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1

Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Maturation Plan (TMP) Fluidized Bed Steam Reforming Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP) Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP) This assessment determines the technology maturity level of the candidate Tank 48H treatment technologies that are being considered for implementation at DOE's SRS - specifically Fluidized Bed Steam Reformer System. Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP) More Documents & Publications Technology Maturation Plan (TMP) Wet Air Oxidation (WAO) Technology for Tank 48H Treatment Project (TTP) SRS Tank 48H Waste Treatment Project Technology Readiness Assessment

2

Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

LWO-SPT-2007-00249 LWO-SPT-2007-00249 Rev. 1 Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) For Tank 48H Treatment Project (TTP) November, 2007 Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP) LWO-SPT-2007-00249 Rev. 1 DISCLAIMER This report was prepared by Washington Savannah River Company (WSRC) for the United States Department of Energy under Contract No. DEA-AC09-96SR18500 and is an account of work performed under that contract. Neither the United States Department of Energy, nor WSRC, nor any of their employees makes any warranty, expressed or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, or product or process

3

DURABILITY TESTING OF FLUIDIZED BED STEAM REFORMER (FBSR) WASTE FORMS  

SciTech Connect

Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium aqueous radioactive wastes. The addition of clay and a catalyst as co-reactants converts high sodium aqueous low activity wastes (LAW) such as those existing at the Hanford and Idaho DOE sites to a granular ''mineralized'' waste form that may be made into a monolith form if necessary. Simulant Hanford and Idaho high sodium wastes were processed in a pilot scale FBSR at Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium-bearing waste (SBW). The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The durability of the FBSR waste form products was tested in order to compare the measured durability to previous FBSR waste form testing on Hanford Envelope C waste forms that were made by THOR Treatment Technologies (TTT) and to compare the FBSR durability to vitreous LAW waste forms, specifically the Hanford low activity waste (LAW) glass known as the Low-activity Reference Material (LRM). The durability of the FBSR waste form is comparable to that of the LRM glass for the test responses studied.

Jantzen, C

2006-01-06T23:59:59.000Z

4

Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer (FBSR) Na-Al-Si (NAS) Waste Form Qualification  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hanford Low Activity Waste (LAW) Fluidized Bed Steam Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer (FBSR) Na-Al-Si (NAS) Waste Form Qualification C.M. Jantzen and E.M. Pierce November 18, 2010 2 Participating Organizations 3 Incentive and Objectives FBSR sodium-aluminosilicate (NAS) waste form has been identified as a promising supplemental treatment technology for Hanford LAW Objectives: Reduce the risk associated with implementing the FBSR NAS waste form as a supplemental treatment technology for Hanford LAW Conduct test with actual tank wastes Use the best science to fill key data gaps Linking previous and new results together 4 Outline FBSR NAS waste form processing scales FBSR NAS waste form data/key assumptions FBSR NAS key data gaps FBSR NAS testing program 5 FBSR NAS Waste Form Processing

5

RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING (FBSR) WITH HANFORD LOW ACTIVITY WASTES  

SciTech Connect

Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) are being evaluated. One immobilization technology being considered is Fluidized Bed Steam Reforming (FBSR) which offers a low temperature (700-750°C) continuous method by which wastes high in organics, nitrates, sulfates/sulfides, or other aqueous components may be processed into a crystalline ceramic (mineral) waste form. The granular waste form produced by co-processing the waste with kaolin clay has been shown to be as durable as LAW glass. The FBSR granular product will be monolithed into a final waste form. The granular component is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals such as sodalite. Production of the FBSR mineral product has been demonstrated both at the industrial, engineering, pilot, and laboratory scales on simulants. Radioactive testing at SRNL commenced in late 2010 to demonstrate the technology on radioactive LAW streams which is the focus of this study.

Jantzen, C.; Crawford, C.; Burket, P.; Bannochie, C.; Daniel, G.; Nash, C.; Cozzi, A.; Herman, C.

2012-10-22T23:59:59.000Z

6

Radioactive Demonstrations Of Fluidized Bed Steam Reforming (FBSR) With Hanford Low Activity Wastes  

Science Conference Proceedings (OSTI)

Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) are being evaluated. One immobilization technology being considered is Fluidized Bed Steam Reforming (FBSR) which offers a low temperature (700-750?C) continuous method by which wastes high in organics, nitrates, sulfates/sulfides, or other aqueous components may be processed into a crystalline ceramic (mineral) waste form. The granular waste form produced by co-processing the waste with kaolin clay has been shown to be as durable as LAW glass. The FBSR granular product will be monolithed into a final waste form. The granular component is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals such as sodalite. Production of the FBSR mineral product has been demonstrated both at the industrial, engineering, pilot, and laboratory scales on simulants. Radioactive testing at SRNL commenced in late 2010 to demonstrate the technology on radioactive LAW streams which is the focus of this study.

Jantzen, C. M.; Crawford, C. L.; Burket, P. R.; Bannochie, C. J.; Daniel, W. G.; Nash, C. A.; Cozzi, A. D.; Herman, C. C.

2012-10-22T23:59:59.000Z

7

FLUIDIZED BED STEAM REFORMER (FBSR) PRODUCT: MONOLITH FORMATION AND CHARACTERIZATION  

SciTech Connect

The most important requirement for Hanford's low activity waste (LAW) form for shallow land disposal is the chemical durability of the product. A secondary, but still essential specification, is the compressive strength of the material with regards to the strength of the material under shallow land disposal conditions, e.g. the weight of soil overburden and potential intrusion by future generations, because the term ''near-surface disposal'' indicates disposal in the uppermost portion, or approximately the top 30 meters, of the earth's surface. The THOR{reg_sign} Treatment Technologies (TTT) mineral waste form for LAW is granular in nature because it is formed by Fluidized Bed Steam Reforming (FBSR). As a granular product it has been shown to be as durable as Hanford's LAW glass during testing with ASTM C-1285-02 known as the Product Consistency Test (PCT) and with the Single Pass Flow Through Test (SPFT). Hanford Envelope A and Envelope C simulants both performed well during PCT and SPFT testing and during subsequent performance assessment modeling. This is partially due to the high aluminosilicate content of the mineral product which provides a natural aluminosilicate buffering mechanism that inhibits leaching and is known to occur in naturally occurring aluminosilicate mineral analogs. In order for the TTT Na-Al-Si (NAS) granular mineral product to meet the compressive strength requirements (ASTM C39) for a Hanford waste form, the granular product needs to be made into a monolith or disposed of in High Integrity Containers (HIC's). Additionally, the Hanford intruder scenario for disposal in the Immobilized Low Activity Waste (ILAW) trench is mitigated as there is reduced intruder exposure when a waste form is in a monolithic form. During the preliminary testing of a monolith binder for TTT's FBSR mineral product, four parameters were monitored: (1) waste loading (not optimized for each waste form tested); (2) density; (3) compressive strength; and (4) durability must not be compromised--binding agent should not react with the NAS product and binding agent should not create an unfavorable pH environment that may cause accelerated leaching. It is the goal of the present study to survey cementitious waste forms based on Ordinary Portland Cement (OPC), Ceramicrete, and hydroceramic binders by correlating waste loading, density and compressive strength and then determine if these binders affect the product performance in terms of the PCT response. This will be done by making a one-to-one comparison of the PCT response measured on granular NAS mineral product (mixed bed and fines products) with the PCT response of the monolithed NAS product in the different binders. Future studies may include, refining the above binders, and examining other binders. It is likely that binders formed from kaolin would be most compatible with the chemistry of the THOR{reg_sign} mineral waste form which is made by steam reforming of kaolin and sodium rich wastes. The economics of production on a large scale have yet to be investigated for any of the binders tested.

Jantzen, C

2006-09-13T23:59:59.000Z

8

Single Pass Flow-Through (SPFT) Test Results of Fluidized Bed Steam Reforming (FBSR) Waste Forms used for LAW Immobilization  

Science Conference Proceedings (OSTI)

Several supplemental technologies for treating and immobilizing Hanford low activity waste (LAW) are being evaluated. One such immobilization technology being considered is the Fluidized Bed Steam Reforming (FBSR) granular product. The FBSR granular product is composed of insoluble sodium aluminosilicate (NAS) feldspathoid minerals. Production of the FBSR mineral product has been demonstrated both at the industrial and laboratory scale. Single-Pass Flow-Through (SPFT) tests at various flow rates have been conducted with the granular products fabricated using these two methods. Results show that the materials exhibit a relatively low forward dissolution rate on the order of 10-3 g/(m2d) with the material made in the laboratory giving slightly higher values.

Neeway, James J.; Qafoku, Nikolla; Williams, Benjamin D.; Valenta, Michelle M.; Cordova, Elsa A.; Strandquist, Sara C.; Dage, DeNomy C.; Brown, Christopher F.

2012-03-20T23:59:59.000Z

9

Microsoft PowerPoint - 9-03 Jantzen FBSR EM TECH EX SLIDES-JANTZEN-PIERCE.ppt  

NLE Websites -- All DOE Office Websites (Extended Search)

Reformer (FBSR) Na-Al-Si (NAS) Waste Reformer (FBSR) Na-Al-Si (NAS) Waste Form For Hanford LAW and Secondary Waste C.M. Jantzen and E.M. Pierce November 17, 2010 Print Close 2 FY10: Participating Organizations Print Close 3 Incentive and Objectives FBSR sodium-aluminosilicate (NAS) waste form has been identified as a promising supplemental treatment technology for Hanford LAW and/or Waste Treatment Plant Secondary Waste (WTP-SW) Objectives:

10

RADIOACTIVE DEMONSTRATION OF MINERALIZED WASTE FORMS MADE FROM HANFORD LOW ACTIVITY WASTE (TANK FARM BLEND) BY FLUIDIZED BED STEAM REFORMATION (FBSR)  

Science Conference Proceedings (OSTI)

The U.S. Department of Energy’s Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford’s tank waste. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Supplemental Treatment is likely to be required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP’s LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750°C) continuous method by which LAW can be processed irrespective of whether the waste contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be comparable to LAW glass, i.e. leaches Tc-99, Re and Na at 6 (the Hanford IDF criteria for Na) in the first few hours. The granular and monolithic waste forms also pass the EPA Toxicity Characteristic Leaching Procedure (TCLP) for all Resource Conservation and Recovery Act (RCRA) components at the Universal Treatment Standards (UTS). Two identical Benchscale Steam Reformers (BSR) were designed and constructed at SRNL, one to treat non-radioactive simulants and the other to treat actual radioactive wastes. The results from the non-radioactive BSR were used to determine the parameters needed to operate the radioactive BSR in order to confirm the findings of non-radioactive FBSR pilot scale and engineering scale tests and to qualify an FBSR LAW waste form for applications at Hanford. Radioactive testing commenced using SRS LAW from Tank 50 chemically trimmed to look like Hanford’s blended LAW known as the Rassat simulant as this simulant composition had been tested in the non-radioactive BSR, the non-radioactive pilot scale FBSR at the Science Applications International Corporation-Science and Technology Applications Research (SAIC-STAR) facility in Idaho Falls, ID and in the TTT Engineering Scale Technology Demonstration (ESTD) at Hazen Research Inc. (HRI) in Denver, CO. This provided a “tie back” between radioactive BSR testing and non-radioactive BSR, pilot scale, and engineering scale testing. Approximately six hundred grams of non-radioactive and radioactive BSR product were made for extensive testing and comparison to the non-radioactive pilot scale tests performed in 2004 at SAIC-STAR and the engineering scale test performed in 2008 at HRI with the Rassat simulant. The same mineral phases and off-gas species were found in the radioactive and non-radioactive testing. The granular ESTD and BSR products (radioactive and non-radioactive) were analyzed for to

Jantzen, C. M.; Crawford, C. L.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Daniel, W. E.; Hall, H. K.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.

2013-08-21T23:59:59.000Z

11

RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING WITH ACUTAL HANFORD LOW ACTIVITY WASTES VERIFYING FBSR AS A SUPPLEMENTARY TREATMENT  

SciTech Connect

The U.S. Department of Energy's Office of River Protection is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level waste (HLW) and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the cleanup mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA). Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. Fluidized Bed Steam Reforming (FBSR) is one of the supplementary treatments being considered. FBSR offers a moderate temperature (700-750 C) continuous method by which LAW and other secondary wastes can be processed irrespective of whether they contain organics, nitrates/nitrites, sulfates/sulfides, chlorides, fluorides, and/or radio-nuclides like I-129 and Tc-99. Radioactive testing of Savannah River LAW (Tank 50) shimmed to resemble Hanford LAW and actual Hanford LAW (SX-105 and AN-103) have produced a ceramic (mineral) waste form which is the same as the non-radioactive waste simulants tested at the engineering scale. The radioactive testing demonstrated that the FBSR process can retain the volatile radioactive components that cannot be contained at vitrification temperatures. The radioactive and nonradioactive mineral waste forms that were produced by co-processing waste with kaolin clay in an FBSR process are shown to be as durable as LAW glass.

Jantzen, C.; Crawford, C.; Burket, P.; Bannochie, C.; Daniel, G.; Nash, C.; Cozzi, A.; Herman, C.

2012-01-12T23:59:59.000Z

12

RADIOACTIVE DEMONSTRATION OF MINERALIZED WASTE FORMS MADE FROM HANFORD LOW ACTIVITY WASTE (TANK FARM BLEND) BY FLUIDIZED BED STEAM REFORMATION (FBSR)  

SciTech Connect

The U.S. Department of Energy’s Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford’s tank waste. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Supplemental Treatment is likely to be required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP’s LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750°C) continuous method by which LAW can be processed irrespective of whether the waste contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be comparable to LAW glass, i.e. leaches Tc-99, Re and Na at <2g/m2 during ASTM C1285 (Product Consistency) durability testing. Monolithing of the granular FBSR product was investigated to prevent dispersion during transport or burial/storage. Monolithing in an inorganic geopolymer binder, which is amorphous, macro-encapsulates the granules, and the monoliths pass ANSI/ANS 16.1 and ASTM C1308 durability testing with Re achieving a Leach Index (LI) of 9 (the Hanford Integrated Disposal Facility, IDF, criteria for Tc-99) after a few days and Na achieving an LI of >6 (the Hanford IDF criteria for Na) in the first few hours. The granular and monolithic waste forms also pass the EPA Toxicity Characteristic Leaching Procedure (TCLP) for all Resource Conservation and Recovery Act (RCRA) components at the Universal Treatment Standards (UTS). Two identical Benchscale Steam Reformers (BSR) were designed and constructed at SRNL, one to treat non-radioactive simulants and the other to treat actual radioactive wastes. The results from the non-radioactive BSR were used to determine the parameters needed to operate the radioactive BSR in order to confirm the findings of non-radioactive FBSR pilot scale and engineering scale tests and to qualify an FBSR LAW waste form for applications at Hanford. Radioactive testing commenced using SRS LAW from Tank 50 chemically trimmed to look like Hanford’s blended LAW known as the Rassat simulant as this simulant composition had been tested in the non-radioactive BSR, the non-radioactive pilot scale FBSR at the Science Applications International Corporation-Science and Technology Applications Research (SAIC-STAR) facility in Idaho Falls, ID and in the TTT Engineering Scale Technology Demonstration (ESTD) at Hazen Research Inc. (HRI) in Denver, CO. This provided a “tie back” between radioactive BSR testing and non-radioactive BSR, pilot scale, and engineering scale testing. Approximately six hundred grams of non-radioactive and radioactive BSR product were made for extensive testing and comparison to the non-radioactive pilot scale tests performed in 2004 at SAIC-STAR and the engineering scale test performed in 2008 at HRI with the Rassat simulant. The same mineral phases and off-gas species were found in the radioactive and non-radioactive testing. The granular ESTD and BSR products (radioactive and non-radioactive) were analyzed for to

Jantzen, C. M.; Crawford, C. L.; Bannochie, C. J.; Burket, P. R.; Cozzi, A. D.; Daniel, W. E.; Hall, H. K.; Miller, D. H.; Missimer, D. M.; Nash, C. A.; Williams, M. F.

2013-08-21T23:59:59.000Z

13

RADIOACTIVE DEMONSTRATION OF MINERALIZED WASTE FORMS MADE FROM HANFORD LOW ACTIVITY WASTE (TANK SX-105, TANK AN-103, AND AZ-101/102) BY FLUIDIZED BED STEAM REFORMATION (FBSR)  

Science Conference Proceedings (OSTI)

Fluidized Bed Steam Reforming (FBSR) is a robust technology for the immobilization of a wide variety of radioactive wastes. Applications have been tested at the pilot scale for the high sodium, sulfate, halide, organic and nitrate wastes at the Hanford site, the Idaho National Laboratory (INL), and the Savannah River Site (SRS). Due to the moderate processing temperatures, halides, sulfates, and technetium are retained in mineral phases of the feldspathoid family (nepheline, sodalite, nosean, carnegieite, etc). The feldspathoid minerals bind the contaminants such as Tc-99 in cage (sodalite, nosean) or ring (nepheline) structures to surrounding aluminosilicate tetrahedra in the feldspathoid structures. The granular FBSR mineral waste form that is produced has a comparable durability to LAW glass based on the short term PCT testing in this study, the INL studies, SPFT and PUF testing from previous studies as given in the columns in Table 1-3 that represent the various durability tests. Monolithing of the granular product was shown to be feasible in a separate study. Macro-encapsulating the granular product provides a decrease in leaching compared to the FBSR granular product when the geopolymer is correctly formulated.

Jantzen, C.; Crawford, C.; Bannochie, C.; Burket, P.; Cozzi, A.; Daniel, G.; Hall, H.; Miller, D.; Missimer, D.; Nash, C.; Williams, F.

2013-09-18T23:59:59.000Z

14

(FBSR) with Hanford Low Activity Wastes - Programmaster.org  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

15

CRUCIBLE TESTING OF TANK 48 RADIOACTIVE WASTE SAMPLE USING FBSR TECHNOLOGY FOR ORGANIC DESTRUCTION  

SciTech Connect

The purpose of crucible scale testing with actual radioactive Tank 48H material was to duplicate the test results that had been previously performed on simulant Tank 48H material. The earlier crucible scale testing using simulants was successful in demonstrating that bench scale crucible tests produce results that are indicative of actual Fluidized Bed Steam Reforming (FBSR) pilot scale tests. Thus, comparison of the results using radioactive Tank 48H feed to those reported earlier with simulants would then provide proof that the radioactive tank waste behaves in a similar manner to the simulant. Demonstration of similar behavior for the actual radioactive Tank 48H slurry to the simulant is important as a preliminary or preparation step for the more complex bench-scale steam reformer unit that is planned for radioactive application in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF) later in 2008. The goals of this crucible-scale testing were to show 99% destruction of tetraphenylborate and to demonstrate that the final solid product produced is sodium carbonate. Testing protocol was repeated using the specifications of earlier simulant crucible scale testing, that is sealed high purity alumina crucibles containing a pre-carbonated and evaporated Tank 48H material. Sealing of the crucibles was accomplished by using an inorganic 'nepheline' sealant. The sealed crucibles were heat-treated at 650 C under constant argon flow to inert the system. Final product REDOX measurements were performed to establish the REDuction/OXidation (REDOX) state of known amounts of added iron species in the final product. These REDOX measurements confirm the processing conditions (pyrolysis occurring at low oxygen fugacity) of the sealed crucible environment which is the environment actually achieved in the fluidized bed steam reformer process. Solid product dissolution in water was used to measure soluble cations and anions, and to investigate insoluble fractions of the product solids. Radioanalytical measurements were performed on the Tank 48H feed material and on the dissolved products in order to estimate retention of Cs-137 in the process. All aspects of prior crucible scale testing with simulant Tank 48H slurry were demonstrated to be repeatable with the actual radioactive feed. Tetraphenylborate destruction was shown to be >99% and the final solid product is sodium carbonate crystalline material. Less than 10 wt% of the final solid products are insoluble components comprised of Fe/Ni/Cr/Mn containing sludge components and Ti from monosodium titanate present in Tank 48H. REDOX measurements on the radioactive solid products indicate a reducing atmosphere with extremely low oxygen fugacity--evidence that the sealed crucible tests performed in the presence of a reductant (sugar) under constant argon purge were successful in duplicating the pyrolysis reactions occurring with the Tank 48H feed. Soluble anion measurements confirm that using sugar as reductant at 1X stoichiometry was successful in destroying nitrate/nitrite in the Tank 48H feed. Radioanalytical measurements indicate that {approx}75% of the starting Cs-137 is retained in the solid product. No attempts were made to analyze/measure other potential Cs-137 in the process, i.e., as possible volatile components on the inner surface of the alumina crucible/lid or as offgas escaping the sealed crucible. The collective results from these crucible scale tests on radioactive material are in good agreement with simulant testing. Crucible scale processing has been shown to duplicate the complex reactions of an actual fluidized bed steam reformer. Thus this current testing should provide a high degree of confidence that upcoming bench-scale steam reforming with radioactive Tank 48H slurry will be successful in tetraphenylborate destruction and production of sodium carbonate product.

Hammond, C; William Pepper, W

2008-09-19T23:59:59.000Z

16

Applications of solar reforming technology  

DOE Green Energy (OSTI)

Research in recent years has demonstrated the efficient use of solar thermal energy for driving endothermic chemical reforming reactions in which hydrocarbons are reacted to form synthesis gas (syngas). Closed-loop reforming/methanation systems can be used for storage and transport of process heat and for short-term storage for peaking power generation. Open-loop systems can be used for direct fuel production; for production of syngas feedstock for further processing to specialty chemicals and plastics and bulk ammonia, hydrogen, and liquid fuels; and directly for industrial processes such as iron ore reduction. In addition, reforming of organic chemical wastes and hazardous materials can be accomplished using the high-efficiency destruction capabilities of steam reforming. To help identify the most promising areas for future development of this technology, we discuss in this paper the economics and market potential of these applications.

Spiewak, I. [Weizmann Inst. of Science, Rehovoth (Israel); Tyner, C.E. [Sandia National Labs., Albuquerque, NM (United States); Langnickel, U. [Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V. (DLR), Koeln (Germany)

1993-11-01T23:59:59.000Z

17

STEAM REFORMING TECHNOLOGY DEMONSTRATION FOR THE DESTRUCTION OF ORGANICS ON ACTUAL DOE SAVANNAH RIVER SITE TANK 48H WASTE 9138  

SciTech Connect

This paper describes the design of the Bench-scale Steam Reformer (BSR); a processing unit for demonstrating steam reforming technology on actual radioactive waste [1]. It describes the operating conditions of the unit used for processing a sample of Savannah River Site (SRS) Tank 48H waste. Finally, it compares the results from processing the actual waste in the BSR to processing simulant waste in the BSR to processing simulant waste in a large pilot scale unit, the Fluidized Bed Steam Reformer (FBSR), operated at Hazen Research Inc. in Golden, CO. The purpose of this work was to prove that the actual waste reacted in the same manner as the simulant waste in order to validate the work performed in the pilot scale unit which could only use simulant waste.

Burket, P

2009-02-24T23:59:59.000Z

18

Steam Reforming, 6-in. Bench-Scale Design and Testing Project -- Technical and Functional Requirements Description  

SciTech Connect

Feasibility studies and technology development work are currently being performed on several processes to treat radioactive liquids and solids currently stored at the Idaho Nuclear Technology and Engineering Center (INTEC), located within the Idaho National Engineering and Environmental Laboratory (INEEL). These studies and development work will be used to select a treatment process for treatment of the radioactive liquids and solids to meet treatment milestones of the Settlement Agreement between the Department of Energy and the State of Idaho. One process under consideration for treating the radioactive liquids and solids, specifically Sodium-Bearing Waste (SBW) and tank heel solids, is fluid bed steam reforming (FBSR). To support both feasibility and development studies a bench-scale FBSR is being designed and constructed. This report presents the technical and functional requirements, experimental objectives, process flow sheets, and equipment specifications for the bench-scale FBSR.

Losinski, Sylvester John; Marshall, Douglas William

2002-08-01T23:59:59.000Z

19

BENCH-SCALE STEAM REFORMING OF ACTUAL TANK 48H WASTE  

Science Conference Proceedings (OSTI)

Fluidized Bed Steam Reforming (FBSR) has been demonstrated to be a viable technology to remove >99% of the organics from Tank 48H simulant, to remove >99% of the nitrate/nitrite from Tank 48H simulant, and to form a solid product that is primarily carbonate based. The technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration Fluidized Bed Steam Reformer1 (ESTD FBSR) at the Hazen Research Inc. (HRI) facility in Golden, CO. The purpose of the Bench-scale Steam Reformer (BSR) testing was to demonstrate that the same reactions occur and the same product is formed when steam reforming actual radioactive Tank 48H waste. The approach used in the current study was to test the BSR with the same Tank 48H simulant and same Erwin coal as was used at the ESTD FBSR under the same operating conditions. This comparison would allow verification that the same chemical reactions occur in both the BSR and ESTD FBSR. Then, actual radioactive Tank 48H material would be steam reformed in the BSR to verify that the actual tank 48H sample reacts the same way chemically as the simulant Tank 48H material. The conclusions from the BSR study and comparison to the ESTD FBSR are the following: (1) A Bench-scale Steam Reforming (BSR) unit was successfully designed and built that: (a) Emulated the chemistry of the ESTD FBSR Denitration Mineralization Reformer (DMR) and Carbon Reduction Reformer (CRR) known collectively as the dual reformer flowsheet. (b) Measured and controlled the off-gas stream. (c) Processed real (radioactive) Tank 48H waste. (d) Met the standards and specifications for radiological testing in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF). (2) Three runs with radioactive Tank 48H material were performed. (3) The Tetraphenylborate (TPB) was destroyed to > 99% for all radioactive Bench-scale tests. (4) The feed nitrate/nitrite was destroyed to >99% for all radioactive BSR tests the same as the ESTD FBSR. (5) The radioactive Tank 48H DMR product was primarily made up of soluble carbonates. The three most abundant species were thermonatrite, [Na{sub 2}CO{sub 3} {center_dot} H{sub 2}O], sodium carbonate, [Na{sub 2}CO{sub 3}], and trona, [Na{sub 3}H(CO{sub 3}){sub 2} {center_dot} 2H{sub 2}O] the same as the ESTD FBSR. (6) Insoluble solids analyzed by X-Ray Diffraction (XRD) did not detect insoluble carbonate species. However, they still may be present at levels below 2 wt%, the sensitivity of the XRD methodology. Insoluble solids XRD characterization indicated that various Fe/Ni/Cr/Mn phases are present. These crystalline phases are associated with the insoluble sludge components of Tank 48H slurry and impurities in the Erwin coal ash. The percent insoluble solids, which mainly consist of un-burnt coal and coal ash, in the products were 4 to 11 wt% for the radioactive runs. (7) The Fe{sup +2}/Fe{sub total} REDOX measurements ranged from 0.58 to 1 for the three radioactive Bench-scale tests. REDOX measurements > 0.5 showed a reducing atmosphere was maintained in the DMR indicating that pyrolysis was occurring. (8) Greater than 90% of the radioactivity was captured in the product for all three runs. (9) The collective results from the FBSR simulant tests and the BSR simulant tests indicate that the same chemistry occurs in the two reactors. (10) The collective results from the BSR simulant runs and the BSR radioactive waste runs indicates that the same chemistry occurs in the simulant as in the real waste. The FBSR technology has been proven to destroy the organics and nitrates in the Tank 48H waste and form the anticipated solid carbonate phases as expected.

Burket, P; Gene Daniel, G; Charles Nash, C; Carol Jantzen, C; Michael Williams, M

2008-09-25T23:59:59.000Z

20

Technology Development for Nuclear Waste Stabilization II  

Science Conference Proceedings (OSTI)

Oct 10, 2012... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity ... A total of 8 sludge batches have been processed through the DWPF ...

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Fluidized Bed Steam Reforming Technology Overview  

Coal added as reductant and for energy • What happens inside the reformer? Water evaporates Nitrates reduced to nitrogen gas

22

Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hanford Low Activity Waste (LAW) Fluidized Bed Steam Reformer (FBSR) Na-Al-Si (NAS) Waste Form Qualification C.M. Jantzen and E.M. Pierce November 18, 2010 2 Participating...

23

Fractionation of reformate: A new variant of gasoline production technology  

Science Conference Proceedings (OSTI)

The Novo-Ufa Petroleum Refinery is the largest domestic producer of the unique high-octane unleaded automotive gasolines AI-93 and AI-95 and the aviation gasolines B-91/115 and B-92. The base component for these gasolines is obtained by catalytic reforming of wide-cut naphtha; this basic component is usually blended with certain other components that are expensive and in short supply: toluene, xylenes, and alkylate. For example, the unleaded gasoline AI-93 has been prepared by blending reformate, alkylate, and toluene in a 65:20:15 weight ratio; AI-95 gasoline by blending alkylate and xylenes in an 80:20 weight ratio; and B-91/115 gasoline by compounding a reformate obtained with light straight-run feed, plus alkylate and toluene, in a 55:35:10 weight ratio. Toluene and xylenes have been obtained by process schemes that include the following consecutive processes: redistillation of straight-run naphtha cuts to segregate the required narrow fraction; catalytic reforming (Platforming) of the narrow toluene-xylene straight-run fraction; azeotropic distillation of the reformate to recover toluene and xylenes. A new technology based on the use of reformate fractions is proposed.

Karakuts, V.N.; Tanatarov, M.A.; Telyashev, G.G. [and others

1995-07-01T23:59:59.000Z

24

Communications Technology and Urban Governance Reform: Project Highlights  

E-Print Network (OSTI)

In this paper, we describe highlights of a research project funded by the NSF Digital Government program. The study has examined the impacts of advanced communication technologies in the implementation of a system of neighborhood councils in Los Angeles. It employs social network analysis to chart the development of political networks engendered by the reform and the role of email in shaping these networks.

Christopher Weare

2005-01-01T23:59:59.000Z

25

Microchannel Process Technology for Compact Methane Steam Reforming  

Science Conference Proceedings (OSTI)

The study of microchannel reaction engineering and applications to compact chemical reactors has expanded rapidly both academically and industrially in recent years. Velocys{reg_sign}, a spin-out company from Battelle Memorial Institute, is commercializing microchannel process technology for large-scale chemical processing. Hydrogen production at industrial rates in compact Velocys hardware is made possible through increases in both heat and mass transfer rates for highly active and novel catalysts. In one example, a microchannel methane steam reforming reactor is presented with integrated catalytic partial oxidation of methane prior to catalytic combustion with low excess air (25%) to generate the required energy for undothermic methane steam reforming in adjacent channels. Heat transfer rates from the exothermic reactions exceed 18 W/cm{sup 2} of interplanar heat transfer surface area and exceed 65 W/cm{sup 3} of total reaction volume for a methane steam reforming contact time near 4 milliseconds. The process intensity of the Velocys methane steam reformer well exceeds that of conventional steam reformers, which have a typical volumetric heat flux below 1 W/cm{sup 3}. The integration of multiple unit operations and improvements in process intensification result in significant capital and operating cost savings for commercial applications.

Tonkovich, A L.; Perry, Steve; Wang, Yong; Qiu, Dongming; LaPlante, Timothy J.; Rogers, William A.

2004-12-01T23:59:59.000Z

26

Steam Reforming Technology Demonstration for Conversion of DOE Sodium-Bearing Tank Wastes at Idaho National Laboratory into a Leach-Resistant Alkali Aluminosilicate Waste Form  

Science Conference Proceedings (OSTI)

The patented THOR{sup R} fluidized-bed steam reforming (FBSR) technology was selected by the U.S. Department of Energy (DOE) for treatment of sodium-bearing waste (SBW) in the Integrated Waste Treatment Unit (IWTU), currently under construction at the Idaho National Laboratory (INL) Site.1 SBW is an acidic waste created primarily from cleanup of the fuel reprocessing equipment at the Idaho Nuclear Technology and Engineering Center (INTEC) at the INL. The SBW contains high concentrations of nitric acid, and alkali and aluminum nitrates, along with many other inorganic compounds, including substantial levels of radionuclides. As part of the implementation of the THOR{sup R} process at INTEC, an engineering-scale technology demonstration (ESTD) was conducted using a specially designed pilot plant located at Hazen Research, Inc. in Golden Colorado. This ESTD confirmed the efficacy of the THOR{sup R} FBSR process to convert the SBW into a granular carbonate-based waste form suitable for disposal at the Waste Isolation Pilot Plant (WIPP). DOE authorized, as a risk reduction measure, the performance of an additional ESTD to demonstrate the production of an insoluble mineralized product, in the event that an alternate disposition path is required. The additional ESTD was conducted at the Hazen Research facility using the THOR{sup R} process and the same SBW simulant employed previously. An alkali aluminosilicate mineral product was produced that exhibited excellent leach resistance and chemical durability. The demonstration established general system operating parameters for a full-scale facility; provided process off-gas data that confirmed operation within regulatory limits; determined that the mineralized product exhibits superior leach resistance and durability, compared to Environmental Assessment (EA) and Low-activity Reference Material (LRM) glasses, as indicated by the Product Consistency Test (PCT); ascertained that Cs and Re (a surrogate for Tc) were non-volatile and were retained in the mineral product; and showed that heavy metals were converted into mineral forms that were not leachable, as determined by the Toxicity Characteristic Leaching Procedure (TCLP) test. (authors)

Ryan, K.; Bradley Mason, J.; Evans, B.; Vora, V. [THOR Treatment Technologies, LLC, Aiken, SC (United States); Olson, A. [CH2M-WG Idaho, LLC, Idaho Falls, ID (United States)

2008-07-01T23:59:59.000Z

27

EM Engineering & Technology Roadmap and Major Technology Demonstration...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

LLC proprietary FBSR technology (currently under construction for treatment of sodium bearing waste in Idaho) to process early LAW and future WTP recycle streams and to...

28

DATA QUALITY OBJECTIVES FOR SELECTING WASTE SAMPLES FOR THE BENCH STEAM REFORMER TEST  

SciTech Connect

This document describes the data quality objectives to select archived samples located at the 222-S Laboratory for Fluid Bed Steam Reformer testing. The type, quantity and quality of the data required to select the samples for Fluid Bed Steam Reformer testing are discussed. In order to maximize the efficiency and minimize the time to treat Hanford tank waste in the Waste Treatment and Immobilization Plant, additional treatment processes may be required. One of the potential treatment processes is the fluid bed steam reformer (FBSR). A determination of the adequacy of the FBSR process to treat Hanford tank waste is required. The initial step in determining the adequacy of the FBSR process is to select archived waste samples from the 222-S Laboratory that will be used to test the FBSR process. Analyses of the selected samples will be required to confirm the samples meet the testing criteria.

BANNING DL

2010-08-03T23:59:59.000Z

29

Technology Maturation Plans (TMPs) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Tank Waste and Waste Processing » Tank Waste and Waste Processing » Technology Maturation Plans (TMPs) Technology Maturation Plans (TMPs) Documents Available for Download November 1, 2007 Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP) This assessment determines the technology maturity level of the candidate Tank 48H treatment technologies that are being considered for implementation at DOE's SRS - specifically Fluidized Bed Steam Reformer System. November 1, 2007 Technology Maturation Plan (TMP) Wet Air Oxidation (WAO) Technology for Tank 48H Treatment Project (TTP) This assessment determines the technology maturity level of the candidate Tank 48H treatment technologies that are being considered for implementation at DOE's SRS - specifically Wet Air Oxidation.

30

Preparation and initial characterization of fluidized bed steam reforming pure-phase standards  

SciTech Connect

Hanford is investigating the Fluidized Bed Steam Reforming (FBSR) process for their Low Activity Waste. The FBSR process offers a low-temperature continuous method by which liquid waste can be processed with the addition of clay into a sodium aluminosilicate (NAS) waste form. The NAS waste form is mainly comprised of nepheline (NaAlSiO{sub 4}), sodalite (Na{sub 8}[AlSiO{sub 4}]{sub 6}Cl{sub 2}), and nosean (Na{sub 8}[AlSiO{sub 4}]{sub 6}SO{sub 4}). Anions such as perrhenate (ReO{sub 4}{sup -}), pertechnetate (TcO{sub 4}{sup -}), and iodine (I{sup -}) are expected to replace sulfate in the nosean structure and/or chloride in the sodalite mineral structure (atomically bonded inside the aluminosilicate cages that these mineral structures possess). In the FBSR waste form, each of these phases can exist in a variety of solid solutions that differ from the idealized forms observed in single crystals in nature. The lack of understanding of the durability of these stoichiometric or idealized mineral phases complicates the ability to deconvolute the durability of the mixed phase FBSR product since it is a combination of different NAS phases. To better understand the behavior, fabrication and testing of the individual phases of the FBSR product is required. Analytical Development (AD) of the Science and Technology directorate of the Savannah River National Laboratory (SRNL) was requested to prepare the series of phase-pure standards, consisting of nepheline, nosean, and Cl, Re, and I sodalite. Once prepared, X-ray Diffraction (XRD) analyses were used to confirm the products were phase pure. These standards are being used for subsequent characterization studies consisting of the following: single-pass flow-through (SPFT) testing, development of thermodynamic data, and x-ray diffraction (XRD) calibration curves. In addition to the above mentioned phase-pure standards, AD was tasked with fabricating a mixed Tc-Re sodalite.

Missimer, D. M.; Rutherford, R. L.

2013-03-21T23:59:59.000Z

31

Catalytic Reforming  

Science Conference Proceedings (OSTI)

Don Little's Catalytic Reforming deals exclusively with reforming. With the increasing need for unleaded gasoline, the importance of this volume has escalated since it combines various related aspects of reforming technology into a single publication. For those with no practical knowledge of catalytic reforming, the chemical reactions, flow schemes and how the cat reformer fits into the overall refinery process will be of interest. Contents include: Catalytic reforming in refinery processing: How catalytic reformers work - chemical reactions; Process design; The catalyst, process variables and unit operation; Commercial processes; BTX operation; Feed preparation; naphtha hydrotreating and catalytic reforming; Index.

Little, D.M.

1985-01-01T23:59:59.000Z

32

RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE BY FLUIDIZED BED STEAM REFORMING USING THE BENCH SCALE REFORMER PLATFORM  

Science Conference Proceedings (OSTI)

The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750 C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage, but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the SRNL to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. BSR testing with WTP SW waste surrogates and associated analytical analyses and tests of granular products (GP) and monoliths began in the Fall of 2009, and then was continued from the Fall of 2010 through the Spring of 2011. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of {sup 125/129}I and {sup 99}Tc to chemically resemble WTP-SW. Prior to these radioactive feed tests, non-radioactive simulants were also processed. Ninety six grams of radioactive granular product were made for testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

Crawford, C.; Burket, P.; Cozzi, A.; Daniel, W.; Jantzen, C.; Missimer, D.

2012-02-02T23:59:59.000Z

33

HYDROGEN GENERATION FROM PLASMATRON REFORMERS: A PROMISING TECHNOLOGY FOR NOX ADSORBER REGENERATION AND OTHER AUTOMOTIVE APPLICATIONS  

DOE Green Energy (OSTI)

Plasmatron reformers are being developed at MIT and ArvinMeritor [1]. In these reformers a special low power electrical discharge is used to promote partial oxidation conversion of hydrocarbon fuels into hydrogen and CO. The partial oxidation reaction of this very fuel rich mixture is difficult to initiate. The plasmatron provides continuous enhanced volume initiation. To minimize electrode erosion and electrical power requirements, a low current, high voltage discharge with wide area electrodes is used. The reformers operate at or slightly above atmospheric pressure. Plasmatron reformers provide the advantages of rapid startup and transient response; efficient conversion of the fuel to hydrogen rich gas; compact size; relaxation or elimination of reformer catalyst requirements; and capability to process difficult to reform fuels, such as diesel and bio-oils. These advantages facilitate use of onboard hydrogen-generation technology for diesel exhaust after-treatment. Plasma-enhanced reformer technology can provide substantial conversion even without the use of a catalyst. Recent progress includes a substantial decrease in electrical power consumption (to about 200 W), increased flow rate (above 1 g/s of diesel fuel corresponding to approximately 40 kW of chemical energy), soot suppression and improvements in other operational features.. Plasmatron reformer technology has been evaluated for regeneration of NOx adsorber after-treatment systems. At ArvinMeritor tests were performed on a dual-leg NOx adsorber system using a Cummins 8.3L diesel engine both in a test cell and on a vehicle. A NOx adsorber system was tested using the plasmatron reformer as a regenerator and without the reformer i.e., with straight diesel fuel based regeneration as the baseline case. The plasmatron reformer was shown to improve NOx regeneration significantly compared to the baseline diesel case. The net result of these initial tests was a significant decrease in fuel penalty, roughly 50% at moderate adsorber temperatures. This fuel penalty improvement is accompanied by a dramatic drop in slipped hydrocarbon emissions, which decreased by 90% or more. Significant advantages are demonstrated across a wide range of engine conditions and temperatures. The study also indicated the potential to regenerate NOx adsorbers at low temperatures where diesel fuel based regeneration is not effective, such as those typical of idle conditions. Two vehicles, a bus and a light duty truck, have been equipped for plasmatron reformer NOx adsorber regeneration tests.

Bromberg, L.; Crane, S; Rabinovich, A.; Kong, Y; Cohn, D; Heywood, J; Alexeev, N.; Samokhin, A.

2003-08-24T23:59:59.000Z

34

The Advanced Technology Program: Reform with a Purpose  

Science Conference Proceedings (OSTI)

... In fact, Dr. Steven Price, Director of University-Industry Relations at the ... For example, Department of Energy's Clean Coal Technology Program has ...

2011-10-19T23:59:59.000Z

35

Novel Catalytic Fuel Reforming Using Micro-Technology with Advanced Separations Technology  

E-Print Network (OSTI)

by the combustion of membrane raffinate for the production of clean hydrogen by steam reforming natural gas primary fuel sources from existing production and distribution networks ­ i.e. natural gas, gasoline gas -- optimize catalyst composition and evaluate reforming conditions. · Hydrogen purification using

36

Development of internal reforming carbonate fuel cell stack technology  

DOE Green Energy (OSTI)

Activities under this contract focused on the development of a coal-fueled carbonate fuel cell system design and the stack technology consistent with the system design. The overall contract effort was divided into three phases. The first phase, completed in January 1988, provided carbonate fuel cell component scale-up from the 1ft{sup 2} size to the commercial 4ft{sup 2} size. The second phase of the program provided the coal-fueled carbonate fuel cell system (CGCFC) conceptual design and carried out initial research and development needs of the CGCFC system. The final phase of the program emphasized stack height scale-up and improvement of stack life. The results of the second and third phases are included in this report. Program activities under Phase 2 and 3 were designed to address several key development areas to prepare the carbonate fuel cell system, particularly the coal-fueled CFC power plant, for commercialization in late 1990's. The issues addressed include: Coal-Gas Related Considerations; Cell and Stack Technology Improvement; Carbonate Fuel Cell Stack Design Development; Stack Tests for Design Verification; Full-Size Stack Design; Test Facility Development; Carbonate Fuel Cell Stack Cost Assessment; and Coal-Fueled Carbonate Fuel Cell System Design. All the major program objectives in each of the topical areas were successfully achieved. This report is organized along the above-mentioned topical areas. Each topical area has been processed separately for inclusion on the data base.

