate the thermal stability of each nano-metric oxide dispersoid phase. Transmission electron microscopy coupled with X-ray diffraction was used to evaluate phase evolution within the alloy microstructure.

Rieken, Joel; Anderson, Iver; Kramer, Matthew

2011-04-01T23:59:59.000Z

397

Peg supported thermal insulation panel  

DOE Patents (OSTI)

A thermal insulation panel which is lightweight, load bearing, accommodates thermal stress, and has excellent high temperature insulation capability comprises high performance insulation between thin metal walls supported by high density, high strength glass pegs made in compliance with specified conditions of time, temperature and pressure. 2 figs.

Nowobilski, J.J.; Owens, W.J.

1985-04-30T23:59:59.000Z

398

Peg supported thermal insulation panel  

DOE Patents (OSTI)

A thermal insulation panel which is lightweight, load bearing, accommodates thermal stress, and has excellent high temperature insulation capability comprising high performance insulation between thin metal walls supported by high density, high strength glass pegs made in compliance with specified conditions of time, temperature and pressure.

Nowobilski, Jeffert J. (Orchard Park, NY); Owens, William J. (Kenmore, NY)

1985-01-01T23:59:59.000Z

399

Thermalization of isolated quantum systems  

E-Print Network (OSTI)

Understanding the evolution towards thermal equilibrium of an isolated quantum system is at the foundation of statistical mechanics and a subject of interest in such diverse areas as cold atom physics or the quantum mechanics of black holes. Since a pure state can never evolve into a thermal density matrix, the Eigenstate Thermalization Hypothesis (ETH) has been put forward by Deutsch and Srednicki as a way to explain this apparent thermalization, similarly to what the ergodic theorem does in classical mechanics. In this paper this hypothesis is tested numerically. First, it is observed that thermalization happens in a subspace of states (the Krylov subspace) with dimension much smaller than that of the total Hilbert space. We check numerically the validity of ETH in such a subspace, for a system of hard core bosons on a two-dimensional lattice. We then discuss how well the eigenstates of the Hamiltonian projected on the Krylov subspace represent the true eigenstates. This discussion is aided by bringing the projected Hamiltonian to the tridiagonal form and interpreting it as an Anderson localization problem for a finite one-dimensional chain. We also consider thermalization of a subsystem and argue that generation of a large entanglement entropy can lead to a thermal density matrix for the subsystem well before the whole system thermalizes. Finally, we comment on possible implications of ETH in quantum gravity.

Sergei Khlebnikov; Martin Kruczenski

2014-03-12T23:59:59.000Z

400

Biogas fuel reforming for solid oxide fuel cells  

Science Journals Connector (OSTI)

In this paper strategies for biogas reforming and their ensuing effects on solid oxide fuel cell(SOFC) performance are explored. Synthesized biogas (65% CH4?+?35% CO2) fuel streams are reformed over a rhodium catalyst supported on a porous ?-alumina foam. Reforming approaches include steam reforming and catalytic partial oxidation (CPOX) utilizing either air or pure oxygen as the oxidant. A computational model is developed and utilized to guide the specification of reforming conditions that maximize both CH4 and CO2 conversions. Model predictions are validated with experimental measurements over a wide range of biogas-reforming conditions. Higher reforming temperatures are shown to activate the biogas-borne CO2 to enable significant methane dry-reforming chemistry. Dry reforming minimizes the oxidant-addition needs for effective biogas conversion potentially decreasing the thermal requirements for reactant heating and improving system efficiency. Such high-temperature reforming conditions are prevalent during CPOX with a pure-O2 oxidant. While CPOX-with-O2 reforming is highly exothermic the endothermicity of dry-reforming chemistry can be exploited to ensure that catalyst temperatures do not reach levels which cause catalyst sintering and degradation. SOFCelectrochemical performance under biogas reformate is shown to vary substantially with reforming approach. Cell operation under CPOX-with-O2 reformate is found to be comparable to that under humidified hydrogen.

Danielle M. Murphy; Amy E. Richards; Andrew Colclasure; Wade A. Rosensteel; Neal P. Sullivan

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Thermal Conductivity and Noise Attenuation in  

E-Print Network (OSTI)

.3.4 Corrosion-resistant and high-temperature filters 9 1.3.5 Acoustic Applications 9 2. THERMAL CONDUCTIVITY 2.1 THERMAL RESISTANCE 2.1.1 Thermal Conductors in Series 12 2.1.2 Thermal conductors in parallel 13 2 difference RTH Thermal resistance of conductor sb Stefan's constant T4 Temperature difference K* Total

Cambridge, University of

402

Nanoscale Thermal Transport andMicrorefrigeratorsonaChip  

E-Print Network (OSTI)

are promising candidates as thermal vias and thermal interface materials due to their inherently high thermal; superlattices; thermal boundary resistance; thermionics; thermotunneling; thermoelectrics I. INTRODUCTIONINVITED P A P E R Nanoscale Thermal Transport andMicrorefrigeratorsonaChip Devices for cooling high

403

Influence of a Cerium surface treatment on the oxidation behavior of type 347 stainless steel  

SciTech Connect

A surface treatment was applied to the surface of Type 347 stainless steel to enhance oxidation resistance. The treatment consisted of dip coating coupons in a CeO2 and halide activator slurry, followed by a thermal treatment at 900C in an inert atmosphere for 12 hours. Cyclical oxidation tests were conducted at 800C in either dry air or air+3%H2O. In dry air, the treatment reduced the oxidation rate (reduced the magnitude of weight gain) of the alloy by a factor of three. Protective chromium based oxide and spinel ((Mn,Cr)3O4 and (Cr,Fe)2O3) phases formed on the surface of the untreated and treated alloy. More significantly, the treatment suppressed the oxide scale spallation that occurred upon cyclical exposure of this alloy to moist air. In moist air, less protective chromite (FeCr2O4), magnetite (Fe+2Fe2+3O4), and hematite (Fe2O3) formed as oxide products on the surface of the base alloy. The treated alloy did not spall during exposure to moist air, and interestingly, the treated alloy possessed similar oxidation rates (magnitude of weight gain) in both moist and dry air. The same protective chromium based oxide and spinel ((Mn,Cr)3O4 and (Cr,Fe)2O3) phases formed on the surface of the treated alloy exposed to both moist and dry air. In the aggressive moist environment, the Ce surface treatment suppressed the formation of less protective iron-oxides, and concomitant oxide scale spallation during thermal cycling.

Alman, D.E.; Jablonski, P.D.

2007-04-01T23:59:59.000Z

404

Thermal Degradation Studies of A Polyurethane Propellant Binder  

SciTech Connect

The thermal oxidative aging of a crosslinked hydroxy-terminated polybutadiene (HTPB)/isophorone diisocyanate (IPDI) based polyurethane rubber, used as a polymeric binder in solid propellant grain, was investigated at temperatures from 25 C to 125 C. The changes in tensile elongation, polymer network properties and chain dynamics, mechanical hardening and density were determined with a range of techniques including modulus profiling, solvent swelling, NMR relaxation and O{sub 2} permeability measurements. We critically evaluated the Arrhenius methodology that is commonly used with a linear extrapolation of high temperature aging data using extensive data superposition and highly sensitive oxygen consumption experiments. The effects of other constituents in the propellant formulation on aging were also investigated. We conclude that crosslinking is the dominant process at higher temperatures and that the degradation involves only limited hardening in the bulk of the material. Significant curvature in the Arrhenius diagram of the oxidation rates was observed. This is similar to results for other rubber materials.

Assink, R.A.; Celina, M.; Gillen, K.T.; Graham, A.C.; Minier, L.M.

1999-06-12T23:59:59.000Z

405

Thermal-performance study of liquid metal fast breeder reactor insulation  

SciTech Connect

Three types of metallic thermal insulation were investigated analytically and experimentally: multilayer reflective plates, multilayer honeycomb composite, and multilayer screens. Each type was subjected to evacuated and nonevacuated conditions, where thermal measurements were made to determine thermal-physical characteristics. A variation of the separation distance between adjacent reflective plates of multilayer reflective plates and multilayer screen insulation was also experimentally studied to reveal its significance. One configuration of the multilayer screen insulation was further selected to be examined in sodium and sodium oxide environments. The emissivity of Type 304 stainless steel used in comprising the insulation was measured by employing infrared technology. A comprehensive model was developed to describe the different proposed types of thermal insulation. Various modes of heat transfer inherent in each type of insulation were addressed and their relative importance compared. Provision was also made in the model to allow accurate simulation of possible sodium and sodium oxide contamination of the insulation. The thermal-radiation contribution to heat transfer in the temperature range of interest for LMFBR's was found to be moderate, and the suppression of natural convection within the insulation was vital in preserving its insulating properties. Experimental data were compared with the model and other published results. Moreover, the three proposed test samples were assessed and compared under various conditions as viable LMFBR thermal insulations.

