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1

Soil washing treatability study  

SciTech Connect

Soil washing was identified as a viable treatment process option for remediating soil at the FEMP Environmental Management Project (FEMP). Little information relative to the specific application and potential effectiveness of the soil washing process exists that applies to the types of soil at the FEMP. To properly evaluate this process option in conjunction with the ongoing FEMP Remedial Investigation/Feasibility Study (RI/FS), a treatability testing program was necessary to provide a foundation for a detailed technical evaluation of the viability of the process. In August 1991, efforts were initiated to develop a work plan and experimental design for investigating the effectiveness of soil washing on FEMP soil. In August 1992, the final Treatability Study Work Plan for Operable Unit 5: Soil Washing (DOE 1992) was issued. This document shall be referenced throughout the remainder of this report as the Treatability Study Work Plan (TSWP). The purpose of this treatability study was to generate data to support initial screening and the detailed analysis of alternatives for the Operable Unit 5 FS.

Krstich, M.

1995-12-01T23:59:59.000Z

2

DATA QUALITY OBJECTIVES FOR SELECTING WASTE SAMPLES FOR BENCH-SCALE REFORMER TREATABILITY STUDIES  

SciTech Connect

This document describes the data quality objectives to select archived samples located at the 222-S Laboratory for Bench-Scale Reforming testing. The type, quantity, and quality of the data required to select the samples for Fluid Bed Steam Reformer testing are discussed. In order to maximize the efficiency and minimize the time to treat Hanford tank waste in the Waste Treatment and Immobilization Plant, additional treatment processes may be required. One of the potential treatment processes is the fluidized bed steam reformer. A determination of the adequacy of the fluidized bed steam reformer process to treat Hanford tank waste is required. The initial step in determining the adequacy of the fluidized bed steam reformer process is to select archived waste samples from the 222-S Laboratory that will be used in a bench scale tests. Analyses of the selected samples will be required to confirm the samples meet the shipping requirements and for comparison to the bench scale reformer (BSR) test sample selection requirements.

BANNING DL

2011-02-11T23:59:59.000Z

3

Hanford Site Annual Treatability Studies Report, Calendar Year 2002  

SciTech Connect

This report provides information required to be reported annually by the Washington Administrative Code (WAC) 173-303-071 (3)(r)(ii)(F) and (3)(s)(ix) on the treatability studies conducted on the Hanford Site in 2002. These studies were conducted as required by WAC 173-303-071, “Excluded Categories of Waste,” sections (3)(r) and (s). Unless otherwise noted, the waste samples were provided by and the treatability studies were performed for the U.S. Department of Energy, Richland Operations Office, P.O. Box 550, Richland, Washington 99352. The U.S. Environmental Protection Agency identification number for these studies is WA7890008967.

Grohs, Eugene L.

2003-02-28T23:59:59.000Z

4

Treatability studies on different refinery wastewater samples using high-throughput microbial electrolysis cells (MECs)  

E-Print Network (OSTI)

, 2005), brewery (Feng et al., 2008), animal (Min et al., 2005) and paper recycling wastewaters (HuangTreatability studies on different refinery wastewater samples using high-throughput microbial, University Park, PA 16802, USA h i g h l i g h t s Refinery wastewaters were tested as fuels in MECs

5

Survey of commercial firms with mixed-waste treatability study capability  

SciTech Connect

According to the data developed for the Proposed Site Treatment Plans, the US Department of Energy (DOE) mixed low-level and mixed transuranic waste inventory was estimated at 230,000 m{sup 3} and embodied in approximately 2,000 waste streams. Many of these streams are unique and may require new technologies to facilitate compliance with Resource Conservation and Recovery Act disposal requirements. Because most waste streams are unique, a demonstration of the selected technologies is justified. Evaluation of commercially available or innovative technologies in a treatability study is a cost-effective method of providing a demonstration of the technology and supporting decisions on technology selection. This paper summarizes a document being prepared by the Mixed Waste Focus Area of the DOE Office of Science and Technology (EM-50). The document will provide DOE waste managers with a list of commercial firms (and universities) that have mixed-waste treatability study capabilities and with the specifics regarding the technologies available at those facilities. In addition, the document will provide a short summary of key points of the relevant regulations affecting treatability studies and will compile recommendations for successfully conducting an off-site treatability study. Interim results of the supplier survey are tabulated in this paper. The tabulation demonstrates that treatment technologies in 17 of the US Environmental Protection Agency`s technology categories are available at commercial facilities. These technologies include straightforward application of standard technologies, such as pyrolysis, as well as proprietary technologies developed specifically for mixed waste. The paper also discusses the key points of the management of commercial mixed-waste treatability studies.

McFee, J.; McNeel, K.; Eaton, D. [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States); Kimmel, R. [Dept. of Energy, Idaho Falls, ID (United States). Idaho Operations Office

1996-04-01T23:59:59.000Z

6

Treatability studies for uranium and plutonium contaminated soils using physical separation methods. Environmental Assessment  

SciTech Connect

The Nevada Field Office of the Department of Energy (DOE/NV) has stated in the Environmental Restoration and Waste Management (ERWM) Site Specific Plan for the Nevada Test Site (NTS) that DOE/NV is committed to achieving compliance with all applicable environmental laws, regulations, guidelines, and agreements covering operations at the NTS. The primary DOE/NV objective identified by the Site-Specific Plan is to comply with all laws and regulations aimed at protecting human health and the environment. These include Nevada statutes and regulations which may be applicable, including federally delegated authorities. This environmental assessment discusses limited bench-scale soil treatability testing of physical processes for decontamination of plutonium- and uranium-contaminated soil. The proposed location of these studies would be the Treatability Testing Facility (TTF), Building 3124 at Test Cell ``All in Area 25 of the NTS.

none,

1992-07-01T23:59:59.000Z

7

Operable Unit 7-13/14 in situ thermal desorption treatability study work plan  

SciTech Connect

This Work Plan provides technical details for conducting a treatability study that will evaluate the application of in situ thermal desorption (ISTD) to landfill waste at the Subsurface Disposal Area (SDA) at the Idaho National Engineering and Environmental Laboratory (INEEL). ISTD is a form of thermally enhanced vapor vacuum extraction that heats contaminated soil and waste underground to raise its temperature and thereby vaporize and destroy most organics. An aboveground vapor vacuum collection and treatment system then destroys or absorbs the remaining organics and vents carbon dioxide and water to the atmosphere. The technology is a byproduct of an advanced oil-well thermal extraction program. The purpose of the ISTD treatability study is to fill performance-based data gaps relative to off-gas system performance, administrative feasibility, effects of the treatment on radioactive contaminants, worker safety during mobilization and demobilization, and effects of landfill type waste on the process (time to remediate, subsidence potential, underground fires, etc.). By performing this treatability study, uncertainties associated with ISTD as a selected remedy will be reduced, providing a better foundation of remedial recommendations and ultimate selection of remedial actions for the SDA.

Shaw, P.; Nickelson, D.; Hyde, R.

1999-05-01T23:59:59.000Z

8

Final waste forms project: Performance criteria for phase I treatability studies  

SciTech Connect

This document defines the product performance criteria to be used in Phase I of the Final Waste Forms Project. In Phase I, treatability studies will be performed to provide {open_quotes}proof-of-principle{close_quotes} data to establish the viability of stabilization/solidification (S/S) technologies. This information is required by March 1995. In Phase II, further treatability studies, some at the pilot scale, will be performed to provide sufficient data to allow treatment alternatives identified in Phase I to be more fully developed and evaluated, as well as to reduce performance uncertainties for those methods chosen to treat a specific waste. Three main factors influence the development and selection of an optimum waste form formulation and hence affect selection of performance criteria. These factors are regulatory, process-specific, and site-specific waste form standards or requirements. Clearly, the optimum waste form formulation will require consideration of performance criteria constraints from each of the three categories. Phase I will focus only on the regulatory criteria. These criteria may be considered the minimum criteria for an acceptable waste form. In other words, a S/S technology is considered viable only if it meet applicable regulatory criteria. The criteria to be utilized in the Phase I treatability studies were primarily taken from Environmental Protection Agency regulations addressed in 40 CFR 260 through 265 and 268; and Nuclear Regulatory Commission regulations addressed in 10 CFR 61. Thus the majority of the identified criteria are independent of waste form matrix composition (i.e., applicable to cement, glass, organic binders etc.).

Gilliam, T.M. [Oak Ridge National Lab., TN (United States); Hutchins, D.A. [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States); Chodak, P. III [Massachusetts Institute of Technology (United States)

1994-06-01T23:59:59.000Z

9

TREATABILITY STUDIES USED TO TEST FOR EXOTHERMIC REACTIONS OF PLUTONIUM DECONTAMINATION CHEMICALS  

SciTech Connect

Fluor Hanford is decommissioning the Plutonium Finishing Plant (PFP) at the Hanford site in Eastern Washington. Aggressive chemicals are commonly used to remove transuranic contaminants from process equipment to allow disposal as low level waste. Chemicals being considered for decontamination of gloveboxes in PFP include cerium(IV) nitrate in a nitric acid solution, and proprietary commercial solutions that include acids, degreasers, and sequestering agents. Fluor's decontamination procedure involves application of chemical solutions as a spray on the contaminated surfaces, followed by a wipe-down with rags. This process effectively transfers the transuranic materials to the decontamination liquids, which are then absorbed by rags and packaged for disposal as TRU waste. Concerns regarding the safety of this procedure developed following a fire at Rocky Flats in 2003. The fire occurred in a glovebox that had been treated with cerium nitrate, which is one of the decontamination chemicals that Fluor Hanford has proposed to use. The investigation of the event was hampered by the copious use of chemicals and water to extinguish the fire, and was not conclusive regarding the cause. However, the reviewers noted that rags were found in the glovebox, suggesting that the combination of rags and chemicals may have contributed to the fire. With that uncertainty, Fluor began an investigation into the potential for fire when using the chemicals and materials in the decontamination process. The focus of this work has been to develop a disposal strategy that will provide a chemically stable waste form at expected Hanford waste storage temperatures. Treatability tests under CERCLA were used to assess the use of certain chemicals and wipes during the decontamination process. Chemicals being considered for decontamination of gloveboxes at PFP include cerium (IV) nitrate in a nitric acid solution, and proprietary commercial solutions as RadPro{trademark} that include acids, degreasers, and sequestering agents. As part of the treatability study, Fluor and the Pacific Northwest National Laboratory (PNNL) personnel have evaluated the potential for self-heating and exothermic reactions in the residual decontamination materials. Exothermic reactions that release significant heat and off-gas have been discovered for both the cerium nitrate, as seen in a fire at Rocky Flats, and proprietary solutions developed for decontamination purposes. From the treatability studies, certain limiting conditions have been defined that will aid in assuring safe operations and waste packaging during the decommissioning process.

EWALT, J.R.

2005-06-06T23:59:59.000Z

10

Steam reformer study proposed by Battelle  

Science Journals Connector (OSTI)

Steam reformer study proposed by Battelle ... At a meeting held at Battelle's Columbus, Ohio, laboratories, D. B. Roach told representatives of 24 firms involved in various aspects of steam reforming that, though production of hydrogen through steam reforming has been a highly successful process, "increased plant size and more severe operating conditions have given rise to serious problems." ...

1969-01-13T23:59:59.000Z

11

Treatability studies of actual listed waste sludges from the Oak Ridge Reservation (ORR)  

SciTech Connect

Oak Ridge National Laboratory (ORNL) and Savannah River Technology Center (SRTC) are investigating vitrification for various low-level and mixed wastes on the Oak Ridge Reservation (ORR). Treatability studies have included surrogate waste formulations at the laboratory-, pilot-, and field-scales and actual waste testing at the laboratory- and pilot-scales. The initial waste to be processing through SRTC`s Transportable Vitrification System (TVS) is the K-1407-B and K-1407-C (B/C) Pond sludge waste which is a RCRA F-listed waste. The B/C ponds at the ORR K-25 site were used as holding and settling ponds for various waste water treatment streams. Laboratory-, pilot-, and field- scale ``proof-of-principle`` demonstrations are providing needed operating parameters for the planned field-scale demonstration with actual B/C Pond sludge waste at ORR. This report discusses the applied systems approach to optimize glass compositions for this particular waste stream through laboratory-, pilot-, and field-scale studies with surrogate and actual B/C waste. These glass compositions will maximize glass durability and waste loading while optimizing melt properties which affect melter operation, such as melt viscosity and melter refractory corrosion. Maximum waste loadings minimize storage volume of the final waste form translating into considerable cost savings.

Jantzen, C.M.; Peeler, D.K. [Westinghouse Savannah River Co., Aiken, SC (United States); Gilliam, T.M.; Bleier, A.; Spence, R.D. [Oak Ridge National Lab., TN (United States)

1996-05-06T23:59:59.000Z

12

Treatability study of Tank E-3-1 waste: mixed waste stream SR-W049  

SciTech Connect

Treatability studies were conducted for tank E-3-1 waste which was previously characterized in WSRC-RP-87-0078. The waste was determined to be mixed waste because it displayed the characteristic of metal toxicity for Hg and Cr and was also contaminated with low levels of radionuclides. Two types of treatments for qualifying this waste suitable for land disposal were evaluated: ion exchange and stabilization with hydraulic materials (portland cement, slag and magnesium phosphate cement). These treatments were selected for testing because: (1) Both treatments can be carried out as in-drum processes., (2) Cement stabilization is the RCRA/LDR best developed available technology (BDAT) for Hg (less than 280 mg/L) and for Cr., and (3) Ion exchange via Mag-Sep is a promising alternative technology for in drum treatment of liquid wastes displaying metal toxicity. Cement stabilization of the E-3-1 material ( supernate and settled solids) resulted in waste forms which passed the TCLP test for both Hg and Cr. However, the ion exchange resins tested were ineffective in removing the Hg from this waste stream. Consequently, cement stabilization is recommended for a treatment of the five drums of the actual waste.

Langton, C.A. [Westinghouse Savannah River Company, AIKEN, SC (United States)

1997-08-21T23:59:59.000Z

13

Comparative case studies of health reform in England  

E-Print Network (OSTI)

Comparative case studies of health reform in England Report submitted to the Department of Health........................................................................................14 1.1 Presenting the Health System Reform policy agenda...................................14 1 ..........................................................................................64 Demand Side Reform.........................................

Birmingham, University of

14

300-FF-1 operable unit remedial investigation phase II report: Physical separation of soils treatability study  

SciTech Connect

This report describes the approach and results of physical separations treatability tests conducted at the Hanford Site in the North Process Pond of the 300-FF-1 Operable Unit. Physical separation of soils was identified as a remediation alternative due to the potential to significantly reduce the amount of contaminated soils prior to disposal. Tests were conducted using a system developed at Hanford consisting of modified EPA equipment integrated with screens, hoppers, conveyors, tanks, and pumps from the Hanford Site. The treatability tests discussed in this report consisted of four parts, in which an estimated 84 tons of soil was processed: (1) a pre-test run to set up the system and adjust system parameters for soils to be processed; (2) a baseline run to establish the performance of the system - Test No. 1; (3) a final run in which the system was modified as a result of findings from the baseline run - Test No. 2; and (4) water treatment.

Not Available

1994-04-01T23:59:59.000Z

15

THE USE OF A TREATABILITY STUDY TO INVESTIGATE THE POTENTIAL FOR SELF HEATING & EXOTHERMIC REACTIONS IN DECONTAMINATION MATERIALS AT PFP  

SciTech Connect

Cerium Nitrate has been proposed for use in the decontamination of plutonium contaminated equipment at the Plutonium Finishing Plant (PFP) located on the Hanford Nuclear Reservation in eastern Washington. A Treatability Study was conducted to determine the validity of this decontamination technology in terms of meeting its performance goals and to understand the risks associated with the use of Cerium Nitrate under the conditions found at the PFP. Fluor Hanford is beginning the decommissioning of the PFP at the Hanford site. Aggressive chemicals are commonly used to remove transuranic contaminants from process equipment to allow disposal as low level waste. Chemicals being considered for decontamination of gloveboxes in PFP include cerium (IV) nitrate in a nitric acid solution, and proprietary commercial solutions that include acids, degreasers, and sequestering agents. Fluor's decontamination procedure involves application of the chemicals, followed by a wipe-down of the contaminated surfaces with rags. This process effectively transfers the decontamination liquids containing the transuranic materials to the rags, which can then be readily packaged for disposal as TRU waste. As part of a treatability study, Fluor Hanford and the Pacific Northwest National Laboratory (PNNL) have evaluated the potential for self-heating and exothermic reactions in the residual decontamination materials and the waste packages. Laboratory analyses and thermal-hydraulic modeling reveal a significant self-heating risk for cerium nitrate solutions when used with cotton rags. Exothermic reactions that release significant heat and off-gas have been discovered for cerium nitrate at higher temperatures. From these studies, limiting conditions have been defined to assure safe operations and waste packaging.

HOPKINS, A.M.

2005-02-23T23:59:59.000Z

16

100 area excavation treatability test plan  

SciTech Connect

This test plan documents the requirements for a treatability study on field radionuclide analysis and dust control techniques. These systems will be used during remedial actions involving excavation. The data from this treatability study will be used to support the feasibility study (FS) process. Development and screening of remedial alternatives for the 100 Area, using existing data, have been completed and are documented in the 100 Area Feasibility Study, Phases 1 and 2 (DOE-RL 1992a). Based on the results of the FS, the Treatability Study Program Plan (DOE-RL 1992b) identifies and prioritizes treatability studies for the 100 Area. The data from the treatability study program support future focused FS, interim remedial measures (IRM) selection, operable unit final remedy selection, remedial design, and remedial actions. Excavation is one of the high-priority, near-term, treatability study needs identified in the program plan (DOE-RL 1992b). Excavation of contaminated soils and buried solid wastes is included in several of the alternatives identified in the 100 Area FS. Although a common activity, excavation has only been used occasionally at the Hanford Site for waste removal applications.

Not Available

1993-05-01T23:59:59.000Z

17

Treatability Study Operational Testing Program and Implementation Plan for the Gunite and Associated Tanks at the Oak Ridge National Laboratory, Oak Ridge, Tennessee  

SciTech Connect

To support future decision making of the Gunite and Associated Tanks (GAAT) Operable Unit (OU) remedy selection, the Department of Energy (DOE) is performing a Treatability Study (TS), consistent with the EPA guidance for Comprehensive Environmental Response, compensation, and Liability Act (CERCLA) treatability studies. The study will inform stakeholders about various waste removal technologies and the cost of potential remediation approaches, particularly the cost associated with sluicing and the reduction in risk to human health and the environment from tank content removal. As part of the GAAT OU remedy, a series of studies and technology tests will be preformed. These may address one or more of the following areas, characterization, removal, treatment, and transfer of wastes stored in the GAAT OU.

NONE

1996-09-01T23:59:59.000Z

18

Phase 1 report on the Bear Creek Valley treatability study, Oak Ridge Y-12 Plant, Oak Ridge, Tennessee  

SciTech Connect

Bear Creek Valley (BCV) is located within the US Department of Energy (DOE) Oak Ridge Reservation and encompasses multiple waste units containing hazardous and radioactive wastes associated with past operations at the adjacent Oak Ridge Y-12 Plant. The BCV Remedial Investigation determined that disposal of wastes at the S-3 Site, Boneyard/Burnyard (BYBY), and Bear Creek Burial Grounds (BCBG) has caused contamination of both deep and shallow groundwater. The primary contaminants include uranium, nitrate, and VOCs, although other metals such as aluminum, magnesium, and cadmium persist. The BCV feasibility study will describe several remedial options for this area, including both in situ and ex situ treatment of groundwater. This Treatability Study Phase 1 Report describes the results of preliminary screening of treatment technologies that may be applied within BCV. Four activities were undertaken in Phase 1: field characterization, laboratory screening of potential sorbents, laboratory testing of zero valent iron products, and field screening of three biological treatment systems. Each of these activities is described fully in technical memos attached in Appendices A through G.

NONE

1997-04-01T23:59:59.000Z

19

Treatability Study of In Situ Technologies for Remediation of Hexavalent Chromium in Groundwater at the Puchack Well Field Superfund Site, New Jersey  

SciTech Connect

This treatability study was conducted by Pacific Northwest National Laboratory (PNNL), at the request of the U. S. Environmental Protection Agency (EPA) Region 2, to evaluate the feasibility of using in situ treatment technologies for chromate reduction and immobilization at the Puchack Well Field Superfund Site in Pennsauken Township, New Jersey. In addition to in situ reductive treatments, which included the evaluation of both abiotic and biotic reduction of Puchack aquifer sediments, natural attenuation mechanisms were evaluated (i.e., chromate adsorption and reduction). Chromate exhibited typical anionic adsorption behavior, with greater adsorption at lower pH, at lower chromate concentration, and at lower concentrations of other competing anions. In particular, sulfate (at 50 mg/L) suppressed chromate adsorption by up to 50%. Chromate adsorption was not influenced by inorganic colloids.

Vermeul, Vince R.; Szecsody, Jim E.; Truex, Michael J.; Burns, Carolyn A.; Girvin, Donald C.; Phillips, Jerry L.; Devary, Brooks J.; Fischer, Ashley E.; Li, Shu-Mei W.

2006-11-13T23:59:59.000Z

20

A Comparative Study between Co and Rh for Steam Reforming of...  

NLE Websites -- All DOE Office Websites (Extended Search)

between Co and Rh for Steam Reforming of Ethanol. A Comparative Study between Co and Rh for Steam Reforming of Ethanol. Abstract: Rh and Co-based catalyst performance was compared...

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Quality Assurance Project Plan for the treatability study of in situ vitrification of Seepage Pit 1 in Waste Area Grouping 7 at Oak Ridge National Laboratory  

SciTech Connect

This Quality Assurance Project Plan (QAPjP) establishes the quality assurance procedures and requirements to be implemented for the control of quality-related activities for Phase 3 of the Treatability Study (TS) of In Situ Vitrification (ISV) of Seepage Pit 1, ORNL Waste Area Grouping 7. This QAPjP supplements the Quality Assurance Plan for Oak Ridge National Laboratory Environmental Restoration Program by providing information specific to the ISV-TS. Phase 3 of the TS involves the actual ISV melt operations and posttest monitoring of Pit 1 and vicinity. Previously, Phase 1 activities were completed, which involved determining the boundaries of Pit 1, using driven rods and pipes and mapping the distribution of radioactivity using logging tools within the pipes. Phase 2 involved sampling the contents, both liquid and solids, in and around seepage Pit 1 to determine their chemical and radionuclide composition and the spatial distribution of these attributes. A separate QAPjP was developed for each phase of the project. A readiness review of the Phase 3 activities presented QAPjP will be conducted prior to initiating field activities, and an Operational Acceptance, Test (OAT) will also be conducted with no contamination involved. After, the OAT is complete, the ISV process will be restarted, and the melt will be allowed to increase with depth and incorporate the radionuclide contamination at the bottom of Pit 1. Upon completion of melt 1, the equipment will be shut down and mobilized to an adjacent location at which melt 2 will commence.

NONE

1995-07-01T23:59:59.000Z

22

Treatability study operational testing program and implementation plan for the Gunite and Associated Tanks at Oak Ridge National Laboratory, Oak Ridge, Tennessee  

SciTech Connect

This Treatability Study (TS) Operational Testing Program and Implementation Plan identifies operational testing to be performed to: (1) Demonstrate the technical feasibility of methods proposed for the removal of radiochemical sludge heels from the underground storage tanks located at Oak Ridge National Laboratory (ORNL), known as the Gunite and Associated Tanks (GAAT) Operable Unit (OU). (The bulk of the radiochemical waste, which was previously stored in the tanks, was removed during the 1980s, and only a sludge heel remains.) (2) Reduce the uncertainty in meeting the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) requirements for the GAAT OU. (3) Minimize the overall costs to accomplish the first two objectives. An initial Feasibility Study (FS) effort identified uncertainties in the evaluation of various alternatives for addressing the remediation of the GAAT OU. To support future decision making, the US. Department of Energy is performing a TS to identify cost-effective remediation approaches for the GAAT OU by providing information to reduce cost and technical uncertainty and better define acceptable remediation strategies. The testing activities will be initially conducted in a nonradioactive environment at the Tanks Technology Cold Test Facility (TTCTF) at ORNL. This will permit the design and initial performance testing and training activities to be completed while minimizing the risk, employee exposure, and costs associated with the testing effort. The component design and functional testing and initial system performance testing will be completed in the TTCTF. After the component and initial system performance testing have been completed, the operations testing will continue in the North Tank Farm (NTF). This testing has an associated higher cost and risk, but is necessary to provide results for actual waste heel removal.

NONE

1996-03-01T23:59:59.000Z

23

100 Area excavation treatability test plan. Revision 1  

SciTech Connect

This test plan documents the requirements for a treatability study on field radionuclide analysis and dust control techniques. These systems will be used during remedial actions involving excavation. The data from this treatability study will be used to support the feasibility study (FS) process. Excavation is one of the high-priority, near-term, treatability study needs identified in the program plan (DOE-RL 1992f). Excavation of contaminated soils and buried solid wastes is included in several of the alternatives identified in the 100 Area FS. Although a common activity, excavation has only been used occasionally at the Hanford Site for waste removal applications. The most recent applications are excavation of the 618-9 burial ground and partial remediation of the 316-5 process trenches (DOE-RL 1992a, 1992b). Both projects included excavation of soil and dust control (using water sprays). Excavation is a well-developed technology and equipment is readily available; however, certain aspects of the excavation process require testing before use in full-scale operations. These include the following: Measurement and control of excavation-generated dust and airborne contamination; verification of field analytical system capabilities; demonstration of soil removal techniques specific to the 100 Area waste site types and configurations. The execution of this treatability test may produce up to 500 yd{sub 3} of contaminated soil, which will be used for future treatability tests. These tests may include soil washing with vitrification of the soil washing residuals. Other tests will be conducted if soil washing is not a viable alternative.

Not Available

1993-08-01T23:59:59.000Z

24

Experimental Study on Gasoline Reforming Assisted by Nonthermal Arc Discharge  

Science Journals Connector (OSTI)

The gasoline conversion efficiency decreased when the electric discharge regime was changing from continuous to gliding arc and from gliding to streamer. ... Compared with catalytic reformers, plasma devices have so far lower performances, which is explained by the early stage of research on nonthermal plasma reforming and the need of an external energy input (electricity). ... and design of the plasma reactor, composed of two gliding arc discharges in series, were detailed. ...

Jean-Damien Rollier; José Gonzalez-Aguilar; Guillaume Petitpas; Adeline Darmon; Laurent Fulcheri; Rudolf Metkemeijer

2007-12-06T23:59:59.000Z

25

Evaporative oxidation treatability test report  

SciTech Connect

In 1992, Congress passed the Federal Facilities Compliance Act that requires the U.S. Department of Energy (DOE) to treat and dispose of its mixed waste in accordance with the Resource Conservation and Recovery Act (RCRA) land disposal restrictions (LDRs). In response to the need for mixed-waste treatment capacity where available off-site commercial treatment facilities do not exist or cannot be used, the DOE Albuquerque Operations Office (DOE-AL) organized a Treatment Selection Team to match mixed wastes with treatment options and develop a strategy for treatment of its mixed wastes. DOE-AL manages operations at nine sites with mixed-waste inventories. The Treatment Selection Team determined a need to develop mobile treatment capacity to treat wastes at the sites where the wastes are generated. Treatment processes used for mixed waste not only must address the hazardous component (i.e., meet LDRs) but also must contain the radioactive component in a form that allows final disposal while protecting workers, the public, and the environment. On the basis of recommendations of the Treatment Selection Team, DOE-AL assigned projects to the sites to bring mixed-waste treatment capacity on-line. The three technologies assigned to the DOE Grand Junction Projects Office (GJPO) are evaporative oxidation, thermal desorption, and treated wastewater evaporation. Rust Geotech, the DOE-GJPO prime contractor, was assigned to design and fabricate mobile treatment units (MTUs) for these three technologies and to deliver the MTUs to selected DOE-AL sites. To conduct treatability tests at the GJPO, Rust leased a pilot-scale evaporative oxidation unit from the Clemson Technical Center (CTC), Anderson, South Carolina. The purpose of this report is to document the findings and results of tests performed using this equipment.

NONE

1995-04-01T23:59:59.000Z

26

Catalytic deactivation on methane steam reforming catalysts. 2. Kinetic study  

SciTech Connect

The kinetics of methane steam reforming reaction over an alumina-supported nickel catalyst was investigated at a temperature range of 640-740/sup 0/C in a flow reactor at atmospheric pressure. The experiments were performed varying the inlet concentration of methane, hydrogen, and water. A kinetic scheme of the Houghen-Watson type was satisfactorily proposed assuming the dissociative adsorption of CH/sub 4/ as the rate-limiting step, but this kinetic scheme can be easily replaced by a first-order kinetics (r/sub CH/4/sub / = kapparho/sub CH/4/sub /) for engineering purposes. Catalyst activation with H/sub 2/ and N/sub 2/ mixtures or with the reactant mixture results in the same extent of reaction.

Agnelli, M.E.; Ponzi, E.N.; Yeramian, A.A.

1987-08-01T23:59:59.000Z

27

Sector reform impact on rural drinking water schemes -A case study from Raigad district in Maharashtra  

E-Print Network (OSTI)

- Sector reform impact on rural drinking water schemes - A case study from Raigad district of Technology, Bombay Abstract: This paper analyses the ground level impact of the national rural drinking water policy in Maharashtra. We observe that compared to what is reflected in the national rural drinking water

Sohoni, Milind

28

Studies of mechanisms and kinetics of methane and ethane steam reforming on nickel catalysts  

SciTech Connect

Methane and ethane adsorption/desorption and reaction on steam-reforming catalysts, Ni(INCO), Ni/ZrO{sub 2}, and Ni/CaAl{sub 2}O{sub 4}, were studied by temperature-programmed desorption (TPD), temperature-programmed surface reaction (TPSR), and thermogravimetric (TGA) techniques. The data show that only a fraction of the methane adsorbed (determined by TPSR with H{sub 2}) on nickel catalysts is desorbed during TPD experiments. The results of TPD indicate supports and promoters affect the adsorption of methane and ethane, and transformation of adsorbed carbon species. Several carbon types formed during methane and ethane adsorptions including {alpha}, {beta}, {gamma}, vermicular (v), and graphitic (c) carbon can be identified by TPSR. These data indicate that the distribution of these carbon forms is also strongly a function of adsorption temperature and catalyst. The results show that there are significant quantities of CH{sub 4}, CO, and CO{sub 2} desorbed during TPSR reaction of H{sub 2}O with preadsorbed CH{sub 4}, CD{sub 4} and C{sub 2}H{sub 6}. The agreement between previously reported steady-state and the unsteady-state steam reforming reforming rates of this study indicates that the steam-reforming kinetic data can be quantitatively measured by TPSR experiments.

Hsieh, H.Y.

1988-01-01T23:59:59.000Z

29

DUNCAN PRITCHARD Reforming Reformed Epistemology*  

E-Print Network (OSTI)

DUNCAN PRITCHARD Reforming Reformed Epistemology* 0. Introduction There has been a renaissance-called "reformed" defence of the rationality of reli- gious belief. The starting-point for this reformed conception concern here. Instead, I will be outlining one way in which the reformed epistemological stance can

Edinburgh, University of

30

Reforming Science: Structural Reforms  

Science Journals Connector (OSTI)

...Managing the business of science. Physiology 24 :2-3. 7. Bush V . 1945. Science the endless frontier. U.S. Government Printing Office, Washington, DC. 8. Casadevall...FC Fang. 2012. Reforming science: Methodological and culture...

Ferric C. Fang; Arturo Casadevall

2011-12-19T23:59:59.000Z

31

Experimental and modeling study of catalytic steam reforming of methane mixture with propylene in a packed bed reactor  

Science Journals Connector (OSTI)

Abstract Producer gas from biomass gasification contains mainly hydrogen, carbon dioxide, carbon monoxide, methane and some other low molecular hydrocarbons like propylene. This paper reports mathematical simulation and experimental study of steam reforming of methane mixture with propylene in a packed bed reactor filled with nickel based catalysts. Due to the high heat input through the reformer tube wall and the endothermic reforming reactions, a two-dimensional pseudo-heterogeneous model that takes into account the diffusion reaction phenomena in gas phase as well as inside the catalyst particles has been used to represent temperature distribution and species concentration within the reactor. Steam reforming of propylene is faster and more selective than methane and it is shown that addition of propylene to the methane steam mixture reduces the conversion of methane. The obtained results play a key role in optimization and design of a commercial reactor.

Parham Sadooghi; Reinhard Rauch

2014-01-01T23:59:59.000Z

32

Treatability study for barge cleaning wastes  

E-Print Network (OSTI)

number of crude oil Grab Samples TABLE I. From One Barge Cleaning Company Date pH Chloride Cl COD mg/1 BOD5 mg/1 Total Residue mg/1 Total Suspended Solids mg/1 Volatile Suspended Solids mg/1 9-30-7 2 10- 9-72 12-14-72 1- 5-73 1... 60 18 60 5 (continued) Crab Samples From One Barge Cleaning Company Chloride Cl Total COD BOD Residue mg/1 mg/) mg/1 Total Suspended Solids mg/1 Volatile Suspended Solids mg/1 Average 7. 3 3, 600 3, 760 2, 280 7, 020 62* High 11. 5...

Stryker, Charles Alva

1974-01-01T23:59:59.000Z

33

Quality and Membrane Treatability of the Lake Houston Water Supply  

E-Print Network (OSTI)

TWRI TR-186 Quality and Membrane Treatability of the Lake Houston Water Supply Final Report October 1, 2001 By Shankar Chellam, Ramesh Sharma, Grishma Shetty (all with the University of Houston), and Ying Wei (City of Houston) PUBLISHED BY THE TEXAS... WATER RESOURCES INSTITUE (TWRI) Quality and Membrane Treatability of the Lake Houston Water Supply by Shankar Chellam, Ramesh Sharma, and Grishma Shetty, Civil Engineering Department, the University of Houston, Houston, TX, and Ying Wei, City of Houston...

Chellam, Shankar; Sharma, Ramesh; Shetty, Grishma; Wei, Ying

2001-10-01T23:59:59.000Z

34

Treatability Test Plan for an In Situ Biostimulation Reducing Barrier  

SciTech Connect

This treatability test plan supports a new, integrated strategy to accelerate cleanup of chromium in the Hanford 100 Areas. This plan includes performing a field-scale treatability test for bioreduction of chromate, nitrate, and dissolved oxygen. In addition to remediating a portion of the plume and demonstrating reduction of electron acceptors in the plume, the data from this test will be valuable for designing a full-scale bioremediation system to apply at this and other chromium plumes at Hanford.

Truex, Michael J.; Vermeul, Vince R.; Long, Philip E.; Brockman, Fred J.; Oostrom, Mart; Hubbard, Susan; Borden, Robert C.; Fruchter, Jonathan S.

2007-07-21T23:59:59.000Z

35

Experimental Plan: Uranium Stabilization Through Polyphosphate Injection 300 Area Uranium Plume Treatability Demonstration Project  

SciTech Connect

This Test Plan describes a laboratory-testing program to be performed at Pacific Northwest National Laboratory (PNNL) in support of the 300-FF-5 Feasibility Study (FS). The objective of the proposed treatability test is to evaluate the efficacy of using polyphosphate injections to treat uranium contaminated groundwater in situ. This study will be used to: (1) Develop implementation cost estimates; (2) Identify implementation challenges; and (3) Investigate the technology's ability to meet remedial objectives These activities will be conducted in parallel with a limited field investigation, which is currently underway to more accurately define the vertical extent of uranium in the vadose zone, and in the capillary fringe zone laterally throughout the plume. The treatability test will establish the viability of the method and, along with characterization data from the limited field investigation, will provide the means for determining how best to implement the technology in the field. By conducting the treatability work in parallel with the ongoing Limited Field Investigation, the resulting Feasibility Study (FS) will provide proven, site-specific information for evaluating polyphosphate addition and selecting a suitable remediation strategy for the uranium plume within the FS time frame at an overall cost savings.

Wellman, Dawn M.; Fruchter, Jonathan S.; Vermeul, Vince R.

2006-09-20T23:59:59.000Z

36

The Tablighi Jamaat in Bangladesh and the UK: an ethnographic study of an Islamic reform movement.  

E-Print Network (OSTI)

??Jamaat, a transnational Islamic reform movement, which originated in India in the 1920s. The movement claims to reinforce faith by preaching among Muslims. Tablighi Jamaat… (more)

Siddiqi, Mohammad

2015-01-01T23:59:59.000Z

37

Treatability Test Plan for an In Situ Biostimulation Reducing Barrier  

SciTech Connect

This treatability test plan supports a new, integrated strategy to accelerate cleanup of chromium in the 100 Areas at the Hanford Site. This plan includes performing a field-scale treatability test for bioreduction of chromate, nitrate, and dissolved oxygen. In addition to remediating a portion of the plume and demonstrating reduction of electron acceptors in the plume, the data from this test will be valuable for designing a full-scale bioremediation system to apply at this and other chromium plumes at the Hanford Site.

Truex, Michael J.; Vermeul, Vince R.; Long, Philip E.; Brockman, Fred J.; Oostrom, Mart; Hubbard, Susan; Borden, Robert C.; Fruchter, Jonathan S.

2007-10-26T23:59:59.000Z

38

Kinetic studies of methane steam reforming on ceria-supported Pd  

Science Journals Connector (OSTI)

Steady-state, steam-reforming rates for methane were measured on model and high-surface-...5...and were higher even than rates reported in the literature for Ni catalysts. Model catalysts prepared with Pt or Rh o...

R. Craciun; B. Shereck; R.J. Gorte

39

How Educational Data Mining Empowers State Policies to Reform Education: The Mexican Case Study  

Science Journals Connector (OSTI)

Nowadays, Mexico is living a full transformation in strategic areas such as: education, energy, finances, fiscal, and labor. This ... , the Federal Government has ordered an educational reform. A briefing of the ...

Alejandro Peña-Ayala; Leonor Cárdenas

2014-01-01T23:59:59.000Z

40

A numerical study of the effectiveness factors of nickel catalyst pellets used in steam methane reforming for residential fuel cell applications  

Science Journals Connector (OSTI)

Abstract A numerical study is performed to evaluate the effectiveness factors of commercial nickel catalyst pellets commonly used in small-scale steam methane reformers for residential fuel cell applications. Based on the intrinsic reaction kinetics of the steam reforming process, the standard composition of the partially reformed gas mixture is determined as a function of the methane conversion. The heterogeneous reforming reactions inside the spherical catalyst pellets are then modeled by considering the distributed reaction, multi-component diffusion and permeation, and conductive and convective heat transfer in the porous media. Various operating conditions, including the reforming temperature, steam-to-carbon (S/C) ratio, operating pressure, and geometrical parameters, such as the pellet diameter and mean pore size, are simulated. The effectiveness factors calculated for each condition are presented as a function of the methane conversion. Finally, simple correlations for the effectiveness factors are presented, and their accuracies are assessed.

Seung Man Baek; Jung Ho Kang; Kyu-Jin Lee; Jin Hyun Nam

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Hanford Apatite Treatability Test Report Errata: Apatite Mass Loading Calculation  

SciTech Connect

The objective of this errata report is to document an error in the apatite loading (i.e., treatment capacity) estimate reported in previous apatite treatability test reports and provide additional calculation details for estimating apatite loading and barrier longevity. The apatite treatability test final report (PNNL-19572; Vermeul et al. 2010) documents the results of the first field-scale evaluation of the injectable apatite PRB technology. The apatite loading value in units of milligram-apatite per gram-sediment is incorrect in this and some other previous reports. The apatite loading in units of milligram phosphate per gram-sediment, however, is correct, and this is the unit used for comparison to field core sample measurements.

Szecsody, James E.; Vermeul, Vincent R.; Williams, Mark D.; Truex, Michael J.

2014-05-19T23:59:59.000Z

42

A comprehensive energy–exergy-based assessment and parametric study of a hydrogen production process using steam glycerol reforming  

Science Journals Connector (OSTI)

Abstract Various assessment tools are applied to comprehensively investigate a glycerol-to-hydrogen production system. These tools investigate the chemical reactions, design and simulate the entire hydrogen production process, study the energetic and exergetic performances and perform parametric analyses (using intuitive and design of experiment-based methods). Investigating the chemical reaction of steam glycerol reforming reveals that the optimal conditions, determined based on maximizing the hydrogen production while minimizing the methane and carbon monoxide contents and coke formation, can be achieved at a reforming temperature and a water-to-glycerol feed ratio (WGFR) of 950 K and 9, respectively. The thermal and exergetic efficiencies of the resulting process are 66.6% and 59.9%, respectively. These findings are lower than those cited in the literature and relative to other reformates (methane, ethanol and methanol). The parametric investigation indicates that the performance of the process (energetic and exergetic) could be ensured by using an appropriate and judiciously selected combination of the reactor temperature and WGFR. Based on the parametric energetic and exergetic investigation, WGFR = 6 and T = 1100 K appear to be the most accurate parameters for the entire glycerol-to-hydrogen process. For this recommend configuration, the thermal and exergetic efficiencies are 78.1% and 66.1%, respectively.

Noureddine Hajjaji; Amna Chahbani; Zouhour Khila; Marie-Noëlle Pons

2014-01-01T23:59:59.000Z

43

Studies of potassium-promoted nickel catalysts for methane steam reforming: Effect of surface potassium location  

Science Journals Connector (OSTI)

Abstract The effect of potassium addition to the Ni/Al2O3 steam reforming catalyst has been investigated on several model systems, including K/Al2O3 with various amounts of alkali promoters (1–4 wt% of K2O), a model catalyst 90%NiO-10%Al2O3 promoted with potassium and a commercial catalyst. The potassium surface state and stability were investigated by means of the Species Resolved Thermal Alkali Desorption method (SR-TAD). The activity of the catalysts in the steam reforming of methane and their coking-resistance were also evaluated. The results reveal that the beneficial effect of potassium addition is strongly related to its location in the catalysts. The catalyst surface should be promoted with potassium in order to obtain high coking-resistant catalysts. Moreover, the catalyst preparation procedure should ensure a direct interaction of potassium with the Al2O3 support surface. Due to the low stability of potassium on ?-Al2O3 this phase is undesirable during the preparation of a stable steam reforming catalyst.

Tadeusz Borowiecki; Andrzej Denis; Micha? Rawski; Andrzej Go??biowski; Kazimierz Sto?ecki; Jaromir Dmytrzyk; Andrzej Kotarba

2014-01-01T23:59:59.000Z

44

A study of the deactivation of low loading Ni/Al2O3 steam reforming catalyst by tetrahydrothiophene  

Science Journals Connector (OSTI)

Abstract The steam reforming (SR) of ethanol/phenol mixture (168 gTOT/N m3, ethanol:phenol 2:1 mol, GHSV = 54,000 h? 1), assumed as a model for tar mixtures, has been studied over a 5% Ni/Al2O3 catalyst (155 m2/g), in the presence and in the absence of 210 ppm tetrahydrothiophene (THT) as a sulphur containing contaminant. The sulphidation of the catalyst by THT has been studied by IR spectroscopy. Infrared spectra of CO adsorbed at low temperature over the oxidized, the reduced and the sulphurized catalyst have also been recorded. The catalyst acts as a bifunctional one, with the behaviour attributed to the uncovered support (alumina modified by nickel ions) at 773 K (dehydration of ethanol to ethylene, dehydrogenation to acetaldehyde and alkylation of phenol with ethanol) that fully disappears at 973 K when steam reforming occurs very selectively. By lowering back the reaction temperature, the support behaviour reappears. THT poisons selectively the Ni component, thus causing the appearance of the support behaviour also at 973 K. IR experiments show that THT deposes sulphur at the catalyst surface with the production of gas-phase 1,3-butadiene, thus converting the catalyst into a “sulphided” SR-inactive state. The steam reforming activity of the poisoned catalyst progressively reappears upon feeding back S-free feed at 973 K. IR study suggests that steam “cleans” the catalyst surface by sulphur, generating a “disordered” surface with dispersed Ni2 + and Ni0 species, that could slowly re-approach the initial active state.

Gabriella Garbarino; Alvaro Romero Perez; Elisabetta Finocchio; Guido Busca

2013-01-01T23:59:59.000Z

45

Annual report of tank waste treatability  

SciTech Connect

This report has been prepared as part of the Hanford Federal Facility Agreement and Consent Order* (Tri-Party Agreement) and constitutes completion of Tri-Party Agreement milestone M-04-00D for fiscal year 1993. This report provides a summary of treatment activities for newly generated waste, existing double-shell tank waste, and existing single-shell tank waste, as well as a summary of grout disposal feasibility, glass disposal feasibility, alternate methods for disposal, and safety issues which may impact the treatment and disposal of existing defense nuclear wastes. This report is an update of the 1992 report and is intended to provide traceability for the documentation by statusing the studies, activities, and issues which occurred in these areas listed above over the period of March 1, 1992, through February 28, 1993. Therefore, ongoing studies, activities, and issues which were documented in the previous (1992) report are addressed in this (1993) report.

Lane, A.G. [Los Alamos Technical Associates, Inc., NM (United States); Kirkbride, R.A. [Westinghouse Hanford Co., Richland, WA (United States)

1993-09-01T23:59:59.000Z

46

Annual report of tank waste treatability  

SciTech Connect

This report has been prepared as part of the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) and constitutes completion of Tri-Party Agreement Milestone M-04-00 for fiscal year 1991. This report provides a summary of treatment activities for newly generated waste, existing double-shell tank waste, and existing single-shell tank waste, as well as a summary of grout disposal feasibility, glass disposal feasibility, alternate methods of disposal, and safety issues which may impact the treatment and disposal of existing defense nuclear wastes. This report is an update of the 1990 report and is intended to provide traceability for the documentation of the areas listed above by statusing the studies, activities, and issues which occurred in these areas over the period of March 1, 1990, through February 28, 1991. Therefore, ongoing studies, activities, and issues which were documented in the previous (1990) report are addressed in this subsequent (1991) report. 40 refs., 4 figs., 3 tabs.

Giese, K.A.