Farooque, M.

1990-10-01T23:59:59.000Z

37

Steam Reforming Application for Treatment of DOE Sodium Bearing Tank Wastes at Idaho National Laboratory for Idaho Cleanup Project  

SciTech Connect

The patented THOR{sup R} steam reforming waste treatment technology has been selected by the Department of Energy (DOE) as the technology of choice for treatment of about one million gallons of Sodium Bearing Waste (SBW) at the Idaho National Laboratory (INL). SBW is an acidic waste created primarily from cleanup of the fuel reprocessing equipment at the Idaho Nuclear Technology and Engineering Center (INTEC) at the INL. SBW contains high concentrations of nitric acid and alkali and aluminum nitrates with minor amounts of many inorganic compounds including radionuclides, mainly cesium. The steam reforming process will convert the SBW into dry, solid, carbonate and aluminate minerals supporting a preferred path for disposal as remote handled transuranic (RH-TRU) waste at the Waste Isolation Pilot Project (WIPP). The Idaho Cleanup Project (ICP) will design, build, and operate an Integrated Waste Treatment Unit (IWTU) that will comprise an integrated THOR{sup R} process system that will utilize dual fluidized bed steam reformers (FBSR) for treatment of the SBW. Design of the IWTU is nearing completion. The IWTU will be constructed at INTEC, immediately east of the New Waste Calcine Facility (NWCF), with planned fabrication and construction to start in early 2007 upon receipt of needed permits and completion of design and engineering. This paper provides a project and process overview of the IWTU and discusses the design and construction status. IWTU equipment and facility designs and bases will be presented. (authors)

Landman, W.; Roesener, S. [CH2M WG Idaho, LLC, Idaho Falls, ID (United States); Mason, B.; Wolf, K.; Amaria, N. [THOR Treatment Technologies, LLC, Aiken, SC (United States)

2007-07-01T23:59:59.000Z

38

Fluidized Bed Steam Reformer (FBSR) Na-Al-Si (NAS) Waste Form ...  

Clay/Coal Superheated Steam (pyrolizes organics and catalyzes mineralization) CO2, N2, H2O CRR HVAC HTF PBF Feed Tank Sand Filter or Stack DISPOSAL ...

39

RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING AS A SUPPLEMENTARY TREATMENT FOR HANFORD'S LOW ACTIVITY WASTE AND SECONDARY WASTES  

SciTech Connect

The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP's LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as Cs-137, I-129, Tc-99, Cl, F, and SO4 that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap. The current waste disposal path for the WTP-SW is to recycle it to the supplemental LAW treatment to avoid a large steady state accumulation in the pretreatment-vitrification loop. Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750 C) continuous method by which LAW and/or WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the Savannah River National Laboratory (SRNL) to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of I-125/129 and Tc-99 to chemically resemble WTP-SW. Ninety six grams of radioactive product were made for testing. The second campaign commenced using SRS LAW chemically trimmed to look like Hanford's LAW. Six hundred grams of radioactive product were made for extensive testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

Jantzen, C.; Crawford, C.; Cozzi, A.; Bannochie, C.; Burket, P.; Daniel, G.

2011-02-24T23:59:59.000Z

40

FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING  

SciTech Connect

Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO{sub 4}, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

2006-12-06T23:59:59.000Z

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

FLUIDIZED BED STEAM REFORMED MINERAL WASTE FORMS: CHARACTERIZATION AND DURABILITY TESTING  

SciTech Connect

Fluidized Bed Steam Reforming (FBSR) is being considered as a potential technology for the immobilization of a wide variety of high sodium low activity wastes (LAW) such as those existing at the Hanford site, at the Idaho National Laboratory (INL), and the Savannah River Site (SRS). The addition of clay, charcoal, and a catalyst as co-reactants with the waste denitrates the aqueous wastes and forms a granular mineral waste form that can subsequently be made into a monolith for disposal if necessary. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage and ring structures and iron bearing spinel minerals. The mineralization occurs at moderate temperatures between 650-750 C in the presence of superheated steam. The cage and ring structured feldspathoid minerals atomically bond radionuclides like Tc-99 and Cs-137 and anions such as SO4, I, F, and Cl. The spinel minerals stabilize Resource Conservation and Recovery Act (RCRA) hazardous species such as Cr and Ni. Granular mineral waste forms were made from (1) a basic Hanford Envelope A low-activity waste (LAW) simulant and (2) an acidic INL simulant commonly referred to as sodium bearing waste (SBW) in pilot scale facilities at the Science Applications International Corporation (SAIC) Science and Technology Applications Research (STAR) facility in Idaho Falls, ID. The FBSR waste forms were characterized and the durability tested via ASTM C1285 (Product Consistency Test), the Environmental Protection Agency (EPA) Toxic Characteristic Leaching Procedure (TCLP), and the Single Pass Flow Through (SPFT) test. The results of the SPFT testing and the activation energies for dissolution are discussed in this study.

Jantzen, C; Troy Lorier, T; John Pareizs, J; James Marra, J

2007-03-31T23:59:59.000Z

42

Fluidized Bed Steam Reforming of INEEL SBW Using THORsm Mineralizing Technology  

SciTech Connect

Sodium bearing waste (SBW) disposition is one of the U.S. Department of Energy (DOE) Idaho Operation Office’s (NE-ID) and State of Idaho’s top priorities at the Idaho National Engineering and Environmental Laboratory (INEEL). Many studies have resulted in the identification of five treatment alternatives that form a short list of perhaps the most appropriate technologies for the DOE to select from. The alternatives are (a) calcination with maximum achievable control technology (MACT) upgrade, (b) steam reforming, (c) cesium ion exchange (CsIX) with immobilization, (d) direct evaporation, and (e) vitrification. Each alternative has undergone some degree of applied technical development and preliminary process design over the past four years. DOE desired further experimental data, with regard to steam reforming technology, to make informed decisions concerning selection of treatment technology for SBW. Mineralizing steam reforming technology, offered by THOR Treatment Technologies, LLC would produce a denitrated, granular mineral waste form using a high-temperature fluidized bed process. A pilot scale demonstration of the technology was performed in a 15-cm-diameter reactor vessel September 27 through October 1, 2004. The pilot scale equipment is owned by the DOE, and located at the Science and Technology Applications Research (STAR) Center in Idaho Falls, ID. Flowsheet chemistry and operational parameters were defined through a collaborative effort involving Idaho National Engineering and Environmental Laboratory, Savannah River National Laboratory (SRNL), and THOR Treatment Technologies personnel. Personnel from Science Applications International Corporation, owners of the STAR Center, operated the pilot plant. The pilot scale test was terminated as planned after achieving a total of 100 hrs of cumulative/continuous processing operation. About 230 kg of SBW surrogate were processed that resulted in about 88 kg of solid product, a mass reduction of about 62%. The process achieved about a 90% turnover of the starting bed. Samples of mineralized solid product materials were analyzed for chemical/physical properties. Results of product performance testing conducted by SRNL will be reported separately by SRNL.

Arlin L. Olson; Nicholas R. Soelberg; Douglas W. Marshall; Gary L. Anderson

2004-12-01T23:59:59.000Z

43

Fishman, B., Pinkard, N., & Bruce, C. (1998). Preparing schools for curricular reform: Planning for Technology vs. Technology Planning. In A. Bruckman, M. Guzdial, J. Kolodner, & A. Ram (Eds.), International Conference on the  

E-Print Network (OSTI)

Fishman, B., Pinkard, N., & Bruce, C. (1998). Preparing schools for curricular reform: Planning for Technology vs. Technology Planning. In A. Bruckman, M. Guzdial, J. Kolodner, & A. Ram (Eds.), International for Curricular Reform: Planning for Technology vs. Technology Planning Barry Fishman, Nichole Pinkard, Chris

Fishman, Barry

44

Fluidized Bed Steam Reforming of Hanford LAW Using THORsm Mineralizing Technology  

SciTech Connect

The U.S. Department of Energy (DOE) documented, in 2002, a plan for accelerating cleanup of the Hanford Site, located in southeastern Washington State, by at least 35 years. A key element of the plan was acceleration of the tank waste program and completion of ''tank waste treatment by 2028 by increasing the capacity of the planned Waste Treatment Plant (WTP) and using supplemental technologies for waste treatment and immobilization.'' The plan identified steam reforming technology as a candidate for supplemental treatment of as much as 70% of the low-activity waste (LAW). Mineralizing steam reforming technology, offered by THOR Treatment Technologies, LLC would produce a denitrated, granular mineral waste form using a high-temperature fluidized bed process. A pilot scale demonstration of the technology was completed in a 15-cm-diameter reactor vessel. The pilot scale facility was equipped with a highly efficient cyclone separator and heated sintered metal filters for particulate removal, a thermal oxidizer for reduced gas species and NOx destruction, and a packed activated carbon bed for residual volatile species capture. The pilot scale equipment is owned by the DOE, but located at the Science and Technology Applications Research (STAR) Center in Idaho Falls, ID. Pilot scale testing was performed August 2–5, 2004. Flowsheet chemistry and operational parameters were defined through a collaborative effort involving Idaho National Engineering and Environmental Laboratory, Savannah River National Laboratory (SRNL), and THOR Treatment Technologies personnel. Science Application International Corporation, owners of the STAR Center, personnel performed actual pilot scale operation. The pilot scale test achieved a total of 68.7 hrs of cumulative/continuous processing operation before termination in response to a bed de-fluidization condition. 178 kg of LAW surrogate were processed that resulted in 148 kg of solid product, a mass reduction of about 17%. The process achieved essentially complete bed turnover within approximately 40 hours. Samples of mineralized solid product materials were analyzed for chemical/physical properties. SRNL will report separately the results of product performance testing that were accomplished.

Olson, Arlin L.; Nicholas R Soelberg; Douglas W. Marshall; Gary L. Anderson

2004-11-01T23:59:59.000Z

45

--No Title--  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

A mixed waste treatability study will be performed to test the fluidized bed steam reforming (FBSR) technology on SRS Low Activity Waste (LAW) modified to simulate Hanford waste....

46

Multi-fuel reformers for fuel cells used in transportation: Assessment of hydrogen storage technologies. Phase 1, Final report  

DOE Green Energy (OSTI)

This report documents a portion of the work performed Multi-fuel Reformers for Fuel Cells Used in Transportation. One objective for development is to develop advanced fuel processing systems to reform methanol, ethanol, natural gas, and other hydrocarbons into hydrogen for use in transportation fuel cell systems, while a second objective is to develop better systems for on-board hydrogen storage. This report examines techniques and technology available for storage of pure hydrogen on board a vehicle as pure hydrogen of hydrides. The report focuses separately on near- and far-term technologies, with particular emphasis on the former. Development of lighter, more compact near-term storage systems is recommended to enhance competitiveness and simplify fuel cell design. The far-term storage technologies require substantial applied research in order to become serious contenders.

Not Available

1994-03-01T23:59:59.000Z

47

Pyrolysis/Steam Reforming Technology for Treatment of TRU Orphan Wastes  

SciTech Connect

Certain transuranic (TRU) waste streams within the Department of Energy (DOE) complex cannot be disposed of at the Waste Isolation Pilot Plant (WIPP) because they do not meet the shipping requirements of the TRUPACT-II or the disposal requirements of the Waste Analysis Plan (WAP) in the WIPP RCRA Part B Permit. These waste streams, referred to as orphan wastes, cannot be shipped or disposed of because they contain one or more prohibited items, such as liquids, volatile organic compounds (VOCs), hydrogen gas, corrosive acids or bases, reactive metals, or high concentrations of polychlorinated biphenyl (PCB), etc. The patented, non-incineration, pyrolysis and steam reforming processes marketed by THOR Treatment Technologies LLC removes all of these prohibited items from drums of TRU waste and produces a dry, inert, inorganic waste material that meets the existing TRUPACT-II requirements for shipping, as well as the existing WAP requirements for disposal of TRU waste at WIPP. THOR Treatment Technologies is a joint venture formed in June 2002 by Studsvik, Inc. (Studsvik) and Westinghouse Government Environmental Services Company LLC (WGES) to further develop and deploy Studsvik's patented THORSM technology within the DOE and Department of Defense (DoD) markets. The THORSM treatment process is a commercially proven system that has treated over 100,000 cu. ft. of nuclear waste from commercial power plants since 1999. Some of this waste has had contact dose rates of up to 400 R/hr. A distinguishing characteristic of the THORSM process for TRU waste treatment is the ability to treat drums of waste without removing the waste contents from the drum. This feature greatly minimizes criticality and contamination issues for processing of plutonium-containing wastes. The novel features described herein are protected by issued and pending patents.

Mason, J. B.; McKibbin, J.; Schmoker, D.; Bacala, P.

2003-02-27T23:59:59.000Z

48

Before the House Oversight and Government Reform Subcommittee...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Information Policy, Intergovernmental Relations, and Procurement Reform Before the House Oversight and Government Reform Subcommittee on Technology, Information Policy,...

49

Steam Reforming Application for Treatment of DOE Sodium-Bearing Tank Wastes at Idaho National Laboratory for Idaho Cleanup Project  

SciTech Connect

The patented THOR{sup R} steam reforming waste treatment technology has been selected by the U.S. Department of Energy (DOE) as the technology of choice for treatment of about one million gallons of sodium-bearing waste (SBW) at the Idaho National Laboratory (INL) Site 1. SBW is an acidic waste created primarily from cleanup of the fuel reprocessing equipment at the Idaho Nuclear Technology and Engineering Center (INTEC) at the INL. SBW contains high concentrations of nitric acid and alkali and aluminum nitrates with minor amounts of many inorganic compounds including radionuclides, mainly cesium. The steam reforming process will convert the SBW into dry, solid, carbonate and aluminate minerals supporting a preferred path for disposal as remote handled transuranic (RH-TRU) waste at the Waste Isolation Pilot Project (WIPP). The Idaho Cleanup Project (ICP) will design, build, and operate an Integrated Waste Treatment Unit (IWTU) that will comprise an integrated THOR{sup R} process system that will utilize dual fluidized bed steam reformers (FBSR) for treatment of the SBW. The IWTU is being constructed at INTEC, immediately east of the New Waste Calcine Facility (NWCF). Detailed design of the IWTU has been completed and DOE has approved the CD-3 detailed design. The State of Idaho has approved the RCRA and construction air permits. Construction of the IWTU started in April 2007 with civil and foundation work. This paper provides a project and process overview of the IWTU and discusses the design and construction status. IWTU equipment and facility designs and bases will be presented. (authors)

Landman, W.; Roesener, S. [CH2M-WG Idaho, LLC, Idaho Falls, ID (United States); Bradley Mason, J.; Bourgeois, T.; Amaria, N. [THOR Treatment Technologies, LLC, Aiken, SC (United States)

2008-07-01T23:59:59.000Z

50

DURABILITY TESTING OF FLUIDIZED BED STEAM REFORMER WASTE FORMS FOR SODIUM BEARING WASTE AT IDAHO NATIONAL LABORATORY  

SciTech Connect

Fluidized Bed Steam Reforming (FBSR) processing of Sodium Bearing Waste simulants was performed in December 2006 by THOR{sup sm} Treatment Technologies LLC (TTT) The testing was performed at the Hazen Research Inc. (HRI) pilot plant facilities in Golden, CO. FBSR products from these pilot tests on simulated waste representative of the SBW at the Idaho Nuclear Technology and Engineering Center (INTEC) were subsequently transferred to the Savannah River National Laboratory (SRNL) for characterization and leach testing. Four as-received Denitration and Mineralization Reformer (DMR) granular/powder samples and four High Temperature Filter (HTF) powder samples were received by SRNL. FBSR DMR samples had been taken from the ''active'' bed, while the HTF samples were the fines collected as carryover from the DMR. The process operated at high fluidizing velocities during the mineralization test such that nearly all of the product collected was from the HTF. Active bed samples were collected from the DMR to monitor bed particle size distribution. Characterization of these crystalline powder samples shows that they are primarily Al, Na and Si, with > 1 wt% Ca, Fe and K. The DMR samples contained less than 1 wt% carbon and the HTF samples ranged from 13 to 26 wt% carbon. X-ray diffraction analyses show that the DMR samples contained significant quantities of the Al{sub 2}O{sub 3} startup bed. The DMR samples became progressively lower in starting bed alumina with major Na/Al/Si crystalline phases (nepheline and sodium aluminosilicate) present as cumulative bed turnover occurred but 100% bed turnover was not achieved. The HTF samples also contained these major crystalline phases. Durability testing of the DMR and HTF samples using the ASTM C1285 Product Consistency Test (PCT) 7-day leach test at 90 C was performed along with several reference glass samples. Comparison of the normalized leach rates for the various DMR and HTF components was made with the reference glasses and the Low Activity Waste (LAW) specification for the Hanford Waste Treatment and Vitrification Plant (WTP). Normalized releases from the DMR and HTF samples were all less than 1 g/m{sup 2}. For comparison, normalized release from the High-Level Waste (HLW) benchmark Environmental Assessment (EA) glass for Si, Li, Na and B ranges from 2 to 8 g/m{sup 2}. The normalized release specification for LAW glass for the Hanford WTP is 2 g/m{sup 2}. The Toxicity Characteristic Leach Test (TCLP) was performed on DMR and HTF as received samples and the tests showed that these products meet the criteria for the EPA RCRA Universal Treatment Standards for all of the constituents contained in the starting simulants such as Cr, Pb and Hg (RCRA characteristically hazardous metals) and Ni and Zn (RCRA metals required for listed wastes).

Crawford, C; Carol Jantzen, C

2007-08-27T23:59:59.000Z

51

Radionuclide and contaminant immobilization in the fluidized bed steam reforming waste products  

Science Conference Proceedings (OSTI)

The goal of this chapter is to introduce the reader to the Fluidized Bed Steam Reforming (FBSR) process and resulting waste form. The first section of the chapter gives an overview of the potential need for FBSR processing in nuclear waste remediation followed by an overview of the engineering involved in the process itself. This is followed by a description of waste form production at a chemical level followed by a section describing different process streams that have undergone the FBSR process. The third section describes the resulting mineral product in terms of phases that are present and the ability of the waste form to encapsulate hazardous and radioactive wastes from several sources. Following this description is a presentation of the physical properties of the granular and monolith waste form product including and contaminant release mechanisms. The last section gives a brief summary of this chapter and includes a section on the strengths associated with this waste form and the needs for additional data and remaining questions yet to be answered. The reader is directed elsewhere for more information on other waste forms such as Cast Stone (Lockrem, 2005), Ceramicrete (Singh et al., 1997, Wagh et al., 1999) and geopolymers (Kyritsis et al., 2009; Russell et al., 2006).

Neeway, James J.; Qafoku, Nikolla; Westsik, Joseph H.; Brown, Christopher F.; Jantzen, Carol; Pierce, Eric M.

2012-05-01T23:59:59.000Z

52

CESIUM REMOVAL FROM TANKS 241-AN-103 & 241-SX-105 & 241-AZ-101 & 241AZ-102 COMPOSITE FOR TESTING IN BENCH SCALE STEAM REFORMER  

SciTech Connect

This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-l0-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannah River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FBSR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-5.2.1-2010-001, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using Hanford Waste Samples.

DUNCAN JB; HUBER HJ

2011-04-21T23:59:59.000Z

53

Faculty Attitude towards Technology-Assisted Instruction for Introductory Statistics in the Context of Educational Reform  

E-Print Network (OSTI)

Boulder, T. (2006). The pedagogy of technology integration.Journal of Technology Studies, 32(2), 66-71. Petherbridge,acceptance of computer based technology: Cross-validation of

Hassad, Rossi A.

2013-01-01T23:59:59.000Z

54

Diesel Reforming for Fuel Cell Auxiliary Power Units  

DOE Green Energy (OSTI)

This objective of this project was to develop technology suitable for onboard reforming of diesel. The approach was to examine catalytic partial oxidation and steam reforming.

Borup, R.; Parkinson, W. J.; Inbody, M.; Brosha, E.L.; Guidry, D.R.

2005-01-27T23:59:59.000Z

55

CESIUM REMOVAL FROM TANKS 241-AN-103 & 241-SX-105 & 241-AZ-101/102 COMPOSITE FOR TESTING IN BENCH SCALE STEAM REFORMER  

SciTech Connect

This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-10-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannah River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FB SR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-S.2.1-20 1 0-00 1, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, 'Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using Hanford Waste Samples.'

DUNCAN JB; HUBER HJ

2011-06-08T23:59:59.000Z

56

REFORMING PROCESSES FOR MICRO COMBINED HEAT AND POWER SYSTEM BASED ON SOLID OXIDE FUEL CELL  

E-Print Network (OSTI)

and energy balance, different types of fuel reforming including steam reforming, autothermal reforming technologies. Steam reforming, partial oxidation and autothermal reforming are the three major fuel of an activated carbon bed. Prior to enter the SOFC stack, the fuel is pre-reformed (methane is partially

Liso, Vincenzo

57

Before the House Oversight and Government Reform Subcommittee on  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Oversight and Government Reform Subcommittee on Oversight and Government Reform Subcommittee on Technology, Information Policy, Intergovernmental Relations, and Procurement Reform Before the House Oversight and Government Reform Subcommittee on Technology, Information Policy, Intergovernmental Relations, and Procurement Reform Before the Subcommittee on Technology, Information Policy, Intergovernmental Relations and Procurement Reform, Committee on Oversight and Government Reform, United States House of Representatives Written Statement By: Owen Barwell, Acting Chief Financial Officer, United States Department of Energy Subject: DOE Financial Information Systems Final_Testimony_for_Owen_Barwell.pdf More Documents & Publications AL2010-03.pdf Request for Information - Operations and Maintenance (O & M) Support

58

--No Title--  

NLE Websites -- All DOE Office Websites (Extended Search)

A mixed waste treatability study will be performed to test the fluidized bed steam reforming (FBSR) technology on two caustic Hanford waste streams (SX-105 and An-103). The tests...

59

Catalytic reforming  

Science Conference Proceedings (OSTI)

This patent describes a process for the catalytic reforming of a feedstock which contains at least one reformable organic compound. The process consists of contacting the feedstock under suitable reforming conditions with a catalyst composition selected from the group consisting of a catalyst. The catalyst essentially consists of zinc oxide and a spinel structure alumina. Another catalyst consists essentially of a physical mixture of zinc titanate and a spinel structure alumina in the presence of sufficient added hydrogen to substantially prevent the formation of coke. Insufficient zinc is present in the catalyst composition for the formation of a bulk zinc aluminate.

Aldag, A.W. Jr.

1986-01-28T23:59:59.000Z

60

EVALUATION OF THOR MINERALIZED WASTE FORMS FOR THE DOE ADVANCED REMEDIATION TECHNOLOGIES PHASE 2 PROJECT  

SciTech Connect

The U.S. Department of Energy's (DOE) Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP's LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). In addition, the WTP LAW Vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as Cs-137, I-129, Tc-99, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap. The current waste disposal path for the WTP-SW is to recycle it to the supplemental LAW treatment to avoid a large steady state accumulation in the pretreatment-vitrification loop. Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750 C) continuous method by which LAW and/or WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product, which is one of the objectives of this current study, is being investigated to prevent dispersion during transport or burial/storage but is not necessary for performance. FBSR testing of a Hanford LAW simulant and a WTP-SW simulant at the pilot scale was performed by THOR Treatment Technologies, LLC at Hazen Research Inc. in April/May 2008. The Hanford LAW simulant was the Rassat 68 tank blend and the target concentrations for the LAW was increased by a factor of 10 for Sb, As, Ag, Cd, and Tl; 100 for Ba and Re (Tc surrogate); 1,000 for I; and 254,902 for Cs based on discussions with the DOE field office and the environmental regulators and an evaluation of the Hanford Tank Waste Envelopes A, B, and C. It was determined through the evaluation of the actual tank waste metals concentrations that some metal levels were not sufficient to achieve reliable detection in the off-gas sampling. Therefore, the identified metals concentrations were increased in the Rassat simulant processed by TTT at HRI to ensure detection and enable calculation of system removal efficiencies, product retention efficiencies, and mass balance closure without regard to potential results of those determinations or impacts on product durability response such as Toxicity Characteristic Leach Procedure (TCLP). A WTP-SW simulant based on melter off-gas analyses from Vitreous State Laboratory (VSL) was also tested at HRI in the 15-inch diameter Engineering Scale Test Demonstration (ESTD) dual reformer at HRI in 2008. The target concentrations for the Resource Conservation and Recovery Act (RCRA) metals were increased by 16X for Se, 29X for Tl, 42X for Ba, 48X for Sb, by 100X for Pb and Ni, 1000X for Ag, and 1297X for Cd to ensure detection by the an

Crawford, C.; Jantzen, C.

2012-02-02T23:59:59.000Z

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Microsoft PowerPoint - 1-07 Mason DOE EM Waste Processing Technology...  

NLE Websites -- All DOE Office Websites (Extended Search)

plants: Studsvik Processing Facility: Ion exchange resins (45" diameter FBSR) DOE Idaho Integrated Waste Treatment Unit: SBW treatment (48" diameter FBSR) DOE...

62

Bio-Derived Liquids to Hydrogen Distributed Reforming Targets (Presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

Distributed Reforming Targets Arlene F. Anderson Technology Development Manager, U.S. DOE Office of Energy Efficiency and Renewable Energy Hydrogen, Fuel Cells and Infrastructure Technologies Program Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group and Hydrogen Production Technical Team Review November 6, 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) The Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG), launched in October 2006, provides a forum for effective communication and collaboration among participants in DOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program (HFCIT) cost-shared research directed at distributed bio-liquid reforming. The Working Group includes

63

Microsoft Word - Poster Abstract_2010_NETL_ Oxide-Based Reforming...  

NLE Websites -- All DOE Office Websites (Extended Search)

Structured Oxide - Based Reforming Catalyst Development U.S. Dept of Energy, National Energy Technology Laboratory, Morgantown, WV 26507 Dushyant Shekhawat Dushyant.Shekhawat@NETL....

64

Fuels Technology - Capabilities - FEERC  

NLE Websites -- All DOE Office Websites (Extended Search)

Research Capabilities Fuels Technology Advanced petroleum-based fuels Fuel-borne reductants On-board reforming Alternative fuels...

65

Multi-fuel reformers for fuel cells used in transportation: Assessment of hydrogen storage technologies. Phase 2: Final report  

DOE Green Energy (OSTI)

During Phase 1 of this program, the authors evaluated all known hydrogen storage technologies (including those that are now practiced and those that are development) in the context of fuel cell vehicles. They determined that among the development technologies, carbon sorbents could most benefit from closer scrutiny. During Phase 2 of this program, they tested ten different carbon sorbents at various practical temperatures and pressures, and developed the concept of the usable Capacity Ratio, which is the ratio of the mass of hydrogen that can be released from a carbon-filled tank to the mass of hydrogen that can be released from an empty tank. The authors also commissioned the design, fabrication, and NGV2 (Natural Gas Vehicle) testing of an aluminum-lined, carbon-composite, full-wrapped pressure vessel to store hydrogen at 78 K and 3,000 psi. They constructed a facility to pressure cycle the tank at 78 K and to temperature cycle the tank at 3,000 psi, tested one such tank, and submitted it for a burst test. Finally, they devised a means by which cryogenic compressed hydrogen gas tanks can be filled and discharged using standard hardware--that is, without using filters, valves, or pressure regulators that must operate at both low temperature and high pressure. This report describes test methods and test results of carbon sorbents and the design of tanks for cold storage. 7 refs., 91 figs., 10 tabs.

NONE

1995-05-01T23:59:59.000Z

66

Methods of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts  

NLE Websites -- All DOE Office Websites (Extended Search)

of Reforming Hydrocarbon Fuels Using of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts Contact NETL Technology Transfer Group techtransfer@netl.doe.gov May 2012 Opportunity Research is currently active on the technology "Methods of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts." The technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview This invention discloses a method to reform hydrocarbon fuels using hexa- aluminate catalysts. In general, the method successfully disrupts the forma- tion of carbon that leads to the deactivation of the catalyst, a key element in the reforming of hydrocarbon fuels. When researchers are designing catalysts to reform hydrocarbon fuels, one

67

Synergize fuel and petrochemical processing plans with catalytic reforming  

Science Conference Proceedings (OSTI)

Depending on the market, refiner`s plans to produce clean fuels and higher value petrochemicals will weigh heavily on the catalytic reformer`s flexibility. It seems that as soon as a timely article related to catalytic reforming operations is published, a new {open_quotes}boutique{close_quotes} gasoline fuel specification is slapped on to existing fuel standards, affecting reformer operations and processing objectives. Just as importantly, the petrochemical market (such as aromatics) that refiners are targeting, can be very fickle. That`s why process engineers have endeavored to maintain an awareness of the flexibility that technology suppliers are building into modern catalytic reformers.

NONE

1997-03-01T23:59:59.000Z

68

WHEC 16 / 13-16 June 2006 Lyon France Plasma assisted fuel reforming for on-board hydrogen rich gas production  

E-Print Network (OSTI)

through hydrogen on-board storage. The main reforming technology is catalytic reforming, which has been points are challenges for automotive applications. In parallel with research on catalytic reforming assisted reforming could be used complementary to catalytic reforming to ensure dynamics performance (start

Paris-Sud XI, Université de

69

Sulfate Volatilization in Simulated Nuclear Waste Glasses  

Science Conference Proceedings (OSTI)

Radioactive Demonstrations of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes · Radionuclide Behavior and Geochemistry in Boom

70

(NaAlSiO4) – Malinkoite (NaBSiO4  

Science Conference Proceedings (OSTI)

Radioactive Demonstrations of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes · Radionuclide Behavior and Geochemistry in Boom

71

Utilizing Oxygen Uptake to Predict Lifetimes of Elastomeric O-rings  

Science Conference Proceedings (OSTI)

Radioactive Demonstrations of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes · Radionuclide Behavior and Geochemistry in Boom

72

Radionuclide Behavior and Geochemistry in Boom Clay after ...  

Science Conference Proceedings (OSTI)

Radioactive Demonstrations of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes · Radionuclide Behavior and Geochemistry in Boom  ...

73

Epsilon Metal Waste Form Development for Fission Products in ...  

Science Conference Proceedings (OSTI)

Radioactive Demonstrations of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes · Radionuclide Behavior and Geochemistry in Boom  ...

74

Multiscale Modeling for Predicting Long-Term Behavior of Glass ...  

Science Conference Proceedings (OSTI)

Radioactive Demonstrations of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes · Radionuclide Behavior and Geochemistry in Boom  ...

75

Adsorbents of Titanate Nanofibers and Nanotubes for the Removal ...  

Science Conference Proceedings (OSTI)

Radioactive Demonstrations of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes · Radionuclide Behavior and Geochemistry in Boom  ...

76

Electrochemical and Thermal Properties of Rare-Earth Chlorides in ...  

Science Conference Proceedings (OSTI)

Radioactive Demonstrations of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes · Radionuclide Behavior and Geochemistry in Boom  ...

77

Before the House Subcommittee on Technology, Information Policy...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

and Procurement Reform of the Committee on Overshigh and Government Reform Before the House Subcommittee on Technology, Information Policy, Intergovernmental Relations and...

78

Process for catalytic reforming  

Science Conference Proceedings (OSTI)

An improved catalytic reforming process is disclosed wherein hydrogen and light hydrocarbons generated in the catalytic reaction zone are passed to a hydrogen production/purification zone and and reacted and processed therein to produce substantially pure hydrogen. A portion of the hydrogen is then admixed with the charge stock to the catalytic reforming zone to provide the hydrogen requirements of the catalytic reforming reaction zone.

James, R. B. Jr.

1984-11-20T23:59:59.000Z

79

Systemic Reform Bibliography  

NLE Websites -- All DOE Office Websites (Extended Search)

(5) support local initiatives and model sites; (6) align state policy; (7) reform higher education and teacher preparation; and (8) mobilize public and professional...

80

Plasma—Methane Reformation  

INL thermal plasma methane reformation process produces hydrogen and elemental carbon from natural gas and other hydrocarbons, such as natural gas or ...

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Catalytic reforming process  

Science Conference Proceedings (OSTI)

A catalytic reforming process is disclosed in which substantially all of the heat requirements of the product stabilizer column is supplied by multiple indirect heat exchange.

Peters, K.D.

1983-10-11T23:59:59.000Z

82

Hydrocarbon Reformers for Fuel Cell Systems  

Science Conference Proceedings (OSTI)

Several new or emerging technologies are vying to compete in the distributed resources market; notably, fuel cells and microturbines. Fuel cells represent an idealized power generation technology with tremendous long-term promise. As a hydrogen-fueled system, however, fuel cells need either a hydrogen fuel supply infrastructure or fuel processing (reforming and clean-up) technology to convert conventional fossil fuels to a hydrogen-rich energy source. This report provides an overview of fuel processing t...

2000-11-30T23:59:59.000Z

83

Security and Suitability Process Reform  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Security and Suitability Process Reform December 2008 Provided by the Joint Security and Suitability Reform Team EXECUTIVE OFFICE OF THE PRESIDENT OFFICE OF MANAGEMENT AND BUDGET...

84

Copyright reform step zero  

Science Conference Proceedings (OSTI)

'A reasonable person might well think it's a fool's errand to contemplate a [copyright] reform project of any sort.' The US Copyright Act of 1976 and its subsequent amendments is contained in over 200 pages of incomprehensible, sometimes inconsistent, ... Keywords: US copyright law, administrative law, copyright reform, institutional frameworks

Terry Hart

2010-06-01T23:59:59.000Z

85

Catalytic reforming process  

Science Conference Proceedings (OSTI)

A catalytic reforming process is disclosed wherein the reboiler heat requirements of the stabilizer column are supplied by means of indirect heat exchange with hot combustion gases in the reforming reactants fired heater convection heating section. Heat in excess of the reboiler requirements is passed to the stabilizer column with control being effected by removal of excess heat from the column.

James, R.B. Jr.

1984-02-14T23:59:59.000Z

86

Catalytic reforming methods  

DOE Patents (OSTI)

A catalytic reforming method is disclosed herein. The method includes sequentially supplying a plurality of feedstocks of variable compositions to a reformer. The method further includes adding a respective predetermined co-reactant to each of the plurality of feedstocks to obtain a substantially constant output from the reformer for the plurality of feedstocks. The respective predetermined co-reactant is based on a C/H/O atomic composition for a respective one of the plurality of feedstocks and a predetermined C/H/O atomic composition for the substantially constant output.

Tadd, Andrew R; Schwank, Johannes

2013-05-14T23:59:59.000Z

87

Multizone naphtha reforming process  

Science Conference Proceedings (OSTI)

This patent describes a catalytic reforming process for conversion of a naphtha hydrocarbon at reforming conditions having at least two segregated catalyst zones. The improvement comprises contacting the hydrocarbon in a first zone with a first catalyst comprising tin and at least one platinum group metal deposited on a solid catalyst support followed by contacting in a second zone with a second catalyst comprising at least one metal selected from the group consisting of platinum group metals deposited on a solid catalyst support.

Fleming, B.

1987-05-05T23:59:59.000Z

88

Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles  

DOE Green Energy (OSTI)

The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

1992-08-01T23:59:59.000Z

89

Reformers for the production of hydrogen from methanol and alternative fuels for fuel cell powered vehicles  

DOE Green Energy (OSTI)

The objective of this study was (i) to assess the present state of technology of reformers that convert methanol (or other alternative fuels) to a hydrogen-rich gas mixture for use in a fuel cell, and (ii) to identify the R&D needs for developing reformers for transportation applications. Steam reforming and partial oxidation are the two basic types of fuel reforming processes. The former is endothermic while the latter is exothermic. Reformers are therefore typically designed as heat exchange systems, and the variety of designs used includes shell-and-tube, packed bed, annular, plate, and cyclic bed types. Catalysts used include noble metals and oxides of Cu, Zn, Cr, Al, Ni, and La. For transportation applications a reformer must be compact, lightweight, and rugged. It must also be capable of rapid start-up and good dynamic performance responsive to fluctuating loads. A partial oxidation reformer is likely to be better than a steam reformer based on these considerations, although its fuel conversion efficiency is expected to be lower than that of a steam reformer. A steam reformer better lends itself to thermal integration with the fuel cell system; however, the thermal independence of the reformer from the fuel cell stack is likely to yield much better dynamic performance of the reformer and the fuel cell propulsion power system. For both steam reforming and partial oxidation reforming, research is needed to develop compact, fast start-up, and dynamically responsive reformers. For transportation applications, steam reformers are likely to prove best for fuel cell/battery hybrid power systems, and partial oxidation reformers are likely to be the choice for stand-alone fuel cell power systems.

Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

1992-08-01T23:59:59.000Z

90

SUMMARY PLAN FOR BENCH-SCALE REFORMER AND PRODUCT TESTING TREATABILITY STUDIES USING HANFORD TANK WASTE  

SciTech Connect

This paper describes the sample selection, sample preparation, environmental, and regulatory considerations for shipment of Hanford radioactive waste samples for treatability studies of the FBSR process at the Savannah River National Laboratory and the Pacific Northwest National Laboratory.

ROBBINS RA

2011-02-11T23:59:59.000Z

91

Multi-fuel reformers for fuel cells used in transportation. Multi-fuel reformers: Phase 1 -- Final report  

DOE Green Energy (OSTI)

DOE has established the goal, through the Fuel Cells in Transportation Program, of fostering the rapid development and commercialization of fuel cells as economic competitors for the internal combustion engine. Central to this goal is a safe feasible means of supplying hydrogen of the required purity to the vehicular fuel cell system. Two basic strategies are being considered: (1) on-board fuel processing whereby alternative fuels such as methanol, ethanol or natural gas stored on the vehicle undergo reformation and subsequent processing to produce hydrogen, and (2) on-board storage of pure hydrogen provided by stationary fuel processing plants. This report analyzes fuel processor technologies, types of fuel and fuel cell options for on-board reformation. As the Phase 1 of a multi-phased program to develop a prototype multi-fuel reformer system for a fuel cell powered vehicle, the objective of this program was to evaluate the feasibility of a multi-fuel reformer concept and to select a reforming technology for further development in the Phase 2 program, with the ultimate goal of integration with a DOE-designated fuel cell and vehicle configuration. The basic reformer processes examined in this study included catalytic steam reforming (SR), non-catalytic partial oxidation (POX) and catalytic partial oxidation (also known as Autothermal Reforming, or ATR). Fuels under consideration in this study included methanol, ethanol, and natural gas. A systematic evaluation of reforming technologies, fuels, and transportation fuel cell applications was conducted for the purpose of selecting a suitable multi-fuel processor for further development and demonstration in a transportation application.

Not Available

1994-05-01T23:59:59.000Z

92

Extended Operations of the Pratt & Whitney Rocketdyne Pilot-Scale Compact Reformer Year 6 - Activity 3.2 - Development of a National Center for Hydrogen Technology  

SciTech Connect

U.S. and global demand for hydrogen is large and growing for use in the production of chemicals, materials, foods, pharmaceuticals, and fuels (including some low-carbon biofuels). Conventional hydrogen production technologies are expensive, have sizeable space requirements, and are large carbon dioxide emitters. A novel sorbent-based hydrogen production technology is being developed and advanced toward field demonstration that promises smaller size, greater efficiency, lower costs, and reduced to no net carbon dioxide emissions compared to conventional hydrogen production technology. Development efforts at the pilot scale have addressed materials compatibility, hot-gas filtration, and high-temperature solids transport and metering, among other issues, and have provided the basis for a preliminary process design with associated economics. The process was able to achieve a 93% hydrogen purity on a purge gasfree basis directly out of the pilot unit prior to downstream purification.

Almlie, Jay

2011-10-01T23:59:59.000Z

93

Catalytic reforming process  

Science Conference Proceedings (OSTI)

This patent describes a catalytic reforming process which comprises contacting a naphtha range feed with a low acidity extrudate comprising an intermediate and/or a large pore acidic zeolite bound with a low acidity refractory oxide under reforming conditions to provide a reaction product of increased aromatic content, the extrudate having been prepared with at least an extrusion-facilitating amount of a low acidity refractory oxide in colloidal form and containing at least one metal species selected from the platinum group metals.

Absil, R.P.; Huss, A. Jr.; McHale, W.D.; Partridge, R.D.

1989-06-13T23:59:59.000Z

94

Catalytic autothermal reforming of hydrocarbon fuels for fuel cells.  

DOE Green Energy (OSTI)

Fuel cell development has seen remarkable progress in the past decade because of an increasing need to improve energy efficiency as well as to address concerns about the environmental consequences of using fossil fuel for producing electricity and for propulsion of vehicles [1]. The lack of an infrastructure for producing and distributing H{sub 2} has led to a research effort to develop on-board fuel processing technology for reforming hydrocarbon fuels to generate H{sub 2} [2]. The primary focus is on reforming gasoline, because a production and distribution infrastructure for gasoline already exists to supply internal combustion engines [3]. Existing reforming technology for the production of H{sub 2} from hydrocarbon feedstocks used in large-scale manufacturing processes, such as ammonia synthesis, is cost prohibitive when scaled down to the size of the fuel processor required for transportation applications (50-80 kWe) nor is it designed to meet the varying power demands and frequent shutoffs and restarts that will be experienced during normal drive cycles. To meet the performance targets required of a fuel processor for transportation applications will require new reforming reactor technology developed to meet the volume, weight, cost, and operational characteristics for transportation applications and the development of new reforming catalysts that exhibit a higher activity and better thermal and mechanical stability than reforming catalysts currently used in the production of H{sub 2} for large-scale manufacturing processes.

Krumpelt, M.; Krause, T.; Kopasz, J.; Carter, D.; Ahmed, S.