Shiu, Kelvin K.

1980-09-01T23:59:59.000Z

406

MINIMIZING THE BONDLINE THERMAL RESISTANCE IN THERMAL INTERFACE MATERIALS WITHOUT AFFECTING RELIABILITY  

E-Print Network (OSTI)

MINIMIZING THE BONDLINE THERMAL RESISTANCE IN THERMAL INTERFACE MATERIALS WITHOUT AFFECTING microstructure, and bondline thermal resistance with the tradeoffs between material systems, manufacturability of devices to heat sinks using existing commercial thermal interface materials (TIMs). The present study

Paris-Sud XI, Université de

407

Computational Design and Experimental Validation of New Thermal Barrier Systems  

SciTech Connect

This project (10/01/2010-9/30/2014), “Computational Design and Experimental Validation of New Thermal Barrier Systems”, originates from Louisiana State University (LSU) Mechanical Engineering Department and Southern University (SU) Department of Computer Science. This project will directly support the technical goals specified in DE-FOA-0000248, Topic Area 3: Turbine Materials, by addressing key technologies needed to enable the development of advanced turbines and turbine-based systems that will operate safely and efficiently using coal-derived synthesis gases. In this project, the focus is to develop and implement novel molecular dynamics method to improve the efficiency of simulation on novel TBC materials; perform high performance computing (HPC) on complex TBC structures to screen the most promising TBC compositions; perform material characterizations and oxidation/corrosion tests; and demonstrate our new thermal barrier coating (TBC) systems experimentally under integrated gasification combined cycle (IGCC) environments.

Guo, Shengmin; Yang, Shizhong; Khosravi, Ebrahim

2014-04-01T23:59:59.000Z

408

Thermal Analysis of the SAFKEG Package for Long Term Storage  

SciTech Connect

Interim plutonium storage for up to 10 years in the K-reactor building is currently being planned at Savannah River Site (SRS). SAFKEG package could be used to store Pu metal and oxide (PuO2) in the K-reactor complex with other packagings like 9975. The SAFKEG is designed for carrying Type-B materials across the DOE complex and meets the 10CFR71 requirements. Thermal analyses were performed to ensure that the temperatures of the SAFKEG components will not exceed their temperature limits under the K-reactor storage conditions. Thermal analyses of the SAFKEG packaging with three content configurations using BNFL 3013 outer container (Rocky Flats, SRS bagless transfer cans, and BNFL inner containers) were performed for storage of PuO2 and plutonium metal

NARENDRA, GUPTA

2005-01-10T23:59:59.000Z

409

Thermal to electricity conversion using thermal magnetic properties  

DOE Patents (OSTI)

A system for the generation of Electricity from Thermal Energy using the thermal magnetic properties of a Ferromagnetic, Electrically Conductive Material (FECM) in one or more Magnetic Fields. A FECM is exposed to one or more Magnetic Fields. Thermal Energy is applied to a portion of the FECM heating the FECM above its Curie Point. The FECM, now partially paramagnetic, moves under the force of the one or more Magnetic Fields. The movement of the FECM induces an electrical current through the FECM, generating Electricity.

West, Phillip B [Idaho Falls, ID; Svoboda, John [Idaho Falls, ID

2010-04-27T23:59:59.000Z

410

Analysis of Zinc 65 Contamination after Vacuum Thermal Process  

SciTech Connect

Radioactive contamination with a gamma energy emission consistent with {sup 65}Zn was detected in a glovebox following a vacuum thermal process. The contaminated components were removed from the glovebox and subjected to examination. Selected analytical techniques were used to determine the nature of the precursor material, i.e., oxide or metallic, the relative transferability of the deposit and its nature. The deposit was determined to be borne from natural zinc and was further determined to be deposited as a metallic material from vapor.

Korinko, Paul S.; Tosten, Michael H.

2013-01-01T23:59:59.000Z

411

Black Carbon in the Soil Carbon Cycle: Is it an Oxidation Resistant End-Product?  

E-Print Network (OSTI)

for different materials and combustion temperatures. It is less than 1% for thermally altered biomass at combusBlack Carbon in the Soil Carbon Cycle: Is it an Oxidation Resistant End-Product? Simone resistant product of incomplete combustion, and consists out of a range of combustion products such as char

Fischlin, Andreas

412

Anaerobic methane oxidation in metalliferous hydrothermal sediments: influence on carbon flux and  

E-Print Network (OSTI)

Anaerobic methane oxidation in metalliferous hydrothermal sediments: influence on carbon flux significant sink that regulates methane flux from sediments into the oceans and atmosphere. Here we examine mesophilic to thermophilic AOM in hydro- thermal sediments recovered from the Middle Valley vent field

Girguis, Peter R.

413

Improved irradiances for use in ocean heating, primary production, and photo-oxidation calculations  

E-Print Network (OSTI)

computed by a radiative transfer code that can be used to convert above-surface values in either energy- plankton affect upper-ocean thermal structure via absorption of solar irradiance at visible wavelengthsImproved irradiances for use in ocean heating, primary production, and photo-oxidation calculations

Boss, Emmanuel S.

414

Generating random thermal momenta  

E-Print Network (OSTI)

Generation of random thermal particle momenta is a basic task in many problems, such as microscopic studies of equilibrium and transport properties of systems, or the conversion of a fluid to particles. In heavy-ion physics, the (in)efficiency of the algorithm matters particularly in hybrid hydrodynamics + hadronic transport calculations. With popular software packages, such as UrQMD 3.3p1 or THERMINATOR, it can still take ten hours to generate particles for a single Pb+Pb "event" at the LHC from fluid dynamics output. Below I describe reasonably efficient simple algorithms using the MPC package, which should help speed momentum generation up by at least one order of magnitude. It is likely that this wheel has been reinvented many times instead of reuse, so there may very well exist older and/or better algorithms that I am not aware of (MPC has been around only since 2000). The main goal here is to encourage practitioners to use available efficient routines, and offer a few practical solutions.

Denes Molnar

2012-12-09T23:59:59.000Z

415

Microelectromechanical (MEM) thermal actuator  

DOE Patents (OSTI)

Microelectromechanical (MEM) buckling beam thermal actuators are disclosed wherein the buckling direction of a beam is constrained to a desired direction of actuation, which can be in-plane or out-of-plane with respect to a support substrate. The actuators comprise as-fabricated, linear beams of uniform cross section supported above the substrate by supports which rigidly attach a beam to the substrate. The beams can be heated by methods including the passage of an electrical current through them. The buckling direction of an initially straight beam upon heating and expansion is controlled by incorporating one or more directional constraints attached to the substrate and proximal to the mid-point of the beam. In the event that the beam initially buckles in an undesired direction, deformation of the beam induced by contact with a directional constraint generates an opposing force to re-direct the buckling beam into the desired direction. The displacement and force generated by the movement of the buckling beam can be harnessed to perform useful work, such as closing contacts in an electrical switch.

Garcia, Ernest J. (Albuquerque, NM); Fulcher, Clay W. G. (Sandia Park, NM)

2012-07-31T23:59:59.000Z

416

Developing a High Thermal Conductivity Fuel with Silicon Carbide Additives  

SciTech Connect

The objective of this research is to increase the thermal conductivity of uranium oxide (UO{sub 2}) without significantly impacting its neutronic properties. The concept is to incorporate another high thermal conductivity material, silicon carbide (SiC), in the form of whiskers or from nanoparticles of SiC and a SiC polymeric precursor into UO{sub 2}. This is expected to form a percolation pathway lattice for conductive heat transfer out of the fuel pellet. The thermal conductivity of SiC would control the overall fuel pellet thermal conductivity. The challenge is to show the effectiveness of a low temperature sintering process, because of a UO{sub 2}-SiC reaction at 1,377°C, a temperature far below the normal sintering temperature. Researchers will study three strategies to overcome the processing difficulties associated with pore clogging and the chemical reaction of SiC and UO{sub 2} at temperatures above 1,300°C:

Ronald baney; James Tulenko

2012-11-20T23:59:59.000Z

417

THERMAL ENERGY STORAGE IN AQUIFERS WORKSHOP  

E-Print Network (OSTI)

and J. Schwarz, Survey of Thermal Energy Storage in AquifersLow Temperature Thermal Energy Storage Program of Oak RidgeAquifers for Seasonal Thermal Energy Storage: An Overview of

Authors, Various

2011-01-01T23:59:59.000Z

418

Advanced nanofabrication of thermal emission devices  

E-Print Network (OSTI)

Nanofabricated thermal emission devices can be used to modify and modulate blackbody thermal radiation. There are many areas in which altering thermal radiation is extremely useful, especially in static power conversion, ...

