National Library of Energy BETA

Sample records for refrigeration electrochemical processes

  1. Low-Cost Electrochemical Compressor Utilizing Green Refrigerants...

    Office of Environmental Management (EM)

    Low-Cost Electrochemical Compressor Utilizing Green Refrigerants for HVAC Applications Low-Cost Electrochemical Compressor Utilizing Green Refrigerants for HVAC Applications...

  2. Chemically assisted mechanical refrigeration process

    DOE Patents [OSTI]

    Vobach, A.R.

    1987-11-24

    There is provided a chemically assisted mechanical refrigeration process including the steps of: mechanically compressing a refrigerant stream which includes vaporized refrigerant; contacting the refrigerant with a solvent in a mixer at a pressure sufficient to promote substantial dissolving of the refrigerant in the solvent in the mixer to form a refrigerant-solvent solution while concurrently placing the solution in heat exchange relation with a working medium to transfer energy to the working medium, said refrigerant-solvent solution exhibiting a negative deviation from Raoult's Law; reducing the pressure over the refrigerant-solvent solution in an evaporator to allow the refrigerant to vaporize and substantially separate from the solvent while concurrently placing the evolving refrigerant-solvent solution in heat exchange relation with a working medium to remove energy from the working medium to thereby form a refrigerant stream and a solvent stream; and passing the solvent and refrigerant stream from the evaporator. 5 figs.

  3. Chemically assisted mechanical refrigeration process

    DOE Patents [OSTI]

    Vobach, A.R.

    1987-06-23

    There is provided a chemically assisted mechanical refrigeration process including the steps of: mechanically compressing a refrigerant stream which includes vaporized refrigerant; contacting the refrigerant with a solvent in a mixer at a pressure sufficient to promote substantial dissolving of the refrigerant in the solvent in the mixer to form a refrigerant-solvent solution while concurrently placing the solution in heat exchange relation with a working medium to transfer energy to the working medium, said refrigerant-solvent solution exhibiting a negative deviation from Raoult's Law; reducing the pressure over the refrigerant-solvent solution in an evaporator to allow the refrigerant to vaporize and substantially separate from the solvent while concurrently placing the evolving refrigerant-solvent solution in heat exchange relation with a working medium to remove energy from the working medium to thereby form a refrigerant stream and a solvent stream; and passing the solvent and refrigerant stream from the evaporator. 5 figs.

  4. Chemically assisted mechanical refrigeration process

    DOE Patents [OSTI]

    Vobach, Arnold R. (6006 Allentown Dr., Spring, TX 77379)

    1987-01-01

    There is provided a chemically assisted mechanical refrigeration process including the steps of: mechanically compressing a refrigerant stream which includes vaporized refrigerant; contacting the refrigerant with a solvent in a mixer (11) at a pressure sufficient to promote substantial dissolving of the refrigerant in the solvent in the mixer (11) to form a refrigerant-solvent solution while concurrently placing the solution in heat exchange relation with a working medium to transfer energy to the working medium, said refrigerant-solvent solution exhibiting a negative deviation from Raoult's Law; reducing the pressure over the refrigerant-solvent solution in an evaporator (10) to allow the refrigerant to vaporize and substantially separate from the solvent while concurrently placing he evolving refrigerant-solvent solution in heat exchange relation with a working medium to remove energy from the working medium to thereby form a refrigerant stream and a solvent stream; and passing the solvent and refrigerant stream from the evaporator.

  5. Chemically assisted mechanical refrigeration process

    DOE Patents [OSTI]

    Vobach, Arnold R. (6006 Allentown Dr., Spring, TX 77389)

    1987-01-01

    There is provided a chemically assisted mechanical refrigeration process including the steps of: mechanically compressing a refrigerant stream which includes vaporized refrigerant; contacting the refrigerant with a solvent in a mixer (11) at a pressure sufficient to promote substantial dissolving of the refrigerant in the solvent in the mixer (11) to form a refrigerant-solvent solution while concurrently placing the solution in heat exchange relation with a working medium to transfer energy to the working medium, said refrigerant-solvent solution exhibiting a negative deviation from Raoult's Law; reducing the pressure over the refrigerant-solvent solution in an evaporator (10) to allow the refrigerant to vaporize and substantially separate from the solvent while concurrently placing the evolving refrigerant-solvent solution in heat exchange relation with a working medium to remove energy from the working medium to thereby form a refrigerant stream and a solvent stream; and passing the solvent and refrigerant stream from the evaporator.

  6. Design of Industrial Process Refrigeration Systems 

    E-Print Network [OSTI]

    Witherell, W. D.

    1987-01-01

    of Cascade Refrigeration and Liquefaction Systems", Industrial Engineering Chemicals, Process Des. Develop., Vol. 13, No.4, 1974, pp. 421-433. 5. Cheng, W.B., and Mah, R.S.H., "Interactive Synthesis of Cascade Refrigeration Systems", Indus trial...

  7. Process for electrochemically gasifying coal

    DOE Patents [OSTI]

    Botts, T.E.; Powell, J.R.

    1985-10-25

    A process is claimed for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution. 7 figs.

  8. Active magnetic refrigerants based on Gd-Si-Ge material and refrigeration apparatus and process

    DOE Patents [OSTI]

    Gschneidner, K.A. Jr.; Pecharsky, V.K.

    1998-04-28

    Active magnetic regenerator and method using Gd{sub 5} (Si{sub x}Ge{sub 1{minus}x}){sub 4}, where x is equal to or less than 0.5, as a magnetic refrigerant that exhibits a reversible ferromagnetic/antiferromagnetic or ferromagnetic-II/ferromagnetic-I first order phase transition and extraordinary magneto-thermal properties, such as a giant magnetocaloric effect, that renders the refrigerant more efficient and useful than existing magnetic refrigerants for commercialization of magnetic regenerators. The reversible first order phase transition is tunable from approximately 30 K to approximately 290 K (near room temperature) and above by compositional adjustments. The active magnetic regenerator and method can function for refrigerating, air conditioning, and liquefying low temperature cryogens with significantly improved efficiency and operating temperature range from approximately 10 K to 300 K and above. Also an active magnetic regenerator and method using Gd{sub 5} (Si{sub x} Ge{sub 1{minus}x}){sub 4}, where x is equal to or greater than 0.5, as a magnetic heater/refrigerant that exhibits a reversible ferromagnetic/paramagnetic second order phase transition with large magneto-thermal properties, such as a large magnetocaloric effect that permits the commercialization of a magnetic heat pump and/or refrigerant. This second order phase transition is tunable from approximately 280 K (near room temperature) to approximately 350 K by composition adjustments. The active magnetic regenerator and method can function for low level heating for climate control for buildings, homes and automobile, and chemical processing. 27 figs.

  9. Active magnetic refrigerants based on Gd-Si-Ge material and refrigeration apparatus and process

    DOE Patents [OSTI]

    Gschneidner, Jr., Karl A. (Ames, IA); Pecharsky, Vitalij K. (Ames, IA)

    1998-04-28

    Active magnetic regenerator and method using Gd.sub.5 (Si.sub.x Ge.sub.1-x).sub.4, where x is equal to or less than 0.5, as a magnetic refrigerant that exhibits a reversible ferromagnetic/antiferromagnetic or ferromagnetic-II/ferromagnetic-I first order phase transition and extraordinary magneto-thermal properties, such as a giant magnetocaloric effect, that renders the refrigerant more efficient and useful than existing magnetic refrigerants for commercialization of magnetic regenerators. The reversible first order phase transition is tunable from approximately 30 K to approximately 290 K (near room temperature) and above by compositional adjustments. The active magnetic regenerator and method can function for refrigerating, air conditioning, and liquefying low temperature cryogens with significantly improved efficiency and operating temperature range from approximately 10 K to 300 K and above. Also an active magnetic regenerator and method using Gd.sub.5 (Si.sub.x Ge.sub.1-x).sub.4, where x is equal to or greater than 0.5, as a magnetic heater/refrigerant that exhibits a reversible ferromagnetic/paramagnetic second order phase transition with large magneto-thermal properties, such as a large magnetocaloric effect that permits the commercialization of a magnetic heat pump and/or refrigerant. This second order phase transition is tunable from approximately 280 K (near room temperature) to approximately 350 K by composition adjustments. The active magnetic regenerator and method can function for low level heating for climate control for buildings, homes and automobile, and chemical processing.

  10. Waste Heat Recovery from Refrigeration in a Meat Processing Facility 

    E-Print Network [OSTI]

    Murphy, W. T.; Woods, B. E.; Gerdes, J. E.

    1980-01-01

    A case study is reviewed on a heat recovery system installed in a meat processing facility to preheat water for the plant hot water supply. The system utilizes waste superheat from the facility's 1,350-ton ammonia refrigeration system. The heat...

  11. Process for electrochemically gasifying coal using electromagnetism

    DOE Patents [OSTI]

    Botts, Thomas E. (Markham, VA); Powell, James R. (Shoreham, NY)

    1987-01-01

    A process for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution.

  12. RECENT PROGRESS IN DYNAMIC PROCESS SIMULATION OF CRYOGENIC REFRIGERATORS

    SciTech Connect (OSTI)

    Kuendig, A. [Linde Kryotechnik AG, Dattlikonerstrasse 5, CH-8422 Pfungen (Switzerland)

    2008-03-16

    At the CEC 2005 a paper with the title 'Helium refrigerator design for pulsed heat load in Tokamaks' was presented. That paper highlighted the control requirements for cryogenic refrigerators to cope with the expected load variations of future nuclear fusion reactors. First dynamic computer simulations have been presented.In the mean time, the computer program is enhanced and a new series of process simulations are available. The new program considers not only the heat flows and the temperature variations within the heat exchangers, but also the variation of mass flows and pressure drops. The heat transfer numbers now are calculated in dependence of the flow speed and the gas properties. PI-controllers calculate the necessary position of specific valves for maintaining pressures, temperatures and the rotation speed of turbines.Still unsatisfactory is the fact, that changes in the process arrangement usually are attended by adjustments in the program code. It is the main objective of the next step of development a more flexible code which enables that any user defined process arrangements can be assembled by input data.

  13. Electrochemical Processing of Used Nuclear Fuel

    SciTech Connect (OSTI)

    K. M. Goff; J. C. Wass; G. M. Teske

    2011-08-01

    As part of the Department of Energy’s Fuel Cycle Research and Development Program an electrochemical technology employing molten salts is being developed for recycle of metallic fast reactor fuel and treatment of light water reactor oxide fuel to produce a feed for fast reactors. This technology has been deployed for treatment of used fuel from the Experimental Breeder Reactor II (EBR-II) in the Fuel Conditioning Facility, located at the Materials and Fuel Complex of Idaho National Laboratory. This process is based on dry (non-aqueous) technologies that have been developed and demonstrated since the 1960s. These technologies offer potential advantages compared to traditional aqueous separations including: compactness, resistance to radiation effects, criticality control benefits, compatibility with advanced fuel types, and ability to produce low purity products. This paper will summarize the status of electrochemical development and demonstration activities with used nuclear fuel, including preparation of associated high-level waste forms.

  14. Economizer refrigeration cycle space heating and cooling system and process

    DOE Patents [OSTI]

    Jardine, Douglas M. (Colorado Springs, CO)

    1983-01-01

    This invention relates to heating and cooling systems and more particularly to an improved system utilizing a Stirling Cycle engine heat pump in a refrigeration cycle.

  15. Economizer refrigeration cycle space heating and cooling system and process

    DOE Patents [OSTI]

    Jardine, D.M.

    1983-03-22

    This invention relates to heating and cooling systems and more particularly to an improved system utilizing a Stirling Cycle engine heat pump in a refrigeration cycle. 18 figs.

  16. Sandia Energy - Electro-Chemical Processes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    transients and produce fuels to replace petroleum. Electrochemical devices such as batteries, electrolyzers, and fuel cells are the most promising because of their inherently...

  17. PROCESS DESIGN AND CONTROL Steady-State Operational Degrees of Freedom with Application to Refrigeration

    E-Print Network [OSTI]

    Skogestad, Sigurd

    of the circulating refrigerant are also discussed. Two liquified natural gas (LNG) processes of current interest study on degrees of freedom is that of Konda et al.6 Processes for liquefaction of natural gas are very as a possible degree of freedom in cyclic processes. Additional degrees of freedom related to the composition

  18. Electrochemical process and production of novel complex hydrides

    DOE Patents [OSTI]

    Zidan, Ragaiy

    2013-06-25

    A process of using an electrochemical cell to generate aluminum hydride (AlH.sub.3) is provided. The electrolytic cell uses a polar solvent to solubilize NaAlH.sub.4. The resulting electrochemical process results in the formation of AlH.sub.3. The AlH.sub.3 can be recovered and used as a source of hydrogen for the automotive industry. The resulting spent aluminum can be regenerated into NaAlH.sub.4 as part of a closed loop process of AlH.sub.3 generation.

  19. Solid oxide electrochemical cell fabrication process

    DOE Patents [OSTI]

    Dollard, Walter J. (Churchill Borough, PA); Folser, George R. (Lower Burrell, PA); Pal, Uday B. (Cambridge, MA); Singhal, Subhash C. (Murrysville, PA)

    1992-01-01

    A method to form an electrochemical cell (12) is characterized by the steps of thermal spraying stabilized zirconia over a doped lanthanum manganite air electrode tube (14) to provide an electrolyte layer (15), coating conductive particles over the electrolyte, pressurizing the outside of the electrolyte layer, feeding halide vapors of yttrium and zirconium to the outside of the electrolyte layer and feeding a source of oxygen to the inside of the electrolyte layer, heating to cause oxygen reaction with the halide vapors to close electrolyte pores if there are any and to form a metal oxide coating on and between the particles and provide a fuel electrode (16).

  20. An electrochemical Claus process for sulfur recovery

    SciTech Connect (OSTI)

    Pujare, N.U.; Tsai, K.J.; Sammuells, A.F. (Eltron Research, Inc., Aurora, IL (US))

    1989-12-01

    Electrochemical oxidation of H{sub 2}S to give sulfur and water was achieved at 900{degrees}C using fuel cells possessing the general configuration where anode electrocatalysts experimentally investigated for promoting the subject oxidation reaction included WS{sub 2} and the thiospinels CuNi{sub 2}S{sub 4}, CuCo{sub 2}S{sub 4}, CuFe{sub 2}S{sub 4}, and NiFe{sub 2}S{sub 4}. The predominant oxidizable electroactive species present in the fuel cell anode compartment was suggested to be hydrogen originating from the initial thermal dissociation of H{sub 2}S (H{sub 2}S {r reversible} H{sub 2} + 1/2 S{sub 2}) at fuel cell operating temperatures. Rapid anode kinetics were found for the anodic reaction with the empirical trend for exchange currents (i{sub o}) per geometric area being found to be NiFe{sub 2}S{sub 4}{gt}WS{sub 2}{gt}CuCo{sub 2}S{sub 4}{gt}CuFe{sub 2}S{sub 4}{approx equal}NiCo{sub 2}S{sub 4}{gt}CuNi{sub 2}S{sub 4}.

  1. Apparatus and process for the refrigeration, liquefaction and separation of gases with varying levels of purity

    DOE Patents [OSTI]

    Bingham, Dennis N. (Idaho Falls, ID); Wilding, Bruce M. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID)

    2000-01-01

    A process for the separation and liquefaction of component gasses from a pressurized mix gas stream is disclosed. The process involves cooling the pressurized mixed gas stream in a heat exchanger so as to condense one or more of the gas components having the highest condensation point; separating the condensed components from the remaining mixed gas stream in a gas-liquid separator; cooling the separated condensed component stream by passing it through an expander; and passing the cooled component stream back through the heat exchanger such that the cooled component stream functions as the refrigerant for the heat exchanger. The cycle is then repeated for the remaining mixed gas stream so as to draw off the next component gas and further cool the remaining mixed gas stream. The process continues until all of the component gases are separated from the desired gas stream. The final gas stream is then passed through a final heat exchanger and expander. The expander decreases the pressure on the gas stream, thereby cooling the stream and causing a portion of the gas stream to liquify within a tank. The portion of the gas which is not liquefied is passed back through each of the heat exchanges where it functions as a refrigerant.

  2. Apparatus and process for the refrigeration, liquefaction and separation of gases with varying levels of purity

    DOE Patents [OSTI]

    Bingham, Dennis N. (Idaho Falls, ID); Wilding, Bruce M. (Idaho Falls, ID); McKellar, Michael G. (Idaho Falls, ID)

    2002-01-01

    A process for the separation and liquefaction of component gasses from a pressurized mix gas stream is disclosed. The process involves cooling the pressurized mixed gas stream in a heat exchanger so as to condensing one or more of the gas components having the highest condensation point; separating the condensed components from the remaining mixed gas stream in a gas-liquid separator; cooling the separated condensed component stream by passing it through an expander; and passing the cooled component stream back through the heat exchanger such that the cooled component stream functions as the refrigerant for the heat exchanger. The cycle is then repeated for the remaining mixed gas stream so as to draw off the next component gas and further cool the remaining mixed gas stream. The process continues until all of the component gases are separated from the desired gas stream. The final gas stream is then passed through a final heat exchanger and expander. The expander decreases the pressure on the gas stream, thereby cooling the stream and causing a portion of the gas stream to liquify within a tank. The portion of the gas which is hot liquefied is passed back through each of the heat exchanges where it functions as a refrigerant.

  3. Chapter 3: Refrigeration Process Control: Case Study Model 42 33.. RREEFFRRIIGGEERRAATTIIOONN PPRROOCCEESSSS

    E-Print Network [OSTI]

    Skogestad, Sigurd

    the compressor turbine. A forced draft air cooler is used to condense the HP refrigerant vapour, followed flash of saturated liquid letdown from the high pressure (HP) refrigerant receiver. The LP evaporator vessels differ by a factor of 5. The LP and IP evaporators are designed to provide adequate liquid

  4. Electrochemical/Pyrometallurgical Waste Stream Processing and Waste Form Fabrication

    SciTech Connect (OSTI)

    Steven Frank; Hwan Seo Park; Yung Zun Cho; William Ebert; Brian Riley

    2015-07-01

    This report summarizes treatment and waste form options being evaluated for waste streams resulting from the electrochemical/pyrometallurgical (pyro ) processing of used oxide nuclear fuel. The technologies that are described are South Korean (Republic of Korea – ROK) and United States of America (US) ‘centric’ in the approach to treating pyroprocessing wastes and are based on the decade long collaborations between US and ROK researchers. Some of the general and advanced technologies described in this report will be demonstrated during the Integrated Recycle Test (IRT) to be conducted as a part of the Joint Fuel Cycle Study (JFCS) collaboration between US Department of Energy (DOE) and ROK national laboratories. The JFCS means to specifically address and evaluated the technological, economic, and safe guard issues associated with the treatment of used nuclear fuel by pyroprocessing. The IRT will involve the processing of commercial, used oxide fuel to recover uranium and transuranics. The recovered transuranics will then be fabricated into metallic fuel and irradiated to transmutate, or burn the transuranic elements to shorter lived radionuclides. In addition, the various process streams will be evaluated and tested for fission product removal, electrolytic salt recycle, minimization of actinide loss to waste streams and waste form fabrication and characterization. This report specifically addresses the production and testing of those waste forms to demonstrate their compatibility with treatment options and suitability for disposal.

  5. Malone refrigeration

    SciTech Connect (OSTI)

    Swift, G.W.

    1993-01-01

    Malone refrigeration is the use of a liquid near its critical points without evaporations as working fluid in a regenerative or recuperative refrigeration cycle such as the Stirling and Brayton cycles. It's potential advantages include compactness, efficiency, an environmentally benign working fluid, and reasonable cost. One Malone refrigerator has been built and studied; two more are under construction. Malone refrigeration is such a new, relatively unexplored technology that the potential for inventions leading to improvements in efficiency and simplicity is very high.

  6. Removal of Chloride from Wastewater by Advanced Softening Process Using Electrochemically Generated Aluminum Hydroxide 

    E-Print Network [OSTI]

    Mustafa, Syed Faisal

    2014-07-23

    solubility. Chloride can be removed from water and wastewater by precipitation as calcium chloroaluminate using advanced softening process. This research was conducted to evaluate chloride removal using electrochemically generated aluminum hydroxide and lime...

  7. Glass composition and process for sealing void spaces in electrochemical devices

    SciTech Connect (OSTI)

    Meinhardt, Kerry D. (Richland, WA); Kirby, Brent W. (Kennewick, WA)

    2012-05-01

    A glass foaming material and method are disclosed for filling void spaces in electrochemical devices. The glass material includes a reagent that foams at a temperature above the softening point of the glass. Expansion of the glass fills void spaces including by-pass and tolerance channels of electrochemical devices. In addition, cassette to cassette seals can also be formed while channels and other void spaces are filled, reducing the number of processing steps needed.

  8. Malone refrigeration

    SciTech Connect (OSTI)

    Swift, G W

    1992-01-01

    Malone refrigeration is the use of a liquid near its critical point, without evaporation, as working fluid in a refrigeration cycle such as the Stirling cycle. We discuss relevant properties of appropriate liquids, and describe two Malone refrigerators. The first completed several years ago, established the basic principles of use of liquids in such cycles. The second, now under construction, is a linear, free-piston machine.

  9. Malone refrigeration

    SciTech Connect (OSTI)

    Swift, G.W.

    1993-06-01

    Malone refrigeration is the use of a liquid near its critical points without evaporations as working fluid in a regenerative or recuperative refrigeration cycle such as the Stirling and Brayton cycles. It`s potential advantages include compactness, efficiency, an environmentally benign working fluid, and reasonable cost. One Malone refrigerator has been built and studied; two more are under construction. Malone refrigeration is such a new, relatively unexplored technology that the potential for inventions leading to improvements in efficiency and simplicity is very high.

  10. Materials Development for Improved Efficiency of Hydrogen Production by Steam Electrolysis and Thermochemical-Electrochemical Processes

    E-Print Network [OSTI]

    Yildiz, Bilge

    and Thermochemical-Electrochemical Processes Jennifer Mawdsley, Deborah Myers, and Bilge Yildiz Chemical Engineering and depositing a thin doped-ceria interlayer between the perovskite electrodes and zirconia electrolytes² area) deposited on one side of a 200-m thick YSZ (8 mol% yttria-stabilized zirconia) or SSZ (10 mol

  11. Economic analysis of wind-powered refrigeration cooling/water-heating systems in food processing. Final report

    SciTech Connect (OSTI)

    Garling, W.S.; Harper, M.R.; Merchant-Geuder, L.; Welch, M.

    1980-03-01

    Potential applications of wind energy include not only large central turbines that can be utilized by utilities, but also dispersed systems for farms and other applications. The US Departments of Energy (DOE) and Agriculture (USDA) currently are establishing the feasibility of wind energy use in applications where the energy can be used as available, or stored in a simple form. These applications include production of hot water for rural sanitation, heating and cooling of rural structures and products, drying agricultural products, and irrigation. This study, funded by USDA, analyzed the economic feasibility of wind power in refrigeration cooling and water heating systems in food processing plants. Types of plants included were meat and poultry, dairy, fruit and vegetable, and aquaculture.

  12. Thermoacoustic refrigeration

    SciTech Connect (OSTI)

    Garrett, S.L.; Hofler, T.J. )

    1992-12-01

    Shortly after their introduction, chlorofluorocarbons (CFCs) used as working fluids in a vapor compression (Rankine) refrigeration cycle became dominant in almost all small and medium-scale food refrigerator/freezer and building/residential air-conditioning applications. That situation is about to change dramatically and, at this moment, unpredictably. Two recent events are responsible for the new era in refrigeration that will dawn before the beginning of the 21st Century. The most significant of these is the international ban on the production of CFCs which were found to be destroying the Earth's protective ozone layer. The second event was the discovery of high temperature superconductors and the development of high speed and high density electronic circuits that require active cooling. It is the purpose of this article to introduce an entirely new approach to refrigeration that was first discovered in the early 1980s. This new approach-thermoacoustic refrigeration-uses high intensity sound waves to pump heat, with inert gases as the working fluid.

  13. 12.11.2014bo Akademi Univ -Thermal and Flow Engineering Piispankatu 8, 20500 Turku 1/32 4. Refrigeration process comparison;

    E-Print Network [OSTI]

    Zevenhoven, Ron

    12.11.2014Åbo Akademi Univ - Thermal and Flow Engineering Piispankatu 8, 20500 Turku 1/32 4 Engineering Laboratory / Värme- och strömningsteknik tel. 3223 ; ron.zevenhoven@abo.fi Kylteknik ("KYL and Flow Engineering Piispankatu 8, 20500 Turku 2/32 4.1 Refrigeration process comparison #12;12.11.2014Åbo

  14. Kylteknik ("KYL")Kylteknik ("KYL") RefrigerationRefrigerationRefrigerationRefrigeration

    E-Print Network [OSTI]

    Zevenhoven, Ron

    (Hvaporisation >> Hmelting), for example: water The Carnot power cycle can be executed in a reverse within the 8.11.2012Åbo Akademi Univ - Thermal and Flow Engineering - Piispankatu 8, 20500 Turku 3/64 The Carnot power cycle can be executed in a reverse within the saturation dome of a refrigerant fluid Reversed Carnot

  15. Kylteknik ("KYL")Kylteknik ("KYL") RefrigerationRefrigerationRefrigerationRefrigeration

    E-Print Network [OSTI]

    Zevenhoven, Ron

    - compression cycle Sources for "cheap heat" could be waste heat from power generation or steamp g plants, a refrigeration cycle can be driven by heat (preferably 100-200°C) The replaces the compressor in a vapour to the surroundings in a d i th ttl d tcondenser, is throttled to low pressure and takes up heat in the evaporator

  16. Carbon activation process for increased surface accessibility in electrochemical capacitors

    DOE Patents [OSTI]

    Doughty, Daniel H. (Albuquerque, NM); Eisenmann, Erhard T. (Belpre, OH)

    2001-01-01

    A process for making carbon film or powder suitable for double capacitor electrodes having a capacitance of up to about 300 F/cm.sup.3 is disclosed. This is accomplished by treating in aqueous nitric acid for a period of about 5 to 15 minutes thin carbon films obtained by carbonizing carbon-containing polymeric material having a high degree of molecular directionality, such as polyimide film, then heating the treated carbon film in a non-oxidizing atmosphere at a non-graphitizing temperature of at least 350.degree. C. for about 20 minutes, and repeating alternately the nitric acid step and the heating step from 7 to 10 times. Capacitors made with this carbon may find uses ranging from electronic devices to electric vehicle applications.

  17. Process for manufacturing a lithium alloy electrochemical cell

    DOE Patents [OSTI]

    Bennett, William R. (North Olmstead, OH)

    1992-10-13

    A process for manufacturing a lithium alloy, metal sulfide cell tape casts slurried alloy powders in an organic solvent containing a dissolved thermoplastic organic binder onto casting surfaces. The organic solvent is then evaporated to produce a flexible tape removable adhering to the casting surface. The tape is densified to increase its green strength and then peeled from the casting surface. The tape is laminated with a separator containing a lithium salt electrolyte and a metal sulfide electrode to form a green cell. The binder is evaporated from the green cell at a temperature lower than the melting temperature of the lithium salt electrolyte. Lithium alloy, metal sulfide and separator powders may be tape cast.

  18. Fluorescent refrigeration

    DOE Patents [OSTI]

    Epstein, Richard I. (Santa Fe, NM); Edwards, Bradley C. (Los Alamos, NM); Buchwald, Melvin I. (Santa Fe, NM); Gosnell, Timothy R. (Santa Fe, NM)

    1995-01-01

    Fluorescent refrigeration is based on selective radiative pumping, using substantially monochromatic radiation, of quantum excitations which are then endothermically redistributed to higher energies. Ultimately, the populated energy levels radiatively deexcite emitting, on the average, more radiant energy than was initially absorbed. The material utilized to accomplish the cooling must have dimensions such that the exciting radiation is strongly absorbed, but the fluorescence may exit the material through a significantly smaller optical pathlength. Optical fibers and mirrored glasses and crystals provide this requirement.

  19. Refrigerant directly cooled capacitors

    DOE Patents [OSTI]

    Hsu, John S. (Oak Ridge, TN); Seiber, Larry E. (Oak Ridge, TN); Marlino, Laura D. (Oak Ridge, TN); Ayers, Curtis W. (Kingston, TN)

    2007-09-11

    The invention is a direct contact refrigerant cooling system using a refrigerant floating loop having a refrigerant and refrigeration devices. The cooling system has at least one hermetic container disposed in the refrigerant floating loop. The hermetic container has at least one electronic component selected from the group consisting of capacitors, power electronic switches and gating signal module. The refrigerant is in direct contact with the electronic component.

  20. Fluorescent refrigeration

    DOE Patents [OSTI]

    Epstein, R.I.; Edwards, B.C.; Buchwald, M.I.; Gosnell, T.R.

    1995-09-05

    Fluorescent refrigeration is based on selective radiative pumping, using substantially monochromatic radiation, of quantum excitations which are then endothermically redistributed to higher energies. Ultimately, the populated energy levels radiatively deexcite emitting, on the average, more radiant energy than was initially absorbed. The material utilized to accomplish the cooling must have dimensions such that the exciting radiation is strongly absorbed, but the fluorescence may exit the material through a significantly smaller optical pathlength. Optical fibers and mirrored glasses and crystals provide this requirement. 6 figs.

  1. ARTI refrigerant database

    SciTech Connect (OSTI)

    Calm, J.M.

    1996-07-01

    The Refrigerant Database is an information system on alternative refrigerants, associated lubricants, and their use in air conditioning and refrigeration. It consolidates and facilitates access to property, compatibility, environmental, safety, application and other information. It provides corresponding information on older refrigerants, to assist manufacturers and those using alternative refrigerants, to make comparisons and determine differences. The underlying purpose is to accelerate phase out of chemical compounds of environmental concern.

  2. ARTI refrigerant database

    SciTech Connect (OSTI)

    Calm, J.M.

    1999-01-01

    The Refrigerant Database is an information system on alternative refrigerants, associated lubricants, and their use in air conditioning and refrigeration. It consolidates and facilities access to property, compatibility, environmental, safety, application and other information. It provides corresponding information on older refrigerants, to assist manufacturers and those using alternative refrigerants, to make comparisons and determine differences. The underlying purpose is to accelerate phase out of chemical compounds of environmental concern.

  3. ARTI refrigerant database

    SciTech Connect (OSTI)

    Calm, J.M.

    1996-11-15

    The Refrigerant Database is an information system on alternative refrigerants, associated lubricants, and their use in air conditioning and refrigeration. It consolidates and facilitates access to property, compatibility, environmental, safety, application and other information. It provides corresponding information on older refrigerants, to assist manufacturers and those using alternative refrigerants, to make comparisons and determine differences. The underlying purpose is to accelerate phase out of chemical compounds of environmental concern.

  4. Optimal refrigerator

    E-Print Network [OSTI]

    Armen E. Allahverdyan; Karen Hovhannisyan; Guenter Mahler

    2010-07-25

    We study a refrigerator model which consists of two $n$-level systems interacting via a pulsed external field. Each system couples to its own thermal bath at temperatures $T_h$ and $T_c$, respectively ($\\theta\\equiv T_c/T_hisolated interaction between the systems driven by the external field and isothermal relaxation back to equilibrium. There is a complementarity between the power of heat transfer from the cold bath and the efficiency: the latter nullifies when the former is maximized and {\\it vice versa}. A reasonable compromise is achieved by optimizing the product of the heat-power and efficiency over the Hamiltonian of the two system. The efficiency is then found to be bounded from below by $\\zeta_{\\rm CA}=\\frac{1}{\\sqrt{1-\\theta}}-1$ (an analogue of the Curzon-Ahlborn efficiency), besides being bound from above by the Carnot efficiency $\\zeta_{\\rm C} = \\frac{1}{1-\\theta}-1$. The lower bound is reached in the equilibrium limit $\\theta\\to 1$. The Carnot bound is reached (for a finite power and a finite amount of heat transferred per cycle) for $\\ln n\\gg 1$. If the above maximization is constrained by assuming homogeneous energy spectra for both systems, the efficiency is bounded from above by $\\zeta_{\\rm CA}$ and converges to it for $n\\gg 1$.

  5. Management of Salt Waste from Electrochemical Processing of Used Nuclear Fuel

    SciTech Connect (OSTI)

    Michael F. Simpson; Michael N. Patterson; Joon Lee; Yifeng Wang; Joshua Versey; Ammon Williams; Supathorn Phongikaroon; James Allensworth; Man-Sung Yim

    2013-10-01

    Electrochemical processing of used nuclear fuel involves operation of one or more cells containing molten salt electrolyte. Processing of the fuel results in contamination of the salt via accumulation of fission products and transuranic (TRU) actinides. Upon reaching contamination limits, the salt must be removed and either disposed or treated to remove the contaminants and recycled back to the process. During development of the Experimental Breeder Reactor-II spent fuel treatment process, waste salt from the electrorefiner was to be stabilized in a ceramic waste form and disposed of in a high-level waste repository. With the cancellation of the Yucca Mountain high-level waste repository, other options are now being considered. One approach that involves direct disposal of the salt in a geologic salt formation has been evaluated. While waste forms such as the ceramic provide near-term resistance to corrosion, they may not be necessary to ensure adequate performance of the repository. To improve the feasibility of direct disposal, recycling a substantial fraction of the useful salt back to the process equipment could minimize the volume of the waste. Experiments have been run in which a cold finger is used for this purpose to crystallize LiCl from LiCl/CsCl. If it is found to be unsuitable for transportation, the salt waste could also be immobilized in zeolite without conversion to the ceramic waste form.

  6. Management of salt waste from electrochemical processing of used nuclear fuel

    SciTech Connect (OSTI)

    Simpson, M.F.; Patterson, M.N.; Lee, J.; Wang, Y.; Versey, J.; Phongikaroon, S.

    2013-07-01

    Electrochemical processing of used nuclear fuel involves operation of one or more cells containing molten salt electrolyte. Processing of the fuel results in contamination of the salt via accumulation of fission products and transuranic (TRU) actinides. Upon reaching contamination limits, the salt must be removed and either disposed or treated to remove the contaminants and recycled back to the process. During development of the Experimental Breeder Reactor-II spent fuel treatment process, waste salt from the electro-refiner was to be stabilized in a ceramic waste form and disposed of in a high-level waste repository. With the cancellation of the Yucca Mountain high-level waste repository, other options are now being considered. One approach that involves direct disposal of the salt in a geologic salt formation has been evaluated. While waste forms such as the ceramic provide near-term resistance to corrosion, they may not be necessary to ensure adequate performance of the repository. To improve the feasibility of direct disposal, recycling a substantial fraction of the useful salt back to the process equipment could minimize the volume of the waste. Experiments have been run in which a cold finger is used for this purpose to crystallize LiCl from LiCl/CsCl. If it is found to be unsuitable for transportation, the salt waste could also be immobilized in zeolite without conversion to the ceramic waste form. (authors)

  7. ARTI Refrigerant Database

    SciTech Connect (OSTI)

    Calm, J.M.

    1994-05-27

    The Refrigerant Database consolidates and facilitates access to information to assist industry in developing equipment using alternative refrigerants. The underlying purpose is to accelerate phase out of chemical compounds of environmental concern.

  8. Plant Site Refrigeration Upgrade 

    E-Print Network [OSTI]

    Zdrojewski, R.; Healy, M.; Ramsey, J.

    1999-01-01

    Bayer Corporation operates a multi-division manufacturing facility in Bushy Park, South Carolina. Low temperature refrigeration (-4°F) is required by many of the chemical manufacturing areas and is provided by a Plant Site Refrigeration System...

  9. Helium dilution refrigeration system

    DOE Patents [OSTI]

    Roach, Patrick R. (Darien, IL); Gray, Kenneth E. (Naperville, IL)

    1988-01-01

    A helium dilution refrigeration system operable over a limited time period, and recyclable for a next period of operation. The refrigeration system is compact with a self-contained pumping system and heaters for operation of the system. A mixing chamber contains .sup.3 He and .sup.4 He liquids which are precooled by a coupled container containing .sup.3 He liquid, enabling the phase separation of a .sup.3 He rich liquid phase from a dilute .sup.3 He-.sup.4 He liquid phase which leads to the final stage of a dilution cooling process for obtaining low temperatures. The mixing chamber and a still are coupled by a fluid line and are maintained at substantially the same level with the still cross sectional area being smaller than that of the mixing chamber. This configuration provides maximum cooling power and efficiency by the cooling period ending when the .sup.3 He liquid is depleted from the mixing chamber with the mixing chamber nearly empty of liquid helium, thus avoiding unnecessary and inefficient cooling of a large amount of the dilute .sup.3 He-.sup.4 He liquid phase.

  10. Helium dilution refrigeration system

    DOE Patents [OSTI]

    Roach, P.R.; Gray, K.E.

    1988-09-13

    A helium dilution refrigeration system operable over a limited time period, and recyclable for a next period of operation is disclosed. The refrigeration system is compact with a self-contained pumping system and heaters for operation of the system. A mixing chamber contains [sup 3]He and [sup 4]He liquids which are precooled by a coupled container containing [sup 3]He liquid, enabling the phase separation of a [sup 3]He rich liquid phase from a dilute [sup 3]He-[sup 4]He liquid phase which leads to the final stage of a dilution cooling process for obtaining low temperatures. The mixing chamber and a still are coupled by a fluid line and are maintained at substantially the same level with the still cross sectional area being smaller than that of the mixing chamber. This configuration provides maximum cooling power and efficiency by the cooling period ending when the [sup 3]He liquid is depleted from the mixing chamber with the mixing chamber nearly empty of liquid helium, thus avoiding unnecessary and inefficient cooling of a large amount of the dilute [sup 3]He-[sup 4]He liquid phase. 2 figs.

  11. ARTI refrigerant database

    SciTech Connect (OSTI)

    Calm, J.M.

    1997-02-01

    The Refrigerant Database is an information system on alternative refrigerants, associated lubricants, and their use in air conditioning and refrigeration. It consolidates and facilitates access to property, compatibility, environmental, safety, application and other information. It provides corresponding information on older refrigerants, to assist manufacturers and those using alterative refrigerants, to make comparisons and determine differences. The underlying purpose is to accelerate phase out of chemical compounds of environmental concern. The database provides bibliographic citations and abstracts for publications that may be useful in research and design of air-conditioning and refrigeration equipment. The complete documents are not included, though some may be added at a later date. The database identifies sources of specific information on various refrigerants. It addresses lubricants including alkylbenzene, polyalkylene glycol, polyolester, and other synthetics as well as mineral oils. It also references documents addressing compatibility of refrigerants and lubricants with metals, plastics, elastomers, motor insulation, and other materials used in refrigerant circuits. Incomplete citations or abstracts are provided for some documents. They are included to accelerate availability of the information and will be completed or replaced in future updates.

  12. ARTI refrigerant database

    SciTech Connect (OSTI)

    Calm, J.M.

    1998-08-01

    The Refrigerant Database is an information system on alternative refrigerants, associated lubricants, and their use in air conditioning and refrigeration. It consolidates and facilitates access to property, compatibility, environmental, safety, application and other information. It provides corresponding information on older refrigerants, to assist manufactures and those using alternative refrigerants, to make comparisons and determine differences. The underlying purpose is to accelerate phase out of chemical compounds of environmental concern. The database provides bibliographic citations and abstracts for publications that may be useful in research and design of air-conditioning and refrigeration equipment. The complete documents are not included, though some may be added at a later date. The database identifies sources of specific information on many refrigerants including propane, ammonia, water, carbon dioxide, propylene, ethers, and others as well as azeotropic and zeotropic blends of these fluids. It addresses lubricants including alkylbenzene, polyalkylene glycol, polyolester, and other synthetics as well as mineral oils. It also references documents addressing compatibility of refrigerants and lubricants with metals, plastics, elastomers, motor insulation, and other materials used in refrigerant circuits. Incomplete citations or abstracts are provided for some documents. They are included to accelerate availability of the information and will be completed or replaced in future updates.

  13. Combined cold compressor/ejector helium refrigerator

    DOE Patents [OSTI]

    Brown, D.P.

    1984-06-05

    A refrigeration apparatus having an ejector operatively connected with a cold compressor to form a two-stage pumping system. This pumping system is used to lower the pressure, and thereby the temperature of a bath of boiling refrigerant (helium). The apparatus as thus arranged and operated has substantially improved operating efficiency when compared to other processes or arrangements for achieving a similar low pressure.

  14. ARTI Refrigerant Database

    SciTech Connect (OSTI)

    Calm, J.M.

    1992-04-30

    The Refrigerant Database consolidates and facilitates access to information to assist industry in developing equipment using alternative refrigerants. The underlying purpose is to accelerate phase out of chemical compounds of environmental concern. The database provides bibliographic citations and abstracts for publications that may be useful in research and design of air- conditioning and refrigeration equipment. The complete documents are not included, though some may be added at a later date. The database identifies sources of specific information on R-32, R-123, R-124, R- 125, R-134a, R-141b, R142b, R-143a, R-152a, R-290 (propane), R-717 (ammonia), ethers, and others as well as azeotropic and zeotropic blends of these fluids. It addresses polyalkylene glycol (PAG), ester, and other lubricants. It also references documents addressing compatibility of refrigerants and lubricants with metals, plastics, elastomers, motor insulation, and other materials used in refrigerant circuits.

  15. Basics of Low-temperature Refrigeration

    E-Print Network [OSTI]

    Alekseev, A

    2014-01-01

    This chapter gives an overview of the principles of low temperature refrigeration and the thermodynamics behind it. Basic cryogenic processes - Joule-Thomoson process, Brayton process as well as Claude process - are described and compared. A typical helium laboratory refrigerator based on Claude process is used as a typical example of a low-temperature refrigeration system. A description of the hardware components for helium liquefaction is an important part of this paper, because the design of the main hardware components (compressors, turbines, heat exchangers, pumps, adsorbers, etc.) provides the input for cost calculation, as well as enables to estimate the reliability of the plant and the maintenance expenses. All these numbers are necessary to calculate the economics of a low temperature application.

  16. Microcomputer Software for Refrigerant Property and Cycle Analysis Calculations 

    E-Print Network [OSTI]

    Bierschenk, J. L.; Strohl, S. T.; Schmidt, P. S.

    1985-01-01

    .e., minimum temperature difference betweeD the refrigerant and the process stream) in the evapo rator and condenser on the energy utilization and cooling requirements for the refrigeration system. The assumed refrigeration load is 30 million Btu... on an existing system for purposes of improving energy utilization efficiency. Consider the case of a chiller for a commercial office building, operating on R12 at an evapo rator temperature of 42 deg F. During typical summer conditions, the chiller provides...