2002-01-11T23:59:59.000Z

95

BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids (Presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

High Pressure Steam Reforming of High Pressure Steam Reforming of Bio-Derived Liquids S. Ahmed, S. Lee, D. Papadias, and R. Kumar November 6, 2007 Laurel, MD Research sponsored by the Hydrogen, Fuel Cells, and Infrastructure Technologies Program of DOE's Office of Energy Efficiency and Renewable Energy Rationale and objective Rationale „ Steam reforming of liquid fuels at high pressures can reduce hydrogen compression costs - Much less energy is needed to pressurize liquids (fuel and water) than compressing gases (reformate or H 2 ) „ High pressure reforming is advantageous for subsequent separations and hydrogen purification Objective „ Develop a reformer design that takes advantage of the savings in compression cost in the steam reforming bio-derived liquid fuels - Metric:

96

IFP solutions for revamping catalytic reforming units  

Science Conference Proceedings (OSTI)

The decision-making process for the refiner considering a revamp of a catalytic reforming unit comprises many factors. These may be grouped in two broad areas: technical and economic. This paper presents the results of a study performed by IFP that illustrates catalytic reforming unit revamp options. Three IFP processes are described and operating conditions, expected yields, and economic data are presented. The following options are discussed: base case Conventional, fixed-bed, semi-regenerative catalytic reformer; Case 1--revamp using IFP Dualforming technology; Case 2--revamp using IFP Dualforming Plus technology; and Case 3--revamp to IFP Octanizing technology. The study illustrates various options for the refiner to balance unit performance improvements with equipment, site, and economic constraints. The study was performed assuming design feedrate of 98.2 tons/hour (20,000 BPSD) in all cases. Because of the increased need for octane in many refineries, the study assumed that operating severity was set at a design value of 100 research octane number clear (RON). In all of the cases in this study, it was assumed that the existing recycle compressor was reused. Operating pressure differences between the cases is discussed separately. Also, in all cases, a booster compressor was included in order to return export hydrogen pressure to that of the conventional unit.

Gendler, J.L. [HRI, Inc., Princeton, NJ (United States); Domergue, B.; Mank, L. [Inst. Francais du Petrole, Rueil Malmaison (France)

1996-12-01T23:59:59.000Z

97

Secondary Waste Form Screening Test Results—THOR® Fluidized Bed Steam Reforming Product in a Geopolymer Matrix  

SciTech Connect

Screening tests are being conducted to evaluate waste forms for immobilizing secondary liquid wastes from the Hanford Tank Waste Treatment and Immobilization Plant (WTP). Plans are underway to add a stabilization treatment unit to the Effluent Treatment Facility to provide the needed capacity for treating these wastes from WTP. The current baseline is to use a Cast Stone cementitious waste form to solidify the wastes. Through a literature survey, DuraLith alkali-aluminosilicate geopolymer, fluidized-bed steam reformation (FBSR) granular product encapsulated in a geopolymer matrix, and a Ceramicrete phosphate-bonded ceramic were identified both as candidate waste forms and alternatives to the baseline. These waste forms have been shown to meet waste disposal acceptance criteria, including compressive strength and universal treatment standards for Resource Conservation and Recovery Act (RCRA) metals (as measured by the toxicity characteristic leaching procedure [TCLP]). Thus, these non-cementitious waste forms should also be acceptable for land disposal. Information is needed on all four waste forms with respect to their capability to minimize the release of technetium. Technetium is a radionuclide predicted to be in the secondary liquid wastes in small quantities, but the Integrated Disposal Facility (IDF) risk assessment analyses show that technetium, even at low mass, produces the largest contribution to the estimated IDF disposal impacts to groundwater.

Pires, Richard P.; Westsik, Joseph H.; Serne, R. Jeffrey; Mattigod, Shas V.; Golovich, Elizabeth C.; Valenta, Michelle M.; Parker, Kent E.

2011-07-14T23:59:59.000Z

98

Before the House Subcommittee on Technology, Information Policy,  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Technology, Information Policy, Technology, Information Policy, Intergovernmental Relations and Procurement Reform of the Committee on Overshigh and Government Reform Before the House Subcommittee on Technology, Information Policy, Intergovernmental Relations and Procurement Reform of the Committee on Overshigh and Government Reform Before the House Subcommittee on Technology, Information Policy, Intergovernmental Relations and Procurement Reform of the Committee on Overshigh and Government Reform By: Michael Locatis Subject: The Government Accountability Office's Report on Potentially Duplicative IT Investments 2-17-12_MichaelLocatis_FT.pdf More Documents & Publications IT Modernization Strategy OCIO Strategic Plan Before House Subcommittee on Oversight and Investigations - Committee on

99

Multifuel reformer R D  

DOE Green Energy (OSTI)

The on-board fuel for fuel cell powered vehicles may be one or more of hydrogen, methanol, ethanol, natural gas, propane, or other liquified petroleum gases. To use hydrogen as the fuel, suitable means of storing, and subsequently delivering, adequate quantities of the gas must be developed. For all other fuels suitable reformers must be developed to convert the fuel to hydrogen or a hydrogen-rich gas mixture at rates corresponding to the varying power demand rates of the automotive system; this is especially true for the lower temperature fuel cells, such as the polymer electrolyte fuel cell which operates at 80{degrees}C and the phosphoric acid fuel cell which operates at 190{degrees}C. This paper discusses the key design and performance characteristics of such hydrogen storage and fuel reformer systems for use in stand-alone fuel cell automotive applications.

Kumar, R.; Ahmed, S.

1991-01-01T23:59:59.000Z

100

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-24T23:59:59.000Z

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Methanol partial oxidation reformer  

DOE Patents (OSTI)

A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

Ahmed, S.; Kumar, R.; Krumpelt, M.

1999-08-17T23:59:59.000Z

102

Catalytic reforming catalyst  

Science Conference Proceedings (OSTI)

An improved catalyst, having a reduced fouling rate when used in a catalytic reforming process, said catalyst comprising platinum disposed on an alumina support wherein the alumina support is obtained by removing water from aluminum hydroxide produced as a by-product from a ziegler higher alcohol synthesis reaction, and wherein the alumina is calcined at a temperature of 1100-1400/sup 0/F so as to have a surface area of 165 to 215 square meters per gram.

Buss, W.C.; Kluksdahl, H.E.

1980-12-09T23:59:59.000Z

103

TWR Bench-Scale Steam Reforming Demonstration  

SciTech Connect

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by ThermoChem Waste Remediation, LLC, (TWR) for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). TWR is the licensee of Manufacturing Technology Conservation International (MTCI) steam-reforming technology in the field of radioactive waste treatment. A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrate residues were about 400 ppm in the product and NOx destruction exceeded 86%. The demonstration was successful.

Marshall, D.W.; Soelberg, N.R.

2003-05-21T23:59:59.000Z

104

TWR Bench-Scale Steam Reforming Demonstration  

SciTech Connect

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by ThermoChem Waste Remediation, LLC, (TWR) for treatment of SBW into a "road ready" waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). TWR is the licensee of Manufacturing Technology Conservation International (MTCI) steam-reforming technology in the field of radioactive waste treatment. A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrate residues were about 400 ppm in the product and NOx destruction exceeded 86%. The demonstration was successful.

D. W. Marshall; N. R. Soelberg

2003-05-01T23:59:59.000Z

105

Steam reformer with catalytic combustor  

DOE Patents (OSTI)

A steam reformer is disclosed having an annular steam reforming catalyst bed formed by concentric cylinders and having a catalytic combustor located at the center of the innermost cylinder. Fuel is fed into the interior of the catalytic combustor and air is directed at the top of the combustor, creating a catalytic reaction which provides sufficient heat so as to maintain the catalytic reaction in the steam reforming catalyst bed. Alternatively, air is fed into the interior of the catalytic combustor and a fuel mixture is directed at the top. The catalytic combustor provides enhanced radiant and convective heat transfer to the reformer catalyst bed.

Voecks, Gerald E. (La Crescenta, CA)

1990-03-20T23:59:59.000Z

106

Novel Reforming Catalysts  

Science Conference Proceedings (OSTI)

Aqueous phase reforming is useful for processing oxygenated hydrocarbons to hydrogen and other more useful products. Current processing is hampered by the fact that oxide based catalysts are not stable under high temperature hydrothermal conditions. Silica in the form of structured MCM-41 is thermally a more stable support for Co and Ni than conventional high surface area amorphous silica but hydrothermal stability is not demonstrated. Carbon nanotube supports, in contrast, are highly stable under hydrothermal reaction conditions. In this project we show that carbon nanotubes are stable high activity/selectivity supports for the conversion of ethylene glycol to hydrogen.

Pfefferle, Lisa D; Haller, Gary L

2012-10-16T23:59:59.000Z

107

NEPA Contracting Reform Guidance  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

defining early what contractors should accomplish < establishing contracts ahead of time < minimizing cost while maintaining quality by * maximizing competition and use of incentives * using past performance information in awarding work * managing the NEPA process as a project This guidance provides: < model statements of work < information on contract types and incentives < direction on effective NEPA contract management by the NEPA Document Manager < a system for measuring NEPA process costs < NEPA contractor evaluation procedures < details on the DOE NEPA Web site U.S. Department of Energy, Office of NEPA Policy and Assistance, December 1996 NEPA CONTRACTING REFORM GUIDANCE Table of Contents 1. INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

108

Multizone catalytic reforming process  

Science Conference Proceedings (OSTI)

This patent describes a process for the catalytic reforming of hydrocarbons comprising contacting the hydrocarbon feed in two sequential catalyst zones. It comprises: a first catalyst zone contains a first catalytic composite consisting essentially of a platinum component, a germanium component, a refractory inorganic oxide, and a halogen component; and a second catalyst zone contains a second catalytic composite comprising a platinum component, a germanium component, a refractory inorganic oxide, a halogen component, and catalytically effective amounts of a metal promoter selected from rhenium, rhodium, ruthenium, cobalt, nickel, and iridium, and mixtures thereof.

Moser, M.C.; Lawson, R.J.; Antos, G.J.; Wang, L.; Parulekar, V.N.

1990-05-29T23:59:59.000Z

109

Patent Counsel - Patent Reform | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Patent Counsel - Patent Reform Patent Counsel - Patent Reform America invents Act 20112.pdf More Documents & Publications PETITION FOR ADVANCE WAIVER OF PATENT RIGHTS Office of...

110

Attrition resistant fluidizable reforming catalyst - Energy ...  

A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and ...

111

Catalytic reforming optimization  

Science Conference Proceedings (OSTI)

The authors have previously examined correlations between catalytic reforming parameters for an L-35-6 unit at the Gor'knefteorgsintez Industrial Association. Experimental design was used to derive polynomial equations describing the correlations for each reactor. Further research on optimizing the reforming has been based on these results. They adopted the following strategy to define the best working parameters: they define a temperature that would provide the maximum target-product yield while maintaining a given working life. Most of the aromatic hydrocarbons are formed by the naphthene dehydrogenation, which is endothermic, so the greater the temperature drop over the height, the more rapid the process. The temperature difference thus indicates the current catalyst activity. To increase the target-product yield, one must raise the inlet temperature and ensure the largest drop across the catalyst. They examined an algorithm with fixed inlet conditions as regards flow rate and raw material composition. This algorithm provides the basis of software for the automatic control of the L-35-6 reactor unit at the Gor'knefteorgsintez Industrial Association. The system has been checked out and put into experimental operation.

Mazina, S.G.; Rybtsov, V.V.; Priss-Titarenko, T.A.

1988-11-10T23:59:59.000Z

112

Update on IT Reform at the Department of Energy | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Update on IT Reform at the Department of Energy Update on IT Reform at the Department of Energy Update on IT Reform at the Department of Energy June 4, 2012 - 2:14pm Addthis The last 18 months have seen great improvements in the Department of Energy's (DOE) information technology and cybersecurity. A major factor in our success is our alignment with the 25 Point Implementation Plan To Reform Federal Information Technology Management to move to a "Cloud First" environment and maximize the use of shared services to reduce costs and improve IT delivery. Cloud-First/Shared Services: In August 2011, we revamped our online presence by launching Energy.gov and delivering a single platform solution through an open-source content management system and cloud hosting environment. Ultimately, the website reform effort aims to save taxpayers more than $10 million per

113

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

71 - 18180 of 29,416 results. 71 - 18180 of 29,416 results. Download Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP) This assessment determines the technology maturity level of the candidate Tank 48H treatment technologies that are being considered for implementation at DOE's SRS - specifically Fluidized Bed... http://energy.gov/em/downloads/technology-maturation-plan-tmp-fluidized-bed-steam-reforming-fbsr Download Audit of Shutdown and Transition of the Mound Plant, IG-0408 http://energy.gov/ig/downloads/audit-shutdown-and-transition-mound-plant-ig-0408 Download HQFMSP Chapter 11, Incidents of Security Concern 2013 Headquarters Facilities Master Security Plan - Chapter 11, Incidents of Security Concern Describes DOE Headquarters procedures for reporting, investigating, and

114

High severity catalytic reforming process  

Science Conference Proceedings (OSTI)

A high-severity catalytic reforming process is described comprising: (a) passing a mixture comprising a catalytic reforming feed stream and a recycle stream into a catalytic reforming reaction zone which is maintained at high-severity reforming conditions; (b) cooling an effluent stream comprising hydrogen and hydrocarbonaceous catalytic reforming reaction products which is withdrawn from the reaction zone; (c) passing the cooled effluent stream into a vapor-liquid separation zone and recovering therefrom a liquid stream comprising hydrocarbons and a hydrogen-rich gas stream; (d) passing the hydrogen-rich gas stream through an adsorption zone wherein the gas is contacted with a treating material which removes polycyclic aromatic compounds from the gas stream, the compounds remaining in the adsorption zone; (e) mixing a portion of the hydrogen-rich gas stream, which is the recycle stream, with the feed stream to form the charge stock mixture and withdrawing the balance of the hydrogen-rich gas stream, which is denoted as net hydrogen, from the catalytic reforming area, all of the hydrogen-rich gas stream being substantially free of polycyclic aromatic compounds; and (f) fractionating the liquid stream and recovering an overhead product comprising light hydrocarbons and a bottoms product comprising reformate.

Bennett, R.W.; Cottrell, P.R.; Gilsdorf, N.L.; Winfield, M.D.

1988-03-22T23:59:59.000Z

115

Liquid fuel reformer development.  

DOE Green Energy (OSTI)

At Argonne National Laboratory we are developing a process to convert hydrocarbon fuels to a clean hydrogen feed for a fuel cell. The process incorporates a partial oxidation/steam reforming catalyst that can process hydrocarbon feeds at lower temperatures than existing commercial catalysts. We have tested the catalyst with three diesel-type fuels: hexadecane, low-sulfur diesel fuel, and a regular diesel fuel. We achieved complete conversion of the feed to products. Hexadecane yielded products containing 60% hydrogen on a dry, nitrogen-free basis at 800 C. For the two diesel fuels, higher temperatures, >850 C, were required to approach similar levels of hydrogen in the product stream. At 800 C, hydrogen yield of the low sulfur diesel was 32%, while that of the regular diesel was 52%. Residual products in both cases included CO, CO{sub 2}, ethane, ethylene, and methane.

Ahmed, S.; Krumpelt, M.; Pereira, C.; Wilkenhoener, R.

1999-07-30T23:59:59.000Z

116

Multizone catalytic reforming process  

Science Conference Proceedings (OSTI)

This patent describes a process for the catalytic reforming of hydrocarbons comprising contacting the hydrocarbon feed in two sequential catalyst zones. It comprises: an initial catalyst zone which is a fixed-bed system and contains an initial catalytic composite comprising a platinum component, a germanium component, a refractory inorganic oxide, and a halogen component; and a terminal catalyst zone which is a moving-bed system with associated continuous catalyst regeneration and contains a terminal catalytic composite having the essential absence of germanium and comprising a platinum component, a refractory inorganic oxide, a halogen component, and catalytically effective amounts of a metal promoter selected from one or more of the rhenium, tin, indium, rhodium, ruthenium, cobalt, nickel, and iridium.

Moser, M.; Lawson, R.J.; Wang, L.; Parulekar, V.; Peer, R.L.; Hamlin, C.R.

1991-01-15T23:59:59.000Z

117

Puerto Rico Refinery Catalytic Reforming Downstream Charge ...  

U.S. Energy Information Administration (EIA)

Puerto Rico Refinery Catalytic Reforming Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

118

Mississippi Refinery Catalytic Reforming Downstream Charge ...  

U.S. Energy Information Administration (EIA)

Mississippi Refinery Catalytic Reforming Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

119

Louisiana Refinery Catalytic Reforming Downstream Charge Capacity ...  

U.S. Energy Information Administration (EIA)

Louisiana Refinery Catalytic Reforming Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

120

Recent Advances in the Capture/Sequestration of Volatile ...  

Science Conference Proceedings (OSTI)

... would work collaboratively to solve the technical challenges and develop the ... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes.

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121

Impact of Particle Agglomeration on Accumulation Rates in the ...  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

122

Liquidus Temperature Studies for High Level Nuclear Waste Glasses  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

123

Burst, Ring and Biaxial Creep of Zircaloy Cladding – Applications to ...  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

124

The Effect of Particle Geometry on the Dissolution Behavior of Glasses  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

125

Functionalized Nanoporous Sorbent Materials for Chemical ...  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

126

The Effects of Lithium Nitrate on Highly Active Liquor in the ...  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

127

Viscosity of Multicomponent Glasses as a Function of Temperature ...  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

128

Determining Thermal Conductivity of Simulated Feed for High Level ...  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

129

Thermal Degradation and Immobilisation of Spent Ion Exchange ...  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

130

Advanced Electrochemical Waste Forms  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

131

Sodalite-Based Forms for Wastes Containing Actinides and Halides  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

132

Adsorption of of Radioactive Iodine from Used Nuclear Fuel ...  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

133

Environmental Cracking of Nickel Alloys in Bicarbonate and ...  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

134

Advanced Ceramic Waste Forms for the Immobilisation of ...  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

135

Migration of Iodine Solidified in Ettringite into Compacted Bentonite  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

136

REDuction/OXidation (REDOX) Modeling and Process Control in the ...  

Science Conference Proceedings (OSTI)

... of Fluidized Bed Steam Reforming (FBSR) with Hanford Low Activity Wastes ... Level Waste at the Defense Waste Processing Facility through Sludge Batch 7b.

137

Technologies  

Technologies Materials. Aggregate Spray for Air Particulate; Actuators Made From Nanoporous Materials; Ceramic Filters; Energy Absorbing Material; Diode Arrays for ...

138

Technologies  

Science & Technology. Weapons & Complex Integration. News Center. News Center. Around the Lab. Contacts. For Reporters. Livermore Lab Report. ...

139

Technologies  

Technologies Energy. Advanced Carbon Aerogels for Energy Applications; Distributed Automated Demand Response; Electrostatic Generator/Motor; Modular Electromechanical ...

140

Technologies  

Technologies Energy, Utilities, & Power Systems. Advanced Carbon Aerogels for Energy Applications; Distributed Automated Demand Response; Electrostatic Generator/Motor

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
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to obtain the most current and comprehensive results.


141

Technologies  

Technologies Research Tools. Cell-Free Assembly of NanoLipoprotein Particles; Chemical Prism; Lawrence Livermore Microbial Detection Array (LLMDA) ...

142

Hiring Reform | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hiring Reform Hiring Reform Hiring Reform President Obama's Memorandum dated May 11, 2010, Improving the Federal Recruitment and Hiring Process, is Phase I of the Administration's comprehensive initiative to address major, long-standing impediments to recruiting and hiring the best and the brightest into the Federal civilian workforce. The Memorandum is based on issues that DOE and others brought to the attention of OPM, and it is designed to help Agencies build the workforce you need to achieve your goals. The Presidential Memorandum launches the Obama Administration's flagship personnel policy reform initiative. It builds on a nearly year-long collaboration between OPM and Agencies aimed at streamlining the hiring process and recruiting top talent, especially for mission-critical jobs.

143

Steam Reforming of Low-Level Mixed Waste  

Science Conference Proceedings (OSTI)

Under DOE Contract No. DE-AR21-95MC32091, Steam Reforming of Low-Level Mixed Waste, ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design construction, and testing of the PDU as well as performance and economic projections for a 500- lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area published April 1997.1 The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfidly tested including a 750-hour test on material simulating a PCB- and Uranium- contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (>99.9999oA) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radlonuclides in the volume-reduced solids. Cost studies have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

None

1998-01-01T23:59:59.000Z

144

Partial oxidation reforming of methanol  

DOE Green Energy (OSTI)

Methanol is an attractive fuel for fuel cell-powered vehicles because it has a fairly high energy density, can be pumped into the tank of a vehicle mush like gasoline, and is relatively easy to reform. For on-board reforming, the reformer must be compact and lightweight, and have rapid start-up and good dynamic response. Steam reforming reactors with the tube-and-shell geometry that was used on the prototype fuel cell-powered buses are heat transfer limited. To reach their normal operating temperature, these types of reactors need 45 minutes from ambient temperature start-up. The dynamic response is poor due to temperature control problems. To overcome the limitations of steam reforming, ANL explored the partial oxidation concept used in the petroleum industry to process crude oils. In contrast to the endothermic steam reforming reaction, partial oxidations is exothermic. Fuel and air are passed together over a catalyst or reacted thermally, yielding a hydrogen-rich gas. Since the operating temperature of such a reactor can be controlled by the oxygen-to- methanol ratio, the rates of reaction are not heat transfer limited. Start-up and transient response should be rapid, and the mass and volume are expected to be small by comparison.

Krumpelt, M.; Ahmed, S.; Kumar, R.

1996-04-01T23:59:59.000Z

145

Before House Committee on Oversight and Government Reform | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

House Committee on Oversight and Government Reform Before House Committee on Oversight and Government Reform Before House Committee on Oversight and Government Reform By: Secretary...

146

Before the House Committee on Oversight and Government Reform...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Oversight and Government Reform Before the House Committee on Oversight and Government Reform Before the Committee on Oversight and Government Reform, U.S. House of Representatives...

147

Technologies  

High Performance Computing (HPC) Technologies; Industrial Partnerships Office P.O. Box 808, L-795 Livermore, CA 94551 Phone: (925) 422-6416 Fax: (925) ...

148

Technolog  

NLE Websites -- All DOE Office Websites (Extended Search)

Research in Research in Science and Technolog y Sandia pushes frontiers of knowledge to meet the nation's needs, today and tomorrow Sandia National Laboratories' fundamental science and technology research leads to greater understanding of how and why things work and is intrinsic to technological advances. Basic research that challenges scientific assumptions enables the nation to push scientific boundaries. Innovations and breakthroughs produced at Sandia allow it to tackle critical issues, from maintaining the safety, security and effectiveness of the nation's nuclear weapons and preventing domestic and interna- tional terrorism to finding innovative clean energy solutions, develop- ing cutting-edge nanotechnology and moving the latest advances to the marketplace. Sandia's expertise includes:

149

Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

Technology Computers and the internet play an increasingly larger role in the lives of students. In this activity, students must use various web sites to locate specific pieces of...

150

Home Production and Social Security Reform ?  

E-Print Network (OSTI)

This paper incorporates home production into a dynamic general equilibrium model of overlapping generations with endogenous retirement to study Social Security reforms. As such, the model differentiates both consumption goods and labor effort according to their respective roles in home production and market activities. Using a calibrated model, we conduct a policy experiment where we eliminate the current pay-as-you-go Social Security System and study the steady state impact. We find that the experiment has important implications for labor supply as well as consumption decisions and that these decisions are influenced by the presence of a home production technology. Comparing our economy to a onegood economy without home production, the welfare gains of eliminating Social Security are magnified significantly. We further demonstrate that the qualitative results hold with the less extreme policy reform where we delay the eligible Social Security benefits claimant age by four years. These policy analyses suggest the importance of modeling home production and distinguishing between both time

Michael Dotsey; Wenli Li; Fang Yang

2012-01-01T23:59:59.000Z

151

Safety and Security Directives Reform  

NLE Websites -- All DOE Office Websites (Extended Search)

Reforming a "Mountain" of Policy Reforming a "Mountain" of Policy Beginning with his confirmation hearings in January 2009, Energy Secretary Steven Chu challenged the Department of Energy to take a fresh look at how we conduct business. This challenge provided the opportunity for DOE to put in place the most effective and efficient strategies to accomplish the Department's missions safely and securely. In response to the Secretary's challenge and building on the results of Deputy Secretary Poneman's Safety and Security Reform studies, the Office of Health, Safety and Security (HSS) broadened its directives review activities during 2009. By November 2009 HSS had initiated a disciplined review of all health, safety, and security directives, which included a systematic review of the Department's safety and security regulatory model.

152

Evaluate reformer performance at a glance  

Science Conference Proceedings (OSTI)

Catalytic reforming is becoming increasingly important in replacing octane lost as the removal of lead from worldwide gasoline pools continues. A method has been developed that can quickly evaluate the performance of any catalytic reformer. The catalytic naphtha reforming process primarily involves three well-known reactions. These are aromatization of naphthenes, cyclization of paraffins and hydrocracking of paraffins. Hydrogen is produced in the process of aromatization and dehydrocyclization of paraffins. Reformer performance is normally evaluated with a reformate analysis (PONA) and yield of C{sub 5{sup +}} reformate. This method of quick evaluation of reformer performance is based upon the main assumption that the increase in hydrocarbon moles in the process is equal to the number of C{single_bond}C bond ruptures and one mole of hydrogen is absorbed to saturate the same. This new method calculates aromatization efficiency, paraffin conversion, aromatic selectivity and finally the paraffin, naphthene and aromatic content of C{sub 5{sup +}} reformate.

Nag, A. [Indian Oil Corporation Ltd., Gujarat (India)

1996-02-01T23:59:59.000Z

153

Bringing electricity reform to the Philippines  

SciTech Connect

Electricity reforms will not translate to competition overnight. But reforms are inching their way forward in institutions and stakeholders of the Philippine electricity industry, through regulatory and competition frameworks, processes, and systems promulgated and implemented. (author)

Fe Villamejor-Mendoza, Maria

2008-12-15T23:59:59.000Z

154

Refiners look at H sub 2 SO sub 4 alkylation and catalytic reforming  

Science Conference Proceedings (OSTI)

Sulfuric acid alkylation and catalytic reforming drew many questions at the most recent National Petroleum Refiners Association (NPRA) question and answer session on refining and petrochemical technology. At this annual meeting, presubmitted questions are answered by a panel of experts. For more information on the meeting's format, see OGJ, Mar. 16, p. 37. This third and final article in the series of excerpts from the 1991 NPRA Q and A Session examines such pertinent alkylation topics as tertiary amyl methyl ether (TAME) raffinate processing and unit operation during acid runaway. Also discussed are skewed platinum/rhenium reforming catalyst and how catalyst life affects reformate aromatics levels.

Not Available

1992-04-27T23:59:59.000Z

155

Method of steam reforming methanol to hydrogen  

DOE Patents (OSTI)

The production of hydrogen by the catalyzed steam reforming of methanol is accomplished using a reformer of greatly reduced size and cost wherein a mixture of water and methanol is superheated to the gaseous state at temperatures of about 800.degree. to about 1,100.degree. F. and then fed to a reformer in direct contact with the catalyst bed contained therein, whereby the heat for the endothermic steam reforming reaction is derived directly from the superheated steam/methanol mixture.

Beshty, Bahjat S. (Lower Makefield, PA)

1990-01-01T23:59:59.000Z

156

Olefins from High Yield Autothermal Reforming Process ...  

Isobutylene is used to produce fuel additives. The autothermal reforming process can produce isobutylene and requires no external energy input ...

157

Accelerated Weathering of Fluidized Bed Steam Reformation ...  

Science Conference Proceedings (OSTI)

Sep 16, 2007 ... Accelerated Weathering of Fluidized Bed Steam Reformation Material Under Hydraulically Unsaturated Conditions by E.M. Pierce ...

158

Continuing Management Reform | National Nuclear Security Administratio...  

National Nuclear Security Administration (NNSA)

Continuing Management Reform | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response...

159

Attrition resistant fluidizable reforming catalyst  

DOE Patents (OSTI)

A method of preparing a steam reforming catalyst characterized by improved resistance to attrition loss when used for cracking, reforming, water gas shift and gasification reactions on feedstock in a fluidized bed reactor, comprising: fabricating the ceramic support particle, coating a ceramic support by adding an aqueous solution of a precursor salt of a metal selected from the group consisting of Ni, Pt, Pd, Ru, Rh, Cr, Co, Mn, Mg, K, La and Fe and mixtures thereof to the ceramic support and calcining the coated ceramic in air to convert the metal salts to metal oxides.

Parent, Yves O. (Golden, CO); Magrini, Kim (Golden, CO); Landin, Steven M. (Conifer, CO); Ritland, Marcus A. (Palm Beach Shores, FL)

2011-03-29T23:59:59.000Z

160

INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING  

E-Print Network (OSTI)

INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE Prepared For: California Energy REPORT (FAR) INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE CYCLES EISG AWARDEE University://www.energy.ca.gov/research/index.html. #12;Page 1 Integral Catalytic Combustion/Fuel Reforming for Gas Turbine Cycles EISG Grant # 99

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

THOR Bench-Scale Steam Reforming Demonstration  

SciTech Connect

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrates were not detected in the product and NOx destruction exceeded 98%. The demonstration was successful.

Marshall, D.W.; Soelberg, N.R.; Shaber, K.M.

2003-05-21T23:59:59.000Z

162

THOR Bench-Scale Steam Reforming Demonstration  

SciTech Connect

The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a "road ready" waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrates were not detected in the product and NOx destruction exceeded 98%. The demonstration was successful.

D. W. Marshall; N. R. Soelberg; K. M. Shaber

2003-05-01T23:59:59.000Z

163

Unfunded Mandates Reform Act; Intergovernmental Consultation | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Unfunded Mandates Reform Act; Intergovernmental Consultation Unfunded Mandates Reform Act; Intergovernmental Consultation Unfunded Mandates Reform Act; Intergovernmental Consultation The Department of Energy (DOE) today publishes a final statement of policy on intergovernmental consultation under the Unfunded Mandates Reform Act of 1995. The policy reflects the guidelines and instructions that the Director of the Office of Management and Budget (OMB) provided to each agency to develop, with input from State, local, and tribal officials, an intergovernmental consultation process with regard to significant intergovernmental mandates contained in a notice of proposed rulemaking. Unfunded Mandates Reform Act; Intergovernmental Consultation More Documents & Publications TEC Working Group Topic Groups Tribal Key Documents

164

NEPA Contracting Reform Guidance | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Contracting Reform Guidance Contracting Reform Guidance NEPA Contracting Reform Guidance This documents provides guidance on NEPA contracting strategy, including: defining the work of the contractor; establishing contracts ahead of time; minimizing cost while maintaining quality. Guidance also provides: model statements of work, direction on NEPA contract management by NEPA Document Manager; a system for measuring NEPA costs and for evaluating contractor procedures; details on the DOE NEPA website. NEPA Contracting Reform Guidance More Documents & Publications NEPA Contracting Reform Guidance (December 1996) Statement of Work-National Environmental Policy Act (NEPA) Support Services Acquisition: Preparation and Review of Environmental Impact Statements, Environmental Assessments, Environmental Reports, and other Environmental

165

Unfunded Mandates Reform Act; Intergovernmental Consultation | Department  

NLE Websites -- All DOE Office Websites (Extended Search)

Unfunded Mandates Reform Act; Intergovernmental Consultation Unfunded Mandates Reform Act; Intergovernmental Consultation Unfunded Mandates Reform Act; Intergovernmental Consultation The Department of Energy (DOE) today publishes a final statement of policy on intergovernmental consultation under the Unfunded Mandates Reform Act of 1995. The policy reflects the guidelines and instructions that the Director of the Office of Management and Budget (OMB) provided to each agency to develop, with input from State, local, and tribal officials, an intergovernmental consultation process with regard to significant intergovernmental mandates contained in a notice of proposed rulemaking. Unfunded Mandates Reform Act; Intergovernmental Consultation More Documents & Publications TEC Working Group Topic Groups Tribal Key Documents

166

Modelling and Experimental Study of Methane Catalytic Cracking as a Hydrogen Production Technology.  

E-Print Network (OSTI)

??Production of hydrogen is primarily achieved via catalytic steam reforming, partial oxidation,and auto-thermal reforming of natural gas. Although these processes are mature technologies, they are… (more)

Amin, Ashraf Mukhtar Lotfi

2011-01-01T23:59:59.000Z

167

Commercialization of a high-performance continuous reforming catalyst  

Science Conference Proceedings (OSTI)

In 1971, the first CCR Platforming process was started up in the US on the Gulf Coast. Twenty-two years later, more than 108 continuous reforming units are operating worldwide. Another 50 CCR Platforming units are in various stages of design, construction, or start-up. Continuous catalytic reforming now represents more than 25% of the world's reforming capacity. Throughout these three decades, the UOP CCR Platforming technology continuously improved in terms of catalyst and process in response to changing industry requirements. Processing conditions in 1993 place tremendous demands on the catalyst in the reforming unit. This paper reviews the challenges and needs of the changing refining industry and the development of a new generation of CCR Platforming catalyst, R-132, and focuses on the first commercial operation of this high-activity, surface-stable catalyst. Case studies show how a refiner can improve margins by using the high activity, yield stability, longer life, and improved chloride retention benefits of this new R-132 Platforming catalyst.

Gilsdorf, N.L.; Doornbos, A.E.; Gevelinger, T.J. (UOP, Des Plaines, IL (United States)); Angelo, C.M.D. (Petrogal Refinaria de Sines (Portugal))

1993-01-01T23:59:59.000Z

168

Steam reforming of low-level mixed waste. Final report  

Science Conference Proceedings (OSTI)

ThermoChem has successfully designed, fabricated and operated a nominal 90 pound per hour Process Development Unit (PDU) on various low-level mixed waste surrogates. The design, construction, and testing of the PDU as well as performance and economic projections for a 300-lb/hr demonstration and commercial system are described. The overall system offers an environmentally safe, non-incinerating, cost-effective, and publicly acceptable method of processing LLMW. The steam-reforming technology was ranked the No. 1 non-incineration technology for destruction of hazardous organic wastes in a study commissioned by the Mixed Waste Focus Area and published in April 1997. The ThermoChem steam-reforming system has been developed over the last 13 years culminating in this successful test campaign on LLMW surrogates. Six surrogates were successfully tested including a 750-hour test on material simulating a PCB- and Uranium-contaminated solid waste found at the Portsmouth Gaseous Diffusion Plant. The test results indicated essentially total (> 99.9999%) destruction of RCRA and TSCA hazardous halogenated organics, significant levels of volume reduction (> 400 to 1), and retention of radionuclides in the volume-reduced solids. Economic evaluations have shown the steam-reforming system to be very cost competitive with more conventional and other emerging technologies.

NONE

1998-06-01T23:59:59.000Z

169

Fuel Cell Technologies Office: Bio-Derived Liquids to Hydrogen...  

NLE Websites -- All DOE Office Websites (Extended Search)

Meeting - November 2007 to someone by E-mail Share Fuel Cell Technologies Office: Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group Meeting - November 2007 on...

170

Vehicle Technologies Office: Fact #571: May 18, 2009 Light Truck CAFE  

NLE Websites -- All DOE Office Websites (Extended Search)

1: May 18, 2009 1: May 18, 2009 Light Truck CAFE Standards - 2006 Reformation to someone by E-mail Share Vehicle Technologies Office: Fact #571: May 18, 2009 Light Truck CAFE Standards - 2006 Reformation on Facebook Tweet about Vehicle Technologies Office: Fact #571: May 18, 2009 Light Truck CAFE Standards - 2006 Reformation on Twitter Bookmark Vehicle Technologies Office: Fact #571: May 18, 2009 Light Truck CAFE Standards - 2006 Reformation on Google Bookmark Vehicle Technologies Office: Fact #571: May 18, 2009 Light Truck CAFE Standards - 2006 Reformation on Delicious Rank Vehicle Technologies Office: Fact #571: May 18, 2009 Light Truck CAFE Standards - 2006 Reformation on Digg Find More places to share Vehicle Technologies Office: Fact #571: May 18, 2009 Light Truck CAFE Standards - 2006 Reformation on

171

Solar Reforming of Carbon Dioxide to Produce Diesel Fuel  

SciTech Connect

This project focused on the demonstration of an innovative technology, referred to as the Sunexus CO2 Solar Reformer, which utilizes waste CO2 as a feedstock for the efficient and economical production of synthetic diesel fuel using solar thermal energy as the primary energy input. The Sunexus technology employs a two stage process for the conversion of CO2 to diesel fuel. A solar reforming system, including a specially designed reactor and proprietary CO2 reforming catalyst, was developed and used to convert captured CO2 rich gas streams into syngas (primarily hydrogen and carbon monoxide) using concentrated solar energy at high conversion efficiencies. The second stage of the system (which has been demonstrated under other funding) involves the direct conversion of the syngas into synthetic diesel fuel using a proprietary catalyst (Terra) previously developed and validated by Pacific Renewable Fuels and Chemicals (PRFC). The overall system energy efficiency for conversion of CO2 to diesel fuel is 74%, due to the use of solar energy. The results herein describe modeling, design, construction, and testing of the Sunexus CO2 Solar Reformer. Extensive parametric testing of the solar reformer and candidate catalysts was conducted and chemical kinetic models were developed. Laboratory testing of the Solar Reformer was successfully completed using various gas mixtures, temperatures, and gas flow rates/space velocities to establish performance metrics which can be employed for the design of commercial plants. A variety of laboratory tests were conducted including dry reforming (CO2 and CH{sub 4}), combination dry/steam reforming (CO2, CH{sub 4} & H{sub 2}O), and tri-reforming (CO2, CH{sub 4}, H{sub 2}O & O{sub 2}). CH{sub 4} and CO2 conversions averaged 95-100% and 50-90% per reformer cycle, respectively, depending upon the temperatures and gas space velocities. No formation of carbon deposits (coking) on the catalyst was observed in any of these tests. A 16 ft. diameter, concentrating solar dish was modified to accommodate the Sunexus CO2 Solar Reformer and the integrated system was installed at the Pacific Renewable Fuels and Chemicals test site at McClellan, CA. Several test runs were conducted without catalyst during which the ceramic heat exchanger in the Sunexus Solar Reformer reached temperatures between 1,050 F (566 C) and 2,200 F (1,204 C) during the test period. A dry reforming mixture of CO2/CH{sub 4} (2.0/1.0 molar ratio) was chosen for all of the tests on the integrated solar dish/catalytic reformer during December 2010. Initial tests were carried out to determine heat transfer from the collimated solar beam to the catalytic reactor. The catalyst was operated successfully at a steady-state temperature of 1,125 F (607 C), which was sufficient to convert 35% of the 2/1 CO2/CH{sub 4} mixture to syngas. This conversion efficiency confirmed the results from laboratory testing of this catalyst which provided comparable syngas production efficiencies (40% at 1,200 F [650 C]) with a resulting syngas composition of 20% CO, 16% H{sub 2}, 39% CO2 and 25% CH{sub 4}. As based upon the laboratory results, it is predicted that 90% of the CO2 will be converted to syngas in the solar reformer at 1,440 F (782 C) resulting in a syngas composition of 50% CO: 43% H{sub 2}: 7% CO2: 0% CH{sub 4}. Laboratory tests show that the higher catalyst operating temperature of 1,440 F (782 C) for efficient conversion of CO2 can certainly be achieved by optimizing solar reactor heat transfer, which would result in the projected 90% CO2-to-syngas conversion efficiencies. Further testing will be carried out during 2011, through other funding support, to further optimize the solar dish CO2 reformer. Additional studies carried out in support of this project and described in this report include: (1) An Assessment of Potential Contaminants in Captured CO2 from Various Industrial Processes and Their Possible Effect on Sunexus CO2 Reforming Catalysts; (2) Recommended Measurement Methods for Assessing Contaminant Levels in Captured CO2 Streams; (3) An Asse

Dennis Schuetzle; Robert Schuetzle

2010-12-31T23:59:59.000Z

172

Secondary Waste Form Down-Selection Data Package—Fluidized Bed Steam Reforming Waste Form  

SciTech Connect

The Hanford Site in southeast Washington State has 56 million gallons of radioactive and chemically hazardous wastes stored in 177 underground tanks (ORP 2010). The U.S. Department of Energy (DOE), Office of River Protection (ORP), through its contractors, is constructing the Hanford Tank Waste Treatment and Immobilization Plant (WTP) to convert the radioactive and hazardous wastes into stable glass waste forms for disposal. Within the WTP, the pretreatment facility will receive the retrieved waste from the tank farms and separate it into two treated process streams. These waste streams will be vitrified, and the resulting waste canisters will be sent to offsite (high-level waste [HLW]) and onsite (immobilized low-activity waste [ILAW]) repositories. As part of the pretreatment and ILAW processing, liquid secondary wastes will be generated that will be transferred to the Effluent Treatment Facility (ETF) on the Hanford Site for further treatment. These liquid secondary wastes will be converted to stable solid waste forms that will be disposed of in the Integrated Disposal Facility (IDF). To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions (WRPS) has initiated secondary waste form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is developing data packages to support that down-selection. The objective of the data packages is to identify, evaluate, and summarize the existing information on the four waste forms being considered for stabilizing and solidifying the liquid secondary wastes. At the Hanford Site, the FBSR process is being evaluated as a supplemental technology for treating and immobilizing Hanford LAW radioactive tank waste and for treating secondary wastes from the WTP pretreatment and LAW vitrification processes.

Qafoku, Nikolla; Westsik, Joseph H.; Strachan, Denis M.; Valenta, Michelle M.; Pires, Richard P.

2011-09-12T23:59:59.000Z

173

Implementation of Technology Integration in Higher Education: A Case Study of the University of Dar-es-Salaam in Tanzania.  

E-Print Network (OSTI)

??The use of technology in education is one of the major trends in educational reforms all over the world. Integrating technology into the learning and… (more)

Kajuna, Laxford W.

2009-01-01T23:59:59.000Z

174

Plasma-catalyzed fuel reformer  

DOE Patents (OSTI)

A reformer is disclosed that includes a plasma zone to receive a pre-heated mixture of reactants and ionize the reactants by applying an electrical potential thereto. A first thermally conductive surface surrounds the plasma zone and is configured to transfer heat from an external heat source into the plasma zone. The reformer further includes a reaction zone to chemically transform the ionized reactants into synthesis gas comprising hydrogen and carbon monoxide. A second thermally conductive surface surrounds the reaction zone and is configured to transfer heat from the external heat source into the reaction zone. The first thermally conductive surface and second thermally conductive surface are both directly exposed to the external heat source. A corresponding method and system are also disclosed and claimed herein.

Hartvigsen, Joseph J.; Elangovan, S.; Czernichowski, Piotr; Hollist, Michele

2013-06-11T23:59:59.000Z

175

Fuel Reformation: Microchannel Reactor Design  

DOE Green Energy (OSTI)

Fuel processing is used to extract hydrogen from conventional vehicle fuel and allow fuel cell powered vehicles to use the existing petroleum fuel infrastructure. Kilowatt scale micro-channel steam reforming, water-gas shift and preferential oxida-tion reactors have been developed capable of achieving DOE required system performance metrics. Use of a microchannel design effectively supplies heat to the highly endothermic steam reforming reactor to maintain high conversions, controls the temperature profile for the exothermic water gas shift reactor, which optimizes the overall reaction conversion, and removes heat to prevent the unwanted hydrogen oxidation in the prefer-ential oxidation reactor. The reactors combined with micro-channel heat exchangers, when scaled to a full sized 50 kWe automotive system, will be less than 21 L in volume and 52 kg in weight.