Hurley, Fergus (Fergus Gerard)

2008-01-01T23:59:59.000Z

419

Ceramic thermal barrier coating for rapid thermal cycling applications  

DOE Patents (OSTI)

A thermal barrier coating for metal articles subjected to rapid thermal cycling includes a metallic bond coat deposited on the metal article, at least one MCrAlY/ceramic layer deposited on the bond coat, and a ceramic top layer deposited on the MCrAlY/ceramic layer. The M in the MCrAlY material is Fe, Ni, Co, or a mixture of Ni and Co. The ceramic in the MCrAlY/ceramic layer is mullite or Al.sub.2 O.sub.3. The ceramic top layer includes a ceramic with a coefficient of thermal expansion less than about 5.4.times.10.sup.-6 .degree.C.sup.-1 and a thermal conductivity between about 1 J sec.sup.-1 m.sup.-1 .degree.C.sup.-1 and about 1.7 J sec.sup.-1 m.sup.-1 .degree.C.sup.-1.

Scharman, Alan J. (Hebron, CT); Yonushonis, Thomas M. (Columbus, IN)

1994-01-01T23:59:59.000Z

420

Recycling of wasted energy : thermal to electrical energy conversion  

E-Print Network (OSTI)

heat source can be solar thermal energy, biological thermaland concentrated solar thermal energy farms. They demandsources include solar thermal energy, geo-thermal energy,

Lim, Hyuck

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Thermoelectrics Combined with Solar Concentration for Electrical and Thermal Cogeneration  

E-Print Network (OSTI)

significant challenge for solar thermal energy generation issolar thermal, cogeneration of electrical and thermal energy,for efficient energy production. Solar thermal plants, such

Jackson, Philip Robert

2012-01-01T23:59:59.000Z

422

Oxidation resistant alloys, method for producing oxidation resistant alloys  

DOE Patents (OSTI)

A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800.degree. C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800.degree. C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700.degree. C. at a low cost

Dunning, John S. (Corvallis, OR); Alman, David E. (Salem, OR)

2002-11-05T23:59:59.000Z

423

Oxidation resistant alloys, method for producing oxidation resistant alloys  

DOE Patents (OSTI)

A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800 C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800 C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700 C. at a low cost

Dunning, John S.; Alman, David E.

2002-11-05T23:59:59.000Z

424

Thermal coatings for titanium-aluminum alloys  

SciTech Connect

Titanium aluminides and titanium alloys are candidate materials for use in hot structure and heat-shield components of hypersonic vehicles because of their good strength-to-weight characteristics at elevated temperature. However, in order to utilize their maximum temperature capability, they must be coated to resist oxidation and to have a high total remittance. Also, surface catalysis for recombination of dissociated species in the aerodynamic boundary layer must be minimized. Very thin chemical vapor deposition (CVD) coatings are attractive candidates for this application because of durability and very light weight. To demonstrate this concept, coatings of boron-silicon and aluminum-boron-silicon compositions were applied to the titanium-aluminides alpha2 (Ti-14Al-21Nb), super-alpha2 (Ti-14Al-23-Nb-2V), and gamma (Ti-33Al-6Nb-1Ta) and to the titanium alloy beta-21S (Ti-15Mo-3Al-3Nb-0.2Si). Coated specimens of each alloy were subjected to a set of simulated hypersonic vehicle environmental tests to determine their properties of oxidation resistance, surface catalysis, radiative emittance, and thermal shock resistance. Surface catalysis results should be viewed as relative performance only of the several coating-alloy combinations tested under the specific environmental conditions of the LaRC Hypersonic Materials Environmental Test System (HYMETS) arc-plasma-heated hypersonic wind tunnel. Tests were also conducted to evaluate the hydrogen transport properties of the coatings and any effects of the coating processing itself on fatigue life of the base alloys. Results are presented for three types of coatings, which are as follows: (1) a single layer boron silicon coating, (2) a single layer aluminum-boron-silicon coating, and (3) a multilayer coating consisting of an aluminum-boron-silicon sublayer with a boron-silicon outer layer.

Cunnington, G.R.; Clark, R.K.; Robinson, J.C.

1993-04-01T23:59:59.000Z

425

Thermal Conversion Process (TCP) Technology  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Changing World Technologies' Changing World Technologies' Thermal Conversion Process Commercial Demonstration Plant DOE/EA 1506 Weld County, Colorado December 2004 U.S. DEPARTMENT OF ENERGY GOLDEN FIELD OFFICE 1617 Cole Boulevard Golden, Colorado 80401 Thermal Conversion Process (TCP) Technology Commercial Demonstration - Weld County, CO TABLE OF CONTENTS Environmental Assessment Thermal Conversion Process (TCP) Technology Commercial Demonstration Project Weld County, Colorado SUMMARY............................................................................................................................. S-1 1.0 INTRODUCTION.........................................................................................................1-1 1.1. National Environmental Policy Act and Related Procedures...........................1-1

426

Tunneling oxide engineering by ion implantation of nitrogen for 3D vertical silicon pillar SONOS flash memory  

Science Journals Connector (OSTI)

The electrical characteristics of silicon-oxide-nitride-oxide-silicon (SONOS) flash memory with a 3D vertical silicon pillar structure were studied. As an alternative method for the formation of the tunneling oxide, nitrogen ion implantation was applied to thermally grown pure silicon dioxide with a low energy (5 keV). The devices show significant improvement in the erase characteristics compared to conventional tunneling oxide. Secondary ion mass spectrometry was used to analyze the nitrogen distribution within tunnel oxide, and the improved erase properties can be attributed to the incorporation of about 4.8% nitrogen (2 × 1021 atoms/cm3) into the tunnel oxide formed by nitrogen ion implantation.

Jae-Sub Oh; Seong-Dong Yang; Sang-Youl Lee; Young-Su Kim; Min-Ho Kang; Sung-Kyu Lim; Hi-Deok Lee; Ga-Won Lee

2013-01-01T23:59:59.000Z

427

MHD oxidant intermediate temperature ceramic heater study. Final report  

SciTech Connect

The use of three types of directly fired ceramic heaters for preheating oxygen enriched air to an intermediate temperature of 1144K was investigated. The three types of ceramic heaters are: (1) a fixed bed, periodic flow ceramic brick regenerative heater (2) a ceramic pebble regenerative heater. The heater design, performance and operating characteristics under conditions in which the particulate matter is not solidified are evaluated. A comparison and overall evaluation of the three types of ceramic heaters and temperature range determination at which the particulate matter in the MHD exhaust gas is estimated to be a dry powder are presented.

Carlson, A.W.; Chait, I.L.; Saari, D.P.; Marksberry, C.L.

1981-09-01T23:59:59.000Z

428

REACTOR GROUT THERMAL PROPERTIES  

SciTech Connect

Savannah River Site has five dormant nuclear production reactors. Long term disposition will require filling some reactor buildings with grout up to ground level. Portland cement based grout will be used to fill the buildings with the exception of some reactor tanks. Some reactor tanks contain significant quantities of aluminum which could react with Portland cement based grout to form hydrogen. Hydrogen production is a safety concern and gas generation could also compromise the structural integrity of the grout pour. Therefore, it was necessary to develop a non-Portland cement grout to fill reactors that contain significant quantities of aluminum. Grouts generate heat when they set, so the potential exists for large temperature increases in a large pour, which could compromise the integrity of the pour. The primary purpose of the testing reported here was to measure heat of hydration, specific heat, thermal conductivity and density of various reactor grouts under consideration so that these properties could be used to model transient heat transfer for different pouring strategies. A secondary purpose was to make qualitative judgments of grout pourability and hardened strength. Some reactor grout formulations were unacceptable because they generated too much heat, or started setting too fast, or required too long to harden or were too weak. The formulation called 102H had the best combination of characteristics. It is a Calcium Alumino-Sulfate grout that contains Ciment Fondu (calcium aluminate cement), Plaster of Paris (calcium sulfate hemihydrate), sand, Class F fly ash, boric acid and small quantities of additives. This composition afforded about ten hours of working time. Heat release began at 12 hours and was complete by 24 hours. The adiabatic temperature rise was 54 C which was within specification. The final product was hard and displayed no visible segregation. The density and maximum particle size were within specification.

Steimke, J.; Qureshi, Z.; Restivo, M.; Guerrero, H.

2011-01-28T23:59:59.000Z

429

Materials Selection Considerations for Thermal Process Equipment...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Materials Selection Considerations for Thermal Process Equipment: A BestPractices Process Heating Technical Brief Materials Selection Considerations for Thermal Process Equipment:...

430

NREL: Energy Systems Integration Facility - Thermal Distribution...  

NLE Websites -- All DOE Office Websites (Extended Search)

thermal distribution bus consists of a thermal water loop connected to a research boiler and chiller that provide precise and efficient control of the water temperature...

431

Integrated External Aerodynamic and Underhood Thermal Analysis...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

External Aerodynamic and Underhood Thermal Analysis for Heavy Vehicles Integrated External Aerodynamic and Underhood Thermal Analysis for Heavy Vehicles 2012 DOE Hydrogen and Fuel...

