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Sample records for refining silver eagle

  1. EAGLE

    Energy Science and Technology Software Center (OSTI)

    003500WKSTN00 EAGLE: 'EAGLE'Is an' Algorithmic Graph Library for Exploration https://github.com/ssrangan

  2. Golden Eagle Territories and Ecology at Site 300

    SciTech Connect (OSTI)

    Fratanduono, M.

    2015-09-29

    Garcia and Associates (GANDA) was contracted by the Lawrence Livermore National Laboratory (LLNL) to collect information on golden eagle (Aquila chrysaetos) use of Site 300. During 2014, we conducted surveys at Site 300 and for an area including a 10-mile radius of Site 300. Those surveys documented 42 golden eagle territories including two territories that overlapped with Site 300. These were named ‘Tesla’ and ‘Linac Road’. In 2015, we conducted surveys to refine the territory boundaries of golden eagle territories that overlapped with Site 300 and to document eagle activity at Site 300.

  3. Eagle County, Colorado Data Dashboard

    Broader source: Energy.gov [DOE]

    The data dashboard for Eagle County, Colorado, a partner in the Better Buildings Neighborhood Program.

  4. Reclaiming silver from silver zeolite

    SciTech Connect (OSTI)

    Reimann, G.A.

    1991-10-01

    Silver zeolite is used to capture radioiodines from air cleaning systems in some nuclear facilities at the Idaho National Engineering Laboratory. It may become radioactively contaminated and/or poisoned by hydrocarbon vapors, which diminishes its capacity for iodine. Silver zeolite contains up to 38 wt% silver. A pyrometallurgical process was developed to reclaim the silver before disposing of the unserviceable zeolite as a radioactive waste. A flux was formulated to convert the refractory aluminosilicate zeolite structure into a low-melting fluid slag, with Na[sub 2]O added as NAOH instead of Na[sub 2]CO[sub 3] to avoid severe foaming due to CO[sub 2] evolution. A propane-fired furnace was built to smelt 45 kg charges at 1300C in a carbon-bonded silicon carbide crucible. A total of 218 kg (7000 tr oz) of silver was reclaimed from 1050 kg of unserviceable zeolite. Silver recoveries of 97% were achieved, and the radioisotopes were fixed as stable silicates in a vitreous slag that was disposed of as a low level waste. Recovered silver was refined using oxygen and cast into 100 tr oz bars assaying 99.8+% silver and showing no radioactive contamination.

  5. Reclaiming silver from silver zeolite

    SciTech Connect (OSTI)

    Reimann, G.A.

    1991-10-01

    Silver zeolite is used to capture radioiodines from air cleaning systems in some nuclear facilities at the Idaho National Engineering Laboratory. It may become radioactively contaminated and/or poisoned by hydrocarbon vapors, which diminishes its capacity for iodine. Silver zeolite contains up to 38 wt% silver. A pyrometallurgical process was developed to reclaim the silver before disposing of the unserviceable zeolite as a radioactive waste. A flux was formulated to convert the refractory aluminosilicate zeolite structure into a low-melting fluid slag, with Na{sub 2}O added as NAOH instead of Na{sub 2}CO{sub 3} to avoid severe foaming due to CO{sub 2} evolution. A propane-fired furnace was built to smelt 45 kg charges at 1300C in a carbon-bonded silicon carbide crucible. A total of 218 kg (7000 tr oz) of silver was reclaimed from 1050 kg of unserviceable zeolite. Silver recoveries of 97% were achieved, and the radioisotopes were fixed as stable silicates in a vitreous slag that was disposed of as a low level waste. Recovered silver was refined using oxygen and cast into 100 tr oz bars assaying 99.8+% silver and showing no radioactive contamination.

  6. Eagle County, Colorado Data Dashboard | Department of Energy

    Energy Savers [EERE]

    Data Dashboard Eagle County, Colorado Data Dashboard The data dashboard for Eagle County, Colorado, a partner in the Better Buildings Neighborhood Program. Eagle County Data ...

  7. EAGLE: 'EAGLE'Is an' Algorithmic Graph Library for Exploration

    SciTech Connect (OSTI)

    2015-01-16

    The Resource Description Framework (RDF) and SPARQL Protocol and RDF Query Language (SPARQL) were introduced about a decade ago to enable flexible schema-free data interchange on the Semantic Web. Today data scientists use the framework as a scalable graph representation for integrating, querying, exploring and analyzing data sets hosted at different sources. With increasing adoption, the need for graph mining capabilities for the Semantic Web has emerged. Today there is no tools to conduct "graph mining" on RDF standard data sets. We address that need through implementation of popular iterative Graph Mining algorithms (Triangle count, Connected component analysis, degree distribution, diversity degree, PageRank, etc.). We implement these algorithms as SPARQL queries, wrapped within Python scripts and call our software tool as EAGLE. In RDF style, EAGLE stands for "EAGLE 'Is an' algorithmic graph library for exploration. EAGLE is like 'MATLAB' for 'Linked Data.'

  8. EAGLE: 'EAGLE'Is an' Algorithmic Graph Library for Exploration

    Energy Science and Technology Software Center (OSTI)

    2015-01-16

    The Resource Description Framework (RDF) and SPARQL Protocol and RDF Query Language (SPARQL) were introduced about a decade ago to enable flexible schema-free data interchange on the Semantic Web. Today data scientists use the framework as a scalable graph representation for integrating, querying, exploring and analyzing data sets hosted at different sources. With increasing adoption, the need for graph mining capabilities for the Semantic Web has emerged. Today there is no tools to conduct "graphmore » mining" on RDF standard data sets. We address that need through implementation of popular iterative Graph Mining algorithms (Triangle count, Connected component analysis, degree distribution, diversity degree, PageRank, etc.). We implement these algorithms as SPARQL queries, wrapped within Python scripts and call our software tool as EAGLE. In RDF style, EAGLE stands for "EAGLE 'Is an' algorithmic graph library for exploration. EAGLE is like 'MATLAB' for 'Linked Data.'« less

  9. Eagle, Idaho: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Idaho's 1st congressional district.12 Registered Energy Companies in Eagle, Idaho Hyperion Energy References US Census Bureau Incorporated place and minor civil division...

  10. Eagle Conservation Plan Guidance | Open Energy Information

    Open Energy Info (EERE)

    the Eagle Conservation Plan (ECP) process and requirements. Calls for: 1) Preliminary landscape-level assessments to assess potential wildlife interactions; 2) Site-specific...

  11. Suzhou Eagle Electric Vehicle Manufacturing Co Ltd | Open Energy...

    Open Energy Info (EERE)

    Suzhou Eagle Electric Vehicle Manufacturing Co Ltd Jump to: navigation, search Name: Suzhou Eagle Electric Vehicle Manufacturing Co Ltd Place: Suzhou, China Sector: Vehicles...

  12. National Bald Eagle Management Guidelines | Open Energy Information

    Open Energy Info (EERE)

    National Bald Eagle Management Guidelines Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: National Bald Eagle Management...

  13. Rietveld Refinement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    profile Chi-squared value 4.944 Progress so far Inverse Modeling Method 2 Fourier Method Data Model Refined Structure 40 60 80 100 120 140 160 0 1000 2000 3000 4000...

  14. EIS-0471: Areva Eagle Rock Enrichment Facility in Bonneville...

    Office of Environmental Management (EM)

    1: Areva Eagle Rock Enrichment Facility in Bonneville County, ID EIS-0471: Areva Eagle Rock Enrichment Facility in Bonneville County, ID May 20, 2011 delete me old download page ...

  15. NREL: Wind Research - Eagles are Making Wind Turbines Safer for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A bald eagle named Spirit and a golden eagle named Nova recently helped a team of researchers at the National Wind Technology Center (NWTC) collect terabytes of data for a project ...

  16. Eagle County, Colorado Summary of Reported Data | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Summary of Reported Data Eagle County, Colorado Summary of Reported Data Summary of data reported by Better Buildings Neighborhood Program partner Eagle County, Colorado. Eagle County, Colorado Summary of Reported Data (2.15 MB) More Documents & Publications Virginia -- SEP Summary of Reported Data Los Angeles Summary of Reported Data St. Lucie County Summary of Reported Data

  17. Jonathan Silver

    Broader source: Energy.gov [DOE]

    Jonathan Silver was named Executive Director of the U.S. Department of Energy’s Loan Programs Office in November 2009. Mr. Silver leads the Obama Administration’s $70 billion dollar investment...

  18. Refiner Crude Oil Inputs

    U.S. Energy Information Administration (EIA) Indexed Site

    Net Inputs (Refiner and Blender) of RBOB Blending Components Net Inputs (Refiner and Blender) of CBOB Blending Components Net Inputs (Refiner and Blender) of GTAB Blending ...

  19. Take of Eagles Permit 3-200-16 | Open Energy Information

    Open Energy Info (EERE)

    Reference LibraryAdd to library Form: Take of Eagles Permit 3-200-16 Abstract Federal Fish and Wildlife Permit Application Form for Take of Depredating Eagles and Eagles that...

  20. Eagles are Making Wind Turbines Safer for Birds | Community | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Eagles are Making Wind Turbines Safer for Birds March 17, 2016 A bald eagle named Spirit and a golden eagle named Nova recently helped a team of researchers at the National Wind Technology Center (NWTC) collect terabytes of data for a project aimed at helping researchers make wind energy safer for birds. The National Renewable Energy Laboratory partnered with industry to gather data about bird flight patterns, which will help the companies develop technology to reduce bird collisions with

  1. FOA Announcement: Eagle Impact Minimization Technology Development and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Field Testing Opportunities | Department of Energy FOA Announcement: Eagle Impact Minimization Technology Development and Field Testing Opportunities FOA Announcement: Eagle Impact Minimization Technology Development and Field Testing Opportunities June 22, 2016 - 4:08pm Addthis The Energy Department's Wind Program issued a Funding Opportunity Announcement (FOA) to advance the readiness of technologies intended to reduce eagle mortalities at operational wind turbines or wind facilities. This

  2. Notice of Intent: Eagle Impact Minimization Technology Development...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to issue a Funding Opportunity Announcement (FOA) to advance the readiness of technologies intended to reduce eagle mortalities at operational wind turbines or wind facilities. ...

  3. Smart Phone Technologies Reduce Risks to Eagles from Wind Turbines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Eagles are Making Wind Turbines Safer for Birds PNNL Reviews Wildlife-Interaction Monitoring for Offshore Wind Farms - Technology Hybrids Show Best Potential Mitigating Wind-Radar ...

  4. Eagle Mountain, Utah: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Eagle Mountain, Utah: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 40.3141169, -112.006882 Show Map Loading map... "minzoom":false,"mappings...

  5. Eagle County, Colorado Summary of Reported Data | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon Eagle County, Colorado Summary of Reported Data More Documents & Publications Virginia -- SEP Summary of Reported Data Los Angeles Summary of Reported Data St. Lucie ...

  6. Webinar: Eagle Impact Minimization Technology Development and Field Testing Opportunities

    Broader source: Energy.gov [DOE]

    Today, the Energy Department's Wind Program issued a Funding Opportunity Announcement (FOA) to advance the readiness of technologies intended to reduce eagle mortalities at operational wind...

  7. Application for Nonpurposeful Eagle Take Permit | Open Energy...

    Open Energy Info (EERE)

    Eagle Take Permit Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- Permit ApplicationPermit Application: Application for Nonpurposeful...

  8. Eagle County- Energy Smart Colorado Energy Efficiency Rebate Program

    Broader source: Energy.gov [DOE]

    Residents of Roaring Fork Valley and Eagle, Gunnison, Lake, and Summit Counties are eligible for energy efficiency and renewable energy assistance, rebates, and financing through the Energy Smart...

  9. Eagle County- Energy Smart Colorado Renewable Energy Rebate Program

    Broader source: Energy.gov [DOE]

    Residents of Roaring Fork Valley and Eagle, Gunnison, Lake, and Summit Counties are eligible for energy efficiency and renewable energy assistance, rebates, and financing through the Energy Smart...

  10. Solasta aka The Eagle Axis | Open Energy Information

    Open Energy Info (EERE)

    Zip: 2458 Sector: Efficiency, Solar Product: Start-up planning to produce high-efficiency solar cells using nanoscale elements. References: Solasta (aka The Eagle Axis)1 This...

  11. Alternative Fuels Data Center: Golden Eagle Distributors Inc...

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    ... Golden Eagle was also recognized for its recycling and energy-efficiency initiatives, employee carpooling, and its green transportation program. Project at a Glance Fleet Type: ...

  12. Scaled Eagle Nebula Experiments on NIF (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Scaled Eagle Nebula Experiments on NIF Citation Details In-Document Search Title: Scaled Eagle Nebula Experiments on NIF You are accessing a document from the Department of ...

  13. EAGLE project for IGFC in Japan

    SciTech Connect (OSTI)

    Kiso, Fumihiko; Akiyama, Tooru; Morihara, Atsushi; Takahashi, Kouji; Kida, Eiji; Iritani, Junichi; Tsujiguchi, Satoshi

    2000-07-01

    An Integrated Coal Gasification Fuel Cell power plant (IGFC) is one of the most attractive power plants in the 21st century because of its high efficiency and low impact on the environment. Under financial support of NEDO, the project for IGFC named ``Coal Energy Application for Gas, Liquid and Electricity (EAGLE)'' is in progress. This paper shows the current status of the project. EAGLE project aims to establish coal gasification technology for fuel cells, with special emphasis, to develop an coal gasifier and a gas clean up system which reduces trace elements within the tolerant level for fuel cells. Electric Power Development Co., Ltd. (EPDC) and Hitachi Ltd. have researched and designed the plant. Plant Capacity of the plant is 150 tons per day of coal. Oxidization agent is pure oxygen produced by an air separation unit. Two-stage entrained flow type gasifier has been selected for EAGLE. Both cyclone and filter is used for dust removal. Syngas contains not only H{sub 2}S but also COS as sulfur compounds. H{sub 2}S is removed by the wet gas clean-up system using methyl di-ethanol amine (MDEA). However COS cannot be absorbed by MDEA. To improve the desulfurization ratio, Carbonyl Sulfide (COS) hydrolysis unit is used for conversion of COS to H{sub 2}S. Construction of the plant started in 1998. The gasifier and the heat recovery boiler have been already manufactured and constructed at the plant site Wakamatsu in Fukuoka prefecture. Testing of the plant operation will start in 2001 and continue until 2004.

  14. Eagle Point, Oregon: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    This article is a stub. You can help OpenEI by expanding it. Eagle Point is a city in Jackson County, Oregon. It falls under Oregon's 2nd congressional district.12 References...

  15. Erigo and EaglePicher | Energy Systems Integration | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Erigo and EaglePicher NREL researchers are testing an energy storage system for a microgrid-developed by Erigo and EaglePicher and sponsored by U.S. Northern Command-that contains three independently controllable energy storage technologies. Photo of energy storage system hardware in a laboratory Photo by Dennis Schroeder Microgrids-and effective storage systems supporting them-are especially important for remote military bases where accessing energy can be costly and dangerous. This research is

  16. ITP Petroleum Refining: Profile of the Petroleum Refining Industry...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Profile of the Petroleum Refining Industry in California: California Industries of the Future Program ITP Petroleum Refining: Profile of the Petroleum Refining Industry in ...

  17. ITP Petroleum Refining: Energy Bandwidth for Petroleum Refining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bandwidth for Petroleum Refining Processes ITP Petroleum Refining: Energy Bandwidth for Petroleum Refining Processes bandwidth.pdf (1.16 MB) More Documents & Publications ITP ...

  18. Progress in 2012-2013 on HEDLP LAB 11-583 Eagle Nebula (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Progress in 2012-2013 on HEDLP LAB 11-583 Eagle Nebula Citation Details In-Document Search Title: Progress in 2012-2013 on HEDLP LAB 11-583 Eagle Nebula Authors: ...

  19. EIS-0471: Areva Eagle Rock Enrichment Facility in Bonneville County, ID |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 1: Areva Eagle Rock Enrichment Facility in Bonneville County, ID EIS-0471: Areva Eagle Rock Enrichment Facility in Bonneville County, ID May 20, 2011 delete me old download page duplicate

  20. Eagle LNG Partners Jacksonville LLC- Dkt. No. 16-15-LNG

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy (FE) of the Department of Energy (DOE) gives notice of receipt of an application (Application), filed on January 27, 2016, by Eagle LNG Partners Jacksonville LLC (Eagle...

  1. Step 3: Project Refinement

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3: Project Refinement 2 1 Potential 3 Refinement 4 Implementation 5 Operations & Maintenance 2 Options 3 Refinement 1/28/2016 2 3 FUNDING AND FINANCING OPTIONS Project Ownership Financing structure is highly dependent on size of the project and the capital available for a given project: * Tribe owns the project (cash purchase or debt) * Tribe hosts the project and buys the electricity (power purchase agreement) * Tribe partners with private sector and co-owns the project (uncertainties about

  2. Refiners trade hydroprocessing experience

    SciTech Connect (OSTI)

    Not Available

    1984-04-16

    Hydrogen treating and conversion processes less severe than hydrocracking abound in most refineries and therefore were a subject of high interest at the National Petroleum Refiners Association question and answer session on refining technology. The present paper, which is the second abstract of the transcript of the most recent meeting, covers hydroprocessing and some of its mechanical, process, and catalytic aspects.

  3. EA-1905: Double Eagle Water System, Carlsbad, New Mexico

    Broader source: Energy.gov [DOE]

    This EA, prepared by the U.S. Department of the Interior’s Bureau of Land Management Carlsbad Field Office and adopted by DOE, evaluates the expansion and upgrade of the City of Carlsbad’s Double Eagle Water System.

  4. NAFTA opportunities: Petroleum refining

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The North American Free Trade Agreement (NAFTA) creates a more transparent environment for the sale of refined petroleum products to Mexico, and locks in access to Canada's relatively open market for these products. Canada and Mexico are sizable United States export markets for refined petroleum products, with exports of $556 million and $864 million, respectively, in 1992. These markets represent approximately 24 percent of total U.S. exports of these goods.

  5. Eagles are Making Wind Turbines Safer for Birds | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Eagles are Making Wind Turbines Safer for Birds Eagles are Making Wind Turbines Safer for Birds March 16, 2016 - 10:38am Addthis Video by Simon Edelman, Energy Department. | Footage courtesy of the National Renewable Energy Laboratory and RES Americas. Kelly Yaker National Renewable Energy Laboratory How does it work? Researchers at NREL teamed with industry to study the flight patterns of two eagles. The data will help the companies develop systems to detect birds and prevent collisions with

  6. Eagle, Gunnison, Lake, and Pitkin Counties- Energy Smart Colorado Loan Program

    Broader source: Energy.gov [DOE]

    Residents of Roaring Fork Valley and Eagle, Gunnison, Lake, and Summit Counties are eligible for energy efficiency and renewable energy assistance, rebates, and financing through the Energy Smart...

  7. Notice of Intent: Eagle Impact Minimization Technology Development and Field Testing Opportunities

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Energy Department's Wind Program intends to issue a Funding Opportunity Announcement (FOA) to advance the readiness of technologies intended to reduce eagle mortalities at operational wind...

  8. Eagle, Garfield, Gunnison, Lake, and Pitkin Counties- Energy Smart Colorado Loan Program

    Broader source: Energy.gov [DOE]

    Residents of Roaring Fork Valley and Eagle, Gunnison, Lake, and Summit Counties are eligible for energy efficiency and renewable energy assistance, rebates, and financing through the Energy Smart...

  9. Eagle LNG Partners Jacksonville LLC- Dkt. No. 16-15-LNG Exports to (FTA and NFTA) Countries

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Office of Fossil Energy (FE) of the Department of Energy (DOE) gives notice of receipt of an application (Application), filed on January 27, 2016, by Eagle LNG Partners Jacksonville LLC (Eagle...

  10. Minimally refined biomass fuel

    DOE Patents [OSTI]

    Pearson, Richard K.; Hirschfeld, Tomas B.

    1984-01-01

    A minimally refined fluid composition, suitable as a fuel mixture and derived from biomass material, is comprised of one or more water-soluble carbohydrates such as sucrose, one or more alcohols having less than four carbons, and water. The carbohydrate provides the fuel source; water solubilizes the carbohydrates; and the alcohol aids in the combustion of the carbohydrate and reduces the vicosity of the carbohydrate/water solution. Because less energy is required to obtain the carbohydrate from the raw biomass than alcohol, an overall energy savings is realized compared to fuels employing alcohol as the primary fuel.

  11. CLAMR (Compute Language Adaptive Mesh Refinement)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CLAMR (Compute Language Adaptive Mesh Refinement) CLAMR (Compute Language Adaptive Mesh Refinement) CLAMR (Compute Language Adaptive Mesh Refinement) is being developed as a DOE...

  12. Silver Award - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    About Us Hanford Site Wide Programs DOE Human Resources Management Recognition and Awards Program Silver Award About Us DOE Human Resources Management Division DOE Employment Recognition and Awards Program Gold Awards Silver Award Federal Employees Union (AFGE Local 788) Work Schedules / Pay and Leave Benefits and Services EEO & Diversity Silver Award Email Email Page | Print Print Page | Text Increase Font Size Decrease Font Size Recognition is provided through monetary, non-monetary, and

  13. Dosimetry using silver salts

    DOE Patents [OSTI]

    Warner, Benjamin P.

    2003-06-24

    The present invention provides a method for detecting ionizing radiation. Exposure of silver salt AgX to ionizing radiation results in the partial reduction of the salt to a mixture of silver salt and silver metal. The mixture is further reduced by a reducing agent, which causes the production of acid (HX) and the oxidized form of the reducing agent (R). Detection of HX indicates that the silver salt has been exposed to ionizing radiation. The oxidized form of the reducing agent (R) may also be detected. The invention also includes dosimeters employing the above method for detecting ionizing radiation.

  14. Refines Efficiency Improvement

    SciTech Connect (OSTI)

    WRI

    2002-05-15

    Refinery processes that convert heavy oils to lighter distillate fuels require heating for distillation, hydrogen addition or carbon rejection (coking). Efficiency is limited by the formation of insoluble carbon-rich coke deposits. Heat exchangers and other refinery units must be shut down for mechanical coke removal, resulting in a significant loss of output and revenue. When a residuum is heated above the temperature at which pyrolysis occurs (340 C, 650 F), there is typically an induction period before coke formation begins (Magaril and Aksenova 1968, Wiehe 1993). To avoid fouling, refiners often stop heating a residuum before coke formation begins, using arbitrary criteria. In many cases, this heating is stopped sooner than need be, resulting in less than maximum product yield. Western Research Institute (WRI) has developed innovative Coking Index concepts (patent pending) which can be used for process control by refiners to heat residua to the threshold, but not beyond the point at which coke formation begins when petroleum residua materials are heated at pyrolysis temperatures (Schabron et al. 2001). The development of this universal predictor solves a long standing problem in petroleum refining. These Coking Indexes have great potential value in improving the efficiency of distillation processes. The Coking Indexes were found to apply to residua in a universal manner, and the theoretical basis for the indexes has been established (Schabron et al. 2001a, 2001b, 2001c). For the first time, a few simple measurements indicates how close undesired coke formation is on the coke formation induction time line. The Coking Indexes can lead to new process controls that can improve refinery distillation efficiency by several percentage points. Petroleum residua consist of an ordered continuum of solvated polar materials usually referred to as asphaltenes dispersed in a lower polarity solvent phase held together by intermediate polarity materials usually referred to as

  15. ITP Petroleum Refining: Energy Bandwidth for Petroleum Refining Processes

    Broader source: Energy.gov [DOE]

    This energy bandwidth analysis provides a realistic estimate of the energy that may be saved in petroleum refining processes by quantifying measures of energy consumption.

  16. WINDExchange Webinar: Wind Energy and Eagles: The Problem, the Permit, and the Path Forward

    Broader source: Energy.gov [DOE]

    Save the date for this free webinar. Wally Erickson of WEST, Inc. will present on the conservation and permitting challenges associated with wind and eagles; Annie Mudge of Cox, Castle &...

  17. Petroleum Refining | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Energy Efficiency Roadmap for Petroleum Refineries in California (2004) ... Photo credit: iStockphoto.com15906809 Petroleum Refining The United States is the largest, most ...

  18. Method for the recovery of silver from silver zeolite

    DOE Patents [OSTI]

    Reimann, George A.

    1986-01-01

    High purity silver is recovered from silver exchanged zeolite used to capture radioactive iodine from nuclear reactor and nuclear fuel reprocessing environments. The silver exchanged zeolite is heated with slag formers to melt and fluidize the zeolite and release the silver, the radioactivity removing with the slag. The silver containing metallic impurities is remelted and treated with oxygen and a flux to remove the metal impurities. About 98% of the silver in the silver exchanged zeolite having a purity of 99% or better is recoverable by the method.

  19. Method for the recovery of silver from silver zeolite

    DOE Patents [OSTI]

    Reimann, G.A.

    1985-03-05

    High purity silver is recovered from silver exchanged zeolite used to capture radioactive iodine from nuclear reactor and nuclear fuel reprocessing environments. The silver exchanged zeolite is heated with slag formers to melt and fluidize the zeolite and release the silver, the radioactivity removing with the slag. The silver containing metallic impurities is remelted and treated with oxygen and a flux to remove the metal impurities. About 98% of the silver in the silver exchanged zeolite having a purity of 99% or better is recoverable by the method.

  20. Midcourse Refinements of Financing Strategies

    Broader source: Energy.gov [DOE]

    Better Buildings Neighborhood Program Financing Peer Exchange Call: Midcourse Refinements of Financing Strategies, Call Slides and Discussion Summary, March 29, 2012. During this webinar participants discussed how programs have adapted and refined their financing strategies based on initial implementation experience and learning.

  1. Jonathan Silver | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Silver About Us Jonathan Silver - Executive Director of the Loan Programs Office Photo of Jonathan Silver Jonathan Silver was named Executive Director of the U.S. Department of Energy's Loan Programs Office in November 2009. Mr. Silver leads the Obama Administration's $70 billion dollar investment program in alternative energy, financing a wide range of solar, wind, geothermal, biofuels, fossil and nuclear energy projects. He also heads the government's $20 billion investment program in advanced

  2. Crystal structure refinement with SHELXL

    SciTech Connect (OSTI)

    Sheldrick, George M., E-mail: gsheldr@shelx.uni-ac.gwdg.de [Department of Structural Chemistry, Georg-August Universitt Gttingen, Tammannstrae 4, Gttingen 37077 (Germany)

    2015-01-01

    New features added to the refinement program SHELXL since 2008 are described and explained. The improvements in the crystal structure refinement program SHELXL have been closely coupled with the development and increasing importance of the CIF (Crystallographic Information Framework) format for validating and archiving crystal structures. An important simplification is that now only one file in CIF format (for convenience, referred to simply as a CIF) containing embedded reflection data and SHELXL instructions is needed for a complete structure archive; the program SHREDCIF can be used to extract the .hkl and .ins files required for further refinement with SHELXL. Recent developments in SHELXL facilitate refinement against neutron diffraction data, the treatment of H atoms, the determination of absolute structure, the input of partial structure factors and the refinement of twinned and disordered structures. SHELXL is available free to academics for the Windows, Linux and Mac OS X operating systems, and is particularly suitable for multiple-core processors.

  3. Electronic structure of superconductivity refined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electronic structure of superconductivity refined Electronic structure of superconductivity refined A team of physicists propose a new model that expands on a little understood aspect of the electronic structure in high-temperature superconductors. July 10, 2008 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma

  4. MECS 2006 - Petroleum Refining | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Manufacturing Energy and Carbon Footprint Petroleum Refining (123.98 KB) More Documents & Publications Petroleum Refining (2010 MECS) MECS 2006 - Alumina and Aluminum MECS 2006 - ...

  5. ,"U.S. Refiner Petroleum Product Prices"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...EMAEPPRLPTGNUSDPG","EMAEPPRHPTGNUSDPG" "Date","U.S. Total Gasoline Retail Sales by Refiners (Dollars per Gallon)","U.S. Aviation Gasoline Retail Sales by Refiners (Dollars ...

  6. Renewable Energy Financial Instruments Guidance Tool (REFINe...

    Open Energy Info (EERE)

    Guidance Tool (REFINe) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Renewable Energy Financial Instruments Guidance Tool (REFINe) Focus Area: Renewable Energy...

  7. ,"U.S. Refiner Petroleum Product Prices"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...AEPPRLPTGNUSDPG","EMAEPPRHPTGNUSDPG" "Date","U.S. Total Gasoline Retail Sales by Refiners (Dollars per Gallon)","U.S. Aviation Gasoline Retail Sales by Refiners (Dollars ...

  8. Bald and Golden Eagle Protection Act (16 USC §§ 668–668d) and Related Regulations (50 CFR Part 22)

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Bald and Golden Eagle Act (16 U.S.C. 668-668c) prohibits anyone from taking, possessing, or transporting a bald eagle (Haliaeetus leucocephalus) or golden eagle (Aquila chrysaetos), or the parts, nests, or eggs of such birds without prior authorization.

  9. GRAIN REFINEMENT OF URANIUM BILLETS

    DOE Patents [OSTI]

    Lewis, L.

    1964-02-25

    A method of refining the grain structure of massive uranium billets without resort to forging is described. The method consists in the steps of beta- quenching the billets, annealing the quenched billets in the upper alpha temperature range, and extrusion upset of the billets to an extent sufficient to increase the cross sectional area by at least 5 per cent. (AEC)

  10. Method for refining contaminated iridium

    DOE Patents [OSTI]

    Heshmatpour, B.; Heestand, R.L.

    1982-08-31

    Contaminated iridium is refined by alloying it with an alloying agent selected from the group consisting of manganese and an alloy of manganese and copper, and then dissolving the alloying agent from the formed alloy to provide a purified iridium powder.

  11. ITP Petroleum Refining: Energy Bandwidth for Petroleum Refining Processes

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bandwidth for Petroleum Refining Processes Prepared by Energetics Incorporated for the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Industrial Technologies Program October 2006 Foreword The Industrial Technologies Program (ITP) is a research and development (R&D) program within the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy (EERE). This program works in collaboration with U.S. industry to improve industrial energy efficiency and

  12. Reformulated Gasoline Market Affected Refiners Differently, 1995

    Reports and Publications (EIA)

    1996-01-01

    This article focuses on the costs of producing reformulated gasoline (RFG) as experienced by different types of refiners and on how these refiners fared this past summer, given the prices for RFG at the refinery gate.

  13. Silver Sage Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Sage Wind Farm Jump to: navigation, search Name Silver Sage Wind Farm Facility Silver Sage Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  14. Silver Star Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Star Wind Farm Jump to: navigation, search Name Silver Star Wind Farm Facility Silver Star Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner...

  15. Firing of pulverized solvent refined coal

    DOE Patents [OSTI]

    Derbidge, T. Craig; Mulholland, James A.; Foster, Edward P.

    1986-01-01

    An air-purged burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired without the coking thereof on the burner components. The air-purged burner is designed for the firing of pulverized solvent refined coal in a tangentially fired boiler.

  16. Corrosion protection for silver reflectors

    DOE Patents [OSTI]

    Arendt, Paul N.; Scott, Marion L.

    1991-12-31

    A method of protecting silver reflectors from damage caused by contact with gaseous substances which are often present in the atmosphere and a silver reflector which is so protected. The inventive method comprises at least partially coating a reflector with a metal oxide such as aluminum oxide to a thickness of 15 .ANG. or less.

  17. ITP Petroleum Refining: Energy and Environmental Profile of the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Environmental Profile of the U.S. Petroleum Refining Industry (November 2007) ITP Petroleum Refining: Energy and Environmental Profile of the U.S. Petroleum Refining Industry ...

  18. Process for making silver metal filaments

    DOE Patents [OSTI]

    Bamberger, Carlos E.

    1997-01-01

    A process for making silver metal particles from silver salt particles having the same morphology. Precursor silver salt particles selected from the group consisting of silver acetate and silver sulfide having a selected morphology are contained in a reactor vessel having means for supporting the particles in an air suspension to prevent the agglomeration of the particles. Air is flowed through the reactor vessel at a flow rate sufficient to suspend the particles in the reactor vessel. The suspended precursor silver salt particles are heated to a processing temperature and at a heating rate below which the physical deterioration of the suspended precursor silver salt particles takes place. The suspended precursor silver salt particles are maintained at the processing temperature for a period of time sufficient to convert the particles into silver metal particles having the same morphology as the precursor silver salt particles.

  19. Improving the accuracy of macromolecular structure refinement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is challenging at low resolution. We compared refinement methods using synchrotron diffraction data of photosystem I at 7.4 resolution, starting from different initial models...

  20. Refiners Increasingly Employing Catalyst Regeneration as Alternative...

    Open Energy Info (EERE)

    million by the end of 2019. Refiners Benefit from Catalyst Regeneration Technology via Price Reductions and Lower Maintenance Costs The catalyst regeneration technology is the...

  1. Midcourse Refinements of Financing Strategies | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    March 29, 2012. During this webinar participants discussed how programs have adapted and refined their financing strategies based on initial implementation experience and learning. ...

  2. Right rock: Finding/refining customer expectations

    SciTech Connect (OSTI)

    Ashby, R.

    1997-11-01

    This report contains viewgraphs on methods of finding customer expectations of software and then refining the documentation and software to fit these expectations.

  3. Pneumatic conveying of pulverized solvent refined coal

    DOE Patents [OSTI]

    Lennon, Dennis R.

    1984-11-06

    A method for pneumatically conveying solvent refined coal to a burner under conditions of dilute phase pneumatic flow so as to prevent saltation of the solvent refined coal in the transport line by maintaining the transport fluid velocity above approximately 95 ft/sec.

  4. North Dakota Refining Capacity Study

    SciTech Connect (OSTI)

    Dennis Hill; Kurt Swenson; Carl Tuura; Jim Simon; Robert Vermette; Gilberto Marcha; Steve Kelly; David Wells; Ed Palmer; Kuo Yu; Tram Nguyen; Juliam Migliavacca

    2011-01-05

    According to a 2008 report issued by the United States Geological Survey, North Dakota and Montana have an estimated 3.0 to 4.3 billion barrels of undiscovered, technically recoverable oil in an area known as the Bakken Formation. With the size and remoteness of the discovery, the question became 'can a business case be made for increasing refining capacity in North Dakota?' And, if so what is the impact to existing players in the region. To answer the question, a study committee comprised of leaders in the region's petroleum industry were brought together to define the scope of the study, hire a consulting firm and oversee the study. The study committee met frequently to provide input on the findings and modify the course of the study, as needed. The study concluded that the Petroleum Area Defense District II (PADD II) has an oversupply of gasoline. With that in mind, a niche market, naphtha, was identified. Naphtha is used as a diluent used for pipelining the bitumen (heavy crude) from Canada to crude markets. The study predicted there will continue to be an increase in the demand for naphtha through 2030. The study estimated the optimal configuration for the refinery at 34,000 barrels per day (BPD) producing 15,000 BPD of naphtha and a 52 percent refinery charge for jet and diesel yield. The financial modeling assumed the sponsor of a refinery would invest its own capital to pay for construction costs. With this assumption, the internal rate of return is 9.2 percent which is not sufficient to attract traditional investment given the risk factor of the project. With that in mind, those interested in pursuing this niche market will need to identify incentives to improve the rate of return.

  5. Firing of pulverized solvent refined coal

    DOE Patents [OSTI]

    Lennon, Dennis R.; Snedden, Richard B.; Foster, Edward P.; Bellas, George T.

    1990-05-15

    A burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired successfully without any performance limitations and without the coking of the solvent refined coal on the burner components. The burner is provided with a tangential inlet of primary air and pulverized fuel, a vaned diffusion swirler for the mixture of primary air and fuel, a center water-cooled conical diffuser shielding the incoming fuel from the heat radiation from the flame and deflecting the primary air and fuel steam into the secondary air, and a watercooled annulus located between the primary air and secondary air flows.

  6. Monodispersed biocompatible silver sulfide nanoparticles: Facile...

    Office of Scientific and Technical Information (OSTI)

    ... Subject: 14 SOLAR ENERGY; AMBIENT TEMPERATURE; BACILLUS; BIOSYNTHESIS; FABRICATION; LIGHT SCATTERING; LUNGS; MACROPHAGES; PRODUCTION; SHAPE; SILVER SULFIDES; SOLAR CELLS; ...

  7. Silver State Geothermal Project | Open Energy Information

    Open Energy Info (EERE)

    State Geothermal Project Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Development Project: Silver State Geothermal Project Project Location Information Coordinates...

  8. Durable silver coating for mirrors

    DOE Patents [OSTI]

    Wolfe, Jesse D.; Thomas, Norman L.

    2000-01-01

    A durable multilayer mirror includes reflective layers of aluminum and silver and has high reflectance over a broad spectral range from ultraviolet to visible to infrared. An adhesion layer of a nickel and/or chromium alloy or nitride is deposited on an aluminum surface, and a thin layer of silver is then deposited on the adhesion layer. The silver layer is protected by a passivation layer of a nickel and/or chromium alloy or nitride and by one or more durability layers made of metal oxides and typically a first layer of metal nitride. The durability layers may include a composite silicon aluminum nitride and an oxinitride transition layer to improve bonding between nitride and oxide layers.

  9. U.S. Refining Capacity Utilization

    Reports and Publications (EIA)

    1995-01-01

    This article briefly reviews recent trends in domestic refining capacity utilization and examines in detail the differences in reported crude oil distillation capacities and utilization rates among different classes of refineries.

  10. Hydrogen Piping Experience in Chevron Refining

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Piping Experience in Chevron Refining Ned Niccolls Materials Engineer Chevron Energy Technology Company Hydrogen Pipeline Working Group Workshop August 30-31, 2005 Outline 2 Overall perspectives from long term use of hydrogen piping in refining. Piping specifications and practices. The (few) problem areas. Related industry work: American Petroleum Institute corrosion and materials work on high temperature hydrogen attack. Overall Perspectives 3 Few problems with hydrogen piping operating at

  11. EIS-0471: Department of Energy Loan Guarantee to Support Proposed Eagle Rock Enrichment Facility in Bonneville County, Idaho

    Broader source: Energy.gov [DOE]

    This EIS evaluates the environmental impacts of construction, operation, and decommissioning of the proposed Eagle Rock Enrichment Facility (EREF), a gas centrifuge uranium enrichment facility to be located in a rural area in western Bonneville County, Idaho. (DOE adopted this EIS issued by NRC on 04/13/2007.)

  12. Refining Bio-Oil alongside Petroleum | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Refining Bio-Oil alongside Petroleum Refining Bio-Oil alongside Petroleum April 9, 2013 - 12:00am Addthis W.R. Grace, a leading provider of refining technologies, and Pacific ...

  13. ,"U.S. Motor Gasoline Refiner Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","U.S. Motor Gasoline Refiner Sales ... AM" "Back to Contents","Data 1: U.S. Motor Gasoline Refiner Sales Volumes" ...

  14. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Motor Gasoline No. 2 Distillate Residual Fuel Oil 5. U.S. Refiner Wholesale Petroleum Product Volumes Figure Percentages of Refiner Wholesale Volumes 1995 Annual Averages Motor...

  15. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Day Motor Gasoline No. 2 Distillate Residual Fuel Oil 3. U.S. Refiner Retail Petroleum Product Volumes Figure Percentages of Refiner Retail Volumes 1997 Annual Averages Motor...

  16. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Motor Gasoline No. 2 Distillate Residual Fuel Oil 5. U.S. Refiner Wholesale Petroleum Product Volumes Figure Percentages of Refiner Wholesale Volumes 1997 Annual Averages Motor...

  17. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Day Motor Gasoline No. 2 Distillate Residual Fuel Oil 3. U.S. Refiner Retail Petroleum Product Volumes Figure Percentages of Refiner Retail Volumes 1995 Annual Averages Motor...

  18. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Day Motor Gasoline No. 2 Distillate Residual Fuel Oil 3. U.S. Refiner Retail Petroleum Product Volumes Figure Percentages of Refiner Retail Volumes 1996 Annual Averages Motor...

  19. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Motor Gasoline No. 2 Distillate Residual Fuel Oil 5. U.S. Refiner Wholesale Petroleum Product Volumes Figure Percentages of Refiner Wholesale Volumes 1996 Annual Averages Motor...

  20. ITP Petroleum Refining: Impacts of Condition Assessment on Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Impacts of Condition Assessment on Energy Use: Selected Applications in Chemicals Processing and Petroleum Refining ITP Petroleum Refining: Impacts of Condition Assessment on ...

  1. Historical impacts of environmental regulation of silver

    SciTech Connect (OSTI)

    Purcell, T.W.; Peters, J.J.

    1999-01-01

    Exposure to silver, and hence its possible environmental effects, has been regulated since the 1960s. Rules were first developed in the United States to protect against potential negative effects to humans due to ingestion of drinking water containing silver. As regulations for other environmental media were developed, silver was generally included because of its designation as a drinking water chemical of concern. Ambient water quality criteria were developed based on the toxic action of ionic silver. In the early 1990s the US Environmental Protection Agency`s Office of Drinking Water downgraded silver from a primary to a secondary maximum contaminant level because the effects of exposure to silver were judged to be cosmetic. Regulations pertaining to solid waste, surface waters, and occupational exposure have not been changed, but may be changed in the near future as the fate and toxic mechanisms of silver become better understood.

  2. Parallel tetrahedral mesh refinement with MOAB.

    SciTech Connect (OSTI)

    Thompson, David C.; Pebay, Philippe Pierre

    2008-12-01

    In this report, we present the novel functionality of parallel tetrahedral mesh refinement which we have implemented in MOAB. This report details work done to implement parallel, edge-based, tetrahedral refinement into MOAB. The theoretical basis for this work is contained in [PT04, PT05, TP06] while information on design, performance, and operation specific to MOAB are contained herein. As MOAB is intended mainly for use in pre-processing and simulation (as opposed to the post-processing bent of previous papers), the primary use case is different: rather than refining elements with non-linear basis functions, the goal is to increase the number of degrees of freedom in some region in order to more accurately represent the solution to some system of equations that cannot be solved analytically. Also, MOAB has a unique mesh representation which impacts the algorithm. This introduction contains a brief review of streaming edge-based tetrahedral refinement. The remainder of the report is broken into three sections: design and implementation, performance, and conclusions. Appendix A contains instructions for end users (simulation authors) on how to employ the refiner.