1991-09-01T23:59:59.000Z

47

100 Area Hanford soil washing treatability tests  

SciTech Connect

Soil washing laboratory tests performed at Hanford in support of 100 Area Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) feasibility studies included characterization of soils, physical separation, chemical extraction, and water treatment. Results to date show that < 20 % of the soil is finer than 0.25 mm ({minus}40 mesh). The highest concentration of {sup 60}Co, {sup 152}Eu, and {sup 137}Cs contaminants is generally associated with fine soil particles. However, measurable concentrations of contaminants were found in all sizes of soil particles. In initial testing, attrition scrubbing was generally sufficient to treat soils to meet selected performance levels for {sup 60}Co and {sup 152}Eu. However, more intense attrition scrubbing, autogenous grinding, or chemical extraction was required to enhance removal of {sup 137}Cs. Additional tests and assessment of the feasibility of using soil washing techniques are in progress.

Field, J.G.; Belden, R.D. [Westinghouse Hanford Co., Richland, WA (United States); Serne, R.J.; Mattigod, S.V.; Freeman, H.D. [Pacific Northwest Lab., Richland, WA (United States); Scheck, R.W. [Mactec/Dames and Moore (United States); Goller, E.D. [USDOE Richland Operations Office, WA (United States)

1993-09-01T23:59:59.000Z

48

Annual report of tank waste treatability  

SciTech Connect

This report has been prepared as part of the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) and constitutes completion of Tri-Party Agreement milestone M-04-00C for fiscal year 1992. This report provides a summary of treatment activities for newly generated waste, existing double-shell tank waste, and existing single-shell tank waste, as well as a summary of grout disposal feasibility, glass disposal feasibility, alternate methods for disposal, and safety issues which may impact the treatment and disposal of existing defense nuclear wastes. This report is an update of the 1991 report and is intended to provide traceability for the documentation of the areas listed above by statusing the studies, activities, and issues which occurred in these areas over the period of March 1, 1991, through February 29, 1992.

Barker, S.A. (Westinghouse Hanford Co., Richland, WA (United States)); Lane, A.G. (Los Alamos Technical Associates, Inc., NM (United States))

1992-09-01T23:59:59.000Z

49

Hanford 100-D Area Biostimulation Treatability Test Results  

SciTech Connect

Pacific Northwest National Laboratory conducted a treatability test designed to demonstrate that in situ biostimulation can be applied to help meet cleanup goals in the Hanford Site 100-D Area. In situ biostimulation has been extensively researched and applied for aquifer remediation over the last 20 years for various contaminants. In situ biostimulation, in the context of this project, is the process of amending an aquifer with a substrate that induces growth and/or activity of indigenous bacteria for the purpose of inducing a desired reaction. For application at the 100-D Area, the purpose of biostimulation is to induce reduction of chromate, nitrate, and oxygen to remove these compounds from the groundwater. The in situ biostimulation technology is intended to provide supplemental treatment upgradient of the In Situ Redox Manipulation (ISRM) barrier previously installed in the Hanford 100-D Area and thereby increase the longevity of the ISRM barrier. Substrates for the treatability test were selected to provide information about two general approaches for establishing and maintaining an in situ permeable reactive barrier based on biological reactions, i.e., a biobarrier. These approaches included 1) use of a soluble (miscible) substrate that is relatively easy to distribute over a large areal extent, is inexpensive, and is expected to have moderate longevity; and 2) use of an immiscible substrate that can be distributed over a reasonable areal extent at a moderate cost and is expected to have increased longevity.

Truex, Michael J.; Vermeul, Vincent R.; Fritz, Brad G.; Mackley, Rob D.; Mendoza, Donaldo P.; Elmore, Rebecca P.; Mitroshkov, Alexandre V.; Sklarew, Deborah S.; Johnson, Christian D.; Oostrom, Martinus; Newcomer, Darrell R.; Brockman, Fred J.; Bilskis, Christina L.; Hubbard, Susan S.; Peterson, John E.; Williams, Kenneth H.; Gasperikova, E.; Ajo-Franklin, J.

2009-09-30T23:59:59.000Z

50

Treatability Test Plan for 300 Area Uranium Stabilization through Polyphosphate Injection  

SciTech Connect

The U.S. Department of Energy has initiated a study into possible options for stabilizing uranium at the 300 Area using polyphosphate injection. As part of this effort, PNNL will perform bench- and field-scale treatability testing designed to evaluate the efficacy of using polyphosphate injections to reduced uranium concentrations in the groundwater to meet drinking water standards (30 ug/L) in situ. This technology works by forming phosphate minerals (autunite and apatite) in the aquifer that directly sequester the existing aqueous uranium in autunite minerals and precipitates apatite minerals for sorption and long term treatment of uranium migrating into the treatment zone, thus reducing current and future aqueous uranium concentrations. Polyphosphate injection was selected for testing based on technology screening as part of the 300-FF-5 Phase III Feasibility Study for treatment of uranium in the 300-Area.

Vermeul, Vincent R.; Williams, Mark D.; Fritz, Brad G.; Mackley, Rob D.; Mendoza, Donaldo P.; Newcomer, Darrell R.; Rockhold, Mark L.; Williams, Bruce A.; Wellman, Dawn M.

2007-06-01T23:59:59.000Z

51

Direct Internal Reformation and Mass Transport in the Solid Oxide Fuel Cell Anode: A Pore-Scale Lattice Boltzmann Study with Detailed Reaction Kinetics  

SciTech Connect

The solid oxide fuel cell (SOFC) allows the conversion of chemical energy that is stored in a given fuel, including light hydrocarbons, to electrical power. Hydrocarbon fuels, such as methane, are logistically favourable and provide high energy densities. However, the use of these fuels often results in a decreased efficiency and life. An improved understanding of the reactive flow in the SOFC anode can help address these issues. In this study, the transport and heterogeneous internal reformation of a methane based fuel is addressed. The effect of the SOFC anode's complex structure on transport and reactions is shown to exhibit a complicated interplay between the local molar concentrations and the anode structure. Strong coupling between the phenomenological microstructures and local reformation reaction rates are recognised in this study, suggesting the extension to actual microstructures may provide new insights into the reformation processes.

Grew, Kyle N.; Joshi, Abhijit S.; Chiu, W. K. S.

2010-01-01T23:59:59.000Z

52

Methane-steam reforming  

SciTech Connect

A discussion covers steam reforming developments to the 1950's; the kinetics of methane-steam reforming, of the water-gas shift during methane-steam reforming, and of the carbon formation during methane-steam reforming, as approached by Akers and Camp.

Van Hook, J.P.

1980-01-01T23:59:59.000Z

53

Experimental Research on Low-Temperature Methane Steam Reforming Technology in a Chemically Recuperated Gas Turbine  

Science Journals Connector (OSTI)

Under the operating parameters of a chemically recuperated gas turbine (CRGT), the low-temperature methane steam reforming test bench is designed and built; systematic experimental studies about fuel steam reforming are conducted. Four different reforming ...

Qian Liu; Hongtao Zheng

2014-09-24T23:59:59.000Z

54

Combined Steam Reforming of Methane and Fischer–Tropsch Synthesis for the Formation of Hydrocarbons: A Proof of Concept Study  

Science Journals Connector (OSTI)

The concept of combining the reactions of methane steam reforming and the Fischer–Tropsch synthesis is explored in an attempt to convert methane directly to hydrocarbons. Consideration of the thermodynamics ... c...

Meleri Johns; Paul Collier; Michael S. Spencer; Tony Alderson…

2003-10-01T23:59:59.000Z

55

A study of land reform and its impact in the Greater Letaba Local Municipality of the Mopani District in the Limpopo Province.  

E-Print Network (OSTI)

??Since the dawn of democracy in South Africa, numerous land reform projects have been approved by the Minister of Rural Development and Land Reform. This… (more)

Malahlela, Tebogo.

2015-01-01T23:59:59.000Z

56

Selecting activated carbon for water and wastewater treatability studies  

SciTech Connect

A series of follow-up investigations were performed to produce data for improving the four-indicator carbon selection method that we developed to identify high-potential activated carbons effective for removing specific organic water pollutants. The carbon's pore structure and surface chemistry are dependent on the raw material and the activation process. Coconut carbons have relatively more small pores than large pores; coal and apricot nutshell/walnut shell fruit carbons have the desirable pore structures for removing adsorbates of all sizes. Chemical activation, excessive activation, and/or thermal reactivation enlarge small pores, resulting in reduced phenol number and higher tannic acid number. Activated carbon's phenol, iodine, methylene blue, and tannic acid numbers are convenient indicators of its surface area and pore volume of pore diameters < 10, 10-15, 15-28, and > 28 angstrom, respectively. The phenol number of a carbon is also a good indicator of its surface acidity of oxygen-containing organic functional groups that affect the adsorptive capacity for aromatic and other small polar organics. The tannic acid number is an indicator of carbon's capacity for large, high-molecular-weight natural organic precursors of disinfection by-products in water treatment. The experimental results for removing nitrobenzene, methyl-tert-butyl ether, 4,4-bisphenol, humic acid, and the organic constituents of a biologically treated coking-plant effluent have demonstrated the effectiveness of this capacity-indicator-based method of carbon selection.

Zhang, W.; Chang, Q.G.; Liu, W.D.; Li, B.J.; Jiang, W.X.; Fu, L.J.; Ying, W.C. [East China University of Chemical Technology, Shanghai (China)

2007-10-15T23:59:59.000Z

57

Reformate Cleanup: The Case for Microchannel Architecture  

E-Print Network (OSTI)

Reformate Cleanup: The Case for Microchannel Architecture DOE Hydrogen and Fuel Cells 2003 Annual for MicrochannelMicrochannel ArchitectureArchitecture DOE Hydrogen and Fuel CellsDOE Hydrogen and Fuel Cells 2003, controls Integrated reformer/fuel cell demonstration at ~2 kWeFY 2002 WGS/PROX catalyst studies

58

Process and Pattern in Institutional Reforms: A Case Study of the Police Pacifying Units (UPPs) in Brazil  

Science Journals Connector (OSTI)

Summary This paper explores the importance of processes in institutional change and the relationship between processes and patterns of change. Using an ongoing case of police reform in Rio de Janeiro, the police pacification units (Unidades de Polícia Pacificadora) as an illustration, we develop two claims. First, the concept of reflective planning, developed by urban planning scholars, may help development scholars understand processes of institutional change. Second, some patterns, such as the institutional bypass, when combined with particular processes, such as reflective planning, may reinforce each other and further the objectives of reform processes.

Graham Denyer Willis; Mariana Mota Prado

2014-01-01T23:59:59.000Z

59

Supported metal catalysts for alcohol/sugar alcohol steam reforming  

SciTech Connect

Despite extensive studies on hydrogen production via steam reforming of alcohols and sugar alcohols, catalysts typically suffer a variety of issues from poor hydrogen selectivity to rapid deactivation. Here, we summarize recent advances in fundamental understanding of functionality and structure of catalysts for alcohol/sugar alcohol steam reforming, and provide perspectives on further development required to design highly efficient steam reforming catalysts.

Davidson, Stephen; Zhang, He; Sun, Junming; Wang, Yong

2014-08-21T23:59:59.000Z

60

WHEN DOES FINANCIAL SECTOR (IN)STABILITY INDUCE FINANCIAL REFORMS?  

E-Print Network (OSTI)

WHEN DOES FINANCIAL SECTOR (IN)STABILITY INDUCE FINANCIAL REFORMS? Susie LEE Ingmar SCHUMACHER (in)stability induce financial reforms? Susie Lee1 Ingmar Schumacher2 October 26, 2011 Abstract The article studies whether financial sector (in)stability had an effect on reforms in the fi- nancial sector

Boyer, Edmond

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Safety and Security Directives Reform  

NLE Websites -- All DOE Office Websites (Extended Search)

Reforming a "Mountain" of Policy Reforming a "Mountain" of Policy Beginning with his confirmation hearings in January 2009, Energy Secretary Steven Chu challenged the Department of Energy to take a fresh look at how we conduct business. This challenge provided the opportunity for DOE to put in place the most effective and efficient strategies to accomplish the Department's missions safely and securely. In response to the Secretary's challenge and building on the results of Deputy Secretary Poneman's Safety and Security Reform studies, the Office of Health, Safety and Security (HSS) broadened its directives review activities during 2009. By November 2009 HSS had initiated a disciplined review of all health, safety, and security directives, which included a systematic review of the Department's safety and security regulatory model.

62

Steam reforming analyzed  

SciTech Connect

This paper reports that maximum steam reformer operation without excessive coking reactions requires careful control of thermodynamic and kinetic conditions. Regardless of the syngas-based feedstock composition, carbon formation problems can be avoided while increasing reformer CO or H{sub 2} production. Steam reforming technology is best understood via: Primary steam reformer developments, Kinetics of methane steam reforming, Simulation of an industrial steam/CO{sub 2} reformer, Example conditions (steam/CO{sub 2} reforming), Thermodynamic approach (minimum to steam ratio). Hydrogen and carbon monoxide are two of the most important building blocks in the chemical industry. Hydrogen is mainly used in ammonia and methanol synthesis and petroleum refining. Carbon monoxide is used to produce pains, plastics, foams, pesticides and insecticides, to name a few. Production of H{sub 2} and CO is usually carried out by the following processes: Steam reforming (primary and secondary) of hydrocarbons, Partial oxidation of hydrocarbons, Coal gasification. Coal gasification and partial oxidation do not use catalysts and depend on partial combustion of the feedstock to internally supply reaction heat. Secondary (autothermal) reforming is a type of steam reforming that also uses the heat of partial combustion but afterwards uses a catalyst of promote the production of hydrogen and CO.

Wagner, E.S. (KTI Corp., San Dimas, CA (US)); Froment, G.F. (Ghent Rijksuniversiteit (Belgium))

1992-07-01T23:59:59.000Z

63

Catalytic steam reforming of hydrocarbons  

SciTech Connect

The hot effluent from the catalytic steam reforming of a major portion of a fluid hydrocarbon feed stream in the reformer tubes of a primary reformer, or said effluent after secondary reforming thereof, is mixed with the hot effluent from the catalytic steam reforming of the remaining portion of the feed discharged from the reformer tubes of a primary reformer-exchanger. The combined gas steam is passed on the shell side of the reformer-exchanger countercurrently to the passage of feed in the reformer tubes thereof, thus supplying the heat for the reforming of the portion of the feed passed through the reformer tubes of the reformerexchanger. At least about 2/3 of the hydrocarbon feed stream is passed to the reformer tubes of said primary reformer, heated by radiant heat transfer and/or by contact with combustion gases, at a steam/hydrocarbon mole ratio of about 2-4/1. The remainder of said feed stream is passed to the reformer tubes of said reformer -exchanger at a steam/hydrocarbon mole ratio of about 3-6/1. The reformer shell of the reformer-exchanger is internally insulated by a refractory lining or by use of a double shell with passage of water or a portion of the feed material between the inner and outer shells. There is no significant difference between the pressure inside and outside of the reformer tubes of said primary reformer-exchanger.

Fuderer, A.

1982-06-29T23:59:59.000Z

64

Treatability of PCB-contaminated soils with quicklime (CaO)  

SciTech Connect

The possibility that quicklime (calcium oxide, CaO) can destroy PCBs has received much attention over the past year. Observations at an EPA remediation site, where lime-containing kiln dusts were used for interim stabilization of PCB-containing wastes prompted the EPA to sponsor a small research project to investigate quicklime-PCB interactions. That study reported decreases in PCB content in synthetic, PCB-spiked soil following the application of quicklime and heat. META Environmental, Inc., as a contractor to EPRI, recently completed research designed to evaluate the effectiveness of quicklime for treating PCBs in soil and sand matrices under several reaction conditions, and to examine the underlying dechlorination chemistry involved, if any. Experiments were run with PCB-spiked sand and with actual PCB-contaminated soil. A variety of experimental conditions were employed including tests in open and closed containers, at ambient and elevated temperatures, and over a range of one hour to four days. Granular quicklime, fly ash, and kiln dust were all tested for reaction with PCBs. Early experiments showed that a mixture of sand/quicklime/water at 1:3:1.5 by weight, placed in an insulated container reached a maximum temperature of 216[degree]C. Treatability experiments were subsequently run under controlled heat at room temperature, at 80[degree]C, and at 200[degree]C (following the initial temperature increase which occurs when water is added to quicklime). Little or no loss of PCBs was observed in open or closed containers at ambient or at 800[degree]C over any period of time studied. A significant decrease of PCBs levels was observed only in the high temperature experiments (above 200[degree]C), however the fate of the PCBs in those experiments was not determined. The conditions and the results of the PCB treatment tests are presented in this report, as well as recommendations for further studies.

Mauro, D.; Taylor, B.B. (Meta Environmental, Inc., Watertown, MA (United States))

1992-12-01T23:59:59.000Z

65

Pillars of reform  

Science Journals Connector (OSTI)

... misgivings seem to have reached crisis point. China today is full of new initiatives, reforms and an anti-corruption drive that together aim to set the nation on the right ... to be monumental — if China follows it through. The nation is also right to reform how the Chinese Academy of Sciences supports promising research projects. And perhaps most boldly ...

2014-10-29T23:59:59.000Z

66

Natural Gas Reforming  

Energy.gov (U.S. Department of Energy (DOE))

Natural gas reforming is an advanced and mature production process that builds upon the existing natural gas pipeline delivery infrastructure. Today, 95% of the hydrogen produced in the United States is made by natural gas reforming in large central plants. This technology is an important pathway for near-term hydrogen production.

67

NIH Peer Review Reform  

Science Journals Connector (OSTI)

...EDITOR LETTER TO THE EDITOR NIH Peer Review Reform Marc C. Torjman Phone...Camden, NJ 08103 The editorial NIH Peer Review Reform-Change We Need, or Lipstick...better exposed the problems of grant peer review and, more importantly, the irreparable...

Marc C. Torjman

2009-07-01T23:59:59.000Z

68

Physician payments under health care reform  

Science Journals Connector (OSTI)

Abstract This study examines the impact of major health insurance reform on payments made in the health care sector. We study the prices of services paid to physicians in the privately insured market during the Massachusetts health care reform. The reform increased the number of insured individuals as well as introduced an online marketplace where insurers compete. We estimate that, over the reform period, physician payments increased at least 11 percentage points relative to control areas. Payment increases began around the time legislation passed the House and Senate—the period in which their was a high probability of the bill eventually becoming law. This result is consistent with fixed-duration payment contracts being negotiated in anticipation of future demand and competition.

Abe Dunn; Adam Hale Shapiro

2015-01-01T23:59:59.000Z

69

Pilot-scale treatability test plan for the 200-BP-5 operable unit  

SciTech Connect

This document presents the treatability test plan for pilot-scale pump and treat testing at the 200-BP-5 Operable Unit. This treatability test plan has been prepared in response to an agreement between the U.S. Department of Energy (DOE), the U.S. Environmental Protection Agency (EPA), and the State of Washington Department of Ecology (Ecology), as documented in Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement, Ecology et al. 1989a) Change Control Form M-13-93-03 (Ecology et al. 1994) and a recent 200 NPL Agreement Change Control Form (Appendix A). The agreement also requires that, following completion of the activities described in this test plan, a 200-BP-5 Operable Unit Interim Remedial Measure (IRM) Proposed Plan be developed for use in preparing an Interim Action Record of Decision (ROD). The IRM Proposed Plan will be supported by the results of this treatability test plan, as well as by other 200-BP-5 Operable Unit activities (e.g., development of a qualitative risk assessment). Once issued, the Interim Action ROD will specify the interim action(s) for groundwater contamination at the 200-BP-5 Operable Unit. The treatability test approach is to conduct a pilot-scale pump and treat test for each of the two contaminant plumes associated with the 200-BP-5 Operable Unit. Primary contaminants of concern are {sup 99}Tc and {sup 60}Co for underwater affected by past discharges to the 216-BY Cribs, and {sup 90}Sr, {sup 239/240}Pu, and Cs for groundwater affected by past discharges to the 216-B-5 Reverse Well. The purpose of the pilot-scale treatability testing presented in this testplan is to provide the data basis for preparing an IRM Proposed Plan. To achieve this objective, treatability testing must: Assess the performance of groundwater pumping with respect to the ability to extract a significant amount of the primary contaminant mass present in the two contaminant plumes.

Not Available

1994-08-01T23:59:59.000Z

70

Renewable Liquid Fuels Reforming  

Energy.gov (U.S. Department of Energy (DOE))

The Program anticipates that distributed reforming of biomass-derived liquid fuels could be commercial during the transition to hydrogen and used in the mid- and long-term time frames.

71

NETL - Fuel Reforming Facilities  

ScienceCinema (OSTI)

Research using NETL's Fuel Reforming Facilities explores catalytic issues inherent in fossil-energy related applications, including catalyst synthesis and characterization, reaction kinetics, catalyst activity and selectivity, catalyst deactivation, and stability.

None

2014-06-27T23:59:59.000Z

72

--No Title--  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

A mixed waste treatability study will be performed to test the fluidized bed steam reforming (FBSR) technology on SRS Low Activity Waste (LAW) modified to simulate Hanford waste....

73

Natural Gas Reforming | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hydrogen Production Natural Gas Reforming Natural Gas Reforming Photo of Petroleum Refinery Natural gas reforming is an advanced and mature production process that builds upon...

74

100-NR-2 Apatite Treatability Test FY09 Status: High Concentration Calcium-Citrate-Phosphate Solution Injection for In Situ Strontium-90 Immobilization  

SciTech Connect

100-NR-2 Apatite Treatability Test FY09 Status: High Concentration Calcium-Citrate-Phosphate Solution Injection for In Situ Strontium-90 Immobilization INTERIM LETTER REPORT

Vermeul, Vincent R.; Fritz, Brad G.; Fruchter, Jonathan S.; Szecsody, James E.; Williams, Mark D.

2009-12-16T23:59:59.000Z

75

Studies on the Stability of a La0.8Pr0.2NiAl11O19 Catalyst for Syngas Production by CO2 Reforming of Methane  

Science Journals Connector (OSTI)

CO2 reforming of CH4 was studied over a magnetoplumbite-type hexaaluminate La0.8Pr0.2NiAl11O19 catalyst, which showed very high activity for over 300 h without deactivation at 1023 K. This catalyst showed good re...

Yan Liu; Tiexin Cheng; Dongmei Li; Pengbo Jiang; Junxia Wang…

2003-01-01T23:59:59.000Z

76

Internal tar/CH4 reforming in a biomass dual fluidised bed gasifier  

Science Journals Connector (OSTI)

An internal reformer is developed for in situ catalytic reforming of tar and methane (CH4) in allothermal gasifiers. The study has been performed in the ... 150 kW dual fluidised bed (DFB) biomass gasifier at Mid...

Kristina Göransson; Ulf Söderlind; Till Henschel…

2014-10-01T23:59:59.000Z

77

FOOD REFORM MOVEMENTS Nicolas Larchet  

E-Print Network (OSTI)

FOOD REFORM MOVEMENTS Nicolas Larchet Social historians have broadly defined two cycles of American history characterized by an efflorescence of social movements aiming to reform both the individual to the 1920s. The reform impulse thrived wherever there was a perceived vice, abuse or corruption

Boyer, Edmond

78

Reforming the Private Insurance Market  

E-Print Network (OSTI)

SUMMARY s national health care reform efforts go forward, it is instructive to review states' experience INTRODUCTION he prospects for national health care reform are more promising than at any time since 1994. President Obama and Members of Congress have made health care reform a top priority and legislation

Kammen, Daniel M.

79

Telecommunications reform and efficiency performance: Do good institutions matter?  

Science Journals Connector (OSTI)

Abstract Until recently, most studies investigating telecommunication reforms performance have failed to incorporate the importance of institutions into the empirical analysis. This study highlights the importance of institutional governance on telecommunications efficiency and provides empirical results for the impact of institutions on reform outcomes. It provides significant evidence that the institutional environment in which reform progress takes place is an important determinant for successful reform. This study uses the stochastic distance function approach to capture the role of institutions in explaining efficiency differences across 70 countries. The empirical analysis reveals that policy stability in the form of substantive checks and balances on executive power is the most important aspect for successful reform. Independently, legal integrity improves telecommunications efficiency through privatization, while greater freedom from corruption influences the effectiveness of a regulatory body.

Noorihsan Mohamad

2014-01-01T23:59:59.000Z

80

Borehole Data Package for Nine CY 2006 Polyphosphate Treatability Testing Wells, 300-FF-5 Operable Unit, Hanford Site, Washington  

SciTech Connect

Nine new CERCLA groundwater monitoring wells were installed in the 300-FF-5 Operable Unit in calendar year 2006 to fulfill commitments for the EM-20 funded polyphosphate treatability test. Nine new performance monitoring wells were drilled into the uppermost unconfined aquifer, to the Hanford formation - Ringold Formation contact boundary, and completed within the permeable Hanford fm. unit 1 gravel-dominated sequence. The overall objective of the polyphosphate treatability test is to evaluate the efficacy of using polyphosphate injections to treat 300 Area uranium contaminated groundwater in situ. The objective of this work was to install the performance monitoring network surrounding the existing treatability injection well C5000 (399-1-23) in support of the implementation of a field scale demonstration of the polyphosphate technology.

Williams, Bruce A.

2007-04-12T23:59:59.000Z

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Dry reforming of hydrocarbon feedstocks  

SciTech Connect

Developments in catalyst technology for the dry reforming of hydrocarbon feedstocks are reviewed for methane, higher hydrocarbons and alcohols. Thermodynamics, mechanisms and the kinetics of dry reforming are also reviewed. The literature on Ni catalysts, bi-metallic Ni catalysts and the role of promoters on Ni catalysts is critically evaluated. The use of noble and transitional metal catalysts for dry reforming is discussed. The application of solid oxide and metal carbide catalysts to dry reforming is also evaluated. Finally, various mechanisms for catalyst deactivation are assessed. This review also examines the various process related issues associated with dry reforming such as its application and heat optimization. Novel approaches such as supercritical dry reforming and microwave assisted dry reforming are briefly expanded upon.

Shah, Yatish T. [Norfolk State University; Gardner, Todd H. [U.S. DOE

2014-01-01T23:59:59.000Z

82

200-BP-5 operable unit treatability test report  

SciTech Connect

The 200-BP-5 Operable Unit was established in response to recommendations presented in the 200 East Groundwater Aggregate Area Management Study Report (AAMSR) (DOE-RL 1993a). Recognizing different approaches to remediation, the groundwater AAMSR recommended separating groundwater from source and vadose zone operable units and subdividing 200 East Area groundwater into two operable units. The division between the 200-BP-5 and 200-PO-1 Operable Units was based principally on source operable unit boundaries and distribution of groundwater plumes derived from either B Plant or Plutonium/Uranium Extraction (PUREX) Plant liquid waste disposal sites.

NONE

1996-04-01T23:59:59.000Z

83

DOES HOSPITAL COMPETITION SAVE LIVES? EVIDENCE FROM THE ENGLISH NHS PATIENT CHOICE REFORMS*  

E-Print Network (OSTI)

DOES HOSPITAL COMPETITION SAVE LIVES? EVIDENCE FROM THE ENGLISH NHS PATIENT CHOICE REFORMS* Zack Cooper, Stephen Gibbons, Simon Jones and Alistair McGuire Recent substantive reforms to the English with fixed prices. This study investigates whether these reforms led to improvements in hospital quality. We

Mateo, Jill M.

84

Energy and exergy analysis of an ethanol reforming process for solid oxide fuel cell applications  

Science Journals Connector (OSTI)

Abstract The fuel processor in which hydrogen is produced from fuels is an important unit in a fuel cell system. The aim of this study is to apply a thermodynamic concept to identify a suitable reforming process for an ethanol-fueled solid oxide fuel cell (SOFC). Three different reforming technologies, i.e., steam reforming, partial oxidation and autothermal reforming, are considered. The first and second laws of thermodynamics are employed to determine an energy demand and to describe how efficiently the energy is supplied to the reforming process. Effect of key operating parameters on the distribution of reforming products, such as H2, CO, CO2 and CH4, and the possibility of carbon formation in different ethanol reformings are examined as a function of steam-to-ethanol ratio, oxygen-to-ethanol ratio and temperatures at atmospheric pressure. Energy and exergy analysis are performed to identify the best ethanol reforming process for SOFC applications.

Phanicha Tippawan; Amornchai Arpornwichanop

2014-01-01T23:59:59.000Z

85

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

1999-01-01T23:59:59.000Z

86

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

2001-01-01T23:59:59.000Z

87

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-17T23:59:59.000Z

88

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-24T23:59:59.000Z

89

Methane-steam reforming  

SciTech Connect

The literature relating to the kinetics of methane-steam reforming involving integral and differential reactor data, porous nickel catalysts and nickel foil, and data over large ranges of temperature (500 to 1700/sup 0/F), pressure (0.01 to 50 atm), and intrinsic catalyst activities (200,000-fold) was reviewed. A simple reversible first-order kinetic expression for the steam-methane reaction appears to be applicable throughout the operable region of steam-to-carbon ratios. Internal pore diffusion limitation on the conversion rate, due to catalyst size and/or intrinsic catalyst activity and total operating pressure was underlined. S-shaped Arrhenium plots (changing activation energy) are obtained when steam reforming is conducted over a temperature range sufficient to produce intrinsic kinetics (low temperature, inactive catalyst, or small catalyst size), pore diffusional limitations, and reaction on the outside surface. Homogeneous gas-phase kinetics appear to contribute only at relatively high temperature (1400/sup 0/F). In steam reforming, the water-gas shift reaction departs from its equilibrium position, especially at low methane conversion level. A general correlation of approach to water-gas shift equilibration as a function of conversion level only was indicated. (DP) 18 figures, 6 tables.

Van Hook, J.P.

1980-01-01T23:59:59.000Z

90

Distributed Bio-Oil Reforming  

Energy.gov (U.S. Department of Energy (DOE))

Presentation by NREL's Robert Evans at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

91

Experimental and Modeling Studies of the Methane Steam Reforming Reaction at High Pressure in a Ceramic Membrane Reactor.  

E-Print Network (OSTI)

??This dissertation describes the preparation of a novel inorganic membrane for hydrogen permeation and its application in a membrane reactor for the study of the… (more)

Hacarlioglu, Pelin

2007-01-01T23:59:59.000Z

92

Renewable Hydrogen from Ethanol by Autothermal Reforming  

Science Journals Connector (OSTI)

...soy oil limits its economics. Ethanol is now...desirability of autothermal reforming of ethanol (10...reaction with water in the steam-reforming reaction (1113...partial oxidation with steam reforming and the WGS...

G. A. Deluga; J. R. Salge; L. D. Schmidt; X. E. Verykios

2004-02-13T23:59:59.000Z

93

What's right SHIP & Healthcare Reform Forum  

E-Print Network (OSTI)

&Health Reform What's right for you SHIP & Healthcare Reform Forum: What's Right for You This session will help you: * demystify the healthcare reform changes * explore your options * learn how

Walker, Matthew P.

94

European Islam and reform: a comparative study of the theologies of Yusuf al-Qaradawi and Tariq Ramadan.  

E-Print Network (OSTI)

??This study investigates Yusuf al-Qaradawi’s and Tariq Ramadan’s conceptualizations of European Islam centering on three thematic issues: “European-Muslim” identity and the role of Muslims in… (more)

Haji Mohamad, Mohamad Azmi Bin

2015-01-01T23:59:59.000Z

95

NEPA Contracting Reform Guidance  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

defining early what contractors should accomplish < establishing contracts ahead of time < minimizing cost while maintaining quality by * maximizing competition and use of incentives * using past performance information in awarding work * managing the NEPA process as a project This guidance provides: < model statements of work < information on contract types and incentives < direction on effective NEPA contract management by the NEPA Document Manager < a system for measuring NEPA process costs < NEPA contractor evaluation procedures < details on the DOE NEPA Web site U.S. Department of Energy, Office of NEPA Policy and Assistance, December 1996 NEPA CONTRACTING REFORM GUIDANCE Table of Contents 1. INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

96

Steam reforming process  

SciTech Connect

Methane-containing gases are produced by the catalytic-stream reforming of hydrocarbon feedstocks using a catalyst which includes a group VIII metal such as nickel and alumina, and which in its calcined but unreduced precursor form has a pore size distribution defined as follows: (I) at least 55% of the pore volume of pores having a pore radius between 12 and 120 angstrom units is in the range of 12-30 angstrom units, and (II) the ratio of the pore volume contained in pores of 10-50 a to the pore volume contained in pores 50-300 a is at least 5:1.

Banks, R.G.; Williams, A.

1981-07-28T23:59:59.000Z

97

State of Ni in catalysts for glycerol hydrogenation and methane steam reforming as studied by X-ray absorption spectroscopy  

Science Journals Connector (OSTI)

X-ray absorption spectroscopy is used to study 1% Ni/Al2O3, 5% Ni/Al2O3, and 5% Ni/TiO2 catalysts for glycerol and methane conversion. The effect of treatment in H2 under microwave irradiation on the reduction of...

O. P. Tkachenko; L. M. Kustov

2013-06-01T23:59:59.000Z

98

Carbon deposition in steam reforming and methanation  

SciTech Connect

The purpose of this review is to survey recent studies of carbon deposition on metals used as catalysts in steam reforming and methanation, emphasizing research where significant progress has been made. Where possible, an attempt is made to treat the fundamental nature of carbon formation and deactivation by carbon and the relationships between these two phenomena. Steam reforming and methanation are emphasized in this review because (1) deactivation of catalysts by carbon deposits is a serious concern in both processes, (2) much of the previous research with carbon formation on metals involved one or the other of these two reactions, and (3) there are interesting differences and similarities between these two reactions; for example, methanation is typically carried out at moderate reaction temperatures (200-450/sup 0/C) while steam reforming is typically carried out at significantly higher reaction temperatures (600-900/sup 0/C). Yet the two reactions are very closely related, since methane steam reforming is the reverse of methanation of CO. Moreover, there is evidence that some of the carbons formed in these two different processes are similar in their morphology.

Bartholomew, C.H.

1982-01-01T23:59:59.000Z

99

Experiences of niobium-containing alloys for steam reformers  

SciTech Connect

Destructive testing of niobium alloys was made in steam reformer as well as the study of the effects of the chemical compositions on the creep rupture and tensile properties.

Shibasaki, T.; Takemura, K.; Kawai, T.; Mohri, T.

1987-01-01T23:59:59.000Z

100

ECONOMIC REFORM AND COMMUNIST REGIME SURVIVABILTY: PAST, PRESENT, AND FUTURE  

E-Print Network (OSTI)

of their respective Politburos and may be described as not only ‘surviving’ but thriving, experiencing economic stability and enjoying high rates of growth. This study examines the ramifications of economic and political reform policies implemented by four collapsed...

Nelson, John

2006-08-16T23:59:59.000Z

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

The nuclear heated steam reformer — Design and semitechnical operating experiences  

Science Journals Connector (OSTI)

Good operating experiences of the EVA I- and EVA II-plant have been described. Therin the comparison of the different catalyst concepts has been given. Further the behaviour of the bundle of EVA II plant by isolation of individual reformer tubes as well as the performance of the bundle under transient conditions have been explained. Different design concepts for a nuclear heated steam reformer based on the concentric tubes and baffles have been given. Main points of studies are constructional details, thermohydraulic of the bundle and stress analysis. It can be shown that the present standard of knowledge allows the application of the steam reformer for coal refinement with nuclear heat.

J. Singh; H.F. Niessen; R. Harth; H. Fedders; H. Reutler; W. Panknin; W.D. Müller; H.G. Harms

1984-01-01T23:59:59.000Z

102

Effect of Gas-to-Liquid Diesel Fuels on Combustion Characteristics, Engine Emissions, and Exhaust Gas Fuel Reforming. Comparative Study  

Science Journals Connector (OSTI)

School of Engineering, Mechanical and Manufacturing Engineering, University of Birmingham, Birmingham B15 2TT, U.K., Shell Global Solutions, Cheshire Innovation Park, Chester CH1 3SH, U.K., Mechanical Engineering, School of Engineering and Design, Brunel University, West London, Uxbridge UB8 3PH, U.K., and Johnson Matthey Technology Centre, Blount's Court, Sonning Common, Reading RG4 9NH, U.K. ... Clearly, the general trend is toward higher efficiency engines and improved fuel economy, something that puts current technology spark ignition (SI) engines in a relatively weak position compared to compression ignition (CI) engines. ... As the diesel engine used in this study was equipped with a pump-line-nozzle-type fuel injection system, all the observed effects may not apply to common rail or unit injection equipped engines. ...

A. Abu-Jrai; A. Tsolakis; K. Theinnoi; R. Cracknell; A. Megaritis; M. L. Wyszynski; S. E. Golunski

2006-10-18T23:59:59.000Z

103

Multi-fuel reformers for fuel cells used in transportation. Multi-fuel reformers: Phase 1 -- Final report  

SciTech Connect

DOE has established the goal, through the Fuel Cells in Transportation Program, of fostering the rapid development and commercialization of fuel cells as economic competitors for the internal combustion engine. Central to this goal is a safe feasible means of supplying hydrogen of the required purity to the vehicular fuel cell system. Two basic strategies are being considered: (1) on-board fuel processing whereby alternative fuels such as methanol, ethanol or natural gas stored on the vehicle undergo reformation and subsequent processing to produce hydrogen, and (2) on-board storage of pure hydrogen provided by stationary fuel processing plants. This report analyzes fuel processor technologies, types of fuel and fuel cell options for on-board reformation. As the Phase 1 of a multi-phased program to develop a prototype multi-fuel reformer system for a fuel cell powered vehicle, the objective of this program was to evaluate the feasibility of a multi-fuel reformer concept and to select a reforming technology for further development in the Phase 2 program, with the ultimate goal of integration with a DOE-designated fuel cell and vehicle configuration. The basic reformer processes examined in this study included catalytic steam reforming (SR), non-catalytic partial oxidation (POX) and catalytic partial oxidation (also known as Autothermal Reforming, or ATR). Fuels under consideration in this study included methanol, ethanol, and natural gas. A systematic evaluation of reforming technologies, fuels, and transportation fuel cell applications was conducted for the purpose of selecting a suitable multi-fuel processor for further development and demonstration in a transportation application.

Not Available

1994-05-01T23:59:59.000Z

104

Multipath Curved Planar Reformation of the Peripheral  

E-Print Network (OSTI)

Multipath Curved Planar Reformation of the Peripheral Arterial Tree in CT Angiography1 Justus that cause artifacts in multipath curved planar reformations (MPCPRs) of the peripheral arterial tree in 10-oblique multiplanar reformations perpendicular to the ves- sel centerline (10), and curved planar reformations

105

Toward a Reformalization of QSIM Benjamin Shults  

E-Print Network (OSTI)

Toward a Reformalization of QSIM Benjamin Shults Department of Mathematics University of Texas is to reformalize part of the framework of the Guaranteed Coverage Theorem for QSIM. The intention is not to reformalize every detail of the proof but merely to mention some areas whose reformalization lends deeper

Kuipers, Benjamin

106

Optimization of Multiplanar Reformations from Isotropic  

E-Print Network (OSTI)

Optimization of Multiplanar Reformations from Isotropic Data Sets Acquired with 16­ Detector Row coronal reformations at vari- ous thicknesses were ranked qualitatively by three radiol- ogists. Effective reformations of data acquired in the custom phantom were compared, coronal reformations obtained with the 16

107

Faculty perceptions of presidential leadership in urban school reform  

E-Print Network (OSTI)

FACULTY PERCEPTIONS OF PRESIDENTIAL LEADERSHIP IN URBAN SCHOOL REFORM A Dissertation by RODNEY PRESCOTT McCLENDON Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of DOCTOR OF PHILOSOPHY August 2007 Major Subject: Agricultural Education FACULTY PERCEPTIONS OF PRESIDENTIAL LEADERSHIP IN URBAN SCHOOL REFORM A Dissertation by RODNEY PRESCOTT McCLENDON Submitted...

McClendon, Rodney Prescott

2009-06-02T23:59:59.000Z

108

Study of Co/CeO2-?-Al2O3 catalysts for steam and oxidative reforming of ethanol for hydrogen production  

Science Journals Connector (OSTI)

Abstract Cobalt catalysts supported on ?Al2O3, CeO2 and CeO2-?Al2O3 were prepared by the impregnation method and applied to steam and oxidative reforming of ethanol. The catalysts were characterized by temperature-programmed reduction with H2 (TPR-H2), X-ray diffraction (XRD), N2-physisorption and diffuse reflectance spectroscopy in the ultra-violet visible range (DRS-UV–Vis). Steam reforming of ethanol was carried out at 400 °C, 500 °C and 600 °C with an ethanol/water feed in a molar ratio of 1:3. The oxidative reforming of ethanol was carried out at 500 °C with an ethanol/H2O/O2 feed in molar proportion 1:3:0.20. Analysis of the gaseous products showed that the Co/?Al2O3 and Co/CeO2-?Al2O3 catalysts were highly selective for H2 and CO2, and this was attributed to the high specific surface area of these catalysts. The addition of O2 to the feed improved the hydrogen selectivity and reduced the carbon formation on Co/?Al2O3, which suffered fast deactivation in the SRE reaction at low temperature.

Thaisa A. Maia; José M. Assaf; Elisabete M. Assaf

2014-01-01T23:59:59.000Z

109

Hiring Reform | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hiring Reform Hiring Reform Hiring Reform President Obama's Memorandum dated May 11, 2010, Improving the Federal Recruitment and Hiring Process, is Phase I of the Administration's comprehensive initiative to address major, long-standing impediments to recruiting and hiring the best and the brightest into the Federal civilian workforce. The Memorandum is based on issues that DOE and others brought to the attention of OPM, and it is designed to help Agencies build the workforce you need to achieve your goals. The Presidential Memorandum launches the Obama Administration's flagship personnel policy reform initiative. It builds on a nearly year-long collaboration between OPM and Agencies aimed at streamlining the hiring process and recruiting top talent, especially for mission-critical jobs.

110

Applications of solar reforming technology  

SciTech Connect

Research in recent years has demonstrated the efficient use of solar thermal energy for driving endothermic chemical reforming reactions in which hydrocarbons are reacted to form synthesis gas (syngas). Closed-loop reforming/methanation systems can be used for storage and transport of process heat and for short-term storage for peaking power generation. Open-loop systems can be used for direct fuel production; for production of syngas feedstock for further processing to specialty chemicals and plastics and bulk ammonia, hydrogen, and liquid fuels; and directly for industrial processes such as iron ore reduction. In addition, reforming of organic chemical wastes and hazardous materials can be accomplished using the high-efficiency destruction capabilities of steam reforming. To help identify the most promising areas for future development of this technology, we discuss in this paper the economics and market potential of these applications.

Spiewak, I. [Weizmann Inst. of Science, Rehovoth (Israel); Tyner, C.E. [Sandia National Labs., Albuquerque, NM (United States); Langnickel, U. [Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V. (DLR), Koeln (Germany)

1993-11-01T23:59:59.000Z

111

Treatability test of a stacked-tray air stripper for VOC in water  

SciTech Connect

A common strategy for hydraulic containment and mass removal at VOC contaminated sites is `pump and treat (P&T)`. In P&T operations, contaminated ground water is pumped from wells, treated above ground, and discharged. Many P&T remediation systems at VOC sites rely on air stripping technology because VOCs are easily transferred to the vapor phase. In stacked-tray air strippers, contaminated water is aerated while it flows down through a series of trays. System operations at LLNL are strictly regulated by the California and federal Environmental Protection Agencies (Cal/EPA and EPA), the Bay Area Air Quality Management District (BAAQMD), the California Regional Water Quality Control Board (RWQCB) and the Department of Toxic Substances Control (DTSC). These agencies set discharge limits, require performance monitoring, and assess penalties for non-compliance. National laboratories are also subject to scrutiny by the public and other government agencies. This extensive oversight makes it necessary to accurately predict field treatment performance at new extraction locations to ensure compliance with all requirements prior to facility activation. This paper presents treatability test results for a stacked- tray air stripper conducted at LLNL and compares them to the vendor`s modeling software results.

Pico, T., LLNL

1998-04-01T23:59:59.000Z

112

Syngas production in a novel methane dry reformer by utilizing of tri-reforming process for energy supplying: Modeling and simulation  

Science Journals Connector (OSTI)

Abstract In this study, tri-reforming process has been utilized as an energy source for driving highly endothermic process of methane dry reforming process in a multi-tubular recuperative thermally coupled reactor (TCTDR). 184 two-concentric-tubes have been proposed for this configuration. Outer tube sides of the two-concentric-tubes have been considered for the tri-reforming reactions while dry reforming process takes place in inner tube sides. Simulation results of co-current mode have been compared with corresponding predictions of thermally coupled tri- and steam reformer (TCTSR); in which the tri-reforming process has been coupled with steam reforming of methane in same conditions. A mathematical heterogeneous model has been applied to simulate both dry and tri-reforming sides of the TCTDR. Results showed that methane conversion at the output of dry and tri-reforming sides reached to 63% and 93%, respectively. Also, molar flow rate of syngas at the output of DR side of TCTDR reached to 7464 kmol h?1 in comparison to 3912 kmol h?1 for SR side of TCTSR.

Mehdi Farniaei; Mohsen Abbasi; Hamid Rahnama; Mohammad Reza Rahimpour; Alireza Shariati

2014-01-01T23:59:59.000Z

113

Steam reforming of n-hexane on pellet and monolithic catalyst beds. A comparative study on improvements due to heat transfer  

SciTech Connect

Monolithic catalysts with higher available active surface areas and better thermal conductivity than conventional pellets beds, making possible the steam reforming of fuels heavier than naphtha, were examined. Performance comparisons were made between conventional pellet beds and honeycomb monolith catalysts using n-hexane as the fuel. Metal-supported monoliths were examined. These offer higher structural stability and higher thermal conductivity than ceramic supports. Data from two metal monoliths of different nickel catalyst loadings were compared to pellets under the same operating conditions. Improved heat transfer and better conversion efficiencies were obtained with the monolith having higher catalyst loading. Surface-gas interaction was observed throughout the length of the monoliths.