432

Continuous Processing of High Thermal Conductivity Polyethylene...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Processing of High Thermal Conductivity Polyethylene Fibers and Sheets Continuous Processing of High Thermal Conductivity Polyethylene Fibers and Sheets Massachusetts Institute of...

433

Electric Motor Thermal Management | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Peer Evaluation Meeting ape030bennion2012o.pdf More Documents & Publications Electric Motor Thermal Management Electric Motor Thermal Management Vehicle Technologies...

434

Thermal Regenerator Testing | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Thermal Regenerator Testing Thermal Regenerator Testing Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007,...

435

NREL: Energy Storage - Energy Storage Thermal Management  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Storage Thermal Management Infrared image of rectangular battery cell. Infrared thermal image of a lithium-ion battery cell with poor terminal design. Graph of relative...

436

Solar Thermal Process Heat | Open Energy Information  

Open Energy Info (EERE)

Solar Thermal Process Heat Incentives Retrieved from "http:en.openei.orgwindex.php?titleSolarThermalProcessHeat&oldid267198" Category: Articles with outstanding TODO tasks...

437

OCEAN THERMAL ENERGY CONVERSION PROGRAMMATIC ENVIRONMENTAL ASSESSMENT  

E-Print Network (OSTI)

Ocean Thermal Energy Conversion (OTEC) Draft Programmaticof ocean thermal energy conversion technology. U.S. Depart~on Ocean TherUial Energy Conversion, June 18, 1979. Ocean

Sands, M.Dale

2013-01-01T23:59:59.000Z

438

Laser Texturing for Solar Thermal Systems  

Science Journals Connector (OSTI)

High solar absorptance and low thermal emittance is desired for absorber surface in solar thermal systems. Molybdenum surface was textured by pulsed fiber laser and...

Shah, Ankit; Gupta, Mool

439

Solar Keymark Testing of Solar Thermal Products  

Science Journals Connector (OSTI)

The Solar Keymark is the official CEN certification scheme for thermal solar collectors and factory made thermal solar systems. The Solar Keymark requires that the products fulfil the...

Harald Drück; Stephan Fischer…

2009-01-01T23:59:59.000Z

440

Thermal-Mechanical Technologies | Argonne National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermal-Mechanical Technologies Thermal-Mechanical Technologies Heat management plays a critical role in almost all energy-related applications. Research topics in this area...

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Power Electronic Thermal System Performance and Integration ...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Power Electronic Thermal System Performance and Integration Power Electronic Thermal System Performance and Integration 2009 DOE Hydrogen Program and Vehicle Technologies Program...

442

Investigation of the stability of paraffin-exfoliated graphite nanoplatelet composites for latent heat thermal storage systems  

SciTech Connect

Organic materials, such as paraffin wax, are sought as stable and environmentally friendly phase change materials (PCM) for thermal energy storage, but they suffer from low thermal conductivity which limits the rate at which thermal energy flows into and out of the material. A common method to improve the PCM thermal behavior is through loading with high thermal conductivity particulate fillers. However, the stability of these composites in the molten state is a concern as settling of the fillers will change the effective thermal conductivity. In this work, we investigate the stability of wax loaded with exfoliated graphite nanoplatelets either of 1 m (xGnP-1) or 15 m (xGnP-15) diameter. The effect of dispersants, oxidation of the wax, viscosity of the wax, mixing time, and hydrocarbon chain length on stability is reported. It was found that the addition of octadecylphosphonic acid (ODPA) is an effective dispersant for xGnP in paraffin and microcrystalline wax. In addition, mixing time, viscosity, and oxidation of the wax influence stability in the molten state. Overall, it was found that a mixing time of 24 hours for xGnP-15 along with ODPA mixed in a high viscosity, oxidized microcrystalline wax results in composite PCM systems with the greatest stability determined at 80 C in the molten state.

Abdelaziz, Omar [ORNL; Mallow, Anne [Georgia Institute of Technology; Graham, Samuel [Georgia Institute of Technology; Kalaitzidou, Kyriaki [Georgia Institute of Technology

2012-01-01T23:59:59.000Z

443

Thermal Shock Resistance (TSR) and Thermal Fatigue Resistance (TFR) of Refractory Materials. Evaluation Method Based on the Dynamic Elastic Modulus  

Science Journals Connector (OSTI)

The importance of the thermal shock resistance (TSR) of refractory material is discussed. Understanding the evolution of thermal ... undergo repeated thermal cycling. The thermal fatigue resistance (TFR) behavior...

Nicolás M. Rendtorff; Esteban F. Aglietti

2014-01-01T23:59:59.000Z

444

Mixed Waste Focus Area alternative oxidation technologies development and demonstration program  

SciTech Connect

The Mixed Waste Focus Area (MWFA) is currently supporting the development and demonstration of several alternative oxidation technology (AOT) processes for treatment of combustible mixed low-level wastes. The impetus for this support derives from regulatory and political hurdles frequently encountered by traditional thermal techniques, primarily incinerators. AOTs have been defined as technologies that destroy organic material without using open-flame reactions. Whether thermal or nonthermal, the processes have the potential advantages of relatively low-volume gaseous emissions, generation of few or no dioxin/furan compounds, and operation at low enough temperatures that metals (except mercury) and most radionuclides are not volatilized. Technology development and demonstration are needed to confirm and realize the potential of AOTs and to compare them on an equal basis with their fully demonstrated thermal counterparts. AOTs include both thermal and nonthermal processes that oxidize organic wastes but operate under significantly different physical and chemical conditions than incinerators. Nonthermal processes currently being studied include Delphi DETOX and acid digestion at the Savannah River Site, and direct chemical oxidation at Lawrence Livermore National Laboratory. All three technologies are at advanced stages of development or are entering the demonstration phase. Nonflame thermal processes include catalytic chemical oxidation, which is being developed and deployed at Lawrence Berkeley National Laboratory, and team reforming, a commercial process being supported by Department of Energy. Related technologies include two low-flow, secondary oxidation processes (Phoenix and Thermatrix units) that have been tested at MSE, Inc., in Butte, Montana. Although testing is complete on some AOT technologies, most require additional support to complete some or all of the identified development objectives. Brief descriptions, status, and planned paths forward for each of the technologies are presented.

Borduin, L.C. [Los Alamos National Lab., NM (United States); Fewell, T.; Gombert, D.; Priebe, S. [Lockheed Martin Idaho Technologies Co., Idaho Falls, ID (United States)

1998-07-01T23:59:59.000Z

445

Domestic Heating and Thermal Insulation  

Science Journals Connector (OSTI)

... DIGEST 133 of the Building Research Station, entitled "Domestic Heating and Thermal Insulation" (Pp. 7. London : H.M. Stationery Office, 1960. 4insulation, the standard of heating, the ventilation-rate and the length of the heating season ...

1960-09-17T23:59:59.000Z

446

Thermal Insulation for Energy Conservation  

Science Journals Connector (OSTI)

The use of thermal insulations to reduce heat flow across the building ... decades. Materials available for use as building insulation include naturally occurring fibers and particles, man ... plastics, evacuated...

Dr. David W. Yarbrough Ph.D.; PE

2012-01-01T23:59:59.000Z

447

Thermal Solar Power Plants Experience  

Science Journals Connector (OSTI)

In parallel with rising interest in solar power generation, several solar thermal facilities of different configuration and size were ... were designed as modest-size experimental or prototype solar power plants ...

W. Grasse; H. P. Hertlein; C.-J. Winter; G. W. Braun

1991-01-01T23:59:59.000Z

448

Anodic oxidation of zircaloy-2  

Science Journals Connector (OSTI)

The anodic polarization of zircaloy-2 in different electrolytic baths has been investigated in order to obtain thick oxide films with properties suitable for wear applications.

A. Conte; A. Borello; A. Cabrini

1976-07-01T23:59:59.000Z

449

Thermal Batteries for Electric Vehicles  

SciTech Connect

HEATS Project: UT Austin will demonstrate a high-energy density and low-cost thermal storage system that will provide efficient cabin heating and cooling for EVs. Compared to existing HVAC systems powered by electric batteries in EVs, the innovative hot-and-cold thermal batteries-based technology is expected to decrease the manufacturing cost and increase the driving range of next-generation EVs. These thermal batteries can be charged with off-peak electric power together with the electric batteries. Based on innovations in composite materials offering twice the energy density of ice and 10 times the thermal conductivity of water, these thermal batteries are expected to achieve a comparable energy density at 25% of the cost of electric batteries. Moreover, because UT Austin’s thermal energy storage systems are modular, they may be incorporated into the heating and cooling systems in buildings, providing further energy efficiencies and positively impacting the emissions of current building heating/cooling systems.