  3. Off-shelf portion of Harris delta: a reexamination of downdip Woodbine-Eagle Ford

    SciTech Connect (OSTI)

    Porter, M.

    1989-03-01

    This study relates the Eagle Ford-equivalent Harris delta north of the Stuart City shelf edge with the downdip Woodbine-Eagle Ford section south of that shelf edge. Together, they comprised one large deltaic complex that divided into two major lobes at an avulsion site near Anderson County. One lobe prograded southwestward toward Kurten field in Brazos County; the other (now partly eroded) prograded southeastward beside the low-lying Sabine (uplift) landmass into Polk County. The Polk County lobe crossed the Stuart City shelf edge in the Seven Oaks-Hortense field area and continued to prograde southward into deeper and higher energy water. Such an environment caused this off-shelf Harris delta to oversteepen, resulting in frequent slumps and gravity flows that deposited debris-flow and turbidite sands along with predominantly fine-grained prodelta sediments. More familiar deltaic facies (outer fringe) are present in the uppermost section. Numerous structural and stratigraphic maps and cross sections illustrate the progradation of the downdip Harris delta and its features. The progradation was arrested for a time by deeper water at the older and more precipitous Sligo shelf edge. This progradational hiatus is recorded by a relatively strong reflection that separates two seismic sequences. The younger, onlapping sequence appears to represent continued Harris delta sedimentation. Among the interesting features mapped seismically and/or geologically are mounded reflections that represent the largest slumping events, thickness anomalies associated with the carbonate substrate, and erosional( ) channels at the section top. These off-shelf Harris delta deposits appear to interfinger laterally with a genetically different eastern (Tuscaloosa ) sequence in Tyler and Jasper Counties.

  4. Off-shelf portion of Harris delta: Reexamination of downdip Woodbine-Eagle Ford

    SciTech Connect (OSTI)

    Porter, M.H. ); Van Siclen, D.C.; Sheriff, R.E. )

    1989-09-01

    This study related the Eagle Ford equivalent Harris delta north of the Stuart City shelf edge with downdip Woodbine-Eagle Ford section south of that shelf edge. Together, they comprised one large deltaic complex that divided into two major lobes at an avulsion site near Anderson County, Texas. One lobe prograded southwestward toward Kurten field in Brazos County, the other (now partly eroded) prograded southeastward beside the low-lying Sabine (uplift) landmass into Polk County. The Polk County lobe crossed the Stuart City shelf edge in the Seven Oaks-Hortense field area, and continued to prograde southward into deeper and higher energy water. Such an environment caused this off-shelf Harris delta to oversteepen, resulting in frequent slumps and gravity flows that deposited debris-flow and turbidite sands along with predominantly fine-grained prodelta sediments. More familiar deltaic facies (outer fringe) are present in the uppermost section. Numerous structural and stratigraphic maps and cross sections illustrate the progradation of the downdip Harris delta and its features. The progradation was arrested for a time by deeper water at the older and more precipitous Sligo shelf edge. This progradational hiatus is recorded by a relatively strong reflection that separates two seismic sequences. The younger onlapping sequence appears to represent continued Harris delta sedimentation. among the interesting features mapped seismically and/or geologically are: mounded reflections that represent the largest slumping events, thickness anomalies associated with the carbonate substrate, and erosional( ) channels at the section top. These off-shelf Harris delta deposits appear to interfinger laterally with a genetically different eastern (Tuscaloosa ) sequence in Tyler and Jasper Counties.

  5. Trends in petroleum refining process technology

    SciTech Connect (OSTI)

    Kowalczyk, D.

    1995-12-31

    In the 1990`s, the shift toward reformulated fuels and the unrelenting economic pressures on the petroleum refining industry have led to the ongoing development of a series of technological advances to improve fuels quality and industry operating efficiency. In this paper, ten of the most innovative and high impact recent developments in petroleum refining process technology will be highlighted. Process improvements and innovations have occurred in all facets of petroleum refining operations including fluid catalytic cracking, ether production, desulfurization, hydrocracking, gas processing, environmental control and heavy oil processing. Discussed will be the technical and economic impact of each of these new technologies on the petroleum refinery of the late 20th and early 21st century.

  6. JAPAN: Refining options and liberalization plans

    SciTech Connect (OSTI)

    Totto, L.; Isaak, D.T.

    1988-01-01

    The reformulation of Japan's petroleum import policy is important to Japan and to the international energy community. The technical and economic factors involved in opening the Japanese market is unknown. Assuming that foreign refiners have the technical capability to meet Japanese product specifications, the prices and volumes that will prove economical to both parties are also little known. Japanese refiners have been investigating the possibility of exporting gasoline and processing crude for China and Malaysia. The study demonstrates that under certain trade policies, Japan could become a significant product exporter. This study's purpose is to investigate the economic efficiency of alternative petroleum supply options, i.e., combining Japan's refining and product imports. An evaluation of the current import program and the technically feasible alternatives will play a major role in a new import policy. For this evaluation, a linear programming (LP) model of Japan's domestic refinery capacity and the petroleum import system was constructed. 3 figs., 23 tabs.

  7. Arbitrary Lagrangian Eulerian Adaptive Mesh Refinement

    Energy Science and Technology Software Center (OSTI)

    2009-09-29

    This is a simulation code involving an ALE (arbitrary Lagrangian-Eulerian) hydrocode with AMR (adaptive mesh refinement) and pluggable physics packages for material strength, heat conduction, radiation diffusion, and laser ray tracing developed a LLNL, UCSD, and Berkeley Lab. The code is an extension of the open source SAMRAI (Structured Adaptive Mesh Refinement Application Interface) code/library. The code can be used in laser facilities such as the National Ignition Facility. The code is alsi being appliedmore » to slurry flow (landslides).« less

  8. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2015-06-09

    A system and method for reactively refining hydrocarbons, such as heavy oils with API gravities of less than 20 degrees and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure, using a selected fluid at supercritical conditions. A reaction portion of the system and method delivers lightweight, volatile hydrocarbons to an associated contacting unit which operates in mixed subcritical/supercritical or supercritical modes. Using thermal diffusion, multiphase contact, or a momentum generating pressure gradient, the contacting unit separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques.

  9. The strategic outlook for petroleum refiners

    SciTech Connect (OSTI)

    Cobb, C.

    1994-12-31

    After several years of acceptable and relatively reliable profitability, refiners were plunged into uncertainty once again following passage of the Clean Air Act Amendments (CAAA) in 1990. While many of the original uncertainties that attended these regulations have since been resolved, the industry now must prepare for the new manufacturing, distributions, and transportation challenges that undoubtedly will accompany the first stages of reformulated gasoline (RFG) compliance in early 1995. This impending challenge introduces several fundamental questions: (1) How has the industry changed and adjusted to respond to anticipated future needs? (2) What strategies are refiners employing today? (3) What are industry performance expectations over the next several years?

  10. Silver Spring Networks comments on DOE NBP RFI: Data Access ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Data Access Silver Spring Networks comments on DOE NBP RFI: Data Access Silver Spring Networks comments on DOE NBP RFI: Data Access Silver Spring Networks comments on DOE NBP RFI: ...

  11. Energy Bandwidth for Petroleum Refining Processes

    SciTech Connect (OSTI)

    none,

    2006-10-01

    The petroleum refining energy bandwidth report analyzes the most energy-intensive unit operations used in U.S. refineries: crude oil distillation, fluid catalytic cracking, catalytic hydrotreating, catalytic reforming, and alkylation. The "bandwidth" provides a snapshot of the energy losses that can potentially be recovered through best practices and technology R&D.

  12. Focus on Venezuelan heavy crude: refining margins

    SciTech Connect (OSTI)

    Not Available

    1984-01-25

    Of six crudes refined in the US Gulf Coast, heavy Venezuelan crude Lagunillas (15/sup 0/ API) provides the best margin per barrel. Data for end of December 1983 and the first three weeks of January show that margins on all crudes are on the rise in this market, due to a turnaround in product prices. The lighter crudes are showing the greatest increase in Gross Product Worth. This is having a modest shrinking effect on the margin differential between light and heavy crudes in this market. The domestic crude West Texas Intermediate, at 40/sup 0/ API, provides the highest GPW in this crude slate sample, over US $31 per barrel, compared to GPW of under US $28 per barrel for Lagunillas. Still, as Lagunillas cost about US $8 less than does WTI, refiners with sufficient residue conversion capacity can be earning about US $3.50 more in margin per barrel than they can with WTI. Although few refiners would be using a 15/sup 0/ API crude exclusively for any length of time, heavier oil's inclusion in modern refiners' diets is enhancing their competitive position more than any other single factor. This issue of Energy Detente presents the fuel price/tax series and industrial fuel prices for January 1984 for countries of the Western Hemisphere.

  13. Silver Peak Innovative Exploration Project

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. Project objectives: Reduce the high level of risk during the early stages of geothermal project development by conducting a multi-faceted and innovative exploration and drilling program at Silver Peak. Determine the combination of techniques that are most useful and cost-effective in identifying the geothermal resource through a detailed, post-project evaluation of the exploration and drilling program.

  14. Silver Spring Networks Inc | Open Energy Information

    Open Energy Info (EERE)

    Spring Networks Inc Jump to: navigation, search Name: Silver Spring Networks Inc Place: Redwood City, California Zip: 94063 Product: California-based, developer of utility...

  15. Down-conversion photoluminescence sensitizing plasmonic silver...

    Office of Scientific and Technical Information (OSTI)

    sensitizing plasmonic silver nanoparticles on ZnO nanorods to generate hydrogen by water splitting photochemistry Citation Details In-Document Search Title:...

  16. Development Wells At Silver Peak Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Development Wells At Silver Peak Area (DOE GTP) Exploration Activity...

  17. Deep Bed Adsorption Testing using Silver-Functionalized Aerogel...

    Office of Scientific and Technical Information (OSTI)

    Deep Bed Adsorption Testing using Silver-Functionalized Aerogel Citation Details In-Document Search Title: Deep Bed Adsorption Testing using Silver-Functionalized Aerogel Nuclear ...

  18. Magnetotellurics At Silver Peak Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Magnetotellurics At Silver Peak Area (DOE GTP) Exploration Activity...

  19. Geothermometry At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Silver Peak Area (DOE GTP) Exploration Activity...

  20. Cuttings Analysis At Silver Peak Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Cuttings Analysis At Silver Peak Area (DOE GTP) Exploration Activity...

  1. Ground Magnetics At Silver Peak Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Magnetics At Silver Peak Area (DOE GTP) Exploration Activity...

  2. Pressure Temperature Log At Silver Peak Area (DOE GTP) | Open...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Pressure Temperature Log At Silver Peak Area (DOE GTP) Exploration Activity Details Location Silver Peak...

  3. Silver Creek Farms Aquaculture Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Creek Farms Aquaculture Low Temperature Geothermal Facility Jump to: navigation, search Name Silver Creek Farms Aquaculture Low Temperature Geothermal Facility Facility Silver...

  4. Advanced Manufacture of Second-Surface, Silvered Glass Reflectors...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Manufacture of Second-Surface, Silvered Glass Reflectors for High-Performance, Low-Cost CSP Collector Systems Advanced Manufacture of Second-Surface, Silvered Glass Reflectors for ...

  5. Energetics Measurements of Silver Halfraum Targets at the National...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Energetics Measurements of Silver Halfraum Targets at the National Ignition Facility Citation Details In-Document Search Title: Energetics Measurements of Silver ...

  6. Silver Spring Networks comments on DOE NBP RFI: Comms Requirements...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Comms Requirements Silver Spring Networks comments on DOE NBP RFI: Comms Requirements Comments of Silver Spring Networks on Implementing the National Broadband Plan by Studying the ...

  7. Silver Star Hot Springs Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Silver Star Hot Springs Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Silver Star Hot Springs Geothermal Area Contents 1 Area Overview 2 History and...

  8. EAGLES 1.1: A microcomputer software package for analyzing fuel efficiency of electric and gasoline vehicles

    SciTech Connect (OSTI)

    Marr, W.M.

    1994-05-15

    As part of the U.S. Department of Energy`s electric/hybrid vehicle research program, Argonne National Laboratory has developed a computer software package called EAGLES. This paper describes the capability of the software and its many features and potential applications. EAGLES version 1.1 is an interactive microcomputer software package for the analysis of battery performance in electric-vehicle applications, or the estimation of fuel economy for a gasoline vehicle. The principal objective of the electric-vehicle analysis is to enable the prediction of electric-vehicle performance (e.g., vehicle range) on the basis of laboratory test data for batteries. The model provides a second-by-second simulation of battery voltage and current for any specified velocity/time or power/time profile, taking into consideration the effects of battery depth-of-discharge and regenerative braking. Alternatively, the software package can be used to determine the size of the battery needed to satisfy given vehicle mission requirements (e.g., range and driving patterns). For gasoline-vehicle analysis, an empirical model relating fuel economy, vehicle parameters, and driving-cycle characteristics is included in the software package. For both types of vehicles, effects of heating/cooling loads on vehicle performance can be simulated. The software package includes many default data sets for vehicles, driving cycles, and battery technologies. EAGLES 1.1 is written in the FORTRAN language for use on IBM-compatible microcomputers.

  9. Using supercritical fluids to refine hydrocarbons

    DOE Patents [OSTI]

    Yarbro, Stephen Lee

    2014-11-25

    This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20.degree. and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.

  10. Refining New-Physics Searches in B→Dτν with Lattice QCD | Argonne

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Data Series: Refiner Crude Oil Inputs Refiner Gross Inputs Refiner Operable Capacity (Calendar Day) Refiner Percent Operable Utilization Net Inputs (Refiner and Blender) of Motor Gasoline Blending Comp Net Inputs (Refiner and Blender) of RBOB Blending Components Net Inputs (Refiner and Blender) of CBOB Blending Components Net Inputs (Refiner and Blender) of GTAB Blending Components Net Inputs (Refiner and Blender) of All Other Blending Component Net Inputs (Refiner and Blender) of Fuel Ethanol

  11. Structured Adaptive Mesh Refinement Application Infrastructure

    Energy Science and Technology Software Center (OSTI)

    2010-07-15

    SAMRAI is an object-oriented support library for structured adaptice mesh refinement (SAMR) simulation of computational science problems, modeled by systems of partial differential equations (PDEs). SAMRAI is developed and maintained in the Center for Applied Scientific Computing (CASC) under ASCI ITS and PSE support. SAMRAI is used in a variety of application research efforts at LLNL and in academia. These applications are developed in collaboration with SAMRAI development team members.

  12. Refining quadrilateral and brick element meshes

    SciTech Connect (OSTI)

    Schneiders, R.; Debye, J.

    1995-12-31

    We consider the problem of refining unstructured quadrilateral and brick element meshes. We present an algorithm which is a generalization of an algorithm developed by Cheng et. al. for structured quadrilateral element meshes. The problem is solved for the two-dimensional case. Concerning three dimensions we present a solution for some special cases and a general solution that introduces tetrahedral and pyramidal transition elements.

  13. Silver manganese oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Vaughey, John T.; Dees, Dennis W.

    2006-05-09

    This invention relates to electrodes for non-aqueous lithium cells and batteries with silver manganese oxide positive electrodes, denoted AgxMnOy, in which x and y are such that the manganese ions in the charged or partially charged electrodes cells have an average oxidation state greater than 3.5. The silver manganese oxide electrodes optionally contain silver powder and/or silver foil to assist in current collection at the electrodes and to improve the power capability of the cells or batteries. The invention relates also to a method for preparing AgxMnOy electrodes by decomposition of a permanganate salt, such as AgMnO4, or by the decomposition of KMnO4 or LiMnO4 in the presence of a silver salt.

  14. ,"Residual Fuel Oil Sales to End Users Refiner Sales Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Residual Fuel Oil Sales to End Users Refiner Sales ... "Back to Contents","Data 1: Residual Fuel Oil Sales to End Users Refiner Sales Volumes" ...

  15. ,"U.S. Residual Fuel Oil Refiner Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","U.S. Residual Fuel Oil Refiner Sales Volumes",2,"Monthly","5... "Back to Contents","Data 1: U.S. Residual Fuel Oil Refiner Sales Volumes" ...

  16. Diameter-Refined Metallic Carbon Nanotubes as Optically Tunable Transparent

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conductors | ANSER Center | Argonne-Northwestern National Laboratory Diameter-Refined Metallic Carbon Nanotubes as Optically Tunable Transparent Conductors Home > Research > ANSER Research Highlights > Diameter-Refined Metallic Carbon Nanotubes as Optically Tunable Transparent Conductors

  17. Grain Refinement of Permanent Mold Cast Copper Base Alloys

    SciTech Connect (OSTI)

    M.Sadayappan; J.P.Thomson; M.Elboujdaini; G.Ping Gu; M. Sahoo

    2005-04-01

    Grain refinement is a well established process for many cast and wrought alloys. The mechanical properties of various alloys could be enhanced by reducing the grain size. Refinement is also known to improve casting characteristics such as fluidity and hot tearing. Grain refinement of copper-base alloys is not widely used, especially in sand casting process. However, in permanent mold casting of copper alloys it is now common to use grain refinement to counteract the problem of severe hot tearing which also improves the pressure tightness of plumbing components. The mechanism of grain refinement in copper-base alloys is not well understood. The issues to be studied include the effect of minor alloy additions on the microstructure, their interaction with the grain refiner, effect of cooling rate, and loss of grain refinement (fading). In this investigation, efforts were made to explore and understand grain refinement of copper alloys, especially in permanent mold casting conditions.

  18. Secretary Bodman Tours Refinery and Calls for More Domestic Refining...

    Office of Environmental Management (EM)

    Bodman today renewed the call for expanded oil refining capacity in the United States and ... and one way to do that is to strengthen and expand our domestic oil refining capacity. ...

  19. Bandwidth Study U.S. Petroleum Refining | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Petroleum Refining Bandwidth Study U.S. Petroleum Refining Bandwidth Study U.S. Petroleum Refining Energy bandwidth studies of U.S. manufacturing sectors can serve as foundational references in framing the range (or bandwidth) of potential energy savings opportunities. This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. petroleum refining. The study relies on multiple sources to estimate the energy used in nine individual process areas,

  20. Genealogy of major U.S. refiners - Energy Information Administration

    U.S. Energy Information Administration (EIA) Indexed Site

    See full Genealogy of Major U.S. Refiners Previous Release Genealogy of Major U.S. Refiners Genealogy of Major U.S. Refiners Release date: September 18, 2013 figre 1. World energy consumption, 1990-2040. The structure of the U.S. petroleum refining industry has changed substantially over the past several years. In the diagram the companies shown on the right side are presently active in U.S. refining. The transactions over the past 25 years that created these companies also are shown. The

  1. Deformable elastic network refinement for low-resolution macromolecular crystallography

    SciTech Connect (OSTI)

    Schrder, Gunnar F.; Levitt, Michael; Brunger, Axel T.

    2014-09-01

    An overview of applications of the deformable elastic network (DEN) refinement method is presented together with recommendations for its optimal usage. Crystals of membrane proteins and protein complexes often diffract to low resolution owing to their intrinsic molecular flexibility, heterogeneity or the mosaic spread of micro-domains. At low resolution, the building and refinement of atomic models is a more challenging task. The deformable elastic network (DEN) refinement method developed previously has been instrumental in the determinion of several structures at low resolution. Here, DEN refinement is reviewed, recommendations for its optimal usage are provided and its limitations are discussed. Representative examples of the application of DEN refinement to challenging cases of refinement at low resolution are presented. These cases include soluble as well as membrane proteins determined at limiting resolutions ranging from 3 to 7 . Potential extensions of the DEN refinement technique and future perspectives for the interpretation of low-resolution crystal structures are also discussed.

  2. Pollution prevention in the petroleum refining industry

    SciTech Connect (OSTI)

    Fromm, C.H.; White, S.L.

    1995-09-01

    Pollution prevention (P2) as applied to petroleum refining should seek opportunities to reduce waste by preventing oil/hydrocarbon loss, by decreasing consumption of auxiliary input materials, and by improving conversion of incoming impurities into useful products. This chapter will focus on P2 techniques that have found or could find applications in minimizing or eliminating reducible solid waste and wastewater from the petroleum refining process. Air emissions are not covered. The following commonly encountered wastes are considered in this chapter: oily sludges; spent caustics; spent catalysts; miscellaneous process wastes; wastewater; maintenance and materials handling wastes. Following a brief description of waste components and sources, specific P2 techniques are presented in tabular form for each of these wastestreams. None of the P2 techniques presented is discussed here in any detail--the intent is to give the reader a menu of potentially effective P2 options to consider, along with the references where a more detailed discussion may be found. Some of the options presented were advanced in the original references merely as suggestions or plans for improvement. No effort was made to verify their efficacy or applicability in this compilation.

  3. Silver-hafnium braze alloy

    DOE Patents [OSTI]

    Stephens, Jr., John J.; Hosking, F. Michael; Yost, Frederick G.

    2003-12-16

    A binary allow braze composition has been prepared and used in a bonded article of ceramic-ceramic and ceramic-metal materials. The braze composition comprises greater than approximately 95 wt % silver, greater than approximately 2 wt % hafnium and less than approximately 4.1 wt % hafnium, and less than approximately 0.2 wt % trace elements. The binary braze alloy is used to join a ceramic material to another ceramic material or a ceramic material, such as alumina, quartz, aluminum nitride, silicon nitride, silicon carbide, and mullite, to a metal material, such as iron-based metals, cobalt-based metals, nickel-based metals, molybdenum-based metals, tungsten-based metals, niobium-based metals, and tantalum-based metals. A hermetic bonded article is obtained with a strength greater than 10,000 psi.

  4. Process for preparing improved silvered glass mirrors

    DOE Patents [OSTI]

    Buckwalter, C.Q. Jr.

    1980-01-28

    Glass mirrors having improved weathering properties are prepared by an improvement in the process for making the mirrors. The glass surface after it has been cleaned but before it is silvered, is contacted with a solution of lanthanide rare earths in addition to a sensitization solution of tin or palladium. The addition of the rare earths produces a mirror which has increased resistance to delamination of the silver from the glass surface in the presence of water.

  5. Process for preparing improved silvered glass mirrors

    DOE Patents [OSTI]

    Buckwalter, Jr., Charles Q. (Benton, WA)

    1981-01-01

    Glass mirrors having improved weathering properties are prepared by an improvement in the process for making the mirrors. The glass surface after it has been cleaned but before it is silvered, is contacted with a solution of lanthanide rare earths in addition to a sensitization solution of tin or palladium. The addition of the rare earths produces a mirror which has increased resistance to delamination of the silver from the glass surface in the presence of water.

  6. COSMOLOGICAL ADAPTIVE MESH REFINEMENT MAGNETOHYDRODYNAMICS WITH ENZO

    SciTech Connect (OSTI)

    Collins, David C.; Xu Hao; Norman, Michael L.; Li Hui; Li Shengtai

    2010-02-01

    In this work, we present EnzoMHD, the extension of the cosmological code Enzo to include the effects of magnetic fields through the ideal magnetohydrodynamics approximation. We use a higher order Godunov method for the computation of interface fluxes. We use two constrained transport methods to compute the electric field from those interface fluxes, which simultaneously advances the induction equation and maintains the divergence of the magnetic field. A second-order divergence-free reconstruction technique is used to interpolate the magnetic fields in the block-structured adaptive mesh refinement framework already extant in Enzo. This reconstruction also preserves the divergence of the magnetic field to machine precision. We use operator splitting to include gravity and cosmological expansion. We then present a series of cosmological and non-cosmological test problems to demonstrate the quality of solution resulting from this combination of solvers.

  7. Visualization Tools for Adaptive Mesh Refinement Data

    SciTech Connect (OSTI)

    Weber, Gunther H.; Beckner, Vincent E.; Childs, Hank; Ligocki,Terry J.; Miller, Mark C.; Van Straalen, Brian; Bethel, E. Wes

    2007-05-09

    Adaptive Mesh Refinement (AMR) is a highly effective method for simulations that span a large range of spatiotemporal scales, such as astrophysical simulations that must accommodate ranges from interstellar to sub-planetary. Most mainstream visualization tools still lack support for AMR as a first class data type and AMR code teams use custom built applications for AMR visualization. The Department of Energy's (DOE's) Science Discovery through Advanced Computing (SciDAC) Visualization and Analytics Center for Enabling Technologies (VACET) is currently working on extending VisIt, which is an open source visualization tool that accommodates AMR as a first-class data type. These efforts will bridge the gap between general-purpose visualization applications and highly specialized AMR visual analysis applications. Here, we give an overview of the state of the art in AMR visualization research and tools and describe how VisIt currently handles AMR data.

  8. Visualization of Scalar Adaptive Mesh Refinement Data

    SciTech Connect (OSTI)

    VACET; Weber, Gunther; Weber, Gunther H.; Beckner, Vince E.; Childs, Hank; Ligocki, Terry J.; Miller, Mark C.; Van Straalen, Brian; Bethel, E. Wes

    2007-12-06

    Adaptive Mesh Refinement (AMR) is a highly effective computation method for simulations that span a large range of spatiotemporal scales, such as astrophysical simulations, which must accommodate ranges from interstellar to sub-planetary. Most mainstream visualization tools still lack support for AMR grids as a first class data type and AMR code teams use custom built applications for AMR visualization. The Department of Energy's (DOE's) Science Discovery through Advanced Computing (SciDAC) Visualization and Analytics Center for Enabling Technologies (VACET) is currently working on extending VisIt, which is an open source visualization tool that accommodates AMR as a first-class data type. These efforts will bridge the gap between general-purpose visualization applications and highly specialized AMR visual analysis applications. Here, we give an overview of the state of the art in AMR scalar data visualization research.

  9. ITP Petroleum Refining: Energy and Environmental Profile of the U.S.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Petroleum Refining Industry (November 2007) | Department of Energy and Environmental Profile of the U.S. Petroleum Refining Industry (November 2007) ITP Petroleum Refining: Energy and Environmental Profile of the U.S. Petroleum Refining Industry (November 2007) profile.pdf (1.62 MB) More Documents & Publications ITP Petroleum Refining: Energy Bandwidth for Petroleum Refining Processes ITP Petroleum Refining: Energy and Environmental Profile of the U.S. Petroleum Refining Industry

  10. The Space-Based Telescopes for Actionable Refinement of Ephemeris...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: The Space-Based Telescopes for Actionable Refinement of Ephemeris Pathfinder Mission Citation Details In-Document Search Title: The Space-Based Telescopes for ...

  11. ,"U.S. Reformulated, Average Refiner Gasoline Prices"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...www.eia.govdnavpetpetprirefmg2cnusepm0rdpgalm.htm" ,"Source:","Energy Information ... Reformulated Gasoline Retail Sales by Refiners (Dollars per ...

  12. ,"U.S. Conventional, Average Refiner Gasoline Prices"

    U.S. Energy Information Administration (EIA) Indexed Site

    ...www.eia.govdnavpetpetprirefmg2cnusepm0udpgalm.htm" ,"Source:","Energy Information ... Conventional Gasoline Retail Sales by Refiners (Dollars per ...

  13. Refiners react to changes in the pipeline infrastructure

    SciTech Connect (OSTI)

    Giles, K.A.

    1997-06-01

    Petroleum pipelines have long been a critical component in the distribution of crude and refined products in the U.S. Pipelines are typically the most cost efficient mode of transportation for reasonably consistent flow rates. For obvious reasons, inland refineries and consumers are much more dependent on petroleum pipelines to provide supplies of crude and refined products than refineries and consumers located on the coasts. Significant changes in U.S. distribution patterns for crude and refined products are reshaping the pipeline infrastructure and presenting challenges and opportunities for domestic refiners. These changes are discussed.

  14. EERE Success Story—Refining Bio-Oil alongside Petroleum

    Office of Energy Efficiency and Renewable Energy (EERE)

    W.R. Grace and Pacific Northwest National Laboratory are working to establish a bio-oil refining process that users existing petroleum refinery infrastructure.

  15. New Process for Grain Refinement of Aluminum. Final Report

    SciTech Connect (OSTI)

    Dr. Joseph A. Megy

    2000-09-22

    A new method of grain refining aluminum involving in-situ formation of boride nuclei in molten aluminum just prior to casting has been developed in the subject DOE program over the last thirty months by a team consisting of JDC, Inc., Alcoa Technical Center, GRAS, Inc., Touchstone Labs, and GKS Engineering Services. The Manufacturing process to make boron trichloride for grain refining is much simpler than preparing conventional grain refiners, with attendant environmental, capital, and energy savings. The manufacture of boride grain refining nuclei using the fy-Gem process avoids clusters, salt and oxide inclusions that cause quality problems in aluminum today.

  16. The Space-based Telescopes for Actionable Refinement of Ephemeris...

    Office of Scientific and Technical Information (OSTI)

    Title: The Space-based Telescopes for Actionable Refinement of Ephemeris (STARE) mission Authors: Riot, V ; Devries, W ; Bauman, B ; Simms, L ; Carter, D ; Phillion, D ; Olivier, S ...

  17. ,"U.S. Total Refiner Petroleum Product Prices"

    U.S. Energy Information Administration (EIA) Indexed Site

    NUSDPG","EMAEPPRPTGNUSDPG","EMAEPPRLPTGNUSDPG","EMAEPPRHPTGNUSDPG" "Date","U.S. Total Gasoline Retail Sales by Refiners (Dollars per Gallon)","U.S. Aviation Gasoline...

  18. Petroleum Products Table 43. Refiner Motor Gasoline Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    of table. 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State 262 Energy Information Administration Petroleum Marketing Annual 1997 Table 43....

  19. Petroleum Products Table 43. Refiner Motor Gasoline Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    1995 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per Day) - Continued Geographic Area Month Premium All Grades Sales...

  20. Petroleum Products Table 43. Refiner Motor Gasoline Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    2000 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per Day) - Continued Geographic Area Month Premium All Grades Sales...

  1. Petroleum Products Table 43. Refiner Motor Gasoline Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    of table. 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State 262 Energy Information Administration Petroleum Marketing Annual 1996 Table 43....

  2. ITP Petroleum Refining: Petroleum Technology Vision 2020 | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Petroleum Technology Vision 2020 ITP Petroleum Refining: Petroleum Technology Vision 2020 techvision.pdf (684.96 KB) More Documents & Publications Manufacturing Energy and Carbon ...

  3. The Space-Based Telescopes for Actionable Refinement of Ephemeris...

    Office of Scientific and Technical Information (OSTI)

    Title: The Space-Based Telescopes for Actionable Refinement of Ephemeris Pathfinder Mission Authors: Simms, L ; De Vries, W ; RIot, V ; Olivier, S ; Pertica, A ; Bauman, B ; ...

  4. ITP Petroleum Refining: Energy Efficiency Roadmap for Petroleum...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency Roadmap for Petroleum Refineries in California ITP Petroleum Refining: Energy Efficiency Roadmap for Petroleum Refineries in California refiningroadmap.pdf (1.34 ...

  5. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information Administration Petroleum Marketing Annual 1995 Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  6. Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    250 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales Type, PAD District, and State (Thousand Gallons...

  7. Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information Administration Petroleum Marketing Annual 1995 Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales Type, PAD District, and State (Thousand Gallons...

  8. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    134 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  9. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    134 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  10. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    220 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per...

  11. Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    - - - - W W - - - - - - See footnotes at end of table. 44. Refiner Motor Gasoline Volumes by Formulation, Sales Type, PAD District, and State 292 Energy...

  12. Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    250 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 44. Refiner Motor Gasoline Volumes by Formulation, Sales Type, PAD District, and State (Thousand Gallons...

  13. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    220 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per...

  14. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information Administration Petroleum Marketing Annual 1995 Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State (Thousand Gallons per...

  15. Adaptive h -refinement for reduced-order models: ADAPTIVE h -refinement for reduced-order models

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Carlberg, Kevin T.

    2014-11-05

    Our work presents a method to adaptively refine reduced-order models a posteriori without requiring additional full-order-model solves. The technique is analogous to mesh-adaptive h-refinement: it enriches the reduced-basis space online by ‘splitting’ a given basis vector into several vectors with disjoint support. The splitting scheme is defined by a tree structure constructed offline via recursive k-means clustering of the state variables using snapshot data. This method identifies the vectors to split online using a dual-weighted-residual approach that aims to reduce error in an output quantity of interest. The resulting method generates a hierarchy of subspaces online without requiring large-scale operationsmore » or full-order-model solves. Furthermore, it enables the reduced-order model to satisfy any prescribed error tolerance regardless of its original fidelity, as a completely refined reduced-order model is mathematically equivalent to the original full-order model. Experiments on a parameterized inviscid Burgers equation highlight the ability of the method to capture phenomena (e.g., moving shocks) not contained in the span of the original reduced basis.« less

  16. Silver-catalyzed synthesis of amides from amines and aldehydes

    DOE Patents [OSTI]

    Madix, Robert J; Zhou, Ling; Xu, Bingjun; Friend, Cynthia M; Freyschlag, Cassandra G

    2014-11-18

    The invention provides a method for producing amides via the reaction of aldehydes and amines with oxygen adsorbed on a metallic silver or silver alloy catalyst. An exemplary reaction is shown in Scheme 1: (I), (II), (III). ##STR00001##

  17. Silver Spring, Maryland: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    You can help OpenEI by expanding it. Silver Spring is a census-designated place in Montgomery County, Maryland.1 Registered Energy Companies in Silver Spring, Maryland CPV Wind...

  18. Sintered silver joints via controlled topography of electronic packaging subcomponents

    DOE Patents [OSTI]

    Wereszczak, Andrew A.

    2014-09-02

    Disclosed are sintered silver bonded electronic package subcomponents and methods for making the same. Embodiments of the sintered silver bonded EPSs include topography modification of one or more metal surfaces of semiconductor devices bonded together by the sintered silver joint. The sintered silver bonded EPSs include a first semiconductor device having a first metal surface, the first metal surface having a modified topography that has been chemically etched, grit blasted, uniaxial ground and/or grid sliced connected to a second semiconductor device which may also include a first metal surface with a modified topography, a silver plating layer on the first metal surface of the first semiconductor device and a silver plating layer on the first metal surface of the second semiconductor device and a sintered silver joint between the silver plating layers of the first and second semiconductor devices which bonds the first semiconductor device to the second semiconductor device.

  19. Steel refining with an electrochemical cell

    DOE Patents [OSTI]

    Blander, Milton; Cook, Glenn M.

    1988-01-01

    Apparatus for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight oxygen and not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom.

  20. Steel refining with an electrochemical cell

    DOE Patents [OSTI]

    Blander, M.; Cook, G.M.

    1988-05-17

    Apparatus is described for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight oxygen and not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom. 2 figs.

  1. Steel refining with an electrochemical cell

    DOE Patents [OSTI]

    Blander, M.; Cook, G.M.

    1985-05-21

    Disclosed is an apparatus for processing a metallic fluid containing iron oxide, container for a molten metal including an electrically conductive refractory disposed for contact with the molten metal which contains iron oxide, an electrolyte in the form of a basic slag on top of the molten metal, an electrode in the container in contact with the slag electrically separated from the refractory, and means for establishing a voltage across the refractory and the electrode to reduce iron oxide to iron at the surface of the refractory in contact with the iron oxide containing fluid. A process is disclosed for refining an iron product containing not more than about 10% by weight sulfur, comprising providing an electrolyte of a slag containing one or more of calcium oxide, magnesium oxide, silica or alumina, providing a cathode of the iron product in contact with the electrolyte, providing an anode in contact with the electrolyte electrically separated from the cathode, and operating an electrochemical cell formed by the anode, the cathode and the electrolyte to separate oxygen or sulfur present in the iron product therefrom.

  2. Refining and End Use Study of Coal Liquids

    SciTech Connect (OSTI)

    1997-10-01

    This report summarizes revisions to the design basis for the linear programing refining model that is being used in the Refining and End Use Study of Coal Liquids. This revision primarily reflects the addition of data for the upgrading of direct coal liquids.

  3. ,"Motor Gasoline Sales to End Users, Total Refiner Sales Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Refiners (Thousand Gallons per Day)","New Mexico Total Gasoline Retail Sales by Refiners ...87,16127.8,1684.4,1377.2,128.8,497.8,835.6,2030.3,1178.7,674.5,56.4,3.9,4678.6,764.1,9.3,1...

  4. ,"No. 2 Distillate Sales to End Users Refiner Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Refiners (Thousand Gallons per Day)","New Mexico No 2 Distillate Retail Sales by Refiners ...57.7,6018.7,64.6,101.5,691.5,1553.8,1576.9,2030.5,4320.3,1350.4,683.2,792.4,316.4,804.3,37...

  5. Reitveld refinement study of PLZT ceramics

    SciTech Connect (OSTI)

    Kumar, Rakesh; Bavbande, D. V.; Bafna, V. H.; Mohan, D.; Kothiyal, G. P.; Mishra, R.

    2013-02-05

    PLZT ceramics of composition Pb{sub 0.93}La{sub 0.07}(Zr{sub 0.60}Ti{sub 0.40})O{sub 3}, have been milled for 6hrs and 24hrs were prepared by solid state synthesis route. The 6hrs milled and 24hrs milled samples are represented as PLZT-6 and PLZT-24 ceramics respectively. X-ray diffraction (XRD) pattern was recorded at room temperature. The XRD pattern has been analyzed by employing Rietveld refinement method. Phase identification shows that all the peaks observed in PLZT-6 and PLZT-24 ceramics could be indexed to P4mm space group with tetragonal symmetry. The unit cell parameters of 6hrs milled PLZT ceramics are found to be a=b=4.0781(5)A and c=4.0938(7)A and for 24hrs milled PLZT ceramics unit cell parameters are a=b=4.0679(4)A and c=4.1010(5)A . The axial ratio c/a and unit cell volume of PLZT-6 are 1.0038 and 68.09(2)A{sup 3} respectively. In PLZT-24 samples, the axial ratio c/a value is 1.0080 which is little more than that of the 6hr milled PLZT sample whereas the unit cell volume decrease to 67.88 (1) A{sup 3}. An average crystallite size was estimated by using Scherrer's formula. Dielectric properties were obtained by measuring the capacitance and tand loss using Stanford LCR meter.

  6. Silver doped catalysts for treatment of exhaust

    DOE Patents [OSTI]

    Park, Paul Worn [Peoria, IL; Boyer, Carrie L [Shiloh, IL

    2006-12-26

    A method of making an exhaust treatment catalyst includes dispersing a metal-based material in a first solvent to form a first slurry and allowing polymerization of the first slurry to occur. Polymerization of the first slurry may be quenched and the first slurry may be allowed to harden into a solid. This solid may be redistributed in a second solvent to form a second slurry. The second slurry may be loaded with a silver-based material, and a silver-loaded powder may be formed from the second slurry.

  7. Biosynthesis and structural characterization of silver nanoparticles from bacterial isolates

    SciTech Connect (OSTI)

    Zaki, Sahar; El Kady, M.F.; Abd-El-Haleem, Desouky

    2011-10-15

    Graphical abstract: In this study five bacterial isolates belong to different genera were found to be able to biosynthesize silver nanoparticles. Biosynthesis and spectral characterization are reported here. Highlights: {yields} About 300 bacterial isolates were screened for their ability to produce nanosilvers {yields} Five of them were potential candidates for synthesis of silver nanoparticles {yields} Production of silver nanoparticles was examined using UV-Vis, XRD, SEM and EDS. {yields} The presence of nanoparticles with all five bacterial isolates was confirmed. -- Abstract: This study aimed to develop a green process for biosynthesis of silver nanomaterials by some Egyptian bacterial isolates. This target was achieved by screening an in-house culture collection consists of 300 bacterial isolates for silver nanoparticle formation. Through screening process, it was observed that strains belonging to Escherichia coli (S30, S78), Bacillus megaterium (S52), Acinetobacter sp. (S7) and Stenotrophomonas maltophilia (S54) were potential candidates for synthesis of silver nanoparticles. The extracellular production of silver nanoparticles by positive isolates was investigated by UV-Vis spectroscopy, X-ray diffraction (XRD), transmission electron microscope (TEM), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The results demonstrated that UV-visible spectrum of the aqueous medium containing silver ion showed a peak at 420 nm corresponding to the plasmon absorbance of silver nanoparticles. Scanning electron microscopy micrograph showed formation of silver nanoparticles in the range of 15-50 nm. XRD-spectrum of the silver nanoparticles exhibited 2{theta} values corresponding to the silver nanocrystal that produce in hexagonal and cubic crystal configurations with different plane of orientation. In addition, the signals of the silver atoms were observed by EDS-spectrum analysis that confirms the presence of silver nanoparticles (Ag

  8. Integrated process for the solvent refining of coal

    DOE Patents [OSTI]

    Garg, Diwakar

    1983-01-01

    A process is set forth for the integrated liquefaction of coal by the catalytic solvent refining of a feed coal in a first stage to liquid and solid products and the catalytic hydrogenation of the solid product in a second stage to produce additional liquid product. A fresh inexpensive, throw-away catalyst is utilized in the second stage hydrogenation of the solid product and this catalyst is recovered and recycled for catalyst duty in the solvent refining stage without any activation steps performed on the used catalyst prior to its use in the solvent refining of feed coal.

  9. PIXE analysis of medieval silver coins

    SciTech Connect (OSTI)

    Abdelouahed, H. Ben; Gharbi, F.; Roumie, M.; Baccouche, S.; Romdhane, K. Ben; Nsouli, B.; Trabelsi, A.