Not Available

1981-10-01T23:59:59.000Z

114

Recover heat from steam reforming  

SciTech Connect

Steam reforming is one of the most important chemical processes--it is used in the manufacture of ammonia, hydrogen, methanol, and many chemicals made from hydrogen and carbon monoxide. Furthermore, many current trends will increase its importance. For example, methanol for addition to gasoline is likely to be produced by steam reforming. Because steam reforming occurs at high temperatures--typically 750 C--900 C--it generates a large amount of waste heat. Clearly, heat recovery is crucial to process economics. A typical 50,000 Nm[sup 3]/h hydrogen plant using natural gas feed has a radiant heat duty of about 50 MW. At a radiant efficiency of 50% and fuel cost of $3/GJ, this means that the reformer fires $9 million worth of fuel per year. Obviously, this amount of fuel justifies a close loot at ways to reduce costs. This article first provides a brief overview of steam reforming. It then outlines the available heat-recovery options and explains how to select the best method.

Fleshman, J.D. (Foster Wheeler USA Corp., Livingston, NJ (United States))

1993-10-01T23:59:59.000Z

115

Hydrogen Generation Via Fuel Reforming  

Science Journals Connector (OSTI)

Reforming is the conversion of a hydrocarbon based fuel to a gas mixture that contains hydrogen. The H2 that is produced by reforming can then be used to produce electricity via fuel cells. The realization of H2?based power generation via reforming is facilitated by the existence of the liquid fuel and natural gas distribution infrastructures. Coupling these same infrastructures with more portable reforming technology facilitates the realization of fuel cell powered vehicles. The reformer is the first component in a fuel processor. Contaminants in the H2?enriched product stream such as carbon monoxide (CO) and hydrogen sulfide (H2S) can significantly degrade the performance of current polymer electrolyte membrane fuel cells (PEMFC’s). Removal of such contaminants requires extensive processing of the H2?rich product stream prior to utilization by the fuel cell to generate electricity. The remaining components of the fuel processor remove the contaminants in the H2 product stream. For transportation applications the entire fuel processing system must be as small and lightweight as possible to achieve desirable performance requirements. Current efforts at Argonne National Laboratory are focused on catalyst development and reactor engineering of the autothermal processing train for transportation applications.

John F. Krebs

2003-01-01T23:59:59.000Z

116

Pilot-scale treatability test plan for the 100-HR-3 operable unit  

SciTech Connect

This document presents the treatability test plan for pilot-scale pump-and-treat testing at the 100-HR-3 Operable Unit. The test will be conducted in fulfillment of interim Milestone M-15-06E to begin pilot-scale pump-and-treat operations by August 1994. The scope of the test was determined based on the results of lab/bench-scale tests (WHC 1993a) conducted in fulfillment of Milestone M-15-06B. These milestones were established per agreement between the U.S. Department of Energy (DOE), the Washington State Department of Ecology and the U.S. Environmental Protection Agency (EPA), and documented on Hanford Federal of Ecology Facility Agreement and Consent Order Change Control Form M-15-93-02. This test plan discusses a pilot-scale pump-and-treat test for the chromium plume associated with the D Reactor portion of the 100-HR-3 Operable Unit. Data will be collected during the pilot test to assess the effectiveness, operating parameters, and resource needs of the ion exchange (IX) pump-and-treat system. The test will provide information to assess the ability to remove contaminants by extracting groundwater from wells and treating extracted groundwater using IX. Bench-scale tests were conducted previously in which chromium VI was identified as the primary contaminant of concern in the 100-D reactor plume. The DOWEX 21K{trademark} resin was recommended for pilot-scale testing of an IX pump-and-treat system. The bench-scale test demonstrated that the system could remove chromium VI from groundwater to concentrations less than 50 ppb. The test also identified process parameters to monitor during pilot-scale testing. Water will be re-injected into the plume using wells outside the zone of influence and upgradient of the extraction well.

Not Available

1994-08-01T23:59:59.000Z

117

Attrition resistant fluidizable reforming catalyst  

DOE Patents (OSTI)

A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.

Parent, Yves O. (Golden, CO); Magrini, Kim (Golden, CO); Landin, Steven M. (Conifer, CO); Ritland, Marcus A. (Palm Beach Shores, FL)

2011-03-29T23:59:59.000Z

118

SULFUR POLYMER STABILIZATION/SOLIDIFICATION TREATABILITY STUDY OF MERCURY CONTAMINATED SOIL FROM THE Y-12 SITE  

E-Print Network (OSTI)

has cleanup responsibilities on the DOE Oak Ridge Reservation and is investigating potential mercury to support the remediation of the Y-12 site. URS CH2M Oak Ridge LLC (UCOR) under its prime contract with DOE THE Y-12 SITE P. D. Kalb, L. Milian, and S. P. Yim Informal Report Prepared for URS CH2M OAK RIDGE LLC

Johnson, Peter D.

119

E-Print Network 3.0 - annual treatability studies Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

6 Presented at: The 2002 Borchardt Conference, A Seminar on Advancements in Water and Wastewater. The University of Michigan, Ann Arbor, Feb. 2002. Summary: . These critical...

120

Treatability study of industrial waste using sanitary sewage to supply nutrients  

E-Print Network (OSTI)

Ferguson, B. S. , U. S. Merchant Marine Academy Co-Chairmen of Advisory Conmittee: Dr. Harold W. Wolf Dr. Tom D. Reynolds Industrial wastewaters in many instances do not contain suffi- cient nutrients such as nitrogen and phosphorus to permit effective... and phosphorus, which adds to the cost. Sanitary sewage contains these nutrients and, if mixed in proper proportions with petrochemical industrial waste- waters requiring added nutrients, could satisfy the nutrient demand and reduce treatment cost. A limited...

Ferguson, James Ritchie

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
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121

Plasma catalytic reforming of methane  

Science Journals Connector (OSTI)

Thermal plasma technology can be efficiently used in the production of hydrogen and hydrogen-rich gases from methane and a variety of fuels. This article describes progress in plasma reforming experiments and calculations of high temperature conversion of methane using heterogeneous processes. The thermal plasma is a highly energetic state of matter that is characterized by extremely high temperatures (several thousand degrees Celsius), and a high degree of dissociation and a substantial degree of ionization. The high temperatures accelerate the reactions involved in the reforming process. Hydrogen-rich gas (40% H2, 17% CO2 and 33% N2, for partial oxidation/water shifting) can be efficiently made in compact plasma reformers. Experiments have been carried out in a small device (2–3 kW) and without the use of efficient heat regeneration. For partial oxidation/water shifting, it was determined that the specific energy consumption in the plasma reforming processes is 16 MJ/kg H2 with high conversion efficiencies. Larger plasmatrons, better reactor thermal insulation, efficient heat regeneration and improved plasma catalysis could also play a major role in specific energy consumption reduction and increasing the methane conversion. A system has been demonstrated for hydrogen production with low CO content (?1.5%) with power densities of ?30 kW (H2 HHV)/l of reactor, or ?10 m3/h H2 per liter of reactor. Power density should further increase with increased power and improved design.

L Bromberg; D.R Cohn; A Rabinovich; N Alexeev

1999-01-01T23:59:59.000Z

122

NEPA Contracting Reform Guidance | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Contracting Reform Guidance Contracting Reform Guidance NEPA Contracting Reform Guidance This documents provides guidance on NEPA contracting strategy, including: defining the work of the contractor; establishing contracts ahead of time; minimizing cost while maintaining quality. Guidance also provides: model statements of work, direction on NEPA contract management by NEPA Document Manager; a system for measuring NEPA costs and for evaluating contractor procedures; details on the DOE NEPA website. NEPA Contracting Reform Guidance More Documents & Publications NEPA Contracting Reform Guidance (December 1996) Statement of Work-National Environmental Policy Act (NEPA) Support Services Acquisition: Preparation and Review of Environmental Impact Statements, Environmental Assessments, Environmental Reports, and other Environmental

123

Unfunded Mandates Reform Act; Intergovernmental Consultation | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Unfunded Mandates Reform Act; Intergovernmental Consultation Unfunded Mandates Reform Act; Intergovernmental Consultation Unfunded Mandates Reform Act; Intergovernmental Consultation The Department of Energy (DOE) today publishes a final statement of policy on intergovernmental consultation under the Unfunded Mandates Reform Act of 1995. The policy reflects the guidelines and instructions that the Director of the Office of Management and Budget (OMB) provided to each agency to develop, with input from State, local, and tribal officials, an intergovernmental consultation process with regard to significant intergovernmental mandates contained in a notice of proposed rulemaking. Unfunded Mandates Reform Act; Intergovernmental Consultation More Documents & Publications TEC Working Group Topic Groups Tribal Key Documents

124

Unfunded Mandates Reform Act; Intergovernmental Consultation | Department  

NLE Websites -- All DOE Office Websites (Extended Search)

Unfunded Mandates Reform Act; Intergovernmental Consultation Unfunded Mandates Reform Act; Intergovernmental Consultation Unfunded Mandates Reform Act; Intergovernmental Consultation The Department of Energy (DOE) today publishes a final statement of policy on intergovernmental consultation under the Unfunded Mandates Reform Act of 1995. The policy reflects the guidelines and instructions that the Director of the Office of Management and Budget (OMB) provided to each agency to develop, with input from State, local, and tribal officials, an intergovernmental consultation process with regard to significant intergovernmental mandates contained in a notice of proposed rulemaking. Unfunded Mandates Reform Act; Intergovernmental Consultation More Documents & Publications TEC Working Group Topic Groups Tribal Key Documents

125

Hydrocarbon steam reforming using series steam superheaters  

SciTech Connect

In a process for steam reforming of a hydrocarbon gas feedstream wherein: the hydrocarbon gas feedstream is partially reformed at elevated temperatures in indirect heat exchange with hot combustion gases in a direct fired primary reforming furnace provided with a convection section for recovery of excess heat from said combustion gases; and the partially reformed feedstream is then further reformed in the presence of an oxygen-containing gas and steam in a secondary reformer to form a secondary reformer gaseous effluent; the improvement which comprises recovering waste heat from said secondary reformer effluent gas and from said primary reforming combustion products by heating a high pressure saturated steam in a first steam superheating zone by indirect heat exchange with at least a portion of said secondary reformer effluent gas to form a first superheated steam stream; and further heating said first superheated steam in a second steam superheating zone by indirect heat exchange with at least a portion of said primary reformer hot combustion gases for form a second superheated steam stream.

Osman, R. M.

1985-10-08T23:59:59.000Z

126

What Determines the Likelihood of Structural Reforms?  

Science Journals Connector (OSTI)

Abstract We use data for a panel of 60 countries over the period 1980-2005 to investigate the main drivers of the likelihood of structural reforms. We find that: (i) external debt crises are the main trigger of financial and banking reforms; (ii) inflation and banking crises are the key drivers of external capital account reforms; (iii) banking crises also hasten financial reforms; and (iv) economic recessions play an important role in promoting the necessary consensus for financial, capital, banking and trade reforms, especially in the group of OECD-countries. Additionally, we also observe that the degree of globalisation is relevant for financial reforms, in particular in the group of non-OECD countries. Moreover, an increase in the income gap accelerates the implementation of structural reforms, but increased political fragmentation does not seem to have a significant impact.

Luca Agnello; Vitor Castro; João Tovar Jalles; Ricardo M. Sousa

2014-01-01T23:59:59.000Z

127

Electron-induced dry reforming of methane in a temperature-controlled dielectric barrier discharge reactor  

Science Journals Connector (OSTI)

Dry reforming of methane has the potential to reduce the greenhouse gases methane and carbon dioxide and to generate hydrogen-rich syngas. In reforming methane, plasma-assisted reforming processes may have advantages over catalytic processes because they are free from coking and their response time for mobile applications is quick. Although plasma-assisted reforming techniques have seen recent developments, systematic studies that clarify the roles that electron-induced chemistry and thermo-chemistry play are needed for a full understanding of the mechanisms of plasma-assisted reformation. Here, we developed a temperature-controlled coaxial dielectric barrier discharge (DBD) apparatus to investigate the relative importance of electron-induced chemistry and thermo-chemistry in dry reforming of methane. In the tested background temperature range 297–773 K, electron-induced chemistry, as characterized by the physical properties of micro-discharges, was found to govern the conversions of CH4 and CO2, while thermo-chemistry influenced the product selectivities because they were found to depend on the background temperature. Comparisons with results from arc-jet reformation indicated that thermo-chemistry is an efficient conversion method. Our findings may improve designs of plasma-assisted reformers by using relatively hotter plasma sources. However, detailed chemical kinetic studies are needed.

Xuming Zhang; Min Suk Cha

2013-01-01T23:59:59.000Z

128

Plasma catalytic reforming of methane  

SciTech Connect

Thermal plasma technology can be efficiently used in the production of hydrogen and hydrogen-rich gases from methane and a variety of fuels. This paper describes progress in plasma reforming experiments and calculations of high temperature conversion of methane using heterogeneous processes. The thermal plasma is a highly energetic state of matter that is characterized by extremely high temperatures (several thousand degrees Celsius) and high degree of dissociation and substantial degree of ionization. The high temperatures accelerate the reactions involved in the reforming process. Hydrogen-rich gas (50% H{sub 2}, 17% CO and 33% N{sub 2}, for partial oxidation/water shifting) can be efficiently made in compact plasma reformers. Experiments have been carried out in a small device (2--3 kW) and without the use of efficient heat regeneration. For partial oxidation/water shifting, it was determined that the specific energy consumption in the plasma reforming processes is 16 MJ/kg H{sub 2} with high conversion efficiencies. Larger plasmatrons, better reactor thermal insulation, efficient heat regeneration and improved plasma catalysis could also play a major role in specific energy consumption reduction and increasing the methane conversion. A system has been demonstrated for hydrogen production with low CO content ({approximately} 1.5%) with power densities of {approximately} 30 kW (H{sub 2} HHV)/liter of reactor, or {approximately} 10 m{sup 3}/hr H{sub 2} per liter of reactor. Power density should further increase with increased power and improved design.

Bromberg, L.; Cohn, D.R.; Rabinovich, A. [Massachusetts Inst. of Technology, Cambridge, MA (United States). Plasma Science and Fusion Center; Alexeev, N. [Russian Academy of Sciences, Moscow (Russian Federation). Baikov Inst. of Metallurgy

1998-08-01T23:59:59.000Z

129

Activity and structure of perovskites as diesel reforming catalysts for solid oxide fuel cells.  

SciTech Connect

Recent progress in developing perovskite materials as more cost-effective catalysts in autothermal reforming (ATR) of diesel fuel to hydrogen-rich reformate for solid oxide fuel cell (SOFC) application is reported. Perovskite-type metal oxides with B sites partially exchanged by ruthenium were prepared and evaluated under ATR reaction conditions. The hydrogen yield, reforming efficiency, and CO{sub x} selectivity of these catalysts were investigated using diesel surrogate fuel with 50 ppm sulfur. The catalyst performances have approached or exceeded a benchmark, high-cost rhodium-based material. In parallel with the reactivity study, we also investigated the physical properties of B-site doped perovskites and their impact on the reforming performance using various characterization techniques such as BET, X-ray powder diffraction, temperature programmable reduction, scanning electron microscopy, and synchrotron X-ray absorption spectroscopy. We found that ruthenium is highly dispersed into perovskite lattice and its redox behavior is directly associated with reforming activity.

Liu, D.-J.; Krumpelt, M.; Chemical Engineering

2005-01-01T23:59:59.000Z

130

First Generation Indian External Sector Reforms in Context  

E-Print Network (OSTI)

India's first generation external sector reforms are a fascinating case study of emergence from a post-Independence socialist-style economy to the world’s largest free market democracy. Part I of this article reviews the Indian license Raj system...

Bhala, Raj

2013-01-01T23:59:59.000Z

131

Environmental fiscal reform (EFR) | Open Energy Information  

Open Energy Info (EERE)

Environmental fiscal reform (EFR) Environmental fiscal reform (EFR) Jump to: navigation, search Tool Summary Name: Environmental fiscal reform (EFR) Agency/Company /Organization: Global Subsidies Initiative (GSI), International Institute for Sustainable Development (IISD), World Bank Phase: Develop Goals, Prepare a Plan, Develop Finance and Implement Projects Topics: Co-benefits assessment, Finance, Market analysis, Policies/deployment programs References: Environmental fiscal reform - What should be done and how to achieve it[1] Reforming fiscal policies to close the gap between economic and ecological efficiencies[2] Overview "The term environmental fiscal reform (EFR) refers to: a range of taxation or pricing instruments that can raise revenue, while simultaneously furthering environmental goals. This is achieved by providing economic

132

Steam reforming utilizing high activity catalyst  

SciTech Connect

High activity, sulfur tolerant steam reforming catalysts are described comprising rhodium or nickel supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. The catalysts have improved activity over conventionally used catalysts in the presence of sulfur containing hydrocarbon fuel (such as No. 2 fuel oil) in a steam reforming environment. The material has particular utility in autothermal, tubular, cyclic and adiabatic steam reforming processes.

Setzer, H. J.

1985-03-05T23:59:59.000Z

133

Distributed Reforming of Biomass Pyrolysis Oils (Presentation)  

Energy.gov (U.S. Department of Energy (DOE))

Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

134

100-D Area In Situ Redox Treatability Test for Chromate-Contaminated Groundwater: FY 1998 Year-End Report  

SciTech Connect

A treatability test was conducted for the In Situ Redox Manipulation (ISRM) technology at the US Department of Energy's Hanford, Washington 100D Area. The target contaminant was dissolved chromate [Cr(VI)] in groundwater. The ISRM technology involves creating a permeable subsurface treatment zone to reduce mobile chromate in groundwater to an insoluble form. The ISRM permeable treatment zone is created by reducing ferric iron [Fe(III)] to ferrous iron [Fe(II)] within the aquifer sediments. This is accomplished by injecting aqueous sodium dithionite into the aquifer and withdrawing the reaction products. The goal of the treatability test was to create a linear ISRM barrier by injecting sodium dithionite into five wells. Well installation and site characterization activities began in the spring of 1997. The first dithionite injection took place in September 1997. The results of this first injection were monitored through the spring of 1998; the remaining four dithionite injections were carried out in May through July of 1998. These five injections created a reduced zone in the Hanford unconfined aquifer 150 feet in length (perpendicular to groundwater flow) by 50 feet wide. The reduced zone extended over the thickness of the unconfined zone, which is approximately 15 feet. Analysis of recent groundwater sampling events shows that the concentrations of chromate [Cr(VI)] in groundwater in the reduced zone have been decreased from starting concentrations of approximately 900 ppb to below analytical detection limits (<7 ppb). Chromate concentrations are also declining in some downgradient monitoring wells. Laboratory analysis of iron in the soil indicates that the barrier should remain in place for approximately 20 to 25 years. These measurements will be confirmed by analysis of sediment cores in FY 1999.

Williams, M.D.; Vermeul, V.R.; Szecsody, J.E.; Fruchter, J.S.; Cole, C.R.

1999-04-15T23:59:59.000Z

135

Sulfur-deactivated steam reforming of gasified biomass  

SciTech Connect

The effect of hydrogen sulfide on the stream reforming of methane has been studied. Methane is the most difficult component to convert by steam reforming in the mixture of hydrocarbons, which is produced in biomass gasification. Two catalysts were subjected to hydrogen sulfide levels up to 300 ppm so as to study the effect of sulfur on their deactivation. These catalysts were the C11-9-061, from United Catalyst Inc., and the HTSR1, from Haldor Topsoee. The activation energy of the sulfur-deactivated steam-reforming reaction was calculated to be 280 and 260 kJ/mol, for each catalyst, respectively. The high values most probably originate from the fact that the degree of sulfur coverage of the nickel surface is close to 1 for these experiments. Even under these severe conditions, steam reforming of methane is possible without any carbon formation. The HTSR1 catalyst exhibits a very high sulfur-free activity, resulting in a performance in the presence of hydrogen sulfide higher than that for the C11-9-061 catalyst. By using the HTSR1 catalyst, the reactor temperature can be lowered by 60 C in order to reach comparable levels of conversion.

Koningen, J.; Sjoestroem, K. [Kungl Tekniska Hoegskolan, Stockholm (Sweden)] [Kungl Tekniska Hoegskolan, Stockholm (Sweden)

1998-02-01T23:59:59.000Z

136

Steam Reforming of Low-Level Mixed Waste  

SciTech Connect

Under DOE Contract No. DE-AR21-95MC32091, Steam Reforming of Low-Level Mixed Waste, ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design construction, and testing of the PDU as well as performance and economic projections for a 500- lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area published April 1997.1 The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfidly tested including a 750-hour test on material simulating a PCB- and Uranium- contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (>99.9999oA) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radlonuclides in the volume-reduced solids. Cost studies have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

None

1998-01-01T23:59:59.000Z

137

The role of civil society in health care reforms: An arena for hegemonic struggles  

Science Journals Connector (OSTI)

Abstract The present paper argues that current mainstream understandings of civil society as ontologically different from the state and essentially positive (either normative or functionally) are problematic in order to understand the development of health care reforms. The paper proposes to ground an explanation of the role of civil society in health care reforms in a Gramscian understanding of civil society as analytically different from the state, and as an arena for hegemonic struggles. The study of health care reform in Israel serves as a case study for this claim.

Dani Filc

2014-01-01T23:59:59.000Z

138

Experimental and numerical analysis of transport phenomena in an internal indirect fuel reforming type Solid Oxide Fuel Cells using Ni/SDC as a catalyst  

Science Journals Connector (OSTI)

This paper presents experimental and numerical studies on the fuel reforming process on an Ni/SDC catalyst. To optimize the reforming reactors, detailed data about the entire reforming process is required. In the present paper kinetics of methane/steam reforming on the Ni/SDC catalyst was experimentally investigated. Measurements including different thermal boundary conditions, the fuel flow rate and the steam-to-methane ratios were performed. The reforming rate equation derived from experimental data was implemented in into numerical model which was numerically solved in order to discuss this process in details.

G Brus; S Kimijima; J S Szmyd

2012-01-01T23:59:59.000Z

139

How Not to Reform Medicare  

Science Journals Connector (OSTI)

...private insurers would continue to compete primarily by trying to enroll the healthy and not the sick — a practice called risk selection. The result would be increased administrative costs, not improved quality. The elderly and disabled would face ever heavier financial burdens and larger risks as the... Medicare reform has become a hot political issue. The program is wildly popular but expensive. It is the principal source of projected increases in budget deficits. With deficits increasingly seen as a mortal economic threat, many believe that now is the ...

Aaron H.J.

2011-04-28T23:59:59.000Z

140

Carbon Dioxide Reforming of Methane to Syngas by Thermal Plasma  

Science Journals Connector (OSTI)

Experiments were conducted on syngas preparation from dry reforming of methane by carbon dioxide with a DC arc plasma at atmospheric pressure. In all experiments, nitrogen gas was used as the working gas for thermal plasma to generate a high-temperature jet into a horizontal tube reactor. A mixture of methane and carbon dioxide was fed vertically into the jet. In order to obtain a higher conversion rate of methane and carbon dioxide, chemical energy efficiency and fuel production efficiency, parametric screening studies were conducted, in which the volume ratio of carbon dioxide to methane in fed gases and the total flux of fed gases were taken into account. Results showed that carbon dioxide reforming of methane to syngas by thermal plasma exhibited a larger processing capacity, higher conversion of methane and carbon dioxide and higher chemical energy efficiency and fuel production efficiency. In addition, thermodynamic simulation for the reforming process was conducted. Experimental data agreed well with the thermodynamic results, indicating that high thermal efficiency can be achieved with the thermal plasma reforming process.

Sun Yanpeng (???); Nie Yong (??); Wu Angshan (???); Ji Dengxiang (???); Yu Fengwen (???); Ji Jianbing (???)

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Static and Dynamic Simulation of Steam Methane Reformers  

Science Journals Connector (OSTI)

The steam-methane reaction is an essential step for many processing plants. Hydrogen, ammonia and methanol are mostly produced by means of methane steam reforming. Since hydrogen is essential for any refinery employing hydrotreating, the performance monitoring of the hydrogen plant is highly desirable. The use of models or simulation is now a standard practice in most chemical plants and refineries. However, reliable models are still lacking for speciality reactors like the methane steam reformer. This paper describes steady-state and dynamic models for the reactions involved in reforming methane and higher hydrocarbon gases. The performance of the reformer is then illustrated by sensitivity analysis to various input disturbances like inlet pressure, temperature, feed concentration and rate, fuel rate and density and steam to carbon ratio. The effect of these disturbances on exit temperature and conversion is studied and analyzed. Catalyst deactivation effects are also discussed and it is shown by sample calculations that the simulator can give insight into catalyst performance and assist in monitoring catalyst deactivation. The transient effects are also reported and dynamic elements like gains and response time are discussed. Such information should give insight into controller design and effects of various parameters.

I.M. Alatiqi; A.M. Meziou; G.A. Gasmelseed

1989-01-01T23:59:59.000Z

142

Fuel Reformer, LNT and SCR Aftertreatment System Meeting Emissions...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Reformer, LNT and SCR Aftertreatment System Meeting Emissions Useful Life Requirements Fuel Reformer, LNT and SCR Aftertreatment System Meeting Emissions Useful Life Requirements...

143

Diesel Reforming for Fuel Cell Auxiliary Power Units  

SciTech Connect

This objective of this project was to develop technology suitable for onboard reforming of diesel. The approach was to examine catalytic partial oxidation and steam reforming.

Borup, R.; Parkinson, W. J.; Inbody, M.; Brosha, E.L.; Guidry, D.R.

2005-01-27T23:59:59.000Z

144

DOE Safety and Security Reform Meeting | Department of Energy  

Office of Environmental Management (EM)

DOE Safety and Security Reform Meeting DOE Safety and Security Reform Meeting Meeting Date: August 13, 2010 HSS senior managers with lead responsibilities in DOE's safety and...

145

Hydrogen generation from plasmatron reformers and use for diesel...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

generation from plasmatron reformers and use for diesel exhaust aftertreatment Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment 2003 DEER...

146

Methane Steam Reforming Kinetics on a Ni/Mg/K/Al2O3 Catalyst  

Science Journals Connector (OSTI)

The kinetics of methane steam reforming were studied on a Ni/Mg/K/...2O3...catalyst that was developed for conditioning of biomass-derived syngas. Reactions were conducted in a packed-bed reactor while the concen...

Allison M. Robinson; Megan E. Gin; Matthew M. Yung

2013-12-01T23:59:59.000Z

147

Use of Pd membranes in catalytic reactors for steam methane reforming for pure hydrogen production  

Science Journals Connector (OSTI)

This review analyzes publications on experimental studies and mathematical modeling in the field of development of a catalytic reformer (mainly, steam methane conversion) with a fixed catalytic bed. The specif...

A. B. Shigarov; V. D. Meshcheryakov…

2011-10-01T23:59:59.000Z

148

Fuel cell integrated with steam reformer  

SciTech Connect

A H.sub.2 -air fuel cell integrated with a steam reformer is disclosed wherein a superheated water/methanol mixture is fed to a catalytic reformer to provide a continuous supply of hydrogen to the fuel cell, the gases exhausted from the anode of the fuel cell providing the thermal energy, via combustion, for superheating the water/methanol mixture.

Beshty, Bahjat S. (Lower Makefield, PA); Whelan, James A. (Bricktown, NJ)

1987-01-01T23:59:59.000Z

149

Has Massachusetts health care reform worked for the working poor? Results from an analysis of opportunity  

Science Journals Connector (OSTI)

AbstractPurpose Health care reform was introduced in Massachusetts (MA) in 2006 and serves as a model for what was subsequently introduced nationally as the Patient Protection and Affordable Care Act. The Boston Area Community Health survey collected data before (2002–2005) and after (2006–2010) introduction of the MA health insurance mandate, providing a unique opportunity to assess its effects in a large, epidemiologic cohort. Methods We report on the apparent effects of the mandate on the same participants over time, focusing specifically on the vulnerable working poor (WP). We evaluated differences in subpopulations of interest at pre- and post-reform periods to explore whether MA health care reform resulted in an overall gain in insurance coverage. Results MA health care reform was associated with net gains in health insurance coverage overall and among the subgroups studied. Our findings suggest that despite being targeted by health care reform legislation, the WP in MA continue to report lower rates of insurance coverage compared with both the nonworking poor and the not poor. Conclusions MA health care reform legislation, including the expansion of Medicaid, resulted in substantial overall gains in coverage. Disparities in insurance coverage persist among some subgroups following health care reform implementation in MA. These results have important implications for health services researchers and policy makers, particularly in light of the ongoing implementation of the Patient Protection and Affordable Care Act.

Liane J. Tinsley; Susan A. Hall; John B. McKinlay

2014-01-01T23:59:59.000Z

150

Steam reforming of methane using double-walled reformer tubes containing high-temperature thermal storage Na2CO3/MgO composites for solar fuel production  

Science Journals Connector (OSTI)

Abstract Double-walled reactor tubes containing thermal storage materials based on the molten carbonate salts—100 wt% Na2CO3 molten salt, 90 wt% Na2CO3/10 wt% MgO and 80 wt% Na2CO3/20 wt% MgO composite materials—were studied for the performances of the reactor during the heat charging mode, while those of methane reforming with steam during heat discharging mode for solar steam reforming. The variations in the temperatures of the catalyst and storage material, methane conversion, duration of reforming for obtaining high levels of methane conversion (>90%), higher heating value (HHV) power of reformed gas and efficiency of the reactor tubes were evaluated for the double-walled reactor tubes and a single-wall reactor tube without the thermal storage. The results for the heat charging mode indicated that the composite thermal storage could successfully store the heat transferred from the exterior wall of the reactor in comparison to the pure molten-salt. The double-walled reactor tubes with the 90 wt% Na2CO3/10 wt% MgO composite material was the most desirable for steam reforming of methane to realize large HHV amounts of reformed gas and higher efficiencies during heat-discharging mode.

Nobuyuki Gokon; Shohei Nakamura; Tsuyoshi Hatamachi; Tatsuya Kodama

2014-01-01T23:59:59.000Z

151

Methane Steam Reforming Thermally Coupled with Fuel Combustion: Application of Chemical Looping Concept as a Novel Technology  

Science Journals Connector (OSTI)

Methane Steam Reforming Thermally Coupled with Fuel Combustion: Application of Chemical Looping Concept as a Novel Technology ... One of these new methods is chemical looping combustion (CLC). ... Experimental Study of Chemical-Looping Reforming in a Fixed-Bed Reactor: Performance Investigation of Different Oxygen Carriers on Al2O3 and TiO2 Support ...

Mohammad Reza Rahimpour; Marziyeh Hesami; Majid Saidi; Abdolhossein Jahanmiri; Mahdi Farniaei; Mohsen Abbasi

2013-03-14T23:59:59.000Z

152

976 JOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 15, NO. 4, AUGUST 2006 Methanol Steam Reformer on a Silicon Wafer  

E-Print Network (OSTI)

976 JOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 15, NO. 4, AUGUST 2006 Methanol Steam Reformer without mass transport considerations. The 1-D model provided a rapid analytical tool to assess is achieved through on-chip resis- tive heaters, whereby methanol steam reforming reactions were studied over

Malen, Jonathan A.

153

REFORM, LOBBIES AND WELFARE: A COMMON AGENCY APPROACH  

E-Print Network (OSTI)

REFORM, LOBBIES AND WELFARE: A COMMON AGENCY APPROACH Cecilia TESTA London School of Economics are a reform and a compensating taxation. The main feature of the reform is that it creates gainers and losers on tax parameters. keywords: reform, lobbying, redistribution, economic welfare. 1 #12;Introduction

Royal Holloway, University of London

154

September 25, 2013 AFSCME Continues to Object to Pension Reform;  

E-Print Network (OSTI)

September 25, 2013 AFSCME Continues to Object to Pension Reform; UC Implements Latest Bargaining working conditions and reasonable pension reform. However, AFSCME has rejected UC's proposals. From the start, AFSCME leadership has objected to UC's responsible pension reform -- the kind of reform that

Leistikow, Bruce N.

155

AN UPDATE ON REFORM IN EASTERN EUROPE AND RUSSIA  

E-Print Network (OSTI)

AN UPDATE ON REFORM IN EASTERN EUROPE AND RUSSIA Jeffrey Sachs ABSTRACT: The paper reviews the experience of Poland and Russia with economic reform, with occasional comparison to China's experience. The author argues that macroeconomic chaos in Poland and Russia preceded reform and was allayed by reform

156

Diesel Reforming for Solid Oxide Fuel Cell Application  

SciTech Connect

This presentation discusses the development of a diesel reforming catalyst and catalytic system development.

Liu, D-J.; Sheen, S-H.; Krumpelt, M.

2005-01-27T23:59:59.000Z

157

Electricity reform in developing and transition countries: A reappraisal  

E-Print Network (OSTI)

Electricity reform in developing and transition countries: A reappraisal J.H. Williams, R. Ghanadan-oriented reforms in their electric power sectors. Despite the widespread adoption of a standard policy model features of non-OECD electricity reform and reappraises reform policies and underlying assumptions

Kammen, Daniel M.

158

HYDROGEN GENERATION FROM PLASMATRON REFORMERS: A PROMISING TECHNOLOGY FOR NOX ADSORBER REGENERATION AND OTHER AUTOMOTIVE APPLICATIONS  

SciTech Connect

Plasmatron reformers are being developed at MIT and ArvinMeritor [1]. In these reformers a special low power electrical discharge is used to promote partial oxidation conversion of hydrocarbon fuels into hydrogen and CO. The partial oxidation reaction of this very fuel rich mixture is difficult to initiate. The plasmatron provides continuous enhanced volume initiation. To minimize electrode erosion and electrical power requirements, a low current, high voltage discharge with wide area electrodes is used. The reformers operate at or slightly above atmospheric pressure. Plasmatron reformers provide the advantages of rapid startup and transient response; efficient conversion of the fuel to hydrogen rich gas; compact size; relaxation or elimination of reformer catalyst requirements; and capability to process difficult to reform fuels, such as diesel and bio-oils. These advantages facilitate use of onboard hydrogen-generation technology for diesel exhaust after-treatment. Plasma-enhanced reformer technology can provide substantial conversion even without the use of a catalyst. Recent progress includes a substantial decrease in electrical power consumption (to about 200 W), increased flow rate (above 1 g/s of diesel fuel corresponding to approximately 40 kW of chemical energy), soot suppression and improvements in other operational features.. Plasmatron reformer technology has been evaluated for regeneration of NOx adsorber after-treatment systems. At ArvinMeritor tests were performed on a dual-leg NOx adsorber system using a Cummins 8.3L diesel engine both in a test cell and on a vehicle. A NOx adsorber system was tested using the plasmatron reformer as a regenerator and without the reformer i.e., with straight diesel fuel based regeneration as the baseline case. The plasmatron reformer was shown to improve NOx regeneration significantly compared to the baseline diesel case. The net result of these initial tests was a significant decrease in fuel penalty, roughly 50% at moderate adsorber temperatures. This fuel penalty improvement is accompanied by a dramatic drop in slipped hydrocarbon emissions, which decreased by 90% or more. Significant advantages are demonstrated across a wide range of engine conditions and temperatures. The study also indicated the potential to regenerate NOx adsorbers at low temperatures where diesel fuel based regeneration is not effective, such as those typical of idle conditions. Two vehicles, a bus and a light duty truck, have been equipped for plasmatron reformer NOx adsorber regeneration tests.

Bromberg, L.; Crane, S; Rabinovich, A.; Kong, Y; Cohn, D; Heywood, J; Alexeev, N.; Samokhin, A.

2003-08-24T23:59:59.000Z

159

Steam Reforming on Transition-metal Carbides from Density-functional Theory  

SciTech Connect

A screening study of the steam reforming reaction on clean and oxygen covered early transition-metal carbides surfaces is performed by means of density-functional theory calculations. It is found that carbides provide a wide spectrum of reactivities, from too reactive via suitable to too inert. Several molybdenum-based systems are identified as possible steam reforming catalysts. The findings suggest that carbides provide a playground for reactivity tuning, comparable to the one for pure metals.

Vojvodic, Aleksandra

2012-05-11T23:59:59.000Z

160

Steam reforming utilizing iron oxide catalyst  

SciTech Connect

High activity steam reforming iron oxide catalysts are described. Such catalysts can be unsupported utilizing at least 90% by weight iron oxide and various modifiers (Ai/sub 2/O/sub 3/, K/sub 2/O, CaO, SiO/sub 2/) or unmodified and supported on such things as alumina, CaO impregnated alumina, and lanthanum stabilized alumina. When used in steam reformers such as autothermal and tubular steam reformers, these catalysts demonstrate much improved resistance to carbon plugging.

Setzer, H. T.; Bett, J. A. S.

1985-06-11T23:59:59.000Z

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Before the House Oversight and Government Reform Subcommittee on  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Oversight and Government Reform Subcommittee on Oversight and Government Reform Subcommittee on Technology, Information Policy, Intergovernmental Relations, and Procurement Reform Before the House Oversight and Government Reform Subcommittee on Technology, Information Policy, Intergovernmental Relations, and Procurement Reform Before the Subcommittee on Technology, Information Policy, Intergovernmental Relations and Procurement Reform, Committee on Oversight and Government Reform, United States House of Representatives Written Statement By: Owen Barwell, Acting Chief Financial Officer, United States Department of Energy Subject: DOE Financial Information Systems Final_Testimony_for_Owen_Barwell.pdf More Documents & Publications AL2010-03.pdf Request for Information - Operations and Maintenance (O & M) Support

162

Incentives in Water Management Reform: Assessing the Effect on Water Use,  

NLE Websites -- All DOE Office Websites (Extended Search)

Incentives in Water Management Reform: Assessing the Effect on Water Use, Incentives in Water Management Reform: Assessing the Effect on Water Use, Production and Poverty in the Yellow River Basin Speaker(s): Jinixia Wang Date: May 22, 2003 - 12:00pm Location: Bldg. 90 The purpose of this presentation is to better understand water management reform in China's rural communities, focusing on the effect of incentives to water managers on the nation's water resources and the welfare of the rural population. Based on a survey study in the Yellow River Basin, our findings show that Water User Associations and contracting have begun to systematically replace traditional forms of collective management. The analysis demonstrates, however, that it is not a nominal implementation of the reform that matters, but rather it is a creation of new management

163

Status of Power Sector Reform in Africa: Impact on the Poor | Open Energy  

Open Energy Info (EERE)

Status of Power Sector Reform in Africa: Impact on the Poor Status of Power Sector Reform in Africa: Impact on the Poor Jump to: navigation, search Tool Summary Name: Status of Power Sector Reform in Africa: Impact on the Poor Agency/Company /Organization: Stephen Karekezi and John Kimani Sector: Energy Focus Area: Renewable Energy, Energy Efficiency, People and Policy Phase: Create a Vision Topics: Co-benefits assessment, - Energy Access Resource Type: Publications User Interface: Website Website: www.sciencedirect.com/science/article/pii/S0301421502000484 Cost: Free UN Region: Eastern Africa, Southern Africa Language: English This article is based on a regional study by the authors reviewing the status, challenges and prospects of ongoing and planned power sector reform in eastern and southern Africa with special emphasis on the implications

164

Payment reform and changes in health care in China  

Science Journals Connector (OSTI)

Abstract This paper is intended to assess the primary effects on cost, utilization and quality of care from payment reform of capitation and open enrollment in Changde city, Hunan Province of China. Open enrollment policy was introduced to deal with possible cream skimming associated with capitation. Based on the longitudinal Urban Resident Basic Medical Insurance (URBMI) Household Survey, this study analyses the URBMI data through a set of regression models. The original data included over five thousand inpatient admissions during the study period between 2008 and 2010. The study finds the payment reform to reduce its inpatient out-of-pocket cost by 19.7%, out-of-pocket ratio by 9.5%, and length of stay by 17.7%. However, the total inpatient cost, drug cost ratio, treatment effect, and patient satisfaction showed little difference between Fee-For-Service and capitation models. We conclude that the payment reform in Changde did not reduce overall inpatient expenditure, but it decreased the financial risk and length of stay of inpatient patients without compromising quality of care. The findings would contribute to the health care payment literatures from developing countries and open further research tracks on the ability of open enrollment to compensate for capitation drawbacks.

Chen Gao; Fei Xu; Gordon G. Liu

2014-01-01T23:59:59.000Z

165

Effects of welfare reform on women's crime  

Science Journals Connector (OSTI)

Abstract We investigate the effects of broad-based work incentives on female crime by exploiting the welfare reform legislation of the 1990s, which dramatically increased employment among women at risk for relying on cash assistance. We base the analyses on the supply of crime model in the human capital literature which emphasizes the importance of employment prospects in the legal and illegal labor markets. We find suggestive evidence that welfare reform decreased female arrests for property crimes (by 4–5%), but that it did not affect arrests for other types of crimes. The effects appear to be stronger in states with larger welfare caseload declines. As welfare reform policies are targeted to females, it is empirically validating that we do not find any substantively or statistically significant effects of welfare reform on crime among males. The findings point to broad-based work incentives—and, by inference, employment—as an important determinant of female property crime.

Hope Corman; Dhaval M. Dave; Nancy E. Reichman

2014-01-01T23:59:59.000Z

166

A Multistage Steam Reformer Utilizing Solar Heat  

Science Journals Connector (OSTI)

Today a large amount of the required hydrogen or synthesis gas (mixture of hydrogen and carbonmonoxide) is won by steam reforming of low hydrocarbons, especially methane. Hereby the mixture of hydrocarbons and...

W. Jäger; U. Leuchs; W. Siebert

1987-01-01T23:59:59.000Z

167

Improve reformer operation with trace sulfur removal  

SciTech Connect

Modern bimetallic reforming catalysts typically have feed specifications for sulfur of 0.5 to 1 wppm in the reformer naphtha carge. Sulfur in the raw naphtha is reduced to this level by naphtha hydrotreating. While most naphtha hydrotreating operations can usually obtain these levels without substantial problems. It is difficult to obtain levels much below 0.5 to 1 wppm with this process. Revamp of a constrained existing hydrotreater to reduce product sulfur slightly can be extremely costly typically entailing replacement or addition of a new reactor. At Engelhard the authors demonstrated that if the last traces of sulfur remaining from hydrotreating can be removed, the resulting ultra-low sulfur feed greatly improves the reformer operation and provides substantial economic benefit to the refiner. Removal of the remaining trace sulfur is accomplished in a simple manner with a special adsorbent bed, without adding complexity to the reforming operation.

McClung, R.G.; Novak, W.J.

1987-01-01T23:59:59.000Z

168

Biogas fuel reforming for solid oxide fuel cells  

Science Journals Connector (OSTI)

In this paper strategies for biogas reforming and their ensuing effects on solid oxide fuel cell(SOFC) performance are explored. Synthesized biogas (65% CH4?+?35% CO2) fuel streams are reformed over a rhodium catalyst supported on a porous ?-alumina foam. Reforming approaches include steam reforming and catalytic partial oxidation (CPOX) utilizing either air or pure oxygen as the oxidant. A computational model is developed and utilized to guide the specification of reforming conditions that maximize both CH4 and CO2 conversions. Model predictions are validated with experimental measurements over a wide range of biogas-reforming conditions. Higher reforming temperatures are shown to activate the biogas-borne CO2 to enable significant methane dry-reforming chemistry. Dry reforming minimizes the oxidant-addition needs for effective biogas conversion potentially decreasing the thermal requirements for reactant heating and improving system efficiency. Such high-temperature reforming conditions are prevalent during CPOX with a pure-O2 oxidant. While CPOX-with-O2 reforming is highly exothermic the endothermicity of dry-reforming chemistry can be exploited to ensure that catalyst temperatures do not reach levels which cause catalyst sintering and degradation. SOFCelectrochemical performance under biogas reformate is shown to vary substantially with reforming approach. Cell operation under CPOX-with-O2 reformate is found to be comparable to that under humidified hydrogen.

Danielle M. Murphy; Amy E. Richards; Andrew Colclasure; Wade A. Rosensteel; Neal P. Sullivan

2012-01-01T23:59:59.000Z

169

Experimental Study of Chemical-Looping Reforming in a Fixed-Bed Reactor: Performance Investigation of Different Oxygen Carriers on Al2O3 and TiO2 Support  

Science Journals Connector (OSTI)

E. Karimi †, H. R. Forutan †, M. Saidi †, M. R. Rahimpour *†‡, and A. Shariati † ... Rahimpour, M. R.; Hesami, M.; Saidi, M.; Jahanmiri, A.; Farniaei, M.; Abbasi, M.Methane steam reforming thermally coupled with fuel combustion: Application of chemical looping concept as a novel technology Energy Fuels 2013, 27 ( 4) 2351– 2362 ... Rahimpour, Mohammad Reza; Hesami, Marziyeh; Saidi, Majid; Jahanmiri, Abdolhossein; Farniaei, Mahdi; Abbasi, Mohsen ...

E. Karimi; H. R. Forutan; M. Saidi; M. R. Rahimpour; A. Shariati

2014-03-26T23:59:59.000Z

170

Health system reform in rural China: Voices of healthworkers and service-users  

Science Journals Connector (OSTI)

Abstract Like many other countries China is undergoing major health system reforms, with the aim of providing universal health coverage, and addressing problems of low efficiency and inequity. The first phase of the reforms has focused on strengthening primary care and improving health insurance coverage and benefits. The aim of the study was to explore the impacts of these reforms on healthworkers and service-users at township level, which has been the major target of the first phase of the reforms. From January to March 2013 we interviewed eight health officials, 80 township healthworkers and 80 service-users in eight counties in Zhejiang and Yunnan provinces, representing rich and poor provinces respectively. Thematic analysis identified key themes around the impacts of the health reforms. We found that some elements of the reforms may actually be undermining primary care. While the new health insurance system was popular among service-users, it was criticised for contributing to fast-growing medical costs, and for an imbalance of benefits between outpatient and inpatient services. Salary reform has guaranteed healthworkers' income, but greatly reduced their incentives. The essential drug list removed perverse incentives to overprescribe, but led to falls in income for healthworkers, and loss of autonomy for doctors. Serious problems with drug procurement also emerged. The unintended consequences have included a brain drain of experienced healthworkers from township hospitals, and patients have flowed to county hospitals at greater cost. In conclusion, in the short term resources must be found to ensure rural healthworkers feel appropriately remunerated and have more clinical autonomy, measures for containment of the medical costs must be taken, and drug procurement must show increased transparency and accountability. More importantly the study shows that all countries undergoing health reforms should elicit the views of stakeholders, including service-users, to avoid and address unintended consequences.