Brooks, Kriston P.; Davis, James M.; Fischer, Christopher M.; King, David L.; Pederson, Larry R.; Rawlings, Gregg C.; Stenkamp, Victoria S.; TeGrotenhuis, Ward E.; Wegeng, Robert S.; Whyatt, Greg A.

2005-09-01T23:59:59.000Z

176

Thermochemical Fuel Reformer Development Project  

Science Conference Proceedings (OSTI)

Thermochemical Fuel Reforming (TCFR) is the recovery of internal combustion engine exhaust heat to chemically convert natural gas into a higher calorific flow fuel stream containing a significant concentration of hydrogen. This technique of recycling the engine exhaust heat can reduce fuel use (heat rate). In addition, the hydrogen enhanced combustion also allows stable engine operation at a higher air-fuel ratio (leaner combustion) which results in very low NOx production. This interim report covers two...

2006-12-11T23:59:59.000Z

177

Environmental fiscal reform (EFR) | Open Energy Information  

Open Energy Info (EERE)

Environmental fiscal reform (EFR) Environmental fiscal reform (EFR) Jump to: navigation, search Tool Summary Name: Environmental fiscal reform (EFR) Agency/Company /Organization: Global Subsidies Initiative (GSI), International Institute for Sustainable Development (IISD), World Bank Phase: Develop Goals, Prepare a Plan, Develop Finance and Implement Projects Topics: Co-benefits assessment, Finance, Market analysis, Policies/deployment programs References: Environmental fiscal reform - What should be done and how to achieve it[1] Reforming fiscal policies to close the gap between economic and ecological efficiencies[2] Overview "The term environmental fiscal reform (EFR) refers to: a range of taxation or pricing instruments that can raise revenue, while simultaneously furthering environmental goals. This is achieved by providing economic

178

In situ Gas Conditioning in Fuel Reforming for Hydrogen Generation  

DOE Green Energy (OSTI)

The production of hydrogen for fuel cell applications requires cost and energy efficient technologies. The Absorption Enhanced Reforming (AER), developed at ZSW with industrial partners, is aimed to simplify the process by using a high temperature in situ CO2 absorption. The in situ CO2 removal results in shifting the steam reforming reaction equilibrium towards increased hydrogen concentration (up to 95 vol%). The key part of the process is the high temperature CO2 absorbent. In this contribution results of Thermal Gravimetric Analysis (TGA) investigations on natural minerals, dolomites, silicates and synthetic absorbent materials in regard of their CO2 absorption capacity and absorption/desorption cyclic stability are presented and discussed. It has been found that the inert parts of the absorbent materials have a structure stabilizing effect, leading to an improved cyclic stability of the materials.

Bandi, A.; Specht, M.; Sichler, P.; Nicoloso, N.

2002-09-20T23:59:59.000Z

179

Effect of reformer conditions on catalytic reforming of biomass-gasification tars  

Science Conference Proceedings (OSTI)

Parametric tests on catalytic reforming of tars produced in biomass gasification are performed using a bench-scale, fluid-bed catalytic reformer containing a commercial nickel-based catalyst. The product gas composition and yield vary with reformer temperature, space time, and steam: biomass ratio. Under certain catalytic tar reforming conditions, the gas yield increases by 70%; 97% of the tars are cracked into gases; and benzene and naphthalene, the predominant tar species, are virtually eliminated from the product gas.

Kinoshita, C.M.; Wang, Y.; Zhou, J. [Univ. of Hawaii, Honolulu, HI (United States)

1995-09-01T23:59:59.000Z

180

Distributed Bio-Oil Reforming (Presentation)  

DOE Green Energy (OSTI)

This presentation by Bob Evans at the 2007 DOE Hydrogen Program Annual Merit Review Meeting provides information about NREL's distributed bio-oil reforming efforts.

Evans, R. J.; Czernik, S.; French, R.; Ratcliff, M.; Marda, J.; Dean, A. M.

2007-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

TransForum v4n2 - Diesel Reformer  

NLE Websites -- All DOE Office Websites (Extended Search)

1 ARGONNE SCIENTISTS TEAM UP TO DEVELOP NEW DIESEL REFORMER Liu tests diesel reformer Argonne's Di-Jia Liu conducted extensive testing of the diesel reformer; his experiments are...

182

An update on catalytic reforming  

Science Conference Proceedings (OSTI)

The UOP Platforming process is a catalytic reforming process in widespread use throughout the petroleum and petrochemical industries. Since the first unit went onstream in 1949, the process has become a standard feature in refineries worldwide. Over the years, significant improvements have been made in process catalysts and process design. The most recent improvement is the combination of a catalyst called R-72 with a new patented flow scheme, R-72 staged loading, which gives significantly higher yields and provides increased catalyst stability. In this article, the authors describe two types of Platforming processes and the new R-72 staged loading scheme.

Wei, D.H.; Moser, M.D.; Haizmann, R.S.

1996-10-01T23:59:59.000Z

183

Before House Committee on Oversight and Government Reform | Department...  

NLE Websites -- All DOE Office Websites (Extended Search)

Oversight and Government Reform Before House Committee on Oversight and Government Reform Testimony of Daniel Poneman, Deputy Secretary of Energy Before House Committee on...

184

Bio-Derived Liquids to Hydrogen Distributed Reforming Targets...  

NLE Websites -- All DOE Office Websites (Extended Search)

Group includes individuals from DOE, the national laboratories, industry, and academia. Corn Stover Harvest Bio-Derived Liquids Reforming Distributed reforming of biomass derived...

185

Regulatory and Financial Reform of Federal Research Policy: Recommenda...  

NLE Websites -- All DOE Office Websites (Extended Search)

and Financial Reform of Federal Research Policy: Recommendations to the NRC Committee on Research Universities Regulatory and Financial Reform of Federal Research Policy:...

186

Guidance_Application_Federal_Vacancies_Reform_Act_1998.pdf |...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

nceApplicationFederalVacanciesReformAct1998.pdf More Documents & Publications Intelligence Reform and Terroroism Prevention Act - December 17, 2004 Bond Amendment, Security...

187

Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

Reforming of Renewable Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) * U. (Balu) Balachandran, T. H. Lee, C. Y. Park, and S. E. Dorris Energy Systems Division E-mail: balu@anl.gov * Work supported by the Hydrogen, Fuel Cells, and Infrastructure Technologies Program of DOE's Office of Energy Efficiency and Renewable Energy Presented at the Bio-derived Liquids Working Group (BILIWG) Meeting, Nov. 6, 2007. BILIWG Meeting, Nov. 6, 2007 2 Objective & Rationale Objective: Develop compact dense ceramic membrane reactors that enable the efficient and cost-effective production of hydrogen by reforming renewable liquid fuels using pure oxygen produced by water splitting and transported by an OTM. Rationale: Membrane technology provides the means to attack barriers to the

188

Fuel cell integrated with steam reformer  

DOE Patents (OSTI)

A H.sub.2 -air fuel cell integrated with a steam reformer is disclosed wherein a superheated water/methanol mixture is fed to a catalytic reformer to provide a continuous supply of hydrogen to the fuel cell, the gases exhausted from the anode of the fuel cell providing the thermal energy, via combustion, for superheating the water/methanol mixture.

Beshty, Bahjat S. (Lower Makefield, PA); Whelan, James A. (Bricktown, NJ)

1987-01-01T23:59:59.000Z

189

School Finance Reform: Assessing General Equilibrium Effects  

E-Print Network (OSTI)

In 1994 the state of Michigan implemented one of the most comprehensive school finance reforms undertaken to date in any of the states. Understanding the effects of the reform is thus of value in informing other potential reform initiatives. In addition, the reform and associated changes in the economic environment provide an opportunity to assess whether a simple general equilibrium model can be of value in framing the study of such reform initiatives. In this paper, we present and use such a model to derive predictions about the effects of the reform on housing prices and neighborhood demographic compositions. Broadly, our analysis implies that the effects of the reform and changes in the economic environment are likely to have been reflected primarily in housing prices and only modestly on neighborhood demographics. We find that evidence for the Detroit metropolitan area from the decade encompassing the reform is largely consistent with the predictions of the model (JEL codes: H42, H71, H73, I22).

Maria Marta Ferreyra

2007-01-01T23:59:59.000Z

190

Octane Number Prediction in a Reforming Plant  

Science Conference Proceedings (OSTI)

In this work a neural network for the prediction of the complex and non-linear behavior of a Catalytic Reforming of a refinery has been developed. In a fuel, refinery reforming is a conversion process to increase octane number (RON) of the desulphurated ...

E. Chibaro

2000-07-01T23:59:59.000Z

191

Methanol Steam Reformer on a Silicon Wafer  

DOE Green Energy (OSTI)

A study of the reforming rates, heat transfer and flow through a methanol reforming catalytic microreactor fabricated on a silicon wafer are presented. Comparison of computed and measured conversion efficiencies are shown to be favorable. Concepts for insulating the reactor while maintaining small overall size and starting operation from ambient temperature are analyzed.

Park, H; Malen, J; Piggott, T; Morse, J; Sopchak, D; Greif, R; Grigoropoulos, C; Havstad, M; Upadhye, R

2004-04-15T23:59:59.000Z

192

New model accurately predicts reformate composition  

Science Conference Proceedings (OSTI)

Although naphtha reforming is a well-known process, the evolution of catalyst formulation, as well as new trends in gasoline specifications, have led to rapid evolution of the process, including: reactor design, regeneration mode, and operating conditions. Mathematical modeling of the reforming process is an increasingly important tool. It is fundamental to the proper design of new reactors and revamp of existing ones. Modeling can be used to optimize operating conditions, analyze the effects of process variables, and enhance unit performance. Instituto Mexicano del Petroleo has developed a model of the catalytic reforming process that accurately predicts reformate composition at the higher-severity conditions at which new reformers are being designed. The new AA model is more accurate than previous proposals because it takes into account the effects of temperature and pressure on the rate constants of each chemical reaction.

Ancheyta-Juarez, J.; Aguilar-Rodriguez, E. (Inst. Mexicano del Petroleo, Mexico City (Mexico))

1994-01-31T23:59:59.000Z

193

Cost Analysis of Bio-Derived Liquids Reforming (Presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

Analysis of Analysis of Bio-Derived Liquids Reforming Brian James Directed Technologies, Inc. 6 November 2007 This presentation does not contain any proprietary, confidential, or otherwise restricted information Objective * Assess cost of H 2 from bio-derived liquids * Looking at forecourt scale systems: 100-1500kg/day * Emphasis on Ethanol * Looking at both "conventional" and "advanced" systems * Interaction with the Researchers is bi-directional * Researchers help me with catalysts, performance, configurations * I can assist Researchers with system studies, configurations, and system performance estimates * Output of my work will be: * System/Configuration Definition * Performance specification & optimization * Capital cost estimation

194

FLUIDIZED BED STEAM REFORMING FOR TREATMENT AND IMMOBILIZATION OF LOW-ACTIVITY WASTE  

SciTech Connect

This report is one of four reports written to provide background information regarding immobilization technologies remaining under consideration for supplemental immobilization of Hanford's low-activity waste. This paper provides the reader a general understanding of fluidized bed steam reforming and its possible application to treat and immobilize Hanford low-activity waste.

HEWITT WM

2011-04-08T23:59:59.000Z

195

Autothermal Cyclic Reforming Based H2 Generating & Dispensing System  

E-Print Network (OSTI)

Pressure Reforming Comp- ressor 100 psig 100 psig Reformer H2 PSA SyngasNatural Gas Low Pressure Reforming CMP Syngas 5 psig5 psig Reformer CMP 100 psig H2 PSA Natural Gas Syngas CMP HX CMP HX Thermal Reliability (Eliminates Syngas Compressor) Advantages 70-80%70-80%Thermal Efficiency (Excludes Electricity

196

Electricity reform in developing and transition countries: A reappraisal  

E-Print Network (OSTI)

Electricity reform in developing and transition countries: A reappraisal J.H. Williams, R. Ghanadan-oriented reforms in their electric power sectors. Despite the widespread adoption of a standard policy model features of non-OECD electricity reform and reappraises reform policies and underlying assumptions

Kammen, Daniel M.

197

Diesel Reforming for Solid Oxide Fuel Cell Application  

DOE Green Energy (OSTI)

This presentation discusses the development of a diesel reforming catalyst and catalytic system development.

Liu, D-J.; Sheen, S-H.; Krumpelt, M.

2005-01-27T23:59:59.000Z

198

Internal reforming fuel cell assembly with simplified fuel feed  

DOE Patents (OSTI)

A fuel cell assembly in which fuel cells adapted to internally reform fuel and fuel reformers for reforming fuel are arranged in a fuel cell stack. The fuel inlet ports of the fuel cells and the fuel inlet ports and reformed fuel outlet ports of the fuel reformers are arranged on one face of the fuel cell stack. A manifold sealing encloses this face of the stack and a reformer fuel delivery system is arranged entirely within the region between the manifold and the one face of the stack. The fuel reformer has a foil wrapping and a cover member forming with the foil wrapping an enclosed structure.

Farooque, Mohammad (Huntington, CT); Novacco, Lawrence J. (Brookfield, CT); Allen, Jeffrey P. (Naugatuck, CT)

2001-01-01T23:59:59.000Z

199

SMALL SCALE FUEL CELL AND REFORMER SYSTEMS FOR REMOTE POWER  

DOE Green Energy (OSTI)

New developments in fuel cell technologies offer the promise of clean, reliable affordable power, resulting in reduced environmental impacts and reduced dependence on foreign oil. These developments are of particular interest to the people of Alaska, where many residents live in remote villages, with no roads or electrical grids and a very high cost of energy, where small residential power systems could replace diesel generators. Fuel cells require hydrogen for efficient electrical production, however. Hydrogen purchased through conventional compressed gas suppliers is very expensive and not a viable option for use in remote villages, so hydrogen production is a critical piece of making fuel cells work in these areas. While some have proposed generating hydrogen from renewable resources such as wind, this does not appear to be an economically viable alternative at this time. Hydrogen can also be produced from hydrocarbon feed stocks, in a process known as reforming. This program is interested in testing and evaluating currently available reformers using transportable fuels: methanol, propane, gasoline, and diesel fuels. Of these, diesel fuels are of most interest, since the existing energy infrastructure of rural Alaska is based primarily on diesel fuels, but this is also the most difficult fuel to reform, due to the propensity for coke formation, due to both the high vaporization temperature and to the high sulfur content in these fuels. There are several competing fuel cell technologies being developed in industry today. Prior work at UAF focused on the use of PEM fuel cells and diesel reformers, with significant barriers identified to their use for power in remote areas, including stack lifetime, system efficiency, and cost. Solid Oxide Fuel Cells have demonstrated better stack lifetime and efficiency in demonstrations elsewhere (though cost still remains an issue), and procuring a system for testing was pursued. The primary function of UAF in the fuel cell industry is in the role of third party independent testing. In order for tests to be conducted, hardware must be purchased and delivered. The fuel cell industry is still in a pre-commercial state, however. Commercial products are defined as having a fixed set of specifications, fixed price, fixed delivery date, and a warrantee. Negotiations with fuel cell companies over these issues are often complex, and the results of these discussions often reveal much about the state of development of the technology. This work includes some of the results of these procurement experiments. Fuel cells may one day replace heat engines as the source of electrical power in remote areas. However, the results of this program to date indicate that currently available hardware is not developed sufficiently for these environments, and that significant time and resources will need to be committed for this to occur.

Dennis Witmer

2003-12-01T23:59:59.000Z

200

Computational Fluid Dynamics Simulation of Steam Reforming and Autothermal Reforming for Fuel Cell Applications.  

E-Print Network (OSTI)

??With the increasing demand for fuel cell applications in transportation, the performance of reformers using gasoline or diesel as the fuel needs to be optimized.… (more)

Shi, Liming

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Bank Regulation and Mortgage Market Reform  

E-Print Network (OSTI)

America’s Housing Finance Market: A Report To Congress”,Subordinated Debt: A Capital Markets Approach to BankBank Regulation and Mortgage Market Reform Dwight M. Jaffee

Jaffee, Dwight M.

2011-01-01T23:59:59.000Z

202

Electricity reform abroad and US investment  

SciTech Connect

This report reviews and analyzes the recent electricity reforms in Argentina, Australia, and the United Kingdom (UK) to illustrate how different models of privatization and reform have worked in practice. This report also analyzes the motivations of the U.S. companies who have invested in the electricity industries in these countries, which have become the largest targets of U.S. foreign investment in electricity. Two calculations of foreign investment are used. One is the foreign direct investment series produced by the U.S. Department of Commerce. The other is based on transactions in electric utilities of the three countries. The electricity reform and privatization experiences reviewed may offer some insight as to how the U.S. electricity industry might develop as a result of recent domestic reform efforts and deregulation at the state and national levels. 126 refs., 23 figs., 27 tabs.

1997-10-01T23:59:59.000Z

203

Distributed Reforming of Biomass Pyrolysis Oils (Presentation...  

NLE Websites -- All DOE Office Websites (Extended Search)

gas (0.5% H 2 ) System Definition (1500 kgday station used for H2A analysis) Capital Costs Bio-Oil Reforming H2A Analysis Bio-Oil Case (Ethanol Case) Bio-oil Storage Tank...

204

Device for cooling and humidifying reformate  

Science Conference Proceedings (OSTI)

Devices for cooling and humidifying a reformate stream from a reforming reactor as well as related methods, modules and systems includes a heat exchanger and a sprayer. The heat exchanger has an inlet, an outlet, and a conduit between the inlet and the outlet. The heat exchanger is adapted to allow a flow of a first fluid (e.g. water) inside the conduit and to establish a heat exchange relationship between the first fluid and a second fluid (e.g. reformate from a reforming reactor) flowing outside the conduit. The sprayer is coupled to the outlet of the heat exchanger for spraying the first fluid exiting the heat exchanger into the second fluid.

Zhao, Jian Lian (Belmont, MA); Northrop, William F. (Ann Arbor, MI)

2008-04-08T23:59:59.000Z

205

Liquid fuel reformer development: Autothermal reforming of Diesel fuel  

DOE Green Energy (OSTI)

Argonne National Laboratory is developing a process to convert hydrocarbon fuels to clean hydrogen feeds for a polymer electrolyte fuel cell. The process incorporates an autothermal reforming catalyst that can process hydrocarbon feeds at lower temperatures than existing commercial catalysts. The authors have tested the catalyst with three diesel-type fuels: hexadecane, certified low-sulfur grade 1 diesel, and a standard grade 2 diesel. Hexadecane yielded products containing 60% hydrogen on a dry, nitrogen-free basis at 850 C, while maximum hydrogen product yields for the two diesel fuels were near 50%. Residual products in all cases included CO, CO{sub 2}, ethane, and methane. Further studies with grade 1 diesel showed improved conversion as the water:fuel ratio was increased from 1 to 2 at 850 C. Soot formation was reduced when the oxygen:carbon ratio was maintained at 1 at 850 C. There were no significant changes in hydrogen yield as the space velocity and the oxygen:fuel ratio were varied. Tests with a microchannel monolithic catalyst yielded similar or improved hydrogen levels at higher space velocities than with extruded pellets in a packed bed.

Pereira, C.; Bae, J-M.; Ahmed, S.; Krumpelt, M.

2000-07-24T23:59:59.000Z

206

Agenda for the Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Hydrogen Production Technical Team Research Review  

NLE Websites -- All DOE Office Websites (Extended Search)

& Hydrogen Production Technical Team Research Review Agenda for Tuesday, November 6, 2007 Location: BCS Incorporated, 8929 Stephens Road, Laurel, MD. 20723 410-997-7778 8:30 - 9:00 Continental Breakfast 9:00 DOE Targets, Tools and Technology o Bio-Derived Liquids to Hydrogen Distributed Reforming Targets DOE, Arlene Anderson o H2A Overview, NREL, Darlene Steward o Bio-Derived Liquids to Hydrogen Distributed Reforming Cost Analysis DTI, Brian James 10:00 Research Review o Low-Cost Hydrogen Distributed Production Systems, H2Gen, Sandy Thomas o Integrated Short Contact Time Hydrogen Generator, GE Global Research, Wei Wei o Distributed Bio-Oil Reforming, NREL, Darlene Steward o High Pressure Steam Ethanol Reforming, ANL, Romesh Kumar

207

Reforming of fuel inside fuel cell generator  

DOE Patents (OSTI)

Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream 1 and spent fuel stream 2. Spent fuel stream 1 is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream 1 and exhaust stream 2, and exhaust stream 1 is vented. Exhaust stream 2 is mixed with spent fuel stream 2 to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells. 1 fig.

Grimble, R.E.

1988-03-08T23:59:59.000Z

208

Reforming of fuel inside fuel cell generator  

DOE Patents (OSTI)

Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream I and spent fuel stream II. Spent fuel stream I is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream I and exhaust stream II, and exhaust stream I is vented. Exhaust stream II is mixed with spent fuel stream II to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells.

Grimble, Ralph E. (Finleyville, PA)

1988-01-01T23:59:59.000Z

209

Heat Transfer Limitations in Hydrogen Production Via Steam Reformation: The Effect of Reactor Geometry  

E-Print Network (OSTI)

Ratio Parameters in Steam-Reforming Hydrogen productionan Insufficient Parameter in the Steam-Reforming Process,”Impurities on the Methanol Steam-Reforming Process for Fuel

Vernon, David R.; Davieau, David D.; Dudgeon, Bryce A.; Erickson, Paul A.

2006-01-01T23:59:59.000Z

210

Engineering Study for a Full Scale Demonstration of Steam Reforming Black Liquor Gasification at Georgia-Pacific's Mill in Big Island, Virginia  

SciTech Connect

Georgia-Pacific Corporation performed an engineering study to determine the feasibility of installing a full-scale demonstration project of steam reforming black liquor chemical recovery at Georgia-Pacific's mill in Big Island, Virginia. The technology considered was the Pulse Enhanced Steam Reforming technology that was developed and patented by Manufacturing and Technology Conversion, International (MTCI) and is currently licensed to StoneChem, Inc., for use in North America. Pilot studies of steam reforming have been carried out on a 25-ton per day reformer at Inland Container's Ontario, California mill and on a 50-ton per day unit at Weyerhaeuser's New Bern, North Carolina mill.

Robert De Carrera; Mike Ohl

2002-03-19T23:59:59.000Z

211

Hydrogen generation utilizing integrated CO2 removal with steam reforming  

DOE Patents (OSTI)

A steam reformer may comprise fluid inlet and outlet connections and have a substantially cylindrical geometry divided into reforming segments and reforming compartments extending longitudinally within the reformer, each being in fluid communication. With the fluid inlets and outlets. Further, methods for generating hydrogen may comprise steam reformation and material adsorption in one operation followed by regeneration of adsorbers in another operation. Cathode off-gas from a fuel cell may be used to regenerate and sweep the adsorbers, and the operations may cycle among a plurality of adsorption enhanced reformers to provide a continuous flow of hydrogen.

Duraiswamy, Kandaswamy; Chellappa, Anand S

2013-07-23T23:59:59.000Z

212

Steam reforming as a method to treat Hanford underground storage tank (UST) wastes  

Science Conference Proceedings (OSTI)

This report summarizes a Sandia program that included partnerships with Lawrence Livermore National Laboratory and Synthetica Technologies, Inc. to design and test a steam reforming system for treating Hanford underground storage tank (UST) wastes. The benefits of steam reforming the wastes include the resolution of tank safety issues and improved radionuclide separations. Steam reforming destroys organic materials by first gasifying, then reacting them with high temperature steam. Tests indicate that up to 99% of the organics could be removed from the UST wastes by steam exposure. In addition, it was shown that nitrates in the wastes could be destroyed by steam exposure if they were first distributed as a thin layer on a surface. High purity alumina and nickel alloys were shown to be good candidates for materials to be used in the severe environment associated with steam reforming the highly alkaline, high nitrate content wastes. Work was performed on designing, building, and demonstrating components of a 0.5 gallon per minute (gpm) system suitable for radioactive waste treatment. Scale-up of the unit to 20 gpm was also considered and is feasible. Finally, process demonstrations conducted on non-radioactive waste surrogates were carried out, including a successful demonstration of the technology at the 0.1 gpm scale.

Miller, J.E.; Kuehne, P.B. [eds.] [and others

1995-07-01T23:59:59.000Z

213

Testing of a Catalytic Partial Oxidation Diesel Reformer with a Solid Oxide Fuel Cell System  

DOE Green Energy (OSTI)

Rural Alaska currently uses diesel generator sets to produce much of its power. The high energy content of diesel (i.e. ~140,000 BTU per gallon) makes it the fuel of choice because this reduces the volume of fuel that must be transported, stored, and consumed in generating the power. There is an existing investment in infrastructure for the distribution and use of diesel fuel. Problems do exist, however, in that diesel generators are not very efficient in their use of diesel, maintenance levels can be rather high as systems age, and the environmental issues related to present diesel generators are of concern. The Arctic Energy Technology Development Laboratory at the University of Alaska -- Fairbanks is sponsoring a project to address the issues mentioned above. The project takes two successful systems, a diesel reformer and a tubular solid oxide fuel cell unit, and jointly tests those systems with the objective of producing a for-purpose diesel fueled solid oxide fuel cell system that can be deployed in rural Alaska. The reformer will convert the diesel to a mixture of carbon monoxide and hydrogen that can be used as a fuel by the fuel cell. The high temperature nature of the solid oxide fuel cell (SOFC is capable of using this mixture to generate electricity and provide usable heat with higher efficiency and lower emissions. The high temperature nature of the SOFC is more compatible with the arctic climate than are low temperature technologies such as the proton exchange membrane fuel cells. This paper will look at the interaction of a SOFC system that is designed to internally reform methane and a catalytic partial oxidation (CPOX) diesel reformer. The diesel reformer produces a reformate that is approximately 140 BTU per scf (after removal of much of the reformate water) as compared to a methane based reformate that is over twice that value in BTU content. The project also considers the effect of altitude since the test location will be at 4800 feet with the consequential drop in oxygen content and necessary increases in flow rates.

Lyman Frost; Bob Carrington; Rodger McKain; Dennis Witmer

2005-03-01T23:59:59.000Z

214

Thermally integrated staged methanol reformer and method  

DOE Green Energy (OSTI)

A thermally integrated two-stage methanol reformer including a heat exchanger and first and second reactors colocated in a common housing in which a gaseous heat transfer medium circulates to carry heat from the heat exchanger into the reactors. The heat transfer medium comprises principally hydrogen, carbon dioxide, methanol vapor and water vapor formed in a first stage reforming reaction. A small portion of the circulating heat transfer medium is drawn off and reacted in a second stage reforming reaction which substantially completes the reaction of the methanol and water remaining in the drawn-off portion. Preferably, a PrOx reactor will be included in the housing upstream of the heat exchanger to supplement the heat provided by the heat exchanger.

Skala, Glenn William (Churchville, NY); Hart-Predmore, David James (Rochester, NY); Pettit, William Henry (Rochester, NY); Borup, Rodney Lynn (East Rochester, NY)

2001-01-01T23:59:59.000Z

215

Fundamental kinetic modeling of the catalytic reforming process  

Science Conference Proceedings (OSTI)

In this work, a fundamental kinetic model for the catalytic reforming process has been developed. The complex network of elementary steps and molecular reactions occurring in catalytic reforming has been generated through a computer algorithm characterizing ...

Rogelio Sotelo-Boyas / Gilbert F. Froment; Rayford G. Anthony

2005-01-01T23:59:59.000Z

216

Electricity reform in Chile : lessons for developing countries  

E-Print Network (OSTI)

Chile was the first country in the world to implement a comprehensive reform of its electricity sector in the recent period. Among developing countries only Argentina has had a comparably comprehensive and successful reform. ...

Pollitt, Michael G.

2004-01-01T23:59:59.000Z

217

Before the House Oversight and Government Reform Subcommittee...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Government Management, Organization, and Procurement Before the House Oversight and Government Reform Subcommittee on Government Management, Organization, and Procurement Before...

218

Cost Analysis of Bio-Derived Liquids Reforming  

E-Print Network (OSTI)

) steam reforming C2H5OH + H2O Ă? 2CO + 4H2 6) Water gas shift 7) Methanation 8) Coking from CH4 (methane Ethanol Reforming Options Gas Phase Liquid Phase Virent Steam Partial Oxidation Reforming GE (SCPO) decomposition C2H5OH Ă? CH4 + CO + H2 steam reforming CH4 + 2H2O Ă? 4H2 + CO2 3) C2H5OH dehydrogenation

219

New Jersey Refinery Catalytic Reforming/High Pressure Downstream ...  

U.S. Energy Information Administration (EIA)

New Jersey Refinery Catalytic Reforming/High Pressure Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

220

Arkansas Refinery Catalytic Reforming/High Pressure Downstream ...  

U.S. Energy Information Administration (EIA)

Arkansas Refinery Catalytic Reforming/High Pressure Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

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221

Simulation of terrace wall methane-steam reforming reactors  

Science Conference Proceedings (OSTI)

Terrace wall arrangement is one of the most common arrangements for methane-steam reforming reactor furnaces. In this work, a mathematical model of heat transfer in terrace wall furnaces has been developed. The model has been coupled with a reliable ... Keywords: heat transfer modeling, methane-steam reforming, reformer simulation, terrace wall furnace

J. S. Soltan Mohammadzadeh; A. Zamaniyan

2002-08-01T23:59:59.000Z

222

Integrated autothermal reactor concepts for oxidative coupling and reforming of  

E-Print Network (OSTI)

. . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 1.3 Oxidative coupling and steam reforming of methane . . . . . . . . . . 5 1.4 This thesis of methane . . . . . . . . . . . . . . . . . . . 23 2.4 Only steam reforming of methane#12;Integrated autothermal reactor concepts for oxidative coupling and reforming of methane #12

Twente, Universiteit

223

Legal aspects of Internet governance reform  

Science Conference Proceedings (OSTI)

The Internet has moved on from its early almost lawless nature. There are now multiple organisations and legal aspects associated with Internet governance. Whether the issue on the Internet is network security, intellectual property rights (IPRs), e-commerce, ... Keywords: ICANN, WGIG, WSIS, cybercrime, framework, governance, internet, law, reform, treaty

David Satola

2007-01-01T23:59:59.000Z

224

Catalytic partial oxidation reforming of hydrocarbon fuels.  

DOE Green Energy (OSTI)

The polymer electrolyte fuel cell (PEFC) is the primary candidate as the power source for light-duty transportation systems. On-board conversion of fuels (reforming) to supply the required hydrogen has the potential to provide the driving range that is typical of today's automobiles. Petroleum-derived fuels, gasoline or some distillate similar to it, are attractive because of their existing production, distribution, and retailing infrastructure. The fuel may be either petroleum-derived or other alternative fuels such as methanol, ethanol, natural gas, etc. [1]. The ability to use a variety of fuels is also attractive for stationary distributed power generation [2], such as in buildings, or for portable power in remote locations. Argonne National Laboratory has developed a catalytic reactor based on partial oxidation reforming that is suitable for use in light-duty vehicles powered by fuel cells. The reactor has shown the ability to convert a wide variety of fuels to a hydrogen-rich gas at less than 800 C, temperatures that are several hundreds of degrees lower than alternative noncatalytic processes. The fuel may be methanol, ethanol, natural gas, or petroleum-derived fuels that are blends of various hydrocarbons such as paraffins, olefins, aromatics, etc., as in gasoline. This paper will discuss the results obtained from a bench-scale (3-kWe) reactor., where the reforming of gasoline and natural gas generated a product gas that contained 38% and 42% hydrogen on a dry basis at the reformer exit, respectively.

Ahmed, S.

1998-09-21T23:59:59.000Z

225

Five Kilowatt Solid Oxide Fuel Cell/Diesel Reformer  

DOE Green Energy (OSTI)

Reducing fossil fuel consumption both for energy security and for reduction in global greenhouse emissions has been a major goal of energy research in the US for many years. Fuel cells have been proposed as a technology that can address both these issues--as devices that convert the energy of a fuel directly into electrical energy, they offer low emissions and high efficiencies. These advantages are of particular interest to remote power users, where grid connected power is unavailable, and most electrical power comes from diesel electric generators. Diesel fuel is the fuel of choice because it can be easily transported and stored in quantities large enough to supply energy for small communities for extended periods of time. This projected aimed to demonstrate the operation of a solid oxide fuel cell on diesel fuel, and to measure the resulting efficiency. Results from this project have been somewhat encouraging, with a laboratory breadboard integration of a small scale diesel reformer and a Solid Oxide Fuel Cell demonstrated in the first 18 months of the project. This initial demonstration was conducted at INEEL in the spring of 2005 using a small scale diesel reformer provided by SOFCo and a fuel cell provided by Acumentrics. However, attempts to integrate and automate the available technology have not proved successful as yet. This is due both to the lack of movement on the fuel processing side as well as the rather poor stack lifetimes exhibited by the fuel cells. Commercial product is still unavailable, and precommercial devices are both extremely expensive and require extensive field support.

Dennis Witmer; Thomas Johnson

2008-12-31T23:59:59.000Z

226

March 16, 2010, Safety and Security Reform Roundtable - Agenda  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Safety and Security Reform Roundtable Safety and Security Reform Roundtable Forrestal Building, Washington, DC March 16 th , 2010 1:00 PM (EST) AGENDA * Introduction of Union Leaders Glenn Podonsky, Chief Health, Safety and Security Officer * Welcome/Introductory Remarks on Reform Goals Dan Poneman, Deputy Secretary * Reform Status and Approach - Oversight, Directives, Mission Support Glenn Podonsky, Chief Health, Safety and Security Officer * Discussion Forum - Union Feedback - Feedback on oversight reform initiatives - Priority safety issues - Experience in collaborative focus group efforts - Recommendations for a path forward * Operating Organization Perspectives 1. Tom D'Agostino Administrator, National Nuclear Security Administration 2. Steven Koonin Under Secretary for Science

227

Effect of reaction pressure on octane number and reformate and hydrogen yields in catalytic reforming  

Science Conference Proceedings (OSTI)

The effect of reaction pressure in catalytic reforming was studied in a pilot reactor with a commercial Pt-Re/Al{sub 2}O{sub 3} reforming catalyst and a hydrotreated naphtha from a North Sea crude. Reformate and hydrogen yields, research octane numbers (RON), and reformate composition at reactor pressures in the range of 12--25 bar were measured as a function of temperature in the range of 95--105 RON. Reformate and hydrogen yields increased as the pressure range. For the lower reaction pressures the hydrogen yields increased with increasing severity, but for the higher pressures the hydrogen yields started to decline above certain severities. RON was linearly dependent on the concentration of aromatics in the reformate, although the selectivity toward aromatics depends on both pressure and temperature. Less hydro dealkylation of C{sub 8} and heavier aromatics to benzene and toluene resulted in a shift toward xylenes and heavier aromatic components when pressure was lowered. Variations in the degree of paraffin isomerization did not influence RON significantly at those severities.

Moljord, K.; Hellenes, H.G.; Hoff, A.; Tanem, I. [SINTEF Applied Chemistry, Trondheim (Norway); Grande, K. [Statoil Research Centre, Trondheim (Norway); Holmen, A. [Univ. of Trondheim (Norway). Dept. Industrial Chemistry

1996-01-01T23:59:59.000Z

228

THE EFFECT OF SULFUR ON METHANE PARTIAL OXIDATION AND REFORMING PROCESSES FOR LEAN NOX TRAP CATALYSIS  

Science Conference Proceedings (OSTI)

Lean NOx trap catalysis has demonstrated the ability to reduce NOx emissions from lean natural gas reciprocating engines by >90%. The technology operates in a cyclic fashion where NOx is trapped on the catalyst during lean operation and released and reduced to N2 under rich exhaust conditions; the rich cleansing operation of the cycle is referred to as "regeneration" since the catalyst is reactivated for more NOx trapping after NOx purge. Creating the rich exhaust conditions for regeneration can be accomplished by catalytic partial oxidation of methane in the exhaust system. Furthermore, catalytic reforming of partial oxidation exhaust can enable increased quantities of H2 which is an excellent reductant for lean NOx trap regeneration. It is critical to maintain clean and efficient partial oxidation and reforming processes to keep the lean NOx trap functioning properly and to reduce extra fuel consumption from the regeneration process. Although most exhaust constituents do not impede partial oxidation and reforming, some exhaust constituents may negatively affect the catalysts and result in loss of catalytic efficiency. Of particular concern are common catalyst poisons sulfur, zinc, and phosphorous. These poisons form in the exhaust through combustion of fuel and oil, and although they are present at low concentrations, they can accumulate to significant levels over the life of an engine system. In the work presented here, the effects of sulfur on the partial oxidation and reforming catalytic processes were studied to determine any durability limitations on the production of reductants for lean NOx trap catalyst regeneration.

Parks, II, James E [ORNL; Ponnusamy, Senthil [ORNL

2006-01-01T23:59:59.000Z

229

Hydrocarbon reforming catalyst material and configuration of the same  

DOE Patents (OSTI)

A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall. 5 figs.

Singh, P.; Shockling, L.A.; George, R.A.; Basel, R.A.

1996-06-18T23:59:59.000Z

230

Hydrocarbon reforming catalyst material and configuration of the same  

DOE Patents (OSTI)

A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall.

Singh, Prabhakar (Export, PA); Shockling, Larry A. (Plum Borough, PA); George, Raymond A. (Pittsburgh, PA); Basel, Richard A. (Plub Borough, PA)

1996-01-01T23:59:59.000Z

231

Autothermal reforming catalyst having perovskite structure  

DOE Patents (OSTI)

The invention addressed two critical issues in fuel processing for fuel cell application, i.e. catalyst cost and operating stability. The existing state-of-the-art fuel reforming catalyst uses Rh and platinum supported over refractory oxide which add significant cost to the fuel cell system. Supported metals agglomerate under elevated temperature during reforming and decrease the catalyst activity. The catalyst is a perovskite oxide or a Ruddlesden-Popper type oxide containing rare-earth elements, catalytically active firs row transition metal elements, and stabilizing elements, such that the catalyst is a single phase in high temperature oxidizing conditions and maintains a primarily perovskite or Ruddlesden-Popper structure under high temperature reducing conditions. The catalyst can also contain alkaline earth dopants, which enhance the catalytic activity of the catalyst, but do not compromise the stability of the perovskite structure.

Krumpel, Michael (Naperville, IL); Liu, Di-Jia (Naperville, IL)

2009-03-24T23:59:59.000Z

232

Operation of a solid oxide fuel cell on biodiesel with a partial oxidation reformer  

Science Conference Proceedings (OSTI)

The National Energy Technology Laboratory’s Office of Research & Development (NETL/ORD) has successfully demonstrated the operation of a solid oxide fuel cell (SOFC) using reformed biodiesel. The biodiesel for the project was produced and characterized by West Virginia State University (WVSU). This project had two main aspects: 1) demonstrate a catalyst formulation on monolith for biodiesel fuel reforming; and 2) establish SOFC stack test stand capabilities. Both aspects have been completed successfully. For the first aspect, in–house patented catalyst specifications were developed, fabricated and tested. Parametric reforming studies of biofuels provided data on fuel composition, catalyst degradation, syngas composition, and operating parameters required for successful reforming and integration with the SOFC test stand. For the second aspect, a stack test fixture (STF) for standardized testing, developed by Pacific Northwest National Laboratory (PNNL) and Lawrence Berkeley National Laboratory (LBNL) for the Solid Energy Conversion Alliance (SECA) Program, was engineered and constructed at NETL. To facilitate the demonstration of the STF, NETL employed H.C. Starck Ceramics GmbH & Co. (Germany) anode supported solid oxide cells. In addition, anode supported cells, SS441 end plates, and cell frames were transferred from PNNL to NETL. The stack assembly and conditioning procedures, including stack welding and sealing, contact paste application, binder burn-out, seal-setting, hot standby, and other stack assembly and conditioning methods were transferred to NETL. In the future, fuel cell stacks provided by SECA or other developers could be tested at the STF to validate SOFC performance on various fuels. The STF operated on hydrogen for over 1000 hrs before switching over to reformed biodiesel for 100 hrs of operation. Combining these first two aspects led to demonstrating the biodiesel syngas in the STF. A reformer was built and used to convert 0.5 ml/min of biodiesel into mostly hydrogen and carbon monoxide (syngas.) The syngas was fed to the STF and fuel cell stack. The results presented in this experimental report document one of the first times a SOFC has been operated on syngas from reformed biodiesel.

Siefert, N, Shekhawat, D.; Gemmen, R.; Berry, D.

2010-01-01T23:59:59.000Z

233

Biomass Gasification Technology Assessment: Consolidated Report  

SciTech Connect

Harris Group Inc. (HGI) was commissioned by the National Renewable Energy Laboratory to assess gasification and tar reforming technologies. Specifically, the assessments focused on gasification and tar reforming technologies that are capable of producing a syngas suitable for further treatment and conversion to liquid fuels. HGI gathered sufficient information to analyze three gasification and tar reforming systems. This report summarizes the equipment, general arrangement of the equipment, operating characteristics, and operating severity for each technology. The order of magnitude capital cost estimates are supported by a basis-of-estimate write-up, which is also included in this report. The report also includes Microsoft Excel workbook models, which can be used to design and price the systems. The models can be used to analyze various operating capacities and pressures. Each model produces a material balance, equipment list, capital cost estimate, equipment drawings and preliminary general arrangement drawings. Example outputs of each model are included in the Appendices.

Worley, M.; Yale, J.

2012-11-01T23:59:59.000Z

234

Purification of reformer streams by catalytic hydrogenation  

Science Conference Proceedings (OSTI)

Catalytic Reforming is one of the most important processes to produce high grade motor gasolines. Feedstocks are mainly gasoline and naphtha streams from the crude oil distillation boiling in the range of 212 F to 350 F. By catalytic reforming the octane number of these gasoline components is increased from 40--60 RON to 95--100 RON. Besides isomerization and dehydrocyclization reactions mainly formation of aromatics by dehydrogenation of naphthenes occur. Thus, catalytic reformers within refineries are an important source of BTX--aromatics (benzene, toluene, xylenes). Frequently, high purity aromatics are recovered from these streams using modern extractive distillation or liquid extraction processes, e.g. the Krupp-Koppers MORPHYLANE{reg_sign} process. Aromatics product specifications, notably bromine index and acid wash color, have obligated producers to utilize clay treatment to remove trace impurities of diolefins and/or olefins. The conventional clay treatment is a multiple vessel batch process which periodically requires disposal of the spent clay in a suitable environmental manner. BASF, in close cooperation with Krupp-Koppers, has developed a continuous Selective Catalytic Hydrogenation Process (SCHP) as an alternative to clay treatment which is very efficient, cost effective and environmentally compatible. In the following the main process aspects including the process scheme catalyst and operating conditions is described.