    2010-01-15

    We applied the proton-induced X-ray emission (PIXE) analytical technique to twenty-eight medieval silver coins, selected from the Tunisian treasury. The purpose is to study the fineness evolution from the beginning of the 7th to the 15th centuries AD. Each silver coin was cleaned with a diluted acid solution and then exposed to a 3 MeV proton beam from a 1.7 MV tandem accelerator. To allow the simultaneous detection of light and heavy elements, a funny aluminum filter was positioned in front of the Si(Li) detector entrance which is placed at 135{sup o} to the beam direction. The elements Cu, Pb, and Au were observed in the studied coins along with the major component silver. The concentration of Ag, presumably the main constituent of the coins, varies from 55% to 99%. This significant variation in the concentration of the major constituent reveals the economical difficulties encountered by each dynasty. It could be also attributed to differences in the composition of the silver mines used to strike the coins in different locations. That fineness evolution also reflects the poor quality of the control practices during this medieval period. In order to verify the ability of PIXE analytical method to distinguish between apparently similar coins, we applied hierarchical cluster analysis to our results to classify them into different subgroups of similar elemental composition.

  10. Silver doped catalysts for treatment of exhaust

    DOE Patents [OSTI]

    Park, Paul Worn; Hester, Virgil Raymond; Ragle, Christie Susan; Boyer, Carrie L.

    2009-06-02

    A method of making an exhaust treatment element includes washcoating a substrate with a slurry that includes a catalyst support material. At least some of the catalyst support material from the slurry may be transferred to the substrate, and silver metal (Ag) is dispersed within the catalyst support material.

  11. May 28 Webinar to Focus on Tribal Energy Project Refinement

    Broader source: Energy.gov [DOE]

    Register for the Tribal Renewable Energy Project Refinement webinar, which will be held on Wednesday, May 28, 2014, from 11 a.m. to 12:30 p.m. Mountain time.

  12. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    253.2 2,222.4 W W 206.4 134.3 - 340.7 See footnotes at end of table. 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State 262 Energy Information...

  13. Table 43. Refiner Motor Gasoline Volumes by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    150.0 2,026.7 W W 234.5 161.7 - 396.3 See footnotes at end of table. 43. Refiner Motor Gasoline Volumes by Grade, Sales Type, PAD District, and State 262 Energy Information...

  14. Waste minimization for selected residuals in the petroleum refining industry

    SciTech Connect (OSTI)

    1996-12-01

    This technical report on residuals in the petroleum refining industry provides an industry overview, process description, and process flow diagrams. It presents residual descriptions for each of the 29 petroleum refining residuals of concern and what source reduction option exist. It reviews the data sources - RCRA Section 2007 surveys, site visits, and journal articles. It also describes major findings and evaluates the quantity and quality of waste minization information for each source.

  15. Hydrogen Piping Experience in Chevron Refining | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Piping Experience in Chevron Refining Hydrogen Piping Experience in Chevron Refining Overall Perspectives: Few problems with hydrogen piping operating at ambient to at least 800F and pressures up to at least 3000psia as long as we stay within well-defined limits hpwgw_chevronrefining_niccolls.pdf (373.32 KB) More Documents & Publications DOE Hydrogen Pipeline Working Group Workshop Hydrogen Pipeline Working Group Workshop: Code for Hydrogen Pipelines A Review of Stress Corrosion

  16. DOE - Office of Legacy Management -- Belmont Smelting and Refining Works

    Office of Legacy Management (LM)

    Inc - NY 44 Belmont Smelting and Refining Works Inc - NY 44 FUSRAP Considered Sites Site: Belmont Smelting & Refining Works Inc (NY 0-04) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Brooklyn , New York NY.44-1 Evaluation Year: 1987 NY.44-1 Site Operations: Supplied the MED with construction materials. NY.44-1 Site Disposition: Eliminated - No indication of radioactive materials handled at this site NY.44-1 Radioactive

  17. EERE Success Story-Refining Bio-Oil alongside Petroleum | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Refining Bio-Oil alongside Petroleum EERE Success Story-Refining Bio-Oil alongside Petroleum April 9, 2013 - 12:00am Addthis W.R. Grace, a leading provider of refining ...

  18. PJM Presentation - The Silver Bullet: Storage! (July 12, 2011) | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy PJM Presentation - The Silver Bullet: Storage! (July 12, 2011) PJM Presentation - The Silver Bullet: Storage! (July 12, 2011) Presentation by Terry Boston, President and CEO pf PJM Interconnection before the Electricity Advisorty Committee, July 12, 2011, on storage for the smart grid. The Silver Bullet: Storage! (1.25 MB) More Documents & Publications Support for Steffes Corporation, Application for Exception, OHA Case No. EXC-14-0002 Ex Parte Communication, Docket

  19. Durable Corrosion and Ultraviolet-Resistant Silver Mirror

    DOE Patents [OSTI]

    Jorgensen, G. J.; Gee, R.

    2006-01-24

    A corrosion and ultra violet-resistant silver mirror for use in solar reflectors; the silver layer having a film-forming protective polymer bonded thereto, and a protective shield overlay comprising a transparent multipolymer film that incorporates a UV absorber. The corrosion and ultraviolet resistant silver mirror retains spectral hemispherical reflectance and high optical clarity throughout the UV and visible spectrum when used in solar reflectors.

  20. Carlsbad Field Office Receives New Mexico's Silver Award for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Environmental Excellence | Department of Energy Receives New Mexico's Silver Award for Environmental Excellence Carlsbad Field Office Receives New Mexico's Silver Award for Environmental Excellence August 1, 2012 - 12:00pm Addthis DOE Carlsbad Field Office Deputy Manager Ed Ziemianski presents a Waste Isolation Pilot Plant (WIPP) team with the Green Zia Program Silver Level Leader award from the New Mexico Environment Department earlier this month in recognition of environmental initiatives.

  1. Silver Ink for Conductor Printing - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    flake suspended in a suitable solvent amenable to printing. These silver metal suspension formulations require high processing temperatures to sinter the particles (180 C)....

  2. Humidity Effect on Nanoscale Electrochemistry in Solid Silver...

    Office of Scientific and Technical Information (OSTI)

    Nanoscale Electrochemistry in Solid Silver Ion Conductors and the Dual Nature of Its Locality Citation Details In-Document Search Title: Humidity Effect on Nanoscale ...

  3. Deep Bed Adsorption Testing using Silver-Functionalized Aerogel...

    Office of Scientific and Technical Information (OSTI)

    Bed Adsorption Testing using Silver-Functionalized Aerogel Nick Soelberg; Tony Watson 12 MGMT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES aerogel; iodine...

  4. DNA Origami Directed Self-Assembly of Discrete Silver Nanoparticle...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DNA origami nanostructures were utilized as spatially addressable templates to organize noble-metal nanoparticles of silver and gold into well-defined discrete architectures ...

  5. Multispectral Imaging At Silver Peak Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Multispectral Imaging At Silver Peak Area (DOE GTP) Exploration Activity Details...

  6. Hot-junction electrode members for copper/silver chalcogenides

    DOE Patents [OSTI]

    Hampl, Jr., Edward F.

    1979-12-25

    Tungsten, molybdenum, and alloys thereof are useful as electrode members for thermoelectric legs made from chalcogenides of copper and/or silver.

  7. There is no Silver Bullet: Regionalization and Market Fragmentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Market Fragmentation in Greenhouse Gas Mitigation Strategies There is no Silver Bullet: Regionalization and Market Fragmentation in Greenhouse Gas Mitigation Strategies 2004 ...

  8. Synthesis of silver particles on copper substrates using ethanol...

    Office of Scientific and Technical Information (OSTI)

    Analysis of the surface morphologies of sample substrates by field emission scanning electron microscopy (FESEM) showed that the silver nanoparticles prepared by this new method ...

  9. Deep Bed Adsorption Testing using Silver-Functionalized Aerogel...

    Office of Scientific and Technical Information (OSTI)

    Title: Deep Bed Adsorption Testing using Silver-Functionalized Aerogel Nuclear fission ... Subject: 12 MGMT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES ...

  10. Humidity Effect on Nanoscale Electrochemistry in Solid Silver...

    Office of Scientific and Technical Information (OSTI)

    and the Dual Nature of Its Locality Prev Next Title: Humidity Effect on Nanoscale Electrochemistry in Solid Silver Ion Conductors and the Dual Nature of Its Locality ...

  11. Anion-controlled assembly of silver-di(aminophenyl)sulfone coordinatio...

    Office of Scientific and Technical Information (OSTI)

    Anion-controlled assembly of silver-di(aminophenyl)sulfone coordination polymers: ... Title: Anion-controlled assembly of silver-di(aminophenyl)sulfone coordination polymers: ...

  12. Gamma Log At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gamma Log At Silver Peak Area (DOE GTP) Exploration Activity Details...

  13. Neutron Log At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Neutron Log At Silver Peak Area (DOE GTP) Exploration Activity Details...

  14. Slim Holes At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Slim Holes At Silver Peak Area (DOE GTP) Exploration Activity Details...

  15. Core Analysis At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Silver Peak Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Core Analysis At Silver Peak Area (DOE GTP) Exploration Activity...

  16. 2-M Probe At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: 2-M Probe At Silver Peak Area (DOE GTP) Exploration Activity Details Location Silver Peak...

  17. Flow Test At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Flow Test At Silver Peak Area (DOE GTP) Exploration Activity Details Location Silver Peak Area...

  18. Rock Density At Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Rock Density At Silver Peak Area (DOE GTP) Exploration Activity Details Location Silver Peak Area...

  19. Density Log at Silver Peak Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Density Log at Silver Peak Area (DOE GTP) Exploration Activity Details Location Silver Peak...

  20. The US petroleum refining industry in the 1980's

    SciTech Connect (OSTI)

    Not Available

    1990-10-11

    As part of the EIA program on petroleum, The US Petroleum Refining Industry in the 1980's, presents a historical analysis of the changes that took place in the US petroleum refining industry during the 1980's. It is intended to be of interest to analysts in the petroleum industry, state and federal government officials, Congress, and the general public. The report consists of six chapters and four appendices. Included is a detailed description of the major events and factors that affected the domestic refining industry during this period. Some of the changes that took place in the 1980's are the result of events that started in the 1970's. The impact of these events on US refinery configuration, operations, economics, and company ownership are examined. 23 figs., 11 tabs.

  1. Toward parallel, adaptive mesh refinement for chemically reacting flow simulations

    SciTech Connect (OSTI)

    Devine, K.D.; Shadid, J.N.; Salinger, A.G. Hutchinson, S.A.; Hennigan, G.L.

    1997-12-01

    Adaptive numerical methods offer greater efficiency than traditional numerical methods by concentrating computational effort in regions of the problem domain where the solution is difficult to obtain. In this paper, the authors describe progress toward adding mesh refinement to MPSalsa, a computer program developed at Sandia National laboratories to solve coupled three-dimensional fluid flow and detailed reaction chemistry systems for modeling chemically reacting flow on large-scale parallel computers. Data structures that support refinement and dynamic load-balancing are discussed. Results using uniform refinement with mesh sequencing to improve convergence to steady-state solutions are also presented. Three examples are presented: a lid driven cavity, a thermal convection flow, and a tilted chemical vapor deposition reactor.

  2. Trends in heavy oil production and refining in California

    SciTech Connect (OSTI)

    Olsen, D.K.; Ramzel, E.B.; Pendergrass, R.A. II

    1992-07-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production and is part of a study being conducted for the US Department of Energy. This report summarizes trends in oil production and refining in Canada. Heavy oil (10{degrees} to 20{degrees} API gravity) production in California has increased from 20% of the state`s total oil production in the early 1940s to 70% in the late 1980s. In each of the three principal petroleum producing districts (Los Angeles Basin, Coastal Basin, and San Joaquin Valley) oil production has peaked then declined at different times throughout the past 30 years. Thermal production of heavy oil has contributed to making California the largest producer of oil by enhanced oil recovery processes in spite of low oil prices for heavy oil and stringent environmental regulation. Opening of Naval Petroleum Reserve No. 1, Elk Hills (CA) field in 1976, brought about a major new source of light oil at a time when light oil production had greatly declined. Although California is a major petroleum-consuming state, in 1989 the state used 13.3 billion gallons of gasoline or 11.5% of US demand but it contributed substantially to the Nation`s energy production and refining capability. California is the recipient and refines most of Alaska`s 1.7 million barrel per day oil production. With California production, Alaskan oil, and imports brought into California for refining, California has an excess of oil and refined products and is a net exporter to other states. The local surplus of oil inhibits exploitation of California heavy oil resources even though the heavy oil resources exist. Transportation, refining, and competition in the market limit full development of California heavy oil resources.

  3. Trends in heavy oil production and refining in California

    SciTech Connect (OSTI)

    Olsen, D.K.; Ramzel, E.B.; Pendergrass, R.A. II.

    1992-07-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production and is part of a study being conducted for the US Department of Energy. This report summarizes trends in oil production and refining in Canada. Heavy oil (10{degrees} to 20{degrees} API gravity) production in California has increased from 20% of the state's total oil production in the early 1940s to 70% in the late 1980s. In each of the three principal petroleum producing districts (Los Angeles Basin, Coastal Basin, and San Joaquin Valley) oil production has peaked then declined at different times throughout the past 30 years. Thermal production of heavy oil has contributed to making California the largest producer of oil by enhanced oil recovery processes in spite of low oil prices for heavy oil and stringent environmental regulation. Opening of Naval Petroleum Reserve No. 1, Elk Hills (CA) field in 1976, brought about a major new source of light oil at a time when light oil production had greatly declined. Although California is a major petroleum-consuming state, in 1989 the state used 13.3 billion gallons of gasoline or 11.5% of US demand but it contributed substantially to the Nation's energy production and refining capability. California is the recipient and refines most of Alaska's 1.7 million barrel per day oil production. With California production, Alaskan oil, and imports brought into California for refining, California has an excess of oil and refined products and is a net exporter to other states. The local surplus of oil inhibits exploitation of California heavy oil resources even though the heavy oil resources exist. Transportation, refining, and competition in the market limit full development of California heavy oil resources.

  4. PROP re-refined oil engine test performance

    SciTech Connect (OSTI)

    Linnard, R.E.

    1980-11-01

    Using conventional, commercially-available nonproprietary (to Phillips) additive treatments, engine test programs have successfully demonstrated Phillips Re-refined Oil Process (PROP) oils' compliance with the performance requirements of MIL-L-46152A and API Services SE/CC. This paper reports on the engine testing experience with PROP refined oils as produced in a full-scale 2 MM GPY PROP plant operating with Buyer-collected used oil feedstocks. Comment is also made on the status of the first two PROP plants, one built for the state of North Carolina and the other for Mohawk Oil Company, Ltd., Vancouver B.C., Canada.

  5. Energy Efficiency Improvement in the Petroleum RefiningIndustry

    SciTech Connect (OSTI)

    Worrell, Ernst; Galitsky, Christina

    2005-05-01

    Information has proven to be an important barrier inindustrial energy efficiency improvement. Voluntary government programsaim to assist industry to improve energy efficiency by supplyinginformation on opportunities. ENERGY STAR(R) supports the development ofstrong strategic corporate energy management programs, by providingenergy management information tools and strategies. This paper summarizesENERGY STAR research conducted to develop an Energy Guide for thePetroleum Refining industry. Petroleum refining in the United States isthe largest in the world, providing inputs to virtually every economicsector, including the transport sector and the chemical industry.Refineries spend typically 50 percent of the cash operating costs (e.g.,excluding capital costs and depreciation) on energy, making energy amajor cost factor and also an important opportunity for cost reduction.The petroleum refining industry consumes about 3.1 Quads of primaryenergy, making it the single largest industrial energy user in the UnitedStates. Typically, refineries can economically improve energy efficiencyby 20 percent. The findings suggest that given available resources andtechnology, there are substantial opportunities to reduce energyconsumption cost-effectively in the petroleum refining industry whilemaintaining the quality of the products manufactured.

  6. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    2. U.S. Refiner Retail Petroleum Product Prices Figure J F M A M J J A S O N D 0 20 40 60 80 100 120 1995 Cents per Gallon Excluding Taxes Kero-jet Propane No. 1 Distillate No. 4...

  7. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    4. U.S. Refiner Wholesale Petroleum Product Prices Figure J F M A M J J A S O N D 0 20 40 60 80 100 120 1997 Cents per Gallon Excluding Taxes Kero-jet Propane No. 1 Distillate No....

  8. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    4. U.S. Refiner Wholesale Petroleum Product Prices Figure J F M A M J J A S O N D 0 20 40 60 80 100 120 1995 Cents per Gallon Excluding Taxes Kero-jet Propane No. 1 Distillate No....

  9. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    2. U.S. Refiner Retail Petroleum Product Prices Figure J F M A M J J A S O N D 0 20 40 60 80 100 120 1996 Cents per Gallon Excluding Taxes Kero-jet Propane No. 1 Distillate No. 4...

  10. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    Prices J F M A M J J A S O N D 0 10 20 30 40 50 60 70 1995 Cents per Gallon Excluding Taxes Retail < or 1% Wholesale < or 1% Retail > 1% Wholesale > 1% 7. U.S. Refiner Residual...

  11. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    4. U.S. Refiner Wholesale Petroleum Product Prices Figure J F M A M J J A S O N D 0 20 40 60 80 100 120 1996 Cents per Gallon Excluding Taxes Kero-jet Propane No. 1 Distillate No....

  12. Source: Energy Information Administration, Form EIA-782A, "Refiners...

    U.S. Energy Information Administration (EIA) Indexed Site

    2. U.S. Refiner Retail Petroleum Product Prices Figure J F M A M J J A S O N D 0 20 40 60 80 100 120 1997 Cents per Gallon Excluding Taxes Kero-jet Propane No. 1 Distillate No. 4...

  13. Process for electroslag refining of uranium and uranium alloys

    DOE Patents [OSTI]

    Lewis, P.S. Jr.; Agee, W.A.; Bullock, J.S. IV; Condon, J.B.

    1975-07-22

    A process is described for electroslag refining of uranium and uranium alloys wherein molten uranium and uranium alloys are melted in a molten layer of a fluoride slag containing up to about 8 weight percent calcium metal. The calcium metal reduces oxides in the uranium and uranium alloys to provide them with an oxygen content of less than 100 parts per million. (auth)

  14. Decontamination of transuranic contaminated metals by melt refining

    SciTech Connect (OSTI)

    Heshmatpour, B.; Copeland, G.L.; Heestand, R.L.

    1983-01-01

    Melt refining of transuranic contaminated metals is a possible decontamination process with the potential advantages of producing metal for reuse and of simplifying chemical analyses. By routinely achieving the 10 nCi/g( about0.1ppm) level by melt refining, scrap metal can be removed from the transuranic waste category. (To demonstrate the effectiveness of this melt refining process, mild steel, stainless steel, nickel, and copper were contaminated with 500 ppm (..mu..g/g) PuO/sub 2/ and melted with various fluxes. The solidified slags and metals were analyzed for their plutonium contents, and corresponding partition ratios for plutonium were calculated. Some metals were double refined in order to study the effect of secondary slag treatment. The initial weight of the slags was also varied to investigate the effect of slag weight on the degree of plutonium removal. In general, all four metals could be decontaminated below 1 ppm (..mu..g/g) Pu ( about100 nCi/g) by a single slag treatment. Doubling the slag weight did not improve decontamination significantly; however, double slag treatment using 5 wt.% slag did decontaminate the metals to below 0.1 ppm (..mu..g/g) Pu (10 nCi/g).)

  15. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    71.8 W 70.5 78.9 W 76.0 83.6 W 69.2 75.2 See footnotes at end of table. 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District and State 176 Energy Information...

  16. Table 35. Refiner Motor Gasoline Prices by Grade, Sales Type...

    U.S. Energy Information Administration (EIA) Indexed Site

    W 68.4 70.8 W W 78.6 W 85.7 81.8 W 69.3 73.8 See footnotes at end of table. 35. Refiner Motor Gasoline Prices by Grade, Sales Type, PAD District and State 176 Energy Information...

  17. ,"Conventional Gasoline Sales to End Users, Total Refiner Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Refiners (Thousand Gallons per Day)","New Mexico Conventional Gasoline Retail Sales by ...928.8,,587,12358.1,196,1145.9,128.8,497.8,,2030.3,,459.7,56.4,3.9,4678.6,764.1,9.3,1677.4,...

  18. A possible oriented attachment growth mechanism for silver nanowire formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Murph, Simona E. Hunyadi; Murphy, Catherine J.; Leach, Austin; Gall, Kenneth

    2015-04-06

    Electron microscopy studies suggest that silver nanowires prepared by an approach reported earlier by us (Caswell, K. K., Bender, C. M., Murphy, C. J. Nano Lett.,2003, 3, 667–669) form through a coarsening process via an oriented attachment mechanism. Initially, silver nucleation centers were produced by chemical reduction of silver ions in boiling water, with sodium citrate and sodium hydroxide as additives in solution. These nucleation centers, with a twinned crystallographic orientation, ultimately merge into fully grown silver nanowires. This is a completely different mechanism from the seed-mediated growth approach, which has also been used to produce silver nanowires. Furthermore, companionmore » molecular dynamics performed with the embedded atom method are in agreement with our experimental data.« less

  19. A possible oriented attachment growth mechanism for silver nanowire formation

    SciTech Connect (OSTI)

    Murph, Simona E. Hunyadi; Murphy, Catherine J.; Leach, Austin; Gall, Kenneth

    2015-04-06

    Electron microscopy studies suggest that silver nanowires prepared by an approach reported earlier by us (Caswell, K. K., Bender, C. M., Murphy, C. J. Nano Lett.,2003, 3, 667–669) form through a coarsening process via an oriented attachment mechanism. Initially, silver nucleation centers were produced by chemical reduction of silver ions in boiling water, with sodium citrate and sodium hydroxide as additives in solution. These nucleation centers, with a twinned crystallographic orientation, ultimately merge into fully grown silver nanowires. This is a completely different mechanism from the seed-mediated growth approach, which has also been used to produce silver nanowires. Furthermore, companion molecular dynamics performed with the embedded atom method are in agreement with our experimental data.

  20. Properties of Bulk Sintered Silver As a Function of Porosity

    SciTech Connect (OSTI)

    Wereszczak, Andrew A; Vuono, Daniel J; Wang, Hsin; Ferber, Mattison K; Liang, Zhenxian

    2012-06-01

    This report summarizes a study where various properties of bulk-sintered silver were investigated over a range of porosity. This work was conducted within the National Transportation Research Center's Power Device Packaging project that is part of the DOE Vehicle Technologies Advanced Power Electronics and Electric Motors Program. Sintered silver, as an interconnect material in power electronics, inherently has porosity in its produced structure because of the way it is made. Therefore, interest existed in this study to examine if that porosity affected electrical properties, thermal properties, and mechanical properties because any dependencies could affect the intended function (e.g., thermal transfer, mechanical stress relief, etc.) or reliability of that interconnect layer and alter how its performance is modeled. Disks of bulk-sintered silver were fabricated using different starting silver pastes and different sintering conditions to promote different amounts of porosity. Test coupons were harvested out of the disks to measure electrical resistivity and electrical conductivity, thermal conductivity, coefficient of thermal expansion, elastic modulus, Poisson's ratio, and yield stress. The authors fully recognize that the microstructure of processed bulk silver coupons may indeed not be identical to the microstructure produced in thin (20-50 microns) layers of sintered silver. However, measuring these same properties with such a thin actual structure is very difficult, requires very specialized specimen preparation and unique testing instrumentation, is expensive, and has experimental shortfalls of its own, so the authors concluded that the herein measured responses using processed bulk sintered silver coupons would be sufficient to determine acceptable values of those properties. Almost all the investigated properties of bulk sintered silver changed with porosity content within a range of 3-38% porosity. Electrical resistivity, electrical conductivity, thermal

  1. Adsorption of silver dimer on graphene - A DFT study

    SciTech Connect (OSTI)

    Kaur, Gagandeep, E-mail: gaganj1981@yahoo.com [Department of Physics and Centre of Advanced Studies in Physics, Panjab University, Chandigarh-160014, India and Chandigarh Engineering College, Landran, Mohali-140307, Punjab (India); Gupta, Shuchi [Department of Physics and Centre of Advanced Studies in Physics, Panjab University, Chandigarh-160014, India and University Institute of Engineering and Technology, Panjab University, Chandigarh -160014 (India); Rani, Pooja; Dharamvir, Keya [Department of Physics and Centre of Advanced Studies in Physics, Panjab University, Chandigarh-160014 (India)

    2014-04-24

    We performed a systematic density functional theory (DFT) study of the adsorption of silver dimer (Ag{sub 2}) on graphene using SIESTA (Spanish Initiative for Electronic Simulations with Thousands of Atoms) package, in the generalized gradient approximation (GGA). The adsorption energy, geometry, and charge transfer of Ag2-graphene system are calculated. The minimum energy configuration for a silver dimer is parallel to the graphene sheet with its two atoms directly above the centre of carbon-carbon bond. The negligible charge transfer between the dimer and the surface is also indicative of a weak bond. The methodology demonstrated in this paper may be applied to larger silver clusters on graphene sheet.

  2. REFINING AND END USE STUDY OF COAL LIQUIDS

    SciTech Connect (OSTI)

    Unknown

    2002-01-01

    This document summarizes all of the work conducted as part of the Refining and End Use Study of Coal Liquids. There were several distinct objectives set, as the study developed over time: (1) Demonstration of a Refinery Accepting Coal Liquids; (2) Emissions Screening of Indirect Diesel; (3) Biomass Gasification F-T Modeling; and (4) Updated Gas to Liquids (GTL) Baseline Design/Economic Study.

  3. Environmental Regulations and Changes in Petroleum Refining Operations

    Gasoline and Diesel Fuel Update (EIA)

    Environmental Regulations and Changes in Petroleum Refining Operations By Tancred C.M. Lidderdale Contents * Introduction * Motor Gasoline Summer Volatility (RVP) Regulations o Table 1. Summer Volatility Regulations for Motor Gasoline o Table 2. Refinery Inputs and Production of Normal Butane o Figure 1. Refinery Inputs and Production of Normal Butane o Table 3. Price Relationship Between Normal Butane and Motor Gasoline o Table 4. Market Price Premium for Low Vapor Pressure (RVP) Gasoline *

  4. Decontamination of steel by melt refining: A literature review

    SciTech Connect (OSTI)

    Ozturk, B.; Fruehan, R.J.

    1994-12-31

    It has been reported that a large amount of metal waste is produced annually by nuclear fuel processing and nuclear power plants. These metal wastes are contaminated with radioactive elements, such as uranium and plutonium. Current Department of Energy guidelines require retrievable storage of all metallic wastes containing transuranic elements above a certain level. Because of high cost, it is important to develop an effective decontamination and volume reduction method for low level contaminated metals. It has been shown by some investigators that a melt refining technique can be used for the processing of the contaminated metal wastes. In this process, contaminated metal is melted wit a suitable flux. The radioactive elements are oxidized and transferred to a slag phase. In order to develop a commercial process it is important to have information on the thermodynamics and kinetics of the removal. Therefore, a literature search was carried out to evaluate the available information on the decontamination uranium and transuranic-contaminated plain steel, copper and stainless steel by melt a refining technique. Emphasis was given to the thermodynamics and kinetics of the removal. Data published in the literature indicate that it is possible to reduce the concentration of radioactive elements to a very low level by the melt refining method. 20 refs.

  5. Mesh refinement for uncertainty quantification through model reduction

    SciTech Connect (OSTI)

    Li, Jing Stinis, Panos

    2015-01-01

    We present a novel way of deciding when and where to refine a mesh in probability space in order to facilitate uncertainty quantification in the presence of discontinuities in random space. A discontinuity in random space makes the application of generalized polynomial chaos expansion techniques prohibitively expensive. The reason is that for discontinuous problems, the expansion converges very slowly. An alternative to using higher terms in the expansion is to divide the random space in smaller elements where a lower degree polynomial is adequate to describe the randomness. In general, the partition of the random space is a dynamic process since some areas of the random space, particularly around the discontinuity, need more refinement than others as time evolves. In the current work we propose a way to decide when and where to refine the random space mesh based on the use of a reduced model. The idea is that a good reduced model can monitor accurately, within a random space element, the cascade of activity to higher degree terms in the chaos expansion. In turn, this facilitates the efficient allocation of computational sources to the areas of random space where they are more needed. For the Kraichnan–Orszag system, the prototypical system to study discontinuities in random space, we present theoretical results which show why the proposed method is sound and numerical results which corroborate the theory.

  6. Parallel Block Structured Adaptive Mesh Refinement on Graphics Processing Units

    SciTech Connect (OSTI)

    Beckingsale, D. A.; Gaudin, W. P.; Hornung, R. D.; Gunney, B. T.; Gamblin, T.; Herdman, J. A.; Jarvis, S. A.

    2014-11-17

    Block-structured adaptive mesh refinement is a technique that can be used when solving partial differential equations to reduce the number of zones necessary to achieve the required accuracy in areas of interest. These areas (shock fronts, material interfaces, etc.) are recursively covered with finer mesh patches that are grouped into a hierarchy of refinement levels. Despite the potential for large savings in computational requirements and memory usage without a corresponding reduction in accuracy, AMR adds overhead in managing the mesh hierarchy, adding complex communication and data movement requirements to a simulation. In this paper, we describe the design and implementation of a native GPU-based AMR library, including: the classes used to manage data on a mesh patch, the routines used for transferring data between GPUs on different nodes, and the data-parallel operators developed to coarsen and refine mesh data. We validate the performance and accuracy of our implementation using three test problems and two architectures: an eight-node cluster, and over four thousand nodes of Oak Ridge National Laboratory’s Titan supercomputer. Our GPU-based AMR hydrodynamics code performs up to 4.87× faster than the CPU-based implementation, and has been scaled to over four thousand GPUs using a combination of MPI and CUDA.

  7. ,"Kerosene-Type Jet Fuel Sales to End Users Refiner Sales Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    Kerosene-Type Jet Fuel Sales to End Users Refiner Sales Volumes" ,"Click worksheet name or ... Data for" ,"Data 1","Kerosene-Type Jet Fuel Sales to End Users Refiner Sales ...

  8. RFA-14-0001 - In the Matter of Commonwealth Oil Refining Company...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    RFA-14-0001 - In the Matter of Commonwealth Oil Refining Company, Inc.Commonwealth of Puerto Rico RFA-14-0001 - In the Matter of Commonwealth Oil Refining Company, Inc....

  9. Catalytic hydroprocessing of solvent refined coal to provide a liquid and a solid fuel

    SciTech Connect (OSTI)

    Dabkowski, M.J.; Heck, R.H.; Stein, T.R.

    1980-04-29

    In the hydroprocessing of blends of solvent refined coal and recycle solvent, small pore hydrotreating catalysts cause separation of a solid phase from treating blends containing high concentration of solvent refined coal.

  10. Silver Peak, Nevada: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    This article is a stub. You can help OpenEI by expanding it. Silver Peak is a city in Esmeralda County, Nevada. References USGS GNIS Retrieved from "http:en.openei.orgw...

  11. Humidity Effect on Nanoscale Electrochemistry in Solid Silver...

    Office of Scientific and Technical Information (OSTI)

    the Dual Nature of Its Locality Citation Details In-Document Search Title: Humidity Effect on Nanoscale Electrochemistry in Solid Silver Ion Conductors and the Dual Nature of Its ...

  12. Occupational employment survey, booklet of definitions. Petroleum refining, coal products, and related industries

    SciTech Connect (OSTI)

    Not Available

    1992-01-01

    The publication gives occupational definitions for 149 occupations in the petroleum refining, coal products, and related industries.

  13. Petroleum Refining Sector (NAICS 324110) Energy and GHG Combustion Emissions Profile, November 2012

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    69 2.4 PETROLEUM REFINING SECTOR (NAICS 324110) 2.4.1. Overview of the Petroleum Refining Manufacturing Sector Petroleum refining is a complex industry that generates a diverse slate of fuel products and petrochemicals, from gasoline to asphalt. Refining requires a range of processing steps, including distillation, cracking, reforming, and treating. Most of these processes are highly reliant on process heating and steam energy. Petroleum refineries are an essential part of the U.S. economy.

  14. Deep Bed Adsorption Testing using Silver-Functionalized Aerogel (Technical

    Office of Scientific and Technical Information (OSTI)

    Report) | SciTech Connect Deep Bed Adsorption Testing using Silver-Functionalized Aerogel Citation Details In-Document Search Title: Deep Bed Adsorption Testing using Silver-Functionalized Aerogel Nuclear fission results in the production of fission products and activation products, some of which tend to be volatile during used fuel reprocessing and evolve in gaseous species into the reprocessing facility off-gas systems. Analyses have shown that I129, due to its radioactivity, high

  15. There is no Silver Bullet: Regionalization and Market Fragmentation in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Greenhouse Gas Mitigation Strategies | Department of Energy There is no Silver Bullet: Regionalization and Market Fragmentation in Greenhouse Gas Mitigation Strategies There is no Silver Bullet: Regionalization and Market Fragmentation in Greenhouse Gas Mitigation Strategies 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Joint Global Change Research Institute 2004_deer_stokes.pdf (661.01 KB) More Documents & Publications Analysis Activities at Pacific Northwest

  16. Environmental control technology for mining, milling, and refining thorium

    SciTech Connect (OSTI)

    Weakley, S.A.; Blahnik, D.E.; Young, J.K.; Bloomster, C.H.

    1980-02-01

    The purpose of this report is to evaluate, in terms of cost and effectiveness, the various environmental control technologies that would be used to control the radioactive wastes generated in the mining, milling, and refining of thorium from domestic resources. The technologies, in order to be considered for study, had to reduce the radioactivity in the waste streams to meet Atomic Energy Commission (10 CFR 20) standards for natural thorium's maximum permissible concentration (MPC) in air and water. Further regulatory standards or licensing requirements, either federal, state, or local, were not examined. The availability and cost of producing thorium from domestic resources is addressed in a companion volume. The objectives of this study were: (1) to identify the major waste streams generated during the mining, milling, and refining of reactor-grade thorium oxide from domestic resources; and (2) to determine the cost and levels of control of existing and advanced environmental control technologies for these waste streams. Six potential domestic deposits of thorium oxide, in addition to stockpiled thorium sludges, are discussed in this report. A summary of the location and characteristics of the potential domestic thorium resources and the mining, milling, and refining processes that will be needed to produce reactor-grade thorium oxide is presented in Section 2. The wastes from existing and potential domestic thorium oxide mines, mills, and refineries are identified in Section 3. Section 3 also presents the state-of-the-art technology and the costs associated with controlling the wastes from the mines, mills, and refineries. In Section 4, the available environmental control technologies for mines, mills, and refineries are assessed. Section 5 presents the cost and effectiveness estimates for the various environmental control technologies applicable to the mine, mill, and refinery for each domestic resource.

  17. Cogeneration handbook for the petroleum refining industry. [Contains glossary

    SciTech Connect (OSTI)

    Fassbender, L.L.; Garrett-Price, B.A.; Moore, N.L.; Fassbender, A.G.; Eakin, D.E.; Gorges, H.A.

    1984-03-01

    The decision of whether to cogenerate involves several considerations, including technical, economic, environmental, legal, and regulatory issues. Each of these issues is addressed separately in this handbook. In addition, a chapter is included on preparing a three-phase work statement, which is needed to guide the design of a cogeneration system. In addition, an annotated bibliography and a glossary of terminology are provided. Appendix A provides an energy-use profile of the petroleum refining industry. Appendices B through O provide specific information that will be called out in subsequent chapters.

  18. Changing Trends in the Refining Industry (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01

    There have been some major changes in the U.S. refining industry recently, prompted in part by a significant decline in the quality of imported crude oil and by increasing restrictions on the quality of finished products. As a result, high-quality crudes, such as the West Texas Intermediate (WTI) crude that serves as a benchmark for oil futures on the New York Mercantile Exchange (NYMEX), have been trading at record premiums to the OPEC (Organization of the Petroleum Exporting Countries) Basket price.

  19. Metal decontamination for waste minimization using liquid metal refining technology

    SciTech Connect (OSTI)

    Joyce, E.L. Jr.; Lally, B.; Ozturk, B.; Fruehan, R.J.

    1993-09-01

    The current Department of Energy Mixed Waste Treatment Project flowsheet indicates that no conventional technology, other than surface decontamination, exists for metal processing. Current Department of Energy guidelines require retrievable storage of all metallic wastes containing transuranic elements above a certain concentration. This project is in support of the National Mixed Low Level Waste Treatment Program. Because of the high cost of disposal, it is important to develop an effective decontamination and volume reduction method for low-level contaminated metals. It is important to be able to decontaminate complex shapes where surfaces are hidden or inaccessible to surface decontamination processes and destruction of organic contamination. These goals can be achieved by adapting commercial metal refining processes to handle radioactive and organic contaminated metal. The radioactive components are concentrated in the slag, which is subsequently vitrified; hazardous organics are destroyed by the intense heat of the bath. The metal, after having been melted and purified, could be recycled for use within the DOE complex. In this project, we evaluated current state-of-the-art technologies for metal refining, with special reference to the removal of radioactive contaminants and the destruction of hazardous organics. This evaluation was based on literature reports, industrial experience, plant visits, thermodynamic calculations, and engineering aspects of the various processes. The key issues addressed included radioactive partitioning between the metal and slag phases, minimization of secondary wastes, operability of the process subject to widely varying feed chemistry, and the ability to seal the candidate process to prevent the release of hazardous species.

  20. Synthesis Of Silver Sulfide Stratified Photocatalyst

    SciTech Connect (OSTI)

    Baba, Y.; Yokoyama, S.; Takahashi, H.; Tohji, K.

    2008-02-25

    In this report, silver sulfide (Ag{sub 2}S) was selected as a new H{sub 2}S splitting photocatalyst material, and considered the synthesis method of Ag{sub 2}S photocatalyst particles with stratified structure. Previous stratified particles were synthesized by using metal oxide (hydroxide) as the precursor. Ag{sub 2}O particles as the precursor of Ag{sub 2}S were synthesized by mixing AgNO{sub 3} solution and NaOH, and their particle sizes could be controlled by the solutions' concentration. Then, Ag{sub 2}S particles were obtained by adding Na{sub 2}S solution into suspending solution of Ag{sub 2}O particles with optimum sizes. Particle sizes of Ag{sub 2}S were changed by Na{sub 2}S concentration control, and remaining Ag{sub 2}O precursor could be dissolved by adding NH{sub 3} solution. The photocatalytic H{sub 2}S splitting could be realized by UV-light irradiation on the Ag{sub 2}S particles without co-catalyst like Pt.

  1. Size-dependent structure of silver nanoparticles under high pressure

    SciTech Connect (OSTI)

    Koski, Kristie Jo

    2008-12-31

    Silver noble metal nanoparticles that are<10 nm often possess multiply twinned grains allowing them to adopt shapes and atomic structures not observed in bulk materials. The properties exhibited by particles with multiply twinned polycrystalline structures are often far different from those of single-crystalline particles and from the bulk. I will present experimental evidence that silver nanoparticles<10 nm undergo a reversible structural transformation under hydrostatic pressures up to 10 GPa. Results for nanoparticles in the intermediate size range of 5 to 10 nm suggest a reversible linear pressure-dependent rhombohedral distortion which has not been previously observed in bulk silver. I propose a mechanism for this transitiion that considers the bond-length distribution in idealized multiply twinned icosahedral particles. Results for nanoparticles of 3.9 nm suggest a reversible linear pressure-dependent orthorhombic distortion. This distortion is interpreted in the context of idealized decahedral particles. In addition, given these size-dependent measurements of silver nanoparticle compression with pressure, we have constructed a pressure calibration curve. Encapsulating these silver nanoparticles in hollow metal oxide nanospheres then allows us to measure the pressure inside a nanoshell using x-ray diffraction. We demonstrate the measurement of pressure gradients across nanoshells and show that these nanoshells have maximum resolved shear strengths on the order of 500 MPa to IGPa.

  2. ENZO: AN ADAPTIVE MESH REFINEMENT CODE FOR ASTROPHYSICS

    SciTech Connect (OSTI)

    Bryan, Greg L.; Turk, Matthew J.; Norman, Michael L.; Bordner, James; Xu, Hao; Kritsuk, Alexei G.; O'Shea, Brian W.; Smith, Britton; Abel, Tom; Wang, Peng; Skillman, Samuel W.; Wise, John H.; Reynolds, Daniel R.; Collins, David C.; Harkness, Robert P.; Kim, Ji-hoon; Kuhlen, Michael; Goldbaum, Nathan; Hummels, Cameron; Collaboration: Enzo Collaboration; and others

    2014-04-01

    This paper describes the open-source code Enzo, which uses block-structured adaptive mesh refinement to provide high spatial and temporal resolution for modeling astrophysical fluid flows. The code is Cartesian, can be run in one, two, and three dimensions, and supports a wide variety of physics including hydrodynamics, ideal and non-ideal magnetohydrodynamics, N-body dynamics (and, more broadly, self-gravity of fluids and particles), primordial gas chemistry, optically thin radiative cooling of primordial and metal-enriched plasmas (as well as some optically-thick cooling models), radiation transport, cosmological expansion, and models for star formation and feedback in a cosmological context. In addition to explaining the algorithms implemented, we present solutions for a wide range of test problems, demonstrate the code's parallel performance, and discuss the Enzo collaboration's code development methodology.

  3. Fuel and oxygen addition for metal smelting or refining process

    DOE Patents [OSTI]

    Schlichting, Mark R.

    1994-01-01

    A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

  4. Fuel and oxygen addition for metal smelting or refining process

    DOE Patents [OSTI]

    Schlichting, M.R.

    1994-11-22

    A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figs.

  5. A case study of energy conservation opportunities in copper refining

    SciTech Connect (OSTI)

    Somers, W.E.; Hughen, M.L.; Kurylko, L.; Stone, J.R.