  17. Thermoacoustic engines and refrigerators

    SciTech Connect (OSTI)

    Swift, G.

    1996-12-31

    This report is a transcript of a practice lecture given in preparation for a review lecture on the operation of thermoacoustic engines and refrigerators. The author begins by a brief review of the thermodynamic principles underlying the operation of thermoacoustic engines and refrigerators. Remember from thermodynamics class that there are two kinds of heat engines, the heat engine or the prime mover which produces work from heat, and the refrigerator or heat pump that uses work to pump heat. The device operates between two thermal reservoirs at temperatures T{sub hot} and T{sub cold}. In the heat engine, heat flows into the device from the reservoir at T{sub hot}, produces work, and delivers waste heat into the reservoir at T{sub cold}. In the refrigerator, work flows into the device, lifting heat Q{sub cold} from reservoir at T{sub cold} and rejecting waste heat into the reservoir at T{sub hot}.

  18. Predicting the Voltage Dependence of Interfacial Electrochemical Processes at Lithium-Intercalated Graphite Edge Planes

    E-Print Network [OSTI]

    Leung, Kevin

    2015-01-01

    The applied potential governs lithium-intercalation and electrode passivation reactions in lithium ion batteries, but are challenging to calibrate in condensed phase DFT calculations. In this work, the "anode potential" of charge-neutral lithium-intercalated graphite (LiC(6)) with oxidized edge planes is computed as a function of Li-content n(Li)) at edge planes, using ab initio molecular dynamics (AIMD), a previously introduced Li+ transfer free energy method, and the experimental Li+/Li(s) value as reference. The voltage assignments are corroborated using explicit electron transfer from fluoroethylene carbonate radical anion markers. PF6- is shown to decompose electrochemically (i.e., not just thermally) at low potentials imposed by our voltage calibration technique. We demonstrate that excess electrons reside in localized states-in-the-gap in the organic carbonate liquid region, which is not semiconductor-like (band-state-like) as widely assumed in the literature.

  19. Electrochemical machining process for forming surface roughness elements on a gas turbine shroud

    DOE Patents [OSTI]

    Lee, Ching-Pang (Cincinnati, OH); Johnson, Robert Alan (Simpsonville, SC); Wei, Bin (Mechanicville, NY); Wang, Hsin-Pang (Rexford, NY)

    2002-01-01

    The back side recessed cooling surface of a shroud defining in part the hot gas path of a turbine is electrochemically machined to provide surface roughness elements and spaces therebetween to increase the heat transfer coefficient. To accomplish this, an electrode with insulating dielectric portions and non-insulating portions is disposed in opposition to the cooling surface. By passing an electrolyte between the cooling surface and electrode and applying an electrical current between the electrode and a shroud, roughness elements and spaces therebetween are formed in the cooling surface in opposition to the insulating and non-insulating portions of the electrode, hence increasing the surface area and heat transfer coefficient of the shroud.

  20. ARTI Refrigerant Database

    SciTech Connect (OSTI)

    Cain, J.M. , Great Falls, VA )

    1993-04-30

    The Refrigerant Database consolidates and facilitates access to information to assist industry in developing equipment using alternative refrigerants. The underlying purpose is to accelerate phase out of chemical compounds of environmental concern. The database provides bibliographic citations and abstracts for publications that may be useful in research and design of air-conditioning and refrigeration equipment. The complete documents are not included. The database identifies sources of specific information on R-32, R-123, R-124, R-125, R-134, R-134a, R-141b, R-142b, R-143a, R-152a, R-245ca, R-290 (propane), R-717 (ammonia), ethers, and others as well as azeotropic and zeotropic blends of these fluids. It addresses lubricants including alkylbenzene, polyalkylene glycol, ester, and other synthetics as well as mineral oils. It also references documents addressing compatibility of refrigerants and lubricants with metals, plastics, elastomers, motor insulation, and other materials used in refrigerant circuits. Incomplete citations or abstracts are provided for some documents to accelerate availability of the information and will be completed or replaced in future updates.

  1. Downhole pulse tube refrigerators

    SciTech Connect (OSTI)

    Swift, G.; Gardner, D.

    1997-12-01

    This report summarizes a preliminary design study to explore the plausibility of using pulse tube refrigeration to cool instruments in a hot down-hole environment. The original motivation was to maintain Dave Reagor`s high-temperature superconducting electronics at 75 K, but the study has evolved to include three target design criteria: cooling at 30 C in a 300 C environment, cooling at 75 K in a 50 C environment, cooling at both 75 K and 30 C in a 250 C environment. These specific temperatures were chosen arbitrarily, as representative of what is possible. The primary goals are low cost, reliability, and small package diameter. Pulse-tube refrigeration is a rapidly growing sub-field of cryogenic refrigeration. The pulse tube refrigerator has recently become the simplest, cheapest, most rugged and reliable low-power cryocooler. The authors expect this technology will be applicable downhole because of the ratio of hot to cold temperatures (in absolute units, such as Kelvin) of interest in deep drilling is comparable to the ratios routinely achieved with cryogenic pulse-tube refrigerators.

  2. Energy Efficient, Environmentally Friendly Refrigerants 

    E-Print Network [OSTI]

    Nimitz, J.; Glass, S.; Dhooge, P. M.

    1998-01-01

    refrigerants have become expensive or unavailable. A safe, environmentally friendly, high performance refrigerant mixture for replacement of R-12 and R-134a has been developed. The mixture, designated Ikon B, is nonflammable, has zero ozone depletion potential...

  3. Waste Heat Recovery from Refrigeration 

    E-Print Network [OSTI]

    Jackson, H. Z.

    1982-01-01

    heat recovery from refrigeration machines is a concept which has great potential for implementation in many businesses. If a parallel requirement for refrigeration and hot water exists, the installation of a system to provide hot water as a by...

  4. ARTI Refrigerant Database

    SciTech Connect (OSTI)

    Calm, J.M.

    1992-11-09

    The database provides bibliographic citations and abstracts for publications that may be useful in research and design of air- conditioning and refrigeration equipment. The database identifies sources of specific information on R-32, R-123, R-124, R-125, R-134, R-134a, R-141b, R-142b, R-143a, R-152a, R-245ca, R-290 (propane), R- 717 (ammonia), ethers, and others as well as azeotropic and zeotropic and zeotropic blends of these fluids. It addresses lubricants including alkylbenzene, polyalkylene glycol, ester, and other synthetics as well as mineral oils. It also references documents on compatibility of refrigerants and lubricants with metals, plastics, elastomers, motor insulation, and other materials used in refrigerant circuits. A computerized version is available that includes retrieval software.

  5. Refrigeration monitor and alarm system

    SciTech Connect (OSTI)

    Branz, M.A.; Renaud, P.F.

    1986-09-23

    A monitor is described for a refrigeration system including a heat reclaiming system coupled therewith, comprising: a sensor positioned to detect the level of liquid state refrigerant in the system and provide an electrical output signal therefrom; a digital display for displaying the refrigerant level; first circuit means coupling the digital display to the sensor for actuating the digital display; and lockout means coupled with the sensor for deactivating the heat reclaiming system when a preselected refrigerant level is reached.

  6. Ames Lab 101: Magnetic Refrigeration

    SciTech Connect (OSTI)

    Pecharsky, Vitalij

    2011-01-01

    Vitalij Pecharsky, distinguished professor of materials science and engineering, discusses his research in magnetic refrigeration at Ames Lab.

  7. Ames Lab 101: Magnetic Refrigeration

    ScienceCinema (OSTI)

    Pecharsky, Vitalij

    2013-03-01

    Vitalij Pecharsky, distinguished professor of materials science and engineering, discusses his research in magnetic refrigeration at Ames Lab.

  8. Variable Refrigerant Flow HVAC 

    E-Print Network [OSTI]

    Jones, S.

    2013-01-01

    Variable refrigerant flow technology HVAC CATEE 2013 San Antonio, TX ESL-KT-13-12-33 CATEE 2013: Clean Air Through Energy Efficiency Conference, San Antonio, Texas Dec. 16-18 What is the acronym VRF? ? Variable Refrigerant Flow Operates like a... heat pump utilizing VFD Inverter Compressors and LEV’s Unlike conventional commercial and residential HVAC systems in the USA The predominate method of cooling and heating in the world ESL-KT-13-12-33 CATEE 2013: Clean Air Through Energy Efficiency...

  9. Low-temperature magnetic refrigerator

    DOE Patents [OSTI]

    Barclay, J.A.

    1983-05-26

    The invention relates to magnetic refrigeration and more particularly to low temperature refrigeration between about 4 and about 20 K, with an apparatus and method utilizing a belt of magnetic material passed in and out of a magnetic field with heat exchangers within and outside the field operably disposed to accomplish refrigeration.

  10. Exergy analysis of magnetic refrigeration

    E-Print Network [OSTI]

    Lucia, Umberto

    2010-01-01

    One of the main challenges of the industry today is to face its impact on global warming considering that the greenhouse effect problem is not be solved completely yet. Magnetic refrigeration represents an environment-safe refrigeration technology. The magnetic refrigeration is analysed using the second law analysis and introducing exergy in order to obtain a model for engineering application.

  11. Extending the Range of Organic Compounds that Can Be Destroyed Using the Process of Adsorption Coupled with Electrochemical Regeneration - 13054

    SciTech Connect (OSTI)

    Brown, Nigel; Lodge, Mike; Hilton, Linda; Adams, Alex [Arvia Technology Ltd, Sci-Tech Daresbury, Keckwick Lane, Daresbury, Cheshire, WA4, 4FS (United Kingdom)] [Arvia Technology Ltd, Sci-Tech Daresbury, Keckwick Lane, Daresbury, Cheshire, WA4, 4FS (United Kingdom); Vaudey, Claire-Emilie [AREVA CL BU, AREVA BUA STMI ZAC de Courcelle 1 route de la Noue 91196 Gif-sur-Yvette (France)] [AREVA CL BU, AREVA BUA STMI ZAC de Courcelle 1 route de la Noue 91196 Gif-sur-Yvette (France); Toulemonde, Valerie [AREVA DRD, Tour AREVA, 1, place Jean Millier, 92084 Paris La Defense Cedex (France)] [AREVA DRD, Tour AREVA, 1, place Jean Millier, 92084 Paris La Defense Cedex (France)

    2013-07-01

    The nuclear industry is not a provider of oils and solvents but uses them in motors, equipment and even in chemical processes to extract valuable products. Currently, for old and contaminated oils and solvents, techniques still exist, such as incineration, but not all the oils and solvents are compatible with this technique because the activities of some components inside the oils are too high to be accepted at the incineration facility. For these oils, an alternative technique needs to be found for treatment. A process developed for water treatment using a technique of adsorption coupled with electrochemical regeneration has been investigated to assess its capability to treat these organic wastes. One of the strengths of the process is its flexibility and adaptation to different compositions of oils. This point is important because, in the AREVA case, there are a lot of small volumes of old oils which need to be re-characterized. It takes time and money to do it especially when oils are contaminated; this is one reason why the technique is interesting to investigate. Tests have been performed with different oils coming from different sites to test the feasibility. Results demonstrate the destruction of a range of organics with regeneration energy requirements of 13.4 - 68.7 kWh/l and offer confidence for the future potential of the process. (authors)

  12. Thermoacoustic engines and refrigerators

    SciTech Connect (OSTI)

    Swift, G.W.

    1995-07-01

    We ordinarily think of a sound wave in a gas as consisting of coupled pressure and displacement oscillations. However, temperature oscillations always accompany the pressure changes. The combination of all these oscillations, and their interaction with solid boundaries, produces a rich variety of `thermoacoustic` effects. Although these effects as they occur in every-day life are too small to be noticed, one can harness extremely loud sound waves in acoustically sealed chambers to produce powerful heat engines, heat pumps and refrigerators. Whereas typical engines and refrigerators have crankshaft-coupled pistons or rotating turbines, thermoacoustic engines and refrigerators have at most a single flexing moving part (as in a loudspeaker) with no sliding seals. Thermoacoustic devices may be of practical use where simplicity, reliability or low cost is more important than the highest efficiency (although one cannot say much more about their cost-competitiveness at this early stage). This paper discusses the fundamentals of thermoacoustic engines and refrigerators, research in this field, and their commercial development. 16 refs., 5 figs.

  13. Potential of the tractor-trailer and container segments as entry markets for a proposed refrigeration technology

    SciTech Connect (OSTI)

    Smith, S.A.; Davis, L.J.; Garrett, B.A.

    1987-05-01

    The refrigerated trailer and container segments of the transportation industry are evaluated as potential entry markets for a proposed absorption refrigeration technology. To perform this analysis the existing transportation refrigeration industry is characterized; this includes a description of the current refrigeration technology, rating systems, equipment manufacturers, maintenance requirements, and sales trends. This information indicates that the current transportation refrigeration industry is composed of two major competitors, Thermo King and Carrier. In addition, it has low profit potential, some barriers to entry and low growth potential. Data are also presented that characterize the transportation refrigeration consumers, specifically, major groups, market segmentation, consumer decision process, and buying criteria. This consumer information indicates that the majority of refrigerated trailer consumers are private carriers, and that the majority of refrigerated container consumers are shipping companies. Also, these consumers are primarily interested in buying reliable equipment at a low price, and are quite satisfied with existing refrigeration equipment.

  14. Novel materials for laser refrigeration

    SciTech Connect (OSTI)

    Hehlen, Markus P

    2009-01-01

    The status of optical refrigeration of rare-earth-doped solids is reviewed, and the various factors that limit the performance of current laser-cooling materials are discussed. Efficient optical refrigeration is possible in materials for which {Dirac_h}{omega}{sub max} < E{sub p}/8, where {Dirac_h}{omega}{sub max} is the maximum phonon energy of the host material and E{sub p} is the pump energy of the rare-earth dopant. Transition-metal and OH{sup -}impurities at levels >100 ppb are believed to be the main factors for the limited laser-cooling performance in current materials. The many components of doped ZBLAN glass pose particular processing challenges. Binary fluoride glasses such as YF{sub 3}-LiF are considered as alternatives to ZBLAN. The crystalline system KPb{sub 2}CI{sub 5} :Dy{sup 3+} is identified as a prime candidate for high-efficiency laser cooling.

  15. Treatment methods for spent decontamination electrolyte produced in the ABB Atom electrochemical decontamination process ELDECON 

    E-Print Network [OSTI]

    Carlsson, Charlotta Elisabeth

    1995-01-01

    that is produced in the ELDECON process contains chromate (Cr 6+), which makes it a mixed waste problem (Cr 6+ and radioactivity) . According to 40 CFR 261, if a process in any step creates chromate, the final waste has to be tested in a toxicity characteristic...

  16. Compact acoustic refrigerator

    SciTech Connect (OSTI)

    Bennett, G.A.

    1991-12-31

    This invention is comprised of a compact acoustic refrigeration system that actively cools components, e.g., electrical circuits, in a borehole environment. An acoustic engine includes first thermodynamic elements for generating a standing acoustic wave in a selected medium. An acoustic refrigerator includes second thermodynamic elements located in the standing wave for generating a relatively cold temperature at a first end of the second thermodynamic elements and a relatively hot temperature at a second end of the second thermodynamic elements. A resonator volume cooperates with the first and second thermodynamic elements to support the standing wave. To accommodate the high heat fluxes required for heat transfer to/from the first and second thermodynamic elements, first heat pipes transfer heat from the heat load to the second thermodynamic elements and second heat pipes transfer heat from first and second thermodynamic elements to the borehole environment.

  17. Superfluid thermodynamic cycle refrigerator

    DOE Patents [OSTI]

    Swift, G.W.; Kotsubo, V.Y.

    1992-12-22

    A cryogenic refrigerator cools a heat source by cyclically concentrating and diluting the amount of [sup 3]He in a single phase [sup 3]He-[sup 4]He solution. The [sup 3]He in superfluid [sup 4]He acts in a manner of an ideal gas in a vacuum. Thus, refrigeration is obtained using any conventional thermal cycle, but preferably a Stirling or Carnot cycle. A single phase solution of liquid [sup 3]He at an initial concentration in superfluid [sup 4]He is contained in a first variable volume connected to a second variable volume through a superleak device that enables free passage of [sup 4]He while restricting passage of [sup 3]He. The [sup 3]He is compressed (concentrated) and expanded (diluted) in a phased manner to carry out the selected thermal cycle to remove heat from the heat load for cooling below 1 K. 12 figs.

  18. Superfluid thermodynamic cycle refrigerator

    DOE Patents [OSTI]

    Swift, Gregory W. (Santa Fe, NM); Kotsubo, Vincent Y. (La Canada, CA)

    1992-01-01

    A cryogenic refrigerator cools a heat source by cyclically concentrating and diluting the amount of .sup.3 He in a single phase .sup.3 He-.sup.4 He solution. The .sup.3 He in superfluid .sup.4 He acts in a manner of an ideal gas in a vacuum. Thus, refrigeration is obtained using any conventional thermal cycle, but preferably a Stirling or Carnot cycle. A single phase solution of liquid .sup.3 He at an initial concentration in superfluid .sup.4 He is contained in a first variable volume connected to a second variable volume through a superleak device that enables free passage of .sup.4 He while restricting passage of .sup.3 He. The .sup.3 He is compressed (concentrated) and expanded (diluted) in a phased manner to carry out the selected thermal cycle to remove heat from the heat load for cooling below 1 K.

  19. Compact acoustic refrigerator

    DOE Patents [OSTI]

    Bennett, Gloria A. (Los Alamos, NM)

    1992-01-01

    A compact acoustic refrigeration system actively cools components, e.g., electrical circuits (22), in a borehole environment. An acoustic engine (12, 14) includes first thermodynamic elements (12) for generating a standing acoustic wave in a selected medium. An acoustic refrigerator (16, 26, 28) includes second thermodynamic elements (16) located in the standing wave for generating a relatively cold temperature at a first end of the second thermodynamic elements (16) and a relatively hot temperature at a second end of the second thermodynamic elements (16). A resonator volume (18) cooperates with the first and second thermodynamic elements (12, 16) to support the standing wave. To accommodate the high heat fluxes required for heat transfer to/from the first and second thermodynamic elements (12, 16), first heat pipes (24, 26) transfer heat from the heat load (22) to the second thermodynamic elements (16) and second heat pipes (28, 32) transfer heat from first and second thermodynamic elements (12, 16) to the borehole environment.

  20. Compact acoustic refrigerator

    DOE Patents [OSTI]

    Bennett, G.A.

    1992-11-24

    A compact acoustic refrigeration system actively cools components, e.g., electrical circuits, in a borehole environment. An acoustic engine includes first thermodynamic elements for generating a standing acoustic wave in a selected medium. An acoustic refrigerator includes second thermodynamic elements located in the standing wave for generating a relatively cold temperature at a first end of the second thermodynamic elements and a relatively hot temperature at a second end of the second thermodynamic elements. A resonator volume cooperates with the first and second thermodynamic elements to support the standing wave. To accommodate the high heat fluxes required for heat transfer to/from the first and second thermodynamic elements, first heat pipes transfer heat from the heat load to the second thermodynamic elements and second heat pipes transfer heat from first and second thermodynamic elements to the borehole environment. 18 figs.

  1. Refrigerants in Transition 

    E-Print Network [OSTI]

    Stouppe, D. E.

    1991-01-01

    . 27-30. 7. Hayes, Floyd C., "Centrifugal\\~ater Chillers," CFCs: Today's Options Tomorrow's Solutions, ASHRAE Publication, Atlanta, GA, 1990, pp. 71-73. 8. Lorenz, Michael R., "CFCs: The Designer's Dilemma," Heating/Piping/Air Conditioning, April 1990... IN TRANSITION DAVID E. STOUPPE, P.E. Senior Engineer The Hartford Steam Boiler Inspection and Insurance Company Hartford,. Connecticut ABSTRACT The massive growth of air conditioning and refrigeration has been a direct result of the development of a...

  2. Magnetic Refrigeration | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and it will become hotter. Move it away (demagnetization) and the food cools down. GE researchers predict the cooling refrigerators could reduce energy consumption by 20%, in...

  3. Recovery of critical and value metals from mobile electronics enabled by electrochemical processing

    SciTech Connect (OSTI)

    Tedd E. Lister; Peiming Wang; Andre Anderko

    2014-10-01

    Electrochemistry-based schemes were investigated as a means to recover critical and value metals from scrap mobile electronics. Mobile electronics offer a growing feedstock for replenishing value and critical metals and reducing need to exhaust primary sources. The electrorecycling process generates oxidizing agents at an anode to dissolve metals from the scrap matrix while reducing dissolved metals at the cathode. The process uses a single cell to maximize energy efficiency. E vs pH diagrams and metals dissolution experiments were used to assess effectiveness of various solution chemistries. Following this work, a flow chart was developed where two stages of electrorecycling were proposed: 1) initial dissolution of Cu, Sn, Ag and magnet materials using Fe+3 generated in acidic sulfate and 2) final dissolution of Pd and Au using Cl2 generated in an HCl solution. Experiments were performed using a simulated metal mixture equivalent to 5 cell phones. Both Cu and Ag were recovered at ~ 97% using Fe+3 while leaving Au and Pd intact. Strategy for extraction of rare earth elements (REE) from dissolved streams is discussed as well as future directions in process development.

  4. Electrochemical planarization for multilevel metallization

    SciTech Connect (OSTI)

    Contolini, R.J.; Bernhardt, A.F.; Mayer, S.T. (Lawrence Livermore National Lab., Livermore, CA (United States))

    1994-09-01

    The authors describe an electrochemical planarization technology involving electroplating followed by electropolishing, resulting in a very flat surface containing embedded conductors. Electrochemical planarization technology has been used to produce silicon substrate multichip modules. Both the electroplating and electropolishing processes have a thickness uniformity of better than [+-] 2% ([+-]3[sigma]) across a 100 mm wafer.

  5. Electrochemical photovoltaic cells and electrodes

    DOE Patents [OSTI]

    Skotheim, Terje A. (East Patchogue, NY)

    1984-01-01

    Improved electrochemical photovoltaic cells and electrodes for use therein, particularly electrodes employing amorphous silicon or polyacetylene coating are produced by a process which includes filling pinholes or porous openings in the coatings by electrochemical oxidation of selected monomers to deposit insulating polymer in the openings.

  6. Case Study: Transcritical Carbon Dioxide Supermarket Refrigeration...

    Broader source: Energy.gov (indexed) [DOE]

    Low-Emission Refrigeration System Research & Development Roadmap: Next-Generation Low Global Warming Potential Refrigerants Energy Savings Potential and RD&D Opportunities for...

  7. New Energy Efficiency Standards for Commercial Refrigeration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Commercial Refrigeration Equipment to Cut Businesses' Energy Bills and Carbon Pollution New Energy Efficiency Standards for Commercial Refrigeration Equipment to Cut...

  8. New Supermarket Refrigeration Systems Reduce Cost

    Office of Energy Efficiency and Renewable Energy (EERE)

    Traditional supermarket refrigeration systems found in most grocery stores across the country are vulnerable to issues which can cause significant refrigerant leakage – especially with older...

  9. New Advanced Refrigeration Technology Provides Clean Energy,...

    Office of Environmental Management (EM)

    Refrigeration Technology Provides Clean Energy, Low Utility Bills for Supermarkets New Advanced Refrigeration Technology Provides Clean Energy, Low Utility Bills for...

  10. Electrochemical Techniques

    SciTech Connect (OSTI)

    Chen, Gang; Lin, Yuehe

    2008-07-20

    Sensitive and selective detection techniques are of crucial importance for capillary electrophoresis (CE), microfluidic chips, and other microfluidic systems. Electrochemical detectors have attracted considerable interest for microfluidic systems with features that include high sensitivity, inherent miniaturization of both the detection and control instrumentation, low cost and power demands, and high compatibility with microfabrication technology. The commonly used electrochemical detectors can be classified into three general modes: conductimetry, potentiometry, and amperometry.

  11. General Guidelines for the Disposal of Refrigerators, Freezers, and other Refrigeration Abandon or dispose of refrigerators, freezers, or window air conditioning units in

    E-Print Network [OSTI]

    Cina, Jeff

    not Abandon or dispose of refrigerators, freezers, or window air conditioning units in dumpsters or in common working and nonworking household refrigeration units (refrigerators, freezers, window air conditioning

  12. Electrochemical Processes for Removing

    E-Print Network [OSTI]

    Fay, Noah

    in boilers for electric power generation and evaporative cooling need to have potential scale of ion exchange media produces large quantities of brine. For example, a single regeneration cycle can

  13. Cryogenic refrigeration apparatus

    DOE Patents [OSTI]

    Crunkleton, James A. (Cambridge, MA)

    1992-01-01

    A technique for producing a cold environment in a refrigerant system in which input fluid from a compressor at a first temperature is introduced into an input channel of the system and is pre-cooled to a second temperature for supply to one of at least two stages of the system, and to a third temperature for supply to another stage thereof. The temperatures at such stages are reduced to fourth and fifth temperatures below the second and third temperatures, respectively. Fluid at the fourth temperature from the one stage is returned through the input channel to the compressor and fluid at the fifth temperature from the other stage is returned to the compressor through an output channel so that pre-cooling of the input fluid to the one stage occurs by regenerative cooling and counterflow cooling and pre-cooling of the input fluid to the other stage occurs primarily by counterflow cooling.

  14. Cryogenic refrigeration apparatus

    DOE Patents [OSTI]

    Crunkleton, J.A.

    1992-03-31

    A technique for producing a cold environment in a refrigerant system in which input fluid from a compressor at a first temperature is introduced into an input channel of the system and is pre-cooled to a second temperature for supply to one of at least two stages of the system, and to a third temperature for supply to another stage thereof. The temperatures at such stages are reduced to fourth and fifth temperatures below the second and third temperatures, respectively. Fluid at the fourth temperature from the one stage is returned through the input channel to the compressor and fluid at the fifth temperature from the other stage is returned to the compressor through an output channel so that pre-cooling of the input fluid to the one stage occurs by regenerative cooling and counterflow cooling and pre-cooling of the input fluid to the other stage occurs primarily by counterflow cooling. 6 figs.

  15. Electrochemical cell

    DOE Patents [OSTI]

    Redey, L.I.; Vissers, D.R.; Prakash, J.

    1996-07-16

    An electrochemical cell is described having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm{sup 3}; the cell can be 90% recharged in three hours and can operate at temperatures below 160 C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6{times}10{sup 4}cm{sup 2}/g of Ni. 6 figs.

  16. Electrochemical cell

    DOE Patents [OSTI]

    Redey, L.I.; Vissers, D.R.; Prakash, J.

    1994-02-01

    An electrochemical cell is described having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm[sup 3]; the cell can be 90% recharged in three hours and can operate at temperatures below 160 C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6[times]10[sup 4] cm[sup 2]/g of Ni. 8 figures.

  17. Electrochemical cell

    DOE Patents [OSTI]

    Redey, Laszlo I. (Downers Grove, IL); Vissers, Donald R. (Naperville, IL); Prakash, Jai (Downers Grove, IL)

    1994-01-01

    An electrochemical cell having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm.sup.3 ; the cell can be 90% recharged in three hours and can operate at temperatures below 160.degree. C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6.times.10.sup.4 cm.sup.2 /g of Ni.

  18. Electrochemical cell

    DOE Patents [OSTI]

    Redey, Laszlo I. (6851 Carpenter St., Downers Grove, IL 60516); Vissers, Donald R. (611 Clover Ct., Naperville, IL 60540); Prakash, Jai (2205 Arbor Cir. 8, Downers Grove, IL 60515)

    1996-01-01

    An electrochemical cell having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm.sup.3 ; the cell can be 90% recharged in three hours and can operate at temperatures below 160.degree. C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6.times.10.sup.4 cm.sup.2 /g of Ni.

  19. Coating Active Materials for Applications in Electrochemical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coating Active Materials for Applications in Electrochemical Devices Technology available for licensing: A process that includes suspendingdissolving an electro-active material...

  20. Low-Cost Electrochemical Compressor Utilizing Green Refrigerants for HVAC

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested Parties - WAPA PublicLED1,400 Jobs |Inc. | Department of

  1. Electrochemical construction

    DOE Patents [OSTI]

    Einstein, Harry (Springfield, NJ); Grimes, Patrick G. (Westfield, NJ)

    1983-08-23

    An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.

  2. Electrochemical device

    DOE Patents [OSTI]

    Grimes, Patrick G. (Westfield, NJ); Einstein, Harry (Springfield, NJ); Bellows, Richard J. (Westfield, NJ)

    1988-01-12

    A tunnel protected electrochemical device features channels fluidically communicating between manifold, tunnels and cells. The channels are designed to provide the most efficient use of auxiliary power. The channels have a greater hydraulic pressure drop and electrical resistance than the manifold. This will provide a design with the optimum auxiliary energy requirements.

  3. Electrochemical components employing polysiloxane-derived binders

    DOE Patents [OSTI]

    Delnick, Frank M.

    2013-06-11

    A processed polysiloxane resin binder for use in electrochemical components and the method for fabricating components with the binder. The binder comprises processed polysiloxane resin that is partially oxidized and retains some of its methyl groups following partial oxidation. The binder is suitable for use in electrodes of various types, separators in electrochemical devices, primary lithium batteries, electrolytic capacitors, electrochemical capacitors, fuel cells and sensors.

  4. Development of Versatile Compressor Modeling using Approximation Techniques for Alternative Refrigerants Evaluation

    SciTech Connect (OSTI)

    Abdelaziz, Omar; Shrestha, Som S

    2014-01-01

    Refrigerants are the life-blood of vapor compression systems that are widely used in Heating, Ventilation, Air-Conditioning, and Refrigeration (HVAC&R) applications. The HVAC&R community is currently transitioning from main-stream refrigerants that have high Global Warming Potential (GWP) to alternative lower-GWP refrigerants. During this transition, it is important to account for the life cycle climate performance of alternative refrigerants since their performance will be different than that of higher-GWP refrigerants. This requires the evaluation of the system performance with the new refrigerants. Unfortunately, it is extremely difficult to predict the realistic performance of new alternative refrigerants without experimental validation. One of the main challenges in this regard is modeling the compressor performance with high fidelity due to the complex interaction of operating parameters, geometry, boundary conditions, and fluid properties. High fidelity compressor models are computationally expensive and require significant pre-processing to evaluate the performance of alternative refrigerants. This paper presents a new approach to modeling compressor performance when alternative refrigerants are used. The new modeling concept relies on using existing compressor performance to create an approximate model that captures the dependence of compressor performance on key operating parameters and fluid properties. The model can be built using a myriad of approximation techniques. This paper focuses on Kriging-based techniques to develop higher fidelity approximate compressor models. Baseline and at least one alternative refrigerant performance data are used to build the model. The model accuracy was evaluated by comparing the model results with compressor performance data using other refrigerants. Preliminary results show that the approximate model can predict the compressor mass flow rate and power consumption within 5%.

  5. Electrochemical cell

    SciTech Connect (OSTI)

    Walsh, F.M.

    1986-12-23

    This patent describes an electrochemical cell having a metal anode wherein the metal is selected from zinc and cadmium; a bromine cathode; and an aqueous electrolyte containing a metal bromide, the metal bromide having the same metal as the metal of the anode. The improvement described here comprises: a bromine complexing agent in the aqueous metal bromide electrolyte, the complexing agent consisting solely of a quaternary ammonium salt of an N-organo substituted alpha amino acid, ester, or betaine.

  6. Alternative Refrigerant Evaluation for High-Ambient-Temperature Environments: R-22 and R-410A Alternatives for Mini-Split Air Conditioners

    SciTech Connect (OSTI)

    Abdelaziz, Omar; Shrestha, Som S.; Munk, Jeffrey D.; Linkous, Randall Lee; Goetzler, William; Guernsey, Matt; Kassuga, Theo

    2015-10-01

    The Oak Ridge National Laboratory (ORNL) High-Ambient-Temperature Evaluation Program for low– global warming potential (Low-GWP) Refrigerants aims to develop an understanding of the performance of low-GWP alternative refrigerants to hydrochlorofluorocarbon (HCFC) and hydrofluorocarbon (HFC) refrigerants in mini-split air conditioners under high-ambient-temperature conditions. This final report describes the parties involved, the alternative refrigerant selection process, the test procedures, and the final results.

  7. Electrochemical cell

    DOE Patents [OSTI]

    Nagy, Z.; Yonco, R.M.; You, H.; Melendres, C.A.

    1992-08-25

    An electrochemical cell has a layer-type or sandwich configuration with a Teflon center section that houses working, reference and counter electrodes and defines a relatively narrow electrolyte cavity. The center section is surrounded on both sides with thin Teflon membranes. The membranes are pressed in place by a pair of Teflon inner frames which are in turn supported by a pair of outer metal frames. The pair of inner and outer frames are provided with corresponding, appropriately shaped slits that are in plane generally transverse to the plane of the working electrode and permit X-ray beams to enter and exit the cell through the Teflon membranes that cover the slits so that the interface between the working electrode and the electrolyte within the cell may be analyzed by transmission geometry. In one embodiment, the center section consists of two parts, one on top of the other. Alternatively, the center section of the electrochemical cell may consist of two intersliding pieces or may be made of a single piece of Teflon sheet material. The electrolyte cavity is shaped so that the electrochemical cell can be rotated 90[degree] in either direction while maintaining the working and counter electrodes submerged in the electrolyte. 5 figs.

  8. International Refrigeration: Order (2012-CE-1510)

    Broader source: Energy.gov [DOE]

    DOE ordered International Refrigeration Products to pay an $8,000 civil penalty after finding International Refrigeration had failed to certify that certain room air conditioners comply with the applicable energy conservation standard.

  9. Thermoelectric refrigerator having improved temperature stabilization means

    DOE Patents [OSTI]

    Falco, Charles M. (Woodridge, IL)

    1982-01-01

    A control system for thermoelectric refrigerators is disclosed. The thermoelectric refrigerator includes at least one thermoelectric element that undergoes a first order change at a predetermined critical temperature. The element functions as a thermoelectric refrigerator element above the critical temperature, but discontinuously ceases to function as a thermoelectric refrigerator element below the critical temperature. One example of such an arrangement includes thermoelectric refrigerator elements which are superconductors. The transition temperature of one of the superconductor elements is selected as the temperature control point of the refrigerator. When the refrigerator attempts to cool below the point, the metals become superconductors losing their ability to perform as a thermoelectric refrigerator. An extremely accurate, first-order control is realized.

  10. Wheel-type magnetic refrigerator

    DOE Patents [OSTI]

    Barclay, J.A.

    1982-01-20

    The disclosure is directed to a wheel-type magnetic refrigerator capable of cooling over a large temperature range. Ferromagnetic or paramagnetic porous materials are layered circumferentially according to their Curie temperature. The innermost layer has the lowest Curie temperature and the outermost layer has the highest Curie temperature. The wheel is rotated through a magnetic field perpendicular to the axis of the wheel and parallel to its direction of rotation. A fluid is pumped through portions of the layers using inner and outer manifolds to achieve refrigeration of a thermal load.

  11. Wheel-type magnetic refrigerator

    DOE Patents [OSTI]

    Barclay, J.A.

    1983-10-11

    The disclosure is directed to a wheel-type magnetic refrigerator capable of cooling over a large temperature range. Ferromagnetic or paramagnetic porous materials are layered circumferentially according to their Curie temperature. The innermost layer has the lowest Curie temperature and the outermost layer has the highest Curie temperature. The wheel is rotated through a magnetic field perpendicular to the axis of the wheel and parallel to its direction of rotation. A fluid is pumped through portions of the layers using inner and outer manifolds to achieve refrigeration of a thermal load. 7 figs.

  12. Ternary Dy-Er-Al magnetic refrigerants

    DOE Patents [OSTI]

    Gschneidner, K.A. Jr.; Takeya, Hiroyuki

    1995-07-25

    A ternary magnetic refrigerant material comprising (Dy{sub 1{minus}x}Er{sub x})Al{sub 2} for a magnetic refrigerator using the Joule-Brayton thermodynamic cycle spanning a temperature range from about 60K to about 10K, which can be adjusted by changing the Dy to Er ratio of the refrigerant. 29 figs.

  13. Natural Refrigerant, Geothermal Heating & Cooling Solutions

    E-Print Network [OSTI]

    properties Kilmarnock Scotland demonstration History of Carbon Dioxide (R744) as Refrigerant CO2 proposed · Introduction to Thar Geothermal · Carbon Dioxide (R744) the Environmentally Exceptional Refrigerant · Thar Scale, Direct Exchange Design Carbon Dioxide (co2) R744 the Safe & Natural Refrigerant #12;150 Gamma

  14. Electrochemical cell

    DOE Patents [OSTI]

    Redey, L.I.; Vissers, D.R.; Prakash, J.

    1994-08-23

    An electrochemical cell is described having an alkali metal negative electrode such as sodium and a positive electrode including Ni or transition metals, separated by a [beta] alumina electrolyte and NaAlCl[sub 4] or other compatible material. Various concentrations of a bromine, iodine and/or sulfur containing additive and pore formers are disclosed, which enhance cell capacity and power. The pore formers may be the ammonium salts of carbonic acid or a weak organic acid or oxamide or methylcellulose. 6 figs.

  15. page 1 of 4 TkF Vrmeteknik Refrigeration / Kylteknik

    E-Print Network [OSTI]

    Zevenhoven, Ron

    devices. 201. An office is heated using a heat pump system based on a vapour-compression cycle is the compressor work w (kJ/kg refrigerant) (2 p.) c. What is the coefficient of performance COP of this heat pump? Compare it with the COP of a Carnot process heat pump operating between -20°C and 30°C. (2 p.) d

  16. Demand Response Opportunities in Industrial Refrigerated Warehouses in California

    SciTech Connect (OSTI)

    Goli, Sasank; McKane, Aimee; Olsen, Daniel

    2011-06-14

    Industrial refrigerated warehouses that implemented energy efficiency measures and have centralized control systems can be excellent candidates for Automated Demand Response (Auto-DR) due to equipment synergies, and receptivity of facility managers to strategies that control energy costs without disrupting facility operations. Auto-DR utilizes OpenADR protocol for continuous and open communication signals over internet, allowing facilities to automate their Demand Response (DR). Refrigerated warehouses were selected for research because: They have significant power demand especially during utility peak periods; most processes are not sensitive to short-term (2-4 hours) lower power and DR activities are often not disruptive to facility operations; the number of processes is limited and well understood; and past experience with some DR strategies successful in commercial buildings may apply to refrigerated warehouses. This paper presents an overview of the potential for load sheds and shifts from baseline electricity use in response to DR events, along with physical configurations and operating characteristics of refrigerated warehouses. Analysis of data from two case studies and nine facilities in Pacific Gas and Electric territory, confirmed the DR abilities inherent to refrigerated warehouses but showed significant variation across facilities. Further, while load from California's refrigerated warehouses in 2008 was 360 MW with estimated DR potential of 45-90 MW, actual achieved was much less due to low participation. Efforts to overcome barriers to increased participation may include, improved marketing and recruitment of potential DR sites, better alignment and emphasis on financial benefits of participation, and use of Auto-DR to increase consistency of participation.

  17. Load Forecasting of Supermarket Refrigeration

    E-Print Network [OSTI]

    @compute.dtu.dk www.compute.dtu.dk M.Sc.-2013-87 #12;Summary (English) The Danish power production coming from energy system. Observed refrigeration load and local ambient temperature from a Danish su- permarket renewable energy, is increasing, therefore a flexible energy system is needed. In the present Thesis

  18. A recuperative superfluid stirling refrigerator

    SciTech Connect (OSTI)

    Brisson, J.G.; Swift, G.W.

    1993-07-01

    A superfluid Stirling refrigerator has been built with a counterflow heat exchanger serving as a recuperative regenerator. It has achieved temperatures of 296 mK with a 4% {sup 3}He-{sup 4}He mixture. Cooling power versus temperature and speed is presented for a 6.6% mixture.

  19. Low-temperature magnetic refrigerator

    DOE Patents [OSTI]

    Barclay, John A. (Los Alamos, NM)

    1985-01-01

    The disclosure is directed to a low temperature 4 to 20 K. refrigeration apparatus and method utilizing a ring of magnetic material moving through a magnetic field. Heat exchange is accomplished in and out of the magnetic field to appropriately utilize the device to execute Carnot and Stirling cycles.

  20. Opportunities for Energy Efficiency and Automated Demand Response in Industrial Refrigerated Warehouses in California

    E-Print Network [OSTI]

    Lekov, Alex

    2009-01-01

    48 hrs if doors o Cold Storage (Ammonia chiller 1: 450 ton,o Building 2: Cold storage, 54000 sq ft (2 ammonia chillersAmmonia is the most commonly used refrigerant for food processing and storage

  1. Electrochemical supercapacitors

    DOE Patents [OSTI]

    Rudge, Andrew J. (Los Alamos, NM); Ferraris, John P. (Dallas, TX); Gottesfeld, Shimshon (Los Alamos, NM)

    1996-01-01

    A new class of electrochemical capacitors provides in its charged state a positive electrode including an active material of a p-doped material and a negative electrode including an active material of an n-doped conducting polymer, where the p-doped and n-doped materials are separated by an electrolyte. In a preferred embodiment, the positive and negative electrode active materials are selected from conducting polymers consisting of polythiophene, polymers having an aryl group attached in the 3-position, polymers having aryl and alkyl groups independently attached in the 3- and 4-positions, and polymers synthesized from bridged dimers having polythiophene as the backbone. A preferred electrolyte is a tetraalykyl ammonium salt, such as tetramethylammonium trifluoromethane sulphonate (TMATFMS), that provides small ions that are mobile through the active material, is soluble in acetonitrile, and can be used in a variety of capacitor configurations.

  2. Energy Efficient Commercial Refrigeration with Carbon Dioxide Refrigerant and Scroll Expanders

    SciTech Connect (OSTI)

    Dieckmann, John

    2013-04-04

    Current supermarket refrigeration systems are built around conventional fluorocarbon refrigerants – HFC-134a and the HFC blends R-507 and R404A, which replaced the CFC refrigerants, R-12 and R-502, respectively, used prior to the Montreal Protocol phase out of ozone depleting substances. While the HFC refrigerants are non-ozone depleting, they are strong greenhouse gases, so there has been continued interest in replacing them, particularly in applications with above average refrigerant leakage. Large supermarket refrigeration systems have proven to be particularly difficult to maintain in a leak-tight condition. Refrigerant charge losses of 15% of total charge per year are the norm, making the global warming impact of refrigerant emissions comparable to that associated with the energy consumption of these systems.