Polanek, P.J. [BASF Corp., Geismar, LA (United States); Hooper, H.M. [Krupp Wilputte Corp., Bridgeville, PA (United States); Mueller, J.; Walter, M. [BASF AG, Ludwigshafen (Germany); Emmrich, G. [Krupp Koppers GmbH, Essen (Germany)

1996-12-01T23:59:59.000Z

235

Chemical Looping Reforming for H2, CO and Syngas Production  

SciTech Connect

We demonstrate that the extension of CLC onto oxidants beyond air opens new, highly efficient pathways for production of ultra-pure hydrogen, activation of CO{sub 2} via reduction to CO, and are currently working on production of syngas using nanocomposite Fe-BHA. CLR hold great potential due to fuel flexibility and CO{sub 2} capture. Chemical Looping Combustion (CLC) is a novel clean combustion technology which offers an elegant and highly efficient route for fossil fuel combustion. In CLC, combustion of a fuel is broken down into two spatially separated steps. In the reducer, the oxygen carrier (typically a metal) supplies the stoichiometric oxygen required for fuel combustion. In the oxidizer, the oxygen-depleted carrier is then re-oxidized with air. After condensation of steam from the effluent of the reducer, a high-pressure, high-purity sequestration-ready CO{sub 2} stream is obtained. In the present study, we apply the CLC principle to the production of high-purity H{sub 2}, CO, and syngas streams by replacing air with steam and/or CO{sub 2} as oxidant, respectively. Using H{sub 2}O as oxidant, pure hydrogen streams can be obtained. Similarly, using CO{sub 2} as oxidant, CO is obtained, thus opening an efficient route for CO{sub 2} utilization. Using steam and CO{sub 2} mixtures for carrier oxidation should thus allow production of syngas with adjustable CO:H{sub 2} ratios. Overall, these processes result in Chemical Looping Reforming (CLR), i.e. the net overall reaction is the steam and/or dry reforming of the respective fuel.

Bhavsar,Saurabh; Najera,Michelle; Solunke,Rahul; Veser,Götz

2001-06-06T23:59:59.000Z

236

Autothermal Reforming of Natural Gas to Synthesis Gas  

DOE Green Energy (OSTI)

This Project Final Report serves to document the project structure and technical results achieved during the 3-year project titled Advanced Autothermal Reformer for US Dept of Energy Office of Industrial Technology. The project was initiated in December 2001 and was completed March 2005. It was a joint effort between Sandia National Laboratories (Livermore, CA), Kellogg Brown & Root LLC (KBR) (Houston, TX) and Süd-Chemie (Louisville, KY). The purpose of the project was to develop an experimental capability that could be used to examine the propensity for soot production in an Autothermal Reformer (ATR) during the production of hydrogen-carbon monoxide synthesis gas intended for Gas-to-Liquids (GTL) applications including ammonia, methanol, and higher hydrocarbons. The project consisted of an initial phase that was focused on developing a laboratory-scale ATR capable of reproducing conditions very similar to a plant scale unit. Due to budget constraints this effort was stopped at the advanced design stages, yielding a careful and detailed design for such a system including ATR vessel design, design of ancillary feed and let down units as well as a PI&D for laboratory installation. The experimental effort was then focused on a series of measurements to evaluate rich, high-pressure burner behavior at pressures as high as 500 psi. The soot formation measurements were based on laser attenuation at a view port downstream of the burner. The results of these experiments and accompanying calculations show that soot formation is primarily dependent on oxidation stoichiometry. However, steam to carbon ratio was found to impact soot production as well as burner stability. The data also showed that raising the operating pressure while holding mass flow rates constant results in considerable soot formation at desirable feed ratios. Elementary reaction modeling designed to illuminate the role of CO2 in the burner feed showed that the conditions in the burner allow for the direct participation of CO2 in the oxidation chemistry.

Steven F. Rice; David P. Mann

2007-04-13T23:59:59.000Z

237

Autothermal Reforming of Renewable Fuels  

DOE Green Energy (OSTI)

The conversion of biomass into energy and chemicals is a major research and technology challenge of this century, comparable to petroleum processing in the last century. Recently we have successfully transformed both volatile liquids and nonvolatile liquids and solids into syngas with no carbon formation in autothermal catalytic reactors with residence times of ~10 milliseconds. In the proposed research program we explore the mechanisms of these processes and their extensions to other biomass sources and applications by examining different feeds, catalysts, flow conditions, and steam addition to maximize production of either syngas or chemicals. We will systematically study the catalytic partial oxidation in millisecond autothermal reactors of solid biomass and the liquid products formed by pyrolysis of solid biomass. We will examine alcohols, polyols, esters, solid carbohydrates, and lignocellulose to try to maximize formation of either hydrogen and syngas or olefins and oxygenated chemicals. We will explore molecules and mixtures of practical interest as well as surrogate molecules that contain the functional groups of biofuels but are simpler to analyze and interpret. We will examine spatial profiles within the catalyst and transient and periodic operation of these reactors at pressures up to 10 atm to obtain data from which to explore more detailed mechanistic models and optimize performance to produce a specific desired product. New experiments will examine the conversion of syngas into biofuels such as methanol and dimethyl ether to explore the entire process of producing biofuels from biomass in small distributed systems. Experiments and modeling will be integrated to probe and understand detailed reaction kinetics and the processes by which solid biomass particles are transformed into syngas and chemicals by reactive flash volatilization.

Schmidt, Lanny D

2009-05-01T23:59:59.000Z

238

Partial oxidation fuel reforming for automotive power systems.  

DOE Green Energy (OSTI)

For widespread use of fuel cells to power automobiles in the near future, it is necessary to convert gasoline or other transportation fuels to hydrogen on-board the vehicle. Partial oxidation reforming is particularly suited to this application as it eliminates the need for heat exchange at high temperatures. Such reformers offer rapid start and good dynamic performance. Lowering the temperature of the partial oxidation process, which requires the development of a suitable catalyst, can increase the reforming efficiency. Catalytic partial oxidation (or autothermal) reformers and non-catalytic partial oxidation reformers developed by various organizations are presently undergoing testing and demonstration. This paper summarizes the process chemistries as well as recent test data from several different reformers operating on gasoline, methanol, and other fuels.

Ahmed, S.; Chalk, S.; Krumpelt, M.; Kumar, R.; Milliken, J.

1999-09-07T23:59:59.000Z

239

Phase 2 THOR Steam Reforming Tests for Sodium Bearing Waste Treatment  

Science Conference Proceedings (OSTI)

About one million gallons of acidic, hazardous, and radioactive sodium-bearing waste is stored in stainless steel tanks at the Idaho Nuclear Technology and Engineering Center (INTEC), which is a major operating facility of the Idaho National Engineering and Environmental Laboratory. Steam reforming is a candidate technology being investigated for converting the waste into a road ready waste form that can be shipped to the Waste Isolation Pilot Plant in New Mexico for interment. A steam reforming technology patented by Studsvik, Inc., and licensed to THOR Treatment Technologies has been tested in two phases using a Department of Energy-owned fluidized bed test system located at the Science Applications International Corporation (SAIC) Science and Technology Applications Research Center located in Idaho Falls, Idaho. The Phase 1 tests were reported earlier in 2003. The Phase 2 tests are reported here. For Phase 2, the process feed rate, stoichiometry, and chemistry were varied to identify and demonstrate process operation and product characteristics under different operating conditions. Two test series were performed. During the first series, the process chemistry was designed to produce a sodium carbonate product. The second series was designed to produce a more leach-resistant, mineralized sodium aluminosilicate product. The tests also demonstrated the performance of a MACT-compliant off-gas system.

Nicholas R. Soelberg

2004-01-01T23:59:59.000Z

240

Phase 2 TWR Steam Reforming Test for Sodium-Bearing Waste Treatment  

SciTech Connect

About one million gallons of acidic, hazardous, and radioactive sodium-bearing waste (SBW) is stored in stainless steel tanks a the Idaho Nuclear Technology and Engineering Center (INTEC), which is a major operating facility of the Idaho National Engineering and Environmental Laboratory (INEEL). Steam reforming is a candidate technology being investigated for converting the SBW into a road ready waste form that can be shipped to the Waste Isolation Pilot Plant in New Mexico for interment. Fluidized bed steam reforming technology, licensed to ThermoChem Waste Remediation, LLC (TWR) by Manufacturing Technology Conversion International, was tested in two phases using an INEEL (Department of Energy) fluidized bed test system located at the Science Applications International Corporation (SAIC) Science and Technology Applications Research Center in Idaho Falls, Idaho. The Phase 1 tests were reported earlier. The Phase 2 tests are reported here. For Phase 2, the process feed rate, reductant stoichiometry, and process temperature were varied to identify and demonstrate how the process might be optimized to improve operation and product characteristics. The first week of testing was devoted primarily to process chemistry and the second week was devoted more toward bed stability and particle size control.

Nicholas R. Soelberg; Doug Marshall; Dean Taylor; Steven Bates

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Will electricity market reform likely reduce retail rates?  

Science Conference Proceedings (OSTI)

To win public support, proponents for electricity market reform to introduce competition often promise that the post-reform retail rates will be lower than the average embedded cost rates that would have prevailed under the status quo of a regulated monopoly. A simple economic analysis shows that such a promise is unlikely to occur without the critical assumption that the post-reform market has marginal costs below average costs. (author)

Woo, C.K.; Zarnikau, Jay

2009-03-15T23:59:59.000Z

242

Compatibility of selected ceramics with steam-methane reformer environments  

DOE Green Energy (OSTI)

Conventional steam reforming of methane to synthesis gas (CO and H{sub 2}) hasa conversion efficiency of about 85%. Replacement of metal tubes in the reformer with ceramic tubes offers the potential for operation at temperatures high enough to increase the efficiency to 98-99%. However, the two candidate ceramic materials being given strongest consideration, sintered alpha Si carbide and Si carbide particulate-strengthened alumina, have been shown to react with components of the reformer environment. Extent of degradation as a function of steam partial pressure and exposure time has been studied, and results suggest limits under which these structural ceramics can be used in advanced steam-methane reformers.

Keiser, J.R.; Howell, M. [Oak Ridge National Lab., TN (United States); Williams, J.J.; Rosenberg, R.A. [Stone and Webster Engineering Corp., Boston, MA (United States)

1996-04-01T23:59:59.000Z

243

Thermodynamic and Experimental Study on the Steam Reforming ...  

Science Conference Proceedings (OSTI)

For improving hydrogen yield, a new system for steam reforming of bio-oil with site ... Kinetic Modeling Study of Oxy-methane Combustion at Ordinary Pressure.

244

Women and the reform of the welfare system: An introduction  

Science Conference Proceedings (OSTI)

This special issue of Gender Issues, one of a three-part series, examines the welfare reform measures initiated a decade ago and their consequences for ...

245

Kinetics of Supercritical Water Reformation of Ethanol to H  

Science Conference Proceedings (OSTI)

Sep 16, 2007 ... Description Kinetics of the supercritical water reformation of ethanol was experimentally studied in a tubular reactor made of Inconel 625 alloy.

246

Catalytic reforming boosts octane for gasoline blending - Today in ...  

U.S. Energy Information Administration (EIA)

Because reformate contains significant amounts of benzene, toluene, and xylene, it also is an important source of feedstock for the petrochemical industry.

247

New process model proves accurate in tests on catalytic reformer  

Science Conference Proceedings (OSTI)

A mathematical model has been devised to represent the process that takes place in a fixed-bed, tubular, adiabatic catalytic reforming reactor. Since its development, the model has been applied to the simulation of a commercial semiregenerative reformer. The development of mass and energy balances for this reformer led to a model that predicts both concentration and temperature profiles along the reactor. A comparison of the model's results with experimental data illustrates its accuracy at predicting product profiles. Simple steps show how the model can be applied to simulate any fixed-bed catalytic reformer.

Aguilar-Rodriguez, E.; Ancheyta-Juarez, J. (Inst. Mexicano del Petroleo, Mexico City (Mexico))

1994-07-25T23:59:59.000Z

248

 

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

A mixed waste treatability study will be performed to test the fluidized bed steam reforming (FBSR) technology on a composite of two caustic Hanford A mixed waste treatability study will be performed to test the fluidized bed steam reforming (FBSR) technology on a composite of two caustic Hanford tank waste streams (AZ101 and AZ102). The tests will be performed in SRNL 773-A Shielded Cells, A-block with portions being completed in B-wing and in the Analytical Development labs. Approximately, 1.5 L of each waste stream will be fed to the process over the course of ~15 runs (<100 mL of waste per run). Steam Reforming Treatability Study with Hanford Sample E Savannah River Site Aiken South Carolina TC-A-2011-0004, Rev.0 Feb 10, 2011 Andrew R. Grainger Digitally signed by Andrew R. Grainger DN: cn=Andrew R. Grainger, o=DOE-SR, ou=EQMD, email=drew.grainger@srs.gov, c=US Date: 2011.03.16 14:24:12

249

Report for Treating Hanford LAW and WTP SW Simulants: Pilot Plant Mineralizing Flowsheet  

SciTech Connect

The US Department of Energy is responsible for managing the disposal of radioactive liquid waste in underground storage tanks at the Hanford site in Washington State. The Hanford waste treatment and immobilization plant (WPT) will separate the waste into a small volume of high level waste (HLW), containing most of the radioactive constituents, and a larger volume of low activity waste (LAW), containing most of the non-radioactive chemical and hazardous constituents. The HLW and LAW will be converted into immobilized waste forms for disposal. Currently there is inadequate LAW vitrification capacity planned at the WTP to complete the mission within the required timeframe. Therefore additional LAW capacity is required. One candidate supplemental treatment technology is the fluidized bed steam reformer process (FBSR). This report describes the demonstration testing of the FBSR process using a mineralizing flowsheet for treating simulated Hanford LAW and secondary waste from the WTP (WTP SW). The FBSR testing project produced leach-resistant solid products and environmentally compliant gaseous effluents. The solid products incorporated normally soluble ions into an alkali alumino-silicate (NaS) mineral matrix. Gaseous emissions were found to be within regulatory limits. Cesium and rhenium were captured in the mineralized products with system removal efficiencies of 99.999% and 99.998 respectively. The durability and leach performance of the FBSR granular solid were superior to the low activity reference material (LMR) glass standards. Normalized product consistency test (PCT) release rates for constituents of concern were approximately 2 orders of magnitude less than that of sodium in the Hanford glass [standard].

Arlin Olson

2012-02-28T23:59:59.000Z

250

Analysis of Chemically Reacting Gas Flow and Heat Transfer in Methane Reforming Processes  

Science Conference Proceedings (OSTI)

This paper presents simulation and analysis of gas flow and heat transfer affected by chemical reactions relating to steam reforming of methane in a compact reformer. The reformer conditions such as the combined thermal boundary conditions on solid walls, ...

Guogang Yang; Danting Yue; Xinrong Lv; Jinliang Yuan

2009-10-01T23:59:59.000Z

251

Process for removal of polynuclear aromatics from a hydrocarbon in an endothermic reformer reaction system  

Science Conference Proceedings (OSTI)

A process is described for reforming a hydrocarbon in a multi-stage endothermic reforming series of catalytic reforming reactors where the hydrocarbon is passed through the series of catalytic reforming reactors to form a reformate. The hydrocarbon is heated prior to entry to the next catalytic reforming reactor in the series, which process comprises contact of the hydrocarbon intermediate from the series of catalytic reforming reactors containing reforming catalyst with a polynuclear aromatic adsorbent to adsorb at least a portion of the polynuclear aromatic content from the hydrocarbon prior to entry to each of the next catalytic reforming reactor in the series and recovering a reformate from the last catalytic reforming reactor in the series, the recovered reformate having a reduced content of polynuclear aromatics.

Ngan, D.Y.

1989-02-14T23:59:59.000Z

252

Steam Reforming Application for Treatment of DOE Sodium Bearing Tank Wastes at INL for ICP  

SciTech Connect

The patented THOR® steam reforming waste treatment technology has been selected as the technology of choice for treatment of Sodium Bearing Waste (SBW) at the Idaho National Laboratory (INL) for the Idaho Cleanup Project (ICP). SBW is an acidic tank waste at the Idaho Nuclear Technology and Engineering Center (INTEC) at INL. It consists primarily of waste from decontamination activities and laboratory wastes. SBW contains high concentrations of nitric acid, alkali and aluminum nitrates, with minor amounts of many inorganic compounds including radionuclides, mainly cesium and strontium. The THOR® steam reforming process will convert the SBW tank waste feed into a dry, solid, granular product. The THOR® technology was selected to treat SBW, in part, because it can provide flexible disposal options to accommodate the final disposition path selected for SBW. THOR® can produce a final end-product that will meet anticipated requirements for disposal as Remote-Handled TRU (RH-TRU) waste; and, with modifications, THOR® can also produce a final endproduct that could be qualified for disposal as High Level Waste (HLW). SBW treatment will be take place within the Integrated Waste Treatment Unit (IWTU), a new facility that will be located at the INTEC. This paper provides an overview of the THOR® process chemistry and process equipment being designed for the IWTU.

J. Bradley Mason; Kevin Ryan; Scott Roesener; Michael Cowen; Duane Schmoker; Pat Bacala; Bill Landman

2006-03-01T23:59:59.000Z

253

NEPA Contracting Reform Guidance (December 1996)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

defining early what contractors should accomplish defining early what contractors should accomplish < establishing contracts ahead of time < minimizing cost while maintaining quality by * maximizing competition and use of incentives * using past performance information in awarding work * managing the NEPA process as a project This guidance provides: < model statements of work < information on contract types and incentives < direction on effective NEPA contract management by the NEPA Document Manager < a system for measuring NEPA process costs < NEPA contractor evaluation procedures < details on the DOE NEPA Web site U.S. Department of Energy, Office of NEPA Policy and Assistance, December 1996 NEPA CONTRACTING REFORM GUIDANCE Table of Contents 1. INTRODUCTION . . . . . . . . . . . . . . . . . . . . . .

254

Noble metal alkaline zeolites for catalytic reforming  

Science Conference Proceedings (OSTI)

This patent describes a method for producing a noble-metal containing zeolite suitable for catalytic reforming contacting a zeolite selected from alkaline faujasites and L zeolites and zeolites and zeolites isostructural thereto, with a noble-metal compound selected from Pt(acetylacetonate){sub 2} and Pd(acetylacetonate){sub 2} for a effective amount of time to incorporate Pt and/or Pd into the pore surface regions of the zeolite, but not to disperse the Pt and/or Pd throughout the entire zeolite; and calcining the so treated zeolite at a temperature from about 250 {degrees} C, to about 600 {degrees} C for an effective amount of time.

Schweizer, A.E.

1991-02-12T23:59:59.000Z

255

Production Technology | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

Production Technology | National Nuclear Security Administration Production Technology | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog Production Technology Home > About Us > Our Programs > Defense Programs > Future Science & Technology Programs > Production Technology Production Technology NNSA continues to assure the safety, security, and reliability of the

256

Computational Model For Transient And Steady State Analysis Of A 1-dimensional Auto-thermal Reformer.  

E-Print Network (OSTI)

??Kim, Daejong This study presents a 1-dimensional mathematical model of steam reformer to be used with high temperature solid oxide fuel cell (SOFC). Steam reforming… (more)

Honavara-Prasad, Srikanth

2011-01-01T23:59:59.000Z

257

Sequencing in telecommunications reform: A review of the Turkish case  

Science Conference Proceedings (OSTI)

This paper reviews the Turkish case of telecommunications reform with reference to the evidence from the sequencing literature. Turkey's progress is in line with the proper sequencing of reform suggested by the literature. Accordingly, Turkey has pursued ... Keywords: Industrial policy, Privatisation, Regulation, Telecommunications

Necmiddin Bagdadioglu; Murat Cetinkaya

2010-12-01T23:59:59.000Z

258

Steam reforming of fuel to hydrogen in fuel cells  

DOE Patents (OSTI)

A fuel cell capable of utilizing a hydrocarbon such as methane as fuel and having an internal dual catalyst system within the anode zone, the dual catalyst system including an anode catalyst supporting and in heat conducting relationship with a reforming catalyst with heat for the reforming reaction being supplied by the reaction at the anode catalyst.

Fraioli, Anthony V. (Hawthorne Woods, IL); Young, John E. (Woodridge, IL)

1984-01-01T23:59:59.000Z

259

Steam reforming of fuel to hydrogen in fuel cell  

DOE Patents (OSTI)

A fuel cell is described capable of utilizing a hydrocarbon such as methane as fuel and having an internal dual catalyst system within the anode zone, the dual catalyst system including an anode catalyst supporting and in heat conducting relationship with a reforming catalyst with heat for the reforming reaction being supplied by the reaction at the anode catalyst.

Young, J.E.; Fraioli, A.V.

1983-07-13T23:59:59.000Z

260

Electricity Reform Abroad and U.S. Investment  

Reports and Publications (EIA)

Reviews and analyzes the recent electricity reforms in Argentina, Australia, and the United Kingdom in an attempt to better understand how different models of privatization and reform have worked in practice. This report also analyzes the motivations of the U.S. companies who have invested in the electricity industries of Argentina, Australia, and the UK.

Kevin Lillis

1997-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Reforming naphtha with boron-containing large-pore zeolites  

Science Conference Proceedings (OSTI)

This patent describes a catalytic reforming process. It comprises contacting a hydrocarbonaceous feedstream under catalytic reforming conditions with a composition comprising larger-pore borosilicate zeolites having a pore size greater than 6 and less than 8 angstroms containing less that 1000 parts per million aluminum.

Zones, S.I.; Holtermann, D.L.; Rainis, A.

1992-05-19T23:59:59.000Z

262

Reforming Power Markets in Developing Countries | Open Energy Information  

Open Energy Info (EERE)

Reforming Power Markets in Developing Countries Reforming Power Markets in Developing Countries Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Reforming Power Markets in Developing Countries Agency/Company /Organization: World Bank Sector: Energy Focus Area: Conventional Energy, Renewable Energy Topics: Policies/deployment programs Resource Type: Publications, Lessons learned/best practices Website: siteresources.worldbank.org/INTENERGY/Resources/Energy19.pdf References: Reforming Power Markets in Developing Countries [1] Summary "This paper complements the World Bank's Operational Guidance Note by compiling lessons of this experience that help in applying the Note's guidance. These lessons are taken from the rapidly growing literature on power market reform in developing countries. They cover the range of issues

263

Electricity Reform in Chile. Lessons for Developing Countries  

E-Print Network (OSTI)

Chile was the first country in the world to implement a comprehensive reform of its electricity sector in the recent period. Among developing countries only Argentina has had a comparably comprehensive and successful reform. This paper traces the history of the Chilean reform, which began in 1982, and assesses its progress and its lessons. We conclude that the reform has been very successful. We suggest lessons for the generation, transmission and distribution sectors, as well as the economic regulation of electricity and the general institutional environment favourable to reform. We note that while the initial market structure and regulatory arrangements did give rise to certain problems, the overall experience argues strongly for the private ownership and operation of the electricity industry.

Michael Pollitt

2004-01-01T23:59:59.000Z

264

Removal of sulfur from recycle gas streams in catalytic reforming  

Science Conference Proceedings (OSTI)

This patent describes improvement in a process for catalytically reforming a hydrocarbonaceous feedstock boiling in the gasoline range, wherein the reforming is conducted in the presence of hydrogen in a reforming process unit under reforming conditions, the process unit comprised of serially connected reactors, each of the reactors containing a reforming catalyst, and which process unit also includes a regeneration circuit for regenerating the catalyst after it becomes coked, the regeneration comprising treatment with a sulfur containing gas, and which process unit also includes a gas/liquid separator wherein a portion of the gas is recycled and the remaining portion is collected as make-gas. The improvement comprises using a sulfur trap, containing a catalyst comprised of about 10 to about 70 wt. % nickel dispersed on a support, between the gas/liquid separator and the first reactor.

Boyle, J.P.

1991-08-27T23:59:59.000Z

265

Advances in the chemistry of catalytic reforming of naphtha  

Science Conference Proceedings (OSTI)

Catalytic reforming of naphtha remains the key process for production of high octane gasoline and aromatics (BTX) which are used as petrochemicals feedstocks. The increased demand for these products has led refiners to investigate ways for improving the performance of the reforming process and its catalysts. Moreover, in order to comply with environmental restrictions, the reduction in lead content would require further increase in the reformate octane number. In response to these requirements, refiners and catalyst manufacturers are examining the role of the catalysts in improving the selectivity to aromatics and in octane enhancement. By understanding the chemistry and the mechanism of the reforming process, higher performance catalysts with longer life on stream and lower cost can be developed. This review covers recent developments in reforming catalysts, process reaction chemistry and mechanism. It also highlights prospective areas of research.

Anabtawi, J.A.; Redwan, D.S.; Al-Jarallah, A.M.; Aitani, A.M. (Petroleum and Gas Technology Div., Research Inst., King Fahd Univ. of Petroleum and Minerals, Dhahran (SA))

1991-01-01T23:59:59.000Z

266

Regulatory and Financial Reform of Federal Research Policy: Recommendations  

NLE Websites -- All DOE Office Websites (Extended Search)

and Financial Reform of Federal Research Policy: and Financial Reform of Federal Research Policy: Recommendations to the NRC Committee on Research Universities Regulatory and Financial Reform of Federal Research Policy: Recommendations to the NRC Committee on Research Universities At the request of the National Research Council (NRC) Committee on Research Universities, the Council on Governmental Relations (COGR), the Association of American Universities (AAU), and the Association of Public and Land-grant Universities (APLU) have assembled a set of ten recommendations for regulatory reform that would improve research universities' ability to carry out their missions without requiring a significant financial investment by the Federal government. Regulatory and Financial Reform of Federal Research Policy: Recommendations

267

Process Reform, Security and Suitability - December 17, 2008 | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Process Reform, Security and Suitability - December 17, 2008 Process Reform, Security and Suitability - December 17, 2008 Process Reform, Security and Suitability - December 17, 2008 December 17, 2008 This is to report on the progress made to improve the timeliness and effectiveness of our hiring and clearing decisions and the specific plan to reform the process further, in accordance with our initial proposals made in April ofthis year. In response to significant, continuing security clearance timeliness concerns, Congress called for improvements and established specific timeliness goals as part of the Intelligence Reform and Terrorism Prevention Act of 2004 (IRTPA). Since the enactment of IRTPA, average timeliness for 90 percent of all clearance determinations reported has been substantially improved, from 265 days (in 2005) to 82 days (4th Quarter,

268

FUEL CELL TECHNOLOGIES PROGRAM Technologies  

E-Print Network (OSTI)

be produced from natural gas using high-temperature steam. This process, called steam methane reforming-INFO (1-877-337-3463) www.eere.energy.gov/informationcenter hydrogen by burning methane in air. Both steam reforming and partial oxida- tion produce a "synthesis gas," which is then reacted with additional steam

269

February 2012Home Production and Social Security Reform  

E-Print Network (OSTI)

This paper incorporates home production into a dynamic general equilibrium model of overlapping generations with endogenous retirement to study Social Security reforms. As such, the model di¤erentiates both consumption goods and labor e¤ort according to their respective roles in home production and market activities. Using a calibrated model, we …nd that eliminating the current pay-asyou-go Social Security system has important implications for both labor supply and consumption decisions and that these decisions are in‡uenced by the presence of a home production technology. Comparing our benchmark economy to one with di¤erentiated goods but no home production, we …nd that eliminating Social Security bene…ts generates larger welfare gains in the presence of home production. This result is due to the self insurance aspects generated by the presence of home production. Comparing our economy to a one-good economy without home production, we show that the welfare gains of eliminating Social Security are magni…ed even further. These policy analyses suggest the importance of modeling home production and distinguishing between both time use and consumption goods depending on whether they are involved in market or home production. JEL Classi…cations: E21, E62, H55

Michael Dotsey; Wenli Li; Michael Dotsey; Wenli Li; Fang Yang

2012-01-01T23:59:59.000Z

270

Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer  

DOE Green Energy (OSTI)

University of Utah's project entitled 'Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer' (DOE Cooperative Agreement DE-FC26-02NT41490) was developed in response to a solicitation released by the U.S. Department of Energy in December 2001, requesting proposals for projects targeted towards black liquor/biomass gasification technology support research and development. Specifically, the solicitation was seeking projects that would provide technical support for Department of Energy supported black liquor and biomass gasification demonstration projects under development at the time.

Kevin Whitty

2007-06-30T23:59:59.000Z

271

Role of metal-support interactions on the activity of Pt and Rh catalysts for reforming methane and butane.  

DOE Green Energy (OSTI)

For residential fuel cell systems, reforming of natural gas is one option being considered for providing the H{sub 2} necessary for the fuel cell to operate. Industrially, natural gas is reformed using Ni-based catalysts supported on an alumina substrate, which has been modified to inhibit coke formation. At Argonne National Laboratory, we have developed a new family of catalysts derived from solid oxide fuel cell technology for reforming hydrocarbon fuels to generate H{sub 2}. These catalysts consist of a transition metal supported on an oxide-ion-conducting substrate, such as ceria, that has been doped with a small amount of a non-reducible element, such as gadolinium, samarium, or zirconium. Unlike alumina, the oxide-ion-conducting substrate has been shown to induce strong metal-support interactions. Metal-support interactions are known to play an important role in influencing the catalytic activity of many metals supported on oxide supports. Based on results from temperature-programmed reduction/oxidation and kinetic reaction studies, this paper discusses the role of the metal and the substrate in the metal-support interactions, and how these interactions influence the activity and the selectivity of the catalyst in reforming methane and butane to hydrogen for use in fuel cell power systems.

Rossignol, C.; Krause, T.; Krumpelt, M.

2002-01-11T23:59:59.000Z

272

Technology Transfer: Available Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials Biofuels Biofuels Biotechnology and Medecine Biotechnology & Medicine Chemistry Developing World Energy Efficient Technologies Energy Environmental Technologies...

273

Hiring Reform Memoranda and Action Plan  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

0585 0585 October 7, 2010 MEMORANDUM FOR HEADS OF ALL DEPARTMENTAL ELEMEI\lTS HUMAI\l RESOURCES DIRECTORS FROM: MICHAELC. KANE~~~ CHIEF HUMAN CAPITAL ~ c· SUBJECT: IMPROVING DOE RECRUITMENT AND HIRING PROCESSES This is a follow-up to the Deputy Secretary's Memorandum dated October 6, 2010 where he communicated the need to implement the Action Plan developed to improve the recruitment and hiring processes throughout the Department. One of the central tenets of the President's reform efforts and the Department's Action Plan is management's commitment and attention to an efficient and effective hiring process that yields quality employees. This was clearly articulated in the President's Memorandum dated May 11, 2010 where he directed that management be held accountable through the performance evaluation system for their role

274

Evaluation of Partial Oxidation Reformer Emissions  

DOE Green Energy (OSTI)

In this study, a gasoline fuel processor and an ethanol fuel processor were operated under conditions simulating both startup and normal operation. Emissions were measured before and after the AGB in order to quantify the effectiveness of the burner catalyst in controlling emissions. The emissions sampling system includes CEM for O2, CO2, CO, NOx, and THC. Also, integrated gas samples are collected in evacuated canisters for hydrocarbon speciation analysis via GC. This analysis yields the concentrations of the hydrocarbon species required for the California NMOG calculation. The PM concentration in the anode burner exhaust was measured through the placement of a filter in the exhaust stream. The emissions from vehicles with fully developed on board reformer systems were estimated.

Unnasch, Stefan; Fable, Scott; Waterland, Larry

2006-01-06T23:59:59.000Z

275

Clean gasoline reforming with superacid catalysts  

DOE Green Energy (OSTI)

The objectives of this project are to: (a) determine if a coal-derived naphtha can be hydrotreated to produce a product with a sufficiently low heteroatom content that can be used for reforming, (b) identify hydrocarbon compounds in the naphtha with concentrations greater than 0.5 wt %, (c) develop a Pt/Al[sub 2]O[sub 3] heavily chlorided catalyst and determine the activity, selectivity and deactivation of this catalyst using model compounds and the hydrotreated naphtha, and (d) develop both a sulfated Pt/ZrO[sub 2] and Fe/Mn/ZrO[sub 2] catalyst formulations and determine the activity, selectivity and deactivation of these catalysts using model compounds and d warranted, the hydrotreated naphtha.

Davis, B.H.

1992-01-01T23:59:59.000Z

276

SOLAR UPGRADE OF METHANE USING DRY REFORMING IN DIRECT CONTACT BUBBLE REACTOR  

E-Print Network (OSTI)

SOLAR UPGRADE OF METHANE USING DRY REFORMING IN DIRECT CONTACT BUBBLE REACTOR Khalid Al-Ali 1 process of a solar reformer of dry methane reforming was proposed to operate in a temperature range of 600:2:2 fulfills our requirements for the direct contact bubble reactor of the solar reformer, in which a CO2-rich

Recanati, Catherine

277

Thermally efficient melting and fuel reforming for glass making  

DOE Patents (OSTI)

An integrated process is described for utilizing waste heat from a glass making furnace. The hot off-gas from the furnace is initially partially cooled, then fed to a reformer. In the reformer, the partially cooled off-gas is further cooled against a hydrocarbon which is thus reformed into a synthesis gas, which is then fed into the glass making furnace as a fuel. The further cooled off-gas is then recycled back to absorb the heat from the hot off-gas to perform the initial cooling. 2 figures.

Chen, M.S.; Painter, C.F.; Pastore, S.P.; Roth, G.S.; Winchester, D.C.

1991-10-15T23:59:59.000Z

278

Page iManaging Investment Climate Reforms: Viet Nam Case Study Table of Contents  

E-Print Network (OSTI)

The primary objective of this study is to learn about Viet Nam’s experience with reforms aimed at facilitating private entry into businesses, and in particular to understand how the reform process itself was managed, what have been the results or outcomes of the reforms, and what lessons have been learned. The focus of the analysis is the Enterprise Law reform episode and related reforms to promote domestic private sector development in Viet Nam.

Viet Nam; Raymond Mallon; Economic Consultant

2004-01-01T23:59:59.000Z

279

Reforming The Government Hiring Process | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Reforming The Government Hiring Process Reforming The Government Hiring Process Reforming The Government Hiring Process November 19, 2010 - 10:10am Addthis Rita Franklin Rita Franklin Deputy Chief Human Capital Officer What does this mean for me? In the video, Deputy Secretary Daniel Poneman highlights the Department's "Time-to-Hire Tracking and Reporting System." The Department reduced the end-to-end time-to-hire from 174 calendar days for Fiscal Year FY 2009 to 100 days for FY 2010. Wednesday, Deputy Secretary Daniel Poneman and I met with leaders from across the Federal government to share our progress in the our Department's hiring reform efforts. Six months ago, President Obama called on all executive departments and federal agencies to overhaul the way we recruit and hire. As the President

280

Intelligence Reform and Terroroism Prevention Act - December 17, 2004 |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Intelligence Reform and Terroroism Prevention Act - December 17, Intelligence Reform and Terroroism Prevention Act - December 17, 2004 Intelligence Reform and Terroroism Prevention Act - December 17, 2004 December 17, 2004 To reform the intelligence community and the intelligence and intelligence-related activities of the United States Government, and for other purposes. SEC. 102. (a) DIRECTOR OF NATIONAL INTELLIGENCE.-(1) There is a Director of National Intelligence who shall be appointed by the President, by and with the advice and consent of the Senate. Any individual nominated for appointment as Director of National Intelligence shall have extensive national security expertise. ''(2) The Director of National Intelligence shall not be located within the Executive Office of the President. ''(b) PRINCIPAL RESPONSIBILITY.-Subject to the authority, direction,

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While these samples are representative of the content of NLEBeta,
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281

Reforming The Government Hiring Process | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Reforming The Government Hiring Process Reforming The Government Hiring Process Reforming The Government Hiring Process November 19, 2010 - 10:10am Addthis Rita Franklin Rita Franklin Deputy Chief Human Capital Officer What does this mean for me? In the video, Deputy Secretary Daniel Poneman highlights the Department's "Time-to-Hire Tracking and Reporting System." The Department reduced the end-to-end time-to-hire from 174 calendar days for Fiscal Year FY 2009 to 100 days for FY 2010. Wednesday, Deputy Secretary Daniel Poneman and I met with leaders from across the Federal government to share our progress in the our Department's hiring reform efforts. Six months ago, President Obama called on all executive departments and federal agencies to overhaul the way we recruit and hire. As the President

282

Chemical simulation of hydrogen generation in a plasma fuel reformer  

E-Print Network (OSTI)

A model for a plasma fuel reformer or plasmatron has been developed. The model was based in a series of experiments realized at the Plasma Science and Fusion Center with such a plasmatron. The device is set up to produce ...

Margarit Bel, Nuria, 1977-

2004-01-01T23:59:59.000Z

283

The stability of coerced economic reform : the case of IPR  

E-Print Network (OSTI)

Theories in international relations posit, and empirical evidence has verified, that unwilling states can be compelled by another state or by an international institution to enact domestic policy reform. However, these ...

Wilcox, Trudy

2005-01-01T23:59:59.000Z

284

Study on Hydrogen-Enriching Gas Reforming in Smelting ... - TMS  

Science Conference Proceedings (OSTI)

May 1, 2007 ... For the two-step smelting reduction iron-making process, the advantages of hydrogen-enriching gas reforming are not only to lower the export ...

285

Separation of hydrogen from a catalytic reforming zone effluent stream  

Science Conference Proceedings (OSTI)

A process for the catalytic reforming of a hydrocarbonaceous feedstock at reforming conditions including a pressure of from about 50 to about 250 psig. Is disclosed. A portion of the hydrogen-rich vapor phase recovered from the reforming zone effluent at a relatively low pressure is compressed and recycled to the reforming zone without further purification. The balance of said hydrogen-rich vapor phase, or the net hydrogen, is compressed to a relatively high pressure and recontacted with at least a portion of the liquid hydrocarbon phase recovered from said low pressure separation to effect a further purification of said net hydrogen and to maximize the recovery of C/sub 3/-C/sub 6/+ the liquid phase.

Schmelzer, E.; Tagamolila, C.P.

1983-02-22T23:59:59.000Z

286

Hydrogen & Fuel Cells - Hydrogen - Distributed Ethanol Reforming  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen from Bio-Derived Liquids Hydrogen from Bio-Derived Liquids Bio-derived liquid fuels can be produced from renewable agricultural products, such as wood chips. Background Bio-derived renewable fuels are attractive for their high energy density and ease of transport. One scenario for a sustainable hydrogen economy considers that these bio-derived liquid fuels will be produced at plants close to the biomass resource, and then transported to distributed hydrogen production centers (e.g., hydrogen refueling stations), where the fuels will be reformed via the steam reforming process, similar to the current centralized production of hydrogen by the steam reforming of natural gas. Hydrogen produced by reforming these fuels must first be purified and compressed to appropriate storage and dispensing pressures. Compressing

287

Electrical Generation Tax Reform Act (Montana) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Generation Tax Reform Act (Montana) Generation Tax Reform Act (Montana) Electrical Generation Tax Reform Act (Montana) < Back Eligibility Utility Fed. Government Commercial Agricultural Investor-Owned Utility State/Provincial Govt Industrial Municipal/Public Utility Local Government Residential Installer/Contractor Rural Electric Cooperative Tribal Government Low-Income Residential Schools Institutional Multi-Family Residential Systems Integrator Nonprofit General Public/Consumer Transportation Savings Category Alternative Fuel Vehicles Hydrogen & Fuel Cells Buying & Making Electricity Water Home Weatherization Solar Wind Program Info State Montana Program Type Fees Provider Montana Department of Revenue This Act reforms taxes paid by electricity generators to reduce tax rates and imposes replacement taxes in response to the 1997 restructuring of the

288

CRUCIBLE TESTING OF TANK 48H RADIOACTIVEWASTE SAMPLE USING FLUIDIZED BED STEAMREFORMING TECHNOLOGY FOR ORGANICDESTRUCTION  

SciTech Connect

The purpose of crucible scale testing with actual radioactive Tank 48H material was to duplicate the test results that had been previously performed on simulant Tank 48H material. The earlier crucible scale testing using simulants was successful in demonstrating that bench scale crucible tests produce results that are indicative of actual Fluidized Bed Steam Reforming (FBSR) pilot scale tests. Thus, comparison of the results using radioactive Tank 48H feed to those reported earlier with simulants would then provide proof that the radioactive tank waste behaves in a similar manner to the simulant. Demonstration of similar behavior for the actual radioactive Tank 48H slurry to the simulant is important as a preliminary or preparation step for the more complex bench-scale steam reformer unit that is planned for radioactive application in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF) later in 2008. The goals of this crucible-scale testing were to show 99% destruction of tetraphenylborate and to demonstrate that the final solid product produced is sodium carbonate. Testing protocol was repeated using the specifications of earlier simulant crucible scale testing, that is sealed high purity alumina crucibles containing a pre-carbonated and evaporated Tank 48H material. Sealing of the crucibles was accomplished by using an inorganic 'nepheline' sealant. The sealed crucibles were heat-treated at 650 C under constant argon flow to inert the system. Final product REDOX measurements were performed to establish the REDuction/OXidation (REDOX) state of known amounts of added iron species in the final product. These REDOX measurements confirm the processing conditions (pyrolysis occurring at low oxygen fugacity) of the sealed crucible environment which is the environment actually achieved in the fluidized bed steam reformer process. Solid product dissolution in water was used to measure soluble cations and anions, and to investigate insoluble fractions of the product solids. Radioanalytical measurements were performed on the Tank 48H feed material and on the dissolved products in order to estimate retention of Cs-137 in the process. All aspects of prior crucible scale testing with simulant Tank 48H slurry were demonstrated to be repeatable with the actual radioactive feed. Tetraphenylborate destruction was shown to be >99% and the final solid product is sodium carbonate crystalline material. Less than 10 wt% of the final solid products are insoluble components comprised of Fe/Ni/Cr/Mn containing sludge components and Ti from monosodium titanate present in Tank 48H. REDOX measurements on the radioactive solid products indicate a reducing atmosphere with extremely low oxygen fugacity--evidence that the sealed crucible tests performed in the presence of a reductant (sugar) under constant argon purge were successful in duplicating the pyrolysis reactions occurring with the Tank 48H feed. Soluble anion measurements confirm that using sugar as reductant at 1X stoichiometry was successful in destroying nitrate/nitrite in the Tank 48H feed. Radioanalytical measurements indicate that {approx}75% of the starting Cs-137 is retained in the solid product. No attempts were made to analyze/measure other potential Cs-137 in the process, i.e., as possible volatile components on the inner surface of the alumina crucible/lid or as offgas escaping the sealed crucible. The collective results from these crucible scale tests on radioactive material are in good agreement with simulant testing. Crucible scale processing has been shown to duplicate the complex reactions of an actual fluidized bed steam reformer. Thus this current testing should provide a high degree of confidence that upcoming bench-scale steam reforming with radioactive Tank 48H slurry will be successful in tetraphenylborate destruction and production of sodium carbonate product.