    1982-07-01

    A study of energy usage and distribution in a copper refinery was conducted in an attempt to determine possible cost savings in operations of the plant. The study covered those processes which were the major users of energy, namely, smelting, anode casting, electrolytic refining, steam generation and distribution, and electricity distribution. The study involved obtaining data of mass and energy flows in the refinery; identifying energy conservation opportunities (ECO's); obtaining price, operating costs, and saving potentials; for each conservation measure; and analyzing the economical viability of each conservation proposal. Potential cost savings were found to be substantial in heat recovery from slag and anode furnace hot gases, modification of the central steam supply system, control, and redistribution of electrical loads, insulation of electrolytic tanks, and changes in the atomization of oil.

  6. A Comparative Assessment of Resource Efficiency in Petroleum Refining

    SciTech Connect (OSTI)

    Han, Jeongwoo; Forman, G; Elgowainy, Amgad; Cai, Hao; Wang, Michael; Divita, V

    2015-10-01

    Because of increasing environmental and energy security concerns, a detailed understanding of energy efficiency and greenhouse gas (GHG) emissions in the petroleum refining industry is critical for fair and equitable energy and environmental policies. To date, this has proved challenging due in part to the complex nature and variability within refineries. In an effort to simplify energy and emissions refinery analysis, we delineated LP modeling results from 60 large refineries from the US and EU into broad categories based on crude density (API gravity) and heavy product (HP) yields. Product-specific efficiencies and process fuel shares derived from this study were incorporated in Argonne National Laboratory's GREET life-cycle model, along with regional upstream GHG intensities of crude, natural gas and electricity specific to the US and EU regions. The modeling results suggest that refineries that process relatively heavier crude inputs and have lower yields of HPs generally have lower energy efficiencies and higher GHG emissions than refineries that run lighter crudes with lower yields of HPs. The former types of refineries tend to utilize energy-intensive units which are significant consumers of utilities (heat and electricity) and hydrogen. Among the three groups of refineries studied, the major difference in the energy intensities is due to the amount of purchased natural gas for utilities and hydrogen, while the sum of refinery feed inputs are generally constant. These results highlight the GHG emissions cost a refiner pays to process deep into the barrel to produce more of the desirable fuels with low carbon to hydrogen ratio. (c) 2015 Argonne National Laboratory. Published by Elsevier Ltd.

  7. A comparative assessment of resource efficiency in petroleum refining

    SciTech Connect (OSTI)

    Han, Jeongwoo; Forman, Grant S.; Elgowainy, Amgad; Cai, Hao; Wang, Michael; DiVita, Vincent B.

    2015-03-25

    Because of increasing environmental and energy security concerns, a detailed understanding of energy efficiency and greenhouse gas (GHG) emissions in the petroleum refining industry is critical for fair and equitable energy and environmental policies. To date, this has proved challenging due in part to the complex nature and variability within refineries. In an effort to simplify energy and emissions refinery analysis, we delineated LP modeling results from 60 large refineries from the US and EU into broad categories based on crude density (API gravity) and heavy product (HP) yields. Product-specific efficiencies and process fuel shares derived from this study were incorporated in Argonne National Laboratory’s GREET life-cycle model, along with regional upstream GHG intensities of crude, natural gas and electricity specific to the US and EU regions. The modeling results suggest that refineries that process relatively heavier crude inputs and have lower yields of HPs generally have lower energy efficiencies and higher GHG emissions than refineries that run lighter crudes with lower yields of HPs. The former types of refineries tend to utilize energy-intensive units which are significant consumers of utilities (heat and electricity) and hydrogen. Among the three groups of refineries studied, the major difference in the energy intensities is due to the amount of purchased natural gas for utilities and hydrogen, while the sum of refinery feed inputs are generally constant. These results highlight the GHG emissions cost a refiner pays to process deep into the barrel to produce more of the desirable fuels with low carbon to hydrogen ratio.

  8. A comparative assessment of resource efficiency in petroleum refining

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Han, Jeongwoo; Forman, Grant S.; Elgowainy, Amgad; Cai, Hao; Wang, Michael; DiVita, Vincent B.

    2015-03-25

    Because of increasing environmental and energy security concerns, a detailed understanding of energy efficiency and greenhouse gas (GHG) emissions in the petroleum refining industry is critical for fair and equitable energy and environmental policies. To date, this has proved challenging due in part to the complex nature and variability within refineries. In an effort to simplify energy and emissions refinery analysis, we delineated LP modeling results from 60 large refineries from the US and EU into broad categories based on crude density (API gravity) and heavy product (HP) yields. Product-specific efficiencies and process fuel shares derived from this study weremore » incorporated in Argonne National Laboratory’s GREET life-cycle model, along with regional upstream GHG intensities of crude, natural gas and electricity specific to the US and EU regions. The modeling results suggest that refineries that process relatively heavier crude inputs and have lower yields of HPs generally have lower energy efficiencies and higher GHG emissions than refineries that run lighter crudes with lower yields of HPs. The former types of refineries tend to utilize energy-intensive units which are significant consumers of utilities (heat and electricity) and hydrogen. Among the three groups of refineries studied, the major difference in the energy intensities is due to the amount of purchased natural gas for utilities and hydrogen, while the sum of refinery feed inputs are generally constant. These results highlight the GHG emissions cost a refiner pays to process deep into the barrel to produce more of the desirable fuels with low carbon to hydrogen ratio.« less

  9. Atmospheric pressure plasma enhanced spatial ALD of silver

    SciTech Connect (OSTI)

    Bruele, Fieke J. van den Smets, Mireille; Illiberi, Andrea; Poodt, Paul; Buskens, Pascal; Roozeboom, Fred

    2015-01-15

    The authors have investigated the growth of thin silver films using a unique combination of atmospheric process elements: spatial atomic layer deposition and an atmospheric pressure surface dielectric barrier discharge plasma source. Silver films were grown on top of Si substrates with good purity as revealed by resistivity values as low as 18 μΩ cm and C- and F-levels below detection limits of energy dispersive x-ray analysis. The growth of the silver films starts through the nucleation of islands that subsequently coalesce. The authors show that the surface island morphology is dependent on surface diffusion, which can be controlled by temperature within the deposition temperature range of 100–120 °C.

  10. Tin-silver-bismuth solders for electronics assembly

    DOE Patents [OSTI]

    Vianco, P.T.; Rejent, J.A.

    1995-08-08

    A lead-free solder alloy is disclosed for electronic assemblies composed of a eutectic alloy of tin and silver with a bismuth addition, x, of 0silver composition to a desired level. Melting point ranges from about 218 C down to about 205 C depending an the amount of bismuth added to the eutectic tin-silver alloy as determined by DSC analysis, 10 C/min. A preferred alloy composition is 91.84Sn-3.33Ag-4.83Bi (weight percent based on total alloy weight). 4 figs.

  11. Tin-silver-bismuth solders for electronics assembly

    DOE Patents [OSTI]

    Vianco, Paul T.; Rejent, Jerome A.

    1995-01-01

    A lead-free solder alloy for electronic assemblies composed of a eutectic alloy of tin and silver with a bismuth addition, x, of 0silver composition to a desired level. Melting point ranges from about 218.degree. C. down to about 205.degree. C. depending an the amount of bismuth added to the eutectic tin-silver alloy as determined by DSC analysis, 10.degree. C./min. A preferred alloy composition is 91.84Sn-3.33Ag-4.83Bi (weight percent based on total alloy weight).

  12. PATCHY SILICA-COATED SILVER NANOWIRES AS SERS SUBSTRATES

    SciTech Connect (OSTI)

    Murph, S.; Murphy, C.

    2013-03-29

    We report a class of core-shell nanomaterials that can be used as efficient surface-enhancement Raman scattering (SERS) substrates. The core consists of silver nanowires, prepared through a chemical reduction process, that are used to capture 4- mercaptobenzoic acid (4-MBA), a model analyte. The shell was prepared through a modified Stber method and consists of patchy or full silica coats. The formation of silica coats was monitored via transmission electron microscopy, UV-visible spectroscopy and phase-analysis light scattering for measuring effective surface charge. Surprisingly, the patchy silica coated silver nanowires are better SERS substrate than silver nanowires; nanomolar concentration of 4-MBA can be detected. In addition, nano-matryoshka configurations were used to quantitate/explore the effect of the electromagnetic field at the tips of the nanowire (hot spots) in the Raman scattering experiment.

  13. Evaluation of tropical channel refinement using MPAS-A aquaplanet simulations: TROPICAL CHANNEL REFINEMENT IN MPAS-A

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Martini, Matus N.; Gustafson, William I.; O'Brien, Travis A.; Ma, Po-Lun

    2015-09-01

    Climate models with variable-resolution grids offer a computationally less expensive way to provide more detailed information at regional scales and increased accuracy for processes that cannot be resolved by a coarser grid. This study uses the Model for Prediction Across Scales–Atmosphere (MPAS22A), consisting of a nonhydrostatic dynamical core and a subset of Advanced Research Weather Research and Forecasting (ARW-WRF) model atmospheric physics that have been modified to include the Community Atmosphere Model version 5 (CAM5) cloud fraction parameterization, to investigate the potential benefits of using increased resolution in an tropical channel. The simulations are performed with an idealized aquaplanet configurationmore » using two quasi-uniform grids, with 30 km and 240 km grid spacing, and two variable-resolution grids spanning the same grid spacing range; one with a narrow (20°S–20°N) and one with a wide (30°S–30°N) tropical channel refinement. Results show that increasing resolution in the tropics impacts both the tropical and extratropical circulation. Compared to the quasi-uniform coarse grid, the narrow-channel simulation exhibits stronger updrafts in the Ferrel cell as well as in the middle of the upward branch of the Hadley cell. The wider tropical channel has a closer correspondence to the 30 km quasi-uniform simulation. However, the total atmospheric poleward energy transports are similar in all simulations. The largest differences are in the low-level cloudiness. The refined channel simulations show improved tropical and extratropical precipitation relative to the global 240 km simulation when compared to the global 30 km simulation. All simulations have a single ITCZ. The relatively small differences in mean global and tropical precipitation rates among the simulations are a promising result, and the evidence points to the tropical channel being an effective method for avoiding the extraneous numerical artifacts seen in earlier

  14. Silver Peak Innovative Exploration Project (Ram Power Inc.)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Miller, Clay

    2010-01-01

    Data generated from the Silver Peak Innovative Exploration Project, in Esmeralda County, Nevada, encompasses a deep-circulation (amagmatic) meteoric-geothermal system circulating beneath basin-fill sediments locally blanketed with travertine in western Clayton Valley (lithium-rich brines from which have been mined for several decades). Spring- and shallow-borehole thermal-water geochemistry and geothermometry suggest that a Silver Peak geothermal reservoir is very likely to attain the temperature range 260- 300oF (~125-150oC), and may reach 300-340oF (~150-170oC) or higher (GeothermEx, Inc., 2006). Results of detailed geologic mapping, structural analysis, and conceptual modeling of the prospect (1) support the GeothermEx (op. cit.) assertion that the Silver Peak prospect has good potential for geothermal-power production; and (2) provide a theoretical geologic framework for further exploration and development of the resource. The Silver Peak prospect is situated in the transtensional (regional shearing coupled with extension) Walker Lane structural belt, and squarely within the late Miocene to Pliocene (11 Ma to ~5 Ma) Silver Peak-Lone Mountain metamorphic core complex (SPCC), a feature that accommodated initial displacement transfer between major right-lateral strike- slip fault zones on opposite sides of the Walker Lane. The SPCC consists essentially of a ductiley-deformed lower plate, or core, of Proterozoic metamorphic tectonites and tectonized Mesozoic granitoids separated by a regionally extensive, low-angle detachment fault from an upper plate of severely stretched and fractured structural slices of brittle, Proterozoic to Miocene-age lithologies. From a geothermal perspective, the detachment fault itself and some of the upper-plate structural sheets could function as important, if secondary, subhorizontal thermal-fluid aquifers in a Silver Peak hydrothermal system.

  15. Silver Peak Innovative Exploration Project (Ram Power Inc.)

    SciTech Connect (OSTI)

    Miller, Clay

    2010-01-01

    Data generated from the Silver Peak Innovative Exploration Project, in Esmeralda County, Nevada, encompasses a “deep-circulation (amagmatic)” meteoric-geothermal system circulating beneath basin-fill sediments locally blanketed with travertine in western Clayton Valley (lithium-rich brines from which have been mined for several decades). Spring- and shallow-borehole thermal-water geochemistry and geothermometry suggest that a Silver Peak geothermal reservoir is very likely to attain the temperature range 260- 300oF (~125-150oC), and may reach 300-340oF (~150-170oC) or higher (GeothermEx, Inc., 2006). Results of detailed geologic mapping, structural analysis, and conceptual modeling of the prospect (1) support the GeothermEx (op. cit.) assertion that the Silver Peak prospect has good potential for geothermal-power production; and (2) provide a theoretical geologic framework for further exploration and development of the resource. The Silver Peak prospect is situated in the transtensional (regional shearing coupled with extension) Walker Lane structural belt, and squarely within the late Miocene to Pliocene (11 Ma to ~5 Ma) Silver Peak-Lone Mountain metamorphic core complex (SPCC), a feature that accommodated initial displacement transfer between major right-lateral strike- slip fault zones on opposite sides of the Walker Lane. The SPCC consists essentially of a ductiley-deformed lower plate, or “core,” of Proterozoic metamorphic tectonites and tectonized Mesozoic granitoids separated by a regionally extensive, low-angle detachment fault from an upper plate of severely stretched and fractured structural slices of brittle, Proterozoic to Miocene-age lithologies. From a geothermal perspective, the detachment fault itself and some of the upper-plate structural sheets could function as important, if secondary, subhorizontal thermal-fluid aquifers in a Silver Peak hydrothermal system.

  16. Silver Peak Innovative Exploration Project (Ram Power Inc.)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Miller, Clay

    Data generated from the Silver Peak Innovative Exploration Project, in Esmeralda County, Nevada, encompasses a deep-circulation (amagmatic) meteoric-geothermal system circulating beneath basin-fill sediments locally blanketed with travertine in western Clayton Valley (lithium-rich brines from which have been mined for several decades). Spring- and shallow-borehole thermal-water geochemistry and geothermometry suggest that a Silver Peak geothermal reservoir is very likely to attain the temperature range 260- 300oF (~125-150oC), and may reach 300-340oF (~150-170oC) or higher (GeothermEx, Inc., 2006). Results of detailed geologic mapping, structural analysis, and conceptual modeling of the prospect (1) support the GeothermEx (op. cit.) assertion that the Silver Peak prospect has good potential for geothermal-power production; and (2) provide a theoretical geologic framework for further exploration and development of the resource. The Silver Peak prospect is situated in the transtensional (regional shearing coupled with extension) Walker Lane structural belt, and squarely within the late Miocene to Pliocene (11 Ma to ~5 Ma) Silver Peak-Lone Mountain metamorphic core complex (SPCC), a feature that accommodated initial displacement transfer between major right-lateral strike- slip fault zones on opposite sides of the Walker Lane. The SPCC consists essentially of a ductiley-deformed lower plate, or core, of Proterozoic metamorphic tectonites and tectonized Mesozoic granitoids separated by a regionally extensive, low-angle detachment fault from an upper plate of severely stretched and fractured structural slices of brittle, Proterozoic to Miocene-age lithologies. From a geothermal perspective, the detachment fault itself and some of the upper-plate structural sheets could function as important, if secondary, subhorizontal thermal-fluid aquifers in a Silver Peak hydrothermal system.

  17. Influence of Alloy and Solidification Parameters on Grain Refinement in Aluminum Weld Metal due to Inoculation

    SciTech Connect (OSTI)

    Schempp, Philipp [BAM, Germany; Tang, Z. [BIAS, Germany; Cross, Carl E. [Los Alamos National Laboratory; Seefeld, T. [BIAS, Germany; Pittner, A. [BAM, Germany; Rethmeier, M. [BAM, Germany

    2012-06-28

    The goals are: (1) Establish how much Ti/B grain refiner is need to completely refine aluminum weld metal for different alloys and different welding conditions; (2) Characterize how alloy composition and solidification parameters affect weld metal grain refinement; and (3) Apply relevant theory to understand observed behavior. Conclusions are: (1) additions of Ti/B grain refiner to weld metal in Alloys 1050, 5083, and 6082 resulted in significant grain refinement; (2) grain refinement was more effective in GTAW than LBW, resulting in finer grains at lower Ti content - reason is limited time available for equiaxed grain growth in LBW (inability to occlude columnar grain growth); (3) welding travel speed did not markedly affect grain size within GTAW and LBW clusters; and (4) application of Hunt CET analysis showed experimental G to be on the order of the critical G{sub CET}; G{sub CET} was consistently higher for GTAW than for LBW.

  18. Silver chromate and silver dichromate nanostructures: Sonochemical synthesis, characterization, and photocatalytic properties

    SciTech Connect (OSTI)

    Soofivand, Faezeh; Mohandes, Fatemeh; Salavati-Niasari, Masoud

    2013-06-01

    Graphical abstract: In this work, Ag{sub 2}CrO{sub 4} and Ag{sub 2}Cr{sub 2}O{sub 7} nanostructures have been sonochemically prepared using silver salicylate. The effect of preparation parameters on the morphology of the products was investigated by SEM images. Highlights: ? Herein, Ag{sub 2}CrO{sub 4} and Ag{sub 2}Cr{sub 2}O{sub 7} nanostructures have been sonochemically prepared. ? The effect of preparation parameters on the morphology of the products was investigated. ? The photocatalytic activity of the as-prepared Ag{sub 2}CrO{sub 4} nanoparticles was tested. ? XPS spectra indicated the high purity of Ag{sub 2}Cr{sub 2}O{sub 7} nanostructures obtained. - Abstract: In this work, Ag{sub 2}CrO{sub 4} and Ag{sub 2}Cr{sub 2}O{sub 7} nanostructures have been produced via a sonochemical method using silver salicylate as precursor. Besides silver salicylate, Na{sub 2}CrO{sub 4} and (NH{sub 4}){sub 2}Cr{sub 2}O{sub 7} as starting reagents were applied. To investigate the effect of preparation parameters on the morphology and particle size of Ag{sub 2}CrO{sub 4} and Ag{sub 2}Cr{sub 2}O{sub 7}, sonication time, type of surfactant and its concentration were changed. The as-produced nanostructures were characterized by techniques like powder X-ray diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy. The scanning electron micrographs showed that particle-like and rod-like nanostructures of Ag{sub 2}CrO{sub 4} and Ag{sub 2}Cr{sub 2}O{sub 7} were produced using different surfactants. To investigate the catalytic properties of Ag{sub 2}CrO{sub 4} nanoparticles, photooxidation of methyl orange (MO) was performed. According to the obtained results, it was found that the methyl orange degradation was about 87.3% after 280 min irradiation of visible light.

  19. Silver particles improve performance of battery material | Argonne National

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Silver particles improve performance of battery material December 16, 2014 Tweet EmailPrint Researchers at the U.S. Department of Energy's Argonne National Laboratory are working to create an electric car battery that is smaller, cheaper and allows drivers to go farther on a charge. Materials scientist Larry Curtiss is part of an Argonne team working on a new battery architecture that uses lithium-oxygen bonds as it stores and releases energy, and silver as the metal catalyst that

  20. Impact of Environmental Compliance Costs on U.S. Refining Profitability 1995-2001

    Reports and Publications (EIA)

    2003-01-01

    This report assesses the effects of pollution abatement requirements on the financial performance of U.S. petroleum refining and marketing operations during the 1995 to 2001 period. This study is a follow-up to the October 1997 publication entitled The Impact of Environmental Compliance Costs on U.S. Refining Profitability, that focused on the financial impacts of U.S. refining pollution abatement investment requirements in the 1988 to1995 period.

  1. ,"U.S. Sales for Resale, Total Refiner Motor Gasoline Sales Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    Resale, Total Refiner Motor Gasoline Sales Volumes" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ...

  2. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1999 421 Table A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) -...

  3. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1995 467 Table A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) -...

  4. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Petroleum Marketing Annual 1999 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  5. Table 12. U.S. Refiner Reformulated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    retail outlets, e.g., sales to agricultural customers, commercial sales, and industrial sales. Source: Energy Information Administration Form EIA-782A, "Refiners'Gas...

  6. Table A1. Refiner/Reseller Motor Gasoline Prices by Grade, PAD...

    U.S. Energy Information Administration (EIA) Indexed Site

    Information Administration Petroleum Marketing Annual 1995 Table A1. RefinerReseller Motor Gasoline Prices by Grade, PAD District and State, 1984-Present (Cents per Gallon...

  7. Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Information Administration Petroleum Marketing Annual 1995 Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales Type (Cents per Gallon Excluding Taxes) - Continued...

  8. Table A1. Refiner/Reseller Motor Gasoline Prices by Grade, PAD...

    U.S. Energy Information Administration (EIA) Indexed Site

    AdministrationPetroleum Marketing Annual 1999 401 Table A1. RefinerReseller Motor Gasoline Prices by Grade, PAD District and State, 1984-Present (Cents per Gallon...

  9. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Information Administration Petroleum Marketing Annual 1995 Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type (Million Gallons per Day) - Continued Year...

  10. Method for extracting copper, silver and related metals

    DOE Patents [OSTI]

    Moyer, Bruce A.; McDowell, W. J.

    1990-01-01

    A process for selectively extracting precious metals such as silver and gold concurrent with copper extraction from aqueous solutions containing the same. The process utilizes tetrathiamacrocycles and high molecular weight organic acids that exhibit a synergistic relationship when complexing with certain metal ions thereby removing them from ore leach solutions.

  11. Method for extracting copper, silver and related metals

    DOE Patents [OSTI]

    Moyer, B.A.; McDowell, W.J.

    1987-10-23

    A process for selectively extracting precious metals such as silver and gold concurrent with copper extraction from aqueous solutions containing the same. The process utilizes tetrathiamacrocycles and high molecular weight organic acids that exhibit a synergistic relationship when complexing with certain metal ions thereby removing them from ore leach solutions.

  12. The silver bullet myth of sustainable energy savings

    SciTech Connect (OSTI)

    Pasqualetti, Martin J.; Tabbert, Michael K.; Boscamp, Robert L.

    2010-10-15

    Especially in the U.S., people like to think that solving problems just requires finding the proper ''silver bullet.'' Such fixes are not sustainable. Any utility company wanting sustainable long-term savings in personal energy demand requires a more thorough commitment that might be referred to as ''head'' (education), ''heart'' (motivation), and ''hands'' (action). (author)

  13. AGING AND IODINE LOADING OF SILVER-FUNCTIONALIZED AEROGELS

    SciTech Connect (OSTI)

    Bruffey, Stephanie H [ORNL; Jubin, Robert Thomas [ORNL; Anderson, Kaara K [ORNL; Walker Jr, Joseph Franklin [ORNL

    2013-01-01

    Engineered silver-functionalized silica aerogels are being investigated for their application in off-gas treatment at a used nuclear fuel reprocessing facility. Reprocessing will release several key volatile radionuclides, including iodine-129. To achieve regulatory compliance, iodine-129 must be removed from any off-gas stream prior to environmental discharge. Silver-functionalized aerogels have been demonstrated to have high iodine capture capacity, high porosity and potential for conversion into a waste form. Capture materials used in off-gas treatment may be exposed to a heated, high humidity, acidic gas stream for months. Extended exposure to this stream could affect sorbent performance. It was the aim of this study to evaluate what impacts might be observed when Ag0-functionalized aerogels prepared at Pacific Northwest National Laboratory were contacted with a dry air stream for up to 6 months and then used to adsorb iodine from a synthetic off-gas stream. Results demonstrate that there is some loss of iodine capture capacity caused by aging, but that this loss is not as marked as for aging of more traditional iodine sorbents, such as silver-impregnated mordenite. Specifically, aging silver-functionalized aerogel under a dry air stream for up to 6 months can decrease its iodine capacity from 41wt% to 32wt%.

  14. Advances in Patch-Based Adaptive Mesh Refinement Scalability

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gunney, Brian T.N.; Anderson, Robert W.

    2015-12-18

    Patch-based structured adaptive mesh refinement (SAMR) is widely used for high-resolution simu- lations. Combined with modern supercomputers, it could provide simulations of unprecedented size and resolution. A persistent challenge for this com- bination has been managing dynamically adaptive meshes on more and more MPI tasks. The dis- tributed mesh management scheme in SAMRAI has made some progress SAMR scalability, but early al- gorithms still had trouble scaling past the regime of 105 MPI tasks. This work provides two critical SAMR regridding algorithms, which are integrated into that scheme to ensure efficiency of the whole. The clustering algorithm is an extensionmore » of the tile- clustering approach, making it more flexible and efficient in both clustering and parallelism. The partitioner is a new algorithm designed to prevent the network congestion experienced by its prede- cessor. We evaluated performance using weak- and strong-scaling benchmarks designed to be difficult for dynamic adaptivity. Results show good scaling on up to 1.5M cores and 2M MPI tasks. Detailed timing diagnostics suggest scaling would continue well past that.« less

  15. Environmental regulations and changes in petroleum refining operations

    SciTech Connect (OSTI)

    Lidderdale, T.C.M.

    1996-03-01

    The U.S. petroleum industry has responded to four major new federal rules on motor gasoline product quality in the last 6 years: Phase 1 Summer Volatility (Rvp) Regulation, June 1989; Phase 2 Summer Volatility (Rvp) regulation, May 1992; oxygenated Gasoline, November 1992; and reformulated Gasoline Phase I Simple Model, December 1994. These regulations have generated significant changes in domestic refinery operations, affecting marginal production costs and market prices, refinery yields, and the seasonality of production. Some changes have been dramatic. The price of motor gasoline has increased by as much as 60 {cents}/gal due to regulations. Refinery yields of motor gasoline (refinery output of motor gasoline as a fraction of refinery inputs or total refinery output), which historically peaked in the early summer to meet high summer driving demand, now are highest during the winter months. These changes in domestic refining operations are identified and related to the vapor pressure, oxygenated and reformulated gasoline (RFG) product quality regulations. This analysis uses linear regression equations from the Energy Information Administration`s (EIA) Short-Term Integrated Forecasting System (STIFS). The STIFS model is used for producing forecasts appearing in the EIA`s Short-Term Energy Outlook.

  16. Bioremediation of petroleum wastes from the refining of lubricant oils

    SciTech Connect (OSTI)

    Prince, M.; Sambasivam, Y. )

    1993-02-01

    The results of an initial feasibility study on the bioremediation of sludge are presented. The sludge used in the study was taken from a site containing waste produced during the refining of lubricant oils to which sulfuric acid had been added. The effectiveness of bioremediation was examined using shake flask experiments with indigenous and other bacteria sources and nutrient supplementation. The initial results show limited effectiveness of biological treatment at conditions employing indigenous bacteria and low (2%) sludge concentrations in Bushnell-Haas media. In addition, the indigenous bacteria were seen to degrade the polycyclic aromatic hydrocarbons naphthalene, penanthrene and pyrene which are present at some locations at the site. No apparent degradation of material was seen using conditions of high (30%) sludge concentrations in Bushnell-Haas medium under a variety of conditions. In addition, nutrients were rapidly depleted at these sludge concentrations, with the exception of sulfates which were produced when high sludge concentrations were used. 23 refs., 8 figs., 3 tabs.

  17. Advances in Patch-Based Adaptive Mesh Refinement Scalability

    SciTech Connect (OSTI)

    Gunney, Brian T.N.; Anderson, Robert W.

    2015-12-18

    Patch-based structured adaptive mesh refinement (SAMR) is widely used for high-resolution simu- lations. Combined with modern supercomputers, it could provide simulations of unprecedented size and resolution. A persistent challenge for this com- bination has been managing dynamically adaptive meshes on more and more MPI tasks. The dis- tributed mesh management scheme in SAMRAI has made some progress SAMR scalability, but early al- gorithms still had trouble scaling past the regime of 105 MPI tasks. This work provides two critical SAMR regridding algorithms, which are integrated into that scheme to ensure efficiency of the whole. The clustering algorithm is an extension of the tile- clustering approach, making it more flexible and efficient in both clustering and parallelism. The partitioner is a new algorithm designed to prevent the network congestion experienced by its prede- cessor. We evaluated performance using weak- and strong-scaling benchmarks designed to be difficult for dynamic adaptivity. Results show good scaling on up to 1.5M cores and 2M MPI tasks. Detailed timing diagnostics suggest scaling would continue well past that.

  18. Aspects of Western Refining, Inc.'s Proposed Acquisition of Giant Industries, Inc.

    Reports and Publications (EIA)

    2006-01-01

    Presentation of company-level, non-proprietary data and relevant aggregate data for U.S. refinery capacity and gasoline marketing of Western Refining and Giant Industries to inform discussions of Western Refining Inc.'s proposed acquisition of Giant Industries Inc. for a total of $1.5 billion, which was announced August 28, 2006.

  19. ,"No. 2 Diesel Fuel Sales to End Users Refiner Sales Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Refiners (Thousand Gallons per Day)","New Mexico No 2 Diesel Retail Sales by Refiners ...17.9,1773.9,,,781.9,,3446.1,296.5,,,,129.9,2030.1,,,,182.8,,416.2,,60.5,369.8,1495.2,,76.6...

  20. Azine bridged silver coordination polymers: Powder X-ray diffraction route to crystal structure determination of silver benzotriazole

    SciTech Connect (OSTI)

    Rajeswaran, Manju . E-mail: manju.rajeswaran@kodak.com; Blanton, Thomas N.; Giesen, David J.; Whitcomb, David R.; Zumbulyadis, Nicholas; Antalek, Brian J.; Neumann, Marcus M.; Misture, Scott T.

    2006-04-15

    In continuation of our interest in solid-state structures of silver complexes of photographic importance, the structure for silver benzotriazole (AgBZT), has now been obtained. The preferred method for solving crystal structures is via single-crystal X-ray diffraction (XRD). However, for some materials, growing single crystals of appropriate size and quality is often difficult or even impossible. AgBZT is an example of such a silver complex with poor solubility. The usual routes to preparing single crystals using recrystallization from a cooperating solvent resulted in polycrystalline powder samples. We propose a crystal structure for AgBZT, solved from synchrotron X-ray powder diffraction data, using a direct-space Monte Carlo simulated annealing approach. AgBZT crystals are monoclinic (P2{sub 1} /c), with unit cell dimensions, a=14.8052(3) A, b=3.7498(4) A, c=12.3495(12) A, and {beta}=114.200(6){sup o}. The AgBZT complex is constructed from all three of the Benzotriazole (BZT) nitrogens bonding to a separate silver atom. As a consequence of this bonding mode, the structure is a highly cross-linked, coordination polymer.

  1. Impact of oxygenates on petroleum refining, review and forecast

    SciTech Connect (OSTI)

    Unzelman, G.H.

    1995-09-01

    During the coming decade, oxygenates will continue to impact light oil processing and will steadily change the composition of the US gasoline pool. There are several major driving forces that will sustain the gradual influx of oxygen to US gasoline toward the regulatory limits: (1) the positive environmental characteristics of oxygenated compounds, (2) the high-octane quality of ethers that promote elimination of less desirable hydrocarbons and (3) the competitive need for ultra-clean gasoline to compete with alternatives. From 1995 forward, conventional gasoline will gradually shift to RFG (reformulated gasoline) containing a minimum of 2 wt% oxygen and less aromatics. As a result some processing changes, already in motion in the refining industry, will continue. For example, less severe naphtha reforming and cracking innovations to yield more feed for etherification and alkylation. While alternative fuel and vehicle technology will continue to develop, oxygenates in US gasoline will contribute the major alternative dimension to transportation fuel in the foreseeable future. With RFG, internal-combustion engine emissions will be progressively less toxic and lower in photochemical reactivity. The oxygenate mix will favor methyl ethers in spite of the recent methanol price spike. Ethyl ethers will be used on a more limited basis for specific situations where lower volatility and feedstock economics are an advantage. Downstream blending of ethanol will supplement ethers blended at the refinery in situations where economics are more favorable than refinery ethers. Long-range survival of ethanol, as a direct blending agent or feedstock for refinery ethers, depends on one or more of several factors: future crude oil costs, longevity of subsidies and/or mandates, and new production technology based on cellulose yielding ethanol economically competitive with hydrocarbons.

  2. RAM: a Relativistic Adaptive Mesh Refinement Hydrodynamics Code

    SciTech Connect (OSTI)

    Zhang, Wei-Qun; MacFadyen, Andrew I.; /Princeton, Inst. Advanced Study

    2005-06-06

    The authors have developed a new computer code, RAM, to solve the conservative equations of special relativistic hydrodynamics (SRHD) using adaptive mesh refinement (AMR) on parallel computers. They have implemented a characteristic-wise, finite difference, weighted essentially non-oscillatory (WENO) scheme using the full characteristic decomposition of the SRHD equations to achieve fifth-order accuracy in space. For time integration they use the method of lines with a third-order total variation diminishing (TVD) Runge-Kutta scheme. They have also implemented fourth and fifth order Runge-Kutta time integration schemes for comparison. The implementation of AMR and parallelization is based on the FLASH code. RAM is modular and includes the capability to easily swap hydrodynamics solvers, reconstruction methods and physics modules. In addition to WENO they have implemented a finite volume module with the piecewise parabolic method (PPM) for reconstruction and the modified Marquina approximate Riemann solver to work with TVD Runge-Kutta time integration. They examine the difficulty of accurately simulating shear flows in numerical relativistic hydrodynamics codes. They show that under-resolved simulations of simple test problems with transverse velocity components produce incorrect results and demonstrate the ability of RAM to correctly solve these problems. RAM has been tested in one, two and three dimensions and in Cartesian, cylindrical and spherical coordinates. they have demonstrated fifth-order accuracy for WENO in one and two dimensions and performed detailed comparison with other schemes for which they show significantly lower convergence rates. Extensive testing is presented demonstrating the ability of RAM to address challenging open questions in relativistic astrophysics.

  3. User`s guide to EAGLES Version 1.1: An electric- and gasoline-vehicle fuel-efficiency software package

    SciTech Connect (OSTI)

    Marr, W.W.

    1995-01-01

    EAGLES is an interactive microcomputer software package for the analysis of fuel efficiency in electric-vehicle (EV) applications or the estimation of fuel economy for a gasoline vehicle. The principal objective of the EV analysis is to enable the prediction of EV performance on the basis of laboratory test data for batteries. The EV model included in the software package provides a second-by-second simulation of battery voltage and current for any specified vehicle velocity/time or power/time profile. The capability of the battery is modeled by an algorithm that relates the battery voltage to the withdrawn (or charged) current, taking into account the effect of battery depth-of-discharge. Alternatively, the software package can be used to determine the size of the battery needed to satisfy given vehicle mission requirements. For gasoline vehicles, a generic fuel-economy model based on data from EPA Test Car List 1991 is included in the software package. For both types of vehicles, effects of heating/cooling loads on vehicle performance, including range penalty for EVs, can be studied. Also available is an option to estimate the time needed by a specified vehicle to reach a certain speed with the application of a constant power and an option to compute the fraction of time and/or distance in a driving cycle at speeds exceeding a specified value. Certain parameters can be changed interactively prior to a run.

  4. An adaptive mesh-moving and refinement procedure for one-dimensional conservation laws

    SciTech Connect (OSTI)

    Biswas, R.; Flaherty, J.E.; Arney, D.C. Rensselaer Polytech. Inst., Troy, NY Military Acad., West Point, NY )

    1993-01-01

    We examine the performance of an adaptive mesh-moving and /or local mesh refinement procedure for the finite difference solution of one-dimensional hyperbolic systems of conservation laws. Adaptive motion of a base mesh is designed to isolate spatially distinct phenomena, and recursive local refinement of the time step and cells of the stationary or moving base mesh is performed in regions where a refinement indicator exceeds a prescribed tolerance. These adaptive procedures are incorporated into a computer code that includes a MacCormack finite difference scheme wih Davis' artificial viscosity model and a discretization error estimate based on Richardson's extrapolation. Experiments are conducted on three problems in order to qualify the advantages of adaptive techniques relative to uniform mesh computations and the relative benefits of mesh moving and refinement. Key results indicate that local mesh refinement, with and without mesh moving, can provide reliable solutions at much lower computational cost than possible on uniform meshes; that mesh motion can be used to improve the results of uniform mesh solutions for a modest computational effort; that the cost of managing the tree data structure associated with refinement is small; and that a combination of mesh motion and refinement reliably produces solutions for the least cost per unit accuracy.

  5. Super-Joule heating in graphene and silver nanowire network

    SciTech Connect (OSTI)

    Maize, Kerry; Das, Suprem R.; Sadeque, Sajia; Mohammed, Amr M. S.; Shakouri, Ali E-mail: alam@purdue.edu; Janes, David B.; Alam, Muhammad A. E-mail: alam@purdue.edu

    2015-04-06

    Transistors, sensors, and transparent conductors based on randomly assembled nanowire networks rely on multi-component percolation for unique and distinctive applications in flexible electronics, biochemical sensing, and solar cells. While conduction models for 1-D and 1-D/2-D networks have been developed, typically assuming linear electronic transport and self-heating, the model has not been validated by direct high-resolution characterization of coupled electronic pathways and thermal response. In this letter, we show the occurrence of nonlinear super-Joule self-heating at the transport bottlenecks in networks of silver nanowires and silver nanowire/single layer graphene hybrid using high resolution thermoreflectance (TR) imaging. TR images at the microscopic self-heating hotspots within nanowire network and nanowire/graphene hybrid network devices with submicron spatial resolution are used to infer electrical current pathways. The results encourage a fundamental reevaluation of transport models for network-based percolating conductors.

  6. Influence of Aluminum Content on Grain Refinement and Strength of AZ31 Magnesium GTA Weld Metal

    SciTech Connect (OSTI)

    Babu, N. Kishore; Cross, Carl E.

    2012-06-28

    The goal is to characterize the effect of Al content on AZ31 weld metal, the grain size and strength, and examine role of Al on grain refinement. The approach is to systematically vary the aluminum content of AZ31 weld metal, Measure average grain size in weld metal, and Measure cross-weld tensile properties and hardness. Conclusions are that: (1) increased Al content in AZ31 weld metal results in grain refinement Reason: higher undercooling during solidification; (2) weld metal grain refinement resulted in increased strength & hardness Reason: grain boundary strengthening; and (3) weld metal strength can be raised to wrought base metal levels.

  7. Fact #676: May 23, 2011 U.S. Refiners Produce about 19 Gallons of Gasoline

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from a Barrel of Oil | Department of Energy 6: May 23, 2011 U.S. Refiners Produce about 19 Gallons of Gasoline from a Barrel of Oil Fact #676: May 23, 2011 U.S. Refiners Produce about 19 Gallons of Gasoline from a Barrel of Oil A standard U.S. barrel contains 42 gallons of crude oil which yields about 44 gallons of petroleum products. The additional 2 gallons of petroleum products come from refiner gains which result in an additional 6% of product. As shown in the figure below, a little more

  8. Te

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Refineras Refineries Refinera Raffinerie Asphalt ... Usine de valorisation United States Estados Unidos ... Ltd 71 Marathon Petroleum Co LP 106 Silver Eagle ...

  9. Advanced ultraviolet-resistant silver mirrors for use in solar reflectors

    DOE Patents [OSTI]

    Jorgensen, Gary J.; Gee, Randy

    2009-11-03

    A silver mirror construction that maintains a high percentage of hemispherical reflectance throughout the UV and visible spectrum when used in solar reflectors, comprising:a) a pressure sensitive adhesive layer positioned beneath a silver overlay;b) a polymer film disposed on the silver overlay;c) an adhesive layer positioned on the polymer film; andd) a UV screening acrylic film disposed on the adhesive layer.

  10. Aging and iodine loading of silver-functionalized aerogels

    SciTech Connect (OSTI)

    Bruffey, S.H.; Jubin, R.T.; Anderson, K.K.; Walker, J.F.

    2013-07-01

    Engineered silver-functionalized silica aerogels are being investigated for their potential application in off-gas treatment at a used nuclear fuel reprocessing facility. Reprocessing will release several key volatile radionuclides, including iodine-129. To achieve regulatory compliance, iodine-129 must be removed from any off-gas stream prior to environmental discharge. Ag{sup 0}-functionalized aerogels have been demonstrated to have high iodine-capture capacity, high porosity, and potential for conversion into a waste form. Capture materials used in off-gas treatment may be exposed to a heated, high-humidity, acidic gas stream for months. Extended exposure to this stream could affect sorbent performance. It was the aim of this study to evaluate what impacts might be observed when Ag{sup 0}-functionalized aerogels prepared at Pacific Northwest National Laboratory were contacted with a dry air stream for up to 6 months and then used to adsorb iodine from a synthetic off-gas stream. Results demonstrate that there is some loss of iodine-capture capacity caused by aging, but that this loss is not as marked as for aging of more traditional iodine sorbents, such as silver-impregnated mordenite. Specifically, aging silver-functionalized aerogel under a dry air stream for up to 6 months can decrease its iodine capacity from 41 wt% to 32 wt%. (authors)

  11. Electrical studies on silver based fast ion conducting glassy materials

    SciTech Connect (OSTI)

    Rao, B. Appa Kumar, E. Ramesh Kumari, K. Rajani Bhikshamaiah, G.

    2014-04-24

    Among all the available fast ion conductors, silver based glasses exhibit high conductivity. Further, glasses containing silver iodide enhances fast ion conducting behavior at room temperature. Glasses of various compositions of silver based fast ion conductors in the AgI−Ag{sub 2}O−[(1−x)B{sub 2}O{sub 3}−xTeO{sub 2}] (x=0 to1 mol% in steps of 0.2) glassy system have been prepared by melt quenching method. The glassy nature of the compounds has been confirmed by X-ray diffraction. The electrical conductivity (AC) measurements have been carried out in the frequency range of 1 KHz–3MHz by Impedance Analyzer in the temperature range 303–423K. The DC conductivity measurements were also carried out in the temperature range 300–523K. From both AC and DC conductivity studies, it is found that the conductivity increases and activation energy decreases with increasing the concentration of TeO{sub 2} as well as with temperature. The conductivity of the present glass system is found to be of the order of 10{sup −2} S/cm at room temperature. The ionic transport number of these glasses is found to be 0.999 indicating that these glasses can be used as electrolyte in batteries.