Xu Dong Zhou; Lu Li; Therese Hesketh

2014-01-01T23:59:59.000Z

171

Navigating the tension between the master narrative of the academy and the counter-narrative of reform: personal case studies from within an engineering education coalition  

E-Print Network (OSTI)

happen here the way That they happened here?? from ?Someone in a Tree? Pacific Overtures By Stephen Sondheim vi ACKNOWLEDGEMENTS I would like to thank all the participants in my study, especially Dr. Louis Everett, Dr. Jim Richardson, Dr............................................................................. 58 IV REBEL, HIRED GUN AND TRUE BELIEVER: DR. LOUIS EVERETT?S STORY............................................. 60 Overview of Louis?s Career in the FC ............................... 61 Four Themes of Change and Identity...

Merton, Prudence

2006-08-16T23:59:59.000Z

172

Reforming of fuel inside fuel cell generator  

DOE Patents (OSTI)

Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream I and spent fuel stream II. Spent fuel stream I is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream I and exhaust stream II, and exhaust stream I is vented. Exhaust stream II is mixed with spent fuel stream II to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells.

Grimble, Ralph E. (Finleyville, PA)

1988-01-01T23:59:59.000Z

173

E-Print Network 3.0 - assessing welfare reform Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

reventionscience.umn.edu Summary: , poverty, welfare reform, school reform, and health- care reform. An emphasis is given to large... , and dissemination of a variety of programs...

174

Steam reforming of low-level mixed waste. Final report  

SciTech Connect

ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design, construction, and testing of the PDU as well as performance and economic projections for a 300-lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area and published in April 1997. The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfully tested including a 750-hour test on material simulating a PCB- and Uranium-contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (> 99.9999%) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radionuclides in the volume-reduced solids. Economic evaluations have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

NONE

1998-06-01T23:59:59.000Z

175

Low Cost Autothermal Diesel Reforming Catalyst Development  

SciTech Connect

Catalytic autothermal reforming (ATR) represents an important step of converting fossil fuel to hydrogen rich reformate for use in solid oxide fuel cell (SOFC) stacks. The state-of-the-art reforming catalyst, at present, is a Rh based material which is effective but costly. The objective of our current research is to reduce the catalyst cost by finding an efficient ATR catalyst containing no rhodium. A group of perovskite based catalysts have been synthesized and evaluated under the reforming condition of a diesel surrogate fuel. Hydrogen yield, reforming efficiency, and conversion selectivity to carbon oxides of the catalyst ATR reaction are calculated and compared with the benchmark Rh based material. Several catalyst synthesis improvements were carried out including: 1) selectively doping metals on the A-site and B-site of the perovskite structure, 2) changing the support from perovskite to alumina, 3) altering the method of metal addition, and 4) using transition metals instead of noble metals. It was found that the catalytic activity changed little with modification of the A-site metal, while it displayed considerable dependence on the B-site metal. Perovskite supports performed much better than alumina based supports.

Shihadeh, J.; Liu, D.

2004-01-01T23:59:59.000Z

176

An attempt to minimize the temperature gradient along a plug-flow methane/steam reforming reactor by adopting locally controlled heating zones  

Science Journals Connector (OSTI)

Plug flow reactors are very common in the chemical process industry, including methane/steam reforming applications. Their operation presents many challenges, such as a strong dependence of temperature and composition distribution on the inlet conditions. The strongly endothermic methane/steam reforming reaction might result in a temperature drop at the inlet of the reactor and consequently the occurrence of large temperature gradients. The strongly non-uniform temperature distribution due to endothermic chemical reaction can have tremendous consequences on the operation of the reactor, such as catalyst degradation, undesired side reactions and thermal stresses. To avoid such unfavorable conditions, thermal management of the reactor becomes an important issue. To carry out thermal management properly, detailed modeling and corresponding numerical analyses of the phenomena occurring inside the reforming system is required. This paper presents experimental and numerical studies on the methane/steam reforming process inside a plug-flow reactor. To optimize the reforming reactors, detailed data about the entire reforming process is required. In this study the kinetics of methane/steam reforming on the Ni/YSZ catalyst was experimentally investigated. Measurements including different thermal boundary conditions, the fuel flow rate and the steam- to-methane ratios were performed. The reforming rate equation derived from experimental data was used in the numerical model to predict gas composition and temperature distribution along the steam-reforming reactor. Finally, an attempt was made to control the temperature distribution by adopting locally controlled heating zones.

M Mozdzierz; G Brus; A Sciazko; Y Komatsu; S Kimijima; J S Szmyd

2014-01-01T23:59:59.000Z

177

Simulation of Steam Reformers for Methane  

Science Journals Connector (OSTI)

Abstract A model is developed for industrial steam reformers for both top fired and side fired furnaces. The catalyst tube model is a one-dimensional heterogeneous model with intra-particle diffusional resistances. The two point boundary value differential equations of the catalyst pellets are solved using a modified novel orthogonal collocation technique to obtain the effectiveness factor variation along the length of the reactor. The side fired furnace equations are algebraic equations, the top fired furnace equations are two-point boundary value differential equations which are solved using the orthogonal collocation technique. A recently developed more general rate expression is used. The model performance is checked against industrial steam reformers. The model is used to investigate the effect of various parameters on the behaviour of the catalyst tubes and the furnace. The effectiveness factor variation along the length of the catalyst tube is also analysed. Keywords: Steam Reforming, Reactor modeling, Digital Simulation, effectiveness factor

M.A. Soliman; S.S.E.H. El-Nashaie; A.S. Al-Ubaid; A. Adris

1988-01-01T23:59:59.000Z

178

On-Board Ammonia Generation Using Delphi Diesel Fuel Reformer  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fuel LNT (Generates Ammonia) Exhaust Selective Catalytic DPF Valve Reduction Catalyst (SCR) 2 DEER 2007 Bypass V2 LNT V1 Reformer SCR Bypass V2 LNT V1 SCR Reformer * NOx storage...

179

Does health reform affect self-employment? Evidence from Massachusetts  

Science Journals Connector (OSTI)

This paper evaluates whether the implementation of the 2006 Massachusetts health reform law affected the decision of taxpayers to ... Though tenuous, our results suggest that the reform led to a decline in the ra...

Bradley T. Heim; Ithai Z. Lurie

2014-12-01T23:59:59.000Z

180

Electricity reform in Chile : lessons for developing countries  

E-Print Network (OSTI)

Chile was the first country in the world to implement a comprehensive reform of its electricity sector in the recent period. Among developing countries only Argentina has had a comparably comprehensive and successful reform. ...

Pollitt, Michael G.

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

The Effect of Welfare Reform on Childbirth, Marriage, and Divorce  

E-Print Network (OSTI)

This dissertation contains two essays on the effect of welfare reform on child- birth, marriage, and divorce. In the first essay, I exploit the cross state variation in welfare reform implementation to identify its effect on birth rates. The results...

Pakdeethai, Pimrak

2010-10-12T23:59:59.000Z

182

SECOND GENERATION REFORMS IN CHILE, POWER EXCHANGE MODEL. THE SOLUTION?  

E-Print Network (OSTI)

SECOND GENERATION REFORMS IN CHILE, POWER EXCHANGE MODEL. THE SOLUTION? David Watts Paulo Atienza to participate. Chile was the pioneer introducing this kind of reforms, through the application of a centralized

Catholic University of Chile (Universidad Católica de Chile)

183

MORE HEALTH CARE REFORM By Victor R. Fuchs  

E-Print Network (OSTI)

MORE HEALTH CARE REFORM By Victor R. Fuchs #12;2 | MORE HEALTH CARE REFORM The Robert Wood Johnson?................................................................................... 8 Government Payment for Health Care -- Causes and Consequences....................................................................................................................................................................................... 16 Health Care Is Different -- That's Why Expenditures Matter

Zalta, Edward N.

184

SECTORAL EFFECTS OF TAX REFORMS IN AN OPEN ECONOMY  

E-Print Network (OSTI)

SECTORAL EFFECTS OF TAX REFORMS IN AN OPEN ECONOMY Olivier CARDI Romain RESTOUT December, 2010 REFORMS IN AN OPEN ECONOMY Olivier CARDI Universit´e Panth´eon-Assas ERMES Ecole Polytechnique Romain with traded and non traded goods to in- vestigate the sectoral effects of three tax reforms: i) two revenue

Boyer, Edmond

185

the triple aim MEETING THE GOAL OF HEALTH REFORM  

E-Print Network (OSTI)

the triple aim MEETING THE GOAL OF HEALTH REFORM Produced by OHSU Strategic Communications -- emphasizing shared decision-making and coordination between providers -- could influence reform in a big way care. health reform is about getting better health outcomes for our communities, improving access

Chapman, Michael S.

186

Preliminary and incomplete A Modest Proposal for International Monetary Reform  

E-Print Network (OSTI)

Preliminary and incomplete A Modest Proposal for International Monetary Reform International Columbia University #12;- 1 - - 1 - #12;- 2 - A Modest Proposal for International Monetary Reform Bruce are fundamental aspects of the present system and that, without reform, they will continue to plague the global

Grishok, Alla

187

health reform mattersTM alert ATTORNEY ADVERTISINGropesgray.com  

E-Print Network (OSTI)

health reform mattersTM alert ATTORNEY ADVERTISINGropesgray.com On March 23, President Obama signed is tracking the myriad other developments of the new health reform law. You can find a wide range of related material, including enacting language, implementing documents, and analysis through the Health Reform

Chapman, Michael S.

188

Wellcome Trust CONSULTATION RESPONSE Ofqual: A level Reform Consultation  

E-Print Network (OSTI)

Wellcome Trust CONSULTATION RESPONSE Ofqual: A level Reform Consultation September 2012 1 Ofqual: A Level Reform Consultation Response by the Wellcome Trust September 2012 Key Points National Subject to university. We are therefore pleased to respond to this consultation on reforming A levels. Our comments

Rambaut, Andrew

189

Data reconciliation and optimal operation of a catalytic naphtha reformer  

E-Print Network (OSTI)

-mail:skoge@chemeng.ntnu.no) #12;Abstract The naphtha reforming process converts low-octane gasoline blending compo- nents to high cases. #12;1 Introduction The naphtha reforming process converts low-octane gasoline blending compo-octane components for use in high-performance gasoline fuels. The reformer also has an important function

Skogestad, Sigurd

190

Land Reform and Exclusion of Poor Jagat Basnet  

E-Print Network (OSTI)

of effective land management, land administration and all land reform processes interrelated, by land reform, it is widely understood to be a process of confiscating someone's land and award or with the land reform because of historical reasons of a power nexus. 6.2 The Historical Process of Land

Richner, Heinz

191

Hydrogen Production by Low-temperature Steam Reforming of Bio-oil over Ni/HZSM-5 Catalyst  

Science Journals Connector (OSTI)

We investigated high catalytic activity of Ni/HZSM-5 catalysts synthesized by the impregnation method, which was successfully applied for low-temperature steam reforming of bio-oil. The influences of the catalyst composition, reforming temperature and the molar ratio of steam to carbon fed on the stream reforming process of bio-oil over the Ni/HZSM-5 catalysts were investigated in the reforming reactor. The promoting effects of current passing through the catalyst on the bio-oil reforming were also studied using the electrochemical catalytic reforming approach. By comparing Ni/HZSM-5 with commonly used Ni/Al2O3 catalysts, the Ni20/ZSM catalyst with Ni-loading content of about 20% on the HZSM-5 support showed the highest catalytic activity. Even at 450 °C, the hydrogen yield of about 90% with a near complete conversion of bio-oil was obtained using the Ni20/ZSM catalyst. It was found that the performance of the bio-oil reforming was remarkably enhanced by the HZSM-5 supporter and the current through the catalyst. The features of the Ni/HZSM-5 catalysts were also investigated via X-ray diffraction, inductively coupled plasma and atomic emission spectroscopy, hydrogen temperature-programmed reduction, and Brunauer-Emmett-Teller methods.

Song-bai Qiu; Lu Gong; Lu Liu; Cheng-gui Hong; Li-xia Yuan; Quan-xin Li

2011-01-01T23:59:59.000Z

192

Experimental and computational investigations of sulfur-resistant bimetallic catalysts for reforming of biomass gasification products  

SciTech Connect

A combination of density functional theory (DFT) calculations and experimental studies of supported catalysts was used to identify H{sub 2}S-resistant biomass gasification product reforming catalysts. DFT calculations were used to search for bimetallic, nickel-based (1 1 1) surfaces with lower sulfur adsorption energies and enhanced ethylene adsorption energies. These metrics were used as predictors for H{sub 2}S resistance and activity toward steam reforming of ethylene, respectively. Relative to Ni, DFT studies found that the Ni/Sn surface alloy exhibited enhanced sulfur resistance and the Ni/Ru system exhibited an improved ethylene binding energy with a small increase in sulfur binding energy. A series of supported bimetallic nickel catalysts was prepared and screened under model ethylene reforming conditions and simulated biomass tar reforming conditions. The observed experimental trends in activity were consistent with theoretical predictions, with observed reforming activities in the order Ni/Ru > Ni > Ni/Sn. Interestingly, Ni/Ru showed a high level of resistance to sulfur poisoning compared with Ni. This sulfur resistance can be partly explained by trends in sulfur versus ethylene binding energy at different types of sites across the bimetallic surface.

Rangan, Meghana; Yung, Matthew M.; Medlin, J. William (NREL); (Colorado)

2011-11-17T23:59:59.000Z

193

Alternative technologies to steam-methane reforming  

SciTech Connect

Steam-methane reforming (SMR) has been the conventional route for hydrogen and carbon monoxide production from natural gas feedstocks. However, several alternative technologies are currently finding favor for an increasing number of applications. The competing technologies include: steam-methane reforming combined with oxygen secondary reforming (SMR/O2R); autothermal reforming (ATR); thermal partial oxidation (POX). Each of these alternative technologies uses oxygen as a feedstock. Accordingly, if low-cost oxygen is available, they can be an attractive alternate to SMR with natural gas feedstocks. These technologies are composed technically and economically. The following conclusions can be drawn: (1) the SMR/O2R, ATR and POX technologies can be attractive if low-cost oxygen is available; (2) for competing technologies, the H{sub 2}/CO product ratio is typically the most important process parameter; (3) for low methane slip, the SMR/O2R, ATR and POX technologies are favored; (4) for full CO{sub 2} recycle, POX is usually better than ATR; (5) relative to POX, the ATR is a nonlicensed technology that avoids third-party involvement; (6) economics of each technology are dependent on the conditions and requirements for each project and must be evaluated on a case-by-case basis.

Tindall, B.M.; Crews, M.A. [Howe-Baker Engineers, Inc., Tyler, TX (United States)

1995-11-01T23:59:59.000Z

194

Low severity hydrocarbon steam reforming process  

SciTech Connect

A process is described for producing ammonia which comprises: (a) primary catalytically reforming at super atmospheric pressure in a direct-fired primary reforming zone, a hydrocarbon feedstock with steam to produce a gas containing carbon oxides, hydrogen and methane; (b) secondary catalytically reforming the gas from step (a) by introducing air and bringing the mixture towards equilibrium thereby producing a secondary reformer effluent gas containing nitrogen, carbon oxides, hydrogen and a decreased quantity of methane; (c) converting carbon monoxide catalytically with steam to carbon dioxide and hydrogen; (d) removing carbon oxides to give an ammonia synthesis gas comprising nitrogen and hydrogen and compressing the gas to ammonia synthesis pressure; (e) reacting the synthesis gas in an ammonia synthesis zone to produce ammonia and recovering ammonia from the reacted gas to produce an ammonia-depleted gas stream; (f) recycling at least a portion of the ammonia-depleted gas stream to the ammonia synthesis zone; and (g) treating a sidestream of the ammonia-depleted gas to separate a stream enriched in hydrogen and an inerts-enriched gas stream, and returning the enriched hydrogen stream to the ammonia synthesis zone.

Osman, R.M.; Byington, R.G.

1986-06-03T23:59:59.000Z

195

Affordable Care Act & Medicaid Reform in Wisconsin  

E-Print Network (OSTI)

Affordable Care Act & Medicaid Reform in Wisconsin Enrollment Trends Chartpack 2013-2014 ACA Open,731 Wisconsinites Living in Poverty Access Health Care Through Medicaid," Press Release, May 19, 2014. http://walker.wi.gov/newsroom/press-release/81731-wisconsinites-living-poverty-access-health-care-through- Medicaid Medicaid & CHIP: April 2014

Sheridan, Jennifer

196

Cost Analysis of Bio-Derived Liquids Reforming (Presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

Analysis of Analysis of Bio-Derived Liquids Reforming Brian James Directed Technologies, Inc. 6 November 2007 This presentation does not contain any proprietary, confidential, or otherwise restricted information Objective * Assess cost of H 2 from bio-derived liquids * Looking at forecourt scale systems: 100-1500kg/day * Emphasis on Ethanol * Looking at both "conventional" and "advanced" systems * Interaction with the Researchers is bi-directional * Researchers help me with catalysts, performance, configurations * I can assist Researchers with system studies, configurations, and system performance estimates * Output of my work will be: * System/Configuration Definition * Performance specification & optimization * Capital cost estimation

197

Evaluation of the economic and environmental impact of combining dry reforming with steam reforming of methane  

Science Journals Connector (OSTI)

Lately, there has been considerable interest in the development of more efficient processes to generate syngas, an intermediate in the production of fuels and chemicals, including methanol, dimethyl ether, ethylene, propylene and Fischer–Tropsch fuels. Steam methane reforming (SMR) is the most widely applied method of producing syngas from natural gas. Dry reforming of methane (DRM) is a process that uses waste carbon dioxide to produce syngas from natural gas. Dry reforming alone has not yet been implemented commercially; however, a combination of steam methane reforming and dry reforming of methane (SMR + DRM) has been used in industry for several years. The aim of this work was to simulate both the SMR and SMR + DRM processes and to conduct an economic and environmental analysis to determine whether the SMR + DRM process is competitive with the more popular SMR process. The results indicate that the SMR + DRM process has a lower carbon footprint. Further research on DRM catalysts could make this process economically competitive with steam methane reforming.

Preeti Gangadharan; Krishna C. Kanchi; Helen H. Lou

2012-01-01T23:59:59.000Z

198

Income distribution effects of the Swedish 1991 tax reform: An analysis of a microsimulation using generalized Kakwani decomposition  

Science Journals Connector (OSTI)

In 1991 a major tax reform was implemented in Sweden. This study compares the income equalization (income redistribution), vertical and horizontal equity properties of the pre- and post-reform tax and transfer systems. The method used is a decomposition, first proposed by Kakwani (1984), of the difference between the generalized Gini coefficients of the pre- and post-tax/transfer income distributions. The post-reform income distribution was obtained through a microsimulation carried out by the Ministry of Finance. Several findings on the income distribution effect of the 1991 tax and benefit reform emerge from the study. The overall methodological conclusion is that much more information was gained when different generalizations of the decomposition were considered.

Mårten Palme

1996-01-01T23:59:59.000Z

199

Bio-Derived Liquids to Hydrogen Distributed Reforming Targets (Presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

Distributed Reforming Targets Arlene F. Anderson Technology Development Manager, U.S. DOE Office of Energy Efficiency and Renewable Energy Hydrogen, Fuel Cells and Infrastructure Technologies Program Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group and Hydrogen Production Technical Team Review November 6, 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) The Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG), launched in October 2006, provides a forum for effective communication and collaboration among participants in DOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program (HFCIT) cost-shared research directed at distributed bio-liquid reforming. The Working Group includes

200

March 16, 2010, Safety and Security Reform Roundtable - Agenda  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Safety and Security Reform Roundtable Safety and Security Reform Roundtable Forrestal Building, Washington, DC March 16 th , 2010 1:00 PM (EST) AGENDA * Introduction of Union Leaders Glenn Podonsky, Chief Health, Safety and Security Officer * Welcome/Introductory Remarks on Reform Goals Dan Poneman, Deputy Secretary * Reform Status and Approach - Oversight, Directives, Mission Support Glenn Podonsky, Chief Health, Safety and Security Officer * Discussion Forum - Union Feedback - Feedback on oversight reform initiatives - Priority safety issues - Experience in collaborative focus group efforts - Recommendations for a path forward * Operating Organization Perspectives 1. Tom D'Agostino Administrator, National Nuclear Security Administration 2. Steven Koonin Under Secretary for Science

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Commercial treatability study capabilities for application to the US Department of Energy`s anticipated mixed waste streams  

SciTech Connect

The U.S. Department of Energy (DOE) has established the Mixed Waste Focus Area (MWFA), which represents a national effort to develop and coordinate treatment solutions for mixed waste among all DOE facilities. The hazardous waste component of mixed waste is regulated under the Resource Conservation and Recovery Act (RCRA), while the radioactive component is regulated under the Atomic Energy Act, as implemented by the DOE, making mixed waste one of the most complex types of waste for the DOE to manage. The MWFA has the mission to support technologies that meet the needs of the DOE`s waste management efforts to characterize, treat, and dispose of mixed waste being generated and stored throughout the DOE complex. The technologies to be supported must meet all regulatory requirements, provide cost and risk improvements over available technologies, and be acceptable to the public. The most notable features of the DOE`s mixed-waste streams are the wide diversity of waste matrices, volumes, radioactivity levels, and RCRA-regulated hazardous contaminants. Table 1-1 is constructed from data from the proposed site treatment plans developed by each DOE site and submitted to DOE Headquarters. The table shows the number of mixed-waste streams and their corresponding volumes. This table illustrates that the DOE has a relatively small number of large-volume mixed-waste streams and a large number of small-volume mixed-waste streams. There are 1,033 mixed-waste streams with volumes less than 1 cubic meter; 1,112 mixed-waste streams with volumes between 1 and 1,000 cubic meters; and only 61 mixed-waste streams with volumes exceeding 1,000 cubic meters.

NONE

1996-07-01T23:59:59.000Z

202

Effects of Current on Microcosmic Properties of Catalyst and Reforming of Bio-oil  

Science Journals Connector (OSTI)

Highly effective production of hydrogen from bio-oil was achieved by using a low-temperature electrochemical catalytic reforming approach over the conventional Ni-based reforming catalyst (NiO-Al2O3), where an AC electronic current passed through the catalyst bed. The promoting effects of current on the bio-oil reforming were studied. It was found that the performance of the bio-oil reforming was remarkably enhanced by the current which passed through the catalyst. The effects of currents on the microcosmic properties of the catalyst, including the Brunauer–Emmett–Teller (BET) surface area, pore diameter, pore volume, the size of the crystallites and the reduction level of NiO into Ni, were carefully characterized by BET, X-ray diffraction, X-ray photoelectron spectroscopy, and scanning electron microscope. The desorption of the thermal electrons from the electrified catalyst was directly observed by the TOF (time of flight) measurements. The mechanism of the electrochemical catalytic reforming of bio-oil is discussed based on the above investigation.

Li-xia Yuan; Tong-qi Ye; Fei-yan Gong; Quan-xin Li

2009-01-01T23:59:59.000Z

203

Catalytic performances of Ni–CaO–mayenite in CO2 sorption enhanced steam methane reforming  

Science Journals Connector (OSTI)

Abstract Ni–CaO–mayenite (Ca12Al14O33) catalysts for the CO2 Sorption Enhanced Steam Methane Reforming (SE-SMR) have been developed using the microwave assisted self-combustion method of preparation. The sorption of CO2 by CaO shifts the steam reforming and the Water Gas Shift reaction (WGS) towards H2 production and favors the heat balance of the global reaction. The CO2 sorption has been studied on materials with different CaO/Ca12Al14O33 ratios and for different types of preparation. The specific surface area of materials, the temperature of Ni phases' reducibility and CO2 sorption are all essential for material efficiency. The Ni–CA75MM catalyst was the most active and stable in methane steam reforming with CO2 sorption, even at an unusually low temperature (650 °C).

Moisés R. Cesário; Braúlio S. Barros; Claire Courson; Dulce M.A. Melo; Alain Kiennemann

2015-01-01T23:59:59.000Z

204

Steam reforming on transition-metal carbides from density-functional theory  

E-Print Network (OSTI)

A screening study of the steam reforming reaction (CH_4 + H_2O -> CO + 3H_2) on early transition-metal carbides (TMC's) is performed by means of density-functional theory calculations. The set of considered surfaces includes the alpha-Mo_2C(100) surfaces, the low-index (111) and (100) surfaces of TiC, VC, and delta-MoC, and the oxygenated alpha-Mo_2C(100) and TMC(111) surfaces. It is found that carbides provide a wide spectrum of reactivities towards the steam reforming reaction, from too reactive via suitable to too inert. The reactivity is discussed in terms of the electronic structure of the clean surfaces. Two surfaces, the delta-MoC(100) and the oxygen passivated alpha-Mo_2C(100) surfaces, are identified as promising steam reforming catalysts. These findings suggest that carbides provide a playground for reactivity tuning, comparable to the one for pure metals.

Vojvodic, Aleksandra

2009-01-01T23:59:59.000Z

205

Modified Ni-Cu catalysts for ethanol steam reforming  

SciTech Connect

Three Ni-Cu catalysts, having different Cu content, supported on ?-alumina were synthesized by wet co-impregnation method, characterized and tested in the ethanol steam reforming (ESR) reaction. The catalysts were characterized for determination of: total surface area and porosity (N{sub 2} adsorption - desorption using BET and Dollimer Heal methods), Ni surface area (hydrogen chemisorption), crystallinity and Ni crystallites size (X-Ray Diffraction), type of catalytic active centers (Hydrogen Temperature Programmed Reduction). Total surface area and Ni crystallites size are not significantly influenced by the addition of Cu, while Ni surface area is drastically diminished by increasing of Cu concentration. Steam reforming experiments were performed at atmospheric pressure, temperature range 150-350°C, and ethanol - water molar ration of 1 at 30, using Ar as carrier gas. Ethanol conversion and hydrogen production increase by the addition of Cu. At 350°C there is a direct connection between hydrogen production and Cu concentration. Catalysts deactivation in 24h time on stream was studied by Transmission Electron Microscopy (TEM) and temperature-programmed reduction (TPR) on used catalysts. Coke deposition was observed at all studied temperatures; at 150°C amorphous carbon was evidenced, while at 350°C crystalline, filamentous carbon is formed.

Dan, M.; Mihet, M.; Almasan, V.; Borodi, G. [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Street, 400293, Cluj-Napoca (Romania)] [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Street, 400293, Cluj-Napoca (Romania); Katona, G.; Muresan, L. [Univ. Babes Bolyai, Fac. Chem. and Chem. Eng.,11 Arany Janos, 400028, Cluj-Napoca (Romania)] [Univ. Babes Bolyai, Fac. Chem. and Chem. Eng.,11 Arany Janos, 400028, Cluj-Napoca (Romania); Lazar, M. D., E-mail: diana.lazar@itim-cj.ro [65-103 Donath Street (Romania)

2013-11-13T23:59:59.000Z

206

Simulation of steam reformers for methane  

Science Journals Connector (OSTI)

A model is developed for industrial steam reformers for both top fired and side fired furnaces. The catalyst tube model is a one-dimensional heterogeneous model with intra-particle diffusional resistances. The two point boundary value differential equations of the catalyst pellets are solved using a modified novel orthogonal collocation technique to obtain the effectiveness factor variation along the length of the reactor. The side fired furnace equations are algebraic equations, the top fired furnace equations are two-point boundary value differential equations which are solved using the orthogonal collocation technique. A recently developed more general rate expression is used. The model performance is checked against industrial steam reformers. The model is used to investigate the effect of various parameters on the behaviour of the catalyst tubes and the furnace. The effectiveness factor variation along the length of the catalyst tube is also analysed.

M.A. Soliman; S.S.E.H. El-Nashaie; A.S. Al-Ubaid; A. Adris

1988-01-01T23:59:59.000Z

207

The Cost Implications of Health Care Reform  

Science Journals Connector (OSTI)

...health insurance coverage. But there is concern about its implications for health care costs. These concerns have been heightened by a recent report from the actuary at the Centers for Medicare and Medicaid Services (CMS), which shows that health care reform will cause an expansion of national health... Jonathan Gruber argues that by the second decade, the Patient Protection and Affordable Care Act will have reduced national health care spending.

Gruber J.

2010-06-03T23:59:59.000Z

208

An experimental study of a heatexchanger-type steam reformer with a low steam/carbon ratio. Effect of carbon deposition on the distribution of flow among the catalyst tubes and of temperature among and along the tubes  

SciTech Connect

An experimental heat-exchanger-type steam reformer containing eight full-sized tubes of catalyst was operated at low steam/carbon ratios up to the point of onset of carbon deposition. The following phenomena were investigated: the effect of carbon deposition on the distribution of the gas stream among the tubes, the effect of this distribution on the nonuniformity of temperature on the outer surface of the tubes, and the distribution of carbon deposition in the beds of catalyst. At steam/carbon ratios close to the onset of carbon deposition, the average pressure differential through the tubes rose at a rate of 0.1-0.5 kg/cm/sup 2/ . hr. The temperature at the bottom of the catalyst tubes varied about 10 /sup 0/C due to the deposition of carbon. Most of the carbon is deposited within about 1,000 mm from the top of the bed.

Miyasuai T; Kosaka, S.; Suzuki, A.; Yoshioka, S.

1985-07-01T23:59:59.000Z

209

Increased Use of the Emergency Department After Health Care Reform in Massachusetts  

Science Journals Connector (OSTI)

Study objective With implementation of the Patient Protection and Affordable Care Act, 30 million individuals are predicted to gain access to health insurance. The experience in Massachusetts, which implemented a similar reform beginning in 2006, should provide important lessons about the effect of health care reform on emergency department (ED) utilization. Our objective is to understand the extent to which Massachusetts health care reform was associated with changes in ED utilization. Methods We compared changes in ED utilization at the population level for individuals from areas of the state that were affected minimally by health care reform with those from areas that were affected the most, as well as for those younger than 65 years and aged 65 years or older. We used a difference-in-differences identification strategy to compare rates of ED visits in the prereform period, during the reform, and in the postreform period. Because we did not have population-level data on insurance status, we estimated area-level insurance rates by using the percentage of actual visits made during each period by individuals with insurance. Results We studied 13.3 million ED visits during 2004 to 2009. Increasing insurance coverage in Massachusetts was associated with increasing use of the ED; these results were consistent across all specifications, including the younger than 65 years versus aged 65 years or older comparison. Depending on the model used, the implementation of health care reform was estimated to result in an increase in ED visits per year of between 0.2% and 1.2% within reform and 0.2% and 2.2% postreform compared with the prereform period. Conclusion The implementation of health care reform in Massachusetts was associated with a small but consistent increase in the use of the ED across the state. Whether this was due to the elimination of financial barriers to seeking care in the ED, a persistent shortage in access to primary care for those with insurance, or some other cause is not entirely clear and will need to be addressed in future research.

Peter B. Smulowitz; James O’Malley; Xiaowen Yang; Bruce E. Landon

2014-01-01T23:59:59.000Z

210

Thermodynamic investigation and environment impact assessment of hydrogen production from steam reforming of poultry tallow  

Science Journals Connector (OSTI)

Abstract In this research, various assessment tools are applied to comprehensively investigate hydrogen production from steam reforming of poultry tallow (PT). These tools investigate the chemical reactions, design and simulate the entire hydrogen production process, study the energetic performance and perform an environment impact assessment using life cycle assessment (LCA) methodology. The chemical reaction investigation identifies thermodynamically optimal operating conditions at which PT may be converted to hydrogen via the steam reforming process. The synthesis gas composition was determined by simulations to minimize the Gibbs free energy using the Aspen Plus™ 10.2 software. These optimal conditions are, subsequently, used in the design and simulation of the entire PT-to-hydrogen process. LCA is applied to evaluate the environmental impacts of PT-to-hydrogen system. The system boundaries include rendering and reforming along with the required transportation process. The reforming inventories data are derived from process simulation in Aspen Plus™, whereas the rendering data are adapted from a literature review. The life cycle inventories data of PT-to-hydrogen are computationally implemented into SimaPro 7.3. A set of seven relevant environmental impact categories are evaluated: global warming, abiotic depletion, acidification, eutrophication, ozone layer depletion, photochemical oxidant formation, and cumulative non-renewable fossil and nuclear energy demand. The results are subject to a systematic sensitivity analysis and compared to those calculated for hydrogen production from conventional steam methane reforming. The LCA results indicate that the thermal energy production process is the main contributor to the selected environmental impact categories. Improvement actions to minimize the reforming thermal energy and the transport distance are strongly recommended as they would lead to relevant environmental improvements.

Noureddine Hajjaji

2014-01-01T23:59:59.000Z

211

Supported nickel catalysts for low temperature methane steam reforming: comparison between metal additives and support modification  

Science Journals Connector (OSTI)

The effect of Ag (1 wt%) and Au (1 wt%) on the catalytic properties of Ni/Al2O3 (7 wt% Ni) for methane steam reforming (MSR) was studied in parallel with...2 (6 wt%) and La2O3 (6 wt%) addition. The addition of 1 ...

Monica Dan; Maria Mihet; Alexandru R. Biris…

2012-02-01T23:59:59.000Z

212

The causal effect of retirement on health: New evidence from Australian pension reform  

Science Journals Connector (OSTI)

Abstract The causal effect of retirement on health is studied using the Australian 1993 Age Pension reform to isolate exogenous variation in retirement status. Using instrumental variable methods we find that retirement has a positive impact on subjective and objective measures of health.

Kadir Atalay; Garry F. Barrett

2014-01-01T23:59:59.000Z

213

The Effect of Reformate on PEM Fuel Cell Performance Mahesh Murthy  

E-Print Network (OSTI)

Exchanged Membrane (PEM) fuel cells in a "hydrogen-challenged" economy, hydrogen can be produced contains about 35 - 40 % hydrogen [1]. The effects of reformate fuel on the performance of PEM fuel cells in hydrogen for a laboratory polymer electrolyte membrane fuel cell [3, 4]. In these earlier studies

Van Zee, John W.

214

Methods of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts  

NLE Websites -- All DOE Office Websites (Extended Search)

of Reforming Hydrocarbon Fuels Using of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts Contact NETL Technology Transfer Group techtransfer@netl.doe.gov May 2012 Opportunity Research is currently active on the technology "Methods of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts." The technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview This invention discloses a method to reform hydrocarbon fuels using hexa- aluminate catalysts. In general, the method successfully disrupts the forma- tion of carbon that leads to the deactivation of the catalyst, a key element in the reforming of hydrocarbon fuels. When researchers are designing catalysts to reform hydrocarbon fuels, one

215

Structural and regulatory reform in Turkey: Lessons form public utilities  

Science Journals Connector (OSTI)

Abstract Turkey is one of the countries that recently initiated regulatory reform in public utilities. Although Turkey tried to introduce competition to many industries through a liberalization movement that started in the 1980s, utilities remained as monopolies until the early 2000s. In the beginning of the 2000s, reforms restructured the utilities through deregulation and competition policies and established independent regulatory agencies. Whereas the reforms have been successful in some aspects, they remain insufficient in others. This paper anecdotally investigates the effects of (de)regulation on selected public utility industries and analyzes the pros and cons of the reform process. Also, it presents a comparative analysis to better understand the current institutional and governmental issues in the reform process. The findings suggest that the recently changing stance of government towards the (de)regulatory process could thwart the success of reform.

Tamer Çetin

2014-01-01T23:59:59.000Z

216

Improved System Performance and Reduced Cost of a Fuel Reformer...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Improved System Performance and Reduced Cost of a Fuel Reformer, LNT, and SCR Aftertreatment System Meeting Emissions Useful Life Requirement Damodara Poojary, Jacques Nicole,...

217

Solar Steam Reforming of Methane (SSRM) Program Proposals  

Science Journals Connector (OSTI)

Within the intended development work to supply solar HT process heat to industrial processes, especially chemical processes, the steam reforming process is considered suitable in particular.

A. Kalt

1987-01-01T23:59:59.000Z

218

Improved System Performance and Reduced Cost of a Fuel Reformer...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Improved System Performance and Reduced Cost of a Fuel Reformer, LNT, and SCR Aftertreatment System Meeting Emissions Useful Life Requirement Improved System Performance and...

219

Review of Trajectories of Chemistry Education Innovation and Reform  

Science Journals Connector (OSTI)

Review of Trajectories of Chemistry Education Innovation and Reform ... Trajectories of Chemistry Education Innovation and Reform began as a symposium at an American Chemical Society (ACS) meeting, honoring the efforts of Susan Hixon on the occasion of her retirement from the position of program officer in the Division of Undergraduate Education at the National Science Foundation (NSF). ... In addition to providing the reader with an overview of the history of chemical education as a research field, this book summarizes reform efforts in areas of curriculum design, pedagogical tools, and institutional reform. ...

Brittland K. DeKorver

2014-10-22T23:59:59.000Z

220

Bio-Derived Liquids to Hydrogen Distributed Reforming Targets  

Energy.gov (U.S. Department of Energy (DOE))

Presentation by Arlene Anderson at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

FUEL CELLS – SOLID OXIDE FUEL CELLS | Internal and External Reformation  

Science Journals Connector (OSTI)

Three basic concepts of solid oxide fuel cell (SOFC) systems operating on hydrocarbon fuels, with external, internal, and partial prereforming, respectively, are presented and discussed. Internal reforming of methane is advantageously used for additional cooling of the SOFC stack, thus increasing system efficiency. Basic thermodynamics, catalysis, and kinetics of the methane steam reforming process are presented. Examples of SOFC stacks operating on internal reforming of methane and simulated partial prereforming of mine gas and natural gas are discussed. The latter is used to illustrate the effect of internal methane reforming on heat management in SOFC stacks.

L.G.J. de Haart; R. Peters

2009-01-01T23:59:59.000Z

222

Bio-Derived Liquids to Hydrogen Distributed Reforming Targets (Presentation)  

Energy.gov (U.S. Department of Energy (DOE))

Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

223

Assuring Equity Through Health and Health Care Reform Conference Registration Information (Type or Print)  

E-Print Network (OSTI)

Assuring Equity Through Health and Health Care Reform Conference Registration Information (Type Care Structural Reform: What's Happening in Albany and Washington? Changing the Social Determinants of Health Reform in the Pharmaceutical Industry Sustaining Community Health Workers Comparative

Brown, Lucy L.

224

Aligning modes of organization with technology: Critical transactions in the reform of infrastructures  

E-Print Network (OSTI)

1 Aligning modes of organization with technology: Critical transactions in the reform of their reform. Since infrastructures are characterized by strong technical complementarities, we explore the alignment between organization and technology and should be taken explicitly into account when reforming

Boyer, Edmond

225

Edinburgh Research Explorer Reforming State Pension provision in `Liberal' Anglo Saxon  

E-Print Network (OSTI)

Edinburgh Research Explorer Reforming State Pension provision in `Liberal' Anglo Saxon Countries, Vickerstaff, S & Loretto, W 2012, 'Reforming State Pension provision in `Liberal' Anglo Saxon Countries: Re University Press. Lain, D., Vickerstaff, S. & Loretto, W. 2012, "Reforming State Pension provision

Millar, Andrew J.

226

Reforming the EU: The Future of European Law and Policy IV CONFERENCE PROGRAMME  

E-Print Network (OSTI)

Reforming the EU: The Future of European Law and Policy IV CONFERENCE session "Reforming the EU" Chair: Dr Luca Rubini, Deputy Director Institute Rubini Reforming European competition law: should the European Commission have

Birmingham, University of

227

NEPA Contracting Reform Guidance (December 1996)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

defining early what contractors should accomplish defining early what contractors should accomplish < establishing contracts ahead of time < minimizing cost while maintaining quality by * maximizing competition and use of incentives * using past performance information in awarding work * managing the NEPA process as a project This guidance provides: < model statements of work < information on contract types and incentives < direction on effective NEPA contract management by the NEPA Document Manager < a system for measuring NEPA process costs < NEPA contractor evaluation procedures < details on the DOE NEPA Web site U.S. Department of Energy, Office of NEPA Policy and Assistance, December 1996 NEPA CONTRACTING REFORM GUIDANCE Table of Contents 1. INTRODUCTION . . . . . . . . . . . . . . . . . . . . . .

228

Autothermal Reforming of Renewable Fuels  

SciTech Connect

The conversion of biomass into energy and chemicals is a major research and technology challenge of this century, comparable to petroleum processing in the last century. Recently we have successfully transformed both volatile liquids and nonvolatile liquids and solids into syngas with no carbon formation in autothermal catalytic reactors with residence times of ~10 milliseconds. In the proposed research program we explore the mechanisms of these processes and their extensions to other biomass sources and applications by examining different feeds, catalysts, flow conditions, and steam addition to maximize production of either syngas or chemicals. We will systematically study the catalytic partial oxidation in millisecond autothermal reactors of solid biomass and the liquid products formed by pyrolysis of solid biomass. We will examine alcohols, polyols, esters, solid carbohydrates, and lignocellulose to try to maximize formation of either hydrogen and syngas or olefins and oxygenated chemicals. We will explore molecules and mixtures of practical interest as well as surrogate molecules that contain the functional groups of biofuels but are simpler to analyze and interpret. We will examine spatial profiles within the catalyst and transient and periodic operation of these reactors at pressures up to 10 atm to obtain data from which to explore more detailed mechanistic models and optimize performance to produce a specific desired product. New experiments will examine the conversion of syngas into biofuels such as methanol and dimethyl ether to explore the entire process of producing biofuels from biomass in small distributed systems. Experiments and modeling will be integrated to probe and understand detailed reaction kinetics and the processes by which solid biomass particles are transformed into syngas and chemicals by reactive flash volatilization.

Schmidt, Lanny D

2009-05-01T23:59:59.000Z

229

Experimental and Numerical Observations of Hydrate Reformation during Depressurization in a Core-Scale Reactor  

SciTech Connect

Gas hydrate has been predicted to reform around a wellbore during depressurization-based gas production from gas hydrate-bearing reservoirs. This process has an adverse effect on gas production rates and it requires time and sometimes special measures to resume gas flow to producing wells. Due to lack of applicable field data, laboratory scale experiments remain a valuable source of information to study hydrate reformation. In this work, we report laboratory experiments and complementary numerical simulations executed to investigate the hydrate reformation phenomenon. Gas production from a pressure vessel filled with hydrate-bearing sand was induced by depressurization with and without heat flux through the boundaries. Hydrate decomposition was monitored with a medical X-ray CT scanner and pressure and temperature measurements. CT images of the hydrate-bearing sample were processed to provide 3-dimensional data of heterogeneous porosity and phase saturations suitable for numerical simulations. In the experiments, gas hydrate reformation was observed only in the case of no-heat supply from surroundings, a finding consistent with numerical simulation. By allowing gas production on either side of the core, numerical simulations showed that initial hydrate distribution patterns affect gas distribution and flow inside the sample. This is a direct consequence of the heterogeneous pore network resulting in varying hydraulic properties of the hydrate-bearing sediment.

Seol, Yongkoo; Myshakin, Evgeniy

2011-01-01T23:59:59.000Z

230

Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol  

SciTech Connect

Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the fourth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of July 1-Sept 30, 2004 along with a recap of progress from the start of the project on Oct 1, 2003 to Sept 30, 2004. All of the projects are proceeding on or slightly ahead of schedule. This year saw progress in several areas. These areas are: (1) External and internal evaluation of coal based methanol and a fuel cell grade baseline fuel, (2) Design set up and initial testing of three laboratory scale steam reformers, (3) Design, set up and initial testing of a laboratory scale autothermal reactor, (4) Hydrogen generation from coal-derived methanol using steam reformation, (5) Experiments to determine the axial and radial thermal profiles of the steam reformers, (6) Initial catalyst degradation studies with steam reformation and coal based methanol, and (7) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2004-09-30T23:59:59.000Z

231

E-Print Network 3.0 - act contracting reform Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

US Pricing Basics and What to Expect from Healthcare Reform By Jack Mycka... health care reform and pricing 12;3 MME LLC 2010 Applied Pharmacoeconomics and Outcomes...

232

Socioeconomic differences in self-rated oral health and dental care utilisation after the dental care reform in 2008 in Sweden  

Science Journals Connector (OSTI)

The aims of this study were to determine self-rated oral health and dental attendance habits among Swedish adults, ... of social inequalities, after the Swedish dental care reform in 2008.

Anu Molarius; Sevek Engström; Håkan Flink; Bo Simonsson; Åke Tegelberg

2014-11-01T23:59:59.000Z

233

Effects of Current upon Electrochemical Catalytic Reforming of Anisole  

Science Journals Connector (OSTI)

The reforming of anisole (as model compound of bio-oil) was performed over the NiCuZn-Al2O3 catalyst, using a recently-developed electrochemical catalytic reforming (ECR). The influence of the current on the anisole reforming in the ECR process has been investigated. It was observed that anisole reforming was significantly enhanced by the current approached over the catalyst in the electrochemical catalytic process, which was due to the non-uniform temperature distribution in the catalytic bed and the role of the thermal electrons originating from the electrified wire. The maximum hydrogen yield of 88.7% with a carbon conversion of 98.3% was obtained through the ECR reforming of anisole at 700°C and 4 A. X-ray diffraction was employed to characterize catalyst features and their alterations in the anisole reforming. The apparent activation energy for the anisole reforming is calculated as 99.54 kJ/mol, which is higher than ethanol, acetic acid, and light fraction of bio-oil. It should owe to different physical and chemical properties and reforming mechanism for different hydrocarbons.

Jia-xing Xiong; Tao Kan; Xing-long Li; Tong-qi Ye; Quan-xin Li

2010-01-01T23:59:59.000Z

234

ISSN 1745-9648 Potential Impact of Electricity Reforms on  

E-Print Network (OSTI)

ISSN 1745-9648 Potential Impact of Electricity Reforms on Turkish Households by Necmiddin Finance, Hacettepe University & Catherine Waddams Price ESRC Centre for Competition Policy and Norwich the potential effect of electricity reform on different households, using a series of potential scenarios

Feigon, Brooke

235

Steam reforming of fuel to hydrogen in fuel cells  

SciTech Connect

A fuel cell is claimed capable of utilizing a hydrocarbon such as methane as fuel and having an internal dual catalyst system within the anode zone, the dual catalyst system including an anode catalyst supporting and in heat conducting relationship with a reforming catalyst with heat for the reforming reaction being supplied by the reaction at the anode catalyst.

Fraioli, A.V.; Young, J.E.