None

2011-11-21T23:59:59.000Z

450

Operation of staged membrane oxidation reactor systems  

SciTech Connect

A method of operating a multi-stage ion transport membrane oxidation system. The method comprises providing a multi-stage ion transport membrane oxidation system with at least a first membrane oxidation stage and a second membrane oxidation stage, operating the ion transport membrane oxidation system at operating conditions including a characteristic temperature of the first membrane oxidation stage and a characteristic temperature of the second membrane oxidation stage; and controlling the production capacity and/or the product quality by changing the characteristic temperature of the first membrane oxidation stage and/or changing the characteristic temperature of the second membrane oxidation stage.

Repasky, John Michael

2012-10-16T23:59:59.000Z

451

Catalytic wet oxidation of phenolic wastes  

E-Print Network (OSTI)

Possible catalyst deactivation problems High capital, low operating Supercritical water oxidation (SCWO) Feasible only at high organic concentra- tions High Fast reaction, complete oxidation Severe reaction conditions, canosion problems... of milder reaction conditions and is much less energy intensive. Thus, catalytic wet oxidation would be an alternative to solvent extraction, supercritical water oxidation, homogeneous oxidation, and incineration. It should also be feasible at low...

Thomas, Brook James

1995-01-01T23:59:59.000Z

452

Creep analysis of solid oxide fuel cell with bonded compliant seal design  

Science Journals Connector (OSTI)

Abstract Solid oxide fuel cell (SOFC) requires good sealant because it works in harsh conditions (high temperature, thermal cycle, oxidative and reducing gas environments). Bonded compliant seal (BCS) is a new sealing method for planar SOFC. It uses a thin foil metal to bond the window frame and cell, achieving the seal between window frame and cell. At high temperature, a comprehensive evaluation of its creep strength is essential for the adoption of BCS design. In order to characterize the creep behavior, the creep induced by thermal stresses in SOFC with BCS design is simulated by finite element method. The results show that the foil is compressed and large thermal stresses are generated. The initial peak thermal stress is located in the thin foil because the foil acts as a spring stores the thermal stresses by elastic and plastic deformation in itself. Serving at high temperature, initial thermal displacement is partially recovered because of the creep relaxation, which becomes a new discovered advantage for BCS design. It predicts that the failures are likely to happen in the middle of the cell edge and BNi-2 filler metal, because the maximum residual displacement and creep strain are located.

Wenchun Jiang; Yucai Zhang; Yun Luo; J.M. Gong; S.T. Tu

2013-01-01T23:59:59.000Z

453

Low Temperature Constrained Sintering of Cerium Gadolinium Oxide Films for Solid Oxide Fuel Cell Applications  

E-Print Network (OSTI)

Temperature Solid Oxide Fuel Cells, In: S.C. Singhal and M.solidoxide.html, Tubular Solid Oxide Fuel Cell Technology,Oxide Films for Solid Oxide Fuel Cell Applications by Jason

Nicholas, Jason.D.

2007-01-01T23:59:59.000Z

454

AVCEM: Advanced Vehicle Cost and Energy Use Model. Overview of AVCEM  

E-Print Network (OSTI)

regenerative braking, battery thermal management, and fuel-the requirements of battery thermal management, and thebattery tray, tie downs, electrical auxiliaries (such as bus bars), thermal

Delucchi, Mark

2005-01-01T23:59:59.000Z

455

AVCEM: Advanced-Vehicle Cost and Energy Use Model  

E-Print Network (OSTI)

regenerative braking, battery thermal management, and fuel-the requirements of battery thermal management, and thebattery tray, tie downs, electrical auxiliaries (such as bus bars), thermal

Delucchi, Mark

2005-01-01T23:59:59.000Z

456

Refractory oxide hosts for a high power, broadly tunable laser with high quantum efficiency and method of making same  

DOE Patents (OSTI)

Refractory oxide crystals having high-quantum efficiency and high thermal stability for use as broadly tunable laser host materials. The crystals are formed by removing hydrogen from a single crystal of the oxide material to a level below about 10/sup 12/ protons per cm/sup 3/ and subsequently thermochemically reducing the oxygen content of the crystal to form sufficient oxygen anion vacancies so that short-lived F/sup +/ luminescence is produced when the crystal is optically excited.

Chen, Yok; Gonzalez, R.

1985-07-03T23:59:59.000Z

457

Refractory oxide hosts for a high power, broadly tunable laser with high quantum efficiency and method of making same  

DOE Patents (OSTI)

Refractory oxide crystals having high-quantum efficiency and high thermal stability for use as broadly tunable laser host materials. The crystals are formed by removing hydrogen from a single crystal of the oxide material to a level below about 10.sup.12 protons per cm.sup.3 and subsequently thermochemically reducing the oxygen content of the crystal to form sufficient oxygen anion vacancies so that short-lived F.sup.+ luminescence is produced when the crystal is optically excited.

Chen, Yok (Oak Ridge, TN); Gonzalez, Roberto (Madrid, ES)

1986-01-01T23:59:59.000Z

458

Superalloys for ultra supercritical steam turbines--oxidation behavior  

SciTech Connect

Goals of the U.S. Department of Energy’s Advanced Power Systems Initiatives include power generation from coal at 60% efficiency, which requires steam conditions of up to 760 °C and 340 atm, so called ultra-supercritical (USC) steam conditions. One of the important materials performance considerations is steam-side oxidation resistance. Evaporation of protective chromia scales is expected to be a primary corrosion mechanism under USC conditions. A methodology to calculate Cr evaporation rates from chromia scales with cylindrical geometries was developed that allows for the effects of CrO2(OH)2 saturation within the gas phase. This approach was combined with Cr diffusion calculations within the alloy (with a constant flux of Cr leaving the alloy from evaporation) to predict Cr concentration profiles as a function of exposure time and to predict the time until the alloy surface concentration of Cr reaches zero. This time is a rough prediction of the time until breakaway oxidation. A hypothetical superheater tube, steam pipe, and high pressure turbine steam path was examined. At the highest temperatures and pressures, the time until breakaway oxidation was predicted to be quite short for the turbine blade, and of concern within the steam pipe and the higher temperature portions of the superheater tube. The predicted time until breakaway oxidation increases dramatically with decreases in temperature and total pressure. Possible mitigation techniques were discussed, including those used in solid oxide fuel cell metallic interconnects (lowering the activity of Cr in the oxide scale by adding Mn to the alloy), and thermal barrier coating use on high pressure turbine blades for both erosion and chromia evaporation protection.

Holcomb, G.R.

2008-09-01T23:59:59.000Z

459

Metal oxide films on metal  

DOE Patents (OSTI)

A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

1995-01-01T23:59:59.000Z

460

Ethylene Oxide for Soil Sterilization  

Science Journals Connector (OSTI)

... , this method may be time-consuming, and in view of the physical properties of ethylene oxide (solubility in water and boiling point 12-5 C.) it was considered ... consists of making up an aqueous solution to supply 2 or 4 c.c. of ethylene oxide in a given amount of water, using pre-chilled glassware and water. The ...

R. E. ROSE; R. W. BAILEY

1952-04-26T23:59:59.000Z

Note: This page contains sample records for the topic "regenerative thermal oxidizer" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Thermal storage module for solar dynamic receivers  

DOE Patents (OSTI)

A thermal energy storage system comprising a germanium phase change material and a graphite container.

Beatty, Ronald L. (Farragut, TN); Lauf, Robert J. (Oak Ridge, TN)

1991-01-01T23:59:59.000Z

462

NUMERICAL DESIGN TOOLS FOR THERMAL REPLICATION OF  

E-Print Network (OSTI)

by heating Ceramic block Glass workpiece before heating Figure 1: Thermal Replication (after Smith et al. [14NUMERICAL DESIGN TOOLS FOR THERMAL REPLICATION OF OPTICAL­QUALITY SURFACES Y.M. Stokes 1 Department. #12; Thermal replication of optical surfaces 1 1 Introduction Thermal replication is an industrial

Stokes, Yvonne

463

Battery Thermal Management System Design Modeling (Presentation)  

SciTech Connect

Presents the objectives and motivations for a battery thermal management vehicle system design study.

Kim, G-H.; Pesaran, A.

2006-10-01T23:59:59.000Z

464

Steamside Oxidation Behavior of Experimental 9%Cr Steels  

SciTech Connect

Reducing emissions and increasing economic competitiveness require more efficient steam power plants that utilize fossil fuels. One of the major challenges in designing these plants is the availability of materials that can stand the supercritical and ultra-supercritical steam conditions at a competitive cost. There are several programs around the world developing new ferritic and austenitic steels for superheater and reheater tubes exposed to the advanced steam conditions. The new steels must possess properties better than current steels in terms of creep strength, steamside oxidation resistance, fireside corrosion resistance, and thermal fatigue resistance. This paper introduces a series of experimental 9%Cr steels containing Cu, Co, and Ti. Stability of the phases in the new steels is discussed and compared to the phases in the commercially available materials. The steels were tested under both the dry and moist conditions at 650ºC for their cyclical oxidation resistance. Results of oxidation tests are presented. Under the moist conditions, the experimental steels exhibited significantly less mass gain compared to the commercial P91 steel. Microstructural characterization of the scale revealed different oxide compositions.