  12. Characterization of Dry-Air Aged Granules of Silver-Functionalized...

    Office of Scientific and Technical Information (OSTI)

    Silica Aerogel Matyas, Josef; Fryxell, Glen E.; Robinson, Matthew J. Reprocessing; Silver-functionalized arogel; Radioiodine; Aging; Sorption; BET; SEM; XRD...

  13. Assessment of Methods to Consolidate Iodine-Loaded Silver-Functionaliz...

    Office of Scientific and Technical Information (OSTI)

    Title: Assessment of Methods to Consolidate Iodine-Loaded Silver-Functionalized Silica Aerogel The U.S. Department of Energy is currently investigating alternative sorbents ...

  14. Characterization of Dry-Air Aged Granules of Silver-Functionalized...

    Office of Scientific and Technical Information (OSTI)

    The results showed no impact of aging on the aerogel microstructure or the silver nanoparticles in the aerogel, including their spatial distribution and morphology. Authors: ...

  15. Durable silver mirror with ultra-violet thru far infra-red reflection

    DOE Patents [OSTI]

    Wolfe, Jesse D.

    2010-11-23

    A durable highly reflective silver mirror characterized by high reflectance in a broad spectral range of about 300 nm in the UV to the far infrared (.about.10000 nm), as well as exceptional environmental durability. A high absorptivity metal underlayer is used which prevents the formation of a galvanic cell with a silver layer while increasing the reflectance of the silver layer. Environmentally durable overcoat layers are provided to enhance mechanical and chemical durability and protect the silver layer from corrosion and tarnishing, for use in a wide variety of surroundings or climates, including harsh or extreme environments.

  16. Water Sampling At Silver Peak Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Silver Peak Area (Henkle, Et Al., 2005) Exploration Activity Details...

  17. Mercury Vapor At Silver Peak Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Mercury Vapor At Silver Peak Area (Henkle, Et Al., 2005) Exploration Activity Details...

  18. Thermal Gradient Holes At Silver Peak Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Thermal Gradient Holes At Silver Peak Area (DOE GTP) Exploration Activity Details Location...

  19. Thermal And-Or Near Infrared At Silver Peak Area (DOE GTP) |...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Thermal And-Or Near Infrared At Silver Peak Area (DOE GTP) Exploration Activity Details...

  20. Recovery Act - Refinement of Cross Flow Turbine Airfoils

    SciTech Connect (OSTI)

    McEntee, Jarlath

    2013-08-30

    Ocean Renewable Power Company, LLC (ORPC) is a global leader in hydrokinetic technology and project development. ORPC develops hydrokinetic power systems and eco-conscious projects that harness the power of oceans and rivers to create clean, predictable renewable energy. ORPC’s technology consists of a family of modular hydrokinetic power systems: the TidGen® Power System, for use at shallow to medium-depth tidal sites; the RivGen™ Power System, for use at river and estuary sites; and the OCGen® Power System, presently under development, for use at deep tidal and offshore ocean current sites. These power systems convert kinetic energy in moving water into clean, renewable, grid-compatible electric power. The core technology component for all ORPC power systems is its patented turbine generator unit (TGU). The TGU uses proprietary advanced design cross flow (ADCF) turbines to drive an underwater permanent magnet generator mounted at the TGU’s center. It is a gearless, direct-drive system that has the potential for high reliability, requires no lubricants and releases no toxins that could contaminate the surrounding water. The hydrokinetic industry shows tremendous promise as a means of helping reduce the U.S.’s use of fossil fuels and dependence on foreign oil. To exploit this market opportunity, cross-flow hydrokinetic devices need to advance beyond the pre-commercial state and more systematic data about the structure and function of cross-flow hydrokinetic devices is required. This DOE STTR project, “Recovery Act - Refinement of Cross Flow Turbine Airfoils,” refined the cross-flow turbine design process to improve efficiency and performance and developed turbine manufacturing processes appropriate for volume production. The project proposed (1) to overcome the lack of data by extensively studying the properties of cross flow turbines, a particularly competitive design approach for extracting hydrokinetic energy and (2) to help ORPC mature its pre

  1. Impact of Environmental Compliance Costs on U.S. Refining Profitability

    Reports and Publications (EIA)

    1997-01-01

    Assesses the effects of pollution abatement requirements on the financial performance of U.S. petroleum refining and marketing operations. The analysis draws heavily on financial and operating data from the Energy Information Administration's Financial Reporting System (FRS).

  2. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    NA 26.6 See footnotes at end of table. 14 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type...

  3. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    NA 27.4 See footnotes at end of table. 14 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type...

  4. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    Gasoline and Diesel Fuel Update (EIA)

    - W 73.5 See footnotes at end of table. A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present Energy Information Administration ...

  5. Energy and Environmental Profile of the U.S. Petroleum Refining Industry

    SciTech Connect (OSTI)

    Pellegrino, Joan; Brueske, Sabine; Carole, Tracy; Andres, Howard

    2007-11-01

    This 2007 report provides an overview of the U.S. petroleum refining industry, including new data on market trends and energy and material consumption, as well as information on environmental performance.

  6. Process for solvent refining of coal using a denitrogenated and dephenolated solvent

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA); Schweighardt, Frank K. (Allentown, PA)

    1984-01-01

    A process is disclosed for the solvent refining of non-anthracitic coal at elevated temperatures and pressure in a hydrogen atmosphere using a hydrocarbon solvent which before being recycled in the solvent refining process is subjected to chemical treatment to extract substantially all nitrogenous and phenolic constituents from the solvent so as to improve the conversion of coal and the production of oil in the solvent refining process. The solvent refining process can be either thermal or catalytic. The extraction of nitrogenous compounds can be performed by acid contact such as hydrogen chloride or fluoride treatment, while phenolic extraction can be performed by caustic contact or contact with a mixture of silica and alumina.

  7. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    839.2 135.0 1,251.9 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

  8. Table 9. U.S. Refiner Conventional Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    0.1 18.7 See footnotes at end of table. 18 Energy Information Administration Petroleum Marketing Annual 1995 Table 9. U.S. Refiner Conventional Motor Gasoline Volumes by Grade...

  9. FIA-15-0002 - In the Matter of Alon Refining Krotz Springs, Inc...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Springs, Inc. This Decision concerns an Appeal that Alon Refining Krotz Springs, Inc. ... Energy (DOE) in 10 C.F.R. Part 1004. This Appeal, if granted, would require that the OIR ...

  10. Fact #676: May 23, 2011 U.S. Refiners Produce about 19 Gallons...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A standard U.S. barrel contains 42 gallons of crude oil which yields about 44 gallons of ... and 10 gallons of diesel fuel are produced from a barrel of crudeoil by U.S. refiners. ...

  11. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    U.S. Energy Information Administration (EIA) Indexed Site

    A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) Geographic Area Year No. 1 Distillate No. 2...

  12. Table 13. U.S. Refiner Reformulated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    3.3 3.4 7.9 3.3 W 11.3 See footnotes at end of table. 13. U.S. Refiner Reformulated Motor Gasoline Volumes by Grade and Sales Type 26 Energy Information Administration ...

  13. Table 8. U.S. Refiner Conventional Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    88.4 87.8 80.1 70.0 NA 72.6 See footnotes at end of table. 8. U.S. Refiner Conventional Motor Gasoline Prices by Grade and Sales Type 16 Energy Information Administration ...

  14. Table 9. U.S. Refiner Conventional Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    5.7 5.9 4.4 12.9 NA 17.3 See footnotes at end of table. 9. U.S. Refiner Conventional Motor Gasoline Volumes by Grade and Sales Type 18 Energy Information Administration ...

  15. Table 12. U.S. Refiner Reformulated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    92.8 92.5 84.0 72.5 W 80.7 See footnotes at end of table. 12. U.S. Refiner Reformulated Motor Gasoline Prices by Grade and Sales Type 24 Energy Information Administration ...

  16. Table 8. U.S. Refiner Conventional Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    87.4 86.9 78.3 68.5 W 70.8 See footnotes at end of table. 8. U.S. Refiner Conventional Motor Gasoline Prices by Grade and Sales Type 16 Energy Information Administration ...

  17. Table 12. U.S. Refiner Reformulated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    92.4 92.1 83.7 74.1 W 80.9 See footnotes at end of table. 12. U.S. Refiner Reformulated Motor Gasoline Prices by Grade and Sales Type 24 Energy Information Administration ...

  18. Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    98.0 98.0 86.6 75.0 - 80.1 See footnotes at end of table. 10. U.S. Refiner Oxygenated Motor Gasoline Prices by Grade and Sales Type 20 Energy Information Administration ...

  19. Table 10. U.S. Refiner Oxygenated Motor Gasoline Prices by...

    U.S. Energy Information Administration (EIA) Indexed Site

    94.0 93.9 83.2 73.8 - 79.3 See footnotes at end of table. 10. U.S. Refiner Oxygenated Motor Gasoline Prices by Grade and Sales Type 20 Energy Information Administration ...

  20. Table 13. U.S. Refiner Reformulated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    3.6 3.7 7.9 3.1 W 11.0 See footnotes at end of table. 13. U.S. Refiner Reformulated Motor Gasoline Volumes by Grade and Sales Type 26 Energy Information Administration ...

  1. DOE - Office of Legacy Management -- National Smelting and Refining Co - OH

    Office of Legacy Management (LM)

    20 Smelting and Refining Co - OH 20 FUSRAP Considered Sites Site: NATIONAL SMELTING & REFINING CO. (OH.20) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 6800 Grand Avenue , Cleveland , Ohio OH.20-1 Evaluation Year: 1993 OH.20-2 Site Operations: No indication of other test operations using very limited quantities of slag material. OH.20-1 Site Disposition: Eliminated - Potential for contamination considered remote based upon

  2. Implications of Increasing Light Tight Oil Production for U.S. Refining -

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Information Administration Petroleum & Other Liquids Glossary › FAQS › Overview Data Summary Prices Crude reserves and production Refining and processing Imports/exports & movements Stocks Consumption/sales All petroleum & other liquids data reports Analysis & Projections Major Topics Most popular Consumption & sales Crude reserves & production Imports/exports & movements Prices Projections Recurring Refining & processing Stocks All reports Browse

  3. Petroleum movements and investments in the refining industry: The impact of worldwide environmental regulations

    SciTech Connect (OSTI)

    Guariguata U., G.

    1995-09-01

    Since the enactment of the US Clean Air Act Amendments of 1990, the worldwide refining industry has aligned itself to become increasing attuned to the future well-being of the environment. Refiners must now develop strategies which address careful selection of crude slates, significant increases and changes in product movements, and upgrading of facilities to meet growing demand--in short, strategies which allow them to make substantial increases in capital investments. The objective of this paper is to determine the regional capital investments refiners must make in order to comply with environmental legislation. The methodology in making this determination was founded on a comprehensive analysis of worldwide petroleum supply/demand and distribution patterns for the coming five years, and included evaluation of a set of linear programming (LP) models based on forecasts for regional product demands and projections of regional specifications. The models considered two scenarios, in which either (1) refinery expansion occurs chiefly in the market consuming regions, or (2) crude producers take control of incremental crude volumes and further expand their planned refining projects and the marketing of refined products. The results of these models, coupled with an understanding of geopolitical situations and economic analyses, provided estimates for capital expenditures for the coming decade. In specific, the following issues were addressed, and are discussed in this paper: refined product trade outlook; crude supply; crude quality; shipping; and capital investments.

  4. Influences of impurities on iodine removal efficiency of silver alumina adsorbent

    SciTech Connect (OSTI)

    Fukasawa, Tetsuo; Funabashi, Kiyomi; Kondo, Yoshikazu

    1997-08-01

    Silver impregnated alumina adsorbent (AgA), which was developed for iodine removal from off-gas of nuclear power and reprocessing plants has been tested laying emphasis on investigation of the influences gaseous impurities have on adsorbent chemical stability and iodine removal efficiency. The influences of the major impurities such as nitrogen oxides and water vapor were checked on the chemical state of impregnated silver compound (AgNO{sub 3}) and decontamination factor (DF) value. At 150{degrees}C, a forced air flow with 1.5% nitrogen oxide (NO/NO{sub 2}=1/1) reduced silver nitrate to metallic silver, whereas pure air and air with 1.5% NO{sub 2} had no effect on the chemical state of silver. Metallic silver showed a lower DF value for methyl iodide in pure air (without impurities) than silver nitrate and the lower DF of metallic silver was improved when impurities were added. At 40{degrees}C, a forced air flow with 1.5% nitrogen dioxide (NO{sub 2}) increased the AgA weight by about 20%, which was caused by the adsorption of nitric acid solution on the AgA surface. AgA with l0wt% silver showed higher weight increase than that with 24wt% silver which had lower porosity. Adsorption of acid solution lowered the DF value, which would be due to the hindrance of contact between methyl iodide and silver. The influences of other gaseous impurities were also investigated and AgA showed superior characteristics at high temperatures. 14 refs., 11 figs.

  5. Grain refinement of permanent mold cast copper base alloys. Final report

    SciTech Connect (OSTI)

    Sadayappan, M.; Thomson, J. P.; Elboujdaini, M.; Gu, G. Ping; Sahoo, M.

    2004-04-29

    Grain refinement behavior of copper alloys cast in permanent molds was investigated. This is one of the least studied subjects in copper alloy castings. Grain refinement is not widely practiced for leaded copper alloys cast in sand molds. Aluminum bronzes and high strength yellow brasses, cast in sand and permanent molds, were usually fine grained due to the presence of more than 2% iron. Grain refinement of the most common permanent mold casting alloys, leaded yellow brass and its lead-free replacement EnviroBrass III, is not universally accepted due to the perceived problem of hard spots in finished castings and for the same reason these alloys contain very low amounts of iron. The yellow brasses and Cu-Si alloys are gaining popularity in North America due to their low lead content and amenability for permanent mold casting. These alloys are prone to hot tearing in permanent mold casting. Grain refinement is one of the solutions for reducing this problem. However, to use this technique it is necessary to understand the mechanism of grain refinement and other issues involved in the process. The following issues were studied during this three year project funded by the US Department of Energy and the copper casting industry: (1) Effect of alloying additions on the grain size of Cu-Zn alloys and their interaction with grain refiners; (2) Effect of two grain refining elements, boron and zirconium, on the grain size of four copper alloys, yellow brass, EnviroBrass II, silicon brass and silicon bronze and the duration of their effect (fading); (3) Prediction of grain refinement using cooling curve analysis and use of this method as an on-line quality control tool; (4) Hard spot formation in yellow brass and EnviroBrass due to grain refinement; (5) Corrosion resistance of the grain refined alloys; (6) Transfer the technology to permanent mold casting foundries; It was found that alloying elements such as tin and zinc do not change the grain size of Cu-Zn alloys

  6. Advanced Manufacture of Second-Surface, Silvered Glass Reflectors for High-Performance, Low-Cost CSP Collector Systems

    Broader source: Energy.gov [DOE]

    Advanced Manufacture of Second-Surface, Silvered Glass Reflectors for High-Performance, Low-Cost CSP Collector Systems

  7. Dry method for recycling iodine-loaded silver zeolite

    DOE Patents [OSTI]

    Thomas, Thomas R.; Staples, Bruce A.; Murphy, Llewellyn P.

    1978-05-09

    Fission product iodine is removed from a waste gas stream and stored by passing the gas stream through a bed of silver-exchanged zeolite until the zeolite is loaded with iodine, passing dry hydrogen gas through the bed to remove the iodine and regenerate the bed, and passing the hydrogen stream containing the hydrogen iodide thus formed through a lead-exchanged zeolite which adsorbs the radioactive iodine from the gas stream and permanently storing the lead-exchanged zeolite loaded with radioactive iodine.

  8. Durable silver thin film coating for diffraction gratings

    DOE Patents [OSTI]

    Wolfe, Jesse D.; Britten, Jerald A.; Komashko, Aleksey M.

    2006-05-30

    A durable silver film thin film coated non-planar optical element has been developed to replace Gold as a material for fabricating such devices. Such a coating and resultant optical element has an increased efficiency and is resistant to tarnishing, can be easily stripped and re-deposited without modifying underlying grating structure, improves the throughput and power loading of short pulse compressor designs for ultra-fast laser systems, and can be utilized in variety of optical and spectrophotometric systems, particularly high-end spectrometers that require maximized efficiency.

  9. High pressure melting curves of silver, gold and copper

    SciTech Connect (OSTI)

    Hieu, Ho Khac

    2013-11-15

    In this work, based on the Lindemann's formula of melting and the pressure-dependent Grüneisen parameter, we have investigated the pressure effect on melting temperature of silver, gold and copper metals. The analytical expression of melting temperature as a function of volume compression has been derived. Our results are compared with available experimental data as well as with previous theoretical studies and the good and reasonable agreements are found. We also proposed the potential of this approach on predicting melting of copper at very high pressure.

  10. Silver-bearing, high-temperature, superconducting (HTS) paint

    SciTech Connect (OSTI)

    Ferrando, W.A.

    1990-02-15

    A substantial set of device applications awaits development of a workable, durable, high-temperature superconducting (HTS) paint. Such a paint should be truly superconducting with its critical temperature T sub c>77K. For most of these applications, a high critical current (J sub c) is not required, although probably desirable. A process is described which can be used to produce silver-bearing HTS paint coatings on many engineering materials. Preliminary tests have shown good adherence to several ceramics and the ability to meet the superconducting criteria. Moreover, the coatings withstand multiple thermal cycling and stability under laboratory ambient storage conditions for periods of at least several months.

  11. Green synthesis and characterization of silver nanoparticle using Aloe barbadensis

    SciTech Connect (OSTI)

    Thappily, Praveen E-mail: shiiuvenus@gmail.com; Shiju, K. E-mail: shiiuvenus@gmail.com

    2014-10-15

    Green synthesis of silver nanoparticles was achieved by simple visible light irradiation using aloe barbadensis leaf extract as reducing agent. UV-Vis spectroscopic analysis was used for confirmation of the successful formation of nanoparticles. Investigated the effect of light irradiation time on the light absorption of the nanoparticles. It is observed that upto 25 minutes of light irradiation, the absorption is linearly increasing with time and after that it becomes saturated. Finally, theoretically fitted the time-absorption graph and modeled a relation between them with the help of simulation software.

  12. Need for refining capacity creates opportunities for producers in Middle East

    SciTech Connect (OSTI)

    Ali, M.S.S. )

    1994-07-11

    Oil industry interest in refining has revived in the past few years in response to rising oil consumption. The trend creates opportunities, for countries in the Middle East, which do not own refining assets nearly in proportion to their crude oil reserved. By closing this gap between reserves and refining capacity, the countries can ease some of the instability now characteristic of the oil market. Some major oil producing countries have begun to move downstream. During the 1980s, Venezuela, Kuwait, Saudi Arabia, Libya, and other members of the Organization of Petroleum Exporting Countries acquired refining assets through direct total purchase or joint ventures. Nevertheless, the oil industry remains largely unintegrated, with the Middle East holding two thirds of worldwide oil reserves but only a small share downstream. As worldwide refining capacity swings from a period of surplus toward one in which the need for new capacity will be built. The paper discusses background of the situation, shrinking surplus, investment requirements, sources of capital, and shipping concerns.

  13. An adaptive grid refinement strategy for the simulation of negative streamers

    SciTech Connect (OSTI)

    Montijn, C. . E-mail: carolynne.montijn@cwi.nl; Hundsdorfer, W. . E-mail: willem.hundsdorfer@cwi.nl; Ebert, U. . E-mail: ute.ebert@cwi.nl

    2006-12-10

    The evolution of negative streamers during electric breakdown of a non-attaching gas can be described by a two-fluid model for electrons and positive ions. It consists of continuity equations for the charged particles including drift, diffusion and reaction in the local electric field, coupled to the Poisson equation for the electric potential. The model generates field enhancement and steep propagating ionization fronts at the tip of growing ionized filaments. An adaptive grid refinement method for the simulation of these structures is presented. It uses finite volume spatial discretizations and explicit time stepping, which allows the decoupling of the grids for the continuity equations from those for the Poisson equation. Standard refinement methods in which the refinement criterion is based on local error monitors fail due to the pulled character of the streamer front that propagates into a linearly unstable state. We present a refinement method which deals with all these features. Tests on one-dimensional streamer fronts as well as on three-dimensional streamers with cylindrical symmetry (hence effectively 2D for numerical purposes) are carried out successfully. Results on fine grids are presented, they show that such an adaptive grid method is needed to capture the streamer characteristics well. This refinement strategy enables us to adequately compute negative streamers in pure gases in the parameter regime where a physical instability appears: branching streamers.

  14. Adaptive h -refinement for reduced-order models: ADAPTIVE h -refinement for reduced-order models

    SciTech Connect (OSTI)

    Carlberg, Kevin T.

    2014-11-05

    Our work presents a method to adaptively refine reduced-order models a posteriori without requiring additional full-order-model solves. The technique is analogous to mesh-adaptive h-refinement: it enriches the reduced-basis space online by ‘splitting’ a given basis vector into several vectors with disjoint support. The splitting scheme is defined by a tree structure constructed offline via recursive k-means clustering of the state variables using snapshot data. This method identifies the vectors to split online using a dual-weighted-residual approach that aims to reduce error in an output quantity of interest. The resulting method generates a hierarchy of subspaces online without requiring large-scale operations or full-order-model solves. Furthermore, it enables the reduced-order model to satisfy any prescribed error tolerance regardless of its original fidelity, as a completely refined reduced-order model is mathematically equivalent to the original full-order model. Experiments on a parameterized inviscid Burgers equation highlight the ability of the method to capture phenomena (e.g., moving shocks) not contained in the span of the original reduced basis.

  15. Refining of fossil resin flotation concentrate from western coal. Final report

    SciTech Connect (OSTI)

    Jensen, G.F.; Miller, J.D.

    1995-02-16

    During the past several years, significant research efforts have been made to develop process technology for the selective flotation of fossil resin from western coals. As a result of these efforts, several new flotation technologies have been developed. Operation of a proof-of-concept continuous flotation circuit showed the selective flotation process to be sufficiently profitable to justify the development of a fossil resin industry. However, little attention has been given to the refining of the fossil resin flotation concentrate although solvent refining is a critical step for the fossil resin to become a marketable product. In view of this situation, DOE funded this two-year project to evaluate the following aspects of the fossil resin refining technology: 1) Characterization of the fossil resin flotation concentrate and its refined products; 2) Kinetics of fossil resin extraction; 3) Effects of operating variables on solvent extraction; 4) Extraction solvents; 5) Proof-of-concept continuous refining tests; and 6) Technical and economic analysis. The results from this research effort have led to the following conclusions: Hexane- or heptane-refined fossil resin has a light-yellow color, a melting point of 140 - 142{degrees}C, a density of 1.034 gram/cm, and good solubility in nonpolar solvents. Among the four solvents evaluated (hexane, heptane, toluene and ethyl acetate), hexane is the most appropriate solvent based on overall technical and economic considerations. Batch extraction tests and kinetic studies suggest that the main interaction between the resin and the solvent is expected to be the forces associated with solvation phenomena. Temperature has the most significant effect on extraction rate. With hexane as the solvent, a recovery of 90% cam be achieved at 50{degrees}C and 10% solids concentration with moderate agitation for 1 hour.

  16. Free kick instead of cross-validation in maximum-likelihood refinement of macromolecular crystal structures

    SciTech Connect (OSTI)

    Pranikar, Jure [Institute Joef Stefan, Jamova 39, 1000 Ljubljana (Slovenia); University of Primorska, (Slovenia); Turk, Duan, E-mail: dusan.turk@ijs.si [Institute Joef Stefan, Jamova 39, 1000 Ljubljana (Slovenia); Center of Excellence for Integrated Approaches in Chemistry and Biology of Proteins, (Slovenia)

    2014-12-01

    The maximum-likelihood free-kick target, which calculates model error estimates from the work set and a randomly displaced model, proved superior in the accuracy and consistency of refinement of crystal structures compared with the maximum-likelihood cross-validation target, which calculates error estimates from the test set and the unperturbed model. The refinement of a molecular model is a computational procedure by which the atomic model is fitted to the diffraction data. The commonly used target in the refinement of macromolecular structures is the maximum-likelihood (ML) function, which relies on the assessment of model errors. The current ML functions rely on cross-validation. They utilize phase-error estimates that are calculated from a small fraction of diffraction data, called the test set, that are not used to fit the model. An approach has been developed that uses the work set to calculate the phase-error estimates in the ML refinement from simulating the model errors via the random displacement of atomic coordinates. It is called ML free-kick refinement as it uses the ML formulation of the target function and is based on the idea of freeing the model from the model bias imposed by the chemical energy restraints used in refinement. This approach for the calculation of error estimates is superior to the cross-validation approach: it reduces the phase error and increases the accuracy of molecular models, is more robust, provides clearer maps and may use a smaller portion of data for the test set for the calculation of R{sub free} or may leave it out completely.

  17. New Seismic Model Will Refine Hazard Analysis at U.S. Nuclear Plants |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Seismic Model Will Refine Hazard Analysis at U.S. Nuclear Plants New Seismic Model Will Refine Hazard Analysis at U.S. Nuclear Plants January 31, 2012 - 2:09pm Addthis The Electric Power Research Institute (EPRI), the U.S. Department of Energy (DOE), and the U.S. Nuclear Regulatory Commission (NRC) released a new seismic study today that will help U.S. nuclear facilities in the central and eastern United States reassess seismic hazards. The Central and Eastern United

  18. ,"Aviation Gasoline Sales to End Users Refiner Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    Aviation Gasoline Sales to End Users Refiner Sales Volumes" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Aviation Gasoline Sales to End Users Refiner Sales Volumes",60,"Monthly","6/2016","1/15/1983" ,"Release Date:","9/1/2016" ,"Next Release

  19. ,"U.S. Aviation Gasoline Refiner Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    Aviation Gasoline Refiner Sales Volumes" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Aviation Gasoline Refiner Sales Volumes",2,"Monthly","6/2016","1/15/1983" ,"Release Date:","9/1/2016" ,"Next Release Date:","10/3/2016" ,"Excel File

  20. Implications of Increasing Light Tight Oil Production for U.S. Refining

    U.S. Energy Information Administration (EIA) Indexed Site

    Implications of Increasing Light Tight Oil Production for U.S. Refining May 2015 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 U.S. Energy Information Administration | Implications of Increasing Light Oil Production on the U.S. Refining System i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are

  1. DOE - Office of Legacy Management -- American Smelting and Refining Co - CO

    Office of Legacy Management (LM)

    0-01 Smelting and Refining Co - CO 0-01 FUSRAP Considered Sites Site: American Smelting and Refining Co (CO.0-01 ) Eliminated from consideration under FUSRAP - DOE facility Designated Name: Not Designated Alternate Name: None Location: Grand Junction , Colorado CO.0-01-1 Evaluation Year: 1987 CO.0-01-1 Site Operations: Purchased and assayed ores for AEC at Grand Junction Office, Colorado from 1949-1954. CO.0-01-1 CO.0-01-2 Site Disposition: Eliminated - Operations performed at Grand Junction

  2. Alternate protection concepts for second surface silver/glass solar mirrors

    SciTech Connect (OSTI)

    Buckwalter, C.Q.; Dake, L.S.; Hartman, J.S.; Lind, M.A.

    1980-10-01

    Investigations into three technologies having the potential of significantly enhancing the durability of solar mirrors are reported. The approaches are based on the assumption that sealing the silver layer on second surface mirrors from the external environment with protective overcoats will significantly extend their useful service life. Considered are: (1) edge sealing a second sheet of glass over the silver layer using solder glasses, (2) overcoating the silver layer with liquid applied SiO/sub 2/ or TiO/sub 2/ coatings, and (3) overcoating the silver layer with an electroless nickel film. Preliminary experiments were performed using Sb/sub 2/O/sub 5/-K/sub 2/O and PbO based solder glasses to edge seal a second sheet of glass over the silver mirror surface. Problems encountered in the formulation of the Sb/sub 2/O/sub 5/-K/sub 2/O glasses forced abandonment of these low melting point solder glass experiments. Materials compatibility problems were encountered when using several of the commercially available PbO based solder glasses alternatives. A cursory evaluation of liquid SiO/sub 2/ and TiO/sub 2/ coatings was also undertaken. The films were applied as direct overcoats on both silver only and silver/copper mirror substrates. Although the process appeared to yield visually acceptable coatings, under microscopic examination the films were found to be porous and pinhole riddled after the final curing step. Consequently, they did not stand up well to salt spray and HCl vapor tests. Background data were collected in an investigation of overcoating the silver or silver/copper mirrors with an electroless deposited nickel film. Two formulations, one a basic solution, the other a commercial acidic solution, were attempted. Film integrity problems were encountered for fairly thick films in the feasibility experiments attempted. Nevertheless, the concept appears sound and merits further investigation.

  3. Wetting and Mechanical Performance of Zirconia Brazed with Silver/Copper Oxide and Silver/Vanadium Oxide Alloys

    SciTech Connect (OSTI)

    Sinnamon, Kathleen E.; Meier, Alan; Joshi, Vineet V.

    2014-12-01

    The wetting behavior and mechanical strength of silver/copper oxide and silver/vanadium oxide braze alloys were investigated for both magnesia-stabilized and yttria-stabilized (Mg-PSZ and Y-TZP) transformation toughened zirconia substrates. The temperatures investigated were 1000 to 1100°C, with oxide additions of 1 to 10 weight percent V2O5 or CuO, and hold times of 0.9 to 3.6 ks. Increasing either the isothermal hold temperature or time had a distinctly negative effect on the joint strength. The maximum strengths for both braze alloys were obtained for 5 wt. % oxide additions at 1050°C with a hold time of 0.9 ks. The Mg-PSZ/Ag-CuO system exhibited a average fracture strength of 255 MPa (45% of the reported monolithic strength), and the Y-TZP/Ag-CuO system had an average fracture strength of 540 MPa (30% of the reported monolithic strength). The fracture strengths were lower for the Ag-V2O5 braze alloys, with fracture strengths of approximately 180 MPa (30% of the monolithic strength) for Mg-PSZ versus approximately 160 MPa (10% of the monolithic strength) for Y-TZP. No interfacial products were observed in low magnification SEM analysis for the brazing alloys containing V2O5 additions, while there were interfacial products present for brazes prepared with CuO additions in the braze alloy.

  4. Studies on design of a process for organo-refining of coal to obtain super clean coal

    SciTech Connect (OSTI)

    Sharma, C.S.; Sharma, D.K.

    1999-08-01

    Organo-refining of coal results in refining the coal to obtain super clean coal and residual coal. Super clean coal may be used to obtain value added chemicals, products, and cleaner fuels from coal. In the present work, studies on the design of a semicontinuous process for organo-refining of one ton of coal have been made. The results are reported. This is only a cursory attempt for the design, and further studies may be required for designing this process for use in the development of a scaled-up process of organo-refining of coal.

  5. Synthesis, crystal, and biological activity of a novel carbene silver(I)

    Office of Scientific and Technical Information (OSTI)

    complex with imidazole derivative (Journal Article) | SciTech Connect Synthesis, crystal, and biological activity of a novel carbene silver(I) complex with imidazole derivative Citation Details In-Document Search Title: Synthesis, crystal, and biological activity of a novel carbene silver(I) complex with imidazole derivative Reaction of 2-(1-methyl-1,2-dihydroimidazol-3-yl)acetonitrile tetrafluoroborate with silver oxide in dichloromethane readily yields [Ag(DIM){sub 2}]BF{sub 4}, where DIM

  6. Rocky Mountain area petroleum product availability with reduced PADD IV refining capacity

    SciTech Connect (OSTI)

    Hadder, G.R.; Chin, S.M.

    1994-02-01

    Studies of Rocky Mountain area petroleum product availability with reduced refining capacity in Petroleum Administration for Defense IV (PADD IV, part of the Rocky Mountain area) have been performed with the Oak Ridge National Laboratory Refinery Yield Model, a linear program which has been updated to blend gasolines to satisfy constraints on emissions of nitrogen oxides and winter toxic air pollutants. The studies do not predict refinery closures in PADD IV. Rather, the reduced refining capacities provide an analytical framework for probing the flexibility of petroleum refining and distribution for winter demand conditions in the year 2000. Industry analysts have estimated that, for worst case scenarios, 20 to 35 percent of PADD IV refining capacity could be shut-down as a result of clean air and energy tax legislation. Given these industry projections, the study scenarios provide the following conclusions: The Rocky Mountain area petroleum system would have the capability to satisfy winter product demand with PADD IV refinery capacity shut-downs in the middle of the range of industry projections, but not in the high end of the range of projections. PADD IV crude oil production can be maintained by re-routing crude released from PADD IV refinery demands to satisfy increased crude oil demands in PADDs II (Midwest), III (Gulf Coast), and Washington. Clean Air Act product quality regulations generally do not increase the difficulty of satisfying emissions reduction constraints in the scenarios.

  7. Environmental Regulations and Changes in Petroleum Refining Operations (Released in the STEO June 1998)

    Reports and Publications (EIA)

    1998-01-01

    Changes in domestic refining operations are identified and related to the summer Reid vapor pressure (RVP) restrictions and oxygenate blending requirements. This analysis uses published Energy Information Administration survey data and linear regression equations from the Short-Term Integrated Forecasting System (STIFS). The STIFS model is used for producing forecasts appearing in the Short-Term Energy Outlook.

  8. Tools for macromolecular model building and refinement into electron cryo-microscopy reconstructions

    SciTech Connect (OSTI)

    Brown, Alan; Long, Fei; Nicholls, Robert A.; Toots, Jaan; Emsley, Paul; Murshudov, Garib, E-mail: garib@mrc-lmb.cam.ac.uk [MRC Laboratory of Molecular Biology, Francis Crick Avenue, Cambridge CB2 0QH (United Kingdom)

    2015-01-01

    A description is given of new tools to facilitate model building and refinement into electron cryo-microscopy reconstructions. The recent rapid development of single-particle electron cryo-microscopy (cryo-EM) now allows structures to be solved by this method at resolutions close to 3 . Here, a number of tools to facilitate the interpretation of EM reconstructions with stereochemically reasonable all-atom models are described. The BALBES database has been repurposed as a tool for identifying protein folds from density maps. Modifications to Coot, including new Jiggle Fit and morphing tools and improved handling of nucleic acids, enhance its functionality for interpreting EM maps. REFMAC has been modified for optimal fitting of atomic models into EM maps. As external structural information can enhance the reliability of the derived atomic models, stabilize refinement and reduce overfitting, ProSMART has been extended to generate interatomic distance restraints from nucleic acid reference structures, and a new tool, LIBG, has been developed to generate nucleic acid base-pair and parallel-plane restraints. Furthermore, restraint generation has been integrated with visualization and editing in Coot, and these restraints have been applied to both real-space refinement in Coot and reciprocal-space refinement in REFMAC.

  9. Towards solution and refinement of organic crystal structures by fitting to the atomic pair distribution function

    SciTech Connect (OSTI)

    Prill, Dragica; Juhas, Pavol; Billinge, Simon J. L.; Schmidt, Martin U.

    2016-01-01

    In this study, a method towards the solution and refinement of organic crystal structures by fitting to the atomic pair distribution function (PDF) is developed. Approximate lattice parameters and molecular geometry must be given as input. The molecule is generally treated as a rigid body. The positions and orientations of the molecules inside the unit cell are optimized starting from random values. The PDF is obtained from carefully measured X-ray powder diffraction data. The method resembles `real-space' methods for structure solution from powder data, but works with PDF data instead of the diffraction pattern itself. As such it may be used in situations where the organic compounds are not long-range-ordered, are poorly crystalline, or nanocrystalline. The procedure was applied to solve and refine the crystal structures of quinacridone (β phase), naphthalene and allopurinol. In the case of allopurinol it was even possible to successfully solve and refine the structure in P1 with four independent molecules. As an example of a flexible molecule, the crystal structure of paracetamol was refined using restraints for bond lengths, bond angles and selected torsion angles. In all cases, the resulting structures are in excellent agreement with structures from single-crystal data.

  10. Towards solution and refinement of organic crystal structures by fitting to the atomic pair distribution function

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Prill, Dragica; Juhas, Pavol; Billinge, Simon J. L.; Schmidt, Martin U.

    2016-01-01

    In this study, a method towards the solution and refinement of organic crystal structures by fitting to the atomic pair distribution function (PDF) is developed. Approximate lattice parameters and molecular geometry must be given as input. The molecule is generally treated as a rigid body. The positions and orientations of the molecules inside the unit cell are optimized starting from random values. The PDF is obtained from carefully measured X-ray powder diffraction data. The method resembles `real-space' methods for structure solution from powder data, but works with PDF data instead of the diffraction pattern itself. As such it may bemore » used in situations where the organic compounds are not long-range-ordered, are poorly crystalline, or nanocrystalline. The procedure was applied to solve and refine the crystal structures of quinacridone (β phase), naphthalene and allopurinol. In the case of allopurinol it was even possible to successfully solve and refine the structure in P1 with four independent molecules. As an example of a flexible molecule, the crystal structure of paracetamol was refined using restraints for bond lengths, bond angles and selected torsion angles. In all cases, the resulting structures are in excellent agreement with structures from single-crystal data.« less

  11. EIS-0069: Solvent Refined Coal-II Demonstration Project, Fort Martin, Monongalia County, West Virginia

    Office of Energy Efficiency and Renewable Energy (EERE)

    The U.S. Department of Energy developed this statement to assess the potential environmental, economic and social impacts associated with the construction and short-term operation of a 6,000-tons-per-stream-day-capacity facility that will demonstrate the technical operability, economic viability, and environmental acceptability of the solvent refined coal process at Fort Martin, West Virginia.

  12. Table A1. Refiner/Reseller Motor Gasoline Prices by Grade, PAD...

    U.S. Energy Information Administration (EIA) Indexed Site

    71.6 92.3 78.2 101.8 83.6 87.5 74.7 See footnotes at end of table. A1. RefinerReseller Motor Gasoline Prices by Grade, PAD District, and State, 1984-Present 452 Energy Information...

  13. Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    61.5 67.3 89.8 89.5 82.2 69.4 71.1 74.9 See footnotes at end of table. 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales Type 12 Energy Information Administration ...

  14. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    35.2 213.6 9.5 9.8 12.9 16.6 NA 29.5 See footnotes at end of table. 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type 14 Energy Information Administration ...

  15. Table 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    W 5.6 0.5 0.5 0.5 0.4 - 0.9 See footnotes at end of table. 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by Grade and Sales Type 22 Energy Information Administration ...

  16. Table 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    62.2 68.5 90.1 89.6 82.4 70.9 NA 75.9 See footnotes at end of table. 6. U.S. Refiner Motor Gasoline Prices by Grade and Sales Type 12 Energy Information Administration ...

  17. Table 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    33.9 215.8 9.7 10.0 12.1 16.3 0.0 28.4 See footnotes at end of table. 7. U.S. Refiner Motor Gasoline Volumes by Grade and Sales Type 14 Energy Information Administration ...

  18. Table 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by...

    U.S. Energy Information Administration (EIA) Indexed Site

    - 4.9 0.4 0.4 0.3 0.4 - 0.7 See footnotes at end of table. 11. U.S. Refiner Oxygenated Motor Gasoline Volumes by Grade and Sales Type 22 Energy Information Administration ...

  19. Facile route to hierarchical silver microstructures with high catalytic activity for the reduction of p-nitrophenol

    SciTech Connect (OSTI)

    Gu, Sasa; Wang, Wei Tan, Fatang; Gu, Jian; Qiao, Xueliang; Chen, Jianguo

    2014-01-01

    Graphical abstract: - Highlights: • A facile route was developed to prepare hierarchical silver microstructures. • The shape and size of secondary units can be tailed by varying reaction conditions. • Hierarchical silver microstructures have excellent catalytic activity. • The morphology and crystallinity of silver particles affect the catalytic activity. - Abstract: A facile, cost-effective and environmentally friendly route was developed to synthesize hierarchical silver microstructures consisting of different shaped secondary units through reducing concentrated silver nitrate with ascorbic acid in the absence of any surfactant. The as-obtained samples were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). The investigation on the morphology evolution revealed that the molar ratio of ascorbic acid to silver nitrate was critical to control the shape of secondary structures. The length of plate-like secondary structures which composed hierarchical silver particles could be controlled by changing the reactant concentrations, and it had a key relationship with the catalytic activity for the reduction of p-nitrophenol by NaBH{sub 4}. The catalytic activity of these surfactant-free silver microstructures was about ten times higher than that of silver nanoparticles, and even comparable to that of gold nanoplates, which indicates that the as-obtained silver microstructures are very promising candidates for the catalytic reduction of p-nitrophenol due to the simple synthesis route and high catalytic activity.

  20. Exploiting structure similarity in refinement: automated NCS and target-structure restraints in BUSTER

    SciTech Connect (OSTI)

    Smart, Oliver S. Womack, Thomas O.; Flensburg, Claus; Keller, Peter; Paciorek, Włodek; Sharff, Andrew; Vonrhein, Clemens; Bricogne, Gérard

    2012-04-01

    Local structural similarity restraints (LSSR) provide a novel method for exploiting NCS or structural similarity to an external target structure. Two examples are given where BUSTER re-refinement of PDB entries with LSSR produces marked improvements, enabling further structural features to be modelled. Maximum-likelihood X-ray macromolecular structure refinement in BUSTER has been extended with restraints facilitating the exploitation of structural similarity. The similarity can be between two or more chains within the structure being refined, thus favouring NCS, or to a distinct ‘target’ structure that remains fixed during refinement. The local structural similarity restraints (LSSR) approach considers all distances less than 5.5 Å between pairs of atoms in the chain to be restrained. For each, the difference from the distance between the corresponding atoms in the related chain is found. LSSR applies a restraint penalty on each difference. A functional form that reaches a plateau for large differences is used to avoid the restraints distorting parts of the structure that are not similar. Because LSSR are local, there is no need to separate out domains. Some restraint pruning is still necessary, but this has been automated. LSSR have been available to academic users of BUSTER since 2009 with the easy-to-use -autoncs and @@target target.pdb options. The use of LSSR is illustrated in the re-refinement of PDB entries http://scripts.iucr.org/cgi-bin/cr.cgi?rm, where -target enables the correct ligand-binding structure to be found, and http://scripts.iucr.org/cgi-bin/cr.cgi?rm, where -autoncs contributes to the location of an additional copy of the cyclic peptide ligand.