1984-06-12T23:59:59.000Z

236

Data reconciliation and optimal operation of a catalytic naphtha reformer  

E-Print Network (OSTI)

-mail:skoge@chemeng.ntnu.no) #12;Abstract The naphtha reforming process converts low-octane gasoline blending compo- nents to high process converts low-octane gasoline blending compo- nents to high-octane components for use in high-octane components for use in high-performance gasoline fuels. The reformer also has a important function

Skogestad, Sigurd

237

Health Care Reform Challenge: Creating a High Performance Healthcare System  

E-Print Network (OSTI)

Health Care Reform Challenge: Creating a High Performance Healthcare System Tom Simmer, MD Chief;The Challenge of Reform: Accountable Care Organizations (ACO) · ACO's are provider organizations health care delivery Organized Systems of Care Population focus for primary care physicians, hospitals

Finley Jr., Russell L.

238

ISSN 1745-9648 Electricity Sector Reform in Greece  

E-Print Network (OSTI)

ISSN 1745-9648 Electricity Sector Reform in Greece by Ekaterini Iliadou Lawyer - Legal Department of the electricity market reform in Greece which started in 2001 and is still developing slowly. This is related to the persisting dominance of the incumbent company and the specificities of the electricity sector of Greece

Feigon, Brooke

239

University of Glasgow -1-Reform of Peer Review: Response to  

E-Print Network (OSTI)

University of Glasgow -1- Reform of Peer Review: Response to Consultation Introduction & Summary The University of Glasgow welcomes the opportunity to comment on these proposals for the reform of peer review and the introduction of processes to scrutinise the economic impact of research within the peer review process and we

Glasgow, University of

240

Steam reforming of fuel to hydrogen in fuel cells  

DOE Patents (OSTI)

A fuel cell capable of utilizing a hydrocarbon such as methane as fuel and having an internal dual catalyst system within the anode zone, the dual catalyst system including an anode catalyst supporting and in heat conducting relationship with a reforming catalyst with heat for the reforming reaction being supplied by the reaction at the anode catalyst.

Fraioli, Anthony V. (Hawthorne Woods, IL); Young, John E. (Woodridge, IL)

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Steam reforming of fuel to hydrogen in fuel cell  

DOE Patents (OSTI)

A fuel cell is described capable of utilizing a hydrocarbon such as methane as fuel and having an internal dual catalyst system within the anode zone, the dual catalyst system including an anode catalyst supporting and in heat conducting relationship with a reforming catalyst with heat for the reforming reaction being supplied by the reaction at the anode catalyst.

Young, J.E.; Fraioli, A.V.

1983-07-13T23:59:59.000Z

242

Steam reforming of gasification-derived tar for syngas production  

Science Journals Connector (OSTI)

Abstract In this study, the steam reforming of tar was catalyzed by dolomite, Ni/dolomite, and Ni/CeO2 for syngas production under different reaction temperature and weight hourly space velocity (WHSV, h?1). The tar was the major side product from the biomass gasification. Current results revealed that the nickel doped catalyst on dolomite with CO2 in the feed stream yielded the highest H2 and syngas production among all reaction conditions. Comparing to the use of dolomite, when Ni–dolomites was used as catalyst, the yield of H2 increased by 33%, the yield of syngas increased by 7%, and the yield of CH4 decreased by 59%. It was also found that the yield of syngas, H2, or CO under the Ni/dolomite catalyst were significant higher (p  CO2 concentration in the feed stream > reaction temperature > weight hourly space velocity.

Alex C.-C. Chang; Lung-Shiang Chang; Cheng-You Tsai; Yu-Chun Chan

2014-01-01T23:59:59.000Z

243

Steam reforming utilizing sulfur tolerant catalyst  

SciTech Connect

This patent describes a steam reforming process for converting hydrocarbon material to hydrogen gas in the presence of sulfur which consists of: adding steam to the hydrocarbon material and passing the steam and hydrocarbon material over catalyst material at elevated temperatures. The improvement comprises utilizing as a catalyst material high activity, sulfur tolerant catalyst of platinum supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. It also describes a steam process for converting hydrocarbon material to hydrogen gas in the presence of sulfur which consists of steam to the hydrocarbon material over catalyst material at elevated temperatures. The improvement comprises utilizing as a catalyst material high activity, sulfur tolerant catalysts consisting essentially of iridium supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. In addition a steam reforming process is described for converting hydrocarbon material to hydrogen gas in the presence of sulfur comprising adding steam to the hydrocarbon material and passing the steam and hydrocarbon material over catalyst material at elevated temperatures. The improvement comprises utilizing as a catalyst material high activity sulfur tolerant catalysts consisting essentially of palladium supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina.

Setzer, H.J.; Karavolis, S.; Bett, J.A.S.

1987-09-15T23:59:59.000Z

244

Reforming Power Markets in Developing Countries | Open Energy Information  

Open Energy Info (EERE)

Reforming Power Markets in Developing Countries Reforming Power Markets in Developing Countries Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Reforming Power Markets in Developing Countries Agency/Company /Organization: World Bank Sector: Energy Focus Area: Conventional Energy, Renewable Energy Topics: Policies/deployment programs Resource Type: Publications, Lessons learned/best practices Website: siteresources.worldbank.org/INTENERGY/Resources/Energy19.pdf References: Reforming Power Markets in Developing Countries [1] Summary "This paper complements the World Bank's Operational Guidance Note by compiling lessons of this experience that help in applying the Note's guidance. These lessons are taken from the rapidly growing literature on power market reform in developing countries. They cover the range of issues

245

Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Maturation Plan (TMP) Fluidized Bed Steam Reforming Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP) Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP) This assessment determines the technology maturity level of the candidate Tank 48H treatment technologies that are being considered for implementation at DOE's SRS - specifically Fluidized Bed Steam Reformer System. Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP) More Documents & Publications Technology Maturation Plan (TMP) Wet Air Oxidation (WAO) Technology for Tank 48H Treatment Project (TTP) SRS Tank 48H Waste Treatment Project Technology Readiness Assessment

246

Steam reformers heated by helium from high temperature reactors  

Science Journals Connector (OSTI)

The manifold possibilities of the application of helium-heated steam reformers combined with high temperature nuclear reactors are elucidated in this article. It is shown that the thermodynamic interpretation of the processes does not cause difficulties because of the good heat transfer in helium at high pressure and that helium peak temperatures of 950°C are sufficient for carrying out the process. The mechanical design of the reformer tube does not lead to problems because the helium and process pressures are so chosen as to be approximately equal. The problems of hydrogen and tritium permeation as well as the contamination of the reformer tube with solid fission products seem to be solvable using the knowledge available at present. Furthermore, the various possibilities for the design arrangements of helium-heated reformer tube furnaces are shown. The status of development attained to date is outlined and in conclusion there is a survey regarding the next steps to be taken in steam reformer technology.

K. Kugeler; M. Kugeler; H.F. Niessen; K.H. Hammelmann

1975-01-01T23:59:59.000Z

247

Produce synthesis gas by steam reforming natural gas  

SciTech Connect

For production of synthesis gas from natural gas the steam reforming process is still the most economical. It generates synthesis gas for ammonia and methanol production as well as hydrogen, oxo gas and town gas. After desulfurization, the natural gas is mixed with steam and fed to the reforming furnace where decomposition of hydrocarbons takes place in the presence of a nickel-containing catalyst. Synthesis gas that must be free of CO and CO/sub 2/ is further treated in a CO shift conversion, a CO/sub 2/ scrubbing unit and a methanation unit. The discussion covers the following topics - reforming furnace; the outlet manifold system; secondary reformer; reformed gas cooling. Many design details of equipment used are given.

Marsch, H.D.; Herbort, H.J.

1982-06-01T23:59:59.000Z

248

Regulatory and Financial Reform of Federal Research Policy: Recommendations  

NLE Websites -- All DOE Office Websites (Extended Search)

and Financial Reform of Federal Research Policy: and Financial Reform of Federal Research Policy: Recommendations to the NRC Committee on Research Universities Regulatory and Financial Reform of Federal Research Policy: Recommendations to the NRC Committee on Research Universities At the request of the National Research Council (NRC) Committee on Research Universities, the Council on Governmental Relations (COGR), the Association of American Universities (AAU), and the Association of Public and Land-grant Universities (APLU) have assembled a set of ten recommendations for regulatory reform that would improve research universities' ability to carry out their missions without requiring a significant financial investment by the Federal government. Regulatory and Financial Reform of Federal Research Policy: Recommendations

249

Process Reform, Security and Suitability - December 17, 2008 | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Process Reform, Security and Suitability - December 17, 2008 Process Reform, Security and Suitability - December 17, 2008 Process Reform, Security and Suitability - December 17, 2008 December 17, 2008 This is to report on the progress made to improve the timeliness and effectiveness of our hiring and clearing decisions and the specific plan to reform the process further, in accordance with our initial proposals made in April ofthis year. In response to significant, continuing security clearance timeliness concerns, Congress called for improvements and established specific timeliness goals as part of the Intelligence Reform and Terrorism Prevention Act of 2004 (IRTPA). Since the enactment of IRTPA, average timeliness for 90 percent of all clearance determinations reported has been substantially improved, from 265 days (in 2005) to 82 days (4th Quarter,

250

Analysis of design variables for an efficient natural gas steam reforming process comprised in a small scale hydrogen fueling station  

Science Journals Connector (OSTI)

Natural gas steam reforming process comprised in a small scale H2-fueling station for on-site hydrogen production was simulated and analyzed. The effects of process variables on the process efficiency of hydrogen production were investigated, and their optimum set point values were suggested to minimize the sizes of the process sub-units and to secure a stable operability of the reforming process. Steam to carbon (S/C) ratio of the reforming reactants was found to be a crucial parameter mostly governing both the hydrogen production efficiency and the stable operability of the process. In this study, a process run was assumed stable if feed water (WR) as a reforming reactant could have been completely evaporated into dry steam through a heat recovery steam generator (HRSG). The optimum S/C ratio was 3.0 where the process efficiency of hydrogen production was maximized and the stable operability of the process was secured. The optimum feed rates of natural gas (NGR) and WR as reforming reactants and of natural gas (NGB) as a burner fuel were also determined for a target rate of hydrogen production, 27 Nm3/h. Set point temperatures of the combustion flue gas (CFG) and the reformed gas (RFG) from the reformer had no effects on the hydrogen production efficiency, however, they were important parameters affecting the stable operability of the process. The effect of the set point temperatures of the RFG from cooler and the CFG from HRSG on the hydrogen production efficiency was not much significant as compared to the S/C ratio, but needed to be adjusted because of their considerable effects on the stable operability of the process and the required heat transfer areas in cooler and HRSG.

Deuk Ki Lee; Kee Young Koo; Dong Joo Seo; Wang Lai Yoon

2012-01-01T23:59:59.000Z

251

The effect of reformer gas mixture on the performance and emissions of an HSDI diesel engine  

Science Journals Connector (OSTI)

Abstract Exhaust gas assisted fuel reforming is an attractive on-board hydrogen production method, which can open new frontiers in diesel engines. Apart from hydrogen, and depending on the reactions promoted, the reformate typically contains a significant amount of carbon monoxide, which is produced as a by-product. Moreover, admission of reformed gas into the engine, through the inlet pipe, leads to an increase of intake air nitrogen to oxygen ratio. It is therefore necessary to study how a mixture of syngas and nitrogen affects the performance and emissions of a diesel engine, in order to gain a better understanding of the effects of supplying fuel reformer products into the engine. In the current research work, a bottled gas mixture with H2 and CO contents resembling those of typical diesel reformer product gas was injected into the inlet pipe of an HSDI diesel engine. Nitrogen (drawn from a separate bottle) at the same volumetric fraction to syngas was simultaneously admitted into the inlet pipe. Exhaust analysis and performance calculation was carried out and compared to a neat diesel operation. Introduction of syngas + N2 gas mixture resulted in simultaneous reduction of the formation of \\{NOx\\} and smoke emissions over a broad range of the engine operating window. Estimation of the bottled carbon monoxide utilisation showed that by increasing either the load or the speed the admitted carbon monoxide is utilised more efficiently. As a general rule, CO2 emissions increase when the bottled carbon monoxide utilisation is approximately over 88%. Isolation of the H2 and N2 effect revealed that a CO diluted flame promotes the formation of smoke. When the intake air is enriched with syngas + N2, an increase of engine speed results in reduction of maximum pressure rise rate (dp/da). The effect of load on dp/da varies depending on engine speed. Finally, the engine is more fuel efficient when running on neat diesel.

Fanos Christodoulou; Athanasios Megaritis

2014-01-01T23:59:59.000Z

252

Chemical Looping Reforming for H2, CO and Syngas Production  

SciTech Connect

We demonstrate that the extension of CLC onto oxidants beyond air opens new, highly efficient pathways for production of ultra-pure hydrogen, activation of CO{sub 2} via reduction to CO, and are currently working on production of syngas using nanocomposite Fe-BHA. CLR hold great potential due to fuel flexibility and CO{sub 2} capture. Chemical Looping Combustion (CLC) is a novel clean combustion technology which offers an elegant and highly efficient route for fossil fuel combustion. In CLC, combustion of a fuel is broken down into two spatially separated steps. In the reducer, the oxygen carrier (typically a metal) supplies the stoichiometric oxygen required for fuel combustion. In the oxidizer, the oxygen-depleted carrier is then re-oxidized with air. After condensation of steam from the effluent of the reducer, a high-pressure, high-purity sequestration-ready CO{sub 2} stream is obtained. In the present study, we apply the CLC principle to the production of high-purity H{sub 2}, CO, and syngas streams by replacing air with steam and/or CO{sub 2} as oxidant, respectively. Using H{sub 2}O as oxidant, pure hydrogen streams can be obtained. Similarly, using CO{sub 2} as oxidant, CO is obtained, thus opening an efficient route for CO{sub 2} utilization. Using steam and CO{sub 2} mixtures for carrier oxidation should thus allow production of syngas with adjustable CO:H{sub 2} ratios. Overall, these processes result in Chemical Looping Reforming (CLR), i.e. the net overall reaction is the steam and/or dry reforming of the respective fuel.

Bhavsar,Saurabh; Najera,Michelle; Solunke,Rahul; Veser,Götz

2001-06-06T23:59:59.000Z

253

Hiring Reform Memoranda and Action Plan  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

0585 0585 October 7, 2010 MEMORANDUM FOR HEADS OF ALL DEPARTMENTAL ELEMEI\lTS HUMAI\l RESOURCES DIRECTORS FROM: MICHAELC. KANE~~~ CHIEF HUMAN CAPITAL ~ c· SUBJECT: IMPROVING DOE RECRUITMENT AND HIRING PROCESSES This is a follow-up to the Deputy Secretary's Memorandum dated October 6, 2010 where he communicated the need to implement the Action Plan developed to improve the recruitment and hiring processes throughout the Department. One of the central tenets of the President's reform efforts and the Department's Action Plan is management's commitment and attention to an efficient and effective hiring process that yields quality employees. This was clearly articulated in the President's Memorandum dated May 11, 2010 where he directed that management be held accountable through the performance evaluation system for their role

254

Fuel cell integrated with steam reformer  

SciTech Connect

A process is described of providing a continuous supply of hydrogen fuel to a fuel cell system. The system comprises a heat exchanger, a burner, a catalytic reactor containing a catalyst bed for catalyzing the production of hydrogen from a gaseous mixture of water and methanol and a fuel cell comprised of a fuel electrode, an oxygen electrode and an electrolyte disposed therebetween. The process comprises: passing a gaseous mixture consisting essentially of water and methanol to the heat exchanger to heat the mixture to a superheated state, the temperature and composition of the superheated mixture being sufficient to supply at least about 90% of the heat required for reforming the methanol contained in the mixture by condensation.

Beshty, B.S.; Whelan, J.A.

1987-06-02T23:59:59.000Z

255

Catalyst for steam reforming of hydrocarbons  

SciTech Connect

A catalyst's resistance to deactivation by polymer formation is vital to the successful gasification of heavy feedstocks such as kerosene and gas oil. The improved polymer-resistance performance of this steam-reforming catalyst is directly relate to the distribution of the pore sizes in its calcined (but unreduced) precursor form and to a certain pore-size ratio: 1) At least 55% of the pore volume of pores having a radius of between 12 and 120 A(2000A) is in the range of 12-30 A(2000A) and 2) the ratio of the pore volume contained in pores of 10-50 A(2000A) to the volume contained in pores of 50-300 A(2000A) is at least 5:1. The catalyst-preparation method involves coprecipitation with a minimum of heat treatment (at temperatures not greater than 140/sup 0/F or 60/sup 0/C).

Banks, R.G.S.; Williams, A.

1980-08-05T23:59:59.000Z

256

Performance tests for steam methane reformers  

SciTech Connect

Most of the synthesis gas plants in operation in the United States for production of hydrogen, carbon monoxide, methanol, and ammonia use steam methane reforming (SMR). Economic projections indicate that the SMR plant may continue to be the most favorable process choice through the 1980s or until partial oxidation or coal gasification processes are technically proven. The complexity of an efficiently designed SMR plant for production of these chemicals requires a thorough understanding of many unit operations to correctly evaluate the performance of an operating plant. Air Products and Chemicals, Inc. (APCI) owns and operates various types of SMR plants for production of hydrogen and carbon monoxide gases for pipe line sales, liquid hydrogen for merchant sale, methanol and ammonia. Over the past few years, APCI has developed guidelines and procedures for plant performance tests done at its major SMR plants. This article documents the plant test procedure used in conducting onsite SMR plant performance tests.

Wang, S.I.; DiMartino, S.P.; Patel, N.M.; Smith, D.D.

1982-08-01T23:59:59.000Z

257

Process for steam reforming of hydrocarbons  

SciTech Connect

A process is provided for the steam reforming of normally liquid hydrocarbons to produce carbon monoxide and hydrogen, which does not promote the deposition of carbonacious materials upon catalytic surfaces. The catalyst consists of nickel promoted with the oxides of iron and manganese within a specific manganese to iron ratio, said metal and metal oxides being supported upon a refractory support. The support is preferably aluminum oxide in its alpha phase having a surface area of more than 0.5 m2/gm but no more than 10 m2/gm. The metallic constituents are impregnated onto said refractory low surface area support as salts and are calcined at sufficiently high temperature to convert the salts to the oxide but at a sufficiently low temperature that they do not chemically react with the support.

Broughton, D.R.; Russ, K.J.

1980-11-11T23:59:59.000Z

258

Wellcome Trust CONSULTATION RESPONSE Wellcome Trust response to the Department for Education's reformed GCSE subject content  

E-Print Network (OSTI)

's reformed GCSE subject content consultation - August 2013 Department for Education: Reformed GCSE subject's reformed GCSE subject content consultation. The proposed changes to science qualifications promote reform and have enclosed a copy for information. 1 ` Direct assessment' is based on the direct assessment

Rambaut, Andrew

259

MOVIE "CHICAGO CITY COUNCIL: READY FOR REFORM?" (27 minutes/color)  

E-Print Network (OSTI)

, transportation, and health care. 8. Investigate how many of the reform proposals were in place twenty years afterMOVIE ­ "CHICAGO CITY COUNCIL: READY FOR REFORM?" (27 minutes/color) SYNOPSIS Following the death of Mayor Harold Washington, residents and reformers of Chicago still hoped for continued reform in Chicago

Illinois at Chicago, University of

260

Thermally efficient melting and fuel reforming for glass making  

DOE Patents (OSTI)

An integrated process for utilizing waste heat from a glass making furnace. The hot off-gas from the furnace is initially partially cooled, then fed to a reformer. In the reformer, the partially cooled off-gas is further cooled against a hydrocarbon which is thus reformed into a synthesis gas, which is then fed into the glass making furnace as a fuel. The further cooled off-gas is then recycled back to absorb the heat from the hot off-gas to perform the initial cooling.

Chen, Michael S. (Zionsville, PA); Painter, Corning F. (Allentown, PA); Pastore, Steven P. (Allentown, PA); Roth, Gary S. (Trexlertown, PA); Winchester, David C. (Allentown, PA)

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

BENCH-SCALE STEAM REFORMING OF ACTUAL TANK 48H WASTE  

SciTech Connect

Fluidized Bed Steam Reforming (FBSR) has been demonstrated to be a viable technology to remove >99% of the organics from Tank 48H simulant, to remove >99% of the nitrate/nitrite from Tank 48H simulant, and to form a solid product that is primarily carbonate based. The technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration Fluidized Bed Steam Reformer1 (ESTD FBSR) at the Hazen Research Inc. (HRI) facility in Golden, CO. The purpose of the Bench-scale Steam Reformer (BSR) testing was to demonstrate that the same reactions occur and the same product is formed when steam reforming actual radioactive Tank 48H waste. The approach used in the current study was to test the BSR with the same Tank 48H simulant and same Erwin coal as was used at the ESTD FBSR under the same operating conditions. This comparison would allow verification that the same chemical reactions occur in both the BSR and ESTD FBSR. Then, actual radioactive Tank 48H material would be steam reformed in the BSR to verify that the actual tank 48H sample reacts the same way chemically as the simulant Tank 48H material. The conclusions from the BSR study and comparison to the ESTD FBSR are the following: (1) A Bench-scale Steam Reforming (BSR) unit was successfully designed and built that: (a) Emulated the chemistry of the ESTD FBSR Denitration Mineralization Reformer (DMR) and Carbon Reduction Reformer (CRR) known collectively as the dual reformer flowsheet. (b) Measured and controlled the off-gas stream. (c) Processed real (radioactive) Tank 48H waste. (d) Met the standards and specifications for radiological testing in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF). (2) Three runs with radioactive Tank 48H material were performed. (3) The Tetraphenylborate (TPB) was destroyed to > 99% for all radioactive Bench-scale tests. (4) The feed nitrate/nitrite was destroyed to >99% for all radioactive BSR tests the same as the ESTD FBSR. (5) The radioactive Tank 48H DMR product was primarily made up of soluble carbonates. The three most abundant species were thermonatrite, [Na{sub 2}CO{sub 3} {center_dot} H{sub 2}O], sodium carbonate, [Na{sub 2}CO{sub 3}], and trona, [Na{sub 3}H(CO{sub 3}){sub 2} {center_dot} 2H{sub 2}O] the same as the ESTD FBSR. (6) Insoluble solids analyzed by X-Ray Diffraction (XRD) did not detect insoluble carbonate species. However, they still may be present at levels below 2 wt%, the sensitivity of the XRD methodology. Insoluble solids XRD characterization indicated that various Fe/Ni/Cr/Mn phases are present. These crystalline phases are associated with the insoluble sludge components of Tank 48H slurry and impurities in the Erwin coal ash. The percent insoluble solids, which mainly consist of un-burnt coal and coal ash, in the products were 4 to 11 wt% for the radioactive runs. (7) The Fe{sup +2}/Fe{sub total} REDOX measurements ranged from 0.58 to 1 for the three radioactive Bench-scale tests. REDOX measurements > 0.5 showed a reducing atmosphere was maintained in the DMR indicating that pyrolysis was occurring. (8) Greater than 90% of the radioactivity was captured in the product for all three runs. (9) The collective results from the FBSR simulant tests and the BSR simulant tests indicate that the same chemistry occurs in the two reactors. (10) The collective results from the BSR simulant runs and the BSR radioactive waste runs indicates that the same chemistry occurs in the simulant as in the real waste. The FBSR technology has been proven to destroy the organics and nitrates in the Tank 48H waste and form the anticipated solid carbonate phases as expected.

Burket, P; Gene Daniel, G; Charles Nash, C; Carol Jantzen, C; Michael Williams, M

2008-09-25T23:59:59.000Z

262

Maximum Hydrogen Production by Autothermal Steam Reforming of Bio-oil With NiCuZnAl Catalyst  

Science Journals Connector (OSTI)

Autothermal steam reforming (ATR) of bio-oil, which couples the endothermic steam reforming reaction with the exothermic partial oxidation, offers many advantages from a technical and economic point of view. Effective production of hydrogen through ATR of bio-oil was performed at lower temperature with NiCuZnAl catalyst. The highest hydrogen yield from bio-oil reached 64.3% with a nearly complete bio-oil conversion at 600 °C, the ratio of steam to carbon fed (S/C) of 3 and the oxygen to carbon ratio (O/C) of 0.34. The reaction conditions in ATR including temperature, O/C, S/C and weight hourly space velocity can be used to control both hydrogen yield and products distribution. The comparison between the ATR and common steam reforming of bio-oil was studied. The mechanism of the ATR of bio-oil was also discussed.

Shi-zhi Yan; Qi Zhai; Quan-xin Li

2012-01-01T23:59:59.000Z

263

Effect of palladium addition on catalytic activity in steam methane reforming over Ni-YSZ porous membrane  

Science Journals Connector (OSTI)

Abstract This study investigated the additive effects of palladium, and the deposition method of palladium on Ni-YSZ porous membrane in steam methane reforming. Pd–Ni-YSZ porous membrane prepared by the wet impregnation method showed superior catalytic activity, where the methane conversion reached 94.6% at 650 °C, with H2 yield above 3.9. The palladium particles were well dispersed, and the Pd–Ni-YSZ porous membrane exhibited high adsorption capacity for water. The addition of palladium and the deposition method of palladium are very important for the steam methane reforming reaction.

Sang Moon Lee; Sung Chang Hong

2014-01-01T23:59:59.000Z

264

Evolution of land distribution in West Bengal 1967–2004: Role of land reform and demographic changes  

Science Journals Connector (OSTI)

Abstract This paper studies how land reform and population growth affect land inequality and landlessness, focusing particularly on indirect effects owing to their influence on household divisions and land market transactions. Theoretical predictions of a model of household division and land transactions are successfully tested using household panel data from West Bengal spanning 1967–2004. The tenancy reform lowered inequality through its effects on household divisions and land market transactions, but its effect was quantitatively dominated by inequality-raising effects of population growth. The land distribution program lowered landlessness but this was partly offset by targeting failures and induced increases in immigration.

Pranab Bardhan; Michael Luca; Dilip Mookherjee; Francisco Pino

2014-01-01T23:59:59.000Z

265

Reforming The Government Hiring Process | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Reforming The Government Hiring Process Reforming The Government Hiring Process Reforming The Government Hiring Process November 19, 2010 - 10:10am Addthis Rita Franklin Rita Franklin Deputy Chief Human Capital Officer What does this mean for me? In the video, Deputy Secretary Daniel Poneman highlights the Department's "Time-to-Hire Tracking and Reporting System." The Department reduced the end-to-end time-to-hire from 174 calendar days for Fiscal Year FY 2009 to 100 days for FY 2010. Wednesday, Deputy Secretary Daniel Poneman and I met with leaders from across the Federal government to share our progress in the our Department's hiring reform efforts. Six months ago, President Obama called on all executive departments and federal agencies to overhaul the way we recruit and hire. As the President

266

Intelligence Reform and Terroroism Prevention Act - December 17, 2004 |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Intelligence Reform and Terroroism Prevention Act - December 17, Intelligence Reform and Terroroism Prevention Act - December 17, 2004 Intelligence Reform and Terroroism Prevention Act - December 17, 2004 December 17, 2004 To reform the intelligence community and the intelligence and intelligence-related activities of the United States Government, and for other purposes. SEC. 102. (a) DIRECTOR OF NATIONAL INTELLIGENCE.-(1) There is a Director of National Intelligence who shall be appointed by the President, by and with the advice and consent of the Senate. Any individual nominated for appointment as Director of National Intelligence shall have extensive national security expertise. ''(2) The Director of National Intelligence shall not be located within the Executive Office of the President. ''(b) PRINCIPAL RESPONSIBILITY.-Subject to the authority, direction,

267

Reforming The Government Hiring Process | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Reforming The Government Hiring Process Reforming The Government Hiring Process Reforming The Government Hiring Process November 19, 2010 - 10:10am Addthis Rita Franklin Rita Franklin Deputy Chief Human Capital Officer What does this mean for me? In the video, Deputy Secretary Daniel Poneman highlights the Department's "Time-to-Hire Tracking and Reporting System." The Department reduced the end-to-end time-to-hire from 174 calendar days for Fiscal Year FY 2009 to 100 days for FY 2010. Wednesday, Deputy Secretary Daniel Poneman and I met with leaders from across the Federal government to share our progress in the our Department's hiring reform efforts. Six months ago, President Obama called on all executive departments and federal agencies to overhaul the way we recruit and hire. As the President

268

A Compact and Efficient Steam Methane Reformer for Hydrogen Production.  

E-Print Network (OSTI)

??A small-scale steam-methane reforming system for localized, distributed production of hydrogen offers improved performance and lower cost by integrating the following technologies developed at the… (more)

Quon, Willard

2012-01-01T23:59:59.000Z

269

Process Reform, Security and Suitability- December 17, 2008  

Energy.gov (U.S. Department of Energy (DOE))

This is to report on the progress made to improve the timeliness and effectiveness of our hiring and clearing decisions and the specific plan to reform the process further, in accordance with our initial proposals made in April ofthis year.

270

Fuel reforming for scramjet thermal management and combustion optimization  

E-Print Network (OSTI)

Fuel reforming for scramjet thermal management and combustion optimization E. DANIAU* , M. BOUCHEZ in a Scramjet combustion chamber. Another critical point is that mixing and combustion should be sufficiently

Paris-Sud XI, Université de

271

Deregulation, tax reform, and the use of consumer credit  

Science Journals Connector (OSTI)

This article analyzes the probable effects of recent deregulation of consumer credit markets and tax reform on household credit-use decisions. The results of the analysis ... that deregulation of rates of charge ...

A. Charlene Sullivan; Debra Drecnik Worden

1989-10-01T23:59:59.000Z

272

ISSN 1745-9648 Organisation and Reforms of the  

E-Print Network (OSTI)

of liberalisation of the Slovenian electricity market to a large extent resembles what other EU countries were: electricity reform, restructuring, competition, South East Europe, liberalisation #12;2 Acknowledgements

Feigon, Brooke

273

A cross country analysis of electricity market reforms  

E-Print Network (OSTI)

econometric model based on Poisson regression with cross-section data covering 51 US states, 13 Canada states and 51 other countries. The results show that both the background of the chairperson of electricity market regulatory agency when reforms started...

Erdogdu, Erkan

2012-06-19T23:59:59.000Z

274

Highly Active Steam Reforming Catalyst for Hydrogen and Syngas Production  

Science Journals Connector (OSTI)

Toyo Engineering Corporation developed a steam reforming catalyst, which is four times as active as conventional catalysts, for hydrogen and syngas production from light natural gas. The catalyst has...3 plant. B...

Toru Numaguchi

2001-11-01T23:59:59.000Z

275

Hydrogen & Fuel Cells - Hydrogen - Distributed Ethanol Reforming  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen from Bio-Derived Liquids Hydrogen from Bio-Derived Liquids Bio-derived liquid fuels can be produced from renewable agricultural products, such as wood chips. Background Bio-derived renewable fuels are attractive for their high energy density and ease of transport. One scenario for a sustainable hydrogen economy considers that these bio-derived liquid fuels will be produced at plants close to the biomass resource, and then transported to distributed hydrogen production centers (e.g., hydrogen refueling stations), where the fuels will be reformed via the steam reforming process, similar to the current centralized production of hydrogen by the steam reforming of natural gas. Hydrogen produced by reforming these fuels must first be purified and compressed to appropriate storage and dispensing pressures. Compressing

276

Electrical Generation Tax Reform Act (Montana) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Generation Tax Reform Act (Montana) Generation Tax Reform Act (Montana) Electrical Generation Tax Reform Act (Montana) < Back Eligibility Utility Fed. Government Commercial Agricultural Investor-Owned Utility State/Provincial Govt Industrial Municipal/Public Utility Local Government Residential Installer/Contractor Rural Electric Cooperative Tribal Government Low-Income Residential Schools Institutional Multi-Family Residential Systems Integrator Nonprofit General Public/Consumer Transportation Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Montana Program Type Fees Provider Montana Department of Revenue This Act reforms taxes paid by electricity generators to reduce tax rates and imposes replacement taxes in response to the 1997 restructuring of the

277

Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons  

SciTech Connect

An apparatus is described for the essentially autothermal, integrated primary and secondary reforming of hydrocarbons comprising: (a) an internally insulated outer reactor shell adapted for the positioning of primary and secondary reforming zones therein; (b) means defining a primary reforming zone within the outer reactor shell and having catalyst-containing reformer tubes positioned therein, the primary reforming zone not requiring an external fuel fired source of heat for the endothermic primary reforming reaction occurring therein; (c) means for introducing a fluid hydrocarbon feed stream and steam to the outer reactor shell for passage through the reformer tubes in the primary reforming zone; (d) means defining a secondary reforming zone within the outer reactor shell comprising a secondary reforming catalyst bed, a catalyst-free reaction space defining a feed end adjacent to the catalyst bed and a discharge end at the opposite side of the secondary reforming catalyst bed to the feed end; and (e) conduit means positioned entirely within the outer reactor shell and extending through the secondary reforming catalyst bed for passing partly reformed product effluent from the primary reforming zone to the catalyst-free reaction space in the secondary reforming zone.

Fuderer, A.

1987-03-17T23:59:59.000Z

278

PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol Steam Reforming, and Reverse-Water-Gas-Shift  

SciTech Connect

Pd/ZnO/Al2O3 catalysts were studied for water-gas-shift (WGS), methanol steam reforming, and reverse-water-gas-shift (RWGS) reactions. WGS activity was found to be dependent on the Pd:Zn ratio with a maximum activity obtained at approximately 0.50, which was comparable to that of a commercial Pt-based catalyst. The catalyst stability was demonstrated for 100 hours time-on-stream at a temperature of 3600C without evidence of metal sintering. WGS reaction rates were approximately 1st order with respect to CO concentration, and kinetic parameters were determined to be Ea = 58.3 kJ mol-1 and k0 = 6.1x107 min-1. During methanol steam reforming, the CO selectivities were observed to be lower than the calculated equilibrium values over a range of temperatures and steam/carbon ratios studied while the reaction rate constants were approximately of the same magnitude for both WGS and methanol steam reforming. These results indicate that although Pd/ZnO/Al2O3 are active WGS catalysts, WGS is not involved in methanol steam reforming. RWGS rate constants are on the order of about 20 times lower than that of methanol steam reforming, suggesting that RWGS reaction could be one of the sources for small amount of CO formation in methanol steam reforming.

Dagle, Robert A.; Platon, Alexandru; Datye, Abhaya K.; Vohs, John M.; Wang, Yong; Palo, Daniel R.

2008-03-07T23:59:59.000Z

279

Fractionation of reformate: A new variant of gasoline production technology  

SciTech Connect

The Novo-Ufa Petroleum Refinery is the largest domestic producer of the unique high-octane unleaded automotive gasolines AI-93 and AI-95 and the aviation gasolines B-91/115 and B-92. The base component for these gasolines is obtained by catalytic reforming of wide-cut naphtha; this basic component is usually blended with certain other components that are expensive and in short supply: toluene, xylenes, and alkylate. For example, the unleaded gasoline AI-93 has been prepared by blending reformate, alkylate, and toluene in a 65:20:15 weight ratio; AI-95 gasoline by blending alkylate and xylenes in an 80:20 weight ratio; and B-91/115 gasoline by compounding a reformate obtained with light straight-run feed, plus alkylate and toluene, in a 55:35:10 weight ratio. Toluene and xylenes have been obtained by process schemes that include the following consecutive processes: redistillation of straight-run naphtha cuts to segregate the required narrow fraction; catalytic reforming (Platforming) of the narrow toluene-xylene straight-run fraction; azeotropic distillation of the reformate to recover toluene and xylenes. A new technology based on the use of reformate fractions is proposed.

Karakuts, V.N.; Tanatarov, M.A.; Telyashev, G.G. [and others

1995-07-01T23:59:59.000Z

280

Sulfur-passivated nickel catalysts for carbon-free steam reforming of methane  

SciTech Connect

It has been observed that carbon-free steam reforming of methane can be obtained on a partly sulfur-passivated nickel catalyst under conditions which, without the presence of sulfur, would result in formation of whisker carbon. This effect has been studied by means of kinetic experiments and thermogravimetry. The kinetic data can be explained by simple blockage of the surface as reflected in the observed kinetic orders and activation energy. The studies of carbon formation confirm a threshold coverage of about 70% of full coverage below which the inhibition of carbon is not effective. Above this coverage, amorphous carbon structures may be formed at a very high carbon potentials. The retarding effect of sulfur on carbon formation is a dynamic phenomenon. Sulfur inhibits the rate of carbon formation more than the rate of the reforming reactions. The effects are explained by assuming that a large ensemble is involved in the nucleation of carbon, whereas the reforming reaction can proceed on the small ensembles left a high sulfur coverages. 6 figures, 6 tables.

Rostrup-Nielsen, J.R.

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Thermodynamic analysis of hydrogen production via chemical looping steam methane reforming coupled with in situ CO2 capture  

Science Journals Connector (OSTI)

Abstract In this study, a detailed thermodynamic analysis of the sorption enhanced chemical looping reforming of methane (SE-CL-SMR), using CaO and NiO as CO2 sorbent and oxygen transfer material respectively, was conducted. The effect of different parameters, such as reactor temperature, pressure, H2O/CH4 ratio, CaO/CH4 ratio and CaO/NiO ratio was investigated. Moreover, the use of different sweep gases and oxidants for the re-oxidation/calcination cycle, like pure oxygen, air, steam and CO2, was specifically addressed. Conventional steam reforming (SMR) and sorption enhanced steam reforming (SE-SMR) were also investigated for comparison reasons. The results of thermodynamic analysis show that there are significant advantages of both sorption enhanced processes compared to conventional steam reforming. Presence of CaO sorbent in the reformer leads to higher methane conversion, hydrogen purity and yield at low temperatures (?650 °C). Addition of the oxygen carrier, in the chemical looping reforming concept, minimizes thermal requirements of the process, and results in superior performance compared to SE-SMR and SMR processes. A negative effect from NiO addition is reduction in hydrogen production (due to the reaction of part of methane with NiO to form CO/CO2). Hydrogen yield is up to 11% lower compared to SE-SMR for a NiO/CaO ratio of 0.7. It was found that only pure O2 can be used for re-oxidation/regeneration in order to reduce the energy requirements of the SE-CL-SMR process up to 26% compared to SE-SMR and up to 55% compared to conventional SMR.

A. Antzara; E. Heracleous; D.B. Bukur; A.A. Lemonidou

2015-01-01T23:59:59.000Z

282

High Temperature Gas-Cooled Reactor Program. Modular HTGR systems design and cost summary. [Methane reforming; steam cycle-cogeneration  

SciTech Connect

This report provides a summary description of the preconceptual design and energy product costs of the modular High Temperature Gas-Cooled Reactor (HTGR). The reactor system was studied for two applications: (1) reforming of methane to produce synthesis gas and (2) steam cycle/cogeneration to produce process steam and electricity.

Not Available

1983-09-01T23:59:59.000Z

283

Hydrogen plant expansion using oxygen secondary reforming  

SciTech Connect

As crude oil feedstocks become heavier and more sour, the H/sub 2/ demands of a refinery increase. Heavier sour crudes require more H/sub 2/ for hydrodesulfurization, hydrocracking and hydrotreating to produce the lighter, high quality products currently in demand. In most cases, this additional H/sub 2/ requirement is satisfied by the generation of on purpose H/sub 2/. The on purpose H/sub 2/ demand is typically satisfied by steam methane reforming (SMR). The conventional SMR process, utilizing shift, CO/sub 2/ removal, and methanation for H/sub 2/ purification, can produce 90 to 98% pure H/sub 2/ at 150 to 400 psig at an energy efficiency of 410 Btu (HHV)/SCF H/sub 2/. An SMR process employing shift and pressure swing adsorption (PSA) for H/sub 2/ purification can produce H/sub 2/ at a purity up to 99.999% and an energy efficiency of 390 Btu (HHV)/SCF H/sub 2/. Two options available for satisfying an increased on purpose H/sub 2/ demand are the addition of a new SMR plant and the debottlenecking of an existing SMR. A new SMR plant is the most capital-intensive means of expanding H/sub 2/ capacity.

Snyder, G.D.; Wang, S.I.

1986-01-01T23:59:59.000Z

284

THOR Bench-Scale Steam Reforming Demonstration  

SciTech Connect

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrates were not detected in the product and NOx destruction exceeded 98%. The demonstration was successful.

Marshall, D.W.; Soelberg, N.R.; Shaber, K.M.

2003-05-21T23:59:59.000Z

285

THOR Bench-Scale Steam Reforming Demonstration  

SciTech Connect

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a "road ready" waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrates were not detected in the product and NOx destruction exceeded 98%. The demonstration was successful.

D. W. Marshall; N. R. Soelberg; K. M. Shaber

2003-05-01T23:59:59.000Z

286

FACULTY OF LAW Centre for Commercial Law Studies  

E-Print Network (OSTI)

FACULTY OF LAW Centre for Commercial Law Studies SEMINAR ON FINANCIAL REGULATORY REFORM Obama recently signed into law a package of financial regulatory reforms unparalleled in scope and depth since the 1930s. The Dodd-Frank Wall Street Reform and Consumer Protection Act is intended

Tan, Chew Lim

287

Methane steam reforming at low temperature: Effect of light alkanes’ presence on coke formation  

Science Journals Connector (OSTI)

Abstract Steam reforming of natural gas for the production of hydrogen at low operation temperature offers significant financial and environmental advantages. However, the presence of higher hydrocarbons as minor components of natural gas can significantly affect the formation of coke and thus the effectiveness of the catalyst. In this study, the effect of the presence of C2–C3 alkanes in the feedstock on the carbon accumulation during low temperature steam reforming of methane is investigated over Ni and Rh catalysts supported on lanthanum doped ceria–zirconia mixed oxide. Both catalysts showed high resistance to coke formation and especially in the case of Rh/La/CeO2–ZrO2, the carbon accumulation detected was low even after 10 h on stream in steam reforming of all mixtures of hydrocarbons tested. The presence of higher alkanes in methane increased the amount of carbon on Ni(10)CeZrLa compared to pure methane as well as the nature of the carbonaceous species. Increase in the C-number of the additive alkane had almost no influence on the total amount of carbon formed (C/H feed ratio = constant) but favored the formation of filamentous carbon.

Sofia D. Angeli; Fotis G. Pilitsis; Angeliki A. Lemonidou

2015-01-01T23:59:59.000Z

288

Hydrogen production from an ethanol reformer with energy saving approaches over various catalysts  

Science Journals Connector (OSTI)

The reforming of ethanol for hydrogen production was carried out in this study. The effects of ethanol supply rate, catalysts, O2/EtOH and different energy-saving approaches on the reforming temperature, H2 + CO (syngas) concentration and thermal efficiency were investigated. The results showed that the best H2 + CO concentration of 43.41% could be achieved by using rhodium (Rh), while the next best concentration of about 42.08% could be obtained using ruthenium (Ru). The results also showed that the conversion efficiency of ethanol, concentrations of H2 and CO, and the energy loss ratio could be improved by heat insulation and heat recycling; and the improvement in the reforming performance was greater by the Ru catalyst rather than by the Rh catalyst with the energy-saving approaches. The greatest improvement in hydrogen production was achieved when using the Ru catalyst with the addition of steam and heat recycling system under an O2/EtOH ratio of 0.625 and S/C ratio of 1.0.

Wei-Cheng Chiu; Rong-Fang Horng; Huann-Ming Chou

2013-01-01T23:59:59.000Z

289

Walk the line: Conflict, state capacity and the political dynamics of reform  

Science Journals Connector (OSTI)

Abstract This paper develops a dynamic framework to analyze the political sustainability of economic reforms in developing countries. First, we demonstrate that economic reforms that are proceeding successfully may run into a political impasse, with the reform's initial success having a negative impact on its political sustainability. Second, we demonstrate that greater state capacity, to make compensatory transfers to those adversely affected by reform, need not always help the political sustainability of reform, but can also hinder it. Finally, we argue that in ethnically divided societies, economic reform may be completed not despite ethnic conflict, but because of it.

Sanjay Jain; Sumon Majumdar; Sharun W Mukand

2014-01-01T23:59:59.000Z

290

FLUIDIZED BED STEAM REFORMER MONOLITH FORMATION  

SciTech Connect

Fluidized Bed Steam Reforming (FBSR) is being considered as an alternative technology for the immobilization of a wide variety of aqueous high sodium containing radioactive wastes at various DOE facilities in the United States. The addition of clay, charcoal, and a catalyst as co-reactants converts aqueous Low Activity Wastes (LAW) to a granular or ''mineralized'' waste form while converting organic components to CO{sub 2} and steam, and nitrate/nitrite components, if any, to N{sub 2}. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage-like structures that atomically bond radionuclides like Tc-99 and anions such as SO{sub 4}, I, F, and Cl. The granular product has been shown to be as durable as LAW glass. Shallow land burial requires that the mineralized waste form be able to sustain the weight of soil overburden and potential intrusion by future generations. The strength requirement necessitates binding the granular product into a monolith. FBSR mineral products were formulated into a variety of monoliths including various cements, Ceramicrete, and hydroceramics. All but one of the nine monoliths tested met the <2g/m{sup 2} durability specification for Na and Re (simulant for Tc-99) when tested using the Product Consistency Test (PCT; ASTM C1285). Of the nine monoliths tested the cements produced with 80-87 wt% FBSR product, the Ceramicrete, and the hydroceramic produced with 83.3 wt% FBSR product, met the compressive strength and durability requirements for an LAW waste form.

Jantzen, C

2006-12-22T23:59:59.000Z

291

DURABILITY TESTING OF FLUIDIZED BED STEAM REFORMER (FBSR) WASTE FORMS  

SciTech Connect

Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium aqueous radioactive wastes. The addition of clay and a catalyst as co-reactants converts high sodium aqueous low activity wastes (LAW) such as those existing at the Hanford and Idaho DOE sites to a granular ''mineralized'' waste form that may be made into a monolith form if necessary. Simulant Hanford and Idaho high sodium wastes were processed in a pilot scale FBSR at Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium-bearing waste (SBW). The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The durability of the FBSR waste form products was tested in order to compare the measured durability to previous FBSR waste form testing on Hanford Envelope C waste forms that were made by THOR Treatment Technologies (TTT) and to compare the FBSR durability to vitreous LAW waste forms, specifically the Hanford low activity waste (LAW) glass known as the Low-activity Reference Material (LRM). The durability of the FBSR waste form is comparable to that of the LRM glass for the test responses studied.