  3. Materials Compatibility and Lubricants Research on CFC-refrigerant substitutes. Quarterly MCLR Program technical progress report, July 1--September 30, 1995

    SciTech Connect (OSTI)

    Szymurski, S.R.; Hourahan, G.C.; Godwin, D.S.; Amrane, K.

    1995-10-01

    The Materials Compatibility and Lubricants Research (MCLR) program supports critical research to accelerate the introduction of CFC and HCFC refrigerant substitutes. The MCLR program addresses refrigerant and lubricant properties and materials compatibility. The primary elements of the work include data collection and dissemination, materials compatibility testing, and methods development. This report summarizes the research conducted during the third quarter of calendar year 1995 on the following projects: Thermophysical properties of HCFC alternatives; Compatibility of manufacturing process fluids with HFC refrigerants and ester lubricants; Compatibility of motor materials used in air-conditioning for retrofits with alternative refrigerants and lubricants; Compatibility of lubricant additives with HFC refrigerants and synthetic lubricants; Products of motor burnouts; Accelerated test methods for predicting the life of motor materials exposed to refrigerant-lubricant mixtures; Investigation of flushing and clean-out methods; Investigation into the fractionation of refrigerant blends; Lean flammability limits as a fundamental refrigerant property; Effect of selected contaminants in AC and R equipment; Study of foaming characteristics; Study of lubricant circulation in systems; Evaluation of HFC-245ca for commercial use in low pressure chillers; Infrared analysis of refrigerant mixtures; Refrigerant database; Refrigerant toxicity survey; Thermophysical properties of HFC-32, HFC-123, HCFC-124 and HFC-125; Thermophysical properties of HFC-143a and HFC-152a; Theoretical evaluations of R-22 alternative fluids; Chemical and thermal stability of refrigerant-lubricant mixtures with metals; Miscibility of lubricants with refrigerants; Viscosity, solubility and density measurements of refrigerant-lubricant mixtures; Electrohydrodynamic enhancement of pool and in-tube boiling of alternative refrigerants; Accelerated screening methods; and more.

  4. Microfluidic electrochemical reactors

    DOE Patents [OSTI]

    Nuzzo, Ralph G. (Champaign, IL); Mitrovski, Svetlana M. (Urbana, IL)

    2011-03-22

    A microfluidic electrochemical reactor includes an electrode and one or more microfluidic channels on the electrode, where the microfluidic channels are covered with a membrane containing a gas permeable polymer. The distance between the electrode and the membrane is less than 500 micrometers. The microfluidic electrochemical reactor can provide for increased reaction rates in electrochemical reactions using a gaseous reactant, as compared to conventional electrochemical cells. Microfluidic electrochemical reactors can be incorporated into devices for applications such as fuel cells, electrochemical analysis, microfluidic actuation, pH gradient formation.

  5. Recognized Leader in Electrochemical Purification

    SciTech Connect (OSTI)

    Hoppe, Eric

    2013-11-20

    PNNL scientists developed an electrochemical method for purifying copper, a key material that makes possible radiation detection systems of unprecedented sensitivity. The method begins with the purest copper materials available, and results in the lowest-background copper in the world. Chemist Eric Hoppe explains the process.

  6. Recognized Leader in Electrochemical Purification

    ScienceCinema (OSTI)

    Hoppe, Eric

    2014-07-24

    PNNL scientists developed an electrochemical method for purifying copper, a key material that makes possible radiation detection systems of unprecedented sensitivity. The method begins with the purest copper materials available, and results in the lowest-background copper in the world. Chemist Eric Hoppe explains the process.

  7. New age water chillers with water as refrigerant

    E-Print Network [OSTI]

    Kühnl-Kinel, J

    1998-01-01

    Vacuum-process technology producing chilled water needs no refrigerant of the conventional kind, but water from the process itself is used to generate cooling. This eye-catching novelty incorporates many of the considerations about the future of refrigerants: "ozone friendly", no extra demands for safety measures or for skilful operators, no special requirements concerning the installation's components, lower maintenance costs since leakages can be accommodated from the system. Vacuum-process technology may be used not only for production of chilled water but also for Binary Ice - pumpable suspension of minute ice crystals in an aqueous solution. This means that all the advantages related to a latent heat system may become available.

  8. M. Bahrami ENSC 461 (S 11) Refrigeration Cycle 1 Refrigeration Cycle

    E-Print Network [OSTI]

    Bahrami, Majid

    COP W Q COP , , The Reversed Carnot Cycle Reversing the Carnot cycle does reverse the directions of heat and work interactions. A refrigerator or heat pump that operates on the reversed Carnot cycle refrigerator. The reversed Carnot cycle is the most efficient refrigeration cycle operating between two

  9. Working Fluids Low Global Warming Potential Refrigerants

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    by 50% compared to today's best common practice - Alternative refrigerants with low global warming potential (GWP) are needed to achieve these goals - Provide guidance to the...

  10. Covered Product Category: Commercial Refrigerators and Freezers

    Broader source: Energy.gov [DOE]

    The Federal Energy Management Program (FEMP) provides acquisition guidance for commercial refrigerators and freezers, which are covered by the ENERGY STAR program.

  11. Natural Refrigerant (R-729) Heat Pump

    Broader source: Energy.gov (indexed) [DOE]

    Natural Refrigerant (R-729) Heat Pump 2014 Building Technologies Office Peer Review New Project Lee Jestings (lee@S-RAM.com), Project Summary Timeline: Key Partners: Start date:...

  12. Multi-stage Cascaded Stirling Refrigerator

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Level: 7 - Full system prototype tested in a controlled environment Patent Status: Thermoacoustic Refrigerators and Engines Comprising Cascading Stirling Thermodynamic Units, US...

  13. Miniaturized Air-to-Refrigerant Heat Exchangers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    kW air-to-water and air-to- refrigerant heat exchangers Investigate conventional and additive manufacturing techniques Analyze system level performance of novel heat...

  14. High Efficiency Low Emission Refrigeration System

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency Low Emission Refrigeration System 2014 Building Technologies Office Peer Review Brian Fricke, frickeba@ornl.gov Oak Ridge National Laboratory Project Summary Timeline:...

  15. Miniaturized Air to Refrigerant Heat Exchangers | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in ORNL's Building Technologies Research & Integration Center. Working Fluids Low Global Warming Potential Refrigerants Improving Data Center Efficiency with Rack or Row...

  16. Covered Product Category: Refrigerated Beverage Vending Machines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    beverage vending machines are the General Services Administration (GSA) and Defense Logistics Agency (DLA). GSA sells refrigerated beverage vending machines through its...

  17. Investigation of pressure drop in capillary tube for mixed refrigerant Joule-Thomson cryocooler

    SciTech Connect (OSTI)

    Ardhapurkar, P. M.; Sridharan, Arunkumar; Atrey, M. D.

    2014-01-29

    A capillary tube is commonly used in small capacity refrigeration and air-conditioning systems. It is also a preferred expansion device in mixed refrigerant Joule-Thomson (MR J-T) cryocoolers, since it is inexpensive and simple in configuration. However, the flow inside a capillary tube is complex, since flashing process that occurs in case of refrigeration and air-conditioning systems is metastable. A mixture of refrigerants such as nitrogen, methane, ethane, propane and iso-butane expands below its inversion temperature in the capillary tube of MR J-T cryocooler and reaches cryogenic temperature. The mass flow rate of refrigerant mixture circulating through capillary tube depends on the pressure difference across it. There are many empirical correlations which predict pressure drop across the capillary tube. However, they have not been tested for refrigerant mixtures and for operating conditions of the cryocooler. The present paper assesses the existing empirical correlations for predicting overall pressure drop across the capillary tube for the MR J-T cryocooler. The empirical correlations refer to homogeneous as well as separated flow models. Experiments are carried out to measure the overall pressure drop across the capillary tube for the cooler. Three different compositions of refrigerant mixture are used to study the pressure drop variations. The predicted overall pressure drop across the capillary tube is compared with the experimentally obtained value. The predictions obtained using homogeneous model show better match with the experimental results compared to separated flow models.

  18. Electrochemical Biosensors: Recommended Definitions and Classification

    E-Print Network [OSTI]

    Wilson, George S.; Thé venot, Daniel R.; Toth, Klara; Durst, Richard A.

    1999-01-01

    with an electrochemical transduction element. Because of their ability to be repeatedly calibrated, we recommend that a biosensor should be clearly distinguished from a bioanalytical system, which requires additional processing steps, such as reagent addition. A device...

  19. Development of Microfluidic Devices Incorporating Electrochemical Detection

    E-Print Network [OSTI]

    Regel, Anne

    2014-05-31

    with electrochemical (EC) detection for the determination of dopamine and nitrite is described. Different fabrication processes were evaluated and optimized to create low cost polymer microchips. A polydimethylsiloxane (PDMS)/glass hybrid microchip capable...

  20. System and method for networking electrochemical devices

    DOE Patents [OSTI]

    Williams, Mark C. (Morgantown, WV); Wimer, John G. (Morgantown, WV); Archer, David H. (Pittsburgh, PA)

    1995-01-01

    An improved electrochemically active system and method including a plurality of electrochemical devices, such as fuel cells and fluid separation devices, in which the anode and cathode process-fluid flow chambers are connected in fluid-flow arrangements so that the operating parameters of each of said plurality of electrochemical devices which are dependent upon process-fluid parameters may be individually controlled to provide improved operating efficiency. The improvements in operation include improved power efficiency and improved fuel utilization in fuel cell power generating systems and reduced power consumption in fluid separation devices and the like through interstage process fluid parameter control for series networked electrochemical devices. The improved networking method includes recycling of various process flows to enhance the overall control scheme.

  1. Working Fluids Low Global Warming Potential Refrigerants | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Refrigerants Working Fluids Low Global Warming Potential Refrigerants Brian Fricke conducts research in ORNL's Building Technologies Research & Integration Center. Brian Fricke...

  2. Working Fluids Low Global Warming Potential Refrigerants - 2013...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Refrigerants - 2013 Peer Review Working Fluids Low Global Warming Potential Refrigerants - 2013 Peer Review Emerging Technologies Project for the 2013 Building Technologies...

  3. Thermodynamic Evaluation of Low-Global Warming Potential Refrigerants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Global Warming Potential Refrigerants - 2013 Peer Review Thermodynamic Evaluation of Low-Global Warming Potential Refrigerants - 2013 Peer Review Emerging Technologies Project for...

  4. Alternative Refrigerant Evaluation for High-Ambient-Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Low-GWP Refrigerants aims to develop an understanding of the performance of lower global warming potential (low-GWP) alternative refrigerants to hydrochlorofluorocarbon...

  5. Thermodynamic Evaluation of Low-Global-Warming-Potential Refrigerants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Global-Warming-Potential Refrigerants Thermodynamic Evaluation of Low-Global-Warming-Potential Refrigerants Lead Performer: National Institute of Standards and Technology -...

  6. High-Performance Refrigerator Using Novel Rotating Heat Exchanger...

    Energy Savers [EERE]

    Cooler relative to current heat exchanger technology are additional refrigerated space, noise reduction, and fouling reduction. Additional refrigerated volume realized by the more...

  7. Active Diesel Emission Control Technology for Transport Refrigeration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transport Refrigeration Units Active Diesel Emission Control Technology for Transport Refrigeration Units This project discusses a CARB Level 2+ verified active regeneration...

  8. China Refrigerator Information Label: Specification Development and Potential Impact

    E-Print Network [OSTI]

    Fridley, David

    2008-01-01

    Urban Refrigerator Stocks, 1990-2006 5 Figure 3 China's Energy Information Label for Refrigerators.. 6 Figure 4 China's Voluntary Energy Efficiency

  9. Air-Conditioning, Heating, and Refrigeration Institute (AHRI...

    Office of Environmental Management (EM)

    Air-Conditioning, Heating, and Refrigeration Institute (AHRI) Regulatory Burden RFI Air-Conditioning, Heating, and Refrigeration Institute (AHRI) Regulatory Burden RFI These...

  10. HEATING, AIR-CONDITIONING AND REFRIGERATION DISTRIBUTORS INTERNATIONAL...

    Energy Savers [EERE]

    HEATING, AIR-CONDITIONING AND REFRIGERATION DISTRIBUTORS INTERNATIONAL (HARDI) HEATING, AIR-CONDITIONING AND REFRIGERATION DISTRIBUTORS INTERNATIONAL (HARDI) OE Framework Document...

  11. Transportation Refrigeration Unit (TRU) Retrofit with HUSS Active...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transportation Refrigeration Unit (TRU) Retrofit with HUSS Active Diesel Particulate Filters Transportation Refrigeration Unit (TRU) Retrofit with HUSS Active Diesel Particulate...

  12. New Refrigerant Boosts Energy Efficiency of Supermarket Display...

    Energy Savers [EERE]

    New Refrigerant Boosts Energy Efficiency of Supermarket Display Cases New Refrigerant Boosts Energy Efficiency of Supermarket Display Cases February 20, 2015 - 4:55pm Addthis New...

  13. Alternative Refrigerant Evaluation for High-Ambient-Temperature...

    Office of Environmental Management (EM)

    Alternative Refrigerant Evaluation for High-Ambient-Temperature Environments: R-22 and R-410A Alternatives for Mini-Split Air Conditioners Alternative Refrigerant Evaluation for...

  14. Final Scientific/Technical Report for DOE/EERE project Advanced Magnetic Refrigerant Materials

    SciTech Connect (OSTI)

    Johnson, Francis

    2014-06-30

    A team led by GE Global Research developed new magnetic refrigerant materials needed to enhance the commercialization potential of residential appliances such as refrigerators and air conditioners based on the magnetocaloric effect (a nonvapor compression cooling cycle). The new magnetic refrigerant materials have potentially better performance at lower cost than existing materials, increasing technology readiness level. The performance target of the new magnetocaloric material was to reduce the magnetic field needed to achieve 4 °C adiabatic temperature change from 1.5 Tesla to 0.75 Tesla. Such a reduction in field minimizes the cost of the magnet assembly needed for a magnetic refrigerator. Such a reduction in magnet assembly cost is crucial to achieving commercialization of magnetic refrigerator technology. This project was organized as an iterative alloy development effort with a parallel material modeling task being performed at George Washington University. Four families of novel magnetocaloric alloys were identified, screened, and assessed for their performance potential in a magnetic refrigeration cycle. Compositions from three of the alloy families were manufactured into regenerator components. At the beginning of the project a previously studied magnetocaloric alloy was selected for manufacturing into the first regenerator component. Each of the regenerators was tested in magnetic refrigerator prototypes at a subcontractor at at GE Appliances. The property targets for operating temperature range, operating temperature control, magnetic field sensitivity, and corrosion resistance were met. The targets for adiabatic temperature change and thermal hysteresis were not met. The high thermal hysteresis also prevented the regenerator components from displaying measurable cooling power when tested in prototype magnetic refrigerators. Magnetic refrigerant alloy compositions that were predicted to have low hysteresis were not attainable with conventional alloy processing methods. Preliminary experiments with rapid solidification methods showed a path towards attaining low hysteresis compositions should this alloy development effort be continued.

  15. Hybridizing Energy Conversion and Storage in a Mechanical-to-Electrochemical Process for Self-Charging Power Cell

    E-Print Network [OSTI]

    Wang, Zhong L.

    Information ABSTRACT: Energy generation and energy storage are two distinct processes that are usually, such as piezoelectric nanogenerator and Li-ion battery; the former converts mechanical energy into electricity, and the latter stores electric energy as chemical energy. Here, we introduce a fundamental mechanism

  16. Seven-effect absorption refrigeration

    DOE Patents [OSTI]

    DeVault, R.C.; Biermann, W.J.

    1989-05-09

    A seven-effect absorption refrigeration cycle is disclosed utilizing three absorption circuits. In addition, a heat exchanger is used for heating the generator of the low absorption circuit with heat rejected from the condenser and absorber of the medium absorption circuit. A heat exchanger is also provided for heating the generator of the medium absorption circuit with heat rejected from the condenser and absorber of the high absorption circuit. If desired, another heat exchanger can also be provided for heating the evaporator of the high absorption circuit with rejected heat from either the condenser or absorber of the low absorption circuit. 1 fig.

  17. Steady-state operational degrees of freedom with application to refrigeration cycles

    E-Print Network [OSTI]

    Skogestad, Sigurd

    - position of the circulating refrigerant are also discussed. Two LNG processes of current interest, the C3MRTM LNG process from Air Products and the MFCTM process developed by Statoil-Linde LNG Technology. The optimal design of LNG processes has been studied extensively by several com- panies such as Air Products

  18. Counterflow absorber for an absorption refrigeration system

    DOE Patents [OSTI]

    Reimann, Robert C. (Lafayette, NY)

    1984-01-01

    An air-cooled, vertical tube absorber for an absorption refrigeration system is disclosed. Strong absorbent solution is supplied to the top of the absorber and refrigerant vapor is supplied to the bottom of the absorber to create a direct counterflow of refrigerant vapor and absorbent solution in the absorber. The refrigeration system is designed so that the volume flow rate of refrigerant vapor in the tubes of the absorber is sufficient to create a substantially direct counterflow along the entire length of each tube in the absorber. This provides several advantages for the absorber such as higher efficiency and improved heat transfer characteristics, and allows improved purging of non-condensibles from the absorber.

  19. Oil cooled, hermetic refrigerant compressor

    DOE Patents [OSTI]

    English, William A. (Murrysville, PA); Young, Robert R. (Murrysville, PA)

    1985-01-01

    A hermetic refrigerant compressor having an electric motor and compressor assembly in a hermetic shell is cooled by oil which is first cooled in an external cooler 18 and is then delivered through the shell to the top of the motor rotor 24 where most of it is flung radially outwardly within the confined space provided by the cap 50 which channels the flow of most of the oil around the top of the stator 26 and then out to a multiplicity of holes 52 to flow down to the sump and provide further cooling of the motor and compressor. Part of the oil descends internally of the motor to the annular chamber 58 to provide oil cooling of the lower part of the motor, with this oil exiting through vent hole 62 also to the sump. Suction gas with entrained oil and liquid refrigerant therein is delivered to an oil separator 68 from which the suction gas passes by a confined path in pipe 66 to the suction plenum 64 and the separated oil drops from the separator to the sump. By providing the oil cooling of the parts, the suction gas is not used for cooling purposes and accordingly increase in superheat is substantially avoided in the passage of the suction gas through the shell to the suction plenum 64.

  20. Oil cooled, hermetic refrigerant compressor

    DOE Patents [OSTI]

    English, W.A.; Young, R.R.

    1985-05-14

    A hermetic refrigerant compressor having an electric motor and compressor assembly in a hermetic shell is cooled by oil which is first cooled in an external cooler and is then delivered through the shell to the top of the motor rotor where most of it is flung radially outwardly within the confined space provided by the cap which channels the flow of most of the oil around the top of the stator and then out to a multiplicity of holes to flow down to the sump and provide further cooling of the motor and compressor. Part of the oil descends internally of the motor to the annular chamber to provide oil cooling of the lower part of the motor, with this oil exiting through vent hole also to the sump. Suction gas with entrained oil and liquid refrigerant therein is delivered to an oil separator from which the suction gas passes by a confined path in pipe to the suction plenum and the separated oil drops from the separator to the sump. By providing the oil cooling of the parts, the suction gas is not used for cooling purposes and accordingly increase in superheat is substantially avoided in the passage of the suction gas through the shell to the suction plenum. 3 figs.

  1. Circulating heat exchangers for oscillating wave engines and refrigerators

    DOE Patents [OSTI]

    Swift, Gregory W.; Backhaus, Scott N.

    2003-10-28

    An oscillating-wave engine or refrigerator having a regenerator or a stack in which oscillating flow of a working gas occurs in a direction defined by an axis of a trunk of the engine or refrigerator, incorporates an improved heat exchanger. First and second connections branch from the trunk at locations along the axis in selected proximity to one end of the regenerator or stack, where the trunk extends in two directions from the locations of the connections. A circulating heat exchanger loop is connected to the first and second connections. At least one fluidic diode within the circulating heat exchanger loop produces a superimposed steady flow component and oscillating flow component of the working gas within the circulating heat exchanger loop. A local process fluid is in thermal contact with an outside portion of the circulating heat exchanger loop.

  2. Dual-circuit, multiple-effect refrigeration system and method

    DOE Patents [OSTI]

    DeVault, Robert C. (Knoxville, TN)

    1995-01-01

    A dual circuit absorption refrigeration system comprising a high temperature single-effect refrigeration loop and a lower temperature double-effect refrigeration loop separate from one another and provided with a double-condenser coupling therebetween. The high temperature condenser of the single-effect refrigeration loop is double coupled to both of the generators in the double-effect refrigeration loop to improve internal heat recovery and a heat and mass transfer additive such as 2-ethyl-1-hexanol is used in the lower temperature double-effect refrigeration loop to improve the performance of the absorber in the double-effect refrigeration loop.

  3. Refrigerant charge management in a heat pump water heater

    DOE Patents [OSTI]

    Chen, Jie; Hampton, Justin W.

    2014-06-24

    Heat pumps that heat or cool a space and that also heat water, refrigerant management systems for such heat pumps, methods of managing refrigerant charge, and methods for heating and cooling a space and heating water. Various embodiments deliver refrigerant gas to a heat exchanger that is not needed for transferring heat, drive liquid refrigerant out of that heat exchanger, isolate that heat exchanger against additional refrigerant flowing into it, and operate the heat pump while the heat exchanger is isolated. The heat exchanger can be isolated by closing an electronic expansion valve, actuating a refrigerant management valve, or both. Refrigerant charge can be controlled or adjusted by controlling how much liquid refrigerant is driven from the heat exchanger, by letting refrigerant back into the heat exchanger, or both. Heat pumps can be operated in different modes of operation, and segments of refrigerant conduit can be interconnected with various components.

  4. Bearing construction for refrigeration compresssor

    DOE Patents [OSTI]

    Middleton, Marc G. (Wyoming, MI); Nelson, Richard T. (Worthington, OH)

    1988-01-01

    A hermetic refrigeration compressor has a cylinder block and a crankshaft rotatable about a vertical axis to reciprocate a piston in a cylinder on the cylinder block. A separate bearing housing is secured to the central portion of the cylinder block and extends vertically along the crankshaft, where it carries a pair of roller bearings to journal the crankshaft. The crankshaft has a radially extending flange which is journaled by a thrust-type roller bearing above the bearing housing to absorb the vertical forces on the crankshaft so that all three of the roller bearings are between the crankshaft and the bearing housing to maintain and control the close tolerances required by such bearings.

  5. Solid-Vapor Sorption Refrigeration Systems 

    E-Print Network [OSTI]

    Graebel, W.; Rockenfeller, U.; Kirol, L.

    1991-01-01

    sorption media. 'i: ! 60 1 60 I 40 SO I 20 a 10 J 0 CC48G-1110 AclivallJd carbon Uquld-II0p0r ~OO-1300 Zealllll Figure 2. Useable refrigerant densities. Summarizing, complex compound exhibit inherent characteristics which make them ideal... refrigerant density than is attainable with any other sorption media. Figure 2 shows usable refrigerant densities for complex compounds and other sorption media. 'i: ! 80 60 1 40 SO 20 a 10 J 0 CC48G-1110 AcIivallld carbon Uqukl-II0p0r ~OO-1300Zaalllll Figure...

  6. Electrochemical methane sensor

    DOE Patents [OSTI]

    Zaromb, S.; Otagawa, T.; Stetter, J.R.

    1984-08-27

    A method and instrument including an electrochemical cell for the detection and measurement of methane in a gas by the oxidation of methane electrochemically at a working electrode in a nonaqueous electrolyte at a voltage about 1.4 volts vs R.H.E. (the reversible hydrogen electrode potential in the same electrolyte), and the measurement of the electrical signal resulting from the electrochemical oxidation.

  7. Status of not-in-kind refrigeration technologies for household space conditioning, water heating and food refrigeration

    SciTech Connect (OSTI)

    Bansal, Pradeep; Vineyard, Edward Allan; Abdelaziz, Omar

    2012-01-01

    This paper presents a review of the next generation not-in-kind technologies to replace conventional vapor compression refrigeration technology for household applications. Such technologies are sought to provide energy savings or other environmental benefits for space conditioning, water heating and refrigeration for domestic use. These alternative technologies include: thermoacoustic refrigeration, thermoelectric refrigeration, thermotunneling, magnetic refrigeration, Stirling cycle refrigeration, pulse tube refrigeration, Malone cycle refrigeration, absorption refrigeration, adsorption refrigeration, and compressor driven metal hydride heat pumps. Furthermore, heat pump water heating and integrated heat pump systems are also discussed due to their significant energy saving potential for water heating and space conditioning in households. The paper provides a snapshot of the future R&D needs for each of the technologies along with the associated barriers. Both thermoelectric and magnetic technologies look relatively attractive due to recent developments in the materials and prototypes being manufactured.

  8. Defrost Temperature Termination in Supermarket Refrigeration Systems

    SciTech Connect (OSTI)

    Fricke, Brian A; Sharma, Vishaldeep

    2011-11-01

    The objective of this project was to determine the potential energy savings associated with implementing demand defrost strategies to defrost supermarket refrigerated display case evaporators, as compared to the widely accepted current practice of controlling display case defrost cycles with a preset timer. The defrost heater energy use of several representative display case types was evaluated. In addition, demand defrost strategies for refrigerated display cases as well as those used in residential refrigerator/freezers were evaluated. Furthermore, it is anticipated that future work will include identifying a preferred defrost strategy, with input from Retail Energy Alliance members. Based on this strategy, a demand defrost system will be designed which is suitable for supermarket refrigerated display cases. Limited field testing of the preferred defrost strategy will be performed in a supermarket environment.

  9. Refrigerator Manufacturers: Proposed Penalty (2013-CE-5341)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Refrigerator Manufacturers, LLC failed to certify a variety of walk-in cooler or freezer components as compliant with the applicable energy conservation standards.

  10. Cospolich Refrigerator: Proposed Penalty (2013-CE-5314)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Cospolich Refrigerator Co, Inc. failed to certify walk-in cooler or freezer components as compliant with the energy conservation standards.

  11. Covered Product Category: Commercial Refrigerators and Freezers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    assumptions: Assumes 24-ft3 capacity, vertical, solid-door refrigerators operated year round. The performance of the less efficient model just meets the U.S. Department of...

  12. Advances in refrigeration and heat transfer engineering

    SciTech Connect (OSTI)

    Bansal, Pradeep [ORNL; Cremaschi, Prof. Lorenzo [Oklahoma State University

    2015-01-01

    This special edition of Science and Technology for the Built Environment (STBE) presents selected high quality papers that were presented at the 15th International Refrigeration and Air Conditioning Conference held at Purdue University during July 14-17 2014. All papers went through the additional review before being finally accepted for publication in this special issue of Science and Technology and the Built Environment. Altogether 20 papers made to this special issue that cover a wide range of topics, including advancements in alternative refrigerants, heat exchangers/heat transfer, nano-fluids, systems design and optimization and modeling approaches. Although CO2 may perhaps have been the most researched and popular refrigerant in the past decade, R32 is being seriously considered lately as an alternative and environmentally friendly refrigerant for small systems due to its low Global Warming Potential (GWP).

  13. International Refrigeration: Proposed Penalty (2012-CE-1510)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that International Refrigeration Products failed to certify a various room air conditioners as compliant with the applicable energy conservation standards.

  14. Refrigeration system having standing wave compressor

    DOE Patents [OSTI]

    Lucas, Timothy S. (Glen Allen, VA)

    1992-01-01

    A compression-evaporation refrigeration system, wherein gaseous compression of the refrigerant is provided by a standing wave compressor. The standing wave compressor is modified so as to provide a separate subcooling system for the refrigerant, so that efficiency losses due to flashing are reduced. Subcooling occurs when heat exchange is provided between the refrigerant and a heat pumping surface, which is exposed to the standing acoustic wave within the standing wave compressor. A variable capacity and variable discharge pressure for the standing wave compressor is provided. A control circuit simultaneously varies the capacity and discharge pressure in response to changing operating conditions, thereby maintaining the minimum discharge pressure needed for condensation to occur at any time. Thus, the power consumption of the standing wave compressor is reduced and system efficiency is improved.

  15. Loveland Water & Power- Refrigerator Recycling Program

    Broader source: Energy.gov [DOE]

    Loveland Water & Power is providing an incentive for customers to recycle older, working refrigerators. Interested customers can call the utility to arrange a time to pick up the old...

  16. Electrochemical formation of field emitters

    SciTech Connect (OSTI)

    Bernhardt, Anthony F. (Berkeley, CA)

    1999-01-01

    Electrochemical formation of field emitters, particularly useful in the fabrication of flat panel displays. The fabrication involves field emitting points in a gated field emitter structure. Metal field emitters are formed by electroplating and the shape of the formed emitter is controlled by the potential imposed on the gate as well as on a separate counter electrode. This allows sharp emitters to be formed in a more inexpensive and manufacturable process than vacuum deposition processes used at present. The fabrication process involves etching of the gate metal and the dielectric layer down to the resistor layer, and then electroplating the etched area and forming an electroplated emitter point in the etched area.

  17. Global warming impacts of ozone-safe refrigerants and refrigeration, heating, and air-conditioning technologies

    SciTech Connect (OSTI)

    Fischer, S.; Sand, J.; Baxter, V.

    1997-12-01

    International agreements mandate the phase-out of many chlorine containing compounds that are used as the working fluid in refrigeration, air-conditioning, and heating equipment. Many of the chemical compounds that have been proposed, and are being used in place of the class of refrigerants eliminated by the Montreal Protocol are now being questioned because of their possible contributions to global warming. Natural refrigerants are put forth as inherently superior to manufactured refrigerants because they have very low or zero global warming potentials (GWPs). Questions are being raised about whether or not these manufactured refrigerants, primarily hydrofluorocarbons (HFCs), should be regulated and perhaps phased out in much the same manner as CFCs and HCFCs. Several of the major applications of refrigerants are examined in this paper and the results of an analysis of their contributions to greenhouse warming are presented. Supermarket refrigeration is shown to be an application where alternative technologies have the potential to reduce emissions of greenhouse gases (GHG) significantly with no clear advantage to either natural or HFC refrigerants. Mixed results are presented for automobile air conditioners with opportunities to reduce GHG emissions dependent on climate and comfort criteria. GHG emissions for hermetic and factory built systems (i.e. household refrigerators/freezers, unitary equipment, chillers) are shown to be dominated by energy use with much greater potential for reduction through efficiency improvements than by selection of refrigerant. The results for refrigerators also illustrate that hydrocarbon and carbon dioxide blown foam insulation have lower overall effects on GHG emissions than HFC blown foams at the cost of increased energy use.

  18. Optical Refrigeration for Ultra-Efficient Photovoltaics

    E-Print Network [OSTI]

    Manor, Assaf; Rotschild, Carmel

    2014-01-01

    Improving the conversion efficiency of solar energy to electricity is most important to mankind. For single-junction photovoltaic solar-cells, the Shockley-Queisser thermodynamic efficiency limit is extensively due to the heat dissipation, inherently accompanying the quantum process of electro-chemical potential generation. Concepts such as solar thermo-photovoltaics and thermo-photonics, have been suggested to harness this wasted heat, yet efficiencies exceeding the Shockley-Queisser limit have not been demonstrated due to the challenge of operating at high temperatures. Here, we present a highly efficient converter based on endothermic photoluminescence, which operates at relative low temperatures. The thermally induced blue-shifted photoluminescence of a low-bandgap absorber is coupled to a high-bandgap photovoltaic cell. The high absorber's photo-current and the high cell's voltage results in 69% maximal theoretical conversion efficiencies. We experimentally demonstrate tenfold thermal-enhancement of usef...

  19. Electrochemical cell stack assembly

    DOE Patents [OSTI]

    Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

    2010-06-22

    Multiple stacks of tubular electrochemical cells having a dense electrolyte disposed between an anode and a cathode preferably deposited as thin films arranged in parallel on stamped conductive interconnect sheets or ferrules. The stack allows one or more electrochemical cell to malfunction without disabling the entire stack. Stack efficiency is enhanced through simplified gas manifolding, gas recycling, reduced operating temperature and improved heat distribution.

  20. Electrochemical thermodynamic measurement system

    DOE Patents [OSTI]

    Reynier, Yvan (Meylan, FR); Yazami, Rachid (Los Angeles, CA); Fultz, Brent T. (Pasadena, CA)

    2009-09-29

    The present invention provides systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and electrochemical energy storage and conversion systems. Systems and methods of the present invention are configured for simultaneously collecting a suite of measurements characterizing a plurality of interconnected electrochemical and thermodynamic parameters relating to the electrode reaction state of advancement, voltage and temperature. Enhanced sensitivity provided by the present methods and systems combined with measurement conditions that reflect thermodynamically stabilized electrode conditions allow very accurate measurement of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and electrochemical systems, such as the energy, power density, current rate and the cycle life of an electrochemical cell.

  1. Variable temperature electrochemical strain microscopy of Sm-doped ceria

    SciTech Connect (OSTI)

    Jesse, Stephen; Morozovska, A. N.; Kalinin, Sergei V; Eliseev, E. A.; Yang, Nan; Doria, Sandra; Tebano, Antonello

    2013-01-01

    Variable temperature electrochemical strain microscopy has been used to study the electrochemical activity of Sm-doped ceria as a function of temperature and bias. The electrochemical strain microscopy hysteresis loops have been collected across the surface at different temperatures and the relative activity at different temperatures has been compared. The relaxation behavior of the signal at different temperatures has been also evaluated to relate kinetic process during bias induced electrochemical reactions with temperature and two different kinetic regimes have been identified. The strongly non-monotonic dependence of relaxation behavior on temperature is interpreted as evidence for water-mediated mechanisms.

  2. Energy Efficiency Evaluation of Refrigeration Technologies in Combined Cooling, Heating and Power Systems 

    E-Print Network [OSTI]

    Zuo, Z.; Hu, W.

    2006-01-01

    With development of absorption refrigeration technology, the cooling requirement can be met using various optional refrigeration technologies in a CCHP system, including compression refrigeration, steam double-effect absorption refrigeration, steam...

  3. ELLIPSOMETRY OF ELECTROCHEMICAL SURFACE LAYERS

    E-Print Network [OSTI]

    Muller, R.H.

    2010-01-01

    in Advances In Electrochemistry and Electrochemicalistry, in Advances in Electrochemistry and Electrochemical ,

  4. Quantum heat engines and refrigerators: Continuous devices

    E-Print Network [OSTI]

    Ronnie Kosloff; Amikam Levy

    2013-10-02

    Quantum thermodynamics supplies a consistent description of quantum heat engines and refrigerators up to the level of a single few level system coupled to the environment. Once the environment is split into three;a hot, cold and work reservoirs a heat engine can operate. The device converts the positive gain into power;where the gain is obtained from population inversion between the components of the device. Reversing the operation transforms the device into a quantum refrigerator. The quantum tricycle, a device connected by three external leads to three heat reservoirs is used as a template for engines and refrigerators. The equation of motion for the heat currents and power can be derived from first principle. Only a global description of the coupling of the device to the reservoirs is consistent with the first and second laws of thermodynamics. Optimisation of the devices leads to a balanced set of parameters where the couplings to the three reservoirs are of the same order and the external driving field is in resonance. When analysing refrigerators special attention is devoted to a dynamical version of the third law of thermodynamics. Bounds on the rate of cooling when approaching the absolute zero are obtained by optimising the cooling current. At low temperature all refrigerators show universal behavior. Restrictions on the system imposed by the dynamical version of the third law are studied.

  5. Electrochemical hydrogen Storage Systems

    SciTech Connect (OSTI)

    Dr. Digby Macdonald

    2010-08-09

    As the global need for energy increases, scientists and engineers have found a possible solution by using hydrogen to power our world. Although hydrogen can be combusted as a fuel, it is considered an energy carrier for use in fuel cells wherein it is consumed (oxidized) without the production of greenhouse gases and produces electrical energy with high efficiency. Chemical storage of hydrogen involves release of hydrogen in a controlled manner from materials in which the hydrogen is covalently bound. Sodium borohydride and aminoborane are two materials given consideration as chemical hydrogen storage materials by the US Department of Energy. A very significant barrier to adoption of these materials as hydrogen carriers is their regeneration from 'spent fuel,' i.e., the material remaining after discharge of hydrogen. The U.S. Department of Energy (DOE) formed a Center of Excellence for Chemical Hydrogen Storage, and this work stems from that project. The DOE has identified boron hydrides as being the main compounds of interest as hydrogen storage materials. The various boron hydrides are then oxidized to release their hydrogen, thereby forming a 'spent fuel' in the form of a lower boron hydride or even a boron oxide. The ultimate goal of this project is to take the oxidized boron hydrides as the spent fuel and hydrogenate them back to their original form so they can be used again as a fuel. Thus this research is essentially a boron hydride recycling project. In this report, research directed at regeneration of sodium borohydride and aminoborane is described. For sodium borohydride, electrochemical reduction of boric acid and sodium metaborate (representing spent fuel) in alkaline, aqueous solution has been investigated. Similarly to literature reports (primarily patents), a variety of cathode materials were tried in these experiments. Additionally, approaches directed at overcoming electrostatic repulsion of borate anion from the cathode, not described in the previous literature for electrochemical reduction of spent fuels, have been attempted. A quantitative analytical method for measuring the concentration of sodium borohydride in alkaline aqueous solution has been developed as part of this work and is described herein. Finally, findings from stability tests for sodium borohydride in aqueous solutions of several different compositions are reported. For aminoborane, other research institutes have developed regeneration schemes involving tributyltin hydride. In this report, electrochemical reduction experiments attempting to regenerate tributyltin hydride from tributyltin chloride (a representative by-product of the regeneration scheme) are described. These experiments were performed in the non-aqueous solvents acetonitrile and 1,2-dimethoxyethane. A non-aqueous reference electrode for electrolysis experiments in acetonitrile was developed and is described. One class of boron hydrides, called polyhedral boranes, became of interest to the DOE due to their ability to contain a sufficient amount of hydrogen to meet program goals and because of their physical and chemical safety attributes. Unfortunately, the research performed here has shown that polyhedral boranes do not react in such a way as to allow enough hydrogen to be released, nor do they appear to undergo hydrogenation from the spent fuel form back to the original hydride. After the polyhedral boranes were investigated, the project goals remained the same but the hydrogen storage material was switched by the DOE to ammonia borane. Ammonia borane was found to undergo an irreversible hydrogen release process, so a direct hydrogenation was not able to occur. To achieve the hydrogenation of the spent ammonia borane fuel, an indirect hydrogenation reaction is possible by using compounds called organotin hydrides. In this process, the organotin hydrides will hydrogenate the spent ammonia borane fuel at the cost of their own oxidation, which forms organotin halides. To enable a closed-loop cycle, our task was then to be able to hydrogenate the organotin halides back to th

  6. Energy Savings from Floating Head Pressure in Ammonia Refrigeration Systems 

    E-Print Network [OSTI]

    Barrer, P. J.; Jones, S. M.

    1998-01-01

    This paper presents case studies of two moderately sized ammonia refrigeration systems retrofitted for floating head pressure control. It also presents a parametric analysis to assist in selecting appropriate pressures in an ammonia refrigeration...

  7. Refrigerant pressurization system with a two-phase condensing ejector

    DOE Patents [OSTI]

    Bergander, Mark (Madison, CT)

    2009-07-14

    A refrigerant pressurization system including an ejector having a first conduit for flowing a liquid refrigerant therethrough and a nozzle for accelerating a vapor refrigerant therethrough. The first conduit is positioned such that the liquid refrigerant is discharged from the first conduit into the nozzle. The ejector includes a mixing chamber for condensing the vapor refrigerant. The mixing chamber comprises at least a portion of the nozzle and transitions into a second conduit having a substantially constant cross sectional area. The condensation of the vapor refrigerant in the mixing chamber causes the refrigerant mixture in at least a portion of the mixing chamber to be at a pressure greater than that of the refrigerant entering the nozzle and greater than that entering the first conduit.

  8. Fully portable, highly flexible dilution refrigerator systems for neutron scattering

    E-Print Network [OSTI]

    Boyer, Edmond

    775 Fully portable, highly flexible dilution refrigerator systems for neutron scattering P. A systems developed specifically for neutron scattering environ- ments. The refrigerators are completely relatively recently however, the lowest temperatures available in almost all neutron scattering laboratories

  9. Optimal Design Refrigeration System for a Mucilage Glue Fiber Factory 

    E-Print Network [OSTI]

    Tan, C.; Liu, J.; Tang, F.; Liu, Y.

    2006-01-01

    In a mucilage glue fiber factory, the design of the refrigeration system takes into account the characteristics of mucilage glue fiber production and fully uses the refrigeration compressor heat to economize energy and reduce the production cost...

  10. T N YORK, NEW YORKI AMERICAN SOCIETY OF HEATING, REFRIGERATING

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    lDC) r; T N YORK, NEW YORKI OF THE AMERICAN SOCIETY OF HEATING, REFRIGERATING /*s\\ TECHNICAL ANDITI

  11. Toxicity Data to Determine Refrigerant Concentration Limits

    SciTech Connect (OSTI)

    Calm, James M.

    2000-09-30

    This report reviews toxicity data, identifies sources for them, and presents resulting exposure limits for refrigerants for consideration by qualified parties in developing safety guides, standards, codes, and regulations. It outlines a method to calculate an acute toxicity exposure limit (ATEL) and from it a recommended refrigerant concentration limit (RCL) for emergency exposures. The report focuses on acute toxicity with particular attention to lethality, cardiac sensitization, anesthetic and central nervous system effects, and other escape-impairing effects. It addresses R-11, R-12, R-22, R-23, R-113, R-114, R-116, R-123, R-124, R-125, R-134, R-134a, R-E134, R-141b, R-142b, R-143a, R-152a, R-218, R-227ea, R-236fa, R-245ca, R-245fa, R-290, R-500, R-502, R-600a, R-717, and R-744. It summarizes additional data for R-14, R-115, R-170 (ethane), R-C318, R-600 (n-butane), and R-1270 (propylene) to enable calculation of limits for blends incorporating them. The report summarizes the data a nd related safety information, including classifications and flammability data. It also presents a series of tables with proposed ATEL and RCL concentrations-in dimensionless form and the latter also in both metric (SI) and inch-pound (IP) units of measure-for both the cited refrigerants and 66 zerotropic and azeotropic blends. They include common refrigerants, such as R-404A, R-407C, R-410A, and R-507A, as well as others in commercial or developmental status. Appendices provide profiles for the cited single-compound refrigerants and for R-500 and R-502 as well as narrative toxicity summaries for common refrigerants. The report includes an extensive set of references.