  1. Efficient incorporation of silver to improve superconducting fibers

    DOE Patents [OSTI]

    Gleixner, Richard A.; LaCount, Dale F.; Finnemore, Douglas K.

    1994-04-26

    An improved method for the efficient incorporation of a metal such as silver in a superconducting material includes blending the metal with a high temperature superconductor or precursor powder and consolidating the same into pellets. The pellets are charged directly into a heating assembly where it is melted and heated sufficiently to a uniform temperature prior to fiberization. Droplets of the melted blend fall through a collar into a nozzle where they are subjected to a high velocity gas to break the melted material into ligaments which solidify into improved flexible fibers having the metal homogeneously dis This invention was made with Government support under a contract with the Department of Energy (DOE) and Ames Laboratory, Contract No. SC-91-225, our reference No. CRD-1272. The Government has certain rights in this invention.

  2. Interactions between silver nanoparticles and polyvinyl alcohol nanofibers

    SciTech Connect (OSTI)

    Chou, H. L.; Wu, C. M.; Lin, F. D.; Rick, J.

    2014-08-15

    The interaction of polyvinylalcohol (PVA) nanofibers with silver (Ag) nanoparticles (mean diameter 8nm) has been modeled using density functional theory (DFT) calculations. The physical adsorption of PVA through the hydroxyl group, to the Ag, and its corresponding molecular orientation was compared with experimental results obtained from surface-enhanced Raman scattering (SERS) studies of the same material. A good agreement was found between the computational model of the vibrational spectrum of the adsorbate and the experimentally observed SERS. In general, aliphatic capping molecules are used to passivate the surface of Ag{sub 55} nanocrystals (55 = atomic number of Ag). In this study, a DFT simulation was employed to show binding energies and electron contour map analyses of Ag{sub 55} with PVA. Here we show that the PVA interacts with the Ag nanoparticle's surface, through the OH group, thereby contributing significantly to the increase in SERS activity.

  3. Precursor composites for oxygen dispersion hardened silver sheathed superconductor composites

    DOE Patents [OSTI]

    Podtburg, Eric R.

    1999-01-01

    An oxide superconductor composite having improved texture and durability. The oxide superconductor composite includes an oxide superconductor phase substantially surrounded with/by a noble metal matrix, the noble metal matrix comprising a metal oxide in an amount effective to form metal oxide domains that increase hardness of the composite. The composite is characterized by a degree of texture at least 10% greater than a comparable oxide superconductor composite lacking metal oxide domains. An oxide superconducting composite may be prepared by oxidizing the precursor composite under conditions effective to form solute metal oxide domains within the silver matrix and to form a precursor oxide in the precursor alloy phase; subjecting the oxidized composite to a softening anneal under conditions effective to relieve stress within the noble metal phase; and converting the oxide precursor into an oxide superconductor.

  4. Precursor composites for oxygen dispersion hardened silver sheathed superconductor composites

    DOE Patents [OSTI]

    Podtburg, E.R.

    1999-06-22

    An oxide superconductor composite having improved texture and durability is disclosed. The oxide superconductor composite includes an oxide superconductor phase substantially surrounded with/by a noble metal matrix, the noble metal matrix comprising a metal oxide in an amount effective to form metal oxide domains that increase hardness of the composite. The composite is characterized by a degree of texture at least 10% greater than a comparable oxide superconductor composite lacking metal oxide domains. An oxide superconducting composite may be prepared by oxidizing the precursor composite under conditions effective to form solute metal oxide domains within the silver matrix and to form a precursor oxide in the precursor alloy phase; subjecting the oxidized composite to a softening anneal under conditions effective to relieve stress within the noble metal phase; and converting the oxide precursor into an oxide superconductor. 1 fig.

  5. Iodine Loading of NO Aged Silver Exchanged Mordenite

    SciTech Connect (OSTI)

    Patton, K. K.; Bruffey, S. H.; Jubin, J. T.; Walker, Jr., J. F.

    2014-09-30

    In an off-gas treatment system for used nuclear fuel processing, a solid sorbent will typically be exposed to a gas stream for months at a time. This gas stream may be at elevated temperature and could contain water vapor, gaseous nitrogen oxides (NO{sub x}), nitric acid vapors, and a variety of other constituents. For this reason, it is important to evaluate the effects of long-term exposure, or aging, on proposed sorbents. Silver exchanged mordenite (AgZ) is being studied at Oak Ridge National Laboratory (ORNL) to determine its iodine sorption capacity after long term exposure to increasingly more complex chemical environments. Studies previously conducted at ORNL investigated the effects of aging reduced silver exchanged mordenite (Ag{sup 0}Z) in dry air, moist air, and NO2. This study investigated the effects of extended exposure to nitric oxide (NO) gas on the iodine capture performance of Ag{sup 0}Z. A deep bed of Ag{sup 0}Z was aged in a 1% nitric oxide (NO) air stream, and portions of the bed were removed at pre-determined intervals. After being removed from the NO stream, each sample was loaded with iodine in a thin bed configuration. These samples were analyzed by neutron activation analysis (NAA) to quantify the iodine content in the sample. Samples were removed at one week and one month. A 78% decrease in sample capacity was seen after one week of exposure, with no further decrease observed after 1 month of aging. The observed loss in capacity is larger in magnitude than previous studies exposing Ag{sup 0}Z to dry air, moist air, or NO2 gas. The aging study was terminated after one month and repeated; this successfully demonstrated the reproducibility of the results.

  6. Infrared laser induced plasma diagnostics of silver target

    SciTech Connect (OSTI)

    Ahmat, L. Nadeem, Ali; Ahmed, I.

    2014-09-15

    In the present work, the optical emission spectra of silver (Ag) plasma have been recorded and analyzed using the laser induced breakdown spectroscopy technique. The emission line intensities and plasma parameters were investigated as a function of lens to sample distance, laser irradiance, and distance from the target surface. The electron number density (n{sub e}) and electron temperature (T{sub e}) were determined using the Stark broadened line profile and Boltzmann plot method, respectively. A gradual increase in the spectral line intensities and the plasma parameters, n{sub e} from 2.89 × 10{sup 17} to 3.92 × 10{sup 17 }cm{sup −3} and T{sub e} from 4662 to 8967 K, was observed as the laser irradiance was increased 2.29 × 10{sup 10}–1.06 × 10{sup 11} W cm{sup −2}. The spatial variations in n{sub e} and T{sub e} were investigated from 0 to 5.25 mm from the target surface, yielding the electron number density from 4.78 × 10{sup 17} to 1.72 × 10{sup 17 }cm{sup −3} and electron temperature as 9869–3789 K. In addition, the emission intensities and the plasma parameters of silver were investigated by varying the ambient pressure from 0.36 to 1000 mbars.

  7. The Present and Future Silver Cost Component in Crystalline Silicon PV Module Manufacturing

    Broader source: Energy.gov [DOE]

    This paper seeks to determine how increased c-Si PV module production might affect future silver demand and prices, as well as the impacts on total c-Si module manufacturing costs. To evaluate how...

  8. NPDES compliance monitoring report: Silver bell mine, Pima County, Arizona. Final report

    SciTech Connect (OSTI)

    Ganter, W.

    1992-10-01

    This presents the findings of a compliance evaluation inspection of the Silver Bell Mine in Pima County, Arizona, conducted on August 19, 1992. It is part of a series of inspections of uncontrolled discharges of mine drainage.

  9. Facile Synthesis of Silver Nanoparticles Under {gamma}-Irradiation: Effect of Chitosan Concentration

    SciTech Connect (OSTI)

    Huang, N. M.; Radiman, S.; Ahmad, A.; Idris, H.; Lim, H. N.; Khiew, P. S.; Chiu, W. S.; Tan, T. K.

    2009-06-01

    In the present study, a biopolymer, low molecular weight chitosan had been utilized as a 'green' stabilizing agent for the synthesis of silver nanoparticles under {gamma}-irradiation. The as-synthesized silver nanoparticles have particle diameters in the range of 5 nm-30 nm depending on the percentage of chitosan used (0.1 wt%, 0.5 wt%, 1.0 wt% and 2.0 wt%). It was found that the yield of the silver nanoparticles was in accordance with the concentration of chitosan presence in the solution due to the reduction by the chitosan radical during irradiation. The highly stable chitosan encapsulated silver nanoparticles were characterized using transmission electron microscopy (TEM), UV-Visible spectrophotometer (UV-VIS) and X-ray diffraction spectroscopy (XRD)

  10. Electroless nickel and ion-plated protective coatings for silvered glass mirrors

    SciTech Connect (OSTI)

    Lind, M.A.; Chaudiere, D.A.; Dake, L.S.; Stewart, T.L.

    1982-04-01

    A preliminary examination of two methods of protecting second surface silvered glass mirrors from environmental degradation is presented. One method employed silver mirrors overcoated with Al, Ni, 304 stainless steel, Cr, or an Al/Cu alloy prepared by ion-plating. The other method used conventional wet process silver mirrors protected with a thin electroless nickel coating. No attempt was made to optimize the coatings for either method. These experimental mirrors were compared with conventional paint backed silver/copper mirrors after exposure to elevated temperatures and water vapor in order to estimate their relative environmental stability. The electroless nickel mirrors showed consistently more resistance to these stresses than either the conventional or ion-plated mirrors, suggesting that they may provide more durable field service.

  11. Testimony of Jonathan Silver, Executive Director Loan Programs Office, U.S.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Before the Subcommittee on Oversight and Investigations Committee on Energy and Commerce U.S. House of Representatives | Department of Energy Testimony of Jonathan Silver, Executive Director Loan Programs Office, U.S. Department of Energy Before the Subcommittee on Oversight and Investigations Committee on Energy and Commerce U.S. House of Representatives Testimony of Jonathan Silver, Executive Director Loan Programs Office, U.S. Department of Energy Before the

  12. Light induced metastable state of silver nitroprusside probed by Raman spectroscopy

    SciTech Connect (OSTI)

    Ghalsasi, Pallavi; Ghalsasi, Prasanna; Thomas, A.; Muthu, D. V. S.; Sood, A. K.

    2015-06-24

    Low temperature Raman spectroscopic measurements on silver nitroprusside (AgNP), Ag{sub 2}[Fe(CN){sub 5}NO] powders display reversible features of a partially converted metastable state. The results are compared with similarly observed metastable state in case of sodium nitroprusside (NaNP) and the differences have been discussed in terms of possible resistance to metastable state formation offered by silver atoms on the basis of hard soft acid base (HSAB) theory.

  13. X-ray Study Reveals How Silver-to-Silicon Contacts Form for Solar Cells |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stanford Synchrotron Radiation Lightsource X-ray Study Reveals How Silver-to-Silicon Contacts Form for Solar Cells Saturday, April 30, 2016 Solar energy must be one of the primary energy sources as society transitions away from predominantly fossil fuels based economy. Currently, the overwhelming majority (>90%) of the photovoltaic (PV) market consists of silicon solar cells. While relatively inexpensive, this technology depends predominately on a screen-printed silver electrical

  14. Substrate decomposition in galvanic displacement reaction: Contrast between gold and silver nanoparticle formation

    SciTech Connect (OSTI)

    Ghosh, Tapas; Satpati, Biswarup

    2015-06-24

    We have investigated substrate decomposition during formation of silver and gold nanoparticles in galvanic displacement reaction on germanium surfaces. Silver and gold nanoparticles were synthesized by electroless deposition on sputter coated germanium thin film (∼ 200 nm) grown initially on silicon substrate. The nanoparticles formation and the substrate corrosion were studied using scanning transmission electron microscopy (STEM) and the energy dispersive X-ray (EDX) spectroscopy.

  15. Earning SEP Silver Certification Leads MedImmune to Significant Savings |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Technical Assistance » Superior Energy Performance » Earning SEP Silver Certification Leads MedImmune to Significant Savings Earning SEP Silver Certification Leads MedImmune to Significant Savings August 4, 2016 - 3:44pm Addthis A recently published case study demonstrates the value that Superior Energy Performance® (SEP(tm)) offers companies in the biopharmaceutical sector. The case study features MedImmune, a global biologics research and development arm of

  16. An investigation into the use of chitosan for the removal of soluble silver from industrial wastewater

    SciTech Connect (OSTI)

    Lasko, C.L.; Hurst, M.P.

    1999-10-15

    Chitosan was examined as a means of removing soluble silver from industrial waste streams. Stirred-batch and column methods were used to remove free (hydrated) silver ion as well as the ammonia, thiocyanate, thiosulfate, and cyanide complexes of silver in simulated wastewater at an initial concentration of 50 ppm and in a pH range of 2--10. An actual sample of X-ray film development rinse water was also tested. Batch method results show 80--95% silver bound at pH 4--8 for Ag{sup +} and Ag(NH{sub 3}){sub 2}{sup +}, while 92% and 75% of Ag(S{sub 2}O{sub 3}){sub 2}{sup 2{minus}}, and Ag(SCN){sub 3}{sup 2{minus}}, respectively, were bound at pH 2. Using a column containing 0.500 g of chitosan, 160 bed volumes of Ag{sup +}, 875 bed volumes of Ag(NH{sub 3}){sub 2}{sup +}, 715 bed volumes of Ag(S{sub 2}O{sub 3}){sub 2}{sup 3{minus}}, and 190 bed volumes of Ag(SCN){sub 3}{sup 2{minus}} solution were treated before silver ion concentration in the effluent reached 5 ppm. Chitosan did not significantly bind Ag(CN){sub 2}{sup {minus}} at any pH tested. Chitosan treated 450 bed volumes of 40 ppm X-ray rinse water before effluent silver concentration reached 5 ppm. Capacity experiment results using the column method indicated 42 mg of silver bound per gram of chitosan. Four commercial resins, Amberlite IRA-67, IRA 458, IRC-718, and Duolite GT-73, were also tested as silver binding agents.

  17. Assessment of Methods to Consolidate Iodine-Loaded Silver-Functionalized

    Office of Scientific and Technical Information (OSTI)

    Silica Aerogel (Technical Report) | SciTech Connect Technical Report: Assessment of Methods to Consolidate Iodine-Loaded Silver-Functionalized Silica Aerogel Citation Details In-Document Search Title: Assessment of Methods to Consolidate Iodine-Loaded Silver-Functionalized Silica Aerogel The U.S. Department of Energy is currently investigating alternative sorbents for the removal and immobilization of radioiodine from the gas streams in a nuclear fuel reprocessing plant. One of these new

  18. Screen printed silver top electrode for efficient inverted organic solar cells

    SciTech Connect (OSTI)

    Kim, Junwoo; Duraisamy, Navaneethan; Lee, Taik-Min; Kim, Inyoung; Choi, Kyung-Hyun

    2015-10-15

    Highlights: • Screen printing of silver pattern. • X-ray diffraction pattern confirmed the face centered cubic structure of silver. • Uniform surface morphology of silver pattern with sheet resistance of 0.06 Ω/sq. • The power conversion efficiency of fabricated solar cell is found to be 2.58%. - Abstract: The present work is mainly focused on replacement of the vacuum process for top electrode fabrication in organic solar cells. Silver top electrode deposited through solution based screen printing on pre-deposited polymeric thin film. The solution based printing technology provides uniform top electrode without damaging the underlying organic layers. The surface crystallinity and surface morphology of silver top electrode are examined through X-ray diffraction, field-emission scanning electron microscope and atomic force microscope. The purity of silver is examined through X-ray energy dispersive spectroscopy. The top electrode exhibits face centered cubic structure with homogeneous morphology. The sheet resistance of top electrode is found to be 0.06 Ω/sq and an average pattern thickness of ∼15 μm. The power conversion efficiency is 2.58%. Our work demonstrates that the solution based screen printing is a significant role in the replacement of vacuum process for the fabrication of top electrode in organic solar cells.

  19. Magnetite and magnetite/silver core/shell nanoparticles with diluted magnet-like behavior

    SciTech Connect (OSTI)

    Garza-Navarro, Marco; Gonzalez, Virgilio; Ortiz, Ubaldo; De la Rosa, Elder

    2010-01-15

    In the present work is reported the use of the biopolymer chitosan as template for the preparation of magnetite and magnetite/silver core/shell nanoparticles systems, following a two step procedure of magnetite nanoparticles in situ precipitation and subsequent silver ions reduction. The crystalline and morphological characteristics of both magnetite and magnetite/silver core/shell nanoparticles systems were analyzed by high resolution transmission electron microscopy (HRTEM) and nanobeam diffraction patterns (NBD). The results of these studies corroborate the core/shell morphology and the crystalline structure of the magnetite core and the silver shell. Moreover, magnetization temperature dependent, M(T), measurements show an unusual diluted magnetic behavior attributed to the dilution of the magnetic ordering in the magnetite and magnetite/silver core/shell nanoparticles systems. - Graphical abstract: Biopolymer chitosan was used as stabilization media to synthesize both magnetite and magnetite/silver core/shell nanoparticles. Results of HRTEM and NBD patterns confirm core/shell morphology of the obtained nanoparticles. It was found that the composites show diluted magnet-like behavior.

  20. The effects of air pollution regulations on the US refining industry. Task 3

    SciTech Connect (OSTI)

    Not Available

    1989-06-01

    Numerous air pollution regulations affecting petroleum refineries recently have been promulgated, have been proposed, or are under consideration at the federal, state, and local level. As shown in Figure ES-1, all of these environmental regulations are intended to take effect over the relatively short time period from 1989 through 1995. In the aggregate these regulatory activities have significant implications for the US refining industry and the Nation, including: Major investment requirements; changes in industry profitability; potential closure of some refineries; and potential changes in crude oil or product import dependence. At issue is whether the cumulative effect of these regulations could so adversely affect the US refining industry that US national security would be affected. In addition to the regulations outlined in Figure ES-1, President Bush recently presented a major new plan to improve the nation`s air quality. The aspects of the President`s plan that could strongly affect US refineries are summarized below.

  1. Profiling of selenium removal in hydrogen ambient zone-refined tellurium bar using RF-GDOES

    SciTech Connect (OSTI)

    Anil, G. . E-mail: anilpillai_99@yahoo.com; Reddy, M.R.P.; Prasad, D.S.; Ali, S.T.; Munirathnam, N.R.; Prakash, T.L.

    2007-01-15

    Ultrapure tellurium (Te) metal has become an important metal in the strategic sector for fabricating high performance infrared devices for thermal imaging and night vision cameras. Zone refining (ZR) is a proven technique for purification of Te. Selenium (Se), present as an impurity in Te, is not easily removed by ZR under normal conditions as the segregation coefficient (K) is around 0.44-0.50. Hence, ZR was performed in a hydrogen atmosphere, during which Se gets converted to hydrogen selenide at the molten moving zones and carried away into the sodium hydroxide scrubbers. In this study a radio-frequency glow discharge optical emission spectrometer (RF-GDOES) was used for determining the concentration of Se along the 56 cm Te zone-refined bar. It was observed that the initial concentration of 1100 ppb Se was decreased to 30 ppb after 2 cycles.

  2. Report to the Congress on the storage of refined petroleum products and on regional supply interruptions

    SciTech Connect (OSTI)

    Not Available

    1991-06-01

    This report describes petroleum and petroleum products storage and supply disruption. Information is presented under the following topics: Historical Perspective; Current Patterns of Supply and Disposition of Petroleum Products in the Primary Distribution System; PADD I Clean Products Supply/Demand; 1990 Regional Petroleum Reserve Annual Computation; Market Infrastructure and Commercial Practices in the California Motor Gasoline Market, as Related to Potential Refined Petroleum Product Reserve Structures and Sales Procedures; Infrastructure and Commercial Practices in the Northeast Distillate Market, as Related to Potential Refined Petroleum Product Reserve Structures and Sales Procedures; Storage Stability Characteristics of Petroleum Products and Crude Oil; Effect of 1990 Clean Air Act Amendments on Demand for Petroleum Product Storage Capacity; and Environmental Regulations on Tanks.

  3. Application of a catalyst deactivation model for hydrotreating solvent refined coal feedstocks

    SciTech Connect (OSTI)

    Nalitham, R.V.

    1983-10-01

    A simple kinetic model, including a first-order catalyst deactivation rate, is applied to upgrading of coal-derived feedstocks prepared from two solvent refined coal fractions. A catalyst deactivation mechanism is proposed which involves the adsorption and surface reaction of coke precursors on catalytic active sites. The effect of feedstock composition, temperature and pressure on kinetic parameters, and in particular the catalyst deactivation rate, is determined.

  4. Grain refinement of cast zinc through magnesium inoculation: Characterisation and mechanism

    SciTech Connect (OSTI)

    Liu, Zhilin; Qiu, Dong; Wang, Feng; Taylor, John A.; Zhang, Mingxing

    2015-08-15

    It was previously found that peritectic-forming solutes are more favourable for the grain refinement of cast Al alloys than eutectic-forming solutes. In this work, we report that the eutectic-forming solute, Mg, can also significantly grain refine cast Zn. Differential thermal analysis (DTA) of a Zn–Mg alloy, in which efficient grain refinement occurred, evidenced an unexpected peak that appeared before the nucleation of η-Zn grains on the DTA spectrum. Based on extensive examination using X-ray diffraction, high resolution SEM and EDS, it was found that: (a) some faceted Zn–Mg intermetallic particles were reproducibly observed; (b) the particles were located at or near grain centres; (c) the atomic ratio of Mg to Zn in the intermetallic compound was determined to be around 1/2. Using tilting selected area diffraction (SAD) and convergent beam Kikuchi line diffraction pattern (CBKLDP) techniques, these faceted particles were identified as MgZn{sub 2} and an orientation relationship between such grain-centred MgZn{sub 2} particles and the η-Zn matrix was determined. Hence, the unexpected peak on the DTA spectrum is believed to correspond to the formation of MgZn{sub 2} particles, which act as effective heterogeneous nucleation sites in the alloy. Together with the effect of Mg solute on restricting grain growth, such heterogeneous nucleation is cooperatively responsible for the grain size reduction in Zn–Mg alloys. - Highlights: • A new eutectic-based grain refiner for the cast Zn was found. • The formation process of an intermetallic compound (MgZn{sub 2}) was characterised. • MgZn{sub 2} can act as potent heterogeneous nucleation sites above the liquidus. • A new OR between MgZn{sub 2} and η-Zn was determined using the CBKLDP technique.

  5. Refined BCF-type boundary conditions for mesoscale surface step dynamics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, Renjie; Ackerman, David M.; Evans, James W.

    2015-06-24

    Deposition on a vicinal surface with alternating rough and smooth steps is described by a solid-on-solid model with anisotropic interactions. Kinetic Monte Carlo (KMC) simulations of the model reveal step pairing in the absence of any additional step attachment barriers. We explore the description of this behavior within an analytic Burton-Cabrera-Frank (BCF)-type step dynamics treatment. Without attachment barriers, conventional kinetic coefficients for the rough and smooth steps are identical, as are the predicted step velocities for a vicinal surface with equal terrace widths. However, we determine refined kinetic coefficients from a two-dimensional discrete deposition-diffusion equation formalism which accounts for stepmore » structure. These coefficients are generally higher for rough steps than for smooth steps, reflecting a higher propensity for capture of diffusing terrace adatoms due to a higher kink density. Such refined coefficients also depend on the local environment of the step and can even become negative (corresponding to net detachment despite an excess adatom density) for a smooth step in close proximity to a rough step. Incorporation of these refined kinetic coefficients into a BCF-type step dynamics treatment recovers quantitatively the mesoscale step-pairing behavior observed in the KMC simulations.« less

  6. Source category survey: secondary copper smelting and refining industry. Final report Oct 79-Jan 80

    SciTech Connect (OSTI)

    Snyder, M.K.; Shobe, F.D.

    1980-05-01

    This report presents the results of a survey of the secondary copper smelting and refining industry to determine the probable impact of the development of new source performance standards under Section 111 of the Clean Air Act. The surveyed industry processes copper scrap to produce pure copper or copper alloy, other than brass and bronze. Secondary copper foundries, which melt and cast high-quality copper scrap without refining it, are excluded. Primary copper smelters and refiners, which produce copper from ore, are also excluded, although they also process copper scrap. Process, emissions, and economic data were gathered by literature searches, contacts with representatives of the industry, trade associations, federal government agencies, and state and local air pollution control agencies, and visits to two plants. The industry's production processes, actual and allowable air emissions, and emission control systems are described. State and local emission regulations are compared. Production and capacity are projected to 1989 and the impact of new source performance standards is assessed.

  7. Refined BCF-type boundary conditions for mesoscale surface step dynamics

    SciTech Connect (OSTI)

    Zhao, Renjie; Ackerman, David M.; Evans, James W.

    2015-06-24

    Deposition on a vicinal surface with alternating rough and smooth steps is described by a solid-on-solid model with anisotropic interactions. Kinetic Monte Carlo (KMC) simulations of the model reveal step pairing in the absence of any additional step attachment barriers. We explore the description of this behavior within an analytic Burton-Cabrera-Frank (BCF)-type step dynamics treatment. Without attachment barriers, conventional kinetic coefficients for the rough and smooth steps are identical, as are the predicted step velocities for a vicinal surface with equal terrace widths. However, we determine refined kinetic coefficients from a two-dimensional discrete deposition-diffusion equation formalism which accounts for step structure. These coefficients are generally higher for rough steps than for smooth steps, reflecting a higher propensity for capture of diffusing terrace adatoms due to a higher kink density. Such refined coefficients also depend on the local environment of the step and can even become negative (corresponding to net detachment despite an excess adatom density) for a smooth step in close proximity to a rough step. Incorporation of these refined kinetic coefficients into a BCF-type step dynamics treatment recovers quantitatively the mesoscale step-pairing behavior observed in the KMC simulations.

  8. Aging of Iodine-Loaded Silver Mordenite in NO2

    SciTech Connect (OSTI)

    Bruffey, Stephanie H.; Jubin, Robert Thomas; Patton, Kaara K.; Walker Jr, Joseph Franklin

    2014-04-01

    Used nuclear fuel facilities need to control and minimize radioactive emissions. Off-gas systems are designed to remove radioactive contaminants, such as 85Kr, 14C, 3H, and 129I. In an off-gas system, any capture material will be exposed to a gas stream for months at a time. This gas stream may be at elevated temperature and could contain water, NOx gas, or a variety of other constituents comprising the dissolver off-gas stream in a nuclear fuel reprocessing plant. For this reason, it is important to evaluate the effects of long-term exposure, or aging, on proposed capture materials. One material under consideration is reduced silver mordenite (Ag0Z), which is recognized for its efficient iodine capture properties. Iodine is immobilized on Ag0Z as AgI, a solid with low volatility (m.p. ≥ 500°C). The aim of this study was to determine whether extended aging at elevated temperature in a nominally 2% NO2 environment would result in a loss of immobilized iodine from this material due to either physical or chemical changes that might occur during aging. Charges of iodine-loaded reduced silver mordenite (I2-Ag0Z) were exposed to a 2% NO2 environment for 1, 2, 3, and 4 months at 150°C, then analyzed for iodine losses The aging study was completed successfully. The material did not visibly change color or form. The results demonstrate that no significant iodine loss was observed over the course of 4 months of 2% NO2 aging of I2-Ag0Z at elevated temperature within the margin of error and the variability (~10%) in the loading along the beds. This provides assurance that iodine will remain immobilized on Ag0Z during extended online use in an off-gas capture treatment system. Future tests should expose I2-Ag0Z to progressively more complex feed gases in an effort to accurately replicate the conditions expected in a reprocessing facility.

  9. Re-refinement from deposited X-ray data can deliver improved models for most PDB entries

    SciTech Connect (OSTI)

    Joosten, Robbie P.; Womack, Thomas; Vriend, Gert; Bricogne, Gérard

    2009-02-01

    An evaluation of validation and real-space intervention possibilities for improving existing automated (re-)refinement methods. The deposition of X-ray data along with the customary structural models defining PDB entries makes it possible to apply large-scale re-refinement protocols to these entries, thus giving users the benefit of improvements in X-ray methods that have occurred since the structure was deposited. Automated gradient refinement is an effective method to achieve this goal, but real-space intervention is most often required in order to adequately address problems detected by structure-validation software. In order to improve the existing protocol, automated re-refinement was combined with structure validation and difference-density peak analysis to produce a catalogue of problems in PDB entries that are amenable to automatic correction. It is shown that re-refinement can be effective in producing improvements, which are often associated with the systematic use of the TLS parameterization of B factors, even for relatively new and high-resolution PDB entries, while the accompanying manual or semi-manual map analysis and fitting steps show good prospects for eventual automation. It is proposed that the potential for simultaneous improvements in methods and in re-refinement results be further encouraged by broadening the scope of depositions to include refinement metadata and ultimately primary rather than reduced X-ray data.

  10. Optical properties and plasmonic response of silver-gallium nanostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lereu, Aude; Lemarchand, F.; Zerrad, M.; Yazdanpanah, M.; Passian, Ali

    2015-02-12

    Silver and gallium form an alloy Ag2Ga via a room temperature spontaneous self-assembly that exhibits remarkable mechanical and electrical properties [1] suitable for nanoscale measurements [2]. However, whether photon excitation of plasmons in this emerging nanomaterial is retained or not has not been established. Here, we present a thin lm formation of Ag2Ga via a spreading- reactive process of liquid Ga on an Ag lm and a characterization of its dielectric function (E) = 1(E) - i 2(E) in the photon energy range 1.42 eV E <4.2 eV. It is observed that while the plasmon damping increases, near an energymore » of 3.4 eV, the real part of exhibits a crossing with respect to that of Ag. Furthermore, the impact of new plasmon supporting materials [3] is discussed and in order to enable further applications in plasmonics, the possibility of photon excitation of surface plasmons in Ag2Ga is studied.« less

  11. Rapid Responding Palladium-Silver Surface Modified Microsensor for Hydrogen

    SciTech Connect (OSTI)

    Patton, James; Hunter, Scott Robert; Sepaniak, Michael; Datskos, Panos G; Smith, Barton

    2010-01-01

    Most palladium thin film based hydrogen gas sensors have response and recovery times that are too long to make them useful in vehicular and stationary gas leak detection applications. In contrast, a palladium-silver thin film based microcantilever (MC) hydrogen gas microsensor is reported herein with near ideal response characteristics for use in these hydrogen economy related applications. Specifically, 3-10 second response and recovery times have been measured for these sensors in contrast to previous sensor response measurements of several to tens of minutes using Pd thin film and MC based sensing techniques. The much reduced response times observed in the present study are attributed to a wet chemical Pd-Ag thin film deposition technique and a gas conditioning protocol that produces a highly nanostructured, porous film that rapidly adsorbs and desorbs H2, allowing rapid equilibration with the H2 concentration in the surrounding air. The wet chemical process and gas phase conditioning offer a novel approach at creating highly structured surfaces that have not been reported for MC devices. Additionally, these sensors have very low H2 detection thresholds, wide dynamic range and very good selectivity relative to common interferents.

  12. Modeling silver binding to gills of rainbow trout (Oncorhynchus mykiss)

    SciTech Connect (OSTI)

    Janes, N.; Playle, R.C.

    1995-11-01

    Rainbow trout (Oncorhynchus mykiss, 1--3 g) were exposed to {approximately} 1.0 {micro}M silver (Ag) ({approximately} 11 {micro}g {center_dot} L{sup {minus}1} Ag) for 2 to 3 h in synthetic soft water (Ca, Na {approximately} 300 {micro}M, pH 6.5--7.5) to which was added Ca, Na, H{sup +}, dissolved organic carbon (DOC), Cl, or thiosulfate (S{sub 2}O{sub 3}). Gills were extracted and gill Ag concentrations were measured using graphite-furnace atomic absorption spectrophotometry. The concentration of cations (Ca, Na, H{sup +}) and complexing agents (DOC, Cl, S{sub 2}O{sub 3}) needed to keep Ag off the gills were used to calculate conditional equilibrium binding constants (K) at the gills. Log K for Ag-gill binding was 10.0, with approximately 1.3 nmol Ag binding sites per fish. All experimentally determined log K values were entered into an aquatic chemistry equilibrium model, MINEQL{sup +}, to predict Ag binding at trout gills. For a series of natural waters, model-predicted gill Ag concentrations correlated well with observed gill Ag concentrations, with one exception, very hard city of Waterloo tapwater. This exception may indicate a kinetic constraint on the thermodynamic basis of the model.

  13. Deep Bed Adsorption Testing using Silver-Functionalized Aerogel

    SciTech Connect (OSTI)

    Nick Soelberg; Tony Watson

    2012-06-01

    Nuclear fission results in the production of fission products and activation products, some of which tend to be volatile during used fuel reprocessing and evolve in gaseous species into the reprocessing facility off-gas systems. Analyses have shown that I129, due to its radioactivity, high potential mobility in the environment, and high longevity (half life of 15.7 million years), can require control efficiencies of up to 1,000x or higher to meet regulatory emission limits. Two Aerogel sorption tests that have been performed this fiscal year. The maximum iodine decontamination factor (DF) was measured to be over 10,000, above the 1,000-10,000 target DF range. The mass transfer zone may be as short as 0.5 inches under the sorption conditions of the first test. Only a small fraction of the iodine sorbed on Bed 1 was desorbed during the purge periods. The silver-functionalized Aerogel appears to have potential to be a very effective and efficient iodine sorbent.

  14. Method for the recovery of silver from waste photographic fixer solutions

    DOE Patents [OSTI]

    Posey, Franz A.; Palko, Aloysius A.

    1984-01-01

    The method of the present invention is directed to the recovery of silver from spent photographic fixer solutions and for providing an effluent essentially silver-free that is suitable for discharge into commercial sewage systems. The present method involves the steps of introducing the spent photographic fixer solution into an alkaline hypochlorite solution. The oxidizing conditions of the alkaline hypochlorite solution are maintained during the addition of the fixer solution so that the silver ion complexing agents of thiosulfate and sulfite ions are effectively destroyed. Hydrazine monohydrate is then added to the oxidizing solution to form a reducing solution to effect the formation of a precipitate of silver which can be readily removed by filtration or decanting. Experimental tests indicate that greater than 99.99% of the original silver in the spent photographic fixer can be efficiently removed by practicing the present method. Also, the chemical and biological oxygen demand of the remaining effluent is significantly reduced so as to permit the discharge thereof into sewage systems at levels in compliance with federal and state environmental standards.

  15. Method for the recovery of silver from waste photographic fixer solutions

    DOE Patents [OSTI]

    Posey, F.A.; Palko, A.A.

    The method of the present invention is directed to the recovery of silver from spent photographic fixer solutions and for providing an effluent essentially silver-free that is suitable for discharge into commercial sewage systems. The present method involves the steps of introducing the spent photographic fixer solution into an alkaline hypochlorite solution. The oxidizing conditions of the alkaline hypochlorite solution are maintained during the addition of the fixer solution so that the silver ion complexing agents of thiosulfate and sulfite ions are effectively destroyed. Hydrazine monohydrate is then added to the oxidizing solution to form a reducing solution to effect the formation of a precipitate of silver which can be readily removed by filtration of decanting. Experimental tests indicate that greater than 99.99% of the original silver in the spent photographic fixer can be efficiently removed by practicing the present method. Also, the chemical and biological oxygen demand of the remaining effluent is significantly reduced so as to permit the discharge thereof into sewage systems at levels in compliance with federal and state environmental standards.

  16. Silver ion mediated shape control of platinum nanoparticles: Removal of silver by selective etching leads to increased catalytic activity

    SciTech Connect (OSTI)

    Grass, Michael E.; Yue, Yao; Habas, Susan E.; Rioux, Robert M.; Teall, Chelsea I.; Somorjai, G.A.

    2008-01-09

    A procedure has been developed for the selective etching of Ag from Pt nanoparticles of well-defined shape, resulting in the formation of elementally-pure Pt cubes, cuboctahedra, or octahedra, with a largest vertex-to-vertex distance of {approx}9.5 nm from Ag-modified Pt nanoparticles. A nitric acid etching process was applied Pt nanoparticles supported on mesoporous silica, as well as nanoparticles dispersed in aqueous solution. The characterization of the silica-supported particles by XRD, TEM, and N{sub 2} adsorption measurements demonstrated that the structure of the nanoparticles and the mesoporous support remained conserved during etching in concentrated nitric acid. Both elemental analysis and ethylene hydrogenation indicated etching of Ag is only effective when [HNO{sub 3}] {ge} 7 M; below this concentration, the removal of Ag is only {approx}10%. Ethylene hydrogenation activity increased by four orders of magnitude after the etching of Pt octahedra that contained the highest fraction of silver. High-resolution transmission electron microscopy of the unsupported particles after etching demonstrated that etching does not alter the surface structure of the Pt nanoparticles. High [HNO{sub 3}] led to the decomposition of the capping agent, polyvinylpyrollidone (PVP); infrared spectroscopy confirmed that many decomposition products were present on the surface during etching, including carbon monoxide.

  17. Steam system opportunity assessment for the pulp and paper, chemical manufacturing, and petroleum refining industries: Main report

    SciTech Connect (OSTI)

    None, None

    2002-10-01

    This report assesses steam generation and use in the pulp and paper, chemical, and petroleum refining industries, and estimates the potential for energy savings from implementation of steam system performance and efficiency improvements.

  18. Studies of n-butane conversion over silica-supported platinum, platinum-silver and platinum-copper catalysts

    SciTech Connect (OSTI)

    Gu, Junhua

    1992-06-09

    The present work was undertaken to elucidate effect of adding silver and copper to silica-supported platinum catalyst on the activity and selectivity in the n-butane reactions. At the conditions of this study n-butane underwent both hydrogenolysis and structural isomerization. The catalytic activity and selectivities between hydrogenolysis and isomerization and within hydrogenolysis were measured at temperature varying from 330 C to 370 C. For platinum-silver catalysts, at lower temperatures studied the catalytic activity per surface platinum atom (turnover frequency) remained constant at lower silver content (between 0 at. % and 30 at. %) and decreased with further increased silver loading, suggesting that low- index planes could be dominant in the hydrogenolysis of n-butane. Moreover, increasing silver content resulted in an enhancement of the selectivity of isomerization products relative to hydrogenolysis products. At the higher temperature studied, no suppression in catalytic activity was observed. It is postulated that surface structure could change due to the mobility of surface silver atoms, leading to surface silver atoms forming islands or going to the bulk, and leaving large portions of basal planes exposed with active platinum atoms. It is also suggested that the presence of inert silver atoms results in weakening of the H-surface bond. This results in increased mobility of hydrogen atoms on the surface and hence, higher reactivity with other adsorbed species. For platinum copper catalysts, the mixed ensembles could play an active role in the hydrogenolysis of n-butane.

  19. Evaluation of tropical channel refinement using MPAS-A aquaplanet simulations

    SciTech Connect (OSTI)

    Martini, Matus N.; Gustafson, Jr., William I.; O'Brien, Travis A.; Ma, Po -Lun

    2015-09-13

    Climate models with variable-resolution grids offer a computationally less expensive way to provide more detailed information at regional scales and increased accuracy for processes that cannot be resolved by a coarser grid. This study uses the Model for Prediction Across Scales–Atmosphere (MPAS22A), consisting of a nonhydrostatic dynamical core and a subset of Advanced Research Weather Research and Forecasting (ARW-WRF) model atmospheric physics that have been modified to include the Community Atmosphere Model version 5 (CAM5) cloud fraction parameterization, to investigate the potential benefits of using increased resolution in an tropical channel. The simulations are performed with an idealized aquaplanet configuration using two quasi-uniform grids, with 30 km and 240 km grid spacing, and two variable-resolution grids spanning the same grid spacing range; one with a narrow (20°S–20°N) and one with a wide (30°S–30°N) tropical channel refinement. Results show that increasing resolution in the tropics impacts both the tropical and extratropical circulation. Compared to the quasi-uniform coarse grid, the narrow-channel simulation exhibits stronger updrafts in the Ferrel cell as well as in the middle of the upward branch of the Hadley cell. The wider tropical channel has a closer correspondence to the 30 km quasi-uniform simulation. However, the total atmospheric poleward energy transports are similar in all simulations. The largest differences are in the low-level cloudiness. The refined channel simulations show improved tropical and extratropical precipitation relative to the global 240 km simulation when compared to the global 30 km simulation. All simulations have a single ITCZ. Furthermore, the relatively small differences in mean global and tropical precipitation rates among the simulations are a promising result, and the evidence points to the tropical channel being an effective method for avoiding the extraneous numerical artifacts seen in earlier

  20. Evaluation of Tropical Channel Refinement using MPAS-A Aquaplanet Simulations

    SciTech Connect (OSTI)

    Martini, Matus; Gustafson, William I.; O'Brien, Travis A.; Ma, Po-Lun

    2015-09-13

    Climate models with variable-resolution grids offer a computationally less expensive way to provide more detailed information at regional scales and increased accuracy for processes that cannot be resolved by a coarser grid. This study uses the Model for Prediction Across Scales–Atmosphere (MPAS22A), consisting of a nonhydrostatic dynamical core and a subset of Advanced Research Weather Research and Forecasting (ARW-WRF) model atmospheric physics that have been modified to include the Community Atmosphere Model version 5 (CAM5) cloud fraction parameterization, to investigate the potential benefits of using increased resolution in an tropical channel. The simulations are performed with an idealized aquaplanet configuration using two quasi-uniform grids, with 30 km and 240 km grid spacing, and two variable-resolution grids spanning the same grid spacing range; one with a narrow (20°S–20°N) and one with a wide (30°S–30°N) tropical channel refinement. Results show that increasing resolution in the tropics impacts both the tropical and extratropical circulation. Compared to the quasi-uniform coarse grid, the narrow-channel simulation exhibits stronger updrafts in the Ferrel cell as well as in the middle of the upward branch of the Hadley cell. The wider tropical channel has a closer correspondence to the 30 km quasi-uniform simulation. However, the total atmospheric poleward energy transports are similar in all simulations. The largest differences are in the low-level cloudiness. The refined channel simulations show improved tropical and extratropical precipitation relative to the global 240 km simulation when compared to the global 30 km simulation. All simulations have a single ITCZ. The relatively small differences in mean global and tropical precipitation rates among the simulations are a promising result, and the evidence points to the tropical channel being an effective method for avoiding the extraneous numerical artifacts seen in earlier studies that

  1. Direct Reduction of Waste through Refining of DOE Metal Assets - 13632

    SciTech Connect (OSTI)

    Hargett, Michael C.; Terekhov, Dimitri; Khozan, Kamran M.