Jantzen, C

2006-01-06T23:59:59.000Z

292

The use of advanced steam reforming technology for hydrogen production  

SciTech Connect

The demand for supplementary hydrogen production in refineries is growing significantly world-wide as environmental legislation concerning cleaner gasoline and diesel fuels is introduced. The main manufacturing method is by steam reforming. The process has been developed both to reduce the capital cost and increase efficiency, reliability and ease of operation. ICI Katalco`s Leading Concept Hydrogen or LCH process continues this process of improvement by replacing the conventional fired steam reformer with a type of heat exchange reformer known as the Gas Heated Reformer or GHR. The GHR was first used in the Leading Concept Ammonia process, LCA at ICI`s manufacturing site at Severnside, England and commissioned in 1988 and later in the Leading Concept Methanol (LCM) process for methanol at Melbourne, Australia and commissioned in 1994. The development of the LCH process follows on from both LCA and LCM processes. This paper describes the development and use of the GHR in steam reforming, and shows how the GHR can be used in LCH. A comparison between the LCH process and a conventional hydrogen plant is given, showing the benefits of the LCH process in certain circumstances.

Abbishaw, J.B.; Cromarty, B.J. [ICI Katalco, Billingham (United Kingdom)

1996-12-01T23:59:59.000Z

293

A novel integrated thermally double coupled configuration for methane steam reforming, methane oxidation and dehydrogenation of propane  

Science Journals Connector (OSTI)

Abstract The goal of this study is the simultaneous production of synthesis gas, hydrogen and propylene in a thermally double coupled steam reformer reactor. This reactor has three concentric tubes where the exothermic reaction of methane oxidation is supposed to occur in the middle tube and the inner and outer tubes are considered to be endothermic sides of steam reforming and propane dehydrogenation, respectively. The motivation is to combine the energy efficient concept of coupling one exothermic reaction with two endothermic reactions, enhancement of synthesis gas production, propylene and hydrogen production and also producing two different H2/CO ratio streams of syngas. A steady state homogeneous model of fixed bed for three sides predicts the performance of this new configuration. The simulation results are compared with corresponding predictions of the conventional steam reformer. The results prove that synthesis gas production is increased in a thermally double coupled reactor in comparison with conventional steam reforming. In addition, the thermally double coupled reactor reduces the capital and operating costs by reducing the reactor size and consumption of energy.

D. Karimipourfard; S. Kabiri; M.R. Rahimpour

2014-01-01T23:59:59.000Z

294

Regulatory and Financial Reform of Federal Research Policy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Regulatory and Financial Reform of Federal Research Policy Regulatory and Financial Reform of Federal Research Policy Recommendations to the NRC Committee on Research Universities January 21, 2011 Introduction At the request of the National Research Council (NRC) Committee on Research Universities, the Council on Governmental Relations (COGR), the Association of American Universities (AAU), and the Association of Public and Land-grant Universities (APLU) have assembled a set of ten recommendations for regulatory reform that would improve research universities' ability to carry out their missions without requiring a significant financial investment by the Federal government. We firmly believe that compliance and regulatory oversight are essential to the conduct of federally-supported research. Rationalizing the Federal regulatory infrastructure is essential to

295

Comments on Request For Information regarding Reducing Regulatory Reform  

NLE Websites -- All DOE Office Websites (Extended Search)

Comments on Request For Information regarding Reducing Regulatory Comments on Request For Information regarding Reducing Regulatory Reform issued February 3, 2011 (Federal Register /Vol. 76, No. 23 /Thursday, February 3, 2011 /Notices). Comments on Request For Information regarding Reducing Regulatory Reform issued February 3, 2011 (Federal Register /Vol. 76, No. 23 /Thursday, February 3, 2011 /Notices). I have reviewed the Request For Information regarding Reducing Regulatory Reform issued February 3, 2011 (Federal Register /Vol. 76, No. 23 /Thursday, February 3, 2011 /Notices). In the Department of Energy"s (DOE) attempt to meet its obligation to implement Executive Order 13563, ""Improving Regulation and Regulatory Review,"" issued by the President on January 18, 2011, I recommend DOE make a bold move to change

296

Forest Tenure Reform in Vietnam | Open Energy Information  

Open Energy Info (EERE)

in Vietnam in Vietnam Jump to: navigation, search Name Forest Tenure Reform in Vietnam Agency/Company /Organization Regional Community Forestry Training Center for Asia and the Pacific Sector Land Focus Area Forestry Topics Resource assessment, Background analysis Resource Type Lessons learned/best practices Website http://recoftc.org/site/filead Country Vietnam UN Region South-Eastern Asia References Forest Tenure Reform in Vietnam[1] Forest Tenure Reform in Vietnam Screenshot Summary "This report presents a synthesis of findings from the two surveys undertaken in Dak Lak (by Dak Lak Department of Agriculture and Rural Development (DARD)) and Hoa Binh by VFU (See Annex A. for a list of members in the two research teams). It was prepared by Nguyen Quang Tan, Nguyen Ba

297

Steam methane reforming in molten carbonate salt. Final report  

SciTech Connect

This report documents the work accomplished on the project {open_quotes}Steam Methane Reforming in Molten Carbonate Salt.{close_quotes}. This effort has established the conceptual basis for molten carbonate-based steam reforming of methane. It has not proceeded to prototype verification, because corrosion concerns have led to reluctance on the part of large hydrogen producers to adopt the technology. Therefore the focus was shifted to a less corrosive embodiment of the same technology. After considerable development effort it was discovered that a European company (Catalysts and Chemicals Europe) was developing a similar process ({open_quotes}Regate{close_quotes}). Accordingly the focus was shifted a second time, to develop an improvement which is generic to both types of reforming. That work is still in progress, and shows substantial promise.

Erickson, D.C.

1996-05-01T23:59:59.000Z

298

Pyrochlore-type catalysts for the reforming of hydrocarbon fuels  

DOE Patents (OSTI)

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A.sub.2-w-xA'.sub.wA''.sub.xB.sub.2-y-zB'.sub.yB''.sub.zO.sub.7-.DELTA.. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H.sub.2+CO) for fuel cells, among other uses.

Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV); Haynes, Daniel (Morgantown, WV); Smith, Mark (Morgantown, WV); Spivey, James J. (Baton Rouge, LA)

2012-03-13T23:59:59.000Z

299

High performance internal reforming unit for high temperature fuel cells  

DOE Patents (OSTI)

A fuel reformer having an enclosure with first and second opposing surfaces, a sidewall connecting the first and second opposing surfaces and an inlet port and an outlet port in the sidewall. A plate assembly supporting a catalyst and baffles are also disposed in the enclosure. A main baffle extends into the enclosure from a point of the sidewall between the inlet and outlet ports. The main baffle cooperates with the enclosure and the plate assembly to establish a path for the flow of fuel gas through the reformer from the inlet port to the outlet port. At least a first directing baffle extends in the enclosure from one of the sidewall and the main baffle and cooperates with the plate assembly and the enclosure to alter the gas flow path. Desired graded catalyst loading pattern has been defined for optimized thermal management for the internal reforming high temperature fuel cells so as to achieve high cell performance.

Ma, Zhiwen (Sandy Hook, CT); Venkataraman, Ramakrishnan (New Milford, CT); Novacco, Lawrence J. (Brookfield, CT)

2008-10-07T23:59:59.000Z

300

Ghana-REDD Readiness Requires Radical Reform | Open Energy Information  

Open Energy Info (EERE)

Readiness Requires Radical Reform Readiness Requires Radical Reform Jump to: navigation, search Name Ghana-REDD Readiness Requires Radical Reform Agency/Company /Organization UN-REDD Programme Sector Land Focus Area Forestry, Agriculture Topics Implementation, GHG inventory, Policies/deployment programs, Resource assessment, Pathways analysis, Background analysis Resource Type Maps, Guide/manual, Training materials Website http://environment.yale.edu/tf Country Ghana UN Region Western Africa References Ghana-REDD Readiness[1] Summary "The fundamental changes needed for sustainable forest management in Ghana have been known for years, and many large projects have been instigated accordingly. Yet real change has proved elusive. The key challenge now is to get REDD-plus right so that it makes a difference. Dialogue participants

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

GUIDANCE ON APPLICATION OF FEDERAL VACANCIES REFORM ACT OF 1998 Page 1 of 13  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

APPLICATION OF FEDERAL VACANCIES REFORM ACT OF 1998 Page 1 of 13 APPLICATION OF FEDERAL VACANCIES REFORM ACT OF 1998 Page 1 of 13 GUIDANCE ON APPLICATION OF FEDERAL VACANCIES REFORM ACT OF 1998 This memorandum provides guidance on the application of the Federal Vacancies Reform Act of1998 to vacancies in Senate-confirmed offices within the executive branch. March 22, 1999 MEMORANDUM FOR AGENCY GENERAL COUNSELS On October 21, 1998, the Federal Vacancies Reform Act of 1998 ("Vacancies Reform Act" or "Act") was signed into law. ( ) The Vacancies Reform Act replaces the old Vacancies Act and alters the way in which vacancies in presidentially appointed, Senate- confirmed offices within the executive branch may be filled on a temporary basis. The following Q&As are intended to provide general guidance on the Vacancies Reform Act. If

302

Catalytic roles of Co0 and Co2+ during steam reforming of ethanol...  

NLE Websites -- All DOE Office Websites (Extended Search)

roles of Co0 and Co2+ during steam reforming of ethanol on CoMgO catalysts . Catalytic roles of Co0 and Co2+ during steam reforming of ethanol on CoMgO catalysts . Abstract:...

303

The Fate of Obamacare: Racial Resentment, Ethnocentrism and Attitudes about Healthcare Reform  

Science Journals Connector (OSTI)

Health care has been a contentious issue in American ... public support for, and opposition to, healthcare reform. Using national survey data, we measure ... and Ethnocentrism, on white support for healthcare reform

Angie Maxwell; Todd Shields

2014-10-01T23:59:59.000Z

304

Abstract 3727: Phase 0 trials, obligation to research and ethical implications of health-care reform  

Science Journals Connector (OSTI)

...obligation to research and ethical implications of health-care reform Silvia Camporesi...are also at the core of the US Health Care reform. On the one hand...currently Special Advisor for Health Policy at the White House...

Silvia Camporesi and Matteo Mameli

2011-01-10T23:59:59.000Z

305

Application of a Diesel Fuel Reformer for Tier 2 Bin 5 Emissions  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

of a Diesel Fuel Reformer for Tier 2 Bin 5 Emissions APPROACH On-board diesel fuel reformation is being evaluated as an alternative to urea SCR to meet Tier 2 Bin 5 emissions...

306

It’s About Time for Autism Reform Legislation in Utah  

Science Journals Connector (OSTI)

On 3 April 2014, Governor Gary Herbert signed into law a health insurance reform bill that requires private insurers to cover ... and the District of Columbia have enacted insurance reform laws. Ensuring that chi...

Brian J. Shiozawa

2014-11-01T23:59:59.000Z

307

FLUIDIZABLE CATALYSTS FOR PRODUCING HYDROGEN BY STEAM REFORMING BIOMASS PYROLYSIS LIQUIDS  

E-Print Network (OSTI)

FLUIDIZABLE CATALYSTS FOR PRODUCING HYDROGEN BY STEAM REFORMING BIOMASS PYROLYSIS LIQUIDS Kimberly established that biomass pyrolysis oil could be steam-reformed to generate hydrogen using non pyrolysis oil could be almost stoichiometrically converted to hydrogen. However, process performance

308

E-Print Network 3.0 - agricultural price reforms Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

T Y J A N U A R Y 1 1 , 2 0 1 0 You Get What You Pay For: The Obama Approach to Health Care Reform 12... fundamental issues in health care reform 12;Coverage is actually quite...

309

Steam reforming of carbo-metallic oils  

SciTech Connect

A process is disclosed for economically converting carbo-metallic oils to liquid fuel products by bringing a converter feed containing 650/sup 0/ F. + material characterized by a carbon residue on pyrolysis of at least about 1 and by containing at least about 4 ppm of nickel equivalents of heavy metals, including nickel, into contact with a particulate cracking catalyst in a progressive flow type reactor having an elongated conversion zone. The suspension of catalyst and feed in the reactor has a vapor residence time in the range of about 0.5 to about 10 seconds, a temperature of about 900/sup 0/ F. to about 1400/sup 0/ F. and a pressure of about 10 to about 50 pounds per square inch absolute for causing a conversion per pass in the range of about 50 to about 90 percent while depositing nickel on the catalyst and coke on the catalyst in amounts in the range of about 0.3 to about 3 percent by weight. The coke-laden catalyst is separated from the resulting stream of hydrocarbons and regenerated by combustion of the coke with oxygen, the regenerated catalyst being characterized by deposited nickel in at least a partially oxidized state and a level of carbon on catalyst of about 0.25 percent by weight or less. The regenerated catalyst is contacted with a reducing gas under reducing conditions sufficient to reduce at least a portion of the oxidized nickel deposits to a reduced state and the regenerated catalyst with reduced nickel deposits is recycled to the conversion zone for contact with fresh feed. Water is also introduced into the reactor conversion zone and the amount of water and the amount of reduced nickel on the recycled catalyst are sufficient to provide a steam reforming reaction so that hydrogen deficient components of the feed are converted to products having higher hydrogen to carbon ratios and the amount of feed converted to coke is reduced. The amount of deposited nickel on catalyst is preferably in the range from about 2,000 to about 20,000 ppm.

Myers, G.D.; Hettinger, W.P. Jr.; Kovach, S.M.; Zandona, O.J.

1984-02-21T23:59:59.000Z

310

Health Insurance Reform and the Tensions of Federalism  

Science Journals Connector (OSTI)

...government will be able to navigate the political and policy-related shoals, but clearly, federal–state tensions are about to be seriously tested. Insurance-Market Reforms and Market-Stabilization Initiatives in the Health Care Reform Law.. Creation of high-risk pools — effective June 21, 2010 (90... Christopher Jennings and Katherine Hayes write that our ability to achieve a workable federal–state balance will be seriously tested as the Obama administration and the states define and apply their roles in implementing the myriad new policies for ...

Jennings C.C.; Hayes K.J.

2010-06-17T23:59:59.000Z

311

Medicare's Chronic Care Management Payment — Payment Reform for Primary Care  

Science Journals Connector (OSTI)

...efforts to reform U.S. health care delivery focus on creating a high-performing primary care system that improves value through increased emphasis on access, prevention, and care coordination. Reformers recognize that the fee-for-service system, which restricts payments for primary care to office-based... In 2015, the Centers for Medicare and Medicaid Services will introduce a non–visit-based payment for chronic care management. The new policy reflects an investment in primary care that may contribute to the development of a value-oriented health system.

Edwards S.T.; Landon B.E.

2014-11-27T23:59:59.000Z

312

High temperature gas cooled reactor steam-methane reformer design  

SciTech Connect

The concept of the long distance transportation of process heat energy from a High Temperature Gas Cooled Reactor (HTGR) heat source, based on the steam-methane reforming reaction, is being evaluated by the Department of Energy as an energy source/application for use early in the 21st century. This paper summaries the design of a helium heated steam reformer utilized in conjunction with an intermediate loop, 850/degree/C reactor outlet temperature, HTGR process heat plant concept. This paper also discusses various design considerations leading to the mechanical design features, the thermochemical performance, the materials selection and the structural design analysis. 12 refs.

Impellezzeri, J.R.; Drendel, D.B.; Odegaard, T.K.

1981-01-01T23:59:59.000Z

313

Heat exchanger for fuel cell power plant reformer  

DOE Patents (OSTI)

A heat exchanger uses the heat from processed fuel gas from a reformer for a fuel cell to superheat steam, to preheat raw fuel prior to entering the reformer and to heat a water-steam coolant mixture from the fuel cells. The processed fuel gas temperature is thus lowered to a level useful in the fuel cell reaction. The four temperature adjustments are accomplished in a single heat exchanger with only three heat transfer cores. The heat exchanger is preheated by circulating coolant and purge steam from the power section during startup of the latter.

Misage, Robert (Manchester, CT); Scheffler, Glenn W. (Tolland, CT); Setzer, Herbert J. (Ellington, CT); Margiott, Paul R. (Manchester, CT); Parenti, Jr., Edmund K. (Manchester, CT)

1988-01-01T23:59:59.000Z

314

The Political Economy of India’s Fiscal Federal System and its Reform  

E-Print Network (OSTI)

for state governments’ capital expenditure. Tax Reform Taxborrow to finance capital expenditure, without underminingfinancing states’ capital expenditure through new borrowing

Rao, M. Govinda; Singh, Nirvikar

2006-01-01T23:59:59.000Z

315

Hydrogen Production by Noncatalytic Autothermal Reformation of Aviation Fuel Using Supercritical Water  

Science Journals Connector (OSTI)

Hydrogen Production by Noncatalytic Autothermal Reformation of Aviation Fuel Using Supercritical Water ... Energy Fuels, 2009, 23 (12), ...

Jason W. Picou; Jonathan E. Wenzel; H. Brian Lanterman; Sunggyu Lee

2009-10-07T23:59:59.000Z

316

Inequality and the Politics of Social Policy Implementation: Gender, Age and Chile's 2004 Health Reforms  

E-Print Network (OSTI)

Reforms CHRISTINA EWIG and GASTO´ N A. PALMUCCI * University of Wisconsin-Madison, USA Summary implementation. We examine the 2004 Chilean health reforms that sought to regulate private insurers, and measure their effects on gender and age inequality. We find that reforms intended to decrease these inequalities largely

Wisconsin at Madison, University of

317

WELLCOME TRUST CONSULTATION RESPONSE Wellcome Trust response to the Reform of the National Curriculum in England  

E-Print Network (OSTI)

WELLCOME TRUST CONSULTATION RESPONSE Wellcome Trust response to the Reform of the National Curriculum in England April 2013 1 Department for Education: Reform of the National Curriculum in England CONSULTATION RESPONSE Wellcome Trust response to the Reform of the National Curriculum in England April 2013 2

Rambaut, Andrew

318

Even if it's not Bribery: The Case for Campaign Finance Reform  

E-Print Network (OSTI)

Even if it's not Bribery: The Case for Campaign Finance Reform Brendan Daley Erik Snowberg Duke reform alleviates this phenomenon and improves voter welfare at the expense of politicians. Thus, we expect successful politicians to oppose true campaign finance reform. We also show our model

Jensen, Grant J.

319

BEHIND THE VEIL THE REFORM OF ISLAM IN INTER-WAR ALBANIA  

E-Print Network (OSTI)

107 BEHIND THE VEIL THE REFORM OF ISLAM IN INTER-WAR ALBANIA OR THE SEARCH FOR A "MODERN" of the country. The dominant role of secularist elites paved the way for the "reform of Islam." This process in the organization and reform of official religious institutions. For example, it interfered in the organization

Boyer, Edmond

320

August 15, 2013 Bargaining Update 8: UC stresses fair compensation and reasonable pension reform  

E-Print Network (OSTI)

reform UC stressed with the California Nurses Association on Aug. 6-8, 2013 the need to reach a fair's market. UC's pension reform proposal calls for: · Employees hired before July 1, 2013: UC would in substantive negotiations over responsible and necessary pension reform. CNA has not accepted UC's pension

Leistikow, Bruce N.

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Wellcome Trust CONSULTATION RESPONSE Wellcome Trust response to Ofqual's GCSE reform consultation -August 2013  

E-Print Network (OSTI)

Wellcome Trust CONSULTATION RESPONSE Wellcome Trust response to Ofqual's GCSE reform consultation - August 2013 1 Ofqual: GCSE reform consultation Response by the Wellcome Trust August 2013 Key points and indirect practical assessment in its reform proposals. The total contribution of direct and indirect

Rambaut, Andrew

322

Using a CSCL-Driven Shift in Agency to Undertake Educational Reform1  

E-Print Network (OSTI)

1 Using a CSCL-Driven Shift in Agency to Undertake Educational Reform1 Mark Guzdial1, Matthew educational reform efforts, but there are many challenges to face before achieving that vision. Two attempting to use this tool to leverage a particular kind of educational reform goal: Achieving integration

Guzdial, Mark

323

Enviro-Friendly Hydrogen Generation From Steel Mill-Scale via Metal-Steam Reforming  

E-Print Network (OSTI)

Enviro-Friendly Hydrogen Generation From Steel Mill-Scale via Metal-Steam Reforming Abdul of certain metals with steam, called metal- steam reforming (MSR). This technique does not gen- erate any: hydrogen generation; metal-steam reform- ing; mill-scale; nanoscale iron; electron microscopy Hydrogen

Azad, Abdul-Majeed

324

Running Head: Mental Health and Welfare Reform MENTAL HEALTH PROBLEMS AMONG SINGLE MOTHERS  

E-Print Network (OSTI)

Running Head: Mental Health and Welfare Reform MENTAL HEALTH PROBLEMS AMONG SINGLE MOTHERS Pennsylvania State University #12;Mental Health and Welfare Reform/2 MENTAL HEALTH PROBLEMS AMONG SINGLE outcomes. #12;Mental Health and Welfare Reform/3 INTRODUCTION The Personal Responsibility and Work

Shyy, Wei

325

THE CALIFORNIAN MODEL AS THE PARADIGM FOR SECOND GENERATION REFORMS IN LATINAMERIC  

E-Print Network (OSTI)

THE CALIFORNIAN MODEL AS THE PARADIGM FOR SECOND GENERATION REFORMS IN LATINAMERIC Hugh Rudnick for a second stage of reform, establishing highly flexible mechanisms of decentralised exchanges, and achieving about the validity of this new paradigm for second stage reforms. They question themselves

Catholic University of Chile (Universidad Católica de Chile)

326

the great invisible pension reform in the uni ted states the economics of social insurance  

E-Print Network (OSTI)

126 the great invisible pension reform in the uni ted states 127 the economics of social insurance: 4 the great InvIsIble PensIon reForm In the unIted states Krzysztof Ostaszewski Is the US bankrupt failure around the world 128 the great invisible pension reform in the uni ted states 129 · every working

Ostaszewski, Krzysztof M.

327

Fiscal Sustainability and Retirement Security: A Reform Proposal for the Illinois State Universities  

E-Print Network (OSTI)

situation: health care and retirement. First, Medicaid expenditures, already a substantial share of state1 Fiscal Sustainability and Retirement Security: A Reform Proposal for the Illinois State errors, are those of the authors alone. I.The Urgent Need for Reform Public pension reform is a national

Illinois at Chicago, University of

328

PHS 650 Summer 2011 Page 1 State-Level Health System and Coverage Reform 2011  

E-Print Network (OSTI)

and describe two state-based reforms underway in Wisconsin's health care industry. Topics/Readings The Big Patient Protection and Affordable Care Act Current State-Level Trends and Health Reforms The SyllabusPHS 650 Summer 2011 Page 1 State-Level Health System and Coverage Reform 2011 Course Overview

Sheridan, Jennifer

329

Health Care Reform: What School Mental Health Professionals Need to Know  

E-Print Network (OSTI)

Health Care Reform: What School Mental Health Professionals Need to Know On March 23, 2010, President Obama signed comprehensive health care reform, the Patient Protection and Affordable Care Act (ACA), into law (P.L. 111-148). This major reform to health care certainly has had and will continue to have

Weber, David J.

330

A review of "Nuns’ Chronicles and Convent Culture in Renaissance and Counter-Reformation Italy." by K. J. P. Lowe  

E-Print Network (OSTI)

150 SEVENTEENTH-CENTURY NEWS Women?s writing scholars and English drama historians will benefit from her study. K. J. P. Lowe. Nuns? Chronicles and Convent Culture in Renaissance and Counter- Reformation Italy. Cambridge: Cambridge University... Press, 2003. xvi + 437 pp. + 42 illus. $90.00. Review by THOMAS WORCESTER, COLLEGE OF THE HOLY CROSS. Vernacular chronicles of three convents form the basis of this study: Santa Maria delle Vergini (Venice), known as Le Vergini; Santa Maria...

Thomas Worcester

2005-01-01T23:59:59.000Z

331

After welfare reform and an economic boom: why is child  

E-Print Network (OSTI)

and 1999 OECD purchasing power parities, the U.S. rate remains well-above those of France, Canada, Germany and welfare reform mandated increased labor supply from single mothers. As a result, the labor force 1999 constant dollars) in private industry were $13.57 in December 1999, 6.4 percent above the December

Shyy, Wei

332

ISSN 1745-9648 The Impact of Electricity Market Reform  

E-Print Network (OSTI)

ISSN 1745-9648 The Impact of Electricity Market Reform on Consumers by Catherine Waddams Price ESRC, University of East Anglia CCP Working Paper 08-7 Abstract: We examine the effect of current electricity, where household expenditure surveys and electricity tariffs are available, we analyse the effects

Feigon, Brooke

333

Catalytic Membrane Reactor for Extraction of Hydrogen from Bioethanol Reforming  

E-Print Network (OSTI)

-gas-shift catalytic membrane reactor, and (2) a multi-layer design for bioethanol reforming. A two-dimensional model is developed to describe reaction and diffusion in the catalytic membrane coupled with plug-flow equations in the retentate and permeate volumes using...

Kuncharam, Bhanu Vardhan

2013-11-26T23:59:59.000Z

334

ISSN 1745-9648 Electricity Reform in Serbia  

E-Print Network (OSTI)

ISSN 1745-9648 Electricity Reform in Serbia by Sandra Jednak Faculty of Organizational Sciences in Serbia have been started, and certain results were achieved. But, the electric power infrastructure decided whether the Serbian Electric Power Industry will be privatised, and if it is privatised which

Feigon, Brooke

335

ISSN 1745-9648 Electricity Reform in Romania  

E-Print Network (OSTI)

ISSN 1745-9648 Electricity Reform in Romania by Oana Diaconu Department of Economics and Management-11 Abstract: Romania is a net exporter of electricity to the SE Europe region. Its performance of this role for international transmission. Romania has committed itself to an electricity restructuring plan that includes

Feigon, Brooke

336

The Clean Development Mechanism and Power Sector Reforms in Developing  

E-Print Network (OSTI)

regions include stimulating private sector financing, increasing operational and managerial efficiencies and lowering electricity tariffs #12;The CDM and renewable energy · Power sector reforms could potentially require higher investments for electricity generation than conventional fuel projects · Can also offer

337

Argonne National Laboratory Chemical Engineering Division Catalysts for autothermal reforming  

E-Print Network (OSTI)

Krause Chemical Engineering Division Argonne National Laboratory Hydrogen, Fuel Cells, and Infrastructure2, CO, CO2, and CH4) as a function of: catalyst composition fuel composition and sulfur content,110,861) awarded Oct 2000: CRADA w/H2Fuel to commercialize reformer Aug 2001: Began work on perovskite catalysts

338

The Role of Informatics in Health Care Reform  

E-Print Network (OSTI)

The Role of Informatics in Health Care Reform Yueyi I. Liu, MD, PhD, Daniel L. Rubin, MD, MS Improving health care quality while simultaneously reducing cost has become a high priority of health care (such as radiation dose tracking) and quality initiatives. Key Words: Informatics; health care. ª

Rubin, Daniel L.

339

Healthcare Reform in Texas: How the Affordable Care Act (ACA)  

E-Print Network (OSTI)

Healthcare Reform in Texas: How the Affordable Care Act (ACA) Will Impact Small Employer Health requirements, the function of health insurance exchanges and the future of employer-sponsored health insurance Shield of Texas Katrina Daniel Associate Commissioner, Life, Accident and Health Section Regulatory

O'Toole, Alice J.

340

Durability Testing of Fluidized Bed Steam Reforming Products  

SciTech Connect

Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of radioactive wastes but especially aqueous high sodium wastes at the Hanford site, at the Idaho National Laboratory (INL), and at the Savannah River Site (SRS). The FBSR technology converts organic compounds to CO{sub 2} and H{sub 2}O, converts nitrate/nitrite species to N{sub 2}, and produces a solid residue through reactions with superheated steam, the fluidizing media. If clay is added during processing a ''mineralized'' granular waste form can be produced. The mineral components of the waste form are primarily Na-Al-Si (NAS) feldspathoid minerals with cage-like and ring structures and iron bearing spinel minerals. The cage and ring structured minerals atomically bond radionuclides like Tc{sup 99} and Cs{sup 137} and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals appear to stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Durability testing of the FBSR products was performed using ASTM C1285 (Product Consistency Test) and the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP). The FBSR mineral products (bed and fines) evaluated in this study were found to be two orders of magnitude more durable than the Hanford Low Activity Waste (LAW) glass requirement of 2 g/m{sup 2} release of Na{sup +}. The PCT responses for the FBSR samples tested were consistent with results from previous FBSR Hanford LAW product testing. Differences in the response can be explained by the minerals formed and their effects on PCT leachate chemistry.

JANTZEN, CAROL M.; PAREIZS, JOHN M.; LORIER, TROY H.; MARRA, JAMES C.

2005-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

HH22 Reformer, Fuel Cell Power Plant,Reformer, Fuel Cell Power Plant, & Vehicle Refueling System& Vehicle Refueling System  

E-Print Network (OSTI)

sufficient hydrogen demand develops. #12;4 Relevant DOE Program Objectives Reduce dependence on foreign oil Promote use of diverse, domestic energy resources ­ Natural gas reformation Develop and demonstrate on test fill tank, CNG/H2 ICE vehicles and H2 Fuel Cell vehicles. Fuel dispensing integrated with City

342

Wellcome Trust SUBMISSION OF EVIDENCE Wellcome Trust response to the NHS Future Forum inquiry into the NHS reforms  

E-Print Network (OSTI)

into the NHS reforms October 2011 1 NHS Future Forum: Inquiry into the NHS reforms Response by the Wellcome focus primarily on the impact of the reforms on health research and innovation, which run throughout the Future Forum's four themes. 3. The reforms of the NHS and public health systems must bring about

Rambaut, Andrew

343

Wellcome Trust SUBMISSION OF EVIDENCE Wellcome Trust response to Department for Education: Reforming Key Stage 4 qualifications  

E-Print Network (OSTI)

: Reforming Key Stage 4 qualifications December 2012 Department for Education: Reforming Key Stage 4 science skills. 2. We are pleased to have the opportunity to respond to the consultation on reforms to Key consultations on the reform to curriculum and assessment at various stages of schooling. There is an opportunity

Rambaut, Andrew

344

Wellcome Trust CONSULTATION RESPONSE Wellcome Trust response to Ofqual Consultation: Completing GCSE, AS and A Level Reform -July 2014  

E-Print Network (OSTI)

GCSE, AS and A Level Reform - July 2014 1 Ofqual: Completing GCSE, AS and A Level Reform Response core content in partnership does not deter exam boards from reforming worthwhile qualifications. 5: Completing GCSE, AS and A Level Reform - July 2014 2 6. Under the new proposals, exam boards will be required

Rambaut, Andrew

345

BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids (Presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

High Pressure Steam Reforming of High Pressure Steam Reforming of Bio-Derived Liquids S. Ahmed, S. Lee, D. Papadias, and R. Kumar November 6, 2007 Laurel, MD Research sponsored by the Hydrogen, Fuel Cells, and Infrastructure Technologies Program of DOE's Office of Energy Efficiency and Renewable Energy Rationale and objective Rationale „ Steam reforming of liquid fuels at high pressures can reduce hydrogen compression costs - Much less energy is needed to pressurize liquids (fuel and water) than compressing gases (reformate or H 2 ) „ High pressure reforming is advantageous for subsequent separations and hydrogen purification Objective „ Develop a reformer design that takes advantage of the savings in compression cost in the steam reforming bio-derived liquid fuels - Metric:

346

A review of "Reformed Theology and Visual Culture: the Protestant Imagination from Calvin to Edwards." by William A. Dyrness  

E-Print Network (OSTI)

REVIEWS 1 William A. Dyrness. Reformed Theology and Visual Culture: the Protestant Imagination from Calvin to Edwards. Cambridge: Cambridge University Press, 2004. xv + 339 pp. + 43 illus. $85.00. Review by GRAHAM PARRY, UNIVERSITY OF YORK... into the early eighteenth century with a study of the ethos of Jonathan Edwards and his associates, Dyrness pursues his search for a distinc- tive aesthetic of Puritanism without discovering more than the familiar and recognised values of simplicity, inwardness...

Graham Parry

2005-01-01T23:59:59.000Z

347

Hydrogen From MillHydrogen From Mill--Scale Waste Via MetalScale Waste Via Metal--Steam ReformingSteam Reforming INTRODUCTIONINTRODUCTION  

E-Print Network (OSTI)

1 Hydrogen From MillHydrogen From Mill--Scale Waste Via MetalScale Waste Via Metal--Steam ReformingSteam Reforming INTRODUCTIONINTRODUCTION Hydrogen is considered to be the ideal energy carrying medium for fuel and supplying hydrogen to the end user in more reversible, much simpler and far safer ways. Metal-steam

Azad, Abdul-Majeed

348

Reforming petroleum-based fuels for fuel cell vehicles : composition-performance relationships.  

SciTech Connect

Onboard reforming of petroleum-based fuels, such as gasoline, may help ease the introduction of fuel cell vehicles to the marketplace. Although gasoline can be reformed, it is optimized to meet the demands of ICEs. This optimization includes blending to increase the octane number and addition of oxygenates and detergents to control emissions. The requirements for a fuel for onboard reforming to hydrogen are quite different than those for combustion. Factors such as octane number and flame speed are not important; however, factors such as hydrogen density, catalyst-fuel interactions, and possible catalyst poisoning become paramount. In order to identify what factors are important in a hydrocarbon fuel for reforming to hydrogen and what factors are detrimental, we have begun a program to test various components of gasoline and blends of components under autothermal reforming conditions. The results indicate that fuel composition can have a large effect on reforming behavior. Components which may be beneficial for ICEs for their octane enhancing value were detrimental to reforming. Fuels with high aromatic and naphthenic content were more difficult to reform. Aromatics were also found to have an impact on the kinetics for reforming of paraffins. The effects of sulfur impurities were dependent on the catalyst. Sulfur was detrimental for Ni, Co, and Ru catalysts. Sulfur was beneficial for reforming with Pt catalysts, however, the effect was dependent on the sulfur concentration.

Kopasz, J. P.; Miller, L. E.; Ahmed, S.; Devlin, P. R.; Pacheco, M.

2001-12-04T23:59:59.000Z

349

Long term savings decisions: Financial reform, peer effects and ethnicity  

Science Journals Connector (OSTI)

Abstract In 2005, a drastic reform in the Israeli capital market shifted the power to choose savings vehicles from employers to individuals. Using a unique dataset from a large employer, this event provides us a rare window into individuals’ savings decisions and the effect of their social environment. In the first year following the reform's implementation, 7% of the employees switched out of the fund in which they all previously saved. Choice of fund was not associated with observable measures of fund performance, but was strongly affected by the employees’ social environment. Exploiting within-department variation in peer groups, we find that savings decisions were strongly influenced by the choices of co-workers from the same ethnic group. Interviews also point to the influence of non-professional colleagues.

Yevgeny Mugerman; Orly Sade; Moses Shayo

2014-01-01T23:59:59.000Z

350

Addiction treatment centers' progress in preparing for health care reform  

Science Journals Connector (OSTI)

Abstract The Patient Protection and Affordable Care Act (PPACA) is expected to significantly alter addiction treatment service delivery. Researchers designed the Health Reform Readiness Index (HRRI) for addiction treatment organizations to assess their readiness for the PPACA. Four-hundred twenty-seven organizations completed the HRRI throughout a 3-year period, using a four-point scale to rank their readiness on 13 conditions. HRRI results completed during two different time periods (between 10/1/2010–6/30/2011 and 9/1/2011–9/30/2012) were analyzed and compared. Most respondents self-assessed as being in the early stages of preparation for 9 of the 13 conditions. Survey results showed that organizations with annual budgets  $5 million (n = 132). The HRRI results suggest that the addiction field, and in particular smaller organizations, is not preparing adequately for health care reform; organizations that are making preparations are making only modest gains.

Todd D. Molfenter

2014-01-01T23:59:59.000Z

351

In situ Gas Conditioning in Fuel Reforming for Hydrogen Generation  

SciTech Connect

The production of hydrogen for fuel cell applications requires cost and energy efficient technologies. The Absorption Enhanced Reforming (AER), developed at ZSW with industrial partners, is aimed to simplify the process by using a high temperature in situ CO2 absorption. The in situ CO2 removal results in shifting the steam reforming reaction equilibrium towards increased hydrogen concentration (up to 95 vol%). The key part of the process is the high temperature CO2 absorbent. In this contribution results of Thermal Gravimetric Analysis (TGA) investigations on natural minerals, dolomites, silicates and synthetic absorbent materials in regard of their CO2 absorption capacity and absorption/desorption cyclic stability are presented and discussed. It has been found that the inert parts of the absorbent materials have a structure stabilizing effect, leading to an improved cyclic stability of the materials.

Bandi, A.; Specht, M.; Sichler, P.; Nicoloso, N.

2002-09-20T23:59:59.000Z

352

Modelling, simulation and sensitivity analysis of steam-methane reformers  

Science Journals Connector (OSTI)

A mathematical model to calculate temperature, conversion and pressure profiles for static operations in steam-methane reformers was simulated. A rigorous kinetic model describing steam-methane reactions was compared to a first order one and an empirical heat distribution model was fitted to describe heat absorbed along the reactor length. A control interface was simulated to allow sensitivity analysis with different control schemes. The kinetic models were tested with data from industrial steam-gas reformers. Simulation results agreed with actual plant data for conversion, temperature and pressure. Nevertheless, the first order kinetic model gave unrealistic sensitivity results to pressure and steam-to-carbon ratio variations. The rigorous model could confidently be used for design analysis, control, and economic evaluation purposes.

I.M. Alatiqi; A.M. Meziou; G.A. Gasmelseed

1989-01-01T23:59:59.000Z

353

Fuel cell system with combustor-heated reformer  

DOE Patents (OSTI)

A fuel cell system including a fuel reformer heated by a catalytic combustor fired by anode effluent and/or fuel from a liquid fuel supply providing fuel for the fuel cell. The combustor includes a vaporizer section heated by the combustor exhaust gases for vaporizing the fuel before feeding it into the combustor. Cathode effluent is used as the principle oxidant for the combustor.

Pettit, William Henry (Rochester, NY)

2000-01-01T23:59:59.000Z

354

Catalyst and process for steam-reforming of hydrocarbons  

SciTech Connect

An improved catalyst and an improved process for use of the catalyst in the steam-hydrocarbon reforming reaction are disclosed. The catalyst comprises a group VIII metal on a cylindrical ceramic support consisting essentially of alpha alumina and having a plurality of gas passages extending axially therethrough. These supported catalysts display a higher geometric surface area and a lower pressure drop than do standard rings.

Atwood, K.; Merriam, J.S.; Wright, J.H.

1980-11-11T23:59:59.000Z

355

Tax reform would renew R&D tax credit  

Science Journals Connector (OSTI)

Tax reform would renew R&D tax credit ... And among all the business tax incentives that are repealed or curtailed in the most recent Administration tax plan, the credit for R&D expenditures, which expires this year, is somewhat exceptional in that it would be renewed at least until Dec. 31,1988. ... However, as detailed in the Treasury Department's 460-page explanation of the tax proposal, the definition of qualifying research would be tightened. ...

1985-06-03T23:59:59.000Z

356

Hydrogen production by methane steam reforming over Ru supported on Ni–Mg–Al mixed oxides prepared via hydrotalcite route  

Science Journals Connector (OSTI)

Abstract Catalytic performance of Ru/NixMg6?xAl2 800 800 mixed oxides, with x = 2, 4 and 6, x being the molar ratio, towards Methane Steam Reforming, was studied. NixMg6?xAl2 800 oxide, used as support, was prepared via hydrotalcite route. It was thermally stabilized at 800 °C, impregnated with 0.5 wt.% ruthenium using ruthenium (III) nitrosyl nitrate Ru(NO) (NO3)3 precursor and then calcined again at 800 °C under an air flow. Ruthenium impregnation significantly enhanced the reactivity of the oxides in Methane Steam Reforming. In fact, it was found, that even with a low ruthenium content (0.5 wt.%), ruthenium oxide particles are formed but are well dispersed over the surface of the oxide NixMg6?xAl2 800. Ru/Ni6Al2 800 800 showed better catalytic performances, towards Methane Steam Reforming, than ruthenium impregnated on the two other supports. Indeed, nickel content is higher in Ni6Al2 800 than in the other studied supports and therefore the probability of Ni–Ru interaction should be greater and consequently catalytic performances could be improved.

Mira Nawfal; Cédric Gennequin; Madona Labaki; Bilal Nsouli; Antoine Aboukaïs; Edmond Abi-Aad

2014-01-01T23:59:59.000Z

357

New data on gas-phase radical reactions in the steam reforming of methane in the presence of catalysts: I. Nickel catalysts  

Science Journals Connector (OSTI)

Methane pyrolysis and steam reforming were studied over a series of nickel...2O3, Ni/MgO, and Ni/LiAlO2) under the same conditions (650-750°C, PCH4...= 0.001-0.03 MPa). Unlike heterogeneous reaction of pyrolysis,...

I. I. Bobrova; V. V. Chesnokov; N. N. Bobrov; V. I. Zaikovskii…

358

Catalytic Properties of MnO, Fe2O3, and MnFe2O4 in the Steam Reforming of Ethanol  

Science Journals Connector (OSTI)

The catalytic activity of manganese ferrite MnFe2O4 and the oxides MnO and Fe2O3 in the steam reforming of ethanol (SRE) has been studied. The similarity...2O3 and MnFe2O4 has been established which may indicate ...

L. Yu. Dolgykh; I. L. Stolyarchuk; L. A. Staraya…

2014-09-01T23:59:59.000Z

359

REFORMING OF LIQUID HYDROCARBONS IN A NOVEL HYDROGEN-SELECTIVE MEMBRANE-BASED FUEL PROCESSOR  

SciTech Connect

We propose to develop an inorganic metal-metal composite membrane to study reforming of liquid hydrocarbons and methanol by equilibrium shift in membrane-reactor configuration, viewed as fuel processor. Based on our current understanding and experience in the Pd-ceramic composite membrane, we propose to further develop this membrane to a Pd and Pd-Ag alloy membrane on microporous stainless steel support to provide structural reliability from distortion due to thermal cycling. Because of the metal-metal composite structure, we believe that the associated end-seal problem in the Pd-ceramic composite membrane in tubular configuration would not be an issue at all. We plan to test this membrane as membrane-reactor-separator for reforming liquid hydrocarbons and methanol for simultaneous production and separation of high-purity hydrogen for PEM fuel cell applications. To improve the robustness of the membrane film and deep penetration into the pores, we have used osmotic pressure field in the electroless plating process. Using this novel method, we deposited thin Pd-film on the inside of microporous stainless steel tube and the deposited film appears to robust and defect free. Work is in progress to evaluate the hydrogen perm-selectivity of the Pd-stainless steel membrane.

Shamsuddin Ilias

2003-06-30T23:59:59.000Z

360

Steam Reforming of Methane Utilizing Solar Heat  

Science Journals Connector (OSTI)

There is a worldwide interest to use solar energy to save or substitute fossil material, which is taken as fuel or chemical feedstock in present technologies. Among the possibilities, which are studied in deta...

W. D. Müller

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

The Politics of Land Reform in Uganda  

E-Print Network (OSTI)

their interests. They evaluate risks and rewards, and they choose. Protecting property - whither government or non-government protection - is foundational to both types of markets, and can determine citizens' choice. In this study, successive governments in Uganda...

Gibb, Ryan

2013-05-31T23:59:59.000Z

362

Hydrogen Production by Catalytic Steam Reforming of Bio-oil, Naphtha  

Science Journals Connector (OSTI)

Hydrogen production by catalytic steam reforming of the bio-oil, naphtha, and CH4 was investigated over a novel metal-doped catalyst of (Ca24Al28O64)4+4O?/Mg (C12A7-Mg). The catalytic steam reforming was investigated from 250 to 850°C in the fixed-bed continuous flow reactor. For the reforming of bio-oil, the yield of hydrogen of 80% was obtained at 750°C, and the maximum carbon conversion is nearly close to 95% under the optimum steam reforming condition. For the reforming of naphtha and CH4, the hydrogen yield and carbon conversion are lower than that of bio-oil at the same temperature. The characteristics of catalyst were also investigated by XPS. The catalyst deactivation was mainly caused by the deposition of carbon in the catalytic steam reforming process.

Yue Pan; Zhao-xiang Wang; Tao Kan; Xi-feng Zhu; Quan-xin Li

2006-01-01T23:59:59.000Z

363

Reformer-pressure swing adsorption process for the production of carbon monoxide  

SciTech Connect

An improved process for the production of carbon monoxide by the steam reforming of hydrocarbons is described comprising: (a) catalytically reacting a fluid hydrocarbon feed stream with steam in a steam reformer; (b) passing the reformer effluent containing hydrogen, carbon monoxide and carbon dioxide from the steam reformer, without scrubbing to remove the carbon dioxide content thereof, to a pressure swing adsorption system having at least four adsorbent beds, each bed of which, on a cyclic basis, undergoes a processing sequence; (c) recycling the carbon dioxide-rich stream to the steam reformer for reaction with additional quantities of the hydrocarbon feed stream being passed to the stream reformer to form additional quantities of carbon monoxide and hydrogen, with product recovery being enhanced and the need for employing a carbon dioxide wash system being obviated.

Fuderer, A.

1988-02-23T23:59:59.000Z

364

PROCS-VERBAL DE DPOUILLEMENT ELECTIONS A LA COMMISSION DE REFORME DE L'IRD  

E-Print Network (OSTI)

PROCÃ?S-VERBAL DE DÃ?POUILLEMENT ELECTIONS A LA COMMISSION DE REFORME DE L'IRD SCRUTIN DU 6 MAI 2009 TALAMOND, Catherine BONTE #12;PROCÃ?S-VERBAL DE DÃ?POUILLEMENT ELECTIONS A LA COMMISSION DE REFORME DE L BONTE #12;PROCÃ?S-VERBAL DE DÃ?POUILLEMENT ELECTIONS A LA COMMISSION DE REFORME DE L'IRD SCRUTIN DU 6 MAI

365

Working Group Meeting Presentation Guidance at a Glance Distributed Reforming of Biomass Pyrolysis Oils  

E-Print Network (OSTI)

(75%) Char (13%) Gas (12%) Catalytic Auto-thermal Reforming of Bio-Oil at 650oC: 0.71 CH1.98O0.76 + 0 Case (Ethanol Case) Bio-oil Storage Tank $106,040 Reformer $803,000 Shift Reactor, PSA, BOP $1 Oils DOE Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Meeting November 6

366

Idle catalytic reformer can be converted to isomerization unit or jet-fuel treater  

SciTech Connect

This article discusses the economic advantages in conversion of catalytic reformers idled by reduced demand or rendered obsolete by replacement with modern technology. An older semi-regenerative reformer can be converted to a modern C4 or C5/C6 isomerization unit or to a kerosene hydrotreater to meet jet fuel specifications. Reactor design parameters operating conditions, and equipment sizing required for the highly endothermic reforming process are discussed.