Crawford, C

2008-07-31T23:59:59.000Z

289

Reforming the Power Sector in Transition: Do Institutions Matter?  

E-Print Network (OSTI)

  tempted  to  add  additional generation capacity through meaningful power sector reforms in the lurch  towards reducing energy dependency.    As  of  1989,  numerous  nuclear  reactors  in  Armenia,  Bulgaria,  Lithuania,  Russia,  Slovakia...  relationship between country level institutions and power sector reforms    Although  the  neoclassical  economic  theory  considers  both  competition  and  privatization  as  the  core  aspects  of  a market  economy;  the  outcomes  cannot  be  guaranteed  to  be  Pareto  efficient  in  the  absence  of  proper  institutional...

Nepal, Rabindra; Jamasb, Tooraj

290

Quick-start catalyzed methanol partial oxidation reformer  

DOE Green Energy (OSTI)

The catalytic methanol partial oxidation reformer described in this paper offers all the necessary attributes for use in transportation fuel cell systems. The bench-scale prototype methanol reformer developed at Argonne is a cylindrical reactor loaded with copper zinc oxide catalyst. Liquid methanol, along with a small amount of water, is injected as a fine spray into a flowing air stream, past an igniter onto the catalyst bed where the partial oxidation reaction takes place.

Ahmed, S.; Kumar, R.

1995-12-01T23:59:59.000Z

291

Performance comparison between partial oxidation and methane steam reforming processes for solid oxide fuel cell (SOFC) micro combined heat and  

E-Print Network (OSTI)

Performance comparison between partial oxidation and methane steam reforming processes for solid recirculation are used along with steam methane reforming. Further Steam Methane Reforming process produces Cell fueled by natural gas with two different types of pre-reforming systems, namely Steam Reforming

Liso, Vincenzo

292

Microsoft PowerPoint - 1-06 Subramanian Sams11-12.ppt  

NLE Websites -- All DOE Office Websites (Extended Search)

WP Technical Exchange WP Technical Exchange Hanford/SRS Tank Waste Path Forward Karthik Subramanian, SRR Terry Sams, WRPS 11/16/2010 SRR-MS-2010-00249 Print Close 2 Overview * Technology Deployment Vision * Tank Waste Strategy and Life-Cycle Benefits - Transformational Technology Scenarios * Hanford - Vitrification Technologies - Salt Processing: LAW Pretreatment and Immobilization * Rotary Microfiltration/Small Column Ion Exchange (RMF/SCIX) * Alternate LLW: Fluidized Bed Steam Reforming (FBSR) - Accelerated SST Retrieval * SRS - Vitrification Technologies - Salt Processing * Rotary Microfiltration/Small Column Ion Exchange (RMF/SCIX) * Next Generation Modular Caustic Side Solvent Extraction (MCU) Print Close 3 Technology Deployment * Goal-oriented technology deployment process to integrate and manage resources through collaboration

293

ENGINEERING TECHNOLOGY Engineering Technology  

E-Print Network (OSTI)

, Mechatronics Technology, and Renewable Energy Technology. Career Opportunities Graduates of four origin, gender, age, marital status, sexual orientation, status as a Vietnam-era veteran, or disability

294

Technology Transfer: Available Technologies  

Please refer to the list of technologies below for licensing and research collaboration availability. If you can't find the technology you ...

295

INVESTIGATION OF FUEL CHEMISTRY AND BED PERFORMANCE IN A FLUIDIZED BED BLACK LIQUOR STEAM REFORMER  

DOE Green Energy (OSTI)

The University of Utah project ''Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer'' (DOE award number DE-FC26-02NT41490) was developed in response to a solicitation for projects to provide technical support for black liquor and biomass gasification. The primary focus of the project is to provide support for a DOE-sponsored demonstration of MTCI's black liquor steam reforming technology at Georgia-Pacific's paper mill in Big Island, Virginia. A more overarching goal is to improve the understanding of phenomena that take place during low temperature black liquor gasification. This is achieved through five complementary technical tasks: (1) construction of a fluidized bed black liquor gasification test system, (2) investigation of bed performance, (3) evaluation of product gas quality, (4) black liquor conversion analysis and modeling and (5) computational modeling of the Big Island gasifier. Four experimental devices have been constructed under this project. The largest facility, which is the heart of the experimental effort, is a pressurized fluidized bed gasification test system. The system is designed to be able to reproduce conditions near the black liquor injectors in the Big Island steam reformer, so the behavior of black liquor pyrolysis and char gasification can be quantified in a representative environment. The gasification test system comprises five subsystems: steam generation and superheating, black liquor feed, fluidized bed reactor, afterburner for syngas combustion and a flue gas cooler/condenser. The three-story system is located at University of Utah's Industrial Combustion and Gasification Research Facility, and all resources there are available to support the research.

Kevin Whitty

2003-12-01T23:59:59.000Z

296

Biomass reforming processes in hydrothermal media  

E-Print Network (OSTI)

While hydrothermal technologies offer distinct advantages in being able to process a wide variety of biomass feedstocks, the composition of the feedstock will have a large effect on the processing employed. This thesis ...

Peterson, Andrew A

2009-01-01T23:59:59.000Z

297

Methanol reformers for fuel cell powered vehicles: Some design considerations  

DOE Green Energy (OSTI)

Fuel cells are being developed for use in automotive propulsion systems as alternatives for the internal combustion engine in buses, vans, passenger cars. The two most important operational requirements for a stand-alone fuel cell power system for a vehicle are the ability to start up quickly and the ability to supply the necessary power on demand for the dynamically fluctuating load. Methanol is a likely fuel for use in fuel cells for transportation applications. It is a commodity chemical that is manufactured from coal, natural gas, and other feedstocks. For use in a fuel cell, however, the methanol must first be converted (reformed) to a hydrogen-rich gas mixture. The desired features for a methanol reformer include rapid start-up, good dynamic response, high fuel conversion, small size and weight, simple construction and operation, and low cost. In this paper the present the design considerations that are important for developing such a reformer, namely: (1) a small catalyst bed for quick starting, small size, and low weight; (2) multiple catalysts for optimum operation of the dissociation and reforming reactions; (3) reforming by direct heat transfer partial oxidation for rapid response to fluctuating loads; and (4) thermal independence from the rest of the fuel cell system. 10 refs., 1 fig.

Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

1990-01-01T23:59:59.000Z

298

Mill Integration-Pulping, Stream Reforming and Direct Causticization for Black Liquor Recovery  

DOE Green Energy (OSTI)

MTCI/StoneChem developed a steam reforming, fluidized bed gasification technology for biomass. DOE supported the demonstration of this technology for gasification of spent wood pulping liquor (or 'black liquor') at Georgia-Pacific's Big Island, Virginia mill. The present pre-commercial R&D project addressed the opportunities as well as identified negative aspects when the MTCI/StoneChem gasification technology is integrated in a pulp mill production facility. The opportunities arise because black liquor gasification produces sulfur (as H{sub 2}S) and sodium (as Na{sub 2}CO{sub 3}) in separate streams which may be used beneficially for improved pulp yield and properties. The negative aspect of kraft black liquor gasification is that the amount of Na{sub 2}CO{sub 3} which must be converted to NaOH (the so called causticizing requirement) is increased. This arises because sulfur is released as Na{sub 2}S during conventional kraft black liquor recovery, while during gasification the sodium associated Na{sub 2}S is partly or fully converted to Na{sub 2}CO{sub 3}. The causticizing requirement can be eliminated by including a TiO{sub 2} based cyclic process called direct causticization. In this process black liquor is gasified in the presence of (low sodium content) titanates which convert Na{sub 2}CO{sub 3} to (high sodium content) titanates. NaOH is formed when contacting the latter titanates with water, thereby eliminating the causticizing requirement entirely. The leached and low sodium titanates are returned to the gasification process. The project team comprised the University of Maine (UM), North Carolina State University (NCSU) and MTCI/ThermoChem. NCSU and MTCI are subcontractors to UM. The principal organization for the contract is UM. NCSU investigated the techno-economics of using advanced pulping techniques which fully utilize the unique cooking liquors produced by steam reforming of black liquor (Task 1). UM studied the kinetics and agglomeration problems of the conversion of Na{sub 2}CO{sub 3} to (high sodium) titanates during gasification of black liquor in the presence of (low sodium) titanates or TiO{sub 2} (Task 2). MTCI/ThermoChem tested the performance and operability of the combined technology of steam reforming and direct causticization in their Process Development Unit (PDU) (Task 3). The specific objectives were: (1) to investigate how split sulfidity and polysulfide (+ AQ) pulping can be used to increase pulp fiber yield and properties compared to conventional kraft pulping; (2) to determine the economics of black liquor gasification combined with these pulping technologies in comparison with conventional kraft pulping and black liquor recovery; (3) to determine the effect of operating conditions on the kinetics of the titanate-based direct causticization reaction during black liquor gasification at relatively low temperatures ({le} 750 C); (4) to determine the mechanism of particle agglomeration during gasification of black liquor in the presence of titanates at relatively low temperatures ({le} 750 C); and (5) to verify performance and operability of the combined technology of steam reforming and direct causticization of black liquor in a pilot scale fluidized bed test facility.

Adriaan van Heiningen

2007-06-30T23:59:59.000Z

299

Development of a Catalyst/Sorbent for Methane Reforming  

Science Conference Proceedings (OSTI)

This project led to the further development of a combined catalyst and sorbent for improving the process technology required for converting CH{sub 4} and/or CO into H{sub 2} while simultaneously separating the CO{sub 2} byproduct all in a single step. The new material is in the form of core-in-shell pellets such that each pellet consists of a CaO core surrounded by an alumina-based shell capable of supporting a Ni catalyst. The Ni is capable of catalyzing the reactions of steam with CH{sub 4} or CO to produce H{sub 2} and CO{sub 2}, whereas the CaO is capable of absorbing the CO{sub 2} as it is produced. The absorption of CO{sub 2} eliminates the reaction inhibiting effects of CO{sub 2} and provides a means for recovering the CO{sub 2} in a useful form. The present work showed that the lifecycle performance of the sorbent can be improved either by incorporating a specific amount of MgO in the material or by calcining CaO derived from limestone at 1100 C for an extended period. It also showed how to prepare a strong shell material with a large surface area required for supporting an active Ni catalyst. The method combines graded particles of {alpha}-alumina with noncrystalline alumina having a large specific surface area together with a strength promoting additive followed by controlled calcination. Two different additives produced good results: 3 {micro}m limestone and lanthanum nitrate which were converted to their respective oxides upon calcination. The oxides partially reacted with the alumina to form aluminates which probably accounted for the strength enhancing properties of the additives. The use of lanthanum made it possible to calcine the shell material at a lower temperature, which was less detrimental to the surface area, but still capable of producing a strong shell. Core-in-shell pellets made with the improved shell materials and impregnated with a Ni catalyst were used for steam reforming CH{sub 4} at different temperatures and pressures. Under all conditions tested, the CH{sub 4} conversion was large (>80%) and nearly equal to the predicted thermodynamic equilibrium level as long as CO{sub 2} was being rapidly absorbed. Similar results were obtained with both shell material additives. Limited lifecycle tests of the pellets also produced similar results that were not affected by the choice of additive. However, during each lifecycle test the period during which CO{sub 2} was rapidly absorbed declined from cycle to cycle which directly affected the corresponding period when CH{sub 4} was reformed rapidly. Therefore, the results showed a continuing need for improving the lifecycle performance of the sorbent. Core-in-shell pellets with the improved shell materials were also utilized for conducting the water gas shift reaction in a single step. Three different catalyst formulations were tested. The best results were achieved with a Ni catalyst, which proved capable of catalyzing the reaction whether CO{sub 2} was being absorbed or not. The calcined alumina shell material by itself also proved to be a very good catalyst for the reaction as long as CO{sub 2} was being fully absorbed by the core material. However, neither the alumina nor a third formulation containing Fe{sub 2}O{sub 3} were good catalysts for the reaction when CO{sub 2} was not absorbed by the core material. Furthermore, the Fe{sub 2}O{sub 3}-containing catalyst was not as good as the other two catalysts when CO{sub 2} was being absorbed.

B.H. Shans; T.D. Wheelock; Justinus Satrio; Karl Albrecht; Tanya Harris Janine Keeley; Ben Silva; Aaron Shell; Molly Lohry; Zachary Beversdorf

2008-12-31T23:59:59.000Z

300

CX-005511: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

511: Categorical Exclusion Determination 511: Categorical Exclusion Determination CX-005511: Categorical Exclusion Determination Steam Reforming Treatability Study with Hanford Sample E CX(s) Applied: B3.6 Date: 02/10/2011 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office A mixed waste treatability study will be performed to test the fluidized bed steam reforming (FBSR) technology on a composite of two caustic Hanford tank waste streams (AZ101 and AZ102). The tests will be performed in Savannah River National Laboratory 773-A Shielded Cells, A-block with portions being completed in B-wing and in the Analytical Development labs. Approximately, 1.5 liters of each waste stream will be fed to the process over the course of ~15 runs ( DOCUMENT(S) AVAILABLE FOR DOWNLOAD

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

CX-004173: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

3: Categorical Exclusion Determination 3: Categorical Exclusion Determination CX-004173: Categorical Exclusion Determination Steam Reforming Treatability Study with Savannah River Site Low Activity Waste (LAW) (Module B) CX(s) Applied: B3/6 Date: 09/30/2010 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office A mixed waste treatability study will be performed to test the fluidized bed steam reforming (FBSR) technology on Savannah River Site Low Activity Waste (LAW) modified to simulate Hanford waste. The tests will be performed in Savannah River National Laboratory 773-A Shielded Cells, A-block with portions being completed in B-wing, C-wing, and in the Analytical Development laboratories. Approximately 2 liters of sample will be fed to the process.

302

CX-003967: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

67: Categorical Exclusion Determination 67: Categorical Exclusion Determination CX-003967: Categorical Exclusion Determination Steam Reforming Treatability Study with Hanford Samples CX(s) Applied: B3.6 Date: 09/03/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office A mixed waste treatability study will be performed to test the fluidized bed steam reforming (FBSR) technology on two caustic Hanford waste streams (SX-105 and An-103). The tests will be performed in Savannah River National Laboratory 773-A Shielded Cells, A-block with portions being completed in B-wing and in the Analytical Development laboratories. Approximately, 1 Liter of each waste stream will be fed to the process over the course of 8 runs (250 milliliter of waste per run). DOCUMENT(S) AVAILABLE FOR DOWNLOAD

303

Steam Reforming Application for Treatment of DOE Sodium Bearing Tank Wastes at Idaho National Laboratory for Idaho Cleanup Project  

SciTech Connect

The patented THOR{sup R} steam reforming waste treatment technology has been selected as the technology of choice for treatment of Sodium Bearing Waste (SBW) at the Idaho National Laboratory (INL) for the Idaho Cleanup Project (ICP). SBW is an acidic tank waste at the Idaho Nuclear Technology and Engineering Center (INTEC) at INL. It consists primarily of waste from decontamination activities and laboratory wastes. SBW contains high concentrations of nitric acid, alkali and aluminum nitrates, with minor amounts of many inorganic compounds including radionuclides, mainly cesium and strontium. The THOR{sup R} steam reforming process will convert the SBW tank waste feed into a dry, solid, granular product. The THOR{sup R} technology was selected to treat SBW, in part, because it can provide flexible disposal options to accommodate the final disposition path selected for SBW. THOR{sup R} can produce a final end-product that will meet anticipated requirements for disposal as Remote-Handled TRU (RH-TRU) waste; and, with modifications, THOR{sup R} can also produce a final end-product that could be qualified for disposal as High Level Waste (HLW). SBW treatment will be take place within the Integrated Waste Treatment Unit (IWTU), a new facility that will be located at the INTEC. This paper provides an overview of the THOR{sup R} process chemistry and process equipment being designed for the IWTU. (authors)

Mason, J.B.; Wolf, K.; Ryan, K.; Roesener, S.; Cowen, M.; Schmoker, D.; Bacala, P. [THOR Treatment Technologies, LLC, 106 Newberry St. SW, Aiken, SC 29801 (United States); Landman, B. [CH2M WG Idaho, LLC, P. O. Box 1625, Idaho Falls, ID 83415 (United States)

2006-07-01T23:59:59.000Z

304

Forest Tenure Reform in Vietnam | Open Energy Information  

Open Energy Info (EERE)

in Vietnam in Vietnam Jump to: navigation, search Name Forest Tenure Reform in Vietnam Agency/Company /Organization Regional Community Forestry Training Center for Asia and the Pacific Sector Land Focus Area Forestry Topics Resource assessment, Background analysis Resource Type Lessons learned/best practices Website http://recoftc.org/site/filead Country Vietnam UN Region South-Eastern Asia References Forest Tenure Reform in Vietnam[1] Forest Tenure Reform in Vietnam Screenshot Summary "This report presents a synthesis of findings from the two surveys undertaken in Dak Lak (by Dak Lak Department of Agriculture and Rural Development (DARD)) and Hoa Binh by VFU (See Annex A. for a list of members in the two research teams). It was prepared by Nguyen Quang Tan, Nguyen Ba

305

Regulatory and Financial Reform of Federal Research Policy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Regulatory and Financial Reform of Federal Research Policy Regulatory and Financial Reform of Federal Research Policy Recommendations to the NRC Committee on Research Universities January 21, 2011 Introduction At the request of the National Research Council (NRC) Committee on Research Universities, the Council on Governmental Relations (COGR), the Association of American Universities (AAU), and the Association of Public and Land-grant Universities (APLU) have assembled a set of ten recommendations for regulatory reform that would improve research universities' ability to carry out their missions without requiring a significant financial investment by the Federal government. We firmly believe that compliance and regulatory oversight are essential to the conduct of federally-supported research. Rationalizing the Federal regulatory infrastructure is essential to

306

Comments on Request For Information regarding Reducing Regulatory Reform  

NLE Websites -- All DOE Office Websites (Extended Search)

Comments on Request For Information regarding Reducing Regulatory Comments on Request For Information regarding Reducing Regulatory Reform issued February 3, 2011 (Federal Register /Vol. 76, No. 23 /Thursday, February 3, 2011 /Notices). Comments on Request For Information regarding Reducing Regulatory Reform issued February 3, 2011 (Federal Register /Vol. 76, No. 23 /Thursday, February 3, 2011 /Notices). I have reviewed the Request For Information regarding Reducing Regulatory Reform issued February 3, 2011 (Federal Register /Vol. 76, No. 23 /Thursday, February 3, 2011 /Notices). In the Department of Energy"s (DOE) attempt to meet its obligation to implement Executive Order 13563, ""Improving Regulation and Regulatory Review,"" issued by the President on January 18, 2011, I recommend DOE make a bold move to change

307

Pyrochlore-type catalysts for the reforming of hydrocarbon fuels  

DOE Patents (OSTI)

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A.sub.2-w-xA'.sub.wA''.sub.xB.sub.2-y-zB'.sub.yB''.sub.zO.sub.7-.DELTA.. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H.sub.2+CO) for fuel cells, among other uses.

Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV); Haynes, Daniel (Morgantown, WV); Smith, Mark (Morgantown, WV); Spivey, James J. (Baton Rouge, LA)

2012-03-13T23:59:59.000Z

308

Pyrochlore-type catalysts for the reforming of hydrocarbon fuels  

Science Conference Proceedings (OSTI)

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A.sub.2-w-xA'.sub.wA''.sub.xB.sub.2-y-zB'.sub.yB''.sub.zO.sub.7-.DELTA.. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H.sub.2+CO) for fuel cells, among other uses.

Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV); Haynes, Daniel (Morgantown, WV); Smith, Mark (Morgantown, WV); Spivey, James J. (Baton Rouge, LA)

2012-03-13T23:59:59.000Z

309

Producing Clean Syngas via Catalytic Reforming for Fuels Production  

Science Conference Proceedings (OSTI)

Thermochemical biomass conversion to fuels and chemicals can be achieved through gasification to syngas. The biomass derived raw syngas contains the building blocks of carbon monoxide and hydrogen as well as impurities such as tars, light hydrocarbons, and hydrogen sulfide. These impurities must be removed prior to fuel synthesis. We used catalytic reforming to convert tars and hydrocarbons to additional syngas, which increases biomass carbon utilization. In this work, nickel based, fluidizable tar reforming catalysts were synthesized and evaluated for tar and methane reforming performance with oak and model syngas in two types of pilot scale fluidized reactors (recirculating and recirculating regenerating). Because hydrogen sulfide (present in raw syngas and added to model syngas) reacts with the active nickel surface, regeneration with steam and hydrogen was required. Pre and post catalyst characterization showed changes specific to the syngas type used. Results of this work will be discussed in the context of selecting the best process for pilot scale demonstration.

Magrini, K. A.; Parent, Y.; Jablonski, W.; Yung, M.

2012-01-01T23:59:59.000Z

310

Ghana-REDD Readiness Requires Radical Reform | Open Energy Information  

Open Energy Info (EERE)

Readiness Requires Radical Reform Readiness Requires Radical Reform Jump to: navigation, search Name Ghana-REDD Readiness Requires Radical Reform Agency/Company /Organization UN-REDD Programme Sector Land Focus Area Forestry, Agriculture Topics Implementation, GHG inventory, Policies/deployment programs, Resource assessment, Pathways analysis, Background analysis Resource Type Maps, Guide/manual, Training materials Website http://environment.yale.edu/tf Country Ghana UN Region Western Africa References Ghana-REDD Readiness[1] Summary "The fundamental changes needed for sustainable forest management in Ghana have been known for years, and many large projects have been instigated accordingly. Yet real change has proved elusive. The key challenge now is to get REDD-plus right so that it makes a difference. Dialogue participants

311

High performance internal reforming unit for high temperature fuel cells  

DOE Patents (OSTI)

A fuel reformer having an enclosure with first and second opposing surfaces, a sidewall connecting the first and second opposing surfaces and an inlet port and an outlet port in the sidewall. A plate assembly supporting a catalyst and baffles are also disposed in the enclosure. A main baffle extends into the enclosure from a point of the sidewall between the inlet and outlet ports. The main baffle cooperates with the enclosure and the plate assembly to establish a path for the flow of fuel gas through the reformer from the inlet port to the outlet port. At least a first directing baffle extends in the enclosure from one of the sidewall and the main baffle and cooperates with the plate assembly and the enclosure to alter the gas flow path. Desired graded catalyst loading pattern has been defined for optimized thermal management for the internal reforming high temperature fuel cells so as to achieve high cell performance.

Ma, Zhiwen (Sandy Hook, CT); Venkataraman, Ramakrishnan (New Milford, CT); Novacco, Lawrence J. (Brookfield, CT)

2008-10-07T23:59:59.000Z

312

GUIDANCE ON APPLICATION OF FEDERAL VACANCIES REFORM ACT OF 1998 Page 1 of 13  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

APPLICATION OF FEDERAL VACANCIES REFORM ACT OF 1998 Page 1 of 13 APPLICATION OF FEDERAL VACANCIES REFORM ACT OF 1998 Page 1 of 13 GUIDANCE ON APPLICATION OF FEDERAL VACANCIES REFORM ACT OF 1998 This memorandum provides guidance on the application of the Federal Vacancies Reform Act of1998 to vacancies in Senate-confirmed offices within the executive branch. March 22, 1999 MEMORANDUM FOR AGENCY GENERAL COUNSELS On October 21, 1998, the Federal Vacancies Reform Act of 1998 ("Vacancies Reform Act" or "Act") was signed into law. ( ) The Vacancies Reform Act replaces the old Vacancies Act and alters the way in which vacancies in presidentially appointed, Senate- confirmed offices within the executive branch may be filled on a temporary basis. The following Q&As are intended to provide general guidance on the Vacancies Reform Act. If

313

Controlling Activity and Stability of Ni-YSZ Catalysts for On-Anode Reforming  

DOE Green Energy (OSTI)

The purposes of the project are to develop an effective Ni-YSZ-based anode for on-anode reforming of methane and natural gas and develop methods to control endothermic steam reforming activity.

King, D.L.; Wang, Y.; Chin, Y-H.; Lin, Y.; Roh, H-S.; Rozmiarek, B.

2005-01-27T23:59:59.000Z

314

www.elsevier.com/locate/econbase School finance reform: Assessing general equilibrium effects  

E-Print Network (OSTI)

In 1994 the state of Michigan implemented one of the most comprehensive school finance reforms undertaken to date in any of the states. Understanding the effects of the reform is thus of value in informing other potential reform initiatives. In addition, the reform and associated changes in the economic environment provide an opportunity to assess whether a simple general equilibrium model can be of value in framing the study of such reform initiatives. In this paper, we present and use such a model to derive predictions about the effects of the reform on housing prices and neighborhood demographic compositions. Broadly, our analysis implies that the effects of the reform and changes in the economic environment are likely to have been reflected primarily in housing prices and only modestly on neighborhood demographics. We find that evidence for the Detroit metropolitan area from the decade encompassing the reform is largely consistent with the predictions of the model.

Maria Marta Ferreyra A

2007-01-01T23:59:59.000Z

315

The Lessons of Practice: Domestic Policy Reform as a Way to Address...  

Open Energy Info (EERE)

The Lessons of Practice: Domestic Policy Reform as a Way to Address Climate Change Jump to: navigation, search Tool Summary Name: The Lessons of Practice: Domestic Policy Reform as...

316

From negotiation to auction : Land-Conveyance Reform in China and its institutional and social impacts  

E-Print Network (OSTI)

The land market and the associated land-development-control mechanism in China have been experiencing a series of reforms since the 1990s, of which Land Conveyance Reform (LCR) in 2004 is a very recent and an important ...

Chen, Zhiyu (Zhiyu Jerry)

2007-01-01T23:59:59.000Z

317

Hydrogen Bus Technology Validation Program  

E-Print Network (OSTI)

buses. Station 1: Steam Methane Reformer, 100 kg/day (10kg) $/yr Station 2: Steam Methane Reformer, 1000 kg/day (100

Burke, Andy; McCaffrey, Zach; Miller, Marshall; Collier, Kirk; Mulligan, Neal

2005-01-01T23:59:59.000Z

318

Hydrogen Bus Technology Validation Program  

E-Print Network (OSTI)

day (10 buses) Natural gas reformer Purifier Storage Systemday (100 buses) Natural gas reformer Purifier Storage Systemnatural gas stations are hydrogen production and storage, a

Burke, Andy; McCaffrey, Zach; Miller, Marshall; Collier, Kirk; Mulligan, Neal

2005-01-01T23:59:59.000Z

319

ECONOMIC REFORM AND COMMUNIST REGIME SURVIVABILTY: PAST, PRESENT, AND FUTURE  

E-Print Network (OSTI)

While the collapse of communist rule and process of transitioning to democracy in the former-Soviet Union and its numerous satellite states certainly warrants the wealth of attention received, by no means does this signal that the history of communist state rule is ended. Contrary to popular belief—and even belief in academe it sometimes seems—Communism still survives. In fact, a number of Asian states still claim to follow the path to a promised societal utopia under the guidance of their respective Politburos and may be described as not only ‘surviving’ but thriving, experiencing economic stability and enjoying high rates of growth. This study examines the ramifications of economic and political reform policies implemented by four collapsed communist regimes which have transitioned to democratic governance—the former-Soviet Union, Poland, Hungary, and Czechoslovakia—as well as two surviving Asian communist regimes—Vietnam and China—in identifying characteristic patterns of reform that are conducive to regime survival and/or collapse. The end objective herein is to provide projections for the future of the Castro regime in Cuba, which faces a critical juncture in the future with the impending death of its charismatic leader. I hypothesize that economic reform, through consistent implementation, generates credibility for both Communist Party elites and their future reform endeavors. Additionally, reform packages that manage to successfully stabilize the economy bestow an increased measure of legitimacy to the political elite, allowing the Communist Party to maintain political control, thereby avoiding collapse and the transition to democracy. The third and final section contains general discussion and what conclusions can be drawn from the results, as well as analysis of the history of reform efforts to present in the Caribbean island state of Cuba.

Nelson, John

2006-08-16T23:59:59.000Z

320

Technology Search  

home \\ technologies \\ search. Technologies: Ready-to-Sign Licenses: Software: Patents: Technology Search. ... Operated by Lawrence Livermore National Security, LLC, ...

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Why are land reforms granting complete property rights politically risky? Electoral outcomes of Mexico's certification program  

E-Print Network (OSTI)

identified adverse political fallouts as the main reason whygains but fear the political fallout of the reform. It helps

de Janvry, Alain; Gonzalez-Navarro, Marco; Sadoulet, Elisabeth

2012-01-01T23:59:59.000Z

322

Tailored Macroporous SiCN and SiC Structures for High-Temperature Fuel Reforming**  

E-Print Network (OSTI)

. The catalytic reforming of hydrocarbons in a microreformer is an attractive approach to supply hydrogen to fuel

Kenis, Paul J. A.

323

Heat exchanger for fuel cell power plant reformer  

DOE Patents (OSTI)

A heat exchanger uses the heat from processed fuel gas from a reformer for a fuel cell to superheat steam, to preheat raw fuel prior to entering the reformer and to heat a water-steam coolant mixture from the fuel cells. The processed fuel gas temperature is thus lowered to a level useful in the fuel cell reaction. The four temperature adjustments are accomplished in a single heat exchanger with only three heat transfer cores. The heat exchanger is preheated by circulating coolant and purge steam from the power section during startup of the latter.

Misage, Robert (Manchester, CT); Scheffler, Glenn W. (Tolland, CT); Setzer, Herbert J. (Ellington, CT); Margiott, Paul R. (Manchester, CT); Parenti, Jr., Edmund K. (Manchester, CT)

1988-01-01T23:59:59.000Z

324

Catalytic reforming of liquid fuels: Deactivation of catalysts  

Science Conference Proceedings (OSTI)

The catalytic reforming of logistic fuels (e.g., diesel) to provide hydrogen-rich gas for various fuel cells is inevitably accompanied by deactivation. This deactivation can be caused by various mechanisms, such as carbon deposition, sintering, and sulfur poisoning. In general, these mechanisms are, not independent—e.g., carbon deposition may affect sulfur poisoning. However, they are typically studied in separate experiments, with relatively little work reported on their interaction at conditions typical of liquid fuel reforming. Recent work at the U.S. Dept. of Energy/NETL and Louisiana State University has shown progress in understanding the interaction of these deactivation processes, and catalysts designed to minimize them.

Spivey, J.J.; Haynes, D.J.; Berry, D.A.; Shekhawat, Dushyant; Gardner, T.H.

2007-10-01T23:59:59.000Z

325

Building Technologies Office: Emerging Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Emerging Technologies Emerging Technologies Printable Version Share this resource Send a link to Building Technologies Office: Emerging Technologies to someone by E-mail Share Building Technologies Office: Emerging Technologies on Facebook Tweet about Building Technologies Office: Emerging Technologies on Twitter Bookmark Building Technologies Office: Emerging Technologies on Google Bookmark Building Technologies Office: Emerging Technologies on Delicious Rank Building Technologies Office: Emerging Technologies on Digg Find More places to share Building Technologies Office: Emerging Technologies on AddThis.com... About Take Action to Save Energy Partner with DOE Activities Technology Research, Standards, & Codes Popular Links Success Stories Previous Next Lighten Energy Loads with System Design.

326

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

41 - 6150 of 26,764 results. 41 - 6150 of 26,764 results. Photo Gallery LED Lighting on the National Mall http://energy.gov/photos/led-lighting-national-mall Download Energy Emergency Preparedness Quarterly Vol 2, Issue 1- January 2013 The Energy Emergency Preparedness Quarterly is published by the Infrastructure Security and Energy Restoration (ISER) Division of the Office of Electricity Delivery and Energy Reliability (OE) to... http://energy.gov/oe/downloads/energy-emergency-preparedness-quarterly-vol-2-issue-1-january-2013 Download Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP) This assessment determines the technology maturity level of the candidate Tank 48H treatment technologies that are being considered for

327

Page not found | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

61 - 18070 of 28,560 results. 61 - 18070 of 28,560 results. Download Financial and Activity Report- February 19, 2010 http://energy.gov/downloads/financial-and-activity-report-february-19-2010 Download Financial and Activity Report- March 26, 2010 http://energy.gov/downloads/financial-and-activity-report-march-26-2010 Download Financial and Activity Report- April 09, 2010 http://energy.gov/downloads/financial-and-activity-report-april-09-2010 Download Financial and Activity Report- August 20, 2010 http://energy.gov/downloads/financial-and-activity-report-august-20-2010 Download Technology Maturation Plan (TMP) Fluidized Bed Steam Reforming (FBSR) Technology for Tank 48H Treatment Project (TTP) This assessment determines the technology maturity level of the candidate Tank 48H treatment technologies that are being considered for

328

Why SOFC Technology? | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Why SOFC Technology? Why SOFC Technology? Why SOFC Technology? Why SOFC Technology? Like most fuel cell technologies, SOFCs are modular, scalable, and efficient. They are not subject to Carnot cycle limitations because they are not heat engines. Also, they benefit the public by minimizing emissions, such as oxides of nitrogen (NOx) <0.5 PPM compared to earlier combustion-based electrical power generation technologies due to lower operating temperatures. There are more reasons why SOFCs are the fuel cell technology of choice in USDOE/FE. First, relative to other fuel cell types, SOFCs are fuel-flexible - they can reform methane internally, use carbon monoxide as a fuel, and tolerate some degree of common fossil fuel impurities, such as ammonia and chlorides. Sulfur-bearing contaminants, such as hydrogen sulfide, are

329

EFFECT OF H2 PRODUCED THROUGH STEAM-METHANE REFORMING ON CHP PLANT EFFICIENCY  

E-Print Network (OSTI)

1 EFFECT OF H2 PRODUCED THROUGH STEAM-METHANE REFORMING ON CHP PLANT EFFICIENCY O. Le Corre1 , C@emn.fr ABSTRACT In-situ hydrogen production is carried out by a catalytic reformer kit set up into exhaust gases-thermal reforming process is achieved. Hydrogen production is mainly dependent on O2 content in exhaust gases

330

Combined Steam Reforming and Partial Oxidation of Methane to Synthesis Gas under Electrical Discharge  

E-Print Network (OSTI)

Combined Steam Reforming and Partial Oxidation of Methane to Synthesis Gas under Electrical production from simultaneous steam reforming and partial oxidation of methane using an ac corona discharge and steam reforming has a benefit in terms of balancing the heat load. Methane conversions can be achieved

Mallinson, Richard

331

Catalysts for hydrogen production by steam reforming of dimethyl ether (DME)  

Science Conference Proceedings (OSTI)

Dimethyl ether (DME) is expected as one of clean fuels. We have been studying on DME steam reforming for hydrogen production. Copper alumina catalysts prepared by a sol-gel method produced large quantities of H2 with DME steam reforming. The reason was ... Keywords: DME, alumina, catalyst, clean fuel, copper, dimethyl ether, hydrogen, sol-gel method, steam reforming

Kaoru Takeishi

2010-02-01T23:59:59.000Z

332

Distributed Bio-Oil Reforming - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

5 5 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Stefan Czernik (Primary Contact), Richard French, Michael Penev National Renewable Energy Laboratory (NREL) 15013 Denver West Parkway Golden, CO 80401 Phone: (303) 384-6135 Email: Stefan.Czernik@nrel.gov DOE Manager Sara Dillich Phone: (202) 586-1623 Email: Sara.Dillich@ee.doe.gov Subcontractor: University of Minnesota, Minneapolis, MN Project Start Date: October 1, 2004 Project End Date: September 30, 2012 Fiscal Year (FY) 2012 Objectives By 2012, develop and demonstrate distributed reforming * technology for producing hydrogen from bio-oil at $4.10/ kilogram (kg) purified hydrogen. Demonstrate integrated performance at bench scale * including bio-oil vaporization, partial-oxidation (POX)

333

DIESEL REFORMERS FOR LEAN NOX TRAP REGENERATION AND OTHER ON-BOARD HYDROGEN APPLICATIONS  

DOE Green Energy (OSTI)

Many solutions to meeting the 2007 and 2010 diesel emissions requirements have been suggested. On board production of hydrogen for in-cylinder combustion and exhaust after-treatment provide promising opportunities for meeting those requirements. Other benefits may include using syngas to rapidly heat up exhaust after-treatment catalysts during engine startup. HydrogenSource's development of a catalytic partial oxidation reformer for generating hydrogen from ultra-low sulfur diesel fuel is presented. The system can operate on engine exhaust and diesel fuel with no water tank. Test data for hydrogen regeneration of a lean NOx trap is presented showing 90% NOx conversion at temperatures as low as 150 degrees C and 99% conversion at 300 degrees C. Finally, additional efforts required to fully understand the benefits and commercial challenges of this technology are discussed.

Mauss, M; Wnuck, W

2003-08-24T23:59:59.000Z

334

Efficiency of a hybrid-type plasma-assisted fuel reformation system  

Science Conference Proceedings (OSTI)

The major advantages of a new plasma-assisted fuel reformation system are its cost effectiveness and technical efficiency. Applied Plasma Technologies has proposed its new highly efficient hybrid-type plasma-assisted system for organic fuel combustion and gasification. The system operates as a multimode multipurpose reactor in a wide range of plasma feedstock gases and turndown ratios. This system also has convenient and simultaneous feeding of several reagents in the reaction zone such as liquid fuels, coal, steam, and air. A special methodology has been developed for such a system in terms of heat balance evaluation and optimization. This methodology considers all existing and possible energy streams, which could influence the system's efficiency. The developed hybrid-type plasma system could be suitable for combustion applications, mobile and autonomous small- to mid-size liquid fuel and coal gasification modules, hydrogen-rich gas generators, waste-processing facilities, and plasma chemical reactors.

Matveev, I.B.; Serbin, S.I.; Lux, S.M. [Applied Plasma Technologies, Mclean, VA (USA)

2008-12-15T23:59:59.000Z

335

Changing the Rules of the 'ROE': A Reform in Waiting  

SciTech Connect

Congress and FERC recognize the need to attract more investment in transmission. FERC promised to increase cash flow for companies investing in transmission and introduced incremental changes in rates of return. But the agency can do better. FERC should enact comprehensive reform of its return-on-equity calculus to conform policy to market reality. (author)

Rokach, Joshua Z.

2006-05-15T23:59:59.000Z

336

Reform and Regulation of the Electricity Sectors in Developing Countries  

E-Print Network (OSTI)

in investment patterns reflect the differences in the reform strategies adopted by the countries in these regions during the 1990s. By and large, the EAP and SA countries opted for power purchase agreements (PPAs) with independent power producers (IPPs) while...

Jamasb, Tooraj; Littlechild, Stephen C

2004-06-16T23:59:59.000Z

337

Understanding electricity market reforms and the case of Philippine deregulation  

Science Conference Proceedings (OSTI)

The experience of the Philippines offers lessons that should be relevant to any country seeking to deregulate its power industry. Regardless of structure, consumers must face the real price of electricity production and delivery that is closer to marginal cost. Politically motivated prices merely shift the burden from ratepayers to taxpayers. And any reform should work within a reasonable timetable. (author)

Santiago, Andrea; Roxas, Fernando

2010-03-15T23:59:59.000Z

338

Electricity reform and Gains from the reallocation of resources  

SciTech Connect

Perhaps the greatest beneficiary of electricity reform in Australia was the state government of Victoria itself, which was able to reduce debt levels and post budget surpluses even while increasing expenditure and employment levels in education, health care, and law and order. (author)

Abbott, Malcolm

2007-08-15T23:59:59.000Z

339

Financial and ratepayer impacts of nuclear power plant regulatory reform  

SciTech Connect

Three reports - ''The Future Market for Electric Generating Capacity,'' ''Quantitative Analysis of Nuclear Power Plant Licensing Reform,'' and ''Nuclear Rate Increase Study'' are recent studies performed by the Los Alamos National Laboratory that deal with nuclear power. This presents a short summary of these three studies. More detail is given in the reports.

Turpin, A.G.

1985-01-01T23:59:59.000Z

340

Fixed-bed reforming with mid-cycle catalyst addition  

Science Conference Proceedings (OSTI)

A fixed-bed catalytic reforming process is described in which on-stream operation is begun with the catalyst retention volume in the first reactor less than 99% full and additional catalyst is added to said reactor while on-stream.

Houston, R.J.; McCoy, C.S.

1981-02-17T23:59:59.000Z

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Tube skin temperature prediction of catalytic reforming unit (CRU) heaters  

Science Conference Proceedings (OSTI)

The maximum duty of reformer heaters is governed by the occurance of maximum tube skin temperature of the heaters. The value of maximum tube skin temperatures of the heaters must not exceed theirs' maximum allowable design temperature. The paper highlights ... Keywords: coke formation, finite element, simulations, tube furnance

Suzana Yusup; Nguyen Duy Vinh; Nurhayati Mellon; Abdullah Hassan

2006-10-01T23:59:59.000Z

342

Technology Capabilities  

NLE Websites -- All DOE Office Websites (Extended Search)

Homeland Security & Defense Homeland Security & Defense Information Technology & Communications Information Technology & Communications Sensors, Electronics &...

343

Separation of normally gaseous hydrocarbons from a catalytic reforming effluent and recovery of purified hydrogen  

Science Conference Proceedings (OSTI)

A process for the catalytic reforming of a hydrocarbonaceous feedstock, preferably to produce high quality gasoline boiling range products, is disclosed. Relatively impure hydrogen is separated from the reforming zone effluent, compressed, and recontacted with at least a portion of the liquid reformate product to provide relatively pure hydrogen, a portion of which is recycled to the reforming zone. The balance is further compressed and recontacted with at least a portion of the liquid reformate product to provide an improved recovery of normally gaseous hydrocarbons as well as an improved recovery of purified hydrogen at a pressure suitable for use in the relatively high pressure hydrotreating of sulfur-containing feedstocks.

Coste, A.C.