    2013-07-01

    CVMR{sup R} presents a technology for refining nickel from the enrichment barrier materials of the DOE that is proven through 100 years of use by the metals industry. CVMR{sup R} applies modern controls, instrumentation for process and monitoring of the system, and innovative production methods to produce a wide spectrum of products that generate new technology applications and improvements to our society and economy. CVMR{sup R} will receive barrier materials as a secure operation and size reduce the metal to a shred that is fed to a carbonylation reactor where nickel is reacted with carbon monoxide and generate nickel carbonyl. The carbonyl will be filtered and decomposed with heat to form a variety of products that include high value nano powders, coated substrates, net shapes and pure nickel. The residue from the reactor will retain radionuclides from enrichment activities. The carbon monoxide will only react and extract nickel under the operating conditions to leave volumetric contamination in the unreacted residue. A demonstration plant was designed and built by CVMR{sup R} and operated by BWXT, to demonstrate the systems capabilities to DOE in 2006. A pilot plant operation precedes the detailed design of the nickel refinery and provides essential data for design, safe work practices, waste characterizations and system kinetics and confirms the project feasibility. CVMR{sup R} produces nickel products that are cleaner than the nickel in U.S. commerce and used by industry today. The CVMR{sup R} process and systems for nickel refining is well suited for DOE materials and will provide value through environmental stewardship, recovery of high value assets, and support of the DOE environmental remediation programs as the refined nickel generates additional long term benefits to local communities. (authors)

  2. Fabrication and characterization of silver- and copper-coated Nylon 6 forcespun nanofibers by thermal evaporation

    SciTech Connect (OSTI)

    Mihut, Dorina M. Lozano, Karen; Foltz, Heinrich

    2014-11-01

    Silver and copper nanoparticles were deposited as thin films onto substrates consisting of Nylon 6 nanofibers manufactured using forcespinning{sup ®} equipment. Different rotational speeds were used to obtain continuous nanofibers of various diameters arranged as nonwoven mats. The Nylon 6 nanofibers were collected as successive layers on frames, and a high-vacuum thermal evaporation method was used to deposit the silver and copper thin films on the nanofibers. The structures were investigated using scanning electron microscopy–scanning transmission electron microscopy, atomic force microscopy, x-ray diffraction, and electrical resistance measurements. The results indicate that evaporated silver and copper nanoparticles were successfully deposited on Nylon 6 nanofibers as thin films that adhered well to the polymer substrate while the native morphology of the nanofibers were preserved, and electrically conductive nanostructures were achieved.

  3. Localized surface plasmon and exciton interaction in silver-coated cadmium sulphide quantum dots

    SciTech Connect (OSTI)

    Ghosh, P.; Rustagi, K. C.; Vasa, P.; Singh, B. P.

    2015-05-15

    Localized surface plasmon and exciton coupling has been investigated on colloidal solutions of silver-coated CdS nanoparticles (NPs), synthesized by gamma irradiation. Two broad photoluminescence (PL) bands (blue/red) corresponding to band to band and defect state transitions have been observed for the bare and coated samples. In case of bare CdS NPs, the intensity of the red PL peak is about ten times higher than the blue PL peak intensity. However, on coating the CdS NPs with silver, the peak intensity of the blue PL band gets enhanced and becomes equal to that of the red PL band. High-resolution transmission electron microscopic (HRTEM) images adequately demonstrate size distribution of these metal/semiconductor nanocomposites. UV-Vis absorption studies show quantum confinement effect in these semiconductor quantum dot (SQD) systems. Absorption spectrum of silver-coated SQDs shows signature of surface plasmon-exciton coupling which has been theoretically verified.

  4. Method of bonding silver to glass and mirrors produced according to this method

    DOE Patents [OSTI]

    Pitts, J.R.; Thomas, T.M.; Czanderna, A.W.

    1984-07-31

    A method for adhering silver to a glass substrate for producing mirrors includes attaining a silicon enriched substrate surface by reducing the oxygen therein in a vacuum and then vacuum depositing a silver layer onto the silicon enriched surface. The silicon enrichment can be attained by electron beam bombardment, ion beam bombardment, or neutral beam bombardment. It can also be attained by depositing a metal, such as aluminum, on the substrate surface, allowing the metal to oxidize by pulling oxygen from the substrate surface, thereby leaving a silicon enriched surface, and then etching or eroding the metal oxide layer away to expose the silicon enriched surface. Ultraviolet rays can be used to maintain dangling silicon bonds on the enriched surface until covalent bonding with the silver can occur. This disclosure also includes encapsulated mirrors with diffusion layers built therein. One of these mirrors is assembled on a polymer substrate.

  5. Method of bonding silver to glass and mirrors produced according to this method

    DOE Patents [OSTI]

    Pitts, John R.; Thomas, Terence M.; Czanderna, Alvin W.

    1985-01-01

    A method for adhering silver to a glass substrate for producing mirrors includes attaining a silicon enriched substrate surface by reducing the oxygen therein in a vacuum and then vacuum depositing a silver layer onto the silicon enriched surface. The silicon enrichment can be attained by electron beam bombardment, ion beam bombardment, or neutral beam bombardment. It can also be attained by depositing a metal, such as aluminum, on the substrate surface, allowing the metal to oxidize by pulling oxygen from the substrate surface, thereby leaving a silicon enriched surface, and then etching or eroding the metal oxide layer away to expose the silicon enriched surface. Ultraviolet rays can be used to maintain dangling silicon bonds on the enriched surface until covalent bonding with the silver can occur. This disclosure also includes encapsulated mirrors with diffusion layers built therein. One of these mirrors is assembled on a polymer substrate.

  6. Cavitation erosion of silver plated coating at different temperatures and pressures

    SciTech Connect (OSTI)

    Hattori, Shuji; Motoi, Yoshihiro; Kikuta, Kengo; Tomaru, Hiroshi

    2014-04-11

    Cavitation often occurs in inducer pumps used for space rockets. Silver plated coating on the inducer liner faces the damage of cavitation. Therefore, it is important to study about the cavitation erosion resistance for silver plated coating at several operating conditions in the inducer pumps. In this study, the cavitation erosion tests were carried for silver plated coating in deionized water and ethanol at several liquid temperatures (273K400K) and pressures (0.10MPa0.48MPa). The mass loss rate is evaluated in terms of thermodynamic parameter ? proposed by Brennen [9], suppression pressure pp{sub v} (p{sub v}: saturated vapor pressure) and acoustic impedance ?c (?: density and c: sound speed). Cavitation bubble behaviors depending on the thermodynamic effect and the liquid type were observed by high speed video camera. The mass loss rate is formulated by thermodynamic parameter ?, suppression pressure pp{sub v} and acoustic impedance ?c.

  7. Structural distortions in 5-10 nm silver nanoparticles under high pressure

    SciTech Connect (OSTI)

    Koski, Kristie J.; Kamp, Noelle M.; Kunz, Martin; Knight, Jason K.; Alivisatos, A.P.; Smith, R.K.

    2008-10-13

    We present experimental evidence that silver nanoparticles in the size range of 5-10 nm undergo a reversible structural transformation under hydrostatic pressures up to 10 GPa. We have used x-ray diffraction with a synchrotron light source to investigate pressure-dependent and size-dependent trends in the crystal structure of silver nanoparticles in a hydrostatic medium compressed in a diamond-anvil cell. Results suggest a reversible linear pressure-dependent rhombohedral distortion which has not been previously observed in bulk silver. We propose a mechanism for this transition that considers the bond-length distribution in idealized multiply twinned icosahedral particles. To further support this hypothesis, we also show that similar measurements of single-crystal platinum nanoparticles reveal no such distortions.

  8. Spectroscopic evidence for Ag(III) in highly oxidized silver films by x-ray photoelectron spectroscopy

    SciTech Connect (OSTI)

    Kaspar, Tiffany C.; Droubay, Timothy C.; Chambers, Scott A.; Bagus, Paul S.

    2010-12-16

    In situ x-ray photoelectron spectroscopy (XPS) was utilized to identify the chemical state of silver in a range of silver oxide thin films obtained by co-deposition of silver and atomic oxygen. A highly oxidized silver species was observed at an unexpectedly low Ag 3d5/2 binding energy (BE) of 366.8 eV with an associated broad satellite at 368.2 eV; this species was assigned as Ag(III). It was found to be highly unstable in vacuum, but could be regenerated by further exposure to atomic oxygen. Both BE shifts and intensity changes of the O 1s peak were found to correlate with changes in the silver oxidation state. Theoretical calculations of the expected XPS of high spin Ag(III) provide insight into the significance of satellite structure and shake features in the Ag 3d spectra.

  9. Table 3a. Imported Refiner Acquisition Cost of Crude Oil, Projected vs. Actual

    U.S. Energy Information Administration (EIA) Indexed Site

    a. Imported Refiner Acquisition Cost of Crude Oil, Projected vs. Actual" "Projected Price in Constant Dollars" " (constant dollars per barrel in ""dollar year"" specific to each AEO)" ,"AEO $ Year",1993,1994,1995,1996,1997,1998,1999,2000,2001,2002,2003,2004,2005,2006,2007,2008,2009,2010,2011,2012,2013 "AEO 1994",1992,16.69,16.42999,16.9899,17.66,18.28,19.0599,19.89,20.72,21.65,22.61,23.51,24.29,24.9,25.6,26.3,27,27.64,28.16

  10. Bandwidth Study on Energy Use and Potential Energy Savings Opportunities in U.S. Petroleum Refining

    SciTech Connect (OSTI)

    Sabine Brueske, Caroline Kramer, Aaron Fisher

    2015-06-01

    Energy bandwidth studies of U.S. manufacturing sectors can serve as foundational references in framing the range (or bandwidth) of potential energy savings opportunities. This bandwidth study examines energy consumption and potential energy savings opportunities in U.S. petroleum refining. The study relies on multiple sources to estimate the energy used in nine individual process areas, representing 68% of sector-wide energy consumption. Energy savings opportunities for individual processes are based on technologies currently in use or under development; these potential savings are then extrapolated to estimate sector-wide energy savings opportunity.

  11. Methods of refining and producing dibasic esters and acids from natural oil feedstocks

    DOE Patents [OSTI]

    Snead, Thomas E.; Cohen, Steven A.; Gildon, Demond L.

    2016-03-15

    Methods are provided for refining natural oil feedstocks and producing dibasic esters and/or dibasic acids. The methods comprise reacting a terminal olefin with an internal olefin in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In certain embodiments, the olefin esters are formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having olefin esters.

  12. ,"U.S. Refiner Acquisition Cost of Crude Oil"

    U.S. Energy Information Administration (EIA) Indexed Site

    Acquisition Cost of Crude Oil" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Refiner Acquisition Cost of Crude Oil",3,"Monthly","7/2016","1/15/1974" ,"Release Date:","9/1/2016" ,"Next Release Date:","10/3/2016" ,"Excel File

  13. MX-2500 thermal processor for the treatment of petroleum refining wastes and contaminated soils

    SciTech Connect (OSTI)

    Swanberg, C. )

    1993-05-01

    Separation and Recovery Systems, Inc. (SRS) of Irvine, California is the market leader in supplying hazardous waste and secondary material dewatering and drying services to the petroleum refining industry. In late 1991, SRS introduced the new generation of dryer technology, the MX-2500. The MX-2500 is an electrically heated dryer system that recovers virtually all of the hydrocarbon value of refinery wastes and secondary materials, while producing a solid residue meeting EPA Land Disposal Restriction (LDR) treatment levels which allows the refinery to land dispose of the solids, thereby realizing two objectives: waste minimization and oil recovery/recycling. 2 figs., 3 tabs.

  14. Managing process innovation through incremental improvements: Empirical evidence in the petroleum refining industry

    SciTech Connect (OSTI)

    Yin, J.Z.

    1994-11-01

    This paper developed a present value index (PVI) model to offer a new solution to differing the effects of radical innovation and incremental improvement. After comparing the return from an initial-radical-process innovation and the return from the incremental changes in petroleum refining processes, it was found that incremental improvements generated higher returns than from its initial innovations. The findings suggest that, in contrast to a conventional research and development (R&D) strategy with a focus on state-of-art innovations, manufacturing companies should place sufficient emphasis on incremental capital and operating improvements to fully exploit economic benefits from an innovation. 49 refs., 3 tabs.

  15. Refinement of overlapping local/global iteration method based on Monte Carlo/p-CMFD calculations

    SciTech Connect (OSTI)

    Jo, Y.; Yun, S.; Cho, N. Z.

    2013-07-01

    In this paper, the overlapping local/global (OLG) iteration method based on Monte Carlo/p-CMFD calculations is refined in two aspects. One is the consistent use of estimators to generate homogenized scattering cross sections. Another is that the incident or exiting angular interval is divided into multi-angular bins to modulate albedo boundary conditions for local problems. Numerical tests show that, compared to the one angle bin case in a previous study, the four angle bin case shows significantly improved results. (authors)

  16. Methods of refining and producing dibasic esters and acids from natural oil feedstocks

    DOE Patents [OSTI]

    Snead, Thomas E; Cohen, Steven A; Gildon, Demond L

    2015-04-07

    Methods are provided for refining natural oil feedstocks and producing dibasic esters and/or dibasic acids. The methods comprise reacting a terminal olefin with an internal olefin in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In certain embodiments, the olefin esters are formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having olefin esters.

  17. European refiners must seek creative processes to justify heavy-ends projects

    SciTech Connect (OSTI)

    Hunt, P.

    1996-12-09

    There are strong reasons for wanting to upgrade the bottom of the crude oil barrel. But European refiners will not find it easy to get approval and funding for major capital investment projects. In most cases, investment justification will have to be creative and may need to rely on factors traditionally considered to be outside the conventional refinery fence. Examples of such creative upgrading schemes are those employed in four gasification projects planned for refineries in Italy. It is clear that the major obstacles to heavy residue processing are not technical, but economic. A review of these obstacles will set the stage for European investment in bottom-of-the-barrel processing.

  18. Quantitative phase analysis of Mg:ZrO{sub 2} nanoparticles by Rietveld refinement method

    SciTech Connect (OSTI)

    Balaji, V. Senthilkumaran, S. Thangadurai, P.

    2014-04-24

    To quantify the structural phases of nanocrystalline ZrO{sub 2} doped with Mg ions of varying concentrations (3, 5, 10, 15 and 20%) and annealed at different temperatures. Magnesia doped zirconia was prepared by chemical co-precipitation method and annealed up to 1000°C. The monoclinic and tetragonal phases present in Mg:ZrO{sub 2} were quantified using Rietveld refinement analysis of the X-ray diffraction data and compared with the Direct method based on peak intensity calculations. Tetragonal phase was dominant in the 600°C annealed Mg:ZrO{sub 2} for all Mg concentrations.

  19. TOPO-capped silver selenide nanoparticles and their incorporation into polymer nanofibers using electrospinning technique

    SciTech Connect (OSTI)

    More, D.S.; Moloto, M.J.; Moloto, N.; Matabola, K.P.

    2015-05-15

    Highlights: • Ag{sub 2}Se nanoparticles produced spherical particles with sizes 12 nm (180 °C) and 27 nm (200 °C). • Higher temperature produced increased particle size (∼75 nm) and changed in shape. • Ag{sub 2}Se nanoparticles (0.2–0.6%) added into PVP (35–45%) to yield reduced fiber beading. • Polymer nanofibers electrospun at 11–20 kV produced fiber diameters of 425–461 nm. • Optical properties in the fibers were observed due to the Ag{sub 2}Se nanoparticles loaded. - Abstract: Electrospinning is the most common technique for fabricating polymer fibers as well as nanoparticles embedded polymer fibers. Silver selenide nanoparticles were synthesized using tri-n-octylphosphine (TOP) as solvent and tri-n-octylphosphine oxide (TOPO) as capping environment. Silver selenide was prepared by reacting silver nitrate and selenium with tri-n-octylphosphine (TOP) to form TOP–Ag and TOP–Se solutions. Both absorption and emission spectra signify the formation of nanoparticles as well as the TEM which revealed spherical particles with an average particle size of 22 nm. The polymer, PVP used was prepared at concentrations ranging from (35 to 45 wt%) and the TOPO-capped silver selenide nanoparticles (0.2 and 0.6 wt%) were incorporated into them and electrospun by varying the voltage from 11 to 20 kV. The SEM images of the Ag{sub 2}Se/PVP composite fibers revealed the fibers of diameters with average values of 425 and 461 nm. The X-ray diffraction results show peaks which were identified due to α-Ag{sub 2}Se body centered cubic compound. The sharp peak observed for all the samples at 2θ = 44.5 suggest the presence of Ag in the face centered cubic which can be attributed to higher concentration of silver nitrate used with molar ratio of selenium to silver and the abundance of silver in the silver selenide crystal. Fourier transform infrared spectroscopy, thermogravimetric analysis (TGA) and ultraviolet–visible spectroscopy were used to characterize the

  20. EERE Success Story-From Silver to Copper: SunShot Awardee TetraSun's

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology to be Mass Produced | Department of Energy From Silver to Copper: SunShot Awardee TetraSun's Technology to be Mass Produced EERE Success Story-From Silver to Copper: SunShot Awardee TetraSun's Technology to be Mass Produced June 17, 2015 - 9:42am Addthis First Solar acquired TetraSun and its unique crystalline silicon solar cell technology, which will soon begin mass production. First Solar acquired TetraSun and its unique crystalline silicon solar cell technology, which will soon

  1. Characterization of Dry-Air Aged Granules of Silver-Functionalized Silica

    Office of Scientific and Technical Information (OSTI)

    Aerogel (Technical Report) | SciTech Connect Characterization of Dry-Air Aged Granules of Silver-Functionalized Silica Aerogel Citation Details In-Document Search Title: Characterization of Dry-Air Aged Granules of Silver-Functionalized Silica Aerogel This is a letter report to complete level 3 milestone "Assess aging characteristics of silica aerogels" for DOE FCRD program. Recently, samples of Ag0-functionalized silica aerogel were aged in flowing dry air for up to 6 months and

  2. Decontamination of metals by melt refining/slagging: First year progress report

    SciTech Connect (OSTI)

    Mizia, R.E.; Worcester, S.A.; Twidwell, L.G.; Paolini, D.J.; Weldon, T.A.

    1994-03-01

    As the number of nuclear installations undergoing decontamination and decommissioning (D&D) increases, current radioactive waste storage space is consumed and establishment of new waste storage areas becomes increasingly difficult. The problem of handling and storing radioactive scrap metal (RSM) gains increasing importance in the DOE Environmental Restoration and Waste Management Program. To alleviate present and future waste storage problems, Westinghouse Idaho Nuclear Company (WINCO) is managing a program for the recycling of RSM for beneficial use within the DOE complex. As part of that effort, Montana Tech has been awarded a contract to help optimize melting and refining technologies for the recycling of stainless steel RSM. The scope of the Montana Tech program includes a literature survey, a decontaminating slag design study, small scale melting studies to determine optimum slag compositions for removal of radioactive contaminant surrogates, analysis of preferred melting techniques, and coordination of pilot scale melting demonstrations (100-500 lbs) to be conducted at selected commercial facilities. This program will identify methods that can be used to recycle stainless steel RSM which will be used to fabricate high and low level waste canisters for the Idaho Waste Immobilization Facility. This report summarizes the results of an extensive literature review and the first year`s progress on slag design, small-scale melt refining of surrogate-containing stainless steel (presently only a three month effort), and pilot-scale preparation of surrogate master ingots.

  3. Projected refined product balances in key Latin American countries: A preliminary examination

    SciTech Connect (OSTI)

    1996-06-01

    Over the years, the East-West Center (EWC) has developed considerable expertise in refinery modeling, especially in the area of forecasting product balances for countries, given planned capacity changes, changes in product demand, changes in crude slates, and changes in product specifications. This expertise has been applied on an ongoing basis to the major refiners in the Middle East and the Asia-Pacific region, along with the US West Coast as region in its own right. Refinery modeling in these three areas has been ongoing for nearly 15 years at the Center, and the tools and information sources are now well developed. To date, the EWC has not applied these tools to Latin America. Although research on Latin America has been an ongoing area of concern at the Center in recent years, the information gathered to date is still not of the level of detail nor quality available for other areas. The modeling efforts undertaken in this report are of a ``baseline`` nature, designed to outline the major issues, attempt a first cut at emerging product balances, and, above all, to elicit commentary from those directly involved in the oil industry in the key countries modeled. Our experience in other regions has shown that it takes a few years dialogue with refiners and government planner in individual countries to develop a reliable database, as well as the insights into operational constraints and practices that make accurate modeling possible. This report is no more than a first step down the road.

  4. Conformation-dependent backbone geometry restraints set a new standard for protein crystallographic refinement

    SciTech Connect (OSTI)

    Moriarty, Nigel W.; Tronrud, Dale E.; Adams, Paul D.; Karplus, P. Andrew

    2014-06-17

    Ideal values of bond angles and lengths used as external restraints are crucial for the successful refinement of protein crystal structures at all but the highest of resolutions. The restraints in common usage today have been designed based on the assumption that each type of bond or angle has a single ideal value independent of context. However, recent work has shown that the ideal values are, in fact, sensitive to local conformation, and as a first step toward using such information to build more accurate models, ultra-high resolution protein crystal structures have been used to derive a conformation-dependent library (CDL) of restraints for the protein backbone (Berkholz et al. 2009. Structure. 17, 1316). Here, we report the introduction of this CDL into the Phenix package and the results of test refinements of thousands of structures across a wide range of resolutions. These tests show that use of the conformation dependent library yields models that have substantially better agreement with ideal main-chain bond angles and lengths and, on average, a slightly enhanced fit to the X-ray data. No disadvantages of using the backbone CDL are apparent. In Phenix usage of the CDL can be selected by simply specifying the cdl=True option. This successful implementation paves the way for further aspects of the context-dependence of ideal geometry to be characterized and applied to improve experimental and predictive modelling accuracy.

  5. US imports. Part II. Refined product market shares, then and now

    SciTech Connect (OSTI)

    Not Available

    1987-07-08

    Unlike imports of crude oil to the US, which were up 45.7% between 1977 and 1986, imports of petroleum products have fallen by about 8.6% during the same period. The crude oil price crash of 1986 deepened US dependency on imports of crude, from 21.4% in 1977 to 25.4% in 1986, but reduced the dependency in the case of total refined products from 11.32% in 1977 to 11.13% in 1986. Comparing the first four months of 1987 with 1986, US dependency on imported petroleum products is down 2.73 percentage points; import dependency on OPEC petroleum products is down 4.60 percentage points; dependency on Arab OPEC countries product imports is down 1.88 percentage points; and for Eastern Hemisphere exporters, that dependency has fallen 2.17 percentage points. This issue also contains: (1) ED refining netback data from the US Gulf and West coasts, Rotterdam, and Singapore for early July 1987; and (2) ED fuel price/tax series for countries of the Western Hemisphere, July 1987 edition. 4 figures, 5 tables.

  6. Conformation-dependent backbone geometry restraints set a new standard for protein crystallographic refinement

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moriarty, Nigel W.; Tronrud, Dale E.; Adams, Paul D.; Karplus, P. Andrew

    2014-06-17

    Ideal values of bond angles and lengths used as external restraints are crucial for the successful refinement of protein crystal structures at all but the highest of resolutions. The restraints in common usage today have been designed based on the assumption that each type of bond or angle has a single ideal value independent of context. However, recent work has shown that the ideal values are, in fact, sensitive to local conformation, and as a first step toward using such information to build more accurate models, ultra-high resolution protein crystal structures have been used to derive a conformation-dependent library (CDL)more » of restraints for the protein backbone (Berkholz et al. 2009. Structure. 17, 1316). Here, we report the introduction of this CDL into the Phenix package and the results of test refinements of thousands of structures across a wide range of resolutions. These tests show that use of the conformation dependent library yields models that have substantially better agreement with ideal main-chain bond angles and lengths and, on average, a slightly enhanced fit to the X-ray data. No disadvantages of using the backbone CDL are apparent. In Phenix usage of the CDL can be selected by simply specifying the cdl=True option. This successful implementation paves the way for further aspects of the context-dependence of ideal geometry to be characterized and applied to improve experimental and predictive modelling accuracy.« less

  7. Solvent Refined Coal (SRC) process. Quarterly technical progress report, January 1979-March 1979

    SciTech Connect (OSTI)

    Not Available

    1980-02-01

    This report summarizes the progress of the Solvent Refined Coal (SRC) Project by the Pittsburg and Midway Coal Mining Co. for the Department of Energy for the period January 1, 1979 to March 31, 1979. Activities included the operation and modification of the Solvent Refined Coal Pilot Plant at Fort Lewis, Washington; the Process Development Unit P-99 at Harmarville, Pennsylvania; and research at Merriam Laboratory in Merriam, Kansas. The Pilot Plant processed Powhatan No. 5 Coal in the SRC-II mode of operation studying the effect of coal particle size and system temperature on coal slurry blending and the effect of carbon monoxide concentration in the reaction feed gas on process yields. January and February were spent completing installation of a fourth High Pressure Separator on Process Development Unit P-99 to better simulate operating conditions for the proposed Demonstration Plant. During March, one run was completed at P-99 feeding Pittsburgh Seam Coal from the Powhatan No. 5 Mine. Merriam investigations included a study of the effect of iron containing additives on SRC-I operation, the addition of carbon monoxide to the feed gas, utilization of a hydrogenated solvent (Cresap process solvent) in the SRC-I mode under both normal and short residence time operating conditions, and development of a simulated distillation technique to determine the entire boiling range distribution of product oils.

  8. Molecular dynamics force-field refinement against quasi-elastic neutron scattering data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Borreguero Calvo, Jose M.; Lynch, Vickie E.

    2015-11-23

    Quasi-elastic neutron scattering (QENS) is one of the experimental techniques of choice for probing the dynamics at length and time scales that are also in the realm of full-atom molecular dynamics (MD) simulations. This overlap enables extension of current fitting methods that use time-independent equilibrium measurements to new methods fitting against dynamics data. We present an algorithm that fits simulation-derived incoherent dynamical structure factors against QENS data probing the diffusive dynamics of the system. We showcase the difficulties inherent to this type of fitting problem, namely, the disparity between simulation and experiment environment, as well as limitations in the simulationmore » due to incomplete sampling of phase space. We discuss a methodology to overcome these difficulties and apply it to a set of full-atom MD simulations for the purpose of refining the force-field parameter governing the activation energy of methyl rotation in the octa-methyl polyhedral oligomeric silsesquioxane molecule. Our optimal simulated activation energy agrees with the experimentally derived value up to a 5% difference, well within experimental error. We believe the method will find applicability to other types of diffusive motions and other representation of the systems such as coarse-grain models where empirical fitting is essential. In addition, the refinement method can be extended to the coherent dynamic structure factor with no additional effort.« less

  9. The Effect of Atmosphere on the Interdiffusion of Silver and Palladium

    SciTech Connect (OSTI)

    Garino, Terry; Rodriguez, Mark

    1999-07-14

    Conductor inks containing silver and palladium, used in ceramic co-fired circuits, sometimes undergo an anomalously large expansion during heating in the temperature range where interdiffusion occurs. Therefore, the interdiffusion of silver and palladium was studied during heating in both air and argon using both powder and foil samples. Measurements on a powder compact made of a mixture of Ag and Pd (80% Ag) particles indicated that a very rapid expansion occurred between 375 and 400 C when heated in air but only a slight expansion occurred in Ar. A pre-alloyed powder with the same composition did not expand during heating. In situ high temperature x-ray diffraction studies indicated that both powders oxidized during heating in air, with the mixture oxidizing more and that interdiffusion occurred between 300 and 500 C. Microstructural examination indicated that larger particles with internal pores had formed in the mixture heated in air to 375 C due to rearrangement during interdiffusion. A porous region much thicker than the original silver film formed on a palladium foil sample when it was heated in air, whereas in inert atmosphere pores formed only in the silver film, indicating a Kirkendall effect occurs in both cases. Based on these results, it was concluded that the expansion of the Ag-Pd powder mixture was due to interdiffusion in the presence of oxygen, not solely to the oxidation of the Pd.

  10. Optical properties and crystallinity of silver mirrors under a 35 krad cobalt-60 radiation

    SciTech Connect (OSTI)

    Chiu, Po-Kai Chiang, Donyau; Lee, Chao-Te; Lin, Yu-Wei; Hsiao, Chien-Nan

    2015-09-15

    This study addresses the effects of thin film optical design and environmental radiation on the optical properties of silver mirrors. Different experimental thin film optical designs are selected, and the film stack is built using Macleod's approach. Mirror elements are exposed to the same dose of radiation and their properties are characterized using a spectrophotometer equipped with an integration sphere and an x-ray diffractometer. Spectrophotometric analyses of mirrors exposed to about 35 krad of {sup 60}Co radiations overall show that the B270 glass substrates coated with titanium oxide (TiO{sub 2}), silicon dioxide (SiO{sub 2}), pure chrome, and pure silver effectively reduces radiation damage. The absorption spectrum of the TiO{sub 2} film in the visible region decreases after radiation and displays drifting. As thin metal films comparison, the silver thin film exhibits higher radiation resistance than the chrome thin film. The x-ray diffraction analysis on metal film layers reveals that crystallinity slightly increases when the silver thin film is irradiated.

  11. Copper-silver-titanium-tin filler metal for direct brazing of structural ceramics

    DOE Patents [OSTI]

    Moorhead, Arthur J.

    1988-04-05

    A method of joining ceramics and metals to themselves and to one another at about 800.degree. C. is described using a brazing filler metal consisting essentially of 35 to 50 at. % copper, 40 to 50 at. % silver, 1 to 15 at. % titanium, and 2 to 8 at. % tin. This method produces strong joints that can withstand high service temperatures and oxidizing environments.

  12. Copper-silver-titanium filler metal for direct brazing of structural ceramics

    DOE Patents [OSTI]

    Moorhead, Arthur J.

    1987-01-01

    A method of joining ceramics and metals to themselves and to one another is described using a brazing filler metal consisting essentially of 35 to 50 atomic percent copper, 15 to 50 atomic percent silver and 10 to 45 atomic percent titanium. This method produces strong joints that can withstand high service temperatures and oxidizing environments.

  13. Pure silver ohmic contacts to N- and P- type gallium arsenide materials

    DOE Patents [OSTI]

    Hogan, Stephen J.

    1986-01-01

    Disclosed is an improved process for manufacturing gallium arsenide semiconductor devices having as its components an n-type gallium arsenide substrate layer and a p-type gallium arsenide diffused layer. The improved process comprises forming a pure silver ohmic contact to both the diffused layer and the substrate layer, wherein the n-type layer comprises a substantially low doping carrier concentration.

  14. Process for forming pure silver ohmic contacts to N- and P-type gallium arsenide materials

    DOE Patents [OSTI]

    Hogan, S.J.

    1983-03-13

    Disclosed is an improved process for manufacturing gallium arsenide semiconductor devices having as its components a n-type gallium arsenide substrate layer and a p-type gallium arsenide diffused layer. The improved process comprises forming a pure silver ohmic contact to both the diffuse layer and the substrate layer wherein the n-type layer comprises a substantially low doping carrier concentration.

  15. Adsorption of iodine on hydrogen-reduced silver-exchanged mordenite: Experiments and modeling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Nan, Yue; Tavlarides, Lawrence L.; DePaoli, David W.

    2016-08-03

    The adsorption process of iodine, a major volatile radionuclide in the off-gas streams of spent nuclear fuel reprocessing, on hydrogen-reduced silver-exchanged mordenite (Ag0Z) was studied at the micro-scale. The gas-solid mass transfer and reaction involved in the adsorption process were investigated and evaluated with appropriate models. Optimal conditions for reducing the silver-exchanged mordenite (AgZ) in a hydrogen stream were determined. Kinetic and equilibrium data of iodine adsorption on Ag0Z were obtained by performing single-layer adsorption experiments with experimental systems of high precision at 373–473 K over various iodine concentrations. Results indicate approximately 91% to 97% of the iodine adsorption wasmore » through the silver-iodine reaction. The effect of temperature on the iodine loading capacity of Ag0Z was discussed. In conclusion, the Shrinking Core model describes the data well, and the primary rate controlling mechanisms were macro-pore diffusion and silver-iodine reaction. © 2016 American Institute of Chemical Engineers AIChE J, 2016« less

  16. Evaluation of tropical channel refinement using MPAS-A aquaplanet simulations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Martini, Matus N.; Gustafson, Jr., William I.; O'Brien, Travis A.; Ma, Po -Lun

    2015-09-13

    Climate models with variable-resolution grids offer a computationally less expensive way to provide more detailed information at regional scales and increased accuracy for processes that cannot be resolved by a coarser grid. This study uses the Model for Prediction Across Scales–Atmosphere (MPAS22A), consisting of a nonhydrostatic dynamical core and a subset of Advanced Research Weather Research and Forecasting (ARW-WRF) model atmospheric physics that have been modified to include the Community Atmosphere Model version 5 (CAM5) cloud fraction parameterization, to investigate the potential benefits of using increased resolution in an tropical channel. The simulations are performed with an idealized aquaplanet configurationmore » using two quasi-uniform grids, with 30 km and 240 km grid spacing, and two variable-resolution grids spanning the same grid spacing range; one with a narrow (20°S–20°N) and one with a wide (30°S–30°N) tropical channel refinement. Results show that increasing resolution in the tropics impacts both the tropical and extratropical circulation. Compared to the quasi-uniform coarse grid, the narrow-channel simulation exhibits stronger updrafts in the Ferrel cell as well as in the middle of the upward branch of the Hadley cell. The wider tropical channel has a closer correspondence to the 30 km quasi-uniform simulation. However, the total atmospheric poleward energy transports are similar in all simulations. The largest differences are in the low-level cloudiness. The refined channel simulations show improved tropical and extratropical precipitation relative to the global 240 km simulation when compared to the global 30 km simulation. All simulations have a single ITCZ. Furthermore, the relatively small differences in mean global and tropical precipitation rates among the simulations are a promising result, and the evidence points to the tropical channel being an effective method for avoiding the extraneous numerical artifacts seen in

  17. Identification of Silver and Palladium in Irradiated TRISO Coated Particles of the AGR-1 Experiment

    SciTech Connect (OSTI)

    van Rooyen, Y. J.; Lillo, T. M.; Wu, Y. Q.

    2014-03-01

    Evidence of the release of certain metallic fission product through intact tristructural isotropic (TRISO) particles has been seen for decades around the world, as well as in the recent AGR-1 experiment at Idaho National Laboratory (INL). However, understanding the basic mechanism of transport is still lacking. This understanding is important because the TRISO coating is part of the high temperature gas reactor functional containment and critical for the safety strategy for licensing purposes. Our approach to identify fission products in irradiated AGR-1 TRISO fuel using scanning transmission electron microscopy (STEM), Electron Energy Loss Spectroscopy (EELS) and Energy Filtered TEM (EFTEM), has led to first-of-a-kind data at the nano-scale indicating the presence of silver at triple points and grain boundaries of the SiC layer in the TRISO particle. Cadmium was also found in the triple junctions. In this initial study, the silver was only identified in SiC grain boundaries and triple points on the edge of the SiC-IPyC interface up to a depth of approximately 0.5 um. Palladium was identified as the main constituent of micron-sized precipitates present at the SiC grain boundaries. Additionally spherical nano-sized palladium rich precipitates were found inside the SiC grains. These nano-sized Pd precipitates were distributed up to a depth of 5 um away from the SiC-IPyC interlayer. No silver was found in the center of the micron-sized fission product precipitates using these techniques, although silver was found on the outer edge of one of the Pd-U-Si containing precipitates which was facing the IPyC layer. Only Pd-U containing precipitates were identified in the IPyC layer and no silver was identified in the IPyC layer. The identification of silver alongside the grain boundaries and the findings of Pd alongside grain boundaries as well as inside the grains, provide significant knowledge for understanding silver and palladium transport in TIRSO fuel, which has been

  18. Synthesis of silver nanoparticles by chemical reduction at various fraction of MSA and their structure characterization

    SciTech Connect (OSTI)

    Diantoro, Markus Fitrianingsih, Rina Mufti, Nandang Fuad, Abdulloh

    2014-03-24

    Nanosilver is currently one of the most common engineered nanomaterials and is used in many applications that lead to the release of silver nanoparticles and silver ions into aqueous systems. Nanosilver also possesses enhanced antimicrobial activity and bioavailability that may less environmental risk compared with other manufactured nanomaterials. Described in this research are the synthesis of silver nanoparticle produced by chemical reduction from silver nitrate (AgNO{sub 3}) solution. As a reducing agent, Sodium Borohydride (NaBH{sub 4}) was used and mercaptosuccinic Acid (MSA) as stabilizer to prevent the nanoparticle from aglomerating. It was also used two kinds of solvent, they are water and methanol. In typical experiment MSA was dissolve in methanol with a number of variation of molarity i.e. 0,03 M, 0,06 M, 0,12 M, 0,15 M, and the mixture was kept under vigorous stirring in an ice bath. A solution of silver nitrate of 340 mg in 6,792 ml water was added. A freshly prepared aqueous solution of sodium borohydride (756,6 mL in 100 mL of water) was added drop wisely. The solution was kept for half an hour for stirring and were allowed to settle down in methanol. The obtained samples then characterized by means of x-ray diffractometer, and scanning electron microscopy, as well as transmission electron microscopy to obtain their structures of silver nanoparticles, morphology, and sizes. It is shown that diameter of silver nanoparticle sized about 24.3 nm (Ag@MSA 0.03 M), 20.4 nm (Ag@MSA 0.06 M), 16.8 nm (Ag@MSA 0.12 M), 16.9 nm (Ag@MSA 0.15 M) which was calculated by Scherrer formula by taking the FWHM from fitting to Gaussian. The phases and lattice parameter showed that there is no significant change in its volume by increasing molarity of stabilizer. In contrast, the size of particles is decreasing.

  19. Table 3a. Imported Refiner Acquisition Cost of Crude Oil, Projected vs. Actual

    U.S. Energy Information Administration (EIA) Indexed Site

    a. Imported Refiner Acquisition Cost of Crude Oil, Projected vs. Actual Projected Price in Constant Dollars (constant dollars per barrel in "dollar year" specific to each AEO) AEO $ Year 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 AEO 1994 1992 16.69 16.43 16.99 17.66 18.28 19.06 19.89 20.72 21.65 22.61 23.51 24.29 24.90 25.60 26.30 27.00 27.64 28.16 AEO 1995 1993 14.90 16.41 16.90 17.45 18.00 18.53 19.13 19.65 20.16 20.63

  20. Methods of refining natural oils and methods of producing fuel compositions

    SciTech Connect (OSTI)

    Firth, Bruce E; Kirk, Sharon E; Gavaskar, Vasudeo S

    2015-11-04

    A method of refining a natural oil includes: (a) providing a feedstock that includes a natural oil; (b) reacting the feedstock in the presence of a metathesis catalyst to form a metathesized product that includes olefins and esters; (c) passivating residual metathesis catalyst with an agent selected from the group consisting of phosphorous acid, phosphinic acid, and a combination thereof; (d) separating the olefins in the metathesized product from the esters in the metathesized product; and (e) transesterifying the esters in the presence of an alcohol to form a transesterified product and/or hydrogenating the olefins to form a fully or partially saturated hydrogenated product. Methods for suppressing isomerization of olefin metathesis products produced in a metathesis reaction, and methods of producing fuel compositions are described.

  1. Methods of refining natural oils, and methods of producing fuel compositions

    SciTech Connect (OSTI)

    Firth, Bruce E.; Kirk, Sharon E.

    2015-10-27

    A method of refining a natural oil includes: (a) providing a feedstock that includes a natural oil; (b) reacting the feedstock in the presence of a metathesis catalyst to form a metathesized product that includes olefins and esters; (c) passivating residual metathesis catalyst with an agent that comprises nitric acid; (d) separating the olefins in the metathesized product from the esters in the metathesized product; and (e) transesterifying the esters in the presence of an alcohol to form a transesterified product and/or hydrogenating the olefins to form a fully or partially saturated hydrogenated product. Methods for suppressing isomerization of olefin metathesis products produced in a metathesis reaction, and methods of producing fuel compositions are described.

  2. Solvent-refined-coal (SRC) process. Volume II. Sections V-XIV. Final report

    SciTech Connect (OSTI)

    Not Available

    1982-05-01

    This report documents the completion of development work on the Solvent Refined Coal Process by The Pittsburgh and Midway Coal Mining Co. The work was initiated in 1966 under Office of Coal Research, US Department of Interior, Contract No. 14-01-0001-496 and completed under US Department of Energy Contract No. DE-AC05-79ET10104. This report discusses work leading to the development of the SRC-I and SRC-II processes, construction of the Fort Lewis Pilot Plant for the successful development of these processes, and results from the operation of this pilot plant. Process design data generated on a 1 ton-per-day Process Development Unit, bench-scale units and through numerous research projects in support of the design of major demonstration plants are also discussed in summary form and fully referenced in this report.