  12. Electrochemical heat engine

    DOE Patents [OSTI]

    Elliott, Guy R. B. (Los Alamos, NM); Holley, Charles E. (Alcalde, NM); Houseman, Barton L. (Cockeysville, MD); Sibbitt, Jr., Wilmer L. (Albuquerque, NM)

    1978-01-01

    Electrochemical heat engines produce electrochemical work, and mechanical motion is limited to valve and switching actions as the heat-to-work cycles are performed. The electrochemical cells of said heat engines use molten or solid electrolytes at high temperatures. One or more reactions in the cycle will generate a gas at high temperature which can be condensed at a lower temperature with later return of the condensate to electrochemical cells. Sodium, potassium, and cesium are used as the working gases for high temperature cells (above 600 K) with halogen gases or volatile halides being used at lower temperature. Carbonates and halides are used as molten electrolytes and the solid electrolyte in these melts can also be used as a cell separator.

  13. Handbook of Electrochemical Nanotechnology

    SciTech Connect (OSTI)

    Lin, Yuehe; Nalwa, H. S.

    2009-02-12

    This 2-volume handbook provides an overview of recent advances in the field of electrochemical nanotechnology. It will be of great interst to graduate students, scientists, and engineering professionals whose research is at the interface of electrochemistry and nanotechnology.

  14. Cooling at the quantum limit and RF refrigeration

    E-Print Network [OSTI]

    Fominov, Yakov

    Cooling at the quantum limit and RF refrigeration Jukka Pekola Low Temperature Laboratory, Helsinki (electromagnetic) heat transport Cooling at the quantum limit: experiments RF refrigeration in a single as a refrigerator Optimum cooling power is reached at V 2/e: Cooling power of a NIS junction: Temperature TN

  15. Control method for mixed refrigerant based natural gas liquefier

    DOE Patents [OSTI]

    Kountz, Kenneth J. (Palatine, IL); Bishop, Patrick M. (Chicago, IL)

    2003-01-01

    In a natural gas liquefaction system having a refrigerant storage circuit, a refrigerant circulation circuit in fluid communication with the refrigerant storage circuit, and a natural gas liquefaction circuit in thermal communication with the refrigerant circulation circuit, a method for liquefaction of natural gas in which pressure in the refrigerant circulation circuit is adjusted to below about 175 psig by exchange of refrigerant with the refrigerant storage circuit. A variable speed motor is started whereby operation of a compressor is initiated. The compressor is operated at full discharge capacity. Operation of an expansion valve is initiated whereby suction pressure at the suction pressure port of the compressor is maintained below about 30 psig and discharge pressure at the discharge pressure port of the compressor is maintained below about 350 psig. Refrigerant vapor is introduced from the refrigerant holding tank into the refrigerant circulation circuit until the suction pressure is reduced to below about 15 psig, after which flow of the refrigerant vapor from the refrigerant holding tank is terminated. Natural gas is then introduced into a natural gas liquefier, resulting in liquefaction of the natural gas.

  16. Method and apparatus for de-superheating refrigerant

    DOE Patents [OSTI]

    Zess, J.A.; Drost, M.K.; Call, C.J.

    1997-11-25

    The present invention is an apparatus and method for de-superheating a primary refrigerant leaving a compressor wherein a secondary refrigerant is used between the primary refrigerant to be de-superheated. Reject heat is advantageously used for heat reclaim. 7 figs.

  17. Solid state electrochemical composite

    DOE Patents [OSTI]

    Visco, Steven J. (Berkeley, CA); Jacobson, Craig P. (Moraga, CA); DeJonghe, Lutgard C. (Lafayette, CA)

    2009-06-30

    Provided is a composite electrochemical device fabricated from highly electronically conductive materials such as metals, metal alloys, or electronically conductive ceramics. The electronic conductivity of the electrode substrate is maximized. The invention allows for an electrode with high electronic conductivity and sufficient catalytic activity to achieve high power density in ionic (electrochemical) devices such as fuel cells and electrolytic gas separation systems including oxygen generation system.

  18. High power thermoacoustic refrigeration. Annual summary report, 1 June 1995-31 May 1996

    SciTech Connect (OSTI)

    Garrett, S.L.

    1996-06-15

    The purpose of this research project is to study the fundamental physical processes which are involved in production of high cooling powers from electrically driven thermoacoustic refrigeration. The results of these experimental investigations are then utilized to produce improved designs for the next generation of high power thermoacoustic refrigerators, chillers, and air conditioners. These research objectives are achieved by an integrated combination of experimental measurements on thermoacoustic components and subsystems, as well as complete refrigeration systems. Comparison of the measured performance to analytic models based on differential equations (low amplitude) and similitude (high amplitude) and to numerical models based on the Los Alamos National Laboratory Design Environment for Low-Amplitude ThermoAcoustic Engines (DELTA-E), are then made.

  19. High frequency thermoacoustic refrigerator. Annual summary report, 2 September 1993-31 May 1994

    SciTech Connect (OSTI)

    Symko, O.G.

    1994-06-16

    A small thermoacoustic refrigerator was developed for operation at 5 kHz. Its main components are a piezoelectric driver of the bimorph type, a cotton wool stack, a 1/2-wave resonator (operated at its 3rd harmonic), and photolithographically processed copper heat exchangers. Tests with air at 1 atmosphere as the working gas produced a temperature difference Delta T across the stack of 32 deg C in 4 seconds for an acoustic power input level of 160 dB. The refrigerator did not have thermal insulation. Improved performance is expected with pressurized helium gas and helium-xenon mixtures. The performance of this refrigerator and its small size make it attractive for applications in high speed electronics and possibly IR detectors.

  20. Floating Loop System For Cooling Integrated Motors And Inverters Using Hot Liquid Refrigerant

    DOE Patents [OSTI]

    Hsu, John S [Oak Ridge, TN; Ayers, Curtis W [Kingston, TN; Coomer, Chester [Knoxville, TN; Marlino, Laura D [Oak Ridge, TN

    2006-02-07

    A floating loop vehicle component cooling and air-conditioning system having at least one compressor for compressing cool vapor refrigerant into hot vapor refrigerant; at least one condenser for condensing the hot vapor refrigerant into hot liquid refrigerant by exchanging heat with outdoor air; at least one floating loop component cooling device for evaporating the hot liquid refrigerant into hot vapor refrigerant; at least one expansion device for expanding the hot liquid refrigerant into cool liquid refrigerant; at least one air conditioning evaporator for evaporating the cool liquid refrigerant into cool vapor refrigerant by exchanging heat with indoor air; and piping for interconnecting components of the cooling and air conditioning system.

  1. 2014-04-10 Issuance: Test Procedures for Refrigerators, Refrigerator-Freezers, and Freezers; Final Rule

    Broader source: Energy.gov [DOE]

    This document is a pre-publication Federal Register final rule regarding test procedures for residential refrigerators and freezers, as issued by the Deputy Assistant Secretary for Energy Efficiency on April 10, 2014.

  2. Buffered Electrochemical Polishing of Niobium

    SciTech Connect (OSTI)

    Gianluigi Ciovati, Hui Tian, Sean Corcoran

    2011-03-01

    The standard preparation of superconducting radio-frequency (SRF) cavities made of pure niobium include the removal of a 'damaged' surface layer, by buffered chemical polishing (BCP) or electropolishing (EP), after the cavities are formed. The performance of the cavities is characterized by a sharp degradation of the quality factor when the surface magnetic field exceeds about 90 mT, a phenomenon referred to as 'Q-drop'. In cavities made of polycrystalline fine grain (ASTM 5) niobium, the Q-drop can be significantly reduced by a low-temperature ({approx} 120 C) 'in-situ' baking of the cavity if the chemical treatment was EP rather than BCP. As part of the effort to understand this phenomenon, we investigated the effect of introducing a polarization potential during buffered chemical polishing, creating a process which is between the standard BCP and EP. While preliminary results on the application of this process to Nb cavities have been previously reported, in this contribution we focus on the characterization of this novel electrochemical process by measuring polarization curves, etching rates, surface finish, electrochemical impedance and the effects of temperature and electrolyte composition. In particular, it is shown that the anodic potential of Nb during BCP reduces the etching rate and improves the surface finish.

  3. Solubility modeling of refrigerant/lubricant mixtures

    SciTech Connect (OSTI)

    Michels, H.H.; Sienel, T.H.

    1996-12-31

    A general model for predicting the solubility properties of refrigerant/lubricant mixtures has been developed based on applicable theory for the excess Gibbs energy of non-ideal solutions. In our approach, flexible thermodynamic forms are chosen to describe the properties of both the gas and liquid phases of refrigerant/lubricant mixtures. After an extensive study of models for describing non-ideal liquid effects, the Wohl-suffix equations, which have been extensively utilized in the analysis of hydrocarbon mixtures, have been developed into a general form applicable to mixtures where one component is a POE lubricant. In the present study we have analyzed several POEs where structural and thermophysical property data were available. Data were also collected from several sources on the solubility of refrigerant/lubricant binary pairs. We have developed a computer code (NISC), based on the Wohl model, that predicts dew point or bubble point conditions over a wide range of composition and temperature. Our present analysis covers mixtures containing up to three refrigerant molecules and one lubricant. The present code can be used to analyze the properties of R-410a and R-407c in mixtures with a POE lubricant. Comparisons with other models, such as the Wilson or modified Wilson equations, indicate that the Wohl-suffix equations yield more reliable predictions for HFC/POE mixtures.

  4. Improving Industrial Refrigeration System Efficiency - Actual Applications 

    E-Print Network [OSTI]

    White, T. L.

    1980-01-01

    in the booster pump suction line to prevent pump cavitation and to improve refrigeration cycle effi ciency. Por each lOOp of sUDcooling, cycle efficiency increases by about 2%. Approxi mately 20 0 p of subcooling is planned for the modified system...

  5. Measurements with a recuperative superfluid Stirling refrigerator

    SciTech Connect (OSTI)

    Watanabe, A.; Swift, G.W.; Brisson, J.G.

    1995-08-01

    A superfluid Stirling refrigerator cooled to 168 mK using a 4.9% {sup 3}He- {sup 4}He mixture and exhausting its waste heat at 383 mK. Cooling power versus temperature and speed is presented for 4.9%, 17%, and 36% mixtures. At the highest concentration, a dissipation mechanism of unknown origin is observed.

  6. Frontiers in thermoacoustic refrigeration and mixture separation

    E-Print Network [OSTI]

    conversion, which harnesses the oscillations of temperature, heat flux, pressure, and motion in intense sound-transfer and acoustic components and filled with a gas-- typically high-pressure helium. Refrigeration is produced because gas that oscillates through the cold heat exchanger is depressurized adiabatically on the pulse

  7. The smallest refrigerators can reach maximal efficiency

    E-Print Network [OSTI]

    Paul Skrzypczyk; Nicolas Brunner; Noah Linden; Sandu Popescu

    2011-12-02

    We investigate whether size imposes a fundamental constraint on the efficiency of small thermal machines. We analyse in detail a model of a small self-contained refrigerator consisting of three qubits. We show analytically that this system can reach the Carnot efficiency, thus demonstrating that there exists no complementarity between size and efficiency.

  8. Ground Loops for Heat Pumps and Refrigeration 

    E-Print Network [OSTI]

    Braud, H. J.

    1986-01-01

    Ground loops are used for water source heat pumps. Refrigeration can be put on a ground loop. Water-cooled condensing units are more efficient than air-cooled, and they can be put indoors. Indoor location makes piping for desuperheater hot water...

  9. Covered Product Category: Refrigerated Beverage Vending Machines

    Broader source: Energy.gov [DOE]

    FEMP provides acquisition guidance and Federal efficiency requirements across a variety of product categories, including refrigerated beverage vending machines, which are covered by the ENERGY STAR® program. Federal laws and requirements mandate that agencies meet these efficiency requirements in all procurement and acquisition actions that are not specifically exempted by law.

  10. Waste Heat Recapture from Supermarket Refrigeration Systems

    SciTech Connect (OSTI)

    Fricke, Brian A

    2011-11-01

    The objective of this project was to determine the potential energy savings associated with improved utilization of waste heat from supermarket refrigeration systems. Existing and advanced strategies for waste heat recovery in supermarkets were analyzed, including options from advanced sources such as combined heat and power (CHP), micro-turbines and fuel cells.

  11. Electrochemical formation of field emitters

    DOE Patents [OSTI]

    Bernhardt, A.F.

    1999-03-16

    Electrochemical formation of field emitters, particularly useful in the fabrication of flat panel displays is disclosed. The fabrication involves field emitting points in a gated field emitter structure. Metal field emitters are formed by electroplating and the shape of the formed emitter is controlled by the potential imposed on the gate as well as on a separate counter electrode. This allows sharp emitters to be formed in a more inexpensive and manufacturable process than vacuum deposition processes used at present. The fabrication process involves etching of the gate metal and the dielectric layer down to the resistor layer, and then electroplating the etched area and forming an electroplated emitter point in the etched area. 12 figs.

  12. Optimizing Cooling Tower Performance Refrigeration Systems, Chemical Plants, and Power Plants All Have A Resource Quietly Awaiting Exploitation-Cold Water!! 

    E-Print Network [OSTI]

    Burger, R.

    1991-01-01

    Cooling towers, because of their seeming simplicity, are usually orphans of the facilities operation. We are all aware that cooling towers are the step-children of the chemical process plant, electric power generating station, and refrigeration...

  13. Eliminating Voltage Decay of Lithium-Rich Li1.14Mn0.54Ni0.14Co0.14O2 Cathodes by Controlling the Electrochemical Process

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wei, Z.; Zhu, Y.; Zhang, W.; Wang, F.; Zhang, Q.; Qiu, B.; Han, S.; Xia, Y.; Liu, Z.

    2015-03-27

    Lithium-rich material owns a particularly high capacity owing to the activation of electrochemical inactive Li2MnO3 phase. But at the same time, MnO2 phase formed after Li2MnO3 activation confronts a severe problem of converting to spinel phase, and resulting in voltage decay. To our knowledge, this phenomenon is inherent property of layered manganese oxide materials and can hardly be overcome. Based on this, unlike previous reports, herein we design a method for the first time to accelerate the phase transformation by tuning the charge upper-limit voltage at a high value, so the phase transformation process can be finished in a fewmore »cycles. Then material structure remains stable while cycling at a low upper-limit voltage. By this novel method voltage decay is eliminated significantly.« less

  14. Electrochemical nitridation of metal surfaces

    DOE Patents [OSTI]

    Wang, Heli; Turner, John A.

    2015-06-30

    Electrochemical nitridation of metals and the produced metals are disclosed. An exemplary method of electrochemical nitridation of metals comprises providing an electrochemical solution at low temperature. The method also comprises providing a three-electrode potentiostat system. The method also comprises stabilizing the three-electrode potentiostat system at open circuit potential. The method also comprises applying a cathodic potential to a metal.

  15. Synthesis of graphene platelets by chemical and electrochemical route

    SciTech Connect (OSTI)

    Ramachandran, Rajendran; Felix, Sathiyanathan [Centre for Nanotechnology Research, VIT University, Vellore 632014, Tamil Nadu (India); Joshi, Girish M. [Materials Physics Division, School of Advanced Sciences, VIT University, Vellore 632014, Tamil Nadu (India); Raghupathy, Bala P.C., E-mail: balapraveen2000@yahoo.com [Centre for Nanotechnology Research, VIT University, Vellore 632014, Tamil Nadu (India); Research and Advanced Engineering Division (Materials), Renault Nissan Technology and Business Center India (P) Ltd., Chennai, Tamil Nadu (India); Jeong, Soon Kwan, E-mail: jeongsk@kier.re.kr [Climate Change Technology Research Division, Korea Institute of Energy Research, Yuseong-gu, Daejeon 305-343 (Korea, Republic of); Grace, Andrews Nirmala, E-mail: anirmalagrace@vit.ac.in [Centre for Nanotechnology Research, VIT University, Vellore 632014, Tamil Nadu (India); Climate Change Technology Research Division, Korea Institute of Energy Research, Yuseong-gu, Daejeon 305-343 (Korea, Republic of)

    2013-10-15

    Graphical abstract: A schematic showing the overall reduction process of graphite to reduced graphene platelets by chemical and electrochemical route. - Highlights: • Graphene was prepared by diverse routes viz. chemical and electrochemical methods. • NaBH{sub 4} was effective for removing oxygen functional groups from graphene oxide. • Sodium borohydride reduced graphene oxide (SRGO) showed high specific capacitance. • Electrochemical rendered a cheap route for production of graphene in powder form. - Abstract: Graphene platelets were synthesized from graphene oxide by chemical and electrochemical route. Under the chemical method, sodium borohydride and hydrazine chloride were used as reductants to produce graphene. In this paper, a novel and cost effective electrochemical method, which can simplify the process of reduction on a larger scale, is demonstrated. The electrochemical method proposed in this paper produces graphene in powder form with good yield. The atomic force microscopic images confirmed that the graphene samples prepared by all the routes have multilayers of graphene. The electrochemical process provided a new route to make relatively larger area graphene sheets, which will have interest for further patterning applications. Attempt was made to quantify the quantum of reduction using cyclic voltammetry and choronopotentiometry techniques on reduced graphene samples. As a measure in reading the specific capacitance values, a maximum specific capacitance value of 265.3 F/g was obtained in sodium borohydride reduced graphene oxide.

  16. Electrochemical fabrication of capacitors

    DOE Patents [OSTI]

    Mansour, Azzam N. (Fairfax Sta., VA); Melendres, Carlos A. (Lemont, IL)

    1999-01-01

    A film of nickel oxide is anodically deposited on a graphite sheet held in osition on an electrochemical cell during application of a positive electrode voltage to the graphite sheet while exposed to an electrolytic nickel oxide solution within a volumetrically variable chamber of the cell. An angularly orientated x-ray beam is admitted into the cell for transmission through the deposited nickel oxide film in order to obtain structural information while the film is subject to electrochemical and in-situ x-ray spectroscopy from which optimum film thickness, may be determined by comparative analysis for capacitor fabrication purposes.

  17. Electrochemical membrane incinerator

    DOE Patents [OSTI]

    Johnson, Dennis C. (Ames, IA); Houk, Linda L. (Ames, IA); Feng, Jianren (Ames, IA)

    2001-03-20

    Electrochemical incineration of p-benzoquinone was evaluated as a model for the mineralization of carbon in toxic aromatic compounds. A Ti or Pt anode was coated with a film of the oxides of Ti, Ru, Sn and Sb. This quaternary metal oxide film was stable; elemental analysis of the electrolyzed solution indicated the concentration of these metal ions to be 3 .mu.g/L or less. The anode showed good reactivity for the electrochemical incineration of benzoquinone. The use of a dissolved salt matrix as the so-called "supporting electrolyte" was eliminated in favor of a solid-state electrolyte sandwiched between the anode and cathode.

  18. Separators for electrochemical cells

    DOE Patents [OSTI]

    Carlson, Steven Allen; Anakor, Ifenna Kingsley

    2014-11-11

    Provided are separators for use in an electrochemical cell comprising (a) an inorganic oxide and (b) an organic polymer, wherein the inorganic oxide comprises organic substituents. Preferably, the inorganic oxide comprises an hydrated aluminum oxide of the formula Al.sub.2O.sub.3.xH.sub.2O, wherein x is less than 1.0, and wherein the hydrated aluminum oxide comprises organic substituents, preferably comprising a reaction product of a multifunctional monomer and/or organic carbonate with an aluminum oxide, such as pseudo-boehmite and an aluminum oxide. Also provided are electrochemical cells comprising such separators.

  19. In-Situ Electrochemical Transmission Electron Microscopy for Battery Research

    SciTech Connect (OSTI)

    Mehdi, Beata L; Gu, Meng; Parent, Lucas; Xu, WU; Nasybulin, Eduard; Chen, Xilin; Unocic, Raymond R; Xu, Pinghong; Welch, David; Abellan, Patricia; Zhang, Ji-Guang; Liu, Jun; Wang, Chongmin; Arslan, Ilke; Evans, James E; Browning, Nigel

    2014-01-01

    The recent development of in-situ liquid stages for (scanning) transmission electron microscopes now makes it possible for us to study the details of electrochemical processes under operando conditions. As electrochemical processes are complex, care must be taken to calibrate the system before any in-situ/operando observations. In addition, as the electron beam can cause effects that look similar to electrochemical processes at the electrolyte/electrode interface, an understanding of the role of the electron beam in modifying the operando observations must also be understood. In this paper we describe the design, assembly, and operation of an in-situ electrochemical cell, paying particular attention to the method for controlling and quantifying the experimental parameters. The use of this system is then demonstrated for the lithiation/delithiation of silicon nanowires.

  20. Measurements of the efficiency and refrigeration power of pulse-tube refrigerators

    SciTech Connect (OSTI)

    Herrmann, S.; Radebaugh, R.

    1986-09-01

    Pulse-tube or thermoacoustic refrigerators have the potential for high reliability since they require only one moving part - an oscillating piston or diaphragm at room temperature. If a tube is closed at one end and connected to a pressure-wave generator at the open end, and if the phase angle between mass flow and pressure is shifted from 90/sup 0/, then refrigeration occurs at the open end. The shift in phase angle can be realized by thermal relaxation between the gas and the tube walls or by an orifice at the closed end. A low temperature of 60 K using helium gas in a one-stage orifice pulse tube has been achieved at NBS. The report describes the first measurements of the efficiency, refrigeration power, and refrigeration power per unit mass flow, for three pulse-tube refrigerators. Three tube sizes, differing in length and diameter, were studied over a frequency range of 3 to 11.5 Hz. Cooling efficiencies as high as 90% of the Carnot efficiency were obtained when compressor and regenerator losses are neglected.

  1. Performance bound for quantum absorption refrigerators

    E-Print Network [OSTI]

    Luis A. Correa; José P. Palao; Gerardo Adesso; Daniel Alonso

    2013-04-29

    An implementation of quantum absorption chillers with three qubits has been recently proposed, that is ideally able to reach the Carnot performance regime. Here we study the working efficiency of such self-contained refrigerators, adopting a consistent treatment of dissipation effects. We demonstrate that the coefficient of performance at maximum cooling power is upper bounded by 3/4 of the Carnot performance. The result is independent of the details of the system and the equilibrium temperatures of the external baths. We provide design prescriptions that saturate the bound in the limit of a large difference between the operating temperatures. Our study suggests that delocalized dissipation, which must be taken into account for a proper modelling of the machine-baths interaction, is a fundamental source of irreversibility which prevents the refrigerator from approaching the Carnot performance arbitrarily closely in practice. The potential role of quantum correlations in the operation of these machines is also investigated.

  2. Development of Low Global Warming Potential Refrigerant Solutions for Commercial Refrigeration Systems using a Life Cycle Climate Performance Design Tool

    SciTech Connect (OSTI)

    Abdelaziz, Omar; Fricke, Brian A; Vineyard, Edward Allan

    2012-01-01

    Commercial refrigeration systems are known to be prone to high leak rates and to consume large amounts of electricity. As such, direct emissions related to refrigerant leakage and indirect emissions resulting from primary energy consumption contribute greatly to their Life Cycle Climate Performance (LCCP). In this paper, an LCCP design tool is used to evaluate the performance of a typical commercial refrigeration system with alternative refrigerants and minor system modifications to provide lower Global Warming Potential (GWP) refrigerant solutions with improved LCCP compared to baseline systems. The LCCP design tool accounts for system performance, ambient temperature, and system load; system performance is evaluated using a validated vapor compression system simulation tool while ambient temperature and system load are devised from a widely used building energy modeling tool (EnergyPlus). The LCCP design tool also accounts for the change in hourly electricity emission rate to yield an accurate prediction of indirect emissions. The analysis shows that conventional commercial refrigeration system life cycle emissions are largely due to direct emissions associated with refrigerant leaks and that system efficiency plays a smaller role in the LCCP. However, as a transition occurs to low GWP refrigerants, the indirect emissions become more relevant. Low GWP refrigerants may not be suitable for drop-in replacements in conventional commercial refrigeration systems; however some mixtures may be introduced as transitional drop-in replacements. These transitional refrigerants have a significantly lower GWP than baseline refrigerants and as such, improved LCCP. The paper concludes with a brief discussion on the tradeoffs between refrigerant GWP, efficiency and capacity.

  3. Method of reducing chlorofluorocarbon refrigerant emissons to the atmosphere

    DOE Patents [OSTI]

    DeVault, Robert C. (Knoxville, TN); Fairchild, Phillip D. (Clinton, TN); Biermann, Wendell J. (Fayetteville, NY)

    1990-01-01

    A method is disclosed for reducing chloroflurocarbon (CFC) refrigerant emissions during removal or transfer or refrigerants from a vapor compression cooling system or heat pump which comprises contacting the refrigerant with a suitable sorbent material. The sorbent material allows for the storage and retention or the chlorofluorocarbon in non-gaseous form so that it does not tend to escape to the atmosphere where it would cause harm by contributing to ozone depletion. In other aspects of the invention, contacting of CFC refrigerants with sorbent material allows for purification and recycling of used refrigerant, and a device containing stored sorbent material can be employed in the detection of refrigerant leakage in a cooling system or heat pump.

  4. Hydrophilic structures for condensation management in refrigerator appliances

    DOE Patents [OSTI]

    Kuehl, Steven John; Vonderhaar, John J; Wu, Guolian; Wu, Mianxue

    2014-10-21

    A refrigerator appliance that includes a freezer compartment having a freezer compartment door, and a refrigeration compartment having at least one refrigeration compartment door. The appliance further includes a mullion with an exterior surface. The mullion divides the compartments and the exterior surface directs condensation toward a transfer point. The appliance may also include a cabinet that houses the compartments and has two sides, each with an exterior surface. Further, at least one exterior surface directs condensation toward a transfer point.

  5. Supermarket with Ground Coupled Carbon Dioxide Refrigeration Plant 

    E-Print Network [OSTI]

    Rehault, N.

    2012-01-01

    SUPERMARKET WITH GROUND COUPLED CARBON DIOXIDE REFRIGERATION PLANT Dipl.-Ing. Nicolas R?hault Fraunhofer Institute for Solar Energy Systems ISE ICEBO 2012 Manchester, 25.10.2012 ? Fraunhofer ISE 2 AGENDA 1. Background on supermarkets, energy...- conditioning: Insulation and air tightness to Passivhaus Standard CO2 refrigeration plant as only energy supply No use of fossil fuels Use of ground to sub-cool refrigerant and as heat source for heat pump Use of covers and night curtains LED...

  6. Retrofitting Doors on Open Refrigerated Cases | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - 2013 BTO Peer Review Better Buildings Alliance Equipment Performance Specifications - 2013 BTO Peer Review Working Fluids Low Global Warming Potential Refrigerants - 2013...

  7. Test results on a supercharged compressor for commercial refrigeration

    SciTech Connect (OSTI)

    Andrews, J.W.; Butcher, T.A.; Wilhelm, W.G. )

    1989-01-01

    This paper reports on a project whose objective was to quantify the technical benefits of using refrigerant R-502 in a supercharged reciprocating compressor for commercial refrigeration applications. The supercharged compressor concept used a special heat exchanger that subcools the major portion of the liquid refrigerant leaving the condenser. This subcooling is achieved by flashing the remaining portion of the condensed liquid through an expansion valve, thereby cooling it, and using it to absorb heat from the rest of the refrigerant. This supercharged stream is then fed to the cylinders through ports in the cylinder walls that are uncovered when the piston reaches bottom dead center.

  8. Development and Evaluation of a Sandia Cooler-based Refrigerator...

    Energy Savers [EERE]

    Radial Sandia Cooler Report Rotating heat exchangers installed in appliances and heat pumps have the potentially to reduce energy costs and refrigerant charge in a compact...

  9. 2014-04-10 Issuance: Test Procedures for Commercial Refrigeration...

    Broader source: Energy.gov (indexed) [DOE]

    final rule regarding test procedures for commercial refrigeration equipment, as issued by the Deputy Assistant Secretary for Energy Efficiency on April 10, 2014. Though it is not...

  10. Acoustic recovery of lost power in pulse tube refrigerators

    SciTech Connect (OSTI)

    Swift, G.W.; Gardner, D.L.; Backhaus, S.

    1999-02-01

    In an efficient Stirling-cycle cryocooler, the cold piston or displacer recovers power from the gas. This power is dissipated into heat in the orifice of an orifice pulse tube refrigerator, decreasing system efficiency. Recovery of some of this power in a pulse tube refrigerator, without sacrificing the simplicity and reliability inherent in a system with no cold moving parts, is described in this paper. In one method of such power recovery, the hot ends of both the regenerator and the pulse tube are connected to the front of the piston driving the refrigerator. Experimental data is presented demonstrating this method using a thermoacoustic driver instead of a piston driver. Control of time-averaged mass flux through the refrigerator is crucial to this power recovery, lest the refrigerator{close_quote}s cooling power be overwhelmed by a room-temperature mass flux. Two methods are demonstrated for control of mass flux: a barrier method, and a hydrodynamic method based on turbulent irreversible flow. At {minus}55{degree}C, the refrigerator provided cooling with 9{percent} of the Carnot coefficient of performance. With straightforward improvements, similar refrigerators should achieve efficiencies greater than those of prior pulse tube refrigerators and prior standing-wave thermoacoustic refrigerators, while maintaining the advantages of no moving parts. {copyright} {ital 1999 Acoustical Society of America.}

  11. New Refrigerant Boosts Energy Efficiency of Supermarket Display...

    Office of Environmental Management (EM)

    Solstice N40 offer supermarkets an easy solution to reduce their refrigeration system's electricity consumption, save energy, and cut greenhouse gas emissions. The Building...

  12. Mexico Sectoral Study on Climate and Refrigeration Technology...

    Open Energy Info (EERE)

    Mexico Sectoral Study on Climate and Refrigeration Technology in Developing Countries and the Development of Methods and Instruments for Identifying Reduction Potential and...

  13. Energy Efficiency Standards for Refrigerators in Brazil: A Methodology...

    Open Energy Info (EERE)

    Energy Efficiency Standards for Refrigerators in Brazil: A Methodology for Impact Evaluation Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Energy Efficiency Standards...

  14. ADVANCED UNDERGROUND GAS STORAGE CONCEPTS REFRIGERATED-MINED CAVERN STORAGE

    SciTech Connect (OSTI)

    1998-09-01

    Limited demand and high cost has prevented the construction of hard rock caverns in this country for a number of years. The storage of natural gas in mined caverns may prove technically feasible if the geology of the targeted market area is suitable; and economically feasible if the cost and convenience of service is competitive with alternative available storage methods for peak supply requirements. It is believed that mined cavern storage can provide the advantages of high delivery rates and multiple fill-withdrawal cycles in areas where salt cavern storage is not possible. In this research project, PB-KBB merged advanced mining technologies and gas refrigeration techniques to develop conceptual designs and cost estimates to demonstrate the commercialization potential of the storage of refrigerated natural gas in hard rock caverns. Five regions of the U.S.A. were studied for underground storage development and PB-KBB reviewed the literature to determine if the geology of these regions was suitable for siting hard rock storage caverns. Area gas market conditions in these regions were also studied to determine the need for such storage. Based on an analysis of many factors, a possible site was determined to be in Howard and Montgomery Counties, Maryland. The area has compatible geology and a gas industry infrastructure for the nearby market populous of Baltimore and Washington D.C.. As Gas temperature is lowered, the compressibility of the gas reaches an optimum value. The compressibility of the gas, and the resultant gas density, is a function of temperature and pressure. This relationship can be used to commercial advantage by reducing the size of a storage cavern for a given working volume of natural gas. This study looks at this relationship and and the potential for commercialization of the process in a storage application. A conceptual process design, and cavern design were developed for various operating conditions. Potential site locations were considered and a typical plant layout was developed. In addition a geomechanical review of the proposed cavern design was performed, evaluating the stability of the mine rooms and shafts, and the effects of the refrigerated gas temperatures on the stability of the cavern. Capital and operating cost estimates were also developed for the various temperature cases considered. The cost estimates developed were used to perform a comparative market analysis of this type of gas storage system to other systems that are commercially used in the region of the study.

  15. Tabletop thermoacoustic refrigerator for demonstrations Daniel A. Russell and Pontus Weibulla)

    E-Print Network [OSTI]

    Russell, Daniel A.

    Tabletop thermoacoustic refrigerator for demonstrations Daniel A. Russell and Pontus Weibulla; accepted 22 April 2002 An inexpensive less than $25 tabletop thermoacoustic refrigerator for demonstration in the literature, this demonstration model effectively illustrates the behavior of a thermoacoustic refrigerator

  16. Energy Efficient Design, Retrofit and Control of Evaporative Condensers in Ammonia Refrigeration Systems

    E-Print Network [OSTI]

    Kissock, Kelly

    Energy Efficient Design, Retrofit and Control of Evaporative Condensers in Ammonia Refrigeration ABSTRACT Ammonia refrigeration systems typically offer many energy efficiency opportunities because efficiency of ammonia refrigeration systems. Introduction About 7.5% of the total manufacturing energy

  17. Floating loop method for cooling integrated motors and inverters using hot liquid refrigerant

    DOE Patents [OSTI]

    Hsu, John S.; Ayers, Curtis W.; Coomer, Chester; Marlino, Laura D.

    2007-03-20

    A method for cooling vehicle components using the vehicle air conditioning system comprising the steps of: tapping the hot liquid refrigerant of said air conditioning system, flooding a heat exchanger in the vehicle component with said hot liquid refrigerant, evaporating said hot liquid refrigerant into hot vapor refrigerant using the heat from said vehicle component, and returning said hot vapor refrigerant to the hot vapor refrigerant line in said vehicle air conditioning system.

  18. Optimizing Cooling Tower Performance- Refrigeration Systems, Chemical Plants, and Power Plants all Have A Resource Quietly Awaiting Exploitation-Cold Water!! 

    E-Print Network [OSTI]

    Burger, R.

    1990-01-01

    TOWER PERFORMANCE REFRIGERATION SYSTEMS, CHEMICAL PLANTS, AND POWER PLANTS ALL HAVE A RESOURCE QUIETLY AWAITING EXPLOITATION - COLD WATER!! ROBERT BURGER President Burger and Associates, Inc. Dallas, Texas Cooling towers, because... of their seeming simplicity, are usually orphans of the facilities operation. We are all aware that cooling towers are the step-children of the chemical process plant, electric power generating station, and refrigeration system. While engineers are pretty...

  19. Electrochemical flow capacitors

    DOE Patents [OSTI]

    Gogotsi, Yury; Presser, Volker; Kumbar, Emin Caglan

    2015-11-05

    The present invention generally relates to devices for energy storage technologies, and more particularly to electrochemical flow capacitor systems and applications. In some aspects, these flow capacitors have at least one electrode comprising a non-stationary solid or semi-solid composition comprising supercapacitive particles and an electrolytic solvent in electrical communication with at least one current collector, and energy is stored and/or released by charging and/or discharging the electrode(s).

  20. Electrochemical flow capacitors

    DOE Patents [OSTI]

    Gogotsi, Yury; Presser, Volker; Kumbur, Emin Caglan

    2015-10-27

    The present invention generally relates to devices for energy storage technologies, and more particularly to electrochemical flow capacitor systems and applications. In some aspects, these flow capacitors have at least one electrode comprising a non-stationary solid or semi-solid composition comprising supercapacitive particles and an electrolytic solvent in electrical communication with at least one current collector, and energy is stored and/or released by charging and/or discharging the electrode(s).

  1. Remote electrochemical sensor

    DOE Patents [OSTI]

    Wang, Joseph (Las Cruces, NM); Olsen, Khris (Richland, WA); Larson, David (Las Cruces, NM)

    1997-01-01

    An electrochemical sensor for remote detection, particularly useful for metal contaminants and organic or other compounds. The sensor circumvents technical difficulties that previously prevented in-situ remote operations. The microelectrode, connected to a long communications cable, allows convenient measurements of the element or compound at timed and frequent intervals and instrument/sample distances of ten feet to more than 100 feet. The sensor is useful for both downhole groundwater monitoring and in-situ water (e.g., shipboard seawater) analysis.

  2. Changing Industrial Energy Behavior Via Education: Case Study of an Energy Efficiency Refrigeration Certification

    E-Print Network [OSTI]

    McClaren, Mersiha; Phoutrides, Steve; O'Neil, Nick; McRae, Marjorie

    2015-01-01

    refrigeration systems efficiently, while more executivesour refrigeration systems efficiently Middle manager (n=28)Value of Operating Equipment Efficiently Vendors are selling

  3. Changing Industrial Energy Behavior Via Education: Case Study of an Energy Efficiency Refrigeration Certification

    E-Print Network [OSTI]

    McClaren, Mersiha; Phoutrides, Steve; O'Neil, Nick; McRae, Marjorie

    2015-01-01

    Changing Industrial Energy Behavior Via Education: Casewith the operation of industrial refrigeration plants,aim was to encourage industrial refrigeration professionals

  4. GEA Refrigeration Technologies / GEA Refrigeration Germany GmbH Wolfgang Dietrich / Dr. Ole Fredrich

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    Technologies3 Achema 2012 // heat pumps using ammonia Industrial demand on heat in Germany Heatdemandin Fredrich GEA Grasso heat pumps using ammonia ­ the megawatt range #12;GEA Refrigeration Technologies2 Achema 2012 // heat pumps using ammonia Heat pumps using ammonia ­ a sustainable choice How to improve

  5. ELECTROCHEMICAL POWER FOR TRANSPORTATION

    SciTech Connect (OSTI)

    Cairns, Elton J.; Hietbrink, Earl H.

    1981-01-01

    This section includes some historical background of the rise and fall and subsequent rebirth of the electric vehicle; and a brief discussion of current transportation needs, and environmental and energy utilization issues that resulted in the renewed interest in applying electrochemical energy conversion technology to electric vehicle applications. Although energy utilization has evolved to be the most significant and important issue, the environmental issue will be discussed first in this section only because of its chronological occurrence. The next part of the chapter is a review of passenger and commercial electric vehicle technology with emphasis on vehicle design and demonstrated performance of vehicles with candidate power sources being developed. This is followed by a discussion of electrochemical power source requirements associated with future electric vehicles that can play a role in meeting modern transportation needs. The last part of the chapter includes first a discussion of how to identify candidate electrochemical systems that might be of interest in meeting electric vehicle power source requirements. This is then followed by a review of the current technological status of these systems and a discussion of the most significant problems that must be resolved before each candidate system can be a viable power source.

  6. Magnetic refrigeration apparatus with heat pipes

    DOE Patents [OSTI]

    Barclay, John A. (Los Alamos, NM); Prenger, Jr., F. Coyne (Madison, WI)

    1987-01-01

    A magnetic refrigerator operating in the 4 to 20 K range utilizes heat pipes to transfer heat to and from the magnetic material at the appropriate points during the material's movement. In one embodiment circular disks of magnetic material can be interleaved with the ends of the heat pipes. In another embodiment a mass of magnetic material reciprocatingly moves between the end of the heat pipe of pipes that transmits heat from the object of cooling to the magnetic material and the end of the heat pipe or pipes that transmits heat from the magnetic material to a heat sink.

  7. Magnetic refrigeration apparatus with heat pipes

    DOE Patents [OSTI]

    Barclay, J.A.; Prenger, F.C. Jr.

    1985-10-25

    A magnetic refrigerator operating in the 4 to 20 K range utilizes heat pipes to transfer heat to and from the magnetic material at the appropriate points during the material's movement. In one embodiment circular disks of magnetic material can be interleaved with the ends of the heat pipes. In another embodiment a mass of magnetic material reciprocatingly moves between the end of the heat pipe or pipes that transmits heat from the object of cooling to the magnetic material and the end of the heat pipe or pipes that transmits heat from the magnetic material to a heat sink.

  8. Commercial Refrigeration Equipment | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePower Ventures Jump to:Information9176632°,InformationRefrigeration

  9. Lanthanide Al-Ni base Ericsson cycle magnetic refrigerants

    DOE Patents [OSTI]

    Gschneidner, K.A. Jr.; Takeya, Hiroyuki

    1995-10-31

    A magnetic refrigerant for a magnetic refrigerator using the Ericsson thermodynamic cycle comprises DyAlNi and (Gd{sub 0.54}Er{sub 0.46})AlNi alloys having a relatively constant {Delta}Tmc over a wide temperature range. 16 figs.

  10. Modeling of advanced integrated circuit planarization processes : electrochemical-mechanical planarization (eCMP), STI CMP using non-conventional slurries

    E-Print Network [OSTI]

    Johnson, Joy Marie

    2009-01-01

    Progression of technology nodes in integrated circuit design is only possible if there are sustainable, cost-efficient processes by which these designs can be implemented. As future technologies are increasing device ...

  11. CX-EWS: A new process for the electrochemical treatment of the spent lead-acid batteries by obtaining electrolytic lead and elemental sulphur

    SciTech Connect (OSTI)

    Olper, M. [Ecowin S.r.l., Milan (Italy); Morocutti, S. [Engitec Impianti S.p.A., Milan (Italy)

    1995-12-31

    After two years of extensive research a new and innovative modification to the CX-EW process has been exploited. This process, called CX-EWS, avoids completely all the critical aspects of the previous process which affected the cost of the energy, of the chemicals and of the maintenance of the insoluble anodes. All these benefits reflect a saving of about 30% of the operating costs compared to the present traditional production and allow for a total operating costs of less than 6.5 cts/lb. lead (net of raw material cost). With this new technology it is allowed for the first time the treatment in the same plant facilities of both primary lead sulfide concentrate and spent batteries. The paper describes the technical and economical aspect of the new process with a Feasibility study for 150.000 t/y spent battery facility throughput.

  12. Design issues of a thermoacoustic refrigerator and its heat exchangers

    SciTech Connect (OSTI)

    Wetzel, M.; Herman, C.

    1996-12-31

    Thermoacoustic refrigeration is a fast advancing new refrigeration technology. Performance calculations indicate remarkable values for the thermoacoustic core of a thermoacoustic refrigerator. The thermoacoustic core is responsible for pumping heat from a cold to a hot temperature reservoir. However, the systems necessary to support the thermoacoustic core, such as heat exchangers and acoustic drivers are the weak points of this refrigeration technology. Particularly, heat exchangers were designed so far without any optimization. A reason for this is the lack of knowledge of the flow structures and heat transfer phenomena at the interface between the thermoacoustic core and the heat exchangers. For the purpose of gaining better insight, the authors built a thermoacoustic refrigerator model and applied visualization techniques, such as smoke injection and holographic interferometry, to visualize the flow and temperature fields at the interface.