Cobb, D.D.; Chapel, D.G.

1985-06-03T23:59:59.000Z

367

Malpractice Reform — Opportunities for Leadership by Health Care Institutions and Liability Insurers  

Science Journals Connector (OSTI)

...care systems or states implement innovative reforms. Second, institutional reforms can be led by physician champions and other insiders, promoting buy-in from clinical and risk-management staff. Third, because most private approaches do not abridge legal remedies, they may be more palatable to consumer... Innovative malpractice reforms can be implemented by health care institutions and liability insurers without requiring changes in the law. Michelle Mello and Dr. Thomas Gallagher focus on emerging models of disclosure of medical injuries and early ...

Mello M.M.; Gallagher T.H.

2010-04-15T23:59:59.000Z

368

Steam Reforming, 6-in. Bench-Scale Design and Testing Project -- Technical and Functional Requirements Description  

SciTech Connect

Feasibility studies and technology development work are currently being performed on several processes to treat radioactive liquids and solids currently stored at the Idaho Nuclear Technology and Engineering Center (INTEC), located within the Idaho National Engineering and Environmental Laboratory (INEEL). These studies and development work will be used to select a treatment process for treatment of the radioactive liquids and solids to meet treatment milestones of the Settlement Agreement between the Department of Energy and the State of Idaho. One process under consideration for treating the radioactive liquids and solids, specifically Sodium-Bearing Waste (SBW) and tank heel solids, is fluid bed steam reforming (FBSR). To support both feasibility and development studies a bench-scale FBSR is being designed and constructed. This report presents the technical and functional requirements, experimental objectives, process flow sheets, and equipment specifications for the bench-scale FBSR.

Losinski, Sylvester John; Marshall, Douglas William

2002-08-01T23:59:59.000Z

369

A Metric Approach to Elastic Reformations  

Science Journals Connector (OSTI)

We study a variational framework to compare shapes, modeled as Radon measures on ${\\mathbb{R}}^{N}$ , in order to quantify how they differ from isometric copies. ... Keywords: 37J50, 49Q15, 49Q20, Calculus of variations, Elasticity, Geometric measure theory, Mass transportation theory, Shape analysis

Luca Granieri, Francesco Maddalena

2014-10-01T23:59:59.000Z

370

Retail restructuring in urban China in the reform era: the case of Beijing.  

E-Print Network (OSTI)

??This dissertation examines the radical economic restructuring and urban transformation in urban China in the reform era through a detailed investigation into the retail sector… (more)

Wang, Enru

2005-01-01T23:59:59.000Z

371

The evolution of the Weapon System Reform Act of 2009 (Public Law 111-23) .  

E-Print Network (OSTI)

??In evaluating the implications of the Weapon System Acquisition Reform Act of 2009 (WSARA), we compare the position of prior acquisition acts and DoD acquisition… (more)

McWhorter, Michael

2011-01-01T23:59:59.000Z

372

Modeling of membrane reactor for steam methane reforming: From granular to structured catalysts  

Science Journals Connector (OSTI)

Different types and operating modes of a tubular membrane reactor for steam methane reforming with a production rate of 0.6...

A. B. Shigarov; V. A. Kirillov

2012-04-01T23:59:59.000Z

373

Computational heterogeneous catalysis applied to steam methane reforming over nickel and nickel/silver catalysts .  

E-Print Network (OSTI)

??The steam methane reforming (SMR) reaction is the primary industrial means for producing hydrogen gas. As such, it is a critical support process for applications… (more)

Blaylock, Donnie Wayne

2011-01-01T23:59:59.000Z

374

Methane Steam Reforming in Hydrogen-permeable Membrane Reactor for Pure Hydrogen Production  

Science Journals Connector (OSTI)

Steam reforming of methane over a ruthenium catalyst has been carried ... hydrogen separation from the reaction mixture, the methane conversion significantly exceeds the equilibrium value, which ... an important ...

Yasuyuki Matsumura; Jianhua Tong

2008-12-01T23:59:59.000Z

375

Health Care 2009: The Burden of Health Care Costs for Working Families — Implications for Reform  

Science Journals Connector (OSTI)

On June 2, 2009, President Barack Obama's Council of Economic Advisers released a report examining the economic case for health care reform, in which they underscored the importance of cost containment to the long-term sustainability of any reform. Despite widespread recognition of the importance of... On June 2, 2009, President Barack Obama's Council of Economic Advisers released a report examining the economic case for health care reform, in which they underscored the importance of cost containment to the long-term sustainability of any reform.1 ...

Polsky D.; Grande D.

2009-07-30T23:59:59.000Z

376

A Fast Start-up On-Board Fuel Reformer for NOx Adsorber Regeneration...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Processor for Rapid and Efficient Regeneration of Single Leg NOx Adsorber Systems Hydrogen generation from plasmatron reformers and use for diesel exhaust aftertreatment...

377

From plan to practice: implementing SB 617, California's regulatory review reform.  

E-Print Network (OSTI)

??SB 617 (Calderon & Pavley, 2011) is an ambitious experiment to improve state regulations and increase government transparency. The statute reforms California’s regulatory review process… (more)

Marin, Angela K.

2013-01-01T23:59:59.000Z

378

Improved Heat Transfer and Performance of High Intensity Combustion Systems for Reformer Furnace Applications  

E-Print Network (OSTI)

of the above premise. The application of vortex stabilized high intensity burners for reformer furnaces in the petrochemical industry is then reviewed and emphasized....

Williams, F. D. M.; Kondratas, H. M.

1983-01-01T23:59:59.000Z

379

Giannini Foundation of Agricultural Economics New Horizons for Rural Reform in China  

E-Print Network (OSTI)

11 Giannini Foundation of Agricultural Economics New Horizons for Rural Reform in China: Resources Population Rice Fruit #12;12 Giannini Foundation of Agricultural Economics dominate domestic production

Kammen, Daniel M.

380

E-Print Network 3.0 - arc plasma-catalyst reformer Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: by reforming their political institutions. States such as Indonesia, Thailand, the Philippines, Taiwan and East... systems and other key democratic...

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

The Ambiguous Transition: Building State Capacity and Expanding Popular Participation in Venezuela's Agrarian Reform  

E-Print Network (OSTI)

El Universal, Caracas, Venezuela. Bengelsdorf, Carollee.Crisis and Reform in Venezuela. ” Journal of Interamerican2):27-61. Datamonitor. (2004). “Venezuela Country Profile. ”

Page, Tiffany Linton

2011-01-01T23:59:59.000Z

382

Regulatory Reform in the Wake of the Financial Crisis of 2007—2008  

E-Print Network (OSTI)

Purpose – The purpose of this paper is to analyse regulatory reform in the wake of the financial crisis of 2007-2008.

Lo, Andrew W.

383

Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation)  

Energy.gov (U.S. Department of Energy (DOE))

Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

384

Hydrogen Generation from Biomass-Derived Carbohydrates via Aqueous-Phase Reforming  

Energy.gov (U.S. Department of Energy (DOE))

Presentation by Virent Energy Systems, Inc. at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting.

385

BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids (Presentation)  

Energy.gov (U.S. Department of Energy (DOE))

Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

386

Investigation of Bio-Ethanol Steam Reforming over Cobalt-based Catalysts (Presentation)  

Energy.gov (U.S. Department of Energy (DOE))

Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

387

Electrochemical fuel cell generator having an internal and leak tight hydrocarbon fuel reformer  

DOE Patents (OSTI)

An electrochemical fuel cell generator configuration is made having a generator section which contains a plurality of axially elongated fuel cells, each cell containing a fuel electrode, air electrode, and solid oxide electrolyte between the electrodes, in which axially elongated dividers separate portions of the fuel cells from each other, and where at least one divider also reforms a reformable fuel gas mixture prior to electricity generation reactions, the at least one reformer-divider is hollow having a closed end and an open end entrance for a reformable fuel mixture to pass to the closed end of the divider and then reverse flow and pass back along the hollowed walls to be reformed, and then finally to pass as reformed fuel out of the open end of the divider to contact the fuel cells, and further where the reformer-divider is a composite structure having a gas diffusion barrier of metallic foil surrounding the external walls of the reformer-divider except at the entrance to prevent diffusion of the reformable gas mixture through the divider, and further housed in an outer insulating jacket except at the entrance to prevent short-circuiting of the fuel cells by the gas diffusion barrier. 10 figs.

Dederer, J.T.; Hager, C.A.

1998-03-31T23:59:59.000Z

388

Electrochemical fuel cell generator having an internal and leak tight hydrocarbon fuel reformer  

DOE Patents (OSTI)

An electrochemical fuel cell generator configuration is made having a generator section which contains a plurality of axially elongated fuel cells, each cell containing a fuel electrode, air electrode, and solid oxide electrolyte between the electrodes, in which axially elongated dividers separate portions of the fuel cells from each other, and where at least one divider also reforms a reformable fuel gas mixture prior to electricity generation reactions, the at least one reformer-divider is hollow having a closed end and an open end entrance for a reformable fuel mixture to pass to the closed end of the divider and then reverse flow and pass back along the hollowed walls to be reformed, and then finally to pass as reformed fuel out of the open end of the divider to contact the fuel cells, and further where the reformer-divider is a composite structure having a gas diffusion barrier of metallic foil surrounding the external walls of the reformer-divider except at the entrance to prevent diffusion of the reformable gas mixture through the divider, and further housed in an outer insulating jacket except at the entrance to prevent short-circuiting of the fuel cells by the gas diffusion barrier.

Dederer, Jeffrey T. (Valencia, PA); Hager, Charles A. (Mars, PA)

1998-01-01T23:59:59.000Z

389

Sulfur-tolerant natural gas reforming for fuel-cell applications.  

E-Print Network (OSTI)

??An attractive simplification of PEM-FC systems operated with natural gas would be the use of a sulfur tolerant reforming catalyst, but such a catalyst has… (more)

Hennings, Ulrich

2010-01-01T23:59:59.000Z

390

E-Print Network 3.0 - abortion law reform Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

in Hagen Collection: Computer Technologies and Information Sciences 30 Health Care Reform Law Challenged in Courts President Barack Obama on March 23, 2010, signed into...

391

Efficiency impacts of the Chinese industrial transition: a quantitative evaluation of reforms in the coal industry  

Science Journals Connector (OSTI)

This paper explains the variation in technical efficiency across firms due to transitional reforms. A translog stochastic frontier production method incorporating regional heterogeneity and technical change is ap...

Xunpeng Shi; R. Quentin Grafton

2010-02-01T23:59:59.000Z

392

Production of high-octane gasoline on a semi-industrial catalytic reforming plant  

Science Journals Connector (OSTI)

Experiments have been carried out on the catalytic reforming at a pressure of 20 atm of a wide, straight-run gasoline fraction on an experimental industrial plant.

A. P. Fedorov; G. N. Maslyanskii…

1967-01-01T23:59:59.000Z

393

At the Nexus of Social Policy and Capital Markets: Pension Reform and Enterprise Governance in Germany  

E-Print Network (OSTI)

Company Pension Schemes in Germany,” Monthly Report, March.2001. “Pension Reform in Germany,” draft chapter in R. Kentof Stakeholderism in Germany,”forthcoming, Industrielle

Ziegler, J. Nicholas

2008-01-01T23:59:59.000Z

394

Autothermal and partial oxidation reformer-based fuel processor, method for improving catalyst function in autothermal and partial oxidation reformer-based processors  

DOE Patents (OSTI)

The invention provides a fuel processor comprising a linear flow structure having an upstream portion and a downstream portion; a first catalyst supported at the upstream portion; and a second catalyst supported at the downstream portion, wherein the first catalyst is in fluid communication with the second catalyst. Also provided is a method for reforming fuel, the method comprising contacting the fuel to an oxidation catalyst so as to partially oxidize the fuel and generate heat; warming incoming fuel with the heat while simultaneously warming a reforming catalyst with the heat; and reacting the partially oxidized fuel with steam using the reforming catalyst.

Ahmed, Shabbir; Papadias, Dionissios D.; Lee, Sheldon H. D.; Ahluwalia, Rajesh K.

2013-01-08T23:59:59.000Z

395

Mathematical modeling and heat transfer experiments for an annular bed methane-steam reformer  

SciTech Connect

A new type of catalytic reactor has been proposed for conducting endothermic chemical reactions. The reactor catalyst bed is in the form of a tubular reactor with an annular cross-section. Heat is supplied to the catalyst bed by countercurrent flowing gases on opposite sides of the annulus walls. This study consisted of the development of a mathematical model to describe the performance of an annular bed reactor employing the methane-steam reforming reaction for the production of hydrogen. The model is two-dimensional, and predicts both axial and radial temperature and concentration profiles throughout the reactor. The model was used to perform parameter sensitivity studies, reactor size optimization, and reactor scaleup.

Summers, W.A.

1986-01-01T23:59:59.000Z

396

Columbia River Hatchery Reform System-Wide Report.  

SciTech Connect

The US Congress funded the Puget Sound and Coastal Washington Hatchery Reform Project via annual appropriations to the US Fish and Wildlife Service (USFWS) beginning in fiscal year 2000. Congress established the project because it recognized that while hatcheries have a necessary role to play in meeting harvest and conservation goals for Pacific Northwest salmonids, the hatchery system was in need of comprehensive reform. Most hatcheries were producing fish for harvest primarily to mitigate for past habitat loss (rather than for conservation of at-risk populations) and were not taking into account the effects of their programs on naturally spawning populations. With numerous species listed as threatened or endangered under the Endangered Species Act (ESA), conservation of salmon in the Puget Sound area was a high priority. Genetic resources in the region were at risk and many hatchery programs as currently operated were contributing to those risks. Central to the project was the creation of a nine-member independent scientific review panel called the Hatchery Scientific Review Group (HSRG). The HSRG was charged by Congress with reviewing all state, tribal and federal hatchery programs in Puget Sound and Coastal Washington as part of a comprehensive hatchery reform effort to: conserve indigenous salmonid genetic resources; assist with the recovery of naturally spawning salmonid populations; provide sustainable fisheries; and improve the quality and cost-effectiveness of hatchery programs. The HSRG worked closely with the state, tribal and federal managers of the hatchery system, with facilitation provided by the non-profit organization Long Live the Kings and the law firm Gordon, Thomas, Honeywell, to successfully complete reviews of over 200 hatchery programs at more than 100 hatcheries across western Washington. That phase of the project culminated in 2004 with the publication of reports containing the HSRG's principles for hatchery reform and recommendations for Puget Sound/Coastal Washington hatchery programs, followed by the development in 2005 of a suite of analytical tools to support application of the principles (all reports and tools are available at www.hatcheryreform.us). In 2005, Congress directed the National Oceanic and Atmospheric Administration-Fisheries (NOAA Fisheries) to replicate the Puget Sound and Coastal Washington Hatchery Reform Project in the Columbia River Basin. The HSRG was expanded to 14 members to include individuals with specific knowledge about the Columbia River salmon and steelhead populations. This second phase was initially envisioned as a one-year review, with emphasis on the Lower Columbia River hatchery programs. It became clear however, that the Columbia River Basin needed to be viewed as an inter-connected ecosystem in order for the review to be useful. The project scope was subsequently expanded to include the entire Basin, with funding for a second year provided by the Bonneville Power Administration (BPA) under the auspices of the Northwest Power and Conservation Council's (NPCC) Fish and Wildlife Program. The objective of the HSRG's Columbia River Basin review was to change the focus of the Columbia River hatchery system. In the past, these hatchery programs have been aimed at supplying adequate numbers of fish for harvest as mitigation primarily for hydropower development in the Basin. A new, ecosystem-based approach is founded on the idea that harvest goals are sustainable only if they are compatible with conservation goals. The challenge before the HSRG was to determine whether or not conservation and harvest goals could be met by fishery managers and, if so, how. The HSRG determined that in order to address these twin goals, both hatchery and harvest reforms are necessary. The HSRG approach represents an important change of direction in managing hatcheries in the region. It provides a clear demonstration that current hatchery programs can indeed be redirected to better meet both conservation and harvest goals. For each Columbia River Basin Environmentally Significant Unit

Warren, Dan [Hatchery Scientific Review Group

2009-04-16T23:59:59.000Z

397

The Effect of Malpractice Reform on Emergency Department Care  

Science Journals Connector (OSTI)

...factors, not explicitly modeled, that are stable over time, such as teaching status or certain features of state tort law. In sensitivity analyses, we tested the effect of omitting the diagnosis covariates, since diagnosis might be affected by the physician's decision regarding admission, and the effect... One aim of malpractice reform has been to reduce the practice of defensive medicine. Laws in three states that changed the malpractice standard for emergency care to gross negligence did not substantially influence practice intensity in emergency departments.

Waxman D.A.Greenberg M.D.Ridgely M.S.Kellermann A.L.Heaton P.

2014-10-16T23:59:59.000Z

398

SMALL SCALE FUEL CELL AND REFORMER SYSTEMS FOR REMOTE POWER  

SciTech Connect

New developments in fuel cell technologies offer the promise of clean, reliable affordable power, resulting in reduced environmental impacts and reduced dependence on foreign oil. These developments are of particular interest to the people of Alaska, where many residents live in remote villages, with no roads or electrical grids and a very high cost of energy, where small residential power systems could replace diesel generators. Fuel cells require hydrogen for efficient electrical production, however. Hydrogen purchased through conventional compressed gas suppliers is very expensive and not a viable option for use in remote villages, so hydrogen production is a critical piece of making fuel cells work in these areas. While some have proposed generating hydrogen from renewable resources such as wind, this does not appear to be an economically viable alternative at this time. Hydrogen can also be produced from hydrocarbon feed stocks, in a process known as reforming. This program is interested in testing and evaluating currently available reformers using transportable fuels: methanol, propane, gasoline, and diesel fuels. Of these, diesel fuels are of most interest, since the existing energy infrastructure of rural Alaska is based primarily on diesel fuels, but this is also the most difficult fuel to reform, due to the propensity for coke formation, due to both the high vaporization temperature and to the high sulfur content in these fuels. There are several competing fuel cell technologies being developed in industry today. Prior work at UAF focused on the use of PEM fuel cells and diesel reformers, with significant barriers identified to their use for power in remote areas, including stack lifetime, system efficiency, and cost. Solid Oxide Fuel Cells have demonstrated better stack lifetime and efficiency in demonstrations elsewhere (though cost still remains an issue), and procuring a system for testing was pursued. The primary function of UAF in the fuel cell industry is in the role of third party independent testing. In order for tests to be conducted, hardware must be purchased and delivered. The fuel cell industry is still in a pre-commercial state, however. Commercial products are defined as having a fixed set of specifications, fixed price, fixed delivery date, and a warrantee. Negotiations with fuel cell companies over these issues are often complex, and the results of these discussions often reveal much about the state of development of the technology. This work includes some of the results of these procurement experiments. Fuel cells may one day replace heat engines as the source of electrical power in remote areas. However, the results of this program to date indicate that currently available hardware is not developed sufficiently for these environments, and that significant time and resources will need to be committed for this to occur.

Dennis Witmer

2003-12-01T23:59:59.000Z

399

Report of the Committee on Legislation and Regulatory Reform  

SciTech Connect

The report of the Committee on Legislation and Regulatory Reform covers legislative developments in the first session and early second session of the 102nd Congress. This Congress has been especially active on energy matters. The Persian Gulf War, the release of the President's National Energy Strategy (NES), and other factors created the impetus for consideration of comprehensive energy legislation. The report is divided into three parts. The first part describes the comprehensive energy legislation pending before the Congress. The second part describes pending environmental legislation. The third part of the report describes miscellaneous Congressional activity that should be of interest.

Not Available

1992-01-01T23:59:59.000Z

400

Stabilization of Savannah River National Laboartory (SRNL) Aqueous Waste by Fluidized Bed Steam Reforming (FBSR)  

SciTech Connect

The Savannah River National Laboratory (SRNL) is a multidisciplinary laboratory operated by Westinghouse Savannah River Company (WSRC) in Aiken, South Carolina. Research and development programs have been conducted at SRNL for {approx}50 years generating non-radioactive (hazardous and non-hazardous) and radioactive aqueous wastes. Typically the aqueous effluents from the R&D activities are disposed of from each laboratory module via the High Activity Drains (HAD) or the Low Activity Drains (LAD) depending on whether they are radioactive or not. The aqueous effluents are collected in holding tanks, analyzed and shipped to either H-Area (HAD waste) or the F/H Area Effluent Treatment Facility (ETF) (LAD waste) for volume reduction. Because collection, analysis, and transport of LAD and HAD waste is cumbersome and since future treatment of this waste may be curtailed as the F/H-Area evaporators and waste tanks are decommissioned, SRNL laboratory operations requested several proof of principle demonstrations of alternate technologies that would define an alternative disposal path for the aqueous wastes. Proof of principle for the disposal of SRNL HAD waste using a technology known as Fluidized Bed Steam Reforming (FBSR) is the focus of the current study. The FBSR technology can be performed either as a batch process, e.g. in each laboratory module in small furnaces with an 8'' by 8'' footprint, or in a semi-continuous Bench Scale Reformer (BSR). The proof of principle experiments described in this study cover the use of the FBSR technology at any scale (pilot or full scale). The proof of principle experiments described in this study used a non-radioactive HAD simulant.

Jantzen, C

2004-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Computational Investigation of the Thermochemistry and Kinetics of Steam Methane Reforming Over a Multi-Faceted Nickel Catalyst  

Science Journals Connector (OSTI)

A microkinetic model of steam methane reforming over a multi-faceted nickel surface using ... on the Ni(100) surface. The primary reforming pathway is predicted to be through C* ... reactions are predicted to be ...

D. Wayne Blaylock; Yi-An Zhu; William H. Green

2011-09-01T23:59:59.000Z

402

Distributed Reforming of Biomass Pyrolysis Oils: Cooperative Research and Development Final Report, CRADA number CRD-06-00192  

SciTech Connect

The objective of this project is for Chevron and NREL to collaborate in determining the effect of bio-oil composition variability on autothermal reforming performance including bio-oil volatilization, homogeneous oxidative cracking, and catalytic reforming.

Czernik, S.

2010-07-01T23:59:59.000Z

403

Copyright reform on the EU level European Network for Copyright in support of  

E-Print Network (OSTI)

a copyright reform on the EU level? Rainer Kuhlen University of Konstanz, HumboldtUniversity Berlin, IPR;Copyright reform on the EU level Extension of IPR in time Extension of IPR to living objects and other objects in nature Extension of IPR to software (still controversial, at least in the EU) Introduction

Kuhlen, Rainer

404

Report of the Ad Hoc Committee on Washington Natural Resource Agency Reform  

E-Print Network (OSTI)

Report of the Ad Hoc Committee on Washington Natural Resource Agency Reform February 16, 2010 recommended formation of an ad hoc committee to evaluate opportunities for SFR and others in College. As a result, the Washington Natural Resource Agency Reform ad hoc Committee was established and given

Borenstein, Elhanan

405

Sir John Tomes FRS, Fellows of the Royal Society, and Dental Reform in the nineteenth Century  

Science Journals Connector (OSTI)

...637-639 (1991). 57 I. Loudon, Medical care and the general practitioner 1750-1850...Fellows of the Royal Society, and dental reform in the nineteenth century. | In this paper...profession of dentistry shared in the process of reform and scientific progress that engaged the...

2010-01-01T23:59:59.000Z

406

ENGINEERING SCALE UP OF RENEWABLE HYDROGEN PRODUCTION BY CATALYTIC STEAM REFORMING OF PEANUT  

E-Print Network (OSTI)

ENGINEERING SCALE UP OF RENEWABLE HYDROGEN PRODUCTION BY CATALYTIC STEAM REFORMING OF PEANUT SHELLS, and academic organizations is developing a steam reforming process to be demonstrated on the gaseous byproducts of this engineering demonstration project. After an initial problem with the heaters that required modification

407

Do R&D and IT tax credits work? Evaluation of the Japanese tax reform  

Science Journals Connector (OSTI)

Our intention is to verify whether or not the tax reform plan can demonstrate benefits of which an impact can be felt in macroeconomic terms. We identify the significant effects of the tax reform plan and the difference in effects between R&D tax credit and IT investment tax credit.

Ichiro Sakata; Kenzo Fujisue; Hirokazu Okumura

2005-01-01T23:59:59.000Z

408

HealtH reform and oHsu how we'll change  

E-Print Network (OSTI)

HealtH reform and oHsu how we'll change Health reform will touch all of oHsu's missions. the coming changes are about more than public policy and health insurance. We will see transformation in how care is delivered, how health professionals are trained and how we decide what health care to buy. oHsu's missions

Chapman, Michael S.

409

Electricity Markets: Should the Rest of the World Adopt the UK Reforms?  

E-Print Network (OSTI)

PWP-069 Electricity Markets: Should the Rest of the World Adopt the UK Reforms? Catherine D;1 Electricity Markets: Should the Rest of the World Adopt the UK Reforms?1 By Catherine D. Wolfram2 Britain was one of the first countries to liberalize its electricity industry when it restructured and privatized

California at Berkeley. University of

410

Electrochemical Removal of Carbon Monoxide in Reformate Hydrogen for Fueling Proton Exchange Membrane  

E-Print Network (OSTI)

Electrochemical Removal of Carbon Monoxide in Reformate Hydrogen for Fueling Proton Exchange Membrane Fuel Cells Sivagaminathan Balasubramanian, Charles E. Holland,* and John W. Weidner*,z Center in reformate hydrogen. In this design, the potential and gas flow are switched between the two filter cells so

Weidner, John W.

411

PHS 650 Summer 2012 Page 1 State-Level Health System and Coverage Reform  

E-Print Network (OSTI)

and Affordable Care Act Current State-Level Trends and Health Reforms The Syllabus includes a variety of readingPHS 650 Summer 2012 Page 1 State-Level Health System and Coverage Reform Course Overview and Syllabus Description: Overview of the state initiatives in health care coverage, access, and costs, trends

Sheridan, Jennifer

412

Inaugural Lecture The Politics of Belief and U.S. Health Care Reform  

E-Print Network (OSTI)

1 Inaugural Lecture The Politics of Belief and U.S. Health Care Reform Joseph White Ph.D John G will not pretend to fully explain the politics of health care reform in the U.S.. I could make many other caveats is to give you some interesting ideas that you might use in thinking about American government. Health care

Oxford, University of

413

GOVERNMENT VERSUS GOVERNANCE AS A FRAMEWORK Government versus Governance as a Framework to analyze Mexico's Energy Reform  

E-Print Network (OSTI)

branch, the oil company PEMEX' union, other critics of the reform among a part of the left party Partido

Texas at Austin, University of

414

Radioactive Demonstrations Of Fluidized Bed Steam Reforming (FBSR) With Hanford Low Activity Wastes  

SciTech Connect

Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) are being evaluated. One immobilization technology being considered is Fluidized Bed Steam Reforming (FBSR) which offers a low temperature (700-750?C) continuous method by which wastes high in organics, nitrates, sulfates/sulfides, or other aqueous components may be processed into a crystalline ceramic (mineral) waste form. The granular waste form produced by co-processing the waste with kaolin clay has been shown to be as durable as LAW glass. The FBSR granular product will be monolithed into a final waste form. The granular component is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals such as sodalite. Production of the FBSR mineral product has been demonstrated both at the industrial, engineering, pilot, and laboratory scales on simulants. Radioactive testing at SRNL commenced in late 2010 to demonstrate the technology on radioactive LAW streams which is the focus of this study.

Jantzen, C. M.; Crawford, C. L.; Burket, P. R.; Bannochie, C. J.; Daniel, W. G.; Nash, C. A.; Cozzi, A. D.; Herman, C. C.

2012-10-22T23:59:59.000Z

415

Hydrogen Production for Fuel Cells Via Reforming Coal-Derived Methanol  

SciTech Connect

Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the third report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of April 1-June 30, 2004. This quarter saw progress in five areas. These areas are: (1) External evaluation of coal based methanol and the fuel cell grade baseline fuel, (2) Design, set up and initial testing of the autothermal reactor, (3) Experiments to determine the axial and radial thermal profiles of the steam reformers, (4) Catalyst degradation studies, and (5) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2004-06-30T23:59:59.000Z

416

HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL  

SciTech Connect

Hydrogen can be produced from many feed stocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the second report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1--March 31, 2004. This quarter saw progress in five areas. These areas are: (1) Internal and external evaluations of coal based methanol and the fuel cell grade baseline fuel; (2) Experimental investigations of heat and mass transfer enhancement methods by flow field manipulation; (3) Design and set up of the autothermal reactor; (4) Steam reformation of Coal Based Methanol; and (5) Initial catalyst degradation studies. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2004-04-01T23:59:59.000Z

417

Investigation of Multistage Circulating Fast Fluidized Bed Membrane Reformers for Production of Ultraclean Hydrogen and Syngas  

Science Journals Connector (OSTI)

Investigation of Multistage Circulating Fast Fluidized Bed Membrane Reformers for Production of Ultraclean Hydrogen and Syngas ... In order to distinguish between the two catalysts employed in this study, the catalyst over which the CSRM and CPOM reactions take place is considered catalyst 1 and that over which the CDRM reaction takes place is considered catalyst 2. The physical significance of catalyst 1 is that both reaction schemes of the CSRM and CPOM are catalyzed by this catalyst to produce hydrogen and syngas and to supply the necessary energy for the heat integration, though catalyst 2 plays an important role to steer the quality of the syngas and to enhance the hydrogen yield. ... In order to check the quality of the corresponding syngas produced in the reaction side, the hydrogen to carbon monoxide feed ratio (H2/CO) profile is presented in Figure 15. ...

Mohamed E. E. Abashar; Said S. E. H. Elnashaie

2014-03-05T23:59:59.000Z

418

Fiftieth CCR reformer goes on stream in Germany  

SciTech Connect

The fiftieth continuous catalytic reformer built since this technology was introduced by UOP Process Division in 1971 has gone on stream in West Germany. The 21,300-b/sd unit is in Deutsche Shell AG's Godorf refinery. It is the sixth such unit put in service by Shell International. Others are in refineries at Harburg, West Germany; Shellhaven, England; Palau Bokum, Singapore; Pernis, Netherlands; and Geelong, Australia. CCR units operate at much higher severity than older reforming units. Severity is a function of higher octane, lower pressure, and feedstock. The operating severity or catalyst deactivation rate may be 20 times that of high pressure, low octane units. Continuous catalyst regeneration is then the key for maintaining long-term operations at steady state conditions. To facilitate continuous catalyst regeneration, the three reactors are stacked. This design permits the catalyst to move in essentially plug flow through the reactors at a rate determined by the rate of catalyst withdrawal to the regeneration section.

Not Available

1985-03-18T23:59:59.000Z

419

Catalytic Reforming Downstream Processing of Fresh Feed Input  

U.S. Energy Information Administration (EIA) Indexed Site

Process: Catalytic Reforming Catalytic Cracking Catalytic Hydrocracking Delayed and Fluid Coking Period-Unit: Monthly-Thousand Barrels per Day Annual-Thousand Barrels per Day Process: Catalytic Reforming Catalytic Cracking Catalytic Hydrocracking Delayed and Fluid Coking Period-Unit: Monthly-Thousand Barrels per Day Annual-Thousand Barrels per Day Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Process Area Apr-13 May-13 Jun-13 Jul-13 Aug-13 Sep-13 View History U.S. 2,563 2,667 2,739 2,807 2,705 2,609 2010-2013 PADD 1 176 178 180 173 156 167 2010-2013 East Coast 166 164 163 161 140 153 2010-2013 Appalachian No. 1 9 14 16 12 15 14 2010-2013 PADD 2 642 638 668 695 677 615 2010-2013 Ind., Ill. and Ky. 426 411 426 460 450 399 2010-2013 Minn., Wis., N. Dak., S. Dak. 67 62 70 72 72 57 2010-2013 Okla., Kans., Mo.

420

Federal Onshore Oil and Gas Leasing Reform Act of 1987 (FOOGLRA) | Open  

Open Energy Info (EERE)

Page Page Edit with form History Facebook icon Twitter icon » Federal Onshore Oil and Gas Leasing Reform Act of 1987 (FOOGLRA) Jump to: navigation, search Statute Name Federal Onshore Oil and Gas Leasing Reform Act of 1987 (FOOGLRA) Year 1987 Url FederalOnshore1987.jpg Description Another amendment to the Mineral Leasing Act, The Federal Onshore Oil and Gas Leasing Reform Act of 1987 granted the USDA Forest Service the authority to make decisions and implement regulations concerning the leasing of public domain minerals on National Forest System lands containing oil and gas. References Federal Onshore Oil and Gas Leasing Reform Act of 1987 (FOOGLRA)[1] Federal Onshore Oil and Gas Leasing Reform Act of 1987 (FOOGLRA) (30 U.S.C. § 181 et seq.) - Another amendment to the Mineral Leasing Act, The Federal

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Update on IT Reform at the Department of Energy | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Update on IT Reform at the Department of Energy Update on IT Reform at the Department of Energy Update on IT Reform at the Department of Energy June 4, 2012 - 2:14pm Addthis The last 18 months have seen great improvements in the Department of Energy's (DOE) information technology and cybersecurity. A major factor in our success is our alignment with the 25 Point Implementation Plan To Reform Federal Information Technology Management to move to a "Cloud First" environment and maximize the use of shared services to reduce costs and improve IT delivery. Cloud-First/Shared Services: In August 2011, we revamped our online presence by launching Energy.gov and delivering a single platform solution through an open-source content management system and cloud hosting environment. Ultimately, the website reform effort aims to save taxpayers more than $10 million per

422

The Lessons of Practice: Domestic Policy Reform as a Way to Address Climate  

Open Energy Info (EERE)

The Lessons of Practice: Domestic Policy Reform as a Way to Address Climate The Lessons of Practice: Domestic Policy Reform as a Way to Address Climate Change Jump to: navigation, search Tool Summary LAUNCH TOOL Name: The Lessons of Practice: Domestic Policy Reform as a Way to Address Climate Change Agency/Company /Organization: International Institute for Sustainable Development (IISD) Topics: Policies/deployment programs Resource Type: Lessons learned/best practices Website: www.iisd.org/pdf/2009/bali_2_copenhagen_dom_policy_lessons.pdf The Lessons of Practice: Domestic Policy Reform as a Way to Address Climate Change Screenshot References: The Lessons of Practice[1] Summary "The objectives of this paper are threefold: to review experience to date with policy reforms that can help mitigate climate change, to review work

423

Hydrogen production in Multi-Channel Membrane Reactor via Steam Methane Reforming and Methane Catalytic Combustion  

Science Journals Connector (OSTI)

Abstract A novel Multi-Channel Membrane Reactor (MCMR) was designed and built for the small-scale production of hydrogen via Steam Methane Reforming (SMR). The prototype alternates an SMR gas channel to produce hydrogen catalytically, with a Methane Catalytic Combustion (MCC) gas channel to provide the heat of reaction needed by the endothermic reforming. A palladium–silver membrane inside the reforming gas channel shifts the reaction equilibrium, allowing lower operating temperatures, and producing pure hydrogen in a single vessel. Using an innovative air-spray coating technique, channels were coated with Ru–MgO–La2O3/?-Al2O3 and Pd/?-Al2O3 catalyst particles for the SMR and MCC reactions, respectively. Results for the proof-of-concept MCMR showed that methane conversion in the reformer of 91% and a hydrogen purity in excess of 99.99% were possible with the reformer operating at 570 °C and 15 bar.

Alexandre Vigneault; John R. Grace

2014-01-01T23:59:59.000Z

424

Forging growth by governing the market in reform-era urban China  

Science Journals Connector (OSTI)

Abstract China’s accelerating urban growth over the past decade has been examined from the perspectives of state devolution or place-making initiatives. Relatively little has been written to contextualize the burgeoning urbanism in China’s reform and the resultant changing relationship between state and market. Through an investigation of fiscal and land use reforms since the mid-1990s, this paper argues that China’s gradual and partial reform has fundamentally re-engineered local states from inward-looking market actors running business to entrepreneurial market governors controlling land supply. Though this transition has triggered urban growth by levering manufacturing and real estate capital, it has also introduced constraints for future urban development by generating inter-regional tensions and making further reforms politically difficult. This paper concludes that sustainable urbanism requires a more clearly oriented and more holistic reform framework.

Lei Wang

2014-01-01T23:59:59.000Z

425

Fluidized Bed Steam Reforming of INEEL SBW Using THORsm Mineralizing Technology  

SciTech Connect

Sodium bearing waste (SBW) disposition is one of the U.S. Department of Energy (DOE) Idaho Operation Office’s (NE-ID) and State of Idaho’s top priorities at the Idaho National Engineering and Environmental Laboratory (INEEL). Many studies have resulted in the identification of five treatment alternatives that form a short list of perhaps the most appropriate technologies for the DOE to select from. The alternatives are (a) calcination with maximum achievable control technology (MACT) upgrade, (b) steam reforming, (c) cesium ion exchange (CsIX) with immobilization, (d) direct evaporation, and (e) vitrification. Each alternative has undergone some degree of applied technical development and preliminary process design over the past four years. DOE desired further experimental data, with regard to steam reforming technology, to make informed decisions concerning selection of treatment technology for SBW. Mineralizing steam reforming technology, offered by THOR Treatment Technologies, LLC would produce a denitrated, granular mineral waste form using a high-temperature fluidized bed process. A pilot scale demonstration of the technology was performed in a 15-cm-diameter reactor vessel September 27 through October 1, 2004. The pilot scale equipment is owned by the DOE, and located at the Science and Technology Applications Research (STAR) Center in Idaho Falls, ID. Flowsheet chemistry and operational parameters were defined through a collaborative effort involving Idaho National Engineering and Environmental Laboratory, Savannah River National Laboratory (SRNL), and THOR Treatment Technologies personnel. Personnel from Science Applications International Corporation, owners of the STAR Center, operated the pilot plant. The pilot scale test was terminated as planned after achieving a total of 100 hrs of cumulative/continuous processing operation. About 230 kg of SBW surrogate were processed that resulted in about 88 kg of solid product, a mass reduction of about 62%. The process achieved about a 90% turnover of the starting bed. Samples of mineralized solid product materials were analyzed for chemical/physical properties. Results of product performance testing conducted by SRNL will be reported separately by SRNL.

Arlin L. Olson; Nicholas R. Soelberg; Douglas W. Marshall; Gary L. Anderson

2004-12-01T23:59:59.000Z

426

Exhaust gas fuel reforming of Diesel fuel by non-thermal arc discharge for NOx trap regeneration  

E-Print Network (OSTI)

1 Exhaust gas fuel reforming of Diesel fuel by non- thermal arc discharge for NOx trap regeneration to the reforming of Diesel fuel with Diesel engine exhaust gas using a non-thermal plasma torch for NOx trap Diesel fuel reforming with hal-00617141,version1-17May2013 Author manuscript, published in "Energy

Boyer, Edmond

427

Comedy, Science, and the Reform of Description in Lombard Painting of the Late Renaissance: Arcimboldo, Vincenzo Campi, and Bartolomeo Passerotti  

E-Print Network (OSTI)

Comedy, Science, and the Reform of Description in Lombard Painting of the Late Renaissance, and the Reform of Description in Lombard Painting of the Late Renaissance: Arcimboldo, Vincenzo Campi, as part of an aesthetic "reform" of description and its critical reputation. Considering that all three

Salzman, Daniel

428

Fairness lost in immigration reform; Never before have sweeping changes to policies been undertaken with so little public debate or  

E-Print Network (OSTI)

Fairness lost in immigration reform; Never before have sweeping changes to policies been undertaken reform is unique neither in terms of its controversial substance nor in its lack of meaningful democratic processes. In the past, major immigration reform has typically been the result of parliamentary deliberation

Handy, Todd C.

429

Assessment of CO2 capture options from various points in steam methane reforming for hydrogen production  

Science Journals Connector (OSTI)

Abstract Steam methane reforming (SMR) is currently the main hydrogen production process in industry, but it has high emissions of CO2, at almost 7 kg CO2/kg H2 on average, and is responsible for about 3% of global industrial sector CO2 emissions. Here, the results are reported of an investigation of the effect of steam-to-carbon ratio (S/C) on CO2 capture criteria from various locations in the process, i.e. synthesis gas stream (location 1), pressure swing adsorber (PSA) tail gas (location 2), and furnace flue gases (location 3). The CO2 capture criteria considered in this study are CO2 partial pressure, CO2 concentration, and CO2 mass ratio compared to the final exhaust stream, which is furnace flue gases. The CO2 capture number (Ncc) is proposed as measure of capture favourability, defined as the product of the three above capture criteria. A weighting of unity is used for each criterion. The best S/C ratio, in terms of providing better capture option, is determined. CO2 removal from synthesis gas after the shift unit is found to be the best location for CO2 capture due to its high partial pressure of CO2. However, furnace flue gases, containing almost 50% of the CO2 in produced in the process, are of great significance environmentally. Consequently, the effects of oxygen enrichment of the furnace feed are investigated, and it is found that this measure improves the CO2 capture conditions for lower S/C ratios. Consequently, for an S/C ratio of 2.5, CO2 capture from a flue gas stream is competitive with two other locations provided higher weighting factors are considered for the full presence of CO2 in the flue gases stream. Considering carbon removal from flue gases, the ratio of hydrogen production rate and Ncc increases with rising reformer temperature.

R. Soltani; M.A. Rosen; I. Dincer

2014-01-01T23:59:59.000Z

430

Dually-Eligible Working-Age Adults with Disabilities: Issues and Challenges as Health Reform is Implemented  

E-Print Network (OSTI)

employment impact of health reform on working-age adults with disabilities. J Disabil Pol Studies, 2012 Online First Available from http://dps.sagepub.com/content/early/2012/05/23/1011771044207312446225; 2012. iv Hall J, Kurth N, Hunt S. Employment as a... Acknowledgements The content of this article is based on information presented at the AcademyHealth Disability Research Interest Group (DRIG) meeting held in Orlando, FL, June 23, 2012, with funding from The Commonwealth Fund. The author would like to thank...

Hall, Jean P.

2013-01-01T23:59:59.000Z

431

Mill Integration-Pulping, Stream Reforming and Direct Causticization for Black Liquor Recovery  

SciTech Connect

MTCI/StoneChem developed a steam reforming, fluidized bed gasification technology for biomass. DOE supported the demonstration of this technology for gasification of spent wood pulping liquor (or 'black liquor') at Georgia-Pacific's Big Island, Virginia mill. The present pre-commercial R&D project addressed the opportunities as well as identified negative aspects when the MTCI/StoneChem gasification technology is integrated in a pulp mill production facility. The opportunities arise because black liquor gasification produces sulfur (as H{sub 2}S) and sodium (as Na{sub 2}CO{sub 3}) in separate streams which may be used beneficially for improved pulp yield and properties. The negative aspect of kraft black liquor gasification is that the amount of Na{sub 2}CO{sub 3} which must be converted to NaOH (the so called causticizing requirement) is increased. This arises because sulfur is released as Na{sub 2}S during conventional kraft black liquor recovery, while during gasification the sodium associated Na{sub 2}S is partly or fully converted to Na{sub 2}CO{sub 3}. The causticizing requirement can be eliminated by including a TiO{sub 2} based cyclic process called direct causticization. In this process black liquor is gasified in the presence of (low sodium content) titanates which convert Na{sub 2}CO{sub 3} to (high sodium content) titanates. NaOH is formed when contacting the latter titanates with water, thereby eliminating the causticizing requirement entirely. The leached and low sodium titanates are returned to the gasification process. The project team comprised the University of Maine (UM), North Carolina State University (NCSU) and MTCI/ThermoChem. NCSU and MTCI are subcontractors to UM. The principal organization for the contract is UM. NCSU investigated the techno-economics of using advanced pulping techniques which fully utilize the unique cooking liquors produced by steam reforming of black liquor (Task 1). UM studied the kinetics and agglomeration problems of the conversion of Na{sub 2}CO{sub 3} to (high sodium) titanates during gasification of black liquor in the presence of (low sodium) titanates or TiO{sub 2} (Task 2). MTCI/ThermoChem tested the performance and operability of the combined technology of steam reforming and direct causticization in their Process Development Unit (PDU) (Task 3). The specific objectives were: (1) to investigate how split sulfidity and polysulfide (+ AQ) pulping can be used to increase pulp fiber yield and properties compared to conventional kraft pulping; (2) to determine the economics of black liquor gasification combined with these pulping technologies in comparison with conventional kraft pulping and black liquor recovery; (3) to determine the effect of operating conditions on the kinetics of the titanate-based direct causticization reaction during black liquor gasification at relatively low temperatures ({le} 750 C); (4) to determine the mechanism of particle agglomeration during gasification of black liquor in the presence of titanates at relatively low temperatures ({le} 750 C); and (5) to verify performance and operability of the combined technology of steam reforming and direct causticization of black liquor in a pilot scale fluidized bed test facility.