  3. Early F-type stars - refined classification, confrontation with Stromgren photometry, and the effects of rotation

    SciTech Connect (OSTI)

    Gray, R.O.; Garrison, R.F.

    1989-02-01

    The classification for early F-type stars in the MK spectral classification system presented by Gray and Garrison (1987) is refined. The effect of rotation on spectral classification and ubvy-beta photometry of early F-type stars is examined. It is found that the classical luminosity criterion, the 4417 A/4481 A ratio gives inconsistent results. It is shown that most of the stars in the Delta Delphini class of metallic-line stars are either normal or are indistinguishable from proto-Am stars. It is suggested that the designation Delta Delphini should be dropped. The classifications are compared with Stromgren photometry. The effects of rotation on the delta-c sub 1 index in the early-F field dwarfs is demonstrated. 55 references.

  4. 3D Adaptive Mesh Refinement Simulations of Pellet Injection in Tokamaks

    SciTech Connect (OSTI)

    R. Samtaney; S.C. Jardin; P. Colella; D.F. Martin

    2003-10-20

    We present results of Adaptive Mesh Refinement (AMR) simulations of the pellet injection process, a proven method of refueling tokamaks. AMR is a computationally efficient way to provide the resolution required to simulate realistic pellet sizes relative to device dimensions. The mathematical model comprises of single-fluid MHD equations with source terms in the continuity equation along with a pellet ablation rate model. The numerical method developed is an explicit unsplit upwinding treatment of the 8-wave formulation, coupled with a MAC projection method to enforce the solenoidal property of the magnetic field. The Chombo framework is used for AMR. The role of the E x B drift in mass redistribution during inside and outside pellet injections is emphasized.

  5. Lance for fuel and oxygen injection into smelting or refining furnace

    DOE Patents [OSTI]

    Schlichting, M.R.

    1994-12-20

    A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figures.

  6. Lance for fuel and oxygen injection into smelting or refining furnace

    DOE Patents [OSTI]

    Schlichting, Mark R.

    1994-01-01

    A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

  7. A technical and economic assessment of petroleum, heavy oil, shale oil and coal liquid refining

    SciTech Connect (OSTI)

    Sikonia, J.G.; Shah, B.R.; Ulowetz, M.A.

    1983-11-01

    Decreasing availability of conventional crude oil will result in the utilization of alternative raw materials for the production of transportation fuels. Based on currently available processes and as a result of detailed pilot plant studies, the differences in the technical and economic aspects of refining alternative feedstocks of heavy oil, coal liquids and shale oil have indicated that heavy, hydrogen-deficient materials require more complex and costly upgrading techniques. Compared to the base case of Arabian Light crude oil, the Mexican Maya heavy oil is worth about $4.35/B less, the coal liquid about $2.38/B less and the shale oil about $5.98/B less. All of these alternative fuels can be upgraded into high quality transportation fuels.

  8. A node-centered local refinement algorithm for poisson's equation in complex geometries

    SciTech Connect (OSTI)

    McCorquodale, Peter; Colella, Phillip; Grote, David P.; Vay, Jean-Luc

    2004-05-04

    This paper presents a method for solving Poisson's equation with Dirichlet boundary conditions on an irregular bounded three-dimensional region. The method uses a nodal-point discretization and adaptive mesh refinement (AMR) on Cartesian grids, and the AMR multigrid solver of Almgren. The discrete Laplacian operator at internal boundaries comes from either linear or quadratic (Shortley-Weller) extrapolation, and the two methods are compared. It is shown that either way, solution error is second order in the mesh spacing. Error in the gradient of the solution is first order with linear extrapolation, but second order with Shortley-Weller. Examples are given with comparison with the exact solution. The method is also applied to a heavy-ion fusion accelerator problem, showing the advantage of adaptivity.

  9. Exploratory research on solvent refined coal liquefaction. Quarterly technical progress report, April 1-June 30, 1979

    SciTech Connect (OSTI)

    1980-07-01

    This report summarizes the progress of the Exploratory Research on Solvent Refined Coal Liquefaction project by The Pittsburgh and Midway Coal Mining Company's Merriam Laboratory for the period April 1, 1979 through June 30, 1979. Experimental work included a number of short residence time runs, but discussion of that work has been delayed until a later report. Experimental work reported focuses on an investigation of the decline in solvent quality experienced by the Wilsonville Pilot Plant during runs in support of the SRC I Demonstration Plant. A four run series was initiated with Wilsonville solvent; both the coal used at Wilsonville (Kentucky 6/11 - Pyro Mine) and Kentucky 9/14 coal from the Colonial Mine were used. The effect of pyrite addition to the Pyro Mine coal was investigated. No solvent quality or coking problems were experienced in the Merriam runs. Significant changes in solvent composition were apparent and equilibrated solvent samples were returned to Wilsonville for solvent quality testing.

  10. Methods of refining and producing isomerized fatty acid esters and fatty acids from natural oil feedstocks

    DOE Patents [OSTI]

    Snead, Thomas E.; Cohen, Steven A.; Gildon, Demond L.; Beltran, Leslie V.; Kunz, Linda A.; Pals, Tessa M.; Quinn, Jordan R; Behrends, Jr., Raymond T.; Bernhardt, Randal J.

    2016-07-05

    Methods are provided for refining natural oil feedstocks and producing isomerized esters and acids. The methods comprise providing a C4-C18 unsaturated fatty ester or acid, and isomerizing the fatty acid ester or acid in the presence of heat or an isomerization catalyst to form an isomerized fatty ester or acid. In some embodiments, the methods comprise forming a dibasic ester or dibasic acid prior to the isomerizing step. In certain embodiments, the methods further comprise hydrolyzing the dibasic ester to form a dibasic acid. In certain embodiments, the olefin is formed by reacting the feedstock in the presence of a metathesis catalyst under conditions sufficient to form a metathesized product comprising olefins and esters, separating the olefins from the esters in the metathesized product, and transesterifying the esters in the presence of an alcohol to form a transesterified product having unsaturated esters.

  11. On the Computation of Integral Curves in Adaptive Mesh Refinement Vector Fields

    SciTech Connect (OSTI)

    Deines, Eduard; Weber, Gunther H.; Garth, Christoph; Van Straalen, Brian; Borovikov, Sergey; Martin, Daniel F.; Joy, Kenneth I.

    2011-06-27

    Integral curves, such as streamlines, streaklines, pathlines, and timelines, are an essential tool in the analysis of vector field structures, offering straightforward and intuitive interpretation of visualization results. While such curves have a long-standing tradition in vector field visualization, their application to Adaptive Mesh Refinement (AMR) simulation results poses unique problems. AMR is a highly effective discretization method for a variety of physical simulation problems and has recently been applied to the study of vector fields in flow and magnetohydrodynamic applications. The cell-centered nature of AMR data and discontinuities in the vector field representation arising from AMR level boundaries complicate the application of numerical integration methods to compute integral curves. In this paper, we propose a novel approach to alleviate these problems and show its application to streamline visualization in an AMR model of the magnetic field of the solar system as well as to a simulation of two incompressible viscous vortex rings merging.

  12. Effects of gas injection condition on mixing efficiency in the ladle refining process

    SciTech Connect (OSTI)

    Pan, S.M.; Chiang, J.D.; Hwang, W.S.

    1997-02-01

    The aim of this research was to investigate the effects of injection condition on the mixing efficiency of the gas injection treatment of the ladle refining process in steelmaking. A water modeling approach was employed. A NaCl solution was injected into the vessel and the electric conductivity value of the water solution was measured to represent the concentration of the additive. The results of this investigation reveal that up to a certain level, mixing efficiency is improved as the gas flow rate increases. Off-center injection is better than centerline injection. However, the injection lance should not be too close to the wall. Also, mixing efficiency is improved when the submerged depth of the immersion lance increases. The immersion hood has a optimal size as far as mixing efficiency is concerned. A larger or smaller hood would reduce its efficiency. The submerged depth of the immersion hood should be kept to a minimum to improve mixing efficiency.

  13. Thermal conductivity studies of novel nanofluids based on metallic silver decorated mesoporous silica nanoparticles

    SciTech Connect (OSTI)

    Tadjarodi, Azadeh; Zabihi, Fatemeh

    2013-10-15

    Graphical abstract: - Highlights: Metallic silver was decorated in mSiO{sub 2} with grafted hemiaminal functional groups. Synthesized nanoparticles were used for preparation of glycerol based nanofluids. The effect of temperature, weight fraction of mSiO{sub 2} and concentration of silver nanoparticles on thermal conductivity of nanofluids was investigated. - Abstract: In the present study, the mesoporous structure of silica (mSiO{sub 2}) nanoparticles as well as hemiaminal grafted mSiO{sub 2} decorated by metallic silver (Ag/mSiO{sub 2}) has been used for the preparation of glycerol based nanofluids. Structural and morphological characterization of the synthesized products have been carried out using Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), X-ray diffraction (XRD), UVvis spectroscopy, inductively coupled plasma (ICP) and N{sub 2} adsorptiondesorption isotherms. The thermal conductivity and viscosity of the nanofluids have been measured as a function of temperature for various weight fractions and silver concentrations of mSiO{sub 2} and Ag/mSiO{sub 2} nanoparticles, respectively. The results show that the thermal conductivity of the nanofluids increase up to 9.24% as the weight fraction of mSiO{sub 2} increases up to 4 wt%. Also, increasing the percent of the silver decorated mSiO{sub 2} (Ag/mSiO{sub 2}) up to 2.98% caused an enhancement in the thermal conductivity of the base fluid up to 10.95%. Furthermore, the results show that the nanofluids have Newtonian behavior in the tested temperature range for various concentrations of nanoparticles.

  14. Refining the site conceptual model at a former uranium mill site in Riverton, Wyoming, USA

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dam, William; Campbell, Sam; Johnson, Ray; Looney, Brian; Denham, Miles E.; Eddy-Dilek, Carol A.; Babits, Steven J.

    2015-07-07

    Milling activities at a former uranium mill site near Riverton, Wyoming, USA, contaminated the shallow groundwater beneath and downgradient of the site. Although the mill operated for <6 years (1958-1963), its impact remains an environmental liability. Groundwater modeling predicted that contaminant concentrations were declining steadily, which confirmed the conceptual site model (CSM). However, local flooding in 2010 mobilized contaminants that migrated downgradient from the Riverton site and resulted in a dramatic increase in groundwater contaminant concentrations. This observation indicated that the original CSM was inadequate to explain site conditions and needed to be refined. In response to the new observationsmore » after the flood, a collaborative investigation to better understand site conditions and processes commenced. This investigation included installing 103 boreholes to collect soil and groundwater samples, sampling and analysis of evaporite minerals along the bank of the Little Wind River, an analysis of evaportranspiration in the shallow aquifer, and sampling naturally organic-rich sediments near groundwater discharge areas. The enhanced characterization revealed that the existing CSM did not account for high uranium concentrations in groundwater remaining on the former mill site and groundwater plume stagnation near the Little Wind River. Observations from the flood and subsequent investigations indicate that additional characterization is still needed to continue refining the CSM and determine the viability of the natural flushing compliance strategy. Additional sampling, analysis, and testing of soil and groundwater are necessary to investigate secondary contaminant sources, mobilization of contaminants during floods, geochemical processes, contaminant plume stagnation, distribution of evaporite minerals and organic-rich sediments, and mechanisms and rates of contaminant transfer from soil to groundwater. Future data collection will be used to

  15. Petroleum refining industry of developed capitalist countries in the 1990s

    SciTech Connect (OSTI)

    Prokhorova, A.A.

    1994-07-01

    Crude oil is the principal source of energy today and in the immediate future. The increases in the consumption of crude oil (1.7% per year up to 2005) will be offset mainly by additional supplies from the countries of the Near East. Data on the imports of oil by the developed capitalists countries are presented in Table 2. In the United States, according to a projection made by Conoco, by the year 2000 the volume of imports will be twice the volume of domestic production; according to another prediction, the amount of Near East crude will increase from 34% in 1990 to 42% in 2000. Since the mid-1980s, the energy policy of the USA has been based on importing so-called cheap crude. Laws have been passed to mandate not only energy saving, but also cuts in the oil and gas production on U.S. territory. The volume of U.S. oil production will be 20% lower in 2000 than in 1990. Some 90% of the worldwide demand for oil is met by light and medium-density crudes, but such crudes account for only 25% of the oil resources. Projections indicate that the oil supplied to refiners in the future will be heavier and will have higher sulfur contents. The U.S. production of low-sulfur crude will drop off sharply in the next 10-15 years. The drop in oil production of the CIS [former USSR] and the consequent drop in exports from these countries will have a destabilizing effect on the world market. The average price of the {open_quotes}market basket{close_quotes} of OPEC crudes in 1991 was $149/ton (in 1990 $178/ton), in comparison with a 1992 price of $148/ton. This report presents data on refining process capacities and the ratio of secondary capacity to primary distillation capacity.

  16. An enriched finite element model with q-refinement for radiative boundary layers in glass cooling

    SciTech Connect (OSTI)

    Mohamed, M. Shadi; Seaid, Mohammed; Trevelyan, Jon; Laghrouche, Omar

    2014-02-01

    Radiative cooling in glass manufacturing is simulated using the partition of unity finite element method. The governing equations consist of a semi-linear transient heat equation for the temperature field and a stationary simplified P{sub 1} approximation for the radiation in non-grey semitransparent media. To integrate the coupled equations in time we consider a linearly implicit scheme in the finite element framework. A class of hyperbolic enrichment functions is proposed to resolve boundary layers near the enclosure walls. Using an industrial electromagnetic spectrum, the proposed method shows an immense reduction in the number of degrees of freedom required to achieve a certain accuracy compared to the conventional h-version finite element method. Furthermore the method shows a stable behaviour in treating the boundary layers which is shown by studying the solution close to the domain boundaries. The time integration choice is essential to implement a q-refinement procedure introduced in the current study. The enrichment is refined with respect to the steepness of the solution gradient near the domain boundary in the first few time steps and is shown to lead to a further significant reduction on top of what is already achieved with the enrichment. The performance of the proposed method is analysed for glass annealing in two enclosures where the simplified P{sub 1} approximation solution with the partition of unity method, the conventional finite element method and the finite difference method are compared to each other and to the full radiative heat transfer as well as the canonical Rosseland model.

  17. Refining the site conceptual model at a former uranium mill site in Riverton, Wyoming, USA

    SciTech Connect (OSTI)

    Dam, William; Campbell, Sam; Johnson, Ray; Looney, Brian; Denham, Miles E.; Eddy-Dilek, Carol A.; Babits, Steven J.

    2015-07-07

    Milling activities at a former uranium mill site near Riverton, Wyoming, USA, contaminated the shallow groundwater beneath and downgradient of the site. Although the mill operated for <6 years (1958-1963), its impact remains an environmental liability. Groundwater modeling predicted that contaminant concentrations were declining steadily, which confirmed the conceptual site model (CSM). However, local flooding in 2010 mobilized contaminants that migrated downgradient from the Riverton site and resulted in a dramatic increase in groundwater contaminant concentrations. This observation indicated that the original CSM was inadequate to explain site conditions and needed to be refined. In response to the new observations after the flood, a collaborative investigation to better understand site conditions and processes commenced. This investigation included installing 103 boreholes to collect soil and groundwater samples, sampling and analysis of evaporite minerals along the bank of the Little Wind River, an analysis of evaportranspiration in the shallow aquifer, and sampling naturally organic-rich sediments near groundwater discharge areas. The enhanced characterization revealed that the existing CSM did not account for high uranium concentrations in groundwater remaining on the former mill site and groundwater plume stagnation near the Little Wind River. Observations from the flood and subsequent investigations indicate that additional characterization is still needed to continue refining the CSM and determine the viability of the natural flushing compliance strategy. Additional sampling, analysis, and testing of soil and groundwater are necessary to investigate secondary contaminant sources, mobilization of contaminants during floods, geochemical processes, contaminant plume stagnation, distribution of evaporite minerals and organic-rich sediments, and mechanisms and rates of contaminant transfer from soil to groundwater. Future data collection will be used to

  18. Development of a performance-based industrial energy efficiency indicator for corn refining plants.

    SciTech Connect (OSTI)

    Boyd, G. A.; Decision and Information Sciences; USEPA

    2006-07-31

    Organizations that implement strategic energy management programs have the potential to achieve sustained energy savings if the programs are carried out properly. A key opportunity for achieving energy savings that plant managers can take is to determine an appropriate level of energy performance by comparing their plant's performance with that of similar plants in the same industry. Manufacturing facilities can set energy efficiency targets by using performance-based indicators. The U.S. Environmental Protection Agency (EPA), through its ENERGY STAR{reg_sign} program, has been developing plant energy performance indicators (EPIs) to encourage a variety of U.S. industries to use energy more efficiently. This report describes work with the corn refining industry to provide a plant-level indicator of energy efficiency for facilities that produce a variety of products--including corn starch, corn oil, animal feed, corn sweeteners, and ethanol--for the paper, food, beverage, and other industries in the United States. Consideration is given to the role that performance-based indicators play in motivating change; the steps needed to develop indicators, including interacting with an industry to secure adequate data for an indicator; and the actual application and use of an indicator when complete. How indicators are employed in the EPA's efforts to encourage industries to voluntarily improve their use of energy is discussed as well. The report describes the data and statistical methods used to construct the EPI for corn refining plants. Individual equations are presented, as are the instructions for using them in an associated Excel spreadsheet.

  19. Characterization report. Bulgarian petroleum refining sector. A sector overview of capability, energy consumption, environmental impacts, May 1992. Export trade information

    SciTech Connect (OSTI)

    Adams, N.

    1992-05-01

    The objective of the report is to provide data that will serve as a basis for the modernization and optimization of the economic performance of the petroleum refining industry of Bulgaria. It addresses the current status of the petroleum refining industry so that recommendations providing low cost economies to improve energy efficiency and environmental control at each refinery can be prepared. Both short and long term improvement possibilities were established and given to the second round team for detailed evaluation. Following the collection of data on operating variables, equipment and refinery impact on the environment, a data base was prepared reflecting refinery characteristics and is the subject of a separate report.

  20. Characterization report. Romanian petroleum refining sector. A sector overview of capability, energy consumption, environmental impacts, May 1992. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    The objective of the report is to provide data that will serve as a basis for the modernization and optimization of the economic performance of the petroleum refining industry of Romania. The report addresses the current status of the petroleum refining industry so that recommendations providing low cost economies to improve energy efficiency and environmental control at each refinery can be prepared. Following the collection of data on operating variables, equipment, and refinery impact on the environment, a computerized data base was prepared, which is the subject of a separate report.

  1. Characterization report. Polish petroleum refining sector. A sector overview of capability, energy consumption, environmental impacts, May 1992. Export trade information

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    The objective of the report is to provide data that will serve as a basis for the modernization and optimization of the economic performance of the petroleum refining industry of Poland. The report addresses the current status of the petroleum refining industry so that recommendations providing low cost economies to improve energy efficiency and environmental control at each refinery can be prepared. Following the collection of data on operating variables, equipment, and refinery impact on the environment, a computerized database was prepared which is the subject of a separate report.

  2. Microsoft Word - Chemetall Foote_Kings Mountain and Silver Peak Final EA 9-15-10-1 _3_

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 Final Environmental Assessment For Chemetall Foote Corporation Electric Drive Vehicle Battery and Component Manufacturing Initiative Kings Mountain, NC and Silver Peak, NV September 2010 Prepared for: Department of Energy National Energy Technology Laboratory This page intentionally left blank. Electric Drive Vehicle Battery and DOE/EA-1715 Component Manufacturing Initiative Project Environmental Assessment Chemetall Foote Corporation, Kings Mountain, NC and Silver Peak, NV September 2010

  3. Local timespace mesh refinement for simulation of elastic wave propagation in multi-scale media

    SciTech Connect (OSTI)

    Kostin, Victor; Lisitsa, Vadim; Reshetova, Galina; Tcheverda, Vladimir

    2015-01-15

    This paper presents an original approach to local timespace grid refinement for the numerical simulation of wave propagation in models with localized clusters of micro-heterogeneities. The main features of the algorithm are the application of temporal and spatial refinement on two different surfaces; the use of the embedded-stencil technique for the refinement of grid step with respect to time; the use of the Fast Fourier Transform (FFT)-based interpolation to couple variables for spatial mesh refinement. The latter makes it possible to perform filtration of high spatial frequencies, which provides stability in the proposed finite-difference schemes. In the present work, the technique is implemented for the finite-difference simulation of seismic wave propagation and the interaction of such waves with fluid-filled fractures and cavities of carbonate reservoirs. However, this approach is easy to adapt and/or combine with other numerical techniques, such as finite elements, discontinuous Galerkin method, or finite volumes used for approximation of various types of linear and nonlinear hyperbolic equations.

  4. Aqueous Dissolution of Silver Iodide and Associated Iodine Release Under Reducing Conditions with Sulfide

    SciTech Connect (OSTI)

    Yaohiro Inagaki; Toshitaka Imamura; Kazuya Idemitsu; Tatsumi Arima; Osamu Kato; Hidekazu Asano; Tsutomu Nishimura

    2007-07-01

    Aqueous dissolution tests of silver iodide (AgI) were performed in Na{sub 2}S solutions in order to evaluate, empirically, dissolution of AgI to release iodine under reducing conditions with sulfide. The results indicated that AgI dissolves to release iodine being controlled by mainly precipitation of Ag{sub 2}S. However, the dissolution of AgI can be depressed to proceed, and the thermodynamic equilibrium cannot be attained easily. Solid phase analysis for the reacted AgI suggested that a thin layer of solid silver forming at AgI surface may evolve to be protective against transportation of reactant species, which can lead to the depression in the dissolution of AgI. (authors)

  5. Reduced graphene oxide based silver sulfide hybrid films formed at a liquid/liquid interface

    SciTech Connect (OSTI)

    Bramhaiah, K. John, Neena S.

    2014-04-24

    Free-standing, ultra-thin films of silver sulfide and reduced graphene oxide (RGO) based silver sulfide hybrids are prepared at a liquid/liquid interface employing in situ chemical reaction strategy. Ag{sub 2}S and RGO−Ag{sub 2}S hybrid films are characterized by various techniques such as UV-visible and photo luminescence spectroscopy, X-ray diffraction and scanning electron microscopy. The morphology of hybrid films consists of Ag{sub 2}S nanocrystals on RGO surface while Ag{sub 2}S films contains branched network of dendritic structures. RGO−Ag{sub 2}S exhibit interesting optical and electrical properties. The hybrid films absorb in the region 500–650 nm and show emission in the red region. A higher conductance is observed for the hybrid films arising from the RGO component. This simple low cost method can be extended to prepare other RGO based metal sulfides.

  6. Table 5.21 Crude Oil Refiner Acquisition Costs, 1968-2011 (Dollars per Barrel)

    U.S. Energy Information Administration (EIA) Indexed Site

    1 Crude Oil Refiner Acquisition Costs, 1968-2011 (Dollars per Barrel) Year Domestic Imported Composite Nominal 1 Real 2 Nominal 1 Real 2 Nominal 1 Real 2 1968E 3.21 14.57 [R] 2.90 13.16 [R] 3.17 14.39 [R] 1969E 3.37 14.58 [R] 2.80 12.11 [R] 3.29 14.23 [R] 1970E 3.46 14.22 [R] 2.96 12.16 [R] 3.40 13.97 [R] 1971E 3.68 14.40 [R] 3.17 12.41 [R] 3.60 14.09 [R] 1972E 3.67 13.77 [R] 3.22 12.08 [R] 3.58 13.43 [R] 1973E 4.17 14.82 [R] 4.08 14.50 [R] 4.15 14.75 [R] 1974 7.18 23.40 [R] 12.52 40.80 [R] 9.07

  7. Dimensional reduction as a tool for mesh refinement and trackingsingularities of PDEs

    SciTech Connect (OSTI)

    Stinis, Panagiotis

    2007-06-10

    We present a collection of algorithms which utilizedimensional reduction to perform mesh refinement and study possiblysingular solutions of time-dependent partial differential equations. Thealgorithms are inspired by constructions used in statistical mechanics toevaluate the properties of a system near a critical point. The firstalgorithm allows the accurate determination of the time of occurrence ofa possible singularity. The second algorithm is an adaptive meshrefinement scheme which can be used to approach efficiently the possiblesingularity. Finally, the third algorithm uses the second algorithm untilthe available resolution is exhausted (as we approach the possiblesingularity) and then switches to a dimensionally reduced model which,when accurate, can follow faithfully the solution beyond the time ofoccurrence of the purported singularity. An accurate dimensionallyreduced model should dissipate energy at the right rate. We construct twovariants of each algorithm. The first variant assumes that we have actualknowledge of the reduced model. The second variant assumes that we knowthe form of the reduced model, i.e., the terms appearing in the reducedmodel, but not necessarily their coefficients. In this case, we alsoprovide a way of determining the coefficients. We present numericalresults for the Burgers equation with zero and nonzero viscosity toillustrate the use of the algorithms.

  8. Biocide usage in cooling towers in the electric power and petroleum refining industries

    SciTech Connect (OSTI)

    Veil, J.; Rice, J.K.; Raivel, M.E.S.

    1997-11-01

    Cooling towers users frequently apply biocides to the circulating cooling water to control growth of microorganisms, algae, and macroorganisms. Because of the toxic properties of biocides, there is a potential for the regulatory controls on their use and discharge to become increasingly more stringent. This report examines the types of biocides used in cooling towers by companies in the electric power and petroleum refining industries, and the experiences those companies have had in dealing with agencies that regulate cooling tower blowdown discharges. Results from a sample of 67 electric power plants indicate that the use of oxidizing biocides (particularly chlorine) is favored. Quaternary ammonia salts (quats), a type of nonoxidizing biocide, are also used in many power plant cooling towers. The experience of dealing with regulators to obtain approval to discharge biocides differs significantly between the two industries. In the electric power industry, discharges of any new biocide typically must be approved in writing by the regulatory agency. The approval process for refineries is less formal. In most cases, the refinery must notify the regulatory agency that it is planning to use a new biocide, but the refinery does not need to get written approval before using it. The conclusion of the report is that few of the surveyed facilities are having any difficulty in using and discharging the biocides they want to use.

  9. Aluminum doped zirconia nanopowders: Wet-chemical synthesis and structural analysis by Rietveld refinement

    SciTech Connect (OSTI)

    Srdic, Vladimir V. Rakic, Srdan; Cvejic, Zeljka

    2008-10-02

    Alumina/zirconia nanopowders, with up to 20 mol% Al{sub 2}O{sub 3}, were prepared by wet-chemical synthesis technique, using controlled hydrolysis of alkoxides. The as-synthesized powders are amorphous, have very high specific surface area and the corresponding particle size smaller than 4 nm. Amorphous powders with 0, 10 and 20 mol% Al{sub 2}O{sub 3} crystallize at 460, 692 and 749 deg. C, respectively, as a single-phase tetragonal zirconia, without any traces of alumina phases. Rietvled refinement of X-ray diffraction data, used for the detailed structural analysis of annealed nanopowders, showed that the high-temperature zirconia phase is stabilized due to the formation of ZrO{sub 2}/Al{sub 2}O{sub 3} solid solutions. High solubility of alumina in the tetragonal zirconia (up to 28.6 at% Al{sup 3+}) and stabilization of tetragonal zirconia solid solution up to high temperature (as high as 1150 deg. C) were also confirmed.

  10. Chemical coal cleaning process and costs refinement for coal-water slurry manufacture

    SciTech Connect (OSTI)

    Bhasin, A.K.; Berggren, M.H.; Ronzio, N.J.; Smit, F.J.

    1985-12-31

    This report describes the results of process and cost refinement studies for the manufacture of ultra-clean coal-slurry fuel for direct-fired gas turbines. The work was performed as an extension to an earlier contract in which AMAX R and D supplied METC with two lots of highly beneficiated coal slurry fuel for use in the Heat Engines program. A conceptual design study and cost estimate supplied to METC at that time indicated that a combined physical and chemical cleaning process could produce ultra-clean fuel at a competitive price. Laboratory and pilot plant studies performed for the contract extension further defined the process conditions and operating and capital costs to prepare coals containing from 0.2 to 1.0% ash as slurry fuels. A base-case fuel containing coal cleaned to 0.5% ash in a 1000 cp slurry containing 55% coal was $4.16 per million Btu when produced in quantities required to fuel a 500 MW gas-turbine generating station. Coal slurry fuel production costs as low as $3.66 per million Btu were projected for coals cleaned to 1.0% ash. 12 refs., 23 figs., 63 tabs.

  11. Solvent Refined Coal (SRC) process. Quarterly technical progress report, April 1979-June 1979

    SciTech Connect (OSTI)

    Not Available

    1980-02-01

    This report summarizes the progress of the Solvent Refined Coal (SRC) Project for the period March 25, 1979, through June 24, 1979. SRC-I turnaround activities at the Fort Lewis Pilot Plant and several other problems delayed successful startup until April 11. Slurry was injected to the Lummus Deashing Unit for the first time April 12. After approximately eight days, slurry feed was diverted because of indications that solids were accumulating in the settler vessel. The Fort Lewis Pilot Plant was shut down from April 28 to May 12, 1979, while the Lummus Unit settler vessel was hydroblasted. Cleaning of the settler vessel was complete May 10. Modifications to the unit were nearly complete at the end of the reporting period. Slurry feed to the Lummus Unit was reestablished June 15. To date, continuous production of specification product at design rates has not been achieved. One material balance run, MBR 79-1, was completed using Kentucky No. 9/14 coal at proposed design conditions for the SRC-I Demonstration Plant. Process Development Unit P-99 was on-stream for all of the second quarter of 1979, with the exception of a two-week scheduled turn-around. Six different run conditions were tested feeding Pittsburgh Seam coal from the Powhatan No. 5 Mine.

  12. Refinement, Validation and Application of Cloud-Radiation Parameterization in a GCM

    SciTech Connect (OSTI)

    Dr. Graeme L. Stephens

    2009-04-30

    The research performed under this award was conducted along 3 related fronts: (1) Refinement and assessment of parameterizations of sub-grid scale radiative transport in GCMs. (2) Diagnostic studies that use ARM observations of clouds and convection in an effort to understand the effects of moist convection on its environment, including how convection influences clouds and radiation. This aspect focuses on developing and testing methodologies designed to use ARM data more effectively for use in atmospheric models, both at the cloud resolving model scale and the global climate model scale. (3) Use (1) and (2) in combination with both models and observations of varying complexity to study key radiation feedback Our work toward these objectives thus involved three corresponding efforts. First, novel diagnostic techniques were developed and applied to ARM observations to understand and characterize the effects of moist convection on the dynamical and thermodynamical environment in which it occurs. Second, an in house GCM radiative transfer algorithm (BUGSrad) was employed along with an optimal estimation cloud retrieval algorithm to evaluate the ability to reproduce cloudy-sky radiative flux observations. Assessments using a range of GCMs with various moist convective parameterizations to evaluate the fidelity with which the parameterizations reproduce key observable features of the environment were also started in the final year of this award. The third study area involved the study of cloud radiation feedbacks and we examined these in both cloud resolving and global climate models.

  13. A Predictive Model of Fragmentation using Adaptive Mesh Refinement and a Hierarchical Material Model

    SciTech Connect (OSTI)

    Koniges, A E; Masters, N D; Fisher, A C; Anderson, R W; Eder, D C; Benson, D; Kaiser, T B; Gunney, B T; Wang, P; Maddox, B R; Hansen, J F; Kalantar, D H; Dixit, P; Jarmakani, H; Meyers, M A

    2009-03-03

    Fragmentation is a fundamental material process that naturally spans spatial scales from microscopic to macroscopic. We developed a mathematical framework using an innovative combination of hierarchical material modeling (HMM) and adaptive mesh refinement (AMR) to connect the continuum to microstructural regimes. This framework has been implemented in a new multi-physics, multi-scale, 3D simulation code, NIF ALE-AMR. New multi-material volume fraction and interface reconstruction algorithms were developed for this new code, which is leading the world effort in hydrodynamic simulations that combine AMR with ALE (Arbitrary Lagrangian-Eulerian) techniques. The interface reconstruction algorithm is also used to produce fragments following material failure. In general, the material strength and failure models have history vector components that must be advected along with other properties of the mesh during remap stage of the ALE hydrodynamics. The fragmentation models are validated against an electromagnetically driven expanding ring experiment and dedicated laser-based fragmentation experiments conducted at the Jupiter Laser Facility. As part of the exit plan, the NIF ALE-AMR code was applied to a number of fragmentation problems of interest to the National Ignition Facility (NIF). One example shows the added benefit of multi-material ALE-AMR that relaxes the requirement that material boundaries must be along mesh boundaries.

  14. Decontamination of metals by melt refinings/slagging: An annotated bibliography

    SciTech Connect (OSTI)

    Mizia, R.E.; Worcester, S.A.; Twidwell, L.G.; Paolini, D.J.; Weldon, T.A.

    1993-07-01

    As the number of nuclear installations undergoing decontamination and decommissioning (D&D) increases, current radioactive waste storage space is consumed and establishment of new waste storage areas becomes increasingly difficult, the problem of handling and storing radioactive scrap metal (RSM) gains increasing importance in the DOE Environmental Restoration and Waste Management Program. To alleviate present and future waste storage problems, Westinghouse Idaho Nuclear Company (WINCO) is managing a program for the recycling of RSM for beneficial use within the DOE complex. As part of that effort, Montana Tech has been awarded a contract to help optimize melting and refining technology for the recycling of stainless steel RSM. The scope of the Montana Tech program includes a literature survey, a decontaminating slag design study, small scale melting studies to determine optimum slag compositions for removal of radioactive contaminant surrogates, analysis of preferred melting techniques, and coordination of large scale melting demonstrations (100--500 lbs) to be conducted at selected facilities. The program will support recycling and decontaminating stainless steel RSM for use in waste canisters for Idaho Waste Immobilization Facility densified high level waste. This report is the result of the literature search conducted to establish a basis for experimental melt/slag program development.

  15. Synthesis and Rietveld refinement of the small-pore zeolite SSZ-16

    SciTech Connect (OSTI)

    Lobo, R.F.; Zones, S.I.; Medrud, R.C.

    1996-10-01

    Recent research efforts invested in the synthesis of new high-silica zeolites have yielded several novel materials with medium ({approximately}5.6 {Angstrom}) and large ({approximately}7.2 {Angstrom}) pores. Examples include new zeolites with intersecting 10 and 12 member rings-i.e., pores bounded by 10 and 12 tetrahedral (T) atoms respectively-like SSZ-26, NU-87, SSZ-37, SSZ-25, MCM-22, CIT-1 (CON), and the aluminophosphate-based DAF-1 (DFO). However, except for the zeolites SSZ-28 (DDR) and SSZ-13 (CHA), no new high-silica zeolites with small pores have been reported. High-silica small-pore zeolites could be potentially useful for several catalytic reactions including the synthesis of dimethylamine, the reduction of NO{sub x} from combustion gases and the dewaxing of fuels for octane upgrading. The authors present here the synthesis and structural characterization using Rietveld refinement of synchrotron X-ray powder diffraction data of the zeolite SSZ-16. 27 refs., 3 figs., 2 tabs.

  16. Refined rotational period, pole solution, and shape model for (3200) Phaethon

    SciTech Connect (OSTI)

    Ansdell, Megan; Meech, Karen J.; Kaluna, Heather; Hainaut, Olivier; Buie, Marc W.; Bauer, James; Dundon, Luke

    2014-09-20

    (3200) Phaethon exhibits both comet- and asteroid-like properties, suggesting it could be a rare transitional object such as a dormant comet or previously volatile-rich asteroid. This justifies detailed study of (3200) Phaethon's physical properties as a better understanding of asteroid-comet transition objects can provide insight into minor body evolution. We therefore acquired time series photometry of (3200) Phaethon over 15 nights from 1994 to 2013, primarily using the Tektronix 2048 2048 pixel CCD on the University of Hawaii 2.2 m telescope. We utilized light curve inversion to (1) refine (3200) Phaethon's rotational period to P = 3.6032 0.0008 hr; (2) estimate a rotational pole orientation of ? = +85 13 and ? = 20 10; and (3) derive a shape model. We also used our extensive light curve data set to estimate the slope parameter of (3200) Phaethon's phase curve as G ? 0.06, consistent with C-type asteroids. We discuss how this highly oblique pole orientation with a negative ecliptic latitude supports previous evidence for (3200) Phaethon's origin in the inner main asteroid belt as well as the potential for deeply buried volatiles fueling impulsive yet rare cometary outbursts.

  17. Large magnetoresistance in non-magnetic silver chalcogenides and new class of magnetoresistive compounds

    DOE Patents [OSTI]

    Saboungi, Marie-Louis; Price, David C. L.; Rosenbaum, Thomas F.; Xu, Rong; Husmann, Anke

    2001-01-01

    The heavily-doped silver chalcogenides, Ag.sub.2+.delta. Se and Ag.sub.2+.delta. Te, show magnetoresistance effects on a scale comparable to the "colossal" magnetoresistance (CMR) compounds. Hall coefficient, magnetoconductivity, and hydrostatic pressure experiments establish that elements of narrow-gap semiconductor physics apply, but both the size of the effects at room temperature and the linear field dependence down to fields of a few Oersteds are surprising new features.

  18. Silver decorated titanate/titania nanostructures for efficient solar driven photocatalysis

    SciTech Connect (OSTI)

    Gong, Dangguo; Ho, Weng Chye Jeffrey; Tang Yuxin; Tay Qiuling; Lai Yuekun; Highfield, James George; Chen Zhong

    2012-05-15

    Photocatalysis has attracted significant interest to solve both the energy crisis and effectively combat environmental contamination. However, as the most widely used photocatalyst, titania (TiO{sub 2}) suffers from inefficient utilization of solar energy due to its wide band gap. In the present paper, we describe a method to extend the absorption edge of photocatalyst to visible region by the surface plasmon effect of silver. Silver ions are photo-reduced onto the surface of titanate nanotubes, which are synthesized by a conventional hydrothermal method. The as-synthesized Ag/titanate composite is transformed into Ag/titania nanoparticles by annealing at different temperatures. It is found that the interaction of Ag nanoparticles with the supports (titanate/titania) plays a key role for the visible light activity. The samples annealed at low temperature (<350 Degree-Sign C) do not show significant activity under our conditions, while the one annealed at 450 Degree-Sign C shows fast-degradation of methyl orange (MO) under visible light irradiation. The detailed mechanisms are also discussed. - Graphical abstract: Silver nanoparticles decorated titanate/titania as visible light active photocatalysts: silver nanoparticles could be excited by visible light due to its surface plasmon effect and excited electrons could be transferred to the conduction band of the semiconductor, where the reduction process occurs. Highlights: Black-Right-Pointing-Pointer Uniform Ag nanoparticles are photo-reduced onto titanate and titania nanostructures. Black-Right-Pointing-Pointer Titania crystal is formed by annealing hydrogen titanate at different temperatures. Black-Right-Pointing-Pointer Best visible-light activity is achieved by Ag-loaded titania annealed at 450 Degree-Sign C. Black-Right-Pointing-Pointer The visible light activity is attributed to the surface plasmonic resonance effect.

  19. Unusual adsorption properties of silver adlayers on the Pt(111) electrode surface

    SciTech Connect (OSTI)

    Marinkovic, N.S.; Wang, J.X.; Adzic, R.R.; Marinkovic, J.S.

    1999-01-07

    Adsorption properties of silver monolayer and bilayer deposited at underpotentials on a Pt(111) electrode were studied by means of linear sweep voltammetry, in situ surface X-ray scattering and infrared spectroelectrochemistry. Surface X-ray scattering measurements show a pseudomorphic Ag monolayer and an incommensurate expanded bilayer on Pt(111) formed at underpotentials. Unusual adsorption properties of the silver layers with respect to the bulk silver are observed. The two Ag adlayers were found to have intermediate adsorption/oxidation characteristics between those of metallic Ag and Pt surfaces with (111) orientation. The Ag monolayer has properties that facilitate adsorption of bisulfate anions and adsorption and oxidation of CO. These properties are closer to the adsorption properties of the Pt(111) surface than to those of Ag(111), which adsorbs sulfate anions and does not adsorb CO. The Ag bilayer on the Pt(111) surface adsorbs sulfate anions as Ag(111) does, but in contrast to the behavior of Ag(111), it adsorbs CO. These properties of the Ag adlayers appear to be a consequence of the charge-transfer process and the electron distribution in the Ag/Pt(111) surface.

  20. Rolling contact fatigue in high vacuum using ion plated nickel-copper-silver solid lubrication

    SciTech Connect (OSTI)

    Danyluk, Mike; Dhingra, Anoop

    2011-01-15

    Ion plated, nickel-copper-silver coated steel ball bearings that were tested in rolling contact fatigue (RCF) experiments in high vacuum are presented in this article. ANSI T5 ball bearings were coated with approximately 10 nm of nickel-copper followed by 100 nm of silver using a dc ion plating process. The balls were then tested for RCF in vacuum in the 10{sup -7} Torr range at 130 Hz rotational speed and at 4.1 GPa Hertzian contact stress. The significance of this work is in the extension of RCF testing to an ultrahigh vacuum (UHV) application using silver as a lubricant instead of oil. The effects of pressure and voltage on the ion plating process were also investigated using scanning electron microscopy and RCF life testing in UHV. Test results with a ball size of 5/16 in. in UHV show that deposition at voltages greater than 2.5 kV shortens the RCF life and introduces a unique failure mode. Voltage and pressure fluctuations during the deposition process result in significant thickness monitor measurement errors as well. A regulator control scheme that minimizes the process pressure overshoot is also simulated.