  13. Assessment of Environmentally Friendly Refrigerants for Window Air Conditioners

    SciTech Connect (OSTI)

    Bansal, Pradeep [ORNL] [ORNL; Shen, Bo [ORNL] [ORNL

    2014-01-01

    This paper presents technical assessment of environmentally friendly refrigerants for window air conditioners that currently use refrigerant R410A for residential and commercial applications. The alternative refrigerants that are studied for its replacement include R32, R600a, R290, R1234yf, R1234ze and a mixture of R32 (90% molar concentration) and R125 (10% molar concentration). Baseline experiments were performed on a window unit charged with R410A. The ORNL Heat Pump Design Model was calibrated with the baseline data and was used to assess the comparative performance of the WAC with alternative refrigerants. The paper discusses the advantages and disadvantages of each refrigerants and their suitability for window air conditioners.

  14. Analysis of Environmentally Friendly Refrigerant Options for Window Air Conditioners

    SciTech Connect (OSTI)

    Bansal, Pradeep [ORNL; Shen, Bo [ORNL

    2015-01-01

    This paper presents a technical assessment of environmentally friendly refrigerants as alternatives to R410A for window air conditioners. The alternative refrigerants that are studied for its replacement include R32, a mixture of R32/R125 with 90%/10% molar concentration, R600a, R290, R1234yf, R1234ze and R134a. Baseline experiments were performed on a window unit charged with R410A. The heat pump design model (HPDM) was modified and calibrated with the baseline data and was used to evaluate the comparative performance of the WAC with alternative refrigerants. The paper discusses the advantages and disadvantages of each refrigerants and their suitability for window air conditioners. Among all the refrigerants studied, R32 offers the best efficiency and the lowest Global Warming Potential (GWP), and hence its use will result in the overall environmental friendliness.

  15. New technologies for refrigeration without CFCs

    SciTech Connect (OSTI)

    Swift, G.W.

    1992-09-01

    Today the appliance industry and other cooling industries are facing the double challenge of eliminating environmentally harmful CFCs while simultaneously improving energy efficiency. These challenges will force this industry to make tremendous changes and to work out many difficult problems, ranging from choice of technology through production-line retooling to product-liability concerns. Three new cooling technologies--sonic compression, thermoacoustic refrigeration, and Malone refrigeration--have been developed at least in part at Los Alamos National Laboratory. We will discuss the principles, features, and status of each of these three technologies. With these three examples we hope to show that mechanical compression and subsequent evaporation of CFCs is not the only potentially practical way to produce cooling. These examples are only three of many alternative cooling technologies. No new technology can be guaranteed a success before development is complete, from either an economic or engineering point of view. But enough alternative cooling technologies exist, and the probability for success of each technology is high enough, that one or more of these technologies can almost certainly be produced at reasonable cost, eliminate CFCS, and reduce the consumption of electricity.

  16. Advanced Hybrid Water Heater using Electrochemical Compressor...

    Energy Savers [EERE]

    Advanced Hybrid Water Heater using Electrochemical Compressor Advanced Hybrid Water Heater using Electrochemical Compressor Xergy is using its Electro Chemical Compression (ECC)...

  17. IEA Heat Pump Conference 2011, 16 -19 May 2011, Tokyo, Japan ON SIDE REFRIGERANT MEASUREMENT OF HEAT PUMP

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    - 1 - 10th IEA Heat Pump Conference 2011, 16 - 19 May 2011, Tokyo, Japan ON SIDE REFRIGERANT MEASUREMENT OF HEAT PUMP SEASONAL PERFORMANCES C. T. Tran, PhD student, Centre for Energy and Processes, MINES, Research Engineer, ENERBAT, Electricity of France R&D, Moret/Loing, France Abstract Heat pump systems have

  18. Materials and Processes for Direct Sun-to-Fuel Chemical Transformations Solar radiation can be used to drive heterogeneous electrochemical reactions at the

    E-Print Network [OSTI]

    Nair, Sankar

    Materials and Processes for Direct Sun-to-Fuel Chemical Transformations Solar radiation can be used and an efficient means for solar radiation delivery and trapping, poses a major challenge to the commercialization, resulting in the production of solar fuels, including hydrogen via water reduction or hydrocarbons (methane

  19. Metal halogen electrochemical cell

    SciTech Connect (OSTI)

    Walsh, F.M.

    1986-06-03

    An electrochemical cell is described having a metal anode selected from the group consisting of zinc and cadmium; a bromine cathode; and, an aqueous electrolyte containing a metal bromide, the metal having the same metal as the metal of the anode, the improvement comprising: a bromine complexing agent in the aqueous metal bromide electrolyte consisting solely of a tetraorgano substituted ammonium salt, which salt is soluble of water and forms and substantially water immiscible liquid bromine complex at temperatures in the range of about 10/sup 0/C. to about 60/sup 0/C. and wherein the tetraorgano substituted ammonium salt is selected from asymmetric quaternary ammonium compounds.

  20. Electrochemical thinning of silicon

    DOE Patents [OSTI]

    Medernach, John W. (Albuquerque, NM)

    1994-01-01

    Porous semiconducting material, e.g. silicon, is formed by electrochemical treatment of a specimen in hydrofluoric acid, using the specimen as anode. Before the treatment, the specimen can be masked. The porous material is then etched with a caustic solution or is oxidized, depending of the kind of structure desired, e.g. a thinned specimen, a specimen, a patterned thinned specimen, a specimen with insulated electrical conduits, and so on. Thinned silicon specimen can be subjected to tests, such as measurement of interstitial oxygen by Fourier transform infra-red spectroscopy (FTIR).

  1. Electrochemical thinning of silicon

    DOE Patents [OSTI]

    Medernach, J.W.

    1994-01-11

    Porous semiconducting material, e.g. silicon, is formed by electrochemical treatment of a specimen in hydrofluoric acid, using the specimen as anode. Before the treatment, the specimen can be masked. The porous material is then etched with a caustic solution or is oxidized, depending of the kind of structure desired, e.g. a thinned specimen, a specimen, a patterned thinned specimen, a specimen with insulated electrical conduits, and so on. Thinned silicon specimen can be subjected to tests, such as measurement of interstitial oxygen by Fourier transform infra-red spectroscopy (FTIR). 14 figures.

  2. Remote electrochemical sensor

    DOE Patents [OSTI]

    Wang, J.; Olsen, K.; Larson, D.

    1997-10-14

    An electrochemical sensor is described for remote detection, particularly useful for metal contaminants and organic or other compounds. The sensor circumvents technical difficulties that previously prevented in-situ remote operations. The microelectrode, connected to a long communications cable, allows convenient measurements of the element or compound at timed and frequent intervals and instrument/sample distances of ten feet to more than 100 feet. The sensor is useful for both downhole groundwater monitoring and in-situ water (e.g., shipboard seawater) analysis. 21 figs.

  3. An Evaluation of the Environmental Impact of Different Commercial Supermarket Refrigeration Systems Using Low Global Warming Potential Refrigerants

    SciTech Connect (OSTI)

    Beshr, Mohamed; Aute, Vikrant; Abdelaziz, Omar; Fricke, Brian A; Radermacher, Reinhard

    2014-01-01

    Commercial refrigeration systems consumed 1.21 Quads of primary energy in 2010 and are known to be a major source for refrigerant charge leakage into the environment. Thus, it is important to study the environmental impact of commercial supermarket refrigeration systems and improve their design to minimize any adverse impacts. The system s Life Cycle Climate Performance (LCCP) was presented as a comprehensive metric with the aim of calculating the equivalent mass of carbon dioxide released into the atmosphere throughout its lifetime, from construction to operation and destruction. In this paper, an open source tool for the evaluation of the LCCP of different air-conditioning and refrigeration systems is presented and used to compare the environmental impact of a typical multiplex direct expansion (DX) supermarket refrigeration systems based on three different refrigerants as follows: two hydrofluorocarbon (HFC) refrigerants (R-404A, and R-407F), and a low global warming potential (GWP) refrigerant (N-40). The comparison is performed in 8 US cities representing different climates. The hourly energy consumption of the refrigeration system, required for the calculation of the indirect emissions, is calculated using a widely used building energy modeling tool (EnergyPlus). A sensitivity analysis is performed to determine the impact of system charge and power plant emission factor on the LCCP results. Finally, we performed an uncertainty analysis to determine the uncertainty in total emissions for both R-404A and N-40 operated systems. We found that using low GWP refrigerants causes a considerable drop in the impact of uncertainty in the inputs related to direct emissions on the uncertainty of the total emissions of the system.

  4. Electrochemical planarization of copper surfaces with submicron features

    SciTech Connect (OSTI)

    Chalupa, R.; Andryushchenko, T.; Han, J.; Ghosh, T.; Shankar, S.; Fischer, P. [Design Technology Solutions Department, Intel Corporation, Hillsboro, Oregon 97124 (United States); Components Research Department, Intel Corporation, Hillsboro, Oregon 97124 (United States); Design Technology Solutions Department, Intel Corporation, Hillsboro, Oregon 97124 (United States); Components Research Department, Intel Corporation, Hillsboro, Oregon 97124 (United States)

    2007-07-15

    Electrochemical planarization (ECP) of copper surfaces in a phosphoric acid-based electrolyte solution is discussed. A first-principles, quantum chemistry modeling work is presented that further validates the water-facilitated (and water rate limited) chemistry model for copper oxidation at the anode. This model has been previously deduced by other researchers [R. Vidal and A. West, J. Electrochem. Soc. 142, 2689 (1995); B. Du and I. I. Suni, J. Appl. Electrochem. 34, 1215 (2004); R. Vidal and A. West J. Electrochem. Soc. 142, 2682 (1995)] based on electrochemical experiments. Resulting water-limited model is validated against experimental data and applied to study the planarization behavior of a set of surface features. Aspect ratios and dimensions of these features were chosen to represent realistic (nonidealized, low aspect ratio structures) post-Damascene electroplate surface topography. Results are presented in a form of remaining feature amplitude versus mean copper thickness removed [A. C. West et al., J. Electrochem. Soc. 152, C652 (2005)]--allowing at-a-glance evaluation of the process against desired targets. The dominant effects of the mass transport boundary layer (BL) thickness on this planarization efficiency are discussed as are the challenges seen at typical flow conditions in ECP systems. Impact of changing the BL thickness and the requisite modulation of flow conditions analysis is included. Insights into practical challenges associated with BL buildup transient and associated surface roughening are summarized [D. Padhi et al., J. Electrochem. Soc. 150, 610 (2003)]. Challenges of applying ECP as a straightforward substitute to the robust chemical mechanical polish (CMP) process are significant. Practical modifications to upstream process flow to enable ECP would include optimized electroplating process or a CMP preprocessing step.

  5. A modified heat leak test facility employing a closed-cycle helium refrigerator

    SciTech Connect (OSTI)

    Boroski, W.N.

    1996-01-01

    A Heat Leak Test Facility (HLTF) has been in use at Fermilab for many years. The apparatus has successfully measured the thermal performance of a variety of cryostat components under simulated operating conditions. While an effective tool in the cryostat design process, the HLTF has several limitations. Temperatures are normally fixed at cryogen boiling points and run times are limited to cryogen inventory. Moreover, close personnel attention is required to maintain system inventories and sustain system equilibrium. To provide longer measurement periods without perturbation and to minimize personnel interaction, a new heat leak measurement facility (HLTF-2) has been designed that incorporates a closed-cycle helium refrigerator. The two-stage refrigerator provides cooling to the various temperature stations of the HLTF while eliminating the need for cryogens. Eliminating cryogen inventories has resulted in a reduction of the amount of direct personnel attention required.

  6. ISSUANCE 2015-10-20: Energy Conservation Program: Energy Conservation Standards for Refrigerated Beverage Vending Machines

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Energy Conservation Standards for Refrigerated Beverage Vending Machines

  7. Refrigerators and Refrigerator-Freezers (Appendix A1 after May 2, 2011) |

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested PartiesBuildingBudgetFinancial Opportunities »Refrigerator Standards

  8. Combined refrigeration system with a liquid pre-cooling heat exchanger

    DOE Patents [OSTI]

    Gaul, Christopher J.

    2003-07-01

    A compressor-pump unit for use in a vapor-compression refrigeration system is provided. The compressor-pump unit comprises a driving device including a rotatable shaft. A compressor is coupled with a first portion of the shaft for compressing gaseous refrigerant within the vapor-compression refrigeration system. A liquid pump is coupled with a second portion of the shaft for receiving liquid refrigerant having a first pressure and for discharging the received liquid refrigerant at a second pressure with the second pressure being higher than the first pressure by a predetermined amount such that the discharged liquid refrigerant is subcooled. A pre-cooling circuit is connected to the liquid pump with the pre-cooling circuit being exposed to the gaseous refrigerant whereby the gaseous refrigerant absorbs heat from the liquid refrigerant, prior to the liquid refrigerant entering the liquid pump.

  9. Bipolar pulse field for magnetic refrigeration

    DOE Patents [OSTI]

    Lubell, M.S.

    1994-10-25

    A magnetic refrigeration apparatus includes first and second steady state magnets, each having a field of substantially equal strength and opposite polarity, first and second bodies made of magnetocaloric material disposed respectively in the influence of the fields of the first and second steady state magnets, and a pulsed magnet, concentric with the first and second steady state magnets, and having a field which cycles between the fields of the first and second steady state magnets, thereby cyclically magnetizing and demagnetizing and thus heating and cooling the first and second bodies. Heat exchange apparatus of suitable design can be used to expose a working fluid to the first and second bodies of magnetocaloric material. A controller is provided to synchronize the flow of working fluid with the changing states of magnetization of the first and second bodies. 2 figs.

  10. Electrochemical sensor for monitoring electrochemical potentials of fuel cell components

    DOE Patents [OSTI]

    Kunz, Harold R. (Vernon, CT); Breault, Richard D. (Coventry, CT)

    1993-01-01

    An electrochemical sensor comprised of wires, a sheath, and a conduit can be utilized to monitor fuel cell component electric potentials during fuel cell shut down or steady state. The electrochemical sensor contacts an electrolyte reservoir plate such that the conduit wicks electrolyte through capillary action to the wires to provide water necessary for the electrolysis reaction which occurs thereon. A voltage is applied across the wires of the electrochemical sensor until hydrogen evolution occurs at the surface of one of the wires, thereby forming a hydrogen reference electrode. The voltage of the fuel cell component is then determined with relation to the hydrogen reference electrode.

  11. Comprehensive Compressor Calorimeter Testing of Lower-GWP Alternative Refrigerants for Heat Pump and Medium Temperature Refrigeration Applications

    SciTech Connect (OSTI)

    Shrestha, Som S; Sharma, Vishaldeep; Abdelaziz, Omar

    2014-01-01

    In response to environmental concerns raised by the use of refrigerants with high Global Warming Potential (GWP), the Air-Conditioning, Heating, and Refrigeration Institute (AHRI) has launched an industry-wide cooperative research program, referred to as the Low-GWP Alternative Refrigerants Evaluation Program (AREP), to identify and evaluate promising alternative refrigerants for major product categories. This paper reports one of the Oak Ridge National Laboratory (ORNL) contributions to AREP. It compares performance of alternative refrigerants to that of R-410A and R-404A for heat pump and medium temperature applications, respectively. The alternatives reported in this paper are: R-32, DR-5, and L-41a for R-410A and ARM-31a, D2Y-65, L-40, and a mixture of R-32 and R-134a for R-404A. All performance comparison tests were conducted using scroll compressors of ~1.85 tons (6.5 kW) cooling capacity. Tests were conducted over a range of combinations of saturation suction and saturation discharge temperatures for both compressors. The tests showed that, in general, energy efficiency ratio (EER) and cooling capacity of R-410A alternative refrigerants were slightly lower than that of the baseline refrigerant with a moderate increases in discharge temperature. On the other hand, R-404A alternative refrigerants showed relative performance dependence on saturation suction and saturation discharge temperatures and larger increases in discharge temperature than for the R-410A alternatives. This paper summarizes the relative performance of all alternative refrigerants compared to their respective baseline.

  12. Renewable-reagent electrochemical sensor

    DOE Patents [OSTI]

    Wang, J.; Olsen, K.B.

    1999-08-24

    A new electrochemical probe(s) design allowing for continuous (renewable) reagent delivery is described. The probe comprises an integrated membrane sampling/electrochemical sensor that prevents interferences from surface-active materials and greatly extends the linear range. The probe(s) is useful for remote or laboratory-based monitoring in connection with microdialysis sampling and electrochemical measurements of metals and organic compounds that are not readily detected in the absence of reacting with the compound. Also disclosed is a method of using the probe(s). 19 figs.

  13. Renewable-reagent electrochemical sensor

    DOE Patents [OSTI]

    Wang, Joseph (Las Cruces, NM); Olsen, Khris B. (Richland, WA)

    1999-01-01

    A new electrochemical probe(s) design allowing for continuous (renewable) reagent delivery. The probe comprises an integrated membrane-sampling/electrochemical sensor that prevents interferences from surface-active materials and greatly extends the linear range. The probe(s) is useful for remote or laboratory-based monitoring in connection with microdialysis sampling and electrochemical measurements of metals and organic compounds that are not readily detected in the absence of reacting with the compound. Also disclosed is a method of using the probe(s).

  14. Electrochemical catalyst recovery method

    DOE Patents [OSTI]

    Silva, L.J.; Bray, L.A.

    1995-05-30

    A method of recovering catalyst material from latent catalyst material solids includes: (a) combining latent catalyst material solids with a liquid acid anolyte solution and a redox material which is soluble in the acid anolyte solution to form a mixture; (b) electrochemically oxidizing the redox material within the mixture into a dissolved oxidant, the oxidant having a potential for oxidation which is effectively higher than that of the latent catalyst material; (c) reacting the oxidant with the latent catalyst material to oxidize the latent catalyst material into at least one oxidized catalyst species which is soluble within the mixture and to reduce the oxidant back into dissolved redox material; and (d) recovering catalyst material from the oxidized catalyst species of the mixture. The invention is expected to be particularly useful in recovering spent catalyst material from petroleum hydroprocessing reaction waste products having adhered sulfides, carbon, hydrocarbons, and undesired metals, and as well as in other industrial applications. 3 figs.

  15. Thermodynamic Evaluation of Low-Global Warming Potential Refrigerants

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermodynamic Evaluation of Low-GWP Refrigerants Mark O. McLinden National Institute of Standards and Technology markm@boulder.nist.gov; 303-497-3580 April 3, 2013 Optimization...

  16. Availability of refrigerants for heat pumps in Europe

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    grids Smart cities #12;8 Residential HPs Refrigerants Use of aero-geo- +hydrothermal renewable energy cooling and heating Residential Future: Heating of electric cars and cooling the batteries Future: Smart

  17. Comparison of Several Eco-Friendly Refrigeration Technologies 

    E-Print Network [OSTI]

    Tang, C.; Luo, Q.; Li, X.; Zhu, X.

    2006-01-01

    will be liquefied. Heat discharged by liquefaction passes through condenser 2 and exchanges heat with refrigerant (such as air or water). When stop heating, adsorbent becomes cool, its adsorbing capacity gradually enhances again. At this moment, it adsorb...

  18. Duracold Refrigeration Manufacturing: Proposed Penalty (2013-CE-5342)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Duracold Refrigeration Manufacturing Company, LLC failed to certify a variety of walk-in cooler or freezer components as compliant with the applicable energy conservation standards.

  19. Commercial Refrigerator Door: Proposed Penalty (2013-CE-5351)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that Commercial Refrigerator Door Company, Inc. failed to certify a variety of walk-in cooler or freezer components as compliant with the applicable energy conservation standards.

  20. Synchronous temperature rate control for refrigeration with reduced energy consumption

    DOE Patents [OSTI]

    Gomes, Alberto Regio; Keres, Stephen L.; Kuehl, Steven J.; Litch, Andrew D.; Richmond, Peter J.; Wu, Guolian

    2015-09-22

    Methods of operation for refrigerator appliance configurations with a controller, a condenser, at least one evaporator, a compressor, and two refrigeration compartments. The configuration may be equipped with a variable-speed or variable-capacity compressor, variable speed evaporator or compartment fans, a damper, and/or a dual-temperature evaporator with a valve system to control flow of refrigerant through one or more pressure reduction devices. The methods may include synchronizing alternating cycles of cooling each compartment to a temperature approximately equal to the compartment set point temperature by operation of the compressor, fans, damper and/or valve system. The methods may also include controlling the cooling rate in one or both compartments. Refrigeration compartment cooling may begin at an interval before or after when the freezer compartment reaches its lower threshold temperature. Freezer compartment cooling may begin at an interval before or after when the freezer compartment reaches its upper threshold temperature.

  1. Modeling of Refrigerant Flow Through Flexible Short Tube Orifices 

    E-Print Network [OSTI]

    Mohamed, Ramadan

    2000-01-01

    Single-phase flow of refrigerants R-22, R-13a, and R-41a through flexible short tube orifices with three different geometries and a range in upstream operating conditions was modeling using the finite element method, FEM. ...

  2. National Weatherization Assistance Program Evaluation: Assessment of Refrigerator Energy Use

    SciTech Connect (OSTI)

    Tonn, Bruce Edward; Goeltz, Rick

    2015-03-01

    This report assesses the energy consumption characteristics and performance of refrigerators that were monintored as a component of the Indoor Air Quality Study that itself was a component of the retrospective evaluation of the Department of Energy's Weatherization Assistance Program.

  3. Optimal Sequencing of Central Refrigeration Equipment in an Industrial Plant 

    E-Print Network [OSTI]

    Fiorino, D. P.; Priest, J. W.

    1986-01-01

    A model was developed to find a viable solution to the problem of selecting the optimal sequence of refrigeration equipment (chillers, cooling towers, pumps) to operate in a Central Utility Plant. The optimal equipment sequence is that sequence...

  4. Commissioning report of the MuCool 5 Tesla solenoid coupled with helium refrigerator

    SciTech Connect (OSTI)

    Geynisman, Michael; /Fermilab

    2010-05-01

    MuCool 5T solenoid was successfully cooled down and operated coupled with MTA 'Brown' refrigerator. The system performed as designed with substantial performance margin. All process alarms and interlocks, as well as ODH and fire alarms, were active and performed as designed. The cooldown of the refrigerator started from warm conditions and took 44 hours to accumulate liquid helium level and solenoid temperature below 5K. Average liquid nitrogen consumption for the refrigerator precool and solenoid shield was measured as 20 gal/hr (including boil-off). Helium losses were small (below 30 scfh). The system was stable and with sufficient margin of performance and ran stably without wet expansion engine. Quench response demonstrated proper operation of the relieving devices and pointed to necessity of improving tightness of the relieving manifolds. Boil-off test demonstrated average heat load of 3 Watts for the unpowered solenoid. The solenoid can stay up to 48 hours cold and minimally filled if the nitrogen shield is maintained. A list of improvements includes commencing into operations the second helium compressor and completion of improvements and tune-ups for system efficiency.

  5. Demand Side Management (DSM) Through Absorption Refrigeration Systems 

    E-Print Network [OSTI]

    Chao, P. Y.; Shukla, D.; Amarnath, A.; Mergens, E.

    1992-01-01

    will be illustrated by two recent case studies. INTRODUCTION This paper deals with a Demand Side Management (DSM) option of using waste heat for refrigeration. Absorption Refrigeration from waste heat offers a viable option for DSM. This can profitably either... years. The potential for avoided cost through DSM will approach $45 billion over the next decade(1,2). Waste Energy And Pollutants The U.S. industry consumes more than 30 quads (quadrillion Btu) of energy each year. About one third...

  6. US DRIVE Electrochemical Energy Storage Technical Team Roadmap...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrochemical Energy Storage Technical Team Roadmap US DRIVE Electrochemical Energy Storage Technical Team Roadmap This U.S. DRIVE electrochemical energy storage roadmap...

  7. Parameter spaces and design optimization of thermoacoustic refrigerators

    SciTech Connect (OSTI)

    Wetzel, M.; Herman, C.

    1996-12-31

    In the last two decades thermoacoustic refrigerators were developed in research laboratories with the goal to understand the basic physics and thermodynamics of thermoacoustic heat pumping. These research efforts led to a good understanding of this new environmentally safe refrigeration technology that employs acoustic power to pump heat. Consequently the next step is to improve and optimize the performance of thermoacoustic refrigerators and seek commercial applications. For this purpose, the need for fast and simple engineering estimates arises. By implementing the simplified linear model of thermoacoustic refrigerators--the short stack boundary layer approximation--such design estimates were derived and presented in this paper in the form of a design algorithm. Calculations obtained with this algorithm predict values for the Coefficient Of Performance (COP) of the order of 5 to 6. These values cannot be achieved at this time because of loss mechanisms in key parts of the thermoacoustic refrigerator, which are not quite understood yet. Nevertheless, these values are encouraging and gaining a better understanding of these loss mechanisms will be a big step towards the commercial market for this new environmentally safe refrigeration technology.

  8. Heat exchanger bypass system for an absorption refrigeration system

    DOE Patents [OSTI]

    Reimann, Robert C. (Lafayette, NY)

    1984-01-01

    A heat exchanger bypass system for an absorption refrigeration system is disclosed. The bypass system operates to pass strong solution from the generator around the heat exchanger to the absorber of the absorption refrigeration system when strong solution builds up in the generator above a selected level indicative of solidification of strong solution in the heat exchanger or other such blockage. The bypass system includes a bypass line with a gooseneck located in the generator for controlling flow of strong solution into the bypass line and for preventing refrigerant vapor in the generator from entering the bypass line during normal operation of the refrigeration system. Also, the bypass line includes a trap section filled with liquid for providing a barrier to maintain the normal pressure difference between the generator and the absorber even when the gooseneck of the bypass line is exposed to refrigerant vapor in the generator. Strong solution, which may accumulate in the trap section of the bypass line, is diluted, to prevent solidification, by supplying weak solution to the trap section from a purge system for the absorption refrigeration system.

  9. Improvement of the Performance for an Absorption Refrigeration System with Lithium bromide-water as Refrigerant by Increasing Absorption Pressure 

    E-Print Network [OSTI]

    Xie, G.; Sheng, G.; Li, G.; Pan, S.

    2006-01-01

    , the low COP of the absorption machine was limited seriously to compete with the refrigeration machine that is drove by electricity. Therefore, most researchers focus their attention on the improvement of performance of the absorption system through many...

  10. Supported liquid membrane electrochemical separators

    DOE Patents [OSTI]

    Pemsler, J. Paul (Lexington, MA); Dempsey, Michael D. (Revere, MA)

    1986-01-01

    Supported liquid membrane separators improve the flexibility, efficiency and service life of electrochemical cells for a variety of applications. In the field of electrochemical storage, an alkaline secondary battery with improved service life is described in which a supported liquid membrane is interposed between the positive and negative electrodes. The supported liquid membranes of this invention can be used in energy production and storage systems, electrosynthesis systems, and in systems for the electrowinning and electrorefining of metals.

  11. Reliability Design and Case Study of a Refrigerator Compressor Subjected to Repetitive Loads, International Journal of Refrigeration 

    E-Print Network [OSTI]

    Woo, S.; O'Neal, D.L.; Pecht, M.

    2009-01-01

    Control Parameters C1: Compressor specifications C2: Condenser specifications C3: Capillary specifications C4: Evaporator specifications Fig. 2 – Parameter diagram of refrigeration cycle.To introduce the Bx life, the characteristic life in the Weibull... ofcharacteristic life in Eq. (4). When the number of failed samples is below four, it follows the Poisson distribution (Ryu and Chang, 2005). At a sixty-percent confidence level, the characteristic life is defined as on refrigeration cycle.cycles and the number...

  12. Heat pump employing optimal refrigerant compressor for low pressure ratio applications

    DOE Patents [OSTI]

    Ecker, Amir L. (Dallas, TX)

    1982-01-01

    What is disclosed is a heat pump apparatus for conditioning a fluid characterized by a fluid handler for circulating the fluid in heat exchange relationship with a refrigerant fluid; two refrigerant heat exchangers; one for effecting the heat exchange with the fluid and a second refrigerant-heat exchange fluid heat exchanger for effecting a low pressure ratio of compression of the refrigerant; a rotary compressor for compressing the refrigerant with low power consumption at the low pressure ratio; at least one throttling valve connecting at the inlet side of heat exchanger in which liquid refrigerant is vaporized; a refrigerant circuit serially connecting the above elements; refrigerant in the circuit; a source of heat exchange fluid; heat exchange fluid circulating device and heat exchange fluid circuit for circulating the heat exchange fluid in heat exchange relationship with the refrigerant.

  13. 11-14 An ideal vapor-compression refrigeration cycle with refrigerant-134a as the working fluid is considered. The rate of heat removal from the refrigerated space, the power input to the compressor, the rate of heat rejection to the environment,

    E-Print Network [OSTI]

    Kostic, Milivoje M.

    -compression refrigeration cycle, the refrigerant enters the compressor as a saturated vapor at the evaporator pressure11-7 11-14 An ideal vapor-compression refrigeration cycle with refrigerant-134a as the working fluid is considered. The rate of heat removal from the refrigerated space, the power input

  14. Electrotechnologies in Process Industries 

    E-Print Network [OSTI]

    Amarnath, K. R.

    1989-01-01

    applications of innovative electrotechnologies in these sectors. APPLICATIONS Electricity is predominantly used in three ways in process industries: 1. Motor Drives 2. Process Heating 3. Electrochemical Processes Motor drives are mainly used in prime..., infrared, and ultraviolet heating have found a variety of applications, and more are under development. ElectrOChemical processes for separation and synthesis (such as Chlor-Alkali production) are significant users of electricity. New processes...

  15. Quantification of Electrochemical Nanoscale Processes in Lithium...

    Office of Scientific and Technical Information (OSTI)

    for a wide variety of portable electronic devices, electric vehicles and renewable energy applications. In addition, extensive worldwide research efforts are now being devoted...

  16. Sandia Energy - Electro-Chemical Processes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) byMultidayAlumniProjectsCyberNotLED Lighting

  17. Method of removing an immiscible lubricant from a refrigeration system and apparatus for same

    DOE Patents [OSTI]

    Spauschus, Hans O. (Stockbridge, GA); Starr, Thomas L. (Roswell, GA)

    1999-01-01

    A method of separating an immiscible lubricant from a liquid refrigerant in a refrigerating system including a compressor, a condenser, an expansion device and an evaporator, wherein the expansion device is connected to the condenser by a liquid refrigerant flow line for liquid refrigerant and immiscible lubricant. The method comprising slowing the rate of flow of the liquid refrigerant and immiscible lubricant between the condenser and the expansion device such that the liquid refrigerant and the immiscible lubricant separate based upon differences in density. The method also comprises collecting the separated immiscible lubricant in a collection chamber in fluid communication with the separated immiscible lubricant. Apparatus for performing the method is also disclosed.

  18. Electrochemical polishing of notches

    DOE Patents [OSTI]

    Kephart, Alan R. (Scotia, NY); Alberts, Alfred H. (Scotia, NY)

    1989-01-01

    An apparatus and method are disclosed for the selective electrochemical polishing of a lateral tip of a deep longitudinal notch in a work piece used to test crack initiation properties of materials. A DC power source is connected to the work piece and to an electrode disposed laterally along the distal end of an insulated body which is inserted in the longitudinal notch. The electrode and distal end of the body are disposed along the tip of the notch, but are spaced from the notch so as to provide a lateral passage for an electrolyte. The electrolyte is circulated through the passage so that the electrolyte only contacts the work piece adjacent the passage. Conveniently, the electrolyte is circulated by use of an inlet tube and an outlet tube provided at opposite ends of the passage. These tubes are preferably detachably located adjacent the ends of the passage and suitable seals are provided. A holding device including arms to which the tubes are attached is conveniently used to rapidly and easily locate the test specimen with the passage aligned with the tubes. The electrode is preferably a wire which is located in grooves along the distal end of the insulated body and up one side of the body or a plastic sheath insulated thin metal strip.

  19. Electrochemical polishing of notches

    DOE Patents [OSTI]

    Kephart, A.R.; Alberts, A.H.

    1989-02-21

    An apparatus and method are disclosed for the selective electrochemical polishing of a lateral tip of a deep longitudinal notch in a work piece used to test crack initiation properties of materials. A DC power source is connected to the work piece and to an electrode disposed laterally along the distal end of an insulated body which is inserted in the longitudinal notch. The electrode and distal end of the body are disposed along the tip of the notch, but are spaced from the notch so as to provide a lateral passage for an electrolyte. The electrolyte is circulated through the passage so that the electrolyte only contacts the work piece adjacent the passage. Conveniently, the electrolyte is circulated by use of an inlet tube and an outlet tube provided at opposite ends of the passage. These tubes are preferably detachably located adjacent the ends of the passage and suitable seals are provided. A holding device including arms to which the tubes are attached is conveniently used to rapidly and easily locate the test specimen with the passage aligned with the tubes. The electrode is preferably a wire which is located in grooves along the distal end of the insulated body and up one side of the body or a plastic sheath insulated thin metal strip. 4 figs.

  20. The development of a proff of principle superfluid Joule-Thomson refrigerator for cooling below 1 Kelvin

    E-Print Network [OSTI]

    Miller, Franklin K., 1970-

    2005-01-01

    A new type of sub-Kelvin refrigerator, the superfluid Joule-Thomson refrigerator, has been developed and its performance has been experimentally verified. This refrigerator uses a liquid superfluid mixture of He and 4He ...

  1. Environmental assessment for proposed energy conservation standards for refrigerators, refrigerator-freezers, and freezers

    SciTech Connect (OSTI)

    NONE

    1996-01-01

    This Environmental Assessment (EA) on the candidate energy conservation standards for refrigerators, refrigerator-freezers, and freezers was prepared pursuant to the National Environmental Policy Act of 1969 (NEPA), regulations of the Council on Environmental Quality, Title 40, Code of Federal Regulations, Parts 1500 through 1508. The proposed energy conservation standard (Level 1) and the alternative standards are being reviewed in an energy-efficiency standards rulemaking that the Department has undertaken pursuant to the Energy Policy and Conservation Act, as amended by the National Energy Conservation Policy Act and the National Appliance Energy Conservation Act. The EA presents the associated environmental impacts from four energy conservation standards for this type of household appliance. For purposes of this EA, each standard is an alternative action and is compared to what is expected to happen if no new standards for this type of product were finalized, i.e., the no action alternative. Of the four energy conservation standard levels considered, standard level 4 has the highest level of energy efficiency and the largest environmental impact. The proposed action implementing Standard Level 1 would have the least environmental impacts, through emission reductions, of the four alternatives. The description of the standards results from the appliance energy-efficiency analyses conducted for the rulemaking. The presentation of environmental impacts for each of the alternatives appears at Section 3 of the EA.

  2. Electrochemical cell for in-situ x-ray characterization

    SciTech Connect (OSTI)

    Doughty, D.H.; Ingersoll, D.; Rodriguez, M.A.

    1998-08-04

    An electrochemical cell suitable for in-situ XRD analysis is presented. Qualitative information such as phase formation and phase stability can be easily monitored using the in-situ cell design. Quantitative information such as lattice parameters and kinetic behavior is also straightforward. Analysis of the LiMn&sub2;O&sub4; spinel using this cell design shows that the lattice undergoes two major structural shrinkages at approx. 4.0 V and approx. 4.07 V during charging. These shrinkages correlate well with the two electrochemical waves observed and indicate the likelihood of two separate redox processes which charging and discharging.

  3. Equipment specifications for an electrochemical fuel reprocessing plant

    SciTech Connect (OSTI)

    Hemphill, Kevin P [Los Alamos National Laboratory

    2010-01-01

    Electrochemical reprocessing is a technique used to chemically separate and dissolve the components of spent nuclear fuel, in order to produce new metal fuel. There are several different variations to electrochemical reprocessing. These variations are accounted for by both the production of different types of spent nuclear fuel, as well as different states and organizations doing research in the field. For this electrochemical reprocessing plant, the spent fuel will be in the metallurgical form, a product of fast breeder reactors, which are used in many nuclear power plants. The equipment line for this process is divided into two main categories, the fuel refining equipment and the fuel fabrication equipment. The fuel refining equipment is responsible for separating out the plutonium and uranium together, while getting rid of the minor transuranic elements and fission products. The fuel fabrication equipment will then convert this plutonium and uranium mixture into readily usable metal fuel.

  4. Counter-Top Thermoacoustic Refrigerator- An Experimental Investigation

    SciTech Connect (OSTI)

    Anwar, Mahmood; Ghazali, Normah Mohd

    2010-06-28

    Thermoacoustic phenomenon is a new alternative refrigeration technology. Though design and fabrication is complex for getting the desired effect, it is environmentally friendly and successful system showed that it is relatively easy to run compared to the traditional vapor compression refrigeration system. Currently, theories supporting the thermoacoustic refrigeration systems are yet to be comprehensive to make them commercially viable. Theoretical, experimental, and numerical studies are being done to address the thermodynamics-acoustics interactions. In this study, experimental investigations were completed to test the feasibility of the practical use of a thermoacoustic refrigerator in its counter-top form for future specific application. The system was designed and fabricated based on linear acoustic theory. Acoustic power was given by a loud speaker and thermoacoustic effects were measured in terms of the cooling effects produced at resonanance. Investigations showed that discrepancies between designed and working resonance frequency exist. Thermoacoutic cooling improved at a certain frequency, achieved when the working frequency was varied away from the design frequency. A cooling effect of 4.8 K below the ambient temperature of 23.3 deg. C was obtained from the counter-top thermoacoustic system. This system uses no refrigerants and no compressor to generate the cooling effect, a potential to be further investigated for a practical system.

  5. In Situ Tribo-Electrochemical Characterization of Diamond-Containing Materials 

    E-Print Network [OSTI]

    Xiao, Huaping

    2014-07-31

    and the diamond surface. In the present research, the wear mechanism of diamond-reinforced composite has been demonstrated. The amorphization-wear process of diamond can be real-timely monitored using electrochemical approach. The frication force between diamond...

  6. Electrochemical phenomena provide unique methods for materials synthesis and surface modification. Within this framework, the group

    E-Print Network [OSTI]

    Zhigilei, Leonid V.

    components for information storage, sensors and energy conversion devices. "Further the understanding or photoelectrochemical solar cells. Green Processing and Electrochemical Energy Conversion Various efforts/nano-electronics and magnetics, with a recent emphasis on energy conversion applications. Our work encompasses

  7. Pathways to Improved Lifetime of Electrochemical Energy Systems: Understanding the Influence of

    E-Print Network [OSTI]

    Bergman, Keren

    of Technology In novel materials for electrochemical energy storage and conversion, dynamic processes with silicon nanostructures (a novel negative electrode material for Li-ion batteries) is explored with in situ

  8. Modeling integrated photovoltaic-electrochemical devices using steady-state equivalent circuits

    E-Print Network [OSTI]

    Winkler, Mark Thomas

    We describe a framework for efficiently coupling the power output of a series-connected string of single-band-gap solar cells to an electrochemical process that produces storable fuels. We identify the fundamental efficiency ...

  9. Solutions for Summer Electric Power Shortages: Demand Response and its Applications in Air Conditioning and Refrigerating Systems

    E-Print Network [OSTI]

    Han, Junqiao; Piette, Mary Ann

    2008-01-01

    LBNL-63806 Refrigeration, Air Conditioning, & Electric Powerand its Applications in Air Conditioning and Refrigeratingand its applications in Air Conditioning and refrigerating

  10. A cryogen-free dilution refrigerator based Josephson qubit measurement system

    E-Print Network [OSTI]

    Tian, Ye; Yu, H. F.; Deng, H.; Xue, G. M.; Liu, D. T.; Ren, Y. F.; Chen, G.; Zheng, D. N.; Jing, X. N.; Lu, Li; Zhao, S. P.; Han, Siyuan

    2012-01-12

    We develop a small-signal measurement system on cryogen-free dilution refrigerator which is suitable for superconductingqubit studies. Cryogen-free refrigerators have several advantages such as less manpower for system operation and large sample...

  11. 1. For a refrigerator, you are given that 1 ,0 20 400 t p t = - ? ? . The ...

    E-Print Network [OSTI]

    Owner

    2011-04-28

    1. For a refrigerator, you are given that. 2. 0. 1. ,0. 20. 400 t t p t. = -. ? ? . The Purdue Actuarial club owns two refrigerators. One is brand new and one was ...

  12. Compatibility of refrigerants and lubricants with electrical sheet insulation under retrofit conditions

    SciTech Connect (OSTI)

    Doerr, R.G.; Waite, T.D.

    1996-11-01

    To determine whether exposure to the original refrigerant/mineral oil would affect compatibility of sheet insulation with alternative refrigerant/lubricant after retrofit, sheet insulation was exposed at elevated temperature to the original refrigerant and mineral oil for 500 hours, followed by exposure to the alternative refrigerant and lubricant for 500 hours. Most of the sheet insulation materials exposed to the alternative refrigerant and lubricant (after an initial exposure to the original refrigerant and mineral oil) appeared to be compatible with the alternative refrigerant and lubricant. The only concern was delamination and blistering of the sheet insulation containing Nomex, especially after removal of absorbed refrigerant at high temperature. This was attributed to incompatibility of the adhesive and not to the Nomex itself. Embrittlement of the polyethylene terephthalate (PET) sheet was initially observed, but 2048 subsequent tests under extremely dry conditions showed that embrittlement of the PET materials was attributed to moisture present during the exposure.

  13. Application Availability of Insulation Heat of the Terrace in a Rebuilt Refrigerator 

    E-Print Network [OSTI]

    Qu, C.; Sun, Y.; Chen, Z.

    2006-01-01

    HVAC Technologies for Energy Efficiency Vol.IV-1-5 Associate Master Professor Application Availability of Insulation Heat of the Terrace in a Rebuilt Refrigerator Chunmin Qu Yong Sun Zhonghai Chen Master... refrigerator; insulation heat; saving energy 1. INTRODUCTION The homoiothermal refrigerators that are built early day need be rebuilt to the cryogenic refrigerators along with the development continuously of market economy. The matching...

  14. Magnetic refrigeration apparatus with belt of ferro or paramagnetic material

    DOE Patents [OSTI]

    Barclay, J.A.; Stewart, W.F.; Henke, M.D.; Kalash, K.E.

    1986-04-03

    A magnetic refrigerator operating in the 12 to 77 K range utilizes a belt which carries ferromagnetic or paramagnetic material and which is disposed in a loop which passes through the center of a solenoidal magnet to achieve cooling. The magnetic material carried by the belt, which can be blocks in frames of a linked belt, can be a mixture of substances with different Curie temperatures arranged such that the Curie temperatures progressively increase from one edge of the belt to the other. This magnetic refrigerator can be used to cool and liquefy hydrogen or other fluids.