Dogan, O.N.; Holcomb, G.R.; Alman, D.E.; Jablonski, P.D.

2007-10-01T23:59:59.000Z

465

Ultra Supercritical Steamside Oxidation  

SciTech Connect

Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy's Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538 C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620 C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which require steam temperatures of up to 760 C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

Holcomb, Gordon R.; Cramer, Stephen D.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Ziomek-Moroz, Malgorzata

2005-01-01T23:59:59.000Z

466

Design consideration of micro thin film solid-oxide fuel cells  

Science Journals Connector (OSTI)

Miniaturized planar solid-oxide fuel cells (SOFCs) and stacks can be fabricated by thin film deposition and micromachining. Serious thermal stresses, originating in fabrication and during operation, cause thermal–mechanical instability of the constituent thin films. In this paper, the effect of thin film geometry on thermal stress and mechanical stability is evaluated to optimize the structure of a thin film. A novel design of thin circular electrolyte films for SOFCs is presented by using corrugated structures, with which small thermal stresses and a broad design range of structure parameters can be obtained. Thermal transfer analysis shows that heat loss by solid conduction is serious in thin films with a small radius. But thermal convection and radiation dominate heat loss in large thin films with a radius of several millimetres. Scale-dependent thermal characteristics show the importance of film size and packaging in optimization of thermal isolation for micro SOFCs. A novel flip-flop stack configuration for micro SOFCs is presented. This configuration allows multiple cells to share one reaction chamber, helps to obtain uniform flow fields, and simplifies the flow field network for micro fuel cell stacks.

Yanghua Tang; Kevin Stanley; Jonathan Wu; Dave Ghosh; Jiujun Zhang

2005-01-01T23:59:59.000Z

467

Thermal method for fabricating a hydrogen separation membrane on a porous substrate  

DOE Patents (OSTI)

A thermal method of making a hydrogen permeable composition is disclosed. A mixture of metal oxide powder and ceramic oxide powder and optionally a pore former is formed and pressed to form an article. The article is dried at elevated temperatures and then sintered in a reducing atmosphere to provide a dense hydrogen permeable portion near the surface of the sintered mixture. The dense hydrogen permeable portion has a higher initial concentration of metal than the remainder of the sintered mixture and is present in the range of from about 20 to about 80 percent by volume of the dense hydrogen permeable portion.

Song, Sun-Ju (Orland Park, IL); Lee, Tae H. (Naperville, IL); Chen, Ling (Woodridge, IL); Dorris, Stephen E. (LaGrange Park, IL); Balachandran, Uthamalingam (Hinsdale, IL)

2009-10-20T23:59:59.000Z

468

Photochemical oxidation of oxalate in Pu-238 process streams  

SciTech Connect

For over forty years, NASA has relied on plutonium-238 in Radioisotope Thermoelectric Generator (RTG) units and Radioisotope Heater Units ( W s ) to provide power and heat for many space missions including Transit, Pioneer, Viking, Voyager, Galileo, Ulysses and Cassini. RHUs provide heat to keep key components warm in extremely cold environments found on planets, moons, or in deep space. RTGs convert heat generated from the radioactive decay of plutonium-238 into electricity using a themocouple, Plutonium-238 has proven to be an excellent heat source far deep space missions because of its high thermal power density, useful lifetime, minimal shielding requirements, and oxide stability.

Long, K. M. (Kristy M.); Ford, D. K. (Doris K.); Trujillo, L. A. (Leonardo A.)

2003-01-01T23:59:59.000Z

469

Device for thermal transfer and power generation  

DOE Patents (OSTI)

A system is provided. The system includes a device that includes top and bottom thermally conductive substrates positioned opposite to one another, wherein a top surface of the bottom thermally conductive substrate is substantially atomically flat and a thermal blocking layer disposed between the top and bottom thermally conductive substrates. The device also includes top and bottom electrodes separated from one another between the top and bottom thermally conductive substrates to define a tunneling path, wherein the top electrode is disposed on the thermal blocking layer and the bottom electrode is disposed on the bottom thermally conductive substrate.

Weaver, Stanton Earl (Northville, NY); Arik, Mehmet (Niskayuna, NY)

2011-04-19T23:59:59.000Z

470

Thermally unstable complexants: Stability of lanthanide/actinide complexes, thermal instability of the ligands, and applications in actinide separations  

SciTech Connect

Water soluble complexing agents are commonly used in separations to enhance the selectivity of both ion exchange and solvent extraction processes. Applications of this type in the treatment of nuclear wastes using conventional complexing agents have found mixed success due to the nature of the complexants. In addition, the residual solutions containing these species have led to potentially serious complications in waste storage. To overcome some of the limitations of carboxylic acid and aminopolycarboxylate ligands, we have initiated a program to investigate the complexing ability, thermal/oxidative instability, and separation potential of a group of water soluble organophosphorus compounds which we call Thermally Unstable Complexants, or simply TUCS. Complexants of this type appear to be superior to conventional analogues in a number of respects. In this report, we will summarize our research to date on the actinide/lanthanide complexes with a series of substituted methanediphosphonic acids, the kinetics of their oxidative decomposition, and a few applications which have been developed for their use. 17 refs., 5 figs., 3 tab.

Nash, K.L.; Rickert, P.G.

1991-01-01T23:59:59.000Z

471

Nanostructured Solid Oxide Fuel Cell Electrodes  

E-Print Network (OSTI)

post-Doping of Solid Oxide Fuel Cell Cathodes,? P.h.D.and V. I. Birss, in Solid Oxide Fuel Cells (SOFC IX), S. C.Nanostructured Solid Oxide Fuel Cell Electrodes By Tal Zvi

Sholklapper, Tal Zvi

2007-01-01T23:59:59.000Z

472

Detection of oxidation in human serum lipoproteins  

E-Print Network (OSTI)

A method for the oxidation of lipoproteins in vitro was developed using the free radical initiator, 2,2?-azobis-(2-amidinopropane) dihydrochloride (AAPH). Following in vitro oxidation, the susceptibility to oxidation of the serum samples...

Myers, Christine Lee

2006-04-12T23:59:59.000Z

473

Effect of Gadolinium Doping on the Air Oxidation of Uranium Dioxide  

SciTech Connect

Researchers at the Pacific Northwest National Laboratory (PNNL) investigated the effects of gadolinia concentration on the air oxidization of gadolinia-doped uranium dioxide using thermogravimetry and differential scanning calorimetry to determine if such doping could improve uranium dioxide's stability as a nuclear fuel during potential accident scenarios in a nuclear reactor or during long-term disposal. We undertook this study to determine whether the resistance of the uranium dioxide to oxidation to the orthorhombic U3O8 with its attendant crystal expansion could be prevented by addition of gadolinia. Our studies found that gadolinium has little effect on the thermal initiation of the first step of the reported two-step air oxidation of UO2; however, increasing gadolinia content does stabilize the initial tetragonal or cubic product allowing significant oxidation before the second expansive step to U3O8 begins.

Scheele, Randall D.; Hanson, Brady D.; Cumblidge, Stephen E.; Jenson, Evan D.; Kozelisky, Anne E.; Sell, Rachel L.; MacFarlan, Paul J.; Snow, Lanee A.

2004-12-04T23:59:59.000Z

474

High Performance Thermal Interface Technology Overview  

E-Print Network (OSTI)

An overview on recent developments in thermal interfaces is given with a focus on a novel thermal interface technology that allows the formation of 2-3 times thinner bondlines with strongly improved thermal properties at lower assembly pressures. This is achieved using nested hierarchical surface channels to control the particle stacking with highly particle-filled materials. Reliability testing with thermal cycling has also demonstrated a decrease in thermal resistance after extended times with longer overall lifetime compared to a flat interface.

R. Linderman; T. Brunschwiler; B. Smith; B. Michel

2008-01-07T23:59:59.000Z

475

High Performance Thermal Interface Technology Overview  

E-Print Network (OSTI)

An overview on recent developments in thermal interfaces is given with a focus on a novel thermal interface technology that allows the formation of 2-3 times thinner bondlines with strongly improved thermal properties at lower assembly pressures. This is achieved using nested hierarchical surface channels to control the particle stacking with highly particle-filled materials. Reliability testing with thermal cycling has also demonstrated a decrease in thermal resistance after extended times with longer overall lifetime compared to a flat interface.