Adriaan van Heiningen

2007-06-30T23:59:59.000Z

432

Reforming of Liquid Hydrocarbons in a Novel Hydrogen-Selective Membrane-Based Fuel Processor  

SciTech Connect

In this work, asymmetric dense Pd/porous stainless steel composite membranes were fabricated by depositing palladium on the outer surface of the tubular support. The electroless plating method combined with an osmotic pressure field was used to deposit the palladium film. Surface morphology and microstructure of the composite membranes were characterized by SEM and EDX. The SEM and EDX analyses revealed strong adhesion of the plated pure palladium film on the substrate and dense coalescence of the Pd film. Membranes were further characterized by conducting permeability experiments with pure hydrogen, nitrogen, and helium gases at temperatures from 325 to 450 C and transmembrane pressure differences from 5 to 45 psi. The permeation results showed that the fabricated membranes have both high hydrogen permeability and selectivity. For example, the hydrogen permeability for a composite membrane with a 20 {micro}m Pd film was 3.02 x 10{sup -5} moles/m{sup 2}.s.Pa{sup 0.765} at 450 C. Hydrogen/nitrogen selectivity for this composite membrane was 1000 at 450 C with a transmembrane pressure difference of 14.7 psi. Steam reforming of methane is one of the most important chemical processes in hydrogen and syngas production. To investigate the usefulness of palladium-based composite membranes in membrane-reactor configuration for simultaneous production and separation of hydrogen, steam reforming of methane by equilibrium shift was studied. The steam reforming of methane using a packed-bed inert membrane tubular reactor (PBIMTR) was simulated. A two-dimensional pseudo-homogeneous reactor model with parallel flow configuration was developed for steam reforming of methane. The shell volume was taken as the feed and sweep gas was fed to the inside of the membrane tube. Radial diffusion was taken into account for concentration gradient in the radial direction due to hydrogen permeation through the membrane. With appropriate reaction rate expressions, a set of partial differential equations was derived using the continuity equation for the reaction system and then solved by finite difference method with appropriate boundary and initial conditions. An iterative scheme was used to obtain a converged solution. Membrane reactor performance was compared to that in a traditional non-membrane packed-bed reactor (PBR). Their performances were also compared with thermodynamic equilibrium values achievable in a conventional non-membrane reactor. Numerical results of the models show that the methane conversions in the PBIMTR are always higher than that in the PBR, as well as thermodynamic equilibrium conversions. For instance, at a reaction pressure of 6 atm, a temperature of 650 C, a space velocity of 900/16.0 SCCM/gm{sub cat}, a steam to methane molar feed ratio of 3.0, a sweep ratio of 0.15, the conversion in the membrane reactor is about 86.5%, while the conversion in the non-membrane reactor is about 50.8%. The corresponding equilibrium conversion is about 56.4%. The effects on the degree of conversion and hydrogen yield were analyzed for different parameters such as temperature, reactor pressure, feed and sweep flow rate, feed molar ratio, and space time. From the analysis of the model results, it is obvious that the membrane reactor operation can be optimized for conversion or yield through the choice of proper operating and design parameters. Comparisons with available literature data for both membrane and non-membrane reactors showed a good agreement.

Shamsuddin Ilias

2006-03-10T23:59:59.000Z

433

Vehicle type choice under the influence of a tax reform and rising fuel prices  

Science Journals Connector (OSTI)

Abstract Differentiated vehicle taxes are considered by many a useful tool for promoting environmentally friendly vehicles. Various structures have been implemented in several countries, e.g. Ireland, France, The Czech Republic, and Denmark. In many countries the tax reforms have been followed by a steep change in new vehicle purchases toward more diesel vehicles and more fuel-efficient vehicles. The paper analyses to what extent a vehicle tax reform similar to the Danish 2007 reform may explain changes in purchasing behaviour. The paper investigates the effects of a tax reform, fuel price changes, and technological development on vehicle type choice using a mixed logit model. The model allows a simulation of the effect of car price changes that resemble those induced by the tax reform. This effect is compared to the effects of fuel price changes and technology improvements. The simulations show that the effect of the tax reform on fuel efficiency is similar to the effect of rising fuel prices while the effect of technological development is much larger. The conclusion is that while the tax reform appeared in the same year as a large increase in fuel efficiency, it seems likely that it only explains a small part of the shift in fuel efficiency that occurred and that the main driver was the technological development.

Stefan L. Mabit

2014-01-01T23:59:59.000Z

434

NiW and NiRu Bimetallic Catalysts for Ethylene Steam Reforming: Alternative Mechanisms for Sulfur Resistance  

SciTech Connect

Previous investigations of Ni-based catalysts for the steam reforming of hydrocarbons have indicated that the addition of a second metal can reduce the effects of sulfur poisoning. Two systems that have previously shown promise for such applications, NiW and NiRu, are considered here for the steam reforming of ethylene, a key component of biomass derived tars. Monometallic and bimetallic Al{sub 2}O{sub 3}-supported Ni and W catalysts were employed for ethylene steam reforming in the presence and absence of sulfur. The NiW catalysts were less active than Ni in the absence of sulfur, but were more active in the presence of 50 ppm H{sub 2}S. The mechanism for the W-induced improvements in sulfur resistance appears to be different from that for Ru in NiRu. To probe reasons for the sulfur resistance of NiRu, the adsorption of S and C{sub 2}H{sub 4} on several bimetallic NiRu alloy surfaces ranging from 11 to 33 % Ru was studied using density functional theory (DFT). The DFT studies reveal that sulfur adsorption is generally favored on hollow sites containing Ru. Ethylene preferentially adsorbs atop the Ru atom in all the NiRu (111) alloys investigated. By comparing trends across the various bimetallic models considered, sulfur adsorption was observed to be correlated with the density of occupied states near the Fermi level while C{sub 2}H{sub 4} adsorption was correlated with the number of unoccupied states in the d-band. The diverging mechanisms for S and C{sub 2}H{sub 4} adsorption allow for bimetallic surfaces such as NiRu that enhance ethylene binding without accompanying increases in sulfur binding energy. In contrast, bimetallics such as NiSn and NiW appear to decrease the affinity of the surface for both the reagent and the poison.

Rangan, M.; Yung, M. M.; Medlin, J. W.

2012-06-01T23:59:59.000Z

435

In silico search for novel methane steam reforming catalysts  

Science Journals Connector (OSTI)

This paper demonstrates a method for screening transition metal and metal alloy catalysts based on their predicted rates and stabilities for a given catalytic reaction. This method involves combining reaction and activation energies (available to the public via a web-based application 'CatApp') with a microkinetic modeling technique to predict the rates and selectivities of a prospective material. This paper illustrates this screening technique using the steam reforming of methane to carbon monoxide and hydrogen as a test reaction. While catalysts are already commercially available for this process, the method demonstrated in this paper is very general and could be applied to a wide range of catalytic reactions. Following the steps outlined herein, such an analysis could potentially enable researchers to understand reaction mechanisms on a fundamental level and, on this basis, develop leads for new metal alloy catalysts.

Yue Xu; Adam C Lausche; Shengguang Wang; Tuhin S Khan; Frank Abild-Pedersen; Felix Studt; Jens K Nørskov; Thomas Bligaard

2013-01-01T23:59:59.000Z

436

Online quality control methods for steam-gas reformers  

Science Journals Connector (OSTI)

This paper presents a classification of online quality control (QC) methods from the view of process control. The QC can be applied on the control loops from each of its three sides: the input (manipulative variable) side, the output (controlled variable) side and from the disturbance side. It was found that online QC can be direct or indirect, depending on the measures taken for quality. This classification can lead to interesting and new options for the control variables that otherwise would have been obscure. Once the proper control variable is selected (in terms of adequate representation of quality) it can be used for control systems analysis and design. Process application is presented for an industrial Steam Gas Reformer. The input is the fuel gas quality for which various options were presented. A correlation was obtained to relate heat input to simple measurements. The output hydrogen quality control options were discussed. Coil outlet temperature is adequate for a crude estimate of conversion, provided that S/C ratio is controlled. S/C ratio correlation was obtained to enable its estimation and control from simple measurements. A precise quality control of hydrogen can be achieved provided that COT is also controlled to protect reformer catalyst. An improved strategy can be implemented where both COT and conversion are controlled in a multivariable sense. This strategy is economically attractive, since it allows continuous manipulation of S/C ratio to the minimum required for COT control. Savings in fuel gas can be achieved accordingly. The feasibility of multivariable control was established via interaction analysis.

I.M. Alatiqi

1990-01-01T23:59:59.000Z

437

Efficient Utilization of Greenhouse Gases in a Gas-to-Liquids Process Combined with CO2/Steam-Mixed Reforming and Fe-Based Fischer–Tropsch Synthesis  

Science Journals Connector (OSTI)

In the reforming unit, CO2 reforming and steam reforming of methane are combined together to produce syngas in flexible composition. ... In the burner-type reformer, NG is used as a heating fuel, in order to reduce the consumption of NG, the vent gas can be applied to the burner to replace some part of NG as fuel. ...

Chundong Zhang; Ki-Won Jun; Kyoung-Su Ha; Yun-Jo Lee; Seok Chang Kang

2014-06-16T23:59:59.000Z

438

Investigation of Bio-Ethanol Steam Reforming over Cobalt-based Catalysts (Presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE Bio-Derived Liquids to Hydrogen Distributed DOE Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Meeting Investigation of Bio-Ethanol Steam Reforming over Cobalt-based Catalysts Hua Song Lingzhi Zhang Umit S. Ozkan* November 6 th , 2007 Heterogeneous Catalysis Research Group Department of Chemical and Biomolecular Engineering The Ohio State University Columbus, OH 43210 *Ozkan.1@osu.edu Biomass to Hydrogen (Environmentally Friendly) Plant cultivation Plant cultivation Saccharification Saccharification / / Fermentation Fermentation Anaerobic digestion Anaerobic digestion Residues of Residues of agroindustries agroindustries and cultivations and cultivations Municipal Solid Waste Municipal Solid Waste (organic fraction) (organic fraction) Distillation Distillation Reformation of ethanol

439

,"Catalytic Reforming Downstream Processing of Fresh Feed Input"  

U.S. Energy Information Administration (EIA) Indexed Site

Catalytic Reforming Downstream Processing of Fresh Feed Input" Catalytic Reforming Downstream Processing of Fresh Feed Input" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Catalytic Reforming Downstream Processing of Fresh Feed Input",16,"Monthly","9/2013","1/15/2010" ,"Release Date:","11/27/2013" ,"Next Release Date:","Last Week of December 2013" ,"Excel File Name:","pet_pnp_dwns_a_(na)_ydr_mbblpd_m.xls" ,"Available from Web Page:","http://www.eia.gov/dnav/pet/pet_pnp_dwns_a_(na)_ydr_mbblpd_m.htm" ,"Source:","Energy Information Administration"

440

Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Kick-Off Meeting  

Energy.gov (U.S. Department of Energy (DOE))

The U.S. Department of Energy held a kick-off meeting for the Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) on October 24, 2006, in Baltimore, Maryland. The Working Group is addressing technical challenges to distributed reforming of biomass-derived, renewable liquid fuels to hydrogen, including the reforming, water-gas shift, and hydrogen recovery and purification steps. The meeting provided the opportunity for researchers to share their experiences in converting bio-derived liquids to hydrogen with each other and with members of the DOE Hydrogen Production Technical Team.

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
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441

How fuel composition affects on-board reforming for fuel cell vehicles.  

SciTech Connect

Different blends of gasoline range hydrocarbons were investigated to determine the effect of aromatic, naphthenic, and paraffinic content on performance in an autothermal reformer. In addition, we investigated the effects of detergent, antioxidant, and oxygenate additives. These tests indicate that composition effects are minimal at temperatures of 800C and above, but at lower temperatures or at high gas hourly space velocities (GHSV approaching 100,000 h{sup -1} ) composition can have a large effect on catalyst performance. Fuels high in aromatic and naphthenic components were more difficult to reform. In addition, additives, such as detergents and oxygenates were shown to decrease reformer performance at lower temperatures.

Kopasz, J. P.; Miller, L. E.; Applegate, D. V.; Chemical Engineering

2003-01-01T23:59:59.000Z

442

Fiscal consolidation in the euro area: How much pain can structural reforms ease?  

Science Journals Connector (OSTI)

Abstract The IMF's Global Integrated Monetary and Fiscal model (GIMF) is used to examine the scope for structural reforms in the euro area to offset the negative impact of fiscal consolidation required to put public debt back on a sustainable path. The results suggest that structural reforms in core countries could be expected to offset the near-term negative impact on activity arising from the required fiscal consolidation. However, for the periphery, the results suggest that it would take several years before structural reforms could return the level of output back to its pre-consolidation path.

Derek Anderson; Benjamin Hunt; Stephen Snudden

2014-01-01T23:59:59.000Z

443

Tar Reforming in Model Gasifier Effluents: Transition Metal/Rare Earth Oxide Catalysts  

Science Journals Connector (OSTI)

Tar Reforming in Model Gasifier Effluents: Transition Metal/Rare Earth Oxide Catalysts ... So in this work we investigated the action of transition metal oxides (TMOs) other than Ni (e.g., Fe, Mn) mixed with REOs for tar reforming, at a medium temperature range (923–1073 K) and under conditions where direct reforming would dominate. ... The heated gas mixture passed through a 1/2” stainless steel tube containing 0.2–1 g of catalyst (40–60 mesh size) diluted with mullite and positioned between beds of ?-Al2O3. ...

Rui Li; Amitava Roy; Joseph Bridges; Kerry M. Dooley

2014-04-24T23:59:59.000Z

444

FDI in retail sector India: structural reform more than a political reform  

Science Journals Connector (OSTI)

In our brief study, we try to address one of these market inefficiencies, by studying the Indian retail sector, which has posed as a structural defect causing a political battle rather than an economic one. We take a historical outlook to the contribution of retail and wholesale sector in our economy with respect to other sectors, before and after FDI was introduced. To prove this defect, we concentrate on two aspects of the retail sector. We discuss the present procurement and distribution system in the basic agricultural commodities which is majorly handled by the government agencies. We also brush along the outdated legislation which regulates the whole market and is the underlying cause of un-competitiveness in the sector. We analyse the views of skeptics and try to reason out some biases within their work. We conclude with recommendations that free market is better than a nationalised one.

Ankit Arora

2014-01-01T23:59:59.000Z

445

An Act to Reform Land Use Planning in the Unorganized Territory (Maine) |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

An Act to Reform Land Use Planning in the Unorganized Territory An Act to Reform Land Use Planning in the Unorganized Territory (Maine) An Act to Reform Land Use Planning in the Unorganized Territory (Maine) < Back Eligibility Agricultural Commercial Investor-Owned Utility Local Government Municipal/Public Utility Nonprofit Rural Electric Cooperative Schools Tribal Government Utility Savings Category Wind Buying & Making Electricity Program Info State Maine Program Type Siting and Permitting Provider Conservation An Act to Reform Land Use Planning in the Unorganized Territory alters the makeup and responsibilities of Maine's Land Use Regulation Commission (LURC). It took effect on August 29, 2012 and changed the Commission's name to the Land Use Planning Commission. Under the Act, permitting review for significant projects, such as

446

Numerical simulation of micro/mini-channel based methane-steam reformer.  

E-Print Network (OSTI)

??Numerical modeling of methane-steam reforming is performed in a micro/mini-channel with heat input through catalytic channel walls. The low-Mach number, variable density Navier-Stokes equations together… (more)

Peterson, Daniel Alan

2010-01-01T23:59:59.000Z

447

Hydrogen production through CO2 sorption-enhanced methane steam reforming: Comparison between different adsorbents  

Science Journals Connector (OSTI)

A two-dimensional transient model has been developed to describe the catalytic methane reforming (MSR) coupled with simultaneous CO2...removal by different absorbents under non-isothermal, non-isobaric and non-ad...

YuMing Chen; YongChun Zhao; JunYing Zhang…

2011-11-01T23:59:59.000Z

448

Steam Reforming of Methane Over Nickel: Development of a Multi-Step Surface Reaction Mechanism  

Science Journals Connector (OSTI)

A detailed multi-step reaction mechanism is developed for modeling steam reforming of methane over nickel-based catalysts. The mechanism also ... tested by simulating experimental investigations of SR of methane ...

L. Maier; B. Schädel; K. Herrera Delgado; S. Tischer; O. Deutschmann

2011-09-01T23:59:59.000Z

449

Thermally Coupled Catalytic Reactor for Steam Reforming of Methane and Liquid Hydrocarbons: Experiment and Mathematical Modeling  

Science Journals Connector (OSTI)

An energy-efficient catalytic reactor for producing synthesis gas from methane and liquid hydrocarbons is proposed that is ... on the coupling of an endothermic reaction (steam reforming of methane, hexane, or is...

V. A. Kirillov; N. A. Kuzin; A. V. Kulikov…

2003-05-01T23:59:59.000Z

450

Outcomes of a Freedom of Choice Reform in Community Mental Health Day Center Services  

Science Journals Connector (OSTI)

Organizational reforms often take place in social and health care services, and in the western world free ... been implemented in various welfare sectors such as health care, disability services, work rehabilitat...

Mona Eklund; Urban Markström

2014-10-01T23:59:59.000Z

451

Reform of Public Hospitals and the Main Role of Medical Staffs  

Science Journals Connector (OSTI)

The success of reforms to the public hospital system in China ... factors are known to influence the motivation of health workers, including remuneration, acquisition of power and reputation, the ability to care ...

Peiying Zhang

2014-11-01T23:59:59.000Z

452

Research and Development of a PEM Fuel Cell, Hydrogen Reformer, and Vehicle Refueling Facility  

Energy.gov (U.S. Department of Energy (DOE))

Technical paper on the development of a hydrogen reformer, vehicle refueling facility, and PEM fuel cell for Las Vegas, NV presented at the 2002 Annual Hydrogen Review held May 6-8, 2002 in Golden, CO.

453

Chemical Looping Autothermal Reforming at a 120 kW Pilot Rig  

Science Journals Connector (OSTI)

Chemical looping with selective oxygen transport allows two step combustion or autothermal reforming without mixing of fuel...4...conversion is achieved. Air/fuel ratio is varied at three different fuel reactor t...

Johannes Bofhàr-Nordenkampf; Tobias Pröll…

2010-01-01T23:59:59.000Z

454

Biosyngas Production in an Integrated Aqueous-Phase Glycerol Reforming/Chemical Looping Combustion Process  

Science Journals Connector (OSTI)

Biosyngas Production in an Integrated Aqueous-Phase Glycerol Reforming/Chemical Looping Combustion Process ... Industrial & Engineering Chemistry Research (2010), 49 (21), 10826-10835 CODEN: IECRED; ISSN:0888-5885. ...

Ion Iliuta; Maria C. Iliuta

2013-10-18T23:59:59.000Z

455

The risk of reform : privatisation and liberalisation in the Brazilian electric power industry  

E-Print Network (OSTI)

In 1996, when Brazil was well-underway to privatising and liberalising its electric power industry, few would have predicted that within five years the reforms would be a shambles. Like its neighbors Argentina and Chile, ...

Tankha, Sunil, Ph. D. Massachusetts Institute of Technology

2006-01-01T23:59:59.000Z

456

Computational heterogeneous catalysis applied to steam methane reforming over nickel and nickel/silver catalysts  

E-Print Network (OSTI)

The steam methane reforming (SMR) reaction is the primary industrial means for producing hydrogen gas. As such, it is a critical support process for applications including petrochemical processing and ammonia synthesis. ...

Blaylock, Donnie Wayne

2011-01-01T23:59:59.000Z

457

Ethanol and E85 Reforming Assisted by a Non-thermal Arc Discharge  

Science Journals Connector (OSTI)

Ethanol and E85 Reforming Assisted by a Non-thermal Arc Discharge ... The input electric power is expressed in terms of the percentage of Qfuel·LHVfuel, and is noted as %LHV. ... for electricity prodn. ...

Guillaume Petitpas; José Gonzalez-Aguilar; Adeline Darmon; Laurent Fulcheri

2010-03-25T23:59:59.000Z

458

American Institute of Aeronautics and Astronautics Measurements for fuel reforming for scramjet thermal management and  

E-Print Network (OSTI)

American Institute of Aeronautics and Astronautics 1 Measurements for fuel reforming for scramjet, since even composite materials can't withstand the large heat load found in a Scramjet combustion

Paris-Sud XI, Université de

459

Demonstration of a high-efficiency steam reformer for fuel cell power plant applications  

SciTech Connect

Full-scale tests of a new modular steam reformer confirm its suitability for a wide range of fuel cell power plant applications. This new fuel processor offers interested utilities excellent performance, operating flexibility, reliability, and maintainability.

Udengaard, N.R.; Christiansen, L.J.; Summers, W.A.

1987-08-01T23:59:59.000Z

460

Steam-Methane Reformer Kinetic Computer Model with Heat Transfer and Geometry Options  

SciTech Connect

A kinetic computer model of a steam/methane reformer has been developed as a design and analytical tool for a fuel cell system's fuel conditioner. This model has reaction, geometry, flow arrangement, and heat transfer options. Model predictions have been compared to previous experimental data, and close agreement was obtained. Initially, the Leva-type, packed-bed, heat transfer correlations were used. However, calculations based upon the reacting, reformer gases indicate a considerably higher heat transfer coefficient for this reforme design. Data analysis from similar designs in the literature also shows this phenomenon. This is thought to be reaction-induced effect, brought about by the changing of gas composition, the increased gas velocity, the lower catalyst temperature during reaction, and the higher thermal and reaction gradients involved in compact fuel cell reformer designs. Future experimental work is planned to verify the model's predictions further.

Murray, A.P.; Snyder, T.S.

1985-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

The Working Families’ Tax Credit and Some European Tax Reforms in A Collective Setting  

Science Journals Connector (OSTI)

A framework for simplified implementation of the collective model of labor supply decisions is presented in the context of fiscal reforms in the UK. Through its collective form the model accounts for the well kno...

Michal Myck; Olivier Bargain; Miriam Beblo…

2006-06-01T23:59:59.000Z

462

Healthcare reform in the United States and China: pharmaceutical market implications  

E-Print Network (OSTI)

. This article analyzes the implications of health system reforms in the United States and China for national pharmaceutical markets. It follows a historical institutionalist approach that identifies path dependency in the design and operation of national health...

Daemmrich, Arthur; Mohanty, Ansuman

2014-07-14T23:59:59.000Z

463

The Resurgence of Land Reform Policy and Agrarian Movements in Indonesia  

E-Print Network (OSTI)

157 He invoked Amartya Sen’s notion of development asby access reform à la Amartya Sen” 166 (Winoto 2006:81, bolddengan reformasi akses ala Amartya Sen. to mention the NARP

Rachman, Noer Fauzi

2011-01-01T23:59:59.000Z

464

The Forgotten Children: African American Children and Child Welfare Reform in St. Louis, 1890-1930  

E-Print Network (OSTI)

Abstract Forgotten Children examines the influence of racial ideology on the trajectory of child welfare reform in late nineteenth century and early twentieth century St. Louis. The modern American child welfare system emerged in this time period...

Thirlkel, Thomas E.

2010-05-07T23:59:59.000Z

465

The rules of ruling : charter reform in Los Angeles, 1850-2008  

E-Print Network (OSTI)

and officers face the charter as a constant constraint. If centralized purchasingand Purchasing Agent. The Mayor would appoint these officerspurchasing, campaign finance reform, strengthen the recall to cover appointed officials and create staggered elections for officers.

Ingram, James Warren

2008-01-01T23:59:59.000Z

466

Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Background Paper  

Energy.gov (U.S. Department of Energy (DOE))

Paper by Arlene Anderson and Tracy Carole presented at the Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group, with a focus on key drivers, purpose, and scope.

467

Admonition and the academy : installation, video, and performance art in Reform Era China  

E-Print Network (OSTI)

China's Reform Era (1978-present) has seen the reinvigoration of academic, and artistic practice, and a rapprochement between the Chinese Communist Party and the intellectual elite. At its beginnings in the early- to ...

Oen, Karin Grace

2012-01-01T23:59:59.000Z

468

Life Cycle Assessment of Hydrogen Production via Natural Gas Steam Reforming  

Energy.gov (U.S. Department of Energy (DOE))

A life cycle assessment of hydrogen production via natural gas steam reforming was performed to examine the net emissions of greenhouse gases as well as other major environmental consequences.

469

Combined isomerization of overhead cuts of straight-run naphtha and reformate  

Science Journals Connector (OSTI)

Technology was developed for combined isomerization of IBP-85°C overhead cuts of straight-run naphtha and reformate to reduce the benzene content in automotive gasolines. In comparison to the traditional technolo...

Nguen Van Ty

2008-07-01T23:59:59.000Z

470

CENTER FOR LATIN AMERICAN STUDIES, UC BERKELEY 11Spring 2014  

E-Print Network (OSTI)

. The future is promising, the foreign press says. Mexico has crossed the threshold and approved reformsCENTER FOR LATIN AMERICAN STUDIES, UC BERKELEY 11Spring 2014 M exico waking up. Mexico moving, propose reforms, and approve them. A country that no longer wants to be hostage to archaic traditions

Kammen, Daniel M.

471

Three Stages Modeling of n-Octane Reforming Assisted by a Nonthermal Arc Discharge  

Science Journals Connector (OSTI)

Three Stages Modeling of n-Octane Reforming Assisted by a Nonthermal Arc Discharge ... After a description of the model and its main assumptions, a parametric analysis of plasma reformer performance addressing the influence of plasma volume, H2O/C ratio, O/C ratio, and input electric power is presented. ... Most of them were particularly dealt with technologies based on arc discharges. ...

José Gonzalez-Aguilar; Guillaume Petitpas; Alexandre Lebouvier; Jean-Damien Rollier; Adeline Darmon; Laurent Fulcheri

2009-09-08T23:59:59.000Z

472

Why PUHCA reform is likely in the 102nd Congress. [Public Utilities Holding Company Act (PUHCA)  

SciTech Connect

This article examines the reasons that it is likely that the 102nd Congress will pass legislation that will reform the Public Utilities Holding Company Act of 1935. The impetus provided by the Persian Gulf War, public opinion, the National Energy Plan and the National Independent Energy Producers (NIEP) is examined. Several proposals of the NIEP to guard against market abuses in the reforms are presented.

Welford, W.H. (Olwine, Connelly, Chase, O'Donnell and Weyher, Washington, DC (United States)); Elston, P.J. (Long Lake Energy Corp., New York, NY (United States))

1991-03-15T23:59:59.000Z

473

Reaction Profiles during Exhaust-Assisted Reforming of Diesel Engine Fuels  

Science Journals Connector (OSTI)

Reaction Profiles during Exhaust-Assisted Reforming of Diesel Engine Fuels ... The reforming efficiency was dependent on the fuel type and followed the general trend of bioethanol > rapeseed methyl ester > low-sulfur diesel fuel. ... The use of exhaust gas recirculation (EGR) in diesel engines reduces nitrogen oxide (NOx) emissions but results in an increased release of smoke and particulate matter (PM), as well as higher fuel consumption. ...

A. Tsolakis; A. Megaritis; S. E. Golunski

2005-03-10T23:59:59.000Z

474

Statistical validation and an empirical model of hydrogen production enhancement found by utilizing passive flow disturbance in the steam-reformation process  

SciTech Connect

A passive flow disturbance has been proven to enhance the conversion of fuel in a methanol-steam reformer. This study presents a statistical validation of the experiment based on a standard 2{sup k} factorial experiment design and the resulting empirical model of the enhanced hydrogen producing process. A factorial experiment design was used to statistically analyze the effects and interactions of various input factors in the experiment. Three input factors, including the number of flow disturbers, catalyst size, and reactant flow rate were investigated for their effects on the fuel conversion in the steam-reformation process. Based on the experimental results, an empirical model was developed and further evaluated with an uncertainty analysis and interior point data. (author)

Erickson, Paul A.; Liao, Chang-hsien [Department of Mechanical and Aeronautical Engineering, University of California, One Shields Avenue, Davis, CA 95616 (United States)

2007-11-15T23:59:59.000Z

475

CX-003967: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

67: Categorical Exclusion Determination 67: Categorical Exclusion Determination CX-003967: Categorical Exclusion Determination Steam Reforming Treatability Study with Hanford Samples CX(s) Applied: B3.6 Date: 09/03/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office A mixed waste treatability study will be performed to test the fluidized bed steam reforming (FBSR) technology on two caustic Hanford waste streams (SX-105 and An-103). The tests will be performed in Savannah River National Laboratory 773-A Shielded Cells, A-block with portions being completed in B-wing and in the Analytical Development laboratories. Approximately, 1 Liter of each waste stream will be fed to the process over the course of 8 runs (250 milliliter of waste per run). DOCUMENT(S) AVAILABLE FOR DOWNLOAD

476

CX-005511: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

511: Categorical Exclusion Determination 511: Categorical Exclusion Determination CX-005511: Categorical Exclusion Determination Steam Reforming Treatability Study with Hanford Sample E CX(s) Applied: B3.6 Date: 02/10/2011 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office A mixed waste treatability study will be performed to test the fluidized bed steam reforming (FBSR) technology on a composite of two caustic Hanford tank waste streams (AZ101 and AZ102). The tests will be performed in Savannah River National Laboratory 773-A Shielded Cells, A-block with portions being completed in B-wing and in the Analytical Development labs. Approximately, 1.5 liters of each waste stream will be fed to the process over the course of ~15 runs ( DOCUMENT(S) AVAILABLE FOR DOWNLOAD

477

CX-004173: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

3: Categorical Exclusion Determination 3: Categorical Exclusion Determination CX-004173: Categorical Exclusion Determination Steam Reforming Treatability Study with Savannah River Site Low Activity Waste (LAW) (Module B) CX(s) Applied: B3/6 Date: 09/30/2010 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office A mixed waste treatability study will be performed to test the fluidized bed steam reforming (FBSR) technology on Savannah River Site Low Activity Waste (LAW) modified to simulate Hanford waste. The tests will be performed in Savannah River National Laboratory 773-A Shielded Cells, A-block with portions being completed in B-wing, C-wing, and in the Analytical Development laboratories. Approximately 2 liters of sample will be fed to the process.

478

Effect of CeO2 and La2O3 on the Activity of CeO2?La2O3/Al2O3-Supported Pd Catalysts for Steam Reforming of Methane  

Science Journals Connector (OSTI)

The effect of the addition of CeO2 or La2O3 on the surface properties and catalytic behaviors of Al2O3-supported Pd catalysts was studied in the steam reforming of methane. The FTIR spectroscopy of adsorbed CO an...

W. H. Cassinelli; L. S. F. Feio; J. C. S. Araújo; C. E. Hori…

2008-01-01T23:59:59.000Z

479

Steam reforming of low-level mixed waste  

SciTech Connect

The U.S. department of Energy (DOE) is responsible for the treatment and disposal of an inventory of approximately 160,000 tons of Low-Level Mixed Waste (LLMW). Most of this LLMW is stored in drums, barrels and steel boxes at 20 different sites throughout the DOE complex. The basic objective of low-level mixed waste treatment systems is to completely destroy the hazardous constituents and to simultaneously isolate and capture the radionuclides in a superior final waste form such as glass. The DOE is sponsoring the development of advanced technologies that meet this objective while achieving maximum volume reduction, low-life cycle costs and maximum operational safety. ThermoChem, Inc. is in the final stages of development of a steam-reforming system capable of treating a wide variety of DOE low-level mixed waste that meets these objectives. The design, construction, and testing of a nominal 1 ton/day Process Development Unit is described.

Voelker, G.E.; Steedman, W.G. [Thermochem, Inc., Columbia, MD (United States); Chandran, R.R. [Manufacturing and Technology Conversion International, Inc., Columbia, MD (United States)

1996-12-31T23:59:59.000Z

480

Second Law Analysis of a Solar Methane Reforming System  

Science Journals Connector (OSTI)

Abstract In this paper, we present the results of a Second Law analysis of a highly efficient, solar thermochemical reaction system for the production of syngas using micro- and meso-channel process technology. The evaluation includes the initial conversion of solar energy/exergy into physical energy/exergy and its subsequent conversion into chemical energy/exergy through the catalytic, endothermic reforming reaction, including quantifications of exergy destruction for components and the overall system. Possible applications include the combustion of the product syngas in a hybrid, solar/natural gas power plant, providing an efficient solar augment to the natural gas fuel; the thermochemical storage of solar energy, as part of an open or closed-cycle storage process; the production of hydrogen for use in fuel cells and for other purposes; and the production of synthetic fuels such as methanol or long-chain hydrocarbons. The analyses show that the overall process is exergetically-efficient and consistent with First Law and economic analyses. Finally, opportunities for improving the exergetic efficiency of the process are identified and discussed

Robert Wegeng; Richard Diver; Paul Humble

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming treatability study" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Methods of reforming hydrocarbon fuels using hexaaluminate catalysts  

DOE Patents (OSTI)

A metal substituted hexaaluminate catalyst for reforming hydrocarbon fuels to synthesis gas of the general formula AB.sub.yAl.sub.12-yO.sub.19-.delta., A being selected from alkali metals, alkaline earth metals and lanthanide metals or mixtures thereof. A dopant or surface modifier selected from a transitions metal, a spinel of an oxygen-ion conductor is incorporated. The dopant may be Ca, Cs, K, La, Sr, Ba, Li, Mg, Ce, Co, Fe, Ir, Rh, Ni, Ru, Cu, Pe, Os, Pd, Cr, Mn, W, Re, Sn, Gd, V, Ti, Ag, Au, and mixtures thereof. The oxygen-ion conductor may be a perovskite selected from M'RhO.sub.3, M'PtO.sub.3, M'PdO.sub.3, M'IrO.sub.3, M'RuO.sub.3 wherein M'=Mg, Sr, Ba, La, Ca; a spinel selected from MRh.sub.2O.sub.4, MPt.sub.2O.sub.4, MPd.sub.2O.sub.4, MIr.sub.2O.sub.4, MRu.sub.2O.sub.4 wherein M=Mg, Sr, Ba, La, Ca and mixtures thereof; a florite is selected from M''O.sub.2.

Gardner, Todd H. (Morgantown, WV); Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV)

2012-03-27T23:59:59.000Z

482

Reform towards National Health Insurance in Malaysia: The equity implications  

Science Journals Connector (OSTI)

Objective This paper assesses the potential equity impact of Malaysia's projected reform of its current tax financed system towards National Health Insurance (NHI). Methods The Kakwani's progressivity index was used to assess the equity consequences of the new NHI system (with flat rate NHI scheme) compared to the current tax financed system. It was also used to model a proposed system (with a progressive NHI scheme) that can generate the same amount of funding more equitably. Results The new NHI system would be less equitable than the current tax financed system, as evident from the reduction of Kakwani's index to 0.168 from 0.217. The new flat rate NHI scheme, if implemented, would reduce the progressivity of the health finance system because it is a less progressive finance source than that of general government revenue. We proposed a system with a progressive NHI scheme that generates the same amount of funding whilst preserving the equity at the Kakwani's progressivity index of 0.213. Conclusions A NHI system with a progressive NHI scheme is proposed to be implemented to raise health funding whilst preserving the equity in health care financing.

Chai Ping Yu; David K. Whynes; Tracey H. Sach

2011-01-01T23:59:59.000Z

483

Hydrogen production from methane dry reforming over nickel-based nanocatalysts using surfactant-assisted or polyol method  

Science Journals Connector (OSTI)

Abstract In this study, two series of Ni-based nanocatalysts were synthesized successfully by the polyol and surfactant-assisted methods and subsequently tested for hydrogen production from CO2–CH4 reforming. Surfactant-assisted catalysts were prepared by using cetyl trimethyl ammonium bromide (CTAB) as a surfactant, whereas polyol catalysts were prepared in ethylene glycol (EG) medium with polyvinylpyrrolidone (PVP) as a nucleation-protective agent. The catalytic performance of each catalyst, in terms of H2 yield and selectivity, was evaluated at different temperatures (500–800 °C). In order to clarify and explain the differences in catalytic activities of catalysts, the prepared samples were characterized by various techniques, such as BET, H2-TPR, CO2-TPD, XRD, TGA, SEM, HRTEM and CO pulse chemisorption. The results demonstrated that the method of preparation had a significant effect on the catalytic performance of tested catalysts. Overall, polyol catalysts showed high activity and selectivity for hydrogen production, while surfactant-assisted catalysts exhibited a fairly high resistance towards carbon deposition under similar reaction conditions of dry reforming of methane. Moreover, due to the reverse water gas shift reaction (RWGS), surfactant-assisted catalysts always produced smaller values of H2/CO product ratio than their corresponding polyol catalysts.

Muhammad Awais Naeem; Ahmed Sadeq Al-Fatesh; Anis Hamza Fakeeha; Ahmed Elhag Abasaeed

2014-01-01T23:59:59.000Z

484

Extraction of aromatics from petroleum naphtha reformate by a 1-cyclohexyl-2-pyrrolidone/ethylene carbonate mixed solvent  

SciTech Connect

The phase equilibria for the extraction of aromatics from petroleum naphtha reformate (with a boiling range of 338--403 K) using a mixed solvent of 1-cyclohexyl-2-pyrrolidone (CHP) and ethylene carbonate (EC) have been correlated using the universal function-group activity coefficients model (UNIFAC). The interaction parameters of CHP and EC with different hydrocarbon groups present in the reformate such as CH{sub 2} (paraffinic CH{sub 2}), ACH (aromatic CH), ACCH{sub 2} (aromatic CCH{sub 2}), and each of the two solvents have been fitted to experimental concentrations of three ternary systems that contain these groups. The extraction runs have been carried out at different temperatures, solvent compositions, and solvent-to-feed ratios. Experimental results compared favorably with those predicted from the UNIFAC method. The optimum extraction conditions were determined by calculation of the minimum energy of separation. In this study these conditions were found to be at a mixed solvent composition of 65% EC (by weight) and 35% CHP. The solvent-to-feed ratio was 1.8 on a volume basis, and the extraction temperature was 329 K.

Radwan, G.M.; Al-Muhtaseb, S.A.; Dowaidar, A.M.; Fahim, M.A. [United Arab Emirates Univ., Al-Ain (United Arab Emirates). Chemical and Petroleum Engineering Dept.] [United Arab Emirates Univ., Al-Ain (United Arab Emirates). Chemical and Petroleum Engineering Dept.

1997-02-01T23:59:59.000Z

485

New nickel-based material (Sr12Al14O33) for biomass tar steam reforming for syngas production  

Science Journals Connector (OSTI)

A new “free oxygen” material Sr12Al14O33 (Sr12A7) was developed as a Ni support for biomass tar steam reforming. Toluene was chosen as the model compound for biomass gasification tar. The steam reforming process was investigated in a fixed-bed reactor. The influence of the operating parameters (i.e. reaction temperature steam-to-carbon ratio and space time) on catalyst activity and product selectivity were studied. Ni/Sr12A7 (5?wt %) showed a higher activity compared with a similar commercial catalyst Ni/Dolomite. The influence of the steam/carbon (S/C) molar ratio on gas yields at values ranging from 1.5 to 4.0 was investigated. The results show that the H2 and CO2 yields increased whereas the CO yield decreased when the S/C ratio was increased. The influence of space-time (w cat/F toluene) was also determined. The H2 CO2 and total gas yields increased when the ratio was increased. Catalyst ageing experiments were characterized by Brunauer-Emmett-Teller (BET) X-ray diffraction (XRD) and energy dispersive X-ray spectrometer (EDX). Based on the results the kinetic model is proposed as a first-order reaction for toluene with an activation energy of 131.2?kJ·mol?1 as generally accepted in the literature.

Chunshan Li

2013-01-01T23:59:59.000Z

486

Fuel processing for fuel cells: a model for fuel conversion and carbon formation in the adiabatic steam reformer  

SciTech Connect

In present fuel cell power plants the fuel processor is a catalytic steam reformer which is limited to the use of fuels such as naphtha and natural gas. The sulfur content of these feeds must be reduced to low levels by hydrotreatment before contacting the nickel catalyst in the reformer. However, future fuel cell power plants may be required to ue coal-derived liquid fuel or heavy petroleum distillates which are more difficult to hydrotreat and reform. To meet this requirement, an adiabatic steam reformer is being developed by United Technologies Corporation with the support of the Electric Power Research Institute. In the adiabatic reformer, air is added to the process stream to provide, by combustion, the heat for endothermic reforming in a catalyst bed. In the inlet section of the reformer, air and fuel combust, and reforming is initiated on special catalysts whose primary functon is to prevent formation and accumulation of carbon. Following the inlet section, catalysts with high activity for steam reforming complete the conversion of the remaining fuel, principally methane. The objective of the present program is to establish a reactor model for the adiabatic reformer which would predict process stream compositions and temperatures and include carbon formation processes. Progress is reported on the four tasks: (1) determine rate expressions for catalytic reactions occurring in the adiabatic reformer; (2) establish a reactor model to predict process stream compositions in the adiabatic reformer using data from Task 1 for cataytic reactions and data from the literature for homogeneous gas-phase reactions; (3) determine critical conditions for carbon formation on selected catalysts using microbalance experiments; and (4) establish a model to predict carbon formation by combination of the model for process stream composition from Task 2 and data for carbon formation from Task 3. (WHK)

Bett, J.A.S.; Cutlip, M.C.; Foley, P.F.; Lesieur, R.R.; Meyer, A.P.; Sederquist, R.A.; Setzer, H.J.

1981-01-01T23:59:59.000Z

487

Syngas production by CO2 reforming of coke oven gas over Ni/La2O3–ZrO2 catalysts  

Science Journals Connector (OSTI)

Abstract Syngas production by CO2 reforming of coke oven gas (COG) was studied in a fixed-bed reactor over Ni/La2O3–ZrO2 catalysts. The catalysts were prepared by sol–gel technique and tested by XRF, BET, XRD, H2-TPR, TEM and TG–DSC. The influence of nickel loadings and calcination temperature of the catalysts on reforming reaction was measured. The characterization results revealed that all of the catalysts present excellent resistance to coking. The catalyst with appropriate nickel content and calcination temperature has better dispersion of active metal and higher conversion. It is found that the Ni/La2O3–ZrO2 catalyst with 10 wt% nickel loading provides the best catalytic activity with the conversions of CH4 and CO2 both more than 95% at 800 °C under the atmospheric pressure. The Ni/La2O3–ZrO2 catalysts show excellent catalytic performance and anti-carbon property, which will be of great prospects for catalytic CO2 reforming of COG in the future.

Wei Tao; Hongwei Cheng; Weilin Yao; Xionggang Lu; Qiuhua Zhu; Guangshi Li; Zhongfu Zhou

2014-01-01T23:59:59.000Z

488

Method for the operation of internal combustion engines. [gasification reactor for reforming gasoline  

SciTech Connect

This is a method for the operation of internal combustion engines which is designed to decontaminate the exhaust gases. The method includes: feeding a gasification air stream into a gasification reactor; feeding fuel into the same gasification reactor; combining the fuel with the gasification air into a homogeneous fuel-air mixture in the gasification reactor; and converting the fuel-air mixture by partial combustion into a soot -free reformed gas. Then, the reformed gas is fed from the gasification reactor to a mixer where the reformed gas is mixed with combustion air and the reformed gas-air mixture is fed to the internal combustion engine for further combustion with the result that there is intensive decontamination of the exhaust gases which thereby reduces air pollution. The reformed gas temperature is adjusted low for maximum engine output, and is adjusted higher for lower engine temperatures in order to obtain a reformed gas which is richer in hydrogen and thereby produce exhaust gases which are lower in harmful substances. In reference to the exhaust gases in an internal combustion engine, this method achieves the highest possible degree of decontamination, not only of the carbon monoxide and hydrocarbons , but also of the nitrous oxides in the exhaust gases. Using this method, the internal combustion engine can be operated not only with high-test, no-knock gasoline, but also with cheap, lead-free low octane, straight-run gasoline which is low in aromatics and olefins, which normally do not have no-knock properties, and the internal combustion engine can be operated with the lowest possible fuel consumption. The gasification reactor operates through chemical reaction in the presence of a catalyst. Optionally, this method may include a return of part of the reformed gas to the input of the gasification reactor.

Muhlberg, E.

1980-01-29T23:59:59.000Z

489

Lineage and land reforms in Malawi: Do matrilineal and patrilineal landholding systems represent a problem for land reforms in Malawi?  

Science Journals Connector (OSTI)

Abstract Based on government statistics and interviews with villagers across Malawi this article argues that customary matrilineal and patrilineal land tenure systems serve to weaken security of land tenure for some family members as well as obstructing the creation of gender-neutral inheritance of lands. Data from the National Census of Agriculture and Livestock 2007and the 2008 Population and Housing Census are used to characterize marriage systems and landholding patterns of local communities. Marriage systems correspond to customary land-tenure patterns of matrilineal or patrilineal cultures. The differences between the two ways of land holding represent a challenge for land reforms aimed at unifying rules for land tenure and land devolution. Drawing on an analogy of the resilience of the patrilineal land holding system in Norway, we argue that it will be difficult to remove the preferential rights of lineage members directly. We recommend that, instead of creating a unified national system, existing land rights should be formally recognized and circumscribed by fair procedures. A well-designed landholding system should aim to ease the transitions of diverse customary tenure systems towards the requirements of a modern large-scale society.

Erling Berge; Daimon Kambewa; Alister Munthali; Henrik Wiig

2014-01-01T23:59:59.000Z

490

Re-formation of the channel of the enisei river in the lower pool of the Krasnoyarsk hydroelectric power station  

Science Journals Connector (OSTI)

1. At first the main re-formation of the channel occurred in the immediate vicinity of the structures, with its ...

T. F. Avrova; A. I. Kuznetsov

1968-11-01T23:59:59.000Z

491

Zur Bedeutung der Diskussion zur Reform der Eingliederungshilfe für die Wohnungslosenhilfe – Verlagerung der Steuerungsverantwortung und verstärkte Wirksamkeitskontrollen  

Science Journals Connector (OSTI)

Seit 2003 wird über die Weiterentwicklung der Eingliederungshilfe für behinderte Menschen diskutiert. Der grundlegende Ansatz der unter dem Begriff „Reform der Eingliederungshilfe“ geführten fachpolitischen Disku...

Johannes Lippert

2014-01-01T23:59:59.000Z

492

Hydrogen production from methane steam reforming: parametric and gradient based optimization of a Pd-based membrane reactor  

Science Journals Connector (OSTI)

In this work three mathematical models for methane steam reforming in membrane reactors were developed. The first ... , the influence of five important parameters on methane conversion (X ...

Leandro C. Silva; Valéria V. Murata; Carla E. Hori…

2010-09-01T23:59:59.000Z

493

Effect of nickel loading on the activity of Ni/ZrO2 for methane steam reforming at low temperature  

Science Journals Connector (OSTI)

The effect of Ni loading on the catalytic activity of Ni/ZrO2 catalyst for methane steam reforming was investigated. The sample containing 15 wt...

Long Q. Nguyen; Leonila C. Abella…

2008-04-01T23:59:59.000Z

494

Simultaneous carbon dioxide and steam reforming of methane to syngas over NiO-CaO catalyst  

SciTech Connect

Steam reforming, Co{sub 2} reforming, and simultaneous steam and CO{sub 2} reforming of methane to CO and H{sub 2} over NiO-CaO catalyst (without any