  15. The growth rate of gas hydrate from refrigerant R12

    SciTech Connect (OSTI)

    Kendoush, Abdullah Abbas; Jassim, Najim Abid [Centre of Engineering Physics, Ministry of Sciences and Technology, P.O. Box 765, Baghdad (Iraq); Joudi, Khalid A. [Al-Nahrain University, Baghdad (Iraq)

    2006-07-15

    Experimental and theoretical investigations were presented dealing with three phase direct-contact heat transfer by evaporation of refrigerant drops in an immiscible liquid. Refrigerant R12 was used as the dispersed phase, while water and brine were the immiscible continuous phase. A numerical solution is presented to predict the formation rate of gas hydrates in test column. The solution provided an acceptable agreement when compared with experimental results. The gas hydrate growth rate increased with time. It increased with increasing dispersed phase flow rate. The presence of surface-active sodium chloride in water had a strong inhibiting effect on the gas hydrate formation rate. (author)

  16. Magnetic refrigeration apparatus with belt of ferro or paramagnetic material

    DOE Patents [OSTI]

    Barclay, John A. (Madison, WI); Stewart, Walter F. (Marshall, WI); Henke, Michael D. (Los Alamos, NM); Kalash, Kenneth E. (Los Alamos, NM)

    1987-01-01

    A magnetic refrigerator operating in the 12 to 77K range utilizes a belt which carries ferromagnetic or paramagnetic material and which is disposed in a loop which passes through the center of a solenoidal magnet to achieve cooling. The magnetic material carried by the belt, which can be blocks in frames of a linked belt, can be a mixture of substances with different Curie temperatures arranged such that the Curie temperatures progressively increase from one edge of the belt to the other. This magnetic refrigerator can be used to cool and liquefy hydrogen or other fluids.

  17. Proceedings of the 1993 non-fluorocarbon insulation, refrigeration and air conditioning technology workshop

    SciTech Connect (OSTI)

    Not Available

    1994-09-01

    Sessions included: HFC blown polyurethanes, carbon dioxide blown foam and extruded polystyrenes, plastic foam insulations, evacuated panel insulation, refrigeration and air conditioning, absorption and adsorption and stirling cycle refrigeration, innovative cooling technologies, and natural refrigerants. Selected papers have been indexed separately for inclusion in the Energy Science and Technology Database.

  18. Exergy analysis of transcritical carbon dioxide refrigeration cycle with an expander

    E-Print Network [OSTI]

    Bahrami, Majid

    Exergy analysis of transcritical carbon dioxide refrigeration cycle with an expander Jun Lan Yang is performed for the transcritical carbon dioxide refrigeration cycles with a throttling valve attracted considerable attention. As one of the natural refrigerants, carbon dioxide has many excellent

  19. Chapter 19. Heat Engines and Refrigerators That's not smoke. It's clouds

    E-Print Network [OSTI]

    Dhamala, Mukesh

    the cooling towers around a large power plant. The power plant is generating electricity by turning heat and refrigerators. #12;Topics: · Turning Heat into Work · Heat Engines and Refrigerators · Ideal-Gas Heat Engines Addison-Wesley. · Ideal-Gas Refrigerators · The Limits of Efficiency · The Carnot Cycle #12;Chapter 19

  20. EFFECTS OF GAMMA RADIATION ON ELECTROCHEMICAL PROPERTIES OF IONIC LIQUIDS

    SciTech Connect (OSTI)

    Visser, A; Nicholas Bridges, N; Thad Adams, T; John Mickalonis, J; Mark02 Williamson, M

    2009-04-21

    The electrochemical properties of ionic liquids (ILs) make them attractive for possible replacement of inorganic salts in high temperature molten salt electrochemical processing of nuclear fuel. To be a feasible replacement solvent, ILs need to be stable in moderate and high doses of radiation without adverse chemical and physical effects. Here, we exposed seven different ILs to a 1.2 MGy dose of gamma radiation to investigate their physical and chemical properties as they related to radiological stability. The azolium-based ILs experienced the greatest change in appearance, but these ILs were chemically more stable to gamma radiation than some of the other classes of ILs tested, due to the presence of aromatic electrons in the azolium ring. All the ILs exhibited a decrease in their conductivity and electrochemical window (at least 1.1 V), both of which could affect the utility of ILs in electrochemical processing. The concentration of the irradiation decomposition products was less than 3 mole %, with no impurities detectable using NMR techniques.

  1. Sheet electrode for electrochemical systems

    DOE Patents [OSTI]

    Tsien, Hsue C. (Chatham Township, Morris County, NJ); Newby, Kenneth R. (Berkeley Heights, NJ); Grimes, Patrick G. (Westfield, NJ); Bellows, Richard J. (Westfield, NJ)

    1983-04-12

    An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.

  2. Separator material for electrochemical cells

    DOE Patents [OSTI]

    Cieslak, Wendy R. (1166 Laurel Loop NE., Albuquerque, NM 87122); Storz, Leonard J. (2215 Ambassador NE., Albuquerque, NM 87112)

    1991-01-01

    An electrochemical cell characterized as utilizing an aramid fiber as a separator material. The aramid fibers are especially suited for lithium/thionyl chloride battery systems. The battery separator made of aramid fibers possesses superior mechanical strength, chemical resistance, and is flame retardant.

  3. Separator material for electrochemical cells

    DOE Patents [OSTI]

    Cieslak, W.R.; Storz, L.J.

    1991-03-26

    An electrochemical cell is characterized as utilizing an aramid fiber as a separator material. The aramid fibers are especially suited for lithium/thionyl chloride battery systems. The battery separator made of aramid fibers possesses superior mechanical strength, chemical resistance, and is flame retardant.

  4. 2014-07-10 Issuance: Test Procedures for Refrigerators, Refrigerator-Freezers, and Freezers; Final Rule Correction

    Broader source: Energy.gov [DOE]

    This document is a pre-publication Federal Register final rule correction regarding test procedures for refrigerators, refrigerator-freezers, and freezers, as issued by the Deputy Assistant Secretary for Energy Efficiency on July 10, 2014. Though it is not intended or expected, should any discrepancy occur between the document posted here and the document published in the Federal Register, the Federal Register publication controls. This document is being made available through the Internet solely as a means to facilitate the public's access to this document.

  5. Purchasing Energy-Efficient Refrigerated Beverage Vending Machines

    Broader source: Energy.gov [DOE]

    FEMP provides acquisition guidance and Federal efficiency requirements across a variety of product categories, including refrigerated beverage vending machines, which are covered by the ENERGY STAR® program. Federal laws and requirements mandate that agencies meet these efficiency requirements in all procurement and acquisition actions that are not specifically exempted by law.

  6. Reliability of Heat Pumps Containing R410-A Refrigerant 

    E-Print Network [OSTI]

    McJimsey, B. A.; Cawley, D.

    1998-01-01

    of their potential destruction of ozone in the troposphere. Residential and commercial rooftop units usually contain hydrochlorofluorocarbon 22 , (also referred to as HCFC-22 or R-22). R-22 has been used successfully as a refrigerant in HVAC equipment for over 40...

  7. Superefficient Refrigerators: Opportunities and Challenges for Efficiency Improvement Globally

    SciTech Connect (OSTI)

    Shah, Nihar; Park, Won Young; Bojda, Nicholas; McNeil, Michael A.

    2014-08-01

    As an energy-intensive mainstream product, residential refrigerators present a significant opportunity to reduce electricity consumption through energy efficiency improvements. Refrigerators expend a considerable amount of electricity during normal use, typically consuming between 100 to 1,000 kWh of electricity per annum. This paper presents the results of a technical analysis done for refrigerators in support of the Super-efficient Equipment and Appliance Deployment (SEAD) initiative. Beginning from a base case representative of the average unit sold in India, we analyze efficiency improvement options and their corresponding costs to build a cost-versus-efficiency relationship. We then consider design improvement options that are known to be the most cost effective and that can improve efficiency given current design configurations. We also analyze and present additional super-efficient options, such as vacuum-insulated panels. We estimate the cost of conserved electricity for the various options, allowing flexible program design for market transformation programs toward higher efficiency. We estimate ~;;160TWh/year of energy savings are cost effective in 2030, indicating significant potential for efficiency improvement in refrigerators in SEAD economies and China.

  8. DEVELOPMENT OF A HIGH EFFICIENCY, AUTOMATIC DEFROSTING REFRIGERATOR-FREEZER

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    and W. David Lee Arthur D. Little, Inc. Abstract This paper describes the development of an energy in the design phase, a computer model was developed by Arthur D. Little, Inc. to simulate the cabinet Refrigeration, Inc., and Arthur D. Little, Inc. In combination, these seven design options were estimated

  9. Feasibility of Solar-Assisted Refrigerated Transport in Australia

    E-Print Network [OSTI]

    unit. This has proven to be reasonably economical, given the high cost of diesel fuel in the UK the fea- sibility of using photovoltaics to minimise the use of diesel generators in refrigerated because it competes with the price of electricity generated off-grid. The UK experience is compelling

  10. Layer of protection analysis applied to ammonia refrigeration systems 

    E-Print Network [OSTI]

    Zuniga, Gerald Alexander

    2009-05-15

    the risks in existing and future ammonia refrigeration systems to ensure their safety. LOPA (Layer of Protection Analysis) is one of the best ways to estimate the risk. It provides quantified risk results with less effort and time than other methods. LOPA...

  11. Triple loop heat exchanger for an absorption refrigeration system

    DOE Patents [OSTI]

    Reimann, Robert C. (Lafayette, NY)

    1984-01-01

    A triple loop heat exchanger for an absorption refrigeration system is disclosed. The triple loop heat exchanger comprises portions of a strong solution line for conducting relatively hot, strong solution from a generator to a solution heat exchanger of the absorption refrigeration system, conduit means for conducting relatively cool, weak solution from the solution heat exchanger to the generator, and a bypass system for conducting strong solution from the generator around the strong solution line and around the solution heat exchanger to an absorber of the refrigeration system when strong solution builds up in the generator to an undesirable level. The strong solution line and the conduit means are in heat exchange relationship with each other in the triple loop heat exchanger so that, during normal operation of the refrigeration system, heat is exchanged between the relatively hot, strong solution flowing through the strong solution line and the relatively cool, weak solution flowing through the conduit means. Also, the strong solution line and the bypass system are in heat exchange relationship in the triple loop heat exchanger so that if the normal flow path of relatively hot, strong solution flowing from the generator to an absorber is blocked, then this relatively, hot strong solution which will then be flowing through the bypass system in the triple loop heat exchanger, is brought into heat exchange relationship with any strong solution which may have solidified in the strong solution line in the triple loop heat exchanger to thereby aid in desolidifying any such solidified strong solution.

  12. Effects of Refrigeration and Freezing on the Electromechanical and

    E-Print Network [OSTI]

    Buschmann, Michael

    Effects of Refrigeration and Freezing on the Electromechanical and Biomechanical Properties.buschmann@polymtl.ca In vitro electromechanical and biomechanical testing of articular cartilage provide critical information,6 . Biomechanical and electromechanical tests are used to assess cartilage functional properties and reflect its

  13. Embedded Smart Controller for an Industrial Reefer Refrigeration1

    E-Print Network [OSTI]

    Reznik, Leon

    Embedded Smart Controller for an Industrial Reefer Refrigeration1 Leon Reznik and Shane Spiteri School of Communications and Informatics Victoria University PO Box 14428, Melbourne City MC VIC 8001 2-5, 2001 Abstract. The paper describes the development of a smart embedded fuzzy system for reefer

  14. Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Scroll compressor modelling for heat pumps using hydrocarbons as refrigerants Paul BYRNE and to install heat pumps in unoccupied spaces. Nevertheless manufacturers keep working on components for hydrocarbons. In the frame of a research project on heat pumps for simultaneous heating and cooling, an R407C

  15. 16 Heat Transfer and Air Flow in a Domestic Refrigerator

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    445 16 Heat Transfer and Air Flow in a Domestic Refrigerator Onrawee Laguerre UMR Génie Industriel........................................................................447 16.2.2 Heat Transfer and Airflow Near a Vertical Plate..................................................448 16.2.3 Heat Transfer and Airflow in Empty Closed Cavity

  16. Demand Response Opportunities in Industrial Refrigerated Warehouses in

    E-Print Network [OSTI]

    LBNL-4837E Demand Response Opportunities in Industrial Refrigerated Warehouses in California Sasank thereof or The Regents of the University of California. #12;Demand Response Opportunities in Industrial centralized control systems can be excellent candidates for Automated Demand Response (Auto- DR) due

  17. Improving the Efficiency of Your Process Cooling System 

    E-Print Network [OSTI]

    Baker, R.

    2005-01-01

    Many industries require process cooling to achieve desired outcomes of specific processes. This cooling may come from cooling towers, once-through water, mechanical refrigeration, or cryogenic sources such as liquid nitrogen or dry ice. This paper...

  18. Floating Refrigerant Loop Based on R-134a Refrigerant Cooling of High-Heat Flux Electronics

    SciTech Connect (OSTI)

    Lowe, K.T.

    2005-10-07

    The Oak Ridge National Laboratory (ORNL) Power Electronics and Electric Machinery Research Center (PEEMRC) have been developing technologies to address the thermal issues associated with hybrid vehicles. Removal of the heat generated from electrical losses in traction motors and their associated power electronics is essential for the reliable operation of motors and power electronics. As part of a larger thermal control project, which includes shrinking inverter size and direct cooling of electronics, ORNL has developed U.S. Patent No. 6,772,603 B2, ''Methods and Apparatus for Thermal Management of Vehicle Systems and Components'' [1], and patent pending, ''Floating Loop System for Cooling Integrated Motors and Inverters Using Hot Liquid Refrigerant'' [2]. The floating-loop system provides a large coefficient of performance (COP) for hybrid-drive component cooling. This loop (based on R-134a) is integrated with a vehicle's existing air-conditioning (AC) condenser, which dissipates waste heat to the ambient air. Because the temperature requirements for cooling of power electronics and electric machines are not as low as that required for passenger compartment air, this adjoining loop can operate on the high-pressure side of the existing AC system. This arrangement also allows the floating loop to run without the need for the compressor and only needs a small pump to move the liquid refrigerant. For the design to be viable, the loop must not adversely affect the existing system. The loop should also provide a high COP, a flat-temperature profile, and low-pressure drop. To date, the floating-loop test prototype has successfully removed 2 kW of heat load in a 9 kW automobile passenger AC system with and without the automotive AC system running. The COP for the tested floating-loop system ranges from 40-45, as compared to a typical AC system COP of about 2-4. The estimated required waste-heat load for future hybrid applications is 5.5 kW and the existing system could be easily scaleable for this larger load.

  19. Refrigerator Magnets It seems that, these days, the home refrigerator was invented primarily as a venue for displaying

    E-Print Network [OSTI]

    Lü, James Jian-Qiang

    of these magnets (I will call them type A), the magnetic force problem we need to solve involves only the magnet and the steel skin of the refrigerator door. The second kind of magnet (I will call it type B) has an additional includes all three components. For both types of configurations we will assume that the magnetization

  20. Electrochemical synthesis of multisegmented nanowires

    SciTech Connect (OSTI)

    Kok, Kuan-Ying; Ng, Inn-Khuan; Saidin, Nur Ubaidah

    2012-11-27

    Electrochemical deposition has emerged as a promising route for nanostructure fabrication in recent years due to the many inherent advantages it possesses. This study focuses on the synthesis of high-aspect-ratio multisegmented Au/Ni nanowires using template-directed sequential electrochemical deposition techniques. By selectively removing the Ni segments in the nanowires, high-yield of pure gold nanorods of predetermined lengths was obtained. Alternatively, the sacrificial Ni segments in the nanowires can be galvanically displaced with Bi and Te to form barbells structures with Bi{sub x}Te{sub y} nanotubes attached to neighbouring gold segments. Detailed studies on the nanostructures obtained were carried out using various microscopy, diffraction and probebased techniques for structural, morphological and chemical characterizations.

  1. Solid state electrochemical current source

    DOE Patents [OSTI]

    Potanin, Alexander Arkadyevich (Sarov, RU); Vedeneev, Nikolai Ivanovich (Sarov, RU)

    2002-04-30

    A cathode and a solid state electrochemical cell comprising said cathode, a solid anode and solid fluoride ion conducting electrolyte. The cathode comprises a metal oxide and a compound fluoride containing at least two metals with different valences. Representative compound fluorides include solid solutions of bismuth fluoride and potassium fluoride; and lead fluoride and potassium fluoride. Representative metal oxides include copper oxide, lead oxide, manganese oxide, vanadium oxide and silver oxide.

  2. Offshore refrigerated LPG loading/unloading terminal using a CALM buoy

    SciTech Connect (OSTI)

    Bonjour, E.L.; Simon, J.M.

    1985-03-01

    In existing Liquefied Petroleum Gases terminals, the transfer of liquefied gases to the tanker is performed via articulated loading arms or flexible hoses, working under quasistatic conditions. The tanker has to be firmly moored alongside a jetty or a process barge in a protected area (such as a harbour in most cases). This paper gives the main results of the development of an offshore refrigerated LPG (-48/sup 0/C) loading/unloading system, using a CALM buoy and LPG floating hoses working under dynamic conditions. The aim of this new concept is to replace the standard harbour structure for loading/unloading refrigerated LPG and to provide a considerable reduction in investments and a greater flexibility regarding the terminal location. The main components of that terminal have been designed so as to enable the loading of a 75 000 cubic meter LPG carrier in 15 hours. The results of static and dynamic low temperature tests on a LPG swivel joint for CALM buoy and LPG floating hoses show that such a SPM terminal is now a realistic solution.

  3. Development of an Electrochemical Separator and Compressor

    SciTech Connect (OSTI)

    Trent Molter

    2011-04-28

    Global conversion to sustainable energy is likely to result in a hydrogen-based economy that supports U.S. energy security objectives while simultaneously avoiding harmful carbon emissions. A key hurdle to successful implementation of a hydrogen economy is the low-cost generation, storage, and distribution of hydrogen. One of the most difficult requirements of this transformation is achieving economical, high density hydrogen storage in passenger vehicles. Transportation applications may require compression and storage of high purity hydrogen up to 12,000 psi. Hydrogen production choices range from centralized low-pressure generation of relatively impure gas in large quantities from steam-methane reformer plants to distributed generation of hydrogen under moderate pressure using water electrolysis. The Electrochemical Hydrogen Separator + Compressor (EHS+C) technology separates hydrogen from impurities and then compresses it to high pressure without any moving parts. The Phase I effort resulted in the construction and demonstration of a laboratory-scale hardware that can separate and compress hydrogen from reformate streams. The completion of Phase I has demonstrated at the laboratory scale the efficient separation and compression of hydrogen in a cost effective manner. This was achieved by optimizing the design of the Electrochemical Hydrogen Compression (EHC) cell hardware and verified by parametric testing in single cell hardware. A broad range of commercial applications exist for reclamation of hydrogen. One use this technology would be in combination with commercial fuel cells resulting in a source of clean power, heat, and compressed hydrogen. Other applications include the reclamation of hydrogen from power plants and other industrial equipment where it is used for cooling, recovery of process hydrogen from heat treating processes, and semiconductor fabrication lines. Hydrogen can also be recovered from reformate streams and cryogenic boil-offs using this technology.

  4. Compacted carbon for electrochemical cells

    DOE Patents [OSTI]

    Greinke, R.A.; Lewis, I.C.

    1997-10-14

    This invention provides compacted carbon that is useful in the electrode of an alkali metal/carbon electrochemical cell of improved capacity selected from the group consisting of: (a) coke having the following properties: (1) an x-ray density of at least 2.00 grams per cubic centimeters, (2) a closed porosity of no greater than 5%, and (3) an open porosity of no greater than 47%; and (b) graphite having the following properties: (1) an x-ray density of at least 2.20 grams per cubic centimeters, (2) a closed porosity of no greater than 5%, and (3) an open porosity of no greater than 25%. This invention also relates to an electrode for an alkali metal/carbon electrochemical cell comprising compacted carbon as described above and a binder. This invention further provides an alkali metal/carbon electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrolytically conductive salt and an alkali metal, and (c) a counter electrode. 10 figs.

  5. Energy Saving with Absorption Refrigeration Technologies 

    E-Print Network [OSTI]

    Davis, R. C.

    1984-01-01

    generally been overlooked by the process industry. This paper will address the application of the lithium bromide-water cycle in various energy saving modes. A waste heat powered absorption chiller producing chilled water can reduce energy consumption in a...

  6. Shock-activated electrochemical power supplies

    DOE Patents [OSTI]

    Benedick, W.B.; Graham, R.A.; Morosin, B.

    1987-04-20

    A shock-activated electrochemical power supply is provided which is initiated extremely rapidly and which has a long shelf life. Electrochemical power supplies of this invention are initiated much faster than conventional thermal batteries. Power supplies of this invention comprise an inactive electrolyte and means for generating a high-pressure shock wave such that the shock wave is propagated through the electrolyte rendering the electrolyte electrochemically active. 2 figs.

  7. Shock-activated electrochemical power supplies

    DOE Patents [OSTI]

    Benedick, W.B.; Graham, R.A.; Morosin, B.

    1988-11-08

    A shock-activated electrochemical power supply is provided which is initiated extremely rapidly and which has a long shelf life. Electrochemical power supplies of this invention are initiated much faster than conventional thermal batteries. Power supplies of this invention comprise an inactive electrolyte and means for generating a high-pressure shock wave such that the shock wave is propagated through the electrolytes rendering the electrolyte electrochemically active. 2 figs.

  8. Shock-activated electrochemical power supplies

    DOE Patents [OSTI]

    Benedick, William B. (Albuquerque, NM); Graham, Robert A. (Los Lunas, NM); Morosin, Bruno (Albuquerque, NM)

    1988-01-01

    A shock-activated electrochemical power supply is provided which is initiated extremely rapidly and which has a long shelf life. Electrochemical power supplies of this invention are initiated much faster than conventional thermal batteries. Power supplies of this invention comprise an inactive electrolyte and means for generating a high-pressure shock wave such that the shock wave is propagated through the electrolytes rendering the electrolyte electrochemically active.

  9. In situ soft X-ray absorption spectroscopy investigation of electrochemical corrosion of copper in aqueous NaHCO3 solution

    SciTech Connect (OSTI)

    Jiang, Peng; Chen, Jeng-Lung; Borondics, Ferenc; Glans, Per-Anders; West, Mark W.; Chang, Ching-Lin; Salmeron, Miquel; Guo, Jinghua

    2010-03-31

    A novel electrochemical setup has been developed for soft x-ray absorption studies of the electronic structure of electrode materials during electrochemical cycling. In this communication we illustrate the operation of the cell with a study of the corrosion behavior of copper in aqueous NaHCO3 solution via the electrochemically induced changes of its electronic structure. This development opens the way for in situ investigations of electrochemical processes, photovoltaics, batteries, fuel cells, water splitting, corrosion, electrodeposition, and a variety of important biological processes.

  10. Compatibility of refrigerants and lubricants with motor materials under retrofit conditions

    SciTech Connect (OSTI)

    Doerr, R.; Waite, T.

    1995-01-12

    Motor materials were exposed to original refrigerants R-11, R-12, R-22 and R-502 in the presence of mineral oil for 500 hours. These same materials were then exposed to alternative refrigerants R-123, R-134a, R-407C (R-32/R-125/R-134a) and R-404A (R-125/R-143a/R-134a), respectively, in the presence of the appropriate lubricant for 500 hours. As a control, some samples were exposed to the original refrigerant/mineral oil for a total of 1,000 hours. These tests were conducted to determine whether exposure to the original refrigerant/mineral oil would affect compatibility of the motor materials with the alternative refrigerant/lubricant after retrofit. Motor materials exposed to the alternative refrigerant and lubricant (after an initial exposure to the original refrigerant and mineral oil) appeared to be compatible with the alternative refrigerant and lubricant. The only concerns were embrittlement of the polyethylene terephthalate (PET) sheet and sleeving insulations, and delamination and blistering of the Nomex sheet insulation in the R-22, R-502, and R-12. Embrittlement of the PET materials was attributed to moisture present during the exposure. Separation of the 475 varnish from metal surfaces in the R-123 was also a concern. The sheet and sleeving insulations were affected by the original refrigerant/mineral oil to a greater extent than by the alternative refrigerant and lubricant.

  11. Structures and fabrication techniques for solid state electrochemical devices

    DOE Patents [OSTI]

    Visco, Steven J.; Jacobson, Craig P.; DeJonghe, Lutgard C.

    2012-10-09

    Porous substrates and associated structures for solid-state electrochemical devices, such as solid-oxide fuel cells (SOFCs), are low-cost, mechanically strong and highly electronically conductive. Some preferred structures have a thin layer of an electrocatalytically active material (e.g., Ni--YSZ) coating a porous high-strength alloy support (e.g., SS-430) to form a porous SOFC fuel electrode. Electrode/electrolyte structures can be formed by co-firing or constrained sintering processes.

  12. Structures and fabrication techniques for solid state electrochemical devices

    DOE Patents [OSTI]

    Visco, Steven J. (Berkeley, CA); Jacobson, Craig P. (El Cerrito, CA); DeJonghe, Lutgard C. (Lafayette, CA)

    2008-04-01

    Porous substrates and associated structures for solid-state electrochemical devices, such as solid-oxide fuel cells (SOFCs), are low-cost, mechanically strong and highly electronically conductive. Some preferred structures have a thin layer of an electrocatalytically active material (e.g., Ni--YSZ) coating a porous high-strength alloy support (e.g., SS-430) to form a porous SOFC fuel electrode. Electrode/electrolyte structures can be formed by co-firing or constrained sintering processes.

  13. Microfluidic devices with thick-film electrochemical detection

    DOE Patents [OSTI]

    Wang, Joseph; Tian, Baomin; Sahlin, Eskil

    2005-04-12

    An apparatus for conducting a microfluidic process and analysis, including at least one elongated microfluidic channel, fluidic transport means for transport of fluids through the microfluidic channel, and at least one thick-film electrode in fluidic connection with the outlet end of the microfluidic channel. The present invention includes an integrated on-chip combination reaction, separation and thick-film electrochemical detection microsystem, for use in detection of a wide range of analytes, and methods for the use thereof.

  14. Solid flexible electrochemical supercapacitor using Tobacco mosaic...

    Office of Scientific and Technical Information (OSTI)

    Solid flexible electrochemical supercapacitor using Tobacco mosaic virus nanostructures and ALD ruthenium oxide Citation Details In-Document Search Title: Solid flexible...

  15. Electrochemical NOx Sensor for Monitoring Diesel Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of oxide electrodes * Decision point: Down select to metal or electronically- conducting oxide electrodes Electrochemical NO x Sensor for Monitoring Diesel Emissions 17 Plans for...

  16. Electrochemical Energy Storage | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrochemical Energy Storage Apr 16 2014 08:00 AM - 05:00 PM Multiple Speakers, in multiple disciplines, from multiple institutions ASM International, Oak Ridge Chapter,...

  17. Apparatus for combinatorial screening of electrochemical materials

    DOE Patents [OSTI]

    A high throughput combinatorial screening method and apparatus for the evaluation of electrochemical materials using a single voltage source (2) is disclosed wherein temperature changes arising from the application of an electrical load to a cell array (1) are used to evaluate the relative electrochemical efficiency of the materials comprising the array. The apparatus may include an array of electrochemical cells (1) that are connected to each other in parallel or in series, an electronic load (2) for applying a voltage or current to the electrochemical cells (1), and a device (3), external to the cells, for monitoring the relative temperature of each cell when the load is applied.

    2009-12-15

    A high throughput combinatorial screening method and apparatus for the evaluation of electrochemical materials using a single voltage source (2) is disclosed wherein temperature changes arising from the application of an electrical load to a cell array (1) are used to evaluate the relative electrochemical efficiency of the materials comprising the array. The apparatus may include an array of electrochemical cells (1) that are connected to each other in parallel or in series, an electronic load (2) for applying a voltage or current to the electrochemical cells (1), and a device (3), external to the cells, for monitoring the relative temperature of each cell when the load is applied.

  18. Nanomaterial-Based Electrochemical Biosensors and Bioassays

    SciTech Connect (OSTI)

    Liu, Guodong; Mao, Xun; Gurung, Anant; Baloda, Meenu; Lin, Yuehe; He, Yuqing

    2010-08-31

    This book chapter summarizes the recent advance in nanomaterials for electrochemical biosensors and bioassays. Biofunctionalization of nanomaterials for biosensors fabrication and their biomedical applications are discussed.

  19. Electronic structural and electrochemical properties of lithium...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Electronic structural and electrochemical properties of lithium zirconates and their capabilities of CO2 capture: A first-principles density-functional theory and...

  20. Electrochemical NOx Sensor for Monitoring Diesel Emissions |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sensor for Monitoring Diesel Emissions Electrochemical NOx Sensor for Monitoring Diesel Emissions Presentation from the U.S. DOE Office of Vehicle Technologies "Mega" Merit Review...

  1. Pilot Testing of Commercial Refrigeration-Based Demand Response

    SciTech Connect (OSTI)

    Hirsch, Adam; Clark, Jordan; Deru, Michael; Trenbath, Kim; Doebber, Ian; Studer, Daniel

    2015-10-08

    Supermarkets potentially offer a substantial demand response (DR) resource because of their high energy intensity and use patterns. This report describes a pilot project conducted to better estimate supermarket DR potential. Previous work has analyzed supermarket DR using heating, ventilating, and air conditioning (HVAC), lighting, and anti-condensate heaters. This project was concerned with evaluating DR using the refrigeration system and quantifying the DR potential inherent in supermarket refrigeration systems. Ancillary aims of the project were to identify practical barriers to the implementation of DR programs in supermarkets and to determine which high-level control strategies were most appropriate for achieving certain DR objectives. The scope of this project does not include detailed control strategy development for DR or development of a strategy for regional implementation of DR in supermarkets.

  2. Free displacer and Ringbom displacer for a Malone refrigerator

    SciTech Connect (OSTI)

    Swift, G.W.; Brown, A.O.

    1994-05-01

    Malone refrigeration uses a liquid near its critical point (instead of the customary gas) as the working fluid in a Stirling, Brayton, or similar regenerative or recuperative cycle. Thus far, we have focused on the Stirling cycle, to avoid the difficult construction of the high-pressure-difference counterflow recuperator required for a Brayton machine. Our first Malone refrigerator used liquid propylene (C{sub 3}H{sub 6}) in a double-acting 4-cylinder Stirling configuration. First measurements with a free displacer used in a liquid working fluid are presented. The displacer was operated both in harmonic mode and in Ringbom mode, in liquid carbon dioxide. The results are in reasonable agreement with expectations.

  3. Heat powered refrigeration compressor. Semi-annual technical report

    SciTech Connect (OSTI)

    Goad, R.R.

    1981-01-01

    The objective of this program is to develop and improve the design of previously started prototypes of the Heat Powered Refrigeration Compressor. To build this prototype and ready it for testing by the University of Evansville is another goal. This prototype will be of similar capacity as the compressor that will eventually be commercially produced. This unit can operate on almost any moderate temperature water heat source. This heat source could include such applications as industrial waste heat, solar, wood burning stove, resistance electrical heat produced by a windmill, or even perhaps heat put out by the condenser of another refrigeration system. Work performed in the past four months has consisted of: engineering of HX-1; comparisons of specifications from different companies to ensure state of the art applications of parts for project; coordinating project requirements with machine shop; designing condenser; and partial assembly of HX-1.

  4. Solar heat pump systems with refrigerant-filled collectors

    SciTech Connect (OSTI)

    O'Dell, M.P.; Beckman, W.A.; Mitchell, J.W.

    1983-01-01

    The heat pump system with a refrigerant-filled evaporator consists of a standard air-to-air or air-to-liquid heat pump that utilizes a solar panel as the evaporator. A combination of solar energy and convection heat transfer acts as the ''free'' energy absorbed by the collector/evaporator. In this paper, the seasonal performance of such systems for industrial applications will be presented. Performance of collector/evaporator heat pumps will be compared with alternative heat pump and solar systems. The benefits of covered and coverless collector/evaporators will be discussed. Results to date have shown that refrigerant-filled collector heat pumps do not perform as well as conventional heat pumps at small collector areas but have as much as 15% performance improvement over conventional heat pumps at an appropriate collector area.

  5. Cryogenics for superconductors: Refrigeration, delivery, and preservation of the cold

    SciTech Connect (OSTI)

    Venkatarao Ganni, James Fesmire

    2012-06-01

    Applications in superconductivity have become widespread, enabled by advancements in cryogenic engineering. In this paper, the history of cryogenic refrigeration, its delivery, its preservation and the important scientific and engineering advancements in these areas in the last 100 years will be reviewed, beginning with small laboratory dewars to very large scale systems. The key technological advancements in these areas that enabled the development of superconducting applications at temperatures from 4 to 77 K are identified. Included are advancements in the components used up to the present state-of-the-art in refrigeration systems design. Viewpoints as both an equipment supplier and the end-user with regard to the equipment design and operations will be presented. Some of the present and future challenges in these areas will be outlined. Most of the materials in this paper are a collection of the historical materials applicable to these areas of interest.

  6. A dilution refrigerator insert for standard ILL cryostats K. Neumaier

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    and liquified by the cold low pressure He3 gas in a counterflow heat exchanger. That allows to operate refrigerator. The tubular heat exchanger is constructed as follows. A Cu-Ni tube 0.6/0.4 mm (o.d., i.d.), 1.5 m into a coil of about 32 mm in diameter. The mixing chamber has a sintered copper heat exchanger with a surface

  7. Speed Control in Industrial Refrigeration: Theory, Application & Case Studies 

    E-Print Network [OSTI]

    Wilcox, M. H.

    1995-01-01

    -pressure regulators (BPRs) or liquid solenoids, and condensers cycle fans. Unfortunately, these control methods do not provide the maximum attainable reduction in brake horsepower (BHP) as refrigeration capacity is reduced. This paper will discuss... theory and case study, speed control of these components provides maximum flexibility, control and energy efficiency. SPEED CONTROL BACKGROUND In standard system design, electric motors are intended to operate at a fixed speed. This speed...

  8. Applications Tests of Energy Efficient, Environmentally Friendly Refrigerants 

    E-Print Network [OSTI]

    Nimitz, J.; Glass, S.; McCullough, E.; Dhooge, P.

    1999-01-01

    the Twenty-first National Industrial Energy Technology Conference, Houston, TX, May 12-13, 1999 ~ ::l ;; il fitO(x) ~- f-T (; av~ 30 -----.------r---..,----r-----,-----r----,---r--i 30 E+++ 0 ~ ~ cr:" -10 -20 -20 L... ambient temperatures, and a moderately high global warming potential (GWP). 197 ESL-IE-99-05-29 Proceedings from the Twenty-first National Industrial Energy Technology Conference, Houston, TX, May 12-13, 1999 The Ikon? Refrigerants The original goal...

  9. page 1 of 5 TkF Vrmeteknik Refrigeration / Kylteknik

    E-Print Network [OSTI]

    Zevenhoven, Ron

    of the cycle (MPa). (1p.) b. Determine the mass flow rate of the working fluid (kg/s) and compressor power (kW) in kW. (2p.) Use tabelised data for R-134a, otherwise the log p, h diagram given below (next page). #12 within 1 hour, calculate the minimum cooling/freezing capacity of the refrigerator (W) and the time

  10. Fuel Cell Based Auxiliary Power Unit for Refrigerated Trucks

    SciTech Connect (OSTI)

    Brooks, Kriston P.

    2014-09-02

    This is the annual report for the Market Transformation project as required by DOE EERE's Fuel Cell Technologies Office. We have been provided with a specific format. It describes the work that was done in developing fuel-cell powered Transport Refrigeration Units for Reefer Trucks. It describes the progress that has been made by Nuvera and Plug Power as they develop and ultimately demonstrate this technology in real world application.

  11. Magnetic Refrigeration Technology for High Efficiency Air Conditioning

    SciTech Connect (OSTI)

    Boeder, A; Zimm, C

    2006-09-30

    Magnetic refrigeration was investigated as an efficient, environmentally friendly, flexible alternative to conventional residential vapor compression central air conditioning systems. Finite element analysis (FEA) models of advanced geometry active magnetic regenerator (AMR) beds were developed to minimize bed size and thus magnet mass by optimizing geometry for fluid flow and heat transfer and other losses. Conventional and magnetocaloric material (MCM) regenerator fabrication and assembly techniques were developed and advanced geometry passive regenerators were built and tested. A subscale engineering prototype (SEP) magnetic air conditioner was designed, constructed and tested. A model of the AMR cycle, combined with knowledge from passive regenerator experiments and FEA results, was used to design the regenerator beds. A 1.5 Tesla permanent magnet assembly was designed using FEA and the bed structure and plenum design was extensively optimized using FEA. The SEP is a flexible magnetic refrigeration platform, with individually instrumented beds and high flow rate and high frequency capability, although the current advanced regenerator geometry beds do not meet performance expectations, probably due to manufacturing and assembly tolerances. A model of the AMR cycle was used to optimize the design of a 3 ton capacity magnetic air conditioner, and the system design was iterated to minimize external parasitic losses such as heat exchanger pressure drop and fan power. The manufacturing cost for the entire air conditioning system was estimated, and while the estimated SEER efficiency is high, the magnetic air conditioning system is not cost competitive as currently configured. The 3 ton study results indicate that there are other applications where magnetic refrigeration is anticipated to have cost advantages over conventional systems, especially applications where magnetic refrigeration, through the use of its aqueous heat transfer fluid, could eliminate intermediate heat exchangers or oil distribution issues found in traditional vapor compression systems.

  12. DOE Opens Three Investigations into Alleged Refrigerator Efficiency

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department ofRefrigeratorsDepartment of Energy Investigation

  13. Refrigerator Standards Save Consumers $ Billions | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested PartiesBuildingBudgetFinancial Opportunities »Refrigerator Standards Save

  14. New waste-heat refrigeration unit cuts flaring, reduces pollution

    SciTech Connect (OSTI)

    Brant, B.; Brueske, S.; Erickson, D.; Papar, R.

    1998-05-18

    Planetec Utility Services Co. Inc. and Energy Concepts Co. (ECC), with the help of the US Department of Energy (DOE), developed and commissioned a unique waste-heat powered LPG recovery plant in August 1997 at the 30,000 b/d Denver refinery, operated by Ultramar Diamond Shamrock (UDS). This new environmentally friendly technology reduces flare emissions and the loss of salable liquid-petroleum products to the fuel-gas system. The waste heat ammonia absorption refrigeration plant (Whaarp) is the first technology of its kind to use low-temperature waste heat (295 F) to achieve sub-zero refrigeration temperatures ({minus}40 F) with the capability of dual temperature loads in a refinery setting. The ammonia absorption refrigeration is applied to the refinery`s fuel-gas makeup streams to condense over 180 b/d of salable liquid hydrocarbon products. The recovered liquid, about 64,000 bbl/year of LPG and gasoline, increases annual refinery profits by nearly $1 million, while substantially reducing air pollution emissions from the refinery`s flare.

  15. Electrochemical preparation of poly(methylene blue)/graphene nanocomposite thin films

    SciTech Connect (OSTI)

    Erçar?kc?, Elif; Da?c?, Kader; Topçu, Ezgi; Alanyal?o?lu, Murat

    2014-07-01

    Highlights: • Poly(MB)/graphene thin films are prepared by a simple electrochemical approach. • Graphene layers in the film show a broad band in visible region of absorbance spectra. • Morphology of composite films indicates both disordered and ordered regions. • XRD reveals that nanocomposite films include rGO layers after electropolymerization process. • Chemically prepared graphene is better than electrochemically prepared graphene for electrooxidation of nitrite. - Abstract: Poly(methylene blue)/graphene nanocomposite thin films were prepared by electropolymerization of methylene blue in the presence of graphene which have been synthesized by two different methods of a chemical oxidation process and an electrochemical approach. Synthesized nanocomposite thin films were characterized by using cyclic voltammetry, UV–vis. absorption spectroscopy, powder X-ray diffraction, and scanning tunneling microscopy techniques. Electrocatalytical properties of prepared poly(methylene blue)/graphene nanocomposite films were compared toward electrochemical oxidation of nitrite. Under optimized conditions, electrocatalytical effect of nanocomposite films of chemically prepared graphene through electrochemical oxidation of nitrite was better than that of electrochemically prepared graphene.

  16. Graphene-Au Nanoparticles Composite-Based Electrochemical Aptamer...

    Office of Scientific and Technical Information (OSTI)

    Graphene-Au Nanoparticles Composite-Based Electrochemical Aptamer Biosensors Citation Details In-Document Search Title: Graphene-Au Nanoparticles Composite-Based Electrochemical...

  17. Method of removing an immiscible lubricant from a refrigeration system and apparatus for same

    DOE Patents [OSTI]

    Spauschus, H.O.; Starr, T.L.

    1999-03-30

    A method is described for separating an immiscible lubricant from a liquid refrigerant in a refrigerating system including a compressor, a condenser, an expansion device and an evaporator, wherein the expansion device is connected to the condenser by a liquid refrigerant flow line for liquid refrigerant and immiscible lubricant. The method comprising slowing the rate of flow of the liquid refrigerant and immiscible lubricant between the condenser and the expansion device such that the liquid refrigerant and the immiscible lubricant separate based upon differences in density. The method also comprises collecting the separated immiscible lubricant in a collection chamber in fluid communication with the separated immiscible lubricant. Apparatus for performing the method is also disclosed. 3 figs.

  18. The LSST Camera 500 watt -130 degC Mixed Refrigerant Cooling System

    SciTech Connect (OSTI)

    Bowden, Gordon B.; Langton, Brian J.; Little, William A.; Powers, Jacob R; Schindler, Rafe H.; Spektor, Sam; /MMR-Technologies, Mountain View, CA

    2014-05-28

    The LSST Camera has a higher cryogenic heat load than previous CCD telescope cameras due to its large size (634 mm diameter focal plane, 3.2 Giga pixels) and its close coupled front-end electronics operating at low temperature inside the cryostat. Various refrigeration technologies are considered for this telescope/camera environment. MMR-Technology’s Mixed Refrigerant technology was chosen. A collaboration with that company was started in 2009. The system, based on a cluster of Joule-Thomson refrigerators running a special blend of mixed refrigerants is described. Both the advantages and problems of applying this technology to telescope camera refrigeration are discussed. Test results from a prototype refrigerator running in a realistic telescope configuration are reported. Current and future stages of the development program are described. (auth)

  19. Liquid over-feeding refrigeration system and method with integrated accumulator-expander-heat exchanger

    DOE Patents [OSTI]

    Mei, Viung C. (Oak Ridge, TN); Chen, Fang C. (Knoxville, TN)

    1997-01-01

    A refrigeration system having a vapor compression cycle utilizing a liquid over-feeding operation with an integrated accumulator-expander-heat exchanger. Hot, high-pressure liquid refrigerant from the condenser passes through one or more lengths of capillary tubing substantially immersed in a pool liquid refrigerant in the accumulator-expander-heat exchanger for simultaneously sub-cooling and expanding the liquid refrigerant while vaporizing liquid refrigerant from the pool for the return thereof to the compressor as saturated vapor. The sub-cooling of the expanded liquid provides for the flow of liquid refrigerant into the evaporator for liquid over-feeding the evaporator and thereby increasing the efficiency of the evaporation cycle.