Linderman, R; Smith, B; Michel, B

2008-01-01T23:59:59.000Z

476

Ultralow thermal conductivity and the thermal d t f i t fconductance of interfaces  

E-Print Network (OSTI)

are critical at the nanoscale · Low thermal conductivity in nanostructured materials ­ improved thermoelectric to the thermal conductivity of materials. · Ultralow thermal conductivity: beating the amorphous limitUltralow thermal conductivity and the thermal d t f i t fconductance of interfaces David G. Cahill

Braun, Paul

477

Cornell University Thermal Comfort Report  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermal Comfort Thermal Comfort Thermal comfort in the CUSD home is a top priority for our team. Accordingly, we designed a redundant HVAC system that would carefully manage the comfort of our decathletes and guests throughout the competition and the life of the house. The CUSD home's HVAC system was optimized for Washington, DC, with the cold Ithaca climate in mind. Our design tools included a schematic energy-modeling interface called TREAT, which was built off of the SuNREL platform. TREAT was used to passively condition the space. Our schematic energy modeling helped us properly size window areas, overhangs, and building mass distribution. We used a computation fluid dynamics (CFD) package called AirPak, to refine our design. The home was modeled in both

478

solar thermal | OpenEI  

Open Energy Info (EERE)

thermal thermal Dataset Summary Description This dataset presents summary information related to world solar energy. It is part of a supporting dataset for the book World On the Edge: How to Prevent Environmental and Economic Collapse by Lester R. Source Earth Policy Institute Date Released January 12th, 2011 (3 years ago) Date Updated Unknown Keywords EU solar solar PV solar thermal world Data application/vnd.ms-excel icon Excel spreadsheet, summary solar energy data on multiple tabs (xls, 145.9 KiB) Quality Metrics Level of Review Some Review Comment Temporal and Spatial Coverage Frequency Time Period License License Open Data Commons Attribution License Comment "Reuse of our data is permitted. We merely ask that wherever it is listed, it be appropriately cited"

479

New manganese catalyst for light alkane oxidation  

DOE Patents (OSTI)

Aluminophosphates containing manganese in the structural framework are employed for the oxidation of alkanes, for example the vapor phase oxidation of methane to methanol.

Durante, Vincent A. (West Chester, PA); Lyons, James E. (Wallingford, PA); Walker, Darrell W. (Visalia, CA); Marcus, Bonita K. (Radnor, PA)

1994-01-01T23:59:59.000Z

480

Sensitivity of 2,6-Diamino-3, 5-Dinitropyrazine-1-Oxide  

SciTech Connect

The thermal and shock sensitivities of plastic bonded explosive formations based on 2,6-diamino-3,5-dinitropyrazine-1-oxide (commonly called LLM-105 for Lawrence Livermore Molecule No.105) are reported. The One Dimensional Time to Explosion (ODTX) apparatus was used to generate times to thermal explosion at various initial temperatures. A four-reaction chemical decomposition model was developed to calculate the time to thermal explosion versus inverse temperature curve. Three embedded manganin pressure gauge experiments were fired at different initial pressures to measure the pressure buildup and the distance required for transition to detonation. An Ignition and Growth reactive model was calibrated to this shock initiation data. LLM-105 exhibited thermal and shock sensitivities intermediate between those of triaminotrinitrobenzene (TATB) and octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazine (HMX).

Tarver, C M; Urtiew, P A; Tran, T D

2005-01-20T23:59:59.000Z

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481

Westinghouse thermal barrier coatings development  

SciTech Connect

Westinghouse, in conjunction with the Department of Energy and Oak Ridge National Laboratory, has embarked upon a program for the development of advanced thermal barrier coatings for industrial gas turbines. Development of thermal barrier coatings (TBC`s) for industrial gas turbines has relied heavily on the transfer of technology from the aerospace industry. Significant differences in the time/temperature/stress duty cycles exist between these two coating applications. Coating systems which perform well in aerospace applications may not been optimized to meet power generation performance requirements. This program will focus on development of TBC`s to meet the specific needs of power generation applications.

Goedjen, J.G.; Wagner, G.

1995-12-31T23:59:59.000Z

482

Effective Thermal Conductivity of Graded Nanocomposites with Interfacial Thermal  

E-Print Network (OSTI)

.M. Yin", G. H. Paulino", W.G. Buttlar", and L.Z. Sun'' '^Department of Civil and Environmental the effective thermal conductivity distribution in functionally graded materials (FGMs) considering the Kapitza is developed to derive the averaged heat flux field of the particle phase. Then the temperature gradient can

Paulino, Glaucio H.

483

Nanoscale thermal transport and the thermal conductance of interfaces  

E-Print Network (OSTI)

-8 2008 #12;Er-fiber laser system, UIUC Nov. 2007 #12;Solid-liquid interfaces: Two approaches · Transient-wide: ­ thermal interface materials ­ so-called "nanofluids" (suspensions in liquids) ­ polymer composites absorption depends on temperature of the nanotube · Assume heat capacity is comparable to graphite · Cooling

Braun, Paul

484

Thermal power plant efficiency enhancement with Ocean Thermal Energy Conversion  

Science Journals Connector (OSTI)

Abstract In addition to greenhouse gas emissions, coastal thermal power plants would gain further opposition due to their heat rejection distressing the local ecosystem. Therefore, these plants need to enhance their thermal efficiency while reducing their environmental offense. In this study, a hybrid plant based on the principle of Ocean Thermal Energy Conversion was coupled to a 740 MW coal-fired power plant project located at latitude 28°S where the surface to deepwater temperature difference would not suffice for regular OTEC plants. This paper presents the thermodynamical model to assess the overall efficiency gained by adopting an ammonia Rankine cycle plus a desalinating unit, heated by the power plant condenser discharge and refrigerated by cold deep seawater. The simulation allowed us to optimize a system that would finally enhance the plant power output by 25–37 MW, depending on the season, without added emissions while reducing dramatically the water temperature at discharge and also desalinating up to 5.8 million tons per year. The supplemental equipment was sized and the specific emissions reduction was estimated. We believe that this approach would improve the acceptability of thermal and nuclear power plant projects regardless of the plant location.

Rodrigo Soto; Julio Vergara

2014-01-01T23:59:59.000Z

485

High Temperature Oxidation Performance of Aluminide Coatings  

SciTech Connect

Aluminide coatings are of interest for many high temperature applications because of the possibility of improving the oxidation resistance of structural alloys by forming a protective external alumina scale. Steam and exhaust gas environments are of particular interest because alumina is less susceptible to the accelerated attack due to hydroxide formation observed for chromia- and silica-forming alloys and ceramics. For water vapor testing, one ferritic (Fe-9Cr-1Mo) and one austenitic alloy (304L) have been selected as substrate materials and CVD coatings have been used in order to have a well-controlled, high purity coating. It is anticipated that similar aluminide coatings could be made by a higher-volume, commercial process such as pack cementation. Previous work on this program has examined as-deposited coatings made by high and low Al activity CVD processes and the short-term performance of these coatings. The current work is focusing on the long term behavior in both diffusion tests16 and oxidation tests of the thicker, high Al activity coatings. For long-term coating durability, one area of concern has been the coefficient of thermal expansion (CTE) mismatch between coating and substrate. This difference could cause cracking or deformation that could reduce coating life. Corrosion testing using thermal cycling is of particular interest because of this potential problem and results are presented where a short exposure cycle (1h) severely degraded aluminide coatings on both types of substrates. To further study the potential role of aluminide coatings in fossil energy applications, several high creep strength Ni-base alloys were coated by CVD for testing in a high pressure (20atm) steam-CO{sub 2} environment for the ZEST (zero-emission steam turbine) program. Such alloys would be needed as structural and turbine materials in this concept. For Ni-base alloys, CVD produces a {approx}50{mu}m {beta}-NiAl outer layer with an underlying interdiffusion zone. Specimens of HR160, alloy 601 and alloy 230 were tested with and without coatings at 900 C and preliminary post-test characterization is reported.

Pint, Bruce A [ORNL; Zhang, Ying [Tennessee Technological University; Haynes, James A [ORNL; Wright, Ian G [ORNL

2004-01-01T23:59:59.000Z

486

University of Colorado Thermal Comfort Report  

NLE Websites -- All DOE Office Websites (Extended Search)

A A Warmboard sub-floor with tubing and wood Image Courtsey of Warmboard Image Thermal Comfort "That Condition of mind, which expresses satisfaction with the thermal environment" (ASHRAE Standard 55) Design Criteria Design Criteria Design Criteria Design Criteria 1. Thermally comfortable conditions achieved by integrating technologically and economically innovative, low-energy strategies: a. Temperatures between 72 o F and 76 o F b. Humidity between 40.0% and 55.0% 2. Minimal distractions to the occupant 3. Easy control of thermal comfort system 4. Uniform thermal conditions exist throughout the house Bio Bio Bio Bio- - - -S S S S ( ( ( (h h h h) ) ) ) ip ip ip ip Thermal Comfort Features Thermal Comfort Features Thermal Comfort Features Thermal Comfort Features

487

Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants  

E-Print Network (OSTI)

COST REDUCTION STUDY FOR SOLAR THERMAL POWER PLANTS, Ottawa,Storage in Concentrated Solar Thermal Power Plants A ThesisStorage in Concentrated Solar Thermal Power Plants by Corey

Hardin, Corey Lee

2011-01-01T23:59:59.000Z

488

Structure, adhesion, and stability of metal/oxide and oxide/oxide interfaces  

SciTech Connect

Studies of structural, electronic, and chemical properties of metal/oxide and oxide/oxide interfaces were performed on well-defined interfaces that created by depositing ultra-thin potassium and aluminum films and their oxides onto single crystal TiO[sub 2] and NiO surfaces. Work focused on determining the structure, growth mechanisms, and morphologies of metal and oxide films as they are deposited an single crystal oxide surfaces using RHEED and atomic force microscopy probing electronic structure, bonding and chemical interactions at the interfaces using x-ray and uv photoelectron spectroscopies (XPS, UPS) and Auger electron spectroscopy (AES), and understanding factors affecting stability and reactivity of the interface regions including the role of defects and impurities. Results indicate that kinetic effects have an important influence on interface structure and composition, and they also show that defects in the oxide substrate induce new electronic states at the interface which play a major role in cation-anion bonding and interface interactions. The results establish a link between electronic and chemical bonding properties and the interface structure and morphology, which is required to successfully manipulate the interfacial properties of advanced ceramic materials.