1982-06-08T23:59:59.000Z

344

Slide 1  

NLE Websites -- All DOE Office Websites (Extended Search)

48 Business Decision Criteria 48 Business Decision Criteria Renee H. Spires Technology Development May 21, 2009 5/21/09 2 Tank 48 Business Decision Criteria Technology development for the treatment of Tank 48 was invested in two alternatives - Fluidized Bed Steam Reforming (FBSR) - Wet Air Oxidation (WAO) Systems engineering processes were used to identify, define and weigh a set of criteria to perform selection of alternatives - Designed with flexibility so that the criteria can be applied to the Tank 48 technology selection at any time The business decision will result in the design, deployment and operation of the selected alternative for the treatment of Tank 48 5/21/09 3 Agenda Tank 48 Background and Importance Development of Criteria Comparison to Past Evaluations Status

345

ANNUAL NAEE/IAEE INTERNATIONAL CONFERENCE ENERGY TECHNOLOGY AND INFRASTRUCTURE FOR SUSTAINABLE  

E-Print Network (OSTI)

5TH ANNUAL NAEE/IAEE INTERNATIONAL CONFERENCE ENERGY TECHNOLOGY AND INFRASTRUCTURE FOR SUSTAINABLE a decade of energy sector and economy-wide reforms, many African countries are confronted with the challenges of the choice and funding of appropriate technology and requisite infrastructure to deliver energy

Texas at Austin, University of

346

Vendor / Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

Brake Assessment Tools Commercial Motor Vehicle Roadside Technology Corridor Safety Technology Showcase October 14, 2010 Commercial Motor Vehicle Roadside Technology Corridor...

347

Vendor / Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

Brake-Related Research Commercial Motor Vehicle Roadside Technology Corridor Safety Technology Showcase October 14, 2010 Commercial Motor Vehicle Roadside Technology Corridor...

348

Faience Technology  

E-Print Network (OSTI)

by Joanne Hodges. Faience Technology, Nicholson, UEE 2009Egyptian materials and technology, ed. Paul T. Nicholson,Nicholson, 2009, Faience Technology. UEE. Full Citation:

Nicholson, Paul

2009-01-01T23:59:59.000Z

349

Reforming petroleum-based fuels for fuel cell vehicles : composition-performance relationships.  

DOE Green Energy (OSTI)

Onboard reforming of petroleum-based fuels, such as gasoline, may help ease the introduction of fuel cell vehicles to the marketplace. Although gasoline can be reformed, it is optimized to meet the demands of ICEs. This optimization includes blending to increase the octane number and addition of oxygenates and detergents to control emissions. The requirements for a fuel for onboard reforming to hydrogen are quite different than those for combustion. Factors such as octane number and flame speed are not important; however, factors such as hydrogen density, catalyst-fuel interactions, and possible catalyst poisoning become paramount. In order to identify what factors are important in a hydrocarbon fuel for reforming to hydrogen and what factors are detrimental, we have begun a program to test various components of gasoline and blends of components under autothermal reforming conditions. The results indicate that fuel composition can have a large effect on reforming behavior. Components which may be beneficial for ICEs for their octane enhancing value were detrimental to reforming. Fuels with high aromatic and naphthenic content were more difficult to reform. Aromatics were also found to have an impact on the kinetics for reforming of paraffins. The effects of sulfur impurities were dependent on the catalyst. Sulfur was detrimental for Ni, Co, and Ru catalysts. Sulfur was beneficial for reforming with Pt catalysts, however, the effect was dependent on the sulfur concentration.

Kopasz, J. P.; Miller, L. E.; Ahmed, S.; Devlin, P. R.; Pacheco, M.

2001-12-04T23:59:59.000Z

350

Contract reform: It`s working at Fernald  

SciTech Connect

DOE`s contract reform initiatives at Fernald and the performance-based system DOE is now using to evaluate FERMCO are key elements to the current and future success of DOE and FERMCO at Fernald. Final cleanup of the Fernald site is planned for completion by 2005 per an accelerated 10-year remediation plan which has been approved by DOE and endorsed by the US EPA, Ohio EPA, and the Fernald Citizens Task Force. Required funding of approximately $276 million plus inflation annually for 10 years to accomplish final cleanup is now being considered by US Congress. Contract reform initiatives and modified performance measurement systems, along with best business practices, are clearing the path for the expedited cleanup of Fernald.

Craig, J. [USDOE Fernald Area Office, Cincinnati, OH (United States); Hunt, A. [Fernald Environmental Restoration Management Corp., Cincinnati, OH (United States)

1996-01-25T23:59:59.000Z

351

Corrosion protection of reforming equipment during regeneration of the catalyst  

Science Conference Proceedings (OSTI)

The authors discuss the important process of catalytic reforming to produce the basic components of high-octane gasolines and aromatic hydrocarbons in petroleum chemistry. Wide use is made of two-stage oxidative regeneration--coke burning and oxychlorination. This increases the activity of the catalysts. The authors developed a two-stage industrial method of corrosion protection for the low-temperature equipment of catalytic reforming plants during catalyst regeneration. The system is washed, before catalyst regeneration, with an aqueous solution of KLOE-15 in order to remove corrosion products already present. During catalyst regeneration, KLOE-15 and a neutralizing additive are fed in. The method is technically simple and economically effective, and has been introduced in a number of petroleum refineries.

Altsybeeva, A.I.; Andreeva, G.A.; Prasolova, O.N.; Ratner, E.M.; Reshetnikov, S.M.; Teslya, B.M.

1986-01-01T23:59:59.000Z

352

Reforming with an improved platinum-containing catalyst  

Science Conference Proceedings (OSTI)

A catalyst is disclosed which comprises a physical particle-form mixture of a Component A and a Component B. Said Component A comprises one or more Group VIII noble metals and combined halogen deposed on a refractory inorganic oxide and said Component B comprising a metal from Group IVB or Group VB of the Periodic Table of Elements and a combined halogen deposed on a refrac inorganic oxide. Such catalyst is suitable for use in a hydrocarbon conversion reaction zone. The catalyst can be employed in a process for the reforming of a hydrocarbon stream, which process comprises contacting said stream in a reaction zone under reforming conditions and in the presence hydrogen with said catalyst. The catalyst is not presulfided. A preferred process comprises contacting a hydrocarbon stream that contains a substantial amount of sulfur.

Pellet, R.J.; Bertolacini, R.J.; Lysholm, D.L.

1983-08-30T23:59:59.000Z

353

Reforming with an improved platinum-containing catalyst  

Science Conference Proceedings (OSTI)

There is disclosed a catalyst, which catalyst comprises a physical particle-form mixture of a component A and a component B , said component A comprising one or more group VIII noble metals and a combined halogen deposed on a refractory inorganic oxide and said component B comprising a metal from group IVB or group VB of the periodic table of elements and a combined halogen deposed on a refractory inorganic oxide. Such catalyst is suitable for use in a hydrocarbon conversion reaction zone. The catalyst can be employed in a process for the reforming of a hydrocarbon stream, which process comprises contacting said stream in a reaction zone under reforming conditions and in the presence of hydrogen with said catalyst. The catalyst is not presulfided. A preferred process comprises contacting a hydrocarbon stream that contains a substantial amount of sulfur.

Bertolacini, R.J.; Lysholm, D.L.; Pellet, R.J.

1982-10-12T23:59:59.000Z

354

Technology Search Results | Brookhaven Technology ...  

There are no technology records available that match the search query. Find a Technology. Search our technologies by categories or by keywords.

355

Technology Transfer: Available Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

test test Please refer to the list of technologies below for licensing and research collaboration availability. If you can't find the technology you're interested in, please contact us at TTD@lbl.gov. Energy ENERGY EFFICIENT TECHNOLOGIES Aerosol Sealing Aerosol Remote Sealing System Clog-free Atomizing and Spray Drying Nozzle Air-stable Nanomaterials for Efficient OLEDs Solvent Processed Nanotube Composites OLEDS with Air-stable Structured Electrodes APIs for Online Energy Saving Tools: Home Energy Saver and EnergyIQ Carbon Dioxide Capture at a Reduced Cost Dynamic Solar Glare Blocking System Electrochromic Device Controlled by Sunlight Electrochromic Windows with Multiple-Cavity Optical Bandpass Filter Electrochromic Window Technology Portfolio Universal Electrochromic Smart Window Coating

356

Making sense of doctoral training reforms in the social sciences:  

E-Print Network (OSTI)

process, occurring through collective reflection and action, whether at the level of the department, institution or the discipline (eg McAlpine et al 2005). Within the UK, this recognition has led the higher education funding council to support a... of this emerging field of academic practice and point to some of the challenges ahead. Within the field of doctoral education, I suggest that these curriculum reforms are often led by senior academic administrators who put their own policy knowledge to good use...

Mills, David

2009-01-01T23:59:59.000Z

357

Fuel cell system with combustor-heated reformer  

DOE Patents (OSTI)

A fuel cell system including a fuel reformer heated by a catalytic combustor fired by anode effluent and/or fuel from a liquid fuel supply providing fuel for the fuel cell. The combustor includes a vaporizer section heated by the combustor exhaust gases for vaporizing the fuel before feeding it into the combustor. Cathode effluent is used as the principle oxidant for the combustor.

Pettit, William Henry (Rochester, NY)

2000-01-01T23:59:59.000Z

358

Power sector reform, private investment and regional co-operation  

E-Print Network (OSTI)

Europe and stimulated FDI in the power sector, and might have similarly stimulative effects in South Asia, quite apart from creating profitable trade opportunities and increasing regional security of supply and greater resilience against external oil... of the Electricity Reforms Act in 1997 setting up the Regulatory Commission. “The state government has directed district administrators and police officials to support the distribution companies for curtailing frauds, theft, etc., but the actual implementation...

Newbery, David

359

Autothermal reforming of natural gas to synthesis gas:reference: KBR paper #2031.  

DOE Green Energy (OSTI)

This Project Final Report serves to document the project structure and technical results achieved during the 3-year project titled Advanced Autothermal Reformer for US Dept of Energy Office of Industrial Technology. The project was initiated in December 2001 and was completed March 2005. It was a joint effort between Sandia National Laboratories (Livermore, CA), Kellogg Brown & Root LLC (KBR) (Houston, TX) and Sued-Chemie (Louisville, KY). The purpose of the project was to develop an experimental capability that could be used to examine the propensity for soot production in an Autothermal Reformer (ATR) during the production of hydrogen-carbon monoxide synthesis gas intended for Gas-to-Liquids (GTL) applications including ammonia, methanol, and higher hydrocarbons. The project consisted of an initial phase that was focused on developing a laboratory-scale ATR capable of reproducing conditions very similar to a plant scale unit. Due to budget constraints this effort was stopped at the advanced design stages, yielding a careful and detailed design for such a system including ATR vessel design, design of ancillary feed and let down units as well as a PI&D for laboratory installation. The experimental effort was then focused on a series of measurements to evaluate rich, high-pressure burner behavior at pressures as high as 500 psi. The soot formation measurements were based on laser attenuation at a view port downstream of the burner. The results of these experiments and accompanying calculations show that soot formation is primarily dependent on oxidation stoichiometry. However, steam to carbon ratio was found to impact soot production as well as burner stability. The data also showed that raising the operating pressure while holding mass flow rates constant results in considerable soot formation at desirable feed ratios. Elementary reaction modeling designed to illuminate the role of CO{sub 2} in the burner feed showed that the conditions in the burner allow for the direct participation of CO{sub 2} in the oxidation chemistry.

Mann, David (KBR, Houston, TX); Rice, Steven, D.

2007-04-01T23:59:59.000Z

360

The Effect of Oxygen to Methane Ratio on the Methane-wet Air Autothermal Reforming and Carbon Deposition in the Micro-chamber  

Science Conference Proceedings (OSTI)

Considering the problems of catalyst carbon deposition and reforming endothermic reaction in micro-reforming chamber, coupled methane catalyst partial oxidation and steam methane reforming can make the micro-reforming system auto-supply heat and inhibit ... Keywords: micro-chamber, autothermal reforming, carbon deposition, oxygen to methane ratio

Ran Jingyu; Tu Weifeng

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

FY 2009 National Security Technologies, LLC, PER Summary | National Nuclear  

National Nuclear Security Administration (NNSA)

National Security Technologies, LLC, PER Summary | National Nuclear National Security Technologies, LLC, PER Summary | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog FY 2009 National Security Technologies, LLC, PER Summary Home > About Us > Our Operations > Acquisition and Project Management > Performance Evaluations > FY 2009 National Security Technologies, LLC, PER

362

FY 2011 National Security Technologies, LLC, PER Summary | National Nuclear  

National Nuclear Security Administration (NNSA)

National Security Technologies, LLC, PER Summary | National Nuclear National Security Technologies, LLC, PER Summary | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog FY 2011 National Security Technologies, LLC, PER Summary Home > About Us > Our Operations > Acquisition and Project Management > Performance Evaluations > FY 2011 National Security Technologies, LLC, PER

363

Prototype system brings advantages of wireless technology to secure  

National Nuclear Security Administration (NNSA)

Prototype system brings advantages of wireless technology to secure Prototype system brings advantages of wireless technology to secure environment | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog Home > NNSA Blog > Prototype system brings advantages of wireless technology ... Prototype system brings advantages of wireless technology to secure environment

364

FY 2007 National Security Technologies, LLC, PER Summary | National Nuclear  

National Nuclear Security Administration (NNSA)

National Security Technologies, LLC, PER Summary | National Nuclear National Security Technologies, LLC, PER Summary | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog FY 2007 National Security Technologies, LLC, PER Summary Home > About Us > Our Operations > Acquisition and Project Management > Performance Evaluations > FY 2007 National Security Technologies, LLC, PER

365

University Program in Advanced Technology | National Nuclear Security  

National Nuclear Security Administration (NNSA)

University Program in Advanced Technology | National Nuclear Security University Program in Advanced Technology | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog University Program in Advanced Technology Home > About Us > Our Programs > Defense Programs > Future Science & Technology Programs > Office of Advanced Simulation and Computing and

366

Electrochemical cell apparatus having an integrated reformer-mixer nozzle-mixer diffuser  

DOE Patents (OSTI)

An electrochemical apparatus is made having a generator section containing electrochemical cells, a fresh gaseous feed fuel inlet, a gaseous feed oxidant inlet, and at least one hot gaseous spent fuel recirculation channel, where the spent fuel recirculation channel, passes from the generator chamber to combine with the fresh feed fuel inlet to form a reformable mixture, where a reforming chamber contains an outer portion containing reforming material, an inner portion preferably containing a mixer nozzle and a mixer-diffuser, and a middle portion for receiving spent fuel, where the mixer nozzle and mixer-diffuser are preferably both within the reforming chamber and substantially exterior to the main portion of the apparatus, where the reformable mixture flows up and then backward before contacting the reforming material, and the mixer nozzle can operate below 400 C. 1 figure.

Shockling, L.A.

1991-09-10T23:59:59.000Z

367

Technology Search Results | Brookhaven Technology ...  

Staff Directory; BNL People Technology Commercialization & Partnerships. Home; For BNL Inventors; ... a nonprofit applied science and technology organization. ...

368

Technology Search Results | Brookhaven Technology ...  

Non-Noble Metal Water Electrolysis Catalysts; Find a Technology. Search our technologies by categories or by keywords. Search ...

369

Technology Search Results | Brookhaven Technology ...  

BSA 08-04: High Temperature Interfacial Superconductivity; Find a Technology. Search our technologies by categories or by keywords. Search ...

370

Technology Search Results | Brookhaven Technology ...  

Receive Technology Updates. Get email notifications about new or improved technologies in your area of interest. Subscribe »

371

Technology Transfer: Available Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Please refer to the list of technologies below for licensing and research Please refer to the list of technologies below for licensing and research collaboration availability. If you can't find the technology you're interested in, please contact us at TTD@lbl.gov. Biotechnology and Medicine DIAGNOSTICS AND THERAPEUTICS CANCER CANCER PROGNOSTICS 14-3-3 Sigma as a Biomarker of Basal Breast Cancer ANXA9: A Therapeutic Target and Predictive Marker for Early Detection of Aggressive Breast Cancer Biomarkers for Predicting Breast Cancer Patient Response to PARP Inhibitors Breast Cancer Recurrence Risk Analysis Using Selected Gene Expression Comprehensive Prognostic Markers and Therapeutic Targets for Drug-Resistant Breast Cancers Diagnostic Test to Personalize Therapy Using Platinum-based Anticancer Drugs Early Detection of Metastatic Cancer Progenitor Cells

372

Privatization and Other Post-Contract Reform Project Delivery Methods: What Works Best and Why  

Science Conference Proceedings (OSTI)

This paper explores the successes and failures of privatization and other contract reform initiatives within the DOE Weapons Complex over the past seven years. The paper concludes that the successes and failures of these project delivery methods depend largely on the risks attendant with the project itself. For example, where the wastes to be remediated defy characterization and the technology is innovative, the Department ordinarily should bear most of the risk, and some specie of cost-reimbursable contracting should be employed. On the other hand, where the risks are readily quantifiable and the technology is proven, more of the risk and responsibility can and should be placed on the contractor. This form of risk transference runs the continuum from lump-sum contracting to design/build, to privatization, depending on the circumstances. The preferred contracting form, however, is not dictated solely by project-related risk. Onto this risk must be overlain a set of risks that derive from the project management capabilities and the institutional biases of the oversight M&O or M&I contractor. Foremost among this additional set of risks is the ability of the oversight contractor to employ a level of contractual interface that is commensurate and proportionate with the selected project delivery method.

Person, J. C.

2003-02-27T23:59:59.000Z

373

Hydrogen Delivery Technologies and Systems - Pipeline Transmission of Hydrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Technologies and Technologies and Systems Pipeline Transmission of Hydrogen Strategic Initiatives for Hydrogen Delivery Workshop May 7- 8, 2003 U.S. Department of Energy â–  Hydrogen, Fuel Cells, and Infrastructure Technologies Program Pipeline Transmission of Hydrogen --- 2 Copyright: Design & Operation Standards Relevant Design and Operating Standards ANSI/ASME B31.8 49 CFR 192 CGA H 2 Pipeline Standard (in development) Pipeline Transmission of Hydrogen --- 3 Copyright: Future H 2 Infrastructure Wind Powered Electrolytic Separation Local Reformers Users Stationary Power Sources Vehicle Fueling Stations Distance from Source to User (Miles) <500 0-5 <2,000 <50 Off-peak Hydroelectric Powered Electrolytic Separation Large Reformers (scale economies) Pipeline Transmission of Hydrogen

374

Technology Transfer: Available Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Software and Information Technologies Software and Information Technologies Algorithm for Correcting Detector Nonlinearites Chatelet: More Accurate Modeling for Oil, Gas or Geothermal Well Production Collective Memory Transfers for Multi-Core Processors Energy Efficiency Software EnergyPlus:Energy Simulation Software for Buildings Tools, Guides and Software to Support the Design and Operation of Energy Efficient Buildings Flexible Bandwidth Reservations for Data Transfer Genomic and Proteomic Software LABELIT - Software for Macromolecular Diffraction Data Processing PHENIX - Software for Computational Crystallography Vista/AVID: Visualization and Allignment Software for Comparative Genomics Geophysical Software Accurate Identification, Imaging, and Monitoring of Fluid Saturated Underground Reservoirs

375

Electrochemical fuel cell generator having an internal and leak tight hydrocarbon fuel reformer  

DOE Patents (OSTI)

An electrochemical fuel cell generator configuration is made having a generator section which contains a plurality of axially elongated fuel cells, each cell containing a fuel electrode, air electrode, and solid oxide electrolyte between the electrodes, in which axially elongated dividers separate portions of the fuel cells from each other, and where at least one divider also reforms a reformable fuel gas mixture prior to electricity generation reactions, the at least one reformer-divider is hollow having a closed end and an open end entrance for a reformable fuel mixture to pass to the closed end of the divider and then reverse flow and pass back along the hollowed walls to be reformed, and then finally to pass as reformed fuel out of the open end of the divider to contact the fuel cells, and further where the reformer-divider is a composite structure having a gas diffusion barrier of metallic foil surrounding the external walls of the reformer-divider except at the entrance to prevent diffusion of the reformable gas mixture through the divider, and further housed in an outer insulating jacket except at the entrance to prevent short-circuiting of the fuel cells by the gas diffusion barrier. 10 figs.

Dederer, J.T.; Hager, C.A.

1998-03-31T23:59:59.000Z

376

Electrochemical fuel cell generator having an internal and leak tight hydrocarbon fuel reformer  

DOE Patents (OSTI)

An electrochemical fuel cell generator configuration is made having a generator section which contains a plurality of axially elongated fuel cells, each cell containing a fuel electrode, air electrode, and solid oxide electrolyte between the electrodes, in which axially elongated dividers separate portions of the fuel cells from each other, and where at least one divider also reforms a reformable fuel gas mixture prior to electricity generation reactions, the at least one reformer-divider is hollow having a closed end and an open end entrance for a reformable fuel mixture to pass to the closed end of the divider and then reverse flow and pass back along the hollowed walls to be reformed, and then finally to pass as reformed fuel out of the open end of the divider to contact the fuel cells, and further where the reformer-divider is a composite structure having a gas diffusion barrier of metallic foil surrounding the external walls of the reformer-divider except at the entrance to prevent diffusion of the reformable gas mixture through the divider, and further housed in an outer insulating jacket except at the entrance to prevent short-circuiting of the fuel cells by the gas diffusion barrier.

Dederer, Jeffrey T. (Valencia, PA); Hager, Charles A. (Mars, PA)

1998-01-01T23:59:59.000Z

377

Beyond National Uniformity: Diverging Local Economic Governance Under Japan's Decentralization Reforms  

E-Print Network (OSTI)

a Research Agenda for Public-Private Partnerships in thesectors in reforms for public-private partnership. Theunder the banner of public-private partnership. New

Lee, Jung Hwan

2010-01-01T23:59:59.000Z

378

Methodology and Estimation of the Welfare Impact of Energy Reforms on Households in Azerbaijan.  

E-Print Network (OSTI)

??ABSTRACT Title of Dissertation: METHODOLOGY AND ESTIMATION OF THE WELFARE IMPACT OF ENERGY REFORMS ON HOUSEHOLDS IN AZERBAIJAN Irina Klytchnikova, Doctor of Philosophy, 2006 Dissertation… (more)

Klytchnikova, Irina

2006-01-01T23:59:59.000Z

379

Regulatory Reform in the Wake of the Financial Crisis of 2007—2008  

E-Print Network (OSTI)

Purpose – The purpose of this paper is to analyse regulatory reform in the wake of the financial crisis of 2007-2008.

Lo, Andrew W.

380

Microchannel steam-methane reforming under constant and variable surface temperature distributions.  

E-Print Network (OSTI)

??Steam-methane reforming is a well understood industrial process used for generating hydrogen and synthesis gas. The reaction is generally carried out with residence times on… (more)

[No author

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

A Mixed-Dimensionality Modeling Approach for Interaction of Heterogeneous Steam Reforming Reactions and Heat Transfer.  

E-Print Network (OSTI)

??Hydrogen is most often produced on an industrial scale by catalytic steam methane reforming, an equilibrium-limited, highly endothermic process requiring the substantial addition of heat… (more)

Valensa, Jeroen

2009-01-01T23:59:59.000Z

382

Fuel-flexible partial oxidation reforming of hydrocarbons for automotive applications.  

DOE Green Energy (OSTI)

Micro-reactor tests indicate that our partial oxidation catalyst is fuel-flexible and can reform conventional (gasoline and diesel) and alternative (ethanol, methanol, natural gas) fuels to hydrogen rich product gases with high hydrogen selectivity. Alcohols are reformed at lower temperatures (< 600 C) while alkanes and unsaturated hydrocarbons require slightly higher temperatures. Cyclic hydrocarbons and aromatics have also been reformed at relatively low temperatures, however, a different mechanism appears to be responsible for their reforming. Complex fuels like gasoline and diesel, which are mixtures of a broad range of hydrocarbons, require temperatures of > 700 C for maximum hydrogen production.

Ahmed, S.; Carter, J. D.; Kopasz, J. P.; Krumpelt, M.; Wilkenhoener, R.

1999-06-07T23:59:59.000Z

383

The Politics of Revenue-Raising Tax Reform in Latin America  

E-Print Network (OSTI)

in the region. These rate increases, along with reforms toby the marginal tax rate increase of 1992. Other causallow despite a small rate increase in 2001—interviews with

Fairfield, Tasha

2010-01-01T23:59:59.000Z

384

Hard or Soft? Institutional Reforms and Infrastructure Spending as Determinants of Foreign Direct Investment in China  

E-Print Network (OSTI)

Soft? Institutional Reforms and Infrastructure Spending aswe examine whether hard infrastructure in the form of moreand railroads or soft infrastructure in the form of more

Fung, K. C.; Garcia-Herrero, Alicia; Iizaka, Hitomi; Siu, Alan

2005-01-01T23:59:59.000Z

385

The Ambiguous Transition: Building State Capacity and Expanding Popular Participation in Venezuela's Agrarian Reform  

E-Print Network (OSTI)

El Universal, Caracas, Venezuela. Bengelsdorf, Carollee.Crisis and Reform in Venezuela. ” Journal of Interamerican2):27-61. Datamonitor. (2004). “Venezuela Country Profile. ”

Page, Tiffany Linton

2011-01-01T23:59:59.000Z

386

Heat Transfer Limitations in Hydrogen Production Via Steam Reformation: The Effect of Reactor Geometry  

E-Print Network (OSTI)

Hydrogen production Reactors, M.S. Thesis, University ofREFORMATION: THE EFFECT OF REACTOR GEOMETRY David, R. ,have been manifest with reactors of different geometries. In

Vernon, David R.; Davieau, David D.; Dudgeon, Bryce A.; Erickson, Paul A.

2006-01-01T23:59:59.000Z

387

Sulfur-tolerant natural gas reforming for fuel-cell applications.  

E-Print Network (OSTI)

??An attractive simplification of PEM-FC systems operated with natural gas would be the use of a sulfur tolerant reforming catalyst, but such a catalyst has… (more)

Hennings, Ulrich

2010-01-01T23:59:59.000Z

388

ZEOLITE CATALYSIS - TECHNOLOGY  

E-Print Network (OSTI)

Rheume, eta/. XBL 805-1065 FIGURE 3 l •--Catalytic reforminga--Catalytic reforming+ selectoforming Q) E Q) +w u 70

Heinemann, Heinz

2013-01-01T23:59:59.000Z

389

PNNL: Available Technologies: Energy  

Smart Grid Devices. ... Redox Flow Batteries for Grid-scale Energy Storage; Fuel Cells. Introducing Fuel Oil into a Steam Reformer with Reduced Carbon ...

390

FEEDSTOCK-FLEXIBLE REFORMER SYSTEM (FFRS) FOR SOLID OXIDE FUEL CELL (SOFC)- QUALITY SYNGAS  

DOE Green Energy (OSTI)

The U.S. Department of Energy National Energy Technology Laboratory funded this research collaboration effort between NextEnergy and the University of Michigan, who successfully designed, built, and tested a reformer system, which produced highquality syngas for use in SOFC and other applications, and a novel reactor system, which allowed for facile illumination of photocatalysts. Carbon and raw biomass gasification, sulfur tolerance of non-Platinum Group Metals (PGM) based (Ni/CeZrO2) reforming catalysts, photocatalysis reactions based on TiO2, and mild pyrolysis of biomass in ionic liquids (ILs) were investigated at low and medium temperatures (primarily 450 to 850 C) in an attempt to retain some structural value of the starting biomass. Despite a wide range of processes and feedstock composition, a literature survey showed that, gasifier products had narrow variation in composition, a restriction used to develop operating schemes for syngas cleanup. Three distinct reaction conditions were investigated: equilibrium, autothermal reforming of hydrocarbons, and the addition of O2 and steam to match the final (C/H/O) composition. Initial results showed rapid and significant deactivation of Ni/CeZrO2 catalysts upon introduction of thiophene, but both stable and unstable performance in the presence of sulfur were obtained. The key linkage appeared to be the hydrodesulfurization activity of the Ni reforming catalysts. For feed stoichiometries where high H2 production was thermodynamically favored, stable, albeit lower, H2 and CO production were obtained; but lower thermodynamic H2 concentrations resulted in continued catalyst deactivation and eventual poisoning. High H2 levels resulted in thiophene converting to H2S and S surface desorption, leading to stable performance; low H2 levels resulted in unconverted S and loss in H2 and CO production, as well as loss in thiophene conversion. Bimetallic catalysts did not outperform Ni-only catalysts, and small Ni particles were found to have lower activities under S-free conditions, but did show less effect of S on performance, in this study. Imidazolium-based ILs, choline chloride compounds and low-melting eutectics of metal nitrates were evaluated, and it was found that, ILs have some capacity to dissolve cellulose and show thermal stability to temperatures where pyrolysis begins, have no vapor pressure, (simplifying product recoveries), and can dissolve ionic metal salts, allowing for the potential of catalytic reactions on breakdown intermediates. Clear evidence of photoactive commercial TiO2 was obtained, but in-house synthesis of photoactive TiO2 proved difficult, as did fixed-bed gasification, primarily due to the challenge of removing the condensable products from the reaction zone quickly enough to prevent additional reaction. Further investigation into additional non-PGM catalysts and ILs is recommended as a follow-up to this work.

Kelly Jezierski; Andrew Tadd; Johannes Schwank; Roland Kibler; David McLean; Mahesh Samineni; Ryan Smith; Sameer Parvathikar; Joe Mayne; Tom Westrich; Jerry Mader; F. Michael Faubert

2010-07-30T23:59:59.000Z

391

Autothermal and partial oxidation reformer-based fuel processor, method for improving catalyst function in autothermal and partial oxidation reformer-based processors  

DOE Patents (OSTI)

The invention provides a fuel processor comprising a linear flow structure having an upstream portion and a downstream portion; a first catalyst supported at the upstream portion; and a second catalyst supported at the downstream portion, wherein the first catalyst is in fluid communication with the second catalyst. Also provided is a method for reforming fuel, the method comprising contacting the fuel to an oxidation catalyst so as to partially oxidize the fuel and generate heat; warming incoming fuel with the heat while simultaneously warming a reforming catalyst with the heat; and reacting the partially oxidized fuel with steam using the reforming catalyst.

Ahmed, Shabbir; Papadias, Dionissios D.; Lee, Sheldon H. D.; Ahluwalia, Rajesh K.

2013-01-08T23:59:59.000Z

392

Columbia River Hatchery Reform System-Wide Report.  

SciTech Connect

The US Congress funded the Puget Sound and Coastal Washington Hatchery Reform Project via annual appropriations to the US Fish and Wildlife Service (USFWS) beginning in fiscal year 2000. Congress established the project because it recognized that while hatcheries have a necessary role to play in meeting harvest and conservation goals for Pacific Northwest salmonids, the hatchery system was in need of comprehensive reform. Most hatcheries were producing fish for harvest primarily to mitigate for past habitat loss (rather than for conservation of at-risk populations) and were not taking into account the effects of their programs on naturally spawning populations. With numerous species listed as threatened or endangered under the Endangered Species Act (ESA), conservation of salmon in the Puget Sound area was a high priority. Genetic resources in the region were at risk and many hatchery programs as currently operated were contributing to those risks. Central to the project was the creation of a nine-member independent scientific review panel called the Hatchery Scientific Review Group (HSRG). The HSRG was charged by Congress with reviewing all state, tribal and federal hatchery programs in Puget Sound and Coastal Washington as part of a comprehensive hatchery reform effort to: conserve indigenous salmonid genetic resources; assist with the recovery of naturally spawning salmonid populations; provide sustainable fisheries; and improve the quality and cost-effectiveness of hatchery programs. The HSRG worked closely with the state, tribal and federal managers of the hatchery system, with facilitation provided by the non-profit organization Long Live the Kings and the law firm Gordon, Thomas, Honeywell, to successfully complete reviews of over 200 hatchery programs at more than 100 hatcheries across western Washington. That phase of the project culminated in 2004 with the publication of reports containing the HSRG's principles for hatchery reform and recommendations for Puget Sound/Coastal Washington hatchery programs, followed by the development in 2005 of a suite of analytical tools to support application of the principles (all reports and tools are available at www.hatcheryreform.us). In 2005, Congress directed the National Oceanic and Atmospheric Administration-Fisheries (NOAA Fisheries) to replicate the Puget Sound and Coastal Washington Hatchery Reform Project in the Columbia River Basin. The HSRG was expanded to 14 members to include individuals with specific knowledge about the Columbia River salmon and steelhead populations. This second phase was initially envisioned as a one-year review, with emphasis on the Lower Columbia River hatchery programs. It became clear however, that the Columbia River Basin needed to be viewed as an inter-connected ecosystem in order for the review to be useful. The project scope was subsequently expanded to include the entire Basin, with funding for a second year provided by the Bonneville Power Administration (BPA) under the auspices of the Northwest Power and Conservation Council's (NPCC) Fish and Wildlife Program. The objective of the HSRG's Columbia River Basin review was to change the focus of the Columbia River hatchery system. In the past, these hatchery programs have been aimed at supplying adequate numbers of fish for harvest as mitigation primarily for hydropower development in the Basin. A new, ecosystem-based approach is founded on the idea that harvest goals are sustainable only if they are compatible with conservation goals. The challenge before the HSRG was to determine whether or not conservation and harvest goals could be met by fishery managers and, if so, how. The HSRG determined that in order to address these twin goals, both hatchery and harvest reforms are necessary. The HSRG approach represents an important change of direction in managing hatcheries in the region. It provides a clear demonstration that current hatchery programs can indeed be redirected to better meet both conservation and harvest goals. For each Columbia River Basin Environmentally Si

Warren, Dan [Hatchery Scientific Review Group

2009-04-16T23:59:59.000Z

393

Columbia River Hatchery Reform System-Wide Report.  

DOE Green Energy (OSTI)

The US Congress funded the Puget Sound and Coastal Washington Hatchery Reform Project via annual appropriations to the US Fish and Wildlife Service (USFWS) beginning in fiscal year 2000. Congress established the project because it recognized that while hatcheries have a necessary role to play in meeting harvest and conservation goals for Pacific Northwest salmonids, the hatchery system was in need of comprehensive reform. Most hatcheries were producing fish for harvest primarily to mitigate for past habitat loss (rather than for conservation of at-risk populations) and were not taking into account the effects of their programs on naturally spawning populations. With numerous species listed as threatened or endangered under the Endangered Species Act (ESA), conservation of salmon in the Puget Sound area was a high priority. Genetic resources in the region were at risk and many hatchery programs as currently operated were contributing to those risks. Central to the project was the creation of a nine-member independent scientific review panel called the Hatchery Scientific Review Group (HSRG). The HSRG was charged by Congress with reviewing all state, tribal and federal hatchery programs in Puget Sound and Coastal Washington as part of a comprehensive hatchery reform effort to: conserve indigenous salmonid genetic resources; assist with the recovery of naturally spawning salmonid populations; provide sustainable fisheries; and improve the quality and cost-effectiveness of hatchery programs. The HSRG worked closely with the state, tribal and federal managers of the hatchery system, with facilitation provided by the non-profit organization Long Live the Kings and the law firm Gordon, Thomas, Honeywell, to successfully complete reviews of over 200 hatchery programs at more than 100 hatcheries across western Washington. That phase of the project culminated in 2004 with the publication of reports containing the HSRG's principles for hatchery reform and recommendations for Puget Sound/Coastal Washington hatchery programs, followed by the development in 2005 of a suite of analytical tools to support application of the principles (all reports and tools are available at www.hatcheryreform.us). In 2005, Congress directed the National Oceanic and Atmospheric Administration-Fisheries (NOAA Fisheries) to replicate the Puget Sound and Coastal Washington Hatchery Reform Project in the Columbia River Basin. The HSRG was expanded to 14 members to include individuals with specific knowledge about the Columbia River salmon and steelhead populations. This second phase was initially envisioned as a one-year review, with emphasis on the Lower Columbia River hatchery programs. It became clear however, that the Columbia River Basin needed to be viewed as an inter-connected ecosystem in order for the review to be useful. The project scope was subsequently expanded to include the entire Basin, with funding for a second year provided by the Bonneville Power Administration (BPA) under the auspices of the Northwest Power and Conservation Council's (NPCC) Fish and Wildlife Program. The objective of the HSRG's Columbia River Basin review was to change the focus of the Columbia River hatchery system. In the past, these hatchery programs have been aimed at supplying adequate numbers of fish for harvest as mitigation primarily for hydropower development in the Basin. A new, ecosystem-based approach is founded on the idea that harvest goals are sustainable only if they are compatible with conservation goals. The challenge before the HSRG was to determine whether or not conservation and harvest goals could be met by fishery managers and, if so, how. The HSRG determined that in order to address these twin goals, both hatchery and harvest reforms are necessary. The HSRG approach represents an important change of direction in managing hatcheries in the region. It provides a clear demonstration that current hatchery programs can indeed be redirected to better meet both conservation and harvest goals. For each Columbia River Basin Environmentally Significant Unit

Warren, Dan [Hatchery Scientific Review Group

2009-04-16T23:59:59.000Z

394

Regulatory Reform and License Termination Planning in Decommissioning  

SciTech Connect

Decommissioning of commercial nuclear power plants (NPPs) must be safe and cost-effective and consider the needs of a wide range of stakeholders. The creative tension among these objectives has provided opportunities to reform the way these plants are regulated and managed in decommissioning. Enlightened and visionary leaders from the U.S. Nuclear Regulatory Commission (NRC) and industry are seizing these opportunities to create new paradigms for risk-informed regulation; creative stakeholder involvement; and effective, end-state focused, license termination planning.

Michael J. Meisner

2000-06-04T23:59:59.000Z

395

Electricity Reform in Chile: Lessons for Developing Countries  

E-Print Network (OSTI)

% for the country as a whole, but 58% in the central system)7 but as demand increases fossil fuels have become more important (in this it is comparable to Columbia and the south west of Brazil). However Chile is perhaps unusual among developing countries because... of the strength of protection for private property and the stability engendered by the long period of economically disciplined military rule. 2. Chile’s Electricity Reform In 1974 Chile’s electricity utilities were in a mess.8 Inflation, high fuel prices...

Pollitt, Michael G.

2006-03-14T23:59:59.000Z

396

DEVELOPMENT OF A CATALYST/SORBENT FOR METHANE REFORMING  

DOE Green Energy (OSTI)

This work has led to the initial development of a very promising material that has the potential to greatly simplify hydrocarbon reforming for the production of hydrogen and to improve the overall efficiency and economics of the process. This material, which was derived from an advanced calcium-based sorbent, was composed of core-in-shell pellets such that each pellet consisted of a CaO core and an alumina-based shell. By incorporating a nickel catalyst in the shell, a combined catalyst and sorbent was prepared to facilitate the reaction of hydrocarbons with steam. It was shown that this material not only catalyzes the reactions of methane and propane with steam, it also absorbs CO{sub 2} simultaneously, and thereby separates the principal reaction products, H{sub 2} and CO{sub 2}. Furthermore, the absorption of CO{sub 2} permits the water gas shift reaction to proceed much further towards completion at temperatures where otherwise it would be limited severely by thermodynamic equilibrium. Therefore, an additional water gas shift reaction step would not be required to achieve low concentrations of CO. In a laboratory test of methane reforming at 600 C and 1 atm it was possible to produce a gaseous product containing 96 mole% H{sub 2} (dry basis) while also achieving a H{sub 2} yield of 95%. Methane reforming under these conditions without CO{sub 2} absorption provided a H{sub 2} concentration of 75 mole% and yield of 82%. Similar results were achieved in a test of propane reforming at 560 C and 1 atm which produced a product containing 96 mole% H{sub 2} while CO{sub 2} was being absorbed but which contained only 69 mole% H{sub 2} while CO{sub 2} was not being absorbed. These results were achieved with an improved catalyst support that was developed by replacing a portion of the {alpha}-alumina in the original shell material with {gamma}-alumina having a much greater surface area. This replacement had the unfortunate consequence of reducing the overall compressive strength of the core-in-shell pellets. Therefore, a preliminary study of the factors that control the surface area and compressive strength of the shell material was conducted. The important factors were identified as the relative concentrations and particle size distributions of the {alpha}-alumina, {gamma}-alumina, and limestone particles plus the calcination temperature and time used for sintering the shell material. An optimization of these factors in the future could lead to the development of a material that has both the necessary mechanical strength and catalytic activity.

B.H. Shanks; T.D. Wheelock; Justinus A. Satrio; Timothy Diehl; Brigitte Vollmer

2004-09-27T23:59:59.000Z

397

Technology Transfer: Available Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Ion Sources and Beam Technologies Ion Sources and Beam Technologies GENERATORS AND DETECTORS Compact, Safe and Energy Efficient Neutron Generator Fast Pulsed Neutron Generator High Energy Gamma Generator Lithium-Drifted Silicon Detector with Segmented Contacts Low Power, High Energy Gamma Ray Detector Calibration Device Nested Type Coaxial Neutron Generator Neutron and Proton Generators: Cylindrical Neutron Generator with Nested Option, IB-1764 Neutron-based System for Nondestructive Imaging, IB-1794 Mini Neutron Tube, IB-1793a Ultra-short Ion and Neutron Pulse Production, IB-1707 Mini Neutron Generator, IB-1793b Compact Spherical Neutron Generator, IB-1675 Plasma-Driven Neutron/Gamma Generators Portable, Low-cost Gamma Source for Active Interrogation ION SOURCES WITH ANTENNAS External Antenna for Ion Sources

398

Tools & Technologies  

Energy.gov (U.S. Department of Energy (DOE))

We provide leadership for transforming workforce development through the power of technology. It develops corporate educational technology policy and enables the use of learning tools and...

399

Available Technologies  

The technology’s subnanometer resolution is a result of superior ... Additional R&D will be required ... U.S. DEPARTMENT OF ENERGY • OFFICE OF SCIENCE ...

400

MINERALIZING, STEAM REFORMING TREATMENT OF HANFORD LOW-ACTIVITY WASTE (a.k.a. INEEL/EXT-05-02526)  

SciTech Connect

The U.S. Department of Energy (DOE) documented, in 2002, a plan for accelerating cleanup of the Hanford Site, located in southeastern Washington State, by at least 35 years. A key element of the plan was acceleration of the tank waste program and completion of ''tank waste treatment by 2028 by increasing the capacity of the planned Waste Treatment Plant (WTP) and using supplemental technologies for waste treatment and immobilization.'' The plan identified steam reforming technology as a candidate for supplemental treatment of as much as 70% of the low-activity waste (LAW). Mineralizing steam reforming technology, offered by THOR Treatment Technologies, LLC would produce a denitrated, granular mineral waste form using a high-temperature fluidized bed process. A pilot scale demonstration of the technology was completed in a 15-cm-diameter reactor vessel. The pilot scale facility was equipped with a cyclone separator and heated sintered metal filters for particulate removal, a thermal oxidizer for reduced gas species and NOx destruction, and a packed activated carbon bed for residual volatile species capture. The pilot scale equipment is owned by the DOE, but located at the Science and Technology Applications Research (STAR) Center in Idaho Falls, ID. Pilot scale testing was performed August 2–5, 2004. Flowsheet chemistry and operational parameters were defined through a collaborative effort involving Idaho National Engineering and Environmental Laboratory (INEEL), Savannah River National Laboratory (SRNL), and THOR Treatment Technologies personnel. Science Application International Corporation, owners of the STAR Center, personnel performed actual pilot scale operation. The pilot scale test achieved a total of 68.4 hours of cumulative/continuous processing operation before termination in response to a bed de-fluidization condition. 178 kg of LAW surrogate were processed that resulted in 148 kg of solid product, a mass reduction of about 17%. The process achieved essentially complete bed turnover within approximately 40 hours. Samples of mineralized solid product materials were analyzed for chemical/physical properties. SRNL will report separately the results of product performance testing that were accomplished.