  20. Liquid over-feeding refrigeration system and method with integrated accumulator-expander-heat exchanger

    DOE Patents [OSTI]

    Mei, V.C.; Chen, F.C.

    1997-04-22

    A refrigeration system is described having a vapor compression cycle utilizing a liquid over-feeding operation with an integrated accumulator-expander-heat exchanger. Hot, high-pressure liquid refrigerant from the condenser passes through one or more lengths of capillary tubing substantially immersed in a pool liquid refrigerant in the accumulator-expander-heat exchanger for simultaneously sub-cooling and expanding the liquid refrigerant while vaporizing liquid refrigerant from the pool for the return thereof to the compressor as saturated vapor. The sub-cooling of the expanded liquid provides for the flow of liquid refrigerant into the evaporator for liquid over-feeding the evaporator and thereby increasing the efficiency of the evaporation cycle. 4 figs.

  1. The superfluid Stirling refrigerator, a new method for cooling below 0.5 K

    SciTech Connect (OSTI)

    Brisson, J.G.; Kotsubo, V.; Swift, G.W.

    1993-04-09

    A new subkelvin refrigerator, the superfluid Stirling cycle refrigerator, uses a working fluid of {sup 3}He-{sup 4}He mixture in a Stirling cycle. The thermodynamically active components of the mixture are the {sup 3}He, which behaves like a Boltzman gas, and the phonon-roton gas in the {sup 4}He. The superfluid component of the liquid is inert. Two refrigerators have been built and temperatures of 340 mK have been achieved.

  2. The superfluid Stirling refrigerator, a new method for cooling below 0. 5 K

    SciTech Connect (OSTI)

    Brisson, J.G.; Kotsubo, V.; Swift, G.W.

    1993-04-09

    A new subkelvin refrigerator, the superfluid Stirling cycle refrigerator, uses a working fluid of [sup 3]He-[sup 4]He mixture in a Stirling cycle. The thermodynamically active components of the mixture are the [sup 3]He, which behaves like a Boltzman gas, and the phonon-roton gas in the [sup 4]He. The superfluid component of the liquid is inert. Two refrigerators have been built and temperatures of 340 mK have been achieved.

  3. Elastohydrodynamic Lubrication with Polyolester Lubricants and HFC Refrigerants, Final Report, Volume 2

    SciTech Connect (OSTI)

    Gunsel, Selda; Pozebanchuk, Michael

    1999-04-01

    Lubrication properties of refrigeration lubricants were investigated in high pressure nonconforming contacts under different conditions of temperature, rolling speed, and refrigerant concentration. The program was based upon the recognition that the lubrication regime in refrigeration compressors is generally elastohydrodynamic or hydrodynamic, as determined by the operating conditions of the compressor and the properties of the lubricant. Depending on the compressor design, elastohydrodynamic lubrication conditions exist in many rolling and sliding elements of refrigeration compressors such as roller element bearings, gears, and rotors. The formation of an elastohydrodynamic film separating rubbing surfaces is important in preventing the wear and failure of compressor elements. It is, therefore, important to predict the elastohydrodynamic (EHD) performance of lubricants under realistic tribocontact renditions. This is, however, difficult as the lubricant properties that control film formation are critically dependent upon pressure and shear, and cannot be evaluated using conventional laboratory instruments. In this study, the elastohydrodynamic behavior of refrigeration lubricants with and without the presence of refrigerants was investigated using the ultrathin film EHD interferometry technique. This technique enables very thin films, down to less than 5 nm, to be measured accurately within an EHD contact under realistic conditions of temperature, shear, and pressure. The technique was adapted to the study of lubricant refrigerant mixtures. Film thickness measurements were obtained on refrigeration lubricants as a function of speed, temperature, and refrigerant concentration. The effects of lubricant viscosity, temperature, rolling speed, and refrigerant concentration on EHD film formation were investigated. From the film thickness measurements, effective pressure-viscosity coefficients were calculated. The lubricants studied in this project included two naphthenic mineral oils (NMO), four polyolesters (POE), and two polyvinyl ether (PVE) fluids. These fluids represented viscosity grades of ISO 32 and ISO 68 and are shown in a table. Refrigerants studied included R-22, R-134a, and R-410A. Film thickness measurements were conducted at 23 C, 45 C, and 65 C with refrigerant concentrations ranging from zero to 60% by weight.

  4. A Variable Refrigerant Flow Heat Pump Computer Model in EnergyPlus

    SciTech Connect (OSTI)

    Raustad, Richard A. [Florida Solar Energy Center

    2013-01-01

    This paper provides an overview of the variable refrigerant flow heat pump computer model included with the Department of Energy's EnergyPlusTM whole-building energy simulation software. The mathematical model for a variable refrigerant flow heat pump operating in cooling or heating mode, and a detailed model for the variable refrigerant flow direct-expansion (DX) cooling coil are described in detail.

  5. Nanoelectrode array for electrochemical analysis

    DOE Patents [OSTI]

    Yelton, William G. (Sandia Park, NM); Siegal, Michael P. (Albuquerque, NM)

    2009-12-01

    A nanoelectrode array comprises a plurality of nanoelectrodes wherein the geometric dimensions of the electrode controls the electrochemical response, and the current density is independent of time. By combining a massive array of nanoelectrodes in parallel, the current signal can be amplified while still retaining the beneficial geometric advantages of nanoelectrodes. Such nanoelectrode arrays can be used in a sensor system for rapid, non-contaminating field analysis. For example, an array of suitably functionalized nanoelectrodes can be incorporated into a small, integrated sensor system that can identify many species rapidly and simultaneously under field conditions in high-resistivity water, without the need for chemical addition to increase conductivity.

  6. Zelenay named Electrochemical Society Fellow

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLos Alamos verifies largestnamed Electrochemical Society Fellow June

  7. Method for making an electrochemical cell

    DOE Patents [OSTI]

    Tuller, Harry L. (Wellesley, MA); Kramer, Steve A. (Somerville, MA); Spears, Marlene A. (Woburn, MA); Pal, Uday B. (Needham, MA)

    1996-01-01

    An electrochemical device including a solid electrolyte and solid electrode composed of materials having different chemical compositions and characterized by different electrical properties but having the same crystalline phase is provided. A method for fabricating an electrochemical device having a solid electrode and solid electrolyte characterized by the same crystalline phase is provided.

  8. Next Generation Low-Global Warming Potential Refrigerants R&D...

    Broader source: Energy.gov (indexed) [DOE]

    of low-global warming potential (GWP) refrigerants. DOE commissioned this roadmap to establish a set of high-priority research and development (R&D) activities that...

  9. Research and Development Roadmap For Next-Generation Low-Global Warming Potential Refrigerants

    SciTech Connect (OSTI)

    none,

    2011-07-01

    The Department of Energy commissioned this roadmap to establish a set of high-priority research and development (R&D) activities that will accelerate the transition to low-GWP refrigerants across the entire heating, ventilation, air-conditioning and refrigeration (HVAC&R) industry. The schedule of R&D activities occurs within an accelerated five-year timeframe, and covers several prominent equipment types. The roadmap is organized around four primary objectives to: assess and mitigate safety risks, characterize refrigerant properties, understand efficiency and environmental tradeoffs, and support new refrigerant and equipment development.

  10. A Cooperative Demand Response Scheme Using Punishment Mechanism and Application to Industrial Refrigerated Warehouses

    E-Print Network [OSTI]

    Ma, Kai; Hu, Guoqiang; Spanos, Costas J

    2014-01-01

    Z. Yang, and Y. Zhang, “Demand response man- agement withwith application to demand response,” IEEE Transactions onand automated demand response in industrial refrigerated

  11. Electrochemical behavior of carbon aerogels derived from different precursors

    SciTech Connect (OSTI)

    Pekala, R.W.; Alviso, C.T.; Nielson, J.K.; Tran, T.D. [Lawrence Livermore National Lab., CA (United States); Reynolds, G.M.; Dresshaus, M.S. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Physics

    1995-04-01

    The ability to tailor the structure and properties of porous carbons has led to their increased use as electrodes in energy storage devices. Our research focuses on the synthesis and characterization of carbon aerogels for use in electrochemical double layer capacitors. Carbon aerogels are formed from the sol-gel polymerization of (1) resorcinol-formaldehyde or (2) phenolic-furfural, followed by supercritical drying from carbon dioxide, and subsequent pyrolysis in an inert atmosphere. These materials can be produced as monoliths, composites, thin films, powders, or microspheres. In all cases, the areogels have an open-cell structure with an ultrafine pore size (<100 nm), high surface area (400-1 100 m{sup 2}/g), and a solid matrix composed of interconnected particles, fibers, or platelets with characteristic dimensions of 10 nm. This paper examines the effects of the carbon precursor and processing conditions on electrochemical performance in aqueous and organic electrolytes.

  12. Structures and fabrication techniques for solid state electrochemical devices

    DOE Patents [OSTI]

    Visco, Steven J.; Jacobson, Craig P.; DeJonghe, Lutgard C.

    2006-10-10

    Low-cost, mechanically strong, highly electronically conductive porous substrates and associated structures for solid-state electrochemical devices, techniques for forming these structures, and devices incorporating the structures provide solid state electrochemical device substrates of novel composition and techniques for forming thin electrode/membrane/electrolyte coatings on the novel or more conventional substrates. In particular, in one aspect the invention provides techniques for co-firing of device substrate (often an electrode) with an electrolyte or membrane layer to form densified electrolyte/membrane films 5 to 20 microns thick. In another aspect, densified electrolyte/membrane films 5 to 20 microns thick may be formed on a pre-sintered substrate by a constrained sintering process. In some cases, the substrate may be a porous metal, alloy, or non-nickel cermet incorporating one or more of the transition metals Cr, Fe and Cu, or alloys thereof.

  13. Structures And Fabrication Techniques For Solid State Electrochemical Devices

    DOE Patents [OSTI]

    Visco, Steven J. (Berkeley, CA); Jacobson, Craig P. (El Cerrito, CA); DeJonghe, Lutgard C. (Lafayette, CA)

    2005-12-27

    Provided are low-cost, mechanically strong, highly electronically conductive porous substrates and associated structures for solid-state electrochemical devices, techniques for forming these structures, and devices incorporating the structures. The invention provides solid state electrochemical device substrates of novel composition and techniques for forming thin electrode/membrane/electrolyte coatings on the novel or more conventional substrates. In particular, in one embodiment the invention provides techniques for co-firing of device substrate (often an electrode) with an electrolyte or membrane layer to form densified electrolyte/membrane films 5 to 20 microns thick. In another embodiment, densified electrolyte/membrane films 5 to 20 microns thick may be formed on a pre-sintered substrate by a constrained sintering process. In some cases, the substrate may be a porous metal, alloy, or non-nickel cermet incorporating one or more of the transition metals Cr, Fe, Cu and Ag, or alloys thereof.

  14. Structures and fabrication techniques for solid state electrochemical devices

    DOE Patents [OSTI]

    Visco, Steven J. (Berkeley, CA); Jacobson, Craig P. (El Cerrito, CA); DeJonghe, Lutgard C. (Lafayette, CA)

    2003-08-12

    Provided are low-cost, mechanically strong, highly electronically conductive porous substrates and associated structures for solid-state electrochemical devices, techniques for forming these structures, and devices incorporating the structures. The invention provides solid state electrochemical device substrates of novel composition and techniques for forming thin electrode/membrane/electrolyte coatings on the novel or more conventional substrates. In particular, in one embodiment the invention provides techniques for co-firing of device substrate (often an electrode) with an electrolyte or membrane layer to form densified electrolyte/membrane films 5 to 20 microns thick. In another embodiment, densified electrolyte/membrane films 5 to 20 microns thick may be formed on a pre-sintered substrate by a constrained sintering process. In some cases, the substrate may be a porous metal, alloy, or non-nickel cermet incorporating one or more of the transition metals Cr, Fe, Cu and Ag, or alloys thereof.

  15. New Regenerative Cycle for Vapor Compression Refrigeration

    SciTech Connect (OSTI)

    Bergander, Mark J [Magnetic Development, Inc.; Butrymowicz, Dariusz [Polish Academy of Scinces

    2010-01-26

    This project was a continuation of Category 1 project, completed in August 2005. Following the successful bench model demonstration of the technical feasibility and economic viability, the main objective in this stage was to fabricate the prototype of the heat pump, working on the new thermodynamic cycle. This required further research to increase the system efficiency to the level consistent with theoretical analysis of the cycle. Another group of objectives was to provide the foundation for commercialization and included documentation of the manufacturing process, preparing the business plan, organizing sales network and raising the private capital necessary to acquire production facilities.

  16. Bussing Structure In An Electrochemical Cell

    DOE Patents [OSTI]

    Romero, Antonio L. (Parkton, MD)

    2001-06-12

    A bussing structure for bussing current within an electrochemical cell. The bussing structure includes a first plate and a second plate, each having a central aperture therein. Current collection tabs, extending from an electrode stack in the electrochemical cell, extend through the central aperture in the first plate, and are then sandwiched between the first plate and second plate. The second plate is then connected to a terminal on the outside of the case of the electrochemical cell. Each of the first and second plates includes a second aperture which is positioned beneath a safety vent in the case of the electrochemical cell to promote turbulent flow of gasses through the vent upon its opening. The second plate also includes protrusions for spacing the bussing structure from the case, as well as plateaus for connecting the bussing structure to the terminal on the case of the electrochemical cell.

  17. Coherence-assisted single-shot cooling by quantum absorption refrigerators

    E-Print Network [OSTI]

    Mark T. Mitchison; Mischa P. Woods; Javier Prior; Marcus Huber

    2015-08-06

    The extension of thermodynamics into the quantum regime has received much attention in recent years. A primary objective of current research is to find thermodynamic tasks which can be enhanced by quantum mechanical effects. With this goal in mind, we explore the finite-time dynamics of absorption refrigerators composed of three qubits. The aim of this finite-time cooling is to reach low temperatures as fast as possible and subsequently extract the cold particle to exploit it for information processing purposes. We show that the coherent oscillations inherent to quantum dynamics can be harnessed to reach temperatures that are colder than the steady state in orders of magnitude less time, thereby providing a fast source of low-entropy qubits. This effect demonstrates that quantum thermal machines can surpass classical ones, reminiscent of quantum advantages in other fields, and is applicable to a broad range of technologically important scenarios.

  18. Solid oxide electrochemical reactor science.

    SciTech Connect (OSTI)

    Sullivan, Neal P.; Stechel, Ellen Beth; Moyer, Connor J.; Ambrosini, Andrea; Key, Robert J.

    2010-09-01

    Solid-oxide electrochemical cells are an exciting new technology. Development of solid-oxide cells (SOCs) has advanced considerable in recent years and continues to progress rapidly. This thesis studies several aspects of SOCs and contributes useful information to their continued development. This LDRD involved a collaboration between Sandia and the Colorado School of Mines (CSM) ins solid-oxide electrochemical reactors targeted at solid oxide electrolyzer cells (SOEC), which are the reverse of solid-oxide fuel cells (SOFC). SOECs complement Sandia's efforts in thermochemical production of alternative fuels. An SOEC technology would co-electrolyze carbon dioxide (CO{sub 2}) with steam at temperatures around 800 C to form synthesis gas (H{sub 2} and CO), which forms the building blocks for a petrochemical substitutes that can be used to power vehicles or in distributed energy platforms. The effort described here concentrates on research concerning catalytic chemistry, charge-transfer chemistry, and optimal cell-architecture. technical scope included computational modeling, materials development, and experimental evaluation. The project engaged the Colorado Fuel Cell Center at CSM through the support of a graduate student (Connor Moyer) at CSM and his advisors (Profs. Robert Kee and Neal Sullivan) in collaboration with Sandia.

  19. Designing Optimal Heat and Power Systems for Industrial Processes 

    E-Print Network [OSTI]

    Rutkowski, M. A.; Witherell, W. D.

    1988-01-01

    . It must facilitate understanding the tradeoffs among the components of the heat and power system including steam generation, furnaces used for process heating, steam and gas turbines, heat exchange networks, heat pumps, refrigeration systems, and purchased...

  20. Steel refining with an electrochemical cell

    DOE Patents [OSTI]

    Blander, M.; Cook, G.M.

    1988-05-17

    Apparatus is described for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight oxygen and not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom. 2 figs.

  1. Steel refining with an electrochemical cell

    DOE Patents [OSTI]

    Blander, M.; Cook, G.M.

    1985-05-21

    Disclosed is an apparatus for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom.

  2. Refrigeration system with a compressor-pump unit and a liquid-injection desuperheating line

    DOE Patents [OSTI]

    Gaul, Christopher J. (Thornton, CO)

    2001-01-01

    The refrigeration system includes a compressor-pump unit and/or a liquid-injection assembly. The refrigeration system is a vapor-compression refrigeration system that includes an expansion device, an evaporator, a compressor, a condenser, and a liquid pump between the condenser and the expansion device. The liquid pump improves efficiency of the refrigeration system by increasing the pressure of, thus subcooling, the liquid refrigerant delivered from the condenser to the expansion device. The liquid pump and the compressor are driven by a single driving device and, in this regard, are coupled to a single shaft of a driving device, such as a belt-drive, an engine, or an electric motor. While the driving device may be separately contained, in a preferred embodiment, the liquid pump, the compressor, and the driving device (i.e., an electric motor) are contained within a single sealable housing having pump and driving device cooling paths to subcool liquid refrigerant discharged from the liquid pump and to control the operating temperature of the driving device. In another aspect of the present invention, a liquid injection assembly is included in a refrigeration system to divert liquid refrigerant from the discharge of a liquid pressure amplification pump to a compressor discharge pathway within a compressor housing to desuperheat refrigerant vapor to the saturation point within the compressor housing. The liquid injection assembly includes a liquid injection pipe with a control valve to meter the volume of diverted liquid refrigerant. The liquid injection assembly may also include a feedback controller with a microprocessor responsive to a pressure sensor and a temperature sensor both positioned between the compressor to operate the control valve to maintain the refrigerant at or near saturation.

  3. ASHRAE $1000 Scholarship Application (02/26/2013) The Utah Chapter of the American Society of Heating, Refrigerating and Air Conditioning

    E-Print Network [OSTI]

    van den Berg, Jur

    of Heating, Refrigerating and Air Conditioning Engineers is offering multiple $1,000 scholarships automation or controls, heating, ventilating, refrigeration or air conditioning (HVAC) principles are invited

  4. Electrical characterization of electrochemically grown single copper nanowires

    E-Print Network [OSTI]

    Ludwig-Maximilians-Universität, München

    of a contamination layer or oxidation of the wire. Electrical measurements on electrochemically grown nanowires were

  5. Energy Savings Potential and Research & Development Opportunities for Commercial Refrigeration

    SciTech Connect (OSTI)

    none,

    2009-09-01

    This study documents the energy consumption of commercial refrigeration equipment (CRE) in the U.S. and evaluated the energy savings potential of various technologies and energy efficiency measures that could be applied to such equipment. The study provided an overview of CRE applications, assessed the energy-savings potential of CRE in the U.S., outline key barriers to adoption of energy-savings technologies, and recommended opportunities for advanced energy saving technology research. The study was modeled after an earlier 1996 report by Arthur D. Little, Inc., and updated key information, examined more equipment types, and outlined long-term research and development opportunities.

  6. An Electrochemical Potentiostat Interface for Mobile Devices: Enabling Remote Medical Diagnostics

    E-Print Network [OSTI]

    Fu, Henry; Lew, Michael; Menon, Shruti; Scratchley, Craig; Parameswaran, M Ash

    2015-01-01

    An electrochemical potentiostat interface for mobile devices has been designed and implemented. The interface consists of a potentiostat module, a microcontroller module, and a Bluetooth module. The potentiostat module performs electrochemical measurements and detects the responses from the samples. The microcontroller module controls the test and communication processes. The Bluetooth module links the system to a mobile device, where the mobile device acts as a control-console, data storage system, communication unit, and graphical plotter for the overall diagnostic processes. This interface is suitable for point-of-care and remote diagnostics, enhancing the capabilities of mobile devices in telemedicine.

  7. Two-Phase Cooling Method Using R134a Refrigerant to Cool Power Electronic Devices

    E-Print Network [OSTI]

    Tolbert, Leon M.

    Two-Phase Cooling Method Using R134a Refrigerant to Cool Power Electronic Devices Jeremy B, TN 37932 Abstract This paper presents a two-phase cooling method using R134a refrigerant). The cooling method involves submerging PE devices in an R134a bath, which limits the junction temperature

  8. Measurements with reticulated vitreous carbon stacks in thermoacoustic prime movers and refrigerators

    SciTech Connect (OSTI)

    Adeff, J.A.; Hofler, T.J.; Atchley, A.A.; Moss, W.C.

    1998-07-01

    Reticulated vitreous carbon has been successfully used as a stack material in thermoacoustic prime movers and refrigerators. It is a rigid glassy carbon material, with a porous spongelike structure. Test results indicate peak pressure amplitudes of up to 32{percent} in a prime mover, and refrigeration performance comparable to that of a traditional plastic roll stack. {copyright} {ital 1998 Acoustical Society of America.}

  9. 2180, Page 1 International Refrigeration and Air Conditioning Conference at Purdue, July 14-17, 2014

    E-Print Network [OSTI]

    2180, Page 1 15th International Refrigeration and Air Conditioning Conference at Purdue, July 14 in Yashar and Lee (2013); they optimized the evaporator circuitry for a rooftop air- conditioning (RTU) unit;2180, Page 2 15th International Refrigeration and Air Conditioning Conference at Purdue, July 14-17, 2014

  10. Use of chlorofluorocarbons in refrigeration, insulation and mobile air conditioning in the USA*

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    . (Keywords: CFCs; refrigeration; air conditioning; insulation; ozone depletion) Utilisation des to this global environmental issue by signing for R22 were obtained from the Air Conditioning and the MontrealFILE COPY DO NOT REMOVE Use of chlorofluorocarbons in refrigeration, insulation and mobile air

  11. M. Bahrami ENSC 461 (S 11) Tutorial 4 1 ENSC 461 Tutorial, Week#6 Refrigeration Cycle

    E-Print Network [OSTI]

    Bahrami, Majid

    M. Bahrami ENSC 461 (S 11) Tutorial 4 1 ENSC 461 Tutorial, Week#6 ­ Refrigeration Cycle A large of the refrigerant, b) the power input to the compressor, c) the mass flow rate of the cooling water, and d) the rate to represent the system Condenser Evaporator LQ 4 3 2 1 Wc QH Expansion Valve Compressor = 100kW High Pressure

  12. DYNAMIC MODEL OF AN INDUSTRIAL HEAT PUMP USING WATER AS REFRIGERANT

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 DYNAMIC MODEL OF AN INDUSTRIAL HEAT PUMP USING WATER AS REFRIGERANT CHAMOUN MARWAN to improve industrial energy efficiency, the development of a high temperature heat pump using water vapor as refrigerant is investigated. Technical problems restraining the feasibility of this industrial heat pump

  13. Balancing Energy Consumption and Food Quality Loss in Supermarket Refrigeration System

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Balancing Energy Consumption and Food Quality Loss in Supermarket Refrigeration System J. Cai and J energy consumption and food quality loss, at varying ambient condition, in a supermarket refrigeration for energy savings without extra loss of food quality. We also show that by utilizing the relatively slow

  14. CORRELATING EVAPORATION HEAT TRANSFER COEFFICIENT OF REFRIGERANT R-134a IN A PLATE HEAT EXCHANGER

    E-Print Network [OSTI]

    Kandlikar, Satish

    1 CORRELATING EVAPORATION HEAT TRANSFER COEFFICIENT OF REFRIGERANT R-134a IN A PLATE HEAT EXCHANGER for evaporation heat transfer coefficient of refrigerant R-134a flowing in a plate heat exchanger. Correlation schemes proposed by Yan and Lin (1999b) for modeling the heat transfer coefficient in both a single- phase

  15. The Impact of Control Technology on the Demand Response Potential of California Industrial Refrigerated Facilities Final Report

    E-Print Network [OSTI]

    Scott, Doug

    2014-01-01

    and Automated Demand Response in Industrial RefrigeratedDemand Response .. ..Technology on the Demand Response Potential of California

  16. Electrolyte for an electrochemical cell

    DOE Patents [OSTI]

    Bates, J.B.; Dudney, N.J.

    1997-01-28

    Described is a thin-film battery, especially a thin-film microbattery, and a method for making the same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte amorphous lithium phosphorus oxynitride which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between {minus}15 C and 150 C. 9 figs.

  17. Electrolyte for an electrochemical cell

    DOE Patents [OSTI]

    Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN)

    1997-01-01

    Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte amorphous lithium phosphorus oxynitride which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

  18. Cathode for an electrochemical cell

    DOE Patents [OSTI]

    Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Gruzalski, Greg R. (Oak Ridge, TN); Luck, Christopher F. (Knoxville, TN)

    2001-01-01

    Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

  19. Synthesis and electrochemical properties of NiO nanospindles

    SciTech Connect (OSTI)

    Zhou, Hai; Lv, Baoliang; Xu, Yao; Wu, Dong

    2014-02-01

    Graphical abstract: NiO nanospindles with a different electrochemical activity as compared to those previous reports were synthesized via an agglomeration–dissolution–recrystallization growth process without the addition of any surfactant. - Highlights: • NiO nanospindles were synthesized without the addition of any surfactant. • The agglomeration–dissolution–recrystallization growth process was used to explain the precursors’ formation process of the spindle-like NiO. • As-obtained spindle-like NiO showed a different electrochemical activity as compared to those previous reports. - Abstract: NiO nanospindles were successfully synthesized via a hydrothermal and post-treatment method. The as-synthesized nanospindles were about several hundred nanometers in width and about one micrometer in length. X-ray diffraction (XRD) analysis revealed that the spindle-like structure was cubic NiO phase crystalline. Scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) analysis indicated that these NiO nanospindles were of single crystal nature. On the basis of time-dependent experiments, a possible agglomeration–dissolution–recrystallization growth process was proposed to explain the formation process of the spindle-like precursors. The cyclic voltammetry (CV) measurement showed that the as-prepared spindle-like NiO exhibited a pseudo-capacitance behavior.

  20. Mapping Ionic Currents and Reactivity on the Nanoscale: Electrochemical Strain Microscopy

    SciTech Connect (OSTI)

    Kalinin, S.V. (Center for Nanophase Materials Sciences, ORNL) [Center for Nanophase Materials Sciences, ORNL

    2010-10-19

    Solid-state electrochemical processes in oxides underpin a broad spectrum of energy and information storage devices, ranging from Li-ion and Li-air batteries, to solid oxide fuel cells (SOFC) to electroresistive and memristive systems. These functionalities are controlled by the bias-driven diffusive and electromigration transport of mobile ionic species, as well as intricate a set of electrochemical and defect-controlled reactions at interfaces and in bulk. Despite the wealth of device-level and atomistic studies, little is known on the mesoscopic mechanisms of ion diffusion and electronic transport on the level of grain clusters, individual grains, and extended defects. The development of the capability for probing ion transport on the nanometer scale is a key to deciphering complex interplay between structure, functionality, and performance in these systems. Here we introduce Electrochemical Strain Microscopy, a scanning probe microscopy technique based on strong strain-bias coupling in the systems in which local ion concentrations are changed by electrical fields. The imaging capability, as well as time- and voltage spectroscopies analogous to traditional current based electrochemical characterization methods are developed. The reversible intercalation of Li and mapping electrochemical activity in LiCoO2 is demonstrated, illustrating higher Li diffusivity at non-basal planes and grain boundaries. In Si-anode device structure, the direct mapping of Li diffusion at extended defects and evolution of Li-activity with charge state is explored. The electrical field-dependence of Li mobility is studied to determine the critical bias required for the onset of electrochemical transformation, allowing reaction and diffusion processes in the battery system to be separated at each location. Finally, the applicability of ESM for probing oxygen vacancy diffusion and oxygen reduction/evolution reactions is illustrated, and the high resolution ESM maps are correlated with aberration corrected scanning transmission electron microscopy imaging. The future potential for deciphering mechanisms of electrochemical transformations on an atomically-defined single-defect level is discussed.

  1. HFC-134A and HCFC-22 supermarket refrigeration demonstration and laboratory testing. Phase I. Final report

    SciTech Connect (OSTI)

    1996-04-01

    Aspen Systems and a team of nineteen agencies and industry participants conducted a series of tests to determine the performance of HFC-134a, HCFC-22, and CFC-502 for supermarket application. This effort constitutes the first phase of a larger project aimed at carrying out both laboratory and demonstration tests of the most viable HFC refrigerants and the refrigerants they replace. The results of the Phase I effort are presented in the present report. The second phase of the project has also been completed. It centered on testing all viable HFC replacement refrigerants for CFC-502. These were HFC-507, HFC-404A, and HFC-407A. The latter results are published in the Phase II report for this project. As part of Phase I, a refrigeration rack utilizing a horizontal open drive screw compressor was constructed in our laboratory. This refrigeration rack is a duplicate of one we have installed in a supermarket in Clifton Park, NY.

  2. COFELY Refrigeration | Rdiger Roth | European Heat Pump Summit 2013 CopyrightCOFELYDeutuschlandGmbH2009.AlleRechtevorbehalten.

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    COFELY Refrigeration | Rüdiger Roth | European Heat Pump Summit 2013 Seite 1 Copyright©COFELYDeutuschlandGmbH2009.AlleRechtevorbehalten. #12;COFELY Refrigeration | Rüdiger Roth | European Heat Pump Summit 2013 Campaign Spectrum: Heat pump with speed controlled screw compressor #12;COFELY Refrigeration | Rüdiger Roth

  3. BF[subscript 3]-Promoted Electrochemical Properties of Quinoxaline in Propylene Carbonate

    E-Print Network [OSTI]

    Diesendruck, Charles E.

    Electrochemical and density functional studies demonstrate that coordination of electrolyte constituents to quinoxalines modulates their electrochemical properties. Quinoxalines are shown to be electrochemically inactive ...

  4. Direct Visualization of Solid Electrolyte Interphase Formation in Lithium-Ion Batteries with In Situ Electrochemical Transmission Electron Microscopy

    SciTech Connect (OSTI)

    Unocic, Raymond R [ORNL] [ORNL; Sun, Xiao-Guang [ORNL] [ORNL; Sacci, Robert L [ORNL] [ORNL; Adamczyk, Leslie A [ORNL] [ORNL; Alsem, Daan Hein [Hummingbird Scientific] [Hummingbird Scientific; Dai, Sheng [ORNL] [ORNL; Dudney, Nancy J [ORNL] [ORNL; More, Karren Leslie [ORNL] [ORNL

    2014-01-01

    Complex, electrochemically driven transport processes form the basis of electrochemical energy storage devices. The direct imaging of electrochemical processes at high spatial resolution and within their native liquid electrolyte would significantly enhance our understanding of device functionality, but has remained elusive. In this work we use a recently developed liquid cell for in situ electrochemical transmission electron microscopy to obtain insight into the electrolyte decomposition mechanisms and kinetics in lithium-ion (Li-ion) batteries by characterizing the dynamics of solid electrolyte interphase (SEI) formation and evolution. Here we are able to visualize the detailed structure of the SEI that forms locally at the electrode/electrolyte interface during lithium intercalation into natural graphite from an organic Li-ion battery electrolyte. We quantify the SEI growth kinetics and observe the dynamic self-healing nature of the SEI with changes in cell potential.

  5. Waste Heat Powered Ammonia Absorption Refrigeration Unit for LPG Recovery

    SciTech Connect (OSTI)

    Donald C, Energy Concepts Co.; Lauber, Eric, Western Refining Co.

    2008-06-20

    An emerging DOE-sponsored technology has been deployed. The technology recovers light ends from a catalytic reformer plant using waste heat powered ammonia absorption refrigeration. It is deployed at the 17,000 bpd Bloomfield, New Mexico refinery of Western Refining Company. The technology recovers approximately 50,000 barrels per year of liquefied petroleum gas that was formerly being flared. The elimination of the flare also reduces CO2 emissions by 17,000 tons per year, plus tons per year reductions in NOx, CO, and VOCs. The waste heat is supplied directly to the absorption unit from the Unifiner effluent. The added cooling of that stream relieves a bottleneck formerly present due to restricted availability of cooling water. The 350oF Unifiner effluent is cooled to 260oF. The catalytic reformer vent gas is directly chilled to minus 25oF, and the FCC column overhead reflux is chilled by 25oF glycol. Notwithstanding a substantial cost overrun and schedule slippage, this project can now be considered a success: it is both profitable and highly beneficial to the environment. The capabilities of directly-integrated waste-heat powered ammonia absorption refrigeration and their benefits to the refining industry have been demonstrated.

  6. Heat pump/refrigerator using liquid working fluid

    DOE Patents [OSTI]

    Wheatley, John C. (Del Mar, CA); Paulson, Douglas N. (Del Mar, CA); Allen, Paul C. (Solana Beach, CA); Knight, William R. (Corvallis, OR); Warkentin, Paul A. (San Diego, CA)

    1982-01-01

    A heat transfer device is described that can be operated as a heat pump or refrigerator, which utilizes a working fluid that is continuously in a liquid state and which has a high temperature-coefficient of expansion near room temperature, to provide a compact and high efficiency heat transfer device for relatively small temperature differences as are encountered in heating or cooling rooms or the like. The heat transfer device includes a pair of heat exchangers that may be coupled respectively to the outdoor and indoor environments, a regenerator connecting the two heat exchangers, a displacer that can move the liquid working fluid through the heat exchangers via the regenerator, and a means for alternately increasing and decreasing the pressure of the working fluid. The liquid working fluid enables efficient heat transfer in a compact unit, and leads to an explosion-proof smooth and quiet machine characteristic of hydraulics. The device enables efficient heat transfer as the indoor-outdoor temperature difference approaches zero, and enables simple conversion from heat pumping to refrigeration as by merely reversing the direction of a motor that powers the device.

  7. Refrigeration options for the Advanced Light Source Superbend Dipole Magnets

    SciTech Connect (OSTI)

    Green, M.A.; Hoyer, E.H.; Schlueter, R.D.; Taylor, C.E.; Zbasnik, J.; Wang, S.T.

    1999-07-09

    The 1.9 GeV Advance Light Source (ALS) at the Lawrence Berkeley National Laboratory (LBNL) produces photons with a critical energy of about 3.1 kev at each of its thirty-six 1.3 T gradient bending magnets. It is proposed that at three locations around the ring the conventional gradient bending magnets be replaced with superconducting bending magnets with a maximum field of 5.6 T. At the point where the photons are extracted, their critical energy will be about 12 keV. In the beam lines where the SuperBend superconducting magnets are installed, the X ray brightness at 20 keV will be increased over two orders of magnitude. This report describes three different refrigeration options for cooling the three SuperBend dipoles. The cooling options include: (1) liquid helium and liquid nitrogen cryogen cooling using stored liquids, (2) a central helium refrigerator (capacity 70 to 100 W) cooling all of the SuperBend magnets, (3) a Gifford McMahon (GM) cryocooler on each of the dipoles. This paper describes the technical and economic reasons for selecting a small GM cryocooler as the method for cooling the SuperBend dipoles on the LBNL Advanced Light Source.

  8. Boundary Layer Analysis of Membraneless Electrochemical Cells

    E-Print Network [OSTI]

    Braff, William

    A mathematical theory is presented for the charging and discharging behavior of membraneless electrochemical cells that rely on slow diffusion in laminar flow to separate the half reactions. Ion transport is described by ...

  9. Electrochemical NOx Sensors for Monitoring Diesel Emissions

    Broader source: Energy.gov [DOE]

    A unique electrochemical sensing strategy correlating the level of NOx with an impedance-based signal shows promise for sensitivity, stability, and accuracy while incorporating single-cell structures and simple electronics into low-cost designs

  10. Microfluidic Actuation Using Electrochemically Generated Bubbles

    E-Print Network [OSTI]

    Sachs, Frederick

    Microfluidic Actuation Using Electrochemically Generated Bubbles Susan Z. Hua,*, Frederick Sachs, Buffalo, New York 14260 Bubble-based actuation in microfluidic applications is attractive owing closing) rate increases with applied voltage, small microfluidic dimensions accelerate bubble deflation

  11. From corrosion to batteries: Electrochemical interface studies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    From corrosion to batteries: Electrochemical interface studies Thursday, October 18, 2012 - 11:00am SSRL, Bldg. 137, Rm 226 Dr. Frank Uwe Renner Max-Planck-Institut fr...

  12. Bismuth-based electrochemical stripping analysis

    DOE Patents [OSTI]

    Wang, Joseph

    2004-01-27

    Method and apparatus for trace metal detection and analysis using bismuth-coated electrodes and electrochemical stripping analysis. Both anodic stripping voltammetry and adsorptive stripping analysis may be employed.

  13. Feedback Controlled High Frequency Electrochemical Micromachining 

    E-Print Network [OSTI]

    Ozkeskin, Fatih Mert

    2008-10-10

    are different from those for silicon. A promising mass production method for micro/meso scale components is electrochemical micromachining. The complex system, however, requires high precision mechanical fixtures and sophisticated instrumentation for proper...

  14. Rechargeable thin-film electrochemical generator

    DOE Patents [OSTI]

    Rouillard, Roger (Beloeil, CA); Domroese, Michael K. (South St. Paul, MN); Hoffman, Joseph A. (Minneapolis, MN); Lindeman, David D. (Hudson, WI); Noel, Joseph-Robert-Gaetan (St-Hubert, CA); Radewald, Vern E. (Austin, TX); Ranger, Michel (Lachine, CA); Sudano, Anthony (Laval, CA); Trice, Jennifer L. (Eagan, MN); Turgeon, Thomas A. (Fridley, MN)

    2000-09-15

    An improved electrochemical generator is disclosed. The electrochemical generator includes a thin-film electrochemical cell which is maintained in a state of compression through use of an internal or an external pressure apparatus. A thermal conductor, which is connected to at least one of the positive or negative contacts of the cell, conducts current into and out of the cell and also conducts thermal energy between the cell and thermally conductive, electrically resistive material disposed on a vessel wall adjacent the conductor. The thermally conductive, electrically resistive material may include an anodized coating or a thin sheet of a plastic, mineral-based material or conductive polymer material. The thermal conductor is fabricated to include a resilient portion which expands and contracts to maintain mechanical contact between the cell and the thermally conductive material in the presence of relative movement between the cell and the wall structure. The electrochemical generator may be disposed in a hermetically sealed housing.

  15. Electrochemical chlorination for purifying domestic water supplies 

    E-Print Network [OSTI]

    Peters, Joseph Ludwig

    1973-01-01

    ELECTROCHEMICAL CHLORINATION FOR PURIFYING DOMESTIC WATER SUPPLIES A Thesis by JOSEPH LUDWIG PETERS' JR' Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE... December 1973 Major Subject: Agricultural Engineering ELECTROCHEMICAL CHLORINATION FOR PURIFYING DOMESTIC WATER SUPPLIES A Thesis JOSEPH LUDWIG PETERS, JR. Approved as to style and content by: (Chairman of Committee) ( ead of epartm nt) (Member...

  16. Electrochemical Energy Storage Technical Team Roadmap

    SciTech Connect (OSTI)

    2013-06-01

    This U.S. DRIVE electrochemical energy storage roadmap describes ongoing and planned efforts to develop electrochemical energy storage technologies for plug-in electric vehicles (PEVs). The Energy Storage activity comprises a number of research areas (including advanced materials research, cell level research, battery development, and enabling R&D which includes analysis, testing and other activities) for advanced energy storage technologies (batteries and ultra-capacitors).

  17. Alternative Waste Forms for Electro-Chemical Salt Waste

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Sundaram, S. K.; Riley, Brian J.; Matyas, Josef; Arreguin, Shelly A.; Vienna, John D.

    2009-10-28

    This study was undertaken to examine alternate crystalline (ceramic/mineral) and glass waste forms for immobilizing spent salt from the Advanced Fuel Cycle Initiative (AFCI) electrochemical separations process. The AFCI is a program sponsored by U.S. Department of Energy (DOE) to develop and demonstrate a process for recycling spent nuclear fuel (SNF). The electrochemical process is a molten salt process for the reprocessing of spent nuclear fuel in an electrorefiner and generates spent salt that is contaminated with alkali, alkaline earths, and lanthanide fission products (FP) that must either be cleaned of fission products or eventually replaced with new salt to maintain separations efficiency. Currently, these spent salts are mixed with zeolite to form sodalite in a glass-bonded waste form. The focus of this study was to investigate alternate waste forms to immobilize spent salt. On a mole basis, the spent salt is dominated by alkali and Cl with minor amounts of alkaline earth and lanthanides. In the study reported here, we made an effort to explore glass systems that are more compatible with Cl and have not been previously considered for use as waste forms. In addition, alternate methods were explored with the hope of finding a way to produce a sodalite that is more accepting of as many FP present in the spent salt as possible. This study was done to investigate two different options: (1) alternate glass families that incorporate increased concentrations of Cl; and (2) alternate methods to produce a mineral waste form.

  18. Study about the flashing process through a metering expansion valve Mohammed Ait Bahajji, Jose M. Corberan *, Javier Urchueguia,

    E-Print Network [OSTI]

    Fernández de Córdoba, Pedro

    of chlorine to the atmosphere. The chlorinefluorocarbons (CFC) have a high destructive power of ozone device in a refrigeration cycle is first to maintain the pressure differential between the low pressure side (evaporator) and the high pressure side (condenser) for a compressor driven refrigerating process

  19. Electrochemical Monitoring of TiO2 Atomic Layer Deposition by Chronoamperometry and Scanning Electrochemical Microscopy

    E-Print Network [OSTI]

    Yu, Edward T.