Lad, R.J.

1992-11-01T23:59:59.000Z

489

An (ultra) high-vacuum compatible sputter source for oxide thin film growth  

SciTech Connect

A miniaturised CF-38 mountable sputter source for oxide and metal thin film preparation with enhanced high-vacuum and ultra-high-vacuum compatibility is described. The all home-built sputtering deposition device allows a high flexibility also in oxidic sputter materials, suitable deposition rates for preparation of films in the nm- and the sub-monolayer regime and excellent reliability and enhanced cleanliness for usage in UHV chambers. For a number of technologically important – yet hardly volatile – materials, the described source represents a significant improvement over thermal deposition techniques like electron-beam- or thermal evaporation, as especially the latter are no adequate tool to prepare atomically clean layers of refractory oxide materials. Furthermore, it is superior to commercially available magnetron sputter devices, especially for applications, where highly reproducible sub-monolayer thin film preparation under very clean UHV conditions is required (e.g., for studying phase boundary effects in catalysis). The device in turn offers the usage of a wide selection of evaporation materials and special target preparation procedures also allow the usage of pressed oxide powder targets. To prove the performance of the sputter-source, test preparations with technologically relevant oxide components, comprising ZrO{sub 2} and yttrium-stabilized ZrO{sub 2}, have been carried out. A wide range of characterization methods (electron microscopy, X-ray photoelectron spectroscopy, low-energy ion scattering, atomic force microscopy, and catalytic testing) were applied to demonstrate the properties of the sputter-deposited thin film systems.

Mayr, Lukas; Köpfle, Norbert; Auer, Andrea; Klötzer, Bernhard; Penner, Simon [Institute for Physical Chemistry, University of Innsbruck, Innrain 52a, A-6020 Innsbruck (Austria)] [Institute for Physical Chemistry, University of Innsbruck, Innrain 52a, A-6020 Innsbruck (Austria)

2013-09-15T23:59:59.000Z

490

Non-thermal radio astronomy  

Science Journals Connector (OSTI)

Abstract This presentation starts with Karl Jansky’s discovery of cosmic radio emission in 1933 and notes the striking similarities to Hess’s discovery of cosmic-rays in 1912. At first it was assumed that this radio emission was thermal but in 1939 Grote Reber discovered that it was stronger at longer wavelengths, requiring a non-thermal emission process. These discoveries had a revolutionary impact on astronomy and radio astronomy was born. The interpretation of this non-thermal radiation as synchrotron emission from high energy particles in the interstellar medium did not occur until the late 1940s but then it provided the link between radio astronomy and cosmic-ray research. Ginzburg, in particular, saw that cosmic-ray astrophysics was now possible using radio waves to trace sources of cosmic-rays. We discuss the discovery of extragalactic active galactic nuclei leading to the discovery of quasars and the first evidence for black holes in the nuclei of galaxies. We summarise the present status and future of some of the main radio telescopes used to image the non-thermal emission from external galaxies. Finally, we include a short description of the use of radio signals for the direct detection of cosmic-rays and UHE neutrinos.

R.D. Ekers

2014-01-01T23:59:59.000Z

491

A Plastic for Thermal Insulation  

Science Journals Connector (OSTI)

... ft. per in. thickness per 1° F. difference of temperature, so that its insulation properties compare very favourably with slab-cork (0-25 B.TH.U.), glass ... tenth that of slab-cork. This makes it of considerable interest in connexion with thermal insulation during transport. Isoflex is non-porous and non-absorbent, with the result that its ...

1941-04-26T23:59:59.000Z

492

APPLIED THERMAL ENGINEERING Manuscript Draft  

E-Print Network (OSTI)

the heat pump from the grid during the two hours of electrical peak power · Design of a new heat exchangerAPPLIED THERMAL ENGINEERING Manuscript Draft TITLE: Experimental assessment of a PCM to air heat This paper presents a heat exchanger prototype containing PCM material designed to provide a 1kW heating

Paris-Sud XI, Université de

493

Practical Solar Thermal Chilled Water  

E-Print Network (OSTI)

the potential to impact America's use of non-renewable energy beyond its own design capacity by applying it to the optimization of an existing building's system. Solar-thermal chilling systems are not new. However, few of them can be described as a practical...

Leavell, B.

2010-01-01T23:59:59.000Z

494

Solar energy thermalization and storage device  

DOE Patents (OSTI)

A passive solar thermalization and thermal energy storage assembly which is visually transparent. The assembly consists of two substantial parallel, transparent wall members mounted in a rectangular support frame to form a liquid-tight chamber. A semitransparent thermalization plate is located in the chamber, substantially paralled to and about equidistant from the transparent wall members to thermalize solar radiation which is stored in a transparent thermal energy storage liquid which fills the chamber. A number of the devices, as modules, can be stacked together to construct a visually transparent, thermal storage wall for passive solar-heated buildings.

McClelland, John F. (Ames, IA)

1981-09-01T23:59:59.000Z

495

Thermal Characterization of Graphitic Carbon Foams for Use in Thermal Storage Applications.  

E-Print Network (OSTI)

?? Highly conductive graphitic foams are currently being studied for use as thermal conductivity enhancers (TCEs) in thermal energy storage (TES) systems. TES systems store… (more)

Drummond, Kevin P.

2012-01-01T23:59:59.000Z

496

Phase Change Materials for Thermal Energy Storage in Concentrated Solar Thermal Power Plants.  

E-Print Network (OSTI)

??Experimental studies are presented that aim to utilize phase change materials (PCM's) to enhance thermal energy storage systems for concentrated solar thermal power (CSP) systems.… (more)

Hardin, Corey Lee

2011-01-01T23:59:59.000Z

497

Optical and Thermal Characterization of High Reflective Surface with Applications in Thermal-Solar Technology  

Science Journals Connector (OSTI)

Selective solar absorbing coating consists of a high thermal reflectance layer and high solar absorbance layer deposited over a substrate. In this work optical and thermal properties...

Macias, Juan Daniel; Ramirez Rincon, Jorge Andres; Lizama Tzec, Francisco Ivan; Ares Muzio, Oscar Eduardo; Oskam, Gerko; De Coss Gomez, Romeo; Alvarado Gil, Juan José

498

Optical and Thermal Characterization of High Reflection Surfaces with Applcations in Thermal-Solar Technology  

Science Journals Connector (OSTI)

Selective solar absorbing coating consists of a high thermal reflectance layer and a high solar absorbance layer deposited over a substrate. In this work optical and thermal properties...

Macias, Juan Daniel; Ramirez Rincon, Jorge Andres; Lizama Tzec, Francisco Ivan; Ares Muzio, Oscar Eduardo; Oskam, Gerko; De Coss Gomez, Romeo; Alvarado Gil, Juan José

499

Approximation of inhomogeneous thermal lines via series connection of homogeneous thermal lines  

Science Journals Connector (OSTI)

A method is given for approximating an arbitrary inhomogeneous thermal line (ITL) as a series connection of homogeneous thermal lines (HTL). The method is compared with...

L. S. Eleinikova

1974-10-01T23:59:59.000Z

500

Single crystal oxide and oxide/oxide eutectic fibres for high temperature composites  

Science Journals Connector (OSTI)

The utilisation of fibre-reinforced metal, intermetallic and ceramic matrix composites (CMCs) in gas turbine engines offers the potential of improved fuel efficiency, higher operating temperature and greater thrust to weight ratio. The development of ceramic fibres with high strength, excellent strength retention at elevated temperatures and good creep resistance is essential to the successful implementation of composites in various high temperature components. Several single crystal oxide and oxide/oxide eutectic fibres have been developed to meet the demanding performance requirements. Recent progress made on developing these fibers will be discussed.

J.-M. Yang

2001-01-01T23:59:59.000Z