A. L. Olson; N. R. Soelberg; D. W. Marshall; G. L. Anderson

2005-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

A flexible computer software package for industrial steam reformers and methanators based on rigorous heterogeneous mathematical models  

Science Conference Proceedings (OSTI)

An advanced software package for industrial steam reformers based upon heterogeneous models for the catalyst tube is developed and successfully checked against a number of top-fired and side-fired industrial reformers. The package is further developed ...

F. M. Alhabdan; M. A. Abashar; S. S. E. Elnashaie

1992-11-01T23:59:59.000Z

402

Survey of the Economics of Hydrogen Technologies  

E-Print Network (OSTI)

Hydrogen Production Steam Methane Reforming Noncatalytic Partial Oxidation Coal Gasification Biomass Combustion Engines Hybrid Vehicles Onboard Storage Onboard Reforming Refueling Options Where possible

403

Evaluation of dissociated and steam-reformed methanol as automotive engine fuels  

SciTech Connect

Dissociated and steam reformed methanol were evaluated as automotive engine fuels. Advantages and disadvantages in using methanol in the reformed rather than liquid state are discussed. Engine dynamometer tests were conducted with a four cylinder, 2.3 liter, spark ignition automotive engine to determine performance and emission characteristics operating on simulated dissociated and steam reformed methanol (2H/sub 2/ + CO and 3H/sub 2/ + CO/sub 2/ respectively), and liquid methanol. Results are presented for engine performance and emissions as functions of equivalence ratio, at various throttle settings and engine speeds. Operation on dissociated and steam reformed methanol was characterized by flashback (violent propagation of a flame into the intake manifold) which limited operation to lower power output than was obtainable using liquid methanol. It was concluded that: an automobile could not be operated solely on dissociated or steam reformed methanol over the entire required power range - a supplementary fuel system or power source would be necessary to attain higher powers; the use of reformed methanol, compared to liquid methanol, may result in a small improvement in thermal efficiency in the low power range; dissociated methanol is a better fuel than steam reformed methanol for use in a spark ignition engine; and use of dissociated or steam reformed methanol may result in lower exhaust emissions compared to liquid methanol. 36 references, 27 figures, 3 tables.

Lalk, T.R.; McCall, D.M.; McCanlies, J.M.

1984-05-01T23:59:59.000Z

404

Performance of Sulfur Tolerant Reforming Catalysts for Production of Hydrogen from Jet Fuel Simulants  

E-Print Network (OSTI)

ReceiVed August 2, 2007 The development of robust desulfurizers and new reforming catalysts for fuel cells: the desulfurization of jet fuel and the development of sulfur-tolerant reforming catalysts/C) ratios. The water gas shift reaction is then used to convert additional CO into CO2. Nickel has been

Azad, Abdul-Majeed

405

Simulation and Optimization of the Stabilizer Tower Operation at Catalytic Reforming of Esfahan Oil Refining Company  

Science Conference Proceedings (OSTI)

Production of gasoline with low RVP specifications have made the operators of the catalytic reforming unit of Esfahan Oil refining company in Iran to apply new operating conditions. RVP is an abbreviation for Reid Vapor Pressure which is the vapor pressure ... Keywords: RVP, platformate, initial boiling point, catalytic reforming, distillation curve

Ali Izadyar; Bahram Hashemi Shahraki; Ahmad Shariati

2010-01-01T23:59:59.000Z

406

Achieving Universal Coverage through Comprehensive Health Reform: The Vermont Experience – Evaluation Results  

E-Print Network (OSTI)

Vermont’s comprehensive health reform law, the Health Care Affordability Acts (HCAA) for Vermonters, was passed in 2006 with the following three goals in mind: 1. To achieve universal access to affordable health insurance for all Vermonters 2. To improve quality of care and contain costs through health system reform

Ronald Deprez; Sherry Glied; Kira Rodriguez; Bill Perry; Brian Robertson; Nina Schwabe

2011-01-01T23:59:59.000Z

407

Catalytic reforming and hydrocracking of organic compounds employing promoted zinc titanate as the catalytic agent  

Science Conference Proceedings (OSTI)

The catalytic reforming of a feedstock which contains at least one reformable organic compound or the hydrocracking of a feedstock which contains at least one hydrocrackable organic compound is carried out in the presence of a catalyst composition comprising zinc, titanium and rhenium.

Drehman, L.E.; Farha, F.E.

1981-04-21T23:59:59.000Z

408

Catalytic reforming and hydrocracking of organic compounds employing zinc titanate as the catalytic agent  

Science Conference Proceedings (OSTI)

The catalytic reforming of a feedstock which contains at least one reformable organic compound or the hydrocracking of a feedstock which contains at least one hydrocrackable organic compound is carried out in the presence of a catalyst composition comprising zinc and titanium.

Drehman, L.E.; Farha, F.E.; Walker, D.W.

1981-04-21T23:59:59.000Z

409

Electricity Markets: Should the Rest of the World Adopt the UK Reforms?  

E-Print Network (OSTI)

PWP-069 Electricity Markets: Should the Rest of the World Adopt the UK Reforms? Catherine D;1 Electricity Markets: Should the Rest of the World Adopt the UK Reforms?1 By Catherine D. Wolfram2 Britain was one of the first countries to liberalize its electricity industry when it restructured and privatized

California at Berkeley. University of

410

Vehicle Technologies Office: Vehicle Technologies Office Organization...  

NLE Websites -- All DOE Office Websites (Extended Search)

Organization and Contacts Organization Chart for the Vehicle Technologies Program Fuel Technologies and Deployment, Technology Managers Advanced Combustion Engines, Technology...

411

Fuel Cell Technologies Office: Technology Validation  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Information Technology Validation Search Search Help Technology Validation EERE Fuel Cell Technologies Office Technology Validation Printable Version Share this resource...

412

Gregory H. Friedman: Provided for The Committee on Oversight and Government Reform U.S. House of Representatives  

Energy.gov (U.S. Department of Energy (DOE))

Gregory H. Friedman: Provided for The Committee on Oversight and Government Reform U.S. House of Representatives

413

Agenda Setting And The Role Of Leadership In National Health Care Reform During The Early 1990s  

E-Print Network (OSTI)

Health care reform was the dominant issue on the political agenda during the early 1990s. Few issues

Kang, Michael S,

2006-01-05T23:59:59.000Z

414

Chemistry - Technology Transfer: Available Technologies  

Please refer to the list of technologies below for licensing and research collaboration availability. If you can't find the technology you ...

415

Technology Analysis - Heavy Vehicle Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

the GPRA benefits estimates for EERE's Vehicle Technologies Program's heavy vehicle technology research activities. Argonne researchers develop the benefits analysis using four...

416

The Lessons of Practice: Domestic Policy Reform as a Way to Address Climate  

Open Energy Info (EERE)

The Lessons of Practice: Domestic Policy Reform as a Way to Address Climate The Lessons of Practice: Domestic Policy Reform as a Way to Address Climate Change Jump to: navigation, search Tool Summary LAUNCH TOOL Name: The Lessons of Practice: Domestic Policy Reform as a Way to Address Climate Change Agency/Company /Organization: International Institute for Sustainable Development (IISD) Topics: Policies/deployment programs Resource Type: Lessons learned/best practices Website: www.iisd.org/pdf/2009/bali_2_copenhagen_dom_policy_lessons.pdf The Lessons of Practice: Domestic Policy Reform as a Way to Address Climate Change Screenshot References: The Lessons of Practice[1] Summary "The objectives of this paper are threefold: to review experience to date with policy reforms that can help mitigate climate change, to review work

417

Federal Onshore Oil and Gas Leasing Reform Act of 1987 (FOOGLRA) | Open  

Open Energy Info (EERE)

Page Page Edit with form History Facebook icon Twitter icon » Federal Onshore Oil and Gas Leasing Reform Act of 1987 (FOOGLRA) Jump to: navigation, search Statute Name Federal Onshore Oil and Gas Leasing Reform Act of 1987 (FOOGLRA) Year 1987 Url FederalOnshore1987.jpg Description Another amendment to the Mineral Leasing Act, The Federal Onshore Oil and Gas Leasing Reform Act of 1987 granted the USDA Forest Service the authority to make decisions and implement regulations concerning the leasing of public domain minerals on National Forest System lands containing oil and gas. References Federal Onshore Oil and Gas Leasing Reform Act of 1987 (FOOGLRA)[1] Federal Onshore Oil and Gas Leasing Reform Act of 1987 (FOOGLRA) (30 U.S.C. § 181 et seq.) - Another amendment to the Mineral Leasing Act, The Federal

418

HYDROGEN PRODUCTION FOR FUEL CELLS VIA REFORMING COAL-DERIVED METHANOL  

DOE Green Energy (OSTI)

Hydrogen can be produced from many feedstocks including coal. The objectives of this project are to establish and prove a hydrogen production pathway from coal-derived methanol for fuel cell applications. This progress report is the tenth report submitted to the DOE reporting on the status and progress made during the course of the project. This report covers the time period of January 1-March 31, 2006. This quarter saw progress in six areas. These areas are: (1) The effect of catalyst dimension on steam reforming, (2) Transient characteristics of autothermal reforming, (3) Rich and lean autothermal reformation startup, (4) Autothermal reformation degradation with coal derived methanol, (5) Reformate purification system, and (6) Fuel cell system integration. All of the projects are proceeding on or slightly ahead of schedule.

Paul A. Erickson

2006-04-01T23:59:59.000Z

419

Separation of normally gaseous hydrocarbons from a catalytic reforming effluent and recovery of purified hydrogen  

Science Conference Proceedings (OSTI)

A process for the catalytic reforming of a hydrocarbonaceous feedstock, preferably to produce high quality gasoline boiling range products, is disclosed. Relatively impure hydrogen is separated from the reforming zone effluent, compressed, and recontacted with at least a portion of the liquid reformate product to provide relatively pure hydrogen, a portion of which is recycled to the reforming zone. The balance is further compressed and recontacted with at least a portion of the liquid reformate product in a plural stage absorption zone to provide an improved recovery of normally gaseous hydrocarbons as well as an improved recovery of purified hydrogen at a pressure suitable, for example, the relatively high pressure hydrotreating of sulfur-containing feedstocks.

O'brien, D.E.

1982-06-08T23:59:59.000Z

420

Catalytic reforming process using noble metal alkaline zeolites  

Science Conference Proceedings (OSTI)

This patent describes improvement in a process wherein a gasoline boiling range hydrocarbonaceous feedstock is catalytically reformed in the presence of hydrogen in a reforming process unit comprised of serially connected reactors wherein each of the reactors contains a supported noble metal-containing catalyst. The improvement comprises the noble-metal catalyst of at least one reactor being selected from the group consisting of alkaline faujasite zeolite, L zeolite and zeolites isostructural thereto, which catalysts are prepared by a: contacting an alkaline faujasite zeolite, L zeolite, or zeolite isostructural thereto, with a noble metal composition selected from Pt(acetylacetonate){sub 2} or Pd(acetylacetonate){sub 2} for an effective amount of time to form a substantially homogeneous mixture and to incorporate the platinum and/or palladium into the near surface regions of the zeolite, but not to disperse the platinum and/or palladium throughout the entire zeolite; and calcining the so treated zeolite at a temperature from about 250 {degrees} C to about 600 {degrees} C for an effective amount of time.

Schweizer, A.E.

1991-02-12T23:59:59.000Z

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Catalytic Reforming Downstream Processing of Fresh Feed Input  

U.S. Energy Information Administration (EIA) Indexed Site

Process: Catalytic Reforming Catalytic Cracking Catalytic Hydrocracking Delayed and Fluid Coking Period-Unit: Monthly-Thousand Barrels per Day Annual-Thousand Barrels per Day Process: Catalytic Reforming Catalytic Cracking Catalytic Hydrocracking Delayed and Fluid Coking Period-Unit: Monthly-Thousand Barrels per Day Annual-Thousand Barrels per Day Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Process Area Apr-13 May-13 Jun-13 Jul-13 Aug-13 Sep-13 View History U.S. 2,563 2,667 2,739 2,807 2,705 2,609 2010-2013 PADD 1 176 178 180 173 156 167 2010-2013 East Coast 166 164 163 161 140 153 2010-2013 Appalachian No. 1 9 14 16 12 15 14 2010-2013 PADD 2 642 638 668 695 677 615 2010-2013 Ind., Ill. and Ky. 426 411 426 460 450 399 2010-2013 Minn., Wis., N. Dak., S. Dak. 67 62 70 72 72 57 2010-2013 Okla., Kans., Mo.

422

[98e]-Catalytic reforming of gasoline and diesel fuel  

DOE Green Energy (OSTI)

Argonne National Laboratory is developing a fuel processor for converting liquid hydrocarbon fuels to a hydrogen-rich product suitable for a polymer electrolyte fuel cell stack. The processor uses an autothermal reformer to convert the feed to a mixture of hydrogen, carbon dioxide, carbon monoxide and water with trace quantities of other components. The carbon monoxide in the product gas is then converted to carbon dioxide in water-gas shift and preferential oxidation reactors. Fuels that have been tested include standard and low-sulfur gasoline and diesel fuel, and Fischer-Tropsch fuels. Iso-octane and n-hexadecane were also examined as surrogates for gasoline and diesel, respectively. Complete conversion of gasoline was achieved at 750 C in a microreactor over a novel catalyst developed at Argonne. Diesel fuel was completely converted at 850 C over this same catalyst. Product streams contained greater than 60% hydrogen on a dry, nitrogen-free basis with iso-octane, gasoline, and n-hexadecane. For a diesel fuel, product streams contained >50% hydrogen on a dry, nitrogen-free basis. The catalyst activity did not significantly decrease over >16 hours operation with the diesel fuel feed. Coke formation was not observed. The carbon monoxide fraction of the product gas could be reduced to as low as 1% on a dry, nitrogen-free basis when the water-gas shift reactors were used in tandem with the reformer.

Pereira, C.; Wilkenhoener, R.; Ahmed, S.; Krumpelt, M.

2000-02-29T23:59:59.000Z

423

FY 2007 Honeywell Federal Manufacturing & Technologies, LLC, PER Summary |  

National Nuclear Security Administration (NNSA)

Honeywell Federal Manufacturing & Technologies, LLC, PER Summary | Honeywell Federal Manufacturing & Technologies, LLC, PER Summary | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog FY 2007 Honeywell Federal Manufacturing & Technologies, LLC, PER Summary Home > About Us > Our Operations > Acquisition and Project Management > Performance Evaluations > FY 2007 Honeywell Federal Manufacturing &

424

FY 2011 Honeywell Federal Manufacturing & Technologies, LLC, PER Summary |  

National Nuclear Security Administration (NNSA)

Honeywell Federal Manufacturing & Technologies, LLC, PER Summary | Honeywell Federal Manufacturing & Technologies, LLC, PER Summary | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog FY 2011 Honeywell Federal Manufacturing & Technologies, LLC, PER Summary Home > About Us > Our Operations > Acquisition and Project Management > Performance Evaluations > FY 2011 Honeywell Federal Manufacturing &

425

FY 2010 Honeywell Federal Manufacturing & Technologies, LLC, PER Summary |  

National Nuclear Security Administration (NNSA)

Honeywell Federal Manufacturing & Technologies, LLC, PER Summary | Honeywell Federal Manufacturing & Technologies, LLC, PER Summary | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog FY 2010 Honeywell Federal Manufacturing & Technologies, LLC, PER Summary Home > About Us > Our Operations > Acquisition and Project Management > Performance Evaluations > FY 2010 Honeywell Federal Manufacturing &

426

FY 2012 National Security Technologies, LLC, PEP | National Nuclear  

National Nuclear Security Administration (NNSA)

PEP | National Nuclear PEP | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog FY 2012 National Security Technologies, LLC, PEP Home > About Us > Our Operations > Acquisition and Project Management > Performance Evaluations > FY 2012 National Security Technologies, LLC, PEP FY 2012 National Security Technologies, LLC, PEP

427

Available Technologies  

APPLICATIONS OF TECHNOLOGY: Thermal management for: microelectronic devices; solar cells and solar energy management systems ; refrigerators

428

Available Technologies  

Energy Storage and Recovery; Renewable Energy; Environmental Technologies. Monitoring and Imaging; Remediation; Modeling; Imaging & Lasers.

429

Catalysis Letters 59 (1999) 9394 93 Stepwise methane steam reforming: a route to CO-free hydrogen  

E-Print Network (OSTI)

Catalysis Letters 59 (1999) 93­94 93 Stepwise methane steam reforming: a route to CO-free hydrogen-free hydrogen. Keywords: methane decomposition, Ni/zirconia, steam gasification In order to utilize hydrogen of impurities, particularly carbon monoxide. Steam reforming, partial oxidation and au- tothermal reforming [1

Goodman, Wayne

430

Aligning modes of organization with technology: Critical transactions in the reform of infrastructures  

E-Print Network (OSTI)

in parenthesis) 24 Initiative to develop intelligent electricity networks include www.smartgrids.eu (2007

Paris-Sud XI, Université de

431

Fuel Cell Technologies Office: Technology Validation  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Technologies Office: Technology Validation to someone by E-mail Share Fuel Cell Technologies Office: Technology Validation on Facebook Tweet about Fuel Cell Technologies...

432

Fundamental kinetic modeling of the catalytic reforming process  

E-Print Network (OSTI)

In this work, a fundamental kinetic model for the catalytic reforming process has been developed. The complex network of elementary steps and molecular reactions occurring in catalytic reforming has been generated through a computer algorithm characterizing the various species by vectors and Boolean relation matrices. The algorithm is based on the fundamental chemistry occurring on both acid and metal sites of the catalyst. Rates are expressed for each of the elementary steps involved in the transformation of the intermediates. The Hougen-Watson approach is used to express the rates of the molecular reactions occurring on the metal sites of the catalyst. The single event approach is used to account for the effect of structure of reactant and activated complex on the rate coefficients of the elementary steps occurring on the acid sites. This approach recognizes that even if the number of elementary steps is very large they belong to a very limited number of types, and therefore it is possible to express the kinetics of elementary steps by a reduced number of parameters. In addition, the single event approach leads to rate coefficients that are independent of the feedstock, due to their fundamental chemical nature. The total number of parameters at isothermal conditions is 45. To estimate these parameters, an objective function based upon the sum of squares of the residuals was minimized through the Marquardt algorithm. Intraparticle mass transport limitations and deactivation of the catalyst by coke formation are considered in the model. Both the Wilke and the Stefan-Maxwell approaches were used to calculate the concentration gradients inside of the particle. The heterogeneous kinetic model was applied in the simulation of the process for typical industrial conditions for both axial and radial flow fixed bed reactors. The influence of the main process variables on the octane number and reformate volume was investigated and optimal conditions were obtained. Additional aspects studied with the kinetic model are the reduction of aromatics, mainly benzene. The results from the simulations agree with the typical performance found in the industrial process.

Sotelo-Boyas, Rogelio

2005-12-01T23:59:59.000Z

433

ELECTROCHEMISTRY AND ON-CELL REFORMATION MODELING FOR SOLID OXIDE FUEL CELL STACKS  

SciTech Connect

ABSTRACT Providing adequate and efficient cooling schemes for solid-oxide-fuel-cell (SOFC) stacks continues to be a challenge coincident with the development of larger, more powerful stacks. The endothermic steam-methane reformation reaction can provide cooling and improved system efficiency when performed directly on the electrochemically active anode. Rapid kinetics of the endothermic reaction typically causes a localized temperature depression on the anode near the fuel inlet. It is desirable to extend the endothermic effect over more of the cell area and mitigate the associated differences in temperature on the cell to alleviate subsequent thermal stresses. In this study, modeling tools validated for the prediction of fuel use, on-cell methane reforming, and the distribution of temperature within SOFC stacks, are employed to provide direction for modifying the catalytic activity of anode materials to control the methane conversion rate. Improvements in thermal management that can be achieved through on-cell reforming is predicted and discussed. Two operating scenarios are considered: one in which the methane fuel is fully pre-reformed, and another in which a substantial percentage of the methane is reformed on-cell. For the latter, a range of catalytic activity is considered and the predicted thermal effects on the cell are presented. Simulations of the cell electrochemical and thermal performance with and without on-cell reforming, including structural analyses, show a substantial decrease in thermal stresses for an on-cell reforming case with slowed methane conversion.

Recknagle, Kurtis P.; Jarboe, Daniel T.; Johnson, Kenneth I.; Korolev, Alexander; Khaleel, Mohammad A.; Singh, Prabhakar

2007-01-16T23:59:59.000Z

434

Membrane reactor advantages for methanol reforming and similar reactions  

Science Conference Proceedings (OSTI)

Membrane reactors achieve efficiencies by combining in one unit a reactor that generates a product with a semipermeable membrane that extracts it. One well-known benefit of this is greater conversion, as removal of a product drives reactions toward completion, but there are several potentially larger advantages that have been largely ignored. Because a membrane reactor tends to limit the partial pressure of the extracted product, it fundamentally changes the way that total pressure in the reactor affects equilibrium conversion. Thus, many gas-phase reactions that are preferentially performed at low pressures in a conventional reactor are found to have maximum conversion at high pressures in a membrane reactor. These higher pressures and reaction conversions allow greatly enhanced product extraction as well. Further, membrane reactors provide unique opportunities for temperature management which have not been discussed previously. These benefits are illustrated for methanol reforming to hydrogen for use with PEM (polymer electrolyte membrane) fuel cells.

Buxbaum, R.E. [REB Research and Consulting Co., Ferndale, MI (United States)

1999-07-01T23:59:59.000Z

435

Petroleum Refinery Catalytic Reforming -- Cutting High Energy Costs  

E-Print Network (OSTI)

Hydrocarbon reforming involves a variety of chemical reactions at high temperatures and pressures in the presence of suitable catalysts. The conversion of naptha to high octane aromatics requires high energy to initiate and sustain the reaction at temperatures of 850-950oF. Hydrogen - rich off - gases are fired in combinations of process furnaces. Heat is transferred to hydrocarbon fluids by radiation, principally. Feed or return stream temperatures determine the need for convection sections. It is essential that the operation and maintenance of these furnaces be optimized to minimize production costs. This paper describes the performance testing and evaluation of a set of ten refinery furnaces used to thermally drive several reforming reactors and to regenerate catalysts. Firing rates provide an input of 216.2 x 106 Btu/hr. to the furnaces, at $1.90 per 106 Btu. The units are fitted with multiple natural draft burners. There is insufficient turbulence and swirl in the burners. Operators manually set up the burners with excessive airflows for normal, full-load firing. These furnaces represent production limits. Products of combustion exhaust at high thermal levels - the range is from 985-1700oF. The mixed gases flow through a "waste heat" boiler, or they bypass the boiler and enter a single stack. Steam generation at 150 psig averages 38,200 lb/hr. Heat is wasted via the bypass at a rate of 41.1x106 Btu /hr. at 1240oF. When airflows are reduced (to 15% excess air) the loss will be 18.7x106 Btu/hr. at 1180oF. Installation of a second, parallel waste heat boiler will result in a saving of l3.4x106 Btu/hr. Energy savings at this furnace complex will be equivalent to $628,700 per year. Investment costs were estimated to be less than $250,000 for the proposed heat trap addition.

Viar, W. L.

1979-01-01T23:59:59.000Z

436

,"Catalytic Reforming Downstream Processing of Fresh Feed Input"  

U.S. Energy Information Administration (EIA) Indexed Site

Catalytic Reforming Downstream Processing of Fresh Feed Input" Catalytic Reforming Downstream Processing of Fresh Feed Input" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Catalytic Reforming Downstream Processing of Fresh Feed Input",16,"Monthly","9/2013","1/15/2010" ,"Release Date:","11/27/2013" ,"Next Release Date:","Last Week of December 2013" ,"Excel File Name:","pet_pnp_dwns_a_(na)_ydr_mbblpd_m.xls" ,"Available from Web Page:","http://www.eia.gov/dnav/pet/pet_pnp_dwns_a_(na)_ydr_mbblpd_m.htm" ,"Source:","Energy Information Administration"

437

Investigation of Bio-Ethanol Steam Reforming over Cobalt-based Catalysts (Presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE Bio-Derived Liquids to Hydrogen Distributed DOE Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group (BILIWG) Meeting Investigation of Bio-Ethanol Steam Reforming over Cobalt-based Catalysts Hua Song Lingzhi Zhang Umit S. Ozkan* November 6 th , 2007 Heterogeneous Catalysis Research Group Department of Chemical and Biomolecular Engineering The Ohio State University Columbus, OH 43210 *Ozkan.1@osu.edu Biomass to Hydrogen (Environmentally Friendly) Plant cultivation Plant cultivation Saccharification Saccharification / / Fermentation Fermentation Anaerobic digestion Anaerobic digestion Residues of Residues of agroindustries agroindustries and cultivations and cultivations Municipal Solid Waste Municipal Solid Waste (organic fraction) (organic fraction) Distillation Distillation Reformation of ethanol

438

Modeling of On-Cell Reforming Reaction for Planar SOFC Stacks  

Science Conference Proceedings (OSTI)

Planar Solid Oxide Fuel Cell (SOFC) stack is known to suffer thermal problem from high stack temperature during operation to generate high current. On-Cell Reforming (OCR) phenomenon is often used to reduce stack temperature by an endothermic reaction of steam-methane reforming process. RIST conducted single-cell experiment to validate modeling tool to simulate OCR performance including temperature measurement. 2D modeling is used to check reforming rate during OCR using temperature measurement data, and 3D modeling is used to check overall thermal performance including furnace boundary conditions.

Yang, Choongmo; Lim, Hyung-Tae; Hwang, Soon Cheol; Kim, Dohyung; Lai, Canhai; Koeppel, Brian J.; Recknagle, Kurtis P.; Khaleel, Mohammad A.

2011-05-30T23:59:59.000Z

439

Catalytic reforming with a platinum group and phosphorus-containing composition  

Science Conference Proceedings (OSTI)

A new catalyst composition for converting hydrocarbons is disclosed. Also disclosed is a method for making the catalyst. The catalyst comprises a platinum group component and a phosphorous component with a porous support material. The catalyst is made by compositing a platinum group component with a porous support material and then contacting that composite with phosphorus or a compound of phosphorus. In a preferred embodiment of the invention a catalyst comprising platinum, phosphorus and chlorine with alumina is utilized in the catalytic reforming of hydrocarbons boiling in the gasoline range to produce a high octane reformate suitable for gasoline blending or a high aromatics content reformate suitable as a petrochemical feedstock.

Antos, G. J.; Chao, T.-H.

1984-11-20T23:59:59.000Z

440

Internal natural gas reformer-dividers for a solid oxide fuel cell generator configuration  

Science Conference Proceedings (OSTI)

This patent describes a fuel cell generator configuration. It comprises electrically connected, axially elongated, fuel cells, each cell having an outer and inner electrode with solid oxide electrolyte therebetween; where elongated dividers separate and are positioned between fuel cells, and where at least one of the elongated dividers is hollow, the hollow divider having solid elongated walls, a reformable fuel mixture entrance, and an exit allowing passage of reformed fuel to the fuel cells, and where the cross-section of the divider contains a catalytic reforming material.

Reichner, P.

1992-01-21T23:59:59.000Z

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Processing Technology  

Science Conference Proceedings (OSTI)

Aug 5, 2013... relevant polymers and hybrid nanocomposite material systems. ... technology to perform lightweight manufacturing of car components.

442

Technology Transfer  

A new search feature has been implemented, which allows searching of technology transfer information across the Department of Energy Laboratories.

443

Technology Transfer  

Science Conference Proceedings (OSTI)

... get started on understanding accessibility in elections and voting technology. ... bibliography was created by the Georgia Tech Research Institute ...

2013-09-17T23:59:59.000Z

444

A Novel Slurry-Based Biomass Reforming Process Final Technical Report  

SciTech Connect

This project was focused on developing a catalytic means of producing H2 from raw, ground biomass, such as fast growing poplar trees, willow trees, or switch grass. The use of a renewable, biomass feedstock with minimal processing can enable a carbon neutral means of producing H2 in that the carbon dioxide produced from the process can be used in the environment to produce additional biomass. For economically viable production of H2, the biomass is hydrolyzed and then reformed without any additional purification steps. Any unreacted biomass and other byproduct streams are burned to provide process energy. Thus, the development of a catalyst that can operate in the demanding corrosive environment and presence of potential poisons is vital to this approach. The concept for this project is shown in Figure 1. The initial feed is assumed to be a >5 wt% slurry of ground wood in dilute base, such as potassium carbonate (K2CO3). Base hydrolysis and reforming of the wood is carried out at high but sub-critical pressures and temperatures in the presence of a solid catalyst. A Pd alloy membrane allows the continuous removal of pure , while the retentate, including methane is used as fuel in the plant. The project showed that it is possible to economically produce H2 from woody biomass in a carbon neutral manner. Technoeconomic analyses using HYSYS and the DOE's H2A tool [1] were used to design a 2000 ton day-1 (dry basis) biomass to hydrogen plant with an efficiency of 46% to 56%, depending on the mode of operation and economic assumptions, exceeding the DOE 2012 target of 43%. The cost of producing the hydrogen from such a plant would be in the range of $1/kg H2 to $2/kg H2. By using raw biomass as a feedstock, the cost of producing hydrogen at large biomass consumption rates is more cost effective than steam reforming of hydrocarbons or biomass gasification and can achieve the overall cost goals of the DOE Fuel Cell Technologies Program. The complete conversion of wood to hydrogen, methane, and carbon dioxide was repeatedly demonstrated in batch reactors varying in size from 50 mL to 7.6 L. The different wood sources (e.g., swamp maple, poplar, and commercial wood flour) were converted in the presence of a heterogeneous catalyst and base at relatively low temperatures (e.g., 310 �������°C) at sub-critical pressures sufficient to maintain the liquid phase. Both precious metal and base metal catalysts were found to be active for the liquid phase hydrolysis and reforming of wood. Pt-based catalysts, particularly Pt-Re, were shown to be more selective toward breaking C-C bonds, resulting in a higher selectivity to hydrogen versus methane. Ni-based catalysts were found to prefer breaking C-O bonds, favoring the production of methane. The project showed that increasing the concentration of base (base to wood ratio) in the presence of Raney Ni catalysts resulted in greater selectivity toward hydrogen but at the expense of increasing the production of undesirable organic acids from the wood, lowering the amount of wood converted to gas. It was shown that by modifying Ni-based catalysts with dopants, it was possible to reduce the base concentration while maintaining the selectivity toward hydrogen and increasing wood conversion to gas versus organic acids. The final stage of the project was the construction and testing of a demonstration unit for H2 production. This continuous flow demonstration unit consisted of wood slurry and potassium carbonate feed pump systems, two reactors for hydrolysis and reforming, and a gas-liquid separation system. The technical challenges associated with unreacted wood fines and Raney Ni catalyst retention limited the demonstration unit to using a fixed bed Raney Ni catalyst form. The lower activity of the larger particle Raney Ni in turn limited the residence time and thus the wood mass flow feed rate to 50 g min-1 for a 1 wt% wood slurry. The project demonstrated continuous H2 yields with unmodified, fixed bed Raney Ni, from 63% to 100% with correspond

Sean C. Emerson; Timothy D. Davis; A. Peles; Ying She; Joshua Sheffel; Rhonda R. Willigan; Thomas H. Vanderspurt; Tianli Zhu

2011-09-30T23:59:59.000Z

445

97e Intermediate Temperature Catalytic Reforming of Bio-Oil for Distributed Hydrogen Production  

Science Conference Proceedings (OSTI)

With the world's energy demands rapidly increasing, it is necessary to look to sources other than fossil fuels, preferably those that minimize greenhouse emissions. One such renewable source of energy is biomass, which has the added advantage of being a near-term source of hydrogen. While there are several potential routes to produce hydrogen from biomass thermally, given the near-term technical barriers to hydrogen storage and delivery, distributed technologies such that hydrogen is produced at or near the point of use are attractive. One such route is to first produce bio-oil via fast pyrolysis of biomass close to its source to create a higher energy-density product, then ship this bio-oil to its point of use where it can be reformed to hydrogen and carbon dioxide. This route is especially well suited for smaller-scale reforming plants located at hydrogen distribution sites such as filling stations. There is also the potential for automated operation of the conversion system. A system has been developed for volatilizing bio-oil with manageable carbon deposits using ultrasonic atomization and by modifying bio-oil properties, such as viscosity, by blending or reacting bio-oil with methanol. Non-catalytic partial oxidation of bio-oil is then used to achieve significant conversion to CO with minimal aromatic hydrocarbon formation by keeping the temperature at 650 C or less and oxygen levels low. The non-catalytic reactions occur primarily in the gas phase. However, some nonvolatile components of bio-oil present as aerosols may react heterogeneously. The product gas is passed over a packed bed of precious metal catalyst where further reforming as well as water gas shift reactions are accomplished completing the conversion to hydrogen. The approach described above requires significantly lower catalyst loadings than conventional catalytic steam reforming due to the significant conversion in the non-catalytic step. The goal is to reform and selectively oxidize the bio-oil and catalyze the water gas shift reaction without catalyzing methanation or oxidation of CO and H{sub 2}, thus attaining equilibrium levels of H{sub 2}, CO, H{sub 2}O, and CO{sub 2} at the exit of the catalyst bed. Experimental Bio-oil (mixed with varied amounts of methanol to reduce the viscosity and homogenize the bio-oil) or selected bio-oil components are introduced at a measured flow rate through the top of a vertical quartz reactor which is heated using a five zone furnace. The ultrasonic nozzle used to feed the reactants allows the bio-oil to flow down the center of the reactor at a low, steady flow rate. Additionally, the fine mist created by the nozzle allows for intimate mixing with oxygen and efficient heat transfer, providing optimal conditions to achieve high conversion at relatively low temperatures in the non-catalytic step thus reducing the required catalyst loading. Generation of the fine mist is especially important for providing good contact between non-volatile bio-oil components and oxygen. Oxygen and helium are also delivered at the top of the reactor via mass flow meters with the amount of oxygen being varied to maximize the yields of H{sub 2} and CO and the amount of helium being adjusted such that the gas phase residence time in the hot zone is {approx}0.3 and {approx}0.45 s for bio-oil and methanol experiments, respectively. A catalyst bed can be located at the bottom of the reactor tube. To date, catalyst screening experiments have used Engelhard noble metal catalysts. The catalysts used for these experiments were 0.5 % rhodium, ruthenium, platinum, and palladium (all supported on alumina). Experiments were performed using pure alumina as well. Both the catalyst type and the effect of oxygen and steam on the residual hydrocarbons and accumulated carbon containing particulates were investigated. The residence time before the catalyst is varied to determine the importance of the non-catalytic step and its potential effect on the required catalyst loading. Non-catalytic experiments (primarily homogeneous cracking) use a bed of quartz p

Marda, J. R.; Dean, A. M.; Czernik, S.; Evans, R. J.; French, R.; Ratcliff, M.

2008-01-01T23:59:59.000Z

446

Technology Strategies  

Science Conference Proceedings (OSTI)

From the Book:PrefaceTechnology as the Strategic AdvantageWhen I began writing this book I struggled with the direction I wanted it to take. Is this book to be about business, technology, or even the business of technology? I ...

Cooper Smith

2001-07-01T23:59:59.000Z

447

An Act to Reform Land Use Planning in the Unorganized Territory (Maine) |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

An Act to Reform Land Use Planning in the Unorganized Territory An Act to Reform Land Use Planning in the Unorganized Territory (Maine) An Act to Reform Land Use Planning in the Unorganized Territory (Maine) < Back Eligibility Agricultural Commercial Investor-Owned Utility Local Government Municipal/Public Utility Nonprofit Rural Electric Cooperative Schools Tribal Government Utility Savings Category Wind Buying & Making Electricity Program Info State Maine Program Type Siting and Permitting Provider Conservation An Act to Reform Land Use Planning in the Unorganized Territory alters the makeup and responsibilities of Maine's Land Use Regulation Commission (LURC). It took effect on August 29, 2012 and changed the Commission's name to the Land Use Planning Commission. Under the Act, permitting review for significant projects, such as

448

Incentives in Water Management Reform: Assessing the Effect on Water Use,  

NLE Websites -- All DOE Office Websites (Extended Search)

Incentives in Water Management Reform: Assessing the Effect on Water Use, Incentives in Water Management Reform: Assessing the Effect on Water Use, Production and Poverty in the Yellow River Basin Speaker(s): Jinixia Wang Date: May 22, 2003 - 12:00pm Location: Bldg. 90 The purpose of this presentation is to better understand water management reform in China's rural communities, focusing on the effect of incentives to water managers on the nation's water resources and the welfare of the rural population. Based on a survey study in the Yellow River Basin, our findings show that Water User Associations and contracting have begun to systematically replace traditional forms of collective management. The analysis demonstrates, however, that it is not a nominal implementation of the reform that matters, but rather it is a creation of new management

449

The risk of reform : privatisation and liberalisation in the Brazilian electric power industry  

E-Print Network (OSTI)

In 1996, when Brazil was well-underway to privatising and liberalising its electric power industry, few would have predicted that within five years the reforms would be a shambles. Like its neighbors Argentina and Chile, ...

Tankha, Sunil, Ph. D. Massachusetts Institute of Technology

2006-01-01T23:59:59.000Z

450

Electricity Sector Reform in Developing Countries: A Survey of Empirical Evidence on Determinants and Performance  

E-Print Network (OSTI)

, patronage, labour opposition to reducing waste, poor collection and other fiscal leakage. Simpler reforms, such as encouraging Independent Power Producers to enter into long-term Power Purchase Agreements with financially fragile counterparts, stored up...

Jamasb, Tooraj; Mota, Raffaella L; Newbery, David; Pollitt, Michael G.

2004-07-09T23:59:59.000Z

451

Synthesis and characterization of 1D ceria nanomaterials for CO oxidation and steam reforming of methanol  

Science Conference Proceedings (OSTI)

Novel one-dimensional (1D) ceria nanostructure has been investigated as a promising and practical approach for the reforming of methanol reaction. Size and shape of the ceria nanomaterials are directly involved with the catalytic activities. Several ...

Sujan Chowdhury; Kuen-Song Lin

2011-01-01T23:59:59.000Z

452

Numerical simulation of micro/mini-channel based methane-steam reformer.  

E-Print Network (OSTI)

??Numerical modeling of methane-steam reforming is performed in a micro/mini-channel with heat input through catalytic channel walls. The low-Mach number, variable density Navier-Stokes equations together… (more)

[No author

2010-01-01T23:59:59.000Z

453

Computational heterogeneous catalysis applied to steam methane reforming over nickel and nickel/silver catalysts  

E-Print Network (OSTI)

The steam methane reforming (SMR) reaction is the primary industrial means for producing hydrogen gas. As such, it is a critical support process for applications including petrochemical processing and ammonia synthesis. ...

Blaylock, Donnie Wayne

2011-01-01T23:59:59.000Z

454

"Quality" control in China's reform era : investigating the suzhi discourse in women's work  

E-Print Network (OSTI)

China's reform era has coincided with an emergence of a Chinese Communist Party-State ideological discourse concerning "population quality." Claims and accusations of 'low quality' are particularly targeted at rural migrant ...

Yip, Cheryl

2008-01-01T23:59:59.000Z

455

Deregulating and regulatory reform in the U.S. electric power sector  

E-Print Network (OSTI)

This paper discusses the evolution of wholesale and retail competition in the U.S electricity sector and associated industry restructuring and regulatory reforms. It begins with a discussion of the industry structure and ...

Joskow, Paul L.

2000-01-01T23:59:59.000Z

456

Organizational sense making : responsibilities to the MCAS reform in the Massachusetts public schools  

E-Print Network (OSTI)

Educational reform has become a central concern of public policy debates at both the state and federal level. The policy trend both nationally and locally is towards uniform standards in education, with testing as the ...

Goldman, Janice J., 1953-

2005-01-01T23:59:59.000Z

457

Jews and Catholics in Catholic Poland: A Beleaguered Church in the Post Reformation Era.  

E-Print Network (OSTI)

??Jews and Heretics in Catholic Poland takes issue with historians’ common contention that the Catholic Church triumphed in Counter-reformation Poland. In fact, the Church’s own… (more)

Teter, Magda

2006-01-01T23:59:59.000Z

458

Fuel cell generator with fuel electrodes that control on-cell fuel reformation  

Science Conference Proceedings (OSTI)

A fuel cell for a fuel cell generator including a housing including a gas flow path for receiving a fuel from a fuel source and directing the fuel across the fuel cell. The fuel cell includes an elongate member including opposing first and second ends and defining an interior cathode portion and an exterior anode portion. The interior cathode portion includes an electrode in contact with an oxidant flow path. The exterior anode portion includes an electrode in contact with the fuel in the gas flow path. The anode portion includes a catalyst material for effecting fuel reformation along the fuel cell between the opposing ends. A fuel reformation control layer is applied over the catalyst material for reducing a rate of fuel reformation on the fuel cell. The control layer effects a variable reformation rate along the length of the fuel cell.

Ruka, Roswell J. (Pittsburgh, PA); Basel, Richard A. (Pittsburgh, PA); Zhang, Gong (Murrysville, PA)

2011-10-25T23:59:59.000Z

459

The wholesale market for electricity in England and Wales : recent developments and future reforms  

E-Print Network (OSTI)

The England and Wales wholesale electricity market is about to undergo major reform (NETA). I describe and analyse the proposed arrangements, contrasting them with those currently in operation. I argue that while NETA will ...

Sweeting, Andrew

2000-01-01T23:59:59.000Z

460

Admonition and the academy : installation, video, and performance art in Reform Era China  

E-Print Network (OSTI)

China's Reform Era (1978-present) has seen the reinvigoration of academic, and artistic practice, and a rapprochement between the Chinese Communist Party and the intellectual elite. At its beginnings in the early- to ...

Oen, Karin Grace

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "reforming fbsr technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Exposing the seams : the impetus for reforming U.S. counterintelligence .  

E-Print Network (OSTI)

??U.S. counterintelligence is in need of reform. The September 11, 2001 attacks by Al-Qa'ida against America highlight this fact but are not in themselves the… (more)

Gleghorn, Todd E.

2003-01-01T23:59:59.000Z

462

Development of Ni-based Sulfur Resistant Catalyst for Diesel Reforming  

DOE Green Energy (OSTI)

In order for diesel fuel to be used in a solid oxide fuel cell auxiliary power unit, the diesel fuel must be reformed into hydrogen, carbon monoxide and carbon dioxide. One of the major problems facing catalytic re