    Electrochemical Monitoring of TiO2 Atomic Layer Deposition by Chronoamperometry and Scanning) was used to characterize the atomic layer deposition (ALD) of TiO2 on indium-doped tin oxide (ITO). KEYWORDS: atomic layer deposition (ALD), scanning electrochemical microscopy (SECM), nanoporous films

  20. Experimental study and analysis on components of a thermoacoustic refrigerator and thermoacoustic prime mover

    SciTech Connect (OSTI)

    Nohtomi, Makoto; Katsuta, Masafumi

    1999-07-01

    A thermoacoustic refrigerator and a thermoacoustic prime mover, due to its simple structure, would serve as very desirable systems because thermoacoustic prime movers can be driven with the waste heat such as an exhaust gas from engines, and with heat from the nature such as sunlight and a geothermal heat. The thermoacoustic refrigerator and the thermoacoustic prime mover combined would serve as a perfect cooling system without moving parts, CFC's and HFC's. Thus this Thermoacoustic-driven Thermoacoustic Refrigerator will replace the previous paper compression refrigeration system. The authors set up the thermoacoustic refrigerator and thermoacoustic prime mover to investigate the fundamental characteristics. On the refrigerator tests, dimensions of the stack are varied as a parameter of experiments. As a result, influences of the stack configuration on the performance are confirmed, so the design method for the optimum dimension to attain the large temperature difference can be indicated. About the prime mover tests, fundamental characteristics of stack dimensions is checked. The way to improve the thermal efficiency of the prime mover is mentioned in terms of the operating condition. Numerical calculations about the refrigerator are made which is based on the enthalpy flow model by Radebaugh. The result of calculations has a good agreement in quality with the experimental results, so the propriety of this model is confirmed.

  1. Safeguards and security modeling for electrochemical plants

    SciTech Connect (OSTI)

    Cipiti, B.B.; Duran, F.A.; Mendoza, L.A.; Parks, M.J.; Dominguez, D.; Le, T.D. [Sandia National Laboratories, PO Box 5800 MS 0747, Albuquerque, NM 87185 (United States)

    2013-07-01

    Safeguards and security design for reprocessing plants can lead to excessive costs if not incorporated early in the design process. The design for electrochemical plants is somewhat uncertain since these plants have not been built at a commercial scale in the past. The Separation and Safeguards Performance Model (SSPM), developed at Sandia National Laboratories, has been used for safeguards design and evaluation for multiple reprocessing plant types. The SSPM includes the following capabilities: -) spent fuel source term library, -) mass tracking of elements 1-99 and bulk solid/liquids, -) tracking of heat load and activity, -) customisable measurement points, -) automated calculation of ID and error propagation, -) alarm conditions and statistical tests, and -) user-defined diversion scenarios. Materials accountancy and process monitoring data can provide more timely detection of material loss specifically to protect against the insider threat. While the SSPM is capable of determining detection probabilities and examining detection times for material loss scenarios, it does not model the operations or spatial effects for a plant design. The STAGE software was chosen to model the physical protection system. STAGE provides a framework to create end-to-end scalable force-on-force combat simulations. It allows for a complete 3D model of a facility to be designed along with the design of physical protection elements. This software, then, can be used to model operations and response for various material loss scenarios. The future integration of the SSPM model data with the STAGE software will provide a more complete analysis of diversion scenarios to assist plant designers.

  2. Alternative Electrochemical Salt Waste Forms, Summary of FY/CY2011 Results

    SciTech Connect (OSTI)

    Riley, Brian J.; McCloy, John S.; Crum, Jarrod V.; Rodriguez, Carmen P.; Windisch, Charles F.; Lepry, William C.; Matyas, Josef; Westman, Matthew P.; Rieck, Bennett T.; Lang, Jesse B.; Pierce, David A.

    2011-12-01

    This report summarizes the 2011 fiscal+calendar year efforts for developing waste forms for a spent salt generated in reprocessing nuclear fuel with an electrochemical separations process. The two waste forms are tellurite (TeO2-based) glasses and sol-gel-derived high-halide mineral analogs to stable minerals found in nature.

  3. Modeling the Effects of Electrode Composition and Pore Structure on the Performance of Electrochemical Capacitors

    E-Print Network [OSTI]

    Popov, Branko N.

    -6 Energy storage mechanisms in an electrochemical capacitor include separation of charge at the interface storage in DL capacitance is essentially electrostatic in nature, and so DL charge/discharge processes Engineering, University of South Carolina, Swearingen Engineering Center, Columbia, South Carolina 29208, USA

  4. In situ atomic-scale imaging of electrochemical lithiation in silicon

    E-Print Network [OSTI]

    Zhu, Ting

    -dependent mobility of the interfaces. L ithium-ion batteries are increasingly being used as energy storage devicesIn situ atomic-scale imaging of electrochemical lithiation in silicon Xiao Hua Liu1 *, Jiang Wei the dynamic lithiation process of single-crystal silicon with atomic resolution. We observe a sharp interface

  5. Charging-free electrochemical system for harvesting low-grade thermal energy

    E-Print Network [OSTI]

    Cui, Yi

    Charging-free electrochemical system for harvesting low-grade thermal energy Yuan Yanga,1 , Seok processes, environment, solar-thermal, and geothermal en- ergy (1­3). It is generally difficult to convert Cuib,d,3 , and Gang Chena,3 a Department of Mechanical Engineering, Massachusetts Institute

  6. Fundamental-mode laser-beam propagation in optically inhomogeneous electrochemical media with

    E-Print Network [OSTI]

    Mandelis, Andreas

    of fuel cells and photoelectrochemical cells for solar energy conversion, electrochemical reactors and ofthe spot shape on the electrochemicalparameters of the system. 1. Introduction Reactions taking place with incident radiation. These processes can be influenced by the chemical species present on the electrode

  7. Theoretical evaluation of the optimal performance of a thermoacoustic refrigerator

    SciTech Connect (OSTI)

    Minner, B.L.; Braun, J.E.; Mongeau, L.G.

    1997-12-31

    Theoretical models were integrated with a design optimization tool to allow estimates of the maximum coefficient of performance for thermoacoustic cooling systems. The system model was validated using experimental results for a well-documented prototype. The optimization tool was then applied to this prototype to demonstrate the benefits of systematic optimization. A twofold increase in performance was predicted through the variation of component dimensions alone, while a threefold improvement was estimated when the working fluid parameters were also considered. Devices with a similar configuration were optimized for operating requirements representative of a home refrigerator. The results indicate that the coefficients of performance are comparable to those of existing vapor-compression equipment for this application. In addition to the choice of working fluid, the heat exchanger configuration was found to be a critical design factor affecting performance. Further experimental work is needed to confirm the theoretical predictions presented in this paper.

  8. Electrochemical synthesis of nanosized hydroxyapatite by pulsed direct current method

    SciTech Connect (OSTI)

    Nur, Adrian; Rahmawati, Alifah; Ilmi, Noor Izzati; Affandi, Samsudin; Widjaja, Arief

    2014-02-24

    Synthesis of nanosized of hydroxyapatite (HA) by electrochemical pulsed direct current (PDC) method has been studied. The aim of this work is to study the influence of various PDC parameters (pH initial, electrode distance, duty cycle, frequency, and amplitude) on particle surface area of HA powders. The electrochemical synthesis was prepared in solution Ca{sup 2+}/EDTA{sup 4?}/PO{sub 4}{sup 3+} at concentration 0.25/0.25/0.15 M for 24 h. The electrochemical cell was consisted of two carbon rectangular electrodes connected to a function generator to produce PDC. There were two treatments for particles after electrosynthesized, namely without aging and aged for 2 days at 40 °C. For both cases, the particles were filtered and washed by demineralized water to eliminate the impurities and unreacted reactants. Then, the particles were dried at 100 °C for 2 days. The dried particles were characterized by X-ray diffraction, surface area analyzer, scanning electron microscopy (SEM), Fourier transform infrared spectra and thermogravimetric and differential thermal analysis. HA particles can be produced when the initial pH > 6. The aging process has significant effect on the produced HA particles. SEM images of HA particles showed that the powders consisted of agglomerates composed of fine crystallites and have morphology plate-like and sphere. The surface area of HA particles is in the range of 25 – 91 m{sup 2}/g. The largest particle surface area of HA was produced at 4 cm electrode distance, 80% cycle duty, frequency 0.1 Hz, amplitude 9 V and with aging process.

  9. Synchronous temperature rate control and apparatus for refrigeration with reduced energy consumption

    DOE Patents [OSTI]

    Gomes, Alberto Regio; Keres, Stephen L.; Kuehl, Steven J.; Litch, Andrew D.; Richmond, Peter J.; Wu, Guolian

    2015-09-22

    A refrigerator appliance configuration, and associated methods of operation, for an appliance with a controller, a condenser, at least one evaporator, a compressor, and two refrigeration compartments. The configuration may be equipped with a variable-speed or variable-capacity compressor, variable speed evaporator or compartment fans, a damper, and/or a dual-temperature evaporator with a valve system to control flow of refrigerant through one or more pressure reduction devices. The controller, by operation of the compressor, fans, damper and/or valve system, depending on the appliance configuration, synchronizes alternating cycles of cooling each compartment to a temperature approximately equal to the compartment set point temperature.

  10. Effects of temperature on desiccant catalysis of refrigerant and lubricant decomposition. Final report

    SciTech Connect (OSTI)

    Rohatgi, N.D.T.

    1998-06-01

    Accelerated aging at high temperatures (149 C) for short aging times (28 days) is effective in screening the compatibility of different materials in refrigeration systems. However, in actual applications temperatures are usually lower and operating times much longer. Therefore plots to allow for interpolation or extrapolation of experimental data to actual operating conditions are needed. In the current study, aging of refrigerant/lubricant/desiccant/metal systems was conducted at five different temperatures, and for each temperature at four different aging times. The data collected from this study provided plots relating refrigerant or lubricant decomposition to aging time, aging temperature, and type of desiccant, which can be used for interpolation or extrapolation.

  11. Development and Evaluation of a Sandia Cooler-based Refrigerator Condenser

    SciTech Connect (OSTI)

    Johnson, Terry A.; Kariya, Harumichi Arthur; Leick, Michael T.; Zimmerman, Mark D.; Li, Manjie; Du, Yilin; Lee, Hoseong; Hwang, Yunho; Radermacher, Reinhard

    2015-07-01

    This report describes the first design of a refrigerator condenser using the Sandia Cooler, i.e. air - bearing supported rotating heat - sink impeller. The project included ba seline performance testing of a residential refrigerator, analysis and design development of a Sandia Cooler condenser assembly including a spiral channel baseplate, and performance measurement and validation of this condenser system as incorporated into the residential refrigerator. Comparable performance was achieved in a 60% smaller volume package. The improved modeling parameters can now be used to guide more optimized designs and more accurately predict performance.

  12. Regeneration tests of a room temperature magnetic refrigerator and heat pump

    E-Print Network [OSTI]

    Brown, G V

    2014-01-01

    A magnetic heat pump apparatus consisting of a solid magnetic refrigerant, gadolinium, and a liquid regenerator column of ethanol and water has been tested. Utilizing a 7T field, it produced a maximum temperature span of 80 K, and in separate tests, a lowest temperature of 241 K and a highest temperature of 328 K. Thermocouples, placed at intervals along the regenerator tube, permitted measurement of the temperature distribution in the regenerator fluid. No attempt was made to extract refrigeration from the device, but analysis of the temperature distributions shows that 34 watts of refrigeration was produced.

  13. Triple-effect absorption refrigeration system with double-condenser coupling

    DOE Patents [OSTI]

    DeVault, R.C.; Biermann, W.J.

    1993-04-27

    A triple effect absorption refrigeration system is provided with a double-condenser coupling and a parallel or series circuit for feeding the refrigerant-containing absorbent solution through the high, medium, and low temperature generators utilized in the triple-effect system. The high temperature condenser receiving vaporous refrigerant from the high temperature generator is double coupled to both the medium temperature generator and the low temperature generator to enhance the internal recovery of heat within the system and thereby increase the thermal efficiency thereof.

  14. Triple-effect absorption refrigeration system with double-condenser coupling

    DOE Patents [OSTI]

    DeVault, Robert C. (Knoxville, TN); Biermann, Wendell J. (Fayetteville, NY)

    1993-01-01

    A triple effect absorption refrigeration system is provided with a double-condenser coupling and a parallel or series circuit for feeding the refrigerant-containing absorbent solution through the high, medium, and low temperature generators utilized in the triple-effect system. The high temperature condenser receiving vaporous refrigerant from the high temperature generator is double coupled to both the medium temperature generator and the low temperature generator to enhance the internal recovery of heat within the system and thereby increase the thermal efficiency thereof.

  15. Exergy Analysis for Cryogenic Process and Equipment Optimizations 

    E-Print Network [OSTI]

    Chiu, C.

    1982-01-01

    an analytical min imum compressor work analysis for the classical cascade natural gas liquefaction cycle. The temp erature dependence of the irreversible work of heat transfer due to a finite temperature approach was shown to be inversely proportional... Liquefaction Process lAl ~-:SUICDDL PROPANE COMPRESSOR -----......... OR (Il~ Cll I I I I I 1 cw -- _ I T lAI' I 1:,N!.J ----------, I FUEL, I I I L~_~ FLASH MIXED REFRIGERANT COMPRESSORS Figure 2 - Propane-Precooled Mixed Refrigerant...

  16. On the Electrochemical Response of Porous Functionalized Graphene Electrodes

    E-Print Network [OSTI]

    Aksay, Ilhan A.

    devices such as fuel cells6-8 or dye-sensitized solar cells,9-12 where porosity enables the diffusive a significant impact on effective kinetics of electrochemical reactions. With the advent of electrochemical

  17. An Advanced Solar-Powered Rotary Solid Adsorption Refrigerator with High Performance 

    E-Print Network [OSTI]

    Zheng, A.; Gu, J.

    2006-01-01

    In this paper, according to practical consideration, a new solar powered rotary solid adsorption refrigerator system adopting activated carbon fibre + ethanol as its adsorption pair has been designed with higher performance. ...

  18. Dynamic Modeling and Cascaded Control for a Multi-Evaporator Supermarket Refrigeration System 

    E-Print Network [OSTI]

    Gupta, Ankush 1986-

    2012-09-27

    The survey from US Department of Energy showed that about one-third of energy consumption in US is due to air conditioning and refrigeration systems. This significant usage of electricity in the HVAC industry has prompted researchers to develop...

  19. Patterns of Refrigerant Use Resulting From Regulations Designed to Protect the Environment 

    E-Print Network [OSTI]

    Thomas, R.

    1996-01-01

    . These difficulties can be turned into a competitive advantage if the contractor understands the source of the difficulties. This paper explores some of the industry wide problems and solutions. The new refrigerants are many and are covered by venting, recycling...

  20. Fluctuations in ASHRAE Refrigerant Physical Properties and the Effect on Single and Two Phase Flow 

    E-Print Network [OSTI]

    Nagy, Paul

    2014-11-17

    handbook edition is released. Thirteen properties (liquid and vapor viscosity, thermal conductivity, specific heat, enthalpy, surface tension, density and specific volume) from five widely used refrigerants (R-22, R-134a, R-410a, R-152a, R-600a...

  1. Global emissions of refrigerants HCFC-22 and HFC-134a: Unforeseen seasonal contributions

    E-Print Network [OSTI]

    Xiang, Bin

    HCFC-22 (CHClF[subscript 2]) and HFC-134a (CH[subscript 2]FCF[subscript 3]) are two major gases currently used worldwide in domestic and commercial refrigeration and air conditioning. HCFC-22 contributes to stratospheric ...

  2. Impact of the Variable Refrigerant Volume Air Conditioning System on Building Energy Efficiency 

    E-Print Network [OSTI]

    Zhu, H.

    2006-01-01

    The application of the variable refrigerant volume multi-zone air conditioning systems has met with mixed results since the publication of the Design Standard for Energy Efficiency of Public Buildings. This paper analyzes the characteristics...

  3. Two-Phase Flow of Two HFC Refrigerant Mixtures Through Short Tube Orifices, Draft Final Report 

    E-Print Network [OSTI]

    Payne, W. V.; O'Neal, D. L.

    1994-01-01

    The present study presents data for flow of two refrigerant mixtures through short tube orifices. The two mixtures were R3211251134a (23%/25%/52% on a mass percentage basis) and R321125 (50%/50%). The following presents ...

  4. A Systems Approach to Optimize the Operation of a Refrigeration Unit at a Chemical Plant 

    E-Print Network [OSTI]

    Papar, R.; Zugibe, K.; Heitler, J.

    2005-01-01

    This paper focuses on the ongoing system level analysis and the optimization results of two steamturbine driven refrigeration units at the Dow Chemical company Peroxymerics (PXC) plant located at St. Charles Operations in Hahnville, LA. Six-sigma...

  5. Evaluating energy dissipation during expansion in a refrigeration cycle using flue pipe acoustic resonators

    E-Print Network [OSTI]

    Luckyanova, Maria N. (Maria Nickolayevna)

    2008-01-01

    This research evaluates the feasibility of using a flue pipe acoustic resonator to dissipate energy from a refrigerant stream in order to achieve greater cooling power from a cryorefrigeration cycle. Two models of the ...

  6. Ongoing Commissioning of a high efficiency supermarket with a ground coupled carbon dioxide refrigeration plant 

    E-Print Network [OSTI]

    Rehault, N.; Kalz, D.

    2012-01-01

    developed a new supermarket concept combining several innovative solutions for the refrigeration, lighting and heating/ventilation with the goal to reduce the energy consumption by about 30% compared to a standard subsidiary. A highly insulated building...

  7. OVERVIEW OF THE APPLIED BATTERY AND ELECTROCHEMICAL RESEARCH PROGRAM

    E-Print Network [OSTI]

    McLarnon, Frank

    2012-01-01

    ENERGY AND ENVIRONMENT DIVISION APPLIED BATTERY AND ELECTROCHEMICAL RESEARCH PROGRAM CONDUCT RESEARCH 30 SUBCONTRACTORS 9 IN-HOUSE PROJECTS

  8. Electrochemical detector integrated on microfabricated capillary electrophoresis chips

    DOE Patents [OSTI]

    Mathies, Richard A. (Moraga, CA); Glazer, Alexander N. (Orinda, CA); Lao, Kaiqin (San Francisco, CA); Woolley, Adam T. (Albany, CA)

    1999-01-01

    A microfabricated capillary electrophoresis chip which includes an integral thin film electrochemical detector for detecting molecules separated in the capillary.

  9. Electrochemical detector integrated on microfabricated capilliary electrophoresis chips

    DOE Patents [OSTI]

    Mathies, Richard A. (Moraga, CA); Glazer, Alexander N. (Orinda, CA); Woolley, Adam T. (Albany, CA); Lao, Kaigin (San Francisco, CA)

    2000-01-01

    A microfabricated capillary electrophoresis chip which includes an integral thin film electrochemical detector for detecting molecules separated in the capillary.

  10. Lithium based electrochemical cell systems having a degassing agent

    DOE Patents [OSTI]

    Hyung, Yoo-Eup (Naperville, IL); Vissers, Donald R. (Naperville, IL); Amine, Khalil (Downers Grove, IL)

    2012-05-01

    A lithium based electrochemical cell system includes a positive electrode; a negative electrode; an electrolyte; and a degassing agent.

  11. The intersection of interfacial forces and electrochemical reactions

    E-Print Network [OSTI]

    2013-01-01

    Electrochem. Soc. (61) Pourbaix, M. Atlas of Electrochemicalas well as the calculated Pourbaix diagram for gold. 61 The

  12. U.S. Residential Miscellaneous Refrigeration Products: Results from Amazon Mechanical Turk Surveys

    SciTech Connect (OSTI)

    Greenblatt, Jeffery B.; Young, Scott J.; Yang, Hung-Chia; Long, Timothy; Beraki, Bereket; Price, Sarah K.; Pratt, Stacy; Willem, Henry; Desroches, Louis-Benoit

    2013-11-14

    Amazon Mechanical Turk was used, for the first time, to collect statistically representative survey data from U.S. households on the presence, number, type and usage of refrigerators, freezers, and various “miscellaneous” refrigeration products (wine/beverage coolers, residential icemakers and non-vapor compression refrigerators and freezers), along with household and demographic information. Such products have been poorly studied to date, with almost no information available about shipments, stocks, capacities, energy use, etc. A total of 9,981 clean survey responses were obtained from five distinct surveys deployed in 2012. General refrigeration product survey responses were weighted to demographics in the U.S. Energy Information Administration’s Residential Energy Consumption Survey 2009 dataset. Miscellaneous refrigeration product survey responses were weighted according to demographics of product ownership found in the general refrigeration product surveys. Model number matching for a portion of miscellaneous refrigeration product responses allowed validation of refrigeration product characteristics, which enabled more accurate estimates of the penetrations of these products in U.S. households. We estimated that there were 12.3±1.0 million wine/beverage coolers, 5.5(–3.5,+3.2) million residential icemakers and 4.4(–2.7,+2.3) million non-vapor compression refrigerators in U.S. households in 2012. (All numerical results are expressed with ranges indicating the 95% confidence interval.) No evidence was found for the existence of non-vapor compression freezers. Moreover, we found that 15% of wine/beverage coolers used vapor compression cooling technology, while 85% used thermoelectric cooling technology, with the vast majority of thermoelectric units having capacities of less than 30 wine bottles (approximately 3.5 cubic feet). No evidence was found for the existence of wine/beverage coolers with absorption cooling technology. Additionally, we estimated that there were 3.6±1.0 million hybrid refrigerator-wine/beverage coolers and 0.9±0.5 million hybrid freezer-wine/beverage coolers in U.S. households. We also obtained estimates of miscellaneous refrigeration product capacities, lifetimes, purchase and installation costs, repair frequencies and costs, and maintenance costs. For wine/beverage coolers, we also obtained information on the penetration of built-in units, AC/DC operating capability, the use of internal lights, and distributions of door opening frequencies. This information is essential to develop detailed estimates of national energy usage and life-cycle costs, and would be helpful in obtaining information on other plug-load appliances. Additional information not highlighted in the main report was presented in Appendices.

  13. Lithium-Assisted Electrochemical Welding in Silicon Nanowire Battery Electrodes

    E-Print Network [OSTI]

    Li, Teng

    Lithium-Assisted Electrochemical Welding in Silicon Nanowire Battery Electrodes Khim Karki, Eric of lithium- assisted welding between physically contacted silicon nano- wires (SiNWs) induced by electrochemical lithiation and delithiation. This electrochemical weld between two SiNWs demonstrates facile

  14. Capacitance studies of cobalt oxide films formed via electrochemical precipitation

    E-Print Network [OSTI]

    Weidner, John W.

    Capacitance studies of cobalt oxide films formed via electrochemical precipitation Venkat prepared by electrochemically precipitating the hydroxide and heating it in air to form Co3O4, it is desirable to study the generality of the electrochemical precipitation technique as a means of fab- ricating

  15. Gas permeable electrode for electrochemical system

    DOE Patents [OSTI]

    Ludwig, Frank A. (Rancho Palos Verdes, CA); Townsend, Carl W. (Los Angeles, CA)

    1989-01-01

    An electrode apparatus adapted for use in electrochemical systems having an anode compartment and a cathode compartment in which gas and ions are produced and consumed in the compartments during generation of electrical current. The electrode apparatus includes a membrane for separating the anode compartment from the cathode compartment wherein the membrane is permeable to both ions and gas. The cathode and anode for the assembly are provided on opposite sides of the membrane. During use of the membrane-electrode apparatus in electrochemical cells, the gas and ions generated at the cathode or anode migrate through the membrane to provide efficient transfer of gas and ions between the anode and cathode compartments.

  16. Electrochemical apparatus comprising modified disposable rectangular cuvette

    DOE Patents [OSTI]

    Dattelbaum, Andrew M; Gupta, Gautam; Morris, David E

    2013-09-10

    Electrochemical apparatus includes a disposable rectangular cuvette modified with at least one hole through a side and/or the bottom. Apparatus may include more than one cuvette, which in practice is a disposable rectangular glass or plastic cuvette modified by drilling the hole(s) through. The apparatus include two plates and some means of fastening one plate to the other. The apparatus may be interfaced with a fiber optic or microscope objective, and a spectrometer for spectroscopic studies. The apparatus are suitable for a variety of electrochemical experiments, including surface electrochemistry, bulk electrolysis, and flow cell experiments.

  17. Tunable Electrochemical Properties of Fluorinated Graphene

    SciTech Connect (OSTI)

    Meduri, Praveen; Chen, Honghao; Xiao, Jie; Martinez, Jayson J.; Carlson, Thomas J.; Zhang, Jiguang; Deng, Zhiqun

    2013-06-18

    The structural and electrochemical properties of fluorinated graphene have been investigated by using a series of graphene fluorides (CFx, x=0.47, 0.66, 0.89). Fluorinated graphene exhibited high capacity retentions of 75-81% of theoretical capacity at moderate rates as cathode materials for primary lithium batteries. Specifically, CF0.47 maintained a capacity of 356 mAhg-1 at a 5C rate, superior to that of traditional fluorinated graphite. The discharged graphene fluorides also provide an electrochemical tool to probe the chemical bonding on the parent graphene substrate.

  18. Nanomaterial Labels in Electrochemical Immunosensors and Immunoassays

    SciTech Connect (OSTI)

    Liu, Guodong; Lin, Yuehe

    2007-12-15

    This article reviews recent advances in nanomaterial labels in electrochemical immunosensors and immunoassays. Various nanomaterial labels are discussed, including colloidal gold/silver, semiconductor nanoparticles, and markers loaded nanocarriers (carbon nanotubes, apoferritin, silica nanoparticles, and liposome beads). The enormous signal enhancement associated with the use of nanomaterial labels and with the formation of nanomaterial–antibody-antigen assemblies provides the basis for ultrasensitive electrochemical detection of disease-related protein biomarkers, biothreat agents, or infectious agents. In general, all endeavors cited here are geared to achieve one or more of the following goals: signal amplification by several orders of magnitude, lower detection limits, and detecting multiple targets.

  19. Overview of Air Liquide refrigeration systems between 1.8 K and 200 K

    SciTech Connect (OSTI)

    Gondrand, C.; Durand, F.; Delcayre, F.; Crispel, S. [AL-AT, 2 rue de Clémencières, 38360 Sassenage (France); Baguer, G. M. Gistau [CRYOGUY, 44, chemin de la Buisse, 38330 Biviers (France)

    2014-01-29

    Cryogenic refrigeration systems are necessary for numerous applications. Gas purification and distillation require temperatures between 15 K and 200 K depending on the application, space simulation chambers down to 15 K, superconductivity between 1.8 K and up to 75 K (magnets, cavities or HTS devices like cables, FCL, SMES, etc), Cold Neutron Sources between 15 and 20 K, etc. Air Liquide Advanced Technologies is designing and manufacturing refrigerators since 60 years to satisfy those needs. The step by step developments achieved have led to machines with higher efficiency and reliability. In 1965, reciprocating compressors and Joule Thomson expansion valves were used. In 1969, centripetal expanders began to be used. In 1980, oil lubricated screw compressors took the place of reciprocating compressors and a standard range of Claude cycle refrigerators was developed: the HELIAL series. 1980 was also the time for cryogenic centrifugal compressor development. In 2011, driven by the need for lower operational cost (high efficiency and low maintenance), cycle oil free centrifugal compressors on magnetic bearings were introduced instead of screw compressors. The power extracted by centripetal expanders was recovered. Based on this technology, a range of Turbo-Brayton refrigerators has been designed for temperatures between 40 K and 150 K. On-going development will enable widening the range of Turbo-Brayton refrigerators to cryogenic temperatures down to 15 K.. Cryogenic centrifugal circulators have been developed in order to answer to an increasing demand of 4 K refrigerators able to distribute cold power.

  20. The Use of Water Vapor as a Refrigerant: Impact of Cycle Modifications on Commercial Viability

    SciTech Connect (OSTI)

    Brandon F. Lachner, Jr.; Gregory F. Nellis; Douglas T. Reindl

    2004-08-30

    This project investigated the economic viability of using water as the refrigerant in a 1000-ton chiller application. The most attractive water cycle configuration was found to be a flash-intercooled, two-stage cycle using centrifugal compressors and direct contact heat exchangers. Component level models were developed that could be used to predict the size and performance of the compressors and heat exchangers in this cycle as well as in a baseline, R-134a refrigeration cycle consistent with chillers in use today. A survey of several chiller manufacturers provided information that was used to validate and refine these component models. The component models were integrated into cycle models that were subsequently used to investigate the life-cycle costs of both an R-134a and water refrigeration cycle. It was found that the first cost associated with the water as a refrigerant cycle greatly exceeded the savings in operating costs associated with its somewhat higher COP. Therefore, the water refrigeration cycle is not an economically attractive option to today's R-134a refrigeration system. There are a number of other issues, most notably the requirements associated with purging non-condensable gases that accumulate in a direct contact heat exchanger, which will further reduce the economic viability of the water cycle.

  1. Process Waste Heat Recovery in the Food Industry - A System Analysis 

    E-Print Network [OSTI]

    Lundberg, W. L.; Mutone, G. A.

    1983-01-01

    An analysis of an industrial waste heat recovery system concept is discussed. For example purposes, a food processing plant operating an ammonia refrigeration system for storage and blast freezing is considered. Heat is withdrawn from...

  2. Survey of electrochemical production of inorganic compounds. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-10-01

    The electrochemical generation of inorganic compounds, excluding chlorine/caustic, has been critically reviewed. About 60 x 10/sup 12/ Btu/y fossil fuel equivalent will be used in the year 2000 for the electrosynthesis of inorganic compounds. Significant energy savings in chlorate production can result from the development of suitable electrocatalysts for lowering the cathodic overpotential. Perchlorates, electrolytic hypochlorite, electrolytic manganese dioxide, fluorine and other miscellaneous compounds use relatively small amounts of electrical energy. Implementation of caustic scrubber technology for stack gas cleanup would result in appreciable amounts of sodium sulfate which could be electrolyzed to regenerate caustic. Hydrogen peroxide, now produced by the alkyl anthraquinone process, could be made electrolytically by a new process coupling anodic oxidation of sulfate with cathodic reduction of oxygen in alkaline solution. Ozone is currently manufactured using energy-inefficient silent discharge equipment. A novel energy-efficient approach which uses an oxygen-enhanced anodic reaction is examined.

  3. Quasi-periodic quantum dot arrays produced by electrochemical synthesis

    SciTech Connect (OSTI)

    Bandyopadhyay, S.; Miller, A.E.; Yue, D.F.; Banerjee, G.; Ricker, R.E.; Jones, S.; Eastman, J.A.; Baugher, E.; Chandrasekhar, M.

    1994-06-01

    We discuss a ``gentle`` electrochemical technique for fabricating quasi-periodic quantum dot arrays. The technique exploits a self-organizing phenomenon to produce quasi-periodic arrangement of dots and provides excellent control over dot size and interdot spacing. Unlike conventional nanolithography, it does not cause radiation damage to the structures during exposure to pattern delineating beams (e-beam, ion-beam or x-ray). Moreover, it does not require harsh processing steps like reactive ion etching, offers a minimum feature size of {approximately}40 {angstrom}, allows the fabrication of structures on nonplanar surfaces (e.g. spherical or cylindrical substrates), is amenable to mass production (millions of wafers can be processed simultaneously) and is potentially orders of magnitude cheaper than conventional nanofabrication. In this paper, we describe our initial results and show the promise of this technique for low-cost and high-yield nanosynthesis.

  4. Method of electrode fabrication for solid oxide electrochemical cells

    DOE Patents [OSTI]

    Jensen, Russell R. (Murrysville, PA)

    1990-01-01

    A process for fabricating cermet electrodes for solid oxide electrochemical cells by sintering is disclosed. First, a porous metal electrode is fabricated on a solid oxide cell, such as a fuel cell by, for example, sintering, and is then infiltrated with a high volume fraction stabilized zirconia suspension. A second sintering step is used to sinter the infiltrated zirconia to a high density in order to more securely attach the electrode to the solid oxide electrolyte of the cell. High performance fuel electrodes can be obtained with this process. Further electrode performance enhancement may be achieved if stabilized zirconia doped with cerium oxide, chromium oxide, titanium oxide, and/or praseodymium oxide for electronic conduction is used.

  5. Method of electrode fabrication for solid oxide electrochemical cells

    DOE Patents [OSTI]

    Jensen, R.R.

    1990-11-20

    A process for fabricating cermet electrodes for solid oxide electrochemical cells by sintering is disclosed. First, a porous metal electrode is fabricated on a solid oxide cell, such as a fuel cell by, for example, sintering, and is then infiltrated with a high volume fraction stabilized zirconia suspension. A second sintering step is used to sinter the infiltrated zirconia to a high density in order to more securely attach the electrode to the solid oxide electrolyte of the cell. High performance fuel electrodes can be obtained with this process. Further electrode performance enhancement may be achieved if stabilized zirconia doped with cerium oxide, chromium oxide, titanium oxide, and/or praseodymium oxide for electronic conduction is used. 5 figs.

  6. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Brian, Riley (Willimantic, CT); Szreders, Bernard E. (Oakdale, CT)

    1989-01-01

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  7. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Riley, B.; Szreders, B.E.

    1988-04-26

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  8. Separator-spacer for electrochemical systems

    DOE Patents [OSTI]

    Grimes, Patrick G. (Westfield, NJ); Einstein, Harry (Springfield, NJ); Newby, Kenneth R. (Berkeley Heights, NJ); Bellows, Richard J. (Westfield, NJ)

    1983-08-02

    An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.

  9. Minimizing electrode contamination in an electrochemical cell

    DOE Patents [OSTI]

    Kim, Yu Seung; Zelenay, Piotr; Johnston, Christina

    2014-12-09

    An electrochemical cell assembly that is expected to prevent or at least minimize electrode contamination includes one or more getters that trap a component or components leached from a first electrode and prevents or at least minimizes them from contaminating a second electrode.

  10. Method of constructing an improved electrochemical cell

    DOE Patents [OSTI]

    Grimes, Patrick G. (Westfield, NJ); Einstein, Harry (Springfield, NJ)

    1984-10-09

    An electrochemical cell construction features a novel co-extruded plastic electrode in an interleaved construction with a novel integral separator-spacer. Also featured is a leak and impact resistant construction for preventing the spill of corrosive materials in the event of rupture.

  11. BioElectrochemically Assisted Microbial Reactor

    E-Print Network [OSTI]

    Lee, Dongwon

    microbial fuel cell-based technologies. Bruce Logan and John M. Regan Hydrogen Energy CenterBioElectrochemically Assisted Microbial Reactor (BEAMR) The BEAMR reactor uses only >0.2 V needed/mol) expected Energy recovery from acetate: 5x the energy in electricity used recovered as H2 (heat

  12. Characterization of electrochemically modified polycrystalline platinum surfaces

    SciTech Connect (OSTI)

    Krebs, L.C.; Ishida, Takanobu

    1991-12-01

    The characterization of electrochemically modified polycrystalline platinum surfaces has been accomplished through the use of four major electrochemical techniques. These were chronoamperometry, chronopotentiommetry, cyclic voltammetry, and linear sweep voltammetry. A systematic study on the under-potential deposition of several transition metals has been performed. The most interesting of these were: Ag, Cu, Cd, and Pb. It was determined, by subjecting the platinum electrode surface to a single potential scan between {minus}0.24 and +1.25 V{sub SCE} while stirring the solution, that the electrocatalytic activity would be regenerated. As a consequence of this study, a much simpler method for producing ultra high purity water from acidic permanganate has been developed. This method results in water that surpasses the water produced by pyrocatalytic distillation. It has also been seen that the wettability of polycrystalline platinum surfaces is greatly dependent on the quantity of oxide present. Oxide-free platinum is hydrophobic and gives a contact angle in the range of 55 to 62 degrees. We have also modified polycrystalline platinum surface with the electrically conducting polymer poly-{rho}-phenylene. This polymer is very stable in dilute sulfuric acid solutions, even under applied oxidative potentials. It is also highly resistant to electrochemical hydrogenation. The wettability of the polymer modified platinum surface is severely dependent on the choice of supporting electrolyte chosen for the electrochemical polymerization. Tetraethylammonium tetrafluoroborate produces a film that is as hydrophobic as Teflon, whereas tetraethylammonium perchlorate produces a film that is more hydrophilic than oxide-free platinum.

  13. Energy Savings in Refrigerated Walk-In Boxes

    SciTech Connect (OSTI)

    Webster, Tom

    1998-06-01

    The purpose of this technical brief is to provide an overview of the results of an assessment of a technique for saving energy in refrigerated walk-in coolers, and to evaluate the potential for this technology in Federal facilities. The focus of this study was on a single manufacturer of the technology, Nevada Energy Control Systems, Inc. (Necsi); no other vendors for this technology could be found. Previous studies were inconclusive about the overall efficacy of this technique due to uncertainties in a number of areas. [1] Previous evaluations also lacked the benefit of the results from recent manufacturer sponsored tests and did not address some fundamental issues about the overall efficacy of this technology that are critical to understanding its potential. The primary objective of this assessment was to determine if the previous studies combined with recent vendor sponsored test results substantiate the manufacturer's claims that this is a cost effective energy saving technique with significant potential in Federal facilities. Secondary objectives included evaluation of intangible benefits such as equipment life and reliability issues, and humidity and airflow effects on product.

  14. ETME 422 -REFRIGERATION & HVAC SYSTEMS FALL 2011 LEC -10:00 -10:50am M W F RH 312

    E-Print Network [OSTI]

    Dyer, Bill

    , fans, compressors, heat exchangers, heaters, refrigerators, etc.) of heating, ventilation, air Load - Introduction HVAC Systems Comfort and Health Solar Radiation Radiant Time Series Method Moist

  15. Comment submitted by the Air Conditioning, Heating and Refrigeration Institute (AHRI) regarding the Energy Star Verification Testing Program

    Office of Energy Efficiency and Renewable Energy (EERE)

    This document is a comment submitted by the Air Conditioning, Heating and Refrigeration Institute (AHRI) regarding the Energy Star Verification Testing Program

  16. Investigation of the suppression effect of polyethylene glycol on copper electroplating by electrochemical impedance spectroscopy

    SciTech Connect (OSTI)

    Hung, C.-C.; Lee, W.-H.; Wang, Y.-L.; Chan, D.-Y.; Hwang, G.-J. [Department of Electrical Engineering, National Cheng Kung University, Tainan 701, Taiwan (China); Department of Electrical Engineering, National Chiayi University, Chiayi, Taiwan (China); College of Science and Engineering, National University of Tainan, Tainan 700, Taiwan (China)

    2008-09-15

    Polyethylene glycol (PEG) is an additive that is commonly used as a suppressor in the semiconductor copper (Cu)-electroplating process. In this study, electrochemical impedance spectroscopy (EIS) was used to analyze the electrochemical behavior of PEG in the Cu-electroplating process. Polarization analysis, cyclic-voltammetry stripping, and cell voltage versus plating time were examined to clarify the suppression behavior of PEG. The equivalent circuit simulated from the EIS data shows that PEG inhibited the Cu-electroplating rate by increasing the charge-transfer resistance as well as the resistance of the adsorption layer. The presence of a large inductance demonstrated the strong adsorption of cuprous-PEG-chloride complexes on the Cu surface during the Cu-electroplating process. Increasing the PEG concentration appears to increase the resistances of charge transfer, the adsorption layer, and the inductance of the electroplating system.

  17. Manufacturing Energy and Carbon Footprint - Sector: All Manufacturing...

    Broader source: Energy.gov (indexed) [DOE]

    1,403 3,988 731 193 18 14,064 4,589 2,430 39 46 438 Conventional Boilers 2,441 CHP Cogeneration Nonprocess Energy Process Cooling and Refrigeration Electro-Chemical Other Process...

  18. ARTI Refrigerant Database. [Quarterly progress report, 1 July 1993--30 September 1993

    SciTech Connect (OSTI)

    Calm, J.M.

    1993-11-28

    The Refrigerant Database consolidates and facilitates access to information to assist industry in developing equipment using alternative refrigerants. The underlying purpose is to accelerate phase out of chemical compounds of environmental concern. The database provides bibliographic citations and abstracts for publications that may be useful in research and design of air-conditioning and refrigeration equipment. The complete documents are not included, though some may be added at a later date. The database identifies sources of specific information on R-32, R-123, R-124, R-125, R-134, R134a, R-141b, R-142b, R-143a, R-152a, R-227ea, R-245ca, R-290 (propane), R-717 (ammonia), ethers, and others as well as azeotropic and zeotropic blends of these fluids. It addresses lubricants including alkylbenzene, polyalkylene glycol, polyol ester, and other synthetics as well as mineral oils. It also references documents addressing compatibility of refrigerants and lubricants with metals, plastics, elastomers, motor insulation, and other materials used in refrigerant circuits. Incomplete citations or abstracts are provided for some documents. They are included to accelerate availability of the information and will be completed or replaced in future updates.

  19. Evaluation of EHD enhancement and thermoacoustic refrigeration for naval applications. Technical report, Jul-Sep 91

    SciTech Connect (OSTI)

    Memory, S.B.

    1991-12-01

    An evaluation has been made of two different techniques which could prove valuable for Naval refrigeration needs in the future. The first is electrohydrodynamic (EHD) enhancement of pool boiling and condensation heat transfer; this has been shown to provide significant enhancements for both modes of heat transfer under certain conditions and could provide increases in efficiency of present vapor-compression systems. EHD techniques are quite advanced and prototype condenser and evaporator bundles are currently being tested. The second technique is an alternative refrigeration technology called thermoacoustic refrigeration; alternative technologies have become increasingly attractive over recent years due to environmental concerns over CFCs. Thermoacoustic refrigeration uses acoustic power to pump heat from a low temperature source to a high temperature sink. It is still in the early stages of development and can presently accommodate only small thermal loads. However, its general principles of operation have been proven and its resent capacity and efficiency limitations are not seen as a problem in the long term. Electrohydrodynamic Enhancement, Boiling and Condensation, Thermoacoustic Refrigeration.

  20. Battery paste compositions and electrochemical cells for use therewith

    DOE Patents [OSTI]

    Olson, J.B.

    1999-02-16

    An improved battery paste composition and a lead-acid electrochemical cell which incorporates the composition are disclosed. The cell includes a positive current collector and a negative current collector which are each coated with a paste containing one or more lead-containing compositions and a paste vehicle to form a positive plate and a negative plate. An absorbent electrolyte-containing separator member may also be positioned between the positive and negative plates. The paste on the positive current collector, the negative current collector, or both further includes a special additive consisting of polyvinyl sulfonic acid or salts thereof which provides many benefits including improved battery cycle life, increased charge capacity, and enhanced overall stability. The additive also makes the pastes smoother and more adhesive, thereby improving the paste application process. The paste compositions of interest may be used in conventional flat-plate cells or in spirally wound batteries with equal effectiveness. 2 figs.